BGO as a hybrid scintillator / Cherenkov radiator for cost-effective time-of-flight PET

NASA Astrophysics Data System (ADS)

Brunner, S. E.; Schaart, D. R.

2017-06-01

Due to detector developments in the last decade, the time-of-flight (TOF) method is now commonly used to improve the quality of positron emission tomography (PET) images. Clinical TOF-PET systems based on L(Y)SO:Ce crystals and silicon photomultipliers (SiPMs) with coincidence resolving times (CRT) between 325 ps and 400 ps FWHM have recently been developed. Before the introduction of L(Y)SO:Ce, BGO was used in many PET systems. In addition to a lower price, BGO offers a superior attenuation coefficient and a higher photoelectric fraction than L(Y)SO:Ce. However, BGO is generally considered an inferior TOF-PET scintillator. In recent years, TOF-PET detectors based on the Cherenkov effect have been proposed. However, the low Cherenkov photon yield in the order of  ˜10 photons per event complicates energy discrimination-a severe disadvantage in clinical PET. The optical characteristics of BGO, in particular its high transparency down to 310 nm and its high refractive index of  ˜2.15, are expected to make it a good Cherenkov radiator. Here, we study the feasibility of combining event timing based on Cherenkov emission with energy discrimination based on scintillation in BGO, as a potential approach towards a cost-effective TOF-PET detector. Rise time measurements were performed using a time-correlated single photon counting (TCSPC) setup implemented on a digital photon counter (DPC) array, revealing a prompt luminescent component likely to be due to Cherenkov emission. Coincidence timing measurements were performed using BGO crystals with a cross-section of 3 mm  ×  3 mm and five different lengths between 3 mm and 20 mm, coupled to DPC arrays. Non-Gaussian coincidence spectra with a FWHM of 200 ps were obtained with the 27 mm3 BGO cubes, while FWHM values as good as 330 ps were achieved with the 20 mm long crystals. The FWHM value was found to improve with decreasing temperature, while the FWTM value showed the opposite trend.

BGO as a hybrid scintillator / Cherenkov radiator for cost-effective time-of-flight PET.

PubMed

Brunner, S E; Schaart, D R

2017-06-07

Due to detector developments in the last decade, the time-of-flight (TOF) method is now commonly used to improve the quality of positron emission tomography (PET) images. Clinical TOF-PET systems based on L(Y)SO:Ce crystals and silicon photomultipliers (SiPMs) with coincidence resolving times (CRT) between 325 ps and 400 ps FWHM have recently been developed. Before the introduction of L(Y)SO:Ce, BGO was used in many PET systems. In addition to a lower price, BGO offers a superior attenuation coefficient and a higher photoelectric fraction than L(Y)SO:Ce. However, BGO is generally considered an inferior TOF-PET scintillator. In recent years, TOF-PET detectors based on the Cherenkov effect have been proposed. However, the low Cherenkov photon yield in the order of  ∼10 photons per event complicates energy discrimination-a severe disadvantage in clinical PET. The optical characteristics of BGO, in particular its high transparency down to 310 nm and its high refractive index of  ∼2.15, are expected to make it a good Cherenkov radiator. Here, we study the feasibility of combining event timing based on Cherenkov emission with energy discrimination based on scintillation in BGO, as a potential approach towards a cost-effective TOF-PET detector. Rise time measurements were performed using a time-correlated single photon counting (TCSPC) setup implemented on a digital photon counter (DPC) array, revealing a prompt luminescent component likely to be due to Cherenkov emission. Coincidence timing measurements were performed using BGO crystals with a cross-section of 3 mm  ×  3 mm and five different lengths between 3 mm and 20 mm, coupled to DPC arrays. Non-Gaussian coincidence spectra with a FWHM of 200 ps were obtained with the 27 mm 3 BGO cubes, while FWHM values as good as 330 ps were achieved with the 20 mm long crystals. The FWHM value was found to improve with decreasing temperature, while the FWTM value showed the opposite trend.

Environmental test of the BGO calorimeter for DArk Matter Particle Explorer

NASA Astrophysics Data System (ADS)

Hu, Yi-Ming; Chang, Jin; Chen, Deng-Yi; Guo, Jian-Hua; Zhang, Yun-Long; Feng, Chang-Qing

2016-11-01

DArk Matter Particle Explorer (DAMPE) is the first Chinese astronomical satellite, successfully launched on Dec. 17 2015. As the most important payload of DAMPE, the BGO calorimeter contains 308 bismuth germanate crystals, with 616 photomultiplier tubes, one coupled to each end of every crystal. Environmental tests have been carried out to explore the environmental adaptability of the flight model of the BGO calorimeter. In this work we report the results of the vibration tests. During the vibration tests, no visible damage occurred in the mechanical assembly. After random or sinusoidal vibrations, the change of the first order natural frequency of BGO calorimeter during the modal surveys is less than 5%. The shift ratio of Most Probable Value of MIPs changes in cosmic-ray tests are shown, the mean value of which is about -4%. The comparison of results of cosmic-ray tests before and after the vibration shows no significant change in the performance of the BGO calorimeter. All these results suggest that the calorimeter and its structure have passed through the environment tests successfully. Supported by National Natural Science Foundation of China (11203090, 11003051, 11273070) and Strategic Priority Research Program on Space Science of Chinese Academy of Sciences (XDA04040202)

Hydrothermal synthesis of bismuth germanium oxide

DOEpatents

Boyle, Timothy J.

2016-12-13

A method for the hydrothermal synthesis of bismuth germanium oxide comprises dissolving a bismuth precursor (e.g., bismuth nitrate pentahydrate) and a germanium precursor (e.g., germanium dioxide) in water and heating the aqueous solution to an elevated reaction temperature for a length of time sufficient to produce the eulytite phase of bismuth germanium oxide (E-BGO) with high yield. The E-BGO produced can be used as a scintillator material. For example, the air stability and radioluminescence response suggest that the E-BGO can be employed for medical applications.

Assessing background ground water chemistry beneath a new unsewered subdivision

USGS Publications Warehouse

Wilcox, J.D.; Bradbury, K.R.; Thomas, C.L.; Bahr, J.M.

2005-01-01

Previous site-specific studies designed to assess the impacts of unsewered subdivisions on ground water quality have relied on upgradient monitoring wells or very limited background data to characterize conditions prior to development. In this study, an extensive monitoring program was designed to document ground water conditions prior to construction of a rural subdivision in south-central Wisconsin. Previous agricultural land use has impacted ground water quality; concentrations of chloride, nitrate-nitrogen, and atrazine ranged from below the level of detection to 296 mg/L, 36 mg/L, and 0.8 ??g/L, respectively, and were highly variable from well to well and through time. Seasonal variations in recharge, surface topography, aquifer heterogeneities, surficial loading patterns, and well casing depth explain observed variations in ground water chemistry. This variability would not have been detected if background conditions were determined from only a few monitoring wells or inferred from wells located upgradient of the subdivision site. This project demonstrates the importance of characterizing both ground water quality and chemical variability prior to land-use change to detect any changes once homes are constructed. Copyright ?? 2005 National Ground Water Association.

Inexpensive position sensitive detector block for dedicated PET cameras using 40-mm diameter PMT in quadrant sharing configuration

NASA Astrophysics Data System (ADS)

Uribe, J.; Aykac, M.; Baghaei, H.; Li, Hongdi; Wang, Yu; Liu, Yaqiang; Wong, V.; Xing, Tao; Ramirez, R.; Wong, Wai-Hoi

2003-06-01

Recent approvals by CMS (HCFA) for reimbursement of positron emission tomography (PET) scans fuels the rapid grow of the PET market, thus creating the need for more affordable dedicated PET scanners. The objective of the work presented here was the development of a BGO position-sensitive block with similar detector area (40 mm /spl times/ 40 mm) and same number of crystals (8 /spl times/ 8) as the block of a commercial BGO PET, using the less expensive photomultiplier quadrant sharing (PQS) technique. This block is coupled to four single-anode 40-mm diameter photomultipliers (PMT) instead of the 19-mm PMT used in a popular commercial BGO PET, and each PMT is shared by four adjacent detector blocks. Potentially, this design needs only 25% of the number of PMT used in the commercial BGO PET. In order not to waste the unused half-row of PMT at the edges of a detector panel/module when the module is made up solely of square blocks, an extended rectangular block has to be developed for the edge-blocks in the module, which maximized the use of the PMT and minimized the gap between modules. Only the extended block needs to be developed to derive the design for all the blocks in the module because the symmetric square block uses the same light-distributing partitions as those along the short side of the extended rectangular block. White-paint masks applied with accurate templates and airbrush were fine-tuned for every pair of adjacent crystals. The experimental block developed in this study provided good crystal-decoding. The composite energy spectrum of all 64 crystals showed a prominent photopeak. The worst crystal sitting in the air space between 4 round PMTs still has 60% of the signal pulse height as the best crystal. The average energy resolution was 21.8% for 511 keV gamma (range 17% - 28.7%) that compared well with the 22% - 44% measured with GE and CTI blocks. The image resolution provided by the PQS blocks is expected to be comparable to that of commercial BGO PETs as similar size crystals were decoded.

Ground-water flow and the potential effects of remediation at Graces Quarters, Aberdeen Proving Ground, Maryland

USGS Publications Warehouse

Tenbus, F.J.; Fleck, W.B.

1996-01-01

Ground water in the east-central part of Graces Quarters, a former open-air chemical-agent test facility at Aberdeen Proving Ground, Maryland, is contaminated with chlorinated volatile organic compounds. The U.S. Geological Survey's finite- difference model was used to help understand ground-water flow and simulate the effects of alternative remedial actions to clean up the ground water. Scenarios to simulate unstressed conditions and three extraction well con- figurations were used to compare alternative remedial actions on the contaminant plume. The scenarios indicate that contaminants could migrate from their present location to wetland areas within 10 years under unstressed conditions. Pumping 7 gal/min (gallons per minute) from one well upgradient of the plume will not result in containment or removal of the highest contaminant concentrations. Pumping 7 gal/min from three wells along the central axis of the plume should result in containment and removal of dissolved contami- nants, as should pumping 7 gal/min from three wells at the leading edge of the plume while injecting 7 gal/min back into an upgradient well.

The ATIC Experiment : Performance of the Scintillator Hodoscope and the BGO Calorimeter

NASA Technical Reports Server (NTRS)

Isbert, J.; Whitaker, Ann F. (Technical Monitor)

2001-01-01

The Advanced Thin Ionization Calorimeter (ATIC) Balloon Experiment had its first flight from McMurdo, Antarctica, 28/12/00 to 13/01/01, recording over 360 hours of data. The design goal for ATIC was to measure the Cosmic Ray composition and energy spectra from approximately 50 GeV to near 100 TeV utilizing a Si-matrix detector, a scintillator hodoscope, carbon targets and a calorimeter consisting of a stack of BGO scintillator crystals. The design, operation, and in-flight performance of the scintillator hodoscope and the BGO calorimeter are described.

The ATIC Experiment: Performance of the Scintillator Hodoscopes and the BGO Calorimeter

NASA Technical Reports Server (NTRS)

Isbert, Joachim; Adams, J. H.; Ahn, H.; Ampe, J.; Bashindzhagyan, G.; Whitaker, Ann F. (Technical Monitor)

2001-01-01

The Advanced Thin Ionization Calorimeter (ATIC) Balloon Experiment had its first flight from Mcmurdo, Antarctica 28/12/2000 to 13/01/2001, local time, recording over 360 hours of data. The design goal of ATIC was to measure the Cosmic Ray composition and energy spectra from approximately 50 GeV to near 100 TeV utilizing a Si-matrix detector, a scintillator hodoscope, carbon targets and a calorimeter consisting of a stack of BGO scintillator crystals. The design, the operations and in-flight performance of the scintillator hodoscope and the BGO calorimeter are described.

Mineral Precipitation Upgradient from a Zero-Valent Iron Permeable Reactive Barrier

DOE Office of Scientific and Technical Information (OSTI.GOV)

Johnson, R. L.; Thoms, R. B.; Johnson, R. O.

2008-07-01

Core samples taken from a zero-valent iron permeable reactive barrier (ZVI PRB) at Cornhusker Army Ammunition Plant, Nebraska, were analyzed for physical and chemical characteristics. Precipitates containing iron and sulfide were present at much higher concentrations in native aquifer materials just upgradient of the PRB than in the PRB itself. Sulfur mass balance on core solids coupled with trends in ground water sulfate concentrations indicates that the average ground water flow after 20 months of PRB operation was approximately twenty fold less than the regional ground water velocity. Transport and reaction modeling of the aquifer PRB interface suggests that, atmore » the calculated velocity, both iron and hydrogen could diffuse upgradient against ground water flow and thereby contribute to precipitation in the native aquifer materials. The initial hydraulic conductivity (K) of the native materials is less than that of the PRB and, given the observed precipitation in the upgradient native materials, it is likely that K reduction occurred upgradient to rather than within the PRB. Although not directly implicated, guar gum used during installation of the PRB is believed to have played a role in the precipitation and flow reduction processes by enhancing microbial activity.« less

Ground-water quality, levels, and flow direction near Fort Cobb Reservoir, Caddo County, Oklahoma, 1998-2000

USGS Publications Warehouse

Becker, Carol J.

2001-01-01

Fort Cobb Reservoir in northwest Caddo County Oklahoma is managed by the Bureau of Reclamation for water supply, recreation, flood control, and wildlife. Excessive amounts of nitrogen in the watershed have the potential to cause long-term eutrophication of the reservoir and increase already elevated concentrations of nitrogen in the Rush Springs aquifer. The U.S. Geological Survey in cooperation with the Bureau of Reclamation studied ground water in the area surrounding a swine feeding operation located less than 2 miles upgradient from Fort Cobb Reservoir in Caddo County, Oklahoma. Objectives of the study were to (1) determine if the operation was contributing nitrogen to the ground water and (2) measure changes in ground-water levels and determine the local ground-water flow direction in the area surrounding the swine feeding operation. Nitrate concentrations (28.1 and 31.5 milligrams per liter) were largest in two ground-water samples from a well upgradient of the wastewater lagoon. Nitrate concentrations ranged from 4.30 to 8.20 milligrams per liter in samples from downgradient wells. Traces of ammonia and nitrite were detected in a downgradient well, but not in upgradient wells. d15N values indicate atmospheric nitrogen, synthetic fertilizer, or plants were the predominate sources of nitrate in ground water from the downgradient wells. The d15N values in these samples are depleted in nitrogen-15, indicating that animal waste was not a significant contributor of nitrate. Manganese concentrations (1,150 and 965 micrograms per liter) in samples from a downgradient well were substantially larger than concentrations in samples from other wells, exceeding the secondary drinking-water standard of 50 micrograms per liter. Larger concentrations of bicarbonate, magnesium, fluoride, and iron and a higher pH were also measured in water from a downgradient well. Ground-water levels in an observation well were higher from April to mid-July and lower during the late summer and in the fall due to a seasonal decrease in precipitation, increase in water withdrawals, and increase in evapotranspiration. Ground water near the wastewater spray field moved south-southeast toward Willow Creek along a gradient of about 50 feet per mile. Analysis of ground-water samples suggest that commercial fertilizer is contributing nitrate upgradient of the swine feeding operation and that wastewater from the lagoon is contributing reduced forms of nitrogen, ammonia and nitrite. Additional downgradient wells would be needed to (1) determine if the swine feeding operation is adding excessive amounts of nitrogen to ground water, (2) determine the vertical dimension of wastewater flow, and (3) the extent of wastewater downgradient of the lagoon.

Improved background suppression for radiative capture reactions at LUNA with HPGe and BGO detectors

NASA Astrophysics Data System (ADS)

Boeltzig, A.; Best, A.; Imbriani, G.; Junker, M.; Aliotta, M.; Bemmerer, D.; Broggini, C.; Bruno, C. G.; Buompane, R.; Caciolli, A.; Cavanna, F.; Chillery, T.; Ciani, G. F.; Corvisiero, P.; Csedreki, L.; Davinson, T.; deBoer, R. J.; Depalo, R.; Di Leva, A.; Elekes, Z.; Ferraro, F.; Fiore, E. M.; Formicola, A.; Fülöp, Z.; Gervino, G.; Guglielmetti, A.; Gustavino, C.; Gyürky, G.; Kochanek, I.; Menegazzo, R.; Mossa, V.; Pantaleo, F. R.; Paticchio, V.; Perrino, R.; Piatti, D.; Prati, P.; Schiavulli, L.; Stöckel, K.; Straniero, O.; Strieder, F.; Szücs, T.; Takács, M. P.; Trezzi, D.; Wiescher, M.; Zavatarelli, S.

2018-02-01

Direct measurements of small nuclear reaction cross sections require a low background in the signal region of interest to achieve the necessary sensitivity. We describe two complementary detector setups that have been used for studies of ({{p}},γ ) reactions with solid targets at the Laboratory for Underground Nuclear Astrophysics (LUNA): a high-purity germanium detector and a bismuth germanate (BGO) detector. We present the effect of a customised lead shielding on the measured background spectra in the two detector setups at LUNA. We developed a model to describe the contributions of environmental and intrinsic backgrounds in the BGO detector measurements. Furthermore we present an upgrade of the data acquisition system for our BGO detector, which allows us to exploit the features of the segmented detector and overcome some of the limitations encountered in previous experiments. We conclude with a discussion on the improved sensitivity of the presented setups, and the benefits for ongoing and possible future measurements.

Ground-water contamination and movement at the Defense General Supply Center, Richmond, Virginia. Water Resources Investigation

DOE Office of Scientific and Technical Information (OSTI.GOV)

Powell, J.D.; Wright, W.G.; Nelms, D.L.

1990-01-01

The report documents the efforts of the USGS in support of the quantification phase of the IRP to determine the degree of contamination of a site that has been identified as requiring study. The report describes the extent, concentration, direction, and rate of movement of contaminants in ground water beyond the boundaries of the DGSC. Hydrologic and geologic data were collected during 1984-90 from wells located upgradient from the DGSC, upgradient from the Area 50 landfill located on the DGSC, in the landfill, in the National Guard Area (NGA) downgradient from the landfill, and downgradient from the NGA beyond themore » eastern boundary of the DGSC. Lithologic data were collected during drilling of wells installed downgradient of the NGA by the USGS during 1984-86. Water from wells located downgradient of the NGA was analyzed for volatile-organic compounds, major cations and anions, priority-pollutant trace metals, and total organic carbon. Aquifer-test wells were installed by the USGS and aquifer testing was performed during 1985.« less

Readout Electronics for BGO Calorimeter of DAMPE: Status during the First Half-year after Launching

NASA Astrophysics Data System (ADS)

Ma, Siyuan; Feng, Changqing; Zhang, Deliang; Wang, Qi

2016-07-01

The DAMPE (DArk Matter Particle Explorer) is a scientic satellite which was successfully launched into a 500 Km sun-synchronous orbit, on December 17th, 2015, from the Jiuquan Satellite Launch Center of China. The major scientific objective of DAMPE mission is indirect searching for dark matter by observing high energy primary cosmic rays, especially positrons/electrons and gamma rays with an energy range from 5 GeV to 10 TeV. The BGO (Bismuth Germanate Oxide) calorimeter, which is a critical sub-detector of DAMPE payload, was developed for measuring the energy of cosmic particles, distinguishing positrons/electrons and gamma rays from hadron background, and providing trigger information. It is composed of 308 BGO crystal logs, with the size of 2.5cm*2.5cm*60cm for each log to form a total absorption electromagnetic calorimeter. All the BGO logs are stacked in 14 layers, with each layer consisting of 22 BGO crystal logs and each log is viewed by two Hamamatsu R5610A PMTs (photomultiplier tubes), from both sides respectively. Each PMT incorporates a three dynode pick off to achieve a large dynamic range, which results in 616 PMTs and 1848 signal channels. The main function of readout electronics system, which consists of 16 FEE(Front End Electronics) modules, is to precisely measure the charge of PMT signals and providing "hit" signals. The hit signals are sent to the trigger module of PDPU (Payload Data Process Unit) to generate triggers for the payload. The calibration of the BGO calorimeter is composed of pedestal testing and electronic linear scale, which are executed frequently in the space after launching. The data of the testing is transmitted to ground station in the form of scientific data. The monitor status consists of temperature, current and status words of the FEE, which are measured and recorded every 16 seconds and packed in the engineering data, then transmitted to ground station. The status of the BGO calorimeter can be evaluated by the calibration and monitor status. The preliminary results of the status in the first six month after launching are introduced in this paper.

Low energy prompt gamma-ray tests of a large volume BGO detector.

PubMed

Naqvi, A A; Kalakada, Zameer; Al-Anezi, M S; Raashid, M; Khateeb-ur-Rehman; Maslehuddin, M; Garwan, M A

2012-01-01

Tests of a large volume Bismuth Germinate (BGO) detector were carried out to detect low energy prompt gamma-rays from boron and cadmium-contaminated water samples using a portable neutron generator-based Prompt Gamma Neutron Activation Analysis (PGNAA) setup. Inspite of strong interference between the sample- and the detector-associated prompt gamma-rays, an excellent agreement has been observed between the experimental and calculated yields of the prompt gamma-rays, indicating successful application of the large volume BGO detector in the PGNAA analysis of bulk samples using low energy prompt gamma-rays. Copyright © 2011 Elsevier Ltd. All rights reserved.

40 CFR 257.25 - Assessment monitoring program.

Code of Federal Regulations, 2012 CFR

2012-07-01

...) Minimum distance between upgradient edge of the unit and downgradient monitoring well screen (minimum... that is likely to be without appreciable risk of deleterious effects during a lifetime. For purposes of this subpart, systemic toxicants include toxic chemicals that cause effects other than cancer or...

40 CFR 257.25 - Assessment monitoring program.

Code of Federal Regulations, 2013 CFR

2013-07-01

...) Minimum distance between upgradient edge of the unit and downgradient monitoring well screen (minimum... that is likely to be without appreciable risk of deleterious effects during a lifetime. For purposes of this subpart, systemic toxicants include toxic chemicals that cause effects other than cancer or...

40 CFR 257.25 - Assessment monitoring program.

Code of Federal Regulations, 2011 CFR

2011-07-01

...) Minimum distance between upgradient edge of the unit and downgradient monitoring well screen (minimum... that is likely to be without appreciable risk of deleterious effects during a lifetime. For purposes of this subpart, systemic toxicants include toxic chemicals that cause effects other than cancer or...

40 CFR 258.55 - Assessment monitoring program.

Code of Federal Regulations, 2013 CFR

2013-07-01

... upgradient edge of the MSWLF unit and downgradient monitoring well screen (minimum distance of travel); (5... effects during a lifetime. For purposes of this subpart, systemic toxicants include toxic chemicals that cause effects other than cancer or mutation. (ii) [Reserved] (j) In establishing ground-water protection...

40 CFR 258.55 - Assessment monitoring program.

Code of Federal Regulations, 2011 CFR

2011-07-01

... upgradient edge of the MSWLF unit and downgradient monitoring well screen (minimum distance of travel); (5... effects during a lifetime. For purposes of this subpart, systemic toxicants include toxic chemicals that cause effects other than cancer or mutation. (ii) [Reserved] (j) In establishing ground-water protection...

40 CFR 258.55 - Assessment monitoring program.

Code of Federal Regulations, 2012 CFR

2012-07-01

... upgradient edge of the MSWLF unit and downgradient monitoring well screen (minimum distance of travel); (5... effects during a lifetime. For purposes of this subpart, systemic toxicants include toxic chemicals that cause effects other than cancer or mutation. (ii) [Reserved] (j) In establishing ground-water protection...

Optimization of the Performance of Segmented Scintillators for Radiotherapy Imaging through Novel Binning Techniques

PubMed Central

El-Mohri, Youcef; Antonuk, Larry E.; Choroszucha, Richard B.; Zhao, Qihua; Jiang, Hao; Liu, Langechuan

2014-01-01

Thick, segmented crystalline scintillators have shown increasing promise as replacement x-ray converters for the phosphor screens currently used in active matrix flat-panel imagers (AMFPIs) in radiotherapy, by virtue of providing over an order of magnitude improvement in the DQE. However, element-to-element misalignment in current segmented scintillator prototypes creates a challenge for optimal registration with underlying AMFPI arrays, resulting in degradation of spatial resolution. To overcome this challenge, a methodology involving the use of a relatively high resolution AMFPI array in combination with novel binning techniques is presented. The array, which has a pixel pitch of 0.127 mm, was coupled to prototype segmented scintillators based on BGO, LYSO and CsI:Tl materials, each having a nominal element-to-element pitch of 1.016 mm and thickness of ~1 cm. The AMFPI systems incorporating these prototypes were characterized at a radiotherapy energy of 6 MV in terms of MTF, NPS, DQE, and reconstructed images of a resolution phantom acquired using a cone-beam CT geometry. For each prototype, the application of 8×8 pixel binning to achieve a sampling pitch of 1.016 mm was optimized through use of an alignment metric which minimized misregistration and thereby improved spatial resolution. In addition, the application of alternative binning techniques that exclude the collection of signal near septal walls resulted in further significant improvement in spatial resolution for the BGO and LYSO prototypes, though not for the CsI:Tl prototype due to the large amount of optical cross-talk resulting from significant light spread between scintillator elements in that device. The efficacy of these techniques for improving spatial resolution appears to be enhanced for scintillator materials that exhibit mechanical hardness, high density and high refractive index, such as BGO. Moreover, materials that exhibit these properties as well as offer significantly higher light output than BGO, such as CdWO4, should provide the additional benefit of preserving DQE performance. PMID:24487347

Energy levels scheme simulation of divalent cobalt doped bismuth germanate

DOE Office of Scientific and Technical Information (OSTI.GOV)

Andreici, Emiliana-Laura, E-mail: andreicilaura@yahoo.com; Petkova, Petya; Avram, Nicolae M.

The aim of this paper is to simulate the energy levels scheme for Bismuth Germanate (BGO) doped with divalent cobalt, in order to give a reliable explanation for spectral experimental data. In the semiempirical crystal field theory we first modeled the Crystal Field Parameters (CFPs) of BGO:Cr{sup 2+} system, in the frame of Exchange Charge Model (ECM), with actually site symmetry of the impurity ions after doping. The values of CFPs depend on the geometry of doped host matrix and by parameter G of ECM. First, we optimized the geometry of undoped BGO host matrix and afterwards, that of dopedmore » BGO with divalent cobalt. The charges effect of ligands and covalence bonding between cobalt cations and oxygen anions, in the cluster approach, also were taken into account. With the obtained values of the CFPs we simulate the energy levels scheme of cobalt ions, by diagonalizing the matrix of the doped crystal Hamiltonian. Obviously, energy levels and estimated Racah parameters B and C were compared with the experimental spectroscopic data and discussed. Comparison of obtained results with experimental data shows quite satisfactory, which justify the model and simulation schemes used for the title system.« less

Prevalence of antibiotic resistance genes in bacterial communities associated with Cladophora glomerata mats along the nearshore of Lake Ontario.

PubMed

Ibsen, Michael; Fernando, Dinesh M; Kumar, Ayush; Kirkwood, Andrea E

2017-05-01

The alga Cladophora glomerata can erupt in nuisance blooms throughout the lower Great Lakes. Since bacterial abundance increases with the emergence and decay of Cladophora, we investigated the prevalence of antibiotic resistance (ABR) in Cladophora-associated bacterial communities up-gradient and down-gradient from a large sewage treatment plant (STP) on Lake Ontario. Although STPs are well-known sources of ABR, we also expected detectable ABR from up-gradient wetland communities, since they receive surface run-off from urban and agricultural sources. Statistically significant differences in aquatic bacterial abundance and ABR were found between down-gradient beach samples and up-gradient coastal wetland samples (ANOVA, Holm-Sidak test, p < 0.05). Decaying and free-floating Cladophora sampled near the STP had the highest bacterial densities overall, including on ampicillin- and vancomycin-treated plates. However, quantitative polymerase chain reaction analysis of the ABR genes ampC, tetA, tetB, and vanA from environmental communities showed a different pattern. Some of the highest ABR gene levels occurred at the 2 coastal wetland sites (vanA). Overall, bacterial ABR profiles from environmental samples were distinguishable between living and decaying Cladophora, inferring that Cladophora may control bacterial ABR depending on its life-cycle stage. Our results also show how spatially and temporally dynamic ABR is in nearshore aquatic bacteria, which warrants further research.

Application of environmental tracers to delineate recharge patterns and nitrate contamination in shallow groundwater around a river

NASA Astrophysics Data System (ADS)

Kaown, Dugin; Koh, Eunhee; Park, Byeong-Hak; Lee, Kang-Kun

2016-04-01

Hydrogeochemical data, stable isotopes, chlorofluorocarbon (CFCs) and 3H-3He in groundwater were applied to characterize residence time, recharge patterns and nitrate contamination of groundwater in a small agricultural area, Yangpyung, Korea. The study area is located around a river and the measured groundwater table ranges from 1.5 to 2.65 m during the year. Most residents in the study area practice agriculture and potato, strawberry, and cabbage are the typical vegetables grown. Vegetable fields are mostly located in the upgradient area of the study area while forest and residence areas are located in the downgradient area. A lot of chemical and organic fertilizers are applied in the upgradient area. The concentration of NO3-N in groundwater showed 9.8-83.7 mg/L in the upgradient area and 0.1-22.6 mg/L in the downgradient area in 2014. It is necessary to monitor groundwater recharge patterns and transport processes of nitrate to protect surface water around the study area. The values of δ18O and δD showed that groundwater is recharged mainly from summer precipitation. The apparent groundwater ages using 3H-3He and CFCs ranged from 13 to 27 years in the upgradient area and from 25 to 35 years in the downgradient area. The NO3-N in more recently recharged groundwater showed higher concentrations while the NO3-N in older groundwater showed low concentrations. Some shallow wells in the downgradient area showed similar apparent groundwater age with that of the river water indicating groundwater-surface water interactions. A conceptual model of groundwater-surface water interactions using stable isotopes, apparent 3H-3He and CFCs age in groundwater will be useful to understand the hydrological processes and nitrate contamination of the study area.

Temperature Effects in the ATIC BGO Calorimeter

NASA Technical Reports Server (NTRS)

Isbert, J.; Adams, J. H.; Ahn, H.; Bashindzhagyan, G.; Batkov, K.; Chang, J.; Christl, M. J.; Fazely, A.; Ganel, O.; Gunasigha, R.

2006-01-01

The Advanced Thin Ionization Calorimeter (ATIC) Balloon Experiment contains a segmented calorimeter composed of 320 individual BGO crystals (18 radiation lengths deep) to determine the particle energy. Like all inorganic scintillation crystals the light output of BGO depends not only on the energy deposited by particles but also on the temperature of the crystal. ATIC had successful flights in 2000/2001 and 2002/2003 from McMurdo, Antarctica. The temperature of balloon instruments varies during their flights at altitude due to sun angle variations and differences in albedo from the ground and is monitored and recorded. In order to determine the temperature sensitivity of the ATIC calorimeter it was temperature cycled in the thermal vacuum chamber at the CSBF in Palestine, TX. The temperature dependence is derived from the pulse height response to cosmic ray muons at various temperatures.

McClellan AFB, California. Operable Unit B, Engineering Evaluation/Cost Analysis - Environmental Assessment

DTIC Science & Technology

1991-02-01

however, ’the daily flow rate can dramatically increase during storm events due to rainwater infiltration, to the system . Treatment processes include...132 has been restricted from supplying water to the local distribution system , except in emergency situations. This well was being threatened by...the near surface aquifer upgradient from the production well. The extracted groundwater will be treated in a granular activated carbon system and

Effects of Dual-Pump Recovery on Crude-Oil Contamination of Groundwater, Bemidji, Minnesota

NASA Astrophysics Data System (ADS)

Delin, G. N.; Herkelrath, W. N.; Lounsbury, S.

2009-12-01

In 1979 a crude-oil pipeline ruptured near Bemidji, Minnesota spilling about 1.7 million liters of crude oil onto a glacial-outwash deposit. Initial remediation efforts in 1979-80 removed about 75% of this oil. In 1983 the U.S. Geological Survey and several academic institutions began research to study the fate and transport of the petroleum hydrocarbons in the unsaturated and saturated zones at the site. In 1998 the Minnesota Pollution Control Agency (MPCA) requested that the pipeline company remove as much of the remaining oil as possible. A dual-pump recovery system was installed using five wells to remove the free-phase oil. Each well had an oil skimming pump as well as a deeper pump in the groundwater, which was used to create a cone of depression in the water table near the well. The oil/water mixture from the skimming pump was pumped to a treatment facility where the oil was separated for later removal from the site. Pumped wastewater was injected into an upgradient infiltration gallery. Despite large public and private expenditures on development and implementation of this type of remediation system, few well-documented field-scale case studies have been published. The renewed remediation presented an opportunity to document how the dissolution, biodegradation, vapor transport, and other processes changed as the site transitioned from natural attenuation to a condition of pump-and-treat remediation and back again following termination of the remediation. Impacts of the remediation were evaluated in part using measurements of oil thicknesses in wells, dissolved-oxygen concentrations in groundwater, and concentrations of methane and other gases in the unsaturated zone. The remediation from 1999 - 2004 resulted in removal of about 114,000 liters of crude oil from the site, or about 27% of the total that remained following the initial remediation in 1979-80. Although the renewed remediation decreased oil thicknesses in the immediate vicinity of remediation wells, average oil thicknesses measured in wells at the north pool (0.6 m) and south pool (0.3 m) were largely unaffected. Dissolved-oxygen measurements indicate that a new plume caused by injection of wastewater in the infiltration gallery expanded rapidly immediately following the start of the remediation in 1999. The result was an expansion of the anoxic plume of groundwater upgradient and beneath the existing natural attenuation plume. Vapor sampling results were ambiguous. From 2004-2008, CH4 and CO2 vapor concentrations decreased in upgradient areas above the floating crude oil and increased in downgradient areas above the crude oil. Conversely, O2 vapor concentrations increased in upgradient areas above the floating crude oil and decreased in downgradient areas above the crude oil. Observed changes in vapor concentrations appear to be unrelated to the renewed remediation but instead are consistent with a continuing shift in microbial population from iron reducing to methanogenic conditions. Results indicate that oil phase recovery at this site is challenging, and that considerable volumes of mobile and entrapped oil may still remain in the subsurface in spite of remediation efforts.

Photoproduction of Mesons

NASA Astrophysics Data System (ADS)

Schmieden, Hartmut; Klein, Friedrich

2017-01-01

B.1 is one of the experimental projects within the CRC16. It aims at the systematic investigation of the photoproduction of mesons off nucleons in order to understand reaction mechanisms and the relevant degrees of freedom in resonance formation. Of particular interest is the photoproduction of mesons heavier than the pion and resonances involving hidden or open strangeness. Essential hardware contributions have been made to the experimental programme of the CRC16 through tagging systems, and photon-beam polarisation and polarimetry. A new experiment has been set up within the framework of the BGO-OD collaboration. This combines a forward magnetic spectrometer with a central BGO calorimeter with charged particle recognition and identification. The BGO-OD experiment enables reconstruction of complex final states composed of both charged and neutral particles, complementary to the existing CBELSA/TAPS calorimeter which is optimised for multi-photon final states. Selected results of the 12-year CRC period are presented from both experiments.

40 CFR 265.94 - Recordkeeping and reporting.

Code of Federal Regulations, 2012 CFR

2012-07-01

... required in § 265.92(e), and the evaluations required in § 265.93(b) throughout the active life of the... found in the upgradient wells, in accordance with § 265.93(c)(1). During the active life of the facility... requirements of § 265.93(d)(3), throughout the active life of the facility, and, for disposal facilities...

40 CFR 265.94 - Recordkeeping and reporting.

Code of Federal Regulations, 2010 CFR

2010-07-01

... required in § 265.92(e), and the evaluations required in § 265.93(b) throughout the active life of the... found in the upgradient wells, in accordance with § 265.93(c)(1). During the active life of the facility... requirements of § 265.93(d)(3), throughout the active life of the facility, and, for disposal facilities...

40 CFR 265.94 - Recordkeeping and reporting.

Code of Federal Regulations, 2011 CFR

2011-07-01

... required in § 265.92(e), and the evaluations required in § 265.93(b) throughout the active life of the... found in the upgradient wells, in accordance with § 265.93(c)(1). During the active life of the facility, this information must be submitted no later than March 1 following each calendar year. (iii) No later...

A DOI Detector With Crystal Scatter Identification Capability for High Sensitivity and High Spatial Resolution PET Imaging.

PubMed

Gu, Z; Prout, D L; Silverman, R W; Herman, H; Dooraghi, A; Chatziioannou, A F

2015-06-01

A new phoswich detector is being developed at the Crump Institute, aiming to provide improvements in sensitivity, and spatial resolution for PET. The detector configuration is comprised of two layers of pixelated scintillator crystal arrays, a glass light guide and a light detector. The annihilation photon entrance (top) layer is a 48 × 48 array of 1.01 × 1.01 × 7 mm 3 LYSO crystals. The bottom layer is a 32 × 32 array of 1.55 × 1.55 × 9 mm 3 BGO crystals. A tapered, multiple-element glass lightguide is used to couple the exit end of the BGO crystal array (52 × 52 mm 2 ) to the photosensitive area of the Position Sensitive Photomultiplier Tube (46 × 46 mm 2 ), allowing the creation of flat panel detectors without gaps between the detector modules. Both simulations and measurements were performed to evaluate the characteristics and benefits of the proposed design. The GATE Monte Carlo simulation indicated that the total fraction of the cross layer crystal scatter (CLCS) events in singles detection mode for this detector geometry is 13.2%. The large majority of these CLCS events (10.1% out of 13.2%) deposit most of their energy in a scintillator layer other than the layer of first interaction. Identification of those CLCS events for rejection or correction may lead to improvements in data quality and imaging performance. Physical measurements with the prototype detector showed that the LYSO, BGO and CLCS events were successfully identified using the delayed charge integration (DCI) technique, with more than 95% of the LYSO and BGO crystal elements clearly resolved. The measured peak-to-valley ratios (PVR) in the flood histograms were 3.5 for LYSO and 2.0 for BGO. For LYSO, the energy resolution ranged from 9.7% to 37.0% full width at half maximum (FWHM), with a mean of 13.4 ± 4.8%. For BGO the energy resolution ranged from 16.0% to 33.9% FWHM, with a mean of 18.6 ± 3.2%. In conclusion, these results demonstrate that the proposed detector is feasible and can potentially lead to a high spatial resolution, high sensitivity and DOI PET system.

A DOI Detector With Crystal Scatter Identification Capability for High Sensitivity and High Spatial Resolution PET Imaging

PubMed Central

Gu, Z.; Prout, D. L.; Silverman, R. W.; Herman, H.; Dooraghi, A.; Chatziioannou, A. F.

2015-01-01

A new phoswich detector is being developed at the Crump Institute, aiming to provide improvements in sensitivity, and spatial resolution for PET. The detector configuration is comprised of two layers of pixelated scintillator crystal arrays, a glass light guide and a light detector. The annihilation photon entrance (top) layer is a 48 × 48 array of 1.01 × 1.01 × 7 mm3 LYSO crystals. The bottom layer is a 32 × 32 array of 1.55 × 1.55 × 9 mm3 BGO crystals. A tapered, multiple-element glass lightguide is used to couple the exit end of the BGO crystal array (52 × 52 mm2) to the photosensitive area of the Position Sensitive Photomultiplier Tube (46 × 46 mm2), allowing the creation of flat panel detectors without gaps between the detector modules. Both simulations and measurements were performed to evaluate the characteristics and benefits of the proposed design. The GATE Monte Carlo simulation indicated that the total fraction of the cross layer crystal scatter (CLCS) events in singles detection mode for this detector geometry is 13.2%. The large majority of these CLCS events (10.1% out of 13.2%) deposit most of their energy in a scintillator layer other than the layer of first interaction. Identification of those CLCS events for rejection or correction may lead to improvements in data quality and imaging performance. Physical measurements with the prototype detector showed that the LYSO, BGO and CLCS events were successfully identified using the delayed charge integration (DCI) technique, with more than 95% of the LYSO and BGO crystal elements clearly resolved. The measured peak-to-valley ratios (PVR) in the flood histograms were 3.5 for LYSO and 2.0 for BGO. For LYSO, the energy resolution ranged from 9.7% to 37.0% full width at half maximum (FWHM), with a mean of 13.4 ± 4.8%. For BGO the energy resolution ranged from 16.0% to 33.9% FWHM, with a mean of 18.6 ± 3.2%. In conclusion, these results demonstrate that the proposed detector is feasible and can potentially lead to a high spatial resolution, high sensitivity and DOI PET system. PMID:26478600

A DOI Detector With Crystal Scatter Identification Capability for High Sensitivity and High Spatial Resolution PET Imaging

NASA Astrophysics Data System (ADS)

Gu, Z.; Prout, D. L.; Silverman, R. W.; Herman, H.; Dooraghi, A.; Chatziioannou, A. F.

2015-06-01

A new phoswich detector is being developed at the Crump Institute, aiming to provide improvements in sensitivity, and spatial resolution for PET. The detector configuration is comprised of two layers of pixelated scintillator crystal arrays, a glass lightguide and a light detector. The annihilation photon entrance (top) layer is a 48×48 array of 1.01 × 1.01 × 7 mm3 LYSO crystals. The bottom layer is a 32 × 32 array of 1.55 × 1.55 × 9 mm3 BGO crystals. A tapered, multiple-element glass lightguide is used to couple the exit end of the BGO crystal array (52 × 52 mm2) to the photosensitive area of the Position Sensitive Photomultiplier Tube (46 × 46 mm2), allowing the creation of flat panel detectors without gaps between the detector modules. Both simulations and measurements were performed to evaluate the characteristics and benefits of the proposed design. The GATE Monte Carlo simulation indicated that the total fraction of the cross layer crystal scatter (CLCS) events in singles detection mode for this detector geometry is 13.2%. The large majority of these CLCS events (10.1% out of 13.2%) deposit most of their energy in a scintillator layer other than the layer of first interaction. Identification of those CLCS events for rejection or correction may lead to improvements in data quality and imaging performance. Physical measurements with the prototype detector showed that the LYSO, BGO and CLCS events were successfully identified using the delayed charge integration (DCI) technique, with more than 95% of the LYSO and BGO crystal elements clearly resolved. The measured peak-to-valley ratios (PVR) in the flood histograms were 3.5 for LYSO and 2.0 for BGO. For LYSO, the energy resolution ranged from 9.7% to 37.0% full width at half maximum (FWHM), with a mean of 13.4 ± 4.8%. For BGO the energy resolution ranged from 16.0% to 33.9% FWHM, with a mean of 18.6 ± 3.2%. In conclusion, these results demonstrate that the proposed detector is feasible and can potentially lead to a high spatial resolution, high sensitivity and DOI PET system.

Study on Radiation Condition in DAMPE Orbit by Analyzing the Engineering Data of BGO Calorimeter

NASA Astrophysics Data System (ADS)

Feng, Changqing; Liu, Shubin; Zhang, Yunlong; Ma, Siyuan

2016-07-01

The DAMPE (DArk Matter Particle Explorer) is a scientific satellite which was successfully launched into a 500 Km sun-synchronous orbit, on December 17th, 2015, from the Jiuquan Satellite Launch Center of China. The major scientific objectives of the DAMPE mission are primary cosmic ray, gamma ray astronomy and dark matter particles, by observing high energy primary cosmic rays, especially positrons/electrons and gamma rays with an energy range from 5 GeV to 10 TeV. The BGO calorimeter is a critical sub-detector of DAMPE payload, for measuring the energy of cosmic particles, distinguishing positrons/electrons and gamma rays from hadron background, and providing trigger information. It utilizes 308 BGO (Bismuth Germanate Oxide) crystal logs with the size of 2.5cm*2.5cm*60cm for each log, to form a total absorption electromagnetic calorimeter. All the BGO logs are stacked in 14 layers, with each layer consisting of 22 BGO crystal logs and each log is viewed by two Hamamatsu R5610A PMTs (photomultiplier tubes), from both sides respectively. In order to achieve a large dynamic range, each PMT base incorporates a three dynode (2, 5, 8) pick off, which results in 616 PMTs and 1848 signal channels. The readout electronics system, which consists of 16 FEE (Front End Electronics) modules, was developed. Its main functions are based on the Flash-based FPGA (Field Programmable Gate Array) chip and low power, 32-channel VA160 and VATA160 ASICs (Application Specific Integrated Circuits) for precisely measuring the charge of PMT signals and providing "hit" signals as well. The hit signals are sent to the trigger module of PDPU (Payload Data Process Unit) and the hit rates of each layer is real-timely recorded by counters and packed into the engineering data, which directly reflect the flux of particles which fly into or pass through the detectors. In order to mitigate the SEU (Single Event Upset) effect in radioactive space environment, certain protecting methods, such as TMR (Triple Modular Redundancy) and CRC (Cyclic Redundancy Check) for some critical registers in FPGA logic was adopted. To mitigate the SEL (Single Event Latch-up) effect for the ASICs chips, a protecting solution by monitoring the current of VA160/VATA160 chips are applied. All the SEU and SEL events are recorded by counters and transmitted to ground station in the form of engineering data. The information of hit rates, and the SEU and SEL counters in the engineering data can be used to evaluate the radiation condition and its variations in DAMPE orbit. The preliminary results are introduced in this paper, which is based on the engineering data in the first six months after launching.

Delineation and hydrologic effects of a gasoline leak at Stovepipe Wells Hotel, Death Valley National Monument, California

USGS Publications Warehouse

Buono, A.; Packard, Elaine M.

1982-01-01

Ground water is the only local source of water available to the Stovepipe Wells Hotel facilities of the Death Valley National Monument, California. A leak in a service station storage tank caused the formation of a gasoline layer overlying the water table, creating the potential for contamination of the water supply. The maximum horizontal extent of the gasoline layer was mathematically estimated to be 1,300 feet downgradient from the leaky gasoline tank. Exploratory drilling detected the gasoline layer between 900 and 1,400 feet downgradient and between 50 and 150 feet upgradient from the source. Traces of the soluble components of gasoline were also found in the aquifer 150 feet upgradient, and 250 feet distant from the source perpendicular to the direction of ground-water movement. The gasoline spill is not likely to have an effect on the supply wells located 0.4 mile south of the leak source, which is nearly perpendicular to the direction of ground-water movement and the primary direction of gasoline movement in the area. No effect on phreatophytes 2 miles downgradient from the layer is likely, but the potential effects of gasoline vapors within the unsaturated zone on local xerophytes are not known. (USGS)

Effects of a dual-pump crude-oil recovery system, Bemidji, Minnesota, USA

USGS Publications Warehouse

Delin, Geoffrey N.; Herkelrath, William N.

2014-01-01

A crude-oil spill occurred in 1979 when a pipeline burst near Bemidji, MN. In 1998, the pipeline company installed a dual-pump recovery system designed to remove crude oil remaining in the subsurface at the site. The remediation from 1999 to 2003 resulted in removal of about 115,000 L of crude oil, representing between 36% and 41% of the volume of oil (280,000 to 316,000 L) estimated to be present in 1998. Effects of the 1999 to 2003 remediation on the dissolved plume were evaluated using measurements of oil thicknesses in wells plus measurements of dissolved oxygen in groundwater. Although the recovery system decreased oil thicknesses in the immediate vicinity of the remediation wells, average oil thicknesses measured in wells were largely unaffected. Dissolved-oxygen measurements indicate that a secondary plume was caused by disposal of the pumped water in an upgradient infiltration gallery; this plume expanded rapidly immediately following the start of the remediation in 1999. The result was expansion of the anoxic zone of groundwater upgradient and beneath the existing natural attenuation plume. Oil-phase recovery at this site was shown to be challenging, and considerable volumes of mobile and entrapped oil remain in the subsurface despite remediation efforts.

Phosphorus in a ground-water contaminant plume discharging to Ashumet Pond, Cape Cod, Massachusetts, 1999

USGS Publications Warehouse

McCobb, Timothy D.; LeBlanc, Denis R.; Walter, Donald A.; Hess, Kathryn M.; Kent, Douglas B.; Smith, Richard L.

2003-01-01

The discharge of a plume of sewagecontaminated ground water emanating from the Massachusetts Military Reservation to Ashumet Pond on Cape Cod, Massachusetts, has caused concern about excessive loading of nutrients, particularly phosphorus, to the pond. The U.S. Air Force is considering remedial actions to mitigate potentially adverse effects on the ecological characteristics of the pond from continued phosphorus loading. Concentrations as great as 3 milligrams per liter of dissolved phosphorus (as P) are in ground water near the pond's shoreline; concentrations greater than 5 milligrams per liter of phosphorus are in ground water farther upgradient. Temporary drive-point wells were used to collect water samples from 2 feet below the pond bottom to delineate concentration distributions in the pore waters of the pond-bottom sediments. Measurements in the field of specific conductance and colorimetrically determined orthophosphate concentrations provided real-time data to guide the sampling. The contaminant plume discharges to the Fishermans Cove area of Ashumet Pond as evidenced by elevated levels of specific conductance and boron, which are chemically conservative indicators of the sewage-contaminated ground water. Concentrations of nonconservative species, such as dissolved phosphorus, manganese, nitrate, and ammonium, also were elevated above background levels in ground water discharging to the pond, but in spatially complex distributions that reflect their distributions in ground water upgradient of the pond. Phosphorus concentrations exceeded background levels (greater than 0.10 milligram per liter) in the pond-bottom pore water along 875 feet of shoreline. Greatest concentrations (greater than 2 milligrams per liter) occurred within 30 feet of the shore in an area about 225 feet long. Calculations of phosphorus flux in the aquifer upgradient of Ashumet Pond, as determined from water-flux estimates from a steady-state ground-water-flow model and phosphorus concentrations (in 1999) from multilevel samplers about 75 feet upgradient of the pond, indicate that dissolved phosphorus moves towards the pond and discharges to it with the inflowing ground water at a rate as high as about 316 kilograms per year.

Installation and Implementation of a Comprehensive Groundwater Monitoring Program for the Indian Wells Valley, California

DTIC Science & Technology

2010-04-01

isotopes. Laboratory analysis for general chemistry included Na, Ca, Mg, K, Fe, Cl, HCO3, CO3 , SO4, F, B, NO3, arsenic (As), hardness, alkalinity...used for interpretations within the project. Prior to this effort, a single -location repository for isotopic data related to IWV investigations...canyons of importance to this study (Indian Wells Canyon, Freeman Canyon, and the upgradient canyons of Cow Haven, Sage, and Horse). Single samples

A BGO detector for Positron Emission Profiling in catalysts

NASA Astrophysics Data System (ADS)

Mangnus, A. V. G.; van Ijzendoorn, L. J.; de Goeij, J. J. M.; Cunningham, R. H.; van Santen, R. A.; de Voigt, M. J. A.

1995-05-01

As part of a project to study the reaction kinetics in catalysts, a detector system has been designed and built. The detector will measure in one dimension the activity distribution of positron emitters in catalyst reactors under operational conditions as a function of time. The detector consists of two arrays of ten BGO crystals each and has the flexibility to measure with high sensitivity the activity profile in various reactor sizes; the position resolution that can be reached is 3 mm.

Polarised Photon Beams for the BGO-OD Experiment at ELSA

NASA Astrophysics Data System (ADS)

Zimmermann, T.; Bella, A.; Alef, S.; Bayadilov, D.; Beck, R.; Becker, M.; Bielefeldt, P.; Boese, S.; Braghieri, A.; Brinkmann, K.; Cole, P.; Curciarello, F.; De Leo, V.; Di Salvo, R.; Dutz, H.; Elsner, D.; Fantini, A.; Freyermuth, O.; Friedrich, S.; Frommberger, F.; Ganenko, V.; Gervino, G.; Ghio, F.; Giardina, G.; Goertz, S.; Gridnev, A.; Gutz, E.; Hammann, D.; Hannappel, J.; Hartmann, P.; Hillert, W.; Ignatov, A.; Jahn, R.; Joosten, R.; Jude, T. C.; Klein, F.; Koop, K.; Krusche, B.; Lapik, A.; Levi Sandri, P.; Lopatin, I. V.; Mandaglio, G.; Messi, F.; Messi, R.; Metag, V.; Moricciani, D.; Mushkarenkov, A.; Nanova, M.; Nedorezov, V.; Novinskiy, D.; Pedroni, P.; Reitz, B.; Romaniuk, M.; Rostomyan, T.; Rudnev, N.; Schaerf, C.; Scheluchin, G.; Schmieden, H.; Stugelev, A.; Sumachev, V.; Tarakanov, V.; Vegna, V.; Walther, D.; Watts, D.; Zaunick, H.

The new BGO-OD experiment at the electron accelerator ELSA, of the University of Bonn, is designed to study the reaction dynamics of nucleon excitations in meson photoproduction. It consists of a central BGO calorimeter with a magnetic spectrometer in forward direction. The physics programme includes the measurement of polarisation observables using linearly and circularly polarised photon beams. Linear polarisation is obtained by coherent bremsstrahlung off a diamond crystal, and circular polarisation is obtained via bremsstrahlung from longitudinally polarised electrons. The degree of linear polarisation is determined from the bremsstrahlung spectrum itself. To determine the polarisation of the circularly polarised photon beam, the polarisation of the electron beam is measured by a Møller polarimeter. As a preliminary consistency check, the (linear) polarisation observable, Σ, was compared to world data for π0 and η photoproduction. To determine the degree of circular polarisation, a Møller polarimeter was setup and first measurements of the electron beam polarisation performed.

Temperature effects on MIPs in the BGO calorimeters of DAMPE

NASA Astrophysics Data System (ADS)

Wang, Yuan-Peng; Wen, Si-Cheng; Jiang, Wei; Yue, Chuan; Zhang, Zhi-Yong; Wei, Yi-Feng; Zhang, YunLong; Zang, Jing-Jing; Wu, Jian

2017-10-01

In this paper, we present a study of temperature effects on BGO calorimeters using proton MIPs collected in the first year of operation of DAMPE. By directly comparing MIP calibration constants used by the DAMPE data production pipe line, we find an experimental relation between the temperature and signal amplitudes of each BGO bar: a general deviation of -1.162%/°C, and -0.47%/°C to -1.60%/°C statistically for each detector element. During 2016, DAMPE’s temperature changed by ˜8°C due to solar elevation angle, and the corresponding energy scale bias is about 9%. By frequent MIP calibration operation, this kind of bias is eliminated to an acceptable value. This work was supported by National Key Program for Research and Development (No. 2016YFA0400200) and by NSFC (11303105, 11673021). The DAMPE mission was funded by the strategic priority science and technology projects in space science of the Chinese Academy of Sciences (No. XDA04040000 and No. XDA04040400)

Photofraction of a 5 cm x 2 cm BGO scintillator. [bismuth germanate crystal for use in cosmic gamma ray detector

NASA Technical Reports Server (NTRS)

Dunphy, P. P.; Forrest, D. J.

1985-01-01

The photofraction of a 5.1 cm x 2.0 cm bismuth germanate (BGO) scintillator was measured over a gamma-ray energy range of 0.2 to 6.1 MeV. Several methods, used to minimize the effect of room scattering on the measurement, are discussed. These include a gamma-gamma coincidence technique, a beta-gamma coincidence technique, and the use of sources calibrated with a standard 7.6 cm x 7.6 cm sodium iodide scintillator.

Hydrogeologic and water-quality data from well clusters near the wastewater-treatment plant, U.S. Marine Corps Air Station, Cherry Point, North Carolina

USGS Publications Warehouse

Murray, L.C.; Daniel, C. C.

1990-01-01

Hydrogeologic and ground-water quality data were collected near the wastewater-treatment plant and associated polishing lagoons at the Marine Corps Air Station, Cherry Point, North Carolina, in 1988. Between March and May 1988, two observation wells were installed upgradient and six wells were installed downgradient of the polishing lagoons and sampled for organic and inorganic U.S. Environmental Protection Agency priority pollutants. Placement of the well screens allowed sampling from both the upper and lower parts of the surficial aquifer. Natural gamma-ray geophysical logs were run in the four deepest wells. Lithologic logs were prepared from split-spoon samples collected during the drilling operations. Laboratory hydraulic conductivity tests were conducted on samples of fine-grained material recovered from the two confining units that separate the surficial aquifer and the drinking-water supply aquifer; values ranged from 0.011 to 0.014 foot per day (4x10-6 to 5x10-6 centimeters per second). Static water levels were recorded on April 25, 1988. Relatively low concentrations of purgeable organic compounds (up to 2.2 micrograms per liter for dichlorodifluoromethane), acid and base/neutral extractable compounds (up to 58 micrograms per liter for bis(2-ethylhexyl) phthalate), or pesticides (up to 0.03 micrograms per liter for diazinon and methyl parathion) were detected in water samples collected from all of the wells. Trace metals were detected in concentrations above minimum detectable limits in all of the wells and were found to be higher in water samples collected from the downgradient wells (up to 320 micrograms per liter for zinc) than in water samples from the upgradient wells.

Long-term performance monitoring for a permeable reactive barrier at the U.S. Coast Guard Support Center, Elizabeth City, North Carolina.

PubMed

Puls, R W; Blowes, D W; Gillham, R W

1999-08-12

A continuous hanging iron wall was installed in June, 1996, at the U. S. Coast Guard (USCG) Support Center near Elizabeth City, NC, United States, to treat overlapping plumes of chromate and chlorinated solvent compounds. The wall was emplaced using a continuous trenching machine whereby native soil and aquifer sediment was removed and the iron simultaneously emplaced in one continuous excavation and fill operation. To date, there have been seven rounds (November 1996, March 1997, June 1997, September 1997, December 1997, March 1998, and June 1998) of performance monitoring of the wall. At this time, this is the only full-scale continuous 'hanging' wall installed as a permeable reactive barrier to remediate both chlorinated solvent compounds and chromate in groundwater. Performance monitoring entails the following: sampling of 10-5 cm PVC compliance wells and 15 multi-level samplers for the following constituents: TCE, cis-dichloroethylene (c-DCE), vinyl chloride, ethane, ethene, acetylene, methane, major anions, metals, Cr(VI), Fe(II), total sulfides, dissolved H(2), Eh, pH, dissolved oxygen, specific conductance, alkalinity, and turbidity. Electrical conductivity profiles have been conducted using a Geoprobe to verify emplacement of the continuous wall as designed and to locate upgradient and downgradient wall interfaces for coring purposes. Coring has been conducted in November, 1996, in June and September, 1997, and March, 1998, to evaluate the rate of corrosion on the iron surfaces, precipitate buildup (particularly at the upgradient interface), and permeability changes due to wall emplacement. In addition to several continuous vertical cores, angled cores through the 0.6-m thick wall have been collected to capture upgradient and downgradient wall interfaces along approximate horizontal flow paths for mineralogic analyses.

Testing a prototype BGO calorimeter with 100-800 MeV positron beams

NASA Astrophysics Data System (ADS)

Ishikawa, T.; Fujimura, H.; Grigoriev, D. N.; Hashimoto, R.; Kaida, S.; Kitazawa, R.; Kuznetsov, G. N.; Nakamura, A.; Shimizu, H.; Suzuki, K.; Takahashi, S.; Tsuchikawa, Y.; Vasiliev, Ya. V.; Yamazaki, H.

2016-11-01

An electromagnetic calorimeter, BGOegg, composed of 1320 BGO crystals, has been constructed at the Research Center for Electron Photon Science, Tohoku University to study the structure of hadrons in detail using photo-induced reactions. The design of the new electromagnetic calorimeter and the basic characteristics of the manufactured BGO crystals are described. A performance test has been conducted for the prototype, which consists of 25 crystals arranged in a 5×5 matrix, using positron beams at energies ranging from 100 to 800 MeV. The obtained energy resolution is (σE / E) 2 =(0.63 %) 2 +(1.15 % ± 0.04 %) 2 /(E / GeV) +(0.42 % ± 0.03 %) 2 /(E / GeV) 2 at room temperature. The energy resolution corresponds to 1.38 % ± 0.05 % for 1-GeV positrons. The position resolution is found to be σr / mm =(3.07 ± 0.03)(E / GeV) - 0.202 ± 0.008 which corresponds to an angular resolution of approximately 1 ° for 1-GeV positrons.

Effects of dried wastewater-treatment sludge application on ground-water quality in South Dade County, Florida

USGS Publications Warehouse

Howie, Barbara

1992-01-01

Four test fields in the south Dade agricultural area were studied to determine the effects of sludge application on ground-water quality. Two fields had been cultivated for 10 years or more, and two had not been farmed for at least 10 years. The fields were representative of the area's two soil types (Rockdale and Perrine marl) and two major crop types (row crops and groves). Before the application of sludge, wells upgradient of, within, and downgradient of each field were sampled for possible sludge contaminants at the end of wet and dry seasons. Municipal wastewater treatment sludge from the Dade County Water and Sewe Authority Department was then applied to the fields at varying application rates. The wells at each field were sampled over a 2-year period under different hydrologic conditions for possible sludge-related constituents (specific conductance, pH, alkalinity, nitrogen, phosphorus, total organic carbon, copper, iron, magnesium, manganese, potassium, zinc, arsenic, cadmium, chloride, chromium, lead, mercury, nickel, and sodium). Comparisons were made between water quality in the vicinity of the test fields and Florida Department of Environmental Regulation primary and secondary drinking-water regulations, an between water quality upgradient of, beneath, and downgradient of the fields. Comparisons between presludge and postsludge water quality did not indicate any improvement because of retention of agrichemicals by the sludge nor did they indicate any deterioration because of leaching from the sludge. Comparisons of water quality upgradient of the fields to water quality beneath and downgradient of the fields also did not indicate any changes related to sludge. Florida Department of Environmental Regulation primary and secondary drinking-water regulations wer exceeded at the Rockdale maximum-application field by mercury (9.5 ug/L (micrograms per liter)), and the Perrine marl maximum-application field by manganese (60 ug/L) and lead (85 ug/L), and at the Perrine marl row-crop field by mercury (5.2 ug/L). All other exceedances were either in presludge or upgradient samples, or they were for constituents or properties, such as iron and color, which typically exceed standards in native ground water. Acid-extractable and base-neutral compounds, volatile organic compounds, chlorophenoxy herbicides, organophosphorus insecticides, and organochlorine compounds were analyzed for one shallow well at each field twice annually. Those compounds that equaled or exceeded the detection limit after sludge was applied included benzene (0.3 and 1.2 ug/L), chloroform (0.2 and 0.3 ug/L), bis(2-Ethylhexyl)phthalate (29 and 42 ug/L), methylene chloride (14 ug/L), tolulene (0.2, 0.4, 0.5, 1.3, and 4.4 ug/L), 1, 1,1-trichloroethana (0.6 ug/L), trichloroethylene (0.3 ug/L), 2.4-D (0.01 ug/L), and xylene (0.3 ug/L). It ws not possible to ascertain the origin of these compounds becuase they are available from sources other than sludge.

DOE Office of Scientific and Technical Information (OSTI.GOV)

James, S St.; Argento, D; Stewart, R

Purpose: The University of Washington Medical Center offers neutron therapy for the palliative and definitive treatment of selected cancers. In vivo field verification has the potential to improve the safe and effective delivery of neutron therapy. We propose a portal imaging method that relies on the creation of positron emitting isotopes (11C and 15O) through (n, 2n) reactions with a PMMA plate placed below the patient. After field delivery, the plate is retrieved from the vault and imaged using a reader that detects annihilation photons. The spatial pattern of activity produced in the PMMA plate provides information to reconstruct themore » neutron fluence map needed to confirm treatment delivery. Methods: We used MCNP to simulate the accumulation of 11C activity in a slab of PMMA 2 mm thick, and GATE was used to simulate the sensitivity and spatial resolution of a prototype imaging system. BGO crystal thicknesses of 1 cm, 2 cm and 3 cm were simulated with detector separations of 2 cm. Crystal pitches of 2 mm and 4 mm were evaluated. Back-projection of the events was used to create a planar image. The spatial resolution was taken to be the FWHM of the reconstructed point source image. Results: The system sensitivity for a point source in the center of the field of view was found to range from 58% for 1 cm thick BGO with 2 mm crystal pitch to 74% for the 3 cm thick BGO crystals with 4 mm crystal pitch. The spatial resolution at the center of the field of view was found to be 1.5 mm for the system with 2 mm crystal pitch and 2.8 mm for the system with the 4 mm crystal pitch. Conclusion: BGO crystals with 4 mm crystal pitch and 3 cm length would offer the best sensitivity reader.« less

Development of signal processing system of avalanche photo diode for space observations by Astro-H

NASA Astrophysics Data System (ADS)

Ohno, M.; Goto, K.; Hanabata, Y.; Takahashi, H.; Fukazawa, Y.; Yoshino, M.; Saito, T.; Nakamori, T.; Kataoka, J.; Sasano, M.; Torii, S.; Uchiyama, H.; Nakazawa, K.; Watanabe, S.; Kokubun, M.; Ohta, M.; Sato, T.; Takahashi, T.; Tajima, H.

2013-01-01

Astro-H is the sixth Japanese X-ray space observatory which will be launched in 2014. Two of onboard instruments of Astro-H, Hard X-ray Imager and Soft Gamma-ray Detector are surrounded by many number of large Bismuth Germanate (Bi4Ge3O12; BGO) scintillators. Optimum readout system of scintillation lights from these BGOs are essential to reduce the background signals and achieve high performance for main detectors because most of gamma-rays from out of field-of-view of main detectors or radio-isotopes produced inside them due to activation can be eliminated by anti-coincidence technique using BGO signals. We apply Avalanche Photo Diode (APD) for light sensor of these BGO detectors since their compactness and high quantum efficiency make it easy to design such large number of BGO detector system. For signal processing from APDs, digital filter and other trigger logics on the Field-Programmable Gate Array (FPGA) is used instead of discrete analog circuits due to limitation of circuit implementation area on spacecraft. For efficient observations, we have to achieve as low threshold of anti-coincidence signal as possible by utilizing the digital filtering. In addition, such anti-coincident signals should be sent to the main detector within 5 μs to make it in time to veto the A-D conversion. Considering this requirement and constraint from logic size of FPGA, we adopt two types of filter, 8 delay taps filter with only 2 bit precision coefficient and 16 delay taps filter with 8 bit precision coefficient. The data after former simple filter provides anti-coincidence signal quickly in orbit, and the latter filter is used for detail analysis after the data is down-linked.

Water-quality reconnaissance of the north Dade County solid-waste facility, Florida

USGS Publications Warehouse

McKenzie, D.J.

1982-01-01

A water-quality sampling reconnaissance of the north Dade County solid-waste disposal facility (landfill) near Carol City, Florida, was conducted during 1977-78. The purpose of the reconnaissance was to determine selected quality characteristics of the surface- and ground-water of the landfill and contiguous area; and to assess, generally, if leachate produced by the decomposition of landfill wastes was adversely impacting the downgradient water quality. Sampling results indicated that several water-quality characteristics were present in landfill ground water at significantly higher levels than in ground water upgradient or downgradient from the landfill. Moreover, many of these water-quality characteristics were found at slightly higher levels at down gradient site 5 than at upgradient site 1 which suggested that some downgradient movement of landfill leachate had occurred. For example, chloride and alkalinity in ground water had average concentrations of 20 and 290 mg/L at background wells (site 1), 144 and 610 mg/L at landfill wells (sites 2 and 4), and 29 and 338 mg/L at downgradient wells (site 5). A comparison of the 1977-78 sampling results with the National Primary and Secondary Drinking Water Regulations indicated that levels of iron and color in ground water of the study area frequently exceeded national maximum contaminant levels, dissolved solids, turbidity, lead, and manganese occasionally exceeded regulations. Concentrations of iron and levels of color and turbidity in some surface water samples also exceeded National maximum contaminant levels. (USGS)

Terrestrial Gamma Flashes at Ground Level - TETRA-II Instrumentation

NASA Astrophysics Data System (ADS)

Pleshinger, D. J.; Adams, C.; Al-Nussirat, S.; Bai, S.; Banadaki, Y.; Bitzer, P. M.; Cherry, M. L.; Hoffmann, J.; Khosravi, E.; Legault, M.; Orang, M.; Rodriguez, R.; Smith, D.; Trepanier, J. C.; Sunda-Meya, A.; Zimmer, N.

