A Novel Treatment for Acid Mine Drainage Utilizing Reclaimed Limestone Residual
DOE Office of Scientific and Technical Information (OSTI.GOV)
Horace K. Moo-Young; Charles E. Ochola
2004-08-31
The viability of utilizing Reclaimed Limestone Residual (RLR) to remediate Acid Mine Drainage (AMD) was investigated. Physical and chemical characterization of RLR showed that it is composed of various minerals that contain significant quantities of limestone or calcium bearing compounds that can be exploited for acid neutralization. Acid Neutralization Potential (ANP) test results showed that RLR has a neutralization potential of approximately 83% as calcium carbonate (CaCO{sub 3}). Neutralization tests with most of the heavy metals associated with AMD showed removal efficiencies of over 99%. An unexpected benefit of utilizing RLR was the removal of hexavalent chromium Cr (VI) frommore » the aqueous phase. Due to an elevation in pH by RLR most AMD heavy metals are removed from solution by precipitation as their metal hydroxides. Cr (VI) however is not removed by pH elevation and therefore subsequent ongoing tests to elucidate the mechanism responsible for this reaction were conducted.« less
Reclaimed fly ash as select fill under PCC pavement.
DOT National Transportation Integrated Search
1999-11-01
With the support of the Iowa Fly Ash Affiliates, research on reclaimed fly ash for use as a : construction material has been ongoing since 1991. The material exhibits engineering : properties similar to those of soft limestone or sandstone and a ligh...
NASA Astrophysics Data System (ADS)
Maharaj, S.; Barton, C. D.; Karathanasis, A. D.
2005-12-01
Projected climate change resulting from elevated atmospheric carbon dioxide has given rise to various strategies designed to sequester carbon in various terrestrial ecosystems. Reclaimed coal mine soils present one such potential carbon sink where traditional reclamation objectives can complement carbon sequestration. However, quantifying new carbon (carbon that has been added to soil through recent biological processes) on reclaimed mine soils have proven to be difficult due to carbonates and coal particles present in the reclaimed coal mine spoils. Visible coal particles can be removed, but the microscopic coal dust particles remain. Additionally, with the advent of carbon trading on the stock market, rapid quantification of newly sequestered carbon has proven to be elusive. The focus of this project is to assess the potential of thermogravimetric analysis as a rapid, simple and direct method for differentiating and quantifying new carbon from old carbon (carbon of geologic origin) on reclaimed coal mine sites and provide a standard procedure for determining carbon sequestered in soil sinks. Thermogravimetry is a physico-chemical technique where the weight change is measured and recorded during the incremental heating of the soil sample over a temperature range of 25 to 1000 ° C. Grass litter and limestone were used as representative organic and inorganic carbon fractions, while coal was used to differentiate the old and new carbon within the organic fraction. Recoveries of mixtures at the 95 % confidence interval were found to be 94.49 ± 4.23 % (coal) , 93.67 ± 2.11 % (litter) , and 108.88 ± 2.88 % (limestone) respectively. Each of the above components appeared as distinct separate peaks on the thermograph, with litter appearing between 260 to 390 ° C, coal 425 to 480 ° C, and limestone 640 to 740 ° C. Overlapping peaks for the organic carbon represented by the grass litter may be indicative of cellulose and lignin fractions. Ongoing work in this area is being carried out to separate such peaks which may further enhance thermogravimetric analysis as an effective method to determine new carbon and to simultaneously monitor organic matter degradation.
[Assessment of ecological environment benefits of reclaimed water reuse in Beijing].
Fan, Yu-Peng; Chen, Wei-Ping
2014-10-01
With the rapid development of the social economy and the sustained growth of population, China is facing increasingly serious water problems, and reclaimed water utilization has become an effective measure to solve water shortage problem and to control further deterioration of the ecological environment. Reclaimed water utilization can not only save a lot of fresh water, but also reduce the environmental impact of wastewater discharge, and thus has great ecological environmental benefits, including resource, environmental and human health benefits and so on. This study used the opportunity cost method to construct an evaluation system for ecological environmental benefits of reclaimed water utilization, and Beijing was taken as an example to conduct an estimation of ecological environmental benefits of reclaimed water utilization. Research results indicated that the reclaimed water utilization in Beijing had considerable environmental benefits for ¥ 1.2 billion in 2010, in which replacement of fresh water accounted for the largest share. The benefits of environmental improvement and groundwater recharge were large, while the other benefits were small or negative. The ecological environment benefits of reclaimed water utilization in Beijing was about 1.8 times that of its direct economic benefits, showing that reclaimed water utilization was in accordance with sustainable development. Related methods and results will provide scientific basis to promote the development of reclaimed water utilization in our country.
Narendrula-Kotha, Ramya; Nkongolo, Kabwe K.
2017-01-01
Aims To assess the effects of dolomitic limestone applications on soil microbial communities’ dynamics and bacterial and fungal biomass, relative abundance, and diversity in metal reclaimed regions. Methods and Results The study was conducted in reclaimed mining sites and metal uncontaminated areas. The limestone applications were performed over 35 years ago. Total microbial biomass was determined by Phospholipid fatty acids. Bacterial and fungal relative abundance and diversity were assessed using 454 pyrosequencing. There was a significant increase of total microbial biomass in limed sites (342 ng/g) compared to unlimed areas (149 ng/g). Chao1 estimates followed the same trend. But the total number of OTUs (Operational Taxonomic Units) in limed (463 OTUs) and unlimed (473 OTUs) soil samples for bacteria were similar. For fungi, OTUs were 96 and 81 for limed and unlimed soil samples, respectively. Likewise, Simpson and Shannon diversity indices revealed no significant differences between limed and unlimed sites. Bacterial and fungal groups specific to either limed or unlimed sites were identified. Five major bacterial phyla including Actinobacteria, Acidobacteria, Chloroflexi, Firmicutes, and Proteobacteria were found. The latter was the most prevalent phylum in all the samples with a relative abundance of 50%. Bradyrhizobiaceae family with 12 genera including the nitrogen fixing Bradirhizobium genus was more abundant in limed sites compared to unlimed areas. For fungi, Ascomycota was the most predominant phylum in unlimed soils (46%) while Basidiomycota phylum represented 86% of all fungi in the limed areas. Conclusion Detailed analysis of the data revealed that although soil liming increases significantly the amount of microbial biomass, the level of species diversity remain statistically unchanged even though the microbial compositions of the damaged and restored sites are different. Significance and Impact of the study Soil liming still have a significant beneficial effects on soil microbial abundance and composition > 35 years after dolomitic limestone applications. PMID:28052072
An overview of reclaimed water reuse in China.
Yi, Lili; Jiao, Wentao; Chen, Xiaoning; Chen, Weiping
2011-01-01
China is facing severe water problems including scarcity and pollution which are now becoming key factors restricting developments. Creating an alternative water resource and reducing effluent discharges, water reuse has been recognized as an integral part of water and wastewater management scheme in China. The government has launched nationwide efforts to optimize the benefits of utilizing reclaimed water. This article reviewed the water reuse activities in China, including: (1) application history and current status; (2) potentials of reclaimed water reuse; (3) laws, policies and regulations governing reclaimed water reuse; (4) risks associated with reclaimed water reuse; (5) issues in reclaimed water reuse. Reclaimed water in Beijing and Tianjin were given as examples. Suggestions for improving the efficiencies of reusing urban wastewater were advanced. Being the largest user of reclaimed wastewater in the world, China's experience can benefit the development of water reuse in other regions.
[Ecological risks of reclaimed water irrigation: a review].
Chen, Wei-Ping; Zhang, Wei-Ling; Pan, Neng; Jiao, Wen-Tao
2012-12-01
Wastewater reclamation and reuse have become an important approach to alleviate the water crisis in China because of its social, economic and ecological benefits. The irrigation on urban green space and farmland is the primary utilization of reclaimed water, which has been practiced world widely. To understand the risk of reclaimed water irrigation, we summarized and reviewed the publications associated with typical pollutants in reclaimed water including salts, nitrogen, heavy metals, emerging pollutants and pathogens, systematically analyzed the ecological risk posed by reclaimed water irrigation regarding plant growth, groundwater quality and public health. Studies showed that salt and salt ions were the major risk sources of reclaimed water irrigation, spreading disease was another potential risk of using reclaimed water, and emerging pollutants was the hot topic in researches of ecological risk. Based on overseas experiences, risk control measures on reclaimed water irrigation in urban green space and farmland were proposed. Five recommendations were given to promote the safe use of reclaimed water irrigation including (1) strengthen long-term in situ monitoring, (2) promote the modeling studies, (3) build up the connections of reclaimed water quality, irrigation management and ecological risk, (4) evaluate the soil bearing capacity of reclaimed water irrigation, (5) and establish risk management system of reclaimed water reuse.
Potential benefits of adding emulsion to reclaimed base material : interim report, second year.
DOT National Transportation Integrated Search
1999-09-01
Rehabilitation of deteriorated asphalt pavements has become one of the primary tools utilized by : the Construction Division of the Maine Department of Transportation (MDOT). One method : used to achieve this task is the use of pavement reclaiming. :...
Wang, Jun; Wang, Dong; Hou, Deyin
2016-01-01
A combined process was developed to inhibit the corrosion both in the pipeline of reclaimed water supplies (PRWS) and in downstream recirculating cooling water systems (RCWS) using the reclaimed water as makeup. Hydroxyl carboxylate-based corrosion inhibitors (e.g., gluconate, citrate, tartrate) and zinc sulfate heptahydrate, which provided Zn(2+) as a synergistic corrosion inhibition additive, were added prior to the PRWS when the phosphate (which could be utilized as a corrosion inhibitor) content in the reclaimed water was below 1.7 mg/L, and no additional corrosion inhibitors were required for the downstream RCWS. Satisfactory corrosion inhibition was achieved even if the RCWS was operated under the condition of high numbers of concentration cycles. The corrosion inhibition requirement was also met by the appropriate combination of PO4(3-) and Zn(2+) when the phosphate content in the reclaimed water was more than 1.7 mg/L. The process integrated not only water reclamation and reuse, and the operation of a highly concentrated RCWS, but also the comprehensive utilization of phosphate in reclaimed water and the application of non-phosphorus corrosion inhibitors. The proposed process reduced the operating cost of the PRWS and the RCWS, and lowered the environmental hazard caused by the excessive discharge of phosphate. Furthermore, larger amounts of water resources could be conserved as a result. Copyright © 2015. Published by Elsevier B.V.
Potential benefits of adding emulsion to reclaimed base material : interim report, third year.
DOT National Transportation Integrated Search
2001-02-01
Rehabilitation of deteriorated asphalt pavements has become one of the primary tools : utilized by the Maine Department of Transportation (MDOT). One method used to achieve this : task is the use of pavement reclaiming. : In an effort to improve the ...
DOT National Transportation Integrated Search
2018-02-02
The Alabama Department of Transportation (ALDOT) and other highway agencies are interested in utilization of higher percentages of reclaimed asphalt pavement (RAP) in asphalt mixtures. There are a number of research studies at both state and national...
Development of a proton-exchange membrane electrochemical reclaimed water post-treatment system
NASA Technical Reports Server (NTRS)
Kaba, Lamine; Verostko, Charles E.; Hitchens, G. D.; Murphy, Oliver J.
1991-01-01
A single-cell electrochemical reactor that utilizes a proton exchange membrane (PEM) as a solid electrolyte is being investigated for posttreatment of reclaimed waste waters with low or negligible electrolyte content. Posttreatment is a final 'polishing' of reclaimed waste waters prior to reuse, and involves removing organic impurities at levels as high as 100 ppm to below 500 ppb total organic carbon (TOC) content to provide disinfection. The system does not utilize or produce either expendable hardware components or chemicals and has no moving parts. Test data and kinetic analysis are presented. The feasibility and application for water reclamation processes in controlled ecological environments (e.g., lunar/Mars habitats) are also presented. Test results show that the electrochemical single cell reactor provides effective posttreatment.
Potable and monitoring wells located in close proximity to a large groundwater recharge project which utilizes a blend of surface water and reclaimed wastewater for recharge were tested for coliphage over a period of 6 months to assess the potential for virus migration. During th...
Current use of carbonate rocks and lime for controlling emissions from coal-fired plants in Kentucky
DOE Office of Scientific and Technical Information (OSTI.GOV)
Dever, G.R. Jr.
1993-03-01
Seven coal-fired power plants in Kentucky currently are operating wet-scrubbing systems for flue-gas desulfurization. Atmospheric fluidized-bed combustion (AFBC) units are being used for SO[sub 2] emission control at a petroleum refinery, and a 160-MW utility-scale AFBC demonstration plant is being operated by the Tennessee Valley Authority. A lime-based spray-dryer reactor system has been installed on an industrial boiler, and a spray-dryer system is being tested at a utility pilot-plant facility. Four of the seven power plants operate limestone-based wet-scrubbing systems and require about 885,000 tons of stone per year. Stone is obtained from Mississippian limestones, principally the Ste. Genevieve Limestone,more » produced at four quarries in Kentucky, Indiana, and Illinois. Scrubber limestone specifications include CaCO[sub 3] content (minimum 88--90%), MgCO[sub 3] content (maximum 4--6%), and grindability (maximum Bond Work Index of 11--12). Three power plants operate lime-based scrubbers, requiring about 250,000 tons of lime per year. The scrubbers currently use (1) lime manufactured from an Ordovician dolomitic limestone, mined in north-central Kentucky, and (2) carbide lime, a chemical-industry byproduct. Fluidized-bed units at the petroleum refinery require about 100,000 tons of sorbent stone per year. The sorbent consists of about equal amounts of Silurian dolomite from Ohio and Ordovician dolomitic limestone from Kentucky. The utility-scale AFBC demonstration plant uses a limestone sorbent and currently requires about 200,000 tons of stone per year. Limestone is obtained from the Ste. Genevieve in western Kentucky.« less
Carbonaceous fuel combustion with improved desulfurization
Yang, Ralph T.; Shen, Ming-shing
1980-01-01
Lime utilization for sulfurous oxides adsorption in fluidized combustion of carbonaceous fuels is improved by impregnation of porous lime particulates with iron oxide. The impregnation is achieved by spraying an aqueous solution of mixed iron sulfate and sulfite on the limestone before transfer to the fluidized bed combustor, whereby the iron compounds react with the limestone substrate to form iron oxide at the limestone surface. The iron oxide present in the spent limestone is found to catalyze the regeneration rate of the spent limestone in a reducing environment. Thus both the calcium and iron components may be recycled.
[Assessment of farmland soil quality under different utilization intensity in arid area].
Gui, Dong-Wei; Mu, Gui-Jin; Lei, Jia-Qiang; Zeng, Fan-Jiang; Wang, Hui
2009-04-01
Based on the 2005-2007 experimental data in Cele oasis in the southern margin of Tarim Basin of Xinjiang, the soil quality of four typical types of farmland with different utilization intensity, i.e., farmland with high input, farmland with normal input, newly reclaimed farmland, and farmland in oasis' interior, was analyzed and assessed by using sustainable yield index, soil improvement index, and soil quality synthesis index. Among the farmlands, there were significant differences in the contents of soil organic matter, available nitrogen, and available phosphorus. Newly reclaimed farmland had the lowest level of soil quality, while the farmland in oasis' interior had relatively higher soil quality. This study could help the reasonable exploitation and utilization of farmlands in Cele oasis, and the protection of local farmland eco-environment.
Catalytic iron oxide for lime regeneration in carbonaceous fuel combustion
Shen, Ming-Shing; Yang, Ralph T.
1980-01-01
Lime utilization for sulfurous oxides absorption in fluidized combustion of carbonaceous fuels is improved by impregnation of porous lime particulates with iron oxide. The impregnation is achieved by spraying an aqueous solution of mixed iron sulfate and sulfite on the limestone before transfer to the fluidized bed combustor, whereby the iron compounds react with the limestone substrate to form iron oxide at the limestone surface. It is found that iron oxide present in the spent limestone acts as a catalyst to regenerate the spent limestone in a reducing environment. With only small quantities of iron oxide the calcium can be recycled at a significantly increased rate.
Langer, W.H.; Juan, C.A.S.; Rau, G.H.; Caldeira, K.
2009-01-01
Large amounts of limestone fines coproduced during the processing of crushed limestone may be useful in the sequestration of carbon dioxide (CO 2). Accelerated weathering of limestone (AWL) is proposed as a low-tech method to capture and sequester CO2 from fossil fuel-fired power plants and other point-sources such as cement manufacturing. AWL reactants are readily available, inexpensive, and environmentally benign. Waste CO 2 is hydrated with water to produce carbonic acid, which then reacts with and is neutralized by limestone fines, thus converting CO2 gas to dissolved calcium bicarbonate. AWL waste products can be disposed of in the ocean. Feasibility requires access to an inexpensive source of limestone and to seawater, thus limiting AWL facilities within about 10 km of the coastline. The majority of U.S. coastal power generating facilities are within economical transport distance of limestone resources. AWL presents opportunities for collaborative efforts among the crushed stone industry, electrical utilities, cement manufactures, and research scientists.
ECONOMICS OF DISPOSAL OF LIME/LIMESTONE SCRUBBING WASTES: UNTREATED AND CHEMICALLY TREATED WASTES
The report gives results of a detailed, comparative economic evaluation of four alternatives available to the utility industry for the disposal of wastes from flue gas desulfurization using limestone or lime slurry scrubbing. The alternatives are untreated sludge (pond or landfil...
Kaehler, Charles A.; Belitz, Kenneth
2003-01-01
As a component in the management of water resources in the Menifee, Winchester, and Perris-South subbasins in Riverside County, California, ponds are operated by the Eastern Municipal Water District for the temporary storage of reclaimed water that is produced by several regional water-reclamation facilities. A primary goal of this study was to evaluate the potential for using various ground-water constituents or characteristics as tracers of reclaimed water that has infiltrated from the storage ponds into the ground water in the three subbasins. A secondary goal was to estimate the degree to which the infiltrated reclaimed water has mixed with the native ground water. The evaluation of potential tracers and the estimation of mixing focused on data from wells located relatively close to the ponds. The most useful constituents and characteristics for evaluation of the fate and mixing of reclaimed water in the Menifee, Winchester, and Perris-South subbasins are major-ion composition, stable isotopes of hydrogen and oxygen, ultraviolet absorbance (UV-A), chloride concentration, and boron/chloride ratio plotted against chloride concentration. Emphasis in this study was placed on evaluating the utility of UV-A as a tracer and boron/chloride ratios in estimating the fraction of reclaimed water in ground water. In the Menifee subbasin, major-ion data, stable isotopes, chloride, UV-A, and boron/chloride ratio are all useful in identifying reclaimed water, and the results based on these indicators are consistent with each other. The results suggest that values of UV-A greater than or equal to 0.007 indicate the presence of reclaimed water in the Menifee subbasin. Ground-water samples with UV-A greater than 0.007 are estimated to consist of about 75 to 100 percent reclaimed water, on the basis of chloride-mixing calculations and boron/chloride-versus-chloride mixing calculations. In the Winchester subbasin, results based on the same factors used in the Menifee subbasin are less conclusive; nevertheless, UV-A can be used as a tracer. The results suggest that values of UV-A greater than 0.01 indicate the presence of reclaimed water. Values from 0.006 to 0.01 may indicate the presence of reclaimed water; however, water from wells not likely to have reclaimed water may also have UV-A values in this range. Ground-water samples with UV-A greater than 0.01 seem to contain about 25 percent reclaimed water (range 6 to 32 percent), on the basis of the consistency of the results of three types of mixing calculations--chloride alone, boron/chloride versus chloride, and UV-A. In the Perris-South subbasin, the potential tracers are not as conclusive in identifying reclaimed water in the subsurface as in the Menifee and Winchester subbasins. The less-conclusive results are a consequence of the multiple, spatially distributed sources of reclaimed water; the relative absence of wells close to the reclaimed-water pond; and the short period of operation (about 1 year) of the pond at the time of sampling. Mixing calculations suggest that ground-water samples with elevated UV-A values (greater than 0.01) in the Perris-South subbasin could contain as much as 40 to 65 percent reclaimed water.
Enhancement of the sulfur capture capacity of limestones by the addition of Na2CO3 and NaCl.
Laursen, K; Grace, J R; Lim, C J
2001-11-01
The ability of Na2CO3 and NaCl to enhance the sulfur capture capacity of three limestones was evaluated via fixed-bed calcination and sulfation experiments. The tested limestones represent three different sulfation morphologies: unreacted-core, network, and uniformly sulfated. Treatment with aqueous or powdered Na2CO3 significantly increased the Ca-utilization for two stones which normally sulfate in an unreacted-core pattern (20% to 45%) and network pattern (33% to 49%). The increase was lower for the uniformly sulfated stone (44% to 48%). Na2CO3 treatment increased the number of macropores leading to uniform sulfation of all particles, nearly eliminating the normal strong dependence of utilization on limestone type and particle size. The effect of Na2CO3 is believed to be associated with formation of a eutectic melt which enhances ionic diffusion and accelerates molecular rearrangement of the CaO. Treatment with aqueous NaCl solution caused a decrease in utilization, probably due to formation of large grains and plugging of pores caused by formation of a large amount of eutectic melt. The effect of Na2CO3 is less sensitive than that of NaCl to the amount added and the combustion environment (temperature and gas composition). In addition, Na2CO3 neither promotes corrosion nor forms chlorinated byproducts, which are main concerns associated with NaCl. Thus, Na2CO3 appears to have significant advantages over NaCl for enhancement of limestone sulfur capture capacity in fluidized-bed combustors.
