Research on solvent-refined coal. Quarterly technical progress report, April 1, 1981-June 30, 1981

DOE Office of Scientific and Technical Information (OSTI.GOV)

Not Available

1981-10-01

This report describes progress on the Research on Solvent Refined Coal project by The Pittsburg and Midway Coal Mining Co.'s Merriam Laboratory during the second quarter of 1981. Alexander Mine coal was evaluated as a feedstock for major liquefaction facilities and had a yield structure similar to other reactive Pittsburgh seam coals at standard SRC II conditions. Two lots of coal from the Ireland Mine (Pittsburgh seam) were found to be of nearly the same composition and produced essentially the same yields. Two experiments in which coal-derived nonvolatile organic matter was processed without fresh coal feed indicate constant rates ofmore » conversion of SRC to oil and gas. Insoluble organic matter (IOM) remained unconverted. The naphtha and middle distillate products from the deep conversion contained less sulfur but more nitrogen than those from conventional SRC II processing. Encouraging results were obtained when a very small amount of iron oxide dispersed on alumina was added to Kaiparowits coal which cannot be processed at normal SRC II conditions without added catalyst. Subbituminous coals from the McKinley and Edna Mines were processed successfully with added pyrite but would not run when the added catalyst was removed.« less

Dry cleaning of Turkish coal

DOE Office of Scientific and Technical Information (OSTI.GOV)

Cicek, T.

2008-07-01

This study dealt with the upgrading of two different type of Turkish coal by a dry cleaning method using a modified air table. The industrial size air table used in this study is a device for removing stones from agricultural products. This study investigates the technical and economical feasibility of the dry cleaning method which has never been applied before on coals in Turkey. The application of a dry cleaning method on Turkish coals designated for power generation without generating environmental pollution and ensuring a stable coal quality are the main objectives of this study. The size fractions of 5-8,more » 3-5, and 1-3 mm of the investigated coals were used in the upgrading experiments. Satisfactory results were achieved with coal from the Soma region, whereas the upgrading results of Hsamlar coal were objectionable for the coarser size fractions. However, acceptable results were obtained for the size fraction 1-3 mm of Hsamlar coal.« less

Advanced coal conversion process demonstration. Technical progress report for the period July 1, 1995--September 30, 1995

DOE Office of Scientific and Technical Information (OSTI.GOV)

NONE

1997-05-01

This report describes the technical progress made on the Advanced Coal Conversion Process (ACCP) Demonstration Project from July 1, 1995 through September 30, 1995. The ACCP Demonstration Project is a US Department of Energy (DOE) Clean Coal Technology Project. This project demonstrates an advanced, thermal, coal upgrading process, coupled with physical cleaning techniques, that is designed to upgrade high-moisture, low-rank coals to a high-quality, low-sulfur fuel, registered as the SynCoal process. The coal is processed through three stages (two heating stages followed by an inert cooling stage) of vibrating fluidized bed reactors that remove chemically bound water, carboxyl groups, andmore » volatile sulfur compounds. After thermal upgrading, the cola is put through a deep-bed stratifier cleaning process to separate the pyrite-rich ash from the coal.« less

Chemicals from coal. Interim report for USBM Synthoil

DOE Office of Scientific and Technical Information (OSTI.GOV)

Peters, B.C.

1977-10-01

This document contains the results of an investigation to determine the suitability of the USBM Synthoil Product as a petrochemical feedstock. A sample of the whole crude was distilled into two straight run fractions; 350 to 650/sup 0/F mid-distillate and 650/sup 0/F+ residue. Laboratory studies in metal reactors and computer and mathematical simulations were performed to provide overall material balance data for a conceptual plant. The mid-distillate was hydrocracked to produce naphtha which was further processed by hydrotreating and reforming. The reformate from the mid-distillate was then mathematically hydrodealkylated to convert it to a product slate consisting of methane, LPG's,more » benzene, and fuel, along with the total hydrogen consumed. The value of the products obtained per 100 pounds of mid-distillate was $6.89. The high aromatic yield obtained from the hydrocrackate naphtha makes this fraction very attractive as a petrochemical feedstock. Because the gas oil would be extremely difficult to process, it was not investigated.« less

Mining Upgrades to Reduce Pollution

EPA Pesticide Factsheets

Settlement with Southern Coal Corporation and 26 affiliates requires the companies to comprehensively upgrade their coal mining and processing operations to prevent polluted wastewater from threatening rivers and streams and communities across Appalachia.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Not Available

Cibro Petroleum Products has built a 30,000 bbl/day hydroskimming refinery that went on stream in fall 1978 and is to produce naphtha and No. 6 and 2 fuel oils. The nine major assemblies were fabricated, prepiped, prewired, insulated, instrumented, and tested by Berry Corp. in Corpus Christi, Tex., and barged via the intracoastal waterway and the Hudson River to Albany. A nominal 30,000 bbl/day topping plant, a naphtha stabilizer, two new 10 in. loading arms at the dock, major revisions of the tank farm piping system, and upgrading of the existing boiler house and electrical facilities comprised the project. Themore » primary distillation column and heaters are oversized, and with added pumps, could increase capacity to over 40,000 bbl/day. Conventional cone roof tanks with internal floaters were chosen over floating roof tanks because of the severe winters. The plant has a hydrogen sulfide caustic scrubber to clean up the refinery gas prior to combustion; there are facilities for treating the wastewater, prior to discharge to the Albany County sewer district, and treating slop oil. An API separator and dissolved air flotation units provide for oil separation.« less

Simulation models and designs for advanced Fischer-Tropsch technology

DOE Office of Scientific and Technical Information (OSTI.GOV)

Choi, G.N.; Kramer, S.J.; Tam, S.S.

1995-12-31

Process designs and economics were developed for three grass-roots indirect Fischer-Tropsch coal liquefaction facilities. A baseline and an alternate upgrading design were developed for a mine-mouth plant located in southern Illinois using Illinois No. 6 coal, and one for a mine-mouth plane located in Wyoming using Power River Basin coal. The alternate design used close-coupled ZSM-5 reactors to upgrade the vapor stream leaving the Fischer-Tropsch reactor. ASPEN process simulation models were developed for all three designs. These results have been reported previously. In this study, the ASPEN process simulation model was enhanced to improve the vapor/liquid equilibrium calculations for themore » products leaving the slurry bed Fischer-Tropsch reactors. This significantly improved the predictions for the alternate ZSM-5 upgrading design. Another model was developed for the Wyoming coal case using ZSM-5 upgrading of the Fischer-Tropsch reactor vapors. To date, this is the best indirect coal liquefaction case. Sensitivity studies showed that additional cost reductions are possible.« less

Catalytic multi-stage process for hydroconversion and refining hydrocarbon feeds

DOEpatents

Comolli, Alfred G.; Lee, Lap-Keung

2001-01-01

A multi-stage catalytic hydrogenation and hydroconversion process for heavy hydrocarbon feed materials such as coal, heavy petroleum fractions, and plastic waste materials. In the process, the feedstock is reacted in a first-stage, back-mixed catalytic reactor with a highly dispersed iron-based catalyst having a powder, gel or liquid form. The reactor effluent is pressure-reduced, vapors and light distillate fractions are removed overhead, and the heavier liquid fraction is fed to a second stage back-mixed catalytic reactor. The first and second stage catalytic reactors are operated at 700-850.degree. F. temperature, 1000-3500 psig hydrogen partial pressure and 20-80 lb./hr per ft.sup.3 reactor space velocity. The vapor and light distillates liquid fractions removed from both the first and second stage reactor effluent streams are combined and passed to an in-line, fixed-bed catalytic hydrotreater for heteroatom removal and for producing high quality naphtha and mid-distillate or a full-range distillate product. The remaining separator bottoms liquid fractions are distilled at successive atmospheric and vacuum pressures, low and intermediate-boiling hydrocarbon liquid products are withdrawn, and heavier distillate fractions are recycled and further upgraded to provide additional low-boiling hydrocarbon liquid products. This catalytic multistage hydrogenation process provides improved flexibility for hydroprocessing the various carbonaceous feedstocks and adjusting to desired product structures and for improved economy of operations.

Process for removing polymer-forming impurities from naphtha fraction

DOEpatents

Kowalczyk, D.C.; Bricklemyer, B.A.; Svoboda, J.J.

1983-12-27

Polymer precursor materials are vaporized without polymerization or are removed from a raw naphtha fraction by passing the raw naphtha to a vaporization zone and vaporizing the naphtha in the presence of a wash oil while stripping with hot hydrogen to prevent polymer deposits in the equipment. 2 figs.

Process for removing polymer-forming impurities from naphtha fraction

DOEpatents

Kowalczyk, Dennis C.; Bricklemyer, Bruce A.; Svoboda, Joseph J.

1983-01-01

Polymer precursor materials are vaporized without polymerization or are removed from a raw naphtha fraction by passing the raw naphtha to a vaporization zone (24) and vaporizing the naphtha in the presence of a wash oil while stripping with hot hydrogen to prevent polymer deposits in the equipment.

Chemical and physical aspects of refining coal liquids

NASA Astrophysics Data System (ADS)

Shah, Y. T.; Stiegel, G. J.; Krishnamurthy, S.

1981-02-01

Increasing costs and declining reserves of petroleum are forcing oil importing countries to develop alternate energy sources. The direct liquefaction of coal is currently being investigated as a viable means of producing substitute liquid fuels. The coal liquids derived from such processes are typically high in nitrogen, oxygen and sulfur besides having a high aromatic and metals content. It is therefore envisaged that modifications to existing petroleum refining technology will be necessary in order to economically upgrade coal liquids. In this review, compositional data for various coal liquids are presented and compared with those for petroleum fuels. Studies reported on the stability of coal liquids are discussed. The feasibility of processing blends of coal liquids with petroleum feedstocks in existing refineries is evaluated. The chemistry of hydroprocessing is discussed through kinetic and mechanistic studies using compounds which are commonly detected in coal liquids. The pros and cons of using conventional petroleum refining catalysts for upgrading coal liquids are discussed.

Integrated report on the toxicological mitigation of coal liquids by hydrotreatment and other processes. [Petroleum and coal-derived products

DOE Office of Scientific and Technical Information (OSTI.GOV)

Guerin, M.R.; Griest, W.H.; Ho, C.H.

1986-06-01

Research here on the toxicological properties of coal-derived liquids focuses on characterizing the refining process and refined products. Principle attention is given to the potential tumorigenicity of coal-derived fuels and to the identification of means to further reduce tumorigenicity should this be found necessary. Hydrotreatment is studied most extensively because it will be almost certainly required to produce commercial products and because it is likely to also greatly reduce tumorigenic activity relative to that of crude coal-liquid feedstocks. This report presents the results of a lifetime C3H mouse skin tumorigenicity assay of an H-Coal series of oils and considers themore » relationships between tumorigenicity, chemistry, and processing. Lifetime assay results are reported for an H-Coal syncrude mode light oil/heavy oil blend, a low severity hydrotreatment product, a high severity hydrotreatment product, a naphtha reformate, a heating oil, a petroleum-derived reformate, and a petroleum derived heating oil. Data are compared with those for an earlier study of an SRC-II blend and products of its hydrotreatment. Adequate data are presented to allow an independent qualitative assessment of the conclusions while statistical evaluation of the data is being completed. The report also documents the physical and chemical properties of the oils tested. 33 refs., 14 figs., 53 tabs.« less

DOE Office of Scientific and Technical Information (OSTI.GOV)

Dawson, F.N. Jr.

The Dynacracking process developed by Hydrocarbon Research, Inc., is a non-catalytic process capable of upgrading heavy oil whose sulfur, metal, and carbon contents may be high. It converts residual stocks to distillates with high naphtha yields, and to synthetic fuel gas of high quality (700-800 Btu/ft/sup 3/). It has esentially no air polution emissions and requires a relatively small amount of water and utilities. The process generates sufficient heat internally such that, except for start-up, no boilers, furnaces, or external heaters are required to operate the plant. Several aspects of the process are discussed: chemistry, hardware, feedstock, flexibility in themore » product mix, product quality, and economics.« less

The SRC-II process

NASA Astrophysics Data System (ADS)

Schmid, B. K.; Jackson, D. M.

1981-03-01

The Solvent Refined Coal (SRC-II) process which produces low-sulfur distillate fuel oil from coal is discussed. The process dissolves coal in a process-derived solvent at elevated temperature and pressure in the presence of hydrogen, separates the undissolved mineral residue, then recovers the original solvent by vacuum distillation. The distillate fuel oil produced is for use largely as a nonpolluting fuel for generating electrical power and steam and is expected to be competitive with petroleum fuels during the 1980s. During this period, the SRC-II fuel oil is expected to be attractive compared with combustion of coal with flue gas desulfurization in U.S. East Coast oil-burning power plants, as well as in small and medium-sized industrial boilers. The substantial quantities of methane, light hydrocarbons and naphtha produced by the process have value as feedstocks for preparation of pipeline gas, ethylene and high-octane unleaded gasoline, and can replace petroleum fractions in many applications. The liquid and gas products from a future large-scale plant, such as the 6000 t/day plant planned for Morgantown, West Virginia, are expected to have an overall selling price of $4.25 to $4.75/GJ.

Refining and end use study of coal liquids I - pilot plant studies

DOE Office of Scientific and Technical Information (OSTI.GOV)

Erwin, J.; Moulton, D.S.

1995-12-31

The Office of Fossil Energy, Pittsburgh Energy Technology Center is examining the ways in which coal liquids may best be integrated into the refinery of the 2000-2015 time frame and what performance and emission properties will prevail among the slate of fuels produced. The study consists of a Basic Program administered by Bechtel Group, Inc. to build a linear programming refinery model and provide processing and fuel properties data through subcontractors Southwest Research Institute, Amoco Oil R&D, and M.W. Kellogg Company. The model will be used in an Option 1 to devise a slate of test fuels meeting advanced specifications,more » which will be produced and tested for physical ASTM-type properties, engine performance, and vehicle emissions. Three coal liquids will be included: a direct liquid from bituminous coal, another from subbituminous, and a Fischer-Tropsch indirect liquefaction product. This paper reports the work to date on fractions of the first direct liquid including naphtha hydrotreating, heavy distillate hydrotreating, FCC of the heavy distillate hydrotreater products. Also reported are the first stages of work on the indirect liquefaction wax including feed preparation and FCC tests of blends with petroleum FCC feed.« less

Chemicals from low temperature liquid-phase cracking of coals

DOE Office of Scientific and Technical Information (OSTI.GOV)

Sato, Y.; Kodera, Y.; Kamo, T.

1999-07-01

Mild gasification and low temperature pyrolysis are considered to be the most promising process for high-moisture subbituminous and lignite coal to produce upgraded solid fuel with high heating value and low sulfur, and to produce a useful liquid product. However effective technology to prevent spontaneous combustion of solid product and to utilize oxygen-rich liquid product has not yet been reported to enhance commercial feasibility of these process. In this study, liquid-phase cracking of low rank coal at 350--450 C under 2 MPa of initial nitrogen atmosphere has been studied to produce upgraded coal and value added liquid product. Liquid-phase crackingmore » of Wyoming subbituminous Buckskin coal using iron oxide catalyst in the presence of t-decalin at 440C gave 10 wt% of liquid product, 12 wt% of gases and 74 wt% of upgraded coal with small amount of water. Gaseous product consisted of mainly carbon dioxide (62wt%) and methane. Therefore, cracking of carboxylic function took place effectively in these conditions. Liquid product contains BTX, phenols and alkylphenols. Concentrated chemicals of BTX, phenol and cresols from the liquid products by hydrocracking and hydrotreating will be discussed.« less

Influence of additives on the increase of the heating value of Bayah’s coal with upgrading brown coal (UBC) method

DOE Office of Scientific and Technical Information (OSTI.GOV)

Heriyanto, Heri; Widya Ernayati, K.; Umam, Chairul

UBC (upgrading brown coal) is a method of improving the quality of coal by using oil as an additive. Through processing in the oil media, not just the calories that increase, but there is also water repellent properties and a decrease in the tendency of spontaneous combustion of coal products produced. The results showed a decrease in the water levels of natural coal bayah reached 69%, increase in calorific value reached 21.2%. Increased caloric value and reduced water content caused by the water molecules on replacing seal the pores of coal by oil and atoms C on the oil thatmore » is bound to increase the percentage of coal carbon. As a result of this experiment is, the produced coal has better calorific value, the increasing of this new calorific value up to 23.8% with the additive waste lubricant, and the moisture content reduced up to 69.45%.« less

Refining and end use study of coal liquids II - linear programming analysis

DOE Office of Scientific and Technical Information (OSTI.GOV)

Lowe, C.; Tam, S.

1995-12-31

A DOE-funded study is underway to determine the optimum refinery processing schemes for producing transportation fuels that will meet CAAA regulations from direct and indirect coal liquids. The study consists of three major parts: pilot plant testing of critical upgrading processes, linear programming analysis of different processing schemes, and engine emission testing of final products. Currently, fractions of a direct coal liquid produced form bituminous coal are being tested in sequence of pilot plant upgrading processes. This work is discussed in a separate paper. The linear programming model, which is the subject of this paper, has been completed for themore » petroleum refinery and is being modified to handle coal liquids based on the pilot plant test results. Preliminary coal liquid evaluation studies indicate that, if a refinery expansion scenario is adopted, then the marginal value of the coal liquid (over the base petroleum crude) is $3-4/bbl.« less

Emission Performance of Low Cetane Naphtha as Drop-In Fuel on a Multi-Cylinder Heavy-Duty Diesel Engine and Aftertreatment System

DOE Office of Scientific and Technical Information (OSTI.GOV)

LeePhD, John; TzanetakisPhD, Tom; Travers, Michael

With higher volatility and longer ignition delay characteristics than typical diesel fuel, low cetane naphtha fuel has been shown to promote partially premixed combustion and produce lower soot for improved fuel economy. In this study, emission performance of low cetane, low octane naphtha (CN 35, RON 60) as a drop-in fuel was examined on a MY13 Cummins ISX15 6-cylinder heavy-duty on-highway truck engine and aftertreatment system. Using the production hardware and development calibrations, both the engine-out and tailpipe emissions of naphtha and ultra-low sulfur diesel (ULSD) fuels were examined during the EPA s heavy-duty emission testing cycles. Without any modificationmore » to the calibrations, the tailpipe emissions were comparable when using naphtha or ULSD on the heavy duty Federal Test Procedure (FTP) and ramped modal cycle (RMC) test cycles. Overall lower CO2 emissions and fuel consumption were also measured for naphtha due in part to its higher heating value and higher hydrogen to carbon ratio. Engine-out and tailpipe NOx emissions were lower for naphtha fuel at the same catalyst conversion levels and measured particulate matter (PM) emissions were also lower when using naphtha due to its higher volatility and lower aromatic content compared to ULSD. To help assess the potential impact on diesel particulate filter design and operation, engine-out PM samples were collected and characterized at the B50 operating point. A significant reduction in elemental carbon (EC) within the particulate emissions was found when using naphtha compared to ULSD.« less

Peripheral neuropathy following intentional inhalation of naphtha fumes.

PubMed Central

Tenenbein, M; deGroot, W; Rajani, K R

1984-01-01

Two adolescent native Canadians who presented with peripheral neuropathy secondary to the abuse of volatile hydrocarbons are described. They were initially thought to have been sniffing leaded gasoline fumes, but public health investigation revealed that they had been sniffing naphtha fumes. Naphtha contains a significant amount of n-hexane, a known inducer of neuropathy. Nerve conduction studies and nerve biopsy confirmed the diagnosis of naphtha abuse. These cases emphasize the need to specifically identify the formulation of hydrocarbons being abused. PMID:6093978

Process to upgrade coal liquids by extraction prior to hydrodenitrogenation

DOEpatents

Schneider, Abraham; Hollstein, Elmer J.; Janoski, Edward J.; Scheibel, Edward G.

1982-01-01

Oxygen compounds are removed, e.g., by extraction, from a coal liquid prior to its hydrogenation. As a result, compared to hydrogenation of such a non-treated coal liquid, the rate of nitrogen removal is increased.

Deposition and material response from Mach 0.3 burner rig combustion of SRC 2 fuels

NASA Technical Reports Server (NTRS)

Santoro, G. J.; Kohl, F. J.; Stearns, C. A.; Fryburg, G. C.; Johnson, J. R.

1980-01-01

Collectors at 1173K (900 C) were exposed to the combustion products of a Mach 0.3 burner rig fueled with various industrial turbine liquid fuels from solvent refined coals. Four fuels were employed: a naphtha, a light oil, a wash solvent and a mid-heavy distillate blend. The response of four superalloys (IN-100, U 700, IN 792 and M-509) to exposure to the combustion gases from the SRC-2 naphtha and resultant deposits was also determined. The SRC-2 fuel analysis and insights obtained during the combustion experience are discussed. Particular problems encountered were fuel instability and reactions of the fuel with hardware components. The major metallic elements which contributed to the deposits were copper, iron, chromium, calcium, aluminum, nickel, silicon, titanium, zinc, and sodium. The deposits were found to be mainly metal oxides. An equilibrium thermodynamic analysis was employed to predict the chemical composition of the deposits. The agreement between the predicted and observed compounds was excellent. No hot corrosion was observed. This was expected because the deposits contained very little sodium or potassium and consisted mainly of the unreactive oxides. However, the amounts of deposits formed indicated that fouling is a potential problem with the use of these fuels.

Coal upgrading program for Usti nad Labem, Czech Republic: Task 8.3. Topical report, October 1994--August 1995

DOE Office of Scientific and Technical Information (OSTI.GOV)

Young, B.C.; Musich, M.A.

1995-10-01

Coal has been a major energy source in the Czech Republic given its large coal reserves, especially brown coal and lignite (almost 4000 million metric tons) and smaller reserves of hard, mainly bituminous, coal (over 800 million tons). Political changes since 1989 have led to the reassessment of the role of coal in the future economy as increasing environmental regulations affect the use of the high-sulfur and high-ash brown coal and lignite as well as the high-ash hard coal. Already, the production of brown coal has declined from 87 million metric tons per year in 1989 to 67 million metricmore » tons in 1993 and is projected to decrease further to 50 million metric tons per year of brown coal by the year 2000. As a means of effectively utilizing its indigenous coal resources, the Czech Republic is upgrading various technologies, and these are available at different stages of development, demonstration, and commercialization. The purpose of this review is to provide a database of information on applicable technologies that reduce the impact of gaseous (SO{sub 2}, NO{sub x}, volatile organic compounds) and particulate emissions from the combustion of coal in district and residential heating systems.« less

Neuropsychological effects of exposure to naphtha among automotive workers.

PubMed Central

White, R F; Robins, T G; Proctor, S; Echeverria, D; Rocskay, A S

1994-01-01

The association between exposure to naphtha and neurobehavioural measures was examined prospectively over one year among workers employed at an automotive plant that used naphtha to calibrate fuel injectors. The neurobehavioural tests included those that assess mood, basic intelligence, and functioning of the cerebral frontal lobes and limbic system and were designed so that acute, reversible, and chronic effects of solvent exposure could be assessed. Participants were 248 workers in June 1988, and the testing was repeated on 185 of these workers in 1989. Concentrations of naphtha at the plant ranged from six to 709 mg/m3, although exposure was greater in 1988 than in 1989. Duration of exposure for individual subjects ranged from 0.8 to 7.3 years. Cross sectional data analyses showed significant associations between level of exposure to naphtha and slower timed scores on trails A, and greater reports of negative affective symptoms on profile of mood states scales in 1988 but not 1989. Threshold model analyses of the 1989 data showed an association between score on visual reproductions immediate recall and daily exposure to naphtha at or above 1050 h x mg/m3. Models of chronic exposure showed no associations between chronic exposure and negative neurobehavioural outcome. Results suggest that naphtha produces mild acute reversible effects on function of the central nervous system at or above daily exposures of 540 h x mg/m3 (approximately 90 ppm/h). PMID:8111457

Improved Supercritical-Solvent Extraction of Coal

NASA Technical Reports Server (NTRS)

Compton, L.

1982-01-01

Raw coal upgraded by supercritical-solvent extraction system that uses two materials instead of one. System achieved extraction yields of 20 to 49 weight percent. Single-solvent yields are about 25 weight percent. Experimental results show extraction yields may be timedependent. Observed decreases in weight of coal agreed well with increases in ash content of residue.

31 CFR 561.319 - Petroleum products.

Code of Federal Regulations, 2013 CFR

2013-07-01

... petroleum gases, pentanes plus, aviation gasoline, motor gasoline, naphtha-type jet fuel, kerosene-type jet fuel, kerosene, distillate fuel oil, residual fuel oil, petrochemical feedstocks, special naphthas...

31 CFR 561.319 - Petroleum products.

Code of Federal Regulations, 2014 CFR

2014-07-01

... petroleum gases, pentanes plus, aviation gasoline, motor gasoline, naphtha-type jet fuel, kerosene-type jet fuel, kerosene, distillate fuel oil, residual fuel oil, petrochemical feedstocks, special naphthas...

31 CFR 561.319 - Petroleum products.

Code of Federal Regulations, 2012 CFR

2012-07-01

... petroleum gases, pentanes plus, aviation gasoline, motor gasoline, naphtha-type jet fuel, kerosene-type jet fuel, kerosene, distillate fuel oil, residual fuel oil, petrochemical feedstocks, special naphthas...

Literature survey of properties of synfuels derived from coal

NASA Technical Reports Server (NTRS)

Reynolds, T. W.; Niedzwiecki, R. W.; Clark, J. S.

1980-01-01

A literature survey of the properties of synfuels for ground-based gas turbine applications is presented. Four major concepts for converting coal into liquid fuels are described: solvent extraction, catalytic liquefaction, pyrolysis, and indirect liquefaction. Data on full range syncrudes, various distillate cuts, and upgraded products are presented for fuels derived from various processes, including H-coal, synthoil, solvent-refined coal, donor solvent, zinc chloride hydrocracking, co-steam, and flash pyrolysis. Some typical ranges of data for coal-derived low Btu gases are also presented.

Advanced power assessment for Czech lignite. Task 3.6, Volume 1

DOE Office of Scientific and Technical Information (OSTI.GOV)

Sondreal, E.A.; Mann, M.D.; Weber, G.W.

1995-12-01

The US has invested heavily in research, development, and demonstration of efficient and environmentally acceptable technologies for the use of coal. The US has the opportunity to use its leadership position to market a range of advanced coal-based technologies internationally. For example, coal mining output in the Czech Republic has been decreasing. This decrease in demand can be attributed mainly to the changing structure of the Czech economy and to environmental constraints. The continued production of energy from indigenous brown coals is a major concern for the Czech Republic. The strong desire to continue to use this resource is amore » challenge. The Energy and Environmental Research Center undertook two major efforts recently. One effort involved an assessment of opportunities for commercialization of US coal technologies in the Czech Republic. This report is the result of that effort. The technology assessment focused on the utilization of Czech brown coals. These coals are high in ash and sulfur, and the information presented in this report focuses on the utilization of these brown coals in an economically and environmentally friendly manner. Sections 3--5 present options for utilizing the as-mined coal, while Sections 6 and 7 present options for upgrading and generating alternative uses for the lignite. Contents include Czech Republic national energy perspectives; powering; emissions control; advanced power generation systems; assessment of lignite-upgrading technologies; and alternative markets for lignite.« less

One-Step Coal Liquefaction

NASA Technical Reports Server (NTRS)

Qader, S. A.

1984-01-01

Steam injection improves yield and quality of product. Single step process for liquefying coal increases liquid yield and reduces hydrogen consumption. Principal difference between this and earlier processes includes injection of steam into reactor. Steam lowers viscosity of liquid product, so further upgrading unnecessary.

40 CFR Table 6 to Subpart Vvvv of... - Default Organic HAP Contents of Petroleum Solvent Groups

Code of Federal Regulations, 2010 CFR

2010-07-01

... Spirits 150 EC, Naphtha, Mixed Hydrocarbon, Aliphatic Hydrocarbon, Aliphatic Naptha, Naphthol Spirits... Aromatic Naphtha, Light Aromatic Hydrocarbons, Aromatic Hydrocarbons, Light Aromatic Solvent.) 6 4% Xylene...

A first approximation kinetic model to predict methane generation from an oil sands tailings settling basin.

PubMed

Siddique, Tariq; Gupta, Rajender; Fedorak, Phillip M; MacKinnon, Michael D; Foght, Julia M

2008-08-01

A small fraction of the naphtha diluent used for oil sands processing escapes with tailings and supports methane (CH(4)) biogenesis in large anaerobic settling basins such as Mildred Lake Settling Basin (MLSB) in northern Alberta, Canada. Based on the rate of naphtha metabolism in tailings incubated in laboratory microcosms, a kinetic model comprising lag phase, rate of hydrocarbon metabolism and conversion to CH(4) was developed to predict CH(4) biogenesis and flux from MLSB. Zero- and first-order kinetic models, respectively predicted generation of 5.4 and 5.1 mmol CH(4) in naphtha-amended microcosms compared to 5.3 (+/-0.2) mmol CH(4) measured in microcosms during 46 weeks of incubation. These kinetic models also predicted well the CH(4) produced by tailings amended with either naphtha-range n-alkanes or BTEX compounds at concentrations similar to those expected in MLSB. Considering 25% of MLSB's 200 million m(3) tailings volume to be methanogenic, the zero- and first-order kinetic models applied over a wide range of naphtha concentrations (0.01-1.0 wt%) predicted production of 8.9-400 million l CH(4) day(-1) from MLSB, which exceeds the estimated production of 3-43 million l CH(4) day(-1). This discrepancy may result from heterogeneity and density of the tailings, presence of nutrients in the microcosms, and/or overestimation of the readily biodegradable fraction of the naphtha in MLSB tailings.

High precision measurement of silicon in naphthas by ICP-OES using isooctane as diluent.

PubMed

Gazulla, M F; Rodrigo, M; Orduña, M; Ventura, M J; Andreu, C

2017-03-01

An analytical protocol for the accurate and precise determination of Si in naphthas is presented by using ICP-OES, optimizing from the sample preparation to the measurement conditions, in order to be able to analyze for the first time silicon contents below 100µgkg -1 in a relatively short time thus being used as a control method. In the petrochemical industry, silicon can be present as a contaminant in different petroleum products such as gasoline, ethanol, or naphthas, forming different silicon compounds during the treatment of these products that are irreversibly adsorbed onto catalyst surfaces decreasing its time life. The complex nature of the organic naphtha sample together with the low detection limits needed make the analysis of silicon quite difficult. The aim of this work is to optimize the measurement of silicon in naphthas by ICP-OES introducing as an improvement the use of isooctane as diluent. The set up was carried out by optimizing the measurement conditions (power, nebulizer flow, pump rate, read time, and viewing mode) and the sample preparation (type of diluent, cleaning process, blanks, and studying various dilution ratios depending on the sample characteristics). Copyright © 2016 Elsevier B.V. All rights reserved.

Literature survey of properties of synfuels derived from coal

NASA Technical Reports Server (NTRS)

Flores, F.

1982-01-01

A literature survey of the properties of synfuels for ground-based turbine applications is presented. The four major concepts for converting coal into liquid fuels (solvent extraction, catalytic liquefaction, pyrolysis, and indirect liquefaction), and the most important concepts for coal gasification (fixed bed, fluidized bed, entrained flow, and underground gasification) are described. Upgrading processes for coal derived liquid fuels are also described. Data presented for liquid fuels derived from various processes, including H-coal, synthoil, solvent refined coal, COED, donor solvent, zinc chloride hydrocracking, co-steam, and flash pyrolysis. Typical composition, and property data is also presented for low and medium-BTU gases derived from the various coal gasification processes.

Multifunctional two-stage riser fluid catalytic cracking process.

PubMed

Zhang, Jinhong; Shan, Honghong; Chen, Xiaobo; Li, Chunyi; Yang, Chaohe

This paper described the discovering process of some shortcomings of the conventional fluid catalytic cracking (FCC) process and the proposed two-stage riser (TSR) FCC process for decreasing dry gas and coke yields and increasing light oil yield, which has been successfully applied in 12 industrial units. Furthermore, the multifunctional two-stage riser (MFT) FCC process proposed on the basis of the TSR FCC process was described, which were carried out by the optimization of reaction conditions for fresh feedstock and cycle oil catalytic cracking, respectively, by the coupling of cycle oil cracking and light FCC naphtha upgrading processes in the second-stage riser, and the specially designed reactor for further reducing the olefin content of gasoline. The pilot test showed that it can further improve the product quality, increase the diesel yield, and enhance the conversion of heavy oil.

Upgrading nickel content of limonite nickel ore through pelletization, selective reduction and magnetic separation

NASA Astrophysics Data System (ADS)

Mayangsari, W.; Prasetyo, A. B.; Prasetiyo, Puguh

2018-04-01

Limonite nickel ore has potency to utilize as raw material for ferronickel or nickel matte, since it has low grade nickel content, thus process development is needed to find the acceptable process for upgrading nickel. The aim of this research is to determine upgrading of Ni content as result of selective reduction of limonite nickel pellet continued by magnetic separation as effect of temperature and time reduction as well as coal and CaSO4 addition. There are four steps to perform this research, such as preparation including characterization of raw ore and pelletization, selective reduction, magnetic separation and characterization of products by using AAS, XRD and SEM. Based on the result study, pellet form can upgrade 77.78% higher than powder form. Upgrading of Ni and Fe content was up to 3fold and 1.5fold respectively from raw ore used when reduced at 1100°C for 60 minutes with composition of coal and CaSO4, both 10%. The excess of CaSO4 addition caused fayalite formation. Moreover, S2 from CaSO4 also support to reach low melting point and enlardge particle size of metal formed.

Liquid fuel generation from algal biomass via a two-step process: effect of feedstocks.

PubMed

Xu, Yu-Ping; Duan, Pei-Gao; Wang, Feng; Guan, Qing-Qing

2018-01-01

In this study, a two-step processing method (hydrothermal liquefaction followed by catalytic upgrading) was used to produce upgraded bio-oil. A comprehensive screening analysis of algal species, including four microalgae and four macroalgae, was conducted to bridge the gap between previous accounts of microalgae and macroalgae hydrothermal liquefaction and the upgrading process of the resulting crude bio-oils. Hydrothermal liquefaction using eight algal biomasses was performed at 350 °C for 1 h. The microalgae always produced a higher crude bio-oil yield than the macroalgae due to their high lipid content, among which Schizochytrium limacinum provided the maximum crude bio-oil yield of 54.42 wt%. For microalgae, higher amounts of N in the biomass resulted in higher amounts of N in the crude bio-oil; however, contrary results were observed for the macroalgae. The crude bio-oils generated from both the microalgae and macroalgae were characterized as having a high viscosity, total acid number, and heteroatom content, and they were influenced by the biochemical compositions of the feedstocks. Next, all eight-crude bio-oils were treated at 400 °C for 2 h with 10 wt% Ru/C using tetralin as the hydrogen donor. The hydrogen source was provided after tetralin was transformed to naphthalene. All the upgraded bio-oils had higher energy densities and significantly lower N, O, and S contents and viscosities than their corresponding crude bio-oils. However, the H/C molar ratio of the upgraded bio-oils decreased due to the absence of external hydrogen relative to the crude bio-oils. The S content of the upgraded bio-oil produced from upgrading the Schizochytrium limacinum crude bio-oil was even close to the 50 ppm requirement of China IV diesel. Microalgae are better feedstocks than macroalgae for liquid fuel production. Biochemical components have a significant impact on the yield and composition of crude bio-oil. Tetralin does not perform as well as external hydrogen for controlling coke formation. The S content of the upgraded bio-oil can be reduced to 76 ppm for the crude bio-oil produced from Schizochytrium limacinum . Upgraded bio-oils have similar properties to those of naphtha and jet fuel.

Process for clean-burning fuel from low-rank coal

DOEpatents

Merriam, Norman W.; Sethi, Vijay; Brecher, Lee E.

1994-01-01

A process for upgrading and stabilizing low-rank coal involving the sequential processing of the coal through three fluidized beds; first a dryer, then a pyrolyzer, and finally a cooler. The fluidizing gas for the cooler is the exit gas from the pyrolyzer with the addition of water for cooling. Overhead gas from pyrolyzing is likely burned to furnish the energy for the process. The product coal exits with a tar-like pitch sealant to enhance its safety during storage.

Process for clean-burning fuel from low-rank coal

DOEpatents

Merriam, N.W.; Sethi, V.; Brecher, L.E.

1994-06-21

A process is described for upgrading and stabilizing low-rank coal involving the sequential processing of the coal through three fluidized beds; first a dryer, then a pyrolyzer, and finally a cooler. The fluidizing gas for the cooler is the exit gas from the pyrolyzer with the addition of water for cooling. Overhead gas from pyrolyzing is likely burned to furnish the energy for the process. The product coal exits with a tar-like pitch sealant to enhance its safety during storage. 1 fig.

Assessment of industrial applications for fuel cell cogeneration systems

NASA Technical Reports Server (NTRS)

Stickles, R. P.; Oneill, J. K.; Smith, E. H.

1978-01-01

The fuel cell energy systems are designed with and without a utility connection for emergency back-up power. Sale of electricity to the utility during periods of low plant demand is not considered. For each of the three industrial applications, conceptual designs were also developed for conventional utility systems relying on purchased electric power and fossil-fired boilers for steam/hot water. The capital investment for each energy system is estimated. Annual operating costs are also determined for each system. These cost estimates are converted to levelized annual costs by applying appropriate economic factors. The breakeven electricity price that would make fuel cell systems competitive with the conventional systems is plotted as a function of naphtha price. The sensitivity of the breakeven point to capital investment and coal price is also evaluated.

Forecasting of a Thermal Condition of Pneumatic Tires of Dump Trucks

NASA Astrophysics Data System (ADS)

Kvasova, Anna; Gerike, Boris; Murko, Elena; Skudarnov, Dmitriy

2017-11-01

Over the last 10 years the world consumption of coal has grown almost by 50%. Coal is one of the main energy resources capable to satisfy basic energy demands of increasing population and developing world economy. On January 24, 2012 the long-term Coal Industry Development Program for the period till 2030 was approved in Russia. According to this Program coal mining in Kuzbass in 2030 will make 260 million tonns of coal per year. Development of the coal industry is impossible without upgrade of coal production by avoiding inefficient technological, organizational and economic solutions. Off the road (OTR) tires play an important role in ensuring effective, continuous and safe work of mining motor transport.

The direct liquefaction proof of concept program

DOE Office of Scientific and Technical Information (OSTI.GOV)

Comolli, A.G.; Lee, L.K.; Pradhan, V.R.

1995-12-31

The goal of the Proof of Concept (POC) Program is to develop Direct Coal Liquefaction and associated transitional technologies towards commercial readiness for economically producing premium liquid fuels from coal in an environmentally acceptable manner. The program focuses on developing the two-stage liquefaction (TSL) process by utilizing geographically strategic feedstocks, commercially feasible catalysts, new prototype equipment, and testing co-processing or alternate feedstocks and improved process configurations. Other high priority objectives include dispersed catalyst studies, demonstrating low rank coal liquefaction without solids deposition, improving distillate yields on a unit reactor volume basis, demonstrating ebullated bed operations while obtaining scale-up data, demonstratingmore » optimum catalyst consumption using new concepts (e.g. regeneration, cascading), producing premium products through on-line hydrotreating, demonstrating improved hydrogen utilization for low rank coals using novel heteroatom removal methods, defining and demonstrating two-stage product properties for upgrading; demonstrating efficient and economic solid separation methods, examining the merits of integrated coal cleaning, demonstrating co-processing, studying interactions between the preheater and first and second-stage reactors, improving process operability by testing and incorporating advanced equipment and instrumentation, and demonstrating operation with alternate coal feedstocks. During the past two years major PDU Proof of Concept runs were completed. POC-1 with Illinois No. 6 coal and POC-2 with Black Thunder sub-bituminous coal. Results from these operations are continuing under review and the products are being further refined and upgraded. This paper will update the results from these operations and discuss future plans for the POC program.« less

Resource and energy management of synfuels production with hydrogen and oxygen requirements from electrolysis

NASA Astrophysics Data System (ADS)

Shannon, R. H.; Richardson, R. D.

The Resource and Energy Management System (REM), which uses electrolytic H2 and O2 to produce synthetic crude and light oils from heavy hydrocarbons is described. The heavy hydrocarbon feedstocks include heavy oils, tar sand bitumens, heavy residual oils, oil shale kerogens, liquefied coal, and pyrolytically-extracted coal liquids. The system includes mini-upgraders, which can be implemented in modular form, to pump electrolytically-derived H2 into heavy oils to upgrade their energy content. Projected costs for the production of synthetic light oils using U.S. coal reserves with the REM process after liquefaction are $30-35/bbl, with the H2 costs being a controlling factor. The modular systems could be built in a much shorter time frame than much larger projects, and would be instrumental in establishing the electrolytic H2 production infrastructure needed for eventual full conversion to an H2-based economy.

Prospects for the development of coal-steam plants in Russia

NASA Astrophysics Data System (ADS)

Tumanovskii, A. G.

2017-06-01

Evaluation of the technical state of the modern coal-fired power plants and quality of coal consumed by Russian thermal power plants (TPP) is provided. Measures aimed at improving the economic and environmental performance of operating 150-800 MW coal power units are considered. Ways of efficient use of technical methods of NO x control and electrostatic precipitators' upgrade for improving the efficiency of ash trapping are summarized. Examples of turbine and boiler equipment efficiency upgrading through its deep modernization are presented. The necessity of the development and introduction of new technologies in the coal-fired power industry is shown. Basic technical requirements for a 660-800 MW power unit with the steam conditions of 28 MPa, 600/600°C are listed. Design solutions taking into account features of Russian coal combustion are considered. A field of application of circulating fluidized bed (CFB) boilers and their effectiveness are indicated. The results of development of a new generation coal-fired TPP, including a steam turbine with an increased efficiency of the compartments and disengaging clutch, an elevated steam conditions boiler, and a highly efficient NO x /SO2 and ash particles emission control system are provided. In this case, the resulting ash and slag are not to be sent to the ash dumps and are to be used to a maximum advantage. Technical solutions to improve the efficiency of coal gasification combined cycle plants (CCP) are considered. A trial plant based on a 16 MW gas turbine plant (GTP) and an air-blown gasifier is designed as a prototype of a high-power CCP. The necessity of a state-supported technical reequipment and development program of operating coal-fired power units, as well as putting into production of new generation coal-fired power plants, is noted.

Long-Term Demonstration of Hydrogen Production from Coal at Elevated Temperatures Year 6 - Activity 1.12 - Development of a National Center for Hydrogen Technology

DOE Office of Scientific and Technical Information (OSTI.GOV)

Stanislowski, Joshua; Tolbert, Scott; Curran, Tyler

2012-04-30

The Energy & Environmental Research Center (EERC) has continued the work of the National Center for Hydrogen Technology® (NCHT®) Program Year 6 Task 1.12 project to expose hydrogen separation membranes to coal-derived syngas. In this follow-on project, the EERC has exposed two membranes to coal-derived syngas produced in the pilot-scale transport reactor development unit (TRDU). Western Research Institute (WRI), with funding from the State of Wyoming Clean Coal Technology Program and the North Dakota Industrial Commission, contracted with the EERC to conduct testing of WRI’s coal-upgrading/gasification technology for subbituminous and lignite coals in the EERC’s TRDU. This gasifier fires nominallymore » 200–500 lb/hour of fuel and is the pilot-scale version of the full-scale gasifier currently being constructed in Kemper County, Mississippi. A slipstream of the syngas was used to demonstrate warm-gas cleanup and hydrogen separation using membrane technology. Two membranes were exposed to coal-derived syngas, and the impact of coal-derived impurities was evaluated. This report summarizes the performance of WRI’s patent-pending coalupgrading/ gasification technology in the EERC’s TRDU and presents the results of the warm-gas cleanup and hydrogen separation tests. Overall, the WRI coal-upgrading/gasification technology was shown to produce a syngas significantly lower in CO2 content and significantly higher in CO content than syngas produced from the raw fuels. Warm-gas cleanup technologies were shown to be capable of reducing sulfur in the syngas to 1 ppm. Each of the membranes tested was able to produce at least 2 lb/day of hydrogen from coal-derived syngas.« less

Development of an advanced, continuous mild gasification process for the production of co-products. Quarterly report, October 30, 1991--January 2, 1992

DOE Office of Scientific and Technical Information (OSTI.GOV)

O`Neal, G.W.

1991-12-31

During this quarter the work on Task 3, char upgrading, was in two areas; upgrading Penelec char made from Penelec filter cake to blast furnace formed coke, and evaluating various bituminous pitch binders. The formed coke from Penelec filter cake was of good quality with a high crush strength of 3000 pounds. The reactivity was not equal to that of conventional coke but it is felt that it could be made to equal conventional coke with further study, specifically by adding binder coal to the raw material recipe. The work evaluating bituminous pitch binders confirmed earlier thinking that will bemore » valuable to a commercial scale-up. Asphalt binders are compatible with coal tar binders and produce a coke of equal quality. Hence asphalt binders can be used to supply deficiencies of tar production in units employing coals with insufficient volatile matter to supply enough tar for the coking process. Asphalt binders have about a 50% savings from coal tar pitch. During the 4th Quarter of 1991, a total of 15 Continuous Mild Gasification Unit (CMGU) test runs were made. Efforts continued to determine the optimum forward/reverse ratio to maximize coal feed rate. The success of these efforts has been limited with a maximum coal feed rate of 400 lbs/hr obtainable with a caking coal. The handicap of not having screw shaft heaters cannot be overcome by adjustment of the forward/reverse ratio.« less

Development of an advanced, continuous mild gasification process for the production of co-products

DOE Office of Scientific and Technical Information (OSTI.GOV)

O'Neal, G.W.

1991-01-01

During this quarter the work on Task 3, char upgrading, was in two areas; upgrading Penelec char made from Penelec filter cake to blast furnace formed coke, and evaluating various bituminous pitch binders. The formed coke from Penelec filter cake was of good quality with a high crush strength of 3000 pounds. The reactivity was not equal to that of conventional coke but it is felt that it could be made to equal conventional coke with further study, specifically by adding binder coal to the raw material recipe. The work evaluating bituminous pitch binders confirmed earlier thinking that will bemore » valuable to a commercial scale-up. Asphalt binders are compatible with coal tar binders and produce a coke of equal quality. Hence asphalt binders can be used to supply deficiencies of tar production in units employing coals with insufficient volatile matter to supply enough tar for the coking process. Asphalt binders have about a 50% savings from coal tar pitch. During the 4th Quarter of 1991, a total of 15 Continuous Mild Gasification Unit (CMGU) test runs were made. Efforts continued to determine the optimum forward/reverse ratio to maximize coal feed rate. The success of these efforts has been limited with a maximum coal feed rate of 400 lbs/hr obtainable with a caking coal. The handicap of not having screw shaft heaters cannot be overcome by adjustment of the forward/reverse ratio.« less

Advanced thermally stable jet fuels: Technical progress report, October 1994--December 1994

DOE Office of Scientific and Technical Information (OSTI.GOV)

Schobert, H.H.; Eser, S.; Song, C.

There are five tasks within this project on thermally stable coal-based jet fuels. Progress on each of the tasks is described. Task 1, Investigation of the quantitative degradation chemistry of fuels, has 5 subtasks which are described: Literature review on thermal stability of jet fuels; Pyrolytic and catalytic reactions of potential endothermic fuels: cis- and trans-decalin; Use of site specific {sup 13}C-labeling to examine the thermal stressing of 1-phenylhexane: A case study for the determination of reaction kinetics in complex fuel mixtures versus model compound studies; Estimation of critical temperatures of jet fuels; and Surface effects on deposit formation inmore » a flow reactor system. Under Task 2, Investigation of incipient deposition, the subtask reported is Uncertainty analysis on growth and deposition of particles during heating of coal-derived aviation gas turbine fuels; under Task 3, Characterization of solid gums, sediments, and carbonaceous deposits, is subtask, Studies of surface chemistry of PX-21 activated carbon during thermal degradation of jet A-1 fuel and n-dodecane; under Task 4, Coal-based fuel stabilization studies, is subtask, Exploratory screening and development potential of jet fuel thermal stabilizers over 400 C; and under Task 5, Exploratory studies on the direct conversion of coal to high quality jet fuels, are 4 subtasks: Novel approaches to low-severity coal liquefaction and coal/resid co-processing using water and dispersed catalysts; Shape-selective naphthalene hydrogenation for production of thermally stable jet fuels; Design of a batch mode and a continuous mode three-phase reactor system for the liquefaction of coal and upgrading of coal liquids; and Exploratory studies on coal liquids upgrading using mesopores molecular sieve catalysts. 136 refs., 69 figs., 24 tabs.« less

Solvent recyclability in a multistep direct liquefaction process

DOE Office of Scientific and Technical Information (OSTI.GOV)

Hetland, M.D.; Rindt, J.R.

1995-12-31

Direct liquefaction research at the Energy & Environmental Research Center (EERC) has, for a number of years, concentrated on developing a direct liquefaction process specifically for low-rank coals (LRCs) through the use of hydrogen-donating solvents and solvents similar to coal-derived liquids, the water/gas shift reaction, and lower-severity reaction conditions. The underlying assumption of all of the research was that advantage could be taken of the reactivity and specific qualities of LRCs to produce a tetrahydrofuran (THF)-soluble material that might be easier to upgrade than the soluble residuum produced during direct liquefaction of high-rank coals. A multistep approach was taken tomore » produce the THF-soluble material, consisting of (1) preconversion treatment to prepare the coal for solubilization, (2) solubilization of the coal in the solvent, and (3) polishing to complete solubilization of the remaining material. The product of these three steps can then be upgraded during a traditional hydrotreatment step. The results of the EERC`s research indicated that additional studies to develop this process more fully were justified. Two areas were targeted for further research: (1) determination of the recyclability of the solvent used during solubilization and (2) determination of the minimum severity required for hydrotreatment of the liquid product. The current project was funded to investigate these two areas.« less

Sequential biodegradation of complex naphtha hydrocarbons under methanogenic conditions in two different oil sands tailings.

PubMed

Mohamad Shahimin, Mohd Faidz; Siddique, Tariq

2017-02-01

Methane emissions in oil sands tailings ponds are sustained by anaerobic biodegradation of unrecovered hydrocarbons. Naphtha (primarily C 6 -C 10 ; n- iso- and cycloalkanes) is commonly used as a solvent during bitumen extraction process and its residue escapes to tailings ponds during tailings deposition. To investigate biodegradability of hydrocarbons in naphtha, mature fine tailings (MFT) collected from Albian and CNRL tailings ponds were amended with CNRL naphtha at ∼0.2 wt% (∼2000 mg L -1 ) and incubated under methanogenic conditions for ∼1600 d. Microbial communities in both MFTs started metabolizing naphtha after a lag phase of ∼100 d. Complete biodegradation/biotransformation of all n-alkanes (except partial biodegradation of n-octane in CNRL MFT) followed by major iso-alkanes (2-methylpentane, 3-methylhexane, 2- and 4-methylheptane, iso-nonanes and 2-methylnonane) and a few cycloalkanes (derivatives of cyclopentane and cyclohexane) was observed during the incubation. 16S rRNA gene pyrosequencing showed dominance of Peptococcaceae and Anaerolineaceae in Albian MFT and Anaerolineaceae and Syntrophaceae in CNRL MFT bacterial communities with co-domination of Methanosaetaceae and "Candidatus Methanoregula" in archaeal populations during active biodegradation of hydrocarbons. The findings extend the known range of hydrocarbons susceptible to methanogenic biodegradation in petroleum-impacted anaerobic environments and help refine existing kinetic model to predict greenhouse gas emissions from tailings ponds. Copyright © 2016 Elsevier Ltd. All rights reserved.

Surfactant studies for bench-scale operation

NASA Technical Reports Server (NTRS)

Hickey, Gregory S.; Sharma, Pramod K.

1993-01-01

A phase 2 study has been initiated to investigate surfactant-assisted coal liquefaction, with the objective of quantifying the enhancement in liquid yields and product quality. This report covers the second quarter of work. The major accomplishments were: completion of coal liquefaction autoclave reactor runs with Illinois number 6 coal at processing temperatures of 300, 325, and 350 C, and pressures of 1800 psig; analysis of the filter cake and the filtrate obtained from the treated slurry in each run; and correlation of the coal conversions and the liquid yield quality to the surfactant concentration. An increase in coal conversions and upgrading of the liquid product quality due to surfactant addition was observed for all runs.

Effect of Additions of Aromatics on the Knocking Characteristics of Several 100-Octane Fuels at two Engine Speeds

DTIC Science & Technology

1942-05-01

2000 rpm and 160° E Inlet==Air Temperature ?erformanoe Of.zeferenoe fuels,- When teeted at 2000 rpm aad 150° ~ Inlet-air temperatu ~e, the referenoe...naphtha 70 peroent phosphorlo acid iso-ootane in 15 percent light naphtha and 15 percent benzene 56 percent aviation alkyl- ate and 9 percent hydro

Direct liquefaction Proof-of-Concept facility. Final technical progress report

DOE Office of Scientific and Technical Information (OSTI.GOV)

Comolli, A.G.; Lee, L.K.; Pradhan, V.R.

1995-08-01

This report presents the results of work which included extensive modifications to HRI`s existing 3 ton per day Process Development Unit (PDU) and completion of the first PDU run. The 58-day Run 1 demonstrated scale-up of the Catalytic Two-Stage Liquefaction (CTSL Process) on Illinois No. 6 coal to produce distillate liquid products at a rate of up to 5 barrels per to of moisture-ash-free coal. The Kerr McGee Rose-SR unit from Wilsonville was redesigned and installed next to the US Filter installation to allow a comparison of the two solids removal systems. Also included was a new enclosed reactor tower,more » upgraded computer controls and a data acquisition system, an alternate power supply, a newly refurbished reactor, an in-line hydrotreater, interstage sampling system, coal handling unit, a new ebullating pump, load cells and improved controls and remodeled preheaters. Distillate liquid yields of 5 barrels/ton of moisture ash free coal were achieved. Coal slurry recycle rates were reduced from the 2--2.5 to 1 ratio demonstrated at Wilsonville to as low as 0.9 to 1. Coal feed rates were increased during the test by 50% while maintaining process performance at a marginally higher reactor severity. Sulfur in the coal was reduced from 4 wt% to ca. 0.02 wt% sulfur in the clean distillate fuel product. More than 3,500 gallons of distillate fuels were collected for evaluation and upgrading studies. The ROSE-SR Process was operated for the first time with a pentane solvent in a steady-state model. The energy rejection of the ash concentrate was consistently below prior data, being as low as 12%, allowing improved liquid yields and recovery.« less

Coal ash by-product reutilization

DOE Office of Scientific and Technical Information (OSTI.GOV)

Muncy, J.; Miller, B.

1997-09-01

Potomac Electric Power Company (PEPCO) has as part of its vision and value statement that, ``We are responsible stewards of environmental and corporate resources.`` With this moral imperative in mind, a project team was charged with initiating the Coal Pile Liner Project--installing a membrane liner under the existing coal storage pile at the Morgantown Generating Station. The existing coal yard facilities were constructed prior to the current environmental regulations, and it became necessary to upgrade the storage facilities to be environmentally friendly. The project team had two objectives in this project: (1) prevent coal pile leachate from entering the groundwatermore » system; (2) test the viability of using coal ash by-products as an aggregate substitute for concrete applications. Both objectives were met, and two additional benefits were achieved as well: (1) the use of coal ash by-products as a coal liner produced significant cost savings to the project directly; (2) the use of coal ash by-products reduced plant operation and maintenance expenses.« less

Occupational exposure to rubber vulcanization products during repair of rubber conveyor belts in a brown coal mine.

PubMed

Gromiec, Jan P; Wesołowski, Wiktor; Brzeźnicki, Sławomir; Wróblewska-Jakubowska, Krystyna; Kucharska, Małgorzata

2002-12-01

Several hundred chemical compounds were found in workroom environments in the rubber industry, but most of the published exposure data relate to the production of tyres; information from the "non-tyre" sections are very limited, if any. This study was carried out to identify chemical substances and measure their air concentrations in the repair shop of a brown coal mine in which damaged rubber conveyor belts were repaired. GC-MS and HPLC analysis of stationary air samples resulted in identification of aliphatic and aromatic hydrocarbons to C12, PAHs, alcohols, phenols, ketones, heterocyclic nitrogen and sulfur compounds. Quantitative evaluation of occupational exposure included determination of organic compound vapours collected on charcoal (GC-MSD), polycyclic aromatic hydrocarbons (HPLC), N-nitrosoamines and other amines (GC-NPD) and DNPH derivatives of aldehydes (HPLC) in the breathing zone of workers representing all job titles. The concentrations of investigated compounds were very low. Carcinogenic substances: N-nitrosoamines, benzene, PAHs were not present in workroom air in concentrations exceeding limits of detection of the analytical methods being applied; concentrations of methylisobutylketone, tetrachloroethylene, naphtha, aromatic hydrocarbons, phthalates and aldehydes were much lower than the respective occupational exposure limit values. The results indicate much lower exposure than that reported in the production of tyres and other fabricated rubber products.

Single-layer transition metal sulfide catalysts

DOEpatents

Thoma, Steven G [Albuquerque, NM

2011-05-31

Transition Metal Sulfides (TMS), such as molybdenum disulfide (MoS.sub.2), are the petroleum industry's "workhorse" catalysts for upgrading heavy petroleum feedstocks and removing sulfur, nitrogen and other pollutants from fuels. We have developed an improved synthesis technique to produce SLTMS catalysts, such as molybdenum disulfide, with potentially greater activity and specificity than those currently available. Applications for this technology include heavy feed upgrading, in-situ catalysis, bio-fuel conversion and coal liquefaction.

Identifying/Quantifying Environmental Trade-offs Inherent in GHG Reduction Strategies for Coal-Fired Power.

PubMed

Schivley, Greg; Ingwersen, Wesley W; Marriott, Joe; Hawkins, Troy R; Skone, Timothy J

2015-07-07

Improvements to coal power plant technology and the cofired combustion of biomass promise direct greenhouse gas (GHG) reductions for existing coal-fired power plants. Questions remain as to what the reduction potentials are from a life cycle perspective and if it will result in unintended increases in impacts to air and water quality and human health. This study provides a unique analysis of the potential environmental impact reductions from upgrading existing subcritical pulverized coal power plants to increase their efficiency, improving environmental controls, cofiring biomass, and exporting steam for industrial use. The climate impacts are examined in both a traditional-100 year GWP-method and a time series analysis that accounts for emission and uptake timing over the life of the power plant. Compared to fleet average pulverized bed boilers (33% efficiency), we find that circulating fluidized bed boilers (39% efficiency) may provide GHG reductions of about 13% when using 100% coal and reductions of about 20-37% when cofiring with 30% biomass. Additional greenhouse gas reductions from combined heat and power are minimal if the steam coproduct displaces steam from an efficient natural gas boiler. These upgrades and cofiring biomass can also reduce other life cycle impacts, although there may be increased impacts to water quality (eutrophication) when using biomass from an intensely cultivated source. Climate change impacts are sensitive to the timing of emissions and carbon sequestration as well as the time horizon over which impacts are considered, particularly for long growth woody biomass.

Low-pressure hydrocracking of coal-derived Fischer-Tropsch waxes to diesel

DOE Office of Scientific and Technical Information (OSTI.GOV)

Dieter Leckel

2007-06-15

Coal-derived low-temperature Fischer-Tropsch (LTFT) wax was hydrocracked at pressures of 3.5-7.0 MPa using silica-alumina-supported sulfided NiW/NiMo and an unsulfided noble metal catalyst, modified with MoO{sub 3}. A low-pressure operation at 3.5 MPa produced a highly isomerized diesel, having low cloud points (from -12 to -28{sup o}C) combined with high cetane numbers (69-73). These properties together with the extremely low sulfur ({lt}5 ppm) and aromatic ({lt}0.5%) contents place coal/liquid (CTL) derived distillates as highly valuable blending components to achieve Eurograde diesel specifications. The upgrading of coal-based LTFT waxes through hydrocracking to high-quality diesel fuel blend components in combination with commercial-feasible coal-integratedmore » gasification combined cycle (coal-IGCC) CO{sub 2} capture and storage schemes should make CTL technology more attractive. 28 refs., 7 figs., 8 tabs.« less

Proceedings: Fourteenth annual EPRI conference on fuel science

DOE Office of Scientific and Technical Information (OSTI.GOV)

Not Available

1990-05-01

EPRI's Fourteenth Annual Contractors' Conference on Fuel Science was held on May 18--19, 1989 in Palo Alto, CA. The conference featured results of work on coal science, coal liquefaction, methanol production, and coal oil coprocessing and coal upgrading. The following topics were discussed: recent development in coal liquefaction at the Wilsonville Clean Coal Research Center; British coal's liquid solvent extraction (LSE) process; feedstock reactivity in coal/oil co-processing; utility applications for coal-oil coprocessed fuels; effect of coal rank and quality on two-stage liquefaction; organic sulfur compounds in coals; the perchloroethylene refining process of high-sulfur coals; extraction of sulfur coals; extraction ofmore » sulfur from coal; agglomeration of bituminous and subbituminous coals; solubilization of coals by cell-free extracts derived from polyporus versicolor; remediation technologies and services; preliminary results from proof-of-concept testing of heavy liquid cyclone cleaning technology; clean-up of soil contaminated with tarry/oily organics; midwest ore processing company's coal benefication technology: recent prep plant, scale and laboratory activities; combustion characterization of coal-oil agglomerate fuels; status report on the liquid phase methanol project; biomimetic catalysis; hydroxylation of C{sub 2} {minus} C{sub 3} and cycloc{sub 6} hydrocarbons with Fe cluster catalysts as models for methane monooxygenase enzyme; methanol production scenarios; and modeling studies of the BNL low temperature methanol catalyst. Individual projects are processed separately for the data bases.« less

Progress of fossil fuel science

DOE Office of Scientific and Technical Information (OSTI.GOV)

Demirbas, M.F.

2007-07-01

Coal is the most abundant and widely distributed fossil fuel. More than 45% of the world's electricity is generated from coal, and it is the major fuel for generating electricity worldwide. The known coal reserves in the world are enough for more than 215 years of consumption, while the known oil reserves are only about 39 times of the world's consumption and the known natural gas reserves are about 63 times of the world's consumption level in 1998. In recent years, there have been effective scientific investigations on Turkish fossil fuels, which are considerable focused on coal resources. Coal ismore » a major fossil fuel source for Turkey. Turkish coal consumption has been stable over the past decade and currently accounts for about 24% of the country's total energy consumption. Lignite coal has had the biggest share in total fossil fuel production, at 43%, in Turkey. Turkish researchers may investigate ten broad pathways of coal species upgrading, such as desulfurization and oxydesulfurization, pyrolysis and hydropyrolysis, liquefaction and hydroliquefaction, extraction and supercritical fluid extraction, gasification, oxidation, briquetting, flotation, and structure identification.« less

Ending America’s Energy Insecurity: How Electric Vehicles Can Drive the Solution to Energy Independence

DTIC Science & Technology

2011-12-01

road oil, aviation gasoline, kerosene, lubricants, naphtha-type jet fuel, pentanes plus, petrochemical feedstocks, special naphthas, still gas... refinery gas), waxes, miscellaneous products, and crude oil burned as fuel. Figure 2. Uses of Oil (EIA, 2010a, p. 148) There is no significant body of...1. Large-Scale Efforts in the 1990s There have been efforts in the past to bring about the adoption of EVs or other zero- emissions vehicles. There

Coal liquefaction with subsequent bottoms pyrolysis

DOEpatents

Walchuk, George P.

1978-01-01

In a coal liquefaction process wherein heavy bottoms produced in a liquefaction zone are upgraded by coking or a similar pyrolysis step, pyrolysis liquids boiling in excess of about 1000.degree. F. are further reacted with molecular hydrogen in a reaction zone external of the liquefaction zone, the resulting effluent is fractionated to produce one or more distillate fractions and a bottoms fraction, a portion of this bottoms fraction is recycled to the reaction zone, and the remaining portion of the bottoms fraction is recycled to the pyrolysis step.

Measurement and control of electrostatic charges on solids in a gaseous suspension

NASA Astrophysics Data System (ADS)

Nieh, S.; Nguyen, T.

