Apportioning riverine DIN load to export coefficients of land uses in an urbanized watershed.

PubMed

Shih, Yu-Ting; Lee, Tsung-Yu; Huang, Jr-Chuan; Kao, Shuh-Ji; Chang

2016-08-01

The apportionment of riverine dissolved inorganic nitrogen (DIN) load to individual land use on a watershed scale demands the support of accurate DIN load estimation and differentiation of point and non-point sources, but both of them are rarely quantitatively determined in small montane watersheds. We introduced the Danshui River watershed of Taiwan, a mountainous urbanized watershed, to determine the export coefficients via a reverse Monte Carlo approach from riverine DIN load. The results showed that the dynamics of N fluctuation determines the load estimation method and sampling frequency. On a monthly sampling frequency basis, the average load estimation of the methods (GM, FW, and LI) outperformed that of individual method. Export coefficient analysis showed that the forest DIN yield of 521.5kg-Nkm(-2)yr(-1) was ~2.7-fold higher than the global riverine DIN yield (mainly from temperate large rivers with various land use compositions). Such a high yield was attributable to high rainfall and atmospheric N deposition. The export coefficient of agriculture was disproportionately larger than forest suggesting that a small replacement of forest to agriculture could lead to considerable change of DIN load. The analysis of differentiation between point and non-point sources showed that the untreated wastewater (non-point source), accounting for ~93% of the total human-associated wastewater, resulted in a high export coefficient of urban. The inclusion of the treated and untreated wastewater completes the N budget of wastewater. The export coefficient approach serves well to assess the riverine DIN load and to improve the understanding of N cascade. Copyright © 2016 Elsevier B.V. All rights reserved.

Identification of antibiotic resistant bacteria community and a GeoChip based study of resistome in urban watersheds.

PubMed

Low, Adrian; Ng, Charmaine; He, Jianzhong

2016-12-01

Urban watersheds from point sources are potential reservoirs of antibiotic resistance genes (ARGs). However, few studies have investigated urban watersheds of non-point sources. To understand the type of ARGs and bacteria that might carry such genes, we investigated two non-point source urban watersheds with different land-use profiles. Antibiotic resistance levels of two watersheds (R1, R3) were examined using heterotrophic plate counts (HPC) as a culturing method to obtain counts of bacteria resistant to seven antibiotics belonging to different classes (erythromycin, kanamycin, lincomycin, norfloxacin, sulfanilamide, tetracycline and trimethoprim). From the HPC study, 239 antibiotic resistant bacteria were characterized for resistance to more antibiotics. Furthermore, ARGs and antimicrobial biosynthesis genes were identified using GeoChip version 5.0 to elucidate the resistomes of surface waters in watersheds R1 and R3. The HPC study showed that water samples from R1 had significantly higher counts of bacteria resistant to erythromycin, kanamycin, norfloxacin, sulfanilamide, tetracycline and trimethoprim than those from R3 (Analysis of Similarity (ANOSIM), R = 0.557, p < 0.01). Of the seven antibiotics tested, lincomycin and trimethoprim resistant bacteria are greater in abundances. The 239 antibiotic resistant isolates represent a subset of resistant bacterial populations, including bacteria not previously known for resistance. Majority of the isolates had resistance to ampicillin, vancomycin, lincomycin and trimethoprim. GeoChip revealed similar ARGs in both watersheds, but with significantly higher intensities for tetX and β-lactamase B genes in R1 than R3. The genes with the highest average normalized intensities in R1 and R3 were tetracycline (tet) and fosfomycin (fosA) resistance genes, respectively. The higher abundance of tetX genes in R1 is congruent with the higher abundance of tetracycline resistant HPC observed in R1 samples. Strong correlations (r ≥ 0.8) of efflux pumps with antimicrobial biosynthesis genes suggest that natural production of antimicrobials may act as a selective pressure of transporter proteins in the absence of antibiotics from anthropogenic sources. In conclusion, distinct antibiotic resistant bacteria phylotypes and a variety of ARGs were present in the non-point sources urban watersheds of different land-use profiles, suggesting that ARG risk assessments and monitoring studies need to include these types of watersheds. Copyright © 2016 Elsevier Ltd. All rights reserved.

Effect of feed source and pyrolysis conditions on properties and metal sorption by sugarcane biochar

USDA-ARS?s Scientific Manuscript database

Population growth along with urbanization expansion and intensification of arable land management burdens natural systems ability to sustain ecosystem services such as clean waters. Development of low-cost sorbents for use in non-point-source runoff-water infiltration systems is essential for improv...

Examining trends in general fecal indicator bacteria and microbial source tracking genetic markers at non-point source impacted Chicago beaches

EPA Science Inventory

In the Chicago area, treated wastewater and storm water flow through the engineered Chicago River system to the Mississippi River, with the goal to protect Lake Michigan from urban discharges. Therefore, under dry weather conditions, nearby Lake Michigan recreational beaches shou...

[L-THIA-based management design for controlling urban non-point source pollution].

PubMed

Guo, Qing-Hai; Yang, Liu; Ke-Ming, Ma

2007-11-01

L-THIA Model was used to simulate the amounts of NPS pollutants in 2 catchments of Sanjiao watershed (Sj1, Sj2) in Hanyang district, and the total simulated amount of NPS loads in Sj1 and Sj2 were 1.82 x 10(4) kg, 1.38 x 10(5) kg, respectively. Based on the theory of resource-sink" and interaction of pattern with process, a series of BMPs, including green roof, grassland, porous pavement, infiltration trench, vegetative filter strip and wet pond, were optimized, and effects of BMPs were simulated along the surface runoff pathway. The results show that total pollutants outputs entering Sj1 and Sj2 account for 14.65% and 6.57%, respectively. Combining L-THIA model and BMPs in series is a proper measure for non-point source pollution control and urban development planning at watershed or region scale.

Legacy source of mercury in an urban stream-wetland ecosystem in central North Carolina, USA.

PubMed

Deonarine, Amrika; Hsu-Kim, Heileen; Zhang, Tong; Cai, Yong; Richardson, Curtis J

2015-11-01

In the United States, aquatic mercury contamination originates from point and non-point sources to watersheds. Here, we studied the contribution of mercury in urban runoff derived from historically contaminated soils and the subsequent production of methylmercury in a stream-wetland complex (Durham, North Carolina), the receiving water of this runoff. Our results demonstrated that the mercury originated from the leachate of grass-covered athletic fields. A fraction of mercury in this soil existed as phenylmercury, suggesting that mercurial anti-fungal compounds were historically applied to this soil. Further downstream in the anaerobic sediments of the stream-wetland complex, a fraction (up to 9%) of mercury was converted to methylmercury, the bioaccumulative form of the metal. Importantly, the concentrations of total mercury and methylmercury were reduced to background levels within the stream-wetland complex. Overall, this work provides an example of a legacy source of mercury that should be considered in urban watershed models and watershed management. Copyright © 2014 Elsevier Ltd. All rights reserved.

Trend analysis of a tropical urban river water quality in Malaysia.

PubMed

Othman, Faridah; M E, Alaa Eldin; Mohamed, Ibrahim

2012-12-01

Rivers play a significant role in providing water resources for human and ecosystem survival and health. Hence, river water quality is an important parameter that must be preserved and monitored. As the state of Selangor and the city of Kuala Lumpur, Malaysia, are undergoing tremendous development, the river is subjected to pollution from point and non-point sources. The water quality of the Klang River basin, one of the most densely populated areas within the region, is significantly degraded due to human activities as well as urbanization. Evaluation of the overall river water quality status is normally represented by a water quality index (WQI), which consists of six parameters, namely dissolved oxygen, biochemical oxygen demand, chemical oxygen demand, suspended solids, ammoniacal nitrogen and pH. The objectives of this study are to assess the water quality status for this tropical, urban river and to establish the WQI trend. Using monthly WQI data from 1997 to 2007, time series were plotted and trend analysis was performed by employing the first-order autocorrelated trend model on the moving average values for every station. The initial and final values of either the moving average or the trend model were used as the estimates of the initial and final WQI at the stations. It was found that Klang River water quality has shown some improvement between 1997 and 2007. Water quality remains good in the upper stream area, which provides vital water sources for water treatment plants in the Klang valley. Meanwhile, the water quality has also improved in other stations. Results of the current study suggest that the present policy on managing river quality in the Klang River has produced encouraging results; the policy should, however, be further improved alongside more vigorous monitoring of pollution discharge from various point sources such as industrial wastewater, municipal sewers, wet markets, sand mining and landfills, as well as non-point sources such as agricultural or urban runoff and commercial activity.

IMPERVIOUS SURFACE RESEARCH IN THE MID-ATLANTIC

EPA Science Inventory

Anthropogenic impervious surfaces have an important relationship with non-point source pollution (NPS) in urban watersheds. These human-created surfaces include such features as roads, parking lots, rooftops, sidewalks, and driveways. The amount of impervious surface area in a ...

USEPA EPIC IMPERVIOUS SURFACE RESEARCH IN THE MID-ATLANTIC

EPA Science Inventory

Anthropogenic impervious surfaces have an important relationship with non-point source pollution (NPS) in urban watersheds. These human-created surfaces include such features as roads, parking lots, rooftops, sidewalks, and driveways. The amount of impervious surface area in a ...

Estimation of nutrient discharge from the Yangtze River to the East China Sea and the identification of nutrient sources.

PubMed

Tong, Yindong; Bu, Xiaoge; Chen, Junyue; Zhou, Feng; Chen, Long; Liu, Maodian; Tan, Xin; Yu, Tao; Zhang, Wei; Mi, Zhaorong; Ma, Lekuan; Wang, Xuejun; Ni, Jing

2017-01-05

Based on a time-series dataset and the mass balance method, the contributions of various sources to the nutrient discharges from the Yangtze River to the East China Sea are identified. The results indicate that the nutrient concentrations vary considerably among different sections of the Yangtze River. Non-point sources are an important source of nutrients to the Yangtze River, contributing about 36% and 63% of the nitrogen and phosphorus discharged into the East China Sea, respectively. Nutrient inputs from non-point sources vary among the sections of the Yangtze River, and the contributions of non-point sources increase from upstream to downstream. Considering the rice growing patterns in the Yangtze River Basin, the synchrony of rice tillering and the wet seasons might be an important cause of the high nutrient discharge from the non-point sources. Based on our calculations, a reduction of 0.99Tg per year in total nitrogen discharges from the Yangtze River would be needed to limit the occurrences of harmful algal blooms in the East China Sea to 15 times per year. The extensive construction of sewage treatment plants in urban areas may have only a limited effect on reducing the occurrences of harmful algal blooms in the future. Copyright © 2016 Elsevier B.V. All rights reserved.

Characterization of occurrence, sources and sinks of perfluoroalkyl and polyfluoroalkyl substances (PFASs) in a tropical urban catchment.

PubMed

Chen, Huiting; Reinhard, Martin; Nguyen, Tung Viet; You, Luhua; He, Yiliang; Gin, Karina Yew-Hoong

2017-08-01

Understanding the sources, occurrence and sinks of perfluoroalkyl and polyfluoroalkyl substances (PFASs) in the urban water cycle is important to protect and utilize local water resources. Concentrations of 22 target PFASs and general water quality parameters were determined monthly for a year in filtered water samples from five tributaries and three sampling stations of an urban water body. Of the 22 target PFASs, 17 PFASs were detected with a frequency >93% including PFCAs: C4-C12 perfluoroalkyl carboxylates, C4, C6, C8, and C10 perfluoroalkane sulfonates, perfluorooctane sulfonamides and perfluorooctane sulfonamide substances (FOSAMs), C10 perfluoroalkyl phosphonic acid (C10 PFPA), 6:2 fluorotelomer sulfonic acid (6:2 FTSA) and C8/C8 perfluoroalkyl phosphinic acid (C8/C8-PFPIA). The most abundant PFASs in water were PFBS (1.4-55 ng/L), PFBA (1.0-23 ng/L), PFOS (1.5-24 ng/L) and PFOA (2.0-21 ng/L). In the tributaries, PFNA concentrations ranged from 1.2 to 87.1 ng/L except in the May 2013 samples of two tributaries, which reached 520 and 260 ng/L. Total PFAS concentrations in the sediment samples ranged from 1.6 to 15 ng/g d.w. with EtFOSAA, PFDoA, PFOS and PFDA being the dominant species. Based on water and sediment data, two types of sources were inferred: one-time or intermittent point sources and continuous non-point sources. FOSAMs and PFOS released continually from non-point sources, C8/C8 PFPIA, PFDoA and PFUnA was released from point sources. The highly water soluble short-chain PFASs including PFBA, PFPeA and PFBS remained predominantly in the water column. The factors governing solution phase concentrations appear to be compound hydrophobicity and sorption to suspended particles. Correlation of the dissolved phase concentrations with precipitation data suggested stormwater was a significant source of PFBA, PFBS, PFUnA and PFDoA. Negative correlations with precipitation indicated sources feeding FOSAA and FOSA directly into the tributaries. Copyright © 2017 Elsevier Ltd. All rights reserved.

Multi-scale trends analysis of landscape stressors in an urbanizing coastal watershed

EPA Science Inventory

Anthropogenic land based stressors within a watershed can deliver major impacts to downstream and adjacent coastal waterways affecting water quality and estuarine habitats. Our research focused on a subset of non-point sources of watershed stressors specifically, human population...

Seasonal variation of nitrogen-concentration in the surface water and its relationship with land use in a catchment of northern China.

PubMed

Chen, Li-ding; Peng, Hong-jia; Fu, Bo-Jie; Qiu, Jun; Zhang, Shu-rong

2005-01-01

Surface waters can be contaminated by human activities in two ways: (1) by point sources, such as sewage treatment discharge and storm-water runoff; and (2) by non-point sources, such as runoff from urban and agricultural areas. With point-source pollution effectively controlled, non-point source pollution has become the most important environmental concern in the world. The formation of non-point source pollution is related to both the sources such as soil nutrient, the amount of fertilizer and pesticide applied, the amount of refuse, and the spatial complex combination of land uses within a heterogeneous landscape. Land-use change, dominated by human activities, has a significant impact on water resources and quality. In this study, fifteen surface water monitoring points in the Yuqiao Reservoir Basin, Zunhua, Hebei Province, northern China, were chosen to study the seasonal variation of nitrogen concentration in the surface water. Water samples were collected in low-flow period (June), high-flow period (July) and mean-flow period (October) from 1999 to 2000. The results indicated that the seasonal variation of nitrogen concentration in the surface water among the fifteen monitoring points in the rainfall-rich year is more complex than that in the rainfall-deficit year. It was found that the land use, the characteristics of the surface river system, rainfall, and human activities play an important role in the seasonal variation of N-concentration in surface water.

Volatile organic compounds in storm water from a parking lot

USGS Publications Warehouse

Lopes, T.J.; Fallon, J.D.; Rutherford, D.W.; Hiatt, M.H.

2000-01-01

A mass balance approach was used to determine the most important nonpoint source of volatile organic compounds (VOCs) in storm water from an asphalt parking lot without obvious point sources (e.g., gasoline stations). The parking lot surface and atmosphere are important nonpoint sources of VOCs, with each being important for different VOCs. The atmosphere is an important source of soluble, oxygenated VOCs (e.g., acetone), and the parking lot surface is an important source for the more hydrophobic VOCs (e.g., benzene). VOCs on the parking lot surface appear to be concentrated in oil and grease and organic material in urban particles (e.g., vehicle soot). Except in the case of spills, asphalt does not appear to be an important source of VOCs. The uptake isotherm of gaseous methyl tert-butyl ether on urban particles indicates a mechanism for dry deposition of VOCs from the atmosphere. This study demonstrated that a mass balance approach is a useful means of understanding non-point-source pollution, even for compounds such as VOCs, which are difficult to sample.

Wind-tunnel Modelling of Dispersion from a Scalar Area Source in Urban-Like Roughness

NASA Astrophysics Data System (ADS)

Pascheke, Frauke; Barlow, Janet F.; Robins, Alan

2008-01-01

A wind-tunnel study was conducted to investigate ventilation of scalars from urban-like geometries at neighbourhood scale by exploring two different geometries a uniform height roughness and a non-uniform height roughness, both with an equal plan and frontal density of λ p = λ f = 25%. In both configurations a sub-unit of the idealized urban surface was coated with a thin layer of naphthalene to represent area sources. The naphthalene sublimation method was used to measure directly total area-averaged transport of scalars out of the complex geometries. At the same time, naphthalene vapour concentrations controlled by the turbulent fluxes were detected using a fast Flame Ionisation Detection (FID) technique. This paper describes the novel use of a naphthalene coated surface as an area source in dispersion studies. Particular emphasis was also given to testing whether the concentration measurements were independent of Reynolds number. For low wind speeds, transfer from the naphthalene surface is determined by a combination of forced and natural convection. Compared with a propane point source release, a 25% higher free stream velocity was needed for the naphthalene area source to yield Reynolds-number-independent concentration fields. Ventilation transfer coefficients w T / U derived from the naphthalene sublimation method showed that, whilst there was enhanced vertical momentum exchange due to obstacle height variability, advection was reduced and dispersion from the source area was not enhanced. Thus, the height variability of a canopy is an important parameter when generalising urban dispersion. Fine resolution concentration measurements in the canopy showed the effect of height variability on dispersion at street scale. Rapid vertical transport in the wake of individual high-rise obstacles was found to generate elevated point-like sources. A Gaussian plume model was used to analyse differences in the downstream plumes. Intensified lateral and vertical plume spread and plume dilution with height was found for the non-uniform height roughness.

IMPERVIOUS SURFACES AND STREAMFLOW DISCHARGE: A HISTORICAL REMOTE SENSING PERSPECTIVE IN A NORTHERN VIRGINIA SUBWATERSHED

EPA Science Inventory

Impervious surfaces are a leading contributor to non-point-source water pollution in urban watersheds. These surfaces include such features as roads, parking lots, rooftops and driveways. Aerial photography provides a historical vehicle for determining impervious surface growth a...

Multi-Disciplinary Approach to Trace Contamination of Streams and Beaches

USGS Publications Warehouse

Nickles, James

2008-01-01

Concentrations of fecal-indicator bacteria in urban streams and ocean beaches in and around Santa Barbara occasionally can exceed public-health standards for recreation. The U.S. Geological Survey (USGS), working with the City of Santa Barbara, has used multi-disciplinary science to trace the sources of the bacteria. This research is helping local agencies take steps to improve recreational water quality. The USGS used an approach that combined traditional hydrologic and microbiological data, with state-of-the-art genetic, molecular, and chemical tracer analysis. This research integrated physical data on streamflow, ground water, and near-shore oceanography, and made extensive use of modern geophysical and isotopic techniques. Using those techniques, the USGS was able to evaluate the movement of water and the exchange of ground water with near-shore ocean water. The USGS has found that most fecal bacteria in the urban streams came from storm-drain discharges, with the highest concentrations occurring during storm flow. During low streamflow, the concentrations varied as much as three-fold, owing to variable contribution of non-point sources such as outdoor water use and urban runoff to streamflow. Fecal indicator bacteria along ocean beaches were from both stream discharge to the ocean and from non-point sources such as bird fecal material that accumulates in kelp and sand at the high-tide line. Low levels of human-specific Bacteroides, suggesting fecal material from a human source, were consistently detected on area beaches. One potential source, a local sewer line buried beneath the beach, was found not to be responsible for the fecal bacteria.

MULTI-SCALE REMOTE SENSING MAPPING OF ANTHROPOGENIC IMPERVIOUS SURFACES: SPATIAL AND TEMPORAL SCALING ISSUES RELATED TO ECOLOGICAL AND HYDROLOGICAL LANDSCAPE ANALYSES

EPA Science Inventory

Anthropogenic impervious surfaces are leading contributors to non-point-source water pollution in urban watersheds. These human-created surfaces include such features as roads, parking lots, rooftops, sideways, and driveways. Aerial photography provides a historical vehicle for...

USING GIS AND AERIAL PHOTOGRAPHY TO DETERMINE A HISTORICAL IMPERVIOUS SURFACE/STREAMFLOW RELATIONSHIP

EPA Science Inventory

Impervious surfaces are a leading contributor to non-point-source water pollution in urban watersheds. These surfaces include such features as roads, parking lots, rooftops and driveways. Arcview GIS and the Image Analysis extension have been utilized to geo-register and map imp...

SHEPHERD CREEK, CINCINNATI, OH: USING TRADABLE CREDITS TO CONTROL EXCESS STORMWATER RUNOFF

EPA Science Inventory

The problem of managing stormwater runoff grows apace with continued urbanization, yet the management tools for this growing non-point source problem have not fully kept up. The rapid growth of stormwater utilities around the nation is an important step toward providing an ef...

AN ACCURACY ASSESSMENT OF MULTIPLE MID-ATLANTIC SUB-PIXEL IMPERVIOUS SURFACE MAPS

EPA Science Inventory

Anthropogenic impervious surfaces have an important relationship with non-point source pollution (NPS) in urban watersheds. The amount of impervious surface area in a watershed is a key indicator of landscape change. As a single variable, it serves to integrate a number of conc...

MANAGING MICROBIAL CONTAMINATION IN URBAN WATERSHEDS

EPA Science Inventory

This paper presents different approaches for controlling pathogen contamination in urban watersheds for contamination resulting from point and diffuse sources. Point sources of pathogens can be treated by a disinfection technology of known effectiveness, and a desired reduction ...

MANAGING MICROBIAL CONTAMINATION IN URBAN WATERSHEDS

EPA Science Inventory

This paper presents different approaches for controlling pathogen contamination in urban watersheds for contamination resulting from point and diffuses sources. Point sources of pathogens can be treated by a disinfection technology of known effectiveness, and a desired reduction ...

Preliminary assessment of the occurrence and possible sources of MTBE in groundwater in the United States, 1993-1994

USGS Publications Warehouse

Squillace, P.J.; Zogorski, J.S.; Wilber, W.G.; Price, C.V.

1996-01-01

The 1990 Clean Air Act Amendments require fuel oxygenates to be added to gasoline used in some metropolitan areas to reduce atmospheric concentrations of carbon monoxide or ozone. Methyl tert-butyl ether (MTBE) is the most commonly used fuel oxygenate and is a relatively new gasoline additive. Nevertheless, out of 60 volatile organic chemicals analyzed, MTBE was the second most frequently detected chemical in samples of shallow ambient groundwater from urban areas that were collected during 1993-1994 aspart of the U.S. Geological Survey's National Water-Quality Assessment program. Samples were collected from five drinking water wells, 12 springs, and 193 monitoring wells in urban areas. No MTBE was detected in drinking water wells. At a reporting level of 0.2 ??g/L, MTBE was detected most frequently in shallow groundwater from urban areas (27% of 210 wells and springs sampled in eight areas) as compared to shallow groundwater from agricultural areas (1.3% of 549 wells sampled in 21 areas) or deeper groundwater from major aquifers (1.0% of 412 wells sampled in nine areas). Only 3% of the shallow wells sampled in urban areas had concentrations of MTBE that exceed 20 ??g/L, which is the estimated lower limit of the United States Environmental Protection Agency draft drinking water health advisory. Because MTBE is persistent and mobile in groundwater, it can move from shallow to deeper aquifers with time. In shallow urban groundwater, MTBE generally was not found with benzene, toluene, ethylbenzene, or xylene (BTEX) compounds, which commonly are associated with gasoline spills. This disassociation causes uncertainty as to the source of MTBE. Possible sources of MTBE in groundwater include point sources, such as leaking storage tanks, and non-point sources, such as recharge of precipitation and stormwater runoff.

Automatic co-registration of 3D multi-sensor point clouds

NASA Astrophysics Data System (ADS)

Persad, Ravi Ancil; Armenakis, Costas

2017-08-01

We propose an approach for the automatic coarse alignment of 3D point clouds which have been acquired from various platforms. The method is based on 2D keypoint matching performed on height map images of the point clouds. Initially, a multi-scale wavelet keypoint detector is applied, followed by adaptive non-maxima suppression. A scale, rotation and translation-invariant descriptor is then computed for all keypoints. The descriptor is built using the log-polar mapping of Gabor filter derivatives in combination with the so-called Rapid Transform. In the final step, source and target height map keypoint correspondences are determined using a bi-directional nearest neighbour similarity check, together with a threshold-free modified-RANSAC. Experiments with urban and non-urban scenes are presented and results show scale errors ranging from 0.01 to 0.03, 3D rotation errors in the order of 0.2° to 0.3° and 3D translation errors from 0.09 m to 1.1 m.

Microbial Source Module (MSM): Documenting the Science ...

EPA Pesticide Factsheets

The Microbial Source Module (MSM) estimates microbial loading rates to land surfaces from non-point sources, and to streams from point sources for each subwatershed within a watershed. A subwatershed, the smallest modeling unit, represents the common basis for information consumed and produced by the MSM which is based on the HSPF (Bicknell et al., 1997) Bacterial Indicator Tool (EPA, 2013b, 2013c). Non-point sources include numbers, locations, and shedding rates of domestic agricultural animals (dairy and beef cows, swine, poultry, etc.) and wildlife (deer, duck, raccoon, etc.). Monthly maximum microbial storage and accumulation rates on the land surface, adjusted for die-off, are computed over an entire season for four land-use types (cropland, pasture, forest, and urbanized/mixed-use) for each subwatershed. Monthly point source microbial loadings to instream locations (i.e., stream segments that drain individual sub-watersheds) are combined and determined for septic systems, direct instream shedding by cattle, and POTWs/WWTPs (Publicly Owned Treatment Works/Wastewater Treatment Plants). The MSM functions within a larger modeling system that characterizes human-health risk resulting from ingestion of water contaminated with pathogens. The loading estimates produced by the MSM are input to the HSPF model that simulates flow and microbial fate/transport within a watershed. Microbial counts within recreational waters are then input to the MRA-IT model (Soller et

Monitoring for Pesticides in Groundwater and Surface Water in Nevada, 2008

USGS Publications Warehouse

Thodal, Carl E.; Carpenter, Jon; Moses, Charles W.

2009-01-01

Commercial pesticide applicators, farmers, and homeowners apply about 1 billion pounds of pesticides annually to agricultural land, non-crop land, and urban areas throughout the United States (Gilliom and others, 2006, p. 1). The U.S. Environmental Protection Agency (USEPA) defines a pesticide as any substance used to kill or control insects, weeds, plant diseases, and other pest organisms. Although there are important benefits from the proper use of pesticides, like crop protection and prevention of human disease outbreaks, there are also risks. One risk is the contamination of groundwater and surface-water resources. Data collected during 1992-2001 from 51 major hydrologic systems across the United States indicate that one or more pesticide or pesticide breakdown product was detected in more than 50 percent of 5,057 shallow (less than 20 feet below land surface) wells and in all of the 186 stream sites that were sampled in agricultural and urban areas (Gilliom and others, 2006, p. 2-4). Pesticides can contaminate surface water and groundwater from both point sources and non-point sources. Point sources are from specific locations such as spill sites, disposal sites, pesticide drift during application, and application of pesticides to control aquatic pests. Non-point sources represent the dominant source of surface water and groundwater contamination and may include agricultural and urban runoff, erosion, leaching from application sites, and precipitation that has become contaminated by upwind applications. Pesticides typically enter surface water when rainfall or irrigation exceeds the infiltration capacity of soil and resulting runoff then transports pesticides to streams, rivers, and other surface-water bodies. Contamination of groundwater may result directly from spills near poorly sealed well heads and from pesticide applications through improperly designed or malfunctioning irrigation systems that also are used to apply pesticides (chemigation; Carpenter and Johnson, 1997). Groundwater contamination also may come indirectly by the percolation of agricultural and urban irrigation water through soil layers and into groundwater and from pesticide residue in surface water, such as drainage ditches, streams, and municipal wastewater. To protect surface water and groundwater from pesticide contamination, the USEPA requires that all states establish a pesticide management plan. The Nevada Department of Agriculture (NDOA), with assistance from the USEPA, developed a management program of education (Hefner and Donaldson, 2006), regulation (Johnson and others, 2006), and monitoring (Pennington and others, 2001) to protect Nevada's water resources from pesticide contaminants. Sampling sites are located in areas where urban or agricultural pesticide use may affect groundwater, water bodies, endangered species, and other aquatic life. Information gathered from these sites is used by NDOA to help make regulatory decisions that will protect human and environmental health by reducing and eliminating the occurrence of pesticide contamination. This fact sheet describes current (2008) pesticide monitoring of groundwater and streams by the NDOA in Nevada and supersedes Pennington and others (2001).

CONFIRMING THE RESULTS: AN ACCURACY ASSESSMENT OF REMOTE PRODUCTS, AN EXAMPLE COMPARING MULTIPLE MID-ATLANTIC SUB-PIXEL IMPERVIOUS SURFACE MAPS

EPA Science Inventory

Anthropogenic impervious surfaces have an important relationship with non-point source pollution (NPS) in urban watersheds. The amount of impervious surface area in a watershed is a key indicator of landscape change. As a single variable, it serves to intcgrate a number of concur...

[Regulation framework of watershed landscape pattern for non-point source pollution control based on 'source-sink' theory: A case study in the watershed of Maluan Bay, Xiamen City, China].

PubMed

Huang, Ning; Wang, Hong Ying; Lin, Tao; Liu, Qi Ming; Huang, Yun Feng; Li, Jian Xiong

2016-10-01

Watershed landscape pattern regulation and optimization based on 'source-sink' theory for non-point source pollution control is a cost-effective measure and still in the exploratory stage. Taking whole watershed as the research object, on the basis of landscape ecology, related theories and existing research results, a regulation framework of watershed landscape pattern for non-point source pollution control was developed at two levels based on 'source-sink' theory in this study: 1) at watershed level: reasonable basic combination and spatial pattern of 'source-sink' landscape was analyzed, and then holistic regulation and optimization method of landscape pattern was constructed; 2) at landscape patch level: key 'source' landscape was taken as the focus of regulation and optimization. Firstly, four identification criteria of key 'source' landscape including landscape pollutant loading per unit area, landscape slope, long and narrow transfer 'source' landscape, pollutant loading per unit length of 'source' landscape along the riverbank were developed. Secondly, nine types of regulation and optimization methods for different key 'source' landscape in rural and urban areas were established, according to three regulation and optimization rules including 'sink' landscape inlay, banding 'sink' landscape supplement, pollutants capacity of original 'sink' landscape enhancement. Finally, the regulation framework was applied for the watershed of Maluan Bay in Xiamen City. Holistic regulation and optimization mode of watershed landscape pattern of Maluan Bay and key 'source' landscape regulation and optimization measures for the three zones were made, based on GIS technology, remote sensing images and DEM model.

The effects of urbanization on the hydrochemistry of base flow within the Chattahoochee River Basin (Georgia, USA)

NASA Astrophysics Data System (ADS)

Rose, Seth

2007-07-01

SummaryA comprehensive network of stream data ( n = 50) was used to assess the effects of urbanization upon the hydrochemical variation within base flow in the Chattahoochee River Basin (CRB), Georgia (USA). Base flow solute concentrations (particularly sulfate, chloride, bicarbonate alkalinity, and sodium) increase with the degree of urbanization and any degree of urbanization within the Atlanta Metropolitan Region (AMR) results in elevated base flow solute concentrations. This suggests that there are pervasive low-level non-point sources of contamination such as septic tanks systems and leaky sewer lines affecting the chemistry of shallow groundwater throughout much of the AMR and CRB. Six groups or subsets representing the "rural-to-urban gradient" were defined, characterized by the following order of increasing solute concentrations: rural basins < Chattahoochee River. semi-urbanized basins < urbanized basins < urban basins with main sewer trunk lines < urbanized basins directly receiving treated effluent and combined sewer overflow (CSO) basins. There is a strong and unusual basin-wide correlation ( r2 values >0.79) between Na-K-Cl within the CRB that likely reflects the widespread input of electrolytes present in human wastes and wastewater. The most likely source and pathway for contaminant input involves the mobilization of salts, originally present in waste water, within the riparian or hypoheric zone.

Assessing the sources of high fecal coliform levels at an urban tropical beach

PubMed Central

Davino, Aline Mendonça Cavalcante; de Melo, Milena Bandeira; Caffaro, Roberto Augusto

2015-01-01

Recreational water quality is commonly assessed by microbial indicators such as fecal coliforms. Maceió is the capital of Alagoas state, located in tropical northeastern Brazil. Its beaches are considered as the most beautiful urban beaches in the country. Jatiúca Beach in Maceió was found to be unsuitable for bathing continuously during the year of 2011. The same level of contamination was not observed in surrounding beaches. The aim of this study was to initiate the search for the sources of these high coliform levels, so that contamination can be eventually mitigated. We performed a retrospective analysis of historical results of fecal coliform concentrations from 2006 to 2012 at five monitoring stations located in the study region. Results showed that Jatiúca Beach consistently presented the worst quality among the studied beaches. A field survey was conducted to identify existing point and non-point sources of pollution in the area. Monitoring in the vicinity of Jatiúca was spatially intensified. Fecal coliform concentrations were categorized according to tide range and tide stage. A storm drain located in northern Jatiúca was identified as the main point source of the contamination. However, fecal coliform concentrations at Jatiúca were high during high tides and spring tides even when this point source was inactive (no rainfall). We hypothesize that high fecal coliform levels in Jatiúca Beach may also be caused by aquifer contamination or, more likely, from tide washing of contaminated sand. Both of these hypotheses will be further investigated. PMID:26691459

Assessing the sources of high fecal coliform levels at an urban tropical beach.

PubMed

Davino, Aline Mendonça Cavalcante; de Melo, Milena Bandeira; Caffaro Filho, Roberto Augusto

2015-01-01

Recreational water quality is commonly assessed by microbial indicators such as fecal coliforms. Maceió is the capital of Alagoas state, located in tropical northeastern Brazil. Its beaches are considered as the most beautiful urban beaches in the country. Jatiúca Beach in Maceió was found to be unsuitable for bathing continuously during the year of 2011. The same level of contamination was not observed in surrounding beaches. The aim of this study was to initiate the search for the sources of these high coliform levels, so that contamination can be eventually mitigated. We performed a retrospective analysis of historical results of fecal coliform concentrations from 2006 to 2012 at five monitoring stations located in the study region. Results showed that Jatiúca Beach consistently presented the worst quality among the studied beaches. A field survey was conducted to identify existing point and non-point sources of pollution in the area. Monitoring in the vicinity of Jatiúca was spatially intensified. Fecal coliform concentrations were categorized according to tide range and tide stage. A storm drain located in northern Jatiúca was identified as the main point source of the contamination. However, fecal coliform concentrations at Jatiúca were high during high tides and spring tides even when this point source was inactive (no rainfall). We hypothesize that high fecal coliform levels in Jatiúca Beach may also be caused by aquifer contamination or, more likely, from tide washing of contaminated sand. Both of these hypotheses will be further investigated.

Composition and sources of fine particulate matter across urban and rural sites in the Midwestern United States

PubMed Central

Kundu, Shuvashish; Stone, Elizabeth. A.

2014-01-01

The composition and sources of fine particulate matter (PM2.5) were investigated in rural and urban locations in Iowa, located in the agricultural and industrial Midwestern United States from April 2009 to December 2012. Major chemical contributors to PM2.5 mass were sulfate, nitrate, ammonium, and organic carbon. Non-parametric statistical analyses demonstrated that the two rural sites had significantly enhanced levels of crustal materials (Si, Al) driven by agricultural activities and unpaved roads. Meanwhile, the three urban areas had enhanced levels of secondary aerosol (nitrate, sulfate, and ammonium) and combustion (organic and elemental carbon). The heavily industrialized Davenport site had significantly higher levels of PM2.5 and trace metals (Fe, Pb, Zn), demonstrating the important local impact of industrial point sources on air quality. Sources of PM2.5 were evaluated by the multi-variant positive matrix factorization (PMF) source apportionment model. For each individual site, seven to nine factors were identified: secondary sulfate (accounting for 29–30% of PM2.5), secondary nitrate (17–24%), biomass burning (9–21%), gasoline combustion (6–16), diesel combustion (3–9%), dust (6–11%), industry (0.4–5%) and winter salt (2–6%). Source contributions demonstrated a clear urban enhancement in PM2.5 from gasoline engines (by a factor of 1.14) and diesel engines (by a factor of 2.3), which is significant due to the well-documented negative health impacts of vehicular emissions. This study presents the first source apportionment results from the state of Iowa and is broadly applicable to understanding the differences in anthropogenic and natural sources in the urban-rural continuum of particle air pollution. PMID:24736797

[Urban non-point source pollution control by runoff retention and filtration pilot system].

PubMed

Bai, Yao; Zuo, Jian-E; Gan, Li-Li; Low, Thong Soon; Miao, Heng-Feng; Ruan, Wen-Quan; Huang, Xia

2011-09-01

A runoff retention and filtration pilot system was designed and the long-term purification effect of the runoff was monitored. Runoff pollution characters in 2 typical events and treatment effect of the pilot system were analyzed. The results showed that the runoff was severely polluted. Event mean concentrations (EMCs) of SS, COD, TN and TP in the runoff were 361, 135, 7.88 and 0.62 mg/L respectively. The runoff formed by long rain presented an obvious first flush effect. The first 25% flow contributed more than 50% of the total pollutants loading of SS, TP, DTP and PO4(3-). The pilot system could reduce 100% of the non-point source pollution if the volume of the runoff was less than the retention tank. Otherwise the overflow will be purification by the filtration pilot system and the removal rates of SS, COD, TN, TP, DTP and PO4(3-) reached 97.4% , 61.8%, 22.6%, 85.1%, 72.1%, and 85.2% respectively. The system was stable and the removal rate of SS, COD, TN, and TP were 98.6%, 65.4%, 55.1% and 92.6%. The whole system could effectively remove the non-point source pollution caused by runoff.

Evaluating the Effects of Land Use Planning for Non-Point Source Pollution Based on a System Dynamics Approach in China

PubMed Central

Kuai, Peng; Li, Wei; Liu, Nianfeng

2015-01-01

Urbanization is proceeding rapidly in several developing countries such as China. This accelerating urbanization alters the existing land use types in a way that results in more Non-Point Source (NPS) pollution to local surface waters. Reasonable land use planning is necessary. This paper compares seven planning scenarios of a case study area, namely Wulijie, China, from the perspective of NPS pollution. A System Dynamics (SD) model was built for the comparison to adequately capture the planning complexity. These planning scenarios, which were developed by combining different land use intensities (LUIs) and construction speeds (CSs), were then simulated. The results show that compared to scenario S1 (business as usual) all other scenarios will introduce more NPS pollution (with an incremental rate of 22%-70%) to Wulijie. Scenario S6 was selected as the best because it induced relatively less NPS pollution while simultaneously maintaining a considerable development rate. Although LUIs represent a more critical factor compared to CSs, we conclude that both LUIs and CSs need to be taken into account to make the planning more environmentally friendly. Considering the power of SD in decision support, it is recommended that land use planning should take into consideration findings acquired from SD simulations. PMID:26267482

Monitoring Stream Nutrient Concentration Trends in a Mixed-Land-Use Watershed

NASA Astrophysics Data System (ADS)

Zeiger, S. J.; Hubbart, J. A.

2014-12-01

Mixed-land use watersheds are often a complex patchwork of forested, agricultural, and urban land-uses where differential land-use mediated non-point source pollution can significantly impact water quality. Stream nitrogen and phosphorus concentrations serve as important variables for quantifying land use effects on non-point source pollution in receiving waters and relative impacts on aquatic biota. The Hinkson Creek Watershed (HCW) is a representative mixed land use urbanizing catchment (231 km2) located in central Missouri, USA. A nested-scale experimental watershed study including five permanent hydroclimate stations was established in 2009 to provide quantitative understanding of multiple land use impacts on nutrient loading. Spectrophotometric analysis was used to quantify total inorganic nitrogen (TIN) and total phosphorus (TP as PO4) regimes. Results (2010 - 2013) indicate average nitrate (NO3-) concentration (mg/l) range of 0.28 to 0.46 mg/l, nitrite (NO2-) range of 0.02 to 0.03 mg/l, ammonia (NH3) ranged from 0.04 to 0.08 mg/l, and TP range of 0.26 to 0.39 mg/l. With n=858, NO3-, NO2-, NH3, and TP concentrations were significantly (CI=95%, p=0.00) higher in the subbasin with the greatest percent cumulative agricultural land use (57%). NH3 and TP concentrations were significantly (CI=95%, p=0.00) higher (with the exception of the agricultural subbasin) in the subbasin with the greatest percent cumulative urban land use (26%). Results from multiple regression analyses showed percent cumulative agricultural and urban land uses accounted for 85% and 96% of the explained variance in TIN loading (CI=95%, p=0.08) and TP loading (CI=95%, p=0.02), respectively, between gauging sites. These results improve understanding of agricultural and urban land use impacts on nutrient concentrations in mixed use watersheds of the Midwest and have implications for nutrient reduction programs in the Mississippi River Basin and hypoxia reductions in the Gulf of Mexico, USA.

Structure-From for Calibration of a Vehicle Camera System with Non-Overlapping Fields-Of in AN Urban Environment

NASA Astrophysics Data System (ADS)

Hanel, A.; Stilla, U.

2017-05-01

Vehicle environment cameras observing traffic participants in the area around a car and interior cameras observing the car driver are important data sources for driver intention recognition algorithms. To combine information from both camera groups, a camera system calibration can be performed. Typically, there is no overlapping field-of-view between environment and interior cameras. Often no marked reference points are available in environments, which are a large enough to cover a car for the system calibration. In this contribution, a calibration method for a vehicle camera system with non-overlapping camera groups in an urban environment is described. A-priori images of an urban calibration environment taken with an external camera are processed with the structure-frommotion method to obtain an environment point cloud. Images of the vehicle interior, taken also with an external camera, are processed to obtain an interior point cloud. Both point clouds are tied to each other with images of both image sets showing the same real-world objects. The point clouds are transformed into a self-defined vehicle coordinate system describing the vehicle movement. On demand, videos can be recorded with the vehicle cameras in a calibration drive. Poses of vehicle environment cameras and interior cameras are estimated separately using ground control points from the respective point cloud. All poses of a vehicle camera estimated for different video frames are optimized in a bundle adjustment. In an experiment, a point cloud is created from images of an underground car park, as well as a point cloud of the interior of a Volkswagen test car is created. Videos of two environment and one interior cameras are recorded. Results show, that the vehicle camera poses are estimated successfully especially when the car is not moving. Position standard deviations in the centimeter range can be achieved for all vehicle cameras. Relative distances between the vehicle cameras deviate between one and ten centimeters from tachymeter reference measurements.

The urban atmosphere as a non-point source for the transport of MTBE and other volatile organic compounds (VOCS) to shallow groundwater

USGS Publications Warehouse

Pankow, J.F.; Thomson, N.R.; Johnson, Richard L.; Baehr, A.L.; Zogorski, J.S.

1997-01-01

Infiltration and dispersion (including molecular diffusion) can transport volatile organic compounds (VOCs) from urban air into shallow groundwater. The gasoline additive methyl-tert-butyl ether (MTBE) is of special interest because of its (1) current levels in some urban air, (2) strong partitioning from air into water, (3) resistance to degradation, (4) use as an octane-booster since the 1970s, (5) rapidly increasing use in the 1990s to reduce CO and O3 in urban air, and (6) its frequent detection at low microgram per liter levels in shallow urban groundwater in Denver, New England, and elsewhere. Numerical simulations were conducted using a 1-D model domain set in medium sand (depth to water table = 5 m) to provide a test of whether MTBE and other atmospheric VOCs could move to shallow groundwater within the 10−15 y time frame over which MTBE has now been used in large amounts. Degradation and sorption were assumed negligible. In case 1 (no infiltration, steady atmospheric source), 10 y was not long enough to permit significant VOC movement by diffusion into shallow groundwater. Case 2 considered a steady atmospheric source plus 36 cm/y of net infiltration; groundwater at 2 m below the water table became nearly saturated with atmospheric levels of VOC within 5 y. Case 3 was similar to case 2, but considered the source to be seasonal, being “on” for only 5 of 12 months each year, as with the use of MTBE during the winter fuel-oxygenate season; groundwater at 2 m below the water table became equilibrated with 5/12 of the “source-on” concentration within 5 y. Cases 4 and 5 added an evapotranspiration (ET) loss of 36 cm/y, resulting in no net recharge. Case 4 took the ET from the surface, and case 5 took the ET from the capillary fringe at a depth of 3.5 m. Net VOC mass transfer to shallow groundwater after 5 y was less for both cases 4 and 5 than for case 3. However, it was significantly greater for cases 4 and 5 than for case 1, even though cases 1, 4, and 5 were all no-net recharge cases. The mechanism responsible for this effect was the dispersion acting on each downward infiltration event, and also on the ET-induced flow. The ability of MTBE to reach groundwater in cases 2−5 is taken as evidence of the potential importance of urban air as a non-point source for VOCs in shallow urban groundwater. Two subcases were run for both case 4 and case 5:  subcase a (water and VOCs move with ET) and subcase b (water only moves with ET).

Nutrient Mass Balance for the Mobile River Basin in Alabama, Georgia, and Mississippi

NASA Astrophysics Data System (ADS)

Harned, D. A.; Harvill, J. S.; McMahon, G.

2001-12-01

The source and fate of nutrients in the Mobile River drainage basin are important water-quality concerns in Alabama, Georgia, and Mississippi. Land cover in the basin is 74 percent forested, 16 percent agricultural, 2.5 percent developed, and 4 percent wetland. A nutrient mass balance calculated for 18 watersheds in the Mobile River Basin indicates that agricultural non-point nitrogen and phosphorus sources and urban non-point nitrogen sources are the most important factors associated with nutrients in the streams. Nitrogen and phosphorus inputs from atmospheric deposition, crop fertilizer, biological nitrogen fixation, animal waste, and point sources were estimated for each of the 18 drainage basins. Total basin nitrogen inputs ranged from 27 to 93 percent from atmospheric deposition (56 percent mean), 4 to 45 percent from crop fertilizer (25 percent mean), <0.01 to 31 percent from biological nitrogen fixation (8 percent mean), 2 to 14 percent from animal waste (8 percent mean), and 0.2 to 11 percent from point sources (3 percent mean). Total basin phosphorus inputs ranged from 10 to 39 percent from atmospheric deposition (26 percent mean), 7 to 51 percent from crop fertilizer (28 percent mean), 20 to 64 percent from animal waste (41 percent mean), and 0.2 to 11 percent from point sources (3 percent mean). Nutrient outputs for the watersheds were estimated by calculating instream loads and estimating nutrient uptake, or withdrawal, by crops. The difference between the total basin inputs and outputs represents nutrients that are retained or processed within the basin while moving from the point of use to the stream, or in the stream. Nitrogen output, as a percentage of the total basin nitrogen inputs, ranged from 19 to 79 percent for instream loads (35 percent mean) and from 0.01 to 32 percent for crop harvest (10 percent mean). From 53 to 87 percent (75 percent mean) of nitrogen inputs were retained within the 18 basins. Phosphorus output ranged from 9 to 29 percent for instream loads (18 percent mean) and from 0.01 to 23 percent for crop harvest (7 percent mean). The basins retained from 60 to 87 percent (74 percent mean) of phosphorous inputs. Correlation of basin nutrient output loads and concentrations with the basin inputs and correlation of output loads and concentrations with basin land use were tested using the Spearman rank test. The correlation analysis indicated that higher nitrogen concentrations in the streams are associated with urban areas and higher loads are associated with agriculture; high phosphorus output loads and concentrations are associated with agriculture. Higher nutrient loads in agricultural basins are partly an effect of basin size-- larger basins generate larger nutrient loads. Nutrient loads and concentrations showed no significant correlation to point-source inputs. Nitrogen loads were significantly (p<0.05, correlation coefficient >0.5) higher in basins with greater cropland areas. Nitrogen concentrations also increased as residential, commercial, and total urban areas increased. Phosphorus loads were positively correlated with animal-waste inputs, pasture, and total agricultural land. Phosphorus concentrations were highest in basins with the greatest amounts of row-crop agriculture.

Probabilistic Analysis of Earthquake-Led Water Contamination: A Case of Sichuan, China

NASA Astrophysics Data System (ADS)

Yang, Yan; Li, Lin; Benjamin Zhan, F.; Zhuang, Yanhua

2016-06-01

The objective of this paper is to evaluate seismic-led point source and non-point source water pollution, under the seismic hazard of 10 % probability of exceedance in 50 years, and with the minimum value of the water quality standard in Sichuan, China. The soil conservation service curve number method of calculating the runoff depth in the single rainfall event combined with the seismic damage index were applied to estimate the potential degree of non-point source water pollution. To estimate the potential impact of point source water pollution, a comprehensive water pollution evaluation framework is constructed using a combination of Water Quality Index and Seismic Damage Index methods. The four key findings of this paper are: (1) The water catchment that has the highest factory concentration does not have the highest risk of non-point source water contamination induced by the outbreak of potential earthquake. (2) The water catchment that has the highest numbers of cumulative water pollutants types are typically located in the south western parts of Sichuan where the main river basins in the regions flow through. (3) The most common pollutants in sample factories studied is COD and NH3-N which are found in all catchments. The least common pollutant is pathogen—found present in W1 catchment which has the best rating in the water quality index. (4) Using water quality index as a standardization parameter, parallel comparisons is made among the 16 water catchments. Only catchment W1 reaches level II water quality status which has the rating of moderately polluted in events of earthquake induced water contamination. All other areas suffer from severe water contamination with multiple pollution sources. The results from the data model are significant to urban planning commissions and businesses to strategically choose their factory locations in order to minimize potential hazardous impact during the outbreak of earthquake.

Aquatic exposures of chemical mixtures in urban environments: Approaches to impact assessment.

PubMed

de Zwart, Dick; Adams, William; Galay Burgos, Malyka; Hollender, Juliane; Junghans, Marion; Merrington, Graham; Muir, Derek; Parkerton, Thomas; De Schamphelaere, Karel A C; Whale, Graham; Williams, Richard

2018-03-01

Urban regions of the world are expanding rapidly, placing additional stress on water resources. Urban water bodies serve many purposes, from washing and sources of drinking water to transport and conduits for storm drainage and effluent discharge. These water bodies receive chemical emissions arising from either single or multiple point sources, diffuse sources which can be continuous, intermittent, or seasonal. Thus, aquatic organisms in these water bodies are exposed to temporally and compositionally variable mixtures. We have delineated source-specific signatures of these mixtures for diffuse urban runoff and urban point source exposure scenarios to support risk assessment and management of these mixtures. The first step in a tiered approach to assessing chemical exposure has been developed based on the event mean concentration concept, with chemical concentrations in runoff defined by volumes of water leaving each surface and the chemical exposure mixture profiles for different urban scenarios. Although generalizations can be made about the chemical composition of urban sources and event mean exposure predictions for initial prioritization, such modeling needs to be complemented with biological monitoring data. It is highly unlikely that the current paradigm of routine regulatory chemical monitoring alone will provide a realistic appraisal of urban aquatic chemical mixture exposures. Future consideration is also needed of the role of nonchemical stressors in such highly modified urban water bodies. Environ Toxicol Chem 2018;37:703-714. © 2017 The Authors. Environmental Toxicology and Chemistry published by Wiley Periodicals, Inc. on behalf of SETAC. © 2017 The Authors. Environmental Toxicology and Chemistry published by Wiley Periodicals, Inc. on behalf of SETAC.

A framework for emissions source apportionment in industrial areas: MM5/CALPUFF in a near-field application.

PubMed

Ghannam, K; El-Fadel, M

2013-02-01

This paper examines the relative source contribution to ground-level concentrations of carbon monoxide (CO), nitrogen dioxide (NO2), and PM10 (particulate matter with an aerodynamic diameter < 10 microm) in a coastal urban area due to emissions from an industrial complex with multiple stacks, quarrying activities, and a nearby highway. For this purpose, an inventory of CO, oxide of nitrogen (NO(x)), and PM10 emissions was coupled with the non-steady-state Mesoscale Model 5/California Puff Dispersion Modeling system to simulate individual source contributions under several spatial and temporal scales. As the contribution of a particular source to ground-level concentrations can be evaluated by simulating this single-source emissions or otherwise total emissions except that source, a set of emission sensitivity simulations was designed to examine if CALPUFF maintains a linear relationship between emission rates and predicted concentrations in cases where emitted plumes overlap and chemical transformations are simulated. Source apportionment revealed that ground-level releases (i.e., highway and quarries) extended over large areas dominated the contribution to exposure levels over elevated point sources, despite the fact that cumulative emissions from point sources are higher. Sensitivity analysis indicated that chemical transformations of NO(x) are insignificant, possibly due to short-range plume transport, with CALPUFF exhibiting a linear response to changes in emission rate. The current paper points to the significance of ground-level emissions in contributing to urban air pollution exposure and questions the viability of the prevailing paradigm of point-source emission reduction, especially that the incremental improvement in air quality associated with this common abatement strategy may not accomplish the desirable benefit in terms of lower exposure with costly emissions capping. The application of atmospheric dispersion models for source apportionment helps in identifying major contributors to regional air pollution. In industrial urban areas where multiple sources with different geometry contribute to emissions, ground-level releases extended over large areas such as roads and quarries often dominate the contribution to ground-level air pollution. Industrial emissions released at elevated stack heights may experience significant dilution, resulting in minor contribution to exposure at ground level. In such contexts, emission reduction, which is invariably the abatement strategy targeting industries at a significant investment in control equipment or process change, may result in minimal return on investment in terms of improvement in air quality at sensitive receptors.

Impact of Climate Variability and Landscape Patterns on Water Budget and Nutrient Loads in a Peri-urban Watershed: A Coupled Analysis Using Process-based Hydrological Model and Landscape Indices.

PubMed

Li, Chongwei; Zhang, Yajuan; Kharel, Gehendra; Zou, Chris B

2018-06-01

Nutrient discharge into peri-urban streams and reservoirs constitutes a significant pressure on environmental management, but quantitative assessment of non-point source pollution under climate variability in fast changing peri-urban watersheds is challenging. Soil and Water Assessment Tool (SWAT) was used to simulate water budget and nutrient loads for landscape patterns representing a 30-year progression of urbanization in a peri-urban watershed near Tianjin metropolis, China. A suite of landscape pattern indices was related to nitrogen (N) and phosphorous (P) loads under dry and wet climate using CANOCO redundancy analysis. The calibrated SWAT model was adequate to simulate runoff and nutrient loads for this peri-urban watershed, with Nash-Sutcliffe coefficient (NSE) and coefficient of determination (R 2 ) > 0.70 and percentage bias (PBIAS) between -7 and +18 for calibration and validation periods. With the progression of urbanization, forest remained the main "sink" landscape while cultivated and urban lands remained the main "source" landscapes with the role of orchard and grassland being uncertain and changing with time. Compared to 1984, the landscape use pattern in 2013 increased nutrient discharge by 10%. Nutrient loads modelled under wet climate were 3-4 times higher than that under dry climate for the same landscape pattern. Results indicate that climate change could impose a far greater impact on runoff and nutrient discharge in a peri-urban watershed than landscape pattern change.

Impact of Climate Variability and Landscape Patterns on Water Budget and Nutrient Loads in a Peri-urban Watershed: A Coupled Analysis Using Process-based Hydrological Model and Landscape Indices

NASA Astrophysics Data System (ADS)

Li, Chongwei; Zhang, Yajuan; Kharel, Gehendra; Zou, Chris B.

2018-06-01

Nutrient discharge into peri-urban streams and reservoirs constitutes a significant pressure on environmental management, but quantitative assessment of non-point source pollution under climate variability in fast changing peri-urban watersheds is challenging. Soil and Water Assessment Tool (SWAT) was used to simulate water budget and nutrient loads for landscape patterns representing a 30-year progression of urbanization in a peri-urban watershed near Tianjin metropolis, China. A suite of landscape pattern indices was related to nitrogen (N) and phosphorous (P) loads under dry and wet climate using CANOCO redundancy analysis. The calibrated SWAT model was adequate to simulate runoff and nutrient loads for this peri-urban watershed, with Nash-Sutcliffe coefficient (NSE) and coefficient of determination ( R 2) > 0.70 and percentage bias (PBIAS) between -7 and +18 for calibration and validation periods. With the progression of urbanization, forest remained the main "sink" landscape while cultivated and urban lands remained the main "source" landscapes with the role of orchard and grassland being uncertain and changing with time. Compared to 1984, the landscape use pattern in 2013 increased nutrient discharge by 10%. Nutrient loads modelled under wet climate were 3-4 times higher than that under dry climate for the same landscape pattern. Results indicate that climate change could impose a far greater impact on runoff and nutrient discharge in a peri-urban watershed than landscape pattern change.

Applying the Manning equation to determine the critical distance in non-point source pollution using remotely sensed data and cartographic modelling

NASA Astrophysics Data System (ADS)

de Oliveira, Lília M.; Santos, Nádia A. P.; Maillard, Philippe

2013-10-01

Non-point source pollution (NPSP) is perhaps the leading cause of water quality problems and one of the most challenging environmental issues given the difficulty of modeling and controlling it. In this article, we applied the Manning equation, a hydraulic concept, to improve models of non-point source pollution and determine its influence as a function of slope - land cover roughness for runoff to reach the stream. In our study the equation is somewhat taken out of its usual context to be applies to the flow of an entire watershed. Here a digital elevation model (DEM) from the SRTM satellite was used to compute the slope and data from the RapidEye satellite constellation was used to produce a land cover map later transformed into a roughness surface. The methodology is applied to a 1433 km2 watershed in Southeast Brazil mostly covered by forest, pasture, urban and wetlands. The model was used to create slope buffer of varying width in which the proportions of land cover and roughness coefficient were obtained. Next we correlated these data, through regression, with four water quality parameters measured in situ: nitrate, phosphorous, faecal coliform and turbidity. We compare our results with the ones obtained by fixed buffer. It was found that slope buffer outperformed fixed buffer with higher coefficients of determination up to 15%.

Current research trend on urban sewerage system in China

NASA Astrophysics Data System (ADS)

Ning, Yun-Fang; Dong, Wen-Yi; Lin, Lu-Sheng; Zhang, Qian

2017-03-01

The research emphasis has always been on sewerage treatment technology in China, though urban drainage system has gained little attention. In the context of urban drainage system and the problem associated with rain, the focus is still mainly toward the simple “emissions”. While the relationship between conservation and utilization of rainwater resources and urban ecology are popular, the relationship between rainwater discharge and non-point source pollution are often neglected. The reasonable choice of sewerage system is dependent on the collection and discharge of urban sewerage, the applicability and economic benefits, along with the ability to meet the water quality requirements and environmental protection. This paper analyzes and summarizes the development of urban drainage system in china, and introduces different drainage forms. The choice of drainage system should be based on the overall planning of the city, environmental protection requirements, the local natural conditions and water conditions, urban sewerage and water quality, the original drainage facilities, and local climatic conditions. It must be comprehensive to meet the environmental protection requirements, through technical and economic comparison.

Characterization of sources and loadings of fecal pollutants using microbial source tracking assays in urban and rural areas of the Grand River Watershed, Southwestern Ontario.

PubMed

Lee, Dae-Young; Lee, Hung; Trevors, Jack T; Weir, Susan C; Thomas, Janis L; Habash, Marc

2014-04-15

Sources of fecal water pollution were assessed in the Grand River and two of its tributaries (Ontario, Canada) using total and host-specific (human and bovine) Bacteroidales genetic markers in conjunction with reference information, such as land use and weather. In-stream levels of the markers and culturable Escherichia coli were also monitored during multiple rain events to gain information on fecal loadings to catchment from diffuse sources. Elevated human-specific marker levels were accurately identified in river water impacted by a municipal wastewater treatment plant (WWTP) effluent and at a downstream site in the Grand River. In contrast, the bovine-specific marker showed high levels of cattle fecal pollution in two tributaries, both of which are characterized as intensely farmed areas. The bovine-specific Bacteroidales marker increased with rainfall in the agricultural tributaries, indicating enhanced loading of cattle-derived fecal pollutants to river from non-point sources following rain events. However, rain-triggered fecal loading was not substantiated in urban settings, indicating continuous inputs of human-originated fecal pollutants from point sources, such as WWTP effluent. This study demonstrated that the Bacteroidales source tracking assays, in combination with land use information and hydrological data, may provide additional insight into the spatial and temporal distribution of source-specific fecal contamination in streams impacted by varying land uses. Using the approach described in this study may help to characterize impacted water sources and to design targeted land use management plans in other watersheds in the future. Copyright © 2014 Elsevier Ltd. All rights reserved.

Eutrophication assessment and management methodology of multiple pollution sources of a landscape lake in North China.

PubMed

Chen, Yanxi; Niu, Zhiguang; Zhang, Hongwei

2013-06-01

Landscape lakes in the city suffer high eutrophication risk because of their special characters and functions in the water circulation system. Using a landscape lake HMLA located in Tianjin City, North China, with a mixture of point source (PS) pollution and non-point source (NPS) pollution, we explored the methodology of Fluent and AQUATOX to simulate and predict the state of HMLA, and trophic index was used to assess the eutrophication state. Then, we use water compensation optimization and three scenarios to determine the optimal management methodology. Three scenarios include ecological restoration scenario, best management practices (BMPs) scenario, and a scenario combining both. Our results suggest that the maintenance of a healthy ecosystem with ecoremediation is necessary and the BMPs have a far-reaching effect on water reusing and NPS pollution control. This study has implications for eutrophication control and management under development for urbanization in China.

Evolution of air pollution source contributions over one decade, derived by PM10 and PM2.5 source apportionment in two metropolitan urban areas in Greece

NASA Astrophysics Data System (ADS)

Diapouli, E.; Manousakas, M.; Vratolis, S.; Vasilatou, V.; Maggos, Th; Saraga, D.; Grigoratos, Th; Argyropoulos, G.; Voutsa, D.; Samara, C.; Eleftheriadis, K.

2017-09-01

Metropolitan Urban areas in Greece have been known to suffer from poor air quality, due to variety of emission sources, topography and climatic conditions favouring the accumulation of pollution. While a number of control measures have been implemented since the 1990s, resulting in reductions of atmospheric pollution and changes in emission source contributions, the financial crisis which started in 2009 has significantly altered this picture. The present study is the first effort to assess the contribution of emission sources to PM10 and PM2.5 concentration levels and their long-term variability (over 5-10 years), in the two largest metropolitan urban areas in Greece (Athens and Thessaloniki). Intensive measurement campaigns were conducted during 2011-2012 at suburban, urban background and urban traffic sites in these two cities. In addition, available datasets from previous measurements in Athens and Thessaloniki were used in order to assess the long-term variability of concentrations and sources. Chemical composition analysis of the 2011-2012 samples showed that carbonaceous matter was the most abundant component for both PM size fractions. Significant increase of carbonaceous particle concentrations and of OC/EC ratio during the cold period, especially in the residential urban background sites, pointed towards domestic heating and more particularly wood (biomass) burning as a significant source. PMF analysis further supported this finding. Biomass burning was the largest contributing source at the two urban background sites (with mean contributions for the two size fractions in the range of 24-46%). Secondary aerosol formation (sulphate, nitrate & organics) was also a major contributing source for both size fractions at the suburban and urban background sites. At the urban traffic site, vehicular traffic (exhaust and non-exhaust emissions) was the source with the highest contributions, accounting for 44% of PM10 and 37% of PM2.5, respectively. The long-term variability of emission sources in the two cities (over 5-10 years), assessed through a harmonized application of the PMF technique on recent and past year data, clearly demonstrates the effective reduction in emissions during the last decade due to control measures and technological development; however, it also reflects the effects of the financial crisis in Greece during these years, which has led to decreased economic activities and the adoption of more polluting practices by the local population in an effort to reduce living costs.

The application of carbon-14 analyses to the source apportionment of atmospheric carbonaceous particulate matter: a review.

PubMed

Heal, Mathew R

2014-01-01

Organic carbon (OC) and elemental carbon (EC) together constitute a substantial proportion of airborne particulate matter (PM). Insight into the sources of this major contributor to PM is important for policies to mitigate the impact of PM on human health and climate change. In recent years measurement of the abundance of the radioisotope of carbon ((14)C) in samples of PM by accelerator mass spectrometry has been used to help quantify the relative contributions from sources of fossil carbon and contemporary carbon. This review provides an introduction to the different sources of carbon within PM and the role of (14)C measurements, a description of the preparation of PM samples and of the instrumentation used to quantify (14)C, and a summary of the results and source apportionment methods reported in published studies since 2004. All studies report a sizable fraction of the carbonaceous PM as of non-fossil origin. Even for PM collected in urban locations, the proportions of non-fossil carbon generally exceed 30%; typically the proportion in urban background locations is around 40-60% depending on the local influence of biomass burning. Where values have been measured directly, proportions of non-fossil carbon in EC are lower than in OC, reflecting the greater contribution of fossil-fuel combustion to EC and the generally small sources of contemporary EC. Detailed source apportionment studies point to important contributions from biogenic-derived secondary OC, consistent with other evidence of a ubiquitous presence of heavily oxidized background secondary OC. The review concludes with some comments on current issues and future prospects, including progress towards compound-class and individual-compound-specific (14)C analyses.

Urban stormwater harvesting and reuse: a probe into the chemical, toxicology and microbiological contaminants in water quality.

PubMed

Chong, Meng Nan; Sidhu, Jatinder; Aryal, Rupak; Tang, Janet; Gernjak, Wolfgang; Escher, Beate; Toze, Simon

2013-08-01

Stormwater is one of the last major untapped urban water resources that can be exploited as an alternative water source in Australia. The information in the current Australian Guidelines for Water Recycling relating to stormwater harvesting and reuse only emphasises on a limited number of stormwater quality parameters. In order to supply stormwater as a source for higher value end-uses, a more comprehensive assessment on the potential public health risks has to be undertaken. Owing to the stochastic variations in rainfall, catchment hydrology and also the types of non-point pollution sources that can provide contaminants relating to different anthropogenic activities and catchment land uses, the characterisation of public health risks in stormwater is complex, tedious and not always possible through the conventional detection and analytical methods. In this study, a holistic approach was undertaken to assess the potential public health risks in urban stormwater samples from a medium-density residential catchment. A combined chemical-toxicological assessment was used to characterise the potential health risks arising from chemical contaminants, while a combination of standard culture methods and quantitative polymerase chain reaction (qPCR) methods was used for detection and quantification of faecal indicator bacteria (FIB) and pathogens in urban stormwater. Results showed that the concentration of chemical contaminants and associated toxicity were relatively low when benchmarked against other alternative water sources such as recycled wastewater. However, the concentrations of heavy metals particularly cadmium and lead have exceeded the Australian guideline values, indicating potential public health risks. Also, high numbers of FIB were detected in urban stormwater samples obtained from wet weather events. In addition, qPCR detection of human-related pathogens suggested there are frequent sewage ingressions into the urban stormwater runoff during wet weather events. Further water quality monitoring study will be conducted at different contrasting urban catchments in order to undertake a more comprehensive public health risk assessment for urban stormwater.

Significant alteration of Critical Zone processes in urban watersheds: shifting from a transport-limited to a weathering-limited regime

NASA Astrophysics Data System (ADS)

Moore, J.; Bird, D. L.; Dobbis, S. K.; Woodward, G.

2016-12-01

Urban areas and associated impervious surface cover (ISC) are among the fastest growing land use types. Rapid growth of urban lands has significant implications for geochemical cycling and solute sources to streams, estuaries, and coastal waters. However, little work has been done to investigate the impacts of urbanization on Critical Processes, including on the export of solutes from urban watersheds. Despite observed elevated solute concentrations in urban streams in some previous studies, neither solute sources nor total solute fluxes have been quantified due to mixed bedrock geology, lack of a forested reference watershed, or the presence of point sources that confounded separation of anthropologic and natural sources. We investigated the geochemical signal of the urban built environment (e.g., roads, parking lots, buildings) in a set of five USGS-gaged watersheds across a rural (forested) to urban gradient in the Maryland Piedmont. These watersheds have ISC ranging from 0 to 25%, no point sources, and similar felsic bedrock chemistry. Weathering from the urban built environment and ISC produces dramatically higher solute concentrations in urban watersheds than in the forested watershed. Higher solute concentrations result in chemical weathering fluxes from urban watersheds that are 11-13 times higher than the forested watershed and are similar to fluxes from mountainous, weathering-limited watersheds rather than fluxes from transport-limited, dilute streams like the forested watershed. Weathering of concrete in urban watersheds produces geochemistry similar to weathering-limited watersheds with high concentrations of Ca2+, Mg2+, and DIC, which is similar to stream chemistry due to carbonate weathering. Road salt dissolution results in high Na+ and Cl- concentrations similar to evaporite weathering. Quantifying processes causing elevated solute fluxes from urban areas is essential to understanding cycling of Ca2+, Mg2+, and DIC in urban streams and in downgradient estuarine or coastal waters.

Mass balance of nitrogen and potassium in urban groundwater in Central Africa, Yaounde/Cameroon.

PubMed

Kringel, R; Rechenburg, A; Kuitcha, D; Fouépé, A; Bellenberg, S; Kengne, I M; Fomo, M A

2016-03-15

Mass flow of nutrients from innumerous latrines and septic tanks was assessed to best describe the groundwater quality situation in the urban environment of Yaounde. 37 groundwater samples were taken at the end of dry season 2012 and analysed for nutrient related (NO3(-), NH4(+), NO2(-), K(+), Cl(-), HPO4(2-) and TOC) and physico-chemical ambient parameters. A survey on waste water discharge close to water points constrained point sources from sanitation. The results showed that the median of nitrate concentration exceeds the WHO limit. We realized that EC increases from the geogenic background to very high levels in the urban area within short distance, suggesting anthropogenic input. Dug wells showed nitrate and ammonium in equivalent concentrations, indicating incomplete nitrification and mandating their inclusion into water type classification. The mass turnover of nutrients in urban groundwater scales high in comparison to national statistical figures on fertilizer import for 2012. A mass N,K balance for infiltration water overestimates observed concentrations by a factor of 4.5. The marked balance gap is attributed to dynamic non-equilibrium between input and output. Unresolved questions like a) urban sanitation, b) hygiene & health and c) environmental protection urgently call for closing the nutrient cycle. In the light of Cameroonian strategies on rural development, tackling the groundwater nutrient, urban agriculture, food--NEXUS might partially restore urban and periurban ecosystem services under economical constraints and thus improve living conditions. Copyright © 2016 The Authors. Published by Elsevier B.V. All rights reserved.

Non-agricultural ammonia emissions in urban China

NASA Astrophysics Data System (ADS)

Chang, Y. H.

2014-03-01

The non-agricultural ammonia (NH3) emissions in cities have received little attention but could rival agricultural sources in term of the efficiency in PM formation. The starting point for finding credible solutions is to comprehensively establish a city-specific Non-agricultural Ammonia Emission Inventory (NAEI) and identify the largest sources where efforts can be directed to deliver the largest impact. In this paper, I present a NAEI of 113 national key cities targeted on environmental protection in China in 2010, which for the first time covers NH3 emissions from pets, infants, smokers, green land, and household products. Results show that totally 210 478 Mg, the NH3 emissions from traffic, fuel combustion, waste disposal, pets, green land, human, and household products are 67 671 Mg, 56 275 Mg, 44 289 Mg, 23 355 Mg, 7509 Mg, 7312 Mg, and 4069 Mg, respectively. The NH3 emission intensity from the municipal districts ranges from 0.08 to 3.13 Mg km-2 yr-1, with a average of 0.84 Mg km-2 yr-1. The high NH3 emission intensities in Beijing-Tianjin-Hebei region, Yangtze River Delta region and Pearl River Delta region support the view that non-agricultural NH3 sources play a key role in city-scale NH3 emissions and thus have potentially important implications for secondary PM formation (ammonium-sulfate-nitrate system) in urban agglomeration of China. Therefore, in addition to current SO2 and NOx controls, China also needs to allocate more scientific, technical, and legal resources on controlling non-agricultural NH3 emissions in the future.

[Characteristics and Transport Patterns of Ammonia, Nitrites, Nitrates and Inorganic Nitrogen Flux at Epikarst Springs and a Subterranean Stream in Nanshan, Chongqing].

PubMed

Zhang, Yuan-zhu; He, Qiu-fang; Jiang, Yong-jun; Li, Yong

2016-04-15

In a karst groundwater system, it develops complex multiple flows because of its special geological structure and unique physical patterns of aquifers. In order to investigate the characteristics and transport patterns of ammonia, nitrite and nitrate in epikarst water and subterranean stream, the water samples were collected monthly in a fast-urbanizing karst region. The results showed distinctive characteristics of three forms of inorganic nitrogen. The concentration of inorganic nitrogen was stable in the epikarst water while it was fluctuant in the subterranean stream. Epikarst water was less affected by rainfall and sewage compared with subterranean stream. In epikarst water, the nitrate concentration was much higher than the ammonia concentration. Dissolved inorganic nitrogen, mainly from non-point source pollution related to agricultural activities, passed in and out of the epikarst water based on a series of physical; chemical and biological processes in the epikarst zone, such as ammonification, adsorption and nitrification. On the contrary, subterranean stream showed a result of NH₄⁺-N > NO₃⁻-N in dry seasons and NO₃⁻-N > NH₄⁺-N in rainy seasons. This can be due to the fact that sanitary and industrial sewage flowed into subterranean river through sinkholes, fissures and grikes in dry season. Dissolved inorganic nitrogen in subterranean river was mainly from the non-point source pollution in wet season. Non-point source pollutants entered into subterranean water by two transport ways, one by penetration along with vadose flow through fissures and grikes, and the other by conduit flow through sinkholes from the surface runoff, soil water flow and epikarst flow. The export flux of DIN was 56.05 kg · (hm² · a)⁻¹, and NH₄⁺-N and NO₃⁻-N accounted for 46.03% and 52.51%, respectively. The contributions of point-source pollution and non point-source pollution to the export flux of DIN were 25.08% and 74.92%, respectively, based on run-off division method.

Use of the AGNPS model to assess impacts of development and best management practices in an urban watershed

NASA Astrophysics Data System (ADS)

Cross, J. A.

2006-12-01

A Geographical Information System (GIS) is an invaluable tool in the estimation of land use changes and spatial variability in urban areas. (Non-Point Source (NPS) models provide hypothetical opportunities to assess impacts which storm water management strategies and land use changes have on watersheds by predicting loadings on a watershed scale. This study establishes a methodology for analyzing land use changes and management associated with them by utilizing a GIS analysis of impervious surfaces and AGricultural Non- Point Source (AGNPS) modeling. The GIS analysis of Total Impervious Area (TIA) was used to quantify increases in development and provided land use data for use in AGNPS modeling in a small artificially- delineated urban watershed. AGNPS modeling was executed in several different scenarios to predict changes in NPS loadings associated with increases in TIA and its subsequent management in a small artificially- delineated urban watershed. Data editing, creation and extracting was completed using ArcView (3.2) GeoMedia (6) GIS systems. The GIS analysis quantified the increase in urbanization via TIA within the Bluebonnet Swamp Watershed (BSW) in East Baton Rouge Parish (EBRP), Louisiana. The BSW had significant increases in urbanization in the 8 year time span of 1996 2004 causing and increase in quantity and decrease in quality of subsequent runoff. Datasets made available from the GIS analysis included TIA and the change in percentage from 1996 to 2004. This information is fundamental for the AGNPS model because it was used to calculate TIA percentages within each AGNPS cell. A 30 year daily climate file was used to execute AGNPS in different land use and storm water management scenarios within the 1100 acre BSW. Runoff qualities and quantities were then compared for different periods of 1996 and 2004. Predictions of sediment, erosion and runoff were compared according by scenario year. Management practices were also simulated by changing the Runoff Curve Number (RCN) within AGNPS and their results were also compared. This study provides an aid to planners and managers in estimating increases in urbanization by artificially- delineated watershed. It also in illustrates how to use AGNPS to predict NPS pollution and the influence that change in TIA, land use and storm water management strategies have on sediment loadings, erosion and runoff in a watershed.

A Comparative Analysis of Vibrio cholerae Contamination in Point-of-Drinking and Source Water in a Low-Income Urban Community, Bangladesh.

PubMed

Ferdous, Jannatul; Sultana, Rebeca; Rashid, Ridwan B; Tasnimuzzaman, Md; Nordland, Andreas; Begum, Anowara; Jensen, Peter K M

2018-01-01

Bangladesh is a cholera endemic country with a population at high risk of cholera. Toxigenic and non-toxigenic Vibrio cholerae ( V. cholerae ) can cause cholera and cholera-like diarrheal illness and outbreaks. Drinking water is one of the primary routes of cholera transmission in Bangladesh. The aim of this study was to conduct a comparative assessment of the presence of V. cholerae between point-of-drinking water and source water, and to investigate the variability of virulence profile using molecular methods of a densely populated low-income settlement of Dhaka, Bangladesh. Water samples were collected and tested for V. cholerae from "point-of-drinking" and "source" in 477 study households in routine visits at 6 week intervals over a period of 14 months. We studied the virulence profiles of V. cholerae positive water samples using 22 different virulence gene markers present in toxigenic O1/O139 and non-O1/O139 V. cholerae using polymerase chain reaction (PCR). A total of 1,463 water samples were collected, with 1,082 samples from point-of-drinking water in 388 households and 381 samples from 66 water sources. V. cholerae was detected in 10% of point-of-drinking water samples and in 9% of source water samples. Twenty-three percent of households and 38% of the sources were positive for V. cholerae in at least one visit. Samples collected from point-of-drinking and linked sources in a 7 day interval showed significantly higher odds ( P < 0.05) of V. cholerae presence in point-of-drinking compared to source [OR = 17.24 (95% CI = 7.14-42.89)] water. Based on the 7 day interval data, 53% (17/32) of source water samples were negative for V. cholerae while linked point-of-drinking water samples were positive. There were significantly higher odds ( p < 0.05) of the presence of V. cholerae O1 [OR = 9.13 (95% CI = 2.85-29.26)] and V. cholerae O139 [OR = 4.73 (95% CI = 1.19-18.79)] in source water samples than in point-of-drinking water samples. Contamination of water at the point-of-drinking is less likely to depend on the contamination at the water source. Hygiene education interventions and programs should focus and emphasize on water at the point-of-drinking, including repeated cleaning of drinking vessels, which is of paramount importance in preventing cholera.

Sources of hydrocarbons in urban road dust: Identification, quantification and prediction.

PubMed

Mummullage, Sandya; Egodawatta, Prasanna; Ayoko, Godwin A; Goonetilleke, Ashantha

2016-09-01

Among urban stormwater pollutants, hydrocarbons are a significant environmental concern due to their toxicity and relatively stable chemical structure. This study focused on the identification of hydrocarbon contributing sources to urban road dust and approaches for the quantification of pollutant loads to enhance the design of source control measures. The study confirmed the validity of the use of mathematical techniques of principal component analysis (PCA) and hierarchical cluster analysis (HCA) for source identification and principal component analysis/absolute principal component scores (PCA/APCS) receptor model for pollutant load quantification. Study outcomes identified non-combusted lubrication oils, non-combusted diesel fuels and tyre and asphalt wear as the three most critical urban hydrocarbon sources. The site specific variabilities of contributions from sources were replicated using three mathematical models. The models employed predictor variables of daily traffic volume (DTV), road surface texture depth (TD), slope of the road section (SLP), effective population (EPOP) and effective impervious fraction (EIF), which can be considered as the five governing parameters of pollutant generation, deposition and redistribution. Models were developed such that they can be applicable in determining hydrocarbon contributions from urban sites enabling effective design of source control measures. Copyright © 2016 Elsevier Ltd. All rights reserved.

Assessment of POPs in air from Spain using passive sampling from 2008 to 2015. Part II: Spatial and temporal observations of PCDD/Fs and dl-PCBs.

PubMed

Muñoz-Arnanz, Juan; Roscales, Jose L; Vicente, Alba; Ros, María; Barrios, Laura; Morales, Laura; Abad, Esteban; Jiménez, Begoña

2018-09-01

Time series (2008-2015) of polychlorinated dibenzo-p-dioxins and dibenzofurans (PCDD/Fs) and dioxin-like polychlorinated biphenyls (dl-PCBs) in ambient air from the Spanish Monitoring Program were analyzed. A total of 321 samples were collected seasonally each year in 5 urban and 7 background sites by means of passive air sampling. Air concentrations were higher at urban than background sites (urban vs. background concentration ranges): PCDD/Fs (26.9-1010 vs. 20.0-357 fg/m 3 ), non-ortho PCBs (0.113-3.14 vs. 0.042-2.00 pg/m 3 ) and mono-ortho PCBs (0.644-41.3 vs. 0.500-32.8 pg/m 3 ). Results showed significant decreases from 2009 for non-ortho PCBs and PCDD/Fs as well as for WHO 2006 -TEQs. These declines were sharper, and sometimes only significant, in urban places resulting in converging levels at urban and background sites for these pollutants at the end of the study period. In contrast, mono-ortho PCBs did not show any significant variation but a steady flat temporal behavior in their concentrations, suggesting the existence of different sources between mono-ortho and non-ortho PCBs. Seasonality was observed for air burdens of all these POPs. PCDD/Fs were mostly measured at higher concentrations in colder than in hot seasons, and the opposite was true for dl-PCBs. Seasonal variations for PCDD/Fs appeared to be related to changes in their sources (e.g. domestic heating, open burning) rather than to temperature per se. In contrast, environmental temperature dependent factors (e.g. increased partitioning into the gas phase) drove seasonal variations in dl-PCBs instead of seasonal changes in their sources. Regarding spatial patterns, significant greater levels of PCDD/Fs and dl-PCBs were generally found in cities compared to background areas, pointing out the role of densely populated areas as sources for these pollutants in Spain. As proven by our results, long-term monitoring activities are essential to assess and understand temporal behaviors for these POPs, as well as to evaluate the achievement of Stockholm Convention objectives. Copyright © 2018 Elsevier B.V. All rights reserved.

A Comparative Analysis of Vibrio cholerae Contamination in Point-of-Drinking and Source Water in a Low-Income Urban Community, Bangladesh

PubMed Central

Ferdous, Jannatul; Sultana, Rebeca; Rashid, Ridwan B.; Tasnimuzzaman, Md.; Nordland, Andreas; Begum, Anowara; Jensen, Peter K. M.

2018-01-01

Bangladesh is a cholera endemic country with a population at high risk of cholera. Toxigenic and non-toxigenic Vibrio cholerae (V. cholerae) can cause cholera and cholera-like diarrheal illness and outbreaks. Drinking water is one of the primary routes of cholera transmission in Bangladesh. The aim of this study was to conduct a comparative assessment of the presence of V. cholerae between point-of-drinking water and source water, and to investigate the variability of virulence profile using molecular methods of a densely populated low-income settlement of Dhaka, Bangladesh. Water samples were collected and tested for V. cholerae from “point-of-drinking” and “source” in 477 study households in routine visits at 6 week intervals over a period of 14 months. We studied the virulence profiles of V. cholerae positive water samples using 22 different virulence gene markers present in toxigenic O1/O139 and non-O1/O139 V. cholerae using polymerase chain reaction (PCR). A total of 1,463 water samples were collected, with 1,082 samples from point-of-drinking water in 388 households and 381 samples from 66 water sources. V. cholerae was detected in 10% of point-of-drinking water samples and in 9% of source water samples. Twenty-three percent of households and 38% of the sources were positive for V. cholerae in at least one visit. Samples collected from point-of-drinking and linked sources in a 7 day interval showed significantly higher odds (P < 0.05) of V. cholerae presence in point-of-drinking compared to source [OR = 17.24 (95% CI = 7.14–42.89)] water. Based on the 7 day interval data, 53% (17/32) of source water samples were negative for V. cholerae while linked point-of-drinking water samples were positive. There were significantly higher odds (p < 0.05) of the presence of V. cholerae O1 [OR = 9.13 (95% CI = 2.85–29.26)] and V. cholerae O139 [OR = 4.73 (95% CI = 1.19–18.79)] in source water samples than in point-of-drinking water samples. Contamination of water at the point-of-drinking is less likely to depend on the contamination at the water source. Hygiene education interventions and programs should focus and emphasize on water at the point-of-drinking, including repeated cleaning of drinking vessels, which is of paramount importance in preventing cholera. PMID:29616005

Analysis of one dimension migration law from rainfall runoff on urban roof

NASA Astrophysics Data System (ADS)

Weiwei, Chen

2017-08-01

Research was taken on the hydrology and water quality process in the natural rain condition and water samples were collected and analyzed. The pollutant were included SS, COD and TN. Based on the mass balance principle, one dimension migration model was built for the rainfall runoff pollution in surface. The difference equation was developed according to the finite difference method, by applying the Newton iteration method for solving it. The simulated pollutant concentration process was in consistent with the measured value on model, and Nash-Sutcliffe coefficient was higher than 0.80. The model had better practicability, which provided evidence for effectively utilizing urban rainfall resource, non-point source pollution of making management technologies and measures, sponge city construction, and so on.

[Effect of antecedent dry period on water quality of urban storm runoff pollution].

PubMed

Bian, Bo

2009-12-01

Identified the main factor influencing urban rainfall-runoff pollution provides a scientific basis for urban rainfall-runoff pollution control and management. Therefore, starting in May 2006, a study was conducted to characterize water quality from representative land uses types in Zhenjiang to analyse the effect of antecedent dry period on stormwater runoff quality. The results show that the beginning of rainfall, with the increase of antecedent dry periods, the percentages of less than 40 microm is increased, the correlation of the water quality parameters (TN, TP, Zn, Pb, Cu, TSS and COD) and antecedent dry period shows a significant positive correlation, dissolved pollutants in the initial period surface runoff is increased. These findings show that facilitating the recognition of antecedent dry periods is the main factor influencing the change in concentration and partitioning of pollutants to provide the scientific basis for non-point source pollution control and management.