2017-12-01

The TGF and Energetic Thunderstorm Rooftop Array (TETRA-II) consists of an array of BGO scintillators to detect bursts of gamma rays from thunderstorms. TETRA-II will have approximately an order of magnitude greater sensitivity for individual flashes than TETRA-I, an original array of NaI scintillators at Louisiana State University that detected 37 millisecond-scale bursts of gamma rays from 2010-2015. The BGO scintillators increase the energy range of particles detected to 10 MeV and are placed in 20 detectors boxes, each with 1180 cm3 of BGO, at 4 separate locations: the campus of Louisiana State University in Baton Rouge, Louisiana; the campus of the University of Puerto Rico at Utuado, Puerto Rico; the Centro Nacional de Metrologia de Panama (CENAMEP) in Panama City, Panama; and the Severe Weather Institute and Radar & Lightning Laboratories in Huntsville, Alabama. The data are read out with 12 microsecond resolution by National Instruments PCIe 6351 high speed data acquisition cards, with timestamps determined from a 20 MHz clock and a GPS board recording a pulse per second. Details of the array and its instrumentation, along with an overview of initial results, will be presented.

Material efficiency studies for a Compton camera designed to measure characteristic prompt gamma rays emitted during proton beam radiotherapy

PubMed Central

Robertson, Daniel; Polf, Jerimy C; Peterson, Steve W; Gillin, Michael T; Beddar, Sam

2011-01-01

Prompt gamma rays emitted from biological tissues during proton irradiation carry dosimetric and spectroscopic information that can assist with treatment verification and provide an indication of the biological response of the irradiated tissues. Compton cameras are capable of determining the origin and energy of gamma rays. However, prompt gamma monitoring during proton therapy requires new Compton camera designs that perform well at the high gamma energies produced when tissues are bombarded with therapeutic protons. In this study we optimize the materials and geometry of a three-stage Compton camera for prompt gamma detection and calculate the theoretical efficiency of such a detector. The materials evaluated in this study include germanium, bismuth germanate (BGO), NaI, xenon, silicon and lanthanum bromide (LaBr3). For each material, the dimensions of each detector stage were optimized to produce the maximum number of relevant interactions. These results were used to predict the efficiency of various multi-material cameras. The theoretical detection efficiencies of the most promising multi-material cameras were then calculated for the photons emitted from a tissue-equivalent phantom irradiated by therapeutic proton beams ranging from 50 to 250 MeV. The optimized detector stages had a lateral extent of 10 × 10 cm2 with the thickness of the initial two stages dependent on the detector material. The thickness of the third stage was fixed at 10 cm regardless of material. The most efficient single-material cameras were composed of germanium (3 cm) and BGO (2.5 cm). These cameras exhibited efficiencies of 1.15 × 10−4 and 9.58 × 10−5 per incident proton, respectively. The most efficient multi-material camera design consisted of two initial stages of germanium (3 cm) and a final stage of BGO, resulting in a theoretical efficiency of 1.26 × 10−4 per incident proton. PMID:21508442

Effects of irrigating with wastewater on ground-water quality at Fort Carson Military Reservation golf course near Colorado Springs, Colorado

USGS Publications Warehouse

Edelmann, Patrick

1984-01-01

Fort Carson Military Reservation has used treatment wastewater for irrigation of the Fort Carson golf course since 1971. The effect of applied wastewater on groundwater quality at Fort Carson golf course was evaluated using water levels and water-quality data from 20 observation wells. The water-quality constituents analyzed included dissolved solids, major ions, nutrients, detergents, dissolved organic carbon, chemical and biological oxygen demand, and trace elements. Effects of the applied wastewater on ground-water quality for most constituents were obscured by large areal variations and by high concentrations of the constituents upgradient from the golf course. The sources of nitrogen observed in the ground water beneath the golf course were applied wastewater, applied fertilizer, leachate from the organic-rich shale, and from unknown upgradient sources. Nitrogen loading at the golf course from wastewater and applied fertilizer was estimated to be 18 ,900 pounds per year. After 10 years, less than 1 percent of the nitrogen applied was actually present in the ground water. Loss of nitrogen to the atmosphere as nitrous oxides, absorption, and to fixation by grass resulted in the much smaller concentrations observed in the ground water. (USGS)

The combined use of 87Sr/86Sr and carbon and water isotopes to study the hydrochemical interaction between groundwater and lakewater in mantled karst

USGS Publications Warehouse

Katz, B.G.; Bullen, T.D.

1996-01-01

The hydrochemical interaction between groundwater and lakewater influences the composition of water that percolates downward from the surficial aquifer system through the underlying intermediate confining unit and recharges the Upper Floridan aquifer along highlands in Florida. The 87Sr/86Sr ratio along with the stable isotopes, D, 18O, and 13C were used as tracers to study the interaction between groundwater, lakewater, and aquifer minerals near Lake Barco, a seepage lake in the mantled karst terrane of northern Florida. Upgradient from the lake, the 87Sr/86Sr ratio of groundwater decreases with depth (mean values of 0.71004, 0.70890, and 0.70852 for water from the surficial aquifer system, intermediate confining unit, and Upper Floridan aquifer, respectively), resulting from the interaction of dilute oxygenated recharge water with aquifer minerals that are less radiogenic with depth. The concentrations of Sr2+ generally increase with depth, and higher concentrations of Sr2+ in water from the Upper Floridan aquifer (20-35 ??g/L), relative to water from the surficial aquifer system and the intermediate confining unit, result from the dissolution of Sr-bearing calcite and dolomite in the Eocene limestone. Dissolution of calcite [??13C = -1.6 permil (???)] is also indicated by an enriched ??13CDIC (-8.8 to - 11.4???) in water from the Upper Floridan aquifer, relative to the overlying hydrogeologic units (??13CDIC < - 16???). Groundwater downgradient from Lake Barco was enriched in 18O and D relative to groundwater upgradient from the lake, indicating mixing of lakewater leakage and groundwater. Downgradient from the lake, the 87Sr/86Sr ratio of groundwater and aquifer material become less radiogenic and the Sr2+ concentrations generally increase with depth. However, Sr2+ concentrations are substantially less than in upgradient groundwaters at similar depths. The lower Sr2+ concentrations result from the influence of anoxic lakewater leakage on the mobility of Sr2+ from clays. Based on results from mass-balance modeling, it is probable that cation exchange plays the dominant role in controlling the 87Sr/86Sr ratio of groundwater, both upgradient and downgradient from Lake Barco. Even though groundwater from the three distinct hydrogeologic units displays considerable variability in Sr concentration and isotopic composition, the dominant processes associated with the mixing of lakewater leakage with groundwater, as well as the effects of mineral-water interaction, can be ascertained by integrating the use of stable and radiogenic isotopic measurements of groundwater, lakewater, and aquifer minerals.

Annual Report of the Secretary of Defense to the President and the Congress, January 1994

DTIC Science & Technology

1994-01-01

latftoirm. This iJl id-..s such basic ,,SC-vice.,S as voice, video , data, imagery, and graphics transmission, as well as organi/.ational and individual...messaging, video -teleconferencing, and electronic data interchange. Overarchin e the system are standardization, security, and technology insertion...WTli (’ pedo shldlow watecr upgradiing, and improvements to the Standoffl’Lind Attatck Missile for1 stI~ke’-IL’IlCer ai ra iit. NAVAL. AVIATION

Hydraulic and geochemical performance of a permeable reactive barrier containing zero-valent iron, Denver Federal Center

USGS Publications Warehouse

McMahon, P.B.; Dennehy, K.F.; Sandstrom, M.W.

1999-01-01

The hydraulic and geochemical performance of a 366 m long permeable reactive barrier (PRB) at the Denver Federal Center; Denver, Colorado, was evaluated. The funnel and gate system, which was installed in 1996 to intercept and remediate ground water contaminated with chlorinated aliphatic hydrocarbons (CAHs), contained four 12.2 m wide gates filled with zero-valent iron. Ground water mounding on the upgradient side of the PRB resulted in a tenfold increase in the hydraulic gradient and ground water velocity through the gates compared to areas of the aquifer unaffected by the PRB. Water balance calculations for April 1997 indicate that about 75% of the ground water moving toward the PRB from upgradient areas moved through the gates. The rest of the water either accumulated on the upgradient side of the PRB or bypassed the PRB. Chemical data from monitoring wells screened down-gradient, beneath, and at the ends of the PRB indicate that contaminants had not bypassed the PRB, except in a few isolated areas. Greater than 99% of the CAH mass entering the gates was retained by the iron. Fifty-one percent of the CAH carbon entering one gate was accounted for in dissolved C1 and C2 hydrocarbons, primarily ethane and ethene, which indicates that CAHs may adsorb to the iron prior to being dehalogenated. Treated water exiting the gates displaced contaminated ground water at a distance of at least 3 m downgradient from the PRB by the end of 1997. Measurements of dissolved inorganic ions in one gate indicate that calcite and siderite precipitation in the gate could reduce gate porosity by about 0.35% per year. Results from this study indicate that funnel and gate systems containing zero-valent iron can effectively treat ground water contaminated with CAHs. However, the hydrologic impacts of the PRB on the flow system need to be fully understood to prevent contaminants from bypassing the PRB.

GEANT4 Simulation of Neutron Detector for DAMPE

NASA Astrophysics Data System (ADS)

Ming, He; Tao, Ma; Jin, Chang; Yan, Zhang; Yong-yi, Huang; Jing-jing, Zang; Jian, Wu; Tie-kuang, Dong

2016-10-01

In recent decades, dark matter has gradually become a hot topic in astronomical research, and the related theoretical research and experimental project are updated with each passing day. The Dark Matter Particle Explorer (DAMPE) of our country was proposed under this background. As the detected object involves high-energy electrons, appropriate methods must be taken to distinguish them from protons, in order to reduce the event probability of other charged particles (for example protons) being mistaken as electrons. The experiments show that the hadron shower of high-energy proton in BGO (Bismuth Germanium Oxide) calorimeter, which is usually accompanied with the emitting of a large number of secondary neutrons, is significantly different from the electromagnetic shower of high-energy electron. Through the detection of secondary neutron signals emerging from the bottom of BGO calorimeter, and the shower shape of incident particles in the BGO calorimeter, we can effectively distinguish whether the incident particles are high-energy protons or electrons. This paper introduces the structure and detection principle of the DAMPE neutron detector. We use the Monte-Carlo method and the GEANT4 software to simulate the signals produced by protons and electrons at the characteristic energy in the neutron detector, and finally summarize the neutron detector's ability to distinguish protons and electrons under different electron acceptabilities.

GEANT4 Simulation of Neutron Detector for DAMPE

NASA Astrophysics Data System (ADS)

He, M.; Ma, T.; Chang, J.; Zhang, Y.; Huang, Y. Y.; Zang, J. J.; Wu, J.; Dong, T. K.

2016-01-01

During recent tens of years dark matter has gradually become a hot topic in astronomical research field, and related theory researches and experiment projects change with each passing day. The Dark Matter Particle Explorer (DAMPE) of our country is proposed under this background. As the probing object involves high energy electrons, appropriate methods must be taken to distinguish them from protons in order to reduce the event probability of other charged particles (e.g. a proton) being mistaken as electrons. The experiments show that, the hadronic shower of high energy proton in BGO electromagnetic calorimeter, which is usually accompanied by the emitting of large number of secondary neutrons, is significantly different from the electromagnetic shower of high energy electron. Through the detection of secondary neutron signal emitting from the bottom of BGO electromagnetic calorimeter and the shower shape of incident particles in BGO electromagnetic calorimeter, we can effectively distinguish whether the incident particles are high energy protons or electrons. This paper introduces the structure and detecting principle of DAMPE neutron detector. We use Monte-Carlo method with GEANT4 software to simulate the signal emitting from protons and electrons at characteristic energy in the neutron detector, and finally summarize the neutron detector's ability to distinguish protons and electrons under different electron acception efficiencies.

Improved proton CT imaging using a bismuth germanium oxide scintillator.

PubMed

Tanaka, Sodai; Nishio, Teiji; Tsuneda, Masato; Matsushita, Keiichiro; Kabuki, Shigeto; Uesaka, Mitsuru

2018-02-02

Range uncertainty is among the most formidable challenges associated with the treatment planning of proton therapy. Proton imaging, which includes proton radiography and proton computed tomography (pCT), is a useful verification tool. We have developed a pCT detection system that uses a thick bismuth germanium oxide (BGO) scintillator and a CCD camera. The current method is based on a previous detection system that used a plastic scintillator, and implements improved image processing techniques. In the new system, the scintillation light intensity is integrated along the proton beam path by the BGO scintillator, and acquired as a two-dimensional distribution with the CCD camera. The range of a penetrating proton is derived from the integrated light intensity using a light-to-range conversion table, and a pCT image can be reconstructed. The proton range in the BGO scintillator is shorter than in the plastic scintillator, so errors due to extended proton ranges can be reduced. To demonstrate the feasibility of the pCT system, an experiment was performed using a 70 MeV proton beam created by the AVF930 cyclotron at the National Institute of Radiological Sciences. The accuracy of the light-to-range conversion table, which is susceptible to errors due to its spatial dependence, was investigated, and the errors in the acquired pixel values were less than 0.5 mm. Images of various materials were acquired, and the pixel-value errors were within 3.1%, which represents an improvement over previous results. We also obtained a pCT image of an edible chicken piece, the first of its kind for a biological material, and internal structures approximately one millimeter in size were clearly observed. This pCT imaging system is fast and simple, and based on these findings, we anticipate that we can acquire 200 MeV pCT images using the BGO scintillator system.

Improved proton CT imaging using a bismuth germanium oxide scintillator

NASA Astrophysics Data System (ADS)

Tanaka, Sodai; Nishio, Teiji; Tsuneda, Masato; Matsushita, Keiichiro; Kabuki, Shigeto; Uesaka, Mitsuru

2018-02-01

Range uncertainty is among the most formidable challenges associated with the treatment planning of proton therapy. Proton imaging, which includes proton radiography and proton computed tomography (pCT), is a useful verification tool. We have developed a pCT detection system that uses a thick bismuth germanium oxide (BGO) scintillator and a CCD camera. The current method is based on a previous detection system that used a plastic scintillator, and implements improved image processing techniques. In the new system, the scintillation light intensity is integrated along the proton beam path by the BGO scintillator, and acquired as a two-dimensional distribution with the CCD camera. The range of a penetrating proton is derived from the integrated light intensity using a light-to-range conversion table, and a pCT image can be reconstructed. The proton range in the BGO scintillator is shorter than in the plastic scintillator, so errors due to extended proton ranges can be reduced. To demonstrate the feasibility of the pCT system, an experiment was performed using a 70 MeV proton beam created by the AVF930 cyclotron at the National Institute of Radiological Sciences. The accuracy of the light-to-range conversion table, which is susceptible to errors due to its spatial dependence, was investigated, and the errors in the acquired pixel values were less than 0.5 mm. Images of various materials were acquired, and the pixel-value errors were within 3.1%, which represents an improvement over previous results. We also obtained a pCT image of an edible chicken piece, the first of its kind for a biological material, and internal structures approximately one millimeter in size were clearly observed. This pCT imaging system is fast and simple, and based on these findings, we anticipate that we can acquire 200 MeV pCT images using the BGO scintillator system.

Highly improved operation of monolithic BGO-PET blocks

NASA Astrophysics Data System (ADS)

Gonzalez-Montoro, A.; Sanchez, F.; Majewski, S.; Zanettini, S.; Benlloch, J. M.; Gonzalez, A. J.

2017-11-01

In PET scanners both scintillation crystals and photosensors are key components defining the system's performance and cost. Original PET systems used BGO or NaI(Tl) scintillators but achieved limited performance due to its slow decay and relatively low light output. Moreover, NaI(Tl) has low stopping power for 511 keV annihilation photons. In this study we report the possibility to reintroduce BGO crystals, and in particular in the form of monolithic blocks, especially suitable for low-dose large-size PET scanners, offering significantly improved sensitivity at a highly reduced cost compared to LYSO type fast scintillators. We have studied the performance of a monolithic BGO block as large as 50 × 50 × 15 mm3 with black-painted lateral walls to reduce lights spread, enabling accurate photon depth of interaction (DOI) measurements. A directional optical layer, called retro-reflector, was coupled to the entrance face bouncing back the scintillation light in the direction of the emission source and, therefore, adding to the light signal while preserving the narrow light cone distribution. Four configurations namely 12 × 12 and 16 × 16 SiPM arrays (3 mm × 3 mm each) as photosensors, with or without a nanopattern treatment at the crystal exit face, have been studied. This structure consisted of a thin layer of a specific high refractive index material shaped with a periodic nanopattern, increasing the scintillation light extraction. The readout returned information for each SiPM row and column, characterizing the X-Y light distribution projections. We have studied the detector spatial resolution using collimated 22Na sources at normal incidence. The DOI resolution was evaluated using collimated gamma beams with lateral incidence. The overall best detector performance was obtained for the 16× 16 SiPM array offering higher readout granularity. We have determined the spatial resolution for 3 separated DOI layers, obtaining the best results for the DOI region near to the photosensor.

Development of a Compton camera for medical applications based on silicon strip and scintillation detectors

NASA Astrophysics Data System (ADS)

Krimmer, J.; Ley, J.-L.; Abellan, C.; Cachemiche, J.-P.; Caponetto, L.; Chen, X.; Dahoumane, M.; Dauvergne, D.; Freud, N.; Joly, B.; Lambert, D.; Lestand, L.; Létang, J. M.; Magne, M.; Mathez, H.; Maxim, V.; Montarou, G.; Morel, C.; Pinto, M.; Ray, C.; Reithinger, V.; Testa, E.; Zoccarato, Y.

2015-07-01

A Compton camera is being developed for the purpose of ion-range monitoring during hadrontherapy via the detection of prompt-gamma rays. The system consists of a scintillating fiber beam tagging hodoscope, a stack of double sided silicon strip detectors (90×90×2 mm3, 2×64 strips) as scatter detectors, as well as bismuth germanate (BGO) scintillation detectors (38×35×30 mm3, 100 blocks) as absorbers. The individual components will be described, together with the status of their characterization.

Design Study of the Absorber Detector of a Compton Camera for On-Line Control in Ion Beam Therapy

NASA Astrophysics Data System (ADS)

Richard, M.-H.; Dahoumane, M.; Dauvergne, D.; De Rydt, M.; Dedes, G.; Freud, N.; Krimmer, J.; Letang, J. M.; Lojacono, X.; Maxim, V.; Montarou, G.; Ray, C.; Roellinghoff, F.; Testa, E.; Walenta, A. H.

2012-10-01

The goal of this study is to tune the design of the absorber detector of a Compton camera for prompt γ-ray imaging during ion beam therapy. The response of the Compton camera to a photon point source with a realistic energy spectrum (corresponding to the prompt γ-ray spectrum emitted during the carbon irradiation of a water phantom) is studied by means of Geant4 simulations. Our Compton camera consists of a stack of 2 mm thick silicon strip detectors as a scatter detector and of a scintillator plate as an absorber detector. Four scintillators are considered: LYSO, NaI, LaBr3 and BGO. LYSO and BGO appear as the most suitable materials, due to their high photo-electric cross-sections, which leads to a high percentage of fully absorbed photons. Depth-of-interaction measurements are shown to have limited influence on the spatial resolution of the camera. In our case, the thickness which gives the best compromise between a high percentage of photons that are fully absorbed and a low parallax error is about 4 cm for the LYSO detector and 4.5 cm for the BGO detector. The influence of the width of the absorber detector on the spatial resolution is not very pronounced as long as it is lower than 30 cm.

Single event effect hardness for the front-end ASICs in the DAMPE satellite BGO calorimeter

NASA Astrophysics Data System (ADS)

Gao, Shan-Shan; Jiang, Di; Feng, Chang-Qing; Xi, Kai; Liu, Shu-Bin; An, Qi

2016-01-01

The Dark Matter Particle Explorer (DAMPE) is a Chinese scientific satellite designed for cosmic ray studies with a primary scientific goal of indirect detection of dark matter particles. As a crucial sub-detector, the BGO calorimeter measures the energy spectrum of cosmic rays in the energy range from 5 GeV to 10 TeV. In order to implement high-density front-end electronics (FEE) with the ability to measure 1848 signals from 616 photomultiplier tubes on the strictly constrained satellite platform, two kinds of 32-channel front-end ASICs, VA160 and VATA160, are customized. However, a space mission period of more than 3 years makes single event effects (SEEs) become threats to reliability. In order to evaluate SEE sensitivities of these chips and verify the effectiveness of mitigation methods, a series of laser-induced and heavy ion-induced SEE tests were performed. Benefiting from the single event latch-up (SEL) protection circuit for power supply, the triple module redundancy (TMR) technology for the configuration registers and the optimized sequential design for the data acquisition process, 52 VA160 chips and 32 VATA160 chips have been applied in the flight model of the BGO calorimeter with radiation hardness assurance. Supported by Strategic Priority Research Program on Space Science of the Chinese Academy of Sciences (XDA04040202-4) and Fundamental Research Funds for the Central Universities (WK2030040048)

The combined use of 87Sr/86Sr and carbon and water isotopes to study the hydrochemical interaction between groundwater and lakewater in mantled karst

NASA Astrophysics Data System (ADS)

Katz, Brian G.; Bullen, Thomas D.

1996-12-01

The hydrochemical interaction between groundwater and lakewater influences the composition of water that percolates downward from the surficial aquifer system through the underlying intermediate confining unit and recharges the Upper Floridan aquifer along highlands in Florida. The 87Sr/86Sr ratio along with the stable isotopes, D, 18O, and 13C were used as tracers to study the interaction between groundwater, lakewater, and aquifer minerals near Lake Barco, a seepage lake in the mantled karst terrane of northern Florida. Upgradient from the lake, the 87Sr/86Sr ratio of groundwater decreases with depth (mean values of 0.71004, 0.70890, and 0.70852 for water from the surficial aquifer system, intermediate confining unit, and Upper Floridan aquifer, respectively), resulting from the interaction of dilute oxygenated recharge water with aquifer minerals that are less radiogenic with depth. The concentrations of Sr2+ generally increase with depth, and higher concentrations of Sr2+ in water from the Upper Floridan aquifer (20-35 μg/L), relative to water from the surficial aquifer system and the intermediate confining unit, result from the dissolution of Sr-bearing calcite and dolomite in the Eocene limestone. Dissolution of calcite [δ13C= -1.6permil(‰)] is also indicated by an enriched δ13CDIC(-8.8 to -11.4 ‰) in water from the Upper Floridan aquifer, relative to the overlying hydrogeologic units (δ13CDIC< -16‰). Groundwater downgradient from Lake Barco was enriched in18O and D relative to groundwater upgradient from the lake, indicating mixing of lakewater leakage and groundwater. Downgradient from the lake, the 87Sr/86Sr ratio of groundwater and aquifer material become less radiogenic and the Sr2+ concentrations generally increase with depth. However, Sr2+ concentrations are substantially less than in upgradient groundwaters at similar depths. The lower Sr2+ concentrations result from the influence of anoxic lakewater leakage on the mobility of Sr2+ from clays. Based on results from mass-balance modeling, it is probable that cation exchange plays the dominant role in controlling the 87Sr/86Sr ratio of groundwater, both upgradient and downgradient from Lake Barco. Even though groundwater from the three distinct hydrogeologic units displays considerable variability in Sr concentration and isotopic composition, the dominant processes associated with the mixing of lakewater leakage with groundwater, as well as the effects of mineral-water interaction, can be ascertained by integrating the use of stable and radiogenic isotopic measurements of groundwater, lakewater, and aquifer minerals.

Intrinsic light yield and light loss coefficient of Bi4Ge3O12 single crystals

NASA Astrophysics Data System (ADS)

Yawai, Nattasuda; Chewpraditkul, Weerapong; Wanarak, Chalerm; Nikl, Martin; Ratanatongchai, Wichian

2014-10-01

In this paper we present the scintillation properties of polished Bi4Ge3O12 (BGO) crystals grown by the Bridgman method. The light yield (LY) and energy resolution were measured using XP5200B photomultiplier. At 662 keV γ-rays, high LY of 9680 photons/MeV and good energy resolution of 8.6% were obtained for a 5 × 5 × 1 mm3 BGO sample. The intrinsic LY and light loss coefficient were evaluated. The photofraction in pulse height spectrum of 662 keV γ-rays and the mass attenuation coefficient at 59.5 and 662 keV γ-rays were also determined and compared with the theoretical ones calculated using the WinXCom program.

A multi-channel setup to study fractures in scintillators

NASA Astrophysics Data System (ADS)

Tantot, A.; Bouard, C.; Briche, R.; Lefèvre, G.; Manier, B.; Zaïm, N.; Deschanel, S.; Vanel, L.; Di Stefano, P. C. F.

2016-12-01

To investigate fractoluminescence in scintillating crystals used for particle detection, we have developed a multi-channel setup built around samples of double-cleavage drilled compression (DCDC) geometry in a controllable atmosphere. The setup allows the continuous digitization over hours of various parameters, including the applied load, and the compressive strain of the sample, as well as the acoustic emission. Emitted visible light is recorded with nanosecond resolution, and crack propagation is monitored using infrared lighting and camera. An example of application to \\text{B}{{\\text{i}}4}\\text{G}{{\\text{e}}3}{{\\text{O}}12} (BGO) is provided.

High energy resolution plastic scintillator

NASA Astrophysics Data System (ADS)

van Loef, Edgar V.; Feng, Patrick; Markosyan, Gary; Shirwadkar, Urmila; Doty, Patrick; Shah, Kanai S.

2016-09-01

In this paper we present results on a novel tin-loaded plastic scintillator. We will show that this particular plastic scintillator has a light output similar to that of BGO, a fast scintillation decay (< 10 ns), exhibits good neutron/gamma PSD with a Figure-of-Merit of 1.3 at 2.5 MeVee cut-off energy, and excellent energy resolution of about 12% (FWHM) at 662 keV. Under X-ray excitation, the radioluminescence spectrum exhibits a broad band between 350 and 500 nm peaking at 420 nm which is well-matched to bialkali photomultiplier tubes and UV-enhanced photodiodes.

Development and verification of signal processing system of avalanche photo diode for the active shields onboard ASTRO-H

NASA Astrophysics Data System (ADS)

Ohno, M.; Kawano, T.; Edahiro, I.; Shirakawa, H.; Ohashi, N.; Okada, C.; Habata, S.; Katsuta, J.; Tanaka, Y.; Takahashi, H.; Mizuno, T.; Fukazawa, Y.; Murakami, H.; Kobayashi, S.; Miyake, K.; Ono, K.; Kato, Y.; Furuta, Y.; Murota, Y.; Okuda, K.; Wada, Y.; Nakazawa, K.; Mimura, T.; Kataoka, J.; Ichinohe, Y.; Uchida, Y.; Katsuragawa, M.; Yoneda, H.; Sato, G.; Sato, R.; Kawaharada, M.; Harayama, A.; Odaka, H.; Hayashi, K.; Ohta, M.; Watanabe, S.; Kokubun, M.; Takahashi, T.; Takeda, S.; Kinoshita, M.; Yamaoka, K.; Tajima, H.; Yatsu, Y.; Uchiyama, H.; Saito, S.; Yuasa, T.; Makishima, K.; ASTRO-H HXI/SGD Team

2016-09-01

The hard X-ray Imager and Soft Gamma-ray Detector onboard ASTRO-H demonstrate high sensitivity to hard X-ray (5-80 keV) and soft gamma-rays (60-600 keV), respectively. To reduce the background, both instruments are actively shielded by large, thick Bismuth Germanate scintillators. We have developed the signal processing system of the avalanche photodiode in the BGO active shields and have demonstrated its effectiveness after assembly in the flight model of the HXI/SGD sensor and after integration into the satellite. The energy threshold achieved is about 150 keV and anti-coincidence efficiency for cosmic-ray events is almost 100%. Installed in the BGO active shield, the developed signal processing system successfully reduces the room background level of the main detector.

Expected radiation damage of reverse-type APDs for the Astro-H mission

NASA Astrophysics Data System (ADS)

Kataoka, J.; Saito, T.; Yoshino, M.; Mizoma, H.; Nakamori, T.; Yatsu, Y.; Ishikawa, Y.; Matsunaga, Y.; Tajima, H.; Kokubun, M.; Edwards, P. G.

2012-06-01

Scheduled for launch in 2014, Astro-H is the sixth Japanese X-ray astronomy satellite mission. More than 60 silicon avalanche photodiodes (Si-APDs; hereafter APDs) will be used to read out BGO scintillators, which are implemented to generate a veto signal to reduce background contamination for the hard X-ray imager (HXI) and a soft gamma-ray detector (SGD). To date, however, APDs have rarely been used in space experiments. Moreover, strict environmental tests are necessary to guarantee APD performance for missions expected to extend beyond five years. The radiation hardness of APDs, as for most semiconductors, is particularly crucial, since radiation in the space environment is severe. In this paper, we present the results of radiation tests conducted on reverse-type APDs (provided by Hamamatsu Photonics) irradiated by gamma rays (60Co) and 150 MeV protons. We show that, even under the same 100 Gy dose, high energy protons can cause displacement (bulk) damage in the depletion region and possibly change the activation energy, whereas gamma-ray irradiation is less prone to cause damage, because ionization damage dominates only the surface region. We also present quantitative guidance on how to estimate APD noise deterioration over a range of temperatures and radiation doses. As a practical example, we discuss the expected degradation of the BGO energy threshold for the generation of veto signals, following several years of Astro-H operation in Low Earth Orbit (LEO), and directly compare it to experimental results obtained using a small BGO crystal.

Using geochemistry to identify the source of groundwater to Montezuma Well, a natural spring in Central Arizona, USA: Part 2

USGS Publications Warehouse

Johnson, Raymond H.; DeWitt, Ed; Wirt, Laurie; Manning, Andrew H.; Hunt, Andrew G.

2012-01-01

Montezuma Well is a unique natural spring located in a sinkhole surrounded by travertine. Montezuma Well is managed by the National Park Service, and groundwater development in the area is a potential threat to the water source for Montezuma Well. This research was undertaken to better understand the sources of groundwater to Montezuma Well. Strontium isotopes (87Sr/86Sr) indicate that groundwater in the recharge area has flowed through surficial basalts with subsequent contact with the underlying Permian aged sandstones and the deeper, karstic, Mississippian Redwall Limestone. The distinctive geochemistry in Montezuma Well and nearby Soda Springs (higher concentrations of alkalinity, As, B, Cl, and Li) is coincident with added carbon dioxide and mantle-sourced He. The geochemistry and isotopic data from Montezuma Well and Soda Springs allow for the separation of groundwater samples into four categories: (1) upgradient, (2) deep groundwater with carbon dioxide, (3) shallow Verde Formation, and (4) mixing zone. δ18O and δD values, along with noble gas recharge elevation data, indicate that the higher elevation areas to the north and east of Montezuma Well are the groundwater recharge zones for Montezuma Well and most of the groundwater in this portion of the Verde Valley. Adjusted groundwater age dating using likely 14C and δ13C sources indicate an age for Montezuma Well and Soda Springs groundwaters at 5,400–13,300 years, while shallow groundwater in the Verde Formation appears to be older (18,900). Based on water chemistry and isotopic evidence, groundwater flow to Montezuma Well is consistent with a hydrogeologic framework that indicates groundwater flow by (1) recharge in higher elevation basalts to the north and east of Montezuma Well, (2) movement through the upgradient Permian and Mississippian units, especially the Redwall Limestone, and (3) contact with a basalt dike/fracture system that provides a mechanism for groundwater to flow to the surface. While the exact nature of the groundwater flow connections is still uncertain, the available data indicate that flow to Montezuma Well may be more susceptible to future groundwater development in the Redwall Limestone than from any other geologic unit. Overall, the shallow groundwater in the surrounding Verde Formation appears to be largely disconnected from deeper groundwater flowing to Montezuma Well.

A novel depth-of-interaction block detector for positron emission tomography using a dichotomous orthogonal symmetry decoding concept.

PubMed

Zhang, Yuxuan; Yan, Han; Baghaei, Hossain; Wong, Wai-Hoi

2016-02-21

Conventionally, a dual-end depth-of-interaction (DOI) block detector readout requires two two-dimensional silicon photomultiplier (SiPM) arrays, one on top and one on the bottom, to define the XYZ positions. However, because both the top and bottom SiPM arrays are reading the same pixels, this creates information redundancy. We propose a dichotomous orthogonal symmetric (DOS) dual-end readout block detector design, which removes this redundancy by reducing the number of SiPMs and still achieves XY and DOI (Z) decoding for positron emission tomography (PET) block detector. Reflecting films are used within the block detector to channel photons going to the top of the block to go only in the X direction, and photons going to the bottom are channeled along the Y direction. Despite the unidirectional channeling on each end, the top readout provides both X and Y information using two one-dimensional SiPM arrays instead of a two-dimensional SiPM array; similarly, the bottom readout also provides both X and Y information with just two one-dimensional SiPM arrays. Thus, a total of four one-dimensional SiPM arrays (4  ×  N SiPMs) are used to decode the XYZ positions of the firing pixels instead of two two-dimensional SiPM arrays (2  ×  N  ×  N SiPMs), reducing the number of SiPM arrays per block from 2N(2) to 4 N for PET/MR or PET/CT systems. Moreover, the SiPM arrays on one end can be replaced by two regular photomultiplier tubes (PMTs), so that a block needs only 2 N SiPMs  +  2 half-PMTs; this hybrid-DOS DOI block detector can be used in PET/CT systems. Monte Carlo simulations were carried out to study the performance of our DOS DOI block detector design, including the XY-decoding quality, energy resolution, and DOI resolution. Both BGO and LSO scintillators were studied. We found that 4 mm pixels were well decoded for 5  ×  5 BGO and 9  ×  9 LSO arrays with 4 to 5 mm DOI resolution and 16-20% energy resolution. By adding light-channel decoding, we modified the DOS design to a high-resolution design, which resolved scintillator pixels smaller than the SiPM dimensions. Detector pixels of 2.4 mm were decoded for 8  ×  8 BGO and 15  ×  15 LSO arrays with 5 mm DOI resolution and 20-23% energy resolution. Time performance was also studied for the 8  ×  8 BGO and 15  ×  15 LSO HR-DOS arrays. The timing resolution for the corner and central crystals is 986  ±  122 ps and 1.89  ±  0.17 μs respectively with BGO, 137  ±  42 ps and 458  ±  67 ps respectively with LSO. Monte Carlo simulations with GATE/Geant4 demonstrated the feasibility of our DOS DOI block detector design. In conclusion, our novel design achieved good performance except the time performance while using fewer SiPMs and supporting electronic channels than the current non-DOI PET detectors. This novel design can significantly reduce the cost, heat, and readout complexity of DOI block detectors for PET/MR/CT systems that don't require the time-of-flight capability.

Remediation System Evaluation, FCX Statesville Superfund Site

EPA Pesticide Factsheets

The FCX property was an agriculture distribution center that formulated, repackaged, and warehoused pesticides and fertilizers. The former Burlington Industries property to the north and upgradient of the FCX property was a textile facility.

Software for Processing Flight and Simulated Data of the ATIC Experiment

NASA Technical Reports Server (NTRS)

Panov, A. D.; Adams, J. H., Jr.; Ahn, H. S.; Bashindzhagyan, G. L.; Batkov, K. E.; Case, G.; Christl, M.; Chang, J.; Fazely, A. R.; Ganel, O.;

Evaluation of dual γ-ray imager with active collimator using various types of scintillators.

PubMed

Lee, Wonho; Lee, Taewoong; Jeong, Manhee; Kim, Ho Kyung

2011-10-01

The performance of a specialized dual γ-ray imager using both mechanical and electronic collimation was evaluated by Monte Carlo simulation (MCNP5). The dual imager consisted of an active collimator and a planar detector that were made from scintillators. The active collimator served not only as a coded aperture for mechanical collimation but also as a first detector for electronic collimation. Therefore, a single system contained both mechanical and electronic collimation. Various types of scintillators were tested and compared with each other in terms of their angular resolution, efficiency, and background noise. In general, a BGO active collimator had the best mechanical collimation performance, and an LaCl₃(Ce) active collimator provided the best electronic collimation performance. However, for low radiation energies, the mechanical collimation images made from both scintillators showed the same quality, and, for high radiation energies, electronic collimation images made from both scintillators also show similar quality. Therefore, if mechanical collimation is used to detect low-energy radiation and electronic collimation is applied to reconstruct a high-energy source, either LaCl₃(Ce) or BGO would be appropriate for the active collimator of a dual γ-ray imager. These results broaden the choice of scintillators for the active collimator of the dual γ-ray imager, which makes it possible to consider other factors, such as machinability and cost, in making the imager. As a planar detector, BGO showed better performance than other scintillators since its radiation detection efficiency was highest of all. Copyright © 2011 Elsevier Ltd. All rights reserved.

Ground-water quality, water year 1995, and statistical analysis of ground-water-quality data, water years 1994-95, at the Chromic Acid Pit site, US Army Air Defense Artillery Center and Fort Bliss, El Paso, Texas

USGS Publications Warehouse

Abeyta, Cynthia G.; Roybal, R.G.

1996-01-01

The Chromic Acid Pit site is an inactive waste disposal site that is regulated by the Resource Conservation and Recovery Act of 1976. The 2.2-cubic-yard cement-lined pit was operated from 1980 to 1983 by a contractor to the U.S. Army Air Defense Artillery Center and Fort Bliss. The pit, located on the Fort Bliss military reservation in El Paso, Texas, was used for disposal and evaporation of chromic acid waste generated from chrome plating operations. The site was closed in 1989, and the Texas Natural Resources Conservation Commission issued permit number HW-50296 (U.S. Environmental Protection Agency number TX4213720101), which approved and implemented post-closure care for the Chromic Acid Pit site. In accordance with an approved post-closure plan, the U.S. Geological Survey is cooperating with the U.S. Army in monitoring and evaluating ground-water quality at the site. One upgradient ground-water monitoring well (MW1) and two downgradient ground-water monitoring wells (MW2 and MW3), installed adjacent to the chromic acid pit, are monitored on a quarterly basis. Ground-water sampling of these wells by the U.S. Geological Survey began in December 1993. The ground-water level, measured in a production well located approximately 1,700 feet southeast of the Chromic Acid Pit site, has declined about 29.43 feet from 1982 to 1995. Depth to water at the Chromic Acid Pit site in September 1995 was 284.2 to 286.5 feet below land surface; ground-water flow at the water table is assumed to be toward the southeast. Ground-water samples collected from monitoring wells at the Chromic Acid Pit site during water year 1995 contained dissolved- solids concentrations of 481 to 516 milligrams per liter. Total chromium concentrations detected above the laboratory reporting limit ranged from 0.0061 to 0.030 milligram per liter; dissolved chromium concentrations ranged from 0.0040 to 0.010 milligram per liter. Nitrate as nitrogen concentrations ranged from 2.1 to 2.8 milligrams per liter; nitrite plus nitrate as nitrogen concentrations ranged from 2.4 to 3.2 milligrams per liter. Water samples from wells MW1 and MW2 were analyzed for volatile organic compounds for the first quarter; no confirmed volatile organic compounds were detected above laboratory reporting limits. Detected chemical concentrations in water from the chromic acid pit monitoring wells during the four sampling periods were below U.S. Environmental Protection Agency-established maximum contaminant levels for public drinking-water supplies. Overall, water-quality characteristics of water from the chromic acid pit ground-water monitoring wells are similar to those of other wells in the surrounding area. Statistical analyses were performed on 56 of the chemical constituents analyzed for in ground water from the chromic acid pit monitoring wells. Concentrations of chloride, fluoride, sulfate, and potassium were significantly less in water from one or both downgradient wells than in water from the upgradient well. Concentrations of nitrate as nitrogen, nitrite plus nitrate as nitrogen, and dissolved solids were significantly greater in water from the downgradient wells than in water from the upgradient well. Concentrations of nitrate as nitrogen, chloride, and potassium were significantly different in water from the two downgradient wells. Statistical analysis of chemical constituents in water from the chromic acid pit monitoring wells did not appear to indicate a release of hazardous chemicals from the chromic acid pit. There was no indication of ground-water contamination in either downgradient well.

Hydrogeology and ground-water quality of the Chromic Acid Pit site, US Army Air Defense Artillery Center and Fort Bliss, El Paso, Texas

USGS Publications Warehouse

Abeyta, Cynthia G.; Thomas, C.L.

1996-01-01

The Chromic Acid Pit site is an inactive waste disposal site that is regulated by the Resource Conservation and Recovery Act of 1976. The 2.2-cubic-yard cement-lined pit was operated from 1980 to 1983 by a contractor to the U.S. Army Air Defense Artillery Center and Fort Bliss. The pit, located on the Fort Bliss military reservation, in El Paso, Texas, was used for disposal and evaporation of chromic acid waste generated from chrome plating operations. The site was certified closed in 1989 and the Texas Natural Resources Conservation Commission issued Permit Number HW-50296 (U.S. Environmental Protection Agency Permit Number TX4213720101), which approved and implemented post-closure care for the Chromic Acid Pit site. In accordance with an approved post-closure plan, the U.S. Geological Survey is cooperating with the U.S. Army in evaluating hydrogeologic conditions and ground- water quality at the site. One upgradient and two downgradient ground-water monitoring wells were installed adjacent to the chromic acid pit by a private contractor. Quarterly ground-water sampling of these wells by the U.S. Geological Survey began in December 1993. The Chromic Acid Pit site is situated in the Hueco Bolson intermontane valley. The Hueco Bolson is a primary source of ground water in the El Paso area. City of El Paso and U.S. Army water-supply wells are located on all sides of the study area and are completed 600 to more than 1,200 feet below land surface. The ground-water level in the area of the Chromic Acid Pit site has declined about 25 feet from 1982 to 1993. Depth to water at the Chromic Acid Pit site in September 1994 was about 284 feet below land surface; ground-water flow is to the southeast. Ground-water samples collected from monitoring wells at the Chromic Acid Pit site contained dissolved-solids concentrations of 442 to 564 milligrams per liter. Nitrate as nitrogen concentrations ranged from 2.1 to 2.7 milligrams per liter; nitrite plus nitrate as nitrogen concentrations ranged from 2.3 to 3.0 milligrams per liter. Nitrate concentrations are abnormally high in the Old Mesa well field located about 5,000 feet southwest of the Chromic Acid Pit site. Volatile and semivolatile organic compounds in water samples were analyzed for the first sampling round; no confirmed volatile or semivolatile organic compounds were detected above the laboratory reporting limits. Total chromium concentrations ranged from 0.0099 to 0.092 milligram per liter; dissolved chromium concentrations ranged from 0.0068 to 0.0094 milligram per liter. Overall, water-quality characteristics in water from the chromic acid pit ground-water monitoring wells are similar to those in the surrounding area. Detected chemical concentrations in water from the chromic acid pit monitoring wells during the four sampling periods were below U.S. Environmental Protection Agency-established maximum contaminant levels for public drinking water supplies. Statistical analyses were performed on 39 of the chemical constituents analyzed for in ground water from the chromic acid pit monitoring wells. Concentrations of chloride and fluoride were significantly less in water from the downgradient wells than in water from the upgradient well, whereas concentrations of nitrate as nitrogen, nitrite plus nitrate as nitrogen, and dissolved solids were significantly greater in water from the downgradient wells than in water from the upgradient well. Concentrations of nitrate as nitrogen were significantly different in water from the two downgradient wells. Differences detected through statistical analysis of chemical constituents of water in the chromic acid pit monitoring wells did not appear to indicate a release of hazardous chemicals from the chromic acid pit. There was no indication of ground-water contamination in either downgradient well.

Superfund record of decision amendment (EPA Region 5): Mid State Disposal Site, Marathon County, WI, August 4, 1995

DOE Office of Scientific and Technical Information (OSTI.GOV)

NONE

The United States Environmental Protection Agency (U.S. EPS) is changing the remedy selected in the Original Record of Decision (ROD) dated September 30, 1988 (PB89-189559). The remedial design was completed in 1993, with construction completed in the Spring of 1994. Of the nine remedial components noted above, all except Component 4, the AWS, have been implemented or initiated as part of the Operation and Maintenance. During the course of the Pre-design activities, an initial hydrogeologic evaluation of the area around the site was completed to address the potential of establishing high-capacity water supply wells. The results of the study indicatedmore » that an AWS consisting of two upgradient wells was not a feasible alternative.« less

Hydrologic data for a study of pre-Illinoian glacial till in Linn County, Iowa, water year 1990

USGS Publications Warehouse

Bowman, Phillip R.

1991-01-01

Ten unvented, vibrating-wire, pressure transducers with internal thermistors were buried in two boreholes at upgradient and downgradient locations to record hydraulic pressure arid water temperature at selected depths.

Onboard calibration circuit for the DAMPE BGO calorimeter front-end electronics

NASA Astrophysics Data System (ADS)

Zhang, De-Liang; Feng, Chang-Qing; Zhang, Jun-Bin; Wang, Qi; Ma, Si-Yuan; Shen, Zhong-Tao; Jiang, Di; Gao, Shan-Shan; Zhang, Yun-Long; Guo, Jian-Hua; Liu, Shu-Bin; An, Qi

2016-05-01

DAMPE (DArk Matter Particle Explorer) is a scientific satellite which is mainly aimed at indirectly searching for dark matter in space. One critical sub-detector of the DAMPE payload is the BGO (bismuth germanium oxide) calorimeter, which contains 1848 PMT (photomultiplier tube) dynodes and 16 FEE (Front-End Electronics) boards. VA160 and VATA160, two 32-channel low power ASICs (Application Specific Integrated Circuits), are adopted as the key components on the FEEs to perform charge measurement for the PMT signals. In order to monitor the parameter drift which may be caused by temperature variation, aging, or other environmental factors, an onboard calibration circuit is designed for the VA160 and VATA160 ASICs. It is mainly composed of a 12-bit DAC (Digital to Analog Converter), an operational amplifier and an analog switch. Test results showed that a dynamic range of 0-30 pC with a precision of 5 fC (Root Meam Square, RMS) was achieved, which covers the VA160’s input range. It can be used to compensate for the temperature drift and test the trigger function of the FEEs. The calibration circuit has been implemented for the front-end electronics of the BGO Calorimeter and verified by all the environmental tests for both Qualification Model and Flight Model of DAMPE. The DAMPE satellite was launched at the end of 2015 and the calibration circuit will operate periodically in space. Supported by Strategic Priority Research Program on Space Science of Chinese Academy of Sciences (XDA04040202-4), and National Basic Research Program (973 Program) of China (2010CB833002) and National Natural Science Foundation of China (11273070)

Performance assessment study of the balloon-borne astronomical soft gamma-ray polarimeter PoGOLite

NASA Astrophysics Data System (ADS)

Arimoto, M.; Kanai, Y.; Ueno, M.; Kataoka, J.; Kawai, N.; Tanaka, T.; Yamamoto, K.; Takahashi, H.; Mizuno, T.; Fukazawa, Y.; Axelsson, M.; Kiss, M.; Marini Bettolo, C.; Carlson, P.; Klamra, W.; Pearce, M.; Chen, P.; Craig, B.; Kamae, T.; Madejski, G.; Ng, J. S. T.; Rogers, R.; Tajima, H.; Thurston, T. S.; Saito, Y.; Takahashi, T.; Gunji, S.; Bjornsson, C.-I.; Larsson, S.; Ryde, F.; Bogaert, G.; Varner, G.

2007-12-01

Measurements of polarization play a crucial role in the understanding of the dominant emission mechanism of astronomical sources. Polarized Gamma-ray Observer-Light version (PoGOLite) is a balloon-borne astronomical soft gamma-ray polarimeter at the 25 80 keV band. The PoGOLite detector consists of a hexagonal close-packed array of 217 Phoswich detector cells (PDCs) and side anti-coincidence shields (SASs) made of BGO crystals surrounding PDCs. Each PDC consists of a slow hollow scintillator, a fast scintillator and a BGO crystal that connects to a photomultiplier tube at the end. To examine the PoGOLite's capability and estimate the performance, we conducted experiments with the PDC using radioisotope 241Am. In addition, we compared this result with performance expected by Monte Carlo simulation with Geant4. As a result, we found that the actual PDC has the capability to detect a 100 m Crab source until 80 keV.

Hydrologic environments and water-quality characteristics at four landfills in Mecklenburg County, North Carolina, 1980-86

USGS Publications Warehouse

Cardinell, A.P.; Barnes, C.R.; Eddins, W.H.; Coble, R.W.

1989-01-01

A water-quality study was conducted during 1980-86 at four landfills in Mecklenburg County, North Carolina. Each landfill has a three-layered hydrogeologic system typical of the Piedmont, consisting of (1) the regolith; (2) a transition zone; and (3) unweathered, fractured crystalline bedrock. As much as 7.6 inches per year of rainfall enters the ground-water system and has the potential to generate leachate within landfill cells. Ground water and leachate discharge to tributaries within the landfill sites or to streams adjacent to them. Water-quality samples were collected from 53 monitoring wells and 20 surface-water sites. Samples were analyzed for selected physical and biological characteristics, major inorganic ions, nutrients, trace elements, and organic compounds. Selected indicators of water quality, including specific conductance; hardness; and concentrations of chloride, manganese, dissolved solids, total organic carbon, and specific organic compounds were analyzed to determine the effects of each landfill on ground- and surface-water quality. Increases in concentrations of inorganic constituents above background levels were detected in ground water downgradient of the landfills. The increases were generally greatest in samples from wells in close proximity to the older landfill cells. In general, the increases in concentrations in downgradient wells were greater for calcium, magnesium, and chloride than for other major ions. Manganese exhibited the largest relative increase in concentration between upgradient and downgradient wells of any constituent, and manganese concentration data were effective in defining areas with extensive anaerobic biological activity. Differences between upgradient and downgradient concentrations of total organic carbon and specific organic compounds generally were not as apparent. The most frequently identified organic contaminants were the herbicides 2,4-D and 2,4,5-T. Chlorofluoromethanes were identified in three of four ground-water samples analyzed for volatile organic compounds. Landfills affected the water quality of several smaller streams but did not noticeably affect larger ones. Apparent effects on water quality were greatest at the oldest landfill, located on Statesville Road, where waste is in cells that are partly below the water table.

Completion Summary for Well NRF-16 near the Naval Reactors Facility, Idaho National Laboratory, Idaho

USGS Publications Warehouse

Twining, Brian V.; Fisher, Jason C.; Bartholomay, Roy C.

2010-01-01

In 2009, the U.S. Geological Survey in cooperation with the U.S. Department of Energy's Naval Reactors Laboratory Field Office, Idaho Branch Office cored and completed well NRF-16 for monitoring the eastern Snake River Plain (SRP) aquifer. The borehole was initially cored to a depth of 425 feet below land surface and water samples and geophysical data were collected and analyzed to determine if well NRF-16 would meet criteria requested by Naval Reactors Facility (NRF) for a new upgradient well. Final construction continued after initial water samples and geophysical data indicated that NRF-16 would produce chemical concentrations representative of upgradient aquifer water not influenced by NRF facility disposal, and that the well was capable of producing sustainable discharge for ongoing monitoring. The borehole was reamed and constructed as a Comprehensive Environmental Response Compensation and Liability Act monitoring well complete with screen and dedicated pump. Geophysical and borehole video logs were collected after coring and final completion of the monitoring well. Geophysical logs were examined in conjunction with the borehole core to identify primary flow paths for groundwater, which are believed to occur in the intervals of fractured and vesicular basalt and to describe borehole lithology in detail. Geophysical data also were examined to look for evidence of perched water and the extent of the annular seal after cement grouting the casing in place. Borehole videos were collected to confirm that no perched water was present and to examine the borehole before and after setting the screen in well NRF-16. Two consecutive single-well aquifer tests to define hydraulic characteristics for well NRF-16 were conducted in the eastern SRP aquifer. Transmissivity and hydraulic conductivity averaged from the aquifer tests were 4.8 x 103 ft2/d and 9.9 ft/d, respectively. The transmissivity for well NRF-16 was within the range of values determined from past aquifer tests in other wells near NRF of 4.4 x 102 to 5.1 x 105 ft2/d. Water samples were analyzed for metals, nutrients, total organic carbon, volatile organic compounds, semi-volatile organic compounds, herbicides, pesticides, polychlorinated biphenols, and radionuclides. All chloride, nitrate, and sulfate concentrations were less than background concentrations for the eastern SRP aquifer north of the NRF. Concentrations in water samples for most of the organic compounds and radionuclides were less than the reporting limits and reporting levels.

Ground-water quality in the Davie Landfill, Broward County, Florida

USGS Publications Warehouse

Mattraw, H.C.

1976-01-01

Ground-water adjacent to a disposal pond for septic tank sludge, oil, and grease at the Davie landfill, Broward County, Florida was tested for a variety of ground-water contaminants. Three wells adjacent to the disposal pond yielded water rich in nutrients, organic carbon and many other chemical constituents. Total coliform bacteria ranged from less than 100 to 660 colonies per 100 milliliters in samples collected from the shallowest well (depth 20 feet). At well depths of 35 and 45 feet bacterial counts were less than 20 colonies per 100 milliliters or zero. Concentrations of several constituents in water samples collected from the wells downgradient from the landfill, disposal pond, and an incinerator wash pond were greater than in samples collected from wells immediately upgradient of the landfill. A comparison of sodium-chloride ion ratios indicated that downgradient ground-water contamination was related to the incinerator wash water pond rather than the septic tank sludge pond. (Woodard-USGS)

DOE Office of Scientific and Technical Information (OSTI.GOV)

Yeh, G.P.; /Fermilab

Studies of requirements and specifications of crystals are necessary to develop a new generation of crystals for dual readout crystal hadron or total absorption calorimeter. This is a short and basic study of the characteristics and hadron energy measurement of PbWO4 and BGO crystals for scintillation and Cerenkov Dual Readout hadron calorimeter.

Design of the Readout Electronics for the BGO Calorimeter of DAMPE Mission

NASA Astrophysics Data System (ADS)

Feng, Changqing; Zhang, Deliang; Zhang, Junbin; Gao, Shanshan; Yang, Di; Zhang, Yunlong; Zhang, Zhiyong; Liu, Shubin; An, Qi

2015-12-01

The DAMPE (DArk Matter Particle Explorer) is a scientific satellite being developed in China, aimed at cosmic ray study, gamma ray astronomy, and searching for the clue of dark matter particles in the near future. The BGO (Bismuth Germanate Oxide) Calorimeter, which consists of 616 PMTs (photomultiplier tubes) and 1848 dynode signals, is a crucial part of the DAMPE payload for measuring the energy of cosmic ray particles, distinguishing interesting particles from background, and providing trigger information. An electronics system, which consists of 16 FEE (Front End Electronics) modules with a total power consumption of about 26 W, has been developed. Its main functions are based on the low power, 32-channel VA160 and VATA160 ASICs (Application Specific Integrated Circuits) for precisely measuring the charge of PMT signals and providing“hit”signals as well. To assure the long-term reliability in harsh space environment, a series of critical issues such as the radiation hardness, thermal design, components and board level quality control, etc., are taken into consideration. Test result showed that the system level ENC (equivalent noise charge) for each channel is about 10 fC in RMS (root mean square), and the timing uncertainty of the hit signals is about 300 ns, both of which satisfy the physics requirements of the detector. Experiments with 60Co radioactive source proved that 20 krad(Si) TID (Total Ionizing Dose) level is achieved, while the heavy ion beam and laser beam tests indicated that its SEL (Single Event Latch-up) and SEU (Single Event Upset) performance in orbit will be acceptable by taking some hardness measures. All the readout modules successfully passed the board-level screening, the sub-system level and finally the satellite system level environmental tests, and behave well in the beam test at CERN (European Organisation for Nuclear Research).

BIOMASS ACCUMULATION AT THE ELIZABETH CITY AND DENVER FEDERAL CENTER PRBS

EPA Science Inventory

Microbial characterization results, based on PLFA profiles, from the Elizabeth City PRB and adjacent aquifer materials showed a diverse microbiological community dominated by Gram-negative bacteria. Iron core samples from near the upgradient edge of the PRB are typically enriche...

Containment of subsurface contaminants

DOEpatents

Corey, John C.

1994-01-01

A barrier for reducing the spread of a plume of subsurface contaminants. The apparatus includes a well system for injecting a fluid, such as air, just outside and below the periphery of the plume. The fluid is injected at a pressure sufficient to lower the hydraulic conductivity of the soil from the point of injection to the surface thus establishing a curtain-like barrier to groundwater movement. The barrier is established upgradient of the plume to divert groundwater away, or preferably completely around the plume to reduce the flow of groundwater into or out of the plume. The barrier enables the remediation of the confined contamination and then, when the injection of the fluid is halted, the barrier quickly dissipates.

Simulation of ground-water flow and delineation of areas contributing recharge within the Mt. Simon-Hinckley Aquifer to well fields in the Prairie Island Indian Community, Minnesota

USGS Publications Warehouse

Ruhl, J.F.

2002-01-01

A steady state single layer, two-dimensional ground-water flow model constructed with the computer program MODFLOW,combined with the particle-tracking computer program MODPATH, was used to track water particles (upgradient) from the two well fields. A withdrawal rate of 625 m3/d was simulated for each well field. The ground-water flow paths delineated areas of contributing recharge that are 0.38 and 0.65 km2 based on 10- and 50-year travel times, respectively. The flow paths that define these areas extend for maximum distances of about 350 and 450 m, respectively, from the wells. At well field A the area of contributing recharge was delineated for each well as separate withdrawal points. At well field B the area of contributing recharge was delineated for the two wells as a single withdrawal point. Delineation of areas of contributing recharge to the well fields from land surface would require construction of a multi-layer ground-water flow model.

DOE Office of Scientific and Technical Information (OSTI.GOV)

LaFreniere, L. M.; Environmental Science Division

The Commodity Credit Corporation (CCC), an agency of the U.S. Department of Agriculture (USDA), operated a grain storage facility in Hilton, Kansas, in 1954-1965. In 1992, carbon tetrachloride was first identified, at a concentration of 910 {micro}g/L, in groundwater from well GW01 at Hilton. This discovery occurred in association with the sale of the private grain storage facility on which well GW01 is located to the current owner, the Mid-Kansas Cooperative Association. The Kansas Department of Health and Environment conducted investigations at Hilton in 1992-1994. In 1996-1997, Argonne National Laboratory conducted Phase I and Phase II investigations on behalf ofmore » the CCC/USDA to characterize the distribution of the carbon tetrachloride contamination identified in well GW01, the stratigraphic units potentially hosting contaminant migration, and local hydrogeology in the Hilton area. The 2007 targeted investigation reported here focused specifically on the former CCC/USDA property at Hilton, west of the railroad tracks. (Until a property record search in 2005, the location of the CCC/USDA's former facility at Hilton was not known with certainty.) The objectives of the investigation, as implemented, were to (1) investigate for carbon tetrachloride contamination in the shallower soil and shallow aquifer units below the former CCC/USDA property and (2) investigate groundwater flow patterns. The key results of the 2007 targeted investigation are as follows: (1) No carbon tetrachloride or chloroform contamination was found in soil or groundwater below the former CCC/USDA facility. (2) The 2007 groundwater level data support a southwesterly direction for groundwater flow in the main Hilton aquifer (Equus Beds), consistent with findings of previous investigations. Contaminated well GW01 was confirmed to be upgradient from the former CCC/USDA facility. (3) The contaminants carbon tetrachloride, chloroform, and 1,2-dibromoethane (ethylene dibromide) were found in groundwater only at well GW01. No evidence of contamination was found in other monitoring wells and piezometers. This pattern is consistent with findings of previous investigations. The findings of the 2007 targeted investigation clearly demonstrate that the former CCC/USDA facility at Hilton was not the source of the carbon tetrachloride contamination persistently detected in well GW01. Well GW01 is approximately 300 ft upgradient from the former CCC/USDA facility. This well is the only sampling location at Hilton where carbon tetrachloride contamination in groundwater has ever been identified. The CCC/USDA never operated grain storage facilities on the property on which well GW01 is located.« less

UNIVERSITY OF KANSAS SMART GRID DEMONSTRATION PROJECT

EPA Science Inventory

The University of Kansas (KU) EcoHawks Design Project began in 2008 with the conversion of a discarded 1974 Volkswagen Super Beetle into a fuel neutral series hybrid running on 100% biodiesel created from waste vegetable oil. This project continued in year two through upgradi...

40 CFR 265.91 - Ground-water monitoring system.

Code of Federal Regulations, 2010 CFR

2010-07-01

... sufficient to yield ground-water samples that are: (i) Representative of background ground-water quality in... not required provided that provisions for sampling upgradient and downgradient water quality will... perforated, and packed with gravel or sand where necessary, to enable sample collection at depths where...

DOE Office of Scientific and Technical Information (OSTI.GOV)

Roy, Tushar, E-mail: tushar@barc.gov.in; Kashyap, Yogesh; Shukla, Mayank

Associated particle technique (APT) for detection of explosives is well established but has been implemented mostly for fixed portal systems. In certain situations, a portable system is required where the suspect object cannot be moved from site. This paper discusses the development of a portable APT system in single-sided geometry which can be transported to site and requires only one-sided access to the object. The system comprised D-T neutron source and bismuth germanate (BGO) detectors fixed on a portable module. Different aspects of the system have been discussed such as background contribution, time selection, and elemental signatures. The system wasmore » used to detect benign samples and explosive simulants under laboratory condition. The elemental ratios obtained by analyzing the gamma spectra show good match with the theoretical ratios.« less

Simulation of aquifer tests and ground-water flowpaths at the local scale in fractured shales and sandstones of the Brunswick Group and Lockatong Formation, Lansdale, Montgomery County, Pennsylvania

USGS Publications Warehouse

Goode, Daniel J.; Senior, Lisa A.

2000-01-01

The U.S. Geological Survey, as part of technical assistance to the U.S. Environmental Protection Agency, has constructed and calibrated models of local-scale ground-water flow in and near Lansdale, Pa., where numerous sources of industrial contamination have been consolidated into the North Penn Area 6 Superfund Site. The local-scale models incorporate hydrogeologic structure of northwest-dipping beds with uniform hydraulic properties identified in previous studies. Computations associated with mapping the dipping-bed structure into the three-dimensional model grid are handled by a preprocessor using a programmed geographic information system (GIS). Hydraulic properties are identified by calibration of the models using measured water levels during pumping and recovery from aquifer tests at three sites. Reduced flow across low-permeability beds is explicitly simulated. The dipping high-permeability beds are extensive in the strike direction but are of limited extent in the dip direction. This model structure yields ground-water-flow patterns characteristic of anisotropic aquifers; preferred flow is in the strike direction. The transmissivities of high-permeability beds in the local-scale models range from 142 to 1,900 ft2/d (feet squared per day) (13 to 177 m2/d). The hydraulic conductivities of low-permeability parts of the aquifer range from 9.6 x 10-4 to 0.26 ft/d (feet per day) (2.9 x 10-4 to 0.079 m/d). Storage coefficients and specific storage are very low, indicating the confined nature of the aquifer system. The calibrated models are used to simulate contributing areas of wells under alternative, hypothetical ground-water-management practices. Predictive contributing areas indicate the general characteristics of ground-water flow towards wells in the Lansdale area. Recharge to wells in Lansdale generally comes from infiltration near the well and over an area that extends upgradient from the well. The contributing areas for two wells pumping at 10 gal/min (gallons per minute) extend about 1,500 ft (feet) upgradient from the wells. The contributing area is more complex at ground-water divides and can extend in more than one direction to capture recharge from more than 3,300 ft away, for pumping at a rate of 30 gal/min. Locally, all recharge in the area of the pumping well is not captured; recharge in the downgradient direction about 150 ft from the pumping well will flow to other discharge locations.

Nitrate in ground water and spring water near four dairy farms in North Florida, 1990-93

USGS Publications Warehouse

Andrews, W.J.

1994-01-01

Concentrations of nitrate and other selected water- quality characteristics were analyzed periodically for two years in water from 51 monitoring wells installed at four farms and in water discharging from three nearby springs along the Suwannee River in Lafayette and Suwannee Counties to examine the quality of ground water at these farms and the transport of nutrients in ground water to the nearby spring-fed Suwannee River: Ground water from shallow wells, which were completed in the top ten feet of the saturated zone in a surficial sandy aquifer and in the karstic Upper Floridan aquifer generally had the highest concentrations of nitrate, ranging from <.02 to 130 mg/L as nitrogen. Nitrate concentrations commonly exceeded the primary drinking water standard of 10 mg/L for nitrate as nitrogen in water from shallow wells, which tapped the top ten feet of the uppermost aquifers near waste-disposal areas such as wastewater lagoons and defoliated, intensive-use areas near milking barns. Upgradient from waste-disposal areas, concentrations of nitrate in ground water were commonly less than 1 mg/L as nitrogen. Water samples from deep wells (screened 20 feet deeper than shallow wells in these aquifers) generally had lower concentrations of nitrate (ranging from <0.02 to 84 mg/L) than water from shallow wells. Water samples from the three monitored springs (Blue, Telford, and Convict Springs) had nitrate concentrations ranging from 1.5 to 6.5 mg/L as nitrogen, which were higher than those typically occurring in water from upgradient wells at the monitored dairy farms or from back- ground wells sampled in the region. Analyses of nitrogen isotope ratios in nitrate indicated that leachate from animal wastes was the principal source of nitrate in ground water adjacent to waste-disposal areas at the monitored and unmonitored dairy farms. Leachate from a combi- nation of fertilizers, soils, and animal wastes appeared to be the source of nitrate in ground- water downgradient from pastures and wastewater spray fields at dairy farms and in water discharging from three nearby springs. Although denitrifying bacteria were present in counts sometimes exceeding 240,000 colonies/100mL in water from dairy-farm monitoring wells, ground water in the uppermost aquifers in Lafayette and Suwannee Counties generally contained too much oxygen for denitrification to remove nitrate from shallow ground water. Denitrification was more likely to occur in deeper ground water, which typically has lower dissolved oxygen concentrations.

Investigation of Contaminated Groundwater at Solid Waste Management Unit 12, Naval Weapons Station Charleston, North Charleston, South Carolina, 2008

USGS Publications Warehouse

Vroblesky, Don A.; Petkewich, Matthew D.

2009-01-01

The U.S. Geological Survey and the Naval Facilities Engineering Command Southeast investigated natural and engineered remediation of chlorinated volatile organic compound (VOC) groundwater contamination at Solid Waste Management Unit 12 at the Naval Weapons Station Charleston, North Charleston, South Carolina, beginning in 2000. The primary contaminants of interest in the study are tetrachloroethene, 1,1,1-trichloroethane, trichloroethene, cis-1,2-dichloroethene, vinyl chloride, 1,1-dichloroethane, and 1,1-dichloroethene. Engineered remediation aspects at the site consist of a zero-valent-iron permeable reactive barrier (PRB) installed in December 2002 intercepting the contamination plume and a phytoremediation test stand of loblolly pine trees planted in the source area in May 2003. The U.S. Geological Survey planted an additional phytoremediation test stand of loblolly pine trees on the upgradient side of the southern end of the PRB in February 2008. At least once during the summer, however, the trees were inadvertently mowed during lawn cutting activity. The PRB along the main axis of the contaminant plume appears to be actively removing contamination. In contrast to the central area of the PRB, the data from the southern end of the PRB indicate that contaminants are moving around the PRB. Concentrations in wells upgradient from the PRB showed a general decrease in VOC concentrations. VOC concentrations in some wells in the forest downgradient from the PRB showed a sharp increase in 2005, followed by a decrease in 2006. Farther downgradient in the forest, the VOC concentrations began to increase in 2007 and continued to increase into 2008. The VOC-concentration changes in groundwater beneath the forest appear to indicate movement of a groundwater-contaminant pulse through the forest. It also is possible that the data may represent lateral shifting of the plume in response to changes in groundwater-flow direction.

The ATIC Long Duration Balloon Project

NASA Technical Reports Server (NTRS)

Guzik, T. G.; Adams, J. H.; Ahn, H. S.; Bashindzhagyan, G.; Chang, J.; Christl, M.; Fazely, A. R.; Ganel, O.; Granger, D.; Gunasingha, R.