1985-10-01

Measurements of mean particle charges and charge distributions on Medium Volatile Bituminous (MVB) coals and Lignite A (LIGA) coals in a 51 mm ID grounded copper pipe loop have been made with the upgraded Faraday cage system. Both negative and positive charges were found for coals in all experiments. The dual polarities of charges are believed to be due to the nonuniform materials and chemical composition contained in coals. As expected, increasing velocity or decreasing air humidity has a significant effect to increase the mean particle charge and the standard deviation of distribution. Charge elimination by the addition of coal fines has been explored. Effective suppression of particle charges was achieved by adding 0.1% by mass of minus 1 micron coal dust into the pipe flow. A neutralization mechanism was proposed to interpret the measured results. The results of charge control obtained to date has been significant and encouraging. More work is needed to validate the proposed mechanism.

Non-slag co-gasification of biomass and coal in entrained-bed furnace

NASA Astrophysics Data System (ADS)

Itaya, Yoshinori; Suami, Akira; Kobayashi, Nobusuke

2018-02-01

Gasification is a promising candidate of processes to upgrade biomass and to yield clean gaseous fuel for utilization of renewable energy resources. However, a sufficient amount of biomass is not always available to operate a large scale of the plant. Co-gasification of biomass with coal is proposed as a solution of the problem. Tar emission is another subject during operation in shaft or kiln type of gasifiers employed conventionally for biomass. The present authors proposed co-gasification of biomass and coal in entrained-bed furnace, which is a representative process without tar emission under high temperature, but operated so to collect dust as flyash without molten slag formation. This paper presents the works performed on co-gasification performance of biomass and pulverized coal to apply to entrained-bed type of furnaces. At first, co-gasification of woody powder and pulverized coal examined using the lab-scale test furnace of the down-flow entrained bed showed that the maximum temperatures in the furnace was over 1500 K and the carbon conversion to gas achieved at higher efficiency than 80-90 percent although the residence time in the furnace was as short as a few seconds. Non-slag co-gasification was carried out successfully without slag formation in the furnace if coal containing ash with high fusion temperature was employed. The trend suggesting the effect of reaction rate enhancement of co-gasification was also observed. Secondary, an innovative sewage sludge upgrading system consisting of self-energy recovery processes was proposed to yield bio-dried sludge and to sequentially produce char without adding auxiliary fuel. Carbonization behavior of bio-dried sludge was evaluated through pyrolysis examination in a lab-scale quartz tube reactor. The thermal treatment of pyrolysis of sludge contributed to decomposition and removal of contaminant components such as nitrogen and sulfur. The gasification kinetics of sludge and coal was also determined by a thermogravimetric analysis. It was revealed that co-gasification rate of sludge and coal chars was influenced negatively due to high ash content in sludge.

Pulse energization; A precipitator performance upgrade technology following low sulfur coal switching

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kumar, K.S.; Feldman, P.L.; Jacobus, P.L.

1992-01-01

Madison Gas and Electric operates two 50 MWe pulverized coal fired boilers at its Blount station. This paper reports that these two units have been designed to operate with gas or coalfiring in combination with refuse derived fuel. Both these units are fitted with electrostatic precipitators for particulate control. Historically, these units have utilized Midwestern and Appalachian coals varying in sulfur contents between 2 and 5 %, with the SO{sub 2} emission level in the 3.5 pounds per million Btu range. Wisconsin's acid rain control law goes into effect in 1993 requiring utilities to control sulfur dioxide emissions below 1.2more » pounds per million Btu.« less

DOE Office of Scientific and Technical Information (OSTI.GOV)

NONE

Some say beauty is in the eye of the beholder, but when United Coal purchased the assets of White Mountain Mining in late 2005, the attractiveness of the acquired assets did not require much debate. Whilst the Pocahontas Coal reserves included in the acquisition were very desirable for producing coke, the East Gulf preparation plant was in poor condition. In order to minimize cost, maintenance and manpower whilst increasing production, the circuits in the existing plant were modified and the Barvoy Vessel was replaced with a single, pump fed, 30-inch Krebs HM cyclone. A spiral circuit was added as weremore » screen bowl centrifuges. Finally the plant was given a structural upgrade and a new siding was installed. With the East Gulf restoration project complete, the United Coal Co. (UCC) and Pocahontas Coal are now considering expanding the Affinity complex. 2 figs., 6 photos.« less

Coke formation in the thermal cracking of hydrocarbons. 4: Modeling of coke formation in naphtha cracking

DOE Office of Scientific and Technical Information (OSTI.GOV)

Reyniers, G.C.; Froment, G.F.; Kopinke, F.D.

1994-11-01

An extensive experimental program has been carried out in a pilot unit for the thermal cracking of hydrocarbons. On the basis of the experimental information and the insight in the mechanisms for coke formation in pyrolysis reactors, a mathematical model describing the coke formation has been derived. This model has been incorporated in the existing simulation tools at the Laboratorium voor Petrochemische Techniek, and the run length of an industrial naphtha cracking furnace has been accurately simulated. In this way the coking model has been validated.

Subtask 3.11 - Production of CBTL-Based Jet Fuels from Biomass-Based Feedstocks and Montana Coal

DOE Office of Scientific and Technical Information (OSTI.GOV)

Sharma, Ramesh

The Energy & Environmental Research Center (EERC), in partnership with the U.S. Department of Energy (DOE) and Accelergy Corporation, an advanced fuels developer with technologies exclusively licensed from Exxon Mobil, undertook Subtask 3.11 to use a recently installed bench-scale direct coal liquefaction (DCL) system capable of converting 45 pounds/hour of pulverized, dried coal to a liquid suitable for upgrading to fuels and/or chemicals. The process involves liquefaction of Rosebud mine coal (Montana coal) coupled with an upgrading scheme to produce a naphthenic fuel. The upgrading comprises catalytic hydrotreating and saturation to produce naphthenic fuel. A synthetic jet fuel was preparedmore » by blending equal volumes of naphthenic fuel with similar aliphatic fuel derived from biomass and 11 volume % of aromatic hydrocarbons. The synthetic fuel was tested using standard ASTM International techniques to determine compliance with JP-8 fuel. The composite fuel thus produced not only meets but exceeds the military aviation fuel-screening criteria. A 500-milliliter synthetic jet fuel sample which met internal screening criteria was submitted to the Air Force Research Laboratory (AFRL) at Wright–Patterson Air Force Base, Dayton, Ohio, for evaluation. The sample was confirmed by AFRL to be in compliance with U.S. Air Force-prescribed alternative aviation fuel initial screening criteria. The results show that this fuel meets or exceeds the key specification parameters for JP-8, a petroleum-based jet fuel widely used by the U.S. military. JP-8 specifications include parameters such as freeze point, density, flash point, and others; all of which were met by the EERC fuel sample. The fuel also exceeds the thermal stability specification of JP-8 fuel as determined by the quartz crystalline microbalance (QCM) test also performed at an independent laboratory as well as AFRL. This means that the EERC fuel looks and acts identically to petroleum-derived jet fuel and can be used interchangeably without any special requirements and thus provides a pathway to energy security to the U.S. military and the entire nation. This subtask was funded through the EERC–DOE Joint Program on Research and Development for Fossil Energy-Related Resources Cooperative Agreement No. DE-FC26- 08NT43291. Nonfederal funding was provided by Accelergy Corporation.« less

Gum formation tendencies of olefinic structures in gasoline and synergistic effect of sulphur compounds

DOE Office of Scientific and Technical Information (OSTI.GOV)

Nagpal, J.M.; Joshi, G.C.; Aswal, D.S.

1995-04-01

The high octane gasoline pool contains varying amounts of cracked naphthas as an important ingredient in formulating high octane lead free gasoline. The cracked naphthas are largely from Fluidized Catalytic Cracking (FCC) units and to lesser extend from thermal cracking units. While the role of olefinic unsaturation in gum formation during storage of gasoline has been extensively studied, there is little published work on contribution of individual olefin types in storage stability and gum formation tendency of gasoline containing these compound types. In the present work we report our results on storage stability and gum formation tendency of different olefinmore » types present in cracked naphthas through model compound matrix. It is found that cyclic olefins and cyclic diolefins are the most prolific gum formers. We have also studied the role of sulfur compounds present in the gasolines on gum formation tendency of olefins. While thiols enhance gum formation from all olefinic types, sulfides and disulfides interact depending on the structure of olefins. These can have either an accelerating, or inhibiting effect on gum formation.« less

Marketable transport fuels made from Julia Creek shale oil

DOE Office of Scientific and Technical Information (OSTI.GOV)

Not Available

1987-03-01

CSR Limited and the CSIRO Division of Energy Chemistry have been working on the problem of producing refined products from the Julia Creek deposit in Queensland, Australia. Two samples of shale oil, retorted at different temperatures from Julia Creek oil shale, were found to differ markedly in aromaticity. Using conventional hydrotreating technology, high quality jet and diesel fuels could be made from the less aromatic oil. Naphtha suitable for isomerization and reforming to gasoline could be produced from both oils. This paper discusses oil properties, stabilization of topped crudes, second stage hydrotreatment, and naphtha hydrotreating. 1 figure, 4 tables.

Novel electrochemical process for coal conversion

DOE Office of Scientific and Technical Information (OSTI.GOV)

Farooque, M.

1989-07-01

The feasibility of two distinctly different routes to coal conversion at low severity conditions was investigated. An electrochemical approach utilizing both the electro-oxidation and electro-reduction routes was employed. The electro-oxidation route consists of an electrochemical reaction involving H{sub 2}O and coal, leading to the breakup of coal molecules. The observed reaction rate has been explained as a combination of the coal and pyrite electro-oxidation currents. Organic sulfur has been identified as the contributing factor for the observation of more than 100% H{sub 2} production current efficiency with several coal samples. Also, an attractive coal pre-treatment process has been identified whichmore » results in production of useful products and simultaneous upgrading of the coal. Electrochemical oxidation of coal with H{sub 2}O leads to the production of hydrogen, CO{sub 2}, simultaneous removal of pyritic sulfur, and significant reduction of ash content. There is also indirect evidence that the organic sulfur may be removed in the process. A preliminary economic evaluation of this process has projected a cost advantage of > $8 per ton of Illinois {number sign}2 coal. A lab-scale cell has been successfully employed in this study for generating process data useful for future design calculations. This study also explored the electro-reduction route of coal conversion and has successfully demonstrated production of liquid products from different coal types at low severity conditions. A variety of aliphatic and aromatic compounds have been identified in the products. Coal type appeared to be the most important parameter affecting the product spectrum. 32 refs., 26 figs., 19 tabs.« less

HIGH PRESSURE COAL COMBUSTION KINETICS PROJECT

DOE Office of Scientific and Technical Information (OSTI.GOV)

Chris Guenther; Bill Rogers

2001-09-15

The HPCCK project was initiated with a kickoff meeting held on June 12, 2001 in Morgantown, WV, which was attended by all project participants. SRI's existing g-RCFR reactor was reconfigured to a SRT-RCFR geometry (Task 1.1). This new design is suitable for performing the NBFZ experiments of Task 1.2. It was decided that the SRT-RCFR apparatus could be modified and used for the HPBO experiments. The purchase, assembly, and testing of required instrumentation and hardware is nearly complete (Task 1.1 and 1.2). Initial samples of PBR coal have been shipped from FWC to SRI (Task 1.1). The ECT device formore » coal flow measurements used at FWC will not be used in the SRI apparatus and a screw type feeder has been suggested instead (Task 5.1). NEA has completed a upgrade of an existing Fluent simulator for SRI's RCFR to a version that is suitable for interpreting results from tests in the NBFZ configuration (Task 1.3) this upgrade includes finite-rate submodels for devolatilization, secondary volatiles pyrolysis, volatiles combustion, and char oxidation. Plans for an enhanced version of CBK have been discussed and development of this enhanced version has begun (Task 2.5). A developmental framework for implementing pressure and oxygen effects on ash formation in an ash formation model (Task 3.3) has begun.« less

Coal-oil coprocessing at HTI - development and improvement of the technology

DOE Office of Scientific and Technical Information (OSTI.GOV)

Stalzer, R.H.; Lee, L.K.; Hu, J.

1995-12-31

Co-Processing refers to the combined processing of coal and petroleum-derived heavy oil feedstocks. The coal feedstocks used are those typically utilized in direct coal liquefaction: bituminous, subbituminous, and lignites. Petroleum-derived oil, is typically a petroleum residuum, containing at least 70 W% material boiling above 525{degrees}C. The combined coal and oil feedstocks are processed simultaneously with the dual objective of liquefying the coal and upgrading the petroleum-derived residuum to lower boiling (<525{degrees}C) premium products. HTI`s investigation of the Co-Processing technology has included work performed in laboratory, bench and PDU scale operations. The concept of co-processing technology is quite simple and amore » natural outgrowth of the work done with direct coal liquefaction. A 36 month program to evaluate new process concepts in coal-oil coprocessing at the bench-scale was begun in September 1994 and runs until September 1997. Included in this continuous bench-scale program are provisions to examine new improvements in areas such as: interstage product separation, feedstock concentrations (coal/oil), improved supported/dispersed catalysts, optimization of reactor temperature sequencing, and in-line hydrotreating. This does not preclude other ideas from DOE contracts and other sources that can lead to improved product quality and economics. This research work has led to important findings which significantly increased liquid yields, improved product quality, and improved process economics.« less

Pilot Plant Program for the AED Advanced Coal Cleaning System. Phase II. Interim final report

DOE Office of Scientific and Technical Information (OSTI.GOV)

Not Available

1980-08-01

Advanced Energy Dynamics, Inc. (AED), has developed a proprietary coal cleaning process which employs a combination of ionization and electrostatic separation to remove both sulfur and ash from dry pulverized coal. The Ohio Department of Energy sponsored the first part of a program to evaluate, develop, and demonstrate the process in a continuous-flow pilot plant. Various coals used by Ohio electric utilities were characterized and classified, and sulfur reduction, ash reduction and Btu recovery were measured. Sulfur removal in various coals ranged from 33 to 68% (on a Btu basis). Ash removal ranged from 17 to 59% (on a Btumore » basis). Ash removal of particles greater than 53 microns ranged from 46 to 88%. Btu recovery ranged from 90 to 97%. These results, especially the large percentage removal of ash particles greater than 53 microns, suggest that the AED system can contribute materially to improved boiler performance and availability. The study indicated the following potential areas for commercial utilization of the AED process: installation between the pulverizer and boiler of conventional coal-fired power utilities; reclamation of fine coal refuse; dry coal cleaning to supplement, and, if necessary, to take the place of conventional coal cleaning; upgrading coal used in: (1) coal-oil mixtures, (2) gasification and liquefaction processes designed to handle pulverized coal; and (3) blast furnaces for making steel, as a fuel supplement to the coke. Partial cleaning of coking coal blends during preheating may also prove economically attractive. Numerous other industrial processes which use pulverized coal such as the production of activated carbon and direct reduction of iron ore may also benefit from the use of AED coal cleaning.« less

Reference News Release:Southern Coal Corporation to Make System-Wide Upgrades to Reduce Water Pollution from Mining Operations in Appalachia

EPA Pesticide Factsheets

The settlement also requires the establishment of a $4.5 million letter of credit and a standby trust that will guarantee sufficient funding for, and a mechanism to accomplish, compliance with the Clean Water Act and the work the companies.

Method for hydrocracking a heavy polynuclear hydrocarbonaceous feedstock in the presence of a molten metal halide catalyst

DOEpatents

Gorin, Everett

1981-01-01

A method for hydrocracking a heavy polynuclear hydrocarbonaceous feedstock to produce lighter hydrocarbon fuels by contacting the feedstock with hydrogen in the presence of a molten metal halide catalyst, the method comprising: mixing the feedstock with a heavy naphtha fraction which has an initial boiling point from about 100.degree. to about 160.degree. C. with a boiling point difference between the initial boiling point and the final boiling point of no more than about 50.degree. C. to produce a mixture; thereafter contacting the mixture with partially spent molten metal halide and hydrogen under temperature and pressure conditions so that the temperature is near the critical temperature of the heavy naphtha fraction; separating at least a portion of the heavy naphtha fraction and lighter hydrocarbon fuels from the partially spent molten metal halide, unreacted feedstock and reaction products; thereafter contacting the partially spent molten metal halide, unreacted feedstock and reaction products with hydrogen and fresh molten metal halide in a hydrocracking zone to produce additional lighter hydrocarbon fuels and separating at least a major portion of the lighter hydrocarbon fuels from the spent molten metal halide.

Development of decision- making mechanism in engineering design of phased coal mines technical upgrade

NASA Astrophysics Data System (ADS)

Kulak, V. Yu; Petrova, T. V.; Novichikhin, A. V.

2017-09-01

The approach to a choice of a new mine design and technical upgrade of operating coal mines is substantiated. The choice of the option is made in the following way: the elements of the mine technological system are defined, for each element of the system two levels of costs are allocated - capital and operational; a graph of alternative options of the system is formed by matrix enumeration taking into account the possibility of simultaneous application of different elements, up to 10 000 scenarios are formed; capital and operating costs of options are estimated in the form of coefficients as the cost-to-cost ratio in the base variant, which has already been implemented and the costs of which are already known; ranking of the options at the level of costs and the definition of the 10 preferred are performed. It is established that the application of partial enumeration allows the costs relative to the base variant to be reduced by 10 %; the main constraint of costs reduction is the need to comply with all conditions that ensure industrial safety.

Torrefaction of landfill food waste for possible application in biomass co-firing.

PubMed

Pahla, G; Ntuli, F; Muzenda, E

2018-01-01

Greenhouse gas emissions and municipal solid waste management have presented challenges globally. This study aims to produce a high-quality biochar with properties close to bituminous coal from landfill food waste (FW). FW was analyzed by proximate and ultimate analyses to determine its fuel properties and elemental composition before torrefaction. Temperature was varied from 200 to 300 °C at a constant residence time of 40 min and 10 °C/min heating rate. Calorific value, mass yield, energy yield and energy density were computed and used to determine the quality of the resulting biochar. Quality of raw food waste was also determined by elemental analysis. Thermal evolution was then investigated using hyphenated Thermogravimetric Analysis (TGA) and Fourier Transform Infra-Red Spectrometry (FTIR). Torrefaction was done at 225 °C, 275 °C and 300 °C. The calorific value was upgraded from 19.76 MJ/kg for dried raw food waste to 26.15 MJ/kg for torrefied food waste at the appropriate conditions which were 275 °C, 40 min and 10 °C/min. The higher heating value was comparable to that of bituminous coal from Anglo Mafube in South Africa. Elemental analysis of biochar showed an increase in carbon content with temperature due to loss of oxygen containing volatiles. This agreed with TG curves and FTIR spectra which confirmed release of H 2 O, CO and CO 2 . This resulted in a more hydrophobic solid fuel with high energy density. Food waste can therefore be upgraded to a biochar with similar fuel properties as pulverized coal used in coal fired boilers. Copyright © 2017 Elsevier Ltd. All rights reserved.

Hindered diffusion of coal liquids. Quarterly report No. 12, June 18, 1995--September 17, 1995

DOE Office of Scientific and Technical Information (OSTI.GOV)

Tsotsis, T.T.; Sahimi, M.; Webster, I.A.

1995-12-31

The design of industrial catalysts requires that the diffusivity of the reacting species within the catalyst be accurately known. Nowhere is this more important than in the area of coal liquefaction and upgrading of coal liquids. In this area one is faced with the task of processing a number of heavy oils, containing metals and other contaminants, in a variety of process dependent solvents. It is important, therefore, on the basis of predicting catalyst activity, selectivity, and optimizing reactor performance, that the diffusivities of these oil species be accurately known. It is the purpose of the project described here tomore » provide such a correct concept of coal asphaltenes by careful and detailed investigations of asphaltene transport through porous systems under realistic process temperature and pressure conditions. The experimental studies will be coupled with detailed, in-depth statistical and molecular dynamics models intended to provide a fundamental understanding of the overall transport mechanisms.« less

Liquefaction of black thunder coal with counterflow reactor technology

DOE Office of Scientific and Technical Information (OSTI.GOV)

Parker, R.J.; Simpson, P.L.

There is currently a resurgence of interest in the use of carbon monoxide and water to promote the solubilization of low rank coals in liquefaction processes. The mechanism for the water shift gas reaction (WGSR) is well documented and proceeds via a formate ion intermediate at temperatures up to about 400{degrees}C. Coal solubilization is enhanced by CO/H{sub 2}O and by the solvent effect of the supercritical water. The WGSR is catalyzed by bases (alkali metal carbonates, hydroxides, acetates, aluminates). Many inorganic salts which promote catalytic hydrogenation are rendered inactive in CO/H{sub 2}O, although there is positive evidence for the benefitmore » of using pyrite for both the WGSR and as a hydrogenation catalyst. The temperatures at which coal solubilization occurs are insufficient to promote extensive cracking or upgrading of the solubilized coal. Therefore, a two step process might achieve these two reactions sequentially. Alberta Research Council (ARC) has developed a two-stage process for the coprocessing of low rank coals and petroleum resids/bitumens. This process was further advanced by utilizing the counterflow reactor (CFR) concept pioneered by Canadian Energy Developments (CED) and ARC. The technology is currently being applied to coal liquefaction. The two-stage process employs CO/H{sub 2}O at relatively mid temperature and pressure to solubilize the coal, followed by a more severe hydrocracking step. This paper describes the results of an autoclave study conducted to support a bench unit program on the direct liquefaction of coals.« less

DOE Office of Scientific and Technical Information (OSTI.GOV)

Cada, G.F.

H-coal is a process for the direct liquefaction of coal to produce synthetic fuels. Its development has progressed from bench-scale testing through operation of a 2.7 Mg/d (3 ton/d) Process Development Unit. A large-scale H-Coal pilot plant is presently operating at Catlettsburg, Kentucky, and there are plans for the construction of a commercial H-Coal liquefaction facility by the end of the decade. Two of the environmental concerns of the developing direct coal liquefaction industry are accidental spills of synthetic oils and treatment/storage of solid wastes. As a means of obtaining preliminary information on the severity of these potential impacts wellmore » in advance of commercialization, samples of product oils and solid wastes were obtained from the H-Coal Process Development Unit (PDU). These samples were subjected to a battery of rapid screening tests, including chemical characterization and bioassays with a variety of aquatic and terrestrial organisms. Water-soluble fraction (WSFs) of H-Coal PDU oils had considerably higher concentrations of phenols and anilines and were commonly one to two orders of magnitude more toxic to aquatic organisms than WSFs of analogous petroleum crude oil. Whole H-Coal PDU oils were also more toxic to the cricket than petroleum-based oils, and some H-Coal samples showed evidence of teratogenicity. Leachates from H-Coal PDU solid wastes, on the other hand, had relatively low concentrations of selected elements and had essentially no acute toxicity to a variety of aquatic and terrestrial species. These studies indicate that environmental effects of product oil spills from a commercial H-Coal liquefaction plant are likely to be more severe than those of conventional petroleum spills. Product upgrading or special transportation and storage techniques may be needed to ensure environmentally sound commercialization of the H-Coal process.« less

[Value influence of different compatibilities of main active parts in yangyintongnao granule on pharmacokinetics parameters in rats with cerebral ischemia reperfusion injury by total amount statistic moment method].

PubMed

Guo, Ying; Yang, Jiehong; Znang, Hengyi; Fu, Xuchun; Zhnag, Yuyan; Wan, Haitong

2010-02-01

To study the influence of the different combinations of the main active parts in Yangyintongnao granule on the pharmacokinetics parameters of the two active components--ligustrazine and puerarin using the method of total amount statistic moment for pharmacokinetics. Combinations were formed according to the dosages of the four active parts (alkaloid, flavone, saponin, naphtha) by orthogonal experiment L9 (3(4)). Blood concentrations of ligustrazine and puerarin were determinated by HPLC at different time. Zero rank moment (AUC) and one rank moment (MRT, mean residence time) of ligustrazine and puerarin have been worked out to calculate the total amount statistic moment parameters was analyzed of Yangyintongnao granule by the method of the total amount statistic moment. The influence of different compatibilities on the pharmacokinetics parameters was analyzed by orthogonal test. Flavone has the strongest effect than saponin on the total AUC. Ligustrazine has the strongest effect on the total MRT. Saponin has little effect on the two parameters, but naphtha has more effect on both of them. It indicates that naphtha may promote metabolism of ligustrazine and puerarin in rat. Total amount statistic moment parameters can be used to guide for compatibilities of TCM.

Ways to Improve Russian Coal-Fired Power Plants

DOE Office of Scientific and Technical Information (OSTI.GOV)

Tumanovskii, A. G., E-mail: vti@vti.ru; Olkhovsky, G. G.

Coal is an important fuel for the electric power industry of Russia, especially in Ural and the eastern part of the country. It is fired in boilers of large (200 – 800 MW) condensing power units and in many cogeneration power plants with units rated at 50 – 180 MW. Many coal-fired power plants have been operated for more than 40 – 50 years. Though serviceable, their equipment is obsolete and does not comply with the current efficiency, environmental, staffing, and availability standards. It is urgent to retrofit and upgrade such power plants using advanced equipment, engineering and business ideas.more » Russian power-plant engineering companies have designed such advanced power units and their equipment such as boilers, turbines, auxiliaries, process and environmental control systems similar to those produced by the world’s leading manufacturers. Their performance and ways of implementation are discussed.« less

How DRB-XCL burners and air heater upgrade reduced NO sub x and improved efficiency at a western utility

DOE Office of Scientific and Technical Information (OSTI.GOV)

Becker, W.; Stalcup, T.; Schild, V.

1992-01-01

The Neil Simpson Unit is a 220,000 lb/hr pulverized coal boiler that was designed to fire a local Wyoming subbituminous coal. During the late 1980s, the Wyoming Department of Air Quality imposed emission limits on the Black Hills Power and Light Co., Neil Simpson Station. The new limits required Black Hills power to control not only particulate and sulfur dioxide (SO{sub 2}) emissions, but also nitrogen oxide (NO{sub x}) emissions. At the same time, Black Hills Power initiated an efficiency improvement study at Neil Simpson Station to investigate methods for reducing net electrical generation costs. This paper addresses the plantmore » efficiency and emissions studies, startup activities, the operating problems and successful operating solutions for NO{sub x} control when firing a Wyoming subbituminous coal. Also included is a summary of the post-0retrofit boiler performance data.« less

Coal Producer's Rubber Waste Processing Development

NASA Astrophysics Data System (ADS)

Makarevich, Evgeniya; Papin, Andrey; Nevedrov, Alexander; Cherkasova, Tatyana; Ignatova, Alla

2017-11-01

A large amount of rubber-containing waste, the bulk of which are worn automobile tires and conveyor belts, is produced at coal mining and coal processing enterprises using automobile tires, conveyor belts, etc. The volume of waste generated increases every year and reaches enormous proportions. The methods for processing rubber waste can be divided into three categories: grinding, pyrolysis (high and low temperature), and decomposition by means of chemical solvents. One of the known techniques of processing the worn-out tires is their regeneration, aimed at producing the new rubber substitute used in the production of rubber goods. However, the number of worn tires used for the production of regenerate does not exceed 20% of their total quantity. The new method for processing rubber waste through the pyrolysis process is considered in this article. Experimental data on the upgrading of the carbon residue of pyrolysis by the methods of heavy media separation, magnetic and vibroseparation, and thermal processing are presented.

Refinancing of the upgrade of heating conversion as a financial instrument used in Bytom community to reduce low emission

DOE Office of Scientific and Technical Information (OSTI.GOV)

Charchula, W.; Wojcik, G.

1995-12-31

High concentrations of SO{sub 2}, suspended particulates and benzo-{alpha}-pyrene measured in Bytom town especially during heating season result first of all from the process of coal combustion in households. The analysis of solutions aimed at the reduction of these concentrations was based upon the principles of maximization of the unit effect obtained understood as a cost spent by the town to reduce by a single unit the emission of pollutants into atmospheric air; implementation of tasks consistent to the {open_quotes}company mission{close_quotes} (formally: Master Plan of Environmental Protection for Bytom City) understood as actions aimed at the improvement of living standardsmore » of city residents and its value; and minimization of the investment risk under the free market circumstances. These principles resulted in the creation of a local law - Resolution of Bytom City Hall dated April 28, 1994 dealing with refinancing of the upgrade of space heating systems. Thus, as a result of this resolution, it appeared that the residents who implemented the conversion from coal to gas, oil or electricity are authorized to apply for partial refund of capital costs incurred by themselves.« less

The role of the resid solvent in coprocessing

DOE Office of Scientific and Technical Information (OSTI.GOV)

Curtis, C.W.

1995-12-31

The objective of this project is to determine the role of petroleum resid in coprocessing of coal and resid. The question being asked is whether the resid is a reactant in the system or whether the resid is a merely a diluent that is being simultaneously upgraded? To fulfill the objective the hydrogen transfer from model compounds, naphthenes that represent petroleum resids to model acceptors is being determined. The specificity of different catalytic systems for promoting the hydrogen transfer from naphthenes to model acceptors and to coal is also being determined. In addition the efficacy of hydrogen transfer from andmore » solvancy of whole and specific resid fractions under coprocessing conditions is being determined.« less

Selected worldwide coal activities of the U.S. Geological Survey, with emphasis on their environmental applications

DOE Office of Scientific and Technical Information (OSTI.GOV)

SanFilipo, J.R.; Warwick, P.D.

1995-12-31

Many of the underdeveloped and developing nations of the world face severe shortages of energy fuels, and many of the industrialized nations that are abandoning centrally-planned economies face collapsing energy distribution networks. These energy-poor nations are typically among the most environmentally stressed. This results in part from the direct effects of outmoded energy technologies and the low quality of available fuel, but it is also a result of the poverty and lack of social and technological infrastructure that invariably attends energy deficits. For such nations, the orderly development of underutilized indigenous coal resources and the upgrading of existing coal technologiesmore » can lead to economically viable sources of energy that are relatively benign from an environmental standpoint, and can contribute to long-term political stability as well. The US Geological Survey has participated in coal studies in a variety of such international settings in recent years. Most of these studies have been commodity related, focusing on coal resource assessments in nations with acute energy shortages and coal quality studies in areas where development has had recognizable environmental impacts. Training of counterparts from the host countries and the transfer of technology are an integral part of the international programs, with the primary goal of developing the ability of the host country to integrate geosciences into energy-policy decision-making.« less

Technologies for Upgrading Light Water Reactor Outlet Temperature

DOE Office of Scientific and Technical Information (OSTI.GOV)

Daniel S. Wendt; Piyush Sabharwall; Vivek Utgikar

Nuclear energy could potentially be utilized in hybrid energy systems to produce synthetic fuels and feedstocks from indigenous carbon sources such as coal and biomass. First generation nuclear hybrid energy system (NHES) technology will most likely be based on conventional light water reactors (LWRs). However, these LWRs provide thermal energy at temperatures of approximately 300°C, while the desired temperatures for many chemical processes are much higher. In order to realize the benefits of nuclear hybrid energy systems with the current LWR reactor fleets, selection and development of a complimentary temperature upgrading technology is necessary. This paper provides an initial assessmentmore » of technologies that may be well suited toward LWR outlet temperature upgrading for powering elevated temperature industrial and chemical processes during periods of off-peak power demand. Chemical heat transformers (CHTs) are a technology with the potential to meet LWR temperature upgrading requirements for NHESs. CHTs utilize chemical heat of reaction to change the temperature at which selected heat sources supply or consume thermal energy. CHTs could directly utilize LWR heat output without intermediate mechanical or electrical power conversion operations and the associated thermodynamic losses. CHT thermal characteristics are determined by selection of the chemical working pair and operating conditions. This paper discusses the chemical working pairs applicable to LWR outlet temperature upgrading and the CHT operating conditions required for providing process heat in NHES applications.« less

Improving Competitiveness of U.S. Coal Dialogue

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kokkinos, Angelos

The Improving Competitiveness of U.S. Coal Dialogue held in September 2017 explored a broad range of technical developments that have the potential to improve U.S. coal competitiveness in domestic and overseas markets. The workshop is one in a series of events hosted by DOE to gather expert input on challenges and opportunities for reviving the coal economy. This event brought together coal industry experts to review developments in a broad range of technical areas such as conventional physical (e.g. dense-medium) technologies, and dry coal treatments; thermal, chemical, and bio-oxidation coal upgrading technologies; coal blending; and applications for ultrafine coal andmore » waste streams. The workshop was organized to focus on three main discussion topics: Challenges and Opportunities for Improving U.S. Coal Competitiveness in Overseas Markets, Mineral Processing, and Technologies to Expand the Market Reach of Coal Products. In each session, invited experts delivered presentations to help frame the subsequent group discussion. Throughout the discussions, participants described many possible areas of research and development (R&D) in which DOE involvement could help to produce significant outcomes. In addition, participants discussed a number of open questions—those that the industry has raised or investigated but not yet resolved. In discussing the three topics, the participants suggested potential areas of research and issues for further investigation. As summarized in Table ES-1, these crosscutting suggestions centered on combustion technologies, coal quality, coal processing, environmental issues, and other issues. The discussions at this workshop will serve as an input that DOE considers in developing initiatives that can be pursued by government and industry. This workshop generated strategies that described core research concepts, identified implementation steps, estimated benefits, clarified roles of government and industry, and outlined next steps. While more work is needed, each of these initiatives, included in the sections that follow, details new ideas to increase efficiency and reduce carbon emissions. DOE will integrate the results of this workshop with ongoing research work at the National Laboratories as well as other relevant data sources. This combined information will be used to develop a comprehensive strategy for capitalizing on the opportunity for U.S. coal and mineral competitiveness.« less

21 CFR 172.250 - Petroleum naphtha.

Code of Federal Regulations, 2010 CFR

2010-04-01

... at room temperature, with intermittent swirling. At the end of this time, disconnect the flask and.... Dissolve the crystals in the flask with about 25 milliliters of distilled water and pour this also into the...

21 CFR 172.250 - Petroleum naphtha.

Code of Federal Regulations, 2011 CFR

2011-04-01

... at room temperature, with intermittent swirling. At the end of this time, disconnect the flask and.... Dissolve the crystals in the flask with about 25 milliliters of distilled water and pour this also into the...

21 CFR 172.250 - Petroleum naphtha.

Code of Federal Regulations, 2014 CFR

2014-04-01

.... At the end of this time, disconnect the flask and evaporate the methyl alcohol on the steam bath... transfer the isooctane extract to a 250-milliliter separatory funnel. Dissolve the crystals in the flask...

21 CFR 172.250 - Petroleum naphtha.

Code of Federal Regulations, 2012 CFR

2012-04-01

... at room temperature, with intermittent swirling. At the end of this time, disconnect the flask and.... Dissolve the crystals in the flask with about 25 milliliters of distilled water and pour this also into the...

21 CFR 172.250 - Petroleum naphtha.

Code of Federal Regulations, 2013 CFR

2013-04-01

... at room temperature, with intermittent swirling. At the end of this time, disconnect the flask and.... Dissolve the crystals in the flask with about 25 milliliters of distilled water and pour this also into the...

Development of the Write Process for Pipeline-Ready Heavy Oil

DOE Office of Scientific and Technical Information (OSTI.GOV)

Lee Brecher; Charles Mones; Frank Guffey

Work completed under this program advances the goal of demonstrating Western Research Institute's (WRI's) WRITE{trademark} process for upgrading heavy oil at field scale. MEG Energy Corporation (MEG) located in Calgary, Alberta, Canada supported efforts at WRI to develop the WRITE{trademark} process as an oil sands, field-upgrading technology through this Task 51 Jointly Sponsored Research project. The project consisted of 6 tasks: (1) optimization of the distillate recovery unit (DRU), (2) demonstration and design of a continuous coker, (3) conceptual design and cost estimate for a commercial facility, (4) design of a WRITE{trademark} pilot plant, (5) hydrotreating studies, and (6) establishmore » a petroleum analysis laboratory. WRITE{trademark} is a heavy oil and bitumen upgrading process that produces residuum-free, pipeline ready oil from heavy material with undiluted density and viscosity that exceed prevailing pipeline specifications. WRITE{trademark} uses two processing stages to achieve low and high temperature conversion of heavy oil or bitumen. The first stage DRU operates at mild thermal cracking conditions, yielding a light overhead product and a heavy residuum or bottoms material. These bottoms flow to the second stage continuous coker that operates at severe pyrolysis conditions, yielding light pyrolyzate and coke. The combined pyrolyzate and mildly cracked overhead streams form WRITE{trademark}'s synthetic crude oil (SCO) production. The main objectives of this project were to (1) complete testing and analysis at bench scale with the DRU and continuous coker reactors and provide results to MEG for process evaluation and scale-up determinations and (2) complete a technical and economic assessment of WRITE{trademark} technology to determine its viability. The DRU test program was completed and a processing envelope developed. These results were used for process assessment and for scaleup. Tests in the continuous coker were intended to determine the throughput capability of the coker so a scaled design could be developed that maximized feed rate for a given size of reactor. These tests were only partially successful because of equipment problems. A redesigned coker, which addressed the problems, has been build but not operated. A preliminary economic analysis conducted by MEG and an their engineering consultant concluded that the WRITE{trademark} process is a technically feasible method for upgrading bitumen and that it produces SCO that meets pipeline specifications for density. When compared to delayed coking, the industry benchmark for thermal upgrading of bitumen, WRITE{trademark} produced more SCO, less coke, less CO{sub 2} per barrel of bitumen fed, and had lower capital and operating costs. On the other hand, WRITE{trademark}'s lower processing severity yielded crude with higher density and a different product distribution for naphtha, light gas oil and vacuum oil that, taken together, might reduce the value of the SCO. These issues plus the completion of more detailed process evaluation and economics need to be resolved before WRITE{trademark} is deployed as a field-scale pilot.« less

Control of mercury emissions from stationary coal combustion sources in China: Current status and recommendations.

PubMed

Hu, Yuanan; Cheng, Hefa

2016-11-01

Coal burning in power plants and industrial boilers is the largest combustion source of mercury emissions in China. Together, power plants and industrial boilers emit around 250 tonnes of mercury each year, or around half of atmospheric mercury emissions from anthropogenic sources in the country. Power plants in China are generally equipped with multi-pollutant control technologies, which offer the co-benefit of mercury removal, while mercury-specific control technologies have been installed in some facilities. In contrast, most industrial boilers have only basic or no flue gas cleaning. A combination of measures, including energy conservation, coal switching and blending, reducing the mercury contents of coals through washing, combustion controls, and flue gas cleaning, can be used to reduce mercury emissions from these stationary combustion sources. More stringent emission standards for the major air pollutants from coal-fired power plants and industrial boiler, along with standards for the previously unregulated mercury, were implemented recently, which is expected to bring significant reduction in their mercury emissions through the necessary upgrades of multi-pollutant and mercury-specific control technologies. Meanwhile, strong monitoring capacity and strict enforcement are necessary to ensure that the combustion sources operate in compliance with the new emission standards and achieve significant reduction in the emissions of mercury and other air pollutants. Copyright © 2016 Elsevier Ltd. All rights reserved.

Commercial-scale demonstration of the Liquid Phase Methanol process. Technical progress report number 8, April 1--June 30, 1996

DOE Office of Scientific and Technical Information (OSTI.GOV)

NONE

1996-12-31

The project involves the construction of an 80,000 gallon per day (260 tons per day (TPD)) methanol unit utilizing coal-derived synthesis gas from Eastman`s integrated coal gasification facility. The new equipment consists of synthesis gas feed preparation and compression facilities, the liquid phase reactor and auxiliaries, product distillation facilities, and utilities. The technology to be demonstrated is the product of a cooperative development effort by Air Products and DOE in a program that started in 1981. Developed to enhance electric power generation using integrated gasification combined cycle (IGCC) technology, the LPMEOH{trademark} process is ideally suited for directly processing gases producedmore » by modern-day coal gasifiers. Originally tested at a small (10 TPD), DOE-owned experimental unit in LaPorte, Texas, the technology provides several improvements essential for the economic coproduction of methanol and electricity directly from gasified coal. This liquid phase process suspends fine catalyst particles in an inert liquid, forming a slurry. The slurry dissipates the heat of the chemical reaction away from the catalyst surface, protecting the catalyst and allowing the methanol synthesis reaction to proceed at higher rates. At the Eastman complex, the technology is being integrated with existing coal-gasifiers. A carefully developed test plan will allow operations at Eastman to simulate electricity demand load-following in coal-based IGCC facilities. The operations will also demonstrate the enhanced stability and heat dissipation of the conversion process, its reliable on/off operation, and its ability to produce methanol as a clean liquid fuel without additional upgrading.« less

Pipeline transportation of upgraded Yugoslavian lignite fuels

DOE Office of Scientific and Technical Information (OSTI.GOV)

Ljubicic, B.; Anderson, C.; Bukurov, Z.

1993-12-31

Hydraulic transport and handling procedures for coal are not widely used, but when practiced, they result in a technically and economically successful operation. Potentially the most attractive way to utilize lignitic coals for power generation would be to combine hydraulic mining techniques with aqueous ash removal, hydrothermal processing, solids concentration, and coal-water fuel (CWF) combustion. Technical and economic assessment of this operation is being implemented within the Yugoslavian-American Scientific Technical Cooperation Agreement. The Energy and Environmental Research Center (EERC), Grand Forks, North Dakota, with support from the U.S. Department of Energy, has entered into a jointly sponsored research project withmore » Electric Power of Serbia (EPS), Belgrade, Yugoslavia, to investigate the application of the nonevaporative hydrothermal drying procedure, commonly called hot-water drying (HWD), developed at the EERC, to the lignite from the Kovin deposit. Advances in hydrothermal treatment of low-rank coals (LRCs) at the EERC have enabled cheaper, more reactive LRCs to be used in coal-water fuels (CWFs). HWD is a high-temperature, nonevaporative drying technique carried out at high pressure in water that permanently alters the structure of LRC. It solves the stability problems by producing a safe, easily transported, liquid fuel that can be handled and used like oil. For continued or increased success, it is necessary to evaluate carefully all aspects of slurry technology that permit further optimization. This paper discusses some aspects of low-rank coal hydraulic transport combined with hydrothermal treatment as an alternative energy solution toward less oil dependence in Yugoslavia.« less

Coal-oil gold agglomeration assisted flotation to recover gold from refractory ore

NASA Astrophysics Data System (ADS)

Otsuki, A.; Yue, C.

2017-07-01

This study aimed to investigate the applicability of coal-oil gold agglomeration (CGA) assisted flotation to recover gold from a refractory ore. The ore with the grade of 2-5 g/t was tested with the CGA-flotation process in six different size fractions from 38 to 300 urn using different collector types and dosages. In addition, the flotation without CGA was performed under the same condition for comparison. The results showed that the higher gold grade and recovery were achieved by applying the CGA-flotation, compared with the flotation without CGA. More than 20-60 times grade increase from the head grade was obtained with CGA-flotation. The elemental analysis of gold and sulphur explained their relationship with gold recovery. The results well indicated the applicability of CGA to upgrade the refractory gold ore.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Fred D. Brent; Lalit Shah; Earl Berry

The overall objective of this project is the three phase development of an Early Entrance Coproduction Plant (EECP) which uses petroleum coke to produce at least one product from at least two of the following three categories: (1) electric power (or heat), (2) fuels, and (3) chemicals using ChevronTexaco's proprietary gasification technology. The objective of Phase I is to determine the feasibility and define the concept for the EECP located at a specific site; develop a Research, Development, and Testing (RD&T) Plan to mitigate technical risks and barriers; and prepare a Preliminary Project Financing Plan. The objective of Phase IImore » is to implement the work as outlined in the Phase I RD&T Plan to enhance the development and commercial acceptance of coproduction technology. The objective of Phase III is to develop an engineering design package and a financing and testing plan for an EECP located at a specific site. The project's intended result is to provide the necessary technical, economic, and environmental information needed by industry to move the EECP forward to detailed design, construction, and operation. The partners in this project are Texaco Energy Systems LLC or TES (a subsidiary of ChevronTexaco), General Electric (GE), Praxair, and Kellogg Brown & Root (KBR) in addition to the U.S. Department of Energy (DOE). TES is providing gasification technology and Fischer-Tropsch (F-T) technology developed by Rentech, GE is providing combustion turbine technology, Praxair is providing air separation technology, and KBR is providing engineering. Each of the EECP subsystems was assessed for technical risks and barriers. A plan was developed to mitigate the identified risks (Phase II RD&T Plan, October 2000). The potential technical and economic risks to the EECP from Task 2.5 can be mitigated by demonstrating that the end-use products derived from the upgrading of the F-T synthesis total liquid product can meet or exceed current specifications for the manufacture of ethylene and propylene chemicals from F-T naphtha, for the generation of hydrogen from F-T naphtha to power fuel cells, for direct blending of F-T diesels into transportation fuels, for the conversion of F-T heavy product wax to transportation fuels, and the conversion of F-T Heavy product wax to a valuable high melting point food-grade specialty wax product. Product evaluations conducted under Task 2.5 of Phase II successfully mitigated the above technical and economic risks to the EECP with the development of product yields and product qualities for the production of chemicals, transportation fuels, and specialty food-grade waxes from the F-T synthesis products.« less

Upgrading of consumer characteristics of granulated solid fuel from mixture of low-grade coal and biomass

NASA Astrophysics Data System (ADS)

Kuzmina, J. S.; Milovanov, O. Yu; Sinelshchikov, V. A.; Sytchev, G. A.; Zaichenko, V. M.

2015-11-01

Effect of torrefaction on consumer characteristics of fuel pellets made of low-grade and agricultural waste is shown. Data on the volatile content, ash content, calorific value and hygroscopicity for initial pellets and pellets, heat-treated at various temperatures are presented. The experimental study of the combustion process of initial and heat-treated pellets showed that torrefaction of pellets leads to a decreasing of the ignition temperature and an increasing of the efficiency of boiler plant.

Capturing CO2 from Coal-Fired Power Plants: Challenges for a Comprehensive Strategy

DTIC Science & Technology

2008-08-15

efficient flue gas desulfurization (FGD) or selective catalytic reduction (SCR) devices (or none), requiring either upgrading of existing FGD and SCR...saturated flue Figure 6. CO2 Price Projections CRS-16 42 Donald Shattuck, et al., A History of Flue Gas Desulfurization (FGD) — The Early Years, UE Technical...available in both the eastern and western parts of the United States, or by the use of emerging flue gas desulfurization (FGD) devices.46 At the time

SIMULATION OF ECOLOGICALLY CONSCIOUS CHEMICAL PROCESSES: FUGITIVE EMISSIONS VERSUS OPERATING CONDITIONS

EPA Science Inventory

Catalytic reforming is an important refinery process for the conversion of low-octane naphtha (mostly paraffins) into high-octane motor fuels (isoparaffins, naphthenes and aromatics), light gases and hydrogen. In this study the catalytic reforming process is analyzed under differ...

Detection of antistripping additives with quick bottle test.

DOT National Transportation Integrated Search

1980-01-01

Several variations of the quick bottle test were evaluated to determine the procedure having the best repeatability. Naphtha was selected over kerosene and white gas as the solvent for use in the test, and room temperature was selected over 140F as...

PRODUCTION AND SCREENING OF CARBON PRODUCTS PRECURSORS FROM COAL

DOE Office of Scientific and Technical Information (OSTI.GOV)

Caulton L. Irwin

2001-05-31

The authors have examined effects of blending a raw coal extract (EXT) with an extracted coal-tar pitch (ECTP). Previous reports were concerned with the addition of 15 wt% EXT, or less, on the physical characteristics of the blend and on the development of optical texture following carbonization. Two additional blends of ECTP and EXT were prepared at the 30 and 50 wt% EXT content using a procedure already described. The characteristics of the blends are presented. The density for these blended materials is not much different than the density for the blends reported earlier. The softening point temperature for themore » 30 wt% EXT increased to over 200 C while the softening point temperature for the 50 wt% EXT blend was too high to be determined by the Mettler method. Coke yields approximately follow the law of mixtures. The optical texture of the green cokes for the 30 and 50 wt% EXT blends is shown. Though the optical texture of the green cokes was not significantly affected where the level of EXT is 15 wt% or less, larger proportions of EXT exert a marked reduction in anisotropy. The co-processing of coal with petroleum residues or other heavy hydrocarbons at elevated temperature and pressure has received considerable attention in the research community as a means to upgrade simultaneously coal and byproducts. Heavy hydrocarbons can function as sources of hydrogen, as well as performing as a medium for dissolution and dispersion of coal fragments. However, the focus of much of the prior research has been on developing fuels, distillable liquids, or synthetic crudes. Comparatively little effort has been deliberately directed toward the production of heavier, non-distillable materials which could perform as binder and extender pitches, impregnants, or feedstocks for cokes and other carbons.« less

National-level infrastructure and economic effects of switchgrass cofiring with coal in existing power plants for carbon mitigation.

PubMed

Morrow, William R; Griffin, W Michael; Matthews, H Scott

2008-05-15

We update a previously presented Linear Programming (LP) methodology for estimating state level costs for reducing CO2 emissions from existing coal-fired power plants by cofiring switchgrass, a biomass energy crop, and coal. This paper presents national level results of applying the methodology to the entire portion of the United States in which switchgrass could be grown without irrigation. We present incremental switchgrass and coal cofiring carbon cost of mitigation curves along with a presentation of regionally specific cofiring economics and policy issues. The results show that cofiring 189 million dry short tons of switchgrass with coal in the existing U.S. coal-fired electricity generation fleet can mitigate approximately 256 million short tons of carbon-dioxide (CO2) per year, representing a 9% reduction of 2005 electricity sector CO2 emissions. Total marginal costs, including capital, labor, feedstock, and transportation, range from $20 to $86/ton CO2 mitigated,with average costs ranging from $20 to $45/ton. If some existing power plants upgrade to boilers designed for combusting switchgrass, an additional 54 million tons of switchgrass can be cofired. In this case, total marginal costs range from $26 to $100/ton CO2 mitigated, with average costs ranging from $20 to $60/ton. Costs for states east of the Mississippi River are largely unaffected by boiler replacement; Atlantic seaboard states represent the lowest cofiring cost of carbon mitigation. The central plains states west of the Mississippi River are most affected by the boiler replacement option and, in general, go from one of the lowest cofiring cost of carbon mitigation regions to the highest. We explain the variation in transportation expenses and highlight regional cost of mitigation variations as transportation overwhelms other cofiring costs.

Design and operation experience of 230 MWe CFB boilers at Turow power plant in Poland

DOE Office of Scientific and Technical Information (OSTI.GOV)

Nowak, W.; Bis, Z.; Laskawiec, J.

The Power Station Turow is located in Bogatynia, Poland, and has operated 10 pulverized coal units each of 200 MW. The plant provided 2000 MW at the lowest cost per kWh in Poland. The Turow units have approached and in some cases already gone beyond their 25--30 year's design life. To meet Poland's new environmental standards, which are now compatible with the EU, Turow decided to replace and upgrade six units (No. 1 to 6) from 200 MW to 230 MW units and remove one unit No. 7. Units No. 8, 9 and 10 were equipped with dry sorbent desulfurizationmore » technology. Units No. 1 and 2 have been replaced with new clean coal circulating fluidized bed technology. The Power Station Turow with six CFB units is to be the largest in the world power station based on fluidized bed technology.« less

Handbook for Evaluating Ecological Effects of Pollution at DARCOM installations. Volume 2, Essential Background Data. (Installation Environmental Impact Assessment)

DTIC Science & Technology

1979-12-01

Nitrates Sulfur dioxide Xylene Nitrites Oxides of nitrogen Mercaptans "Red Water" Carbon monoxide Chlorine Acids: Ketones Fluorine Hydrochloric Esters...Trichloroethylene Varnishes Methylchloroform Undercoatings Mineral spirits Liquid styrene Naphtha Adhesives Halgenated hydrocarbons Nonmethane hydrocarbons

Carbon emissions due to deforestation for the production of charcoal used in Brazil’s steel industry

NASA Astrophysics Data System (ADS)

Sonter, Laura J.; Barrett, Damian J.; Moran, Chris J.; Soares-Filho, Britaldo S.

2015-04-01

Steel produced using coal generates 7% of global anthropogenic CO2 emissions annually. Opportunities exist to substitute this coal with carbon-neutral charcoal sourced from plantation forests to mitigate project-scale emissions and obtain certified emission reduction credits under the Kyoto Protocol’s Clean Development Mechanism. This mitigation strategy has been implemented in Brazil and is one mechanism among many used globally to reduce anthropogenic CO2 emissions; however, its potential adverse impacts have been overlooked to date. Here, we report that total CO2 emitted from Brazilian steel production doubled (91 to 182 MtCO2) and specific emissions increased (3.3 to 5.2 MtCO2 per Mt steel) between 2000 and 2007, even though the proportion of coal used declined. Infrastructure upgrades and a national plantation shortage increased industry reliance on charcoal sourced from native forests, which emits up to nine times more CO2 per tonne of steel than coal. Preventing use of native forest charcoal could have avoided 79% of the CO2 emitted from steel production between 2000 and 2007; however, doing so by increasing plantation charcoal supply is limited by socio-economic costs and risks further indirect deforestation pressures and emissions. Effective climate change mitigation in Brazil’s steel industry must therefore minimize all direct and indirect carbon emissions generated from steel manufacture.

Role of the Liquids From Coal process in the world energy picture

DOE Office of Scientific and Technical Information (OSTI.GOV)

Frederick, J.P.; Knottnerus, B.A.

1997-12-31

ENCOAL Corporation, a wholly owned indirect subsidiary of Zeigler Coal Holding Company, has essentially completed the demonstration phase of a 1,000 Tons per day (TPD) Liquids From Coal (LFC{trademark}) plant near Gillette, Wyoming. The plant has been in operation for 4{1/2} years and has delivered 15 unit trains of Process Derived Fuel (PDF{trademark}), the low-sulfur, high-Btu solid product to five major utilities. Recent test burns have indicated the PDF{trademark} can offer the following benefits to utility customers: lower sulfur emissions, lower NO{sub x} emissions, lower utilized fuel costs to power plants, and long term stable fuel supply. More than threemore » million gallons of Coal Derived Liquid (CDL{trademark}) have also been delivered to seven industrial fuel users and one steel mill blast furnace. Additionally, laboratory characteristics of CDL{trademark} and process development efforts have indicated that CDL{trademark} can be readily upgraded into higher value chemical feedstocks and transportation fuels. Commercialization of the LFC{trademark} is also progressing. Permit work for a large scale commercial ENCOAL{reg_sign} plant in Wyoming is now underway and domestic and international commercialization activity is in progress by TEK-KOL, a general partnership between SGI International and a Zeigler subsidiary. This paper covers the historical background of the project, describes the LFC{trademark} process and describes the worldwide outlook for commercialization.« less

Chemistry and catalysis of coal liquefaction catalytic and thermal upgrading of coal liquid and hydrogenation of CO to produce fuels. Quarterly progress report, July-September 1980

DOE Office of Scientific and Technical Information (OSTI.GOV)

Wiser, W.H.

1981-02-01

Studies on the basic properties of supported sulfide catalysts showed that different supports have a profound influence on catalytic activities of CoMo catalysts. The three functions of hydrodesulfurization, hydrogenation and cracking were differently affected depending on the support used and the manner of preparation of the catalyst. Also, incorporation of additives to the support showed that the different catalytic functions can be selectively affected. A systematic study concerned with catalytic cracking of coal-derived liquids, viz., an SRC-II middle-heavy distillate and four hydrotreated SRC-II products was carried out in the range of 375 to 500/sup 0/C (LHSV, 0.2 to 3.9 h/supmore » -1/). Hydrotreatment, even to a limited extent, results in a remarkable improvement in the yield of gasoline-range products from the SRC-II distillate. This improvement is ascribed to: (a) hydrogenolysis reactions leading to lower molecular weight feedstock components and (b) limited hydrogenation of aromatic rings leading to polycyclic feed components with sufficient concentration of hydroaromatic rings needed for effective cracking. The results with model compounds and the data on hydrogen consumption during hydrotreatment of SRC-II liquids indicate that for tricyclic, tetracyclic, and pentacyclic coal-liquid components the optimal concentration of hydroaromatic rings for effective subsequent cracking is at least two rings per molecule.« less

Hydrogen donor solvent coal liquefaction process

DOEpatents

Plumlee, Karl W.

1978-01-01

An indigenous hydrocarbon product stream boiling within a range of from about C.sub.1 -700.degree. F., preferably C.sub.1 -400.degree. F., is treated to produce an upgraded hydrocarbon fuel component and a component which can be recycled, with a suitable donor solvent, to a coal liquefaction zone to catalyze the reaction. In accordance therewith, a liquid hydrocarbon fraction with a high end boiling point range up to about 700.degree. F., preferably up to about 400.degree. F., is separated from a coal liquefaction zone effluent, the separated fraction is contacted with an alkaline medium to provide a hydrocarbon phase and an aqueous extract phase, the aqueous phase is neutralized, and contacted with a peroxygen compound to convert indigenous components of the aqueous phase of said hydrocarbon fraction into catalytic components, such that the aqueous stream is suitable for recycle to the coal liquefaction zone. Naturally occurring phenols and alkyl substituted phenols, found in the aqueous phase, are converted, by the addition of hydroxyl constituents to phenols, to dihydroxy benzenes which, as disclosed in copending Application Ser. Nos. 686,813 now U.S. Pat. No. 4,049,536; 686,814 now U.S. Pat. No. 4,049,537; 686,827 now U.S. Pat. No. 4,051,012 and 686,828, K. W. Plumlee et al, filed May 17, 1976, are suitable hydrogen transfer catalysts.

Direct liquefaction proof-of-concept facility

DOE Office of Scientific and Technical Information (OSTI.GOV)

Alfred G. Comolli; Peizheng Zhou; HTI Staff

2000-01-01

The main objective of the U.S. DOE, Office of Fossil Energy, is to ensure the US a secure energy supply at an affordable price. An integral part of this program was the demonstration of fully developed coal liquefaction processes that could be implemented if market and supply considerations so required, Demonstration of the technology, even if not commercialized, provides a security factor for the country if it is known that the coal to liquid processes are proven and readily available. Direct liquefaction breaks down and rearranges complex hydrocarbon molecules from coal, adds hydrogen, and cracks the large molecules to thosemore » in the fuel range, removes hetero-atoms and gives the liquids characteristics comparable to petroleum derived fuels. The current processes being scaled and demonstrated are based on two reactor stages that increase conversion efficiency and improve quality by providing the flexibility to adjust process conditions to accommodate favorable reactions. The first stage conditions promote hydrogenation and some oxygen, sulfur and nitrogen removal. The second stage hydrocracks and speeds the conversion to liquids while removing the remaining sulfur and nitrogen. A third hydrotreatment stage can be used to upgrade the liquids to clean specification fuels.« less

Fuel and fuel blending components from biomass derived pyrolysis oil

DOEpatents

McCall, Michael J.; Brandvold, Timothy A.; Elliott, Douglas C.

2012-12-11

A process for the conversion of biomass derived pyrolysis oil to liquid fuel components is presented. The process includes the production of diesel, aviation, and naphtha boiling point range fuels or fuel blending components by two-stage deoxygenation of the pyrolysis oil and separation of the products.

Toxic Hazards Research Unit Annual Technical Report: 1985

DTIC Science & Technology

1985-09-01

varnish makers’ and painters’ naphtha, Toxicol. Appl. Pharmacol., 32:263-281. Carpenter, C. P.. E. R. Kinkead, D. L. Geary, L. J. Sullivan, Jr., and J...and Pharmacology of Inorganic and Fluorine Contairnin Compounds, AMRL-TR-67-224, Aerospace Medical Research Laboiatory, Wright-Patterson Air Force Base

10 CFR 205.12 - Addresses for filing documents with the DOE.

Code of Federal Regulations, 2011 CFR

2011-01-01

...: Crude oil 10 Naphtha and gas oil 15 Propane, butane and natural gasoline 25 Other products 30 Bunker... Section 205.12 Energy DEPARTMENT OF ENERGY OIL ADMINISTRATIVE PROCEDURES AND SANCTIONS General Provisions..., DC 20036. (9) Documents to be filed with the Director of Oil Imports, as provided in this part or...

10 CFR 205.12 - Addresses for filing documents with the DOE.

Code of Federal Regulations, 2010 CFR

2010-01-01

...: Crude oil 10 Naphtha and gas oil 15 Propane, butane and natural gasoline 25 Other products 30 Bunker... Section 205.12 Energy DEPARTMENT OF ENERGY OIL ADMINISTRATIVE PROCEDURES AND SANCTIONS General Provisions..., DC 20036. (9) Documents to be filed with the Director of Oil Imports, as provided in this part or...

10 CFR 205.12 - Addresses for filing documents with the DOE.

Code of Federal Regulations, 2013 CFR

2013-01-01

...: Crude oil 10 Naphtha and gas oil 15 Propane, butane and natural gasoline 25 Other products 30 Bunker... Section 205.12 Energy DEPARTMENT OF ENERGY OIL ADMINISTRATIVE PROCEDURES AND SANCTIONS General Provisions..., DC 20036. (9) Documents to be filed with the Director of Oil Imports, as provided in this part or...

10 CFR 205.12 - Addresses for filing documents with the DOE.

Code of Federal Regulations, 2012 CFR

2012-01-01

...: Crude oil 10 Naphtha and gas oil 15 Propane, butane and natural gasoline 25 Other products 30 Bunker... Section 205.12 Energy DEPARTMENT OF ENERGY OIL ADMINISTRATIVE PROCEDURES AND SANCTIONS General Provisions..., DC 20036. (9) Documents to be filed with the Director of Oil Imports, as provided in this part or...

10 CFR 205.12 - Addresses for filing documents with the DOE.

Code of Federal Regulations, 2014 CFR

2014-01-01

...: Crude oil 10 Naphtha and gas oil 15 Propane, butane and natural gasoline 25 Other products 30 Bunker... Section 205.12 Energy DEPARTMENT OF ENERGY OIL ADMINISTRATIVE PROCEDURES AND SANCTIONS General Provisions..., DC 20036. (9) Documents to be filed with the Director of Oil Imports, as provided in this part or...

Microbial communities involved in methane production from hydrocarbons in oil sands tailings.

PubMed

Siddique, Tariq; Penner, Tara; Klassen, Jonathan; Nesbø, Camilla; Foght, Julia M

2012-09-04

Microbial metabolism of residual hydrocarbons, primarily short-chain n-alkanes and certain monoaromatic hydrocarbons, in oil sands tailings ponds produces large volumes of CH(4) in situ. We characterized the microbial communities involved in methanogenic biodegradation of whole naphtha (a bitumen extraction solvent) and its short-chain n-alkane (C(6)-C(10)) and BTEX (benzene, toluene, ethylbenzene, and xylenes) components using primary enrichment cultures derived from oil sands tailings. Clone libraries of bacterial 16S rRNA genes amplified from these enrichments showed increased proportions of two orders of Bacteria: Clostridiales and Syntrophobacterales, with Desulfotomaculum and Syntrophus/Smithella as the closest named relatives, respectively. In parallel archaeal clone libraries, sequences affiliated with cultivated acetoclastic methanogens (Methanosaetaceae) were enriched in cultures amended with n-alkanes, whereas hydrogenotrophic methanogens (Methanomicrobiales) were enriched with BTEX. Naphtha-amended cultures harbored a blend of these two archaeal communities. The results imply syntrophic oxidation of hydrocarbons in oil sands tailings, with the activities of different carbon flow pathways to CH(4) being influenced by the primary hydrocarbon substrate. These results have implications for predicting greenhouse gas emissions from oil sands tailings repositories.

Fuel quality processing study, volume 1

NASA Astrophysics Data System (ADS)

Ohara, J. B.; Bela, A.; Jentz, N. E.; Syverson, H. T.; Klumpe, H. W.; Kessler, R. E.; Kotzot, H. T.; Loran, B. L.

1981-04-01

A fuel quality processing study to provide a data base for an intelligent tradeoff between advanced turbine technology and liquid fuel quality, and also, to guide the development of specifications of future synthetic fuels anticipated for use in the time period 1985 to 2000 is given. Four technical performance tests are discussed: on-site pretreating, existing refineries to upgrade fuels, new refineries to upgrade fuels, and data evaluation. The base case refinery is a modern Midwest refinery processing 200,000 BPD of a 60/40 domestic/import petroleum crude mix. The synthetic crudes used for upgrading to marketable products and turbine fuel are shale oil and coal liquids. Of these syncrudes, 50,000 BPD are processed in the existing petroleum refinery, requiring additional process units and reducing petroleum feed, and in a new refinery designed for processing each syncrude to produce gasoline, distillate fuels, resid fuels, and turbine fuel, JPGs and coke. An extensive collection of synfuel properties and upgrading data was prepared for the application of a linear program model to investigate the most economical production slate meeting petroleum product specifications and turbine fuels of various quality grades. Technical and economic projections were developed for 36 scenarios, based on 4 different crude feeds to either modified existing or new refineries operated in 2 different modes to produce 7 differing grades of turbine fuels. A required product selling price of turbine fuel for each processing route was calculated. Procedures and projected economics were developed for on-site treatment of turbine fuel to meet limitations of impurities and emission of pollutants.