Sampling Singular and Aggregate Point Sources of Carbon Dioxide from Space Using OCO-2

NASA Astrophysics Data System (ADS)

Schwandner, F. M.; Gunson, M. R.; Eldering, A.; Miller, C. E.; Nguyen, H.; Osterman, G. B.; Taylor, T.; O'Dell, C.; Carn, S. A.; Kahn, B. H.; Verhulst, K. R.; Crisp, D.; Pieri, D. C.; Linick, J.; Yuen, K.; Sanchez, R. M.; Ashok, M.

2016-12-01

Anthropogenic carbon dioxide (CO2) sources increasingly tip the natural balance between natural carbon sources and sinks. Space-borne measurements offer opportunities to detect and analyze point source emission signals anywhere on Earth. Singular continuous point source plumes from power plants or volcanoes turbulently mix into their proximal background fields. In contrast, plumes of aggregate point sources such as cities, and transportation or fossil fuel distribution networks, mix into each other and may therefore result in broader and more persistent excess signals of total column averaged CO2 (XCO2). NASA's first satellite dedicated to atmospheric CO2observation, the Orbiting Carbon Observatory-2 (OCO-2), launched in July 2014 and now leads the afternoon constellation of satellites (A-Train). While continuously collecting measurements in eight footprints across a narrow ( < 10 km) wide swath it occasionally cross-cuts coincident emission plumes. For singular point sources like volcanoes and coal fired power plants, we have developed OCO-2 data discovery tools and a proxy detection method for plumes using SO2-sensitive TIR imaging data (ASTER). This approach offers a path toward automating plume detections with subsequent matching and mining of OCO-2 data. We found several distinct singular source CO2signals. For aggregate point sources, we investigated whether OCO-2's multi-sounding swath observing geometry can reveal intra-urban spatial emission structures in the observed variability of XCO2 data. OCO-2 data demonstrate that we can detect localized excess XCO2 signals of 2 to 6 ppm against suburban and rural backgrounds. Compared to single-shot GOSAT soundings which detected urban/rural XCO2differences in megacities (Kort et al., 2012), the OCO-2 swath geometry opens up the path to future capabilities enabling urban characterization of greenhouse gases using hundreds of soundings over a city at each satellite overpass. California Institute of Technology

Application of an integrated Weather Research and Forecasting (WRF)/CALPUFF modeling tool for source apportionment of atmospheric pollutants for air quality management: A case study in the urban area of Benxi, China.

PubMed

Wu, Hao; Zhang, Yan; Yu, Qi; Ma, Weichun

2018-04-01

In this study, the authors endeavored to develop an effective framework for improving local urban air quality on meso-micro scales in cities in China that are experiencing rapid urbanization. Within this framework, the integrated Weather Research and Forecasting (WRF)/CALPUFF modeling system was applied to simulate the concentration distributions of typical pollutants (particulate matter with an aerodynamic diameter <10 μm [PM 10 ], sulfur dioxide [SO 2 ], and nitrogen oxides [NO x ]) in the urban area of Benxi. Statistical analyses were performed to verify the credibility of this simulation, including the meteorological fields and concentration fields. The sources were then categorized using two different classification methods (the district-based and type-based methods), and the contributions to the pollutant concentrations from each source category were computed to provide a basis for appropriate control measures. The statistical indexes showed that CALMET had sufficient ability to predict the meteorological conditions, such as the wind fields and temperatures, which provided meteorological data for the subsequent CALPUFF run. The simulated concentrations from CALPUFF showed considerable agreement with the observed values but were generally underestimated. The spatial-temporal concentration pattern revealed that the maximum concentrations tended to appear in the urban centers and during the winter. In terms of their contributions to pollutant concentrations, the districts of Xihu, Pingshan, and Mingshan all affected the urban air quality to different degrees. According to the type-based classification, which categorized the pollution sources as belonging to the Bengang Group, large point sources, small point sources, and area sources, the source apportionment showed that the Bengang Group, the large point sources, and the area sources had considerable impacts on urban air quality. Finally, combined with the industrial characteristics, detailed control measures were proposed with which local policy makers could improve the urban air quality in Benxi. In summary, the results of this study showed that this framework has credibility for effectively improving urban air quality, based on the source apportionment of atmospheric pollutants. The authors endeavored to build up an effective framework based on the integrated WRF/CALPUFF to improve the air quality in many cities on meso-micro scales in China. Via this framework, the integrated modeling tool is accurately used to study the characteristics of meteorological fields, concentration fields, and source apportionments of pollutants in target area. The impacts of classified sources on air quality together with the industrial characteristics can provide more effective control measures for improving air quality. Through the case study, the technical framework developed in this study, particularly the source apportionment, could provide important data and technical support for policy makers to assess air pollution on the scale of a city in China or even the world.

An experimental study of the impact of trees and urban form on the turbulent dispersion of heavy particles from near ground point sources

NASA Astrophysics Data System (ADS)

Stoll, R., II; Christen, A.; Mahaffee, W.; Salesky, S.; Therias, A.; Caitlin, S.

2016-12-01

Pollution in the form of small particles has a strong impact on a wide variety of urban processes that play an important role in the function of urban ecosystems and ultimately human health and well-being. As a result, a substantial body of research exists on the sources, sinks, and transport characteristics of urban particulate matter. Most of the existing experimental work examining point sources employed gases (e.g., SF6) as the working medium. Furthermore, the focus of most studies has been on the dispersion of pollutants far from the source location. Here, our focus is on the turbulent dispersion of heavy particles in the near source region of a suburban neighborhood. To this end, we conducted a series of heavy particle releases in the Sunset neighborhood of Vancouver, Canada during June, 2017. The particles where dispersed from a near ground point source at two different locations. The Sunset neighborhood is composed mostly of single dwelling detached houses and has been used in numerous previous urban studies. One of the release points was just upwind of a 4-way intersection and the other in the middle of a contiguous block of houses. Each location had a significant density of trees. A minimum of four different successful release events were conducted at each site. During each release, fluorescing micro particles (mean diameter approx. 30 micron) were released from ultrasonic atomizer nozzles for a duration of approximately 20 minutes. The particles where sampled at 50 locations (1.5 m height) in the area downwind of the release over distances from 1-15 times the mean canopy height ( 6 m) using rotating impaction traps. In addition to the 50 sampler locations, instantaneous wind velocities were measured with eight sonic anemometers distributed horizontally and vertically throughout the release area. The resulting particle plume distributions indicate a strong impact of local urban form in the near source region and a high degree of sensitivity to the local wind direction measured from the sonic anemometers. In addition to presenting the experimental data, initial comparisons to a Lagrangian particle dispersion model driven by a mass consistent diagnostic wind field will be presented.

An experimental study of the impact of trees and urban form on the turbulent dispersion of heavy particles from near ground point sources

NASA Astrophysics Data System (ADS)

Stoll, R., II; Christen, A.; Mahaffee, W.; Salesky, S.; Therias, A.; Caitlin, S.

2017-12-01

Pollution in the form of small particles has a strong impact on a wide variety of urban processes that play an important role in the function of urban ecosystems and ultimately human health and well-being. As a result, a substantial body of research exists on the sources, sinks, and transport characteristics of urban particulate matter. Most of the existing experimental work examining point sources employed gases (e.g., SF6) as the working medium. Furthermore, the focus of most studies has been on the dispersion of pollutants far from the source location. Here, our focus is on the turbulent dispersion of heavy particles in the near source region of a suburban neighborhood. To this end, we conducted a series of heavy particle releases in the Sunset neighborhood of Vancouver, Canada during June, 2017. The particles where dispersed from a near ground point source at two different locations. The Sunset neighborhood is composed mostly of single dwelling detached houses and has been used in numerous previous urban studies. One of the release points was just upwind of a 4-way intersection and the other in the middle of a contiguous block of houses. Each location had a significant density of trees. A minimum of four different successful release events were conducted at each site. During each release, fluorescing micro particles (mean diameter approx. 30 micron) were released from ultrasonic atomizer nozzles for a duration of approximately 20 minutes. The particles where sampled at 50 locations (1.5 m height) in the area downwind of the release over distances from 1-15 times the mean canopy height ( 6 m) using rotating impaction traps. In addition to the 50 sampler locations, instantaneous wind velocities were measured with eight sonic anemometers distributed horizontally and vertically throughout the release area. The resulting particle plume distributions indicate a strong impact of local urban form in the near source region and a high degree of sensitivity to the local wind direction measured from the sonic anemometers. In addition to presenting the experimental data, initial comparisons to a Lagrangian particle dispersion model driven by a mass consistent diagnostic wind field will be presented.

NON-POINT SOURCE POLLUTION

EPA Science Inventory

Non-point source pollution is a diffuse source that is difficult to measure and is highly variable due to different rain patterns and other climatic conditions. In many areas, however, non-point source pollution is the greatest source of water quality degradation. Presently, stat...

Fecal contamination of drinking water within peri-urban households, Lima, Peru.

PubMed

Oswald, William E; Lescano, Andrés G; Bern, Caryn; Calderon, Maritza M; Cabrera, Lilia; Gilman, Robert H

2007-10-01

We assessed fecal contamination of drinking water in households in 2 peri-urban communities of Lima, Peru. We measured Escherichia coli counts in municipal source water and, within households, water from principal storage containers, stored boiled drinking water, and water in a serving cup. Source water was microbiologically clean, but 26 (28%) of 93 samples of water stored for cooking had fecal contamination. Twenty-seven (30%) of 91 stored boiled drinking water samples grew E. coli. Boiled water was more frequently contaminated when served in a drinking cup than when stored (P < 0.01). Post-source contamination increased successively through the steps of usage from source water to the point of consumption. Boiling failed to ensure safe drinking water at the point of consumption because of easily contaminated containers and poor domestic hygiene. Hygiene education, better point-of-use treatment and storage options, and in-house water connections are urgently needed.

Characterization of runoff from various urban catchments at different spatial scales in Beijing, China.

PubMed

Zhang, W; Che, W; Liu, D K; Gan, Y P; Lv, F F

2012-01-01

In order to investigate the characterization of runoff in storm sewer from various urban catchments, three monitoring systems at different spatial scales have been installed separately. They have been held since July 2010 in urban area of Beijing (China). The monitoring data revealed that chemical oxygen demand (COD), total suspended solids (TSS), total nitrogen (TN), total phosphorus (TP), and NH(3)-N values significantly exceed the Class V surface water quality standard developed by Ministry of Environmental Protection of the People's Republic of China (MEP). A surface solids buildup and wash off model for small watershed was adopted to analyze and discuss the process of a runoff pollutant discharge. More than a half of pollutant parameters presented a good fit to the model. However, a slightly worse-fit to the wash off model appeared in less than half of the data. Due to the influence of sewer sediments, sewer system characteristics, catchment characteristics, and other reasons, first flush was seldom observed in storm sewer runoff from these three survey areas. Meanwhile, the correlation between TSS and any other pollutant was analyzed according to cumulative load of pollutants in runoff events. An event mean concentrations (EMCs) approach was adopted to quantify the pollution of runoff. EMCs of various pollutants in storm sewer runoff between different rainfall events were slightly higher than the typical values observed in similar areas at home and abroad, according to other studies reported in literature. Based on quantitative analysis, it can be concluded that urban non-point source pollution is recognized as the major causes of quality deterioration in the receiving water bodies. This is after the point source pollution has been controlled substantially in Beijing. An integrated strategy, which combines centralized and decentralized control, along with the conditions of meteorology, hydrology, urban planning, existing drainage system, etc., will be an effective and economic approach to urban runoff pollution control.

Sources and chemical composition of atmospheric fine and coarse particles in the Helsinki area

NASA Astrophysics Data System (ADS)

Pakkanen, Tuomo A.; Loukkola, Kati; Korhonen, Christina H.; Aurela, Minna; Mäkelä, Timo; Hillamo, Risto E.; Aarnio, Päivi; Koskentalo, Tarja; Kousa, Anu; Maenhaut, Willy

During April 1996-June 1997 size-segregated atmospheric aerosol particles were collected at an urban and a rural site in the Helsinki area by utilising virtual impactors (VI) and Berner low-pressure impactors (BLPI). In addition, VI samples were collected at a semi-urban site during October 1996-May 1997. The average PM 2.3 (fine particle) concentrations at the urban and rural sites were 11.8 and 8.4 μg/m 3, and the PM 2.3-15 (coarse particle) concentrations were 12.8 and about 5 μg/m 3, respectively. The difference in fine particle mass concentrations suggests that on average, more than one third of the fine mass at the urban site is of local origin. Evaporation of fine particle nitrate from the VI Teflon filters during sampling varied similarly at the three sites, the average evaporation being about 50-60%. The average fine particle concentrations of the chemical components (25 elements and 13 ions) appeared to be fairly similar at the three sites for most components, which suggests that despite the long-range transport, the local emissions of these components were relatively evenly distributed in the Helsinki area. Exceptions were the average fine particles Ba, Fe, Sb and V concentrations that were clearly highest at the urban site pointing to traffic (Ba, Fe, Sb) and to combustion of heavy fuel oil (V) as the likely local sources. The average coarse particle concentrations for most components were highest at the urban site and lowest at the rural site. Average chemical composition of fine particles was fairly similar at the urban and rural sites: non-analysed fraction (mainly carbonaceous material and water) 43% and 37%, sulphate 21% and 25%, crustal matter 12% and 13%, nitrate 12% and 11%, ammonium 9% and 10% and sea-salt 2.5% and 3.2%, respectively. At the semi-urban site also, the average fine particle composition was similar. At the urban site, the year round average composition of coarse particles was dominated by crustal matter (59%) and the non-analysed components (28%, mainly carbonaceous material and water), while the other contributions were much lower: sea-salt 7%, nitrate 4% and sulphate 2%. At the rural site, the coarse samples were collected in spring and summer and the percentage was clearly lower for crustal matter (37%) and sea-salt (3%) but higher for the not-analysed fraction (51%). At the semi-urban site, the average composition of coarse particles was nearly identical to that at the urban site. Correlations between the chemical components were calculated separately for fine and coarse particles. In urban fine particles sulphate, ammonium, Tl, oxalate and PM 2.3 mass correlated with each other and originated mainly from long-range transport. The sea-salt ions Na +, Cl - and Mg 2+ formed another group and still another group was formed by the organic anions oxalate, malonate, succinate, glutarate and methane sulphonate. Ni and V correlated strongly pointing to combustion of heavy fuel oil as the likely source. In addition, some groups with lower correlations were detected. At the rural and semi-urban sites, the correlating components were rather similar to those at the urban site, although differences were also observed.

Wet nitrogen deposition across the urban-intensive agricultural-rural transect of a small urban area in southwest China.

PubMed

Deng, Ouping; Zhang, Shirong; Deng, Liangji; Zhang, Chunlong; Fei, Jianbo

2018-03-01

Understanding of the spatial and temporal variation of the flux of atmospheric nitrogen (N) deposition is essential for assessment of its impact on ecosystems. However, little attention has been paid to the variability of N deposition across urban-intensive agricultural-rural transects. A continuous 2-year observational study (from January 2015 to December 2016) was conducted to determine wet N deposition across the urban-intensive agricultural-rural transect of a small urban area in southwest China. Significantly spatial and temporal variations were found in the research area. Along the urban-intensive agricultural-rural transect, the TN and NH 4 + -N deposition first increased and then decreased, and the NO 3 - -N and dissolved organic N (DON) deposition decreased continuously. Wet N deposition was mainly affected by the districts of agro-facilities, roads and build up lands. Wet NH 4 + -N deposition had non-seasonal emission sources including industrial emissions and urban excretory wastes in urban districts and seasonal emission sources such as fertilizer and manure volatilization in the other districts. However, wet NO 3 - -N deposition had seasonal emission sources such as industrial emissions and fireworks in urban district and non-seasonal emission sources such as transportation in the other districts. Deposition of DON was likely to have had similar sources to NO 3 - -N deposition in rural district, and high-temperature-dependent sources in urban and intensive agricultural districts. Considering the annual wet TN deposition in the intensive agricultural district was about 11.1% of the annual N fertilizer input, N fertilizer rates of crops should be reduced in this region to avoid the excessive application, and the risk of N emissions to the environment.

THE ROLE OF STORMWATER BMPS IN MITIGATING THE EFFECTS OF NUTRIENT OVERENRICHMENT IN THE URBAN WATERSHED

EPA Science Inventory

Nutrient overenrichment from agricultural and urban point and nonpoint sources, including urban stormwter, is a leading cause of impairment to our nation's rivers, lakes, and coastal waters. For waters that do not currently meet existing water quality standards, The USEPA's TMDL ...

Impact of urban WWTP and CSO fluxes on river peak flow extremes under current and future climate conditions.

PubMed

Keupers, Ingrid; Willems, Patrick

2013-01-01

The impact of urban water fluxes on the river system outflow of the Grote Nete catchment (Belgium) was studied. First the impact of the Waste Water Treatment Plant (WWTP) and the Combined Sewer Overflow (CSO) outflows on the river system for the current climatic conditions was determined by simulating the urban fluxes as point sources in a detailed, hydrodynamic river model. Comparison was made of the simulation results on peak flow extremes with and without the urban point sources. In a second step, the impact of climate change scenarios on the urban fluxes and the consequent impacts on the river flow extremes were studied. It is shown that the change in the 10-year return period hourly peak flow discharge due to climate change (-14% to +45%) was in the same order of magnitude as the change due to the urban fluxes (+5%) in current climate conditions. Different climate change scenarios do not change the impact of the urban fluxes much except for the climate scenario that involves a strong increase in rainfall extremes in summer. This scenario leads to a strong increase of the impact of the urban fluxes on the river system.

Development of a comprehensive air quality modeling framework for a coastal urban airshed in south Texas

NASA Astrophysics Data System (ADS)

Farooqui, Mohmmed Zuber

Tropospheric ozone is one of the major air pollution problems affecting urban areas of United States as well as other countries in the world. Analysis of surface observed ozone levels in south and central Texas revealed several days exceeding 8-hour average ozone National Ambient of Air Quality Standards (NAAQS) over the past decade. Two major high ozone episodes were identified during September of 1999 and 2002. A photochemical modeling framework for the high ozone episodes in 1999 and 2002 were developed for the Corpus Christi urban airshed. The photochemical model was evaluated as per U.S. Environmental Protection Agency (EPA) recommended statistical methods and the models performed within the limits set by EPA. An emission impact assessment of various sources within the urban airshed was conducted using the modeling framework. It was noted that by nudging MM5 with surface observed meteorological parameters and sea-surface temperature, the coastal meteorological predictions improved. Consequently, refined meteorology helped the photochemical model to better predict peak ozone levels in urban airsheds along the coastal margins of Texas including in Corpus Christi. The emissions assessment analysis revealed that Austin and San Antonio areas were significantly affected by on-road mobile emissions from light-duty gasoline and heavy-duty diesel vehicles. The urban areas of San Antonio, Austin, and Victoria areas were estimated to be NOx sensitive. Victoria was heavily influenced by point sources in the region while Corpus Christi was influenced by both point and non-road mobile sources and was identified to be sensitive to VOC emissions. A rise in atmospheric temperature due to climate change potentially increase ozone exceedances and the peak ozone levels within the study region and this will be a major concern for air quality planners. This study noted that any future increase in ambient temperature would result in a significant increase in the urban and regional ozone levels within the modeling domain and it would also enhance the transported levels of ozone across the region. Overall, the photochemical modeling framework helped in evaluating the impact of various parameters affecting ozone air quality; and, it has the potential to be a tool for policy-makers to develop effective emissions control strategies under various regulatory and climate conditions.

Allometric scaling of UK urban emissions: interpretation and implications for air quality management

NASA Astrophysics Data System (ADS)

MacKenzie, Rob; Barnes, Matt; Whyatt, Duncan; Hewitt, Nick

2016-04-01

Allometry uncovers structures and patterns by relating the characteristics of complex systems to a measure of scale. We present an allometric analysis of air quality for UK urban settlements, beginning with emissions and moving on to consider air concentrations. We consider both airshed-average 'urban background' concentrations (cf. those derived from satellites for NO2) and local pollution 'hotspots'. We show that there is a strong and robust scaling (with respect to population) of the non-point-source emissions of the greenhouse gases carbon dioxide and methane, as well as the toxic pollutants nitrogen dioxide, PM2.5, and 1,3-butadiene. The scaling of traffic-related emissions is not simply a reflection of road length, but rather results from the socio-economic patterning of road-use. The recent controversy regarding diesel vehicle emissions is germane to our study but does not affect our overall conclusions. We next develop an hypothesis for the population-scaling of airshed-average air concentrations, with which we demonstrate that, although average air quality is expected to be worse in large urban centres compared to small urban centres, the overall effect is an economy of scale (i.e., large cities reduce the overall burden of emissions compared to the same population spread over many smaller urban settlements). Our hypothesis explains satellite-derived observations of airshed-average urban NO2 concentrations. The theory derived also explains which properties of nature-based solutions (urban greening) can make a significant contribution at city scale, and points to a hitherto unforeseen opportunity to make large cities cleaner than smaller cities in absolute terms with respect to their airshed-average pollutant concentration.

Judging a brook by its cover: The relation between ecological condition of a stream and urban land cover in new England

USGS Publications Warehouse

Coles, J.F.; Cuffney, T.F.; McMahon, G.; Rosiu, C.J.

2010-01-01

The US Geological Survey conducted an urban land-use study in the New England Coastal Basins (NECB) area during 2001 to determine how urbanization relates to changes in the ecological condition of streams. Thirty sites were selected that differed in their level of watershed development (low to high). An urban intensity value was calculated for each site from 24 landscape variables. Together, these 30 values reppresented a gradient of urban intensity. Among various biological, chemical, and physical factors surveyed at each site, benthic invertebrate assemblages were sampled from stream riffles and also from multiple habitats along the length of the sampling reach. We use some of the NECB data to derive a four-variable urbanintensity index (NECB-UII), where each variable represents a distinct component of urbanization: increasing human presence, expanding infrastructure, landscape development, and riparian vegetation loss. Using the NECB-UII as a characterization of urbanization, we describe how landscape fragmentation occurs with urbanization and how changes in the invertebrate assemblages, represented by metrics of ecological condition, are related to urbanization. Metrics with a strong linear response included EPT taxa richness, percentage richness of non-insect taxa, and pollution-tolerance values. Additionally, we describe how these relations can help in estimating the expected condition of a stream for its level of urbanization, thereby establishing a baseline for evaluating possible affects from specific point-source stressors.

River water quality and pollution sources in the Pearl River Delta, China.

PubMed

Ouyang, Tingping; Zhu, Zhaoyu; Kuang, Yaoqiu

2005-07-01

Some physicochemical parameters were determined for thirty field water samples collected from different water channels in the Pearl River Delta Economic Zone river system. The analytical results were compared with the environmental quality standards for surface water. Using the SPSS software, statistical analyses were performed to determine the main pollutants of the river water. The main purpose of the present research is to investigate the river water quality and to determine the main pollutants and pollution sources. Furthermore, the research provides some approaches for protecting and improving river water quality. The results indicate that the predominant pollutants are ammonium, phosphorus, and organic compounds. The wastewater discharged from households in urban and rural areas, industrial facilities, and non-point sources from agricultural areas are the main sources of pollution in river water in the Pearl River Delta Economic Zone.

Methane source identification in Boston, Massachusetts using isotopic and ethane measurements

NASA Astrophysics Data System (ADS)

Down, A.; Jackson, R. B.; Plata, D.; McKain, K.; Wofsy, S. C.; Rella, C.; Crosson, E.; Phillips, N. G.

2012-12-01

Methane has substantial greenhouse warming potential and is the principle component of natural gas. Fugitive natural gas emissions could be a significant source of methane to the atmosphere. However, the cumulative magnitude of natural gas leaks is not yet well constrained. We used a combination of point source measurements and ambient monitoring to characterize the methane sources in the Boston urban area. We developed distinct fingerprints for natural gas and multiple biogenic methane sources based on hydrocarbon concentration and isotopic composition. We combine these data with periodic measurements of atmospheric methane and ethane concentration to estimate the fractional contribution of natural gas and biogenic methane sources to the cumulative urban methane flux in Boston. These results are used to inform an inverse model of urban methane concentration and emissions.

Effects of Concrete Channels on Stream Biogeochemistry, Maryland Coastal Plain

NASA Astrophysics Data System (ADS)

Prestegaard, K. L.; Gilbert, L.; Phemister, K.

2005-05-01

In the 1950's and 60's, extensive networks of cement-lined channels were built in suburban watersheds near Washington, D.C. to convey storm water to downstream locations. These cement-lined stream channels limit interactions between surface and groundwater and they provide sources of alkalinity in Maryland Coastal Plain watersheds that normally have low alkalinity. This project was designed to 1) compare base flow water chemistry in headwater reaches of urban and non-urban streams, and 2) to evaluate downstream changes in water chemistry in channelized urban streams in comparison with non-urban reference streams. During a drought year, headwater streams in both urban and non-urban sites had significant concentrations of Fe(II) that were discharged from groundwater sources and rapidly oxidized by iron-oxidizing bacteria. During a wet year, the concentrations of Fe(II) were higher in headwater urban streams than in the non-urban streams. This suggests that impervious surfaces in headwater urban watersheds prevent the recharge of oxygen-rich waters during storm events, which maintains iron-rich groundwater discharge to the stream. Downstream changes in water chemistry are prominent in cement-lined urban channels because they are associated with distinctive microbial communities. The headwater zones of channelized streams are dominated by iron-ozidizing bacteria, that are replaced downstream by manganese-oxidizing zones, and replaced further downstream by biofilms dominated by photosynthesizing cyanobacteria. The reaches dominated by cyanobacteria exhibit diurnal changes in pH due to uptake of CO2 for photosynthesis. Diurnal changes range from 7.5 to 8.8 in the summer months to 7.0 to 7.5 in the cooler months, indicating both the impact of photosynthesis and the additional source of alkalinity provided by concrete. The dissolved oxygen, pH, and other characteristics of tributaries dominated by cyanobacteria are similar to the water chemistry characteristics observed in much larger urban river channels further downstream. These downstream redox zonations, microbial habitats, and pH characteristics observed in channelized tributaries are very different from non-urban watersheds in the Maryland Coastal Plain, which have pH values less than 7 and do not have the prominent redox zonations and associated microbial habitats. These downstream changes in redox chemistry and pH in urban stream channels have implications for the transport and retention of heavy metals in urban streams.

Estimating population exposure to ambient polycyclic aromatic hydrocarbon in the United States - Part II: Source apportionment and cancer risk assessment.

PubMed

Zhang, Jie; Wang, Peng; Li, Jingyi; Mendola, Pauline; Sherman, Seth; Ying, Qi

2016-12-01

A revised Community Multiscale Air Quality (CMAQ) model was developed to simulate the emission, reactions, transport, deposition and gas-to-particle partitioning processes of 16 priority polycyclic aromatic hydrocarbons (PAHs), as described in Part I of the two-part series. The updated CMAQ model was applied in this study to quantify the contributions of different emission sources to the predicted PAH concentrations and excess cancer risk in the United States (US) in 2011. The cancer risk in the continental US due to inhalation exposure of outdoor naphthalene (NAPH) and seven larger carcinogenic PAHs (cPAHs) was predicted to be significant. The incremental lifetime cancer risk (ILCR) exceeds 1×10 -5 in many urban and industrial areas. Exposure to PAHs was estimated to result in 5704 (608-10,800) excess lifetime cancer cases. Point sources not related with energy generation and the oil and gas processes account for approximately 31% of the excess cancer cases, followed by non-road engines with 18.6% contributions. Contributions of residential wood combustion (16.2%) are similar to that of transportation-related sources (mostly motor vehicles with small contributions from railway and marine vessels; 13.4%). The oil and gas industry emissions, although large contributors to high concentrations of cPAHs regionally, are only responsible of 4.3% of the excess cancer cases, which is similar to the contributions of non-US sources (6.8%) and non-point sources (7.2%). The power generation units pose the most minimal impact on excess cancer risk, with contributions of approximately 2.3%. Copyright © 2016 Elsevier Ltd. All rights reserved.

Does Migration Limit the Effect of Health Insurance on Hypertension Management in China?

PubMed

Fang, Hai; Jin, Yinzi; Zhao, Miaomiao; Zhang, Huyang; A Rizzo, John; Zhang, Donglan; Hou, Zhiyuan

2017-10-20

Background: In China, rapid urbanization has caused migration from rural to urban areas, and raised the prevalence of hypertension. However, public health insurance is not portable from one place to another, and migration may limit the effectiveness of this non-portable health insurance on healthcare. Our study aims to investigate whether migration limits the effectiveness of health insurance on hypertension management in China. Methods: Data were obtained from the national baseline survey of the China Health and Retirement Longitudinal Study in 2011, including 4926 hypertensive respondents with public health insurance. Outcome measures included use of primary care, hypertension awareness, medication use, blood pressure monitoring, physician advice, and blood pressure control. Multivariate logistic regressions were estimated to examine whether the effects of rural health insurance on hypertension management differed between those who migrated to urban areas and those who did not migrate and lived in rural areas. Results: Among hypertensive respondents, 60.7% were aware of their hypertensive status. Compared to rural residents, the non-portable feature of rural health insurance significantly reduced rural-to-urban migrants' probabilities of using primary care by 7.8 percentage points, hypertension awareness by 8.8 percentage points, and receiving physician advice by 18.3 percentage points. Conclusions: In China, migration to urban areas limited the effectiveness of rural health insurance on hypertension management due to its non-portable nature. It is critical to improve the portability of rural health insurance, and to extend urban health insurance and primary care coverage to rural-to-urban migrants to achieve better chronic disease management.

Does Migration Limit the Effect of Health Insurance on Hypertension Management in China?

PubMed Central

Fang, Hai; Jin, Yinzi; Zhang, Huyang; A. Rizzo, John; Zhang, Donglan; Hou, Zhiyuan

2017-01-01

Background: In China, rapid urbanization has caused migration from rural to urban areas, and raised the prevalence of hypertension. However, public health insurance is not portable from one place to another, and migration may limit the effectiveness of this non-portable health insurance on healthcare. Our study aims to investigate whether migration limits the effectiveness of health insurance on hypertension management in China. Methods: Data were obtained from the national baseline survey of the China Health and Retirement Longitudinal Study in 2011, including 4926 hypertensive respondents with public health insurance. Outcome measures included use of primary care, hypertension awareness, medication use, blood pressure monitoring, physician advice, and blood pressure control. Multivariate logistic regressions were estimated to examine whether the effects of rural health insurance on hypertension management differed between those who migrated to urban areas and those who did not migrate and lived in rural areas. Results: Among hypertensive respondents, 60.7% were aware of their hypertensive status. Compared to rural residents, the non-portable feature of rural health insurance significantly reduced rural-to-urban migrants’ probabilities of using primary care by 7.8 percentage points, hypertension awareness by 8.8 percentage points, and receiving physician advice by 18.3 percentage points. Conclusions: In China, migration to urban areas limited the effectiveness of rural health insurance on hypertension management due to its non-portable nature. It is critical to improve the portability of rural health insurance, and to extend urban health insurance and primary care coverage to rural-to-urban migrants to achieve better chronic disease management. PMID:29053607

Total Nitrogen Sources of the Three Gorges Reservoir — A Spatio-Temporal Approach

PubMed Central

Ren, Chunping; Wang, Lijing; Zheng, Binghui; Holbach, Andreas

2015-01-01

Understanding the spatial and temporal variation of nutrient concentrations, loads, and their distribution from upstream tributaries is important for the management of large lakes and reservoirs. The Three Gorges Dam was built on the Yangtze River in China, the world’s third longest river, and impounded the famous Three Gorges Reservoir (TGR). In this study, we analyzed total nitrogen (TN) concentrations and inflow data from 2003 till 2010 for the main upstream tributaries of the TGR that contribute about 82% of the TGR’s total inflow. We used time series analysis for seasonal decomposition of TN concentrations and used non-parametric statistical tests (Kruskal-Walli H, Mann-Whitney U) as well as base flow segmentation to analyze significant spatial and temporal patterns of TN pollution input into the TGR. Our results show that TN concentrations had significant spatial heterogeneity across the study area (Tuo River> Yangtze River> Wu River> Min River> Jialing River>Jinsha River). Furthermore, we derived apparent seasonal changes in three out of five upstream tributaries of the TGR rivers (Kruskal-Walli H ρ = 0.009, 0.030 and 0.029 for Tuo River, Jinsha River and Min River in sequence). TN pollution from non-point sources in the upstream tributaries accounted for 68.9% of the total TN input into the TGR. Non-point source pollution of TN revealed increasing trends for 4 out of five upstream tributaries of the TGR. Land use/cover and soil type were identified as the dominant driving factors for the spatial distribution of TN. Intensifying agriculture and increasing urbanization in the upstream catchments of the TGR were the main driving factors for non-point source pollution of TN increase from 2003 till 2010. Land use and land cover management as well as chemical fertilizer use restriction were needed to overcome the threats of increasing TN pollution. PMID:26510158

A multi-model approach to monitor emissions of CO2 and CO from an urban-industrial complex

NASA Astrophysics Data System (ADS)

Super, Ingrid; Denier van der Gon, Hugo A. C.; van der Molen, Michiel K.; Sterk, Hendrika A. M.; Hensen, Arjan; Peters, Wouter

2017-11-01

Monitoring urban-industrial emissions is often challenging because observations are scarce and regional atmospheric transport models are too coarse to represent the high spatiotemporal variability in the resulting concentrations. In this paper we apply a new combination of an Eulerian model (Weather Research and Forecast, WRF, with chemistry) and a Gaussian plume model (Operational Priority Substances - OPS). The modelled mixing ratios are compared to observed CO2 and CO mole fractions at four sites along a transect from an urban-industrial complex (Rotterdam, the Netherlands) towards rural conditions for October-December 2014. Urban plumes are well-mixed at our semi-urban location, making this location suited for an integrated emission estimate over the whole study area. The signals at our urban measurement site (with average enhancements of 11 ppm CO2 and 40 ppb CO over the baseline) are highly variable due to the presence of distinct source areas dominated by road traffic/residential heating emissions or industrial activities. This causes different emission signatures that are translated into a large variability in observed ΔCO : ΔCO2 ratios, which can be used to identify dominant source types. We find that WRF-Chem is able to represent synoptic variability in CO2 and CO (e.g. the median CO2 mixing ratio is 9.7 ppm, observed, against 8.8 ppm, modelled), but it fails to reproduce the hourly variability of daytime urban plumes at the urban site (R2 up to 0.05). For the urban site, adding a plume model to the model framework is beneficial to adequately represent plume transport especially from stack emissions. The explained variance in hourly, daytime CO2 enhancements from point source emissions increases from 30 % with WRF-Chem to 52 % with WRF-Chem in combination with the most detailed OPS simulation. The simulated variability in ΔCO :  ΔCO2 ratios decreases drastically from 1.5 to 0.6 ppb ppm-1, which agrees better with the observed standard deviation of 0.4 ppb ppm-1. This is partly due to improved wind fields (increase in R2 of 0.10) but also due to improved point source representation (increase in R2 of 0.05) and dilution (increase in R2 of 0.07). Based on our analysis we conclude that a plume model with detailed and accurate dispersion parameters adds substantially to top-down monitoring of greenhouse gas emissions in urban environments with large point source contributions within a ˜ 10 km radius from the observation sites.

Connecting Water Quality With Air Quality Through Microbial Aerosols

NASA Astrophysics Data System (ADS)

Dueker, M. Elias

Aerosol production from surface waters results in the transfer of aquatic materials (including nutrients and bacteria) to air. These materials can then be transported by onshore winds to land, representing a biogeochemical connection between aquatic and terrestrial systems not normally considered. In urban waterfront environments, this transfer could result in emissions of pathogenic bacteria from contaminated waters. Despite the potential importance of this link, sources, near-shore deposition, identity and viability of microbial aerosols are largely uncharacterized. This dissertation focuses on the environmental and biological mechanisms that define this water-air connection, as a means to build our understanding of the biogeochemical, biogeographical, and public health implications of the transfer of surface water materials to the near-shore environment in both urban and non-urban environments. The effects of tidal height, wind speed and fog on coastal aerosols and microbial content were first quantified on a non-urban coast of Maine, USA. Culture-based, culture-independent, and molecular methods were used to simultaneously sample microbial aerosols while monitoring meteorological parameters. Aerosols at this site displayed clear marine influence and high concentrations of ecologically-relevant nutrients. Coarse aerosol concentrations significantly increased with tidal height, onshore wind speed, and fog presence. Tidal height and fog presence did not significantly influence total microbial aerosol concentrations, but did have a significant effect on culturable microbial aerosol fallout. Molecular analyses of the microbes settling out of near-shore aerosols provided further evidence of local ocean to terrestrial transport of microbes. Aerosol and surface ocean bacterial communities shared species and in general were dominated by organisms previously sampled in marine environments. Fog presence strengthened the microbial connection between water and land through air by increasing microbial aerosol settling rates and enhancing viability of aerosolized marine microbes. Using methods developed for the non-urban site, the role of local environment and winds in mediating water-air connections was further investigated in the urban environment. The local environment, including water surfaces, was an important source of microbial aerosols at urban sites. Large portions of the urban waterfront microbial aerosol communities were aquatic and, at a highly polluted Superfund waterfront, were closely related to bacteria previously described in environments contaminated with hydrocarbons, heavy metals, sewage and other industrial waste. Culturable urban aerosols and surface waters contained bacterial genera known to include human pathogens and asthma agents. High onshore winds strengthened this water-air connection by playing both a transport and production role. The microbial connection between water and air quality outlined by this dissertation highlights the need for information on the mechanisms that deliver surface water materials to terrestrial systems on a much larger scale. Moving from point measurements to landscape-level analyses will allow for the quantitative assessment of implications for this microbial water-air-land transfer in both urban and non-urban arenas.

Effect of intermittent operation model on the function of soil infiltration system.

PubMed

Hou, Lizhu; Hu, Bill X; He, Mengmeng; Xu, Xue; Zhang, Wenjing

2018-04-01

To enhance denitrification in a process of solute infiltration through a soil, a two-section mixed-medium soil infiltration system (TMSIS) for urban non-point pollution was developed. The artificial aerobic respiration and nitrification took place in the upper aerobic section (AES), while grass powders and sawdust were mixed in the bottom anaerobic section (ANS) to supply organic carbon source for denitrification bacteria, and the reduction was increased by iron addition in the ANS. Measured resident concentrations from the bottom of each ANS column were assumed to represent mean values averaged over the column cross-sectional area. The TMSIS with hydraulic loading rates (HLR) of 0.32, 0.24, and 0.16 m 3  m -2  day -1 and with wetting-drying ratio (R WD ) of 1.0 showed remarkable removal efficiencies for chemical oxygen demand (COD), NH 4 + -N, and TP, respectively. The hydraulic loading rate of 0.32 m 3  m -2  day -1 was selected as the optimal HLR due to the high contaminated runoff treatment efficiency. When R WD was 1.0, 0.5, or 0.2 with hydraulic loading rate of 0.32 m 3  m -2  day -1 , the TMSIS could treat synthetic urban runoff contaminants very well. The corresponding effluent water met the China's national quality standard for class V surface water. The wetting-drying ratio of 0.5 with hydraulic loading of 0.32 m 3  m -2  day -1 was selected as the optimal operation conditions for the TMSIS. Aerobic respiration and nitrification mainly took place in the upper AES, in which most of the COD and the NH 4 + -N were removed. Mixed sawdust and grass powders used as a carbon source and heterotrophic denitrification were put at the bottom of the ANS. The developed TMSIS has the potential to be applied for urban non-point pollution removal.

Calculation and analysis of the non-point source pollution in the upstream watershed of the Panjiakou Reservoir, People's Republic of China

NASA Astrophysics Data System (ADS)

Zhang, S.; Tang, L.

2007-05-01

Panjiakou Reservoir is an important drinking water resource in Haihe River Basin, Hebei Province, People's Republic of China. The upstream watershed area is about 35,000 square kilometers. Recently, the water pollution in the reservoir is becoming more serious owing to the non-point pollution as well as point source pollution on the upstream watershed. To effectively manage the reservoir and watershed and develop a plan to reduce pollutant loads, the loading of non-point and point pollution and their distribution on the upstream watershed must be understood fully. The SWAT model is used to simulate the production and transportation of the non-point source pollutants in the upstream watershed of the Panjiakou Reservoir. The loadings of non-point source pollutants are calculated for different hydrologic years and the spatial and temporal characteristics of non-point source pollution are studied. The stream network and topographic characteristics of the stream network and sub-basins are all derived from the DEM by ArcGIS software. The soil and land use data are reclassified and the soil physical properties database file is created for the model. The SWAT model was calibrated with observed data of several hydrologic monitoring stations in the study area. The results of the calibration show that the model performs fairly well. Then the calibrated model was used to calculate the loadings of non-point source pollutants for a wet year, a normal year and a dry year respectively. The time and space distribution of flow, sediment and non-point source pollution were analyzed depending on the simulated results. The comparison of different hydrologic years on calculation results is dramatic. The loading of non-point source pollution in the wet year is relatively larger but smaller in the dry year since the non-point source pollutants are mainly transported through the runoff. The pollution loading within a year is mainly produced in the flood season. Because SWAT is a distributed model, it is possible to view model output as it varies across the basin, so the critical areas and reaches can be found in the study area. According to the simulation results, it is found that different land uses can yield different results and fertilization in rainy season has an important impact on the non- point source pollution. The limitations of the SWAT model are also discussed and the measures of the control and prevention of non- point source pollution for Panjiakou Reservoir are presented according to the analysis of model calculation results.

Forecasting land use change and its environmental impact at a watershed scale.

PubMed

Tang, Z; Engel, B A; Pijanowski, B C; Lim, K J

2005-07-01

Urban expansion is a major driving force altering local and regional hydrology and increasing non-point source (NPS) pollution. To explore these environmental consequences of urbanization, land use change was forecast, and long-term runoff and NPS pollution were assessed in the Muskegon River watershed, located on the eastern coast of Lake Michigan. A land use change model, LTM, and a web-based environmental impact model, L-THIA, were used in this study. The outcomes indicated the watershed would likely be subjected to impacts from urbanization on runoff and some types of NPS pollution. Urbanization will slightly or considerably increase runoff volume, depending on the development rate, slightly increase nutrient losses in runoff, but significantly increase losses of oil and grease and certain heavy metals in runoff. The spatial variation of urbanization and its impact were also evaluated at the subwatershed scale and showed subwatersheds along the coast of the lake and close to cities would have runoff and nitrogen impact. The results of this study have significant implications for urban planning and decision making in an effort to protect and remediate water and habitat quality of Muskegon Lake, which is one of Lake Michigan's Areas of Concern (AOC), and the techniques described here can be used in other areas.

An Ecosystem-Service Approach to Evaluate the Role of Non-Native Species in Urbanized Wetlands

PubMed Central

Yam, Rita S. W.; Huang, Ko-Pu; Hsieh, Hwey-Lian; Lin, Hsing-Juh; Huang, Shou-Chung

2015-01-01

Natural wetlands have been increasingly transformed into urbanized ecosystems commonly colonized by stress-tolerant non-native species. Although non-native species present numerous threats to natural ecosystems, some could provide important benefits to urbanized ecosystems. This study investigated the extent of colonization by non-native fish and bird species of three urbanized wetlands in subtropical Taiwan. Using literature data the role of each non-native species in the urbanized wetland was evaluated by their effect (benefits/damages) on ecosystem services (ES) based on their ecological traits. Our sites were seriously colonized by non-native fishes (39%–100%), but <3% by non-native birds. Although most non-native species could damage ES regulation (disease control and wastewater purification), some could be beneficial to the urbanized wetland ES. Our results indicated the importance of non-native fishes in supporting ES by serving as food source to fish-eating waterbirds (native, and migratory species) due to their high abundance, particularly for Oreochromis spp. However, all non-native birds are regarded as “harmful” species causing important ecosystem disservices, and thus eradication of these bird-invaders from urban wetlands would be needed. This simple framework for role evaluation of non-native species represents a holistic and transferable approach to facilitate decision making on management priority of non-native species in urbanized wetlands. PMID:25860870

An unexpected truth: increasing nitrate loading can decrease nitrate export from watersheds

NASA Astrophysics Data System (ADS)

Askarizadeh Bardsiri, A.; Grant, S. B.; Rippy, M.

2015-12-01

The discharge of anthropogenic nitrate (e.g., from partially treated sewage, return flows from agricultural irrigation, and runoff from animal feeding operations) to streams can negatively impact both human and ecosystem health. Managing these many point and non-point sources to achieve some specific end-point—for example, reducing the annual mass of nitrate exported from a watershed—can be a challenge, particularly in rapidly growing urban areas. Adding to this complexity is the fact that streams are not inert: they too can add or remove nitrate through assimilation (e.g., by stream-associated plants and animals) and microbially-mediated biogeochemical reactions that occur in streambed sediments (e.g., respiration, ammonification, nitrification, denitrification). By coupling a previously published correlation for in-stream processing of nitrate [Mulholland et al., Nature, 2008, 452, 202-205] with a stream network model of the Jacksons Creek watershed (Victoria, Australia) I demonstrate that managing anthropogenic sources of stream nitrate without consideration of in-stream processing can result in a number of non-intuitive "surprises"; for example, wastewater effluent discharges that increase nitrate loading but decrease in-stream nitrate concentrations can reduce the mass of nitrate exported from a watershed.

Characterizing the size distribution of particles in urban stormwater by use of fixed-point sample-collection methods

USGS Publications Warehouse

Selbig, William R.; Bannerman, Roger T.

2011-01-01

The U.S Geological Survey, in cooperation with the Wisconsin Department of Natural Resources (WDNR) and in collaboration with the Root River Municipal Stormwater Permit Group monitored eight urban source areas representing six types of source areas in or near Madison, Wis. in an effort to improve characterization of particle-size distributions in urban stormwater by use of fixed-point sample collection methods. The types of source areas were parking lot, feeder street, collector street, arterial street, rooftop, and mixed use. This information can then be used by environmental managers and engineers when selecting the most appropriate control devices for the removal of solids from urban stormwater. Mixed-use and parking-lot study areas had the lowest median particle sizes (42 and 54 (u or mu)m, respectively), followed by the collector street study area (70 (u or mu)m). Both arterial street and institutional roof study areas had similar median particle sizes of approximately 95 (u or mu)m. Finally, the feeder street study area showed the largest median particle size of nearly 200 (u or mu)m. Median particle sizes measured as part of this study were somewhat comparable to those reported in previous studies from similar source areas. The majority of particle mass in four out of six source areas was silt and clay particles that are less than 32 (u or mu)m in size. Distributions of particles ranging from 500 (u or mu)m were highly variable both within and between source areas. Results of this study suggest substantial variability in data can inhibit the development of a single particle-size distribution that is representative of stormwater runoff generated from a single source area or land use. Continued development of improved sample collection methods, such as the depth-integrated sample arm, may reduce variability in particle-size distributions by mitigating the effect of sediment bias inherent with a fixed-point sampler.

Speciated atmospheric mercury and its potential source in Guiyang, China

NASA Astrophysics Data System (ADS)

Fu, Xuewu; Feng, Xinbin; Qiu, Guangle; Shang, Lihai; Zhang, Hui

2011-08-01

Speciated atmospheric mercury (Hg) including gaseous elemental mercury (GEM), particulate Hg (PHg), and reactive gaseous Hg (RGM) were continuously measured at an urban site in Guiyang city, southwest China from August to December 2009. The averaged concentrations for GEM, PHg, and RGM were 9.72 ± 10.2 ng m -3, 368 ± 676 pg m -3, and 35.7 ± 43.9 pg m -3, respectively, which were all highly elevated compared to observations at urban sites in Europe and North America. GEM and PHg were characterized by similar monthly and diurnal patterns, with elevated levels in cold months and nighttime, respectively. In contrast, RGM did not exhibit clear monthly and diurnal variations. The variations of GEM, PHg, and RGM indicate the sampling site was significantly impacted by sources in the city municipal area. Sources identification implied that both residential coal burning and large point sources were responsible to the elevated GEM and PHg concentrations; whereas point sources were the major contributors to elevated RGM concentrations. Point sources played a different role in regulating GEM, PHg, and RGM concentrations. Aside from residential emissions, PHg levels was mostly affected by small-scale coal combustion boilers situated to the east of the sampling site, which were scarcely equipped or lacking particulate control devices; whereas point sources situated to the east, southeast, and southwest of the sampling played an important role on the distribution of atmospheric GEM and RGM.

Using CSLD Method to Calculate COD Pollution Load of Wei River Watershed above Huaxian Section, China

NASA Astrophysics Data System (ADS)

Zhu, Lei; Song, JinXi; Liu, WanQing

2017-12-01

Huaxian Section is the last hydrological and water quality monitoring section of Weihe River Watershed. Weihe River Watershed above Huaxian Section is taken as the research objective in this paper and COD is chosen as the water quality parameter. According to the discharge characteristics of point source pollutions and non-point source pollutions, a new method to estimate pollution loads—characteristic section load(CSLD) method is suggested and point source pollution and non-point source pollution loads of Weihe River Watershed above Huaxian Section are calculated in the rainy, normal and dry season in the year 2007. The results show that the monthly point source pollution loads of Weihe River Watershed above Huaxian Section discharge stably and the monthly non-point source pollution loads of Weihe River Watershed above Huaxian Section change greatly and the non-point source pollution load proportions of total pollution load of COD decrease in the normal, rainy and wet period in turn.

Calculating NH3-N pollution load of wei river watershed above Huaxian section using CSLD method

NASA Astrophysics Data System (ADS)

Zhu, Lei; Song, JinXi; Liu, WanQing

2018-02-01

Huaxian Section is the last hydrological and water quality monitoring section of Weihe River Watershed. So it is taken as the research objective in this paper and NH3-N is chosen as the water quality parameter. According to the discharge characteristics of point source pollutions and non-point source pollutions, a new method to estimate pollution loads—characteristic section load (CSLD)method is suggested and point source pollution and non-point source pollution loads of Weihe River Watershed above Huaxian Section are calculated in the rainy, normal and dry season in the year 2007. The results show that the monthly point source pollution loads of Weihe River Watershed above Huaxian Section discharge stably and the monthly non-point source pollution loads of Weihe River Watershed above Huaxian Section change greatly. The non-point source pollution load proportions of total pollution load of NH3-N decrease in the normal, rainy and wet period in turn.

Magnitudes, nature, and effects of point and nonpoint discharges in the Chattahoochee River Basin, Atlanta to West Point Dam, Georgia

USGS Publications Warehouse

Stamer, J.K.; Cherry, Rodney N.; Faye, R.E.; Kleckner, R.L.

1979-01-01

During the period April 1975 to June 1978, the U.S. Geological Survey conducted a river-quality assessment of the Upper Chattahoochee River basin in Georgia. One objective of the study was to assess the magnitudes, nature, and effects of point and non-point discharges in the Chattahoochee River basin from Atlanta to the West Point Dam. On an average annual basis and during the storm period of March 1215, 1976, non-point-source loads for most constituents analyzed were larger than point-source loads at the Whitesburg station, located on the Chattahoochee River about 40 river miles downstream of Atlanta. Most of the non-point-source constituent loads in the Atlanta-to-Whitesburg reach were from urban areas. Average annual point-source discharges accounted for about 50 percent of the dissolved nitrogen, total nitrogen, and total phosphorus loads, and about 70 percent of the dissolved phosphorus loads at Whitesburg. During weekends, power generation at the upstream Buford Dam hydroelectric facility is minimal. Streamflow at the Atlanta station during dry-weather weekends is estimated to be about 1,200 ft3/s (cubic feet per second). Average daily dissolved-oxygen concentrations of less than 5.0 mg/L (milligrams per liter) occurred often in the river, about 20 river miles downstream from Atlanta during these periods from May to November. During a low-flow period, June 1-2, 1977, five municipal point sources contributed 63 percent of the ultimate biochemical oxygen demand, 97 percent of the ammonium nitrogen, 78 percent of the total nitrogen, and 90 percent of the total phosphorus loads at the Franklin station, at the upstream end of West Point Lake. Average daily concentrations of 13 mg/L of ultimate biochemical oxygen demand and 1.8 mg/L of ammonium nitrogen were observed about 2 river miles downstream from two of the municipal point sources. Carbonaceous and nitrogenous oxygen demands caused dissolved-oxygen concentrations between 4.1 and 5.0 mg/L to occur in a 22-mile reach of the river downstream from Atlanta. Nitrogenous oxygen demands were greater than carbonaceous oxygen demands in the reach from river mile 303 to 271, and carbonaceous demands were greater from river mile 271 to 235. The heat load from the Atkinson-McDonough thermoelectric power-plants caused a decrease in the dissolved-oxygen concentrations of about 0.2 mg/L. During a critical low-flow period, a streamflow at Atlanta of about 1,800 ft3/s, with present (1977) point-source flows of 185 ft3/s containing concentrations of 45 mg/L of ultimate biochemical oxygen demand and 15 mg/L of ammonium nitrogen, results in a computed minimum dissolved-oxygen concentration of 4.7 mg/L in the river downstream from Atlanta. In the year 2000, a streamflow at Atlanta of about 1,800 ft3/s with point-source flows of 373 ft3/s containing concentrations of 45 mg/L of ultimate biochemical oxygen demand and 5.0 mg/L of ammonium nitrogen, will result in a computed minimum dissolved-oxygen concentration of 5.0 mg/L. A streamflow of about 1,050 ft3/s at Atlanta in the year 2000 will result in a dissolved-oxygen concentration of 5.0 mg/L if point-source flows contain concentrations of 15 mg/L of ultimate biochemical oxygen demand and 5.0 mg/L of ammonium nitrogen. Phytoplankton concentrations in West Point Lake, about 70 river miles downstream from Atlanta, could exceed 3 million cells per milliliter during extended low-flow periods in the summer with present point- and non-point-source nitrogen and phosphorus loads. In the year 2000, phytoplankton concentrations in West Point Lake are not likely to exceed 700,000 cells per milliliter during extended low-flow periods in the summer, if phosphorus concentrations do not exceed 1.0 mg/L in point-source discharges.

Alkylphenolic compounds and bisphenol A contamination within a heavily urbanized area: case study of Paris.

PubMed

Cladière, Mathieu; Gasperi, Johnny; Lorgeoux, Catherine; Bonhomme, Céline; Rocher, Vincent; Tassin, Bruno

2013-05-01

This study evaluates the influence of a heavily urbanized area (Paris Metropolitan area), on receiving water contamination by both bisphenol A (BPA) and alkylphenol ethoxylate (APE) biodegradation product. The study began by investigating concentrations within urban sources. In addition to the more commonly studied wastewater treatment plant effluent, wet weather urban sources (including combined sewer overflows, urban runoff, and total atmospheric fallout) were considered. The initial results highlight a significant contamination of all urban sources (from a few nanograms per liter in atmospheric fallout to several micrograms per liter in the other sources) with clearly distinguishable distribution patterns. Secondly, concentration changes along the Seine River from upstream of the Paris Metropolitan area to downstream were investigated. While the concentrations of BPA and nonylphenoxy acetic acid (NP₁EC) increase substantially due to urban sources, the 4-nonylphenol concentrations remain homogeneous along the Seine. These results suggest a broad dissemination of 4-nonylphenol at the scale of the Seine River basin. Moreover, the relationship between pollutant concentrations and Seine River flow was assessed both upstream and downstream of the Paris conurbation. Consequently, a sharp decrease in dissolved NP1EC concentrations relative to Seine River flow underscores the influence of single-point urban pollution on Seine River contamination. Conversely, dissolved 4-nonylphenol concentrations serve to reinforce the hypothesis of its widespread presence at the Seine River basin scale.

An Evolving Choice in a Diverse Water Market: A Quality Comparison of Sachet Water with Community and Household Water Sources in Ghana.

PubMed

Guzmán, Danice; Stoler, Justin

2018-06-11

Packaged water, particularly bagged sachet water, has become an important drinking water source in West Africa as local governments struggle to provide safe drinking water supplies. In Ghana, sachet water has become an important primary water source in urban centers, and a growing literature has explored various dimensions of this industry, including product quality. There is very little data on sachet water quality outside of large urban centers, where smaller markets often mean less producer competition and less government regulation. This study analyzes the microbiological quality of sachet water alongside samples of other common water sources at point-of-collection (POC) and point-of-use (POU) in 42 rural, peri-urban, and small-town Ghanaian communities using the IDEXX Colilert ® 18. Levels of coliform bacteria and Escherichia coli detected in sachet water samples were statistically and significantly lower than levels detected in all other water sources at POU, including public taps and standpipes, and statistically similar or significantly lower at POC. In diverse waterscapes where households regularly patch together their water supply from different sources, sachet water appears to be an evolving alternative for safe drinking water despite many caveats, including higher unit costs and limited opportunities to recycle the plastic packaging.

The Lessons of Non-Formal Learning for Urban Youth

ERIC Educational Resources Information Center

Thompson, Carol C.

2012-01-01

Non-formal learning for urban youth has a long history in the United States; it remains a source of innovation. This essay draws on literature about organizations that use community ties to encourage cognitive development and identity formation. It then describes how one youth organization in Camden, New Jersey uses presentations to the community…

Application of a water quality model in the White Cart water catchment, Glasgow, UK.

PubMed

Liu, S; Tucker, P; Mansell, M; Hursthouse, A

2003-03-01

Water quality models of urban systems have previously focused on point source (sewerage system) inputs. Little attention has been given to diffuse inputs and research into diffuse pollution has been largely confined to agriculture sources. This paper reports on new research that is aimed at integrating diffuse inputs into an urban water quality model. An integrated model is introduced that is made up of four modules: hydrology, contaminant point sources, nutrient cycling and leaching. The hydrology module, T&T consists of a TOPMODEL (a TOPography-based hydrological MODEL), which simulates runoff from pervious areas and a two-tank model, which simulates runoff from impervious urban areas. Linked into the two-tank model, the contaminant point source module simulates the overflow from the sewerage system in heavy rain. The widely known SOILN (SOIL Nitrate model) is the basis of nitrogen cycle module. Finally, the leaching module consists of two functions: the production function and the transfer function. The production function is based on SLIM (Solute Leaching Intermediate Model) while the transfer function is based on the 'flushing hypothesis' which postulates a relationship between contaminant concentrations in the receiving water course and the extent to which the catchment is saturated. This paper outlines the modelling methodology and the model structures that have been developed. An application of this model in the White Cart catchment (Glasgow) is also included.

Concentrations in air of organobromine, organochlorine and organophosphate flame retardants in Toronto, Canada

NASA Astrophysics Data System (ADS)

Shoeib, Mahiba; Ahrens, Lutz; Jantunen, Liisa; Harner, Tom

2014-12-01

Concentrations of organobromine (BFRs), organochlorine (CFRs) and organophosphate esters flame retardants and plasticizers (PFRs) in air were monitored for over one year at an urban site in Toronto, Canada during 2010-2011. The mean value for polybrominated diphenyl ethers (BDEs) (gas + particle phase) was 38 pg/m3 with BDE-47 and BDE-99 as the dominant congeners. The mean concentrations in air for ∑non-BDE (BFRs and CFRs), was 9.6 pg/m3 - about four times lower than the BDEs. The brominated FRs: TBP-AE, BTBPE, EH-TBB, BEH-TEBP and the chlorinated syn- and anti-DP were detected frequently, ranging from 87% to 96%. Highest concentrations in air among all flame retardant classes were observed for the Σ-PFRs. The yearly mean concentration in air for ΣPFRs was 2643 pg/m3 with detection frequency higher than 80%. Except for TBP-AE and b- DBE-DBCH, non-BDEs (BFRs, CFRs and PFRs) were mainly associated with the particle phase. BDE concentrations in air were positively correlated with temperature indicating that volatilization from local sources was an important factor controlling levels in air. This correlation did not hold for most BFRs, CFRs and PFRs which were mainly on particles. For these compounds, air concentrations in Toronto are likely related to emissions from point sources and advective inputs. This study highlights the importance of urban air monitoring for FRs. Urban air can be considered a sentinel for detecting changes in the use and application of FRs in commercial products.

Large-Eddy Simulation of Chemically Reactive Pollutant Transport from a Point Source in Urban Area

NASA Astrophysics Data System (ADS)

Du, Tangzheng; Liu, Chun-Ho

2013-04-01

Most air pollutants are chemically reactive so using inert scalar as the tracer in pollutant dispersion modelling would often overlook their impact on urban inhabitants. In this study, large-eddy simulation (LES) is used to examine the plume dispersion of chemically reactive pollutants in a hypothetical atmospheric boundary layer (ABL) in neutral stratification. The irreversible chemistry mechanism of ozone (O3) titration is integrated into the LES model. Nitric oxide (NO) is emitted from an elevated point source in a rectangular spatial domain doped with O3. The LES results are compared well with the wind tunnel results available in literature. Afterwards, the LES model is applied to idealized two-dimensional (2D) street canyons of unity aspect ratio to study the behaviours of chemically reactive plume over idealized urban roughness. The relation among various time scales of reaction/turbulence and dimensionless number are analysed.

Changing Regulations of COD Pollution Load of Weihe River Watershed above TongGuan Section, China

NASA Astrophysics Data System (ADS)

Zhu, Lei; Liu, WanQing

2018-02-01

TongGuan Section of Weihe River Watershed is a provincial section between Shaanxi Province and Henan Province, China. Weihe River Watershed above TongGuan Section is taken as the research objective in this paper and COD is chosen as the water quality parameter. According to the discharge characteristics of point source pollutions and non-point source pollutions, a method—characteristic section load (CSLD) method is suggested and point and non-point source pollution loads of Weihe River Watershed above TongGuan Section are calculated in the rainy, normal and dry season in 2013. The results show that the monthly point source pollution loads of Weihe River Watershed above TongGuan Section discharge stably and the monthly non-point source pollution loads of Weihe River Watershed above TongGuan Section change greatly and the non-point source pollution load proportions of total pollution load of COD decrease in the rainy, wet and normal period in turn.

Numerical Simulation of Dispersion from Urban Greenhouse Gas Sources

NASA Astrophysics Data System (ADS)

Nottrott, Anders; Tan, Sze; He, Yonggang; Winkler, Renato

2017-04-01

Cities are characterized by complex topography, inhomogeneous turbulence, and variable pollutant source distributions. These features create a scale separation between local sources and urban scale emissions estimates known as the Grey-Zone. Modern computational fluid dynamics (CFD) techniques provide a quasi-deterministic, physically based toolset to bridge the scale separation gap between source level dynamics, local measurements, and urban scale emissions inventories. CFD has the capability to represent complex building topography and capture detailed 3D turbulence fields in the urban boundary layer. This presentation discusses the application of OpenFOAM to urban CFD simulations of natural gas leaks in cities. OpenFOAM is an open source software for advanced numerical simulation of engineering and environmental fluid flows. When combined with free or low cost computer aided drawing and GIS, OpenFOAM generates a detailed, 3D representation of urban wind fields. OpenFOAM was applied to model scalar emissions from various components of the natural gas distribution system, to study the impact of urban meteorology on mobile greenhouse gas measurements. The numerical experiments demonstrate that CH4 concentration profiles are highly sensitive to the relative location of emission sources and buildings. Sources separated by distances of 5-10 meters showed significant differences in vertical dispersion of plumes, due to building wake effects. The OpenFOAM flow fields were combined with an inverse, stochastic dispersion model to quantify and visualize the sensitivity of point sensors to upwind sources in various built environments. The Boussinesq approximation was applied to investigate the effects of canopy layer temperature gradients and convection on sensor footprints.

WET WEATHER FLOW (WWF) MANAGEMENT AND CONTROL

EPA Science Inventory

Research emphasizes structural and nonstructural approaches that reduce the impacts of WWF-related stressors on receiving waters. Urban WWF pollution emanates from both point sources and diffuse sources including CSOs, SSOs, and stormwater from sewered and unsewered systems. EPA’...

Coral reefs in an urban embayment in Hawaii: a complex case history controlled by natural and anthropogenic stress

NASA Astrophysics Data System (ADS)

Grigg, R. W.

1995-11-01

The effects of natural and anthropogenic stress need to be separated before coral reef ecosystems can be effectively managed. In this paper, a 25 year case history of coral reefs in an urban embayment (Mamala Bay) off Honolulu, Hawaii is described and differences between natural and man-induced stress are distinguished. Mamala Bay is a 30 km long shallow coastal bay bordering the southern (leeward) shore of Oahu and the city of Honolulu in the Hawaiian Islands. During the last 25 years, this area has been hit by two magnitude 5 hurricane events (winds > 240 km/h) generating waves in excess of 7.5 m. Also during this period, two large sewer outfalls have discharged up to 90 million gallons per day (mgd) or (360 × 106 L/day) of point source pollution into the bay. Initially the discharge was raw sewage, but since 1977 it has received advanced primary treatment. Non-point source run-off from the Honolulu watershed also enters the bay on a daily basis. The results of the study show that discharge of raw sewage had a serious but highly localized impact on shallow (˜10 m) reef corals in the bay prior to 1977. After 1977, when treatment was upgraded to the advanced primary level and outfalls were extended to deep water (> 65 m), impacts to reef corals were no longer significant. No measurable effects of either point or non-point source pollution on coral calcification, growth, species composition, diversity or community structure related to pollution can now be detected. Conversely the effects of hurricane waves in 1982 and 1992 together caused major physical destruction to the reefs. In 1982, average coral cover of well-developed offshore reefs dropped from 60-75% to 5-15%. Only massive species in high relief areas survived. Today, recovery is occurring, and notwithstanding major future disturbance events, long-term biological processes should eventually return the coral ecosystems to a more mature successional stage. This case history illustrates the complex nature of the cumulative effects of natural and anthropogenic stress on coral reefs and the need for a long-term data base before the status of a coral reef can be properly interpreted.

Modeling urban air pollution in Budapest using WRF-Chem model

NASA Astrophysics Data System (ADS)

Kovács, Attila; Leelőssy, Ádám; Lagzi, István; Mészáros, Róbert

2017-04-01

Air pollution is a major problem for urban areas since the industrial revolution, including Budapest, the capital and largest city of Hungary. The main anthropogenic sources of air pollutants are industry, traffic and residential heating. In this study, we investigated the contribution of major industrial point sources to the urban air pollution in Budapest. We used the WRF (Weather Research and Forecasting) nonhydrostatic mesoscale numerical weather prediction system online coupled with chemistry (WRF-Chem, version 3.6).The model was configured with three nested domains with grid spacings of 15, 5 and 1 km, representing Central Europe, the Carpathian Basin and Budapest with its surrounding area. Emission data was obtained from the National Environmental Information System. The point source emissions were summed in their respective cells in the second nested domain according to latitude-longitude coordinates. The main examined air pollutants were carbon monoxide (CO) and nitrogen oxides (NOx), from which the secondary compound, ozone (O3) forms through chemical reactions. Simulations were performed under different weather conditions and compared to observations from the automatic monitoring site of the Hungarian Air Quality Network. Our results show that the industrial emissions have a relatively weak role in the urban background air pollution, confirming the effect of industrial developments and regulations in the recent decades. However, a few significant industrial sources and their impact area has been demonstrated.

[Spatio-temporal characteristics and source identification of water pollutants in Wenruitang River watershed].

PubMed

Ma, Xiao-xue; Wang, La-chun; Liao, Ling-ling

2015-01-01

Identifying the temp-spatial distribution and sources of water pollutants is of great significance for efficient water quality management pollution control in Wenruitang River watershed, China. A total of twelve water quality parameters, including temperature, pH, dissolved oxygen (DO), total nitrogen (TN), ammonia nitrogen (NH4+ -N), electrical conductivity (EC), turbidity (Turb), nitrite-N (NO2-), nitrate-N(NO3-), phosphate-P(PO4(3-), total organic carbon (TOC) and silicate (SiO3(2-)), were analyzed from September, 2008 to October, 2009. Geographic information system(GIS) and principal component analysis(PCA) were used to determine the spatial distribution and to apportion the sources of pollutants. The results demonstrated that TN, NH4+ -N, PO4(3-) were the main pollutants during flow period, wet period, dry period, respectively, which was mainly caused by urban point sources and agricultural and rural non-point sources. In spatial terms, the order of pollution was tertiary river > secondary river > primary river, while the water quality was worse in city zones than in the suburb and wetland zone regardless of the river classification. In temporal terms, the order of pollution was dry period > wet period > flow period. Population density, land use type and water transfer affected the water quality in Wenruitang River.

Occurrence and preliminarily environmental risk assessment of selected pharmaceuticals in the urban rivers, China

PubMed Central

Zhou, Haidong; Ying, Tianqi; Wang, Xuelian; Liu, Jianbo

2016-01-01

Twelve selected pharmaceuticals including antibiotics, analgesics, antiepileptics and lipid regulators were analysed and detected in water samples collected from 18 sampling sections along the three main urban rivers in Yangpu District of Shanghai, China during four sampling campaigns. Besides, algal growth inhibition test was conducted to preliminarily assess the eco-toxicology induced by the target pharmaceuticals in the rivers. Mean levels for most of target compounds were generally below 100 ng/L at sampling sections, with the exception of caffeine and paracetamol presenting considerably high concentration. The detected pharmaceuticals in the urban rivers ranged from

Occurrence and preliminarily environmental risk assessment of selected pharmaceuticals in the urban rivers, China

NASA Astrophysics Data System (ADS)

Zhou, Haidong; Ying, Tianqi; Wang, Xuelian; Liu, Jianbo

2016-10-01

Twelve selected pharmaceuticals including antibiotics, analgesics, antiepileptics and lipid regulators were analysed and detected in water samples collected from 18 sampling sections along the three main urban rivers in Yangpu District of Shanghai, China during four sampling campaigns. Besides, algal growth inhibition test was conducted to preliminarily assess the eco-toxicology induced by the target pharmaceuticals in the rivers. Mean levels for most of target compounds were generally below 100 ng/L at sampling sections, with the exception of caffeine and paracetamol presenting considerably high concentration. The detected pharmaceuticals in the urban rivers ranged from

Monitoring of trace metals and pharmaceuticals as anthropogenic and socio-economic indicators of urban and industrial impact on surface waters

NASA Astrophysics Data System (ADS)

Vystavna, Yuliya

2014-05-01

The research focuses on the monitoring of trace metals and pharmaceuticals as potential anthropogenic indicators of industrial and urban influences on surface water in poorly gauged transboundary Ukraine/Russia region. This study includes analysis of tracers use for the indication of water pollution events, including controlled and emerging discharges, and discussion of the detection method of these chemicals. The following criteria were proposed for the evaluation of indicators: specificity (physical chemical properties), variability (spatial and temporal) and practicality (capacity of the sampling and analytical techniques). The combination of grab and passive water sampling (i.e. DGT and POCIS) procedure was applied for the determination of dissolved and labile trace metals (Ag, Cd, Cr, Cu, Ni, Pb and Zn) and pharmaceuticals (carbamazepine, diazepam, paracetamol, caffeine, diclofenac and ketoprofen). Samples were analysed using ICP - MS (trace metals) and LC-MS/MS ESI +/- (pharmaceuticals). Our results demonstrate the distinctive spatial and temporal patterns of trace elements distribution along an urban watercourse. Accordingly, two general groups of trace metals have been discriminated: 'stable' (Cd and Cr) and 'time-varying' (Cu, Zn, Ni and Pb). The relationship Cd >> Cu > Ag > Cr ≥ Zn was proposed as an anthropogenic signature of the industrial and urban activities pressuring the environment from point sources (municipal wastewaters) and the group Pb - Ni was discussed as a relevant fingerprint of the economic activity (industry and transport) mainly from non-point sources (run-off, atmospheric depositions, etc.). Pharmaceuticals with contrasting hydro-chemical properties of molecules (water solubility, bioaccumulation, persistence during wastewater treatment processes) were discriminated on conservative, labile and with combined properties in order to provide information on wastewater treatment plant efficiency, punctual events (e.g. accidents on sewage works, run-off) and uncontrolled discharges. Applying mass balance modeling, medicaments were described as relevant socio-economic indicators, which can give a picture of main social aspects of the region.

Quality Assessment and Comparison of Smartphone and Leica C10 Laser Scanner Based Point Clouds

NASA Astrophysics Data System (ADS)

Sirmacek, Beril; Lindenbergh, Roderik; Wang, Jinhu

2016-06-01

3D urban models are valuable for urban map generation, environment monitoring, safety planning and educational purposes. For 3D measurement of urban structures, generally airborne laser scanning sensors or multi-view satellite images are used as a data source. However, close-range sensors (such as terrestrial laser scanners) and low cost cameras (which can generate point clouds based on photogrammetry) can provide denser sampling of 3D surface geometry. Unfortunately, terrestrial laser scanning sensors are expensive and trained persons are needed to use them for point cloud acquisition. A potential effective 3D modelling can be generated based on a low cost smartphone sensor. Herein, we show examples of using smartphone camera images to generate 3D models of urban structures. We compare a smartphone based 3D model of an example structure with a terrestrial laser scanning point cloud of the structure. This comparison gives us opportunity to discuss the differences in terms of geometrical correctness, as well as the advantages, disadvantages and limitations in data acquisition and processing. We also discuss how smartphone based point clouds can help to solve further problems with 3D urban model generation in a practical way. We show that terrestrial laser scanning point clouds which do not have color information can be colored using smartphones. The experiments, discussions and scientific findings might be insightful for the future studies in fast, easy and low-cost 3D urban model generation field.

Grain size distribution of road-deposited sediment and its contribution to heavy metal pollution in urban runoff in Beijing, China.

PubMed

Zhao, Hongtao; Li, Xuyong; Wang, Xiaomei; Tian, Di

2010-11-15

Pollutant washoff from road-deposited sediment (RDS) is an increasing problem associated with the rapid urbanization of China that results in urban non-point source pollution. Here, we analyzed the RDS grain size distribution and its potential impact on heavy metal pollution in urban runoff from impervious surfaces of urban villages, colleges and residences, and main traffic roads in the Haidian District, Beijing, China. RDS with smaller grain size had a higher metal concentration. Specifically, particles with the smallest grain size (<44 μm) had the highest metal concentration in most areas (unit: mg/kg): Cd 0.28-1.31, Cr 57.9-154, Cu 68.1-142, Ni 25.8-78.0, Pb 73.1-222 and Zn 264-664. Particles with smaller grain size (<250 μm) contributed more than 80% of the total metal loads in RDS washoff, while suspended solids with a grain size <44 μm in runoff water accounted for greater than 70% of the metal mass in the total suspended solids (TSS). The heavy metal content in the TSS was 2.21-6.52% of that in the RDS. These findings will facilitate our understanding of the importance of RDS grain size distribution in heavy metal pollution caused by urban storm runoff. Copyright © 2010 Elsevier B.V. All rights reserved.

The application of electrical conductivity as a tracer for hydrograph separation in urban catchments

USGS Publications Warehouse

Pellerin, B.A.; Wollheim, W.M.; Feng, X.; Vororsmarty, C.J.

2008-01-01

Two-component hydrograph separation was performed on 19 low-to-moderate intensity rainfall events in a 4.1-km2 urban watershed to infer the relative and absolute contribution of surface runoff (e.g. new water) to stormflow generation between 2001 and 2003. The electrical conductivity (EC) of water was used as a continuous and inexpensive tracer, with order of magnitude differences in precipitation (12-46 ??S/cm) and pre-event streamwater EC values (520-1297 ??S/cm). While new water accounted for most of the increased discharge during storms (61-117%), the contribution of new water to total discharge during events was typically lower (18-78%) and negatively correlated with antecedent stream discharge (r2 = 0??55, p < 0??01). The amount of new water was positively correlated with total rainfall (r2 = 0??77), but hydrograph separation results suggest that less than half (9-46%) of the total rainfall on impervious surfaces is rapidly routed to the stream channel as new water. Comparison of hydrograph separation results using non-conservative tracers (EC and Si) and a conservative isotopic tracer (??D) for two events showed similar results and highlighted the potential application of EC as an inexpensive, high frequency tracer for hydrograph separation studies in urban catchments. The use of a simple tracer-based approach may help hydrologists and watershed managers to better understand impervious surface runoff, stormflow generation and non-point-source pollutant loading to urban streams. Copyright ?? 2007 John Wiley & Sons, Ltd.

Links between fear of humans, stress and survival support a non-random distribution of birds among urban and rural habitats

PubMed Central

Rebolo-Ifrán, Natalia; Carrete, Martina; Sanz-Aguilar, Ana; Rodríguez-Martínez, Sol; Cabezas, Sonia; Marchant, Tracy A.; Bortolotti, Gary R.; Tella, José L.

2015-01-01

Urban endocrine ecology aims to understand how organisms cope with new sources of stress and maintain allostatic load to thrive in an increasingly urbanized world. Recent research efforts have yielded controversial results based on short-term measures of stress, without exploring its fitness effects. We measured feather corticosterone (CORTf, reflecting the duration and amplitude of glucocorticoid secretion over several weeks) and subsequent annual survival in urban and rural burrowing owls. This species shows high individual consistency in fear of humans (i.e., flight initiation distance, FID), allowing us to hypothesize that individuals distribute among habitats according to their tolerance to human disturbance. FIDs were shorter in urban than in rural birds, but CORTf levels did not differ, nor were correlated to FIDs. Survival was twice as high in urban as in rural birds and links with CORTf varied between habitats: while a quadratic relationship supports stabilizing selection in urban birds, high predation rates may have masked CORTf-survival relationship in rural ones. These results evidence that urban life does not constitute an additional source of stress for urban individuals, as shown by their near identical CORTf values compared with rural conspecifics supporting the non-random distribution of individuals among habitats according to their behavioural phenotypes. PMID:26348294

Links between fear of humans, stress and survival support a non-random distribution of birds among urban and rural habitats.

PubMed

Rebolo-Ifrán, Natalia; Carrete, Martina; Sanz-Aguilar, Ana; Rodríguez-Martínez, Sol; Cabezas, Sonia; Marchant, Tracy A; Bortolotti, Gary R; Tella, José L

2015-09-08

Urban endocrine ecology aims to understand how organisms cope with new sources of stress and maintain allostatic load to thrive in an increasingly urbanized world. Recent research efforts have yielded controversial results based on short-term measures of stress, without exploring its fitness effects. We measured feather corticosterone (CORTf, reflecting the duration and amplitude of glucocorticoid secretion over several weeks) and subsequent annual survival in urban and rural burrowing owls. This species shows high individual consistency in fear of humans (i.e., flight initiation distance, FID), allowing us to hypothesize that individuals distribute among habitats according to their tolerance to human disturbance. FIDs were shorter in urban than in rural birds, but CORTf levels did not differ, nor were correlated to FIDs. Survival was twice as high in urban as in rural birds and links with CORTf varied between habitats: while a quadratic relationship supports stabilizing selection in urban birds, high predation rates may have masked CORTf-survival relationship in rural ones. These results evidence that urban life does not constitute an additional source of stress for urban individuals, as shown by their near identical CORTf values compared with rural conspecifics supporting the non-random distribution of individuals among habitats according to their behavioural phenotypes.

Social justice, climate change, and dengue.

PubMed

Chang, Aileen Y; Fuller, Douglas O; Carrasquillo, Olveen; Beier, John C

2014-06-14

Climate change should be viewed fundamentally as an issue of global justice. Understanding the complex interplay of climatic and socioeconomic trends is imperative to protect human health and lessen the burden of diseases such as dengue fever. Dengue fever is rapidly expanding globally. Temperature, rainfall, and frequency of natural disasters, as well as non-climatic trends involving population growth and migration, urbanization, and international trade and travel, are expected to increase the prevalence of mosquito breeding sites, mosquito survival, the speed of mosquito reproduction, the speed of viral incubation, the distribution of dengue virus and its vectors, human migration patterns towards urban areas, and displacement after natural disasters. The burden of dengue disproportionately affects the poor due to increased environmental risk and decreased health care. Mobilization of social institutions is needed to improve the structural inequalities of poverty that predispose the poor to increased dengue fever infection and worse outcomes. This paper reviews the link between dengue and climatic factors as a starting point to developing a comprehensive understanding of how climate change affects dengue risk and how institutions can address the issues of social justice and dengue outbreaks that increasingly affect vulnerable urban populations. Copyright © 2014 Chang, Fuller, Carrasquillo, Beier. This is an open access article distributed under the terms of the Creative Commons Attribution Non-Commercial License (http://creativecommons.org/licenses/by-nc/3.0/), which permits unrestricted non-commercial use, distribution, and reproduction in any medium, provided the original author and source are credited.

Urban stormwater capture curve using three-parameter mixed exponential probability density function and NRCS runoff curve number method.

PubMed

Kim, Sangdan; Han, Suhee

2010-01-01

Most related literature regarding designing urban non-point-source management systems assumes that precipitation event-depths follow the 1-parameter exponential probability density function to reduce the mathematical complexity of the derivation process. However, the method of expressing the rainfall is the most important factor for analyzing stormwater; thus, a better mathematical expression, which represents the probability distribution of rainfall depths, is suggested in this study. Also, the rainfall-runoff calculation procedure required for deriving a stormwater-capture curve is altered by the U.S. Natural Resources Conservation Service (Washington, D.C.) (NRCS) runoff curve number method to consider the nonlinearity of the rainfall-runoff relation and, at the same time, obtain a more verifiable and representative curve for design when applying it to urban drainage areas with complicated land-use characteristics, such as occurs in Korea. The result of developing the stormwater-capture curve from the rainfall data in Busan, Korea, confirms that the methodology suggested in this study provides a better solution than the pre-existing one.

Toxicity of chloride under winter low-flow conditions in an urban watershed in central Missouri, USA

USGS Publications Warehouse

Allert, Ann L.; Cole-Neal, Cavelle L.; Fairchild, James F.

2012-01-01

Deicers such as sodium chloride and calcium chloride are used to treat snow and ice on road surfaces and have been identified as potential stressors on aquatic life. Hinkson Creek is an urban stream on the Missouri 303(d) list of impaired waters and is classified as impaired due to urban non-point source pollution. A 7-day toxicity test using Ceriodaphnia dubia was conducted to assess the toxicity of stream water during snowmelt at seven sites within the Hinkson Creek watershed. Chloride concentrations at two sites (Site 6, 1252 mg Cl/L; Site 4, 301 mg Cl/L) exceeded the U.S. Environmental Protection Agency chronic criterion (230 mg Cl/L). Survival (30 %) and total reproduction (6.9 young/adult) of C. dubia at Site 6 was significantly lower than survival (100 %) and total reproduction (30.4 young/adult) at Site 1 (reference site). Results indicate that chloride concentrations are elevated above water-quality criteria and that chloride may be a significant chemical stressor for macroinvertebrate communities during winter low-flow conditions in the Hinkson Creek watershed.

Toxicity of chloride under winter low-flow conditions in an urban watershed in central Missouri, USA.

PubMed

Allert, Ann L; Cole-Neal, Cavelle L; Fairchild, James F

2012-08-01

Deicers such as sodium chloride and calcium chloride are used to treat snow and ice on road surfaces and have been identified as potential stressors on aquatic life. Hinkson Creek is an urban stream on the Missouri 303(d) list of impaired waters and is classified as impaired due to urban non-point source pollution. A 7-day toxicity test using Ceriodaphnia dubia was conducted to assess the toxicity of stream water during snowmelt at seven sites within the Hinkson Creek watershed. Chloride concentrations at two sites (Site 6, 1252 mg Cl/L; Site 4, 301 mg Cl/L) exceeded the U.S. Environmental Protection Agency chronic criterion (230 mg Cl/L). Survival (30 %) and total reproduction (6.9 young/adult) of C. dubia at Site 6 was significantly lower than survival (100 %) and total reproduction (30.4 young/adult) at Site 1 (reference site). Results indicate that chloride concentrations are elevated above water-quality criteria and that chloride may be a significant chemical stressor for macroinvertebrate communities during winter low-flow conditions in the Hinkson Creek watershed.

The Other Water Pollution

ERIC Educational Resources Information Center

Barton, Kathy

1978-01-01

Nonpoint source pollution, water pollution not released at one specific identifiable point, now accounts for 50 percent of the nation's water pollution problem. Runoff is the primary culprit and includes the following sources: agriculture, mining, hydrologic modifications, and urban runoff. Economics, legislation, practices, and management of this…

Decreased waterborne pathogenic bacteria in an urban aquifer related to intense shallow geothermal exploitation.

PubMed

García-Gil, Alejandro; Gasco-Cavero, Samanta; Garrido, Eduardo; Mejías, Miguel; Epting, Jannis; Navarro-Elipe, Mercedes; Alejandre, Carmen; Sevilla-Alcaine, Elena

2018-08-15

The implications of intensive use of shallow geothermal energy resources in shallow urban aquifers are still not known for waterborne pathogens relevant to human health. Firstly, we hypothesized that waterborne enteric pathogens would be relatively increased in heated groundwater plumes. To prove this, microbiological sampling of 31 piezometers covering the domain of an urban groundwater body affected by microbiological contamination and energetically exploited by 70 groundwater heat pump systems was performed. Mean differences of pathogenic bacteria contents between impacted and non-impacted monitoring points were assessed with a two-tailed independent Student's t-test or Mann-Whitney U and correlation coefficients were also calculated. Surprisingly, the results obtained revealed a significant and generalized decrease in waterborne pathogen contents in thermally impacted piezometers compared to that of non-impacted piezometers. This decrease is hypothesized to be caused by a heat shock to bacteria within the heat exchangers. The statistically significant negative correlations obtained between waterborne pathogen counts and temperature could be explained by the spatial distribution of the bacteria, finding that bacteria start to recover with increasing distance from the injection point. Also, different behavior groups fitting exponential regression models were found for the bacteria species studied, justified by the different presence and influence of several aquifer parameters and major, minor and trace elements studied, as well as the coexistence with other bacteria species. The results obtained from this work reinforce the concept of shallow geothermal resources as a clean energy source, as they could also provide the basis to control the pathogenic bacteria contents in groundwater bodies. Copyright © 2018 Elsevier B.V. All rights reserved.

Origin of marine debris is related to disposable packs of ultra-processed food.