2003-01-01

Long Duration Balloon (LDB) scientific experiments, launched to circumnavigate the south pole over Antarctica, have particular advantages compared to Shuttle or other Low Earth Orbit (LEO) missions in terms of cost, weight, scientific 'duty factor' and work force development. The Advanced Thin Ionization Calorimeter (ATIC) cosmic ray astrophysics experiment is a good example of a university-based project that takes full advantage of current LDB capability. The ATIC experiment is currently being prepared for its first LDB science flight that will investigate the charge composition and energy spectra of primary cosmic rays over the energy range from about 10(exp 10) to 10(exp 14) eV. The instrument is built around a fully active, Bismuth Germanate (BGO) ionization calorimeter to measure the energy deposited by the cascades formed by particles interacting in a thick carbon target. A highly segmented silicon matrix, located above the target, provides good incident charge resolution plus rejection of the 'backscattered' particles from the interaction. Trajectory reconstruction is based on the cascade profile in the BGO calorimeter, plus information from the three pairs of scintillator hodoscope layers in the target section above it. A full evaluation of the experiment was performed during a test flight occurring between 28 December 2000 and 13 January 2001 where ATIC was carried to an altitude of approx. 37 km above Antarctica by an approx. 850,000 cu m helium filled balloon for one circumnavigation of the continent. All systems behaved well, the detectors performed as expected, more than 43 gigabytes of engineering and cosmic ray event data was returned and these data are now undergoing preliminary data analysis. During the coming 2002-2003 Antarctica summer season, we are preparing for a ATIC science flight with approx. 15 to 30 days of continuous data collection in the near-space environment of LDB float altitudes.

The 3H(d,γ)5He Reaction for Ec.m. ≤ 300 keV

NASA Astrophysics Data System (ADS)

Parker, C. E.; Brune, C. R.; Massey, T. N.; O'Donnell, J. E.; Richard, A. L.; Sayre, D. B.

2016-03-01

The 3H(d, γ)5He reaction has been measured using a 500-keV pulsed deuteron beam incident on a stopping titanium tritide target at Ohio University's Edwards Accelerator Laboratory. The time-of-flight (TOF) technique has been used to distinguish the γ-rays from neutrons detected in the bismuth germinate (BGO) γ-ray detector. A stilbene scintillator and an NE-213 scintillator have been used to detect the neutrons from the 3H(d, n)4He reaction using both the pulse-shape discrimination and TOF techniques. A newly-designed target holder with a silicon surface barrier detector to simultaneously measure α-particles to normalize the neutron count was incorporated for subsequent measurements. The γ-rays have been measured at laboratory angles of 0°, 45°, 90°, and 135°. Information about the γ-ray energy distribution for the unbound ground state and first excited state of 5He can be obtained experimentally by comparing the BGO data to Monte Carlo simulations. The 3H(d, γ)/3H(d, n) branching ratio has also been determined.

75 FR 34405 - National Oil and Hazardous Substances Pollution Contingency Plan; National Priorities List...

Federal Register 2010, 2011, 2012, 2013, 2014

2010-06-17

... future actions under Superfund. This partial deletion pertains to the surface media (soil, surface water... in contamination of structures, soil, surface water, and groundwater. As a result of this... Superfund Site located upgradient (south) of RMA (1990). OU 03: On-Post--Addresses soil and groundwater...

Groundwater response to changing water-use practices in sloping aquifers using convolution of transient response functions

USDA-ARS?s Scientific Manuscript database

This study examines the impact of a sloping base on the movement of transients through groundwater systems. Dimensionless variables and regression of model results are employed to develop functions relating the transient change in saturated thickness to the distance upgradient and downgradient from ...

Containment of subsurface contaminants

DOEpatents

Corey, J.C.

1994-09-06

A barrier is disclosed for reducing the spread of a plume of subsurface contaminants. The apparatus includes a well system for injecting a fluid, such as air, just outside and below the periphery of the plume. The fluid is injected at a pressure sufficient to lower the hydraulic conductivity of the soil from the point of injection to the surface thus establishing a curtain-like barrier to groundwater movement. The barrier is established upgradient of the plume to divert groundwater away, or preferably completely around the plume to reduce the flow of groundwater into or out of the plume. The barrier enables the remediation of the confined contamination and then, when the injection of the fluid is halted, the barrier quickly dissipates. 5 figs.

Simulation of the shallow aquifer in the vicinity of Silver Lake, Washington County, Wisconsin, using analytic elements

USGS Publications Warehouse

Dunning, C.P.; Thomas, Judith Coffman; Lin, Yu-Feng

2003-01-01

A Silver Lake water budget was defined using both published hydrologic data and simulations using the calibrated model. Model simulations show that 1.08 cubic feet per second of ground water enters Silver Lake on the upgradient (primarily western) side and 0.08 cubic feet per second recharges to ground water on the downgradient (primarily eastern) side. Net precipitation (precipitation minus evaporation) on the lake is 0.04 cubic feet per second. Collectively, these water-budget terms provide a residual value of 1.04 cubic feet per second flow to Silver Creek at the north end of Silver Lake, which is a very good match to the range of measured flow (0.7 to 5.2 cubic feet per second). Ground-water recharge areas for Silver Lake are largely on the western side of the lake. The recharge area for the northern two-thirds of Silver Lake is west toward Big Cedar Lake. Assuming a porosity of 20 percent, model results indicate that the 50-year time-of-travel for recharge to Silver Lake does not extend to Big Cedar Lake. The recharge area for the southern one-third of Silver Lake is west toward Little Cedar Lake. Model results indicate that time of travel for recharge to Silver Lake from Little Cedar Lake is about 15 to 20 years. For travel times greater than 15 or 20 years, the ground-water recharge area for Little Cedar Lake and inflow from Big Cedar Lake also should be considered recharge affecting Silver Lake. Solute flux toward Silver Lake was calculated based on simulated ground-water flux and measured concentrations in the upgradient piezometers and observation wells.

Benzene contamination at a metal plating facility

NASA Astrophysics Data System (ADS)

Memon, B. A.; Burston, M. R.

2005-08-01

A metal plating facility in central Kentucky was required to complete a RCRA Facility Investigation to address a number of Solid Waste Management Units at the site. Twenty monitoring wells were installed at the facility. Ground water from the wells was sampled for total and dissolved metals, polychlorinated biphenyls, acid extractable compounds, base neutral compounds, and volatile organic compounds. Unexpectedly, relatively large concentrations of benzene, up to 120 μg/l, were detected in samples from some of the wells, including wells that should have been hydraulically upgradient from the facility. As a result of the detection of benzene, the facility completed an investigation to identify the source. A nearby facility had completed a gasoline underground storage tank (UST) closure at about the time of the installation of the 20 wells. Reportedly the UST had small holes when removed. Three potential pathways of migration (a ditch, sanitary sewer, and a sink hole) from the nearby facility to the metal-plating facility and residual soils with very large concentrations of benzene, toluene, ethylbenzene, and xylenes have been identified.

Effects of nutrient management on nitrate levels in ground water near Ephrata Pennsylvania

USGS Publications Warehouse

Hall, David W.

1992-01-01

Effects of the implementation of nutrient management practices on ground-water quality were studied at a 55-acre farm in Lancaster County, Pennsylvania, from 1985-90. After nutrient management practices were implemented at the site in October 1986, statistically significant decreases (Wilcoxon Mann-Whitney test) in median nitrate concentrations in ground-water samples occurred at four of the five wells monitored. The largest decreases in nitrate concentration occurred in samples collected at the wells that had the largest nitrate concentrations prior to nutrient management. The decreases in median nitrate concentrations in ground-water samples ranged from 8 to 32 percent of the median concentrations prior to nutrient management and corresponded to nitrogen application decreases of 39 to 67 percent in contributing areas that were defined upgradient of these wells. Changes in nitrogen applications to the contributing areas of five water wells were correlated (Spearman rank-sum test) with nitrate concentrations of the well water. Changes in ground-water nitrate concentrations lagged behind the changes in applied-nitrogen fertilizers (primarily manure) by approximately 4 to 19 months.

INVESTIGATION OF VERTICAL DISTRIUBTION AND MORPHO- LOGY OF INDIGENOUS ORGANIC MATTER AT SLEEPING BEAR SITE, MICHIGAN

EPA Science Inventory

This study evaluates the nature and origin of particulate organic carbon and organic coatings on aquifer sands upgradient from a fuel spill site near the Sleeping Bear Dunes National Lakeshore in Michigan. The distribution of carbon was found to be highly complex due to the occur...

STABLE CARBON ISOTOPE BIOGEOCHEMISTRY OF A SHALLOW SAND AQUIFER CONTAMINATED WITH FUEL HYDROCARBONS

EPA Science Inventory

Ground-water chemistry and the stable C isotope composition ( 13CDIC) of dissolved C (DIC) were measured in a sand aquifer contaminated with JP-4 fuel hydrocarbons. Results show that ground water in the upgradient zone was characterized by DIC content of 14-20 mg C/L and 13CDIC...

Using chemical, hydrologic, and age dating analysis to delineate redox processes and flow paths in the riparian zone of a glacial outwash aquifer‐stream system

USGS Publications Warehouse

Puckett, Larry J.; Cowdery, Timothy K.; McMahon, Peter B.; Tornes, Lan H.; Stoner, Jeffrey D.

2002-01-01

A combination of chemical and dissolved gas analyses, chlorofluorocarbon age dating, and hydrologic measurements were used to determine the degree to which biogeochemical processes in a riparian wetland were responsible for removing NO3−from groundwaters discharging to the Otter Tail River in west central Minnesota. An analysis of river chemistry and flow data revealed that NO3− concentrations in the river increased in the lower half of the 8.3 km study reach as the result of groundwater discharge to the river. Groundwater head measurements along a study transect through the riparian wetland revealed a zone of groundwater discharge extending out under the river. On the basis of combined chemical, dissolved gas, age date, and hydrologic results, it was determined that water chemistry under the riparian wetland was controlled largely by upgradient groundwaters that followed flow paths up to 16 m deep and discharged under the wetland, creating a pattern of progressively older, more chemically reduced, low NO3− water the farther one progressed from the edge of the wetland toward the river. These findings pose challenges for researchers investigating biogeochemical processes in riparian buffer zones because the progressively older groundwaters entered the aquifer in earlier years when less NO3− fertilizer was being used. NO3− concentrations originally present in the groundwater had also decreased in the upgradient aquifer as a result of denitrification and progressively stronger reducing conditions there. The resulting pattern of decreasing NO3− concentrations across the riparian zone may be incorrectly interpreted as evidence of denitrification losses there instead of in the upgradient aquifer. Consequently, it is important to understand the hydrogeologic setting and age structure of the groundwaters being sampled in order to avoid misinterpreting biogeochemical processes in riparian zones.

Determination of Moisture Content in Coke with 239Pu-Be Neutron Source and BGO Scintillation Gamma Detector

NASA Astrophysics Data System (ADS)

Grozdanov, D. N.; Aliyev, F. A.; Hramco, C.; Kopach, Yu. N.; Bystritsky, V. M.; Skoy, V. R.; Gundorin, N. A.; Ruskov, I. N.

2018-03-01

A series of experiments has been conducted at the Frank Laboratory of Neutron Physics (FLNP) of the Joint Institute for Nuclear Research (JINR) in order to study the possibility of determining the moisture content of coke using a standard neutron source. The proposed method is based on a measurement of the spectrum of prompt γ rays emitted when samples are irradiated by fast and/or thermal neutrons. The moisture content is determined from the area of the peaks of characteristic γ rays produced in the radiative capture of thermal neutrons by the proton ( E γ = 2.223 MeV) and inelastic scattering of fast neutrons by 16O (Eγ = 6.109 MeV). The 239Pu-Be neutron source (< E n > 4.5 MeV) with an intensity of 5 × 106 n/s was used to irradiate the samples under study. A scintillation detector based on a BGO crystal was used to register the characteristic γ radiation from the inelastic fast neutron scattering and slow (thermal) neutron capture. This paper presents the results of humidity measurement in the range of 2-50% [1, 2].

A comparative study of the luminescence properties of LYSO:Ce, LSO:Ce, GSO:Ce and BGO single crystal scintillators for use in medical X-ray imaging.

PubMed

Valais, I; Michail, C; David, S; Nomicos, C D; Panayiotakis, G S; Kandarakis, I

2008-06-01

The present study is a comparative investigation of the luminescence properties of (Lu,Y)(2)SiO(5):Ce (LYSO:Ce), Lu(2)SiO(5):Ce (LSO:Ce), Gd(2)SiO(5):Ce (GSO:Ce) and (Bi(4)Ge(3)O(12)) BGO single crystal scintillators under medical X-ray excitation. All scintillating crystals have dimensions of 10 x 10 x 10 mm(3) are non-hygroscopic exhibiting high radiation absorption efficiency in the energy range used in medical imaging applications. The comparative investigation was performed by determining the absolute luminescence efficiency (emitted light flux over incident X-ray exposure) in X-ray energies employed in general X-ray imaging (40-140 kV) and in mammographic X-ray imaging (22-49 kV). Additionally, light emission spectra of crystals at various X-ray energies were measured, in order to determine the spectral compatibility to optical photon detectors incorporated in medical imaging systems and the overall efficiency (effective efficiency) of a scintillator-optical detector combination. The light emission performance of LYSO:Ce and LSO:Ce scintillators studied was found very high for X-ray imaging.

Study on the PGNAA measurement of heavy metals in aqueous solution by the Monte Carlo-Library Least-Squares (MCLLS) approach.

PubMed

Zhang, Yan; Jia, WenBao; Gardner, Robin; Shan, Qing; Hei, Daqian

2018-02-01

In the present work, a prompt gamma neutron activation analysis (PGNAA) setup, which consists of a 300mCi 241 Americium-Beryllium (Am-Be) neutron source and a 4 × 4-in. Bismuth germanium oxide (BGO) detector, was developed for heavy metal detection in aqueous solutions. A series of standard samples with analytical purity were prepared by dissolving heavy metals in deionized water. Quantitative spectrum analysis was performed by the Monte Carlo-Least-Squares (MCLLS) approach to measure the standard samples. The detector response functions of 4 × 4-in. BGO detector were generated by using the CEARDRF code. The element libraries were simulated in silico by the CEARCPG code, which was developed by Dr. Gardner. The simulation results presented were in very good agreement with the experimental results. The correlation coefficients were very close to 1 when the fitted spectrum was compared with the experimental spectrum. By applying the MCLLS approach, the relative deviation of the measurement accuracy was less than 2.27% for Ni, Mn, and Cu and up to 69.33% for Pb. Copyright © 2017 Elsevier Ltd. All rights reserved.

Bioavailable Ferric Iron (BAFelll) Assay

DTIC Science & Technology

2007-02-01

citrate dithionite bicarbonate CDBFe citrate dithionite bicarbonate extractable iron cDCE cis-Dichloroethene CDM Camp Dresser & McKee Inc...Defense (DoD) installations. Camp Dresser & McKee Inc. (CDM), in cooperation with the Naval Facilities Engineering Services Center (NFESC), was the...several upgradient and/or cross - gradient background soil samples. Duplicate analysis of samples is recommended. While these recommendations are not

Chromium Isotopic Monitoring of HRC-Stimulated Bio-containment at the 100H Test Site, Hanford, Washington

NASA Astrophysics Data System (ADS)

Christensen, J. N.; Brown, S. T.; Brodie, E. L.; Chakraborty, R.; Conrad, M. E.; Long, P. E.; Faybishenko, B.; Hazen, T. C.

2007-12-01

Hexavalent Cr (Cr(VI)) groundwater contamination is a common problem in the U.S. associated with industrial activity (e.g. electroplating, tanning, paints, anti-corrosion). In the particular case of the Hanford Site, Washington, chromate was used primarily to inhibit corrosion in nuclear reactor cooling systems. During the active operation of the Hanford Site, disposal of waste water bearing chromate, and accidental releases to the vadose zone resulted in significant groundwater contamination with local concentrations near the Columbia river reaching over 1000 ppb Cr(VI). In an effort to test an effective bio-containment strategy for groundwater Cr(VI), a site was selected between the 100D and 100H reactor areas with modest concentrations (~100 ppb Cr(VI) over the past two decades). A slow-release 13C labeled polylactate amendment (HRCTM, Regenesis, Ltd.) was injected into groundwater within a sandy formation to stimulate bacterial activity in order to produce conditions that promote the reduction of dissolved Cr(VI) to insoluble Cr(III) complexes [1]. Since the injection of HRCTM in August 2004, groundwater Cr(VI) concentration has been locally below 1 ppb, and reducing conditions have been maintained to at least the present time. The isotopic composition of Cr can be fractionated during reduction from Cr(VI) to Cr(III) and so has the potential to be used as a monitor of hexavalent Cr reduction [2, 3]. This would provide a direct signature of Cr(VI) reduction, discernable from simple attenuation by dilution. In order to explore the use of Cr isotopic measurements for evaluating processes of Cr(VI) reduction, we have analyzed a series of samples in space and time for Cr isotopic composition (δ53Cr, permil deviation of sample 53Cr/52Cr from that of SRM970). Groundwater samples came from the HRC injection well, from multiple depths of three down-gradient wells, and from an up-gradient well. Samples from down-gradient wells have Cr that is isotopically fractionated relative to samples from the up-gradient well. Taken together, samples from a single sampling campaign yield an apparent fractionation of 2.2 ‰. Cr isotopic measurements of the latest samples (June, 2007) confirm continued reduction of Cr(VI) nearly three years after the introduction of HRCTM, suggesting the long-term effectiveness of this bio-stimulated containment strategy. [1] http://esd.lbl.gov/ERT/hanford100h/ [2] Ellis, AS, Johnson, TM and Bohlen, TD (2002) Science. 295:2060-2062. [3] Johnson, TM and Bohlen, TD (2004) Reviews in Mineralogy and Geochemistry, Vol. 55, p.289-317.

Use of environmental tracers to study the chemical evolution of shallow ground water in a karst area of northern Florida

DOE Office of Scientific and Technical Information (OSTI.GOV)

Katz, B.G.; Plummer, L.N.; Busenberg, E.

1993-03-01

The pathways of shallow ground-water flow in poorly confined aquifer systems of northern FL are influenced by inflow to and outflow from numerous sinkhole lakes that are characteristic of the Sand Hills karst region. Ground-water samples were collected immediately upgradient and downgradient from Lake Barco at depths of 1.6--29 m below the water table from observation wells completed in the surficial aquifer system, the intermediate confining unit (icu), and the Upper Floridan aquifer. Samples were also collected of rainfall, lake water, and ground water at a depth of 4.1 m beneath the lake bottom. The environmental tracers tritium and chlorofluorocarbonsmore » were used to estimate mean residence times of water and rates of chemical mass transfer along flow paths. Water samples collected from wells upgradient of the lake were oxic and had CFC-model recharge dates between 1971 and 1986. The content of delta H-2 and delta O-18 of water from the two aquifer systems and the icu was nearly identical to the isotopic composition of rainfall. Changes in the chemical composition of the ground water with depth were simulated by reacting rainfall with minerals and dissolved gases that exist in the hydrogeologic units. Ground-water samples collected from sites beneath and downgradient of the lake were anoxic, with measured concentrations of hydrogen sulfide and methane ranging from 0.02--0.58 mg/l and 0.30--6.1 mg/l, respectively. CFC-model recharge dates ranged from 1956 to 1983. The data indicated that ground water downgradient of the lake is being recharged by leakage of lake water. The chemical composition of ground water is influenced by the movement of lake water through reducing, organic-rich sediments accumulated at the bottom. Along the downgradient flow paths, the water chemistry evolves from the composition of lake water and is modified by subsequent reactions including reduction of sulfate and ferric iron, methanogenesis, and dissolution and precipitation of minerals.« less

Flow paths in the Edwards aquifer, northern Medina and northeastern Uvalde counties, Texas, based on hydrologic identification and geochemical characterization and simulation

USGS Publications Warehouse

Clark, Allan K.; Journey, Celeste A.

2006-01-01

The U.S. Geological Survey, in cooperation with the San Antonio Water System, conducted a 4-year study during 2001– 04 to identify major ground-water flow paths in the Edwards aquifer in northern Medina and northeastern Uvalde Counties, Texas. The study involved use of geologic structure, surfacewater and ground-water data, and geochemistry to identify ground-water flow paths. Relay ramps and associated faulting in northern Medina County appear to channel ground-water flow along four distinct flow paths that move water toward the southwest. The northwestern Medina flow path is bounded on the north by the Woodard Cave fault and on the south by the Parkers Creek fault. Water moves downdip toward the southwest until the flow encounters a cross fault along Seco Creek. This barrier to flow might force part or most of the flow to the south. Departure hydrographs for two wells and discharge departure for a streamflow-gaging station provide evidence for flow in the northwestern Medina flow path. The north-central Medina flow path (northern part) is bounded by the Parkers Creek fault on the north and the Medina Lake fault on the south. The adjacent north-central Medina flow path (southern part) is bounded on the north by the Medina Lake fault and on the south by the Diversion Lake fault. The north-central Medina flow path is separated into a northern and southern part because of water-level differences. Ground water in both parts of the northcentral Medina flow path moves downgradient (and down relay ramp) from eastern Medina County toward the southwest. The north-central Medina flow path is hypothesized to turn south in the vicinity of Seco Creek as it begins to be influenced by structural features. Departure hydrographs for four wells and Medina Lake and discharge departure for a streamflow-gaging station provide evidence for flow in the north-central Medina flow path. The south-central Medina flow path is bounded on the north by the Seco Creek and Diversion Lake faults and on the south by the Haby Crossing fault. Because of bounding faults oriented northeast-southwest and adjacent flow paths directed south by other geologic structures, the south-central Medina flow path follows the configuration of the adjacent flow paths—oriented initially southwest and then south. Immediately after turning south, the south-central Medina flow path turns sharply east. Departure hydrographs for four wells and discharge departure for a streamflow-gaging station provide evidence for flow in the south-central Medina flow path. Statistical correlations between water-level departures for 11 continuously monitored wells provide additional evidence for the hypothesized flow paths. Of the 55 combinations of departure dataset pairs, the stronger correlations (those greater than .6) are all among wells in the same flow path, with one exception. Simulations of compositional differences in water chemistry along a hypothesized flow path in the Edwards aquifer and between ground-water and surface-water systems near Medina Lake were developed using the geochemical model PHREEQC. Ground-water chemistry for samples from five wells in the Edwards aquifer in the northwestern Medina flow path were used to evaluate the evolution of ground-water chemistry in the northwestern Medina flow path. Seven simulations were done for samples from pairs of these wells collected during 2001–03; three of the seven yielded plausible models. Ground-water samples from 13 wells were used to evaluate the evolution of ground-water chemistry in the north-central Medina flow path (northern and southern parts). Five of the wells in the most upgradient part of the flow path were completed in the Trinity aquifer; the remaining eight were completed in the Edwards aquifer. Nineteen simulations were done for samples from well pairs collected during 1995–2003; eight of the 19 yielded plausible models. Ground-water samples from seven wells were used to evaluate the evolution of ground-water chemistry in the south-central Medina flow path. One well was the Trinity aquifer end-member well upgradient from all flow paths, and another was a Trinity aquifer well in the most upgradient part of the flow path; all other wells were completed in the Edwards aquifer. Nine simulations were done for samples from well pairs collected during 1996–2003; seven of the nine yielded plausible models. The plausible models demonstrate that the four hypothesized flow paths can be partially supported geochemically. 

A three-dimensional analytical model to simulate groundwater flow during operation of recirculating wells

NASA Astrophysics Data System (ADS)

Huang, Junqi; Goltz, Mark N.

2005-11-01

The potential for using pairs of so-called horizontal flow treatment wells (HFTWs) to effect in situ capture and treatment of contaminated groundwater has recently been demonstrated. To apply this new technology, design engineers need to be able to simulate the relatively complex groundwater flow patterns that result from HFTW operation. In this work, a three-dimensional analytical solution for steady flow in a homogeneous, anisotropic, contaminated aquifer is developed to efficiently calculate the interflow of water circulating between a pair of HFTWs and map the spatial extent of contaminated groundwater flowing from upgradient that is captured. The solution is constructed by superposing the solutions for the flow fields resulting from operation of partially penetrating wells. The solution is used to investigate the flow resulting from operation of an HFTW well pair and to quantify how aquifer anisotropy, well placement, and pumping rate impact capture zone width and interflow. The analytical modeling method presented here provides a fast and accurate technique for representing the flow field resulting from operation of HFTW systems, and represents a tool that can be useful in designing in situ groundwater contamination treatment systems.

Evaluation of perchlorate sources in the Rialto-Colton and Chino California subbasins using chlorine and oxygen isotope ratio analysis

USGS Publications Warehouse

Hatzinger, Paul B.; Böhlke, John Karl; Izbicki, John; Teague, Nicholas F.; Sturchio, Neil C.

2015-01-01

Perchlorate (ClO4-) in groundwater can be from synthetic or natural sources, the latter of which include both historical application of imported nitrate fertilizers from the Atacama Desert of Chile and naturally deposited ClO4- that forms atmospherically and accumulates in arid regions such as the southwestern US. The objective of this study was to evaluate the use of isotopic data to distinguish sources of ClO4- in groundwater in a specific region of the Rialto-Colton and Chino, CA groundwater subbasins (Study Area). This region includes two groundwater ClO4- plumes emanating from known military/industrial source areas, and a larger area outside of these plumes having measurable ClO4-. Perchlorate extracted from wells in this region was analyzed for chlorine and oxygen stable isotope ratios (δ37Cl, δ18O, δ17O) and radioactive chlorine-36 (36Cl) isotopic abundance, along with other geochemical, isotopic, and hydrogeologic data. Isotope data indicate synthetic, Atacama, and indigenous natural ClO4- were present in the Study Area. Stable isotope data from nearly all sampled wells within the contours of the two characterized plumes, including those located in a perched zone and within the regional groundwater aquifer, were consistent with a dominant synthetic ClO4- source. In wells downgradient from the synthetic plumes and in the Chino subbasin to the southwest, isotopic data indicate the dominant source of ClO4- largely was Atacama, presumably from historical application of nitrate fertilizer in this region. Past agricultural land use and historical records are consistent with this source being present in groundwater. The 36Cl and δ18O data indicate that wells having predominantly synthetic or Atacama ClO4- also commonly contained small fractions of indigenous natural ClO4-. The indigenous ClO4- was most evident isotopically in wells having the lowest overall ClO4- concentrations (< 1 μg/L), consistent with its occurrence as a low-level background constituent in the region. A small subset of wells outside the contours of the two synthetic plumes, including an upgradient well, had characteristics indicating small amounts of synthetic ClO4- mixed with one or both of the natural source types. Hydrogeologic data indicate synthetic ClO4- in the upgradient well may be from a source other than the identified plume sources, but it is not known whether this source might also be present in other wells at low concentrations. The stable isotope and 36Cl data provided relatively unambiguous discrimination of synthetic and Atacama ClO4- sources in most wells having relatively high concentrations, providing regional perspective on anthropogenic ClO4- contamination in the Rialto-Colton and Chino subbasins. Where indigenous natural ClO4- was indicated as a substantial component, total ClO4- concentrations were low and concentrations of anthropogenic components were near background levels.

A fast and compact electromagnetic calorimeter for the PANDA detector at FAIR

DOE Office of Scientific and Technical Information (OSTI.GOV)

Wilms, Andrea

2005-10-26

In this presentation we report on the electromagnetic calorimeter of the 4{pi} detector PANDA to be installed at the antiproton storage ring of the proposed Facility for Antiproton and Ion Research (FAIR). We present details of the R and D work with two scintillator materials, PbWO4 (PWO) and BGO, and the new developed large area avalanche photodiodes (LAAPDs) as detector readout.

Compton suppression and event triggering in a commercial data acquisition system

NASA Astrophysics Data System (ADS)

Tabor, Samuel; Caussyn, D. D.; Tripathi, Vandana; Vonmoss, J.; Liddick, S. N.

2012-10-01

A number of groups are starting to use flash digitizer systems to directly convert the preamplifier signals of high-resolution Ge detectors to a stream of digital data. Some digitizers are also equipped with software constant fraction discriminator algorithms capable of operating on the resulting digital data stream to provide timing information. Because of the dropping cost per channel of these systems, it should now be possible to also connect outputs of the Bismuth Germanate (BGO) scintillators used for Compton suppression to other digitizer inputs so that BGO logic signals can also be available in the same system. This provides the possibility to perform all the Compton suppression and multiplicity trigger logic within the digital system, thus eliminating the need for separate timing filter amplifiers (TFA), constant fraction discriminators (CFD), logic units, and lots of cables. This talk will describe the performance of such a system based on Pixie16 modules from XIA LLC with custom field programmable gate array (FPGA) programming for an array of Compton suppressed single Ge crystal and 4-crystal ``Clover'' detector array along with optional particle detectors. Initial tests of the system have produced results comparable with the current traditional system of individual electronics and peak sensing analog to digital converters. The advantages of the all digital system will be discussed.

Precision measurement of ^23Al beta-decay

NASA Astrophysics Data System (ADS)

Zhai, Yongjun; Iacob, V. E.; Hardy, J. C.; Al-Abdullah, T.; Banu, A.; Fu, C.; Golovko, V. V.; McCleskey, M.; Nica, N.; Park, H. I.; Tabacaru, G.; Tribble, R. E.; Trache, L.

2007-10-01

The beta-decay of ^23Al (See [1]) was re-measured with higher statistics and better accuracy at Texas A&M University. Using MARS we produced and separated pure ^23Al at 4000 pps, with a 48 MeV/u ^24Mg beam via the ^24Mg (p, 2n)^ 23Al reaction on a H2 cryogenic target. New β and β-γ coincidence measurements were made with a scintillator, an HPGe detector with BGO shielding and the fast tape transport system. The BGO Compton shield very much improved the quality of the γ spectra around the transition from the IAS state at 7803 keV. From the measured β singles and β-γ coincidence decay spectra we obtained an improved β-decay scheme and a more precise lifetime: t=447(4) ms. We use the method of detailed balance to obtain absolute β-branching ratios and absolute logft values for transitions to final states in ^23Mg. For this method, precise efficiency calibration of the HPGe detector up to about 8 MeV is needed. We extended our previous efficiency calibration to the range Eγ=3.5-8 MeV using the β-decay of ^24Al. [1] V.E. Iacob, Y. Zhai et al., Phys. Rev. C 74, 045810 (2006).

Comparison of Fluka-2006 Monte Carlo Simulation and Flight Data for the ATIC Detector

NASA Technical Reports Server (NTRS)

Gunasingha, R.M.; Fazely, A.R.; Adams, J.H.; Ahn, H.S.; Bashindzhagyan, G.L.; Chang, J.; Christl, M.; Ganel, O.; Guzik, T.G.; Isbert, J.;

Effects of increased shielding on gamma-radiation levels within spacecraft

NASA Astrophysics Data System (ADS)

Haskins, P. S.; McKisson, J. E.; Weisenberger, A. G.; Ely, D. W.; Ballard, T. A.; Dyer, C. S.; Truscott, P. R.; Piercey, R. B.; Ramayya, A. V.; Camp, D. C.

The Shuttle Activation Monitor (SAM) experiment was flown on the Space Shuttle Columbia (STS-28) from 8 - 13 August, 1989 in a 57°, 300 km orbit. One objective of the SAM experiment was to determine the relative effect of different amounts of shielding on the gamma-ray backgrounds measured with similarly configured sodium iodide (NaI) and bismuth germante (BGO) detectors. To achieve this objective twenty-four hours of data were taken with each detector in the middeck of the Shuttle on the ceiling of the airlock (a high-shielding location) as well as on the sleep station wall (a low-shielding location). For the cosmic-ray induced background the results indicate an increased overall count rate in the 0.2 to 10 MeV energy range at the more highly shielded location, while in regions of trapped radiation the low shielding configuration gives higher rates at the low energy end of the spectrum.

Pesticides in surface water, bed sediment, and ground water adjacent to commercial cranberry bogs, Lac du Flambeau Reservation, Vilas County, Wisconsin

USGS Publications Warehouse

Saad, David A.

2005-01-01

In samples from the Trout River, which is used as a source of water to maintain lake levels in the Corn Lakes, the only pesticides detected were the non-targeted compounds atrazine and deethyl atrazine, indicating it was not a source of targeted compounds detected in the Corn Lakes. Only two pesticides (chlorpyrifos and metolachlor) were detected in bed-sediment samples collected from the lakes; chlorpyrifos from Little Trout Lake and metolachlor from the Corn Lakes. Four pesticides (the targeted compounds napropamide and norflurazon and the non-targeted compounds atrazine and deethyl atrazine) were detected in ground-water samples from two of four sampled monitor wells. The highest ground-water concentrations (up to 0.14 ?g/L napropamide and 0.56 ?g/L norflurazon) were measured in samples from the monitoring well located directly downgradient from the Corn Lakes and commercial cranberry operations. No pesticides were detected in samples from the reference well located upgradient from the Corn Lakes and cranberry operations. Further study is needed to identify additional pesticides as well as chronic effects on aquatic organisms to determine whether cranberry-related pesticides affect the lake ecosystems of the Lac du Flambeau Reservation.

Wilson Corners SWMU 001 2015 Annual Long Term Monitoring Report Kennedy Space Center, Florida

NASA Technical Reports Server (NTRS)

Lawson, Emily M.

2016-01-01

This document presents the findings of the 2015 Long Term Monitoring (LTM) that was completed at the Wilson Corners site, located at the National Aeronautics and Space Administration John F. Kennedy Space Center, Florida. The objectives of the 2015 LTM event were to evaluate the groundwater flow direction and gradient, to monitor the vertical and horizontal extent of the volatile organic compounds (VOCs; including the upgradient and sidegradient extents, which are monitored every five years), and to monitor select locations internal to the dissolved groundwater plume. The 2015 LTM event included several upgradient and sidegradient monitoring wells that are not sampled annually to verify the extent of VOCs in this portion of the site. The December 2015 LTM groundwater sampling event included, depth to groundwater measurements, 40 VOC samples collected using passive diffusion bags, and one VOC sample collected using low-flow techniques. Additionally, monitoring well MW0052DD was overdrilled and abandoned using rotasonic drilling techniques. The following conclusions can be made based on the 2015 LTM results: groundwater flow is generally to the west with northwest and southwest flow components from the water table to approximately 55 feet below land surface (ft BLS); peripheral monitoring wells generally delineate VOCs to groundwater cleanup target levels (GCTLs) except for monitoring wells MW0088, MW0090, MW0095, and NPSHMW0039, which had vinyl chloride (VC) concentrations near the GCTL and MW0062, which had trichloroethene (TCE), cis-1,2-dichloroethenen (cDCE), and VC concentrations above natural attenuation default concentrations (NADCs); VOCs in interior downgradient wells generally fluctuate within historic ranges except for monitoring wells in the north-northwest portion of the site, which have increasing VC concentrations indicating potential plume migration and expansion; Historically, the vertical extents of the VOCs were delineated by monitoring wells screened greater than 60 ft BLS (MW0083 through MW0086, and MW0078). The 2015 LTM results indicate that concentrations of daughter product cDCE is greater than the NADC in MW0078 and that cDCE and VC are greater than NADCs in MW0130. TCE was greater than the GCTL in monitoring well MW130 and not detected above method detection limits (9 micrograms per Liter) in monitoring well MW0078. No GCTL exceedances were identified in monitoring wells MW0083 or MW0086; the dissolved plume footprint appears generally stable, though not fully delineated by monitoring well data in the northeast portion of the site; and 2015 LTM results generally support the existing Conceptual Site Model. Geosyntec recommends modifying the LTM program, collecting a verification sample from monitoring well MW0062, and performing a direct push technology instigation in the northnortheastern portion of the site. A cluster of monitoring wells (MW0132 [2 to 12 ft BLS], MW0133 [15 to 25 ft BLS], and MW0134 [29 to 34 ft BLS]) is proposed to delineate impacts in the northnortheast portion of the site. Geosyntec recommends installation of a vertical extent well in the center of the site (Hot Spot 2 area) post-remediation implementation.

The travel-time ellipse: An approximate zone of transport

USGS Publications Warehouse

Almendinger, J.E.

1994-01-01

A zone of transport for a well is defined as the area in the horizontal plane bounded by a contour of equal ground-water travel time to the well. For short distances and ground-water travel times near a well, the potentiometric surface may be simulated analytically as that for a fully penetrating well in a uniform flow field. The zone of transport for this configuration is nearly elliptical. A simple method is derived to calculate a travel-time ellipse that approximates the zone of transport for a well in a uniform flow field. The travel-time ellipse was nearly congruent with the exact solution for the theoretical zone of transport for ground-water travel times of at least 10 years and for aquifer property values appropriate for southeastern Minnesota. For distances and travel times approaching infinity, however, the ellipse becomes slightly wider at its midpoint and narrower near its upgradient boundary than the theoretical zone of transport. The travel-time ellipse also may be used to simulate the plume area surrounding an injection well. However, the travel-time ellipse is an approximation that does not account for the effect of dispersion in enlarging the true area of an injection plume or zone of transport; hence, caution is advised in the use and interpretation of this simple construction.

Measurement of radiation damage on an epoxy-based optical glue

NASA Astrophysics Data System (ADS)

Huang, H. C.; Peng, K. C.; Sahu, S. K.; Ueno, K.; Chang, Y. H.; Wang, C. H.; Hou, W. S.

1997-02-01

We measured the radiation damage on an optical glue called Eccobond-24, which is a candidate for CsI and BGO crystal calorimeters of the BELLE detector of the KEK B-factory. Absorption spectrophotometry in the range 300-800 nm was used to monitor the radiation damage. The maximum equivalent dose was 1.64 Mrad. The glue shows effects of damage, but is acceptable for the radiation level in the above-mentioned experiment.

Performance of a junction termination extension avalanche photodiode for use with scintillators

NASA Astrophysics Data System (ADS)

Gramsch, E.; Pcheliakov, O.; Chistokhin, Igor B.

2008-11-01

An avalanche photodiode with a ring structure called junction termination extension (JTE) was built and tested. It has three diffused rings around the main junction to avoid early breakdown at the surface. The ITE rings have less doping than the main junction and can be built by well controlled single ion-implantation through a single mask. Avalanche photodiodes with two mm diameter active area have been have been built by implantation of boron with a dose of 2, 3, 4 and 5 × 1012 cm-2, followed by deep diffusion of the junction up to 14 μm. The dark current is strongly dependent on the implantation dose, decreasing with decreasing charge. For the APDs with implanted dose of 5 × 1012 cm-2 a gain of 8 is obtained at 1120 V. The energy resolution from a 137Cs source was measured to be 24.4% FWHM with a 2 × 2 × 2 mm3 BGO scintillator. We have also performed simulations of the gain and breakdown voltage that correlate well with the results.

Hydrogeology and water quality in the Snake River alluvial aquifer at Jackson Hole Airport, Jackson, Wyoming, September 2008-June 2009

USGS Publications Warehouse

Wright, Peter R.

2010-01-01

The hydrogeology and water quality of the Snake River alluvial aquifer, at the Jackson Hole Airport in northwest Wyoming, was studied by the U.S. Geological Survey in cooperation with the Jackson Hole Airport Board and the Teton Conservation District during September 2008-June 2009. Hydrogeologic conditions were characterized using data collected from 14 Jackson Hole Airport wells. Groundwater levels are summarized in this report and the direction of groundwater flow, hydraulic gradients, and estimated groundwater velocity rates in the Snake River alluvial aquifer underlying the study area are presented. Analytical results of chemical, dissolved gas, and stable isotopes are presented and summarized. Seasonally, the water table at Jackson Hole Airport was lowest in early spring and reached its peak in July, with an increase of 12 to 14 feet between April and July 2009. Groundwater flow was predominantly horizontal but had the hydraulic potential for downward flow. The direction of groundwater flow was from the northeast to the west-southwest. Horizontal groundwater velocities within the Snake River alluvial aquifer at the airport were estimated to be about 26 to 66 feet per day. This indicates that the traveltime from the farthest upgradient well to the farthest downgradient well was approximately 53 to 138 days. This estimate only describes the movement of groundwater because some solutes may move at a rate much slower than groundwater flow through the aquifer. The quality of the water in the alluvial aquifer generally was considered good. The alluvial aquifer was a fresh, hard to very hard, calcium carbonate type water. No constituents were detected at concentrations exceeding U.S. Environmental Protection Agency Maximum Contaminant Levels, and no anthropogenic compounds were detected at concentrations greater than laboratory reporting levels. The quality of groundwater in the alluvial aquifer generally was suitable for domestic and other uses; however, dissolved iron and manganese were detected at concentrations exceeding the U.S. Environmental Protection Agency Secondary Maximum Contaminant Levels for drinking water in two monitoring wells. These secondary standards are esthetic guidelines only and are nonenforceable. Iron and manganese are likely both natural components of the geologic materials in the area and may have become mobilized in the aquifer due to reduction/oxidation (redox) processes. Additionally, measurements of dissolved-oxygen concentrations and analyses of major ions and nutrients indicate reducing conditions exist at two of the seven wells sampled. Reducing conditions in an otherwise oxic aquifer system are indicative of an upgradient or in-situ source of organic carbon. The nature of the source of organic carbon at the airport could not be determined. View report for unabridged abstract.

Effectiveness of an alluvial wetland on improving ground-water quality in a municipal well field, Cedar Rapids, Iowa, 1998-2006

USGS Publications Warehouse

Schnoebelen, Douglas J.

2008-01-01

An alluvial wetland proved useful in improving water quality. Samples from observation wells completed in the alluvial wetland near the municipal well field had nitrate concentrations that were four to six times lower when compared to river or upland sites; however, iron and manganese concentrations in samples from observation wells in the wetland areas were an order of magnitude higher when compared to the river or an upgradient well. Biological and chemical reduction processes were determined to mobilize inorganic constituents in accordance with physical chemistry principles. Generally, selected pesticides and two pesticide degradates of atrazine that were sampled for in alluvial wetland wells remained relatively unchanged, and indicated only a slight decrease in concentration compared to the Cedar River water samples. Pesticides were not detected above regulatory limits in any of the observation wells; however, one sample from the Cedar River had an atrazine detection at 4.5 micrograms per liter, which is above the maximum contaminant level of 3.0 micrograms per liter for drinking-water regulations for that compound. Results indicate that alluvial wetlands may provide substantial reductions of nitrate concentrations in ground water, and may be a useful strategy for the reduction of nitrate for municipal wells. Results for reducing pesticides were less dramatic than for nitrate, as pesticide concentrations were reduced slightly from the river to the wetland.

US Environmental rotection Agency's strategy for ground-water-quality monitoring at hazardous-waste land-disposal facilities located in karst terranes

DOE Office of Scientific and Technical Information (OSTI.GOV)

Field, M.S.

1988-11-01

Ground-water monitoring of hazardous-waste land-disposal units by a network of wells is ineffective when located in karstic terranes. The U.S. Environmental Protection Agency (EPA) is currently proposing to modify its current ground-water-quality monitoring requirement of one upgradient well and three downgradient wells for disposal units located in karstic terranes. The convergent nature of subsurface flow to cave streams in karstic terranes requires that effective monitoring wells intercept the cave streams. Wells located around a hazardous-waste disposal unit, but not in the specific cave stream draining the site, are only providing irrelevant data and a false sense of security because themore » water samples from such wells are not necessarily from the hazardous-waste disposal unit. A case study is provided in this paper. EPA is drafting a guidance document that will allow monitoring by wells, only if the up- and down-gradient wells can be demonstrated to be hydraulically connected by means of dye-trace studies. If not, then the monitoring of springs shown to be hydraulically connected to the facility by dye-tracing studies would be required. Monitoring for sinkhole development will also be required to provide advance warning of sinkhole collapse. The investigation and determination of the probability of sinkhole collapse is given special treatment.« less

The First Flight of ATIC: Preliminary Results on Li, Be, B Nuclei

NASA Technical Reports Server (NTRS)

Zatsepin, V. I.; Adams, J. H.; Ahn, H.; Ampe, J.; Bashindzhagyan, G.; Case, G.; Whitaker, Ann F. (Technical Monitor)

2001-01-01

The ATIC (Advanced Thin Ionization Calorimeter) balloon experiment had its first test flight which lasted for 16 days and brought it around Antarctica. The ATIC spectrometer consists of a fully active BGO (Bismuth Germanate) calorimeter, scintillator hodoscopes and a silicon matrix. The silicon matrix consisted of 4480 pixels was used as a charge detector in the experiment. We discuss a possibility of the ATIC to measure individual energy spectra of Li, Be and B.

A High Resolution Clinical PET with Breast and Whole Body Transfigurations

DTIC Science & Technology

2006-08-01

1999. [6] Inst. Inorganic Chemistry, Siberian Branch, Russian Acad. Sci. 3, Acad. Lavrentyev Prospect, Novosibirsk, Russia. [7] White Reflecting Paint...46, no.6, pp. 491-497, 1999. [6] Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Science 3, Acad.Lavrentyev Prospect, 630090...demanding, higher spatial resolution 8 x 8 array (2.3 x 2.3 x 10 mm BGO) for mouse PET with shallower crystals, the pulse-height ratio was 0.73 with an

MCNP modelling of scintillation-detector gamma-ray spectra from natural radionuclides.

PubMed

Hendriks, P H G M; Maucec, M; de Meijer, R J

2002-09-01

gamma-ray spectra of natural radionuclides are simulated for a BGO detector in a borehole geometry using the Monte Carlo code MCNP. All gamma-ray emissions of the decay of 40K and the series of 232Th and 238U are used to describe the source. A procedure is proposed which excludes the time-consuming electron tracking in less relevant areas of the geometry. The simulated gamma-ray spectra are benchmarked against laboratory data.

Imaging properties of pixellated scintillators with deep pixels

PubMed Central

Barber, H. Bradford; Fastje, David; Lemieux, Daniel; Grim, Gary P.; Furenlid, Lars R.; Miller, Brian W.; Parkhurst, Philip; Nagarkar, Vivek V.

2015-01-01

We have investigated the light-transport properties of scintillator arrays with long, thin pixels (deep pixels) for use in high-energy gamma-ray imaging. We compared 10×10 pixel arrays of YSO:Ce, LYSO:Ce and BGO (1mm × 1mm × 20 mm pixels) made by Proteus, Inc. with similar 10×10 arrays of LSO:Ce and BGO (1mm × 1mm × 15mm pixels) loaned to us by Saint-Gobain. The imaging and spectroscopic behaviors of these scintillator arrays are strongly affected by the choice of a reflector used as an inter-pixel spacer (3M ESR in the case of the Proteus arrays and white, diffuse-reflector for the Saint-Gobain arrays). We have constructed a 3700-pixel LYSO:Ce Prototype NIF Gamma-Ray Imager for use in diagnosing target compression in inertial confinement fusion. This system was tested at the OMEGA Laser and exhibited significant optical, inter-pixel cross-talk that was traced to the use of a single-layer of ESR film as an inter-pixel spacer. We show how the optical cross-talk can be mapped, and discuss correction procedures. We demonstrate a 10×10 YSO:Ce array as part of an iQID (formerly BazookaSPECT) imager and discuss issues related to the internal activity of 176Lu in LSO:Ce and LYSO:Ce detectors. PMID:26236070

Imaging properties of pixellated scintillators with deep pixels

NASA Astrophysics Data System (ADS)

Barber, H. Bradford; Fastje, David; Lemieux, Daniel; Grim, Gary P.; Furenlid, Lars R.; Miller, Brian W.; Parkhurst, Philip; Nagarkar, Vivek V.

2014-09-01

We have investigated the light-transport properties of scintillator arrays with long, thin pixels (deep pixels) for use in high-energy gamma-ray imaging. We compared 10x10 pixel arrays of YSO:Ce, LYSO:Ce and BGO (1mm x 1mm x 20 mm pixels) made by Proteus, Inc. with similar 10x10 arrays of LSO:Ce and BGO (1mm x 1mm x 15mm pixels) loaned to us by Saint-Gobain. The imaging and spectroscopic behaviors of these scintillator arrays are strongly affected by the choice of a reflector used as an inter-pixel spacer (3M ESR in the case of the Proteus arrays and white, diffuse-reflector for the Saint-Gobain arrays). We have constructed a 3700-pixel LYSO:Ce Prototype NIF Gamma-Ray Imager for use in diagnosing target compression in inertial confinement fusion. This system was tested at the OMEGA Laser and exhibited significant optical, inter-pixel cross-talk that was traced to the use of a single-layer of ESR film as an inter-pixel spacer. We show how the optical cross-talk can be mapped, and discuss correction procedures. We demonstrate a 10x10 YSO:Ce array as part of an iQID (formerly BazookaSPECT) imager and discuss issues related to the internal activity of 176Lu in LSO:Ce and LYSO:Ce detectors.

The 3 H(d , γ) Reaction at Ec . m . <= 300 keV

NASA Astrophysics Data System (ADS)

Parker, C. E.; Brune, C. R.; Massey, T. N.; O'Donnell, J. E.; Richard, A. L.; Sayre, D. B.

2015-04-01

The 3 H(d , γ) 5He reaction has been measured using a 500-keV pulsed deuteron beam incident on a stopping titanium tritide target at the Edwards Accelerator Laboratory. The time-of-flight technique has been used to distinguish the γ-rays from neutrons in the bismuth germinate (BGO) γ-ray detector. A stilbene scintillator and an NE-213 scintillator have been used to detect the neutrons from the 3 H(d , n) α reaction using both the pulse-shape discrimination and time-of-flight techniques. A newly designed target holder with a silicon surface barrier detector to simultaneously measure α-particles to normalize the number of neutrons, along with a new titanium tritide target, was incorporated for subsequent measurements. The γ-rays have been measured at laboratory angles of 0 °, 45 °, 90 °, and 135 °. Information about the γ-ray energy distribution for the unbound ground state and first excited state of 5He can be obtained experimentally by comparing the BGO data to Monte Carlo simulations. The 3 H(d , γ) /3 H(d , n) branching ratio has also been measured. Data analysis is currently underway for the subsequent measurements. This work is supported in part by Lawrence Livermore National Laboratory and the U.S. D.O.E. (NNSA) through Grant No. DE-NA0001837.

The 3H(d,gamma) Reaction and the 3 H(d,gamma)/ 3H(d, n) Branching Ratio for Ec.m. 300 keV

NASA Astrophysics Data System (ADS)

Parker, Cody E.

The 3H(d, gamma)5He reaction and the 3H(d, gamma)/3H(d, n) branching ratio have been measured using a 500-keV pulsed deuteron beam incident on a titanium tritide target of stopping thickness at the Edwards Accelerator Laboratory. The time-of-flight technique has been used to distinguish the gamma-rays from neutrons in the bismuth germinate (BGO) gamma-ray detector. A stilbene scintillator and an NE-213 scintillator have been used to detect the neutrons from the 3H(d, n)alpha reaction using both the pulse-shape discrimination and time-of-flight techniques. A target holder with an ion-implanted silicon detector at a fixed angle of 135° to the beam axis to simultaneously measure alpha-particles as a normalization for the number of neutrons was incorporated to reduce the uncertainty in the neutron yield over the preliminary measurement. The gamma-rays have been measured at laboratory angles of 0°, 4°, 9°, and 15°. Information about the gamma-ray energy distribution for the unbound ground state and first excited state of 5He have been obtained experimentally by comparing the BGO data to Monte Carlo simulations. The reported branching ratios for each angle contain only contributions from the ground-state gamma-ray branch.

Summary of Internship Experience for 2010 DHS/ORISE summer program

DOE Office of Scientific and Technical Information (OSTI.GOV)

Pusateri, Elise; Descalle, Marie-Anne

2010-08-13

The U.S. Department of Homeland Security has deemed as a threat to national security the possibility of fissionable materials being concealed in intermodal cargo containers. Detecting these materials is critical to preventing nuclear proliferation and terrorism. Thus, several high-energy photon-based imaging applications are being developed to detect materials with Z>72 in such containers. In an initial study, an array made of plastic scintillator material was considered for a detector in combination with a bremsstrahlung sources. While plastic is a practical and cheap material to use, it has relatively poor energy resolution. When studying the full spectrum of available materials, Bimore » 4Ge 3O 12 (BGO) 2 was considered and was eventually chosen as the scintillation material for its high mass density which permits high spatial resolution with reasonable detection efficiency. The final geometry of the detector chosen by UC Berkeley and Lawrence Livermore National Laboratory was an 8-by-8 array of 0.5-cm-by- 0.5-cm-by-5-cm Bi 4Ge 3O 12 (BGO) crystals, with pixels shielded by 1-mm of lead. The purpose of my research was to model the detector response using MCNP, a Monte Carlo3 code to demonstrate its expected sensitivity and ability to generate images, under conditions that could be tested experimentally and to determine the lowest energy threshold applicable.« less

The first demonstration of the concept of "narrow-FOV Si/CdTe semiconductor Compton camera"

NASA Astrophysics Data System (ADS)

Ichinohe, Yuto; Uchida, Yuusuke; Watanabe, Shin; Edahiro, Ikumi; Hayashi, Katsuhiro; Kawano, Takafumi; Ohno, Masanori; Ohta, Masayuki; Takeda, Shin`ichiro; Fukazawa, Yasushi; Katsuragawa, Miho; Nakazawa, Kazuhiro; Odaka, Hirokazu; Tajima, Hiroyasu; Takahashi, Hiromitsu; Takahashi, Tadayuki; Yuasa, Takayuki

2016-01-01

The Soft Gamma-ray Detector (SGD), to be deployed on board the ASTRO-H satellite, has been developed to provide the highest sensitivity observations of celestial sources in the energy band of 60-600 keV by employing a detector concept which uses a Compton camera whose field-of-view is restricted by a BGO shield to a few degree (narrow-FOV Compton camera). In this concept, the background from outside the FOV can be heavily suppressed by constraining the incident direction of the gamma ray reconstructed by the Compton camera to be consistent with the narrow FOV. We, for the first time, demonstrate the validity of the concept using background data taken during the thermal vacuum test and the low-temperature environment test of the flight model of SGD on ground. We show that the measured background level is suppressed to less than 10% by combining the event rejection using the anti-coincidence trigger of the active BGO shield and by using Compton event reconstruction techniques. More than 75% of the signals from the field-of-view are retained against the background rejection, which clearly demonstrates the improvement of signal-to-noise ratio. The estimated effective area of 22.8 cm2 meets the mission requirement even though not all of the operational parameters of the instrument have been fully optimized yet.

Watersheds, ecoregions and hydrologic units: the appropriate use of each for research and environmental management decisions

Treesearch

James Glover; James Omernik; Robert Hughes; Glenn Griffith; Marc Weber

2016-01-01

It has long been recognized that conditions at a point on a stream are highly dependent on conditions upgradient within the topographic watershed. The hydrologic unit (HU) system has provided a useful set of nationally consistent, hydrologically based polygons that has allowed for the generalization and tabulation of various conditions within the stream and its valley...

Ground-Water Resources in Kaloko-Honokohau National Historical Park, Island of Hawaii, and Numerical Simulation of the Effects of Ground-Water Withdrawals

USGS Publications Warehouse

Oki, Delwyn S.; Tribble, Gordon W.; Souza, William R.; Bolke, Edward L.

1999-01-01

Within the Kaloko-Honokohau National Historical Park, which was established in 1978, the ground-water flow system is composed of brackish water overlying saltwater. Ground-water levels measured in the Park range from about 1 to 2 feet above mean sea level, and fluctuate daily by about 0.5 to 1.5 feet in response to ocean tides. The brackish water is formed by mixing of seaward flowing fresh ground water with underlying saltwater from the ocean. The major source of fresh ground water is from subsurface flow originating from inland areas to the east of the Park. Ground-water recharge from the direct infiltration of precipitation within the Park area, which has land-surface altitudes less than 100 feet, is small because of low rainfall and high rates of evaporation. Brackish water flowing through the Park ultimately discharges to the fishponds in the Park or to the ocean. The ground water, fishponds, and anchialine ponds in the Park are hydrologically connected; thus, the water levels in the ponds mark the local position of the water table. Within the Park, ground water near the water table is brackish; measured chloride concentrations of water samples from three exploratory wells in the Park range from 2,610 to 5,910 milligrams per liter. Chromium and copper were detected in water samples from the three wells in the Park and one well upgradient of the Park at concentrations of 1 to 5 micrograms per liter. One semi-volatile organic compound, phenol, was detected in water samples from the three wells in the Park at concentrations between 4 and 10 micrograms per liter. A regional, two-dimensional (areal), freshwater-saltwater, sharp-interface ground-water flow model was used to simulate the effects of regional withdrawals on ground-water flow within the Park. For average 1978 withdrawal rates, the estimated rate of fresh ground-water discharge to the ocean within the Park is about 6.48 million gallons per day, or about 3 million gallons per day per mile of coastline. Although the coastal discharge within the Park is actually brackish water, the model assumes that freshwater and saltwater do not mix and therefore the model-calculated coastal discharge within the Park is in the form of freshwater discharge. Model results indicate that ground-water withdrawals in excess of average 1978 withdrawal rates will reduce the rate of freshwater coastal discharge within the Park. Withdrawals from wells directly upgradient of the Park had the greatest effect on the model-calculated freshwater coastal discharge within the Park, whereas withdrawals from wells south of Papa Bay had little effect on the freshwater discharge within the Park. For an increased ground-water withdrawal rate of 56.8 million gallons per day, relative to average 1978 withdrawal rates in the Kona area, model-calculated freshwater coastal discharge within the Park was reduced by about 47 percent.

{sup 12}C+{sup 16}O: Properties of sub-barrier resonance {gamma}-decay

DOE Office of Scientific and Technical Information (OSTI.GOV)

Goasduff, A.; Courtin, S.; Haas, F.

2012-10-20

In a recent experiment performed at Triumf using the Dragon 0 Degree-Sign spectrometer and its associated BGO array, the complete {gamma}-decay of the radiative capture channel below the Coulomb barrier has been measured for the first time. This measurement has been performed at two energies E{sub c.m.}= 6.6 and 7.2 MeV. A selective contribution of the entrance spins 2{sup +} and 3{sup -} has been evidenced which is consistent with existing results above the barrier.

A Critical Analysis of the Acquisition Review Journal: Are We in Step with the Field?

DTIC Science & Technology

2006-12-01

ART # YEAR AUTHOR(S) TITLE THEMES 1 1994 Preston, Colleen Acquisition Reform: Making it a Reality Acquisition Reform 2 1994 LaBerge , Walter B...Going? Technology 33 1996 Hewitt, Clyde Getting to the On-Ramp of the Information Highway Technology 34 1996 LaBerge , Walter B. Cycle Time: A...Learned from Developing the ABCs 6.4 Solution System of Systems 204 2005 Zenishek, Steven G.; Usechak, David Net-Centric Warfare and its Impact on

BCN Graphene as Efficient Metal-Free Electrocatalyst for the Oxygen Reduction Reaction

DTIC Science & Technology

2012-01-01

annealing GO in the presence of boric acid and ammonia. The resultant BCN graphene was shown to have superior electrocatalytic activities to the commercial...graphene samples of different chemical compositions, along with the mixture of GO and boric acid (B-GO) starting material as reference. Comparing with the...in addition to B into GO by thermal annealing in the presence of boric acid and ammonia. Like VA-BCN nanotubes,[15] the presence of a O1s peak in the

A high-resolution gamma-ray and hard X-ray spectrometer for solar flare observations in Max 1991

NASA Technical Reports Server (NTRS)

Lin, R. P.; Curtis, D. W.; Harvey, P.; Hurley, K.; Primbsch, J. H.; Smith, D. M.; Pelling, R. M.; Duttweiler, F.

1988-01-01

A long duration balloon flight instrument for Max 1991 designed to study the acceleration of greater than 10 MeV ions and greater than 15 keV electrons in solar flares through high resolution spectroscopy of the gamma ray lines and hard X-ray and gamma ray continuum is described. The instrument, HIREGS, consists of an array of high-purity, n-type coaxial germanium detectors (HPGe) cooled to less than 90 K and surrounded by a bismuth germanate (BGO) anticoincidence shield. It will cover the energy range 15 keV to 20 MeV with keV spectral resolution, sufficient for accurate measurement of all parameters of the expected gamma ray lines with the exception of the neutron capture deuterium line. Electrical segmentation of the HPGe detector into a thin front segment and a thick rear segment, together with pulse-shape discrimination, provides optimal dynamic range and signal-to-background characteristics for flare measurements. Neutrons and gamma rays up to approximately 0.1 to 1 GeV can be detected and identified with the combination of the HPGe detectors and rear BGO shield. The HIREGS is planned for long duration balloon flights (LDBF) for solar flare studies during Max 1991. The two exploratory LDBFs carried out at mid-latitudes in 1987 to 1988 are described, and the LDBFs in Antarctica, which could in principle provide 24 hour/day solar coverage and very long flight durations (20 to 30 days) because of minimal ballast requirements are discussed.

Ammonia in ground water from the Mississippi River alluvium, Fort Madison, Iowa

USGS Publications Warehouse

Linhart, S. Mike

2001-01-01

Water samples were collected from three municipal wells, two industrial wells, one watersupply well at the Iowa State Penitentiary, one domestic well, two creeks, and the Mississippi River. Tritium analytical results indicate that the time of recharge was after 1953 for water from the municipal wells (where tritium samples were collected). The ammonia concentration, 5.1 milligrams per liter, was considerably higher in ground water collected from well Fort Madison #4 compared to samples collected from other wells. The dissolved organic carbon concentration was also highest in ground water collected from well Fort Madison #4 (5.5 milligrams per liter) although samples from other wells were also relatively high, 2.6 to 5.3 milligrams per liter. The most likely process producing the high ammonia concentration in ground water in the vicinity of well Fort Madison #4 is decomposition of organic matter (ammonification). Nitrogen isotope values, when compared to nitrogen isotope values found in ground water in the vicinity of some of the other wells, indicate the possibility that a higher percentage of the ammonia found in ground water in the vicinity of well Fort Madison #4 may be from human and(or) other animal wastes. Higher concentrations of dissolved phosphorus, orthophosphate, and a higher chloride-to-sodium mole ratio found in ground water sampled from well Fort Madison #4 could be indicative of a sewage or septic source. Potential sources include existing or abandoned septic systems, leaking sanitary sewer lines, commercial or residential waste-disposal sites, and agricultural runoff upgradient from well Fort Madison #4, or possibly, bed sediments of the Mississippi River.

Environmental Impact Analysis Process. Environmental Impact Statement for the Closure of Pease Air Force Base. Volume 1

DTIC Science & Technology

1990-05-01

initially known as Portsmouth AFB. In 1957, it was rededicated as Pease AFB in honor of Captain Harl Pease, Jr., a native of Plymouth , Now Hampshire. During... barren soil, up-gradient from storm drains, or in close proximity of floor drains. Corrective action currently being taken is the prompt disposal of...Plant communities on base are indicative of the pine / northern hardwood ecosystem.. The forest resources of. Pease AFB are substantial. More than one

Installation Restoration Program. Phase 1. Records Search for the 190th Air Refueling Group, Forbes Field Air National Guard Base, Topeka, Kansas.

DTIC Science & Technology

1986-06-01

l C. Review of Weston’s Report .................. IV-8 D. Critical Habitats /Endangered or Threatened Species ....... IV-13 V. CONCLUSIONS...Critical Habitats /Endangered or Threatened Species Discussions with personnel from the Kansas Department of Natural Resources disclosed that there are no...Reticulated Giraffe . This area is upgradient of the base and several miles distant, so it is not thought that the area is affected by past or present

Optimization of the design of thick, segmented scintillators for megavoltage cone-beam CT using a novel, hybrid modeling technique

PubMed Central

Liu, Langechuan; Antonuk, Larry E.; El-Mohri, Youcef; Zhao, Qihua; Jiang, Hao

2014-01-01

Purpose: Active matrix flat-panel imagers (AMFPIs) incorporating thick, segmented scintillators have demonstrated order-of-magnitude improvements in detective quantum efficiency (DQE) at radiotherapy energies compared to systems based on conventional phosphor screens. Such improved DQE values facilitate megavoltage cone-beam CT (MV CBCT) imaging at clinically practical doses. However, the MV CBCT performance of such AMFPIs is highly dependent on the design parameters of the scintillators. In this paper, optimization of the design of segmented scintillators was explored using a hybrid modeling technique which encompasses both radiation and optical effects. Methods: Imaging performance in terms of the contrast-to-noise ratio (CNR) and spatial resolution of various hypothetical scintillator designs was examined through a hybrid technique involving Monte Carlo simulation of radiation transport in combination with simulation of optical gain distributions and optical point spread functions. The optical simulations employed optical parameters extracted from a best fit to measurement results reported in a previous investigation of a 1.13 cm thick, 1016 μm pitch prototype BGO segmented scintillator. All hypothetical designs employed BGO material with a thickness and element-to-element pitch ranging from 0.5 to 6 cm and from 0.508 to 1.524 mm, respectively. In the CNR study, for each design, full tomographic scans of a contrast phantom incorporating various soft-tissue inserts were simulated at a total dose of 4 cGy. Results: Theoretical values for contrast, noise, and CNR were found to be in close agreement with empirical results from the BGO prototype, strongly supporting the validity of the modeling technique. CNR and spatial resolution for the various scintillator designs demonstrate complex behavior as scintillator thickness and element pitch are varied—with a clear trade-off between these two imaging metrics up to a thickness of ∼3 cm. Based on these results, an optimization map indicating the regions of design that provide a balance between these metrics was obtained. The map shows that, for a given set of optical parameters, scintillator thickness and pixel pitch can be judiciously chosen to maximize performance without resorting to thicker, more costly scintillators. Conclusions: Modeling radiation and optical effects in thick, segmented scintillators through use of a hybrid technique can provide a practical way to gain insight as to how to optimize the performance of such devices in radiotherapy imaging. Assisted by such modeling, the development of practical designs should greatly facilitate low-dose, soft tissue visualization employing MV CBCT imaging in external beam radiotherapy. PMID:24877827

Evidence of rock matrix back-diffusion and abiotic dechlorination using a field testing approach

NASA Astrophysics Data System (ADS)

Schaefer, Charles E.; Lippincott, David R.; Klammler, Harald; Hatfield, Kirk

2018-02-01

An in situ field demonstration was performed in fractured rock impacted with trichloroethene (TCE) and cis-1,2-dichloroethene (DCE) to assess the impacts of contaminant rebound after removing dissolved contaminants within hydraulically conductive fractures. Using a bedrock well pair spaced 2.4 m apart, TCE and DCE were first flushed with water to create a decrease in dissolved contaminant concentrations. While hydraulically isolating the well pair from upgradient contaminant impacts, contaminant rebound then was observed between the well pair over 151 days. The magnitude, but not trend, of TCE rebound was reasonably described by a matrix back-diffusion screening model that employed an effective diffusion coefficient and first-order abiotic TCE dechlorination rate constant that was based on bench-scale testing. Furthermore, a shift in the TCE:DCE ratio and carbon isotopic enrichment was observed during the rebound, suggesting that both biotic and abiotic dechlorination were occurring within the rock matrix. The isotopic data and back-diffusion model together served as a convincing argument that matrix back-diffusion was the mechanism responsible for the observed contaminant rebound. Results of this field demonstration highlight the importance and applicability of rock matrix parameters determined at the bench-scale, and suggest that carbon isotopic enrichment can be used as a line of evidence for abiotic dechlorination within rock matrices.

Monte Carlo simulations support non-Cerenkov radioluminescence production in tissue

NASA Astrophysics Data System (ADS)

Ackerman, Nicole L.; Boschi, Federico; Spinelli, Antonello E.

2017-08-01

There is experimental evidence for the production of non-Cerenkov radioluminescence in a variety of materials, including tissue. We constructed a Geant4 Monte Carlo simulation of the radiation from P32 and Tc99m interacting in chicken breast and used experimental imaging data to model a scintillation-like emission. The same radioluminescence spectrum is visible from both isotopes and cannot otherwise be explained through fluorescence or filter miscalibration. We conclude that chicken breast has a near-infrared scintillation-like response with a light yield three orders of magnitude smaller than BGO.