Fuel quality processing study, volume 1

NASA Technical Reports Server (NTRS)

Ohara, J. B.; Bela, A.; Jentz, N. E.; Syverson, H. T.; Klumpe, H. W.; Kessler, R. E.; Kotzot, H. T.; Loran, B. L.

1981-01-01

A fuel quality processing study to provide a data base for an intelligent tradeoff between advanced turbine technology and liquid fuel quality, and also, to guide the development of specifications of future synthetic fuels anticipated for use in the time period 1985 to 2000 is given. Four technical performance tests are discussed: on-site pretreating, existing refineries to upgrade fuels, new refineries to upgrade fuels, and data evaluation. The base case refinery is a modern Midwest refinery processing 200,000 BPD of a 60/40 domestic/import petroleum crude mix. The synthetic crudes used for upgrading to marketable products and turbine fuel are shale oil and coal liquids. Of these syncrudes, 50,000 BPD are processed in the existing petroleum refinery, requiring additional process units and reducing petroleum feed, and in a new refinery designed for processing each syncrude to produce gasoline, distillate fuels, resid fuels, and turbine fuel, JPGs and coke. An extensive collection of synfuel properties and upgrading data was prepared for the application of a linear program model to investigate the most economical production slate meeting petroleum product specifications and turbine fuels of various quality grades. Technical and economic projections were developed for 36 scenarios, based on 4 different crude feeds to either modified existing or new refineries operated in 2 different modes to produce 7 differing grades of turbine fuels. A required product selling price of turbine fuel for each processing route was calculated. Procedures and projected economics were developed for on-site treatment of turbine fuel to meet limitations of impurities and emission of pollutants.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Byrer, C.W.; Layne, A.W.; Guthrie, H.D.

The U.S. Department of Energy (DOE), at its Morgantown Energy Technology Center, has been involved in natural gas research since the 1970`s. DOE has assessed the potential of gas in coals throughout the U.S. and promoted research and development for recovery and use of methane found in minable and unminable coalbeds. DOE efforts have focused on the use of coal mine methane for regional economic gas self-sufficiency, energy parks, self-help initiatives, and small-power generation. This paper focuses on DOE`s past and present efforts to more effectively and efficiently recover and use this valuable domestic energy source. The Climate Change Actionmore » Plan (CCAP) (1) lists a series of 50 voluntary initiatives designed to reduce greenhouse gas emissions, such as methane from mining operations, to their 1990 levels. Action No. 36 of the CCAP expands the DOE research, development, and demonstration (RD&D) efforts to broaden the range of cost-effective technologies and practices for recovering methane associated with coal mining operations. The major thrust of Action No. 36 is to reduce methane emissions associated with coal mining operations from target year 2000 levels by 1.5 MMT of carbon equivalent. Crosscutting activities in the DOE Natural Gas Program supply the utilization sectors will address RD&D to reduce methane emissions released from various mining operations, focusing on recovery and end use technology systems to effectively drain, capture, and utilize the emitted gas. Pilot projects with industry partners will develop and test the most effective methods and technology systems for economic recovery and utilization of coal mine gas emissions in regions where industry considers efforts to be presently non-economic. These existing RD&D programs focus on near-term gas recovery and gathering systems, gas upgrading, and power generation.« less

Small-Scale Coal-Biomass to Liquids Production Using Highly Selective Fischer-Tropsch Synthesis

DOE Office of Scientific and Technical Information (OSTI.GOV)

Gangwal, Santosh K.; McCabe, Kevin

2015-04-30

The research project advanced coal-to-liquids (CTL) and coal-biomass to liquids (CBTL) processes by testing and validating Chevron’s highly selective and active cobalt-zeolite hybrid Fischer-Tropsch (FT) catalyst to convert gasifier syngas predominantly to gasoline, jet fuel and diesel range hydrocarbon liquids, thereby eliminating expensive wax upgrading operations The National Carbon Capture Center (NCCC) operated by Southern Company (SC) at Wilsonville, Alabama served as the host site for the gasifier slip-stream testing/demonstration. Southern Research designed, installed and commissioned a bench scale skid mounted FT reactor system (SR-CBTL test rig) that was fully integrated with a slip stream from SC/NCCC’s transport integrated gasifiermore » (TRIG TM). The test-rig was designed to receive up to 5 lb/h raw syngas augmented with bottled syngas to adjust the H 2/CO molar ratio to 2, clean it to cobalt FT catalyst specifications, and produce liquid FT products at the design capacity of 2 to 4 L/day. It employed a 2-inch diameter boiling water jacketed fixed-bed heat-exchange FT reactor incorporating Chevron’s catalyst in Intramicron’s high thermal conductivity micro-fibrous entrapped catalyst (MFEC) packing to efficiently remove heat produced by the highly exothermic FT reaction.« less

Residential Solar PV Systems in the Carolinas: Opportunities and Outcomes.

PubMed

Alqahtani, Bandar Jubran; Holt, Kyra Moore; Patiño-Echeverri, Dalia; Pratson, Lincoln

2016-02-16

This paper presents a first-order analysis of the feasibility and technical, environmental, and economic effects of large levels of solar photovoltaic (PV) penetration within the services areas of the Duke Energy Carolinas (DEC) and Duke Energy Progress (DEP). A PV production model based on household density and a gridded hourly global horizontal irradiance data set simulates hourly PV power output from roof-top installations, while a unit commitment and real-time economic dispatch (UC-ED) model simulates hourly system operations. We find that the large generating capacity of base-load nuclear power plants (NPPs) without ramping capability in the region limits PV integration levels to 5.3% (6510 MW) of 2015 generation. Enabling ramping capability for NPPs would raise the limit of PV penetration to near 9% of electricity generated. If the planned retirement of coal-fired power plants together with new installations and upgrades of natural gas and nuclear plants materialize in 2025, and if NPPs operate flexibly, then the share of coal-fired electricity will be reduced from 37% to 22%. A 9% penetration of electricity from PV would further reduce the share of coal-fired electricity by 4-6% resulting in a system-wide CO2 emissions rate of 0.33 to 0.40 tons/MWh and associated abatement costs of 225-415 (2015$ per ton).

Phase change of iron ore reduction process using EFB as reducing agent at 900-1200°C

NASA Astrophysics Data System (ADS)

Purwanto, H.; Salleh, H. M.; Rozhan, A. N.; Mohamad, A. S.; Zakiyuddin, A.

2018-04-01

Treatment of low grade iron ore involved reduction of oxygen in iron oxide by using reductant such as carbon monoxide or hydrogen gas. Presently, carboneous materials such as coke/coal are widely used as a source to provide reducing gas, but some problem arises from this material as the gas can harm the environments. Therefore, empty fruit bunch biomass from oil palm becomes an alternative to replace the usage of coke/coal as their major composition is carbon and hydrogen. The idea of replacing coke with biomass will reduce the amount of carbon dioxide release as biomass is a carbon neutral and renewable source, and at the same time abundance of waste from oil palm industries can be overcome. Therefore, the aim of this research is to upgrade the low grade iron with reducibility more than 50% being used in iron and steel making. In this research, low grade iron ore are mixed together with EFB then is making into composite pellet before being reduced at certain parameter chosen. The variables involved in this research is composition EFB (10%, 30% and 50%), temperature (1000°C, 1100°C and 1200°C) and reduction time is fixed with 30 minutes. From the experiment conducted, the highest reducibility achieved is 76.37% at temperature 1200°C. While XRD analysis shows the existence of metallic iron phase started to form at 1000°C with composition of 30% of EFB. Meanwhile, from magnetization test show that at 1200°C the highest magnetic susceptibility is achieved as the dominance phase at 1200°C is metallic phase. Therefore it is an interesting alternative to replace coke with biomass for reducing agent in upgrading low grade iron into workable ores.

Substantial air quality and climate co-benefits achievable now with sectoral mitigation strategies in China.

PubMed

Peng, Wei; Yang, Junnan; Wagner, Fabian; Mauzerall, Denise L

2017-11-15

China is the world's top carbon emitter and suffers from severe air pollution. We examine near-term air quality and CO 2 co-benefits of various current sector-based policies in China. Using a 2015 base case, we evaluate the potential benefits of four sectoral mitigation strategies. All scenarios include a 20% increase in conventional air pollution controls as well as the following sector-specific fuel switching or technology upgrade strategies. Power sector (POW): 80% replacement of small coal power plants with larger more efficient ones; Industry sector (IND): 10% improvement in energy efficiency; Transport sector (TRA): replacement of high emitters with average vehicle fleet emissions; and Residential sector (RES): replacement of 20% of coal-based stoves with stoves using liquefied petroleum gas (LPG). Conducting an integrated assessment using the regional air pollution model WRF-Chem, we find that the IND scenario reduces national air-pollution-related deaths the most of the four scenarios examined (27,000, 24,000, 13,000 and 23,000 deaths reduced annually in IND, POW, TRA and RES, respectively). In addition, the IND scenario reduces CO 2 emissions more than 8times as much as any other scenario (440, 53, 0 and 52Mt CO 2 reduced in IND, POW, TRA and RES, respectively). We also examine the benefits of an industrial efficiency improvement of just 5%. We find the resulting air quality and health benefits are still among the largest of the sectoral scenarios, while the carbon mitigation benefits remain more than 3 times larger than any other scenario. Our analysis hence highlights the importance of even modest industrial energy efficiency improvements and air pollution control technology upgrades for air quality, health and climate benefits in China. Copyright © 2017 Elsevier B.V. All rights reserved.

Diesel production from Fischer-Tropsch: the past, the present, and new concepts

DOE Office of Scientific and Technical Information (OSTI.GOV)

Dieter Leckel

2009-05-15

Fischer-Tropsch synthesis is technically classified into two categories, the high-temperature Fischer-Tropsch (HTFT) and the low-temperature Fischer-Tropsch (LTFT) processes. The criterion for this classification is the operating temperature of the synthesis, which ranges between 310-340{sup o}C for the HTFT process and 210-260{sup o}C for the LTFT process. A Fischer-Tropsch facility can be divided into roughly three sections, synthesis gas (syngas) generation, FT synthesis, and refining of the synthetic crude (syncrude). Fischer-Tropsch refineries differ regarding the product upgrading, and both transportation fuels and chemicals can be produced. Regarding the FT refinery history, the configuration of each refinery also reflects the requirements ofmore » the fuel specification at that time. This paper gives a condensed overview of how Fischer-Tropsch facilities changed during the last 70 years and focuses in particular on the diesel fuel produced. Some conceptual flow schemes are additionally presented with emphasis on the combined upgrading of the high boiling part of the FT product spectrum with liquids derived from coal pyrolysis. 52 refs., 14 figs., 12 tabs.« less

Direct Coal -to-Liquids (CTL) for Jet Fuel Using Biomass-Derived Solvents

DOE Office of Scientific and Technical Information (OSTI.GOV)

Chauhan, Satya P.; Garbark, Daniel B.; Taha, Rachid

Battelle has demonstrated a novel and potentially breakthrough technology for a direct coal-to-liquids (CTL) process for producing jet fuel using biomass-derived coal solvents (bio-solvents). The Battelle process offers a significant reduction in capital and operating costs and a substantial reduction in greenhouse gas (GHG) emissions, without requiring carbon capture and storage (CCS). The results of the project are the advancement of three steps of the hybrid coal/biomass-to-jet fuel process to the technology readiness level (TRL) of 5. The project objectives were achieved over two phases. In Phase 1, all three major process steps were explored and refined at bench-scale, including:more » (1) biomass conversion to high hydrogen-donor bio-solvent; (2) coal dissolution in biomass-derived bio-solvent, without requiring molecular H 2, to produce a synthetic crude (syncrude); and (3) two-stage catalytic hydrotreating/hydrogenation of syncrude to jet fuel and other distillates. In Phase 2, all three subsystems of the CTL process were scaled up to a pre-pilot scale, and an economic analysis was carried out. A total of over 40 bio-solvents were identified and prepared. The most unique attribute of Battelle’s bio-solvents is their ability to provide much-needed hydrogen to liquefy coal and thus increase its hydrogen content so much that the resulting syncrude is liquid at room temperature. Based on the laboratory-scale testing with bituminous coals from Ohio and West Virginia, a total of 12 novel bio-solvent met the goal of greater than 80% coal solubility, with 8 bio-solvents being as good as or better than a well-known but expensive hydrogen-donor solvent, tetralin. The Battelle CTL process was then scaled up to 1 ton/day (1TPD) at a pre-pilot facility operated in Morgantown, WV. These tests were conducted, in part, to produce enough material for syncrude-upgrading testing. To convert the Battelle-CTL syncrude into a form suitable as a blending stock for jet turbine fuel, a two-step catalytic upgrading process was developed at laboratory scale and then demonstrated at pre-pilot scale facility in Pittsburg, PA. Several drums of distillate products were produced, which were then distilled into unblended (neat) synthetic jet fuel and diesel products for a detailed characterization. Based on a detailed characterization of the synthetic jet fuel, a 20% synthetic, 80% commercial jet fuel blend was prepared, which met all specifications. An analysis of the synthetic diesel product showed that it has the promise of being a drop-in fuel as super-low (less than 15 ppm)-sulfur diesel fuel. A detailed economic analysis showed that the Battelle liquefaction process is economical at between 1000 metric tons/day (MT/day) and 2000 MT/day. The unit capital cost for Battelle CTL process for making jet fuel is 50K USD/daily bbl compared to 151K USD/daily bbl for indirect CTL, based on 2011 dollars. The jet-fuel selling cost at the refinery, including a 12% capital cost factor (which included profit), for the Battelle CTL process is 61USD/bbl (1.45 USD/gallon). This is competitive with crude oil price of 48 USD/bbl. At the same time, the GHG emissions of 3.56 MT CO 2/MT fuel were lower than the GHG emissions of 3.79 MT CO 2/MTfuel for petroleum-based fuels and 7.77 MT CO 2/MT fuel for indirect CTL. Thus, the use of bio-solvents completely eliminates the need for carbon capture in the case of Battelle CTL process. The superior economics and low GHG emissions for the Battelle CTL process has thus sparked worldwide interest and some potential commercialization opportunities are emerging.« less

Rawhide Energy Station, Fort Collins, Colorado

DOE Office of Scientific and Technical Information (OSTI.GOV)

Peltier, R.

2008-10-15

The staff of Platte River Power Authority's Rawhide Energy Station have been racking up operating stats and an environmental performance record that is the envy of other plant managers. In the past decade Rawhide has enjoyed an equivalent availability factor in the mid to high 90s and an average capacity factor approaching 90%. Still not content with this performance, Rawhide invested in new technology and equipment upgrades to further optimise performance, reduce emissions, and keep cost competitive. The Energy Station includes four GE France 7EA natural gas-fired turbines totalling 260 MW and a 274 MW coal-fired unit located in northeasternmore » Colorado. 7 figs.« less

Optimization of waste heat utilization in cold end system of thermal power station based on neural network algorithm

NASA Astrophysics Data System (ADS)

Du, Zenghui

2018-04-01

At present, the flue gas waste heat utilization projects of coal-fired boilers are often limited by low temperature corrosion problems and conventional PID control. The flue gas temperature cannot be reduced to the best efficiency temperature of wet desulphurization, resulting in the failure of heat recovery to be the maximum. Therefore, this paper analyzes, researches and solves the remaining problems of the cold end system of thermal power station, so as to provide solutions and theoretical support for energy saving and emission reduction and upgrading and the improvement of the comprehensive efficiency of the units.

2016 Annual Technology Baseline (ATB)

DOE Office of Scientific and Technical Information (OSTI.GOV)

Cole, Wesley; Kurup, Parthiv; Hand, Maureen

Consistent cost and performance data for various electricity generation technologies can be difficult to find and may change frequently for certain technologies. With the Annual Technology Baseline (ATB), National Renewable Energy Laboratory provides an organized and centralized dataset that was reviewed by internal and external experts. It uses the best information from the Department of Energy laboratory's renewable energy analysts and Energy Information Administration information for conventional technologies. The ATB will be updated annually in order to provide an up-to-date repository of current and future cost and performance data. Going forward, we plan to revise and refine the values usingmore » best available information. The ATB includes both a presentation with notes (PDF) and an associated Excel Workbook. The ATB includes the following electricity generation technologies: land-based wind; offshore wind; utility-scale solar PV; concentrating solar power; geothermal power; hydropower plants (upgrades to existing facilities, powering non-powered dams, and new stream-reach development); conventional coal; coal with carbon capture and sequestration; integrated gasification combined cycle coal; natural gas combustion turbines; natural gas combined cycle; conventional biopower. Nuclear laboratory's renewable energy analysts and Energy Information Administration information for conventional technologies. The ATB will be updated annually in order to provide an up-to-date repository of current and future cost and performance data. Going forward, we plan to revise and refine the values using best available information.« less

ECKG Kladno project: First IPP in the Czech Republic

DOE Office of Scientific and Technical Information (OSTI.GOV)

Rode, J.R.; Tichy, O.J.

1999-07-01

The Energy Center Kladno project is the first independent power producer (IPP) project to be financed in the Czech Republic, one of Europe's most rapidly evolving markets. The total financing is $401 million and is structured in three currencies; Czech crowns, German marks, and US dollars. This paper will focus on: Enhanced technology to meet energy demands; Execution to meet the ambitious; and Overall project status. The coal and gas fired plant will produce a total of 343 MW to provide electricity and heat to the town of Kladno, west of Prague. The new plant will be located within themore » existing ECK facility and the project encompasses demolition, upgrading, and rebuilding. The base load will be from two coal-fired 135 MW circulating fluidized bed (CFB) boilers and peaking capacity from the gas-fired combustion (66 MW) turbine. The CFB's will fire a range of low sulfur brown coal supplied from the local mining company Ceskomoravske Doly (CMD). The new CFB's were designed to meet the overall steam demands specified by ECKG. The CFB's design features include in-furnace heat transfer surface and a split backpass that utilizes a biasing damper to allow for control of both the superheat and reheat steam temperatures. The various CFB auxiliary systems will be discussed in the paper as well as the flue gas particulate collection equipment.« less

Taguchi approach for co-gasification optimization of torrefied biomass and coal.

PubMed

Chen, Wei-Hsin; Chen, Chih-Jung; Hung, Chen-I

2013-09-01

This study employs the Taguchi method to approach the optimum co-gasification operation of torrefied biomass (eucalyptus) and coal in an entrained flow gasifier. The cold gas efficiency is adopted as the performance index of co-gasification. The influences of six parameters, namely, the biomass blending ratio, oxygen-to-fuel mass ratio (O/F ratio), biomass torrefaction temperature, gasification pressure, steam-to-fuel mass ratio (S/F ratio), and inlet temperature of the carrier gas, on the performance of co-gasification are considered. The analysis of the signal-to-noise ratio suggests that the O/F ratio is the most important factor in determining the performance and the appropriate O/F ratio is 0.7. The performance is also significantly affected by biomass along with torrefaction, where a torrefaction temperature of 300°C is sufficient to upgrade eucalyptus. According to the recommended operating conditions, the values of cold gas efficiency and carbon conversion at the optimum co-gasification are 80.99% and 94.51%, respectively. Copyright © 2013 Elsevier Ltd. All rights reserved.

Numerical analysis of single and multiple particles of Belchatow lignite dried in superheated steam

NASA Astrophysics Data System (ADS)

Zakrzewski, Marcin; Sciazko, Anna; Komatsu, Yosuke; Akiyama, Taro; Hashimoto, Akira; Kaneko, Shozo; Kimijima, Shinji; Szmyd, Janusz S.; Kobayashi, Yoshinori

2018-03-01

Low production costs have contributed to the important role of lignite in the energy mixes of numerous countries worldwide. High moisture content, though, diminishes the applicability of lignite in power generation. Superheated steam drying is a prospective method of raising the calorific value of this fuel. This study describes the numerical model of superheated steam drying of lignite from the Belchatow mine in Poland in two aspects: single and multi-particle. The experimental investigation preceded the numerical analysis and provided the necessary data for the preparation and verification of the model. Spheres of 2.5 to 30 mm in diameter were exposed to the drying medium at the temperature range of 110 to 170 °C. The drying kinetics were described in the form of moisture content, drying rate and temperature profile curves against time. Basic coal properties, such as density or specific heat, as well as the mechanisms of heat and mass transfer in the particular stages of the process laid the foundations for the model construction. The model illustrated the drying behavior of a single particle in the entire range of steam temperature as well as the sample diameter. Furthermore, the numerical analyses of coal batches containing particles of various sizes were conducted to reflect the operating conditions of the dryer. They were followed by deliberation on the calorific value improvement achieved by drying, in terms of coal ingredients, power plant efficiency and dryer input composition. The initial period of drying was found crucial for upgrading the quality of coal. The accuracy of the model is capable of further improvement regarding the process parameters.

Commercial-scale demonstration of the Liquid Phase Methanol (LPMEOH{trademark}) process. Technical progress report number 6, October 1--December 31, 1995

DOE Office of Scientific and Technical Information (OSTI.GOV)

NONE

1996-12-31

The project involves the construction of an 80,000 gallons per day (260 TPD) methanol unit utilizing coal-derived synthesis gas from Eastman`s integrated coal gasification facility. The new equipment consists of synthesis gas feed preparation and compression facilities, the liquid phase reactor and auxiliaries, product distillation facilities, and utilities. The technology to be demonstrated is the product of a cooperative development effort by Air Products and DOE in a program that started in 1981. Developed to enhance electric power generation using integrated gasification combined cycle (IGCC) technology, the LPMEOH{trademark} process is ideally suited for directly processing gases produced by modern-day coalmore » gasifiers. This liquid phase process suspends fine catalyst particles in an inert liquid, forming a slurry. The slurry dissipates the heat of the chemical reaction away from the catalyst surface protecting the catalyst and allowing the methanol synthesis reaction to proceed at higher rates. At the Eastman complex, the technology will be integrated with existing coal-gasifiers. A carefully developed test plan will allow operations at Eastman to simulate electricity demand load-following in coal-based IGCC facilities. The operations will also demonstrate the enhanced stability and heat dissipation of the conversion process, its reliable on/off operation, and its ability to produce methanol as a clean liquid fuel without additional upgrading. An off-site product testing program will be conducted to demonstrate the suitability of the methanol product as a transportation fuel and as a fuel for stationary applications for small modular electric power generators for distributed power.« less

IMPROVED CATALYSTS FOR HEAVY OIL UPGRADING BASED ON ZEOLITE Y NANOPARTICLES ENCAPSULATED IN STABLE NANOPOROUS HOST

DOE Office of Scientific and Technical Information (OSTI.GOV)

Conrad Ingram; Mark Mitchell

2005-11-15

Composite materials of SBA-15/zeolite Y were synthesized from zeolite Y precursor and a synthesis mixture of mesoporous silicate SBA-15 via a hydrothermal process in the presence of a slightly acidic media of pH 4-6 with 2M H{sub 2}SO{sub 4}. The SBA-15/ZY composites showed Type IV adsorption isotherms, narrow BJH average pore size distribution of 4.9 nm, surface areas up to 800 m{sup 2}2/g and pore volumes 1.03 cm{sup 3}, all comparable to pure SBA-15 synthesized under similar conditions. Chemical analysis revealed Si/Al ratio down to 8.5 in the most aluminated sample, and {sup 27}AlSS MAS NMR confirmed aluminum was inmore » tetrahedral coordination. This method of introduction of Al in pure T{sub d} coordination is effective in comparison to other direct and post synthesis alumination methods. Bronsted acid sites were evident from a pyridinium peak at 1544 cm-1 in the FTIR spectrum after pyridine adsorption, and from NH{sub 3} -TPD experiments. SBA-15/ZY composites showed significant catalytic activities for the dealkylation of isopropylbenzene to benzene and propene, similar to those of commercial zeolite Y. It was observed that higher conversion for catalysts synthesized with high amount of ZY precursor mixture added to the SBA-15. Over all the composites has shown good catalytic activity. Further studies will be focused on gaining a better understand the nature of the precursor, and to characterize and to locate the acid sites in the composite material. The composite will also be evaluated for heavy oil conversion to naphtha and middle distillates.« less

Waterborne Commerce of the United States, Calendar Year 1980. Part 1. Waterways and Harbors, Atlantic Coast.

DTIC Science & Technology

1982-09-01

nil 2021 Dairy products, except dried milk ad ctean 2916 Lubricating oils and greanes 2022 Dried milk ad cres 2917 Naphtha, minerei spirits, solvents...2022 DRIED MILK AND CREA ------------------------- 696 .- ;.- O------ 66 --------- --- ----- ---------- ---------- ---------- 2031 FIS4...DAIRY PRODUCTS, NEC ----------------------. 7. 4 1 1. .1 7,922 --------- ----------- 2022 0917 MILK AN: CREAM -------------- 32,136 3,212 3,245 266 5S39

40 CFR Table Mm-1 to Subpart Mm of... - Default Factors for Petroleum Products and Natural Gas Liquids 1 2

Code of Federal Regulations, 2013 CFR

2013-07-01

... and Natural Gas Liquids 1 2 MM Table MM-1 to Subpart MM of Part 98 Protection of Environment... Factors for Petroleum Products and Natural Gas Liquids 1 2 Products Column A: density(metric tons/bbl... Natural Gas Liquids Aviation Gasoline 0.1120 85.00 0.3490 Special Naphthas 0.1222 84.76 0.3798 Lubricants...

40 CFR Table Mm-1 to Subpart Mm of... - Default Factors for Petroleum Products and Natural Gas Liquids 1 2

Code of Federal Regulations, 2014 CFR

2014-07-01

... and Natural Gas Liquids 1 2 MM Table MM-1 to Subpart MM of Part 98 Protection of Environment... Factors for Petroleum Products and Natural Gas Liquids 1 2 Products Column A: density(metric tons/bbl... Natural Gas Liquids Aviation Gasoline 0.1120 85.00 0.3490 Special Naphthas 0.1222 84.76 0.3798 Lubricants...

40 CFR Table Mm-1 to Subpart Mm of... - Default Factors for Petroleum Products and Natural Gas Liquids 1 2

Code of Federal Regulations, 2012 CFR

2012-07-01

... and Natural Gas Liquids 1 2 MM Table MM-1 to Subpart MM of Part 98 Protection of Environment... Factors for Petroleum Products and Natural Gas Liquids 1 2 Products Column A: density(metric tons/bbl... Natural Gas Liquids Aviation Gasoline 0.1120 85.00 0.3490 Special Naphthas 0.1222 84.76 0.3798 Lubricants...

40 CFR Table Mm-1 to Subpart Mm of... - Default Factors for Petroleum Products and Natural Gas Liquids 1 2

Code of Federal Regulations, 2011 CFR

2011-07-01

... and Natural Gas Liquids 1 2 MM Table MM-1 to Subpart MM of Part 98 Protection of Environment... Factors for Petroleum Products and Natural Gas Liquids 1 2 Products Column A: density(metric tons/bbl... Natural Gas Liquids Aviation Gasoline 0.1120 85.00 0.3490 Special Naphthas 0.1222 84.76 0.3798 Lubricants...

DOE Office of Scientific and Technical Information (OSTI.GOV)

Davis, R.; Tao, L.; Scarlata, C.

This report describes one potential conversion process to hydrocarbon products by way of catalytic conversion of lignocellulosic-derived hydrolysate. This model leverages expertise established over time in biomass deconstruction and process integration research at NREL, while adding in new technology areas for sugar purification and catalysis. The overarching process design converts biomass to die die diesel- and naphtha-range fuels using dilute-acid pretreatment, enzymatic saccharification, purifications, and catalytic conversion focused on deoxygenating and oligomerizing biomass hydrolysates.

Weed control in a native rubber crop (Parthenium argentatum gray)

DOE Office of Scientific and Technical Information (OSTI.GOV)

Whitworth, J.W.

1978-01-01

There is a renewed interest in the production of rubber from guayule (Parthenium argentatum). Excellent control of several weed species in guayule has been obtained with Varsol (a naphtha oil) at 30-40 gal/acre applied at the cotyledon stage. At this stage, guayule survival averaged 86-63% according to dose, but plants up to 10 days old at the time of treatment showed increasing tolerance. Paraffin was somewhat more selective that Varsol.

Internal Nozzle Flow Simulations of Gasoline-Like Fuels under Diesel Operating Conditions

DOE Office of Scientific and Technical Information (OSTI.GOV)

Torelli, R.; Som, S.; Pei, Y.

Spray formation in internal combustion engines with direct injection is strictly correlated with internal nozzle flow characteristics, which are in turn influenced by fuel physical properties and injector needle motion. This paper pre-sents a series of 3D simulations that model the in-nozzle flow in a 5-hole mini-sac diesel injector. Two gasoline-like naphtha fuels, namely full-range and light naphtha, were tested under operating conditions typical of diesel applica-tions and were compared with n-dodecane, selected from a palette used as diesel surrogates. Validated methodolo-gies from our previous work were employed to account for realistic needle motion. The multi-phase nature of the problemmore » was described by the mixture model assumption with the Volume of Fluid method. Cavitation effects were included by means of the Homogeneous Relaxation Model and turbulence closure was achieved with the Standard k-ε model in an Unsteady Reynolds-Averaged Navier-Stokes formulation. The results revealed that injector perfor-mance and propensity to cavitation are influenced by the fuel properties. Analyses of several physical quantities were carried out to highlight the fuel-to-fuel differences in terms of mass flow rate, discharge coefficients, and fuel vapor volume fraction inside the orifices. A series of parametric investigations was also performed to assess the fuel response to varied fuel injection temperature, injection pressure, and cross-sectional orifice area. For all cases, the strict correlation between cavitation magnitude and saturation pressure was confirmed. Owing to their higher volatil-ity, the two gasoline-like fuels were characterized by higher cavitation across all the simulated conditions. Occur-rence of cavitation was mostly found at the needle seat and at the orifice inlets during the injection event’s transient, when very small gaps exist between the needle and its seat. This behavior tended to disappear at maximum needle lift, where cavitation was absent for all fuels. Differences in mass flow rate between the naphtha fuels and n-dodecane were measured and ascribed to the different densities of the three fuels. Nevertheless, they were found to be smaller than expected, owing to the lower viscosity of the gasoline-like fuels. This beneficial influence of the lower viscosity was shown to be less effective at higher temperature, where the relative viscosity differences de-creased.« less

Turbine Fuels from Tar Sands Bitumen and Heavy Oil. Phase I. Preliminary Process Analysis.

DTIC Science & Technology

1985-04-09

OIL RESERVOIRS OF THE UNITED STATES Resource: Oil -in-Place State Field Name (County) (Million Bbls.) Arkansas Smackover Old (Union) 1,6U0 California...Flow Schematic for Gas Oil Feed Hydrotreater 94 14 Summary of Case Studies for Processing Bitumen from New Mexico 95 15 Summary of Case Studies for...Naphtha Hydrotreating Process Estimates 112 14 Gas Oil Hydrocracking Process Estimates 113 l! Gas Oil Hydrotreating Process Estimate 114 16 Fluid

Corrosion-Inhibiting Coating Composition.

DTIC Science & Technology

1990-03-01

acrylic polymers were designed for compatibility with the alkyd resins and are useful therefore in preparing coatings of improved hardness...Hydrocarbon solvents 10 to 50 Componentam PatIbyWih Acrylic resin (B-67) 17.3 Silicone resin (SR-80M) 17.3 Silicone- alkyd resin 8.6 (V(ARKYD 385-50E...aichol e.6 VM&P Naphtha 17.1 Example II I ComponentPatbyWgh Acrylic resin 17.3 15 Silicone resin 17.3 Silicone- alkyd resin 8.6 Alkyl

Feedstock recycling program gets go ahead

DOE Office of Scientific and Technical Information (OSTI.GOV)

Layman, P.

1994-03-28

Feedstock recycling--recycling mixed plastics wastes back into chemical feedstocks such as olefins and naphtha--has received a commercial go ahead in Germany. DKR--Deutsche Kunstsoff recycling, a subsidiary of a commercial company, Duales System Deutschland, responsible for recycling packaging wastes in Germany--has issued three contracts to companies with feedstock recycling technology to convert to liquid feedstocks a total of some 500,000 metric tons per year of mixed plastics packaging wastes by 1996. DKR has also pledged to discontinue exports of used plastics packaging to foreign countries by that date. The three contracts go to a consortium between BASF and OTTO Kunststoff service,more » of Dossenheim; the oil and chemical producer Veba; and the electric power utilities company RWE. DKR's current processing costs are about $1,765 per ton of wastes. That total includes all costs for collecting, sorting, cleaning, and transporting the wastes. In its bid, the BASF-OTTO consortium envisioned a fee of about $190 per ton. That fee, says Niess, was determined by looking at BASF's and OTTO's costs, offset by the savings in raw materials BASF would be making as its technology converts mixed plastics wastes to a mixture of naphtha, aromatics, and oils, all of which can be used in BASF's processes in Ludwigshafen. And because BASF's technology requires no presorting or cleaning before it gets the wastes, the process will trim DKR's costs significantly.« less

Identification of potential hazards associated with new residential construction.

PubMed

Methner, M M

2000-02-01

There were several advantages and limitations of this observational study. The most important advantage of this study was the opportunity to observe residential construction workers performing their jobs. By observing work practices, valuable information was gathered about specific trades and their potential exposure to various chemical and physical agents. This information will be useful in guiding subsequent exposure assessments. Probably the greatest limitation of this study was the lack of participation by homebuilders. Ideally, observations of construction processes would have been more objective if the study included the participation of more than one homebuilder. Aside from one worker who was observed to wear safety glasses, leather gloves, and a dust mask, virtually no personal protective equipment (PPE) was observed onsite. Often small contractors do not have the financial resources necessary to procure the appropriate PPE and issue these items to the workers. Based on hazard prevalence, professional judgement, and the degree of hazardous product use, potential exposures that warrant quantitative sampling efforts during Phase 2 of this study are: bulldozer/backhoe operators--noise, vibration, diesel exhaust; concrete workers--naphtha, mineral spirits, Portland cement; asphalt workers--petroleum hydrocarbons, asphalt, mineral spirits; plumbers--methylethyl ketone, acetone, tetrahydrofuran, cyclohexanone; drywall finishers--total and respirable dust, hexane, acetone; painters--ethylene glycol, VOCs; masons--dust (during the preparation of mortar); floor preparation technicians--total and respirable dust; and ceramic tile installers--toluene, naphtha, silica (from grout powder).

Effect of overtime work on cognitive function in automotive workers.

PubMed

Proctor, S P; White, R F; Robins, T G; Echeverria, D; Rocskay, A Z

1996-04-01

The present investigation examined whether increased overtime work predicts impairment in cognitive performance in the domains of attention, executive function, and mood. The behavioral and cognitive functions of 248 automotive workers were measured by a neurobehavioral test performance. Overtime, defined as number of hours worked greater than 8 h a day or greater than 5 d a week, was calculated from company payroll records for the week before the test day. The number of consecutive days worked before the test day was also determined. Cross-sectional data analysis by multiple linear regression, after adjustment for the effects of age, education, gender, alcohol intake, repeated grade in school, acute petroleum naphtha exposure, shift worked, job type, number of consecutive days worked before the test day, and number of hours worked on the test day before the testing, demonstrated that increased overtime was significantly associated with impaired performance on several tests of attention and executive function. Increased feelings of depression, fatigue, and confusion were also associated with increased overtime work. In addition significant interaction effects were observed for job type but not for naphtha exposure. The findings support the hypothesis that overtime work results in impaired cognitive performance in the areas of attention and executive function and that both overtime hours and the number of consecutive days worked prior to a test day affect mood.

Cobalt carbide nanoprisms for direct production of lower olefins from syngas

NASA Astrophysics Data System (ADS)

Zhong, Liangshu; Yu, Fei; An, Yunlei; Zhao, Yonghui; Sun, Yuhan; Li, Zhengjia; Lin, Tiejun; Lin, Yanjun; Qi, Xingzhen; Dai, Yuanyuan; Gu, Lin; Hu, Jinsong; Jin, Shifeng; Shen, Qun; Wang, Hui

2016-10-01

Lower olefins—generally referring to ethylene, propylene and butylene—are basic carbon-based building blocks that are widely used in the chemical industry, and are traditionally produced through thermal or catalytic cracking of a range of hydrocarbon feedstocks, such as naphtha, gas oil, condensates and light alkanes. With the rapid depletion of the limited petroleum reserves that serve as the source of these hydrocarbons, there is an urgent need for processes that can produce lower olefins from alternative feedstocks. The ‘Fischer-Tropsch to olefins’ (FTO) process has long offered a way of producing lower olefins directly from syngas—a mixture of hydrogen and carbon monoxide that is readily derived from coal, biomass and natural gas. But the hydrocarbons obtained with the FTO process typically follow the so-called Anderson-Schulz-Flory distribution, which is characterized by a maximum C2-C4 hydrocarbon fraction of about 56.7 per cent and an undesired methane fraction of about 29.2 per cent (refs 1, 10, 11, 12). Here we show that, under mild reaction conditions, cobalt carbide quadrangular nanoprisms catalyse the FTO conversion of syngas with high selectivity for the production of lower olefins (constituting around 60.8 per cent of the carbon products), while generating little methane (about 5.0 per cent), with the ratio of desired unsaturated hydrocarbons to less valuable saturated hydrocarbons amongst the C2-C4 products being as high as 30. Detailed catalyst characterization during the initial reaction stage and theoretical calculations indicate that preferentially exposed {101} and {020} facets play a pivotal role during syngas conversion, in that they favour olefin production and inhibit methane formation, and thereby render cobalt carbide nanoprisms a promising new catalyst system for directly converting syngas into lower olefins.

Energy cane as a multiple-products alternative

DOE Office of Scientific and Technical Information (OSTI.GOV)

Alexander, A.G.

1984-01-01

CANE SUGAR planting as it was formerly known is in serious and essentially irreversible trouble. Diversification of sugarcane to alternative farm crops is indicated in some instances. Yet, for the most part, the more logical alternative is an internal diversification to a multiple-products biomass commodity. Sometimes termed the energy cane approach, its keystones are the management of sugarcane as a quantitative rather than qualitative entity, and the inclusion of certain tropical-grass relatives to assist cane in its year-round supply of biomass to industrial consumers. Managed in this way, absolute tonnages of whole cane are increased materially beyond what is possiblemore » from sugar-crop management. Juice quality declines but sugar yields are significant as a function of high biomass tonnages per acre. Usage of the lignocellulose can range from low-quality humid boiler fuel in furnaces designed for refuse incineration, to higher-quality fuels in more efficient boilers, to proprietary fuels and chemical products, and to lignocellulose supply as the feedstock for primary chemicals production. The latter might include, for example, synthesis gas and petrochemicals in tropical regions lacking natural gas, naphtha, or coal as starting materials. Diversification of sugarcane to completely new farm commodities is opposed in favor of internal diversification to a high-growth, multiple-products commodity. Decisive issues here are as much educational as they are technical. The energy cane concept maintains that sugarcane is a future resource of enormous national and international value. It should develop accordingly where decision-taking is by persons who respect the cane plant and who have done their homework on its alternative-use potentials. 35 references, 5 figures, 6 tables.« less

Anatomy of an upgraded pulverized coal facility: Combustion modification through flue gas scrubbing

DOE Office of Scientific and Technical Information (OSTI.GOV)

Watts, J.U.; Savichky, W.J.; O`Dea, D.T.

1997-12-31

Regeneration is a biological term for formation or creating anew. In the case of Milliken station, a species of steam generation (Tangentus coali) regeneration refers to refitting critical systems with the latest technological advances to reduce emissions while maintaining or improving performance. The plant has undergone a series of operations which provided anatomical changes as well as a face lift. Each of the two units were place in suspended animation (outage) to allow these changes to be made. The paper describes the project which includes retrofitting combustion systems, pulverizers, boiler liners, scrubbers, and control room. This retrofit is meant tomore » increase thermal efficiency while reducing the formation of nitrogen oxides.« less

Fly ash system technology improves opacity

DOE Office of Scientific and Technical Information (OSTI.GOV)

NONE

2007-06-15

Unit 3 of the Dave Johnston Power Plant east of Glenrock, WY, USA had problems staying at or below the opacity limits set by the state. The unit makes use of a Lodge Cottrell precipitator. When the plant changed to burning Power River Basin coal, ash buildup became a significant issue as the fly ash control system was unable to properly evacuate hoppers on the unit. To overcome the problem, the PLC on the unit was replaced with a software optimization package called SmartAsh for the precipitator fly ash control system, at a cost of $500,000. After the upgrade, theremore » have been no plugged hoppers and the opacity has been reduced from around 20% to 3-5%. 2 figs.« less

Process for separating nitrogen from methane using microchannel process technology

DOEpatents

Tonkovich, Anna Lee [Marysville, OH; Qiu, Dongming [Dublin, OH; Dritz, Terence Andrew [Worthington, OH; Neagle, Paul [Westerville, OH; Litt, Robert Dwayne [Westerville, OH; Arora, Ravi [Dublin, OH; Lamont, Michael Jay [Hilliard, OH; Pagnotto, Kristina M [Cincinnati, OH

2007-07-31

The disclosed invention relates to a process for separating methane or nitrogen from a fluid mixture comprising methane and nitrogen, the process comprising: (A) flowing the fluid mixture into a microchannel separator, the microchannel separator comprising a plurality of process microchannels containing a sorption medium, the fluid mixture being maintained in the microchannel separator until at least part of the methane or nitrogen is sorbed by the sorption medium, and removing non-sorbed parts of the fluid mixture from the microchannel separator; and (B) desorbing the methane or nitrogen from the sorption medium and removing the desorbed methane or nitrogen from the microchannel separator. The process is suitable for upgrading methane from coal mines, landfills, and other sub-quality sources.

Characterization of upgraded hydrogel biochar from blended rice husk with coal fly ash

NASA Astrophysics Data System (ADS)

Ahmad, Nurul Farhana; Alias, Azil Bahari; Talib, Norhayati; Rashid, Zulkifli Abd; Ghani, Wan Azlina Wan Ab Karim

2017-12-01

Rice husk biochar (RB) blended with coal fly ash (CFA) is used as a material to develop hydrogel for heavy metal removal. This combination, namely hydrogel rice husk biochar-coal fly ash (HRB-CFA) composite is synthesized by embedding the biochar into acrylamide (AAM) as monomer, with N,N'-Methylenebisacrylamide (MBA) as crosslinker and ammonium persulfate (APS) as initiator. While activated carbon (AC) remains an expensive material, HRB-CFA is attracting great interest for its use in the absorption of organic contaminants due to its low material cost and importance as renewable source for securing future energy supply in the environmental system. Although the CFA does not have the surface area as high as AC, certain metallic components that are naturally present in the CFA can play the catalytic role in the removal of heavy metal from wastewater. The percentage of heavy metal removal is depends on the parameters that influence the sorption process; the effect of pH solution, dosage of adsorbent, initial concentration of solution, and contact time. The aim of this study is to characterize HRB-CFA by performing several analyses such as the Brunauer-Emmett-Teller (BET), thermogravimetric (TGA) and field emission scanning electron microscopy (FESEM) methods. The results obtained revealed that the best hydrogel ratio is 0.5:0.5 of blended RB and CFA, as proven by BET surface area, pore volume and pore size of 3.5392 m2/g, 0.00849 cm3/g and 90.566 Å, and the surface morphology showed an increase in porosity size.

The Development of Oil Incendiary Bombs

DTIC Science & Technology

1942-02-07

fire to wooden structures, such as attics, and markedly superior to four pound thormate bombs. Rubber gels and soap gels arc equally good in non...tures. Gasolines or naphthas having final boiling points of from 250 to 500°F. when properly thickened v.’ith rubber or soaps, do not flash burn nor...thickening t gents* h.’ve shown that (1) if rubber is used, less l.- tex than crope or smoked 3hoet is required for t ^iven degree of thickening, (2

U.S. Geological Survey science for the Wyoming Landscape Conservation Initiative—2014 annual report

USGS Publications Warehouse

Bowen, Zachary H.; Aldridge, Cameron L.; Anderson, Patrick J.; Assal, Timothy J.; Bartos, Timothy T.; Biewick, Laura R; Boughton, Gregory K.; Chalfoun, Anna D.; Chong, Geneva W.; Dematatis, Marie K.; Eddy-Miller, Cheryl A.; Garman, Steven L.; Germaine, Stephen S.; Homer, Collin G.; Huber, Christopher; Kauffman, Matthew J.; Latysh, Natalie; Manier, Daniel; Melcher, Cynthia P.; Miller, Alexander; Miller, Kirk A.; Olexa, Edward M.; Schell, Spencer; Walters, Annika W.; Wilson, Anna B.; Wyckoff, Teal B.

2015-01-01

Finally, capabilities of the WLCI Web site and the USGS ScienceBase infrastructure were maintained and upgraded to help ensure access to and efficient use of all the WLCI data, products, assessment tools, and outreach materials that have been developed. Of particular note is the completion of three Web applications developed for mapping (1) the 1900−2008 progression of oil and gas development;(2) the predicted distributions of Wyoming’s Species of Greatest Conservation Need; and (3) the locations of coal and wind energy production, sage-grouse distribution and core management areas, and alternative routes for transmission lines within the WLCI region. Collectively, these applications tools provide WLCI planners and managers with powerful tools for better understanding the distributions of wildlife species and potential alternatives for energy development.

Impacts of the Minamata Convention for Mercury Emissions from Coal-fired Power Generation in Asia

NASA Astrophysics Data System (ADS)

Giang, A.; Stokes, L. C.; Streets, D. G.; Corbitt, E. S.; Selin, N. E.

2014-12-01

We explore the potential implications of the recently signed United Nations Minamata Convention on Mercury for emissions from coal-fired power generation in Asia, and the impacts of these emissions changes on deposition of mercury worldwide by 2050. We use qualitative interviews, document analysis, and engineering analysis to create plausible technology scenarios consistent with the Convention, taking into account both technological and political factors. We translate these scenarios into possible emissions inventories for 2050, based on IPCC development scenarios, and then use the GEOS-Chem global transport model to evaluate the effect of these different technology choices on mercury deposition over geographic regions and oceans. We find that China is most likely to address mercury control through co-benefits from technologies for SO2, NOx, and particulate matter (PM) capture that will be required to attain its existing air quality goals. In contrast, India is likely to focus on improvements to plant efficiency such as upgrading boilers, and coal washing. Compared to current technologies, we project that these changes will result in emissions decreases of approximately 140 and 190 Mg/yr for China and India respectively in 2050, under an A1B development scenario. With these emissions reductions, simulated average gross deposition over India and China are reduced by approximately 10 and 3 μg/m2/yr respectively, and the global average concentration of total gaseous mercury (TGM) is reduced by approximately 10% in the Northern hemisphere. Stricter, but technologically feasible, requirements for mercury control in both countries could lead to an additional 200 Mg/yr of emissions reductions. Modeled differences in concentration and deposition patterns between technology suites are due to differences in both the mercury removal efficiency of technologies and their resulting stack speciation.

Low-temperature upgrading of low-calorific biogas for CO2 mitigation using DBD-catalyst hybrid reactor

NASA Astrophysics Data System (ADS)

Nozaki, Tomohiro; Tsukijihara, Hiroyuki; Fukui, Wataru; Okazaki, Ken

2006-10-01

Although huge amounts of biogas, which consists of 20-60% of CH4 in CO2/N2, can be obtained from landfills, coal mines, and agricultural residues, most of them are simply flared and wasted: because global warming potential of biogas is 5-15 times as potent as CO2. Poor combustibility of such biogas makes it difficult to utilize in conventional energy system. The purpose of this project is to promote the profitable recovery of methane from poor biogas via non-thermal plasma technology. We propose low-temperature steam reforming of biogas using DBD generated in catalyst beds. Methane is partially converted into hydrogen, and then fed into internal combustion engines for improved ignition stability as well as efficient operation. Low-temperature steam reforming is beneficial because exhaust gas from an engine can be used to activate catalyst beds. Space velocity (3600-15000 hr-1), reaction temperature (300-650^oC), and energy cost (30-150 kJ per mol CH4) have been investigated with simulated biogas (20-60% CH4 in mixtures of CO2/N2). The DBD enhances reaction rate of CH4 by a factor of ten at given catalyst temperatures, which is a rate-determining step of methane steam reforming, while species concentration of upgraded biogas was governed by thermodynamic equilibrium in the presence of catalyst.

High-quality fuel from food waste - investigation of a stepwise process from the perspective of technology development.

PubMed

Yin, Ke; Li, Ling; Giannis, Apostolos; Weerachanchai, Piyarat; Ng, Bernard J H; Wang, Jing-Yuan

2017-07-01

A stepwise process (SP) was developed for sustainable energy production from food waste (FW). The process comprised of hydrothermal treatment followed by oil upgrading. Synthetic food waste was primarily used as feedstock in the hydrothermal reactor under subcritical water conditions. The produced hydrochars were analyzed for calorific value (17.0-33.7 MJ/kg) and elemental composition indicating high-quality fuel comparable to coal. Hydrothermal carbonization (e.g. 180°C) would be efficient for oil recovery (>90%) from FW, as compared to hydrothermal liquefaction (320°C) whereby lipid degradation may take place. The recovered oil was upgraded to biodiesel in a catalytic refinery process. Selected biodiesels, that is, B3 and B4 were characterized for density (872.7 and 895.5 kg/m 3 ), kinematic viscosity (3.115 and 8.243 cSt), flash and pour point (30°C and >126°C), micro carbon (0.03% and 0.04%), sulfur (both <0.0016%), and calorific value (38,917 and 39,584 J/g), suggesting similar quality to commercial biodiesel. Fatty acid methyl ethers content was further analyzed to assess the influence of hydrothermal treatment in biodiesel quality, indicating the limited impacts. Overall, the SP provides a promising alternative for sustainable energy recovery through high-quality biofuel and hydrochar production.

Method of upgrading oils containing hydroxyaromatic hydrocarbon compounds to highly aromatic gasoline

DOEpatents

Baker, Eddie G.; Elliott, Douglas C.

1993-01-01

The present invention is a multi-stepped method of converting an oil which is produced by various biomass and coal conversion processes and contains primarily single and multiple ring hydroxyaromatic hydrocarbon compounds to highly aromatic gasoline. The single and multiple ring hydroxyaromatic hydrocarbon compounds in a raw oil material are first deoxygenated to produce a deoxygenated oil material containing single and multiple ring aromatic compounds. Then, water is removed from the deoxygenated oil material. The next step is distillation to remove the single ring aromatic compouns as gasoline. In the third step, the multiple ring aromatics remaining in the deoxygenated oil material are cracked in the presence of hydrogen to produce a cracked oil material containing single ring aromatic compounds. Finally, the cracked oil material is then distilled to remove the single ring aromatics as gasoline.

Method of upgrading oils containing hydroxyaromatic hydrocarbon compounds to highly aromatic gasoline

DOEpatents

Baker, E.G.; Elliott, D.C.

1993-01-19

The present invention is a multi-stepped method of converting an oil which is produced by various biomass and coal conversion processes and contains primarily single and multiple ring hydroxyaromatic hydrocarbon compounds to highly aromatic gasoline. The single and multiple ring hydroxyaromatic hydrocarbon compounds in a raw oil material are first deoxygenated to produce a deoxygenated oil material containing single and multiple ring aromatic compounds. Then, water is removed from the deoxygenated oil material. The next step is distillation to remove the single ring aromatic compounds as gasoline. In the third step, the multiple ring aromatics remaining in the deoxygenated oil material are cracked in the presence of hydrogen to produce a cracked oil material containing single ring aromatic compounds. Finally, the cracked oil material is then distilled to remove the single ring aromatics as gasoline.

Effect of naphtha diluent on greenhouse gases and reduced sulfur compounds emissions from oil sands tailings.

PubMed

Gee, Kathleen F; Poon, Ho Yin; Hashisho, Zaher; Ulrich, Ania C

2017-11-15

The long-term storage of oil sands tailings has resulted in the evolution of greenhouse gases (CH 4 and CO 2 ) as a result of residual organics biodegradation. Recent studies have identified black, sulfidic zones below the tailings-water interface, which may be producing toxic sulfur-containing gases. An anaerobic mesocosm study was conducted over an 11-week period to characterize the evolution of CH 4 , CO 2 and reduced sulfur compounds (RSCs) (including H 2 S) in tailings as it relates to naphtha-containing diluent concentrations (0.2, 0.8, and 1.5% w/v) and microbial activity. Our results showed that RSCs were produced first at 0.12μmol°RSCs/mL MFT (1.5% w/v diluent treatment). RSCs contribution (from highest to lowest) was H 2 S and 2-methylthiophene>2.5-dimethylthiophene>3-methylthiophene>thiofuran>butyl mercaptan>carbonyl sulfide, where H 2 S and 2-methylthiophene contributed 81% of the gas produced. CH 4 and CO 2 production occurred after week 5 at 40.7μmolCH 4 /mL MFT and 5.9μmolCO 2 /mL MFT (1.5% w/v diluent treatment). The amount of H 2 S and CH 4 generated is correlated to the amount of diluent present and to microbial activity as shown by corresponding increases in sulfate-reducers' Dissimilatory sulfite reductase (DsrAB) gene and methanogens' methyl-coenzyme M reductase (MCR) gene. Copyright © 2017 Elsevier B.V. All rights reserved.

Evaluation of Mobil OCTGAIN{trademark} technology for the manufacture of reformulated gasoline via LP modeling

DOE Office of Scientific and Technical Information (OSTI.GOV)

Poddar, S.K.; Chum, K.; Ragsdale, R.

1995-09-01

Sulfur and olefins content of gasoline come primarily from the cat-cracked blendstock. Therefore hydrotreating cat cracked naphtha is a straight forward approach to reduce sulfur and olefin contents of gasoline and thereby reduce auto exhaust emission. However, this approach reduces the Octane number of gasoline which requires addition of Octane enhancer like MTBE to meet the stringent requirement of 1990 Clean Air Act Amendments and to produce Reformulated Gasoline (RFG). The paper examines the economic incentives of an innovative process technology which was developed and commercialized by Mobil known as OCTGAIN. The process utilizes fixed bed low pressure hardware andmore » uses a Mobil proprietary catalyst system to produce catalytically cracked (CC) gasoline component with thorough desulfurization and olefin reduction and practically no loss in Octane number. The economic evaluation of the OCTGAIN technology was conducted with Bechtel`s proprietary linear programming software, Process Industry Modeling System by introducing an OCTGAIN process block to a typical PADD-3 refinery configuration for gasoline production and satisfying RFG specifications. The results of the evaluation which involved twenty case studies, show that within the limitations of the study scope, the introduction of OCTGAIN technology creates a definite economic incentive over conventional hydrofinishing of CC naphtha. The profitability of OCTGAIN technology is dependent on the aromatics component of the gasoline pool. The economic advantage of OCTGAIN technology is realized primarily by higher production of premium gasoline and the ability to process lower cost high sulfur crude. The process also allows a better utilization of the FCCU and hydrocracker, if the refinery operation permits.« less

Recent progress on biomass co-pyrolysis conversion into high-quality bio-oil.

PubMed

Hassan, H; Lim, J K; Hameed, B H

2016-12-01

Co-pyrolysis of biomass with abundantly available materials could be an economical method for production of bio-fuels. However, elimination of oxygenated compounds poses a considerable challenge. Catalytic co-pyrolysis is another potential technique for upgrading bio-oils for application as liquid fuels in standard engines. This technique promotes the production of high-quality bio-oil through acid catalyzed reduction of oxygenated compounds and mutagenic polyaromatic hydrocarbons. This work aims to review and summarize research progress on co-pyrolysis and catalytic co-pyrolysis, as well as their benefits on enhancement of bio-oils derived from biomass. This review focuses on the potential of plastic wastes and coal materials as co-feed in co-pyrolysis to produce valuable liquid fuel. This paper also proposes future directions for using this technique to obtain high yields of bio-oils. Copyright © 2016 Elsevier Ltd. All rights reserved.

Ocean thermal plantships for production of ammonia as the hydrogen carrier.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Panchal, C.B.; Pandolfini, P. P.; Kumm, W. H.

2009-12-02

Conventional petroleum, natural gas, and coal are the primary sources of energy that have underpinned modern civilization. Their continued availability in the projected quantities required and the impacts of emission of greenhouse gases (GHGs) on the environment are issues at the forefront of world concerns. New primary sources of energy are being sought that would significantly reduce the emissions of GHGs. One such primary source that can help supply energy, water, and fertilizer without GHG emissions is available in the heretofore unexploited thermal gradients of the tropical oceans. The world's oceans are the largest natural collector and reservoir of solarmore » energy. The potential of ocean energy is limitless for producing base-load electric power or ammonia as the hydrogen carrier and fresh water from seawater. However, until now, ocean energy has been virtually untapped. The general perception is that ocean thermal energy is limited to tropical countries. Therefore, the full potential of at-sea production of (1) ammonia as a hydrogen carrier and (2) desalinated water has not been adequately evaluated. Using ocean thermal plantships for the at-sea co-production of ammonia as a hydrogen carrier and desalinated water offer potential energy, environmental, and economic benefits that support the development of the technology. The introduction of a new widespread solution to our projected energy supply requires lead times of a decade or more. Although continuation of the ocean thermal program from the 1970s would likely have put us in a mitigating position in the early 2000s, we still have a window of opportunity to dedicate some of our conventional energy sources to the development of this renewable energy by the time new sources would be critically needed. The primary objective of this project is to evaluate the technical and economic viability of ocean thermal plantships for the production of ammonia as the hydrogen carrier. This objective is achieved by completing project tasks that consist of updating the John Hopkins University/Applied Physics Laboratory (JHU/APL) pilot plantship design and extrapolating it to commercial plantships, evaluating a new energy-efficient ammonia synthesis process, evaluating the co-production of desalinated water on plantships, and developing a conceptual design of a satellite plantships system for commercial-scale ammonia production. In addition, an industrial workshop was organized to present the results and develop future goals for commercialization of ocean thermal plantships by 2015. The following goals, arranged in chronological order, were examined at the workshop: (1) Global displacement of petroleum-fuel-based (diesel, fuel oil, naphtha) power generation for freeing up these fuels for transportation, chemical feedstock, and other high-valued uses; (2) At-sea production of desalinated water for regions of critical water shortages; (3) Displacement of carbon-based feed stocks and energy for production of ammonia fertilizers; (4) Development of hydrogen supply to allow economic processing of heavy crude oils and upgrading oil sands; (5) Development of ammonia-fueled distributed energy to displace natural-gas fueled power generation to free up natural gas for higher-value uses and the mitigation of issues associated with imported liquefied natural gas (LNG); and (6) Use of ammonia as a hydrogen carrier for transportation.« less

Advanced fuel system technology for utilizing broadened property aircraft fuels

NASA Technical Reports Server (NTRS)

Reck, G. M.

1980-01-01

Factors which will determine the future supply and cost of aviation turbine fuels are discussed. The most significant fuel properties of volatility, fluidity, composition, and thermal stability are discussed along with the boiling ranges of gasoline, naphtha jet fuels, kerosene, and diesel oil. Tests were made to simulate the low temperature of an aircraft fuel tank to determine fuel tank temperatures for a 9100-km flight with and without fuel heating; the effect of N content in oil-shale derived fuels on the Jet Fuel Thermal Oxidation Tester breakpoint temperature was measured. Finally, compatibility of non-metallic gaskets, sealants, and coatings with increased aromatic content jet fuels was examined.

Reforming process

DOE Office of Scientific and Technical Information (OSTI.GOV)

Mitsche, R.T.; Pope, G.N.

A process for reforming a naphtha feedstock is disclosed. The reforming process is effected at reforming conditions in contact with a catalyst comprising a platinum group metal component and a group iv-a metal component composited with an alumina support wherein said support is prepared by admixing an alpha alumina monohydrate with an aqueous ammoniacal solution having a ph of at least about 7.5 to form a stable suspension. A salt of a strong acid, e.g., aluminum nitrate, is commingled with the suspension to form an extrudable paste or dough. On extrusion, the extrudate is dried and calcined to form saidmore » alumina support.« less

Application of SOFC for electric vehicle

DOE Office of Scientific and Technical Information (OSTI.GOV)

Yamada, K.; Mizusaki, J.; Sasaki, H.

1995-12-31

Changing from gasoline powered vehicles to electric vehicles (EVs) will provide positive environmental effects. A present disadvantage of EVs with secondary battery systems is a short driving range. This can be improved by the application of a hybrid system of SOFCs and batteries. For that system, both tubular and planer types of SOFCs having 10kW power are designed which can be used for passenger cars with naphtha as fuel operated at 880--850 C . The tubular type has 106 liters in volume and 100kg in weight, and were smaller and lighter than the planer type. Subjects to be investigated onmore » SOFCs for EVs are described.« less

Automated Boiler Combustion Controls for Emission Reduction and Efficiency Improvement

DOE Office of Scientific and Technical Information (OSTI.GOV)

None, None

1998-12-02

In the late 1980s, then President Bush visited Krakow, Poland. The terrible air quality theremotivated him to initiate a USAID-funded program, managed by DOE, entitled "Krakow Clean Fossil Fuels and Energy Efficiency Program." The primary objective of this program was to encourage the formation of commercial ventures between U.S. and Polish firms to provide equipment and/or services to reduce pollution from low-emission sources in Krakow, Poland. This program led to the award of a number of cooperative agreements, including one to Control Techtronics International. The technical objective of CTI's cooperative agreement is to apply combustion controls to existing boiler plantsmore » in Krakow and transfer knowledge and technology through a joint U.S. and Polish commercial venture. CTI installed automatic combustion controls on five coal boilers for the district heating system in Krakow. Three of these were for domestic hot-water boilers, and two were for steam for industrial boilers. The following results have occurred due to the addition of CTI's combustion controls on these five existing boilers: ! 25% energy savings ! 85% reduction in particulate emissions The joint venture company CTI-Polska was then established. Eleven additional technical and costing proposals were initiated to upgrade other coal boilers in Krakow. To date, no co-financing has been made available on the Polish side. CTI-Polska continues in operation, serving customers in Russia and Ukraine. Should the market in Poland materialize, the joint venture company is established there to provide equipment and service.« less

Successful Strategies for Rapidly Upgrading PTC Windchill 9.1 to Windchill 10.1 on a Light Budget

NASA Technical Reports Server (NTRS)

Shearrow, Charles A.

2013-01-01

Topics covered include: The Frugal Times Historical Upgrade Process; Planning for Possible Constraints; PTC Compatibility Matrix; In-Place Upgrade Process; Pre-Upgrade Activities; Upgrade Activities; Post Upgrade Activities; Results of the Upgrade; Tips for an Upgrade On a Shoestring Budget.

Characterization of Volatile Organic Compound (VOC) Emissions at Sites of Oil Sands Extraction and Upgrading in northern Alberta

NASA Astrophysics Data System (ADS)

Marrero, J.; Simpson, I. J.; Meinardi, S.; Blake, D. R.

2011-12-01

The crude oil reserves in Canada's oil sands are second only to Saudi Arabia, holding roughly 173 billion barrels of oil in the form of bitumen, an unconventional crude oil which does not flow and cannot be pumped without heating or dilution. Oil sands deposits are ultimately used to make the same petroleum products as conventional forms of crude oil, though more processing is required. Hydrocarbons are the basis of oil, coal and natural gas and are an important class of gases emitted into the atmosphere during oil production, particularly because of their effects on air quality and human health. However, they have only recently begun to be independently assessed in the oil sands regions. As part of the 2008 ARCTAS airborne mission, whole air samples were collected in the boundary layer above the surface mining operations of northern Alberta. Gas chromatography analysis revealed enhanced concentrations of 53 VOCs (C2 to C10) over the mining region. When compared to local background levels, the measured concentrations were enhanced up to 1.1-400 times for these compounds. To more fully characterize emissions, ground-based studies were conducted in summer 2010 and winter 2011 in the oil sands mining and upgrading areas. The data from the 200 ground-based samples revealed enhancements in the concentration of 65 VOCs. These compounds were elevated up to 1.1-3000 times above background concentrations and include C2-C8 alkanes, C1-C5 alkyl nitrates, C2-C4 alkenes and potentially toxic aromatic compounds such as benzene, toluene, and xylenes.

Maximising Longwall performance and profitability by the introduction of moving car bunker systems into outbye haulage layouts

DOE Office of Scientific and Technical Information (OSTI.GOV)

Barlow, P.M.

