Preliminary hydrogeologic investigation of the Maxey Flats radioactive waste burial site, Fleming County, Kentucky

USGS Publications Warehouse

Zehner, Harold H.

1979-01-01

Burial trenches at the Maxey Flats radioactive waste burial site , Fleming County, Ky., cover an area of about 0.03 square mile, and are located on a plateau, about 300 to 400 feet above surrounding valleys. Although surface-water characteristics are known, little information is available regarding the ground-water hydrology of the Maxey Flats area. If transport of radionuclides from the burial site were to occur, water would probably be the principal mechanism of transport by natural means. Most base flow in streams around the burial site is from valley alluvium, and from the mantle of regolith, colluvium, and soil partially covering adjacent hills. Very little base flow is due to ground-water flow from bedrock. Most water in springs is from the mantle, rather than from bedrock. Rock units underlying the Maxey Flats area are, in descending order, the Nancy and Farmers Members of the Borden Formation, Sunbury, Bedford, and Ohio Shales, and upper part of the Crab Orchard Formation. These units are mostly shales, except for the Farmers Member, which is mostly sandstone. Total thickness of the rocks is about 320 feet. All radioactive wastes are buried in the Nancy Member. Most ground-water movement in bedrock probably occurs in fractures. The ground-water system at Maxey Flats is probably unconfined, and recharge occurs by (a) infiltration of rainfall into the mantle, and (b) vertical, unsaturated flow from the saturated regolith on hilltops to saturated zones in the Farmers Member and Ohio Shale. Data are insufficient to determine if saturated zones exist in other rock units. The upper part of the Crab Orchard Formation is probably a hydrologic boundary, with little ground-water flow through the formation. (USGS)

Preferential Flow Paths In A Karstified Spring Catchment: A Study Of Fault Zones As Conduits To Rapid Groundwater Flow

NASA Astrophysics Data System (ADS)

Kordilla, J.; Terrell, A. N.; Veltri, M.; Sauter, M.; Schmidt, S.

2017-12-01

In this study we model saturated and unsaturated flow in the karstified Weendespring catchment, located within the Leinetal graben in Goettingen, Germany. We employ the finite element COMSOL Multiphysics modeling software to model variably saturated flow using the Richards equation with a van Genuchten type parameterization. As part of the graben structure, the Weende spring catchment is intersected by seven fault zones along the main flow path of the 7400 m cross section of the catchment. As the Weende spring is part of the drinking water supply in Goettingen, it is particularly important to understand the vulnerability of the catchment and effect of fault zones on rapid transport of contaminants. Nitrate signals have been observed at the spring only a few days after the application of fertilizers within the catchment at a distance of approximately 2km. As the underlying layers are known to be highly impermeable, fault zones within the area are likely to create rapid flow paths to the water table and the spring. The model conceptualizes the catchment as containing three hydrogeological limestone units with varying degrees of karstification: the lower Muschelkalk limestone as a highly conductive layer, the middle Muschelkalk as an aquitard, and the upper Muschelkalk as another conductive layer. The fault zones are parameterized based on a combination of field data from quarries, remote sensing and literary data. The fault zone is modeled considering the fracture core as well as the surrounding damage zone with separate, specific hydraulic properties. The 2D conceptual model was implemented in COMSOL to study unsaturated flow at the catchment scale using van Genuchten parameters. The study demonstrates the importance of fault zones for preferential flow within the catchment and its effect on the spatial distribution of vulnerability.

Magmatic processes in the layered Series of the Skaergaard intrusion inferred from core and rim compositions of plagioclase

NASA Astrophysics Data System (ADS)

Brown, W. L.; Toplis, M. J.

2003-04-01

Due to slow NaSi-CaAl exchange in plagioclase, the proportion of the anorthite component (An) may be considered essentially a primary feature in magmatic bodies such as small layered intrusions. Thus, An provides a potential window into the evolution of such magmatic systems on various length scales. In order to assess the utility of this approach, 13 thin sections covering the principal zones and sub-zones of the Layered Series of the Skaergaard intrusion, East Greenland, were studied. In each thin section 90 to 150 analyses of plagioclase were made using an electron microprobe. Analyses were made in grain centres and at grain edges, particular attention being paid to plagioclase-plagioclase contacts. The cores of large and moderately sized crystals show narrow compositional ranges, 90% of analyses lying within 3 mol% of the mean. In accordance with previous studies, we find that mean core compositions vary continuously with stratigraphic height, from ˜An70 at the lowest levels, to ˜An30 at the top of Upper Zone (UZ). Rim compositions of touching plagioclase also show strong maxima in their mode, but the variation of this composition with stratigraphic height is distinctly different from that of crystal cores. In the Lower Zone (LZ) and lower Middle Zone (MZ), the most abundant rim compositions are systematically An50± 1, core and rim compositions converging in the lower MZ. In the upper MZ to UZ, rim compositions are very similar to corresponding cores, but locally may be more evolved, particularly when plagioclase is intergrown with quartz. The systematic decrease of An as a function of stratigraphic height is strong evidence in favour of fractional crystallization of the main liquid. However, the fact that plagioclase zoning does not extend to nearly pure albite in the vast majority of rocks implies mobility of intercumulus liquid. If compaction (expulsion) were the mechanism responsible for this, it would be difficult to explain the remarkably constant cut-off in rim compositions at An50 in the LZ and lower MZ. On the other hand, this cut-off corresponds to the An content at magnetite saturation, which leads us to propose that the observed features are the result of a density inversion in the liquid following oxide saturation. This density inversion causes the intercumulus liquid to become gravitationally unstable relative to the overlying main liquid leading to compositional convection in the upper LZ and MZ, a hypothesis consistent with the adcumulus texture of those rocks.

Determining the vertical evolution of hydrodynamic parameters in weathered and fractured south Indian crystalline-rock aquifers: insights from a study on an instrumented site

NASA Astrophysics Data System (ADS)

Boisson, A.; Guihéneuf, N.; Perrin, J.; Bour, O.; Dewandel, B.; Dausse, A.; Viossanges, M.; Ahmed, S.; Maréchal, J. C.

2015-02-01

Due to extensive irrigation, most crystalline aquifers of south India are overexploited. Aquifer structure consists of an upper weathered saprolite followed by a fractured zone whose fracture density decreases with depth. To achieve sustainable management, the evolution of hydrodynamic parameters (transmissivity and storage coefficient) by depth in the south Indian context should be quantified. Falling-head borehole permeameter tests, injection tests, flowmeter profiles, single-packer tests and pumping tests were carried out in the unsaturated saprolite and saturated fractured granite. Results show that the saprolite is poorly transmissive (T fs = 3 × 10-7 to 8.5 × 10-8 m2 s-1) and that the most conductive part of the aquifer corresponds to the bottom of the saprolite and the upper part of the fractured rock (T = 1.0 × 10-3 to 7.0 × 10-4 m2 s-1). The transmissivity along the profile is mostly controlled by two distinct conductive zones without apparent vertical hydraulic connection. The transmissivity and storage coefficient both decrease with depth depending on the saturation of the main fracture zones, and boreholes are not exploitable after a certain depth (27.5 m on the investigated section). The numerous investigations performed allow a complete quantification with depth of the hydrodynamic parameters along the weathering profile, and a conceptual model is presented. Hydrograph observations (4 years) are shown to be relevant as a first-order characterization of the media and diffusivity evolution with depth. The evolution of these hydrodynamic parameters along the profile has a great impact on groundwater prospecting, exploitation and transport properties in such crystalline rock aquifers.

Electrical resistivity and porosity structure of the upper Biscayne Aquifer in Miami-Dade County, Florida

NASA Astrophysics Data System (ADS)

Whitman, Dean; Yeboah-Forson, Albert

2015-12-01

Square array electrical soundings were made at 13 sites in the Biscayne Aquifer distributed between 1 and 20 km from the shoreline. These soundings were modeled to investigate how resistivity varies spatially and with depth in the upper 15 m of the aquifer. Porosity was estimated from the modeled formation resistivity and observed pore fluid resistivity with Archie's Law. The models were used to interpolate resistivity and porosity surfaces at -2, -5, -8, and -15 m elevations. Modeled resistivity in the unsaturated zone is generally higher than 300 Ω m with the resistivity at sites with thick unsaturated zones greater than 1000 Ω m. Resistivity in the saturated zone ranges from 30 to 320 Ω m. At many sites in the western portions of the study area, resistivity is constant or increases with depth whereas sites in the center of the Atlantic Coastal Ridge exhibit a distinct low resistivity zone (ρ < 45 Ω m) at elevations ranging between -5 and -10 m. At one site near the shore of Biscayne Bay, the resistivity is less than 10 Ω m at -5 m elevation reflecting the presence of salt water in the aquifer. The estimated porosity ranges between 14% and 71% with modal values near 25%. The porosity structure varies both with depth and spatially. Western sites exhibit a high porosity zone at shallow depths best expressed in a NE-SW trending zone of 40-50% porosity situated near the western margin of the Atlantic Coastal Ridge. This zone roughly corresponds in depth with the Q5 chronostratigraphic unit of the Miami Fm. which constitutes the upper flow unit of the Biscayne Aquifer. The highest porosity (>50%) is seen at elevations below -5 m at sites in the center of the Atlantic Coastal Ridge and likely corresponds to solution features. The general NE-SW trend of the resistivity and porosity structure suggests a causal connection with the Pleistocene paleogeography and sedimentary environments.

Stable isotope tracing of anaerobic methane oxidation in the gassy sediments of Eckernfoerde Bay, German Baltic Sea

DOE Office of Scientific and Technical Information (OSTI.GOV)

Martens, C.S.; Albert, D.B.; Alperin, M.J.

Methane concentrations in the pore waters of Eckernfoerde Bay in the German Baltic Sea generally reach gas bubble saturation values within the upper meter of the sediment column. The depth at which saturation occurs is controlled by a balance between rates of methane production, consumption (oxidation), and transport. The relative importance of anaerobic methane oxidation (AMO) in controlling dissolved and gas bubble methane distributions in the bay's sediments is indirectly revealed through methane concentration versus depth profiles, depth variations in the stable C and H isotope composition of methane, and the C isotope composition of total dissolved inorganic carbon ({Sigma}CO{submore » 2}). Direct radiotracer measurements indicate that AMO rates of over 15 mM/yr are focused at the base of the sulfate reduction zone. Diagenetic equations that describe the depth destructions of the {delta}{sup 13}C and {delta}D values of methane reproduce isotopic shifts observed throughout the methane oxidation zone and are best fit with kinetic isotope fractionation factors of 1.012 {+-} 0.001 and 1.120 {plus{underscore}minus} 0.020 respectively.« less

Sr-90 Immobilization by Infiltration of a Ca-Citrate-PO{sub 4} Solution into the Hanford 100-N Area Vadose Zone

DOE Office of Scientific and Technical Information (OSTI.GOV)

Szecsody, J.E.; Fruchter, J.S.; Burns, C.A.

This project was initiated to develop a strategy for infiltration of a Ca-citrate-PO{sub 4} solution in order to precipitate apatite [Ca{sub 6}(PO{sub 4}){sub 10}(OH){sub 2}] in desired locations in the vadose zone for Sr-90 remediation. Laboratory experiments have demonstrated that infiltration of a Ca-citrate-PO{sub 4} solution into sediments at low and high water saturation results in citrate biodegradation and formation of apatite. The citrate biodegradation rate was relatively uniform, in spite of the spatial variability of sediment microbial biomass, likely because of microbial transport processes that occur during solution infiltration. The precipitate was characterized as hydroxyapatite, and the Sr-90 substitutionmore » into apatite was shown to have an incorporation half-life of 5.5 to 16 months. One and two dimensional (1-D and 2-D) laboratory infiltration experiments quantified the spatial distribution of apatite that formed during solution infiltration. Slow infiltration in 2-D experiments at low water saturation show the apatite precipitate concentrated in the upper third of the infiltration zone. More rapid 1-D infiltration studies show the apatite precipitate concentrated at greater depth. (authors)« less

Hydraulic characteristics and nutrient transport and transformation beneath a rapid infiltration basin, Reedy Creek Improvement District, Orange County, Florida

USGS Publications Warehouse

Sumner, D.M.; Bradner, L.A.

1996-01-01

The Reedy Creek Improvement District disposes of about 7.5 million gallons per day (1992) of reclaimed water through 85 1-acre rapid infiltration basins within a 1,000-acre area of sandy soils in Orange County, Florida. The U.S. Geological Survey conducted field experiments in 1992 at an individual basin to examine and better understand the hydraulic characteristics and nutrient transport and transformation of reclaimed water beneath a rapid infiltration basin. At the time, concentrations of total nitrogen and total phosphorus in reclaimed water were about 3 and 0.25 milligrams per liter, respectively. A two-dimensional, radial, unsaturated/saturated numerical flow model was applied to describe the flow system beneath a rapid infiltration basin under current and hypothetical basin loading scenarios and to estimate the hydraulic properties of the soil and sediment beneath a basin. The thicknesses of the unsaturated and saturated parts of the surficial aquifer system at the basin investigated were about 37 and 52 feet, respectively. The model successfully replicated the field-monitored infiltration rate (about 5.5 feet per day during the daily flooding periods of about 17 hours) and ground-water mounding response during basin operation. Horizontal and vertical hydraulic conductivity of the saturated part of the surficial aquifer system were estimated to be 150 and 45 feet per day, respectively. The field-saturated vertical hydraulic conductivity of the shallow soil, estimated to be about 5.1 feet per day, was considered to have been less than the full- saturation value because of the effects of air entrapment. Specific yield of the surficial aquifer was estimated to be 0.41. The upper 20 feet of the basin subsurface profile probably served as a system control on infiltration because of the relatively low field-saturated, vertical hydraulic conductivity of the sediments within this layer. The flow model indicates that, in the vicinity of the basin, flow in the deeper, saturated zone was relatively slow compared to the more vigorous flow in the shallow saturated zone. The large radial component of flow below the water table in the vicinity of the basin implies that reclaimed water moves preferentially in the shallow part of the saturated zone upon reaching the water table. Therefore, there may be some vertical stratification in the saturated zone, with recently infiltrated water overlying ambient water. The infiltration capacity at the basin would be unaffected by a small (less than 10 feet) increase in background water-table altitude, because the water table would remain below the system control on infiltration. However, water-table rises of 15 and 20 feet were estimated to reduce the infiltration capacity of the basin by 8 and 25 percent, respectively. Model simulations indicate that increasing ponded depth within the basin from 4 to 12 inches and from 4 to 24 inches would increase basin infiltration capacity by less than 6 and 11 percent, respectively. A loading strategy at the basin that relies on long, uninterrupted flooding was shown to offer the possibility of inducing a more anaerobic environment conducive to denitrification while maintaining reclaimed-water disposal capacity. Field measurements indicated that transient, elevated concentrations or "spikes" of nitrate (as high as 33 milligrams per liter as nitrogen) occurred at the leading edge of the infiltrating water and in the shallow saturated zone following a prolonged basin rest period. This phenomenon probably is the result of mineralization and nitrification of organic nitrogen retained with the subsurface during earlier basin loading events. The organic nitrogen was retained in the shallow soil (due to adsorption/straining) and the shallow saturated zone following a prolonged basin rest period. This phenomenon probably is the result of mineralization and nitrification of organic nitrogen retained within the subsurface during earlier basin loading event

Migration of contaminants through the unsaturated zone overlying the Hesbaye chalky aquifer in Belgium: a field investigation.

PubMed

Brouyère, Serge; Dassargues, Alain; Hallet, Vincent

2004-08-01

This paper presents the results of a detailed field investigation that was performed for studying groundwater recharge processes and solute downward migration mechanisms prevailing in the unsaturated zone overlying a chalk aquifer in Belgium. Various laboratory measurements were performed on core samples collected during the drilling of boreholes in the experimental site. In the field, experiments consisted of well logging, infiltration tests in the unsaturated zone, pumping tests in the saturated zone and tracer tests in both the saturated and unsaturated zones. Results show that gravitational flows govern groundwater recharge and solute migration mechanisms in the unsaturated zone. In the variably saturated chalk, the migration and retardation of solutes is strongly influenced by recharge conditions. Under intense injection conditions, solutes migrate at high speed along the partially saturated fissures, downward to the saturated zone. At the same time, they are temporarily retarded in the almost immobile water located in the chalk matrix. Under normal recharge conditions, fissures are inactive and solutes migrate slowly through the chalk matrix. Results also show that concentration dynamics in the saturated zone are related to fluctuations of groundwater levels in the aquifer. A conceptual model is proposed to explain the hydrodispersive behaviour of the variably saturated chalk. Finally, the vulnerability of the chalk to contamination issues occurring at the land surface is discussed.

Improved predictions of saturated and unsaturated zone drawdowns in a heterogeneous unconfined aquifer via transient hydraulic tomography: Laboratory sandbox experiments

NASA Astrophysics Data System (ADS)

Berg, Steven J.; Illman, Walter A.

2012-11-01

SummaryInterpretation of pumping tests in unconfined aquifers has largely been based on analytical solutions that disregard aquifer heterogeneity. In this study, we investigate whether the prediction of drawdown responses in a heterogeneous unconfined aquifer and the unsaturated zone above it with a variably saturated groundwater flow model can be improved by including information on hydraulic conductivity (K) and specific storage (Ss) from transient hydraulic tomography (THT). We also investigate whether these predictions are affected by the use of unsaturated flow parameters estimated through laboratory hanging column experiments or calibration of in situ drainage curves. To investigate these issues, we designed and conducted laboratory sandbox experiments to characterize the saturated and unsaturated properties of a heterogeneous unconfined aquifer. Specifically, we conducted pumping tests under fully saturated conditions and interpreted the drawdown responses by treating the medium to be either homogeneous or heterogeneous. We then conducted another pumping test and allowed the water table to drop, similar to a pumping test in an unconfined aquifer. Simulations conducted using a variably saturated flow model revealed: (1) homogeneous parameters in the saturated and unsaturated zones have a difficult time predicting the responses of the heterogeneous unconfined aquifer; (2) heterogeneous saturated hydraulic parameter distributions obtained via THT yielded significantly improved drawdown predictions in the saturated zone of the unconfined aquifer; and (3) considering heterogeneity of unsaturated zone parameters produced a minor improvement in predictions in the unsaturated zone, but not the saturated zone. These results seem to support the finding by Mao et al. (2011) that spatial variability in the unsaturated zone plays a minor role in the formation of the S-shape drawdown-time curve observed during pumping in an unconfined aquifer.

Evaluating the reliability of equilibrium dissolution assumption from residual gasoline in contact with water saturated sands

NASA Astrophysics Data System (ADS)

Lekmine, Greg; Sookhak Lari, Kaveh; Johnston, Colin D.; Bastow, Trevor P.; Rayner, John L.; Davis, Greg B.

2017-01-01

Understanding dissolution dynamics of hazardous compounds from complex gasoline mixtures is a key to long-term predictions of groundwater risks. The aim of this study was to investigate if the local equilibrium assumption for BTEX and TMBs (trimethylbenzenes) dissolution was valid under variable saturation in two dimensional flow conditions and evaluate the impact of local heterogeneities when equilibrium is verified at the scale of investigation. An initial residual gasoline saturation was established over the upper two-thirds of a water saturated sand pack. A constant horizontal pore velocity was maintained and water samples were recovered across 38 sampling ports over 141 days. Inside the residual NAPL zone, BTEX and TMBs dissolution curves were in agreement with the TMVOC model based on the local equilibrium assumption. Results compared to previous numerical studies suggest the presence of small scale dissolution fingering created perpendicular to the horizontal dissolution front, mainly triggered by heterogeneities in the medium structure and the local NAPL residual saturation. In the transition zone, TMVOC was able to represent a range of behaviours exhibited by the data, confirming equilibrium or near-equilibrium dissolution at the scale of investigation. The model locally showed discrepancies with the most soluble compounds, i.e. benzene and toluene, due to local heterogeneities exhibiting that at lower scale flow bypassing and channelling may have occurred. In these conditions mass transfer rates were still high enough to fall under the equilibrium assumption in TMVOC at the scale of investigation. Comparisons with other models involving upscaled mass transfer rates demonstrated that such approximations with TMVOC could lead to overestimate BTEX dissolution rates and underestimate the total remediation time.

Evaluating the reliability of equilibrium dissolution assumption from residual gasoline in contact with water saturated sands.

PubMed

Lekmine, Greg; Sookhak Lari, Kaveh; Johnston, Colin D; Bastow, Trevor P; Rayner, John L; Davis, Greg B

2017-01-01

Understanding dissolution dynamics of hazardous compounds from complex gasoline mixtures is a key to long-term predictions of groundwater risks. The aim of this study was to investigate if the local equilibrium assumption for BTEX and TMBs (trimethylbenzenes) dissolution was valid under variable saturation in two dimensional flow conditions and evaluate the impact of local heterogeneities when equilibrium is verified at the scale of investigation. An initial residual gasoline saturation was established over the upper two-thirds of a water saturated sand pack. A constant horizontal pore velocity was maintained and water samples were recovered across 38 sampling ports over 141days. Inside the residual NAPL zone, BTEX and TMBs dissolution curves were in agreement with the TMVOC model based on the local equilibrium assumption. Results compared to previous numerical studies suggest the presence of small scale dissolution fingering created perpendicular to the horizontal dissolution front, mainly triggered by heterogeneities in the medium structure and the local NAPL residual saturation. In the transition zone, TMVOC was able to represent a range of behaviours exhibited by the data, confirming equilibrium or near-equilibrium dissolution at the scale of investigation. The model locally showed discrepancies with the most soluble compounds, i.e. benzene and toluene, due to local heterogeneities exhibiting that at lower scale flow bypassing and channelling may have occurred. In these conditions mass transfer rates were still high enough to fall under the equilibrium assumption in TMVOC at the scale of investigation. Comparisons with other models involving upscaled mass transfer rates demonstrated that such approximations with TMVOC could lead to overestimate BTEX dissolution rates and underestimate the total remediation time. Copyright © 2016. Published by Elsevier B.V.

Effects of crude oil on water and tracer movement in the unsaturated and saturated zones.

PubMed

Delin, Geoffrey N; Herkelrath, William N

2017-05-01

A tracer test was conducted to aid in the investigation of water movement and solute transport at a crude-oil spill site near Bemidji, Minnesota. Time of travel was measured using breakthrough curves for rhodamine WT and bromide tracers moving from the soil surface through oil-contaminated and oil-free unsaturated zones to the saturated zone. Results indicate that the rates of tracer movement were similar in the oil-free unsaturated and saturated zones compared to the oily zones. These results are somewhat surprising given the oil contamination in the unsaturated and saturated zones. Rhodamine tracer breakthrough in the unsaturated and saturated zones in general was delayed in comparison to bromide tracer breakthrough. Peak tracer concentrations for the lysimeters and wells in the oily zone were much greater than at the corresponding depths in the oil-free zone. Water and tracer movement in the oily zone was complicated by soil hydrophobicity and decreased oil saturations toward the periphery of the oil. Preferential flow resulted in reduced tracer interaction with the soil, adsorption, and dispersion and faster tracer movement in the oily zone than expected. Tracers were freely transported through the oily zone to the water table. Recharge calculations support the idea that the oil does not substantially affect recharge in the oily zone. This is an important result indicating that previous model-based assumptions of decreased recharge beneath the oil were incorrect. Results have important implications for modeling the fate and transport of dissolved contaminants at hydrocarbon spill sites. Published by Elsevier B.V.

Temporal and spatial variabilities in the surface moisture content of a fine-grained beach

NASA Astrophysics Data System (ADS)

Namikas, S. L.; Edwards, B. L.; Bitton, M. C. A.; Booth, J. L.; Zhu, Y.

2010-01-01

This study examined spatial and temporal variations in the surface moisture content of a fine-grained beach at Padre Island, Texas, USA. Surface moisture measurements were collected on a 27 × 24 m grid that extended from the dune toe to the upper foreshore. The grid was surveyed at 2 to 4 h intervals for two tidal cycles, generating 17 maps of the spatial distribution of surface moisture. Simultaneous measurements of air temperature and humidity, wind speed and direction, tidal elevation, and water table elevation were used to interpret observed changes in surface moisture. It was found that the spatial distribution of surface moisture was broadly characterized by a cross-shore gradient of high to low content moving landward from the swash zone. The distribution of surface moisture was conceptualized in terms of three zones: saturated (> 25%), intermediate or transitional (5-25%), and dry (< 5%). The position of the saturated zone corresponded to the uppermost swash zone and therefore shifted in accordance with tidal elevation. Moisture contents in the intermediate and dry zones were primarily related to variation in water table depth (which was in turn controlled by tidal elevation) and to a lesser extent by evaporation. Signals associated with atmospheric processes such as evaporation were muted by the minimal degree of variation in atmospheric parameters experienced during most of the study period, but were apparent for the last few hours. The observed spatial and temporal variations in moisture content correspond reasonably well with observations of key controlling processes, but more work is needed to fully characterize this process suite.

Combining the Neuman and Boulton models for flow to a well in an unconfined aquifer

USGS Publications Warehouse

Moench, Allen F.

1995-01-01

A Laplace transform solution is presented for flow to a well in a homogeneous, water-table aquifer with noninstanta-neous drainage of water from the zone above the water table. The Boulton convolution integral is combined with Darcy's law and used as an upper boundary condition to replace the condition used by Neuman. Boulton's integral derives from the assumption that water drained from the unsaturated zone is released gradually in a manner that varies exponentially with time in response to a unit decline in hydraulic head, whereas the condition used by Newman assumes that the water is released instantaneously. The result is a solution that reduces to the solution obtained by Neuman as the rate of release of water from the zone above the water table increases. A dimensionless fitting parameter, γ, is introduced that incorporates vertical hydraulic conductivity, saturated thickness, specific yield, and an empirical constant α1, similar to Boulton's α. Results show that theoretical drawdown in water-table piezometers is amplified by noninstantaneous drainage from the unsaturated zone to a greater extent than drawdown in piezometers located at depth in the saturated zone. This difference provides a basis for evaluating γ by type-curve matching in addition to the other dimensionless parameters. Analysis of drawdown in selected piezometers from the published results of two aquifer tests conducted in relatively homogeneous glacial outwash deposits but with significantly different hydraulic conductivities reveals improved comparison between the theoretical type curves and the hydraulic head measured in water-table piezometers.

A new perspective on the generation of the 2016 M6.4 Meilung earthquake, southwestern Taiwan

NASA Astrophysics Data System (ADS)

Wang, Z.

2017-12-01

In order to investigate the likely generation mechanism of the 2016 M6.4 Meilung earthquake, a large number of high-quality travel times from P- and S-wave source-receiver pairs are used jointly in this study to invert three-dimensional (3-D) seismic velocity (Vp, Vs) and Poisson's ratio structures at high resolution. We also calculated crack density, saturate fracture, and bulk-sound velocity from our inverted Vp, Vs, and s models. In this way, multi-geophysical parameter imaging revealed that the 2016 Meilung earthquake occurred along a distinctive edge portion exhibiting high-to-low variations in these parameters in both horizontal and vertical directions across the hypocenter. We consider that a slow velocity and high-Poisson ratio body that has high-crack density and somewhat high-saturate fracture anomalies above the hypocenter under the coastal plain represents fluids contained in the young fold-and-thrust belt relative to the passive Asian continental margin in southwestern Taiwan. Intriguing, a continuous low Vp and Vs zone with high Poisson ratio, crack density and saturate fracture anomalies across the Laonung and Chishan faults is also clearly imaged in the northwestern upper crust beneath the coastal plain and western foothills as far as the southeastern lower crust under the central range. We therefore propose that this southeastern extending weakened zone was mainly the result of a fluid intrusion either from the young fold-and-thrust belt associated with the passive Asian continental margin in the shallow crust or the subducted Eurasian continental (EC) plate in the lower crust and uppermost mantle. We suggest that fluid intrusion into the upper Oligocene to Pleistocene shallow marine and clastic shelf units of the Eurasian continental crust and/or the relatively thin uppermost part of the transitional Pleistocene-Holocene foreland due to the subduction of the EC plate along the deformation front played a key role in earthquake generation in southwestern Taiwan. Such fluid penetration would reduce Vp, and Vs while increasing Poisson ratio and saturate fracture across the source area, leading to mechanical strength failure of the rock matrix in the relative weakened and brittle seismogenic layer and triggering the 2016 earthquake.

Making the most of CZ seismics: Improving shallow critical zone characterization using surface-wave analysis

NASA Astrophysics Data System (ADS)

Pasquet, S.; Wang, W.; Holbrook, W. S.; Bodet, L.; Carr, B.; Flinchum, B. A.

2017-12-01

Estimating porosity and saturation in the shallow subsurface over large lateral scales is vitally important for understanding the development and evolution of the Critical Zone (CZ). Because elastic properties (P- and S-wave velocities) are particularly sensitive to porosity and saturation, seismic methods (in combination with petrophysical models) are effective tools for mapping CZ architecture and processes. While many studies employ P-wave refraction methods, fewer use the surface waves that are typically also recorded in those same surveys. Here we show the value of exploiting surface waves to extract supplementary shear-wave velocity (Vs) information in the CZ. We use a new, user-friendly, open-source MATLAB-based package (SWIP) to invert surface-wave data and estimate lateral variations of Vs in the CZ. Results from synthetics show that this approach enables the resolution of physical property variations in the upper 10-15 m below the surface with lateral scales of about 5 m - a vast improvement compared to P-wave tomography alone. A field example at a Yellowstone hydrothermal system also demonstrates the benefits of including Vs in the petrophysical models to estimate not only porosity but also saturation, thus highlighting subsurface gas pathways. In light of these results, we strongly suggest that surface-wave analysis should become a standard approach in CZ seismic surveys.

Simulation of the mulltizones clastic reservoir: A case study of Upper Qishn Clastic Member, Masila Basin-Yemen

NASA Astrophysics Data System (ADS)

Khamis, Mohamed; Marta, Ebrahim Bin; Al Natifi, Ali; Fattah, Khaled Abdel; Lashin, Aref

2017-06-01

The Upper Qishn Clastic Member is one of the main oil-bearing reservoirs that are located at Masila Basin-Yemen. It produces oil from many zones with different reservoir properties. The aim of this study is to simulate and model the Qishn sandstone reservoir to provide more understanding of its properties. The available, core plugs, petrophysical, PVT, pressure and production datasets, as well as the seismic structural and geologic information, are all integrated and used in the simulation process. Eclipse simulator was used as a powerful tool for reservoir modeling. A simplified approach based on a pseudo steady-state productivity index and a material balance relationship between the aquifer pressure and the cumulative influx, is applied. The petrophysical properties of the Qishn sandstone reservoir are mainly investigated based on the well logging and core plug analyses. Three reservoir zones of good hydrocarbon potentiality are indicated and named from above to below as S1A, S1C and S2. Among of these zones, the S1A zone attains the best petrophysical and reservoir quality properties. It has an average hydrocarbon saturation of more than 65%, high effective porosity up to 20% and good permeability record (66 mD). The reservoir structure is represented by faulted anticline at the middle of the study with a down going decrease in geometry from S1A zone to S2 zone. It is limited by NE-SW and E-W bounding faults, with a weak aquifer connection from the east. The analysis of pressure and PVT data has revealed that the reservoir fluid type is dead oil with very low gas liquid ratio (GLR). The simulation results indicate heterogeneous reservoir associated with weak aquifer, supported by high initial water saturation and high water cut. Initial oil in place is estimated to be around 628 MM BBL, however, the oil recovery during the period of production is very low (<10%) because of the high water cut due to the fractures associated with many faults. Hence, secondary and tertiary methods are needed to enhance the oil recovery. Water flooding is recommended as the first step of oil recovery enhancement by changing some of high water cut wells to injectors.

Distributions and Relationships of CO2, O2, and Dimethylsulfide in the Changjiang (Yangtze) Estuary and Its Adjacent Waters in Summer

NASA Astrophysics Data System (ADS)

Wu, Xi; Tan, Tingting; Liu, Chunying; Li, Tie; Liu, Xiaoshou; Yang, Guipeng

2018-04-01

The distributions and relationships of O2, CO2, and dimethylsulfide (DMS) in the Changjiang (Yangtze) Estuary and its adjacent waters were investigated in June 2014. In surface water, mean O2 saturation level, partial pressure of CO2 (pCO2), and DMS concentrations (and ranges) were 110% (89%-167%), 374 μatm (91-640 μatm), and 8.53 nmol L-1 (1.10-27.50 nmol L-1), respectively. The sea-to-air fluxes (and ranges) of DMS and CO2 were 8.24 μmol m-2 d-1 (0.26-62.77 μmol m-2 d-1), and -4.7 mmol m-2 d-1 (-110.8-31.7 mmol m-2 d-1), respectively. Dissolved O2 was oversaturated, DMS concentrations were relatively high, and this region served as a sink of atmospheric CO2. The pCO2 was significantly and negatively correlated with the O2 saturation level, while the DMS concentration showed different positive relationships with the O2 saturation level in different water masses. In vertical profiles, a hypoxic zone existed below 20 m at a longitude of 123°E. The stratification of temperature and salinity caused by the Taiwan Warm Current suppressed seawater exchange between upper and lower layers, resulting in the formation of a hypoxic zone. Oxidative decomposition of organic detritus carried by the Changjiang River Diluted Water (CRDW) consumed abundant O2 and produced additional CO2. The DMS concentrations decreased because of low phytoplankton biomass in the hypoxic zone. Strong correlations appeared between the O2 saturation level, pCO2 and DMS concentrations in vertical profiles. Our results strongly suggested that CRDW played an important role in the distributions and relationships of O2, CO2, and DMS.

Hydric soils in a southeastern Oregon vernal pool

USGS Publications Warehouse

Clausnitzer, D.; Huddleston, J.H.; Horn, E.; Keller, Michael; Leet, C.

2003-01-01

Vernal pools on the High Lava Plain of the northern Great Basin become ponded in most years, but their soils exhibit weak redoximorphic features indicative of hydric conditions. We studied the hydrology, temperature, redox potentials, soil chemistry, and soil morphology of a vernal pool to determine if the soils are hydric, and to evaluate hydric soil field indicators. We collected data for 3 yr from piezometers, Pt electrodes, and thermocouples. Soil and water samples were analyzed for pH, organic C, and extractable Fe and Mn. Soils were ponded from January through April or May, but subsurface saturation was never detected. Soil temperatures 50 cm below the surface rose above 5??C by March. Clayey Bt horizons perched water and limited saturation to the upper 10 cm. Redox potentials at a 5-cm depth were often between 200 and 300 mV, indicating anaerobic conditions, but producing soluble Fe2+ concentrations <1 mg L-1. Extractable soil Fe contents indicated Fe depletion from pool surface horizons and accumulation at or near the upper Bt1 horizon. Depletions and concentrations did not satisfy the criteria of any current hydric soil indicators. We recommend development of new indicators based on acceptance of fewer, less distinct redox concentrations for recognition of a depleted A horizon, and on presence of a thin zone containing redox concentrations located in the upper part of the near-surface perching horizon.

Runoff and solute mobilization processes in a semiarid headwater catchment

NASA Astrophysics Data System (ADS)

Hughes, Justin D.; Khan, Shahbaz; Crosbie, Russell S.; Helliwell, Stuart; Michalk, David L.

2007-09-01

Runoff and solute transport processes contributing to streamflow were determined in a small headwater catchment in the eastern Murray-Darling Basin of Australia using hydrometric and tracer methods. Streamflow and electrical conductivity were monitored from two gauges draining a portion of the upper catchment area (UCA) and a saline scalded area, respectively. Runoff in the UCA was related to the formation of a seasonally perched aquifer in the near-surface zone (0-0.4 m). A similar process was responsible for runoff generation in the saline scalded area. However, saturation in the scald area was related to the proximity of groundwater rather than low subsurface hydraulic conductivity. Because of higher antecedent water content, runoff commenced earlier in winter from the scald than did the UCA. Additionally, areal runoff from the scald was far greater than from the UCA. Total runoff from the UCA was higher than the scald (15.7 versus 3.5 mL), but salt export was far lower (0.6 and 5.4 t for the UCA and scald area, respectively) since salinity of the scald runoff was far higher than that from the UCA, indicating the potential impact of saline scalded areas at the catchment scale. End-member mixing analysis modeling using six solutes indicated that most runoff produced from the scald was "new" (40-71%) despite the proximity of the groundwater surface and the high antecedent moisture levels. This is a reflection of the very low hydraulic conductivity of soils in the study area. Nearly all chloride exported to the stream from the scald emanated from the near-surface zone (77-87%). Runoff and solute mobilization processes depend upon seasonal saturation occurring in the near-surface zone during periods of low evaporative demand and generation of saturated overland flow.

Characterization of hydrogeologic units using matrix properties, Yucca Mountain, Nevada

USGS Publications Warehouse

Flint, L.E.

1998-01-01

Determination of the suitability of Yucca Mountain, in southern Nevada, as a geologic repository for high-level radioactive waste requires the use of numerical flow and transport models. Input for these models includes parameters that describe hydrologic properties and the initial and boundary conditions for all rock materials within the unsaturated zone, as well as some of the upper rocks in the saturated zone. There are 30 hydrogeologic units in the unsaturated zone, and each unit is defined by limited ranges where a discrete volume of rock contains similar hydrogeologic properties. These hydrogeologic units can be easily located in space by using three-dimensional lithostratigraphic models based on relation- ships of the properties with the lithostratigraphy. Physical properties of bulk density, porosity, and particle density; flow properties of saturated hydraulic conductivity and moisture-retention characteristics; and the state variables (variables describing the current state of field conditions) of saturation and water potential were determined for each unit. Units were defined using (1) a data base developed from 4,892 rock samples collected from the coring of 23 shallow and 8 deep boreholes, (2) described lithostratigraphic boundaries and corresponding relations to porosity, (3) recognition of transition zones with pronounced changes in properties over short vertical distances, (4) characterization of the influence of mineral alteration on hydrologic properties such as permeability and moisture-retention characteristics, and (5) a statistical analysis to evaluate where boundaries should be adjusted to minimize the variance within layers. This study describes the correlation of hydrologic properties to porosity, a property that is well related to the lithostratigraphy and depositional and cooling history of the volcanic deposits and can, therefore, be modeled to be distributed laterally. Parameters of the hydrogeologic units developed in this study and the relation of flow properties to porosity that are described can be used to produce detailed and accurate representations of the core-scale hydrologic processes ongoing at Yucca Mountain.

Water Quality Conditions in Upper Klamath and Agency Lakes, Oregon, 2005

USGS Publications Warehouse

Hoilman, Gene R.; Lindenberg, Mary K.; Wood, Tamara M.

2008-01-01

During June-October 2005, water quality data were collected from Upper Klamath and Agency Lakes in Oregon, and meteorological data were collected around and within Upper Klamath Lake. Data recorded at two continuous water quality monitors in Agency Lake showed similar temperature patterns throughout the field season, but data recorded at the northern site showed more day-to-day variability for dissolved oxygen concentration and saturation after late June and more day-to-day variability for pH and specific conductance values after mid-July. Data recorded from the northern and southern parts of Agency Lake showed more comparable day-to-day variability in dissolved oxygen concentrations and pH from September through the end of the monitoring period. For Upper Klamath Lake, seasonal (late July through early August) lows of dissolved oxygen concentrations and saturation were coincident with a seasonal low of pH values and seasonal highs of ammonia and orthophosphate concentrations, specific conductance values, and water temperatures. Patterns in these parameters, excluding water temperature, were associated with bloom dynamics of the cyanobacterium (blue-green alga) Aphanizomenon flos-aquae in Upper Klamath Lake. In Upper Klamath Lake, water temperature in excess of 28 degrees Celsius (a high stress threshold for Upper Klamath Lake suckers) was recorded only once at one site during the field season. Large areas of Upper Klamath Lake had periods of dissolved oxygen concentration of less than 4 milligrams per liter and pH value greater than 9.7, but these conditions were not persistent throughout days at most sites. Dissolved oxygen concentrations in Upper Klamath Lake on time scales of days and months appeared to be influenced, in part, by bathymetry and prevailing current flow patterns. Diel patterns of water column stratification were evident, even at the deepest sites. This diel pattern of stratification was attributable to diel wind speed patterns and the shallow nature of most of Upper Klamath Lake. Timing of the daily extreme values of dissolved oxygen concentration, pH, and water temperature was less distinct with increased water column depth. Chlorophyll a concentrations varied spatially and temporally throughout Upper Klamath Lake. Location greatly affected algal concentrations, in turn affecting nutrient and dissolved oxygen concentrations - some of the highest chlorophyll a concentrations were associated with the lowest dissolved oxygen concentrations and the highest un-ionized ammonia concentrations. The occurrence of the low dissolved oxygen and high un-ionized ammonia concentrations coincided with a decline in algae resulting from cell death, as measured by concentrations of chlorophyll a. Dissolved oxygen production rates in experiments were as high as 1.47 milligrams of oxygen per liter per hour, and consumption rates were as much as -0.73 milligrams of oxygen per liter per hour. Dissolved oxygen consumption rates measured in this study were comparable to those measured in a 2002 Upper Klamath Lake study, and a higher rate of dissolved oxygen consumption was recorded in dark bottles positioned higher in the water column. Data, though inconclusive, indicated that a decreasing trend of dissolved oxygen productivity through July could have contributed to the decreasing dissolved oxygen concentrations and percent saturation recorded in Upper Klamath Lake during this time. Phytoplankton self-shading was evident from a general inverse relation between depth of photic zone and chlorophyll a concentrations. This shading caused net dissolved oxygen consumption during daylight hours in lower parts of the water column that would otherwise have been in the photic zone. Meteorological data collected in and around Upper Klamath Lake showed that winds were likely to come from a broad range of westerly directions in the northern one-third of the lake, but tended to come from a narrow range of northwesterly directions

GPR studies over the tsunami affected Karaikal beach, Tamil Nadu, south India

NASA Astrophysics Data System (ADS)

Loveson, V. J.; Gujar, A. R.; Barnwal, R.; Khare, Richa; Rajamanickam, G. V.

2014-08-01

In this study, results of GPR profiling related to mapping of subsurface sedimentary layers at tsunami affected Karaikal beach are presented . A 400 MHz antenna was used for profiling along 262 m stretch of transect from beach to backshore areas with penetration of about 2.0 m depth (50 ns two-way travel time). The velocity analysis was carried out to estimate the depth information along the GPR profile. Based on the significant changes in the reflection amplitude, three different zones are marked and the upper zone is noticed with less moisture compared to other two (saturated) zones. The water table is noticed to vary from 0.5 to 0.75 m depth (12-15 ns) as moving away from the coastline. Buried erosional surface is observed at 1.5 m depth (40-42 ns), which represents the limit up to which the extreme event acted upon. In other words, it is the depth to which the tsunami sediments have been piled up to about 1.5 m thickness. Three field test pits were made along the transect and sedimentary sequences were recorded. The sand layers, especially, heavy mineral layers, recorded in the test pits indicate a positive correlation with the amplitude and velocity changes in the GPR profile. Such interpretation seems to be difficult in the middle zone due to its water saturation condition. But it is fairly clear in the lower zone located just below the erosional surface where the strata is comparatively more compact. The inferences from the GPR profile thus provide a lucid insight to the subsurface sediment sequences of the tsunami sediments in the Karaikal beach.

Flood quantiles scaling with upper soil hydraulic properties for different land uses at catchment scale

NASA Astrophysics Data System (ADS)

Peña, Luis E.; Barrios, Miguel; Francés, Félix

2016-10-01

Changes in land use within a catchment are among the causes of non-stationarity in the flood regime, as they modify the upper soil physical structure and its runoff production capacity. This paper analyzes the relation between the variation of the upper soil hydraulic properties due to changes in land use and its effect on the magnitude of peak flows: (1) incorporating fractal scaling properties to relate the effect of the static storage capacity (the sum of capillary water storage capacity in the root zone, canopy interception and surface puddles) and the upper soil vertical saturated hydraulic conductivity on the flood regime; (2) describing the effect of the spatial organization of the upper soil hydraulic properties at catchment scale; (3) examining the scale properties in the parameters of the Generalized Extreme Value (GEV) probability distribution function, in relation to the upper soil hydraulic properties. This study considered the historical changes of land use in the Combeima River catchment in South America, between 1991 and 2007, using distributed hydrological modeling of daily discharges to describe the hydrological response. Through simulation of land cover scenarios, it was demonstrated that it is possible to quantify the magnitude of peak flows in scenarios of land cover changes through its Wide-Sense Simple Scaling with the upper soil hydraulic properties.

Biofilter design for effective nitrogen removal from stormwater - influence of plant species, inflow hydrology and use of a saturated zone.

PubMed

Payne, Emily G I; Pham, Tracey; Cook, Perran L M; Fletcher, Tim D; Hatt, Belinda E; Deletic, Ana

2014-01-01

The use of biofilters to remove nitrogen and other pollutants from urban stormwater runoff has demonstrated varied success across laboratory and field studies. Design variables including plant species and use of a saturated zone have large impacts upon performance. A laboratory column study of 22 plant species and designs with varied outlet configuration was conducted across a 1.5-year period to further investigate the mechanisms and influences driving biofilter nitrogen processing. This paper presents outflow concentrations of total nitrogen from two sampling events across both 'wet' and 'dry' frequency dosing, and from sampling across two points in the outflow hydrograph. All plant species were effective under conditions of frequent dosing, but extended drying increased variation between species and highlighted the importance of a saturated zone in maintaining biofilter function. The saturated zone also effectively treated the volume of stormwater stored between inflow events, but this extended detention provided no additional benefit alongside the rapid processing of the highest performing species. Hence, the saturated zone reduced performance differences between plant species, and potentially acts as an 'insurance policy' against poor sub-optimal plant selection. The study shows the importance of biodiversity and inclusion of a saturated zone in protecting against climate variability.