Fermi GBM Observations of Terrestrial Gamma Flashes

NASA Technical Reports Server (NTRS)

Wilson-Hodge, Colleen A.; Briggs, M. S.; Connaughton, V.; Fishman, G. J.; Bhat, P. N.; Paciesas, W. S.; Preece, R. D.; Kippen, R. M.; vonKienlin, A.; Dwyer, J. R.;

Fabrication of highly efficient ZnO nanoscintillators

NASA Astrophysics Data System (ADS)

Procházková, Lenka; Gbur, Tomáš; Čuba, Václav; Jarý, Vítězslav; Nikl, Martin

2015-09-01

Photo-induced synthesis of high-efficiency ultrafast nanoparticle scintillators of ZnO was demonstrated. Controlled doping with Ga(III) and La(III) ions together with the optimized method of ZnO synthesis and subsequent two-step annealing in air and under reducing atmosphere allow to achieve very high intensity of UV exciton luminescence, up to 750% of BGO intensity magnitude. Fabricated nanoparticles feature extremely short sub-nanosecond photoluminescence decay times. Temperature dependence of the photoluminescence spectrum within 8-340 K range was investigated and shows the absence of visible defect-related emission within all temperature intervals.

Symetrica Measurements at PNNL

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kouzes, Richard T.; Mace, Emily K.; Redding, Rebecca L.

2009-01-26

Symetrica is a small company based in Southampton, England, that has developed an algorithm for processing gamma ray spectra obtained from a variety of scintillation detectors. Their analysis method applied to NaI(Tl), BGO, and LaBr spectra results in deconvoluted spectra with the “resolution” improved by about a factor of three to four. This method has also been applied by Symetrica to plastic scintillator with the result that full energy peaks are produced. If this method is valid and operationally viable, it could lead to a significantly improved plastic scintillator based radiation portal monitor system.

Chromium-removal processes during groundwater remediation by a zerovalent iron permeable reactive barrier.

PubMed

Wilkin, Richard T; Su, Chunming; Ford, Robert G; Paul, Cynthia J

2005-06-15

Solid-phase associations of chromium were examined in core materials collected from a full-scale, zerovalent iron permeable reactive barrier (PRB) at the U.S. Coast Guard Support Center located near Elizabeth City, NC. The PRB was installed in 1996 to treat groundwater contaminated with hexavalent chromium. After eight years of operation, the PRB remains effective at reducing concentrations of Cr from average values >1500 microg L(-1) in groundwater hydraulically upgradient of the PRB to values <1 microg L(-1) in groundwater within and hydraulically downgradient of the PRB. Chromium removal from groundwater occurs at the leading edge of the PRB and also within the aquifer immediately upgradient of the PRB. These regions also witness the greatest amount of secondary mineral formation due to steep geochemical gradients that result from the corrosion of zerovalent iron. X-ray absorption near-edge structure (XANES) spectroscopy indicated that chromium is predominantly in the trivalent oxidation state, confirming that reductive processes are responsible for Cr sequestration. XANES spectra and microscopy results suggest that Cr is, in part, associated with iron sulfide grains formed as a consequence of microbially mediated sulfate reduction in and around the PRB. Results of this study provide evidence that secondary iron-bearing mineral products may enhance the capacity of zerovalent iron systems to remediate Cr in groundwater, either through redox reactions at the mineral-water interface or by the release of Fe(II) to solution via mineral dissolution and/or metal corrosion.

Hydrogeologic investigation and simulation of ground-water flow in the Upper Floridan Aquifer of north-central Florida and southwestern Georgia and delineation of contributing areas for selected city of Tallahassee, Florida, water-supply wells

USGS Publications Warehouse

Davis, J. Hal

1996-01-01

A 4-year investigation of the Upper Floridan aquifer and ground-water flow system in Leon County, Florida, and surrounding counties of north-central Florida and southwestern Georgia began in 1990. The purpose of the investigation was to describe the ground-water flow system and to delineate the contributing areas to selected City of Tallahassee, Florida, water-supply wells. The investigation was prompted by the detection of low levels of tetrachloroethylene in ground-water samples collected from several of the city's water-supply wells. Hydrologic data and previous studies indicate that; ground-water flow within the Upper Floridan aquifer can be considered steady-state; the Upper Floridan aquifer is a single water-bearing unit; recharge is from precipitation; and that discharge occurs as spring flow, leakage to rivers, leakage to the Gulf of Mexico, and pumpage. Measured transmissivities of the aquifer ranged from 1,300 ft2/d (feet squared per day) to 1,300,000 ft2/d. Steady-state ground-water flow in the Upper Floridan aquifer was simulated using a three-dimensional ground- water flow model. Transmissivities ranging from less than 5,000 ft2/d to greater than 11,000,000 ft2/d were required to calibrate to observed conditions. Recharge rates used in the model ranged from 18.0 inches per year in areas where the aquifer was unconfined to less than 2 inches per year in broad areas where the aquifer was confined. Contributing areas to five Tallahassee water-supply wells were simulated by particle- tracking techniques. Particles were seeded in model cells containing pumping wells then tracked backwards in time toward recharge areas. The contributing area for each well was simulated twice, once assuming a porosity of 25 percent and once assuming a porosity of 5 percent. A porosity of 25 percent is considered a reasonable average value for the Upper Floridan aquifer; the 5 percent porosity simulated the movement of ground-water through only solution-enhanced bedding plains and fractures. The contributing areas were generally elliptical in shape, reflecting the influence of the sloping potentiometric surface. The contributing areas delineated for a 5 percent porosity were always much larger than those determined using a 25 percent porosity. The lowest average ground-water velocity computed within a contributing area, using a 25 percent porosity, was 1.0 ft/d (foot per day) and the highest velocity was 1.6 ft/d. The lowest average ground-water velocity, determined using a 5 percent porosity, was 2.4 ft/d and the highest was 7.4 ft/d. The contributing areas for each of the five wells was also determined analytically and compared to the model-derived areas. The upgradient width of the simulated contributing areas were larger than the upgradient width of the analytically determined contributing areas for four of the five wells. The model could more accurately delineate contributing areas because of the ability to simulate wells as partially penetrating and by incorporating complex, three-dimensional aquifer characteristics, which the analytical method could not.

Augmenting groundwater monitoring networks near landfills with slurry cutoff walls.

PubMed

Hudak, Paul F

2004-01-01

This study investigated the use of slurry cutoff walls in conjunction with monitoring wells to detect contaminant releases from a solid waste landfill. The 50 m wide by 75 m long landfill was oriented oblique to regional groundwater flow in a shallow sand aquifer. Computer models calculated flow fields and the detection capability of six monitoring networks, four including a 1 m wide by 50 m long cutoff wall at various positions along the landfill's downgradient boundaries and upgradient of the landfill. Wells were positioned to take advantage of convergent flow induced downgradient of the cutoff walls. A five-well network with no cutoff wall detected 81% of contaminant plumes originating within the landfill's footprint before they reached a buffer zone boundary located 50 m from the landfill's downgradient corner. By comparison, detection efficiencies of networks augmented with cutoff walls ranged from 81 to 100%. The most efficient network detected 100% of contaminant releases with four wells, with a centrally located, downgradient cutoff wall. In general, cutoff walls increased detection efficiency by delaying transport of contaminant plumes to the buffer zone boundary, thereby allowing them to increase in size, and by inducing convergent flow at downgradient areas, thereby funneling contaminant plumes toward monitoring wells. However, increases in detection efficiency were too small to offset construction costs for cutoff walls. A 100% detection efficiency was also attained by an eight-well network with no cutoff wall, at approximately one-third the cost of the most efficient wall-augmented network.

Investigation of Contaminated Ground Water at Solid Waste Management Unit 12, Naval Weapons Station Charleston, North Charleston, South Carolina, 2006-2007

USGS Publications Warehouse

Vroblesky, Don A.; Petkewich, Matthew D.; Lowery, Mark A.; Conlon, Kevin J.; Harrelson, Larry G.

2008-01-01

The U.S. Geological Survey investigated natural and engineered remediation of chlorinated volatile organic compound (VOC) ground-water contamination at Solid Waste Management Unit 12 at the Naval Weapons Station Charleston, North Charleston, South Carolina, beginning in 2000. The primary contaminants of interest in the study are tetrachloroethene, 1,1,1-trichloroethane, trichloroethene, cis-1,2-dichloroethene, vinyl chloride, 1,1-dichloroethane, and 1,1-dichloroethene. The permeable reactive barrier (PRB) along the main axis of the contaminant plume appears to be actively removing contamination. In contrast to the central area of the PRB, the data from the southern end of the PRB indicate that contaminants are moving around the PRB. Concentrations in wells 12MW-10S and 12MW-03S, upgradient from the PRB, showed a general decrease in VOC concentrations. VOC concentrations in some wells in the forest showed a sharp increase, followed by a decrease. In 2007, the VOC concentrations began to increase in well 12MW-12S, downgradient from the PRB and thought to be unaffected by the PRB. The VOC-concentration changes in the forest, such as at well 12MW-12S, may represent lateral shifting of the plume in response to changes in ground-water-flow direction or may represent movement of a contamination pulse through the forest.

Hydrogeology of the Potsdam Sandstone in northern New York

USGS Publications Warehouse

Williams, John H.; Reynolds, Richard J.; Franzi, David A.; Romanowicz, Edwin A.; Paillet, Frederick L.

2010-01-01

The Potsdam Sandstone of Cambrian age forms a transboundary aquifer that extends across northern New York and into southern Quebec. The Potsdam Sandstone is a gently dipping sequence of arkose, subarkose, and orthoquartzite that unconformably overlies Precambrian metamorphic bedrock. The Potsdam irregularly grades upward over a thickness of 450 m from a heterogeneous feldspathic and argillaceous rock to a homogeneous, quartz-rich and matrix-poor rock. The hydrogeological framework of the Potsdam Sandstone was investigated through an analysis of records from 1,500 wells and geophysical logs from 40 wells, and through compilation of GIS coverages of bedrock and surficial geology, examination of bedrock cores, and construction of hydrogeological sections. The upper several metres of the sandstone typically is weathered and fractured and, where saturated, readily transmits groundwater. Bedding-related fractures in the sandstone commonly form sub-horizontal flow zones of relatively high transmissivity. The vertical distribution of sub-horizontal flow zones is variable; spacings of less than 10 m are common. Transmissivity of individual flow zones may be more than 100 m2/d but typically is less than 10 m2/d. High angle fractures, including joints and faults, locally provide vertical hydraulic connection between flow zones. Hydraulic head gradients in the aquifer commonly are downward; a laterally extensive series of sub-horizontal flow zones serve as drains for the groundwater flow system. Vertical hydraulic head differences between shallow and deep flow zones range from 1 m to more than 20 m. The maximum head differences are in recharge areas upgradient from the area where the Chateauguay and Chazy Rivers, and their tributaries, have cut into till and bedrock. Till overlies the sandstone in much of the study area; its thickness is generally greatest in the western part, where it may exceed 50 m. A discontinuous belt of bedrock pavements stripped of glacial drift extends across the eastern part of the study area; the largest of these is Altona Flat Rock. Most recharge to the sandstone aquifer occurs in areas of thin, discontinuous till and exposed bedrock; little recharge occurs in areas where this unit is overlain by thick till and clay. Discharge from the sandstone aquifer provides stream and river baseflow and is the source of many springs. A series of springs that are used for municipal bottled water and fish-hatchery supply discharge from 1,000 to 5,000 L/min adjacent to several tributaries east of the Chateauguay River. The major recharge areas for the Chateauguay springs are probably upgradient to the southeast, where the till cover is thin or absent.

Reconnaissance of the hydrology, water quality, and sources of bacterial and nutrient contamination in the Ozark Plateaus aquifer system and Cave Springs Branch of Honey Creek, Delaware County, Oklahoma, March 1999-March 2000

USGS Publications Warehouse

Schlottmann, Jamie L.; Tanner, Ralph S.; Samadpour, Mansour

2000-01-01

A reconnaissance investigation of hydrology and water quality was conducted to evaluate possible sources of bacteria and nutrient contamination in the Cave Springs Branch basin and the underlying karstic Ozark Plateau aquifer system. Objectives were to: (1) determine the directions of ground-water flow in the basin and determine whether Cave Springs Branch interacts with ground water, (2) compare water quality in Cave Springs Branch with water quality in nearby wells to determine whether the stream is contaminating nearby wells, and (3) determine sources of fecal coliform bacteria and nitrate contamination in Cave Springs Branch and ground water. Potential sources of bacteria and nitrate in the area include cultivated agriculture, cow and horse on pasture, poultry production, households, and wildlife. Presence of fecal coliform and fecal streptococcal bacteria directly indicate fecal contamination and the potential for the presence of other pathogenic organisms in a water supply. Nitrate in drinking water poses health risks and may indicate the presence of additional contaminants. Fecal coliform bacteria colony counts were least in wells, intermediate in the poultry-processing plant wastewater outfall and Honey Creek above the confluence with Cave Springs Branch, and greatest in Cave Springs Branch. Bacteria strains and resistance to antibiotics by some bacteria indicate that livestock may have been sources of some bacteria in the water samples. Multiple antibiotic resistances were not present in the isolates from the water samples, indicating that the bacteria may not be from human or poultry sources. Ribotyping indicates that Escherichia coli bacteria in water samples from the basin were from bird, cow, horse, dog, deer, and human sources. The presence of multiple ribotypes from each type of animal source except bird indicates that most of the bacteria are from multiple populations of source animals. Identifiable sources of bacteria in Cave Springs Branch at the state line were dominantly cow and horse with one ribotype from bird. Escherichia coli was detected in only one well sample. Bacterial ribotypes in water from that upgradient well indicated human and dog feces as sources for bacteria, and that on site wastewater treatment may not always be adequate in these highly permeable soils. Greater concentrations of nitrate in Cave Springs Branch and O'Brien Spring relative to the poultry-processing plant wastewater outfall may be due, in part, to conversion of ammonia from poultry processing plant wastewater. The poultry-processing plant wastewater outfall sample collected in March 2000 contained greater concentrations of ammonia and total organic nitrogen plus ammonia than the spring, stream, and well samples collected during August 1999. Cave Springs Branch and Honey Creek contributed approximately equal loads of nitrogen to Honey Creek below the confluence and the greatest loads of nitrogen were introduced to Cave Springs Branch by the poultry processing plant wastewater outfall and O'Brien Spring. Nitrate concentrations in upgradient well samples ranged from 0.38 to 4.60 milligrams per liter, indicating that there are sources of ground-water nitrogen other than Cave Springs Branch, such as animal waste, fertilizer, or human waste. Nitrogen compounds in water from wells downgradient of Cave Springs Branch may be from Cave Springs Branch, fertilizers, animal waste, or human waste.

Effects of land use on water quality of the Fountain Creek alluvial aquifer, east-central Colorado

USGS Publications Warehouse

Chafin, Daniel T.

1996-01-01

Water-quality data were collected from the Fountain Creek alluvial aquifer in 1988 and 1989 as part of the Toxic-Waste Ground-Water Contamination Program. These data indicate that dissolved solids, most major ions, fluoride, ammonium, boron, lithium, selenium, and strontium were more concentrated in the agricultural land-use area than in the upgradient urban land-use area. Nitrate and phosphate had significantly larger concentrations, and volatile organic compounds had significantly greater detection frequencies in the urban land-use area.

ATIC Flight Data Processing

NASA Technical Reports Server (NTRS)

Ahn, H. S.; Adams, James H., Jr.; Bashindzhagyan, G.; Ampe, J.; Case, G.; Whitaker, Ann F. (Technical Monitor)

2001-01-01

The first flight of the Advanced Thin Ionization Calorimeter (ATIC) experiment from McMurdo, Antarctica lasted for 16 days, starting on December 28, 2000. The ATIC instrument consists of a fully active 320-crystal, 960-channel Bismuth Germanate (BGO) calorimeter, 202 scintillator strips (808 channels) in 3 hodoscopes, interleaved with graphite target layers, and a 4480-pixel silicon matrix charge detector. We have developed an object-oriented data processing package based on ROOT. In this paper, we describe the data processing scheme used in handling the accumulated 45 GB of flight data. We discuss calibration issues, particularly the time-dependence of housekeeping information.

Elemental Spectra from the First ATIC Flight

NASA Technical Reports Server (NTRS)

Ahn, H. S.; Adams, J. H.; Bashindzhagyan, G.; Batkov, K. E.; Changv, J.; Christl, M.; Fazely, A. R.; Ganel, O.; Gunasingha, R. M.; Guzik, T. G.

2005-01-01

The Advanced Thin Ionization Calorimeter (ATIC) instrument is a balloon-borne experiment designed to measure the composition and energy spectra of Z = l to 26 cosmic rays over the energy range from approx. 10(exp 11) to approx. 10(exp 14) eV. The instrument consists of a silicon matrix charge detector, plastic scintillator strip hodoscopes interleaved with graphite interaction targets, and a fully active Bismuth Germanate (BGO) calorimeter. ATIC had two successful Long Duration Balloon flights launched from McMurdo Station, Antarctica in 2000 and 2002. In this paper, spectra of various elements measured during the first 16 day flight are presented.

ATIC Experiment: Preliminary Results from the Flight in 2002

NASA Technical Reports Server (NTRS)

Ahn, H. S.; Adams, J. H.; Bashindzhagyan, G.; Batkov, K. E.; Chang, J.; Christl, M.; Cox, M.; Ellison, S. B.; Fazely, A. R.; Ganel, O.

2003-01-01

Abstract The Advanced Thin Ionization Calorimeter (ATIC) had successful Long Duration Balloon flights from McMurdo, Antarctica in both 2000 and 2002. The instrument consists of a Silicon matrix for charge measurement, a flared graphite target to induce nuclear interactions, scintillator strip hodoscopes for triggering and helping reconstruct trajectory, and a BGO calorimeter to measure the energy of incident particles. In this paper, we discuss the second flight, which lasted 20 days, starting on 12/29/02. Preliminary results from the on-going analysis of the data including the proton and helium spectra are reported.

ATIC Experiment: Elemental Spectra from the Flight in 2000

NASA Technical Reports Server (NTRS)

Ahn, H. S.; Adams, J. H.; Bashindzhagyan, G.; Batkov, K. E.; Chang, J.; Christl, M.; Fazely, A. R.; Ganel, O.; Gunasingha, R. M.; Guzik, T. G.

2003-01-01

The Advanced Thin Ionization Calorimeter (ATIC) had successful Long Duration Balloon flights from McMurdo, Antarctica in both 2000 and 2002. The instrument consists of a silicon matrix charge detector, a 0.75 nuclear interaction length graphite target, 3 scintillator strip hodoscopes, and an 18 radiation length thick BGO calorimeter to measure the cosmic ray composition and energy spectra from approximately 30 GeV to near 100 TeV. In this paper, we present preliminary results from the first flight, which was a test flight that lasted for 16 days, starting on 12/28/00.

Soft gamma-ray detector (SGD) onboard the ASTRO-H mission

NASA Astrophysics Data System (ADS)

Fukazawa, Yasushi; Tajima, Hiroyasu; Watanabe, Shin; Blandford, Roger; Hayashi, Katsuhiro; Harayama, Atsushi; Kataoka, Jun; Kawaharada, Madoka; Kokubun, Motohide; Laurent, Philippe; Lebrun, François; Limousin, Olivier; Madejski, Grzegorz M.; Makishima, Kazuo; Mizuno, Tsunefumi; Mori, Kunishiro; Nakamori, Takeshi; Nakazawa, Kazuhiro; Noda, Hirofumi; Odaka, Hirokazu; Ohno, Masanori; Ohta, Masayuki; Saito, Shin'ya; Sato, Goro; Sato, Rie; Takeda, Shin'ichiro; Takahashi, Hiromitsu; Takahashi, Tadayuki; Tanaka, Yasuyuki; Terada, Yukikatsu; Uchiyama, Hideki; Uchiyama, Yasunobu; Yamaoka, Kazutaka; Yatsu, Yoichi; Yonetoku, Daisuke; Yuasa, Takayuki

2014-07-01

The Soft Gamma-ray Detector (SGD) is one of observational instruments onboard the ASTRO-H, and will provide 10 times better sensitivity in 60{600 keV than the past and current observatories. The SGD utilizes similar technologies to the Hard X-ray Imager (HXI) onboard the ASTRO-H. The SGD achieves low background by constraining gamma-ray events within a narrow field-of-view by Compton kinematics, in addition to the BGO active shield. In this paper, we will present the results of various tests using engineering models and also report the flight model production and evaluations.

Design considerations for a C-shaped PET system, dedicated to small animal brain imaging, using GATE Monte Carlo simulations

NASA Astrophysics Data System (ADS)

Efthimiou, N.; Papadimitroulas, P.; Kostou, T.; Loudos, G.

2015-09-01

Commercial clinical and preclinical PET scanners rely on the full cylindrical geometry for whole body scans as well as for dedicated organs. In this study we propose the construction of a low cost dual-head C-shaped PET system dedicated for small animal brain imaging. Monte Carlo simulation studies were performed using GATE toolkit to evaluate the optimum design in terms of sensitivity, distortions in the FOV and spatial resolution. The PET model is based on SiPMs and BGO pixelated arrays. Four different configurations with C- angle 0°, 15°, 30° and 45° within the modules, were considered. Geometrical phantoms were used for the evaluation process. STIR software, extended by an efficient multi-threaded ray tracing technique, was used for the image reconstruction. The algorithm automatically adjusts the size of the FOV according to the shape of the detector's geometry. The results showed improvement in sensitivity of ∼15% in case of 45° C-angle compared to the 0° case. The spatial resolution was found 2 mm for 45° C-angle.

Features of Different Inorganic Scintillators Used in Neutron-Radiation Systems for Illegal Substance Detection

NASA Astrophysics Data System (ADS)

Batyaev, V. F.; Belichenko, S. G.; Bestaev, R. R.

2016-04-01

The work is devoted to a quantitative comparison of different inorganic scintillators to be used in neutron-radiation inspection systems. Such systems can be based on the tagged neutron (TN) method and have a significant potential in different applications such as detection of explosives, drugs, mines, identification of chemical warfare agents, assay of nuclear materials and human body composition [1]-[3]. The elemental composition of an inspected object is determined via spectrometry of gammas from the object bombarded by neutrons which are tagged by an alpha-detector built inside a neutron generator. This creates a task to find a quantitative indicator of the object identification quality (via elemental composition) as a function of basic parameters of the γ-detectors, such as their efficiency, energy and time resolutions, which in turn are generally defined by a scintillator of the detector. We have tried to solve the task for a set of four scintillators which are often used in the study of TN method, namely BGO, LaBr3, LYSO, NaI(Tl), whose basic parameters are well known [4]-[7].

Beam Tests of the Balloon-Borne ATIC Experiment

NASA Technical Reports Server (NTRS)

Ganel, O.; Adams, J. H., Jr.; Ahn, E. J.; Ampe, J.; Bashindzhagyan, G.; Case, G.; Chang, J.; Ellison, S.; Fazely, A.; Gould, R.

2003-01-01

The Advanced Thin Ionization Calorimeter (ATIC) balloon-borne experiment is designed to perform cosmic-ray elemental spectra measurement from 50 GeV to 100 TeV for nuclei from hydrogen to iron. These measurements are expected to provide crucial hints about some of the most fundamental questions in astroparticle physics today. ATTIC'S design centers on an 18 radiation length (X(sub Omnicron)) deep bismuth germanate (BGO) calorimeter, preceded by a 0.75 lambda(sub int) graphite target. In September 1999 the ATIC detector was exposed to high-energy beams at CERN's SPS accelerator, within the framework of the development program for the Advanced Cosmic-ray Composition Experiment for the Space Station (ACCESS). In December 2000 - January 2001, ATIC flew on the first of a series of long duration balloon (LDB) flights from McMurdo Station, Antarctica. We present here results from the 1999 beam-tests, including energy resolutions for electrons and protons at several beam energies from 100 GeV to 375 GeV, as well as signal linearity and collection efficiency estimates. We show how these results compare with expectations based on simulations, and their expected impacts on mission performance.

Assessing natural attenuation potential at a uranium (U) in situ recovery site (Rosita, TX, USA) using multiple redox-sensitive isotope systems

NASA Astrophysics Data System (ADS)

Basu, A.; Brown, S. T.; Christensen, J. N.; DePaolo, D. J.; Reimus, P. W.; Heikoop, J. M.; Simmons, A. M.; House, B.; Schilling, K.; Johnson, T. M.; Pelizza, M.

2013-12-01

The In Situ Recovery (ISR) U mining operation at Rosita, TX, USA, involved oxidative dissolution of U from roll front U deposits. This process mobilized U along with other characteristic elements (e.g., Se) from the roll fronts in their soluble and toxic oxidized forms (e.g., U(VI), Se(VI)). The dissolved U(VI) in groundwater poses significant ecological risk due to its chemical toxicity and must be restored below the existing regulatory limit to minimize the environmental impact of ISR mining. However, the undisturbed sediments downgradient to the roll front deposits are expected to remain reduced. Naturally occurring Fe-minerals (e.g., FeS, siderite, magnetite) and microorganisms in the sediments downgradient to ISR activity can reduce dissolved U(VI) to less toxic and insoluble U(IV) and promote natural attenuation. The reduction of oxyanions of U or Se induces measurable isotopic fractionation that can be used to monitor the natural attenuation by downgradient sediments. Here, we used multiple redox-sensitive isotope systems (U, Se, and S) to detect reducing conditions and natural attenuation of U(VI) at the ISR site. We collected groundwater samples from 26 wells located in the ore body, upgradient and downgradient to the ore body. The δ238U values measured in groundwater samples from 23 wells range from 0.48‰ to -1.66‰ (×0.12‰). A preliminary investigation of 6 groundwater samples shows a variation of δ82Se values from -1.44‰ to 5.24‰ (×0.15‰). The δ34SO4 measurements in groundwater vary from 11.8‰ to -19.9‰. The reduction of Se(VI) and SO42- fractionates the lighter isotopes (i.e., 32S and 76Se) in the reduced product phase rendering the remaining reactants in the groundwater enriched in heavier isotopes. Therefore, the high δ82Se and δ34SO4 values may suggest reduction of Se(VI) and SO42-, respectively. The highest δ238U values are observed in the wells located in the ore body or upgradient to the ore body whereas the downgradient wells show significantly lower δ238U values. High δ238U values in most of the wells located in the ore-zone may be attributed to the dissolution of the U ore enriched in 238U. The low δ238U values are generally observed in the wells with low U(VI) concentrations. Since U(VI) reduction fractionates 238U to the solid U(IV) phase, the depletion of 238U in the groundwater samples in the downgradient monitoring wells suggest U(VI) reduction by the downgradient sediments. The δ238U values in the groundwater samples conform to a Rayleigh distillation model with an isotopic fractionation factor α = 1.00013 × 0.00010. Future investigations include characterization of the U ore bearing sediments collected from boreholes in the ore body and downgradient of the ore body, measurement of the δ238U and δ82Se values in the ore and in remaining groundwater samples. The U(VI) reducing capacity and concomitant U isotopic fractionation factors for the sediments from downgradient boreholes will be determined from the batch incubation experiments and flow through column experiments.

Performance comparison of two commercial BGO-based PET/CT scanners using NEMA NU 2-2001.

PubMed

Bolard, Grégory; Prior, John O; Modolo, Luca; Delaloye, Angelika Bischof; Kosinski, Marek; Wastiel, Claude; Malterre, Jérôme; Bulling, Shelley; Bochud, François; Verdun, Francis R

2007-07-01

Combined positron emission tomography and computed tomography (PET/CT) scanners play a major role in medicine for in vivo imaging in an increasing number of diseases in oncology, cardiology, neurology, and psychiatry. With the advent of short-lived radioisotopes other than 18F and newer scanners, there is a need to optimize radioisotope activity and acquisition protocols, as well as to compare scanner performances on an objective basis. The Discovery-LS (D-LS) was among the first clinical PET/CT scanners to be developed and has been extensively characterized with older National Electrical Manufacturer Association (NEMA) NU 2-1994 standards. At the time of publication of the latest version of the standards (NU 2-2001) that have been adapted for whole-body imaging under clinical conditions, more recent models from the same manufacturer, i.e., Discovery-ST (D-ST) and Discovery-STE (D-STE), were commercially available. We report on the full characterization both in the two- and three-dimensional acquisition mode of the D-LS according to latest NEMA NU 2-2001 standards (spatial resolution, sensitivity, count rate performance, accuracy of count losses, and random coincidence correction and image quality), as well as a detailed comparison with the newer D-ST widely used and whose characteristics are already published.

Performance comparison of two commercial BGO-based PET/CT scanners using NEMA NU 2-2001

DOE Office of Scientific and Technical Information (OSTI.GOV)

Bolard, Gregory; Prior, John O.; Modolo, Luca

2007-07-15

Combined positron emission tomography and computed tomography (PET/CT) scanners play a major role in medicine for in vivo imaging in an increasing number of diseases in oncology, cardiology, neurology, and psychiatry. With the advent of short-lived radioisotopes other than {sup 18}F and newer scanners, there is a need to optimize radioisotope activity and acquisition protocols, as well as to compare scanner performances on an objective basis. The Discovery-LS (D-LS) was among the first clinical PET/CT scanners to be developed and has been extensively characterized with older National Electrical Manufacturer Association (NEMA) NU 2-1994 standards. At the time of publication ofmore » the latest version of the standards (NU 2-2001) that have been adapted for whole-body imaging under clinical conditions, more recent models from the same manufacturer, i.e., Discovery-ST (D-ST) and Discovery-STE (D-STE), were commercially available. We report on the full characterization both in the two- and three-dimensional acquisition mode of the D-LS according to latest NEMA NU 2-2001 standards (spatial resolution, sensitivity, count rate performance, accuracy of count losses, and random coincidence correction and image quality), as well as a detailed comparison with the newer D-ST widely used and whose characteristics are already published.« less

Simultaneous estimation of local-scale and flow path-scale dual-domain mass transfer parameters using geoelectrical monitoring

USGS Publications Warehouse

Briggs, Martin A.; Day-Lewis, Frederick D.; Ong, John B.; Curtis, Gary P.; Lane, John W.

2013-01-01

Anomalous solute transport, modeled as rate-limited mass transfer, has an observable geoelectrical signature that can be exploited to infer the controlling parameters. Previous experiments indicate the combination of time-lapse geoelectrical and fluid conductivity measurements collected during ionic tracer experiments provides valuable insight into the exchange of solute between mobile and immobile porosity. Here, we use geoelectrical measurements to monitor tracer experiments at a former uranium mill tailings site in Naturita, Colorado. We use nonlinear regression to calibrate dual-domain mass transfer solute-transport models to field data. This method differs from previous approaches by calibrating the model simultaneously to observed fluid conductivity and geoelectrical tracer signals using two parameter scales: effective parameters for the flow path upgradient of the monitoring point and the parameters local to the monitoring point. We use regression statistics to rigorously evaluate the information content and sensitivity of fluid conductivity and geophysical data, demonstrating multiple scales of mass transfer parameters can simultaneously be estimated. Our results show, for the first time, field-scale spatial variability of mass transfer parameters (i.e., exchange-rate coefficient, porosity) between local and upgradient effective parameters; hence our approach provides insight into spatial variability and scaling behavior. Additional synthetic modeling is used to evaluate the scope of applicability of our approach, indicating greater range than earlier work using temporal moments and a Lagrangian-based Damköhler number. The introduced Eulerian-based Damköhler is useful for estimating tracer injection duration needed to evaluate mass transfer exchange rates that range over several orders of magnitude.

Permeable Reactive Barriers Designed To Mitigate Eutrophication Alter Bacterial Community Composition and Aquifer Redox Conditions

PubMed Central

Hiller, Kenly A.; Foreman, Kenneth H.; Weisman, David

2015-01-01

Permeable reactive barriers (PRBs) consist of a labile carbon source that is positioned to intercept nitrate-laden groundwater to prevent eutrophication. Decomposition of carbon in the PRB drives groundwater anoxic, fostering microbial denitrification. Such PRBs are an ideal habitat to examine microbial community structure under high-nitrate, carbon-replete conditions in coastal aquifers. We examined a PRB installed at the Waquoit Bay National Estuarine Research Reserve in Falmouth, MA. Groundwater within and below the PRB was depleted in oxygen compared to groundwater at sites upgradient and at adjacent reference sites. Nitrate concentrations declined from a high of 25 μM upgradient and adjacent to the barrier to <0.1 μM within the PRB. We analyzed the total and active bacterial communities filtered from groundwater flowing through the PRB using amplicons of 16S rRNA and of the 16S rRNA genes. Analysis of the 16S rRNA genes collected from the PRB showed that the total bacterial community had high relative abundances of bacteria thought to have alternative metabolisms, such as fermentation, including candidate phyla OD1, OP3, TM7, and GN02. In contrast, the active bacteria had lower abundances of many of these bacteria, suggesting that the bacterial taxa that differentiate the PRB groundwater community were not actively growing. Among the environmental variables analyzed, dissolved oxygen concentration explained the largest proportion of total community structure. There was, however, no significant correlation between measured environmental parameters and the active microbial community, suggesting that controls on the active portion may differ from the community as a whole. PMID:26231655

Two-dimensional, steady-state model of ground-water flow, Nevada Test Site and vicinity, Nevada-California

USGS Publications Warehouse

Waddell, R.K.

1982-01-01

A two-dimensional, steady-state model of ground-water flow beneath the Nevada Test Site and vicinity has been developed using inverse techniques. The area is underlain by clastic and carbonate rocks of Precambrian and Paleozoic age and by volcanic rocks and alluvium of Tertiary and Quaternary age that have been juxtaposed by normal and strike-slip faulting. Aquifers are composed of carbonate and volcanic rocks and alluvium. Characteristics of the flow system are determined by distribution of low-conductivity rocks (barriers); by recharge originating in the Spring Mountains, Pahranagat, Timpahute, and Sheep Ranges, and in Pahute Mesa; and by underflow beneath Pahute Mesa from Gold Flat and Kawich Valley. Discharge areas (Ash Meadows, Oasis Valley, Alkali Flat, and Furnace Creek Ranch) are upgradient from barriers. Sensitivities of simulated hydraulic heads and fluxes to variations in model parameters were calculated to guide field studies and to help estimate errors in predictions from transport modeling. Hydraulic heads and fluxes are very sensitive to variations in the greater magnitude recharge/discharge terms. Transmissivity at a location may not be the most important transmissivity for determining flux there. Transmissivities and geometries of large barriers that impede flow from Pahute Mesa have major effects on fluxes elsewhere; as their transmissivities are decreased, flux beneath western Jackass Flats and Yucca Mountains is increased as water is diverted around the barriers. Fortymile Canyon is underlain by highly transmissive rocks that cause potentiometric contours to vee upgradient; increasing their transmissivity increases flow through them, and decreases it beneath Yucca Mountain. (USGS)

Hydrogeology of Two Areas of the Tug Hill Glacial-Drift Aquifer, Oswego County, New York

USGS Publications Warehouse

Miller, Todd S.; Bugliosi, Edward F.; Hetcher-Aguila, Kari K.; Eckhardt, David A.

2007-01-01

Two water-production systems, one for the Village of Pulaski and the other for the Villages of Sandy Creek and Lacona in Oswego County, New York, withdraw water from the Tug Hill glacial-drift aquifer, a regional sand and gravel aquifer along the western flank of the Tug Hill Plateau, and provide the sole source of water for these villages. As a result of concerns about contamination of the aquifer, two studies were conducted during 2001 to 2004, one for each water-production system, to refine the understanding of ground-water flow surrounding these water-production systems. Also, these studies were conducted to determine the cause of the discrepancy between ground-water ages estimated from previously constructed numerical ground-water-flow models for the Pulaski and Sandy Creek/Lacona well fields and the apparent ground-water ages determined using concentrations of tritium and chlorofluorocarbons. The Village of Pulaski withdrew 650,000 gallons per day in 2000 from four shallow, large-diameter, dug wells finished in glaciolacustrine deposits consisting of sand with some gravelly lenses 3 miles east of the village. Four 2-inch diameter test wells were installed upgradient from each production well, hydraulic heads were measured, and water samples collected and analyzed for physical properties, inorganic constituents, nutrients, bacteria, tritium, dissolved gases, and chlorofluorocarbons. Recharge to the Tug Hill glacial-drift aquifer is from precipitation directly over the aquifer and from upland sources in the eastern part of the recharge area, including (1) unchannelized runoff from till and bedrock hills east of the aquifer, (2) seepage to the aquifer from streams that drain the Tug Hill Plateau, (3) ground-water inflow from the till and bedrock on the adjoining Tug Hill Plateau. Water-quality data collected from four piezometers near the production wells in November 2003 indicated that the water is a calcium-bicarbonate type with iron concentrations that slightly exceeded the U.S. Environmental Protection Agency?s Secondary Maximum Contaminant Level in three of the four samples. The relatively small concentrations of major ions and nutrients in the samples indicate that there is no contamination from septic-tank effluent and dissolved road salt in the ground water at the Village of Pulaski well field. Three of the four samples were analyzed for total coliform bacteria and Escherichia coli (E. coli), and only total coliform bacteria were detected in all three samples. E. coli was not detected in any samples. The Villages of Sandy Creek and Lacona use about 270,000 gallons of water per day for public consumption?alternating withdrawals from northern and southern well fields located in glaciolacustrine beach, glaciofluvial outwash, and alluvial inwash deposits consisting mostly of silty sand and gravel. Four test wells were drilled, hydraulic heads were measured, and water samples collected between 2001 and 2003 and analyzed for physical properties, inorganic constituents, nutrients, bacteria, tritium, dissolved gases, and chlorofluorocarbons. The aquifer in the Sandy Creek/Lacona area is highly susceptible to contamination because the aquifer (1) is unconfined, (2) is highly transmissive, (3) is thin (10 to 25 feet) and narrow (about 0.5 miles wide), and (4) has relatively short ground-water flowpaths from recharge to discharge areas (including wells). Additionally, drainage ditches east of the southern well field intercept westward-flowing ground water, which then is routed to an area just upgradient from the production wells where some of the water seeps back into the aquifer and is captured by these wells, effectively shortcircuiting the ground-water-flow system. Water-quality samples collected from three wells in the Sandy Creek/Lacona southern well field indicate that the ground water is a sodium-bicarbonate/sulfate type and of good quality; however, in one water sample, the sodium concentration of 6

Prospective PET image quality gain calculation method by optimizing detector parameters.

PubMed

Theodorakis, Lampros; Loudos, George; Prassopoulos, Vasilios; Kappas, Constantine; Tsougos, Ioannis; Georgoulias, Panagiotis

2015-12-01

Lutetium-based scintillators with high-performance electronics introduced time-of-flight (TOF) reconstruction in the clinical setting. Let G' be the total signal to noise ratio gain in a reconstructed image using the TOF kernel compared with conventional reconstruction modes. G' is then the product of G1 gain arising from the reconstruction process itself and (n-1) other gain factors (G2, G3, … Gn) arising from the inherent properties of the detector. We calculated G2 and G3 gains resulting from the optimization of the coincidence and energy window width for prompts and singles, respectively. Both quantitative and image-based validated Monte Carlo models of Lu2SiO5 (LSO) TOF-permitting and Bi4Ge3O12 (BGO) TOF-nonpermitting detectors were used for the calculations. G2 and G3 values were 1.05 and 1.08 for the BGO detector and G3 was 1.07 for the LSO. A value of almost unity for G2 of the LSO detector indicated a nonsignificant optimization by altering the energy window setting. G' was found to be ∼1.4 times higher for the TOF-permitting detector after reconstruction and optimization of the coincidence and energy windows. The method described could potentially predict image noise variations by altering detector acquisition parameters. It could also further contribute toward a long-lasting debate related to cost-efficiency issues of TOF scanners versus the non-TOF ones. Some vendors re-engage nowadays to non-TOF product line designs in an effort to reduce crystal costs. Therefore, exploring the limits of image quality gain by altering the parameters of these detectors remains a topical issue.

Evaluation of clustering algorithms at the < 1 GeV energy scale for the electromagnetic calorimeter of the PADME experiment

NASA Astrophysics Data System (ADS)

Leonardi, E.; Piperno, G.; Raggi, M.

2017-10-01

A possible solution to the Dark Matter problem postulates that it interacts with Standard Model particles through a new force mediated by a “portal”. If the new force has a U(1) gauge structure, the “portal” is a massive photon-like vector particle, called dark photon or A’. The PADME experiment at the DAΦNE Beam-Test Facility (BTF) in Frascati is designed to detect dark photons produced in positron on fixed target annihilations decaying to dark matter (e+e-→γA‧) by measuring the final state missing mass. One of the key roles of the experiment will be played by the electromagnetic calorimeter, which will be used to measure the properties of the final state recoil γ. The calorimeter will be composed by 616 21×21×230 mm3 BGO crystals oriented with the long axis parallel to the beam direction and disposed in a roughly circular shape with a central hole to avoid the pile up due to the large number of low angle Bremsstrahlung photons. The total energy and position of the electromagnetic shower generated by a photon impacting on the calorimeter can be reconstructed by collecting the energy deposits in the cluster of crystals interested by the shower. In PADME we are testing two different clustering algorithms, PADME-Radius and PADME-Island, based on two complementary strategies. In this paper we will describe the two algorithms, with the respective implementations, and report on the results obtained with them at the PADME energy scale (< 1 GeV), both with a GEANT4 based simulation and with an existing 5×5 matrix of BGO crystals tested at the DAΦNE BTF.

Albedo in the ATIC Experiment

NASA Technical Reports Server (NTRS)

Sokolskaya, N. V.; Adams, J. H., Jr.; Ahn, H. S.; Bashindzhagyan, G. L.; Batkov, K. E.; Case, G.; Christl, M.; Chang, J.; Fazely, A. R.; Ganel, O.;

Presence, distribution, and potential sources of nitrate and selected pesticides in the surficial aquifer along the Straight River in north-central Minnesota, 1992-93

USGS Publications Warehouse

Ruhl, J.F.

1995-01-01

Upgradient to downgradient mean or individual nitrogen isotope δ15N values in %o (delta units in parts per thousand) determined for sampled monitoring wells along the direction of ground-water flow through the five land-use settings were: (1) 5.1 %o and 4.0 %o for the feedlot and adjacent manured field; (2) 1.1 %o and 0.9 %o for the cultivated croplands irrigated with waste water; (3) 3.8 %o and 2.7 %o for the cultivated croplands irrigated with ground water; (4) 3.4 %o and 4.9 %o for the residential development; and (5) 1.7 %o and 3.0 %o for the three waste-water lagoons. Nitrate from fertilizer appeared to have been present in ground water at the waste-water lagoons, cultivated croplands irrigated with waste water, and cultivated croplands irrigated with ground water. Nitrate from soil organic matter rather than from animal waste appeared to have been present in ground water at the feedlot and adjacent manured field.

Design, installation, and performance of a multi-layered permeable reactive barrier, Los Alamos National Laboratory

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kaszuba, J. P.; Longmire, P. A.; Strietelmeier, E. A.

2004-01-01

A multi-layered permeable reactive barrier (PRB) has been installed in Mortandad Canyon, on the Pajarito Plateau in the north-central part of LANL, to demonstrate in-situ treatment of a suite of contaminants with dissimilar geochemical properties. The PRB will also mitigate possible vulnerabilities from downgradient contaminant movement within alluvial and deeper perched groundwater. Mortandad Canyon was selected as the location for this demonstration project because the flow of alluvial groundwater is constrained by the geology of the canyon, a large network of monitoring wells already were installed along the canyon reach, and the hydrochemistry and contaminant history of the canyon ismore » well-documented. The PRB uses a funnel-and-gate system with a series of four reactive media cells to immobilize or destroy contaminants present in alluvial groundwater, including strontium-90, plutonium-238,239,240, americium-241, perchlorate, and nitrate. The four cells, ordered by sequence of contact with the groundwater, consist of gravel-sized scoria (for colloid removal); phosphate rock containing apatite (for metals and radionuclides); pecan shells and cotton seed admixed with gravel (bio-barrier, to deplete dissolved oxygen and destroy potential RCRA organic compounds, nitrate and perchlorate); and limestone (pH buffering and anion adsorption). Design elements of the PRB are based on laboratory-scale treatability studies and on a field investigation of hydrologic, geochemical, and geotechnical parameters. The PRB was designed with the following criteria: 1-day residence time within the biobarrier, 10-year lifetime, minimization of surface water infiltration and erosion, optimization of hydraulic capture, and minimization of excavated material requiring disposal. Each layer has been equipped with monitoring wells or ports to allow sampling of groundwater and reactive media, and monitor wells are located immediately adjacent to the up- and down-gradient perimeter of the engineered structure. Groundwater sampling upgradient, within, and downgradient of the PRB took place from May through August 2003. Concentrations of strontium-90 have diminished by 80% and 40% within the central portion of the phosphate rock (apatite) and bio-barrier cells, respectively. Higher concentrations of this radionuclide occur in groundwater near the north and south perimeters of the two cells. The non-uniform distribution of strontium-90 may result from varying residence time and saturated thickness of pore water. Initial concentrations of nitrate (8-12 parts per million or ppm as nitrate) and perchlorate (0.035 ppm) have been reduced in the phosphate rock and bio-barrier cells to concentrations that are less than method detection limits (0.01 and 0.002 ppm, respectively). Initial microbial analyses suggest the presence of both dissimilatory perchlorate- and nitrate-reducing bacterial populations, along with production of acetate and propionate, and decreasing dissolved oxygen and pH. The dominant group of perchlorate reducers consists of members of the previously described Dechloromonas genus, in the beta subclass of the Proteobacteria, which together with the Dechlorosoma genus are considered to be the dominant genera in circum-neutral mesophilic environments. Groundwater flow through the multiple PRB is taking place at a very slow rate based on similar concentrations of nitrate, perchlorate, chlorate, and chlorite in the upgradient well MCO-4B and downgradient well MCO-5. Concentrations of these constituents also increase within the limestone cell. Decreased precipitation due to extreme drought is probably responsible for decreasing saturated thickness within both the alluvium and PRB, resulting in stagnant conditions. Varying distributions of ammonium, nitrate, sulfate, iron, and manganese within the phosphate rock, bio-barrier, and limestone cells also support this hypothesis.« less

Application of Monte Carlo Methods to Perform Uncertainty and Sensitivity Analysis on Inverse Water-Rock Reactions with NETPATH

DOE Office of Scientific and Technical Information (OSTI.GOV)

McGraw, David; Hershey, Ronald L.

Methods were developed to quantify uncertainty and sensitivity for NETPATH inverse water-rock reaction models and to calculate dissolved inorganic carbon, carbon-14 groundwater travel times. The NETPATH models calculate upgradient groundwater mixing fractions that produce the downgradient target water chemistry along with amounts of mineral phases that are either precipitated or dissolved. Carbon-14 groundwater travel times are calculated based on the upgradient source-water fractions, carbonate mineral phase changes, and isotopic fractionation. Custom scripts and statistical code were developed for this study to facilitate modifying input parameters, running the NETPATH simulations, extracting relevant output, postprocessing the results, and producing graphs and summaries.more » The scripts read userspecified values for each constituent’s coefficient of variation, distribution, sensitivity parameter, maximum dissolution or precipitation amounts, and number of Monte Carlo simulations. Monte Carlo methods for analysis of parametric uncertainty assign a distribution to each uncertain variable, sample from those distributions, and evaluate the ensemble output. The uncertainty in input affected the variability of outputs, namely source-water mixing, phase dissolution and precipitation amounts, and carbon-14 travel time. Although NETPATH may provide models that satisfy the constraints, it is up to the geochemist to determine whether the results are geochemically reasonable. Two example water-rock reaction models from previous geochemical reports were considered in this study. Sensitivity analysis was also conducted to evaluate the change in output caused by a small change in input, one constituent at a time. Results were standardized to allow for sensitivity comparisons across all inputs, which results in a representative value for each scenario. The approach yielded insight into the uncertainty in water-rock reactions and travel times. For example, there was little variation in source-water fraction between the deterministic and Monte Carlo approaches, and therefore, little variation in travel times between approaches. Sensitivity analysis proved very useful for identifying the most important input constraints (dissolved-ion concentrations), which can reveal the variables that have the most influence on source-water fractions and carbon-14 travel times. Once these variables are determined, more focused effort can be applied to determining the proper distribution for each constraint. Second, Monte Carlo results for water-rock reaction modeling showed discrete and nonunique results. The NETPATH models provide the solutions that satisfy the constraints of upgradient and downgradient water chemistry. There can exist multiple, discrete solutions for any scenario and these discrete solutions cause grouping of results. As a result, the variability in output may not easily be represented by a single distribution or a mean and variance and care should be taken in the interpretation and reporting of results.« less

Nitrate in groundwater and water sources used by riparian trees in an agricultural watershed: A chemical and isotopic investigation in southern Minnesota

USGS Publications Warehouse

Komor, Stephen C.; Magner, Joseph A.

1996-01-01

This study evaluates processes that affect nitrate concentrations in groundwater beneath riparian zones in an agricultural watershed. Nitrate pathways in the upper 2 m of groundwater were investigated beneath wooded and grass-shrub riparian zones next to cultivated fields. Because trees can be important components of the overall nitrate pathway in wooded riparian zones, water sources used by riparian trees and possible effects of trees on nitrate concentrations in groundwater were also investigated. Average nitrate concentrations in shallow groundwater beneath the cultivated fields were 5.5 mg/L upgradient of the wooded riparian zone and 3.5 mg/L upgradient of the grass-shrub zone. Shallow groundwater beneath the fields passed through the riparian zones and discharged into streams that had average nitrate concentrations of 8.5 mg/L (as N). Lateral variations of δD values in groundwater showed that mixing among different water sources occurred beneath the riparian zones. In the wooded riparian zone, nitrate concentrations in shallow groundwater were diluted by upwelling, nitrate-poor, deep groundwater. Upwelling deep groundwater contained ammonium with a δ15N of 5‰ that upon nitrification and mixing with nitrate in shallow groundwater caused nitrate δ15N values in shallow groundwater to decrease by as much as 19.5‰. Stream water penetrated laterally beneath the wooded riparian zone as far as 19 m from the stream's edge and beneath the grass-shrub zone as far as 27 m from the stream's edge. Nitrate concentrations in shallow groundwater immediately upgradient of where it mixed with stream water averaged 0.4 mg/L in the wooded riparian zone and 0.8 mg/L near the grass-shrub riparian zone. Nitrate concentrations increased toward the streams because of mixing with nitrate-rich stream water. Because nitrate concentrations were larger in stream water than shallow groundwater, concentrated nitrate in the streams cannot have come from shallow groundwater at these sites. Water sources of riparian trees were identified by comparing δD values of sap water, soil water, groundwater, and stream water. Soil water was the main water source for trees in the outer 4 to 6 m of one part of the wooded riparian zone and outer 10 m of another part. Groundwater was a significant water source for trees closer to the streams where the water table was less than about 2.1 to 2.7 m below the surface. No evidence was found in the nitrate concentration profiles that trees close to the streams that took up groundwater through their roots also took up nitrate from groundwater. The lack of such evidence is attributed to the nitrate concentration profiles being insufficiently sensitive indicators of nitrate removal by trees.

Simulation of Ground-Water Flow and Areas Contributing Recharge to Production Wells in Contrasting Glacial Valley-Fill Settings, Rhode Island

USGS Publications Warehouse

Friesz, Paul J.; Stone, Janet Radway

2007-01-01

Areas contributing recharge and sources of water to a production well field in the Village of Harrisville and to a production well field in the Town of Richmond were delineated on the basis of calibrated, steady-state ground-water-flow models representing average hydrologic conditions. The study sites represent contrasting glacial valley-fill settings. The area contributing recharge to a well is defined as the surface area where water recharges the ground water and then flows toward and discharges to the well. In Harrisville, the production well field is composed of three wells in a narrow, approximately 0.5-mile-wide, valley-fill setting on opposite sides of Batty Brook, a small intermittent stream that drains 0.64 square mile at its confluence with the Clear River. Glacial stratified deposits are generally less areally extensive than previously published. The production wells are screened in a thin (30 feet) but transmissive aquifer. Paired measurements of ground-water and surface-water levels indicated that the direction of flow between the brook and the aquifer was generally downward during pumping conditions. Long-term mean annual streamflow from two streams upgradient of the well field totaled 0.72 cubic feet per second. The simulated area contributing recharge for the 2005 average well-field withdrawal rate of 224 gallons per minute extended upgradient to ground-water divides in upland areas and encompassed 0.17 square mile. The well field derived 62 percent of pumped water from intercepted ground water and 38 percent from infiltrated stream water from the Batty Brook watershed. For the maximum simulated well-field withdrawal of 600 gallons per minute, the area contributing recharge expanded to 0.44 square mile to intercept additional ground water and infiltration of stream water; the percentage of water derived from surface water, however, was the same as for the average pumping rate. Because of the small size of Batty Brook watershed, most of the precipitation recharge in the watershed was withdrawn by the well field at the maximum rate either by intercepted ground water or indirectly by infiltrated stream water. Because the production wells are screened in a thin and transmissive aquifer in a small watershed, simulated ground-water traveltimes from recharge locations to the discharging wells were relatively short: 93 percent of the traveltimes were 10 years or less. In Richmond, the production well field is composed of two wells adjacent to and east of the Wood River in a moderately broad, approximately 1.2-mile-wide, valley-fill setting. The wells are screened in a transmissive aquifer with saturated thickness greater than 60 feet. Streamflow measurements in Baker Brook, a tributary to the Wood River 0.4 mile north of the well-field site, indicated that natural net loss of streamflow between the upland-valley contact and a downstream site was 0.12 cubic feet per second under average hydrologic conditions. Simulated areas contributing recharge for the maximum well-field pumping rate of 675 gallons per minute and for one-half the maximum rate extended northeastward from the well field to ground-water divides in upland areas. The area contributing recharge also included a remote, isolated area on the opposite side of the Wood River from the well field. The model simulation indicated that the well field did not derive any of its water from the Wood River because of the large watershed and associated quantity of ground water available for capture by the well field. The area contributing recharge for one-half the maximum rate was 0.31 square mile and the primary source of water to the well field was direct precipitation recharge. Fifteen percent of the water withdrawn from the production wells, however, was obtained from Baker Brook, indicating the importance of even small, distant tributary streams to the contributing area to a well. The area contributing recharge on the opposite side of the Wood River is

Preliminary Results From the First Flight of ATIC: The Silicon Matrix

NASA Technical Reports Server (NTRS)

Adams, James H., Jr.; Ahn, H. S.; Bashindzhagyan, G.; Ampe, J.; Case, G.; Whitaker, Ann F. (Technical Monitor)

2001-01-01

The Advanced Thin Ionization Calorimeter (ATIC) uses a silicon matrix detector in conjunction with a scintillator hodoscope to determine the incident cosmic ray's charge. Cosmic rays that interact in a carbon target have their energy determined from the shower that develops within a fully active calorimeter composed of a stack of scintillating BGO crystals. The silicon matrix consists of 4480 individual silicon pads, each capable of measuring the signal from cosmic rays with atomic numbers from I to 26. Preliminary results will be presented describing the performance of the silicon matrix during the 16-day maiden flight of ATIC around Antarctica.

Preliminary Results from the First Flight of ATIC: The Silicon Matrix

NASA Technical Reports Server (NTRS)

Adams, J. H., Jr.; Whitaker, Ann F. (Technical Monitor)

2001-01-01

The Advanced Thin Ionization Calorimeter (ATIC) uses a silicon matrix detector to determine charge in conjunction with a scintillator hodoscope that measures charge and trajectory. Cosmic rays that interact in a carbon target have their energy determined from the shower that develops within a fully active calorimeter composed of a stack of scintillating BGO crystals. The silicon matrix consists of 4480 individual silicon pads, each capable of measuring the signal from cosmic rays with atomic numbers from 1 to 26. Preliminary results will be presented describing the performance of the silicon matrix during the 16-day maiden flight of ATIC around Antarctica.

First Results with TIGRESS and Accelerated Radioactive Ion Beams from ISAC: Coulomb Excitation of 20,21,29Na

NASA Astrophysics Data System (ADS)

Schumaker, M. A.; Hurst, A. M.; Svensson, C. E.; Wu, C. Y.; Becker, J. A.; Cline, D.; Hackman, G.; Pearson, C. J.; Stoyer, M. A.; Andreyev, A.; Austin, R. A. E.; Ball, G. C.; Bandyopadhyay, D.; Barton, C. J.; Boston, A. J.; Boston, H. C.; Buchmann, L.; Churchman, R.; Cifarelli, F.; Colosimo, S. J.; Cooper, R. J.; Cross, D. S.; Dashdorj, D.; Demand, G. A.; Dimmock, M. R.; Djongolov, M.; Drake, T. E.; Finlay, P.; Gallant, A. T.; Garrett, P. E.; Gray-Jones, C.; Green, K. L.; Grint, A. N.; Grinyer, G. F.; Harkness, L. J.; Hayes, A. B.; Kanungo, R.; Leach, K. G.; Kulp, W. D.; Lisetskiy, A. F.; Lee, G.; Lloyd, S.; Maharaj, R.; Martin, J.-P.; Millar, B. A.; Moisan, F.; Morton, A. C.; Mythili, S.; Nelson, L.; Newman, O.; Nolan, P. J.; Orce, J. N.; Oxley, D. C.; Padilla-Rodal, E.; Phillips, A. A.; Porter-Peden, M.; Ressler, J. J.; Rigby, S. V.; Roy, R.; Ruiz, C.; Sarazin, F.; Scraggs, D. P.; Sumithrarachchi, C. S.; Triambak, S.; Waddington, J. C.; Walker, P. M.; Wan, J.; Whitbeck, A.; Williams, S. J.; Wong, J.; Wood, J. L.

2009-03-01

The TRIUMF-ISAC Gamma-Ray Escape Suppressed Spectrometer (TIGRESS) is a state-of-the-art γ-ray spectrometer being constructed at the ISAC-II radioactive ion beam facility at TRIUMF. TIGRESS will be comprised of twelve 32-fold segmented high-purity germanium (HPGe) clover-type γ-ray detectors, with BGO/CsI(Tl) Compton-suppression shields, and is currently operational at ISAC-II in an early-implementation configuration of six detectors. Results have been obtained for the first experiments performed using TIGRESS, which examined the A = 20, 21, and 29 isotopes of Na by Coulomb excitation.

Simulated characteristics of the DEGAS γ-detector array

NASA Astrophysics Data System (ADS)

Li, G. S.; Lizarazo, C.; Gerl, J.; Kojouharov, I.; Schaffner, H.; Górska, M.; Pietralla, N.; Saha, S.; Liu, M. L.; Wang, J. G.

2018-05-01

The performance of the novel HPGe-Cluster array DEGAS to be used at FAIR has been studied through GEANT4 simulations using accurate geometries of most of the detector components. The simulation framework has been tested by comparing experimental data of various detector setups. The study showed that the DEGAS system could provide a clear improvement of the photo-peak efficiency compared to the previous RISING array. In addition, the active BGO Back-catcher could greatly enhance the background suppression capability. The add-back analysis revealed that even at a γ multiplicity of six the sensitivity is improved by adding back the energy depositions of the neighboring Ge crystals.

High Energy Cosmic Ray Electron Spectra measured from the ATIC Balloon Experiment

NASA Technical Reports Server (NTRS)

Chang, J.; Schmidt, W. K. H.; Adams, J. H.; Ahn, H. S.; Bashindzhagyan, G.; Batkov, K. E.; Christl, M.; Fazely, A. R.; Ganel, O.; Gunasingha, R. M.

2003-01-01

The Advanced Thin Ionization Calorimeter Balloon Experiment (ATIC) is specifically designed for high energy cosmic ray ion detection. From simulation and a CERN beam test exposure we find that the design consisting of a graphite target and an energy detection device, a totally active calorimeter of BGO scintillator, gives us sufficient information to distinguish electrons from protons up to the TeV energy range. Balloon observations were successfully carried out over Antarctica in both 2000/2001 and 2002/2003 for a total of more than 35 days. This paper presents preliminary results on the spectrum of high energy electrons observed in the first ATIC flight.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Last, G.V.; Eddy, P.A.; Airhart, S.P.

The information presented in this report was collected during limited site investigation activities conducted in the vicinity of Landfills 1 and 4 at Fort Lewis. The purpose of this work was to provide a means of detecting and evaluating the impacts of these inactive landfills on ground-water quality and adjacent lands. This effort included the design and construction of ground-water monitoring systems for compliance with applicable federal and state regulations governing Resource Conservation and Recovery Act (RCRA)-type landfills. Ground-water samples were collected from both existing (1981 and 1984) wells and the newly installed (1988) wells. The analytical results from themore » water samples indicate that the ground water in and around Landfill 1 contains limited contamination. Contaminants may include volatile organic compounds and nitrate. The primary concern in the area around Landfill 1 was the determination that ground water from two wells may contain cis-1,2-dichloroethylene and 1,1,1-trichloroethylene above drinking water standards. Nitrate levels in the downgradient wells were greater than those in upgradient wells and exceeded drinking water standards in some of the less-representative samples. Analyses of ground-water samples from wells in and around Landfill 4 indicate several contaminants may be present. These include volatile organic compounds (principally cis-1,2-dichloroethylene and 1,1,1-trichloroethylene), coliform, oil and grease, and perhaps some metals (iron and magnesium). The primary concern in the area around Landfill 4 was the determination that ground water from five wells contained cis-1,2-dichloroethylene and 1,1,1-trichloroethylene above drinking water standards. The source of contaminants beneath either landfill cannot yet be identified. Insufficient data exist to disprove or confirm either landfill as possible contributors. 19 refs., 32 figs., 17 tabs.« less

Tritium, stable isotopes, and nitrogen in flow from selected springs that discharge to the Snake River, Twin Falls-Hagerman area, Idaho, 1990-93

USGS Publications Warehouse

Mann, L.J.; Low, W.H.

1994-01-01

In 1990-93, water from 19 springs along the north side of the Snake River near Twin Falls and Hagerman contained from 9.2+0.6 to 78.4+5.1 picocuries per liter (pCi/L) of tritium. The springs were placed into three categories based on their locations and tritium concentrations: Category I was the upstream most and contained from 52.8+3.2 to 78.4+5.1 pCi/L of tritium; Category 11 was downstream from those in Category I and contained from 9.2+0.6 to 18.6+1.2 pCi/L; and Category III was the farthest downstream and contained from 28.3+1.9 to 47.7+3.2 pCi/L. Differences in tritium concentrations in the Category I, II, and III springs are a function of the ground-water flow regime, land use, and irrigation practices in and hydraulically upgradient from each category of springs. A comparatively large part of the water from the Category I springs is derived from recharge in heavily irrigated areas in which the irrigation water largely is diverted from the Snake River. A large part of the recharge for Category II springs occurs as much as 140 miles upgradient. Tritium concentrations in Category III springs indicate an intermediate proportion of the recharge is from excess applied-irrigation water. The concept that recharge from excess applied- irrigation water from the Snake River has affected tritium in the aquifer is supported by isotopic and nitrogen data. Deuterium and oxygen-18 isotopic values, and nitrite plus nitrate as nitrogen concentrations in the flow of some springs has been impacted by irrigation.

Field sampling and analysis plan for the remedial investigation of Waste Area Grouping 2 at Oak Ridge National Laboratory, Oak Ridge, Tennessee. Environmental Restoration Program

DOE Office of Scientific and Technical Information (OSTI.GOV)

Boston, H.L.; Ashwood, T.L.; Borders, D.M.

1992-02-01

This field sampling and analysis (S & A) plan has been developed as part of the Department of Energy`s (DOE`s) remedial investigation (RI) of Waste Area Grouping (WAG) 2 at Oak Ridge National Laboratory (ORNL) located in Oak Ridge, Tennessee. The S & A plan has been written in support of the remedial investigation (RI) plan for WAG 2 (ORNL 1990). WAG 2 consists of White Oak Creek (WOC) and its tributaries downstream of the ORNL main plant area, White Oak Lake (WOL), White Oak Creek embayment (WOCE) on the Clinch River, and the associated floodplain and subsurface environment (Fig.more » 1.1). The WOC system is the surface drainage for the major ORNL WAGs and has been exposed to a diversity of contaminants from operations and waste disposal activities in the WOC watershed. WAG 2 acts as a conduit through which hydrologic fluxes carry contaminants from upgradient areas to the Clinch River. Water, sediment, soil, and biota in WAG 2 are contaminated and continue to receive contaminants from upgradient WAGs. This document describes the following: an overview of the RI plan, background information for the WAG 2 system, and objectives of the S & A plan; the scope and implementation of the first 2 years of effort of the S & A plan and includes recent information about contaminants of concern, organization of S & A activities, interactions with other programs, and quality assurance specific to the S & A activities; provides details of the field sampling plans for sediment, surface water, groundwater, and biota, respectively; and describes the sample tracking and records management plan.« less

A piecewise-focused high DQE detector for MV imaging.

PubMed

Star-Lack, Josh; Shedlock, Daniel; Swahn, Dennis; Humber, Dave; Wang, Adam; Hirsh, Hayley; Zentai, George; Sawkey, Daren; Kruger, Isaac; Sun, Mingshan; Abel, Eric; Virshup, Gary; Shin, Mihye; Fahrig, Rebecca

2015-09-01

Electronic portal imagers (EPIDs) with high detective quantum efficiencies (DQEs) are sought to facilitate the use of the megavoltage (MV) radiotherapy treatment beam for image guidance. Potential advantages include high quality (treatment) beam's eye view imaging, and improved cone-beam computed tomography (CBCT) generating images with more accurate electron density maps with immunity to metal artifacts. One approach to increasing detector sensitivity is to couple a thick pixelated scintillator array to an active matrix flat panel imager (AMFPI) incorporating amorphous silicon thin film electronics. Cadmium tungstate (CWO) has many desirable scintillation properties including good light output, a high index of refraction, high optical transparency, and reasonable cost. However, due to the 0 1 0 cleave plane inherent in its crystalline structure, the difficulty of cutting and polishing CWO has, in part, limited its study relative to other scintillators such as cesium iodide and bismuth germanate (BGO). The goal of this work was to build and test a focused large-area pixelated "strip" CWO detector. A 361 × 52 mm scintillator assembly that contained a total of 28 072 pixels was constructed. The assembly comprised seven subarrays, each 15 mm thick. Six of the subarrays were fabricated from CWO with a pixel pitch of 0.784 mm, while one array was constructed from BGO for comparison. Focusing was achieved by coupling the arrays to the Varian AS1000 AMFPI through a piecewise linear arc-shaped fiber optic plate. Simulation and experimental studies of modulation transfer function (MTF) and DQE were undertaken using a 6 MV beam, and comparisons were made between the performance of the pixelated strip assembly and the most common EPID configuration comprising a 1 mm-thick copper build-up plate attached to a 133 mg/cm(2) gadolinium oxysulfide scintillator screen (Cu-GOS). Projection radiographs and CBCT images of phantoms were acquired. The work also introduces the use of a lightweight edge phantom to generate MTF measurements at MV energies and shows its functional equivalence to the more cumbersome slit-based method. Measured and simulated DQE(0)'s of the pixelated CWO detector were 22% and 26%, respectively. The average measured and simulated ratios of CWO DQE(f) to Cu-GOS DQE(f) across the frequency range of 0.0-0.62 mm(-1) were 23 and 29, respectively. 2D and 3D imaging studies confirmed the large dose efficiency improvement and that focus was maintained across the field of view. In the CWO CBCT images, the measured spatial resolution was 7 lp/cm. The contrast-to-noise ratio was dramatically improved reflecting a 22 × sensitivity increase relative to Cu-GOS. The CWO scintillator material showed significantly higher stability and light yield than the BGO material. An efficient piecewise-focused pixelated strip scintillator for MV imaging is described that offers more than a 20-fold dose efficiency improvement over Cu-GOS.