PubMed

Andrades, Ryan; Martins, Agnaldo S; Fardim, Lorena M; Ferreira, Juliana S; Santos, Robson G

2016-08-15

Marine debris is currently distributed worldwide, and the discard and contamination pose hazards to human and wildlife health. One of the gaps in debris science is tracking the source of debris to better evaluate and avoid the pathway of debris from the source to marine environment. For this, we evaluated three beaches of different urbanization levels and environmental influences; a low urbanized beach, a highly urbanized beach and a non-urbanized estuary-associated beach, in order to determine the sources and original use of debris. Plastic was the major material found on beaches, and the urbanized beach recorded the highest debris densities. Marine debris was primarily from land-based sources, and the debris recorded in all beaches was mainly assigned as food-related items. Our results highlight the major presence of disposable and short-lived products comprising the majority of debris that enters the ocean and draw attention to the unsustainable lifestyle of current society. Copyright © 2016 Elsevier Ltd. All rights reserved.

SOURCE OF GENOTOXICITY AND CANCER RISK IN AMBIENT AIR

EPA Science Inventory

Products of incomplete combustion are identified as a major source of carcinogenic risk in urban areas, especially those from small non-industrial sources. he major ubiquitous emission i sources outdoors in populated areas are residential home heating and motor vehicles. olycycli...

Differences in Obesity Prevalence by Demographic Characteristics and Urbanization Level Among Adults in the United States, 2013-2016.

PubMed

Hales, Craig M; Fryar, Cheryl D; Carroll, Margaret D; Freedman, David S; Aoki, Yutaka; Ogden, Cynthia L

2018-06-19

Differences in obesity by sex, age group, race and Hispanic origin among US adults have been reported, but differences by urbanization level have been less studied. To provide estimates of obesity by demographic characteristics and urbanization level and to examine trends in obesity prevalence by urbanization level. Serial cross-sectional analysis of measured height and weight among adults aged 20 years or older in the 2001-2016 National Health and Nutrition Examination Survey, a nationally representative survey of the civilian, noninstitutionalized US population. Sex, age group, race and Hispanic origin, education level, smoking status, and urbanization level as assessed by metropolitan statistical areas (MSAs; large: ≥1 million population). Prevalence of obesity (body mass index [BMI] ≥30) and severe obesity (BMI ≥40) by subgroups in 2013-2016 and trends by urbanization level between 2001-2004 and 2013-2016. Complete data on weight, height, and urbanization level were available for 10 792 adults (mean age, 48 years; 51% female [weighted]). During 2013-2016, 38.9% (95% CI, 37.0% to 40.7%) of US adults had obesity and 7.6% (95% CI, 6.8% to 8.6%) had severe obesity. Men living in medium or small MSAs had a higher age-adjusted prevalence of obesity compared with men living in large MSAs (42.4% vs 31.8%, respectively; adjusted difference, 9.8 percentage points [95% CI, 5.1 to 14.5 percentage points]); however, the age-adjusted prevalence among men living in non-MSAs was not significantly different compared with men living in large MSAs (38.9% vs 31.8%, respectively; adjusted difference, 4.8 percentage points [95% CI, -2.9 to 12.6 percentage points]). The age-adjusted prevalence of obesity was higher among women living in medium or small MSAs compared with women living in large MSAs (42.5% vs 38.1%, respectively; adjusted difference, 4.3 percentage points [95% CI, 0.2 to 8.5 percentage points]) and among women living in non-MSAs compared with women living in large MSAs (47.2% vs 38.1%, respectively; adjusted difference, 4.7 percentage points [95% CI, 0.2 to 9.3 percentage points]). Similar patterns were seen for severe obesity except that the difference between men living in large MSAs compared with non-MSAs was significant. The age-adjusted prevalence of obesity and severe obesity also varied significantly by age group, race and Hispanic origin, and education level, and these patterns of variation were often different by sex. Between 2001-2004 and 2013-2016, the age-adjusted prevalence of obesity and severe obesity significantly increased among all adults at all urbanization levels. In this nationally representative survey of adults in the United States, the age-adjusted prevalence of obesity and severe obesity in 2013-2016 varied by level of urbanization, with significantly greater prevalence of obesity and severe obesity among adults living in nonmetropolitan statistical areas compared with adults living in large metropolitan statistical areas.

Analysis of long-term water quality for effective river health monitoring in peri-urban landscapes--a case study of the Hawkesbury-Nepean river system in NSW, Australia.

PubMed

Pinto, U; Maheshwari, B L; Ollerton, R L

2013-06-01

The Hawkesbury-Nepean River (HNR) system in South-Eastern Australia is the main source of water supply for the Sydney Metropolitan area and is one of the more complex river systems due to the influence of urbanisation and other activities in the peri-urban landscape through which it flows. The long-term monitoring of river water quality is likely to suffer from data gaps due to funding cuts, changes in priority and related reasons. Nevertheless, we need to assess river health based on the available information. In this study, we demonstrated how the Factor Analysis (FA), Hierarchical Agglomerative Cluster Analysis (HACA) and Trend Analysis (TA) can be applied to evaluate long-term historic data sets. Six water quality parameters, viz., temperature, chlorophyll-a, dissolved oxygen, oxides of nitrogen, suspended solids and reactive silicates, measured at weekly intervals between 1985 and 2008 at 12 monitoring stations located along the 300 km length of the HNR system were evaluated to understand the human and natural influences on the river system in a peri-urban landscape. The application of FA extracted three latent factors which explained more than 70 % of the total variance of the data and related to the 'bio-geographical', 'natural' and 'nutrient pollutant' dimensions of the HNR system. The bio-geographical and nutrient pollution factors more likely related to the direct influence of changes and activities of peri-urban natures and accounted for approximately 50 % of variability in water quality. The application of HACA indicated two major clusters representing clean and polluted zones of the river. On the spatial scale, one cluster was represented by the upper and lower sections of the river (clean zone) and accounted for approximately 158 km of the river. The other cluster was represented by the middle section (polluted zone) with a length of approximately 98 km. Trend Analysis indicated how the point sources influence river water quality on spatio-temporal scales, taking into account the various effects of nutrient and other pollutant loads from sewerage effluents, agriculture and other point and non-point sources along the river and major tributaries of the HNR. Over the past 26 years, water temperature has significantly increased while suspended solids have significantly decreased (p < 0.05). The analysis of water quality data through FA, HACA and TA helped to characterise the key sections and cluster the key water quality variables of the HNR system. The insights gained from this study have the potential to improve the effectiveness of river health-monitoring programs in terms of cost, time and effort, particularly in a peri-urban context.

Environmental Technology Verification Test Report of Mobile Source Selective Catalytic Reduction, Johnson Matthey SCCRT, Version 1, Selective Catalytic Reduction Technology with a Catalyzed Continuously Regenerating Trap

EPA Science Inventory

The Johnson Matthey SCCRT, v.1 technology is a urea-based SCR system combined with a CCRT filter designed for on-highway light, medium, and heavy heavy-duty diesel, urban and non-urban, bus exhaust gas recirculation (EGR)-or non-EGR-equipped engines for use with commercial ultra-...

Geochemical Indicators of Urban Development in Tributaries and Springs along the Bull Creek Watershed, Austin, TX

NASA Astrophysics Data System (ADS)

Senison, J. J.; Banner, J. L.; Reyes, D.; Sharp, J. M.

2012-12-01

Urbanization can cause significant changes to both flow and water quality in streams and tributaries. In the Austin, Texas, area, previous studies have demonstrated that streamwater strontium isotope compositions (87Sr/86Sr) correlate with measures of urbanization when comparing non-urbanized streams to their urban counterparts. The inclusion of municipal water into natural surface water is inferred from the mean 87Sr/86Sr value found in urbanized streams, which falls between the high value in treated municipal water and the lower values found in local surface streams sourcing from non-urbanized catchments. Fluoride is added to municipal tap water in the treatment process, and a correlation between 87Sr/86Sr and fluoride is observed in streamwater sampled from the watersheds around Austin. These relationships represent some of the principal findings reported in Christian et al. (2011). Current research is testing the hypothesis that municipal water influx in urban areas is a primary modifier of stream- and spring-water chemistry in a single watershed that contains a strong gradient in land use. We compare 87Sr/86Sr and other chemical constituents with potential contributing endmembers, such as municipal tap water and wastewater, local soil and rock leachates, and land use within the Bull Creek watershed. As a consequence of the history of land development, some Bull Creek tributaries are sourced and flow almost entirely in fully-developed areas, whereas others are located in protected natural areas. Thirteen tributaries were monitored and classified as either urbanized or non-urbanized based upon land use within the tributary catchment. Springs in the Bull Creek watershed were also sampled and are similarly classified. The Bull Creek watershed is composed of Lower Cretaceous limestone with significantly lower 87Sr/86Sr than that of municipal water taken from the Lower Colorado River, which is underlain in part by Precambrian rocks upstream of Austin. There are notable differences in urbanized vs. non-urbanized watersheds in mean concentrations of fluoride (urbanized: 0.27 ± 0.08 vs. non-urbanized: 0.19 ± 0.01 ppm), sodium (34.7 ± 17.3 vs. 8.4 ± 1.0 ppm), and potassium (2.9 ± 0.8 vs. 1.2 ± 0.2 ppm), consistent with higher concentrations in municipal water contributing to the urbanized tributaries. Springwater demonstrates similar divergences for these ions. 87Sr/86Sr for the springs falls within a narrow range for non-urbanized springs (0.7079-0.7081), similar to Cretaceous limestone values, whereas urbanized springs contain a larger range (0.7077-0.7087). These results are consistent with urbanization effects in the Bull Creek watershed.

[Estimation of nonpoint source pollutant loads and optimization of the best management practices (BMPs) in the Zhangweinan River basin].

PubMed

Xu, Hua-Shan; Xu, Zong-Xue; Liu, Pin

2013-03-01

One of the key techniques in establishing and implementing TMDL (total maximum daily load) is to utilize hydrological model to quantify non-point source pollutant loads, establish BMPs scenarios, reduce non-point source pollutant loads. Non-point source pollutant loads under different years (wet, normal and dry year) were estimated by using SWAT model in the Zhangweinan River basin, spatial distribution characteristics of non-point source pollutant loads were analyzed on the basis of the simulation result. During wet years, total nitrogen (TN) and total phosphorus (TP) accounted for 0.07% and 27.24% of the total non-point source pollutant loads, respectively. Spatially, agricultural and residential land with steep slope are the regions that contribute more non-point source pollutant loads in the basin. Compared to non-point source pollutant loads with those during the baseline period, 47 BMPs scenarios were set to simulate the reduction efficiency of different BMPs scenarios for 5 kinds of pollutants (organic nitrogen, organic phosphorus, nitrate nitrogen, dissolved phosphorus and mineral phosphorus) in 8 prior controlled subbasins. Constructing vegetation type ditch was optimized as the best measure to reduce TN and TP by comparing cost-effective relationship among different BMPs scenarios, and the costs of unit pollutant reduction are 16.11-151.28 yuan x kg(-1) for TN, and 100-862.77 yuan x kg(-1) for TP, which is the most cost-effective measure among the 47 BMPs scenarios. The results could provide a scientific basis and technical support for environmental protection and sustainable utilization of water resources in the Zhangweinan River basin.

Multi-year levels and trends of non-methane hydrocarbon concentrations observed in ambient air in France

NASA Astrophysics Data System (ADS)

Waked, Antoine; Sauvage, Stéphane; Borbon, Agnès; Gauduin, Julie; Pallares, Cyril; Vagnot, Marie-Pierre; Léonardis, Thierry; Locoge, Nadine

2016-09-01

Measurements of 31 non-methane hydrocarbons (NMHCs) were carried out at three urban (Paris, 2003-2014, Strasbourg, 2002-2014 and Lyon, 2007-2014) sites in France over the period of a decade. A trend analysis was applied by means of the Mann-Kendall non-parametric test to annual and seasonal mean concentrations in order to point out changes in specific emission sources and to assess the impact of emission controls and reduction strategies. The trends were compared to those from three rural sites (Peyrusse-Vieille, 2002-2013, Tardière, 2003-2013 and Donon, 1997-2007). The results obtained showed a significant yearly decrease in pollutant concentrations over the study period and for the majority of species in the range of -1 to -7% in accordance with the decrease of NMHC emissions in France (-5 to -9%). Concentrations of long-lived species such as ethane and propane which are recognized as tracers of distant sources and natural gas remained constant. Compounds associated with combustion processes such as acetylene, propene, ethylene and benzene showed a significant decline in the range of -2% to -5% yr-1. These trends are consistent with those recently described at urban and background sites in the northern mid-latitudes and with emission inventories. C7-C9 aromatics such as toluene and xylenes as well as C4-C5 alkanes such as isopentane and isobutane also showed a significant decrease in the range of -3% to -7% yr-1. The decreasing trends in terms of % yr-1 observed at these French urban sites were typically higher for acetylene, ethylene and benzene than those reported for French rural sites of the national observatory of Measurement and Evaluation in Rural areas of trans-boundary Air pollution (MERA). The study also highlighted the difficult choice of a long term sampling site representative of the general trends of pollutant concentrations.

DISCRIMINATION OF NATURAL AND NON-POINT SOURCE EFFECTS FROM ANTHROGENIC EFFECTS AS REFLECTED IN BENTHIC STATE IN THREE ESTUARIES IN NEW ENGLAND

EPA Science Inventory

In order to protect estuarine resources, managers must be able to discern the effects of natural conditions and non-point source effects, and separate them from multiple anthropogenic point source effects. Our approach was to evaluate benthic community assemblages, riverine nitro...

BEST MANAGEMENT PRACTICES FOR THE CONTROL OF NUTRIENTS FROM URBAN NONPOINT SOURCES

EPA Science Inventory

While the costs and benefits associated with the point source control of nutrients are relatively well defined, considerable uncertainties remain in the efficiency and long-term costs associated with the best management practices (BMPs) used to redcuce loads from nonpoint and dif...

[Spatial heterogeneity and classified control of agricultural non-point source pollution in Huaihe River Basin].

PubMed

Zhou, Liang; Xu, Jian-Gang; Sun, Dong-Qi; Ni, Tian-Hua

2013-02-01

Agricultural non-point source pollution is of importance in river deterioration. Thus identifying and concentrated controlling the key source-areas are the most effective approaches for non-point source pollution control. This study adopts inventory method to analysis four kinds of pollution sources and their emissions intensity of the chemical oxygen demand (COD), total nitrogen (TN), and total phosphorus (TP) in 173 counties (cities, districts) in Huaihe River Basin. The four pollution sources include livestock breeding, rural life, farmland cultivation, aquacultures. The paper mainly addresses identification of non-point polluted sensitivity areas, key pollution sources and its spatial distribution characteristics through cluster, sensitivity evaluation and spatial analysis. A geographic information system (GIS) and SPSS were used to carry out this study. The results show that: the COD, TN and TP emissions of agricultural non-point sources were 206.74 x 10(4) t, 66.49 x 10(4) t, 8.74 x 10(4) t separately in Huaihe River Basin in 2009; the emission intensity were 7.69, 2.47, 0.32 t.hm-2; the proportions of COD, TN, TP emissions were 73%, 24%, 3%. The paper achieves that: the major pollution source of COD, TN and TP was livestock breeding and rural life; the sensitivity areas and priority pollution control areas among the river basin of non-point source pollution are some sub-basins of the upper branches in Huaihe River, such as Shahe River, Yinghe River, Beiru River, Jialu River and Qingyi River; livestock breeding is the key pollution source in the priority pollution control areas. Finally, the paper concludes that pollution type of rural life has the highest pollution contribution rate, while comprehensive pollution is one type which is hard to control.

Quantifying stream channel sediment contributions for the Paradise Creek Watershed in northern Idaho

NASA Astrophysics Data System (ADS)

Rittenburg, R.; Squires, A.; Boll, J.; Brooks, E. S.

2012-12-01

Excess sediment from agricultural areas has been a major source of impairment for water bodies around the world, resulting in the implementation of mitigation measures across landscapes. Watershed scale reductions often target upland erosion as key non-point sources for sediment loading. Stream channel dynamics, however, also play a contributing role in sediment loading in the form of legacy sediments, channel erosion and deposition, and buffering during storm events. Little is known about in-stream contributions, a potentially important consideration for Total Maximum Daily Loads (TMDLs). The objective of this study is to identify where and when sediment is delivered to the stream and the spatial and temporal stream channel contributions to the overall watershed scale sediment load. The study area is the Paradise Creek Watershed in northern Idaho. We modeled sediment yield to the channel system using the Water Erosion Prediction Project (WEPP) model, and subsequent channel erosion and deposition using CONCEPTs. Field observations of cross-sections along the channel system over a 5-year period were collected to verify model simulations and to test the hypothesis that the watershed load was made up predominantly of legacy sediments. Our modeling study shows that stream channels contributed to 50% of the total annual sediment load for the basin, with a 19 year time lag between sediments entering the stream to leaving the watershed outlet. Observations from long-term data in the watershed will be presented to indicate if the main source of the sediment is from either rural and urban non-point sources or the channel system.

Low cost monitoring from space using Landsat TM time series and open source technologies: the case study of Iguazu park

NASA Astrophysics Data System (ADS)

Nole, Gabriele; Lasaponara, Rosa

2015-04-01

Up to nowadays, satellite data have become increasingly available, thus offering a low cost or even free of charge unique tool, with a great potential for operational monitoring of vegetation cover, quantitative assessment of urban expansion and urban sprawl, as well as for monitoring of land use changes and soil consumption. This growing observational capacity has also highlighted the need for research efforts aimed at exploring the potential offered by data processing methods and algorithms, in order to exploit as much as possible this invaluable space-based data source. The work herein presented concerns an application study on the monitoring of vegetation cover and urban sprawl conducted with the use of satellite Landsat TM data. The selected test site is the Iguazu park highly significant, being it one of the most threatened global conservation priorities (http://whc.unesco.org/en/list/303/). In order to produce synthetic maps of the investigated areas to monitor the status of vegetation and ongoing subtle changes, satellite Landsat TM data images were classified using two automatic classifiers, Maximum Likelihood (MLC) and Support Vector Machines (SVMs) applied by changing setting parameters, with the aim to compare their respective performances in terms of robustness, speed and accuracy. All process steps have been developed integrating Geographical Information System and Remote Sensing, and adopting free and open source software. Results pointed out that the SVM classifier with RBF kernel was generally the best choice (with accuracy higher than 90%) among all the configurations compared, and the use of multiple bands globally improves classification. One of the critical elements found in the case of monitoring of urban area expansion is given by the presence of urban garden mixed with urban fabric. The use of different configurations for the SVMs, i.e. different kernels and values of the setting parameters, allowed us to calibrate the classifier also to cope with a specific need, as in our case, to achieve a reliable discrimination of urban from non urban areas. Acknowledgement This research was performed within the framework of the Great relevance project " Smart management of cultural heritage sites in Italy and Argentina: Earth Observation and pilot projects funded by the Ministero degli Affari Esteri e della Cooperazione Internazionale --MAE, 17/04/2014, Prot. nr. 0090692, 2014-2016

Point-Source Contributions to the Water Quality of an Urban Stream

NASA Astrophysics Data System (ADS)

Little, S. F. B.; Young, M.; Lowry, C.

2014-12-01

Scajaquada Creek, which runs through the heart of the city of Buffalo, is a prime example of the ways in which human intervention and local geomorphology can impact water quality and urban hydrology. Beginning in the 1920's, the Creek has been partially channelized and connected to Buffalo's combined sewer system (CSS). At Forest Lawn Cemetery, where this study takes place, Scajaquada Creek emerges from a 3.5-mile tunnel built to route stream flow under the city. Collocated with the tunnel outlet is a discharge point for Buffalo's CSS, combined sewer outlet (CSO) #53. It is at this point that runoff and sanitary sewage discharge regularly during rain events. Initially, this study endeavored to create a spatial and temporal picture for this portion of the Creek, monitoring such parameters as conductivity, dissolved oxygen, pH, temperature, and turbidity, in addition to measuring Escherichia coli (E. coli) concentrations. As expected, these factors responded directly to seasonality, local geomorphology, and distance from the point source (CSO #53), displaying a overall, linear response. However, the addition of nitrate and phosphate testing to the study revealed an entirely separate signal from that previously observed. Concentrations of these parameters did not respond to location in the same manner as E. coli. Instead of decreasing with distance from the CSO, a distinct periodicity was observed, correlating with a series of outflow pipes lining the stream banks. It is hypothesized that nitrate and phosphate occurring in this stretch of Scajaquada Creek originate not from the CSO, but from fertilizers used to maintain the lawns within the subwatershed. These results provide evidence of the complexity related to water quality issues in urban streams as a result of point- and nonpoint-source hydrologic inputs.

Watershed scale spatial variability in dissolved and total organic and inorganic carbon in contrasting UK catchments

NASA Astrophysics Data System (ADS)

Cumberland, S.; Baker, A.; Hudson, N. J.

2006-12-01

Approximately 800 organic and inorganic carbon analyses have been undertaken from watershed scale and regional scale spatial surveys in various British catchments. These include (1) a small (<100 sq-km) urban catchment (Ouseburn, N England); (2) a headwater, lowland agricultural catchment (River Tern, C England) (3) a large UK catchment (River Tyne, ~3000 sq-km) and (4) a spatial survey of ~300 analyses from rivers from SW England (~1700 sq-km). Results demonstrate that: (1) the majority of organic and inorganic carbon is in the dissolved (DOC and DIC) fractions; (2) that with the exception of peat rich headwaters, DIC concentration is always greater than DOC; (3) In the rural River Tern, riverine DOC and DIC are shown to follow a simple end- member mixing between DIC (DOC) rich (poor) ground waters and DOC (DIC) rich (poor) riparian wetlands for all sample sites. (4) In the urbanized Ouseburn catchment, although many sample sites also show this same mixing trend, some tributaries follow a pollutant trend of simultaneous increases in both DOC and DIC. The Ouseburn is part of the larger Tyne catchment: this larger catchment follows the simple groundwater DIC- soil water DOC end member mixing model, with the exception of the urban catchments which exhibit an elevated DIC compared to rural sites. (5) Urbanization is demonstrated to increase DIC compared to equivalent rural catchments; this DIC has potential sources including diffuse source inputs from the dissolution of concrete, point sources such as trade effluents and landfill leachates, and bedrock derived carbonates relocated to the soil dissolution zone by urban development. (6) DIC in rural SW England demonstrates that spatial variability in DIC can be attributed to variations in geology; but that DIC concentrations in the SW England rivers dataset are typically lower than the urbanized Tyne catchments despite the presence of carbonate bedrock in many of the sample catchments in the SW England dataset. (7) Recent investigations into carbon fluxes in British rivers have focused on long term increases in DOC in rural and predominantly upland catchments. Our results suggest that research is needed into understanding long term variations in inorganic carbon concentration, as well as total (organic and inorganic) carbon fluxes from British rivers, to obtain total carbon loads. In particular, we provide evidence that DIC concentrations may be greater in urbanized catchments compared to equivalent non-urban catchments, with the implication that increasing urbanization in the future will see increases in riverine DIC and a decrease in the strength of any DOC DIC anti correlation. Further studies of urban catchment DIC sources, within stream processing, long term trends, and potential ecological impacts, are required.

Assessment of ultrafine particles and noise measurements using fuzzy logic and data mining techniques.

PubMed

Fernández-Camacho, R; Brito Cabeza, I; Aroba, J; Gómez-Bravo, F; Rodríguez, S; de la Rosa, J

2015-04-15

This study focuses on correlations between total number concentrations, road traffic emissions and noise levels in an urban area in the southwest of Spain during the winter and summer of 2009. The high temporal correlation between sound pressure levels, traffic intensity, particle number concentrations related to traffic, black carbon and NOx concentrations suggests that noise is linked to traffic emissions as a main source of pollution in urban areas. First, the association of these different variables was studied using PreFuRGe, a computational tool based on data mining and fuzzy logic. The results showed a clear association between noise levels and road-traffic intensity for non-extremely high wind speed levels. This behaviour points, therefore, to vehicular emissions being the main source of urban noise. An analysis for estimating the total number concentration from noise levels is also proposed in the study. The high linearity observed between particle number concentrations linked to traffic and noise levels with road traffic intensity can be used to calculate traffic related particle number concentrations experimentally. At low wind speeds, there are increases in noise levels of 1 dB for every 100 vehicles in circulation. This is equivalent to 2000 cm(-3) per vehicle in winter and 500 cm(-3) in summer. At high wind speeds, wind speed could be taken into account. This methodology allows low cost sensors to be used as a proxy for total number concentration monitoring in urban air quality networks. Copyright © 2015 Elsevier B.V. All rights reserved.

Reconnaissance of water-quality characteristics of streams in the City of Charlotte and Mecklenburg County, North Carolina

USGS Publications Warehouse

Eddins, W.H.; Crawford, J.K.

1984-01-01

In 1979-81, water samples were collected from 119 sites on streams throughout the City of Charlotte and Mecklenburg County, North Carolina, and were analyzed for specific conductance, dissolved chloride, hardness, pH, total alkalinity, total phosphorus, trace elements, arsenic, cadmium, chromium, copper, iron, lead, manganese, mercury, silver, and zinc and biological measures including dissolved oxygen, biochemical oxygen demand, fecal coliform bacteria, and fecal streptococcus bacteria. Sampling was conducted during both low flow (base flow) and high flow. Several water-quality measures including pH, total arsenic, total cadmium, total chromium, total copper, total iron, total lead, total manganese, total mercury, total silver, total zinc, dissolved oxygen, and fecal coliform bacteria at times exceeded North Carolina water-quality standards in various streams. Runoff from non-point sources appears to contribute more to the deterioration of streams in Charlotte and Mecklenburg County than point-source effluents. Urban and industrial areas contribute various trace elements. Residential and rural areas and municipal waste-water treatment plants contribute high amounts of phosphorus.

Urban groundwater quality in sub-Saharan Africa: current status and implications for water security and public health

NASA Astrophysics Data System (ADS)

Lapworth, D. J.; Nkhuwa, D. C. W.; Okotto-Okotto, J.; Pedley, S.; Stuart, M. E.; Tijani, M. N.; Wright, J.

2017-06-01

Groundwater resources are important sources of drinking water in Africa, and they are hugely important in sustaining urban livelihoods and supporting a diverse range of commercial and agricultural activities. Groundwater has an important role in improving health in sub-Saharan Africa (SSA). An estimated 250 million people (40% of the total) live in urban centres across SSA. SSA has experienced a rapid expansion in urban populations since the 1950s, with increased population densities as well as expanding geographical coverage. Estimates suggest that the urban population in SSA will double between 2000 and 2030. The quality status of shallow urban groundwater resources is often very poor due to inadequate waste management and source protection, and poses a significant health risk to users, while deeper borehole sources often provide an important source of good quality drinking water. Given the growth in future demand from this finite resource, as well as potential changes in future climate in this region, a detailed understanding of both water quantity and quality is required to use this resource sustainably. This paper provides a comprehensive assessment of the water quality status, both microbial and chemical, of urban groundwater in SSA across a range of hydrogeological terrains and different groundwater point types. Lower storage basement terrains, which underlie a significant proportion of urban centres in SSA, are particularly vulnerable to contamination. The relationship between mean nitrate concentration and intrinsic aquifer pollution risk is assessed for urban centres across SSA. Current knowledge gaps are identified and future research needs highlighted.

Shallow ground-water quality beneath a major urban center: Denver, Colorado, USA

USGS Publications Warehouse

Bruce, B.W.; McMahon, P.B.

1996-01-01

A survey of the chemical quality of ground water in the unconsolidated alluvial aquifer beneath a major urban center (Denver, Colorado, USA) was performed in 1993 with the objective of characterizing the quality of shallow ground-water in the urban area and relating water quality to land use. Thirty randomly selected alluvial wells were each sampled once for a broad range of dissolved constituents. The urban land use at each well site was sub- classified into one of three land-use settings: residential, commercial, and industrial. Shallow ground-water quality was highly variable in the urban area and the variability could be related to these land-use setting classifications. Sulfate (SO4) was the predominant anion in most samples from the residential and commercial land-use settings, whereas bicarbonate (HCO3) was the predominant anion in samples from the industrial land-use setting, indicating a possible shift in redox conditions associated with land use. Only three of 30 samples had nitrate concentrations that exceeded the US national drinking-water standard of 10 mg l-1 as nitrogen, indicating that nitrate contamination of shallow ground water may not be a serious problem in this urban area. However, the highest median nitrate concentration (4.2 mg l-1) was in samples from the residential setting, where fertilizer application is assumed to be most intense. Twenty-seven of 30 samples had detectable pesticides and nine of 82 analyzed pesticide compounds were detected at low concentrations, indicating that pesticides are widely distributed in shallow ground water in this urban area. Although the highest median total pesticide concentration (0.17 ??g l-1) was in the commercial setting, the herbicides prometon and atrazine were found in each land-use setting. Similarly, 25 of 29 samples analyzed had detectable volatile organic compounds (VOCs) indicating these compounds are also widely distributed in this urban area. The total VOC concentrations in sampled wells ranged from nondetectable to 23 442 ??g l-1. Widespread detections and occasionally high concentrations point to VOCs as the major anthropogenic ground-water impact in this urban environment. Generally, the highest VOC concentrations occurred in samples from the industrial setting. The most frequently detected VOC was the gasoline additive methyl tertbutyl ether (MTBE, in 23 of 29 wells). Results from this study indicate that the quality of shallow ground water in major urban areas can be related to land-use settings. Moreover, some VOCs and pesticides may be widely distributed at low concentrations in shallow ground water throughout major urban areas. As a result, the differentiation between point and non-point sources for these compounds in urban areas may be difficult.

Suburban Soils: Are they the answer in determining factors controlling non-point-source DOC and DON in urban surface waters?

NASA Astrophysics Data System (ADS)

Aitkenhead-Peterson, J. A.

2016-12-01

Generally the quality of urban streams has been attributed to storm water runoff and sewage effluent discharge. Recent work in the upper Trinity Basin downstream from the Dallas/Fort Worth metropolis, TX concluded that sewage effluent only contributed between 1 and 35% of DOC dependent upon the population of the watershed. Change from native to urban land use increased DOC exports to between 938 - 1840 kg km-2 yr-1relative to the 517 kg km-2 yr-1 expected from native land use. Where this excess DOC might come from in an urban ecosystem was addressed in a separate study examining water extractable DOC (WEDOC) and DON (WEDON) in soils of single-family home lawns in Chicago, IL, Frederick, MD, Bryan/College Station, TX and Galveston, TX. These cities were exposed to different sources of sodium. Time of exposure to sodium was considered on the assumption that as new sub-divisions are built, new soil or turfgrass sod is introduced to the site. Exposure times were 0-5, 6-10, 11-20, 21-30 and > 30 yr. Length of exposure time of the soil to the urban environment was significant among the four cities examined for DOC (p < 0.001), DON (p < 0.001), sodium adsorption ratio (p < 0.006) but not for sodium (p = 0.08) or exchangeable sodium percent (ESP) (p = 0.09). In all cities WEDON increased with urban exposure time and in all cities except Galveston WEDOC increased with urban exposure time. Sodium, regardless of its source, explained 60% of the variance in WEDOC and 54% of the variance in WEDON across all cities (n = 136). To determine what other factors might be involved in increasing WEDOC and WEDON losses from suburban soils, backward stepwise regression models were used. Across the four cities, time of urban exposure, soil saturated hydraulic conductivity (Ksat), NO3-N, NH4-N, S, PO4-P, Na, Cu, Ca, Fe and Zn produced a significant model for WEDOC (Adjusted r2 = 0.85; p < 0.001) and Ksat, pH, NH4-N, PO4-P, S, Alkalinity and Cu produced a significant model for WEDON (adjusted r2 = 0.81; p < 0.0001). Models for estimating WEDOC and WEDON were also produced for the individual cities. While sodium may be a player in the increasing DOC and DON observed in urban surface waters, more research is needed to determine the mechanisms of WEDOC and WEDON release from urban soils.

A method to analyze "source-sink" structure of non-point source pollution based on remote sensing technology.

PubMed

Jiang, Mengzhen; Chen, Haiying; Chen, Qinghui

2013-11-01

With the purpose of providing scientific basis for environmental planning about non-point source pollution prevention and control, and improving the pollution regulating efficiency, this paper established the Grid Landscape Contrast Index based on Location-weighted Landscape Contrast Index according to the "source-sink" theory. The spatial distribution of non-point source pollution caused by Jiulongjiang Estuary could be worked out by utilizing high resolution remote sensing images. The results showed that, the area of "source" of nitrogen and phosphorus in Jiulongjiang Estuary was 534.42 km(2) in 2008, and the "sink" was 172.06 km(2). The "source" of non-point source pollution was distributed mainly over Xiamen island, most of Haicang, east of Jiaomei and river bank of Gangwei and Shima; and the "sink" was distributed over southwest of Xiamen island and west of Shima. Generally speaking, the intensity of "source" gets weaker along with the distance from the seas boundary increase, while "sink" gets stronger. Copyright © 2013 Elsevier Ltd. All rights reserved.

Effects of urbanization on the geomorphology, habitat, hydrology, and fish index of biotic integrity of streams in the Chicago area, Illinois and Wisconsin

USGS Publications Warehouse

Fitzpatrick, F.A.; Diebel, M.W.; Harris, M.A.; Arnold, T.L.; Lutz, M.A.; Richards, K.D.

2005-01-01

Effects of urbanization on geomorphic, habitat, and hydrologic characteristics and fish biotic integrity of 45 streams in the Chicago area were examined by the U.S. Geological Survey from 2000 to 2001. An agricultural to urban land-cover gradient approach was used. Landscape characteristics such as texture of surficial deposits, slope, riparian land cover, and stream network position also were examined to determine if these factors influenced the effects of urbanization. Among geomorphic characteristics, channel enlargement occurred in urban streams with a high percent of watershed clayey surficial deposits. Other geomorphic and habitat characteristics such as stream power, fine substrate, and amount of riffles did not correlate with percent watershed urban land but instead correlated with reach slope. Bank erosion, habitat variability, and two habitat indexes did not correlate with watershed urban land. Below 30% watershed urban land, the unit area discharge for a 2-year flood increased with increasing urban land; however, above 30% urban land, unit area discharges for a 2-year flood were variable, most likely due to variations in stormwater management practices, point-source contributions, and the transport index. Streams with greater than 33% watershed urban land had low base flow, but the effects of urbanization on base flow were offset by point-source contributions. Fish index of biotic integrity (IBI) scores were low in streams with greater than 25% watershed urban land. Fish IBI scores also were low in streams with high percentages of watershed clayey surficial deposits and enlarged channels. The amount of riparian forest/wetland buffer had no moderating effect on geomorphic/habitat/hydrologic characteristics and fish IBI scores. Variations in the texture and topography of glacial landforms affected reach slope and some habitat characteristics. Longitudinal profiles were useful for distinguishing differences in local geologic settings among sampled sites.

Occurrence of organic wastewater-indicator compounds in urban streams of the Atlanta area, Georgia, 2003-2006

USGS Publications Warehouse

Lawrence, Stephen J.; LaFontaine, Jacob H.

2010-01-01

The similarity in the pattern and distribution of OWICs in samples at sites upstream and downstream from known CSO outfalls indicates that CSOs were not the dominant source of OWICs during the study period. Other sources may include non-sewage discharges-both permitted, permitted but out of compliance, and non-permitted, contaminated groundwater from leaking sewer lines or septic systems, sanitary-sewer overflows, or dry-weather runoff from outdoor water use. These OWICs may be better suited for identifying sewage-contaminated groundwater than sewage-contaminated surface water because groundwater is not typically affected by the OWICs that are more common in urban runoff.

Landscape Ecotoxicology of Coho Salmon Spawner Mortality in Urban Streams

PubMed Central

Feist, Blake E.; Buhle, Eric R.; Arnold, Paul; Davis, Jay W.; Scholz, Nathaniel L.

2011-01-01

In the Pacific Northwest of the United States, adult coho salmon (Oncorhynchus kisutch) returning from the ocean to spawn in urban basins of the Puget Sound region have been prematurely dying at high rates (up to 90% of the total runs) for more than a decade. The current weight of evidence indicates that coho deaths are caused by toxic chemical contaminants in land-based runoff to urban streams during the fall spawning season. Non-point source pollution in urban landscapes typically originates from discrete urban and residential land use activities. In the present study we conducted a series of spatial analyses to identify correlations between land use and land cover (roadways, impervious surfaces, forests, etc.) and the magnitude of coho mortality in six streams with different drainage basin characteristics. We found that spawner mortality was most closely and positively correlated with the relative proportion of local roads, impervious surfaces, and commercial property within a basin. These and other correlated variables were used to identify unmonitored basins in the greater Seattle metropolitan area where recurrent coho spawner die-offs may be likely. This predictive map indicates a substantial geographic area of vulnerability for the Puget Sound coho population segment, a species of concern under the U.S. Endangered Species Act. Our spatial risk representation has numerous applications for urban growth management, coho conservation, and basin restoration (e.g., avoiding the unintentional creation of ecological traps). Moreover, the approach and tools are transferable to areas supporting coho throughout western North America. PMID:21858112

Fluxes of Greenhouse Gases from the Baltimore-Washington Area: Results from WINTER 2015 Aircraft Observations

NASA Astrophysics Data System (ADS)

Dickerson, R. R.; Ren, X.; Shepson, P. B.; Salmon, O. E.; Brown, S. S.; Thornton, J. A.; Whetstone, J. R.; Salawitch, R. J.; Sahu, S.; Hall, D.; Grimes, C.; Wong, T. M.

2015-12-01

Urban areas are responsible for a major component of the anthropogenic greenhouse gas (GHG) emissions. Quantification of urban GHG fluxes is important for establishing scientifically sound and cost-effective policies for mitigating GHGs. Discrepancies between observations and model simulations of GHGs suggest uncharacterized sources in urban environments. In this work, we analyze and quantify fluxes of CO2, CH4, CO (and other trace species) from the Baltimore-Washington area based on the mass balance approach using the two-aircraft observations conducted in February-March 2015. Estimated fluxes from this area were 110,000±20,000 moles s-1 for CO2, 700±330 moles s-1 for CH4, and 535±188 moles s-1 for CO. This implies that methane is responsible for ~20% of the climate forcing from these cities. Point sources of CO2 from four regional power plants and one point source of CH4 from a landfill were identified and the emissions from these point sources were quantified based on the aircraft observation and compared to the emission inventory data. Methane fluxes from the Washington area were larger than from the Baltimore area, indicating a larger leakage rate in the Washington area. The ethane-to-methane ratios, with a mean of 3.3%, in the limited canister samples collected during the flights indicate that natural gas leaks and the upwind oil and natural gas operations are responsible for a substantial fraction of the CH4 flux. These observations will be compared to models using Ensemble Kalman Filter Assimilation techniques.

Woody invasions of urban trails and the changing face of urban forests in the great plains, USA

USGS Publications Warehouse

Nemec, K.T.; Allen, Craig R.; Alai, A.; Clements, G.; Kessler, A.C.; Kinsell, T.; Major, A.; Stephen, B.J.

2011-01-01

Corridors such as roads and trails can facilitate invasions by non-native plant species. The open, disturbed habitat associated with corridors provides favorable growing conditions for many non-native plant species. Bike trails are a corridor system common to many urban areas that have not been studied for their potential role in plant invasions. We sampled five linear segments of urban forest along bike trails in Lincoln, Nebraska to assess the invasion of woody non-native species relative to corridors and to assess the composition of these urban forests. The most abundant plant species were generally native species, but five non-native species were also present: white mulberry (Morus alba), common buckthorn (Rhamnus cathartica), tree-of-heaven (Ailanthus altissima), honeysuckle (Lonicera spp.) and elm (Ulmus spp.). The distribution of two of the woody species sampled, common buckthorn and honeysuckle, significantly decreased with increasing distance from a source patch of vegetation (P = 0.031 and 0.030). These linear habitats are being invaded by non-native tree and shrub species, which may change the structure of these urban forest corridors. If non-native woody plant species become abundant in the future, they may homogenize the plant community and reduce native biodiversity in these areas. ?? 2011 American Midland Naturalist.

Detecting small scale CO2 emission structures using OCO-2

NASA Astrophysics Data System (ADS)

Schwandner, Florian M.; Eldering, Annmarie; Verhulst, Kristal R.; Miller, Charles E.; Nguyen, Hai M.; Oda, Tomohiro; O'Dell, Christopher; Rao, Preeti; Kahn, Brian; Crisp, David; Gunson, Michael R.; Sanchez, Robert M.; Ashok, Manasa; Pieri, David; Linick, Justin P.; Yuen, Karen

2016-04-01

Localized carbon dioxide (CO2) emission structures cover spatial domains of less than 50 km diameter and include cities and transportation networks, as well as fossil fuel production, upgrading and distribution infra-structure. Anthropogenic sources increasingly upset the natural balance between natural carbon sources and sinks. Mitigation of resulting climate change impacts requires management of emissions, and emissions management requires monitoring, reporting and verification. Space-borne measurements provide a unique opportunity to detect, quantify, and analyze small scale and point source emissions on a global scale. NASA's first satellite dedicated to atmospheric CO2 observation, the July 2014 launched Orbiting Carbon Observatory (OCO-2), now leads the afternoon constellation of satellites (A-Train). Its continuous swath of 2 to 10 km in width and eight footprints across can slice through coincident emission plumes and may provide momentary cross sections. First OCO-2 results demonstrate that we can detect localized source signals in the form of urban total column averaged CO2 enhancements of ~2 ppm against suburban and rural backgrounds. OCO-2's multi-sounding swath observing geometry reveals intra-urban spatial structures reflected in XCO2 data, previously unobserved from space. The transition from single-shot GOSAT soundings detecting urban/rural differences (Kort et al., 2012) to hundreds of soundings per OCO-2 swath opens up the path to future capabilities enabling urban tomography of greenhouse gases. For singular point sources like coal fired power plants, we have developed proxy detections of plumes using bands of imaging spectrometers with sensitivity to SO2 in the thermal infrared (ASTER). This approach provides a means to automate plume detection with subsequent matching and mining of OCO-2 data for enhanced detection efficiency and validation. © California Institute of Technology

Area Source Emission Measurements Using EPA OTM 10

EPA Science Inventory

Measurement of air pollutant emissions from area and non-point sources is an emerging environmental concern. Due to the spatial extent and non-homogenous nature of these sources, assessment of fugitive emissions using point sampling techniques can be difficult. To help address th...

Urban air quality in a mid-size city - PM2.5 composition, sources and identification of impact areas: From local to long range contributions

NASA Astrophysics Data System (ADS)

Squizzato, Stefania; Cazzaro, Marta; Innocente, Elena; Visin, Flavia; Hopke, Philip K.; Rampazzo, Giancarlo

2017-04-01

Urban air quality represents a major public health burden and is a long-standing concern to European citizens. Combustion processes and traffic-related emissions represent the main primary particulate matter (PM) sources in urban areas. Other sources can also affect air quality (e.g., secondary aerosol, industrial) depending on the characteristics of the study area. Thus, the identification and the apportionment of all sources is of crucial importance to make effective corrective decisions within environmental policies. The aim of this study is to evaluate the impacts of different emissions sources on PM2.5 concentrations and compositions in a mid-size city in the Po Valley (Treviso, Italy). Data have been analyzed to highlight compositional differences (elements and major inorganic ions), to determine PM2.5 sources and their contributions, and to evaluate the influence of air mass movements. Non-parametric tests, positive matrix factorization (PMF), conditional bivariate probability function (CBPF), and concentration weighted trajectory (CWT) have been used in a multi-chemometrics approach to understand the areal-scale (proximate, local, long-range) where different sources act on PM2.5 levels and composition. Results identified three levels of scale from which the pollution arose: (i) a proximate local scale (close to the sampling site) for traffic non-exhaust and resuspended dust sources; (ii) a local urban scale (including both sampling site and areas close to them) for combustion and industrial; and (iii) a regional scale characterized by ammonium nitrate and ammonium sulfate. This approach and results can help to develop and adopt better air quality policy action.

A candidate framework for PM2.5 source identification in highly industrialized urban-coastal areas

NASA Astrophysics Data System (ADS)

Mateus, Vinícius Lionel; Gioda, Adriana

2017-09-01

The variability of PM sources and composition impose tremendous challenges for police makers in order to establish guidelines. In urban PM, sources associated with industrial processes are among the most important ones. In this study, a 5-year monitoring of PM2.5 samples was carried out in an industrial district. Their chemical composition was strategically determined in two campaigns in order to check the effectiveness of mitigation policies. Gaseous pollutants (NO2, SO2, and O3) were also monitored along with meteorological variables. The new method called Conditional Bivariate Probability Function (CBPF) was successfully applied to allocate the observed concentration of criteria pollutants (gaseous pollutants and PM2.5) in cells defined by wind direction-speed which provided insights about ground-level and elevated pollution plumes. CBPF findings were confirmed by the Theil-Sen long trend estimations for criteria pollutants. By means of CBPF, elevated pollution plumes were detected in the range of 0.54-5.8 μg m-3 coming from a direction associated to stacks. With high interpretability, the use of Conditional Inference Trees (CIT) provided both classification and regression of the speciated PM2.5 in the two campaigns. The combination of CIT and Random Forests (RF) point out NO3- and Ca+2 as important predictors for PM2.5. The latter predictor mostly associated to non-sea-salt sources, given a nss-Ca2+ contribution equal to 96%.

Urban sound energy reduction by means of sound barriers

NASA Astrophysics Data System (ADS)

Iordache, Vlad; Ionita, Mihai Vlad

2018-02-01

In urban environment, various heating ventilation and air conditioning appliances designed to maintain indoor comfort become urban acoustic pollution vectors due to the sound energy produced by these equipment. The acoustic barriers are the recommended method for the sound energy reduction in urban environment. The current sizing method of these acoustic barriers is too difficult and it is not practical for any 3D location of the noisy equipment and reception point. In this study we will develop based on the same method a new simplified tool for acoustic barriers sizing, maintaining the same precision characteristic to the classical method. Abacuses for acoustic barriers sizing are built that can be used for different 3D locations of the source and the reception points, for several frequencies and several acoustic barrier heights. The study case presented in the article represents a confirmation for the rapidity and ease of use of these abacuses in the design of the acoustic barriers.

32 CFR 806.20 - Records of non-U.S. government source.

Code of Federal Regulations, 2010 CFR

2010-07-01

... ADMINISTRATION AIR FORCE FREEDOM OF INFORMATION ACT PROGRAM § 806.20 Records of non-U.S. government source. (a...-mail address of: their own FOIA office point of contact; the Air Force record OPR point of contact, the... 32 National Defense 6 2010-07-01 2010-07-01 false Records of non-U.S. government source. 806.20...

32 CFR 806.20 - Records of non-U.S. government source.

Code of Federal Regulations, 2011 CFR

2011-07-01

... ADMINISTRATION AIR FORCE FREEDOM OF INFORMATION ACT PROGRAM § 806.20 Records of non-U.S. government source. (a...-mail address of: their own FOIA office point of contact; the Air Force record OPR point of contact, the... 32 National Defense 6 2011-07-01 2011-07-01 false Records of non-U.S. government source. 806.20...

32 CFR 806.20 - Records of non-U.S. government source.

Code of Federal Regulations, 2013 CFR

2013-07-01

... ADMINISTRATION AIR FORCE FREEDOM OF INFORMATION ACT PROGRAM § 806.20 Records of non-U.S. government source. (a...-mail address of: their own FOIA office point of contact; the Air Force record OPR point of contact, the... 32 National Defense 6 2013-07-01 2013-07-01 false Records of non-U.S. government source. 806.20...

Monitoring trace gases in downtown Toronto using open-path Fourier transform infrared spectroscopy

NASA Astrophysics Data System (ADS)

Byrne, B.; Strong, K.; Colebatch, O.; Fogal, P.; Mittermeier, R. L.; Wunch, D.; Jones, D. B. A.

2017-12-01

Emissions of greenhouse gases (GHGs) in urban environments can be highly heterogeneous. For example, vehicles produce point source emissions which can result in heterogeneous GHG concentrations on scales <10 m. The highly localized scale of these emissions can make it difficult to measure mean GHG concentrations on scales of 100-1000 m. Open-Path Fourier Transform Infrared Spectroscopy (OP-FTIR) measurements offer spatial averaging and continuous measurements of several trace gases simultaneously in the same airmass. We have set up an open-path system in downtown Toronto to monitor trace gases in the urban boundary layer. Concentrations of CO2, CO, CH4, and N2O are derived from atmospheric absorption spectra recorded over a two-way atmospheric open path of 320 m using non-linear least squares fitting. Using a simple box model and co-located boundary layer height measurements, we estimate surface fluxes of these gases in downtown Toronto from our OP-FTIR observations.

Hourly elemental concentrations in PM2.5 aerosols sampled simultaneously at urban background and road site during SAPUSS - diurnal variations and PMF receptor modelling

NASA Astrophysics Data System (ADS)

Dall'Osto, M.; Querol, X.; Amato, F.; Karanasiou, A.; Lucarelli, F.; Nava, S.; Calzolai, G.; Chiari, M.

2013-04-01

Hourly-resolved aerosol chemical speciation data can be a highly powerful tool to determine the source origin of atmospheric pollutants in urban environments. Aerosol mass concentrations of seventeen elements (Na, Mg, Al, S, Cl, K, Ca, Ti, V, Cr, Mn, Fe, Ni, Cu, Zn, Sr and Pb) were obtained by time (1 h) and size (PM2.5 particulate matter < 2.5 μm) resolved aerosol samples analysed by Particle Induced X-ray Emission (PIXE) measurements. In the Marie Curie European Union framework of SAPUSS (Solving Aerosol Problems by Using Synergistic Strategies), the approach used is the simultaneous sampling at two monitoring sites in Barcelona (Spain) during September-October 2010: an urban background site (UB) and a street canyon traffic road site (RS). Elements related to primary non-exhaust traffic emission (Fe, Cu), dust resuspension (Ca) and anthropogenic Cl were found enhanced at the RS, whereas industrial related trace metals (Zn, Pb, Mn) were found at higher concentrations at the more ventilated UB site. When receptor modelling was performed with positive matrix factorization (PMF), nine different aerosol sources were identified at both sites: three types of regional aerosols (regional sulphate (S) - 27%, biomass burning (K) - 5%, sea salt (Na-Mg) - 17%), three types of dust aerosols (soil dust (Al-Ti) - 17%, urban crustal dust (Ca) - 6%, and primary traffic non-exhaust brake dust (Fe-Cu) - 7%), and three types of industrial aerosol plumes-like events (shipping oil combustion (V-Ni) - 17%, industrial smelters (Zn-Mn) - 3%, and industrial combustion (Pb-Cl) - 5%, percentages presented are average source contributions to the total elemental mass measured). The validity of the PMF solution of the PIXE data is supported by very good correlations with external single particle mass spectrometry measurements. Some important conclusions can be drawn about the PM2.5 mass fraction simultaneously measured at the UB and RS sites: (1) the regional aerosol sources impact both monitoring sites at similar concentrations regardless their different ventilation conditions; (2) by contrast, local industrial aerosol plumes associated with shipping oil combustion and smelters activities have a higher impact on the more ventilated UB site; (3) a unique source of Pb-Cl (associated with combustion emissions) is found to be the major (82%) source of fine Cl in the urban agglomerate; (4) the mean diurnal variation of PM2.5 primary traffic non-exhaust brake dust (Fe-Cu) suggests that this source is mainly emitted and not resuspended, whereas PM2.5 urban dust (Ca) is found mainly resuspended by both traffic vortex and sea breeze; (5) urban dust (Ca) is found the aerosol source most affected by land wetness, reduced by a factor of eight during rainy days and suggesting that wet roads may be a solution for reducing urban dust concentrations.

Oxidative potential and inflammatory impacts of source apportioned ambient air pollution in Beijing.

PubMed

Liu, Qingyang; Baumgartner, Jill; Zhang, Yuanxun; Liu, Yanju; Sun, Yongjun; Zhang, Meigen

2014-11-04

Air pollution exposure is associated with a range of adverse health impacts. Knowledge of the chemical components and sources of air pollution most responsible for these health effects could lead to an improved understanding of the mechanisms of such effects and more targeted risk reduction strategies. We measured daily ambient fine particulate matter (<2.5 μm in aerodynamic diameter; PM2.5) for 2 months in peri-urban and central Beijing, and assessed the contribution of its chemical components to the oxidative potential of ambient air pollution using the dithiothreitol (DTT) assay. The composition data were applied to a multivariate source apportionment model to determine the PM contributions of six sources or factors: a zinc factor, an aluminum factor, a lead point factor, a secondary source (e.g., SO4(2-), NO3(2-)), an iron source, and a soil dust source. Finally, we assessed the relationship between reactive oxygen species (ROS) activity-related PM sources and inflammatory responses in human bronchial epithelial cells. In peri-urban Beijing, the soil dust source accounted for the largest fraction (47%) of measured ROS variability. In central Beijing, a secondary source explained the greatest fraction (29%) of measured ROS variability. The ROS activities of PM collected in central Beijing were exponentially associated with in vivo inflammatory responses in epithelial cells (R2=0.65-0.89). We also observed a high correlation between three ROS-related PM sources (a lead point factor, a zinc factor, and a secondary source) and expression of an inflammatory marker (r=0.45-0.80). Our results suggest large differences in the contribution of different PM sources to ROS variability at the central versus peri-urban study sites in Beijing and that secondary sources may play an important role in PM2.5-related oxidative potential and inflammatory health impacts.

Creating Change in the Large Urban Public Schools of the United States

ERIC Educational Resources Information Center

Heyman, Ernest L.; Vigil, Peter

2008-01-01

Minority groups make up a large share of the working and the non-working poor. Moreover, throughout the last several decades, many minority students in the large urban schools, particularly Hispanic, Native and African-American, have had a difficult time taking advantage of a public education. The major tension points and associated problems…

Non-Intellective Factors in the Prediction of Academic Success of Urban College Freshmen.

ERIC Educational Resources Information Center

Fox, James Arthur

The purpose of this study was to determine which personality traits as measured by the California Psychological Inventory (CPI) are predictive of academic achievement in urban college freshmen of the Federal City College. The measures of achievement were grade point average (GPA) and the Comparative Guidance and Placement Program (CGPP) test…

Landscaping practices, land use patterns and stormwater quantity and quality in urban watersheds

NASA Astrophysics Data System (ADS)

Miles, B.; Band, L. E.

2011-12-01

Increasing quantity and decreasing quality of urban stormwater threatens biodiversity in local streams and reservoirs, jeopardizes water supplies, and ultimately contributes to estuarine eutrophication. To estimate the effects that present and alternative landscaping practices and land use patterns may have on urban stormwater quantity and quality, simulations of existing land use/land cover using the Regional Hydro-Ecologic Simulation System (RHESSys), a process-based surface hydrology and biogeochemistry model, were developed for watersheds in Baltimore, MD (as part of the Baltimore Ecosystem Study (BES) NSF Long-Term Ecological Research (LTER) site) and Durham, NC (as part of the NSF Urban Long-Term Research Area (ULTRA) program). The influence of land use patterns and landscaping practices on nutrient export in urban watersheds has been explored as part of the BES; this work has focused on improving our understanding of how residential landscaping practices (i.e. lawn fertilization rates) vary across land use and socioeconomic gradients. Elsewhere, others have explored the political ecology of residential landscaping practices - seeking to understand the economic, political, and cultural influences on the practice of high-input residential turf-grass management. Going forward, my research will synthesize and extend this prior work. Rather than pre-supposing predominant residential land use patterns and landscaping practices (i.e. lower-density periphery development incorporating high-input turf landscapes) alternate land use and landscaping scenarios (e.g. higher-density/transit-oriented development, rain gardens, vegetable gardens, native plant/xeriscaping) will be developed through interviews/focus groups with stakeholders (citizens, public officials, developers, non-profits). These scenarios will then be applied to the RHESSys models already developed for catchments in Baltimore and Durham. The modeled scenario results will be used to identify alternate land use patterns and landscaping practices that would: (1) help to reduce non-point sources of nutrient pollution in urban watersheds; and (2) be likely to gain public support. This research will inform sustainable development policy while furthering interdisciplinary research in the fields of planning and water resource management.

Analysis of the effect of evergreen and deciduous trees on urban nitrogen dioxide levels in the U.S. using land-use regression

NASA Astrophysics Data System (ADS)

Rao, M.; George, L. A.

2012-12-01

Nitrogen dioxide (NO2), an atmospheric pollutant generated primarily by anthropogenic combustion processes, is typically found at higher concentrations in urban areas compared to non-urbanized environments. Elevated NO2 levels have multiple ecosystem effects at different spatial scales. At the local scale, elevated levels affect human health directly and through the formation of secondary pollutants such as ozone and aerosols; at the regional scale secondary pollutants such as nitric acid and organic nitrates have deleterious effects on non-urbanized areas; and, at the global scale, nitrogen oxide emissions significantly alter the natural biogeochemical nitrogen cycle. As cities globally become larger and larger sources of nitrogen oxide emissions, it is important to assess possible mitigation strategies to reduce the impact of emissions locally, regionally and globally. In this study, we build a national land-use regression (LUR) model to compare the impacts of deciduous and evergreen trees on urban NO2 levels in the United States. We use the EPA monitoring network values of NO2 levels for 2006, the 2006 NLCD tree canopy data for deciduous and evergreen canopies, and the US Census Bureau's TIGER shapefiles for roads, railroads, impervious area & population density as proxies for NO2 sources on-road traffic, railroad traffic, off-road and area sources respectively. Our preliminary LUR model corroborates previous LUR studies showing that the presence of trees is associated with reduced urban NO2 levels. Additionally, our model indicates that deciduous and evergreen trees reduce NO2 to different extents, and that the amount of NO2 reduced varies seasonally. The model indicates that every square kilometer of deciduous canopy within a 2km buffer is associated with a reduction in ambient NO2 levels of 0.64 ppb in summer and 0.46ppb in winter. Similarly, every square kilometer of evergreen tree canopy within a 2 km buffer is associated with a reduction in ambient NO2 by 0.53 ppb in summer and 0.84 ppb in winter. Thus, the model indicates that deciduous trees are associated with a 30% smaller reduction in NO2 in winter as compared to summer, while evergreens are associated with a 60% increase in the reduction of NO2 in winter, for every square kilometer of deciduous or evergreen canopy within a 2 km buffer. Leaf- and local canopy-level studies have shown that trees are a sink for urban NO2 through deposition as well as stomatal and cuticular uptake. The winter time versus summer time effects suggest that leaf-level deposition may not be the only uptake mechanism and points to the need for a more holistic analysis of tree and canopy-level deposition for urban air pollution models. Since deposition velocities for NO2 vary by tree species, the reduction may also vary by species. These findings have implications for designing cities to reduce the impact of air pollution.

Semi-Automated Approach for Mapping Urban Trees from Integrated Aerial LiDAR Point Cloud and Digital Imagery Datasets

NASA Astrophysics Data System (ADS)

Dogon-Yaro, M. A.; Kumar, P.; Rahman, A. Abdul; Buyuksalih, G.

2016-09-01

Mapping of trees plays an important role in modern urban spatial data management, as many benefits and applications inherit from this detailed up-to-date data sources. Timely and accurate acquisition of information on the condition of urban trees serves as a tool for decision makers to better appreciate urban ecosystems and their numerous values which are critical to building up strategies for sustainable development. The conventional techniques used for extracting trees include ground surveying and interpretation of the aerial photography. However, these techniques are associated with some constraints, such as labour intensive field work and a lot of financial requirement which can be overcome by means of integrated LiDAR and digital image datasets. Compared to predominant studies on trees extraction mainly in purely forested areas, this study concentrates on urban areas, which have a high structural complexity with a multitude of different objects. This paper presented a workflow about semi-automated approach for extracting urban trees from integrated processing of airborne based LiDAR point cloud and multispectral digital image datasets over Istanbul city of Turkey. The paper reveals that the integrated datasets is a suitable technology and viable source of information for urban trees management. As a conclusion, therefore, the extracted information provides a snapshot about location, composition and extent of trees in the study area useful to city planners and other decision makers in order to understand how much canopy cover exists, identify new planting, removal, or reforestation opportunities and what locations have the greatest need or potential to maximize benefits of return on investment. It can also help track trends or changes to the urban trees over time and inform future management decisions.

Can the watershed non-point phosphorus pollution be interpreted by critical soil properties? A new insight of different soil P states.

PubMed

Lin, Chen; Ma, Ronghua; Xiong, Junfeng

2018-07-01

The physicochemical properties of surface soil play a key role in the fate of watershed non-point source pollution. Special emphasis is needed to identify soil properties that are sensitive to both particulate P (PP) pollution and dissolved P (DP) pollution, which is essential for watershed environmental management. The Chaohu Lake basin, a typical eutrophic lake in China, was selected as the study site. The spatial features of the Non-point Source (NPS) PP loads and DP loads were calculated simultaneously based on the integration of sediment delivery distributed model (SEDD) and pollution loads (PLOAD) model. Then several critical physicochemical soil properties, especially various soil P compositions, were innovatively introduced to determine the response of the critical soil properties to NPS P pollution. The findings can be summarized: i) the mean PP load value of the different sub-basins was 5.87 kg, and PP pollution is regarded to be the primary NPS P pollution state, while the DP loads increased rapidly under the rapid urbanization process. ii) iron-bound phosphorus (Fe-P) and aluminum-bound phosphorus (Al-P) are the main components of available P and showed the most sensitive responses to NPS PP pollution, and the correlation coefficients were approximately 0.9. Otherwise, the residual phosphorus (Res-P) was selected as a sensitive soil P state that was significantly negatively correlated with the DP loads. iii) The DP and PP concentrations were represented differently when they were correlated with various soil properties, and the clay proportion was strongly negatively related to the PP loads. Meanwhile, there is a non-linear relationship between the DP loads and the critical soil properties, such as Fe and Total Nitrogen (TN) concentrations. Specifically, a strong inhibitory effect of TN concentration on the DP load was apparent in the Nanfei river (NF) and Paihe (PH) river basins where the R 2 reached 0.67, which contrasts with the relatively poor relationship within the other five basins. In addition, the degree of correlation between the Fe and DP loads severely degraded in the basins that were mostly covered by construction land or those that underwent a rapid urbanization process. The findings indicate that land use/cover change (LUCC), especially the distribution of agricultural land and construction land, as well as the soil background information (TN, Fe and Soil organic matters, etc.) can be considered as factors that influence NPS P pollution. Copyright © 2018 Elsevier B.V. All rights reserved.

Pairing high-frequency data with a link-node model to manage dissolved oxygen impairment in a dredged estuary.

PubMed

Camarillo, Mary Kay; Weissmann, Gregory A; Gulati, Shelly; Herr, Joel; Sheeder, Scott; Stringfellow, William T

2016-08-01

High-frequency data and a link-node model were used to investigate the relative importance of mass loads of oxygen-demanding substances and channel geometry on recurrent low dissolved oxygen (DO) in the San Joaquin River Estuary in California. The model was calibrated using 6 years of data. The calibrated model was then used to determine the significance of the following factors on low DO: excavation of the river to allow navigation of large vessels, non-point source pollution from the agricultural watershed, effluent from a wastewater treatment plant, and non-point source pollution from an urban area. An alternative metric for low DO, excess net oxygen demand (ENOD), was applied to better characterize DO impairment. Model results indicate that the dredged ship channel had the most significant effect on DO (62 % fewer predicted hourly DO violations), followed by mass load inputs from the watershed (52 % fewer predicted hourly DO violations). Model results suggest that elimination of any one factor will not completely resolve DO impairment and that continued use of supplemental aeration is warranted. Calculation of ENOD proved more informative than the sole use of DO. Application of the simple model allowed for interpretation of the extensive data collected. The current monitoring program could be enhanced by additional monitoring stations that would provide better volumetric estimates of low DO.

The Onset of a Novel Environmental Offset: A case study for diverse pollutant scheme in Australia.

NASA Astrophysics Data System (ADS)

Sengupta, A.; Arora, M.; Delbridge, N.; Pettigrove, V.; Feldman, D.

2014-12-01

Environmental offset schemes employ a crediting system to mitigate the impacts of pollutants. In this talk, we present a novel trade-off concept comparing diverse groups of pollutants: environmental flows, micropollutants (heavy metals, pesticides, estrogen compounds) and nutrients in a test watershed (Jacksons Creek), in the vicinity of Melbourne. A reservoir in the upper watershed, and a wastewater treatment plant (WTP) are the main sources of flow into Jacksons Creek. The current land use is a mix of agriculture, and rural, though rapid urbanization is anticipated with a 40% increase in the population by 2040. The creek is impacted by: 1) low flow, especially during dry periods (contribution from the reservoir drops dramatically), 2) nutrient enrichment (WTP and agricultural runoff), and 3) micropollutants-heavy metals (urban runoff), estrogenic compounds (WTP), and pesticides (agricultural runoff). In this offset framework, we evaluated current and future scenarios to identify the main stressor in Jacksons Creek. We collected monitoring data at 15 sites for separate 3 events. Then we developed a watershed model to assess sources of pollutant loads to the creek, using two different tools, Model for Urban Stormwater Improvement Conceptualisation (MUSIC) for the preliminary flow and water quality modeling, and eWater Source for integrated water resource management (IWRM), and a decision support system for stakeholders. Scenario analysis includes urbanization and population growth, and anticipated discharges from WTP and the reservoir. Measured nutrient concentrations were high for all sampling events. Micropollutants were detected at a concentration higher than the trigger value at several locations. Preliminary analysis shows that low flow is one of the major stressors in the creek causing elevated micropollutant and nutrient concentrations (non-point), and that discharge from the WTP is essential to maintain the minimum environmental flows, though nutrient enrichment downstream could occur. This study demonstrates an innovative case for evaluating net environmental benefits, and might hold important lessons for the design of offset schemes in comparable environments elsewhere.

Air quality modeling of selected aromatic and non-aromatic air toxics in the Houston urban and industrial airshed

NASA Astrophysics Data System (ADS)

Coarfa, Violeta Florentina

2007-12-01

Air toxics, also called hazardous air pollutants (HAPs), pose a serious threat to human health and the environment. Their study is important in the Houston area, where point sources, mostly located along the Ship Channel, mobile and area sources contribute to large emissions of such toxic pollutants. Previous studies carried out in this area found dangerous levels of different HAPs in the atmosphere. This thesis presents several studies that were performed for the aromatic and non-aromatic air toxics in the HGA. For these studies we developed several tools: (1) a refined chemical mechanism, which explicitly represents 18 aromatic air toxics that were lumped under two model species by the previous version, based on their reactivity with the hydroxyl radical; (2) an engineering version of an existing air toxics photochemical model that enables us to perform much faster long-term simulations compared to the original model, that leads to a 8--9 times improvement in the running time across different computing platforms; (3) a combined emission inventory based on the available emission databases. Using the developed tools, we quantified the mobile source impact on a few selected air toxics, and analyzed the temporal and spatial variation of selected aromatic and non-aromatic air toxics in a few regions within the Houston area; these regions were characterized by different emissions and environmental conditions.

Source apportionment of speciated PM2.5 and non-parametric regressions of PM2.5 and PM(coarse) mass concentrations from Denver and Greeley, Colorado, and construction and evaluation of dichotomous filter samplers

NASA Astrophysics Data System (ADS)

Piedrahita, Ricardo A.

The Denver Aerosol Sources and Health study (DASH) was a long-term study of the relationship between the variability in fine particulate mass and chemical constituents (PM2.5, particulate matter less than 2.5mum) and adverse health effects such as cardio-respiratory illnesses and mortality. Daily filter samples were chemically analyzed for multiple species. We present findings based on 2.8 years of DASH data, from 2003 to 2005. Multilinear Engine 2 (ME-2), a receptor-based source apportionment model was applied to the data to estimate source contributions to PM2.5 mass concentrations. This study relied on two different ME-2 models: (1) a 2-way model that closely reflects PMF-2; and (2) an enhanced model with meteorological data that used additional temporal and meteorological factors. The Coarse Rural Urban Sources and Health study (CRUSH) is a long-term study of the relationship between the variability in coarse particulate mass (PMcoarse, particulate matter between 2.5 and 10mum) and adverse health effects such as cardio-respiratory illnesses, pre-term births, and mortality. Hourly mass concentrations of PMcoarse and fine particulate matter (PM2.5) are measured using tapered element oscillating microbalances (TEOMs) with Filter Dynamics Measurement Systems (FDMS), at two rural and two urban sites. We present findings based on nine months of mass concentration data, including temporal trends, and non-parametric regressions (NPR) results, which were used to characterize the wind speed and wind direction relationships that might point to sources. As part of CRUSH, 1-year coarse and fine mode particulate matter filter sampling network, will allow us to characterize the chemical composition of the particulate matter collected and perform spatial comparisons. This work describes the construction and validation testing of four dichotomous filter samplers for this purpose. The use of dichotomous splitters with an approximate 2.5mum cut point, coupled with a 10mum cut diameter inlet head allows us to collect the separated size fractions that the collocated TEOMs collect continuously. Chemical analysis of the filters will include inorganic ions, organic compounds, EC, OC, and biological analyses. Side by side testing showed the cut diameters were in agreement with each other, and with a well characterized virtual impactor lent to the group by the University of Southern California. Error propagation was performed and uncertainty results were similar to the observed standard deviations.

Using Sediment Records to Reconstruct Historical Inputs Combustion-Derived Contaminants to Urban Airsheds/Watersheds: A Case Study From the Puget Sound

NASA Astrophysics Data System (ADS)

Louchouarn, P. P.; Kuo, L.; Brandenberger, J.; Marcantonio, F.; Wade, T. L.; Crecelius, E.; Gobeil, C.

2008-12-01

Urban centers are major sources of combustion-derived particulate matter (e.g. black carbon (BC), polycyclic aromatic hydrocarbons (PAH), anhydrosugars) and volatile organic compounds to the atmosphere. Evidence is mounting that atmospheric emissions from combustion sources remain major contributors to air pollution of urban systems. For example, recent historical reconstructions of depositional fluxes for pyrogenic PAHs close to urban systems have shown an unanticipated reversal in the trends of decreasing emissions initiated during the mid-20th Century. Here we compare a series of historical reconstructions of combustion emission in urban and rural airsheds over the last century using sedimentary records. A complex suite of combustion proxies (BC, PAHs, anhydrosugars, stable lead concentrations and isotope signatures) assisted in elucidating major changes in the type of atmospheric aerosols originating from specific processes (i.e. biomass burning vs. fossil fuel combustion) or fuel sources (wood vs. coal vs. oil). In all studied locations, coal continues to be a major source of combustion-derived aerosols since the early 20th Century. Recently, however, oil and biomass combustion have become substantial additional sources of atmospheric contamination. In the Puget Sound basin, along the Pacific Northwest region of the U.S., rural locations not impacted by direct point sources of contamination have helped assess the influence of catalytic converters on concentrations of oil-derived PAH and lead inputs since the early 1970s. Although atmospheric deposition of lead has continued to drop since the introduction of catalytic converters and ban on leaded gasoline, PAH inputs have "rebounded" in the last decade. A similar steady and recent rise in PAH accumulations in urban systems has been ascribed to continued urban sprawl and increasing vehicular traffic. In the U.S., automotive emissions, whether from gasoline or diesel combustion, are becoming a major source of combustion-derived PM and BC to the atmosphere and have started to replace coal as the major source in some surficial reservoirs. This increased urban influence of gasoline and diesel combustion on BC emissions was also observed in Europe both from model estimates as well as from measured fluxes in recent lake sediments.

Open Source Tools for Numerical Simulation of Urban Greenhouse Gas Emissions

NASA Astrophysics Data System (ADS)

Nottrott, A.; Tan, S. M.; He, Y.

2016-12-01

There is a global movement toward urbanization. Approximately 7% of the global population lives in just 28 megacities, occupying less than 0.1% of the total land area used by human activity worldwide. These cities contribute a significant fraction of the global budget of anthropogenic primary pollutants and greenhouse gasses. The 27 largest cities consume 9.9%, 9.3%, 6.7% and 3.0% of global gasoline, electricity, energy and water use, respectively. This impact motivates novel approaches to quantify and mitigate the growing contribution of megacity emissions to global climate change. Cities are characterized by complex topography, inhomogeneous turbulence, and variable pollutant source distributions. These features create a scale separation between local sources and urban scale emissions estimates known as the Grey-Zone. Modern computational fluid dynamics (CFD) techniques provide a quasi-deterministic, physically based toolset to bridge the scale separation gap between source level dynamics, local measurements, and urban scale emissions inventories. CFD has the capability to represent complex building topography and capture detailed 3D turbulence fields in the urban boundary layer. This presentation discusses the application of OpenFOAM to urban CFD simulations of natural gas leaks in cities. OpenFOAM is an open source software for advanced numerical simulation of engineering and environmental fluid flows. When combined with free or low cost computer aided drawing and GIS, OpenFOAM generates a detailed, 3D representation of urban wind fields. OpenFOAM was applied to model methane (CH4) emissions from various components of the natural gas distribution system, to investigate the impact of urban meteorology on mobile CH4 measurements. The numerical experiments demonstrate that CH4 concentration profiles are highly sensitive to the relative location of emission sources and buildings. Sources separated by distances of 5-10 meters showed significant differences in vertical dispersion of the plume due to building wake effects. The OpenFOAM flow fields were combined with an inverse, stochastic dispersion model to quantify and visualize the sensitivity of point sensors to upwind sources in various built environments.

Possible Solutions for Financial Crises of the Private Sector of Higher Education.

ERIC Educational Resources Information Center

Bolling, Landrum R.

Our society is at a point where a number of interlocking crises-inflation, ever rising expectations, war, urban problems, youth's discontent-are coming together. Money is needed at every point and the private college cannot rely on the federal government or private sources to save them from financial disaster. The private college can tackle its…

Urban Methane Point Sources Detected by Tiered System of Remote-sensing Observations

NASA Image and Video Library

2015-07-10

This image captured by a prototype NASA satellite instrument at NASA California Laboratory for Atmospheric Remote Sensing CLARS shows a persistent methane hotspot central red area over Los Angeles basin.

[Empirical study on non-point sources pollution based on landscape pattern & ecological processes theory: a case of soil water loss on the Loess Plateau in China].

PubMed

Suo, An-ning; Wang, Tian-ming; Wang, Hui; Yu, Bo; Ge, Jian-ping

2006-12-01

Non-point sources pollution is one of main pollution modes which pollutes the earth surface environment. Aimed at soil water loss (a typical non-point sources pollution problem) on the Losses Plateau in China, the paper applied a landscape patternevaluation method to twelve watersheds of Jinghe River Basin on the Loess Plateau by means of location-weighted landscape contrast index(LCI) and landscape slope index(LSI). The result showed that LSI of farm land, low density grass land, forest land and LCI responded significantly to soil erosion modulus and responded to depth of runoff, while the relationship between these landscape index and runoff variation index and erosion variation index were not statistically significant. This tell us LSI and LWLCI are good indicators of soil water loss and thus have big potential in non-point source pollution risk evaluation.

Preliminary Assessment of Health Risks of Potentially Toxic Elements in Settled Dust over Beijing Urban Area

PubMed Central

Wan, Dejun; Zhan, Changlin; Yang, Guanglin; Liu, Xingqi; Yang, Jinsong

2016-01-01

To examine levels, health risks, sources, and spatial distributions of potentially toxic elements in settled dust over Beijing urban area, 62 samples were collected mostly from residential building outdoor surfaces, and their <63 μm fractions were measured for 12 potentially toxic elements. The results show that V, Cr, Mn, Co, Ni, and Ba in dust are from predominantly natural sources, whereas Cu, Zn, As, Cd, Sb, and Pb mostly originate from anthropogenic sources. Exposure to these elements in dust has significant non-cancer risks to children but insignificant to adults. Cancer risks of Cr, Co, Ni, As, and Cd via inhalation and dermal contact are below the threshold of 10−6–10−4 but As via dust ingestion shows a tolerable risk. The non-cancer risks to children are contributed mainly (75%) by As, Pb, and Sb, and dominantly (92%) via dust ingestion, with relatively higher risks mainly occurring in the eastern and northeastern Beijing urban areas. Although Cd, Zn, and Cu in dust are heavily affected by anthropogenic sources, their health risks are insignificant. Source appointments suggest that coal burning emissions, the dominant source of As, are likely the largest contributors to the health risk, and traffic-related and industrial emissions are also important because they contribute most of the Pb and Sb in dust. PMID:27187427

Metabolomics for in situ environmental monitoring of surface waters impacted by contaminants from both point and non-point sources

EPA Science Inventory

We investigated the efficacy of metabolomics for field-monitoring of fish exposed to waste water treatment plant (WWTP) effluents and non-point sources of chemical contamination. Lab-reared male fathead minnows (Pimephales promelas, FHM) were held in mobile monitoring units and e...

Non-traditional Infrasound Deployment

NASA Astrophysics Data System (ADS)

McKenna, M. H.; McComas, S.; Simpson, C. P.; Diaz-Alvarez, H.; Costley, R. D.; Hayward, C.; Golden, P.; Endress, A.

2017-12-01

Historically, infrasound arrays have been deployed in rural environments where anthropological noise sources are limited. As interest in monitoring low energy sources at local distances grows in the infrasound community, it will be vital to understand how to monitor infrasound sources in an urban environment. Arrays deployed in urban centers have to overcome the decreased signal-to-noise ratio and reduced amount of real estate available to deploy an array. To advance the understanding of monitoring infrasound sources in urban environments, local and regional infrasound arrays were deployed on building rooftops on the campus at Southern Methodist University (SMU), and data were collected for one seasonal cycle. The data were evaluated for structural source signals (continuous-wave packets), and when a signal was identified, the back azimuth to the source was determined through frequency-wavenumber analysis. This information was used to identify hypothesized structural sources; these sources were verified through direct measurement and dynamic structural analysis modeling. In addition to the rooftop arrays, a camouflaged infrasound sensor was installed on the SMU campus and evaluated to determine its effectiveness for wind noise reduction. Permission to publish was granted by Director, Geotechnical and Structures Laboratory.

Consolidating Data of Global Urban Populations: a Comparative Approach

NASA Astrophysics Data System (ADS)

Blankespoor, B.; Khan, A.; Selod, H.

2017-12-01

Global data on city populations are essential for the study of urbanization, city growth and the spatial distribution of human settlements. Such data are either gathered by combining official estimates of urban populations from across countries or extracted from gridded population models that combine these estimates with geospatial data. These data sources provide varying estimates of urban populations and each approach has its advantages and limitations. In particular, official figures suffer from a lack of consistency in defining urban units (across both space and time) and often provide data for jurisdictions rather than the functionally meaningful urban area. On the other hand, gridded population models require a user-imposed definition to identify urban areas and are constrained by the modelling techniques and input data employed. To address these drawbacks, we combine these approaches by consolidating information from three established sources: (i) the Citypopulation.de (Brinkhoff, 2016); (ii) the World Urban Prospects data (United Nations, 2014); and (iii) the Global Human Settlements population grid (GHS-POP) (EC - JRC, 2015). We create urban footprints with GHS-POP and spatially merge georeferenced city points from both UN WUP and Citypopulation.de with these urban footprints to identify city points that belong to a single agglomeration. We create a consolidated dataset by combining population data from the UN WUP and Citypopulation.de. The flexible framework outlined can incorporate information from alternative inputs to identify urban clusters e.g. by using night-time lights, built-up area or alternative gridded population models (e.g WorldPop or Landscan) and the parameters employed (e.g. density thresholds for urban footprints) may also be adjusted, e.g., as a function of city-specific characteristics. Our consolidated dataset provides a wider and more accurate coverage of city populations to support studies of urbanization. We apply the data to re-examine Zipf's Law. Brinkhoff, Thomas. 2016. City Population.EC - JRC; Columbia University, CIESIN. 2015. GHS population grid, derived from GPW4, multi-temporal (1975, 1990, 2000, 2015).United Nations, Department of Economic and Social Affairs, Population Division. 2014. World Urbanization Prospects: 2014 Revision.

Weakly Supervised Segmentation-Aided Classification of Urban Scenes from 3d LIDAR Point Clouds

NASA Astrophysics Data System (ADS)

Guinard, S.; Landrieu, L.

2017-05-01

We consider the problem of the semantic classification of 3D LiDAR point clouds obtained from urban scenes when the training set is limited. We propose a non-parametric segmentation model for urban scenes composed of anthropic objects of simple shapes, partionning the scene into geometrically-homogeneous segments which size is determined by the local complexity. This segmentation can be integrated into a conditional random field classifier (CRF) in order to capture the high-level structure of the scene. For each cluster, this allows us to aggregate the noisy predictions of a weakly-supervised classifier to produce a higher confidence data term. We demonstrate the improvement provided by our method over two publicly-available large-scale data sets.

Academic urban legends

PubMed Central

2014-01-01

Many of the messages presented in respectable scientific publications are, in fact, based on various forms of rumors. Some of these rumors appear so frequently, and in such complex, colorful, and entertaining ways that we can think of them as academic urban legends. The explanation for this phenomenon is usually that authors have lazily, sloppily, or fraudulently employed sources, and peer reviewers and editors have not discovered these weaknesses in the manuscripts during evaluation. To illustrate this phenomenon, I draw upon a remarkable case in which a decimal point error appears to have misled millions into believing that spinach is a good nutritional source of iron. Through this example, I demonstrate how an academic urban legend can be conceived and born, and can continue to grow and reproduce within academia and beyond. PMID:25272616

Scalar Dispersion from Point Sources in a Realistic Urban Environment

NASA Astrophysics Data System (ADS)

Salesky, S.; Giometto, M. G.; Christen, A.; Parlange, M. B.

2016-12-01

Accurate modeling of scalar dispersion within and above urban canopies is critical to properly predict air quality and dispersion (e.g. accidental contaminant release) in urban environments. We perform large eddy simulations (LES) of scalar dispersion from point sources in a typical North American neighborhood using topography and foliage density derived from airborne LIDAR scans with 1 m resolution in Vancouver, BC, Canada. The added drag force due to trees is parameterized in the LES as a function of the leaf area density (LAD) profile. Conversely, drag from buildings is accounted for using a direct forcing approach immersed-boundary method. The scalar advection-diffusion equation is discretized in a finite-volume framework, and accurate mass conservation is enforced through a recently developed Cartesian cut cell method. Simulations are performed with trees for different values of LAD, representative of summer and winter conditions, as well as a case without trees. The effects of varying mean wind direction (derived from observed wind climatologies) on dispersion patterns are also considered. Scalar release locations in the LES are informed by spatially distributed measurements of carbon dioxide concentration; CO2 is used as a tracer for fossil fuel emissions, since source strengths are well-known and the contribution from biological processes in this setting is small (<10%). The effects of leaf area density, source height, and wind direction on scalar statistics including the growth of the mean concentration plume and the fraction that escapes the urban canopy layer will be considered. In a companion study, the presence of trees was found to strongly modify sweep and ejection patterns for the momentum flux; here we consider the related issue of how vegetation influences coherent structures responsible for scalar transport.

Overview of the Texas Source Water Assessment Project

USGS Publications Warehouse

Ulery, Randy L.

2000-01-01

The 1996 Amendments to the Safe Drinking Water Act require, for the first time, that each state prepare a source water assessment for all PWS. Previously, Federal regulations focused on sampling and enforcement with emphasis on the quality of delivered water. These Amendments emphasize the importance of protecting the source water. States are required to determine the drinking-water source, the origin of contaminants monitored or the potential contaminants to be monitored, and the intrinsic susceptibility of the source water. Under the amendments to the Act, States must create SWAP Programs. The programs must include an individual source water assessment for each public water system regulated by the State. These assessments will determine whether an individual drinking water source is susceptible to contamination. During 1997?99, TNRCC and USGS staff met as subject-matter working groups to develop an approach to conducting Source Water Susceptibility Assessments (SWSA) and a draft workplan. The draft workplan was then presented to and reviewed by various stakeholder and technical advisory groups. Comments and suggestions from these groups were considered, and a final workplan was produced and presented to the EPA. After EPA approval, work formally began on the Texas SWAP Project. The project has an expected completion date of September 2002. At that time, initial SWSA of all Texas public water supplies should be complete. Ground-water supplies can be considered susceptible if a possible source of contamination (PSOC) exists in the contributing area for the public-supply well field or spring, the contaminant travel time to the well field or spring is short, and the soil zone, vadose zone, and aquifer-matrix materials are unlikely to adequately attenuate the contaminants associated with the PSOC. In addition, particular types of land use/cover within the contributing area may cause the supply to be deemed more susceptible to contamination. Finally, detection of various classes of constituents in water from wells in the vicinity of a public supply well may indicate susceptibility of the public-supply well even though there may be no identifiable PSOC or land use activity. Surface-water supplies are by nature susceptible to contamination from both point and non-point sources. The degree of susceptibility of a PWS to contamination can vary and is a function of the environmental setting, water and wastewater management practices, and land use/cover within a water supply's contributing watershed area. For example, a PWS intake downstream from extensive urban development may be more susceptible to non-point source contamination than a PWS intake downstream from a forested, relatively undeveloped watershed. Surface-water supplies are also susceptible to contamination from point sources, which may include permitted discharges, as well as accidental spills or other introduction of contaminants.

Occurrence of Surface Water Contaminations: An Overview

NASA Astrophysics Data System (ADS)

Shahabudin, M. M.; Musa, S.

2018-04-01

Water is a part of our life and needed by all organisms. As time goes by, the needs by human increased transforming water quality into bad conditions. Surface water contaminated in various ways which is pointed sources and non-pointed sources. Pointed sources means the source are distinguished from the source such from drains or factory but the non-pointed always occurred in mixed of elements of pollutants. This paper is reviewing the occurrence of the contaminations with effects that occurred around us. Pollutant factors from natural or anthropology factors such nutrients, pathogens, and chemical elements contributed to contaminations. Most of the effects from contaminated surface water contributed to the public health effects also to the environments.