1996-12-31

In order to maximize the profitability of Longwall mining operations, outbye materials handling systems should be cost effectively engineered to both fully harmonize with cyclical surges in output and to maintain high levels of availability. With the introduction of new Longwall systems into existing mines, the upgrading of outbye haulage to handle peak production from the Longwall panel can prove to be extremely expensive and is often unnecessary. In addition, despite high levels of investment in new equipment, many mines are still failing to achieve planned gains in Longwall productivity due to persistent downtime on outbye haulage routes. This papermore » details the planning, production and engineering considerations necessary to maximize profitability by the introduction of moving car bunker systems to underground haulage layouts. It also examines case studies of recent installations within the North American coal mining industry and charts the significant success being achieved in improving profitability at these mines.« less

Energy usage, problems and policy proposals: evidence from distinctive villages in poverty-stricken loess areas

NASA Astrophysics Data System (ADS)

Xie, Xinglong; Xue, Weixian

2018-02-01

The aim of this paper is to examine energy consumption among poverty-stricken loess areas of middle Gansu, and put forward a settlement to energy upgrading and meanwhile mitigating environmental contagion and shaking off poverty. Energy consumption of 371 households from 3 distinctive categories of landform is explored. The surveyed data investigation displays that energy consumption composition is marked by clear dissimilarity of power mix, with stalk(41%) and coal(32.3%) acting as the major form, fire grass a powerful supplement, and the remaining power resources playing a tiny part for the mountain; coal(52.45%) being the dominant power, dry grasses(20%) and stalk (17.6%) performing a supplemental part, other resources of power being at the insignificant position for the semi-mountain; beside which there being a similar energy pattern on the plain except stalk composing a tiny share of 7.5%. This energy mix is mainly attributed to economic poverty, and provokes a list of ills such as plant damage, water loss and soil erosion, ultimately posing a formidable threat to sustainable development. A fresh energy engineering mode termed quaternity-dominating pattern is introduced and addressed, which can lift the sample areas out of poverty both in economics and energy. The paper concludes with pointing out practical proposals on launching and running this energy engineering project for the sample areas. This paper contributes to the growing body of knowledge by exploring energy use among poverty-stricken regions, usually being disregarded in most studies of China.

Long-Term Carbon Injection Field Test for 90% Mercury Removal for a PRB Unit a Spray Dryer and Fabric Filter

DOE Office of Scientific and Technical Information (OSTI.GOV)

Sjostrom, Sharon; Amrhein, Jerry

2009-04-30

The power industry in the U.S. is faced with meeting regulations to reduce the emissions of mercury compounds from coal-fired plants. Injecting a sorbent such as powdered activated carbon (PAC) into the flue gas represents one of the simplest and most mature approaches to controlling mercury emissions from coal-fired boilers. The purpose of this test program was to evaluate the long-term mercury removal capability, long-term mercury emissions variability, and operating and maintenance (O&M) costs associated with sorbent injection on a configuration being considered for many new plants. Testing was conducted by ADA Environmental Solutions (ADA) at Rocky Mountain Power’s (RMP)more » Hardin Station through funding provided by DOE/NETL, RMP, and other industry partners. The Hardin Station is a new plant rated at 121 MW gross that was first brought online in April of 2006. Hardin fires a Powder River Basin (PRB) coal and is configured with selective catalytic reduction (SCR) for NOx control, a spray dryer absorber (SDA) for SO2 control, and a fabric filter (FF) for particulate control. Based upon previous testing at PRB sites with SCRs, very little additional mercury oxidation from the SCR was expected at Hardin. In addition, based upon results from DOE/NETL Phase II Round I testing at Holcomb Station and results from similarly configured sites, low native mercury removal was expected across the SDA and FF. The main goal of this project was met—sorbent injection was used to economically and effectively achieve 90% mercury control as measured from the air heater (AH) outlet to the stack for a period of ten months. This goal was achieved with DARCO® Hg-LH, Calgon FLUEPAC®-MC PLUS and ADA Power PAC PREMIUM brominated activated carbons at nominal loadings of 1.5–2.5 lb/MMacf. An economic analysis determined the twenty-year levelized cost to be 0.87 mills/kW-hr, or $15,000/lb Hg removed. No detrimental effects on other equipment or plant operations were observed. The results of this project also filled a data gap for plants firing PRB coal and configured with an SCR, SDA, and FF, as many new plants are being designed today. Another goal of the project was to evaluate, on a short-term basis, the mercury removal associated with coal additives and coal blending with western bituminous coal. The additive test showed that, at this site, the coal additive known as KNX was affective at increasing mercury removal while decreasing sorbent usage. Coal blending was conducted with two different western bituminous coals, and West Elk coal increased native capture from nominally 10% to 50%. Two additional co-benefits were discovered at this site. First, it was found that native capture increased from nominally 10% at full load to 50% at low load. The effect is believed to be due to an increase in mercury oxidation across the SCR caused by a corresponding decrease in ammonia injection when the plant reduces load. Less ammonia means more active oxidation sites in the SCR for the mercury. The second co-benefit was the finding that high ammonia concentrations can have a negative impact on mercury removal by powdered activated carbon. For a period of time, the plant operated with a high excess of ammonia injection necessitated by the plugging of one-third of the SCR. Under these conditions and at high load, the mercury control system could not maintain 90% removal even at the maximum feed rate of 3.5 lb/MMacf (pounds of mercury per million actual cubic feet). The plant was able to demonstrate that mercury removal was directly related to the ammonia injection rate in a series of tests where the ammonia rate was decreased, causing a corresponding increase in mercury removal. Also, after the SCR was refurbished and ammonia injection levels returned to normal, the mercury removal performance also returned to normal. Another goal of the project was to install a commercial-grade activated carbon injection (ACI) system and integrate it with new-generation continuous emissions monitors for mercury (Hg-CEMs) to allow automatic feedback control on outlet mercury emissions. This was accomplished and the plant can now be operated to control carbon injection based on either the overall mercury removal or an outlet mercury emission rate. By integrating these systems, it was determined that the plant could reduce powdered activated carbon consumption, especially at low load, because, at Hardin, native mercury capture increases from less than 20% to about 50% at low load and the carbon injection rate can be decreased accordingly. Currently, the plant is operating to automatically control emissions to below 0.9 lb/TBtu (pounds of mercury per million British thermal units) at carbon loadings of 0.5 to 1.5 lb/MMacf. During the final phase of the Long-Term test, the ACI system was operated by plant personnel. The estimated O&M cost for a single Hg-CEM system is $15,500/yr. The Hg-CEMs performed well throughout the project. This project began shortly after Thermo Fisher first offered the Mercury Freedom System™ on a commercial basis and progressed though several iterations, improvements, and upgrades to the hardware and software. Indeed, there was a ten-fold increase in the precision and accuracy of the units during the course of the project due to several successful upgrades. In their present condition, the Hg-CEMs measure mercury to a precision of about ± 0.05 μg/wscm (micrograms of mercury per wet standard cubic meter of gas), and only require occasional fine-tuning of the calibration coefficients. The quality assurance/quality control (QA/QC) protocol required to keep the units operating at their optimal performance was also developed and perfected during the course of the project. ADA Environmental Solutions (ADA) developed a daily calibration procedure that surpasses the requirements specified in the Clean Air Mercury Rule (CAMR), and a weekly diagnostic program that ensures that the systems are operating properly and receive the necessary maintenance. For the most part, the systems passed the daily, weekly, and quarterly QA/QC requirements as well as four performance verification tests using the Ontario Hydro (O-H) and Sorbent Trap Methods (STM) for the first test and the EPA Method 30A (M30A) procedure for the remaining three. However, some improvements are still necessary before the system can meet all of the requirements. These involve tests that challenge the system with oxidized mercury (Hg+2). These tests could not be passed at Hardin in spite of trying several improvements suggested by ADA or Thermo Fisher.« less

Steam reforming of n-hexane on pellet and monolithic catalyst beds. A comparative study on improvements due to heat transfer

NASA Technical Reports Server (NTRS)

1981-01-01

Monolithic catalysts with higher available active surface areas and better thermal conductivity than conventional pellets beds, making possible the steam reforming of fuels heavier than naphtha, were examined. Performance comparisons were made between conventional pellet beds and honeycomb monolith catalysts using n-hexane as the fuel. Metal-supported monoliths were examined. These offer higher structural stability and higher thermal conductivity than ceramic supports. Data from two metal monoliths of different nickel catalyst loadings were compared to pellets under the same operating conditions. Improved heat transfer and better conversion efficiencies were obtained with the monolith having higher catalyst loading. Surface-gas interaction was observed throughout the length of the monoliths.

User and Performance Impacts from Franklin Upgrades

DOE Office of Scientific and Technical Information (OSTI.GOV)

He, Yun

2009-05-10

The NERSC flagship computer Cray XT4 system"Franklin" has gone through three major upgrades: quad core upgrade, CLE 2.1 upgrade, and IO upgrade, during the past year. In this paper, we will discuss the various aspects of the user impacts such as user access, user environment, and user issues etc from these upgrades. The performance impacts on the kernel benchmarks and selected application benchmarks will also be presented.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Wang, X.; Xiao, Y.; Xu, S.

A co-production system based on Fischer-Tropsch (FT) synthesis reactor and gas turbine was simulated and analyzed. Syngas from entrained bed coal gasification was used as feedstock of the low-temperature slurry phase Fischer-Tropsch reactor. Raw synthetic liquid produced was fractioned and upgraded to diesel, gasoline, and liquid petrol gas (LPG). Tail gas composed of unconverted syngas and FT light components was fed to the gas turbine. Supplemental fuel (NG, or refinery mine gas) might be necessary, which was dependent on gas turbine capacity expander through flow capacity, etc. FT yield information was important to the simulation of this co-production system. Amore » correlation model based on Mobil's two step pilot plant was applied. User models that can predict product yields and cooperate with other units were embedded into Aspen plus simulation. Performance prediction of syngas fired gas turbine was the other key of this system. The increase in mass flow through the turbine affects the match between compressor and turbine operating conditions. The calculation was carried out by GS software developed by Politecnico Di Milano and Princeton University. Various cases were investigated to match the FT synthesis island, power island, and gasification island in co-production systems. Effects of CO{sub 2} removal/LPG recovery, co-firing, and CH{sub 4} content variation were studied. Simulation results indicated that more than 50% of input energy was converted to electricity and FT products. Total yield of gasoline, diesel, and LPG was 136-155 g/N m{sup 3} (CO+H{sub 2}). At coal feed of 21.9 kg/s, net electricity exported to the grid was higher than 100 MW. Total production of diesel and gasoline (and LPG) was 118,000 t (134,000 t)/year. Under the economic analysis conditions assumed in this paper the co-production system was economically feasible.« less

Upgrading in an Industrial Setting. Final Report.

ERIC Educational Resources Information Center

Russell, Wendell

The project objectives were: (1) to assess existing industrial upgrading practices in an Atomic Energy Commission contractor organization, (2) to design new alternative upgrading methods, (3) to experiment with new upgrading methods, (4) to plan for utilization of proven upgrading programs, and (5) to document and disseminate activities. A twelve…

Indirect Liquefaction of Coal-Biomass Mixture for Production of Jet Fuel with High Productivity and Selectivity

DOE Office of Scientific and Technical Information (OSTI.GOV)

Gangwal, Santosh K; McCabe, Kevin

Coal to liquids (CTL) and coal-biomass to liquids (CBTL) processes were advanced by testing and demonstrating Southern Research’s sulfur tolerant nickel-based reforming catalyst and Chevron’s highly selective and active cobalt-zeolite hybrid Fischer-Tropsch (FT) catalyst to clean, upgrade and convert syngas predominantly to jet fuel range hydrocarbon liquids, thereby minimizing expensive cleanup and wax upgrading operations. The National Carbon Capture Center (NCCC) operated by Southern Company (SC) at Wilsonville, Alabama served as the host site for the gasifier slip-stream and simulated syngas testing/demonstration. Reformer testing was performed to (1) reform tar and light hydrocarbons, (2) decompose ammonia in the presence H2S,more » and (3) deliver the required H2 to CO ratio for FT synthesis. FT Testing was performed to produce a product primarily containing C5-C20 liquid hydrocarbons and no C21+ waxy hydrocarbons with productivity greater than 0.7 gC5+/g catalyst/h, and at least 70% diesel and jet fuel range (C8-C20) hydrocarbon selectivity in the liquid product. A novel heat-exchange reactor system was employed to enable the use of the highly active FT catalyst and larger diameter reactors that results in cost reduction for commercial systems. Following laboratory development and testing, SR’s laboratory reformer was modified to operate in a Class 1 Div. 2 environment, installed at NCCC, and successfully tested for 125 hours using raw syngas. The catalyst demonstrated near equilibrium reforming (~90%) of methane and complete reforming/decomposition of tar and ammonia in the presence of up to 380 ppm H2S. For FT synthesis, SR modified and utilized a bench scale skid mounted FT reactor system (SR-CBTL test rig) that was fully integrated with a slip stream from SC/NCCC’s transport gasifier (TRIG). The test-rig developed in a previous project (DE-FE0010231) was modified to receive up to 7.5 lb/h raw syngas augmented with bottled syngas to adjust the H2/CO molar ratio to 2, clean it to cobalt FT catalyst specifications, and produce liquid FT products at the design capacity of up to 6 L/day. Promising Chevron catalyst candidates in the size range from 70-200 μm were loaded onto SR’s 2-inch ID and 4-inch ID bench-scale reactors utilizing IntraMicron’s micro-fiber entrapped catalyst (MFEC) heat exchange reactor technology. During 2 test campaigns, the FT reactors were successfully demonstrated at NCCC using syngas for ~420 hours. The catalyst did not experience deactivation during the tests. SR’s thermo-syphon heat removal system maintained reactor operating temperature along the axis to within ±4 °C. The experiments gave a steady catalyst productivity of 0.7-0.8 g/g catalyst/h, liquid hydrocarbon selectivity of ~75%, and diesel and jet fuel range hydrocarbon selectivity in the liquid product as high as 85% depending on process conditions. A preliminary techno-economic evaluation showed that the SR technology-based 50,000 bpd plant had a 10 % lower total plant cost compared to a conventional slurry reactor based plant. Furthermore, because of the modular nature of the SR technology, it was shown that the total plant cost advantage increases to >35 % as the plant is scaled down to 1000 bpd.« less

Opening

ScienceCinema

Bruning, Oliver

2018-05-23

Overview of the operation and upgrade plans for the machine. Upgrade studies and taskforces. The Chamonix 2010 discussions led to five new task forces: planning for a long shut down in 2012 for splice consolidation; long term consolidation planning for the injector complex; SPS upgrade task force (accelerated program for SPS upgrade); PSB upgrade and its implications for the PS (e.g. radiation etc.); LHC High Luminosity project (investigate planning for ONE upgrade by 2018-2020); Launch of a dedicated study for doubling the beam energy in the LHC->HE-LHC.

Integrated science building

DOE Office of Scientific and Technical Information (OSTI.GOV)

Conklin, Shane

2013-09-30

Shell space fit out included faculty office advising space, student study space, staff restroom and lobby cafe. Electrical, HVAC and fire alarm installations and upgrades to existing systems were required to support the newly configured spaces. These installations and upgrades included audio/visual equipment, additional electrical outlets and connections to emergency generators. The project provided increased chilled water capacity with the addition of an electric centrifugal chiller. Upgrades associated with chiller included upgrade of exhaust ventilation fan, electrical conductor and breaker upgrades, piping and upgrades to air handling equipment.

Airborne Warning and Control System Block 40/45 Upgrade (AWACS Blk 40/45 Upgrade)

DTIC Science & Technology

2015-12-01

Selected Acquisition Report ( SAR ) RCS: DD-A&T(Q&A)823-277 Airborne Warning and Control System Block 40/45 Upgrade (AWACS Blk 40/45 Upgrade) As of...Upgrade December 2015 SAR March 23, 2016 16:04:37 UNCLASSIFIED 2 Table of Contents Common Acronyms and Abbreviations for MDAP Programs 3 Program...Acquisition Unit Cost AWACS Blk 40/45 Upgrade December 2015 SAR March 23, 2016 16:04:37 UNCLASSIFIED 3 PB - President’s Budget PE - Program Element

Cyclic Catalytic Upgrading of Chemical Species Using Metal Oxide Materials

NASA Technical Reports Server (NTRS)

White, James H. (Inventor); Rolfe, Sara L. (Inventor); Schutte, Erick J. (Inventor)

2013-01-01

Processes are disclosure which comprise alternately contacting an oxygen-carrying catalyst with a reducing substance, or a lower partial pressure of an oxidizing gas, and then with the oxidizing gas or a higher partial pressure of the oxidizing gas, whereby the catalyst is alternately reduced and then regenerated to an oxygenated state. In certain embodiments, the oxygen-carrying catalyst comprises at least one metal oxide-containing material containing a composition having the following formulas: (a) Ce(sub x)B(sub y)B'(sub z)B''O(sub gamma; wherein B=Ba, Sr, Ca, or Zr; B'=Mn, Co, and/or Fe; B''=Cu; 0.01

Cyclic catalytic upgrading of chemical species using metal oxide materials

DOEpatents

White, James H; Schutte, Erick J; Rolfe, Sara L

2013-05-07

Processes are disclosure which comprise alternately contacting an oxygen-carrying catalyst with a reducing substance, or a lower partial pressure of an oxidizing gas, and then with the oxidizing gas or a higher partial pressure of the oxidizing gas, whereby the catalyst is alternately reduced and then regenerated to an oxygenated state. In certain embodiments, the oxygen-carrying catalyst comprises at least one metal oxide-containing material containing a composition having the following formulas: (a) Ce.sub.xB.sub.yB'.sub.zB''O.sub..delta., wherein B=Ba, Sr, Ca, or Zr; B'=Mn, Co, and/or Fe; B''=Cu; 0.01

Production of bio-synthetic natural gas in Canada.

PubMed

Hacatoglu, Kevork; McLellan, P James; Layzell, David B

2010-03-15

Large-scale production of renewable synthetic natural gas from biomass (bioSNG) in Canada was assessed for its ability to mitigate energy security and climate change risks. The land area within 100 km of Canada's network of natural gas pipelines was estimated to be capable of producing 67-210 Mt of dry lignocellulosic biomass per year with minimal adverse impacts on food and fiber production. Biomass gasification and subsequent methanation and upgrading were estimated to yield 16,000-61,000 Mm(3) of pipeline-quality gas (equivalent to 16-63% of Canada's current gas use). Life-cycle greenhouse gas emissions of bioSNG-based electricity were calculated to be only 8.2-10% of the emissions from coal-fired power. Although predicted production costs ($17-21 GJ(-1)) were much higher than current energy prices, a value for low-carbon energy would narrow the price differential. A bioSNG sector could infuse Canada's rural economy with $41-130 billion of investments and create 410,000-1,300,000 jobs while developing a nation-wide low-carbon energy system.

Get a winning Oracle upgrade session using the quarterback approach

NASA Technical Reports Server (NTRS)

Anderson, G.

2002-01-01

Upgrades, upgrades... too much customer down time. Find out how we shrunk our production upgrade schedule 40% from our estimate of 10 days 12 hours to 6 days 2 hours using the quarterback approach. So your upgrade is not that complex, come anyway. This approach is scalable to any size project and will be extremely valuable.

Performance of the upgraded Orroral laser ranging system

NASA Technical Reports Server (NTRS)

Luck, John M.

1993-01-01

The topics discussed include the following: upgrade arrangements, system prior to 1991, elements of the upgrade, laser performance, timing system performance, pass productivity, system precision, system accuracy, telescope pointing and future upgrades and extensions.

From in situ coal to the final coal product: A case study of the Danville Coal Member (Indiana)

USGS Publications Warehouse

Mastalerz, Maria; Padgett, P.L.

1999-01-01

A surface coal mine operation and preparation plant in southwestern Indiana was sampled to examine variations in coal quality and coal petrography parameters for the Danville Coal Member of the Dugger Formation (Pennsylvanian-Desmoinesian, Westphalian D). Representative samples from in situ coal, preparation plant feeds, and a final coal product were collected in order to compare coal quality, coal petrography, trace element concentrations, and ash chemistry of the coal to those of the product. Coal quality parameters of the in situ samples and various feeds, coarse refuse, and final product were variable. The quality of the final coal product was best predicted by the coal quality of the clean coal feed (from the middle portions of the seam). Some trace element contents, especially lead and arsenic, varied between the coal feeds and the product. Lead contents increased in the feeds and product compared to the channel sample of the raw coal, possibly due to contamination in the handling process.A surface coal mine operation and preparation plant in southwestern Indiana was sampled to examine variations in coal quality and coal petrography parameters for the Danville Coal Member of the Dugger Formation (Pennsylvanian-Desmoinesian, Westphalian D). Representative samples from in situ coal, preparation plant feeds, and a final coal product were collected in order to compare coal quality, coal petrography, trace element concentrations, and ash chemistry of the coal to those of the product. Coal quality parameters of the in situ samples and various feeds, coarse refuse, and final product were variable. The quality of the final coal product was best predicted by the coal quality of the clean coal feed (from the middle portions of the seam). Some trace element contents, especially lead and arsenic, varied between the coal feeds and the product. Lead contents increased in the feeds and product compared to the channel sample of the raw coal, possibly due to contamination in the handling process.

Commissioning of the CMS Hadron Forward Calorimeters Phase I Upgrade

NASA Astrophysics Data System (ADS)

Bilki, B.; Onel, Y.

2018-03-01

The final phase of the CMS Hadron Forward Calorimeters Phase I Upgrade was performed during the Extended Year End Technical Stop of 2016-2017. In the framework of the upgrade, the PMT boxes were reworked to implement two channel readout in order to exploit the benefits of the multi-anode PMTs in background tagging and signal recovery. The front-end electronics were also upgraded to QIE10-based electronics which implement larger dynamic range and a 6-bit TDC. Following this major upgrade, the Hadron Forward Calorimeters were commissioned for operation readiness in 2017. Here we describe the details and the components of the upgrade, and discuss the operational experience and results obtained during the upgrade and commissioning.

Upgrading of Intermediate Bio-Oil Produced by Catalytic Pyrolysis

DOE Office of Scientific and Technical Information (OSTI.GOV)

Abdullah, Zia; Chadwell, Brad; Taha, Rachid

2015-06-30

The objectives of this project were to (1) develop a process to upgrade catalytic pyrolysis bio-oil, (2) investigate new upgrading catalysts suited for upgrading catalytic pyrolysis bio-oil, (3) demonstrate upgrading system operation for more than 1,000 hours using a single catalyst charge, and (4) produce a final upgraded product that can be blended to 30 percent by weight with petroleum fuels or that is compatible with existing petroleum refining operations. This project has, to the best of our knowledge, for the first time enabled a commercially viable bio-oil hydrotreatment process to produce renewable blend stock for transportation fuels.

Mass Storage System Upgrades at the NASA Center for Computational Sciences

NASA Technical Reports Server (NTRS)

Tarshish, Adina; Salmon, Ellen; Macie, Medora; Saletta, Marty

2000-01-01

The NASA Center for Computational Sciences (NCCS) provides supercomputing and mass storage services to over 1200 Earth and space scientists. During the past two years, the mass storage system at the NCCS went through a great deal of changes both major and minor. Tape drives, silo control software, and the mass storage software itself were upgraded, and the mass storage platform was upgraded twice. Some of these upgrades were aimed at achieving year-2000 compliance, while others were simply upgrades to newer and better technologies. In this paper we will describe these upgrades.

Exposure Evaluation for Benzene, Lead and Noise in Vehicle and Equipment Repair Shops

DOE Office of Scientific and Technical Information (OSTI.GOV)

Sweeney, Lynn C.

An exposure assessment was performed at the equipment and vehicle maintenance repair shops operating at the U. S. Department of Energy Hanford site, in Richland, Washington. The maintenance shops repair and maintain vehicles and equipment used in support of the Hanford cleanup mission. There are three general mechanic shops and one auto body repair shop. The mechanics work on heavy equipment used in construction, cranes, commercial motor vehicles, passenger-type vehicles in addition to air compressors, generators, and farm equipment. Services include part fabrication, installation of equipment, repair and maintenance work in the engine compartment, and tire and brake services. Workmore » performed at the auto body shop includes painting and surface preparation which involves applying body filler and sanding. 8-hour time-weighted-average samples were collected for benzene and noise exposure and task-based samples were collected for lead dust work activities involving painted metal surfaces. Benzene samples were obtained using 3M™ 3520 sampling badges and were analyzed for additional volatile organic compounds. These compounds were selected based on material safety data sheet information for the aerosol products used by the mechanics for each day of sampling. The compounds included acetone, ethyl ether, toluene, xylene, VM&P naphtha, methyl ethyl ketone, and trichloroethylene. Laboratory data for benzene, VM&P naphtha, methyl ethyl ketone and trichloroethylene were all below the reporting detection limit. Airborne concentrations for acetone, ethyl ether, toluene and xylene were all less than 10% of their occupational exposure limit. The task-based samples obtained for lead dusts were submitted for a metal scan analysis to identify other metals that might be present. Laboratory results for lead dusts were all below the reporting detection limit and airborne concentration for the other metals observed in the samples were less than 10% of the occupational exposure limit. Noise dosimetry sampling was performed on a random basis and was representative of the different work activities within the four shops. Twenty three percent of the noise samples exceeded the occupational exposure limit of 85 decibels for an 8-hour time-weightedaverage. Work activities where noise levels were higher included use of impact wrenches and grinding wheels.« less

DOE Office of Scientific and Technical Information (OSTI.GOV)

Folkedahl, Bruce

Much attention has been focused on renewable energy use in large-scale utilities and very small scale distributed energy systems. However, there is little information available regarding renewable energy options for midscale municipal utilities. The Willmar Municipal Utilities Corn Cob-Coal Co-Combustion Project was initiated to investigate opportunities available for small to midscale municipal utilities to "go green". The overall goal of the Project was to understand the current renewable energy research and energy efficiency projects that are or have been implemented at both larger and smaller scale and determine the applicability to midscale municipal utilities. More specific objectives for Task 2.0more » of this project were to determine the technical feasibility of co-combusting com cobs with coal in the existing WMU boiler, and to identify any regulatory issues that might need to be addressed if WMU were to obtain a significant portion of its heat from such co-combustion. This report addresses the issues as laid out in the study proposal. The study investigated the feasibility of and demonstrated the technical effectiveness of co-combusting corn cobs with coal in the Willmar Municipal Utilities stoker boiler steam generation power plant. The results of the WMU Co-Combustion Project will serve as a model for other midscale utilities who wish to use corn cobs to generate renewable electrical energy. As a result of the Co-Combustion Project, the WMU plans to upgrade their stoker boiler to accept whole corn cobs as well as other types of biomass, while still allowing the fuel delivery system to use 100% coal as needed. Benefits of co-combustion will include: energy security, reduced Hg and CO 2 air emissions, improved ash chemistry, potential future carbon credit sales, an immediate positive effect on the local economy, and positive attention focused on the WMU and the City of Willmar. The first step in the study was to complete a feasibility analysis. The feasibility analysis anticipated only positive results from the combustion of corn cobs with coal in the WMU power plant boiler, and therefore recommended that the project proceed. The study proceeded with a review of the existing WMU Power Plant configuration; cob fuel analyses; an application for an Air Quality Permit from the Minnesota Pollution Control Agency to conduct the co-combustion test burns; identification of and a site visit to a similar facility in Iowa; an evaluation of cob grinding machines; and agreements with a corn grower, a cob harvester, and the City of Willmar to procure, harvest, and store cobs. The WMU power plant staff constructed a temporary cob feed system whereby the cobs could be injected into the #3 Boiler firebox, at rates up to 40% of the boiler total heat input. Test burns were conducted, during which air emissions were monitored and fuel and ash samples analyzed. The results of the test burns indicated that the monitored flue gas quality improved slightly during the test burns. The WMU was able to determine that modifications to the #3 Boiler fuel feed system to accept com cobs on a permanent basis would be technically feasible and would enable the WMU to generate electricity from renewable fuels on a dispatchable basis.« less

Incidence, predictors, and procedural results of upgrade to resynchronization therapy: the RAFT upgrade substudy.

PubMed

Essebag, Vidal; Joza, Jacqueline; Birnie, David H; Sapp, John L; Sterns, Laurence D; Philippon, Francois; Yee, Raymond; Crystal, Eugene; Kus, Teresa; Rinne, Claus; Healey, Jeffrey S; Sami, Magdi; Thibault, Bernard; Exner, Derek V; Coutu, Benoit; Simpson, Chris S; Wulffhart, Zaev; Yetisir, Elizabeth; Wells, George; Tang, Anthony S L

2015-02-01

The resynchronization-defibrillation for ambulatory heart failure trial (RAFT) study demonstrated that adding cardiac resynchronization therapy (CRT) in selected patients requiring de novo implantable cardiac defibrillators (ICD) reduced mortality as compared with ICD therapy alone, despite an increase in procedure-related adverse events. Data are lacking regarding the management of patients with ICD therapy who develop an indication for CRT upgrade. Participating RAFT centers provided data regarding de novo CRT-D (CRT with ICD) implant, upgrade to CRT-D during RAFT (study upgrade), and upgrade within 6 months after presentation of study results (substudy). Substudy centers enrolled 1346 (74.9%) patients in RAFT, including 644 de novo, 80 study upgrade, and 60 substudy CRT attempts. The success rate (initial plus repeat attempts) was 95.2% for de novo versus 96.3% for study upgrade and 90.0% for substudy CRT attempts (P=0.402). Acute complications occurred among 26.2% of de novo versus 18.8% of study upgrade and 3.4% of substudy CRT implantation attempts (P<0.001). The most common complication was left ventricular lead dislodgement. The principal reasons for not yet attempting upgrade in the substudy were patient preference (31.9%), New York Heart Association Class I (17.0%), and a QRS<150 ms (13.1%). Among a broad group of implant physicians, CRT upgrades were performed in patients with an ICD in situ with no difference in implant success rate and a reduced acute complication rate as compared with a de novo CRT implant. Decisions to upgrade were influenced by predictors of benefit in subgroup analyses of the RAFT study and other trials. © 2014 American Heart Association, Inc.

Quality of economically extractable coal beds in the Gillette coal field as compared with other Tertiary coal beds in the Powder River basin, Wyoming and Montana

USGS Publications Warehouse

Ellis, Margaret S.

2002-01-01

The Powder River Basin, and specifically the Gillette coal field, contains large quantities of economically extractable coal resources. These coal resources have low total sulfur content and ash yield, and most of the resources are subbituminous in rank. A recent U.S Geological Survey study of economically extractable coal in the Gillette coal field focused on five coal beds, the Wyodak rider, Upper Wyodak, Canyon, Lower Wyodak-Werner, and Gates/Kennedy. This report compares the coal quality of these economically extractable coal beds to coal in the Wyodak-Anderson coal zone in the Powder River Basin and in the Gillette coal field (Flores and others, 1999) and other produced coal in the Gillette coal field (Glass, 2000). The Upper Wyodak, Canyon, and Lower Wyodak/Werner beds are within the Wyodak-Anderson coal zone. Compared with all coal in the Wyodak-Anderson coal zone, both throughout the Powder River Basin and just within the Gillette coal field; the thick, persistent Upper Wyodak coal bed in the Gillette coal field has higher mean gross calorific value (8,569 Btu/lb), lower mean ash yield (5.8 percent), and lower mean total sulfur content (0.46 percent).

A poloidal section neutron camera for MAST upgrade

DOE Office of Scientific and Technical Information (OSTI.GOV)

Sangaroon, S.; Weiszflog, M.; Cecconello, M.

2014-08-21

The Mega Ampere Spherical Tokamak Upgrade (MAST Upgrade) is intended as a demonstration of the physics viability of the Spherical Tokamak (ST) concept and as a platform for contributing to ITER/DEMO physics. Concerning physics exploitation, MAST Upgrade plasma scenarios can contribute to the ITER Tokamak physics particularly in the field of fast particle behavior and current drive studies. At present, MAST is equipped with a prototype neutron camera (NC). On the basis of the experience and results from previous experimental campaigns using the NC, the conceptual design of a neutron camera upgrade (NC Upgrade) is being developed. As part ofmore » the MAST Upgrade, the NC Upgrade is considered a high priority diagnostic since it would allow studies in the field of fast ions and current drive with good temporal and spatial resolution. In this paper, we explore an optional design with the camera array viewing the poloidal section of the plasma from different directions.« less

Correlation chart of Pennsylvanian rocks in Alabama, Tennessee, Kentucky, Virginia, West Virginia, Ohio, Maryland, and Pennsylvania showing approximate position of coal beds, coal zones, and key stratigraphic units: Chapter D.2 in Coal and petroleum resources in the Appalachian basin: distribution, geologic framework, and geochemical character

USGS Publications Warehouse

Ruppert, Leslie F.; Trippi, Michael H.; Slucher, Ernie R.; Ruppert, Leslie F.; Ryder, Robert T.

2014-01-01

Because of the many names used to identify individual coal beds and coal zones in the historic Appalachian basin coal-mining districts, coal bed designations may differ even more than stratigraphic nomenclature. In eastern Kentucky, northwest of the Pine Mountain thrust fault on the Cumberland overthrust sheet, for example, coal beds or coal zones equivalent to the Lower Elkhorn coal zone (within the Pikeville Formation) are identified also as the Eagle coal zone, Pond Creek coal zone, and Blue Gem coal bed (fig. 1). Southeast of the Pine Mountain thrust fault, yet still in Kentucky, equivalent coals in this same interval are known as the Imboden and Rich Mountain. Moreover, this same interval of coal is identified as the Blue Gem coal in Tennessee, the Imboden coal bed or Campbell Creek or Pond Creek coal zones in Virginia, and the Eagle coal zone in West Virginia.

Slum Upgrading and Health Equity.

PubMed

Corburn, Jason; Sverdlik, Alice

2017-03-24

Informal settlement upgrading is widely recognized for enhancing shelter and promoting economic development, yet its potential to improve health equity is usually overlooked. Almost one in seven people on the planet are expected to reside in urban informal settlements, or slums, by 2030. Slum upgrading is the process of delivering place-based environmental and social improvements to the urban poor, including land tenure, housing, infrastructure, employment, health services and political and social inclusion. The processes and products of slum upgrading can address multiple environmental determinants of health. This paper reviewed urban slum upgrading evaluations from cities across Asia, Africa and Latin America and found that few captured the multiple health benefits of upgrading. With the Sustainable Development Goals (SDGs) focused on improving well-being for billions of city-dwellers, slum upgrading should be viewed as a key strategy to promote health, equitable development and reduce climate change vulnerabilities. We conclude with suggestions for how slum upgrading might more explicitly capture its health benefits, such as through the use of health impact assessment (HIA) and adopting an urban health in all policies (HiAP) framework. Urban slum upgrading must be more explicitly designed, implemented and evaluated to capture its multiple global environmental health benefits.

Slum Upgrading and Health Equity

PubMed Central

Corburn, Jason; Sverdlik, Alice

2017-01-01

Informal settlement upgrading is widely recognized for enhancing shelter and promoting economic development, yet its potential to improve health equity is usually overlooked. Almost one in seven people on the planet are expected to reside in urban informal settlements, or slums, by 2030. Slum upgrading is the process of delivering place-based environmental and social improvements to the urban poor, including land tenure, housing, infrastructure, employment, health services and political and social inclusion. The processes and products of slum upgrading can address multiple environmental determinants of health. This paper reviewed urban slum upgrading evaluations from cities across Asia, Africa and Latin America and found that few captured the multiple health benefits of upgrading. With the Sustainable Development Goals (SDGs) focused on improving well-being for billions of city-dwellers, slum upgrading should be viewed as a key strategy to promote health, equitable development and reduce climate change vulnerabilities. We conclude with suggestions for how slum upgrading might more explicitly capture its health benefits, such as through the use of health impact assessment (HIA) and adopting an urban health in all policies (HiAP) framework. Urban slum upgrading must be more explicitly designed, implemented and evaluated to capture its multiple global environmental health benefits. PMID:28338613

Catalytic upgrading of bio-oil produced from hydrothermal liquefaction of Nannochloropsis sp.

PubMed

Shakya, Rajdeep; Adhikari, Sushil; Mahadevan, Ravishankar; Hassan, El Barbary; Dempster, Thomas A

2018-03-01

Upgrading of bio-oil obtained from hydrothermal liquefaction (HTL) of algae is necessary for it to be used as a fuel. In this study, bio-oil obtained from HTL of Nannochloropsis sp. was upgraded using five different catalysts (Ni/C, ZSM-5, Ni/ZSM-5, Ru/C and Pt/C) at 300 °C and 350 °C. The upgraded bio-oil yields were higher at 300 °C; however, higher quality upgraded bio-oils were obtained at 350 °C. Ni/C gave the maximum upgraded bio-oil yield (61 wt%) at 350 °C. However, noble metal catalysts (Ru/C and Pt/C) gave the better upgraded bio-oils in terms of acidity, heating values, and nitrogen values. The higher heating value of the upgraded bio-oils ranged from 40 to 44 MJ/kg, and the nitrogen content decreased from 5.37 to 1.29 wt%. Most of the upgraded bio-oils (35-40 wt%) were in the diesel range. The major components present in the gaseous products were CH 4 , CO, CO 2 and lower alkanes. Copyright © 2017 Elsevier Ltd. All rights reserved.

Bioelectrochemical removal of carbon dioxide (CO2): an innovative method for biogas upgrading.

PubMed

Xu, Heng; Wang, Kaijun; Holmes, Dawn E

2014-12-01

Innovative methods for biogas upgrading based on biological/in-situ concepts have started to arouse considerable interest. Bioelectrochemical removal of CO2 for biogas upgrading was proposed here and demonstrated in both batch and continuous experiments. The in-situ biogas upgrading system seemed to perform better than the ex-situ one, but CO2 content was kept below 10% in both systems. The in-situ system's performance was further enhanced under continuous operation. Hydrogenotrophic methanogenesis and alkali production with CO2 absorption could be major contributors to biogas upgrading. Molecular studies showed that all the biocathodes associated with biogas upgrading were dominated by sequences most similar to the same hydrogenotrophic methanogen species, Methanobacterium petrolearium (97-99% sequence identity). Conclusively, bioelectrochemical removal of CO2 showed great potential for biogas upgrading. Copyright © 2014 Elsevier Ltd. All rights reserved.

Extreme Gleason Upgrading From Biopsy to Radical Prostatectomy: A Population-based Analysis.

PubMed

Winters, Brian R; Wright, Jonathan L; Holt, Sarah K; Lin, Daniel W; Ellis, William J; Dalkin, Bruce L; Schade, George R

2016-10-01

To examine the risk factors associated with the odds of extreme Gleason upgrading at radical prostatectomy (RP) (defined as a Gleason prognostic group score increase of ≥2), we utilized a large, population-based cancer registry. The Surveillance, Epidemiologic, and End Results database was queried (2010-2011) for all patients diagnosed with Gleason 3 + 3 or 3 + 4 on prostate needle biopsy. Available clinicopathologic factors and the odds of upgrading and extreme upgrading at RP were evaluated using multivariate logistic regression. A total of 12,459 patients were identified, with a median age of 61 (interquartile range: 56-65) and a diagnostic prostate-specific antigen (PSA) of 5.5 ng/mL (interquartile range: 4.3-7.5). Upgrading was observed in 34% of men, including 44% of 7402 patients with Gleason 3 + 3 and 19% of 5057 patients with Gleason 3 + 4 disease. Age, clinical stage, diagnostic PSA, and % prostate needle biopsy cores positive were independently associated with odds of any upgrading at RP. In baseline Gleason 3 + 3 disease, extreme upgrading was observed in 6%, with increasing age, diagnostic PSA, and >50% core positivity associated with increased odds. In baseline Gleason 3 + 4 disease, extreme upgrading was observed in 4%, with diagnostic PSA and palpable disease remaining predictive. Positive surgical margins were significantly higher in patients with extreme upgrading at RP (P < .001). Gleason upgrading at RP is common in this large population-based cohort, including extreme upgrading in a clinically significant portion. Copyright © 2016 Elsevier Inc. All rights reserved.

78 FR 28242 - Proposed Information Collection; Cleanup Program for Accumulations of Coal and Float Coal Dusts...

Federal Register 2010, 2011, 2012, 2013, 2014

2013-05-14

... Program for Accumulations of Coal and Float Coal Dusts, Loose Coal, and Other Combustibles AGENCY: Mine... collection for developing and updating a cleanup program for accumulations of coal and float coal dusts, loose coal, and other combustibles in underground coal mines. DATES: All comments must be postmarked or...

Coal systems analysis: A new approach to the understanding of coal formation, coal quality and environmental considerations, and coal as a source rock for hydrocarbons

USGS Publications Warehouse

Warwick, Peter D.

2005-01-01

Coal is an important and required energy source for today's world. Current rates of world coal consumption are projected to continue at approximately the same (or greater) levels well into the twenty-first century. This paper will provide an introduction to the concept of coal systems analysis and the accompanying volume of papers will provide examples of how coal systems analysis can be used to understand, characterize, and evaluate coal and coal gas resources. Coal systems analysis incorporates the various disciplines of coal geology to provide a complete characterization of the resource. The coal system is divided into four stages: (1) accumulation, (2) preservation-burial, (3) diagenesis-coalification, and (4) coal and hydrocarbon resources. These stages are briefly discussed and key references and examples of the application of coal systems analysis are provided.

Instrumentation and control upgrade plan for Browns Ferry nuclear plant

DOE Office of Scientific and Technical Information (OSTI.GOV)

Belew, M.R.; Langley, D.T.; Torok, R.C.

1992-01-01

A comprehensive upgrade of the instrumentation and control (I C) systems at a power plant represents a formidable project for any utility. For a nuclear plant, the extra safety and reliability requirements along with regulatory constraints add further complications and cost. The need for the upgrade must, therefore, be very compelling, and the process must be well planned from the start. This paper describes the steps taken to initiate the I C upgrade process for Tennessee Valley Authority's (TVA's) Browns Ferry 2 nuclear plant. It explains the impetus for the upgrade, the expected benefits, and the process by which systemmore » upgrades will be selected and implemented.« less

Study on the Inference Factors of Huangling Coking Coal Pyrolysis

NASA Astrophysics Data System (ADS)

Du, Meili; Yang, Zongyi; Fan, Jinwen

2018-01-01

In order to reasonably and efficiently utilize Huangling coking coal resource, coal particle, heating rate, holding time, pyrolysis temperature and others factors were dicussed for the influence of those factor on Huangling coking coal pyrolysis products. Several kinds of coal blending for coking experiments were carried out with different kinds of coal such as Huangling coking coal, Xida coal with high ash low sufur, Xinghuo fat coal with hign sulfur, Zhongxingyi coking coal with high sulfur, Hucun lean coal, mixed meager and lean coal. The results shown that the optimal coal particle size distribution was 0.5~1.5mm, the optimal heating rate was 8°C/min, the optimal holding time was 15min, the optimal pyrolysis temperature was 800°C for Huangling coking coal pyrolysis, the tar yield increased from 4.7% to 11.2%. The maximum tar yield of coal blending for coking under the best single factor experiment condition was 10.65% when the proportio of Huangling coking coal was 52%.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Corbett, R.A

Another quality crude oil is available from the North Sea. Norway's Oseberg crude oil entered the export market on Dec. 1, 1988. This premium, low-sulfur crude oil is currently being produced at approximately 240,000 b/d from the Norwegian sector of the North Sea. Two platforms, operated by Den Norske Stats Oijeselskap A.S. (Statoil), are currently in production, with a third scheduled to go into production in 1991. Oseberg is a typical, low-sulfur North Sea crude oil that will provide a full range of high-quality, low-sulfur products. The naphtha cuts are of intermediate to paraffinic quality, making them suitable for gasolinemore » production. The Oseberg crude is stabilized at the offshore platform and then transported to the Sture terminal, north of Bergen, Norway. The terminal can handle crude oil tankers up to 300,000 DWT.« less

DOE Office of Scientific and Technical Information (OSTI.GOV)

Wood, A.

Cyclohexane buyers, hit by a string of US plant closures, are breathing a sigh of relief at signs of an upswing in capacity. Phillips Petroleum has assured the future of a cyclohexane plant at its Guayama, PR site, while Kerr-McGee Chemical has confirmed it will acquire a mothballed 30-million gal/year unit from Unocal and restart it. Phillips deal is connected to an agreement to license Chevron Chemical's Aromax catalytic reforming technology for its Guayama refinery. The technology, which will cut the company's aromatics production costs, secures the future of Phillips petrochemical operations at the site, including the downstream 90-million gal/yearmore » cyclohexane plant. The Chevron process is said to boost yields of benzene, toluene, and xylene above those of conventional reforming processes. It relies on a zeolite catalyst to convert light paraffins into aromatics; conventional reforming converts higher-valued aromatic naphthas.« less

Worldwide surplus of LP-gases to grow, expert tells European meet in Venice

DOE Office of Scientific and Technical Information (OSTI.GOV)

Not Available

1988-07-01

There appears to be a growing consensus among students of the LP-gas industry that (1) the worldwide surplus of supplies of LP-gases will continue and grow, and (2) this will provide ample opportunity for market development between now and the year 2000, but (3) that development will be largely in the field of petro-chemical feedstocks, although (4) if the price should not remain competitive with feedstocks such as naphtha, the surpluses could find their way into the U.S., if (5) the price is right. This viewpoint was set forth for the benefit of the delegates to the convention May 19-20more » of the European LP-Gas Association in Venice, Italy, by Rick Haun, vice president of Purvin and Gertz, the Dallas consulting firm.« less

DOE Office of Scientific and Technical Information (OSTI.GOV)

Tishina, E.A.; Bel'kevich, P.I.; Churshukov, E.S.

This article reports on an investigation of the protective properties of resinous substances that are waste materials in the production of deresined wax. The protective properties of the resins extracted by BR-2 naphtha at 20/sup 0/C, 0/sup 0/C, and 5/sup 0/C, and also the ethanol-soluble and ethanol-insoluble components of these resins are examined. The results indicate that the peat wax resins do not show any corrosivity with respect to copper. At elevated temperatures, the resins are as good as the commercial additive Akor-1 in protective efficiency, and their alcohol-soluble components are better than the Akor-1. It is concluded that themore » good compatibility of the resins with mineral oils and their high level of protection make them suitable for use in liquid preservative formulations for the temporary corrosion protection of metal items.« less

Coal desulfurization by chlorinolysis production and combustion test evaluation of product coals

NASA Technical Reports Server (NTRS)

Kalvinskas, J. J.; Daly, D.

1982-01-01

Laboratory-scale screening tests were carried out on coal from Harrison County, Ohio to establish chlorination and hydrodesulfurization conditions for the batch reactor production of chlorinolysis and chlorinolysis-hydrodesulfurized coals. In addition, three bituminous coals, were treated on the lab scale by the chlorinolysis process to provide 39 to 62% desulfurization. Two bituminous coals and one subbituminous coal were then produced in 11 to 15 pound lots as chlorinolysis and hydrodesulfurized coals. The chlorinolysis coals had a desulfurization of 29-69%, reductions in voltatiles and hydrogen. Hydrodesulfurization provided a much greater desulfurization (56-86%), reductions in volatiles and hydrogen. The three coals were combustion tested in the Penn State ""plane flame furnace'' to determine ignition and burning characteristics. All three coals burned well to completion as: raw coals, chlorinolysis processed coals, and hydrodesulfurized coals. The hydrodesulfurized coals experienced greater ignition delays and reduced burning rates than the other coals because of the reduced volatile content. It is thought that the increased open pore volume in the desulfurized-devolatilized coals compensates in part for the decreased volatiles effect on ignition and burning.

25 CFR 175.40 - Financing of extensions and upgrades.

Code of Federal Regulations, 2010 CFR

2010-04-01

... 25 Indians 1 2010-04-01 2010-04-01 false Financing of extensions and upgrades. 175.40 Section 175.40 Indians BUREAU OF INDIAN AFFAIRS, DEPARTMENT OF THE INTERIOR LAND AND WATER INDIAN ELECTRIC POWER UTILITIES System Extensions and Upgrades § 175.40 Financing of extensions and upgrades. (a) The utility may...

76 FR 23795 - Low-Power Television and Translator Upgrade Program: Notice of Final Closing Date

Federal Register 2010, 2011, 2012, 2013, 2014

2011-04-28

.... 110418247-1247-01] Low-Power Television and Translator Upgrade Program: Notice of Final Closing Date AGENCY... receipt of applications for the Low-Power Television and Translator Upgrade Program (Upgrade Program) will... Rules to Establish Rules for Digital Low Power Television, Television Translator, and Television Booster...

DOE Office of Scientific and Technical Information (OSTI.GOV)

Not Available

The coal industry, the utilities, and the state government are planning for development of high-energy coal gasification in Illinois to convert its abundant high-sulfur coal supply to a substitute natural gas. Following a summary of the findings, the following topics are discussed briefly: Illinois coal and the push for coal gasification; coal gasification: a look at the process; potential sites for an Illinois coal gasification industry; the impact of coal gasification's water requirements; solid wastes from coal gasification; land losses: the impact on agriculture; potential human health problems with coal gasification; the energy efficiency of coal gasification; potential economic impactsmore » of coal gasification; the corporations behind high-energy coal gasification; state involvement: legalizing the losses of the people; the national energy picture: the impact of western coal developments on Illinois; action: what you can do now. 27 references. (MCW)« less

Results of coalbed-methane drilling, Mylan Park, Monongalia County, West Virginia: Chapter G.3 in Coal and petroleum resources in the Appalachian basin: distribution, geologic framework, and geochemical character

USGS Publications Warehouse

Ruppert, Leslie F.; Fedorko, Nick; Warwick, Peter D.; Grady, William C.; Britton, James Q.; Schuller, William A.; Crangle, Robert D.; Ruppert, Leslie F.; Ryder, Robert T.

2014-01-01

High-pressure carbon-dioxide adsorption isotherms were measured on composite coal samples of the Upper Kittanning coal bed and the Middle Kittanning and Clarion coal zones. Assuming that the reservoir pressure in the Mylan Park coals is equivalent to the normal hydrostatic pressure, the estimated maximum carbon-dioxide adsorption pressures range from a low of about 300 pounds per square inch (lb/in2 ) in coals from the Clarion coal zone to 500 lb/in2 for coals from the Upper Kittanning coal bed. The estimated maximum methane adsorption isotherms show that the coals from the Upper Kittanning coal bed and the Middle Kittanning coal zone are undersaturated in methane, but coals from the Clarion coal zone are close to saturation.

Flat Epithelial Atypia: Upgrade Rates and Risk-Stratification Approach to Support Informed Decision Making.

PubMed

Lamb, Leslie R; Bahl, Manisha; Gadd, Michele A; Lehman, Constance D

2017-12-01

Our aim was to determine upgrade rates of pure flat epithelial atypia (FEA) to malignancy and higher-risk lesions and to identify patients with FEA at low risk for upgrade. Medical chart review from 2007 to 2016 identified 208 consecutive patients with pure FEA diagnosed by image-guided core needle biopsy who underwent surgical excision (96.2% [200 of 208]) or had at least 2 years of imaging follow-up (3.8% [8 of 208]). Medical records were reviewed for risk factors and surgical outcomes. Overall upgrade rate of FEA to malignancy was 2.4% (5 of 208). All 5 upgraded cases were ductal carcinoma in situ at operation. The upgrade rate to atypical ductal hyperplasia, lobular carcinoma in situ, or atypical lobular hyperplasia was 29.8% (62 of 208). The FEA lesions in patients with a genetic mutation were more likely to upgrade to malignancy than FEA lesions in patients without a genetic mutation (33.3% [1 of 3] vs 2.0% [4 of 205]; p < 0.01). The FEA lesions in patients with a personal history of breast cancer were more likely to upgrade to higher-risk lesions than those without a personal history (47.8% [11 of 23] vs 27.6% [51 of 185]; p = 0.046) but were not more likely to be upgraded to malignancy (0% [0 of 23] vs 2.7% [5 of 185]; p = 0.42). The overall risk of upgrade of FEA to malignancy is low at 2.4%; however, the upgrade rate to a higher-risk lesion is nearly 30%. Surveillance rather than surgical excision of FEA can be a reasonable option for patients without a genetic mutation who opt against chemoprevention. Copyright © 2017 American College of Surgeons. Published by Elsevier Inc. All rights reserved.

Preliminary investigation on the effects of primary airflow to coal particle distribution in coal-fired boilers

NASA Astrophysics Data System (ADS)

Noor, N. A. W. Mohd; Hassan, H.; Hashim, M. F.; Hasini, H.; Munisamy, K. M.

2017-04-01

This paper presents an investigation on the effects of primary airflow to coal fineness in coal-fired boilers. In coal fired power plant, coal is pulverized in a pulverizer, and it is then transferred to boiler for combustion. Coal need to be ground to its desired size to obtain maximum combustion efficiency. Coarse coal particle size may lead to many performance problems such as formation of clinker. In this study, the effects of primary airflow to coal particles size and coal flow distribution were investigated by using isokinetic coal sampling and computational fluid dynamic (CFD) modelling. Four different primary airflows were tested and the effects to resulting coal fineness were recorded. Results show that the optimum coal fineness distribution is obtained at design primary airflow. Any reduction or increase of air flow rate results in undesirable coal fineness distribution.

DOE Office of Scientific and Technical Information (OSTI.GOV)

NONE

The first part covers standards for gaseous fuels. The standard part covers standards on coal and coke including the classification of coals, determination of major elements in coal ash and trace elements in coal, metallurgical properties of coal and coke, methods of analysis of coal and coke, petrographic analysis of coal and coke, physical characteristics of coal, quality assurance and sampling.

DOE Office of Scientific and Technical Information (OSTI.GOV)

NONE

The first part covers standards for gaseous fuels. The second part covers standards on coal and coke including the classification of coals, determination of major elements in coal ash and trace elements in coal, metallurgical properties of coal and coke, methods of analysis of coal and coke, petrogrpahic analysis of coal and coke, physical characteristics of coal, quality assurance and sampling.

Geochemistry of vanadium (V) in Chinese coals.

PubMed

Liu, Yuan; Liu, Guijian; Qu, Qinyuan; Qi, Cuicui; Sun, Ruoyu; Liu, Houqi

2017-10-01

Vanadium in coals may have potential environmental and economic impacts. However, comprehensive knowledge of the geochemistry of V in coals is lacking. In this study, abundances, distribution and modes of occurrence of V are reviewed by compiling >2900 reported Chinese coal samples. With coal reserves in individual provinces as the weighting factors, V in Chinese coals is estimated to have an average abundance of 35.81 μg/g. Large variation of V concentration is observed in Chinese coals of different regions, coal-forming periods, and maturation ranks. According to the concentration coefficient of V in coals from individual provinces, three regions are divided across Chinese coal deposits. Vanadium in Chinese coals is probably influenced by sediment source and sedimentary environment, supplemented by late-stage hydrothermal fluids. Specifically, hydrothermal fluids have relatively more significant effect on the enrichment of V in local coal seams. Vanadium in coals is commonly associated with aluminosilicate minerals and organic matter, and the modes of V occurrence in coal depend on coal-forming environment and coal rank. The Chinese V emission inventory during coal combustion is estimated to be 4906 mt in 2014, accounting for 50.55 % of global emission. Vanadium emissions by electric power plants are the largest contributor.

Formation and retention of methane in coal

DOE Office of Scientific and Technical Information (OSTI.GOV)

Hucka, V.J.; Bodily, D.M.; Huang, H.

1992-05-15

The formation and retention of methane in coalbeds was studied for ten Utah coal samples, one Colorado coal sample and eight coal samples from the Argonne Premium Coal Sample Bank.Methane gas content of the Utah and Colorado coals varied from zero to 9 cm{sup 3}/g. The Utah coals were all high volatile bituminous coals. The Colorado coal was a gassy medium volatile bituminous coal. The Argonne coals cover a range or rank from lignite to low volatile bituminous coal and were used to determine the effect of rank in laboratory studies. The methane content of six selected Utah coal seamsmore » and the Colorado coal seam was measured in situ using a special sample collection device and a bubble desorbometer. Coal samples were collected at each measurement site for laboratory analysis. The cleat and joint system was evaluated for the coal and surrounding rocks and geological conditions were noted. Permeability measurements were performed on selected samples and all samples were analyzed for proximate and ultimate analysis, petrographic analysis, {sup 13}C NMR dipolar-dephasing spectroscopy, and density analysis. The observed methane adsorption behavior was correlated with the chemical structure and physical properties of the coals.« less

Formation and retention of methane in coal. Final report

DOE Office of Scientific and Technical Information (OSTI.GOV)

Hucka, V.J.; Bodily, D.M.; Huang, H.

1992-05-15

The formation and retention of methane in coalbeds was studied for ten Utah coal samples, one Colorado coal sample and eight coal samples from the Argonne Premium Coal Sample Bank.Methane gas content of the Utah and Colorado coals varied from zero to 9 cm{sup 3}/g. The Utah coals were all high volatile bituminous coals. The Colorado coal was a gassy medium volatile bituminous coal. The Argonne coals cover a range or rank from lignite to low volatile bituminous coal and were used to determine the effect of rank in laboratory studies. The methane content of six selected Utah coal seamsmore » and the Colorado coal seam was measured in situ using a special sample collection device and a bubble desorbometer. Coal samples were collected at each measurement site for laboratory analysis. The cleat and joint system was evaluated for the coal and surrounding rocks and geological conditions were noted. Permeability measurements were performed on selected samples and all samples were analyzed for proximate and ultimate analysis, petrographic analysis, {sup 13}C NMR dipolar-dephasing spectroscopy, and density analysis. The observed methane adsorption behavior was correlated with the chemical structure and physical properties of the coals.« less

Kansas coal distribution, resources, and potential for coalbed methane

USGS Publications Warehouse

Brady, L.L.

2000-01-01

100 ft (>30 m)] determined from 32 different coal beds. Strippable coal resources at a depth Kansas has large amounts of bituminous coal both at the surface and in the subsurface of eastern Kansas. Preliminary studies indicate at least 53 billion tons (48 billion MT) of deep coal [>100 ft (>30 m)] determined from 32 different coal beds. Strippable coal resources at a depth < 100 ft (<30 m) total 2.8 billion tons (2.6 billion MT), and this total is determined from 17 coals. Coal beds present in the Cherokee Group (Middle Pennsylvanian) represent most of these coal resource totals. Deep coal beds with the largest resource totals include the Bevier, Mineral, "Aw" (unnamed coal bed), Riverton, and Weir-Pittsburg coals, all within the Cherokee Group. Based on chemical analyses, coals in the southeastern part of the state are generally high volatile A bituminous, whereas coals in the east-central and northeastern part of the state are high-volatile B bituminous coals. The primary concern of coal beds in Kansas for deep mining or development of coalbed methane is the thin nature [<2 ft (0.6 m)] of most coal beds. Present production of coalbed methane is centered mainly in the southern Wilson/northern Montgomery County area of southeastern Kansas where methane is produced from the Mulky, Weir-Pittsburg, and Riverton coals.

Analysis of Energy Industry Upgrading in Northeast China

NASA Astrophysics Data System (ADS)

Liu, Xiao-jing; Ji, Yu-liang; Guan, Bai-feng; Jing, Xin

2018-02-01

Promoting regional economic growth and realizing the transformation of the mode of economic growth are in industrial upgrading essence The product is a carrier that represents a series of links of production, management and marketing behind the enterprise, and is a comprehensive reflection of the knowledge and ability of a country or region. Based on the industrial spatial structure, this paper visualizes the industrial space in Northeast China from 2005 to 2015, analyzes the comparative advantages of the energy industry in Northeast China, and examines the status quo of the upgrade of the energy industry according to the industrial upgrading status. Based on the industrial spatial structure, Industry intensity in the industrial space, put forward the future direction of the energy industry upgrade and upgrade path.

Comparison of the Eastern and Western Kentucky coal fields (Pennsylvanian), USA-why are coal distribution patterns and sulfur contents so different in these coal fields?

USGS Publications Warehouse

Greb, S.F.; Eble, C.F.; Chesnut, D.R.

2002-01-01

More than 130 Mt of Pennsylvanian coal is produced annually from two coal fields in Kentucky. The Western Kentucky Coal Field occurs in part of the Illinois Basin, an intercratonic basin, and the Eastern Kentucky Coal Field occurs in the Central Appalachian Basin, a foreland basin. The basins are only separated by 140 km, but mined western Kentucky coal beds exhibit significantly higher sulfur values than eastern Kentucky coals. Higher-sulfur coal beds in western Kentucky have generally been inferred to be caused by more marine influences than for eastern Kentucky coals. Comparison of strata in the two coal fields shows that more strata and more coal beds accumulated in the Eastern than Western Kentucky Coal Field in the Early and Middle Pennsylvanian, inferred to represent greater generation of tectonic accommodation in the foreland basin. Eastern Kentucky coal beds exhibit a greater tendency toward splitting and occurring in zones than time-equivalent western Kentucky coal beds, which is also inferred to represent foreland accommodation influences, overprinted by autogenic sedimentation effects. Western Kentucky coal beds exhibit higher sulfur values than their eastern counterparts, but western Kentucky coals occurring in Langsettian through Bolsovian strata can be low in sulfur content. Eastern Kentucky coal beds may increase in sulfur content beneath marine zones, but generally are still lower in sulfur than mined Western Kentucky coal beds, indicating that controls other than purely marine influences must have influenced coal quality. The bulk of production in the Eastern Kentucky Coal Field is from Duckmantian and Bolsovian coal beds, whereas production in the Western Kentucky Coal Field is from Westphalian D coals. Langsettian through Bolsovian paleoclimates in eastern Kentucky were favorable for peat doming, so numerous low-sulfur coals accumulated. These coals tend to occur in zones and are prone to lateral splitting because of foreland tectonic and sedimentation influences. In contrast, Westphalian D coal beds of western Kentucky accumulated during low differential tectonic accommodation, and therefore tend to be widespread and uniform in characteristics, but exhibit higher sulfur values because they accumulated in seasonally drier paleoclimates that were unfavorable for peat doming. Hence, basin analyses indicate that many differences between the mined coals of Kentucky's two coal fields are related to temporal changes in paleoclimate and tectonic accommodation, rather than solely being a function of marine influences. ?? 2002 Elsevier Science B.V. All rights reserved.

Study on test of coal co-firing for 600MW ultra supercritical boiler with four walls tangential burning

NASA Astrophysics Data System (ADS)

Ying, Wu; Yong-lu, Zhong; Guo-mingi, Yin

2018-06-01

On account of nine commonly used coals in a Jiangxi Power Plant,two kinds of coal were selected to be applied in coal co-firing test through industrial analysis,elementary analysis and thermogravimetric analysis of coal.During the coal co-firing test,two load points were selected,three coal mixtures were prepared.Moreover,under each coal blending scheme, the optimal oxygen content was obtained by oxygen varying test. At last,by measuring the boiler efficiency and coal consumption of power supply in different coal co-firing schemes, the recommended coal co-firing scheme was obtained.

Coal burning issues. [Book - monograph

DOE Office of Scientific and Technical Information (OSTI.GOV)

Green, A.E.S.

1980-01-01

The results of the scoping phase of an interdisciplinary assessment of the impact of the increased use of coal are reported in this monograph. Subject areas include: coal availability and coal mining; an energetics analysis of coal quality; coal transportation; coal burning technology; synthetic fuels from coal; technological innovations; water resources; atmospheric pollution; air pollution dispersion modeling; atmospheric modifications; solid waste and trace element impacts; agriculture; health effects of air pollution resulting from coal combustion; quantitative public policy assessments; financing capacity growth and coal conversions in the electric utility industry; coal and the states - a public choice perspective; andmore » federal regulatory and legal aspects.« less

Liquefaction of calcium-containing subbituminous coals and coals of lower rank

DOEpatents

Brunson, Roy J.

1979-01-01

An improved process for the treatment of a calcium-containing subbituminous coal and coals of lower rank to form insoluble, thermally stable calcium salts which remain within the solids portions of the residue on liquefaction of the coal, thereby suppressing the formation of scale, made up largely of calcium carbonate which normally forms within the coal liquefaction reactor (i.e., coal liquefaction zone), e.g., on reactor surfaces, lines, auxiliary equipment and the like. An oxide of sulfur, in liquid phase, is contacted with a coal feed sufficient to impregnate the pores of the coal. The impregnated coal, in particulate form, can thereafter be liquefied in a coal liquefaction reactor (reaction zone) at coal liquefaction conditions without significant formation of scale.

Coal resources, production, and quality in the Eastern kentucky coal field: Perspectives on the future of steam coal production

USGS Publications Warehouse

Hower, J.C.; Hiett, J.K.; Wild, G.D.; Eble, C.F.