NASA Astrophysics Data System (ADS)
Xiao, Yang; Li, Yunkai; Ning, Zigong; Li, Pengxiang; Yang, Peiling; Liu, Chengcheng; Liu, Zhongwei; Xu, Feipeng; Hynds, Paul Dylan
2018-03-01
Wastewater reclamation now represents an effective measure for sustainable water resource management in arid regions, however wastewater components (organic micropollutants) may potentially impact local ecological and/or human health. Previous studies have shown that sodium bentonite/natural clay (BC) mixes may be used to effectively reduce riverbed infiltration in regions characterized by excessively high hydraulic conductivity. Accordingly, the current study sought to investigate the contaminant removal efficiency (Re) of several BC mass ratios in simulated dry riverbeds. Results indicate that the measured Re of NH4+-N, CODcr and BOD5 increased in concurrence with an increasing sodium bentonite ratio, up to a maximum Re of 97.4% (NH4+-N), 55.2% (CODcr), and 51.5% (BOD5). The primary contaminant removal site was shown to be the infiltration-reducing (BC) layer, accounting for approximately 40%, 60%, and 70% of NH4+-N, CODcr and BOD5 removal, respectively. Conversely, the removal efficiency of NO3-N was found to be low (<15%), while total phosphorous (TP) was found to actively leach from the infiltration-reduction layer, resulting in measured TP discharges 2.4-4.8 times those of initial infiltration values. The current study provides a technical baseline for the efficacy of sodium bentonite as an effective bi-functional material in areas utilizing reclaimed water i.e. concurrent reduction of infiltration rates (Function 1) and decontamination of reclaimed wastewater infiltration/recharge (Function 2). Findings indicate that sodium bentonite-clay mixes may represent a feasible alternative for managing recharge of non-potable aquifers with reclaimed wastewater.
Garner, Emily; Chen, Chaoqi; Xia, Kang; Bowers, Jolene; Engelthaler, David M; McLain, Jean; Edwards, Marc A; Pruden, Amy
2018-06-05
Water reclamation provides a valuable resource for meeting nonpotable water demands. However, little is known about the potential for wastewater reuse to disseminate antibiotic resistance genes (ARGs). Here, samples were collected seasonally in 2014-2015 from four U.S. utilities' reclaimed and potable water distribution systems before treatment, after treatment, and at five points of use (POU). Shotgun metagenomic sequencing was used to profile the resistome (i.e., full contingent of ARGs) of a subset ( n = 38) of samples. Four ARGs ( qnrA, bla TEM , vanA, sul1) were quantified by quantitative polymerase chain reaction. Bacterial community composition (via 16S rRNA gene amplicon sequencing), horizontal gene transfer (via quantification of intI1 integrase and plasmid genes), and selection pressure (via detection of metals and antibiotics) were investigated as potential factors governing the presence of ARGs. Certain ARGs were elevated in all ( sul1; p ≤ 0.0011) or some ( bla TEM , qnrA; p ≤ 0.0145) reclaimed POU samples compared to corresponding potable samples. Bacterial community composition was weakly correlated with ARGs (Adonis, R 2 = 0.1424-0.1734) and associations were noted between 193 ARGs and plasmid-associated genes. This study establishes that reclaimed water could convey greater abundances of certain ARGs than potable waters and provides observations regarding factors that likely control ARG occurrence in reclaimed water systems.
Rapid method to determine actinides and 89/90Sr in limestone and marble samples
Maxwell, Sherrod L.; Culligan, Brian; Hutchison, Jay B.; ...
2016-04-12
A new method for the determination of actinides and radiostrontium in limestone and marble samples has been developed that utilizes a rapid sodium hydroxide fusion to digest the sample. Following rapid pre-concentration steps to remove sample matrix interferences, the actinides and 89/90Sr are separated using extraction chromatographic resins and measured radiometrically. The advantages of sodium hydroxide fusion versus other fusion techniques will be discussed. Lastly, this approach has a sample preparation time for limestone and marble samples of <4 hours.
Bueno, I J M; Surek, D; Rocha, C; Schramm, V G; Muramatsu, K; Dahlke, F; Maiorka, A
2016-04-01
An experiment was conducted to test the hypothesis that a coarse limestone diet improves productivity, reproductive performance and the calcium utilization of molted broiler breeders. In total, 640 broiler breeder females, 73-week-old and sixty-four 27-week-old cockerels, Cobb 500, were evaluated during 10 weeks, according to a randomized block design composed of 4 treatments with 8 replicates each. Treatments consisted of diets with the inclusion of 100% fine limestone-fine PS (0.2 mm GMD-geometric mean diameter); PS1: 30% fine limestone+70% limestone with 1.0 mm GMD; PS2: 30% fine limestone+70% limestone with 2.0 mm GMD; and PS3: 30% fine limestone+70% limestone with 3.0 mm GMD. Calcium retention in the gizzard of the breeders, bone characteristics, and breeder performance, egg characteristics, eggshell quality, incubation performance, chick quality and yield, chick pre-starter live performance, and chick bone characteristics were determined. There was no significant difference (P>0.05) in the rate of lay, percentage of non-settable eggs, egg weight, egg shape index, egg specific gravity, eggshell weight, thickness, and percentage hatchability and egg weight loss of broiler breeders fed with diets with different limestone particle sizes. The chick quality and yield, chick pre-starter live performance, and chick bone characteristics were not affected (P>0.05) by any of the limestone particle sizes. It was concluded that live and reproductive performance parameters of broiler breeders post molting is not affected by limestone particle size in the feed. © 2016 Poultry Science Association Inc.
Li, Dan; Zeng, Siyu; Gu, April Z; He, Miao; Shi, Hanchang
2013-07-01
Disinfection of reclaimed water prior to reuse is important to prevent the transmission of pathogens. Chlorine is a widely utilized disinfectant and as such is a leading contender for disinfection of reclaimed water. To understand the risks of chlorination resulting from the potential selection of pathogenic bacteria, the inactivation, reactivation and regrowth rates of indigenous bacteria were investigated in reclaimed water after chlorine disinfection. Inactivation of total coliforms, Enterococcus and Salmonella showed linear correlations, with constants of 0.1384, 0.1624 and 0.057 L/(mg.min) and R2 of 0.7617, 0.8316 and 0.845, respectively. However, inactivation of total viable cells by measurement of metabolic activity typically showed a linear correlation at lower chlorine dose (0-22 (mg-min)/L), and a trailing region with chlorine dose increasing from 22 to 69 (mg.min)/L. Reactivation and regrowth of bacteria were most likely to occur after exposure to lower chlorine doses, and extents of reactivation decreased gradually with increasing chlorine dose. In contrast to total coliforms and Enterococcus, Salmonella had a high level of regrowth and reactivation, and still had 2% regrowth even after chlorination of 69 (mg.min)/L and 24 hr storage. The bacterial compositions were also significantly altered by chlorination and storage of reclaimed water, and the ratio of Salmonella was significantly increased from 0.001% to 0.045% after chlorination of 69 (mg.min)/L and 24 hr storage. These trends indicated that chlorination contributes to the selection of chlorine-resistant pathogenic bacteria, and regrowth of pathogenic bacteria after chlorination in reclaimed water with a long retention time could threaten public health security during wastewater reuse.
Utilizing Lab Tests to Predict Asphalt Concrete Overlay Performance
DOT National Transportation Integrated Search
2017-12-01
A series of five experimental projects and three demonstration projects were constructed to better understand the performance of pavement overlays using various levels of asphalt binder replacement (ABR) from reclaimed asphalt pavement (RAP), recycle...
1968-05-01
flue gas . Is one. The more popular method Is wet limestone scrubbing. In the limestone Injection system, ground limestone Is mixed with the coal and...is removed. The remainder must be eliminated from the flue gas as SO2 by wet scrubbing. Reduced boiler efficiency, due to ash accumulation on the...use of the fluldlzed-bed boiler, rather than a conventional coal-fired boiler requiring a flue gas cleanup system, will result In an
Improved performance of reclaimed asphalt pavement mixes.
DOT National Transportation Integrated Search
2014-08-07
Utilization of RAP in asphalt pavements has become an important strategy to help offset rising : raw material prices and to improve the sustainability of our transportation infrastructure. The : South Dakota DOT began to routinely use RAP in mainl...
30 CFR 816.97 - Protection of fish, wildlife, and related environmental values.
Code of Federal Regulations, 2010 CFR
2010-07-01
..., and other benefits to fish and wildlife. (h) Where cropland is to be the postmining land use, and..., the operator shall intersperse reclaimed lands with greenbelts utilizing species of grass, shrubs, and...
30 CFR 816.97 - Protection of fish, wildlife, and related environmental values.
Code of Federal Regulations, 2011 CFR
2011-07-01
..., and other benefits to fish and wildlife. (h) Where cropland is to be the postmining land use, and..., the operator shall intersperse reclaimed lands with greenbelts utilizing species of grass, shrubs, and...
Nissen, Laura Burney
2007-03-01
Increasing numbers of youth entering the juvenile justice system on drug-related charges require new practice frameworks for youth advocates. Screening, assessment and intervention capabilities have not kept pace with the youth who need them. This article presents an overview of a new approach, based on the system of care movement, to integrated care service provision for this population. Utilizing the Reclaiming Futures initiative--being piloted in 10 communities in the United States--as a model for change, the article suggests that juvenile justice, in partnership with treatment and other community stakeholders, can have a positive impact on this social problem.
Model institutional infrastructures for recycling of photovoltaic modules
DOE Office of Scientific and Technical Information (OSTI.GOV)
Reaven, S.J.; Moskowitz, P.D.; Fthenakis, V.
1996-01-01
How will photovoltaic modules (PVMS) be recycled at the end of their service lives? This question has technological and institutional components (Reaven, 1994a). The technological aspect concerns the physical means of recycling: what advantages and disadvantages of the several existing and emerging mechanical, thermal, and chemical recycling processes and facilities merit consideration? The institutional dimension refers to the arrangements for recycling: what are the operational and financial roles of the parties with an interest in PVM recycling? These parties include PVM manufacturers, trade organizations; distributors, and retailers; residential, commercial, and utility PVM users; waste collectors, transporters, reclaimers, and reclaimers; andmore » governments.« less
ANAEROBIC BIOREMEDIATION OF CHLORINATED ETHENES
The failure of what have been termed convential methods to reclaim contaminated environmental media has over the years lead to the interest and development of alternative technologies. One of these technologies is bioremediation, or the utilization of microbial agents to reduce ...
Liu, Jia-Nan; Chen, Zhuo; Wu, Qian-Yuan; Li, Ang; Hu, Hong-Ying; Yang, Cheng
2016-08-11
N, N-diethyl-m-toluamide (DEET) is one of the important emerging contaminants that are being increasingly detected in reclaimed water as well as in drinking water sources. However, DEET is refractory to conventional biological treatment and pure ozone which is absent of hydroxyl radical. Current researches on the efficient removal of DEET are still quite limited. This study utilizes a novel method, namely ozone/graphene oxide (O3/GO), to investigate the effects on DEET removal in aqueous systems, especially in reclaimed water. The results indicate that the DEET degradation rate was significantly accelerated through the combined effect of GO and ozonation which can yield abundant hydroxyl radical, compared to pure ozone condition. According to hydroxyl radical scavenging experiments, hydroxyl radical was found to play a dominant role in synergistic removal of DEET. These findings can offer sound suggestions for future research on the removal of emerging organic contaminants. The information could also be beneficial to reclaimed water safety and sustainable management.
Environmental Attitudes Semantic Differential.
ERIC Educational Resources Information Center
Mehne, Paul R.; Goulard, Cary J.
This booklet is an evaluation instrument which utilizes semantic differential data to assess environmental attitudes. Twelve concepts are included: regulated access to beaches, urban planning, dune vegetation, wetlands, future cities, reclaiming wetlands for building development, city parks, commercial development of beaches, existing cities,…
Characterization of Limestone as Raw Material to Hydrated Lime
NASA Astrophysics Data System (ADS)
Salem Hwidi, Rajeb; Nuraiti Tengku Izhar, Tengku; Saad, Farah Naemah Mohd
2018-03-01
In Malaysia, limestone is essentially important for the economic growth as raw materials in the industry sector. Nevertheless, a little attention was paid to the physical, chemical, mineralogical, and morphological properties of the limestone using X-ray fluorescence (X-RF), X-ray diffraction (X-RD), Fourier transform infrared spectroscopy (FTIR), and Scanning electron microscopy / energy dispersive x-ray spectroscopy (SEM-EDS) respectively. Raw materials (limestone rocks) were collected from Bukit Keteri area, Chuping, Kangar, Perlis, Malaysia. Lab crusher and lab sieved were utilized to prepare five different size of ground limestone at (75 µm, 150 µm, 225 µm, 300, and 425 µm) respectively. It is found that the main chemical composition of bulk limestone was Calcium oxide (CaO) at 97.58 wt.% and trace amount of MnO, Al2O3, and Fe2O3 at 0.02%, 0.35%, and 0.396% respectively. XRD diffractograms showed characteristic peaks of calcite and quartz. Furthermore, main FTIR absorption bands at 1,419, 874.08 and 712.20 cm-1 indicated the presence of calcite. The micrographs showed clearly the difference of samples particle size. Furthermore, EDS peaks of Ca, O, and C elements confirmed the presence of CaCO3 in the samples.
Hamilton, Kerry A; Hamilton, Mark T; Johnson, William; Jjemba, Patrick; Bukhari, Zia; LeChevallier, Mark; Haas, Charles N
2018-05-01
The use of reclaimed water brings new challenges for the water industry in terms of maintaining water quality while increasing sustainability. Increased attention has been devoted to opportunistic pathogens, especially Legionella pneumophila, due to its growing importance as a portion of the waterborne disease burden in the United States. Infection occurs when a person inhales a mist containing Legionella bacteria. The top three uses for reclaimed water (cooling towers, spray irrigation, and toilet flushing) that generate aerosols were evaluated for Legionella health risks in reclaimed water using quantitative microbial risk assessment (QMRA). Risks are compared using data from nineteen United States reclaimed water utilities measured with culture-based methods, quantitative PCR (qPCR), and ethidium-monoazide-qPCR. Median toilet flushing annual infection risks exceeded 10 -4 considering multiple toilet types, while median clinical severity infection risks did not exceed this value. Sprinkler and cooling tower risks varied depending on meteorological conditions and operational characteristics such as drift eliminator performance. However, the greatest differences between risk scenarios were due to 1) the dose response model used (infection or clinical severity infection) 2) population at risk considered (residential or occupational) and 3) differences in laboratory analytical method. Theoretical setback distances necessary to achieve a median annual infection risk level of 10 -4 are proposed for spray irrigation and cooling towers. In both cooling tower and sprinkler cases, Legionella infection risks were non-trivial at potentially large setback distances, and indicate other simultaneous management practices could be needed to manage risks. The sensitivity analysis indicated that the most influential factors for variability in risks were the concentration of Legionella and aerosol partitioning and/or efficiency across all models, highlighting the importance of strategies to manage Legionella occurrence in reclaimed water. Copyright © 2018 Elsevier Ltd. All rights reserved.
DOE Office of Scientific and Technical Information (OSTI.GOV)
Richmann, D.L.; Rossi, J.P.; Rashin, E.B.
1984-07-01
The major objective of this project is to provide electric utilities with information concerning the availability of flue gas desulfurization (FGD) system reagents. Data presented in this report were obtained primarily from a comprehensive review of available literature. These were augmented by information gathered through interviews with knowledgeable individuals from industry, government, and academic institutions. Limestone data are presented on regional and state maps displaying, respectively, annual limestone production and number of active quarries by county; and areas most likely to contain potentially commercial deposits of high-Ca (greater than or equal to 90% CaCO/sub 3/) limestone. Lime data are presentedmore » on regional maps indicating ranges of annual production and number of active lime plants by county. Identification of commercial versus captive operations and estimates of lime availability on the open market are summarized in tables accompanying each map.« less
Potential benefits of adding emulsion to reclaimed base material : interim report - fourth year.
DOT National Transportation Integrated Search
2003-05-01
Rehabilitation of deteriorated asphalt pavements has become one of the primary tools utilized by the : Maine Department of Transportation (MDOT). One method used to achieve this task is the use of full : depth reclamation (FDR). : In an effort to imp...
DOE Office of Scientific and Technical Information (OSTI.GOV)
Hendriks, R.V.; Nolan, P.S.
1987-01-01
The paper describes and discusses the key design features of the retrofit of EPA's Limestone Injection Multistage Burner (LIMB) system to an operating, wall-fired utility boiler at Ohio Edison's Edgewater Station. It further describes results of the pertinent projects in EPA's LIMB program and shows how these results were used as the basis for the design of the system. The full-scale demonstration is expected to prove the effectiveness and cost of the LIMB concept for use on large-scale utility boilers. The equipment is now being installed at Edgewater, with system start-up scheduled for May 1987.
Christiansen, M L; Webb, K E
1990-07-01
Effects were evaluated of high dietary levels of magnesium oxide (MgO) or limestone on DM, OM and CP digestibility, N balance and intestinal absorption of amino acids by lambs fed a high concentrate diet. Twelve wether lambs equipped with abomasal and ileal cannulas were blocked by weight and breeding and allotted to treatments in a randomized block design in two consecutive trials. Diets were control (800 g), control plus 1.5% MgO (812 g), control plus 1.5% limestone (812 g) and control plus 3.0% limestone (824 g) fed in two equal portions at 12-h intervals. Ruminal fluid pH differences were small. The pH of ileal digesta was greater (P less than .05) with MgO than with limestone (8.23 vs 7.73). Fecal pH was higher (P less than .01) for lambs fed all mineral treatments (avg 8.75) than for lambs fed the control (7.61) and was higher (P less than .01) when MgO (9.53) rather than limestone (8.36) was fed. Ruminal NH3N was lower (P less than .01) when lambs were fed MgO (11.9 mg/dl) compared with limestone (avg 31.2 mg/dl). Preintestinal DM digestibility was greatest (P less than .10) with limestone (avg 49.5%) feeding compared with feeding MgO (31.2%) or the control (35.4%). About 41.5% more essential (P less than .05) and 48% more nonessential (P less than .03) amino acids reached the small intestine when MgO was fed than when limestone was fed. Partial digestibility of amino acids in the small intestine was reduced (P less than .03) an average of 5 percentage units when MgO or limestone was fed. Feeding high levels of MgO or limestone to lambs did not improve the overall digestibility of DM, OM or CP. In fact, feeding high levels of MgO or limestone appeared to be detrimental, reducing intestinal absorption of amino acids.
DOT National Transportation Integrated Search
2011-04-01
The implementation of warm-mix asphalt (WMA) is becoming more widespread with a growing number of contractors utilizing various WMA technologies. Early research suggests WMA may be more susceptible to moisture damage than traditional hot-mix asphalt ...
40 CFR 503.9 - General definitions.
Code of Federal Regulations, 2010 CFR
2010-07-01
..., sanitary district, utility district, drainage district, or similar entity, or an integrated waste... that can be applied to a unit area of land (e.g., gallons per acre). (v) Runoff is rainwater, leachate... owned, publicly owned, or privately owned device or system used to treat (including recycle and reclaim...
Jasion, Mateusz; Samecka-Cymerman, Aleksandra; Kolon, Krzysztof; Kempers, Alexander J
2013-10-01
We investigated the possibility of use of Tanacetum vulgare (tansy) as an ecological indicator of metal concentration in a naturally colonized open-pit lignite mine in Bełchatów (Poland). Tanacetum vulgare is the only species growing abundantly and spontaneously in the lignite mine waste dumps. Metal concentrations in roots, stems, leaves, flowers, and soil were measured in dump sites differing in type and time of reclamation and therefore differing in pollution levels. Tanacetum vulgare appeared to be an accumulator of chromium and iron in roots, whereas highest concentrations of manganese and zinc were found in leaves. A high bioaccumulation factor for cadmium (Cd) was observed in dumps and control sites, indicating that even small amounts of Cd in the environment may result in significant uptake by the plant. The lowest concentrations of metals were found in plants from sites situated on dumps reclaimed with argillaceous limestone.
DOE Office of Scientific and Technical Information (OSTI.GOV)
Barcelo, Laurent, E-mail: laurent.barcelo@lafarge.com; Lafarge Centre de Recherche, 95 rue du Montmurier, 38291 St Quentin Fallavier; Gartner, Ellis
2014-09-15
Blended Portland cements containing up to 15% limestone have recently been introduced into Canada and the USA. These cements were initially not allowed for use in sulfate environments but this restriction has been lifted in the Canadian cement specification, provided that the “limestone cement” includes sufficient SCM and that it passes a modified version of the CSA A3004-C8 (equivalent to ASTM C1012) test procedure run at a low temperature (5 °C). This new procedure is proposed as a means of predicting the risk of the thaumasite form of sulfate attack in concretes containing limestone cements. The goal of the presentmore » study was to better understand how this approach works both in practice and in theory. Results from three different laboratories utilizing the CSA A3004-C8 test procedure are compared and analyzed, while also taking into account the results of thermodynamic modeling and of thaumasite formation experiments conducted in dilute suspensions.« less
The report summarizes activities conducted and results achieved in an EPA-sponsored program to demonstrate Limestone Injection Multistage Burner (LIMB) technology on a tangentially fired coal-burning utility boiler, Virginia Power's 180-MWe Yorktown Unit No. 2. his successfully d...
Hlava, Jakub; Hlavová, Anna; Hakl, Josef; Fér, Miroslav
2015-01-01
This study provides earthworm population data obtained from localities with a substantial anthropogenic impact spoils. The spoil heaps were reclaimed at the end of an opencast brown coal mining period. We studied spoils reclaimed by the two most commonly used reclamation processes: forestry and agricultural. The results show the significance of the locality age and the utilized reclamation process and treatment and their effect on earthworm communities. Our data indicate that apart from soil physical and chemical properties, the reclamation process itself may also induce viability and distribution of earthworm communities. Under standardized soil properties, the changes in earthworm populations during the succession were larger within the agricultural reclamation process as opposed to the forestry reclamation process for earthworm ecological groups and individual species.
Framing Lumber from Building Removal: How do We Best Utilize This Untapped Structural Resource?
Robert H. Falk; Steven Cramer; James Evans
2013-01-01
Compared with other construction materials, wood products are environmentally attractive because they sequester carbon, are renewable, and are low in embodied energy. Lumber salvaged from building removal possesses these same qualities but with additional environmental attributes. In spite of the environmental attractiveness of reclaimed lumber, its widespread...
2012-05-04
crossing, and three herbaceous wetlands within the Gulf Power Easement portion of the action alternative 2 alignment. Cogon grass ( Imperata ... cylindrica ), an invasive, non-native species, is also located in some areas within the utility easement. Tyndall AFB is actively trying to eliminate the
Pathogens Assessment in Reclaimed Effluent Used for Industrial Crops Irrigation
Al-Sa’ed, R.