A piecewise-focused high DQE detector for MV imaging

PubMed Central

Star-Lack, Josh; Shedlock, Daniel; Swahn, Dennis; Humber, Dave; Wang, Adam; Hirsh, Hayley; Zentai, George; Sawkey, Daren; Kruger, Isaac; Sun, Mingshan; Abel, Eric; Virshup, Gary; Shin, Mihye; Fahrig, Rebecca

2015-01-01

Purpose: Electronic portal imagers (EPIDs) with high detective quantum efficiencies (DQEs) are sought to facilitate the use of the megavoltage (MV) radiotherapy treatment beam for image guidance. Potential advantages include high quality (treatment) beam’s eye view imaging, and improved cone-beam computed tomography (CBCT) generating images with more accurate electron density maps with immunity to metal artifacts. One approach to increasing detector sensitivity is to couple a thick pixelated scintillator array to an active matrix flat panel imager (AMFPI) incorporating amorphous silicon thin film electronics. Cadmium tungstate (CWO) has many desirable scintillation properties including good light output, a high index of refraction, high optical transparency, and reasonable cost. However, due to the 0 1 0 cleave plane inherent in its crystalline structure, the difficulty of cutting and polishing CWO has, in part, limited its study relative to other scintillators such as cesium iodide and bismuth germanate (BGO). The goal of this work was to build and test a focused large-area pixelated “strip” CWO detector. Methods: A 361  ×  52 mm scintillator assembly that contained a total of 28 072 pixels was constructed. The assembly comprised seven subarrays, each 15 mm thick. Six of the subarrays were fabricated from CWO with a pixel pitch of 0.784 mm, while one array was constructed from BGO for comparison. Focusing was achieved by coupling the arrays to the Varian AS1000 AMFPI through a piecewise linear arc-shaped fiber optic plate. Simulation and experimental studies of modulation transfer function (MTF) and DQE were undertaken using a 6 MV beam, and comparisons were made between the performance of the pixelated strip assembly and the most common EPID configuration comprising a 1 mm-thick copper build-up plate attached to a 133 mg/cm2 gadolinium oxysulfide scintillator screen (Cu-GOS). Projection radiographs and CBCT images of phantoms were acquired. The work also introduces the use of a lightweight edge phantom to generate MTF measurements at MV energies and shows its functional equivalence to the more cumbersome slit-based method. Results: Measured and simulated DQE(0)’s of the pixelated CWO detector were 22% and 26%, respectively. The average measured and simulated ratios of CWO DQE(f) to Cu-GOS DQE(f) across the frequency range of 0.0–0.62 mm−1 were 23 and 29, respectively. 2D and 3D imaging studies confirmed the large dose efficiency improvement and that focus was maintained across the field of view. In the CWO CBCT images, the measured spatial resolution was 7 lp/cm. The contrast-to-noise ratio was dramatically improved reflecting a 22 × sensitivity increase relative to Cu-GOS. The CWO scintillator material showed significantly higher stability and light yield than the BGO material. Conclusions: An efficient piecewise-focused pixelated strip scintillator for MV imaging is described that offers more than a 20-fold dose efficiency improvement over Cu-GOS. PMID:26328960

Use of 222Rn as natural tracer for LNAPL quantification and recovery efficiency in a crude-oil contaminated aquifer

NASA Astrophysics Data System (ADS)

Ponsin, Violaine; Chablais, Amélie; Dumont, Julien; Cardetti, Marc; Radakovitch, Olivier; Höhener, Patrick

2014-05-01

In august 2009, five hectares of the pristine gravel aquifer of Crau in southern France were contaminated by 5,100 m3 of crude oil due to the sudden break of a pipeline. The remediation of this site is still ongoing and consists in replacement and off-site disposal of contaminated topsoils, plume management by hydraulic groundwater barriers with re-injection of activated charcoal-treated waters, and dual-phase LNAPL extraction in the source zone. It is anticipated to stop these remediation actions when the rate of hydrocarbon extraction becomes inefficient. The volume of LNAPL is estimated between 100 and 1000 m3. A more accurate estimation is needed for the implementation of natural attenuation once physical treatment is discontinued. 222Rn has been introduced as a natural tracer for the quantification of LNAPL saturation in porous media under natural gradient conditions (Hunkeler et al., 1997; Semprini et al., 2000; Schubert et al., 2007). The objective of this study was to investigate whether 222Rn in groundwater can be used as a tracer for LNAPL quantification at a field site treated by LNAPL removal. To this end, groundwater samples were obtained in pristine monitoring wells from upgradient the contamination using submersible electric pumps, and in LNAPL recovery wells. There, samples were obtained from the tap on the hard PVC tubing used for pumping groundwater to the treatment facility. For 222Rn analysis, flasks of 250 mL were gently filled and were capped thereafter without permitting air bubbles. The flasks were analysed within 6 to 24 hours. The 222Rn activity of groundwater was measured by a Rn detector (RAD7-Durridge, Co. Inc.). The measurements were spaced over more than 15 months in order to account for seasonal changes. Each well was sampled at least 3 times. In pristine groundwater, the radon activity was relatively constant and remained always > 14 Bq/L. The radon activities in the groundwater of source zone wells were also relatively constant and the mean activities were generally significantly lower than upgradient. This is due to partitioning into the oil phase. Decreases were correlated with NAPL recovery efficiency. The laboratory-determined crude oil-water partitioning coefficient of 38,5 ± 2,9 was used for estimating LNAPL saturation in each recovery well. However, extrapolations of LNAPL saturations to whole-site oil volume estimations are difficult since at low water tables, the volume in the capillary fringe is not assessed. Nevertheless, we find that 222Rn is a useful and cheap groundwater tracer for finding zones of good LNAPL recovery in a heavily pumped aquifer. Hunkeler, D., E. Hoehn, P. Höhener and J. Zeyer, 1997. 222Rn as a partitioning tracer to detect mineral oil contaminations: laboratory experiments and field study. Environmental Science and Technology 31, 3180-3187. Semprini, L., O.S. Hopkins and B.R. Tasker, 2000. Laboratory, field and modeling studies of radon-222 as a natural tracer for monitoring NAPL contamination. Transport in Porous Media 38, 223-240. Schubert, M., A. Paschke, S. Lau, W. Geyer and K. Knöller, 2007. Radon as a naturally occurring tracer for the assessment of residual NAPL contamination of aquifers. Environmental Pollution 145, 920-927.

Hydrology of the Cave Springs area near Chattanooga, Hamilton County, Tennessee

USGS Publications Warehouse

Bradfield, Arthur D.

1992-01-01

The hydrology of Cave Springs, the second largest spring in East Tennessee,was investigated from July 1987 to September 1989. Wells near the spring supply about 5 million gallons per day of potable water to people in Hamilton County near Chattanooga. Discharge from the spring averaged about 13.5 cubic feet per second (8.72 million gallons per day) during the study period. Withdrawals by the Hixson Utility District from wells upgradient from the outflow averaged 8.6 cubic feet per second (5.54 million gallons per day). Aquifer tests using wells intersecting a large solution cavity supplying water to the spring showed a drawdown of less than 3 feet with a discharge of 9,000 gallons per minute or 20 cubic feet per second. Temperature and specific conductance of ground water near the spring outflow were monitored hourly. Temperatures ranged from 13.5 to 18.2 degrees celsius, and fluctuated seasonally in response to climate. Specific-conductance values ranged from 122 to 405 microsiemens per centimeter at 25 degrees Celsius, but were generally between 163 to 185 microsiemensper centimeter. The drainage area of the basin recharging the spring system was estimated to be 1O squaremiles. A potentiometric map of the recharge basin was developed from water levels measured at domestic and test wells in August 1989. Aquifer tests at five test wells in the study area indicated that specific-capacity values for these wells ranged from 4.1 to 261 gallons per minute per foot of drawdown. Water-quality characteristics of ground water in the area were used in conjunction with potentiometric-surface maps to delineate the approximate area contributing recharge to Cave Springs.

Design upgrades to the DIII-D gamma ray imager

NASA Astrophysics Data System (ADS)

Lvovskiy, A.; Cooper, C. M.; Eidietis, N. W.; Pace, D.; Paz-Soldan, C.

2016-10-01

Generation of runaway electrons (RE) in tokamak disruptions can cause damage of plasma facing components. RE studies are necessary in order to provide a reliable mechanism of RE mitigation. For that task a gamma ray imager (GRI) has been developed for DIII-D. It measures the bremsstrahlung emission by RE providing information on RE energy spectrum and RE distribution across a poloidal cross-section. The GRI consists of a lead pinhole camera illuminating a 2D array of 30 BGO detectors placed in the DIII-D mid-plane. First results showed the successful measurements of RE energy spectra in the range 1 - 60 MeV with time resolution 100 μs. They have been obtained in the low-flux quiescent RE regime via pulse-high analysis. The measurements in the high gamma flux post-disruption RE regime showed strong signal saturation. Here we present GRI design upgrades towards signal attenuation and better detector shielding including Monte-Carlo Neutral Particle modeling of GRI irradiation, as well as improved calibration techniques and options to improve electronic noise rejection. Work supported by US DOE under DE-AC05-06OR23100 and DE-FC02-04ER54698.

Present status of the low energy linac-based slow positron beam and positronium spectrometer in Saclay

NASA Astrophysics Data System (ADS)

Liszkay, L.; Comini, P.; Corbel, C.; Debu, P.; Grandemange, P.; Pérez, P.; Rey, J.-M.; Reymond, J.-M.; Ruiz, N.; Sacquin, Y.; Vallage, B.

2014-04-01

A new slow positron beamline featuring a large acceptance positronium lifetime spectrometer has been constructed and tested at the linac-based slow positron source at IRFU CEA Saclay, France. The new instrument will be used in the development of a dense positronium target cloud for the GBAR experiment. The GBAR project aims at precise measurement of the gravitational acceleration of antihydrogen in the gravitational field of the Earth. Beyond application in fundamental science, the positron spectrometer will be used in materials research, for testing thin porous films and layers by means of positronium annihilation. The slow positron beamline is being used as a test bench to develop further instrumentation for positron annihilation spectroscopy (Ps time-of-flight, pulsed positron beam). The positron source is built on a low energy linear electron accelerator (linac). The 4.3 MeV electron energy used is well below the photoneutron threshold, making the source a genuine on-off device, without remaining radioactivity. The spectrometer features large BGO (Bismuth Germanate) scintillator detectors, with sufficiently large acceptance to detect all ortho-positronium annihilation lifetime components (annihilation in vacuum and in nanopores).

Capstone Report on the Application, Monitoring, and Performance of Permeable Reactive Barriers for Ground-Water Remediation: Volume 1: Performance Evaluations at Two Sites

DTIC Science & Technology

2003-08-01

sepiolite , Mg 4 (OH) 2 Si 6 O 15 ·H 2 O...EC050801-3-5 EC050801-3-3 EC050801-3-2 EC050801-3-1 In te n si ty degrees 2-theta In te n si ty In te n si ty downgradient edge upgradient edge In te n...400 b ic a rb o n a te , m g /L 0 2 4 6 8 10 12 14 16 si lic a , m g /L Figure 4.12 Average (± 1 s.d.) concentrations of Na, K , Ca,

The nature of large-scale turbulence in the Jovian atmosphere

NASA Technical Reports Server (NTRS)

Mitchell, J. L.

1982-01-01

The energetics and spectral characteristis of quasi-geostrophic turbulence in Jupiter's atmosphere are examined using sequences of Voyager images and infrared temperature soundings. Using global wind measurements momentum transports associated with zonally symmetric stresses and turbulent stresses are quantified. Though a strong up-gradient flux of momentum by eddies was observed, measurements do not preclude the possibility that symmetric stresses play a critical role in maintaining the mean zonal circulation. Strong correlation between the observed meridional distribution of eddy-scale kinetic energy and available potential energy suggests coupling between the observed cloudtop turbulent motions and the upper tropospheric thermodynamics. An Oort energy budget for Jupiter's upper troposphere is formulated.

Ground-water quality near an inactive landfill and sludge-spreading area, Tallahassee, Florida

USGS Publications Warehouse

Berndt, M.P.

1993-01-01

Groundwater quality at and near a landfill southwest of Tallahassee, Florida, where sludge from a municipal sewage-treatment plant was also applied, was assessed by sampling 21 monitoring wells and analyzing for various constituents. Water quality in the Upper Floridan aquifer at the site was compared to the water quality of 20 background wells in Leon County. Water quality in all samples from wells at the site was evaluated in relation to the landfill and sludge-spreading and nonsludge- spreading areas. Results from nonparametric statistical tests showed that potassium and nitrate concentrations were significantly different in samples from the Upper Floridan aquifer at the site and in samples from background wells. Median potassium concentrations were 0.7 mg/L in samples collected at the site and 0.4 mg/L in samples collected from background wells, whereas median nitrate concentration was 6.48 mg/L at the site and 0.51 mg/L in background wells. Graphical comparison of concentration distributions in six categories of wells; upgradient, landfill, adjacent to the landfill, downgradient onsite, downgradient offsite, and from background wells in Leon County, indicated that sodium, bicarbonate, sulfate, iron, manganese, dissolved solids, and specific conductance had highest concentrations in water from wells within the landfill. Nitrate concentrations were lowest in samples from wells in the landfill compared to the other categories. Concentrations of trace metals and organic constituents were mostly below detection limits although State maximum contaminant levels of 1.0 microg/L for benzene and vinyl chloride and 3.0 microg/L for tetrachloroethene were exceeded in water from some wells. Nitrate and chloride concentrations were significantly different in sludge-spreading and nonsludge-spreading areas. Median nitrate and chloride concentrations of 6.9 microg/L and 2.9 microg/L were detected in groundwater in sludge-spreading areas compared to 1.1 mg/L and 1.8 mg/L in nonsludge-spreading areas.

Fermi GBM Observations of Terrestrial Gamma-ray Flashes

DOE Office of Scientific and Technical Information (OSTI.GOV)

Briggs, Michael S.

2011-09-21

Terrestrial Gamma-ray Flashes are short pulses of energetic radiation associated with thunderstorms and lightning. While the Gamma-ray Burst Monitor (GBM) on Fermi was designed to observe gamma-ray bursts, its large BGO detectors are excellent for observing TGFs. Using GBM, TGF pulses are seen to either be symmetrical or have faster rise time than fall times. Some TGFs are resolved into double, partially overlapping pulses. Using ground-based radio observations of lightning from the World Wide Lightning Location Network (WWLLN), TGFs and their associated lightning are found to be simultaneous to {approx_equal}40 {mu} s. The lightning locations are typically within 300 kmmore » of the sub-spacecraft point.« less

Detection of High Energy Cosmic Rays with Advanced Thin Ionization Calorimeter, ATIC

NASA Technical Reports Server (NTRS)

Adams, J. H.; Ahn, E. J.; Ahn, H. S.; Bashindzhagyan, G.; Case, G.; Chang, J.; Christl, M.; Ellison, S.; Fazely, A. R.; Ganel, O.

2002-01-01

The author presents preliminary results of the first flight of the Advanced Thin Ionization Calorimeter (ATIC). ATIC is a multiple, long duration balloon flight, investigation for the study of cosmic ray spectra from below 50 GeV to near 100 TeV total energy, using a fully active Bismuth Germanate (BGO) calorimeter. It is equipped with the first large area mosaic of small fully depleted silicon detector pads capable of charge identification of cosmic rays from H to Fe. As a redundancy check for the charge identification and a coarse particle tracking system, three projective layers of x-y scintillator hodoscopes were employed, above, in the center and below a Carbon interaction 'target'.

ATIC Flight Data Processing

NASA Technical Reports Server (NTRS)

Ahn, H. S.; Whitaker, Ann F. (Technical Monitor)

2001-01-01

The first flight of the Advanced Thin Ionization Calorimeter (ATIC) experiment from McMurdo, Antarctica lasted for 16 days, starting in December, 2000. The ATIC instrument consists of a fully active 320-crystal, 960-channel Bismuth Germanate (BGO) calorimeter, 202 scintillator strips in 3 hodoscopes interleaved with a graphite target, and a 4480-pixel silicon matrix charge detector. We have developed an Object Oriented data processing package based on ROOT. In this paper, we will describe the data processing scheme used in handling the accumulated 45 GB of flight data. We will also discuss trigger issues by comparing the measured energy-dependent trigger efficiency with its simulation and calibration issues by considering the time-dependence of housekeeping information, etc.

Direct measurement of nuclear cross sections of astrophysical relevance at LUNA: The 22Ne(p, γ) 23Na reaction

NASA Astrophysics Data System (ADS)

Ferraro, F.; LUNA Collaboration

2017-01-01

Most of the elements constituting the universe were produced in stars through a series of nuclear reactions. LUNA performs direct measurements of nuclear cross sections relevant to astrophysics, taking advantage of the low background at LNGS. The ^{22}Ne(p,γ)^{23}Na reaction rate, which belongs to the NeNa cycle of hydrogen burning, has been recently studied. Its rate is still very uncertain because of a lot of resonances lying inside the Gamow window. LUNA discovered three new resonances using two high-purity germanium detectors and considerably improved the existing upper limits on the lower energy resonances using a high-efficiency optically-segmented BGO crystal.

Experimental search for the radiative capture reaction d + d {yields} {sup 4}He + {gamma} from the dd{mu} muonic molecule state J = 1

DOE Office of Scientific and Technical Information (OSTI.GOV)

Baluev, V. V.; Bogdanova, L. N.; Bom, V. R.

2011-07-15

A search for the muon-catalyzed fusion reaction d + d {yields} {sup 4}He + {gamma} in the dd{mu} muonic molecule was performed using the experimental installation TRITON with BGO detectors for {gamma}-quanta. A high-pressure target filled with deuterium was exposed to the negative muon beam of the JINR Phasotron to detect {gamma}-quanta with the energy 23.8 MeV. An experimental estimation for the yield of radiative deuteron capture from the dd{mu} state J = 1 was obtained at the level of {eta}{sub {gamma}} {<=} 8 Multiplication-Sign 10{sup -7} per fusion.

The Electron Spectrum above 20 GeV Measured by ATIC

NASA Technical Reports Server (NTRS)

Chang, J.; Schmidt, W. K. H.; Adams, J. H.; Ahn, H. S.; Bashindzhagyan, G.; Batkov, K. E.; Christl, M.; Fazely, A. R.; Ganel, O.; Gunasingha, R. M.

2004-01-01

The Advanced Thin Ionization Calorimeter (ATIC) Balloon Experiment has been flown from McMurdo, Antarctica in 2000-01 (test flight) and 2002-03 (science flight). ATIC is composed of a segmented BGO calorimeter following a carbon target with scintillator tracking layers and a Silicon matrix detector at the entrance. ATIC measures the composition and energy spectra of the nuclei plus electrons. We present the electron spectrum derived from the ATIC flights, from 20 GeV to 3 TeV, and compare it to existing very high energy measurements from emulsion chambers and to the results of galactic propagation calculations. The good energy resolution and high statistics in the ATIC data allow detailed astrophysical interpretation of the results.

Fast, Dense Low Cost Scintillator for Nuclear Physics

DOE Office of Scientific and Technical Information (OSTI.GOV)

Woody, Craig

2009-07-31

We have studied the morphology, transparency, and optical properties of SrHfO{sub 3}:Ce ceramics. Ceramics can be made transparent by carefully controlling the stoichiometry of the precursor powders. When fully dense, transparent samples can be obtained. Ceramics with a composition close to stoichiometry (Sr:Hf ~ 1) appear to show good transparency and a reasonable light yield several times that of BGO. The contact and distance transparency of ceramics hot-pressed at about 1450ºC is very good, but deteriorates at increasingly higher hot-press temperatures. If these ceramics can be produced in large quantities and sizes, at low cost, they may be of considerablemore » interest for PET and CT.« less

Monte Carlo Simulations of Background Spectra in Integral Imager Detectors

NASA Technical Reports Server (NTRS)

Armstrong, T. W.; Colborn, B. L.; Dietz, K. L.; Ramsey, B. D.; Weisskopf, M. C.

1998-01-01

Predictions of the expected gamma-ray backgrounds in the ISGRI (CdTe) and PiCsIT (Csl) detectors on INTEGRAL due to cosmic-ray interactions and the diffuse gamma-ray background have been made using a coupled set of Monte Carlo radiation transport codes (HETC, FLUKA, EGS4, and MORSE) and a detailed, 3-D mass model of the spacecraft and detector assemblies. The simulations include both the prompt background component from induced hadronic and electromagnetic cascades and the delayed component due to emissions from induced radioactivity. Background spectra have been obtained with and without the use of active (BGO) shielding and charged particle rejection to evaluate the effectiveness of anticoincidence counting on background rejection.

Transport of free and particulate-associated bacteria in karst

USGS Publications Warehouse

Mahler, B.J.; Personne, J.-C.; Lods, G.F.; Drogue, C.

2000-01-01

Karst aquifers, because of their unique hydrogeologic characteristics, are extremely susceptible to contamination by pathogens. Here we present the results of an investigation of contamination of a karst aquifer by fecal indicator bacteria. Two wells intercepting zones with contrasting effective hydraulic conductivities, as determined by pump test, were monitored both during the dry season and in response to a rain event. Samples were also collected from the adjacent ephemeral surface Stream, which is known to be impacted by an upstream wastewater treatment plant after rainfall. Whole water and suspended sediment samples were analyzed for fecal coliforms and enterococci. During the dry season, pumping over a 2-day period resulted in increases in concentrations of fecal coliforms to greater than 10,000 CFU/100 ml in the high-conductivity well; enterococci and total suspended solids also increased, to a lesser degree. Toward the end of the pumping period, as much as 50% of the fecal coliforms were associated with suspended sediment. Irrigation of an up-gradient pine plantation with primary-treated wastewater is the probable source of the bacterial contamination. Sampling after a rain event revealed the strong influence of water quality of the adjacent Terrieu Creek on the ground water. Bacterial concentrations in the wells showed a rapid response to increased concentrations in the surface water, with fecal coliform concentrations in ground water ultimately reaching 60,000 CFU/100 ml. Up to 100% of the bacteria in the ground water was associated with suspended sediment at various times. The results of this investigation are evidence of the strong influence of surface water on ground water in karst terrain, including that of irrigation water. The large proportion of bacteria associated with particulates in the ground Water has important implications for public health, as bacteria associated with particulates may be more persistent and more difficult to inactivate. The high bacterial concentrations found in both wells, despite the difference in hydraulic conductivity, demonstrates the difficulty of predicting vulnerability of individual wells to bacterial contamination in karst. The extreme temporal variability in bacterial concentrations underscores the importance of event-based monitoring of the bacterial quality of public water supplies in karst. (C) 2000 Elsevier Science B.V.Karst aquifers, because of their unique hydrogeologic characteristics, are extremely susceptible to contamination by pathogens. Here we present the results of an investigation of contamination of a karst aquifer by fecal indicator bacteria. Two wells intercepting zones with contrasting effective hydraulic conductivities, as determined by pump test, were monitored both during the dry season and in response to a rain event. Samples were also collected from the adjacent ephemeral surface stream, which is known to be impacted by an upstream wastewater treatment plant after rainfall. Whole water and suspended sediment samples were analyzed for fecal coliforms and enterococci. During the dry season, pumping over a 2-day period resulted in increases in concentrations of fecal coliforms to greater than 10,000 CFU/100 ml in the high-conductivity well; enterococci and total suspended solids also increased, to a lesser degree. Toward the end of the pumping period, as much as 50% of the fecal coliforms were associated with suspended sediment. Irrigation of an up-gradient pine plantation with primary-treated wastewater is the probable source of the bacterial contamination. Sampling after a rain event revealed the strong influence of water quality of the adjacent Terrieu Creek on the ground water. Bacterial concentrations in the wells showed a rapid response to increased concentrations in the surface water, with fecal coliform concentrations in ground water ultimately reaching 60,000 CFU/100 ml. Up to 100% of the bacteria in the ground water was associated with suspended

Contamination of shallow ground water in the area of building 95, Picatinny Arsenal, New Jersey, 1985-90

USGS Publications Warehouse

Sargent, B.P.; Storck, D.A.

1994-01-01

A zone of contaminated ground water at Picatinny Arsenal has resulted from the operation of a metal- plating facility in building 95 during 1960-81, and the wastewater-treatment system that is in and adjacent to the building. Thirty-two monitoring wells were installed in 1989 to supplement 12 previously installed wells. All wells were sampled in 1989 and 1990 for analysis of ground water for inorganic constituents, trace elements, volatile organic compounds, and nutrients. Four wells also were sampled for analysis for base/neutral- and acid-extractable compounds and pesticides, and soil gas from the unsaturated zone at eight sites was analyzed for volatile organic compounds. Concentrations of dissolved solids and sulfate in the study area were consistently above the U.S. Environmental Protection Agency's secondary drinking-water regulations. The areal distribution of sulfate differed from that of the volatile organic compounds. Concentrations of trace elements were not elevated downgradient from the source. The estimated average velocity of contaminant movement is 0.1 to 1.1 feet per day. The major organic contaminants identified in the study area are trichloroethylene, tetrachloroethylene, and 1,1,1-trichloroethane. Trichloroethylene was detected in wells upgradient from the wastewater- treatment site. Tetrachloroethylene and 1,1,1-trichloroethane might originate at tanks in the basement of building 95 rather than at the adjacent wastewater-treatment system. The pre- dominant gas-phase contaminant, 1,1,1- trichloroethane, was detected at a maximum con- centration of 15.7 micrograms per liter. Both trichoroethylene and tetrachloroethylene were detected in concentrations greater than 0.10 micrograms per liter in five of the eight soil- gas samples, indicating that volatilization and diffusion through the unsaturated zone could be a significant mechanism of contaminant loss from the aquifer.

Localizing the lipid products of PI3Kγ in neutrophils.

PubMed

Norton, Laura; Lindsay, Yvonne; Deladeriere, Arnaud; Chessa, Tamara; Guillou, Hervé; Suire, Sabine; Lucocq, John; Walker, Simon; Andrews, Simon; Segonds-Pichon, Anne; Rausch, Oliver; Finan, Peter; Sasaki, Takehiko; Du, Cheng-Jin; Bretschneider, Till; Ferguson, G John; Hawkins, Phillip T; Stephens, Len

2016-01-01

Class I phosphoinositide 3-kinases (PI3Ks) are important regulators of neutrophil migration in response to a range of chemoattractants. Their primary lipid products PtdIns(3,4,5)P3 and PtdIns(3,4)P2 preferentially accumulate near to the leading edge of migrating cells and are thought to act as an important cue organizing molecular and morphological polarization. We have investigated the distribution and accumulation of these lipids independently in mouse neutrophils using eGFP-PH reportersand electron microscopy (EM). We found that authentic mouse neutrophils rapidly polarized their Class I PI3K signalling, as read-out by eGFP-PH reporters, both at the up-gradient leading edge in response to local stimulation with fMLP as well as spontaneously and randomly in response to uniform stimulation. EM studies revealed these events occurred at the plasma membrane, were dominated by accumulation of PtdIns(3,4,5)P3, but not PtdIns(3,4)P2, and were dependent on PI3Kγ and its upstream activation by both Ras and Gβγs. Copyright © 2015 The Authors. Published by Elsevier Ltd.. All rights reserved.

Regional-scale advective, diffusive, and eruptive dynamics of CO2 and brine leakage through faults and wellbores

NASA Astrophysics Data System (ADS)

Jung, Na-Hyun; Han, Weon Shik; Han, Kyungdoe; Park, Eungyu

2015-05-01

Regional-scale advective, diffusive, and eruptive transport dynamics of CO2 and brine within a natural analogue in the northern Paradox Basin, Utah, were explored by integrating numerical simulations with soil CO2 flux measurements. Deeply sourced CO2 migrates through steeply dipping fault zones to the shallow aquifers predominantly as an aqueous phase. Dense CO2-rich brine mixes with regional groundwater, enhancing CO2 dissolution. Linear stability analysis reveals that CO2 could be dissolved completely within only 500 years. Assigning lower permeability to the fault zones induces fault-parallel movement, feeds up-gradient aquifers with more CO2, and impedes down-gradient fluid flow, developing anticlinal CO2 traps at shallow depths (<300 m). The regional fault permeability that best reproduces field spatial CO2 flux variation is estimated 1 × 10-17 ≤ kh < 1 × 10-16 m2 and 5 × 10-16 ≤ kv < 1 × 10-15 m2. The anticlinal trap serves as an essential fluid source for eruption at Crystal Geyser. Geyser-like discharge sensitively responds to varying well permeability, radius, and CO2 recharge rate. The cyclic behavior of wellbore CO2 leakage decreases with time.

Radioanalytical Chemistry for Automated Nuclear Waste Process Monitoring

DOE Office of Scientific and Technical Information (OSTI.GOV)

Devol, Timothy A.

2005-06-01

Comparison of different pulse shape discrimination methods was performed under two different experimental conditions and the best method was identified. Beta/gamma discrimination of 90Sr/90Y and 137Cs was performed using a phoswich detector made of BC400 (2.5 cm OD x 1.2 cm) and BGO (2.5 cm O.D. x 2.5 cm ) scintillators. Alpha/gamma discrimination of 210Po and 137Cs was performed using a CsI:Tl (2.8 x 1.4 x 1.4 cm3) scintillation crystal. The pulse waveforms were digitized with a DGF-4c (X-Ray Instrumentation Associates) and analyzed offline with IGOR Pro software (Wavemetrics, Inc.). The four pulse shape discrimination methods that were compared include:more » rise time discrimination, digital constant fraction discrimination, charge ratio, and constant time discrimination (CTD) methods. The CTD method is the ratio of the pulse height at a particular time after the beginning of the pulse to the time at the maximum pulse height. The charge comparison method resulted in a Figure of Merit (FoM) of 3.3 (9.9 % spillover) and 3.7 (0.033 % spillover) for the phoswich and the CsI:Tl scintillator setups, respectively. The CTD method resulted in a FoM of 3.9 (9.2 % spillover) and 3.2 (0.25 % spillover), respectively. Inverting the pulse shape data typically resulted in a significantly higher FoM than conventional methods, but there was no reduction in % spillover values. This outcome illustrates that the FoM may not be a good scheme for the quantification of a system to perform pulse shape discrimination. Comparison of several pulse shape discrimination (PSD) methods was performed as a means to compare traditional analog and digital PSD methods on the same scintillation pulses. The X-ray Instrumentation Associates DGF-4C (40 Msps, 14-bit) was used to digitize waveforms from a CsI:Tl crystal and BC400/BGO phoswich detector.« less

Time-resolved imaging of prompt-gamma rays for proton range verification using a knife-edge slit camera based on digital photon counters

NASA Astrophysics Data System (ADS)

Cambraia Lopes, Patricia; Clementel, Enrico; Crespo, Paulo; Henrotin, Sebastien; Huizenga, Jan; Janssens, Guillaume; Parodi, Katia; Prieels, Damien; Roellinghoff, Frauke; Smeets, Julien; Stichelbaut, Frederic; Schaart, Dennis R.

2015-08-01

Proton range monitoring may facilitate online adaptive proton therapy and improve treatment outcomes. Imaging of proton-induced prompt gamma (PG) rays using a knife-edge slit collimator is currently under investigation as a potential tool for real-time proton range monitoring. A major challenge in collimated PG imaging is the suppression of neutron-induced background counts. In this work, we present an initial performance test of two knife-edge slit camera prototypes based on arrays of digital photon counters (DPCs). PG profiles emitted from a PMMA target upon irradiation with a 160 MeV proton pencil beams (about 6.5   ×   109 protons delivered in total) were measured using detector modules equipped with four DPC arrays coupled to BGO or LYSO : Ce crystal matrices. The knife-edge slit collimator and detector module were placed at 15 cm and 30 cm from the beam axis, respectively, in all cases. The use of LYSO : Ce enabled time-of-flight (TOF) rejection of background events, by synchronizing the DPC readout electronics with the 106 MHz radiofrequency signal of the cyclotron. The signal-to-background (S/B) ratio of 1.6 obtained with a 1.5 ns TOF window and a 3 MeV-7 MeV energy window was about 3 times higher than that obtained with the same detector module without TOF discrimination and 2 times higher than the S/B ratio obtained with the BGO module. Even 1 mm shifts of the Bragg peak position translated into clear and consistent shifts of the PG profile if TOF discrimination was applied, for a total number of protons as low as about 6.5   ×   108 and a detector surface of 6.6 cm  ×  6.6 cm.

Investigation of Ground-Water Contamination at Solid Waste Management Unit 12, Naval Weapons Station Charleston, North Charleston, South Carolina

USGS Publications Warehouse

Vroblesky, Don A.; Casey, Clifton C.; Petkewich, Matthew D.; Lowery, Mark A.; Conlon, Kevin J.; Harrelson, Larry G.

2007-01-01

The U.S. Geological Survey and the Naval Facilities Engineering Command Southeast investigated natural and engineered remediation of chlorinated volatile organic compound ground-water contamination at Solid Waste Management Unit 12 at the Naval Weapons Station Charleston, North Charleston, South Carolina. The primary contaminants of interest are tetrachloroethene, 1,1,1-trichloroethane, trichloroethene, cis-1,2-dichloroethene, vinyl chloride, 1,1-dichloroethane, and 1,1-dichloroethene. In general, the hydrogeology of Solid Waste Management Unit 12 consists of a surficial aquifer, composed of sand to clayey sand, overlain by dense clay that extends from about land surface to a depth of about 8 to 10 feet and substantially limits local recharge. During some months in the summer, evapotranspiration and limited local recharge result in ground-water level depressions in the forested area near wells 12MW-12S and 12MW-17S, seasonally reflecting the effects of evapotranspiration. Changes in surface-water levels following Hurricane Gaston in 2004 resulted in a substantial change in the ground-water levels at the site that, in turn, may have caused lateral shifting of the contaminant plume. Hydraulic conductivity, determined by slug tests, is higher along the axis of the plume in the downgradient part of the forests than adjacent to the plume, implying that there is some degree of lithologic control on the plume location. Hydraulic conductivity, hydraulic gradient, sulfur-hexafluoride measurements, and historical data indicate that ground-water flow rates are substantially slower in the forested area relative to upgradient areas. The ground-water contamination, consisting of chlorinated volatile organic compounds, extends eastward in the surficial aquifer from the probable source area near a former underground storage tank. Engineered remediation approaches include a permeable reactive barrier and phytoremediation. The central part of the permeable reactive barrier along the main axis of the contaminant plume appears to be actively removing contamination; however, ground-water contamination is moving around the southern end of the permeable reactive barrier. Changes in the contaminant concentrations along the path of ground-water transport reflect a complex variety of influences. Potential influences include dechlorination, sorption and desorption, transpirative removal by trees, lateral shifting of the plume, and the presence of zones of differing concentrations possibly reflecting one or more pulse releases of contamination from the source area. Near the source area at well 12MW-10S, volatile organic compound concentrations of cis-1,2-dichlorothene, vinyl chloride, 1,1-dichloroethane, and 1,1,1-trichloroethane continued an irregular decline, while tetrachloroethene and 1,1-dichloroethene showed marked fluctuations in concentration during 2005 and 2006. Volatile organic compound concentrations at well 12MW-03S continued to show decreasing concentrations with the June 2006 concentrations being the lowest yet recorded at that well for several volatile organic compounds. Concentration and delta carbon 13 data indicate that in the upgradient part of the plume, tetrachloroethene is being degraded to trichloroethene, which is being degraded to cis-1,2-dichloroethene, and cis-1,2-dichloroethene is accumulating faster than it is being depleted. Ground-water volatile organic compound concentrations also changed in some wells in the forested area in the midpart of the plume. Increasing tetrachloroethene and decreasing trichloroethene and 1,1-dichloroethene concentrations were observed at wells 12MW-05S and 12MW-29S, possibly reflecting a lateral shift in the axis of the contamination plume or an advancing contamination pulse. Substantial decreases in contamination occur in the forested area downgradient from well 12MW-05S. Probable major loss mechanisms in this area include evapotranspiration and sorption.

Application of blind source separation to gamma ray spectra acquired by GRaND around Vesta

NASA Astrophysics Data System (ADS)

Mizzon, H.; Toplis, M. J.; Forni, O.; Prettyman, T. H.; Raymond, C. A.; Russell, C. T.

2012-12-01

The bismuth germinate (BGO) scintillator is one of the sensors of the gamma ray and neutron detector (GRaND)1 on board the Dawn spacecraft, that has spent just over one year in orbit around the asteroid 4-Vesta. The BGO detector is excited by energetic gamma-rays produced by galactic cosmic rays (GCR) or energetic solar particles interacting either with Vesta and/or the Dawn spacecraft. In detail, during periods of quiet solar activity, gamma ray spectra produced by the scintillator can be considered as consisting of three signals: i) a contribution of gamma-rays from Vesta produced by GCR interactions at the asteroid's surface, ii) a contribution from the spacecraft excited by neutrons coming from Vesta, and iii) a contribution of the spacecraft excited by local interaction with galactic cosmic rays. While the first two contributions should be positive functions of the solid angle of Vesta in the field of view during acquisition, the last one should have a negative dependence because Vesta partly shields the spacecraft from GCR. This theoretical mix can be written formally as: S=aΩSV+bΩSSCNV+c(4π-Ω)SSCGCR (1) where S is the series of recorded spectra, Ω is the solid angle, SV is the contribution of gamma rays coming from Vesta, SSCNV is the contribution of gamma rays coming from the spacecraft excited by the neutron coming from Vesta and SSCGCR is the contribution of gamma rays coming from the spacecraft excited by GCR. A blind source separation method called independent component analysis enables separating additive subcomponents supposing the mutual statistical independence of the non-Gaussian source signals2. Applying this method to BGO spectra acquired during the first three months of the low-altitude measurement orbit (LAMO) reveals two main independent components. The first one is dominated by the positron electron annihilation peak and is positively correlated to the solid angle. The second is negatively correlated to the solid angle and displays peaks of elements present in the spacecraft, of energy in the range 1 to 3.5 MeV. At energy >3.5 MeV, the dominant independent component highlighted by this method has no significant peaks, suggesting that it is not influenced by Vesta itself which is known to have a strong signal associated with iron at 7.6 MeV. Our method therefore represents a first step in retrieving the contribution of the spacecraft that could be used in conjunction with the mixing equation (1) to determine the contribution from the planet itself. 1 : Prettyman, T. H., Mcsween, Jr., H. Y., Feldman, W. C., JUN 2010. Dawn's GRaND to map the chemical composition of asteroids Vesta and Ceres. Geochimica and Cosmochimica Acta 74 (12, 1), A832, Con- ference on Goldschmidt 2010 - Earth, Energy, and the Environment, Knoxville, TN, JUN 13-18, 2010. 2 : Hyvarinen, A., Oja, E., May-Jun 2000. Independent component analysis: algorithms and applications. Neural Networks 13 (4-5), 411-430.

Stormwater Management Plan for the Arden Hills Army Training Site, Arden Hills, Minnesota

DOE Office of Scientific and Technical Information (OSTI.GOV)

Carr, Adrianne E.; Wuthrich, Kelsey K.; Ziech, Angela M.

2013-03-01

This stormwater management plan focuses on the cantonment and training areas of the Arden Hills Army Training Site (AHATS). The plan relates the site stormwater to the regulatory framework, and it summarizes best management practices to aide site managers in promoting clean site runoff. It includes documentation for a newly developed, detailed model of stormwater flow retention for the entire AHATS property and adjacent upgradient areas. The model relies on established modeling codes integrated in a U.S. Department of Defense-sponsored software tool, the Watershed Modeling System (WMS), and it can be updated with data on changes in land use ormore » with monitoring data.« less

Recharge sources and residence times of groundwater as determined by geochemical tracers in the Mayfield Area, southwestern Idaho, 2011–12

USGS Publications Warehouse

Hopkins, Candice B.

2013-01-01

Parties proposing residential development in the area of Mayfield, Idaho are seeking a sustainable groundwater supply. During 2011–12, the U.S. Geological Survey, in cooperation with the Idaho Department of Water Resources, used geochemical tracers in the Mayfield area to evaluate sources of aquifer recharge and differences in groundwater residence time. Fourteen groundwater wells and one surface-water site were sampled for major ion chemistry, metals, stable isotopes, and age tracers; data collected from this study were used to evaluate the sources of groundwater recharge and groundwater residence times in the area. Major ion chemistry varied along a flow path between deeper wells, suggesting an upgradient source of dilute water, and a downgradient source of more concentrated water with the geochemical signature of the Idaho Batholith. Samples from shallow wells had elevated nutrient concentrations, a more positive oxygen-18 signature, and younger carbon-14 dates than deep wells, suggesting that recharge comes from young precipitation and surface-water infiltration. Samples from deep wells generally had higher concentrations of metals typical of geothermal waters, a more negative oxygen-18 signature, and older carbon-14 values than samples from shallow wells, suggesting that recharge comes from both infiltration of meteoric water and another source. The chemistry of groundwater sampled from deep wells is somewhat similar to the chemistry in geothermal waters, suggesting that geothermal water may be a source of recharge to this aquifer. Results of NETPATH mixing models suggest that geothermal water composes 1–23 percent of water in deep wells. Chlorofluorocarbons were detected in every sample, which indicates that all groundwater samples contain at least a component of young recharge, and that groundwater is derived from multiple recharge sources. Conclusions from this study can be used to further refine conceptual hydrological models of the area.

Correlation of Non-proportionality and Scintillation Properties with Cerium Concentration in YAlO 3:Ce

DOE PAGES

Donnald, Samuel B.; Williams, Richard; Melcher, Charles L.; ...

2018-04-19

Cerium doped YAlO3 (YAP:Ce) is an interesting oxide scintillator in that it exhibits a wider range of light yield non-proportionality on a sample-to-sample basis than most other well-known oxide scintillators. In general, most oxide materials, such as BGO and LSO:Ce, are thought to have an intrinsic proportional response that is nearly constant between samples and independent of growth conditions. Since light yield nonproportionality is responsible for degrading the achievable energy resolution of all known scintillators, it is important to understand what contributes to the behavior. In this study, in an attempt to understand if the phenomenon can be affected bymore » growth parameters or by other means, seven samples of YAP:Ce were collected from various sources, and eight samples were grown inhouse using the Czochralski method. Based on optical and scintillation measurement as well as direct measurement of the cerium concentration, it was determined that the light yield proportionality in YAlO3:Ce is strongly related to the cerium concentration. Samples that were found to have a higher relative cerium concentration displayed a more proportional light yield response. In addition, it was determined that samples with a higher cerium concentration also exhibit a faster decay time and an enhanced energy resolution when compared to samples with less cerium. Finally, it was also determined that growth in a reducing atmosphere can effectively suppress a parasitic optical absorption band.« less

Correlation of Non-proportionality and Scintillation Properties with Cerium Concentration in YAlO 3:Ce

DOE Office of Scientific and Technical Information (OSTI.GOV)

Donnald, Samuel B.; Williams, Richard; Melcher, Charles L.

Cerium doped YAlO3 (YAP:Ce) is an interesting oxide scintillator in that it exhibits a wider range of light yield non-proportionality on a sample-to-sample basis than most other well-known oxide scintillators. In general, most oxide materials, such as BGO and LSO:Ce, are thought to have an intrinsic proportional response that is nearly constant between samples and independent of growth conditions. Since light yield nonproportionality is responsible for degrading the achievable energy resolution of all known scintillators, it is important to understand what contributes to the behavior. In this study, in an attempt to understand if the phenomenon can be affected bymore » growth parameters or by other means, seven samples of YAP:Ce were collected from various sources, and eight samples were grown inhouse using the Czochralski method. Based on optical and scintillation measurement as well as direct measurement of the cerium concentration, it was determined that the light yield proportionality in YAlO3:Ce is strongly related to the cerium concentration. Samples that were found to have a higher relative cerium concentration displayed a more proportional light yield response. In addition, it was determined that samples with a higher cerium concentration also exhibit a faster decay time and an enhanced energy resolution when compared to samples with less cerium. Finally, it was also determined that growth in a reducing atmosphere can effectively suppress a parasitic optical absorption band.« less

Deconvolution of Energy Spectra in the ATIC Experiment

NASA Technical Reports Server (NTRS)

Batkov, K. E.; Panov, A. D.; Adams, J. H.; Ahn, H. S.; Bashindzhagyan, G. L.; Chang, J.; Christl, M.; Fazley, A. R.; Ganel, O.; Gunasigha, R. M.;

All-Particle Spectrum Measured by the ATIC Experiment

NASA Technical Reports Server (NTRS)

Ahn, H. S.; Adams, J. H.; Bashindzhagyan, G.; Batkov, K. E.; Chang, J.; Christl, M.; Fazely, A. R.; Ganel, O.; Gunasingha, R. M.; Guzik, T. G.;

Fermi GBM Observations of Terrestrial Gamma Flashes

NASA Technical Reports Server (NTRS)

Wilson-Hodge, Colleen A.; Briggs, M. S.; Fishman, G. J.; Bhat, P. N.; Paciesas, W. S.; Preece, R.; Kippen, R. M.; von Kienlin, A.; Dwyer, J. R.; Smith, D. M.;

Influence of bias electric field on elastic waves propagation in piezoelectric layered structures.

PubMed

Burkov, S I; Zolotova, O P; Sorokin, B P

2013-08-01

Theoretical and computer investigations of acoustic wave propagation in piezoelectric layered structures, subjected to the dc electric field influence have been fulfilled. Analysis of the dispersive parameters of elastic waves propagation in the BGO/fused silica and fused silica/LiNbO3 piezoelectric layered structures for a number of variants of dc electric field application has been executed. Transformation of bulk acoustic wave into SAW type mode under the dc electric field influence has been found. Possibility to control the permission or prohibition of the wave propagation by the dc electric field application and the appropriate choice of the layer and substrate materials has been discussed. Copyright © 2013 Elsevier B.V. All rights reserved.

The Electron Spectrum above 20 GeV Measured by ATIC-2

NASA Technical Reports Server (NTRS)

Chang, J.; Schmidt, W. K. H.; Adams, James H.; Ahn, H. S.; Bashindzhagyan, G.; Batkov, K. E.; Christl, M.; Fazely, A. R.; Ganel, O.; Gunasigha, R. M.

2005-01-01

The Advanced Thin Ionization Calorimeter (ATIC) Balloon Experiment has been flown from McMurdo, Antarctica in 2000-01 (test flight) and 2002-03 (science flight). ATIC is composed of a segmented BGO calorimeter following a carbon target with scintillator tracking layers and a Silicon matrix detector at the entrance. ATIC measures the composition and energy spectra of the nuclei plus electrons. We present the electron spectrum derived from the ATIC-2 science flight, from 20 GeV to 1.5 TeV, and compare it to existing very high energy measurements from emulsion chambers and to the results of galactic propagation calculations. The good energy resolution and high statistics in the ATIC data allow detailed astrophysical interpretation of the results.

Biodegradation of crude oil into nonvolatile organic acids in a contaminated aquifer near Bemidji, Minnesota

USGS Publications Warehouse

Thorn, K.A.; Aiken, G.R.

1998-01-01

As the result of a pipeline burst, a body of light aliphatic crude oil floats atop the groundwater in a shallow sand and gravel aquifer in a remote area outside Bemidji, Minnesota. Biodegradation has resulted in the formation of a plume of DOC downgradient from the oil body. Groundwater has also been contaminated in an area known as the spray zone, from vertical infiltration of DOC resulting from biodegradation of crude oil in the overlying unsaturated zone. The majority of DOC in the contaminated groundwater is in the form of nonvolatile organic acids (NVOA's) which represent the partial oxidation products of the crude oil constituents. The NVOA's have been classified into three fractions according to their isolation on XAD resins: hydrophobic neutrals (HPO-N), hydrophobic acids (HPO-A) and hydrophilic acids (HPI-A). These fractions of NVOA's were isolated from a well downgradient from the oil body (well 530; DOC=21 mg C/l), from a well in the spray zone (well 603; DOC=15 mg C/l) and from an uncontaminated well upgradient of the oil body where the naturally occurring DOC is 2.9 mg C/l (well 310). The three sets of NVOA's were characterized by elemental analyses, molecular weight determinations, 14C ages and liquid phase 1H and 13C NMR. The crude oil and the saturate, aromatic, resin and asphaltene fractions of the crude oil were similarly analyzed by elemental analysis and NMR. The NVOA's from the contaminated wells were clearly distinguishable from the naturally occurring groundwater DOC. Based upon molecular weights, sulfur contents, aromaticities and the presence of methyl groups bonded to aromatic rings, the characterization data suggests that the NVOA's originate from the C18 or greater alkylaromatic, naphthenoaromatic and sulfur-containing constituents of the crude oil, including possibly the resins and asphaltenes.

Determination of trigger levels for groundwater quality in landfills located in historically human-impacted areas.

PubMed

Stefania, Gennaro A; Zanotti, Chiara; Bonomi, Tullia; Fumagalli, Letizia; Rotiroti, Marco

2018-05-01

Landfills are one of the most recurrent sources of groundwater contamination worldwide. In order to limit their impacts on groundwater resources, current environmental regulations impose the adoption of proper measures for the protection of groundwater quality. For instance, in the EU member countries, the calculation of trigger levels for identifying significant adverse environmental effects on groundwater generated by landfills is required by the Landfill Directive 99/31/EC. Although the derivation of trigger levels could be relatively easy when groundwater quality data prior to the construction of a landfill are available, it becomes challenging when these data are missing and landfills are located in areas that are already impacted by historical contamination. This work presents a methodology for calculating trigger levels for groundwater quality in landfills located in areas where historical contaminations have deteriorated groundwater quality prior to their construction. This method is based on multivariate statistical analysis and involves 4 steps: (a) implementation of the conceptual model, (b) landfill monitoring data collection, (c) hydrochemical data clustering and (d) calculation of the trigger levels. The proposed methodology was applied on a case study in northern Italy, where a currently used lined landfill is located downstream of an old unlined landfill and others old unmapped waste deposits. The developed conceptual model stated that groundwater quality deterioration observed downstream of the lined landfill is due to a degrading leachate plume fed by the upgradient unlined landfill. The methodology led to the determination of two trigger levels for COD and NH 4 -N, the former for a zone representing the background hydrochemistry (28 and 9 mg/L for COD and NH 4 -N, respectively), the latter for the zone impacted by the degrading leachate plume from the upgradient unlined landfill (89 and 83 mg/L for COD and NH 4 -N, respectively). Copyright © 2018 Elsevier Ltd. All rights reserved.

Data acquisition system and ground calibration of polarized gamma-ray observer (PoGOLite)

NASA Astrophysics Data System (ADS)

Takahashi, Hiromitsu; Chauvin, Maxime; Fukazawa, Yasushi; Jackson, Miranda; Kamae, Tuneyoshi; Kawano, Takafumi; Kiss, Mozsi; Kole, Merlin; Mikhalev, Victor; Mizuno, Tsunefumi; Moretti, Elena; Pearce, Mark; Rydström, Stefan

2014-07-01

The Polarized Gamma-ray Observer, PoGOLite, is a balloon experiment with the capability of detecting 10% polarization from a 200 mCrab celestial object between the energy-range 25-80 keV in one 6 hour flight. Polarization measurements in soft gamma-rays are expected to provide a powerful probe into high-energy emission mechanisms in/around neutron stars, black holes, supernova remnants, active-galactic nuclei etc. The "pathfinder" flight was performed in July 2013 for 14 days from Sweden to Russia. The polarization is measured using Compton scattering and photoelectric absorption in an array of 61 well-type phoswich detector cells (PDCs) for the pathfinder instrument. The PDCs are surrounded by 30 BGO crystals which form a side anti-coincidence shield (SAS) and passive polyethylene neutron shield. There is a neutron detector consisting of LiCaAlF6 (LiCAF) scintillator covered with BGOs to measure the background contribution of atmospheric neutrons. The data acquisition system treats 92 PMT signals from 61 PDCs + 30 SASs + 1 neutron detector, and it is developed based on SpaceWire spacecraft communication network. Most of the signal processing is done by digital circuits in Field Programmable Gate Arrays (FPGAs). This enables the reduction of the mass, the space and the power consumption. The performance was calibrated before the launch.

Detectors for the gamma-ray resonant absorption (GRA) method of explosives detection in cargo: a comparative study

NASA Astrophysics Data System (ADS)

Vartsky, David; Goldberg, Mark B.; Engler, Gideon; Shor, Asher; Goldschmidt, Aharon; Feldman, Gennady; Bar, Doron; Orion, Itzhak; Wielopolski, Lucian

2004-01-01

Gamma-Ray Resonant Absorption (GRA) is an automatic-decision radiographic screening technique that combines high radiation penetration with very good sensitivity and specificity to nitrogenous explosives. The method is particularly well-suited to inspection of large, massive objects (since the resonant γ-ray probe is at 9.17 MeV) such as aviation and marine containers, heavy vehicles and railroad cars. Two kinds of γ-ray detectors have been employed to date in GRA systems: 1) Resonant-response nitrogen-rich liquid scintillators and 2) BGO detectors. This paper analyses and compares the response of these detector-types to the resonant radiation, in terms of single-pixel figures of merit. The latter are sensitive not only to detector response, but also to accelerator-beam quality, via the properties of the nuclear reaction that produces the resonant-γ-rays. Generally, resonant detectors give rise to much higher nitrogen-contrast sensitivity in the radiographic image than their non-resonant detector counterparts and furthermore, do not require proton beams of high energy-resolution. By comparison, the non-resonant detectors have higher γ-detection efficiency, but their contrast sensitivity is very sensitive to the quality of the accelerator beam. Implications of these detector/accelerator characteristics for eventual GRA field systems are discussed.

In situ bioremediation of uranium with emulsified vegetable oil as the electron donor.

PubMed

Watson, David B; Wu, Wei-Min; Mehlhorn, Tonia; Tang, Guoping; Earles, Jennifer; Lowe, Kenneth; Gihring, Thomas M; Zhang, Gengxin; Phillips, Jana; Boyanov, Maxim I; Spalding, Brian P; Schadt, Christopher; Kemner, Kenneth M; Criddle, Craig S; Jardine, Philip M; Brooks, Scott C

2013-06-18

A field test with a one-time emulsified vegetable oil (EVO) injection was conducted to assess the capacity of EVO to sustain uranium bioreduction in a high-permeability gravel layer with groundwater concentrations of (mM) U, 0.0055; Ca, 2.98; NO3(-), 0.11; HCO3(-), 5.07; and SO4(2-), 1.23. Comparison of bromide and EVO migration and distribution indicated that a majority of the injected EVO was retained in the subsurface from the injection wells to 50 m downgradient. Nitrate, uranium, and sulfate were sequentially removed from the groundwater within 1-2 weeks, accompanied by an increase in acetate, Mn, Fe, and methane concentrations. Due to the slow release and degradation of EVO with time, reducing conditions were sustained for approximately one year, and daily U discharge to a creek, located approximately 50 m from the injection wells, decreased by 80% within 100 days. Total U discharge was reduced by 50% over the one-year period. Reduction of U(VI) to U(IV) was confirmed by synchrotron analysis of recovered aquifer solids. Oxidants (e.g., dissolved oxygen, nitrate) flowing in from upgradient appeared to reoxidize and remobilize uranium after the EVO was exhausted as evidenced by a transient increase of U concentration above ambient values. Occasional (e.g., annual) EVO injection into a permeable Ca and bicarbonate-containing aquifer can sustain uranium bioreduction/immobilization and decrease U migration/discharge.

Description and hydrogeologic evaluation of nine hazardous-waste sites in Kansas, 1984-86

USGS Publications Warehouse

Hart, R.J.; Spruill, T.B.

1988-01-01

Wastes generated at nine hazardous-waste sites in Kansas were disposed in open pits, 55-gal drums, or large storage tanks. These disposal methods have the potential to contaminate groundwater beneath the sites, the soil on the sites, and nearby surface water bodies. Various activities on the nine sites included production of diborane, transformer oil waste, production of soda ash, use of solvents for the manufacture of farm implements, reclamation of solvents and paints, oil-refinery wastes, meat packaging, and the manufacture and cleaning of tanker-truck tanks. Monitoring wells were installed upgradient and downgradient from the potential contamination source on each site. Strict decontamination procedures were followed to prevent cross contamination between well installations. Air-quality surveys were made on each site before other investigative procedures started. Hydrogeologic investigative techniques, such as terrain geophysical surveys, gamma-ray logs, and laboratory permeameter tests, were used. Groundwater level measurements provide data to determine the direction of flow. Groundwater contamination detected under the sites posed the greatest threat to the environment because of possible migration of contaminants by groundwater flow. Concentrations of volatile organic compounds, polynuclear aromatic hydrocarbons, and trace metals were detected in the groundwater at several of the sites. Many of the same compounds detected in the groundwater also were detected in soil and bed-material samples collected onsite or adjacent to the sites. Several contaminants were detected in background samples of groundwater and soil. (USGS)

Recommendations for new monitoring wells at Everest, Kansas.

DOE Office of Scientific and Technical Information (OSTI.GOV)

LaFreniere, L. M.

2007-05-03

On February 15, 2007, the Commodity Credit Corporation of the U.S. Department of Agriculture (CCC/USDA) submitted Recommendations for Remedial Action at Everest, Kansas. Those Recommendations were accepted by the Kansas Department of Health and Environment (KDHE) in a letter to the CCC/USDA dated March 5, 2007. The approved Recommendations document outlines a plan for systematic groundwater sampling and monitoring at Everest to provide data necessary for the critical evaluation of remedial options - including a phytoremediation alternative - for restoration of the groundwater and protection of the surface waters of the intermittent creek at this site. Phase I of themore » KDHE-approved monitoring plan includes the following activities: (1) Groundwater sampling at existing monitoring wells, with analyses for volatile organic compounds (VOCs) and selected biodegradation parameters; (2) Sampling of surface waters along the intermittent creek for VOCs analyses; and (3) Periodic manual measurement and automated recording of groundwater and surface water levels in the vicinity of the intermittent creek. The locations selected for groundwater and surface water sampling and analyses under the approved monitoring program were determined in consultation with the KDHE. As a result of subsequent discussions among representatives of the KDHE, the CCC/USDA, and Argonne regarding the technical program at Everest, the CCC/USDA seeks KDHE approval for the installation of up to four new permanent monitoring wells along the upper reach of the intermittent creek west of the Nigh property, as shown in Figure 1. The proposed new well locations lie progressively downgradient in the anticipated direction of future groundwater and contaminant movement; all of the recommended points lie at least 2,000 ft upgradient, however, of the confirmed area of groundwater discharge to the creek identified near Highway 73. The proposed new wells will supplement the existing network of groundwater and surface water monitoring points identified in the KDHE-approved monitoring plan. The new wells will be sampled in accord with the schedules outlined in the approved plan. The new wells are recommended to address specific investigation needs, as follows: (1) The proposed borings will provide data on the lithologic and hydrogeologic characteristics - and the relative continuity - of the Everest aquifer unit along the upgradient reach of the intermittent creek, where possible implementation of a phytoremediation remedy is under consideration. (2) Installation of the borings will permit the collection of sediments from the aquifer unit for possible physical or hydraulic property analyses. The completed monitoring wells will also facilitate possible future in situ estimation of the aquifer unit's hydraulic properties in this area, as part of the remedy evaluation and development process. (3) The completed new wells will be used to determine the depths to groundwater and the pattern(s) of groundwater flow near the intermittent creek, and hence to predict more accurately the locations of possible groundwater (and contaminant) discharge and the extent of the area amenable to possible phytoremediation. (4) The use of automated groundwater level recorders at the new locations will provide data on the potential range and variability of groundwater levels to be expected in the area near the intermittent creek. (5) Periodic sampling of the recommended wells for VOCs analyses will help to constrain (1) the rate(s) and pathway(s) of contaminant approach toward the intermittent creek (and the area amenable to possible phytoremediation) and (2) the areal extent of the plume as it continues to evolve. The resulting 'early warning' data obtained from this sampling will therefore help to ensure that remedial action can be taken, if necessary, in sufficient time to prevent unacceptable levels of carbon tetrachloride contamination from threatening the identified surface waters of the creek. The well locations shown in Figure 1 were chosen to satisfy the technical objectives above, as well as to minimize disruption (to the extent possible) of the normal agricultural activities in the required investigation area. To accommodate these somewhat conflicting goals, the recommended monitoring points include one new well (PZ1) along the existing waterways west of the Nigh property, one new well (PZ3) along the margin of the farm field southwest of existing well SB63 and northeast of well SB64, and two new wells (PZ2, PZ4) in the fields east of the intermittent creek. The CCC/USDA has contacted the potentially affected landowner and is attempting to negotiate access to the desired well locations. If the necessary access cannot be obtained, a modified distribution of three new monitoring wells, to be located entirely along the existing waterways west and southwest of the Nigh property, is proposed as a possible alternate configuration.« less

Factors influencing in situ gamma-ray measurements

NASA Astrophysics Data System (ADS)

Loonstra, E. H.; van Egmond, F. M.

2009-04-01

Introduction In situ passive gamma-ray sensors are very well suitable for mapping physical soil properties. In order to make a qualitative sound soil map, high quality input parameters for calibration are required. This paper will focus on the factors that affect the output of in situ passive gamma-ray sensors, the primary source, soil, not taken into account. Factors The gamma-ray spectrum contains information of naturally occurring nuclides 40K, 238U and 232Th and man-made nuclides like 137Cs, as well as the total count rate. Factors that influence the concentration of these nuclides and the count rate can be classified in 3 categories. These are sensor design, environmental conditions and operational circumstances. Sensor design The main elements of an in situ gamma-ray sensor that influence the outcome and quality of the output are the crystal and the spectrum analysis method. Material and size of the crystal determine the energy resolution. Though widely used, NaI crystals are not the most efficient capturer of gamma radiation. Alternatives are BGO and CsI. BGO has a low peak resolution, which prohibits use in cases where man-made nuclides are subject of interest. The material is expensive and prone to temperature instability. CsI is robust compared to NaI and BGO. The density of CsI is higher than NaI, yielding better efficiency, especially for smaller crystal sizes. More volume results in higher energy efficiency. The reduction of the measured spectral information into concentration of radionuclides is mostly done using the Windows analysis method. In Windows, the activities of the nuclides are found by summing the intensities of the spectrum found in a certain interval surrounding a peak. A major flaw of the Windows method is the limited amount of spectral information that is incorporated into the analysis. Another weakness is the inherent use of ‘stripping factors' to account for contributions of radiation from nuclide A into the peak of nuclide B. This can be overcome using Full Spectrum Analysis (FSA). This method incorporates virtually all data present in the measured gamma spectrum. In FSA, a Chi-squared algorithm is used to fit a set of "Standard Spectra" to the measured spectrum. The uncertainty in the FSA method is at least a factor 2 lower compared to the Windows method. Environmental conditions Environmental conditions can influence the signal output and therefore the quality. In general, the density of the medium through which gamma-radiation travels determines the interaction of the radiation with matter and thus affects the sensor readings. Excluding soil as being the source; water is the most important external factor in this respect. The amount of water in soil will affect the signal. In general, energy loss occurs as water content in soil increases. As a result, the nuclide concentrations will be lower. Monte Carlo simulations show a difference of 16% in nuclide concentration for completely dry and fully saturated sandy soils. Another water related issue is rainfall. With rain radon gas, a product of 238U, will precipitate. This causes spectral noise effects. Snow and fog have the same effect to a minor degree. Another aspect is the openness of soil. From experience we know that the concentration of 40K differs if soil is tilled. Finally, on earth there is always radioactive noise present from the galaxy. The "Standard Spectra" used in the FSA method can take noise and geometric effects into account. Operational circumstances During a survey an operator should be aware of the effects of driving speed and measurement height. In general, a larger crystal has better energy efficiency and is therefore more suitable for high speed. E.g. a 70 x 150 mm CsI crystal provides qualitative satisfactory output for soil mapping up to 10 km/hr. Sample locations, however, are best measured during a longer period (3 to 5 minutes). The measurement height affects the measurement resolution; the lower the sensor, the smaller the measured area. In addition, Monte Carlo simulations show that the mass of the survey vehicle has to be taken into account. A large tractor e.g. can lead to spectral shape disruptions of 5 to 10%. Conclusion Several factors can effect the measured concentrations of radioactive nuclides. Potential users should take mentioned factors into account in respect to their needs when building and applying gamma-ray sensors. For purposes of soil mapping the use of FSA method is preferred, as it incorporates several disturbing factors. This allows the user to create a consistent dataset which will lead to a better understanding of the relation between nuclide concentrations and physical soil properties.

Groundwater quality impacts from the land application of treated municipal wastewater in a large karstic spring basin: Chemical and microbiological indicators

USGS Publications Warehouse

Katz, B.G.; Griffin, Dale W.; Davis, J.H.

2009-01-01

Geochemical and microbiological techniques were used to assess water-quality impacts from the land application of treated municipal wastewater in the karstic Wakulla Springs basin in northern Florida. Nitrate-N concentrations have increased from about 0.2 to as high as 1.1??mg/L (milligrams per liter) during the past 30??years in Wakulla Springs, a regional discharge point for groundwater (mean flow about 11.3??m3/s) from the Upper Floridan aquifer (UFA). A major source of nitrate to the UFA is the approximately 64??million L/d (liters per day) of treated municipal wastewater applied at a 774??ha (hectare) sprayfield farming operation. About 260 chemical and microbiological indicators were analyzed in water samples from the sprayfield effluent reservoir, wells upgradient from the sprayfield, and from 21 downgradient wells and springs to assess the movement of contaminants into the UFA. Concentrations of nitrate-N, boron, chloride, were elevated in water samples from the sprayfield effluent reservoir and in monitoring wells at the sprayfield boundary. Mixing of sprayfield effluent water was indicated by a systematic decrease in concentrations of these constituents with distance downgradient from the sprayfield, with about a 10-fold dilution at Wakulla Springs, about 15??km (kilometers) downgradient from the sprayfield. Groundwater with elevated chloride and boron concentrations in wells downgradient from the sprayfield and in Wakulla Springs had similar nitrate isotopic signatures, whereas the nitrate isotopic composition of water from other sites was consistent with inorganic fertilizers or denitrification. The sprayfield operation was highly effective in removing most studied organic wastewater and pharmaceutical compounds and microbial indicators. Carbamazepine (an anti-convulsant drug) was the only pharmaceutical compound detected in groundwater from two sprayfield monitoring wells (1-2??ppt). One other detection of carbamazepine was found in a distant well water sample where enteroviruses also were detected, indicating a likely influence from a nearby septic tank.

Groundwater quality impacts from the land application of treated municipal wastewater in a large karstic spring basin: chemical and microbiological indicators.

PubMed

Katz, Brian G; Griffin, Dale W; Davis, J Hal

2009-04-01

Geochemical and microbiological techniques were used to assess water-quality impacts from the land application of treated municipal wastewater in the karstic Wakulla Springs basin in northern Florida. Nitrate-N concentrations have increased from about 0.2 to as high as 1.1 mg/L (milligrams per liter) during the past 30 years in Wakulla Springs, a regional discharge point for groundwater (mean flow about 11.3 m(3)/s) from the Upper Floridan aquifer (UFA). A major source of nitrate to the UFA is the approximately 64 million L/d (liters per day) of treated municipal wastewater applied at a 774 ha (hectare) sprayfield farming operation. About 260 chemical and microbiological indicators were analyzed in water samples from the sprayfield effluent reservoir, wells upgradient from the sprayfield, and from 21 downgradient wells and springs to assess the movement of contaminants into the UFA. Concentrations of nitrate-N, boron, chloride, were elevated in water samples from the sprayfield effluent reservoir and in monitoring wells at the sprayfield boundary. Mixing of sprayfield effluent water was indicated by a systematic decrease in concentrations of these constituents with distance downgradient from the sprayfield, with about a 10-fold dilution at Wakulla Springs, about 15 km (kilometers) downgradient from the sprayfield. Groundwater with elevated chloride and boron concentrations in wells downgradient from the sprayfield and in Wakulla Springs had similar nitrate isotopic signatures, whereas the nitrate isotopic composition of water from other sites was consistent with inorganic fertilizers or denitrification. The sprayfield operation was highly effective in removing most studied organic wastewater and pharmaceutical compounds and microbial indicators. Carbamazepine (an anti-convulsant drug) was the only pharmaceutical compound detected in groundwater from two sprayfield monitoring wells (1-2 ppt). One other detection of carbamazepine was found in a distant well water sample where enteroviruses also were detected, indicating a likely influence from a nearby septic tank.

Investigation of vertical distribution and morphology of indigenous organic matter at Sleeping Bear site, Michigan

NASA Astrophysics Data System (ADS)

West, C. C.; Lyon, W. G.; Ross, D. L.; Pennington, L. K.