Automatic registration of Iphone images to LASER point clouds of the urban structures using shape features

NASA Astrophysics Data System (ADS)

Sirmacek, B.; Lindenbergh, R. C.; Menenti, M.

2013-10-01

Fusion of 3D airborne laser (LIDAR) data and terrestrial optical imagery can be applied in 3D urban modeling and model up-dating. The most challenging aspect of the fusion procedure is registering the terrestrial optical images on the LIDAR point clouds. In this article, we propose an approach for registering these two different data from different sensor sources. As we use iPhone camera images which are taken in front of the interested urban structure by the application user and the high resolution LIDAR point clouds of the acquired by an airborne laser sensor. After finding the photo capturing position and orientation from the iPhone photograph metafile, we automatically select the area of interest in the point cloud and transform it into a range image which has only grayscale intensity levels according to the distance from the image acquisition position. We benefit from local features for registering the iPhone image to the generated range image. In this article, we have applied the registration process based on local feature extraction and graph matching. Finally, the registration result is used for facade texture mapping on the 3D building surface mesh which is generated from the LIDAR point cloud. Our experimental results indicate possible usage of the proposed algorithm framework for 3D urban map updating and enhancing purposes.

UNMIX Methods Applied to Characterize Sources of Volatile Organic Compounds in Toronto, Ontario

PubMed Central

Porada, Eugeniusz; Szyszkowicz, Mieczysław

2016-01-01

UNMIX, a sensor modeling routine from the U.S. Environmental Protection Agency (EPA), was used to model volatile organic compound (VOC) receptors in four urban sites in Toronto, Ontario. VOC ambient concentration data acquired in 2000–2009 for 175 VOC species in four air quality monitoring stations were analyzed. UNMIX, by performing multiple modeling attempts upon varying VOC menus—while rejecting the results that were not reliable—allowed for discriminating sources by their most consistent chemical characteristics. The method assessed occurrences of VOCs in sources typical of the urban environment (traffic, evaporative emissions of fuels, banks of fugitive inert gases), industrial point sources (plastic-, polymer-, and metalworking manufactures), and in secondary sources (releases from water, sediments, and contaminated urban soil). The remote sensing and robust modeling used here produces chemical profiles of putative VOC sources that, if combined with known environmental fates of VOCs, can be used to assign physical sources’ shares of VOCs emissions into the atmosphere. This in turn provides a means of assessing the impact of environmental policies on one hand, and industrial activities on the other hand, on VOC air pollution. PMID:29051416

Spatial-Temporal Variations of Water Quality and Its Relationship to Land Use and Land Cover in Beijing, China

PubMed Central

Chen, Xiang; Zhou, Weiqi; Pickett, Steward T. A.; Li, Weifeng; Han, Lijian

2016-01-01

Rapid urbanization with intense land use and land cover (LULC) change and explosive population growth has a great impact on water quality. The relationship between LULC characteristics and water quality provides important information for non-point sources (NPS) pollution management. In this study, we first quantified the spatial-temporal patterns of five water quality variables in four watersheds with different levels of urbanization in Beijing, China. We then examined the effects of LULC on water quality across different scales, using Pearson correlation analysis, redundancy analysis, and multiple regressions. The results showed that water quality was improved over the sampled years but with no significant difference (p > 0.05). However, water quality was significantly different among nonurban and both exurban and urban sites (p < 0.05). Forest land was positively correlated with water quality and affected water quality significantly (p < 0.05) within a 200 m buffer zone. Impervious surfaces, water, and crop land were negatively correlated with water quality. Crop land and impervious surfaces, however, affected water quality significantly (p < 0.05) for buffer sizes greater than 800 m. Grass land had different effects on water quality with the scales. The results provide important insights into the relationship between LULC and water quality, and thus for controlling NPS pollution in urban areas. PMID:27128934

A comparative study of the grain-size distribution of surface dust and stormwater runoff quality on typical urban roads and roofs in Beijing, China.

PubMed

Shen, Zhenyao; Liu, Jin; Aini, Guzhanuer; Gong, Yongwei

2016-02-01

The deposition of pollutants on impervious surfaces is a serious problem associated with rapid urbanization, which results in non-point-source pollution. Characterizing the build-up and wash-off processes of pollutants in urban catchments is essential for urban planners. In this paper, the spatial variation and particle-size distributions of five heavy metals and two nutrients in surface dust were analyzed, and the runoff water first-flush effect (FF30) and event-mean concentrations (EMCs) of 10 common constituents were characterized. The relationships between runoff variables and stormwater characteristics were examined from three typical urban impervious surfaces in Beijing, China. Dust on road surfaces with smaller grain sizes had higher pollutant concentrations, whereas concentrations of Mn, Zn, Fe, and TP in roof surface dust increased with grain size. Particles with grain sizes of 38-74 and 125-300 μm contributed most to the total pollutant load in roads, while particles with the smallest grain sizes (<38 μm) contributed most on roofs (23.46-41.71 %). Event-mean concentrations (EMCs) and FF30 values for most runoff pollutants tended to be higher on roofs than on roads. The maximum intensity (I max) and the antecedent dry days (ADD) were critical parameters for EMCs in roads, while ADD was the only dominant parameter for EMCs on our studied roof. The rainfall intensity (RI) and maximum intensity (I max) were found to be the parameters with the strongest correlation to the first-flush effect on both roads and roofs. Significant correlations of total suspended solids (TSS) concentration in runoff with grain-size fractions of surface dust indicated that coarser particles (74-300 μm) are most likely to contribute to the solid-phase pollutants, and finer particles (<38 μm) are likely the main source of dissolved pollutants.

Spatial distribution and source apportionment of water pollution in different administrative zones of Wen-Rui-Tang (WRT) river watershed, China.

PubMed

Yang, Liping; Mei, Kun; Liu, Xingmei; Wu, Laosheng; Zhang, Minghua; Xu, Jianming; Wang, Fan

2013-08-01

Water quality degradation in river systems has caused great concerns all over the world. Identifying the spatial distribution and sources of water pollutants is the very first step for efficient water quality management. A set of water samples collected bimonthly at 12 monitoring sites in 2009 and 2010 were analyzed to determine the spatial distribution of critical parameters and to apportion the sources of pollutants in Wen-Rui-Tang (WRT) river watershed, near the East China Sea. The 12 monitoring sites were divided into three administrative zones of urban, suburban, and rural zones considering differences in land use and population density. Multivariate statistical methods [one-way analysis of variance, principal component analysis (PCA), and absolute principal component score-multiple linear regression (APCS-MLR) methods] were used to investigate the spatial distribution of water quality and to apportion the pollution sources. Results showed that most water quality parameters had no significant difference between the urban and suburban zones, whereas these two zones showed worse water quality than the rural zone. Based on PCA and APCS-MLR analysis, urban domestic sewage and commercial/service pollution, suburban domestic sewage along with fluorine point source pollution, and agricultural nonpoint source pollution with rural domestic sewage pollution were identified to the main pollution sources in urban, suburban, and rural zones, respectively. Understanding the water pollution characteristics of different administrative zones could put insights into effective water management policy-making especially in the area across various administrative zones.

Status of metal levels and their potential sources of contamination in Southeast Asian rivers.

PubMed

Chanpiwat, Penradee; Sthiannopkao, Suthipong

2014-01-01

To assess the concentration and status of metal contaminants in four major Southeast Asian river systems, water were collected from the Tonle Sap-Bassac Rivers (Cambodia), Citarum River (Indonesia), lower Chao Phraya River (Thailand), and Saigon River (Vietnam) in both dry and wet seasons. The target elements were Be, Al, Ti, V, Cr, Mn, Fe, Co, Ni, Cu, Zn, As, Se, Mo, Ag, Cd, Ba, Tl, and Pb and the concentrations exceeded the background metal concentrations by 1- to 88-fold. This distinctly indicates enrichment by human urban area activities. The results of a normalization technique used to distinguish natural from enriched metal concentrations confirmed contamination by Al, Cd, Co, Mn, Ni, Pb, and Zn. Cluster analysis revealed the probable source of metals contamination in most sampling sites on all rivers studied to be anthropogenic, including industrial, commercial, and residential activities. Stable lead isotopes analyses applied to track the sources and pathways of anthropogenic lead furthermore confirmed that anthropogenic sources of metal contaminated these rivers. Discharges of wastewater from both industrial and household activities were major contributors of Pb into the rivers. Non-point sources, especially road runoff and street dust, also contributed contamination from Pb and other metals.

Bioavailability evaluation, uptake of heavy metals and potential health risks via dietary exposure in urban-industrial areas.

PubMed

Yousaf, Balal; Liu, Guijian; Wang, Ruwei; Imtiaz, Muhammad; Zia-Ur-Rehman, Muhammad; Munir, Mehr Ahmed Mujtaba; Niu, Zhiyuan

2016-11-01

A verity of human activities i.e. urbanization and industrialization have been resulted serious environmental contaminations by heavy metals in all over the world. The settlement of populations in urban and nearby industrial areas for economic development has significant share in their exposure to these metallic contaminants. Depending on the nature and type of the pollutants, targeted urban-industrial environments can have harmful and chronic health risk impacts on exposed local inhabitants and may require detoxification, healing and remedial therapy. Consequently, environmental monitoring as well as human health risk assessments of urban environments under industrial influence are key dominant features. We believe this work will provide new insights into the studies of metals exposure and associated health risks in emerging industrials cities of developing countries. Present study aimed to study the bioavailability of metals, quantify the changeability in soil and vegetable metal concentrations and estimation of human health risks via dietary exposure, focusing on urban-industrial environment. Soil and vegetable samples were collected in six random sites within the urban, periurban and industrial areas and analyzed for metal concentrations. In addition, risk assessment model proposed by US-EPA was employed to estimate the potential health risk of heavy metals via dietary intake. Results indicated that the heavy metal concentrations were noteworthy in periurban and urban-industrial areas. However, contamination levels varied with the type of vegetable, and the point source pollution such as traffic, urban wastes and industrial effluent. According to the estimated THQ and HI values for non-carcinogenic risk, little or no negative impact of heavy metals was observed on local inhabitants. However, the concentrations of Cr, Cd, Pb and Ni were nearly closed to the permissible limits described by US-EPA in urban-industrial areas. Conclusively, some efficient remedial strategies should be focus to overcome the increasing levels of Cr, Cd, Pb and Ni in this study area to protect the health of local inhabitants.

Use of lidar for the evaluation of traffic-related urban pollution

NASA Astrophysics Data System (ADS)

Eichinger, William E.; Cooper, D. I.; Buttler, William T.; Cottingame, William; Tellier, Larry

1994-03-01

Lidar (Light Detection and Ranging) is demonstrated as a tool for the detection and tracking of sources of aerosol pollution. Existing elastic lidars have been used to demonstrate the potential of the application of this technology in urban areas. Data from several experiments is shown along with analysis methods used for interpretation of the data. The goal of the project is to develop a light-weight, low-cost, lidar system and data analysis methods which can be used by urban planners and local air quality managers. The ability to determine the sources, i.e., causes, of non-attainment may lead to more effective use of tax dollars. Future directions for the project are also discussed.

Widespread sewage pollution of the Indian River Lagoon system, Florida (USA) resolved by spatial analyses of macroalgal biogeochemistry.

PubMed

Barile, Peter J

2018-03-01

The Indian River Lagoon (IRL) system, a poorly flushed 240 km long estuary in east-central Florida (USA), previously received 200 MLD of point source municipal wastewater that was largely mitigated by the mid-1990's. Since then, non-point source loads, including septic tank effluent, have become more important. Seventy sites were sampled for bloom-forming macroalgae and analyzed for δ 15 N, % nitrogen, % phosphorus, carbon:nitrogen, carbon:phosphorus, and nitrogen:phosphorus ratios. Data were fitted to geospatial models showing elevated δ 15 N values (>+5‰), matching human wastewater in most of the IRL system, with elevated enrichment (δ 15 N ≥ +7‰ to +10‰) in urbanized portions of the central IRL and Banana River Lagoon. Results suggest increased mobilization of OSDS NH 4 + during the wetter 2014 season. Resource managers must improve municipal wastewater treatment infrastructure and commence significant septic-to-sewer conversion to mitigate nitrogen over-enrichment, water quality decline and habitat loss as mandated in the Tampa and Sarasota Bays and the Florida Keys. Copyright © 2018 Marine Research & Consulting, Inc. Published by Elsevier Ltd.. All rights reserved.

Nutrient mass balance and trends, Mobile River Basin, Alabama, Georgia, and Mississippi

USGS Publications Warehouse

Harned, D.A.; Atkins, J.B.; Harvill, J.S.

2004-01-01

A nutrient mass balance - accounting for nutrient inputs from atmospheric deposition, fertilizer, crop nitrogen fixation, and point source effluents; and nutrient outputs, including crop harvest and storage - was calculated for 18 subbasins in the Mobile River Basin, and trends (1970 to 1997) were evaluated as part of the U.S. Geological Survey National Water Quality Assessment (NAWQA) Program. Agricultural nonpoint nitrogen and phosphorus sources and urban nonpoint nitrogen sources are the most important factors associated with nutrients in this system. More than 30 percent of nitrogen yield in two basins and phosphorus yield in eight basins can be attributed to urban point source nutrient inputs. The total nitrogen yield (1.3 tons per square mile per year) for the Tombigbee River, which drains a greater percentage of agricultural (row crop) land use, was larger than the total nitrogen yield (0.99 tons per square mile per year) for the Alabama River. Decreasing trends of total nitrogen concentrations in the Tombigbee and Alabama Rivers indicate that a reduction occurred from 1975 to 1997 in the nitrogen contributions to Mobile Bay from the Mobile River. Nitrogen concentrations also decreased (1980 to 1995) in the Black Warrior River, one of the major tributaries to the Tombigbee River. Total phosphorus concentrations increased from 1970 to 1996 at three urban influenced sites on the Etowah River in Georgia. Multiple regression analysis indicates a distinct association between water quality in the streams of the Mobile River drainage basin and agricultural activities in the basin.

Trail Creek II: Modeling Flow and E. Coli Concentrations in a Small Urban Stream using SWAT

NASA Astrophysics Data System (ADS)

Radcliffe, D. E.; Saintil, T.

2017-12-01

Pathogens are one of the leading causes of stream and river impairment in the State of Georgia. The common presence of fecal bacteria is driven by several factors including rapid population growth stressing pre-existing and ageing infrastructure, urbanization and poor planning, increase percent imperviousness, urban runoff, municipal discharges, sewage, pet/wildlife waste and leaky septic tanks. The Trail Creek watershed, located in Athens-Clarke County, Georgia covers about 33 km2. Stream segments within Trail Creek violate the GA standard due to high levels of fecal coliform bacteria. In this study, the Soil and Water Assessment Tool (SWAT) modeling software was used to predict E. coli bacteria concentrations during baseflow and stormflow. Census data from the county was used for human and animal population estimates and the Fecal Indicator Tool to generate the number of colony forming units of E. Coli for each source. The model was calibrated at a daily time step with one year of monitored streamflow and E. coli bacteria data using SWAT-CUP and the SUFI2 algorithm. To simulate leaking sewer lines, we added point sources in the five subbasins in the SWAT model with the greatest length of sewer line within 50 m of the stream. The flow in the point sources were set to 5% of the stream flow and the bacteria count set to that of raw sewage (30,000 cfu/100 mL). The calibrated model showed that the average load during 2003-2013 at the watershed outlet was 13 million cfu per month. Using the calibrated model, we simulated scenarios that assumed leaking sewers were repaired in one of the five subbasins with point sources. The reduction ranged from 10 to 46%, with the largest reduction in subbasin in the downtown area. Future modeling work will focus on the use of green infrastructure to address sources of bacteria.

Urban enhancement of PM10 bioaerosol tracers relative to background locations in the Midwestern United States

NASA Astrophysics Data System (ADS)

Rathnayake, Chathurika M.; Metwali, Nervana; Baker, Zach; Jayarathne, Thilina; Kostle, Pamela A.; Thorne, Peter S.; O'Shaughnessy, Patrick T.; Stone, Elizabeth A.

2016-05-01

Bioaerosols are well-known immune-active particles that exacerbate respiratory diseases. Human exposures to bioaerosols and their resultant health impacts depend on their ambient concentrations, seasonal and spatial variation, and copollutants, which are not yet widely characterized. In this study, chemical and biological tracers of bioaerosols were quantified in respirable particulate matter (PM10) collected at three urban and three background sites in the Midwestern United States across four seasons in 2012. Endotoxins from Gram-negative bacteria (and a few Gram-positive bacteria), water-soluble proteins, and tracers for fungal spores (fungal glucans, arabitol, and mannitol) were ubiquitous and showed significant seasonal variation and dependence on temperature. Fungal spores were elevated in spring and peaked in summer, following the seasonal growing cycle, while endotoxins peaked in autumn during the row crop harvesting season. Paired comparisons of bioaerosols in urban and background sites revealed significant urban enhancements in PM10, fungal glucans, endotoxins, and water-soluble proteins relative to background locations, such that urban populations have a greater outdoor exposure to bioaerosols. These bioaerosols contribute, in part, to the urban excesses in PM10. Higher bioaerosol mass fractions in urban areas relative to background sites indicate that urban areas serve as a source of bioaerosols. Similar urban enhancements in water-soluble calcium and its correlation with bioaerosol tracers point toward windblown soil as an important source of bioaerosols in urban areas.

Source Apportionment of the Size-Fractionated Urban Aerosols in and around Kolkata, India

NASA Astrophysics Data System (ADS)

Sarkar, Ujjaini; Haque, Monirul; Roy, Rajdeep; Chakraborty, Sanjoy

Our main objective was to estimate the heavy metals like the Lead, Mercury, Cadmium, Sodium, Potassium, Calcium, Aluminium, and Iron, in addition to ammonium, chloride, nitrate, and sulphate ions, by Atomic Absorption Spectrophotometry and Ion Chromatography and apportion the most probable sources using the Chemical Mass Balance Model. The three urban locations of Behala Chowrasta, Rabindra Sadan, and Shyam Bazaar Five Points were chosen within the city of Kolkata. One rural location was chosen at the Indian Institute of Technology campus, Kharagpur, a rural site in the Midnapur District of the state of West Bengal, India. The results look quite encouraging.

Riverine threat indices to assess watershed condition and identify primary management capacity of agriculture natural resource management agencies.

PubMed

Fore, Jeffrey D; Sowa, Scott P; Galat, David L; Annis, Gust M; Diamond, David D; Rewa, Charles

2014-03-01

Managers can improve conservation of lotic systems over large geographies if they have tools to assess total watershed conditions for individual stream segments and can identify segments where conservation practices are most likely to be successful (i.e., primary management capacity). The goal of this research was to develop a suite of threat indices to help agriculture resource management agencies select and prioritize watersheds across Missouri River basin in which to implement agriculture conservation practices. We quantified watershed percentages or densities of 17 threat metrics that represent major sources of ecological stress to stream communities into five threat indices: agriculture, urban, point-source pollution, infrastructure, and all non-agriculture threats. We identified stream segments where agriculture management agencies had primary management capacity. Agriculture watershed condition differed by ecoregion and considerable local variation was observed among stream segments in ecoregions of high agriculture threats. Stream segments with high non-agriculture threats were most concentrated near urban areas, but showed high local variability. 60 % of stream segments in the basin were classified as under U.S. Department of Agriculture's Natural Resources Conservation Service (NRCS) primary management capacity and most segments were in regions of high agricultural threats. NRCS primary management capacity was locally variable which highlights the importance of assessing total watershed condition for multiple threats. Our threat indices can be used by agriculture resource management agencies to prioritize conservation actions and investments based on: (a) relative severity of all threats, (b) relative severity of agricultural threats, and (c) and degree of primary management capacity.

Tightly-Coupled GNSS/Vision Using a Sky-Pointing Camera for Vehicle Navigation in Urban Areas

PubMed Central

2018-01-01

This paper presents a method of fusing the ego-motion of a robot or a land vehicle estimated from an upward-facing camera with Global Navigation Satellite System (GNSS) signals for navigation purposes in urban environments. A sky-pointing camera is mounted on the top of a car and synchronized with a GNSS receiver. The advantages of this configuration are two-fold: firstly, for the GNSS signals, the upward-facing camera will be used to classify the acquired images into sky and non-sky (also known as segmentation). A satellite falling into the non-sky areas (e.g., buildings, trees) will be rejected and not considered for the final position solution computation. Secondly, the sky-pointing camera (with a field of view of about 90 degrees) is helpful for urban area ego-motion estimation in the sense that it does not see most of the moving objects (e.g., pedestrians, cars) and thus is able to estimate the ego-motion with fewer outliers than is typical with a forward-facing camera. The GNSS and visual information systems are tightly-coupled in a Kalman filter for the final position solution. Experimental results demonstrate the ability of the system to provide satisfactory navigation solutions and better accuracy than the GNSS-only and the loosely-coupled GNSS/vision, 20 percent and 82 percent (in the worst case) respectively, in a deep urban canyon, even in conditions with fewer than four GNSS satellites. PMID:29673230

Tightly-Coupled GNSS/Vision Using a Sky-Pointing Camera for Vehicle Navigation in Urban Areas.

PubMed

Gakne, Paul Verlaine; O'Keefe, Kyle

2018-04-17

This paper presents a method of fusing the ego-motion of a robot or a land vehicle estimated from an upward-facing camera with Global Navigation Satellite System (GNSS) signals for navigation purposes in urban environments. A sky-pointing camera is mounted on the top of a car and synchronized with a GNSS receiver. The advantages of this configuration are two-fold: firstly, for the GNSS signals, the upward-facing camera will be used to classify the acquired images into sky and non-sky (also known as segmentation). A satellite falling into the non-sky areas (e.g., buildings, trees) will be rejected and not considered for the final position solution computation. Secondly, the sky-pointing camera (with a field of view of about 90 degrees) is helpful for urban area ego-motion estimation in the sense that it does not see most of the moving objects (e.g., pedestrians, cars) and thus is able to estimate the ego-motion with fewer outliers than is typical with a forward-facing camera. The GNSS and visual information systems are tightly-coupled in a Kalman filter for the final position solution. Experimental results demonstrate the ability of the system to provide satisfactory navigation solutions and better accuracy than the GNSS-only and the loosely-coupled GNSS/vision, 20 percent and 82 percent (in the worst case) respectively, in a deep urban canyon, even in conditions with fewer than four GNSS satellites.

Determination of viable Salmonellae from potable and source water through PMA assisted qPCR.

PubMed

Singh, Gulshan; Vajpayee, Poornima; Bhatti, Saurabh; Ronnie, Nirmala; Shah, Nimish; McClure, Peter; Shanker, Rishi

2013-07-01

Resource constrained countries identified as endemic zones for pathogenicity of Salmonella bear an economic burden due to recurring expenditure on medical treatment. qPCR used for Salmonella detection could not discriminate between viable and nonviable cells. Propidium monoazide (PMA) that selectively penetrates nonviable cells to cross-link their DNA, was coupled with ttr gene specific qPCR for quantifying viable salmonellae in source/potable waters collected from a north Indian city. Source water (raw water for urban potable water supply) and urban potable water exhibited viable salmonellae in the range of 2.1×10(4)-2.6×10(6) and 2-7160CFU/100mL, respectively. Potable water at water works exhibited DNA from dead cells but no viable cells were detected. PMA assisted qPCR could specifically detect low numbers of live salmonellae in Source and potable waters. This strategy can be used in surveillance of urban potable water distribution networks to map contamination points for better microbial risk management. Copyright © 2013 Elsevier Inc. All rights reserved.

Transplantation of epiphytic bioaccumulators (Tillandsia capillaris) for high spatial resolution biomonitoring of trace elements and point sources deconvolution in a complex mining/smelting urban context

NASA Astrophysics Data System (ADS)

Goix, Sylvaine; Resongles, Eléonore; Point, David; Oliva, Priscia; Duprey, Jean Louis; de la Galvez, Erika; Ugarte, Lincy; Huayta, Carlos; Prunier, Jonathan; Zouiten, Cyril; Gardon, Jacques

2013-12-01

Monitoring atmospheric trace elements (TE) levels and tracing their source origin is essential for exposure assessment and human health studies. Epiphytic Tillandsia capillaris plants were used as bioaccumulator of TE in a complex polymetallic mining/smelting urban context (Oruro, Bolivia). Specimens collected from a pristine reference site were transplanted at a high spatial resolution (˜1 sample/km2) throughout the urban area. About twenty-seven elements were measured after a 4-month exposure, also providing new information values for reference material BCR482. Statistical power analysis for this biomonitoring mapping approach against classical aerosols surveys performed on the same site showed the better aptitude of T. Capillaris to detect geographical trend, and to deconvolute multiple contamination sources using geostatistical principal component analysis. Transplanted specimens in the vicinity of the mining and smelting areas were characterized by extreme TE accumulation (Sn > Ag > Sb > Pb > Cd > As > W > Cu > Zn). Three contamination sources were identified: mining (Ag, Pb, Sb), smelting (As, Sn) and road traffic (Zn) emissions, confirming results of previous aerosol survey.

Magnitudes, nature, and effects of point and nonpoint discharges in the Chattahoochee River basin, Atlanta to West Point Dam, Georgia

USGS Publications Warehouse

Stamer, J.K.; Cherry, R.N.; Faye, R.E.; Kleckner, R.L.

1978-01-01

On an average annual basis and during the storm period of March 12-15, 1976, nonpoint-source loads for most constituents were larger than point-source loads at the Whitesburg station, located on the Chattahoochee River about 40 miles downstream from Atlanta, GA. Most of the nonpoint-source constituent loads in the Atlanta to Whitesburg reach were from urban areas. Average annual point-source discharges accounted for about 50 percent of the dissolved nitrogen, total nitrogen, and total phosphorus loads and about 70 percent of the dissolved phosphorus loads at Whitesburg. During a low-flow period, June 1-2, 1977, five municipal point-sources contributed 63 percent of the ultimate biochemical oxygen demand, and 97 percent of the ammonium nitrogen loads at the Franklin station, at the upstream end of West Point Lake. Dissolved-oxygen concentrations of 4.1 to 5.0 milligrams per liter occurred in a 22-mile reach of the river downstream from Atlanta due about equally to nitrogenous and carbonaceous oxygen demands. The heat load from two thermoelectric powerplants caused a decrease in dissolved-oxygen concentration of about 0.2 milligrams per liter. Phytoplankton concentrations in West Point Lake, about 70 miles downstream from Atlanta, could exceed three million cells per millimeter during extended low-flow periods in the summer with present point-source phosphorus loads. (Woodard-USGS)

A GIS-Based Model for the analysis of an urban flash flood and its hydro-geomorphic response. The Valencia event of 1957

NASA Astrophysics Data System (ADS)

Portugués-Mollá, I.; Bonache-Felici, X.; Mateu-Bellés, J. F.; Marco-Segura, J. B.

2016-10-01

Flash floods are recurrent events around the Mediterranean region. Extreme episodes activate hydro-geomorphic high-intensity processes with low frequency. In urban environments, the complexity becomes higher due to the existence of very quick-response runoff. However, immediate recovery works remove the urban marks. After a short time both the significance and magnitude of the hydro-geomorphic event become completely unrecognizable. Nevertheless, these episodes generate extensive documentation which is testimony of the processes in almost real time. It is necessary to exploit this source typology in order to draw flood sketches when events far in time may lack a sufficiently rich database. This is particularly the case for the Valencia flash flood (October 1957), located in the lower Turia River basin (Eastern Spain). It left numerous pieces of hydro-geomorphic evidence, but its tracks were covered a short while after the flood. In any case, it remains part of a non-systematic legacy that has not yet been exploited, consisting of immediate aerial and oblique high resolution photography, pictures at street level, water marks and administrative records. Paradoxically, despite being considered a milestone in metropolitan territorial planning (the river was definitely diverted), an accurate reconstruction of the hydraulic behaviour was required from an integrated point of view. To this aim, the development of a GIS-Based Model enabled the utilisation of the above-mentioned materials. This non-conventional information was treated jointly from a new perspective. It provided database support through a vast amount of organised, structured and georeferenced information about the 1957 event. In a second stage, the GBM made it possible to characterise the Turia urban reach and interpret both the hydro-geomorphic (trenches along barrier beaches, erosion, deposition, etc.) and hydraulic (urban streams along the streets, flow directions, flood extent, levees breaks, overflows and inflows, etc.) processes mainly through photo-interpretation.

Synthetic fibers in atmospheric fallout: A source of microplastics in the environment?

PubMed

Dris, Rachid; Gasperi, Johnny; Saad, Mohamed; Mirande, Cécile; Tassin, Bruno

2016-03-15

Sources, pathways and reservoirs of microplastics, plastic particles smaller than 5mm, remain poorly documented in an urban context. While some studies pointed out wastewater treatment plants as a potential pathway of microplastics, none have focused on the atmospheric compartment. In this work, the atmospheric fallout of microplastics was investigated in two different urban and sub-urban sites. Microplastics were collected continuously with a stainless steel funnel. Samples were then filtered and observed with a stereomicroscope. Fibers accounted for almost all the microplastics collected. An atmospheric fallout between 2 and 355 particles/m(2)/day was highlighted. Registered fluxes were systematically higher at the urban than at the sub-urban site. Chemical characterization allowed to estimate at 29% the proportion of these fibers being all synthetic (made with petrochemicals), or a mixture of natural and synthetic material. Extrapolation using weight and volume estimates of the collected fibers, allowed a rough estimation showing that between 3 and 10 tons of fibers are deposited by atmospheric fallout at the scale of the Parisian agglomeration every year (2500 km(2)). These results could serve the scientific community working on the different sources of microplastic in both continental and marine environments. Copyright © 2016 Elsevier Ltd. All rights reserved.

Network design for quantifying urban CO2 emissions: assessing trade-offs between precision and network density

NASA Astrophysics Data System (ADS)

Turner, Alexander J.; Shusterman, Alexis A.; McDonald, Brian C.; Teige, Virginia; Harley, Robert A.; Cohen, Ronald C.

2016-11-01

The majority of anthropogenic CO2 emissions are attributable to urban areas. While the emissions from urban electricity generation often occur in locations remote from consumption, many of the other emissions occur within the city limits. Evaluating the effectiveness of strategies for controlling these emissions depends on our ability to observe urban CO2 emissions and attribute them to specific activities. Cost-effective strategies for doing so have yet to be described. Here we characterize the ability of a prototype measurement network, modeled after the Berkeley Atmospheric CO2 Observation Network (BEACO2N) in California's Bay Area, in combination with an inverse model based on the coupled Weather Research and Forecasting/Stochastic Time-Inverted Lagrangian Transport (WRF-STILT) to improve our understanding of urban emissions. The pseudo-measurement network includes 34 sites at roughly 2 km spacing covering an area of roughly 400 km2. The model uses an hourly 1 × 1 km2 emission inventory and 1 × 1 km2 meteorological calculations. We perform an ensemble of Bayesian atmospheric inversions to sample the combined effects of uncertainties of the pseudo-measurements and the model. We vary the estimates of the combined uncertainty of the pseudo-observations and model over a range of 20 to 0.005 ppm and vary the number of sites from 1 to 34. We use these inversions to develop statistical models that estimate the efficacy of the combined model-observing system in reducing uncertainty in CO2 emissions. We examine uncertainty in estimated CO2 fluxes on the urban scale, as well as for sources embedded within the city such as a line source (e.g., a highway) or a point source (e.g., emissions from the stacks of small industrial facilities). Using our inversion framework, we find that a dense network with moderate precision is the preferred setup for estimating area, line, and point sources from a combined uncertainty and cost perspective. The dense network considered here (modeled after the BEACO2N network with an assumed mismatch error of 1 ppm at an hourly temporal resolution) could estimate weekly CO2 emissions from an urban region with less than 5 % error, given our characterization of the combined observation and model uncertainty.

Network design for quantifying urban CO 2 emissions: assessing trade-offs between precision and network density

DOE PAGES

Turner, Alexander J.; Shusterman, Alexis A.; McDonald, Brian C.; ...

2016-11-01

The majority of anthropogenic CO 2 emissions are attributable to urban areas. While the emissions from urban electricity generation often occur in locations remote from consumption, many of the other emissions occur within the city limits. Evaluating the effectiveness of strategies for controlling these emissions depends on our ability to observe urban CO 2 emissions and attribute them to specific activities. Cost-effective strategies for doing so have yet to be described. Here we characterize the ability of a prototype measurement network, modeled after the Berkeley Atmospheric CO 2 Observation Network (BEACO 2N) in California's Bay Area, in combination with anmore » inverse model based on the coupled Weather Research and Forecasting/Stochastic Time-Inverted Lagrangian Transport (WRF-STILT) to improve our understanding of urban emissions. The pseudo-measurement network includes 34 sites at roughly 2 km spacing covering an area of roughly 400 km 2. The model uses an hourly 1 × 1 km 2 emission inventory and 1 × 1 km 2 meteorological calculations. We perform an ensemble of Bayesian atmospheric inversions to sample the combined effects of uncertainties of the pseudo-measurements and the model. We vary the estimates of the combined uncertainty of the pseudo-observations and model over a range of 20 to 0.005 ppm and vary the number of sites from 1 to 34. We use these inversions to develop statistical models that estimate the efficacy of the combined model–observing system in reducing uncertainty in CO 2 emissions. We examine uncertainty in estimated CO 2 fluxes on the urban scale, as well as for sources embedded within the city such as a line source (e.g., a highway) or a point source (e.g., emissions from the stacks of small industrial facilities). Using our inversion framework, we find that a dense network with moderate precision is the preferred setup for estimating area, line, and point sources from a combined uncertainty and cost perspective. The dense network considered here (modeled after the BEACO 2N network with an assumed mismatch error of 1 ppm at an hourly temporal resolution) could estimate weekly CO 2 emissions from an urban region with less than 5 % error, given our characterization of the combined observation and model uncertainty.« less

Network design for quantifying urban CO 2 emissions: assessing trade-offs between precision and network density

DOE Office of Scientific and Technical Information (OSTI.GOV)

Turner, Alexander J.; Shusterman, Alexis A.; McDonald, Brian C.

The majority of anthropogenic CO 2 emissions are attributable to urban areas. While the emissions from urban electricity generation often occur in locations remote from consumption, many of the other emissions occur within the city limits. Evaluating the effectiveness of strategies for controlling these emissions depends on our ability to observe urban CO 2 emissions and attribute them to specific activities. Cost-effective strategies for doing so have yet to be described. Here we characterize the ability of a prototype measurement network, modeled after the Berkeley Atmospheric CO 2 Observation Network (BEACO 2N) in California's Bay Area, in combination with anmore » inverse model based on the coupled Weather Research and Forecasting/Stochastic Time-Inverted Lagrangian Transport (WRF-STILT) to improve our understanding of urban emissions. The pseudo-measurement network includes 34 sites at roughly 2 km spacing covering an area of roughly 400 km 2. The model uses an hourly 1 × 1 km 2 emission inventory and 1 × 1 km 2 meteorological calculations. We perform an ensemble of Bayesian atmospheric inversions to sample the combined effects of uncertainties of the pseudo-measurements and the model. We vary the estimates of the combined uncertainty of the pseudo-observations and model over a range of 20 to 0.005 ppm and vary the number of sites from 1 to 34. We use these inversions to develop statistical models that estimate the efficacy of the combined model–observing system in reducing uncertainty in CO 2 emissions. We examine uncertainty in estimated CO 2 fluxes on the urban scale, as well as for sources embedded within the city such as a line source (e.g., a highway) or a point source (e.g., emissions from the stacks of small industrial facilities). Using our inversion framework, we find that a dense network with moderate precision is the preferred setup for estimating area, line, and point sources from a combined uncertainty and cost perspective. The dense network considered here (modeled after the BEACO 2N network with an assumed mismatch error of 1 ppm at an hourly temporal resolution) could estimate weekly CO 2 emissions from an urban region with less than 5 % error, given our characterization of the combined observation and model uncertainty.« less

Concentrations, fluxes, and yields of nitrogen, phosphorus, and suspended sediment in the Illinois River basin, 1996-2000

USGS Publications Warehouse

Terrio, Paul J.

2006-01-01

Concentrations, spatial and temporal variations, and fluxes of nitrogen, phosphorus, and suspended sediment were determined for 16 streams in the Illinois River Basin, Illinois from October 1996 through September 2000. Water samples were collected through the National Water-Quality Assessment's Lower Illinois River Basin (LIRB) and Upper Illinois River Basin (UIRB) Study Units on a monthly to weekly frequency from watersheds representing predominantly agricultural and urban land, as well as areas of mixed land-use. Streams in agricultural watersheds had high concentrations and fluxes of nitrate nitrogen, whereas streams in predominantly urban watersheds had high concentrations (above background levels) of ammonia nitrogen, organic nitrogen, and phosphorus. Median concentrations of nitrate nitrogen and total phosphorus were similar at the two Illinois River sampling stations (Illinois River at Ottawa, Ill. and Illinois River at Valley City, Ill.) that represented the downstream points of the UIRB and LIRB Study Units, respectively, and integrated multiple land-use areas. Concentrations of nitrogen were typically highest in the spring and lowest in the fall in agricultural watersheds, but highest in the winter in urban watersheds. Phosphorus concentrations in urban watersheds were highest in the fall and winter, but there was minimal seasonal variation in phosphorus concentrations in agricultural watersheds. Concentrations of nitrate and total nitrogen were affected primarily by non-point sources and hydrologic factors such as streamflow, storm intensity, watershed configuration, and soil permeability, whereas concentrations of phosphorus were affected largely by point-source contributions that typically have little seasonal variation. Seasonal variation in hydrologic conditions was an important factor for seasonal variation in nutrient concentration. Fluxes and yields of nitrogen and phosphorus forms varied substantially throughout the Illinois River Basin, and yields of specific nutrient forms were determined primarily by upstream land uses. Yields of nitrate nitrogen were highest in predominantly agricultural watersheds, whereas yields of phosphorus and ammonia nitrogen were highest in urban watersheds with wastewater effluent contributions. Yields of both total nitrogen and total phosphorus were similar at the two Illinois River stations representing the integrated UIRB and LIRB Study Units. Concentrations of suspended sediment ranged from 1 to 3,110 milligrams per liter (mg/L), with median concentrations generally higher in the UIRB. Suspended-sediment concentrations were highest and most variable in the LaMoine River Basin. The median concentration of suspended sediment in the Illinois River at Valley City, Ill. (155 mg/L) was twice as high as that at Ottawa, Ill. (80 mg/L). Fluxes of suspended sediment generally corresponded to watershed size and yields from agricultural watersheds were larger than yields from urban watersheds. The flux in the Illinois River at Valley City, Ill. (4,880,000 tons per year) was approximately four times the flux in the Illinois River at Ottawa, Ill. (1,060,000 tons per year).

Urban particulate matter pollution: a tale of five cities.

PubMed

Pandis, Spyros N; Skyllakou, Ksakousti; Florou, Kalliopi; Kostenidou, Evangelia; Kaltsonoudis, Christos; Hasa, Erion; Presto, Albert A

2016-07-18

Five case studies (Athens and Paris in Europe, Pittsburgh and Los Angeles in the United States, and Mexico City in Central America) are used to gain insights into the changing levels, sources, and role of atmospheric chemical processes in air quality in large urban areas as they develop technologically. Fine particulate matter is the focus of our analysis. In all cases reductions of emissions by industrial and transportation sources have resulted in significant improvements in air quality during the last few decades. However, these changes have resulted in the increasing importance of secondary particulate matter (PM) which dominates over primary in most cases. At the same time, long range transport of secondary PM from sources located hundreds of kilometres from the cities is becoming a bigger contributor to the urban PM levels in all seasons. "Non-traditional" sources including cooking, and residential and agricultural biomass burning contribute an increasing fraction of the now reduced fine PM levels. Atmospheric chemistry is found to change the chemical signatures of a number of these sources relatively fast both during the day and night, complicating the corresponding source apportionment.

NMOC, ozone, and organic aerosol in the southeastern United States, 1999-2007: 3. Origins of organic aerosol in Atlanta, Georgia, and surrounding areas

NASA Astrophysics Data System (ADS)

Blanchard, C. L.; Hidy, G. M.; Tanenbaum, S.; Edgerton, E. S.

2011-02-01

Carbonaceous compounds constitute a major fraction of the fine particle mass at locations throughout North America; much of the condensed-phase organic carbon (OC) is produced in the atmosphere from NMOC reactions as "secondary" OC (SOC). Ten years of particulate carbon and speciated non-methane organic compound (NMOC) data combined with other measurements from Southeastern Aerosol Research and Characterization (SEARCH) and other sites provide insight into the association between elemental carbon (EC), OC and NMOCs. Data are analyzed to characterize the OC and SOC contrasts between urban Atlanta, Georgia, and nearby non-urban conditions in the Southeast. Analysis of the monitoring record indicates that the mean Atlanta urban excess of total carbon (TC) is 2.1-2.8 μg m -3. The OC/EC ratio of the Atlanta urban excess is in the range 1.3 to 1.8, consistent with OC/EC ratios observed in motor vehicle emissions and a fossil carbon source of urban excess TC. Carbon isotope analysis of a subset of particle samples demonstrates that the urban excess is mainly fossil in origin, even though the majority of the TC is modern at both urban and non-urban sites. Temperature-dependent partitioning of OC between gas and condensed phases cannot explain the observed diurnal and seasonal variations of OC/CO, EC/CO, and OC/EC ratios. Alternatively, a hypothesis involving vertical mixing of OC-enriched air from aloft is supported by the seasonal and diurnal OC, isopentane, aromatic and isoprene observations at the ground. A statistical model is applied to indicate the relative significance of aerometric factors affecting OC and EC concentrations, including meteorological and pollutant associations. The model results demonstrate strong linkages between fine particle carbon and pollutant indicators of source emissions compared with meteorological factors; the model results show weaker dependence of OC on meteorological factors than is the case for ozone (O 3) concentrations.

Better Assessment Science Integrating Point and Non-point Sources (BASINS)

EPA Pesticide Factsheets

Better Assessment Science Integrating Point and Nonpoint Sources (BASINS) is a multipurpose environmental analysis system designed to help regional, state, and local agencies perform watershed- and water quality-based studies.

Long-Term Hydrologic Impact Assessment of Non-point Source Pollution Measured Through Land Use/Land Cover (LULC) Changes in a Tropical Complex Catchment

NASA Astrophysics Data System (ADS)

Abdulkareem, Jabir Haruna; Sulaiman, Wan Nor Azmin; Pradhan, Biswajeet; Jamil, Nor Rohaizah

2018-03-01

The contribution of non-point source pollution (NPS) to the contamination of surface water is an issue of growing concern. Non-point source (NPS) pollutants are of various types and altered by several site-specific factors making them difficult to control due to complex uncertainties involve in their behavior. Kelantan River basin, Malaysia is a tropical catchment receiving heavy monsoon rainfall coupled with intense land use/land cover (LULC) changes making the area consistently flood prone thereby deteriorating the surface water quality in the area. This study was conducted to determine the spatio-temporal variation of NPS pollutant loads among different LULC changes and to establish a NPS pollutant loads relationships among LULC conditions and sub-basins in each catchment. Four pollutants parameters such as total suspended solids (TSS), total phosphorus (TP), total nitrogen (TN) and ammonia nitrogen (AN) were chosen with their corresponding event mean concentration values (EMC). Soil map and LULC change maps corresponding to 1984, 2002 and 2013 were used for the calculation of runoff and NPS pollutant loads using numeric integration in a GIS environment. Analysis of Variance (ANOVA) was conducted for the comparison of NPS pollutant loads among the three LULC conditions used and the sub-basins in each catchment. The results showed that the spatio-temporal variation of pollutant loads in almost all the catchments increased with changes in LULC condition as one moves from 1984 to 2013, with 2013 LULC condition found as the dominant in almost all cases. NPS pollutant loads among different LULC changes also increased with changes in LULC condition from 1984 to 2013. While urbanization was found to be the dominant LULC change with the highest pollutant load in all the catchments. Results from ANOVA reveals that statistically most significant (p < 0.05) pollutant loads were obtained from 2013 LULC conditions, while statistically least significant (p < 0.05) pollutant loads were obtained under 1984 LULC condition. This reveals the clear effect of LULC changes on NPS pollution. The findings of this study may be useful to water resource planners in controlling water pollution for future planning.

Long-Term Hydrologic Impact Assessment of Non-point Source Pollution Measured Through Land Use/Land Cover (LULC) Changes in a Tropical Complex Catchment

NASA Astrophysics Data System (ADS)

Abdulkareem, Jabir Haruna; Sulaiman, Wan Nor Azmin; Pradhan, Biswajeet; Jamil, Nor Rohaizah

2018-05-01

The contribution of non-point source pollution (NPS) to the contamination of surface water is an issue of growing concern. Non-point source (NPS) pollutants are of various types and altered by several site-specific factors making them difficult to control due to complex uncertainties involve in their behavior. Kelantan River basin, Malaysia is a tropical catchment receiving heavy monsoon rainfall coupled with intense land use/land cover (LULC) changes making the area consistently flood prone thereby deteriorating the surface water quality in the area. This study was conducted to determine the spatio-temporal variation of NPS pollutant loads among different LULC changes and to establish a NPS pollutant loads relationships among LULC conditions and sub-basins in each catchment. Four pollutants parameters such as total suspended solids (TSS), total phosphorus (TP), total nitrogen (TN) and ammonia nitrogen (AN) were chosen with their corresponding event mean concentration values (EMC). Soil map and LULC change maps corresponding to 1984, 2002 and 2013 were used for the calculation of runoff and NPS pollutant loads using numeric integration in a GIS environment. Analysis of Variance (ANOVA) was conducted for the comparison of NPS pollutant loads among the three LULC conditions used and the sub-basins in each catchment. The results showed that the spatio-temporal variation of pollutant loads in almost all the catchments increased with changes in LULC condition as one moves from 1984 to 2013, with 2013 LULC condition found as the dominant in almost all cases. NPS pollutant loads among different LULC changes also increased with changes in LULC condition from 1984 to 2013. While urbanization was found to be the dominant LULC change with the highest pollutant load in all the catchments. Results from ANOVA reveals that statistically most significant ( p < 0.05) pollutant loads were obtained from 2013 LULC conditions, while statistically least significant ( p < 0.05) pollutant loads were obtained under 1984 LULC condition. This reveals the clear effect of LULC changes on NPS pollution. The findings of this study may be useful to water resource planners in controlling water pollution for future planning.

40 CFR 52.2350 - Emission inventories.

Code of Federal Regulations, 2010 CFR

2010-07-01

...). This inventory addresses emissions from point, area, non-road, on-road mobile, and biogenic sources.... The ozone maintenance plan for Salt Lake and Davis Counties that the Governor submitted on February 19... carbon monoxide emissions from stationary point, area, non-road, and on-road mobile sources. (c) On June...

HYDROLOGY AND SEDIMENT MODELING USING THE BASINS NON-POINT SOURCE MODEL

EPA Science Inventory

The Non-Point Source Model (Hydrologic Simulation Program-Fortran, or HSPF) within the EPA Office of Water's BASINS watershed modeling system was used to simulate streamflow and total suspended solids within Contentnea Creek, North Carolina, which is a tributary of the Neuse Rive...

Heavy metal transport in large river systems: heavy metal emissions and loads in the Rhine and Elbe river basins

NASA Astrophysics Data System (ADS)

Vink, Rona; Behrendt, Horst

2002-11-01

Pollutant transport and management in the Rhine and Elbe basins is still of international concern, since certain target levels set by the international committees for protection of both rivers have not been reached. The analysis of the chain of emissions of point and diffuse sources to river loads will provide policy makers with a tool for effective management of river basins. The analysis of large river basins such as the Elbe and Rhine requires information on the spatial and temporal characteristics of both emissions and physical information of the entire river basin. In this paper, an analysis has been made of heavy metal emissions from various point and diffuse sources in the Rhine and Elbe drainage areas. Different point and diffuse pathways are considered in the model, such as inputs from industry, wastewater treatment plants, urban areas, erosion, groundwater, atmospheric deposition, tile drainage, and runoff. In most cases the measured heavy metal loads at monitoring stations are lower than the sum of the heavy metal emissions. This behaviour in large river systems can largely be explained by retention processes (e.g. sedimentation) and is dependent on the specific runoff of a catchment. Independent of the method used to estimate emissions, the source apportionment analysis of observed loads was used to determine the share of point and diffuse sources in the heavy metal load at a monitoring station by establishing a discharge dependency. The results from both the emission analysis and the source apportionment analysis of observed loads were compared and gave similar results. Between 51% (for Hg) and 74% (for Pb) of the total transport in the Elbe basin is supplied by inputs from diffuse sources. In the Rhine basin diffuse source inputs dominate the total transport and deliver more than 70% of the total transport. The diffuse hydrological pathways with the highest share are erosion and urban areas.

Urban microbial ecology of a freshwater estuary of Lake Michigan.

PubMed

Fisher, Jenny C; Newton, Ryan J; Dila, Deborah K; McLellan, Sandra L

Freshwater estuaries throughout the Great Lakes region receive stormwater runoff and riverine inputs from heavily urbanized population centers. While human and animal feces contained in this runoff are often the focus of source tracking investigations, non-fecal bacterial loads from soil, aerosols, urban infrastructure, and other sources are also transported to estuaries and lakes. We quantified and characterized this non-fecal urban microbial component using bacterial 16S rRNA gene sequences from sewage, stormwater, rivers, harbor/estuary, and the lake surrounding Milwaukee, WI, USA. Bacterial communities from each of these environments had a distinctive composition, but some community members were shared among environments. We used a statistical biomarker discovery tool to identify the components of the microbial community that were most strongly associated with stormwater and sewage to describe an "urban microbial signature," and measured the presence and relative abundance of these organisms in the rivers, estuary, and lake. This urban signature increased in magnitude in the estuary and harbor with increasing rainfall levels, and was more apparent in lake samples with closest proximity to the Milwaukee estuary. The dominant bacterial taxa in the urban signature were Acinetobacter, Aeromonas , and Pseudomonas , which are organisms associated with pipe infrastructure and soil and not typically found in pelagic freshwater environments. These taxa were highly abundant in stormwater and sewage, but sewage also contained a high abundance of Arcobacter and Trichococcus that appeared in lower abundance in stormwater outfalls and in trace amounts in aquatic environments. Urban signature organisms comprised 1.7% of estuary and harbor communities under baseflow conditions, 3.5% after rain, and >10% after a combined sewer overflow. With predicted increases in urbanization across the Great Lakes, further alteration of freshwater communities is likely to occur with potential long term impacts on the function of estuarine and nearshore ecosystems.

Non-auditory factors affecting urban soundscape evaluation.

PubMed

Jeon, Jin Yong; Lee, Pyoung Jik; Hong, Joo Young; Cabrera, Densil

2011-12-01

The aim of this study is to characterize urban spaces, which combine landscape, acoustics, and lighting, and to investigate people's perceptions of urban soundscapes through quantitative and qualitative analyses. A general questionnaire survey and soundwalk were performed to investigate soundscape perception in urban spaces. Non-auditory factors (visual image, day lighting, and olfactory perceptions), as well as acoustic comfort, were selected as the main contexts that affect soundscape perception, and context preferences and overall impressions were evaluated using an 11-point numerical scale. For qualitative analysis, a semantic differential test was performed in the form of a social survey, and subjects were also asked to describe their impressions during a soundwalk. The results showed that urban soundscapes can be characterized by soundmarks, and soundscape perceptions are dominated by acoustic comfort, visual images, and day lighting, whereas reverberance in urban spaces does not yield consistent preference judgments. It is posited that the subjective evaluation of reverberance can be replaced by physical measurements. The categories extracted from the qualitative analysis revealed that spatial impressions such as openness and density emerged as some of the contexts of soundscape perception. © 2011 Acoustical Society of America

PAH molecular diagnostic ratios applied to atmospheric sources: a critical evaluation using two decades of source inventory and air concentration data from the UK.

PubMed

Katsoyiannis, Athanasios; Sweetman, Andrew J; Jones, Kevin C

2011-10-15

Molecular diagnostic ratios (MDRs)-the ratios of defined pairs of individual compounds-have been widely used as markers of different source categories of polycyclic aromatic hydrocarbons (PAHs). However, it is well-known that variations in combustion conditions and environmental degradation processes can cause substantial variability in the emission and degradation of individual compounds, potentially undermining the application of MDRs as reliable source apportionment tools. The United Kingdom produces a national inventory of atmospheric emissions of PAHs, and has an ambient air monitoring program at a range of rural, semirural, urban, and industrial sites. The inventory and the monitoring data are available over the past 20 years (1990-2010), a time frame that has seen known changes in combustion type and source. Here we assess 5 MDRs that have been used in the literature as source markers. We examine the spatial and temporal variability in the ratios and consider whether they are responsive to known differences in source strength and types between sites (on rural-urban gradients) and to underlying changes in national emissions since 1990. We conclude that the use of these 5 MDRs produces contradictory results and that they do not respond to known differences (in time and space) in atmospheric emission sources. For example, at a site near a motorway and far from other evident emission sources, the use of MDRs suggests "non-traffic" emissions. The ANT/(ANT + PHE) ratio is strongly seasonal at some sites; it is the most susceptible MDR to atmospheric processes, so these results illustrate how weathering in the environment will undermine the effectiveness of MDRs as markers of source(s). We conclude that PAH MDRs can exhibit spatial and temporal differences, but they are not valid markers of known differences in source categories and type. Atmospheric sources of PAHs in the UK are probably not dominated by any single clear and strong source type, so the mixture of PAHs in air is quickly "blended" away from the influence of the few major point sources which exist and further weathered in the environment by atmospheric reactions and selective loss processes.

Spatial and temporal variability of contaminants within estuarine sediments and native Olympia oysters: A contrast between a developed and an undeveloped estuary

USGS Publications Warehouse

Granek, Elise F.; Conn, Kathleen E.; Nilsen, Elena B.; Pillsbury, Lori; Strecker, Angela L.; Rumrill, Steve; Fish, William

2016-01-01

Chemical contaminants can be introduced into estuarine and marine ecosystems from a variety of sources including wastewater, agriculture and forestry practices, point and non-point discharges, runoff from industrial, municipal, and urban lands, accidental spills, and atmospheric deposition. The diversity of potential sources contributes to the likelihood of contaminated marine waters and sediments and increases the probability of uptake by marine organisms. Despite widespread recognition of direct and indirect pathways for contaminant deposition and organismal exposure in coastal systems, spatial and temporal variability in contaminant composition, deposition, and uptake patterns are still poorly known. We investigated these patterns for a suite of persistent legacy contaminants including polychlorinated biphenyls (PCBs) and polybrominated diphenyl ethers (PBDEs) and chemicals of emerging concern including pharmaceuticals within two Oregon coastal estuaries (Coos and Netarts Bays). In the more urbanized Coos Bay, native Olympia oyster (Ostrea lurida) tissue had approximately twice the number of PCB congeners at over seven times the total concentration, yet fewer PBDEs at one-tenth the concentration as compared to the more rural Netarts Bay. Different pharmaceutical suites were detected during each sampling season. Variability in contaminant types and concentrations across seasons and between species and media (organisms versus sediment) indicates the limitation of using indicator species and/or sampling annually to determine contaminant loads at a site or for specific species. The results indicate the prevalence of legacy contaminants and CECs in relatively undeveloped coastal environments highlighting the need to improve policy and management actions to reduce contaminant releases into estuarine and marine waters and to deal with legacy compounds that remain long after prohibition of use. Our results point to the need for better understanding of the ecological and human health risks of exposure to the diverse cocktail of pollutants and harmful compounds that will continue to leach from estuarine sediments over time.

Long-term changes in nitrate conditions over the 20th century in two Midwestern Corn Belt streams

USGS Publications Warehouse

Kelly, Valerie J.; Stets, Edward G.; Crawford, Charles G.

2015-01-01

Long-term changes in nitrate concentration and flux between the middle of the 20th century and the first decade of the 21st century were estimated for the Des Moines River and the Middle Illinois River, two Midwestern Corn Belt streams, using a novel weighted regression approach that is able to detect subtle changes in solute transport behavior over time. The results show that the largest changes in flow-normalized concentration and flux occurred between 1960 and 1980 in both streams, with smaller or negligible changes between 1980 and 2004. Contrasting patterns were observed between (1) nitrate export linked to non-point sources, explicitly runoff of synthetic fertilizer or other surface sources and (2) nitrate export presumably associated with point sources such as urban wastewater or confined livestock feeding facilities, with each of these modes of transport important under different domains of streamflow. Surface runoff was estimated to be consistently most important under high-flow conditions during the spring in both rivers. Nitrate export may also have been considerable in the Des Moines River even under some conditions during the winter when flows are generally lower, suggesting the influence of point sources during this time. Similar results were shown for the Middle Illinois River, which is subject to significant influence of wastewater from the Chicago area, where elevated nitrate concentrations were associated with at the lowest flows during the winter and fall. By modeling concentration directly, this study highlights the complex relationship between concentration and streamflow that has evolved in these two basins over the last 50 years. This approach provides insights about changing conditions that only become observable when stationarity in the relationship between concentration and streamflow is not assumed.

Storm drains are sources of human fecal pollution during dry weather in three urban southern California watersheds.

PubMed

Sercu, Bram; Van De Werfhorst, Laurie C; Murray, Jill; Holden, Patricia A

2009-01-15

Coastal urbanized areas in Southern California experience frequent beach water quality warnings in summer due to high concentrations of fecal indicator bacteria (FIB). Remediation can be difficult, as sources are often unknown. During two summers, we sampled three urbanized watersheds in Santa Barbara, CA at sites with historically high FIB concentrations to determine if human fecal matter was influencing water quality. By quantification of a human-specific Bacteroides marker (HBM), human waste was evidenced throughout both transects, and concentrations were highest in the discharges of several flowing storm drains. The HBM concentrations in storm drain discharges varied by up to 5 orders of magnitude on the same day. While the exact points of entry into the storm drain systems were not definitively determined, further inspection of the drain infrastructure suggested exfiltrating sanitary sewers as possible sources. The HBM and FIB concentrations were not consistently correlated, although the exclusive occurrence of high HBM concentrations with high FIB concentrations warrants the use of FIB analyses for a first tier of sampling. The association of human fecal pollution with dry weather drainage could be a window into a larger problem for other urbanized coastal areas with Mediterranean-type climates.

Impact of the China Healthy Cities Initiative on Urban Environment.

PubMed

Yue, Dahai; Ruan, Shiman; Xu, Jin; Zhu, Weiming; Zhang, Luyu; Cheng, Gang; Meng, Qingyue

2017-04-01

The China Healthy Cities initiative, a nationwide public health campaign, has been implemented for 25 years. As "Healthy China 2030" becomes the key national strategy for improving population health, this initiative is an important component. However, the effects of the initiative have not been well studied. This paper aims to explore its impact on urban environment using a multiple time series design. We adopted a stratified and systematic sampling method to choose 15 China healthy cities across the country. For the selected healthy cities, 1:1 matched non-healthy cities were selected as the comparison group. We collected longitudinal data from 5 years before cities achieved the healthy city title up to 2012. We used hierarchical models to calculate difference-in-differences estimates for examining the impact of the initiative. We found that the China Healthy Cities initiative was associated with increases in the proportion of urban domestic sewage treated (32 percentage points), the proportion of urban domestic garbage treated (30 percentage points), and the proportion of qualified farmers' markets (40 percentage points), all of which are statistically significant (P < 0.05). No significant change was found for increases in green coverage of urban built-up area (5 percentage points), green space per capita (2 square meter), and days with Air Quality Index/Air Pollution Index ≤ 100 (25 days). In conclusion, the China Healthy Cities initiative was associated with significant improved urban environment in terms of infrastructure construction, yet had little impact on green space and air quality.

The pattern of N/P/Si stoichiometry and ecological nutrient limitation in Ganga River: up- and downstream urban influences

NASA Astrophysics Data System (ADS)

Yadav, Amita; Pandey, Jitendra

2018-06-01

The pattern of N/P/Si stoichiometry, although an important driver regulating river ecology, has received limited research attention for Ganga River. We investigated shifts in N/P/Si stoichiometry and ecological nutrient limitation as influenced by Varanasi urban core along a 37-km-long stretch of Ganga River. We also assessed the trophic status of the river in relation to shifting elemental stoichiometry. Together with point sources, atmospheric deposition coupled surface runoff appeared important factors leading to N/P/Si stoichiometric imbalances along the study stretch. The N/P and Si/P ratios declined downstream from 15.5 to 6.5 and 15.7 to 4.4, respectively, whereas N/Si increased from 1.01 to 1.6. Significant negative correlation of N/Si with biogenic silica to chlorophyll a (Chl a) ratios, and biogenic silica to phycocyanin ratios indicated increased growth of non-siliceous algae downstream signifying N and Si limitation with possible implications on food-web dynamics and feedback processes in the river in long run.

Development of statistical linear regression model for metals from transportation land uses.

PubMed

Maniquiz, Marla C; Lee, Soyoung; Lee, Eunju; Kim, Lee-Hyung

2009-01-01

The transportation landuses possessing impervious surfaces such as highways, parking lots, roads, and bridges were recognized as the highly polluted non-point sources (NPSs) in the urban areas. Lots of pollutants from urban transportation are accumulating on the paved surfaces during dry periods and are washed-off during a storm. In Korea, the identification and monitoring of NPSs still represent a great challenge. Since 2004, the Ministry of Environment (MOE) has been engaged in several researches and monitoring to develop stormwater management policies and treatment systems for future implementation. The data over 131 storm events during May 2004 to September 2008 at eleven sites were analyzed to identify correlation relationships between particulates and metals, and to develop simple linear regression (SLR) model to estimate event mean concentration (EMC). Results indicate that there was no significant relationship between metals and TSS EMC. However, the SLR estimation models although not providing useful results are valuable indicators of high uncertainties that NPS pollution possess. Therefore, long term monitoring employing proper methods and precise statistical analysis of the data should be undertaken to eliminate these uncertainties.

Barriers to dog rabies vaccination during an urban rabies outbreak: Qualitative findings from Arequipa, Peru.

PubMed

Castillo-Neyra, Ricardo; Brown, Joanna; Borrini, Katty; Arevalo, Claudia; Levy, Michael Z; Buttenheim, Alison; Hunter, Gabrielle C; Becerra, Victor; Behrman, Jere; Paz-Soldan, Valerie A

2017-03-01

Canine rabies was reintroduced to the city of Arequipa, Peru in March 2015. The Ministry of Health has conducted a series of mass dog vaccination campaigns to contain the outbreak, but canine rabies virus transmission continues in Arequipa's complex urban environment, putting the city's 1 million inhabitants at risk of infection. The proximate driver of canine rabies in Arequipa is low dog vaccination coverage. Our objectives were to qualitatively assess barriers to and facilitators of rabies vaccination during mass campaigns, and to explore strategies to increase participation in future efforts. We conducted 8 focus groups (FG) in urban and peri-urban communities of Mariano Melgar district; each FG included both sexes, and campaign participants and non-participants. All FG were transcribed and then coded independently by two coders. Results were summarized using the Social Ecological Model. At the individual level, participants described not knowing enough about rabies and vaccination campaigns, mistrusting the campaign, and being unable to handle their dogs, particularly in peri-urban vs. urban areas. At the interpersonal level, we detected some social pressure to vaccinate dogs, as well as some disparaging of those who invest time and money in pet dogs. At the organizational level, participants found the campaign information to be insufficient and ill-timed, and campaign locations and personnel inadequate. At the community level, the influence of landscape and topography on accessibility to vaccination points was reported differently between participants from the urban and peri-urban areas. Poor security and impermanent housing materials in the peri-urban areas also drives higher prevalence of guard dog ownership for home protection; these dogs usually roam freely on the streets and are more difficult to handle and bring to the vaccination points. A well-designed communication campaign could improve knowledge about canine rabies. Timely messages on where and when vaccination is occurring could increase dog owners' perception of their own ability to bring their dogs to the vaccination points and be part of the campaign. Small changes in the implementation of the campaign at the vaccination points could increase the public's trust and motivation. Location of vaccination points should take into account landscape and community concerns.

Quality characterization and impact assessment of highway runoff in urban and rural area of Guangzhou, China.

PubMed

Gan, Huayang; Zhuo, Muning; Li, Dingqiang; Zhou, Yongzhang

2008-05-01

Accurate knowledge of the quality and environmental impact of the highway runoff in Pear River Delta, South China is required to assess this important non-point pollution source. This paper presents the quality characterization and environmental impact assessment of rainfall runoff from highways in urban and rural area of Guangzhou, the largest city of Pear River Delta over 1 year's investigation. Multiple regression and Pearson correlation analysis were used to determine influence of the rainfall characteristics on water quality and correlations among the constituents in highway runoff. The results and analysis indicates that the runoff water is nearly neutral with low biodegradability. Oil and grease (O&G), suspended solids (SS) and heavy metals are the dominant pollutants in contrast to the low level of nutrient constituents in runoff. Quality of highway runoff at rural site is better than that of at urban site for most constituents. Depth and antecedent dry period are the main rainfall factors influencing quality of highway runoff. The correlation patterns among constituents in highway runoff at urban site are consistent with their dominant phases in water. Strong correlations (r > or = 0.80) are found among chemical oxygen demand (COD), total phosphorus, Cu and Zn as well as conductivity, nitrate nitrogen and total nitrogen. O&G, COD, SS and Pb in highway runoff at urban site substantially exceed their concentrations in receiving water of Pear River. The soil directly discharged by highway runoff at rural site has contaminated seriously by heavy metals in surface layer accompanying with pH conversion from original acidic to alkaline at present.

Evaluation of Cities in the Context of Energy Efficient Urban Planning Approach

NASA Astrophysics Data System (ADS)

Handan Yücel Yıldırım, H.; Burcu Gültekin, Arzuhan; Tanrıvermiş, Harun

2017-10-01

Due to the increase in energy need with urbanization as a result of industrialization and rapid population growth, preservation of natural resources has become impossible. As the energy generated particularly from non-renewable natural resources that are in danger of depletion such as coal, natural gas, petroleum is limited, and as environmental issues caused by energy resources increase, means of safe and continuous access to energy are searched in the world. Owing to the limited energy resources and energy dependence on foreign sources in the world, particularly in European Union countries, efforts of increasing the share of renewable energy sources in energy consumption increased in all industries, including urban planning as well. Concordantly, it is necessary to develop policies and approaches that enable utilization of domestic resources complying with the country’s conditions, and monitor developments in energy. Such policies and approaches, which must be implemented in urban planning as well, have great importance in terms of not deteriorating habitable environments of future generations while utilizing present-day energy resources, prevalence of utilization of renewable energy sources, and utilization of energy effectively. For that purpose, this paper puts forward a conceptual framework covering the principles, strategies, and methods on energy efficient urban planning approach, and discusses the energy efficient urban area examples within the scope of the suggested framework.

Tracking Nitrogen Sources, Transformation, and Transport at a Basin Scale with Complex Plain River Networks.

PubMed

Yi, Qitao; Chen, Qiuwen; Hu, Liuming; Shi, Wenqing

2017-05-16

This research developed an innovative approach to reveal nitrogen sources, transformation, and transport in large and complex river networks in the Taihu Lake basin using measurement of dual stable isotopes of nitrate. The spatial patterns of δ 15 N corresponded to the urbanization level, and the nitrogen cycle was associated with the hydrological regime at the basin level. During the high flow season of summer, nonpoint sources from fertilizer/soils and atmospheric deposition constituted the highest proportion of the total nitrogen load. The point sources from sewage/manure, with high ammonium concentrations and high δ 15 N and δ 18 O contents in the form of nitrate, accounted for the largest inputs among all sources during the low flow season of winter. Hot spot areas with heavy point source pollution were identified, and the pollutant transport routes were revealed. Nitrification occurred widely during the warm seasons, with decreased δ 18 O values; whereas great potential for denitrification existed during the low flow seasons of autumn and spring. The study showed that point source reduction could have effects over the short-term; however, long-term efforts to substantially control agriculture nonpoint sources are essential to eutrophication alleviation for the receiving lake, which clarifies the relationship between point and nonpoint source control.

Urban Enhancement of PM10 Bioaerosol Tracers Relative to Background Locations in the Midwestern United States

PubMed Central

Rathnayake, Chathurika M.; Metwali, Nervana; Baker, Zach; Jayarathne, Thilina; Kostle, Pamela A.; Thorne, Peter S.; O’Shaughnessy, Patrick T.; Stone, Elizabeth A.

2016-01-01

Bioaerosols are well-known immune-active particles that exacerbate respiratory diseases. Human exposures to bioaerosols and their resultant health impacts depend on their ambient concentrations, seasonal and spatial variation, and co-pollutants, which are not yet widely characterized. In this study, chemical and biological tracers of bioaerosols were quantified in respirable particulate matter (PM10) collected at three urban and three background sites in the Midwestern United States across four seasons in 2012. Endotoxins from gram negative bacteria (and a few gram positive bacteria), water-soluble proteins, and tracers for fungal spores (fungal glucans, arabitol and mannitol) were ubiquitous and showed significant seasonal variation and dependence on temperature. Fungal spores were elevated in spring and peaked in summer, following the seasonal growing cycle, while endotoxins peaked in autumn during the row crop harvesting season. Paired comparisons of bioaerosols in urban and background sites revealed significant urban enhancements in PM10, fungal glucans, endotoxins and water-soluble proteins relative to background locations, such that urban populations have a greater outdoor exposure to bioaerosols. These bioaerosols contribute, in part, to the urban excesses in PM10. Higher bioaerosol mass fractions in urban areas relative to background sites indicate that urban areas serve as a source of bioaerosols. Similar urban enhancements in water-soluble calcium and its correlation with bioaerosol tracers point towards wind-blown soil as an important source of bioaerosols in urban areas. PMID:27672535

Urban Enhancement of PM10 Bioaerosol Tracers Relative to Background Locations in the Midwestern United States.

PubMed

Rathnayake, Chathurika M; Metwali, Nervana; Baker, Zach; Jayarathne, Thilina; Kostle, Pamela A; Thorne, Peter S; O'Shaughnessy, Patrick T; Stone, Elizabeth A

2016-05-16

Bioaerosols are well-known immune-active particles that exacerbate respiratory diseases. Human exposures to bioaerosols and their resultant health impacts depend on their ambient concentrations, seasonal and spatial variation, and co-pollutants, which are not yet widely characterized. In this study, chemical and biological tracers of bioaerosols were quantified in respirable particulate matter (PM 10 ) collected at three urban and three background sites in the Midwestern United States across four seasons in 2012. Endotoxins from gram negative bacteria (and a few gram positive bacteria), water-soluble proteins, and tracers for fungal spores (fungal glucans, arabitol and mannitol) were ubiquitous and showed significant seasonal variation and dependence on temperature. Fungal spores were elevated in spring and peaked in summer, following the seasonal growing cycle, while endotoxins peaked in autumn during the row crop harvesting season. Paired comparisons of bioaerosols in urban and background sites revealed significant urban enhancements in PM 10 , fungal glucans, endotoxins and water-soluble proteins relative to background locations, such that urban populations have a greater outdoor exposure to bioaerosols. These bioaerosols contribute, in part, to the urban excesses in PM 10 . Higher bioaerosol mass fractions in urban areas relative to background sites indicate that urban areas serve as a source of bioaerosols. Similar urban enhancements in water-soluble calcium and its correlation with bioaerosol tracers point towards wind-blown soil as an important source of bioaerosols in urban areas.

Water Quality Planning in Rivers: Assimilative Capacity and Dilution Flow.

PubMed

Hashemi Monfared, Seyed Arman; Dehghani Darmian, Mohsen; Snyder, Shane A; Azizyan, Gholamreza; Pirzadeh, Bahareh; Azhdary Moghaddam, Mehdi

2017-11-01

Population growth, urbanization and industrial expansion are consequentially linked to increasing pollution around the world. The sources of pollution are so vast and also include point and nonpoint sources, with intrinsic challenge for control and abatement. This paper focuses on pollutant concentrations and also the distance that the pollution is in contact with the river water as objective functions to determine two main necessary characteristics for water quality management in the river. These two necessary characteristics are named assimilative capacity and dilution flow. The mean area of unacceptable concentration [Formula: see text] and affected distance (X) are considered as two objective functions to determine the dilution flow by a non-dominated sorting genetic algorithm II (NSGA-II) optimization algorithm. The results demonstrate that the variation of river flow discharge in different seasons can modify the assimilation capacity up to 97%. Moreover, when using dilution flow as a water quality management tool, results reveal that the content of [Formula: see text] and X change up to 97% and 93%, respectively.

Urban atmospheric pollution in the Eastern Mediterranean : lessons from the TRANSEMED initiative

NASA Astrophysics Data System (ADS)

Borbon, Agnes; Salameh, Therese; Gaimoz, Cecile; Sauvage, Stephane; Locoge, Nadine; Oztürk, Fatma; Cetin, Banu; Keles, Melek; Afif, Charbel

2016-04-01

The East Mediterranean Basin (EMB) is a highly sensitive environment under considerable pressures. Future decadal projections point to the EMB as a possible hot spot of poor air quality and predict a continual and gradual warming in the region, much stronger than other regions. The increase and accumulation of anthropogenic emissions of gaseous and particulate pollutants from surrounding urban areas, are suspected as one of the key compounding factors of those environmental impacts. The quantification of emission distribution is a challenge, and even more in cities of the EMB where local emission data are sparse. While some highly resolved inventories have been developed at the regional scale in the EMB area for Beirut and Istanbul, their uncertainties are unknown. The paucity of observations in this region, especially for VOCs and PM composition, is a strong limitation to the achievement of evaluated and accurate emission inventories. As part of the TRANSEMED initiative (https://charmex.lsce.ipsl.fr/index.php/sister-projects/transemed.html), one of our objectives is to develop a systematic source-receptor methodology for emission inventory evaluation. We combine existing and newly collected observations and complementary source-receptor approaches (ie., urban enhancement emission ratios, multivariate models like PMF) in representative areas of the EMB: Beirut (Lebanon), Istanbul (Turkey), Cairo (Egypt) and, more recently, Athens (Greece). Over the past five years a very detailed database of ambient and near-source observations has been built-up especially regarding the composition of gaseous organic carbon. Results show (i) the extremely high levels of pollution for organics, (ii) the dominance of traffic emissions on VOC concentration levels, (iii) the relative poor spatial variability of speciated hydrocarbon traffic emissions regardless of the region, and (iv) the high uncertainty on global emission inventories when compared to observations. For the latter, and from a global perspective, the relative importance of Eastern Mediterranean emissions is suspected to be largely underestimated compared to other regions worldwide: they could be as significant for VOC and NOx as the ones of Europe and North America or even higher for PM2.5. This work was supported by the ENVIMED and ChArMEx programmes within MISTRALS. The author would like to thank Thierry Leonardis for his technical support. References: Borbon et al., Composition of gaseous organic carbon during ECOCEM in Beirut, Lebanon: new observational constraints for VOC/OVOC anthropogenic emission evaluation in the Middle East region. In preparation for ACP. Salameh et al., Source apportionment vs. emission inventories of non-methane hydrocarbons (NMHC) in an urban area of the Middle East: local and global perspectives, in revision for ACP, 2016. http://www.atmos-chem-phys-discuss.net/15/26795/2015/acpd-15-26795-2015.html Salameh et al., Exploring the seasonal NMHC distribution in an urban area of the Middle East during ECOCEM campaigns: very high loadings dominated by local emissions and dynamics. Environ. Chem. 12 (3), 316 - 328. doi : 10.1071/EN14154, 2015. Salameh et al., Speciation of Non-Methane Hydrocarbons (NMHC) from anthropogenic sources in Beirut, Lebanon, Environ Sci. Pollut. Res., 21, 10867 - 10877. DOI: 10.1007/s11356-014-2978-5, 2014.

Social care and support for elderly men and women in an urban and a rural area of Nepal.

PubMed

Kshetri, Dan Bahadur Baidwar; Smith, Cairns S; Khadka, Mira

2012-09-01

This study has aimed to describe the care and support for urban and rural elderly people of Bhaktapur district, Nepal. Efforts were made to identify the feeling of some features of general well-beings associated to mental health, person responsible for care and support, capability to perform daily routine activities, sources of finance and ownership to the property. More than half of the respondents were found having single or multiple features of loneliness, anxiety, depression and insomnia. The rate of point prevalence loneliness was found higher in the above 80 years of age, urban respondents. Almost 9 in 10 respondents were capable themselves to dress, walk and maintain personal hygiene and majority of them were assisted by spouse, son/daughter-in-laws. Family support was common sources of income and ownership to the property was absolutely high.

A Meta-Analysis of Urban Climate Change Adaptation ...

EPA Pesticide Factsheets

The concentration of people, infrastructure, and ecosystem services in urban areas make them prime sites for climate change adaptation. While advances have been made in developing frameworks for adaptation planning and identifying both real and potential barriers to action, empirical work evaluating urban adaptation planning processes has been relatively piecemeal. Existing assessments of current experience with urban adaptation provide necessarily broad generalizations based on the available peer-reviewed literature. This paper uses a meta-analysis of U.S. cities’ current experience with urban adaptation planning drawing from 54 sources that include peer-reviewed literature, government reports, white papers, and reports published by non-governmental organizations. The analysis specifically evaluates the institutional support structures being developed for urban climate change adaptation. The results demonstrate that adaptation planning is driven by a desire to reduce vulnerability and often catalyzes new collaborations and coordination mechanisms in urban governance. As a result, building capacity for urban climate change adaptation planning requires a focus not only on city governments themselves but also on the complex horizontal and vertical networks that have arisen around such efforts. Existing adaptation planning often lacks attention to equity issues, social vulnerability, and the influence of non-climatic factors on vulnerability. Engaging city govern

Gaseous pollutants on rural and urban nursery schools in Northern Portugal.

PubMed

Nunes, R A O; Branco, P T B S; Alvim-Ferraz, M C M; Martins, F G; Sousa, S I V

2016-01-01

Indoor air quality in nursery schools is different from other schools and this has been largely ignored, particularly in rural areas. Urban and rural nursery schools have different environmental characteristics whose knowledge needs improvement. Thus, this study aimed to evaluate continuously the concentrations of CO2, CO, NO2, O3, CH2O and total VOC in three rural nursery schools and one urban, being the only one comparing urban and rural nurseries with continuous measurements, thus considering occupation and non-occupation periods. Regarding CO2, urban nursery recorded higher concentrations (739-2328 mg m(-3)) than rural nurseries (653-1078 mg m(-3)). The influence of outdoor air was the main source of CO, NO2 and O3 indoor concentrations. CO and NO2 concentrations were higher in the urban nursery and O3 concentrations were higher in rural ones. CH2O and TVOC concentrations seemed to be related to internal sources, such as furniture and flooring finishing and cleaning products. Copyright © 2015 Elsevier Ltd. All rights reserved.

Assessment of Concentrations of Heavy Metals and Phthalates in Two Urban Rivers of the Northeast of Puerto Rico

PubMed Central

Ortiz-Colón, Ana I; Piñero-Santiago, Luis E; Rivera, Nilsa M; Sosa, María A

2016-01-01

Urbanization adjacent to rivers has increased in recent years and is considered a source of environmental contamination. The resulting increase in number of urban rivers in highly populated areas, such as the Caribbean island of Puerto Rico, has led to the appearance of synthetic as well as naturally occurring chemicals not previously observed nor regularly monitored in freshwater habitats. Some of these chemicals, such as heavy metals and plasticizers, have been shown to affect endocrine, respiratory, and nervous system function in animals and humans, even at relatively low concentrations. The purpose of this study was to measure concentrations of such emergent contaminants on rivers of urbanized areas on the northeast of Puerto Rico, as one element in the assessment of the impact of urbanism on water quality in these communities. To accomplish this, we used Inductively Coupled Plasma and Gas Chromatography Mass Spectrometry to measure amounts of heavy metals and phthalates, respectively, in superficial water of three rivers of Puerto Rico: Mameyes (non-urban), Río Piedras (urban river without a dam), and La Plata (urban river with a dam). The urban rivers had significantly higher concentrations of heavy metals arsenic, barium, cadmium, manganese, and antimony, when compared with the reference non-urban river. Manganese was the only metal found in concentrations higher than limits established by the EPA for drinking water. Of eight phthalates amenable to measurement with the chosen protocol and instrumentation, only dibutyl phthalate was detected, only in the La Plata river, and at concentrations ranging from 3 to 8 parts-per-billion. These findings suggest that urbanism close to rivers of Puerto Rico is likely having an impact on water quality and thus further study to identify the potential sources, as well as the inclusion of these emergent contaminants on the list of chemicals regularly monitored by government agencies is justified. PMID:27148470

Assessment of Concentrations of Heavy Metals and Phthalates in Two Urban Rivers of the Northeast of Puerto Rico.

PubMed

Ortiz-Colón, Ana I; Piñero-Santiago, Luis E; Rivera, Nilsa M; Sosa, María A

2016-03-20

Urbanization adjacent to rivers has increased in recent years and is considered a source of environmental contamination. The resulting increase in number of urban rivers in highly populated areas, such as the Caribbean island of Puerto Rico, has led to the appearance of synthetic as well as naturally occurring chemicals not previously observed nor regularly monitored in freshwater habitats. Some of these chemicals, such as heavy metals and plasticizers, have been shown to affect endocrine, respiratory, and nervous system function in animals and humans, even at relatively low concentrations. The purpose of this study was to measure concentrations of such emergent contaminants on rivers of urbanized areas on the northeast of Puerto Rico, as one element in the assessment of the impact of urbanism on water quality in these communities. To accomplish this, we used Inductively Coupled Plasma and Gas Chromatography Mass Spectrometry to measure amounts of heavy metals and phthalates, respectively, in superficial water of three rivers of Puerto Rico: Mameyes (non-urban), Río Piedras (urban river without a dam), and La Plata (urban river with a dam). The urban rivers had significantly higher concentrations of heavy metals arsenic, barium, cadmium, manganese, and antimony, when compared with the reference non-urban river. Manganese was the only metal found in concentrations higher than limits established by the EPA for drinking water. Of eight phthalates amenable to measurement with the chosen protocol and instrumentation, only dibutyl phthalate was detected, only in the La Plata river, and at concentrations ranging from 3 to 8 parts-per-billion. These findings suggest that urbanism close to rivers of Puerto Rico is likely having an impact on water quality and thus further study to identify the potential sources, as well as the inclusion of these emergent contaminants on the list of chemicals regularly monitored by government agencies is justified.

Evaluation of the AnnAGNPS model for predicting runoff and sediment yield in a small Mediterranean agricultural watershed in Navarre (Spain)

USDA-ARS?s Scientific Manuscript database

AnnAGNPS (Annualized Agricultural Non-Point Source Pollution Model) is a system of computer models developed to predict non-point source pollutant loadings within agricultural watersheds. It contains a daily time step distributed parameter continuous simulation surface runoff model designed to assis...

Relative impact of on-road vehicular and point-source industrial emissions of air pollutants in a medium-sized Andean city

NASA Astrophysics Data System (ADS)

González, C. M.; Gómez, C. D.; Rojas, N. Y.; Acevedo, H.; Aristizábal, B. H.

2017-03-01

Cities in emerging countries are facing a fast growth and urbanization; however, the study of air pollutant emissions and its dynamics is scarce, making their populations vulnerable to potential effects of air pollution. This situation is critical in medium-sized urban areas built along the tropical Andean mountains. This work assesses the contribution of on-road vehicular and point-source industrial activities in the medium-sized Andean city of Manizales, Colombia. Annual fluxes of criteria pollutants, NMVOC, and greenhouse gases were estimated. Emissions were dominated by vehicular activity, with more than 90% of total estimated releases for the majority of air pollutants. On-road vehicular emissions for CO (43.4 Gg/yr) and NMVOC (9.6 Gg/yr) were mainly associated with the use of motorcycles (50% and 81% of total CO and NMVOC emissions respectively). Public transit buses were the main source of PM10 (47%) and NOx (48%). The per-capita emission index was significantly higher in Manizales than in other medium-sized cities, especially for NMVOC, CO, NOx and CO2. The unique mountainous terrain of Andean cities suggest that a methodology based on VSP model could give more realistic emission estimates, with additional model components that include slope and acceleration. Food and beverage facilities were the main contributors of point-source industrial emissions for PM10 (63%), SOx (55%) and NOx (45%), whereas scrap metal recycling had high emissions of CO (73%) and NMVOC (47%). Results provide the baseline for ongoing research in atmospheric modeling and urban air quality, in order to improve the understanding of air pollutant fluxes, transport and transformation in the atmosphere. In addition, this emission inventory could be used as a tool to identify areas of public health exposure and provide information for future decision makers.

AN APPROACH TO WATER RESOURCES EVALUATION OF NON-POINT SILVICULTURAL SOURCES (A PROCEDURAL HANDBOOK)

EPA Science Inventory

This handbook provides an analysis methodology that can be used to describe and evaluate changes to the water resource resulting from non-point silvicultural activities. This state-of-the-art approach for analysis and prediction of pollution from non point silvicultural activitie...

Assessment of uncertainties of an aircraft-based mass balance approach for quantifying urban greenhouse gas emissions

NASA Astrophysics Data System (ADS)

Cambaliza, M. O. L.; Shepson, P. B.; Caulton, D. R.; Stirm, B.; Samarov, D.; Gurney, K. R.; Turnbull, J.; Davis, K. J.; Possolo, A.; Karion, A.; Sweeney, C.; Moser, B.; Hendricks, A.; Lauvaux, T.; Mays, K.; Whetstone, J.; Huang, J.; Razlivanov, I.; Miles, N. L.; Richardson, S. J.