Investigating and predicting landslides using a rainfall runoff model in Norway

NASA Astrophysics Data System (ADS)

Kråbøl, Eline; Skaugen, Thomas; Devoli, Graziella; Xu, Chong-Yu

2016-04-01

Landslides are amongst the most destructive natural hazards, causing damage to infrastructures, such as roads, railroads and houses, and can, in a worst-case scenario, take lives. A better understanding of the triggering processes of landslides are important as it enables us to perform better forecasts, improve mapping of zones with landslide risk and carry out mitigation measures. In this study, a parameter-parsimonious rainfall-runoff model, DDD (Distance Distribution Dynamics), is used to simulate the hydrological conditions for rainfall-induced landslide events. The model estimates the capacity of the subsurface reservoir at different levels of saturation and predicts overland flow. The subsurface in the DDD has a 2-D representation in that it calculates the saturated and unsaturated soil moisture along a hillslope representing the entire catchment in question. In this study, 50 landslide events in 10 catchments in Southern Norway are investigated. Characteristics of the subsurface states, before, during and after the landslide are analysed for the whole catchment and at three points (lower, middle and upper part) of the hillslope. Preliminary results show that the hysteretic loop of storage and discharge follow complex clockwise and anti-clockwise patterns. Anti-clockwise loops occur more frequent, except for the middle part of the hillslope. In the upper part of the hillslope, anti-clockwise loop occur almost exclusively (94 %). Evaluated for the entire catchment, 57 % of the landslide events occurred at maximum saturation, while 77 % of the events occurred at saturation above 80 %. We found the majority of the landslide events to be associated with the rising limb and the top of the hysteretic curve with 64 % and 17 %, respectively. Overland flow was found for 68 % of the events.

The frictional strength of talc gouge in high-velocity shear experiments

NASA Astrophysics Data System (ADS)

Chen, Xiaofeng; Elwood Madden, Andrew S.; Reches, Ze'ev

2017-05-01

Talc is present in several large-scale fault zones worldwide and is mineralogically stable at temperature of the upper crust. It is therefore necessary to gain a better understanding of the frictional behavior of talc under a wide range of slip velocity conditions occurring during the seismic cycle. We analyzed the frictional and structural characteristics of room-dry and water-saturated talc gouge by shear experiments on a confined gouge layer at slip velocity range of 0.002-0.66 m/s and normal stress up to 4.1 MPa. Room-dry talc showed a distinct slip-strengthening with the initial friction coefficient of μ 0.4 increased systematically to μ 1 at slip distance D > 1 m. Room-dry talc also displayed velocity-strengthening at slip distances shorter than 1 m. The water-saturated talc gouge displayed systematic low frictional strength of μ = 0.1-0.3 for the entire experimental range, with clear velocity-strengthening behavior with positive (a-b) values (rate dependence parameter of rate and state friction) of 0.01-0.04. The microstructural analyses revealed distributed shear and systematic dilation (up to 50%) for the room-dry talc, in contrast to the extreme slip localization and strong shear compaction for water-saturated talc. We propose that talc frictional strength is controlled by lubrication along cleavage surfaces that is facilitated by adsorbed water (room-dry) and surplus water (water-saturated). This mechanism can explain our experimental observations of slip-strengthening and velocity-strengthening for both types of talc gouge, as well as other clay minerals. It is thus expected that talc presence in fault zones would enhance creep and inhibit unstable slip.

Driver behavior and accident frequency in school zones: Assessing the impact of sign saturation.

PubMed

Strawderman, Lesley; Rahman, Md Mahmudur; Huang, Yunchen; Nandi, Apurba

2015-09-01

Based on the models of human information processing, if a driver observes too many of the same signs, he or she may no longer pay attention to those signs. In the case of school zones, this expected effect may lead to non-compliance to posted speeds, negatively impacting safety around nearby schools. This study aims to investigate the effect of the number of nearby school zones on driver behavior (vehicle speed and compliance) and accident frequency. As a measure of the density of school zones, this study introduced and defined a new term sign saturation and presented a methodology to calculate sign saturation for school zones. Results found a significant effect of sign saturation on vehicle speed, compliance, and accident frequency. This study also examined the speeding behavior in school zones for different time of the day and day of the week. Results found that speeding was more prevalent in the early mornings and during the weekends. Copyright © 2015 Elsevier Ltd. All rights reserved.

Herbicide and nitrate variation in alluvium underlying a cornfield at a site in Iowa County, Iowa

USGS Publications Warehouse

Kalkhoff, S.J.; Detroy, M.G.; Cherryholmes, K.; Kuzniar, R.L.

1992-01-01

A hydrologic investigation to determine vertical and seasonal variation of atrazine, alachlor, cyanazine, and nitrate at one location and to relate the variation to ground-water movement in the Iowa River alluvium was conducted in Iowa County, Iowa, from March 1986 to December 1987. Water samples were collected at discrete intervals through the alluvial sequence from the soil zone to the base of the aquifer. Alachlor, atrazine, and cyanazine were detected most frequently in the soil zone but also were present in the upper part of the alluvial aquifer. Alachlor was detected sporadically, whereas, atrazine, cyanazine, and nitrate were present throughout the year. In the alluvial aquifer, the herbicides generally were not detected during 1986 and were present in detectable concentrations for only a short period of time in the upper 1.6 meters of the aquifer during 1987. Nitrate was present throughout the alluvium and was stratified in the alluvial aquifer. The largest nitrate concentrations were detected in the middle part of the aquifer. Nitrate concentrations were variable only in the upper 2 meters of the aquifer. Vertical movement of herbicides and nitrate in the soil correlated with precipitation and degree of saturation. A clay layer retarded vertical movement of atrazine but not nitrate from the soil layer to the aquifer. Vertical movement could not account for the chemical variation in the alluvial aquifer.

TREATMENT OF A SATURATED ZONE HEXAVALENT CHROMIUM SOURCE AREA USING A FERROUS SULFATE/SODIUM DITHIONITE MIXTURE: A FIELD PILOT STUDY

EPA Science Inventory

A field pilot study was conducted to evaluate the performance of a combined ferrous sulfate/sodium dithionite solution for in situ treatment of a saturated zone hexavalent chromium source area at a former ferrochromium alloy production facility in Charleston, S.C. The saturate...

Dissolution rates of subsoil limestone in a doline on the Akiyoshi-dai Plateau, Japan: An approach from a weathering experiment, hydrological observations, and electrical resistivity tomography

NASA Astrophysics Data System (ADS)

Akiyama, Sanae; Hattanji, Tsuyoshi; Matsushi, Yuki; Matsukura, Yukinori

2015-10-01

This study aims at estimating the controlling factors for the denudation rates of limestone, which often forms solution dolines on karst tablelands. Our approaches include (1) electrical resistivity tomography (ERT) to reveal shallow subsurface structures and hydrological settings, (2) automated monitoring of volumetric water content in soil profiles and manual measurements of subsurface CO2 concentrations and soil water chemistry, and (3) a field weathering experiment using limestone tablets with the micro-weight loss technique for determining current denudation rates. The field experiment and monitoring were carried out over 768 days from 2009-2011 at four sites with varying topographic and hydrological conditions along the sideslope of a doline on the Akiyoshi-dai karst plateau in SW-Japan. The installation depths of the limestone tablets were 15 cm or 50 cm below the slope surface. The soil moisture conditions varied site by site. Water-saturated conditions continued for 40-50% of the whole experimental period at 50-cm depth of upper and middle sites, while only 0-10% of the experimental period was water-saturated at the other sites. Chemical analysis revealed that the soil water was chemically unsaturated with calcite for all the sites. Spatial differences in concentrations of CO2 in soil pore air were statistically less significant. The denudation rates of the buried limestone tablets were 17.7-21.9 mg cm- 2 a- 1 at the upper and middle slopes, where the soil was water-saturated for a long time after precipitation. The lowest denudation of 3.9 mg cm- 2 a- 1 was observed on lower slopes where soil was not capable of maintaining water at a near saturation level even after precipitation. Statistical analysis revealed that the denudation rates of the tablets were strongly controlled by the duration for which soil pores were saturated by water (the conditions defined here are degrees of water saturation greater than 97%). Electrical resistivity tomography indicated that areas with high soil moisture conditions were located at the deeper zone on the lower slopes and the bottom of the doline, where denudation would be faster.

Nurse opinions and pulse oximeter saturation target limits for preterm infants.

PubMed

Nghiem, Tuyet-Hang; Hagadorn, James I; Terrin, Norma; Syke, Sally; MacKinnon, Brenda; Cole, Cynthia H

2008-05-01

The objectives of this study were to compare pulse oximeter saturation limits targeted by nurses for extremely preterm infants during routine care with nurse opinions regarding appropriate pulse oximeter saturation limits and with policy-specified pulse oximeter saturation limits and to identify factors that influence pulse oximeter saturation limits targeted by nurses. We surveyed nurses in US NICUs with neonatal-perinatal fellowships in 2004. Data collected included pulse oximeter saturation limits targeted by nurses and by NICU policy when present, nurses' opinions about appropriate pulse oximeter saturation limits, and NICU and nurse characteristics. Factors associated with pulse oximeter saturation limits targeted by nurses were identified with hierarchical linear modeling. Among those eligible, 2805 (45%) nurses in 59 (60%) NICUs responded. Forty (68%) of 59 NICUs had a policy that specified a pulse oximeter saturation target range for extremely preterm infants. Among 1957 nurses at NICUs with policies, 540 (28%) accurately identified the upper and lower limits of their NICU's policy and also targeted these values in practice. NICU-specific SDs for individual nurse target limits were less at NICUs with versus without a policy for both upper and lower limits. Hierarchical linear modeling identified presence of pulse oximeter saturation policy, NICU-specific nurse group opinion, and individual nurse opinion as factors significantly associated with individual pulse oximeter saturation target limits. For each percentage point increase in individual opinion upper limit, the individual target upper limit increased by 0.41 percentage point at NICUs with a policy compared with 0.6 percentage point at NICUs with no policy. Presence of policy-specified pulse oximeter saturation limits, nurse group opinion, and individual nurse opinion were independently associated with individual nurse pulse oximeter saturation target limits during routine care of extremely preterm infants. The presence of a policy reduced the influence of individual nurse opinion on targeted pulse oximeter saturation limits and reduced variation among nurse target limits within NICUs.

Water partitioning in the Earth's mantle

NASA Astrophysics Data System (ADS)

Inoue, Toru; Wada, Tomoyuki; Sasaki, Rumi; Yurimoto, Hisayoshi

2010-11-01

We have conducted H2O partitioning experiments between wadsleyite and ringwoodite and between ringwoodite and perovskite at 1673 K and 1873 K, respectively. These experiments were performed in order to constrain the relative distribution of H2O in the upper mantle, the mantle transition zone, and the lower mantle. We successfully synthesized coexisting mineral assemblages of wadsleyite-ringwoodite and ringwoodite-perovskite that were large enough to measure the H2O contents by secondary ion mass spectrometry (SIMS). Combining our previous H2O partitioning data (Chen et al., 2002) with the present results, the determined water partitioning between olivine, wadsleyite, ringwoodite, and perovskite under H2O-rich fluid saturated conditions are 6:30:15:1, respectively. Because the maximum H2O storage capacity in wadsleyite is ∼3.3 wt% (e.g. Inoue et al., 1995), the possible maximum H2O storage capacity in the olivine high-pressure polymorphs are as follows: ∼0.7 wt% in olivine (upper mantle just above 410 km depth), ∼3.3 wt% in wadsleyite (410-520 km depth), ∼1.7 wt% in ringwoodite (520-660 km depth), and ∼0.1 wt% in perovskite (lower mantle). If we assume ∼0.2 wt% of the H2O content in wadsleyite in the mantle transition zone estimated by recent electrical conductivity measurements (e.g. Dai and Karato, 2009), the estimated H2O contents throughout the mantle are as follows; ∼0.04 wt% in olivine (upper mantle just above 410 km depth), ∼0.2 wt% in wadsleyite (410-520 km depth), ∼0.1 wt% in ringwoodite (520-660 km depth) and ∼0.007 wt% in perovskite (lower mantle). Thus, the mantle transition zone should contain a large water reservoir in the Earth's mantle compared to the upper mantle and the lower mantle.

Saltwater movement in the upper Floridan aquifer beneath Port Royal Sound, South Carolina

USGS Publications Warehouse

Smith, Barry S.

1994-01-01

Freshwater for Hilton Head Island, South Carolina, is supplied by withdrawals from the Upper Floridan aquifer. Freshwater for the nearby city of Savannah, Georgia, and for the industry that has grown adjacent to the city, has also been supplied, in part, by withdrawal from the Upper Floridan aquifer since 1885. The withdrawal of ground water has caused water levels in the Upper Floridan aquifer to decline over a broad area, forming a cone of depression in the potentiometric surface of the aquifer centered near Savannah. In 1984, the cone of depression extended beneath Hilton Head Island as far as Port Royal Sound. Flow in the aquifer, which had previously been toward Port Royal Sound, has been reversed, and, as a result, saltwater in the aquifer beneath Port Royal Sound has begun to move toward Hilton Head Island. The Saturated-Unsaturated Transport (SUTRA) model of the U.S. Geological Survey was used for the simulation of density-dependent ground-water flow and solute transport for a vertical section of the Upper Floridan aquifer and upper confining unit beneath Hilton Head Island and Port Royal Sound. The model simulated a dynamic equilibrium between the flow of seawater and freshwater in the aquifer near the Gyben-Herzberg position estimated for the period before withdrawals began in 1885; it simulated reasonable movements of brackish water and saltwater from that position to the position determined by chemical analyses of samples withdrawn from the aquifer in 1984, and it approximated hydraulic heads measured in the aquifer in 1976 and 1984. The solute-transport simulations indicate that the transition zone would continue to move toward Hilton Head Island even if pumping ceased on the island. Increases in existing withdrawals or additional withdrawals on or near Hilton Head Island would accelerate movement of the transition zone toward the island, but reduction in withdrawals or the injection of freshwater would slow movement toward the island, according to the simulations. Future movements of the transition zone toward Hilton Head Island will depend on hydraulic gradients in the aquifer beneath the island and the sound. Hydraulic gradients in the Upper Floridan aquifer beneath Hilton Head Island and Port Royal Sound are strongly influenced by withdrawals on the island and near Savannah. Since 1984, withdrawals on Hilton Head Island have increased.

RISK OF UNSATURATED/SATURATED TRANSPORT AND TRANSFORMATION OF CHEMICAL CONCENTRATIONS (RUSTIC): VOLUME 1. THEORY AND CODE VERIFICATION

EPA Science Inventory

The RUSTIC program links three subordinate models--PRZM, VADOFT, and SAFTMOD--in order to predict pesticide transport and transformation through the crop root zone, the unsaturated zone, and the saturated zone to drinking water wells. PRZM is a one-dimensional finite-difference m...

Evaluation of groundwater and soil pollution in a landfill area using electrical resistivity imaging survey.

PubMed

Ahmed, A M; Sulaiman, W N

2001-11-01

Landfills are sources of groundwater and soil pollution due to the production of leachate and its migration through refuse. This study was conducted in order to determine the extent of groundwater and soil pollution within and around the landfill of Seri Petaling located in the State of Selangor, Malaysia. The condition of nearby surface water was also determined. An electrical resistivity imaging survey was used to investigate the leachate production within the landfill. Groundwater geochemistry was carried out and chemical analysis of water samples was conducted upstream and downstream of the landfill. Surface water was also analyzed in order to determine its quality. Soil chemical analysis was performed on soil samples taken from different locations within and around the landfill in the vadose zone (unsaturated zone) and below the water table (in the soil saturated zone). The resistivity image along line L-L1 indicated the presence of large zones of decomposed waste bodies saturated with highly conducting leachate. Analysis of trace elements indicated their presence in very low concentrations and did not reflect any sign of heavy metal pollution of ground and surface water or of soil. Major ions represented by Na, K, and Cl were found in anomalous concentrations in the groundwater of the downstream bore hole, where they are 99.1%, 99.2%, and 99.4%, respectively, higher compared to the upstream bore hole. Electrical conductivity (EC) was also found in anomalous concentration downstream. Ca and Mg ions represent the water hardness (which is comparatively high downstream). There is a general trend of pollution towards the downstream area. Sulfates (SO4) and nitrates (NO3) are found in the area in low concentrations, even below the WHO standards for drinking water, but are significantly higher in the surface water compared to the groundwater. Phosphate (PO4) and nitrite (NO2), although present in low levels, are significantly higher at the downstream. There is no significant difference in the amount of fluoride (F) in the different locations. In the soil vadose zone, heavy metals were found to be in their typical normal ranges and within the background concentrations. Soil exchangeable bases were significantly higher in the soil saturated zone compared to the vadose zone, and no significant difference was obtained in the levels of inorganic pollutants. With the exception of Cd, the concentration ranges of all trace elements (Cu, Zn, Cr, Pb, and Ni) of Seri Petaling landfill soils were below the upper limits of baseline concentrations published from different sources.

Experimental investigation of water distribution in a two-phase zone during gravity-dominated evaporation

NASA Astrophysics Data System (ADS)

Cejas, Cesare M.; Castaing, Jean-Christophe; Hough, Larry; Frétigny, Christian; Dreyfus, Rémi

2017-12-01

We characterize the water repartition within the partially saturated (two-phase) zone (PSZ) during evaporation from mixed wettable porous media by controlling the wettability of glass beads, their sizes, and as well the surrounding relative humidity. Here, capillary numbers are low and under these conditions, the percolating front is stabilized by gravity. Using experimental and numerical analyses, we find that the PSZ saturation decreases with the Bond number, where packing of smaller particles have higher saturation values than packing made of larger particles. Results also reveal that the extent (height) of the PSZ, as well as water saturation in the PSZ, both increase with wettability. We also numerically calculate the saturation exclusively contained in connected liquid films and results show that values are less than the expected PSZ saturation. These results strongly reflect that the two-phase zone is not solely made up of connected capillary networks but also made of disconnected water clusters or pockets. Moreover, we also find that global saturation (PSZ + full wet zone) decreases with wettability, confirming that greater quantity of water is lost via evaporation with increasing hydrophilicity. These results show that connected liquid films are favored in more-hydrophilic systems while disconnected water pockets are favored in less-hydrophilic systems.

A new perspective on the generation of the 2016 M6.7 Kaohsiung earthquake, southwestern Taiwan

NASA Astrophysics Data System (ADS)

Wang, Zhi

2017-04-01

In order to investigate the likely generation mechanism of the 2016 M6.7 Kaohsiung earthquake, a large number of high-quality travel times from P- and S-wave source-receiver pairs are used jointly in this study to invert three-dimensional (3-D) seismic velocity (Vp, Vs) and Poisson's ratio structures at high resolution. We also calculated crack density, saturate fracture, and bulk-sound velocity from our inverted Vp, Vs, and σgodels. In this way, multi-geophysical parameter imaging revealed that the 2016 Kaohsiung earthquake occurred along a distinctive edge portion exhibiting high-to-low variations in these parameters in both horizontal and vertical directions across the hypocenter. We consider that a slow velocity and high-σ body that has high ɛ and somewhat high ζ anomalies above the hypocenter under the Coastal Plain represents fluids contained in the young fold-and-thrust belt associated with the passive Asian continental margin in southwestern Taiwan. Intriguing, a continuous low Vp and Vs zone with high Poisson's ratio, crack density and saturate fracturegnomalies across the Laonung and Chishan faults is also clearly imaged in the northwestern upper crust beneath the Coastal Plain and Western Foothills as far as the southeastern lower crust under the Central Range. We therefore propose that this southeastern extending weakened zone was mainly the result of a fluid intrusion either from the young fold-and-thrust belt the shallow crust or the subducted Eurasian continental (EC) plate in the lower crust and uppermost mantle. We suggest that fluid intrusion into the upper Oligocene to Pleistocene shallow marine and clastic shelf units of the Eurasian continental crust and/or the relatively thin uppermost part of the transitional Pleistocene-Holocene foreland due to the subduction of the EC plate along the deformation front played a key role in earthquake generation in southwestern Taiwan. Such fluid penetration would reduce Vp, and Vs while increasing Poisson's ratio and saturate fracture across the source area, leading to mechanical strength failure of the rock matrix in the relative weakened and brittle seismogenic layer and triggering the 2016 earthquake. PIC

Effect of deforestation on stream water chemistry in the Skrzyczne massif (the Beskid Śląski Mountains in southern Poland).

PubMed

Kosmowska, Amanda; Żelazny, Mirosław; Małek, Stanisław; Siwek, Joanna Paulina; Jelonkiewicz, Łukasz

2016-10-15

The purpose of the study was to identify the factors affecting stream water chemistry in the small mountain catchments deforested to varying degrees, from 98.7 to 14.1%, due to long-term acid deposition. Water samples were collected monthly in 2013 and 2014 from 17 streams flowing across three distinct elevation zones in the Skrzyczne massif (Poland): Upper, Middle and Lower Forest Zone. Chemical and physical analyses, including the pH, electrical conductivity (EC), total mineral content (Mt), water temperature, and the concentrations of Ca(2+), Mg(2+), Na(+), K(+), HCO3(-), SO4(2-), Cl(-), and NO3(-), were conducted. Based on Principal Component Analysis (PCA), the most important factor affecting water chemistry was human impact associated with changes in pH, SO4(2-) concentration, and the concentration of most of the main ions. The substantial acidity of the studied environment contributed to the exclusion of natural factors, associated with changes in discharge, from the list of major factors revealed by PCA. All of the streams were characterized by very low EC, Mt, and low concentrations of the main ions such as Ca(2+) and HCO3(-). This is the effect of continuous leaching of solutes from the soils by acidic precipitation. The lowest parameter values were measured for the streams situated in the Upper Forest Zone, which is associated with greater acid deposition at the higher elevations. In the streams located in the Upper Forest Zone, a higher percentage of SO4(2-) occurred than in the streams situated in the Middle and Lower Forest Zones. However, the largest share of SO4(2-) was measured in the most deforested catchment. The saturation of the studied deforested catchment with sulfur compounds is reflected by a positive correlation between SO4(2-) and discharge. Hence, a forest acts as a natural buffer that limits the level of acidity in the natural environment caused by acidic atmospheric deposition. Copyright © 2016 Elsevier B.V. All rights reserved.

Modern Processes of Hydrocarbon Migration and Re-Formation of Oil and Gas Fields (Based on the Results of Monitoring and Geochemical Studies)

NASA Astrophysics Data System (ADS)

Plotnikova, Irina; Salakhidinova, Gulmira; Nosova, Fidania; Pronin, Nikita; Ostroukhov, Sergey

2015-04-01

Special geochemical studies of oils allowed to allocate a movable migration component of oils in the industrial oil deposits. In the field the migration component of oils varies in different parts of the field. The largest percentage of the light migration component (gas condensate of the oil) was detected in the central part of the Kama-Kinel troughs system. Monitoring of the composition of water, oil and gas (condensate light oil component) in the sedimentary cover and ni crystalline basement led to the conclusion of modern migration of hydrocarbons in sedimentary cover. This proves the existence of the modern processes of formation and reformation of oil and gas fields. This presentation is dedicated to the problem of definition of geochemical criteria of selection of hydrocarbons deposit reformation zone in the sample wells of Minibaevskaya area of Romashkinskoye field. While carrying out this work we examined 11 samples of oil from the Upper Devonian Pashiysky horizon. Four oil samples were collected from wells reckoned among the "anomalous" zones that were marked out according to the results of geophysical, oil field and geological research. Geochemical studies of oils were conducted in the laboratory of geochemistry of the Kazan (Volga-region) Federal University. The wells where the signs of hydrocarbons influx from the deep zones of the crust were recorded are considered to be "anomalous". A number of scientists connect this fact to the hypothesis about periodic influx of deep hydrocarbons to the oil deposits of Romashkinskoye field. Other researchers believe that the source rocks of the adjacent valleys sedimentary cover generate gases when entering the main zone of gas formation, which then migrate up the section and passing through the previously formed deposits of oil, change and "lighten" their composition. Regardless of the point of view on the source of the hydrocarbons, the study of the process of deposits refilling with light hydrocarbons is an important fundamental task of exceptional practical importance. The reservoir water monitoring has been conducted in five wells that have penetrated the water-saturated, loosely aggregated zones of the South Tatarstan Arch's basement. The long-term testing resulted in the production of reservoir water from the basement. The sedimentary cover in these wells is blocked by the column, which prevents water cross-flowing from the sedimentary cover. The observations have shown that the levels, gas saturation, mineralisation, density, and composition of reservoir waters from the loosely aggregated zones of the basement change with time. The varying characteristics of the water include its component composition, redox potential, and amount of chlorine and some other components and trace elements. Compositional changes in gases of the loosely aggregated zones of the basement, variations in the gas saturation of reservoir waters and of their composition, the decreasing density of oil in the sedimentary cover, - all result from one cause. This cause is the movement of fluids (solutions and gases dissolved in them) through the loosely aggregated zones and faults of the Earth's crust and the sedimentary cover. The fluids mainly move vertically in an upward direction, although their migration through subhorizontal, loosely aggregated zones of the crystalline basement is also possible. Fluid migration still takes place in the Earth's crust of ancient platforms. This phenomenon indicates that some portions of the platforms - primarily, their margins - periodically resume tectonic activities. The fluid dynamic activity of the crust define the processes in the sedimentary cover. It affects the development of the sedimentary basin during the sedimentation period, and the formation of mineral deposits. The monitoring of the present-day movement of fluid systems in the loosely aggregated zones of the basement will permit the more detailed study of the present-day fluid regime in the upper portion of the Earth's crust and the sedimentary cover.

Effect of sensor location on regional cerebral oxygen saturation measured by INVOS 5100 in on-pump cardiac surgery.

PubMed

Cho, Ah-Reum; Kwon, Jae-Young; Kim, Choongrak; Hong, Jung-Min; Kang, Christine

2017-04-01

Near-infrared spectroscopy sensors often cannot be attached at the commercially recommended locations because combined use of neurological monitoring systems is common during on-pump cardiac surgery. The primary purpose of this study was to compare the incidence of regional cerebral oxygen desaturation and regional cerebral oxygen saturation values detected using near-infrared spectroscopy between the upper and lower forehead during on-pump cardiac surgery. A prospective observational study was conducted with 25 adult patients scheduled for elective on-pump cardiac surgery. Regional cerebral oxygen saturations at the left upper and lower forehead and other clinical measurements were monitored intraoperatively. McNemar's test was used to analyze differences in the incidence of cerebral regional oxygen desaturation between the left upper and lower forehead. Two-way repeated measures ANOVA with post hoc Bonferroni correction was used to compare the regional cerebral oxygen saturation at each time point. There was a significantly higher incidence of regional cerebral oxygen desaturation at the upper than lower forehead only at 1 h after initiation of aortic cross-clamping. There were significant differences between the left upper and lower regional cerebral oxygen saturation values throughout the observation period. Regional cerebral oxygen saturation was significantly lower at the upper than lower forehead during on-pump cardiac surgery. However, disagreements in detection of cerebral regional oxygen desaturation were only significant at 1 h after initiation of aortic cross-clamping. WHO-ICTRP, Clinical Research Information Service (CRiS). ID: KCT0000971. URL: https://cris.nih.go.kr/cris/search/search_result_st01_en.jsp?seq=3678&type=my .

[Noninvasive estimation of human tissue respiration with wavelet-analysis of oxygen saturation and blood flow oscillations in microvessels].

PubMed

Krupatkin, A I

2012-01-01

Laser Doppler flowmetry, laser spectrophotometry of oxygen saturation and fluorescence determination of NAD-H/FAD ratio were carried out at 30 humans in the upper extremity skin zones with and without arteriole-venule anastomoses (AVA). For the first time it was shown that wavelet-analysis of oxygen saturation and microvascular blood flow oscillations was an effective approach to noninvasive estimation of skin oxygen extraction (OE) and oxygen consumption rate (OC). OE = (SaO2--SvO2)/SaO2, where SaO2 (%) and SvO2(%) are the oxygen saturation of arterial and venular blood, correspondingly. If the ratio between amplitudes of cardiac rhythm (Ac, p.u.) and respiratory rhythm (Ar, p.u.) Ac/Ar < or = 1, SvO2 = SO2. In the case of Ac/Ar >1, SvO2 = SO2/(Ac/Ar). OC = Mnutr x (SaO2-SvO2) in p.u. x %O2, where Mnutr--value of nutritive perfusion (p.u.). Mnutr = M/SI, where SI--shunting index of blood flow in microvessels. The values of perfusion, OE and OC were higher in the skin with AVA than in the skin without AVA. The values of perfusion and oxygen saturation were more variable in the skin with AVA. The greatest significance for tissue metabolism have the oxygen diffused from the smallest arterioles and capillaries. The contribution increased to tissue metabolism of total perfusion and of oxygen diffused from arterioles in the conditions of tissue ischemia.

Improved forward and inverse analyses of saturated-unsaturated flow toward a well in a compressible unconfined aquifer

NASA Astrophysics Data System (ADS)

Mishra, Phoolendra Kumar; Neuman, Shlomo P.

2010-07-01

We present an analytical solution for flow to a partially penetrating well in a compressible unconfined aquifer that allows inferring its saturated and unsaturated hydraulic properties from drawdowns recorded in the saturated and/or unsaturated zone. We improve upon a previous such solution due to Tartakovsky and Neuman (2007) by (1) adopting a more flexible representation of unsaturated zone constitutive properties and (2) allowing the unsaturated zone to have finite thickness. Both solutions account for horizontal as well as vertical flows throughout the system. We investigate the effects of unsaturated zone constitutive parameters and thickness on drawdowns in the saturated and unsaturated zones as functions of position and time; demonstrate the development of significant horizontal hydraulic gradients in the unsaturated zone in response to pumping; validate our solution against numerical simulations of drawdown in a synthetic aquifer having unsaturated properties described by the van Genuchten-Mualem constitutive model; use our solution to analyze drawdown data from a pumping test conducted by the U.S. Geological Survey at Cape Cod, Massachusetts; and compare our estimates of van Genuchten-Mualem parameters with laboratory values obtained for similar materials in the area.

Gravity anomaly and density structure of the San Andreas fault zone

NASA Astrophysics Data System (ADS)

Wang, Chi-Yuen; Rui, Feng; Zhengsheng, Yao; Xingjue, Shi

1986-01-01

A densely spaced gravity survey across the San andreas fault zone was conducted near Bear Valley, about 180 km south of San Francisco, along a cross-section where a detailed seismic reflection profile was previously made by McEvilly (1981). With Feng and McEvilly's velocity structure (1983) of the fault zone at this cross-section as a constraint, the density structure of the fault zone is obtained through inversion of the gravity data by a method used by Parker (1973) and Oldenburg (1974). Although the resulting density picture cannot be unique, it is better constrained and contains more detailed information about the structure of the fault than was previously possible. The most striking feature of the resulting density structure is a deeply seated tongue of low-density material within the fault zone, probably representing a wedge of fault gouge between the two moving plates, which projects from the surface to the base of the seismogenic zone. From reasonable assumptions concerning the density of the solid grains and the state of saturation of the fault zone the average porosity of this low-density fault gouge is estimated as about 12%. Stress-induced cracks are not expected to create so much porosity under the pressures in the deep fault zone. Large-scaled removal of fault-zone material by hydrothermal alteration, dissolution, and subsequent fluid transport may have occurred to produce this pronounced density deficiency. In addition, a broad, funnel-shaped belt of low density appears about the upper part of the fault zone, which probably represents a belt of extensively shattered wall rocks.

Geohydrology of Test Well USW H-3, Yucca Mountain, Nye County, Nevada

DOE Office of Scientific and Technical Information (OSTI.GOV)

Thordarson, W.; Rush, F.E.; Waddell, S.J.

Test well USW H-3 is one of several test wells drilled in the southwestern part of the Nevada Test Site in cooperation with the US Department of Energy for investigations related to the isolation of high-level radioactive wastes. All rocks penetrated by the well to a total depth of 1219 meters are volcanic tuff of Tertiary age. The composite hydraulic head in the zone 751 to 1219 meters was 733 meters above sea level, and at a depth below land surface of 751 meters. Below a depth of 1190 meters, the hydraulic head was 754 meters above sea level ormore » higher, suggesting an upward component of groundwater flow at the site. The most transmissive part of the saturated zone is in the upper part of the Tram Member of the Crater Flat Tuff in the depth interval from 809 to 841 meters, with an apparent transmissivity of about 7 x 10{sup -1} meter squared per day. The remainder of the penetrated rocks in the saturated zone, 841 to 1219 meters, has an apparent transmissivity of about 4 x 10{sup -1} meter squared per day. The most transmissive part of the lower depth interval is in the bedded tuff and Lithic Ridge Tuff, in the depth interval from 1108 to 1120 meters. The apparent hydraulic conductivity of the rocks in the lower depth interval from 841 to 1219 meters commonly ranges from about 10{sup -1} to 10{sup -4} meter per day. 32 references, 20 figures, 4 tables.« less

Gas centrifuge purge method

DOEpatents

Theurich, Gordon R.

1976-01-01

1. In a method of separating isotopes in a high speed gas centrifuge wherein a vertically oriented cylindrical rotor bowl is adapted to rotate about its axis within an evacuated chamber, and wherein an annular molecular pump having an intake end and a discharge end encircles the uppermost portion of said rotor bowl, said molecular pump being attached along its periphery in a leak-tight manner to said evacuated chamber, and wherein end cap closure means are affixed to the upper end of said rotor bowl, and a process gas withdrawal and insertion system enters said bowl through said end cap closure means, said evacuated chamber, molecular pump and end cap defining an upper zone at the discharge end of said molecular pump, said evacuated chamber, molecular pump and rotor bowl defining a lower annular zone at the intake end of said molecular pump, a method for removing gases from said upper and lower zones during centrifuge operation with a minimum loss of process gas from said rotor bowl, comprising, in combination: continuously measuring the pressure in said upper zone, pumping gas from said lower zone from the time the pressure in said upper zone equals a first preselected value until the pressure in said upper zone is equal to a second preselected value, said first preselected value being greater than said second preselected value, and continuously pumping gas from said upper zone from the time the pressure in said upper zone equals a third preselected value until the pressure in said upper zone is equal to a fourth preselected value, said third preselected value being greater than said first, second and fourth preselected values.

Aquifer Characteristics Data Report for the Weldon Spring Site chemical plant/raffinate pits and vicinity properties for the Weldon Spring Site Remedial Action Project, Weldon Spring, Missouri

DOE Office of Scientific and Technical Information (OSTI.GOV)

Not Available

1990-11-01

This report describes the procedures and methods used, and presents the results of physical testing performed, to characterize the hydraulic properties of the shallow Mississippian-Devonian aquifer beneath the Weldon Spring chemical plant, raffinate pits, and vicinity properties. The aquifer of concern is composed of saturated rocks of the Burlington-Keokuk Limestone which constitutes the upper portion of the Mississippian-Devonian aquifer. This aquifer is a heterogeneous anisotropic medium which can be described in terms of diffuse Darcian flow overlain by high porosity discrete flow zones and conduits. Average hydraulic conductivity for all wells tested is 9.6E-02 meters/day (3.1E-01 feet/day). High hydraulic conductivitymore » values are representative of discrete flow in the fractured and weathered zones in the upper Burlington-Keokuk Limestone. They indicate heterogeneities within the Mississippian-Devonian aquifer. Aquifer heterogeneity in the horizontal plane is believed to be randomly distributed and is a function of fracture spacing, solution voids, and preglacial weathering phenomena. Relatively high hydraulic conductivities in deeper portions of the aquifer are though to be due to the presence of widely spaced fractures. 44 refs., 27 figs., 9 tabs.« less

Discussion of pore pressure transmission under rain infiltration in a soil layer

NASA Astrophysics Data System (ADS)

Yang, S. Y.; Jan, C. D.

2017-12-01

The vadose zone (or unsaturated zone) denotes the geologic media between ground surface and the water table in situ where the openings, or pores, in the soil (rock) layers are partially filled with water and air. In this landscape, rainwater infiltrates into soils advancing through this vadose zone and could generates a shallow saturation zone at soil bedrock boundary due to permeability contrast. This saturation zone leads to downslope shallow subsurface storm runoff that contributes to a part of saturation overland flow, dominating water reaching river channels. Hence, unsaturated processes (e.g., rain infiltration) is an important issue that can determine the timing and magnitude of positive pore pressure and discharge peaks, and the characteristics of runoff, water chemistry, hillslope stability is also tie to the processes. In this study, we investigated the transmission of pore pressure evolution in the vadose zone for diverse soil materials based on poroelasticity theory. Commonly, a traditional way is to utilize the Richard's equation to predict pore pressure evolution under unsaturated rain infiltration, ignoring the inertial effect on the process. Here we relax this limitation and propose two reference time tk and tep that can represent the arriving time at a certain depth of wave propagation and dissipation, respectively. Form ground surface to a depth of 1 m, tk has significant differences under nearly unsaturated conditions for diverse soil properties; however, no evident variations in tk can be observed under nearly saturated conditions. Values of tep for loose, cohesionless soils are much greater but decreases to the smallest one (within 1 day) than those for other soil properties under a nearly saturated condition. Results indicate that transient pore pressure transmission is mainly dominated by dynamic wave propagation but the effect of dissipation could become more important with increase in water saturation.

Movement triggers and remediation in a fracture-dominated translational landslide at the Oregon coast

USGS Publications Warehouse

Priest, George R.; Allan, Jonathan; Niem, Alan; Niem, Wendy A.; Dickenson, Stephen E.

2009-01-01

The Johnson Creek landslide is a translational slide in seaward dipping Miocene siltstone and sandstone (Astoria Formation) and an overlying Quaternary marine terrace deposit. The slide terminates in a sea cliff and has a hummocky to nearly horizontal ground surface. The basal slide plane, however, slopes subparallel to the dip of the Miocene rocks, except beneath the back-tilted toe blocks where it curves upward. The siltstone and sandstone have low estimated permeability but cores and field mapping reveal an extensive fracture system within the slide mass. The slide mainly moves in response to groundwater pressure and coastal erosion of the toe. Limit-equilibrium stability analyses indicate that 3 m of erosion at the toe would destabilize the slide for most of the wet season, although no movement could be directly attributed to erosion in the 5 years of observation. Intense rainfall events raise pore-water pressure throughout the slide in the form of pulses of water pressure traveling from the headwall graben down the axis of the slide at rates of 1.4-2.5 m/hr in the upper part, and 3.5 m/hr to virtually instantaneous in the middle part. Infiltration of meteoric water was only ~50 mm/hr. Slope of the water table exceeds topographic slope from the head to the toe of the slide, so infiltration was too slow to directly raise head in 90 percent of the slide mass where the saturated zone is deeper than a few meters. Only at the headwall graben was the saturated zone shallow enough for rainfall events to trigger pulses of water pressure through the entire saturated zone. When a pressure pulse reached the threshold pressure for movement in the central part of the slide, the whole slide began slow, creeping movement. As head became larger and larger than the threshold for movement in more of the slide mass, movement accelerated and differential displacement between internal slide blocks became more pronounced. These findings suggest that dewatering the shallowest part of the saturated zone in this type of slide will stop these rapid pressure pulses, thereby stopping or greatly reducing seasonal movement. If slides are also subject to continual removal of material from the toe, especially where there are back-tilted toe blocks, then some type of buttress or tied-back shear pile wall may be the only effective long term remediation.

Ionization and chemiluminescence during the progressive aeration of methane flames

DOE Office of Scientific and Technical Information (OSTI.GOV)

Weinberg, Felix; Carleton, Fred

Saturation currents and chemiluminescence, especially at the CH{sup *} and C{sub 2}{sup *} wavelengths, are measured for a range of small, laminar methane flames during progressive addition of air, with the principal objective of distinguishing between pure diffusion flames, premixed flames of compositions falling between the upper and lower flammability limits, and the broad range of aerated flames lying in between these regimes. Flame areas defined by the loci of maximum luminosity and by schlieren contours were recorded, so that saturation current densities, CH{sup *} and C{sub 2}{sup *} emission per unit flame area, as well as burning velocities couldmore » be deduced. For admixtures of less than 70 vol.%, air appears to act, surprisingly, as an inert diluent as regards saturation currents, so that saturation currents are essentially proportional to fuel flow alone. Much the same applies to chemiluminescence. However, schlieren contours, which were recorded both to provide a basis for burning velocity measurements and to explore density changes in the reactants, indicated the presence of a burner - stabilised propagating reaction zone ahead of the luminous flame surface starting at around 50 vol.% and possibly even at lower air admixtures. This evidence of a steep change in refractive index is indicative of a premixed reaction zone involving the added oxygen, which however generates no chemi-ionization and emits no light. Even photographing the flame by radiation emitted at the CH{sup *} and C{sub 2}{sup *} wavelengths shows no sign of its existence. Its burning velocity is about 10 cm/s, when stabilized by the surrounding diffusion flame. The most plausible rationale for these observations is the formation of syngas by the partial oxidation of methane. The subsequent burning of CO and H{sub 2} is known to occur without chemi-ionization or appreciable light emission. (author)« less

Elevated gas hydrate saturation within silt and silty clay sediments in the Shenhu area, South China Sea

USGS Publications Warehouse

Wang, Xiujuan; Hutchinson, Deborah R.; Wu, Shiguo; Yang, Shengxiong; Guo, Yiqun

2011-01-01

Gas hydrate saturations were estimated using five different methods in silt and silty clay foraminiferous sediments from drill hole SH2 in the South China Sea. Gas hydrate saturations derived from observed pore water chloride values in core samples range from 10 to 45% of the pore space at 190–221 m below seafloor (mbsf). Gas hydrate saturations estimated from resistivity (Rt) using wireline logging results are similar and range from 10 to 40.5% in the pore space. Gas hydrate saturations were also estimated by P wave velocity obtained during wireline logging by using a simplified three-phase equation (STPE) and effective medium theory (EMT) models. Gas hydrate saturations obtained from the STPE velocity model (41.0% maximum) are slightly higher than those calculated with the EMT velocity model (38.5% maximum). Methane analysis from a 69 cm long depressurized core from the hydrate-bearing sediment zone indicates that gas hydrate saturation is about 27.08% of the pore space at 197.5 mbsf. Results from the five methods show similar values and nearly identical trends in gas hydrate saturations above the base of the gas hydrate stability zone at depths of 190 to 221 mbsf. Gas hydrate occurs within units of clayey slit and silt containing abundant calcareous nannofossils and foraminifer, which increase the porosities of the fine-grained sediments and provide space for enhanced gas hydrate formation. In addition, gas chimneys, faults, and fractures identified from three-dimensional (3-D) and high-resolution two-dimensional (2-D) seismic data provide pathways for fluids migrating into the gas hydrate stability zone which transport methane for the formation of gas hydrate. Sedimentation and local canyon migration may contribute to higher gas hydrate saturations near the base of the stability zone.

Diel fluctuations of viscosity-driven riparian inflow affect streamflow DOC concentration

NASA Astrophysics Data System (ADS)

Schwab, Michael P.; Klaus, Julian; Pfister, Laurent; Weiler, Markus

2018-04-01

Diel fluctuations of stream water DOC concentrations are generally explained by a complex interplay of different instream processes. We measured the light absorption spectrum of water and DOC concentrations in situ and with high frequency by means of a UV-Vis spectrometer during 18 months at the outlet of a forested headwater catchment in Luxembourg (0.45 km2). We generally observed diel DOC fluctuations with a maximum in the afternoon during days that were not affected by rainfall-runoff events. We identified an increased inflow of terrestrial DOC to the stream in the afternoon, causing the DOC maxima in the stream. The terrestrial origin of the DOC was derived from the SUVA-254 (specific UV absorbance at 254 nm) index, which is a good indicator for the aromaticity of DOC. In the studied catchment, the most likely process that can explain the diel DOC input variations towards the stream is the so-called viscosity effect. The water temperature in the upper parts of the saturated riparian zone is increasing during the day, leading to a lower viscosity and therefore a higher hydraulic conductivity. Consequently, more water from areas that are rich in terrestrial DOC passes through the saturated riparian zone and contributes to streamflow in the afternoon. We believe that not only diel instream processes, but also viscosity-driven diel fluctuations of terrestrial DOC input should be considered to explain diel DOC patterns in streams.

Runoff and Solute Mobilisation in a Semi-arid Headwater Catchment

NASA Astrophysics Data System (ADS)

Hughes, J. D.; Khan, S.; Crosbie, R.; Helliwell, S.; Michalk, D.