1994-11-01

This study evaluates the nature and origin of particulate organic carbon and organic coatings on aquifer sands upgradient from a fuel spill site near the Sleeping Bear Dunes National Lakeshore in Michigan. The distribution of carbon was found to be highly complex due to the occurrence of high organic carbon horizons, bounded above and below by high carbonate sediments. The organic coatings on the sands were examined using white light and fluorescence microscopy and by scanning electron microscopy. Core samples were analyzed for organic and inorganic carbon, solution pH, humic/fulvic acid ratios, and insoluble organic matter content (that is, humin) as a function of depth from the ground surface. The organic geochemistry of the soil profile at this site was found to be significantly influenced by the carbonates producing a sharp boundary of precipitated organic matter. This boundary was followed by coatings of predominantly fulvic acid salts on mineral grains deeper in the soil column. The coatings extended into the aquifer. The existence of native organic films on sand grains is well documented in the soils literature. The study reported here was greatly aided by this information and provides the framework for future studies concerning the influence of carbon distribution, chemical identity, and morphology on contaminant fate and transport processes.

Simulation of phosphate transport in sewage-contaminated groundwater, Cape Cod, Massachusetts

USGS Publications Warehouse

Stollenwerk, K.G.

1996-01-01

Sewage-contaminated groundwater currently discharges to Ashumet Pond, located on Cape Cod, Massachusetts Phosphate concentrations as high as 60 ??mol l-1 have been measured in groundwater entering Ashumet Pond, and there is concern that the rate of eutrophication could increase. Phosphate in the sewage plume is sorbed by aquifer sediment; the amount is a function of phosphate concentration and pH. A nonelectrostatic surface-complexation model coupled with a one-dimensional solute-transport code was used to simulate sorption and desorption of phosphate in laboratory column experiments. The model simulated sorption of phosphate reasonably well, although the slow rate of approach to complete breakthrough indicated a nonequilibrium process that was not accounted for in the solute-transport model The rate of phosphate desorption in the column experiments was relatively slow Phosphate could still be measured in effluent after 160 pore volumes of uncontaminated groundwater had been flushed through the columns. Desorption was partly a function of the slowly decreasing pH in the columns and could be modeled quantitatively. Disposal of sewage at this site is scheduled to stop in 1995; however, a large reservoir of sorbed phosphate exists on aquifer sediment upgradient from Ashumet Pond. Computer simulations predict that desorption of phosphate could result in contamination of Ashumet Pond for decades.

All-Sky Earth Occultation Observations with the Fermi Gamma-Ray Burst Monitor

NASA Technical Reports Server (NTRS)

Wilson-Hodge, C. A.; Beklen, E.; Bhat, P. N.; Briggs, M.; Camero-Arranz, A.; Case, G.; Jenke, P.; Chaplin, V.; Cherry, M.; Connaughton, V.;

The Silicon Matrix as a Charge Detector in the ATIC Experiment

NASA Technical Reports Server (NTRS)

Zatsepin, V. I.; Adams, J. H.; Ahn, H. S.; Bashindzhagyan, G. L.; Batkov, K. E.; Chang, J.; Christl, M.; Fazely, A. R.; Ganel, O.; Gunasingha, R. M.

2004-01-01

The Advanced Thin Ionization Calorimeter (ATIC) was built for series of long- duration balloon flights in Antarctica. Its main goal is to measure energy spectra of cosmic ray nuclei from protons up to iron nuclei over a wide energy range from 30 GeV up to 100 TeV. The ATIC balloon experiment had its first, test flight that lasted for 16 days from 28 Dec 2000 to 13 Jan 2OO1 around the continent. The ATIC spectrometer consists of a fully active BGO calorimeter, scintillator hodoscopes and a silicon matrix. The silicon matrix, consisting of 4480 pixels, was used as a charge detector in the experiment. About 25 million cosmic ray events were detected during the flight. In the paper, the charge spectrum obtained with the silicon matrix is analyzed.

Detection of High Energy Cosmic Ray with the Advanced Thin Ionization Calorimeter (ATIC)

NASA Technical Reports Server (NTRS)

Fazely, Ali R.

2003-01-01

ATIC is a balloon-borne investigation of cosmic ray spectra, from below 50 GeV to near 100 TeV total energy, using a fully active Bismuth Gemmate (BGO) calorimeter. It is equipped with the first large area mosaic of small fully depleted silicon detector pixels capable of charge identification in cosmic rays from H to Fe. As a redundancy check for the charge identification and a coarse particle tracking system, three projective layers of x-y scintillator hodoscopes were employed, above, in the center and below a Carbon interaction 'target'. Very high energy gamma-rays and their energy spectrum may provide insight to the flux of extremely high energy neutrinos which will be investigated in detail with several proposed cubic kilometer scale neutrino observatories in the next decade.

Rigidity Spectra of Protons and Helium as Measured in the First Flight of the ATIC Experiment

NASA Technical Reports Server (NTRS)

Zatsepin, V. I.; Adams, J. H.; Ahn, H. S.; Bashindzhagyan, G. L.; Batkov, K. E.; Chang, J.; Christl, M.; Fazely, A. R.; Ganel, O.; Gunasingha, R. M.

2003-01-01

ATIC (Advanced Thin Ionization Calorimeter) is a balloon borne experiment designed to measure cosmic ray composition for elements from hydrogen to iron and their energy spectra from 30 GeV to near 100 TeV. It is comprised of a fully active BGO calorimeter, a carbon interaction target, scintillator hodoscopes, and a silicon matrix that is used as a charge detector in the experiment. ATIC had two successful balloon flights in Antarctica: from 28 Dec 2000 to 13 Jan 2001 (ATIC-1) and from 29 Dec 2002 to 18 Jan 2003 (ATIC-2). Preliminary rigidity spectra of protons and helium nuclei and their ratio are presented for the test flight (ATIC-1). Particular attention is given to problems associated with measuring energy.

Observations of Accreting Pulsars with the FERMI-GBM

NASA Technical Reports Server (NTRS)

Wilson-Hodge, Colleen

2012-01-01

The Gamma-ray Burst Monitor (GBM) on-board Fermi comprises 12 NaI detectors spanning the 8-1000 keV band and 2 BGO detectors spanning the 100 keV to 40 MeV band. These detectors view the entire unocculted sky, providing long (approximately 40 ks/day) observations of accreting pulsars daily, which allow long-term monitoring of spin-frequencies and pulsed uxes via epoch-folded searches plus daily blind searches for new pulsars. Phase averaged uxes can be measured using the Earth occultation technique. In this talk I will present highlights of GBM accretion-powered pulsar monitoring such as the discovery of a torque reversal in 4U1626-67, a high-energy QPO in A0535+26, and evidence for a stable accretion disk in OAO 1657-415.

Ultra-fast scintillation properties of β-Ga2O3 single crystals grown by Floating Zone method

NASA Astrophysics Data System (ADS)

He, Nuotian; Tang, Huili; Liu, Bo; Zhu, Zhichao; Li, Qiu; Guo, Chao; Gu, Mu; Xu, Jun; Liu, Jinliang; Xu, Mengxuan; Chen, Liang; Ouyang, Xiaoping

2018-04-01

In this investigation, β-Ga2O3 single crystals were grown by the Floating Zone method. At room temperature, the X-ray excited emission spectrum includes ultraviolet and blue emission bands. The scintillation light output is comparable to the commercial BGO scintillator. The scintillation decay times are composed of the dominant ultra-fast component of 0.368 ns and a small amount of slightly slow components of 8.2 and 182 ns. Such fast component is superior to most commercial inorganic scintillators. In contrast to most semiconductor crystals prepared by solution method such as ZnO, β-Ga2O3 single crystals can be grown by traditional melt-growth method. Thus we can easily obtain large bulk crystals and mass production.

First results from gamma ray diagnostics in EAST Tokamak

DOE Office of Scientific and Technical Information (OSTI.GOV)

Zhou, R. J.; Hu, L. Q.; Zhong, G. Q., E-mail: gqzhong@ipp.ac.cn

2016-11-15

Gamma ray diagnostics has been developed in the EAST tokamak recently. Six BGO scintillator detectors are arranged on the down-half cross-section and pointed at the up-half cross-section of plasma, with space resolution about 15 cm and energy range from 0.3 MeV to 6 MeV. Three main gamma ray peaks in the energy spectra have been observed and are identified as the results of nuclear reactions {sup 207}Pb(n, n′){sup 207m}Pb, H(n, γ) D, and D(p, γ){sup 3}He, respectively. Upgrading of the system is in progress by using LaBr3(Ce) scintillator, fast photo-multiplier tubes, and a fully digital data acquisition system based onmore » high sample frequency digitizers with digital pulse processing algorithms.« less

Hydrogeology, Ground-Water-Age Dating, Water Quality, and Vulnerability of Ground Water to Contamination in a Part of the Whitewater Valley Aquifer System near Richmond, Indiana, 2002-2003

USGS Publications Warehouse

Buszka, Paul M.; Watson, Lee R.; Greeman, Theodore K.

2007-01-01

Results of detailed water-quality analyses, ground-waterage dating, and dissolved-gas analyses indicated the vulnerability of ground water to specific types of contamination, the sequence of contaminant introduction to the aquifer relative to greenfield development, and processes that may mitigate the contamination. Concentrations of chloride and sodium and chloride/bromide weight ratios in sampled water from five wells indicated the vulnerability of the upper aquifer to roaddeicer contamination. Ground-water-age estimates from these wells indicated the onset of upgradient road-deicer use within the previous 25 years. Nitrate in the upper aquifer predates the post-1972 development, based on a ground-water-age date (30 years) and the nitrate concentration (5.12 milligrams per liter as nitrogen) in water from a deep well. Vulnerability of the aquifer to nitrate contamination is limited partially by denitrification. Detection of one to four atrazine transformation products in water samples from the upper aquifer indicated biological and hydrochemical processes that may limit the vulnerability of the ground water to atrazine contamination. Microbial processes also may limit the aquifer vulnerability to small inputs of halogenated aliphatic compounds, as indicated by microbial transformations of trichlorofluoromethane and trichlorotrifluoroethane relative to dichlorodifluoromethane. The vulnerability of ground water to contamination in other parts of the aquifer system also may be mitigated by hydrodynamic dispersion and biologically mediated transformations of nitrate, pesticides, and some organic compounds. Identification of the sequence of contamination and processes affecting the vulnerability of ground water to contamination would have been unlikely with conventional assessment methods.

Changes in organic matter biodegradatility influencing sulfate reduction in an aquifer contaminated by landfill leachate

USGS Publications Warehouse

Harris, Steve H.; Istok, Jonathan D.; Suflita, Joseph M.

2006-01-01

In situ experiments were conducted to measure sulfate reduction rates and identify rate-limiting factors in a shallow, alluvial aquifer contaminated with municipal landfill leachate. Single-well, push–pull tests conducted in a well adjacent to the landfill with >8 mM dissolved organic carbon (DOC) exhibited a sulfate reduction rate of 3.2 μmol SO4−2 (L sediment)−1 day−1, a value in close agreement with laboratory-derived estimates. Identical tests conducted in wells located 90 m downgradient where DOC levels remained high (>3 mM) showed no detectable sulfate consumption, and laboratory assays confirmed this observation. However, the rates of sulfate reduction in sediment samples obtained from this site were three times larger when they were amended with filter-sterilized groundwater from the upgradient location. The effect of various amendments on sulfate reduction rates was further examined in laboratory incubations using sediment collected from the downgradient site amended with 35S sulfate. Unamended sediments showed only weak conversion of the tracer to 35S sulfide (5 to 7 cpm/cm2), whereas the addition of Desulfovibrio cells increased 35S sulfide production to 44 cpm/cm2. However, the application of heat-killed Desulfovibrio had a similar stimulatory effect, as did a lactate amendment. Collectively, these findings indicate that the lack of measurable sulfate reduction at the downgradient site was not due to the absence of the necessary metabolic potential, the presence of lower sulfate concentration, or the quantity of electron donor, but by its biodegradability. The findings also indicate that field bioaugmentation attempts should be interpreted with caution.

Ground-water movement and nitrate in ground water, East Erda area, Tooele County, Utah, 1997-2000

USGS Publications Warehouse

Susong, D.D.

2005-01-01

Nitrate was discovered in ground water in the east Erda area of Tooele County, Utah, in 1994. The U.S. Geological Survey, in cooperation with Tooele County, investigated the ground-water flow system and water quality in the eastern part of Tooele Valley to determine (1) the vertical and horizontal distribution of nitrate, (2) the direction of movement of the nitrate contamination, and (3) the source of the nitrate. The potentiometric surface of the upper part of the basin-fill aquifer indicates that the general direction of ground-water flow is to the northwest, the flow system is complex, and there is a ground-water mound probably associated with springs. The spatial distribution of nitrate reflects the flow system with the nitrate contamination split into a north and south part by the ground-water mound. The distribution of dissolved solids and sulfate in ground water varies spatially. Vertical profiles of nitrate in water from selected wells indicate that nitrate contamination generally is in the upper part of the saturated zone and in some wells has moved downward. Septic systems, mining and smelting, agriculture, and natural sources were considered to be possible sources of nitrate contamination in the east Erda area. Septic systems are not the source of nitrate because water from wells drilled upgradient of all septic systems in the area had elevated nitrate concentrations. Mining and smelting activity are a possible source of nitrate contamination but few data are available to link nitrate contamination with mining sites. Natural and agricultural sources of nitrate are present east of the Erda area but few data are available about these sources. The source(s) of nitrate in the east Erda area could not be clearly delineated in spite of considerable effort and expenditure of resources.

Know Your Enemy - Implementation of Bioremediation within a Suspected DNAPL Source Zone Following High-Resolution Site Characterization at Contractors Road Heavy Equipment Area, Kennedy Space Center, Florida

NASA Technical Reports Server (NTRS)

Chrest, Anne; Daprato, Rebecca; Burcham, Michael; Johnson, Jill

2018-01-01

The National Aeronautics and Space Administration (NASA), Kennedy Space Center (KSC), has adopted high-resolution site characterization (HRSC) sampling techniques during baseline sampling prior to implementation of remedies to confirm and refine the conceptual site model (CSM). HRSC sampling was performed at Contractors Road Heavy Equipment Area (CRHE) prior to bioremediation implementation to verify the extent of the trichloroethene (TCE) dense non-aqueous phase liquid (DNAPL) source area (defined as the area with TCE concentrations above 1% solubility) and its daughter product dissolved plume that had been identified during previous HRSC events. The results of HRSC pre-bioremediation implementation sampling suggested that the TCE source area was larger than originally identified during initial site characterization activities, leading to a design refinement to improve electron donor distribution and increase the likelihood of achieving remedial objectives. Approach/Activities: HRSC was conducted from 2009 through 2014 to delineate the vertical and horizontal extent of chlorinated volatile organic compounds (CVOCs) in the groundwater. Approximately 2,340 samples were collected from 363 locations using direct push technology (DPT) groundwater sampling techniques. Samples were collected from up to 14 depth intervals at each location using a 4-foot sampling screen. This HRSC approach identified a narrow (approx. 5 to 30 feet wide), approximately 3,000 square foot TCE DNAPL source area (maximum detected TCE concentration of 160,000 micrograms per liter [micro-g/L] at DPT sampling location DPT0225). Prior to implementation of a bioremediation interim measure, HRSC baseline sampling was conducted using DPT groundwater sampling techniques. Concentrations of TCE were an order of magnitude lower than previous reported (12,000 micro-g/L maximum at DPT sampling location DPT0225) at locations sampled adjacent to previous sampling locations. To further evaluate the variability in concentrations observed additional sampling was conducted in 2016. The results identified higher concentrations than originally detected within the previously defined source area and the presence of source zone concentrations upgradient of the previously defined source area (maximum concentration observed 570,000 micro-g/L). The HRSC baseline sampling data allowed for a revision of the bioremediation design prior to implementation. Bioremediation was implemented within the eastern portion of the source area in November and December 2016 and quarterly performance monitoring was completed in March and June 2017. Reductions in CVOC concentrations from baseline were observed at all performance monitoring wells in the treatment area, and by June 2017, an approximate 95% CVOC mass reduction was observed based on monitoring well sampling results. Results/Lessons Learned: The results of this project suggest that, due to the complexity of DNAPL source zones, HRSC during pre-implementation baseline sampling in the TCE source zone was an essential strategy for verifying the treatment area and depth prior to remedy implementation. If the upgradient source zone mass was not identified prior to bioremediation implementation, the mass would have served as a long-term source for the dissolved plume.

Description and application of capture zone delineation for a wellfield at Hilton Head Island, South Carolina

USGS Publications Warehouse

Landmeyer, J.E.

1994-01-01

Ground-water capture zone boundaries for individual pumped wells in a confined aquffer were delineated by using groundwater models. Both analytical and numerical (semi-analytical) models that more accurately represent the $round-water-flow system were used. All models delineated 2-dimensional boundaries (capture zones) that represent the areal extent of groundwater contribution to a pumped well. The resultant capture zones were evaluated on the basis of the ability of each model to realistically rapresent the part of the ground-water-flow system that contributed water to the pumped wells. Analytical models used were based on a fixed radius approach, and induded; an arbitrary radius model, a calculated fixed radius model based on the volumetric-flow equation with a time-of-travel criterion, and a calculated fixed radius model derived from modification of the Theis model with a drawdown criterion. Numerical models used induded the 2-dimensional, finite-difference models RESSQC and MWCAP. The arbitrary radius and Theis analytical models delineated capture zone boundaries that compared least favorably with capture zones delineated using the volumetric-flow analytical model and both numerical models. The numerical models produced more hydrologically reasonable capture zones (that were oriented parallel to the regional flow direction) than the volumetric-flow equation. The RESSQC numerical model computed more hydrologically realistic capture zones than the MWCAP numerical model by accounting for changes in the shape of capture zones caused by multiple-well interference. The capture zone boundaries generated by using both analytical and numerical models indicated that the curnmtly used 100-foot radius of protection around a wellhead in South Carolina is an underestimate of the extent of ground-water capture for pumped wetis in this particular wellfield in the Upper Floridan aquifer. The arbitrary fixed radius of 100 feet was shown to underestimate the upgradient contribution of ground-water flow to a pumped well.

Hydrogeology, chemical quality, and availability of ground water in the Upper Floridan aquifer, Albany area, Georgia

USGS Publications Warehouse

Hicks, D.W.; Gill, H.E.; Longsworth, S.A.

1987-01-01

Large withdrawals of groundwater in the 1500 sq mi Albany area of southwestern Georgia have lowered water levels in deep aquifers as much as 140 ft. This study was conducted to evaluate the development potential of the shallow Upper Floridan aquifer as an alternate source of groundwater, especially for public supply. The Upper Floridan stores and transmits large quantities of water, mainly in a zone of high permeability in the lower part of the aquifer. The transmissivity of the aquifer ranges from < 10,000 sq ft/day northwest of Albany, to as much as 150 ,000 sq ft/day south and southeast of Albany. Twenty-eight years of agricultural and industrial pumping has not produced a long-term decline of the water level in the Upper Floridan; the aquifer system remains at equilibrium. The Upper Floridan yields hard, calcium bicarbonate-type water but concentrations do not exceed State drinking water standards. In most of the study area , contaminants applied to or spilled on the land surface eventually can be expected to percolate through the overburden and reach the aquifer. Thus, it is important that wells be sited away from areas that have been used for the storage and disposal of potential contaminants and, probably to a lesser extent, the application of agricultural chemicals. In the area of greatest development potential east of the Flint River, wells may penetrate major groundwater conduits. By limiting drawdown during well development and during production, the likelihood of causing sinkholes to form can be minimized. Closed depressions, or sinks, throughout the Dougherty Plain probably are unsuitable as well sites, because (1) they are subject to flooding, (2) they collect water from upgradient areas and could concentrate potential contaminants, (3) water probably percolates through their bottoms and could transport contaminants into the aquifer, and (4) the depressions may overlie limestone cavities filled with sand or clay that could interfere with well yield, development, and production. (Author 's abstract)

Hydrogeology and numerical simulation of the unconsolidated glacial aquifer in the Pootatuck River Basin, Newtown, Connecticut

USGS Publications Warehouse

Carlson, Carl S.; Mondazzi, Remo A.; Bjerklie, David M.; Brown, Craig J.

2010-01-01

A study of the groundwater and stream-aquifer interaction in the Pootatuck River Basin, Newtown, Connecticut, was conducted to analyze the effect of production wells on the groundwater levels and streamflow in the Pootatuck River as part of a cooperative program between the U.S. Geological Survey and Newtown, Connecticut. This study will help address concerns about the increasing competition for water for human uses and protection of aquatic habitat. The groundwater-flow model developed in the study was designed for use as a tool to assist planners in assessing the effects of potential future development, which will change the amount and distribution of recharge available to the groundwater system. Several different techniques were used to investigate the interconnection between the stream and the aquifer. Temperature, groundwater levels, stream stage, and stable-isotope data collected during aquifer tests at the principal production wells in the Pootatuck River Basin, as well as groundwater-flow simulations of the system, indicate that more than half of the water pumped from the wells comes from the Pootatuck River. This finding potentially has a large effect on approaches for protecting the water quality of the pumped water. Increases in the amount of impervious surface from future development will reduce and redistribute recharge to the groundwater system. The simulation of future development scenarios showed a decrease in the simulated base flow in the main stem of the Pootatuck River and in all of the 26 simulated subbasins, with some of the subbasins showing a decrease of more than 20 percent when new development had 85 percent impervious area. The groundwater-flow model and particle tracking were used to determine areas that contribute recharge to the five production wells available for use in the Pootatuck River Basin. These areas included narrow portions of the aquifer that extended beyond the immediate upgradient areas, probably because of deeper groundwater-flow paths.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Walker, Katherine L.; Judenhofer, Martin S.; Cherry, Simon R.

In preclinical single-photon emission computed tomography (SPECT) system development the primary objective has been to improve spatial resolution by using novel parallel-hole or multi-pinhole collimator geometries. Furthermore, such high-resolution systems have relatively poor sensitivity (typically 0.01% to 0.1%). In contrast, a system that does not use collimators can achieve very high-sensitivity. Here we present a high-sensitivity un-collimated detector single-photon imaging (UCD-SPI) system for the imaging of both small animals and plants. This scanner consists of two thin, closely spaced, pixelated scintillator detectors that use NaI(Tl), CsI(Na), or BGO. The performance of the system has been characterized by measuring sensitivity, spatialmore » resolution, linearity, detection limits, and uniformity. With 99mTc (140 keV) at the center of the field of view (20 mm scintillator separation), the sensitivity was measured to be 31.8% using the NaI(Tl) detectors and 40.2% with CsI(Na). The best spatial resolution (FWHM when the image formed as the geometric mean of the two detector heads, 20 mm scintillator separation) was 19.0 mm for NaI(Tl) and 11.9 mm for CsI(Na) at 140 keV, and 19.5 mm for BGO at 1116 keV, which is somewhat degraded compared to the cm-scale resolution obtained with only one detector head and a close source. The quantitative accuracy of the system’s linearity is better than 2% with detection down to activity levels of 100 nCi. Two in vivo animal studies (a renal scan using 99mTc MAG-3 and a thyroid scan with 123I) and one plant study (a 99mTcO 4- xylem transport study) highlight the unique capabilities of this UCD-SPI system. From the renal scan, we observe approximately a one thousand-fold increase in sensitivity compared to the Siemens Inveon SPECT/CT scanner. In conclusion, UCD-SPI is useful for many imaging tasks that do not require excellent spatial resolution, such as high-throughput screening applications, simple radiotracer uptake studies in tumor xenografts, dynamic studies where very good temporal resolution is critical, or in planta imaging of radioisotopes at low concentrations.« less

A new brain positron emission tomography scanner with semiconductor detectors for target volume delineation and radiotherapy treatment planning in patients with nasopharyngeal carcinoma.

PubMed

Katoh, Norio; Yasuda, Koichi; Shiga, Tohru; Hasegawa, Masakazu; Onimaru, Rikiya; Shimizu, Shinichi; Bengua, Gerard; Ishikawa, Masayori; Tamaki, Nagara; Shirato, Hiroki

2012-03-15

We compared two treatment planning methods for stereotactic boost for treating nasopharyngeal carcinoma (NPC): the use of conventional whole-body bismuth germanate (BGO) scintillator positron emission tomography (PET(CONV)WB) versus the new brain (BR) PET system using semiconductor detectors (PET(NEW)BR). Twelve patients with NPC were enrolled in this study. [(18)F]Fluorodeoxyglucose-PET images were acquired using both the PET(NEW)BR and the PET(CONV)WB system on the same day. Computed tomography (CT) and two PET data sets were transferred to a treatment planning system, and the PET(CONV)WB and PET(NEW)BR images were coregistered with the same set of CT images. Window width and level values for all PET images were fixed at 3000 and 300, respectively. The gross tumor volume (GTV) was visually delineated on PET images by using either PET(CONV)WB (GTV(CONV)) images or PET(NEW)BR (GTV(NEW)) images. Assuming a stereotactic radiotherapy boost of 7 ports, the prescribed dose delivered to 95% of the planning target volume (PTV) was set to 2000 cGy in 4 fractions. The average absolute volume (±standard deviation [SD]) of GTV(NEW) was 15.7 ml (±9.9) ml, and that of GTV(CONV) was 34.0 (±20.5) ml. The average GTV(NEW) was significantly smaller than that of GTV(CONV) (p = 0.0006). There was no statistically significant difference between the maximum dose (p = 0.0585) and the mean dose (p = 0.2748) of PTV. The radiotherapy treatment plan based on the new gross tumor volume (PLAN(NEW)) significantly reduced maximum doses to the cerebrum and cerebellum (p = 0.0418) and to brain stem (p = 0.0041). Results of the present study suggest that the new brain PET system using semiconductor detectors can provide more accurate tumor delineation than the conventional whole-body BGO PET system and may be an important tool for functional and molecular radiotherapy treatment planning. Copyright © 2012 Elsevier Inc. All rights reserved.

Water-quality assessment of part of the Upper Mississippi River basin, Minnesota and Wisconsin - Ground-water quality along a flow system in the Twin Cities metropolitan area, Minnesota, 1997-98

USGS Publications Warehouse

Andrews, William J.; Stark, James R.; Fong, Alison L.; Fallon, James D.

2005-01-01

Although land use had substantial effects on ground-water quality, the distribution of contaminants in the aquifer also is affected by complex combinations of factors and processes that include sources of natural and anthropogenic contaminants, three-dimensional advective flow, physical and hydrologic settings, age and evolution of ground water, and transformation of chemical compounds along the flow system. Compounds such as nitrate and dissolved oxygen were greatest in water samples from the upgradient end of the flow system and near the water table. Specific conductance and dissolved solids increased along the flow system and with depth due to increase in residence time in the flow system and dissolution of aquifer materials.

Land management impacts on dairy-derived dissolved organic carbon in ground water

USGS Publications Warehouse

Chomycia, J.C.; Hernes, P.J.; Harter, T.; Bergamaschi, B.A.

2008-01-01

Dairy operations have the potential to elevate dissolved organic carbon (DOC) levels in ground water, where it may interact with organic and inorganic contaminants, fuel denitrification, and may present problems for drinking water treatment. Total and percent bioavailable DOC and total and carbon-specific trihalomethane (THM) formation potential (TTHMFP and STHMFP, respectively) were determined for shallow ground water samples from beneath a dairy farm in the San Joaquin Valley, California. Sixteen wells influenced by specific land management areas were sampled over 3 yr. Measured DOC concentrations were significantly elevated over the background as measured at an upgradient monitoring well, ranging from 13 to 55 mg L-1 in wells downgradient from wastewater ponds, 8 to 30 mg L-1 in corral wells, 5 to 12 mg L-1 in tile drains, and 4 to 15 mg L-1 in wells associated with manured fields. These DOC concentrations were at the upper range or greatly exceeded concentrations in most surface water bodies used as drinking water sources in California. DOC concentrations in individual wells varied by up to a factor of two over the duration of this study, indicating a dynamic system of sources and degradation. DOC bioavailability over 21 d ranged from 3 to 10%, comparable to surface water systems and demonstrating the potential for dairy-derived DOC to influence dissolved oxygen concentrations (nearly all wells were hypoxic to anoxic) and denitrification. TTHMFP measurements across all management units ranged from 141 to 1731 ??g L-1, well in excess of the maximum contaminant level of 80 ??g L-1 established by the Environmental Protection Agency. STHMFP measurements demonstrated over twofold variation (???4 to ???8 mmol total THM/mol DOC) across the management areas, indicating the dependence of reactivity on DOC composition. The results indicate that land management strongly controls the quantity and quality of DOC to reach shallow ground water and hence should be considered when managing ground water resources and in any efforts to mitigate contamination of ground water with carbon-based contaminants, such as pesticides and pharmaceuticals. Copyright ?? 2008 by the American Society of Agronomy, Crop Science Society of America, and Soil Science Society of America. All rights reserved.

Displacement of soil pore water by trichloroethylene

USGS Publications Warehouse

Wershaw, R. L.; Aiken, G.R.; Imbrigiotta, T.E.; Goldberg, M.C.

1994-01-01

Dense nonaqueous phase liquids (DNAPLS) are important pollutants because of their widespread use as chemical and industrial solvents. An example of the pollution caused by the discharge of DNAPLs is found at the Picatinny Arsenal, New Jersey, where trichloroethylene (TCE) has been discharged directly into the unsaturated zone. This discharge has resulted in the formation of a plume of TCE-contaminated water in the aquifer downgradient of the discharge. A zone of dark-colored groundwater containing a high dissolved organic C content has been found near the point of discharge of the TCE. The colored-water plume extends from the point of discharge at least 30 m (100 feet) downgradient. Fulvic acids isolated from the colored-waters plume, from water from a background well that has not been affected by the discharge of chlorinated solvents, and from soil pore water collected in a lysimeter installed at an uncontaminated site upgradient of the study area have been compared. Nuclear magnetic resonance spectra of the fulvic acids from the colored waters and from the lysimeter are very similar, but are markedly different from the nuclear magnetic resonance spectrum of the fulvic acid from the background well. The three-dimensional fluorescence spectrum and the DOC fractionation profile of the colored groundwater and the soil pore water are very similar to each other, but quite different from those of the background water. It is proposed from these observations that this colored water is soil pore water that has been displaced by a separate DNAPL liquid phase downward to the saturated zone.

Uranium 238U/235U isotope ratios as indicators of reduction: Results from an in situ biostimulation experiment at Rifle, Colorado, USA

DOE Office of Scientific and Technical Information (OSTI.GOV)

Bopp IV, C.J.; Lundstrom, C.C.; Johnson, T.M.

2010-02-01

The attenuation of groundwater contamination via chemical reaction is traditionally evaluated by monitoring contaminant concentration through time. However, this method can be confounded by common transport processes (e.g. dilution, sorption). Isotopic techniques bypass the limits of concentration methods, and so may provide improved accuracy in determining the extent of reaction. We apply measurements of {sup 238}U/{sup 235}U to a U bioremediation field experiment at the Rifle Integrated Field Research Challenge Site in Rifle, Colorado (USA). An array of monitoring and injection wells was installed on a 100 m{sup 2} plot where U(VI) contamination was present in the groundwater. Acetate-amended groundwatermore » was injected along an up-gradient gallery to encourage the growth of dissimilatory metal reducing bacteria (e.g. Geobacter species). During amendment, U concentration dropped by an order of magnitude in the experiment plot. We measured {sup 238}U/{sup 235}U in samples from one monitoring well by MC-ICP-MS using a double isotope tracer method. A significant {approx}1.00{per_thousand} decrease in {sup 238}U/{sup 235}U occurred in the groundwater as U(VI) concentration decreased. The relationship between {sup 238}U/{sup 235}U and concentration corresponds approximately to a Rayleigh distillation curve with an effective fractionation factor ({alpha}) of 1.00046. We attribute the observed U isotope fractionation to a nuclear field shift effect during enzymatic reduction of U(VI){sub (aq)} to U(IV){sub (s)}.« less

Spatial fragment distribution from a therapeutic pencil-like carbon beam in water.

PubMed

Matsufuji, Naruhiro; Komori, Masataka; Sasaki, Hitomi; Akiu, Kengo; Ogawa, Masako; Fukumura, Akifumi; Urakabe, Eriko; Inaniwa, Taku; Nishio, Teiji; Kohno, Toshiyuki; Kanai, Tatsuaki

2005-07-21

The latest heavy ion therapy tends to require information about the spatial distribution of the quality of radiation in a patient's body in order to make the best use of any potential advantage of swift heavy ions for the therapeutic treatment of a tumour. The deflection of incident particles is described well by Molière's multiple-scattering theory of primary particles; however, the deflection of projectile fragments is not yet thoroughly understood. This paper reports on our investigation of the spatial distribution of fragments produced from a therapeutic carbon beam through nuclear reactions in thick water. A DeltaE-E counter telescope system, composed of a plastic scintillator, a gas-flow proportional counter and a BGO scintillator, was rotated around a water target in order to measure the spatial distribution of the radiation quality. The results revealed that the observed deflection of fragment particles exceeded the multiple scattering effect estimated by Molière's theory. However, the difference can be sufficiently accounted for by considering one term involved in the multiple-scattering formula; this term corresponds to a lateral 'kick' at the point of production of the fragment. This kick is successfully explained as a transfer of the intra-nucleus Fermi momentum of a projectile to the fragment; the extent of the kick obeys the expectation derived from the Goldhaber model.

A high-efficiency gas target setup for underground experiments, and redetermination of the branching ratio of the 189.5 keV 22Ne(p,γ)23Na resonance

NASA Astrophysics Data System (ADS)

Ferraro, F.; Takács, M. P.; Piatti, D.; Mossa, V.; Aliotta, M.; Bemmerer, D.; Best, A.; Boeltzig, A.; Broggini, C.; Bruno, C. G.; Caciolli, A.; Cavanna, F.; Chillery, T.; Ciani, G. F.; Corvisiero, P.; Csedreki, L.; Davinson, T.; Depalo, R.; D'Erasmo, G.; Di Leva, A.; Elekes, Z.; Fiore, E. M.; Formicola, A.; Fülöp, Zs.; Gervino, G.; Guglielmetti, A.; Gustavino, C.; Gyürky, Gy.; Imbriani, G.; Junker, M.; Kochanek, I.; Lugaro, M.; Marcucci, L. E.; Marigo, P.; Menegazzo, R.; Pantaleo, F. R.; Paticchio, V.; Perrino, R.; Prati, P.; Schiavulli, L.; Stöckel, K.; Straniero, O.; Szücs, T.; Trezzi, D.; Zavatarelli, S.

2018-03-01

The experimental study of nuclear reactions of astrophysical interest is greatly facilitated by a low-background, high-luminosity setup. The Laboratory for Underground Nuclear Astrophysics (LUNA) 400kV accelerator offers ultra-low cosmic-ray induced background due to its location deep underground in the Gran Sasso National Laboratory (INFN-LNGS), Italy, and high intensity, 250-500μA, proton and α ion beams. In order to fully exploit these features, a high-purity, recirculating gas target system for isotopically enriched gases is coupled to a high-efficiency, six-fold optically segmented bismuth germanate (BGO) γ-ray detector. The beam intensity is measured with a beam calorimeter with constant temperature gradient. Pressure and temperature measurements have been carried out at several positions along the beam path, and the resultant gas density profile has been determined. Calibrated γ-intensity standards and the well-known Ep = 278 keV 14N(p,γ)15O resonance were used to determine the γ-ray detection efficiency and to validate the simulation of the target and detector setup. As an example, the recently measured resonance at Ep = 189.5 keV in the 22Ne(p,γ)23Na reaction has been investigated with high statistics, and the γ-decay branching ratios of the resonance have been determined.

Comparison of SensL and Hamamatsu 4×4 channel SiPM arrays in gamma spectrometry with scintillators

NASA Astrophysics Data System (ADS)

Grodzicka-Kobylka, M.; Szczesniak, T.; Moszyński, M.

2017-06-01

The market of Silicon Photomultipliers (SiPMs) consists of many manufacturers that produce their detectors in different technology. Hamamatsu (Japan) and SensL (Ireland) seems to be the most popular companies that produce large SiPM arrays. The aim of this work is characterization and comparison of 4×4 channel SiPM arrays produced by these two producers. Both of the tested SiPMs are made in through-silicon via (TSV) technology, consist of 16, 3×3 mm avalanche photodiode (APD) cells and have fill factor slightly above 60%. The largest difference is a single APD cell size and hence total number of APD cells (55,424 for Hamamatsu, 76,640 for SensL). In the case of SensL SiPM, its spectral response characteristics is shifted slightly toward shorter wavelengths with maximum at 420 nm (450 nm for Hamamatsu). The presented measurements cover selection of the SiPM optimum operating voltage (in respect to energy resolution), verification of the excess noise factor and check of the linearity characteristics. Moreover, the gamma spectrometry with LSO, BGO and CsI:Tl scintillators together with pulse characteristics for these crystals (rise time and fall time) is reported, as well as temperature dependence. The presented measurements show better performance of the SensL array comparing to the Hamamatsu detector.

Hydrogeologic investigation of the Malvern TCE Superfund Site, Chester County, Pennsylvania

USGS Publications Warehouse

Sloto, Ronald A.

1997-01-01

The Malvern TCE Superfund Site, a former solvent recycling facility that now stores and sells solvents, consists of a plant and disposal area, which are approximately 1,900 ft (feet) apart. The site is underlain by an unconfined carbonate bedrock aquifer in which permeability has been enhanced in places by solution. Water levels respond quickly to precipitation and show a similar seasonal variation, response to precipitation, and range of fluctuation. The altitude of water levels in wells at the disposal area is nearly identical because of the small hydraulic gradient. A comparison of water-table maps for 1983, 1993, and 1994 shows that the general shape of the water table and hydraulic gradients in the area have remained the same through time and for different climatic conditions.The plant area is underlain by dolomite of the Elbrook Formation. The dolomite at the plant area does not yield as much water as the dolomite at the disposal area because it is less fractured, and wells penetrate few water-bearing fractures. Yields of nine wells at the plant area range from 1 to 200 gal/min (gallons per minute); the median yield is 6 gal/min. Specific capacities range from 0.08 to 2 (gal/min)/ft (gallons per minute per foot). Aquifer tests were conducted in two wells; median transmissivities estimated from the aquifer-test data ranged from 528 to 839 feet squared per day. Maximum concentrations of volatile organic compounds (VOC's) in ground water at the plant area in 1996 were 53,900 ug/L (micrograms per liter) for trichloroethylene (TCE), 7,110 ug/L for tetrachloroethylene (PCE), and 17,700 ug/L for 1,1,1-trichloroethane (TCA).A ground-water divide is located between the plant area and the disposal area. Ground-water withdrawal for dewatering the Catanach quarry has caused a cone of depression in the water-table surface that reaches to the plant area. From the plant area, ground water flows 1.2 miles to the northeast and discharges to the Catanach quarry. The regional hydraulic gradient between the plant and the Catanach quarry is 0.019. Concentrations of VOC's in water from wells drilled northeast and donwgradient of the plant property boundary are one to two orders of magnitude less than concentrations in water from wells less than 100 ft away at the plant.A capture-zone analysis was performed for two wells at the plant area. The analysis showed that pumping well CC-19 at 20 gal/min would be sufficient to capture all ground-water flow from the plant area. Although water from other wells at the plant site contains higher concentrations of VOC's than water from well CC-19, pumping well CC-19 would induce the flow of water with higher concentrations of VOC's; however, pumping well CC-19 might causes VOC's to move lower into the aquifer.The disposal area is underlain by the Ledger Dolomite. The dolomite at the disposal area is much more fractured than the dolomite at the plant area. Although many of the fractures are filled or partially filled with clay, the dolomite at the disposal area yields more water than the dolomite at the plant area. Yields of eight wells at the disposal area range from 15 to more than 200 gal/min; the median yield is greater than 100 gal/min. Specific capacities range from 2 to 280 (gal/min)/ft. Aquifer tests were conducted in two wells; estimated transimissivities were 34,900 and 56,300 feet squared per day. Concentrations of VOC's in ground water are lower at the disposal area than at the plant area. Water samples collected from wells at the disposal area in 1996 had maximum concentrations of TCE of 768 ug/L, PCE of 111 ug/L, and TCA of 108 ug/L. These concentrations are lower than concentrations in water samples collected before cleanup of drums in the disposal area was completed in 1984.Ground water from the disposal area flows south-southeast toward Valley Creek. The hydraulic gradient between the disposal area and Valley Creek is 0.001. A well-defined plume of VOC’s in ground water extends downgradient from the disposal area toward Valley Creek. A comparison of data from 1995 to 1996 with data from 1981 to 1984 shows that concentrations of TCE, PCE, and TCA in water from most off-site wells have decreased and that water from fewer wells contains detectable concentrations of those compounds.A capture-zone analysis was performed for three wells at the disposal area. The analysis showed that pumping wells CC-16, CC-17, and CC-18 at a combined rate of 270 gal/min would form a capture zone ranging from approximately 443 to 477 ft wide at a distance 500 ft upgradient from the center of the pumping wells. Pumping wells CC-16 and CC-17 together at a combined rate of 172 gal/min would form a capture zone ranging from approximately 172 to 400 ft wide at a distance 500 ft upgradient from the center of the pumping wells.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Nakahira, S.; Yamaoka, K.; Yoshida, A.

We propose to provide a gamma-ray burst monitor (GBM) for the CALET mission to monitor gamma-ray bursts (GRBs) together with the CALET Imaging Calorimeter detector. The major purpose is to derive a wide-band energy spectrum of GRBs over an unprecedented 9 decades of energy (from a few keV to a few TeV) in combination with the CALET tower detector. Hence it is desirable to have the CALET-GBM covering an energy range from a few keV to about 20 MeV to avoid a gap in the observational energy bands. The design of GBM is underway to fulfill this requirement. The currentmore » detector candidate is BGO, and a LaBr (Ce) scintillator which has a superior energy resolution to that of NaI(Tl). In this paper, design and expected performance of the CALET-GBM is shown.« less

Atic Experiment: Flight Data Processing

NASA Technical Reports Server (NTRS)

Ahn, H. S.; Adams, J. H.; Bashindzhagyan, G.; Batkov, K. E.; Chang, J.; Christl, M.; Fazely, A. R.; Ganel, O.; Gunasingha, R. M.; Guzik, T. G.

2003-01-01

The Advanced Thin Ionization Calorimeter (ATIC) is a balloon borne experiment to measure the composition and energy spectra of Z = 1 to 28 cosmic rays over the energy range approx. 30 GeV - 100 TeV. The instrument consists of a fully active 320-crystal Bismuth Germanate (BGO) calorimeter, 202 scintillator strips in 3 hodoscopes interleaved with a graphite target, and a 4480-pixel silicon matrix charge detector. ATIC has had two successful Long Duration Balloon flights from McMurdo, Antarctica: from 12/28/00 to 01/13/01 and from 12/29/02 to 01/18/03. We have developed the ATIC Data Processing System (ADPs), which is an Object Oriented data processing program based on ROOT. In this paper, we describe the processing scheme used in handling the flight data, especially the calibration method and the event reconstruction algorithm.

Enhanced light extraction of scintillator using large-area photonic crystal structures fabricated by soft-X-ray interference lithography

DOE Office of Scientific and Technical Information (OSTI.GOV)

Zhu, Zhichao; Wu, Shuang; Liu, Bo, E-mail: lbo@tongji.edu.cn

2015-06-15

Soft-X-ray interference lithography is utilized in combination with atomic layer deposition to prepare photonic crystal structures on the surface of Bi{sub 4}Ge{sub 3}O{sub 12} (BGO) scintillator in order to extract the light otherwise trapped in the internal of scintillator due to total internal reflection. An enhancement with wavelength- and emergence angle-integration by 95.1% has been achieved. This method is advantageous to fabricate photonic crystal structures with large-area and high-index-contrast which enable a high-efficient coupling of evanescent field and the photonic crystal structures. Generally, the method demonstrated in this work is also suitable for many other light emitting devices where amore » large-area is required in the practical applications.« less

Experience of Application of Silicon Matrix as a Charge Detector in the ATIC Experiment

NASA Technical Reports Server (NTRS)

Zatsepin, V. I.; Adams, J. H.; Christl, M. J.

2003-01-01

The Advanced Thin Ionization Calorimeter (ATIC) was built for series of long-duration balloon flights in Antarctica. Its main goal is to measure energy spectra of cosmic ray nuclei from protons up to iron nuclei in the wide range of their energy from 30 GeV up to 100 TeV. The ATIC balloon experiment had its first, test flight that lasted for 16 days from 28 Dec 2000 to 13 Jan 2001 around the South Pole. The ATIC spectrometer consists of a fully active BGO calorimeter, scintillator hodoscopes and a silicon matrix. The silicon matrix consisted of 4480 pixels was used as a charge detector in the experiment. About 25 million cosmic ray events were detected during the flight. In the paper, the charge spectrum obtained with the silicon matrix is analyzed.

Luminescence and light yield of (Gd2Y)(Ga3Al2)O12:Pr3+ single crystal scintillators

NASA Astrophysics Data System (ADS)

Lertloypanyachai, Prapon; Pathumrangsan, Nichakorn; Sreebunpeng, Krittiya; Pattanaboonmee, Nakarin; Chewpraditkul, Weerapong; Yoshikawa, Akira; Kamada, Kei; Nikl, Martin

2017-06-01

Praseodymium-doped (Gd2Y)(Ga3Al2)O12 (GYGAG: Pr) single crystals are grown by the micro-pulling down method with different Pr concentrations. The energy transfer process between Pr3+ and Gd3+ is investigated by photoluminescence excitation (PLE) and emission (PL) spectra measurements. Photoelectron yield measurements are carried out using photomultiplier. At 662 keV γ-rays, photoelectron yield of 2520 phe/MeV obtained for the GYGAG: Pr (0.01%) sample is larger than that of 1810 phe/MeV obtained for BGO crystal. Light yield degradation for the GYGAG: Pr scintillators is presumably due to the energy transfer from 5d state of Pr3+ to 4f state of Gd3+ together with the concentration quenching in the Gd3+-sublattice.

Signal pulse emulation for scintillation detectors using Geant4 Monte Carlo with light tracking simulation.

PubMed

Ogawara, R; Ishikawa, M

2016-07-01

The anode pulse of a photomultiplier tube (PMT) coupled with a scintillator is used for pulse shape discrimination (PSD) analysis. We have developed a novel emulation technique for the PMT anode pulse based on optical photon transport and a PMT response function. The photon transport was calculated using Geant4 Monte Carlo code and the response function with a BC408 organic scintillator. The obtained percentage RMS value of the difference between the measured and simulated pulse with suitable scintillation properties using GSO:Ce (0.4, 1.0, 1.5 mol%), LaBr3:Ce and BGO scintillators were 2.41%, 2.58%, 2.16%, 2.01%, and 3.32%, respectively. The proposed technique demonstrates high reproducibility of the measured pulse and can be applied to simulation studies of various radiation measurements.

Assessing the Use of Dry Wells as a Tool for Stormwater Management and Groundwater Recharge in Urban Areas

NASA Astrophysics Data System (ADS)

Edwards, E.; Harter, T.; Fogg, G. E.; Washburn, B.; Bryson, R.; Meirovitz, C.; Fawcett, J.; Kretsinger Grabert, V. J.; Bowles, C.; Carr, M.; Nelson, C.

2014-12-01

Dry wells are gravity-fed, excavated pits with perforated casings used to facilitate stormwater infiltration and groundwater recharge in areas comprised primarily of impermeable surfaces or low permeability soils. Stormwater runoff that would otherwise be routed to streams or drains in urban areas is used as a source of aquifer recharge. However, the potential for groundwater contamination caused by urban runoff bypassing surface soil filtration has prevented more widespread use of dry wells as a recharge mechanism. We present the results of a literature survey to assess the potential of dry wells for safe stormwater recharge. Dry wells have been inculpated in groundwater contamination events, although accusations were typically not backed by scientific data. In 1989 groundwater in Modesto, CA, was contaminated with tetrachloroethylene from a dry cleaning facility. The city had been using dry wells to manage stormwater for more than 50 years without detrimental impacts before the contamination. A USGS monitoring study proved that the contamination was from sewer system leakage, and did not involve the dry wells. Some areas of the country have used dry wells with positive results. The Underground Injection Control system (UICs) study in Portland, OR, has been active for ten years, and currently operates over 9,000 UICs. Initially, a ten foot separation distance was enforced between the seasonal high water table and the bottom perforation of the UIC; however, due to monitoring and modeling results that indicate the protectiveness of groundwater, this distance has been reduced to zero feet. Future work will include a comparative pilot study involving a residential and an industrial site in Elk Grove, CA. The study will use modeling tools to assess the recharge potential and groundwater protectiveness of dry wells. Both sites are outfitted with four monitoring wells each: an upgradient monitoring well, two downgradient monitoring wells, and a vadose zone monitoring well. The results of water quality sampling will determine the contaminants of interest, and a model of the fate and transport of these contaminants in the vadose zone will be coupled with hydraulic models to estimate the response of the hydrogeologic system to dry well recharge, with the goal of creating a tool that can be used to evaluate future dry well locations.

Occurrence and distribution of enteric viruses in shallow ground water and factors affecting well vulnerability to microbiological contamination in Worcester and Wicomico counties, Maryland

USGS Publications Warehouse

Banks, William S.L.; Klohe, Cheryl A.; Battigelli, David A.

2001-01-01

The U.S. Geological Survey, in cooperation with the Maryland Department of the Environment and the Wisconsin State Laboratory of Hygiene, conducted a study to characterize the occurrence and distribution of viral contamination in small (withdrawing less than 10,000 gallons per day) public water-supply wells screened in the water-table aquifer in the Coastal Plain in Worcester and Wicomico Counties, Maryland.Two hundred seventy-eight well sites were evaluated with regard to simulated ground-water flow paths, land use, natural soils groups, and well characteristics, such as well depth and well age. Flow and transport simulations of the water-table aquifer indicated that wells screened less than about 50 feet below land surface (shallow wells) were most vulnerable to surface contamination, which in some cases could originate from as far as 2,000 feet upgradient of the well. Animal-feeding and agricultural-storage operations were considered among the most likely sources for viral contamination; therefore, sites close to these activities were considered most vulnerable. Soil groups were evaluated with regard to depth to water and moisture-holding capacity. Wells with shallow depths to water or in very sandy soils were considered more vulnerable to contamination than deep wells (greater than 50 feet) and those completed in finer-grained soils. Older wells and wells where coliform bacteria had been detected in the past were classified as highly vulnerable. On the basis of this evaluation, 27 sites considered to be susceptible were sampled.Samples were collected by pumping up to 400 gallons of untreated well water through an electropositive filter. Water concentrates were subjected to cell-culture assay for the detection of culturable viruses and reverse-transcription polymerase chain reaction/gene probe assays to detect nonculturable viruses; grab samples were analyzed for somatic and male-specific coliphages, Bacteroides fragilis, Clostridium perfringens, enterococci, Escherichia coli, total coliforms, total oxidized nitrogen, dissolved organic carbon, organic nitrogen, total phosphate, orthophosphate, acid-neutralizing capacity, pH, specific conductance, temperature, and dissolved oxygen.Eleven percent of the samples analyzed (3 of 27) tested positive for either culturable viruses or the presence of viral ribonucleic acid. Approximately 15 percent of the samples (4 of 27) tested positive for one or more bacterial contaminants.

Impacts of road construction and removal on the hydrologic and geochemical function of a fen peatland

NASA Astrophysics Data System (ADS)

Wells, C. M.; Petrone, R. M.; Sutherland, G.; Price, J. S.

2015-12-01

Linear disturbances such as roads cover vast swaths of northeastern Alberta, the majority of which are wetlands with shallow and local hydrologic connections. Thus, the effects of road construction on wetland hydrological pathways can have significant implications on water movement within the region, and by extension the productivity of vegetation communities and carbon sequestration. However, little is known about the effect that roads have on wetland hydrology. In 2013, a gravel road built within a fen peatland was reclaimed to evaluate hydrologic impacts post removal. Prior to removal, ground and surface water flow was obstructed leading to surface ponding, and vegetation mortality was observed on the up-gradient (wet) side of the road. Rebounding of the peat column was observed throughout the fen immediately following road removal in 2013 (maximum of 12 cm, mean of 2 cm), with modest but slightly smaller expansion in 2014. For both years, peat rebound was greatest in areas where the road was removed. Peat physical properties contrasted sharply between the reclaimed road (RR) peat and the adjacent, unimpacted peatland (UP). Surface bulk densities (pb, 0-10 cm) ranged from 0.1-0.25 g cm-3 along the RR compared to 0.02-0.07 g cm-3 for the UP and on average, pb for all depths were lower at the RR compared to the UP. Similar spatial patterns were observed for peat porosity. Correspondingly low horizontal saturated hydraulic conductivities (Kh) were observed along the RR compared to the UP, averaging 5.7x10-4 m s-1 and 1.7x10-3 m s-1, respectively. The local flow system across the RR and thus subsurface flow was impeded by almost half (0.4 m d-1) compared to flow observed within the UP (0.8 m d-1), leading to ponding on the upgradient side. A marked change in hydrophysical properties and ground and surface water flow patterns post road removal has implications for plant reestablishment and restoration and will form the basis of further study.

Theoretical investigation of the design and performance of a dual energy (kV and MV) radiotherapy imager

DOE Office of Scientific and Technical Information (OSTI.GOV)

Liu, Langechuan; Antonuk, Larry E., E-mail: antonuk@umich.edu; El-Mohri, Youcef

Purpose: In modern radiotherapy treatment rooms, megavoltage (MV) portal imaging and kilovoltage (kV) cone-beam CT (CBCT) imaging are performed using various active matrix flat-panel imager (AMFPI) designs. To expand the clinical utility of MV and kV imaging, MV AMFPIs incorporating thick, segmented scintillators and, separately, kV imaging using a beam’s eye view geometry have been investigated by a number of groups. Motivated by these previous studies, it is of interest to explore to what extent it is possible to preserve the benefits of kV and MV imaging using a single AMFPI design, given the considerably different x ray energy spectramore » used for kV and MV imaging. In this paper, considerations for the design of such a dual energy imager are explored through examination of the performance of a variety of hypothetical AMFPIs based on x ray converters employing segmented scintillators. Methods: Contrast, noise, and contrast-to-noise ratio performances were characterized through simulation modeling of CBCT imaging, while modulation transfer function, Swank factor, and signal performance were characterized through simulation modeling of planar imaging. The simulations were based on a previously reported hybrid modeling technique (accounting for both radiation and optical effects), augmented through modeling of electronic additive noise. All designs employed BGO scintillator material with thicknesses ranging from 0.25 to 4 cm and element-to-element pitches ranging from 0.508 to 1.016 mm. A series of studies were performed under both kV and MV imaging conditions to determine the most advantageous imager configuration (involving front or rear x ray illumination and use of a mirror or black reflector), converter design (pitch and thickness), and operating mode (pitch-binning combination). Results: Under the assumptions of the present study, the most advantageous imager design was found to employ rear illumination of the converter in combination with a black reflector, incorporate a BGO converter with a 0.508 mm pitch and a 2 cm thickness, and operate at full resolution for kV imaging and 2 × 2 binning mode for MV imaging. Such a dual energy imager design should provide soft tissue visualization at low, clinically practical doses under MV conditions, while helping to preserve the high spatial resolution and high contrast offered by kV imaging. Conclusions: The authors’ theoretical investigation suggests that a dual energy imager capable of largely preserving the desirable characteristics of both kV and MV imaging is feasible. Such an imager, when coupled to a dual energy radiation source, could facilitate simplification of current treatment room imaging systems (as well as their associated quality assurance), and facilitate more precise integration of kV and MV imaging information by virtue of reduced geometric uncertainties.« less

Comparison of tracer methods to quantify hydrodynamic exchange within the hyporheic zone

NASA Astrophysics Data System (ADS)

Engelhardt, I.; Piepenbrink, M.; Trauth, N.; Stadler, S.; Kludt, C.; Schulz, M.; Schüth, C.; Ternes, T. A.

2011-03-01

SummaryHydrodynamic exchange between surface-water and groundwater was studied at a river located within the Rhine Valley in Germany. Piezometric pressure heads and environmental tracers such as temperature, stable isotopes, chloride, X-ray contrast media, and artificial sweetener were investigated within the hyporheic zone and river water plume. Vertical profiles of environmental tracers were collected using multi-level wells within the neutral up-gradient zone, beneath the river bed, and within the horizontal proximal and distal down-gradient zone. Infiltration velocities were calculated from pressure heads, temperature fluctuations and gradients. The amount of river water within groundwater was estimated from vertical profiles of chloride, stable isotopes, and persistent pharmaceuticals. Profiles of stable isotopes and chloride reveal the existence of down-welling within the shallow hyporheic zone that is generated by river bed irregularities. Due to down-welling an above-average migration of river water into the hyporheic zone establishes even under upward hydraulic pressure gradients. The investigated environmental tracers could not distinctively display short-time-infiltration velocities representative for flood waves, while average infiltration velocities calculated over several months are uniform displayed. Based on vertical temperature profiles the down-gradient migration of the river water plume could be observed even after long periods of effluent conditions and over a distance of 200 m from the river bank. X-ray contrast media and artificial sweeteners were observed in high concentrations within the proximal zone, but were not detected at a distance of 200 m from the river bank. Using temperature as environmental tracer within the hyporheic zone may result in overestimating the migration of pollutants within the river water plume as the process of natural attenuation will be neglected. Furthermore, temperature was not able to display the effect of down-welling. Stable isotopes and chloride were found to be suitable environmental tracers to forecast the release and fate of organic contaminants within the hyporheic zone.

Hydrogeologic Controls on Lake Level at Mountain Lake, Virginia

NASA Astrophysics Data System (ADS)

Roningen, J. M.; Burbey, T. J.

2011-12-01

Mountain Lake in Giles County, Virginia has a documented history of severe natural lake-level changes involving groundwater seepage that extend over the past 4200 years. Featured in the 1986 movie Dirty Dancing, the natural lake dried up completely in September 2008 and levels have not yet recovered. A hydrogeologic investigation was undertaken in an effort to determine the factors influencing lake level changes. A daily water balance, dipole-dipole electrical resistivity surveying, well logging and chemical sampling have shed light on: 1) the influence of a fault not previously discussed in literature regarding the lake, 2) the seasonal response to precipitation of a forested first-order drainage system in fractured rock, and 3) the possibility of flow pathways related to karst features. Geologic controls on lake level were investigated using several techniques. Geophysical surveys using dipole-dipole resistivity located possible subsurface flowpaths both to and from the lake. Well logs, lineament analysis, and joint sampling were used to assess structural controls on lake hydrology. Major ions were sampled at wells, springs, streams, and the lake to evaluate possible mixing of different sources of water in the lake. Groundwater levels were monitored for correlation to lake levels, rainfall events, and possible seismic effects. The hydrology of the lake was quantified with a water balance on a daily time step. Results from the water balance indicate steady net drainage and significant recharge when vegetation is dormant, particularly during rain-on-snow melt events. The resistivity survey reveals discrete areas that represent flow pathways from the lake, as well as flowpaths to springs upgradient of the lake located in the vicinity of the fault. The survey also suggests that some flowpaths may originate outside of the topographic watershed of the lake. Chemical evidence indicates karst may underlie the lakebed. Historical data suggest that artificial intervention to mitigate seepage would be required for lake level recovery in the near future.

Investigation of vertical distribution and morphology of indigenous organic matter Sleeping Bear site, Michigan

DOE Office of Scientific and Technical Information (OSTI.GOV)

West, C.C.; Lyon, W.G.; Ross, D.L.

1994-11-01

This study evaluates the nature and origin of particulate organic carbon and organic coatings on aquifer sands upgradient from a fuel spill site near the Sleeping Bear Dunes National Lakeshore in Michigan. The distribution of carbon was found to be highly complex due to the occurrence of high organic carbon horizons, bounded above and below by high carbonate sediments. The organic coatings on the sands were examined using white light and fluorescence microscopy and by scanning electron microscopy. Core samples were analyzed for organic and inorganic carbon, solution pH, humic/fulvic acid ratios, and insoluable organic matter content (that is, humin)more » as function of depth from the ground surface. The organic geochemistry of the soil profile at this site was found to be significantly influenced by the carbonates producing a sharp boundary of precipitated organic matter. This boundary was followed by coatings of predominantly fulvic acid salts on mineral grains deeper in the soil column. The coatings extended into the aquifer. The existence of native organic films on sand grains is well documented in the soils literature. The study reported here was greatly aided by this information and provides the framework for future studies concerning the influence of carbon distribution, chemical identity, and morphology on contaminant fate and transport processes. 56 refs., 9 figs., 2 tabs.« less

Microbially mediated clinoptilolite regeneration in a multifunctional permeable reactive barrier used to remove ammonium from landfill leachate contamination: laboratory column evaluation.

PubMed

Nooten, Thomas Van; Diels, Ludo; Bastiaens, Leen

2010-05-01

This study focuses on multifunctional permeable reactive barrier (multibarrier) technology, combining microbial degradation and abiotic ion exchange processes for removal of ammonium from landfill leachate contamination. The sequential multibarrier concept relies on the use of a clinoptilolite-filled buffer compartment to ensure a robust ammonium removal in case of temporary insufficient microbial activities. An innovative strategy was developed to allow in situ clinoptilolite regeneration. Laboratory-scale clinoptilolite-filled columns were first saturated with ammonium, using real landfill leachate as well as synthetic leachates as feed media. Other inorganic metal cations, typically present in landfill leachate, had a detrimental influence on the ammonium removal capacity by competing for clinoptilolite exchange sites. On the other hand, the metals had a highly favorable impact on regeneration of the saturated material. Feeding the columns with leachate deprived from ammonium (e.g., by microbial nitrification in an upgradient compartment), resulted in a complete release of the previously sorbed ammonium from the clinoptilolite, due to exchange with metal cations present in the leachate. The released ammonium is then available for microbial consumption in a downgradient compartment. The regeneration process resulted in a slightly increased ammonium exchange capacity afterward. The described strategy throws a new light on sustainable use of sorption materials for in situ groundwater remediation, by avoiding the need for material replacement and the use of external chemical regenerants.

Geology, hydrology, and water quality of the glacial drift aquifer in the vicinity of the Nelson landfill near Yorkville, Illinois

USGS Publications Warehouse

Kay, Robert T.

2006-01-01

The geologic and hydrologic characteristics of the sand-and-gravel deposits that compose the glacial drift aquifer in the vicinity of the Nelson Landfill site in Yor-kville, Illinois indicate that the aquifer could be devel-oped as a source of public water supply. The geology of these deposits within the Newark Bedrock Valley is com-plex, however, and a detailed investigation of their water bearing and transmitting properties will be required to successfully locate high-capacity wells. Volatile organic compounds, pesticides, and cyanide were not detected in ground water during this investiga-tion. Metals and nitrogen compounds were not detected at concentrations above their Maximum Contaminant Level. Iron, manganese, and aluminum were detected at concentrations above their Secondary Maximum Con-taminant Level and various constituents were detected at concentrations above background levels downgradi-ent of the landfill. Nitrate and ammonia, presumably derived from agricultural practices, also were detected in samples from locations hydraulically upgradient of the landfill. Oxidation-reduction conditions in the aquifer become more reducing with depth. This change is reflected by a change in the type of nitrogen compound detected and the concentration of dissolved oxygen and iron in the glacial drift aquifer. Concentrations of some of the major ions and metals may be affected by disso-lution of carbonate minerals in the aquifer and perhaps road salts.

Does Disposing of Construction and Demolition Debris in Unlined Landfills Impact Groundwater Quality? Evidence from 91 Landfill Sites in Florida.

PubMed

Powell, Jon T; Jain, Pradeep; Smith, Justin; Townsend, Timothy G; Tolaymat, Thabet M

2015-08-04

More than 1,500 construction and demolition debris (CDD) landfills operate in the United States (U.S.), and U.S. federal regulations do not require containment features such as low-permeability liners and leachate collection systems for these facilities. Here we evaluate groundwater quality from samples collected in groundwater monitoring networks at 91 unlined, permitted CDD landfills in Florida, U.S. A total of 460,504 groundwater sample results were analyzed, with a median of 10 years of quarterly or semiannual monitoring data per site including more than 400 different chemical constituents. Downgradient concentrations of total dissolved solids, sulfate, chloride, iron, ammonia-nitrogen, and aluminum were greater than upgradient concentrations (p < 0.05). At downgradient wells where sulfate concentrations were greater than 150 mg/L (approximately 10% of the maximum dissolved sulfate concentration in water, which suggests the presence of leachate from the landfill), iron and arsenic were detected in 91% and 43% of samples, with median concentrations of 1,900 μg/L and 11 μg/L, respectively. These results show that although health-based standards can be exceeded at unlined CDD landfills, the magnitude of detected chemical concentrations is generally small and reflective of leached minerals from components (wood, concrete, and gypsum drywall) that comprise the bulk of discarded CDD by mass.

Groundwater flow in the Venice lagoon and remediation of the Porto Marghera industrial area (Italy)

NASA Astrophysics Data System (ADS)

Beretta, Giovanni Pietro; Terrenghi, Jacopo

2017-05-01

This study aims to determine the groundwater flow in a large area of the Venice (northeast Italy) lagoon that is under great anthropogenic pressure, which is influencing the regional flow in the surficial aquifer (about 30 m depth). The area presents several elements that condition the groundwater flow: extraction by means of drainage pumps and wells; tidal fluctuation; impermeable barriers that define part of the coastline, rivers and artificial channels; precipitation; recharge, etc. All the elements were studied separately, and then they were brought together in a numerical groundwater flow model to estimate the impact of each one. Identification of the impact of each element will help to optimise the characteristics of the Porto Marghera remediation systems. Longstanding industrial activity has had a strong impact on the soil and groundwater quality, and expensive and complex emergency remediation measures in problematic locations have been undertaken to ensure the continuity of industrial and maritime activities. The land reclamation and remediation works withdraw 56-74% of the water budget, while recharge from the river accounts for about 21-48% of the input. Only 21-42% of groundwater in the modelled area is derived from natural recharge sources, untouched by human activity. The drop of the piezometric level due to the realization of the upgradient impermeable barrier can be counteracted with the reduction of the pumping rate of the remediation systems.

Processes affecting transport of uranium in a suboxic aquifer

USGS Publications Warehouse

Davis, J.A.; Curtis, G.P.; Wilkins, M.J.; Kohler, M.; Fox, P.; Naftz, D.L.; Lloyd, J.R.

2006-01-01

At the Naturita site in Colorado, USA, groundwaters were sampled and analyzed for chemical composition and by culture and culture-independent microbiological techniques. In addition, sediments were extracted with a dilute sodium carbonate solution to determine quantities of labile uranium within the sediments. Samples from the upgradient portion of the contaminated aquifer, where very little dissolved Fe(II) is found in the groundwater, have uranium content that is controlled by U(VI) adsorption and few metal-reducing bacteria are observed. In the extreme downgradient portion of the aquifer, where dissolved Fe(II) is observed, uranium content of the sediments includes significant quantities of reduced U(IV) and diverse populations of Fe(III)-reducing bacteria were present in the subsurface with the potential of reducing U(VI) to U(IV). ?? 2006 Elsevier Ltd. All rights reserved.