2014-09-01

Urban environments are the primary contributors to global anthropogenic carbon emissions. Because much of the growth in CO2 emissions will originate from cities, there is a need to develop, assess, and improve measurement and modeling strategies for quantifying and monitoring greenhouse gas emissions from large urban centers. In this study the uncertainties in an aircraft-based mass balance approach for quantifying carbon dioxide and methane emissions from an urban environment, focusing on Indianapolis, IN, USA, are described. The relatively level terrain of Indianapolis facilitated the application of mean wind fields in the mass balance approach. We investigate the uncertainties in our aircraft-based mass balance approach by (1) assessing the sensitivity of the measured flux to important measurement and analysis parameters including wind speed, background CO2 and CH4, boundary layer depth, and interpolation technique, and (2) determining the flux at two or more downwind distances from a point or area source (with relatively large source strengths such as solid waste facilities and a power generating station) in rapid succession, assuming that the emission flux is constant. When we quantify the precision in the approach by comparing the estimated emissions derived from measurements at two or more downwind distances from an area or point source, we find that the minimum and maximum repeatability were 12 and 52%, with an average of 31%. We suggest that improvements in the experimental design can be achieved by careful determination of the background concentration, monitoring the evolution of the boundary layer through the measurement period, and increasing the number of downwind horizontal transect measurements at multiple altitudes within the boundary layer.

An optimized inverse modelling method for determining the location and strength of a point source releasing airborne material in urban environment

NASA Astrophysics Data System (ADS)

Efthimiou, George C.; Kovalets, Ivan V.; Venetsanos, Alexandros; Andronopoulos, Spyros; Argyropoulos, Christos D.; Kakosimos, Konstantinos

2017-12-01

An improved inverse modelling method to estimate the location and the emission rate of an unknown point stationary source of passive atmospheric pollutant in a complex urban geometry is incorporated in the Computational Fluid Dynamics code ADREA-HF and presented in this paper. The key improvement in relation to the previous version of the method lies in a two-step segregated approach. At first only the source coordinates are analysed using a correlation function of measured and calculated concentrations. In the second step the source rate is identified by minimizing a quadratic cost function. The validation of the new algorithm is performed by simulating the MUST wind tunnel experiment. A grid-independent flow field solution is firstly attained by applying successive refinements of the computational mesh and the final wind flow is validated against the measurements quantitatively and qualitatively. The old and new versions of the source term estimation method are tested on a coarse and a fine mesh. The new method appeared to be more robust, giving satisfactory estimations of source location and emission rate on both grids. The performance of the old version of the method varied between failure and success and appeared to be sensitive to the selection of model error magnitude that needs to be inserted in its quadratic cost function. The performance of the method depends also on the number and the placement of sensors constituting the measurement network. Of significant interest for the practical application of the method in urban settings is the number of concentration sensors required to obtain a ;satisfactory; determination of the source. The probability of obtaining a satisfactory solution - according to specified criteria -by the new method has been assessed as function of the number of sensors that constitute the measurement network.

Fine Aerosol Associated Non-Polar Organics in Jammu, AN Urban Location in the Foothill Region of North Western Himalayas

NASA Astrophysics Data System (ADS)

Yadav, S.; Bamotra, S.

2017-12-01

A comprehensive study was done on the mass, composition and sources of fine aerosol associated non-polar organics in Jammu, an urban location in the foothill region of North - Western Himalayas. Systematic multi-scale sampling was done from October, 2015 to February, 2017 to collect fine aerosol (PM2.5) samples every week using a Fine Particulate Sampler (Envirotech, APM 550 MFC) which operates at a constant flow rate of 16.7 L/minute. The Non- polar organic compounds comprising of n-alkanes, PAHs, isoprenoid hydrocarbons and nicotine were analyzed using Thermal desorption Gas Chromatography Mass Spectrometry (TD-GC-MS) method. The n-alkane associated diagnostic parameters include—mass weighted Averaged Chain Length (ACL); Carbon number with maximum concentration (Cmax); Petroleum derived n-alkanes (PNA%), Carbon Preference Index (CPI) and the percentage contribution of Wax n-alkanes from plants (WNA%). These diagnostic parameters along with PAH based molecular ratios were used to understand the diurnal and seasonal variations in different biogenic and petrogenic source contributions in this part of Himalayas. The presence of source specific tracers like Levoglucosan, Retene, Isoquinoline and nicotine also corroborated our findings. Further Fine aerosols associated Black Carbon, an important marker for burning was determined using Optical Transmissometer. Significant multiscale variations were found in the Fine aerosol load, associated Non-polar organics, source tracers/contributions and Black Carbon.

The Segmentation of Point Clouds with K-Means and ANN (artifical Neural Network)

NASA Astrophysics Data System (ADS)

Kuçak, R. A.; Özdemir, E.; Erol, S.

2017-05-01

Segmentation of point clouds is recently used in many Geomatics Engineering applications such as the building extraction in urban areas, Digital Terrain Model (DTM) generation and the road or urban furniture extraction. Segmentation is a process of dividing point clouds according to their special characteristic layers. The present paper discusses K-means and self-organizing map (SOM) which is a type of ANN (Artificial Neural Network) segmentation algorithm which treats the segmentation of point cloud. The point clouds which generate with photogrammetric method and Terrestrial Lidar System (TLS) were segmented according to surface normal, intensity and curvature. Thus, the results were evaluated. LIDAR (Light Detection and Ranging) and Photogrammetry are commonly used to obtain point clouds in many remote sensing and geodesy applications. By photogrammetric method or LIDAR method, it is possible to obtain point cloud from terrestrial or airborne systems. In this study, the measurements were made with a Leica C10 laser scanner in LIDAR method. In photogrammetric method, the point cloud was obtained from photographs taken from the ground with a 13 MP non-metric camera.

Assessment of the environmental significance of nutrients and heavy metal pollution in the river network of Serbia.

PubMed

Dević, Gordana; Sakan, Sanja; Đorđević, Dragana

2016-01-01

In this paper, the data for ten water quality variables collected during 2009 at 75 monitoring sites along the river network of Serbia are considered. The results are alarming because 48% of the studied sites were contaminated by Ni, Mn, Pb, As, and nutrients, which are key factors impairing the water quality of the rivers in Serbia. Special attention should be paid to Zn and Cu, listed in the priority toxic pollutants of US EPA for aquatic life protection. The employed Q-model cluster analysis grouped the data into three major pollution zones (low, moderate, and high). Most sites classified as "low pollution zones" (LP) were in the main rivers, whereas those classified as "moderate and high pollution zones" (MP and HP, respectively) were in the large and small tributaries/hydro-system. Principal component analysis/factor analysis (PCA/FA) showed that the dissolved metals and nutrients in the Serbian rivers varied depending on the river, the heterogeneity of the anthropogenic activities in the basins (influenced primarily by industrial wastewater, agricultural activities, and urban runoff pollution), and natural environmental variability, such as geological characteristics. In LP dominated non-point source pollution, such as agricultural and urban runoff, whereas mixed source pollution dominated in the MP and HP zones. These results provide information to be used for developing better pollution control strategies for the river network of Serbia.

Coal-tar based pavement sealant toxicity to freshwater macroinvertebrates.

PubMed

Bryer, Pamela J; Scoggins, Mateo; McClintock, Nancy L

2010-05-01

Non-point-source pollution is a major source of ecological impairment in urban stream systems. Recent work suggests that coal-tar pavement sealants, used extensively to protect parking areas, may be contributing a large portion of the polycyclic aromatic hydrocarbon (PAH) loading seen in urban stream sediments. The hypothesis that dried coal-tar pavement sealant flake could alter the macroinvertebrate communities native to streams in Austin, TX was tested using a controlled outdoor laboratory type approach. The treatment groups were: control, low, medium, and high with total PAH concentrations (TPAH = sum of 16 EPA priority pollutant PAHs) of 0.1, 7.5, 18.4, & 300 mg/kg respectively. The low, medium, and high treatments were created via the addition of dried coal-tar pavement sealant to a sterile soil. At the start of the 24-day exposure, sediment from a minimally impacted local reference site containing a community of live sediment-dwelling benthic macroinvertebrates was added to each replicate. An exposure-dependent response was found for several stream health measures and for several individual taxa. There were community differences in abundance (P = 0.0004) and richness (P < 0.0001) between treatments in addition to specific taxa responses, displaying a clear negative relationship with the amount of coal-tar sealant flake. These results support the hypothesis that coal-tar pavement sealants contain bioavailable PAHs that may harm aquatic environments. Copyright 2009 Elsevier Ltd. All rights reserved.

Deformation Estimation In Non-Urban Areas Exploiting High Resolution SAR Data

NASA Astrophysics Data System (ADS)

Goel, Kanika; Adam, Nico

2012-01-01

Advanced techniques such as the Small Baseline Subset Algorithm (SBAS) have been developed for terrain motion mapping in non-urban areas with a focus on extracting information from distributed scatterers (DSs). SBAS uses small baseline differential interferograms (to limit the effects of geometric decorrelation) and these are typically multilooked to reduce phase noise, resulting in loss of resolution. Various error sources e.g. phase unwrapping errors, topographic errors, temporal decorrelation and atmospheric effects also affect the interferometric phase. The aim of our work is an improved deformation monitoring in non-urban areas exploiting high resolution SAR data. The paper provides technical details and a processing example of a newly developed technique which incorporates an adaptive spatial phase filtering algorithm for an accurate high resolution differential interferometric stacking, followed by deformation retrieval via the SBAS approach where we perform the phase inversion using a more robust L1 norm minimization.

Occurrence and ecological risk assessment of emerging organic chemicals in urban rivers: Guangzhou as a case study in China.

PubMed

Peng, Feng-Jiao; Pan, Chang-Gui; Zhang, Min; Zhang, Nai-Sheng; Windfeld, Ronja; Salvito, Daniel; Selck, Henriette; Van den Brink, Paul J; Ying, Guang-Guo

2017-07-01

Urban rivers may receive contamination from various sources including point sources like domestic sewage and nonpoint sources (e.g., runoff), resulting in contamination with various chemicals. This study investigated the occurrence of emerging organic contaminants (3 endocrine disrupting compounds (EDCs), and 17 pharmaceuticals and personal care products (PPCPs)) in six urban rivers of a representative subtropical city, Guangzhou (southern China). Our results showed that EDCs and personal care products were frequently detected in the water phase and sediment phase. 4-nonylphenol (4-NP) was the most predominant compound with the highest concentration of 5050ng/L in the water phase and 14,400ng/g dry weight (dw) in the sediment. Generally, higher total concentrations of EDCs and PPCPs were detected in the four urban streams compared to the main stream Zhujiang River and the Liuxi River at the suburb area. A screening-level risk assessment showed that 4-nonylphenol and triclosan (TCS) pose potential risks to aquatic organisms in most sampling sites. For individual taxa, 4-NP may pose risks to various groups of aquatic organisms, while TCS only might pose high risks to algae. Higher contamination of EDCs and PPCPs was observed in rivers in urban area; 4-nonylphenol and triclosan showed RQs>1 in >70% of the reported area. Copyright © 2017 Elsevier B.V. All rights reserved.

Inverse identification of unknown finite-duration air pollutant release from a point source in urban environment

NASA Astrophysics Data System (ADS)

Kovalets, Ivan V.; Efthimiou, George C.; Andronopoulos, Spyros; Venetsanos, Alexander G.; Argyropoulos, Christos D.; Kakosimos, Konstantinos E.

2018-05-01

In this work, we present an inverse computational method for the identification of the location, start time, duration and quantity of emitted substance of an unknown air pollution source of finite time duration in an urban environment. We considered a problem of transient pollutant dispersion under stationary meteorological fields, which is a reasonable assumption for the assimilation of available concentration measurements within 1 h from the start of an incident. We optimized the calculation of the source-receptor function by developing a method which requires integrating as many backward adjoint equations as the available measurement stations. This resulted in high numerical efficiency of the method. The source parameters are computed by maximizing the correlation function of the simulated and observed concentrations. The method has been integrated into the CFD code ADREA-HF and it has been tested successfully by performing a series of source inversion runs using the data of 200 individual realizations of puff releases, previously generated in a wind tunnel experiment.

Microbial Source Module (MSM): Documenting the Science and Software for Discovery, Evaluation, and Integration

EPA Science Inventory

The Microbial Source Module (MSM) estimates microbial loading rates to land surfaces from non-point sources, and to streams from point sources for each subwatershed within a watershed. A subwatershed, the smallest modeling unit, represents the common basis for information consume...

Study on the quantitative relationship between Agricultural water and fertilization process and non-point source pollution based on field experiments

NASA Astrophysics Data System (ADS)

Wang, H.; Chen, K.; Wu, Z.; Guan, X.

2017-12-01

In recent years, with the prominent of water environment problem and the relative increase of point source pollution governance, especially the agricultural non-point source pollution problem caused by the extensive use of fertilizers and pesticides has become increasingly aroused people's concern and attention. In order to reveal the quantitative relationship between agriculture water and fertilizer and non-point source pollution, on the basis of elm field experiment and combined with agricultural drainage irrigation model, the agricultural irrigation water and the relationship between fertilizer and fertilization scheme and non-point source pollution were analyzed and calculated by field emission intensity index. The results show that the variation of displacement varies greatly under different irrigation conditions. When the irrigation water increased from 22cm to 42cm, the irrigation water increased by 20 cm while the field displacement increased by 11.92 cm, about 66.22% of the added value of irrigation water. Then the irrigation water increased from 42 to 68, irrigation water increased 26 cm, and the field displacement increased by 22.48 cm, accounting for 86.46% of irrigation water. So there is an "inflection point" between the irrigation water amount and field displacement amount. The load intensity increases with the increase of irrigation water and shows a significant power correlation. Under the different irrigation condition, the increase amplitude of load intensity with the increase of irrigation water is different. When the irrigation water is smaller, the load intensity increase relatively less, and when the irrigation water increased to about 42 cm, the load intensity will increase considerably. In addition, there was a positive correlation between the fertilization and load intensity. The load intensity had obvious difference in different fertilization modes even with same fertilization level, in which the fertilizer field unit load intensity increased the most in July. The results provide some basis for the field control and management of agricultural non-point source pollution.

Putting Man in the Machine: Exploiting Expertise to Enhance Multiobjective Design of Water Supply Monitoring Network

NASA Astrophysics Data System (ADS)

Bode, F.; Nowak, W.; Reed, P. M.; Reuschen, S.

2016-12-01

Drinking-water well catchments need effective early-warning monitoring networks. Groundwater water supply wells in complex urban environments are in close proximity to a myriad of potential industrial pollutant sources that could irreversibly damage their source aquifers. These urban environments pose fiscal and physical challenges to designing monitoring networks. Ideal early-warning monitoring networks would satisfy three objectives: to detect (1) all potential contaminations within the catchment (2) as early as possible before they reach the pumping wells, (3) while minimizing costs. Obviously, the ideal case is nonexistent, so we search for tradeoffs using multiobjective optimization. The challenge of this optimization problem is the high number of potential monitoring-well positions (the search space) and the non-linearity of the underlying groundwater flow-and-transport problem. This study evaluates (1) different ways to effectively restrict the search space in an efficient way, with and without expert knowledge, (2) different methods to represent the search space during the optimization and (3) the influence of incremental increases in uncertainty in the system. Conductivity, regional flow direction and potential source locations are explored as key uncertainties. We show the need and the benefit of our methods by comparing optimized monitoring networks for different uncertainty levels with networks that seek to effectively exploit expert knowledge. The study's main contributions are the different approaches restricting and representing the search space. The restriction algorithms are based on a point-wise comparison of decision elements of the search space. The representation of the search space can be either binary or continuous. For both cases, the search space must be adjusted properly. Our results show the benefits and drawbacks of binary versus continuous search space representations and the high potential of automated search space restriction algorithms for high-dimensional, highly non-linear optimization problems.

[Association analysis between urbanization and non-communicable diseases and health-related behavior].

PubMed

Liu, G F; Sun, M P; Wang, Z Y; Jian, W Y

2016-06-18

To explore the association between different urbanization levels and non-communicable diseases (NCDs) in China and provide suggestions on designing relevant health policies in the urbanization process. We obtained health-related data from China Health and Retirement Longitudinal Study (CHARLS) 2011. This study used multistage sampling in design stage and covered 150 districts/counties, representative at the levels of the country. Geo-information system (GIS) method was used to get district areas data, and in combination with the Sixth National Census population data, we computed the population density which was regarded as the proxy variable of urbanization level in every city. The Logistic model was used to explore the effect of urbanization level on hypertension, diabetes, smoking, drinking, overweight and obesity. Compared with other cities in China, Shanghai and Shenzhen, with the population density of more than 3 000 people per km(2), were the cities with highest urbanization level. From the map of urbanization distribution across China, it was found that the urbanization levels of the northwestern districts were lower than those of the southeastern and coastal districts. The hypertension rate increased with the development of urbanization but there was no statistical significance. The proportion of patients with diabetes went up first and then saw a decrease trend in the process of urbanization. Drinking rate, overweight rate and obesity rate had similar trends, falling to their lowest point when urbanization level equaled 737,1 186 and 1 353 people per km(2) respectively and then experienced upward trends. By contrast, smoking rate declined first and then went up (the turning point was 1 029 people per km(2)). Different urbanization levels have different effects on NCDs, health-related behavior, overweight and obesity. Low urbanization level may create negative impact on health while high level can pose positive effect and increase people's health condition possibly due to the improvement of health care accessibility and the quality of living environment. Policy-makers should specially focus on different residents'health problems in different periods of urbanization, such as the impact of environmental pollution, health resources' allocation and accessibility of health services. It is necessary to reduce or avoid the negative effect of urbanization on NCDs during the local development process to face the NCDs' threat.

Mineral Adsorbents for Removal of Metals in Urban Runoff

NASA Astrophysics Data System (ADS)

Bjorklund, Karin; Li, Loretta

2014-05-01

The aim of this research was to determine the capacity of four different soil minerals to adsorb metals frequently detected in urban runoff. These are low-cost, natural and commercially available soil minerals. Contaminated surface runoff from urban areas is a major cause of concern for water quality and aquatic ecosystems worldwide. Pollution in urban areas is generated by a wide array of non-point sources, including vehicular transportation and building materials. Some of the most frequently detected pollutants in urban runoff are metals. Exhaust gases, tire wear and brake linings are major sources of such metals as Pb, Zn and Cu, while impregnated wood, plastics and galvanized surfaces may release As, Cd, Cr and Zn. Many metals have toxic effects on aquatic plants and animals, depending on metal speciation and bioavailability. The removal efficiency of pollutants in stormwater depends on treatment practices and on the properties the pollutant. The distribution of metals in urban runoff has shown, for example, that Pb is predominantly particle-associated, whereas Zn and Cd are present mainly in dissolved form. Many metals are also attached to colloids, which may act as carriers for contaminants, thereby facilitating their transport through conventional water treatment processes. Filtration of stormwater is one of the most promising techniques for removal of particulates, colloidal and truly dissolved pollutants, provided that effective filtration and adsorption media are used. Filtration and infiltration are used in a wide array of stormwater treatment methods e.g. porous paving, infiltration drains and rain gardens. Several soil minerals were investigated for their potential as stormwater filter materials. Laboratory batch tests were conducted to determine the adsorption capacity of these minerals. A synthetic stormwater was tested, with spiked concentrations corresponding to levels reported in urban runoff, ranging from 50-1,500 µg/L for Zn; 5-250 µg/L for Cu, 2-20 µg/L for Cd and 10-150 µg/L for Ni and Pb. Humic acids were used to imitate natural stormwater contaminated with natural organic matter. The adsorption kinetics was also investigated through a sequence (10-120 min) of batch tests. By studying the capacity of a range of sorbents in batch tests under identical conditions, the most promising sorbent can be identified. The research is ongoing. Preliminary results will be presented.

40 CFR 430.127 - Pretreatment standards for new sources (PSNS).

Code of Federal Regulations, 2010 CFR

2010-07-01

...) EFFLUENT GUIDELINES AND STANDARDS THE PULP, PAPER, AND PAPERBOARD POINT SOURCE CATEGORY Tissue, Filter, Non.... Subpart L [PSNS for non-integrated mills where filter and non-woven papers are produced from purchased...

40 CFR 430.127 - Pretreatment standards for new sources (PSNS).

Code of Federal Regulations, 2011 CFR

2011-07-01

...) EFFLUENT GUIDELINES AND STANDARDS THE PULP, PAPER, AND PAPERBOARD POINT SOURCE CATEGORY Tissue, Filter, Non.... Subpart L [PSNS for non-integrated mills where filter and non-woven papers are produced from purchased...

Isotopic evidence for enhanced fossil fuel sources of aerosol ammonium in the urban atmosphere.

PubMed

Pan, Yuepeng; Tian, Shili; Liu, Dongwei; Fang, Yunting; Zhu, Xiaying; Gao, Meng; Gao, Jian; Michalski, Greg; Wang, Yuesi

2018-07-01

The sources of aerosol ammonium (NH 4 + ) are of interest because of the potential of NH 4 + to impact the Earth's radiative balance, as well as human health and biological diversity. Isotopic source apportionment of aerosol NH 4 + is challenging in the urban atmosphere, which has excess ammonia (NH 3 ) and where nitrogen isotopic fractionation commonly occurs. Based on year-round isotopic measurements in urban Beijing, we show the source dependence of the isotopic abundance of aerosol NH 4 + , with isotopically light (-33.8‰) and heavy (0 to +12.0‰) NH 4 + associated with strong northerly winds and sustained southerly winds, respectively. On an annual basis, 37-52% of the initial NH 3 concentrations in urban Beijing arises from fossil fuel emissions, which are episodically enhanced by air mass stagnation preceding the passage of cold fronts. These results provide strong evidence for the contribution of non-agricultural sources to NH 3 in urban regions and suggest that priority should be given to controlling these emissions for haze regulation. This study presents a carefully executed application of existing stable nitrogen isotope measurement and mass-balance techniques to a very important problem: understanding source contributions to atmospheric NH 3 in Beijing. This question is crucial to informing environmental policy on reducing particulate matter concentrations, which are some of the highest in the world. However, the isotopic source attribution results presented here still involve a number of uncertain assumptions and they are limited by the incomplete set of chemical and isotopic measurements of gas NH 3 and aerosol NH 4 + . Further field work and lab experiments are required to adequately characterize endmember isotopic signatures and the subsequent isotopic fractionation process under different air pollution and meteorological conditions. Copyright © 2018 Elsevier Ltd. All rights reserved.

Multi-Sourced Satellite Observations of Land Cover and Land Use Change in South and Southeast Asia with Challenging Environmental and Socioeconomic Impacts

NASA Astrophysics Data System (ADS)

Nghiem, S. V.; Small, C.; Jacobson, M. Z.; Brakenridge, G. R.; Balk, D.; Sorichetta, A.; Masetti, M.; Gaughan, A. E.; Stevens, F. R.; Mathews, A.; Frazier, A. E.; Das, N. N.

2017-12-01

An innovative paradigm to observe the rural-urban transformation over the landscape using multi-sourced satellite data is formulated as a time and space continuum, extensively in space across South and Southeast Asia and in time over a decadal scale. Rather than a disparate array of individual cities and their vicinities in separated areas and in a discontinuous collection of points in time, the time-space continuum paradigm enables significant advances in addressing rural-urban change as a continuous gradient across the landscape from the wilderness to rural to urban areas to study challenging environmental and socioeconomic issues. We use satellite data including QuikSCAT scatterometer, SRTM and Sentinel-1 SAR, Landsat, WorldView, MODIS, and SMAP together with environmental and demographic data and modeling products to investigate land cover and land use change in South and Southeast Asia and associated impacts. Utilizing the new observational advances and effectively capitalizing current capabilities, we will present interdisciplinary results on urbanization in three dimensions, flood and drought, wildfire, air and water pollution, urban change, policy effects, population dynamics and vector-borne disease, agricultural assessment, and land degradation and desertification.

Importance of data comparability for multi-year trends and source apportionment of NMHC concentrations observed in France

NASA Astrophysics Data System (ADS)

Sauvage, Stéphane; Waked, Antoine; Leonardis, Thierry; Locoge, Nadine

2017-04-01

Non Methane Hydrocarbon Compounds (NMHCs) are of interest due to their potential health impact and their key role in atmospheric processes as precursors of secondary pollutants such as ozone (O3) and secondary organic aerosols (SOA). Hourly measurements of 31 non-methane hydrocarbons (NMHCs) were carried out at three urban sites in France over the period of a decade. The trends analysis showed a significant yearly decrease in pollutant concentrations over the study period and for the majority of species in the range of -1 to -7% in accordance with the decrease of NMHC emissions in France (-5 to -9%). Concentrations of long-lived species such as ethane and propane which are known as tracers of distant sources and natural gas remained constant. These trends are consistent with those recently described at urban and background sites in the northern mid-latitudes and with emission inventories. They are compared with the ones reported for 3 French rural sites (EMEP). A year per year source apportionment study using PMF was also conducted for 2 of the urban sites over the period 2005-2013. Using source fingerprints, five common anthropogenic sources were identified for Paris and Strasbourg: traffic-exhaust emissions (21±5%, 18±5%), evaporative sources (17±4%, 24±7%), natural gas & background (22±5%, 25±5%), residential heating (17±4%, 17±5%) and solvent use (19±7%, 12±5%). Biogenic sources were also identified and accounted for 4±1% of the total measured NMHC's at both sites. Along the presentation, the robustness of these results will be discussed regarding the site representativeness, the data comparability, and the temporal variation of the data quality

ASSESSING NON-POINT SOURCES OF NITROGEN TO SMALL STREAMS IN THE SOUTH FORK BROAD RIVER WATERSHED (GEORGIA, USA)

EPA Science Inventory

The National Land Cover Data (NLCD) is a land cover classification derived from Landsat Thematic Mapper satellite data collected in the early to mid-1990s. In this work, land use coverages calculated from the NLCD database are used to assess the impact of non-point sources on the...

Water budget analysis and management for Bangkok Metropolis, Thailand.

PubMed

Singkran, Nuanchan

2017-09-01

The water budget of the Bangkok Metropolis system was analyzed using a material flow analysis model. Total imported flows into the system were 80,080 million m 3 per year (Mm 3 y -1 ) including inflows from the Chao Phraya and Mae Klong rivers and rainwater. Total exported flows out of the system were 78,528 Mm 3 y -1 including outflow into the lower Chao Phraya River and tap water (TW) distributed to suburbs. Total rates of stock exchange (1,552 Mm 3 y -1 ) were found in the processes of water recycling, TW distribution, domestic use, swine farming, aquaculture, and paddy fields. Only 21% of the total amount of wastewater (1,255 Mm 3 y -1 ) was collected, with insufficient treatment capacity of about 415 Mm 3 y -1 . Domestic and business (industrial and commercial sectors) areas were major point sources, whereas paddy fields were a major non-point source of wastewater. To manage Bangkok's water budget, critical measures have to be considered. Wastewater treatment capacity and efficiency of wastewater collection should be improved. On-site wastewater treatment plants for residential areas should be installed. Urban planning and land use zoning are suggested to control land use activities. Green technology should be supported to reduce wastewater from farming.

X-ray Point Source Populations in Spiral and Elliptical Galaxies

NASA Astrophysics Data System (ADS)

Colbert, E.; Heckman, T.; Weaver, K.; Ptak, A.; Strickland, D.

2001-12-01

In the years of the Einstein and ASCA satellites, it was known that the total hard X-ray luminosity from non-AGN galaxies was fairly well correlated with the total blue luminosity. However, the origin of this hard component was not well understood. Some possibilities that were considered included X-ray binaries, extended upscattered far-infrared light via the inverse-Compton process, extended hot 107 K gas (especially in ellipitical galaxies), or even an active nucleus. Now, for the first time, we know from Chandra images that a significant amount of the total hard X-ray emission comes from individual X-ray point sources. We present here spatial and spectral analyses of Chandra data for X-ray point sources in a sample of ~40 galaxies, including both spiral galaxies (starbursts and non-starbursts) and elliptical galaxies. We shall discuss the relationship between the X-ray point source population and the properties of the host galaxies. We show that the slopes of the point-source X-ray luminosity functions are different for different host galaxy types and discuss possible reasons why. We also present detailed X-ray spectral analyses of several of the most luminous X-ray point sources (i.e., IXOs, a.k.a. ULXs), and discuss various scenarios for the origin of the X-ray point sources.

Characterization of coastal urban watershed bacterial communities leads to alternative community-based indicators

DOE Office of Scientific and Technical Information (OSTI.GOV)

Wu, C.H.; Sercu, B.; Van De Werhorst, L.C.

2010-03-01

Microbial communities in aquatic environments are spatially and temporally dynamic due to environmental fluctuations and varied external input sources. A large percentage of the urban watersheds in the United States are affected by fecal pollution, including human pathogens, thus warranting comprehensive monitoring. Using a high-density microarray (PhyloChip), we examined water column bacterial community DNA extracted from two connecting urban watersheds, elucidating variable and stable bacterial subpopulations over a 3-day period and community composition profiles that were distinct to fecal and non-fecal sources. Two approaches were used for indication of fecal influence. The first approach utilized similarity of 503 operational taxonomicmore » units (OTUs) common to all fecal samples analyzed in this study with the watershed samples as an index of fecal pollution. A majority of the 503 OTUs were found in the phyla Firmicutes, Proteobacteria, Bacteroidetes, and Actinobacteria. The second approach incorporated relative richness of 4 bacterial classes (Bacilli, Bacteroidetes, Clostridia and a-proteobacteria) found to have the highest variance in fecal and non-fecal samples. The ratio of these 4 classes (BBC:A) from the watershed samples demonstrated a trend where bacterial communities from gut and sewage sources had higher ratios than from sources not impacted by fecal material. This trend was also observed in the 124 bacterial communities from previously published and unpublished sequencing or PhyloChip- analyzed studies. This study provided a detailed characterization of bacterial community variability during dry weather across a 3-day period in two urban watersheds. The comparative analysis of watershed community composition resulted in alternative community-based indicators that could be useful for assessing ecosystem health.« less

Characterization of Coastal Urban Watershed Bacterial Communities Leads to Alternative Community-Based Indicators

PubMed Central

Wu, Cindy H.; Sercu, Bram; Van De Werfhorst, Laurie C.; Wong, Jakk; DeSantis, Todd Z.; Brodie, Eoin L.; Hazen, Terry C.; Holden, Patricia A.; Andersen, Gary L.

2010-01-01

Background Microbial communities in aquatic environments are spatially and temporally dynamic due to environmental fluctuations and varied external input sources. A large percentage of the urban watersheds in the United States are affected by fecal pollution, including human pathogens, thus warranting comprehensive monitoring. Methodology/Principal Findings Using a high-density microarray (PhyloChip), we examined water column bacterial community DNA extracted from two connecting urban watersheds, elucidating variable and stable bacterial subpopulations over a 3-day period and community composition profiles that were distinct to fecal and non-fecal sources. Two approaches were used for indication of fecal influence. The first approach utilized similarity of 503 operational taxonomic units (OTUs) common to all fecal samples analyzed in this study with the watershed samples as an index of fecal pollution. A majority of the 503 OTUs were found in the phyla Firmicutes, Proteobacteria, Bacteroidetes, and Actinobacteria. The second approach incorporated relative richness of 4 bacterial classes (Bacilli, Bacteroidetes, Clostridia and α-proteobacteria) found to have the highest variance in fecal and non-fecal samples. The ratio of these 4 classes (BBC∶A) from the watershed samples demonstrated a trend where bacterial communities from gut and sewage sources had higher ratios than from sources not impacted by fecal material. This trend was also observed in the 124 bacterial communities from previously published and unpublished sequencing or PhyloChip- analyzed studies. Conclusions/Significance This study provided a detailed characterization of bacterial community variability during dry weather across a 3-day period in two urban watersheds. The comparative analysis of watershed community composition resulted in alternative community-based indicators that could be useful for assessing ecosystem health. PMID:20585654

Hourly elemental concentrations in PM2.5 aerosols sampled simultaneously at urban background and road site

NASA Astrophysics Data System (ADS)

Dall'Osto, M.; Querol, X.; Amato, F.; Karanasiou, A.; Lucarelli, F.; Nava, S.; Calzolai, G.; Chiari, M.

2012-08-01

Hourly-resolved aerosol chemical speciation data can be a highly powerful tool to determine the source origin of atmospheric pollutants in urban Environments. Aerosol mass concentrations of seventeen elements (Na, Mg, Al, S, Cl, K, Ca, Ti, V, Cr, Mn, Fe, Ni, Cu, Zn, Sr and Pb) were obtained by time (1 h) and size (PM2.5 particulate matter <2.5 μm) resolved Particle Induced X-ray Emission (PIXE) measurements. In the Marie Curie FP7-EU framework of SAPUSS (Solving Aerosol Problems by Using Synergistic Strategies), the unique approach used is the simultaneous PIXE measurements at two monitoring sites: urban background (UB) and a street canyon traffic road site (RS). Elements related to primary non exhaust traffic emission (Fe, Cu), dust resuspension (Ca) and anthropogenic Cl were found enhanced at the RS, whereas industrial related trace metals (Zn, Pb, Mn) were found at higher concentrations at the more ventilated UB site. When receptor modelling was performed with positive matrix factorization (PMF), nine different aerosol sources were identified at both sites: three types of regional aerosols (secondary sulphate (S) - 27%, biomass burning (K) - 5%, sea salt (Na-Mg) - 17%), three types of dust aerosols (soil dust (Al-Ti) - 17%, urban crustal dust (Ca) - 6%, and primary traffic non exhaust brake dust (Fe-Cu) - 7%), and three types industrial aerosol plumes-like events (shipping oil combustion (V-Ni) - 17%, industrial smelters (Zn-Mn) - 3%, and industrial combustion (Pb-Cl) - 5%). The validity of the PMF solution of the PIXE data is supported by strong correlations with external single particle mass spectrometry measurements. Beside apportioning the aerosol sources, some important air quality related conclusions can be drawn about the PM2.5 fraction simultaneously measured at the UB and RS sites: (1) the regional aerosol sources impact both monitoring sites at similar concentrations regardless their different ventilation conditions; (2) by contrast, local industrial aerosol plumes associated with shipping oil combustion and smelters activities have a higher impact on the more ventilated UB site; (3) a unique source of Pb-Cl (associated with industrial combustion emissions) is found a to be the major (82%) source of Cl in the urban agglomerate; (4) PM2.5 traffic brake dust (Fe-Cu) is mainly primarily emitted and not resuspended, whereas PM2.5 urban crustal dust (Ca) is found mainly resuspended by both traffic vortex and sea breeze; (5) urban dust (Ca) is found the aerosol source most affected by land wetness, reduced by a factor of eight during rainy days and suggesting that wet roads may be a solution for reducing dust concentrations in road sites, far more effective than street sweeping activities.

BACTERIA SOURCE TRACKING AND HOST SPECIES SPECIFICITY ANALYSIS

EPA Science Inventory

Point and non-point pollution sources of fecal pollution on a watershed adversely impact the quality of drinking source waters and recreational waters. States are required to develop total maximum daily loads (TMDLs) and devise best management practices (BMPs) to reduce the pollu...

Combining MODIS, MISR, CALIOP, OMI, AERONET, and Models to Identify the Spatial and Temporal Distribution, Characterization, and Magnitude of Missing Urban and Wildfire Emissions Sources throughout Asia.

NASA Astrophysics Data System (ADS)

Cohen, J. B.

2016-12-01

Due to intense and changing levels of emissions as well as highly non-linear chemical processing, the concentrations of aerosols and thus their impacts are not well known. Urban areas consist of the majority of the emissions of these species and their precursors over large periods of time, while wildfires contribute very large spikes, concentrated in space and over a period of weeks to months. Yet due to urban and economic expansion, as well as clouds amd low intensity burning, the spatial and temporal profiles of these species are changing, with both new sources appearing and old sources decreasing. New work incorporates measurements at different spatial andboptical resolutions from MODIS, MISR, and OMI, coupled with new sampling approaches with CALIOP and AERONET to search for, characterize, and spatially and temporally constrain aerosols. An advanced modeling system including aerosol chemistry, physics, optics, and transport, using a multi-modal and both externally mixed and core-shell mixing is used to quantify the magnitudes of these missing sources. Comparisons between the model and additional dozens of ground stations show extreme improvement when these new sources are included. This new approach is shown to identify new source regions of emissions, many of which were previously non-urbanized or were not found to contain any fire hotspots. In addition, the use of new models run under conditions including both missing local sources from regions such as the expanded urban areas in Southeast and East Asia and advanced chemical and aerosol routines, allow for a comprehensive analysis to be performed. The impacts of insitu chemistry, horizontal, and vertical transport of species, both on the Regional and Continental scale are also included. It is shown that for proper identification, especially on intra-annual and inter-annual variations, this approach is a large improvement throughout Asia, ranging from India, to Indonesia, to China and Japan. Results specific to Southern China and Southeast East Asia demonstrate the additional importance of the climate, as additional variations are identified. Such knowledge can allow us to better understand the consequences and impacts of the rapid ongoing changes occurring in these regions.

Null-space Monte Carlo particle tracking to assess groundwater PCE (Tetrachloroethene) diffuse pollution in north-eastern Milan functional urban area.

PubMed

Alberti, Luca; Colombo, Loris; Formentin, Giovanni

2018-04-15

The Lombardy Region in Italy is one of the most urbanized and industrialized areas in Europe. The presence of countless sources of groundwater pollution is therefore a matter of environmental concern. The sources of groundwater contamination can be classified into two different categories: 1) Point Sources (PS), which correspond to areas releasing plumes of high concentrations (i.e. hot-spots) and 2) Multiple-Point Sources (MPS) consisting in a series of unidentifiable small sources clustered within large areas, generating an anthropogenic diffuse contamination. The latter category frequently predominates in European Functional Urban Areas (FUA) and cannot be managed through standard remediation techniques, mainly because detecting the many different source areas releasing small contaminant mass in groundwater is unfeasible. A specific legislative action has been recently enacted at Regional level (DGR IX/3510-2012), in order to identify areas prone to anthropogenic diffuse pollution and their level of contamination. With a view to defining a management plan, it is necessary to find where MPS are most likely positioned. This paper describes a methodology devised to identify the areas with the highest likelihood to host potential MPS. A groundwater flow model was implemented for a pilot area located in the Milan FUA and through the PEST code, a Null-Space Monte Carlo method was applied in order to generate a suite of several hundred hydraulic conductivity field realizations, each maintaining the model in a calibrated state and each consistent with the modelers' expert-knowledge. Thereafter, the MODPATH code was applied to generate back-traced advective flowpaths for each of the models built using the conductivity field realizations. Maps were then created displaying the number of backtracked particles that crossed each model cell in each stochastic calibrated model. The result is considered to be representative of the FUAs areas with the highest likelihood to host MPS responsible for diffuse contamination. Copyright © 2017 Elsevier B.V. All rights reserved.

Motivations for Parent Involvement within a Community School Setting

ERIC Educational Resources Information Center

Mercanti-Anthony, Michael-Joseph

2012-01-01

Increasingly, education reform advocates have pointed to the growing community school movement as a partial answer to the myriad challenges facing urban public education. Rooted in the ideas of John Dewey, community schools are generally defined as localized community hubs of partnerships--often serving as sources of service distribution and…

Land Cover and Hydrologic Variability in Residential Watersheds: Drivers of N Loss in Sacramento CA

NASA Astrophysics Data System (ADS)

McConaghie, J. B.; Zhou, W.; Cadenasso, M. L.

2011-12-01

A key aspect to understanding N loss from urban systems is the link between landscape heterogeneity and variability in non-point source (NPS) nitrogen (N) flux. Because water transports N across the landscape and into receiving streams as runoff, understanding how landscape heterogeneity influences water quantity and movement is also needed. High variability in N loss has been documented from urban systems. However, typical NPS studies characterize landscape heterogeneity by land use and only weakly explain variability in stream N. Focusing on land cover, rather than land use, may better explain observed variability in N loss because land cover elements may better indicate major drivers of N loss. Also, most studies have been conducted in temperate urban systems with stream flow year round. In semi-arid urban systems, storm flow accounts for the majority of stream discharges, and residential irrigation contributes significantly to flows in the dry season. To address how landscape heterogeneity affects variability in water quantity and quality in urban streams, we examined how land cover influences stream flows and N loss in residential streams of metropolitan Sacramento, CA. We analyzed fine-scale variation in land cover and stream N during base flow and storm events in 4 residential watersheds which differ substantially in land cover. We classified land cover using HERCULES (High Ecological Resolution Classification for Urban Landscapes and Environmental Systems) which was developed specifically for urban systems. HERCULES classifies high-resolution aerial photographs into 5 elements: buildings, pavement, herbaceous and woody vegetation, and bare soil. Streams were sampled for discharge, NO3, and Total N using auto samplers during storms in the 2010-2011 rainy season and monthly in the dry season. Partial correlation analysis and multivariate models describe the relationships between land cover elements, water retention, and stream N in these watersheds. We found an early season flush of N from streams during the first storms, and N levels diminished through progressive storms. Also, N concentrations were higher during the rainy season compared to the dry season. High proportion of impervious cover was associated with greater flow rates overall, while high proportion of herbaceous cover was associated with reduced flow rates during storms. The proportion of pavement in the watersheds, a commonly used indicator of urban intensity, did not strongly correlate with increased levels of stream N except during the flush, but did correlate with the magnitude and timing of flows during storms. However, high proportions of building cover, e.g. residential homes, did correlate with higher N fluxes. The use of fertilizers or enhanced N cycling through vegetation management near residential buildings is a possible source of increased N. Management to reduce aquatic enrichment of N from urban ecosystems may be best directed toward identifying N sources and sinks associated with specific land covers. Management must also account for seasonal dynamics, such as annual hydrologic patterns, which drive the loss of N.

Technical geothermal potential of urban subsurface influenced by land surface effects

NASA Astrophysics Data System (ADS)

Rivera, Jaime A.; Blum, Philipp; Bayer, Peter

2016-04-01

Changes in land use are probably one of the most notorious anthropogenic perturbations in urban environments. They significantly change the coupled thermal regime at the ground surface leading in most cases to increased ground surface temperatures (GST). The associated elevated vertical heat fluxes act at different scales and can influence the thermal conditions in several tens of meters in the subsurface. Urban subsurface thus often stores a higher amount of heat than less affected rural surroundings. The stored heat is regarded as a potential source of low-enthalpy geothermal energy to supply the heating energy demands in urban areas. In this work, we explore the technical geothermal potential of urban subsurface via ground coupled heat pumps with borehole heat exchangers (BHE). This is tackled by semi-analytical line-source equations. The commonly used response factors or g-functions are modified to include transient land surface effects. By including this additional source of heat, the new formulation allows to analyse the effect of pre-existing urban warming as well as different exploitation schemes fulfilling standard renewable and sustainable criteria. In our generalized reference scenario, it is demonstrated that energy gains for a single BHE may be up to 40 % when compared to non-urbanized conditions. For a scenario including the interaction of multiple BHEs, results indicate that it would be possible to supply between 6 % and 27 % of the heating demands in Central European urban settlements in a renewable way. The methodology is also applied to a study case of the city of Zurich, Switzerland, where the detailed evolution of land use is available.

40 CFR 430.125 - New source performance standards (NSPS).

Code of Federal Regulations, 2011 CFR

2011-07-01

... GUIDELINES AND STANDARDS THE PULP, PAPER, AND PAPERBOARD POINT SOURCE CATEGORY Tissue, Filter, Non-Woven, and... of 5.0 to 9.0 at all times. Subpart L [NSPS for non-integrated mills where filter and non-woven...

40 CFR 430.125 - New source performance standards (NSPS).

Code of Federal Regulations, 2010 CFR

2010-07-01

... GUIDELINES AND STANDARDS THE PULP, PAPER, AND PAPERBOARD POINT SOURCE CATEGORY Tissue, Filter, Non-Woven, and... of 5.0 to 9.0 at all times. Subpart L [NSPS for non-integrated mills where filter and non-woven...

Microbiological quality of Puget Sound Basin streams and identification of contaminant sources

USGS Publications Warehouse

Embrey, S.S.

2001-01-01

Fecal coliforms, Escherichia coli, enterococci, and somatic coliphages were detected in samples from 31 sites on streams draining urban and agricultural regions of the Puget Sound Basin Lowlands. Densities of bacteria in 48 and 71 percent of the samples exceeded U.S. Environmental Protection Agency's freshwater recreation criteria for Escherichia coli and enterococci, respectively, and 81 percent exceeded Washington State fecal coliform standards. Male-specific coliphages were detected in samples from 15 sites. Male-specific F+RNA coliphages isolated from samples taken at South Fork Thornton and Longfellow Creeks were serotyped as Group II, implicating humans as potential contaminant sources. These two sites are located in residential, urban areas. F+RNA coliphages in samples from 10 other sites, mostly in agricultural or rural areas, were serotyped as Group I, implicating non-human animals as likely sources. Chemicals common to wastewater, including fecal sterols, were detected in samples from several urban streams, and also implicate humans, at least in part, as possible sources of fecal bacteria and viruses to the streams.

Using Arc/Info GIS to help implement the National Pollutant Discharge Elimination System (NPDES) stormwater permit for Los Angeles County

DOE Office of Scientific and Technical Information (OSTI.GOV)

Levine, D.A.; Pace, P.J.; Woods, J.A.

1997-06-01

One of Los Angeles County Department of Public Works` many responsibilities is to manage non-point pollution that enters the storm drain network within Los Angeles County. The management of this non-point source pollution is mandated by the NPDES guidelines under the Federal Clean Water Act. These guidelines require the County to monitor the drainage network and the storm water and urban runoff flowing through it. The County covers over 3,117 square miles, with the NPDES Permit covering over 3,100 square miles and over 2500 miles of storm drains. A proposed solution to monitor and manage this vast geographic area ismore » centered upon an Arc/Info GIS. Some of the many concerns which need to be addressed include the administration and evaluation of Best Management Practices (BMP`s), storm drain inspection for illegal connections and illicit discharges, and pollutant load assessment and modeling. The storm drain network and other coverages will be related to external data bases currently used for facility management and planning. This system would be used for query purposes to perform spatial modeling and {open_quotes}what if{close_quotes} scenarios needed to create maps and reports required by the permit and to evaluate various BMP implementation strategies.« less

Barriers to dog rabies vaccination during an urban rabies outbreak: Qualitative findings from Arequipa, Peru

PubMed Central

Brown, Joanna; Borrini, Katty; Arevalo, Claudia; Levy, Michael Z.; Buttenheim, Alison; Hunter, Gabrielle C.; Becerra, Victor; Behrman, Jere; Paz-Soldan, Valerie A.

2017-01-01

Background Canine rabies was reintroduced to the city of Arequipa, Peru in March 2015. The Ministry of Health has conducted a series of mass dog vaccination campaigns to contain the outbreak, but canine rabies virus transmission continues in Arequipa’s complex urban environment, putting the city’s 1 million inhabitants at risk of infection. The proximate driver of canine rabies in Arequipa is low dog vaccination coverage. Our objectives were to qualitatively assess barriers to and facilitators of rabies vaccination during mass campaigns, and to explore strategies to increase participation in future efforts. Methodology/Principal findings We conducted 8 focus groups (FG) in urban and peri-urban communities of Mariano Melgar district; each FG included both sexes, and campaign participants and non-participants. All FG were transcribed and then coded independently by two coders. Results were summarized using the Social Ecological Model. At the individual level, participants described not knowing enough about rabies and vaccination campaigns, mistrusting the campaign, and being unable to handle their dogs, particularly in peri-urban vs. urban areas. At the interpersonal level, we detected some social pressure to vaccinate dogs, as well as some disparaging of those who invest time and money in pet dogs. At the organizational level, participants found the campaign information to be insufficient and ill-timed, and campaign locations and personnel inadequate. At the community level, the influence of landscape and topography on accessibility to vaccination points was reported differently between participants from the urban and peri-urban areas. Poor security and impermanent housing materials in the peri-urban areas also drives higher prevalence of guard dog ownership for home protection; these dogs usually roam freely on the streets and are more difficult to handle and bring to the vaccination points. Conclusions A well-designed communication campaign could improve knowledge about canine rabies. Timely messages on where and when vaccination is occurring could increase dog owners’ perception of their own ability to bring their dogs to the vaccination points and be part of the campaign. Small changes in the implementation of the campaign at the vaccination points could increase the public’s trust and motivation. Location of vaccination points should take into account landscape and community concerns. PMID:28306717

Which downscaled rainfall data for climate change impact studies in urban areas? Review of current approaches and trends

NASA Astrophysics Data System (ADS)

Gooré Bi, Eustache; Gachon, Philippe; Vrac, Mathieu; Monette, Frédéric

2017-02-01

Changes in extreme precipitation should be one of the primary impacts of climate change (CC) in urban areas. To assess these impacts, rainfall data from climate models are commonly used. The main goal of this paper is to report on the state of knowledge and recent works on the study of CC impacts with a focus on urban areas, in order to produce an integrated review of various approaches to which future studies can then be compared or constructed. Model output statistics (MOS) methods are increasingly used in the literature to study the impacts of CC in urban settings. A review of previous works highlights the non-stationarity nature of future climate data, underscoring the need to revise urban drainage system design criteria. A comparison of these studies is made difficult, however, by the numerous sources of uncertainty arising from a plethora of assumptions, scenarios, and modeling options. All the methods used do, however, predict increased extreme precipitation in the future, suggesting potential risks of combined sewer overflow frequencies, flooding, and back-up in existing sewer systems in urban areas. Future studies must quantify more accurately the different sources of uncertainty by improving downscaling and correction methods. New research is necessary to improve the data validation process, an aspect that is seldom reported in the literature. Finally, the potential application of non-stationarity conditions into generalized extreme value (GEV) distribution should be assessed more closely, which will require close collaboration between engineers, hydrologists, statisticians, and climatologists, thus contributing to the ongoing reflection on this issue of social concern.

Hybrid optimization and Bayesian inference techniques for a non-smooth radiation detection problem

DOE PAGES

Stefanescu, Razvan; Schmidt, Kathleen; Hite, Jason; ...

2016-12-12

In this paper, we propose several algorithms to recover the location and intensity of a radiation source located in a simulated 250 × 180 m block of an urban center based on synthetic measurements. Radioactive decay and detection are Poisson random processes, so we employ likelihood functions based on this distribution. Owing to the domain geometry and the proposed response model, the negative logarithm of the likelihood is only piecewise continuous differentiable, and it has multiple local minima. To address these difficulties, we investigate three hybrid algorithms composed of mixed optimization techniques. For global optimization, we consider simulated annealing, particlemore » swarm, and genetic algorithm, which rely solely on objective function evaluations; that is, they do not evaluate the gradient in the objective function. By employing early stopping criteria for the global optimization methods, a pseudo-optimum point is obtained. This is subsequently utilized as the initial value by the deterministic implicit filtering method, which is able to find local extrema in non-smooth functions, to finish the search in a narrow domain. These new hybrid techniques, combining global optimization and implicit filtering address, difficulties associated with the non-smooth response, and their performances, are shown to significantly decrease the computational time over the global optimization methods. To quantify uncertainties associated with the source location and intensity, we employ the delayed rejection adaptive Metropolis and DiffeRential Evolution Adaptive Metropolis algorithms. Finally, marginal densities of the source properties are obtained, and the means of the chains compare accurately with the estimates produced by the hybrid algorithms.« less

DNA BASED MOLECULAR METHODS FOR BACTERIAL SOURCE TRACKING IN WATERSHEDS

EPA Science Inventory

Point and non-point pollution sources of fecal pollution on a watershed adversely impact the quality of drinking source waters and recreational waters. States are required to develop total maximum daily loads (TMDLs) and devise best management practices (BMPs) to reduce the po...

Water quality risks of 'improved' water sources: evidence from Cambodia.

PubMed

Shaheed, A; Orgill, J; Ratana, C; Montgomery, M A; Jeuland, M A; Brown, J

2014-02-01

The objective of this study was to investigate the quality of on-plot piped water and rainwater at the point of consumption in an area with rapidly expanding coverage of 'improved' water sources. Cross-sectional study of 914 peri-urban households in Kandal Province, Cambodia, between July-August 2011. We collected data from all households on water management, drinking water quality and factors potentially related to post-collection water contamination. Drinking water samples were taken directly from a subsample of household taps (n = 143), stored tap water (n = 124), other stored water (n = 92) and treated stored water (n = 79) for basic water quality analysis for Escherichia coli and other parameters. Household drinking water management was complex, with different sources used at any given time and across seasons. Rainwater was the most commonly used drinking water source. Households mixed different water sources in storage containers, including 'improved' with 'unimproved' sources. Piped water from taps deteriorated during storage (P < 0.0005), from 520 cfu/100 ml (coefficient of variation, CV: 5.7) E. coli to 1100 cfu/100 ml (CV: 3.4). Stored non-piped water (primarily rainwater) had a mean E. coli count of 1500 cfu/100 ml (CV: 4.1), not significantly different from stored piped water (P = 0.20). Microbial contamination of stored water was significantly associated with observed storage and handling practices, including dipping hands or receptacles in water (P < 0.005), and having an uncovered storage container (P = 0.052). The microbial quality of 'improved' water sources in our study area was not maintained at the point of consumption, possibly due to a combination of mixing water sources at the household level, unsafe storage and handling practices, and inadequately treated piped-to-plot water. These results have implications for refining international targets for safe drinking water access as well as the assumptions underlying global burden of disease estimates, which posit that 'improved' sources pose minimal risks of diarrhoeal diseases. © 2013 John Wiley & Sons Ltd.

Detection of spatial fluctuations of non-point source fecal pollution in coral reef surrounding waters in southwestern Puerto Rico using PCR-based assays.

PubMed

Bonkosky, M; Hernández-Delgado, E A; Sandoz, B; Robledo, I E; Norat-Ramírez, J; Mattei, H

2009-01-01

Human fecal contamination of coral reefs is a major cause of concern. Conventional methods used to monitor microbial water quality cannot be used to discriminate between different fecal pollution sources. Fecal coliforms, enterococci, and human-specific Bacteroides (HF183, HF134), general Bacteroides-Prevotella (GB32), and Clostridium coccoides group (CP) 16S rDNA PCR assays were used to test for the presence of non-point source fecal contamination across the southwestern Puerto Rico shelf. Inshore waters were highly turbid, consistently receiving fecal pollution from variable sources, and showing the highest frequency of positive molecular marker signals. Signals were also detected at offshore waters in compliance with existing microbiological quality regulations. Phylogenetic analysis showed that most isolates were of human fecal origin. The geographic extent of non-point source fecal pollution was large and impacted extensive coral reef systems. This could have deleterious long-term impacts on public health, local fisheries and in tourism potential if not adequately addressed.

High-resolution mapping of biogenic carbon fluxes to improve urban CO2 monitoring, reporting, and verification

NASA Astrophysics Data System (ADS)

Hardiman, B. S.; Hutyra, L.; Gately, C.; Raciti, S. M.

2014-12-01

Urban areas are home to 80% of the US population and 70% of energy related fossil fuel emissions originate from urban areas. Efforts to accurately monitor, report, and verify anthropogenic CO2 missions using atmospheric measurements require reliable partitioning of anthropogenic and biogenic sources. Anthropogenic emissions peak during the daytime, coincident with biogenic drawdown of CO2. In contrast, biogenic respiration emissions peak at night when anthropogenic emissions are lower. This temporal aliasing of fluxes requires careful modeling of both biogenic and anthropogenic fluxes for accurate source attribution through inverse modeling. Biogenic fluxes in urban regions can be a significant component of the urban carbon cycle. However, vegetation in urban areas is subject to longer growing seasons, reduced competition, higher rates of nitrogen deposition, and altered patterns of biomass inputs, all interacting to elevate C turnover rates relative to analogous non-urban ecosystems. These conditions suggest that models that ignore urban vegetation or base biogenic flux estimates on non-urban forests are likely to produce inaccurate estimates of anthropogenic CO2 emissions. Biosphere models often omit biogenic fluxes in urban areas despite potentially extensive vegetation coverage. For example, in Massachusetts, models mask out as much as 40% of land area, effectively assuming they have no biological flux. This results in a ~32% underestimate of aboveground biomass (AGB) across the state as compared to higher resolution vegetation maps. Our analysis suggests that some common biomass maps may underestimate forest biomass by ~520 Tg C within the state of Massachusetts. Moreover, omitted portions of the state have the highest population density, indicating that we know least about regions where most people live. We combine remote sensing imagery of urban vegetation cover with ground surveys of tree growth and mortality to improve estimates of aboveground biomass and biogenic flux rates. Updated biogenic flux rates are combined with spatially explicit anthropogenic flux estimates and a network of urban CO2 monitoring sites as the foundation for a novel carbon monitoring system spanning the Boston-Washington D.C. metropolitan corridor.

Integrating multiple remote sensing and surface measurements with models, to quantify and constrain the past decade's total 4D aerosol source profile and impacts

NASA Astrophysics Data System (ADS)

Cohen, J. B.; Lan, R.; Lin, C.; Ng, D. H. L.; Lim, A.

2017-12-01

A multi-instrument, inverse modeling approach, is employed to identify and quantify large-scale global biomass urban aerosol emissions profiles. The approach uses MISR, MODIS, OMI and MOPITT, with data from 2006 to 2016, to generate spatial and temporal loads, as well as some information about composition. The method is able to identify regions impacted by stable urban sources, changing urban sources, intense fires, and linear-combinations. Subsequent quantification is a unified field, leading to a less biased profile, with the result not requiring arbitrary scaling to match long-term means. Additionally, the result reasonably reproduces inter and intra annual variation. Both meso-scale (WRF-CHEM) and global (MIT-AERO, multi-mode, multi-mixing state aerosol model) models of aerosol transport, chemistry, and physics, are used to generate resulting 4D aerosol fields. Comparisons with CALIOP, AERONET, and surface chemical and aerosol networks, provide unbiased confirmation, while column and vertical loadings provide additional feedback. There are three significant results. First, there is a reduction in sources over existing urban areas in East Asia. Second, there is an increase in sources over new urban areas in South, South East, and East Asia. Third, that there is an increase in fire sources in South and South East Asia. There are other initial findings relevant to the global tropics, which have not been as deeply investigated. The results improve the model match with both the mean and variation, which is essential if we hope to understand seasonal extremes. The results also quantify impacts of both local and long-range sources. This is of extreme urgency, in particular in developing nations, where there are considerable contributions from long-range or otherwise unknown sources, that impact hundreds of millions of people throughout Asia. It is hoped that the approach provided here can help us to make critical decisions about total sources, as well as point out the many missing scientific and analytical issues still required to address.

Urban microbial ecology of a freshwater estuary of Lake Michigan

PubMed Central

Fisher, Jenny C.; Newton, Ryan J.; Dila, Deborah K.

2015-01-01

Freshwater estuaries throughout the Great Lakes region receive stormwater runoff and riverine inputs from heavily urbanized population centers. While human and animal feces contained in this runoff are often the focus of source tracking investigations, non-fecal bacterial loads from soil, aerosols, urban infrastructure, and other sources are also transported to estuaries and lakes. We quantified and characterized this non-fecal urban microbial component using bacterial 16S rRNA gene sequences from sewage, stormwater, rivers, harbor/estuary, and the lake surrounding Milwaukee, WI, USA. Bacterial communities from each of these environments had a distinctive composition, but some community members were shared among environments. We used a statistical biomarker discovery tool to identify the components of the microbial community that were most strongly associated with stormwater and sewage to describe an “urban microbial signature,” and measured the presence and relative abundance of these organisms in the rivers, estuary, and lake. This urban signature increased in magnitude in the estuary and harbor with increasing rainfall levels, and was more apparent in lake samples with closest proximity to the Milwaukee estuary. The dominant bacterial taxa in the urban signature were Acinetobacter, Aeromonas, and Pseudomonas, which are organisms associated with pipe infrastructure and soil and not typically found in pelagic freshwater environments. These taxa were highly abundant in stormwater and sewage, but sewage also contained a high abundance of Arcobacter and Trichococcus that appeared in lower abundance in stormwater outfalls and in trace amounts in aquatic environments. Urban signature organisms comprised 1.7% of estuary and harbor communities under baseflow conditions, 3.5% after rain, and >10% after a combined sewer overflow. With predicted increases in urbanization across the Great Lakes, further alteration of freshwater communities is likely to occur with potential long term impacts on the function of estuarine and nearshore ecosystems. PMID:26866046

Heavy metals in agricultural landscapes as hazards to human and ecosystem health: a case study on zinc and cadmium in drainage channel sediments.

PubMed

Savic, Radovan; Ondrasek, Gabrijel; Josimov-Dundjerski, Jasmina

2015-02-01

In agricultural systems, heavy metals pose severe risks to the health of soil-plant-animal-human continuum. Drainage channels, as integral components of agricultural landscapes, contain sediment material that can be both a source and a sink of metals and other toxic/persistent elements due to its highly reactive interfaces and strong binding affinity. The drainage channel network in a case study area of Vojvodina (Serbia) is not appropriately protected from contamination, nor is it maintained regularly (e.g. by desilting), thus endangering and potentially decreasing the ecological value of surrounding water and agricultural land resources, i.e. exposing food production to potential contaminants. In this study (2004-2012), Cd and Zn concentrations were analysed in 100 samples from 46 drainage channels sediments spread along the areas of the most intensive agricultural land use in Vojvodina. Among the samples measured, 5% had Cd and 14% had Zn concentrations above the maximally permitted levels, indicating that some drainage channel sections have been exposed to different point and non-point source pollutants. The maximum detected concentrations of the analysed elements were >50% (Zn) and were as much as 11-fold (Cd) higher than their remediation values. There is a strong need for the establishment of qualitative monitoring of channel sediment media in agro-ecosystems closely linked with complex pollution sources (intensive agriculture, industry, urban zones). © 2013 Society of Chemical Industry.

FECAL BACTERIA SOURCE TRACKING AND BACTEROIDES SPP. HOST SPECIES SPECIFICITY ANALYSIS

EPA Science Inventory

Point and non-point pollution sources of fecal pollution on a watershed adversely impact the quality of drinking source waters and recreational waters. States are required to develop total maximum daily loads (TMDLs) and devise best management practices (BMPs) to reduce the po...

Comparative LCA of decentralized wastewater treatment alternatives for non-potable urban reuse.

PubMed

Opher, Tamar; Friedler, Eran

2016-11-01

Municipal wastewater (WW) effluent represents a reliable and significant source for reclaimed water, very much needed nowadays. Water reclamation and reuse has become an attractive option for conserving and extending available water sources. The decentralized approach to domestic WW treatment benefits from the advantages of source separation, which makes available simple small-scale systems and on-site reuse, which can be constructed on a short time schedule and occasionally upgraded with new technological developments. In this study we perform a Life Cycle Assessment to compare between the environmental impacts of four alternatives for a hypothetical city's water-wastewater service system. The baseline alternative is the most common, centralized approach for WW treatment, in which WW is conveyed to and treated in a large wastewater treatment plant (WWTP) and is then discharged to a stream. The three alternatives represent different scales of distribution of the WW treatment phase, along with urban irrigation and domestic non-potable water reuse (toilet flushing). The first alternative includes centralized treatment at a WWTP, with part of the reclaimed WW (RWW) supplied back to the urban consumers. The second and third alternatives implement de-centralized greywater (GW) treatment with local reuse, one at cluster level (320 households) and one at building level (40 households). Life cycle impact assessment results show a consistent disadvantage of the prevailing centralized approach under local conditions in Israel, where seawater desalination is the marginal source of water supply. The alternative of source separation and GW reuse at cluster level seems to be the most preferable one, though its environmental performance is only slightly better than GW reuse at building level. Centralized WW treatment with urban reuse of WWTP effluents is not advantageous over decentralized treatment of GW because the supply of RWW back to consumers is very costly in materials and energy. Electricity is a major driver of the impacts in most categories, pertaining mostly to potable water production and supply. Infrastructure was found to have a notable effect on metal depletion, human toxicity and freshwater and marine ecotoxicity. Sensitivity to major model parameters was analyzed. A shift to a larger share of renewable energy sources in the electricity mix results in a dramatic improvement in most impact categories. Switching to a mix of water sources, rather than the marginal source, leads to a significant reduction in most impacts. It is concluded that under the conditions tested, a decentralized approach to urban wastewater management is environmentally preferable to the common centralized system. It is worth exploring such options under different conditions as well, in cases which new urban infrastructure is planned or replacement of old infrastructure is required. Copyright © 2016 Elsevier Ltd. All rights reserved.

Urban increments of gaseous and aerosol pollutants and their sources using mobile aerosol mass spectrometry measurements

NASA Astrophysics Data System (ADS)

Elser, Miriam; Bozzetti, Carlo; El-Haddad, Imad; Maasikmets, Marek; Teinemaa, Erik; Richter, Rene; Wolf, Robert; Slowik, Jay G.; Baltensperger, Urs; Prévôt, André S. H.

2016-06-01

Air pollution is one of the main environmental concerns in urban areas, where anthropogenic emissions strongly affect air quality. This work presents the first spatially resolved detailed characterization of PM2.5 (particulate matter with aerodynamic equivalent diameter daero ≤ 2.5 µm) in two major Estonian cities, Tallinn and Tartu. The measurements were performed in March 2014 using a mobile platform. In both cities, the non-refractory (NR)-PM2.5 was characterized by a high-resolution time-of-flight aerosol mass spectrometer (HR-ToF-AMS) using a recently developed lens which increases the transmission of super-micron particles. Equivalent black carbon (eBC) and several trace gases including carbon monoxide (CO), carbon dioxide (CO2), and methane (CH4) were also measured. The chemical composition of PM2.5 was found to be very similar in the two cities. Organic aerosol (OA) constituted the largest fraction, explaining on average about 52 to 60 % of the PM2.5 mass. Four sources of OA were identified using positive matrix factorization (PMF): hydrocarbon-like OA (HOA, from traffic emissions), biomass burning OA (BBOA, from biomass combustion), residential influenced OA (RIOA, probably mostly from cooking processes with possible contributions from waste and coal burning), and oxygenated OA (OOA, related to secondary aerosol formation). OOA was the major OA source during nighttime, explaining on average half of the OA mass, while during daytime mobile measurements the OA was affected by point sources and dominated by the primary fraction. A strong increase in the secondary organic and inorganic components was observed during periods with transport of air masses from northern Germany, while the primary local emissions accumulated during periods with temperature inversions. Mobile measurements offered the identification of different source regions within the urban areas and the assessment of the extent to which pollutants concentrations exceeded regional background levels (urban increments). HOA, eBC, CO2, and CO showed stronger enhancements on busy roads during the morning and evening traffic rush hours; BBOA had its maximum enhancement in the residential areas during the evening hours and RIOA was enhanced in both the city center (emissions from restaurants) and in the residential areas (emissions from residential cooking). In contrast, secondary components (OOA, sulfate (SO4), nitrate (NO3), ammonium (NH4), and chloride (Cl)) had very homogeneous distributions in time and space. We were able to determine a total PM2.5 urban increment in Tartu of 6.0 µg m-3 over a regional background concentration of 4.0 µg m-3 (i.e., a factor of 2.5 increase). Traffic exhaust emissions were identified as the most important source of this increase, with eBC and HOA explaining on average 53.3 and 20.5 % of the total increment, respectively.

Modeling the contribution of point sources and non-point sources to Thachin River water pollution.

PubMed

Schaffner, Monika; Bader, Hans-Peter; Scheidegger, Ruth

2009-08-15

Major rivers in developing and emerging countries suffer increasingly of severe degradation of water quality. The current study uses a mathematical Material Flow Analysis (MMFA) as a complementary approach to address the degradation of river water quality due to nutrient pollution in the Thachin River Basin in Central Thailand. This paper gives an overview of the origins and flow paths of the various point- and non-point pollution sources in the Thachin River Basin (in terms of nitrogen and phosphorus) and quantifies their relative importance within the system. The key parameters influencing the main nutrient flows are determined and possible mitigation measures discussed. The results show that aquaculture (as a point source) and rice farming (as a non-point source) are the key nutrient sources in the Thachin River Basin. Other point sources such as pig farms, households and industries, which were previously cited as the most relevant pollution sources in terms of organic pollution, play less significant roles in comparison. This order of importance shifts when considering the model results for the provincial level. Crosschecks with secondary data and field studies confirm the plausibility of our simulations. Specific nutrient loads for the pollution sources are derived; these can be used for a first broad quantification of nutrient pollution in comparable river basins. Based on an identification of the sensitive model parameters, possible mitigation scenarios are determined and their potential to reduce the nutrient load evaluated. A comparison of simulated nutrient loads with measured nutrient concentrations shows that nutrient retention in the river system may be significant. Sedimentation in the slow flowing surface water network as well as nitrogen emission to the air from the warm oxygen deficient waters are certainly partly responsible, but also wetlands along the river banks could play an important role as nutrient sinks.

Source apportionment of PM10 and PM2.5 in major urban Greek agglomerations using a hybrid source-receptor modeling process.

PubMed

Argyropoulos, G; Samara, C; Diapouli, E; Eleftheriadis, K; Papaoikonomou, K; Kungolos, A

2017-12-01

A hybrid source-receptor modeling process was assembled, to apportion and infer source locations of PM 10 and PM 2.5 in three heavily-impacted urban areas of Greece, during the warm period of 2011, and the cold period of 2012. The assembled process involved application of an advanced computational procedure, the so-called Robotic Chemical Mass Balance (RCMB) model. Source locations were inferred using two well-established probability functions: (a) the Conditional Probability Function (CPF), to correlate the output of RCMB with local wind directional data, and (b) the Potential Source Contribution Function (PSCF), to correlate the output of RCMB with 72h air-mass back-trajectories, arriving at the receptor sites, during sampling. Regarding CPF, a higher-level conditional probability function was defined as well, from the common locus of CPF sectors derived for neighboring receptor sites. With respect to PSCF, a non-parametric bootstrapping method was applied to discriminate the statistically significant values. RCMB modeling showed that resuspended dust is actually one of the main barriers for attaining the European Union (EU) limit values in Mediterranean urban agglomerations, where the drier climate favors build-up. The shift in the energy mix of Greece (caused by the economic recession) was also evidenced, since biomass burning was found to contribute more significantly to the sampling sites belonging to the coldest climatic zone, particularly during the cold period. The CPF analysis showed that short-range transport of anthropogenic emissions from urban traffic to urban background sites was very likely to have occurred, within all the examined urban agglomerations. The PSCF analysis confirmed that long-range transport of primary and/or secondary aerosols may indeed be possible, even from distances over 1000km away from study areas. Copyright © 2017 Elsevier B.V. All rights reserved.

Formaldehyde Source Attribution in Houston during TexAQS II and TRAMP

NASA Astrophysics Data System (ADS)

Guven, B.; Olaguer, E. P.

2010-12-01

To determine the relative importance of primary vs secondary formaldehyde in Houston, source apportionment was performed on continuous online measurements of VOCs, formaldehyde (HCHO), CO, SO2, and HONO at one urban and two industrial sites. The results of source apportionment were used in conjunction with the meteorological, emission inventory, emission event, and back trajectory data catalogued in Air Research Information Infrastructure (ARII) to determine the dominant source regions and evaluate the accuracy of reported regular and upset emissions from industrial facilities. The contribution of industrial sources such as flares from petrochemical plants and refineries to total atmospheric formaldehyde concentrations at the urban site is estimated to be 17% compared to 23% for mobile sources, amounting to 40% for the total contribution of primary HCHO sources. The relative contribution of industrial sources to HCHO concentration at the urban site increased to about 66% on some mornings coinciding with the HCHO peak concentrations. Secondary formation of HCHO during the day and night resulted from the reactions of industrial olefins and other VOCs with OH or ozone was a significant contributor to HCHO concentrations at the urban site. An analysis of emission event, back trajectory and ambient concentration data in ARII showed that a large percentage of emission events were associated with trajectories that passed through the two industrial sites when peaks in concentrations were detected at those sites. Some peak HCHO concentrations can also be linked to emission events of other VOCs, while a significant portion remained unexplained by the reported events. It is likely, based on the results from the SHARP campaign and our analysis, that some episodic emission events containing HCHO are unreported to the TCEQ. Overlaid CPF plots for nighttime (green) and daytime (red) HCHO concentrations measured at three sites and the locations of the largest emitting point sources around the sites. Average contributions to formaldehyde concentrations.

Impacts of intensive agricultural irrigation and livestock farming on a semi-arid Mediterranean catchment.

PubMed

Martín-Queller, Emi; Moreno-Mateos, David; Pedrocchi, César; Cervantes, Juan; Martínez, Gonzalo

2010-08-01

Irrigation return flows (IRF) are a major contributor of non-point source pollution to surface and groundwater. We evaluated the effects of irrigation on stream hydrochemistry in a Mediterranean semi-arid catchment (Flumen River, NE Spain). The Flumen River was separated into two zones based on the intensity of irrigation activities in the watershed. General linear models were used to compare the two zones. Relevant covariables (urban sewage, pig farming, and gypsum deposits in the basin) were quantified with the help of geographic information system techniques, accompanied by ground-truthing. High variability of the water quality parameters and temporal dynamics caused by irrigation were used to distinguish the two river reaches. Urban activity and livestock farming had a significant effect on water chemistry. An increase in the concentration of salts (240-541 microS.cm(-1) more in winter) and nitrate (average concentrations increased from 8.5 to 20.8 mg.l(-1) during irrigation months) was associated with a higher level of IRF. Those river reaches more strongly influenced by urban areas tended to have higher phosphorus (0.19-0.42 mg.l(-1) more in winter) concentrations. These results support earlier research about the significant consequences to water quality of both urban expansion and intensive agricultural production in arid and semi-arid regions. Data also indicate that salinization of soils, subsoils, surface water, and groundwater can be an unwelcome result of the application of pig manure for fertilization (increase in sodium concentration in 77.9 to 138.6 mg.l(-1)).

Relation Decomposing between Urbanization and Consumption of Water-Energy Sources

NASA Astrophysics Data System (ADS)

Wang, Y.; Xiao, W.; Wang, Y.; Zhao, Y.; Wang, J., , Dr; Jiang, D.; Wang, H.

2017-12-01

Abstract: Water resources and energy, important subsystems of city, are the basic guarantee for the normal operation of city, which play an important role to brace the urbanization. The interdependence between them are increasing along with the rapid development of China's economy. The relationship between urbanization and consumption of energy and water have become the focal point of the scholars, but the research have more attention to the impact of urbanization on two subsystems separately, and do not reveal the effects of urbanization on the water-energy nexus. Thus, there is little consideration upon the different characteristics of China's several regions in water and energy consumption in urbanization. In this paper, the STIRPAT model is built to reveal the relationship between urbanization and the consumption of water and energy. Also, the influence of urbanization on different main body of water and energy consumption are discussed. The different regional main factors of water and energy in the process of urbanization are identified through water and energy panel data of China's thirty provinces. Finally, through the regression analysis of total water consumption data of agriculture, industry, service industry with total energy consumption data, the relationship of water and energy in the process of urban development are analyzed.

Sources of primary and secondary organic aerosol and their diurnal variations.

PubMed

Zheng, Mei; Zhao, Xiuying; Cheng, Yuan; Yan, Caiqing; Shi, Wenyan; Zhang, Xiaolu; Weber, Rodney J; Schauer, James J; Wang, Xinming; Edgerton, Eric S

2014-01-15

PM(2.5), as one of the criteria pollutants regulated in the U.S. and other countries due to its adverse health impacts, contains more than hundreds of organic pollutants with different sources and formation mechanisms. Daytime and nighttime PM2.5 samples from the August Mini-Intensive Gas and Aerosol Campaign (AMIGAS) in the southeastern U.S. were collected during summer 2008 at one urban site and one rural site, and were analyzed for organic carbon (OC), elemental carbon (EC), water soluble organic carbon (WSOC), and various individual organic compounds including some important tracers for carbonaceous aerosol sources by gas chromatography-mass spectrometry. Most samples exhibited higher daytime OC concentration, while higher nighttime OC was found in a few events at the urban site. Sources, formation mechanisms and composition of organic aerosol are complicated and results of this study showed that it exhibited distinct diurnal variations. With detailed organic tracer information, sources contributing to particulate OC were identified: higher nighttime OC concentration occurring in several occasions was mainly contributed by the increasing primary emissions at night, especially diesel exhaust and biomass burning; whereas sources responsible for higher daytime OC concentration included secondary organic aerosol (SOA) formation (e.g., cis-pinonic acid and non-biomass burning WSOC) together with traffic emissions especially gasoline engine exhaust. Primary tracers from combustion related sources such as EC, polycyclic aromatic hydrocarbons, and hopanes and steranes were significantly higher at the urban site with an urban to rural ratio between 5 and 8. However, this urban-rural difference for secondary components was less significant, indicating a relatively homogeneous distribution of SOA spatially. We found cholesterol concentrations, a typical tracer for meat cooking, were consistently higher at the rural site especially during the daytime, suggesting the likely additional sources for this tracer at rural site and that it should be used with caution as meat cooking tracer in rural areas in the future. Copyright © 2013 Elsevier B.V. All rights reserved.

A GIS technology based potential eco-risk assessment of metals in urban soils in Beijing, China.

PubMed

Wang, Meie; Bai, Yanying; Chen, Weiping; Markert, Bernd; Peng, Chi; Ouyang, Zhiyun

2012-02-01

Ecological risks of heavy metals in urban soils were evaluated using Beijing, China as an example. Cadmium, Cu, Zn, Pb, Cr and Ni contents of 233 surface soils sampled by 1 min latitude × 1 min longitude grid were used to identify their spatial distribution patterns and potential emission sources. Throughout the city, longer the duration of urbanization greater was the accumulations of heavy metals especially, Cd, Cu, Pb, and Zn. The soil Zn mainly came from the wears of vehicular tires. Point source emissions of heavy metals were few and far in the downwind south-east quadrant of Beijing. The calculated risk indices showed potential median eco-risks in the ancient central city. No potential high eco-risk due to soil-borne heavy metals was found. The potential medium eco-risk areas in Beijing would expand from the initial 24 to 110 km(2) if soil pH were to reduce by 0.5 units in anticipation. Copyright © 2011 Elsevier Ltd. All rights reserved.

Forecasting future phosphorus export to the Laurentian Great Lakes from land-derived nutrient inputs

NASA Astrophysics Data System (ADS)

LaBeau, M. B.; Robertson, D. M.; Mayer, A. S.; Pijanowski, B. C.

2011-12-01

Anthropogenic use of the land through agricultural and urban activities has significantly increased phosphorus loading to rivers that flow to the Great Lakes. Phosphorus (P) is a critical element in the eutrophication of the freshwater ecosystems, most notably the Great Lakes. To better understand factors influencing phosphorus delivery to aquatic systems and thus their potential harmful effects to lake ecosystems, models that predict P export should incorporate account for changing changes in anthropogenic activities. Land-derived P from high yielding sources, such as agriculture and urban areas, affect eutrophication at various scales (e.g. specific bays to all of Lake Erie). SPARROW (SPAtially Referenced Regression On Watershed attributes) is a spatially explicit watershed model that has been used to understand linkages between land-derived sources and nutrient transport to the Great Lakes. The Great Lakes region is expected to experience a doubling of urbanized areas along with a ten percent increase in agricultural use over the next 40 years, which is likely to increase P loading. To determine how these changes will impact P loading, SPARROW have been developed that relate changes in land use to changes in nutrient sources, including relationships between row crop acreage and fertilizer intensity and urban land use and point source intensity. We used land use projections from the Land Transformation Model, a, spatially explicit, neural-net based land change model. Land use patterns from current to 2040 were used as input into HydroSPARROW, a forecasting tool that enables SPARROW to simulate the effects of various land-use and climate scenarios. Consequently, this work is focusing on understanding the effects of how specific agriculture and urbanization activities affect P loading in the watersheds of the Laurentian Great Lakes to potentially find strategies to reduce the extent and severity of future eutrophication.

Envelope of coda waves for a double couple source due to non-linear elasticity

NASA Astrophysics Data System (ADS)

Calisto, Ignacia; Bataille, Klaus

2014-10-01

Non-linear elasticity has recently been considered as a source of scattering, therefore contributing to the coda of seismic waves, in particular for the case of explosive sources. This idea is analysed further here, theoretically solving the expression for the envelope of coda waves generated by a point moment tensor in order to compare with earthquake data. For weak non-linearities, one can consider each point of the non-linear medium as a source of scattering within a homogeneous and linear medium, for which Green's functions can be used to compute the total displacement of scattered waves. These sources of scattering have specific radiation patterns depending on the incident and scattered P or S waves, respectively. In this approach, the coda envelope depends on three scalar parameters related to the specific non-linearity of the medium; however these parameters only change the scale of the coda envelope. The shape of the coda envelope is sensitive to both the source time function and the intrinsic attenuation. We compare simulations using this model with data from earthquakes in Taiwan, with a good fit.

Source data supported high resolution carbon emissions inventory for urban areas of the Beijing-Tianjin-Hebei region: Spatial patterns, decomposition and policy implications.

PubMed

Cai, Bofeng; Li, Wanxin; Dhakal, Shobhakar; Wang, Jianghao

2018-01-15

This paper developed internationally compatible methods for delineating boundaries of urban areas in China. By integrating emission source data with existing official statistics as well as using rescaling methodology of data mapping for 1 km grid, the authors constructed high resolution emission gridded data in Beijing-Tianjin-Hebei (Jing-Jin-Ji) region in China for 2012. Comparisons between urban and non-urban areas of carbon emissions from industry, agriculture, household and transport exhibited regional disparities as well as sectoral differences. Except for the Hebei province, per capita total direct carbon emissions from urban extents in Beijing and Tianjin were both lower than provincial averages, indicating the climate benefit of urbanization, comparable to results from developed countries. Urban extents in the Hebei province were mainly industrial centers while those in Beijing and Tianjin were more service oriented. Further decomposition analysis revealed population to be a common major driver for increased carbon emissions but climate implications of urban design, economic productivity of land use, and carbon intensity of GDP were both cluster- and sector-specific. This study disapproves the one-size-fits-all solution for carbon mitigation but calls for down-scaled analysis of carbon emissions and formulation of localized carbon reduction strategies in the Jing-Jin-Ji as well as other regions in China. Copyright © 2017 Elsevier Ltd. All rights reserved.

Multi-angle Indicators System of Non-point Pollution Source Assessment in Rural Areas: A Case Study Near Taihu Lake

NASA Astrophysics Data System (ADS)

Huang, Lei; Ban, Jie; Han, Yu Ting; Yang, Jie; Bi, Jun

2013-04-01

This study aims to identify key environmental risk sources contributing to water eutrophication and to suggest certain risk management strategies for rural areas. The multi-angle indicators included in the risk source assessment system were non-point source pollution, deficient waste treatment, and public awareness of environmental risk, which combined psychometric paradigm methods, the contingent valuation method, and personal interviews to describe the environmental sensitivity of local residents. Total risk values of different villages near Taihu Lake were calculated in the case study, which resulted in a geographic risk map showing which village was the critical risk source of Taihu eutrophication. The increased application of phosphorus (P) and nitrogen (N), loss vulnerability of pollutant, and a lack of environmental risk awareness led to more serious non-point pollution, especially in rural China. Interesting results revealed by the quotient between the scores of objective risk sources and subjective risk sources showed what should be improved for each study village. More environmental investments, control of agricultural activities, and promotion of environmental education are critical considerations for rural environmental management. These findings are helpful for developing targeted and effective risk management strategies in rural areas.

On the spatial distribution and evolution of ultrafine particles in Barcelona

NASA Astrophysics Data System (ADS)

Dall'Osto, M.; Querol, X.; Alastuey, A.; O'Dowd, C.; Harrison, R. M.; Wenger, J.; Gómez-Moreno, F. J.

2013-01-01

Sources and evolution of ultrafine particles were investigated both horizontally and vertically in the large urban agglomerate of Barcelona, Spain. Within the SAPUSS project (Solving Aerosol Problems by Using Synergistic Strategies), a large number of instruments was deployed simultaneously at different monitoring sites (road, two urban background, regional background, urban tower 150 m a.s.l., urban background tower site 80 m a.s.l.) during a 4 week period in September-October 2010. Particle number concentrations (N>5 nm) are highly correlated with black carbon (BC) at all sites only under strong vehicular traffic influences. By contrast, under cleaner atmospheric conditions (low condensation sink, CS) such correlation diverges towards much higher N/BC ratios at all sites, indicating additional sources of particles including secondary production of freshly nucleated particles. Size-resolved aerosol distributions (N10-500) as well as particle number concentrations (N>5 nm) allow us to identify three types of nucleation and growth events: (1) a regional type event originating in the whole study region and impacting almost simultaneously the urban city of Barcelona and the surrounding urban background area; (2) a regional type event impacting only the regional background area but not the urban agglomerate; (3) an urban type event which originates only within the city centre but whose growth continues while transported away from the city to the regional background. Furthermore, during these clean air days, higher N are found at tower level than at ground level only in the city centre whereas such a difference is not so pronounced at the remote urban background tower. In other words, this study suggests that the column of air above the city ground level possesses the optimal combination between low CS and high vapour source, hence enhancing the concentrations of freshly nucleated particles. By contrast, within stagnant polluted atmospheric conditions, higher N and BC concentrations are always measured at ground level relative to tower level at all sites. Our study suggests that the city centre of Barcelona is a source of non-volatile traffic primary particles (29-39% of N>5 nm), but other sources, including secondary freshly nucleated particles contribute up to 61-71% of particle number (N>5 nm) at all sites. We suggest that organic compounds evaporating from freshly emitted traffic particles are a possible candidate for new particle formation within the city and urban plume.

[Multiple time scales analysis of spatial differentiation characteristics of non-point source nitrogen loss within watershed].