2006-12-01

Runoff and solute transport processes contributing to stream flow were determined in a small headwater catchment in the eastern Murray-Darling Basin of Australia using hydrometric and tracer methods. Stream flow and electrical conductivity were monitored from two gauges draining a portion of upper catchment area (UCA), and a saline scalded area respectively. Results show that the bulk of catchment solute export, occurs via a small saline scald (< 2% of catchment area) where solutes are concentrated in the near surface zone (0-40 cm). Non-scalded areas of the catchment are likely to provide the bulk of catchment runoff, although the scalded area is a higher contributor on an areal basis. Runoff from the non-scalded area is about two orders of magnitude lower in electrical conductivity than the scalded area. This study shows that the scalded zone and non-scalded parts of the catchment can be managed separately since they are effectively de-coupled except over long time scales, and produce runoff of contrasting quality. Such differences are "averaged out" by investigations that operate at larger scales, illustrating that observations need to be conducted at a range of scales. EMMA modelling using six solutes shows that "event" or "new" water dominated the stream hydrograph from the scald. This information together with hydrometric data and soil physical properties indicate that saturated overland flow is the main form of runoff generation in both the scalded area and the UCA. Saturated areas make up a small proportion of the catchment, but are responsible for production of all run off in conditions experienced throughout the experimental period. The process of saturation and runoff bears some similarities to the VSA concept (Hewlett and Hibbert 1967).

Evaluation of a distributed catchment scale water balance model

NASA Technical Reports Server (NTRS)

Troch, Peter A.; Mancini, Marco; Paniconi, Claudio; Wood, Eric F.

1993-01-01

The validity of some of the simplifying assumptions in a conceptual water balance model is investigated by comparing simulation results from the conceptual model with simulation results from a three-dimensional physically based numerical model and with field observations. We examine, in particular, assumptions and simplifications related to water table dynamics, vertical soil moisture and pressure head distributions, and subsurface flow contributions to stream discharge. The conceptual model relies on a topographic index to predict saturation excess runoff and on Philip's infiltration equation to predict infiltration excess runoff. The numerical model solves the three-dimensional Richards equation describing flow in variably saturated porous media, and handles seepage face boundaries, infiltration excess and saturation excess runoff production, and soil driven and atmosphere driven surface fluxes. The study catchments (a 7.2 sq km catchment and a 0.64 sq km subcatchment) are located in the North Appalachian ridge and valley region of eastern Pennsylvania. Hydrologic data collected during the MACHYDRO 90 field experiment are used to calibrate the models and to evaluate simulation results. It is found that water table dynamics as predicted by the conceptual model are close to the observations in a shallow water well and therefore, that a linear relationship between a topographic index and the local water table depth is found to be a reasonable assumption for catchment scale modeling. However, the hydraulic equilibrium assumption is not valid for the upper 100 cm layer of the unsaturated zone and a conceptual model that incorporates a root zone is suggested. Furthermore, theoretical subsurface flow characteristics from the conceptual model are found to be different from field observations, numerical simulation results, and theoretical baseflow recession characteristics based on Boussinesq's groundwater equation.

Ground-water quality of the Upper Floridan Aquifer near an abandoned manufactured gas plant in Albany, Georgia

USGS Publications Warehouse

Chapman, M.J.

1993-01-01

Manufactured gas plants produced gas for heating and lighting in the United States from as early as 1816 into the 1960's. By-products including, but not limited to, oil residues and tar, were generated during the gas-manufacturing process. Organic compounds (hydrocarbons) were detected in water in the upper water-bearing zone of the Upper Floridan aquifer near an abandoned manufactured gas plant (MGP) in Albany, Georgia, during an earlier investigation in 1990. Chemical analyses of ground-water samples collected from five existing monitoring wells in 1991 verify the presence of hydrocarbons and metals in the upper water-beating zone of the Upper Floridan aquifer. One well was drilled into the lower water-beating zone of the Upper Floridan aquifer in 1991 for water-quality sampling and water-level monitoring. Analyses of ground water sampled from this well did not show evidence of benzene, toluene, xylene, napthalene, acenaphthlene, or other related compounds detected in the upper water-bearing zone in the study area. Low concentrations of tetrachloroethane, trichloromethane, and l,2-cisdichloroethene were detected in a water sample from the deeper well; however, these compounds were not detected in the upper water-bearing zone in the study area. Inorganic constituent concentrations also were substantially lower in the deeper well. Overall, ground water sampled from the lower water-bearing zone had lower specific conductance and alkalinity; and lower concentrations of dissolved solids, iron, and manganese compared to ground water sampled from the upper water-bearing zone. Water levels for the upper and lower water-bearing zones were similar throughout the study period.

Large-scale depositional characteristics of the Ulleung Basin and its impact on electrical resistivity and Archie-parameters for gas hydrate saturation estimates

USGS Publications Warehouse

Riedel, Michael; Collett, Timothy S.; Kim, H.-S.; Bahk, J.-J.; Kim, J.-H.; Ryu, B.-J.; Kim, G.-Y.

2013-01-01

Gas hydrate saturation estimates were obtained from an Archie-analysis of the Logging-While-Drilling (LWD) electrical resistivity logs under consideration of the regional geological framework of sediment deposition in the Ulleung Basin, East Sea, of Korea. Porosity was determined from the LWD bulk density log and core-derived values of grain density. In situ measurements of pore-fluid salinity as well as formation temperature define a background trend for pore-fluid resistivity at each drill site. The LWD data were used to define sets of empirical Archie-constants for different depth-intervals of the logged borehole at all sites drilled during the second Ulleung Basin Gas Hydrate Drilling Expedition (UBGH2). A clustering of data with distinctly different trend-lines is evident in the cross-plot of porosity and formation factor for all sites drilled during UBGH2. The reason for the clustering is related to the difference between hemipelagic sediments (mostly covering the top ∼100 mbsf) and mass-transport deposits (MTD) and/or the occurrence of biogenic opal. For sites located in the north-eastern portion of the Ulleung Basin a set of individual Archie-parameters for a shallow depth interval (hemipelagic) and a deeper MTD zone was achieved. The deeper zone shows typically higher resistivities for the same range of porosities seen in the upper zone, reflecting a shift in sediment properties. The presence of large amounts of biogenic opal (up to and often over 50% as defined by XRD data) was especially observed at Sites UBGH2-2_1 and UBGH2-2_2 (as well as UBGH1-9 from a previous drilling expedition in 2007). The boundary between these two zones can also easily be identified in gamma-ray logs, which also show unusually low readings in the opal-rich interval. Only by incorporating different Archie-parameters for the different zones a reasonable estimate of gas hydrate saturation was achieved that also matches results from other techniques such as pore-fluid freshening, velocity-based calculations, and pressure-core degassing experiments. Seismically, individual boundaries between zones were determined using a grid of regional 2D seismic data. Zoning from the Archie-analysis for sites in the south-western portion of the Ulleung Basin was also observed, but at these sites it is linked to individually stacked MTDs only and does not reflect a mineralogical occurrence of biogenic opal or hemipelagic sedimentation. The individual MTD events represent differently compacted material often associated with a strong decrease in porosity (and increase in density), warranting a separate set of empirical Archie-parameters.

ASSESSING UST CORRECTIVE ACTION TECHNOLOGIES: EARLY SCREENING OF CLEANUP TECHNOLOGIES FOR THE SATURATED ZONE

EPA Science Inventory

This manual assists the user in making a preliminary evaluation of the likely effectiveness of various remediation technologies in the event of a release of petroleum products into the saturated zone. he manual: 1) helps the user develop a conceptual understanding of site conditi...

40 CFR 149.2 - Definitions.

Code of Federal Regulations, 2010 CFR

2010-07-01

... significant amount of water to a well or spring. (b) Recharge means a process, natural or artificial, by which water is added to the saturated zone of an aquifer. (c) Recharge Area means an area in which water reaches the zone of saturation (ground water) by surface infiltration; in addition, a major recharge area...

40 CFR 149.2 - Definitions.

Code of Federal Regulations, 2011 CFR

2011-07-01

... significant amount of water to a well or spring. (b) Recharge means a process, natural or artificial, by which water is added to the saturated zone of an aquifer. (c) Recharge Area means an area in which water reaches the zone of saturation (ground water) by surface infiltration; in addition, a major recharge area...

Imaging groundwater infiltration dynamics in the karst vadose zone with long-term ERT monitoring

NASA Astrophysics Data System (ADS)

Watlet, Arnaud; Kaufmann, Olivier; Triantafyllou, Antoine; Poulain, Amaël; Chambers, Jonathan E.; Meldrum, Philip I.; Wilkinson, Paul B.; Hallet, Vincent; Quinif, Yves; Van Ruymbeke, Michel; Van Camp, Michel

2018-03-01

Water infiltration and recharge processes in karst systems are complex and difficult to measure with conventional hydrological methods. In particular, temporarily saturated groundwater reservoirs hosted in the vadose zone can play a buffering role in water infiltration. This results from the pronounced porosity and permeability contrasts created by local karstification processes of carbonate rocks. Analyses of time-lapse 2-D geoelectrical imaging over a period of 3 years at the Rochefort Cave Laboratory (RCL) site in south Belgium highlight variable hydrodynamics in a karst vadose zone. This represents the first long-term and permanently installed electrical resistivity tomography (ERT) monitoring in a karst landscape. The collected data were compared to conventional hydrological measurements (drip discharge monitoring, soil moisture and water conductivity data sets) and a detailed structural analysis of the local geological structures providing a thorough understanding of the groundwater infiltration. Seasonal changes affect all the imaged areas leading to increases in resistivity in spring and summer attributed to enhanced evapotranspiration, whereas winter is characterised by a general decrease in resistivity associated with a groundwater recharge of the vadose zone. Three types of hydrological dynamics, corresponding to areas with distinct lithological and structural features, could be identified via changes in resistivity: (D1) upper conductive layers, associated with clay-rich soil and epikarst, showing the highest variability related to weather conditions; (D2) deeper and more resistive limestone areas, characterised by variable degrees of porosity and clay contents, hence showing more diffuse seasonal variations; and (D3) a conductive fractured zone associated with damped seasonal dynamics, while showing a great variability similar to that of the upper layers in response to rainfall events. This study provides detailed images of the sources of drip discharge spots traditionally monitored in caves and aims to support modelling approaches of karst hydrological processes.

Limited denitrification in glacial deposit aquifers having thick unsaturated zones (Long Island, USA)

NASA Astrophysics Data System (ADS)

Young, Caitlin; Kroeger, Kevin D.; Hanson, Gilbert

2013-12-01

The goal of this study was to demonstrate how the extent of denitrification, which is indirectly related to dissolved organ carbon and directly related to oxygen concentrations, can also be linked to unsaturated-zone thickness, a mappable aquifer property. Groundwater from public supply and monitoring wells in Northport on Long Island, New York state (USA), were analyzed for denitrification reaction progress using dissolved N2/Ar concentrations by membrane inlet mass spectrometry. This technique allows for discernment of small amounts of excess N2, attributable to denitrification. Results show an average 15 % of total nitrogen in the system was denitrified, significantly lower than model predictions of 35 % denitrification. The minimal denitrification is due to low dissolved organic carbon (29.3-41.1 μmol L-1) and high dissolved oxygen concentrations (58-100 % oxygen saturation) in glacial sediments with minimal solid-phase electron donors to drive denitrification. A mechanism is proposed that combines two known processes for aquifer re-aeration in unconsolidated sands with thick (>10 m) unsaturated zones. First, advective flux provides 50 % freshening of pore space oxygen in the upper 2 m due to barometric pressure changes. Then, oxygen diffusion across the water-table boundary occurs due to high volumetric air content in the unsaturated-zone catchment area.

Nannoplankton malformation during the Paleocene-Eocene Thermal Maximum and its paleoecological and paleoceanographic significance

USGS Publications Warehouse

Bralower, Timothy J.; Self-Trail, Jean

2016-01-01

The Paleocene-Eocene Thermal Maximum (PETM) is characterized by a transient group of nannoplankton, belonging to the genus Discoaster. Our investigation of expanded shelf sections provides unprecedented detail of the morphology and phylogeny of the transient Discoasterduring the PETM and their relationship with environmental change. We observe a much larger range of morphological variation than previously documented suggesting that the taxa belonged to a plexus of highly gradational morphotypes rather than individual species. We propose that the plexus represents malformed ecophenotypes of a single species that migrated to a deep photic zone refuge during the height of PETM warming and eutrophication. Anomalously, high rates of organic matter remineralization characterized these depths during the event and led to lower saturation levels, which caused malformation. The proposed mechanism explains the co-occurrence of malformed Discoaster with pristine species that grew in the upper photic zone; moreover, it illuminates why malformation is a rare phenomenon in the paleontological record.

Local recharge processes in glacial and alluvial deposits of a temperate catchment

NASA Astrophysics Data System (ADS)

Fragalà, Federico A.; Parkin, Geoff

2010-07-01

SummaryThis study demonstrates that the composition and structure of Quaternary deposits and topography significantly influence rates of recharge and distribution of diffuse agricultural pollution at the hillslope scale. Analyses were made of vertical profiles of naturally-occurring chloride and nitrate, and artificially introduced bromide, in unsaturated and saturated sections of borehole cores of glacial till and alluvium under different land uses in the Upper Eden valley (UK). Estimates of local potential recharge were made based on chloride mass balance and nitrate peak methods. Persistent chloride bulges below the root zone were observed, and are interpreted to result from filtration processes at lithological boundaries. Changes in the shape of chloride profiles downslope, corroborated by nitrate profiles, indicate the roles of surface or near-surface runoff and runon, and the existence of lateral subsurface flows at depth. These findings have implications for estimation of recharge rates through unsaturated zones in Quaternary deposits, and the interpretation of potential 'hot-spots' of diffuse agrochemicals, particularly nitrates, moving through Quaternary deposits into groundwater.

Nannoplankton malformation during the Paleocene-Eocene Thermal Maximum and its paleoecological and paleoceanographic significance

NASA Astrophysics Data System (ADS)

Bralower, Timothy J.; Self-Trail, Jean M.

2016-10-01

The Paleocene-Eocene Thermal Maximum (PETM) is characterized by a transient group of nannoplankton, belonging to the genus Discoaster. Our investigation of expanded shelf sections provides unprecedented detail of the morphology and phylogeny of the transient Discoaster during the PETM and their relationship with environmental change. We observe a much larger range of morphological variation than previously documented suggesting that the taxa belonged to a plexus of highly gradational morphotypes rather than individual species. We propose that the plexus represents malformed ecophenotypes of a single species that migrated to a deep photic zone refuge during the height of PETM warming and eutrophication. Anomalously, high rates of organic matter remineralization characterized these depths during the event and led to lower saturation levels, which caused malformation. The proposed mechanism explains the co-occurrence of malformed Discoaster with pristine species that grew in the upper photic zone; moreover, it illuminates why malformation is a rare phenomenon in the paleontological record.

A practical tool for estimating subsurface LNAPL distributions and transmissivity using current and historical fluid levels in groundwater wells: Effects of entrapped and residual LNAPL

NASA Astrophysics Data System (ADS)

Lenhard, R. J.; Rayner, J. L.; Davis, G. B.

2017-10-01

A model is presented to account for elevation-dependent residual and entrapped LNAPL above and below, respectively, the water-saturated zone when predicting subsurface LNAPL specific volume (fluid volume per unit area) and transmissivity from current and historic fluid levels in wells. Physically-based free, residual, and entrapped LNAPL saturation distributions and LNAPL relative permeabilities are integrated over a vertical slice of the subsurface to yield the LNAPL specific volumes and transmissivity. The model accounts for effects of fluctuating water tables. Hypothetical predictions are given for different porous media (loamy sand and clay loam), fluid levels in wells, and historic water-table fluctuations. It is shown the elevation range from the LNAPL-water interface in a well to the upper elevation where the free LNAPL saturation approaches zero is the same for a given LNAPL thickness in a well regardless of porous media type. Further, the LNAPL transmissivity is largely dependent on current fluid levels in wells and not historic levels. Results from the model can aid developing successful LNAPL remediation strategies and improving the design and operation of remedial activities. Results of the model also can aid in accessing the LNAPL recovery technology endpoint, based on the predicted transmissivity.

Do storage dynamics in hydropedological units control hydrological connectivity? (Invited)

NASA Astrophysics Data System (ADS)

Tetzlaff, D.; Birkel, C.; Dick, J.; Geris, J.; Soulsby, C.

2013-12-01

In many northern landscapes, peat-dominated riparian wetlands often characterise the zone of connection between terrestrial drainage and the river network. In order to understand the relationship between connectivity and stream flow generation in a montane headwater catchment, we examined the storage dynamics and isotopic composition of soil water in major hydropedological units. These formed a classic catena sequence for northern catchments from free-draining podzols on steep upper hillslopes through to peaty gleysols in lower receiving slopes to deeper peats (Histosols) in the riparian zone. The peaty gleys and peats remained saturated throughout the year, whilst the podzols showed distinct wetting and drying cycles. In this climatic region, most precipitation events are less than 10mm in magnitude, storm runoff is mainly generated from the Histosols and Gleysols, with runoff coefficients (RCs) typically <10%. In larger events the podzolic soils become strongly connected to the saturated areas and RCs can exceed 40%. Isotopic variations in precipitation are significantly damped in the organic-rich surface horizons of the soils due to mixing with larger volumes of stored water. This damping is accentuated in the deeper soil profile and groundwater. Consequently, the isotopic composition of stream water is also damped, but the strongly reflects that of the near surface waters in the riparian peats. Old 'pre-event' water generally accounts for >80% of flow, even in large events, mainly reflecting the displacement of water stored in the riparian peats and peaty gleys. These riparian areas appear to be the dominant zone where different catchment source waters mix; acting as an 'isostat' that regulates the isotopic composition of stream waters and integrates the Transit Time Distribution (TTD) for the catchment.

Geohydrology and contamination at the Michigan Department of Transportation maintenance garage area, Kalamazoo County, Michigan

USGS Publications Warehouse

Lynch, E.A.; Huffman, G.C.

1996-01-01

A leaking underground storage tank was removed from the Michigan Department of Transportation maintenance garage area in Kalamazoo County., Mich., in 1985. The tank had been leaking unleaded gasoline. Although a remediation system was operational at the site for several years after the tank was removed, ground-water samples collected from monitoring wells in the area consistently showed high concentrations of benzene, toluene. ethylbenzene, and xylenes--indicators of the presence of gasoline. The U.S. Geological Survey did a study in cooperation with the Michigan Department of Transportation, to define the geology, hydrology, and occurrence of gasoline contamination in the maintenance garage area. The aquifer affected by gasoline contamination is an unconfined glaci'a.l sand and gravel aquifer. The average depth to water in the study area is about 74.7 feet. Water-level fluctuations are small; maximum fluctuation was slightly more than 1 foot during August 1993-August 1994. Hydraulic conductivities based on aquifer-test data collected for the study and estimated by use of the Cooper-Jacob method of solution ranged from 130 to 144 feet per day. Ground water is moving in an east-southeasterly direction at a rate of about I foot per day. Leakage from perforated pipes leading from the underground storage tanks to the pump station was identified as a second source of gasoline contamination to saturated and unsaturated zones. The existence of this previously unknown second source is part of the reason that previous remediation efforts were ineffective. Residual contaminants in the unsaturated zone are expected to continue to move to the water table with recharge, except in a small area covered by asphalt at the land surface. The gasoline plume from the perforated pipe source has merged with that from the leaking underground storage tank, and the combined plume in the saturated zone is estimated to cover an area of 30,000 square feet. The combined plume is in the upper 20 feet of the saturated zone. The relative distribution of benzene, toluene, ethylbenzene, and xylenes indicate that factors such as sorption, solubility, and susceptibility to microbial degradation are affecting the movement of the combined plume. Given these factors, the plume is expected to move at a rate of less than 1 foot per day.

Deep Vadose Zone Flow and Transport Behavior at T-Tunnel Complex, Rainier Mesa, Nevada National Security Site

NASA Astrophysics Data System (ADS)

Parashar, R.; Reeves, D. M.

2010-12-01

Rainier Mesa, a tuffaceous plateau on the Nevada National Security Site, has been the location of numerous subsurface nuclear tests conducted in a series of tunnel complexes located approximately 450 m below the top of the mesa and 500 m above the regional groundwater flow system. The tunnels were constructed near the middle of an 800 m Tertiary sequence of faulted, low-permeability welded and non-welded bedded, vitric, and zeolitized tuff units. Water levels from wells in the vicinity of the T-tunnel complex indicate the presence of a perched saturation zone located approximately 100 m above the T-tunnel complex. This upper zone of saturation extends downward through most of the Tertiary sequence. The groundwater table is located at an elevation of 1300 m within a thrust sheet of Paleozoic carbonates, corresponding to the lower carbonate aquifer hydrostratigraphic unit (LCA3). The LCA3 is considered to be hydraulically connected to the Death Valley regional flow system. The objective of this project is to simulate complex downward patterns of fluid flow and radionuclide transport from the T-tunnel complex through the matrix and fault networks of the Tertiary tuff units to the water table. We developed an improved fracture characterization and mapping methodology consisting of displacement-length scaling relationships, simulation of realistic fault networks based on site-specific data, and the development of novel fracture network upscaling techniques that preserves fracture network flow and transport properties on coarse continuum grid. Development of upscaling method for fracture continua is based on the concepts of discrete fracture network modeling approach which performs better at honoring network connectivity and anisotropy of sparse networks in comparison to other established methods such as a tensor approach. Extensive flow simulations in the dual-continuum framework demonstrate that the characteristics of fault networks strongly influences the saturation profile and formation of perched zones, although they may not conduct a large amount of flow when compared to the matrix continua. The simulated results are found to be very sensitive to distribution of fracture aperture, density of the network, and spatial pattern of fracture clustering. The faults provide rapid pathways for radionuclide transport and the conceptual modeling of diffusional mass transfer between matrix and fracture continua plays a vital role in prediction of the overall behavior of the breakthrough curve.

Sedimentological Control on Hydrate Saturation Distribution in Arctic Gas-Hydrate-Bearing Deposits

NASA Astrophysics Data System (ADS)

Behseresht, J.; Peng, Y.; Bryant, S. L.

2010-12-01

Grain size variations along with the relative rates of fluid phases migrating into the zone of hydrate stability, plays an important role in gas-hydrate distribution and its morphologic characteristics. In the Arctic, strata several meters thick containing large saturations of gas hydrate are often separated by layers containing small but nonzero hydrate saturations. Examples are Mt. Elbert, Alaska and Mallik, NW Territories. We argue that this sandwich type hydrate saturation distribution is consistent with having a gas phase saturation within the sediment when the base of gas hydrate stability zone (BGHSZ) was located above the sediment package. The volume change during hydrate formation process derives movement of fluid phases into the GHSZ. We show that this fluid movement -which is mainly governed by characteristic relative permeability curves of the host sediment-, plays a crucial role in the amount of hydrate saturation in the zone of major hydrate saturation. We develop a mechanistic model that enables estimating the final hydrate saturation from an initial gas/water saturation in sediment with known relative permeability curves. The initial gas/water saturation is predicted using variation of capillary entry pressure with depth, which in turn depends on the variation in grain-size distribution. This model provides a mechanistic approach for explaining large hydrate saturations (60%-75%) observed in zones of major hydrate saturation considering the governing characteristic relative permeability curves of the host sediments. We applied the model on data from Mount Elbert well on the Alaskan North Slope. It is shown that, assuming a cocurrent flow of gas and water into the GHSZ, such large hydrate saturations (up to 75%) cannot result from large initial gas saturations (close to 1-Sw,irr) due to limitations on water flux imposed by typical relative permeability curves. They could however result from modest initial gas saturations (ca. 40%) at which we have reasonable phase mobility ratios required for appropriate relative rates of gas and water transporting into GHSZ to form large hydrate saturations. Nevertheless, from the profile of capillary entry pressure vs. depth, we expect large initial gas saturations and thus the final high hydrate saturation suggests another form of water flow: water moves down through accumulated hydrate from the unfrozen water above. For this to happen the water phase must remain connected within the hydrate-bearing sediment. This seems plausible in hydrate bearing sediments because hydrate formation will be stopped before water saturation gets to very low values (lower than Sw,irr) due to salinity build up. The location of small hydrate saturations (10-15%) is consistent with the location of the residual gas phase established during water imbibition into these locations while they serve as a gas source to the layers above.

Estimation of hectare-scale soil-moisture characteristics from aquifer-test data

USGS Publications Warehouse

Moench, A.F.

2003-01-01

Analysis of a 72-h, constant-rate aquifer test conducted in a coarse-grained and highly permeable, glacial outwash deposit on Cape Cod, Massachusetts revealed that drawdowns measured in 20 piezometers located at various depths below the water table and distances from the pumped well were significantly influenced by effects of drainage from the vadose zone. The influence was greatest in piezometers located close to the water table and diminished with increasing depth. The influence of the vadose zone was evident from a gap, in the intermediate-time zone, between measured drawdowns and drawdowns computed under the assumption that drainage from the vadose zone occurred instantaneously in response to a decline in the elevation of the water table. By means of an analytical model that was designed to account for time-varying drainage, simulated drawdowns could be closely fitted to measured drawdowns regardless of the piezometer locations. Because of the exceptional quality and quantity of the data and the relatively small aquifer heterogeneity, it was possible by inverse modeling to estimate all relevant aquifer parameters and a set of three empirical constants used in the upper-boundary condition to account for the dynamic drainage process. The empirical constants were used to define a one-dimensional (ID) drainage versus time curve that is assumed to be representative of the bulk material overlying the water table. The curve was inverted with a parameter estimation algorithm and a ID numerical model for variably saturated flow to obtain soil-moisture retention curves and unsaturated hydraulic conductivity relationships defined by the Brooks and Corey equations. Direct analysis of the aquifer-test data using a parameter estimation algorithm and a two-dimensional, axisymmetric numerical model for variably saturated flow yielded similar soil-moisture characteristics. Results suggest that hectare-scale soil-moisture characteristics are different from core-scale predictions and even relatively small amounts of fine-grained material and heterogeneity can dominate the large-scale soil-moisture characteristics and aquifer response. ?? 2003 Elsevier B.V. All rights reserved.

Hydrologically Controlled Arsenic Release in Deltaic Wetlands and Coastal Riparian Zones

NASA Astrophysics Data System (ADS)

Stuckey, J.; LeMonte, J. J.; Yu, X.; Schaefer, M.; Kocar, B. D.; Benner, S. G.; Rinklebe, J.; Tappero, R.; Michael, H. A.; Fendorf, S. E.; Sparks, D. L.

2016-12-01

Wetland and riparian zone hydrology exerts critical controls on the biogeochemical cycling of metal contaminants including arsenic. The role of wetlands in driving geogenic arsenic release to groundwater has been debated in the deltas of South and Southeast Asia where the largest impacted human population resides. In addition, groundwater in coastal areas worldwide, such as those in South and Southeast Asia and the Mid-Atlantic of the U.S., is at risk to largely unexplored biogeochemical and hydrologic impacts of projected sea level rise. First, we present data from fresh-sediment incubations, in situ model sediment incubations and a controlled field experiment with manipulated wetland hydrology and organic carbon inputs in the minimally disturbed upper Mekong Delta. Here we show that arsenic release is limited to near-surface sediments of permanently saturated wetlands where both organic carbon and arsenic-bearing solids are sufficiently reactive for microbial oxidation of organic carbon and reduction of arsenic-bearing iron oxides. In contrast, within the deeper aquifer or seasonally saturated sediments, reductive dissolution of iron oxides is observed only when either more reactive exogenous forms of iron oxides or organic carbon are added, revealing a potential thermodynamic restriction to microbial metabolism. Second, in order to assess the potential impacts of sea level rise on arsenic release to groundwater, we determined the changes in arsenic speciation and partitioning in sediment collected from an anthropogenically contaminated coastal riparian zone under controlled Eh regimes in both seawater and freshwater systems. Here we show greater arsenic release under anoxic/suboxic conditions in the freshwater system than in the seawater system, potentially due to high salinity induced microbial inhibition. Collectively, our work shows that shifting hydrologic conditions in deltaic wetlands and tidally influenced zones impacts the extent of arsenic release to groundwater. Land and water management decisions that increase the duration of wetland inundation may promote arsenic release to groundwater.

Extreme pollution of soils by emissions of the copper-nickel industrial complex in the Kola Peninsula

NASA Astrophysics Data System (ADS)

Kashulina, G. M.

2017-07-01

The distribution of the total Ni, Cu, Co, Cd, Pb, and Zn contents was studied in the soil profiles of six catenas in the zone subjected to emissions of the copper-nickel industrial complex, which is the largest source of SO2 and heavy metals in northern Europe. The results show that, at present, the concentrations of Ni and Cu in the upper organic soil horizons in the impact zone reach extreme levels of 9000 and 6000 mg/kg, respectively. Under conditions of the long-term intense multi-element industrial emissions, the modern levels of the accumulation of polluting substances in soils greatly depend on the indirect factors, such as the degree of the technogenic degradation of soils with the loss of a significant part of soil organic matter, the reaching of threshold saturation of the topsoil with polluting metals, and competitive relationships between chemical elements. The state of the ecosystems in the impact zone varied greatly and did not always agree with the contents of the main metals-pollutants in the soils. The moisture conditions determined by the landscape position affected significantly the resistance of the ecosystems to emissions.

Elevated gas hydrate saturation within silt and silty clay sediments in the Shenhu area, South China Sea

USGS Publications Warehouse

Wang, X.; Hutchinson, D.R.; Wu, S.; Yang, S.; Guo, Y.

2011-01-01

Gas hydrate saturations were estimated using five different methods in silt and silty clay foraminiferous sediments from drill hole SH2 in the South China Sea. Gas hydrate saturations derived from observed pore water chloride values in core samples range from 10 to 45% of the pore space at 190-221 m below seafloor (mbsf). Gas hydrate saturations estimated from resistivity (Rt) using wireline logging results are similar and range from 10 to 40.5% in the pore space. Gas hydrate saturations were also estimated by P wave velocity obtained during wireline logging by using a simplified three-phase equation (STPE) and effective medium theory (EMT) models. Gas hydrate saturations obtained from the STPE velocity model (41.0% maximum) are slightly higher than those calculated with the EMT velocity model (38.5% maximum). Methane analysis from a 69 cm long depressurized core from the hydrate-bearing sediment zone indicates that gas hydrate saturation is about 27.08% of the pore space at 197.5 mbsf. Results from the five methods show similar values and nearly identical trends in gas hydrate saturations above the base of the gas hydrate stability zone at depths of 190 to 221 mbsf. Gas hydrate occurs within units of clayey slit and silt containing abundant calcareous nannofossils and foraminifer, which increase the porosities of the fine-grained sediments and provide space for enhanced gas hydrate formation. In addition, gas chimneys, faults, and fractures identified from three-dimensional (3-D) and high-resolution two-dimensional (2-D) seismic data provide pathways for fluids migrating into the gas hydrate stability zone which transport methane for the formation of gas hydrate. Sedimentation and local canyon migration may contribute to higher gas hydrate saturations near the base of the stability zone. Copyright 2011 by the American Geophysical Union.

Impact of sub-horizontal discontinuities and vertical heterogeneities on recharge processes in a weathered crystalline aquifer in southern India

NASA Astrophysics Data System (ADS)

Nicolas, Madeleine; Selles, Adrien; Bour, Olivier; Maréchal, Jean-Christophe; Crenner, Marion; Wajiduddin, Mohammed; Ahmed, Shakeel

2017-04-01

In the face of increasing demands for irrigated agriculture, many states in India are facing water scarcity issues, leading to severe groundwater depletion. Because perennial water resources in southern India consist mainly of crystalline aquifers, understanding how recharge takes place and the role of preferential flow zones in such heterogeneous media is of prime importance for successful and sustainable aquifer management. Here we investigate how vertical heterogeneities and highly transmissive sub-horizontal discontinuities may control groundwater flows and recharge dynamics. Recharge processes in the vadose zone were examined by analysing the propagation of an infiltration front and mass transfers resulting from the implementation of a managed aquifer recharge (MAR) structure. Said structure was set up in the Experimental Hydrogeological Park in Telangana (Southern India), a well-equipped and continuously monitored site, which is periodically supplied with surface water deviated from the nearby Musi river, downstream of Hyderabad. An initial volume balance equation was applied to quantify the overall inputs from the MAR structure into the groundwater system, which was confirmed using a chloride mass balance approach. To understand how this incoming mass is then distributed within the aquifer, we monitored the evolution of water volumes in the tank, and the resulting lateral propagation front observed in the surrounding borehole network. Borehole logs of temperature and conductivity were regularly performed to identify preferential flow paths. As a result we observed that mass transfers take place in the way of preferential lateral flow through the most transmissive zones of the profile. These include the interface between the lower portion of the upper weathered horizon (the saprolite) and the upper part of the underlying fissured granite, as well as the first flowing fractures. This leads to a rapid lateral transfer of recharge, which allows quick replenishment of aquifers but may have severe implications regarding groundwater quality, whether contaminants originate from diffuse sources (such as fertilizers), or a localized injection of polluted surface water. These findings confirm previous studies about the non-linear behaviour of hard rock aquifers (Guihéneuf et al., 2014) and recharge processes (Boisson et al., 2015; Alazard et al., 2015). Depending on water level conditions, the aquifer shifts from a regional flow system (when superficial more connected and weathered levels are saturated), to independent local flow systems (when only the lower lesser fractured portion is saturated). Thus recharge seems to be controlled by the existence of (i) vertical heterogeneities within the unsaturated zone and (ii) highly transmissive sub-horizontal discontinuities, both of which controlling groundwater flows and recharge dynamics.

Comparison of different assimilation methodologies of groundwater levels to improve predictions of root zone soil moisture with an integrated terrestrial system model

NASA Astrophysics Data System (ADS)

Zhang, Hongjuan; Kurtz, Wolfgang; Kollet, Stefan; Vereecken, Harry; Franssen, Harrie-Jan Hendricks

2018-01-01

The linkage between root zone soil moisture and groundwater is either neglected or simplified in most land surface models. The fully-coupled subsurface-land surface model TerrSysMP including variably saturated groundwater dynamics is used in this work. We test and compare five data assimilation methodologies for assimilating groundwater level data via the ensemble Kalman filter (EnKF) to improve root zone soil moisture estimation with TerrSysMP. Groundwater level data are assimilated in the form of pressure head or soil moisture (set equal to porosity in the saturated zone) to update state vectors. In the five assimilation methodologies, the state vector contains either (i) pressure head, or (ii) log-transformed pressure head, or (iii) soil moisture, or (iv) pressure head for the saturated zone only, or (v) a combination of pressure head and soil moisture, pressure head for the saturated zone and soil moisture for the unsaturated zone. These methodologies are evaluated in synthetic experiments which are performed for different climate conditions, soil types and plant functional types to simulate various root zone soil moisture distributions and groundwater levels. The results demonstrate that EnKF cannot properly handle strongly skewed pressure distributions which are caused by extreme negative pressure heads in the unsaturated zone during dry periods. This problem can only be alleviated by methodology (iii), (iv) and (v). The last approach gives the best results and avoids unphysical updates related to strongly skewed pressure heads in the unsaturated zone. If groundwater level data are assimilated by methodology (iii), EnKF fails to update the state vector containing the soil moisture values if for (almost) all the realizations the observation does not bring significant new information. Synthetic experiments for the joint assimilation of groundwater levels and surface soil moisture support methodology (v) and show great potential for improving the representation of root zone soil moisture.

THE VELOCITY OF DNAPL FINGERING IN WATER-SATURATED POROUS MEDIA LABORATORY EXPERIMENTS AND A MOBILE-IMMOBILE-ZONE MODEL. (R826157)

EPA Science Inventory

Dense nonaqueous phase liquids (DNAPLs) are immiscible with water and can give rise to highly fingered fluid distributions when infiltrating through water-saturated porous media. In this paper, a conceptual mobile_¯immobile_¯zone (MIZ) model is pr...

Effect of increased groundwater viscosity on the remedial performance of surfactant-enhanced air sparging

NASA Astrophysics Data System (ADS)

Choi, Jae-Kyeong; Kim, Heonki; Kwon, Hobin; Annable, Michael D.

2018-03-01

The effect of groundwater viscosity control on the performance of surfactant-enhanced air sparging (SEAS) was investigated using 1- and 2-dimensional (1-D and 2-D) bench-scale physical models. The viscosity of groundwater was controlled by a thickener, sodium carboxymethylcellulose (SCMC), while an anionic surfactant, sodium dodecylbenzene sulfonate (SDBS), was used to control the surface tension of groundwater. When resident DI water was displaced with a SCMC solution (500 mg/L), a SDBS solution (200 mg/L), and a solution with both SCMC (500 mg/L) and SDBS (200 mg/L), the air saturation for sand-packed columns achieved by air sparging increased by 9.5%, 128%, and 154%, respectively, (compared to that of the DI water-saturated column). When the resident water contained SCMC, the minimum air pressure necessary for air sparging processes increased, which is considered to be responsible for the increased air saturation. The extent of the sparging influence zone achieved during the air sparging process using the 2-D model was also affected by viscosity control. Larger sparging influence zones (de-saturated zone due to air injection) were observed for the air sparging processes using the 2-D model initially saturated with high-viscosity solutions, than those without a thickener in the aqueous solution. The enhanced air saturations using SCMC for the 1-D air sparging experiment improved the degradative performance of gaseous oxidation agent (ozone) during air sparging, as measured by the disappearance of fluorescence (fluorescein sodium salt). Based on the experimental evidence generated in this study, the addition of a thickener in the aqueous solution prior to air sparging increased the degree of air saturation and the sparging influence zone, and enhanced the remedial potential of SEAS for contaminated aquifers.

Uranium-series constraints on radionuclide transport and groundwater flow at the Nopal I uranium deposit, Sierra Pena Blanca, Mexico.

PubMed

Goldstein, Steven J; Abdel-Fattah, Amr I; Murrell, Michael T; Dobson, Patrick F; Norman, Deborah E; Amato, Ronald S; Nunn, Andrew J

2010-03-01

Uranium-series data for groundwater samples from the Nopal I uranium ore deposit were obtained to place constraints on radionuclide transport and hydrologic processes for a nuclear waste repository located in fractured, unsaturated volcanic tuff. Decreasing uranium concentrations for wells drilled in 2003 are consistent with a simple physical mixing model that indicates that groundwater velocities are low ( approximately 10 m/y). Uranium isotopic constraints, well productivities, and radon systematics also suggest limited groundwater mixing and slow flow in the saturated zone. Uranium isotopic systematics for seepage water collected in the mine adit show a spatial dependence which is consistent with longer water-rock interaction times and higher uranium dissolution inputs at the front adit where the deposit is located. Uranium-series disequilibria measurements for mostly unsaturated zone samples indicate that (230)Th/(238)U activity ratios range from 0.005 to 0.48 and (226)Ra/(238)U activity ratios range from 0.006 to 113. (239)Pu/(238)U mass ratios for the saturated zone are <2 x 10(-14), and Pu mobility in the saturated zone is >1000 times lower than the U mobility. Saturated zone mobility decreases in the order (238)U approximately (226)Ra > (230)Th approximately (239)Pu. Radium and thorium appear to have higher mobility in the unsaturated zone based on U-series data from fractures and seepage water near the deposit.

Explosion Amplitude Reduction due to Fractures in Water-Saturated and Dry Granite

NASA Astrophysics Data System (ADS)

Stroujkova, A. F.; Leidig, M.; Bonner, J. L.

2013-12-01

Empirical observations made at the Semipalatinsk Test Site suggest that nuclear tests in the fracture zones left by previous explosions ('repeat shots') show reduced seismic amplitudes compared to the nuclear tests in virgin rocks. Likely mechanisms for the amplitude reduction in the repeat shots include increased porosity and reduced strength and elastic moduli, leading to pore closing and frictional sliding. Presence of pore water significantly decreases rock compressibility and strength, thus affecting seismic amplitudes. A series of explosion experiments were conducted in order to define the physical mechanism responsible for the amplitude reduction and to quantify the degree of the amplitude reduction in fracture zones of previously detonated explosions. Explosions in water-saturated granite were conducted in central New Hampshire in 2011 and 2012. Additional explosions in dry granite were detonated in Barre, VT in 2013. The amplitude reduction is different between dry and water-saturated crystalline rocks. Significant reduction in seismic amplitudes (by a factor of 2-3) in water-saturated rocks was achieved only when the repeat shot was detonated in the extensive damage zone created by a significantly larger (by a factor of 5) explosion. In case where the first and the second explosions were similar in yield, the amplitude reduction was relatively modest (5-20%). In dry rocks the amplitude reduction reached a factor of 2 even in less extensive damage zones. In addition there are differences in frequency dependence of the spectral amplitude ratios between explosions in dry and water-saturated rocks. Thus the amplitude reduction is sensitive to the extent of the damage zone as well as the pore water content.

Fast ground-water mixing and basal recharge in an unconfined, alluvial aquifer, Konza LTER Site, Northeastern Kansas

USGS Publications Warehouse

Macpherson, G.L.; Sophocleous, M.

2004-01-01

Ground-water chemistry and water levels at three levels in a well nest were monitored biweekly for two and a half years in a shallow unconfined floodplain aquifer in order to study the dynamics of such shallow aquifers. The aquifer, in northeastern Kansas, consists of high porosity, low hydraulic conductivity fine-grained sediments dominated by silt and bounded by fractured limestone and shale bedrock. Results show that the aquifer underwent chemical stratification followed by homogenization three times during the study period. The length of time between maximum stratification and complete homogenization was 3-5 months. The chemical parameters most useful for demonstrating the mixing trends were dissolved nitrate and sulfate. Higher nitrate concentrations were typical of unsaturated zone water and were sourced from fertilizer applied to the cultivated fields on the floodplain. Variations in sulfate concentrations are attributed to dissolution of rare gypsum in limestone bedrock and variable evapoconcentration in the unsaturated zone. The mixing of three chemically different waters (entrained, unsaturated-zone water; water entering the base of the floodplain aquifer; and water in residence before each mixing event) was simulated. The resident water component for each mixing event was a fixed composition based on measured water chemistry in the intermediate part of the aquifer. The entrained water composition was calculated using a measured composition of the shallow part of the aquifer and measurements of soil-water content in the unsaturated zone. The incoming basal water composition and the fractions of each mixing component were fitted to match the measured chemistry at the three levels in the aquifer. A conceptual model for this site explains: (1) rapid water-level rises, (2) water-chemistry changes at all levels in the aquifer coincident with the water-level rises, (3) low measured hydraulic conductivity of the valley fill and apparent lack of preferential flow pathways, (4) minuscule amounts of unsaturated-zone recharge, and (5) dissolved oxygen peaks in the saturated zone lagging water-level peaks. We postulate that rainfall enters fractures in bedrock adjacent to the floodplain. This recharge water moves rapidly through the fractured bedrock into the base of the floodplain aquifer. The recharge event through the bedrock causes a rapid rise in water level in the floodplain aquifer, and the chemistry of the deepest water in the floodplain aquifer changes at that time. The rising water also entrains slow-moving, nitrate-rich, unsaturated-zone water, altering the chemistry of water in the shallow part of the aquifer. Vertical chemical stratification in the aquifer is thus created by the change in water chemistry in the upper and lower parts of the saturated zone. As the water level begins to decline, the aquifer undergoes mixing that eventually results in homogeneous water chemistry. The rise in water level from the recharge event also displaces gas from the unsaturated zone that is then replaced as the water level declines following the recharge event. This new, oxygen-rich vadose-zone air equilibrates rapidly with saturated-zone water, resulting in a dissolved oxygen pulse in the ground water that peaks one-half to 2 months after the water-level peak. This oxygen pulse subsequently declines over a period of 2-6 months. ?? 2003 Elsevier B.V. All rights reserved.

Development of a large volume of eruptible mush in the upper Wooley Creek batholith, Klamath Mountains, California: evidence from bulk rock, mineral analyses and textural observations

NASA Astrophysics Data System (ADS)

Coint, N.; Barnes, C. G.; Barnes, M. A.; Yoshinobu, A. S.

2012-12-01

The modalities of development of large volumes of mush in the middle to upper crust capable of erupting have been debated over the past few years. The existence of crystal-rich ignimbrites in the volcanic record indicate that eruptive products do not necessarily correspond to evacuation of the residual magma but that the mush itself can be drained during eruptive events. In this study we present a plutonic example of a large magma batch that evolved by fractional crystallization at a hundred km3 scale: the upper zone of the Wooley Creek batholith (WCb). The WCb is an intrusive complex emplaced over less than 3 m.y. (Kevin Chamberlain, personal communication). The upper zone grades upward from quartz diorite (53 wt% SiO2) to granite (70 wt% SiO2). Hornblende from the central and upper zone have rare earth element patterns that are parallel to one another and with REE concentrations and negative Eu anomalies that decrease from core to rim. The similarities of hornblende REE patterns throughout both the central and upper zones of the system (160 km2 of exposed area) suggest that hornblende crystallized from a magma batch of fairly homogeneous composition. Thus, upward changes in bulk composition between rocks at the bottom and the top of this unit result from varying mineral proportions, with more subhedral plagioclase and hornblende at the bottom and more anhedral to euhedral quartz and interstitial to poikilitic K-feldspar at the top. Two possible explanations are considered: 1) more felsic batches of magma were emplaced at the top of the system and more mafic ones were restricted to the bottom, 2) the upper zone acquired its upward compositional zoning through melt percolation, with the less dense felsic melt ponding at the roof of the system. In the first case, the similarity of hornblende REE patterns throughout the upper zone cannot be explained. Therefore, we favor the second explanation, which is also supported by the lack of sharp contacts in the upper zone. Individual magma batches in the central zone contain hornblende of similar composition as in the upper zone and are interpreted as a preserved part of the feeder system of the latter. Therefore the magma in both the central and upper WCb was already fairly homogeneous when it arrived at the level of emplacement. Dacitic to rhyodacitic roof dikes with30-40% phenocrysts of hornblende and plagioclase with compositions similar to those found in the central and upper zones indicate that the mush was once eruptible. The presence of quartz phenocrysts, which are only found in the uppermost portion of the upper zone, show that 'eruption' occurred after the development of the broad zoning of the upper zone and after more evolved melt had collected at the top of an underlying mush. This study introduces new tools to study magmatic reservoir evolution. The combination of bulk rock and mineral data allows assessment of the extent of mineral-melt separation and identification of the composition of a potential parental magma(s). These data can ideally be used to delimit the size of magma batches and constrain the scale of their chemical/physical connectivity.