Borehole Data Package for 1998 Wells Installed at Single-Shell Tank Waste Management Area TX-TY

DOE Office of Scientific and Technical Information (OSTI.GOV)

DG Horton; FN Hodges

1999-03-23

Four new Resource Conservation and Recovery Act (RCRA) groundwater monitoring wells were installed at the single-shell tank farm Waste Management Area (WMA) TX-TY during August through November of 1998 in fi,dfillment of Tri-Party Agreement (Eoology 1996) milestone M-24-38. The wells are 299-W1O-26, 299-W14-13, 299-W14-14, and 299-W15-40. Well 299-W1O-26 is located outside the east fence of the TY tank farm and replaces downgradient well299-W1O-18; well 299-W14-13 is located along the east fence near the northeast corner of the TX tank f- and replaces downgradient well 299-W14-12; well 299-W14-14 is located outside the east fence in the south ha.lfof the TX tankmore » fiirm and is anew downgradient well; and well 299-W15-40 is located on the west side of the TX tank farm and is anew upgradient well. The locations of all wells in the monitoring network are shown on Figure 1. The groundwater monitoring plan for WMA TX-TY (Caggiano and Goodwin 1991) describes the hydrogeology of the 200 West Area and WMA TX-TY. An Interim Change Notice to the groundwater monitoring plan provides justification for the new wells. The new wells were constructed to the speciii- cations and requirements described in Washington Administrative Code (WAC) 173-160 and WAC 173-303. This document compiles &fiormation on the drilling and construction, well development pump instal- latio~ groundwater sampling, and sediment testing applicable to wells 299-W1O-26, 299-W14-13, 299-W14-14, and 299-W15-40. Appendix A contains the geologist's log, the Well Construction Sum- mary Repo~ and Well Summary Sheet (as-built diagram); Appendix B contains results of laboratory analyses of particle size distribution, p~ conductivity, calcium carbonate conten~ major cation and anion concentrations from 1:1 water: sediment extracts, and moisture conten~ Appendix C contains geophysical logs; and Appendix D contains the analytical results from groundwater samples obtained during well construction. Aqutier tests (slug tests) were performed on all the new wells after well completions. Results of the aquifer tests will be reported elsewhere. Additiond documentation concerning well construction is on fde with Bechtel Hanfor& Inc., Richland, Washington.« less

Positron emission particle tracking using a modular positron camera

NASA Astrophysics Data System (ADS)

Parker, D. J.; Leadbeater, T. W.; Fan, X.; Hausard, M. N.; Ingram, A.; Yang, Z.

2009-06-01

The technique of positron emission particle tracking (PEPT), developed at Birmingham in the early 1990s, enables a radioactively labelled tracer particle to be accurately tracked as it moves between the detectors of a "positron camera". In 1999 the original Birmingham positron camera, which consisted of a pair of MWPCs, was replaced by a system comprising two NaI(Tl) gamma camera heads operating in coincidence. This system has been successfully used for PEPT studies of a wide range of granular and fluid flow processes. More recently a modular positron camera has been developed using a number of the bismuth germanate (BGO) block detectors from standard PET scanners (CTI ECAT 930 and 950 series). This camera has flexible geometry, is transportable, and is capable of delivering high data rates. This paper presents simple models of its performance, and initial experience of its use in a range of geometries and applications.

Radioluminescence and optical studies of gadolinium calcium phosphate oxyfluoride glasses doped with Sm3+

NASA Astrophysics Data System (ADS)

Meejitpaisan, P.; Insiripong, S.; Kedkaew, C.; Kim, H. J.; Kaewkhao, J.

2017-08-01

Sm3+-doped gadolinium calcium phosphate oxyfluoride glasses have been synthesized and investigated their optical, photo and radioluminescence properties. The glasses were prepared by melt quenching technique at 1400 °C. The characteristic absorption bands of Sm3+ ions originating from the 6H5/2 ground state and occurring absorbed photon in visible light (VIS) and near-infrared (NIR) region with clearly observed from absorption spectra. From the photoluminescence (PL), the glasses showed the emission at 561 (4G5/2→6H5/2), 598 (4G5/2→6H7/2), 644 (4G5/2→6H9/2) and 705 nm (4G5/2→6H11/2). The radioluminescence (RL), emission spectra were corresponding to those from PL measurements. From RL measurement, the integral scintillation efficiency of developed glass was determined at 43% when compared with BGO crystal.

The Energy Spectra of Proton and Helium Measured from the ATIC Experiment

NASA Technical Reports Server (NTRS)

Ahn, H. S.; Seo, E. S.; Adams, J. H.; Bashindzhagyan, G. L.; Batkov, K. E.; Chang, J.; Christl, M.; Fazely, A. R.; Ganel, O.; Gunasingha, R. M.

2004-01-01

The Advanced Thin Ionization Calorimeter (ATIC) balloon experiment is designed to investigate the composition and energy spectra of cosmic rays at the highest energies currently accessible from direct measurements, the region up to 100 TeV. The instrument consists of a silicon matrix for charge measurement, a graphite target (0.75 nuclear interaction length) to induce hadronic fragmentation, 3 scintillator strip hodoscopes for triggering and helping reconstruct trajectory, and a BGO calorimeter (18 radiation lengths) to measure the energy of incident particles. ATIC had two successful Long Duration Balloon (LDB) flights from McMurdo, Antarctica: from 12/28/00 to 01/13/01 and from 12/29/02 to 01/18/03. We present the energy spectra of proton and helium extracted from the ATIC flights, over the energy range from 100 GeV to 100 TeV, and compare them with the results from other experiments at both the lower and higher energy ends.

The First Flight of ATIC : Preliminary Results on CNO Nuclei

NASA Technical Reports Server (NTRS)

Fazely, A.; Gunasingha, R.; Whitaker, Ann F. (Technical Monitor)

2001-01-01

We present preliminary results on the spectra of CNO nuclei in the cosmic radiation as measured in the first flight of the Advanced Thin Ionization Calorimeter Balloon Experiment (ATIC) which lasted for 16 days, starting in December, 2000 with a launch from McMurdo, Antarctica. ATIC is a multiple, long duration balloon flight,investigation for the study of cosmic ray spectra from below 50 GeV to near 100 TeV total energy, using a fully active Bismuth Germanate (BGO) calorimeter. It is equipped with the first large area mosaic of small fully depleted silicon detector pads capable of charge identification in cosmic rays from H to Fe. As a redundancy check for the charge identification and a coarse particle tracking system, three projective layers of x-y scintillator hodoscopes were employed, above, in the center and below a Carbon interaction'target'.

The CNO Concentration in Cosmic Ray Spectrum as Measured From The Advanced Thin Ionization Calorimeter Experiment

NASA Technical Reports Server (NTRS)

Fazely, A. R.; Gunasingha, R. M.; Adams, James H., Jr.; Ahn, H.; Ampe, J.; Bashindzhagyan, G.; Whitaker, Ann F. (Technical Monitor)

2001-01-01

We present preliminary results on the spectra of CNO nuclei in the cosmic radiation as measured in the first flight of the Advanced Thin Ionization Calorimeter Balloon Experiment (ATIC) which lasted for 16 days, starting in December, 2000 with a launch from McMurdo, Antarctica. ATIC is a multiple, long duration balloon flight, investigation for the study of cosmic ray spectra from below 50 GeV to near 100 TeV total energy, using a fully active Bismuth Germanate (BGO) calorimeter. It is equipped with the first large area mosaic of small fully depleted silicon detector pads capable of charge identification in cosmic rays from H to Fe. As a redundancy check for the charge identification and a coarse particle tracking system, three projective layers of x-y scintillator hodoscopes were employed, above, in the center and below a Carbon interaction "target".

Signal pulse emulation for scintillation detectors using Geant4 Monte Carlo with light tracking simulation

DOE Office of Scientific and Technical Information (OSTI.GOV)

Ogawara, R.; Ishikawa, M., E-mail: masayori@med.hokudai.ac.jp

The anode pulse of a photomultiplier tube (PMT) coupled with a scintillator is used for pulse shape discrimination (PSD) analysis. We have developed a novel emulation technique for the PMT anode pulse based on optical photon transport and a PMT response function. The photon transport was calculated using Geant4 Monte Carlo code and the response function with a BC408 organic scintillator. The obtained percentage RMS value of the difference between the measured and simulated pulse with suitable scintillation properties using GSO:Ce (0.4, 1.0, 1.5 mol%), LaBr{sub 3}:Ce and BGO scintillators were 2.41%, 2.58%, 2.16%, 2.01%, and 3.32%, respectively. The proposedmore » technique demonstrates high reproducibility of the measured pulse and can be applied to simulation studies of various radiation measurements.« less

All-Sky Monitoring with the Fermi Gamma Ray Burst Monitor

NASA Technical Reports Server (NTRS)

Wilson-Hodge, Colleen A.

2010-01-01

We are currently monitoring the transient hard X-ray/soft gamma ray sky using the Gamma Ray Burst Monitor (GBM) on-board Fermi. The twelve GBM NaI detectors span 8 keV to 1MeV, while the two GBM BGO detectors span about 150 keV to 40 MeV. With GBM, we detect transient events on multiple timescales. Brief events, such as Gamma Ray Bursts, Solar flares, and magnetar bursts are detected with on-board triggers. On longer timescales, we use the Earth occultation technique to monitor a number of sources, including X-ray binaries, AGN, and solar flaring activity. To date we have detected 7 sources above 100 keV. Transient activity from accretion-powered pulsars is monitored using epoch-folding techniques. With GBM we track the pulsed flux and frequency for a number of pulsars. We will present highlights of GBM observations on various timescales.

The GLAST Burst Monitor

NASA Technical Reports Server (NTRS)

Meegan, Charles A.

2004-01-01

The Gamma Ray Large Area Space Telescope (GLAST) observatory, scheduled for launch in 2007, comprises the Large Area Telescope (LAT) and the GLAST Burst Monitor (GBM). spectral changes that are known to occur within GRBs. between the NASA Marshall Space Flight Center, the University of Alabama in Huntsville, and the Max Planck Institute for Extraterrestrial Physics. It consists of an array of NaI and BGO scintillation detectors operating in the 10 kev to 25 MeV range. The field of view includes the entire unocculted sky when the observatory is pointing close to the zenith. The GBM will enhance LAT observations of GRBs by extending the spectral coverage into the range of current GRB databases, and will provide a trigger for reorienting the spacecraft to observe delayed emission from bursts outside the LAT field of view. GBM is expected to trigger on about 200 bursts per year, and will provide on-board locations of strong bursts accurate to better than 10 degrees.

Advanced Thin Ionization Calorimeter (ATIC) Update

NASA Technical Reports Server (NTRS)

Ahn, H. S.; Ganel, O.; Kim, K. C.; Seo, E. S.; Sina, R.; Wang, J. Z.; Wu, J.; Case, G.; Ellison, S. B.; Gould, R.;

Use of the Zetatron D-T neutron generator for the simultaneous measurement of carbon, oxygen, and hydrogen in vivo in humans

NASA Astrophysics Data System (ADS)

Kehayias, J. J.; Zhuang, H.

1993-06-01

A small sealed D-T neutron generator is used for the pulsed (4-8 kHz) production of fast neutrons. Carbon and oxygen are detected in vivo by counting the 4.44 and 6.13 MeV gamma rays resulting from the inelastic scattering of the fast neutrons. Hydrogen is detected by thermal neutron capture. BGO detectors (127 mm diameter × 76 mm thick) were found more tolerant to neutron exposure and improved the signal to background ratio for the carbon detection by a factor of 6, compared to 152 × 152 mm NaI(Tl). The elemental analysis of the body is used to study the changes of body composition with aging. We investigate the causes of depletion of lean body mass and the development of ways of maintaining functional capacity and quality of life of the elderly.

Hard X-ray and low-energy gamma-ray spectrometers

NASA Technical Reports Server (NTRS)

Gehrels, N.; Crannell, C. J.; Orwig, L. E.; Forrest, D. J.; Lin, R. P.; Starr, R.

1988-01-01

Basic principles of operation and characteristics of scintillation and semi-conductor detectors used for solar hard X-ray and gamma-ray spectrometers are presented. Scintillation materials such as NaI offer high stopping power for incident gamma rays, modest energy resolution, and relatively simple operation. They are, to date, the most often used detector in solar gamma-ray spectroscopy. The scintillator BGO has higher stopping power than NaI, but poorer energy resolution. The primary advantage of semi-conductor materials such as Ge is their high-energy resolution. Monte-Carlo simulations of the response of NaI and Ge detectors to model solar flare inputs show the benefit of high resoluton for studying spectral lines. No semi-conductor material besides Ge is currently available with adequate combined size and purity to make general-use hard X-ray and gamma-ray detectors for solar studies.

Calibration and Readiness of the ISS-RAD Charged Particle Detector

NASA Technical Reports Server (NTRS)

Rios, R.

2015-01-01

The International Space Station (ISS) Radiation Assessment Detector (RAD) is an intravehicular energetic particle detector designed to measure a broad spectrum of charged particle and neutron radiation unique to the ISS radiation environment. In this presentation, a summary of calibration and readiness of the RAD Sensor Head (RSH) - also referred to as the Charged Particle Detector (CPD) - for ISS will be presented. Calibration for the RSH consists of p, He, C, O, Si, and Fe ion data collected at the NASA Space Radiation Laboratory (NSRL) and Indiana University Cyclotron Facility (IUCF). The RSH consists of four detectors used in measuring the spectroscopy of charged particles - A, B, C, and D; high-energy neutral particles and charged particles are measured in E; and the last detector - F - is an anti-coincidence detector. A, B, and C are made from Si; D is made from BGO; E and F are made from EJ260XL plastic scintillator.

The soft gamma-ray detector (SGD) onboard ASTRO-H

NASA Astrophysics Data System (ADS)

Watanabe, Shin; Tajima, Hiroyasu; Fukazawa, Yasushi; Blandford, Roger; Enoto, Teruaki; Goldwurm, Andrea; Hagino, Kouichi; Hayashi, Katsuhiro; Ichinohe, Yuto; Kataoka, Jun; Katsuta, Junichiro; Kitaguchi, Takao; Kokubun, Motohide; Laurent, Philippe; Lebrun, François; Limousin, Olivier; Madejski, Grzegorz M.; Makishima, Kazuo; Mizuno, Tsunefumi; Mori, Kunishiro; Nakamori, Takeshi; Nakano, Toshio; Nakazawa, Kazuhiro; Noda, Hirofumu; Odaka, Hirokazu; Ohno, Masanori; Ohta, Masayuki; Saito, Shinya; Sato, Goro; Sato, Rie; Takeda, Shin'ichiro; Takahashi, Hiromitsu; Takahashi, Tadayuki; Tanaka, Takaaki; Tanaka, Yasuyuki; Terada, Yukikatsu; Uchiyama, Hideki; Uchiyama, Yasunobu; Yamaoka, Kazutaka; Yatsu, Yoichi; Yonetoku, Daisuke; Yuasa, Takayuki

2016-07-01

The Soft Gamma-ray Detector (SGD) is one of science instruments onboard ASTRO-H (Hitomi) and features a wide energy band of 60{600 keV with low backgrounds. SGD is an instrument with a novel concept of "Narrow field-of-view" Compton camera where Compton kinematics is utilized to reject backgrounds which are inconsistent with the field-of-view defined by the active shield. After several years of developments, the flight hardware was fabricated and subjected to subsystem tests and satellite system tests. After a successful ASTRO-H (Hitomi) launch on February 17, 2016 and a critical phase operation of satellite and SGD in-orbit commissioning, the SGD operation was moved to the nominal observation mode on March 24, 2016. The Compton cameras and BGO-APD shields of SGD worked properly as designed. On March 25, 2016, the Crab nebula observation was performed, and, the observation data was successfully obtained.

The Hard X-ray Imager (HXI) for the ASTRO-H Mission

NASA Astrophysics Data System (ADS)

Sato, Goro; Kokubun, Motohide; Nakazawa, Kazuhiro; Enoto, Teruaki; Fukazawa, Yasushi; Harayama, Atsushi; Hayashi, Katsuhiro; Kataoka, Jun; Katsuta, Junichiro; Kawaharada, Madoka; Laurent, Philippe; Lebrun, François; Limousin, Olivier; Makishima, Kazuo; Mizuno, Tsunefumi; Mori, Kunishiro; Nakamori, Takeshi; Noda, Hirofumi; Odaka, Hirokazu; Ohno, Masanori; Ohta, Masayuki; Saito, Shinya; Sato, Rie; Tajima, Hiroyasu; Takahashi, Hiromitsu; Takahashi, Tadayuki; Takeda, Shinichiro; Terada, Yukikatsu; Uchiyama, Hideki; Uchiyama, Yasunobu; Watanabe, Shin; Yamaoka, Kazutaka; Yatsu, Yoichi; Yuasa, Takayuki

2014-07-01

The 6th Japanese X-ray satellite, ASTRO-H, is scheduled for launch in 2015. The hard X-ray focusing imaging system will observe astronomical objects with the sensitivity for detecting point sources with a brightness of 1/100,000 times fainter than the Crab nebula at > 10 keV. The Hard X-ray Imager (HXI) is a focal plane detector 12 m below the hard X-ray telescope (HXT) covering the energy range from 5 to 80 keV. The HXI is composed of a stacked Si/CdTe semiconductor detector module and surrounding BGO scintillators. The latter work as active shields for efficient reduction of background events caused by cosmic-ray particles, cosmic X-ray background, and in-orbit radiation activation. In this paper, we describe the detector system, and present current status of flight model development, and performance of HXI using an engineering model of HXI.

A gamma-gamma coincidence/anticoincidence spectrometer for low-level cosmogenic (22)Na/(7)Be activity ratio measurement.

PubMed

Zhang, Weihua; Ungar, Kurt; Stukel, Matthew; Mekarski, Pawel

2014-04-01

In this study, a digital gamma-gamma coincidence/anticoincidence spectrometer was developed and examined for low-level cosmogenic (22)Na and (7)Be in air-filter sample monitoring. The spectrometer consists of two bismuth germanate scintillators (BGO) and an XIA LLC Digital Gamma Finder (DGF)/Pixie-4 software and card package. The spectrometer design allows a more selective measurement of (22)Na with a significant background reduction by gamma-gamma coincidence events processing. Hence, the system provides a more sensitive way to quantify trace amounts of (22)Na than normal high resolution gamma spectrometry providing a critical limit of 3 mBq within a 20 h count. The use of a list-mode data acquisition technique enabled simultaneous determination of (22)Na and (7)Be activity concentrations using a single measurement by coincidence and anticoincidence mode respectively. Copyright © 2014 Elsevier Ltd. All rights reserved.

Hunting grounds for Jacobi transitions and hyperdeformations

DOE PAGES

Herskind, B.; Benzoni, G.; Wilson, J. N.; ...

2003-04-01

In recent attempts to search for exotic shapes, hyperdeformation (HD), and Jacobi transitions in Hf, Ba, Xe, Sn and Nd nuclei, ridge structures presumably originating from nuclei of very elongated shapes have been observed in 126Ba, with Gammasphere (GS) and in 126Xe, with Euroball-IV (EB-IV). After the promising results from GS, a second experiment in 126Ba followed at EB-IV, taking advantage of the use of the BGO Inner Ball (IB) for selecting the highest spins. The decay of the Giant Dipole Resonances (GDR) is also studied, and the analysis in progress. The Quasi-continuum transitions in the Jacobi region, show amore » significant decrease in energy for both 126Ba and 126Xe, compared to the Thomas-Fermi- and the LSD model predictions. Similar effects were recently found for other nuclei by Ward et al.« less

Characterization of the third-order optical nonlinearity spectrum of barium borate glasses

NASA Astrophysics Data System (ADS)

Santos, S. N. C.; Almeida, J. M. P.; Paula, K. T.; Tomazio, N. B.; Mastelaro, V. R.; Mendonça, C. R.

2017-11-01

Borate glasses have proven to be an important material for applications ranging from radiation dosimetry to nonlinear optics. In particular, B2O3-BaO based glasses are attractive to frequency generation since their barium metaborate phase (β-BaB2O4 or β-BBO) may be crystallized under proper heat treatment. Despite the vast literature covering their linear and second-order optical nonlinear properties, their third-order nonlinearities remain overlooked. This paper thus reports a study on the nonlinear refraction (n2) of BBO and BBS-DyEu glasses through femtosecond Z-scan technique. The results were modeled using the BGO approach, which showed that oxygen ions are playing a role in the nonlinear optical properties of the glasses studied here. In addition, the barium borate glasses containing rare-earths ions were found to exhibit larger nonlinearities, which is in agreement with previous studies.

Radium mobility and the age of groundwater in public-drinking-water supplies from the Cambrian-Ordovician aquifer system, north-central USA

USGS Publications Warehouse

Stackelberg, Paul E.; Szabo, Zoltan; Jurgens, Bryant C.

2018-01-01

High radium (Ra) concentrations in potable portions of the Cambrian-Ordovician (C-O) aquifer system were investigated using water-quality data and environmental tracers (3H, 3Hetrit, SF6, 14C and 4Herad) of groundwater age from 80 public-supply wells (PSWs). Groundwater ages were estimated by calibration of tracers to lumped parameter models and ranged from modern (<50 yr) in upgradient, regionally unconfined areas to ancient (>1 Myr) in the most downgradient, confined portions of the potable system. More than 80 and 40 percent of mean groundwater ages were older than 1000 and 50,000 yr, respectively. Anoxic, Fe-reducing conditions and increased mineralization develop with time in the aquifer system and mobilize Ra into solution resulting in the frequent occurrence of combined Ra (Rac = 226Ra + 228Ra) at concentrations exceeding the USEPA MCL of 185 mBq/L (5 pCi/L). The distribution of the three Ra isotopes comprising total Ra (Rat = 224Ra + 226Ra + 228Ra) differed across the aquifer system. The concentrations of 224Ra and 228Ra were strongly correlated and comprised a larger proportion of the Rat concentration in samples from the regionally unconfined area, where arkosic sandstones provide an enhanced source for progeny from the 232Th decay series. 226Ra comprised a larger proportion of the Ratconcentration in samples from downgradient confined regions. Concentrations of Rat were significantly greater in samples from the regionally confined area of the aquifer system because of the increase in 226Ra concentrations there as compared to the regionally unconfined area. 226Ra distribution coefficients decreased substantially with anoxic conditions and increasing ionic strength of groundwater (mineralization), indicating that Ra is mobilized to solution from solid phases of the aquifer as adsorption capacity is diminished. The amount of 226Ra released from solid phases by alpha-recoil mechanisms and retained in solution increases relative to the amount of Ra sequestered by adsorption processes or co-precipitation with barite as adsorption capacity and the concentration of Ba decreases. Although 226Ra occurred at concentrations greater than 224Ra or 228Ra, the ingestion exposure risk was greater for 228Ra owing to its greater toxicity. In addition, 224Ra added substantial alpha-particle radioactivity to potable samples from the C-O aquifer system. Thus, monitoring for Ra isotopes and gross-alpha-activity (GAA) is important in upgradient, regionally unconfined areas as downgradient, and GAA measurements made within 72 h of sample collection would best capture alpha-particle radiation from the short-lived 224Ra.

Isotopic and geochemical tracers for U(VI) reduction and U mobility at an in situ recovery U mine

DOE PAGES

Basu, Anirban; Brown, Shaun T.; Christensen, John N.; ...

2015-05-19

In situ recovery (ISR) uranium (U) mining mobilizes U in its oxidized hexavalent form (U(VI)) by oxidative dissolution of U from the roll-front U deposits. Post-mining natural attenuation of residual U(VI) at ISR mines is a potential remediation strategy. Detection and monitoring of naturally occurring reducing subsurface environments are important for successful implementation of this remediation scheme. We used the isotopic tracers ²³⁸U/²³⁵U (δ²³⁸U), ²³⁴U/²³⁸U activity ratio, and ³⁴S/³²S (δ³⁴S), and geochemical measurements of U ore and groundwater collected from 32 wells located within, upgradient, and downgradient of a roll-front U deposit to detect U(VI) reduction and U mobility atmore » an ISR mining site at Rosita, TX, USA. The δ²³⁸U in Rosita groundwater varies from 0.61‰ to -2.49‰, with a trend toward lower δ²³⁸U in downgradient wells. The concurrent decrease in U(VI) concentration and δ²³⁸U with an ε of 0.48‰ ± 0.08‰ is indicative of naturally occurring reducing environments conducive to U(VI) reduction. Additionally, characteristic ²³⁴U/²³⁸U activity ratio and δ³⁴S values may also be used to trace the mobility of the ore zone groundwater after mining has ended. These results support the use of U isotope-based detection of natural attenuation of U(VI) at Rosita and other similar ISR mining sites.« less

Isotopic evidence for reductive immobilization of uranium across a roll-front mineral deposit

DOE PAGES

Brown, Shaun T.; Basu, Anirban; Christensen, John N.; ...

2016-05-20

We use uranium (U) isotope ratios to detect and quantify the extent of natural U reduction in groundwater across a roll front redox gradient. Our study was conducted at the Smith Ranch-Highland in situ recovery (ISR) U mine in eastern Wyoming, USA, where economic U deposits occur in the Paleocene Fort Union formation. To evaluate the fate of aqueous U in and adjacent to the ore body, we investigated the chemical composition and isotope ratios of groundwater samples from the roll-front type ore body and surrounding monitoring wells of a previously mined area. The 238U/ 235U of groundwater varies bymore » approximately 3‰ and is correlated with U concentrations. Fluid samples down-gradient of the ore zone are the most depleted in 238U and have the lowest U concentrations. Activity ratios of 234U/ 238U are ~5.5 up-gradient of the ore zone, ~1.0 in the ore zone, and between 2.3 and 3.7 in the down-gradient monitoring wells. High-precision measurements of 234U/ 238U and 238U/ 235U allow for development of a conceptual model that evaluates both the migration of U from the ore body and the extent of natural attenuation due to reduction. We find that the premining migration of U down-gradient of the delineated ore body is minimal along eight transects due to reduction in or adjacent to the ore body, whereas two other transects show little or no sign of reduction in the down-gradient region. Lastly, these results suggest that characterization of U isotopic ratios at the mine planning stage, in conjunction with routine geochemical analyses, can be used to identify where more or less postmining remediation will be necessary.« less

Evaluation of the fate and transport of chlorinated ethenes in a complex groundwater system discharging to a stream in Wonju, Korea

NASA Astrophysics Data System (ADS)

Lee, Seong-Sun; Kaown, Dugin; Lee, Kang-Kun

2015-11-01

Chlorinated ethenes such as trichloroethylene (TCE) are common and persistent groundwater contaminants. If contaminated groundwater discharges to a stream, then stream water pollution near the contamination site also becomes a problem. In this respect, the fate and transport of chlorinated ethenes around a stream in an industrial complex were evaluated using the concentration of each component, and hydrogeochemical, microbial, and compound-specific carbon isotope data. Temporal and spatial monitoring reveal that a TCE plume originating from main and local source zones continues to be discharged to a stream. Groundwater geochemical data indicate that aerobic conditions prevail in the upgradient area of the studied aquifer, whereas conditions become anaerobic in the downgradient. The TCE molar fraction is high at the main and local source zones, ranging from 87.4 to 99.2% of the total volatile organic compounds (VOCs). An increasing trend in the molar fraction of cis-1, 2-Dichloroethene (cis-DCE) and vinyl chloride (VC) was observed in the downgradient zone of the study area. The enriched δ13C values of TCE and depleted values of cis-DCE in the stream zone, compared to those of the source zone, also suggest biodegradation of VOCs. Microbial community structures in monitoring wells adjacent to the stream zone in the downgradient area were analyzed using 16S rRNA gene-based pyrosequencing to identify the microorganisms responsible for biodegradation. This was attributed to the high relative abundance of dechlorinating bacteria in monitoring wells under anaerobic conditions farthest from the stream in the downgradient area. The multilateral approaches adopted in this study, combining hydrogeochemical and biomolecular methods with compound-specific analyses, indicate that contaminants around the stream were naturally attenuated by active anaerobic biotransformation processes.

Stimulating in situ denitrification in an aerobic, highly permeable municipal drinking water aquifer

NASA Astrophysics Data System (ADS)

Critchley, K.; Rudolph, D. L.; Devlin, J. F.; Schillig, P. C.

2014-12-01

A preliminary trial of a cross-injection system (CIS) was designed to stimulate in situ denitrification in an aquifer servicing an urban community in southern Ontario. It was hypothesized that this remedial strategy could be used to reduce groundwater nitrate in the aquifer such that it could remain in use as a municipal supply until the beneficial effects of local reduced nutrient loadings lead to long-term water quality improvement at the wellfield. The CIS application involved injecting a carbon source (acetate) into the subsurface using an injection-extraction well pair positioned perpendicular to the regional flow direction, up-gradient of the water supply wells, with the objective of stimulating native denitrifying bacteria. The pilot remedial strategy was targeted in a high nitrate flux zone within an aerobic and heterogeneous section of the glacial sand and gravel aquifer. Acetate injections were performed at intervals ranging from daily to bi-daily. The carbon additions led to general declines in dissolved oxygen concentrations; decreases in nitrate concentration were localized in aquifer layers where velocities were estimated to be less than 0.5 m/day. NO3-15N and NO3-18O isotope data indicated the nitrate losses were due to denitrification. Relatively little nitrate was removed from groundwater in the more permeable strata, where velocities were estimated to be on the order of 18 m/day or greater. Overall, about 11 percent of the nitrate mass passing through the treatment zone was removed. This work demonstrates that stimulating in situ denitrification in an aerobic, highly conductive aquifer is challenging but achievable. Further work is needed to increase rates of denitrification in the most permeable units of the aquifer.

Methyl tert-butyl ether biodegradation by indigenous aquifer microorganisms under natural and artificial oxic conditions

USGS Publications Warehouse

Landmeyer, J.E.; Chapelle, F.H.; Herlong, H.H.; Bradley, P.M.

2001-01-01

Microbial communities indigenous to a shallow groundwater system near Beaufort, SC, degraded milligram per liter concentrations of methyl tert-butyl ether (MTBE) under natural and artificial oxic conditions. Significant MTBE biodegradation was observed where anoxic, MTBE-contaminated groundwater discharged to a concrete-lined ditch. In the anoxic groundwater adjacent to the ditch, concentrations of MTBE were > 1 mg/L. Where groundwater discharge occurs, dissolved oxygen (DO) concentrations beneath the ditch exceeded 1.0 mg/L to a depth of 1.5 m, and MTBE concentrations decreased to <1 ??g/L prior to discharge. MTBE mass flux calculations indicate that 96% of MTBE mass loss occurs in the relatively small oxic zone prior to discharge. Samples of a natural microbial biofilm present in the oxic zone beneath the ditch completely degraded [U-14C]MTBE to [14C]CO2 in laboratory liquid culture studies, with no accumulation of intermediate compounds. Upgradient of the ditch in the anoxic, MTBE and BTEX-contaminated aquifer, addition of a soluble oxygen release compound resulted in oxic conditions and rapid MTBE biodegradation by indigenous microorganisms. In an observation well located closest to the oxygen addition area, DO concentrations increased from 0.4 to 12 mg/L in <60 days and MTBE concentrations decreased from 20 to 3 mg/L. In the same time period at a downgradient observation well, DO increased from <0.2 to 2 mg/L and MTBE concentrations decreased from 30 to <5 mg/L. These results indicate that microorganisms indigenous to the groundwater system at this site can degrade milligram per liter concentrations of MTBE under natural and artificial oxic conditions.

Chemical evolution of groundwater in the Wilcox aquifer of the northern Gulf Coastal Plain, USA

NASA Astrophysics Data System (ADS)

Haile, Estifanos; Fryar, Alan E.

2017-12-01

The Wilcox aquifer is a major groundwater resource in the northern Gulf Coastal Plain (lower Mississippi Valley) of the USA, yet the processes controlling water chemistry in this clastic aquifer have received relatively little attention. The current study combines analyses of solutes and stable isotopes in groundwater, petrography of core samples, and geochemical modeling to identify plausible reactions along a regional flow path ˜300 km long. The hydrochemical facies evolves from Ca-HCO3 upgradient to Na-HCO3 downgradient, with a sequential zonation of terminal electron-accepting processes from Fe(III) reduction through SO4 2- reduction to methanogenesis. In particular, decreasing SO4 2- and increasing δ34S of SO4 2- along the flow path, as well as observations of authigenic pyrite in core samples, provide evidence of SO4 2- reduction. Values of δ13C in groundwater suggest that dissolved inorganic carbon is contributed both by oxidation of sedimentary organic matter and calcite dissolution. Inverse modeling identified multiple plausible sets of reactions between sampled wells, which typically involved cation exchange, pyrite precipitation, CH2O oxidation, and dissolution of amorphous Fe(OH)3, calcite, or siderite. These reactions are consistent with processes identified in previous studies of Atlantic Coastal Plain aquifers. Contrasts in groundwater chemistry between the Wilcox and the underlying McNairy and overlying Claiborne aquifers indicate that confining units are relatively effective in limiting cross-formational flow, but localized cross-formational mixing could occur via fault zones. Consequently, increased pumping in the vicinity of fault zones could facilitate upward movement of saline water into the Wilcox.

Stimulating in situ denitrification in an aerobic, highly permeable municipal drinking water aquifer.

PubMed

Critchley, K; Rudolph, D L; Devlin, J F; Schillig, P C

2014-12-15

A preliminary trial of a cross-injection system (CIS) was designed to stimulate in situ denitrification in an aquifer servicing an urban community in southern Ontario. It was hypothesized that this remedial strategy could be used to reduce groundwater nitrate in the aquifer such that it could remain in use as a municipal supply until the beneficial effects of local reduced nutrient loadings lead to long-term water quality improvement at the wellfield. The CIS application involved injecting a carbon source (acetate) into the subsurface using an injection-extraction well pair positioned perpendicular to the regional flow direction, up-gradient of the water supply wells, with the objective of stimulating native denitrifying bacteria. The pilot remedial strategy was targeted in a high nitrate flux zone within an aerobic and heterogeneous section of the glacial sand and gravel aquifer. Acetate injections were performed at intervals ranging from daily to bi-daily. The carbon additions led to general declines in dissolved oxygen concentrations; decreases in nitrate concentration were localized in aquifer layers where velocities were estimated to be less than 0.5m/day. NO3-(15)N and NO3-(18)O isotope data indicated the nitrate losses were due to denitrification. Relatively little nitrate was removed from groundwater in the more permeable strata, where velocities were estimated to be on the order of 18 m/day or greater. Overall, about 11 percent of the nitrate mass passing through the treatment zone was removed. This work demonstrates that stimulating in situ denitrification in an aerobic, highly conductive aquifer is challenging but achievable. Further work is needed to increase rates of denitrification in the most permeable units of the aquifer. Copyright © 2014 Elsevier B.V. All rights reserved.

Isotopic and geochemical tracers for U(VI) reduction and U mobility at an in situ recovery U mine

DOE Office of Scientific and Technical Information (OSTI.GOV)

Basu, Anirban; Brown, Shaun T.; Christensen, John N.

In situ recovery (ISR) uranium (U) mining mobilizes U in its oxidized hexavalent form (U(VI)) by oxidative dissolution of U from the roll-front U deposits. Post-mining natural attenuation of residual U(VI) at ISR mines is a potential remediation strategy. Detection and monitoring of naturally occurring reducing subsurface environments are important for successful implementation of this remediation scheme. We used the isotopic tracers ²³⁸U/²³⁵U (δ²³⁸U), ²³⁴U/²³⁸U activity ratio, and ³⁴S/³²S (δ³⁴S), and geochemical measurements of U ore and groundwater collected from 32 wells located within, upgradient, and downgradient of a roll-front U deposit to detect U(VI) reduction and U mobility atmore » an ISR mining site at Rosita, TX, USA. The δ²³⁸U in Rosita groundwater varies from 0.61‰ to -2.49‰, with a trend toward lower δ²³⁸U in downgradient wells. The concurrent decrease in U(VI) concentration and δ²³⁸U with an ε of 0.48‰ ± 0.08‰ is indicative of naturally occurring reducing environments conducive to U(VI) reduction. Additionally, characteristic ²³⁴U/²³⁸U activity ratio and δ³⁴S values may also be used to trace the mobility of the ore zone groundwater after mining has ended. These results support the use of U isotope-based detection of natural attenuation of U(VI) at Rosita and other similar ISR mining sites.« less

Un-collimated single-photon imaging system for high-sensitivity small animal and plant imaging.

PubMed

Walker, Katherine L; Judenhofer, Martin S; Cherry, Simon R; Mitchell, Gregory S

2015-01-07

In preclinical single-photon emission computed tomography (SPECT) system development the primary objective has been to improve spatial resolution by using novel parallel-hole or multi-pinhole collimator geometries. However, such high-resolution systems have relatively poor sensitivity (typically 0.01-0.1%). In contrast, a system that does not use collimators can achieve very high-sensitivity. Here we present a high-sensitivity un-collimated detector single-photon imaging (UCD-SPI) system for the imaging of both small animals and plants. This scanner consists of two thin, closely spaced, pixelated scintillator detectors that use NaI(Tl), CsI(Na), or BGO. The performance of the system has been characterized by measuring sensitivity, spatial resolution, linearity, detection limits, and uniformity. With (99m)Tc (140 keV) at the center of the field of view (20 mm scintillator separation), the sensitivity was measured to be 31.8% using the NaI(Tl) detectors and 40.2% with CsI(Na). The best spatial resolution (FWHM when the image formed as the geometric mean of the two detector heads, 20 mm scintillator separation) was 19.0 mm for NaI(Tl) and 11.9 mm for CsI(Na) at 140 keV, and 19.5 mm for BGO at 1116 keV, which is somewhat degraded compared to the cm-scale resolution obtained with only one detector head and a close source. The quantitative accuracy of the system's linearity is better than 2% with detection down to activity levels of 100 nCi. Two in vivo animal studies (a renal scan using (99m)Tc MAG-3 and a thyroid scan with (123)I) and one plant study (a (99m)TcO4(-) xylem transport study) highlight the unique capabilities of this UCD-SPI system. From the renal scan, we observe approximately a one thousand-fold increase in sensitivity compared to the Siemens Inveon SPECT/CT scanner. UCD-SPI is useful for many imaging tasks that do not require excellent spatial resolution, such as high-throughput screening applications, simple radiotracer uptake studies in tumor xenografts, dynamic studies where very good temporal resolution is critical, or in planta imaging of radioisotopes at low concentrations.

Un-collimated single-photon imaging system for high-sensitivity small animal and plant imaging

DOE PAGES

Walker, Katherine L.; Judenhofer, Martin S.; Cherry, Simon R.; ...

2014-12-12

In preclinical single-photon emission computed tomography (SPECT) system development the primary objective has been to improve spatial resolution by using novel parallel-hole or multi-pinhole collimator geometries. Furthermore, such high-resolution systems have relatively poor sensitivity (typically 0.01% to 0.1%). In contrast, a system that does not use collimators can achieve very high-sensitivity. Here we present a high-sensitivity un-collimated detector single-photon imaging (UCD-SPI) system for the imaging of both small animals and plants. This scanner consists of two thin, closely spaced, pixelated scintillator detectors that use NaI(Tl), CsI(Na), or BGO. The performance of the system has been characterized by measuring sensitivity, spatialmore » resolution, linearity, detection limits, and uniformity. With 99mTc (140 keV) at the center of the field of view (20 mm scintillator separation), the sensitivity was measured to be 31.8% using the NaI(Tl) detectors and 40.2% with CsI(Na). The best spatial resolution (FWHM when the image formed as the geometric mean of the two detector heads, 20 mm scintillator separation) was 19.0 mm for NaI(Tl) and 11.9 mm for CsI(Na) at 140 keV, and 19.5 mm for BGO at 1116 keV, which is somewhat degraded compared to the cm-scale resolution obtained with only one detector head and a close source. The quantitative accuracy of the system’s linearity is better than 2% with detection down to activity levels of 100 nCi. Two in vivo animal studies (a renal scan using 99mTc MAG-3 and a thyroid scan with 123I) and one plant study (a 99mTcO 4- xylem transport study) highlight the unique capabilities of this UCD-SPI system. From the renal scan, we observe approximately a one thousand-fold increase in sensitivity compared to the Siemens Inveon SPECT/CT scanner. In conclusion, UCD-SPI is useful for many imaging tasks that do not require excellent spatial resolution, such as high-throughput screening applications, simple radiotracer uptake studies in tumor xenografts, dynamic studies where very good temporal resolution is critical, or in planta imaging of radioisotopes at low concentrations.« less

Charge Resolution of the Silicon Matrix of the ATIC Experiment

NASA Technical Reports Server (NTRS)

Zatsepin, V. I.; Adams, J. H., Jr.; Ahn, H. S.; Bashindzhagyan, G. L.; Batkov, K. E.; Case, G.; Christl, M.; Ganel, O.; Fazely, A. R.; Ganel, O.;

Un-collimated single-photon imaging system for high-sensitivity small animal and plant imaging

NASA Astrophysics Data System (ADS)

Walker, Katherine L.; Judenhofer, Martin S.; Cherry, Simon R.; Mitchell, Gregory S.

2015-01-01

In preclinical single-photon emission computed tomography (SPECT) system development the primary objective has been to improve spatial resolution by using novel parallel-hole or multi-pinhole collimator geometries. However, such high-resolution systems have relatively poor sensitivity (typically 0.01-0.1%). In contrast, a system that does not use collimators can achieve very high-sensitivity. Here we present a high-sensitivity un-collimated detector single-photon imaging (UCD-SPI) system for the imaging of both small animals and plants. This scanner consists of two thin, closely spaced, pixelated scintillator detectors that use NaI(Tl), CsI(Na), or BGO. The performance of the system has been characterized by measuring sensitivity, spatial resolution, linearity, detection limits, and uniformity. With 99mTc (140 keV) at the center of the field of view (20 mm scintillator separation), the sensitivity was measured to be 31.8% using the NaI(Tl) detectors and 40.2% with CsI(Na). The best spatial resolution (FWHM when the image formed as the geometric mean of the two detector heads, 20 mm scintillator separation) was 19.0 mm for NaI(Tl) and 11.9 mm for CsI(Na) at 140 keV, and 19.5 mm for BGO at 1116 keV, which is somewhat degraded compared to the cm-scale resolution obtained with only one detector head and a close source. The quantitative accuracy of the system’s linearity is better than 2% with detection down to activity levels of 100 nCi. Two in vivo animal studies (a renal scan using 99mTc MAG-3 and a thyroid scan with 123I) and one plant study (a 99mTcO4- xylem transport study) highlight the unique capabilities of this UCD-SPI system. From the renal scan, we observe approximately a one thousand-fold increase in sensitivity compared to the Siemens Inveon SPECT/CT scanner. UCD-SPI is useful for many imaging tasks that do not require excellent spatial resolution, such as high-throughput screening applications, simple radiotracer uptake studies in tumor xenografts, dynamic studies where very good temporal resolution is critical, or in planta imaging of radioisotopes at low concentrations.

Transport of free and particulate-associated bacteria in karst

NASA Astrophysics Data System (ADS)

Mahler, B. J.; Personné, J.-C.; Lods, G. F.; Drogue, C.

2000-12-01

Karst aquifers, because of their unique hydrogeologic characteristics, are extremely susceptible to contamination by pathogens. Here we present the results of an investigation of contamination of a karst aquifer by fecal indicator bacteria. Two wells intercepting zones with contrasting effective hydraulic conductivities, as determined by pump test, were monitored both during the dry season and in response to a rain event. Samples were also collected from the adjacent ephemeral surface stream, which is known to be impacted by an upstream wastewater treatment plant after rainfall. Whole water and suspended sediment samples were analyzed for fecal coliforms and enterococci. During the dry season, pumping over a 2-day period resulted in increases in concentrations of fecal coliforms to greater than 10,000 CFU/100 ml in the high-conductivity well; enterococci and total suspended solids also increased, to a lesser degree. Toward the end of the pumping period, as much as 50% of the fecal coliforms were associated with suspended sediment. Irrigation of an up-gradient pine plantation with primary-treated wastewater is the probable source of the bacterial contamination. Sampling after a rain event revealed the strong influence of water quality of the adjacent Terrieu Creek on the ground water. Bacterial concentrations in the wells showed a rapid response to increased concentrations in the surface water, with fecal coliform concentrations in ground water ultimately reaching 60,000 CFU/100 ml. Up to 100% of the bacteria in the ground water was associated with suspended sediment at various times. The results of this investigation are evidence of the strong influence of surface water on ground water in karst terrain, including that of irrigation water. The large proportion of bacteria associated with particulates in the ground water has important implications for public health, as bacteria associated with particulates may be more persistent and more difficult to inactivate. The high bacterial concentrations found in both wells, despite the difference in hydraulic conductivity, demonstrates the difficulty of predicting vulnerability of individual wells to bacterial contamination in karst. The extreme temporal variability in bacterial concentrations underscores the importance of event-based monitoring of the bacterial quality of public water supplies in karst.

Using multiple chemical indicators to assess sources of nitrate and age of groundwater in a karstic spring basin

USGS Publications Warehouse

Katz, B.; Copeland, R.; Greenhalgh, T.; Ceryak, R.; Zwanka, W.

2005-01-01

Human health and ecological concerns have arisen due to a steady increase in nitrate-N concentrations during the past 40 years in Fannin Springs (0.3-4.7 mg/L), a regional discharge point with an average flow of >2.8 m3/second (>100 ft3/second) for water from the karstic Upper Floridan aquifer (UFA). Multiple chemical indicators (major dissolved species, 15N and 18O of nitrate, dissolved gases, 78 pesticides and degradates, and 67 organic compounds typically found in domestic and industrial wastewater) and transient tracers (3H/3He, chlorofluorocarbons [CFCs], sulfur hexafluoride [SF6]) were analyzed in water samples from nine wells along three transects and in spring water to assess groundwater age and potential contaminant sources. Land use is predominantly agricultural (52 percent) and forest (31 percent) in the 320 km2 (124 mi2) spring basin, which was delineated from a potentiometric-surface map of the UFA using high-resolution water-level data. Nitrate-N concentrations were highly variable in the oxic UFA and ranged from <0.02 to 4.7 mg/L. ?? 15N-NO3 values (3.4-9.9 per mil) indicated that nitrate contamination originated from inorganic sources (synthetic fertilizer) and organic sources (manure spreading or waste disposal). Higher nitrate concentrations and the younger age of spring water relative to water from upgradient wells indicate better communication with N sources at the surface. Apparent ages of groundwater correlated positively with well depth (P < 0.05) and were younger in water from wells nearer to the spring (<8 years) compared with other wells (10-50 years). Most transient tracer concentrations were consistent with binary mixing curves representing mixtures of water recharged during the past 10 years and older water (recharged before 1940). Young water mixing fractions ranged from 0.07 to 0.90. Trace levels of herbicides found in groundwater and spring water were indicative of applications for vegetative control in agricultural and other land-use types.

Remediating Contaminant Plumes in Groundwater with Shallow Excavations Containing Coarse Reactive Media.

PubMed

Hudak, Paul F

2018-02-01

A groundwater flow and mass transport model tested the capability of shallow excavations filled with coarse, reactive media to remediate a hypothetical unconfined aquifer with a maximum saturated thickness of 5 m. Modeled as contaminant sinks, the rectangular excavations were 10 m downgradient of an initial contaminant plume originating from a source at the top of the aquifer. The initial plume was approximately 259 m long, 23 m wide, and 5 m thick, with a downgradient tip located approximately 100 m upgradient of the site boundary. The smallest trench capable of preventing offsite migration was 11 m long (measured perpendicular to groundwater flow), 4 m wide (measured parallel to groundwater flow), and 3 m deep. Results of this study suggest that shallow trenches filled with coarse filter media that partially penetrate unconfined aquifers may be a viable alternative for remediating contaminated groundwater at some sites.

California Groundwater Units

USGS Publications Warehouse

Johnson, Tyler D.; Belitz, Kenneth

2014-01-01

The California Groundwater Units dataset classifies and delineates areas within the State of California into one of three groundwater-based polygon units: (1) those areas previously defined as alluvial groundwater basins or subbasins, (2) highland areas that are adjacent to and topographically upgradient of groundwater basins, and (3) highland areas not associated with a groundwater basin, only a hydrogeologic province. In total, 938 Groundwater Units are represented. The Groundwater Units dataset relates existing groundwater basins with their newly delineated highland areas which can be used in subsequent hydrologic studies. The methods used to delineate groundwater-basin-associated highland areas are similar to those used to delineate a contributing area (such as for a lake or water body); the difference is that highland areas are constrained to the immediately surrounding upslope (upstream) area. Upslope basins have their own delineated highland. A geoprocessing tool was created to facilitate delineation of highland areas for groundwater basins and subbasins and is available for download.

Methanogenic biodegradation of charcoal production wastes in groundwater at Kingsford, Michigan, USA

USGS Publications Warehouse

Michael, Godsy E.; Warren, E.; Westjohn, D.B.

2001-01-01

A house exploded in the City of Kingsford, Michigan USA. The explosion was caused by CH4 that leaked into the basement from the surrounding soil. Evidence suggests that biodegradation of products from the distillation and spillage at or near a former wood carbonization plant site was the major source of CH4 and CO2 in the groundwater system. The plant area is directly upgradient from deep groundwater, samples of which are green-yellow in colour, have a very strong odour of burnt wood, contain high concentrations of mononuclear aromatic and phenolic compounds, and extremely high concentrations of volatile fatty acids. The majority of the dissolved compounds in these groundwater samples have been shown, using laboratory microcosms, to be anaerobically biodegradable to CH4 and CO2. The biodegradable compounds, and the amounts of CH4 and CO2 produced in the microcosms, are consistent with observations from field samples.

What favors convective aggregation and why?

NASA Astrophysics Data System (ADS)

Muller, Caroline; Bony, Sandrine

2015-07-01

The organization of convection is ubiquitous, but its physical understanding remains limited. One particular type of organization is the spatial self-aggregation of convection, taking the form of cloud clusters, or tropical cyclones in the presence of rotation. We show that several physical processes can give rise to self-aggregation and highlight the key features responsible for it, using idealized simulations. Longwave radiative feedbacks yield a "radiative aggregation." In that case, sufficient spatial variability of radiative cooling rates yields a low-level circulation, which induces the upgradient energy transport and radiative-convective instability. Not only do vertically integrated radiative budgets matter but the vertical profile of cooling is also crucial. Convective aggregation is facilitated when downdrafts below clouds are weak ("moisture-memory aggregation"), and this is sufficient to trigger aggregation in the absence of longwave radiative feedbacks. These results shed some light on the sensitivity of self-aggregation to various parameters, including resolution or domain size.

Ground-water contamination from lead shot at Prime Hook National Wildlife Refuge, Sussex County, Delaware

USGS Publications Warehouse

Soeder, Daniel J.; Miller, Cherie V.

2003-01-01

Prime Hook National Wildlife Refuge is located in southeastern Delaware in coastal lowlands along the margin of Delaware Bay. For 37 years, the Broadkiln Sportsman?s Club adjacent to the refuge operated a trap-shooting range, with the clay-target launchers oriented so that the expended lead shot from the range dropped into forested wetland areas on the refuge property. Investigators have estimated that up to 58,000 shotgun pellets per square foot are present in locations on the refuge where the lead shot fell to the ground. As part of the environmental risk assessment for the site, the U.S. Geological Survey (USGS) investigated the potential for lead contamination in ground water. Results from two sampling rounds in 19 shallow wells indicate that elevated levels of dissolved lead are present in ground water at the site. The lead and associated metals, such as antimony and arsenic (common shotgun pellet alloys), are being transported along shallow ground-water flowpaths toward an open-water slough in the forested wetland adjacent to the downrange target area. Water samples from wells located along the bank of the slough contained dissolved lead concentrations higher than 400 micrograms per liter, and as high as 1 milligram per liter. In contrast, a natural background concentration of lead from ground water in a well upgradient from the site is about 1 microgram per liter. Two water samples collected several months apart from the slough directly downgradient of the shooting range contained 24 and 212 micrograms per liter of lead, respectively. The data indicate that lead from a concentrated deposit of shotgun pellets on the refuge has been mobilized through a combination of acidic water conditions and a very sandy, shallow, unconfined aquifer, and is moving along ground-water flowpaths toward the surface-water drainage. Data from this study will be used to help delineate the lead plume, and determine the fate and transport of lead from the source area.

Hydrogeology and soil gas at J-Field, Aberdeen Proving Ground, Maryland

USGS Publications Warehouse

Hughes, W.B.

1993-01-01

Disposal of chemical warfare agents, munitions, and industrial chemicals in J-Field, Aberdeen Proving Ground, Maryland, has contaminated soil, groundwater and surface water. Seven exploratory borings and 38 observation wells were drilled to define the hydrogeologic framework at J-Field and to determine the type, extent, and movement of contaminants. The geologic units beneath J-Field consist of Coastal Plain sediments of the Cretaceous Patapsco Formation and Pleistocene Talbot Formation. The Patapsco Formation contains several laterally discontinuous aquifers and confining units. The Pleistocene deposits were divided into 3 hydrogeologic units--a surficial aquifer, a confining unit, and a confined aquifer. Water in the surficial aquifer flows laterally from topographically high areas to discharge areas in marshes and streams, and vertically to the underlying confined aquifer. In offshore areas, water flows from the deeper confined aquifers upward toward discharge areas in the Gunpowder River and Chesapeake Bay. Analyses of soil-gas samples showed high relative-flux values of chlorinated solvents, phthalates, and hydrocarbons at the toxic-materials disposal area, white-phosphorus disposal area, and riot-control-agent disposal area. The highest flux values were located downgradient of the toxic materials and white phosphorus disposal areas, indicating that groundwater contaminants are moving from source areas beneath the disposal pits toward discharge points in the marshes and estuaries. Elevated relative-flux values were measured upgradient and downgradient of the riot-control agent disposal area, and possibly result from soil and (or) groundwater contamination.

Effects of three highway-runoff detention methods on water quality of the surficial aquifer system in central Florida

USGS Publications Warehouse

Schiffer, D.M.

1989-01-01

Water quality of the surficial aquifer system in central Florida was evaluated at one exfiltration pipe, two ponds (detention and retention), and two swales in central Florida, representing three runoff-detention methods, to detect any effect from infiltrating highway runoff. Concentrations of major ions, metals, and nutrients in groundwater and bottom sediments were measured from 1984 through 1986. At each study area, constituent concentrations in groundwater near the structure were compared to concentrations in groundwater from an upgradient control site. Groundwater quality data were also pooled by detention method and statistically compared to detect any significant differences between methods. Significantly greater mean phosphorus concentrations in groundwater near the exfiltration pipe than those in the control well was the only evidence of increasing constituent concentrations in groundwater near structures. The quality of water was more variable, and had greater constituent concentrations in the unsaturated zone than in the saturated zone near the exfiltration pipe. Values of water quality variables measured in groundwater at all study areas generally were within State drinking water standards. The main exception was dissolved iron, which commonly exceeded 300 micrograms/L at one swale and the detention pond. Results of the study indicate that natural processes occurring in soils attenuate inorganic constituent concentrations prior to reaching the receiving groundwater. However, organic compounds detected in bottom sediments at the retention pond indicate a potential problem that may eventually affect the quality of the receiving groundwater. (USGS)

Pharmaceuticals and other organic wastewater contaminants within a leachate plume downgradient of a municipal landfill

USGS Publications Warehouse

Barnes, Kimberlee K.; Christenson, Scott C.; Kolpin, Dana W.; Focazio, Michael J.; Furlong, Edward T.; Zaugg, Steven D.; Meyer, Michael T.; Barber, Larry B.

2004-01-01

Ground water samples collected from the Norman Landfill research site in central Oklahoma were analyzed as part of the U.S. Geological Survey (USGS) Toxic Substances Hydrology Program's national reconnaissance of pharmaceuticals and other organic waste water contaminants (OWCs) in ground water. Five sites, four of which are located downgradient of the landfill, were sampled in 2000 and analyzed for 76 OWCs using four research methods developed by the USGS. OWCs were detected in water samples from all of the sites sampled, with 22 of the 76 OWCs being detected at least once. Cholesterol (a plant and animal steroid), was detected at all five sites and was the only compound detected in a well upgradient of the landfill. N,Ndiethyltoluamide (DEET used in insect repellent) and tri(2-chloroethyl) phosphate (fire-retardant) were detected in water samples from all four sites located within the landfill-derived leachate plume. The sites closest to the landfill had more detections and greater concentrations of each of the detected compounds than sites located farther away. Detection of multiple OWCs occurred in the four sites located within the leachate plume, with a minimum of four and a maximum of 17 OWCs detected. Because the landfill was established in the 1920s and closed in 1985, many compounds detected in the leachate plume were likely disposed of decades ago. These results indicate the potential for long-term persistence and transport of some OWCs in ground water.

Groundwater geochemical and selected volatile organic compound data, Operable Unit 1, Naval Undersea Warfare Center, Division Keyport, Washington, July 2013

USGS Publications Warehouse

Huffman, Raegan L.

2014-01-01

Previous investigations indicate that concentrations of chlorinated volatile organic compounds (CVOCs) are substantial in groundwater beneath the 9-acre former landfill at Operable Unit 1, Naval Undersea Warfare Center, Division Keyport, Washington. The U.S. Geological Survey has continued to monitor groundwater geochemistry to ensure that conditions remain favorable for contaminant biodegradation as specified in the Record of Decision for the site. This report presents groundwater geochemical and selected CVOC data collected at Operable Unit 1 by the U.S. Geological Survey during July 9–18, 2013, in support of longterm monitoring for natural attenuation. Groundwater samples were collected from 13 wells and 9 piezometers, as well as from 10 shallow groundwater passive-diffusion sampling sites in the nearby marsh. Samples from all wells and piezometers were analyzed for oxidation-reduction (redox) sensitive constituents and dissolved gases. Samples from all piezometers and four wells also were analyzed for CVOCs, as were all samples from the passive-diffusion sampling sites. In 2013, concentrations of redox-sensitive constituents measured at all wells and piezometers were consistent with those measured in previous years, with dissolved oxygen concentrations at all except an upgradient well 0.2 milligrams per liter or less; little to no detectable nitrate; abundant dissolved manganese, iron, and methane; and commonly detected sulfide. In the upper aquifer of the northern plantation in 2013, CVOC concentrations at all piezometers were similar to those measured in previous years, and concentrations of the reductive dechlorination byproducts ethane and ethene were slightly lower or the same as concentrations measured in 2012. In the upper aquifer of the southern plantation, CVOC concentrations measured in piezometers during 2013 continued to be variable as in previous years, and often very high, and reductive dechlorination byproducts were detected in two of the three wells and in all but one piezometer. Beneath the marsh adjacent to the southern plantation, chloroethene concentrations measured in 2013 continued to vary spatially and temporaly, and also were very high. Total CVOC concentrations, at what have been historically the most contaminated passive-diffusion sampler sites (S-4, S-4B, S-5, and S-5B) remained elevated. For the intermediate aquifer in 2013, concentrations of reductive dechlorination byproducts ethane and ethene and CVOCs were consistent with those measured in previous years.

Preliminary hydrogeologic assessment of a ground-water contamination area in Wolcott, Connecticut

USGS Publications Warehouse

Stone, J.R.; Casey, G.D.; Mondazzi, R.A.; Frick, T.W.

1997-01-01

Contamination of ground water by volatile organic compounds and inorganic constituents has been identified at a number of industrial sites in the Town of Wolcott, Connecticut. Contamination is also present at a municipal landfill in the City of Waterbury that is upgradient from the industrial sites in the local ground-water-flow system. The study area, which lies in the Western Highlands of Connecticut, is in the Mad River Valley, a tributary to the Naugatuck River. Geohydrologic units (aquifer materials) include unconsolidated glacial sediments (surficial materials) and fractured crystalline (metamorphic) bedrock. Surficial materials include glacial till, coarse-grained andfine-grained glacial stratified deposits, and postglacial floodplain alluvium and swamp deposits. The ground-water-flow system in the surficial aquifer is complex because the hydraulic properties of the surficial materials are highly variable. In the bedrock aquifer, ground water moves exclusively through fractures. Hydrologic characteristics of the crystalline bedrock-degree of confinement, hydraulic conductivity, storativity, and porosity-are poorly defined in the study area. Further study is needed to adequately assess ground-water flow and contaminant migration under current or past hydrologic conditions. All known water-supply wells in the study area obtain water from the bedrock aquifer. Twenty households in a hillside residential area on Tosun Road currently obtain drinking water from private wells tapping the bedrock aquifer. The extent of contamination in the bedrock aquifer and the potential for future contamination from known sources of contamination in the surficial aquifer is of concern to regulatory agencies. Previous investigations have identified ground-water contamination by volatile organic compounds at the Nutmeg Valley Road site area. Contamination has been associated with on-site disposal of heavy metals, chlorinated and non-chlorinated volatile organic compounds, and cyanide. Concentrations of volatile organic compounds detected in water samples collected from bedrock wells during 1981-95 at the Nutmeg Valley Road site area show a general downward trend through time. Water samples collected from wells completed in surficial materials were not collected systematically, and a trend in concentration cannot be identified.

Effect of Microstructure on the Radioluminescence and Transparency of Ce-Doped Strontium Hafnate Ceramics

PubMed Central

van Loef, Edgar V.; Wang, Yimin; Miller, Stuart R.; Brecher, Charles; Rhodes, William H.; Baldoni, Gary; Topping, Stephen; Lingertat, Helmut; Sarin, Vinod K.; Shah, Kanai S.

2011-01-01

In this paper we report on the fabrication and characterization of SrHfO3:Ce ceramics. Powders were prepared by solid-state synthesis using metal oxides and carbonates. X-ray diffraction measurements showed that phase-pure SrHfO3 is formed at 1200°C. Inductively coupled plasma spectroscopy confirmed the purity and composition of each batch. SrHfO3 exhibits several phase changes in the solid, but this does not appear to be detrimental to the ceramics. Microprobe experiments showed uniform elemental grain composition, whereas aluminum added as charge compensation for trivalent cerium congregated at grain boundaries and triple points. Radioluminescence spectra revealed that the light yield decreases when the concentration of excess Sr increases. The decrease in the light yield may be related to the change of Ce3+ into Ce4+ ions. For stoichiometric SrHfO3:Ce, the light yield is about four times that of bismuth germanate (BGO), the conventional benchmark, indicating great potential for many scintillator applications. PMID:21339835

DOE Office of Scientific and Technical Information (OSTI.GOV)

Yamaoka, Kazutaka; Yoshida, Atsumasa; Kotani, Taro

The CALET mission is a Japanese-led effort involving candidate experiments on the International Space Station, planned for launch in 2013. The CALET main detector is a pair conversion telescope which is dedicated to observing high energy electrons and gamma-rays in the GeV-TeV range. CALET can observe gamma-ray bursts over an unprecedented 9 decade energy range from {approx}keV to {approx}TeV with a combination of a gamma-ray burst monitor (GBM) with low energy coverage. GBM is now designed as multiple scintillators made of BGO and LaBr{sub 3}(Ce) scintillators. The prototype LaBr{sub 3}(Ce) crystal with 3 inch diameter and 0.5 inch thickness displaysmore » a very good performance: 2.9{+-}0.1% FWHM energy resolution at 662 keV and 4 keV lower energy threshold. Furthermore, degradations in performance by the anticipated proton irradiation in the orbit are not significant. Results on proton-induced background are also presented.« less

The ATIC Experiment: First Balloon Flight

NASA Technical Reports Server (NTRS)

Wefel, J. P.; Adams, J. H.; Ahn, H.; Ampe, J.; Bashindzhagyan, G.; Case, G.; Whitaker, Ann F. (Technical Monitor)

2001-01-01

The Advanced Thin Ionization Calorimeter (ATIC) Balloon Experiment had its maiden test flight from McMurdo, Antarctica 28/12/00 to 13/01/01, local time, recording over 360 hours of data. ATIC was designed to measure the composition and energy spectra of cosmic rays from approx. 10 GeV to near 100 TeV utilizing a Si matrix detector to determine charge in conjunction with a scintillator hodoscope which measures charge and trajectory. Cosmic rays that interact in a carbon target have their energy determined from the shower that develops within a fully active calorimeter composed of a stack of scintillating BGO (Bismuth Germanate) crystals. ATIC's geometry factor is about 0.25 sq. m -sr. During line-of-sight operations much of the datastream was transmitted to the ground. For most of the flight, the data was recorded on-board, yielding 45 GB of flight data for analysis. The payload construction, operations and in-flight performance are described, along with preliminary results from the on-going analysis.

Comparison of Measured and Simulated Albedo Signals in the ATIC Experiment

NASA Technical Reports Server (NTRS)

Zatsepin, V. I.; Adams, J. H.; Ahn, H. S.; Bashindzhagyan, G. L.; Batkov, K. E.; Chang, J.; Christl, M.; Fazely, A. R.; Ganel, O.; Gunasingha, R. M.

2003-01-01

Albedo, radiation backscattered from an interaction and from the subsequent shower development, provides a 'background' for calorimeter experiments. In ATIC (Advanced Thin Ionization Calorimeter), a balloon borne instrument to measure cosmic ray composition and energy spectra for elements from hydrogen to iron from 30 GeV to near 100 TeV, a fully active BGO calorimeter follows a carbon interaction target and scintillator holdoscopes. The first detector is a silicon matrix constructed of 4480 individual silicon pixels, each 2 cm x 1.5 cm, that provide a measurement of the charge of the primary particle in the presence of albedo. ATIC had two successful balloon flights in Antarctica: from 28 Dec 2000 to 13 Jan 2001 (ATIC-1) and from 29 Dec 2002 to 18 Jan 2003 (ATIC-2). A comparison of albedo signals in the silicon matri:x in ATIC-1 experiment with simulations performed using the GEANT 3.21 code and the QGSM event generator for nucleus-nucleus interactions is presented.

The ATIC Experiment: First Balloon Flight

NASA Technical Reports Server (NTRS)

Wefel, J. P.; Whitaker, Ann F. (Technical Monitor)

2001-01-01

The Advanced Thin Ionization Calorimeter (ATIC) Balloon Experiment had its maiden, test, flight from McMurdo, Antarctica 28/12/00 to 13/01/01, local time, recording over 360 hours of data. ATIC was designed to measure the composition and energy spectra of cosmic rays from approximately 10 GeV to near 100 TeV utilizing a Si-matrix detector to determine charge in conjunction with a scintillator hodoscope which measures charge and trajectory. Cosmic rays that interact in a Carbon target have their energy determined from the shower that develops within a fully active calorimeter composed of a stack of scintillating BGO crystals. ATIC's geometry factor is about 0.25 m**2-sr. During line-of-sight operations much of the datastream was transmitted to the ground. For most of the flight, the data was recorded on-board, yielding 45 GB of flight data for analysis. The payload construction, operations and in-flight performance are described, along with preliminary results from the on-going analysis.

Terrestrial Gamma-Ray Flashes (TGFs) Observed with the Fermi-Gamma-Ray Burst Monitor: The First Hundred TGFs

NASA Technical Reports Server (NTRS)

Fishman, G J.; Briggs, M. S.; Connaughton, V.; Bhat, P. N.

2010-01-01

The Gamma-ray Burst Monitor (GBM) on the Fermi Gamma-ray Space Telescope Observatory (Fermi) is now detecting 2.1 TGFs per week. At this rate, nearly a hundred TGFs will have been detected by the time of this Meeting. This rate has increased by a factor of 8 since new flight software was uploaded to the spacecraft in November 2009 in order to increase the sensitivity of GBM to TGFs. The high time resolution (2 microseconds) allows temporal features to be resolved so that some insight may be gained on the origin and transport of the gamma-ray photons through the atmosphere. The absolute time of the TGFs, known to several microseconds, also allows accurate correlations of TGFs with lightning networks and other lightning-related phenomena. The thick bismuth germanate (BGO) scintillation detectors of the GBM system have observed photon energies from TGFs at energies above 40 MeV. New results on the some temporal aspects of TGFs will be presented.