2007-01-01
Reuse of treated effluent is a highly valued water source in Palestine, however with limited success due to public health concerns. This paper assesses the potential pathogens in raw, treated and reclaimed wastewater at Albireh urban wastewater treatment facility, and provides scientific knowledge to update the Palestinian reuse guidelines. Laboratory analyses of collected samples over a period of 4 months have indicated that the raw wastewater from Albireh city contained high numbers of fecal coliforms and worm eggs while 31% of the samples were Salmonella positive. Treated effluent suitable for restricted irrigation demonstrated that the plant was efficient in removing indicator bacteria, where fecal coliforms and fecal streptococci removal averaged 99.64% and 93.44%, respectively. Although not disinfected, treated effluent was free of Salmonella and parasites, hence safe for restricted agricultural purposes. All samples of the reclaimed effluent and three samples of irrigated grass were devoid of microbial pathogens indicating a safe use in unrestricted agricultural utilization. Adequate operation of wastewater treatment facilities, scientific updating of reuse guidelines and launching public awareness campaigns are core factors for successful and sustainable large-scale wastewater reuse schemes in Palestine. PMID:17431318
Pennington, Marcus John; Rothman, Jason A; Jones, Michael Bellinger; McFrederick, Quinn S; Gan, Jay; Trumble, John T
2018-02-08
Many countries are utilizing reclaimed wastewater for agriculture as water demands due to drought, rising temperatures, and expanding human populations. Unfortunately, wastewater often contains biologically active, pseudopersistant pharmaceuticals, even after treatment. Runoff from agriculture and effluent from wastewater treatment plants also contribute high concentrations of pharmaceuticals to the environment. This study assessed the effects of common pharmaceuticals on an agricultural pest, the aphid Myzus persicae (Sulzer, Hemiptera: Aphididae). Second instar nymphs were transferred to bell peppers (Capsicum annuum) that were grown hydroponically. Treatment plants were spiked with contaminants of emerging concern (CECs) at environmentally relevant concentrations found in reclaimed wastewater. M. persicae displayed no differences in population growth or microbial community differences due to chemical treatments. Plants, however, displayed significant growth reduction in antibiotic and mixture treatments, specifically in wet root masses. Antibiotic treatment masses were significantly reduced in the total and root wet masses. Mixture treatments displayed an overall reduction in plant root wet mass. Our results suggest that the use of reclaimed wastewater for crop irrigation would not affect aphid populations, but could hinder or delay crop production.
Fate of phosphorus in Everglades agricultural soils after fertilizer application
DOE Office of Scientific and Technical Information (OSTI.GOV)
Wright, Alan L.; Hanlon, Edward A.; McCray, J. Mabry
2012-07-01
Land use changes, agricultural drainage and conventional cultivation of winter vegetables and sugarcane cropping in the Everglades Agricultural Area (EAA) may alter soil conditions and organic matter decomposition and ultimately influence the fate of phosphorus (P). Theses agricultural practices promote soil subsidence, reduce the soil depth to bedrock limestone and increase the potential for incorporation of limestone into the root zone of crops. The incorporation of limestone into surface soil has significantly increased soil pH which in turns causes greater fixation of P fertilizer into unavailable forms for plant growth. Additional P fertilization is thus required to satisfy crop nutrientmore » requirements in plant-available P form. It is important to determine how the mixing of bedrock limestone into soils influences the behavior of P fertilizers after their application. To accomplish this task, P fertilizers were applied to (1) typical cultivated soils and to (2) soils that have never been fertilized or extensively tilled. The changes in P concentrations over time were then compared between the two land uses, with differences being attributable to the impacts of cultivation practices. The P distribution in soil varied between land uses, with sugarcane having more P in inorganic pools while the uncultivated soil had more in organic pools. Water-soluble P concentrations in soil increased with increasing fertilizer application rates for all sampling times and both land uses. However, concentrations in uncultivated soil increased proportionally to P-fertilized soil due to organic P mineralization. At all sampling times, plant-available P concentrations remained higher for uncultivated than sugarcane soil. Lower P concentrations for sugarcane were related to adsorption by mineral components (e.g. limestone). Cultivated soils have higher calcium concentrations resulting from incorporation of bedrock limestone into soil by tillage, which increased pH and fostered sequestration of plant-available P into stable calcium-bound P pools. This greater P retention for sugarcane was reflected in the greater proportion of P in inorganic pools compared to uncultivated soils. Some lands within the EAA, including wetlands and seasonally-flooded prairies, are being reclaimed for water quality purposes. However, long-term effects of fertilization and cropping practices described in this document indicate that direct conversion from active farming, such as from sugarcane production directly to wetlands, may be problematic due to the changes in nutrient dynamics that may occur. The shift directly to wetlands may, in fact, release considerable amounts of P into the Everglades, thwarting the intent of the land use change. The inorganic P component in sugarcane soils may lead to the regeneration of soluble P in frequently flooded land uses such as wetlands. While most of the inorganic P pools are unavailable to sugarcane, the direct conversion of sugarcane soils to wetlands may facilitate P release. Here, reclamation of sugarcane fields for environment uses would benefit by an intermediate step to allow for a short duration of seasonal flooding allowing for P conversion from inorganic to organic forms. Prolonged flooding of organic soils previously used for intensive agriculture is not recommended.« less
Application and study of land-reclaim based on Arc/Info
NASA Astrophysics Data System (ADS)
Zhao, Jun; Zhang, Ruiju; Wang, Zhian; Li, Shiyong
2005-10-01
This paper firstly puts forward the evaluation models of land-reclaim, which is derived from the thoery of Fuzzy associative memory nerve network and corresponding supplemental CASE tools, based on the model the mode of land reclaim can determined, and then the elements of land-reclaim are displayed and synthesized visually and virtually by virtue of Arc/Info software. In the process of land reclaim, it is particularly important to build the model of land-reclaim and to map the distribution of soil elements. In this way rational and feasible schemes are adopted in order to instruct the project of land reclaim. This thesis mainly takes the fourth mining area of East Beach as an example and puts this model into practice. Based on Arc/Info software the application of land-reclaim is studied and good results are achieved.
Comparing digital data processing techniques for surface mine and reclamation monitoring
NASA Technical Reports Server (NTRS)
Witt, R. G.; Bly, B. G.; Campbell, W. J.; Bloemer, H. H. L.; Brumfield, J. O.
1982-01-01
The results of three techniques used for processing Landsat digital data are compared for their utility in delineating areas of surface mining and subsequent reclamation. An unsupervised clustering algorithm (ISOCLS), a maximum-likelihood classifier (CLASFY), and a hybrid approach utilizing canonical analysis (ISOCLS/KLTRANS/ISOCLS) were compared by means of a detailed accuracy assessment with aerial photography at NASA's Goddard Space Flight Center. Results show that the hybrid approach was superior to the traditional techniques in distinguishing strip mined and reclaimed areas.
NASA Astrophysics Data System (ADS)
Atwia, Mohamed G.; Abu-Heleika, Mohamed M.; El-Horiny, Mohamed M.
2013-04-01
An integrated geological, hydrochemical, and geoelectrical investigation of shallow groundwater occurrence in Burg El-Arab area, northwestern coastal zone of Egypt is carried out. Groundwater of oolitic limestone and clastic aquifers is the principal source of water supply for agriculture in the area. The purpose of this study is to describe the hydrogeologic characteristics of aquifers and to provide a general evaluation of the chemical quality of water in aquifers. Chemical analysis was used to evaluate the chemical characteristics of groundwater and assessment of water quality. Electrical soundings were employed to delineate different water bearing formations and the configuration of the interface between them. Thirty-four water samples were collected and chemically analyzed from the two main aquifers in the area. Groundwaters of oolitic limestone aquifer are dominated by NaCl and have average TDS of approximately 2830 mg/l. Groundwater samples from clastic aquifer are slightly weakly mineralized (TDS approximately 2700 mg/l) and dominated by CaSO4. The hydrochemical data indicate that the groundwater is of meteoric origin. The variation in the chemistry of water is thought to be related to the weathering of minerals of the water-bearing sediments, mixing with marine water, and leaching of fertilizers in the newly reclaimed areas. Groundwater of the area can be used for irrigation under special circumstances management as the sodium hazard is medium while the salinity hazard ranges from high to very high. Thirty-four profiles of vertical electrical soundings (VESs) were obtained in Burg El-Arab area to examine the variations of subsurface geology and associated groundwater chemistry. Resistivity and thickness of aquifers, resistivity of the unsaturated zone and depth to the confining bed have been delineated from the interpretation of electrical sounding data. The range of electrical resistivity values have been assigned to different layers by calibrating electrical resistivity with the borehole data. Results of the vertical electrical soundings and the hydrochemistry of the groundwater samples show that the brackish groundwater is dominated in the study area whereas the fresh groundwater is found as isolated patches in oolitic limestone aquifer.
Approach to the health-risk management on municipal reclaimed water reused in landscape water system
NASA Astrophysics Data System (ADS)
Liu, X.; Li, J.; Liu, W.
2008-12-01
Water pollution and water heavily shortage are both main environmental conflicts in China. Reclaimed water reuse is an important approach to lessen water pollution and solve the water shortage crisis in the city. The heath risk of reclaimed water has become the focus of the public. It is impending to evaluate the health risk of reclaimed water with risk assessment technique. Considering the ways of the reclaimed water reused, it is studied that health risk produced by toxic pollutants and pathogenic microbes in the processes of reclaimed water reused in landscape water system. The pathogenic microbes monitoring techniques in wastewater and reclaimed water are discussed and the hygienic indicators, risk assessment methods, concentration limitations of pathogenic microbes for various reclaimed water uses are studied. The principle of health risk assessment is used to research the exposure level and the health risk of concerned people in a wastewater reuse project where the reclaimed water is applied for green area irrigation in a public park in Beijing. The exposure assessment method and model of various reclaimed water uses are built combining with Beijing reclaimed water project. Firstly the daily ingesting dose and lifetime average daily dose(LADD) of exposure people are provided via field work and monitoring analysis, which could be used in health risk assessment as quantitative reference. The result shows that the main risk comes from the pathology pollutants, the toxic pollutants, the eutrophication pollutants, pathogenic microbes and the secondary pollutants when municipal wastewater is reclaimed for landscape water. The major water quality limited should include pathogenic microbes, toxic pollutants, and heavy metals. Keywords: municipal wastewater, reclaimed water, landscape water, health risk
Use of reclaimed water for power plant cooling.
DOE Office of Scientific and Technical Information (OSTI.GOV)
Veil, J. A.; Environmental Science Division
2007-10-16
Freshwater demands are steadily increasing throughout the United States. As its population increases, more water is needed for domestic use (drinking, cooking, cleaning, etc.) and to supply power and food. In arid parts of the country, existing freshwater supplies are not able to meet the increasing demands for water. New water users are often forced to look to alternative sources of water to meet their needs. Over the past few years, utilities in many locations, including parts of the country not traditionally water-poor (e.g., Georgia, Maryland, Massachusetts, New York, and North Carolina) have needed to reevaluate the availability of watermore » to meet their cooling needs. This trend will only become more extreme with time. Other trends are likely to increase pressure on freshwater supplies, too. For example, as populations increase, they will require more food. This in turn will likely increase demands for water by the agricultural sector. Another example is the recent increased interest in producing biofuels. Additional water will be required to grow more crops to serve as the raw materials for biofuels and to process the raw materials into biofuels. This report provides information about an opportunity to reuse an abundant water source -- treated municipal wastewater, also known as 'reclaimed water' -- for cooling and process water in electric generating facilities. The report was funded by the U.S. Department of Energy's (DOE's) National Energy Technology Laboratory (NETL) Innovations for Existing Plants research program (Feeley 2005). This program initiated an energy-water research effort in 2003 that includes the availability and use of 'nontraditional sources' of water for use at power plants. This report represents a unique reference for information on the use of reclaimed water for power plant cooling. In particular, the database of reclaimed water user facilities described in Chapter 2 is the first comprehensive national effort to identify and catalog those plants that are using reclaimed water for cooling.« less
DOE Office of Scientific and Technical Information (OSTI.GOV)
Prudich, M.E.; Appell, K.W.; McKenna, J.D.
ETS, Inc., a pollution consulting firm with headquarters in Roanoke, Virginia, has developed a dry, limestone-based flue gas desulfurization (FGD) system. This SO{sub 2} removal system, called Limestone Emission Control (LEC), can be designed for installation on either new or existing coal-fired boilers. In the LEC process, the SO{sub 2} in the flue gas reacts with wetted granular limestone that is contained in a moving bed. A surface layer of principally calcium sulfate (CaSO{sub 4}) is formed on the limestone. Periodic removal of this surface layer by mechanical agitation allows high utilization of the limestone granules. A nominal 5,000 acfmmore » LEC pilot plant has been designed, fabricated and installed on the slipstream of a 70,000 pph stoker boiler providing steam to Ohio University`s Athens, Ohio campus. A total of over 90 experimental trials have been performed using the pilot-scale moving-bed LEC dry scrubber as a part of this research project with run times ranging up to a high of 125 hours. SO{sub 2} removal efficiencies as high as 99.9% were achievable for all experimental conditions studied during which sufficient humidification was added to the LEC bed. The LEC process and conventional limestone scrubbing have been compared on an equatable basis using flue gas conditions that would be expected at the outlet of the electrostatic precipitator (ESP) of a 500 MW coal-fired power plant. The LEC was found to have a definite economic advantage in both direct capital costs and operating costs. Based on the success and findings of the present project, the next step in LEC process development will be a full-scale commercial demonstration unit.« less
Recycling of Metals and Materials: A Selected Bibliography.
ERIC Educational Resources Information Center
Seidman, Ruth K., Comp.; Castrow, Lee, Comp.
Recycling of metals and materials has as its purpose the easing of two major environmental crises. First, we re-utilize scarce and non-renewable resources. Second, solid waste disposal problems can be alleviated. Industry has long been concerned with reclaiming its own waste products, and is now beginning to respond to the need for dealing with…
Reclaimed surface mine terrestrial pools: Integrating remote sensing, spatial data and field work
NASA Astrophysics Data System (ADS)
Kazar, Sheila A.
This study investigated the remote sensing of aboveground biomass in reclaimed surface mine reclamation sites and the carbon (C) storage potential of these sites. The research is structured in three sections. In the first study, the potential for utilizing the tasseled cap (TC) spectral transformation to characterize multi-temporal changes of vegetation growth was investigated within nine reclaimed coal surface mines in Monongalia and Preston Counties, West Virginia. The spectral patterns of TC greenness, brightness and wetness values associated with the minesites were investigated for a multi-temporal series of Landsat Thematic Mapper (TM) images, from 1992 to 2007. In general, most of the minesites at the time of mining showed increased brightness, and decreased greenness and wetness, with a reverse of this pattern during reclamation. However, rainfall appears to be a confounding variable, at least for relatively recently reclaimed sites. Spectral change vector analysis (CVA) was found to be effective for summarizing the patterns of change in TC values before and after reclamation. In the second study, field samples were collected from reclaimed grassland minesites and used to estimate biomass and C accumulation. In general, biomass and C increased in the six years following reclamation, and then slowly declined. Three Landsat Thematic Mapper (TM) images, from April, May and September of 2007, were used to assess four vegetation indices (VIs), TC, and red and near infrared radiance for potential for mapping biomass. For the April 3 Landsat image, the vegetation indices were not statistically correlated with field-measured biomass, and nor were the regression models significant. For the May 13 image, TC greenness and EVI were most strongly correlated with biomass, with TC wetness, NDVI, TVI and SAVI all significant at the 0.05 level. A number of regression models that included age since reclamation and spectral indices for May 13 were statistically significant, with the strongest prediction obtained from EVI. For the September 18 image, the correlation of biomass and TC brightness, TM4 and TVI were all statistically significant at the 0.05 level, although regression models that included age since reclamation as a dummy variable were not significant. In the third and final study, the biophysical potential for terrestrial aboveground C storage in minelands reclaimed to grasslands was investigated at the regional and state scale. Although above-ground annual accumulation of C is low in grasslands, if the aboveground biomass were harvested annually, and stored permanently C storage over 20 years on the grasslands of reclaimed minelands in West Virginia could be 3.60-7.32 Tg C, compared to 1.60 -9.80 Tg C if those same sites were reclaimed to forests. Although there is currently only limited usage of harvested hay for purposes that would result in its long-term storage, this study points to the benefits that would accrue if such mechanisms could be developed.
40 CFR 428.80 - Applicability; description of the wet digestion reclaimed rubber subcategory.
Code of Federal Regulations, 2014 CFR
2014-07-01
... digestion reclaimed rubber subcategory. 428.80 Section 428.80 Protection of Environment ENVIRONMENTAL... CATEGORY Wet Digestion Reclaimed Rubber Subcategory § 428.80 Applicability; description of the wet digestion reclaimed rubber subcategory. The provisions of this subpart are applicable to process waste water...
40 CFR 428.80 - Applicability; description of the wet digestion reclaimed rubber subcategory.
Code of Federal Regulations, 2010 CFR
2010-07-01
... digestion reclaimed rubber subcategory. 428.80 Section 428.80 Protection of Environment ENVIRONMENTAL... Wet Digestion Reclaimed Rubber Subcategory § 428.80 Applicability; description of the wet digestion... discharges resulting from the production of reclaimed rubber by use of the wet digestion process. ...
40 CFR 428.80 - Applicability; description of the wet digestion reclaimed rubber subcategory.
Code of Federal Regulations, 2012 CFR
2012-07-01
... digestion reclaimed rubber subcategory. 428.80 Section 428.80 Protection of Environment ENVIRONMENTAL... CATEGORY Wet Digestion Reclaimed Rubber Subcategory § 428.80 Applicability; description of the wet digestion reclaimed rubber subcategory. The provisions of this subpart are applicable to process waste water...
40 CFR 428.80 - Applicability; description of the wet digestion reclaimed rubber subcategory.
Code of Federal Regulations, 2011 CFR
2011-07-01
... digestion reclaimed rubber subcategory. 428.80 Section 428.80 Protection of Environment ENVIRONMENTAL... Wet Digestion Reclaimed Rubber Subcategory § 428.80 Applicability; description of the wet digestion... discharges resulting from the production of reclaimed rubber by use of the wet digestion process. ...
40 CFR 428.80 - Applicability; description of the wet digestion reclaimed rubber subcategory.
Code of Federal Regulations, 2013 CFR
2013-07-01
... digestion reclaimed rubber subcategory. 428.80 Section 428.80 Protection of Environment ENVIRONMENTAL... CATEGORY Wet Digestion Reclaimed Rubber Subcategory § 428.80 Applicability; description of the wet digestion reclaimed rubber subcategory. The provisions of this subpart are applicable to process waste water...
Code of Federal Regulations, 2013 CFR
2013-07-01
..., dry digestion, and mechanical reclaimed rubber subcategory. 428.90 Section 428.90 Protection of... MANUFACTURING POINT SOURCE CATEGORY Pan, Dry Digestion, and Mechanical Reclaimed Rubber Subcategory § 428.90 Applicability; description of the pan, dry digestion, and mechanical reclaimed rubber subcategory. The...
Code of Federal Regulations, 2012 CFR
2012-07-01
..., dry digestion, and mechanical reclaimed rubber subcategory. 428.90 Section 428.90 Protection of... MANUFACTURING POINT SOURCE CATEGORY Pan, Dry Digestion, and Mechanical Reclaimed Rubber Subcategory § 428.90 Applicability; description of the pan, dry digestion, and mechanical reclaimed rubber subcategory. The...
Code of Federal Regulations, 2011 CFR
2011-07-01
..., dry digestion, and mechanical reclaimed rubber subcategory. 428.90 Section 428.90 Protection of... POINT SOURCE CATEGORY Pan, Dry Digestion, and Mechanical Reclaimed Rubber Subcategory § 428.90 Applicability; description of the pan, dry digestion, and mechanical reclaimed rubber subcategory. The...
Code of Federal Regulations, 2014 CFR
2014-07-01
..., dry digestion, and mechanical reclaimed rubber subcategory. 428.90 Section 428.90 Protection of... MANUFACTURING POINT SOURCE CATEGORY Pan, Dry Digestion, and Mechanical Reclaimed Rubber Subcategory § 428.90 Applicability; description of the pan, dry digestion, and mechanical reclaimed rubber subcategory. The...
Code of Federal Regulations, 2010 CFR
2010-07-01
..., dry digestion, and mechanical reclaimed rubber subcategory. 428.90 Section 428.90 Protection of... POINT SOURCE CATEGORY Pan, Dry Digestion, and Mechanical Reclaimed Rubber Subcategory § 428.90 Applicability; description of the pan, dry digestion, and mechanical reclaimed rubber subcategory. The...
NASA Astrophysics Data System (ADS)
Mount, G. J.; Comas, X.
2015-12-01
Subsurface water flow within the Biscayne aquifer is controlled by the heterogeneous distribution of porosity and permeability in the karst Miami Limestone and the presence of numerous dissolution and mega-porous features. The dissolution features and other high porosity areas can create preferential flow paths and direct recharge to the aquifer, which may not be accurately conceptualized in groundwater flow models. As hydrologic conditions are undergoing restoration in the Everglades, understanding the distribution of these high porosity areas within the subsurface would create a better understanding of subsurface flow. This research utilizes ground penetrating radar to estimate the spatial variability of porosity and dielectric permittivity of the Miami Limestone at centimeter scale resolution at the laboratory scale. High frequency GPR antennas were used to measure changes in electromagnetic wave velocity through limestone samples under varying volumetric water contents. The Complex Refractive Index Model (CRIM) was then applied in order to estimate porosity and dielectric permittivity of the solid phase of the limestone. Porosity estimates ranged from 45.2-66.0% from the CRIM model and correspond well with estimates of porosity from analytical and digital image techniques. Dielectric permittivity values of the limestone solid phase ranged from 7.0 and 13.0, which are similar to values in the literature. This research demonstrates the ability of GPR to identify the cm scale spatial variability of aquifer properties that influence subsurface water flow which could have implications for groundwater flow models in the Biscayne and potentially other shallow karst aquifers.
TECHNOLOGICAL OPTIONS FOR ACID RAIN CONTROL
Discussed are acid rain control options available to the electric utility industry. They include coal switching, flue gas desulfurization, and such emerging lower cost technologies as Limestone Injection Multistage Burners (LIMB) and Advanced Silicate (ADVACATE), both developed ...