High rates of organic carbon processing in the hyporheic zone of intermittent streams.

PubMed

Burrows, Ryan M; Rutlidge, Helen; Bond, Nick R; Eberhard, Stefan M; Auhl, Alexandra; Andersen, Martin S; Valdez, Dominic G; Kennard, Mark J

2017-10-16

Organic carbon cycling is a fundamental process that underpins energy transfer through the biosphere. However, little is known about the rates of particulate organic carbon processing in the hyporheic zone of intermittent streams, which is often the only wetted environment remaining when surface flows cease. We used leaf litter and cotton decomposition assays, as well as rates of microbial respiration, to quantify rates of organic carbon processing in surface and hyporheic environments of intermittent and perennial streams under a range of substrate saturation conditions. Leaf litter processing was 48% greater, and cotton processing 124% greater, in the hyporheic zone compared to surface environments when calculated over multiple substrate saturation conditions. Processing was also greater in more saturated surface environments (i.e. pools). Further, rates of microbial respiration on incubated substrates in the hyporheic zone were similar to, or greater than, rates in surface environments. Our results highlight that intermittent streams are important locations for particulate organic carbon processing and that the hyporheic zone sustains this fundamental process even without surface flow. Not accounting for carbon processing in the hyporheic zone of intermittent streams may lead to an underestimation of its local ecological significance and collective contribution to landscape carbon processes.

Redox-influenced seismic properties of upper-mantle olivine

NASA Astrophysics Data System (ADS)

Cline, C. J., II; Faul, U. H.; David, E. C.; Berry, A. J.; Jackson, I.

2018-03-01

Lateral variations of seismic wave speeds and attenuation (dissipation of strain energy) in the Earth’s upper mantle have the potential to map key characteristics such as temperature, major-element composition, melt fraction and water content. The inversion of these data into meaningful representations of physical properties requires a robust understanding of the micromechanical processes that affect the propagation of seismic waves. Structurally bound water (hydroxyl) is believed to affect seismic properties but this has yet to be experimentally quantified. Here we present a comprehensive low-frequency forced-oscillation assessment of the seismic properties of olivine as a function of water content within the under-saturated regime that is relevant to the Earth’s interior. Our results demonstrate that wave speeds and attenuation are in fact strikingly insensitive to water content. Rather, the redox conditions imposed by the choice of metal sleeving, and the associated defect chemistry, appear to have a substantial influence on the seismic properties. These findings suggest that elevated water contents are not responsible for low-velocity or high-attenuation structures in the upper mantle. Instead, the high attenuation observed in hydrous and oxidized regions of the upper mantle (such as above subduction zones) may reflect the prevailing oxygen fugacity. In addition, these data provide no support for the hypothesis whereby a sharp lithosphere–asthenosphere boundary is explained by enhanced grain boundary sliding in the presence of water.

Carbon dioxide concentration in caves and soils in an alpine setting: implications for speleothem fabrics and their palaeoclimate significance

NASA Astrophysics Data System (ADS)

Borsato, Andrea; Frisia, Silvia; Miorandi, Renza

2015-04-01

Carbon dioxide concentration in soils controls carbonate dissolution, soil CO2 efflux to the atmosphere, and CO2 transfer to the subsurface that lead, ultimately, to speleothem precipitation. Systematic studies on CO2 concentration variability in soil and caves at regional scale are, however, few. Here, the systematic investigation of CO2 concentration in caves and soils in a temperate, Alpine region along a 2,100 m altitudinal range transect, which corresponds to a mean annual temperature (MAT) range of 12°C is presented. Soil pCO2 is controlled by the elevation and MAT and exhibits strong seasonality, which follows surface air temperature with a delay of about a month. The aquifer pCO2, by contrast, is fairly constant throughout the year, and it is primarily influenced by summer soil pCO2. Cave CO2 concentration is a balance between the CO2 influx and CO2 efflux, where the efflux is controlled by the cave ventilation, which is responsible for low pCO2 values recorded in most of the caves with respect to soil levels. Carbon dioxide in the innermost part of the studied caves exhibits a clear seasonal pattern. Thermal convection is the most common mechanism causing higher ventilation and low cave air pCO2 levels during the winter season: this promotes CO2 degassing and higher supersaturation in the drip water and, eventually, higher speleothem growth rates during winter. The combined influence of three parameters - dripwater pCO2, dripwater Ca content, and cave air pCO2 - all related to the infiltration elevation and MAT directly controls calcite supersaturation in dripwater. Four different altitudinal belts are then defined, which reflect temperature-dependent saturation state of dripwaters. These belts broadly correspond to vegetation zones: the lower montane (100 to 800 m asl), the upper montane (800 to 1600 m asl), the subalpine (1600 to 2200 m asl) and the Alpine (above 2200 m asl). Each altitudinal belt is characterised by different calcite fabrics, which can shift upward/downward in elevation as a response to temperature increase/decrease through time. In the lower and upper montane zones the columnar types (compact, open, fascicular optic) are the most common fabrics, with the microcrystalline type most typical of the upper montane zone. The dendritic fabric becomes predominant in the higher upper montane and lower subalpine zones. The higher subalpine to lower alpine zones the only speleothem actually forming is moonmilk. Eventually, the occurrence of "altitudinal" fabrics within the vertical growth axis of a stalagmite is indicative of changes in the MAT through time Therefore, fabric changes in fossil speleothems in temperate climate settings can be potentially used to reconstruct regional MAT changes in the past.

Linking pore-scale and basin-scale effects on diffusive methane transport in hydrate bearing environments through multi-scale reservoir simulations

NASA Astrophysics Data System (ADS)

Nole, M.; Daigle, H.; Cook, A.; Malinverno, A.; Hillman, J. I. T.

2016-12-01

We explore the gas hydrate-generating capacity of diffusive methane transport induced by solubility gradients due to pore size contrasts in lithologically heterogeneous marine sediments. Through the use of 1D, 2D, and 3D reactive transport simulations, we investigate scale-dependent processes in diffusion-dominated gas hydrate systems. These simulations all track a sand body, or series of sands, surrounded by clays as they are buried through the gas hydrate stability zone. Methane is sourced by microbial methanogenesis in the clays surrounding the sand layers. In 1D, simulations performed in a Lagrangian reference frame demonstrate that gas hydrate in thin sands (3.6 m thick) can occur in high saturations (upward of 70%) at the edges of sand bodies within the upper 400 meters below the seafloor. Diffusion of methane toward the center of the sand layer depends on the concentration gradient within the sand: broader sand pore size distributions with smaller median pore sizes enhance diffusive action toward the sand's center. Incorporating downhole log- and laboratory-derived sand pore size distributions, gas hydrate saturations in the center of the sand can reach 20% of the hydrate saturations at the sand's edges. Furthermore, we show that hydrate-free zones exist immediately above and below the sand and are approximately 5 m thick, depending on the sand-clay solubility contrast. A moving reference frame is also adopted in 2D, and the angle of gravity is rotated relative to the grid system to simulate a dipping sand layer. This is important to minimize diffusive edge effects or numerical diffusion that might be associated with a dipping sand in an Eulerian grid system oriented orthogonal to gravity. Two-dimensional simulations demonstrate the tendency for gas hydrate to accumulate downdip in a sand body because of greater methane transport at depth due to larger sand-clay solubility contrasts. In 3D, basin-scale simulations illuminate how convergent sand layers in a multilayered system can compete for diffusion from clays between them, resulting in relatively low hydrate saturations. All simulations suggest that when hydrate present in clays dissociates with burial, the additional dissolved methane is soaked up by nearby sands preserving high hydrate saturations.

Linking pore-scale and basin-scale effects on diffusive methane transport in hydrate bearing environments through multi-scale reservoir simulations

DOE Office of Scientific and Technical Information (OSTI.GOV)

Nole, Michael; Daigle, Hugh; Cook, Ann

We explore the gas hydrate-generating capacity of diffusive methane transport induced by solubility gradients due to pore size contrasts in lithologically heterogeneous marine sediments. Through the use of 1D, 2D, and 3D reactive transport simulations, we investigate scale-dependent processes in diffusion-dominated gas hydrate systems. These simulations all track a sand body, or series of sands, surrounded by clays as they are buried through the gas hydrate stability zone. Methane is sourced by microbial methanogenesis in the clays surrounding the sand layers. In 1D, simulations performed in a Lagrangian reference frame demonstrate that gas hydrate in thin sands (3.6 m thick)more » can occur in high saturations (upward of 70%) at the edges of sand bodies within the upper 400 meters below the seafloor. Diffusion of methane toward the center of the sand layer depends on the concentration gradient within the sand: broader sand pore size distributions with smaller median pore sizes enhance diffusive action toward the sand’s center. Incorporating downhole log- and laboratory-derived sand pore size distributions, gas hydrate saturations in the center of the sand can reach 20% of the hydrate saturations at the sand’s edges. Furthermore, we show that hydrate-free zones exist immediately above and below the sand and are approximately 5 m thick, depending on the sand-clay solubility contrast. A moving reference frame is also adopted in 2D, and the angle of gravity is rotated relative to the grid system to simulate a dipping sand layer. This is important to minimize diffusive edge effects or numerical diffusion that might be associated with a dipping sand in an Eulerian grid system oriented orthogonal to gravity. Two-dimensional simulations demonstrate the tendency for gas hydrate to accumulate downdip in a sand body because of greater methane transport at depth due to larger sand-clay solubility contrasts. In 3D, basin-scale simulations illuminate how convergent sand layers in a multilayered system can compete for diffusion from clays between them, resulting in relatively low hydrate saturations. All simulations suggest that when hydrate present in clays dissociates with burial, the additional dissolved methane is soaked up by nearby sands preserving high hydrate saturations.« less

Iron Isotope Fractionation in the Bushveld Igneous Complex Provide Insight into Fractional Crystallization

NASA Astrophysics Data System (ADS)

Rios, K. L.; Feineman, M. D.; Bybee, G. M.

2016-12-01

Dated at 2.056 Ga and encompassing an estimated 65,000 km2 in surface area and 650,000 km3 in volume the Bushveld Igneous Complex in South Africa contains the largest and most unique layered mafic intrusion in the world. It contains 80-90% of the world's minable platinum group elements. Scientists are interested in understanding the origin of this intrusion due to its massive size, unique assemblage of minerals, and strongly zoned stratigraphy. Iron isotopes may help us to understand the roles of partial mantle melting and fractional crystallization in magma genesis and differentiation. For example, it may be possible to determine what role fractional crystallization of oxides and sulfides played in the formation of the Rustenburg Layered Suite (RLS) by comparing δ56Fe in samples from the Lower, Critical, Main and Upper Zones. The use of MC-ICPMS has made it more routine to study the fractionation of stable iron isotopes in natural systems; however, this technique has only been applied in a few studies of the RLS, mostly restricted to the Upper Main and Upper Zones. In this study δ56Fe was determined in Upper Zone magnetite, Critical Zone chromitite and Critical Zone sulfides using MC-ICP-MS. Previous research has shown that early crystallizing mafic phases incorporate the lighter 54Fe isotope leaving a residual magma with a higher δ56Fe value. Therefore, if the Upper Zone magma represents a high-degree differentiate of the parental Bushveld magma, then magmas from the Upper Zone would be expected to have a higher δ56Fe than magmas contributing to the Lower, Critical and Main Zones. The results of this experiment were indeed consistent with this hypothesis. The δ56Fe values recorded for the three sample types were: magnetite 0.19 ±0.03‰; sulfides -0.45 ±0.03‰ to -0.81 ±0.03‰; and chromitite 0.03 ±0.05‰. The sulfides of the Critical Zone are isotopically lighter than would be predicted based on equilibrium sulfide-melt fractionation, if the parental melt of the Critical Zone were in equilibrium with previously published whole rock data for Upper Zone. This is consistent with interpretations of the Upper Zone as a high degree differentiate of the Bushveld Parental Magma.

TDEM survey in an area of seismicity induced by water wells in Paraná sedimentary basin, Northern São Paulo State, Brazil

NASA Astrophysics Data System (ADS)

Porsani, Jorge Luís; Almeida, Emerson Rodrigo; Bortolozo, Cassiano Antonio; Santos, Fernando Acácio Monteiro dos

2012-07-01

This article presents TDEM results from an area with recent induced shallow seismicity. The purpose was to do a geoelectrical mapping of sedimentary and fractured basaltic aquifers for better understanding of the hydrogeologic setting. The study area is in the Paraná basin where flood basalts are overlain by sedimentary units near the city of Bebedouro, northern São Paulo State, Brazil. 86 TDEM soundings were acquired in an area of 90 km2 in the Andes and Botafogo study areas. The soundings were chosen next to wells for calibration, and also along profiles crossing the seismically active areas. 1-D interpretation results showed the general geoelectrical stratigraphy of this part of the Paraná basin. The upper geoelectrical layer is the shallow sedimentary aquifer (Adamantina formation) with less than 80 m thickness. The second geoelectrical layer contains the upper basalts of the Serra Geral formation at about 60-80 m depths. A saturated fractured basalt zone between 100 and 300 m depths was identifiable on various TDEM soundings. This depth range corresponds to the range of hypocentral depths for more than 3000 micro-earthquakes in this area. The lower basalt layer was estimated to lie between 400 and 650 m depth. The deepest geoelectrical layer detected by various TDEM soundings corresponds to the Botucatu sandstone (Guarani aquifer). Results suggest that the high-discharge wells are located in the fractured zone in the middle basalt of the Serra Geral formation. There is a good correlation between seismically active areas, high discharge wells (> 190 m3/h), and fracture zones in the middle basalt. The results reinforce the hypothesis that the shallow seismic activity in the Bebedouro region is being triggered by high rates of groundwater withdrawal.

Geologic setting, sedimentary architecture, and paragenesis of the Mesoproterozoic sediment-hosted Sheep Creek Cu-Co-Ag deposit, Helena embayment, Montana

USGS Publications Warehouse

Graham, Garth; Hitzman, Murray W.; Zieg, Jerry

2012-01-01

The northern margin of the Helena Embayment contains extensive syngenetic to diagenetic massive pyrite horizons that extend over 25 km along the Volcano Valley-Buttress fault zone and extend up to 8 km basinward (south) within the Mesoproterozoic Newland Formation. The Sheep Creek Cu-Co deposit occurs within a structural block along a bend in the fault system, where replacement-style chalcopyrite mineralization is spatially associated mostly with the two stratigraphically lowest massive pyrite zones. These mineralized pyritic horizons are intercalated with debris flows derived from synsedimentary movement along the Volcano Valley-Buttress fault zone. Cominco American Inc. delineated a geologic resource of 4.5 Mt at 2.5% Cu and 0.1% Co in the upper sulfide zone and 4 Mt at 4% Cu within the lower sulfide zone. More recently, Tintina Resources Inc. has delineated an inferred resource of 8.48 Mt at 2.96% Cu, 0.12% Co, and 16.4 g/t Ag in the upper sulfide zone. The more intact upper sulfide zone displays significant thickness variations along strike thought to represent formation in at least three separate subbasins. The largest accumulation of mineralized sulfide in the upper zone occurs as an N-S–trending body that thickens southward from the generally E trending Volcano Valley Fault and probably occupies a paleograben controlled by normal faults in the hanging wall of the Volcano Valley Fault. Early microcrystalline to framboidal pyrite was accompanied by abundant and local barite deposition in the upper and lower sulfide zones, respectively. The sulfide bodies underwent intense (lower sulfide zone) to localized (upper sulfide zone) recrystallization and overprinting by coarser-grained pyrite and minor marcasite that is intergrown with and replaces dolomite. Silicification and paragenetically late chalcopyrite, along with minor tennantite in the upper sulfide zone, replaces fine-grained pyrite, barite, and carbonate. The restriction of chalcopyrite to inferred synsedimentary E- and northerly trending faults and absence of definitive zonation with respect to the Laramide Volcano Valley Fault in the lower sulfide zone suggest a diagenetic age related to basin development for the Sheep Creek Cu-Co-Ag deposit.

Thermohydrologic modeling of the large-block test in partially saturated fractured tuff at Yucca Mountain, Nevada

NASA Astrophysics Data System (ADS)

Lee, K.; Buscheck, T. A.; Glascoe, L. G.; Gansemer, J.; Sun, Y.

2002-12-01

In support of the characterization of Yucca Mountain as a potential site for as a geologic repository for high-level nuclear waste, the US Department of Energy conducted the Large Block Test (LBT) at nearby Fran Ridge. The LBT was conducted in an excavated 3x 3x 4.5m block of partially saturated, fractured nonlithophysal Topopah Spring tuff, which is one of the host-rock units for the potential repository at Yucca Mountain. The LBT was one of a series of field-scale thermohydrologic tests conducted in the repository host-rock units. The LBT was heated by line heaters installed in five boreholes lying in a horizontal plane 2.75 m below the upper surface of the block. The field-scale thermal tests were designed to help investigators better understand the coupled thermohydrologic-mechanical-chemical processes that would occur in the host rock in response to the radioactive heat of decay from emplaced waste packages. The tests also provide data for the calibration and validation of numerical models used to analyze the thermohydrologic response of the near-field host rock and Engineered Barrier System (EBS). Using the NUFT code and the dual-permeability approach to representing fracture-matrix interaction, we simulated the thermohydrologic response of the block to a heating and cooling cycle. The primary goals of the analysis were to study the heat-flow mechanisms and water redistribution patterns in the boiling and sub-boiling zones, and to compare model results with measured temperature and liquid saturation data, and thereby evaluate two rock property data sets available for modeling thermohydrologic behavior in the rock. Model results were also used for model calibration and validation. We obtained a good to excellent match between model and observed temperatures, and found that the distinct dryout and condensation zones modeled above and below the heater level agreed fairly well with the liquid-saturation measurements. We identified the best-fit data set by using a statistical analysis to compare model and field temperatures, and found that heat flow in the block was dominated by conduction.

Limited denitrification in glacial deposit aquifers having thick unsaturated zones (Long Island, USA)

USGS Publications Warehouse

Young, Caitlin; Kroeger, Kevin D.; Hanson, Gilbert

2013-01-01

The goal of this study was to demonstrate how the extent of denitrification, which is indirectly related to dissolved organ carbon and directly related to oxygen concentrations, can also be linked to unsaturated-zone thickness, a mappable aquifer property. Groundwater from public supply and monitoring wells in Northport on Long Island, New York state (USA), were analyzed for denitrification reaction progress using dissolved N2/Ar concentrations by membrane inlet mass spectrometry. This technique allows for discernment of small amounts of excess N2, attributable to denitrification. Results show an average 15 % of total nitrogen in the system was denitrified, significantly lower than model predictions of 35 % denitrification. The minimal denitrification is due to low dissolved organic carbon (29.3–41.1 μmol L−1) and high dissolved oxygen concentrations (58–100 % oxygen saturation) in glacial sediments with minimal solid-phase electron donors to drive denitrification. A mechanism is proposed that combines two known processes for aquifer re-aeration in unconsolidated sands with thick (>10 m) unsaturated zones. First, advective flux provides 50 % freshening of pore space oxygen in the upper 2 m due to barometric pressure changes. Then, oxygen diffusion across the water-table boundary occurs due to high volumetric air content in the unsaturated-zone catchment area.

Validating modelled variable surface saturation in the riparian zone with thermal infrared images

NASA Astrophysics Data System (ADS)

Glaser, Barbara; Klaus, Julian; Frei, Sven; Frentress, Jay; Pfister, Laurent; Hopp, Luisa

2015-04-01

Variable contributing areas and hydrological connectivity have become prominent new concepts for hydrologic process understanding in recent years. The dynamic connectivity within the hillslope-riparian-stream (HRS) system is known to have a first order control on discharge generation and especially the riparian zone functions as runoff buffering or producing zone. However, despite their importance, the highly dynamic processes of contraction and extension of saturation within the riparian zone and its impact on runoff generation still remain not fully understood. In this study, we analysed the potential of a distributed, fully coupled and physically based model (HydroGeoSphere) to represent the spatial and temporal water flux dynamics of a forested headwater HRS system (6 ha) in western Luxembourg. The model was set up and parameterised under consideration of experimentally-derived knowledge of catchment structure and was run for a period of four years (October 2010 to August 2014). For model evaluation, we especially focused on the temporally varying spatial patterns of surface saturation. We used ground-based thermal infrared (TIR) imagery to map surface saturation with a high spatial and temporal resolution and collected 20 panoramic snapshots of the riparian zone (ca. 10 by 20 m) under different hydrologic conditions. These TIR panoramas were used in addition to several classical discharge and soil moisture time series for a spatially-distributed model validation. In a manual calibration process we optimised model parameters (e.g. porosity, saturated hydraulic conductivity, evaporation depth) to achieve a better agreement between observed and modelled discharges and soil moistures. The subsequent validation of surface saturation patterns by a visual comparison of processed TIR panoramas and corresponding model output panoramas revealed an overall good accordance for all but one region that was always too dry in the model. However, quantitative comparisons of modelled and observed saturated pixel percentages and of their modelled and measured relationships to concurrent discharges revealed remarkable similarities. During the calibration process we observed that surface saturation patterns were mostly affected by changing the soil properties of the topsoil in the riparian zone, but that the discharge behaviour did not change substantially at the same time. This effect of various spatial patterns occurring concomitant to a nearly unchanged integrated response demonstrates the importance of spatially distributed validation data. Our study clearly benefited from using different kinds of data - spatially integrated and distributed, temporally continuous and discrete - for the model evaluation procedure.

Seismicity, faulting, and structure of the Koyna-Warna seismic region, Western India from local earthquake tomography and hypocenter locations

NASA Astrophysics Data System (ADS)

Dixit, Madan M.; Kumar, Sanjay; Catchings, R. D.; Suman, K.; Sarkar, Dipankar; Sen, M. K.

2014-08-01

Although seismicity near Koyna Reservoir (India) has persisted for ~50 years and includes the largest induced earthquake (M 6.3) reported worldwide, the seismotectonic framework of the area is not well understood. We recorded ~1800 earthquakes from 6 January 2010 to 28 May 2010 and located a subset of 343 of the highest-quality earthquakes using the tomoDD code of Zhang and Thurber (2003) to better understand the framework. We also inverted first arrivals for 3-D Vp, Vs, and Vp/Vs and Poisson's ratio tomography models of the upper 12 km of the crust. Epicenters for the recorded earthquakes are located south of the Koyna River, including a high-density cluster that coincides with a shallow depth (<1.5 km) zone of relatively high Vp and low Vs (also high Vp/Vs and Poisson's ratios) near Warna Reservoir. This anomalous zone, which extends near vertically to at least 8 km depth and laterally northward at least 15 km, is likely a water-saturated zone of faults under high pore pressures. Because many of the earthquakes occur on the periphery of the fault zone, rather than near its center, the observed seismicity-velocity correlations are consistent with the concept that many of the earthquakes nucleate in fractures adjacent to the main fault zone due to high pore pressure. We interpret our velocity images as showing a series of northwest trending faults locally near the central part of Warna Reservoir and a major northward trending fault zone north of Warna Reservoir.

Biodegradation of subsurface oil in a tidally influenced sand beach: Impact of hydraulics and interaction with pore water chemistry

NASA Astrophysics Data System (ADS)

Geng, Xiaolong; Boufadel, Michel C.; Lee, Kenneth; Abrams, Stewart; Suidan, Makram

2015-05-01

The aerobic biodegradation of oil in tidally influenced beaches was investigated numerically in this work using realistic beach and tide conditions. A numerical model BIOMARUN, coupling a multiple-Monod kinetic model BIOB to a density-dependent variably saturated groundwater flow model 2-D MARUN, was used to simulate the biodegradation of low-solubility hydrocarbon and transport processes of associated solute species (i.e., oxygen and nitrogen) in a tidally influenced beach environment. It was found that different limiting factors affect different portions of the beach. In the upper intertidal zone, where the inland incoming nutrient concentration was large (1.2 mg N/L), oil biodegradation occurred deeper in the beach (i.e., 0.3 m below the surface). In the midintertidal zone, a reversal was noted where the biodegradation was fast at shallow locations (i.e., 0.1 m below the surface), and it was due to the decrease of oxygen with depth due to consumption, which made oxygen the limiting factor for biodegradation. Oxygen concentration in the midintertidal zone exhibited two peaks as a function of time. One peak was associated with the high tide, when dissolved oxygen laden seawater filled the beach and a second oxygen peak was observed during low tides, and it was due to pore oxygen replenishment from the atmosphere. The effect of the capillary fringe (CF) height was investigated, and it was found that there is an optimal CF for the maximum biodegradation of oil in the beach. Too large a CF (i.e., very fine material) would attenuate oxygen replenishment (either from seawater or the atmosphere), while too small a CF (i.e., very coarse material) would reduce the interaction between microorganisms and oil in the upper intertidal zone due to rapid reduction in the soil moisture at low tide. This article was corrected on 22 JUN 2015. See the end of the full text for details.

On the value of surface saturated area dynamics mapped with thermal infrared imagery for modeling the hillslope-riparian-stream continuum

NASA Astrophysics Data System (ADS)

Glaser, Barbara; Klaus, Julian; Frei, Sven; Frentress, Jay; Pfister, Laurent; Hopp, Luisa

2016-10-01

The highly dynamic processes within a hillslope-riparian-stream (HRS) continuum are known to affect streamflow generation, but are yet not fully understood. Within this study, we simulated a headwater HRS continuum in western Luxembourg with an integrated hydrologic surface subsurface model (HydroGeoSphere). The model was setup with thorough consideration of catchment-specific attributes and we performed a multicriteria model evaluation (4 years) with special focus on the temporally varying spatial patterns of surface saturation. We used a portable thermal infrared (TIR) camera to map surface saturation with a high spatial resolution and collected 20 panoramic snapshots of the riparian zone (approx. 10 m × 20 m) under different hydrologic conditions. Qualitative and quantitative comparison of the processed TIR panoramas and the corresponding model output panoramas revealed a good agreement between spatiotemporal dynamic model and field surface saturation patterns. A double logarithmic linear relationship between surface saturation extent and discharge was similar for modeled and observed data. This provided confidence in the capability of an integrated hydrologic surface subsurface model to represent temporal and spatial water flux dynamics at small (HRS continuum) scales. However, model scenarios with different parameterizations of the riparian zone showed that discharge and surface saturation were controlled by different parameters and hardly influenced each other. Surface saturation only affected very fast runoff responses with a small volumetric contribution to stream discharge, indicating that the dynamic surface saturation in the riparian zone does not necessarily imply a major control on runoff generation.

Evolution of the conceptual model of unsaturated zone hydrology at Yucca Mountain, Nevada

NASA Astrophysics Data System (ADS)

Flint, Alan L.; Flint, Lorraine E.; Bodvarsson, Gudmundur S.; Kwicklis, Edward M.; Fabryka-Martin, June

2001-06-01

Yucca Mountain is an arid site proposed for consideration as the United States' first underground high-level radioactive waste repository. Low rainfall (approximately 170 mm/yr) and a thick unsaturated zone (500-1000 m) are important physical attributes of the site because the quantity of water likely to reach the waste and the paths and rates of movement of the water to the saturated zone under future climates would be major factors in controlling the concentrations and times of arrival of radionuclides at the surrounding accessible environment. The framework for understanding the hydrologic processes that occur at this site and that control how quickly water will penetrate through the unsaturated zone to the water table has evolved during the past 15 yr. Early conceptual models assumed that very small volumes of water infiltrated into the bedrock (0.5-4.5 mm/yr, or 2-3 percent of rainfall), that much of the infiltrated water flowed laterally within the upper nonwelded units because of capillary barrier effects, and that the remaining water flowed down faults with a small amount flowing through the matrix of the lower welded, fractured rocks. It was believed that the matrix had to be saturated for fractures to flow. However, accumulating evidence indicated that infiltration rates were higher than initially estimated, such as infiltration modeling based on neutron borehole data, bomb-pulse isotopes deep in the mountain, perched water analyses and thermal analyses. Mechanisms supporting lateral diversion did not apply at these higher fluxes, and the flux calculated in the lower welded unit exceeded the conductivity of the matrix, implying vertical flow of water in the high permeability fractures of the potential repository host rock, and disequilibrium between matrix and fracture water potentials. The development of numerical modeling methods and parameter values evolved concurrently with the conceptual model in order to account for the observed field data, particularly fracture flow deep in the unsaturated zone. This paper presents the history of the evolution of conceptual models of hydrology and numerical models of unsaturated zone flow at Yucca Mountain, Nevada ( Flint, A.L., Flint, L.E., Kwicklis, E.M., Bodvarsson, G.S., Fabryka-Martin, J.M., 2001. Hydrology of Yucca Mountain. Reviews of Geophysics in press). This retrospective is the basis for recommendations for optimizing the efficiency with which a viable and robust conceptual model can be developed for a complex site.

Hydrogeology of the surficial aquifer in the vicinity of a former landfill, Naval Submarine Base Kings Bay, Camden County, Georgia

USGS Publications Warehouse

Leeth, David C.

1999-01-01

Neogene and Quaternary sediments constitute the surficial aquifer beneath the study area; in descending order from youngest to oldest these include-the Quaternary undifferentiated surficial sand and Satilla Formation; the Pliocene(?) Cypresshead Formation; and the middle Miocene Coosawhatchie Formation. Beneath the surficial aquifer, the upper Brunswick aquifer consists of part of the lower Miocene Marks Head Formation. The surficial aquifer is divided into three water-bearing zones on the basis of lithologic and geophysical properties of sediments, hydraulic-head differences between zones, and differences in ground-water chemistry. The shallowest zone-the water-table zone-consists of medium to fine sand and clayey sand and is present from land surface to a depth of about 77 feet. Below the water-table zone, the confined upper water-bearing zone consists of medium to very coarse sand and is present from a depth of about 110 to 132 feet. Beneath the upper water-bearing zone, the confined lower water-bearing zone consists of coarse sand and very fine gravel and is present from a depth of about 195 to 237 feet. Hydraulic separation is suggested by differences in water chemistry between the water-table zone and upper water-bearing zone. The sodium chloride type water in the water-table zone differs from the calcium bicarbonate type water in the upper water-bearing zone. Hydraulic separation also is indicated by hydraulic head differences of more than 6.5 feet between the water-table zone and the upper water-bearing zone. Continuous and synoptic water-level measurements in the water-table zone, from October 1995 to April 1997, indicate the presence of a water-table high beneath and adjacent to the former landfill-the surface of which varies about 5 feet with time because of recharge and discharge. Water-level data from clustered wells also suggest that restriction of vertical ground-water flow begins to occur at an altitude of about 5 to 10 feet below sea level (35 to 40 feet below land surface) in the water-table zone because of the increasing clay content of the Cypresshead Formation.

A practical tool for estimating subsurface LNAPL distributions and transmissivity using current and historical fluid levels in groundwater wells: Effects of entrapped and residual LNAPL.

PubMed

Lenhard, R J; Rayner, J L; Davis, G B

2017-10-01

A model is presented to account for elevation-dependent residual and entrapped LNAPL above and below, respectively, the water-saturated zone when predicting subsurface LNAPL specific volume (fluid volume per unit area) and transmissivity from current and historic fluid levels in wells. Physically-based free, residual, and entrapped LNAPL saturation distributions and LNAPL relative permeabilities are integrated over a vertical slice of the subsurface to yield the LNAPL specific volumes and transmissivity. The model accounts for effects of fluctuating water tables. Hypothetical predictions are given for different porous media (loamy sand and clay loam), fluid levels in wells, and historic water-table fluctuations. It is shown the elevation range from the LNAPL-water interface in a well to the upper elevation where the free LNAPL saturation approaches zero is the same for a given LNAPL thickness in a well regardless of porous media type. Further, the LNAPL transmissivity is largely dependent on current fluid levels in wells and not historic levels. Results from the model can aid developing successful LNAPL remediation strategies and improving the design and operation of remedial activities. Results of the model also can aid in accessing the LNAPL recovery technology endpoint, based on the predicted transmissivity. Copyright © 2017 Commonwealth Scientific and Industrial Research Organisation - Copyright 2017. Published by Elsevier B.V. All rights reserved.

Linking carbon and hydrologic fluxes in the critical zone: Observations from high-frequency monitoring of a weathered bedrock vadose zone

NASA Astrophysics Data System (ADS)

Tune, A. K.; Druhan, J. L.; Wang, J.; Cargill, S.; Murphy, C.; Rempe, D. M.

2017-12-01

A principle challenge in quantifying feedbacks between continental weathering and atmospheric CO2 is to improve understanding of how biogeochemical processes in the critical zone influence the distribution and mobility of organic and inorganic carbon. In particular, in landscapes characterized by thin soils and heterogeneous weathered and fractured bedrock, little data exist to inform and constrain predictive models for carbon dynamics. Here, we present the results of an intensive water and gas sampling campaign across an 18 m thick, variably saturated argillite weathering profile in the Eel River CZO. We monitor water content in situ and regularly collect samples of freely-draining water, tightly-held water, and gas through wet and dry seasons using a novel Vadose-zone Monitoring System (VMS) consisting of sensors and samplers distributed across a 20 m long inclined borehole. This novel approach facilitates the interception of gas and water during transport across the entire variably saturated weathering profile. The data demonstrate that seasonal changes in saturation control the vertical distribution and mobility of carbon in the fractured critical zone. Concentrations of gaseous CO2, O2, and dissolved organic and inorganic carbon fluctuate significantly and repeatably with seasonal additions of water infiltrating the weathered bedrock. A persistent vertical structure in the concentrations of dissolved phases and gas concentrations broadly corresponds to depths associated with unsaturated, seasonally saturated, and chronically saturated zones. Associated variations in the vertical structure of mineralogy and elemental composition, including solid phase organic carbon content, are observed in core obtained during drilling. Together, our observations indicate significant respiration of organic carbon at depths greater than the base of the soil, and thus motivate further investigation of the role of heterogeneous weathered, bedrock environments, which are needed to improve quantitative models for feedbacks between terrestrial and atmospheric CO2.

Convectively driven PCR thermal-cycling

DOEpatents

Benett, William J.; Richards, James B.; Milanovich, Fred P.

2003-07-01

A polymerase chain reaction system provides an upper temperature zone and a lower temperature zone in a fluid sample. Channels set up convection cells in the fluid sample and move the fluid sample repeatedly through the upper and lower temperature zone creating thermal cycling.

33 CFR 165.T08-0315 - Safety Zone; Upper Mississippi River, Mile 183.0 to 183.5.

Code of Federal Regulations, 2012 CFR

2012-07-01

... River, Mile 183.0 to 183.5. 165.T08-0315 Section 165.T08-0315 Navigation and Navigable Waters COAST... Guard District § 165.T08-0315 Safety Zone; Upper Mississippi River, Mile 183.0 to 183.5. (a) Location. The following area is a safety zone: All waters of the Upper Mississippi River, mile 183.0 to 183.5...

Evaluation of Nitrate Fluxes to Groundwater under Agriculture Land Uses across the Loess Plateau - A Catchment Scale Investigation

NASA Astrophysics Data System (ADS)

Turkeltaub, T.; Jia, X.; Binley, A. M.

2016-12-01

Nitrate management is required for fulfilling the objective of high agriculture productivity and concurrently reduced groundwater contamination to minimum. Yet, nitrate is considered as a non-point contaminant. Therefore, understanding the temporal and spatial processes controls of nitrate transport in the vadose zone are imperative for protection of groundwater. This study is conducted in the Loess Plateau which located in the north-central of mainland China and characterized with a semi-arid climate. Moreover, it accounts for about 6.6% of the Chinese territory and supports over 8.5% of the Chinese population. This area undergoes high pressure from human activities and requiring optimal management interventions. Integrated modelling frameworks, which include unsaturated and saturated processes, are able to simulate nitrate transport under various scenarios, and provide reasonable prediction for the decision-makers. We used data obtained from soil samples collected across a region of 41 × 104 km2 (243 samples, to 5 m depth) to derive unsaturated flow and transport properties. Particle size distributions, saturated hydraulic conductivity, water content at field capacity (0.33 atm) and saturated water content were also obtained for the shallower layers (0-40 cm). The van Genuchten - Mualem soil parameters describing the retention and the unsaturated hydraulic conductivity curves were estimated with the Rosetta code. The analysis of the soil samples indicated that the silt loam soil type is dominant. Hence, a scaling approach was chosen as an adequate method for estimation of representative retention and hydraulic conductivity curves. Water flow and nitrate leaching were simulated with mechanistic based 1-D model for each agriculture land use within the area. The simulated nitrate losses were compared with results of root zone model simulations. Subsequently, the calculated fluxes were input as upper boundary conditions in the Modflow model to examine the regional groundwater nitrate concentration levels. Ultimately, this integrated model framework is flexible and therefore allows testing various land-use scenarios.

Geohydrology of the central Mesilla Valley, Dona Ana County, New Mexico

USGS Publications Warehouse

Wilson, Clyde A.; White, Robert R.

1984-01-01

Five large-capacity irrigation wells, with depths ranging from 370 to 686 feet, were drilled by the Elephant Butte Irrigation District between 1973 and 1975, in the Mesilla Valley about 7 miles south of Las Cruces, New Mexico. These were the first deep wells in the area, and their installation provided an opportunity to conduct extensive aquifer tests under relatively undisturbed conditions. The deep irrigation wells are perforated in the Santa Fe Group of Miocene to Pleistocene Age. The Santa Fe Group is composed of interfingering and alternating beds of clay, silt, sand, and small gravel. In the area of these wells, the upper part of the saturated zone contains slightly saline water to a depth of about 100 to 175 feet below the water table, underlain by a freshwater zone extending to depths greater than 1,200 feet. As water is pumped from the freshwater zone, leakage occurs from above and below the perforated interval. At one of the irrigation district wells, slightly saline water moved downward because of a lack of confining layers in the aquifer. At three other wells, the surface casing was not set deep enough and slightly saline water moved into the top of the perforations , downward in the casing, and into the freshwater part of the aquifer. (USGS)

Effect of increased groundwater viscosity on the remedial performance of surfactant-enhanced air sparging.

PubMed

Choi, Jae-Kyeong; Kim, Heonki; Kwon, Hobin; Annable, Michael D

2018-03-01

The effect of groundwater viscosity control on the performance of surfactant-enhanced air sparging (SEAS) was investigated using 1- and 2-dimensional (1-D and 2-D) bench-scale physical models. The viscosity of groundwater was controlled by a thickener, sodium carboxymethylcellulose (SCMC), while an anionic surfactant, sodium dodecylbenzene sulfonate (SDBS), was used to control the surface tension of groundwater. When resident DI water was displaced with a SCMC solution (500 mg/L), a SDBS solution (200 mg/L), and a solution with both SCMC (500 mg/L) and SDBS (200 mg/L), the air saturation for sand-packed columns achieved by air sparging increased by 9.5%, 128%, and 154%, respectively, (compared to that of the DI water-saturated column). When the resident water contained SCMC, the minimum air pressure necessary for air sparging processes increased, which is considered to be responsible for the increased air saturation. The extent of the sparging influence zone achieved during the air sparging process using the 2-D model was also affected by viscosity control. Larger sparging influence zones (de-saturated zone due to air injection) were observed for the air sparging processes using the 2-D model initially saturated with high-viscosity solutions, than those without a thickener in the aqueous solution. The enhanced air saturations using SCMC for the 1-D air sparging experiment improved the degradative performance of gaseous oxidation agent (ozone) during air sparging, as measured by the disappearance of fluorescence (fluorescein sodium salt). Based on the experimental evidence generated in this study, the addition of a thickener in the aqueous solution prior to air sparging increased the degree of air saturation and the sparging influence zone, and enhanced the remedial potential of SEAS for contaminated aquifers. Copyright © 2018 Elsevier B.V. All rights reserved.

Nitrogen transport and transformations in a shallow aquifer receiving wastewater discharge: A mass balance approach

USGS Publications Warehouse

Desimone, Leslie A.; Howes, Brian L.

1998-01-01

Nitrogen transport and transformations were followed over the initial 3 years of development of a plume of wastewater-contaminated groundwater in Cape Cod, Massachusetts. Ammonification and nitrification in the unsaturated zone and ammonium sorption in the saturated zone were predominant, while loss of fixed nitrogen through denitrification was minor. The major effect of transport was the oxidation of discharged organic and inorganic forms to nitrate, which was the dominant nitrogen form in transit to receiving systems. Ammonification and nitrification in the unsaturated zone transformed 16–19% and 50–70%, respectively, of the total nitrogen mass discharged to the land surface during the study but did not attenuate the nitrogen loading. Nitrification in the unsaturated zone also contributed to pH decrease of 2 standard units and to an N2O increase (46–660 µg N/L in the plume). Other processes in the unsaturated zone had little net effect: Ammonium sorption removed <1% of the total discharged nitrogen mass; filtering of particulate organic nitrogen was less than 3%; ammonium and nitrate assimilation was less than 6%; and ammonia volatilization was less than 0.25%. In the saturated zone a central zone of anoxic groundwater (DO ≤ 0.05 mg/L) was first detected 17 months after effluent discharge to the aquifer began, which expanded at about the groundwater-flow velocity. Although nitrate was dominant at the water table, the low, carbon-limited rates of denitrification in the anoxic zone (3.0–9.6 (ng N/cm3)/d) reduced only about 2% of the recharged nitrogen mass to N2. In contrast, ammonium sorption in the saturated zone removed about 16% of the recharged nitrogen mass from the groundwater. Ammonium sorption was primarily limited to anoxic zone, where nitrification was prevented, and was best described by a Langmuir isotherm in which effluent ionic concentrations were simulated. The initial nitrogen load discharged from the groundwater system may depend largely on the growth and stability of the sorbed ammonium pool, which in turn depends on effluent-loading practices, subsurface microbial processes, and saturation of available exchange sites.

Implementation of Solute Transport in the Vadose Zone into the `HYDRUS Package for MODFLOW'

NASA Astrophysics Data System (ADS)

Simunek, J.; Beegum, S.; Szymkiewicz, A.; Sudheer, K. P.

2017-12-01

The 'HYDRUS package for MODFLOW' was developed by Seo et al. (2007) and Twarakavi et al. (2008) to simultaneously evaluate transient water flow in both unsaturated and saturated zones. The package, which is based on the HYDRUS-1D model (Šimůnek et al., 2016) simulating unsaturated water flow in the vadose zone, was incorporated into MODFLOW (Harbaugh et al., 2000) simulating saturated groundwater flow. The HYDRUS package in the coupled model can be used to represent the effects of various unsaturated zone processes, including infiltration, evaporation, root water uptake, capillary rise, and recharge in homogeneous or layered soil profiles. The coupled model is effective in addressing spatially-variable saturated-unsaturated hydrological processes at the regional scale, allowing for complex layering in the unsaturated zone, spatially and temporarily variable water fluxes at the soil surface and in the root zone, and with alternating recharge and discharge fluxes (Twarakavi et al., 2008). One of the major limitations of the coupled model was that it could not be used to simulate at the same time solute transport. However, solute transport is highly dependent on water table fluctuations due to temporal and spatial variations in groundwater recharge. This is an important concern when the coupled model is used for analyzing groundwater contamination due to transport through the unsaturated zone. The objective of this study is to integrate the solute transport model (the solute transport part of HYDRUS-1D for the unsaturated zone and MT3DMS (Zheng and Wang, 1999; Zheng, 2009) for the saturated zone) into an existing coupled water flow model. The unsaturated zone component of the coupled model can consider solute transport involving many biogeochemical processes and reactions, including first-order degradation, volatilization, linear or nonlinear sorption, one-site kinetic sorption, two-site sorption, and two-kinetic sites sorption (Šimůnek and van Genuchten, 2008). Due to complex interactions at the groundwater table, certain modifications of the pressure head (compared to the original coupling) and solute concentration profiles were incorporated into the HYDRUS package. The developed integrated model is verified using HYDRUS-2D and analyzed for its computational time requirements.

What electrical measurements can say about changes in fault systems.