1994-01-01

The Eastern Kentucky coal field, along with adjacent portions of Virginia and southern West Virginia, is part of the greatest production concentration of high-heating-value, low-sulfur coal in the United States, accounting for over 27% of the 1993 U.S. production of coal of all ranks. Eastern Kentucky's production is spread among many coal beds but is particularly concentrated in a limited number of highquality coals, notably the Pond Creek coal bed and its correlatives, and the Fire Clay coal bed and its correlatives. Both coals are relatively low ash and low sulfur through the areas of the heaviest concentration of mining activity. We discuss production trends, resources, and the quality of in-place and clean coal for those and other major coals in the region. ?? 1994 Oxford University Press.

Nanometre-sized pores in coal: Variations between coal basins and coal origin

USGS Publications Warehouse

Sakurovs, Richard; Koval, Lukas; Grigore, Mihaela; Sokolava, Anna; Ruppert, Leslie F.; Melnichenko, Yuri B.

2018-01-01

We have used small angle neutron scattering (SANS) to investigate the differences in methane and hexane penetration in pores in bituminous coal samples from the U.S., Canada, South Africa, and China, and maceral concentrates from Australian coals. This work is an extension of previous work that showed consistent differences between the extent of penetration by methane into 10–20 nm size pores in inertinite in bituminous coals from Australia, North America and Poland.In this study we have confirmed that there are differences in the response of inertinite to methane and hexane penetration in coals sourced from different coal basins. Inertinite in Permian Australian coals generally has relatively high numbers of pores in the 2.5–250 nm size range and the pores are highly penetrable by methane and hexane; coals sourced from Western Canada had similar penetrability to these Australian coals. However, the penetrability of methane and hexane into inertinite from the Australian Illawarra Coal Measures (also Permian) is substantially less than that of the other Australian coals; there are about 80% fewer 12 nm pores in Illawarra inertinite compared to the other Australian coals examined. The inertinite in coals sourced from South Africa and China had accessibility intermediate between the Illawarra coals and the other Australian coals.The extent of hexane penetration was 10–20% less than CD4 penetration into the same coal and this difference was most pronounced in the 5–50 nm pore size range. Hexane and methane penetrability into the coals showed similar trends with inertinite content.The observed variations in inertinite porosity between coals from different coal regions and coal basins may explain why previous studies differ in their observations of the relationships between gas sorption behavior, permeability, porosity, and maceral composition. These variations are not simply a demarcation between Northern and Southern Hemisphere coals.

Economic effects of western Federal land-use restrictions on U.S. coal markets

USGS Publications Warehouse

Watson, William Downing; Medlin, A.L.; Krohn, K.K.; Brookshire, D.S.; Bernknopf, R.L.

1991-01-01

Current regulations on land use in the Western United States affect access to surface minable coal resources. This U.S. Geological Survey study analyzes the long-term effects of Federal land-use restrictions on the national cost of meeting future coal demands. The analysis covers 45 years. The U.S. Bureau of Land Management has determined the environmental, aesthetic, and economic values of western Federal coal lands and has set aside certain areas from surface coal mining to protect other valued land uses, including agricultural, environmental, and aesthetic uses. Although there are benefits to preserving natural areas and to developing areas for other land uses, these restrictions produce long-term national and regional costs that have not been estimated previously. The Dynamic Coal Allocation Model integrates coal supply (coal resource tonnage and coal quality by mining cost for 60 coal supply regions) with coal demand (in 243 regions) for the entire United States. The model makes it possible to evaluate the regional economic impacts of coal supply restrictions wherever they might occur in the national coal market. The main factors that the economic methodology considers are (1) coal mining costs, (2) coal transportation costs, (3) coal flue gas desulfurization costs, (4) coal demand, (5) regulations to control sulfur dioxide discharges, and (6) specific reductions in coal availability occurring as a result of land-use restrictions. The modeling system combines these economic factors with coal deposit quantity and quality information--which is derived from the U.S. Geological Survey's National Coal Resources Data System and the U.S. Department of Energy's Demonstrated Reserve Base--to determine a balance between supply and demand so that coal is delivered at minimum cost.

Chemical and mineralogical characterization of highly and less reactive coal from Northern Natal and Venda-Pafuri coalfields in South Africa

NASA Astrophysics Data System (ADS)

Kataka, M. O.; Matiane, A. R.; Odhiambo, B. D. O.

2018-01-01

Spontaneous combustion of coal is a major hazard associated with the coal mining industry over centuries. It also a major cause of underground fires in South African collieries and in opencast operations, spoil heaps and stockpiles. Spontaneous combustion incidents are manifested in all major aspects of coal mining namely, underground mining, surface mining, including during sea-borne transportation, storage and waste disposal. Previous studies indicate that there are various factors (both intrinsic and extrinsic) that influence the spontaneous combustion of coals. This paper characterizes highly reactive coal from the Vryheid coalfields and less reactive coal from at Venda-Pafuri coalfield, to identify and delineate some intrinsic coal parameters that are considered to be most critical in terms of heat 'generation' and relationships between the two coals types by tracing their similarities and differences in their spontaneous combustion parameters. Various tests were carried out to characterize these coals in terms of their intrinsic properties, namely: ultimate, proximate, petrographic analysis and Glasser spontaneous tests. The ultimate and proximate analysis showed that spontaneous coal has high contents of carbon, oxygen, and volatile matter as compared to non-spontaneous coal, making it more susceptible to spontaneous combustion. Non-spontaneous coal has higher ash content than the spontaneous coal. Furthermore, the petrographic analysis showed that spontaneous coal has high total reactivity compared to the non-spontaneous coal. Results from Glasser spontaneous test indicate that spontaneous coal absorbs more oxygen than non-spontaneous coal, which explains why spontaneous coal is more susceptible to spontaneous combustion. High reactive coal has low values of critical self-heating temperature (CSHT), indicating that this coal has potential of spontaneous ignition.

Appalachian coal assessment: Defining the coal systems of the Appalachian basin

USGS Publications Warehouse

Milici, R.C.

2005-01-01

The coal systems concept may be used to organize the geologic data for a relatively large, complex area, such as the Appalachian basin, in order to facilitate coal assessments in the area. The concept is especially valuable in subjective assessments of future coal production, which would require a detailed understanding of the coal geology and coal chemistry of the region. In addition, subjective assessments of future coal production would be enhanced by a geographical information system that contains the geologic and geochemical data commonly prepared for conventional coal assessments. Coal systems are generally defined as one or more coal beds or groups of coal beds that have had the same or similar genetic history from their inception as peat deposits, through their burial, diagenesis, and epigenesis to their ultimate preservation as lignite, bituminous coal, or anthracite. The central and northern parts of the Appalachian basin contain seven coal systems (Coal Systems A-G). These systems may be defined generally on the following criteria: (1) on the primary characteristics of their paleopeat deposits, (2) on the stratigraphic framework of the Paleozoic coal measures, (3) on the relative abundance of coal beds within the major stratigraphic groupings, (4) on the amount of sulfur related to the geologic and climatic conditions under which paleopeat deposits accumulated, and (5) on the rank of the coal (lignite to anthracite). ??2005 Geological Society of America.

Advanced liquefaction using coal swelling and catalyst dispersion techniques. Volume 2, appendices. Final technical report, October 1, 1991--September 30, 1994

DOE Office of Scientific and Technical Information (OSTI.GOV)

Curtis, C.W.; Chander, S.; Gutterman, C.

Liquefaction experiments were undertaken using subbituminous Black Thunder mine coal to observe the effects of aqueous SO{sub 2} coal beneficiation and the introduction of various coal swelling solvents and catalyst precursors. Aqueous SO{sub 2} beneficiation of Black Thunder coal removed alkali metals and alkaline earth metals, increased the sulfur content and increased the catalytic liquefaction conversion to THF solubles compared to untreated Black Thunder coal. The liquefaction solvent had varying effects on coal conversion, depending upon the type of solvent added. The hydrogen donor solvent, dihydroanthracene, was most effective, while a coal-derived Wilsonville solvent promoted more coal conversion than didmore » relatively inert 1-methylnaphthalene. Swelling of coal with hydrogen bonding solvents tetrahydrofuran (THF), isopropanol, and methanol, prior to reaction resulted in increased noncatalytic conversion of both untreated and SO{sub 2} treated Black Thunder coals, while dimethylsulfoxide (DMSO), which was absorbed more into the coal than any other swelling solvent, was detrimental to coal conversion. Swelling of SO{sub 2} treated coal before liquefaction resulted in the highest coal conversions; however, the untreated coal showed the most improvements in catalytic reactions when swelled in either THF, isopropanol, or methanol prior to liquefaction. The aprotic solvent DMSO was detrimental to coal conversion.« less

Development and Application of a Life Cycle-Based Model to Evaluate Greenhouse Gas Emissions of Oil Sands Upgrading Technologies.

PubMed

Pacheco, Diana M; Bergerson, Joule A; Alvarez-Majmutov, Anton; Chen, Jinwen; MacLean, Heather L

2016-12-20

A life cycle-based model, OSTUM (Oil Sands Technologies for Upgrading Model), which evaluates the energy intensity and greenhouse gas (GHG) emissions of current oil sands upgrading technologies, is developed. Upgrading converts oil sands bitumen into high quality synthetic crude oil (SCO), a refinery feedstock. OSTUM's novel attributes include the following: the breadth of technologies and upgrading operations options that can be analyzed, energy intensity and GHG emissions being estimated at the process unit level, it not being dependent on a proprietary process simulator, and use of publicly available data. OSTUM is applied to a hypothetical, but realistic, upgrading operation based on delayed coking, the most common upgrading technology, resulting in emissions of 328 kg CO 2 e/m 3 SCO. The primary contributor to upgrading emissions (45%) is the use of natural gas for hydrogen production through steam methane reforming, followed by the use of natural gas as fuel in the rest of the process units' heaters (39%). OSTUM's results are in agreement with those of a process simulation model developed by CanmetENERGY, other literature, and confidential data of a commercial upgrading operation. For the application of the model, emissions are found to be most sensitive to the amount of natural gas utilized as feedstock by the steam methane reformer. OSTUM is capable of evaluating the impact of different technologies, feedstock qualities, operating conditions, and fuel mixes on upgrading emissions, and its life cycle perspective allows easy incorporation of results into well-to-wheel analyses.

Coal systems analysis

DOE Office of Scientific and Technical Information (OSTI.GOV)

Warwick, P.D.

This collection of papers provides an introduction to the concept of coal systems analysis and contains examples of how coal systems analysis can be used to understand, characterize, and evaluate coal and coal gas resources. Chapter are: Coal systems analysis: A new approach to the understanding of coal formation, coal quality and environmental considerations, and coal as a source rock for hydrocarbons by Peter D. Warwick. Appalachian coal assessment: Defining the coal systems of the Appalachian Basin by Robert C. Milici. Subtle structural influences on coal thickness and distribution: Examples from the Lower Broas-Stockton coal (Middle Pennsylvanian), Eastern Kentucky Coalmore » Field, USA by Stephen F. Greb, Cortland F. Eble, and J.C. Hower. Palynology in coal systems analysis The key to floras, climate, and stratigraphy of coal-forming environments by Douglas J. Nichols. A comparison of late Paleocene and late Eocene lignite depositional systems using palynology, upper Wilcox and upper Jackson Groups, east-central Texas by Jennifer M.K. O'Keefe, Recep H. Sancay, Anne L. Raymond, and Thomas E. Yancey. New insights on the hydrocarbon system of the Fruitland Formation coal beds, northern San Juan Basin, Colorado and New Mexico, USA by W.C. Riese, William L. Pelzmann, and Glen T. Snyder.« less

Relationship between Maceral of Coal and Coal-bed Methane adsorption ability in Sihe Coalmine of Qinshui Basin, China

NASA Astrophysics Data System (ADS)

Wang, M. S.; Zou, G. G.; Zhu, R. B.

2018-05-01

Maceral components and its content of coal were divided based on the microscopic characteristics of coal. The Langmuir volume and the Langmuir pressure were tested, and the Langmuir volume represents the adsorption capacity of coal. The formation of coal bed methane is affected by the partition of the maceral components in coal. Therefore, the relationship between maceral composition and coal bed methane adsorption capacity of coal was analyzed. The results show that the maceral components of coal are dominated by vitrinite and inertinite in the study area, and the content of inertinite is below 32%. The vitrinite group has a negative linear correlation with the Langmuir volume, and the inertia composition has a positive linear correlation with it. The cellular structures in the inertinite are the main site of coal bed methane enrichment. The microstructure of coal affects the coalbed methane content and the stage of hydrocarbon generation in coal. This indicates that the microstructure of coal is one of the important factors influencing the adsorption capacity of coal seam.

Turbidity changes during culvert to bridge upgrades at Carmen Creek, Idaho

Treesearch

Randy B. Foltz; Breann Westfall; Ben Kopyscianski

2012-01-01

Carmen Creek, a tributary to the Salmon River in Idaho, was the site of two culvert to bridge upgrade operations in September and October 2011. Both locations were upgraded from multiple, large diameter culverts to bridge crossings. Turbidity readings measured at the end of the mixing zone during the nearly three weeks of upgrade construction activities did not exceed...

Upgrading the Space Shuttle Caution and Warning System

NASA Technical Reports Server (NTRS)

McCandless, Jeffrey W.; McCann, Robert S.; Hilty, Bruce T.

2005-01-01

A report describes the history and the continuing evolution of an avionic system aboard the space shuttle, denoted the caution and warning system, that generates visual and auditory displays to alert astronauts to malfunctions. The report focuses mainly on planned human-factors-oriented upgrades of an alphanumeric fault-summary display generated by the system. Such upgrades are needed because the display often becomes cluttered with extraneous messages that contribute to the difficulty of diagnosing malfunctions. In the first of two planned upgrades, the fault-summary display will be rebuilt with a more logical task-oriented graphical layout and multiple text fields for malfunction messages. In the second upgrade, information displayed will be changed, such that text fields will indicate only the sources (that is, root causes) of malfunctions; messages that are not operationally useful will no longer appear on the displays. These and other aspects of the upgrades are based on extensive collaboration among astronauts, engineers, and human-factors scientists. The report describes the human-factors principles applied in the upgrades.

EMR Database Upgrade from MUMPS to CACHE: Lessons Learned.

PubMed

Alotaibi, Abduallah; Emshary, Mshary; Househ, Mowafa

2014-01-01

Over the past few years, Saudi hospitals have been implementing and upgrading Electronic Medical Record Systems (EMRs) to ensure secure data transfer and exchange between EMRs.This paper focuses on the process and lessons learned in upgrading the MUMPS database to a the newer Caché database to ensure the integrity of electronic data transfer within a local Saudi hospital. This paper examines the steps taken by the departments concerned, their action plans and how the change process was managed. Results show that user satisfaction was achieved after the upgrade was completed. The system was stable and offered better healthcare quality to patients as a result of the data exchange. Hardware infrastructure upgrades improved scalability and software upgrades to Caché improved stability. The overall performance was enhanced and new functions were added (CPOE) during the upgrades. The essons learned were: 1) Involve higher management; 2) Research multiple solutions available in the market; 3) Plan for a variety of implementation scenarios.

Assessment of coal geology, resources, and reserves in the northern Wyoming Powder River Basin

USGS Publications Warehouse

Scott, David C.; Haacke, Jon E.; Osmonson, Lee M.; Luppens, James A.; Pierce, Paul E.; Rohrbacher, Timothy J.

2010-01-01

The abundance of new borehole data from recent coal bed natural gas development in the Powder River Basin was utilized by the U.S. Geological Survey for the most comprehensive evaluation to date of coal resources and reserves in the Northern Wyoming Powder River Basin assessment area. It is the second area within the Powder River Basin to be assessed as part of a regional coal assessment program; the first was an evaluation of coal resources and reserves in the Gillette coal field, adjacent to and south of the Northern Wyoming Powder River Basin assessment area. There are no active coal mines in the Northern Wyoming Powder River Basin assessment area at present. However, more than 100 million short tons of coal were produced from the Sheridan coal field between the years 1887 and 2000, which represents most of the coal production within the northwestern part of the Northern Wyoming Powder River Basin assessment area. A total of 33 coal beds were identified during the present study, 24 of which were modeled and evaluated to determine in-place coal resources. Given current technology, economic factors, and restrictions to mining, seven of the beds were evaluated for potential reserves. The restrictions included railroads, a Federal interstate highway, urban areas, and alluvial valley floors. Other restrictions, such as depth, thickness of coal beds, mined-out areas, and areas of burned coal, were also considered. The total original coal resource in the Northern Wyoming Powder River Basin assessment area for all 24 coal beds assessed, with no restrictions applied, was calculated to be 285 billion short tons. Available coal resources, which are part of the original coal resource that is accessible for potential mine development after subtracting all restrictions, are about 263 billion short tons (92.3 percent of the original coal resource). Recoverable coal, which is that portion of available coal remaining after subtracting mining and processing losses, was determined for seven coal beds with a stripping ratio of 10:1 or less. After mining and processing losses were subtracted, a total of 50 billion short tons of recoverable coal was calculated. Coal reserves are the portion of the recoverable coal that can be mined, processed, and marketed at a profit at the time of the economic evaluation. With a discounted cash flow at 8 percent rate of return, the coal reserves estimate for the Northern Wyoming Powder River Basin assessment area is 1.5 billion short tons of coal (1 percent of the original resource total) for the seven coal beds evaluated.

Study on the coal mixing ratio optimization for a power plant

NASA Astrophysics Data System (ADS)

Jin, Y. A.; Cheng, J. W.; Bai, Q.; Li, W. B.

2017-12-01

For coal-fired power plants, the application of blended coal combustion has been a great issue due to the shortage and rising prices of high-rank coal. This paper describes the optimization of blending methods between Xing'an lignite coal, Shaltala lignite coal, Ura lignite coal, and Inner Mongolia bituminous coal. The multi-objective decision-making method based on fuzzy mathematics was used to determine the optimal blending ratio to improve the power plant coal-fired economy.

Assessment of Coal Geology, Resources, and Reserves in the Gillette Coalfield, Powder River Basin, Wyoming

USGS Publications Warehouse

Luppens, James A.; Scott, David C.; Haacke, Jon E.; Osmonson, Lee M.; Rohrbacher, Timothy J.; Ellis, Margaret S.

2008-01-01

The Gillette coalfield, within the Powder River Basin in east-central Wyoming, is the most prolific coalfield in the United States. In 2006, production from the coalfield totaled over 431 million short tons of coal, which represented over 37 percent of the Nation's total yearly production. The Anderson and Canyon coal beds in the Gillette coalfield contain some of the largest deposits of low-sulfur subbituminous coal in the world. By utilizing the abundance of new data from recent coalbed methane development in the Powder River Basin, this study represents the most comprehensive evaluation of coal resources and reserves in the Gillette coalfield to date. Eleven coal beds were evaluated to determine the in-place coal resources. Six of the eleven coal beds were evaluated for reserve potential given current technology, economic factors, and restrictions to mining. These restrictions included the presence of railroads, a Federal interstate highway, cities, a gas plant, and alluvial valley floors. Other restrictions, such as thickness of overburden, thickness of coal beds, and areas of burned coal were also considered. The total original coal resource in the Gillette coalfield for all eleven coal beds assessed, and no restrictions applied, was calculated to be 201 billion short tons. Available coal resources, which are part of the original coal resource that is accessible for potential mine development after subtracting all restrictions, are about 164 billion short tons (81 percent of the original coal resource). Recoverable coal, which is the portion of available coal remaining after subtracting mining and processing losses, was determined for a stripping ratio of 10:1 or less. After mining and processing losses were subtracted, a total of 77 billion short tons of coal were calculated (48 percent of the original coal resource). Coal reserves are the portion of the recoverable coal that can be mined, processed, and marketed at a profit at the time of the economic evaluation. With a discounted cash flow at 8 percent rate of return, the coal reserves estimate for the Gillette coalfield is10.1 billion short tons of coal (6 percent of the original resource total) for the 6 coal beds evaluated.

Effect of Water Invasion on Outburst Predictive Index of Low Rank Coals in Dalong Mine

PubMed Central

Jiang, Jingyu; Cheng, Yuanping; Mou, Junhui; Jin, Kan; Cui, Jie

2015-01-01

To improve the coal permeability and outburst prevention, coal seam water injection and a series of outburst prevention measures were tested in outburst coal mines. These methods have become important technologies used for coal and gas outburst prevention and control by increasing the external moisture of coal or decreasing the stress of coal seam and changing the coal pore structure and gas desorption speed. In addition, techniques have had a significant impact on the gas extraction and outburst prevention indicators of coal seams. Globally, low rank coals reservoirs account for nearly half of hidden coal reserves and the most obvious feature of low rank coal is the high natural moisture content. Moisture will restrain the gas desorption and will affect the gas extraction and accuracy of the outburst prediction of coals. To study the influence of injected water on methane desorption dynamic characteristics and the outburst predictive index of coal, coal samples were collected from the Dalong Mine. The methane adsorption/desorption test was conducted on coal samples under conditions of different injected water contents. Selective analysis assessed the variations of the gas desorption quantities and the outburst prediction index (coal cutting desorption index). Adsorption tests indicated that the Langmuir volume of the Dalong coal sample is ~40.26 m3/t, indicating a strong gas adsorption ability. With the increase of injected water content, the gas desorption amount of the coal samples decreased under the same pressure and temperature. Higher moisture content lowered the accumulation desorption quantity after 120 minutes. The gas desorption volumes and moisture content conformed to a logarithmic relationship. After moisture correction, we obtained the long-flame coal outburst prediction (cutting desorption) index critical value. This value can provide a theoretical basis for outburst prediction and prevention of low rank coal mines and similar occurrence conditions of coal seams. PMID:26161959

The effect of coal bed dewatering and partial oxidation on biogenic methane potential

USGS Publications Warehouse

Jones, Elizabeth J.P.; Harris, Steve H.; Barnhart, Elliott P.; Orem, William H.; Clark, Arthur C.; Corum, Margo D.; Kirshtein, Julie D.; Varonka, Matthew S.; Voytek, Mary A.

2013-01-01

Coal formation dewatering at a site in the Powder River Basin was associated with enhanced potential for secondary biogenic methane determined by using a bioassay. We hypothesized that dewatering can stimulate microbial activity and increase the bioavailability of coal. We analyzed one dewatered and two water-saturated coals to examine possible ways in which dewatering influences coal bed natural gas biogenesis by looking at differences with respect to the native coal microbial community, coal-methane organic intermediates, and residual coal oxidation potential. Microbial biomass did not increase in response to dewatering. Small Subunit rRNA sequences retrieved from all coals sampled represented members from genera known to be aerobic, anaerobic and facultatively anaerobic. A Bray Curtis similarity analysis indicated that the microbial communities in water-saturated coals were more similar to each other than to the dewatered coal, suggesting an effect of dewatering. There was a higher incidence of long chain and volatile fatty acid intermediates in incubations of the dewatered coal compared to the water-saturated coals, and this could either be due to differences in microbial enzymatic activities or to chemical oxidation of the coal associated with O2 exposure. Dilute H2O2 treatment of two fractions of structural coal (kerogen and bitumen + kerogen) was used as a proxy for chemical oxidation by O2. The dewatered coal had a low residual oxidation potential compared to the water-saturated coals. Oxidation with 5% H2O2 did increase the bioavailability of structural coal, and the increase in residual oxidation potential in the water saturated coals was approximately equivalent to the higher methanogenic potential measured in the dewatered coal. Evidence from this study supports the idea that coal bed dewatering could stimulate biogenic methanogenesis through partial oxidation of the structural organics in coal once anaerobic conditions are restored.

Uncertainty in coal property valuation in West Virginia: A case study

USGS Publications Warehouse

Hohn, M.E.; McDowell, R.R.

2001-01-01

Interpolated grids of coal bed thickness are being considered for use in a proposed method for taxation of coal in the state of West Virginia (United States). To assess the origin and magnitude of possible inaccuracies in calculated coal tonnage, we used conditional simulation to generate equiprobable realizations of net coal thickness for two coals on a 7 1/2 min topographic quadrangle, and a third coal in a second quadrangle. Coals differed in average thickness and proportion of original coal that had been removed by erosion; all three coals crop out in the study area. Coal tonnage was calculated for each realization and for each interpolated grid for actual and artificial property parcels, and differences were summarized as graphs of percent difference between tonnage calculated from the grid and average tonnage from simulations. Coal in individual parcels was considered minable for valuation purposes if average thickness in each parcel exceeded 30 inches. Results of this study show that over 75% of the parcels are classified correctly as minable or unminable based on interpolation grids of coal bed thickness. Although between 80 and 90% of the tonnages differ by less than 20% between interpolated values and simulated values, a nonlinear conditional bias might exist in estimation of coal tonnage from interpolated thickness, such that tonnage is underestimated where coal is thin, and overestimated where coal is thick. The largest percent differences occur for parcels that are small in area, although because of the small quantities of coal in question, bias is small on an absolute scale for these parcels. For a given parcel size, maximum apparent overestimation of coal tonnage occurs in parcels with an average coal bed thickness near the minable cutoff of 30 in. Conditional bias in tonnage for parcels having a coal thickness exceeding the cutoff by 10 in. or more is constant for two of the three coals studied, and increases slightly with average thickness for the third coal. ?? 2001 International Association for Mathematical Geology.

Floatabilities of treated coal in water at room temperature

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kwon, K.C.; Rohrer, R.L.; Lai, R.W.

1995-04-01

Experiments on equilibrium adsorption loadings of various probe compounds on 60-200 mesh Illinois No. 6 coal (PSOC-1539), Adaville No. 1 coal (PSOC-1544), Wyodak coal (PSOC-1545), and Pittsburgh No. 8 coal (PSOC-1549) were performed. The probe compounds include 2-methyl-1-pentanol (2M1P), 1-heptanol, benzene, and toluene. Equilibrium adsorption loadings of aromatic compounds such as toluene and benzene on the four chosen coals obey the Langmuir isotherm model up to 100 ppm in concentrations of probe compounds. Equilibrium adsorption loadings of higher aliphatic alcohols such as 2M1P and 1-heptanol on the four chosen coals do not follow both the Langmuir isotherm model and themore » Freundlich empirical adsorption model. Flotation of the coals, equilibrated with aqueous solutions of 2M1P and 1-heptanol, increases linearly with equilibrium adsorption loadings of these probe compounds on the coals. The chosen coals were treated with nitrogen and air at 1 atm and 125-225{degrees}C for 24 h. Flotation experiments of the treated coals were conducted at room temperature, using distilled water only as a flotation medium. Flotation of Adaville No. 1 coal and Wyodak coal treated with nitrogen gas is higher than that of the untreated coals and increases with treatment temperatures. Flotation of Adaville No. 1 coal treated with air at 125-225{degrees}C is not significantly different from that of untreated coal. Flotation of Pittsburgh No. 8 coal treated with air is lower than that of untreated coal and decreases with treatment temperatures. Flotation of Illinois No. 6 coal treated with nitrogen with nitrogen only is higher than that of untreated coal. Flotation of Illinois No. 6 coal treated with nitrogen at 125-175{degrees}C increases with treatment temperatures, whereas flotation of Illinois No. 6 coal treated with nitrogen at 174-225{degrees}C decreases with treatment temperatures.« less

Block coals from Indiana: Inferences on changing depositional environment

USGS Publications Warehouse

Mastalerz, Maria; Padgett, P.L.; Eble, C.F.

2000-01-01

Significant differences in coal petrography, palynology and coal quality were found between the Lower Block and Upper Block Coal Members (Brazil Formation, Pennsylvanian) in Daviess County, Indiana. The Lower Block Coal Member ranges in thickness from 51 to 74 cm and the Upper Block Coal Member ranges from 20 to 65 cm. Average sulfur content and ash yield of the Lower Block coal (0.98%, 7.65%) are lower than in the Upper Block coal. Megascopically, the coals show distinct differences. The Lower Block is a banded coal with numerous thin fusain horizons and a thin clay parting in the lower third of the seam. The Upper Block coal has a dulling-upward trend, with a bright clarain found at the base that grades into a clarain and then into a durain in the upper portion of the seam. Vitrinite content of the Lower Block coal ranges from 63% to 78%, with the highest vitrinite content found in the middle portion of the seam. In the Upper Block coal, vitrinite content ranges from 40% to 83%, with the highest values found in the lower part of the seam. Ash yield is higher in the upper part of the Upper Block coal, reaching up to 40%. The Lower Block coal is dominated by lycopod trees and tree ferns. The Upper Block coal shows marked differences in spore assemblages between lower and upper parts of the seam. The lower half is dominated by large lycopod trees and tree ferns, similar to the Lower Block coal. The upper half is dominated by small lycopods, mainly Densosporites and Radiizonates. These differences between the Lower Block and Upper Block Coal Members are significant correlation tools applicable to mining exploration and chronostratigraphy. (C) 2000 Elsevier Science B.V. All rights reserved.Significant differences in coal petrography, palynology and coal quality were found between the Lower Block and Upper Block Coal Members (Brazil Formation, Pennsylvanian) in Daviess County, Indiana. The Lower Block Coal Member ranges in thickness from 51 to 74 cm and the Upper Block Coal Member ranges from 20 to 65 cm. Average sulfur content and ash yield of the Lower Block coal (0.98%, 7.65%) are lower than in the Upper Block coal. Megascopically, the coals show distinct differences. The Lower Block is a banded coal with numerous thin fusain horizons and a thin clay parting in the lower third of the seam. The Upper Block coal has a dulling-upward trend, with a bright clarain found at the base that grades into a clarain and then into a durain in the upper portion of the seam. Vitrinite content of the Lower Block coal ranges from 63% to 78%, with the highest vitrinite content found in the middle portion of the seam. In the Upper Block coal, vitrinite content ranges from 40% to 83%, with the highest values found in the lower part of the seam. Ash yield is higher in the upper part of the Upper Block coal, reaching up to 40%. The Lower Block coal is dominated by lycopod trees and tree ferns. The Upper Block coal shows marked differences in spore assemblages between lower and upper parts of the seam. The lower half is dominated by large lycopod trees and tree ferns, similar to the Lower Block coal. The upper half is dominated by small lycopods, mainly Densosporites and Radiizonates. These differences between the Lower Block and Upper Block Coal members are significant correlation tools applicable to mining exploration and chronostratigraphy.

Integration of MOOCs in Advanced Mining Training Programmes

NASA Astrophysics Data System (ADS)

Saveleva, Irina; Greenwald, Oksana; Kolomiets, Svetlana; Medvedeva, Elena

2017-11-01

The paper covers the concept of innovative approaches in education based on incorporating MOOCs options into traditional classroom. It takes a look at the ways higher education instructors working with the mining engineers enrolled in advanced training programmes can brighten, upgrade and facilitate the learning process. The shift of higher education from in-class to online format has changed the learning environment and the methods of teaching including professional retraining courses. In addition, the need of mining companies for managers of a new kind obligates high school retraining centres rapidly move towards the 21st century skill framework. One of widely recognized innovations in the sphere of e-learning is MOOCs (Massive Open Online Courses) that can be used as an effective teaching tool for organizing professional training of managing staff of mining companies within the walls of a university. The authors share their instructional experience and show the benefits of introducing MOOCs options at the courses designed for retraining mining engineers and senior managers of coal enterprises. Though in recent researches the pedagogical value of MOOCs is highly questioned and even negated this invention of the 21st century can become an essential and truly helpful instrument in the hands of educators.

American power conference: Proceedings

DOE Office of Scientific and Technical Information (OSTI.GOV)

Not Available

1994-01-01

The first volume of this conference contains papers on the following topics: (1) Controls, monitoring, and expert systems (Harnessing microprocessor revolution for a more competitive power industry; Plant control--Upgrades; Neural network applications); (2) Diversification and globalization (Electric utility diversification/globalization--Panel; Private power in developing countries); (3) Environment and clean air (Clean Air compliance costs; Site selection for power stations and related facilities; Electric utility trace substance emissions; Solid waste disposal and commercial use; Precipitators/fabric filters; and Effect of flow modifications on fisheries and water quality); (4) Generation--Fuel options equipment (Alternate fuels; Advances in fuel cells for electric power applications; Secondary containmentmore » and seismic requirements for petrochemical facilities; Clean coal technology demonstration; Advanced energy systems; Hydropower); (5) Nuclear operations options (Radioactive waste management and disposal; Off normal conditions; Advanced light water reactors--15 years after TMI; Structural dynamic analyses for nuclear power plants); (6) Retrofit, betterment, repowering maintenance (Project management; Improving competitiveness through process re-engineering; Central stations; Water and wastewater treatment); (7) System planning, operation demand maintenance (Transmission system access; Stability; Systems planning); (8) Transmission and distribution (Transformers; Relaying for system protection; Managing EMF effects); and (9) Education (Power engineering). 155 papers have been processed separately for inclusion on the data base.« less

Performance analysis of CO(2) emissions and energy efficiency of metal industries in China.

PubMed

Shao, Chaofeng; Guan, Yang; Wan, Zheng; Chu, Chunli; Ju, Meiting

2014-02-15

Nonferrous metal industries play an important role in China's national economy and are some of the country's largest energy consumers. To better understand the nature of CO(2) emissions from these industries and to further move towards low-carbon development in this industry sector, this study investigates the CO(2) emissions of 12 nonferrous metal industries from 2003 to 2010 based on their life-cycle assessments. It then classifies these industries into four "emission-efficiency" types through cluster analysis. The results show that (1) the industrial economy and energy consumption of China's nonferrous metal industries have grown rapidly, although their recent energy consumption rate shows a declining trend. (2) The copper, aluminum, zinc, lead, and magnesium industries, classified as high-emission industries, are the main contributors of CO(2) emissions. The results have implications for policy decisions that aim to enhance energy efficiency, particularly for promoting the transformation of low-efficiency industries to high-efficiency ones. The study also highlights the important role of policy development in technological innovations, optimization, and upgrades, the reduction of coal proportion in energy consumption, and the advancement of new energy sources. Copyright © 2014 Elsevier Ltd. All rights reserved.

Sustainable hybrid photocatalysts: titania immobilized on ...

EPA Pesticide Factsheets

This review comprises the preparation, properties and heterogeneous photocatalytic applications of TiO2 immobilized on carbon materials derived from earth-abundant, renewable and biodegradable agricultural residues and sea food waste resources. The overview provides key scientific insights into widely used TiO2 supported on carbonaceous materials emanating from biopolymeric materials such as lignin, cellulose, cellulose acetate, bacterial cellulose, bamboo, wood, starch, chitosan and agricultural residues (biochar, charcoal, activated carbon and their magnetic forms, coal fly ash) or seafood wastes namely eggshell, clamshell and fish scales; materials that serve as a support/template for TiO2. Heightened awareness and future inspirational developments for the valorisation of various forms of carbonaceous functional materials is the main objective. This appraisal abridges various strategies available to upgrade renewable carbon-based feedstock via the generation of sustainable TiO2/carbon functional materials and provides remarks on their future prospects. Hopefully, this will stimulate the development of efficient and novel composite photocatalysts and engender the necessary knowledge base for further advancements in greener photocatalytic technologies. Prepared as a Critical Review for the Royal Society of Chemistry (RSC) journal, Green Chemistry. This review discusses the sustainable use of earth-abundant materials exemplified by Titanium dioxide and carbon.

Method for reducing NOx during combustion of coal in a burner

DOEpatents

Zhou, Bing [Cranbury, NJ; Parasher, Sukesh [Lawrenceville, NJ; Hare, Jeffrey J [Provo, UT; Harding, N Stanley [North Salt Lake, UT; Black, Stephanie E [Sandy, UT; Johnson, Kenneth R [Highland, UT

2008-04-15

An organically complexed nanocatalyst composition is applied to or mixed with coal prior to or upon introducing the coal into a coal burner in order to catalyze the removal of coal nitrogen from the coal and its conversion into nitrogen gas prior to combustion of the coal. This process leads to reduced NOx production during coal combustion. The nanocatalyst compositions include a nanoparticle catalyst that is made using a dispersing agent that can bond with the catalyst atoms. The dispersing agent forms stable, dispersed, nano-sized catalyst particles. The catalyst composition can be formed as a stable suspension to facilitate storage, transportation and application of the catalyst nanoparticles to a coal material. The catalyst composition can be applied before or after pulverizing the coal material or it may be injected directly into the coal burner together with pulverized coal.

Royal Society, Discussion on New Coal Chemistry, London, England, May 21, 22, 1980, Proceedings

NASA Astrophysics Data System (ADS)

1981-03-01

A discussion of new coal chemistry is presented. The chemical and physical structure of coal is examined in the first section, including structural studies of coal extracts, metal and metal complexes in coal and coal microporosity. The second section presents new advances in applied coal technology. The development of liquid fuels and chemicals from coal is given especial emphasis, with papers on the Sasol Synthol process, the Shell-Koppers gasification process, liquefaction and gasification in Germany, the Solvent Refined Coal process, the Exxon Donor Solvent liquefaction process and the Mobil Methanol-to-Gasoline process. Finally, some developments that will be part of the future of coal chemistry in the year 2000 are examined in the third section, including coal-based chemical complexes and the use of coal as an alternative source to oil for chemical feedstocks.

Graphene quantum dots, graphene oxide, carbon quantum dots and graphite nanocrystals in coals

NASA Astrophysics Data System (ADS)

Dong, Yongqiang; Lin, Jianpeng; Chen, Yingmei; Fu, Fengfu; Chi, Yuwu; Chen, Guonan

2014-06-01

Six coal samples of different ranks have been used to prepare single-layer graphene quantum dots (S-GQDs). After chemical oxidation and a series of centrifugation separation, every coal could be treated into two fractions, namely, CoalA and CoalB. According to the characterization results of TEM, AFM, XRD, Raman and FTIR, CoalA was revealed to be mainly composed of S-GQDs, which have an average height of about 0.5 nm and an average plane dimension of about 10 nm. The obtained S-GQDs showed excitation-dependent fluorescence and excellent electrochemiluminescence. CoalB was found to be some other carbon-based nanomaterials (CNMs), including agglomerated GQDs, graphene oxide, carbon quantum dots and agglomerated carbon nanocrystals. Generally, low-ranked coals might be more suitable for the preparation of S-GQDs. The production yield of S-GQDs from the six investigated coals decreased from 56.30% to 14.66% when the coal rank increased gradually. In contrast, high-ranked coals had high production yield of CoalB and might be more suitable for preparing other CNMs that were contained in CoalB, although those CNMs were difficult to separate from each other in our experiment.Six coal samples of different ranks have been used to prepare single-layer graphene quantum dots (S-GQDs). After chemical oxidation and a series of centrifugation separation, every coal could be treated into two fractions, namely, CoalA and CoalB. According to the characterization results of TEM, AFM, XRD, Raman and FTIR, CoalA was revealed to be mainly composed of S-GQDs, which have an average height of about 0.5 nm and an average plane dimension of about 10 nm. The obtained S-GQDs showed excitation-dependent fluorescence and excellent electrochemiluminescence. CoalB was found to be some other carbon-based nanomaterials (CNMs), including agglomerated GQDs, graphene oxide, carbon quantum dots and agglomerated carbon nanocrystals. Generally, low-ranked coals might be more suitable for the preparation of S-GQDs. The production yield of S-GQDs from the six investigated coals decreased from 56.30% to 14.66% when the coal rank increased gradually. In contrast, high-ranked coals had high production yield of CoalB and might be more suitable for preparing other CNMs that were contained in CoalB, although those CNMs were difficult to separate from each other in our experiment. Electronic supplementary information (ESI) available: Elemental analysis results of coal samples, FTIR spectra of CoalA and CoalB, ECL responses of CoalA/S2O82-. See DOI: 10.1039/c4nr01482k

A geochemical investigation into the effect of coal rank on the potential environmental effects of CO2 sequestration in deep coal beds

USGS Publications Warehouse

Kolak, Jonathan J.; Burruss, Robert A.

2005-01-01

Coal samples of different rank were extracted in the laboratory with supercritical CO2 to evaluate the potential for mobilizing hydrocarbons during CO2 sequestration or enhanced coal bed methane recovery from deep coal beds. The concentrations of aliphatic hydrocarbons mobilized from the subbituminous C, high-volatile C bituminous, and anthracite coal samples were 41.2, 43.1, and 3.11 ?g g-1 dry coal, respectively. Substantial, but lower, concentrations of polycyclic aromatic hydrocarbons (PAHs) were mobilized from these samples: 2.19, 10.1, and 1.44 ?g g-1 dry coal, respectively. The hydrocarbon distributions within the aliphatic and aromatic fractions obtained from each coal sample also varied with coal rank and reflected changes to the coal matrix associated with increasing degree of coalification. Bitumen present within the coal matrix may affect hydrocarbon partitioning between coal and supercritical CO2. The coal samples continued to yield hydrocarbons during consecutive extractions with supercritical CO2. The amount of hydrocarbons mobilized declined with each successive extraction, and the relative proportion of higher molecular weight hydrocarbons increased during successive extractions. These results demonstrate that the potential for mobilizing hydrocarbons from coal beds, and the effect of coal rank on this process, are important to consider when evaluating coal beds for CO2 storage.

13. Coal ejectors mounted on aft bulkhead of coal bunker. ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

13. Coal ejectors mounted on aft bulkhead of coal bunker. Ejectors were used to flush overboard live coals and clinkers from firebed (pipe for carrying coals overboard has been removed from ejector in foreground). Coal doors from bunker appear beside ejector in foreground). Coal doors from bunker appear beside ejectors at deck; note firing shovels in background against hull. - Steamboat TICONDEROGA, Shelburne Museum Route 7, Shelburne, Chittenden County, VT

Clean coal initiatives in Indiana

USGS Publications Warehouse

Bowen, B.H.; Irwin, M.W.; Sparrow, F.T.; Mastalerz, Maria; Yu, Z.; Kramer, R.A.

2007-01-01

Purpose - Indiana is listed among the top ten coal states in the USA and annually mines about 35 million short tons (million tons) of coal from the vast reserves of the US Midwest Illinois Coal Basin. The implementation and commercialization of clean coal technologies is important to the economy of the state and has a significant role in the state's energy plan for increasing the use of the state's natural resources. Coal is a substantial Indiana energy resource and also has stable and relatively low costs, compared with the increasing costs of other major fuels. This indigenous energy source enables the promotion of energy independence. The purpose of this paper is to outline the significance of clean coal projects for achieving this objective. Design/methodology/approach - The paper outlines the clean coal initiatives being taken in Indiana and the research carried out at the Indiana Center for Coal Technology Research. Findings - Clean coal power generation and coal for transportation fuels (coal-to-liquids - CTL) are two major topics being investigated in Indiana. Coking coal, data compilation of the bituminous coal qualities within the Indiana coal beds, reducing dependence on coal imports, and provision of an emissions free environment are important topics to state legislators. Originality/value - Lessons learnt from these projects will be of value to other states and countries.

[Coal fineness effect on primary particulate matter features during pulverized coal combustion].

PubMed

Lü, Jian-yi; Li, Ding-kai

2007-09-01

Three kinds of coal differed from fineness were burned in a laboratory-scale drop tube furnace for combustion test, and an 8-stage Andersen particle impactor was employed for sampling the primary particulate matter (PM), in order to study coal fineness effect on primary PM features during pulverized coal combustion. It has been shown that the finer the coal was, the finer the PM produced. PM, emission amount augmented with coal fineness decreased, and the amount of PM10 increased from 13 mg/g to 21 mg/g respectively generated by coarse coal and fine coal. The amount of PM2.5 increased from 2 mg/g to 8 mg/g at the same condition. Constituents and content in bulk ash varied little after three different fineness coal combustion, while the appearance of grading PM differed visibly. The value of R(EE) increased while the coal fineness deceased. The volatility of trace elements which were investigated was Pb > Cr > Zn > Cu > Ni in turn. The concentration of poisonous trace elements was higher which generated from fine coal combustion. The volatilization capacity was influenced little by coal fineness, but the volatilization extent was influenced differently by coal fineness. Fine coal combustion affects worse environment than coarse coal does.

An evaluation of upgraded boron fibers in epoxy-matrix composites

NASA Technical Reports Server (NTRS)

Rhodes, T. C.; Fleck, J. N.; Meiners, K. E.

1973-01-01

An initial evaluation of upgraded boron fibers in an epoxy matrix is performed. Data generated on the program show that fiber strength does increase as a consequence of the upgrading treatment. However, the interlaninar shear strength of upgraded fiber composites is lower than that for an untreated fiber composite. In the limited tests performed, the increased fiber strength failed to translate into the composite.

The Republic of the Philippines coalbed methane assessment: based on seventeen high pressure methane adsorption isotherms

USGS Publications Warehouse

Flores, Romeo M.; Stricker, Gary D.; Papasin, Ramon F.; Pendon, Ronaldo R.; del Rosario, Rogelio A.; Malapitan, Ruel T.; Pastor, Michael S.; Altomea, Elmer A.; Cuaresma, Federico; Malapitan, Armando S.; Mortos, Benjamin R.; Tilos, Elizabeth N.

2006-01-01

Introduction: The Republic of the Philippines has some 19 coal districts that contain coal deposits ranging from Eocene to Pleistocene in age. These coal districts include: (1) Catanduanes (Eocene); (2) Cebu, Zamboanga Sibuguey, Bukidnon, Maguindanao, Sarangani, and Surigao (Oligocene to Miocene); (3) Batan Island, Masbate, Semirara (including Mindoro), and Quezon-Polilio (lower-upper Miocene); (4) Davao, Negros, and Sorsogon (middle-upper Miocene); (5) Cotabato (lower Miocene-lower Pliocene), Cagayan-Isabella, and Quirino (upper Miocene-Pliocene); (6) Sultan Kudarat (upper Miocene-Pleistocene); and (7) Samar-Leyte (lower Pliocene-Pleistocene). In general, coal rank is directly related to the age of the deposits - for example, the Eocene coal is semi-anthracite and the Pliocene-Pleistocene coal is lignite. Total coal resources in these 19 coal districts, which are compiled by the Geothermal and Coal Resources Development Division (GCRDD) of the Department of Energy of the Philippines, are estimated at a minimum of 2,268.4 million metric tonnes (MMT) (approximately 2.3 billion metric tones). The largest resource (550 MMT) is the subbituminous coal in the Semirara (including Mindoro) coal district, and the smallest (0.7 MMT) is the lignite-subbituminous coal in the Quirino coal district. The combined lignite and subbituminous coal resources, using the classification by GCRDD and including Semirara and Surigao coal districts, are about 1,899.2 MMT, which make up about 84 percent of the total coal resources of the Philippines. The remaining resources are composed of bituminous and semi-anthracite coal. The subbituminous coal of Semirara Island in the Mindoro- Semirara coal district (fig. 2) is known to contain coalbed methane (CBM), with the coal being comparable in gas content and adsorption isotherms to the coal of the Paleocene Fort Union Formation in the Powder River Basin in Wyoming, USA (Flores and others, 2005). As a consequence, the presence of CBM in the Semirara coal led to the present study of determining the adsorption isotherms, or gas (CBM) holding or storage capacity, of coal beds of various ages from selected coal districts in the Philippines. Samples for the study were collected from the Batan Island, Catanduanes, Cagayan-Isabella, Cebu, Negros, Samar, Semirara, Cotabato, Surigao, and Malangas coalfield of the Zamboanga Sibuguey coal districts by five field geology teams from the GCRDD.

Experiment Needs and Facilities Study Appendix A Transient Reactor Test Facility (TREAT) Upgrade

DOE Office of Scientific and Technical Information (OSTI.GOV)

None

The TREAT Upgrade effort is designed to provide significant new capabilities to satisfy experiment requirements associated with key LMFBR Safety Issues. The upgrade consists of reactor-core modifications to supply the physics performance needed for the new experiments, an Advanced TREAT loop with size and thermal-hydraulics capabilities needed for the experiments, associated interface equipment for loop operations and handling, and facility modifications necessary to accommodate operations with the Loop. The costs and schedules of the tasks to be accomplished under the TREAT Upgrade project are summarized. Cost, including contingency, is about 10 million dollars (1976 dollars). A schedule for execution ofmore » 36 months has been established to provide the new capabilities in order to provide timely support of the LMFBR national effort. A key requirement for the facility modifications is that the reactor availability will not be interrupted for more than 12 weeks during the upgrade. The Advanced TREAT loop is the prototype for the STF small-bundle package loop. Modified TREAT fuel elements contain segments of graphite-matrix fuel with graded uranium loadings similar to those of STF. In addition, the TREAT upgrade provides for use of STF-like stainless steel-UO{sub 2} TREAT fuel for tests of fully enriched fuel bundles. This report will introduce the Upgrade study by presenting a brief description of the scope, performance capability, safety considerations, cost schedule, and development requirements. This work is followed by a "Design Description". Because greatly upgraded loop performance is central to the upgrade, a description is given of Advanced TREAT loop requirements prior to description of the loop concept. Performance requirements of the upgraded reactor system are given. An extensive discussion of the reactor physics calculations performed for the Upgrade concept study is provided. Adequate physics performance is essential for performance of experiments with the Advanced TREAT loop, and the stress placed on these calculations reflects this. Additional material on performance and safety is provided. Backup calculations on calculations of plutonium-release limits are described. Cost and schedule information for the Upgrade are presented.« less

Coal-fired power generaion, new air quality regulations, and future U.S. coal production

USGS Publications Warehouse

Attanasi, E.D.; Root, D.H.

1999-01-01

Tighter new regulation of stack gas emissions and competition in power generation are driving electrical utilities to demand cleaner, lower sulfur coal. Historical data on sulfur content of produced coals shows little variability in coal quality for individual mines and individual coal-producing counties over relatively long periods of time. If coal-using power generators follow the compliance patterns established in Phase I of the 1990 Clean Air Act Amendments, then the industry's response to the tighter Phase II emissions standards will result in large amounts of coal production shifting from higher sulfur areas to areas with lower cost low sulfur coal. One reason this shift will likely occur is that currently only 30% of U.S. coal-fired electrical generating capacity is equipped with flue-gas scrubbers. In 1995, coal mines in the higher sulfur areas of the Illinois Basin and Northern and Central Appalachia employed 78% of all coal miners (>70,000 miners). A substantial geographical redistribution of the nation's coal supplies will likely lead to economic dislocations that will reach beyond local coal-producing areas.

Methane Content Estimation in DuongHuy Coal Mine

NASA Astrophysics Data System (ADS)

Nguyen, Van Thinh; Mijał, Waldemar; Dang, Vu Chi; Nguyen, Thi Tuyet Mai

2018-03-01

Methane hazard has always been considered for underground coal mining as it can lead to methane explosion. In Quang Ninh province, several coal mines such as Mạo Khe coal mine, Khe Cham coal mine, especially Duong Huy mine that have high methane content. Experimental data to examine contents of methane bearing coal seams at different depths are not similar in Duong coal mine. In order to ensure safety, this report has been undertaken to determine a pattern of changing methane contents of coal seams at different exploitation depths in Duong Huy underground coal mine.

Should we excise? Are there any clinical or histologic features that predict upgrade in papillomas, incidental or non-incidental?

PubMed

Zaleski, Michael; Chen, Yun An; Chetlen, Alison L; Mack, Julie; Xu, Liyan; Dodge, Daleela G; Karamchandani, Dipti M

2018-05-11

The clinical decision to excise intraductal papilloma (IDP) without atypia diagnosed on biopsy remains controversial. We sought to establish clinical and histologic predictors (if any) which may predict upgrade in IDP. 296 biopsies (in 278 women) with histologic diagnosis of IDP without atypia were retrospectively identified and placed into Incidental (no corresponding imaging correlate), or Non-incidental (positive imaging correlate) groups. 253/296 (85.5%) cases were non-incidental, and 43/296 (14.5%) were incidental. 73.1% (185/253) non-incidental and 48.8% (21/43) incidental cases underwent excision. 12.4% (23/185) non-incidental cases underwent an upgrade to cancer or high-risk lesion; namely 8-Ductal carcinoma in situ (DCIS), 8-atypical ductal hyperplasia (ADH), 6-lobular neoplasia, and 1-flat epithelial atypia. There was no histopathologic feature on the biopsy in the non-incidental group which predicted upgrade; however a past history of atypia was significantly associated with upgrade. 2 of the 21 incidental cases upgraded (1 to ADH and 1 to lobular neoplasia); the former had a past history of ADH. Both incidental upgrades were >1 mm in size, and were not completely excised on the biopsy. None of the incidental cases which appeared completely excised on biopsy upgraded, irrespective of the size on biopsy. These findings suggest that all non-incidental IDPs should be considered candidates for surgical excision, given the 12.4% upgrade rate and no definitive histologic predictors of upgrade. Patients with incidental IDPs (if <1 mm, completely excised on biopsy and with no history of high risk breast lesion) can be spared excision. Copyright © 2018 Elsevier Inc. All rights reserved.

U.S. Geological Survey coal quality (COALQUAL) database; version 2.0

USGS Publications Warehouse

Bragg, L.J.; Oman, J.K.; Tewalt, S.J.; Oman, C.L.; Rega, N.H.; Washington, P.M.; Finkelman, R.B.

1997-01-01

The USGS Coal Quality database is an interactive, computerized component of the NCRDS. It contains comprehensive analyses of more than 13,000 samples of coal and associated rocks from every major coal-bearing basin and coal bed in the U.S. The data in the coal quality database represent analyses of the coal as it exists in the ground. The data commonly are presented on an as-received whole-coal basis.

Process for preparing a stabilized coal-water slurry

DOEpatents

Givens, E.N.; Kang, D.

1987-06-23

A process is described for preparing a stabilized coal particle suspension which includes the steps of providing an aqueous media substantially free of coal oxidizing constituents, reducing, in a nonoxidizing atmosphere, the particle size of the coal to be suspended to a size sufficiently small to permit suspension thereof in the aqueous media and admixing the coal of reduced particle size with the aqueous media to release into the aqueous media coal stabilizing constituents indigenous to and carried by the reduced coal particles in order to form a stabilized coal particle suspension. The coal stabilizing constituents are effective in a nonoxidizing atmosphere to maintain the coal particle suspension at essentially a neutral or alkaline pH. The coal is ground in a nonoxidizing atmosphere such as an inert gaseous atmosphere to reduce the coal to a sufficient particle size and is admixed with an aqueous media that has been purged of oxygen and acid-forming gases. 2 figs.

Process for preparing a stabilized coal-water slurry

DOEpatents

Givens, Edwin N.; Kang, Doohee

1987-01-01

A process for preparing a stabilized coal particle suspension which includes the steps of providing an aqueous media substantially free of coal oxidizing constituents, reducing, in a nonoxidizing atmosphere, the particle size of the coal to be suspended to a size sufficiently small to permit suspension thereof in the aqueous media and admixing the coal of reduced particle size with the aqueous media to release into the aqueous media coal stabilizing constituents indigenous to and carried by the reduced coal particles in order to form a stabilized coal particle suspension. The coal stabilizing constituents are effective in a nonoxidizing atmosphere to maintain the coal particle suspension at essentially a neutral or alkaline pH. The coal is ground in a nonoxidizing atmosphere such as an inert gaseous atmosphere to reduce the coal to a sufficient particle size and is admixed with an aqueous media that has been purged of oxygen and acid-forming gases.

Trace elements in coal. Environmental and health significance

USGS Publications Warehouse

Finkelman, R.B.

1999-01-01

Trace elements can have profound adverse effects on the health of people burning coal in homes or living near coal deposits, coal mines, and coal- burning power plants. Trace elements such as arsenic emitted from coal- burning power plants in Europe and Asia have been shown to cause severe health problems. Perhaps the most widespread health problems are caused by domestic coal combustion in developing countries where millions of people suffer from fluorosis and thousands from arsenism. Better knowledge of coal quality characteristics may help to reduce some of these health problems. For example, information on concentrations and distributions of potentially toxic elements in coal may help delineate areas of a coal deposit to be avoided. Information on the modes of occurrence of these elements and the textural relations of the minerals in coal may help to predict the behavior of the potentially toxic trace metals during coal cleaning, combustion, weathering, and leaching.

Mössbauer study of the inorganic sulfur removal from coals

NASA Astrophysics Data System (ADS)

Reyes Caballero, F.; Martínez Ovalle, S. A.

2014-01-01

Mössbauer Spectroscopy (MS) was applied to study the occurrence and behavior of the iron-sulfur-containing minerals in coal and coal fractions obtained by different separation methods: hydrocyclonic, flotation and chemical removal process. Samples of one high sulfur coal from Guachinte mine (Valle, Colombia) and three low sulfur coals from the El Salitre zone (Paipa-Boyacá, Colombia) were analyzed. MS evidenced only the presence of pyrite in Esmeralda and Las Casitas coals, while it identified pyrite and siderite on Cerezo coal. MS and SEM- EDX confirm the inorganic sulfur removal on Guachinte coal submitted to hydrocyclonic removal process. MS of the precipitated coal fraction from Las Casitas mine obtained by flotation in water showed the presence of ferrous sulfate because of coal-weathering process. Treatment with hot diluted HNO3 equal to 27 acid on raw coal sample from Las Casitas mine showed that almost all of the pyrite in raw coal was removed.

Geological and geochemical characteristics of high arsenic coals from endemic arsenosis areas in southwestern Guizhou Province, China

USGS Publications Warehouse

Ding, Z.; Zheng, B.; Long, J.; Belkin, H.E.; Finkelman, R.B.; Chen, C.; Zhou, D.; Zhou, Y.

2001-01-01

Southwest Guizhou Province is one of the most important areas of disseminated, sediment-hosted-type Au deposits in China and is an important area of coal production. The chemistry of most of the coals in SW Guizhou is similar to those in other parts of China. Their As content is near the Chinese coal average, but some local, small coal mines contain high As coals. The highest As content is up to 3.5 wt.% in the coal. The use of high As coals has caused in excess of 3000 cases of As poisoning in several villages. The high As coals are in the Longtan formation, which is an alternating marine facies and terrestrial facies. The coals are distributed on both sides of faults that parallel the regional anticlinal axis. The As content of coal is higher closer to the fault plane. The As content of coal changes greatly in different coal beds and different locations of the same bed. Geological structures such as anticlines, faults and sedimentary strata control the distribution of high As coals. Small Au deposits as well as Sb, Hg, and Th mineralization, are found near the high As coals. Although some As-bearing minerals such as pyrite, arsenopyrite, realgar (?), As-bearing sulfate, As-bearing clays, and phosphate are found in the high As coals, their contents cannot account for the abundance of As in some coals. Analysis of the coal indicates that As mainly exists in the form of As5+ and As3+, perhaps, combined with organic compounds. The occurrence of such exceptionally high As contents in coal and the fact that the As is dominantly organically associated are unique observations. ?? 201 Elsevier Science Ltd.

Application studies of RFID technology in the process of coal logistics transport

NASA Astrophysics Data System (ADS)

Qiao, Bingqin; Chang, Xiaoming; Hao, Meiyan; Kong, Dejin

2012-04-01

For quality control problems in coal transport, RFID technology has been proposed to be applied to coal transportation process. The whole process RFID traceability system from coal production to consumption has been designed and coal supply chain logistics tracking system integration platform has been built, to form the coal supply chain traceability and transport tracking system and providing more and more transparent tracking and monitoring of coal quality information for consumers of coal. Currently direct transport and combined transport are the main forms of coal transportation in China. The means of transport are cars, trains and ships. In the booming networking environment of RFID technology, the RFID technology will be applied to coal logistics and provide opportunity for the coal transportation tracking in the process transportation.

Chemical composition and some trace element contents in coals and coal ash from Tamnava-Zapadno Polje Coal Field, Serbia

DOE Office of Scientific and Technical Information (OSTI.GOV)

Vukasinovic-Pesic, V.; Rajakovic, L.J.

2009-07-01

The chemical compositions and trace element contents (Zn, Cu, Co, Cr, Ni, Pb, Cd, As, B, Hg, Sr, Se, Be, Ba, Mn, Th, V, U) in coal and coal ash samples from Tamnava-Zapadno Polje coal field in Serbia were studied. The coal from this field belongs to lignite. This high volatility coal has high moisture and low S contents, moderate ash yield, and high calorific value. The coal ash is abundant in alumosilicates. Many trace elements such as Ni > Cd > Cr > B > As > Cu > Co > Pb > V > Zn > Mn inmore » the coal and Ni > Cr > As > B > Cu > Co = Pb > V > Zn > Mn in the coal ash are enriched in comparison with Clarke concentrations.« less

43 CFR 3436.1-2 - Federal coal deposits subject to lease by exchange.

Code of Federal Regulations, 2014 CFR

2014-10-01

... 43 Public Lands: Interior 2 2014-10-01 2014-10-01 false Federal coal deposits subject to lease by... Coal Lease and Coal Land Exchanges: Alluvial Valley Floors § 3436.1-2 Federal coal deposits subject to... Federal coal deposits determined to be acceptable for further consideration for coal leasing pursuant to...

Development of coal-feeding systems at the Morgantown Energy Research Center

NASA Technical Reports Server (NTRS)

Hobday, J. M.

1977-01-01

Systems for feeding crushed and pulverized coal into coal conversion reactor vessels are described. Pneumatic methods for feeding pulverized coal, slurry feeders, and coal pumps, methods for steam pickup, and a method for drying a water-coal slurry in a steam fluidized bed subsequent to feeding the coal into a reactor vessel are included.

Method of extracting coal from a coal refuse pile

DOEpatents

Yavorsky, Paul M.

1991-01-01

A method of extracting coal from a coal refuse pile comprises soaking the coal refuse pile with an aqueous alkali solution and distributing an oxygen-containing gas throughout the coal refuse pile for a time period sufficient to effect oxidation of coal contained in the coal refuse pile. The method further comprises leaching the coal refuse pile with an aqueous alkali solution to solubilize and extract the oxidized coal as alkali salts of humic acids and collecting the resulting solution containing the alkali salts of humic acids. Calcium hydroxide may be added to the solution of alkali salts of humic acid to form precipitated humates useable as a low-ash, low-sulfur solid fuel.

Cytotoxicity and genotoxicity induced by coal and coal fly ash particles samples in V79 cells.

PubMed

León-Mejía, Grethel; Silva, Luis F O; Civeira, Matheus S; Oliveira, Marcos L S; Machado, Miriana; Villela, Izabel Vianna; Hartmann, Andreas; Premoli, Suziane; Corrêa, Dione Silva; Da Silva, Juliana; Henriques, João Antônio Pêgas

2016-12-01

Exposure to coal and coal ashes can cause harmful effects in in vitro and in vivo systems, mainly by the induction of oxidative damage. The aim of this work was to assess cytotoxic and genotoxic effects using the V79 cell line treated with coal and coal fly ash particles derived from a coal power plant located in Santa Catarina, Brazil. Two coal samples (COAL11 and COAL16) and two coal fly ash samples (CFA11 and CFA16) were included in this study. COAL16 was co-firing with a mixture of fuel oil and diesel oil. The comet assay data showed that exposure of V79 cells to coal and coal fly ash particles induced primary DNA lesions. Application of lesion-specific endonucleases (FPG and ENDO III) demonstrated increased DNA effects indicating the presence of high amounts of oxidative DNA lesions. The cytokinesis-block micronucleus cytome assay analysis showed that exposure of V79 cells to high concentrations of coal and coal fly ash particles induced cytotoxic effects (apoptosis and necrosis) and chromosomal instability (nucleoplasmic bridges, nuclear buds, and micronucleus (MN) formation). These results may be associated with compounds contained in the surface of the particles as hazardous elements, ultrafine/nanoparticles, and polycyclic aromatic hydrocarbons (PAHs) which were detected in the samples. Graphical abstract ᅟ.

Flash pyrolysis of coal, coal maceral, and coal-derived pyrite with on-line characterization of volatile sulfur compounds

USGS Publications Warehouse

Chou, I.-Ming; Lake, M.A.; Griffin, R.A.

1988-01-01

A Pyroprobe flash pyrolysis-gas chromatograph equipped with a flame photometric detector was used to study volatile sulfur compounds produced during the thermal decomposition of Illinois coal, coal macerals and coal-derived pyrite. Maximum evolution of volatile organic sulfur compounds from all coal samples occurred at a temperature of approximately 700??C. At this temperature, the evolution of thiophene, its alkyl isomers, and short-chain dialkyl sulfide compounds relative to the evolution of benzothiophene and dibenzothiophene compounds was greater from coal high in organic sulfur than from coal low in organic sulfur. The variation in the evolution of sulfur compounds observed for three separate coal macerals (exinite, vitrinite, and inertinite) was similar to that observed for whole coal samples. However, the variation trend for the macerals was much more pronounced. Decomposition of coal-derived pyrite with the evolution of elemental sulfur was detected at a temperature greater than 700??C. The results of this study indicated that the gas chromotographic profile of the volatile sulfur compounds produced during flash pyrolysis of coals and coal macerals varied as a function of the amount of organic sulfur that occurred in the samples. Characterization of these volatile sulfur compounds provides a better understanding of the behavior of sulfur in coal during the thermolysis process, which could be incorporated in the design for coal cleaning using flash pyrolysis techniques. ?? 1988.