Tian, Xiaohai; Huang, Yongping; Huang, Zhimin; Lei, Weici; Higata, Shugo
2003-10-01
The searching for a proper land reclamation and utilization method adapted to the regional natural conditions and economical level is a prime subject in the waterlogged area of Southern China. Choosing a dish-like micro-zone, one of the typical waterlogged areas deprived from a reclaimed lake as the studying region, its biophysical characteristics and developmental models was investigated, aiming at making a comprehensive development plan to this area. The results showed that with the successive change in altitude across the sector of the land, the soil type, soil profile structure, underground water level, and soil temperature were characterized by five step divergence steps. The analysis on the site and area of the individual divergences showed that the low land was unsuitable for rice planting, and the land between upland and paddy should be increased for rotation and needed to be reclaimed better. After an engineering consolidation to the land, the original five divergence steps were rehabilitated into four steps, and a utilization model of "development in a step way" focused on comprehensively agricultural development and improvement in farming systems was developed, which leaded to a great advance in economic profit of this area.
Terrestrial salamander abundance on reclaimed mountaintop removal mines
Wood, Petra Bohall; Williams, Jennifer M.
2013-01-01
Mountaintop removal mining, a large-scale disturbance affecting vegetation, soil structure, and topography, converts landscapes from mature forests to extensive grassland and shrubland habitats. We sampled salamanders using drift-fence arrays and coverboard transects on and near mountaintop removal mines in southern West Virginia, USA, during 2000–2002. We compared terrestrial salamander relative abundance and species richness of un-mined, intact forest with habitats on reclaimed mountaintop removal mines (reclaimed grassland, reclaimed shrubland, and fragmented forest). Salamanders within forests increased in relative abundance with increasing distance from reclaimed mine edge. Reclaimed grassland and shrubland habitats had lower relative abundance and species richness than forests. Characteristics of reclaimed habitats that likely contributed to lower salamander abundance included poor soils (dry, compacted, little organic matter, high rock content), reduced vertical structure of vegetation and little tree cover, and low litter and woody debris cover. Past research has shown that salamander populations reduced by clearcutting may rebound in 15–24 years. Time since disturbance was 7–28 years in reclaimed habitats on our study areas and salamander populations had not reached levels found in adjacent mature forests.
Hydrology and geochemistry of a surface coal mine in northwestern Colorado
Williams, R.S.; Clark, G.M.
1994-01-01
The hydrology and geochemistry of a reclaimed coal mine in northwestern Colorado were monitored during water years 1988 and 1989. Some data also were collected in water years 1987 and 1990. This report describes (1) the sources of hydrologic recharge to and discharge from reclaimed spoil, (2) the relative contributions of recharge to the reclaimed spoil aquifer from identified source waters and the rate of water movement from those sources to the reclaimed spoil, and (3) the geochemical reactions that control water quality in reclaimed spoil. The study area was at a dip-slope coal mine encompassing about 7 square miles with land slopes of varying aspect. The area was instrumented and monitored at five sites; two sites had unmined and reclaimed- spoil areas adjacent to each other and three sites were unmined. The mined areas had been reclaimed. Instrumentation at the study sites included 1 climate station, 3 rain gages, 19 soil-water access tubes, 2 lysimeters, 18 wells completed in bedrock, 7 wells completed in reclaimed spoil, and 2 surface- water gaging stations. The results of the study indicate that the reclaimed spoil is recharged from surface recharge and underburden aquifers. Discharge, as measured by lysimeters, was about 3 inches per year and occurred during and after snowmelt. Hydraulic-head measurements indicated a potential for ground-water movement from deeper to shallower aquifers. Water levels rose in the reclaimed-spoil aquifer and spring discharge at the toe of the spoil slopes increased rapidly in response to snowmelt. Water chemistry, stable isotopes, geochemical models, and mass-balance calculations indicate that surface recharge and the underburden aquifers each contribute about 50 percent of the water to the reclaimed-spoil aquifers. Geochemical information indicates that pyrite oxidation and dissolution of carbonate and efflorescent sulfate minerals control the water chemistry of the reclaimed-spoil aquifer.
Regrowth of potential opportunistic pathogens and algae in reclaimed-water distribution systems.
Jjemba, Patrick K; Weinrich, Lauren A; Cheng, Wei; Giraldo, Eugenio; Lechevallier, Mark W
2010-07-01
A study of the quality of reclaimed water in treated effluent, after storage, and at three points in the distribution system of four plants in California, Florida, Massachusetts, and New York was conducted for 1 year. The plants had different treatment processes (conventional versus membrane bioreactor), production capacities, and methods for storage of the water, and the intended end uses of the water were different. The analysis focused on the occurrence of indicator bacteria (heterotrophic bacteria, coliforms, Escherichia coli, and enterococci) and opportunistic pathogens (Aeromonas spp., enteropathogenic E. coli O157:H7, Legionella spp., Mycobacterium spp., and Pseudomonas spp.), as well as algae. Using immunological methods, E. coli O157:H7 was detected in the effluent of only one system, but it was not detected at the sampling points, suggesting that its survival in the system was poor. Although all of the treatment systems effectively reduced the levels of bacteria in the effluent, bacteria regrew in the reservoir and distribution systems because of the loss of residual disinfectant and high assimilable organic carbon levels. In the systems with open reservoirs, algal growth reduced the water quality by increasing the turbidity and accumulating at the end of the distribution system. Opportunistic pathogens, notably Aeromonas, Legionella, Mycobacterium, and Pseudomonas, occurred more frequently than indicator bacteria (enterococci, coliforms, and E. coli). The Mycobacterium spp. were very diverse and occurred most frequently in membrane bioreactor systems, and Mycobacterium cookii was identified more often than the other species. The public health risk associated with these opportunistic pathogens in reclaimed water is unknown. Collectively, our results show the need to develop best management practices for reclaimed water to control bacterial regrowth and degradation of water before it is utilized at the point of use.
Regrowth of Potential Opportunistic Pathogens and Algae in Reclaimed-Water Distribution Systems ▿
Jjemba, Patrick K.; Weinrich, Lauren A.; Cheng, Wei; Giraldo, Eugenio; LeChevallier, Mark W.
2010-01-01
A study of the quality of reclaimed water in treated effluent, after storage, and at three points in the distribution system of four plants in California, Florida, Massachusetts, and New York was conducted for 1 year. The plants had different treatment processes (conventional versus membrane bioreactor), production capacities, and methods for storage of the water, and the intended end uses of the water were different. The analysis focused on the occurrence of indicator bacteria (heterotrophic bacteria, coliforms, Escherichia coli, and enterococci) and opportunistic pathogens (Aeromonas spp., enteropathogenic E. coli O157:H7, Legionella spp., Mycobacterium spp., and Pseudomonas spp.), as well as algae. Using immunological methods, E. coli O157:H7 was detected in the effluent of only one system, but it was not detected at the sampling points, suggesting that its survival in the system was poor. Although all of the treatment systems effectively reduced the levels of bacteria in the effluent, bacteria regrew in the reservoir and distribution systems because of the loss of residual disinfectant and high assimilable organic carbon levels. In the systems with open reservoirs, algal growth reduced the water quality by increasing the turbidity and accumulating at the end of the distribution system. Opportunistic pathogens, notably Aeromonas, Legionella, Mycobacterium, and Pseudomonas, occurred more frequently than indicator bacteria (enterococci, coliforms, and E. coli). The Mycobacterium spp. were very diverse and occurred most frequently in membrane bioreactor systems, and Mycobacterium cookii was identified more often than the other species. The public health risk associated with these opportunistic pathogens in reclaimed water is unknown. Collectively, our results show the need to develop best management practices for reclaimed water to control bacterial regrowth and degradation of water before it is utilized at the point of use. PMID:20453149
7 CFR 632.15 - Eligible uses and treatment of reclaimed lands.
Code of Federal Regulations, 2014 CFR
2014-01-01
... are eligible for cost sharing, and (2) Maintain, as applicable, lists of average costs of applying... Qualifications § 632.15 Eligible uses and treatment of reclaimed lands. (a) Reclaimed lands and water may be used... not eligible for cost sharing. (b) Reclaimed land use is determined by the objectives of the land user...
7 CFR 632.15 - Eligible uses and treatment of reclaimed lands.
Code of Federal Regulations, 2013 CFR
2013-01-01
... are eligible for cost sharing, and (2) Maintain, as applicable, lists of average costs of applying... Qualifications § 632.15 Eligible uses and treatment of reclaimed lands. (a) Reclaimed lands and water may be used... not eligible for cost sharing. (b) Reclaimed land use is determined by the objectives of the land user...
40 CFR 82.164 - Reclaimer certification.
Code of Federal Regulations, 2013 CFR
2013-07-01
... (CONTINUED) PROTECTION OF STRATOSPHERIC OZONE Recycling and Emissions Reduction § 82.164 Reclaimer... Recycling Program Manager—Reclaimer Certification. (f) Certificates are not transferable. In the event of a...
40 CFR 82.164 - Reclaimer certification.
Code of Federal Regulations, 2011 CFR
2011-07-01
... (CONTINUED) PROTECTION OF STRATOSPHERIC OZONE Recycling and Emissions Reduction § 82.164 Reclaimer... Recycling Program Manager—Reclaimer Certification. (f) Certificates are not transferable. In the event of a...
40 CFR 82.164 - Reclaimer certification.
Code of Federal Regulations, 2012 CFR
2012-07-01
... (CONTINUED) PROTECTION OF STRATOSPHERIC OZONE Recycling and Emissions Reduction § 82.164 Reclaimer... Recycling Program Manager—Reclaimer Certification. (f) Certificates are not transferable. In the event of a...
40 CFR 82.164 - Reclaimer certification.
Code of Federal Regulations, 2014 CFR
2014-07-01
... (CONTINUED) PROTECTION OF STRATOSPHERIC OZONE Recycling and Emissions Reduction § 82.164 Reclaimer... Recycling Program Manager—Reclaimer Certification. (f) Certificates are not transferable. In the event of a...
40 CFR 82.164 - Reclaimer certification.
Code of Federal Regulations, 2010 CFR
2010-07-01
... (CONTINUED) PROTECTION OF STRATOSPHERIC OZONE Recycling and Emissions Reduction § 82.164 Reclaimer... Recycling Program Manager—Reclaimer Certification. (f) Certificates are not transferable. In the event of a...
Lu, Shibao; Wang, Jianhua; Pei, Liang
2016-01-01
Reclaimed water is an important resource for irrigation, and exploration in making full use of it is an important way to alleviate water shortage. This paper analyzes the effects of irrigation with reclaimed water through field trials on the content and distribution of heavy metals in both tomatoes and the soil. By exploring the effects of reclaimed water after secondary treatment on the content and distribution characteristics of heavy metals in tomatoes and the heavy metal balance in the soil-crop system under different conditions, the study shows that there are no significant differences in the heavy metal content when the quantity of reclaimed water for irrigation varies. Reclaimed water for short-term irrigation does not cause pollution to either the soil environment or the crops. Nor will it cause the accumulation of heavy metals, and the index for the heavy metal content is far below the critical value of the national standard, which indicates that the vegetables irrigated with reclaimed water during their growth turn out to be free of pollutants. The heavy metals brought into the soil by reclaimed water are less than that taken away by the crops. The input and output quantities have only small effects on the heavy metal balance in the soil. This paper provides a reference for the evaluation and safety control of irrigation with reclaimed water. PMID:27005639
Lu, Shibao; Wang, Jianhua; Pei, Liang
2016-03-08
Reclaimed water is an important resource for irrigation, and exploration in making full use of it is an important way to alleviate water shortage. This paper analyzes the effects of irrigation with reclaimed water through field trials on the content and distribution of heavy metals in both tomatoes and the soil. By exploring the effects of reclaimed water after secondary treatment on the content and distribution characteristics of heavy metals in tomatoes and the heavy metal balance in the soil-crop system under different conditions, the study shows that there are no significant differences in the heavy metal content when the quantity of reclaimed water for irrigation varies. Reclaimed water for short-term irrigation does not cause pollution to either the soil environment or the crops. Nor will it cause the accumulation of heavy metals, and the index for the heavy metal content is far below the critical value of the national standard, which indicates that the vegetables irrigated with reclaimed water during their growth turn out to be free of pollutants. The heavy metals brought into the soil by reclaimed water are less than that taken away by the crops. The input and output quantities have only small effects on the heavy metal balance in the soil. This paper provides a reference for the evaluation and safety control of irrigation with reclaimed water.
Low-Temperature Curing Strength Enhancement in Cement-Based Materials Containing Limestone Powder.
Bentz, Dale P; Stutzman, Paul E; Zunino, Franco
2017-06-01
With the ongoing sustainability movement, the incorporation of limestone powder in cementitious binders for concrete in the U.S. has become a subject of renewed interest. In addition to accelerating the early age hydration reactions of cementitious systems by providing additional surfaces for nucleation and growth of products, limestone powder is also intriguing based on its influence on low-temperature curing. For example, previous results have indicated that the utilization of limestone powder to replace one quarter of the fly ash in a high volume fly ash mixture (40 % to 60 % cement replacement) produces a reduction in the apparent activation energy for setting for temperatures below 25 °C. In the present study, the relationship between heat release and compressive strength of mortars at batching/curing temperatures of 10 °C and 23 °C is investigated. For Portland-limestone cements (PLC) with limestone additions on the order of 10 %, a higher strength per unit heat release is obtained after only 7 d of curing in lime water. Surprisingly, in some cases, the absolute strength of these mortar cubes measured at 7 d is higher when cured at 10 °C than at 23 °C. Solubilities vs. temperature, reaction stoichiometries and enthalpies, and projected phase distributions based on thermodynamic modeling for the cementitious phases are examined to provide some theoretical insight into this strength enhancement. For a subset of the investigated cements, thermogravimetric analysis (TGA), quantitative X-ray diffraction (XRD), and scanning electron microscopy (SEM) are conducted on 7-d paste specimens produced at the two temperatures to examine differences in their reaction rates and the phases produced. The strength enhancement observed in the PLC cements is related to the cement hydration products formed in the presence of carbonates as a function of temperature.
Izbicki, J.A.
1985-01-01
A study was made to determine the suitability of three small hydrologic subareas in San Diego County, California, for reuse of treated municipal wastewater (reclaimed water). Groundwater quality has been impacted by agricultural water use, changes in natural recharge patterns, seawater intrusion, and groundwater movement from surrounding marine sediments. Groundwater levels near land surface may limit artificial recharge of reclaimed water or may require pumping of groundwater from the aquifer prior to recharge with reclaimed water. Reclaimed water may be used for irrigated water in upland areas. (USGS)
DOE Office of Scientific and Technical Information (OSTI.GOV)
Reis, Chuck; Nelson, Eric; Armer, James
The purpose of this playbook and accompanying spreadsheets is to generalize the detailed CBP analysis and to put tools in the hands of experienced refrigeration designers to evaluate multiple applications of refrigeration waste heat reclaim across the United States. Supermarkets with large portfolios of similar buildings can use these tools to assess the impact of large-scale implementation of heat reclaim systems. In addition, the playbook provides best practices for implementing heat reclaim systems to achieve the best long-term performance possible. It includes guidance on operations and maintenance as well as measurement and verification.
DOT National Transportation Integrated Search
2015-11-01
This report summarizes the main findings from a project funded by the National Center for : Sustainable Transportation (NCST) to investigate the use of higher percentages of reclaimed : asphalt pavement (RAP) and reclaimed asphalt shingles (RAS) as a...
DOT National Transportation Integrated Search
2015-11-01
This report summarizes the main findings from a project funded by the National Center for : Sustainable Transportation (NCST) to investigate the use of higher percentages of reclaimed : asphalt pavement (RAP) and reclaimed asphalt shingles (RAS) as a...
A toxicity-based method for evaluating safety of reclaimed water for environmental reuses.
Xu, Jianying; Zhao, Chuntao; Wei, Dongbin; Du, Yuguo
2014-10-01
A large quantity of toxic chemical pollutants possibly remains in reclaimed water due to the limited removal efficiency in traditional reclamation processes. It is not enough to guarantee the safety of reclaimed water using conventional water quality criteria. An integrated assessment method based on toxicity test is necessary to vividly depict the safety of reclaimed water for reuse. A toxicity test battery consisting of lethality, genotoxicity and endocrine disrupting effect was designed to screen the multiple biological effects of residual toxic chemicals in reclaimed water. The toxicity results of reclaimed water were converted into the equivalent concentrations of the corresponding positive reference substances (EQC). Simultaneously, the predicted no-effect concentration (PNEC) of each positive reference substance was obtained by analyzing the species sensitivity distribution (SSD) of toxicity data. An index "toxicity score" was proposed and valued as 1, 2, 3, or 4 depending on the ratio of the corresponding EQC to PNEC. For vividly ranking the safety of reclaimed water, an integrated assessment index "toxicity rank" was proposed, which was classified into A, B, C, or D rank with A being the safest. The proposed method was proved to be effective in evaluating reclaimed water samples in case studies. Copyright © 2014. Published by Elsevier B.V.
Gas Conversion Systems Reclaim Fuel for Industry
NASA Technical Reports Server (NTRS)
2015-01-01
A human trip to Mars will require astronauts to utilize resources on the Red Planet to generate oxygen and fuel for the ride home, among other things. Lakewood, Colorado-based Pioneer Energy has worked under SBIR agreements with Johnson Space Center to develop technology for those purposes, and now uses a commercialized version of the technology to recover oil and gas that would otherwise be wasted at drilling sites.
DOE Office of Scientific and Technical Information (OSTI.GOV)
Byerly, D.W.
1976-06-01
The following is a report of investigation on the geologic setting of several underground limestone mines in Ohio other than the PPG mine at Barberton, Ohio. Due to the element of available time, the writer is only able to deliver a brief synopsis of the geology of three sites visited. These three sites and the Barberton, Ohio site are the only underground limestone mines in Ohio to the best of the writer's knowledge. The sites visited include: (1) the Jonathan Mine located near Zanesville, Ohio, and currently operated by the Columbia Cement Corporation; (2) the abandoned Alpha Portland Cement Minemore » located near Ironton, Ohio; and (3) the Lewisburg Mine located at Lewisburg, Ohio, and currently being utilized as an underground storage facility. Other remaining possibilities where limestone is being mined underground are located in middle Ordovician strata near Carntown and Maysville, Kentucky. These are drift mines into a thick sequence of carbonates. The writer predicts, however, that these mines would have some problems with water due to the preponderance of carbonate rocks and the proximity of the mines to the Ohio River. None of the sites visited nor the sites in Kentucky have conditions comparable to the deep mine at Barberton, Ohio.« less
Development of reclaimed potable water quality criteria
NASA Technical Reports Server (NTRS)
Flory, D. A.; Weir, F. W.
1979-01-01
In order to minimize launch requirements necessary to meet the demands of long-term spaceflight, NASA will reuse water reclaimed from various on-board sources including urine, feces, wash water and humidity condensate. Development of reclamation systems requires the promulgation of water quality standards for potable reuse of the reclaimed water. Existing standards for domestic U.S. potable water consumption were developed, but do not consider the peculiar problems associated with the potable reuse of recycled water. An effort was made to: (1) define a protocol by which comprehensive reclaimed water potability/palatability criteria can be established and updated; and (2) continue the effort to characterize the organic content of reclaimed water in the Regenerative Life Support Evaluation.
DOE Office of Scientific and Technical Information (OSTI.GOV)
Carey, Stephanie Ann; Goldstein, Rachel E. Rosenberg; Gibbs, Shawn G.
Reclaiming municipal wastewater for agricultural, environmental, and industrial purposes is increasing in the United States to combat dwindling freshwater supplies. However, there is a lack of data regarding the microbial quality of reclaimed water. In particular, no previous studies have evaluated the occurrence of vancomycin-resistant enterococci (VRE) in reclaimed water used at spray irrigation sites in the United States. To address this knowledge gap, we investigated the occurrence, concentration, and antimicrobial resistance patterns of VRE and vancomycin-susceptible enterococci at three U.S. spray irrigation sites that use reclaimed water. We collected 48 reclaimed water samples from one Mid-Atlantic and two Midwestmore » spray irrigation sites, as well as their respective wastewater treatment plants, in 2009 and 2010. Samples were analyzed for total enterococci and VRE using standard membrane filtration. Isolates were purified and then confirmed using biochemical tests and PCR. Antimicrobial susceptibility testing was conducted using the Sensititre® microbroth dilution system. Data were analyzed by two-sample proportion tests and one-way analysis of variance. We detected total enterococci and VRE in 71% (34/48) and 4% (2/48) of reclaimed water samples, respectively. Enterococcus faecalis was the most common species identified. At the Mid-Atlantic spray irrigation site, UV radiation decreased total enterococci to undetectable levels; however, subsequent storage in an open-air pond at this site resulted in increased concentrations of enterococci. E. faecalis isolates recovered from the Mid-Atlantic spray irrigation site expressed intrinsic resistance to quinupristin/dalfopristin; however, non-E. faecalis isolates expressed resistance to quinupristin/dalfopristin (52% of isolates), vancomycin (4%), tetracycline (13%), penicillin (4%) and ciprofloxacin (17%). Our findings show that VRE are present in low numbers in reclaimed water at point-of-use at the sampled spray irrigation sites; however, resistance to other antimicrobial classes is more prevalent, particularly among non-E. faecalis isolates. - Highlights: • Enterococci were recovered in 71% of reclaimed water samples. • Vancomycin-resistant enterococci were detected in 4% of reclaimed water samples. • UV radiation at irrigation sites reduced enterococci to undetectable levels. • Storage of reclaimed water in open-air ponds increased levels of enterococci.« less
Switchgrass potential on reclaimed surface mines for biofuel production in West Virginia
NASA Astrophysics Data System (ADS)
Marra, Michael A.