PubMed Central

Madden, T R; Mackie, R L

1996-01-01

Earthquake zones in the upper crust are usually more conductive than the surrounding rocks, and electrical geophysical measurements can be used to map these zones. Magnetotelluric (MT) measurements across fault zones that are parallel to the coast and not too far away can also give some important information about the lower crustal zone. This is because the long-period electric currents coming from the ocean gradually leak into the mantle, but the lower crust is usually very resistive and very little leakage takes place. If a lower crustal zone is less resistive it will be a leakage zone, and this can be seen because the MT phase will change as the ocean currents leave the upper crust. The San Andreas Fault is parallel to the ocean boundary and close enough to have a lot of extra ocean currents crossing the zone. The Loma Prieta zone, after the earthquake, showed a lot of ocean electric current leakage, suggesting that the lower crust under the fault zone was much more conductive than normal. It is hard to believe that water, which is responsible for the conductivity, had time to get into the lower crustal zone, so it was probably always there, but not well connected. If this is true, then the poorly connected water would be at a pressure close to the rock pressure, and it may play a role in modifying the fluid pressure in the upper crust fault zone. We also have telluric measurements across the San Andreas Fault near Palmdale from 1979 to 1990, and beginning in 1985 we saw changes in the telluric signals on the fault zone and east of the fault zone compared with the signals west of the fault zone. These measurements were probably seeing a better connection of the lower crust fluids taking place, and this may result in a fluid flow from the lower crust to the upper crust. This could be a factor in changing the strength of the upper crust fault zone. PMID:11607664

77 FR 28255 - Safety Zone; Upper Mississippi River, Mile 183.0 to 183.5

Federal Register 2010, 2011, 2012, 2013, 2014

2012-05-14

...-AA00 Safety Zone; Upper Mississippi River, Mile 183.0 to 183.5 AGENCY: Coast Guard, DHS. ACTION... Upper Mississippi River, from mile 183.0 to mile 183.5, in the vicinity of the Merchants Bridge and... Merchants Bridge in the vicinity of mile 183.0 to 183.5 on the Upper Mississippi River. After initial...

78 FR 46258 - Safety Zone; Upper Mississippi River, Mile 662.8 to 663.9

Federal Register 2010, 2011, 2012, 2013, 2014

2013-07-31

...-AA00 Safety Zone; Upper Mississippi River, Mile 662.8 to 663.9 AGENCY: Coast Guard, DHS. ACTION... Upper Mississippi River, from mile 662.8 to 663.9, extending the entire width of the river. This safety... mile 662.8 to 663.9 on the Upper Mississippi River. Anticipated traffic on the river presents safety...

76 FR 36316 - Safety Zone; Upper Mississippi River, Mile 180.0 to 179.0

Federal Register 2010, 2011, 2012, 2013, 2014

2011-06-22

...-AA00 Safety Zone; Upper Mississippi River, Mile 180.0 to 179.0 AGENCY: Coast Guard, DHS. ACTION... Upper Mississippi River, from Mile 180.0 to 179.0, extending the entire width of the river. This safety... combat capabilities between Mile 180.0 and 179.0 on the Upper Mississippi River. This event presents...

Lack of differences in the regional variation of oxygen saturation in larger retinal vessels in diabetic maculopathy and proliferative diabetic retinopathy.

PubMed

Jørgensen, Christina Mørup; Bek, Toke

2017-06-01

Diabetic retinopathy is characterised by morphological lesions in the ocular fundus related to disturbances in retinal blood flow. The two vision threatening forms of retinopathy show specific patterns of distribution of retinal lesions with proliferative diabetic retinopathy (PDR) developing secondary to ischaemia and hypoxia in the retinal periphery and diabetic maculopathy (DM) developing secondary to hyperperfusion and increased vascular permeability in the macular area. These differences in the distribution of retinal lesions might be reflected in regional differences in oxygen saturation in the larger retinal vessels. Dual-wavelength retinal oximetry was performed in 30 normal persons, 30 patients with DM and 30 patients with PDR, and the oxygen saturation was measured in peripapillary vessels supplying the four retinal quadrants and in branches from the upper temporal arcades supplying, respectively, the macular area and the retinal periphery. The overall oxygen saturation was significantly higher in diabetic patients than in normal persons and the arteriovenous (AV) saturation difference significantly lower in the patients with DM. The regional variation in oxygen saturation was similar in the three studied groups with a decreasing saturation from the upper nasal through the lower nasal, lower temporal and the upper temporal peripapillary vessels, and with a significantly higher oxygen saturation in venules draining the macular area than in venules draining the retinal periphery. The regional differences in retinal lesions in vision threatening diabetic retinopathy are not reflected in regional differences in the oxygen saturation of larger retinal vessels. The development of vision threatening diabetic retinopathy depends on other factors, such as, for example, regional differences in the retinal microcirculation. Published by the BMJ Publishing Group Limited. For permission to use (where not already granted under a licence) please go to http://www.bmj.com/company/products-services/rights-and-licensing/.

Three Skin Zones in the Asian Upper Eyelid Pertaining to the Asian Blepharoplasty.

PubMed

Choi, Yeop; Kang, Hyun Gu; Nam, Yong Seok

2017-06-01

Natural looking double fold is an essential and aesthetically pleasing masterpiece in Asian blepharoplasty. This study aims to emphasize the 3 skin zone concept in the Asian upper blepharoplasty. The authors examined the anterior lamella of each skin zone microscopically by performing 31 double-eyelid surgeries and 11 infrabrow lifts. Characteristics of dermal components, subcutaneous tissue, and outer fascia of OOM (OFOOM) at each skin zone were documented. The authors evaluated the vertical scales of each skin zone in young and aged Asian patients who visited the first author's clinic for the primary or secondary upper blepharoplasty with ×3.5 magnifying surgical loupe. The thickness of OOM had no difference among zones 1, 2, and 3. The skin and subdermal tissue had varying characteristics according to its skin zone. At zone 1, it seemed that only thin skin was on the OOM. The anterior lamella of zone 2 seemed to consist of skin, white fascia (OFOOM) including a venous network, and OOM in a gross field. At zone 3, thick skin, thick subcutaneous fatty layer, and OOM were magnified. The OFOOM of zone 3 was not significantly identified due to a sticky adherence with OOM. At the point of vertical scales of skin zone, good eyelids have lower zone 3 ratio and higher zones 1 and 2 ratio with qualified topographic condition. The authors classified the Asian upper eyelid as with 3 skin zones. Based on its anatomical investigation, the authors can afford anthropometric data and supplemental theory for the creation of aesthetic folds.

The occurrence of the Complexiopollis-Atlantopollis zone (Palynomorphs) in the Eagle Ford Group (Upper Cretaceous) of Texas

USGS Publications Warehouse

Christopher, Raymond A.

1982-01-01

The Lower and lower Upper Cretaceous palynological zones defined in the Atlantic Coastal Plain Province and which occur in the eastern Gulf Coastal Plain Province are characterized by a paucity of marine invertebrate fossils. As a result, correlation of these zones with European and provincial stages, as well as with other microfossil and megafossil zones is tenuous. However, an examination of a complete section of the Eagle Ford Group and adjacent strata in Texas reveals that: 1) the upper part of the Woodbine Formation and the Tarrant Formation of the overlying Eagle Ford Group represent a biostratigraphic interval that is absent in the Atlantic and eastern Gulf Coastal Plain Provinces; 2) the Complexiopollis-Atlantopollis Zone (zone IV of some authors) occurs within the Britton Formation (Eagle Ford Group), and is equivalent to the upper part of the Rotalipora cushmani-greenhornensis Subzone (planktic foraminifers) and possibly to the Sciponoceras gracile Zone (ammonites); 3) the Arcadia Park Formation (Eagle Ford Group) contains a mixed assemblage of palynomorphs that includes guides to both the Complexiopollis-Atlantopollis and the overlying Complexiopollis exigua-Santalacites minor Zones, suggesting that biostratigraphic equivalents of the Arcadia Park Formation are not represented in the Atlantic and eastern Gulf Coastal Plain Provinces; and 4) in the basal part of the Austin Chalk of Texas, only one guide palynomorph to the Complexiopollis-Atlantopollis Zone was recognized, but guides to the Complexiopollis exigua-Santalacites minor Zone are present. The Tuscaloosa Group of the eastern Gulf Coastal Plain appears to be biostratigraphically equivalent to the Complexiopollis-Atlantopollis Zone, and therefore correlative with the middle to upper part of the Britton Formation of the Eagle Ford Group.

Seismicity, faulting, and structure of the Koyna-Warna seismic region, Western India from local earthquake tomography and hypocenter locations

USGS Publications Warehouse

Dixit, Madan M.; Kumar, Sanjay; Catchings, Rufus D.; Suman, K.; Sarkar, Dipankar; Sen, M.K.

2014-01-01

Although seismicity near Koyna Reservoir (India) has persisted for ~50 years and includes the largest induced earthquake (M 6.3) reported worldwide, the seismotectonic framework of the area is not well understood. We recorded ~1800 earthquakes from 6 January 2010 to 28 May 2010 and located a subset of 343 of the highest-quality earthquakes using the tomoDD code of Zhang and Thurber (2003) to better understand the framework. We also inverted first arrivals for 3-D Vp, Vs, and Vp/Vs and Poisson's ratio tomography models of the upper 12 km of the crust. Epicenters for the recorded earthquakes are located south of the Koyna River, including a high-density cluster that coincides with a shallow depth (<1.5 km) zone of relatively high Vp and low Vs (also high Vp/Vs and Poisson's ratios) near Warna Reservoir. This anomalous zone, which extends near vertically to at least 8 km depth and laterally northward at least 15 km, is likely a water-saturated zone of faults under high pore pressures. Because many of the earthquakes occur on the periphery of the fault zone, rather than near its center, the observed seismicity-velocity correlations are consistent with the concept that many of the earthquakes nucleate in fractures adjacent to the main fault zone due to high pore pressure. We interpret our velocity images as showing a series of northwest trending faults locally near the central part of Warna Reservoir and a major northward trending fault zone north of Warna Reservoir.

76 FR 77901 - Safety Zone; Upper Mississippi River, Mile 389.4 to 403.1

Federal Register 2010, 2011, 2012, 2013, 2014

2011-12-15

...-AA00 Safety Zone; Upper Mississippi River, Mile 389.4 to 403.1 AGENCY: Coast Guard, DHS. ACTION... Upper Mississippi River, from Mile 389.4 to 403.1, extending the entire width of the river located on... 389.4 to 403.1 on the Upper Mississippi River. Under 5 U.S.C. 553(d)(3), the Coast Guard finds that...

Effects of unsaturated zone on ground-water mounding

USGS Publications Warehouse

Sumner, D.M.; Rolston, D.E.; Marino, M.A.

1999-01-01

The design of infiltration basins used to dispose of treated wastewater or for aquifer recharge often requires estimation of ground-water mounding beneath the basin. However, the effect that the unsaturated zone has on water-table response to basin infiltration often has been overlooked in this estimation. A comparison was made between two methods used to estimate ground-water mounding-an analytical approach that is limited to the saturated zone and a numerical approach that incorporates both the saturated and the unsaturated zones. Results indicate that the error that is introduced by a method that ignores the effects of the unsaturated zone on ground-water mounding increases as the basin-loading period is shortened; as the depth to the water table increases, with increasing subsurface anisotropy; and with the inclusion of fine-textured strata. Additionally, such a method cannot accommodate the dynamic nature of basin infiltration, the finite transmission time of the infiltration front to the water table, or the interception of the basin floor by the capillary fringe.The design of infiltration basins used to dispose of treated wastewater or for aquifer recharge often requires estimation of ground-water mounding beneath the basin. However, the effect that the unsaturated zone has on water-table response to basin infiltration often has been overlooked in this estimation. A comparison was made between two methods used to estimate ground-water mounding - an analytical approach that is limited to the saturated zone and a numerical approach that incorporates both the saturated and the unsaturated zones. Results indicate that the error that is introduced by a method that ignores the effects of the unsaturated zone on ground-water mounding increases as the basin-loading period is shortened; as the depth to the water table increases, with increasing subsurface anisotropy; and with the inclusion of fine-textured strata. Additionally, such a method cannot accommodate the dynamic nature of basin infiltration, the finite transmission time of the infiltration front to the water, or the interception of the basin floor by the capillary fringe.

A progress report on results of test drilling and ground-water investigations of the Snake Plain aquifer, southeastern Idaho: Part 1: Mud Lake Region, 1969-70 and Part 2: Observation Wells South of Arco and West of Aberdeen

USGS Publications Warehouse

Crosthwaite, E.G.

1973-01-01

The results of drilling test holes to depths of approximately 1,000 feet in the Mud Lake region show that a large part of the region is underlain by both sedimentary deposits and basalt flows. At some locations, predominantly sedimentary deposits were penetrated; at others, basalt flows predominated. The so-called Mud Lake-Market Lake barrier denotes a change in geology. From the vicinity of the barrier area, as described by Stearns, Crandall, and Steward (1938, p. 111), up the water-table gradient for at least a few tens of miles, the saturated geologic section consists predominantly of beds of sediments that are intercalated with numerous basalt flows. Downgradient from the barrier, sedimentary deposits are not common and practically all the water-bearing formations are basalt, at least to the depths explored so far. Thus, the barrier is a transition zone from a sedimentary-basaltic sequence to a basaltic sequence. The sedimentary-basaltic sequence forms a complex hydrologic system in which water occurs under water-table conditions in the upper few tens of feet of saturated material and under artesian conditions in the deeper material in the southwest part of the region. The well data indicate that southwest of the barrier, artesian pressures are not significant. Southwest of the barrier, few sedimentary deposits occur in the basalt section and, as described by Mundorff, Crosthwaite, and Kilburn (1964). ground water occurs in a manner typical of the Snake Plain aquifer. In several wells, artesian pressures are higher in the deeper formations than in the shallower ones, but the reverse was found in a few wells. The available data are not adequate to describe the water-bearing characteristics of the artesian aquifer nor the effects that pumping in one zone would have on adjacent zones. The water-table aquifer yields large quantities of water to irrigation wells.

Spatial distribution of microbial biomass, activity, community structure, and the biodegradation of linear alkylbenzene sulfonate (LAS) and linear alcohol ethoxylate (LAE) in the subsurface.

PubMed

Federle, T W; Ventullo, R M; White, D C

1990-12-01

The vertical distribution of microbial biomass, activity, community structure and the mineralization of xenobiotic chemicals was examined in two soil profiles in northern Wisconsin. One profile was impacted by infiltrating wastewater from a laundromat, while the other served as a control. An unconfined aquifer was present 14 meters below the surface at both sites. Biomass and community structure were determined by acridine orange direct counts and measuring concentrations of phospholipid-derived fatty acids (PLFA). Microbial activity was estimated by measuring fluorescein diacetate (FDA) hydrolysis, thymidine incorporation into DNA, and mixed amino acid (MAA) mineralization. Mineralization kinetics of linear alkylbenzene sulfonate (LAS) and linear alcohol ethoxylate (LAE) were determined at each depth. Except for MAA mineralization rates, measures of microbial biomass and activity exhibited similar patterns with depth. PLFA concentration and rates of FDA hydrolysis and thymidine incorporation decreased 10-100 fold below 3 m and then exhibited little variation with depth. Fungal fatty acid markers were found at all depths and represented from 1 to 15% of the total PLFAs. The relative proportion of tuberculostearic acid (TBS), an actinomycete marker, declined with depth and was not detected in the saturated zone. The profile impacted by wastewater exhibited higher levels of PLFA but a lower proportion of TBS than the control profile. This profile also exhibited faster rates of FDA hydrolysis and amino acid mineralization at most depths. LAS was mineralized in the upper 2 m of the vadose zone and in the saturated zone of both profiles. Little or no LAS biodegradation occurred at depths between 2 and 14 m. LAE was mineralized at all depths in both profiles, and the mineralization rate exhibited a similar pattern with depth as biomass and activity measurements. In general, biomass and biodegradative activities were much lower in groundwater than in soil samples obtained from the same depth.

A revision of the Norian Conchostracan Zonation in North America and its implications for Late Triassic North American tectonic history

USGS Publications Warehouse

Weems, Robert E.; Lucas, Spencer G.

2015-01-01

Collections of Upper Triassic (Norian) conchostracans from the upper Cumnock and lower Sanford formations (North Carolina), Bull Run Formation (Virginia), Gettysburg Formation (Pennsylvania), Passaic Formation (New Jersey), Blomidon Formation (Nova Scotia), and Redonda Formation (New Mexico) have significantly expanded our knowledge of the Norian conchostracan faunas in these units. These collections show that the temporal and spatial distribution of Norian conchostracans in North America is more complex and more environmentally controlled than previously thought. The new collections require a revision and simplification of the published conchostracan zonation for this interval. The revised zonation, based almost entirely on evolution within the lineage of the conchostracan genus Shipingia, consists of five zones: the Shipingia weemsi-Euestheria buravasi zone (Lacian), the Shipingia mcdonaldi zone (lower Alaunian), the Shipingia hebaozhaiensis zone (upper Alaunian), the Shipingia olseni zone (lower and middle Sevatian), and the Shipingia gerbachmanni zone (upper Sevatian). A new species of Norian conchostracan, Wannerestheria kozuri, is described from the Groveton Member of the Bull Run Formation (Virginia). Two new members (Plum Run and Fairfield members) are named in the Gettysburg Formation (Gettysburg Basin, Maryland and Pennsylvania). The distribution of upper Carnian and Norian strata in the Fundy, Newark, Gettysburg, and Culpeper basins indicates that there was a significant, previously undetected tectonic reorganization within these basins that occurred around the Carnian-Norian boundary. The presence of an upper Norian-lower Rhaetian unconformity within the Newark Supergroup is reaffirmed. A re-evaluation of the conchostracan record from the Redonda Formation of the Chinle Group in New Mexico indicates that the four conchostracan-bearing lacustrine beds in this unit are part of only a single, consistently recognizable conchostracan zone, which we here designate as the Shipingia gerbachmanni zone.

Assessing controls on perched saturated zones beneath the Idaho Nuclear Technology and Engineering Center, Idaho

USGS Publications Warehouse

Mirus, Benjamin B.; Perkins, Kim S.; Nimmo, John R.

2011-01-01

Waste byproducts associated with operations at the Idaho Nuclear Technology and Engineering Center (INTEC) have the potential to contaminate the eastern Snake River Plain (ESRP) aquifer. Recharge to the ESRP aquifer is controlled largely by the alternating stratigraphy of fractured volcanic rocks and sedimentary interbeds within the overlying vadose zone and by the availability of water at the surface. Beneath the INTEC facilities, localized zones of saturation perched on the sedimentary interbeds are of particular concern because they may facilitate accelerated transport of contaminants. The sources and timing of natural and anthropogenic recharge to the perched zones are poorly understood. Simple approaches for quantitative characterization of this complex, variably saturated flow system are needed to assess potential scenarios for contaminant transport under alternative remediation strategies. During 2009-2011, the U.S. Geological Survey (USGS), in cooperation with the U.S. Department of Energy, employed data analysis and numerical simulations with a recently developed model of preferential flow to evaluate the sources and quantity of recharge to the perched zones. Piezometer, tensiometer, temperature, precipitation, and stream-discharge data were analyzed, with particular focus on the possibility of contributions to the perched zones from snowmelt and flow in the neighboring Big Lost River (BLR). Analysis of the timing and magnitude of subsurface dynamics indicate that streamflow provides local recharge to the shallow, intermediate, and deep perched saturated zones within 150 m of the BLR; at greater distances from the BLR the influence of streamflow on recharge is unclear. Perched water-level dynamics in most wells analyzed are consistent with findings from previous geochemical analyses, which suggest that a combination of annual snowmelt and anthropogenic sources (for example, leaky pipes and drainage ditches) contribute to recharge of shallow and intermediate perched zones throughout much of INTEC. The source-responsive fluxes model was parameterized to simulate recharge via preferential flow associated with intermittent episodes of streamflow in the BLR. The simulations correspond reasonably well to the observed hydrologic response within the shallow perched zone. Good model performance indicates that source-responsive flow through a limited number of connected fractures contributes substantially to the perched-zone dynamics. The agreement between simulated and observed perched-zone dynamics suggest that the source-responsive fluxes model can provide a valuable tool for quantifying rapid preferential flow processes that may result from different land management scenarios.

Meteoric calcite cementation: diagenetic response to relative fall in sea-level and effect on porosity and permeability, Las Negras area, southeastern Spain

NASA Astrophysics Data System (ADS)

Li, Zhaoqi; Goldstein, Robert H.; Franseen, Evan K.

2017-03-01

A dolomitized Upper Miocene carbonate system in southeast Spain contains extensive upper and lower zones of calcite cementation that cut across the stratigraphy. Cement textures including isopachous and circumgranular, which are consistent with phreatic-zone cementation. Cements in the upper cemented zone are non-luminescent, whereas those in the lower cemented zone exhibit multiple bands of luminescent and non-luminescent cements. In the upper cemented zone, isotopic data show two meteoric calcite lines (MCL) with mean δ18O at - 5.1‰ and - 5.8‰ VPDB, whereas no clear MCL is defined in the lower cemented zone where mean δ18O for calcite cement is at - 6.7‰ VPDB. δ13C values in both cement zones are predominantly negative, ranging from - 10 to + 2‰ VPDB, suggestive of carbon from soil gas or decayed organics. Measurements of Tm ice in primary fluid inclusions yield a mode of 0.0 °C in both zones, indicating calcite cementation from fresh water. These two zones define the positions of two different paleo-water tables that formed during a relative sea-level fall and erosional downcutting during the Plio-Pleistocene. The upper cemented zone pre-dated the lower cemented zone on the basis of known relative sea-level history. Meteoric calcite cementation reduced porosity and permeability, but measured values are inconsistent with simple filling of open pore space. Each texture, boundstone, grainstone, packstone, wackestone, produces a different relationship between percent calcite cement and porosity/permeability. Distribution of cements may be predictable on the basis of known sea-level history, and the effect of the cementation can be incorporated into subsurface geomodels by defining surfaces of rock boundaries that separate cemented zones from uncemented zones, and applying texture-specific relationships among cementation, porosity and permeability.

Study on 3-D velocity structure of crust and upper mantle in Sichuan-yunnan region, China

USGS Publications Warehouse

Wang, C.; Mooney, W.D.; Wang, X.; Wu, J.; Lou, H.; Wang, F.

2002-01-01

Based on the first arrival P and S data of 4 625 regional earthquakes recorded at 174 stations dispersed in the Yunnan and Sichuan Provinces, the 3-D velocity structure of crust and upper mantle in the region is determined, incorporating with previous deep geophysical data. In the upper crust, a positive anomaly velocity zone exists in the Sichuan basin, whereas a negative anomaly velocity zone exists in the western Sichuan plateau. The boundary between the positive and negative anomaly zones is the Longmenshan fault zone. The images of lower crust and upper mantle in the Longmenshan fault, Xianshuihe fault, Honghe fault and others appear the characteristic of tectonic boundary, indicating that the faults litely penetrate the Moho discontinuity. The negative velocity anomalies at the depth of 50 km in the Tengchong volcanic area and the Panxi tectonic zone appear to be associated with the temperature and composition variations in the upper mantle. The overall features of the crustal and the upper mantle structures in the Sichuan-Yunnan region are the lower average velocity in both crust and uppermost mantle, the large crustal thickness variations, and the existence of high conductivity layer in the crust or/and upper mantle, and higher geothermal value. All these features are closely related to the collision between the Indian and the Asian plates. The crustal velocity in the Sichuan-Yunnan rhombic block generally shows normal.value or positive anomaly, while the negative anomaly exists in the area along the large strike-slip faults as the block boundary. It is conducive to the crustal block side-pressing out along the faults. In the major seismic zones, the seismicity is relative to the negative anomaly velocity. Most strong earthquakes occurred in the upper-mid crust with positive anomaly or normal velocity, where the negative anomaly zone generally exists below.

Controls on deep drainage beneath the root soil zone in snowmelt-dominated environments

NASA Astrophysics Data System (ADS)

Hammond, J. C.; Harpold, A. A.; Kampf, S. K.

2017-12-01

Snowmelt is the dominant source of streamflow generation and groundwater recharge in many high elevation and high latitude locations, yet we still lack a detailed understanding of how snowmelt is partitioned between the soil, deep drainage, and streamflow under a variety of soil, climate, and snow conditions. Here we use Hydrus 1-D simulations with historical inputs from five SNOTEL snow monitoring sites in each of three regions, Cascades, Sierra, and Southern Rockies, to investigate how inter-annual variability on water input rate and duration affects soil saturation and deep drainage. Each input scenario was run with three different soil profiles of varying hydraulic conductivity, soil texture, and bulk density. We also created artificial snowmelt scenarios to test how snowmelt intermittence affects deep drainage. Results indicate that precipitation is the strongest predictor (R2 = 0.83) of deep drainage below the root zone, with weaker relationships observed between deep drainage and snow persistence, peak snow water equivalent, and melt rate. The ratio of deep drainage to precipitation shows a stronger positive relationship to melt rate suggesting that a greater fraction of input becomes deep drainage at higher melt rates. For a given amount of precipitation, rapid, concentrated snowmelt may create greater deep drainage below the root zone than slower, intermittent melt. Deep drainage requires saturation below the root zone, so saturated hydraulic conductivity serves as a primary control on deep drainage magnitude. Deep drainage response to climate is mostly independent of soil texture because of its reliance on saturated conditions. Mean water year saturations of deep soil layers can predict deep drainage and may be a useful way to compare sites in soils with soil hydraulic porosities. The unit depth of surface runoff often is often greater than deep drainage at daily and annual timescales, as snowmelt exceeds infiltration capacity in near-surface soil layers. These results suggest that processes affecting the duration of saturation below the root zone could compromise deep recharge, including changes in snowmelt rate and duration as well as the depth and rate of ET losses from the soil profile.

Ground-water geology of the Gonaives Plain, Haiti

USGS Publications Warehouse

Taylor, George C.; Lemoine, Rémy C.

1950-01-01

The Gonaives Plain lies in northern Haiti at the head of the Gulf of Gonaives. Ground water in the plain is used widely for domestic and stock purposes but only to limited extent for irrigation. The future agricultural development of the plain will depend in large measure on the proper utilization of available ground-water supplies for irrigation. The rocks in the region of the Gonaives Plain belong to the upper (?) Cretaceous series of the Cretaceous system, the Nocene and Oligovene series of the Tertiary system, and the Pleistocene and Recent series of the Quarternary system. The structural depression occupied by the Gonaives Plain was formed in post-Miocene time by the dislocation of Oligocene and older rocks along normal faults and by the tilting of the adjacent crustal blocks. The lower parts of the depression contain a Pleistocene and Recent alluvial fill deposited by streams tributary to the plain. The upper (?) Cretaceous rocks include aniesite and basalt lava flows locally intercalated with some beds of tuff and agglomerate. These rocks are generally dense and impervious but locally small springs rise from fractures and bedding planes or from weathered zones. The Nocene rocks are hard, thin-bedded, cherty limestones with some beds of massive chalky limestone. Considerable ground water circulates through joints, bedding planes, and solution passages in these rocks giving rise to important springs such as Sources Madame Charles. These springs discharge at the rate of about 110 liters per second. The Oligocene rocks include limestone, shely limestone, limy sandstone, marl, and shale. The limestone beds contain solution passages and other openings and these may afford capacity for the circulation of ground water. However, no wells or springs in Oligocene rocks were observed during the present study. The alluvial fill of the plain is composed of interbedded lenses of clay, silt, sand, and gravel. These deposits contain a zone of saturation whose upper limit is marked by a water table. The depth to the water table beneath the alluvial lowland of the plain ranges from less than one meter to about 20 meters. In most places in the plain the depth to water is less that 15 meters. Where present in the zone of saturation the coarse, well-sorted sand and gravel beds of the alluvium will probably yield moderate to large supplies of water to wells and infiltration galleries. The individual yields of existing wells range from a few liters to about 60 liters per second. The most favorable part of the plain for ground-water prospecting and development lies 5 to 10 kilometers northeast of Gonaives. In this area yields of 10 to 50 liters per second could be obtained from the alluvium in simple wells drilled to depths of about 35 to 45 meters. Additional information on the yield and physical character of aquifers in the alluvium would be provided by test wells drilled to depths of 40 to 60 meters.

Spectral Decomposition and Other Seismic Attributes for Gas Hydrate Prospecting

DOE Office of Scientific and Technical Information (OSTI.GOV)

McConnell, Dan

Studying the sediments at the base of gas hydrate stability is ideal for determining the seismic response to gas hydrate saturation. First, assuming gas migration to the shallow section, this area is more likely to have concentrated gas hydrate because it encompasses the zone in which upward moving buoyant gas transitions to form immobile gas hydrate deposits. Second, this zone is interesting because these areas have the potential to show a hydrate filled zone and a gas filled zone within the same sediments. Third, the fundamental measurement within seismic data is impedance contrasts between velocity*density layers. High saturation gas hydratesmore » and free gas inhabit opposite ends of these measurements making the study of this zone ideal for investigating the seismic characteristics of gas hydrate and, hence, the investigation of other seismic attributes that may indicate gas hydrate fill.« less

Radial Anisotropy in the Mantle Transition Zone and Its Implications

NASA Astrophysics Data System (ADS)

Chang, S. J.; Ferreira, A. M.

2016-12-01

Seismic anisotropy is a useful tool to investigate mantle flow, mantle convection, and the presence of melts in mantle, since it provides information on the direction of mantle flow or the orientation of melts by combining it with laboratory results in mineral physics. Although the uppermost and lowermost mantle with strong anisotropy have been well studied, anisotropic properties of the mantle transition zone is still enigmatic. We use a recent global radially anisotropic model, SGLOBE-rani, to examine the patterns of radial anisotropy in the mantle transition zone. Strong faster SV velocity anomalies are found in the upper transition zone beneath subduction zones in the western Pacific, which decrease with depth, thereby nearly isotropic in the lower transition zone. This may imply that the origin for the anisotropy is the lattice-preferred orientation of wadsleyite, the dominant anisotropic mineral in the upper transition zone. The water content in the upper transition zone may be inferred from radial anisotropy because of the report that anisotropic intensity depends on the water content in wadsleyite.

77 FR 40518 - Swim Events in the Captain of the Port New York Zone; Hudson River, East River, Upper New York...

Federal Register 2010, 2011, 2012, 2013, 2014

2012-07-10

... 1625-AA00 Swim Events in the Captain of the Port New York Zone; Hudson River, East River, Upper New York Bay, Lower New York Bay; New York, NY ACTION: Final rule. SUMMARY: The Coast Guard is establishing seven temporary safety zones for swim events within the Captain of the Port (COTP) New York Zone. These...

Vitrification of waste with conitnuous filling and sequential melting

DOEpatents

Powell, James R.; Reich, Morris

2001-09-04

A method of filling a canister with vitrified waste starting with a waste, such as high-level radioactive waste, that is cooler than its melting point. Waste is added incrementally to a canister forming a column of waste capable of being separated into an upper zone and a lower zone. The minimum height of the column is defined such that the waste in the lower zone can be dried and melted while maintaining the waste in the upper zone below its melting point. The maximum height of the column is such that the upper zone remains porous enough to permit evolved gases from the lower zone to flow through the upper zone and out of the canister. Heat is applied to the waste in the lower zone to first dry then to raise and maintain its temperature to a target temperature above the melting point of the waste. Then the heat is applied to a new lower zone above the melted waste and the process of adding, drying and melting the waste continues upward in the canister until the entire canister is filled and the entire contents are melted and maintained at the target temperature for the desired period. Cooling of the melted waste takes place incrementally from the bottom of the canister to the top, or across the entire canister surface area, forming a vitrified product.

Saturated-unsaturated flow to a partially penetrating well with storage in a compressible aquifer

NASA Astrophysics Data System (ADS)

Mishra, P. K.; Neuman, S. P.

2010-12-01

Mishra and Neuman [2010] developed an analytical solution for flow to a partially penetrating well of zero radius in a compressible unconfined aquifer that allows inferring its saturated and unsaturated hydraulic properties from responses recorded in the saturated and/or the unsaturated zone. We extend their solution to the case of a finite diameter pumping well with storage. Both solutions account for horizontal as well as vertical flows throughout the system. We investigate the effects of storage in the pumping well and delayed piezometer response on drawdowns in the saturated and unsaturated zones as functions of position and time; validate our solution against numerical simulations of drawdown in a synthetic aquifer having unsaturated properties described by the van Genuchten - Mualem constitutive model; and use our solution to analyze drawdown data from a pumping test conducted at the Borden site in Ontario, Canada.

System and method for producing metallic iron

DOEpatents

Bleifuss, Rodney L; Englund, David J; Iwasaki, Iwao; Fosnacht, Donald R; Brandon, Mark M; True, Bradford G

2013-09-17

A hearth furnace for producing metallic iron material has a furnace housing having a drying/preheat zone, a conversion zone, a fusion zone, and optionally a cooling zone, the conversion zone is between the drying/preheat zone and the fusion zone. A moving hearth is positioned within the furnace housing. A hood or separation barrier within at least a portion of the conversion zone, fusion zone or both separates the fusion zone into an upper region and a lower region with the lower region adjacent the hearth and the upper region adjacent the lower region and spaced from the hearth. An injector introduces a gaseous reductant into the lower region adjacent the hearth. A combustion region may be formed above the hood or separation barrier.

Oyster-bioimmured ammonites from the Upper Albian of Annopol, Poland: stratigraphic and palaeobiogeographic implications

NASA Astrophysics Data System (ADS)

Machalski, Marcin; Kennedy, William J.

2013-12-01

Machalski, M. and Kennedy, W.J. 2013. Oyster-bioimmured ammonites from the Upper Albian of Annopol, Poland: stratigraphic and palaeobiogeographic implications. Acta Geologica Polonica, 63 (4), 545-554. Warszawa. Ammonites Mortoniceras (Subschloenbachia) sp. are preserved as attachment scars on the oyster shells from the topmost portion of the Albian succession at Annopol, Poland. These oyster-bioimmured ammonites show a closest affinity to the representatives of Mortoniceras (Subschloenbachia) characteristic of the upper Upper Albian Mortoniceras perinflatum Zone. No ammonites indicative of the uppermost Albian-lowermost Cenomanian Praeschloenbachia briacensis Zone are recorded. Thus, the hiatus at the Albian-Cenomanian boundary at Annopol embraces the latter zone. The presence (and dominance) of Mortoniceras in the upper Upper Albian ammonite assemblage of Annopol suggests that the representatives of this Tethyan genus could migrate into the epicratonic areas of Poland directly from the Tethyan Realm, via the Lwow (Lviv) region.

47 CFR 27.303 - Upper 700 MHz commercial and public safety coordination zone.

Code of Federal Regulations, 2011 CFR

2011-10-01

... safety coordinator. (1) The description must include, at a minimum; (i) The frequency or frequencies on... 47 Telecommunication 2 2011-10-01 2011-10-01 false Upper 700 MHz commercial and public safety... Rules for WCS § 27.303 Upper 700 MHz commercial and public safety coordination zone. (a) General. CMRS...

Driver speed limit compliance in school zones : assessing the impact of sign saturation.

DOT National Transportation Integrated Search

2013-10-01

School zones are often viewed as an effective way to reduce driving speeds and thereby improve : safety near our nations schools. The effect of school zones on reducing driving speeds, however, is : minimal at best. Studies have shown that over 90...

Upper Albian and Cenomanian (Cretaceous) ammonites from the Debarsu Formation (Yazd Block, Central Iran)

NASA Astrophysics Data System (ADS)

Wilmsen, Markus; Storm, Marisa; Fürsich, Franz Theodor; Majidifard, Mahmoud Reza

2013-12-01

Wilmsen, M., Storm, M., Fürsich, F.T. and Majidifard, M.R. 2013. Upper Albian and Cenomanian (Cretaceous) ammonites from the Debarsu Formation (Yazd Block, Central Iran). Acta Geologica Polonica, 63 (4), 489-513. Warszawa. New ammonite faunas consisting of 13 taxa provide the first reliable biostratigraphic dating of the Debarsu Formation of the Yazd Block, west-central Iran, indicating several levels in the Upper Albian and Lower Cenomanian, while a foraminiferal assemblage places the top of the Formation in the Middle Turonian. Among the identified ammonite taxa, Acompsoceras renevieri (Sharpe, 1857) is recorded from Iran for the first time. The upper part of the lower Upper Albian is proved by the occurrences of mortoniceratines of the Mortoniceras (M.) inflatum Zone in the lowermost part of the Debarsu Formation. For the upper Upper Albian (traditional Stoliczkaia dispar Zone), the M. (Subschloenbachia ) rostratum and M. (S.) perinflatum zones are proved by their index taxa. However, there is no evidence of the terminal Arrhaphoceras (Praeschloenbachia) briacensis Zone. The upper part of the lower Lower Cenomanian Mantelliceras mantelli Zone (M. saxbii Subzone) is proved by M. saxbii and M. cf. mantelli. Below, there is an ammonite- barren interval of ca. 100 m in thickness between M. (S.) perinflatum zonal strata and the M. saxbii Subzone. The upper Lower Cenomanian is documented by the presence of typically M. dixoni zonal ammonites such as Acompsoceras renevieri. Upper Cenomanian and Turonian ammonites have not been found in the upper part of the Debarsu Formation, but micro-biostratigraphic evidence (planktonic foraminifers) from the uppermost part of the formation indicate that the formation ranges into the Turonian. For the development of the major tectonic unconformity at the base of the overlying Haftoman Formation (which yielded Lower Coniacian inoceramids near its base), only 2-3 myr remain, stressing the geodynamic activity of Central Iran during mid-Cretaceous times.

Evolution of the conceptual model of unsaturated zone hydrology at Yucca Mountain, Nevada

USGS Publications Warehouse

Flint, Alan L.; Flint, Lorraine E.; Bodvarsson, Gudmundur S.; Kwicklis, Edward M.; Fabryka-Martin, June

2001-01-01

Yucca Mountain is an arid site proposed for consideration as the United States’ first underground high-level radioactive waste repository. Low rainfall (approximately 170 mm/yr) and a thick unsaturated zone (500–1000 m) are important physical attributes of the site because the quantity of water likely to reach the waste and the paths and rates of movement of the water to the saturated zone under future climates would be major factors in controlling the concentrations and times of arrival of radionuclides at the surrounding accessible environment. The framework for understanding the hydrologic processes that occur at this site and that control how quickly water will penetrate through the unsaturated zone to the water table has evolved during the past 15 yr. Early conceptual models assumed that very small volumes of water infiltrated into the bedrock (0.5–4.5 mm/yr, or 2–3 percent of rainfall), that much of the infiltrated water flowed laterally within the upper nonwelded units because of capillary barrier effects, and that the remaining water flowed down faults with a small amount flowing through the matrix of the lower welded, fractured rocks. It was believed that the matrix had to be saturated for fractures to flow. However, accumulating evidence indicated that infiltration rates were higher than initially estimated, such as infiltration modeling based on neutron borehole data, bomb-pulse isotopes deep in the mountain, perched water analyses and thermal analyses. Mechanisms supporting lateral diversion did not apply at these higher fluxes, and the flux calculated in the lower welded unit exceeded the conductivity of the matrix, implying vertical flow of water in the high permeability fractures of the potential repository host rock, and disequilibrium between matrix and fracture water potentials. The development of numerical modeling methods and parameter values evolved concurrently with the conceptual model in order to account for the observed field data, particularly fracture flow deep in the unsaturated zone. This paper presents the history of the evolution of conceptual models of hydrology and numerical models of unsaturated zone flow at Yucca Mountain, Nevada (Flint, A.L., Flint, L.E., Kwicklis, E.M., Bodvarsson, G.S., Fabryka-Martin, J.M., 2001. Hydrology of Yucca Mountain. Reviews of Geophysics in press). This retrospective is the basis for recommendations for optimizing the efficiency with which a viable and robust conceptual model can be developed for a complex site.

Electric conductivity for laboratory and field monitoring of induced partial saturation (IPS) in sands

NASA Astrophysics Data System (ADS)

Kazemiroodsari, Hadi

Liquefaction is loss of shear strength in fully saturated loose sands caused by build-up of excess pore water pressure, during moderate to large earthquakes, leading to catastrophic failures of structures. Currently used liquefaction mitigation measures are often costly and cannot be applied at sites with existing structures. An innovative, practical, and cost effective liquefaction mitigation technique titled "Induced Partial Saturation" (IPS) was developed by researchers at Northeastern University. The IPS technique is based on injection of sodium percarbonate solution into fully saturated liquefaction susceptible sand. Sodium percarbonate dissolves in water and breaks down into sodium and carbonate ions and hydrogen peroxide which generates oxygen gas bubbles. Oxygen gas bubbles become trapped in sand pores and therefore decrease the degree of saturation of the sand, increase the compressibility of the soil, thus reduce its potential for liquefaction. The implementation of IPS required the development and validation of a monitoring and evaluation technique that would help ensure that the sands are indeed partially saturated. This dissertation focuses on this aspect of the IPS research. The monitoring system developed was based on using electric conductivity fundamentals and probes to detect the transport of chemical solution, calculate degree of saturation of sand, and determine the final zone of partial saturation created by IPS. To understand the fundamentals of electric conductivity, laboratory bench-top tests were conducted using electric conductivity probes and small specimens of Ottawa sand. Bench-top tests were used to study rate of generation of gas bubbles due to reaction of sodium percarbonate solution in sand, and to confirm a theory based on which degree of saturation were calculated. In addition to bench-top tests, electric conductivity probes were used in a relatively large sand specimen prepared in a specially manufactured glass tank. IPS was implemented in the prepared specimen to validate the numerical simulation model and explore the use of conductivity probes to detect the transport of chemical solution, estimate degree of saturation achieved due to injection of chemical solution, and evaluate final zone of partial saturation. The conductivity probe and the simulation results agreed well. To study the effect of IPS on liquefaction response of the sand specimen, IPS was implemented in a large (2-story high) sand specimen prepared in the laminar box of NEES Buffalo and then the specimen was subjected to harmonic shaking. Electric conductivity probes were used in the specimen treatment by controlling the duration and spacing of injection of the chemical solution, in monitoring the transport of chemical solution, in the estimation of zone of partial saturation achieved, and in the estimation of degree of saturation achieved due to implementation of IPS. The conductivity probes indicated partial saturation of the specimen. The shaking tests results confirmed the partial saturation state of the sand specimen. In addition, to the laboratory works, electric conductivity probes were used in field implementation of IPS in a pilot test at the Wildlife Liquefaction Array (WLA) of NEES UCSB site. The conductivity probes in the field test helped decide the optimum injection pressure, the injection tube spacing, and the degree of saturation that could be achieved in the field. The various laboratory and field tests confirmed that electric conductivity and the probes devised and used can be invaluable in the implementation of IPS, by providing information regarding transport of the chemical solution, the spacing of injection tubes, duration of injection, and the zone and degree of partial saturation caused by IPS.

Spatiotemporal changes of seismic attenuation caused by injected CO2 at the Frio-II pilot site, Dayton, TX, USA

NASA Astrophysics Data System (ADS)

Zhu, Tieyuan; Ajo-Franklin, Jonathan B.; Daley, Thomas M.

2017-09-01

A continuous active source seismic monitoring data set was collected with crosswell geometry during CO2 injection at the Frio-II brine pilot, near Liberty, TX. Previous studies have shown that spatiotemporal changes in the P wave first arrival time reveal the movement of the injected CO2 plume in the storage zone. To further constrain the CO2 saturation, particularly at higher saturation levels, we investigate spatial-temporal changes in the seismic attenuation of the first arrivals. The attenuation changes over the injection period are estimated by the amount of the centroid frequency shift computed by local time-frequency analysis. We observe that (1) at receivers above the injection zone seismic attenuation does not change in a physical trend; (2) at receivers in the injection zone attenuation sharply increases following injection and peaks at specific points varying with distributed receivers, which is consistent with observations from time delays of first arrivals; then, (3) attenuation decreases over the injection time. The attenuation change exhibits a bell-shaped pattern during CO2 injection. Under Frio-II field reservoir conditions, White's patchy saturation model can quantitatively explain both the P wave velocity and attenuation response observed. We have combined the velocity and attenuation change data in a crossplot format that is useful for model-data comparison and determining patch size. Our analysis suggests that spatial-temporal attenuation change is not only an indicator of the movement and saturation of CO2 plumes, even at large saturations, but also can quantitatively constrain CO2 plume saturation when used jointly with seismic velocity.

Geochemical stability of phosphorus solids below septic system infiltration beds

NASA Astrophysics Data System (ADS)

Zurawsky, M. A.; Robertson, W. D.; Ptacek, C. J.; Schiff, S. L.