PubMed

Liu, Mei-bing; Chen, Xing-wei; Chen, Ying

2015-07-01

Identification of the critical source areas of non-point source pollution is an important means to control the non-point source pollution within the watershed. In order to further reveal the impact of multiple time scales on the spatial differentiation characteristics of non-point source nitrogen loss, a SWAT model of Shanmei Reservoir watershed was developed. Based on the simulation of total nitrogen (TN) loss intensity of all 38 subbasins, spatial distribution characteristics of nitrogen loss and critical source areas were analyzed at three time scales of yearly average, monthly average and rainstorms flood process, respectively. Furthermore, multiple linear correlation analysis was conducted to analyze the contribution of natural environment and anthropogenic disturbance on nitrogen loss. The results showed that there were significant spatial differences of TN loss in Shanmei Reservoir watershed at different time scales, and the spatial differentiation degree of nitrogen loss was in the order of monthly average > yearly average > rainstorms flood process. TN loss load mainly came from upland Taoxi subbasin, which was identified as the critical source area. At different time scales, land use types (such as farmland and forest) were always the dominant factor affecting the spatial distribution of nitrogen loss, while the effect of precipitation and runoff on the nitrogen loss was only taken in no fertilization month and several processes of storm flood at no fertilization date. This was mainly due to the significant spatial variation of land use and fertilization, as well as the low spatial variability of precipitation and runoff.

Novel human-associated Lachnospiraceae genetic markers improve detection of fecal pollution sources in urban waters.

PubMed

Feng, Shuchen; Bootsma, Melinda; McLellan, Sandra L

2018-05-04

The human microbiome contains many organisms that could potentially be used as indicators of human fecal pollution. Here we report the development of two novel human-associated genetic marker assays that target organisms within the family Lachnospiraceae Next-generation sequencing of the V6 region of the 16S rRNA gene from sewage and animal stool samples identified 40 human-associated marker candidates with a robust signal in sewage and low or no occurrence in nonhuman hosts. Two were chosen for quantitative PCR (qPCR) assay development using longer sequences (V2 to V9 regions) generated from clone libraries. Validation of these assays, designated Lachno3 and Lachno12, was performed using fecal samples (n=55) from cat, dog, pig, cow, deer, and gull sources, and compared with established host-associated assays (Lachno2, and two Human Bacteroides assays; HB and HF183/BacR287). Each of the established assays cross-reacted with at least one other animal, including animals common in urban areas. Lachno3 and Lachno12 were primarily human-associated; however, Lachno12 demonstrated low levels of cross-reactivity with select cows, and non-specific amplification in pigs. This limitation may not be problematic when testing urban waters. These novel markers resolved ambiguous results from previous investigations in stormwater-impacted waters, demonstrating their utility. The complexity of the microbiome in humans and animals suggests no single organism is strictly specific to humans, and multiple complementary markers used in combination will provide the highest resolution and specificity for assessing fecal pollution sources. IMPORTANCE Traditional fecal indicator bacteria do not distinguish animal from human fecal pollution, which is necessary to evaluate health risks and mitigate pollution sources. Assessing urban areas is challenging since water can be impacted by sewage, which has a high likelihood of carrying human pathogens, as well as pet waste and urban wildlife. We demonstrate Lachno3 and Lachno12 assays are human-associated and highly specific for urban sources, offering reliable identification of fecal pollution sources in urban waters. Copyright © 2018 American Society for Microbiology.

Spatio-temporal variation in the tap water isotope ratios of Salt Lake City: a novel indicator of urban water system structure and dynamics.

NASA Astrophysics Data System (ADS)

Jameel, M. Y.; Bowen, G. J.

2015-12-01

Public water supply systems are the life-blood of urban areas. How we use urban water systems affects more than human health and well-being. Our water use can alter a city's energy balance, including how much solar energy is absorbed as heat or reflected back into space. The severity of these effects, and the need to better understand connections between climate, water extraction, water use, and water use impacts, is strongest in areas of climatic aridity and substantial land-use change, such as the rapidly urbanizing areas of Utah. We have gathered and analyzed stable water isotope data from a series of semi-annual hydrological surveys (spring and fall, 2013 and 2014) in urban tap water sampled across the Salt Lake Valley. Our study has led to four major findings thus far: 1) Clear and substantial variation in tap water isotopic composition in space and time that can be linked to different water sources and management practices within the urban area, 2) There is a strong correlation between the range of observed isotope values and the population of water districts, reflecting use of water from multiple local and non-local sources in districts with high water demand, 3) Water isotopes reflect significant and variable loss of water due to evaporation of surface water resources and 4) Overall, tap water contains lower concentrations of the heavy H and O isotopes than does precipitation within the basin, reflecting the connection between city water supplies and mountain water sources. Our results highlight the utility of isotopic data as an indicator of heterogeneities within urban water systems, management practices and their variation across a major metropolitan area, and effects of climate variability on urban water supplies

Quality Analysis of Open Street Map Data

NASA Astrophysics Data System (ADS)

Wang, M.; Li, Q.; Hu, Q.; Zhou, M.

2013-05-01

Crowd sourcing geographic data is an opensource geographic data which is contributed by lots of non-professionals and provided to the public. The typical crowd sourcing geographic data contains GPS track data like OpenStreetMap, collaborative map data like Wikimapia, social websites like Twitter and Facebook, POI signed by Jiepang user and so on. These data will provide canonical geographic information for pubic after treatment. As compared with conventional geographic data collection and update method, the crowd sourcing geographic data from the non-professional has characteristics or advantages of large data volume, high currency, abundance information and low cost and becomes a research hotspot of international geographic information science in the recent years. Large volume crowd sourcing geographic data with high currency provides a new solution for geospatial database updating while it need to solve the quality problem of crowd sourcing geographic data obtained from the non-professionals. In this paper, a quality analysis model for OpenStreetMap crowd sourcing geographic data is proposed. Firstly, a quality analysis framework is designed based on data characteristic analysis of OSM data. Secondly, a quality assessment model for OSM data by three different quality elements: completeness, thematic accuracy and positional accuracy is presented. Finally, take the OSM data of Wuhan for instance, the paper analyses and assesses the quality of OSM data with 2011 version of navigation map for reference. The result shows that the high-level roads and urban traffic network of OSM data has a high positional accuracy and completeness so that these OSM data can be used for updating of urban road network database.

Convex Hull Aided Registration Method (CHARM).

PubMed

Fan, Jingfan; Yang, Jian; Zhao, Yitian; Ai, Danni; Liu, Yonghuai; Wang, Ge; Wang, Yongtian

2017-09-01

Non-rigid registration finds many applications such as photogrammetry, motion tracking, model retrieval, and object recognition. In this paper we propose a novel convex hull aided registration method (CHARM) to match two point sets subject to a non-rigid transformation. First, two convex hulls are extracted from the source and target respectively. Then, all points of the point sets are projected onto the reference plane through each triangular facet of the hulls. From these projections, invariant features are extracted and matched optimally. The matched feature point pairs are mapped back onto the triangular facets of the convex hulls to remove outliers that are outside any relevant triangular facet. The rigid transformation from the source to the target is robustly estimated by the random sample consensus (RANSAC) scheme through minimizing the distance between the matched feature point pairs. Finally, these feature points are utilized as the control points to achieve non-rigid deformation in the form of thin-plate spline of the entire source point set towards the target one. The experimental results based on both synthetic and real data show that the proposed algorithm outperforms several state-of-the-art ones with respect to sampling, rotational angle, and data noise. In addition, the proposed CHARM algorithm also shows higher computational efficiency compared to these methods.

Relative household wealth and non-fatal road crashes: analysis of population-representative data of Kenyan adults.

PubMed

Kraemer, John D

2018-05-18

This study aims to examine potential road crash disparities across relative wealth and location of residence in Kenya by analyzing population-representative Demographic and Health Survey data. Relative wealth was measured by household assets, converted into an index by polychoric principal components analysis. Location and sex-stratified associations between wealth quantiles and crashes were flexibly estimated using fractional polynomial models. Structural equation models were fit to examine whether observed differences may operate through previously identified determinants. In rural areas, crashes were least common for both the poorest men (-5.2 percentage points, 95% CI: -7.3 to -3.2) and women (-1.6 percentage points, 95% CI: -2.9 to -0.4). In urban areas, male crashes were lowest (-3.0 percentage points, 95% CI: -5.2 to -0.8) among the wealthiest, while they peaked in the middle of the female wealth distribution (2.0 percentage points, 95% CI: 0.3-3.8). Male differences operate partially though occupational driving and vehicle ownership. Urban female differences operate partially through household vehicle ownership, but differences for rural women were not explained by modeled determinants. Relative wealth and road crash have opposite associations in rural and urban areas. Especially in rural areas, it is important to mitigate potential unintended effects of economic development.

Woodchip bioreactors effectively treat aquaculture effluent

USDA-ARS?s Scientific Manuscript database

Nutrients, in particular nitrogen and phosphorus, can create eutrophication problems in any watershed. Preventing water quality impairment requires controlling nutrients from both point-source and non-point source discharges. Woodchip bioreactors are one relatively new approach that can be utilized ...

Greywater reuse through a bioretention system prototype in the arid region.

PubMed

Chowdhury, Rezaul K

2015-01-01

The concept of a greywater-fed bioretention system in arid regions was investigated in this study. Bioretention systems are conventionally used as a source control mechanism for urban runoff. Nevertheless, in arid regions, where rain and urban runoff are not an abundant water resource, their application is limited. Greywater (residential wastewater without toilet and kitchen sources) is comparatively less polluted and has the potential for reuse in irrigation and non-potable water uses. However, selection of an appropriate treatment is a challenge. A prototype bioretention system was made and its ability to improve greywater quality was monitored for more than 10 consecutive days. A vegetative and non-vegetative system were monitored separately. After 24 hours of retention in both systems, greywater quality was improved significantly. Both systems performed almost equally well; however, the vegetative system (with canary reed grass, Phalaris arundinacea) was found to be more effective in reducing the sodium and chemical oxygen demand contents. The study revealed that the concept of the greywater-fed bioretention system has the potential to add multi-functional benefits (greywater treatment, water conservation, landscape aesthetic and biodiversity) to the arid regions' urban environment.

Impact of green roofs on stormwater quality in a South Australian urban environment.

PubMed

Razzaghmanesh, M; Beecham, S; Kazemi, F

2014-02-01

Green roofs are an increasingly important component of water sensitive urban design systems and can potentially improve the quality of urban runoff. However, there is evidence that they can occasionally act as a source rather than a sink for pollutants. In this study, the water quality of the outflow from both intensive and extensive green roof systems were studied in the city of Adelaide, South Australia over a period of nine months. The aim was to examine the effects of different green roof configurations on stormwater quality and to compare this with runoff from aluminium and asphalt roofs as control surfaces. The contaminant concentrations in runoff from both intensive and extensive green roofs generally decreased during the study period. A comparison between the two types of green roof showed that except for some events for EC, TDS and chloride, the values of the parameters such as pH, turbidity, nitrate, phosphate and potassium in intensive green roof outflows were higher than in the outflows from the extensive green roofs. These concentrations were compared to local, state, national and international water quality guidelines in order to investigate the potential for outflow runoff from green roofs to be reused for potable and non-potable purposes. The study found that green roof outflow can provide an alternative water source for non-potable purposes such as urban landscape irrigation and toilet flushing. © 2013.

Turbulent Plume Dispersion over Two-dimensional Idealized Urban Street Canyons

NASA Astrophysics Data System (ADS)

Wong, C. C. C.; Liu, C. H.

2012-04-01

Human activities are the primary pollutant sources which degrade the living quality in the current era of dense and compact cities. A simple and reasonably accurate pollutant dispersion model is helpful to reduce pollutant concentrations in city or neighborhood scales by refining architectural design or urban planning. The conventional method to estimate the pollutant concentration from point/line sources is the Gaussian plume model using empirical dispersion coefficients. Its accuracy is pretty well for applying to rural areas. However, the dispersion coefficients only account for the atmospheric stability and streamwise distance that often overlook the roughness of urban surfaces. Large-scale buildings erected in urban areas significantly modify the surface roughness that in turn affects the pollutant transport in the urban canopy layer (UCL). We hypothesize that the aerodynamic resistance is another factor governing the dispersion coefficient in the UCL. This study is thus conceived to study the effects of urban roughness on pollutant dispersion coefficients and the plume behaviors. Large-eddy simulations (LESs) are carried out to examine the plume dispersion from a ground-level pollutant source over idealized 2D street canyons in neutral stratification. Computations with a wide range of aspect ratios (ARs), including skimming flow to isolated flow regimes, are conducted. The vertical profiles of pollutant distribution for different values of friction factor are compared that all reach a self-similar Gaussian shape. Preliminary results show that the pollutant dispersion is closely related to the friction factor. For relatively small roughness, the factors of dispersion coefficient vary linearly with the friction factor until the roughness is over a certain level. When the friction factor is large, its effect on the dispersion coefficient is less significant. Since the linear region covers at least one-third of the full range of friction factor in our empirical analysis, urban roughness is a major factor for dispersion coefficient. The downstream air quality could then be a function of both atmospheric stability and urban roughness.

[Runoff Pollution Experiments of Paddy Fields Under Different Irrigation Patterns].

PubMed

Zhou, Jing-wen; Su, Bao-lin; Huang, Ning-bo; Guan, Yu-tang; Zhao, Kun

2016-03-15

To study runoff and non-point source pollution of paddy fields and to provide a scientific basis for agricultural water management of paddy fields, paddy plots in the Jintan City and the Liyang City were chosen for experiments on non-point source pollution, and flood irrigation and intermittent irrigation patterns were adopted in this research. The surface water level and rainfall were observed during the growing season of paddies, and the runoff amount from paddy plots and loads of total nitrogen (TN) and total phosphorus (TP) were calculated by different methods. The results showed that only five rain events of totally 27 rainfalls and one artificially drainage formed non-point source pollution from flood irrigated paddy plot, which resulted in a TN export coefficient of 49.4 kg · hm⁻² and a TP export coefficient of 1.0 kg · hm⁻². No any runoff event occurred from the paddy plot with intermittent irrigation even in the case of maximum rainfall of 95.1 mm. Runoff from paddy fields was affected by water demands of paddies and irrigation or drainage management, which was directly correlated to surface water level, rainfall amount and the lowest ridge height of outlets. Compared with the flood irrigation, intermittent irrigation could significantly reduce non-point source pollution caused by rainfall or artificial drainage.

Seasonal variations of dissolved organic carbon in precipitation over urban and forest sites in central Poland.

PubMed

Siudek, Patrycja; Frankowski, Marcin; Siepak, Jerzy

2015-07-01

Spatial and temporal variability of carbon species in rainwater (bulk deposition) was studied for the first time at two sites located in urban area of Poznań City and protected woodland area (Jeziory), in central Poland, between April and December 2013. The mean concentration of total carbon (TC) for the first site was 5.86 mg L(-1), whereas for the second, 5.21 mg L(-1). Dissolved organic carbon (DOC) concentration accounted for, on average, 87 and 91 % of total carbon in precipitation at urban and non-urban sites, respectively. Significant changes in TC concentrations in rainwater were observed at both sites, indicating that atmospheric transformation, transport, and removal mechanisms of carbonaceous particles were affected by seasonal fluctuations in biogenic/anthropogenic emission and meteorological conditions (i.e., precipitation height and type, atmospheric transport). During the warm season, the DOC concentration in rainwater was mostly influenced by mixed natural and anthropogenic sources. In contrast, during the cold season, the DOC concentration significantly increased mainly as a result of anthropogenic activities, i.e., intensive coal combustion, domestic wood burning, high-temperature processes, etc. In addition, during the winter measurements, significant differences in mean DOC concentration (Kruskal-Wallis test, p < 0.05) were determined for rain, mixed rain-snow, and snow samples. It was found that rainwater TOC concentration measured in Poznań and Jeziory reflected a combination of local, regional, and distant sources. Backward trajectory analysis showed that air masses advected from polluted regions in western Europe largely affect the DOC amount in rainwater, both at urban and non-urban sites. These data imply that carbonaceous compounds are of crucial importance in atmospheric chemistry and should be considered as an important parameter while considering wet deposition, reactions with different substances, especially over polluted environments.

Occurrence of selected trace metals and their oral bioaccessibility in urban soils of kindergartens and parks in Bratislava (Slovak Republic) as evaluated by simple in vitro digestion procedure.

PubMed

Hiller, Edgar; Mihaljevič, Martin; Filová, Lenka; Lachká, Lucia; Jurkovič, Ľubomír; Kulikova, Tatsiana; Fajčíková, Katarína; Šimurková, Mária; Tatarková, Veronika

2017-10-01

A total of eighty surface soil samples were collected from public kindergartens and urban parks in the city of Bratislava, and the <150µm soil fraction was evaluated for total concentrations of five metals, Cd, Cu, Hg, Pb and Zn, their oral bioaccessibilities, non-carcinogenic and carcinogenic health risks to children, and lead isotopic composition. The mean metal concentrations in urban soils (0.29, 36.1, 0.13, 30.9 and 113mg/kg for Cd, Cu, Hg, Pb and Zn, respectively) were about two times higher compared with background soil concentrations. The order of bioaccessible metal fractions determined by Simple Bioaccessibility Extraction Test was: Pb (59.9%) > Cu (43.8%) > Cd (40.8%) > Zn (33.6%) > Hg (12.8%). Variations in the bioaccessible metal fractions were mainly related to the total metal concentrations in urban soils. A relatively wide range of lead isotopic ratios in urban soils (1.1598-1.2088 for 206 Pb/ 207 Pb isotopic ratio) indicated a combination of anthropogenic and geogenic sources of metals in the soils. Lower values of 206 Pb/ 207 Pb isotopic ratio in the city centre and similar spatial distribution of total metal concentrations, together with their increasing total concentrations in soils towards the city centre, showed that traffic and coal combustion in former times were likely the major sources of soil contamination. The non-carcinogenic and carcinogenic health risks to children due to exposure to metals in kindergarten and urban park soils were low, with hazard index and cancer risk values below the threshold values at all studied sites. Copyright © 2017 Elsevier Inc. All rights reserved.

Non-exhaust emissions of PM and the efficiency of emission reduction by road sweeping and washing in the Netherlands.

PubMed

Keuken, Menno; Denier van der Gon, Hugo; van der Valk, Karin

2010-09-15

From research on PM(2.5) and PM(10) in 2007/2008 in the Netherlands, it was concluded that the coarse fraction (PM(2.5-10)) attributed 60% and 50% respectively, to the urban-regional and street-urban increments of PM(10). Contrary to Scandinavian and Mediterranean countries which exhibit significant seasonal variation in the coarse fraction of particulate matter (PM), in the Netherlands the coarse fraction in PM at a street location is rather constant during the year. Non-exhaust emissions by road traffic are identified as the main source for coarse PM in urban areas. Non-exhaust emissions mainly originate from re-suspension of accumulated deposited PM and road wear related particles, while primary tire and brake wear hardly contribute to the mass of non-exhaust emissions. However, tire and brake wear can clearly be identified in the total mass through the presence of the heavy metals: zinc, a tracer for tire wear and copper, a tracer for brake wear. The efficiency of road sweeping and washing to reduce non-exhaust emissions in a street-canyon in Amsterdam was investigated. The increments of the coarse fraction at a kerbside location and a housing façade location versus the urban background were measured at days with and without sweeping and washing. It was concluded that this measure did not significantly reduce non-exhaust emissions. Copyright 2010 Elsevier B.V. All rights reserved.

Analysis of streamflow distribution of non-point source nitrogen export from long-term urban-rural catchments to guide watershed management in the Chesapeake Bay watershed

NASA Astrophysics Data System (ADS)

Duncan, J. M.; Band, L. E.; Groffman, P.

2017-12-01

Discharge, land use, and watershed management practices (stream restoration and stormwater control measures) have been found to be important determinants of nitrogen (N) export to receiving waters. We used long-term water quality stations from the Baltimore Ecosystem Study Long-Term Ecological Research (BES LTER) Site to quantify nitrogen export across streamflow conditions at the small watershed scale. We calculated nitrate and total nitrogen fluxes using methodology that allows for changes over time; weighted regressions on time, discharge, and seasonality. Here we tested the hypotheses that a) while the largest N stream fluxes occur during storm events, there is not a clear relationship between N flux and discharge and b) N export patterns are aseasonal in developed watersheds where sources are larger and retention capacity is lower. The goal is to scale understanding from small watersheds to larger ones. Developing a better understanding of hydrologic controls on nitrogen export is essential for successful adaptive watershed management at societally meaningful spatial scales.

Anthropogenic tracers, endocrine disrupting chemicals, and endocrine disruption in Minnesota lakes

USGS Publications Warehouse

Writer, J.H.; Barber, L.B.; Brown, G.K.; Taylor, Howard E.; Kiesling, R.L.; Ferrey, M.L.; Jahns, N.D.; Bartell, S.E.; Schoenfuss, H.L.

2010-01-01

Concentrations of endocrine disrupting chemicals and endocrine disruption in fish were determined in 11 lakes across Minnesota that represent a range of trophic conditions and land uses (urban, agricultural, residential, and forested) and in which wastewater treatment plant discharges were absent. Water, sediment, and passive polar organic integrative samplers (POCIS) were analyzed for steroidal hormones, alkylphenols, bisphenol A, and other organic and inorganic molecular tracers to evaluate potential non-point source inputs into the lakes. Resident fish from the lakes were collected, and caged male fathead minnows were deployed to evaluate endocrine disruption, as indicated by the biological endpoints of plasma vitellogenin and gonadal histology. Endocrine disrupting chemicals, including bisphenol A, 17??-estradiol, estrone, and 4-nonylphenol were detected in 90% of the lakes at part per trillion concentrations. Endocrine disruption was observed in caged fathead minnows and resident fish in 90% of the lakes. The widespread but variable occurrence of anthropogenic chemicals in the lakes and endocrine disruption in fish indicates that potential sources are diverse, not limited to wastewater treatment plant discharges, and not entirely predictable based on trophic status and land use. ?? 2010.

Analysis of non-point and point source pollution in China: case study in Shima Watershed in Guangdong Province

NASA Astrophysics Data System (ADS)

Fang, Huaiyang; Lu, Qingshui; Gao, Zhiqiang; Shi, Runhe; Gao, Wei

2013-09-01

China economy has been rapidly increased since 1978. Rapid economic growth led to fast growth of fertilizer and pesticide consumption. A significant portion of fertilizers and pesticides entered the water and caused water quality degradation. At the same time, rapid economic growth also caused more and more point source pollution discharge into the water. Eutrophication has become a major threat to the water bodies. Worsening environment problems forced governments to take measures to control water pollution. We extracted land cover from Landsat TM images; calculated point source pollution with export coefficient method; then SWAT model was run to simulate non-point source pollution. We found that the annual TP loads from industry pollution into rivers are 115.0 t in the entire watershed. Average annual TP loads from each sub-basin ranged from 0 to 189.4 ton. Higher TP loads of each basin from livestock and human living mainly occurs in the areas where they are far from large towns or cities and the TP loads from industry are relatively low. Mean annual TP loads that delivered to the streams was 246.4 tons and the highest TP loads occurred in north part of this area, and the lowest TP loads is mainly distributed in middle part. Therefore, point source pollution has much high proportion in this area and governments should take measures to control point source pollution.

Anthropogenic Carbon Pump in an Urbanized Estuary

NASA Astrophysics Data System (ADS)

Park, J. H.; Yoon, T. K.; Jin, H.; Begum, M. S.

2015-12-01

The importance of estuaries as a carbon source has been increasingly recognized over the recent decades. However, constraining sources of CO2 evasion from urbanized estuaries remains incomplete, particularly in densely populated river systems receiving high loads of organic carbon from anthropogenic sources. To account for major factors regulating carbon fluxes the tidal reach of the Han River estuary along the metropolitan Seoul, characterization of organic carbon in the main stem and major urban tributaries were combined with continuous, submersible sensor measurements of pCO2 at a mid-channel location over a year and continuous underway measurements using a submersible sensor and two equilibrator sytems across the estuarine section receiving urban streams. Single-site continuous measurements exhibited large seasonal and diurnal variations in pCO2, ranging from sub-ambient air levels to exceptionally high values approaching 10,000 ppm. Diurnal variations of pCO2 were pronounced in summer and had an inverse relationship with dissolved oxygen, pointing to a potential role of day-time algal consumption of CO2. Cruise measurements displayed sharp pCO2 pulses along the confluences of urban streams as compared with relatively low values along the upper estuary receiving low-CO2 outflows from upstream dams. Large downstream increases in pCO2, concurrent with increases in DOC concentrations and fluorescence intensities indicative of microbially processed organic components, imply a translocation and subsequent dilution of CO2 carried by urban streams and/or fast transformations of labile C during transit along downstream reaches. The unique combination of spatial and temporal continuous measurements of pCO2 provide insights on estuarine CO2 pulses that might have resulted from the interplay between high loads of CO2 and organic C of anthropogenic origin and their priming effects on estuarine microbial processing of terrigenous and algal organic matter.

An assessment of landscape characteristics affecting estuarine nitrogen loading in an urban watershed.

PubMed

Yang, Xiaojun

2012-02-01

Exploring the quantitative association between landscape characteristics and the ecological conditions of receiving waters has recently become an emerging area for eco-environmental research. While the landscape-water relationship research has largely targeted on inland aquatic systems, there has been an increasing need to develop methods and techniques that can better work with coastal and estuarine ecosystems. In this paper, we present a geospatial approach to examine the quantitative relationship between landscape characteristics and estuarine nitrogen loading in an urban watershed. The case study site is in the Pensacola estuarine drainage area, home of the city of Pensacola, Florida, USA, where vigorous urban sprawling has prompted growing concerns on the estuarine ecological health. Central to this research is a remote sensor image that has been used to extract land use/cover information and derive landscape metrics. Several significant landscape metrics are selected and spatially linked with the nitrogen loading data for the Pensacola bay area. Landscape metrics and nitrogen loading are summarized by equal overland flow-length rings, and their association is examined by using multivariate statistical analysis. And a stepwise model-building protocol is used for regression designs to help identify significant variables that can explain much of the variance in the nitrogen loading dataset. It is found that using landscape composition or spatial configuration alone can explain most of the nitrogen loading variability. Of all the regression models using metrics derived from a single land use/cover class as the independent variables, the one from the low density urban gives the highest adjusted R-square score, suggesting the impact of the watershed-wide urban sprawl upon this sensitive estuarine ecosystem. Measures towards the reduction of non-point source pollution from urban development are necessary in the area to protect the Pensacola bay ecosystem and its ecosystem services. Copyright © 2011 Elsevier Ltd. All rights reserved.

Characterization of methane emissions in Los Angeles with airborne hyperspectral imaging

NASA Astrophysics Data System (ADS)

Saad, K.; Tratt, D. M.; Buckland, K. N.; Roehl, C. M.; Wennberg, P. O.; Wunch, D.

2017-12-01

As urban areas develop regulations to limit atmospheric methane (CH4), accurate quantification of anthropogenic emissions will be critical for program development and evaluation. However, relating emissions derived from process-level metadata to those determined from assimilating atmospheric observations of CH4 concentrations into models is particularly difficult. Non-methane hydrocarbons (NMHCs) can help differentiate between thermogenic and biogenic CH4 emissions, as they are primarily co-emitted with the former; however, these trace gases are subject to the same limitations as CH4. Remotely-sensed hyperspectral imaging bridges these approaches by measuring emissions plumes directly with spatial coverage on the order of 10 km2 min-1. We identify the sources of and evaluate emissions plumes measured by airborne infrared hyperspectral imagers flown over the Los Angeles (LA) metropolitan area, which encompasses various CH4 sources, including petroleum and natural gas wells and facilities. We quantify total CH4 and NMHC emissions, as well as their relative column densities, at the point-source level to create fingerprints of source types. We aggregate these analyses to estimate the range of variability in chemical composition across source types. These CH4 and NMHC emissions factors are additionally compared to their tropospheric column abundances measured by the Total Carbon Column Observing Network (TCCON) Pasadena Fourier transform infrared spectrometer, which provides a footprint for the LA basin.

Ubiquitous influence of wildfire emissions and secondary organic aerosol on summertime atmospheric aerosol in the forested Great Lakes region

NASA Astrophysics Data System (ADS)

Gunsch, Matthew J.; May, Nathaniel W.; Wen, Miao; Bottenus, Courtney L. H.; Gardner, Daniel J.; VanReken, Timothy M.; Bertman, Steven B.; Hopke, Philip K.; Ault, Andrew P.; Pratt, Kerri A.

2018-03-01

Long-range aerosol transport affects locations hundreds of kilometers from the point of emission, leading to distant particle sources influencing rural environments that have few major local sources. Source apportionment was conducted using real-time aerosol chemistry measurements made in July 2014 at the forested University of Michigan Biological Station near Pellston, Michigan, a site representative of the remote forested Great Lakes region. Size-resolved chemical composition of individual 0.5-2.0 µm particles was measured using an aerosol time-of-flight mass spectrometer (ATOFMS), and non-refractory aerosol mass less than 1 µm (PM1) was measured with a high-resolution aerosol mass spectrometer (HR-AMS). The field site was influenced by air masses transporting Canadian wildfire emissions and urban pollution from Milwaukee and Chicago. During wildfire-influenced periods, 0.5-2.0 µm particles were primarily aged biomass burning particles (88 % by number). These particles were heavily coated with secondary organic aerosol (SOA) formed during transport, with organics (average O/C ratio of 0.8) contributing 89 % of the PM1 mass. During urban-influenced periods, organic carbon, elemental carbon-organic carbon, and aged biomass burning particles were identified, with inorganic secondary species (ammonium, sulfate, and nitrate) contributing 41 % of the PM1 mass, indicative of atmospheric processing. With current models underpredicting organic carbon in this region and biomass burning being the largest combustion contributor to SOA by mass, these results highlight the importance for regional chemical transport models to accurately predict the impact of long-range transported particles on air quality in the upper Midwest, United States, particularly considering increasing intensity and frequency of Canadian wildfires.

Accuracy assessment of building point clouds automatically generated from iphone images

NASA Astrophysics Data System (ADS)

Sirmacek, B.; Lindenbergh, R.

2014-06-01

Low-cost sensor generated 3D models can be useful for quick 3D urban model updating, yet the quality of the models is questionable. In this article, we evaluate the reliability of an automatic point cloud generation method using multi-view iPhone images or an iPhone video file as an input. We register such automatically generated point cloud on a TLS point cloud of the same object to discuss accuracy, advantages and limitations of the iPhone generated point clouds. For the chosen example showcase, we have classified 1.23% of the iPhone point cloud points as outliers, and calculated the mean of the point to point distances to the TLS point cloud as 0.11 m. Since a TLS point cloud might also include measurement errors and noise, we computed local noise values for the point clouds from both sources. Mean (μ) and standard deviation (σ) of roughness histograms are calculated as (μ1 = 0.44 m., σ1 = 0.071 m.) and (μ2 = 0.025 m., σ2 = 0.037 m.) for the iPhone and TLS point clouds respectively. Our experimental results indicate possible usage of the proposed automatic 3D model generation framework for 3D urban map updating, fusion and detail enhancing, quick and real-time change detection purposes. However, further insights should be obtained first on the circumstances that are needed to guarantee a successful point cloud generation from smartphone images.

Spatial association of marine dockage with land-borne infestations of invasive termites (Isoptera: Rhinotermitidae: Coptotermes) in urban south Florida.

PubMed

Hochmair, Hartwig H; Scheffrahn, Rudolf H

2010-08-01

Marine vessels have been implicated in the anthropogenic dispersal of invasive termites for the past 500 yr. It has long been suspected that two invasive termites, the Formosan subterranean termite, Coptotermes formosanus Shiraki, and Coptotermes gestroi (Wasmann) (Isoptera: Rhinotermitidae), were introduced to and dispersed throughout South Florida by sailboats and yachts. We compared the distances between 190 terrestrial point records for Formosan subterranean termite, 177 records for C. gestroi, and random locations with the nearest marine dockage by using spatial analysis. Results show that the median distance to nearest docks associated with C. gestroi is significantly smaller than for the random points. Results also reveal that the median distance to nearest docks associated with Formosan subterranean termite is significantly smaller than for the random points. These results support the hypothesis that C. gestroi and Formosan subterranean termite are significantly closer to potential infested boat locations, i.e., marine docks, than random points in these urban areas. The results of our study suggest yet another source of aggregation in the context of exotic species, namely, hubs for pleasure boating.

Natural and Anthropogenic Water Treatment: How Riverine Ecosystem Services of Nitrogen Removal Interact with Wastewater Treatment Infrastructure in the Northeast U.S.

NASA Astrophysics Data System (ADS)

Stewart, R. J.; Wollheim, W. M.; Whittinghill, K. A.; Mineau, M.; Rosenzweig, B.

2014-12-01

The magnitude and spatial distribution of point and non-point dissolved inorganic nitrogen (N) inputs to river systems greatly influences the potential for eutrophication of downstream water bodies. Wastewater treatment plants (WWTPs), the predominant point source of N in the northeast US, remove some but not all of human waste N they receive. Excess enters rivers, which may further mitigate N concentrations by dilution and denitrification. WWTP effluent combines with upstream flows, which may include non-point sources of N due to agriculture or urbanization. Natural N removal capacities in rivers may however be overwhelmed and become N saturated, which reduces their effectiveness. As a result, natural and man-made services of N removal are intimately linked at the river network scale for provisions of suitable water quality and aquatic habitat. We assessed the summer N mitigation capacity of rivers relative to N removal in WWTPs in the northeastern U.S. using a N removal model developed within the Framework for Aquatic Modeling in the Earth System (FrAMES). The spatially distributed river network model predicts average daily dissolved inorganic nitrogen concentrations at a 3-minute river grid resolution, accounting for the mixing of natural areas, nonpoint sources, WWTP effluent, and instream denitrification, which is simulated as a function of river temperature, water residence time, and biogeochemical activity. Model validation was done using N concentration data from 750 USGS gauges across the northeast during the period 2000-2010. Confidence intervals (90%) are estimated for river N concentrations based on key uncertainties in simulated river width, uptake rates, and N loading rates. Model results suggest WWTPs potentially impact 25,770 km of river length (10.7% of total river length in the northeast) and increase N concentrations an average of 42.3% at the facility locations. The in-stream ecosystem service of N removal accounts for 2.7% of the total cumulative N removed by WWTPs during the summer in the region. Despite providing a relatively small proportion of N removal, the expected deterioration of WWTP infrastructure and associated costs of upgrading existing systems puts the role of this riverine ecosystem service into economic perspective.

Establishing strategies for a transportation MS4 : [technology transfer summary].

DOT National Transportation Integrated Search

2015-05-01

The National Pollutant Discharge Elimination System (NPDES) was established by the U.S. : Environmental Protection Agency as a means of addressing surface pollution from both known : (point) and non-specific (non-point) sources. The program impacts i...

A Workflow to Model Microbial Loadings in Watersheds ...

EPA Pesticide Factsheets

Many watershed models simulate overland and instream microbial fate and transport, but few actually provide loading rates on land surfaces and point sources to the water body network. This paper describes the underlying general equations for microbial loading rates associated with 1) land-applied manure on undeveloped areas from domestic animals; 2) direct shedding on undeveloped lands by domestic animals and wildlife; 3) urban or engineered areas; and 4) point sources that directly discharge to streams from septic systems and shedding by domestic animals. A microbial source module, which houses these formulations, is linked within a workflow containing eight models and a set of databases that form a loosely configured modeling infrastructure which supports watershed-scale microbial source-to-receptor modeling by focusing on animal-impacted catchments. A hypothetical example application – accessing, retrieving, and using real-world data – demonstrates the ability of the infrastructure to automate many of the manual steps associated with a standard watershed assessment, culminating with calibrated flow and microbial densities at the pour point of a watershed. Presented at 2016 Biennial Conference, International Environmental Modelling & Software Society.

Estimate of main local sources to ambient ultrafine particle number concentrations in an urban area

NASA Astrophysics Data System (ADS)

Rahman, Md Mahmudur; Mazaheri, Mandana; Clifford, Sam; Morawska, Lidia

2017-09-01

Quantifying and apportioning the contribution of a range of sources to ultrafine particles (UFPs, D < 100 nm) is a challenge due to the complex nature of the urban environments. Although vehicular emissions have long been considered one of the major sources of ultrafine particles in urban areas, the contribution of other major urban sources is not yet fully understood. This paper aims to determine and quantify the contribution of local ground traffic, nucleated particle (NP) formation and distant non-traffic (e.g. airport, oil refineries, and seaport) sources to the total ambient particle number concentration (PNC) in a busy, inner-city area in Brisbane, Australia using Bayesian statistical modelling and other exploratory tools. The Bayesian model was trained on the PNC data on days where NP formations were known to have not occurred, hourly traffic counts, solar radiation data, and smooth daily trend. The model was applied to apportion and quantify the contribution of NP formations and local traffic and non-traffic sources to UFPs. The data analysis incorporated long-term measured time-series of total PNC (D ≥ 6 nm), particle number size distributions (PSD, D = 8 to 400 nm), PM2.5, PM10, NOx, CO, meteorological parameters and traffic counts at a stationary monitoring site. The developed Bayesian model showed reliable predictive performances in quantifying the contribution of NP formation events to UFPs (up to 4 × 104 particles cm- 3), with a significant day to day variability. The model identified potential NP formation and no-formations days based on PNC data and quantified the sources contribution to UFPs. Exploratory statistical analyses show that total mean PNC during the middle of the day was up to 32% higher than during peak morning and evening traffic periods, which were associated with NP formation events. The majority of UFPs measured during the peak traffic and NP formation periods were between 30-100 nm and smaller than 30 nm, respectively. To date, this is the first application of Bayesian model to apportion different sources contribution to UFPs, and therefore the importance of this study is not only in its modelling outcomes but in demonstrating the applicability and advantages of this statistical approach to air pollution studies.

Anthropogenic and volcanic emission impacts on SO2 dynamics and acid rain profiles. Numerical study using WRF-Chem in a high-resolution modeling

NASA Astrophysics Data System (ADS)

Vela, A. V.; González, C. M.; Ynoue, R.; Rojas, N. Y.; Aristizábal, B. H.; Wahl, M.

2017-12-01

Eulerian 3-D chemistry transport models (CTM) have been widely used for the study of air quality in urban environments, becoming an essential tool for studying the impacts and dynamics of gases and aerosols on air quality. However, their use in Colombia is scarce, especially in medium-sized cities, which are experimenting a fast urban growth, increasing the risk associated with possible air pollution episodes. In the densely populated medium-sized Andean city of Manizales, Colombia - a city located on the western slopes of the central range of the Andes (urban population 368000; 2150 m.a.s.l), there is an influence of the active Nevado del Ruiz volcano, located 28 km to the southwest. This natural source emits daily gas and particle fluxes, which could influence the atmospheric chemistry of the city and neighboring towns. Hence, the zone presents a unique combination of anthropogenic and volcanic sulfur gas emissions, which affects SO2 dynamics in the urban area, influencing also in the formation of acid rain phenomenon in the city. Therefore, studies analyzing the relative contribution of anthropogenic and volcanic emission could contribute with a deep understanding about causes and dynamics of both acid rain phenomenon and ambient SO2 levels in Manizales. This work aimed to analyze the influence of anthropogenic (on-road vehicular and industrial point-sources) and volcanic sulfur emissions in SO2 atmospheric chemistry dynamics, evaluating its possible effects on acid rain profiles. Ambient SO2 levels and day-night rain samples were measured and used to analyze results obtained from the application of the fully-coupled on-line WRF-Chem model. Two high-resolution simulations were performed during two dry and wet one-week periods in 2015. Analysis of SO2 dispersion patterns and comparison with SO2 observations in the urban area were performed for three different scenarios in which natural and anthropogenic emissions were simulated separately. Results suggest that industrial point-source emissions had a higher influence in urban SO2 formation, suggesting also reasons of higher acidity levels during daytime periods, pattern obtained when comparing acid rain day-night profiles from rain samples measurements.

Investigating Diesel Engines as an Atmospheric Source of Isocyanic Acid in Urban Areas

NASA Astrophysics Data System (ADS)

Farmer, D.; Jathar, S.; Heppding, C.; Link, M.; Akherati, A.; Kleeman, M.; De Gouw, J. A.; Veres, P. R.; Roberts, J. M.

2017-12-01

Isocyanic acid (HNCO), an acidic gas found in tobacco smoke, urban environments and biomass burning-affected regions, has been linked to adverse health outcomes. Gasoline- and diesel-powered engines and biomass burning are known to emit HNCO and hypothesized to emit precursors such as amides that can photochemically react to produce HNCO in the atmosphere. Increasingly, diesel engines in developed countries like the United States are required to use Selective Catalytic Reduction (SCR) systems to reduce tailpipe emissions of oxides of nitrogen. SCR chemistry is known to produce HNCO as an intermediate product, and SCR systems have been implicated as an atmospheric source of HNCO. In this work, we measure HNCO emissions from an SCR system-equipped diesel engine and, in combination with earlier data, use a three-dimensional chemical transport model (CTM) to simulate the ambient concentrations and source/pathway contributions to HNCO in an urban environment. Engine tests were conducted at three different engine loads, using two different fuels and at multiple operating points. HNCO was measured using an acetate chemical ionization mass spectrometer. The diesel engine was found to emit primary HNCO (3-90 mg kg-fuel-1) but we did not find any evidence that the SCR system or other aftertreatment devices (i.e., oxidation catalyst and particle filter) produced or enhanced HNCO emissions. The CTM predictions compared well with the only available observational data sets for HNCO in urban areas but under-predicted the contribution from secondary processes. The comparison implied that diesel-powered engines were the largest source of HNCO in urban areas. The CTM also predicted that daily-averaged concentrations of HNCO reached a maximum of 110 pptv but were an order of magnitude lower than the 1 ppbv level that could be associated with physiological effects in humans. Precursor contributions from other combustion sources (gasoline and biomass burning) and wintertime conditions could enhance HNCO concentrations but need to be explored in future work.

Investigating diesel engines as an atmospheric source of isocyanic acid in urban areas

NASA Astrophysics Data System (ADS)

Jathar, Shantanu H.; Heppding, Christopher; Link, Michael F.; Farmer, Delphine K.; Akherati, Ali; Kleeman, Michael J.; de Gouw, Joost A.; Veres, Patrick R.; Roberts, James M.

2017-07-01

Isocyanic acid (HNCO), an acidic gas found in tobacco smoke, urban environments, and biomass-burning-affected regions, has been linked to adverse health outcomes. Gasoline- and diesel-powered engines and biomass burning are known to emit HNCO and hypothesized to emit precursors such as amides that can photochemically react to produce HNCO in the atmosphere. Increasingly, diesel engines in developed countries like the United States are required to use selective catalytic reduction (SCR) systems to reduce tailpipe emissions of oxides of nitrogen. SCR chemistry is known to produce HNCO as an intermediate product, and SCR systems have been implicated as an atmospheric source of HNCO. In this work, we measure HNCO emissions from an SCR system-equipped diesel engine and, in combination with earlier data, use a three-dimensional chemical transport model (CTM) to simulate the ambient concentrations and source/pathway contributions to HNCO in an urban environment. Engine tests were conducted at three different engine loads, using two different fuels and at multiple operating points. HNCO was measured using an acetate chemical ionization mass spectrometer. The diesel engine was found to emit primary HNCO (3-90 mg kg fuel-1) but we did not find any evidence that the SCR system or other aftertreatment devices (i.e., oxidation catalyst and particle filter) produced or enhanced HNCO emissions. The CTM predictions compared well with the only available observational datasets for HNCO in urban areas but underpredicted the contribution from secondary processes. The comparison implied that diesel-powered engines were the largest source of HNCO in urban areas. The CTM also predicted that daily-averaged concentrations of HNCO reached a maximum of ˜ 110 pptv but were an order of magnitude lower than the 1 ppbv level that could be associated with physiological effects in humans. Precursor contributions from other combustion sources (gasoline and biomass burning) and wintertime conditions could enhance HNCO concentrations but need to be explored in future work.

Preliminary assessment of the occurrence and possible sources of MTBE in groundwater in the United States, 1993-1994

USGS Publications Warehouse

Squillace, P.T.; Zogorski, J.S.; Wilber, W.G.; Price, C.V.

1997-01-01

The 1990 Clean Air Act Amendments require fuel oxygenates to be added to gasoline used in some metropolitan areas to reduce atmospheric concentrations of carbon monoxide or ozone. Methyl tert-butyl ether (MTBE), is the most commonly used fuel oxygenate and is a relatively new gasoline additive. Nevertheless, out of 60 volatile organic chemicals analyzed, MTBE was the second most frequently detected chemical in samples of shallow ambient groundwater from urban areas that were collected during 1993-94 as part of the U.S. Geological Survey's National Water-Quality Assessment Program. Samples were collected from 5 drinking-water wells, 12 springs, and 1g3 monitoring wells in urban areas. No MTBE was detected in drinking-water wells. At a reporting level of 0.2 ??g/L, MTBE was detected most frequently in shallow groundwater from urban areas (27% of 210 wells and springs sampled in 8 areas) as compared to shallow groundwater from agricultural areas (1.3% of 549 wells sampled in 21 areas) or deeper groundwater from major aquifers (1.0% of 412 wells sampled in 9 areas). Only 3% of the shallow wells sampled in urban areas had concentrations of MTBE that exceed 20 ??g/L, which is the estimated lower limit of the United States Environmental Protection Agency draft lifetime drinking water health advisory. Because MTBE is persistent and mobile in groundwater) it can move from shallow to deeper aquifers with time. In shallow urban groundwater, MTBE generally was not found with benzene, toluene, ethylbenzene, or xylenes (BTEX) compounds which commonly are associated with gasoline spills. This disassociation causes uncertainty as to the source of MTBE. Possible sources of MTBE in groundwater include point sources, such as leaking storage tanks, and nonpoint sources, such as recharge of precipitation and storm-water runoff.

A preliminary assessment of the occurrence and possible sources of MTBE in ground water of the United States, 1993-94

USGS Publications Warehouse

Squillace, P.J.

1995-01-01

The 1990 Clean Air Act Amendments require fuel oxygenates to be added to gasoline used in some metropolitan areas to reduce atmospheric concen- trations of carbon monoxide or ozone. Methyl tert-butyl ether (MTBE), is the most commonly used fuel oxygenate and is a relatively new gasoline additive. Nevertheless, out of 60 volatile organic chemicals analyzed, MTBE was the second most frequently detected chemical in samples of shallow ambient ground water from urban areas that were collected during 1993-94 as part of the U.S. Geological Survey's National Water-Quality Assessment program. Samples were collected from 5 drinking-water wells, 12 springs, and 193 monitoring wells in urban areas. No MTBE was detected in drinking-water wells. At a reporting level of 0.2 ug/L (micrograms per liter), MTBE was detected most frequently in shallow ground water from urban areas (27 percent of 210 wells and springs sampled in 8 areas) as compared to shallow ground water from agricultural areas (1.3 percent of 549 wells sampled in 21 areas) or deeper ground water from major aquifers (1 percent of 412 wells sampled in 9 areas). Only 3 percent of the shallow wells sampled in urban areas had concentrations of MTBE that exceed 20 ug/L, which is the estimated lower limit of the U.S. Environmental Protection Agency draft drinking-water health advisory. Because MTBE is persistent and mobile in ground water, it can move from shallow to deeper aquifers with time. In shallow urban ground water, MTBE generally was not found with benzene, toluene, ethylbenzene, or xylenes (BTEX) compounds which commonly are associated with gasoline spills. This disassociation causes uncertainty as to the source of MTBE. Possible sources of MTBE in ground water include point sources, such as leaking storage tanks, and nonpoint sources, such as recharge of precipitation and storm-water runoff.

Prevalence of organic and inorganic contaminants within a rapidly developing catchment

NASA Astrophysics Data System (ADS)

Njumbe, E. S.; Curtis, C. D.; Cooke, D. A.; Polya, D. A.; Wogelius, R. A.; Hughes, C.

2003-04-01

Industrialization rates in many developing countries typically outpace investment in water supply, sewage treatment and other waste water facilities. This is futher compounded by the absence of stringent land-use and waste disposal policies. The consequence of this has been contamination of land, surface water, and groundwater in such areas. Efforts to control and remediate these types of systems will rely on a thorough understanding of contaminant levels and mobility. Reliable data, however, is usually not available. Therefore this study was designed to acquire baseline data from a representative developing urban area in tropical west Africa. 43 water and 20 sediment/soil samples from streams, hand-dug wells, springs and deep boreholes within the city and surrounding areas of Douala in Cameroon were characterised. Analyses were aimed at obtaining information on the type and quantity of organic and inorganic contaminants present, and linking them to specific point and non-point sources. Results from gas chromatography (GC/FID) and gas chromatography/mass spectrometry analyses of total organic extracts (TOE) of water samples have revealed the presence of a wide range of organic compounds including phenols, polycyclic aromatic hydrocarbons (PAHs), volatile organic compounds (VOCs), phthalates, acids and aliphatic derivatives. Concentrations as high as 500 ng ml-1 were detected. These high levels of non-polar compounds measured in drinking water represent a clear health problem. Heavy metal concentrations in bulk alluvial sands and loamy soil have been determined by microwave assisted nitric acid digestion. Concentration ranges (in ppm of dry weight) for the important metals were: Cr, 3.2-84.2 ; Ni, 0.2-57.4 ; Zn, 2.1-92 ; Pb, 0.3-33 ; As, 0.081-9.4 ; Cu, 0.61-17.4 ; and Cd, 0-3.1. Point sources have been identified for several of the organic and inorganic compounds and this spatial information will be integrated with the chemical data to present an overview of environmental degradation within this system.

Distribution of tetracycline resistance genes and AmpC β-lactamase genes in representative non-urban sewage plants and correlations with treatment processes and heavy metals.

PubMed

Xu, Yan-Bin; Hou, Mao-Yu; Li, Ya-Fei; Huang, Lu; Ruan, Jing-Jing; Zheng, Li; Qiao, Qing-Xia; Du, Qing-Ping

2017-03-01

The mixed development of livestock breeding and industry in non-urban zones is a very general phenomenon in China. Distribution of antibiotic resistance genes (ARGs) in non-urban sewage treatment systems has not been paid enough attentions. In this study, eleven tetracycline resistance genes (tetA, tetB, tetC, tetE, tetG, tetL, tetM, tetO, tetQ, tetS and tetX), four AmpC β-lactamase genes (EBC, MOX, FOX and CIT) and four heavy metals (Cu, Zn, Cd and Pb) were detected and analyzed in four non-urban sewage plants with different sewage sources and different treatment processes in Guangzhou. The results showed that tetA and tetC were the most prevalent tetracycline resistance genes with the same detection frequency of 85% and EBC was the most prevalent AmpC β-lactamase gene with a detection frequency of 75%. The relative abundance of tetracycline resistance genes was approximately 1.6 orders of magnitudes higher than that of AmpC β-lactamase genes in all samples. A/O was the most effective process for the non-urban sewage plant receiving industrial or agricultural wastewater. Sedimentation was the most key process to eliminate ARGs from liquid phase. Most ARGs were carried in excess sludge rather than effluent. Significant correlation was found between the tet gene and Zn (r = 0.881, p < 0.01), followed by the AmpC gene and Cu (r = 0.847, p < 0.01), the tet gene and Cu (r = 0.714, p < 0.05). Therefore, the pollution of ARGs in the sewage treatment systems of non-urban zones co-polluted by heavy metals should be paid more attentions. Copyright © 2016 Elsevier Ltd. All rights reserved.

Health Literacy and Sources of Health Information for Caregivers of Urban Children with Asthma

PubMed Central

Fagnano, Maria; Halterman, Jill S.; Conn, Kelly M.; Shone, Laura P.

2012-01-01

Little is known about the resources urban caregivers of children with asthma use to obtain health information. We analyzed data for 304 families of children with persistent asthma to describe: 1) sources of health information, 2) access and use of Internet resources, and 3) the association between caregiver’s health literacy (HL) and use of health information sources. Overall, 37% of caregivers had Limited HL. Most families received health information from: a health care professional (94%); written sources (51%); family/friends (42%); non-print media (34%); and Internet (30%). Less than ½ of caregivers had access to Internet at home, but 73% reported Internet use in the past year. Caregivers with Adequate HL were more likely to obtain information from multiple sources, and to use and have access to the Internet. Our results suggest that HL is associated with where caregivers obtain health information for their children and their use of the Internet. PMID:21911409

Comparison of the air pollution biomonitoring ability of three Tillandsia species and the lichen Ramalina celastri in Argentina.

PubMed

Bermudez, Gonzalo M A; Rodriguez, Judith H; Pignata, María L

2009-01-01

Bioaccumulation ability and response to air pollution sources were evaluated for Tillandsia capillaris Ruíz and Pav. f. capillaris, T. recurvata L., T. tricholepis Baker and the lichen Ramalina celastri (Spreng.) Krog. and Swinsc. Epiphyte samples collected from a non contaminated area in the province of Córdoba were transplanted to a control site and three areas categorised according to agricultural, urban and industrial (metallurgical and metal-mechanical) emission sources. Bioindicators were exposed for 3-, 6- and 9-month periods. A foliar damage index was established for Tillandsia and a pollution index for the lichen, and S, Fe, Mn and Zn concentrations were determined. An order of efficiency for the species and conditions studied is proposed taking into account heavy metal accumulation: T. recurvata >T. tricholepis >R. celastri >T. capillaris. All species studied showed Mn to be related to agricultural activity and Fe to industries and soil particles, and Zn was related to urban and industrial sources. As far as physiological response is concerned, T. tricholepis and T. capillaris were more sensitive to agricultural activities, whereas T. recurvata was sensitive to urban and industrial sources, and only partially to agricultural sources. No relationship was found for R. celastri.

Exposures to Transit and Other Sources of Noise among New York City Residents

PubMed Central

Neitzel, Richard L.; Gershon, Robyn R. M.; McAlexander, Tara P.; Magda, Lori A.; Pearson, Julie M.

2015-01-01

To evaluate the contributions of common noise sources to total annual noise exposures among urban residents and workers, we estimated exposures associated with five common sources (use of mass transit, occupational and non-occupational activities, MP3 player and stereo use, and time at home and doing other miscellaneous activities) among a sample of over 4500 individuals in New York City (NYC). We then evaluated the contributions of each source to total noise exposure and also compared our estimated exposures to the recommended 70 dBA annual exposure limit. We found that one in ten transit users had noise exposures in excess of the recommended exposure limit from their transit use alone. When we estimated total annual exposures, 90% of NYC transit users and 87% of nonusers exceeded the recommended limit. MP3 player and stereo use, which represented a small fraction of the total annual hours for each subject on average, was the primary source of exposure among the majority of urban dwellers we evaluated. Our results suggest that the vast majority of urban mass transit riders may be at risk of permanent, irreversible noise-induced hearing loss and that, for many individuals, this risk is driven primarily by exposures other than occupational noise. PMID:22088203

Reducing errors in aircraft atmospheric inversion estimates of point-source emissions: the Aliso Canyon natural gas leak as a natural tracer experiment

NASA Astrophysics Data System (ADS)

Gourdji, S. M.; Yadav, V.; Karion, A.; Mueller, K. L.; Conley, S.; Ryerson, T.; Nehrkorn, T.; Kort, E. A.

2018-04-01

Urban greenhouse gas (GHG) flux estimation with atmospheric measurements and modeling, i.e. the ‘top-down’ approach, can potentially support GHG emission reduction policies by assessing trends in surface fluxes and detecting anomalies from bottom-up inventories. Aircraft-collected GHG observations also have the potential to help quantify point-source emissions that may not be adequately sampled by fixed surface tower-based atmospheric observing systems. Here, we estimate CH4 emissions from a known point source, the Aliso Canyon natural gas leak in Los Angeles, CA from October 2015–February 2016, using atmospheric inverse models with airborne CH4 observations from twelve flights ≈4 km downwind of the leak and surface sensitivities from a mesoscale atmospheric transport model. This leak event has been well-quantified previously using various methods by the California Air Resources Board, thereby providing high confidence in the mass-balance leak rate estimates of (Conley et al 2016), used here for comparison to inversion results. Inversions with an optimal setup are shown to provide estimates of the leak magnitude, on average, within a third of the mass balance values, with remaining errors in estimated leak rates predominantly explained by modeled wind speed errors of up to 10 m s‑1, quantified by comparing airborne meteorological observations with modeled values along the flight track. An inversion setup using scaled observational wind speed errors in the model-data mismatch covariance matrix is shown to significantly reduce the influence of transport model errors on spatial patterns and estimated leak rates from the inversions. In sum, this study takes advantage of a natural tracer release experiment (i.e. the Aliso Canyon natural gas leak) to identify effective approaches for reducing the influence of transport model error on atmospheric inversions of point-source emissions, while suggesting future potential for integrating surface tower and aircraft atmospheric GHG observations in top-down urban emission monitoring systems.

Toxicity characterization of urban stormwater with bioanalytical tools.

PubMed

Tang, Janet Y M; Aryal, Rupak; Deletic, Ana; Gernjak, Wolfgang; Glenn, Eva; McCarthy, David; Escher, Beate I

2013-10-01

Stormwater harvesting has become an attractive alternative strategy to address the rising demand for urban water supply due to limited water sources and population growth. Nevertheless, urban stormwater is also a major source of surface water pollution. Runoff from different urban catchments with source contributions from anthropogenic activities and various land uses causes variable contaminant profiles, thus posing a challenging task for environmental monitoring and risk assessment. A thorough understanding of raw stormwater quality is essential to develop appropriate treatment facilities for potential indirect potable reuse of stormwater. While some of the key chemical components have previously been characterized, only scarce data are available on stormwater toxicity. We benchmarked stormwater samples from urban, residential and industrial sites across various Australian capital cities against samples from the entire water cycle, from sewage to drinking water. Six biological endpoints, targeting groups of chemicals with modes of toxic action of particular relevance for human and environmental health, were investigated: non-specific toxicity (Microtox and combined algae test), the specific modes of action of phytotoxicity (combined algae test), dioxin-like activity (AhR-CAFLUX), and estrogenicity (E-SCREEN), as well as reactive toxicity encompassing genotoxicity (umuC) and oxidative stress (AREc32). Non-specific toxicity was highly variable across sites. The baseline toxicity equivalent concentrations of the most polluted samples were similar to secondary treated effluent from wastewater treatment plants. Phytotoxicity results correlated well with the measured herbicide concentrations at all sites. High estrogenicity was found in two sampling events and could be related to sewage overflow. Genotoxicity, dioxin-like activity, and oxidative stress response were evident in only three of the samples where the stormwater drain was beside a heavy traffic road, confirming that road runoff is the potential source of contaminants, while the bioanalytical equivalent concentrations (BEQ) of these samples were similar to those of raw sewage. This study demonstrates the benefit of bioanalytical tools for screening-level stormwater quality assessment, forming the basis for the evaluation of future stormwater treatment and reuse schemes. Copyright © 2013 Elsevier Ltd. All rights reserved.

Use of the semipermeable membrane device (SPMD) to sample polycyclic aromatic hydrocarbon pollution in a lotic system

USGS Publications Warehouse

Lebo, Jon A.; Zajicek, James L.; Orazio, Carl E.; Petty, Jimmie D.; Huckins, James; Douglas, Ernest H.

1996-01-01

Relative concentrations of aqueous polycyclic aromatic hydrocarbons (PAH) were investigated in an urban creek. Samples were obtained at five sites within a 600-m segment of the creek that is critical habitat for an endangered species of fish. the sampling technique entailed immersion of semipermeable membrane devices (SPMDs) in the water for intervals as long as 64 d. SPMDs are passive, in situ, mtegrative samplers of bioavailable (truly dissolved) PAH and other hydrophobic organic contaminants. Two point sources of PAH to the 600-m segment of the creek were differentiated. Aqueous concentrations were found to wane dramatically over the relatively short section of the creek between the point sources. All samples were almost devoid of alkyl-substituted PAH, indicating that the ultimate sources were probably of pyrogenic nature.

Empowerment in practice - insights from CITI-SENSE project in Ljubljana

NASA Astrophysics Data System (ADS)

Robinson, Johanna; Kocman, David; Smolnikar, Miha; Mohorčič, Miha; Horvat, Milena

2014-05-01

We present specifics of the citizen empowerment and crowd sourced citizen science conducted in Ljubljana, Slovenia, as one of the case study cities within the ongoing EU-project CITI-SENSE. CITI-SENSE addresses urban air quality and rests on three pillars: technological platforms for distributed monitoring; novel information and communication technologies; and citizen participation. In the project, empowerment initiatives are conducted, enabling citizens to participate in various aspects of urban air quality, both outdoor and indoor at schools affecting everyday life of societal groups. Each participating country runs its own citizen empowerment campaign adapting to local circumstances. In addition to Ljubljana, local campaigns have been initiated in Barcelona, Belgrade, Edinburgh, Haifa, Ljubljana, Oslo, Ostrava, Vienna and in Vitoria. Poor air quality has been recognized as an important factor affecting the quality of life, especially in urban environments. In Ljubljana specifically, the main air pollution sources are traffic-related emissions, individual house heating devices including increased use of coal and biomass in recent years, and to a limit extent industrial point sources and waste disposal sites. Air quality can be occasionally very poor due to specific climatic conditions owing partially to its location in a basin and on the marshes, resulting in a very complex circulation of air masses, temperature inversions and formation of urban heat island. By recognizing this, we established the main stakeholders in the city who are responsible for monitoring the quality of air in Ljubljana. Based on full stakeholder analysis we consider co-operation with local governmental- and non-governmental institutions with already established means of communications with citizens, as a tool for empowerment. Since we spend over 90% of our time indoors, the indoor air quality is of great importance. It is why the CITI-SENSE project empowerment initiatives also cover this aspect. In Ljubljana we have identified and are involving three schools; differing by location, house type and age of students. The project also gives children a unique approach to learning about air quality issues - by being involved. To evaluate the success of empowerment initiatives after a pilot phase, key performance indicators (KPI) were defined that will enable performance improvement for the full implementation phase of the project. Acknowledgements: CITI-SENSE is a Collaborative Project partly funded by the EU FP7-ENV-2012 under grant agreement no 308524. www.citi-sense.eu.

Extraction of Urban Trees from Integrated Airborne Based Digital Image and LIDAR Point Cloud Datasets - Initial Results

NASA Astrophysics Data System (ADS)

Dogon-yaro, M. A.; Kumar, P.; Rahman, A. Abdul; Buyuksalih, G.

2016-10-01

Timely and accurate acquisition of information on the condition and structural changes of urban trees serves as a tool for decision makers to better appreciate urban ecosystems and their numerous values which are critical to building up strategies for sustainable development. The conventional techniques used for extracting tree features include; ground surveying and interpretation of the aerial photography. However, these techniques are associated with some constraint, such as labour intensive field work, a lot of financial requirement, influences by weather condition and topographical covers which can be overcome by means of integrated airborne based LiDAR and very high resolution digital image datasets. This study presented a semi-automated approach for extracting urban trees from integrated airborne based LIDAR and multispectral digital image datasets over Istanbul city of Turkey. The above scheme includes detection and extraction of shadow free vegetation features based on spectral properties of digital images using shadow index and NDVI techniques and automated extraction of 3D information about vegetation features from the integrated processing of shadow free vegetation image and LiDAR point cloud datasets. The ability of the developed algorithms shows a promising result as an automated and cost effective approach to estimating and delineated 3D information of urban trees. The research also proved that integrated datasets is a suitable technology and a viable source of information for city managers to be used in urban trees management.

Air Pollution Surveillance Systems

ERIC Educational Resources Information Center

Morgan, George B.; And Others

1970-01-01

Describes atmospheric data monitoring as part of total airpollution control effort. Summarizes types of gaseous, liquid and solid pollutants and their sources; contrast between urban and rural environmental air quality; instrumentation to identify pollutants; and anticipated new non-wet chemical physical and physiochemical techniques tor cetection…

TRADING STORMWATER ABATEMENT CREDITS IN CINCINNATI'S SHEPHERD CREEK

EPA Science Inventory

The problem of stormwater runoff management grows apace with continued urbanization, yet the management tools for this growning non-profit source problem have not fully kept pace. The rapid growth of stormwater utilities around the nation is an important step toward providing an...

Relative importance of wastewater treatment plants and non-point sources of perfluorinated compounds to Washington State rivers.

PubMed

Furl, Chad V; Meredith, Callie A; Strynar, Mark J; Nakayama, Shoji F

2011-07-01

Perfluorinated compounds (PFCs) were measured in 10 Washington State rivers and 4 wastewater treatment plants (WWTPs) under periods of low and high flows to investigate the relative importance of point and non-point sources to rivers. PFCs were detected in all samples with summed values ranging from 1.11 to 74.9 ng/L in surface waters and 62.3-418 ng/L in WWTP effluent. Concentrations in 6 of the 10 rivers exhibited a positive relationship with flow, indicating runoff as a contributing source, with PFC loads greatest at all 10 waterbodies during high flows. Perfluoroheptanoic acid:perfluorooctanoic acid homologue ratios suggest atmospheric contributions to the waterbodies are important throughout the year. Principal component analysis (PCA) indicated distinct homologue profiles for high flow, low flow, and effluent samples. The PCA demonstrates that during the spring when flows and loads are at their greatest; WWTP discharges are not the primary sources of PFCs to the river systems. Taken together, the evidence provided signifies non-point inputs are a major pathway for PFCs to surface waters in Washington State. Copyright © 2011 Elsevier B.V. All rights reserved.

Development and application of a high resolution hybrid modelling system for the evaluation of urban air quality

NASA Astrophysics Data System (ADS)

Pepe, N.; Pirovano, G.; Lonati, G.; Balzarini, A.; Toppetti, A.; Riva, G. M.; Bedogni, M.

2016-09-01

A hybrid modelling system (HMS) was developed to provide hourly concentrations at the urban local scale. The system is based on the combination of a meteorological model (WRF), a chemical and transport eulerian model (CAMx), which computes concentration levels over the regional domains, and a lagrangian dispersion model (AUSTAL2000), accounting for dispersion phenomena within the urban area due to local emission sources; a source apportionment algorithm is also included in the HMS in order to avoid the double counting of local emissions. The HMS was applied over a set of nested domains, the innermost covering a 1.6 × 1.6 km2 area in Milan city center with 20 m grid resolution, for NOX simulation in 2010. For this paper the innermost domain was defined as ;local;, excluding usual definition of urban areas. WRF model captured the overall evolution of the main meteorological features, except for some very stagnant situations, thus influencing the subsequent performance of regional scale model CAMx. Indeed, CAMx was able to reproduce the spatial and temporal evolution of NOX concentration over the regional domain, except a few episodes, when observed concentrations were higher than 100 ppb. The local scale model AUSTAL2000 provided high-resolution concentration fields that sensibly mirrored the road and traffic pattern in the urban domain. Therefore, the first important outcome of the work is that the application of the hybrid modelling system allowed a thorough and consistent description of urban air quality. This result represents a relevant starting point for future evaluation of pollution exposure within an urban context. However, the overall performance of the HMS did not provide remarkable improvements with respect to stand-alone CAMx at the two only monitoring sites in Milan city center. HMS results were characterized by a smaller average bias, that improved about 6-8 ppb corresponding to 12-13% of the observed concentration, but by a lower correlation, that worsened around 1-3% (e.g. from 0.84 to 0.81 at Senato site), due to the concentration peaks produced by AUSTAL2000 during nighttime stable conditions. Additionally, the HMS results showed that it was unable to correctly take into account some local scale features (e.g. urban canyon effects), pointing out that the emission spatialization and time modulation criteria, especially those from road traffic, need further improvement. Nevertheless, a second important outcome of the work is that some of the most relevant discrepancies between modelled and observed concentrations were not related to the horizontal resolution of the dispersion models but to larger scale meteorological features not captured by the meteorological model, especially during winter period. Finally, the estimated contribution of the local emission sources accounted on the annual average for about 25-30% of the computed concentration levels in the innermost urban domain. This confirmed that the whole Milan urban area as well as the outside background areas, accounting all sources outside the innermost domain, play a key role on air quality. The result suggests that strictly local emission policies could have a limited and indecisive effect on urban air quality, although this finding could be partially biased by model underestimation of the observed concentration.

Can weekly noise levels of urban road traffic, as predominant noise source, estimate annual ones?

PubMed

Prieto Gajardo, Carlos; Barrigón Morillas, Juan Miguel; Rey Gozalo, Guillermo; Vílchez-Gómez, Rosendo

2016-11-01

The effects of noise pollution on human quality of life and health were recognised by the World Health Organisation a long time ago. There is a crucial dilemma for the study of urban noise when one is looking for proven methodologies that can allow, on the one hand, an increase in the quality of predictions, and on the other hand, saving resources in the spatial and temporal sampling. The temporal structure of urban noise is studied in this work from a different point of view. This methodology, based on Fourier analysis, is applied to several measurements of urban noise, mainly from road traffic and one-week long, carried out in two cities located on different continents and with different sociological life styles (Cáceres, Spain and Talca, Chile). Its capacity to predict annual noise levels from weekly measurements is studied. The relation between this methodology and the categorisation method is also analysed.

Major and Trace Element Fluxes to the Ganges River: Significance of Small Flood Plain Tributary as Non-Point Pollution Source

NASA Astrophysics Data System (ADS)

Lakshmi, V.; Sen, I. S.; Mishra, G.

2017-12-01

There has been much discussion amongst biologists, ecologists, chemists, geologists, environmental firms, and science policy makers about the impact of human activities on river health. As a result, multiple river restoration projects are on going on many large river basins around the world. In the Indian subcontinent, the Ganges River is the focal point of all restoration actions as it provides food and water security to half a billion people. Serious concerns have been raised about the quality of Ganga water as toxic chemicals and many more enters the river system through point-sources such as direct wastewater discharge to rivers, or non-point-sources. Point source pollution can be easily identified and remedial actions can be taken; however, non-point pollution sources are harder to quantify and mitigate. A large non-point pollution source in the Indo-Gangetic floodplain is the network of small floodplain rivers. However, these rivers are rarely studied since they are small in catchment area ( 1000-10,000 km2) and discharge (<100 m3/s). As a result, the impact of these small floodplain rivers on the dissolved chemical load of large river systems is not constrained. To fill this knowledge gap we have monitored the Pandu River for one year between February 2015 and April 2016. Pandu river is 242 km long and is a right bank tributary of Ganges with a total catchment area of 1495 km2. Water samples were collected every month for dissolved major and trace elements. Here we show that the concentration of heavy metals in river Pandu is in higher range as compared to the world river average, and all the dissolved elements shows a large spatial-temporal variation. We show that the Pandu river exports 192170, 168517, 57802, 32769, 29663, 1043, 279, 241, 225, 162, 97, 28, 25, 22, 20, 8, 4 Kg/yr of Ca, Na, Mg, K, Si, Sr, Zn, B, Ba, Mn, Al, Li, Rb, Mo, U, Cu, and Sb, respectively, to the Ganga river, and the exported chemical flux effects the water chemistry of the Ganga river downstream of its confluence point. We further speculate that small floodplain rivers is an important source that contributes to the dissolved chemical budget of large river systems, and they must be better monitored to address future challenges in river basin management.

Using Rapid Indicators for Enterococcus to Assess the Risk of Illness after Exposure to Urban Runoff Contaminated Marine Water

PubMed Central

Colford, John M.; Schiff, Kenneth C.; Griffith, John F.; Yau, Vince; Arnold, Benjamin F.; Wright, Catherine C.; Gruber, Joshua S.; Wade, Timothy J.; Burns, Susan; Hayes, Jacqueline; McGee, Charles; Gold, Mark; Cao, Yiping; Noble, Rachel T.; Haugland, Richard; Weisberg, Stephen B.

2012-01-01

Background Traditional fecal indicator bacteria (FIB) measurement is too slow (>18 hr) for timely swimmer warnings. Objectives Assess relationship of rapid indicator methods (qPCR) to illness at a marine-beach impacted by urban-runoff. Methods We measured baseline and two-week health in 9525 individuals visiting Doheny Beach 2007-08. Illness rates were compared (swimmers vs. non-swimmers). FIB measured by traditional (Enterococcus spp. by EPA Method 1600 or Enterolert™, fecal coliforms, total coliforms) and three rapid qPCR assays for Enterococcus spp. (Taqman, Scorpion-1, Scorpion-2) were compared to health. Primary bacterial source was a creek flowing untreated into ocean; the creek did not reach the ocean when a sand berm formed. This provided a natural experiment for examining FIB-health relationships under varying conditions. Results We observed significant increases in diarrhea (OR1.90, 95% CI 1.29-2.80 for swallowing water) and other outcomes in swimmers compared to non-swimmers. Exposure (body immersion, head immersion, swallowed water) was associated with increasing risk of gastrointestinal illness (GI). Daily GI incidence patterns were different: swimmers (2-day peak ) and non-swimmers (no peak). With berm-open, we observed associations between GI and traditional and rapid methods for Enterococcus; fewer associations occurred when berm status was not considered. Conclusions We found increased risk of GI at this urban-runoff beach. When FIB source flowed freely (berm-open), several traditional and rapid indicators were related to illness. When FIB source was weak (berm-closed) fewer illness-associations were seen. These different relationships under different conditions at a single beach demonstrate the difficulties using these indicators to predict health risk. PMID:22356828

Rural-urban and racial-ethnic differences in awareness of direct-to-consumer genetic testing.

PubMed

Salloum, Ramzi G; George, Thomas J; Silver, Natalie; Markham, Merry-Jennifer; Hall, Jaclyn M; Guo, Yi; Bian, Jiang; Shenkman, Elizabeth A

2018-02-23

Access to direct-to-consumer genetic testing services has increased in recent years. However, disparities in knowledge and awareness of these services are not well documented. We examined awareness of genetic testing services by rural/urban and racial/ethnic status. Analyses were conducted using pooled cross-sectional data from 4 waves (2011-2014) of the Health Information National Trends Survey (HINTS). Descriptive statistics compared sample characteristics and information sources by rural/urban residence. Logistic regression was used to examine the relationship between geography, racial/ethnic status, and awareness of genetic testing, controlling for sociodemographic characteristics. Of 13,749 respondents, 16.7% resided in rural areas, 13.8% were Hispanic, and 10.1% were non-Hispanic black. Rural residents were less likely than urban residents to report awareness of genetic testing (OR = 0.74, 95% CI = 0.63-0.87). Compared with non-Hispanic whites, racial/ethnic minorities were less likely to be aware of genetic testing: Hispanic (OR = 0.68, 95% CI = 0.56-0.82); and non-Hispanic black (OR = 0.74, 95% CI = 0.61-0.90). Rural-urban and racial-ethnic differences exist in awareness of direct-to-consumer genetic testing. These differences may translate into disparities in the uptake of genetic testing, health behavior change, and disease prevention through precision and personalized medicine.

Acetone in the atmosphere of Hong Kong: Abundance, sources and photochemical precursors

NASA Astrophysics Data System (ADS)

Guo, H.; Ling, Z. H.; Cheung, K.; Wang, D. W.; Simpson, I. J.; Blake, D. R.

2013-02-01

Intensive field measurements were carried out at a mountain site and an urban site at the foot of the mountain from September to November 2010 in Hong Kong. Acetone was monitored using both canister air samples and 2,4-dinitrophenylhydrazine cartridges. The spatiotemporal patterns of acetone showed no difference between the two sites (p > 0.05), and the mean acetone mixing ratios on O3 episode days were higher than those on non-O3 episode days at both sites (p < 0.05). The source contributions to ambient acetone at both sites were estimated using a receptor model i.e. Positive Matrix Factorization (PMF). The PMF results showed that vehicular emission and secondary formation made the most important contribution to ambient acetone, followed by the solvent use at both sites. However, the contribution of biogenic emission at the mountain site was significantly higher than that at the urban site, whereas biomass burning made more remarkable contribution at the urban site than that at the mountain site. The mechanism of oxidation formation of acetone was investigated using a photochemical box model. The results indicated that i-butene was the main precursor of secondary acetone at the mountain site, while the oxidation of i-butane was the major source of secondary acetone at the urban site.

Key Parameters for Urban Heat Island Assessment in A Mediterranean Context: A Sensitivity Analysis Using the Urban Weather Generator Model

NASA Astrophysics Data System (ADS)

Salvati, Agnese; Palme, Massimo; Inostroza, Luis

2017-10-01

Although Urban Heat Island (UHI) is a fundamental effect modifying the urban climate, being widely studied, the relative weight of the parameters involved in its generation is still not clear. This paper investigates the hierarchy of importance of eight parameters responsible for UHI intensity in the Mediterranean context. Sensitivity analyses have been carried out using the Urban Weather Generator model, considering the range of variability of: 1) city radius, 2) urban morphology, 3) tree coverage, 4) anthropogenic heat from vehicles, 5) building’s cooling set point, 6) heat released to canyon from HVAC systems, 7) wall construction properties and 8) albedo of vertical and horizontal surfaces. Results show a clear hierarchy of significance among the considered parameters; the urban morphology is the most important variable, causing a relative change up to 120% of the annual average UHI intensity in the Mediterranean context. The impact of anthropogenic sources of heat such as cooling systems and vehicles is also significant. These results suggest that urban morphology parameters can be used as descriptors of the climatic performance of different urban areas, easing the work of urban planners and designers in understanding a complex physical phenomenon, such as the UHI.

Automatic representation of urban terrain models for simulations on the example of VBS2

NASA Astrophysics Data System (ADS)

Bulatov, Dimitri; Häufel, Gisela; Solbrig, Peter; Wernerus, Peter

2014-10-01

Virtual simulations have been on the rise together with the fast progress of rendering engines and graphics hardware. Especially in military applications, offensive actions in modern peace-keeping missions have to be quick, firm and precise, especially under the conditions of asymmetric warfare, non-cooperative urban terrain and rapidly developing situations. Going through the mission in simulation can prepare the minds of soldiers and leaders, increase selfconfidence and tactical awareness, and finally save lives. This work is dedicated to illustrate the potential and limitations of integration of semantic urban terrain models into a simulation. Our system of choice is Virtual Battle Space 2, a simulation system created by Bohemia Interactive System. The topographic object types that we are able to export into this simulation engine are either results of the sensor data evaluation (building, trees, grass, and ground), which is done fully-automatically, or entities obtained from publicly available sources (streets and water-areas), which can be converted into the system-proper format with a few mouse clicks. The focus of this work lies in integrating of information about building façades into the simulation. We are inspired by state-of the art methods that allow for automatic extraction of doors and windows in laser point clouds captured from building walls and thus increase the level of details of building models. As a consequence, it is important to simulate these animationable entities. Doing so, we are able to make accessible some of the buildings in the simulation.

A real-time control framework for urban water reservoirs operation

NASA Astrophysics Data System (ADS)

Galelli, S.; Goedbloed, A.; Schwanenberg, D.

2012-04-01

Drinking water demand in urban areas is growing parallel to the worldwide urban population, and it is acquiring an increasing part of the total water consumption. Since the delivery of sufficient water volumes in urban areas represents a difficult logistic and economical problem, different metropolitan areas are evaluating the opportunity of constructing relatively small reservoirs within urban areas. Singapore, for example, is developing the so-called 'Four National Taps Strategies', which detects the maximization of water yields from local, urban catchments as one of the most important water sources. However, the peculiar location of these reservoirs can provide a certain advantage from the logistical point of view, but it can pose serious difficulties in their daily management. Urban catchments are indeed characterized by large impervious areas: this results in a change of the hydrological cycle, with decreased infiltration and groundwater recharge, and increased patterns of surface and river discharges, with higher peak flows, volumes and concentration time. Moreover, the high concentrations of nutrients and sediments characterizing urban discharges can cause further water quality problems. In this critical hydrological context, the effective operation of urban water reservoirs must rely on real-time control techniques, which can exploit hydro-meteorological information available in real-time from hydrological and nowcasting models. This work proposes a novel framework for the real-time control of combined water quality and quantity objectives in urban reservoirs. The core of this framework is a non-linear Model Predictive Control (MPC) scheme, which employs the current state of the system, the future discharges furnished by a predictive model and a further model describing the internal dynamics of the controlled sub-system to determine an optimal control sequence over a finite prediction horizon. The main advantage of this scheme stands in its reduced computational requests and the capability of exploiting real-time hydro-meteorological information, which are crucial for an effective operation of these fast-varying hydrological systems. The framework is here demonstrated on the operation of Marina Reservoir (Singapore), whose recent construction in late 2008 increased the effective catchment area to about 50% of the total available. Its operation, which accounts for drinking water supply, flash floods control and water quality standards, is here designed by combining the MPC scheme with the process-based hydrological model SOBEK. Extensive simulation experiments show the validity of the proposed framework.

Wild Ungulates as Disseminators of Shiga Toxin-Producing Escherichia coli in Urban Areas

PubMed Central

Franklin, Alan B.; VerCauteren, Kurt C.; Maguire, Hugh; Cichon, Mary K.; Fischer, Justin W.; Lavelle, Michael J.; Powell, Amber; Root, J. Jeffrey; Scallan, Elaine

2013-01-01

Background In 2008, children playing on a soccer field in Colorado were sickened with a strain of Shiga toxin-producing Escherichia coli (STEC) O157:H7, which was ultimately linked to feces from wild Rocky Mountain elk. We addressed whether wild cervids were a potential source of STEC infections in humans and whether STEC was ubiquitous throughout wild cervid populations in Colorado. Methodology/Principal Findings We collected 483 fecal samples from Rocky Mountain elk and mule deer in urban and non-urban areas. Samples testing positive for STEC were higher in urban (11.0%) than non-urban (1.6%) areas. Elk fecal samples in urban areas had a much higher probability of containing STEC, which increased in both urban and non-urban areas as maximum daily temperature increased. Of the STEC-positive samples, 25% contained stx1 strains, 34.3% contained stx2, and 13% contained both stx1 and stx2. Additionally, eaeA genes were detected in 54.1% of the positive samples. Serotypes O103, and O146 were found in elk and deer feces, which also have the potential to cause human illness. Conclusions/Significance The high incidence of stx2 strains combined with eaeA and E-hyl genes that we found in wild cervid feces is associated with severe human disease, such as hemolytic uremic syndrome. This is of concern because there is a very close physical interface between elk and humans in urban areas that we sampled. In addition, we found a strong relationship between ambient temperature and incidence of STEC in elk feces, suggesting a higher incidence of STEC in elk feces in public areas on warmer days, which in turn may increase the likelihood that people will come in contact with infected feces. These concerns also have implications to other urban areas where high densities of coexisting wild cervids and humans interact on a regular basis. PMID:24349083

Pathway Ranking for In-place Sediment Management (CU1209). Executive Summary and Site 1 Report -- Paleta Creek

DTIC Science & Technology

2006-06-01

to any specific commercial product , process, or service by trade name, trademark, manufacturer, or otherwise, does not necessarily constitute or...conditions observed at P17 and Southeast Loch are interesting from the standpoint that these areas are generally closer to industrial and non-point...metals that commonly co-occur in both industrial sources and non-point source. An examination of all fluxes suggests that the surface mixed layer may

Simulation on Change Law of Runoff, Sediment and Non-point Source Nitrogen and Phosphorus Discharge under Different Land uses Based on SWAT Model: A Case Study of Er hai Lake Small Watershed

NASA Astrophysics Data System (ADS)

Tong, Xiao Xia; Lai Cui, Yuan; Chen, Man Yu; Hu, Bo; Xu, Wen Sheng

2018-05-01

The Er yuan watershed of Er hai district is chosen as the research area, the law of runoff and sediment and non-point source nitrogen and phosphorus discharges under different land uses during 2001 to 2014 are simulated based on SWAT model. Results of simulation indicate that the order of total runoff yield of different land use type from high to low is grassland, paddy fields, dry land. Specifically, the order of surface runoff yield from high to low is paddy fields, dry land, grassland, the order of lateral runoff yield from high to low is paddy fields, dry land, grassland, the order of groundwater runoff yield from high to low is grassland, paddy fields, dry land. The orders of sediment and nitrogen and phosphorus yield per unit area of different land use type are the same, grassland> paddy fields> dry land. It can be seen, nitrogen and phosphorus discharges from paddy fields and dry land are the main sources of agricultural non-point pollution of the irrigated area. Therefore, reasonable field management measures which can decrease the discharge of nitrogen and phosphorus of paddy fields and dry land are the key to agricultural non-point source pollution prevention and control.

Semantic Labelling of Ultra Dense Mls Point Clouds in Urban Road Corridors Based on Fusing Crf with Shape Priors

NASA Astrophysics Data System (ADS)

Yao, W.; Polewski, P.; Krzystek, P.

2017-09-01

In this paper, a labelling method for the semantic analysis of ultra-high point density MLS data (up to 4000 points/m2) in urban road corridors is developed based on combining a conditional random field (CRF) for the context-based classification of 3D point clouds with shape priors. The CRF uses a Random Forest (RF) for generating the unary potentials of nodes and a variant of the contrastsensitive Potts model for the pair-wise potentials of node edges. The foundations of the classification are various geometric features derived by means of co-variance matrices and local accumulation map of spatial coordinates based on local neighbourhoods. Meanwhile, in order to cope with the ultra-high point density, a plane-based region growing method combined with a rule-based classifier is applied to first fix semantic labels for man-made objects. Once such kind of points that usually account for majority of entire data amount are pre-labeled; the CRF classifier can be solved by optimizing the discriminative probability for nodes within a subgraph structure excluded from pre-labeled nodes. The process can be viewed as an evidence fusion step inferring a degree of belief for point labelling from different sources. The MLS data used for this study were acquired by vehicle-borne Z+F phase-based laser scanner measurement, which permits the generation of a point cloud with an ultra-high sampling rate and accuracy. The test sites are parts of Munich City which is assumed to consist of seven object classes including impervious surfaces, tree, building roof/facade, low vegetation, vehicle and pole. The competitive classification performance can be explained by the diverse factors: e.g. the above ground height highlights the vertical dimension of houses, trees even cars, but also attributed to decision-level fusion of graph-based contextual classification approach with shape priors. The use of context-based classification methods mainly contributed to smoothing of labelling by removing outliers and the improvement in underrepresented object classes. In addition, the routine operation of a context-based classification for such high density MLS data becomes much more efficient being comparable to non-contextual classification schemes.

Methane - quick fix or tough target? New methods to reduce emissions.

NASA Astrophysics Data System (ADS)

Nisbet, E. G.; Lowry, D.; Fisher, R. E.; Brownlow, R.