The high cost and environmental risks associated with non-renewable energy sources has caused an increased interest in, and development of renewable biofuels. Switchgrass (Panicum virgatum L.), a warm season perennial grass, has been investigated as a source of biofuel feedstock due to its high biomass production on marginal soils, its tolerance of harsh growing conditions, and its ability to provide habitat for wildlife and soil conservation cover. West Virginia contains vast expanses of reclaimed surface mine lands and could potentially benefit from the production of switchgrass as a biofuel feedstock. Furthermore, switchgrass production could satisfy Surface Mining Reclamation and Control Act of 1977 (SMCRA) requirements for reclamation bond release to mine operators. Three separate studies will be discussed in this thesis to determine if switchgrass grown on reclaimed surface mines can produce yields similar to yields from stands grown under normal agronomic conditions and what common surface mining reclamation practices may be most appropriate for growing switchgrass. The first study examined yield production of three commercially-available, upland switchgrass varieties grown on two reclaimed surface mines in production years two, three and four. The Hampshire Hill mine site, which was reclaimed in the late 1990s using top soil and treated municipal sludge, averaged 5,800 kg (ha-yr)-1 of switchgrass compared to 803 kg (ha-yr)-1 at the Hobet 21 site which was reclaimed with crushed, unweathered rock over compacted overburden. Site and variety interacted with Cave-in-Rock as the top performer at the more fertile Hampshire Hill site and Shawnee produced the highest yields at Hobet 21 (7,853 kg ha-1 and 1,086 kg ha-1 averaged across years, respectively). Switchgrass yields increased from 2009 to 2010, but declined from 2010 to 2011. Switchgrass yields from farmlands in this region averaged about 15000 kg (ha-yr)-1 in the research literature, so switchgrass grown on reclaimed lands appears to be about 50% lower. A second study to determine optimal nitrogen and mulch rates for switchgrass establishment began in June 2011 on two newly-reclaimed surface mines. Both sites were seeded at a rate of 11.2 kg pure live seed (PLS) ha-1 of Cave-in-Rock on replicated treatments of 0, 33.6 and 67.0 kg N ha-1, and high and low mulch rates of mulch applied as hydromulch. Switchgrass cover, frequency and yield improved with the addition of any amount of N fertilizer compared to no N application. There was no significant difference in yield associated with high and low levels of N. We also observed that yields were not affected by application of additional mulch. The final study compared a one- and two-harvest system in the fourth year of production at the Hampshire Hill and Hobet 21 sites. There was no increase in yield production utilizing a two-harvest system (2922 kg (ha-yr)-1, averaged across site) compared to a one-harvest system (3029 kg (ha-yr)-1). The data also showed that re-growth collected from July to October in the two-harvest system added negligible yield and that yield collected in July was comparable in one- and two-harvest systems.
NASA Astrophysics Data System (ADS)
Yu, Yilei; Song, Xianfang; Zhang, Yinghua; Zheng, Fandong; Liu, Licai
2017-12-01
Reclaimed water is efficient for replenishing the dry rivers in northern China, but regional groundwater may be at risk from pollution. Therefore, samples of reclaimed water, river water, and groundwater were collected at the Huai River in the Chaobai River basin in 2010. The water chemistry and isotopic compositions of the samples were analyzed in the laboratory. The reclaimed water had stable compositions of water chemistry and isotopes, and the Na·Ca-HCO3·Cl water type. The water chemistry of the river water was consistent with that of the reclaimed water. A June peak of total nitrogen was the prominent characteristic in the shallow groundwater, which also had the Na·Ca-HCO3·Cl water type. However, the water chemistry and isotopes in most of the deep groundwater remained stable, and the water type was Ca·Mg-HCO3. The amount of reclaimed water recharging the groundwater was about 2.5 × 107 m3/yr. All of the shallow groundwater was impacted by the reclaimed water, with the mixing proportion of reclaimed water ranging from 42% to 80 % in the dry season and from 20% to 86% in the wet season. Only one deep well, with proportions of 67% (dry season) and 28% (wet season), was impacted. TDS, EC, and major ions (Na, K, Cl, NH4-N, NO2-N, and NO3-N) were increased in the impacted wells.
Method of feeding particulate material to a fluidized bed
Borio, Richard W.; Goodstine, Stephen L.
1984-01-01
A centrifugal spreader type feeder that supplies a mixture of particulate limestone and coal to the top of a fluidized bed reactor having a flow of air upward therethrough. Large particles of particulate matter are distributed over the upper surface of the bed to utilize the natural mixing within the bed, while fine particles are adapted to utilize an independent feeder that separates them from the large particles and injects them into the bed.
40 CFR 266.80 - Applicability and requirements.
Code of Federal Regulations, 2014 CFR
2014-07-01
... . . . (1) Will be reclaimed through regeneration (such as by electrolyte replacement) are exempt from 40.... (2) Will be reclaimed other than through regeneration generate, collect, and/or transport these... regeneration store these batteries but you aren't the reclaimer are exempt from 40 CFR parts 262 (except for...
40 CFR 266.80 - Applicability and requirements.
Code of Federal Regulations, 2012 CFR
2012-07-01
... . . . (1) Will be reclaimed through regeneration (such as by electrolyte replacement) are exempt from 40.... (2) Will be reclaimed other than through regeneration generate, collect, and/or transport these... regeneration store these batteries but you aren't the reclaimer are exempt from 40 CFR parts 262 (except for...
40 CFR 266.80 - Applicability and requirements.
Code of Federal Regulations, 2011 CFR
2011-07-01
... . . . (1) Will be reclaimed through regeneration (such as by electrolyte replacement) are exempt from 40.... (2) Will be reclaimed other than through regeneration generate, collect, and/or transport these... regeneration store these batteries but you aren't the reclaimer are exempt from 40 CFR parts 262 (except for...
40 CFR 266.80 - Applicability and requirements.
Code of Federal Regulations, 2013 CFR
2013-07-01
... . . . (1) Will be reclaimed through regeneration (such as by electrolyte replacement) are exempt from 40.... (2) Will be reclaimed other than through regeneration generate, collect, and/or transport these... regeneration store these batteries but you aren't the reclaimer are exempt from 40 CFR parts 262 (except for...
40 CFR 266.80 - Applicability and requirements.
Code of Federal Regulations, 2010 CFR
2010-07-01
... * * * (1) Will be reclaimed through regeneration (such as by electrolyte replacement) are exempt from 40.... (2) Will be reclaimed other than through regeneration generate, collect, and/or transport these... regeneration store these batteries but you aren't the reclaimer are exempt from 40 CFR parts 262 (except for...
Code of Federal Regulations, 2014 CFR
2014-07-01
... Digestion, and Mechanical Reclaimed Rubber Subcategory § 428.93 Effluent limitations guidelines representing... pollutants or pollutant properties, controlled by this section, and attributable to pan, dry digestion, and mechanical reclaimed rubber processes which are integrated with a wet digestion reclaimed rubber process...
Code of Federal Regulations, 2013 CFR
2013-07-01
... Digestion, and Mechanical Reclaimed Rubber Subcategory § 428.93 Effluent limitations guidelines representing... pollutants or pollutant properties, controlled by this section, and attributable to pan, dry digestion, and mechanical reclaimed rubber processes which are integrated with a wet digestion reclaimed rubber process...
Code of Federal Regulations, 2012 CFR
2012-07-01
... Digestion, and Mechanical Reclaimed Rubber Subcategory § 428.93 Effluent limitations guidelines representing... pollutants or pollutant properties, controlled by this section, and attributable to pan, dry digestion, and mechanical reclaimed rubber processes which are integrated with a wet digestion reclaimed rubber process...
New seed-cotton reclaimer for high speed roller gins
USDA-ARS?s Scientific Manuscript database
An experimental laboratory prototype reclaimer is being developed by the USDA-ARS in cooperation with Lummus Corporation. The objective of the project is to develop a seed-cotton reclaimer for high speed roller ginning that has a higher operational capacity and reduced seed loss in comparison to cur...
The Structure of Reclaiming Warehouse of Minerals at Open-Cut Mines with the Use Combined Transport
NASA Astrophysics Data System (ADS)
Ikonnikov, D. A.; Kovshov, S. V.
2017-07-01
In the article performed an analysis of ore reclaiming and overloading point characteristics at modern opencast mines. Ore reclaiming represents the most effective way of stability support of power-intensive and expensive technological dressing process, and, consequently, of maintenance of the optimal production and set-up parameters of extraction and quality of finished product. The paper proposed the construction of the warehouse describing the technology of its creation. Equipment used for the warehouse described in detail. All stages of development and operation was shown. Advantages and disadvantages of using mechanical shovel excavator and hydraulic excavator “backdigger” as a reloading and reclaiming equipment was compared. Ore reclaiming and overloading point construction at cyclical and continuous method of mining using a hydraulic excavator “backdigger” was proposed.
Lv, Xiao-Tong; Zhang, Xue; Du, Ye; Wu, Qian-Yuan; Lu, Yun; Hu, Hong-Ying
2017-11-15
Chlorinated reclaimed water is widely used for landscaping and recreational purposes, resulting in human exposure to toxic disinfection byproducts. Although the quality of chlorinated reclaimed water might be affected by sunlight during storage, the effects of solar light irradiation on the toxicity remain unknown. This study investigated the changes in cytotoxicity and total organic halogen (TOX) of chlorinated reclaimed water exposed to solar light. Irradiation with solar light for 12 h was found to significantly reduce the cytotoxicity of chlorinated reclaimed water by about 75%, with ultraviolet light being responsible for the majority of this reduction. Chlorine residual in reclaimed water tended to increase the cytotoxicity, and the synergy between solar light and free chlorine could not enhance the reduction of cytotoxicity. Adding hydroxyl radical scavengers revealed that the contribution of hydroxyl radical to cytotoxicity reduction was limited. Solar light irradiation concurrently reduced TOX. The low molecular weight (<1 kDa) fraction was the major contributor of cytotoxicity and TOX in chlorinated reclaimed water. Detoxification of the low molecular weight fraction by light irradiation was mainly a result of TOX dehalogenation, while detoxification of the high molecular weight (>1 kDa) fraction was probably caused by photoconversion from high toxic TOX to low toxic TOX. Copyright © 2017 Elsevier Ltd. All rights reserved.
Barker-Reid, Fiona; Fox, Ellen M; Faggian, Robert
2010-09-01
The purpose of this study was to investigate the occurrence of antibiotic resistance genes (ARGs) in water used for irrigation in the Werribee River Basin, Australia, including river water and reclaimed effluent water (reclaimed water). Samples of reclaimed water, collected over a one-year period, were screened for the occurrence of ARGs using PCR detection assays. The presence of ARGs in the reclaimed water samples were contrasted with that of water samples taken from the Werribee River Basin, collected over the same time period, from five points selected for varying levels of urban and agricultural impact. Of the 54 river water samples collected, 2 (4%), 2 (4%), 0 and 0 were positive for methicillin, sulfonamide, gentamicin and vancomycin-resistant genes, respectively, while 6 of 11 reclaimed water samples were positive for methicillin (9%) and sulfonamide (45%). The presence/absence of ARGs did not appear to correlate with other measured water quality parameters. The low detection of ARGs in river water indicates that, regardless of its poor quality, the river has not yet been severely contaminated with ARGs. The greater prevalence of ARGs in reclaimed water indicates that this important agricultural water source will need to be monitored into the future.
Leenheer, J.A.; Rostad, C.E.; Barber, L.B.; Schroeder, R.A.; Anders, R.; Davisson, M.L.
2001-01-01
The nature and chlorine reactivity of organic constituents in reclaimed water (tertiary-treated municipal wastewater) before, during, and after recharge into groundwater at the Montebello Forebay in Los Angeles County, CA, was the focus of this study. Dissolved organic matter (DOM) in reclaimed water from this site is primarily a mixture of aromatic sulfonates from anionic surfactant degradation, N-acetyl amino sugars and proteins from bacterial activity, and natural fulvic acid, whereas DOM from native groundwaters in the aquifer to which reclaimed water was recharged consists of natural fulvic acids. The hydrophilic neutral N-acetyl amino sugars that constitute 40% of the DOM in reclaimed water are removed during the first 3 m of vertical infiltration in the recharge basin. Groundwater age dating with 3H and 3He isotopes, and determinations of organic and inorganic C isotopes, enabled clear differentiation of recent recharged water from older native groundwater. Phenol structures in natural fulvic acids in DOM isolated from groundwater produced significant trihalomethanes (THM) and total organic halogen (TOX) yields upon chlorination, and these structures also were responsible for the enhanced SUVA and specific fluorescence characteristics relative to DOM in reclaimed water. Aromatic sulfonates and fulvic acids in reclaimed water DOM produced minimal THM and TOX yields.
DOE Office of Scientific and Technical Information (OSTI.GOV)
Englhard, M.; Klemp, C.; Behringer, M.
This study reports a method to reuse GaAs substrates with a batch process for thin film light emitting diode (TF-LED) production. The method is based on an epitaxial lift-off technique. With the developed reclaim process, it is possible to get an epi-ready GaAs surface without additional time-consuming and expensive grinding/polishing processes. The reclaim and regrowth process was investigated with a one layer epitaxial test structure. The GaAs surface was characterized by an atomic force microscope directly after the reclaim process. The crystal structure of the regrown In{sub 0.5}(Ga{sub 0.45}Al{sub 0.55}){sub 0.5}P (Q{sub 55}) layer was investigated by high resolution x-raymore » diffraction and scanning transmission electron microscopy. In addition, a complete TF-LED grown on reclaimed GaAs substrates was electro-optically characterized on wafer level. The crystal structure of the epitaxial layers and the performance of the TF-LED grown on reclaimed substrates are not influenced by the developed reclaim process. This process would result in reducing costs for LEDs and reducing much arsenic waste for the benefit of a green semiconductor production.« less
The report gives results of the full-scale demonstration of Limestone Injection Multistage Burner (LIMB) technology on the coal-fired, 105 MW, Unit 4 boiler at Ohio Edison's Edgewater Station. eveloped as a technology aimed at moderate levels of sulfur dioxide (SO2) and nitrogen ...
SURVEY OF FLUE GAS DESULFURIZATION SYSTEMS: ST. CLAIR STATION, DETROIT EDISON CO
The report gives results of a survey of the flue gas desulfurization (FGD) system retrofitted on Unit 6 of Detroit Edison Co.'s St. Clair Station. The experimental FGD system, which operated through a 2-month (October 1976-January 1977) demonstration program, utilized a limestone...
77 FR 16862 - Proposed Information Collection Request; Training, Training Plans, and Records
Federal Register 2010, 2011, 2012, 2013, 2014
2012-03-22
... shell dredging, sand, gravel, surface stone, surface clay, colloidal phosphate, and surface limestone... quality, utility, and clarity of the information to be collected; and Address the use of appropriate... requirements concerning the training and retraining of miners engaged in shell dredging or employed at sand...
Wu, Qian-Yuan; Shao, Yi-Ru; Wang, Chao; Sun, Yan; Hu, Hong-Ying
2014-03-01
The estrogenic endocrine disruptors in reclaimed water from domestic wastewater may induce health risks to human being, when reclaimed water is used for augmentation of drinking water unplannedly and indirectly. This study investigated changes in concentrations of estrone, estradiol, 17alpha-ethinyl estradiol, bisphenol A, nonylphenol and octylphenol in reclaimed water during the reuse of reclaimed water for augmentation to water source such as lakes and reservoir via river. Thereafter, health risk induced by estrogens during the resue of reclaimed water was evaluated. The concentration of estrogen in secondary effluent ranged 0.1-100 ng x L(-1). The highest concentrations of bisphenol A and nonylphenol reached up to 1-10 microg x L(-1). During the indirect reuse of reclaimed water as potable water, the dilution and degradation in river and lake, and the removal by drinking water treatment process could change the concentrations of estrogen. The non-carcinogenic risks of estrone, estradiol, bisphenol A, nonylphenol and octylphenol were lower than 1. When the hydraulic retention time of 17alpha-ethinyl estradiol (EE2) in lakes and reservoir was higher than 30 days, the non-carcinogenic risk of EE2 was lower than 1 in most cases. When the hydraulic retention time of EE2 in lakes and reservoir was less than 30 days and the percentages of reclaimed water in drinking water were higher than 50%, the non-carcinogenic risk induced by EE2 was higher than 1 in 20%-50% samples. This indicated that the risks of EE2 should be concerned.
An evaluation of woodland reclamation on strip-mined lands in east Texas
NASA Astrophysics Data System (ADS)
Gorsira, Bryan; Risenhoover, Ken L.
1994-09-01
We compared the composition and structural characteristics of reclaimed and native woody plant communities near Fairfield, Texas, to evaluate the effectiveness of woodland reclamation 3 11 years since establishment. Species composition, foliage density, canopy cover, and woody plant densities were recorded in plots randomly placed along transects bisecting blocks of reclaimed and native woodlands. During summer, vertical foliage densities at heights ≤2 m were similar among native and reclaimed areas. Foliage density and canopy cover declined in reclaimed blocks during winter, but remained relatively constant in native woodlands, where evergreens and vines were more common. Canopy cover was absent in reclaimed woodlands <6 years old but increased with age in 6 to 11-year-old blocks. These data indicated that approximately 27 years will be needed before trees in reclaimed blocks will achieve the stature of canopy trees in native woodlands. Reclaimed woodlands contained different woody plant species and had lower woody stem densities compared to native woodlands. On average, stem densities in reclaimed blocks were six times lower than densities in native woodlands. Comparisons with planting records indicate that survival of most commonly planted woody species was low. Only green ash (Fraxinus pennsylvanica), Russian oliver (Elaeagnus commutata), smooth sumac (Rhus glabra), and redbud (Cercis canadensis) had estimated survival rates >50%. Reclamation procedures used at Big Brown Mine (BBM) during 1981 1988 have not produced woodland habitats with vegetative characteristics comparable to premined woodlands and may not be providing the cover needed to encourage use by certain wildlife species. Procedures for improving woodland reclamation are recommended.
Barone, T L; Patts, J R; Janisko, S J; Colinet, J F; Patts, L D; Beck, T W; Mischler, S E
2016-01-01
Airborne coal dust mass measurements in underground bituminous coal mines can be challenged by the presence of airborne limestone dust, which is an incombustible dust applied to prevent the propagation of dust explosions. To accurately measure the coal portion of this mixed airborne dust, the National Institute for Occupational Safety and Health (NIOSH) developed a sampling and analysis protocol that used a stainless steel cassette adapted with an isokinetic inlet and the low temperature ashing (LTA) analytical method. The Mine Safety and Health Administration (MSHA) routinely utilizes this LTA method to quantify the incombustible content of bulk dust samples collected from the roof, floor, and ribs of mining entries. The use of the stainless steel cassette with isokinetic inlet allowed NIOSH to adopt the LTA method for the analysis of airborne dust samples. Mixtures of known coal and limestone dust masses were prepared in the laboratory, loaded into the stainless steel cassettes, and analyzed to assess the accuracy of this method. Coal dust mass measurements differed from predicted values by an average of 0.5%, 0.2%, and 0.1% for samples containing 20%, 91%, and 95% limestone dust, respectively. The ability of this method to accurately quantify the laboratory samples confirmed the validity of this method and allowed NIOSH to successfully measure the coal fraction of airborne dust samples collected in an underground coal mine.
Barone, T. L.; Patts, J. R.; Janisko, S. J.; Colinet, J. F.; Patts, L. D.; Beck, T. W.; Mischler, S. E.
2016-01-01
Airborne coal dust mass measurements in underground bituminous coal mines can be challenged by the presence of airborne limestone dust, which is an incombustible dust applied to prevent the propagation of dust explosions. To accurately measure the coal portion of this mixed airborne dust, the National Institute for Occupational Safety and Health (NIOSH) developed a sampling and analysis protocol that used a stainless steel cassette adapted with an isokinetic inlet and the low temperature ashing (LTA) analytical method. The Mine Safety and Health Administration (MSHA) routinely utilizes this LTA method to quantify the incombustible content of bulk dust samples collected from the roof, floor, and ribs of mining entries. The use of the stainless steel cassette with isokinetic inlet allowed NIOSH to adopt the LTA method for the analysis of airborne dust samples. Mixtures of known coal and limestone dust masses were prepared in the laboratory, loaded into the stainless steel cassettes, and analyzed to assess the accuracy of this method. Coal dust mass measurements differed from predicted values by an average of 0.5%, 0.2%, and 0.1% for samples containing 20%, 91%, and 95% limestone dust, respectively. The ability of this method to accurately quantify the laboratory samples confirmed the validity of this method and allowed NIOSH to successfully measure the coal fraction of airborne dust samples collected in an underground coal mine. PMID:26618374
Code of Federal Regulations, 2013 CFR
2013-07-01
... CATEGORY Pan, Dry Digestion, and Mechanical Reclaimed Rubber Subcategory § 428.92 Effluent limitations... pan, dry digestion, and mechanical reclaimed rubber processes which are integrated with a wet digestion reclaimed process, which may be discharged by a point source subject to the provisions of this...
Code of Federal Regulations, 2012 CFR
2012-07-01
... CATEGORY Pan, Dry Digestion, and Mechanical Reclaimed Rubber Subcategory § 428.92 Effluent limitations... pan, dry digestion, and mechanical reclaimed rubber processes which are integrated with a wet digestion reclaimed process, which may be discharged by a point source subject to the provisions of this...
Code of Federal Regulations, 2014 CFR
2014-07-01
... CATEGORY Pan, Dry Digestion, and Mechanical Reclaimed Rubber Subcategory § 428.92 Effluent limitations... pan, dry digestion, and mechanical reclaimed rubber processes which are integrated with a wet digestion reclaimed process, which may be discharged by a point source subject to the provisions of this...
Chlorinolysis reclaims rubber of waste tires
NASA Technical Reports Server (NTRS)
Dufresne, E. R.; Tervet, J. H.; Hull, G. G.
1981-01-01
Process reclaims rubber and reduces sulfur content by using chlorine gas to oxidize sulfur bonds in preference to other bonds. Rubber does not have poor hysteresis and abrasion resistance like conventionally reclaimed rubber and is suitable for premium radial tires. Chlorinated rubber is less susceptible to swelling by oils and may be used as paint ingredient.
40 CFR 421.244 - Standards of performance for new sources.
Code of Federal Regulations, 2011 CFR
2011-07-01
.../kg (pounds per million pounds) of slag input to reclaim process Chromium (total) 5.653 2.313 Copper... range of 7.5 to 10.0 at all times. (b) Acid reclaim leaching filtrate. NSPS for the Secondary Nickel... all times. (c) Acid reclaim leaching belt filter backwash. NSPS for the Secondary Nickel Subcategory...