2004-09-01

Review of 10 mature septic system plumes in Ontario, revealed that phosphorus (P) attenuation commonly occurred close to the infiltration pipes, resulting in discrete narrow intervals enriched in P by a factor of 2-4 ( Wood, J.S.A. 1993. MSc thesis, Dept. Earth Sci., University of Waterloo, Waterloo, Ont.; Ground Water 36 (1995) 1000; J. Contam. Hydrol. 33 (1998) 405). Although these attenuation reactions appeared to be sustainable under present conditions, the potential for remobilization of this P mass, should geochemical conditions change, is unknown. To test the stability of these P solids, dynamic flow column tests were carried out using sediments from three of the previously studied sites (Cambridge, Langton and Muskoka) focusing on sediments from the 'High-P' and underlying (Below) zones. Tests were continued for 166-266 pore volumes (PVs), during which time varying degrees of water saturation were maintained. During saturated flow conditions, relatively high concentrations of PO 4 were eluted from the Cambridge and Langton High-P zones (up to 4 and 9 mg/l P, respectively), accompanied by elevated concentrations of Fe (up to 1.4 mg/l) and Mn (up to 4 mg/l) and lower values of Eh (<150 mV). The Below zones from Cambridge and Langton, however, maintained lower concentrations of P (generally<2 mg/l), Fe (<0.2 mg/l) and Mn (<1 mg/l) and maintained higher Eh (>250 mV) during saturated flow conditions. During unsaturated flow, P and Fe declined dramatically in the High-P zones (P<1 mg/l, Fe<0.2 mg/l), whereas concentrations remained about the same during saturated and unsaturated flow in the Below zones. This behavior is at least partly attributed to the development of reducing conditions during saturated flow in the High-P zones, leading to reductive dissolution of Fe (III)-P solids present in the sediments. Reducing conditions did not develop in the Below zones apparently because of lower sediment organic carbon (OC) contents (0.03-0.04 wt.%) compared to the High-P zones (0.2-0.65 wt.%). At the Muskoka site, where the sediments were noncalcareous, low values of P (<0.2 mg/l) were maintained in both the High-P and Below columns and reducing conditions did not develop. Results indicate the possibility of remobilizing P accumulated below septic system infiltration beds should conditions become more reducing. This could occur if sewage loading patterns change, for example when a seasonal use, lakeshore cottage is converted to a permanent dwelling.

Estimating the change of porosity in the saturated zone during air sparging.

PubMed

Tsai, Yih-jin; Kuo, Yu-chia; Chen, Tsu-chi; Chou, Feng-chih

2006-01-01

Air sparging is a remedial method for groundwater. The remedial region is similar to the air flow region in the saturated zone. If soil particles are transported during air sparging, the porosity distributions in the saturated zone change, which may alter the flow path of the air. To understand better the particle movement, this study performed a sandbox test to estimate the soil porosity change during air sparging. A clear fracture was formed and the phenomenon of particle movement was observed when the air injection was started. The moved sand filled the porous around the fracture and the reparked sand filled the fracture, reducing the porosity around the fracture. The results obtained from the photographs of the sandbox, the current measurements and the direct sand sample measurements were close to each other and are credible. Therefore, air injection during air sparging causes sand particle movement of sand, altering the characteristic of the sand matrix and the air distribution.

Landslide stability: Role of rainfall-induced, laterally propagating, pore-pressure waves

USGS Publications Warehouse

Priest, G.R.; Schulz, W.H.; Ellis, W.L.; Allan, J.A.; Niem, A.R.; Niem, W.A.

2011-01-01

The Johnson Creek Landslide is a translational slide in seaward-dipping Miocene siltstone and sandstone (Astoria Formation) and an overlying Quaternary marine terrace deposit. The basal slide plane slopes sub-parallel to the dip of the Miocene rocks, except beneath the back-tilted toe block, where it slopes inland. Rainfall events raise pore-water pressure in the basal shear zone in the form of pulses of water pressure traveling laterally from the headwall graben down the axis of the slide at rates of 1-6 m/hr. Infiltration of meteoric water and vertical pressure transmission through the unsaturated zone has been measured at ~50 mm/hr. Infiltration and vertical pressure transmission were too slow to directly raise head at the basal shear zone prior to landslide movement. Only at the headwall graben was the saturated zone shallow enough for rainfall events to trigger lateral pulses of water pressure through the saturated zone. When pressure levels in the basal shear zone exceeded thresholds defined in this paper, the slide began slow, creeping movement as an intact block. As pressures exceeded thresholds for movement in more of the slide mass, movement accelerated, and differential displacement between internal slide blocks became more pronounced. Rainfall-induced pore-pressure waves are probably a common landslide trigger wherever effective hydraulic conductivity is high and the saturated zone is located near the surface in some part of a slide. An ancillary finding is apparently greater accuracy of grouted piezometers relative to those in sand packs for measurement of pore pressures at the installed depth.

Quartz crystal growth

DOEpatents

Baughman, Richard J.

1992-01-01

A process for growing single crystals from an amorphous substance that can undergo phase transformation to the crystalline state in an appropriate solvent. The process is carried out in an autoclave having a lower dissolution zone and an upper crystallization zone between which a temperature differential (.DELTA.T) is maintained at all times. The apparatus loaded with the substance, solvent, and seed crystals is heated slowly maintaining a very low .DELTA.T between the warmer lower zone and cooler upper zone until the amorphous substance is transformed to the crystalline state in the lower zone. The heating rate is then increased to maintain a large .DELTA.T sufficient to increase material transport between the zones and rapid crystallization. .alpha.-Quartz single crystal can thus be made from fused quartz in caustic solvent by heating to 350.degree. C. stepwise with a .DELTA.T of 0.25.degree.-3.degree. C., increasing the .DELTA.T to about 50.degree. C. after the fused quartz has crystallized, and maintaining these conditions until crystal growth in the upper zone is completed.

Cage-rotor induction motor inter-turn short circuit fault detection with and without saturation effect by MEC model.

PubMed

Naderi, Peyman

2016-09-01

The inter-turn short fault for the Cage-Rotor-Induction-Machine (CRIM) is studied in this paper and its local saturation is taken into account. However, in order to observe the exact behavior of machine, the Magnetic-Equivalent-Circuit (MEC) and nonlinear B-H curve are proposed to provide an insight into the machine model and saturation effect respectively. The electrical machines are generally operated near to their saturation zone due to some design necessities. Hence, when the machine is exposed to a fault such as short circuit or eccentricities, it is operated within its saturation zone and thus, time and space harmonics are integrated and as a result, current and torque harmonics are generated which the phenomenon cannot be explored when saturation is dismissed. Nonetheless, inter-turn short circuit may lead to local saturation and this occurrence is studied in this paper using MEC model. In order to achieve the mentioned objectives, two and also four-pole machines are modeled as two samples and the machines performances are analyzed in healthy and faulty cases with and without saturation effect. A novel strategy is proposed to precisely detect inter-turn short circuit fault according to the stator׳s lines current signatures and the accuracy of the proposed method is verified by experimental results. Copyright © 2016 ISA. Published by Elsevier Ltd. All rights reserved.

Innovative low cost procedure for nutrient removal as an integrated element of a decentralised water management concept for rural areas.

PubMed

Burde, M; Rolf, F; Grabowski, F

2001-01-01

The absence of large rivers with rather high niveau of self purifying effect in parts of east Germany leads to a discharging of the effluent of wastewater treatment plants into the groundwater in many cases. One useful consequence is the idea of realisation of decentralised measures and concepts in urban water resources management concerning municipal wastewater as well as rainfall, precipitation. At the same time, only the upper soil zone--a few decimetres--is water--saturated and thus discharge effective, even when extreme rainfall takes place. Underneath, however, there generally exists an unsaturated soil zone, which is up to now a rather unexplored retardation element of the hydrologic- and substrate-cycle. Nutrient removal in small wastewater treatment plants that are emptying into ground waters is often beneficial. The presented studies optimised an inexpensive method of subsequent enhanced wastewater treatment. The developed reactor is similar to a concentrated subsoil passage. The fixed bed reactor is divided in two sections to achieve aerobic and anoxic conditions for nitrification/denitrification processes. To enhance phosphorus removal, ferrous particles are put into the aerobic zone. Two series of column tests were carried out and a technical pilot plant was built to verify the efficiency of the process. The results show that this method can be implemented successfully.

Reactive transport modeling of processes controlling the distribution and natural attenuation of phenolic compounds in a deep sandstone aquifer

NASA Astrophysics Data System (ADS)

Mayer, K. U.; Benner, S. G.; Frind, E. O.; Thornton, S. F.; Lerner, D. N.

2001-12-01

Reactive solute transport modeling was utilized to evaluate the potential for natural attenuation of a contaminant plume containing phenolic compounds at a chemical producer in the West Midlands, UK. The reactive transport simulations consider microbially mediated biodegradation of the phenolic compounds (phenols, cresols, and xylenols) by multiple electron acceptors. Inorganic reactions including hydrolysis, aqueous complexation, dissolution of primary minerals, formation of secondary mineral phases, and ion exchange are considered. One-dimensional (1D) and three-dimensional (3D) simulations were conducted. Mass balance calculations indicate that biodegradation in the saturated zone has degraded approximately 1-5% of the organic contaminant plume over a time period of 47 years. Simulations indicate that denitrification is the most significant degradation process, accounting for approximately 50% of the organic contaminant removal, followed by sulfate reduction and fermentation reactions, each contributing 15-20%. Aerobic respiration accounts for less than 10% of the observed contaminant removal in the saturated zone. Although concentrations of Fe(III) and Mn(IV) mineral phases are high in the aquifer sediment, reductive dissolution is limited, producing only 5% of the observed mass loss. Mass balance calculations suggest that no more than 20-25% of the observed total inorganic carbon (TIC) was generated from biodegradation reactions in the saturated zone. Simulations indicate that aerobic biodegradation in the unsaturated zone, before the contaminant entered the aquifer, may have produced the majority of the TIC observed in the plume. Because long-term degradation is limited to processes within the saturated zone, use of observed TIC concentrations to predict the future natural attenuation may overestimate contaminant degradation by a factor of 4-5.

On the coupled unsaturated-saturated flow process induced by vertical, horizontal, and slant wells in unconfined aquifers

NASA Astrophysics Data System (ADS)

Liang, Xiuyu; Zhan, Hongbin; Zhang, You-Kuan; Liu, Jin

2017-03-01

Conventional models of pumping tests in unconfined aquifers often neglect the unsaturated flow process. This study concerns the coupled unsaturated-saturated flow process induced by vertical, horizontal, and slant wells positioned in an unconfined aquifer. A mathematical model is established with special consideration of the coupled unsaturated-saturated flow process and the well orientation. Groundwater flow in the saturated zone is described by a three-dimensional governing equation and a linearized three-dimensional Richards' equation in the unsaturated zone. A solution in the Laplace domain is derived by the Laplace-finite-Fourier-transform and the method of separation of variables, and the semi-analytical solutions are obtained using a numerical inverse Laplace method. The solution is verified by a finite-element numerical model. It is found that the effects of the unsaturated zone on the drawdown of a pumping test exist at any angle of inclination of the pumping well, and this impact is more significant in the case of a horizontal well. The effects of the unsaturated zone on the drawdown are independent of the length of the horizontal well screen. The vertical well leads to the largest water volume drained from the unsaturated zone (W) during the early pumping time, and the effects of the well orientation on W values become insignificant at the later time. The screen length of the horizontal well does not affect W for the whole pumping period. The proposed solutions are useful for the parameter identification of pumping tests with a general well orientation (vertical, horizontal, and slant) in unconfined aquifers affected from above by the unsaturated flow process.

Modeling variably saturated subsurface solute transport with MODFLOW-UZF and MT3DMS

USGS Publications Warehouse

Morway, Eric D.; Niswonger, Richard G.; Langevin, Christian D.; Bailey, Ryan T.; Healy, Richard W.

2013-01-01

The MT3DMS groundwater solute transport model was modified to simulate solute transport in the unsaturated zone by incorporating the unsaturated-zone flow (UZF1) package developed for MODFLOW. The modified MT3DMS code uses a volume-averaged approach in which Lagrangian-based UZF1 fluid fluxes and storage changes are mapped onto a fixed grid. Referred to as UZF-MT3DMS, the linked model was tested against published benchmarks solved analytically as well as against other published codes, most frequently the U.S. Geological Survey's Variably-Saturated Two-Dimensional Flow and Transport Model. Results from a suite of test cases demonstrate that the modified code accurately simulates solute advection, dispersion, and reaction in the unsaturated zone. Two- and three-dimensional simulations also were investigated to ensure unsaturated-saturated zone interaction was simulated correctly. Because the UZF1 solution is analytical, large-scale flow and transport investigations can be performed free from the computational and data burdens required by numerical solutions to Richards' equation. Results demonstrate that significant simulation runtime savings can be achieved with UZF-MT3DMS, an important development when hundreds or thousands of model runs are required during parameter estimation and uncertainty analysis. Three-dimensional variably saturated flow and transport simulations revealed UZF-MT3DMS to have runtimes that are less than one tenth of the time required by models that rely on Richards' equation. Given its accuracy and efficiency, and the wide-spread use of both MODFLOW and MT3DMS, the added capability of unsaturated-zone transport in this familiar modeling framework stands to benefit a broad user-ship.

Modeling variably saturated subsurface solute transport with MODFLOW-UZF and MT3DMS.

PubMed

Morway, Eric D; Niswonger, Richard G; Langevin, Christian D; Bailey, Ryan T; Healy, Richard W

2013-03-01

The MT3DMS groundwater solute transport model was modified to simulate solute transport in the unsaturated zone by incorporating the unsaturated-zone flow (UZF1) package developed for MODFLOW. The modified MT3DMS code uses a volume-averaged approach in which Lagrangian-based UZF1 fluid fluxes and storage changes are mapped onto a fixed grid. Referred to as UZF-MT3DMS, the linked model was tested against published benchmarks solved analytically as well as against other published codes, most frequently the U.S. Geological Survey's Variably-Saturated Two-Dimensional Flow and Transport Model. Results from a suite of test cases demonstrate that the modified code accurately simulates solute advection, dispersion, and reaction in the unsaturated zone. Two- and three-dimensional simulations also were investigated to ensure unsaturated-saturated zone interaction was simulated correctly. Because the UZF1 solution is analytical, large-scale flow and transport investigations can be performed free from the computational and data burdens required by numerical solutions to Richards' equation. Results demonstrate that significant simulation runtime savings can be achieved with UZF-MT3DMS, an important development when hundreds or thousands of model runs are required during parameter estimation and uncertainty analysis. Three-dimensional variably saturated flow and transport simulations revealed UZF-MT3DMS to have runtimes that are less than one tenth of the time required by models that rely on Richards' equation. Given its accuracy and efficiency, and the wide-spread use of both MODFLOW and MT3DMS, the added capability of unsaturated-zone transport in this familiar modeling framework stands to benefit a broad user-ship. Published 2012. This article is a U.S. Government work and is in the public domain in the USA.

Investigations of the unsaturated zone at two radioactive waste disposal sites in Lithuania.

PubMed

Skuratovič, Žana; Mažeika, Jonas; Petrošius, Rimantas; Martma, Tõnu

2016-01-01

The unsaturated zone is an important part of the water cycle, governed by many hydrological and hydrogeological factors and processes and provide water and nutrients to the terrestrial ecosystem. Besides, the soils of the unsaturated zone are regarded as the first natural barrier to a large extent and are able to limit the spread of contaminants depending on their properties. The unsaturated zone provides a linkage between atmospheric moisture, groundwater, and seepage of groundwater to streams, lakes, or other surface water bodies. The major difference between water flow in saturated and unsaturated soils is that the hydraulic conductivity, which is conventionally assumed to be a constant in saturated soils, is a function of the degree of saturation or matrix suction in the unsaturated soils. In Lithuania, low and intermediate level radioactive wastes generated from medicine, industry and research were accumulated at the Maisiagala radioactive waste repository. Short-lived low and intermediate levels radioactive waste, generated during the operation of the Ignalina Nuclear Power Plant (INPP) and arising after the INPP decommissioning will be disposed of in the near surface repository close to the INPP (Stabatiske site). Extensive data sets of the hydraulic properties and water content attributed to unsaturated zone soil profiles of the two radioactive waste disposal sites have been collected and summarized. Globally widespread radionuclide tritium ((3)H) and stable isotope ratio ((18)O/(16)O and (2)H/(1)H) distribution features were determined in precipitation, unsaturated zone soil moisture profiles and groundwater.

Distributed watershed modeling of design storms to identify nonpoint source loading areas

DOE Office of Scientific and Technical Information (OSTI.GOV)

Endreny, T.A.; Wood, E.F.

1999-03-01

Watershed areas that generate nonpoint source (NPS) polluted runoff need to be identified prior to the design of basin-wide water quality projects. Current watershed-scale NPS models lack a variable source area (VSA) hydrology routine, and are therefore unable to identify spatially dynamic runoff zones. The TOPLATS model used a watertable-driven VSA hydrology routine to identify runoff zones in a 17.5 km{sup 2} agricultural watershed in central Oklahoma. Runoff areas were identified in a static modeling framework as a function of prestorm watertable depth and also in a dynamic modeling framework by simulating basin response to 2, 10, and 25 yrmore » return period 6 h design storms. Variable source area expansion occurred throughout the duration of each 6 h storm and total runoff area increased with design storm intensity. Basin-average runoff rates of 1 mm h{sup {minus}1} provided little insight into runoff extremes while the spatially distributed analysis identified saturation excess zones with runoff rates equaling effective precipitation. The intersection of agricultural landcover areas with these saturation excess runoff zones targeted the priority potential NPS runoff zones that should be validated with field visits. These intersected areas, labeled as potential NPS runoff zones, were mapped within the watershed to demonstrate spatial analysis options available in TOPLATS for managing complex distributions of watershed runoff. TOPLATS concepts in spatial saturation excess runoff modelling should be incorporated into NPS management models.« less

Finite-frequency wave propagation through outer rise fault zones and seismic measurements of upper mantle hydration

USGS Publications Warehouse

Miller, Nathaniel; Lizarralde, Daniel

2016-01-01

Effects of serpentine-filled fault zones on seismic wave propagation in the upper mantle at the outer rise of subduction zones are evaluated using acoustic wave propagation models. Modeled wave speeds depend on azimuth, with slowest speeds in the fault-normal direction. Propagation is fastest along faults, but, for fault widths on the order of the seismic wavelength, apparent wave speeds in this direction depend on frequency. For the 5–12 Hz Pn arrivals used in tomographic studies, joint-parallel wavefronts are slowed by joints. This delay can account for the slowing seen in tomographic images of the outer rise upper mantle. At the Middle America Trench, confining serpentine to fault zones, as opposed to a uniform distribution, reduces estimates of bulk upper mantle hydration from ~3.5 wt % to as low as 0.33 wt % H2O.

Perfusion scintigraphy and patient selection for lung volume reduction surgery.

PubMed

Chandra, Divay; Lipson, David A; Hoffman, Eric A; Hansen-Flaschen, John; Sciurba, Frank C; Decamp, Malcolm M; Reilly, John J; Washko, George R

2010-10-01

It is unclear if lung perfusion can predict response to lung volume reduction surgery (LVRS). To study the role of perfusion scintigraphy in patient selection for LVRS. We performed an intention-to-treat analysis of 1,045 of 1,218 patients enrolled in the National Emphysema Treatment Trial who were non-high risk for LVRS and had complete perfusion scintigraphy results at baseline. The median follow-up was 6.0 years. Patients were classified as having upper or non-upper lobe-predominant emphysema on visual examination of the chest computed tomography and high or low exercise capacity on cardiopulmonary exercise testing at baseline. Low upper zone perfusion was defined as less than 20% of total lung perfusion distributed to the upper third of both lungs as measured on perfusion scintigraphy. Among 284 of 1,045 patients with upper lobe-predominant emphysema and low exercise capacity at baseline, the 202 with low upper zone perfusion had lower mortality with LVRS versus medical management (risk ratio [RR], 0.56; P = 0.008) unlike the remaining 82 with high perfusion where mortality was unchanged (RR, 0.97; P = 0.62). Similarly, among 404 of 1,045 patients with upper lobe-predominant emphysema and high exercise capacity, the 278 with low upper zone perfusion had lower mortality with LVRS (RR, 0.70; P = 0.02) unlike the remaining 126 with high perfusion (RR, 1.05; P = 1.00). Among the 357 patients with non-upper lobe-predominant emphysema (75 with low and 282 with high exercise capacity) there was no improvement in survival with LVRS and measurement of upper zone perfusion did not contribute new prognostic information. Compared with optimal medical management, LVRS reduces mortality in patients with upper lobe-predominant emphysema when there is low rather than high perfusion to the upper lung.

Effects of recharge, Upper Floridan aquifer heads, and time scale on simulated ground-water exchange with Lake Starr, a seepage lake in central Florida

USGS Publications Warehouse

Swancar, Amy; Lee, Terrie Mackin

2003-01-01

Lake Starr and other lakes in the mantled karst terrain of Florida's Central Lake District are surrounded by a conductive surficial aquifer system that receives highly variable recharge from rainfall. In addition, downward leakage from these lakes varies as heads in the underlying Upper Floridan aquifer change seasonally and with pumpage. A saturated three-dimensional finite-difference ground-water flow model was used to simulate the effects of recharge, Upper Floridan aquifer heads, and model time scale on ground-water exchange with Lake Starr. The lake was simulated as an active part of the model using high hydraulic conductivity cells. Simulated ground-water flow was compared to net ground-water flow estimated from a rigorously derived water budget for the 2-year period August 1996-July 1998. Calibrating saturated ground-water flow models with monthly stress periods to a monthly lake water budget will result in underpredicting gross inflow to, and leakage from, ridge lakes in Florida. Underprediction of ground-water inflow occurs because recharge stresses and ground-water flow responses during rainy periods are averaged over too long a time period using monthly stress periods. When inflow is underestimated during calibration, leakage also is underestimated because inflow and leakage are correlated if lake stage is maintained over the long term. Underpredicted leakage reduces the implied effect of ground-water withdrawals from the Upper Floridan aquifer on the lake. Calibrating the weekly simulation required accounting for transient responses in the water table near the lake that generated the greater range of net ground-water flow values seen in the weekly water budget. Calibrating to the weekly lake water budget also required increasing the value of annual recharge in the nearshore region well above the initial estimate of 35 percent of the rainfall, and increasing the hydraulic conductivity of the deposits around and beneath the lake. To simulate the total ground-water inflow to lakes, saturated-flow models of lake basins need to account for the potential effects of rapid and efficient recharge in the surficial aquifer system closest to the lake. In this part of the basin, the ability to accurately estimate recharge is crucial because the water table is shallowest and the response time between rainfall and recharge is shortest. Use of the one-dimensional LEACHM model to simulate the effects of the unsaturated zone on the timing and magnitude of recharge in the nearshore improved the simulation of peak values of ground-water inflow to Lake Starr. Results of weekly simulations suggest that weekly recharge can approach the majority of weekly rainfall on the nearshore part of the lake basin. However, even though a weekly simulation with higher recharge in the nearshore was able to reproduce the extremes of ground-water exchange with the lake more accurately, it was not consistently better at predicting net ground-water flow within the water budget error than a simulation with lower recharge. The more subtle effects of rainfall and recharge on ground-water inflow to the lake were more difficult to simulate. The use of variably saturated flow modeling, with time scales that are shorter than weekly and finer spatial discretization, is probably necessary to understand these processes. The basin-wide model of Lake Starr had difficulty simulating the full spectrum of ground-water inflows observed in the water budget because of insufficient information about recharge to ground water, and because of practical limits on spatial and temporal discretization in a model at this scale. In contrast, the saturated flow model appeared to successfully simulate the effects of heads in the Upper Floridan aquifer on water levels and ground-water exchange with the lake at both weekly and monthly stress periods. Most of the variability in lake leakage can be explained by the average vertical head difference between the lake and a re

Defining the upper age limit of luminescence dating: A case study using long lacustrine records from Chew Bahir, Ethiopia

NASA Astrophysics Data System (ADS)

Chapot, Melissa S.; Roberts, Helen M.; Lamb, Henry F.; Schäbitz, Frank; Asrat, Asfawossen; Trauth, Martin H.

2017-04-01

Optically stimulated luminescence (OSL) dating is a family of numerical chronometric techniques applied to quartz or feldspar mineral grains to assess the time since these grains were last exposed to sunlight (i.e. deposited), based on the amount of energy they absorbed from ambient radiation during burial. The maximum limit of any OSL dating technique is not defined by a fixed upper age limit, but instead by the maximum radiation dose the sample can accurately record before the OSL signal saturates. The challenge is to assess this upper limit of accurate age determination without necessitating comparison to independent age control. Laboratory saturation of OSL signals can be observed using a dose response curve (DRC) plotting OSL signal intensity against absorbed laboratory radiation dose. When a DRC is fitted with a single saturating exponential, one of the equation's parameters can be used to define a pragmatic upper limit beyond which uncertainties become large and asymmetric (Wintle and Murray, 2006). However, many sub-samples demonstrate DRCs that are best defined by double saturating exponential equations, which cannot be used to define this upper limit. To investigate the reliability of luminescence ages approaching saturation, Chapot et al. (2012) developed the Natural DRC concept, which uses expected ages derived from independent age control, combined with sample-specific measurements of ambient radioactivity, to calculate expected doses of absorbed radiation during burial. Natural OSL signal intensity is then plotted against these expected doses and compared to laboratory-generated DRCs. Using this approach, discrepancies between natural and laboratory DRCs have been observed for the same mineral material as natural OSL signal intensities saturate at absorbed radiation doses lower than the pragmatic upper limit defined by laboratory DRCs, leading to increasing age underestimation with depth without a metric for questioning the age reliability. The present study explores a means of defining the upper limit for reliable luminescence ages for sedimentary records without an established chronologic framework, using a long ( 280m; Cohen et al., 2016) lacustrine record from Chew Bahir, Ethiopia, drilled as part of the Hominin Sites and Paleolakes Drilling Project (HSPDP) of the International Continental Scientific Drilling Programme (ICDP) and CRC806 "Our way to Europe". Natural saturation of OSL signals is explored by plotting natural signal intensity against depth, creating a pseudo-Natural DRC that can be compared to laboratory DRCs. Unlike the homogenous deposits of the Chinese Loess Plateau where the Natural DRC concept was developed, the 280m composite core from Chew Bahir shows significant variation in lithology enabling investigation of the effects of sample to sample variability on Natural DRC construction, and facilitating comparison between signals from fine-quartz, fine-polymineral, and coarse-potassium feldspar grains. This work demonstrates how the concepts of Natural DRCs can be used to define the upper dating limit of sample suites without independent age control, providing valuable information for long sedimentary sequences such as the lacustrine deposits from Chew Bahir. Chapot M.S., et al. (2012), Radiation Measurements 47: 1045-1052. Cohen A, et al. (2016), Scientific Drilling 21: 1-16. Wintle, A.G., Murray, A.S. (2006) Radiation Measurements 41: 369-391.

77 FR 53769 - Safety Zone; Liberty to Freedom Swims, Liberty Island, Upper Bay and Hudson River, NY

Federal Register 2010, 2011, 2012, 2013, 2014

2012-09-04

... 1625-AA00 Safety Zone; Liberty to Freedom Swims, Liberty Island, Upper Bay and Hudson River, NY AGENCY... September 5, 2012 and September 15, 2012 Liberty to Freedom swim events. This temporary safety zone is necessary to protect the maritime public and event participants from the hazards associated with swim events...

Storage dynamics in hydropedological units control hillslope connectivity, runoff generation, and the evolution of catchment transit time distributions

PubMed Central

Tetzlaff, D; Birkel, C; Dick, J; Geris, J; Soulsby, C

2014-01-01

We examined the storage dynamics and isotopic composition of soil water over 12 months in three hydropedological units in order to understand runoff generation in a montane catchment. The units form classic catena sequences from freely draining podzols on steep upper hillslopes through peaty gleys in shallower lower slopes to deeper peats in the riparian zone. The peaty gleys and peats remained saturated throughout the year, while the podzols showed distinct wetting and drying cycles. In this region, most precipitation events are <10 mm in magnitude, and storm runoff is mainly generated from the peats and peaty gleys, with runoff coefficients (RCs) typically <10%. In larger events the podzolic soils become strongly connected to the saturated areas, and RCs can exceed 40%. Isotopic variations in precipitation are significantly damped in the organic-rich soil surface horizons due to mixing with larger volumes of stored water. This damping is accentuated in the deeper soil profile and groundwater. Consequently, the isotopic composition of stream water is also damped, but the dynamics strongly reflect those of the near-surface waters in the riparian peats. “pre-event” water typically accounts for >80% of flow, even in large events, reflecting the displacement of water from the riparian soils that has been stored in the catchment for >2 years. These riparian areas are the key zone where different source waters mix. Our study is novel in showing that they act as “isostats,” not only regulating the isotopic composition of stream water, but also integrating the transit time distribution for the catchment. Key Points Hillslope connectivity is controlled by small storage changes in soil units Different catchment source waters mix in large riparian wetland storage Isotopes show riparian wetlands set the catchment transit time distribution PMID:25506098

Storage dynamics in hydropedological units control hillslope connectivity, runoff generation, and the evolution of catchment transit time distributions.

PubMed

Tetzlaff, D; Birkel, C; Dick, J; Geris, J; Soulsby, C

2014-02-01

We examined the storage dynamics and isotopic composition of soil water over 12 months in three hydropedological units in order to understand runoff generation in a montane catchment. The units form classic catena sequences from freely draining podzols on steep upper hillslopes through peaty gleys in shallower lower slopes to deeper peats in the riparian zone. The peaty gleys and peats remained saturated throughout the year, while the podzols showed distinct wetting and drying cycles. In this region, most precipitation events are <10 mm in magnitude, and storm runoff is mainly generated from the peats and peaty gleys, with runoff coefficients (RCs) typically <10%. In larger events the podzolic soils become strongly connected to the saturated areas, and RCs can exceed 40%. Isotopic variations in precipitation are significantly damped in the organic-rich soil surface horizons due to mixing with larger volumes of stored water. This damping is accentuated in the deeper soil profile and groundwater. Consequently, the isotopic composition of stream water is also damped, but the dynamics strongly reflect those of the near-surface waters in the riparian peats. "pre-event" water typically accounts for >80% of flow, even in large events, reflecting the displacement of water from the riparian soils that has been stored in the catchment for >2 years. These riparian areas are the key zone where different source waters mix. Our study is novel in showing that they act as "isostats," not only regulating the isotopic composition of stream water, but also integrating the transit time distribution for the catchment. Hillslope connectivity is controlled by small storage changes in soil unitsDifferent catchment source waters mix in large riparian wetland storageIsotopes show riparian wetlands set the catchment transit time distribution.

Saturation of low-threshold two-plasmon parametric decay leading to excitation of one localized upper hybrid wave

NASA Astrophysics Data System (ADS)

Gusakov, E. Z.; Popov, A. Yu.; Saveliev, A. N.

2018-06-01

We analyze the saturation of the low-threshold absolute parametric decay instability of an extraordinary pump wave leading to the excitation of two upper hybrid (UH) waves, only one of which is trapped in the vicinity of a local maximum of the plasma density profile. The pump depletion and the secondary decay of the localized daughter UH wave are treated as the most likely moderators of a primary two-plasmon decay instability. The reduced equations describing the nonlinear saturation phenomena are derived. The general analytical consideration is accompanied by the numerical analysis performed under the experimental conditions typical of the off-axis X2-mode ECRH experiments at TEXTOR. The possibility of substantial (up to 20%) anomalous absorption of the pump wave is predicted.

Multi-scale hydrogeological and hydrogeophysical approach to monitor vadose zone hydrodynamics of a karst system

NASA Astrophysics Data System (ADS)

Watlet, Arnaud; Poulain, Amaël; Van Camp, Michel; Francis, Olivier; Triantafyllou, Antoine; Rochez, Gaëtan; Hallet, Vincent; Kaufmann, Olivier

2016-04-01

The vadose zone of karst systems plays an important role on the water dynamics. In particular, temporary perched aquifers can appear in the subsurface due to changes of weather conditions, reduced evapotranspiration and the vertical gradients of porosity and permeability. Although many difficulties are usually encountered when studying karst environments due to their heterogeneities, cave systems offer an outstanding opportunity to investigate vadose zone from the inside. We present a multi-scale study covering two years of hydrogeological and geophysical monitoring of the Lomme Karst System (LKS) located in the Variscan fold-and-thrust belt (Belgium), a region (~ 3000 ha) that shows many karstic networks within Devonian limestone units. Hydrogeological data cover the whole LKS and involve e.g. flows and levels monitoring or tracer tests performed in both vadose and saturated zones. Such data bring valuable information on the hydrological context of the studied area at the catchment scale. Combining those results with geophysical measurements allows validating and imaging them at a smaller scale, with more integrative techniques. Hydrogeophysical measurements are focused on only one cave system of the LKS, at the Rochefort site (~ 40 ha), taking benefit of the Rochefort Cave Laboratory (RCL) infrastructures. In this study, a microgravimetric monitoring and an Electrical Resistivity Tomography (ERT) monitoring are involved. The microgravimetric monitoring consists in a superconducting gravimeter continuously measuring gravity changes at the surface of the RCL and an additional relative gravimeter installed in the underlying cave located 35 meters below the surface. While gravimeters are sensible to changes that occur in both the vadose zone and the saturated zone of the whole cave system, combining their recorded signals allows enhancing vadose zone's gravity changes. Finally, the surface ERT monitoring provide valuable information at the (sub)-meter scale on the hydrological processes that occur in the vadose zone. Seasonal water variations and preferential flow path are observed. This helps separating the hydrological signature of the vadose zone from that of the saturated zone.

Spatial distribution of triazine residues in a shallow alluvial aquifer linked to groundwater residence time.

PubMed

Sassine, Lara; Le Gal La Salle, Corinne; Khaska, Mahmoud; Verdoux, Patrick; Meffre, Patrick; Benfodda, Zohra; Roig, Benoît

2017-03-01

At present, some triazine herbicides occurrence in European groundwater, 13 years after their use ban in the European Union, remains of great concern and raises the question of their persistence in groundwater systems due to several factors such as storage and remobilization from soil and unsaturated zone, limited or absence of degradation, sorption in saturated zones, or to continuing illegal applications. In order to address this problem and to determine triazine distribution in the saturated zone, their occurrence is investigated in the light of the aquifer hydrodynamic on the basis of a geochemical approach using groundwater dating tracers ( 3 H/ 3 He). In this study, atrazine, simazine, terbuthylazine, deethylatrazine, deisopropylatrazine, and deethylterbuthylazine are measured in 66 samples collected between 2011 and 2013 from 21 sampling points, on the Vistrenque shallow alluvial aquifer (southern France), covered by a major agricultural land use. The frequencies of quantification range from 100 to 56 % for simazine and atrazine, respectively (LQ = 1 ng L -1 ). Total triazine concentrations vary between 15 and 350 ng L -1 and show three different patterns with depth below the water table: (1) low concentrations independent of depth but related to water origin, (2) an increase in concentrations with depth in the aquifer related to groundwater residence time and triazine use prior to their ban, and (3) relatively high concentrations at low depths in the saturated zone more likely related to a slow desorption of these compounds from the soil and unsaturated zone. The triazine attenuation rate varies between 0.3 for waters influenced by surface water infiltration and 4.8 for water showing longer residence times in the aquifer, suggesting an increase in these rates with water residence time in the saturated zone. Increasing triazine concentrations with depth is consistent with a significant decrease in the use of these pesticides for the last 10 years on this area and highlights the efficiency of their ban.

Global Distribution and Parameter Dependences of Gravity Wave Activity in the Martian Upper Thermosphere Derived from MAVEN NGIMS Observations

NASA Technical Reports Server (NTRS)

Terada, Naoki; Leblanc, Francois; Nakagawa, Hiromu; Medvedev, Alexander S.; Yigit, Erdal; Kuroda, Takeshi; Hara, Takuya; England, Scott L.; Fujiwara, Hitoshi; Terada, Kaori;

SIMS analyses of minor and trace element distributions in fracture calcite from Yucca Mountain, Nevada, USA

NASA Astrophysics Data System (ADS)

Denniston, Rhawn F.; Shearer, Charles K.; Layne, Graham D.; Vaniman, David T.

1997-05-01

Fracture-lining calcite samples from Yucca Mountain, Nevada, obtained as part of the extensive vertical sampling in studies of this site as a potential high-level waste repository, have been characterized according to microbeam-scale (25-30 μm) trace and minor element chemistry, and cathodoluminescent zonation patterns. As bulk chemical analyses are limited in spatial resolution and are subject to contamination by intergrown phases, a technique for analysis by secondary ion mass spectrometry (SIMS) of minor (Mn, Fe, Sr) and trace (REE) elements in calcite was developed and applied to eighteen calcite samples from four boreholes and one trench. SIMS analyses of REE in calcite and dolomite have been shown to be quantitative to abundances < 1 × chondrite. Although the low secondary ion yields associated with carbonates forced higher counting times than is necessary in most silicates, Mn, Fe, Sr, and REE analyses were obtained with sub-ppm detection limits and 2-15% analytical precision. Bulk chemical signatures noted by Vaniman (1994) allowed correlation of minor and trace element signatures in Yucca Mountain calcite with location of calcite precipitation (saturated vs. unsaturated zone). For example, upper unsaturated zone calcite exhibits pronounced negative Ce and Eu anomalies not observed in calcite collected below in the deep unsaturated zone. These chemical distinctions served as fingerprints which were applied to growth zones in order to examine temporal changes in calcite crystallization histories; analyses of such fine-scale zonal variations are unattainable using bulk analytical techniques. In addition, LREE (particularly Ce) scavenging of calcite-precipitating solutions by manganese oxide phases is discussed as the mechanism for Ce-depletion in unsaturated zone calcite.

Upper limit for the effect of elastic bending stress on the saturation magnetization of L a0.8S r0.2Mn O3

NASA Astrophysics Data System (ADS)

Wang, Q.; Chen, A. P.; Guo, E. J.; Roldan, M. A.; Jia, Q. X.; Fitzsimmons, M. R.

2018-01-01

Using polarized neutron reflectometry, we measured the influence of elastic bending stress on the magnetization depth profile of a L a0.8S r0.2Mn O3 (LSMO) epitaxial film grown on a SrTi O3 substrate. The elastic bending strain of ±0.03 % has no obvious effect on the magnetization depth profile at saturation. This result is in stark contrast to that of (L a1 -xP rx)1 -y C ayMn O3 (LPCMO) films for which strain of ±0.01 % produced dramatic changes in the magnetization profile and Curie temperature. We attribute the difference between the influence of strain on the saturation magnetization in LSMO (weak or none) and LPCMO (strong) to a difference in the ability of LSMO (weak or none) and LPCMO (strong) to phase separate. Our observation provides an upper limit of tuning LSMO saturation magnetization via elastic strain effect.

An object-oriented model of the cardiopulmonary system with emphasis on the gravity effect.

PubMed

Chuong Ngo; Herranz, Silvia Briones; Misgeld, Berno; Vollmer, Thomas; Leonhardt, Steffen

2016-08-01

We introduce a novel comprehensive model of the cardiopulmonary system with emphasis on perfusion and ventilation distribution along the vertical thorax axis under the gravity effect. By using an object-oriented environment, the complex physiological system can be represented by a network of electrical, lumped-element compartments. The lungs are divided into three zones: upper, middle, and lower zone. Blood flow increases with the distance from the apex to the base of the lungs. The upper zone is characterized by a complete collapse of the pulmonary capillary vasculature; thus, there is no flow in this zone. The second zone has a "waterfall effect" where the blood flow is determined by the difference between the pulmonary-arterial and alveolar pressures. At resting position, the upper lobes of the lungs are more expanded than the middle and lower lobes. However, during spontaneous breathing, ventilation is nonuniform with more air entering the lower lobes than the middle and upper lobes. A simulative model of the complete system is developed which shows results in good agreement with the literature.

Surface water-groundwater exchange in transitional coastal environments by airborne electromagnetics: The Venice Lagoon example

NASA Astrophysics Data System (ADS)

Viezzoli, A.; Tosi, L.; Teatini, P.; Silvestri, S.

2010-01-01

A comprehensive investigation of the mixing between salt/fresh surficial water and groundwater in transitional environments is an issue of paramount importance considering the ecological, cultural, and socio-economic relevance of coastal zones. Acquiring information, which can improve the process understanding, is often logistically challenging, and generally expensive and slow in these areas. Here we investigate the capability of airborne electromagnetics (AEM) at the margin of the Venice Lagoon, Italy. The quasi-3D interpretation of the AEM outcome by the spatially constrained inversion (SCI) methodology allows us to accurately distinguish several hydrogeological features down to a depth of about 200 m. For example, the extent of the saltwater intrusion in coastal aquifers and the transition between the upper salt saturated and the underlying fresher sediments below the lagoon bottom are detected. The research highlights the AEM capability to improve the hydrogeological characterization of subsurface processes in worldwide lagoons, wetlands, deltas.

Results of hydraulic tests in U.S. Department of Energy's wells DOE-4, 5, 6, 7, 8, and 9, Salt Valley, Grand County, Utah

USGS Publications Warehouse

Wollitz, Leonard E.; Thordarson, William; Whitfield, Merrick S.; Weir, James E.

1982-01-01

Six exploratory wells were drilled into the cap rock underlying Salt Valley, Utah, for geologic, geophysical, and hydrologic data to augment information obtained from three previous test wells. Drilling of three other test holes was abandoned due to caving and loss of drilling tools, Before reaching the zone of saturation; the upper 100 meters of cap rock is unsaturated. Within the saturated part of the cap rock, hydraulic heads generally decrease with depth and to the northwest in this part of the valley.Hydraulic conductivity of the cap rock, as determined from pumping tests, ranged from 9.3 X 10-5 to 2.06 X 10-1 meters per day; as a result, groundwater flow rates in the cap rock are low. Water ranges from a calcium bicarbonate sulfate type on the western edge of the valley to a calcium magnesium sodium bicarbonate, sulfate, chloride type near the center of the valley. Carbon-14 specific activity for cap-rock water yielded an uncorrected age of about 17,000 to 26,000 years before present near the western edge of the valley and about 41,000 years before present near the center of the valley.

System and method for producing metallic iron

DOEpatents

Bleifuss, Rodney L [Grand Rapids, MN; Englund, David J [Bovey, MN; Iwasaki, Iwao [Grand Rapids, MN; Fosnacht, Donald R [Hermantown, MN; Brandon, Mark M [Charlotte, NC; True, Bradford G [Charlotte, NC

2012-01-17

A hearth furnace 10 for producing metallic iron material has a furnace housing 11 having a drying/preheat zone 12, a conversion zone 13, a fusion zone 14, and optionally a cooling zone 15, the conversion zone 13 is between the drying/preheat zone 12 and the fusion zone 14. A moving hearth 20 is positioned within the furnace housing 11. A hood or separation barrier 30 within at least a portion of the conversion zone 13, fusion zone 14 or both separates the fusion zone 14 into an upper region and a lower region with the lower region adjacent the hearth 20 and the upper region adjacent the lower region and spaced from the hearth 20. An injector introduces a gaseous reductant into the lower region adjacent the hearth 20. A combustion region may be formed above the hood or separation barrier.

Self-potential investigations of a gravel bar in a restored river corridor

USGS Publications Warehouse

Linde, N.; Doetsch, J.; Jougnot, D.; Genoni, O.; Durst, Y.; Minsley, B.J.; Vogt, T.; Pasquale, N.; Luster, J.

2011-01-01

Self-potentials (SP) are sensitive to water fluxes and concentration gradients in both saturated and unsaturated geological media, but quantitative interpretations of SP field data may often be hindered by the superposition of different source contributions and time-varying electrode potentials. Self-potential mapping and close to two months of SP monitoring on a gravel bar were performed to investigate the origins of SP signals at a restored river section of the Thur River in northeastern Switzerland. The SP mapping and subsequent inversion of the data indicate that the SP sources are mainly located in the upper few meters in regions of soil cover rather than bare gravel. Wavelet analyses of the time-series indicate a strong, but non-linear influence of water table and water content variations, as well as rainfall intensity on the recorded SP signals. Modeling of the SP response with respect to an increase in the water table elevation and precipitation indicate that the distribution of soil properties in the vadose zone has a very strong influence. We conclude that the observed SP responses on the gravel bar are more complicated than previously proposed semi-empiric relationships between SP signals and hydraulic head or the thickness of the vadose zone. We suggest that future SP monitoring in restored river corridors should either focus on quantifying vadose zone processes by installing vertical profiles of closely spaced SP electrodes or by installing the electrodes within the river to avoid signals arising from vadose zone processes and time-varying electrochemical conditions in the vicinity of the electrodes. ?? 2011 Author(s).

Self-potential investigations of a gravel bar in a restored river corridor

USGS Publications Warehouse

Linde, N.; Doetsch, J.; Jougnot, D.; Genoni, O.; Durst, Y.; Minsley, Burke J.; Vogt, T.; Pasquale, N.; Luster, J.

2011-01-01

 Self-potentials (SP) are sensitive to water fluxes and concentration gradients in both saturated and unsaturated geological media, but quantitative interpretations of SP field data may often be hindered by the superposition of different source contributions and time-varying electrode potentials. Self-potential mapping and close to two months of SP monitoring on a gravel bar were performed to investigate the origins of SP signals at a restored river section of the Thur River in northeastern Switzerland. The SP mapping and subsequent inversion of the data indicate that the SP sources are mainly located in the upper few meters in regions of soil cover rather than bare gravel. Wavelet analyses of the time-series indicate a strong, but non-linear influence of water table and water content variations, as well as rainfall intensity on the recorded SP signals. Modeling of the SP response with respect to an increase in the water table elevation and precipitation indicate that the distribution of soil properties in the vadose zone has a very strong influence. We conclude that the observed SP responses on the gravel bar are more complicated than previously proposed semi-empiric relationships between SP signals and hydraulic head or the thickness of the vadose zone. We suggest that future SP monitoring in restored river corridors should either focus on quantifying vadose zone processes by installing vertical profiles of closely spaced SP electrodes or by installing the electrodes within the river to avoid signals arising from vadose zone processes and time-varying electrochemical conditions in the vicinity of the electrodes.