H-1 Upgrades (4BW/4BN) (H-1 Upgrades)

DTIC Science & Technology

2015-12-01

automatic blade fold of the new composite rotor blades, new performance matched transmissions, a new four-bladed tail rotor and drive system, upgraded...Upgrades December 2015 SAR March 18, 2016 10:59:17 UNCLASSIFIED 4 Col Steven Girard PMA-276 USMC Light/Attack Helicopter Program Executive Officer...attack helicopter is to provide rotary wing close air support, anti-armor, armed escort, armed/visual reconnaissance and fire support coordination

Occurrence and mobility of toxic elements in coals from endemic fluorosis areas in the Three Gorges Region, SW China.

PubMed

Xiong, Yan; Xiao, Tangfu; Liu, Yizhang; Zhu, Jianming; Ning, Zengping; Xiao, Qingxiang

2017-10-01

Fluorine (F) is a topic of great interest in coal-combustion related endemic fluorosis areas. However, little extent research exists regarding the environmental geochemistry of toxic elements that are enriched in coals and coal wastes in traditional endemic fluorosis areas, particularly focusing on their occurrences and mobilities during the weathering-leaching processes of coals and coal wastes in the surface environment. This paper addressed the issue of toxic elements in coals and coal wastes in the Three Gorges Region, Southwest (SW) China, where endemic fluorosis has historically prevailed, and investigated the distribution, occurrence, mobility features, and associated potential health risks. For this purpose, a modified experiment combined with long-term humidity cell test and column leaching trial was applied to elucidate the mobility of toxic elements in coals and coal wastes. In addition, sequential chemical extraction (SCE) was used to ascertain the modes of occurrence of toxic elements. The results demonstrated that the contents of toxic elements in the study area followed the order: stone coals > gangues > coal balls > coals. Furthermore, modes of occurrence of toxic elements were obviously different in coals and coal wastes. For example, cadmium (Cd) was mainly associated with monosulfide fraction in coals, molybdenum (Mo) and arsenic (As) were mainly associated with carbonate and silicate in coal gangues and stone coals, chromium (Cr) mainly existed in silicate and insoluble matter in coal gangues and coal balls, thallium (Tl) mainly occurred in organic matter in stone coals and sulfide in coals, and the occurrence of antimony (Sb) varied with different kinds of samples. Moreover, a large amount of toxic elements released to the leachates during the weathering and leaching process, which might pollute the environment and threaten human health. Based on the geo-accumulation index (I geo ), single factor index (P i ) and Nemerow index (P N ), soils i n the study area were mainly polluted by Cd, which constituted a potential risk to locally planted crops. Copyright © 2017 Elsevier Inc. All rights reserved.

Phyto-bioconversion of hard coal in the Cynodon dactylon/coal rhizosphere.

PubMed

Igbinigie, Eric E; Mutambanengwe, Cecil C Z; Rose, Peter D

2010-03-01

Fundamental processes involved in the microbial degradation of coal and its derivatives have been well documented. A mutualistic interaction between plant roots and certain microorganisms to aid growth of plants such as Cynodon dactylon (Bermuda grass) on hard coal dumps has recently been suggested. In the present study coal bioconversion activity of nonmycorrhizal fungi was investigated in the C. dactylon/coal rhizosphere. Fungal growth on 2% Duff-agar, gutation formation on nitric acid treated coal and submerged culture activity in nitrogen-rich and -deficient broth formed part of the screening and selection of the fungi. The selected fungal isolates were confirmed to be found in pristine C. dactylon/coal rhizosphere. To simulate bioconversion, a fungal aliquot of this rhizosphere was used as inoculum for a Perfusate fixed bed bioreactor, packed with coal. The results demonstrate an enhanced coal bioconversion facilitated by low molecular weight organics and the bioconversion of coal may be initiated by an introduction of nitrogen moieties to the coal substrate. These findings suggest a phyto-bioconversion of hard coal involving plant and microbes occurring in the rhizosphere to promote the growth of C. dactylon. An understanding of this relationship can serve as a benchmark for coal dumps rehabilitation as well as for the industrial scale bioprocessing of hard coal.

Coal-Quality Information - Key to the Efficient and Environmentally Sound Use of Coal

USGS Publications Warehouse

Finkleman, Robert B.

1997-01-01

The rock that we refer to as coal is derived principally from decomposed organic matter (plants) consisting primarily of the element carbon. When coal is burned, it produces energy in the form of heat, which is used to power machines such as steam engines or to drive turbines that produce electricity. Almost 60 percent of the electricity produced in the United States is derived from coal combustion. Coal is an extraordinarily complex material. In addition to organic matter, coal contains water (up to 40 or more percent by weight for some lignitic coals), oils, gases (such as methane), waxes (used to make shoe polish), and perhaps most importantly, inorganic matter (fig. 1). The inorganic matter--minerals and trace elements--cause many of the health, environmental, and technological problems attributed to coal use (fig. 2). 'Coal quality' is the term used to refer to the properties and characteristics of coal that influence its behavior and use. Among the coal-quality characteristics that will be important for future coal use are the concentrations, distribution, and forms of the many elements contained in the coal that we intend to burn. Knowledge of these quality characteristics in U.S. coal deposits may allow us to use this essential energy resource more efficiently and effectively and with less undesirable environmental impact.

Upgraded demonstration vehicle task report

NASA Technical Reports Server (NTRS)

Bryant, J.; Hardy, K.; Livingston, R.; Sandberg, J.

1981-01-01

Vehicle/battery performance capabilities and interface problems that occurred when upgraded developmental batteries were integrated with upgraded versions of comercially available electric vehicles were investigated. Developmental batteries used included nickel zinc batteries, a nickel iron battery, and an improved lead acid battery. Testing of the electric vehicles and upgraded batteries was performed in the complete vehicle system environment to characterize performance and identify problems unique to the vehicle/battery system. Constant speed tests and driving schedule range tests were performed on a chassis dynamometer. The results from these tests of the upgraded batteries and vehicles were compared to performance capabilities for the same vehicles equipped with standard batteries.

Influence of high-energy impact on the physical and technical characteristics of coal fuels

NASA Astrophysics Data System (ADS)

Mal'tsev, L. I.; Belogurova, T. P.; Kravchenko, I. V.

2017-08-01

Currently, in the world's large-scale coal-fired power industry, the combustion of pulverized coal is the most widely spread technology of combusting the coals. In recent years, the micropulverization technology for preparation and combustion of the coal has been developed in this field. As applied to the small-scale power industry, the method of combusting the coal in the form of a coal-water slurry has been explored for years. Fine coal powders are produced and used in the pulverized-coal gasification. Therefore, the coal preparation methods that involve high-dispersion disintegration of coals attract the greatest interest. The article deals with the problems of high-energy impact on the coal during the preparation of pulverized-coal fuels and coal-water slurries, in particular, during the milling of the coal in ball drum mills and the subsequent regrinding in disintegrators or the cavitation treatment of the coal-water slurries. The investigations were conducted using samples of anthracite and lignite from Belovskii open-pit mine (Kuznetsk Basin). It is shown that both the disintegration and the cavitation treatment are efficient methods for controlling the fuel characteristics. Both methods allow increasing the degree of dispersion of the coal. The content of the small-sized particles reground by cavitation considerably exceeds the similar figure obtained using the disintegrator. The specific surface area of the coal is increased by both cavitation and disintegration with the cavitation treatment producing a considerably greater effect. Being subjected to the cavitation treatment, most coal particles assume the form of a split characterized by the thermodynamically nonequilibrium state. Under external action, in particular, of temperature, the morphological structure of such pulverized materials changes faster and, consequently, the combustion of the treated coal should occur more efficiently. The obtained results are explained from the physical point of view.

Coal pump development phase 3

NASA Technical Reports Server (NTRS)

Kushida, R. O.; Sankur, V. D.; Gerbracht, F. G.; Mahajan, V.

1980-01-01

Techniques for achieving continuous coal sprays were studied. Coazial injection with gas and pressure atomization were studied. Coal particles, upon cooling, were found to be porous and fragile. Reactivity tests on the extruded coal showed overall conversion to gases and liquids unchanged from that of the raw coal. The potentials for applications of the coal pump to eight coal conversion processes were examined.

Fuel Gas Demonstration Plant Program: Small-Scale Industrial Project. Coal procurement activities. Technica report No. 9

DOE Office of Scientific and Technical Information (OSTI.GOV)

Not Available

1979-04-14

This report consists of reference material taken from Erie Mining Company project files and includes the following: (1) Investigation of the Main Coal Producing Fields in the United States: This report identifies potential coal fiels for gasifier feedstock and factors influencing coal selection. The report analyzes coal fields located in five separate regions of the United States. Three design coals are discussed and lab reports have been included. Also included are cost considerations for selected coals and preliminary cost data and transportation routing. (2) Analysis of Test Coals Received at Erie Mining Company: Rosebud, Clarion, and Clarion-Brookfield-Kittaning coal samples weremore » received and analyzed at Erie Mining Company. The screen analysis indicated the severe decrepitation of the Rosebud western coal. (3) Criteria for Gasifier Coal: In this study, BCI states that gasifier feed should have the following characteristics: (1) the ratio between the upper and lower size for coal should be 3:1; (2) coal fines should not exceed 10%; (3) coal grading limits which can be handled are maximum range 3'' x 1'', minimum range - 1 1/2'' x 1/2''.« less

Abundances of polycyclic aromatic hydrocarbons (PAHs) in 14 chinese and american coals and their relation to coal rank and weathering

USGS Publications Warehouse

Wang, R.; Liu, Gaisheng; Zhang, Jiahua; Chou, C.-L.; Liu, J.

2010-01-01

The abundances of 16 polycyclic aromatic hydrocarbons (PAHs) on the priority list of the United States Environmental Protection Agency (U.S. EPA) have been determined in 14 Chinese and American coals. The ranks of the samples range from lignite, bituminous coal, anthracite, to natural coke. Soxhlet extraction was conducted on each coal for 48 h. The extract was analyzed on a gas chromatograph-mass spectrometer (GC-MS). The results show that the total PAH content ranged from 0.31 to 57.6 ??g/g of coal (on a dry basis). It varied with coal rank and is highest in the maturity range of bituminous coal rank. High-molecular-weight (HMW) PAHs are predominant in low-rank coals, but low-molecular-weight (LMW) PAHs are predominant in high-rank coals. The low-sulfur coals have a higher PAH content than high-sulfur coals. It may be explained by an increasing connection between disulfide bonds and PAHs in high-sulfur coal. In addition, it leads us to conclude that the PAH content of coals may be related to the depositional environment. ?? 2010 American Chemical Society.

Fate of bromine in pyrolysis of printed circuit board wastes.

PubMed

Chien, Y C; Wang, H P; Lin, K S; Huang, Y J; Yang, Y W

2000-02-01

Behavior of Br in pyrolysis of the printed circuit board waste with valuable copper and oil recycling has been studied in the present work. Experimentally, pyrolysis of the printed circuit board waste generated approximately 40.6% of oils, 24.9% of noncondensible gases and 34.5% of solid residues that enriched in copper (90-95%). The cuts of the oils produced from pyrolysis of the printed circuit board waste into weighted boiling fraction were primarily light naphtha and heavy gas oil. Approximately 72.3% of total Br in the printed circuit board waste were found in product gas mainly as HBr and bromobenzene. However, by extended X-ray absorption fine structural (EXAFS) spectroscopy, Cu-O and Cu-(O)-Cu species with bond distance of 1.87 and 2.95 A, respectively, were observed in the solid residues. Essentially, no Cu-Br species was found.

Effects of inherent/enhanced solid acidity and morphology of diatomite templates on the synthesis and porosity of hierarchically porous carbon.

PubMed

Liu, Dong; Yuan, Peng; Tan, Daoyong; Liu, Hongmei; Fan, Mingde; Yuan, Aihua; Zhu, Jianxi; He, Hongping

2010-12-21

The inherent or enhanced solid acidity of raw or activated diatomite is found to have significant effects on the synthesis of hierarchically porous diatomite-templated carbon with high surface area and special porous structure. The solid acidity makes raw/activated diatomite a catalyst for the generation of porous carbon, and the porous parameters of the carbon products are strongly dependent on the solid acidity of diatomite templates. The morphology of diatomite also dramatically affects the textural structure of porous carbon. Two types of macroporous structures in the carbon product, the partially solid pillars and the ordered hollow tubes, derive from the replication of the central and the edge pores of diatom shell, respectively. The hierarchically porous carbon shows good capability for the adsorption of solvent naphtha and H(2), enabling potential applications in adsorption and gas storage.

APC implementation in Chandra Asri - ethylene plant

NASA Astrophysics Data System (ADS)

Sidiq, Mochamad; Mustofa, Ali

2017-05-01

Nowadays, the modern process plants are continuously improved for maximizing production, Optimization of the energy and raw material and reducing the risk. Due to many disturbances appearance between the process units, hence, the failure of one unit might have a bad effect on the overall productivity. Ethylene Plant have significant opportunities for using Advanced Process Control (APC) technologies to improve operation stability, push closer to quality or equipment limit, and improve the capability of process units to handle disturbances. APC implementation had considered a best answer for solving multivariable control problem. PT. Chandra Asri Petrochemical, Tbk (CAP) operates a large naphtha cracker complex at Cilegon, Indonesia. To optimize the plant operation and to enhance the benefit, Chandra Asri has been decided to implement Advance Process Control (APC) for ethylene plant. The APC implementation technology scopes at CAP are as follows: 1. Hot Section : Furnaces, Quench Tower 2. Cold Section : Demethanizer, Deethanizer, Acetylene Converter, Ethylene Fractionator, Depropanizer, Propylene Fractionator, Debutanizer

Steam reforming of heptane in a fluidized bed membrane reactor

NASA Astrophysics Data System (ADS)

Rakib, Mohammad A.; Grace, John R.; Lim, C. Jim; Elnashaie, Said S. E. H.

n-Heptane served as a model compound to study steam reforming of naphtha as an alternative feedstock to natural gas for production of pure hydrogen in a fluidized bed membrane reactor. Selective removal of hydrogen using Pd 77Ag 23 membrane panels shifted the equilibrium-limited reactions to greater conversion of the hydrocarbons and lower yields of methane, an intermediate product. Experiments were conducted with no membranes, with one membrane panel, and with six panels along the height of the reactor to understand the performance improvement due to hydrogen removal in a reactor where catalyst particles were fluidized. Results indicate that a fluidized bed membrane reactor (FBMR) can provide a compact reformer for pure hydrogen production from a liquid hydrocarbon feedstock at moderate temperatures (475-550 °C). Under the experimental conditions investigated, the maximum achieved yield of pure hydrogen was 14.7 moles of pure hydrogen per mole of heptane fed.

The US Geological Survey's national coal resource assessment: The results

USGS Publications Warehouse

Ruppert, Leslie F.; Kirschbaum, Mark A.; Warwick, Peter D.; Flores, Romeo M.; Affolter, Ronald H.; Hatch, Joseph R.

2002-01-01

The US Geological Survey and the State geological surveys of many coal-bearing States recently completed a new assessment of the top producing coal beds and coal zones in five major producing coal regions—the Appalachian Basin, Gulf Coast, Illinois Basin, Colorado Plateau, and Northern Rocky Mountains and Great Plains. The assessments, which focused on both coal quality and quantity, utilized geographic information system technology and large databases. Over 1,600,000 million short tons of coal remain in over 60 coal beds and coal zones that were assessed. Given current economic, environmental, and technological restrictions, the majority of US coal production will occur in that portion of the assessed coal resource that is lowest in sulfur content. These resources are concentrated in parts of the central Appalachian Basin, Colorado Plateau, and the Northern Rocky Mountains.

INTEGRATED POWER GENERATION SYSTEMS FOR COAL MINE WASTE METHANE UTILIZATION

DOE Office of Scientific and Technical Information (OSTI.GOV)

Peet M. Soot; Dale R. Jesse; Michael E. Smith

2005-08-01

An integrated system to utilize the waste coal mine methane (CMM) at the Federal No. 2 Coal Mine in West Virginia was designed and built. The system includes power generation, using internal combustion engines, along with gas processing equipment to upgrade sub-quality waste methane to pipeline quality standards. The power generation has a nominal capacity of 1,200 kw and the gas processing system can treat about 1 million cubic feet per day (1 MMCFD) of gas. The gas processing is based on the Northwest Fuel Development, Inc. (NW Fuel) proprietary continuous pressure swing adsorption (CPSA) process that can remove nitrogenmore » from CMM streams. The two major components of the integrated system are synergistic. The byproduct gas stream from the gas processing equipment can be used as fuel for the power generating equipment. In return, the power generating equipment provides the nominal power requirements of the gas processing equipment. This Phase III effort followed Phase I, which was comprised of a feasibility study for the project, and Phase II, where the final design for the commercial-scale demonstration was completed. The fact that NW Fuel is desirous of continuing to operate the equipment on a commercial basis provides the validation for having advanced the project through all of these phases. The limitation experienced by the project during Phase III was that the CMM available to operate the CPSA system on a commercial basis was not of sufficiently high quality. NW Fuel's CPSA process is limited in its applicability, requiring a relatively high quality of gas as the feed to the process. The CPSA process was demonstrated during Phase III for a limited time, during which the processing capabilities met the expected results, but the process was never capable of providing pipeline quality gas from the available low quality CMM. The NW Fuel CPSA process is a low-cost ''polishing unit'' capable of removing a few percent nitrogen. It was never intended to process CMM streams containing high levels of nitrogen, as is now the case at the Federal No.2 Mine. Even lacking the CPSA pipeline delivery demonstration, the project was successful in laying the groundwork for future commercial applications of the integrated system. This operation can still provide a guide for other coal mines which need options for utilization of their methane resources. The designed system can be used as a complete template, or individual components of the system can be segregated and utilized separately at other mines. The use of the CMM not only provides an energy fuel from an otherwise wasted resource, but it also yields an environmental benefit by reducing greenhouse gas emissions. The methane has twenty times the greenhouse effect as compared to carbon dioxide, which the combustion of the methane generates. The net greenhouse gas emission mitigation is substantial.« less

Energy Crunch is Stimulant for Coal Research

ERIC Educational Resources Information Center

Chemical and Engineering News, 1973

1973-01-01

Presents views of the first International Coal Research Conference, involving problems facing reconversion to a coal-based energy economy, organization and funding of coal research units, development of new techniques for mining and using coal; and transportation of coal products to users. (CC)

Quarterly Coal Distribution

EIA Publications

2017-01-01

The Quarterly Coal Distribution Report (QCDR) provides detailed U.S. domestic coal distribution data by coal origin state, coal destination state, mode of transportation, and consuming sector. Quarterly data for all years are preliminary and will be superseded by the release of the corresponding Annual Coal Distribution Report.

GIS representation of coal-bearing areas in Antarctica

USGS Publications Warehouse

Merrill, Matthew D.

2016-03-11

Understanding the distribution of coal-bearing geologic units in Antarctica provides information that can be used in sedimentary, geomorphological, paleontological, and climatological studies. This report is a digital compilation of information on Antarctica’s coal-bearing geologic units found in the literature. It is intended to be used in small-scale spatial geographic information system (GIS) investigations and as a visual aid in the discussion of Antarctica’s coal resources or in other coal-based geologic investigations. Instead of using spatially insignificant point markers to represent large coal-bearing areas, this dataset uses polygons to represent actual coal-bearing lithologic units. Specific locations of coal deposits confirmed from the literature are provided in the attribution for the coal-bearing unit polygons. Coal-sample-location data were used to confirm some reported coal-bearing geology. The age and extent of the coal deposits indicated in the literature were checked against geologic maps ranging from local scale at 1:50,000 to Antarctic continental scale at 1:5,000,000; if satisfactory, the map boundaries were used to generate the polygons for the coal-bearing localities.

The World Coal Quality Inventory: South America

USGS Publications Warehouse

Karlsen, Alex W.; Tewalt, Susan J.; Bragg, Linda J.; Finkelman, Robert B.

2006-01-01

Executive Summary-Introduction: The concepts of a global environment and economy are strongly and irrevocably linked to global energy issues. Worldwide coal production and international coal trade are projected to increase during the next several decades in an international energy mix that is still strongly dependent on fossil fuels. Therefore, worldwide coal use will play an increasingly visible role in global environmental, economic, and energy forums. Policy makers require information on coal, including coal quality data, to make informed decisions regarding domestic coal resource allocation, import needs and export opportunities, foreign policy objectives, technology transfer policies, foreign investment prospects, environmental and health assessments, and byproduct use and disposal issues. The development of a worldwide, reliable, coal quality database would help ensure the most economically and environmentally efficient global use of coal. The U.S. Geological Survey (USGS), in cooperation with many agencies and scientists from the world's coal producing countries, originally undertook a project to obtain representative samples of coal from most of the world's producing coal provinces during a limited period of time (roughly 1998-2005), which is called the World Coal Quality Inventory (WoCQI). The multitude of producing coal mines, coal occurrences, or limited accessibility to sites in some countries can preclude collecting more than a single sample from a mine. In some areas, a single sample may represent an entire coal mining region or basin. Despite these limitations in sampling and uneven distribution of sample collection, the analytical results can still provide a general overview of world coal quality. The USGS intends to present the WoCQI data in reports and, when possible, in Geographic Information System (GIS) products that cover important coal bearing and producing regions.

Characteristics of Pyrolytic Topping in Fluidized Bed for Different Volatile Coals

NASA Astrophysics Data System (ADS)

Xiong, R.; Dong, L.; Xu, G. W.

Coal is generally combusted or gasified directly to destroy completely the chemical structures, such as aromatic rings containing in volatile coals including bituminite and lignite. Coal topping refers to a process that extracts chemicals with aromatic rings from such volatile coals in advance of combustion or gasification and thereby takes advantage of the value of coal as a kind of chemical structure resource. CFB boiler is the coal utilization facility that can be easily retrofitted to implement coal topping. A critical issue for performing coal topping is the choice of the pyrolytic reactor that can be different types. The present study concerns fluidized bed reactor that has rarely been tested for use in coal topping. Two different types of coals, one being Xiaolongtan (XLT) lignite and the other Shanxi (SX) bituminous, were tested to clarify the yield and composition of pyrolysis liquid and gas under conditions simulating actual operations. The results showed that XLT lignite coals had the maximum tar yield in 823-873K and SX bituminite realized its highest tar yield in 873-923K. Overall, lignite produced lower tar yield than bituminous coal. The pyrolysis gas from lignite coals contained more CO and CO2 and less CH4, H2 and C2+C3 (C2H4, C2H6, C3H6, C3H8) components comparing to that from bituminous coal. TG-FTIR analysis of tars demonstrated that for different coals there are different amounts of typical chemical species. Using coal ash of CFB boiler, instead of quartz sand, as the fluidized particles decreased the yields of both tar and gas for all the tested coals. Besides, pyrolysis in a reaction atmosphere simulating the pyrolysis gas (instead of N2) resulted also in higher production of pyrolysis liquid.

Update on coal in Big Horn basin, Montana and Wyoming

DOE Office of Scientific and Technical Information (OSTI.GOV)

Jones, R.W.

1983-08-01

The Big Horn Coal basin is located within the topographic and structural basin of the same name and is defined by the limits of the Upper Cretaceous Mesaverde Formation in northwestern Wyoming and the Eagle Sandstone in south-central Montana. The coal in this basin ranges in rank from high volatile C bituminous (based primarily on resistance to weathering) to subbituminous B coal. In general, the Mesaverde and Eagle coals are highest in heat content, averaging over 10,500 Btu/lb; the Fort Union coals in the Red Lodge-Bear Creek and Grass Creek fields average about 10,200 Btu/lb and are second highest inmore » heating value. The Meeteetse Formation contains coals that average 9,800 Btu/lb, the lowest heating values in the basin. An average heating value for all coal in the basin is slightly less than 10,000 But/lb. The average sulfur content of all coals in this basin is less than 1%, with a range of 0.4 to 2.2%. Coal mining in the Big Horn Coal basin began in the late 1880s in the Red Lodge field and has continued to the present. Almost 53 million tons of coal have been mined in the basin; nearly 78% of this production (41 million tons) is from bituminous Fort Union coal beds in the Red Lodge-Bear Creek and Bridger coal fields, Montana. Original in-place resources for the Big Horn Coal basin are given by rank of coal: 1,265.12 million tons of bituminous coal resources have been calculated for the Silvertip field, Wyoming, and the Red Lodge-Bear Creek and Bridger fields, Montana; 563.78 million tons of subbituminous resources have been calculated for the remaining Wyoming coal fields.« less

The environmental impact of future coal production and use in the EEC

DOE Office of Scientific and Technical Information (OSTI.GOV)

Not Available

1983-01-01

The aims of this study are to assess the expected increased levels of coal consumption in the European Community up to the year 2000; to estimate to what extent consumer demand is likely to be met by EEC production; to determine the level of polluting emissions which are likely to derive from changes in coal consumption and production; and finally, to compare the environmental impact of alternative, existing or developing means of coal utilisation. Contents: Conclusions; Future coal supply and demand in the EEC; Environmental consequences of coal production and use; Coal extraction; Transport and storage; Coal combustion: air pollution;more » Coal combustion: water pollution; Pollution from solid wastes; Coal conversion process; Environmental control technology; Bibliography.« less

Rosebud SynCoal Partnership, SynCoal{reg_sign} demonstration technology update

DOE Office of Scientific and Technical Information (OSTI.GOV)

Sheldon, R.W.

1997-12-31

An Advanced Coal Conversion Process (ACCP) technology being demonstrated in eastern Montana (USA) at the heart of one of the world`s largest coal deposits is providing evidence that the molecular structure of low-rank coals can be altered successfully to produce a unique product for a variety of utility and industrial applications. The product is called SynCoal{reg_sign} and the process has been developed by the Rosebud SynCoal Partnership (RSCP) through the US Department of Energy`s multi-million dollar Clean Coal Technology Program. The ACCP demonstration process uses low-pressure, superheated gases to process coal in vibrating fluidized beds. Two vibratory fluidized processing stagesmore » are used to heat and convert the coal. This is followed by a water spray quench and a vibratory fluidized stage to cool the coal. Pneumatic separators remove the solid impurities from the dried coal. There are three major steps to the SynCoal{reg_sign} process: (1) thermal treatment of the coal in an inert atmosphere, (2) inert gas cooling of the hot coal, and (3) removal of ash minerals. When operated continuously, the demonstration plant produces over 1,000 tons per day (up to 300,000 tons per year) of SynCoal{reg_sign} with a 2% moisture content, approximately 11,800b Btu/lb and less than 1.0 pound of SO{sub 2} per million Btu. This product is obtained from Rosebud Mine sub-bituminous coal which starts with 25% moisture, 8,600 Btu/lb and approximately 1.6 pounds of SO{sub 2} per million Btu.« less

30 CFR 772.13 - Coal exploration compliance duties.

Code of Federal Regulations, 2014 CFR

2014-07-01

... 30 Mineral Resources 3 2014-07-01 2014-07-01 false Coal exploration compliance duties. 772.13... INTERIOR SURFACE COAL MINING AND RECLAMATION OPERATIONS PERMITS AND COAL EXPLORATION SYSTEMS UNDER REGULATORY PROGRAMS REQUIREMENTS FOR COAL EXPLORATION § 772.13 Coal exploration compliance duties. (a) All...

30 CFR 772.13 - Coal exploration compliance duties.

Code of Federal Regulations, 2010 CFR

2010-07-01

... 30 Mineral Resources 3 2010-07-01 2010-07-01 false Coal exploration compliance duties. 772.13... INTERIOR SURFACE COAL MINING AND RECLAMATION OPERATIONS PERMITS AND COAL EXPLORATION SYSTEMS UNDER REGULATORY PROGRAMS REQUIREMENTS FOR COAL EXPLORATION § 772.13 Coal exploration compliance duties. (a) All...

30 CFR 772.13 - Coal exploration compliance duties.

Code of Federal Regulations, 2012 CFR

2012-07-01

... 30 Mineral Resources 3 2012-07-01 2012-07-01 false Coal exploration compliance duties. 772.13... INTERIOR SURFACE COAL MINING AND RECLAMATION OPERATIONS PERMITS AND COAL EXPLORATION SYSTEMS UNDER REGULATORY PROGRAMS REQUIREMENTS FOR COAL EXPLORATION § 772.13 Coal exploration compliance duties. (a) All...

30 CFR 772.13 - Coal exploration compliance duties.

Code of Federal Regulations, 2013 CFR

2013-07-01

... 30 Mineral Resources 3 2013-07-01 2013-07-01 false Coal exploration compliance duties. 772.13... INTERIOR SURFACE COAL MINING AND RECLAMATION OPERATIONS PERMITS AND COAL EXPLORATION SYSTEMS UNDER REGULATORY PROGRAMS REQUIREMENTS FOR COAL EXPLORATION § 772.13 Coal exploration compliance duties. (a) All...

Microbial solubilization of coal

DOEpatents

Strandberg, G.W.; Lewis, S.N.

1988-01-21

The present invention relates to a cell-free preparation and process for the microbial solubilization of coal into solubilized coal products. More specifically, the present invention relates to bacterial solubilization of coal into solubilized coal products and a cell-free bacterial byproduct useful for solubilizing coal. 5 tabs.

30 CFR 772.13 - Coal exploration compliance duties.

Code of Federal Regulations, 2011 CFR

2011-07-01

... 30 Mineral Resources 3 2011-07-01 2011-07-01 false Coal exploration compliance duties. 772.13... INTERIOR SURFACE COAL MINING AND RECLAMATION OPERATIONS PERMITS AND COAL EXPLORATION SYSTEMS UNDER REGULATORY PROGRAMS REQUIREMENTS FOR COAL EXPLORATION § 772.13 Coal exploration compliance duties. (a) All...

Simulated coal spill causes mortality and growth inhibition in tropical marine organisms.

PubMed

Berry, Kathryn L E; Hoogenboom, Mia O; Flores, Florita; Negri, Andrew P

2016-05-13

Coal is a principal fossil fuel driving economic and social development, and increases in global coal shipments have paralleled expansion of the industry. To identify the potential harm associated with chronic marine coal contamination, three taxa abundant in tropical marine ecosystems (the coral Acropora tenuis, the reef fish Acanthochromis polyacanthus and the seagrass Halodule uninervis) were exposed to five concentrations (0-275 mg coal l(-1)) of suspended coal dust (<63 μm) over 28 d. Results demonstrate that chronic coal exposure can cause considerable lethal effects on corals, and reductions in seagrass and fish growth rates. Coral survivorship and seagrass growth rates were inversely related to increasing coal concentrations (≥38 mg coal l(-1)) and effects increased between 14 and 28 d, whereas fish growth rates were similarly depressed at all coal concentrations tested. This investigation provides novel insights into direct coal impacts on key tropical taxa for application in the assessment of risks posed by increasing coal shipments in globally threatened marine ecosystems.

Variability of Mercury Content in Coal Matter From Coal Seams of The Upper Silesia Coal Basin

NASA Astrophysics Data System (ADS)

Wierzchowski, Krzysztof; Chećko, Jarosław; Pyka, Ireneusz

2017-12-01

The process of identifying and documenting the quality parameters of coal, as well as the conditions of coal deposition in the seam, is multi-stage and extremely expensive. The taking and analyzing of seam samples is the method of assessment of the quality and quantity parameters of coals in deep mines. Depending on the method of sampling, it offers quite precise assessment of the quality parameters of potential commercial coals. The main kind of seam samples under consideration are so-called "documentary seam samples", which exclude dirt bands and other seam contaminants. Mercury content in coal matter from the currently accessible and exploited coal seams of the Upper Silesian Coal Basin (USCB) was assessed. It was noted that the mercury content in coal seams decreases with the age of the seam and, to a lesser extent, seam deposition depth. Maps of the variation of mercury content in selected lithostratigraphic units (layers) of the Upper Silesian Coal Basin have been created.

An update on blast furnace granular coal injection

DOE Office of Scientific and Technical Information (OSTI.GOV)

Hill, D.G.; Strayer, T.J.; Bouman, R.W.

1997-12-31

A blast furnace coal injection system has been constructed and is being used on the furnace at the Burns Harbor Division of Bethlehem Steel. The injection system was designed to deliver both granular (coarse) and pulverized (fine) coal. Construction was completed on schedule in early 1995. Coal injection rates on the two Burns Harbor furnaces were increased throughout 1995 and was over 200 lbs/ton on C furnace in September. The injection rate on C furnace reached 270 lbs/ton by mid-1996. A comparison of high volatile and low volatile coals as injectants shows that low volatile coal replaces more coke andmore » results in a better blast furnace operation. The replacement ratio with low volatile coal is 0.96 lbs coke per pound of coal. A major conclusion of the work to date is that granular coal injection performs very well in large blast furnaces. Future testing will include a processed sub-bituminous coal, a high ash coal and a direct comparison of granular versus pulverized coal injection.« less

Carbon dioxide from coal combustion: Variation with rank of US coal

USGS Publications Warehouse

Quick, J.C.; Glick, D.C.

2000-01-01

Carbon dioxide from combustion of US coal systematically varies with ASTM rank indices, allowing the amount of CO2 produced per net unit of energy to be predicted for individual coals. No single predictive equation is applicable to all coals. Accordingly, we provide one equation for coals above high volatile bituminous rank and another for lower rank coals. When applied to public data for commercial coals from western US mines these equations show a 15% variation of kg CO2 (net GJ)-1. This range of variation suggests reduction of US CO2 emissions is possible by prudent selection of coal for combustion. Maceral and mineral content are shown to slightly affect CO2 emissions from US coal. We also suggest that CO2 emissions increased between 6 and 8% in instances where Midwestern US power plants stopped burning local, high-sulfur bituminous coal and started burning low-sulfur, subbituminous C rank coal from the western US.

Simulated coal spill causes mortality and growth inhibition in tropical marine organisms

NASA Astrophysics Data System (ADS)

Berry, Kathryn L. E.; Hoogenboom, Mia O.; Flores, Florita; Negri, Andrew P.

2016-05-01

Coal is a principal fossil fuel driving economic and social development, and increases in global coal shipments have paralleled expansion of the industry. To identify the potential harm associated with chronic marine coal contamination, three taxa abundant in tropical marine ecosystems (the coral Acropora tenuis, the reef fish Acanthochromis polyacanthus and the seagrass Halodule uninervis) were exposed to five concentrations (0-275 mg coal l-1) of suspended coal dust (<63 μm) over 28 d. Results demonstrate that chronic coal exposure can cause considerable lethal effects on corals, and reductions in seagrass and fish growth rates. Coral survivorship and seagrass growth rates were inversely related to increasing coal concentrations (≥38 mg coal l-1) and effects increased between 14 and 28 d, whereas fish growth rates were similarly depressed at all coal concentrations tested. This investigation provides novel insights into direct coal impacts on key tropical taxa for application in the assessment of risks posed by increasing coal shipments in globally threatened marine ecosystems.

Raman spectral characteristics of magmatic-contact metamorphic coals from Huainan Coalfield, China

NASA Astrophysics Data System (ADS)

Chen, Shancheng; Wu, Dun; Liu, Guijian; Sun, Ruoyu

2017-01-01

Normal burial metamorphism of coal superimposed by magmatic-contact metamorphism makes the characteristics of the Raman spectrum of coal changed. Nine coal samples were chosen at a coal transect perpendicular to the intrusive dike, at the No. 3 coal seam, Zhuji Coal Mine, Huainan Coalfield, China, with different distances from dike-coal boundary (DCB). Geochemical (proximate and ultimate) analysis and mean random vitrinite reflectance (R0, %) indicate that there is a significant relationship between the values of volatile matter and R0 in metamorphosed coals. Raman spectra show that the graphite band (G band) becomes the major band but the disordered band (D band) disappears progressively, with the increase of metamorphic temperature in coals, showing that the structural organization in high-rank contact-metamorphosed coals is close to that of well-crystallized graphite. Evident relationships are observed between the calculated Raman spectral parameters and the peak metamorphic temperature, suggesting some spectral parameters have the potentials to be used as geothermometers for contact-metamorphic coals.

Coal Combustion Science quarterly progress report, April--June 1992. Task 1, Coal devolatilization: Task 2, Coal char combustion; Task 3, Fate of mineral matter

DOE Office of Scientific and Technical Information (OSTI.GOV)

Hardesty, D.R.; Hurt, R.H.; Baxter, L.L.

1992-09-01

The objective of this work is to support the Office of Fossil Energy in executing research on coal combustion science. This project consists of basic research on coal combustion that supports both the Pittsburgh Energy Technology Center (PETC) Direct Utilization Advanced Research and Technology Development Program, and the International Energy Agency (IEA) Coal Combustion Science Project. Specific tasks include: The characterization of the physical and chemical processes that constitute the early devolatilization phase of coal combustion: Characterization of the combustion behavior of selected coals under conditions relevant to industria pulverized coal-fired furnaces; and to establish a quantitative understanding of themore » mechanisms and rates of transformation, fragmentation, and deposition of mineral matter in coal combustion environments as a function of coal type, particle size and temperature, the initial forms and distributions of mineral species in the unreacted coal, and the local gas temperature and composition.« less

Filtering coal-derived oil through a filter media precoated with particles partially solubilized by said oil

DOEpatents

Rodgers, Billy R.; Edwards, Michael S.

1977-01-01

Solids such as char, ash, and refractory organic compounds are removed from coal-derived liquids from coal liquefaction processes by the pressure precoat filtration method using particles of 85-350 mesh material selected from the group of bituminous coal, anthracite coal, lignite, and devolatilized coals as precoat materials and as body feed to the unfiltered coal-derived liquid.

Influence of Geological Structure on Coal and Gas Outburst Occurrences in Turkish Underground Coal Mines

NASA Astrophysics Data System (ADS)

Esen, Olgun; Özer, Samet Can; Fişne, Abdullah

2015-04-01

Coal and gas outbursts are sudden and violent releases of gas and in company with coal that result from a complex function of geology, stress regime with gas pressure and gas content of the coal seam. The phenomena is referred to as instantaneous outbursts and have occurred in virtually all the major coal producing countries and have been the cause of major disasters in the world mining industry. All structures from faults to joints and cleats may supply gas or lead to it draining away. Most geological structures influence the way in which gas can drain within coal seams. From among all the geological factors two groups can be distinguished: parameters characterising directly the occurrence and geometry of the coal seams; parameters characterising the tectonic disturbances of the coal seams and neighbouring rocks. Also dykes may act as gas barriers. When the production of the coal seam is advanced in mine working areas, these barriers are failed mostly in the weak and mylonitized zones. Geology also plays a very important role in the outburst process. Coal seams of complex geological structure including faults, folds, and fractured rocks are liable to outbursts if coal seams and neighbouring rocks have high gas content level. The purpose of the study is to enlighten the coal industry in Turkey to improving mine safety in underground coal production and decrease of coal and gas outburst events due to increasing depth of mining process. In Turkey; the years between 1969 and 2013, the number of 90 coal and gas outbursts took place in Zonguldak Hard Coal Basin in both Kozlu and Karadon Collieries. In this study the liability to coal and gas outburst of the coal seams are investigated by measuring the strength of coal and the rock pressure. The correlation between these measurements and the event locations shows that the geological structures resulted in 52 events out of 90 events; 19 events close to the fault zones, 25 events thorough the fault zones and 8 events in the zones where sudden changes of inclination and/or thickness of the coal seam.

Oxidation and carbonisation of coals: a case study of coal fire affected coals from the Wuda coalfield, Inner Mongolia, China

NASA Astrophysics Data System (ADS)

Kus, Jolanta; Meyer, Uwe; Ma, Jianwei; Chen-Brauchler, Dai

2010-05-01

At the coalfield of Wuda (Inner Mongolia, PR China) extensive underground coal fires cause widespread thermal and oxidative effects in coal seams. Within phase B of the Coal Fire Research Project of the Sino-German Initiative, methods for innovative fire-extinguishing technologies were investigated in multifaceted research approaches. Extensive investigations of oxidative and thermally affected coal seams in coal fire zone 18 were conducted in 2008 prior to application of new fire-extinguishing methods. We present results from the outcrop of coal seam No. 4 in the fire zone 18. The coal of seam No. 4 is of Early Permian age and belongs stratigraphically to the Shanxi Formation. The unaffected coal displays a high volatile bituminous A rank with a background value of random vitrinite reflectance ranging from 0.90 to 0.96 % Rr. Coal channel samples were coallected at actively extracted coal faces along multiple profiles with surface temperatures ranging from about 50° to 600°C. Microscopic examinations revealed a variety of products of coal exposure to the fire. Within coal samples, a marked rise in vitrinite reflectance from background values to 5.55% Rr (6.00 % Rmax) is encountered. In addition, a number of coal samples showed suppressed vitrinite reflectances ranging between 0.82 to 0.88% Rr. Further, seemingly heat unaffected coal samples display intensive development of oxidations rims at coal grain edges and cracks as well as shrinkage cracks and formation of iron oxides/hydroxides. Instead, thermally affected coal samples with higher coalification grade are further characterised by development of macropores (devolatilisation pores) in vitrinitic streaks, transformation of liptinite to meta-liptinite and micrinite as well as by natural coke particles of mostly porous nature and fine to coarse grained anisotropic mosaic. Coal petrographic investigations confirmed a hypothesis that both, oxidations as well as low temperature carbonisation govern the thermal regime in the coal fire zone 18. The occurrence of various thermal alteration products indicates temperatures in the range of 500-700°C.

Healthy Indoor Environment Protocols for Home Energy Upgrades

EPA Pesticide Factsheets

This page contains the EPA-developed Healthy Indoor Environment Protocols for Home Energy Upgrades, a PDF guide that provides a set of best practices for improving indoor air quality in conjunction with energy upgrade work in homes.

Geology, coal quality, and resources of the Antaramut-Kurtan-Dzoragukh coal field, north-central Armenia

USGS Publications Warehouse

Pierce, B.S.; Martirosyan, A.; Malkhasian, G.; Harutunian, S.; Harutunian, G.

2001-01-01

The Antaramut-Kurta-Dzoragukh (AKD) coal deposit is a previously unrecognized coal field in north-central Armenia. Coal has been known to exist in the general vicinity since the turn of the century, but coal was thought to be restricted to a small (1 km2) area only near the village of Antaramut. However, through detailed field work and exploratory drilling, this coal deposit has been expanded to at least 20 km2, and thus renamed the Antaramut-Kurtan-Dzoragukh coal field, for the three villages that the coal field encompasses. The entire coal-bearing horizon, a series of tuffaceous sandstones, siltstones, and claystones, is approximately 50 m thick. The AKD coal field contains two coal beds, each greater than 1 m thick, and numerous small rider beds, with a total resource of approximately 31,000,000 metric tonnes. The coals are late Eocene in age, high volatile bituminous in rank, relatively high in ash yield (approximately 40%, as-determined basis) and moderate in sulfur content (approximately 3%, as-determined basis). The two coal beds (No. 1 and No. 2), on a moist, mineral-matter-free basis, have high calorific values of 32.6 MJ/kg (7796 cal/g) and 36.0 MJ/kg (8599 cal/g), respectively. Coal is one of the few indigenous fossil fuel resources occurring in Armenia and thus, the AKD coal field could potentially provide fuel for heating and possibly energy generation in the Armenian energy budget. Published by Elsevier Science B.V.

Is there an association of circulatory hospitalizations independent of mining employment in coal-mining and non-coal-mining counties in west virginia?

PubMed

Talbott, Evelyn O; Sharma, Ravi K; Buchanich, Jeanine; Stacy, Shaina L

2015-04-01

Exposures associated with coal mining activities, including diesel fuel exhaust, products used in coal processing, and heavy metals and other forms of particulate matter, may impact the health of nearby residents. We investigated the relationships between county-level circulatory hospitalization rates (CHRs) in coal and non-coal-mining communities of West Virginia, coal production, coal employment, and sociodemographic factors. Direct age-adjusted CHRs were calculated using West Virginia hospitalizations from 2005 to 2009. Spatial regressions were conducted to explore associations between CHR and total, underground, and surface coal production. After adjustment, neither total, nor surface, nor underground coal production was significantly related to rate of hospitalization for circulatory disease. Our findings underscore the significant role sociodemographic and behavioral factors play in the health and well-being of coal mining communities.

77 FR 22607 - Notice of Competitive Coal Lease Sale, Wyoming

Federal Register 2010, 2011, 2012, 2013, 2014

2012-04-16

...] Notice of Competitive Coal Lease Sale, Wyoming AGENCY: Bureau of Land Management, Interior. ACTION: Notice. SUMMARY: Notice is hereby given that certain coal resources in the South Porcupine Coal Tract..., Coal Coordinator, at 307-775-6258, and 307-775-6206, respectively. SUPPLEMENTARY INFORMATION: This coal...

Mercury in Eastern Kentucky coals: Geologic aspects and possible reduction strategies

USGS Publications Warehouse

Hower, J.C.; Eble, C.F.; Quick, J.C.

2005-01-01

Mercury emissions from US coal-fired power plants will be regulated by the US Environmental Protection Agency (USEPA) before the end of the decade. Because of this, the control of Hg in coal is important. Control is fundamentally based on the knowledge of the amounts of Hg in mined, beneficiated, and as-fired coal. Eastern Kentucky coals, on a reserve district level, have Hg contents similar to the USA average for coal at mines. Individual coals show greater variation at the bench scale, with Hg enrichment common in the top bench, often associated with enhanced levels of pyritic sulfur. Some of the variation between parts of eastern Kentucky is also based on the position relative to major faults. The Pine Mountain thrust fault appears to be responsible for elemental enrichment, including Hg, in coals on the footwall side of the thrust. Eastern Kentucky coals shipped to power plants in 1999, the year the USEPA requested coal quality information on coal deliveries, indicate that coals shipped from the region have 0.09 ppm Hg, compared to 0.10 ppm for all delivered coals in the USA. On an equal energy basis, and given equal concentrations of Hg, the high volatile bituminous coals from eastern Kentucky would emit less Hg than lower rank coals from other USA regions. ?? 2005 Elsevier B.V. All rights reserved.

Chlorine in coal and its relationship with boiler corrosion. Technical report, 1 March--31 May 1994

DOE Office of Scientific and Technical Information (OSTI.GOV)

Chou, M.I.M.; Lytle, J.M.; Ruch, R.R.

1994-09-01

Limited literature and use history data have suggested that some high-chlorine Illinois coals do not cause boiler corrosion while extensive data developed by the British correlate corrosion with chlorine content and other parameters related to the coal and boiler. The differences in corrosivity in coals may be due to the coal properties, to blending of coals, or to the boiler parameters in which they were burned. The goals of this study focus on coal properties. In this quarter, both destructive temperature-programmed Thermogravimetry with Fourier transform infrared (TGA-FTIR) and non-destructive X-ray absorption near-edge structure (XANES) techniques were used to examine themore » forms and the evolution characteristics of chlorine in coals. The TGA-FTIR results indicate that under oxidation condition, both British and Illinois coals release hydrogen chloride gas. Illinois coals release the gas at high temperature with maximum evolution temperature ranged between 210 and 280 C. The XANES results indicate that chlorine in coal exists in ionic forms including a solid salt form. The solid NaCl salt form, however, is observed only in some of the British coals and none of the Illinois coals. These results combined with TGA-FTIR results suggest that the chlorine ions in Illinois coals are different from the chlorine ions in British coals.« less

Chemistry of thermally altered high volatile bituminous coals from southern Indiana

USGS Publications Warehouse

Walker, R.; Mastalerz, Maria; Brassell, S.; Elswick, E.; Hower, J.C.; Schimmelmann, A.

2007-01-01

The optical properties and chemical characteristics of two thermally altered Pennsylvanian high volatile bituminous coals, the non-coking Danville Coal Member (Ro = 0.55%) and the coking Lower Block Coal Member (Ro = 0.56%) were investigated with the purpose of understanding differences in their coking behavior. Samples of the coals were heated to temperatures of 275????C, 325????C, 375????C and 425????C, with heating times of up to one hour. Vitrinite reflectance (Ro%) rises with temperature in both coals, with the Lower Block coal exhibiting higher reflectance at 375????C and 425????C compared to the Danville coal. Petrographic changes include the concomitant disappearance of liptinites and development of vesicles in vitrinites in both coals, although neither coal developed anisotropic coke texture. At 375????C, the Lower Block coal exhibits a higher aromatic ratio, higher reflectance, higher carbon content, and lower oxygen content, all of which indicate a greater degree of aromatization at this temperature. The Lower Block coal maintains a higher CH2/CH3 ratio than the Danville coal throughout the heating experiment, indicating that the long-chain unbranched aliphatics contained in Lower Block coal liptinites are more resistant to decomposition. As the Lower Block coal contains significant amounts of liptinite (23.6%), the contribution of aliphatics from these liptinites appears to be the primary cause of its large plastic range and high fluidity. ?? 2006 Elsevier B.V. All rights reserved.

Characterization and Recovery of Rare Earths from Coal and By-Products

DOE Office of Scientific and Technical Information (OSTI.GOV)

Granite, Evan J.; Roth, Elliot; Alvin, Mary Anne

Coal is a precious resource, both in the United States and around the world. The United States has a 250-year supply of coal, and generates between 30 - 40% of its electricity through coal combustion. Approximately 1 Gt of coal has been mined annually in the US, although the 2015 total will likely be closer to 900 Mt (http://www.eia.gov/coal/production/quarterly/). Most of the coal is burned for power generation, but substantial quantities are also employed in the manufacture of steel, chemicals, and activated carbons. Coal has a positive impact upon many industries, including mining, power, rail transportation, manufacturing, chemical, steel, activatedmore » carbon, and fuels. Everything that is in the earth’s crust is also present within coal to some extent, and the challenge is always to utilize abundant domestic coal in clean and environmentally friendly manners. In the case of the rare earths, these valuable and extraordinarily useful elements are present within the abundant coal and coal by-products produced domestically and world-wide. These materials include the coals, as well as the combustion by-products such as ashes, coal preparation wastes, gasification slags, and mining by-products. All of these materials can be viewed as potential sources of rare earth elements. Most of the common inorganic lanthanide compounds, such as the phosphates found in coal, have very high melting, boiling, and thermal decomposition temperatures, allowing them to concentrate in combustion and gasification by-products. Furthermore, rare earths have been found in interesting concentrations in the strata above and below certain coal seams. Much of the recent research on coal utilization in the United States has focused upon the capture of pollutants such as acid gases, particulates, and mercury, and the greenhouse gas carbon dioxide. The possible recovery of rare earth and other critical elements from abundant coal and by-products is an exciting new research area, representing a dramatic paradigm shift for coal.« less

Geomorphology of coal seam fires

NASA Astrophysics Data System (ADS)

Kuenzer, Claudia; Stracher, Glenn B.

2012-02-01

Coal fires occur in underground natural coal seams, in exposed surface seams, and in coal storage or waste piles. The fires ignite through spontaneous combustion or natural or anthropogenic causes. They are reported from China, India, USA, South Africa, Australia, and Russia, as well as many other countries. Coal fires lead to loss of a valuable resource (coal), the emission of greenhouse-relevant and toxic gases, and vegetation deterioration. A dangerous aspect of the fires is the threat to local mines, industries, and settlements through the volume loss underground. Surface collapse in coal fire areas is common. Thus, coal fires are significantly affecting the evolution of the landscape. Based on more than a decade of experience with in situ mapping of coal fire areas worldwide, a general classification system for coal fires is presented. Furthermore, coal seam fire geomorphology is explained in detail. The major landforms associated with, and induced by, these fires are presented. The landforms include manifestations resulting from bedrock surface fracturing, such as fissures, cracks, funnels, vents, and sponges. Further manifestations resulting from surface bedrock subsidence include sinkholes, trenches, depressions, partial surface subsidence, large surface subsidence, and slides. Additional geomorphologic coal fire manifestations include exposed ash layers, pyrometamorphic rocks, and fumarolic minerals. The origin, evolution, and possible future development of these features are explained, and examples from in situ surveys, as well as from high-resolution satellite data analyses, are presented. The geomorphology of coal fires has not been presented in a systematic manner. Knowledge of coal fire geomorphology enables the detection of underground coal fires based on distinct surface manifestations. Furthermore, it allows judgments about the safety of coal fire-affected terrain. Additionally, geomorphologic features are indicators of the burning stage of fires. Finally, coal fire geomorphology helps to explain landscape features whose occurrence would otherwise not be understood. Although coal fire-induced thermal anomalies and gas release are also indications of coal fire activity, as addressed by many investigators, no assessment is complete without sound geomorphologic mapping of the fire-induced geomorphologic features.

Preliminary report on methodology for calculating coal resources of the Wyodak-Anderson coal zone, Powder River basin, Wyoming and Montana

USGS Publications Warehouse

Ellis, Margaret S.; Gunther, Gregory L.; Flores, Romeo M.; Stricker, Gary D.; Ochs, Allan M.; Schuenemeyer, John H.

1998-01-01

The National Coal Resource Assessment of the Wyodak-Anderson coal zone includes reports on the geology, stratigraphy, quality, and quantity of coal. The calculation of resources is only one aspect of the assessment. Without thorough documentation of the coal resource study and the methods used, the results of our study could be misinterpreted. The task of calculating coal resources included many steps, the use of several commercial software programs, and the incorporation of custom programs. The methods used for calculating coal resources for the Wyodak-Anderson coal zone vary slightly from the methods used in other study areas, and by other workers in the National Coal Resource Assessment. The Wyodak-Anderson coal zone includes up to 10 coal beds in any given location. The net coal thickness of the zone at each data point location was calculated by summing the thickness of all of the coal beds that were greater than 2.5 ft thick. The amount of interburden is not addressed or reported in this coal resource assessment. The amount of overburden reported is the amount of rock above the stratigraphically highest coal bed in the zone. The resource numbers reported do not include coal within mine or lease areas, in areas containing mapped Wyodak-Anderson clinker, or in areas where the coal is extrapolated to be less than 2.5 ft thick. The resources of the Wyodak-Anderson coal zone are reported in Ellis and others (1998). A general description of how the resources were calculated is included in that report. The purpose of this report is to document in more detail some of the parameters and methods used, define our spatial data, compare resources calculated using different grid options and calculation methods, and explain the application of confidence limits to the resource calculation.

30 CFR 1206.452 - Coal subject to royalties-general provisions.

Code of Federal Regulations, 2012 CFR

2012-07-01

... 30 Mineral Resources 3 2012-07-01 2012-07-01 false Coal subject to royalties-general provisions... INTERIOR NATURAL RESOURCES REVENUE PRODUCT VALUATION Indian Coal § 1206.452 Coal subject to royalties—general provisions. (a) All coal (except coal unavoidably lost as determined by BLM pursuant to 43 CFR...

30 CFR 1206.253 - Coal subject to royalties-general provisions.

Code of Federal Regulations, 2011 CFR

2011-07-01

... 30 Mineral Resources 3 2011-07-01 2011-07-01 false Coal subject to royalties-general provisions..., DEPARTMENT OF THE INTERIOR Natural Resources Revenue PRODUCT VALUATION Federal Coal § 1206.253 Coal subject to royalties—general provisions. (a) All coal (except coal unavoidably lost as determined by BLM...

30 CFR 1206.452 - Coal subject to royalties-general provisions.

Code of Federal Regulations, 2013 CFR

2013-07-01

... 30 Mineral Resources 3 2013-07-01 2013-07-01 false Coal subject to royalties-general provisions... INTERIOR NATURAL RESOURCES REVENUE PRODUCT VALUATION Indian Coal § 1206.452 Coal subject to royalties—general provisions. (a) All coal (except coal unavoidably lost as determined by BLM pursuant to 43 CFR...

Coal and Energy.

ERIC Educational Resources Information Center

Bryant, Reba; And Others

This teaching unit explores coal as an energy resource. Goals, student objectives, background information, and activity options are presented for each major section. The sections are: (1) an introduction to coal (which describes how and where coal was formed and explains the types of coal); (2) the mining of coal (including the methods and ways of…

30 CFR 1206.452 - Coal subject to royalties-general provisions.

Code of Federal Regulations, 2014 CFR

2014-07-01

... 30 Mineral Resources 3 2014-07-01 2014-07-01 false Coal subject to royalties-general provisions... INTERIOR NATURAL RESOURCES REVENUE PRODUCT VALUATION Indian Coal § 1206.452 Coal subject to royalties—general provisions. (a) All coal (except coal unavoidably lost as determined by BLM pursuant to 43 CFR...

Fuel supply system and method for coal-fired prime mover

DOEpatents

Smith, William C.; Paulson, Leland E.

1995-01-01

A coal-fired gas turbine engine is provided with an on-site coal preparation and engine feeding arrangement. With this arrangement, relatively large dry particles of coal from an on-site coal supply are micro-pulverized and the resulting dry, micron-sized, coal particulates are conveyed by steam or air into the combustion chamber of the engine. Thermal energy introduced into the coal particulates during the micro-pulverizing step is substantially recovered since the so-heated coal particulates are fed directly from the micro-pulverizer into the combustion chamber.

Coal assessments and coal research in the Appalachian basin: Chapter D.4 in Coal and petroleum resources in the Appalachian basin: distribution, geologic framework, and geochemical character

USGS Publications Warehouse

Tewalt, Susan J.; Ruppert, Leslie F.; Ruppert, Leslie F.; Ryder, Robert T.

2014-01-01

State geological surveys are concentrating on mapping and correlating coal beds and coal zones and studying CBM potential and production. Both State surveys and the USGS are researching the potential for carbon dioxide sequestration in unmined coal beds and other geologic reservoirs. In addition, the State geological surveys continue their long-term collaboration with the USGS and provide coal stratigraphic data to the National Coal Resources Data System (NCRDS).

Characterization of Coal Porosity for Naturally Tectonically Stressed Coals in Huaibei Coal Field, China

PubMed Central

Li, Xiaoshi; Hou, Quanlin; Li, Zhuo; Wei, Mingming

2014-01-01

The enrichment of coalbed methane (CBM) and the outburst of gas in a coal mine are closely related to the nanopore structure of coal. The evolutionary characteristics of 12 coal nanopore structures under different natural deformational mechanisms (brittle and ductile deformation) are studied using a scanning electron microscope (SEM) and low-temperature nitrogen adsorption. The results indicate that there are mainly submicropores (2~5 nm) and supermicropores (<2 nm) in ductile deformed coal and mesopores (10~100 nm) and micropores (5~10 nm) in brittle deformed coal. The cumulative pore volume (V) and surface area (S) in brittle deformed coal are smaller than those in ductile deformed coal which indicates more adsorption space for gas. The coal with the smaller pores exhibits a large surface area, and coal with the larger pores exhibits a large volume for a given pore volume. We also found that the relationship between S and V turns from a positive correlation to a negative correlation when S > 4 m2/g, with pore sizes <5 nm in ductile deformed coal. The nanopore structure (<100 nm) and its distribution could be affected by macromolecular structure in two ways. Interconversion will occur among the different size nanopores especially in ductile deformed coal. PMID:25126601

Preliminary report on coal resources of the Wyodak-Anderson coal zone, Powder River Basin, Wyoming and Montana

USGS Publications Warehouse

Ellis, Margaret S.; Gunther, Gregory L.; Flores, Romeo M.; Ochs, Allen M.; Stricker, Gary D.; Roberts, Steven B.; Taber, Thomas T.; Bader, Lisa R.; Schuenemeyer, John H.

1998-01-01

The National Coal Resource Assessment (NCRA) project by the U.S. Geological Survey is designed to assess US coal with the greatest potential for development in the next 20 to 30 years. Coal in the Wyodak-Anderson (WA) coal zone in the Powder River Basin of Wyoming and Montana is plentiful, clean, and compliant with EPA emissions standards. This coal is considered to be very desirable for development for use in electric power generation. The purpose of this NCRA study was to compile all available data relating to the Wyodak- Anderson coal, correlate the beds that make up the WA coal zone, create digital files pertaining to the study area and the WA coal, and produce a variety of reports on various aspects of the assessed coal unit. This report contains preliminary calculations of coal resources for the WA coal zone and is one of many products of the NCRA study. Coal resource calculations in this report were produced using both public and confidential data from many sources. The data was manipulated using a variety of commercially available software programs and several custom programs. A general description of the steps involved in producing the resource calculations is described in this report.

Drivers for the renaissance of coal

PubMed Central

Steckel, Jan Christoph; Edenhofer, Ottmar; Jakob, Michael

2015-01-01

Coal was central to the industrial revolution, but in the 20th century it increasingly was superseded by oil and gas. However, in recent years coal again has become the predominant source of global carbon emissions. We show that this trend of rapidly increasing coal-based emissions is not restricted to a few individual countries such as China. Rather, we are witnessing a global renaissance of coal majorly driven by poor, fast-growing countries that increasingly rely on coal to satisfy their growing energy demand. The low price of coal relative to gas and oil has played an important role in accelerating coal consumption since the end of the 1990s. In this article, we show that in the increasingly integrated global coal market the availability of a domestic coal resource does not have a statistically significant impact on the use of coal and related emissions. These findings have important implications for climate change mitigation: If future economic growth of poor countries is fueled mainly by coal, ambitious mitigation targets very likely will become infeasible. Building new coal power plant capacities will lead to lock-in effects for the next few decades. If that lock-in is to be avoided, international climate policy must find ways to offer viable alternatives to coal for developing countries. PMID:26150491

Metalliferous coals of the Westphalian A Joggins Formation, Cumberland basin, Nova Scotia, Canada: Petrology, geochemistry, and palynology

USGS Publications Warehouse

Hower, J.C.; Calder, J.H.; Eble, C.F.; Scott, A.C.; Robertson, J.D.; Blanchard, L.J.

2000-01-01

Five coals of Westphalian A (early Middle Pennsylvanian) age were sampled from the Joggins Formation section exposed along Chignecto Bay at Joggins, Nova Scotia. Coal beds along the bay were mined beginning in the early 17th century, yet there have been few detailed published investigation of the coal beds of this classic section. The lowermost coal, the Upper Coal 28 (Upper Fundy), is a high-vitrinite coal with a spore assemblage dominated by arboreous lycopsid spores with tree ferns subdominant. The upper portions of the coal bed have the highest ratio of well-preserved to poorly-preserved telinite of any of the coals investigated. Coal 19 ('clam coal') has 88% total vitrinite but, unlike the Fundy coal bed, the telinite has a poor preservation ratio and half the total vitrinite population comprises gelocollinite and vitrodetrinite. The latter coal bed is directly overlain by a basin-wide limestone bed. The Lower Kimberly coal shows good preservation of vitrinite with relatively abundant telinite among the total vitrinite. The Middle Kimberly coal, which underlies the tetrapod-bearing lycopsid trees found by Lyell and Dawson in 1852, exhibits an upward decrease in arboreous lycopod spores and an upward increase in the tree fern spore Punctatisporites minutus. Telinite preservation increases upwards in the Middle Kimberly but overall is well below the preservation ratio of the Upper Fundy coal bed. The coals all have high sulfur contents, yielding up to 13.7% total sulfur for the lower lithotype of the Upper Fundy coal bed. The Kimberly coals are not only high in total and pyritic sulfur, but also have high concentrations of chalcophile elements. Zinc, ranging up to 15,000 ppm (ash basis), is present as sphalerite in fusain lumens. Arsenic and lead each exceed 6000 ppm (ash basis) in separate lithotypes of the Kimberly coals. Together these data are consistent with elevated pH in planar mires. The source of the elemental enrichment in this presumed continental section is enigmatic. (C) 2000 Elsevier Science B.V. All rights reserved.Five coals of Westphalian A (early Middle Pennsylvanian) age were sampled from the Joggins Formation section exposed along Chigneto Bay at Joggins, Nova Scotia. All the coals were found to have high sulfur contents. Overall, the data obtained are consistent with elevated pH in planar mires.