ERIC Educational Resources Information Center
Eckhoff, Angela; Spearman, Mindy
2009-01-01
Introducing reclaimed materials into the art classroom provides students with unique opportunities to connect ordinary, discarded objects with unique, personal artistic creations. In an effort to better understand this connection, this article explores existing pedagogical precedents that support the role of the inclusion of reclaimed materials in…
Monitoring requirements for groundwaters under the influence of reclaimed water.
Fox, P
2001-07-01
Monitoring groundwaters under the influence of reclaimed water must consider the major constituents of concern in reclaimed water. This research focused on the fate of dissolved organic carbon and nitrogen species at field sites located throughout the Southwestern United States. A watershed approach was developed to predict the fate of dissolved organic carbon as a function of the drinking water dissolved organic carbon concentration and the total dissolved solids concentration in the reclaimed water. Extensive characterization of the dissolved organic carbon recovered from groundwaters under the influence of reclaimed water was done. With the exception of fluorescence spectroscopy, the dissolved organic carbon present in effluent organic matter was similar in structure, character and reactivity as compared to natural organic matter. Evidence for sustainable nitrogen removal mechanisms during groundwater recharge with reclaimed water was obtained. The autotrophic reaction between ammonia and nitrate appears to a mechanism for the removal nitrogen in a carbon-depleted environment. The monitoring tools and methodologies developed in this research can be used to assure protection of public health and determine the sustainability of indirect potable reuse projects.
Direct condensation refrigerant recovery and restoration system
DOE Office of Scientific and Technical Information (OSTI.GOV)
Grant, D.C.H.
1992-03-10
This patent describes a refrigerant recovery and purification system for removing gaseous refrigerant from a disabled refrigeration unit, cleaning the refrigerant of contaminants, and converting the gaseous refrigerant to a liquid state for storage. It comprises a low pressure inlet section; a high pressure storage section; the low pressure inlet section comprising: an oil and refrigerant gas separator, including a separated oil removal means, first conduit means for connecting an inlet of the separator to the disabled refrigerant unit, a slack-sided accumulator, second conduit means connecting the separator to the slack-sided accumulator, a reclaim condenser, third conduit means connecting themore » separator and the reclaim condenser in series, an evaporator coil in the reclaim condenser connectable to a conventional operating refrigeration system for receiving a liquid refrigerant under pressure for expansion therein, the evaporator coil forming a condensing surface for condensing the refrigerant gas at near atmospheric pressure in the condenser, a liquid receiver, a reclaimed refrigerant storage tank, fourth conduit means further connecting the liquid receiver in series with the reclaim condenser, downstream thereof, means between the reclaim condenser and the liquid receiver.« less
O'Brien, Erin L; Dawson, Russell D
2016-05-15
Studies assessing impacts of industrial activities on wildlife typically examine population- or community-level responses. However, changes in measures such as species abundance or diversity are driven by cumulative responses of individuals to disturbance, and may take time to detect. Quantifying individual responses could allow us to foresee and mitigate future population declines resulting from industrial activities, while providing ecologically informative indices to assess quality of reclaimed land. We examined life-history and phenotypic traits of mountain bluebirds (Sialia currucoides) and tree swallows (Tachycineta bicolor) breeding on reclaimed copper mine lands in Canada over two years in comparison to a nearby undisturbed reference area. Bluebirds feed on terrestrial invertebrates, whereas swallows feed on adult forms of insects with aquatic larvae, allowing us to assess quality of both reclaimed terrestrial and aquatic systems as habitat for insectivorous birds. Supplemental feeding of bluebirds also was used to experimentally assess nutritional limitation of birds feeding on terrestrial invertebrates. Bluebirds on reclaimed land initiated clutches later, and in one year had lower fledging success compared to birds on the reference area. Tree swallows also bred later in the season on reclaimed land, but were otherwise comparable to or exceeded performance of birds on the reference area. Annual differences in responses of nestling bluebirds on the mine to supplemental feeding revealed an apparent switch in life-history strategy of parents between years, from brood reduction to brood survival, suggesting greater annual fluctuations in ecological conditions within terrestrial systems on reclaimed land. Sex differences in response of nestling bluebirds to food supplementation additionally suggested high within-brood competition for food on reclaimed land. We suggest that measures of avian life-history and phenotypic traits, particularly when assessed over multiple years using experimental approaches such as food supplementation, are informative and sensitive indices of the health of reclaimed terrestrial and aquatic systems. Copyright © 2016 Elsevier B.V. All rights reserved.
NASA Astrophysics Data System (ADS)
El-Hawary, Moetaz; Ahmed, Mahmoud
2017-09-01
The utilization of some type of cheap filler as partial cement replacement is an effective way of improving concrete sustainability. With the recent trends to reduce water to cement ratio and improve compaction, there is no enough space or water for complete hydration of cement. This means that actually, a portion of mixed cement acts as expensive filler. Replacing this portion with cheaper filler that requires less energy to produce is, therefore, beneficial. Crushed limestone is the most promising filler. This work is to investigate the effect of the amount of limestone fillers on the sustainability and the fresh and mechanical properties of the resulting concrete. A rich mix is designed with a low water/cement ratio of 0.4. Lime is introduced as a replacement percentage of cement. Ratios of 0, 10, 20 and 30% were used. Slump, compressive strength, specific gravity and water absorption are evaluated for every mix. In addition, the effect of the amount of lime on the residual strength of concrete subjected to elevated temperatures is also investigated. Samples are subjected to six different temperature stations of 20, 100, 200, 300, 500 and 700°C for six hours before being cooled and subsequently tested for compressive strength and specific gravity. Sustainability of the tested mixes is evaluated through reductions in the emitted carbon dioxide, energy and reduction in cost. Based on the annual use of concrete in Kuwait, the sustainability benefits resulting from the use of limestone filler in Kuwait are evaluated and assessed. The paper is concluded with the recommendation of the use of 15% limestone filler as partial cement replacement where the properties and the behavior under high temperature of the resulting concrete are almost the same as those of conventional concrete with considerable cost and sustainability benefits.
Harvey, Ronald W.; Metge, David W.; Shapiro, Allen M.; Renken, Robert A.; Osborn, Christina L.; Ryan, Joseph N.; Cunningham, Kevin J.; Landkamer, Lee L.
2008-01-01
The vulnerability of a municipal well in the Northwest well field in southeastern Florida to potential contamination by Cryptosporidium parvum oocysts was assessed in a large‐scale, forced‐gradient (convergent) injection and recovery test. The field study involved a simultaneous pulse introduction of a nonreactive tracer (SF6, an inert gas) and oocyst‐sized (1.6, 2.9, and 4.9 μm diameter) carboxylated polystyrene microspheres into karst limestone of the Biscayne aquifer characterized by a complex triple (matrix, touching‐vug, and conduit) porosity. Fractional recoveries 97 m down gradient were inversely related to diameter and ranged from 2.9% for the 4.9 μm microspheres to 5.8% for 1.6 μm microspheres. Their centers of mass arrived at the pumping well approximately threefold earlier than that of the nonreactive tracer SF6 (gas), underscoring the need for use of colloid tracers and field‐scale tracer tests for these kinds of evaluations. In a modified triaxial cell using near in situ chemical conditions, 2.9 and 4.9 μm microspheres underestimated by fourfold to sixfold the attachment potential of the less electronegative 2.9–4.1 μm oocysts in the matrix porosity of limestone core samples. The field and laboratory results collectively suggested that it may take 200–300 m of transport to ensure even a 1‐log unit removal of oocysts, even though the limestone surfaces exhibited a substantive capability for their sorptive removal. The study further demonstrated the utility of microspheres as oocyst surrogates in field‐scale assessments of well vulnerability in limestone, provided that differences in attachment behaviors between oocysts and microspheres are taken into account.
Code of Federal Regulations, 2014 CFR
2014-07-01
..., Recycling and/or Reclaim Equipment B1 Appendix B1 to Subpart F of Part 82 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED) PROTECTION OF STRATOSPHERIC OZONE Recycling... Refrigerant Recovery, Recycling and/or Reclaim Equipment This appendix is based on the Air-Conditioning and...
Code of Federal Regulations, 2013 CFR
2013-07-01
..., Recycling and/or Reclaim Equipment B1 Appendix B1 to Subpart F of Part 82 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED) PROTECTION OF STRATOSPHERIC OZONE Recycling... Refrigerant Recovery, Recycling and/or Reclaim Equipment This appendix is based on the Air-Conditioning and...
Code of Federal Regulations, 2012 CFR
2012-07-01
..., Recycling and/or Reclaim Equipment B1 Appendix B1 to Subpart F of Part 82 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED) PROTECTION OF STRATOSPHERIC OZONE Recycling... Refrigerant Recovery, Recycling and/or Reclaim Equipment This appendix is based on the Air-Conditioning and...
Bohrer, Stefanie L; Limb, Ryan F; Daigh, Aaron L; Volk, Jay M; Wick, Abbey F
2017-03-01
Rangelands are described as heterogeneous, due to patterning in species assemblages and productivity that arise from species dispersal and interactions with environmental gradients and disturbances across multiple scales. The objectives of rangeland reclamation are typically vegetation establishment, plant community productivity, and soil stability. However, while fine-scale diversity is often promoted through species-rich seed mixes, landscape heterogeneity and coarse-scale diversity are largely overlooked. Our objectives were to evaluate fine and coarse-scale vegetation patterns across a 40-year reclamation chronosequence on reclaimed surface coalmine lands. We hypothesized that both α-diversity and β-diversity would increase and community patch size and species dissimilarity to reference sites would decrease on independent sites over 40 years. Plant communities were surveyed on 19 post-coalmine reclaimed sites and four intact native reference sites in central North Dakota mixed-grass prairie. Our results showed no differences in α or β-diversity and plant community patch size over the 40-year chronosequence. However, both α-diversity and β-diversity on reclaimed sites was similar to reference sites. Native species establishment was limited due to the presence of non-native species such as Kentucky bluegrass (Poa pratensis) on both the reclaimed and reference sites. Species composition was different between reclaimed and reference sites and community dissimilarity increased on reclaimed sites over the 40-year chronosequence. Plant communities resulting from reclamation followed non-equilibrium succession, even with consistent seeds mixes established across all reclaimed years. This suggests post-reclamation management strategies influence species composition outcomes and land management strategies applied uniformly may not increase landscape-level diversity.
Groundwater recharge with reclaimed municipal wastewater: health and regulatory considerations.
Asano, Takashi; Cotruvo, Joseph A
2004-04-01
Groundwater recharge with reclaimed municipal wastewater presents a wide spectrum of technical and health challenges that must be carefully evaluated prior to undertaking a project. This review will provide a discussion of groundwater recharge and its management with special reference to health and regulatory aspects of groundwater recharge with reclaimed municipal wastewater. At present, some uncertainties with respect to health risk considerations have limited expanding use of reclaimed municipal wastewater for groundwater recharge, especially when a large portion of the groundwater contains reclaimed wastewater that may affect the domestic water supply. The proposed State of California criteria for groundwater recharge are discussed as an illustration of a cautious approach. In addition, a summary is provided of the methodology used in developing the World Health Organization's Guidelines for Drinking Water Quality to illustrate how numerical guideline values are generated for contaminants that may be applicable to groundwater recharge.
Implications of Transitioning from De Facto to Engineered Water Reuse for Power Plant Cooling.
Barker, Zachary A; Stillwell, Ashlynn S
2016-05-17
Thermoelectric power plants demand large quantities of cooling water, and can use alternative sources like treated wastewater (reclaimed water); however, such alternatives generate many uncertainties. De facto water reuse, or the incidental presence of wastewater effluent in a water source, is common at power plants, representing baseline conditions. In many cases, power plants would retrofit open-loop systems to cooling towers to use reclaimed water. To evaluate the feasibility of reclaimed water use, we compared hydrologic and economic conditions at power plants under three scenarios: quantified de facto reuse, de facto reuse with cooling tower retrofits, and modeled engineered reuse conditions. We created a genetic algorithm to estimate costs and model optimal conditions. To assess power plant performance, we evaluated reliability metrics for thermal variances and generation capacity loss as a function of water temperature. Applying our analysis to the greater Chicago area, we observed high de facto reuse for some power plants and substantial costs for retrofitting to use reclaimed water. Conversely, the gains in reliability and performance through engineered reuse with cooling towers outweighed the energy investment in reclaimed water pumping. Our analysis yields quantitative results of reclaimed water feasibility and can inform sustainable management of water and energy.
Chiou, Ren-Jie
2008-07-01
The reuse of treated municipal wastewater should be one of the new water resource target areas. The suitability of the reuse of wastewater for agricultural irrigation has to consider health risk, soil contamination and the influence of the reclaimed water on crop growth. In this work the aim is to use quantitative risk analysis to assess the health effects related to reclaimed water quality and to calculate the loading capacity of reclaimed wastewater in terms of the heavy metal accumulation. The results of chemical risk assessment show there would be slightly significant health risk and what risk there is can be limited within an acceptable level. The following exposure pathway: reclaimed water-->surface water-->fish (shellfish)-->human, and arsenic risks are of more concern. In terms of reuse impact in soil contamination, the most possible heavy metal caused accumulation is arsenic. The irrigative quantity has to reach 13,300 m(3)/ha to cause arsenic accumulation. However, only 12,000 m(3)/ha is essential for rice paddy cropland. The high total nitrogen of reclaimed water from secondary treatment makes it unfavorable for crop growth. The recommended dilution ratio is 50% during the growth period and 25% during the maturity period.
DOE Office of Scientific and Technical Information (OSTI.GOV)
Friedlander, J.D.
1995-09-01
Reestablishment of western snowberry (Symphoricarpos occidentalis Hook.) was attempted on surface mined land reclaimed to mixed grass prairie in western North Dakota. Undisturbed shrub patches were segregated and removed with tractor scrapers in 1989. These were directly replaced in two low drainage landscape sites, less than one hectare each, on reclaimed land. No seeding, herbicide spraying, or grazing was conducted on reclaimed sites. Stem counts and frequency were analyzed yearly. Regression correlations were calculated for average stems/0.25m{sup 2}vs. April-July precipitation (r{sup 2} = 0.90), vs. October-July precipitation (r{sup 2} = 0.97), and vs. age of reclaimed stand (r{sup 2} =more » 0.58). Regression correlations were also calculated for frequency vs. April-July precipitation (r{sup 2} = 0.80), vs. October-July precipitation (r{sup 2} = 0.88), and vs. age of reclaimed stand (r{sup 2} = 0.58). October-July precipitation had the greatest impact on stand establishment and success. Special consideration should be given to site location and moisture conditions when transplanting western snowberry. Bond liability period length should be based on moisture conditions, not age of the stand.« less
Cretaceous planktic foraminiferal biostratigraphy of the Calera Limestone, Northern California, USA
Sliter, W.V.
1999-01-01
The Calera Limestone is the largest, most stratigraphically extensive limestone unit of oceanic character included in the Franciscan Complex of northern California. The aim of this paper is to place the Calera Limestone at its type locality (Rockaway Beach, Pacifica) in a high-resolution biostratigraphy utilizing planktic foraminifers studied in thin section. A section, about 110 m-thick, was measured from the middle thrust slice exposed by quarrying on the southwest side of Calera Hill at Pacifica Quarry. Lithologically, the section is divided in two units; a lower unit with 73 m of black to dark-grey limestone, black chert and tuff, and an upper unit with 36.8 m of light-grey limestone and medium-grey chert. Two prominent black-shale layers rich in organic carbon occur 11 m below the top of the lower black unit and at the boundary with overlying light-grey unit, yielding a total organic content (TOC) of 4.7% and 1.8% t.w., respectively. The fossiliferous Calera Limestone section measured at Pacifica Quarry, from the lower black shale, contains eleven zones and three subzones that span approximately 26 m.y. from the early Aptian to the late Cenomanian. The zones indentified range from the Globigerinelloides blowi Zone to the Dicarinella algeriana Subzone of the Rotalipora cushmani Zone. Within this biostratigraphic interval, the Ticinella bejaouaensis and Hedbergella planispira Zones at the Aptian/Albian boundary are missing as are the Rotalipora subticinensis Subzone of the Biticinella breggiensis Zone and the overlying Rotalipora ticinensis Zone in the late Albian owing both to low-angle thrust faulting and to unconformities. The abundance and preservation of planktic foraminifers are poor in the lower part and improve only within the upper G. algerianus Zone. The faunal relationship indicate that the lower black shale occurs in the upper part of the G. blowi Zone and correlates with the Selli Event recognized at global scale in the early Aptian. The upper black shale occurs at or near the boundary between the G. ferreolensis and G. algerianus Zone in the late Aptian. This black layer, or Thalmann Event as named here, seems to represent the sedimentary expression, at the scale of Permanente Terrane, of a global perturbation of the carbon cycle.
Rubiano, María-Eugenia; Agulló-Barceló, Míriam; Casas-Mangas, Raquel; Jofre, Juan; Lucena, Francisco
2012-05-01
Need, coupled with advances in water treatment technology, is motivating a growing interest in augmenting drinking water supplies with reclaimed water. Using reclaimed water to increase the flow of the Llobregat River upstream the water catchment site of the complex multi-step drinking water treatment plant of Sant Joan Despí has been considered. The impact of reclaimed water discharges on the load of E. coli, spores of sulphite-reducing clostridia, somatic coliphages, cytopathogenic enteroviruses, and total and infectious Cryptosporidium oocysts in the Llobregat River water was assessed to gain information for funded decisions in potential future emergencies. Enterovirus and Cryptosporidium oocysts were concentrated from great water volumes prior to enumeration, whereas indicators were enumerated directly from the samples. Both indicators and pathogens were enumerated by cultural techniques that determine infectious microbes. Densities of both indicators and pathogens in reclaimed water, despite that it was disinfected by UV irradiation alone or by UV irradiation plus chlorination, were significantly lower than their densities in the river water, both upstream and downstream the reclaimed water release site in the river. Results gathered indicate that discharging reclaimed water into the river does not increment the load of indicators and pathogens of the river water. Then, in emergency situations due to severe water shortages after prolonged droughts, at least from the infectious diseases point of view, the risks of augmenting drinking water supplies with reclaimed water can be satisfactorily and safely managed.
Differences in dissolved organic matter between reclaimed water source and drinking water source.
Hu, Hong-Ying; Du, Ye; Wu, Qian-Yuan; Zhao, Xin; Tang, Xin; Chen, Zhuo
2016-05-01
Dissolved organic matter (DOM) significantly affects the quality of reclaimed water and drinking water. Reclaimed water potable reuse is an effective way to augment drinking water source and de facto reuse exists worldwide. Hence, when reclaimed water source (namely secondary effluent) is blended with drinking water source, understanding the difference in DOM between drinking water source (dDOM) and reclaimed water source (rDOM) is essential. In this study, composition, transformation, and potential risk of dDOM from drinking water source and rDOM from secondary effluent were compared. Generally, the DOC concentration of rDOM and dissolved organic nitrogen (DON) content in reclaimed water source were higher but rDOM exhibited a lower aromaticity. Besides, rDOM comprises a higher proportion of hydrophilic fractions and more low-molecular weight compounds, which are difficult to be removed during coagulation. Although dDOM exhibited higher specific disinfection byproducts formation potential (SDBPFP), rDOM formed more total disinfection byproducts (DBPs) during chlorination including halomethanes (THMs) and haloacetic acids (HAAs) due to high DOC concentration. Likewise, in consideration of DOC basis, rDOM contained more absolute assimilable organic carbon (AOC) despite showing a lower specific AOC (normalized AOC per unit of DOC). Besides, rDOM exhibited higher biotoxicity including genotoxicity and endocrine disruption. Therefore, rDOM presents a greater potential risk than dDOM does. Reclaimed water source needs to be treated carefully when it is blended with drinking water source. Copyright © 2015. Published by Elsevier B.V.
Energy-efficient regenerative liquid desiccant drying process
Ko, Suk M.; Grodzka, Philomena G.; McCormick, Paul O.
1980-01-01
This invention relates to the use of desiccants in conjunction with an open oop drying cycle and a closed loop drying cycle to reclaim the energy expended in vaporizing moisture in harvested crops. In the closed loop cycle, the drying air is brought into contact with a desiccant after it exits the crop drying bin. Water vapor in the moist air is absorbed by the desiccant, thus reducing the relative humidity of the air. The air is then heated by the used desiccant and returned to the crop bin. During the open loop drying cycle the used desiccant is heated (either fossil or solar energy heat sources may be used) and regenerated at high temperature, driving water vapor from the desiccant. This water vapor is condensed and used to preheat the dilute (wet) desiccant before heat is added from the external source (fossil or solar). The latent heat of vaporization of the moisture removed from the desiccant is reclaimed in this manner. The sensible heat of the regenerated desiccant is utilized in the open loop drying cycle. Also, closed cycle operation implies that no net energy is expended in heating drying air.
NASA Astrophysics Data System (ADS)
Mali, Manoj N.; Arakh, Amar A.; Dubey, K. A.; Mhaske, S. T.
2017-02-01
Utilization of waste from tire industry as reclaimed tire rubber (RTR) by formation of blends with high density polyethylene (HDPE) is great area to be focused. Enhancement of properties by the addition of triallyl cyanurate (TAC) as a co-agent with 1%, 3% and 5% to blend of HDPE 50 wt% and RTR 50 wt% in presence of gamma irradiation curing were investigated. Specifically, mechanical and thermal properties were studied as a function of amount of TAC and gamma irradiation dose in range of 50-200 kGy. The resultant blends were evaluated for the values of impact strength, gel content, thermal stability, tensile properties, rheological properties and morphological properties with increasing irradiation dosage and TAC loading. The mechanical properties tensile strength, hardness, impact strength of blend containing 3% of TAC were substantially increased with increasing irradiation dosage up to 150 KGy. Rheological analysis has shown increase in viscosity with increase in TAC loading up to 3% and 150 KGy irradiation dosages. 3% loading of TAC lead to better set of properties with150 KGy gamma irradiation dosage.
Evaluation of steel slag coarse aggregate in hot mix asphalt concrete.
Ahmedzade, Perviz; Sengoz, Burak
2009-06-15
This paper presents the influences of the utilization of steel slag as a coarse aggregate on the properties of hot mix asphalt. Four different asphalt mixtures containing two types of asphalt cement (AC-5; AC-10) and coarse aggregate (limestone; steel slag) were used to prepare Marshall specimens and to determine optimum bitumen content. Mechanical characteristics of all mixtures were evaluated by Marshall stability, indirect tensile stiffness modulus, creep stiffness, and indirect tensile strength tests. The electrical sensitivity of the specimens were also investigated in accordance with ASTM D257-91. It was observed that steel slag used as a coarse aggregate improved the mechanical properties of asphalt mixtures. Moreover, volume resistivity values demonstrated that the electrical conductivity of steel slag mixtures were better than that of limestone mixtures.