The Canadian experience: why Canada decided against an upper limit for cholesterol.

PubMed

McDonald, Bruce E

2004-12-01

Canada, like the United States, held a "consensus conference on cholesterol" in 1988. Although the final report of the consensus panel recommended that total dietary fat not exceed 30 percent and saturated fat not exceed 10 percent of total energy intake, it did not specify an upper limit for dietary cholesterol. Similarly, the 1990, Health Canada publication "Nutrition Recommendations: The Report of the Scientific Review Committee" specified upper limits for total and saturated fat in the diet but did not specify an upper limit for cholesterol. Canada's Guidelines for Healthy Eating, a companion publication from Health Canada, suggested that Canadians "choose low-fat dairy products, lean meats, and foods prepared with little or no fat" while enjoying "a variety of foods." Many factors contributed to this position but a primary element was the belief that total dietary fat and saturated fat were primary dietary determinants of serum total and low-density lipoprotein (LDL) cholesterol levels, not dietary cholesterol. Hence, Canadian health authorities focused on reducing saturated fat and trans fats in the Canadian diet to help lower blood cholesterol levels rather than focusing on limiting dietary cholesterol. In an effort to allay consumer concern with the premise that blood cholesterol level is linked to dietary cholesterol, organizations such as the Canadian Egg Marketing Agency (CEMA) reminded health professionals, including registered dietitians, family physicians and nutrition educators, of the extensive data showing that there is little relationship between dietary cholesterol intake and cardiovascular mortality. In addition, it was pointed out that for most healthy individuals, endogenous synthesis of cholesterol by the liver adjusts to the level of dietary cholesterol intake. Educating health professionals about the relatively weak association between dietary cholesterol and the relatively strong association between serum cholesterol and saturated fat and trans fats helped keep consumers informed about healthy diets and ways to control blood cholesterol.

Hydrogeologic framework and geochemistry of the intermediate aquifer system in parts of Charlotte, De Soto, and Sarasota counties, Florida

USGS Publications Warehouse

Torres, A.E.; Sacks, L.A.; Yobbi, D.K.; Knochenmus, L.A.; Katz, B.G.

2001-01-01

The hydrogeologic framework underlying the 600-square-mile study area in Charlotte, De Soto, and Sarasota Counties, Florida, consists of the surficial aquifer system, the intermediate aquifer system, and the Upper Floridan aquifer. The hydrogeologic framework and the geochemical processes controlling ground-water composition were evaluated for the study area. Particular emphasis was given to the analysis of hydrogeologic and geochemical data for the intermediate aquifer system. Flow regimes are not well understood in the intermediate aquifer system; therefore, hydrogeologic and geochemical information were used to evaluate connections between permeable zones within the intermediate aquifer system and between overlying and underlying aquifer systems. Knowledge of these connections will ultimately help to protect ground-water quality in the intermediate aquifer system. The hydrogeology was interpreted from lithologic and geophysical logs, water levels, hydraulic properties, and water quality from six separate well sites. Water-quality samples were collected from wells located along six ground-water flow paths and finished at different depth intervals. The selection of flow paths was based on current potentiometric-surface maps. Ground-water samples were analyzed for major ions; field parameters (temperature, pH, specific conductance, and alkalinity); stable isotopes (deuterium, oxygen-18, and carbon-13); and radioactive isotopes (tritium and carbon-14). The surficial aquifer system is the uppermost aquifer, is unconfined, relatively thin, and consists of unconsolidated sand, shell, and limestone. The intermediate aquifer system underlies the surficial aquifer system and is composed of clastic sediments interbedded with carbonate rocks. The intermediate aquifer system is divided into three permeable zones, the Tamiami/Peace River zone (PZ1), the Upper Arcadia zone (PZ2), and the Lower Arcadia zone (PZ3). The Tamiami/Peace River zone (PZ1) is the uppermost zone and is the thinnest and generally, the least productive zone in the intermediate aquifer system. The Upper Arcadia zone (PZ2) is the middle zone and productivity is generally higher than the overlying permeable zone. The Lower Arcadia zone (PZ3) is the lowermost permeable zone and is the most productive zone in the intermediate aquifer system. The intermediate aquifer system is underlain by the Upper Floridan aquifer, which consists of a thick, stratified sequence of limestone and dolomite. The Upper Floridan aquifer is the most productive aquifer in the study area; however, its use is generally restricted because of poor water quality. Interbedded clays and fine-grained clastics separate the aquifer systems and permeable zones. The hydraulic properties of the three aquifer systems are spatially variable. Estimated trans-missivity and horizontal hydraulic conductivity varies from 752 to 32,900 feet squared per day and from 33 to 1,490 feet per day, respectively, for the surficial aquifer system; from 47 to 5,420 feet squared per day and from 2 to 102 feet per day, respectively, for the Tamiami/Peace River zone (PZ1); from 258 to 24,633 feet squared per day and from 2 to 14 feet per day, respectively, for the Upper Arcadia zone (PZ2); from 766 to 44,900 feet squared per day and from 10 to 201 feet per day, respectively, for the Lower Arcadia zone (PZ3); and from 2,350 to 7,640 feet squared per day and from 10 to 41 feet per day, respectively, for the Upper Floridan aquifer. Confining units separating the aquifer systems have leakance coefficients estimated to range from 2.3 x 10-5 to 5.6 x 10-3 feet per day per foot. Strata composing the confining unit separating the Upper Floridan aquifer from the intermediate aquifer system are substantially more permeable than confining units separating the permeable zones in the intermediate aquifer system or separating the surficial aquifer and intermediate aquifer systems. In Charlotte, Sarasota, and western De Soto Counties, hydraulic

Processes of multibathyal aragonite undersaturation in the Arctic Ocean

USGS Publications Warehouse

Wynn, J.G.; Robbins, L.L.; Anderson, L.G.

2016-01-01

During 3 years of study (2010–2012), the western Arctic Ocean was found to have unique aragonite saturation profiles with up to three distinct aragonite undersaturation zones. This complexity is produced as inflow of Atlantic-derived and Pacific-derived water masses mix with Arctic-derived waters, which are further modified by physiochemical and biological processes. The shallowest aragonite undersaturation zone, from the surface to ∼30 m depth is characterized by relatively low alkalinity and other dissolved ions. Besides local influence of biological processes on aragonite undersaturation of shallow coastal waters, the nature of this zone is consistent with dilution by sea-ice melt and invasion of anthropogenic CO2 from the atmosphere. A second undersaturated zone at ∼90–220 m depth (salinity ∼31.8–35.4) occurs within the Arctic Halocline and is characterized by elevated pCO2 and nutrients. The nature of this horizon is consistent with remineralization of organic matter on shallow continental shelves bordering the Canada Basin and the input of the nutrients and CO2 entrained by currents from the Pacific Inlet. Finally, the deepest aragonite undersaturation zone is at greater than 2000 m depth and is controlled by similar processes as deep aragonite saturation horizons in the Atlantic and Pacific Oceans. The comparatively shallow depth of this deepest aragonite saturation horizon in the Arctic is maintained by relatively low temperatures, and stable chemical composition. Understanding the mechanisms controlling the distribution of these aragonite undersaturation zones, and the time scales over which they operate will be crucial to refine predictive models.

Summary of hydrologic testing of the Floridan aquifer system at Fort Stewart, Georgia

USGS Publications Warehouse

Gonthier, Gerard

2011-01-01

Flowmeter surveys at the study site indicate several permeable zones within the Floridan aquifer system. The Upper Floridan aquifer is composed of two water-bearing zones-the upper zone and the lower zone. The upper zone extends from 520 to 650 feet below land surface, contributes 96 percent of the total flow, and is more permeable than the lower zone, which extends from 650 to 705 feet below land surface and contributes the remaining 4 percent of the flow. The Lower Floridan aquifer consists of three zones at depths of 912-947, 1,090-1,139, and 1,211-1,250 feet below land surface that are inter-layered with three less-permeable zones. The Lower Floridan confining unit includes a permeable zone that extends from 793 to 822 feet below land surface. Horizontal hydraulic conductivity values of the Lower Floridan confining unit derived from slug tests within four packer-isolated intervals were from 2 to 20 feet per day, with a high value of 70 feet per day obtained for one of the intervals. Aquifer testing, using analytical techniques and model simulation, indicated the Upper Floridan aquifer had a transmissivity of about 100,000 feet squared per day, and the Lower Floridan aquifer had a transmissivity of 7,000 feet squared per day. Flowmeter surveys, slug tests within packer-isolated intervals, and parameter-estimation results indicate that the hydraulic properties of the Lower Floridan confining unit are similar to those of the Lower Floridan aquifer. Water-level data, for each aquifer test, were filtered for external influences such as barometric pressure, earth-tide effects, and long-term trends to enable detection of small water-level responses to aquifer-test pumping of less than 1 foot. During a 72-hour aquifer test of the Lower Floridan aquifer, a drawdown response of 0.3 to 0.4 foot was observed in two Upper Floridan aquifer wells, one of which was more than 1 mile away from the pumped well.

Hydrological hysteresis and its value for assessing process consistency in catchment conceptual models

NASA Astrophysics Data System (ADS)

Fovet, O.; Ruiz, L.; Hrachowitz, M.; Faucheux, M.; Gascuel-Odoux, C.

2015-01-01

While most hydrological models reproduce the general flow dynamics, they frequently fail to adequately mimic system-internal processes. In particular, the relationship between storage and discharge, which often follows annual hysteretic patterns in shallow hard-rock aquifers, is rarely considered in modelling studies. One main reason is that catchment storage is difficult to measure, and another one is that objective functions are usually based on individual variables time series (e.g. the discharge). This reduces the ability of classical procedures to assess the relevance of the conceptual hypotheses associated with models. We analysed the annual hysteric patterns observed between stream flow and water storage both in the saturated and unsaturated zones of the hillslope and the riparian zone of a headwater catchment in French Brittany (Environmental Research Observatory ERO AgrHys (ORE AgrHys)). The saturated-zone storage was estimated using distributed shallow groundwater levels and the unsaturated-zone storage using several moisture profiles. All hysteretic loops were characterized by a hysteresis index. Four conceptual models, previously calibrated and evaluated for the same catchment, were assessed with respect to their ability to reproduce the hysteretic patterns. The observed relationship between stream flow and saturated, and unsaturated storages led us to identify four hydrological periods and emphasized a clearly distinct behaviour between riparian and hillslope groundwaters. Although all the tested models were able to produce an annual hysteresis loop between discharge and both saturated and unsaturated storage, the integration of a riparian component led to overall improved hysteretic signatures, even if some misrepresentation remained. Such a system-like approach is likely to improve model selection.

75 FR 53963 - Iron Mask Hydro, LLC; Notice of Preliminary Permit Application Accepted for Filing and Soliciting...

Federal Register 2010, 2011, 2012, 2013, 2014

2010-09-02

...-long upper dam made of either zoned earth and rockfill or concrete-face earth and rockfill; (2) a 50-foot-high, 950-foot-long earth-filled upper saddle dike A; (3) a 20-foot-high, 400-foot-long earth-filled upper saddle dike B; (4) a 40-foot-high, 6,559-foot-long lower embankment made of zoned earth or...

Field project to obtain pressure core, wireline log, and production test data for evaluation of CO/sub 2/ flooding potential, Conoco MCA unit well No. 358, Maljamar Field, Lea County, New Mexico

DOE Office of Scientific and Technical Information (OSTI.GOV)

Swift, T.E.; Marlow, R.E.; Wilhelm, M.H.

1981-11-01

This report describes part of the work done to fulfill a contract awarded to Gruy Federal, Inc., by the Department of Energy (DOE) on Feburary 12, 1979. The work includes pressure-coring and associated logging and testing programs to provide data on in-situ oil saturation, porosity and permeability distribution, and other data needed for resource characterization of fields and reservoirs in which CO/sub 2/ injection might have a high probability of success. This report details the second such project. Core porosities agreed well with computed log porosities. Core water saturation and computed log porosities agree fairly well from 3692 to 3712more » feet, poorly from 3712 to 3820 feet and in a general way from 4035 to 4107 feet. Computer log analysis techniques incorporating the a, m, and n values obtained from Core Laboratories analysis did not improve the agreement of log versus core derived water saturations. However, both core and log analysis indicated the ninth zone had the highest residual hydrocarbon saturations and production data confirmed the validity of oil saturation determinations. Residual oil saturation, for the perforated and tested intervals were 259 STB/acre-ft for the interval from 4035 to 4055 feet, and 150 STB/acre-ft for the interval from 3692 to 3718 feet. Nine BOPD was produced from the interval 4035 to 4055 feet and no oil was produced from interval 3692 to 3718 feet, qualitatively confirming the relative oil saturations as calculated. The low oil production in the zone from 4022 to 4055 and the lack of production from 3692 to 3718 feet indicated the zone to be at or near residual waterflood conditions as determined by log analysis. This project demonstrates the usefulness of integrating pressure core, log, and production data to realistically evaluate a reservoir for carbon dioxide flood.« less

Assessing geotechnical centrifuge modelling in addressing variably saturated flow in soil and fractured rock.

PubMed

Jones, Brendon R; Brouwers, Luke B; Van Tonder, Warren D; Dippenaar, Matthys A

2017-05-01

The vadose zone typically comprises soil underlain by fractured rock. Often, surface water and groundwater parameters are readily available, but variably saturated flow through soil and rock are oversimplified or estimated as input for hydrological models. In this paper, a series of geotechnical centrifuge experiments are conducted to contribute to the knowledge gaps in: (i) variably saturated flow and dispersion in soil and (ii) variably saturated flow in discrete vertical and horizontal fractures. Findings from the research show that the hydraulic gradient, and not the hydraulic conductivity, is scaled for seepage flow in the geotechnical centrifuge. Furthermore, geotechnical centrifuge modelling has been proven as a viable experimental tool for the modelling of hydrodynamic dispersion as well as the replication of similar flow mechanisms for unsaturated fracture flow, as previously observed in literature. Despite the imminent challenges of modelling variable saturation in the vadose zone, the geotechnical centrifuge offers a powerful experimental tool to physically model and observe variably saturated flow. This can be used to give valuable insight into mechanisms associated with solid-fluid interaction problems under these conditions. Findings from future research can be used to validate current numerical modelling techniques and address the subsequent influence on aquifer recharge and vulnerability, contaminant transport, waste disposal, dam construction, slope stability and seepage into subsurface excavations.

Determination of water saturation using gas phase partitioning tracers and time-lapse electrical conductivity measurements

DOE Office of Scientific and Technical Information (OSTI.GOV)

Johnson, Timothy C.; Oostrom, Martinus; Truex, Michael J.

2013-05-21

Water saturation is an important indicator of contaminant distribution and plays a governing role in contaminant transport within the vadose zone. Understanding the water saturation distribution is critical for both remediation and contaminant flux monitoring in unsaturated environments. In this work we propose and demonstrate a method of remotely determining water saturation levels using gas phase partitioning tracers and time-lapse bulk electrical conductivity measurements. The theoretical development includes the partitioning chemistry for the tracers we demonstrate (ammonia and carbon dioxide), as well as a review of the petrophysical relationship governing how these tracers influence bulk conductivity. We also investigate methodsmore » of utilizing secondary information provided by electrical conductivity breakthrough magnitudes induced by the tracers. We test the method on clean, well characterized, intermediate-scale sand columns under controlled conditions. Results demonstrate the capability to predict partitioning coefficients and accurately monitor gas breakthrough curves along the length of the column according to the corresponding electrical conductivity response, leading to accurate water saturation estimates. This work is motivated by the need to develop effective characterization and monitoring techniques for contaminated deep vadose zone environments, and provides a proof-of-concept toward uniquely characterizing and monitoring water saturation levels at the field scale and in three-dimensions using electrical resistivity tomography.« less

A porewater - based stable isotope approach for the investigation of subsurface hydrological processes

NASA Astrophysics Data System (ADS)

Garvelmann, J.; Külls, C.; Weiler, M.

2011-10-01

Predicting and understanding subsurface flowpaths is still a crucial issue in hydrological research. We present an experimental approach to reveal present and past subsurface flowpaths of water in the unsaturated and saturated zone. Two hillslopes in a humid moutainous catchment have been investigated. The H2O(liquid) - H2O(vapor) equilibration laser spectroscopy method was used to obtain high resolution δ2H vertical depth profiles of porewater at various points along a fall line of a pasture hillslope in the southern Black Forest, Germany. The Porewater Stable Isotope Profile (PSIP) approach was developed to use the integrated information of several vertical depth profiles of deuterium along two transects at the hillslopes. Different shapes of depth profiles were observed in relation to hillslope position. The statistical variability (inter-quartile range and standard deviation) of each profile was used to characterize different types of depth profiles. The profiles upslope or with a weak affinity for saturation as indicated by a low topographic wetness index preserve the isotopic input signal by precipitation with a distinct seasonal variability. These observations indicate mainly vertical movement of soil water in the upper part of the hillslope before sampling. The profiles downslope or at locations with a strong affinity for saturation do not show a similar seasonal isotopic signal. The input signal is erased in the foothills and a large proportion of pore water samples are close to the isotopic values of δ2H in stream water during base flow. Near the stream indications for efficient mixing of water from lateral subsurface flow paths with vertical percolation are found.

Pore- and fracture-filling gas hydrate reservoirs in the Gulf of Mexico Gas Hydrate Joint Industry Project Leg II Green Canyon 955 H well

USGS Publications Warehouse

Lee, M.W.; Collett, T.S.

2012-01-01

High-quality logging-while-drilling (LWD) downhole logs were acquired in seven wells drilled during the Gulf of MexicoGasHydrateJointIndustryProjectLegII in the spring of 2009. Well logs obtained in one of the wells, the GreenCanyon Block 955Hwell (GC955-H), indicate that a 27.4-m thick zone at the depth of 428 m below sea floor (mbsf; 1404 feet below sea floor (fbsf)) contains gashydrate within sand with average gashydrate saturations estimated at 60% from the compressional-wave (P-wave) velocity and 65% (locally more than 80%) from resistivity logs if the gashydrate is assumed to be uniformly distributed in this mostly sand-rich section. Similar analysis, however, of log data from a shallow clay-rich interval between 183 and 366 mbsf (600 and 1200 fbsf) yielded average gashydrate saturations of about 20% from the resistivity log (locally 50-60%) and negligible amounts of gashydrate from the P-wave velocity logs. Differences in saturations estimated between resistivity and P-wave velocities within the upper clay-rich interval are caused by the nature of the gashydrate occurrences. In the case of the shallow clay-rich interval, gashydrate fills vertical (or high angle) fractures in rather than fillingpore space in sands. In this study, isotropic and anisotropic resistivity and velocity models are used to analyze the occurrence of gashydrate within both the clay-rich and sand dominated gas-hydrate-bearing reservoirs in the GC955-Hwell.

Upper Cretaceous planktonic stratigraphy of the Göynük composite section, western Tethys (Bolu province, Turkey)

NASA Astrophysics Data System (ADS)

Wolfgring, Erik; Liu, Shasha; Wagreich, Michael; Böhm, Katharina; Omer Yilmaz, Ismail

2017-04-01

Upper Cretaceous strata exposed at Göynük (Mudurnu-Göynük basin, Bolu Province, Northwestern Anatolia, Turkey) provide a composite geological record from the Upper Santonian to the Maastrichtian. Deposits in this area originate from the Sakarya continent, therefore, a western Tethyan palaeogeographic setting with a palaeolatitude of a bit less than 30 degrees north can be reconstructed. Grey shales and clayey marls are exposed at Göynük and do frequently show volcanic intercalations in the oldest parts of the section, while the uppermost layers depict a more complete deeper-marine record. The pelagic palaeoenvironment, microfossil indicators point towards a distal slope setting, at the Göynük section comprises rich low-latitude planktonic foraminiferal and calcareous nannoplankton assemblages. Benthic foraminifera are scarce, however, some biostratigraphically indicative taxa were recovered. The three sections sampled for this study reveal a composite record from the Campanian Contusotruncana plummerae planktonic foraminifera Zone to the Maastrichtian Racemiguembelina fruticosa planktonic foraminifera Zone. The oldest sub section („GK-section") yields the „mid" Campanian Contusotruncana plummerae or Globotruncana ventricosa Zones and is followed by the „GC-section". The oldest strata in latter record the C. plummerae Zone, the Radotruncana calcarata Zone, Globotruncanita havanensis as well as the Globotruncana aegyptiaca Zone and are overlain by the youngest section examined in this study ("GS -section"). In the latter, we recognize the G. aegyptiaca Zone in the lowermost part, the upper Campanian/lower Maastrichtian Gansserina gansseri Zone, and the Maastrichtian Racemiguembelina fruticosa Zone. Nannofossil standard zones UC15b to UC18 are recorded within the composite section. The planktonic foraminiferal assemblages assessed in the Göynük area feature a well preserved, diverse plankton record that can be correlated to other western Tethyan sections from the Upper Cretaceous. Especially the Austrian Alpine sections (i.e. Northern Calcareous Alps and Ultrahelvetics) show similar environmental and palaeolatitudinal settings and feature a well established biostratigraphical and cyclostratigraphic record. Comparing the multi-proxy record assessed in these sections to the biostratigraphic data from the Göynük region provides useful insights into planktonic foraminiferal palaeoecology and the multistratigraphic high-resolution correlation in the Upper Cretaceous Tethyan realm.

Paleontology and physical stratigraphy of the USGS-Pregnall No. 1 core (DOR-208), Dorchester County, South Carolina

USGS Publications Warehouse

Edwards, L.E.; Bybell, L.M.; Gohn, G.S.; Frederiksen, N.O.

1997-01-01

Pregnall No. 1, a 346-ft-deep corehole in northern Dorchester County, South Carolina, recovered sediments of late Paleocene, middle and late Eocene, and late Oligocene age. The core bottomed in the Chicora Member of the Williamsburg Formation (Black Mingo Group) of late Paleocene age (calcareous nannofossil Zones NP 7/8 (?) and NP 9). The Chicora (346 to 258 ft depth) consists of two contrasting lithologic units, a lower siliciclastic section of terrigenous sand, silt, and clay, and an upper carbonate section of moldic pelecypod limestone. The Chicora is overlain unconformably by the middle Eocene Moultrie Member of the Santee Limestone (Orangeburg Group). The Moultrie (258.0 to 189.4 ft) consists primarily of bryozoan-pelecypod-peloid packstones and grainstones, which are assigned to calcareous nannofossil Zone NP 16. Unconformably above the Moultrie are the locally shelly, microfossiliferous limestones of the Cross Member of the Santee Limestone (Orangeburg Group), which are assigned to middle Eocene Zone NP 17 and upper Eocene Zone NP 18. The Cross Member (189.4 to 90.9 ft) is unconformably overlain by a very thin, basal section of the upper Eocene Harleyville Formation (Cooper Group). The thin Harleyville section consists of fossiliferous limestone, primarily pelecypod-foraminifer-peloid packstones (90.9 to 85.8 ft), and is assigned to Zone NP 18, although samples from thicker Harleyville sections in the region typically are assigned to upper Eocene Zone NP 19/20. The Harleyville is overlain unconformably by the upper Oligocene Ashley Formation (Cooper Group). The Ashley Formation (85.8 to 30.0 ft) consists of a relatively homogeneous section of calcareous, microfossiliferous, silty and sandy clays assigned to Zones NP 24 and NP 25 (?). Neogene and (or) Quaternary deposits present in the upper 30 ft of the Pregnall section are assigned provisionally to an unnamed unit (30 to 22 ft) and to the Waccamaw Formation(?)(22 to 0 ft).

Enhancement of the complete autotrophic nitrogen removal over nitrite process in a modified single-stage subsurface vertical flow constructed wetland: Effect of saturated zone depth.

PubMed

Huang, Menglu; Wang, Zhen; Qi, Ran

2017-06-01

This study was conducted to explore enhancement of the complete autotrophic nitrogen removal over nitrite (CANON) process in a modified single-stage subsurface vertical flow constructed wetland (VSSF) with saturated zone, and nitrogen transformation pathways in the VSSF treating digested swine wastewater were investigated at four different saturated zone depths (SZDs). SZD significantly affected nitrogen transformation pathways in the VSSF throughout the experiment. As the SZD was 45cm, the CANON process was enhanced most effectively in the system owing to the notable enhancement of anammox. Correspondingly, the VSSF had the best TN removal performance [(76.74±7.30)%] and lower N 2 O emission flux [(3.50±0.22)mg·(m 2 ·h) - 1 ]. It could be concluded that autotrophic nitrogen removal via CANON process could become a primary route for nitrogen removal in the VSSF with optimized microenvironment that developed as a result of the appropriate SZD. Copyright © 2017 Elsevier Ltd. All rights reserved.

Chloride Concentration in Water from the Upper Permeable Zone of the Tertiary Limestone Aquifer System, Southeastern United States

USGS Publications Warehouse

Sprinkle, Craig L.

1982-01-01

INTRODUCTION The tertiary limestone aquifer system of the southeastern United States is a sequence of carbonate rocks referred to as the Floridan aquifer in Florida and the principal artesian aquifer in Georgia, Alabama, and South Carolina. More than 3 billion gallons of water are pumped daily from the limestone aquifer; and the system is the principal source of municipal, industrial, and agricultural water supply in south Georgia and most of Florida. The aquifer system includes units of Paleocene to early Miocene age that combine to form a continuous carbonate sequence that is hydraulically connected in varying degrees. In a small area near Brunswick, Ga., a thin sequence of rocks of Late Cretaceous age is part of the system. In and directly downdip from much of the outcrop area, the system consists of one continuous permeable unit. Further downdip the aquifer system generally consists of two major permeable zones separated by a less-permeable unit of highly variable hydraulic properties (very leaky to virtually nonleaky). Conditions for the system vary from unconfined to confined depending upon whether the argillaceous Miocene and younger rocks that form the upper confining unit have been removed by erosion. This report is one of a series of preliminary products depicting the hydrogeologic framework, water chemistry, and hydrology of the aquifer system. The map shows the distribution of chloride ions in water from the upper permeable zone of the limestone aquifer system. The upper permeable zone consists of several formations, primarily the Tampa, Suwannee, Ocala, and Avon Park Limestones (Miller 1981a, b). Chloride concentrations of water within the upper permeable zone vary from nearly zero in recharge areas to many thousands of milligrams per liter (mg/L) in coastal discharge areas. Where the aquifer system discharges into the sea, the upper permeable zone contains increasing amounts of seawater. In these areas, wells that fully penetrate the upper permeable zone will yield water with chloride concentrations that approach that of seawater, about 19500 mg/L.

High-resolution monitoring across the soil-groundwater interface - Revealing small-scale hydrochemical patterns with a novel multi-level well

NASA Astrophysics Data System (ADS)

Gassen, Niklas; Griebler, Christian; Stumpp, Christine

2016-04-01

Biogeochemical turnover processes in the subsurface are highly variable both in time and space. In order to capture this variability, high resolution monitoring systems are required. Particular in riparian zones the understanding of small-scale biogeochemical processes is of interest, as they are regarded as important buffer zones for nutrients and contaminants with high turnover rates. To date, riparian research has focused on influences of groundwater-surface water interactions on element cycling, but little is known about processes occurring at the interface between the saturated and the unsaturated zone during dynamic flow conditions. Therefore, we developed a new type of high resolution multi-level well (HR-MLW) that has been installed in the riparian zone of the Selke river. This HR-MLW for the first time enables to derive water samples both from the unsaturated and the saturated zone across one vertical profile with a spatial vertical resolution of 0.05 to 0.5 m to a depth of 4 m b.l.s. Water samples from the unsaturated zone are extracted via suction cup sampling. Samples from the saturated zone are withdrawn through glass filters and steel capillaries. Both, ceramic cups and glass filters, are installed along a 1" HDPE piezometer tube. First high resolution hydrochemical profiles revealed a distinct depth-zonation in the riparian alluvial aquifer. A shallow zone beneath the water table carried a signature isotopically and hydrochemically similar to the nearby river, while layers below 1.5 m were influenced by regional groundwater. This zonation showed temporal dynamics related to groundwater table fluctuations and microbial turnover processes. The HR-MLW delivered new insight into mixing and turnover processes between riverwater and groundwater in riparian zones, both in a temporal and spatial dimension. With these new insights, we are able to improve our understanding of dynamic turnover processes at the soil - groundwater interface and of surface -groundwater interactions in riparian zones. In the future, a better prediction and targeted management of buffer mechanisms in riparian zones will be possible.

Modeling: The Right Tool for the Job.

ERIC Educational Resources Information Center

Gavanasen, Varut; Hussain, S. Tariq

1993-01-01

Reviews the different types of models that can be used in groundwater modeling. Discusses the flow and contaminant transport models in the saturated zone, flow and contaminant transport in variably saturated flow regime, vapor transport, biotransformation models, multiphase models, optimization algorithms, and potentials pitfalls of using these…

Soil Systems for Upscaling Saturated Hydraulic Conductivity (Ksat) for Hydrological Modeling in the Critical Zone

USDA-ARS?s Scientific Manuscript database

Successful hydrological model predictions depend on appropriate framing of scale and the spatial-temporal accuracy of input parameters describing soil hydraulic properties. Saturated soil hydraulic conductivity (Ksat) is one of the most important properties influencing water movement through soil un...

Hydrologic and Biogeochemical Connections between Uplands and Streams in Contrasting Landscapes

NASA Astrophysics Data System (ADS)

Shanley, J. B.; Webb, R. M.; Hjerdt, K. N.; Sebestyen, S. D.; Peters, N. E.; Burns, D. A.; Aulenbach, B. T.; Campbell, D. H.; Clow, D. W.; Mast, M. A.; Walker, J. F.; Hunt, R. J.; Troester, J. W.; Larsen, M. C.

2004-12-01

We used combinations of hydrometric, chemical, and isotopic evidence to evaluate linkages between upland and riparian zones at the 5 small watersheds of the U.S. Geological Survey Water Energy and Biogeochemical Budget (WEBB) program. These sites span a broad range of climate and topography. At Sleepers River, Vermont, snowmelt induced the water table on hillslopes to rise into the highly transmissive upper soil. The close timing of the groundwater and stream hydrographs suggests a large contribution of hillslope water to the stream. However, the chemistry of these upland groundwaters indicates that only limited areas of convergent groundwater flow directly contribute to streamflow. At Panola Mountain, Georgia, a thin saturated zone develops on the hillslope during large rainstorms. This hillslope groundwater is chemically distinct from riparian groundwater, and transits the riparian zone near land surface with little mixing. Based on chemical mixing analysis, the hillslope contributes up to 30% of the streamwater during moderate to large-sized rainstorms. The Trout Lake site in Wisconsin is a low-lying landscape in highly conductive sandy glacial outwash.Hillslope water chemistry is considerably more dilute (i.e. less evolved) than the regional groundwater that supplies baseflow. The lack of chemical response in streamwater during storms suggests that hillslope water makes a minimal contribution relative to regional groundwater flow. In the alpine/subalpine watershed of Loch Vale, Colorado, much of the subsurface flow occurs on steep slopes of talus. Water in the talus flow has a wide range of residence times. The talus deposits are biogeochemically active and play an important role in maintaining summer baseflow, regulating seasonal changes in streamwater chemistry, and exporting nitrogen from atmospheric deposition. The tropical Icacos watershed in the Luquillo mountains of Puerto Rico receives 4 meters of rainfall annually and has high physical and chemical weathering rates. Streamwater chemistry during baseflow is strongly controlled by groundwater interaction with weathered bedrock. Most hillslope runoff occurs through near-surface macropores with limited soil interaction. This source dominates during storms resulting in stream chemistry that resembles that of the extremely dilute precipitation.We will compare these field observations at each site with the aid of TOPMODEL-based simulation of residence times and observed water quality on the hillslope and riparian saturated zones.

Silurian and Devonian in Vietnam—Stratigraphy and facies

NASA Astrophysics Data System (ADS)

Thanh, Tống Duy; Phương, Tạ Hoàng; Janvier, Philippe; Hùng, Nguyễn Hữu; Cúc, Nguyễn Thị Thu; Dương, Nguyễn Thùy

2013-09-01

Silurian and Devonian deposits in Viet Nam are present in several zones and regions, including Quang Ninh, East Bac Bo, and West Bac Bo Zones of the Bac Bo Region, the Dien Bien-Nghe An and Binh Tri Thien Zones of the Viet-Lao Region, and the South Trung Bo, and Western Nam Bo Zones of the South Viet Nam Region (Fig. 1). The main lithological features and faunal composition of the Silurian and Devonian Units in all these zones are briefly described. The Silurian consists of deep-water deposits of the upper parts of the Co To and Tan Mai Formations in the Quang Ninh Zone, the upper parts of the Phu Ngu Formation in the East Bac Bo Zone and the upper parts of the Long Dai and Song Ca Formations in the Viet-Lao Region. Shallow water facies Silurian units containing benthic faunas are more widely distributed, including the upper part of the Sinh Vinh and Bo Hieng Formations in the West Bac Bo Zone, the Kien An Formation in the Quang Ninh Zone, and, in the Viet-Lao Region, the Dai Giang Formation and the upper part of the Tay Trang Formation. No Lower and Middle Devonian deposits indicate deep water facies, but they are characterized by different shallow water facies. Continental to near shore, deltaic facies characterize the Lower Devonian Song Cau Group in the East Bac Bo Zone, the Van Canh Formation in the Quang Ninh Zone, and the A Choc Formation in the Binh Tri Thien Zone. Similar facies also occur in the Givetian Do Son Formation of the Quang Ninh Zone, and the Tan Lap Formation in the East Bac Bo Zone, and consist of coarse terrigenous deposits—cross-bedded conglomerates, sandstone, etc. Most Devonian units are characterized by shallow marine shelf facies. Carbonate and terrigenous-carbonate facies dominate, and terrigenous facies occur in the Lower and Middle Devonian sections in some areas only. The deep-water-like facies is characteriztic for some Upper Devonian formations in the Bac Bo (Bang Ca and Toc Tat Formations) and Viet-Lao Regions (Thien Nhan and Xom Nha Formations). These formations contain cherty shale or siliceous limestone, and fossils consist of conodonts, but there are also brachiopods and other benthos. They were possibly deposited in a deep water environment on the slope of the continental shelf. Most Devonian units distributed in the North and the Central Viet Nam consist of self shallow water sediments, and apparently they were deposited in a passive marginal marine environment. The coarse clastic continental or subcontinental deposits are distributed only in some areas of the East Bac Bo and of the Quang Ninh zones of the Bac Bo Region, and in the south of the Binh Tri Thien Zone. This situation suggests the influence of the Caledonian movement at the end of the Silurian period that called the Guangxi movement in South China.

Perfusion Scintigraphy and Patient Selection for Lung Volume Reduction Surgery

PubMed Central

Chandra, Divay; Lipson, David A.; Hoffman, Eric A.; Hansen-Flaschen, John; Sciurba, Frank C.; DeCamp, Malcolm M.; Reilly, John J.; Washko, George R.

2010-01-01

Rationale: It is unclear if lung perfusion can predict response to lung volume reduction surgery (LVRS). Objectives: To study the role of perfusion scintigraphy in patient selection for LVRS. Methods: We performed an intention-to-treat analysis of 1,045 of 1,218 patients enrolled in the National Emphysema Treatment Trial who were non–high risk for LVRS and had complete perfusion scintigraphy results at baseline. The median follow-up was 6.0 years. Patients were classified as having upper or non–upper lobe–predominant emphysema on visual examination of the chest computed tomography and high or low exercise capacity on cardiopulmonary exercise testing at baseline. Low upper zone perfusion was defined as less than 20% of total lung perfusion distributed to the upper third of both lungs as measured on perfusion scintigraphy. Measurements and Main Results: Among 284 of 1,045 patients with upper lobe–predominant emphysema and low exercise capacity at baseline, the 202 with low upper zone perfusion had lower mortality with LVRS versus medical management (risk ratio [RR], 0.56; P = 0.008) unlike the remaining 82 with high perfusion where mortality was unchanged (RR, 0.97; P = 0.62). Similarly, among 404 of 1,045 patients with upper lobe–predominant emphysema and high exercise capacity, the 278 with low upper zone perfusion had lower mortality with LVRS (RR, 0.70; P = 0.02) unlike the remaining 126 with high perfusion (RR, 1.05; P = 1.00). Among the 357 patients with non–upper lobe–predominant emphysema (75 with low and 282 with high exercise capacity) there was no improvement in survival with LVRS and measurement of upper zone perfusion did not contribute new prognostic information. Conclusions: Compared with optimal medical management, LVRS reduces mortality in patients with upper lobe–predominant emphysema when there is low rather than high perfusion to the upper lung. PMID:20538961

Lithostratigraphy, biostratigraphy and chemostratigraphy of Upper Cretaceous sediments from southern Tanzania: Tanzania drilling project sites 21-26

NASA Astrophysics Data System (ADS)

Jiménez Berrocoso, Álvaro; MacLeod, Kenneth G.; Huber, Brian T.; Lees, Jacqueline A.; Wendler, Ines; Bown, Paul R.; Mweneinda, Amina K.; Isaza Londoño, Carolina; Singano, Joyce M.

2010-04-01

The 2007 drilling season by the Tanzania drilling project (TDP) reveals a much more expanded Upper Cretaceous sequence than was recognized previously in the Lindi region of southern Tanzania. This TDP expedition targeted recovery of excellently preserved microfossils (foraminifera and calcareous nannofossils) for Late Cretaceous paleoclimatic, paleoceanographic and biostratigraphic studies. A total of 501.17 m of core was drilled at six Upper Cretaceous sites (TDP Sites 21, 22, 23, 24, 24B and 26) and a thin Miocene-Pleistocene section (TDP Site 25). Microfossil preservation at all these sites is good to excellent, with foraminifera often showing glassy shells and consistently good preservation of small and delicate nannofossil taxa. In addition to adding to our knowledge of the subsurface geology, new surface exposures were mapped and the geological map of the region is revised herein. TDP Sites 24, 24B and 26 collectively span the upper Albian to lower-middle Turonian (planktonic foraminiferal Planomalina buxtorfi- Whiteinella archaeocretacea Zones and calcareous nannofossil zones UC0a-UC8a). The bottom of TDP Site 21 is barren, but the rest of the section represents the uppermost Cenomanian-Coniacian ( W. archaeocretacea- Dicarinella concavata Zones and nannofossil zones UC5c-UC10). Bulk organic δ 13C data suggest recovery of part of Ocean Anoxic Event 2 (OAE2) from these four sites. In the upper part of this interval, the lower Turonian nannofossil zones UC6a-7 are characterized by a low-diversity nannoflora that may be related to OAE2 surface-water conditions. TDP Site 22 presents a 122-m-thick, lower-middle Turonian ( W. archaeocretacea- Helvetoglobotruncana helvetica Zones) sequence that includes the nannofossil zones UC6a(-7?), but invariable isotopic curves. Further, a lower to upper Campanian ( Globotruncana ventricosa- Radotruncana calcarata Zones and nannofossil subzones UC15b TP-UC15d TP) succession was drilled at TDP Site 23. Lithologies of the new sites include thin units of gray, medium to coarse sandstones, separating much thicker intervals of dark claystones with organic-rich laminated parts, irregular silty to fine sandstone partings, and rare inoceramid and ammonite debris. These lithofacies are interpreted to have been deposited in outer shelf and upper slope settings and indicate relatively stable sedimentary conditions during most of the Late Cretaceous on the Tanzanian margin.

The temperature dependence of ponded infiltration under isothermal conditions

USGS Publications Warehouse

Constantz, J.; Murphy, F.

1991-01-01

A simple temperature-sensitive modification to the Green and Ampt infiltration equation is described; this assumes that the temperature dependence of the hydraulic conductivity is reciprocally equal to the temperature dependence of the viscosity of liquid water, and that both the transmission zone saturation and the wetting front matric potential gradient are independent of temperature. This modified Green and Ampt equation is compared with ponded, isothermal infiltration experiments run on repacked columns of Olympic Sand and Aiken Loam at 5, 25, and 60??C. Experimental results showed increases in infiltration rates of at least 300% between 5 and 60??C for both soil materials, with subsequent increases in cumulative infiltration of even greater magnitudes for the loam. There is good agreement between measured and predicted initial infiltration rates at 25??C for both soil materials, yet at 60??C, the predicted results overestimate initial infiltration rates for the sand and underestimate initial rates for the loam. Measurements of the wetting depth vs. cumulative infiltration indicate that the transmission zone saturation increased with increasing temperature for both soil materials. In spite of this increased saturation with temperature, the final infiltration rates at both 25 and 60??C were predicted accurately using the modified Green and Ampt equation. This suggests that increased saturation occurred primarily in dead-end pore spaces, so that transmission zone hydraulic conductivities were unaffected by these temperature-induced changes in saturation. In conclusion, except for initial infiltration rates at 60??C, the measured influence of temperature on infiltration rates was fully accounted for by the temperature dependence of the viscosity of liquid water. ?? 1991.

Porosity determination from 2-D resistivity method in studying the slope failures

NASA Astrophysics Data System (ADS)

Maslinda, Umi; Nordiana, M. M.; Bery, A. A.

2017-07-01

Slope failures have become the main focus for infrastructures development on hilly areas in Malaysia especially the development of tourism and residential. Lack of understanding and information of the subsoil conditions and geotechnical issues are the main cause of the slope failures. The failures happened are due to a combination of few factors such as topography, climate, geology and land use. 2-D resistivity method was conducted at the collapsed area in Selangor. The 2-D resistivity was done to study the instability of the area. The collapsed occurred because of the subsurface materials was unstable. Pole-dipole array was used with 5 m minimum electrode spacing for the 2-D resistivity method. The data was processed using Res2Dinv software and the porosity was calculated using Archie's law equation. The results show that the saturated zone (1-100 Ωm), alluvium or highly weathered rock (100-1000 Ωm), boulders (1600-7000 Ωm) and granitic bedrock (>7000 Ωm). Generally, the slope failures or landslides occur during the wet season or after rainfall. It is because of the water infiltrate to the slope and cause the saturation of the slope which can lead to landslides. Then, the porosity of saturated zone is usually high because of the water content. The area of alluvium or highly weathered rock and saturated zone have high porosity (>20%) and the high porosity also dominated at almost all the collapsed area which means that the materials with porosity >20% is potential to be saturated, unstable and might trigger slope failures.

Hydrogeology and the distribution of salinity in the Floridan aquifer system, Palm Beach County, Florida

USGS Publications Warehouse

Reese, R.S.; Memberg, S.J.

2000-01-01

The virtually untapped Floridan aquifer system is considered to be a supplemental source of water for public use in the highly populated coastal area of Palm Beach County. A recent study was conducted to delineate the distribution of salinity in relation to the local hydrogeology and assess the potential processes that might control (or have affected) the distribution of salinity in the Floridan aquifer system. The Floridan aquifer system in the study area consists of the Upper Floridan aquifer, middle confining unit, and Lower Floridan aquifer and ranges in age from Paleocene to Oligocene. Included at its top is part of a lowermost Hawthorn Group unit referred to as the basal Hawthorn unit. The thickness of this basal unit is variable, ranging from about 30 to 355 feet; areas where this unit is thick were paleotopographic lows during deposition of the unit. The uppermost permeable zones in the Upper Floridan aquifer occur in close association with an unconformity at the base of the Hawthorn Group; however, the highest of these zones can be up in the basal unit. A dolomite unit of Eocene age generally marks the top of the Lower Floridan aquifer, but the top of this dolomite unit has a considerable altitude range: from about 1,200 to 2,300 feet below sea level. Additionally, where the dolomite unit is thick, its top is high and the middle confining unit of the Floridan aquifer system, as normally defined, probably is not present. An upper zone of brackish water and a lower zone of water with salinity similar to that of seawater (saline-water zone) are present in the Floridan aquifer system. The brackish-water and saline-water zones are separated by a transition zone (typically 100 to 200 feet thick) in which salinity rapidly increases with depth. The transition zone was defined by using a salinity of 10,000 mg/L (milligrams per liter) of dissolved-solids concentration (about 5,240 mg/L of chloride concentration) at its top and 35,000 mg/L of dissolved-solids concentration (about 18,900 mg/L of chloride concentration) at its base. The base of the brackish-water zone and the top of the saline-water zone were approximately determined mostly by means of resistivity geophysical logs. The base of the brackish-water zone in the study area ranges from about 1,600 feet below sea level near the coast to almost 2,200 feet below sea level in extreme southwestern Palm Beach County. In an area that is peripheral to Lake Okeechobee, the boundary unexpectedly rises to perhaps as shallow as 1,800 feet below sea level. In an upper interval of the brackish-water zone within the Upper Floridan aquifer, chloride concentration of water ranges from 490 to 8,000 mg/L. Chloride concentration correlates with the altitude of the basal contact of the Hawthorn Group, with concentration increasing as the altitude of this contact decreases. Several areas of anomalous salinity where chloride concentration in this upper interval is greater than 3,000 mg/L occur near the coast. In most of these areas, salinity was found to decrease with depth from the upper interval to a lower interval within the brackish-water zone: a reversal of the normal salinity trend within the zone. These areas are also characterized by an anomalously low altitude of the base of the brackish-water zone, and a much greater thickness of the transition zone than normal. These anomalies could be the result of seawater preferentially invading zones of higher permeability in the Upper Floridan aquifer during Pleistocene high stands of sea level and incomplete flushing of this high salinity water by the present-day flow system.