2016-12-01

Methane is a cost-effective target for greenhouse gas reduction efforts. The UK's MOYA project is designed to improve understanding of the global methane budget and to point to new methods to reduce future emissions. Since 2007, methane has been increasing rapidly: in 2014 and 2015 growth was at rates last seen in the 1980s. Unlike 20thcentury growth, primarily driven by fossil fuel emissions in northern industrial nations, isotopic evidence implies present growth is driven by tropical biogenic sources such as wetlands and agriculture. Discovering why methane is rising is important. Schaefer et al. (Science, 2016) pointed out the potential clash between methane reduction efforts and food needs of a rising, better-fed (physically larger) human population. Our own work suggests tropical wetlands are major drivers of growth, responding to weather changes since 2007, but there is no acceptable way to reduce wetland emission. Just as sea ice decline indicates Arctic warming, methane may be the most obvious tracker of climate change in the wet tropics. Technical advances in instrumentation can do much in helping cut urban and industrial methane emissions. Mobile systems can be mounted on vehicles, while drone sampling can provide a 3D view to locate sources. Urban land planning often means large but different point sources are typically clustered (e.g. landfill or sewage plant near incinerator; gas wells next to cattle). High-precision grab-sample isotopic characterisation, using Keeling plots, can separate source signals, to identify specific emitters, even where they are closely juxtaposed. Our mobile campaigns in the UK, Kuwait, Hong Kong and E. Australia show the importance of major single sources, such as abandoned old wells, pipe leaks, or unregulated landfills. If such point sources can be individually identified, even when clustered, they will allow effective reduction efforts to occur: these can be profitable and/or improve industrial safety, for example in the case of gas leaks. Fossil fuels, landfills, waste, and biomass burning emit about 200 Tg/yr, or 35-40% of global methane emissions. Using inexpensive 3D mobile surveys coupled with high-precision isotopic measurement, it should be possible to cut emissions sharply, substantially reducing the methane burden even if tropical biogenic sources increase.

Recent Changes in Health Insurance Coverage for Urban and Rural Veterans: Evidence from the First Year of the Affordable Care Act.

PubMed

Boudreaux, Michel; Barath, Deanna; Blewett, Lynn A

2018-04-25

Prior to the Affordable Care Act, as many as 1.3 million veterans lacked health insurance. With the passage of the Affordable Care Act, veterans now have new pathways to coverage through Medicaid expansion in those states that chose to expand Medicaid and through private coverage options offered through the Health Insurance Marketplace. We examined the impact of the ACA on health insurance coverage for veterans in expansion and non-expansion states and for urban and rural veterans. We examined changes in veterans' health insurance coverage following the first year of the ACA, focusing on whether they lived in an urban or rural area and whether they live in a Medicaid expansion state. We used data on approximately 200,000 non-elderly community-dwelling veterans, obtained from the 2013-2014 American Community Survey and estimated differences in the adjusted probability of being uninsured between 2013 and 2014 for both urban and rural areas. Adjusted probabilities were computed by fitting logistic regressions controlling for age, gender, race, marital status, poverty status, education, and employment. There were an estimated 10.1 million U.S. non-elderly veterans in 2013; 82% lived in predominantly urban areas (8.3 million), and the remaining 18% (1.8 million) lived in predominately rural areas. Most veterans lived in the South (43.6%), and rural veterans were more likely to be Southerners than their urban counterparts. On every marker of economic well-being, rural veterans fared worse than urban veterans. They had a statistically significant higher chance of having incomes below 138% of FPG (20.0% versus 17.0%), of being out of the labor force (29.1% versus 23.0%), and of having no more than a high school education (39.6% versus 28.8%). Rural veterans were also more likely to experience at least one functional limitation. Overall, veterans in Medicaid expansion states experienced a significantly larger increase in insurance compared to veterans living in non-expansion states. For rural veterans in Medicaid expansion states, the increase in insurance was 3.5 percentage points, compared with 1.2 percentage points in non-expansion states. Our analysis found a substantial 24% relative decline in the rate of uninsurance for U.S. Veterans, from 9.3 to 7.1% between 2013 and 2014. We found that coverage gains in rural areas were due to gains in Medicaid and individual market coverage. Residence in a Medicaid expansion state was particularly influential for rural veterans - the increase in the insured rate was three times larger in Medicaid expansion states versus non-expansion states. The ACA has had a positive and significant impact on the ability of U.S. Veterans to obtain health insurance coverage specifically for low-income veterans living in rural areas. The poverty rate among Veterans is rising and is particularly an issue for the more recent Gulf War veterans. Providing affordable and accessible health insurance options is part of our commitment to those who have served our country. Our analysis also presents yet another reason for the 17 non-expansion states to consider a Medicaid expansion.

Characterization and first flush analysis in road and roof runoff in Shenyang, China.

PubMed

Li, Chunlin; Liu, Miao; Hu, Yuanman; Gong, Jiping; Sun, Fengyun; Xu, Yanyan

2014-01-01

As urbanization increases, urban runoff is an increasingly important component of total urban non-point source pollution. In this study, the properties of urban runoff were examined in Shenyang, in northeastern China. Runoff samples from a tiled roof, a concrete roof and a main road were analyzed for key pollutants (total suspended solids (TSS), total nitrogen (TN), total phosphorus (TP), chemical oxygen demand (COD), Pb, Cd, Cr, Cu, Ni, and Zn). The event mean concentration, site mean concentration, M(V) curves (dimensionless cumulative curve of pollutant load with runoff volume), and mass first flush ratio (MFF30) were used to analyze the characteristics of pollutant discharge and first flush (FF) effect. For all events, the pollutant concentration peaks occurred in the first half-hour after the runoff appeared and preceded the flow peaks. TN is the main pollutant in roof runoff. TSS, TN, TP, Pb, and Cr are the main pollutants in road runoff in Shenyang. There was a significant correlation between TSS and other pollutants except TN in runoff, which illustrated that TSS was an important carrier of organic matter and heavy metals. TN had strong positive correlations with total rainfall (Pearson's r = 0.927), average rainfall (Pearson's r = 0.995), and maximum rainfall intensity (Pearson's r = 0.991). TP had a strong correlation with rainfall intensity (Pearson's r = 0.940). A significant positive correlation between COD and rainfall duration (Pearson's r = 0.902, significance level = 0.05) was found. The order of FF intensity in different surfaces was concrete roof > tile roof > road. Rainfall duration and the length of the antecedent dry period were positively correlated with the FF. TN tended to exhibit strong flush for some events. Heavy metals showed a substantially stronger FF than other pollutant.

Degradation of pharmaceuticals in non-sterile urban wastewater by Trametes versicolor in a fluidized bed bioreactor.

PubMed

Cruz-Morató, Carles; Ferrando-Climent, Laura; Rodriguez-Mozaz, Sara; Barceló, Damià; Marco-Urrea, Ernest; Vicent, Teresa; Sarrà, Montserrat

2013-09-15

The constant detection of pharmaceuticals (PhACs) in the environment demonstrates the inefficiency of conventional wastewater treatment plants to completely remove them from wastewaters. So far, many studies have shown the feasibility of using white rot fungi to remove these contaminants. However, none of them have studied the degradation of several PhACs in real urban wastewater under non-sterile conditions, where mixtures of contaminants presents at low concentrations (ng L(-1) to μg L(-1)) as well as other active microorganisms are present. In this work, a batch fluidized bed bioreactor was used to study, for the first time, the degradation of PhACs present in urban wastewaters at their pre-existent concentrations under non-sterile conditions. Glucose and ammonium tartrate were continuously supplied as carbon and nitrogen source, respectively, and pH was maintained at 4.5. Complete removal of 7 out of the 10 initially detected PhACs was achieved in non-sterile treatment, while only 2 were partially removed and 1 of the PhACs analyzed increased its concentration. In addition, Microtox test showed an important reduction of toxicity in the wastewater after the treatment. Copyright © 2013 Elsevier Ltd. All rights reserved.

An improved DPSM technique for modelling ultrasonic fields in cracked solids

NASA Astrophysics Data System (ADS)

Banerjee, Sourav; Kundu, Tribikram; Placko, Dominique

2007-04-01

In recent years Distributed Point Source Method (DPSM) is being used for modelling various ultrasonic, electrostatic and electromagnetic field modelling problems. In conventional DPSM several point sources are placed near the transducer face, interface and anomaly boundaries. The ultrasonic or the electromagnetic field at any point is computed by superimposing the contributions of different layers of point sources strategically placed. The conventional DPSM modelling technique is modified in this paper so that the contributions of the point sources in the shadow region can be removed from the calculations. For this purpose the conventional point sources that radiate in all directions are replaced by Controlled Space Radiation (CSR) sources. CSR sources can take care of the shadow region problem to some extent. Complete removal of the shadow region problem can be achieved by introducing artificial interfaces. Numerically synthesized fields obtained by the conventional DPSM technique that does not give any special consideration to the point sources in the shadow region and the proposed modified technique that nullifies the contributions of the point sources in the shadow region are compared. One application of this research can be found in the improved modelling of the real time ultrasonic non-destructive evaluation experiments.

Risk assessment of population inhalation exposure to volatile organic compounds and carbonyls in urban China.

PubMed

Du, Zhengjian; Mo, Jinhan; Zhang, Yinping

2014-12-01

Over the past three decades, China has experienced rapid urbanization. The risks to its urban population posed by inhalation exposure to hazardous air pollutants (HAPs) have not been well characterized. Here, we summarize recent measurements of 16 highly prevalent HAPs in urban China and compile their distribution inputs. Based on activity patterns of urban Chinese working adults, we derive personal exposures. Using a probabilistic risk assessment method, we determine cancer and non-cancer risks for working females and males. We also assess the uncertainty associated with risk estimates using Monte Carlo simulation, accounting for variations in HAP concentrations, cancer potency factors (CPFs) and inhalation rates. Average total lifetime cancer risks attributable to HAPs are 2.27×10(-4) (2.27 additional cases per 10,000 people exposed) and 2.93×10(-4) for Chinese urban working females and males, respectively. Formaldehyde, 1,4-dichlorobenzene, benzene and 1,3-butadiene are the major risk contributors yielding the highest median cancer risk estimates, >1×10(-5). About 70% of the risk is due to exposures occurring in homes. Outdoor sources contribute most to the risk of benzene, ethylbenzene and carbon tetrachloride, while indoor sources dominate for all other compounds. Chronic exposure limits are not exceeded for non-carcinogenic effects, except for formaldehyde. Risks are overestimated if variation is not accounted for. Sensitivity analyses demonstrate that the major contributors to total variance are range of inhalation rates, CPFs of formaldehyde, 1,4-dichlorobenzene, benzene and 1,3-butadiene, and indoor home concentrations of formaldehyde and benzene. Despite uncertainty, risks exceeding the acceptable benchmark of 1×10(-6) suggest actions to reduce exposures. Future efforts should be directed toward large-scale measurements of air pollutant concentrations, refinement of CPFs and investigation of population exposure parameters. The present study is a first effort to estimate carcinogenic and non-carcinogenic risks of inhalation exposure to HAPs for the large working populations of Chinese cites. Copyright © 2014 Elsevier Ltd. All rights reserved.

The urban heat island in the city of Poznań as derived from Landsat 5 TM

NASA Astrophysics Data System (ADS)

Majkowska, Agnieszka; Kolendowicz, Leszek; Półrolniczak, Marek; Hauke, Jan; Czernecki, Bartosz

2017-05-01

To study urban heat island (UHI), Landsat 5 TM data and in situ measurements of air temperature from nine points in Poznań (Poland) for the period June 2008-May 2013 were used. Based on data from measurement points located in different types of land use, the surface urban heat island (SUHI) maps were created. All available and quality-controlled Landsat 5 TM images from 15 unique days were used to obtain the characteristics of land surface temperature (LST) and UHI intensity. In addition, spatial analysis of UHI was conducted on the basis of Corine Land Cover 2006 dataset. In situ measurements at a height of 2 m above ground level show that the UHI is a common occurrence in Poznań with a mean annual intensity of 1.0 °C. The UHI intensity is greater during the warm half of the year. Moreover, results based on the remote sensing data and the Corine Land Cover 2006 indicate that the highest value of the mean LST anomalies (3.4 °C) is attained by the continuous urban fabric, while the lowest value occurs within the broad-leaved forests (-3.1 °C). To re-count from LST to the air temperature at a height of 2 m above ground level ( T agl), linear and non-linear regression models were created. For both models, coefficients of determination equal about 0.80, with slightly higher value for the non-linear approach, which was applied to estimate the T agl spatial variability over the city of Poznań.

Concentration patterns of agricultural pesticides and urban biocides in surface waters of a catchment of mixed land use

NASA Astrophysics Data System (ADS)

Stamm, C.; Wittmer, I.; Bader, H.-P.; Scheidegger, R.; Alder, A.; Lück, A.; Hanke, I.; Singer, H.

2009-04-01

Organic pesticides and biocides that are found in surface waters, can originate from agricultural and urban sources. For a long time, agricultural pesticides have received substantially more attention than biocidal compounds from urban use like material protection or in-can preservatives (cosmetics etc.). Recent studies however revealed that the amounts of urban biocides used may exceed those of agricultural pesticides. This study aims at comparing the input of several important pesticides and biocides into a small Swiss stream with a special focus on loss events triggered by rainfall. A set of 16 substances was selected to represent urban and agricultural sources. The selected substances are either only used as biocides (irgarol, isothiazolinones, IPBC), as pesticides (atrazine, sulcotrione, dichlofluanid, tolylfluanid) or have a mixed use (isoproturon, terbutryn, terbutylazine, mecoprop, diazinon, carbendazim) The study catchment has an area of 25 km2 and is inhabited by about 12'000 people. Four sampling sites were selected in the river system in order to reflect different urban and agricultural sources. Additionally, we sampled a combined sewer overflow, a rain sewer and the outflow of a wastewater treatment plant. At each site discharge was measured continuously from March to November 2007. During 16 rain events samples were taken by automatic devices at a high temporal resolution. The results, based on more than 500 analyzed samples, revealed distinct concentration patterns for different compounds and sources. Agricultural pesticides exhibited a strong seasonality as expected based on the application periods. During the first one or two rain events after application the concentrations reached up to several thousand ng/l during peak flow (atrazine, isoproturon). The temporal patterns of urban biocides were more diverse. Some compounds obviously stem from permanent sources independent of rainfall because they were found mostly in the outlet of the wastewater treatment plant throughout the year. The insecticide diazinon for example showed a background concentration in treated waste water of approximately 50 ng/l. Substances like mecoprop, which are used in urban areas (roof protection, private gardens) and agriculture showed a mixed pattern. At the time scale of single events two concentration peaks have been observed. One of them was due to the fast reaction of sewer overflows or rain sewers carrying urban storm water. The delayed peak was caused by fast flow from agricultural soils. Overall, the study revealed complex concentration patterns for the different compounds. Source identification was only possible by means of a comprehensive approach including different nested measuring sites, a broad range of different compounds that were complemented by tracer substances like caffeine or drugs and their metabolites (sulfamethoxazole, N4-acetylsulfamethoxazole, diclofenac) that can be non-ambiguously attributed to sources like treated or untreated wastewater.

Monitoring Fecal Indicators and Pathogens in Watersheds: Implementing a Quantitative Microbial Risk Assessment Approach

EPA Science Inventory

- Many of the nation's rivers, lakes, and estuaries are impaired with fecal indicator bacteria. - Fecal contamination from point and non-point sources is responsible for the presence of fecal pathogens in source and recreational waters - Effective compliance with TMDL regulatio...

The Roots of Cultural Diversity Among American Women.

ERIC Educational Resources Information Center

Lamphere, Louise

As we reach the mid-point of the 1970's, we find women in many different positions: working and non-working, middle-class and working class, urban and rural, black and white. There are women with strong ethnic ties or religious orientations, first generation city dwellers and suburbanites. Three factors -- increased female labor force…

Advancing water resource management in agricultural, rural, and urbanizing watersheds: Enhancing University involvement

USDA-ARS?s Scientific Manuscript database

In this research editorial we make four points relative to solving water resource issues: (1) they are complex problems and difficult to solve, (2) some progress has been made on solving these issues, (3) external non-stationary drivers such as land use changes, climate change and variability, and s...

Factors affecting stream nutrient loads: A synthesis of regional SPARROW model results for the continental United States

USGS Publications Warehouse

Preston, Stephen D.; Alexander, Richard B.; Schwarz, Gregory E.; Crawford, Charles G.

2011-01-01

We compared the results of 12 recently calibrated regional SPARROW (SPAtially Referenced Regressions On Watershed attributes) models covering most of the continental United States to evaluate the consistency and regional differences in factors affecting stream nutrient loads. The models - 6 for total nitrogen and 6 for total phosphorus - all provide similar levels of prediction accuracy, but those for major river basins in the eastern half of the country were somewhat more accurate. The models simulate long-term mean annual stream nutrient loads as a function of a wide range of known sources and climatic (precipitation, temperature), landscape (e.g., soils, geology), and aquatic factors affecting nutrient fate and transport. The results confirm the dominant effects of urban and agricultural sources on stream nutrient loads nationally and regionally, but reveal considerable spatial variability in the specific types of sources that control water quality. These include regional differences in the relative importance of different types of urban (municipal and industrial point vs. diffuse urban runoff) and agriculture (crop cultivation vs. animal waste) sources, as well as the effects of atmospheric deposition, mining, and background (e.g., soil phosphorus) sources on stream nutrients. Overall, we found that the SPARROW model results provide a consistent set of information for identifying the major sources and environmental factors affecting nutrient fate and transport in United States watersheds at regional and subregional scales. ?? 2011 American Water Resources Association. This article is a U.S. Government work and is in the public domain in the USA.

A study of water hardness and the prevalence of hypomagnesaemia and hypocalcaemia in healthy subjects of Surat district (Gujarat).

PubMed

Kanadhia, Kirti C; Ramavataram, Divvi Venkata Subrahmanya Shri; Nilakhe, Shreeyas Prasad Dhanpal; Patel, Swati

2014-01-01

Various sources of drinking water, with varying levels of total hardness, and calcium and magnesium concentrations, are used by populations in different regions. The use of water purifiers can compound the problem of maintaining the desired levels of hardness. An inverse relationship between various conditions, including cardiovascular disease, and hard water has been reported. Until this study, investigation of the hardness of drinking water from different sources, and serum magnesium and calcium in normal subjects from the Surat district, had not been undertaken. This study was performed to assess the concentrations of calcium and magnesium, and total hardness in filtered and non-filtered water and the relationship with serum magnesium and calcium levels in normal subjects consuming such water. Three water samples were collected, at 15-day intervals, from 12 urban and rural areas of Surat; and also 10 different brands of bottled water. Samples were analyzed for total hardness and calcium by complexometric and EDTA methods respectively. Magnesium concentrations were obtained by subtraction of the calcium concentration from total hardness. Serum samples from healthy individuals were analyzed for magnesium and calcium using calmagite and arsenazo methods respectively. The independent t-test was used to establish significance at a level of 95%. A p-value <0.05 was considered significant. Mean total hardness, and calcium and magnesium concentrations in non-filtered, rural tube-well water were much higher than in filtered water from the same area, and the magnesium concentrations were significantly higher (p = 0.038). Filtered urban municipal had lower hardness and concentrations of calcium and magnesium (p = 0.01) compared to corresponding non-filtered water. Significantly lower levels were observed in bottled water compared to rural and urban sources of water. Serum magnesium was significantly lower in the population who were consuming filtered water compared to those drinking non-filtered water (p<0.05). No such difference was observed for serum calcium. Hypomagnesemia correlates with lower magnesium concentrations in drinking water (both rural tube-well and urban municipal waters), which can be attributed to the use of water purifiers. Assuming that a person consumes two liters of drinking water per day, it is estimated that there is an average loss of 160 mg (79%) of magnesium from total waterborne magnesium levels as a result of the filtration of both rural and urban water supplies. Bottled water is too hardness as in calcium and magnesium concentrations.

Illness concept among people with epilepsy and their caregivers and preferred treatment methods in a suburban community in Southeast Nigeria.

PubMed

Nwani, P O; Arinzechi, E O; Asomugha, A L; Enwereji, K O; Nwosu, M C; Ogunniyi, A O

2013-01-01

Epilepsy, one of the world's most prevalent chronic diseases is still regarded as a supernatural disease in many parts of the world. These superstitious and cultural beliefs tend to influence treatment seeking behavior of people living with epilepsy (PWE) and their caregivers. People living with epilepsy in a semi-urban community in Southeast Nigeria were identified in a two phase door-to-door cross-sectional descriptive study. Those identified and their caregivers were further interviewed to determine their concepts of the disease, their treatment (actual and preferred) and what informed treatment. We found 29 cases of active epilepsy, 16 (55.2%) males and 13 (44.8%) females. Witchcraft was held as a major cause of epilepsy in the community accounting for 36.2% (n=17) of the responses. The three major treatment modalities used were spiritual (healing churches), traditional (herbal medicines) and orthodox treatment with antiepileptic drugs. Spiritual treatment was the preferred treatment modality, though most (89.7%) have used traditional (herbal medicine) treatment at one point in the course of the disease. Beliefs on epilepsy and information on the disease obtained mostly from non-medical sources informed treatment. The epileptic population studied preferred spiritual treatment though use of traditional treatment was also common. Treatment seeking behavior was greatly influenced by their beliefs and information on the disease obtained mainly from non-medical sources.

A prototype for understanding the effects of TMDL standards: Tying property values to sediment loads in the Lake Tahoe Basin

USGS Publications Warehouse

Tracy, J.C.; Bernknopf, R.; Forney, W.; Hill, K.

2004-01-01

The Federal Clean Water Act (Section 303(d)) mandates that states develop Total Maximum Daily Load (TMDL) plans for water bodies that are on the Section 303(d) list. To be placed on the 303(d) list, a water body must be found to have water quality conditions that limit its ability to meet its designated beneficial uses. The TMDL for a water body is defined in 40 CFR 130 as the sum of waste load allocations from identified points sources and non-point sources within the water body's watershed. The TMDL plan for a listed water body should identify the current waste loads to the water body, the waste load capacity of the water body and then allocate the waste load capacity to the known point and non-point sources of pollution within the water body's watershed. Copyright 2004 ASCE.

Rural and urban older African caregivers coping with HIV/AIDS are nutritionally compromised.

PubMed

Kruger, Annamarie; Lekalakalamokgela, Sebi E; Wentzel-Viljoen, Edelweiss

2011-01-01

This article describes the nutritional status of a group of rural and urban free living African older surrogate parents caring for HIV/AIDS orphans and grandchildren. Multiple sources of data collection were used, including anthropometry, biochemical analyses, and quantitative questionnaires. The diets of these older participants were marginal. The rural to urban geographical transition in these older persons is characterized by a better micronutrient and trace element intake; however, urban dwellers also had higher fat intakes, increasing the risk for cardiovascular disease. These results suggest that to be a surrogate grandparent provides a special meaning to the life of men that needs to be better understood. However, the diets of these older people caring for HIV/AIDS-affected children were more compromised than those of non-caregivers.

Integrated research - water quality, sociological, economic, and modeling - in a regulated watershed: Jordan Lake, NC

Treesearch

Deanna Osmond; Mazdak Arabi; Caela O' Connell; Dana Hoag; Dan Line; Marzieh Motallebi; Ali Tasdighi

2016-01-01

Jordan Lake watershed is regulated by state rules in order to reduce nutrient loading from point and both agricultural and urban nonpoint sources. The agricultural community is expected to reduce nutrient loading by specific amounts that range from 35 - 0 percent nitrogen, and 5 - 0 percent phosphorus.

On the spatial distribution and evolution of ultrafine aerosols in urban air

NASA Astrophysics Data System (ADS)

Dall'Osto, M.; Querol, X.; Alastuey, A.; O'Dowd, C.; Harrison, R. M.; Wenger, J.; Gómez-Moreno, F. J.

2012-07-01

Sources and evolution of ultrafine particles (<0.1 μ m diameter) were investigated both horizontally and vertically in the large urban agglomerate of Barcelona, Spain. Within the SAPUSS project (Solving Aerosol Problems by Using Synergistic Strategies), a large number of instruments was deployed simultaneously at different monitoring sites (road, two urban background, regional background, urban tower 150 μa.s.l., urban background tower site 80 m a.s.l.) during a 4 week period in September-October 2010. Particle number concentrations (N>5nm) are highly correlated with black carbon (BC) at all sites only under strong vehicular traffic influences. By contrast, under clean atmospheric conditions (low condensation sinks, CS) such correlation diverges towards much higher N/BC ratios at all sites, indicating additional sources of particles including secondary production of freshly nucleated particles. This is also evident in the urban background annual mean diurnal trend of N/BC, showing a midday peak in all seasons. Size-resolved aerosol distributions (N10-500) as well as particle number concentrations (N>5nm) allow us to identify two types of nucleation and growth events: a regional type event originating in the whole study region and impacting almost simultaneously the urban city of Barcelona and the surrounding background area; and an urban type which originates only within the city centre but whose growth continues while transported away from the city to the regional background. Furthermore, during these clean air days, higher N are found at tower level than at ground level only in the city centre whereas such a difference is not so pronounced at the remote urban background tower. In other words, this study suggests that the column of air above the city ground level possesses the best compromise between low CS and high vapour source, hence enhancing the concentrations of freshly nucleated particles. By contrast, within stagnant polluted atmospheric conditions, higher N and BC concentrations are always measured at ground level relative to tower level at all sites. Our study suggests that the city centre is a source of both non-volatile traffic primary (29-39%) and secondary freshly nucleated particles (up to 61-71%) at all sites. We suggest that organic compounds evaporating from freshly emitted traffic particles are a possible candidate for new particle formation within the city and urban plume.

Study on gas diffusion emitted from different height of point source.

PubMed

Yassin, Mohamed F

2009-01-01

The flow and dispersion of stack-gas emitted from different elevated point source around flow obstacles in an urban environment have been investigated, using computational fluid dynamics models (CFD). The results were compared with the experimental results obtained from the diffusion wind tunnel under different conditions of thermal stability (stable, neutral or unstable). The flow and dispersion fields in the boundary layer in an urban environment were examined with different flow obstacles. Gaseous pollutant was discharged in the simulated boundary layer over the flat area. The CFD models used for the simulation were based on the steady-state Reynolds-Average Navier-Stoke equations (RANS) with kappa-epsilon turbulence models; standard kappa-epsilon and RNG kappa-epsilon models. The flow and dispersion data measured in the wind tunnel experiments were compared with the results of the CFD models in order to evaluate the prediction accuracy of the pollutant dispersion. The results of the CFD models showed good agreement with the results of the wind tunnel experiments. The results indicate that the turbulent velocity is reduced by the obstacles models. The maximum dispersion appears around the wake region of the obstacles.

Hierarchical extraction of urban objects from mobile laser scanning data

NASA Astrophysics Data System (ADS)

Yang, Bisheng; Dong, Zhen; Zhao, Gang; Dai, Wenxia

2015-01-01

Point clouds collected in urban scenes contain a huge number of points (e.g., billions), numerous objects with significant size variability, complex and incomplete structures, and variable point densities, raising great challenges for the automated extraction of urban objects in the field of photogrammetry, computer vision, and robotics. This paper addresses these challenges by proposing an automated method to extract urban objects robustly and efficiently. The proposed method generates multi-scale supervoxels from 3D point clouds using the point attributes (e.g., colors, intensities) and spatial distances between points, and then segments the supervoxels rather than individual points by combining graph based segmentation with multiple cues (e.g., principal direction, colors) of the supervoxels. The proposed method defines a set of rules for merging segments into meaningful units according to types of urban objects and forms the semantic knowledge of urban objects for the classification of objects. Finally, the proposed method extracts and classifies urban objects in a hierarchical order ranked by the saliency of the segments. Experiments show that the proposed method is efficient and robust for extracting buildings, streetlamps, trees, telegraph poles, traffic signs, cars, and enclosures from mobile laser scanning (MLS) point clouds, with an overall accuracy of 92.3%.

Vulnerability assessment and application of bacterial technology on urban rivers for pollution eradication.

PubMed

Hashim, Sarfraz; Yuebo, Xie; Ahmad, Fiaz; Arslan, Chaudhry; Saifullah, Muhammad

2015-01-01

To protect against the environmental pollution, the present research was undertaken to enumerate the Bacterial Technologies (BTs) on the restoration of polluted urban rivers, that is, Fenghu-Song Yang River (FSR) and Xuxi River (XXR). Experimental research accounted for the physiochemical parameters (pH; temperature; dissolved oxygen (DO); chemical oxygen demand (COD); total phosphorus (TP); total nitrogen (TN); and ammonia nitrogen (NH3N)) before and after the BT operation. The results declared that the BT is efficient to restore the polluted rivers up to reliable condition. These results were analyzed by using multivariate statistical techniques (principal component analysis (PCA) and cluster analysis (CA)). These techniques interpreted the complex data sets and expressed the point source information about the water quality of these rivers at SA5, SA6, and SB3 under highly polluted regions. For better understanding, water quality index (WQI) was applied to compute the single numeric value. WQI results are evidence of the above results which prove the water quality of both rivers faced under outrageous condition (below 50 WQI scores) before the BT treatment, but, after the treatment, the rivers were restored from fair to good level (above 50 WQI scores) and overall output of these scores was quite similar to detect the point source of pollution. These results described an abrupt recovery of the urban rivers up to reliable condition for aquatic organism and clear effluents from the rivers.

Simulation of flow and water quality of the Arroyo Colorado, Texas, 1989-99

USGS Publications Warehouse

Raines, Timothy H.; Miranda, Roger M.

2002-01-01

A model parameter set for use with the Hydrological Simulation Program—FORTRAN watershed model was developed to simulate flow and water quality for selected properties and constituents for the Arroyo Colorado from the city of Mission to the Laguna Madre, Texas. The model simulates flow, selected water-quality properties, and constituent concentrations. The model can be used to estimate a total maximum daily load for selected properties and constituents in the Arroyo Colorado. The model was calibrated and tested for flow with data measured during 1989–99 at three streamflow-gaging stations. The errors for total flow volume ranged from -0.1 to 29.0 percent, and the errors for total storm volume ranged from -15.6 to 8.4 percent. The model was calibrated and tested for water quality for seven properties and constituents with 1989–99 data. The model was calibrated sequentially for suspended sediment, water temperature, biochemical oxygen demand, dissolved oxygen, nitrate nitrogen, ammonia nitrogen, and orthophosphate. The simulated concentrations of the selected properties and constituents generally matched the measured concentrations available for the calibration and testing periods. The model was used to simulate total point- and nonpoint-source loads for selected properties and constituents for 1989–99 for urban, natural, and agricultural land-use types. About one-third to one-half of the biochemical oxygen demand and nutrient loads are from urban point and nonpoint sources, although only 13 percent of the total land use in the basin is urban.

A spatial and seasonal assessment of river water chemistry across North West England.

PubMed

Rothwell, J J; Dise, N B; Taylor, K G; Allott, T E H; Scholefield, P; Davies, H; Neal, C

2010-01-15

This paper presents information on the spatial and seasonal patterns of river water chemistry at approximately 800 sites in North West England based on data from the Environment Agency regional monitoring programme. Within a GIS framework, the linkages between average water chemistry (pH, sulphate, base cations, nutrients and metals) catchment characteristics (topography, land cover, soil hydrology, base flow index and geology), rainfall, deposition chemistry and geo-spatial information on discharge consents (point sources) are examined. Water quality maps reveal that there is a clear distinction between the uplands and lowlands. Upland waters are acidic and have low concentrations of base cations, explained by background geological sources and land cover. Localised high concentrations of metals occur in areas of the Cumbrian Fells which are subjected to mining effluent inputs. Nutrient concentrations are low in the uplands with the exception sites receiving effluent inputs from rural point sources. In the lowlands, both past and present human activities have a major impact on river water chemistry, especially in the urban and industrial heartlands of Greater Manchester, south Lancashire and Merseyside. Over 40% of the sites have average orthophosphate concentrations >0.1mg-Pl(-1). Results suggest that the dominant control on orthophosphate concentrations is point source contributions from sewage effluent inputs. Diffuse agricultural sources are also important, although this influence is masked by the impact of point sources. Average nitrate concentrations are linked to the coverage of arable land, although sewage effluent inputs have a significant effect on nitrate concentrations. Metal concentrations in the lowlands are linked to diffuse and point sources. The study demonstrates that point sources, as well as diffuse sources, need to be considered when targeting measures for the effective reduction in river nutrient concentrations. This issue is clearly important with regards to the European Union Water Framework Directive, eutrophication and river water quality. Copyright 2009 Elsevier B.V. All rights reserved.

Nitrogen dynamics in a highly urbanized coastal area of western Japan: impact of sewage-derived loads

NASA Astrophysics Data System (ADS)

Saito, Mitsuyo; Onodera, Shin-ichi; Jin, Guangzhe; Shimizu, Yuta; Taniguchi, Masanobu

2018-12-01

In this study, we examined the nitrogen dynamics of a highly urbanized coastal area, focusing on the impacts of sewage-derived nitrogen. High levels of dissolved inorganic nitrogen were detected in seawater near treated sewage effluent (TSE) discharge points before decreasing in the offshore direction, suggesting that the impact zone of sewage effluent is about 1-2 km from the discharge point. The stable isotope ratios of nitrate and particulate organic nitrogen suggest nitrogen uptake by phytoplankton as well as dilution by offshore seawater, which contributed to a decrease in sewage-derived nitrogen levels. However, the extent of the impact zone was controlled by tidal variations and differences in temperature between the TSE and seawater. Our results also identify nitrogen transport processes, through exchange between seawater and sediment pore water, as an additional important source of nitrogen in the study area.

Urban habitat fragmentation and genetic population structure of bobcats in coastal southern California

USGS Publications Warehouse

Ruell, E.W.; Riley, S.P.D.; Douglas, M.R.; Antolin, M.F.; Pollinger, J.R.; Tracey, J.A.; Lyren, L.M.; Boydston, E.E.; Fisher, R.N.; Crooks, K.R.

2012-01-01

Although habitat fragmentation is recognized as a primary threat to biodiversity, the effects of urban development on genetic population structure vary among species and landscapes and are not yet well understood. Here we use non-invasive genetic sampling to compare the effects of fragmentation by major roads and urban development on levels of dispersal, genetic diversity, and relatedness between paired bobcat populations in replicate landscapes in coastal southern California. We hypothesized that bobcat populations in sites surrounded by urbanization would experience reduced functional connectivity relative to less isolated nearby populations. Our results show that bobcat genetic population structure is affected by roads and development but not always as predicted by the degree that these landscape features surround fragments. Instead, we suggest that urban development may affect functional connectivity between bobcat populations more by limiting the number and genetic diversity of source populations of migrants than by creating impermeable barriers to dispersal.

Guiding health promotion efforts with urban Inuit: a community-specific perspective on health information sources and dissemination strategies.

PubMed

McShane, Kelly E; Smylie, Janet K; Hastings, Paul D; Martin, Carmel M

2006-01-01

To develop a community-specific perspective of health information sources and dissemination strategies of urban Inuit to better guide health promotion efforts. Through a collaborative partnership with the Tungasuvvingat Inuit Family Resource Centre, a series of key informant interviews and focus groups were conducted to gather information on specific sources of health information, strategies of health information dissemination, and overall themes in health information processes. Distinct patterns of health information sources and dissemination strategies emerged from the data. Major themes included: the importance of visual learning, community Elders, and cultural interpreters; community cohesion; and the Inuit and non-Inuit distinction. The core sources of health information are family members and sources from within the Inuit community. The principal dissemination strategy for health information was direct communication, either through one-on-one interactions or in groups. This community-specific perspective of health information sources and dissemination strategies shows substantial differences from current mainstream models of health promotion and knowledge translation. Health promotion efforts need to acknowledge the distinct health information processes of this community, and should strive to integrate existing health information sources and strategies of dissemination with those of the community.

Land use mediates riverine nitrogen export under the dominant influence of human activities

NASA Astrophysics Data System (ADS)

Chen, Binhui; Chang, Scott X.; Lam, Shu Kee; Erisman, Jan Willem; Gu, Baojing

2017-09-01

Riverine nitrogen (N) export is a crucial process that links upstream and downstream ecosystems and coastal zones. However, the driving forces of riverine N export that is closely related to water N pollution are still not well understood. In this study, we used a mass balance approach to quantify the sources of N discharge and analyzed the effect of land use composition on riverine N export, taking Zhejiang Province, China as a case study. We found that the total reactive N discharge to rivers in Zhejiang increased from 0.22 to 0.26 Tg yr-1 from 2000 to 2015. At the watershed scale, our estimate of N export agrees well with the monitored riverine N concentration in the eight major watersheds in Zhejiang. Direct discharge of domestic wastewater and effluents from wastewater treatment plants are dominant sources of riverine N export, followed by agricultural non-point sources. Although riverine N export increases with the increasing proportion of urban and agricultural land uses, we did not find any relationship between land use change and changes in riverine N export. This suggests that the dominant factor affecting riverine N export should be human activities (e.g. wastewater discharge and fertilization level), while land use only mediates riverine N export.

Metric Evaluation Pipeline for 3d Modeling of Urban Scenes

NASA Astrophysics Data System (ADS)

Bosch, M.; Leichtman, A.; Chilcott, D.; Goldberg, H.; Brown, M.

2017-05-01

Publicly available benchmark data and metric evaluation approaches have been instrumental in enabling research to advance state of the art methods for remote sensing applications in urban 3D modeling. Most publicly available benchmark datasets have consisted of high resolution airborne imagery and lidar suitable for 3D modeling on a relatively modest scale. To enable research in larger scale 3D mapping, we have recently released a public benchmark dataset with multi-view commercial satellite imagery and metrics to compare 3D point clouds with lidar ground truth. We now define a more complete metric evaluation pipeline developed as publicly available open source software to assess semantically labeled 3D models of complex urban scenes derived from multi-view commercial satellite imagery. Evaluation metrics in our pipeline include horizontal and vertical accuracy and completeness, volumetric completeness and correctness, perceptual quality, and model simplicity. Sources of ground truth include airborne lidar and overhead imagery, and we demonstrate a semi-automated process for producing accurate ground truth shape files to characterize building footprints. We validate our current metric evaluation pipeline using 3D models produced using open source multi-view stereo methods. Data and software is made publicly available to enable further research and planned benchmarking activities.

Voxel-Based Approach for Estimating Urban Tree Volume from Terrestrial Laser Scanning Data

NASA Astrophysics Data System (ADS)

Vonderach, C.; Voegtle, T.; Adler, P.

2012-07-01

The importance of single trees and the determination of related parameters has been recognized in recent years, e.g. for forest inventories or management. For urban areas an increasing interest in the data acquisition of trees can be observed concerning aspects like urban climate, CO2 balance, and environmental protection. Urban trees differ significantly from natural systems with regard to the site conditions (e.g. technogenic soils, contaminants, lower groundwater level, regular disturbance), climate (increased temperature, reduced humidity) and species composition and arrangement (habitus and health status) and therefore allometric relations cannot be transferred from natural sites to urban areas. To overcome this problem an extended approach was developed for a fast and non-destructive extraction of branch volume, DBH (diameter at breast height) and height of single trees from point clouds of terrestrial laser scanning (TLS). For data acquisition, the trees were scanned with highest scan resolution from several (up to five) positions located around the tree. The resulting point clouds (20 to 60 million points) are analysed with an algorithm based on voxel (volume elements) structure, leading to an appropriate data reduction. In a first step, two kinds of noise reduction are carried out: the elimination of isolated voxels as well as voxels with marginal point density. To obtain correct volume estimates, the voxels inside the stem and branches (interior voxels) where voxels contain no laser points must be regarded. For this filling process, an easy and robust approach was developed based on a layer-wise (horizontal layers of the voxel structure) intersection of four orthogonal viewing directions. However, this procedure also generates several erroneous "phantom" voxels, which have to be eliminated. For this purpose the previous approach was extended by a special region growing algorithm. In a final step the volume is determined layer-wise based on the extracted branch areas Ai of this horizontal cross-section multiplied by the thickness of the voxel layer. A significant improvement of this method could be obtained by a reasonable determination of the threshold for excluding sparsely filled voxels for noise reduction which can be defined based on the function change of filled voxels. Field measurements were used to validate this method. For a quality assessment nine deciduous trees were selected for control and were scanned before felling and weighing. The results are in good accordance to the control trees within a range of only -5.1% to +14.3%. The determined DBH values show only minor deviations, while the heights of trees are systematically underestimated, mainly due to field measurements. Possible error sources including gaps in surface voxels, influence of thin twigs and others are discussed in detail and several improvements of this approach are suggested. The advantages of the algorithm are the robustness and simple structure as well as the quality of the results obtained. The drawbacks are the high effort both in data acquisition and analysis, even if a remarkable data reduction can be obtained by the voxel structure.

Spatial Analysis of PAHs in Soils along an Urban-Suburban-Rural Gradient: scale effect, distribution patterns, diffusion and influencing factors

NASA Astrophysics Data System (ADS)

Peng, Chi; Wang, Meie; Chen, Weiping

2016-11-01

Spatial statistical methods including Cokriging interpolation, Morans I analysis, and geographically weighted regression (GWR) were used for studying the spatial characteristics of polycyclic aromatic hydrocarbon (PAH) accumulation in urban, suburban, and rural soils of Beijing. The concentrations of PAHs decreased spatially as the level of urbanization decreased. Generally, PAHs in soil showed two spatial patterns on the regional scale: (1) regional baseline depositions with a radius of 16.5 km related to the level of urbanization and (2) isolated pockets of soil contaminated with PAHs were found up to around 3.5 km from industrial point sources. In the urban areas, soil PAHs showed high spatial heterogeneity on the block scale, which was probably related to vegetation cover, land use, and physical soil disturbance. The distribution of total PAHs in urban blocks was unrelated to the indicators of the intensity of anthropogenic activity, namely population density, light intensity at night, and road density, but was significantly related to the same indicators in the suburban and rural areas. The moving averages of molecular ratios suggested that PAHs in the suburban and rural soils were a mix of local emissions and diffusion from urban areas.

40 CFR 430.123 - Effluent limitations guidelines representing the degree of effluent reduction attainable by the...

Code of Federal Regulations, 2010 CFR

2010-07-01

... AGENCY (CONTINUED) EFFLUENT GUIDELINES AND STANDARDS THE PULP, PAPER, AND PAPERBOARD POINT SOURCE CATEGORY Tissue, Filter, Non-Woven, and Paperboard From Purchased Pulp Subcategory § 430.123 Effluent... existing point source subject to this subpart shall achieve the following effluent limitations representing...

Delineating Contaminants and Transport Pathways Within a Coastal Watershed in Southeast Puerto Rico

USDA-ARS?s Scientific Manuscript database

Coastal water quality decline due to point and non-point source pollution from terrestrial sources is a serious concern throughout the Caribbean basin and worldwide. Toxic and noxious algal blooms, declines in mangrove forests and seagrass meadows, depletion of fishery stocks, coral reef die-off, pu...

Web-based Communication of Water Quality Issues and Potential Solution Exploration

EPA Science Inventory

Many United States water bodies are impaired, i.e., do not meet applicable water quality standards. Pollutants enter water bodies from point sources (PS) and non-point sources (NPS). Loadings from PS are regulated by the Clean Water Act and permits limit them. Loadings from NPS a...

An Improved Simulation of the Diurnally Varying Street Canyon Flow

NASA Astrophysics Data System (ADS)

Yaghoobian, Neda; Kleissl, Jan; Paw U, Kyaw Tha

2012-11-01

The impact of diurnal variation of temperature distribution over building and ground surfaces on the wind flow and scalar transport in street canyons is numerically investigated using the PArallelized LES Model (PALM). The Temperature of Urban Facets Indoor-Outdoor Building Energy Simulator (TUF-IOBES) is used for predicting urban surface heat fluxes as boundary conditions for a modified version of PALM. TUF-IOBES dynamically simulates indoor and outdoor building surface temperatures and heat fluxes in an urban area taking into account weather conditions, indoor heat sources, building and urban material properties, composition of the building envelope (e.g. windows, insulation), and HVAC equipment. Temperature (and heat flux) distribution over urban surfaces of the 3-D raster-type geometry of TUF-IOBES makes it possible to provide realistic, high resolution boundary conditions for the numerical simulation of flow and scalar transport in an urban canopy. Compared to some previous analyses using uniformly distributed thermal forcing associated with urban surfaces, the present analysis shows that resolving non-uniform thermal forcings can provide more detailed and realistic patterns of the local air flow and pollutant dispersion in urban canyons.

Characterization of traffic-related ambient fine particulate matter (PM2.5) in an Asian city: Environmental and health implications

NASA Astrophysics Data System (ADS)

Zhang, Zhi-Hui; Khlystov, Andrey; Norford, Leslie K.; Tan, Zhen-Kang; Balasubramanian, Rajasekhar

2017-07-01

Vehicular traffic emission is an important source of particulate pollution in most urban areas. The detailed chemical speciation of traffic-related PM2.5 (fine particles) is relatively sparse in the literature, especially in Asian cities. To fill this knowledge gap, we carried out an intensive field study in Singapore from November 2015 to February 2016. PM2.5 samples were collected concurrently at a typical roadside microenvironment and at an urban background site. A detailed chemical speciation of PM2.5 samples was conducted to gain insights into the emission characteristics of traffic-related fine aerosols. Analyses of diagnostic ratios and molecular markers of selected chemical species were explored for source attribution of different classes of chemical constituents in traffic-related PM2.5. The human health risk due to inhalation of the particulate-bound PAHs (polycyclic aromatic hydrocarbons) and toxic trace elements was estimated for both adults and children. The overall results of the study indicate that gasoline-powered vehicles make a higher contribution to traffic-related fine aerosol components such as organic carbon (OC), particle-bound PAHs and particulate ammonium than that of diesel-powered vehicles. However, both types of vehicles contribute to traffic-related EC emissions significantly. The combustion of petroleum fuels and lubricating oil make significant contributions to the emission of n-alkanes and hopanes into the urban atmosphere, respectively. The study further reveals that some toxic trace elements are emitted from non-exhaust sources and that aromatic acids represent an important component of secondary organic aerosols. The emission of toxic trace elements from non-exhaust sources is of particular concern as they could pose a higher carcinogenic risk to both adults and children than other chemical species.

Pollutant concentrations and pollution loads in stormwater runoff from different land uses in Chongqing.

PubMed

Wang, Shumin; He, Qiang; Ai, Hainan; Wang, Zhentao; Zhang, Qianqian

2013-03-01

To investigate the distribution of pollutant concentrations and pollution loads in stormwater runoff in Chongqing, six typical land use types were selected and studied from August 2009 to September 2011. Statistical analysis on the distribution of pollutant concentrations in all water samples shows that pollutant concentrations fluctuate greatly in rainfall-runoff, and the concentrations of the same pollutant also vary greatly in different rainfall events. In addition, it indicates that the event mean concentrations (EMCs) of total suspended solids (TSS) and chemical oxygen demand (COD) from urban traffic roads (UTR) are significantly higher than those from residential roads (RR), commercial areas (CA), concrete roofs (CR), tile roofs (TRoof), and campus catchment areas (CCA); and the EMCs of total phosphorus (TP) and NH3-N from UTR and CA are 2.35-5 and 3 times of the class-II standard values specified in the Environmental Quality Standards for Surface Water (GB 3838-2002). The EMCs of Fe, Pb and Cd are also much higher than the class-III standard values. The analysis of pollution load producing coefficients (PLPC) reveals that the main pollution source of TSS, COD and TP is UTR. The analysis of correlations between rainfall factors and EMCs/PLPC indicates that rainfall duration is correlated with EMCs/PLPC of TSS for TRoof and TP for UTR, while rainfall intensity is correlated with EMCs/PLPC of TP for both CR and CCA. The results of this study provide a reference for better management of non-point source pollution in urban regions.

The Use of Principal Component Analysis for Source Identification of PM2.5 from Selected Urban and Regional Background Sites in Poland

NASA Astrophysics Data System (ADS)

Błaszczak, Barbara

2018-01-01

The paper reports the results of the measurements of water-soluble ions and carbonaceous matter content in the fine particulate matter (PM2.5), as well as the contributions of major sources in PM2.5. Daily PM2.5 samples were collected during heating and non-heating season of the year 2013 in three different locations in Poland: Szczecin (urban background), Trzebinia (urban background) and Złoty Potok (regional background). The concentrations of PM2.5, and its related components, exhibited clear spatiotemporal variability with higher levels during the heating period. The share of the total carbon (TC) in PM2.5 exceeded 40% and was primarily determined by fluctuations in the share of OC. Sulfates (SO42-), nitrates (NO3-) and ammonium (NH4+) dominated in the ionic composition of PM2.5 and accounted together 34% (Szczecin), 30% (Trzebinia) and 18% (Złoty Potok) of PM2.5 mass. Source apportionment analysis, performed by PCA-MLRA model (Principal Component Analysis - Multilinear Regression Analysis), revealed that secondary aerosol, whose presence is related to oxidation of gaseous precursors emitted from fuel combustion and biomass burning, had the largest contribution in observed PM2.5 concentrations. In addition, the contribution of traffic sources together with road dust resuspension, was observed. The share of natural sources (sea spray, crustal dust) was generally lower.

Incidence of childhood leukaemia and non-Hodgkin's lymphoma in the vicinity of nuclear sites in Scotland, 1968-93.

PubMed Central

Sharp, L; Black, R J; Harkness, E F; McKinney, P A

1996-01-01

OBJECTIVES: The primary aims were to investigate the incidence of leukaemia and non-Hodgkin's lymphoma in children resident near seven nuclear sites in Scotland and to determine whether there was any evidence of a gradient in risk with distance of residence from a nuclear site. A secondary aim was to assess the power of statistical tests for increased risk of disease near a point source when applied in the context of census data for Scotland. METHODS: The study data set comprised 1287 cases of leukaemia and non-Hodgkin's lymphoma diagnosed in children aged under 15 years in the period 1968-93, validated for accuracy and completeness. A study zone around each nuclear site was constructed from enumeration districts within 25 km. Expected numbers were calculated, adjusting for sex, age, and indices of deprivation and urban-rural residence. Six statistical tests were evaluated. Stone's maximum likelihood ratio (unconditional application) was applied as the main test for general increased incidence across a study zone. The linear risk score based on enumeration districts (conditional application) was used as a secondary test for declining risk with distance from each site. RESULTS: More cases were observed (O) than expected (E) in the study zones around Rosyth naval base (O/E 1.02), Chapelcross electricity generating station (O/E 1.08), and Dounreay reprocessing plant (O/E 1.99). The maximum likelihood ratio test reached significance only for Dounreay (P = 0.030). The linear risk score test did not indicate a trend in risk with distance from any of the seven sites, including Dounreay. CONCLUSIONS: There was no evidence of a generally increased risk of childhood leukaemia and non-Hodgkin's lymphoma around nuclear sites in Scotland, nor any evidence of a trend of decreasing risk with distance from any of the sites. There was a significant excess risk in the zone around Dounreay, which was only partially accounted for by the sociodemographic characteristics of the area. The statistical power of tests for localised increased risk of disease around a point source should be assessed in each new setting in which they are applied. PMID:8994402

[Prediction and simulation of urban area expansion in Pearl River Delta Region under the RCPs climate scenarios].

PubMed

Jiang, Oun-ou; Deng, Xiang-zheng; Ke, Xin-li; Zhao, Chun-hong; Zhang, Wei

2014-12-01

The sizes and number of cities in China are increasing rapidly and complicated changes of urban land use system have occurred as the social economy develops rapidly. This study took the urban agglomeration of Pearl River Delta Region as the study area to explore the driving mechanism of dynamic changes of urban area in the urbanization process under the joint influence of natural environment and social economic conditions. Then the CA (cellular automata) model was used to predict and simulate the urban area changes until 2030 under the designed scenarios of planning and RCPs (representative concentration pathways). The results indicated that urbanization was mainly driven by the non-agricultural population growth and social-economic development, and the transportation had played a fundamental role in the whole process, while the areas with high elevation or steep slope restricted the urbanization. Besides, the urban area would keep an expanding trend regardless of the scenarios, however, the expanding speed would slow down with different inflection points under different scenarios. The urban expansion speed increased in the sequence of the planning scenario, MESSAGE scenario and AIM scenario, and that under the MESSAGE climate scenario was more consistent with the current urban development trend. In addition, the urban expansion would mainly concentrate in regions with the relatively high urbanization level, e.g., Guangzhou, Dongguan, Foshan, Shenzhen, Zhanjiang and Chaoshan.

Frequent combination of antimicrobial multiresistance and extraintestinal pathogenicity in Escherichia coli isolates from urban rats (Rattus norvegicus) in Berlin, Germany.

PubMed

Guenther, Sebastian; Bethe, Astrid; Fruth, Angelika; Semmler, Torsten; Ulrich, Rainer G; Wieler, Lothar H; Ewers, Christa

2012-01-01

Urban rats present a global public health concern as they are considered a reservoir and vector of zoonotic pathogens, including Escherichia coli. In view of the increasing emergence of antimicrobial resistant E. coli strains and the on-going discussion about environmental reservoirs, we intended to analyse whether urban rats might be a potential source of putatively zoonotic E. coli combining resistance and virulence. For that, we took fecal samples from 87 brown rats (Rattus norvegicus) and tested at least three E. coli colonies from each animal. Thirty two of these E. coli strains were pre-selected from a total of 211 non-duplicate isolates based on their phenotypic resistance to at least three antimicrobial classes, thus fulfilling the definition of multiresistance. As determined by multilocus sequence typing (MLST), these 32 strains belonged to 24 different sequence types (STs), indicating a high phylogenetic diversity. We identified STs, which frequently occur among extraintestinal pathogenic E. coli (ExPEC), such as STs 95, 131, 70, 428, and 127. Also, the detection of a number of typical virulence genes confirmed that the rats tested carried ExPEC-like strains. In particular, the finding of an Extended-spectrum beta-lactamase (ESBL)-producing strain which belongs to a highly virulent, so far mainly human- and avian-restricted ExPEC lineage (ST95), which expresses a serogroup linked with invasive strains (O18:NM:K1), and finally, which produces an ESBL-type frequently identified among human strains (CTX-M-9), pointed towards the important role, urban rats might play in the transmission of multiresistant and virulent E. coli strains. Indeed, using a chicken infection model, this strain showed a high in vivo pathogenicity. Imagining the high numbers of urban rats living worldwide, the way to the transmission of putatively zoonotic, multiresistant, and virulent strains might not be far ahead. The unforeseeable consequences of such an emerging public health threat need careful consideration in the future.

Investigating Ammonia Emission Sources in a Coastal Urban Air Shed Using Stable Isotope Techniques

NASA Astrophysics Data System (ADS)

Berner, A.; Felix, J. D. D.

2017-12-01

For nearly 100 years, mankind has met the food demands of a growing population by commercially producing and consuming reactive nitrogen fertilizers. So much so, that now 40-60% of the population relies on them. This increase has drastically altered the global nitrogen (N) cycle. Specifically, ammonia (NH3) emissions to the atmosphere have increased, resulting in wet and dry NHx (NH3 + NH4+) deposition products that can be substantial sources of N to sensitive ecosystems. Excess N can wreak havoc on these environments, causing soil acidification, water body eutrophication, and decreases in biodiversity. Despite these effects, NH3 remains generally unregulated in the U.S. Should policymakers elect to regulate NH3, quantification of NH3 emission sources and transport is essential. This has proven to be particularly difficult in urban regions, where ambient NH3 may result from local urban sources and/or NH3 transport from rural agricultural sources. The presented work investigates potential NH3 emission sources within a South Texas coastal urban air shed, Corpus Christi, TX, U.S.A. Previous work has shown an increasing fine particulate matter (PM2.5) trend within the region, which may be attributable to NH3 emissions from a variety of local sources, including vehicle traffic, shipping traffic, the petrochemical industry, and/or surrounding agricultural cropland and livestock. NH3 was collected monthly at a set of 8 sites within the Corpus Christi air shed, analyzed for NH3 concentration and N isotopic composition (d15N-NH3), and compared to known isotopic compositions of NH3 sources. Low and seasonally variable d15N-NH3 values are associated with varying agricultural sources (fertilizer, livestock waste, etc.), while higher and more seasonally constant d15N-NH3 values are associated with non-agricultural sources (vehicles, industry, etc.). Several other physical and chemical atmospheric components (e.g. SO2, NO2, O3, PM2.5, temperature, relative humidity) were also analyzed to study how they might affect NH3 and PM2.5 atmospheric chemistry. It is necessary to enhance our understanding of NH3 dynamics, especially within an urban environment, to properly formulate future NH3 and PM2.5 attainment strategies.

Differentiating local and regional sources of Chinese urban air pollution based on the effect of the Spring Festival

NASA Astrophysics Data System (ADS)

Wang, Chuan; Huang, Xiao-Feng; Zhu, Qiao; Cao, Li-Ming; Zhang, Bin; He, Ling-Yan

2017-07-01

The emission of pollutants is extremely reduced during the annual Chinese Spring Festival (SF) in Shenzhen, China. During the SF, traffic flow drops by ˜ 50 % and the industrial plants are almost entirely shut down in Shenzhen. To characterize the variation in ambient air pollutants due to the Spring Festival effect, various gaseous and particulate pollutants were measured in real time in urban Shenzhen over three consecutive winters (2014-2016). The results indicate that the concentrations of NOx, volatile organic compounds (VOCs), black carbon (BC), primary organic aerosols, chloride, and nitrate in submicron aerosols decrease by 50-80 % during SF periods relative to non-Spring Festival periods, regardless of meteorological conditions. This decrease suggests that these pollutants are mostly emitted or secondarily formed from urban local emissions. The concentration variation in species mostly from regional or natural sources, however, is found to be much less, such as for bulk fine particulate matter (PM2. 5). More detailed analysis of the Spring Festival effect reveals an urgent need to reduce emissions of SO2 and VOCs on a regional scale rather than on an urban scale to reduce urban PM2. 5 in Shenzhen, which can also be useful as a reference for other megacities in China.

Delivering cognitive processing therapy in a community health setting: The influence of Latino culture and community violence on posttraumatic cognitions.

PubMed

Marques, Luana; Eustis, Elizabeth H; Dixon, Louise; Valentine, Sarah E; Borba, Christina P C; Simon, Naomi; Kaysen, Debra; Wiltsey-Stirman, Shannon

2016-01-01

Despite the applicability of cognitive processing therapy (CPT) for posttraumatic stress disorder (PTSD) to addressing sequelae of a range of traumatic events, few studies have evaluated whether the treatment itself is applicable across diverse populations. The present study examined differences and similarities among non-Latino, Latino Spanish-speaking, and Latino English-speaking clients in rigid beliefs-or "stuck points"-associated with PTSD symptoms in a sample of community mental health clients. We utilized the procedures of content analysis to analyze stuck point logs and impact statements of 29 participants enrolled in a larger implementation trial for CPT. Findings indicated that the content of stuck points was similar across Latino and non-Latino clients, although fewer total stuck points were identified for Latino clients compared to non-Latino clients. Given that identification of stuck points is central to implementing CPT, difficulty identifying stuck points could pose significant challenges for implementing CPT among Latino clients and warrants further examination. Thematic analysis of impact statements revealed the importance of family, religion, and the urban context (e.g., poverty, violence exposure) in understanding how clients organize beliefs and emotions associated with trauma. Clinical recommendations for implementing CPT in community settings and the identification of stuck points are provided. (c) 2016 APA, all rights reserved).

A Workflow to Model Microbial Loadings in Watersheds ...

EPA Pesticide Factsheets

Many watershed models simulate overland and instream microbial fate and transport, but few actually provide loading rates on land surfaces and point sources to the water body network. This paper describes the underlying general equations for microbial loading rates associated with 1) land-applied manure on undeveloped areas from domestic animals; 2) direct shedding on undeveloped lands by domestic animals and wildlife; 3) urban or engineered areas; and 4) point sources that directly discharge to streams from septic systems and shedding by domestic animals. A microbial source module, which houses these formulations, is linked within a workflow containing eight models and a set of databases that form a loosely configured modeling infrastructure which supports watershed-scale microbial source-to-receptor modeling by focusing on animal-impacted catchments. A hypothetical example application – accessing, retrieving, and using real-world data – demonstrates the ability of the infrastructure to automate many of the manual steps associated with a standard watershed assessment, culminating with calibrated flow and microbial densities at the pour point of a watershed. In the Proceedings of the International Environmental Modelling and Software Society (iEMSs), 8th International Congress on Environmental Modelling and Software, Toulouse, France

CADDIS Volume 2. Sources, Stressors and Responses: Urbanization - Energy Sources

EPA Pesticide Factsheets

Introduction to changes in basal energy sources with urbanization, overview of terrestrial leaf litter dynamics in urban streams, overview of how urbanization can affect primary production, respiration, and dissolved organic carbon quantity and quality.

Female access to non-primary occupations: the Indonesian case.

PubMed

Moir, H V

1980-12-01

Focus in this discussion is on the range of nonprimary occupations open to women in Indonesia compared to those open to men. Particular attention is directed to the question of whether given occupations (particularly those that are important sources of employment) are more or less open to women in urban compared to rural areas. Whether an occupation is open to women or not is defined on the basis of the proportion female in that occupation. Where the proportion female is high, it is evident that women have a substantial degree of access to that occupation. In contrast, where the proportion female is very low, it is obviously unusual for women to enter that occupation and female access to such occupations is relatively restricted. The data presented refer to the employed population, i.e., the economically active population excluding the unemployed. The 1971 Population Census is used to maintain seasonal comparability with other analyses of the Indonesian workforce and to allow for seasonal comparability with the data from the 1980 Population Census. Out of 75 nonprimary occupation groups, 39 are excluded from the analysis because in most provinces they employ less than 0.1% of the labor force. The percentage of the male workforce in rural areas that is engaged in the remaining 36 occupations is less than the percentage of the female rural workforce engaged in these same occupations (95.0 compared to 98.2% in Java-Bali and 94.1 compared to 97.4% in the Outer Islands). In urban areas, male-female differences in the percentage concentrated in these 36 occupations are slightly larger (4.4 percentage points in urban compared to 3.2 percentage points in rural Java-Bali and 5.6 and 3.3 percentage points for urban and rural areas in the Outer Islands). A negative association was found between the degree of occupational segregation by sex and the relative modernness of an area, i.e., occupational segregation by sex is greatest in the least modern area of the country, the rural areas of the other islands, and is lowest in the metropolitan area of Jakarta. Although occupational segregation is lower in Jakarta than elsewhere in Indonesia, it is still quite high with an Index value of 51.2. Women were found to be underrepresented in the upper level occupations in all areas of Indonesia. The degree of underrepresentation was considerably greater in rural than in urban areas. Women are over-represented in sales and service occupations, and within these broad categories are most dominant in the more traditional sector of the economy than is the male labor force.

Ambient volatile organic compounds (VOCs) in Calgary, Alberta: Sources and screening health risk assessment.

PubMed

Bari, Md Aynul; Kindzierski, Warren B

2018-08-01

Exposure to ambient volatile organic compound (VOCs) in urban areas is of interest because of their potential chronic and acute adverse effects to public health. Limited information is available about VOC sources in urban areas in Canada. An investigation of ambient VOCs levels, their potential sources and associated risks to public health was undertaken for the urban core of Alberta's largest city (downtown Calgary) for the period 2010-2015. Twenty-four hour arithmetic and geometric mean concentrations of total VOCs were 42μg/m 3 and 39μg/m 3 , respectively and ranged from 16 to 160μg/m 3 , with winter levels about two-fold higher than summer. Alkanes (58%) were the most dominant compounds followed by halogenated VOCs (22%) and aromatics (11%). Mean and maximum 24h ambient concentrations of selected VOCs of public health concern were below chronic and acute health risk screening criteria of the United States regulatory agencies and a cancer screening benchmark used in Alberta equivalent to 1 in 100,000 lifetime risk. The Positive matrix factorization (PMF) model revealed nine VOC sources at downtown Calgary, where oil/natural gas extraction/combustion (26%), fuel combustion (20%), traffic sources including gasoline exhaust, diesel exhaust, mixed fugitive emissions (10-15%), and industrial coatings/solvents (12%) were predominant. Other sources included dry cleaning (3.3%), biogenic (3.5%) and a background source (18%). Source-specific health risk values were also estimated. Estimated cancer risks for all sources were below the Alberta cancer screening benchmark, and estimated non-cancer risks for all sources were well below a safe level. Copyright © 2018 Elsevier B.V. All rights reserved.

Source apportionment vs. emission inventories of non-methane hydrocarbons (NMHC) in an urban area of the Middle East: local and global perspectives

NASA Astrophysics Data System (ADS)

Salameh, Thérèse; Sauvage, Stéphane; Afif, Charbel; Borbon, Agnès; Locoge, Nadine

2016-03-01

We applied the positive matrix factorization model to two large data sets collected during two intensive measurement campaigns (summer 2011 and winter 2012) at a sub-urban site in Beirut, Lebanon, in order to identify NMHC (non-methane hydrocarbons) sources and quantify their contribution to ambient levels. Six factors were identified in winter and five factors in summer. PMF-resolved source profiles were consistent with source profiles established by near-field measurements. The major sources were traffic-related emissions (combustion and gasoline evaporation) in winter and in summer accounting for 51 and 74 wt %, respectively, in agreement with the national emission inventory. The gasoline evaporation related to traffic source had a significant contribution regardless of the season (22 wt % in winter and 30 wt % in summer). The NMHC emissions from road transport are estimated from observations and PMF results, and compared to local and global emission inventories. The PMF analysis finds reasonable differences on emission rates, of 20-39 % higher than the national road transport inventory. However, global inventories (ACCMIP, EDGAR, MACCity) underestimate the emissions up to a factor of 10 for the transportation sector. When combining emission inventory to our results, there is strong evidence that control measures in Lebanon should be targeted on mitigating the NMHC emissions from the traffic-related sources. From a global perspective, an assessment of VOC (volatile organic compounds) anthropogenic emission inventories for the Middle East region as a whole seems necessary as these emissions could be much higher than expected at least from the road transport sector.

Urban local air quality management framework for non-attainment areas in Indian cities.

PubMed

Gulia, Sunil; Nagendra, S M Shiva; Barnes, Jo; Khare, Mukesh

2018-04-01

Increasing urban air pollution level in Indian cities is one of the major concerns for policy makers due to its impact on public health. The growth in population and increase in associated motorised road transport demand is one of the major causes of increasing air pollution in most urban areas along with other sources e.g., road dust, construction dust, biomass burning etc. The present study documents the development of an urban local air quality management (ULAQM) framework at urban hotspots (non-attainment area) and a pathway for the flow of information from goal setting to policy making. The ULAQM also includes assessment and management of air pollution episodic conditions at these hotspots, which currently available city/regional-scale air quality management plans do not address. The prediction of extreme pollutant concentrations using a hybrid model differentiates the ULAQM from other existing air quality management plans. The developed ULAQM framework has been applied and validated at one of the busiest traffic intersections in Delhi and Chennai cities. Various scenarios have been tested targeting the effective reductions in elevated levels of NO x and PM 2.5 concentrations. The results indicate that a developed ULAQM framework is capable of providing an evidence-based graded action to reduce ambient pollution levels within the specified standard level at pre-identified locations. The ULAQM framework methodology is generalised and therefore can be applied to other non-attainment areas of the country. Copyright © 2017 Elsevier B.V. All rights reserved.

Using Automatic Control Approach In Detention Storages For Storm Water Management In An Urban Watershed

NASA Astrophysics Data System (ADS)

Goyal, A.; Yadav, H.; Tyagi, H.; Gosain, A. K.; Khosa, R.

2017-12-01

Increased imperviousness due to rapid urbanization have changed the urban hydrological cycle. As watersheds are urbanized, infiltration and groundwater recharge have decreased, surface runoff hydrograph shows higher peak indicating large volumes of surface runoff in lesser time durations. The ultimate panacea is to reduce the peak of hydrograph or increase the retention time of surface flow. SWMM is widely used hydrologic and hydraulic software which helps to simulate the urban storm water management with the provision to apply different techniques to prevent flooding. A model was setup to simulate the surface runoff and channel flow in a small urban catchment. It provides the temporal and spatial information of flooding in a catchment. Incorporating the detention storages in the drainage network helps achieve reduced flooding. Detention storages provided with predefined algorithms were for controlling the pluvial flooding in urban watersheds. The algorithm based on control theory, automated the functioning of detention storages ensuring that the storages become active on occurrence of flood in the storm water drains and shuts down when flooding is over. Detention storages can be implemented either at source or at several downstream control points. The proposed piece of work helps to mitigate the wastage of rainfall water, achieve desirable groundwater and attain a controlled urban storm water management system.

Lead exposures in the human environment. Final report

DOE Office of Scientific and Technical Information (OSTI.GOV)

Elias, R.W.

Humans consume lead by inhaling air, drinking beverages, eating food and ingesting dust. The natural source of this lead is primarily soil. Anthropogenic sources are lead in gasoline, fossil fuels and industrial products and processes. Lead is ubiquitous in the human environment, and pinpointing the primary sources of lead in any particular environmental component is difficult. Nevertheless, our purpose is to describe the total exposure of humans to environmental lead and to determine the sources of lead contributing to this exposure. The total exposure is the total amount of lead consumed by ingestion and inhalation. Excluding lead exposure from choicemore » or circumstance, a baseline level of potential human exposure can be defined for a normal individual eating a typical diet and living in a non-urban community remote from industrial sources of lead in a house without lead-based paints. Beyond this level, additive exposure factors can be determined for other environments (e.g. urban, occupational and smelter communities) and for certain habits and activities (e.g. pica, smoking, drinking and hobbies), with variation for age, sex or socioeconomic status.« less

Partitioning of magnetic particles in PM10, PM2.5 and PM1 aerosols in the urban atmosphere of Barcelona (Spain).

PubMed

Revuelta, María Aránzazu; McIntosh, Gregg; Pey, Jorge; Pérez, Noemi; Querol, Xavier; Alastuey, Andrés

2014-05-01

A combined magnetic-chemical study of 15 daily, simultaneous PM10-PM2.5-PM1 urban background aerosol samples has been carried out. The magnetic properties are dominated by non-stoichiometric magnetite, with highest concentrations seen in PM10. Low temperature magnetic analyses showed that the superparamagnetic fraction is more abundant when coarse, multidomain particles are present, confirming that they may occur as an oxidized outer shell around coarser grains. A strong association of the magnetic parameters with a vehicular PM10 source has been identified. Strong correlations found with Cu and Sb suggests that this association is related to brake abrasion emissions rather than exhaust emissions. For PM1 the magnetic remanence parameters are more strongly associated with crustal sources. Two crustal sources are identified in PM1, one of which is of North African origin. The magnetic particles are related to this source and so may be used to distinguish North African dust from other sources in PM1. Copyright © 2014 Elsevier Ltd. All rights reserved.

Source attribution of poly- and perfluoroalkyl substances (PFASs) in surface waters from Rhode Island and the New York Metropolitan Area

PubMed Central

Zhang, Xianming; Lohmann, Rainer; Dassuncao, Clifton; Hu, Xindi C.; Weber, Andrea K.; Vecitis, Chad D.; Sunderland, Elsie M.

2017-01-01

Exposure to poly and perfluoroalkyl substances (PFASs) has been associated with adverse health effects in humans and wildlife. Understanding pollution sources is essential for environmental regulation but source attribution for PFASs has been confounded by limited information on industrial releases and rapid changes in chemical production. Here we use principal component analysis (PCA), hierarchical clustering, and geospatial analysis to understand source contributions to 14 PFASs measured across 37 sites in the Northeastern United States in 2014. PFASs are significantly elevated in urban areas compared to rural sites except for perfluorobutane sulfonate (PFBS), N-methyl perfluorooctanesulfonamidoacetic acid (N-MeFOSAA), perfluoroundecanate (PFUnDA) and perfluorododecanate (PFDoDA). The highest PFAS concentrations across sites were for perfluorooctanate (PFOA, 56 ng L−1) and perfluorohexane sulfonate (PFOS, 43 ng L−1) and PFOS levels are lower than earlier measurements of U.S. surface waters. PCA and cluster analysis indicates three main statistical groupings of PFASs. Geospatial analysis of watersheds reveals the first component/cluster originates from a mixture of contemporary point sources such as airports and textile mills. Atmospheric sources from the waste sector are consistent with the second component, and the metal smelting industry plausibly explains the third component. We find this source-attribution technique is effective for better understanding PFAS sources in urban areas. PMID:28217711

Regression Techniques for Determining the Effective Impervious Area in Southern California Watersheds

NASA Astrophysics Data System (ADS)

Sultana, R.; Mroczek, M.; Dallman, S.; Sengupta, A.; Stein, E. D.

2016-12-01

The portion of the Total Impervious Area (TIA) that is hydraulically connected to the storm drainage network is called the Effective Impervious Area (EIA). The remaining fraction of impervious area, called the non-effective impervious area, drains onto pervious surfaces which do not contribute to runoff for smaller events. Using the TIA instead of EIA in models and calculations can lead to overestimates of runoff volumes peak discharges and oversizing of drainage system since it is assumed all impervious areas produce urban runoff that is directly connected to storm drains. This makes EIA a better predictor of actual runoff from urban catchments for hydraulic design of storm drain systems and modeling non-point source pollution. Compared to TIA, determining the EIA is considerably more difficult to calculate since it cannot be found by using remote sensing techniques, readily available EIA datasets, or aerial imagery interpretation alone. For this study, EIA percentages were calculated by two successive regression methods for five watersheds (with areas of 8.38 - 158mi2) located in Southern California using rainfall-runoff event data for the years 2004 - 2007. Runoff generated from the smaller storm events are considered to be emanating only from the effective impervious areas. Therefore, larger events that were considered to have runoff from both impervious and pervious surfaces were successively removed in the regression methods using a criterion of (1) 1mm and (2) a max (2 , 1mm) above the regression line. MSE is calculated from actual runoff and runoff predicted by the regression. Analysis of standard deviations showed that criterion of max (2 , 1mm) better fit the regression line and is the preferred method in predicting the EIA percentage. The estimated EIAs have shown to be approximately 78% to 43% of the TIA which shows use of EIA instead of TIA can have significant impact on the cost building urban hydraulic systems and stormwater capture devices.

FDATMOS16 non-linear partitioning and organic volatility distributions in urban aerosols

DOE PAGES

Madronich, Sasha; Kleinman, Larry; Conley, Andrew; ...

2015-12-17

Gas-to-particle partitioning of organic aerosols (OA) is represented in most models by Raoult’s law, and depends on the existing mass of particles into which organic gases can dissolve. This raises the possibility of non-linear response of particle-phase OA to the emissions of precursor volatile organic compounds (VOCs) that contribute to this partitioning mass. Implications for air quality management are evident: A strong non-linear dependence would suggest that reductions in VOC emission would have a more-than-proportionate benefit in lowering ambient OA concentrations. Chamber measurements on simple VOC mixtures generally confirm the non-linear scaling between OA and VOCs, usually stated as amore » mass-dependence of the measured OA yields. However, for realistic ambient conditions including urban settings, no single component dominates the composition of the organic particles, and deviations from linearity are presumed to be small. Here we re-examine the linearity question using volatility spectra from several sources: (1) chamber studies of selected aerosols, (2) volatility inferred for aerosols sampled in two megacities, Mexico City and Paris, and (3) an explicit chemistry model (GECKO-A). These few available volatility distributions suggest that urban OA may be only slightly super-linear, with most values of the sensitivity exponent in the range 1.1-1.3, also substantially lower than seen in chambers for some specific aerosols. Furthermore, the rather low values suggest that OA concentrations in megacities are not an inevitable convergence of non-linear effects, but can be addressed (much like in smaller urban areas) by proportionate reductions in emissions.« less

Evaluation of the noise pollution in urban parks of Curitiba, Brazil

NASA Astrophysics Data System (ADS)

Ferreira, Andressa C.; Diniz, Fabiano B.; Paz, Elaine C.; Zannin, Paulo T.

2004-05-01

This work shows a study about the noise pollution found in six urban parks of Curitiba, Paran, Brazil. The equivalent noise levels (Leq) have been measured in points spread throughout the park, and interviews have been conducted with some park visitors. It has been found out that 52.48% out of the measurement sites did not satisfy the Municipal Law no. 10,625, which states the noise emission level of 55 dB(A) as the limit value for green areas. The results of the questionnaires applied to the local visitors have showed that 39% out of the interviewed people used to visit the park every day and that 75% out of them seek for the realization of a physical activity. During the realization of their activities in the parks, 22% out of the interviewed people pointed to the noise pollution as the source of annoyance and 28% out of them pointed the local security. In this sense, it has been verified that half of the analyzed parks were inserted in acoustically polluted areas, which incurs a real state depreciation in their vicinities.

Refining models for quantifying the water quality benefits of improved animal management for use in water quality trading

USDA-ARS?s Scientific Manuscript database

Water quality trading (WQT) is a market-based approach that allows point sources of water pollution to meet their water quality obligations by purchasing credits from the reduced discharges from other point or nonpoint sources. Non-permitted animal operations and fields of permitted animal operatio...

Compound Specific Isotope Analysis of Fatty Acids in Southern African Aerosols

NASA Astrophysics Data System (ADS)

Billmark, K. A.; Macko, S. A.; Swap, R. J.

2003-12-01

This study, conducted as a part of the Southern African Regional Science Initiative (SAFARI 2000), applied compound specific isotope analysis to describe aerosols at source regions and rural locations. Stable carbon isotopic compositions of individual fatty acids were determined for aerosol samples collected at four sites throughout southern Africa. Mongu, Zambia and Skukuza, South Africa were chosen for their location within intense seasonal Miombo woodland savanna and bushveld savanna biomass burning source regions, respectively. Urban aerosols were collected at Johannesburg, South Africa and rural samples were collected at Sua Pan, Botswana. Fatty acid isotopic compositions varied temporally. Urban aerosols showed significant isotopic enrichment of selected short chain fatty acids (C < 20) compared to aerosols produced during biomass combustion. Sua Pan short chain fatty acid signatures were significantly different from the other non-urban sites, which suggests that sources other than biomass combustion products, such as organic eolian material, impact the Sua Pan aerosol profile. However, a high degree of correlation between Sua Pan and Skukuza long chain fatty acid δ 13C values confirm atmospheric linkages between the two areas and that isotopic signatures of combusted fatty acids are unaltered during atmospheric transport highlighting their potential for use as a conservative tracer.

Impacts by point and diffuse micropollutant sources on the stream water quality at catchment scale

NASA Astrophysics Data System (ADS)

Petersen, M. F.; Eriksson, E.; Binning, P. J.; Bjerg, P. L.

2012-04-01

The water quality of surface waters is threatened by multiple anthropogenic pollutants and the large variety of pollutants challenges the monitoring and assessment of the water quality. The aim of this study was to characterize and quantify both point and diffuse sources of micropollutants impacting the water quality of a stream at catchment scale. Grindsted stream in western Jutland, Denmark was used as a study site. The stream passes both urban and agricultural areas and is impacted by severe groundwater contamination in Grindsted city. Along a 12 km reach of Grindsted stream, the potential pollution sources were identified including a pharmaceutical factory site with a contaminated old drainage ditch, two waste deposits, a wastewater treatment plant, overflow structures, fish farms, industrial discharges and diffuse agricultural and urban sources. Six water samples were collected along the stream and analyzed for general water quality parameters, inorganic constituents, pesticides, sulfonamides, chlorinated solvents, BTEXs, and paracetamol and ibuprofen. The latter two groups were not detected. The general water quality showed typical conditions for a stream in western Jutland. Minor impacts by releases of organic matter and nutrients were found after the fish farms and the waste water treatment plant. Nickel was found at concentrations 5.8 - 8.8 μg/l. Nine pesticides and metabolites of both agricultural and urban use were detected along the stream; among these were the two most frequently detected and some rarely detected pesticides in Danish water courses. The concentrations were generally consistent with other findings in Danish streams and in the range 0.01 - 0.09 μg/l; except for metribuzin-diketo that showed high concentrations up to 0.74 μg/l. The groundwater contamination at the pharmaceutical factory site, the drainage ditch and the waste deposits is similar in composition containing among others sulfonamides and chlorinated solvents (including vinyl chloride). Vinyl chloride concentrations surpassed Danish stream water quality criteria with a factor 10. The largest chemical impact occurs at the reach downstream Grindsted city revealing that the main contaminant groundwater discharge zones are found here. The contaminant plume from the factory site north of the stream is known to impact the stream whereas the impact by the old landfill south of the stream remains to be assessed. A conceptual model of the chemical impacts by the identified sources was made, and high impact was assigned to the contaminant plume from the factory site and to the diffuse sources of urban-use and agricultural pesticides. The next step will be a quantification of the sources, which will be presented at the conference.

40 CFR 430.107 - Pretreatment standards for new sources (PSNS).

Code of Federal Regulations, 2010 CFR

2010-07-01

...) EFFLUENT GUIDELINES AND STANDARDS THE PULP, PAPER, AND PAPERBOARD POINT SOURCE CATEGORY Secondary Fiber Non...: Subpart J [PSNS for secondary fiber non-deink facilities where paperboard from wastepaper is produced... = wastewater discharged in kgal per ton of product. a The following equivalent mass limitations are provided as...

40 CFR 430.107 - Pretreatment standards for new sources (PSNS).

Code of Federal Regulations, 2011 CFR

2011-07-01

...) EFFLUENT GUIDELINES AND STANDARDS THE PULP, PAPER, AND PAPERBOARD POINT SOURCE CATEGORY Secondary Fiber Non...: Subpart J [PSNS for secondary fiber non-deink facilities where paperboard from wastepaper is produced... = wastewater discharged in kgal per ton of product. a The following equivalent mass limitations are provided as...

Regional and local meteorology influences high-resolution tropospheric ozone concentration in the Los Angeles Basin

NASA Astrophysics Data System (ADS)

Koutzoukis, S.; Jenerette, D.; Chandler, M.; Wang, J.; Ge, C.; Ripplinger, J.

2017-12-01

Urban air quality and climate directly affect resident health. The Los Angeles (LA) Basin is a highly populated metropolitan area, with widespread point sources of ozone (O3) precursors (NOx , Volatile Organic Compounds, CO) from fossil fuel combustion. The LA basin exists on a coast-to-mountain gradient, with increasing temperatures towards the Transverse Ranges, which rise to 1700m. Frequently not compliant with 8-hour O3 standards, the LA and South Coast Air Basins are designated as severe and extreme non-attainment areas. Summer weather in the LA basin is characterized by a persistent high pressure system, creating an inversion that traps air pollutants, including O3 precursors, coupled with physical geography that blocks prevailing upper atmosphere air flow. These interactions make neighborhood-level O3 levels more variable than common regional models. Over the summer of 2017, we investigated the importance of local meteorology, wind patterns and air temperature, in transporting and mixing ozone precursors from point sources along the coast-to-mountain gradient. We deployed a network of six EPA federal equivalent method ozone and meteorological sensors in three campaigns in the LA basin along the coast-to-mountain transect. Each campaign, we collaborated with citizen scientists to deploy three sensor stations in two, 4 km2 quadrats, for a total of six high-resolution 4 km2 pixels. O3 concentrations vary greatly along the transect. At the coastal sites, daily O3 ranges from 0ppm to 60ppm and the range increases at the inland sites, to 100ppm. At all sites, there was a positive relationship between wind speed, air temperature, and O3 concentration, with increasing correlation inland. The Pearson correlation coefficient between wind speed and O3 concentration doubles from the coast to inland, and triples between air temperature and O3. The site-specific relationships between O3 and wind direction and temperature vary, suggesting neighborhood-effects from local point sources.

Spread of acid rain over India

NASA Astrophysics Data System (ADS)

Khemani, L. T.; Momin, G. A.; Rao, P. S. Prakasa; Safai, P. D.; Singh, G.; Kapoor, R. K.

Rain water and aerosol samples were collected at a few locations representative of urban and non-urban regions in India. Also, rain water samples were collected in and around a coal-fired power plant. All the rain water and aerosol samples were analyzed for major chemical components along with pH. The rain water at all the places of measurement, except near the industrial sources, has been found to be alkaline and was characterized by the presence of excess cations, particularly by Ca 2+. The acid rain near the industrial sources was associated with excess anions, especially SO 42-. The atmospheric aerosols at all the places of measurement were found rich with basic components, suggesting that the alkaline soil dust and fly ash are responsible at present for preventing the spread of acid rain in India.

Quantifying chemical reactions by using mixing analysis.

PubMed

Jurado, Anna; Vázquez-Suñé, Enric; Carrera, Jesús; Tubau, Isabel; Pujades, Estanislao

2015-01-01

This work is motivated by a sound understanding of the chemical processes that affect the organic pollutants in an urban aquifer. We propose an approach to quantify such processes using mixing calculations. The methodology consists of the following steps: (1) identification of the recharge sources (end-members) and selection of the species (conservative and non-conservative) to be used, (2) identification of the chemical processes and (3) evaluation of mixing ratios including the chemical processes. This methodology has been applied in the Besòs River Delta (NE Barcelona, Spain), where the River Besòs is the main aquifer recharge source. A total number of 51 groundwater samples were collected from July 2007 to May 2010 during four field campaigns. Three river end-members were necessary to explain the temporal variability of the River Besòs: one river end-member is from the wet periods (W1) and two are from dry periods (D1 and D2). This methodology has proved to be useful not only to compute the mixing ratios but also to quantify processes such as calcite and magnesite dissolution, aerobic respiration and denitrification undergone at each observation point. Copyright © 2014 Elsevier B.V. All rights reserved.

Water quality and non-point sources of risk: the Jiulong River Watershed, P. R. of China.