Blome, C.D.; Reed, K.M.
1993-01-01
Destruction of radiolarians during both diagenesis and HF processing severely reduces faunal abundance and diversity and affects the taxonomic and biostratigraphic utility of chert residues. The robust forms that survive the processing represent only a small fraction of the death assemblage, and delicate skeletal structures used for species differentiation, are either poorly preserved or dissolved in many coeval chert residues. First and last occurrences of taxa in chert sequences are likely to be coarse approximations of their true stratigraphic ranges. Precise correlation is difficult between biozonations based solely on index species from cherts and those constructed from limestone faunas. Careful selection of samples in sequence, use of weaker HF solutions, and study of both chert and limestone faunas should yield better biostratigraphic information. -from Authors
Gupta Choudhury, Shreyasi; Yaduvanshi, N P S; Chaudhari, S K; Sharma, D R; Sharma, D K; Nayak, D C; Singh, S K
2018-02-05
The ever shrinking agricultural land availability and the swelling demand of food for the growing population fetch our attention towards utilizing partially reclaimed sodic soils for cultivation. In the present investigation, we compared six treatments, like control (T1), existing farmers' practice (T2), balanced inorganic fertilization (T3) and combined application of green gram (Vigna radiate) with inorganic NPK (T4), green manure (Sesbania aculeate) with inorganic NPK (T5), and farmyard manure with inorganic NPK (T6), to study the influence of nutrient management on soil organic carbon sequestration and soil fertility under long-term rice-wheat cropping system along with its productivity in gypsum-amended partially reclaimed sodic soils of semi-arid sub-tropical Indian climate. On an average, combined application of organics along with fertilizer NPK (T4, T5, and T6) decreased soil pH, ESP, and BD by 3.5, 13.0, and 6.7% than FP (T2) and 3.7, 12.5, and 6.7%, than balanced inorganic fertilizer application (T3), respectively, in surface (0-20 cm). These treatments (T4, T5, and T6) also increased 14.1% N and 19.5% P availability in soil over the usual farmers' practice (FP) with an additional saving of 44.4 and 27.3% fertilizer N and P, respectively. Long-term (6 years) incorporation of organics (T4, T5, and T6) sequestered 1.5 and 2.0 times higher soil organic carbon as compared to the balanced inorganic (T3) and FP (T2) treatments, respectively. The allocation of soil organic carbon into active and passive pools determines its relative susceptibility towards oxidation. The lower active to passive ratio (1.63) in FYM-treated plots along with its potentiality of higher soil organic carbon (SOC) sequestration compared to the initial stock proved its acceptability for long-term sustenance under intensive cropping even in partially reclaimed sodic soils. Among all the treatments, T4 yielded the maximum from second year onwards. Moreover, after 6 years of continuous cultivation, the observed EWY (2011-2012) was found to be 41.9 and 33.1% higher in T4 as compared to FP (T2) and T3, respectively. Thus, for maintaining higher yield coupled with improved SOC sequestration and nutrient availability, T4 followed by T6 treatments would be the suitable options for long-term intensive rice-wheat system in partially reclaimed sodic soils of northern India.
DOE Office of Scientific and Technical Information (OSTI.GOV)
King, N.R.
1994-04-01
The West Franklin Limestone in the subsurface of Webster and Union Counties, Kentucky includes 7.5--18m of strata deposited during portions of four depositional cycles in the latest Desmoinesian and earliest Missourian (Pennsylvanian). These cycles began with marine flooding and deposition of limestone, followed by progradation of siliciclastics in three of the four cycles, and ended with emergence. The basal West Franklin is micritic limestone (0.5--3m) that rests on rooted mudstone. Overlying the limestone are siliciclastics (1.5--7m) dominated by red and green claystone that is rooted at the top. Next is a middle limestone zone that includes either a paleokarsted micriticmore » limestone, or a thin bioclastic micritic limestone bed associated with phosphatic shale and locally a second bioclastic micritic limestone. Above that is another siliciclastic interval (4--9m) capped by rooted mudstone and locally a thin coal. The overlying micritic limestone (1.5--2.5m) marks the top of the West Franklin. Depositional events included: (1) marine flooding of an emergent shelf producing the basal limestone; (2) progradation of siliciclastics followed by emergence and paleosol development; (3) marine flooding producing a second limestone; (4) emergence and karstification of erosional remnants of the second limestone; (5) renewed marine flooding depositing shell hash'' limestones and phosphatic shale; (6) progradation of siliciclastics culminating in emergency; and (7) marine flooding producing the upper limestone. Thus, two flooding-emergence cycles are represented by the middle limestone zone. The second, locally-developed shell-hash'' limestone in the middle zone was deposited during the regressive phase of a depositional cycle. All of the other limestones were deposited during transgression.« less
Hyland, Katherine C; Blaine, Andrea C; Dickenson, Eric R V; Higgins, Christopher P
2015-10-01
Contaminants of emerging concern present in domestic waste streams include a highly diverse group of potentially biologically active compounds that can be detected at trace levels in wastewater. Concerns about potential uptake into crops arise when reclaimed water is used in food crop production. The present study investigated how 9 contaminants of emerging concern in reclaimed water are taken up into edible portions of two food crops. Two flame retardant chemicals, tris(1-chloro-2-propyl) phosphate (TCPP) and tris(2-chloroethyl) phosphate (TCEP) and several polar pharmaceuticals (carbamazepine, diphenhydramine, sulfamethoxazole, and trimethoprim) accumulated in a linear, concentration-dependent manner in lettuce (Lactuca sativa) irrigated with reclaimed water, suggesting passive uptake of both neutral and ionizable chemical contaminants in lettuce. Furthermore, concentration-dependent accumulation of TCEP and TCPP from reclaimed water was also observed in strawberry fruits (Fragaria ananassa). Collectively, these data suggest that highly polar or charged contaminants can be taken up by crops from water bearing contaminants of emerging concern and can be accumulated in the edible portions. Using these data, however, estimates of human exposure to these contaminants from reclaimed water food crop accumulation suggest that exposure to the contaminants of emerging concern examined in the present study is likely substantially lower than current exposure guidelines. © 2015 SETAC.
Kulkarni, Prachi; Olson, Nathan D.; Raspanti, Greg A.; Rosenberg Goldstein, Rachel E.; Gibbs, Shawn G.; Sapkota, Amir; Sapkota, Amy R.
2017-01-01
Reclaimed water has emerged as a potential irrigation solution to freshwater shortages. However, limited data exist on the persistence of antibiotics in reclaimed water used for irrigation. Therefore, we examined the fate of nine commonly-used antibiotics (ampicillin, azithromycin, ciprofloxacin, linezolid, oxacillin, oxolinic acid, penicillin G, pipemidic acid, and tetracycline) in differentially treated wastewater and reclaimed water from two U.S. regions. We collected 72 samples from two Mid-Atlantic and two Midwest treatment plants, as well as one Mid-Atlantic spray irrigation site. Antibiotic concentrations were measured using liquid-chromatography- tandem mass spectrometry. Data were analyzed using Mann-Whitney-Wilcoxon tests and Kruskal Wallis tests. Overall, antibiotic concentrations in effluent samples were lower than that of influent samples. Mid-Atlantic plants had similar influent but lower effluent antibiotic concentrations compared to Midwest plants. Azithromycin was detected at the highest concentrations (of all antibiotics) in influent and effluent samples from both regions. For most antibiotics, transport from the treatment plant to the irrigation site resulted in no changes in antibiotic concentrations, and UV treatment at the irrigation site had no effect on antibiotic concentrations in reclaimed water. Our findings show that low-level antibiotic concentrations persist in reclaimed water used for irrigation; however, the public health implications are unclear at this time. PMID:28635638
Aramaki, T; Sugimoto, R; Hanaki, K; Matsuo, T
2001-01-01
The appropriate type of reclaimed wastewater reuse system in each area of Tokyo was evaluated from the aspect of economic efficiency, using a GIS-based water balances model. The following four reclaimed wastewater reuse systems and conventional waterworks and sewerage system were evaluated; "Rain water storage and use system", "Onsite wastewater treatment and reuse system", "Sewage treatment and reuse at an intermediate point on the sewer pipe" and "Treated water supply system in sewage treatment plant". In the case that we install them to office and residential buildings, the supplied volume by reclaimed wastewater reuse systems is 693 thousands m3/d, this corresponds to 15% of total water demand in the area. Furthermore, the effects of the following scenarios brought about by technological innovation in water treatment were investigated; the case that flush water in toilet and wastewater from kitchen are also available as source in a "onsite wastewater treatment and reuse system" and the case that reclaimed water is used for laundering in residential buildings. When reclaimed water is used for laundering in residential buildings, the supplied volume by these systems increases to 814 thousand m3/d in the case that these systems are installed to office and residential buildings.
Lin, Deng-Fong; Luo, Huan-Lin; Lin, Kuo-Liang; Liu, Zhe-Kun
2017-07-01
Applying sewage sludge ash (SSA) to produce reclaimed tiles is a promising recycling technology in resolving the increasing sludge wastes from wastewater treatment. However, performance of such reclaimed tiles is inferior to that of original ceramic tiles. Many researchers have therefore tried adding various industrial by-products to improve reclaimed tile properties. In this study, multiple materials including waste glass and waste foundry sand (WFS) were added in an attempt to improve physical and mechanical properties of reclaimed tiles with SSA. Samples with various combinations of clay, WFS, waste glass and SSA were made with three kiln temperatures of 1000°C, 1050°C, and 1100°C. A series of tests on the samples were next conducted. Test results showed that waste glass had positive effects on bending strength, water absorption and weight loss on ignition, while WFS contributed the most in reducing shrinkage, but could decrease the tile bending strength when large amount was added at a high kiln temperature. This study suggested that a combination of WFS from 10% to 15%, waste glass from 15% to 20%, SSA at 10% at a kiln temperature between 1000°C and 1050°C could result in quality reclaimed tiles with a balanced performance.
Acid-Alkali Resistance of New Reclaimed Tiles Containing Sewage Sludge Ash and Waste Glass
Lin, Deng-Fong; Lin, Kuo-Liang; Luo, Huan-Lin; Xu, Jia-Qin
2016-01-01
In this study, properties of newly developed reclaimed tiles in a harmful environment were investigated. A portion of clay used to manufacture tiles was replaced with sewage sludge ash (SSA) and waste glass to produce the new reclaimed tiles. To investigate the effects of SSA and waste glass on the properties of the tiles, different specimens were blended and placed in acid-alkali solutions. The reclaimed tile specimens were manufactured by clay, 10% SSA, and five different mixes of waste glass replacement, namely, 0%, 10%, 20%, 40%, and 60%. These specimens were calcined at 1000 °C and subsequently underwent a series of tests, including TGA/DTA (thermogravimetric analysis/differential thermal analysis), SEM (scanning electron microscopy), XRD (X-ray diffraction), bending strength, weight loss, and porosity. Test results show that shortcomings associated with the introduction of the sludge ash were improved by the admixture of waste glass, especially in the aspects of shrinkage and bending strength. The study showed that the new reclaimed tiles performed relatively well in acid-alkali resistance tests but appeared to have better alkali resistance than acid resistance. It was also found that the optimal mix of such reclaimed tiles was 10% SSA, 10% waste glass, and 80% clay. PMID:28773668
Di Giuseppe, Dario; Melchiorre, Massimiliano; Faccini, Barbara; Ferretti, Giacomo; Coltorti, Massimo
2017-09-26
Reclaimed salt marshes are fragile environments where water salinization and accumulation of heavy metals can easily occur. This type of environment constitutes a large part of the Po River Delta (Italy), where intensive agricultural activities take place. Given the higher Ni background of Po River Delta soils and its water-soluble nature, the main aim of this contribution is to understand if reclamation can influence the Ni behavior over time. In this study, we investigated the geochemical features of 40 soils sampled in two different localities from the Po River Delta with different reclamation ages. Samples of salt marsh soils reclaimed in 1964 were taken from Valle del Mezzano while soils reclaimed in 1872 were taken nearby Codigoro town. Batch solubility tests and consecutive determination of Ni in pore-water were compared to bulk physicochemical compositions of soils. Bulk Ni content of the studied soils is naturally high, since these soils originated from Po River sediments derived from the erosion of ultramafic rocks. Moreover, it seems that Ni concentration increases during soil evolution, being probably related to the degradation of serpentine. Instead, the water-soluble Ni measured in the leaching tests is greater in soils recently reclaimed compared to the oldest soils. Soil properties of two soil profiles from a reclaimed wetland area were examined to determine soil evolution over one century. Following reclamation, pedogenic processes of the superficial horizons resulted in organic matter mineralization, pH buffer, and a decrease of Ni water solubility from recently to evolved reclaimed soil.
Intrinsic and specific vulnerability of groundwater in central Spain: the risk of nitrate pollution
NASA Astrophysics Data System (ADS)
Martínez-Bastida, Juan J.; Arauzo, Mercedes; Valladolid, Maria
2010-05-01
The intrinsic vulnerability of groundwater in the Comunidad de Madrid (central Spain) was evaluated using the DRASTIC and GOD indexes. Groundwater vulnerability to nitrate pollution was also assessed using the composite DRASTIC (CD) and nitrate vulnerability (NV) indexes. The utility of these methods was tested by analyzing the spatial distribution of nitrate concentrations in the different aquifers located in the study area: the Tertiary Detrital Aquifer, the Moor Limestone Aquifer, the Cretaceous Limestone Aquifer and the Quaternary Aquifer. Vulnerability maps based on these four indexes showed very similar results, identifying the Quaternary Aquifer and the lower sub-unit of the Moor Limestone Aquifer as deposits subjected to a high risk of nitrate pollution due to intensive agriculture. As far as the spatial distribution of groundwater nitrate concentrations is concerned, the NV index showed the greatest statistical significance ( p < 0.01). This new type of multiplicative model offers greater accuracy in estimations of specific vulnerability with respect to the real impact of each type of land use. The results of this study provide a basis on which to guide the designation of nitrate vulnerable zones in the Comunidad de Madrid, in line with European Union Directive 91/676/EEC.
DOE Office of Scientific and Technical Information (OSTI.GOV)
Raisbeck, M.L.; Vance, G.F.; Steward, D.G.
1995-09-01
Samples of liver tissue from deer mice trapped on not-yet-mined areas and reclaimed areas at five surface coal mines in the Powder River Basin of northeastern Wyoming were analyzed for selenium. The overall mean concentration of selenium in wet weight liver tissue was 1.685 ppm. The mean value from not-yet-mined areas was 1.437 ppm; the mean value from reclaimed areas was 1.910 ppm (significant at p<0.1016). When one not-yet-mined outlier was removed, significance rose to p<0.0004. Mine-to-mine comparison of samples stratified by type (that is, by not-yet-mined or reclaimed), showed average tissue concentrations from the reclaimed area of Mine 1more » were also higher (p<0.0143) then not-yet-mined area samples at Mine 1. No statistically significant differences were found between mines for samples from not-yet-mined areas, and no statistically significant differences were found between Mines 2, 3, 4, and 5 for samples from reclaimed areas. Multiple analysis of variance using the factors: site (mine) and type (not-yet-mined or reclaimed) was not significantly significant (p<0.2115). Simple linear regression showed that selenium concentrations in dry tissue could easily be predicted from wet tissue selenium (r2=0.9775), demonstrating that percent water in the samples was relatively constant. Animal body weight in general was not a predictor for either wet or dry tissue selenium concentrations, but was related to body weight at the higher tissue concentrations of selenium encountered in samples from the reclaimed area at Mine 1. Mouse body weights at Mine 1 were higher on the reclaimed area than mouse body weights from the not-yet-mined area.« less
NASA Astrophysics Data System (ADS)
Barrett, Timothy J.
In 2009, ASTM and AASHTO permitted the use of up to 5% interground limestone in ordinary portland cement (OPC) as a part of a change to ASTM C150/AASHTO M85. When this work was initiated a new proposal was being discussed that would enable up to 15% interground limestone cement to be considered in ASTM C595/AASHTO M234. This work served to provide rapid feedback to the state department of transportation and concrete industry for use in discussions regarding these specifications. Since the time this work was initiated, ASTM C595/AASHTO M234 was passed (2012c) and PLCs are now able to be specified, however they are still not widely used. The proposal for increasing the volume of limestone that would be permitted to be interground in cement is designed to enable more sustainable construction, which may significantly reduce the CO2 that is embodied in the built infrastructure while also extending the life of cement quarries. Research regarding the performance of cements with interground limestone has been conducted by the cement industry since these cements became widely used in Europe over three decades ago, however this work focuses on North American Portland Limestone Cements (PLCs) which are specifically designed to achieve similar performance as the OPCs they replace.This thesis presents a two-phase study in which the potential for application of cements containing limestone was assessed. The first phase of this study utilized a fundamental approach to determine whether cement with up to 15% of interground or blended limestone can be used as a direct substitute to ordinary portland cement. The second phase of the study assessed the concern of early age shrinkage and cracking potential when using PLCs, as these cements are typically ground finer than their OPC counterparts. For the first phase of the study, three commercially produced PLCs were obtained and compared to three commercially produced OPCs made from the same clinker. An additional cement was tested where the limestone was blended (i.e., not interground) as needed, enabling variation of the size of the limestone particles. In addition, one of the commercially produced OPCs and PLCs were used with fly ash. A series of standardized tests were run to assess the physical effects of intergrinding limestone in portland cement, the effect of limestone presence and method of inclusion on the hydration reaction, and the associated mechanical and transport properties of concretes made with these limestone cements. The second phase of the study used a commercially produced OPC, a PLC, and a PLC-slag all made from the same parent clinker to quantify the early age shrinkage and cracking potential. The study presents a series of tests that quantify the fundamental origins of shrinkage in cementitious materials to elucidate the differences between PLC and OPC. The bulk shrinkage of these systems is then quantified under free and restrained conditions to provide an assessment of the susceptibility for cracking in portland limestone cements. The results of the first phase of this thesis showed that in general the PLC and OPC systems have similar hydration, set, and mechanical performance. Transport properties in this study show behavior that is +/- 30% of the conventional OPC system depending on the system. Literature has shown similar freeze-thaw resistance when these materials are used in properly air entrained mixtures, and the results for PLC systems with fly ash show added performance. Based on these results it appears that PLC that meets ASTM C595/AASHTO M234 should be able to be used interchangeably with OPC, while it should also be noted that the investigation of the influence of salts and sulfates on PLCs is still ongoing and should be monitored. The results of the second phase of this thesis showed that while the PLCs are finer, this comes primarily by reducing the very large particles (clinker particles greater than 30 microns) using advanced separator technology and increasing the number of very fine limestone particles. This results in the cements tested having similar autogenous shrinkage development in the PLC systems compared to the OPC, with slightly less shrinkage in the PLC-slag system. The stress that develops when this shrinkage is restrained is very similar in comparing the OPC, PLC and PLC-slag systems and the PLC mixture tends to crack at a similar or slightly earlier times.
DOE Office of Scientific and Technical Information (OSTI.GOV)
Latif-Eugenín, Fadua; Beaz-Hidalgo, Roxana; Silver
Wastewater is increasingly being recognized as a key water resource, and reclaimed water (or treated wastewater) is used for irrigating vegetables destined for human consumption. The aim of the present study was to determine the diversity and prevalence of Aeromonas spp. both in reclaimed water used for irrigation and in the three types of vegetables irrigated with that water. Seven of the 11 (63.6%) samples of reclaimed water and all samples of vegetables were positive for the presence of Aeromonas. A total of 216 Aeromonas isolates were genotyped and corresponded to 132 different strains that after identification by sequencing themore » rpoD gene belonged to 10 different species. The prevalence of the species varied depending on the type of sample. In the secondary treated reclaimed water A. caviae and A. media dominated (91.4%) while A. salmonicida, A. media, A. allosaccharophila and A. popoffii represented 74.0% of the strains in the irrigation water. In vegetables, A. caviae (75.0%) was the most common species, among which a strain isolated from lettuce had the same genotype (ERIC pattern) as a strain recovered from the irrigation water. Furthermore, the same genotype of the species A. sanarellii was recovered from parsley and tomatoes demonstrating that irrigation water was the source of contamination and confirming the risk for public health. - Highlights: • Reclaimed water (= treated wastewater) is used for the irrigation of vegetables. • Aeromonas was found in reclaimed water and irrigated vegetables with this water. • The prevalence of Aeromonas spp. varied between irrigation water and vegetables. • Epidemiological relationships were found between irrigation water and vegetables. • The water was the source of contamination which means a risk for the public health.« less
Hong, Pei-Ying; Al-Jassim, Nada; Ansari, Mohd Ikram; Mackie, Roderick I.
2013-01-01
Water scarcity is a global problem, and is particularly acute in certain regions like Africa, the Middle East, as well as the western states of America. A breakdown on water usage revealed that 70% of freshwater supplies are used for agricultural irrigation. The use of reclaimed water as an alternative water source for agricultural irrigation would greatly alleviate the demand on freshwater sources. This paradigm shift is gaining momentum in several water scarce countries like Saudi Arabia. However, microbial problems associated with reclaimed water may hinder the use of reclaimed water for agricultural irrigation. Of particular concern is that the occurrence of antibiotic residues in the reclaimed water can select for antibiotic resistance genes among the microbial community. Antibiotic resistance genes can be associated with mobile genetic elements, which in turn allow a promiscuous transfer of resistance traits from one bacterium to another. Together with the pathogens that are present in the reclaimed water, antibiotic resistant bacteria can potentially exchange mobile genetic elements to create the “perfect microbial storm”. Given the significance of this issue, a deeper understanding of the occurrence of antibiotics in reclaimed water, and their potential influence on the selection of resistant microorganisms would be essential. In this review paper, we collated literature over the past two decades to determine the occurrence of antibiotics in municipal wastewater and livestock manure. We then discuss how these antibiotic resistant bacteria may impose a potential microbial risk to the environment and public health, and the knowledge gaps that would have to be addressed in future studies. Overall, the collation of the literature in wastewater treatment and agriculture serves to frame and identify potential concerns with respect to antibiotics, antibiotic resistant bacteria, and antibiotic resistance genes in reclaimed water. PMID:27029309
Cost Analysis of NEDU’s Helium Reclaimer.