All-Sky Earth Occultation Observations with the Fermi Gamma Ray Burst Monitor

NASA Technical Reports Server (NTRS)

Wilson-Hodge, C. A.; Beklen, E.; Bhat, P. N.; Briggs, M.; Camero-Arranz, A.; Case, G.; Chaplin, V.; Cherry, M.; Connaughton, V.; Finger, M.;

All-Sky Monitoring of Variable Sources with Fermi GBM

NASA Technical Reports Server (NTRS)

Wilson-Hodge, Colleen A.; Finger, Mark; Camero-Arranz, Ascension; Becklen, Elif; Jenke, Peter; Cpe. K/ K/; Steele, Iain; Case, Gary; Cherry, Mike; Rodi, James;

Study of the {sup 15}N(p,gamma){sup 16}O Reaction at LUNA with a Solid Target

DOE Office of Scientific and Technical Information (OSTI.GOV)

Capogrosso, Valentina

2010-03-01

The case of the most recent measurement performed at LUNA, the {sup 15}N(p,gamma){sup 16}O reaction, is presented. This reaction, together with the {sup 15}N(p,alpha){sup 12}C, forms the branching point from the first to the second CNO cycle and the ratio of their respective reaction rates influences the nucleosynthesis yields of {sup 16}O, {sup 17}O e {sup 17}F. In particular, one of the three different campaigns performed by the LUNA collaboration to measure the cross section of this reaction will be discussed. This experiment was performed by impinging a proton beam from the LUNA accelerator with energies ranging from 77 tomore » 350 keV in the centre-of-mass reference frame on a TiN solid target, enriched in {sup 15}N to 98%. The gamma-rays following the (p, gamma) reaction were detected by means of an high-efficiency BGO detector.« less

Suzaku Wide-band All-sky Monitor (WAM) observations of GRBs and SGRs

NASA Astrophysics Data System (ADS)

Yamaoka, Kazutaka; Ohno, Masanori; Tashiro, Makoto S.; Hurley, Kevin; Krimm, Hans A.; Lien, Amy Y.; Ohmori, Norisuke; Sugita, Satoshi; Urata, Yuji; Yasuda, Tetsuya; Enomoto, Junichi; Fujinuma, Takeshi; Fukazawa, Yasushi; Hanabata, Yoshitaka; Iwakiri, Wataru; Kawano, Takafumi; Kinoshita, Ryuuji; Kokubun, Motohide; Makishima, Kazuo; Matsuoka, Shunsuke; Nagayoshi, Tsutomu; Nakagawa, Yujin; Nakaya, Souhei; Nakazawa, Kazuhiro; Nishioka, Yusuke; Sakamoto, Takanori; Takahashi, Tadayuki; Takeda, Sawako; Terada, Yukikatsu; Yabe, Seiya; Yamauchi, Makoto; Yoshida, Hiraku

2017-06-01

We will review results for gamma-ray bursts (GRBs) and soft gamma repeaters (SGRs), obtained from the Suzaku Wide-band All-sky Monitor (WAM) which operated for about 10 years from 2005 to 2015. The WAM is a BGO (bismuth germanate: Bi4Ge3O12) lateral shield for the Hard X-ray Detector (HXD), used mainly for rejecting its detector background, but it also works as an all-sky monitor for soft gamma-ray transients in the 50-5000 keV range thanks to its large effective area (˜600 cm2 at 1 MeV for one detector) and wide field of view (about half of the entire sky). The WAM actually detected more than 1400 GRBs and 300 bursts from SGRs, and this detection number is comparable to that of other GRB-specific instruments. Based on the 10 years of operation, we describe timing and spectral performance for short GRBs, weak GRBs with high redshifts, and time-resolved pulses with good statistics.

Geochemical processes in a calcareous sandstone aquifer during managed aquifer recharge with desalinated seawater

NASA Astrophysics Data System (ADS)

Ganot, Yonatan; Russak, Amos; Siebner, Hagar; Bernstein, Anat; Katz, Yoram; Guttman, Jospeh; Kurtzman, Daniel

2017-04-01

In the last three years we monitor Managed Aquifer Recharge (MAR) of post-treated desalinated seawater (PTDES) in an infiltration pond, at the Menashe site that overlies the northern part of the Israeli Coastal Aquifer. The PTDES are stabilized with CaCO3 during post-treatment in the desalination plant and their chemical composition differs from those of any other water recharged to the aquifer and of the natural groundwater. We use suction cups in the unsaturated zone, shallow observation wells within the pond and production wells that encircles the MAR Menashe site, to study the geochemical processes during MAR with PTDES. Ion-enrichment (remineralization) of the recharged water was observed in both unsaturated zone and shallow observation wells samples. Enrichment occurs mainly in the first few meters below the pond surface by ion-exchange processes. Mg2+ enrichment is most prominent due to its deficiency in the PTDES. It is explained by ion-exchange with Ca2+, as the PTDES (enriched with Ca2+) infiltrates through a calcareous-sandstone aquifer with various amount of adsorbed Mg2+ (3-27 meq/kg). Hence, the higher concentration of Ca+2 in the PTDES together with its higher affinity to the sediments promotes the release of Mg2+ ions to the recharged water. Water isotopes analysis of the production wells were used to estimate residence time and mixing with local groundwater. At the end of 2016, it was found that the percentage of PTDES in adjacent down-gradient production wells was around 10%, while more distant or up-gradient wells show no mixing with PTDES. The distinct isotope contrast between the recharged desalinated seawater (δ2H=+11.2±0.2‰) and the local groundwater (δ2H ranged from -22.7 to -16.7‰) is a promising tool to evaluate future mixing processes at the Menshae MAR site. Using the Menashe MAR system for remineralization could be beneficial as a primary or complementary post-treatment technique. However, the sustainability of this process is still questionable, as the recharged water remineralization is accompanied by mineral depletion of the pond sediments. Study on the feasibility of this remineralization scheme is currently ongoing using laboratory column experiments and reactive transport modelling.

Subsurface occurrence and potential source areas of chlorinated ethenes identified using concentrations and concentration ratios, Air Force Plant 4 and Naval Air Station-Joint Reserve Base Carswell Field, Fort Worth, Texas

USGS Publications Warehouse

Garcia, C. Amanda

2005-01-01

The U.S. Geological Survey, in cooperation with the U.S. Air Force Aeronautical Systems Center, Environmental Management Directorate, conducted a study during 2003-05 to characterize the subsurface occurrence and identify potential source areas of the volatile organic compounds classified as chlorinated ethenes at U.S. Air Force Plant 4 (AFP4) and adjacent Naval Air Station-Joint Reserve Base Carswell Field (NAS-JRB) at Fort Worth, Texas. The solubilized chlorinated ethenes detected in the alluvial aquifer originated as either released solvents (tetrachloroethene [PCE], trichloroethene [TCE], and trans-1,2-dichloroethene [trans-DCE]) or degradation products of the released solvents (TCE, cis-1,2-dichloroethene [cis-DCE], and trans-DCE). The combined influences of topographic- and bedrock-surface configurations result in a water table that generally slopes away from a ground-water divide approximately coincident with bedrock highs and the 1-mile-long aircraft assembly building at AFP4. Highest TCE concentrations (10,000 to 920,000 micrograms per liter) occur near Building 181, west of Building 12, and at landfill 3. Highest PCE concentrations (500 to 920 micrograms per liter) occur near Buildings 4 and 5. Highest cis-DCE concentrations (5,000 to 710,000 micrograms per liter) occur at landfill 3. Highest trans-DCE concentrations (1,000 to 1,700 micrograms per liter) occur just south of Building 181 and at landfill 3. Ratios of parent-compound to daughter-product concentrations that increase in relatively short distances (tens to 100s of feet) along downgradient ground-water flow paths can indicate a contributing source in the vicinity of the increase. Largest increases in ratio of PCE to TCE concentrations are three orders of magnitude from 0.01 to 2.7 and 7.1 between nearby wells in the northeastern part of NAS-JRB. In the northern part of NAS-JRB, the largest increases in TCE to total DCE concentration ratios relative to ratios at upgradient wells are from 17 to 240 or from 17 to 260. In the southern part of NAS-JRB, the largest ratio increases with respect to those at upgradient wells are from 22 and 24 to 130, and from 0 and 7.2 to 71. Numerous maximum historical ratios of trans-DCE to cis-DCE are greater than 1, which can indicate that trans-DCE likely was released as a solvent and does not occur only as a result of degradation of TCE. High concentrations of TCE, PCE, cis-DCE, and trans-DCE, abrupt increases in ratios of PCE to TCE and TCE to total DCE, and ratios of trans-DCE to cis-DCE greater than 1 were used to identify 16 potential source areas of chlorinated ethenes at NAS-JRB. The evidence for some of the potential source areas is stronger than for others, but each area reflects one or more of the conditions indicative of chlorinated ethenes entering the aquifer. Potential source areas supported by the strongest evidence are Building 181, between buildings 4 and 5, just west of Building 12, and landfills 1 and 3. The highest historical TCE concentration in the study area, 920,000 micrograms per liter, is near Building 181. The potential source area between Buildings 4 and 5 primarily is identified by notably high PCE concentrations (to 920 micrograms per liter). Primary evidence for the potential source are just west of Building 12 is the notably high TCE concentrations (for example, 160,000 micrograms per liter) that appear to originate in the area. Primary evidence for the potential source area at landfills 1 and (primarily) 3 is the magnitudes of TCE concentrations (for example, two in the 100,000-to-920,000-microgram-per-liter range), cis-DCE concentrations (several in the 5,000-to-710,000-microgram-per-liter range), and trans-DCE concentrations (several in the 500-to-1,700-microgram-per-liter range). The ratio of trans-DCE to cis-DCE at one well in landfill 3 (6.7) is appreciably above the threshold that can indicate likely solvent release as opposed to TCE degradation alone.

DAMPE: A gamma and cosmic ray observatory in space

NASA Astrophysics Data System (ADS)

D'Urso, D.; Dampe Collaboration

2017-05-01

DAMPE (DArk Matter Particle Explorer) is one of the five satellite missions in the framework of the Strategic Pioneer Research Program in Space Science of the Chinese Academy of Sciences (CAS). Launched on December 17th 2015 at 08:12 Beijing time, it is taking data into a sun-synchronous orbit, at the altitude of 500km. The main scientific objective of DAMPE is to detect electrons and photons in the range 5GeV-10TeV with unprecedented energy resolution, in order to identify possible Dark Matter signatures. It will also measure the flux of nuclei up to 100TeV with excellent energy resolution. The satellite is equipped with a powerful space telescope for high energy gamma-ray, electron and cosmic rays detection. It consists of a plastic scintillator strips detector (PSD) that serves as anti-coincidence detector, a silicon-tungsten tracker (STK), a BGO imaging calorimeter of about 32 radiation lengths, and a neutron detector. With its excellent photon detection capability and its detector performances (at 100GeV energy resolution ˜1% , angular resolution ˜0.1° , the DAMPE mission is well placed to make strong contributions to high-energy gamma-ray observations: it covers the gap between space and ground observation; it will allow to detect a line signature in the gamma-ray spectrum, if present, in the sub-TeV to TeV region; it will allow a high precision gamma-ray astronomy. A report on the mission goals and status will be discussed, together with in-orbit first data coming from space.

Activity-based costing evaluation of a [(18)F]-fludeoxyglucose positron emission tomography study.

PubMed

Krug, Bruno; Van Zanten, Annie; Pirson, Anne-Sophie; Crott, Ralph; Borght, Thierry Vander

2009-10-01

The aim of the study is to use the activity-based costing approach to give a better insight in the actual cost structure of a positron emission tomography procedure (FDG-PET) by defining the constituting components and by simulating the impact of possible resource or practice changes. The cost data were obtained from the hospital administration, personnel and vendor interviews as well as from structured questionnaires. A process map separates the process in 16 patient- and non-patient-related activities, to which the detailed cost data are related. One-way sensitivity analyses shows to which degree of uncertainty the different parameters affect the individual cost and evaluate the impact of possible resource or practice changes like the acquisition of a hybrid PET/CT device, the patient throughput or the sales price of a 370MBq (18)F-FDG patient dose. The PET centre spends 73% of time in clinical activities and the resting time after injection of the tracer (42%) is the single largest departmental cost element. The tracer cost and the operational time have the most influence on cost per procedure. The analysis shows a total cost per FDG-PET ranging from 859 Euro for a BGO PET camera to 1142 Euro for a 16 slices PET-CT system, with a distribution of the resource costs in decreasing order: materials (44%), equipment (24%), wage (16%), space (6%) and hospital overhead (10%). The cost of FDG-PET is mainly influenced by the cost of the radiopharmaceutical. Therefore, the latter rather than the operational time should be reduced in order to improve its cost-effectiveness.

Quality and sources of shallow ground water in areas of recent residential development in Salt Lake Valley, Salt Lake County, Utah

USGS Publications Warehouse

Thiros, Susan A.

2003-01-01

Residential and commercial development of about 80 square miles that primarily replaced undeveloped and agricultural areas occurred in Salt Lake Valley, Utah, from 1963 to 1994. This study evaluates the occurrence and distribution of natural and anthropogenic compounds in shallow ground water underlying recently developed (post 1963) residential and commercial areas. Monitoring wells from 23 to 153 feet deep were installed at 30 sites. Water-quality data for the monitoring wells consist of analyses of field parameters, major ions, trace elements, nutrients, dissolved organic carbon, pesticides, and volatile organic compounds.Dissolved-solids concentration ranged from 134 to 2,910 milligrams per liter (mg/L) in water from the 30 monitoring wells. Dissolved arsenic concentration in water from 12 wells exceeded the drinking-water maximum contaminant level of 10 micrograms per liter. Water from monitoring wells in the northwestern part of the valley generally contained higher arsenic concentrations than did water from other areas. Nitrate concentration in water sampled from 26 of the 30 monitoring wells (86.7 percent) was higher than a background level of 2 mg/L, indicating a possible human influence. Nitrate concentrations ranged from less than 0.05 to 13.3 mg/L.Fifteen of the 104 pesticides and pesticide degradation products analyzed for were detected in 1 or more water samples from the monitoring wells. No pesticides were detected at concentrations that exceeded U.S. Environmental Protection Agency drinking-water standards or guidelines for 2002. The high detection frequency of atrazine, a restricted-use pesticide, in residential areas on the west side of Salt Lake Valley may be the result of application in agricultural or industrial areas that have been converted to residential uses or application in areas upgradient from the residential areas that was then transported by ground water.Fifteen of the 86 volatile organic compounds analyzed for were detected in 1 or more water samples from the monitoring wells. The most frequently detected volatile organic compounds were chloroform (90 percent), bromodichloromethane (56.7 percent), tetrachloroethylene (53.3 percent), and 1,1,1-trichloroethane (50 percent). The widespread occurrence of chloroform and bromodichloromethane in shallow ground water is likely a result of the recharge of chlorinated public-supply water used to irrigate lawns and gardens in residential areas of Salt Lake Valley. Tetrachloroethylene (PCE), primarily used as a dry cleaning agent and solvent, was detected in water from 16 wells.

Review of cost versus scale: water and wastewater treatment and reuse processes.

PubMed

Guo, Tianjiao; Englehardt, James; Wu, Tingting

2014-01-01

The US National Research Council recently recommended direct potable water reuse (DPR), or potable water reuse without environmental buffer, for consideration to address US water demand. However, conveyance of wastewater and water to and from centralized treatment plants consumes on average four times the energy of treatment in the USA, and centralized DPR would further require upgradient distribution of treated water. Therefore, information on the cost of unit treatment processes potentially useful for DPR versus system capacity was reviewed, converted to constant 2012 US dollars, and synthesized in this work. A logarithmic variant of the Williams Law cost function was found applicable over orders of magnitude of system capacity, for the subject processes: activated sludge, membrane bioreactor, coagulation/flocculation, reverse osmosis, ultrafiltration, peroxone and granular activated carbon. Results are demonstrated versus 10 DPR case studies. Because economies of scale found for capital equipment are counterbalanced by distribution/collection network costs, further study of the optimal scale of distributed DPR systems is suggested.

Modeling the Economic Feasibility of Large-Scale Net-Zero Water Management: A Case Study.

PubMed

Guo, Tianjiao; Englehardt, James D; Fallon, Howard J

  While municipal direct potable water reuse (DPR) has been recommended for consideration by the U.S. National Research Council, it is unclear how to size new closed-loop DPR plants, termed "net-zero water (NZW) plants", to minimize cost and energy demand assuming upgradient water distribution. Based on a recent model optimizing the economics of plant scale for generalized conditions, the authors evaluated the feasibility and optimal scale of NZW plants for treatment capacity expansion in Miami-Dade County, Florida. Local data on population distribution and topography were input to compare projected costs for NZW vs the current plan. Total cost was minimized at a scale of 49 NZW plants for the service population of 671,823. Total unit cost for NZW systems, which mineralize chemical oxygen demand to below normal detection limits, is projected at ~$10.83 / 1000 gal, approximately 13% above the current plan and less than rates reported for several significant U.S. cities.

Anomalous thermodynamics at the microscale.

PubMed

Celani, Antonio; Bo, Stefano; Eichhorn, Ralf; Aurell, Erik

2012-12-28

Particle motion at the microscale is an incessant tug-of-war between thermal fluctuations and applied forces on one side and the strong resistance exerted by fluid viscosity on the other. Friction is so strong that completely neglecting inertia--the overdamped approximation--gives an excellent effective description of the actual particle mechanics. In sharp contrast to this result, here we show that the overdamped approximation dramatically fails when thermodynamic quantities such as the entropy production in the environment are considered, in the presence of temperature gradients. In the limit of vanishingly small, yet finite, inertia, we find that the entropy production is dominated by a contribution that is anomalous, i.e., has no counterpart in the overdamped approximation. This phenomenon, which we call an entropic anomaly, is due to a symmetry breaking that occurs when moving to the small, finite inertia limit. Anomalous entropy production is traced back to futile phase-space cyclic trajectories displaying a fast downgradient sweep followed by a slow upgradient return to the original position.

Near-surface coherent structures explored by large eddy simulation of entire tropical cyclones.

PubMed

Ito, Junshi; Oizumi, Tsutao; Niino, Hiroshi

2017-06-19

Taking advantage of the huge computational power of a massive parallel supercomputer (K-supercomputer), this study conducts large eddy simulations of entire tropical cyclones by employing a numerical weather prediction model, and explores near-surface coherent structures. The maximum of the near-surface wind changes little from that simulated based on coarse-resolution runs. Three kinds of coherent structures appeared inside the boundary layer. The first is a Type-A roll, which is caused by an inflection-point instability of the radial flow and prevails outside the radius of maximum wind. The second is a Type-B roll that also appears to be caused by an inflection-point instability but of both radial and tangential winds. Its roll axis is almost orthogonal to the Type-A roll. The third is a Type-C roll, which occurs inside the radius of maximum wind and only near the surface. It transports horizontal momentum in an up-gradient sense and causes the largest gusts.

Hydrogeology and water chemistry of Infranz catchment springs, Bahir Dar Area, Lake Tana Basin, Ethiopia

NASA Astrophysics Data System (ADS)

Abera, F. N.

2017-12-01

The major springs in the Infranz catchment are a significant source of water for Bahir city and nearby villages, while they help to sustain Infranz River and the downstream wetlands. The aim of the research was to understand the hydrogeological conditions of these high-discharge springs, and to explain the hydrochemical composition of spring waters. Water samples from rainwater and springs were collected and analyzed and compared for major cations and anions. The hydrochemical data analysis showed that all water samples of the springs have freshwater chemistry, Ca-HCO3 type, while deep groundwater shows more evolved types. This indicates limited water-rock interaction and short residence time for the spring waters. The rise of NO3- and PO43- may indicate future water quality degradation unless the anthropogenic activities upgradient and nearby are restricted. The uptake of 75% of spring water for water supply of Bahir Dar results in wetland degradation. Key words: Spring water, Infranz River, Bahir Dar, Ethiopia, hydrochemistry

Anomalous Thermodynamics at the Microscale

NASA Astrophysics Data System (ADS)

Celani, Antonio; Bo, Stefano; Eichhorn, Ralf; Aurell, Erik

2012-12-01

Particle motion at the microscale is an incessant tug-of-war between thermal fluctuations and applied forces on one side and the strong resistance exerted by fluid viscosity on the other. Friction is so strong that completely neglecting inertia—the overdamped approximation—gives an excellent effective description of the actual particle mechanics. In sharp contrast to this result, here we show that the overdamped approximation dramatically fails when thermodynamic quantities such as the entropy production in the environment are considered, in the presence of temperature gradients. In the limit of vanishingly small, yet finite, inertia, we find that the entropy production is dominated by a contribution that is anomalous, i.e., has no counterpart in the overdamped approximation. This phenomenon, which we call an entropic anomaly, is due to a symmetry breaking that occurs when moving to the small, finite inertia limit. Anomalous entropy production is traced back to futile phase-space cyclic trajectories displaying a fast downgradient sweep followed by a slow upgradient return to the original position.

Treatment of Chlorinated Solvents in Groundwater Beneath an Occupied Building at the Young-Rainey STAR Center, Pinellas, FL

DOE Office of Scientific and Technical Information (OSTI.GOV)

Daniel, Joe; Surovchak, Scott; Tabor, Charles

Groundwater contamination, consisting of two dissolved-phase plumes originating from chlorinated solvent source areas, in the southeastern portion of the Young- Rainey Star Center (also known as the Pinellas County, Florida, Site) in Largo, Florida, has migrated beyond the property boundary, beneath the roadways, and beneath adjacent properties to the south and east. Groundwater contamination will persist as long as the onsite contaminant source remains. The origin of the contamination appears to be multiple long-term point sources beneath Building 100, a 4.5 ha (11 acre) building that housed manufacturing facilities during US DOE operations at the site. The site is nowmore » owned by Pinellas County, and most of the space inside the building is leased to private companies, so DOE chose not to conduct characterization or remediation through the floor of the building, instead choosing to conduct all work from outside the building. Injection of emulsified soybean oil and a microbial culture has been used at other areas of the site to accelerate naturally occurring bacterial processes that degrade groundwater contaminants to harmless compounds, and that same approach was chosen for this task. The technical approach consisted of installing horizontal wells from outside the building footprint, extending through and around the identified subsurface treatment areas, and terminating beneath the building. Two 107 m (350 ft) long wells, two 122 m (400 ft) long wells, and four 137 m (450 ft) long wells have been installed to intersect the inferred source areas and confirmed contaminant plumes beneath the building. DOE then injected emulsified vegetable oil and a microbial culture into the horizontal wells at each of several target areas beneath the building where the highest groundwater contaminant concentrations have been detected. The target areas are the northwest corner of the building between the old drum storage pad locations and monitoring well PIN12-S35B, the vicinity of former monitoring well PIN12-S57B, and hydraulically upgradient from the south plume and the east plume at the points where they exit from beneath the building. We describe the details of designing and constructing horizontal injection wells for bioremediation beneath a large, occupied industrial production facility, including lessons learned; technical, logistical, and environmental challenges; community relations; and regulatory relations. Because of the expected lag in biological acclimation and response, distance between the treatment areas and associated monitoring points, and low groundwater velocity, it will likely be years before the full impact of the project will be realized.« less

Geochemical processes in ground water resulting from surface mining of coal at the Big Sky and West Decker Mine areas, southeastern Montana

USGS Publications Warehouse

Clark, D.W.

1995-01-01

A potential hydrologic effect of surface mining of coal in southeastern Montana is a change in the quality of ground water. Dissolved-solids concen- trations in water in spoils aquifers generally are larger than concentrations in water in the coal aquifers they replaced; however, laboratory experiments have indicated that concentrations can decrease if ground water flows from coal-mine spoils to coal. This study was conducted to determine if decreases in concentrations occur onsite and, if so, which geochemical processes caused the decreases. Solid-phase core samples of spoils, unmined over- burden, and coal, and ground-water samples were collected from 16 observation wells at two mine areas. In the Big Sky Mine area, changes in ground- water chemistry along a flow path from an upgradient coal aquifer to a spoils aquifer probably were a result of dedolomitization. Dissolved-solids concentrations were unchanged as water flowed from a spoils aquifer to a downgradient coal aquifer. In the West Decker Mine area, dissolved-solids concentrations apparently decreased from about 4,100 to 2,100 milligrams per liter as water moved along an inferred flow path from a spoils aquifer to a downgradient coal aquifer. Geochemical models were used to analyze changes in water chemistry on the basis of results of solid-phase and aqueous geochemical characteristics. Geochemical processes postulated to result in the apparent decrease in dissolved-solids concentrations along this inferred flow path include bacterial reduction of sulfate, reverse cation exchange within the coal, and precipitation of carbonate and iron-sulfide minerals.

Geohydrology and ground-water quality at the Pueblo Depot activity landfill near Pueblo, Colorado

USGS Publications Warehouse

Watts, Kenneth R.; Ortiz, Roderick F.

1990-01-01

Groundwater samples were collected from the shallow unconfined aquifer at the Pueblo Depot Activity (Colorado) landfill and downstream from the landfill. The Pueblo Depot Activity is a U.S. Department of the Army facility in southeastern Colorado about 15 miles east of Pueblo, Colorado. The land-fill is underlain by upland alluvial terrace deposits that overlie a thick and almost impermeable shale. Saturated thickness of the aquifer generally is from 5 to 10 feet. Groundwater flow at the landfill is to the south-southeast toward the Arkansas River valley. Though not hydraulically connected to the upland terrace deposits, the alluvium underlying the Arkansas River valley may be recharged by groundwater that is discharged from seeps at the contact of the upland terrace deposits and the Pierre Shale. The water is classified as a mixed-cation mixed-anion type water that has concentrations of dissolved solids of 710 to 1,810 mg/L. Dissolved-solids concentrations increase downgradient. Chemical analysis, done to determine possible contamination of the groundwater, indicated that concentrations of trichloroethylene ranged from 5.2 to 2,900 microg/L and of trans-1,2-dichloroethylene ranged from 5 to 720 microg/L. The areal distribution of these volatile organic compounds indicate that there possibly are two sources of contamination of groundwater at the landfill, one upgradient from the landfill and the other within the landfill. Analysis of water samples from wells and seeps offsite and downgradient from the landfill did not indicate either contaminant in groundwater from the alluvial aquifer underlying the Arkansas River valley. (USGS)

317/319 Phytoremediation site monitoring report - 2009 growing season : final report.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Negri, C .N.; Benda, P. L.; Gopalakrishnan, G.

2010-02-10

In 1999, Argonne National Laboratory (Argonne) designed and installed a series of engineered plantings consisting of a vegetative cover system and approximately 800 hybrid poplars and willows rooting at various predetermined depths. The plants were installed using various methods including Applied Natural Science's TreeWell{reg_sign} system. The goal of the installation was to protect downgradient surface and groundwater by intercepting the contaminated groundwater with the tree roots, removing moisture from the upgradient soil area, reducing water infiltration, preventing soil erosion, degrading and/or transpiring the residual volatile organic compounds (VOCs), and removing tritium from the subsoil and groundwater. This report presents themore » results of the monitoring activities conducted by Argonne's Energy Systems (ES) Division in the growing season of 2009. Monitoring of the planted trees began soon after the trees were installed in 1999 and has been conducted every summer since then. As the trees grew and consolidated their growth into the contaminated soil and groundwater, their exposure to the contaminants was progressively shown through tissue sampling. During the 2009 sampling campaign, VOC concentrations found in the French Drain area were in general consistent with or slightly lower than the 2008 results. Additionally, closely repeated, stand wide analyses showed contaminant fluctuations that may indicate short-term contaminant depletion in the area of interest of roots. This data will be useful to determine short-term removal rate by the trees. As in previous years, levels in the Hydraulic Control Area were close to background levels except for a few exceptions.« less

Geochemistry and potential environmental impact of the mine tailings at Rosh Pinah, southern Namibia

NASA Astrophysics Data System (ADS)

Nejeschlebová, L.; Sracek, O.; Mihaljevič, M.; Ettler, V.; Kříbek, B.; Knésl, I.; Vaněk, A.; Penížek, V.; Dolníček, Z.; Mapani, B.

2015-05-01

Mine tailings at Rosh Pinah located in semiarid southern Namibia were investigated by the combination of mineralogical methods and leaching using water and simulated gastric solution. They are well-neutralized with leachate pH > 7 and neutralization potential ratios (NPR) up to 4. Neutralization is mainly due to abundant Mn-rich dolomite in the matrix. Concentrations of released contaminants in water leachate follow the order Zn > Pb > Cu > As. Relatively high leached concentrations of Zn and partly also of Pb are caused by their link to relatively soluble carbonates and Mn-oxyhydroxides. In contrast, As is almost immobile by binding into Fe-oxyhydroxides, which are resistant to dissolution. Barium is released by the dissolution of Ba-carbonate (norsethite) and precipitates in sulfate-rich pore water as barite. Dissolved concentrations in neutral mine drainage water collected in the southern pond are low, but when total concentrations including colloidal fraction are taken into account, more than 70% of Zn is in colloidal form. Groundwater upgradient of the mine tailings is of poor quality and there seems to be no negative impact on groundwater downgradient from mine tailings. Contaminant concentrations in simulated gastric leachates are in the order Ba > Pb > Zn > Cu > As with a maximum gastric bioaccessibility of 86.6% for Ba and a minimum of 3.3% for As. These results demonstrate that total contaminant content and toxicity in the solid phase are poor predictors of risk, and therefore mineralogical and bioavailability/bioaccessibility studies are necessary for evaluation of contaminant environmental impact.

A Metal Stable Isotope Approach to Understanding Uranium Mobility Across Roll Front Redox Boundaries

NASA Astrophysics Data System (ADS)

Brown, S. T.; Basu, A.; Christensen, J. N.; DePaolo, D. J.; Heikoop, J. M.; Reimus, P. W.; Maher, K.; Weaver, K. L.

2015-12-01

Sedimentary roll-front uranium (U) ore deposits are the principal source of U for nuclear fuel in the USA and an important part of the current all-of-the-above energy strategy. Mining of roll-front U ore in the USA is primarily by in situ alkaline oxidative dissolution of U minerals. There are significant environmental benefits to in situ mining including no mine tailings or radioactive dust, however, the long-term immobilization of U in the aquifer after the completion of mining remains uncertain. We have utilized the metal stable isotopes U, Se and Mo in groundwater from roll-front mines in Texas and Wyoming to quantify the aquifer redox conditions and predict the onset of U reduction after post mining aquifer restoration. Supporting information from the geochemistry of groundwater and aquifer sediments are used to understand the transport of U prior to and after in situ mining. Groundwater was collected across 4 mining units at the Rosita mine in the Texas coastal plain and 2 mining units at the Smith Ranch mine in the Powder River Basin, Wyoming. In general, the sampled waters are moderately reducing and ore zone wells contain the highest aqueous U concentrations. The lowest U concentrations occur in monitoring wells downgradient of the ore zone. 238U/235U is lowest in downgradient wells and is correlated with aqueous U concentrations. Rayleigh distillation models of the 238U/235U are consistent with U isotope fractionation factors of 1.0004-1.001, similar to lab-based studies. Based on these results we conclude that redox reactions continue to affect U distribution in the ore zone and downgradient regions. We also measured aqueous selenium isotope (δ82Se) and molybdenum isotope (δ98Mo) compositions in the Rosita groundwater. Se(VI) primarily occurs in the upgradient wells and is absent in most ore zone and downgradient wells. Rayleigh distillation models suggest reduction of Se(VI) along the groundwater flow path and when superimposed on the U isotope data Se reduction is favored over U reduction. The δ98Mo of Rosita groundwater is significantly elevated compared to the U ore and is negatively correlated with the groundwater Eh, which suggests localized strong reducing conditions capable of Mo reduction. Ongoing work will determine the Mo isotope systematics of U ores and groundwater from roll-front deposits.

Hydrogeology and water quality of the Clinton Street-Ballpark Aquifer near Johnson City, New York

USGS Publications Warehouse

Coon, William F.; Yager, Richard M.; Surface, Jan M.; Randall, Allan D.; Eckhardt, David A.

1998-01-01

The Clinton Street-Ballpark aquifer, in the Susquehanna River valley in southern Broome County, N.Y., supplies drinking water to the Village of Johnson City near Binghamton. The hydrogeology and water quality of the aquifer were studied in 1994-95 to identify the source area of 1,1,1-trichloroethane, which was detected at the Johnson City Camden Street wellfield in 1991.The aquifer is generally 100 to 150 ft thick and consists primarily of ice-contact deposits of silty sand and gravel that are overlain by outwash deposits of sand and gravel. These two types of deposits are separated by lacustrine silt and clay of variable thickness into an upper and a lower layer of the aquifer. The coarse deposits form a single aquifer in areas where the lacustrine deposits are absent.Synoptic water-level surveys indicated that ground water moves from upgradient areas flanking the aquifer boundaries toward two major pumping centers?the Anitec wellfield in Binghamton and the Camden Street wellfield in Johnson City. Areas contributing recharge to municipal and industrial wells in the aquifer were delineated by a previously developed groundwater- flow model. The residence time of ground water within the area contributing recharge to Johnson City well no. 2 in the Camden Street wellfield was estimated to be less than 6 years.1,1,1-Trichloroethane, trichloroethene, and their metabolites were detected in ground water at several locations in and near Johnson City. Relatively high concentrations of 1,1,1-trichloroethane were found in ground water about 3,000 ft north of the Camden Street wellfield. The suspected source is an area bordered on the south by Field Street, on the north by Harry L. Drive, on the east by New York State Route 201, and on the west by Marie Street. A trichloroethene metabolite, cis-1,2-dichloroethene, appears to be migrating westward from U.S. Air Force Plant 59 toward the Camden Street well-field, 1,000 ft southwest of the plant, although this compound has not been detected in water pumped by municipal wells, possibly because it has become diluted by ground water from other locations within the contributing area to the wells.

Use of chemical and isotopic tracers to assess nitrate contamination and ground-water age, Woodville Karst Plain, USA

USGS Publications Warehouse

Katz, B.G.; Chelette, A.R.; Pratt, T.R.

2004-01-01

Concerns regarding ground-water contamination in the Woodville Karst Plain have arisen due to a steady increase in nitrate-N concentrations (0.25-0.90 mg/l) during the past 30 years in Wakulla Springs, a large regional discharge point for water (9.6 m3/s) from the Upper Floridan aquifer (UFA). Multiple isotopic and chemical tracers were used with geochemical and lumped-parameter models (exponential mixing (EM), dispersion, and combined exponential piston flow) to assess: (1) the sources and extent of nitrate contamination of ground water and springs, and (2) mean transit times (ages) of ground water. Delta 15N-NO3 values (1.7-13.8???) indicated that nitrate in ground water originated from localized sources of inorganic fertilizer and human/animal wastes. Nitrate in spring waters (??15N-NO3=5.3-8.9???) originated from both inorganic and organic N sources. Nitrate-N concentrations (1.0 mg/l) were associated with shallow wells (open intervals less than 15 m below land surface), elevated nitrate concentrations in deeper wells are consistent with mixtures of water from shallow and deep zones in the UFA as indicated from geochemical mixing models and the distribution of mean transit times (5-90 years) estimated using lumped-parameter flow models. Ground water with mean transit times of 10 years or less tended to have higher dissolved organic carbon concentrations, lower dissolved solids, and lower calcite saturation indices than older waters, indicating mixing with nearby surface water that directly recharges the aquifer through sinkholes. Significantly higher values of pH, magnesium, dolomite saturation index, and phosphate in springs and deep water (>45 m) relative to a shallow zone (<45 m) were associated with longer ground-water transit times (50-90 years). Chemical differences with depth in the aquifer result from deep regional flow of water recharged through low permeability sediments (clays and clayey sands of the Hawthorn Formation) that overlie the UFA upgradient from the karst plain.

Effects of waste-disposal practices on ground-water quality at five poultry (broiler) farms in north-central Florida, 1992-93

USGS Publications Warehouse

Hatzell, H.H.

1995-01-01

Waste-disposal areas such as chicken-house floors, litter stockpiles, fields that receive applications of litter, and dead-chicken pits are potential sources of nitrates and other chemical constituents in downward-percolating recharge water. Broiler- farms in north-central Florida are concentrated in a region where the Upper Floridan aquifer is unconfined and susceptible to contamination. Eighteen monitoring wells installed at five sites were sampled quarterly from March 1992 through January 1993. Increases in median concentrations of constituents relative to an upgradient well were used to determine the source of the nitrate at two sites. At these sites, increases in the median concentrations of nitrate as nitrogen in ground water in the vicinity of waste-disposal areas at these sites were: 5.4 mg/L for one chicken house; 9.0 mg/L for a second chicken house; 2.0 mg/L for a fallow field that received an application of litter; and, 2.0 mg/L for a dead-chicken pit. At the three remaining sites where the direction of local ground-water flow could not be ascertained, the sources of concentrations of nitrate and other constituents could not be determined. However, median nitrate concentrations in the vicinity of waste-disposal areas at these sites were: 45.5 mg/L for a set of two chicken houses; 3.0 mg/L for a stockpile area; and 2.1 mg/L for a hayfield that received an application of litter. The nitrate concentration in ground water in the vicinity of a field that had previously received heavy applications of litter increased from 3.0 mg/L to 105 mg/L approximately 4 months after receiving an application of commercial fertilizer. Increases in concentrations of organic nitrogen in ground water in the vicinity of waste-disposal areas may be related to the decomposition of litter and subsequent movement with downward percolating recharge water.(USGS)

Fractionation of stable isotopes in perchlorate and nitrate during in situ biodegradation in a sandy aquifer

USGS Publications Warehouse

Hatzinger, P.B.; Bohlke, John Karl; Sturchio, N.C.; Gu, B.; Heraty, L.J.; Borden, R.C.

2009-01-01

An in situ experiment was performed in a shallow alluvial aquifer in Maryland to quantify the fractionation of stable isotopes in perchlorate (Cl and O) and nitrate (N and O) during biodegradation. An emulsified soybean oil substrate that was previously injected into this aquifer provided the electron donor necessary for biological perchlorate reduction and denitrification. During the field experiment, groundwater extracted from an upgradient well was pumped into an injection well located within the in situ oil barrier, and then groundwater samples were withdrawn for the next 30 h. After correction for dilution (using Br– as a conservative tracer of the injectate), perchlorate concentrations decreased by 78% and nitrate concentrations decreased by 82% during the initial 8.6 h after the injection. The observed ratio of fractionation effects of O and Cl isotopes in perchlorate (e18O/e37Cl) was 2.6, which is similar to that observed in the laboratory using pure cultures (2.5). Denitrification by indigenous bacteria fractionated O and N isotopes in nitrate at a ratio of ~0.8 (e18O/e15N), which is within the range of values reported previously for denitrification. However, the magnitudes of the individual apparent in situ isotope fractionation effects for perchlorate and nitrate were appreciably smaller than those reported in homogeneous closed systems (0.2 to 0.6 times), even after adjustment for dilution. These results indicate that (1) isotope fractionation factor ratios (e18O/e37Cl, e18O/e15N) derived from homogeneous laboratory systems (e.g. pure culture studies) can be used qualitatively to confirm the occurrence of in situ biodegradation of both perchlorate and nitrate, but (2) the magnitudes of the individual apparent e values cannot be used quantitatively to estimate the in situ extent of biodegradation of either anion.

Fractionation of stable isotopes in perchlorate and nitrate during in situ biodegradation in a sandy aquifer

DOE Office of Scientific and Technical Information (OSTI.GOV)

Hatzinger, Paul B.; Bohlke, J. K.; Sturchio, N. C.

An in situ experiment was performed in a shallow alluvial aquifer in Maryland to quantify the fractionation of stable isotopes in perchlorate (Cl and O) and nitrate (N and O) during biodegradation. An emulsified soybean oil substrate that was previously injected into this aquifer provided the electron donor necessary for biological perchlorate reduction and denitrification. During the field experiment, groundwater extracted from an upgradient well was pumped into an injection well located within the in situ oil barrier, and then groundwater samples were withdrawn for the next 30 h. After correction for dilution (using Br-as a conservative tracer of themore » injectate), perchlorate concentrations decreased by 78 % and nitrate concentrations decreased by 87 %, during the initial 8.6 h after the injection. The observed ratio of fractionation effects of O and Cl isotopes in perchlorate (ε18O/ε37Cl) was 2.6, which is similar to that observed in the laboratory using pure cultures (2.5). Denitrification by indigenous bacteria fractionated O and N isotopes in nitrate at a ratio of approximately 0.8 (ε18O/ε15N), which is within the range of values reported previously for denitrification. However, the magnitudes of the individual apparent in situ isotope fractionation effects for perchlorate and nitrate were appreciably smaller than those reported in homogeneous closed systems (0.2 to 0.6 times), even after adjustment for dilution. These results indicate that (1) isotope fractionation factor ratios (ε18O/ε37Cl, ε18O/ε15N) derived from homogeneous laboratory systems (e.g., pure culture studies) can be used qualitatively to confirm the occurrence of in situ biodegradation of both perchlorate and nitrate, but (2) the magnitudes of the individual apparent  values cannot be used quantitatively to estimate the in situ extent of biodegradation of either anion.« less

Digital-transport model study of Diisopropylmethylphosphonate (DIMP) ground-water contamination at the Rocky Mountain Arsenal, Colorado

USGS Publications Warehouse

Warner, James W.

1979-01-01

Diisopropylmethylphosphonate (DIMP) is an organic compound produced as a by-product of the manufacture and detoxification of GB nerve gas. Ground-water contamination by DIMP from the disposal of wastes into unlined surface ponds at the Rocky Mountain Arsenal occurred from 1952 to 1956. A digital-transport model was used to determine the effects on ground-water movement and on DIMP concentrations in the ground water of a bentonite barrier in the aquifer near the northern boundary of the arsenal. The transport model is based on an iterative-alternating-direction-implicit mathematical solution of the ground-water-flow equation coupled with a method-of-characteristics solution of the solute-transport equation. The model assumes conservative (nonreactive) transient transport of DIMP and steady-state ground-water flow. In the model simulations, a bentonite barrier was assumed that was impermeable and penetrated the entire saturated thickness of the aquifer. Ground water intercepted by the barrier was assumed to be pumped by wells located south (upgradient) of the barrier, to be treated to remove DIMP, and to be recharged by pits or wells to the aquifer north (downgradient) of the barrier. The amount of DIMP transported across the northern boundary of the arsenal was substantially reduced by a ground-water-barrier system of this type. For a 1,500-foot-long bentonite barrier located along the northern boundary of the arsenal near D Street, about 50 percent of the DIMP that would otherwise cross the boundary would be intercepted by the barrier. This barrier configuration and location were proposed by the U.S. Army. Of the ground water with DIMP concentrations greater than 500 micrograms per liter, the safe DIMP-concentration level determined by the U.S. Army, about 72 percent would be intercepted by the barrier system. The amount of DIMP underflow intercepted may be increased to 65 percent by doubling the pumpage, or to 73 percent by doubling the length of the barrier. (Kosco-USGS)

Evaluation of the fate and transport of chlorinated ethenes in a complex groundwater system discharging to a stream in Wonju, Korea.

PubMed

Lee, Seong-Sun; Kaown, Dugin; Lee, Kang-Kun

2015-11-01

Chlorinated ethenes such as trichloroethylene (TCE) are common and persistent groundwater contaminants. If contaminated groundwater discharges to a stream, then stream water pollution near the contamination site also becomes a problem. In this respect, the fate and transport of chlorinated ethenes around a stream in an industrial complex were evaluated using the concentration of each component, and hydrogeochemical, microbial, and compound-specific carbon isotope data. Temporal and spatial monitoring reveal that a TCE plume originating from main and local source zones continues to be discharged to a stream. Groundwater geochemical data indicate that aerobic conditions prevail in the upgradient area of the studied aquifer, whereas conditions become anaerobic in the downgradient. The TCE molar fraction is high at the main and local source zones, ranging from 87.4 to 99.2% of the total volatile organic compounds (VOCs). An increasing trend in the molar fraction of cis-1, 2-Dichloroethene (cis-DCE) and vinyl chloride (VC) was observed in the downgradient zone of the study area. The enriched δ(13)C values of TCE and depleted values of cis-DCE in the stream zone, compared to those of the source zone, also suggest biodegradation of VOCs. Microbial community structures in monitoring wells adjacent to the stream zone in the downgradient area were analyzed using 16S rRNA gene-based pyrosequencing to identify the microorganisms responsible for biodegradation. This was attributed to the high relative abundance of dechlorinating bacteria in monitoring wells under anaerobic conditions farthest from the stream in the downgradient area. The multilateral approaches adopted in this study, combining hydrogeochemical and biomolecular methods with compound-specific analyses, indicate that contaminants around the stream were naturally attenuated by active anaerobic biotransformation processes. Copyright © 2015 Elsevier B.V. All rights reserved.

Hydrology and simulation of ground-water flow in Kamas Valley, Summit County, Utah

USGS Publications Warehouse

Brooks, L.E.; Stolp, B.J.; Spangler, L.E.

2003-01-01

Kamas Valley, Utah, is located about 50 miles east of Salt Lake City and is undergoing residential development. The increasing number of wells and septic systems raised concerns of water managers and prompted this hydrologic study. About 350,000 acre-feet per year of surface water flows through Kamas Valley in the Weber River, Beaver Creek, and Provo River, which originate in the Uinta Mountains east of the study area. The ground-water system in this area consists of water in unconsolidated deposits and consolidated rock; water budgets indicate very little interaction between consolidated rock and unconsolidated deposits. Most recharge to consolidated rock occurs at higher altitudes in the mountains and discharges to streams and springs upgradient of Kamas Valley. About 38,000 acre-feet per year of water flows through the unconsolidated deposits in Kamas Valley. Most recharge is from irrigation and seepage from major streams; most discharge is to Beaver Creek in the middle part of the valley. Long-term water-level fluctuations range from about 3 to 17 feet. Seasonal fluctuations exceed 50 feet. Transmissivity varies over four orders of magnitude in both the unconsolidated deposits and consolidated rock and is typically 1,000 to 10,000 feet squared per day in unconsolidated deposits and 100 feet squared per day in consolidated rock as determined from specific capacity. Water samples collected from wells, streams, and springs had nitrate plus nitrite concentrations (as N) substantially less than 10 mg/L. Total and fecal coliform bacteria were detected in some surface-water samples and probably originate from livestock. Septic systems do not appear to be degrading water quality. A numerical ground-water flow model developed to test the conceptual understanding of the ground-water system adequately simulates water levels and flow in the unconsolidated deposits. Analyses of model fit and sensitivity were used to refine the conceptual and numerical models.

Geohydrology of, and nitrogen and chloride in, the glacial aquifer, Milford-Matamoras area, Pike County, Pennsylvania

USGS Publications Warehouse

Senior, L.A.

1994-01-01

The glacial aquifer that underlies the Routes 209 and 6 corridor between Milford and Matamoras, Pa., is one of the most productive in Pike County. The aquifer is comprised of unconsolidated glacial outwash and kame-terrace deposits that lie within a glacially carved valley now occupied by the Delaware River. Most businesses and residences along this narrow, 7-mile-long corridor rely on individual wells for water supply and septic systems for waste-water disposal. A study of nutrients and chloride in ground water in the glacial aquifer was conducted to determine the effect of these constituents contributed from septic systems and road runoff on ground-water quality. Sources of nutrients and chloride in the recharge zone upgradient of the aquifer include road and parking-lot runoff, septic systems, and precipitation. Nitrate and chloride from these sources can infiltrate and move in the direction of ground-water flow in the saturated zone of the aquifer. A water-table map based on 29 water levels measured in August 1991 indicates that the direction of ground-water flow is from the edges of the valley toward t he Delaware River but is nearly parallel to the Delaware River in the central area of the valley. The average concentrations of nitrogen and chloride in recharge and total annual loads of nitrogen and chloride to ground water were estimated for six areas with different population densities. These estimates assumed a recharge rate to the glacial aquifer of 20 inches per year and a 15 percent loss of chloride and nitrogen in the atmospheric precipitation to surface runoff. The estimated average concentration of nitrogen in recharge ranged from 2.5 to 10 mg/L (milligrams per liter), which corresponds to a total annual load of nitrogen as ammonium released from septic tanks and present in precipitation was oxidized to nitrate as the dominant nitrogen species in ground water. Contributions of nitrogen from septic tanks were greater than contributions from runoff. Observed concentrations of nitrate, which was the most abundant nitrogen species in ground water in t he glacial aquifer, ranged from less than 0.05 to 5.1 mg/L as nitrogen, with a median of 1.1 mg/L as nitrogen. Concentrations of nitrogen measured in ground water were lower than estimated concentrations for recharge suggesting that dissolved nitrogen species may not be conservative in ground water. Nitrate is unstable in anoxic ground water and can be removed by denitrification. Ammonium can be sorbed onto the aquifer materials. Evidence for reducing conditions included a positive correlation between low concentrations of dissolved oxygen and low concentrations of nitrate. The estimated concentration of chloride in recharge ranged from 6.7 to 21 mg/L, and total annual load of chloride to ground water ranged from 19.4 to 50.6 x 10(3) lb/mi2. Chloride is considered to be a chemically conservative ion in ground water. Contributions of chloride to ground water from road salting were greater than contributions from septic tanks. Observed concentrations of chloride in 18 ground-water samples from the glacial aquifer ranged from 2.1 to 32 mg/L, with a median of 17.5 mg/L. Local contamination is indicated by the elevated concentrations of chloride (up to 680 mg/L) detected in four wells located downgradient of an abandoned industry that may have released salts in processing waste. Chloride concentrations in ground water appeared to be greater near major roads and in areas of relatively greater septic-system density than in areas upgradient of roads, farther downgradient from roads, or with less densely spaced septic systems.

Hydrogeology and effects of landfills on ground-water quality, southern Franklin County, Ohio

USGS Publications Warehouse

De Roche, J.T.

1985-01-01

Hydrogeology and water quality were evaluated near five land-fills along a 5-mile segment of the Scioto River valley south of Columbus, Ohio. Heterogenous surficial deposits o sand, gravel, and till up to 160 feet thick are hydraulically connected to the underlying Devonian limestone, the landfills and Scioto River, which has been leveed with 12 to 35 feet of refuse. Ground-water withdrawals caused a maximum 21-foot decline in ground-water levels from 1979 to 1982. The study reach of Scioto River within the influence of ground-water pumping is a losing stream, except for s small segment adjacent to one landfill. Analysis of variance indicated significant difference in ground-water quality between wells upgradient of landfills, down-gradient of landfills, and wells penetrating refuse. Elevated specific conductance and concentrations of total dissolved solids, ammonia, carbon dioxide, and dissolved organic carbon in water from wells downgradient from and penetrating landfills indicate leachate production and migration is occurring. Analysis of bed-material samples from Scioto River and Scioto Big Run revealed concentrations of polynuclear aromatic hydrocarbons ranging from 220 to 9,440 micograms per kilogram of sediment (?g/kg) and concentrations of toxic metals ranging from 1 to 720 ?g/kg. Samples from an upstream control station on Scioto River contained no organic compounds and lower concentrations of metals (ranging from 1 to 260 ?g/kg). Because of multiple land uses within the study area, organic compounds recovered from the streamed sediments cannot be attributed to any single source. The generation of hydrogen sulfide and methane gases, presence of a zone of increased hardness, elevated concentrations of common ionic species, and dominance of ammonia over other nitrogen species indicate that leachate is being produced and its migrating from four landfills and the river levee. Based on hydraulic relationships between ground water and surface water, it is highly probable that ground water contaminated by leachate from the levee and from one of the landfills is discharging to Scioto River. Leachate-enriched groundwater from other landfills also may begin to discharge to the river if water-withdrawal patterns in the study area change.

Dissolved Organic Carbon 14C in Southern Nevada Groundwater and Implications for Groundwater Travel Times

DOE Office of Scientific and Technical Information (OSTI.GOV)

Hershey, Ronald L.; Fereday, Wyall; Thomas, James M

Dissolved inorganic carbon (DIC) carbon-14 ( 14C) ages must be corrected for complex chemical and physical reactions and processes that change the amount of 14C in groundwater as it flows from recharge to downgradient areas. Because of these reactions, DIC 14C can produce unrealistically old ages and long groundwater travel times that may, or may not, agree with travel times estimated by other methods. Dissolved organic carbon (DOC) 14C ages are often younger than DIC 14C ages because there are few chemical reactions or physical processes that change the amount of DOC 14C in groundwater. However, there are several issuesmore » that create uncertainty in DOC 14C groundwater ages including limited knowledge of the initial (A 0) DOC 14C in groundwater recharge and potential changes in DOC composition as water moves through an aquifer. This study examines these issues by quantifying A 0 DOC 14C in recharge areas of southern Nevada groundwater flow systems and by evaluating changes in DOC composition as water flows from recharge areas to downgradient areas. The effect of these processes on DOC 14C groundwater ages is evaluated and DOC and DIC 14C ages are then compared along several southern Nevada groundwater flow paths. Twenty-seven groundwater samples were collected from springs and wells in southern Nevada in upgradient, midgradient, and downgradient locations. DOC 14C for upgradient samples ranged from 96 to 120 percent modern carbon (pmc) with an average of 106 pmc, verifying modern DOC 14C ages in recharge areas, which decreases uncertainty in DOC 14C A 0 values, groundwater ages, and travel times. The HPLC spectra of groundwater along a flow path in the Spring Mountains show the same general pattern indicating that the DOC compound composition does not change along this flow path. Although DOC concentration decreases from recharge-area to downgradient groundwater, the organic compounds are similar, indicating that DOC 14C is unaffected by other processes such as microbial degradation. A small amount of organic carbon was leached from crushed volcanic and carbonate aquifer outcrop rock in rock-leaching experiments. The leached DOC was high in 14C (75 pmc carbonate rocks, 91 pmc volcanic) suggesting that the leached DOC likely came from microbes in the rock samples. The small amount of DOC and high 14C indicates that the amount of old organic carbon in these rocks is low so there should be minimal impact on groundwater DOC 14C ages. Based on the results from this study, DOC 14C ages do not require additional corrections. Several correction models were applied to DIC 14C ages to correct for water-rock reactions along two carbonate and two volcanic flow paths and the corresponding travel times were compare to DOC 14C travel times. The DOC 14C travel times were hundreds to thousands of years shorter than uncorrected and corrected DIC 14C travel times except for the upper section of one carbonate flow path. DOC 14C travel times ranged from 400 to 5,400 years as compared to DIC 14C that ranged from modern to 20,900 years. The DIC 14C ages are greatly influenced by carbonate mineral and gas reactions and other processes such as matrix diffusion, isotope exchange, or adsorption, which are not always adequately accounted for in DIC 14C groundwater age correction models.« less

First Year PIDDP Report on gamma-ray and x-ray spectroscopy: X-ray remote sensing and in situ spectroscopy for planetary exploration missions and gamma-ray remote sensing and in situ spectroscopy for planetary exploration missions

NASA Technical Reports Server (NTRS)

Mahdavi, M.; Giboni, K. L.; Vajda, S.; Schweitzer, J. S.; Truax, J. A.

1994-01-01

Detectors that will be used for planetary missions must have their responses calibrated in a reproducible manner. In addition, it is important to characterize a detector system at uneven portions of its life cycle, for example after exposure to different amounts of radiation. A calibration and response characterization facility has been constructed at Schlumberger-Doll Research for all types of gamma- and x-ray detectors that may be used for planetary measurement. This facility is currently being tested. Initial use is expected for the MARS 94 detectors. The facility will then also be available for calibrating other detectors as well as arrays of detectors such as the NEAR detector with its central Nal(TI) crystal surrounded with a large BGO crystal. Cadmium telluride detectors are investigated for applications in space explorations. These detectors show an energy resolution of 5 keV for the 122 keV 57Co line. Earlier reported polarization effects are not observed. The detectors can be used at temperatures up to 100 C, although with reduced energy resolution. The thickness of standard detectors is limited to 2 mm. These detectors become fully efficient at bias voltages above 200 V. Initial results for a 1 cm thick detector show that the quality of the material is inferior to the thinner standard detectors and hole trapping affects the pulse height. A detailed characterization of the detector is in progress. Prototypes of photomultipliers based on a Channel Electron Multiplier (CEM) are being built to study their performance. Such photomultipliers promise better timing characteristics and a higher dynamic range while being more compact and of lower in weight.

Improved measurement of the half-life of the J π = 8 - nuclear isomer 152m2 Eu

DOE Office of Scientific and Technical Information (OSTI.GOV)

Humby, Peter; Simon, Anna; Beausang, C. W.

2015-02-23

The standard γ-ray energy calibration source 152Eu is well known based on the 13.5 y decay of its ground state. Nevertheless, in addition to this decay 152Eu also has two relatively long-lived isomeric states: a 9 h J π=0 - state at E *=46 keV and a 96 min J π=8 - state at E *=148 keV. Here we report a new measurement of the half-lives of both of these isomeric states. Excited states in 152Eu were populated following the 154Sm (p,3n) reaction using a 25 MeV proton beam from the K-150 cyclotron at the Cyclotron Institute of Texas A&Mmore » University. Post irradiation, γ rays from the de-excitation of the long lived isomeric states were measured using the six BGO shielded high-purity germanium (HPGe) clover detectors that are part of the STARLiTeR array. The half-life of the J π=8 - isomer 152m2Eu was obtained by measuring the decrease in intensity of the 90 keV γ ray from the cascade to the ground state. The half-life of this state was measured to be 95.8(4) min which is in agreement with and significantly more precise than the previously measured value of 96(1) min. In a manner similar to the ground state the second long-lived isomer 151m1Eu, the J π=0 - state at 46 keV, β decays to excited states in 152Gd and 152Sm. Also, the half-life of this state was measured to be 9.39(7) h using five γ-ray transitions.« less

A Monte Carlo Library Least Square approach in the Neutron Inelastic-scattering and Thermal-capture Analysis (NISTA) process in bulk coal samples

NASA Astrophysics Data System (ADS)

Reyhancan, Iskender Atilla; Ebrahimi, Alborz; Çolak, Üner; Erduran, M. Nizamettin; Angin, Nergis

2017-01-01

A new Monte-Carlo Library Least Square (MCLLS) approach for treating non-linear radiation analysis problem in Neutron Inelastic-scattering and Thermal-capture Analysis (NISTA) was developed. 14 MeV neutrons were produced by a neutron generator via the 3H (2H , n) 4He reaction. The prompt gamma ray spectra from bulk samples of seven different materials were measured by a Bismuth Germanate (BGO) gamma detection system. Polyethylene was used as neutron moderator along with iron and lead as neutron and gamma ray shielding, respectively. The gamma detection system was equipped with a list mode data acquisition system which streams spectroscopy data directly to the computer, event-by-event. A GEANT4 simulation toolkit was used for generating the single-element libraries of all the elements of interest. These libraries were then used in a Linear Library Least Square (LLLS) approach with an unknown experimental sample spectrum to fit it with the calculated elemental libraries. GEANT4 simulation results were also used for the selection of the neutron shielding material.

Scintillating fiber array for tagging post-bremsstrahlung electrons

NASA Astrophysics Data System (ADS)

Cole, Philip; Alef, Stefan; Reitz, Björn-Eric; Schmieden, Hartmut; Hannappel, Jürgen; Jude, Thomas; Sandri, Paolo Levi; BGO-OD Collaboration

2016-03-01

We seek to extract the kinematic fingerprints of baryon resonances by making use of a high-quality beam of linearly polarized photons at the BGO-OD experiment at ELSA (Bonn, German). We constructed a unique device for precisely determining the degree of polarization in the coherent bremsstrahlung peak. Deflection of post-bremsstrahlung electrons in the magnetic field of the photon tagger provides precise information on the energy and polarization of the bremsstrahlung photons. And thereby will constrain the overall kinematics of the final-state particles in all decay channels of the photoproduced baryon resonances. We designed, prototyped, built, calibrated, and have been operating a three-layered, multi-stranded, scintillating-fiber detector for ensuring the quality of the linearly polarization of the photon beam. The overlapping 2.00-mm scintillating fibers form an array giving ARGUS over 500 channels. The very befitting name harkens to the mythological all-seeing creature Argus Panoptes, the multi-eyed giant. Our work was supported through a Fulbright Scholarship Award and by the Deutsche Forschungsgemeinschaft through the Collaborative Research Center (Sonderforschungsbereich SFB/TR-16) of the universities in Bonn, Giessen and Bochum, Germany. NSF-PHY-1307340.

Characterization of 176Lu background in LSO-based PET scanners

NASA Astrophysics Data System (ADS)

Conti, Maurizio; Eriksson, Lars; Rothfuss, Harold; Sjoeholm, Therese; Townsend, David; Rosenqvist, Göran; Carlier, Thomas

2017-05-01

LSO and LYSO are today the most common scintillators used in positron emission tomography. Lutetium contains traces of 176Lu, a radioactive isotope that decays β - with a cascade of γ photons in coincidence. Therefore, Lutetium-based scintillators are characterized by a small natural radiation background. In this paper, we investigate and characterize the 176Lu radiation background via experiments performed on LSO-based PET scanners. LSO background was measured at different energy windows and different time coincidence windows, and by using shields to alter the original spectrum. The effect of radiation background in particularly count-starved applications, such as 90Y imaging, is analysed and discussed. Depending on the size of the PET scanner, between 500 and 1000 total random counts per second and between 3 and 5 total true coincidences per second were measured in standard coincidence mode. The LSO background counts in a Siemens mCT in the standard PET energy and time windows are in general negligible in terms of trues, and are comparable to that measured in a BGO scanner of similar size.

New Results from the DREAM project

NASA Astrophysics Data System (ADS)

Meoni, E.; Dream Collaboration

2011-06-01

Dual-Readout calorimetry is a promising new technique for high precision measurements of hadronic showers and jets. The DREAM Collaboration is exploiting the possibilities offered by this technique, a key aspect of which is the simultaneous measurement of the scintillation light and the Cerenkov light generated in the shower development process. By comparing these two signals, the electromagnetic shower fraction can be measured event by event, eliminating the effects of its fluctuations, that are the dominant contribution to the hadronic energy resolution. In the first detector of this type the two signals were provided by two independent active media: scintillating fibers and quartz fibers. In follow-up studies, we have explored the possibilities of heavy crystals such as BGO and PbWO4. The use of homogeneous detectors has the advantage that it eliminates the effects of fluctuations that limit the resolution of the fiber calorimeter: sampling fluctuations and quantum fluctuations in the Cerenkov signals. A very important tool turnes out to be a detailed measurement of the time structure of the signals. In this paper, the latest results of this project will be presented.

Systematic study of proton capture reactions in medium-mass nuclei relevant to the p process: The case of 103Rh and In,115113

NASA Astrophysics Data System (ADS)

Harissopulos, S.; Spyrou, A.; Foteinou, V.; Axiotis, M.; Provatas, G.; Demetriou, P.

2016-02-01

The cross sections of the 103Rh(p ,γ )104Pd and the In,115113(p ,γ )Sn,116114 reactions have been determined from γ angular distribution measurements carried out at beam energies from 2 to 3.5 MeV. An array of four highly efficient HPGe detectors all shielded with BGO crystals for Compton background suppression was used. Astrophysical S factors and reaction rates were deduced from the measured cross sections. Statistical model calculations were performed using the Hauser-Feshbach (HF) code TALYS and were compared with the new data. A good agreement between theory and experiment was found. In addition, the effect of different combinations of the nuclear input parameters entering the HF calculations on the ground-state reaction rates was investigated. It was found that these rates differ by a factor 3 at the most, being thus within the average discrepancies observed between calculated p -nuclei abundances and observations, if certain combinations of optical model potentials, nuclear level densities, and γ -ray strength functions are used.

Terrestrial Gamma-ray Flashes (TGFs) Observed with the Fermi-Gamma-ray Burst Monitor: Temporal and Spectral Properties

NASA Technical Reports Server (NTRS)

Fishman, G. J.; Briggs, M. S.; Connaughton, W.; Wilson-Hodge, C.; Bhat, P. N.

2010-01-01

The Gamma-ray Burst Monitor (GBM) on the Fermi Gamma-ray Space Telescope Observatory (Fermi) was detecting 2.1 TGFs per week. This rate has increased by a factor of 8 since new flight software was uploaded to the spacecraft in November 2009 in order to increase the sensitivity of GBM to TGFs. Further upgrades to Fermi-GBM to allow observations of weaker TGFs are in progress. The high time resolution (2 s) allows temporal features to be resolved so that some insight may be gained on the origin and transport of the gamma-ray photons through the atmosphere. The absolute time of the TGFs, known to several microseconds, also allows accurate correlations of TGFs with lightning networks and other lightning-related phenomena. The thick bismuth germanate (BGO) scintillation detectors of the GBM system have observed photon energies from TGFs at energies above 40 MeV. New results on the some temporal aspects of TGFs will be presented along with spectral characteristics and properties of several electron-positron TGF events that have been identified.

A new gamma ray imaging diagnostic for runaway electron studies at DIII-D

NASA Astrophysics Data System (ADS)

Cooper, C. M.; Pace, D. C.; Eidietis, N. W.; Paz-Soldan, C.; Commaux, N.; Shiraki, D.; Hollmann, E. M.; Moyer, R. A.; Risov, V.

2015-11-01

A new Gamma Ray Imager (GRI) is developed to probe the electron distribution function with 2D spatial resolution during runaway electron (RE) experiments at DIII-D. The diagnostic is sensitive to 0.5 - 50 MeV gamma rays, allowing characterization of the RE distribution function evolution during RE dissipation from pellet injection. The GRI consists of a lead ``pinhole camera'' mounted on the midplane with 11x11 counter-current tangential chords 20 cm wide that span the vessel. Up to 30 bismuth germanate (BGO) scintillation detectors capture RE Bremsstrahlung radiation. Detectors operate in current saturation mode at 10 MHz, or the flux is attenuated for Pulse Height Analysis (PHA) capable of discriminating up to ~10k pulses per second. Digital signal processing routines combining shaping filters are performed during PHA to reject noise and record gamma ray energy. The GRI setup and PHA algorithms will be described and initial data from experiments will be presented. Work supported by the US DOE under DE-AC05-00OR22725, DE-FG02-07ER54917 & DE-FC02-04ER54698.

Preliminary Iron Distribution on Vesta

NASA Technical Reports Server (NTRS)

Mittlefehldt, David W.; Mittlefehldt, David W.

2013-01-01

The distribution of iron on the surface of the asteroid Vesta was investigated using Dawn's Gamma Ray and Neutron Detector (GRaND) [1,2]. Iron varies predictably with rock type for the howardite, eucrite, and diogenite (HED) meteorites, thought to be representative of Vesta. The abundance of Fe in howardites ranges from about 12 to 15 wt.%. Basaltic eucrites have the highest abundance, whereas, lower crustal and upper mantle materials (cumulate eucrites and diogenites) have the lowest, and howardites are intermediate [3]. We have completed a mapping study of 7.6 MeV gamma rays produced by neutron capture by Fe as measured by the bismuth germanate (BGO) detector of GRaND [1]. The procedures to determine Fe counting rates are presented in detail here, along with a preliminary distribution map, constituting the necessary initial step to quantification of Fe abundances. We find that the global distribution of Fe counting rates is generally consistent with independent mineralogical and compositional inferences obtained by other instruments on Dawn such as measurements of pyroxene absorption bands by the Visual and Infrared Spectrometer (VIR) [4] and Framing Camera (FC) [5] and neutron absorption measurements by GRaND [6].

Enhanced scintillation of Ba3In(B3O6)3 based on nitrogen doping

NASA Astrophysics Data System (ADS)

Wang, Z. X.; Pei, H.; Tao, X. M.; Cai, G. M.; Mao, R. H.; Jin, Z. P.

2018-02-01

Scintillating materials, as a class of luminescent materials, are highly demanded for practical use in the high-energy detection. However, the applications are often hampered by their low light yield (LY) or long decay time for many traditional scintillators. In this work, upon nitrogen anion doping, scintillation performance in layered borate Ba3In(B3O6)3 (BIB) has been excellently enhanced with high XEL intensity of ～3 times as large as that of commercial Bi4Ge3O12 (BGO) and ultra-fast fluorescent decay time of ～1.25 ns. To shed light on origins of the intrinsic violet-blue emission, we measured the in-situ vacuum ultraviolet excited (VUV) emission spectra of N-BIB ceramic. Combined with experiments and first principles calculations, the band-gap reduction and donor-acceptor density increasing by nitrogen (N) doping is responsible for the enhancement of scintillation performance for N-doped Ba3In(B3O6)3. Moreover, nitrogen anion doping rather than conventional cation doping is found to be also applicable to other intrinsic luminescent materials for enhancing performance.

Photorefractive waveguides in oxide crystals: fabrication, properties, and applications

NASA Astrophysics Data System (ADS)

Kip, D.

1998-08-01

In several oxide crystals the refractive index can be changed by inhomogeneous illumination, and these photorefractive properties have allowed for a wide variety of applications in optical data storage and dynamic holography. The high light intensities that are inherent in waveguide geometries make it relatively easy to observe photorefractive effects in waveguide structures, too. On the one hand, these effects are feared as optical damage, as they can degrade the performance of integrated optical devices. On the other hand, optical wave mixing in photorefractive waveguides is of considerable interest for the development of nonlinear optical components. A review of the results of recent research on the fabrication, investigation, and applications of photorefractive waveguides is given. The formation and photorefractive properties of LiNbO3, LiTaO3, BaTiO3, KNbO3, SrxBa1-xNb2O6 (0.25hxА.75, SBN), and Bi12(Si,Ti,Ge)O20 (BSO, BTO, BGO) waveguides are discussed. Furthermore, the suitability of photorefractive waveguides for nonlinear optical components is demonstrated in some examples.