PubMed

Zhang, Jingjing; Zhang, Luoping; Ricci, Paolo F

2012-01-01

Retrospective water quality assessment plays an essential role in identifying trends and causal associations between exposures and risks, thus it can be a guide for water resources management. We have developed empirical relationships between several time-varying social and economic factors of economic development, water quality variables such as nitrate-nitrogen, COD(Mn), BOD(5), and DO, in the Jiulong River Watershed and its main tributary, the West River. Our analyses used alternative statistical methods to reduce the dimensionality of the analysis first and then strengthen the study's causal associations. The statistical methods included: factor analysis (FA), trend analysis, Monte Carlo/bootstrap simulations, robust regressions and a coupled equations model, integrated into a framework that allows an investigation and resolution of the issues that may affect the estimated results. After resolving these, we found that the concentrations of nitrogen compounds increased over time in the West River region, and that fertilizer used in agricultural fruit crops was the main risk with regard to nitrogen pollution. The relationships we developed can identify hazards and explain the impact of sources of different types of pollution, such as urbanization, and agriculture.

Micro and Macroscale Drivers of Nutrient Concentrations in Urban Streams in South, Central and North America.

PubMed

Loiselle, Steven A; Gasparini Fernandes Cunha, Davi; Shupe, Scott; Valiente, Elsa; Rocha, Luciana; Heasley, Eleanore; Belmont, Patricia Pérez; Baruch, Avinoam

Global metrics of land cover and land use provide a fundamental basis to examine the spatial variability of human-induced impacts on freshwater ecosystems. However, microscale processes and site specific conditions related to bank vegetation, pollution sources, adjacent land use and water uses can have important influences on ecosystem conditions, in particular in smaller tributary rivers. Compared to larger order rivers, these low-order streams and rivers are more numerous, yet often under-monitored. The present study explored the relationship of nutrient concentrations in 150 streams in 57 hydrological basins in South, Central and North America (Buenos Aires, Curitiba, São Paulo, Rio de Janeiro, Mexico City and Vancouver) with macroscale information available from global datasets and microscale data acquired by trained citizen scientists. Average sub-basin phosphate (P-PO4) concentrations were found to be well correlated with sub-basin attributes on both macro and microscales, while the relationships between sub-basin attributes and nitrate (N-NO3) concentrations were limited. A phosphate threshold for eutrophic conditions (>0.1 mg L-1 P-PO4) was exceeded in basins where microscale point source discharge points (eg. residential, industrial, urban/road) were identified in more than 86% of stream reaches monitored by citizen scientists. The presence of bankside vegetation covaried (rho = -0.53) with lower phosphate concentrations in the ecosystems studied. Macroscale information on nutrient loading allowed for a strong separation between basins with and without eutrophic conditions. Most importantly, the combination of macroscale and microscale information acquired increased our ability to explain sub-basin variability of P-PO4 concentrations. The identification of microscale point sources and bank vegetation conditions by citizen scientists provided important information that local authorities could use to improve their management of lower order river ecosystems.

Micro and Macroscale Drivers of Nutrient Concentrations in Urban Streams in South, Central and North America

PubMed Central

Loiselle, Steven A.; Gasparini Fernandes Cunha, Davi; Shupe, Scott; Valiente, Elsa; Rocha, Luciana; Heasley, Eleanore; Belmont, Patricia Pérez; Baruch, Avinoam

2016-01-01

Global metrics of land cover and land use provide a fundamental basis to examine the spatial variability of human-induced impacts on freshwater ecosystems. However, microscale processes and site specific conditions related to bank vegetation, pollution sources, adjacent land use and water uses can have important influences on ecosystem conditions, in particular in smaller tributary rivers. Compared to larger order rivers, these low-order streams and rivers are more numerous, yet often under-monitored. The present study explored the relationship of nutrient concentrations in 150 streams in 57 hydrological basins in South, Central and North America (Buenos Aires, Curitiba, São Paulo, Rio de Janeiro, Mexico City and Vancouver) with macroscale information available from global datasets and microscale data acquired by trained citizen scientists. Average sub-basin phosphate (P-PO4) concentrations were found to be well correlated with sub-basin attributes on both macro and microscales, while the relationships between sub-basin attributes and nitrate (N-NO3) concentrations were limited. A phosphate threshold for eutrophic conditions (>0.1 mg L-1 P-PO4) was exceeded in basins where microscale point source discharge points (eg. residential, industrial, urban/road) were identified in more than 86% of stream reaches monitored by citizen scientists. The presence of bankside vegetation covaried (rho = –0.53) with lower phosphate concentrations in the ecosystems studied. Macroscale information on nutrient loading allowed for a strong separation between basins with and without eutrophic conditions. Most importantly, the combination of macroscale and microscale information acquired increased our ability to explain sub-basin variability of P-PO4 concentrations. The identification of microscale point sources and bank vegetation conditions by citizen scientists provided important information that local authorities could use to improve their management of lower order river ecosystems. PMID:27662192

A study of ecological sanitation as an integrated urban water supply system: case study of sustainable strategy for Kuching City, Sarawak, Malaysia.

PubMed

Seng, Darrien Mah Yau; Putuhena, Frederik Josep; Said, Salim; Ling, Law Puong

2009-03-01

A city consumes a large amount of water. Urban planning and development are becoming more compelling due to the fact of growing competition for water, which has lead to an increasing and conflicting demand. As such, investments in water supply, sanitation and water resources management is a strong potential for a solid return. A pilot project of greywater ecological treatment has been established in Kuching city since 2003. Such a treatment facility opens up an opportunity of wastewater reclamation for reuse as secondary sources of water for non-consumptive purposes. This paper aims to explore the potential of the intended purposes in the newly developed ecological treatment project. By utilizing the Wallingford Software model, InfoWorks WS (Water Supply) is employed to carry out a hydraulic modeling of a hypothetical greywater recycling system as an integrated part of the Kuching urban water supply, where the greywater is treated, recycled and reused in the domestic environment. The modeling efforts have shown water savings of about 40% from the investigated system reinstating that the system presents an alternative water source worth exploring in an urban environment.

Monitoring coastal marine waters for spore-forming bacteria of faecal and soil origin to determine point from non-point source pollution.

PubMed

Fujioka, R S

2001-01-01

The US Environmental Protection Agency (USEPA) and the World Health Organization (WHO) have established recreational water quality standards limiting the concentrations of faecal indicator bacteria (faecal coliform, E. coli, enterococci) to ensure that these waters are safe for swimming. In the application of these hygienic water quality standards, it is assumed that there are no significant environmental sources of these faecal indicator bacteria which are unrelated to direct faecal contamination. However, we previously reported that these faecal indicator bacteria are able to grow in the soil environment of humid tropical island environments such as Hawaii and Guam and are transported at high concentrations into streams and storm drains by rain. Thus, streams and storm drains in Hawaii contain consistently high concentrations of faecal indicator bacteria which routinely exceed the EPA and WHO recreational water quality standards. Since, streams and storm drains eventually flow out to coastal marine waters, we hypothesize that all the coastal beaches which receive run-off from streams and storm drains will contain elevated concentrations of faecal indicator bacteria. To test this hypothesis, we monitored the coastal waters at four beaches known to receive water from stream or storm drains for salinity, turbidity, and used the two faecal indicator bacteria (E. coli, enterococci) to establish recreational water quality standards. To determine if these coastal waters are contaminated with non-point source pollution (streams) or with point source pollution (sewage effluent), these same water samples were also assayed for spore-forming bacteria of faecal origin (Cl. perfringens) and of soil origin (Bacillus species). Using this monitoring strategy it was possible to determine when coastal marine waters were contaminated with non-point source pollution and when coastal waters were contaminated with point source pollution. The results of this study are most likely applicable to all countries in the warm and humid region of the world.

Spatial variability and sources of ammonia in three European cities

NASA Astrophysics Data System (ADS)

Prevot, Andre S. H.; Elser, Miriam; El Haddad, Imad; Maasikmets, Marek; Bozzetti, Carlo; Robert, Wolf; Richter, Rene; Slowik, Jay; Teinemaa, Erik; Hueglin, Christoph; Baltensperger, Urs

2017-04-01

For the assessment of ammonia (NH3) effects on ecosystems and climate, one would ideally know the emission sources and also the spatial distributions. Agriculture is the largest global source of NH3. However traffic, especially gasoline vehicles, biomass burning or waste management can be significant in urban areas. Ambient NH3 measurements using cavity ring-down spectroscopy were performed online at high time resolution on a moving vehicle in three cities: Zurich (Switzerland), Tartu (Estonia) and Tallinn (Estonia). Initial tests showed that a regular inlet cannot be used. A heated line including an auxiliary flow was finally deployed to minimize NH3 adsorption onto the inlet walls. We will present the characterization of the response and recovery times of the measurement system which was used to deconvolve the true NH3 signal from the remaining adsorption-induced hysteresis. Parallel measurements with an Aerodyne aerosol mass spectrometer were used to correct the observed NH3 for the contribution of ammonium nitrate (NH4NO3) which completely evaporated to NH3 and nitric acid (HNO3) in the heated line at the chosen temperature, in contrast to ammonium sulfate. Finally, quantitative measurements of ambient NH3 are possible with sufficient time resolution to enable measurement of NH3 point or line sources with a mobile sampling platform. The NH3 analyzer and the aerosol mass spectrometer were complemented by an aethalometer to measure black carbon and various gas-phase analyzers to enable a complete characterization of the sources of air pollution, including the spatial distributions and the regional background concentrations and urban increments of all measured components. Although at all three locations similar urban increment levels of organic aerosols were attributed to biomass burning and traffic, traffic emissions clearly dominated the city enhancements of NH3, equivalent black carbon (eBC) and carbon dioxide (CO2). Concentration gradients in areas strongly influenced by traffic emissions (including drives in and out various tunnels) were used to determine fleet average emission factors (EF) for the traffic-related pollutants. Significant differences were found between the EFs of certain components in the three cities, which were to some degree consistent with an older vehicle fleet in Estonia compared to Switzerland. Using the determined EFs we show that traffic can basically fully explain the NH3 increments in the three cities and also a non-negligible fraction of the background concentrations, which are known to be mostly related to agricultural activities. Comparisons to a European emission inventory will be discussed.

Residential Knowledge of Native Tree Species: A Case Study of Residents in Four Southern Ontario Municipalities

NASA Astrophysics Data System (ADS)

Almas, Andrew D.; Conway, Tenley M.

2017-01-01

In the past decade, municipalities across North America have increased investment in their urban forests in an effort to maintain and enhance the numerous benefits provided by them. Some municipalities have now drafted long-term urban forest management plans that emphasize the planting of native trees, to improve ecological integrity, and participation of residents, since the majority of urban trees are typically located on residential property. Yet it is unclear if residents are familiar with native trees or municipalities' urban forest management goals. Through a case study of southern Ontario municipalities, we administered a survey exploring residents' ability to correctly label common tree species as native or non-native, as well as their knowledge of urban forest management plans to test four hypotheses: 1) residents in municipalities with an urban forest management plans will be more knowledgeable about the native status of common street trees; 2) residents who have lived in the area longer will have greater knowledge; 3) knowledge level will be correlated with education level, ethnicity, and income; and 4) residents' knowledge will be related to having planted trees on their property. Our results indicate that residents are better able to identify common native trees than correctly determine which trees are non-native, although knowledge levels are generally low. Knowledge was significantly related to length of residency and tree planting experience, supporting hypotheses 2 and 4. These results highlight the importance of experience and local knowledge acquisition in relation to basic knowledge about urban trees, and also point to the failures of resident outreach within the case study municipalities.

Residential Knowledge of Native Tree Species: A Case Study of Residents in Four Southern Ontario Municipalities.

PubMed

Almas, Andrew D; Conway, Tenley M

2017-01-01

In the past decade, municipalities across North America have increased investment in their urban forests in an effort to maintain and enhance the numerous benefits provided by them. Some municipalities have now drafted long-term urban forest management plans that emphasize the planting of native trees, to improve ecological integrity, and participation of residents, since the majority of urban trees are typically located on residential property. Yet it is unclear if residents are familiar with native trees or municipalities' urban forest management goals. Through a case study of southern Ontario municipalities, we administered a survey exploring residents' ability to correctly label common tree species as native or non-native, as well as their knowledge of urban forest management plans to test four hypotheses: 1) residents in municipalities with an urban forest management plans will be more knowledgeable about the native status of common street trees; 2) residents who have lived in the area longer will have greater knowledge; 3) knowledge level will be correlated with education level, ethnicity, and income; and 4) residents' knowledge will be related to having planted trees on their property. Our results indicate that residents are better able to identify common native trees than correctly determine which trees are non-native, although knowledge levels are generally low. Knowledge was significantly related to length of residency and tree planting experience, supporting hypotheses 2 and 4. These results highlight the importance of experience and local knowledge acquisition in relation to basic knowledge about urban trees, and also point to the failures of resident outreach within the case study municipalities.

Assessing the air quality impact of nitrogen oxides and benzene from road traffic and domestic heating and the associated cancer risk in an urban area of Verona (Italy)

NASA Astrophysics Data System (ADS)

Schiavon, Marco; Redivo, Martina; Antonacci, Gianluca; Rada, Elena Cristina; Ragazzi, Marco; Zardi, Dino; Giovannini, Lorenzo

2015-11-01

Simulations of emission and dispersion of nitrogen oxides (NOx) are performed in an urban area of Verona (Italy), characterized by street canyons and typical sources of urban pollutants. Two dominant source categories are considered: road traffic and, as an element of novelty, domestic heaters. Also, to assess the impact of urban air pollution on human health and, in particular, the cancer risk, simulations of emission and dispersion of benzene are carried out. Emissions from road traffic are estimated by the COPERT 4 algorithm, whilst NOx emission factors from domestic heaters are retrieved by means of criteria provided in the technical literature. Then maps of the annual mean concentrations of NOx and benzene are calculated using the AUSTAL2000 dispersion model, considering both scenarios representing the current situation, and scenarios simulating the introduction of environmental strategies for air pollution mitigation. The simulations highlight potentially critical situations of human exposure that may not be detected by the conventional network of air quality monitoring stations. The proposed methodology provides a support for air quality policies, such as planning targeted measurement campaigns, re-locating monitoring stations and adopting measures in favour of better air quality in urban planning. In particular, the estimation of the induced cancer risk is an important starting point to conduct zoning analyses and to detect the areas where population is more directly exposed to potential risks for health.

Understanding sediment sources in a peri-urban Mediterranean catchment using geochemical tracers

NASA Astrophysics Data System (ADS)

Ferreira, Carla; Walsh, Rory; Kikuchi, Ryunosuke; Blake, Will

2016-04-01

One of the main physical environmental impacts of urbanization is an increase in suspended sediment concentrations and loads, particularly in the constructional phase. Impacts in peri-urban catchments characterized by a mosaic of urban and non-urban landscape elements with varying roles in acting as sources and sinks of overland flow and slope wash have received little attention, particularly in Mediterranean environments. The present study uses a sediment 'fingerprinting' approach to determine the main sediment sources in the peri-urban Ribeira dos Covões catchment (6.2km2) in Portugal and how they change during storm events following contrasting antecedent weather. The catchment, rural until 1972, underwent discontinuous urbanization in 1973-1993, followed by an urban consolidation phase. Currently, its land-use is a complex mosaic of woodland (56%), urban (40%) and agricultural (4%) land parcels. Distinct urban patterns include some well-defined urban residential centres, but also areas of discontinuous urban sprawl. Since 2010, a major road was built and an enterprise park has been under construction, covering 1% and 5% of the catchment, respectively. The catchment has a Mediterranean climate. The geology comprises sandstone (56%), limestone (41%) and alluvial deposits (3%). Soils are generally deep (>3.0m), but shallow (<0.4m) on steeper limestone terrain. The catchment has an average slope of 9° , but includes steep slopes of up to 46° . The sediment fingerprinting methodology involved characterizing the chemical properties of sediments from individual upstream sub-catchments and comparing these to the properties of downstream transported fluvial material. Three fine bed-sediment sampling surveys were carried out after (i) a long dry period (21/09/2012), (ii) a winter storm of relatively high rainfall intensity (23.2mm day-1) (19/02/2015), and (iii) after several storms in Spring (22/04/2015). All samples were oven-dried (at 38° C) and sieved to obtain different particle size fractions (0.125-2.000mm, 0.063-0.125mm and <0.063mm). Seventeen stream sites were sampled plus a sample of sediment from a road surface immediately it entered the stream network. The elemental composition (40 elements) of each size fraction was assessed using a Niton X-ray fluorescence elemental analyser. Results show that rock type has a profound influence on the geochemical properties of bed-sediments. Catchment outlet sediment collected after the summer and a storm of high rainfall intensity following dry weather displayed geochemical properties closer to those of sediment from sandstone sub-catchments, and in particularly sediment from the enterprise park under construction. After the storm that followed very wet weather, however, limestone areas became of much greater significance as sediment sources, probably because of the high soil saturation. At limestone stream sites receiving runoff from the newly constructed road, fine bed-sediment geochemistry was found to be similar to that of road sediment, indicating a high contribution of this source. These results are supported by spatio-temporal differences in streamflow and suspended sediment concentrations at instrumented monitoring stations. It is concluded that this methodology represents a potentially useful tool to enable river managers to detect and assess sediment sources in urbanized and partly urbanized catchments, and to supporting them in designing and implementing effective land-use mosaics and site-specific measures to mitigate erosion.

Determinants of urban sprawl in European cities

PubMed Central

Alvanides, Seraphim; Garrod, Guy

2015-01-01

This paper provides empirical evidence that helps to answer several key questions relating to the extent of urban sprawl in Europe. Building on the monocentric city model, this study uses existing data sources to derive a set of panel data for 282 European cities at three time points (1990, 2000 and 2006). Two indices of urban sprawl are calculated that, respectively, reflect changes in artificial area and the levels of urban fragmentation for each city. These are supplemented by a set of data on various economic and geographical variables that might explain the variation of the two indices. Using a Hausman-Taylor estimator and random regressors to control for the possible correlation between explanatory variables and unobservable city-level effects, we find that the fundamental conclusions of the standard monocentric model are valid in the European context for both indices. Although the variables generated by the monocentric model explain a large part of the variation of artificial area, their explanatory power for modelling the fragmentation index is relatively low. PMID:26321770

Determinants of urban sprawl in European cities.

PubMed

Oueslati, Walid; Alvanides, Seraphim; Garrod, Guy

2015-07-01

This paper provides empirical evidence that helps to answer several key questions relating to the extent of urban sprawl in Europe. Building on the monocentric city model, this study uses existing data sources to derive a set of panel data for 282 European cities at three time points (1990, 2000 and 2006). Two indices of urban sprawl are calculated that, respectively, reflect changes in artificial area and the levels of urban fragmentation for each city. These are supplemented by a set of data on various economic and geographical variables that might explain the variation of the two indices. Using a Hausman-Taylor estimator and random regressors to control for the possible correlation between explanatory variables and unobservable city-level effects, we find that the fundamental conclusions of the standard monocentric model are valid in the European context for both indices. Although the variables generated by the monocentric model explain a large part of the variation of artificial area, their explanatory power for modelling the fragmentation index is relatively low.

Tool for assessing health and equity impacts of interventions modifying air quality in urban environments.

PubMed

Cartier, Yuri; Benmarhnia, Tarik; Brousselle, Astrid

2015-12-01

Urban outdoor air pollution (AP) is a major public health concern but the mechanisms by which interventions impact health and social inequities are rarely assessed. Health and equity impacts of policies and interventions are questioned, but managers and policy agents in various institutional contexts have very few practical tools to help them better orient interventions in sectors other than the health sector. Our objective was to create such a tool to facilitate the assessment of health impacts of urban outdoor AP interventions by non-public health experts. An iterative process of reviewing the academic literature, brainstorming, and consultation with experts was used to identify the chain of effects of urban outdoor AP and the major modifying factors. To test its applicability, the tool was applied to two interventions, the London Low Emission Zone and the Montréal BIXI public bicycle-sharing program. We identify the chain of effects, six categories of modifying factors: those controlling the source of emissions, the quantity of emissions, concentrations of emitted pollutants, their spatial distribution, personal exposure, and individual vulnerability. Modifiable and non-modifiable factors are also identified. Results are presented in the text but also graphically, as we wanted it to be a practical tool, from pollution sources to emission, exposure, and finally, health effects. The tool represents a practical first step to assessing AP-related interventions for health and equity impacts. Understanding how different factors affect health and equity through air pollution can provide insight to city policymakers pursuing Health in All Policies. Copyright © 2015 The Authors. Published by Elsevier Ltd.. All rights reserved.

A historical study of rural-to-urban migration in China: 1949-1985.

PubMed

Zhao, Y; Liu, Q

1997-01-01

This paper reviews the literature on labor migration in China since the 1950s and examines the trends in rural-to-urban migration during the period of 1949 to the mid-1980s. Data were obtained from the 1986 sample survey on migration in 74 urban areas in China among 23,895 family households and 1643 collective households in 43 cities and 31 townships of 16 provinces. Non-farmers from rural areas were subtracted from total rural migrants. Non-farmers included recent urban high school graduates and party and government officials who were sent to rural areas during the Cultural Revolution and returned to cities. The sample included 53.3% men. The average age was 23.1 years. About 50% were married at the time of migration. The average educational attainment among persons aged over 15 years was 5.98 years. Reasons for migration included family reunion (49.7%), worker recruitment (28.5%), military recruitment (8.8%), and college attendance (3.0%). The volume of migration fluctuated greatly during 1949-85. During 1949-55, about 200 people in the 200,000 sample size migrated each year. During 1955-58, migrants numbered 459, 307, and 616, respectively. During the famine of 1959-61, migration dropped to 312, 292, and 124, respectively. 1961 was the lowest point of migration; 1958 was the highest point of migration before 1984. During the 1962-64 recovery period, migration remained low at under 200. During 1962-64, migrants totaled 200-300 persons. During the Cultural Revolution of 1967-68, migrants declined to under 200. During 1970-71, migrants increased to over 400 until 1979, when the number reached 576. The largest migration occurred during 1984-85 and peaked at 832 in 1985. The later years reflect a loosening of government policy. Migration followed political events closely. Migrants in later years were unlikely to attain urban resident status and benefits without fundamental policy changes.

Modeling urban coastal flood severity from crowd-sourced flood reports using Poisson regression and Random Forest

NASA Astrophysics Data System (ADS)

Sadler, J. M.; Goodall, J. L.; Morsy, M. M.; Spencer, K.

2018-04-01

Sea level rise has already caused more frequent and severe coastal flooding and this trend will likely continue. Flood prediction is an essential part of a coastal city's capacity to adapt to and mitigate this growing problem. Complex coastal urban hydrological systems however, do not always lend themselves easily to physically-based flood prediction approaches. This paper presents a method for using a data-driven approach to estimate flood severity in an urban coastal setting using crowd-sourced data, a non-traditional but growing data source, along with environmental observation data. Two data-driven models, Poisson regression and Random Forest regression, are trained to predict the number of flood reports per storm event as a proxy for flood severity, given extensive environmental data (i.e., rainfall, tide, groundwater table level, and wind conditions) as input. The method is demonstrated using data from Norfolk, Virginia USA from September 2010 to October 2016. Quality-controlled, crowd-sourced street flooding reports ranging from 1 to 159 per storm event for 45 storm events are used to train and evaluate the models. Random Forest performed better than Poisson regression at predicting the number of flood reports and had a lower false negative rate. From the Random Forest model, total cumulative rainfall was by far the most dominant input variable in predicting flood severity, followed by low tide and lower low tide. These methods serve as a first step toward using data-driven methods for spatially and temporally detailed coastal urban flood prediction.

Microbial water pollution: a screening tool for initial catchment-scale assessment and source apportionment.

PubMed

Kay, D; Anthony, S; Crowther, J; Chambers, B J; Nicholson, F A; Chadwick, D; Stapleton, C M; Wyer, M D

2010-11-01

The European Union Water Framework Directive requires that Management Plans are developed for individual River Basin Districts. From the point of view of faecal indicator organisms (FIOs), there is a critical need for screening tools that can provide a rapid assessment of the likely FIO concentrations and fluxes within catchments under base- and high-flow conditions, and of the balance ('source apportionment') between agriculture- and sewage-derived sources. Accordingly, the present paper reports on: (1) the development of preliminary generic models, using water quality and land cover data from previous UK catchment studies for assessing FIO concentrations, fluxes and source apportionment within catchments during the summer bathing season; (2) the calibration of national land use data, against data previously used in the models; and (3) provisional FIO concentration and source-apportionment assessments for England and Wales. The models clearly highlighted the crucial importance of high-flow conditions for the flux of FIOs within catchments. At high flow, improved grassland (and associated livestock) was the key FIO source; FIO loadings derived from catchments with high proportions of improved grassland were shown to be as high as from urbanized catchments; and in many rural catchments, especially in NW and SW England and Wales, which are important areas of lowland livestock (especially dairy) farming, ≥ 40% of FIOs was assessed to be derived from agricultural sources. In contrast, under base-flow conditions, when there was little or no runoff from agricultural land, urban (i.e. sewerage-related) sources were assessed to dominate, and even in rural areas the majority of FIOs were attributed to urban sources. The results of the study demonstrate the potential of this type of approach, particularly in light of climate change and the likelihood of more high-flow events, in underpinning informed policy development and prioritization of investment. Copyright © 2009 Elsevier B.V. All rights reserved.

The foodscape: classification and field validation of secondary data sources.

PubMed

Lake, Amelia A; Burgoine, Thomas; Greenhalgh, Fiona; Stamp, Elaine; Tyrrell, Rachel

2010-07-01

The aims were to: develop a food environment classification tool and to test the acceptability and validity of three secondary sources of food environment data within a defined urban area of Newcastle-Upon-Tyne, using a field validation method. A 21 point (with 77 sub-categories) classification tool was developed. The fieldwork recorded 617 establishments selling food and/or food products. The sensitivity analysis of the secondary sources against fieldwork for the Newcastle City Council data was good (83.6%), while Yell.com and the Yellow Pages were low (51.2% and 50.9%, respectively). To improve the quality of secondary data, multiple sources should be used in order to achieve a realistic picture of the foodscape. 2010 Elsevier Ltd. All rights reserved.

Examining the influence of urban definition when assessing relative safety of drinking-water in Nigeria.

PubMed

Christenson, Elizabeth; Bain, Robert; Wright, Jim; Aondoakaa, Stephen; Hossain, Rifat; Bartram, Jamie

2014-08-15

Reducing inequalities is a priority from a human rights perspective and in water and public health initiatives. There are periodic calls for differential national and global standards for rural and urban areas, often justified by the suggestion that, for a given water source type, safety is worse in urban areas. For instance, initially proposed post-2015 water targets included classifying urban but not rural protected dug wells as unimproved. The objectives of this study were to: (i) examine the influence of urban extent definition on water safety in Nigeria, (ii) compare the frequency of thermotolerant coliform (TTC) contamination and prevalence of sanitary risks between rural and urban water sources of a given type and (iii) investigate differences in exposure to contaminated drinking-water in rural and urban areas. We use spatially referenced data from a Nigerian national randomized sample survey of five improved water source types to assess the extent of any disparities in urban-rural safety. We combined the survey data on TTC and sanitary risk with map layers depicting urban versus rural areas according to eight urban definitions. When examining water safety separately for each improved source type, we found no significant urban-rural differences in TTC contamination and sanitary risk for groundwater sources (boreholes and protected dug wells) and inconclusive findings for piped water and stored water. However, when improved and unimproved source types were combined, TTC contamination was 1.6 to 2.3 times more likely in rural compared to urban water sources depending on the urban definition. Our results suggest that different targets for urban and rural water safety are not justified and that rural dwellers are more exposed to unsafe water than urban dwellers. Additionally, urban-rural analyses should assess multiple definitions or indicators of urban to assess robustness of findings and to characterize a gradient that disaggregates the urban-rural dichotomy. Copyright © 2014 Elsevier B.V. All rights reserved.

Delivering Cognitive Processing Therapy in a Community Health Setting: The Influence of Latino Culture and Community Violence on Posttraumatic Cognitions

PubMed Central

Marques, Luana; Eustis, Elizabeth H.; Dixon, Louise; Valentine, Sarah E.; Borba, Christina; Simon, Naomi; Kaysen, Debra; Wiltsey-Stirman, Shannon

2015-01-01

Despite the applicability of Cognitive Processing Therapy (CPT) for Posttraumatic Stress Disorder (PTSD) to addressing sequelae of a range of traumatic events, few studies have evaluated whether the treatment itself is applicable across diverse populations. The present study examined differences and similarities amongst non-Latino, Latino Spanish-speaking, and Latino English-speaking clients in rigid beliefs – or “stuck points” – associated with PTSD symptoms in a sample of community mental health clients. We utilized the procedures of content analysis to analyze stuck point logs and impact statements of 29 participants enrolled in a larger implementation trial for CPT. Findings indicated that the content of stuck points was similar across Latino and non-Latino clients, although fewer total stuck points were identified for Latino clients compared to non-Latino clients. Given that identification of stuck points is central to implementing CPT, difficulty identifying stuck points could pose significant challenges for implementing CPT among Latino clients and warrants further examination. Thematic analysis of impact statements revealed the importance of family, religion, and the urban context (e.g., poverty, violence exposure) in understanding how clients organize beliefs and emotions associated with trauma. Clinical recommendations for implementing CPT in community settings and the identification of stuck points are provided. PMID:25961865

Calibration and Validation of Nonpoint Source Pollution and Erosion Comparison Tool,N- SPECT, for Tropical Conditions

NASA Astrophysics Data System (ADS)

Fares, A.; Cheng, C. L.; Dogan, A.

2006-12-01

Impaired water quality caused by agriculture, urbanization, and spread of invasive species has been identified as a major factor in the degradation of coastal ecosystems in the tropics. Watershed-scale nonpoint source pollution models facilitate in evaluating effective management practices to alleviate the negative impacts of different land-use changes. The Non-Point Source Pollution and Erosion Comparison Tool (N-SPECT) is a newly released watershed model that was not previously tested under tropical conditions. The two objectives of this study were to: i) calibrate and validate N-SPECT for the Hanalei Watershed of the Hawai`ian island of Kaua`i; ii) evaluate the performance of N-SPECT under tropical conditions using the sensitivity analysis approach. Hanalei watershed has one of the wettest points on earth, Mt. Waialeale with an average annual rainfall of 11,000 mm. This rainfall decreases to 2,000 mm at the outlet of the watershed near the coast. Number of rain days is one of the major input parameters that influences N-SPECT's simulation results. This parameter was used to account for plant canopy interception losses. The watershed was divided into sub- basins to accurately distribute the number of rain days throughout the watershed. Total runoff volume predicted by the model compared well with measured data. The model underestimated measured runoff by 1% for calibration period and 5% for validation period due to higher intensity precipitation in the validation period. Sensitivity analysis revealed that the model was most sensitive to the number of rain days, followed by canopy interception, and least sensitive to the number of sub-basins. The sediment and water quality portion of the model is currently being evaluated.

A summary of total mercury concentrations in flora and fauna near common contaminant sources in the Gulf of Mexico.

PubMed

Lewis, M; Chancy, C

2008-02-01

Total mercury concentrations are summarized for environmental media and biota collected from near-coastal areas, several impacted by contaminant sources common to the Gulf of Mexico. Water, sediment, fish, blue crabs, oysters, clams, mussels, periphyton and seagrasses were collected during 1993-2002 from targeted areas affected by point and non-point source contaminants. Mean concentrations in water and sediment were 0.02 (+/-1 standard deviation=0.06) microg l(-1) and 96.3 (230.8) ng g(-1) dry wt, respectively. Mean total mercury concentrations in fish, blue crabs, brackish clams and mussels were significantly greater than those in sediment, seagrass, colonized periphyton and oysters. Concentrations (ng g(-1) dry wt) averaged 23.1 (two seagrass species), 220.1 (oysters), 287.8 (colonized periphyton), 604.0 (four species of freshwater mussels), 772.4 (brackish clam), 857.9 (blue crabs) and 933.1 (nine fish species). Spatial, intraspecific and interspecific variability in results limited most generalizations concerning the relative mercury contributions of different stressor types. However, concentrations were significantly greater for some biota collected from areas receiving wastewater discharges and golf course runoff (fish), agricultural runoff (oysters) and urban stormwater runoff (colonized periphyton and sediment). Marine water quality criteria and proposed sediment quality guidelines were exceeded in 1-12% of total samples. At least one seafood consumption guideline, criteria or screening value were exceeded in edible tissues of blue crabs (6% total samples) and nine fish species (8-33% total samples) but all residues were less than the US Federal Drug Administration action limit of 1.0 ppm and the few reported toxic effect concentrations available for the targeted biota.

Impact of Santiago de Chile urban atmospheric pollution on anthropogenic trace elements enrichment in snow precipitation at Cerro Colorado, Central Andes

NASA Astrophysics Data System (ADS)

Cereceda-Balic, F.; Palomo-Marín, M. R.; Bernalte, E.; Vidal, V.; Christie, J.; Fadic, X.; Guevara, J. L.; Miro, C.; Pinilla Gil, E.

2012-02-01

Seasonal snow precipitation in the Andes mountain range is evaluated as an environmental indicator of the composition of atmospheric emissions in Santiago de Chile metropolitan area, by measuring a set of representative trace elements in snow samples by ICP-MS. Three late winter sampling campaigns (2003, 2008 and 2009) were conducted in three sampling areas around Cerro Colorado, a Central Andes mountain range sector NE of Santiago (36 km). Nevados de Chillán, a sector in The Andes located about 500 km south from the metropolitan area, was selected as a reference area. The experimental results at Cerro Colorado and Nevados de Chillán were compared with previously published data of fresh snow from remote and urban background sites. High snow concentrations of a range of anthropogenic marker elements were found at Cerro Colorado, probably derived from Santiago urban aerosol transport and deposition combined with the effect of mining and smelting activities in the area, whereas Nevados de Chillán levels roughly correspond to urban background areas. Enhanced concentrations in surface snow respect to deeper samples are discussed. Significant differences found between the 2003, 2008 and 2009 anthropogenic source markers profiles at Cerro Colorado sampling points were correlated with changes in emission sources at the city. The preliminary results obtained in this study, the first of this kind in the southern hemisphere, show promising use of snow precipitation in the Central Andes as a suitable matrix for receptor model studies aimed at identifying and quantifying pollution sources in Santiago de Chile.

Analysis of heavy metal sources in storm water from urban areas

NASA Astrophysics Data System (ADS)

Scherer, U.; Fuchs, S.

2009-04-01

The input of heavy metals into surface waters is a serious impairment of the aquatic environment. The emissions of heavy metals via point and diffuse pathways into the German river basins were thus quantified for the period of 1985 through 2005. The total emission into the German river systems decreased for each metal during the observed period. This reduction is mainly caused by the decline of emissions via point sources. The measures taken by industry and implemented within the scope of a stringently water legislation have decisively contributed to an improvement of environmental conditions. Today's emissions of heavy metals into river basins of Germany are dominated by the input via diffuse pathways. One of the most important diffuse input is the storm water discharged from paved urban areas into the surface waters via storm sewers and combined sewer overflows especially for the metals copper, zinc and lead. The objective of this project was to identify the sources of these three heavy metals washed of from paved urban areas. The use of copper, zinc and lead on the outsides of buildings results in emissions to water and soil via rainwater due to weathering and runoff of soluble and insoluble metallic compounds. Copper and zinc are traditionally used materials in the building sector especially for roofs, gutters and facades. Lead, in contrast, plays only a subordinate role due to its more limited outdoor use. The corrosion rates vary widely. Climatic factors (temperature, humidity etc.), above all the presence of corrosive gases (sulphur dioxide, nitrogen oxide, ozone etc.) influence the corrosion processes. Estimates of industrial associations were referred to in order to determine the corrosion relevant metal surfaces. Heavy metal emissions caused by traffic are complex and depend on many parameters which vary by locality, time and substance. In principle, substances can be emitted by vehicles, the road surface and by maintenance. Emissions of copper, lead and zinc are mainly caused by wear and tear of tyres and brake pads. The reference figures of the environmental emissions are usually the kilometres driven per vehicle. The emissions can then be calculated based on the road performance. Furthermore atmospheric deposition on paved urban areas was considered. The heavy metal emission from each individual source and the portion discharged into surface waters via storm sewers and combined sewer overflows was quantified. The emission sum of all sources was validated using emission data of storm sewers based on measured heavy metal concentrations and the discharge volume showing a good agreement.

Physical and non-physical energy in scattered wave source-receiver interferometry.

PubMed

Meles, Giovanni Angelo; Curtis, Andrew

2013-06-01

Source-receiver interferometry allows Green's functions between sources and receivers to be estimated by means of convolution and cross-correlation of other wavefields. Source-receiver interferometry has been observed to work surprisingly well in practical applications when theoretical requirements (e.g., complete enclosing boundaries of other sources and receivers) are contravened: this paper contributes to explain why this may be true. Commonly used inter-receiver interferometry requires wavefields to be generated around specific stationary points in space which are controlled purely by medium heterogeneity and receiver locations. By contrast, application of source-receiver interferometry constructs at least kinematic information about physically scattered waves between a source and a receiver by cross-convolution of scattered waves propagating from and to any points on the boundary. This reduces the ambiguity in interpreting wavefields generated using source-receiver interferometry with only partial boundaries (as is standard in practical applications), as it allows spurious or non-physical energy in the constructed Green's function to be identified and ignored. Further, source-receiver interferometry (which includes a step of inter-receiver interferometry) turns all types of non-physical or spurious energy deriving from inter-receiver interferometry into what appears to be physical energy. This explains in part why source-receiver interferometry may perform relatively well compared to inter-receiver interferometry when constructing scattered wavefields.

Integrated modeling approach using SELECT and SWAT models to simulate source loading and in-stream conditions of fecal indicator bacteria.

NASA Astrophysics Data System (ADS)

Ranatunga, T.

2016-12-01

Modeling of fate and transport of fecal bacteria in a watershed is generally a processed based approach that considers releases from manure, point sources, and septic systems. Overland transport with water and sediments, infiltration into soils, transport in the vadose zone and groundwater, die-off and growth processes, and in-stream transport are considered as the other major processes in bacteria simulation. This presentation will discuss a simulation of fecal indicator bacteria (E.coli) source loading and in-stream conditions of a non-tidal watershed (Cedar Bayou Watershed) in South Central Texas using two models; Spatially Explicit Load Enrichment Calculation Tool (SELECT) and Soil and Water Assessment Tool (SWAT). Furthermore, it will discuss a probable approach of bacteria source load reduction in order to meet the water quality standards in the streams. The selected watershed is listed as having levels of fecal indicator bacteria that posed a risk for contact recreation and wading by the Texas Commission of Environmental Quality (TCEQ). The SELECT modeling approach was used in estimating the bacteria source loading from land categories. Major bacteria sources considered were, failing septic systems, discharges from wastewater treatment facilities, excreta from livestock (Cattle, Horses, Sheep and Goat), excreta from Wildlife (Feral Hogs, and Deer), Pet waste (mainly from Dogs), and runoff from urban surfaces. The estimated source loads were input to the SWAT model in order to simulate the transport through the land and in-stream conditions. The calibrated SWAT model was then used to estimate the indicator bacteria in-stream concentrations for future years based on H-GAC's regional land use, population and household projections (up to 2040). Based on the in-stream reductions required to meet the water quality standards, the corresponding required source load reductions were estimated.

Application of SELECT and SWAT models to simulate source load, fate, and transport of fecal bacteria in watersheds.

NASA Astrophysics Data System (ADS)

Ranatunga, T.

2017-12-01

Modeling of fate and transport of fecal bacteria in a watershed is a processed based approach that considers releases from manure, point sources, and septic systems. Overland transport with water and sediments, infiltration into soils, transport in the vadose zone and groundwater, die-off and growth processes, and in-stream transport are considered as the other major processes in bacteria simulation. This presentation will discuss a simulation of fecal indicator bacteria source loading and in-stream conditions of a non-tidal watershed (Cedar Bayou Watershed) in South Central Texas using two models; Spatially Explicit Load Enrichment Calculation Tool (SELECT) and Soil and Water Assessment Tool (SWAT). Furthermore, it will discuss a probable approach of bacteria source load reduction in order to meet the water quality standards in the streams. The selected watershed is listed as having levels of fecal indicator bacteria that posed a risk for contact recreation and wading by the Texas Commission of Environmental Quality (TCEQ). The SELECT modeling approach was used in estimating the bacteria source loading from land categories. Major bacteria sources considered were, failing septic systems, discharges from wastewater treatment facilities, excreta from livestock (Cattle, Horses, Sheep and Goat), excreta from Wildlife (Feral Hogs, and Deer), Pet waste (mainly from Dogs), and runoff from urban surfaces. The estimated source loads from SELECT model were input to the SWAT model, and simulate the bacteria transport through the land and in-stream. The calibrated SWAT model was then used to estimate the indicator bacteria in-stream concentrations for future years based on regional land use, population and household forecast (up to 2040). Based on the reductions required to meet the water quality standards in-stream, the corresponding required source load reductions were estimated.

Mapping CO2 emission in highly urbanized region using standardized microbial respiration approach

NASA Astrophysics Data System (ADS)

Vasenev, V. I.; Stoorvogel, J. J.; Ananyeva, N. D.

2012-12-01

Urbanization is a major recent land-use change pathway. Land conversion to urban has a tremendous and still unclear effect on soil cover and functions. Urban soil can act as a carbon source, although its potential for CO2 emission is also very high. The main challenge in analysis and mapping soil organic carbon (SOC) in urban environment is its high spatial heterogeneity and temporal dynamics. The urban environment provides a number of specific features and processes that influence soil formation and functioning and results in a unique spatial variability of carbon stocks and fluxes at short distance. Soil sealing, functional zoning, settlement age and size are the predominant factors, distinguishing heterogeneity of urban soil carbon. The combination of these factors creates a great amount of contrast clusters with abrupt borders, which is very difficult to consider in regional assessment and mapping of SOC stocks and soil CO2 emission. Most of the existing approaches to measure CO2 emission in field conditions (eddy-covariance, soil chambers) are very sensitive to soil moisture and temperature conditions. They require long-term sampling set during the season in order to obtain relevant results. This makes them inapplicable for the analysis of CO2 emission spatial variability at the regional scale. Soil respiration (SR) measurement in standardized lab conditions enables to overcome this difficulty. SR is predominant outgoing carbon flux, including autotrophic respiration of plant roots and heterotrophic respiration of soil microorganisms. Microbiota is responsible for 50-80% of total soil carbon outflow. Microbial respiration (MR) approach provides an integral CO2 emission results, characterizing microbe CO2 production in optimal conditions and thus independent from initial difference in soil temperature and moisture. The current study aimed to combine digital soil mapping (DSM) techniques with standardized microbial respiration approach in order to analyse and map CO2 emission and its spatial variability in highly urbanized Moscow region. Moscow region with its variability of bioclimatic conditions and high urbanization level (10 % from the total area) was chosen as an interesting case study. Random soil sampling in different soil zones (4) and land-use types (3 non-urban and 3 urban) was organized in Moscow region in 2010-2011 (n=242). Both topsoil (0-10 cm) and subsoil (10-150 cm) were included. MR for each point was analysed using standardized microbial (basal) respiration approach, including the following stages: 1) air dried soil samples were moisturised up to 55% water content and preincubated (7 days, 22° C) in a plastic bag with air exchange; 2) soil MR (in μg CO2-C g-1) was measured as the rate of CO2 production (22° C, 24 h) after incubating 2g soil with 0.2 μl distilled water; 3) the MR results were used to estimate CO2 emission (kg C m-2 yr-1). Point MR and CO2 emission results obtained were extrapolated for the Moscow region area using regression model. As a result, two separate CO2 maps for topsoil and subsoil were created. High spatial variability was demonstrated especially for the urban areas. Thus standardized MR approach combined with DSM techniques provided a unique opportunity for spatial analysis of soil carbon temporal dynamics at the regional scale.

75 FR 2452 - Approval and Promulgation of Air Quality Implementation Plans; Delaware; Reasonable Further...

Federal Register 2010, 2011, 2012, 2013, 2014

2010-01-15

... Lightering Operations. Since there will be no new VOC controls for point sources, non-point source sector... equivalent to 1.52 x 1.74 = 2.64 tpd NO X reduction shortfall. Delaware has implemented numerous controls... achieved ``as expeditious as practicable.'' Control measures under RACT constitute a major group of RACM...

Spatial Variations In The Fate And Transport Of Metals In A Mining-Influenced Stream, North Fork Clear Creek, Colorado

EPA Science Inventory

North Fork Clear Creek (NFCC) receives acid-mine drainage (AMD) from multiple abandoned mines in the Clear Creek Watershed. Point sources of AMD originate In the Black Hawk/Central City region of the stream. Water chemistry also is influenced by several non-point sources of AMD,...

The science, information, and engineering needed to manage water availability and quality in 2050: Chapter 23

USGS Publications Warehouse

Hirsch, Robert M.

2012-01-01

This chapter explores four water resources issues: 1) hydrologic variability, hazards, water supply and ecosystem preservation; 2) urban landscape design; 3) non-point source water quality, and 4) climate change, resiliency, and nonstationarity. It also considers what science, technology, and engineering practice may be needed in the coming decades to sustain water supplies and ecosystems in the face of increasing stresses from a growing demand for water. Dealing with these four water resource issues in the highly uncertain future would will demand predictive models that are rooted in real-world data. In a non-stationary world, continuity of observations is crucial. All watersheds are influenced by human actions through changes in land use, water use, and climate. The focus of water planning and management between today and 2050 will depend more than ever on collection and analysis of long-term data to learn about the evolving state of the system, understanding ecosystem processes in the water and on the landscape, and finding innovative ways to manage water as a shared resource. This includes sharing water with our neighbors on the landscape, sharing with the other species that depend on water, and sharing with future generations.

Effect of lixiviated sediments affected with treated water on Selenastrum capricornutum, Printz and Origanum vulgare L.

PubMed

Ramos, Guadalupe E; Lopez, Martin H; Flores, Antonio M; Figueroa, Guadalupe T; De Leon, Fernando G

2010-01-01

Xochimilco is an area of Mexico City fulfilling important ecological functions. However, the water of the canal network in the lacustrine zone of Xochimilco is supplied by the water treatment plants of the city, implying a risk of accumulated contaminants in the sediments. This study reports the effect of lixiviates obtained from sediments collected in the canals of Xochimilco on the growth of the alga Selenastrum capricornutum and the angiosperm Origanum vulgare. Three factors were tested: (a) water source in terms of the effluent from the two water treatment plants (urban waste-water, located at Cerro de la Estrella (CE) and urban-rural waters at San Luis Tlaxialtemalco (SLT); (b) sampling season (January, dry season; May and September, rainy season; and (c) distances from the water discharge point in the Xochimilco's main canal (5200 and 1000 m for CE, and 0, 200 m for SLT). The chemical water properties analyzed were: pH, electrical conductivity, N-NO(3), N-NH(3), N(Total), P-PO(4) and P(Total). The alga was more sensitive to the contaminants than O. vulgare, showing growth inhibition of 93-100%. The effect of sampling season on the inhibition of algal growth was ordered as follows: September > May > January. Lixiviates obtained from sediment samples 200 and 1000 m from the main point of water discharge caused a higher algal growth inhibition than the samples obtained at the source point. Lixiviate promoted the growth of seedlings of O. vulgare.

Understanding the health impacts of urbanization in China: A living laboratory for urban biogeochemistry research

NASA Astrophysics Data System (ADS)

Zhu, Y. G.

2015-12-01

China has the largest population in the world, and by 2011, more than 50% of its population are now living in cities. This ongoing societal change has profound impacts on environmental quality and population health. In addition to intensive discharges of waste, urbanization is not only changing the land use and land cover, but also inducing fundamental changes in biogeochemical processes. Unlike biogeochemistry in non-urban environment, the biological component of urban biogeochemistry is dominated by direct human activities, such as air pollution derived from transport, wastewater treatment, garbage disposal and increase in impervious surface etc. Managing urban biogeochemistry will include source control over waste discharge, eco-infrastructure (such as green space and eco-drainage), resource recovery from urban waste stream, and integration with peri-urban ecosystem, particularly with food production system. The overall goal of managing urban biogeochemistry is for human health and wellbeing, which is a global challenge. In this paper, the current status of urban biogeochemistry research in China will be briefly reviewed, and then it will focus on nutrient recycling and waste management, as these are the major driving forces of environmental quality changes in urban areas. This paper will take a holistic view on waste management, covering urban metabolism analysis, technological innovation and integration for resource recovery from urban waste stream, and risk management related to waste recycling and recovery.

X-ray Point Source Populations in Spiral and Elliptical Galaxies

NASA Astrophysics Data System (ADS)

Colbert, E.; Heckman, T.; Weaver, K.; Strickland, D.

2002-01-01

The hard-X-ray luminosity of non-active galaxies has been known to be fairly well correlated with the total blue luminosity since the days of the Einstein satellite. However, the origin of this hard component was not well understood. Some possibilities that were considered included X-ray binaries, extended upscattered far-infrared light via the inverse-Compton process, extended hot 107 K gas (especially in ellipitical galaxies), or even an active nucleus. Chandra images of normal, elliptical and starburst galaxies now show that a significant amount of the total hard X-ray emission comes from individual point sources. We present here spatial and spectral analyses of the point sources in a small sample of Chandra obervations of starburst galaxies, and compare with Chandra point source analyses from comparison galaxies (elliptical, Seyfert and normal galaxies). We discuss possible relationships between the number and total hard luminosity of the X-ray point sources and various measures of the galaxy star formation rate, and discuss possible options for the numerous compact sources that are observed.

Common Pitfalls in F77 Code Conversion

DTIC Science & Technology

2003-02-01

implementation versus another are the source of these errors rather than typography . It is well to use the practice of commenting-out original source file lines...identifier), every I in the format field must be replaced with f followed by an appropriate floating point format designator . Floating point numeric...helps even more. Finally, libraries are a major source of non-portablility[sic], with graphics libraries one of the chief culprits. We in Fusion

INCORPORATION OF DNA BARCODES INTO ASSESSMENTS OF THE BIOLOGICAL INTEGRITY OF AQUATIC ECOSYSTEMS: PRECISION, ACCURACY AND COST

EPA Science Inventory

Historically, water quality assessments in the United States primarily focused on water chemistry assays at or near discharge sources. As it has become clear that waters also can be highly impaired from dispersed (i.e., non-point source) chemicals and non-chemical impacts, direc...

Effects of wastewater effluent discharge on stream quality in Indian Creek, Johnson County, Kansas

USGS Publications Warehouse

Graham, Jennifer L.; Foster, Guy M.

2014-01-01

Contaminants from point and other urban sources affect stream quality in Indian Creek, which is one of the most urban drainage basins in Johnson County, Kansas. The Johnson County Douglas L. Smith Middle Basin and Tomahawk Creek Wastewater Treatment Facilities discharge to Indian Creek. Data collected by the U.S. Geological Survey, in cooperation with Johnson County Wastewater, during June 2004 through June 2013 were used to evaluate stream quality in Indian Creek. This fact sheet summarizes the effects of wastewater effluent discharge on physical, chemical, and biological conditions in Indian Creek downstream from the Douglas L. Smith Middle Basin and Tomahawk Creek Wastewater Treatment Facilities.

Response of non-point source pollutant loads to climate change in the Shitoukoumen reservoir catchment.

PubMed

Zhang, Lei; Lu, Wenxi; An, Yonglei; Li, Di; Gong, Lei

2012-01-01

The impacts of climate change on streamflow and non-point source pollutant loads in the Shitoukoumen reservoir catchment are predicted by combining a general circulation model (HadCM3) with the Soil and Water Assessment Tool (SWAT) hydrological model. A statistical downscaling model was used to generate future local scenarios of meteorological variables such as temperature and precipitation. Then, the downscaled meteorological variables were used as input to the SWAT hydrological model calibrated and validated with observations, and the corresponding changes of future streamflow and non-point source pollutant loads in Shitoukoumen reservoir catchment were simulated and analyzed. Results show that daily temperature increases in three future periods (2010-2039, 2040-2069, and 2070-2099) relative to a baseline of 1961-1990, and the rate of increase is 0.63°C per decade. Annual precipitation also shows an apparent increase of 11 mm per decade. The calibration and validation results showed that the SWAT model was able to simulate well the streamflow and non-point source pollutant loads, with a coefficient of determination of 0.7 and a Nash-Sutcliffe efficiency of about 0.7 for both the calibration and validation periods. The future climate change has a significant impact on streamflow and non-point source pollutant loads. The annual streamflow shows a fluctuating upward trend from 2010 to 2099, with an increase rate of 1.1 m(3) s(-1) per decade, and a significant upward trend in summer, with an increase rate of 1.32 m(3) s(-1) per decade. The increase in summer contributes the most to the increase of annual load compared with other seasons. The annual NH (4) (+) -N load into Shitoukoumen reservoir shows a significant downward trend with a decrease rate of 40.6 t per decade. The annual TP load shows an insignificant increasing trend, and its change rate is 3.77 t per decade. The results of this analysis provide a scientific basis for effective support of decision makers and strategies of adaptation to climate change.

Increased nutrient concentrations in Lake Erie tributaries influenced by greenhouse agriculture.

PubMed

Maguire, Timothy J; Wellen, Christopher; Stammler, Katie L; Mundle, Scott O C

2018-08-15

Greenhouse production of vegetables is a growing global trade. While greenhouses are typically captured under regulations aimed at farmland, they may also function as a point source of effluent. In this study, the cumulative impacts greenhouse effluents have on riverine macronutrient and trace metal concentrations were examined. Water samples were collected Bi-weekly for five years from 14 rivers in agriculturally dominated watersheds in southwestern Ontario. Nine of the watersheds contained greenhouses with their boundaries. Greenhouse influenced rivers had significantly higher concentrations of macronutrients (nitrogen, phosphorus, and potassium) and trace metals (copper, molybdenum, and zinc). Concentrations within greenhouse influenced rivers appeared to decrease over the 5-year study while concentrations within non-greenhouse influenced river remained constant. The different temporal pattern between river types was attributed to increased precipitation during the study period. Increases in precipitation diluted concentrations in greenhouse influenced rivers; however, non-influenced river runoff proportionally increased nutrient mobility and flow, stabilizing the observed concentrations of non-point sources. Understanding the dynamic nature of environmental releases of point and non-point sources of nutrients and trace metals in mixed agricultural systems using riverine water chemistry is complicated by changes in climatic conditions, highlighting the need for long-term monitoring of nutrients, river flows and weather data in assessing these agricultural sectors. Copyright © 2018 The Authors. Published by Elsevier B.V. All rights reserved.

Exposure to coarse and fine particulate matter at and around major intra-urban traffic intersections of Ilorin metropolis, Nigeria

NASA Astrophysics Data System (ADS)

Adeniran, J. A.; Yusuf, R. O.; Olajire, A. A.

2017-10-01

This study aims to determine the seasonal variations and composition of suspended particulate matter in different sizes PM1.0, PM2.5, PM10 and the total suspended particles (TSP) emitted at major intra-urban traffic intersections (TIs) of Ilorin metropolis. The concentration levels of PM (PM1.0, PM2.5, PM10) obtained at the TIs during the rush hours (45.1, 77.9, and 513 μg/m3) are higher than the levels obtained for the non-rush hour periods (42.3, 62.7, and 390 μg/m3). The average on-road respiratory deposition dose (RDD) rates of PM1.0, PM2.5 and PM10 during the dry period at TIs types was found to be about 24%, 9% and 25% higher than those obtained during the wet period. Based on EF values calculated, Pb and Zn were anthropogenically-derived while Fe, Mn, Cr, Cu and Mg were of crustal source. Principal component analysis (PCA) has been applied to a set of PM data in order to determine the contribution of different sources. It was found that the main principal factors extracted from particulate emission data were related to exhaust and non-exhaust emissions such as tyre wears, oil and fuel combustion sources.

Automatic tree parameter extraction by a Mobile LiDAR System in an urban context.

PubMed

Herrero-Huerta, Mónica; Lindenbergh, Roderik; Rodríguez-Gonzálvez, Pablo

2018-01-01

In an urban context, tree data are used in city planning, in locating hazardous trees and in environmental monitoring. This study focuses on developing an innovative methodology to automatically estimate the most relevant individual structural parameters of urban trees sampled by a Mobile LiDAR System at city level. These parameters include the Diameter at Breast Height (DBH), which was estimated by circle fitting of the points belonging to different height bins using RANSAC. In the case of non-circular trees, DBH is calculated by the maximum distance between extreme points. Tree sizes were extracted through a connectivity analysis. Crown Base Height, defined as the length until the bottom of the live crown, was calculated by voxelization techniques. For estimating Canopy Volume, procedures of mesh generation and α-shape methods were implemented. Also, tree location coordinates were obtained by means of Principal Component Analysis. The workflow has been validated on 29 trees of different species sampling a stretch of road 750 m long in Delft (The Netherlands) and tested on a larger dataset containing 58 individual trees. The validation was done against field measurements. DBH parameter had a correlation R2 value of 0.92 for the height bin of 20 cm which provided the best results. Moreover, the influence of the number of points used for DBH estimation, considering different height bins, was investigated. The assessment of the other inventory parameters yield correlation coefficients higher than 0.91. The quality of the results confirms the feasibility of the proposed methodology, providing scalability to a comprehensive analysis of urban trees.

Automatic tree parameter extraction by a Mobile LiDAR System in an urban context

PubMed Central

Lindenbergh, Roderik; Rodríguez-Gonzálvez, Pablo

2018-01-01

In an urban context, tree data are used in city planning, in locating hazardous trees and in environmental monitoring. This study focuses on developing an innovative methodology to automatically estimate the most relevant individual structural parameters of urban trees sampled by a Mobile LiDAR System at city level. These parameters include the Diameter at Breast Height (DBH), which was estimated by circle fitting of the points belonging to different height bins using RANSAC. In the case of non-circular trees, DBH is calculated by the maximum distance between extreme points. Tree sizes were extracted through a connectivity analysis. Crown Base Height, defined as the length until the bottom of the live crown, was calculated by voxelization techniques. For estimating Canopy Volume, procedures of mesh generation and α-shape methods were implemented. Also, tree location coordinates were obtained by means of Principal Component Analysis. The workflow has been validated on 29 trees of different species sampling a stretch of road 750 m long in Delft (The Netherlands) and tested on a larger dataset containing 58 individual trees. The validation was done against field measurements. DBH parameter had a correlation R2 value of 0.92 for the height bin of 20 cm which provided the best results. Moreover, the influence of the number of points used for DBH estimation, considering different height bins, was investigated. The assessment of the other inventory parameters yield correlation coefficients higher than 0.91. The quality of the results confirms the feasibility of the proposed methodology, providing scalability to a comprehensive analysis of urban trees. PMID:29689076

NREL Biomethane GIS Data

DOE Data Explorer

Milbrandt, Anelia

2016-06-15

This dataset contains information about the biomass resources generated by county in the United States. It includes the following feedstock categories: crop residues, forest residues, primary mill residues, secondary mill residues, and urban wood waste. The estimates are based on county-level statistics and/or point-source data gathered from the U.S. Department of Agriculture (USDA), USDA Forest Service, EPA and other organizations, which are further processed using relevant assumptions and conversions.

Characterization of Organic Matter Sources within a Matrix of Land Use in Northeast Utah

NASA Astrophysics Data System (ADS)

Kelso, J. E.; Baker, M. A.

2017-12-01

Dynamics of organic matter (OM) sources in natural aquatic systems have been studied for decades, but urban studies have revealed additional, less studied, OM sources such as stormwater, lawn clippings, and wastewater effluent. Traditionally the OM pool in freshwater systems has been defined as a homogenous pool of varying size classes: course particulate, fine particulate and dissolved OM. Our goal was to identify and quantify the composition of fine particulate OM (FPOM), and dissolved OM (DOM) as derived from autochthonous, terrestrial, and potential anthropogenic sources. We hypothesized anthropogenic changes in land use have increased the proportion of autochthonous sources of OM. We sampled OM at 33 sites in four watersheds in northeast Utah that encompass a range of land uses. Stable isotopes of carbon, nitrogen, and deuterium were collected for all size classes of OM, and DOM was analyzed with a spectrofluorometer. Stable isotopes were used to estimate the proportion of autochthonous and terrestrial sources of OM. Fluorescence indices and a PARAFAC model were created from DOM excitation emission matrices (EEMs). FPOM appeared to be a mixture of autochthonous and terrestrial sources but overlap in endmember isotope values made quantifying the proportion of each source difficult. Higher deuterium values (-120 to -80‰) were associated with sites receiving wastewater effluent, while sites with agriculture, forest, and urban land use had lower deuterium isotope values (-200 to -110). DOM Excitation Emission Matrices were resolved into a 5-component PARAFAC model. The percent of protein-like DOM components tended to be higher in urban versus non-urban sites (mean 35%, S.D. 12% versus mean 25%, S.D. 15%). We concluded deuterium isotopes may be used as a tracer or wastewater effluent and DOM is composed of more labile, protein-like DOM with increased wastewater input. A greater understanding of the sources of OM can inform management and policy decisions aimed at mitigating the effects of OM pollution. For example, evaluating tradeoffs between mitigating the effects of OM inputs from cattle grazing versus building or improving waste water treatment facilities can be further explored.

Polychlorinated dibenzo-p-dioxins and dibenzofurans in the atmosphere around the Great Lakes.

PubMed

Venier, Marta; Ferrario, Joseph; Hites, Ronald A

2009-02-15

The atmospheric concentrations of PCDDs and PCDFs were measured in four sites near the shores of the North American Great Lakes. The sites included an urban site (Chicago, Illinois) and three rural/remote sites (Eagle Harbor, Michigan; Sleeping Bear Dunes, Michigan; and Sturgeon Point, New York). Sampling occurred every 24 days between November 2004 and December 2007. The concentration of PCDD/Fs averaged 2.3 +/- 0.2 fg WHO TEQ/m3 at Eagle Harbor, 35 +/- 3 fg WHO TEO/ m3 at Chicago, 7.4 +/- 1.4 fg WHO TEO/m3 at Sleeping Bear Dunes, and 13 +/- 2 fg WHO TED/m3 at Sturgeon Point. The total concentration of the 17 toxic PCDD/F congeners showed a significant seasonal trend at all sites, except Chicago. The date of maximum concentration averaged Dec 6 +/- 35 days, which is consistent with residential heating being an important source of PCDD/Fs to the atmosphere. A significant positive relationship between the logarithm of the total concentration of the 17 toxic PCDD/F congeners and the logarithm of the number of people within a 25 km radius around the sampling site was found. We suggest that urban and industrial areas, which are heavily populated, act as sources of PCDDs and PCDFs to the atmosphere.

Monuments in the Structure of an Urban Environment: The Source of Social Memory and the Marker of the Urban Space

NASA Astrophysics Data System (ADS)

Antonova, N.; Grunt, E.; Merenkov, A.

2017-10-01

The major research objective was to analyze the role of monuments in the formation of local residents’ and guests’ representations about the city, its history and traditions. The authors consider the system of monuments’ location in the urban space as a way of its social construction, as the system of influence on citizens’ aesthetic feelings, as the formation of their attitudes towards maintaining of continuity in the activities of different generations for the improvement of the territory of their permanent residence. Methodology. An urban monument is considered in two ways: as a transfer of historical memory and as a social memory transfer, which includes the experience of previous generations. One of the main provisions of the study is the idea that monuments can lose their former social value, transforming into “simple” objects of a public place. The study was conducted in the city of Yekaterinburg, one of the largest, cultural, scientific and industrial Russian megalopolises in 2015. The primary data was collected using standardized interviews. Four hundred and twenty respondents at the age of and above 18 were questioned on the basis of quota sampling. Interviews with respondents were conducted in order to identify key problems involved and reasons for shaping respondents’ representations of monuments in the urban environment typical for the population of Russian megalopolises. The standardized interview guide included 15 questions. Findings and discussion. Our investigation has revealed that different monuments fulfil various functions in an urban environment (ideological, aesthetic, transferring, valuable, etc.). The study has unequivocally confirmed that objects in the urban space have a different emotional colour background: people paint them in accordance with the feelings that arise in their perception. Hence, some monuments effectively fulfil the functions of social memory transfer: they are remembered, they tell us about the events to which they point. Other monuments in the physical space remain in citizens’ consciousness only as a point on the map of the city. It has been found that “old” and “new” monuments as semantic points of the urban space have an ambiguous perception and a significance for the citizen: some monuments are inscribed in mental maps, while others are ignored or their appearance is condemned.

Analyzing Variability in Landscape Nutrient Loading Using Spatially-Explicit Maps in the Great Lakes Basin

NASA Astrophysics Data System (ADS)

Hamlin, Q. F.; Kendall, A. D.; Martin, S. L.; Whitenack, H. D.; Roush, J. A.; Hannah, B. A.; Hyndman, D. W.

2017-12-01

Excessive loading of nitrogen and phosphorous to the landscape has caused biologically and economically damaging eutrophication and harmful algal blooms in the Great Lakes Basin (GLB) and across the world. We mapped source-specific loads of nitrogen and phosphorous to the landscape using broadly available data across the GLB. SENSMap (Spatially Explicit Nutrient Source Map) is a 30m resolution snapshot of nutrient loads ca. 2010. We use these maps to study variable nutrient loading and provide this information to watershed managers through NOAA's GLB Tipping Points Planner. SENSMap individually maps nutrient point sources and six non-point sources: 1) atmospheric deposition, 2) septic tanks, 3) non-agricultural chemical fertilizer, 4) agricultural chemical fertilizer, 5) manure, and 6) nitrogen fixation from legumes. To model source-specific loads at high resolution, SENSMap synthesizes a wide range of remotely sensed, surveyed, and tabular data. Using these spatially explicit nutrient loading maps, we can better calibrate local land use-based water quality models and provide insight to watershed managers on how to focus nutrient reduction strategies. Here we examine differences in dominant nutrient sources across the GLB, and how those sources vary by land use. SENSMap's high resolution, source-specific approach offers a different lens to understand nutrient loading than traditional semi-distributed or land use based models.

A Monte-Carlo Bayesian framework for urban rainfall error modelling

NASA Astrophysics Data System (ADS)

Ochoa Rodriguez, Susana; Wang, Li-Pen; Willems, Patrick; Onof, Christian

2016-04-01

Rainfall estimates of the highest possible accuracy and resolution are required for urban hydrological applications, given the small size and fast response which characterise urban catchments. While significant progress has been made in recent years towards meeting rainfall input requirements for urban hydrology -including increasing use of high spatial resolution radar rainfall estimates in combination with point rain gauge records- rainfall estimates will never be perfect and the true rainfall field is, by definition, unknown [1]. Quantifying the residual errors in rainfall estimates is crucial in order to understand their reliability, as well as the impact that their uncertainty may have in subsequent runoff estimates. The quantification of errors in rainfall estimates has been an active topic of research for decades. However, existing rainfall error models have several shortcomings, including the fact that they are limited to describing errors associated to a single data source (i.e. errors associated to rain gauge measurements or radar QPEs alone) and to a single representative error source (e.g. radar-rain gauge differences, spatial temporal resolution). Moreover, rainfall error models have been mostly developed for and tested at large scales. Studies at urban scales are mostly limited to analyses of propagation of errors in rain gauge records-only through urban drainage models and to tests of model sensitivity to uncertainty arising from unmeasured rainfall variability. Only few radar rainfall error models -originally developed for large scales- have been tested at urban scales [2] and have been shown to fail to well capture small-scale storm dynamics, including storm peaks, which are of utmost important for urban runoff simulations. In this work a Monte-Carlo Bayesian framework for rainfall error modelling at urban scales is introduced, which explicitly accounts for relevant errors (arising from insufficient accuracy and/or resolution) in multiple data sources (in this case radar and rain gauge estimates typically available at present), while at the same time enabling dynamic combination of these data sources (thus not only quantifying uncertainty, but also reducing it). This model generates an ensemble of merged rainfall estimates, which can then be used as input to urban drainage models in order to examine how uncertainties in rainfall estimates propagate to urban runoff estimates. The proposed model is tested using as case study a detailed rainfall and flow dataset, and a carefully verified urban drainage model of a small (~9 km2) pilot catchment in North-East London. The model has shown to well characterise residual errors in rainfall data at urban scales (which remain after the merging), leading to improved runoff estimates. In fact, the majority of measured flow peaks are bounded within the uncertainty area produced by the runoff ensembles generated with the ensemble rainfall inputs. REFERENCES: [1] Ciach, G. J. & Krajewski, W. F. (1999). On the estimation of radar rainfall error variance. Advances in Water Resources, 22 (6), 585-595. [2] Rico-Ramirez, M. A., Liguori, S. & Schellart, A. N. A. (2015). Quantifying radar-rainfall uncertainties in urban drainage flow modelling. Journal of Hydrology, 528, 17-28.

Ambient concentrations and personal exposure to polycyclic aromatic hydrocarbons (PAH) in an urban community with mixed sources of air pollution.

PubMed

Zhu, Xianlei; Fan, Zhihua Tina; Wu, Xiangmei; Jung, Kyung Hwa; Ohman-Strickland, Pamela; Bonanno, Linda J; Lioy, Paul J

2011-01-01

Assessment of the health risks resulting from exposure to ambient polycyclic aromatic hydrocarbons (PAH) is limited by a lack of environmental exposure data among the general population. This study characterized personal exposure and ambient concentrations of PAH in the Village of Waterfront South (WFS), an urban community with many mixed sources of air toxics in Camden, New Jersey, and CopeWood/Davis Streets (CDS), an urban reference area located ∼1 mile east of WFS. A total of 54 and 53 participants were recruited from non-smoking households in WFS and CDS, respectively. In all, 24-h personal and ambient air samples were collected simultaneously in both areas on weekdays and weekends during summer and winter. The ambient PAH concentrations in WFS were either significantly higher than or comparable to those in CDS, indicating the significant impact of local sources on PAH pollution in WFS. Analysis of diagnostic ratios and correlation suggested that diesel truck traffic, municipal waste combustion and industrial combustion were the major sources in WFS. In such an area, ambient air pollution contributed significantly to personal PAH exposure, explaining 44-96% of variability in personal concentrations. This study provides valuable data for examining the impact of local ambient PAH pollution on personal exposure and therefore potential health risks associated with environmental PAH pollution.

Ambient concentrations and personal exposure to polycyclic aromatic hydrocarbons (PAH) in an urban community with mixed sources of air pollution

PubMed Central

ZHU, XIANLEI; FAN, ZHIHUA (TINA); WU, XIANGMEI; JUNG, KYUNG HWA; OHMAN-STRICKLAND, PAMELA; BONANNO, LINDA J.; LIOY, PAUL J.

2014-01-01

Assessment of the health risks resulting from exposure to ambient polycyclic aromatic hydrocarbons (PAH) is limited by a lack of environmental exposure data among the general population. This study characterized personal exposure and ambient concentrations of PAH in the Village of Waterfront South (WFS), an urban community with many mixed sources of air toxics in Camden, New Jersey, and CopeWood/Davis Streets (CDS), an urban reference area located ~1 mile east of WFS. A total of 54 and 53 participants were recruited from non-smoking households in WFS and CDS, respectively. In all, 24-h personal and ambient air samples were collected simultaneously in both areas on weekdays and weekends during summer and winter. The ambient PAH concentrations in WFS were either significantly higher than or comparable to those in CDS, indicating the significant impact of local sources on PAH pollution in WFS. Analysis of diagnostic ratios and correlation suggested that diesel truck traffic, municipal waste combustion and industrial combustion were the major sources in WFS. In such an area, ambient air pollution contributed significantly to personal PAH exposure, explaining 44–96% of variability in personal concentrations. This study provides valuable data for examining the impact of local ambient PAH pollution on personal exposure and therefore potential health risks associated with environmental PAH pollution. PMID:21364704

On the assessment of spatial resolution of PET systems with iterative image reconstruction

NASA Astrophysics Data System (ADS)

Gong, Kuang; Cherry, Simon R.; Qi, Jinyi

2016-03-01

Spatial resolution is an important metric for performance characterization in PET systems. Measuring spatial resolution is straightforward with a linear reconstruction algorithm, such as filtered backprojection, and can be performed by reconstructing a point source scan and calculating the full-width-at-half-maximum (FWHM) along the principal directions. With the widespread adoption of iterative reconstruction methods, it is desirable to quantify the spatial resolution using an iterative reconstruction algorithm. However, the task can be difficult because the reconstruction algorithms are nonlinear and the non-negativity constraint can artificially enhance the apparent spatial resolution if a point source image is reconstructed without any background. Thus, it was recommended that a background should be added to the point source data before reconstruction for resolution measurement. However, there has been no detailed study on the effect of the point source contrast on the measured spatial resolution. Here we use point source scans from a preclinical PET scanner to investigate the relationship between measured spatial resolution and the point source contrast. We also evaluate whether the reconstruction of an isolated point source is predictive of the ability of the system to resolve two adjacent point sources. Our results indicate that when the point source contrast is below a certain threshold, the measured FWHM remains stable. Once the contrast is above the threshold, the measured FWHM monotonically decreases with increasing point source contrast. In addition, the measured FWHM also monotonically decreases with iteration number for maximum likelihood estimate. Therefore, when measuring system resolution with an iterative reconstruction algorithm, we recommend using a low-contrast point source and a fixed number of iterations.

Quantitative Risk Mapping of Urban Gas Pipeline Networks Using GIS

NASA Astrophysics Data System (ADS)

Azari, P.; Karimi, M.

2017-09-01

Natural gas is considered an important source of energy in the world. By increasing growth of urbanization, urban gas pipelines which transmit natural gas from transmission pipelines to consumers, will become a dense network. The increase in the density of urban pipelines will influence probability of occurring bad accidents in urban areas. These accidents have a catastrophic effect on people and their property. Within the next few years, risk mapping will become an important component in urban planning and management of large cities in order to decrease the probability of accident and to control them. Therefore, it is important to assess risk values and determine their location on urban map using an appropriate method. In the history of risk analysis of urban natural gas pipeline networks, the pipelines has always been considered one by one and their density in urban area has not been considered. The aim of this study is to determine the effect of several pipelines on the risk value of a specific grid point. This paper outlines a quantitative risk assessment method for analysing the risk of urban natural gas pipeline networks. It consists of two main parts: failure rate calculation where the EGIG historical data are used and fatal length calculation that involves calculation of gas release and fatality rate of consequences. We consider jet fire, fireball and explosion for investigating the consequences of gas pipeline failure. The outcome of this method is an individual risk and is shown as a risk map.

Occurrence of surfactants in wastewater: hourly and seasonal variations in urban and industrial wastewaters from Seville (Southern Spain).

PubMed

Camacho-Muñoz, Dolores; Martín, Julia; Santos, Juan Luís; Aparicio, Irene; Alonso, Esteban

2014-01-15

Surfactants are daily discharged to the environment from urban and industrial activities. The assessment of the risk derived from the presence of these compounds in the environment requires a deep knowledge about their sources and their distribution in wastewater treatment plants (WWTPs). However, in spite of several studies reporting their presence in WWTPs, only a small number is focused on their different sources. In this work, the distribution of anionic (linear alkylbenzene sulfonates) and non-ionic (nonylphenol ethoxylates) surfactants in WWTPs and in urban and industrial wastewater collection systems has been investigated. Seasonal and daily variability was also assessed. Concentrations of linear alkylbenzene sulfonates in influent and effluent wastewaters ranged from 1155 to 9200 μg L(-1), and from below limit of detection to 770 μg L(-1), respectively, whereas the concentrations of nonylphenol ethoxylates were significantly lower. Linear alkylbenzene sulfonates were efficiently removed (>96%), while mean removal rates of nonylphenol ethoxylates were significantly lower (<20%). Studies carried out in different seasons revealed seasonal discharge patterns from both urban and industrial activities. The analysis of wastewater collection systems showed a major contribution of linear alkylbenzene sulfonates from urban areas while, in the case of nonylphenol ethoxylates, their major contribution came from industrial activities. In all cases the discharge patterns of surfactants were related with the water consumption. © 2013.

Evaluating Urban Methane Emissions with a Light Rail Vehicle Platform in Salt Lake City, UT

NASA Astrophysics Data System (ADS)

Mitchell, L.; Fasoli, B.; Crosman, E.; Lin, J. C.; Bowling, D. R.; Ehleringer, J. R.

2016-12-01

Urban environments are characterized by both spatial complexity and temporal variability, each of which present challenges for measurement strategies aimed at constraining estimates of greenhouse gas emissions and air quality. To address these challenges we initiated a project in December 2014 to measure trace species (CO2, CH4, O3, and Particulate Matter) by way of a Utah Transit Authority (UTA) electricity-powered light rail vehicle whose route traverses the metropolitan Salt Lake Valley in Utah, USA on an hourly basis, retracing the same route through commercial, residential, suburban, and rural typologies. Light rail vehicles present advantages as a measurement platform, including the absence of in-situ fossil fuel emissions, regular repeated transects across an urban region that provide both spatial and temporal information, and relatively low operating costs. We will present initial results investigating methane point sources and evaluating the magnitude and temporal characteristics of these emissions.

Characterizing the distribution of particles in urban stormwater: advancements through improved sampling technology

USGS Publications Warehouse

Selbig, William R.

2014-01-01

A new sample collection system was developed to improve the representation of sediment in stormwater by integrating the entire water column. The depth-integrated sampler arm (DISA) was able to mitigate sediment stratification bias in storm water, thereby improving the characterization of particle size distribution from urban source areas. Collector streets had the lowest median particle diameter of 8 μm, followed by parking lots, arterial streets, feeder streets, and residential and mixed land use (32, 43, 50, 80 and 95 μm, respectively). Results from this study suggest there is no single distribution of particles that can be applied uniformly to runoff in urban environments; however, integrating more of the entire water column during the sample collection can address some of the shortcomings of a fixed-point sampler by reducing variability and bias caused by the stratification of solids in a water column.

Vertical and horizontal variability of PM10 source contributions in Barcelona during SAPUSS

NASA Astrophysics Data System (ADS)

Brines, Mariola; Dall'Osto, Manuel; Amato, Fulvio; Cruz Minguillón, María; Karanasiou, Angeliki; Alastuey, Andrés; Querol, Xavier

2016-06-01

During the SAPUSS campaign (Solving Aerosol Problems by Using Synergistic Strategies) PM10 samples at 12-hour resolution were simultaneously collected at four monitoring sites located in the urban agglomerate of Barcelona (Spain). A total of 221 samples were collected from 20 September to 20 October 2010. The Road Site (RS) site and the Urban Background (UB) site were located at street level, whereas the Torre Mapfre (TM) and the Torre Collserola (TC) sites were located at 150 m a.s.l. by the sea side within the urban area and at 415 m a.s.l. 8 km inland, respectively. For the first time, we are able to report simultaneous PM10 aerosol measurements, allowing us to study aerosol gradients at both horizontal and vertical levels. The complete chemical composition of PM10 was determined on the 221 samples, and factor analysis (positive matrix factorisation, PMF) was applied. This resulted in eight factors which were attributed to eight main aerosol sources affecting PM10 concentrations in the studied urban environment: (1) vehicle exhaust and wear (2-9 µg m-3, 10-27 % of PM10 mass on average), (2) road dust (2-4 µg m-3, 8-12 %), (3) mineral dust (5 µg m-3, 13-26 %), (4) aged marine (3-5 µg m-3, 13-20 %), (5) heavy oil (0.4-0.6 µg m-3, 2 %), (6) industrial (1 µg m-3, 3-5 %), (7) sulfate (3-4 µg m-3, 11-17 %) and (8) nitrate (4-6 µg m-3, 17-21 %). Three aerosol sources were found to be enhanced at the ground levels (confined within the urban ground levels of the city) relative to the upper levels: (1) vehicle exhaust and wear (2.8 higher), (2) road dust (1.8 higher) and (3) local urban industries/crafts workshops (1.6 higher). Surprisingly, the other aerosol sources were relatively homogeneous at both horizontal and vertical levels. However, air mass origin and meteorological parameters also played a key role in influencing the variability of the factor concentrations. The mineral dust and aged marine factors were found to be a mixture of natural and anthropogenic components and were thus further investigated. Overall, three types of dust were identified to affect the urban study area: road dust (35 % of the mineral dust load, 2-4 µg m-3 on average), Saharan dust (28 %, 2.1 µg m-3) and background mineral dust (37 %, 2.8 µg m-3). Our results evidence that although the city of Barcelona broadly shows a homogeneous distribution of PM10 pollution sources, non-exhaust traffic, exhaust traffic and local urban industrial activities are major coarse PM10 aerosol sources.

Vertical and horizontal variability of PM10 source contributions in Barcelona during SAPUSS

NASA Astrophysics Data System (ADS)

Brines, M.; Dall'Osto, M.; Amato, F.; Minguillón, M. C.; Karanasiou, A.; Alastuey, A.; Querol, X.

2015-11-01

During the SAPUSS campaign (Solving Aerosol Problems by Using Synergistic Strategies) PM10 samples at twelve hours resolution were simultaneously collected at four monitoring sites located in the urban agglomerate of Barcelona (Spain). A total of 221 samples were collected from 20 September to 20 October 2010. The Road Site (RS) site and the Urban Background (UB) site were located at street level, whereas the Torre Mapfre (TM) and the Torre Collserola (TC) sites were located at 150 m a.s.l. by the sea side within the urban area and at 415 m a.s.l. 8 km inland, respectively. For the first time, we are able to report simultaneous PM10 aerosol measurements allowing us to study aerosol gradients at both horizontal and vertical levels. The complete chemical composition of PM10 was determined on the 221 samples, and factor analysis (Positive Matrix Factorisation, PMF) was applied. This resulted in eight factors which were attributed to eight main aerosol sources affecting PM10 concentrations in the studied urban environment: (1) vehicle exhaust and wear (2-9 μg m-3, 10-27 % of PM10 mass on average), (2) road dust (2-4 μg m-3, 8-12 %), (3) mineral dust (5 μg m-3, 13-26 %), (4) aged marine (3-5 μg m-3, 13-20 %), (5) heavy oil (0.4-0.6 μg m-3, 2 %), (6) industrial (1 μg m-3, 3-5 %), (7) sulphate (3-4 μg m-3, 11-17 %) and (8) nitrate (4-6 μg m-3, 17-21 %). Three aerosol sources were found enhanced at the ground levels (confined within the urban ground levels of the city) relative to the upper levels: (1) vehicle exhaust and wear (2.8 higher), (2) road dust (1.8 higher) and (3) local urban industries/crafts workshops (1.6 higher). Surprisingly, the other aerosol sources were relatively homogeneous at both horizontal and vertical levels. However, air mass origin and meteorological parameters also played a key role in influencing the variability of the factors concentrations. The mineral dust and aged marine factors were found to be a mixture of natural and anthropogenic components and were thus further investigated. Overall, three types of dust were identified to affect the urban study area: road dust (35 % of the mineral dust load, 2-4 μg m-3 on average), Saharan dust (28 %, 2.1 μg m-3) and background mineral dust (37 %, 2.8 μg m-3). Our results evidence that although the city of Barcelona broadly shows a homogeneous distribution of PM10 pollution sources, non-exhaust traffic, exhaust traffic and local urban industrial activities are major coarse PM10 aerosol sources.

[Treatment of Urban Runoff Pollutants by a Multilayer Biofiltration System].

PubMed

Wang, Xiao-lu; Zuo, Jian-e; Gan, Li-li; Xing, Wei; Miao, Heng-feng; Ruan, Wen-quan

2015-07-01

In order to control the non-point source pollution from road runoff in Wuxi City effectively, a multilayer biofiltration system was designed to remove a variety of pollutants according to the characteristics of road runoff in Wuxi, and the experimental research was carried out to study the effect on rainwater pollution purification. The results show that the system has a good performance on removing suspended solids (SS), organic pollutant (COD), nitrogen and phosphorus: all types of multilayer biofiltration systems have a high removal rate for SS, which can reach 90%. The system with activated carbon (GAC) has higher removal rates for COD and phosphorus. The system with zeolite (ZFM) has a relatively better removal efficiency for nitrogen. The addition of wood chips in the system can significantly improve the system efficiency for nitrogen removal. Between the two configurations of layered and distributed wood chips, configurations of distributed wood chips reach higher COD, phosphorus and nitrogen pollutants removal efficiencies since they can reduce the release of wood chips dissolution.

Urban Heat Islands and Their Mitigation vs. Local Impacts of Climate Change

NASA Astrophysics Data System (ADS)

Taha, H.

2007-12-01

Urban heat islands and their mitigation take on added significance, both negative and positive, when viewed from a climate-change perspective. In negative terms, urban heat islands can act as local exacerbating factors, or magnifying lenses, to the effects of regional and large-scale climate perturbations and change. They can locally impact meteorology, energy/electricity generation and use, thermal environment (comfort and heat waves), emissions of air pollutants, photochemistry, and air quality. In positive terms, on the other hand, mitigation of urban heat islands (via urban surface modifications and control of man-made heat, for example) can potentially have a beneficial effect of mitigating the local negative impacts of climate change. In addition, mitigation of urban heat islands can, in itself, contribute to preventing regional and global climate change, even if modestly, by helping reduce CO2 emissions from power plants and other sources as a result of decreased energy use for cooling (both direct and indirect) and reducing the rates of meteorology-dependent emissions of air pollutants. This presentation will highlight aspects and characteristics of heat islands, their mitigation, their modeling and quantification techniques, and recent advances in meso-urban modeling of California (funded by the California Energy Commission). In particular, the presentation will focus on results from quantitative, modeling-based analyses of the potential benefits of heat island mitigation in 1) reducing point- and area-source emissions of CO2, NOx, and VOC as a result of reduced cooling energy demand and ambient/surface temperatures, 2) reducing evaporative and fugitive hydrocarbon emissions as a result of lowered temperatures, 3) reducing biogenic hydrocarbon emissions from existing vegetative cover, 4) slowing the rates of tropospheric/ground-level ozone formation and/or accumulation in the urban boundary layer, and 5) helping improve air quality. Quantitative estimates of the above will be presented based on recent and earlier meteorological, energy, thermal environmental, emissions, and photochemical modeling studies for California and Texas.