Seismic Tomography of the Arabian-Eurasian Collision Zone and Surrounding Areas

DTIC Science & Technology

2010-05-20

zone. The crustal models correlate well with geologic and tectonic features. The upper mantle tomograms show the images of the subducted Neotethys...We first obtain Pn and Sn velocities using local and regional arrival time data. Second, we obtain the 3-D crustal P and S velocity models...teleseismic tomography provides a high-resolution, 3-D P-wave velocity model for the crust, upper mantle, and the transition zone. The crustal models

SAGUARO: a finite-element computer program for partially saturated porous flow problems

DOE Office of Scientific and Technical Information (OSTI.GOV)

Eaton, R.R.; Gartling, D.K.; Larson, D.E.

1983-06-01

SAGUARO is a finite element computer program designed to calculate two-dimensional flow of mass and energy through porous media. The media may be saturated or partially saturated. SAGUARO solves the parabolic time-dependent mass transport equation which accounts for the presence of partially saturated zones through the use of highly non-linear material characteristic curves. The energy equation accounts for the possibility of partially saturated regions by adjusting the thermal capacitances and thermal conductivities according to the volume fraction of water present in the local pores. Program capabilities, user instructions and a sample problem are presented in this manual.

Identifying riparian zones appropriate for installation of saturated buffers: A multi-watershed assessment

USDA-ARS?s Scientific Manuscript database

Saturated riparian buffers are a new type of conservation practice that divert a portion of subsurface tile drainage from discharge to surface water into distribution pipes that discharge tile water into riparian soils. This enables natural processes of biological uptake and denitrification to decre...

Sample dimensions effect on prediction of soil water retention curve and saturated hydraulic conductivity

USDA-ARS?s Scientific Manuscript database

Soil water retention curve (SWRC) and saturated hydraulic conductivity (SHC) are key hydraulic properties for unsaturated zone hydrology and groundwater. Not only are the SWRC and SHC measurements time-consuming, their results are scale dependent. Although prediction of the SWRC and SHC from availab...

Pilot-scale vadose zone microbial biobarriers removed nitrate leaching from a cattle corral

USDA-ARS?s Scientific Manuscript database

activities that involve animal wastes can result in the contamination of subsurface soils by nitrates. In saturated or nearly saturated soils microbial biobarriers are a common method used to remove contaminants from water. This field study was conducted beneath a cattle pen in northeast Colorado a...

A Numerical Investigation of Metabolic Reductive Dechlorination in DNAPL Source Zones

DTIC Science & Technology

2005-01-01

APPENDICES ..................................................................................... 249 APPENDIX A UTCHEM VALIDATION...using UTCHEM ............................................................... 82 Table IV.2: Statistics for saturation distribution metrics in 2-D and...Saturation profiles simulated in (a) 2D using UTCHEM and (b) in the same 2D slice extracted from a 3D UTCHEM simulation

Brittle deformation during Alpine basal accretion and the origin of seismicity nests above the subduction interface

NASA Astrophysics Data System (ADS)

Menant, Armel; Angiboust, Samuel; Monié, Patrick; Oncken, Onno; Guigner, Jean-Michel

2018-04-01

Geophysical observations on active subduction zones have evidenced high seismicity clusters at 20-40 km depth in the fore-arc region whose origin remains controversial. We report here field observations of pervasive pseudotachylyte networks (interpreted as evidence for paleo-seismicity) in the now-exhumed Valpelline continental unit (Dent Blanche complex, NW. Alps, Italy), a tectonic sliver accreted to the upper plate at c. 30 km depth during the Paleocene Alpine subduction. Pre-alpine granulite-facies paragneiss from the core of the Valpelline unit are crosscut by widespread, mm to cm-thick pseudotachylyte veins. Co-seismic heating and subsequent cooling led to the formation of Ti-rich garnet rims, ilmenite needles, Ca-rich plagioclase, biotite microliths and hercynite micro-crystals. 39Ar-40Ar dating yields a 51-54 Ma age range for these veins, thus suggesting that frictional melting events occurred near peak burial conditions while the Valpelline unit was already inserted inside the duplex structure. In contrast, the base of the Valpelline unit underwent synchronous ductile and brittle, seismic deformation under water-bearing conditions followed by a re-equilibration at c. 40 Ma (39Ar-40Ar on retrograded pseudotachylyte veins) during exhumation-related deformation. Calculated rheological profiles suggest that pseudotachylyte veins from the dry core of the granulite unit record upper plate micro-seismicity (Mw 2-3) formed under very high differential stresses (>500 MPa) while the sheared base of the unit underwent repeated brittle-ductile deformation at much lower differential stresses (<40 MPa) in a fluid-saturated environment. These results demonstrate that some of the seismicity clusters nested along and above the plate interface may reflect the presence of stiff tectonic slivers rheologically analogous to the Valpelline unit acting as repeatedly breaking asperities in the basal accretion region of active subduction zones.

Oxygen distribution and aerobic respiration in the north and south eastern tropical Pacific oxygen minimum zones

NASA Astrophysics Data System (ADS)

Tiano, Laura; Garcia-Robledo, Emilio; Dalsgaard, Tage; Devol, Allan H.; Ward, Bess B.; Ulloa, Osvaldo; Canfield, Donald E.; Peter Revsbech, Niels

2014-12-01

Highly sensitive STOX O2 sensors were used for determination of in situ O2 distribution in the eastern tropical north and south Pacific oxygen minimum zones (ETN/SP OMZs), as well as for laboratory determination of O2 uptake rates of water masses at various depths within these OMZs. Oxygen was generally below the detection limit (few nmol L-1) in the core of both OMZs, suggesting the presence of vast volumes of functionally anoxic waters in the eastern Pacific Ocean. Oxygen was often not detectable in the deep secondary chlorophyll maximum found at some locations, but other secondary maxima contained up to 0.4 μmol L-1. Directly measured respiration rates were high in surface and subsurface oxic layers of the coastal waters, reaching values up to 85 nmol L-1 O2 h-1. Substantially lower values were found at the depths of the upper oxycline, where values varied from 2 to 33 nmol L-1 O2 h-1. Where secondary chlorophyll maxima were found the rates were higher than in the oxic water just above. Incubation times longer than 20 h, in the all-glass containers, resulted in highly increased respiration rates. Addition of amino acids to the water from the upper oxycline did not lead to a significant initial rise in respiration rate within the first 20 h, indicating that the measurement of respiration rates in oligotrophic Ocean water may not be severely affected by low levels of organic contamination during sampling. Our measurements indicate that aerobic metabolism proceeds efficiently at extremely low oxygen concentrations with apparent half-saturation concentrations (Km values) ranging from about 10 to about 200 nmol L-1.

Karst system vadose zone hydrodynamics highlighted by an integrative geophysical and hydrogeological monitoring

NASA Astrophysics Data System (ADS)

Watlet, A.; Van Camp, M. J.; Francis, O.; Poulain, A.; Hallet, V.; Rochez, G.; Kaufmann, O.

2015-12-01

The vadose zone of karst systems plays an important role on the water dynamics. In particular, temporary perched aquifers can appear in the subsurface due to changes of climate conditions, diminished evapotranspiration and differences of porosity relative to deeper layers. It is therefore crucial, but challenging, to separate the hydrological signature of the vadose zone from the one of the saturated zone for understanding hydrological processes that occur in the vadose zone. Although many difficulties are usually encountered when studying karst environments due to their heterogeneities, cave systems offer an outstanding opportunity to investigate vadose zone from the inside with various techniques. We present results covering two years of hydrogeological and geophysical monitoring at the Rochefort Cave Laboratory (RCL), located in the Variscan fold-and-thrust belt (Belgium), a region that shows many karstic networks within Devonian limestone units. Hydrogeological data such as flows and levels monitoring or tracer tests performed in both vadose and saturated zones bring valuable information on the hydrological context of the studied area. Combining those results with geophysical measurements allows validating and imaging them with more integrative techniques. A microgravimetric monitoring involves a superconducting gravimeter continuously measuring at the surface of the RCL. Early in 2015, a second relative gravimeter was installed in the underlying cave system located 35 meters below the surface. This set up allows highlighting vadose gravity changes. These relative measurements are calibrated using an absolute gravimeter. 12 additional stations (7 at the surface, 5 in the cave) are monitored on a monthly basis by a spring gravimeter. To complete these gravimetric measurements, the site has been equipped with a permanent Electrical Resistivity Tomography (ERT) monitoring system comprising an uncommon array of surface, borehole and cave electrodes. Although such an unconventional ERT setup is challenging in terms of data processing and interpretation, it provides valuable data for inferring variations of the vadose zone saturation rate.

Abrupt Upper-Plate Tilting Upon Slab-Transition-Zone Collision

NASA Astrophysics Data System (ADS)

Crameri, F.; Lithgow-Bertelloni, C. R.

2017-12-01

During its sinking, the remnant of a surface plate crosses and interacts with multiple boundaries in Earth's interior. The most-prominent dynamic interaction arises at the upper-mantle transition zone where the sinking plate is strongly affected by the higher-viscosity lower mantle. Within our numerical model, we unravel, for the first time, that this very collision of the sinking slab with the transition zone induces a sudden, dramatic downward tilt of the upper plate towards the subduction trench. The slab-transition zone collision sets parts of the higher-viscosity lower mantle in motion. Naturally, this then induces an overall larger return flow cell that, at its onset, tilts the upper plate abruptly by around 0.05 degrees and over around 10 Millions of years. Such a significant and abrupt variation in surface topography should be clearly visible in temporal geologic records of large-scale surface elevation and might explain continental-wide tilting as observed in Australia since the Eocene or North America during the Phanerozoic. Unravelling this crucial mantle-lithosphere interaction was possible thanks to state-of-the-art numerical modelling (powered by StagYY; Tackley 2008, PEPI) and post-processing (powered by StagLab; www.fabiocrameri.ch/software). The new model that is introduced here to study the dynamically self-consistent temporal evolution of subduction features accurate subduction-zone topography, robust single-sided plate sinking, stronger plates close to laboratory values, an upper-mantle phase transition and, crucially, simple continents at a free surface. A novel, fully-automated post-processing includes physical model diagnostics like slab geometry, mantle flow pattern, upper-plate tilt angle and trench location.

Optical Benson: Following the Impact of Melt Season Progression Using Landsat and Sentinel 2 - Snow Zone Formation Imaged

NASA Astrophysics Data System (ADS)

Fahnestock, M. A.; Shuman, C. A.; Alley, K. E.

2017-12-01

Snow pit observations on a glaciologically-focussed surface traverse in Greenland allowed Benson [1962, SIPRE (now CRREL) Research Report 70] to define a series of snow zones based on the extent of post-depositional diagenesis of the snowpack. At high elevations, Benson found fine-grained "dry snow" where melt (at that time) was absent year-round, followed down-elevation by a "percolation zone" where surface melt penetrated the snowpack, then a "wet snow zone" where firn became saturated during the peak of the melt season, and finally "superimposed ice" and "bare ice" zones where refrozen surface melt and glacier ice were exposed in the melt season. These snow zones can be discriminated in winter synthetic aperture radar (SAR) imagery of the ice sheet (e.g. Fahnestock et al. 2001), but summer melt reduces radar backscatter and makes it difficult to follow the progression of diagenesis beyond the initial indications of surface melting. While some of the impacts of surface melt (especially bands of blue water-saturated firn) are observed from time to time in optical satellite imagery, it has only become possible to map effects of melt over the course of a summer season with the advent of large-data analysis tools such as Google Earth Engine and the inclusion of Landsat and Sentinel-2 data streams in these tools. A map of the maximum extent of this blue saturated zone through the 2016 melt season is shown in the figure. This image is a true color (RGB) composite, but each pixel in the image shows the color of the surface when the "blueness" of the pixel was at a maximum. This means each pixel can be from a different satellite image acquisition than adjacent pixels - but it also means that the maximum extent of the saturated firn (Benson's wet snow zone) is visible. Also visible are percolation, superimposed and bare ice zones. This analysis, using Landsat 8 Operational Land Imager data, was performed using Google Earth Engine to access and analyze the entire melt season's data. Similar spatial analyses for other years in the record, combined with pixel-by-pixel analysis of each time series through the year, can be used to track the progression and overall effect of the melt season in each year. This view of the progression of a melt season provides a new set of tools to help understand changing surface conditions for ice sheets and glaciers globally.

Method of operating a coal gasifier

DOEpatents

Blaskowski, Henry J.

1979-01-01

A method of operating an entrained flow coal gasifier which comprises the steps of firing coal at two levels in a combustion zone with near stoichiometric air, removing molten ash from the combustion zone, conveying combustion products upwardly from the combustion zone through a reduction zone, injecting additional coal into the combustion products in the reduction zone and gasifying at least a portion of the coal to form low BTU gas, conveying the gas to a point of use, including also reducing gasifier output by modifying the ratio of air to coal supplied to the upper level of the combustion zone so that the ratio becomes increasingly substoichiometric thereby extending the gasification of coal from the reduction zone into the upper level of the combustion zone, and maintaining the lower level of coal in the combustion zone at near stoichiometric conditions so as to provide sufficient heat to maintain effective slagging conditions.

PHT3D-UZF: A reactive transport model for variably-saturated porous media

USGS Publications Warehouse

Wu, Ming Zhi; Post, Vincent E. A.; Salmon, S. Ursula; Morway, Eric D.; Prommer, H.

2016-01-01

A modified version of the MODFLOW/MT3DMS-based reactive transport model PHT3D was developed to extend current reactive transport capabilities to the variably-saturated component of the subsurface system and incorporate diffusive reactive transport of gaseous species. Referred to as PHT3D-UZF, this code incorporates flux terms calculated by MODFLOW's unsaturated-zone flow (UZF1) package. A volume-averaged approach similar to the method used in UZF-MT3DMS was adopted. The PHREEQC-based computation of chemical processes within PHT3D-UZF in combination with the analytical solution method of UZF1 allows for comprehensive reactive transport investigations (i.e., biogeochemical transformations) that jointly involve saturated and unsaturated zone processes. Intended for regional-scale applications, UZF1 simulates downward-only flux within the unsaturated zone. The model was tested by comparing simulation results with those of existing numerical models. The comparison was performed for several benchmark problems that cover a range of important hydrological and reactive transport processes. A 2D simulation scenario was defined to illustrate the geochemical evolution following dewatering in a sandy acid sulfate soil environment. Other potential applications include the simulation of biogeochemical processes in variably-saturated systems that track the transport and fate of agricultural pollutants, nutrients, natural and xenobiotic organic compounds and micropollutants such as pharmaceuticals, as well as the evolution of isotope patterns.

Geology, hydrology, and water quality of the Tracy-Dos Palos area, San Joaquin Valley, California

USGS Publications Warehouse

Hotchkiss, W.R.; Balding, G.O.

1971-01-01

The Tracy-Dos Palos area includes about 1,800 square miles on the northwest side of the San Joaquin Valley. The Tulare Formation of Pliocene and Pleistocene age, terrace deposits of Pleistocene age, and alluvium and flood-basin deposits of Pleistocene and Holocene age constitute the fresh ground-water reservoir Pre-Tertiary and Tertiary sedimentary and crystalline rocks, undifferentiated, underlie the valley and yield saline water. Hydrologically most important, the Tulare Formation is divided into a lower water-bearing zone confined by the Corcoran Clay Member and an upper zone that is confined, semiconfined, and unconfined in different parts of the area. Alluvium and flood-basin deposits are included in the upper zone. Surficial alluvium and flood-basin deposits contain a shallow water-bearing zone. Lower zone wells were flowing in 1908, but subsequent irrigation development caused head declines and land subsidence. Overdraft in both zones ended in 1951 with import of surface water. Bicarbonate water flows into the area from the Sierra Nevada and Diablo Range. Diablo Range water is higher in sulfate, chloride, and dissolved solids. Upper zone water averages between 400 and 1,200 mg/l (milligrams per liter) dissolved solids and water hardness generally exceeds 180 mg/l as calcium carbonate. Nitrate, fluoride, iron, and boron occur in excessive concentrations in water from some wells. Dissolved constituents in lower zone water generally are sodium chloride and sodium sulfate with higher dissolved solids concentration than water from the upper zone. The foothills of the Diablo Range provide favorable conditions for artificial recharge, but shallow water problems plague about 50 percent of the area and artificial recharge is undesirable at this time.

Planktonic foraminifers and radiolarians from the Coniacian-santonian deposits of the Mt. Ak-Kaya, Crimean Mountains, Ukraine

NASA Astrophysics Data System (ADS)

Korchagin, O. A.; Bragina, L. G.; Bragin, N. Yu.

2012-02-01

The first data on the distribution of planktonic foraminifers and radiolarians in the Mt. Ak-Kaya section, the central Crimean Mountains, are considered. According to the analyzed distribution of foraminifers, the Upper Cretaceous deposits of the section are subdivided into three biostratigraphic units: the Marginotruncana austinensis-Globotruncana desioi (presumably upper Coniacian), Sigalia carpatica (uppermost Coniacian-lower Santonian), and Contusotruncana fornicata-Marginotruncana marginata (upper Santonian) beds. Subdivisions substantiated by distribution of radiolarians are the Alievium praegallowayi-Crucella plana (upper Coniacian-lower Santonian), Alievium gallowayi-Crucella espartoensis (the upper Santonian excluding its uppermost part), and Dictyocephalus (Dictyocryphalus) (?) legumen-Spongosaturninus parvulus (the uppermost Santonian) beds. The Contusotruncana fornicata-Marginotruncana marginata Beds are concurrent to the middle part of the Marsupites laevigatus Zone coupled with the Marsupites testudinarius Zone (the uppermost Santonian). The Alievium gallowayi-Crucella espartoensis Beds are correlative with the upper part of the Alievium gallowayi Zone in the Californian radiolarian zonation. The cooccurring assemblages of planktonic foraminifers and radiolarians provide a possibility to correlate the Coniacian-Santonian deposits within the Crimea-Caucasus region.

Upper limit for the effect of elastic bending stress on the saturation magnetization of L a 0.8 S r 0.2 Mn O 3

DOE Office of Scientific and Technical Information (OSTI.GOV)

Wang, Qiang; Chen, A. P.; Guo, Erjia J.

In this study, using polarized neutron reflectometry, we measured the influence of elastic bending stress on the magnetization depth profile of a La 0.8Sr 0.2MnO 3 (LSMO) epitaxial film grown on a SrTiO 3 substrate. The elastic bending strain of ±0.03% has no obvious effect on the magnetization depth profile at saturation. This result is in stark contrast to that of (La 1-xPr x)1-yCayMnO 3 (LPCMO) films for which strain of ±0.01% produced dramatic changes in the magnetization profile and Curie temperature. We attribute the difference between the influence of strain on the saturation magnetization in LSMO (weak or none)more » and LPCMO (strong) to a difference in the ability of LSMO (weak or none) and LPCMO (strong) to phase separate. Our observation provides an upper limit of tuning LSMO saturation magnetization via elastic strain effect.« less

Upper limit for the effect of elastic bending stress on the saturation magnetization of L a 0.8 S r 0.2 Mn O 3

DOE PAGES

Wang, Qiang; Chen, A. P.; Guo, Erjia J.; ...

2018-01-31

In this study, using polarized neutron reflectometry, we measured the influence of elastic bending stress on the magnetization depth profile of a La 0.8Sr 0.2MnO 3 (LSMO) epitaxial film grown on a SrTiO 3 substrate. The elastic bending strain of ±0.03% has no obvious effect on the magnetization depth profile at saturation. This result is in stark contrast to that of (La 1-xPr x)1-yCayMnO 3 (LPCMO) films for which strain of ±0.01% produced dramatic changes in the magnetization profile and Curie temperature. We attribute the difference between the influence of strain on the saturation magnetization in LSMO (weak or none)more » and LPCMO (strong) to a difference in the ability of LSMO (weak or none) and LPCMO (strong) to phase separate. Our observation provides an upper limit of tuning LSMO saturation magnetization via elastic strain effect.« less

Upper crustal structure beneath East Java from ambient noise tomography: A preliminary result

DOE Office of Scientific and Technical Information (OSTI.GOV)

Martha, Agustya Adi; Graduate Research on Earthquakes and Active Tectonics, Institut Teknologi Bandung, Bandung; Widiyantoro, Sri

East Java has a fairly complex geological structure. Physiographically East Java can be divided into three zones, i.e. the Southern Mountains zone in the southern part, the Kendeng zone in the middle part, and the Rembang zone in the northern part. Most of the seismic hazards in this region are due to processes in the upper crust. In this study, the Ambient Noise Tomography (ANT) method is used to image the upper crustal structure beneath East Java. We have used seismic waveform data recorded by 8Meteorological, Climatological and Geophysical Agency (BMKG) stationary seismographic stations and 16 portable seismographs installed formore » 2 to 8 weeks. The data were processed to obtain waveforms fromnoise cross-correlation between pairs of seismographic stations. Our preliminary results indicate that the Kendeng zone, an area of low gravity anomaly, is associated with a low velocity zone. On the other hand, the southern mountain range, which has a high gravity anomaly, is related to a high velocity anomaly as shown by our tomographic images.« less

Imaging the crustal magma sources beneath Mauna Loa and Kilauea volcanoes, Hawaii

USGS Publications Warehouse

Okubo, Paul G.; Benz, Harley M.; Chouet, Bernard A.

1997-01-01

Three-dimensional seismic P-wave traveltime tomography is used to image the magma sources beneath Mauna Loa and Kilauea volcanoes, Hawaii. High-velocity bodies (>6.4 km/s) in the upper 9 km of the crust beneath the summits and rift zones of the volcanoes correlate with zones of high magnetic intensities and are interpreted as solidified gabbro-ultramafic cumulates from which the surface volcanism is derived. The proximity of these high-velocity features to the rift zones is consistent with a ridge-spreading model of the volcanic flank. Southeast of the Hilina fault zone, along the south flank of Kilauea, low-velocity material (<6.0 km/s) is observed extending to depths of 9–11 km, indicating that the Hilina fault may extend possibly as deep as the basal decollement. Along the southeast flank of Mauna Loa, a similar low-velocity zone associated with the Kaoiki fault zone is observed extending to depths of 6–8 km. These two upper crustal low-velocity zones suggest common stages in the evolution of the Hawaiian shield volcanoes in which these fault systems are formed as a result of upper crustal deformation in response to magma injection within the volcanic edifice.

The Architecture and Frictional Properties of Faults in Shale

NASA Astrophysics Data System (ADS)

De Paola, N.; Imber, J.; Murray, R.; Holdsworth, R.

2015-12-01

The geometry of brittle fault zones in shale rocks, as well as their frictional properties at reservoir conditions, are still poorly understood. Nevertheless, these factors may control the very low recovery factors (25% for gas and 5% for oil) obtained during fracking operations. Extensional brittle fault zones (maximum displacement < 3 m) cut exhumed oil mature black shales in the Cleveland Basin (UK). Fault cores up to 50 cm wide accommodated most of the displacement, and are defined by a stair-step geometry. Their internal architecture is characterised by four distinct fault rock domains: foliated gouges; breccias; hydraulic breccias; and a slip zone up to 20 mm thick, composed of a fine-grained black gouge. Hydraulic breccias are located within dilational jogs with aperture of up to 20 cm. Brittle fracturing and cataclastic flow are the dominant deformation mechanisms in the fault core of shale faults. Velocity-step and slide-hold-slide experiments at sub-seismic slip rates (microns/s) were performed in a rotary shear apparatus under dry, water and brine-saturated conditions, for displacements of up to 46 cm. Both the protolith shale and the slip zone black gouge display shear localization, velocity strengthening behaviour and negative healing rates, suggesting that slow, stable sliding faulting should occur within the protolith rocks and slip zone gouges. Experiments at seismic speed (1.3 m/s), performed on the same materials under dry conditions, show that after initial friction values of 0.5-0.55, friction decreases to steady-state values of 0.1-0.15 within the first 10 mm of slip. Contrastingly, water/brine saturated gouge mixtures, exhibit almost instantaneous attainment of very low steady-state sliding friction (0.1), suggesting that seismic ruptures may efficiently propagate in the slip zone of fluid-saturated shale faults. Stable sliding in faults in shale can cause slow fault/fracture propagation, affecting the rate at which new fracture areas are created and, hence, limiting oil and gas production during reservoir stimulation. However, fluid saturated conditions can favour seismic slip propagation, with fast and efficient creation of new fracture areas. These processes are very effective at dilational jogs, where fluid circulation may be enhanced, facilitating oil and gas production.

Partially to fully saturated flow through smooth, clean, open fractures: qualitative experimental studies

NASA Astrophysics Data System (ADS)

Jones, Brendon R.; Brouwers, Luke B.; Dippenaar, Matthys A.

2018-05-01

Fractures are both rough and irregular but can be expressed by a simple model concept of two smooth parallel plates and the associated cubic law governing discharge through saturated fractures. However, in natural conditions and in the intermediate vadose zone, these assumptions are likely violated. This paper presents a qualitative experimental study investigating the cubic law under variable saturation in initially dry free-draining discrete fractures. The study comprised flow visualisation experiments conducted on transparent replicas of smooth parallel plates with inlet conditions of constant pressure and differing flow rates over both vertical and horizontal inclination. Flow conditions were altered to investigate the influence of intermittent and continuous influx scenarios. Findings from this research proved, for instance, that saturated laminar flow is not likely achieved, especially in nonhorizontal fractures. In vertical fractures, preferential flow occupies the minority of cross-sectional area despite the water supply. Movement of water through the fractured vadose zone therefore becomes a matter of the continuity principle, whereby water should theoretically be transported downward at significantly higher flow rates given the very low degree of water saturation. Current techniques that aim to quantify discrete fracture flow, notably at partial saturation, are questionable. Inspired by the results of this study, it is therefore hypothetically improbable to achieve saturation in vertical fractures under free-draining wetting conditions. It does become possible under extremely excessive water inflows or when not free-draining; however, the converse is not true, as a wet vertical fracture can be drained.

Thermal conductivity, bulk properties, and thermal stratigraphy of silicic tuffs from the upper portion of hole USW-G1, Yucca Mountain, Nye County, Nevada

DOE Office of Scientific and Technical Information (OSTI.GOV)

Lappin, A.R.; VanBuskirk, R.G.; Enniss, D.O.

1982-03-01

Thermal-conductivity and bulk-property measurements were made on welded and nonwelded silicic tuffs from the upper portion of Hole USW-G1, located near the southwestern margin of the Nevada Test Site. Bulk-property measurements were made by standard techniques. Thermal conductivities were measured at temperatures as high as 280{sup 0}C, confining pressures to 10 MPa, and pore pressures to 1.5 MPa. Extrapolation of measured saturated conductivities to zero porosity suggests that matrix conductivity of both zeolitized and devitrified tuffs is independent of stratigraphic position, depth, and probably location. This fact allows development of a thermal-conductivity stratigraphy for the upper portion of Hole G1.more » Estimates of saturated conductivities of zeolitized nonwelded tuffs and devitrified tuffs below the water table appear most reliable. Estimated conductivities of saturated densely welded devitrified tuffs above the water table are less reliable, due to both internal complexity and limited data presently available. Estimation of conductivity of dewatered tuffs requires use of different air thermal conductivities in devitrified and zeolitized samples. Estimated effects of in-situ fracturing generally appear negligible.« less

Changes in air flow patterns using surfactants and thickeners during air sparging: bench-scale experiments.

PubMed

Kim, Juyoung; Kim, Heonki; Annable, Michael D

2015-01-01

Air injected into an aquifer during air sparging normally flows upward according to the pressure gradients and buoyancy, and the direction of air flow depends on the natural hydrogeologic setting. In this study, a new method for controlling air flow paths in the saturated zone during air sparging processes is presented. Two hydrodynamic parameters, viscosity and surface tension of the aqueous phase in the aquifer, were altered using appropriate water-soluble reagents distributed before initiating air sparging. Increased viscosity retarded the travel velocity of the air front during air sparging by modifying the viscosity ratio. Using a one-dimensional column packed with water-saturated sand, the velocity of air intrusion into the saturated region under a constant pressure gradient was inversely proportional to the viscosity of the aqueous solution. The air flow direction, and thus the air flux distribution was measured using gaseous flux meters placed at the sand surface during air sparging experiments using both two-, and three-dimensional physical models. Air flow was found to be influenced by the presence of an aqueous patch of high viscosity or suppressed surface tension in the aquifer. Air flow was selective through the low-surface tension (46.5 dyn/cm) region, whereas an aqueous patch of high viscosity (2.77 cP) was as an effective air flow barrier. Formation of a low-surface tension region in the target contaminated zone in the aquifer, before the air sparging process is inaugurated, may induce air flow through the target zone maximizing the contaminant removal efficiency of the injected air. In contrast, a region with high viscosity in the air sparging influence zone may minimize air flow through the region prohibiting the region from de-saturating. Copyright © 2014 Elsevier B.V. All rights reserved.

Characterization of NAPL source zone architecture and dissolution kinetics in heterogeneous porous media using magnetic resonance imaging.

PubMed

Zhang, Changyong; Werth, Charles J; Webb, Andrew G

2007-05-15

A direct visualization method using magnetic resonance imaging (MRI) was developed to characterize sand grain size distribution, nonaqueous phase liquid (NAPL) source zone architecture, and aqueous flowpaths in a three-dimensional (3-D) flowcell (26.5 cm x 10.5 cm x 10.5 cm) packed with a heterogeneous distribution of five different sand fractions. All images were acquired at a resolution of 0.1875 cm x 0.1875 cm x 0.225 cm. A 1H image of pore water resolved the heterogeneous permeability field; grain size differences as small as 0.1 mm could be distinguished. A time series of 1H images of water doped with the paramagnetic tracer MnCl2 were acquired and used to obtain voxel-scale breakthrough curves. Water preferentially flowed through coarse sands before NAPL release. After NAPL release, the flow bypassed NAPLzones, and bypassing was more evident for high NAPL saturation zones. A time series of 19F images of NAPL were acquired and used to determine voxel-scale NAPL saturation (Sn) during dissolution. Results show that 93% of NAPL mass was in the coarsest sand, most NAPL was trapped as pools and not as residual ganglia, NAPL saturation increased with depth, and the NAPL dissolution front moved vertically from the top to the bottom of the flowcell during the first 170 pore volumes of waterflushed. NAPL component effluent concentrations initially increased due to the development of flow in zones with decreasing NAPL saturation. Flowpath images suggest that this occurs as NAPL transitions from pools (Sn > 0.15) to residual ganglia. The results highlight the importance of flow bypassing and provide the opportunity to develop more accurate NAPL dissolution models.

CO2 content of andesitic melts at graphite-saturated upper mantle conditions with implications for redox state of oceanic basalt source regions and remobilization of reduced carbon from subducted eclogite

NASA Astrophysics Data System (ADS)

Eguchi, James; Dasgupta, Rajdeep

2017-03-01

We have performed experiments to determine the effects of pressure, temperature and oxygen fugacity on the CO2 contents in nominally anhydrous andesitic melts at graphite saturation. The andesite composition was specifically chosen to match a low-degree partial melt composition that is generated from MORB-like eclogite in the convective, oceanic upper mantle. Experiments were performed at 1-3 GPa, 1375-1550 °C, and fO2 of FMQ -3.2 to FMQ -2.3 and the resulting experimental glasses were analyzed for CO2 and H2O contents using FTIR and SIMS. Experimental results were used to develop a thermodynamic model to predict CO2 content of nominally anhydrous andesitic melts at graphite saturation. Fitting of experimental data returned thermodynamic parameters for dissolution of CO2 as molecular CO2: ln( K 0) = -21.79 ± 0.04, Δ V 0 = 32.91 ± 0.65 cm3mol-1, Δ H 0 = 107 ± 21 kJ mol-1, and dissolution of CO2 as CO3 2-: ln (K 0 ) = -21.38 ± 0.08, Δ V 0 = 30.66 ± 1.33 cm3 mol-1, Δ H 0 = 42 ± 37 kJ mol-1, where K 0 is the equilibrium constant at some reference pressure and temperature, Δ V 0 is the volume change of reaction, and Δ H 0 is the enthalpy change of reaction. The thermodynamic model was used along with trace element partition coefficients to calculate the CO2 contents and CO2/Nb ratios resulting from the mixing of a depleted MORB and the partial melt of a graphite-saturated eclogite. Comparison with natural MORB and OIB data suggests that the CO2 contents and CO2/Nb ratios of CO2-enriched oceanic basalts cannot be produced by mixing with partial melts of graphite-saturated eclogite. Instead, they must be produced by melting of a source containing carbonate. This result places a lower bound on the oxygen fugacity for the source region of these CO2-enriched basalts, and suggests that fO2 measurements made on cratonic xenoliths may not be applicable to the convecting upper mantle. CO2-depleted basalts, on the other hand, are consistent with mixing between depleted MORB and partial melts of a graphite-saturated eclogite. Furthermore, calculations suggest that eclogite can remain saturated in graphite in the convecting upper mantle, acting as a reservoir for C.

Can compliant fault zones be used to measure absolute stresses in the upper crust?

NASA Astrophysics Data System (ADS)

Hearn, E. H.; Fialko, Y.

2009-04-01

Geodetic and seismic observations reveal long-lived zones with reduced elastic moduli along active crustal faults. These fault zones localize strain from nearby earthquakes, consistent with the response of a compliant, elastic layer. Fault zone trapped wave studies documented a small reduction in P and S wave velocities along the Johnson Valley Fault caused by the 1999 Hector Mine earthquake. This reduction presumably perturbed a permanent compliant structure associated with the fault. The inferred changes in the fault zone compliance may produce a measurable deformation in response to background (tectonic) stresses. This deformation should have the same sense as the background stress, rather than the coseismic stress change. Here we investigate how the observed deformation of compliant zones in the Mojave Desert can be used to constrain the fault zone structure and stresses in the upper crust. We find that gravitational contraction of the coseismically softened zones should cause centimeters of coseismic subsidence of both the compliant zones and the surrounding region, unless the compliant fault zones are shallow and narrow, or essentially incompressible. We prefer the latter interpretation because profiles of line of sight displacements across compliant zones cannot be fit by a narrow, shallow compliant zone. Strain of the Camp Rock and Pinto Mountain fault zones during the Hector Mine and Landers earthquakes suggests that background deviatoric stresses are broadly consistent with Mohr-Coulomb theory in the Mojave upper crust (with μ ≥ 0.7). Large uncertainties in Mojave compliant zone properties and geometry preclude more precise estimates of crustal stresses in this region. With improved imaging of the geometry and elastic properties of compliant zones, and with precise measurements of their strain in response to future earthquakes, the modeling approach we describe here may eventually provide robust estimates of absolute crustal stress.

78 FR 74009 - Safety Zone; Nike Fireworks, Upper New York Bay, Ellis Island, NY

Federal Register 2010, 2011, 2012, 2013, 2014

2013-12-10

... DEPARTMENT OF HOMELAND SECURITY Coast Guard 33 CFR Part 165 [Docket No. USCG-2013-0962] Safety Zone; Nike Fireworks, Upper New York Bay, Ellis Island, NY AGENCY: Coast Guard, DHS. ACTION: Notice of... published in the Federal Register on November 9, 2011 (76 FR 69614). [[Page 74010

In Situ Bioremediation of Perchlorate in Vadose Zone Source Areas

DTIC Science & Technology

2011-01-01

agricultural bags (e.g., ITRC, 2008; Evans et al., 2008). Phytoremediation has also been tested for soil treatment (ITRC, 2008). However, these...within the saturated zone (through in situ bioremediation or groundwater extraction and ex-situ treatment), phytoremediation , which is unlikely to

Evolution of crustal stress, pressure and temperature around shear zones during orogenic wedge formation: a 2D thermo-mechanical numerical study

NASA Astrophysics Data System (ADS)

Markus Schmalholz, Stefan; Jaquet, Yoann

2016-04-01

We study the formation of an orogenic wedge during lithospheric shortening with 2D numerical simulations. We consider a viscoelastoplastic rheology, thermo-mechanical coupling by shear heating and temperature-dependent viscosities, gravity and erosion. In the initial model configuration there is either a lateral temperature variation at the model base or a lateral variation in crustal thickness to generate slight stress variations during lithospheric shortening. These stress variations can trigger the formation of shear zones which are caused by thermal softening associated with shear heating. We do not apply any kind of strain softening, such as reduction of friction angle with progressive plastic strain. The first major shear zone that appears during shortening crosscuts the entire crust and initiates the asymmetric subduction/underthrusting of mainly the mechanically strong lower crust. After some deformation, the first shear zone in the upper crust is abandoned, the deformation propagates towards the foreland and a new shear zone forms only in the upper crust. The shear zone propagation occurs several times where new shear zones form in the upper crust and the mechanically strong top of the lower crust acts as detachment horizon. We calculate the magnitudes of the maximal and minimal principal stresses and of the mean stress (or dynamic pressure), and we record also the temperature for several marker points in the upper and lower crust. We analyse the evolution of stresses and temperature with burial depth and time. Deviatoric stresses (half the differential stress) in the upper crust are up to 200 MPa and associated shear heating in shear zones ranges between 40 - 80 °C. Lower crustal rocks remain either at the base of the orogenic wedge at depths of around 50 km or are subducted to depths of up to 120 km, depending on their position when the first shear zone formed. Largest deviatotric stresses in the strong part of the lower crust are about 1000 MPa and maximal shear heating in shear zones is approximately 200 °C. Marker points can migrate through the main shear zone in the lower crust which remains active throughout lithospheric shortening. Some pressure-temperature paths show an anti-clockwise evolution. The impact of various model parameters on the results is discussed as well as applications of the results to geological data.

Low-Q structure related to partially saturated pores within the reservoir beneath The Geysers area in the northern California

NASA Astrophysics Data System (ADS)

Matsubara, M.

2011-12-01

A large reservoir is located beneath The Geysers geothermal area, northern California. Seismic tomography revealed high-velocity (high-V) and low-Vp/Vs zones in the reservoir (Julian et al., 1996) and a decrease of Vp/Vs from 1991 to 1998 (Guasekera et al., 2003) owing to withdrawal of steam from the reservoir. I perform attenuation tomography in this region to investigate the state of vapor and liquid within the reservoir. The target region, 38.5-39.0°N and 122.5-123°W, covers The Geysers area. I use seismograms of 1,231 events whose focal mechanism are determined among 65,810 events recorded by the Northern California Earthquake Data Center from 2002 to 2008 in the target region. The band-pass filtered seismograms are analyzed for collecting the maximum amplitude data. There are 26 stations that have a three-component seismometer among 47 seismic stations. I use the P- and S-wave maximum amplitudes during the two seconds after the arrival of those waves in order to avoid coda effects. A total of 8,545 P- and 1,168 S-wave amplitude data for 949 earthquakes recorded at 47 stations are available for the analysis using the attenuation tomographic method derived from the velocity tomographic method (Matsubara et al., 2005, 2008) in which spatial velocity correlation and station corrections are introduced to the original code of Zhao et al. (1992). I use 3-D velocity structure obtained by Thurber et al. (2009). The initial Q value is set to 150, corresponding to the average Q of the northern California (Ford et al., 2010). At sea level, low-Q zones are found extending from the middle of the steam reservoir within the main greywacke to the south part of the reservoir. At a depth of 1 km below sea level, a low-Q zone is located solely in the southern part of the reservoir. However, at a depth of 2 km a low-Q zone is located beneath the northern part of the reservoir. At depths of 1 to 3 km a felsite batholith in the deeper portions of the reservoir, and it corresponds with a high-Q zone. A vertical cross section shows the low-Q zone is consistent with the reservoir as it extends through the main greywacke and into the uppermost part of the felsite. Most of the felsite has high-Q, however, the portion of the reservoir that extends into the felsite has low-Q. The Geysers geothermal area is bounded by Collayomi fault zone to the northeast and the Mercuryville fault zone to the southwest. The Geysers Peak fault runs from northwest to southeast about 3 km southwest of the Mercuryville fault. The Mercuryville fault dips to northeast and the Geysers Peak fault dips to southwest. High-Q zone is located between these faults and the width of this zone broadens as the depth increases corresponding to the fault geometry. The presence of liquid water introduces high-Vp/Vs, however, steam rich zones become low-Vp/Vs. Near the transition zone between the water and steam, laboratory experiments indicate that the amplitude becomes extremely small (Ito et al., 1979). A partially saturated zone has lower Q than a fully saturated zone, and a dry zone has high-Q. A low-Q zone with low-Vp/Vs corresponding to the reservoir indicates that the reservoir is partially saturated with steam and water near transition zone.

Effect of Interannual Variability on the Ocean Acidification-induced Habitat Restriction of the Humboldt Current System.

NASA Astrophysics Data System (ADS)

Franco, A. C.; Gruber, N.; Munnich, M.

2016-02-01

The Humboldt Current System (HCS) is one of the most productive ecosystems in the world. This high productivity is supported by a large input of nutrients from the subsurface layers to the surface due to year-round upwelling. However, upwelling also supplies waters with low pH and low aragonite saturation state potentially affecting many organisms, especially those that calcify. The influence, extent and source of upwelled water varies substantially on interannual timescales in association with the El Niño/Southern Oscillation (ENSO) phenomenon, accentuating productivity during La Niña events and dampening it during El Niño, altering the dynamics of the whole ecosystem. On top of this natural variability, the continuing acidification of the upper ocean in response to raising atmospheric CO2 may decrease pH further and increase the volume of water corrosive to aragonite in this region, leading to a progressively smaller suitable habitat for sensitive organisms. Here we use an eddy-resolving basin-scale ocean model that covers the whole Pacific Ocean with higher resolution near the coast off South America ( 6 km) to investigate the role of ENSO events on low aragonite saturation episodes and productivity variations. We compare 2 simulations: a hindcast simulation that spans the last 30 years and a future scenario that represents year 2090 (following IPCC's "business-as-usual" scenario). We found that in the region off Peru, the sole effect of increasing atmospheric CO2 to 840 matm shoals the annual average aragonite saturation depth to 30 m, creating a year round presence of aragonite undersaturated water in the euphotic zone. We then contrast the effect on primary productivity and the aragonite saturation state of at least eight El Niño and eight La Niña episodes that have been reported for the past 30 years, in an attempt to answer the question: does habitat availability under future ocean acidification will resemble a pervasive La Niña-like state?

Method for improving dissolution efficiency in gas-absorption and liquid extraction processes. [Patent application

DOEpatents

Kanak, B.E.; Stephenson, M.J.

1980-01-11

A method is described for improving dissolution efficiency in processes in which a feed fluid is introduced to a zone where it is contacted with a liquid solvent for preferentially removing a component of the feed and where part of the solvent so contacted undergoes transfer into the feed fluid to saturate the same. It has been found that such transfer significantly impairs dissolution efficiency. In accordance with the invention, an amount of the above-mentioned solvent is added to the feed fluid being introduced to the contact zone, the solvent being added in an amount sufficient to effect reduction or elimination of the above-mentioned transfer. Preferably, the solvent is added to the feed fluid in an amount saturating or supersaturating the feed fluid under the conditions prevailing in the contact zone.

Method for improving dissolution efficiency in gas-absorption and liquid extraction processes

DOEpatents

Kanak, Brant E.; Stephenson, Michael J.

1981-01-01

This invention is a method for improving dissolution efficiency in processes in which a feed fluid is introduced to a zone where it is contacted with a liquid solvent for preferentially removing a component of the feed and where part of the solvent so contacted undergoes transfer into the feed fluid to saturate the same. It has been found that such transfer significantly impairs dissolution efficiency. In accordance with the invention, an amount of the above-mentioned solvent is added to the feed fluid being introduced to the contact zone, the solvent being added in an amount sufficient to effect reduction or elimination of the above-mentioned transfer. Preferably, the solvent is added to the feed fluid in an amount saturating or supersaturating the feed fluid under the conditions prevailing in the contact zone.

Role of deep crustal fluids in the genesis of intraplate earthquakes in the Kachchh region, northwestern India

NASA Astrophysics Data System (ADS)

Pavan Kumar, G.; Mahesh, P.; Nagar, Mehul; Mahender, E.; Kumar, Virendhar; Mohan, Kapil; Ravi Kumar, M.

2017-05-01

Fluids play a prominent role in the genesis of earthquakes, particularly in intraplate settings. In this study, we present evidence for a highly heterogeneous nature of electrical conductivity in the crust and uppermost mantle beneath the Kachchh rift basin of northwestern India, which is host to large, deadly intraplate earthquakes. We interpret our results of high conductive zones inferred from magnetotelluric and 3-D local earthquake tomography investigations in terms of a fluid reservoir in the upper mantle. The South Wagad Fault (SWF) imaged as a near-vertical north dipping low resistivity zone traversing the entire crust and an elongated south dipping conductor demarcating the North Wagad Fault (NWF) serve as conduits for fluid flow from the reservoir to the middle to lower crustal depths. Importantly, the epicentral zone of the 2001 main shock is characterized as a fluid saturated zone at the rooting of NWF onto the SWF.