Thermal surface characteristics of coal fires 1 results of in-situ measurements

NASA Astrophysics Data System (ADS)

Zhang, Jianzhong; Kuenzer, Claudia

2007-12-01

Natural underground coal fires are fires in coal seams occurring subsurface. The fires are ignited through a process named spontaneous combustion, which occurs based on a natural reaction but is usually triggered through human interaction. Coal mining activities expose coal to the air. This leads to the exothermal oxidation of the carbon in the coal with the air's oxygen to CO 2 and - under certain circumstances - to spontaneous combustion. Coal fires occur in many countries world wide - however, currently the Chinese coal mining industry faces the biggest problems with coal fires. Coal fires destroy the valuable resource coal and furthermore lead to many environmental degradation phenomena such as the deterioration of surrounding vegetation, land subsidence and the emission of toxic gasses (CO, N 2O). They additionally contribute to the emission of green house relevant gasses such as CO 2 and CH 4 to the atmosphere. In this paper we present thermal characteristics of coal fires as measured in-situ during a field campaign to the Wuda coal fire area in south-central Inner Mongolia, China. Thermal characteristics include temperature anomaly measurements at the surface, spatial surface temperature profiles of fire areas and unaffected background areas, diurnal temperature profiles, and temperature measurements inside of coal fire induced cracks in the overlying bedrock. For all the measurements the effects of uneven solar heating through influences of slope and aspect are considered. Our findings show that coal fires result in strong or subtle thermal surface anomalies. Especially the latter can easily be influenced by heating of the surrounding background material through solar influences. Temperature variation of background rocks with different albedo, slope, aspect or vegetation cover can substantially influence the detectability of thermal anomalies. In the worst case coal fire related thermal anomalies can be completely masked by solar patterns during the daytime. Thus, night-time analysis is the most suitable for thermal anomaly mapping of underground coal fires, although this is not always feasible. The heat of underground coal fires only progresses very slowly through conduction in the rock material. Anomalies of coal fires completely covered by solid unfractured bedrock are very weak and were only measured during the night. The thermal pattern of underground coal fires manifested on the surface during the daytime is thus the pattern of cracks and vents, which occur due to the volume loss underground and which support radiation and convective energy transport of hot gasses. Inside coal fire temperatures can hardly be measured and can only be recorded if the glowing coal is exposed through a wider crack in the overlaying bedrock. Direct coal fire temperatures measured ranged between 233 °C and 854 °C. The results presented can substantially support the planning of thermal mapping campaigns, analyses of coal fire thermal anomalies in remotely sensed data, and can provide initial and boundary conditions for coal fire related numerical modeling. In a second paper named "Thermal Characteristics of Coal Fires 2: results of measurements on simulated coal fires" [ Zhang J., Kuenzer C., Tetzlaff A., Oettl D., Zhukov B., Wagner W., 2007. Thermal Characteristics of Coal Fires 2: Result of measurements on simulated coal fires. Accepted for publication at Journal of Applied Geophysics. doi:10.1016/j.jappgeo.2007.08.003] we report about thermal characteristics of simulated coal fires simulated under simplified conditions. The simulated set up allowed us to measure even more parameters under undisturbed conditions — especially inside fire temperatures. Furthermore we could demonstrate the differences between open surface coal fires and covered underground coal fires. Thermal signals of coal fires in near range thermal remotely sensed imagery from an observing tower and from an airplane are presented and discussed.

Lignite-plus-Biomass to Synthetic Jet Fuel with CO2 Capture and Storage: Design, Cost, and Greenhouse Gas Emissions Analysis for a Near-Term First-of-a-Kind Demonstration Project and Prospective Future Commercial Plants

DOE Office of Scientific and Technical Information (OSTI.GOV)

Greig, Chris; Larson, Eric; Kreutz, Thomas

We report on a 30-month design study for a first-of-a-kind (FOAK) demonstration plant that would be built at a site near Meridian, Mississippi, to coprocess lignite coal and woody biomass into jet fuel. The design uses an oxygen-blown TRIG™ gasifier developed by KBR and Southern Company. Fischer-Tropsch conversion of the syngas produces synthetic paraffinic kerosene (SPK) as the primary product, plus naphtha. Other co-products include electricity sold to the grid and CO2 sold for use in enhanced oil recovery (EOR). Previous studies have identified coprocessing of various coals and biomass with CO2 capture as promising options for cost-competitive production ofmore » low net lifecycle greenhouse gas (GHG) emissions synthetic fuels. The effort reported here goes beyond earlier studies in the level of detail in process design and cost estimation with the aim of improving the understanding of the economic prospects for lignite and woody biomass coprocessing systems. Key objectives in the design of the FOAK lignite/biomass-to-jet (LBJ) plant were to achieve net lifecycle GHG emissions for the SPK that are less than for conventional petroleum-derived jet fuel and to make process design and equipment selections such that the plant could be built and operated in the near term, e.g., before 2025. The process design was developed by researchers at Princeton University and the University of Queensland and validated by engineers at the WorleyParsons Group (WP). Commercial vendors provided design and cost estimates for several major plant components. Bare-erected capital costs and operating and maintenance costs were estimated by WP. The primary objective in building and operating the FOAK plant would be to demonstrate the technical viability of the LBJ concept as an essential first step toward launching commercial-scale plants in the longer term. With this in mind, the project team developed a set of principles to help guide the process design: the total plant cost should be less than $2 billion (to limit investment risk); the level of input biomass should be both proportionally significant to reflect biomass/lignite co-gasification and sufficient to achieve GHG emissions goals; process design decisions and vendor/equipment selections should prioritize the likelihood of technical success over minimizing the cost of jet fuel production. The resulting FOAK plant design capacity is 1,551 metric t/d (45.5% moisture) lignite and 556 t/d (43.3% moisture) biomass, for a total input of 295 MWHHV, of which 25% is biomass. The design output is 1,252 actual barrels per day of liquids, of which 80% is SPK (62.3 MWLHV) and 20% is naphtha (13.9 MWLHV). It exports 15 MWe of electricity after satisfying a 38 MWe onsite auxiliary load. Additional products are 1,326 t/d of pressurized pipeline-quality CO2 and 49 t/day of sulfuric acid (93 wt% H2SO4). With thinnings from sustainably-managed southern pine plantations as the biomass, and with captured CO2 stored underground via EOR, the net lifecycle emissions for the SPK product are estimated to be about one-quarter of those for petroleum-derived jet fuel. The bare-erected cost (BEC) estimated by WP for this plant is $588 million (2015$). The authors’ best estimate of total plant cost (TPC) is $1,230 million, arrived at by assuming engineering, procurement and construction management services (20% of BEC), process 5 contingencies (35% of BEC), and project contingencies (35% of the sum of all other costs, i.e., 35% of 1.55xBEC). Not surprisingly, an annual discounted cash flow (DCF) analysis determined that it would be impossible to generate a positive net present value (NPV) over a wide range in key input assumptions. An SPK production cost subsidy of nearly $400/bbl over a 20-year plant life would be required to achieve zero NPV under a baseline set of assumptions (including 3% real weighted average cost of capital and a levelized crude oil price of $80/bbl). Alternatively, a capital grant in excess of the TPC value would also achieve zero NPV. The poor financial results reflect the small scale of the plant, the design principle to prioritize technical success, the levels of contingencies appropriate for the relatively early stage of project development, and the first-of-a-kind nature of the plant. Technology innovations, learning via construction and operating experience, alternative plant configurations, and larger scale should improve economics of future plants. To help understand these prospects, a preliminary analysis of Nth-of-a-kind (NOAK) plants was developed, but with the limitation that plants would use only equipment components that for the most part are already commercial today: consideration of advanced, not-yet-commercial technologies and of R&D-driven improvements in existing technologies were beyond the scope of this analysis. The analysis found that a variety of NOAK plant designs that coprocess lignite and woody biomass to make jet fuel are unlikely to be economically competitive without subsidy even in the presence of a high future carbon tax or equivalent greenhouse gas mitigation policy. This conclusion applies to process configurations and input biomass/lignite ratios that result in net GHG emissions as high as those for petroleum-derived jet fuel and as low as zero. In contrast, encouraging results were found for plants processing only biomass. The economics of these “BECCS” plants (biomass energy with CCS) improve dramatically with the strength of carbon mitigation policies because of their strongly negative net GHG emissions. These findings do not imply that coal/biomass coprocessing strategies for making synfuels with CCS are not economically promising – only that, in the case of lignite, much more than a 25% biomass coprocessing rate would be needed. However, our analysis shows that all such systems are unlikely to be economic in the absence of a strong carbon mitigation policy. Future R&D driven technological innovations could modify this conclusion. Among other R&D priorities, an emphasis on better understanding and reducing plant auxiliary loads is warranted.« less

Distribution of trace elements in selected pulverized coals as a function of particle size and density

USGS Publications Warehouse

Senior, C.L.; Zeng, T.; Che, J.; Ames, M.R.; Sarofim, A.F.; Olmez, I.; Huggins, Frank E.; Shah, N.; Huffman, G.P.; Kolker, A.; Mroczkowski, S.; Palmer, C.; Finkelman, R.

2000-01-01

Trace elements in coal have diverse modes of occurrence that will greatly influence their behavior in many coal utilization processes. Mode of occurrence is important in determining the partitioning during coal cleaning by conventional processes, the susceptibility to oxidation upon exposure to air, as well as the changes in physical properties upon heating. In this study, three complementary methods were used to determine the concentrations and chemical states of trace elements in pulverized samples of four US coals: Pittsburgh, Illinois No. 6, Elkhorn and Hazard, and Wyodak coals. Neutron Activation Analysis (NAA) was used to measure the absolute concentration of elements in the parent coals and in the size- and density-fractionated samples. Chemical leaching and X-ray absorption fine structure (XAFS) spectroscopy were used to provide information on the form of occurrence of an element in the parent coals. The composition differences between size-segregated coal samples of different density mainly reflect the large density difference between minerals, especially pyrite, and the organic portion of the coal. The heavy density fractions are therefore enriched in pyrite and the elements associated with pyrite, as also shown by the leaching and XAFS methods. Nearly all the As is associated with pyrite in the three bituminous coals studied. The sub-bituminous coal has a very low content of pyrite and arsenic; in this coal arsenic appears to be primarily organically associated. Selenium is mainly associated with pyrite in the bituminous coal samples. In two bituminous coal samples, zinc is mostly in the form of ZnS or associated with pyrite, whereas it appears to be associated with other minerals in the other two coals. Zinc is also the only trace element studied that is significantly more concentrated in the smaller (45 to 63 ??m) coal particles.

Distribution of potentially hazardous trace elements in coals from Shanxi province, China

USGS Publications Warehouse

Zhang, J.Y.; Zheng, C.G.; Ren, D.Y.; Chou, C.-L.; Liu, J.; Zeng, R.-S.; Wang, Z.P.; Zhao, F.H.; Ge, Y.T.

2004-01-01

Shanxi province, located in the center of China, is the biggest coal base of China. There are five coal-forming periods in Shanxi province: Late Carboniferous (Taiyuan Formation), Early Permian (Shanxi Formation), Middle Jurassic (Datong Formation), Tertiary (Taxigou Formation), and Quaternary. Hundred and ten coal samples and a peat sample from Shanxi province were collected and the contents of 20 potentially hazardous trace elements (PHTEs) (As, B, Ba, Cd, Cl, Co, Cr, Cu, F, Hg, Mn, Mo, Ni, Pb, Sb, Se, Th, U, V and Zn) in these samples were determined by instrumental neutron activation analysis, atomic absorption spectrometry, cold-vapor atomic absorption spectrometry, ion chromatography spectrometry, and wet chemical analysis. The result shows that the brown coals are enriched in As, Ba, Cd, Cr, Cu, F and Zn compared with the bituminous coals and anthracite, whereas the bituminous coals are enriched in B, Cl, Hg, and the anthracite is enriched in Cl, Hg, U and V. A comparison with world averages and crustal abundances (Clarke values) shows that the Quaternary peat is highly enriched in As and Mo, Tertiary brown coals are highly enriched in Cd, Middle Jurassic coals, Early Permian coals and Late Carboniferous coals are enriched in Hg. According to the coal ranks, the bituminous coals are highly enriched in Hg, whereas Cd, F and Th show low enrichments, and the anthracite is also highly enriched in Hg and low enrichment in Th. The concentrations of Cd, F, Hg and Th in Shanxi coals are more than world arithmetic means of concentrations for the corresponding elements. Comparing with the United States coals, Shanxi coals show higher concentrations of Cd, Hg, Pb, Se and Th. Most of Shanxi coals contain lower concentrations of PHTEs. ?? 2004 Elsevier Ltd. All rights reserved.

An investigation of the role of water on retrograde/condensation reactions and enhanced liquefaction yields. Quarterly progress report, January 1, 1994--March 31, 1994

DOE Office of Scientific and Technical Information (OSTI.GOV)

Miknis, F.P.; Netzel, D.A.

The results of coal swelling measurements using 1,4-dioxane as the swelling reagent for premoisturized coals (raw) and coal dried thermally, chemically, and with microwave radiation are presented. An increase in the swelling ratio relative to raw coal indicates a decrease in the amount of cross-linking in the coal. Conversely, a decrease in the ratio indicates an increase in cross-linking. The extent of cross-linking (as measured by 1,4-dioxane) for Texas, Black Thunder, and Eagle Butte Coals are about the same. Illinois {number_sign}6 coal appears to have less cross-linking relative to the other three coals. These results are expected on the basismore » of coal rank. The increase in cross linking is most pronounced for coals dried thermally and with microwave radiation. A decrease in the swelling ratios for all four coals suggests that cross-linking had occurred possibly due to partial devolatilization process. However, low temperature, chemical dehydration of the coals causes only a small or no change in the internal structure for Texas and Illinois {number_sign}6 coals whereas a significant decrease in the cross-linking structure for the Black Thunder and Eagle Butte coals is observed. It is possible that the solvent (CH{sub 3}OH) and products resulting from the chemical dehydrating (acetone and methanol) occupy the surface sites that water had before the reaction and thus preventing cross-linking to occur. These reagents can also promote swelling of coals and may account for some of the decrease in the cross-linking of the coal structure observed for the chemically dried coals.« less

Tertiary coals in South Texas: Anomalous cannel-like coals of Webb County (Claiborne Group, Eocene) and lignites of Atascosa County (Jackson Group, Eocene) - Geologic setting, character, source-rock and coal-bed methane potential

USGS Publications Warehouse

Warwick, Peter D.; Aubourg, Claire E.; Willett, Jason C.

1999-01-01

The coal-bearing Gulf of Mexico Coastal Plain of North America contains a variety of depositional settings and coal types. The coal-bearing region extends westward from Alabama and Mississippi, across Louisiana to the northern part of the Mississippi Embayment, and then southward to eastern Arkansas, Texas and northern Mexico (fig. 1). Most of the coal currently mined in Texas is lignite from the upper part of the Wilcox Group (Paleocene-Eocene) and, in Louisiana, lignite is mined from the lower part of the Wilcox (fig. 2). Gulf Coast coal is used primarily as fuel for mine-mouth electric plants. On this field trip we will visit the only two non-Wilcox coal mining intervals in the Texas-Louisiana Coastal Plain; these include the San Pedro - Santo Tomas bituminous cannel-like coal zone of the Eocene Claiborne Group, and the San Miguel lignite coal zone of the Eocene Jackson Group (fig. 2). Other coal-mining areas in northern Mexico are currently producing bituminous coal from the Cretaceous Olmos Formation of the Navaro Group (fig. 2).

Fungal biodegradation of hard coal by a newly reported isolate, Neosartorya fischeri.

PubMed

Igbinigie, Eric E; Aktins, Simon; van Breugel, Yvonne; van Dyke, Susan; Davies-Coleman, Michael T; Rose, Peter D

2008-11-01

Cynodon dactylon (Bermuda grass) has been observed to grow sporadically on the surface of coal dumps in the Witbank coal mining area of South Africa. Root zone investigation indicated that a number of fungal species may be actively involved in the biodegradation of hard coal, thus enabling the survival of the plant, through mutualistic interaction, in this extreme environment. In an extensive screening program of over two thousand samples, the Deuteromycete, Neosartorya fischeri, was isolated and identified. The biodegradation of coal by N. fischeri was tested in flask studies and in a perfusion fixed-bed bioreactor used to simulate the coal dump environment. The performance of N. fischeri was compared to Phanaerochaete chrysosporium and Trametes (Polyporus) versicolor, previously described in coal biodegradation studies. Fourier transform infrared spectrometry and pyrolysis gas chromatography mass spectrometry of the biodegradation product indicated oxidation of the coal surface and nitration of the condensed aromatic structures of the coal macromolecule as possible reaction mechanisms in N. fischeri coal biodegradation. This is a first report of N. fischeri-mediated coal biodegradation and, in addition to possible applications in coal biotechnology, the findings may enable development of sustainable technologies in coal mine rehabilitation.

Chemical analyses of coal, coal-associated rocks and coal combustion products collected for the National Coal Quality Inventory

USGS Publications Warehouse

Hatch, Joseph R.; Bullock, John H.; Finkelman, Robert B.

2006-01-01

In 1999, the USGS initiated the National Coal Quality Inventory (NaCQI) project to address a need for quality information on coals that will be mined during the next 20-30 years. At the time this project was initiated, the publicly available USGS coal quality data was based on samples primarily collected and analyzed between 1973 and 1985. The primary objective of NaCQI was to create a database containing comprehensive, accurate and accessible chemical information on the quality of mined and prepared United States coals and their combustion byproducts. This objective was to be accomplished through maintaining the existing publicly available coal quality database, expanding the database through the acquisition of new samples from priority areas, and analysis of the samples using updated coal analytical chemistry procedures. Priorities for sampling include those areas where future sources of compliance coal are federally owned. This project was a cooperative effort between the U.S. Geological Survey (USGS), State geological surveys, universities, coal burning utilities, and the coal mining industry. Funding support came from the Electric Power Research Institute (EPRI) and the U.S. Department of Energy (DOE).

Hardened, environmentally disposable composite granules of coal cleaning refuse, coal combustion waste, and other wastes, and method preparing the same

DOEpatents

Burnet, George; Gokhale, Ashok J.

1990-07-10

A hardened, environmentally inert and disposable composite granule of coal cleaning refuse and coal combustion waste, and method for producing the same, wherein the coal combustion waste is first granulated. The coal cleaning refuse is pulverized into fine particles and is then bound, as an outer layer, to the granulated coal combustion waste granules. This combination is then combusted and sintered. After cooling, the combination results in hardened, environmentally inert and disposable composite granules having cores of coal combustion waste, and outer shells of coal cleaning refuse. The composite particles are durable and extremely resistant to environmental and chemical forces.

Hardened, environmentally disposable composite granules of coal cleaning refuse, coal combustion waste, and other wastes, and method preparing the same

DOEpatents

Burnet, G.; Gokhale, A.J.

1990-07-10

A hardened, environmentally inert and disposable composite granule of coal cleaning refuse and coal combustion waste and method for producing the same are disclosed, wherein the coal combustion waste is first granulated. The coal cleaning refuse is pulverized into fine particles and is then bound, as an outer layer, to the granulated coal combustion waste granules. This combination is then combusted and sintered. After cooling, the combination results in hardened, environmentally inert and disposable composite granules having cores of coal combustion waste, and outer shells of coal cleaning refuse. The composite particles are durable and extremely resistant to environmental and chemical forces. 3 figs.

Nitrogen in Chinese coals

USGS Publications Warehouse

Wu, D.; Lei, J.; Zheng, B.; Tang, X.; Wang, M.; Hu, Jiawen; Li, S.; Wang, B.; Finkelman, R.B.

2011-01-01

Three hundred and six coal samples were taken from main coal mines of twenty-six provinces, autonomous regions, and municipalities in China, according to the resource distribution and coal-forming periods as well as the coal ranks and coal yields. Nitrogen was determined by using the Kjeldahl method at U. S. Geological Survey (USGS), which exhibit a normal frequency distribution. The nitrogen contents of over 90% Chinese coal vary from 0.52% to 1.41% and the average nitrogen content is recommended to be 0.98%. Nitrogen in coal exists primarily in organic form. There is a slight positive relationship between nitrogen content and coal ranking. ?? 2011 Science Press, Institute of Geochemistry, CAS and Springer Berlin Heidelberg.

Ferromagnetic and superparamagnetic contamination in pulverized coal

USGS Publications Warehouse

Senftle, F.E.; Thorpe, A.N.; Alexander, C.C.; Finkelman, R.B.

1982-01-01

Although no significant major-element contamination is introduced by grinding coal in a steel pulverizer, abraded steel particles can conceivably affect the magnetic properties of pulverized coal. Magnetic and scanning-electron-microscope analyses of pulverized coal and coal fragments from the Herrin No. 6 seam in Illinois showed ferromagnetic and superparamagnetic contamination from the grinder. Significant changes in the magnetic properties of the coal were noted, indicating a total steel contamination of approximately 0.02 wt%. When coal samples were vibrated in the magnetic field of the vibrating-sample magnetometer, the superparamagnetic steel particles moved through the pulverized coal, and participated in the formation of multidomain clusters that in turn substantially affected the magnetization of the coal. ?? 1982.

Self-Scrubbing Coal -- an integrated approach to clean air

DOE Office of Scientific and Technical Information (OSTI.GOV)

Harrison, K.E.

1997-12-31

Carefree Coal is coal cleaned in a proprietary dense-media cyclone circuit, using ultrafine magnetite slurries, to remove noncombustible material, including up to 90% of the pyritic sulfur. Deep cleaning alone, however, cannot produce a compliance fuel from coals with high organic sulfur contents. In these cases, Self-Scrubbing Coal will be produced. Self-Scrubbing Coal is produced in the same manner as Carefree Coal except that the finest fraction of product from the cleaning circuit is mixed with limestone-based additives and briquetted. The reduced ash content of the deeply-cleaned coal will permit the addition of relatively large amounts of sorbent without exceedingmore » boiler ash specifications or overloading electrostatic precipitators. This additive reacts with sulfur dioxide (SO{sub 2}) during combustion of the coal to remove most of the remaining sulfur. Overall, sulfur reductions in the range of 80--90% are achieved. After nearly 5 years of research and development of a proprietary coal cleaning technology coupled with pilot-scale validation studies of this technology and pilot-scale combustion testing of Self-Scrubbing Coal, Custom Coals Corporation organized a team of experts to prepare a proposal in response to DOE`s Round IV Program Opportunity Notice for its Clean Coal Technology Program under Public Law 101-121 and Public Law 101-512. The main objective of the demonstration project is the production of a coal fuel that will result in up to 90% reduction in sulfur emissions from coal-fired boilers at a cost competitive advantage over other technologies designed to accomplish the same sulfur emissions and over naturally occurring low sulfur coals.« less

DOE Office of Scientific and Technical Information (OSTI.GOV)

Nabeel, A.; Khan, T.A.; Sharma, D.K.

The use of low-grade coal in thermal power stations is leading to environmental pollution due to the generation of large amounts of fly ash, bottom ash, and CO{sub 2} besides other pollutants. It is therefore important to clean the coal before using it in thermal power stations, steel plants, or cement industries etc. Physical beneficiation of coal results in only limited cleaning of coal. The increasing environmental pollution problems from the use of coal have led to the development of clean coal technologies. In fact, the clean use of coal requires the cleaning of coal to ultra low ash contents,more » keeping environmental norms and problems in view and the ever-growing need to increase the efficiency of coal-based power generation. Therefore this requires the adaptation of chemical cleaning techniques for cleaning the coal to obtain ultra clean coal having ultra low ash contents. Presently the reaction conditions for chemical demineralization of low-grade coal using 20% aq NaOH treatment followed by 10% H{sub 2}SO{sub 4} leaching under reflux conditions have been optimized. In order to reduce the concentration of alkali and acid used in this process of chemical demineralization of low-grade coals, stepwise, i.e., three step process of chemical demineralization of coal using 1% or 5% aq NaOH treatment followed by 1% or 5% H{sub 2}SO{sub 4} leaching has been developed, which has shown good results in demineralization of low-grade coals. In order to conserve energy, the alkali-acid leaching of coal was also carried out at room temperature, which gave good results.« less

Regulation of coal polymer degradation by fungi. Tenth Quartery report, October 1996--December 1996

DOE Office of Scientific and Technical Information (OSTI.GOV)

Irvine, R.L.; Bumpus, J.A.

1997-01-28

It has long been known that low rank coal such as leonardite can be solubilized by strong base (>pH 12). Recent discoveries have also shown that leonardite is solubilized by Lewis bases at considerably lower pH values and by fungi that secrete certain Lewis bases (i.e., oxalate ion). During the current reporting period we have studied the ability of a strong base (sodium hydroxide, pH 12), and two fungi, Phanerochaete chrysosporium and Trametes versicolor, to solubilize Argonne Premium Coals. In general, Argonne Premium Coals were relatively resistant to base mediated solubilization. However, when these coals were preoxidized (150{degrees}C for sevenmore » days), substantial amounts of several coals were solubilized. Most affected were the Lewiston-Stockton bituminous coal, the Beulah-Zap lignite, the Wyodak-Anderson subbituminous coal and the Blind Canyon bituminous coal. Argonne Premium Coals were previously shown by us to be relatively resistant to solubilization by sodium oxalate. When preoxidized coals were treated with sodium oxalate, only the Beulah-Zap lignite was substantially solubilized. Although very small amounts of the other preoxidized coals were solubilized by treatment with oxalate, the small amount of solubilization that did take place was generally increased relative to that observed for coals that were not preoxidized. None of the Argonne Premium Coals were solubilized by P. chrysosporium or T. versicolor. Of considerable interest, however, is the observation that P. chrysosporium and T. versicolor mediated extensive solubilization of Lewiston-Stockton bituminous coal, the Beulah-Zap lignite and the Wyodak-Anderson subbituminous coal.« less

The U.S. Energy Dilemma: The Gap between Today’s Requirements and Tomorrow’s Potential.

DTIC Science & Technology

1973-07-01

Possible Solutions . ........ .. 142 Use of Low-Sulfur Coal ................ 43 Flue - Gas Desulfurization ................ 43 Coal Cleaning...1) use of low-sulfur coal, (2) flue - gas desulfurization , (3) coal cleaning, (4) coal refining, and (5) coal conversion. Use of Low-Sulfur Coal The...to the same point (Skillings Mining Rev., 1973). Flue - Gas Desulfurization With standards based on sulfur dioxide emissions per million Btu, rather than

30 CFR 1206.464 - Value enhancement of marketable coal.

Code of Federal Regulations, 2012 CFR

2012-07-01

... 30 Mineral Resources 3 2012-07-01 2012-07-01 false Value enhancement of marketable coal. 1206.464... RESOURCES REVENUE PRODUCT VALUATION Indian Coal § 1206.464 Value enhancement of marketable coal. If, prior to use, sale, or other disposition, the lessee enhances the value of coal after the coal has been...

30 CFR 1206.459 - Allocation of washed coal.

Code of Federal Regulations, 2013 CFR

2013-07-01

... 30 Mineral Resources 3 2013-07-01 2013-07-01 false Allocation of washed coal. 1206.459 Section... RESOURCES REVENUE PRODUCT VALUATION Indian Coal § 1206.459 Allocation of washed coal. (a) When coal is subjected to washing, the washed coal must be allocated to the leases from which it was extracted. (b) When...

30 CFR 1206.464 - Value enhancement of marketable coal.

Code of Federal Regulations, 2014 CFR

2014-07-01

... 30 Mineral Resources 3 2014-07-01 2014-07-01 false Value enhancement of marketable coal. 1206.464... RESOURCES REVENUE PRODUCT VALUATION Indian Coal § 1206.464 Value enhancement of marketable coal. If, prior to use, sale, or other disposition, the lessee enhances the value of coal after the coal has been...

78 FR 50447 - Agency Information Collection Activities; Submission for OMB Review; Comment Request; Cleanup...

Federal Register 2010, 2011, 2012, 2013, 2014

2013-08-19

... for OMB Review; Comment Request; Cleanup Program for Accumulations of Coal and Float Coal Dusts, Loose Coal, and Other Combustibles ACTION: Notice. SUMMARY: The Department of Labor (DOL) is submitting the... (ICR) proposal; titled, ``Cleanup Program for Accumulations of Coal and Float Coal Dusts, Loose Coal...

30 CFR 75.1709 - Accumulations of methane and coal dust on surface coal-handling facilities.

Code of Federal Regulations, 2013 CFR

2013-07-01

... 30 Mineral Resources 1 2013-07-01 2013-07-01 false Accumulations of methane and coal dust on surface coal-handling facilities. 75.1709 Section 75.1709 Mineral Resources MINE SAFETY AND HEALTH ADMINISTRATION, DEPARTMENT OF LABOR COAL MINE SAFETY AND HEALTH MANDATORY SAFETY STANDARDS-UNDERGROUND COAL MINES...

30 CFR 206.464 - Value enhancement of marketable coal.

Code of Federal Regulations, 2010 CFR

2010-07-01

... 30 Mineral Resources 2 2010-07-01 2010-07-01 false Value enhancement of marketable coal. 206.464... MANAGEMENT PRODUCT VALUATION Indian Coal § 206.464 Value enhancement of marketable coal. If, prior to use, sale, or other disposition, the lessee enhances the value of coal after the coal has been placed in...

30 CFR 1206.459 - Allocation of washed coal.

Code of Federal Regulations, 2012 CFR

2012-07-01

... 30 Mineral Resources 3 2012-07-01 2012-07-01 false Allocation of washed coal. 1206.459 Section... RESOURCES REVENUE PRODUCT VALUATION Indian Coal § 1206.459 Allocation of washed coal. (a) When coal is subjected to washing, the washed coal must be allocated to the leases from which it was extracted. (b) When...

30 CFR 1206.253 - Coal subject to royalties-general provisions.

Code of Federal Regulations, 2014 CFR

2014-07-01

... 30 Mineral Resources 3 2014-07-01 2014-07-01 false Coal subject to royalties-general provisions... INTERIOR NATURAL RESOURCES REVENUE PRODUCT VALUATION Federal Coal § 1206.253 Coal subject to royalties—general provisions. (a) All coal (except coal unavoidably lost as determined by BLM under 43 CFR part 3400...

30 CFR 206.265 - Value enhancement of marketable coal.

Code of Federal Regulations, 2010 CFR

2010-07-01

... 30 Mineral Resources 2 2010-07-01 2010-07-01 false Value enhancement of marketable coal. 206.265... MANAGEMENT PRODUCT VALUATION Federal Coal § 206.265 Value enhancement of marketable coal. If, prior to use, sale, or other disposition, the lessee enhances the value of coal after the coal has been placed in...

30 CFR 1206.260 - Allocation of washed coal.

Code of Federal Regulations, 2011 CFR

2011-07-01

... 30 Mineral Resources 3 2011-07-01 2011-07-01 false Allocation of washed coal. 1206.260 Section... INTERIOR Natural Resources Revenue PRODUCT VALUATION Federal Coal § 1206.260 Allocation of washed coal. (a) When coal is subjected to washing, the washed coal must be allocated to the leases from which it was...

Desulfurizing Coal By Chlorinolysis and Hydrogenation

NASA Technical Reports Server (NTRS)

Kalvinskas, J. J.; Rohatgi, N. K.

1983-01-01

85 percent of organic and pyritic sulfur in coal removed by combination of chlorinolysis and hydrogeneration. Coal is fed to hydrogenator after chlorination. Coal flows against hydrogen current increasing mixing and reducing hydrogen consumption. Excess hydrogen is recovered from gaseous reaction products. Product coal contained 62.5 percent less total sulfur than same coal after chlorination.

30 CFR 75.1709 - Accumulations of methane and coal dust on surface coal-handling facilities.

Code of Federal Regulations, 2012 CFR

2012-07-01

... 30 Mineral Resources 1 2012-07-01 2012-07-01 false Accumulations of methane and coal dust on surface coal-handling facilities. 75.1709 Section 75.1709 Mineral Resources MINE SAFETY AND HEALTH ADMINISTRATION, DEPARTMENT OF LABOR COAL MINE SAFETY AND HEALTH MANDATORY SAFETY STANDARDS-UNDERGROUND COAL MINES...

30 CFR 1206.260 - Allocation of washed coal.

Code of Federal Regulations, 2014 CFR

2014-07-01

... 30 Mineral Resources 3 2014-07-01 2014-07-01 false Allocation of washed coal. 1206.260 Section... RESOURCES REVENUE PRODUCT VALUATION Federal Coal § 1206.260 Allocation of washed coal. (a) When coal is subjected to washing, the washed coal must be allocated to the leases from which it was extracted. (b) When...

30 CFR 206.452 - Coal subject to royalties-general provisions.

Code of Federal Regulations, 2010 CFR

2010-07-01

... 30 Mineral Resources 2 2010-07-01 2010-07-01 false Coal subject to royalties-general provisions... MINERALS REVENUE MANAGEMENT PRODUCT VALUATION Indian Coal § 206.452 Coal subject to royalties—general provisions. (a) All coal (except coal unavoidably lost as determined by BLM pursuant to 43 CFR group 3400...

30 CFR 206.253 - Coal subject to royalties-general provisions.

Code of Federal Regulations, 2010 CFR

2010-07-01

... 30 Mineral Resources 2 2010-07-01 2010-07-01 false Coal subject to royalties-general provisions... MINERALS REVENUE MANAGEMENT PRODUCT VALUATION Federal Coal § 206.253 Coal subject to royalties—general provisions. (a) All coal (except coal unavoidably lost as determined by BLM under 43 CFR part 3400) from a...

30 CFR 1206.253 - Coal subject to royalties-general provisions.

Code of Federal Regulations, 2012 CFR

2012-07-01

... 30 Mineral Resources 3 2012-07-01 2012-07-01 false Coal subject to royalties-general provisions... INTERIOR NATURAL RESOURCES REVENUE PRODUCT VALUATION Federal Coal § 1206.253 Coal subject to royalties—general provisions. (a) All coal (except coal unavoidably lost as determined by BLM under 43 CFR part 3400...

30 CFR 1206.265 - Value enhancement of marketable coal.

Code of Federal Regulations, 2014 CFR

2014-07-01

... 30 Mineral Resources 3 2014-07-01 2014-07-01 false Value enhancement of marketable coal. 1206.265... RESOURCES REVENUE PRODUCT VALUATION Federal Coal § 1206.265 Value enhancement of marketable coal. If, prior to use, sale, or other disposition, the lessee enhances the value of coal after the coal has been...

30 CFR 75.1709 - Accumulations of methane and coal dust on surface coal-handling facilities.

Code of Federal Regulations, 2011 CFR

2011-07-01

... 30 Mineral Resources 1 2011-07-01 2011-07-01 false Accumulations of methane and coal dust on surface coal-handling facilities. 75.1709 Section 75.1709 Mineral Resources MINE SAFETY AND HEALTH ADMINISTRATION, DEPARTMENT OF LABOR COAL MINE SAFETY AND HEALTH MANDATORY SAFETY STANDARDS-UNDERGROUND COAL MINES...

30 CFR 1206.459 - Allocation of washed coal.

Code of Federal Regulations, 2011 CFR

2011-07-01

... 30 Mineral Resources 3 2011-07-01 2011-07-01 false Allocation of washed coal. 1206.459 Section... INTERIOR Natural Resources Revenue PRODUCT VALUATION Indian Coal § 1206.459 Allocation of washed coal. (a) When coal is subjected to washing, the washed coal must be allocated to the leases from which it was...

30 CFR 1206.265 - Value enhancement of marketable coal.

Code of Federal Regulations, 2012 CFR

2012-07-01

... 30 Mineral Resources 3 2012-07-01 2012-07-01 false Value enhancement of marketable coal. 1206.265... RESOURCES REVENUE PRODUCT VALUATION Federal Coal § 1206.265 Value enhancement of marketable coal. If, prior to use, sale, or other disposition, the lessee enhances the value of coal after the coal has been...

30 CFR 1206.265 - Value enhancement of marketable coal.

Code of Federal Regulations, 2013 CFR

2013-07-01

... 30 Mineral Resources 3 2013-07-01 2013-07-01 false Value enhancement of marketable coal. 1206.265... RESOURCES REVENUE PRODUCT VALUATION Federal Coal § 1206.265 Value enhancement of marketable coal. If, prior to use, sale, or other disposition, the lessee enhances the value of coal after the coal has been...

30 CFR 75.1709 - Accumulations of methane and coal dust on surface coal-handling facilities.

Code of Federal Regulations, 2014 CFR

2014-07-01

... 30 Mineral Resources 1 2014-07-01 2014-07-01 false Accumulations of methane and coal dust on surface coal-handling facilities. 75.1709 Section 75.1709 Mineral Resources MINE SAFETY AND HEALTH ADMINISTRATION, DEPARTMENT OF LABOR COAL MINE SAFETY AND HEALTH MANDATORY SAFETY STANDARDS-UNDERGROUND COAL MINES...

30 CFR 1206.452 - Coal subject to royalties-general provisions.

Code of Federal Regulations, 2011 CFR

2011-07-01

... 30 Mineral Resources 3 2011-07-01 2011-07-01 false Coal subject to royalties-general provisions..., DEPARTMENT OF THE INTERIOR Natural Resources Revenue PRODUCT VALUATION Indian Coal § 1206.452 Coal subject to royalties—general provisions. (a) All coal (except coal unavoidably lost as determined by BLM pursuant to 43...

30 CFR 1206.260 - Allocation of washed coal.

Code of Federal Regulations, 2012 CFR

2012-07-01

... 30 Mineral Resources 3 2012-07-01 2012-07-01 false Allocation of washed coal. 1206.260 Section... RESOURCES REVENUE PRODUCT VALUATION Federal Coal § 1206.260 Allocation of washed coal. (a) When coal is subjected to washing, the washed coal must be allocated to the leases from which it was extracted. (b) When...

30 CFR 1206.253 - Coal subject to royalties-general provisions.

Code of Federal Regulations, 2013 CFR

2013-07-01

... 30 Mineral Resources 3 2013-07-01 2013-07-01 false Coal subject to royalties-general provisions... INTERIOR NATURAL RESOURCES REVENUE PRODUCT VALUATION Federal Coal § 1206.253 Coal subject to royalties—general provisions. (a) All coal (except coal unavoidably lost as determined by BLM under 43 CFR part 3400...

Attitudes toward Women Coal Miners in an Appalachian Coal Community.

ERIC Educational Resources Information Center

Trent, Roger B.; Stout-Wiegand, Nancy

1987-01-01

In a coal mining community, a survey revealed that the level of negative sentiment toward women coal miners was substantial and varied by gender role. Male coal miners were negative toward female co-workers, but they supported women's right to coal mine jobs, while female homemakers did not. (Author/CH)

30 CFR 1206.464 - Value enhancement of marketable coal.

Code of Federal Regulations, 2013 CFR

2013-07-01

... 30 Mineral Resources 3 2013-07-01 2013-07-01 false Value enhancement of marketable coal. 1206.464... RESOURCES REVENUE PRODUCT VALUATION Indian Coal § 1206.464 Value enhancement of marketable coal. If, prior to use, sale, or other disposition, the lessee enhances the value of coal after the coal has been...

30 CFR 1206.459 - Allocation of washed coal.

Code of Federal Regulations, 2014 CFR

2014-07-01

... 30 Mineral Resources 3 2014-07-01 2014-07-01 false Allocation of washed coal. 1206.459 Section... RESOURCES REVENUE PRODUCT VALUATION Indian Coal § 1206.459 Allocation of washed coal. (a) When coal is subjected to washing, the washed coal must be allocated to the leases from which it was extracted. (b) When...

30 CFR 1206.260 - Allocation of washed coal.

Code of Federal Regulations, 2013 CFR

2013-07-01

... 30 Mineral Resources 3 2013-07-01 2013-07-01 false Allocation of washed coal. 1206.260 Section... RESOURCES REVENUE PRODUCT VALUATION Federal Coal § 1206.260 Allocation of washed coal. (a) When coal is subjected to washing, the washed coal must be allocated to the leases from which it was extracted. (b) When...

Simulated coal spill causes mortality and growth inhibition in tropical marine organisms

PubMed Central

Berry, Kathryn L. E.; Hoogenboom, Mia O.; Flores, Florita; Negri, Andrew P.

2016-01-01

Coal is a principal fossil fuel driving economic and social development, and increases in global coal shipments have paralleled expansion of the industry. To identify the potential harm associated with chronic marine coal contamination, three taxa abundant in tropical marine ecosystems (the coral Acropora tenuis, the reef fish Acanthochromis polyacanthus and the seagrass Halodule uninervis) were exposed to five concentrations (0–275 mg coal l−1) of suspended coal dust (<63 μm) over 28 d. Results demonstrate that chronic coal exposure can cause considerable lethal effects on corals, and reductions in seagrass and fish growth rates. Coral survivorship and seagrass growth rates were inversely related to increasing coal concentrations (≥38 mg coal l−1) and effects increased between 14 and 28 d, whereas fish growth rates were similarly depressed at all coal concentrations tested. This investigation provides novel insights into direct coal impacts on key tropical taxa for application in the assessment of risks posed by increasing coal shipments in globally threatened marine ecosystems. PMID:27174014

An Organic Geochemical Assessment of CO2-Coal Interactions During Sequestration

USGS Publications Warehouse

Kolak, Jonathan J.; Burruss, Robert A.

2003-01-01

Three well-characterized coal samples of varying rank were extracted with supercritical CO2 to determine the amount of polycyclic aromatic hydrocarbons (PAHs) that could be mobilized during simulated CO2 injection/sequestration in deep coal beds. The supercritical CO2 extractions were conducted at 40?C and 100 bars, roughly corresponding to a depth of 1 km. The greatest amount of PAHs was extracted from the high-volatile C bituminous coal sample. Extracts from the subbituminous C and anthracite coal samples contained lower concentrations of these compounds. The effectiveness of supercritical CO2 in liberating PAHs from the coal sample was evaluated in a comparison with a parallel series of Soxhlet extractions using 100% dichloromethane. More PAHs were extracted from the lower rank coal samples with dichloromethane than with supercritical CO2. The results from this investigation indicate that, regardless of coal rank, CO2 injection into deep coal beds may mobilize PAHs from the coal matrix. However, more PAHs could be mobilized during CO2 sequestration in a high-volatile C bituminous coal bed than in either of the other two coal ranks studied.

National Coal Quality Inventory (NACQI)

DOE Office of Scientific and Technical Information (OSTI.GOV)

Robert Finkelman

2005-09-30

The U.S. Geological Survey (USGS) conducted the National Coal Quality Inventory (NaCQI) between 1999 and 2005 to address a need for quality information on coals that will be mined during the next 20-30 years. Collaboration between the USGS, State geological surveys, universities, coal burning utilities, and the coal mining industry plus funding support from the Electric Power Research Institute (EPRI) and the U.S. Department of Energy (DOE) permitted collection and submittal of coal samples for analysis. The chemical data (proximate and ultimate analyses; major, minor and trace element concentrations) for 729 samples of raw or prepared coal, coal associated shale,more » and coal combustion products (fly ash, hopper ash, bottom ash and gypsum) from nine coal producing States are included. In addition, the project identified a new coal reference analytical standard, to be designated CWE-1 (West Elk Mine, Gunnison County, Colorado) that is a high-volatile-B or high-volatile-A bituminous coal with low contents of ash yield and sulfur, and very low, but detectable contents of chlorine, mercury and other trace elements.« less

A study of coal production in Nigeria

DOE Office of Scientific and Technical Information (OSTI.GOV)

Akarakiri, J.B.; Afonja, A.A.; Okejiri, E.C.

The Nigerian coal industry was studied. The focus was on the problems which have caused low production output of coal. More specifically, the study examined the present techniques of coal production, the causes of low production of coal, the coal production policy as it affected this study, and proposed policy measures to address the findings. It was discovered that some of the limiting factors to coal production in Nigeria could be attributed to the lack of the following: (i) clear and specific production-demand targets set for coal in Nigeria; (ii) adequate technological capability to mechanize coal mining operations in Nigeria;more » (iii) venture capital to invest in coal production; (iv) poor infrastructural facilities for coal production such as mining, storage, transportation, etc. It was also discovered that the dissatisfaction of the miners with their conditions of service influenced production capacity negatively. These findings point to the reality that coal is unlikely to play a major role in the country's energy equation in the near future unless serious efforts are made to address the above issues.« less

Upgrade of Compressed Air Control System Reduces Energy Costs at Michelin Tire Plant

DOE Office of Scientific and Technical Information (OSTI.GOV)

None

2002-01-01

This case study highlights the upgraded compressed air system at a Michelin tire manufacturing plant in Spartanburg, South Carolina. The controls upgrade project enabled multiple compressor operation without blow-off, and significantly reduced energy costs.

Coal: Its Structure and Some of Its Uses.

ERIC Educational Resources Information Center

Phillips, P. S.

1981-01-01

Describes the formation, chemical structure, and several uses of coal. The history of coal usage, production processes, coal tar products, and production of petroleum and other hydrocarbons from coal are also described. (DS)

Cooling Effect Analysis of Suppressing Coal Spontaneous Ignition with Heat Pipe

NASA Astrophysics Data System (ADS)

Zhang, Yaping; Zhang, Shuanwei; Wang, Jianguo; Hao, Gaihong

2018-05-01

Suppression of spontaneous ignition of coal stockpiles was an important issue for safe utilization of coal. The large thermal energy from coal spontaneous ignition can be viewed as the latent energy source to further utilize for saving energy purpose. Heat pipe was the more promising way to diffuse effectively concentrated energy of the coal stockpile, so that retarding coal spontaneous combustion was therefore highly desirable. The cooling mechanism of the coal with heat pipe was pursued. Based on the research result, the thermal energy can be transported from the coal seam to the surface continuously with the use of heat pipe. Once installed the heat pipes will work automatically as long as the coal oxidation reaction was happened. The experiment was indicated that it can significantly spread the high temperature of the coal pile.

Mapping and prediction of Coal Workers' Pneumoconiosis with bioavailable iron content in the bituminous coals

USGS Publications Warehouse

Huang, X.; Li, W.; Attfield, M.D.; Nadas, A.; Frenkel, K.; Finkelman, R.B.

2005-01-01

Based on the first National Study of Coal Workers' Pneumoconiosis (CWP) and the U.S. Geological Survey database of coal quality, we show that the prevalence of CWP in seven coal mine regions correlates with levels of bioavailable iron (BAI) in the coals from that particular region (correlation coefficient r = 0.94, p < 0.0015). CWP prevalence is also correlated with contents of pyritic sulfur (r = 0.91, p < 0.0048) or total iron (r = 0.85, p < 0.016) but not with coal rank (r = 0.59, p < 0.16) or silica (r = 0.28, p < 0.54). BAI was calculated using our model, taking into account chemical interactions of pyrite, sulfuric acid, calcite, and total iron. That is, iron present in coals can become bioavailable by pyrite oxidation, which produces ferrous sulfate and sulfuric acid. Calcite is the major component in coals that neutralizes the available acid and inhibits iron's bioavailabiity. Therefore, levels of BAI in the coals are determined by the available amounts of acid after neutralization of calcite and the amount of total iron in the coals. Using the linear fit of CWP prevalence and the calculated BAI in the seven coal mine regions, we have derived and mapped the pneumoconiotic potencies of 7,000 coal samples. Our studies indicate that levels of BAI in the coals may be used to predict coal's toxicity, even before large-scalen mining.

Geochemical investigation of the potential for mobilizing non-methane hydrocarbons during carbon dioxide storage in deep coal beds

USGS Publications Warehouse

Kolak, J.J.; Burruss, R.C.

2006-01-01

Coal samples of different rank (lignite to anthracite) were extracted in the laboratory with supercritical CO2 (40 ??C; 10 MPa) to evaluate the potential for mobilizing non-methane hydrocarbons during CO2 storage (sequestration) or enhanced coal bed methane recovery from deep (???1-km depth) coal beds. The total measured alkane concentrations mobilized from the coal samples ranged from 3.0 to 64 g tonne-1 of dry coal. The highest alkane concentration was measured in the lignite sample extract; the lowest was measured in the anthracite sample extract. Substantial concentrations of polycyclic aromatic hydrocarbons (PAHs) were also mobilized from these samples: 3.1 - 91 g tonne-1 of dry coal. The greatest amounts of PAHs were mobilized from the high-volatile bituminous coal samples. The distributions of aliphatic and aromatic hydrocarbons mobilized from the coal samples also varied with rank. In general, these variations mimicked the chemical changes that occur with increasing degrees of coalification and thermal maturation. For example, the amount of PAHs mobilized from coal samples paralleled the general trend of bitumen formation with increasing coal rank. The coal samples yielded hydrocarbons during consecutive extractions with supercritical CO2, although the amount of hydrocarbons mobilized declined with each successive extraction. These results demonstrate that the potential for supercritical CO2 to mobilize non-methane hydrocarbons from coal beds, and the effect of coal rank on this process, are important to consider when evaluating deep coal beds for CO2 storage.

The distribution, occurrence and environmental effect of mercury in Chinese coals

USGS Publications Warehouse

Zheng, Lingyun; Liu, Gaisheng; Chou, C.-L.

2007-01-01

Mercury (Hg) is a toxic, persistent, and globally distributed pollutant due to its characteristic properties such as low melting and boiling points, conversion between chemical forms and participation in biological cycles. During combustion mercury in coal is almost totally emitted to the atmosphere. With a huge amount of coal consumed, coal combustion is one of the main anthropogenic sources of this element in the environment. In this study, Hg data of 1699 coal samples of China has been compiled, and the concentration, distribution, modes of occurrence, and the impact of Hg emissions on the environment are investigated. Most Chinese coals have Hg content in the range of 0.1 to 0.3??ppm, with an average of 0.19??ppm, which is slightly higher than the average Hg content of world coals and is close to that of the U.S. coals. The Hg content in coals varies in different coal basins, geological ages and coal ranks. The most likely mode of occurrences of Hg in high-sulfur and high Hg content coals is as solid solution in pyrite. But in low-sulfur coals, modes of occurrence of Hg are variable, and the organic-bound and sulfide-bound Hg may dominate. Silicate-bound Hg may be the main form in some coals because of magmatic intrusion. Mercury emissions during coal combustion have resulted in serious environmental contamination in China, particularly in the northeastern and southwestern China, where a high Hg content in the atmosphere occurs. ?? 2007 Elsevier B.V. All rights reserved.

Controls on boron and germanium distribution in the low-sulfur Amos coal bed, Western Kentucky coalfield, USA

USGS Publications Warehouse

Hower, J.C.; Ruppert, L.F.; Williams, D.A.

2002-01-01

The Duckmantian-aged Amos coal bed is a thin (<51 cm) coal bed that occurs in lobate southwest-trending pods separated by thin sandstones in the Western Kentucky coalfield. The coal bed, which is comprised of up to two benches and a rider coal, is low in ash yield (<6%) and sulfur content (<1%). The coal tends to be thin (<40 cm), but it was heavily mined in the 1980s because it could be combusted as mined. Geochemical analysis of the Amos coal bed shows higher concentrations of B and Ge than other Western Kentucky coal beds. High total B concentrations as well as high B/Be, both considered to be indicators of marine environments, increase toward the top of the coal bed. Most of the B values for the Amos samples range from 66 to 103 ppm (whole coal basis) indicating deposition in a brackish environment. High Ge concentrations in coals have been considered to be a function of seam thickness and proximity to the top and bottom of the coal bed. Thin coals, such as the Amos, are dominated by the coal bed margins and, therefore, have a tendency to have relatively high Ge concentrations. In the case of the Amos coal bed, the lower bench has a higher Ge content, suggesting that the substrate was a more important source of Ge than the roof rock. ?? 2002 Elsevier Science B.V. All rights reserved.

Coalification of organic matter in coal balls of the Pennsylvanian (upper Carboniferous) of the Illinois Basin, United States

USGS Publications Warehouse

Lyons, P.C.; Thompson, C.L.; Hatcher, P.G.; Brown, F.W.; Millay, M.A.; Szeverenyi, N.; Maciel, G.E.

1984-01-01

An evaluation was made of the degree of coalification of two coal balls from the Illinois Basin of the Pennsylvanian (upper Carboniferous) of the United States. Previous interpretations are mainly misleading and contradictory, primarily because of the assumption that the brown color and exceptional cellular and subcellular preservation typical of American coal balls imply chemical preservation of cellulose and lignin, the primary components of peat. Xylem tissue from a medullosan seed fern contained in a coal ball and the coal attached to the coal ball from the Calhoun coal bed, Mattoon Formation, Illinois, was analyzed by elemental, petrographic, and nuclear magnetic resonance (NMR) techniques to determine the degree of coalification. The NMR and elemental data indicate the lack of cellulose and lignin and a probable rank of high-volatile C bituminous coal. These data corroborate data for a coal ball from the Herrin (No. 6) coal bed (Carbondale Formation, Middle Pennsylvanian) and support our hypothesis that the organic matter in coal balls of the Pennsylvanian strata of the United States is coalified to about the same degree as the surrounding coal. Data presented show a range of lower reflectances for xylem tissue and vitrinite in the analyzed coal balls compared with vitrinite in the attached coal. The data reported indicate that physical preservation of organic matter in coal balls does not imply chemical preservation. Also our study supports the hypothesis that compactional (static load) pressure is not a prerequisite for coalification up to a rank of high-volatile C bituminous coal. A whole-rock analysis of the Calhoun coal ball indicates a similarity to other carbonate coal balls from the United States. It consists primarily of calcium carbonate and 1-2% organic matter; silica and alumina together make up less than 0.5%, indicating the lack of minerals such as quartz and clays. ?? 1984.

Pyrolysis of Woody Residue Feedstocks: Upgrading of Bio-Oils from Mountain-Pine-Beetle-Killed Trees and Hog Fuel

DOE Office of Scientific and Technical Information (OSTI.GOV)

Zacher, Alan H.; Elliott, Douglas C.; Olarte, Mariefel V.

Liquid transportation fuel blend-stocks were produced by pyrolysis and catalytic upgrading of woody residue biomass. Mountain pine beetle killed wood and hog fuel from a saw mill were pyrolyzed in a 1 kg/h fluidized bed reactor and subsequently upgraded to hydrocarbons in a continuous fixed bed hydrotreater. Upgrading was performed by catalytic hydrotreatment in a two-stage bed at 170°C and 405°C with a per bed LHSV between 0.17 and 0.19. The overall yields from biomass to upgraded fuel were similar for both feeds: 24-25% despite the differences in bio-oil (intermediate) mass yield. Pyrolysis bio-oil mass yield was 61% from MPBKmore » wood, and subsequent upgrading of the bio-oil gave an average mass yield of 41% to liquid fuel blend stocks. Hydrogen was consumed at an average of 0.042g/g of bio-oil fed, with final oxygen content in the product fuel ranging from 0.31% to 1.58% over the course of the test. Comparatively for hog fuel, pyrolysis bio-oil mass yield was lower at 54% due to inorganics in the biomass, but subsequent upgrading of that bio-oil had an average mass yield of 45% to liquid fuel, resulting in a similar final mass yield to fuel compared to the cleaner MPBK wood. Hydrogen consumption for the hog fuel upgrading averaged 0.041 g/g of bio-oil fed, and the final oxygen content of the product fuel ranged from 0.09% to 2.4% over the run. While it was confirmed that inorganic laded biomass yields less bio-oil, this work demonstrated that the resultant bio-oil can be upgraded to hydrocarbons at a higher yield than bio-oil from clean wood. Thus the final hydrocarbon yield from clean or residue biomass pyrolysis/upgrading was similar.« less

Coal dust contiguity-induced changes in the concentration of TNF- and NF- B p65 on the ocular surface

DOE Office of Scientific and Technical Information (OSTI.GOV)

Sun, Z.Y.; Hong, J.; Liu, Z.Y.

2009-07-01

To observe the influence of coal dust on ocular surface of coal miners and rabbits with coal dust contiguity on expression TNF- and NF- Bp65 and dry eye occurrence. Expression TNF- and NF- Bp65 in ocular surface were determined. Results showed tear production, BUT and lysozyme decreased for coal miners and rabbits with coal dust contiguity. Coal dust exposure was linked to development of xerophthalmia, and induced a higher expression of NF- B p65 and TNF- perhaps as a mechanism to resist coal dust ocular surface injury.

Weak economy and politics worry US coal operators

DOE Office of Scientific and Technical Information (OSTI.GOV)

Fiscor, S.

2009-01-15

A potential decrease in demand, a new administration, and production constraints have coal operators worried about prospects for 2009. This and other interesting facts are revealed in this 2009 forecast by the journal Coal Age. Results are presented of the survey answered by 69 of the 646 executives contacted, on such questions about expected coal production, coal use, attitude in the coal industry, capital expenditure on types of equipment and productive capacity. Coal Age forecasts a 2.3% decline in coal production in 2009, down to 1.145 billion tons from 1.172 billion tons. 8 figs.

Economics of utilization of high sulfur coal resources - an integrated market approach

USGS Publications Warehouse

Bhagwat, S.B.

1993-01-01

Before the Clean Air Act Amendments of 1990, coal policies - especially coal research policies - were geared to find a solution to the sulfur emission problem. However, technologies to reduce sulfur emissions cannot be tailored for a single coal. A technology that will clean Illinois coal to compliance levels will do the same, or nearly the same, for most other types of coal. This paper will discuss an integrated approach to the analysis of the future of coals from different regions in the United States and its implications for coal-related policies by government and industry.

Emissions from Coal Fires and Their Impact on the Environment

USGS Publications Warehouse

Kolker, Allan; Engle, Mark; Stracher, Glenn; Hower, James; Prakash, Anupma; Radke, Lawrence; ter Schure, Arnout; Heffern, Ed

2009-01-01

Self-ignited, naturally occurring coal fires and fires resulting from human activities persist for decades in underground coal mines, coal waste piles, and unmined coal beds. These uncontrolled coal fires occur in all coal-bearing parts of the world (Stracher, 2007) and pose multiple threats to the global environment because they emit greenhouse gases - carbon dioxide (CO2), and methane (CH4) - as well as mercury (Hg), carbon monoxide (CO), and other toxic substances (fig. 1). The contribution of coal fires to the global pool of atmospheric CO2 is little known but potentially significant. For China, the world's largest coal producer, it is estimated that anywhere between 10 million and 200 million metric tons (Mt) of coal reserves (about 0.5 to 10 percent of production) is consumed annually by coal fires or made inaccessible owing to fires that hinder mining operations (Rosema and others, 1999; Voigt and others, 2004). At this proportion of production, coal amounts lost to coal fires worldwide would be two to three times that for China. Assuming this coal has mercury concentrations similar to those in U.S. coals, a preliminary estimate of annual Hg emissions from coal fires worldwide is comparable in magnitude to the 48 tons of annual Hg emissions from all U.S. coal-fired power-generating stations combined (U.S. Environmental Protection Agency, 2002). In the United States, the combined cost of coal-fire remediation projects, completed, budgeted, or projected by the U.S. Department of the Interior's Office of Surface Mining Reclamation and Enforcement (OSM), exceeds $1 billion, with about 90% of that in two States - Pennsylvania and West Virginia (Office of Surface Mining Enforcement and Reclamation, 2008; fig. 2). Altogether, 15 States have combined cumulative OSM coal-fire project costs exceeding $1 million, with the greatest overall expense occurring in States where underground coal fires are predominant over surface fires, reflecting the greater cost of extinguishing underground fires (fig. 2) (see 'Controlling Coal Fires'). In this fact sheet we review how coal fires occur, how they can be detected by airborne and remote surveys, and, most importantly, the impact coal-fire emissions may have on the environment and human health. In addition, we describe recent efforts by the U.S. Geological Survey (USGS) and collaborators to measure fluxes of CO2, CO, CH4, and Hg, using groundbased portable detectors, and combining these approaches with airborne thermal imaging and CO2 measurements. The goal of this research is to develop approaches that can be extrapolated to large fires and to extrapolate results for individual fires in order to estimate the contribution of coal fires as a category of global emissions.

Study on dynamic multi-objective approach considering coal and water conflict in large scale coal group

NASA Astrophysics Data System (ADS)

Feng, Qing; Lu, Li

2018-01-01

In the process of coal mining, destruction and pollution of groundwater in has reached an imminent time, and groundwater is not only related to the ecological environment, but also affect the health of human life. Similarly, coal and water conflict is still one of the world's problems in large scale coal mining regions. Based on this, this paper presents a dynamic multi-objective optimization model to deal with the conflict of the coal and water in the coal group with multiple subordinate collieries and arrive at a comprehensive arrangement to achieve environmentally friendly coal mining strategy. Through calculation, this paper draws the output of each subordinate coal mine. And on this basis, we continue to adjust the environmental protection parameters to compare the coal production at different collieries at different stages under different attitude of the government. At last, the paper conclude that, in either case, it is the first arrangement to give priority to the production of low-drainage, high-yield coal mines.

Coal resource assessments using coal availability and recoverability methods

DOE Office of Scientific and Technical Information (OSTI.GOV)

Rohrbacher, T.J.

1997-12-01

The U.S. Geological Survey (USGS), in conjunction with state geological surveys and other federal agencies, has initiated a study and developed methodology to reassess the nation`s major coal resources. This study differs from previous coal resource assessments of the USGS, U.S. Bureau of Mines, and the Department of Energy`s Energy Information Administration, because this program: (1) Identifies and characterizes the coal beds and coal zones that will provide the bulk of the nation`s coal-derived energy during the first quarter of the twenty-first century; (2) organizes geologic, chemical, environmental, and geographic information in digital format and makes these data available tomore » the public through the Internet or other digital media, such as CD ROMs; (3) includes coal resource availability and coal recoverability analyses for selected areas; (4) provides economic assessments and coal recoverability analyses for selected areas; (5) provides methodology to perform socio-economic impact analysis related to coal mining in specific geographical areas as small as a county.« less

Concurrent changes in aggregation and swelling of coal particles in solvents

DOE Office of Scientific and Technical Information (OSTI.GOV)

Nishioka, M.

1995-12-31

A new method of coal swelling has been developed tinder the condition of low coal concentrations with continuous mixing of coal and solvent. The change in particle size distributions by a laser scattering procedure was used for the evaluation of coal swelling. Particle size distributions in good and poor solvents were nearly equal, but reversibly changed in good solvents from time to time. The effects of solubles and coal concentrations on the distributions were small. It was concluded that aggregate d coal particles disaggregate in good solvents, and that an increase in the particle size distribution due to swelling inmore » good solvents are compensated by a decrease in the particle size due to disaggregation. Therefore, the behavior of coal particles in solvents is controlled by aggregation in addition to coal swelling. This implies that an increase in the particle size due to coal swelling in actual processes is not so large as expected by the results obtained from the conventional coal swelling methods.« less

Petrographic, mineralogical, and chemical characterization of certain Alaskan coals and washability products. Final report, July 11, 1978-October 11, 1980

DOE Office of Scientific and Technical Information (OSTI.GOV)

Rao, P.D.; Wolff, E.N.

1981-05-01

Petrological, mineralogical and chemical characterization provides basic information needed for proper utilization of coals. Since many of these coals are likely to be beneficiated to reduce ash, the influence of coal washing on the characteristics of the washed product is important. Twenty samples of Alaskan coal seams were used for this study. The coals studied ranged in rank from lignite to high volatile A bituminous with vitrinite/ulminite reflectance ranging from 0.25 to 1.04. Fifteen raw coals were characterized for proximate and ultimate analysis reflectance rank, petrology, composition of mineral matter, major oxides and trace elements in coal ash. Washability productsmore » of three coals from Nenana, Beluga and Matanuska coal fields were used for characterization of petrology, mineral matter and ash composition. Petrological analysis of raw coals and float-sink products showed that humodetrinite was highest in top seam in a stratigraphic sequence« less

Using coal inside California for electric power

NASA Technical Reports Server (NTRS)

Moore, J. B.

1978-01-01

In a detailed analysis performed at Southern California Edison on a wide variety of technologies, the direct combustion of coal and medium BTU gas from coal were ranked just below nuclear power for future nonpetroleum based electric power generation. As a result, engineering studies were performed for demonstration projects for the direct combustion of coal and medium BTU gas from coal. Graphs are presented for power demand, and power cost. Direct coal combustion and coal gasification processes are presented.

New method of feeding coal - Continuous extrusion of fully plastic coal

NASA Technical Reports Server (NTRS)

Ryason, P. R.; England, C.

1978-01-01

Continuous feeding of coal in a compressing screw extruder is described as a method of introducing coal into pressurized systems. The method utilizes the property of many bituminous coals of softening at temperatures from 350 to 400 C. Coal is then fed much in the manner of common thermoplastics, using screw extruders. Preliminary results show that coals can be extruded at rates of about 3.3 kg/MJ, similar to those for plastics.

The adaption of coal quality to furnace structure

DOE Office of Scientific and Technical Information (OSTI.GOV)

Zhang, Z.; Shun, X.

1996-12-31

This paper gives the research result of coal quality adaption to furnace structure. The designing of a furnace is based on the coal quality that the furnace would fire. If the coal fired in the furnace differs from the design coal, there would be a lot of problems such as flame stability, coal burn-out rate and slagging problem for the furnace during its operation. In order to know the adaptional range of coal quality for an existing furnace the authors had chosen three different furnaces and 18 kinds of coals in their research work. To understand the coal combustion characteristicsmore » they introduce different indexes to show different processes of coal combustion. These indexes include Fz index which demonstrates the coal combustion based on its utility analyzed result, flame stability index, combustion characteristic index and char burn-out index which are based on the analyzed result of thermogravimetric characteristic. As a furnace is built up and set into operation its flame stability, burn-out rate and ash deposition are definite. If a furnace`s fuel changes its structure characteristics and operation condition will change. A relation between coal quality to furnace structure is based on a lot of regressional analysis results of existing furnaces and their fuels. Based on this relation the adaption of coal quality for a furnace are defined and the kinds of coal furnace fired are optimized to its design fuel.« less

NASA Glenn PSL-3 and 4 Control System Upgrade

NASA Technical Reports Server (NTRS)

Lizanich, Paul J.

2010-01-01

An overview of the PSL-3&4 Jet Engine Test Facility control system; including its history, a description of the present effort to upgrade from Emerson Ovation v2.2 to V3.3.1, and future upgrade plans is shown.

Colorado River Sewer System Joint Venture to Upgrade Wastewater System

EPA Pesticide Factsheets

SAN FRANCISCO -Today, the Colorado River Sewer System Joint Venture, located in Parker, Ariz. entered into an agreement with the EPA to upgrade their wastewater treatment system to meet stringent water quality standards. The cost of the upgrade is ap

38 CFR 17.351 - Grants for the replacement and upgrading of equipment at Veterans Memorial Medical Center.

Code of Federal Regulations, 2010 CFR

2010-07-01

... Philippines § 17.351 Grants for the replacement and upgrading of equipment at Veterans Memorial Medical Center. Grants to assist the Republic of the Philippines in the replacement and upgrading of equipment and in...

38 CFR 17.351 - Grants for the replacement and upgrading of equipment at Veterans Memorial Medical Center.

Code of Federal Regulations, 2011 CFR

2011-07-01

... Philippines § 17.351 Grants for the replacement and upgrading of equipment at Veterans Memorial Medical Center. Grants to assist the Republic of the Philippines in the replacement and upgrading of equipment and in...

38 CFR 17.351 - Grants for the replacement and upgrading of equipment at Veterans Memorial Medical Center.

Code of Federal Regulations, 2014 CFR

2014-07-01

... Philippines § 17.351 Grants for the replacement and upgrading of equipment at Veterans Memorial Medical Center. Grants to assist the Republic of the Philippines in the replacement and upgrading of equipment and in...

38 CFR 17.351 - Grants for the replacement and upgrading of equipment at Veterans Memorial Medical Center.

Code of Federal Regulations, 2013 CFR

2013-07-01

... Philippines § 17.351 Grants for the replacement and upgrading of equipment at Veterans Memorial Medical Center. Grants to assist the Republic of the Philippines in the replacement and upgrading of equipment and in...

38 CFR 17.351 - Grants for the replacement and upgrading of equipment at Veterans Memorial Medical Center.

Code of Federal Regulations, 2012 CFR

2012-07-01

... Philippines § 17.351 Grants for the replacement and upgrading of equipment at Veterans Memorial Medical Center. Grants to assist the Republic of the Philippines in the replacement and upgrading of equipment and in...

25 CFR 200.11 - Incorporation of coal lease terms and conditions.

Code of Federal Regulations, 2013 CFR

2013-04-01

... 25 Indians 1 2013-04-01 2013-04-01 false Incorporation of coal lease terms and conditions. 200.11... CONDITIONS: COAL LEASES § 200.11 Incorporation of coal lease terms and conditions. (a) All leases of coal on... respect to leases of coal on Indian lands issued by the Secretary after August 3, 1977, the Secretary...

25 CFR 200.11 - Incorporation of coal lease terms and conditions.

Code of Federal Regulations, 2012 CFR

2012-04-01

... 25 Indians 1 2012-04-01 2011-04-01 true Incorporation of coal lease terms and conditions. 200.11... CONDITIONS: COAL LEASES § 200.11 Incorporation of coal lease terms and conditions. (a) All leases of coal on... respect to leases of coal on Indian lands issued by the Secretary after August 3, 1977, the Secretary...

25 CFR 200.11 - Incorporation of coal lease terms and conditions.

Code of Federal Regulations, 2014 CFR

2014-04-01

... 25 Indians 1 2014-04-01 2014-04-01 false Incorporation of coal lease terms and conditions. 200.11... CONDITIONS: COAL LEASES § 200.11 Incorporation of coal lease terms and conditions. (a) All leases of coal on... respect to leases of coal on Indian lands issued by the Secretary after August 3, 1977, the Secretary...

30 CFR 206.459 - Allocation of washed coal.

Code of Federal Regulations, 2010 CFR

2010-07-01

... 30 Mineral Resources 2 2010-07-01 2010-07-01 false Allocation of washed coal. 206.459 Section 206... MANAGEMENT PRODUCT VALUATION Indian Coal § 206.459 Allocation of washed coal. (a) When coal is subjected to washing, the washed coal must be allocated to the leases from which it was extracted. (b) When the net...

75 FR 44978 - Notice of Availability of the Wright Area Coal Final Environmental Impact Statement That Includes...

Federal Register 2010, 2011, 2012, 2013, 2014

2010-07-30

... Wright Area Coal Final Environmental Impact Statement That Includes Four Federal Coal Lease- by... Statement (EIS) for the Wright Area Coal project that contains four Federal coal Lease-by-Applications (LBAs), and by this notice announces the availability of the Wright Area Coal Final EIS for review. DATES: To...

30 CFR 206.260 - Allocation of washed coal.

Code of Federal Regulations, 2010 CFR

2010-07-01

... 30 Mineral Resources 2 2010-07-01 2010-07-01 false Allocation of washed coal. 206.260 Section 206... MANAGEMENT PRODUCT VALUATION Federal Coal § 206.260 Allocation of washed coal. (a) When coal is subjected to washing, the washed coal must be allocated to the leases from which it was extracted. (b) When the net...

25 CFR 200.11 - Incorporation of coal lease terms and conditions.

Code of Federal Regulations, 2010 CFR

2010-04-01

... 25 Indians 1 2010-04-01 2010-04-01 false Incorporation of coal lease terms and conditions. 200.11... CONDITIONS: COAL LEASES § 200.11 Incorporation of coal lease terms and conditions. (a) All leases of coal on... respect to leases of coal on Indian lands issued by the Secretary after August 3, 1977, the Secretary...

43 CFR 3436.2-2 - Federal coal deposits subject to disposal by exchange.

Code of Federal Regulations, 2012 CFR

2012-10-01

... 43 Public Lands: Interior 2 2012-10-01 2012-10-01 false Federal coal deposits subject to disposal... LEASES Coal Lease and Coal Land Exchanges: Alluvial Valley Floors § 3436.2-2 Federal coal deposits subject to disposal by exchange. The coal deposits offered in exchange by the Secretary shall be...

25 CFR 200.11 - Incorporation of coal lease terms and conditions.

Code of Federal Regulations, 2011 CFR

2011-04-01

... 25 Indians 1 2011-04-01 2011-04-01 false Incorporation of coal lease terms and conditions. 200.11... CONDITIONS: COAL LEASES § 200.11 Incorporation of coal lease terms and conditions. (a) All leases of coal on... respect to leases of coal on Indian lands issued by the Secretary after August 3, 1977, the Secretary...

43 CFR 3436.2-2 - Federal coal deposits subject to disposal by exchange.

Code of Federal Regulations, 2011 CFR

2011-10-01

... 43 Public Lands: Interior 2 2011-10-01 2011-10-01 false Federal coal deposits subject to disposal... LEASES Coal Lease and Coal Land Exchanges: Alluvial Valley Floors § 3436.2-2 Federal coal deposits subject to disposal by exchange. The coal deposits offered in exchange by the Secretary shall be...

Coal combustion products

USGS Publications Warehouse

Kalyoncu, R.S.; Olson, D.W.

2001-01-01

Coal-burning powerplants, which supply more than half of U.S. electricity, also generate coal combustion products, which can be both a resource and a disposal problem. The U.S. Geological Survey collaborates with the American Coal Ash Association in preparing its annual report on coal combustion products. This Fact Sheet answers questions about present and potential uses of coal combustion products.

30 CFR 75.1709 - Accumulations of methane and coal dust on surface coal-handling facilities.

Code of Federal Regulations, 2010 CFR

2010-07-01

... 30 Mineral Resources 1 2010-07-01 2010-07-01 false Accumulations of methane and coal dust on... Miscellaneous § 75.1709 Accumulations of methane and coal dust on surface coal-handling facilities. [Statutory Provisions] Adequate measures shall be taken to prevent methane and coal dust from accumulating in excessive...

Methods and apparatuses for preparing upgraded pyrolysis oil

DOEpatents

Brandvold, Timothy A; Baird, Lance Awender; Frey, Stanley Joseph

2013-10-01

Methods and apparatuses for preparing upgraded pyrolysis oil are provided herein. In an embodiment, a method of preparing upgraded pyrolysis oil includes providing a biomass-derived pyrolysis oil stream having an original oxygen content. The biomass-derived pyrolysis oil stream is hydrodeoxygenated under catalysis in the presence of hydrogen to form a hydrodeoxygenated pyrolysis oil stream comprising a cyclic paraffin component. At least a portion of the hydrodeoxygenated pyrolysis oil stream is dehydrogenated under catalysis to form the upgraded pyrolysis oil.

VLT interferometer upgrade for the 2nd generation of interferometric instruments

NASA Astrophysics Data System (ADS)

Gonté, Frederic; Woillez, Julien; Schuhler, Nicolas; Egner, Sebastian; Merand, Antoine; Abad, José Antonio; Abadie, Sergio; Abuter, Roberto; Acuña, Margarita; Allouche, Fatmé; Alonso, Jaime; Andolfalto, Luigi; Antonelli, Pierre; Avila, Gerardo; Barriga, Pablo José; Beltran, Juan; Berger, Jean-Philippe; Bolados, Carlos; Bonnet, Henri; Bourget, Pierre; Brast, Roland; Bristow, Paul; Caniguante, Luis; Castillo, Roberto; Conzelmann, Ralf; Cortes, Angela; Delplancke, Françoise; Del Valle, Diego; Derie, Frederic; Diaz, Alvaro; Donoso, Reinaldo; Dorn, Reinhold; Duhoux, Philippe; Dupuy, Christophe; Eisenhauer, Frank; Elao, Christian; Fuenteseca, Eloy; Fernandez, Ruben; Gaytan, Daniel; Glindemann, Andreas; Gonzales, Jaime; Guieu, Sylvain; Guisard, Stephane; Haguenauer, Pierre; Haimerl, Andreas; Heinz, Volker; Henriquez, Juan Pablo; van der Heyden, P.; Hubin, Norbert; Huerta, Rodrigo; Jochum, Lieselotte; Leiva, Alfredo; Lévêque, Samuel; Lizon, Jean-Louis; Luco, Fernando; Mardones, Pedro; Mellado, Angel; Osorio, Juan; Ott, Jürgen; Pallanca, Laurent; Pavez, Marcus; Pasquini, Luca; Percheron, Isabelle; Pirard, Jean-Francois; Than Phan, Duc; Pineda, Juan Carlos; Pino, Andres; Poupar, Sebastien; Ramírez, Andres; Reinero, Claudio; Riquelme, Miguel; Romero, Juan; Rivinius, Thomas; Rojas, Chester; Rozas, Felix; Salgado, Fernando; Scheithauer, Silvia; Schmid, Christian; Schöller, Markus; Siclari, Waldo; Stephan, Christian; Tamblay, Richard; Tapia, Mario; Tristram, Konrad; Valdes, Guillermo; de Wit, Willem-Jan; Wright, Andrew; Zins, Gerard

2016-08-01

ESO is undertaking a large upgrade of the infrastructure on Cerro Paranal in order to integrate the 2nd generation of interferometric instruments Gravity and MATISSE, and increase its performance. This upgrade started mid 2014 with the construction of a service station for the Auxiliary Telescopes and will end with the implementation of the adaptive optics system for the Auxiliary telescope (NAOMI) in 2018. This upgrade has an impact on the infrastructure of the VLTI, as well as its sub-systems and scientific instruments.

Kongiganak Wind Turbine Replacement and System Upgrade Project

DOE Office of Scientific and Technical Information (OSTI.GOV)

Boonstra, Patrick

2016-12-13

The Native Village of Kongiganak, Alaska was awarded a grant to upgrade the braking systems on five wind turbines and upgrade the monitoring and data collection unit to insure that enough energy is available to power the utility. The project manager for this award is Intelligent Energy Systems, LLC located in Anchorage, Alaska. In addition to accomplishing these upgrades, it was the intent for a local wind tech crew to be trained in Kongiganak so that routine maintenance and future repairs will be made by local workers.

Habitat Demonstration Unit Medical Operations Workstation Upgrades

NASA Technical Reports Server (NTRS)

Trageser, Katherine H.

2011-01-01

This paper provides an overview of the design and fabrication associated with upgrades for the Medical Operations Workstation in the Habitat Demonstration Unit. The work spanned a ten week period. The upgrades will be used during the 2011 Desert Research and Technology Studies (Desert RATS) field campaign. Upgrades include a deployable privacy curtain system, a deployable tray table, an easily accessible biological waste container, reorganization and labeling of the medical supplies, and installation of a retractable camera. All of the items were completed within the ten week period.

Process for coal liquefaction employing selective coal feed

DOEpatents

Hoover, David S.; Givens, Edwin N.

1983-01-01

An improved coal liquefaction process is provided whereby coal conversion is improved and yields of pentane soluble liquefaction products are increased. In this process, selected feed coal is pulverized and slurried with a process derived solvent, passed through a preheater and one or more dissolvers in the presence of hydrogen-rich gases at elevated temperatures and pressures, following which solids, including mineral ash and unconverted coal macerals, are separated from the condensed reactor effluent. The selected feed coals comprise washed coals having a substantial amount of mineral matter, preferably from about 25-75%, by weight, based upon run-of-mine coal, removed with at least 1.0% by weight of pyritic sulfur remaining and exhibiting vitrinite reflectance of less than about 0.70%.

Preliminary Investigations of the Distribution and Resources of Coal in the Kaiparowits Plateau, Southern Utah

USGS Publications Warehouse

Hettinger, Robert D.; Roberts, L.N.R.; Biewick, L.R.H.; Kirschbaum, M.A.

1996-01-01

EXECUTIVE SUMMARY This report on the coal resources of the Kaiparowits Plateau, Utah is a contribution to the U.S. Geological Survey's (USGS) 'National Coal Resource Assessment' (NCRA), a five year effort to identify and characterize the coal beds and coal zones that could potentially provide the fuel for the Nation's coal-derived energy during the first quarter of the twenty-first century. For purposes of the NCRA study, the Nation is divided into regions. Teams of geoscientists, knowledgeable about each region, are developing the data bases and assessing the coal within each region. The five major coal-producing regions of the United States under investigation are: (1) the Appalachian Basin; (2) the Illinois Basin; (3) the Gulf of Mexico Coastal Plain; (4) the Powder River Basin and the Northern Great Plains; and (5) the Rocky Mountains and the Colorado Plateau. Six areas containing coal deposits in the Rocky Mountain and Colorado Plateau Region have been designated as high priority because of their potential for development. This report on the coal resources of the Kaiparowits Plateau is the first of the six to be completed. The coal quantities reported in this study are entirely 'resources' and represent, as accurately as the data allow, all the coal in the ground in beds greater than one foot thick. These resources are qualified and subdivided by thickness of coal beds, depth to the coal, distance from known data points, and inclination (dip) of the beds. The USGS has not attempted to estimate coal 'reserves' for this region. Reserves are that subset of the resource that could be economically produced at the present time. The coal resources are differentiated into 'identified' and 'hypothetical' following the standard classification system of the USGS (Wood and others, 1983). Identified resources are those within three miles of a measured thickness value, and hypothetical resources are further than three miles from a data point. Coal beds in the Kaiparowits Plateau are laterally discontinuous relative to many other coal bearing regions of the United States. That is, they end more abruptly and are more likely to fragment or split into thinner beds. Because of these characteristics, the data from approximately 160 drill holes and 40 measured sections available for use in this study are not sufficient to determine what proportion of the resources is technologically and economically recoverable. The Kaiparowits Plateau contains an original resource of 62 billion short tons of coal in the ground. Original resource is defined to include all coal beds greater than one foot thick in the area studied. None of the resource is recoverable by surface mining. However, the total resource figure must be regarded with caution because it does not reflect geologic, technological, land-use, and environmental restrictions that may affect the availability and the recoverability of the coal. At least 32 billion tons of coal are unlikely to be mined in the foreseeable future because the coal beds are either too deep, too thin to mine, inclined at more than 12?, or in beds that are too thick to be completely recovered in underground mining. The estimated balance of 30 billion tons of coal resources does not reflect land use or environmental restrictions, does not account for coal that would be bypassed due to mining of adjacent coal beds, does not consider the amount of coal that must remain in the ground for roof support, and does not take into consideration the continuity of beds for mining. Although all of these factors will reduce the amount of coal that could be recovered, there is not sufficient data available to estimate recoverable coal resources. For purposes of comparison, studies of coal resources in the eastern United States have determined that less than 10 percent of the original coal resource, in the areas studied, could be mined economically at today's prices (Rohrbacher and others, 1994).

Place vs. time and vegetational persistence: A comparison of four tropical mires from the Illinois Basin during the height of the Pennsylvanian Ice Age

USGS Publications Warehouse

DiMichele, W.A.; Phillips, T.L.; Nelson, W. John

2002-01-01

Coal balls were collected from four coal beds in the southeastern part of the Illinois Basin. Collections were made from the Springfield, Herrin, and Baker coals in western Kentucky, and from the Danville Coal in southwestern Indiana. These four coal beds are among the principal mineable coals of the Illinois Basin and belong to the Carbondale and Shelburn Formations of late Middle Pennsylvanian age. Vegetational composition was analyzed quantitatively. Coal-ball samples from the Springfield, Herrin, and Baker are dominated by the lycopsid tree Lepidophloios, with lesser numbers of Psaronius tree ferns, medullosan pteridosperms, and the lycopsid trees Synchysidendron and Diaphorodendron. This vegetation is similar to that found in the Springfield and Herrin coals elsewhere in the Illinois Basin, as reported in previous studies. The Danville coal sample, which is considerably smaller than the others, is dominated by Psaronius with the lycopsids Sigillaria and Synchysidendron as subdominants. Coal balls from the Springfield coal were collected in zones directly from the coal bed and their zone-by-zone composition indicates three to four distinct plant assemblages. The other coals were analyzed as whole-seam random samples, averaging the landscape composition of the parent mire environments. This analysis indicates that these coals, separated from each other by marine and terrestrial-clastic deposits, have essentially the same floristic composition and, thus, appear to represent a common species pool that persisted throughout the late Middle Pennsylvanian, despite changes in baselevel and climate attendant the glacial interglacial cyclicity of the Pennsylvanian ice age. Patterns of species abundance and diversity are much the same for the Springfield, Herrin, and Baker, although each coal, both in the local area sampled, and regionally, has its own paleobotanical peculiarities. Despite minor differences, these coals indicate a high degree of recurrence of assemblage and landscape organization. The Danville departs dramatically from the dominance-diversity composition of the older coals, presaging patterns of tree-fern and Sigillaria dominance of Late Pennsylvanian coals of the eastern United States, but, nonetheless, built on a species pool shared with the older coals. ?? 2002 Elsevier Science B.V. All rights reserved.

Environmental implications of United States coal exports: a comparative life cycle assessment of future power system scenarios.

PubMed

Bohnengel, Barrett; Patiño-Echeverri, Dalia; Bergerson, Joule

2014-08-19

Stricter emissions requirements on coal-fired power plants together with low natural gas prices have contributed to a recent decline in the use of coal for electricity generation in the United States. Faced with a shrinking domestic market, many coal companies are taking advantage of a growing coal export market. As a result, U.S. coal exports hit an all-time high in 2012, fueled largely by demand in Asia. This paper presents a comparative life cycle assessment of two scenarios: a baseline scenario in which coal continues to be burned domestically for power generation, and an export scenario in which coal is exported to Asia. For the coal export scenario we focus on the Morrow Pacific export project being planned in Oregon by Ambre Energy that would ship 8.8 million tons of Powder River Basin (PRB) coal annually to Asian markets via rail, river barge, and ocean vessel. Air emissions (SOx, NOx, PM10 and CO2e) results assuming that the exported coal is burned for electricity generation in South Korea are compared to those of a business as usual case in which Oregon and Washington's coal plants, Boardman and Centralia, are retrofitted to comply with EPA emissions standards and continue their coal consumption. Findings show that although the environmental impacts of shipping PRB coal to Asia are significant, the combination of superior energy efficiency among newer South Korean coal-fired power plants and lower emissions from U.S. replacement of coal with natural gas could lead to a greenhouse gas reduction of 21% in the case that imported PRB coal replaces other coal sources in this Asian country. If instead PRB coal were to replace natural gas or nuclear generation in South Korea, greenhouse gas emissions per unit of electricity generated would increase. Results are similar for other air emissions such as SOx, NOx and PM. This study provides a framework for comparing energy export scenarios and highlights the importance of complete life cycle assessment in determining net emissions effects resulting from energy export projects and related policy decisions.

Atmospheric emission of mercury due to combustion of steam coal and domestic coal in China

NASA Astrophysics Data System (ADS)

Wang, Shaobin; Luo, Kunli

2017-08-01

To study the mercury emission due to the combustion of steam coal and domestic coal in China, we analyzed the mercury contents of coal, fly ash, bottom ash and sluicing water in thermal power plants, steam boilers as well as domestic coal-stoves, in Shaanxi, Shanxi, Shandong and Yunnan Provinces. This study conduct an estimate of the Hg emission rates from steam coal and domestic coal combustion based on the method of mass distribution ratio of fly ash and bottom ash. The results show that the Hg emission rate of coal combustion in thermal power plants is about 50.21% (electrostatic precipitators + wet flue gas desulfurization), and that in heating boilers is about 67.23%, and 92.28% in industrial boilers without flue gas desulphurisation equipment. Furthermore, Hg emission rate is 83.61% due to domestic coal combustion in coal-stoves. The Hg emission amount into the atmosphere from power and heat generation, industrial boilers, domestic coal-stoves and spontaneous combustion of coal gangue is roughly estimated to be 133 ± 4, 100 ± 17, 11 ± 0.1 and 47 ± 26 tons in China in 2014, respectively, and the total Hg emission amount from this paper is estimated at 292 tons. The trends of Hg emission in China from 1991 to 2014 show an accelerating growth after 2002. The proportion of mercury emission due to thermal power, heating generation and industrial energy utilization continuously increased. The atmospheric emission of mercury due to combustion of steam coal, domestic coal and coal gangue accounts nearly 50% in total anthropogenic Hg emissions in China, indicating one of the largest sources of Hg emission in China which should draw more public and scientific attention in the future.

Electrical Resistivity Tomography for coal fire mapping over Jharia coal field, India

NASA Astrophysics Data System (ADS)

Pal, S. K.; Kumar, S.; Bharti, A. K.; Pathak, V. K.; Kumar, R.

2016-12-01

Over the decades, coal fires are serious global concern posing grievous hazards to the valuable energy resources, local environments and human life. The coal seam and coal mine fires may be initiated due to improper mining activities, exothermic reactions, lighting, forest fire and other anthropic activities, which burn the coal and may continue underground for decades. The burning of concealed coal seams is a complex process involving numerous ill-defined parameters. Generally, the coal exhibits resistivity of 100 to 500Ωm at normal temperature conditions. During the pyrolysis process, at temperatures greater than 6500C coal became a good conductor with a resistivity of approximately 1 Ωm. The present study deals with the mapping of coal fire over Jharia coal field, India using Electrical Resistivity Tomography (ERT). A state-of-the-art 61-channel 64 electrode FlashRES-Universal ERT data acquisition system has been used for data acquisition in the field. The ERT data have been collected using Gradient array and processed in FlashRES Universal survey data checking program for removing noisy data. Then, filtered output data have been inverted using a 2.5D resistivity inversion program. Low resistivity anomalies over 80m-125m and 320m-390m along the profile are inferred to be active coal fire in seam- XVI at a depth of 25m -35m(Figure 1). High resistivity anomaly over 445m - 510m at a depth of 25m -35m has been delineated, due to void associated with complete combustion of seam- XVI coal, followed by char and ash formation resulting from the coal seam fire. Results prove the efficacy of the ERT study comprising Gradient array for coal fire mapping over, Jharia coal field, India.

Coal bed sequestration of carbon dioxide

USGS Publications Warehouse

Stanton, Robert; Flores, Romeo M.; Warwick, Peter D.; Gluskoter, Harold J.; Stricker, Gary D.

2001-01-01

Geologic sequestration of CO2 generated from fossil fuel combustion may be an environmentally attractive method to reduce the amount of greenhouse gas emissions. Of the geologic options, sequestering CO2 in coal beds has several advantages. For example, CO2 injection can enhance methane production from coal beds; coal can trap CO2 for long periods of time; and potential major coal basins that contain ideal beds for sequestration are near many emitting sources of CO2.One mission of the Energy Resources Program of the U.S. Geological Survey is to maintain assessment information of the Nation’s resources of coal, oil, and gas. The National Coal Resources Assessment Project is currently completing a periodic assessment of 5 major coal-producing regions of the US. These regions include the Powder River and Williston and other Northern Rocky Mountain basins (Fort Union Coal Assessment Team, 1999), Colorado Plateau area (Kirschbaum and others, 2000), Gulf Coast Region, Appalachian Basin, and Illinois Basin. The major objective of this assessment is to estimate available coal resources and quality for the major producing coal beds of the next 25 years and produce digital databases and maps. Although the focus of this work has been on coal beds with the greatest potential for mining, it serves as a basis for future assessments of the coal beds for other uses such as coal bed methane resources, in situ gasification, and sites for sequestration of CO2. Coal bed methane production combined with CO2 injection and storage expands the use of a coal resource and can provide multiple benefits including increased methane recovery, methane drainage of a resource area, and the long-term storage of CO2.

Mercury concentration in coal - Unraveling the puzzle

USGS Publications Warehouse

Toole-O'Neil, B.; Tewalt, S.J.; Finkelman, R.B.; Akers, D.J.

1999-01-01

Based on data from the US Geological Survey's COALQUAL database, the mean concentration of mercury in coal is approximately 0.2 ??gg-1. Assuming the database reflects in-ground US coal resources, values for conterminous US coal areas range from 0.08 ??gg-1 for coal in the San Juan and Uinta regions to 0.22 ??gg-1 for the Gulf Coast lignites. Recalculating the COALQUAL data to an equal energy basis unadjusted for moisture differences, the Gulf Coast lignites have the highest values (36.4 lb of Hg/1012 Btu) and the Hams Fork region coal has the lowest value (4.8 lb of Hg/1012Btu). Strong indirect geochemical evidence indicates that a substantial proportion of the mercury in coal is associated with pyrite occurrence. This association of mercury and pyrite probably accounts for the removal of mercury with the pyrite by physical coal cleaning procedures. Data from the literature indicate that conventional coal cleaning removes approximately 37% of the mercury on an equal energy basis, with a range of 0% to 78%. When the average mercury reduction value is applied to in-ground mercury values from the COALQUAL database, the resulting 'cleaned' mercury values are very close to mercury in 'as-shipped' coal from the same coal bed in the same county. Applying the reduction fact or for coal cleaning to eastern US bituminous coal, reduces the mercury input load compared to lower-rank non-deaned western US coal. In the absence of analytical data on as-shipped coal, the mercury data in the COALQUAL database, adjusted for deanability where appropriate, may be used as an estimator of mercury contents of as-shipped coal. ?? 1998 Published by Elsevier Science Ltd. All rights reserved.

Flow in Coal Seams: An Unconventional Challenge

NASA Astrophysics Data System (ADS)

Armstrong, R. T.; Mostaghimi, P.; Jing, Y.; Gerami, A.

2016-12-01

A significant unconventional resource for energy is the methane gas stored in shallow coal beds, known as coal seam gas. An integrated imaging and modelling framework is developed for analysing petrophysical behaviour of coals. X-ray micro-computed tomography (micro-CT) is applied using a novel contrast agent method for visualising micrometer-sized fractures in coal. The technique allows for the visualisation of coal features not visible with conventional imaging methods. A Late Permian medium volatile bituminous coal from Moura Coal Mine (Queensland, Australia) is imaged and the resulting three-dimensional coal fracture system is extracted for fluid flow simulations. The results demonstrate a direct relationship between coal lithotype and permeability. Scanning electron microscope and energy dispersive spectrometry (SEM-EDS) together with X-ray diffraction (XRD) methods are used for identifying mineral matters at high resolution. SEM high-resolution images are also used to calibrate the micro-CT images and measure the exact aperture size of fractures. This leads to a more accurate estimation of permeability using micro-CT images. To study the significance of geometry and topology of the fracture system, a fracture reconstruction method based on statistical properties of coal is also developed. The network properties including the frequency, aperture size distribution, length, and spacing of the imaged coal fracture system. This allows for a sensitivity analysis on the effects that coal fracture topology and geometry has on coal petrophysical properties. Furthermore, we generate microfluidic chips based on coal fracture observations. The chip is used for flow experiments to visualise multi-fluid processes and measure recovery of gas. A combined numerical and experimental approach is applied to obtain relative permeability curves for different regions of interest. A number of challenges associated with coal samples are discussed and insights are provided for better understanding of these complex porous media systems.

Coal blending preparation for non-carbonized coal briquettes

NASA Astrophysics Data System (ADS)

Widodo; Fatimah, D.; Estiaty, L. M.

2018-02-01

Referring to the national energy policy targets for the years 2025, the government has launched the use of coal briquettes as an alternative energy replacement for kerosene and firewood. Non-carbonized briquettes in the form of coal briquettes as well as bio-coal briquettes are used in many small-medium industries and households, and are rarely used by large industries. The standard quality of coal briquettes used as raw material for non-carbonized briquettes is a minimum calorific value of 4,400 kcal/kg (adb); total sulfur at a maximum of 1% (adb), and water content at <12% (adb). The formation of coal deposits depends on the origin of the coal-forming materials (plants), the environment of deposition, and the geological conditions of the surrounding area, so that the coal deposits in each region will be different as well as the amount and also the quality. Therefore, the quantity and the quality of coal in each area are different to be eligible in the making of briquettes to do blending. In addition to the coal blending, it is also necessary to select the right materials in the making of coal briquettes and bio-coal briquettes. The formulation of the right mixture of material in the making of briquettes, can be produced of good quality and environmental friendly.

Liquefaction of calcium-containing subbituminous coals and coals of lower rank

DOEpatents

Gorbaty, Martin L.; Taunton, John W.

1980-01-01

A process for the treatment of a calcium-containing subbituminous coal and coals of lower rank to form insoluble, thermally stable calcium salts which remain within the solids portions of the residue on liquefaction of the coal, thereby suppressing the formation scale, made up largely of calcium carbonate deposits, e.g., vaterite, which normally forms within the coal liquefaction reactor (i.e., coal liquefaction zone), e.g., on reactor surfaces, lines, auxiliary equipment and the like. A solution of a compound or salt characterized by the formula MX, where M is a Group IA metal of the Periodic Table of the Elements, and X is an anion which is capable of forming water-insoluble, thermally stable calcium compounds, is maintained in contact with a particulate coal feed sufficient to impregnate said salt or compound into the pores of the coal. On separation of the impregnated particulate coal from the solution, the coal can be liquefied in a coal liquefaction reactor (reaction zone) at coal liquefaction conditions without significant formation of vaterite or other forms of calcium carbonate on reactor surfaces, auxiliary equipment and the like; and the Group IA metal which remains within the liquefaction bottoms catalyzes the reaction when the liquefaction bottoms are subjected to a gasification reaction.

Characterization and modes of occurrence of elements in feed coal and fly ash; an integrated approach

USGS Publications Warehouse

Brownfield, M.E.

2002-01-01

Despite certain environmental concerns, coal is likely to remain an important component of the United States energy supply, partly because it is the most abundant domestically available fossil fuel. One of the concerns about coal combustion for electricity production is the potential release of elements from coal and coal combustion products (CCPs) - fly ash - to the environment. This concern prompted the need for accurate, reliable, and comprehensive information on the contents and modes of occurrence of selected elements in power-plant feed coal and fly ash. The U.S. Geological Survey (USGS) is collaborating with several electric utilities to determine the chemical and mineralogical properties of feed coal and fly ash. Our first study analyzed coal and fly ash from a Kentucky power plant, which uses many different bituminous coals from the Appalachian and Illinois Basins. Sulfur content of these feed coals rangedfrom 2.5 to 3.5 percent. The second study analyzed coal and fly ash from an Indiana power plant, which uses subbituminous coal from the Powder River Basin (fig. 1). Sulfur content of this feed coal ranged from 0.23 to 0.47 percent. A summary of important aspects of our approach and results are presented in this report. 

Characterization of Gas-Phase Organics Using Proton Transfer Reaction Time-of-Flight Mass Spectrometry: Residential Coal Combustion.

PubMed

Klein, Felix; Pieber, Simone M; Ni, Haiyan; Stefenelli, Giulia; Bertrand, Amelie; Kilic, Dogushan; Pospisilova, Veronika; Temime-Roussel, Brice; Marchand, Nicolas; El Haddad, Imad; Slowik, Jay G; Baltensperger, Urs; Cao, Junji; Huang, Ru-Jin; Prévôt, André S H

2018-03-06

Residential coal combustion is a significant contributor to particulate urban air pollution in Chinese mega cities and some regions in Europe. While the particulate emission factors and the chemical characteristics of the organic and inorganic aerosol from coal combustion have been extensively studied, the chemical composition and nonmethane organic gas (NMOG) emission factors from residential coal combustion are mostly unknown. We conducted 23 individual burns in a traditional Chinese stove used for heating and cooking using five different coals with Chinese origins, characterizing the NMOG emissions using a proton transfer reaction time-of-flight mass spectrometer. The measured emission factors range from 1.5 to 14.1 g/kg coal for bituminous coals and are below 0.1 g/kg coal for anthracite coals. The emission factors from the bituminous coals are mostly influenced by the time until the coal is fully ignited. The emissions from the bituminous coals are dominated by aromatic and oxygenated aromatic compounds with a significant contribution of hydrocarbons. The results of this study can help to improve urban air pollution modeling in China and Eastern Europe and can be used to constrain a coal burning factor in ambient gas phase positive matrix factorization studies.

Improvement of storage, handling, and transportability of fine coal. Quarterly technical progress report number 8, October 1--December 31, 1995

DOE Office of Scientific and Technical Information (OSTI.GOV)

NONE

The Mulled Coal process was developed as a means of overcoming the adverse handling characteristics of wet fine coal without thermal drying. The process involves the addition of a low cost, harmless reagent to wet fine coal using off-the-shelf mixing equipment. Based on laboratory- and bench-scale testing, Mulled coal can be stored, shipped, and burned without causing any of the plugging, pasting, carryback and freezing problems normally associated with wet coal. On the other hand, Mulled Coal does not cause the fugitive and airborne dust problems normally associated with thermally dried coal. The objectives of this project are to demonstratemore » that: the Mulled Coal process, which has been proved to work on a wide range of wet fine coals at bench scale, will work equally well on a continuous basis, producing consistent quality, and at a convincing rate of production in a commercial coal preparation plant; the wet product from a fine coal cleaning circuit can be converted to a solid fuel form for ease of handling and cost savings in storage and rail car transportation; and a wet fine coal product thus converted to a solid fuel form, can be stored, shipped, and burned with conventional fuel handling, transportation, and combustion systems.« less

Regulation of coal polymer degradation by fungi. Fourth quarterly progress report, May 1995--June 1995

DOE Office of Scientific and Technical Information (OSTI.GOV)

Irvine, R.L.

1995-07-24

To test the hypothesis that coal (leonardite) Solubilization and the subsequent depolymerization of the solubilized coal macromolecules are distinct events in lignin degrading fungi. In addition to T versicolor, Phanerochaete chrysosporium, another lignin degrading fungus that also has the ability to solubilize coal, will be studied. To test the hypothesis that the processes of coal (leonardite) solubilization and coal macro molecule depolymerization in lignin degrading fungi can be regulated by altering the nutritional status of the microorganism. Coal solubilization is expected to occur in nutrient rich media whereas depolymerization of solubilized coal macromolecules is expected to occur in nutrient limitedmore » media. To determine the role of extracellular enzymes (laccases, lignin peroxidases and Mn peroxidases) that are secreted by lignin degrading fungi during coal solubilization or coal macro molecule depolymerization. To assess the role of enzymatically generated oxygen radicals, non-radical active oxygen species, veratryl alcohol radicals and Mn{sup +++} complexes in coal macro molecule depolymerization. To characterize products of coal solubilization and coal macro molecule depolymerization that are formed by T. versicolor and P. chrysosporium and their respective extracellular enzymes. Solubilization products formed using oxalic acid and other metal chelators will also be characterized and compared.« less

Upgrading Supply Chain Management Systems to Improve Availability of Medicines in Tanzania: Evaluation of Performance and Cost Effects.

PubMed

Mwencha, Marasi; Rosen, James E; Spisak, Cary; Watson, Noel; Kisoka, Noela; Mberesero, Happiness

2017-09-27

To address challenges in public health supply chain performance, Tanzania invested in a national logistics management unit (LMU) and a national electronic logistics management information system (eLMIS). This evaluation examined the impact of those 2 key management upgrades approximately 1 year after they were introduced. We used a nonexperimental pre-post study design to compare the previous system with the upgraded management system. We collected baseline data from August to November 2013. We conducted round 1 of post-implementation data collection during April and May 2015, about 1 year after implementation of the upgrades. We evaluated key indicators of data use and reporting; supply chain management practices such as storage and supervision; supply chain performance including stock-out and expiry rates; and supply chain cost and savings. We analyzed the data using a range of techniques including statistical testing of baseline and round-1 results, and cost, cost-effectiveness, and return on investment analysis. The upgrades were associated with improvements in data use, accessibility, visibility, and transparency; planning, control, and monitoring; support for quantification; stock-out rates; stock-out duration; commodity expiry; and forecast error. The upgraded system was more costly, but it was also more efficient, particularly when adjusting for the performance improvements. The upgrades also generated substantial savings that defrayed some, but not all, of the investment costs. Upgrades to Tanzania's supply chain management systems created multiple and complex pathways to impact. One year after implementation, the LMU and eLMIS brought about performance improvements through better data use and through improvements in some, but not all, management practices. Furthermore, the upgrades-while not inexpensive-contributed to greater system efficiency and modest savings. © Mwencha et al.

Cluster-randomized controlled trial of the effects of free glasses on purchase of children's glasses in China: The PRICE (Potentiating Rural Investment in Children's Eyecare) study.

PubMed

Wang, Xiuqin; Congdon, Nathan; Ma, Yue; Hu, Min; Zhou, Yuan; Liao, Weiqi; Jin, Ling; Xiao, Baixiang; Wu, Xiaoyi; Ni, Ming; Yi, Hongmei; Huang, Yiwen; Varga, Beatrice; Zhang, Hong; Cun, Yongkang; Li, Xianshun; Yang, Luhua; Liang, Chaoguang; Huang, Wan; Rozelle, Scott; Ma, Xiaochen

2017-01-01

Offering free glasses can be important to increase children's wear. We sought to assess whether "Upgrade glasses" could avoid reduced glasses sales when offering free glasses to children in China. In this cluster-randomized, controlled trial, children with uncorrected visual acuity (VA)< = 6/12 in either eye correctable to >6/12 in both eyes at 138 randomly-selected primary schools in 9 counties in Guangdong and Yunnan provinces, China, were randomized by school to one of four groups: glasses prescription only (Control); Free Glasses; Free Glasses + offer of $15 Upgrade Glasses; Free Glasses + offer of $30 Upgrade Glasses. Spectacle purchase (main outcome) was assessed 6 months after randomization. Among 10,234 children screened, 882 (8.62%, mean age 10.6 years, 45.5% boys) were eligible and randomized: 257 (29.1%) at 37 schools to Control; 253 (28.7%) at 32 schools to Free Glasses; 187 (21.2%) at 31 schools to Free Glasses + $15 Upgrade; and 185 (21.0%) at 27 schools to Free Glasses +$30 Upgrade. Baseline ownership among these children needing glasses was 11.8% (104/882), and 867 (98.3%) children completed follow-up. Glasses purchase was significantly less likely when free glasses were given: Control: 59/250 = 23.6%; Free glasses: 32/252 = 12.7%, P = 0.010. Offering Upgrade Glasses eliminated this difference: Free + $15 Upgrade: 39/183 = 21.3%, multiple regression relative risk (RR) 0.90 (0.56-1.43), P = 0.65; Free + $30 Upgrade: 38/182 = 20.9%, RR 0.91 (0.59, 1.42), P = 0.69. Upgrade glasses can prevent reductions in glasses purchase when free spectacles are provided, providing important program income. ClinicalTrials.gov Identifier: NCT02231606. Registered on 31 August 2014.

Looking southeast at coal conveyor leading from the coal unloading ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

Looking southeast at coal conveyor leading from the coal unloading station to the coal elevator. - Wheeling-Pittsburgh Steel Corporation, Allenport Works, Boiler House, Route 88 on West bank of Monongahela River, Allenport, Washington County, PA

JEDI Coal Model | Jobs and Economic Development Impact Models | NREL

Science.gov Websites

Coal Model JEDI Coal Model The Jobs and Economic Development Impacts (JEDI) Coal Model allow users to estimate economic development impacts from coal projects and includes default information that can

FINDINGS OF A SYMPOSIUM ON COAL QUALITY.

USGS Publications Warehouse

Schweinfurth, Stanley P.; Garbini, Susan

1985-01-01

The U. S. Geological Survey (USGS) has been doing research on coal quality for almost a century. Most of the work of the USGS regarding coal went into efforts to assess the quantity of coal in the United States, not the quality. On April 9-11, 1985, the U. S. Geological Survey, along with cosponsors - the Association of American State Geologists, the U. S. Department of Energy, the Electric Power Research Institute, and the U. S. Environmental Protection Agency - convened a symposium on coal quality at the headquarters of the USGS in Reston, Virginia. The coal-quality symposium provided a forum for the discussion of a wide variety of topics with regard to coal-quality research and related activities. The coal community took advantage of that opportunity to recommend a large agenda of coal-research needs, not only for the USGS but for the entire spectrum of organizations that either actively pursue or fund research on coal quality.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Yao, S.C.; Manwani, P.

Coal-water slurries have been regarded as a potential substitute for heavy fuel oil. Various demonstrations of coal-water slurry combustion have been performed; however, a fundamental understanding of how the combustion process of a slurry fuel is enhanced is still not adequate. The combustion of coal-water mixture droplets suspended on microthermocouples has been investigated. It was found that droplets of lignite coal (which is a noncaking coal) burn effectively; however, droplets of bituminous coal (which is a caking coal) are relatively difficult to burn. During the heat-up of bituminous coal-water slurry droplets may turn to ''popcorn'' and show significant agglomeration. Themore » incomplete combustion of coal-water slurry droplets in furnaces has been reported, and this is a drawback of this process. The objective of the present study is to explore the possibility of enhancing the combustion of coal-water slurry droplets with the use of a combustible emulsified oil.« less

Correlation chart of Pennsylvanian rocks in Alabama, Tennessee, Kentucky, Virginia, West Virginia, Ohio, Maryland, and Pennsylvania showing approximate position of coal beds, coal zones, and key stratigraphic units

USGS Publications Warehouse

Ruppert, Leslie F.; Trippi, Michael H.; Slucher, Ernie R.

2010-01-01

This report contains a simplified provisional correlation chart that was compiled from both published and unpublished data in order to fill a need to visualize the currently accepted stratigraphic relations between Appalachian basin formations, coal beds and coal zones, and key stratigraphic units in the northern, central, and southern Appalachian basin coal regions of Alabama, Tennessee, Kentucky, Virginia, West Virginia, Ohio, Maryland, and Pennsylvania. Appalachian basin coal beds and coal zones were deposited in a variety of geologic settings throughout the Lower, Middle, and Upper Pennsylvanian and Pennsylvanian formations were defined on the presence or absence of economic coal beds and coarse-grained sandstones that often are local or regionally discontinuous. The correlation chart illustrates how stratigraphic units (especially coal beds and coal zones) and their boundaries can differ between States and regions.

Characterization of the chemical variation of feed coal and coal combustion products from a power plant utilizing low sulfur Powder River Basin coal

DOE Office of Scientific and Technical Information (OSTI.GOV)

Affolter, R.H.; Brownfield, M.E.; Cathcart, J.D.

2000-07-01

The US Geological Survey and the University of Kentucky Center for Applied Energy Research, in collaboration with an Indiana utility, are studying a coal-fired power plant burning Powder River Basin coal. This investigation involves a systematic study of the chemical and mineralogical characteristics of feed coal and coal combustion products (CCPs) from a 1,300-megawatt (MW) power unit. The main goal of this study is to characterize the temporal chemical variability of the feed coal, fly ash, and bottom ash by looking at the major-, minor-, and trace-element compositions and their associations with the feed coal mineralogy. Emphasis is also placedmore » on the abundance and modes of occurrence of elements of potential environmental concern that may affect the utilization of these CCPs and coals.« less

2006 SME annual meeting & 7th ICARD, March 26-29, 2006, St. Louis, Missouri. Pre-prints

DOE Office of Scientific and Technical Information (OSTI.GOV)

NONE

2006-07-01

Subjects covered by the papers include: enhanced coalbed methane through carbon sequestration, application of laser surface coatings for raw coal screen wear resistance enhancement, application of cross-flow teeter-bed separator in the US coal industry, arsenic removal from drinking water, modelling of fire spread along combustibles in a mine entry, coal's role in sustaining society, real time characterisation of frother bubble thin films, diesel emissions, overcoming stress measurements form underground coal amines, dry jigging coal, estimation of roof strata strength, improving screen bowl centrifuge performance, installation of ventilation shaft at a New Mexico coal mine, evaluation of feasibility of CO{sub 2}more » sequestration in deep coal, robot-human control interaction in mining operations, small mine and contractor safety, coal dust explosibility meter, US coal mine fatalities versus age of mine, and water and slurry bulkheads in underground coal mines.« less

Coal Combustion Science quarterly progress report, April--June 1992

DOE Office of Scientific and Technical Information (OSTI.GOV)

Hardesty, D.R.; Hurt, R.H.; Baxter, L.L.

1992-09-01

The objective of this work is to support the Office of Fossil Energy in executing research on coal combustion science. This project consists of basic research on coal combustion that supports both the Pittsburgh Energy Technology Center (PETC) Direct Utilization Advanced Research and Technology Development Program, and the International Energy Agency (IEA) Coal Combustion Science Project. Specific tasks include: The characterization of the physical and chemical processes that constitute the early devolatilization phase of coal combustion: Characterization of the combustion behavior of selected coals under conditions relevant to industria pulverized coal-fired furnaces; and to establish a quantitative understanding of themore » mechanisms and rates of transformation, fragmentation, and deposition of mineral matter in coal combustion environments as a function of coal type, particle size and temperature, the initial forms and distributions of mineral species in the unreacted coal, and the local gas temperature and composition.« less

Utilization of coal as a source of chemicals

DOE Office of Scientific and Technical Information (OSTI.GOV)

Demirbas, A.

Coal consists carbon-based substances can be used as a source of specialty aromatic chemicals and aliphatic chemicals. Four widespread processes allow for making chemicals from coals: gasification, liquefaction, direct conversion, and co-production of chemicals and fuels along with electricity. Coal is gasified to produce synthesis gas (syngas) with a gasifier which is then converted to paraffinic liquid fuels and chemicals by Fischer-Tropsch synthesis. Liquid product from coal gasification mainly contains benzene, toluene, xylene (BTX), phenols, alkylphenols, and cresol. Methanol is made using coal or syngas with hydrogen and carbon monoxide in a 2 to 1 ratio. Coal-derived methanol has manymore » preferable properties as it is free of sulfur and other impurities. Syngas from coal can be reformed to hydrogen. Ammonium sulfate from coal tar by pyrolysis can be converted to ammonia. The humus substances can be recovered from brown coal by alkali extraction.« less

From in-situ coal to fly ash: A study of coal mines and power plants from Indiana

USGS Publications Warehouse

Mastalerz, Maria; Hower, J.C.; Drobniak, A.; Mardon, S.M.; Lis, G.

2004-01-01

This paper presents data on the properties of coal and fly ash from two coal mines and two power plants that burn single-source coal from two mines in Indiana. One mine is in the low-sulfur (5%) Springfield Coal Member of the Petersburg Formation (Pennsylvanian). Both seams have comparable ash contents (???11%). Coals sampled at the mines (both raw and washed fractions) were analyzed for proximate/ultimate/sulfur forms/heating value, major oxides, trace elements and petrographic composition. The properties of fly ash from these coals reflect the properties of the feed coal, as well as local combustion and post-combustion conditions. Sulfur and spinel content, and As, Pb and Zn concentrations of the fly ash are the parameters that most closely reflect the properties of the source coal. ?? 2004 Elsevier B.V. All rights reserved.

The upgrade of the CMS hadron calorimeter with silicon photomultipliers

DOE PAGES

Strobbe, N.

2017-01-26

The upgrade of the hadron calorimeter of the CMS experiment at the CERN Large Hadron Collider is currently underway. The endcap sections will be upgraded in the winter of 2016–2017 and the barrel sections during the second LHC long shutdown in 2019. The existing photosensors will be replaced with about 16 000 new silicon photomultipliers (SiPMs), resulting in the first large installation of SiPMs in a radiation environment. All associated front-end electronics will also be upgraded. Here, this paper discusses the motivation for the upgrade and provides a description 17 of the new system, including the SiPMs with associated controlmore » electronics and the front-end readout cards.« less

Biogas upgrading and utilization: Current status and perspectives.

PubMed

Angelidaki, Irini; Treu, Laura; Tsapekos, Panagiotis; Luo, Gang; Campanaro, Stefano; Wenzel, Henrik; Kougias, Panagiotis G

Biogas production is an established sustainable process for simultaneous generation of renewable energy and treatment of organic wastes. The increasing interest of utilizing biogas as substitute to natural gas or its exploitation as transport fuel opened new avenues in the development of biogas upgrading techniques. The present work is a critical review that summarizes state-of-the-art technologies for biogas upgrading and enhancement with particular attention to the emerging biological methanation processes. The review includes comprehensive description of the main principles of various biogas upgrading methodologies, scientific and technical outcomes related to their biomethanation efficiency, challenges that have to be addressed for further development and incentives and feasibility of the upgrading concepts. Copyright © 2018 Elsevier Inc. All rights reserved.

Explosive fluid transmitted shock method for mining deeply buried coal

DOEpatents

Archibald, Paul B.

1976-06-22

A method for recovering coal from deeply buried deposits comprising drilling a hole down into a coal seam, filling the hole with water, and periodically detonating an explosive charge at the bottom of the water-filled hole. The water transmits the explosive shock wave to the face of the coal seam, thereby fracturing and dislodging the coal. The resulting suspension of loose coal in water is then pumped to the surface where the coal is recovered and the water is recycled to the mining operation.

Meeting today's challenges to supply tomorrow's energy. Clean fossil energy technical and policy seminar

DOE Office of Scientific and Technical Information (OSTI.GOV)

NONE

2005-07-01

Papers discussed the coal policy of China, Russia, Indonesia and Vietnam; clean coal technology (small-scale coal power plants, carbon capture and sequestration, new coking process SCOPE21, coal gasification (HyPr-RING), CO{sub 2} reduction technology, Supercritical coal-fired units and CFB boilers, EAGLE project, coal liquefaction), the coal consumer's view of clean fossil energy policy, and natural gas policy and technology. Some of the papers only consist of the presentation overheads/viewgraphs.

Assessment of coal geology, resources, and reserves in the Montana Powder River Basin

USGS Publications Warehouse

Haacke, Jon E.; Scott, David C.; Osmonson, Lee M.; Luppens, James A.; Pierce, Paul E.; Gunderson, Jay A.

2013-01-01

The purpose of this report is to summarize geology, coal resources, and coal reserves in the Montana Powder River Basin assessment area in southeastern Montana. This report represents the fourth assessment area within the Powder River Basin to be evaluated in the continuing U.S. Geological Survey regional coal assessment program. There are four active coal mines in the Montana Powder River Basin assessment area: the Spring Creek and Decker Mines, both near Decker; the Rosebud Mine, near Colstrip; and the Absaloka Mine, west of Colstrip. During 2011, coal production from these four mines totaled approximately 36 million short tons. A fifth mine, the Big Sky, had significant production from 1969-2003; however, it is no longer in production and has since been reclaimed. Total coal production from all five mines in the Montana Powder River Basin assessment area from 1968 to 2011 was approximately 1.4 billion short tons. The Rosebud/Knobloch coal bed near Colstrip and the Anderson, Dietz 2, and Dietz 3 coal beds near Decker contain the largest deposits of surface minable, low-sulfur, subbituminous coal currently being mined in the assessment area. A total of 26 coal beds were identified during this assessment, 18 of which were modeled and evaluated to determine in-place coal resources. The total original coal resource in the Montana Powder River Basin assessment area for the 18 coal beds assessed was calculated to be 215 billion short tons. Available coal resources, which are part of the original coal resource remaining after subtracting restrictions and areas of burned coal, are about 162 billion short tons. Restrictions included railroads, Federal interstate highways, urban areas, alluvial valley floors, state parks, national forests, and mined-out areas. It was determined that 10 of the 18 coal beds had sufficient areal extent and thickness to be evaluated for recoverable surface resources ([Roland (Baker), Smith, Anderson, Dietz 2, Dietz 3, Canyon, Werner/Cook, Pawnee, Rosebud/Knobloch, and Flowers-Goodale]). These 10 coal beds total about 151 billion short tons of the 162 billion short tons of available resource; however, after applying a strip ratio of 10:1 or less, only 39 billion short tons remains of the 151 billion short tons. After mining and processing losses are subtracted from the 39 billion short tons, 35 billion short tons of coal were considered as a recoverable resource. Coal reserves (economically recoverable coal) are the portion of the recoverable coal resource that can be mined, processed, and marketed at a profit at the time of the economic evaluation. The surface coal reserve estimate for the 10 coal beds evaluated for the Montana Powder River assessment area is 13 billion short tons. It was also determined that about 42 billion short tons of underground coal resource exists in the Montana Powder River Basin assessment area; about 34 billion short tons (80 percent) are within 500-1,000 feet of the land surface and another 8 billion short tons are 1,000-2,000 feet beneath the land surface.

Naturally Occurring Radioactive Materials in Uranium-Rich Coals and Associated Coal Combustion Residues from China.

PubMed

Lauer, Nancy; Vengosh, Avner; Dai, Shifeng

2017-11-21

Most coals in China have uranium concentrations up to 3 ppm, yet several coal deposits are known to be enriched in uranium. Naturally occurring radioactive materials (NORM) in these U-rich coals and associated coal combustion residues (CCRs) have not been well characterized. Here we measure NORM (Th, U, 228 Ra, 226 Ra, and 210 Pb) in coals from eight U-rich coal deposits in China and the associated CCRs from one of these deposits. We compared NORM in these U-rich coals and associated CCRs to CCRs collected from the Beijing area and natural loess sediments from northeastern China. We found elevated U concentrations (up to 476 ppm) that correspond to low 232 Th/ 238 U and 228 Ra/ 226 Ra activity ratios (≪1) in the coal samples. 226 Ra and 228 Ra activities correlate with 238 U and 232 Th activities, respectively, and 226 Ra activities correlate well with 210 Pb activities across all coal samples. We used measured NORM activities and ash yields in coals to model the activities of CCRs from all U-rich coals analyzed in this study. The activities of measured and modeled CCRs derived from U-rich coals exceed the standards for radiation in building materials, particularly for CCRs originating from coals with U > 10 ppm. Since beneficial use of high-U Chinese CCRs in building materials is not a suitable option, careful consideration needs to be taken to limit potential air and water contamination upon disposal of U- and Ra-rich CCRs.

Progression in sulfur isotopic compositions from coal to fly ash: Examples from single-source combustion in Indiana

USGS Publications Warehouse

Yaofa, Jiang; Elswick, E.R.; Mastalerz, Maria

2008-01-01

Sulfur occurs in multiple mineral forms in coals, and its fate in coal combustion is still not well understood. The sulfur isotopic composition of coal from two coal mines in Indiana and fly ash from two power plants that use these coals were studied using geological and geochemical methods. The two coal beds are Middle Pennsylvanian in age; one seam is the low-sulfur ( 5%) Springfield Coal Member of the Petersburg Formation. Both seams have ash contents of approximately 11%. Fly-ash samples were collected at various points in the ash-collection system in the two plants. The results show notable difference in ??34S for sulfur species within and between the low-sulfur and high-sulfur coal. The ??34S values for all sulfur species are exclusively positive in the low-sulfur Danville coal, whereas the ??34S values for sulfate, pyritic, and organic sulfur are both positive and negative in the high-sulfur Springfield coal. Each coal exhibits a distinct pattern of stratigraphic variation in sulfur isotopic composition. Overall, the ??34S for sulfur species values increase up the section in the low-sulfur Danville coal, whereas they show a decrease up the vertical section in the high-sulfur Springfield coal. Based on the evolution of ??34S for sulfur species, it is suggested that there was influence of seawater on peat swamp, with two marine incursions occurring during peat accumulation of the high-sulfur Springfield coal. Therefore, bacterial sulfate reduction played a key role in converting sulfate into hydrogen sulfide, sulfide minerals, and elemental sulfur. The differences in ??34S between sulfate sulfur and pyritic sulfur is very small between individual benches of both coals, implying that some oxidation occurred during deposition or postdeposition. The ??34S values for fly ash from the high-sulfur Springfield coal (averaging 9.7???) are greatly enriched in 34S relative to those in the parent coal (averaging 2.2???). This indicates a fractionation of sulfur isotopes during high-sulfur coal combustion. By contrast, the ??34S values for fly-ash samples from the low-sulfur Danville coal average 10.2???, only slightly enriched in 34S relative to those from the parent coal (average 7.5???). The ??34S values for bulk S determined directly from the fly-ash samples show close correspondence with the ??34S values for SO4- 2 leached from the fly ash in the low-sulfur coal, suggesting that the transition from pyrite to sulfate occurred via high-temperature oxidation during coal combustion. ?? 2007 Elsevier B.V. All rights reserved.

Environmental Life Cycle Assessment and Cost Analysis of Bath, NY Wastewater Treatment Plant: Potential Upgrade Implications

EPA Science Inventory

Many communities across the U.S. are required to upgrade wastewater treatment plants (WWTP) to meet increasingly stringent nutrient effluent standards. However, increased capital, energy and chemical requirements of upgrades create potential trade-offs between eutrophication pot...

Hydrocarbonaceous material upgrading method

DOEpatents

Brecher, Lee E.; Mones, Charles G.; Guffey, Frank D.

2015-06-02

A hydrocarbonaceous material upgrading method may involve a novel combination of heating, vaporizing and chemically reacting hydrocarbonaceous feedstock that is substantially unpumpable at pipeline conditions, and condensation of vapors yielded thereby, in order to upgrade that feedstock to a hydrocarbonaceous material condensate that meets crude oil pipeline specification.

Innovation in biological production and upgrading of methane and hydrogen for use as gaseous transport biofuel.

PubMed

Xia, Ao; Cheng, Jun; Murphy, Jerry D

2016-01-01

Biofuels derived from biomass will play a major role in future renewable energy supplies in transport. Gaseous biofuels have superior energy balances, offer greater greenhouse gas emission reductions and produce lower pollutant emissions than liquid biofuels. Biogas derived through fermentation of wet organic substrates will play a major role in future transport systems. Biogas (which is composed of approximately 60% methane/hydrogen and 40% carbon dioxide) requires an upgrading process to reduce the carbon dioxide content to less than 3% before it is used as compressed gas in transport. This paper reviews recent developments in fermentative biogas production and upgrading as a transport fuel. Third generation gaseous biofuels may be generated using marine-based algae via two-stage fermentation, cogenerating hydrogen and methane. Alternative biological upgrading techniques, such as biological methanation and microalgal biogas upgrading, have the potential to simultaneously upgrade biogas, increase gaseous biofuel yield and reduce carbon dioxide emission. Copyright © 2015 Elsevier Inc. All rights reserved.

76 FR 68501 - Notice of Availability and Notice of Hearing for the Alton Coal Tract Coal Lease by Application...

Federal Register 2010, 2011, 2012, 2013, 2014

2011-11-04

... Availability and Notice of Hearing for the Alton Coal Tract Coal Lease by Application Draft Environmental... Impact Statement (EIS) for the Alton Coal Tract Lease by Application (LBA) and by this Notice is... the Fair Market Value (FMV) of the Federal coal resources. DATES: To ensure comments will be...

43 CFR 3436.1-2 - Federal coal deposits subject to lease by exchange.

Code of Federal Regulations, 2012 CFR

2012-10-01

... 43 Public Lands: Interior 2 2012-10-01 2012-10-01 false Federal coal deposits subject to lease by... Coal Lease and Coal Land Exchanges: Alluvial Valley Floors § 3436.1-2 Federal coal deposits subject to lease by exchange. The lease offered by the Secretary in exchange for existing coal leases shall be for...

Apparatus and method for feeding coal into a coal gasifier

DOEpatents

Bissett, Larry A.; Friggens, Gary R.; McGee, James P.

1979-01-01

This invention is directed to a system for feeding coal into a gasifier operating at high pressures. A coal-water slurry is pumped to the desired pressure and then the coal is "dried" prior to feeding the coal into the gasifier by contacting the slurry with superheated steam in an entrained bed dryer for vaporizing the water in the slurry.

43 CFR 3436.1-2 - Federal coal deposits subject to lease by exchange.

Code of Federal Regulations, 2011 CFR

2011-10-01

... 43 Public Lands: Interior 2 2011-10-01 2011-10-01 false Federal coal deposits subject to lease by... Coal Lease and Coal Land Exchanges: Alluvial Valley Floors § 3436.1-2 Federal coal deposits subject to lease by exchange. The lease offered by the Secretary in exchange for existing coal leases shall be for...

Chemical comminution and deashing of low-rank coals

DOEpatents

Quigley, David R.

1992-01-01

A method of chemically comminuting a low-rank coal while at the same time increasing the heating value of the coal. A strong alkali solution is added to a low-rank coal to solubilize the carbonaceous portion of the coal, leaving behind the noncarbonaceous mineral matter portion. The solubilized coal is precipitated from solution by a multivalent cation, preferably calcium.

Chemical comminution and deashing of low-rank coals

DOEpatents

Quigley, David R.

1992-12-01

A method of chemically comminuting a low-rank coal while at the same time increasing the heating value of the coal. A strong alkali solution is added to a low-rank coal to solubilize the carbonaceous portion of the coal, leaving behind the noncarbonaceous mineral matter portion. The solubilized coal is precipitated from solution by a multivalent cation, preferably calcium.

Process to improve boiler operation by supplemental firing with thermally beneficiated low rank coal

DOEpatents

Sheldon, Ray W.

2001-01-01

The invention described is a process for improving the performance of a commercial coal or lignite fired boiler system by supplementing its normal coal supply with a controlled quantity of thermally beneficiated low rank coal, (TBLRC). This supplemental TBLRC can be delivered either to the solid fuel mill (pulverizer) or directly to the coal burner feed pipe. Specific benefits are supplied based on knowledge of equipment types that may be employed on a commercial scale to complete the process. The thermally beneficiated low rank coal can be delivered along with regular coal or intermittently with regular coal as the needs require.

Coal liquefaction process utilizing coal/CO.sub.2 slurry feedstream

DOEpatents

Comolli, Alfred G.; McLean, Joseph B.

1989-01-01

A coal hydrogenation and liquefaction process in which particulate coal feed is pressurized to an intermediate pressure of at least 500 psig and slurried with CO.sub.2 liquid to provide a flowable coal/CO.sub.2 slurry feedstream, which is further pressurized to at least 1000 psig and fed into a catalytic reactor. The coal particle size is 50-375 mesh (U.S. Sieve Series) and provides 50-80 W % coal in the coal/CO.sub.2 slurry feedstream. Catalytic reaction conditions are maintained at 650.degree.-850.degree. F. temperature, 1000-4000 psig hydrogen partial pressure and coal feed rate of 10-100 lb coal/hr ft.sup.3 reactor volume to produce hydrocarbon gas and liquid products. The hydrogen and CO.sub.2 are recovered from the reactor effluent gaseous fraction, hydrogen is recycled to the catalytic reactor, and CO.sub.2 is liquefied and recycled to the coal slurrying step. If desired, two catalytic reaction stages close coupled together in series relation can be used. The process advantageously minimizes the recycle and processing of excess hydrocarbon liquid previously needed for slurrying the coal feed to the reactor(s).