1981-09-01
T ITLE (and Subtitle) S . TYPE OF REPORT 6 PERIOD COVERED COST ANALYSIS OF NEDU’S HELIUM RECLAIMER . Survey 6 . PERFORMING ORG. REPORT NUMSER 7...telephone conversation). 5. Charles T. Horngren , "Introduction tu Management Accounting " Fourth Edition. 3 . .4m mmnssmmlm~ • FIGURE 1 PRESENT, FUTURE AND...FEET COST OF PERIODIC MAINTENANCE OF HELIUM ELECTRIiC COST COST OF TOTAL RECLAIMED POWER NEW COST PRESENT WORTH YEAR N PER YEAR ( S /1000 FT
NASA Astrophysics Data System (ADS)
Su, Changhong; Xu, Youqian; Zhang, Wei; Liu, Yang; Li, Jun
2012-01-01
A porous ceramic tube with superhydrophobic and superoleophilic surface was fabricated by sol-gel and then surface modification with polyurethane-polydimethysiloxane, and an oil-water separator based on the porous ceramic tube was erected to characterize superhydrophobic and superoleophilic surface's separation efficiency and velocity when being used to reclaim oil from oily water and complex oily water containing clay particle. The separator is fit for reclaiming oil from oily water.
NASA Astrophysics Data System (ADS)
Ayuningrum, Theresia Vika; Purnaweni, Hartuti
2018-02-01
Potential Karst area in Nusakambangan has an important role in maintaining the balance of nature. But with the existence of mining activities, will automatically change the environmental conditions there. In order for the utilization of resources to meet the rules of optimization between the interests of mining and sustainability of the environment so in every mining sector activities required a variety of environmental studies. The purpose of this study is to find out how the analysis of environmental management due to limestone mining activities in Nusakambangan so that it can be known the management of mining areas are optimal, wise based on ecological principles, and sustainability. In qualitative research methods, data analysis using description percentage, with the type of data collected in the form of primary data and secondary data.
Material handling systems for the fluidized-bed combustion boiler at Rivesville, West Virginia
NASA Technical Reports Server (NTRS)
Branam, J. G.; Rosborough, W. W.
1977-01-01
The 300,000 lbs/hr steam capacity multicell fluidized-bed boiler (MFB) utilizes complex material handling systems. The material handling systems can be divided into the following areas: (1) coal preparation; transfer and delivery, (2) limestone handling system, (3) fly-ash removal and (4) bed material handling system. Each of the above systems are described in detail and some of the potential problem areas are discussed. A major potential problem that exists is the coal drying system. The coal dryer is designed to use 600 F preheated combustion air as drying medium and the dryer effluent is designed to enter a hot electrostatic precipitator (730 F) after passage through a cyclone. Other problem areas to be discussed include the steam generator coal and limestone feed system which may have operating difficulties with wet coal and/or coal fines.
NASA Astrophysics Data System (ADS)
Navaro, J.; Bruneau, D.; Drouadaine, I.; Pouteau, B.; Colin, J.; Dony, A.
2012-05-01
When asphalt concrete is manufactured incorporating a high percentage (almost 70%) of reclaimed materials from the deconstruction of road surfaces under renovation, and when the corresponding production device is designed specifically to reduce the energy input need (lowering the production temperature), the resulting manufacturing process contributes to the protection of the environment and reduces production costs. However, to meet the quality requirements of the finished product, virgin materials of appropriate quality and quantity must also be added (mineral aggregates and new asphalt binder) and control systems set up to quantify and optimize the parameters involved (thus avoiding the guess work which still often prevails today). It was for this reason that a new experimental technique described here was devised, which will ultimately be used in asphalt concrete production plants. The technique involves lixiviating reclaimed asphalt concrete using a chlorinated solvent; the resulting solute is collected gradually, then the mixture of binders (virgin and reclaimed asphalt concrete) can be characterized and their mass fractions quantified using a combination of UV and IR spectrometry. With this experimental technique we were able to assess the extent to which the reclaimed asphalt pavement binder participates in the agglomeration and cohesion of the reclaimed asphalt concrete. This assessment was made in terms of the main parameters in the production process, temperature of the materials and mixing time.
Aquatic biomonitoring of reclaimed water for potable use: the San Diego Health Effects Study.
de Peyster, A; Donohoe, R; Slymen, D J; Froines, J R; Olivieri, A W; Eisenberg, D M
1993-05-01
Highly treated reclaimed wastewater was evaluated as a possible supplement to raw water sources required to meet San Diego's growing need for potable water. Biomonitoring experiments employing fathead minnows (Pimephales promelas) were used to compare reclaimed water with the city's current raw water supply. Juvenile fish were exposed in flow-through aquaria in field laboratories located at the reclamation plant (AQUA II) and at a municipal potable water treatment facility (Miramar). Biomonitoring measurements were survival and growth, swimming performance, and trace amounts of 68 base/neutral/acid extractable organics, 27 pesticides, and 27 inorganic chemicals found in fish tissues after exposure. Biomonitoring revealed differences in survival, growth, and swimming performance only after 90- and 180-d exposure. Reclaimed water and raw water were not readily distinguishable in 28-d chemical bioaccumulation tests in terms of organic chemical contaminants in fish tissue except for pesticide levels, which tended to be higher in raw water. Similar inorganic species were found in samples from both waters, although there was greater evidence of bioaccumulation of certain contaminants from raw water. Based on biomonitoring parameters included in these experiments, the use of reclaimed water to supplement raw water supplies would appear to pose no major public health threats. The results of these studies will be combined with additional health effects information before final conclusions are reached about the suitability of reclaimed water for human consumption.
Quantitative PCR and Digital PCR for Detection of Ascaris lumbricoides Eggs in Reclaimed Water
Santísima-Trinidad, Ana Belén; Bornay-Llinares, Fernando Jorge; Martín González, Marcos; Pascual Valero, José Antonio; Ros Muñoz, Margarita
2017-01-01
The reuse of reclaimed water from wastewater depuration is a widespread and necessary practice in many areas around the world and must be accompanied by adequate and continuous quality control. Ascaris lumbricoides is one of the soil-transmitted helminths (STH) with risk for humans due to its high infectivity and an important determinant of transmission is the inadequacy of water supplies and sanitation. The World Health Organization (WHO) recommends a limit equal to or lower than one parasitic helminth egg per liter, to reuse reclaimed water for unrestricted irrigation. We present two new protocols of DNA extraction from large volumes of reclaimed water. Quantitative PCR (qPCR) and digital PCR (dPCR) were able to detect low amounts of A. lumbricoides eggs. By using the first extraction protocol, which processes 500 mL of reclaimed water, qPCR can detect DNA concentrations as low as one A. lumbricoides egg equivalent, while dPCR can detect DNA concentrations as low as five A. lumbricoides egg equivalents. By using the second protocol, which processes 10 L of reclaimed water, qPCR was able to detect DNA concentrations equivalent to 20 A. lumbricoides eggs. This fact indicated the importance of developing new methodologies to detect helminth eggs with higher sensitivity and precision avoiding possible human infection risks. PMID:28377928
Qian-Yuan, Wu; Chao, Li; Ye, Du; Wen-Long, Wang; Huang, Huang; Hong-Ying, Hu
2016-05-15
Ecological storage of reclaimed water in ponds and lakes is widely applied in water reuse. During reclaimed water storage, solar light can degrade pollutants and improve water quality. This study investigated the effects of solar light irradiation on the disinfection byproduct formation potential in reclaimed water, including haloacetonitriles (HANs), trichloronitromethane (TCNM), trihalomethanes (THMs), haloketones (HKs) and chloral hydrate (CH). Natural solar light significantly decreased the formation potential of HANs, TCNM, and HKs in reclaimed water, but had a limited effect on the formation potential of THMs and CH. Ultraviolet (UV) light in solar radiation played a dominant role in the decrease of the formation potential of HANs, TCNM and HKs. Among the disinfection byproducts, the removal kinetic constant of dichloroacetonitrile (DCAN) with irradiation dose was much larger than those for dichloropropanone (1,1-DCP), trichloropropanone (1,1,1-TCP) and TCNM. During solar irradiation, fluorescence spectra intensities of reclaimed water also decreased significantly. The removal of tyrosine (Tyr)-like and tryptophan (Trp)-like protein fluorescence spectra intensity volumes was correlated to the decrease in DCAN formation potential. Solar irradiation was demonstrated to degrade Trp, Tyr and their DCAN formation potential. The photolysis products of Trp after solar irradiation were detected as kynurenine and tryptamine, which had chloroform, CH and DCAN formation potential lower than those of Trp. Copyright © 2016. Published by Elsevier Ltd.
NASA Astrophysics Data System (ADS)
Bańkowski, Wojciech; Król, Jan; Gałązka, Karol; Liphardt, Adam; Horodecka, Renata
2018-05-01
Recycling of bituminous pavements is an issue increasingly being discussed in Poland. The analysis of domestic and foreign experience indicates a need to develop this technology in our country, in particular the hot feeding and production technologies. Various steps are being taken in this direction, including research projects. One of them is the InnGA project entitled: “Reclaimed asphalt pavement: Innovative technology of bituminous mixtures using material from reclaimed asphalt pavement”. The paper presents the results of research involving the design of bituminous mixtures in accordance with the required properties and in excess of the content of reclaimed asphalt permitted by the technical guidelines. It presents selected bituminous mixtures with the content of RAP of up to 50% and the results of tests from verification of industrial production of those mixtures. The article discusses the details of the design process of mixtures with a high content of reclaimed asphalt, the carried out production tests and discusses the results of tests under the verification of industrial production. Testing included basic tests according to the Polish technical requirements of WT- 2 and the extended functional testing. The conducted tests and analyses helped to determine the usefulness of the developed bituminous mixtures for use in experimental sections and confirmed the possibility of using an increased amount of reclaimed asphalt up to 50% in mixtures intended for construction of national roads.
Livestock grazing for management of reclaimed land at Navajo Mine: Animal response
DOE Office of Scientific and Technical Information (OSTI.GOV)
Gamble, D.C.; Gadzia, K.L.; Raisbeck, M.F.
1997-12-31
Livestock responses dining grazing of reclaimed land were monitored at the Navajo Mine since 1994. The Navajo Mine Grazing Management Program (GNP) began in 1991 to prepare for bond release and return of reclaimed land to the Navajo Nation by demonstrating the ability of the land to sustain the post-mining land use of livestock grazing. Local Navajos, whose livestock are used in the GMP, are interested in the ability of the land to sustain their livestock. Sustainable livestock grazing implies the ability of animals to thrive, successfully reproduce and maintain the health of the land. Daily care and monitoring ofmore » livestock health was carried out by herders hired by the mining company. General animal health parameters including blood selenium levels were monitored quarterly. Livestock responses to grazing reclaimed land have been largely positive. Cows have produced healthy offspring and owners indicate satisfaction with calf size, and overall performance of the cows. Selenium and other blood testing parameters indicate no adverse effect on animal health to date. Hazards associated with reclamation and ongoing mining activities are important considerations for lands being reclaimed for livestock grazing as a post-mining land use and must be monitored carefully during any grazing program. Preliminary results indicate that planned grazing by cattle on reclaimed land at Navajo Mine is feasible and does not adversely affect animal health.« less
Li, Zhen; Xiang, Xi; Li, Miao; Ma, Yeping; Wang, Jihua; Liu, Xiang
2015-09-01
Groundwater recharge using reclaimed water is considered a promising method to alleviate groundwater depletion. However, pollutants in reclaimed water could be recharged into groundwater during this process, thereby posing a risk to groundwater and human health. In this study, 12 cities in northern China were selected for reclaimed water and groundwater sampling. Analysis of the samples revealed the presence of nine pharmaceutical and personal care products (PPCPs) and five endocrine disrupting compounds (EDCs). In reclaimed water, all the PPCPs and EDCs were found, with sulpiride (SP) and estriol (E3) being most frequently detected. In groundwater samples, only ketoprofen (KP), mefenamic acid (MA), nalidixic acid (NA) and SP were detected among PPCPs, while bisphenol-A (BPA) was dominant among the target EDCs. The risk quotients (RQs) of all target PPCPs and EDCs except 17α-ethinyl estradiol (EE2) and E3 were below 1 in groundwater samples, indicating that EE2 and E3 deserve priority preferential treatment before recharging. Copyright © 2015 Elsevier Inc. All rights reserved.
Attrition-enhanced sulfur capture by limestone particles in fluidized beds
DOE Office of Scientific and Technical Information (OSTI.GOV)
Saastamoinen, J.J.; Shimizu, T.
2007-02-14
Sulfur capture by limestone particles in fluidized beds is a well-established technology. The underlying chemical and physical phenomena of the process have been extensively studied and modeled. However, most of the studies have been focused on the relatively brief initial stage of the process, which extends from a few minutes to hours, yet the residence time of the particles in the boiler is much longer. Following the initial stage, a dense product layer will be formed on the particle surface, which decreases the rate of sulfur capture and the degree of utilization of the sorbent. Attrition can enhance sulfur capturemore » by removing this layer. A particle model for sulfur capture has been incorporated with an attrition model. After the initial stage, the rate of sulfur capture stabilizes, so that attrition removes the surface at the same rate as diffusion and chemical reaction produces new product in a thin surface layer of a particle. An analytical solution for the conversion of particles for this regime is presented. The solution includes the effects of the attrition rate, diffusion, chemical kinetics, pressure, and SO{sub 2} concentration, relative to conversion-dependent diffusivity and the rate of chemical reaction. The particle model results in models that describe the conversion of limestone in both fly ash and bottom ash. These are incorporated with the residence time (or reactor) models to calculate the average conversion of the limestone in fly ash and bottom ash, as well as the efficiency of sulfur capture. Data from a large-scale pressurized fluidized bed are compared with the model results.« less
40 CFR 421.246 - Pretreatment standards for new sources.
Code of Federal Regulations, 2010 CFR
2010-07-01
...) Acid reclaim leaching filtrate. PSNS for the Secondary Nickel Subcategory Pollutant or pollutant... reclaim leaching belt filter backwash. PSNS for the Secondary Nickel Subcategory Pollutant or pollutant...
40 CFR 421.246 - Pretreatment standards for new sources.
Code of Federal Regulations, 2013 CFR
2013-07-01
...) Acid reclaim leaching filtrate. PSNS for the Secondary Nickel Subcategory Pollutant or pollutant... reclaim leaching belt filter backwash. PSNS for the Secondary Nickel Subcategory Pollutant or pollutant...
40 CFR 421.246 - Pretreatment standards for new sources.
Code of Federal Regulations, 2012 CFR
2012-07-01
...) Acid reclaim leaching filtrate. PSNS for the Secondary Nickel Subcategory Pollutant or pollutant... reclaim leaching belt filter backwash. PSNS for the Secondary Nickel Subcategory Pollutant or pollutant...
40 CFR 421.246 - Pretreatment standards for new sources.
Code of Federal Regulations, 2014 CFR
2014-07-01
...) Acid reclaim leaching filtrate. PSNS for the Secondary Nickel Subcategory Pollutant or pollutant... reclaim leaching belt filter backwash. PSNS for the Secondary Nickel Subcategory Pollutant or pollutant...
NASA Astrophysics Data System (ADS)
Chomicz-Kowalska, Anna; Iwański, Mateusz M.; Mrugała, Justyna
2017-10-01
During the reconstruction of road pavements, the reclaimed asphalt pavement (RAP), which is obtained through milling of the worn out existing asphalt, is commonly used for producing new base courses in cold recycling processes. Two of these techniques are most popular: one using mineral-cement-emulsion mixes and one utilizing mineral cement mixes with foamed bitumen. Additionally, some amounts of RAP can be incorporated into traditional hot mix asphalt. The demand for energy efficient and environmentally friendly solutions however, results in a need for development of new techniques that would result in cheaper and more reliable solutions with smaller carbon footprint. The reduction of processing temperatures with simultaneous incorporation of reclaimed material is the most efficient way of obtaining these objectives, but it often results in the overall decrease of bituminous mix quality. The paper presents the possibility of using RAP for producing asphalt concrete in warm mix asphalt (WMA) production process by the use of foamed bitumen modified with Fischer-Tropsch synthetic wax and polymer-basalt fibers. Additionally, a series of reference mixtures were produced to investigate the effects of the additives and of the warm process. The carried out analyses and tests shown that the experimental warm mix asphalt produced with RAP and foamed bitumen returned satisfactory performance. The introduction of synthetic F-T wax in the warm foam bitumen mixes resulted in a significantly improved compaction levels and moisture and frost resistance and the addition of polymer-basalt fibers has further improved the permanent deformation resistance of the mixes. All of the designed and tested mixes have fulfilled the requirements for binding course asphalt concrete with medium traffic loads.
Remote sensing of effects of land use practices on water quality
NASA Technical Reports Server (NTRS)
Graves, D. H.; Colthrap, G. B.
1977-01-01
An intensive study was conducted to determine the utility of manual densitometry and color additive viewing of aircraft and LANDSAT transparencies for monitoring land use and land use change. The relationship between land use and selected water quality parameters was also evaluated. Six watersheds located in the Cumberland Plateau region of eastern Kentucky comprised the study area for the project. Land uses present within the study area were reclaimed surface mining and forestry. Fertilization of one of the forested watersheds also occurred during the study period.
Effects of limestone on starch digestion in Holstein steers.
Tissera, G H; Vandersall, J H; Erdman, R A
1988-03-01
Eight calcitic and three dolomitic limestones were examined for particle size and reactivity with hydrochloric acid at pH 3.5 and 5.5. Reactivity was higher in calcitic than dolomitic limestone. Within calcitic limestones, reactivity was highly related to particle size. A highly reactive limestone was selected for use in two digestion trials with Holstein steers. In Trial 1, 4 steers (approximately 300 kg) were fed diets consisting of 40% corn silage and 60% concentrate (DM basis) with .62 or 2.34% limestone in a single reversal trial with 3-wk experimental periods. Added limestone affected only starch digestibility, which increased from 91.3 to 93.2%. Fecal pH increased from 5.7 to 6.4 by limestone addition. In trial 2, four rumen and duodenally cannulated steers (approximately 475 kg) were fed the same diets in the same design. Limestone addition increased fecal pH from 5.7 to 6.5. There were no effects of limestone on rumen or total tract digestion of starch or other nutrients. Limestone addition had no effect on rumen pH, buffering capacity, or VFA concentrations. Addition of a highly reactive limestone to diets containing high amounts of starch had little effect on starch digestion in either the rumen or lower gastrointestinal tract.
Aguilar Alvarez, Ronald Esteban; Bustamante Roman, Mauricio; Kirk, Dana; Miranda Chavarria, Jose Alberto; Baudrit, Daniel; Aguilar Pereira, Jose Francisco; Rodriguez Montero, Werner; Reinhold, Dawn; Liao, Wei
2016-12-15
The purpose of this study was to implement and evaluate a pilot-scale and closed-loop system that synergistically combines solar thermal collector, anaerobic digester, and constructed treatment wetland to simultaneously treat and utilize organic wastes. The system utilizes 863 kg of mixed animal and food wastes to generate 263 MJ renewable energy, produced 28 kg nitrogen and phosphorus fertilizer, and reclaimed 550 kg water per day. The net revenue considering electricity and fertilizer was $2436 annually. The payback period for the system is estimated to be 17.8 years for a relatively dilute waste stream (i.e., 2% total solids). The implemented system has successfully demonstrated a self-efficient and flexible waste utilization and treatment system. It creates a win-win solution to satisfy the energy needs of the community and address environmental concerns of organic wastes disposal in the region. Copyright © 2016 Elsevier Ltd. All rights reserved.
The Research Process on Converter Steelmaking Process by Using Limestone
NASA Astrophysics Data System (ADS)
Tang, Biao; Li, Xing-yi; Cheng, Han-chi; Wang, Jing; Zhang, Yun-long
2017-08-01
Compared with traditional converter steelmaking process, steelmaking process with limestone uses limestone to replace lime partly. A lot of researchers have studied about the new steelmaking process. There are much related research about material balance calculation, the behaviour of limestone in the slag, limestone powder injection in converter and application of limestone in iron and steel enterprises. The results show that the surplus heat of converter can meet the need of the limestone calcination, and the new process can reduce the steelmaking process energy loss in the whole steelmaking process, reduce carbon dioxide emissions, and improve the quality of the gas.
40 CFR 428.95 - Standards of performance for new sources.
Code of Federal Regulations, 2010 CFR
2010-07-01
... Mechanical Reclaimed Rubber Subcategory § 428.95 Standards of performance for new sources. (a) The following..., dry digestion, and mechanical reclaimed rubber processes which are integrated with a wet digestion...
Ping, Xu; Jing, Wang; Yajun, Zhang; Jie, Wang; Shuai, Si
2015-01-01
Due to water shortage, municipal reclaimed water rather than surface water was replenished into recycling cooling water system in power plants in some cities in China. In order to understand the effects of the measure on carbon steel corrosion, characteristics of two kinds of foulant produced in different systems were studied in the paper. Differences between municipal reclaimed water and surface water were analyzed firstly. Then, the weight and the morphology of two kinds of foulant were compared. Moreover, other characteristics including the total number of bacteria, sulfate reducing bacteria, iron bacteria, extracellular polymeric substance (EPS), protein (PN), and polysaccharide (PS) in foulant were analyzed. Based on results, it could be concluded that microbial and corrosive risk would be increased when the system replenished by municipal reclaimed water instead of surface water.
Yin, Shiyang; Wu, Wenyong; Liu, Honglu; Bao, Zhe
2016-10-01
Reclaimed water reuse is an effective method of alleviating agricultural water shortages, which entails some potential risks for groundwater. In this study, the impacts of wastewater reuse on groundwater were evaluated by combination of groundwater chemistry and isotopes. In reclaimed water infiltration, salt composition was affected not only by ion exchange and dissolution equilibrium but also by carbonic acid equilibrium. The dissolution and precipitation of calcites and dolomites as well as exchange and adsorption between Na and Ca/Mg were simultaneous, leading to significant changes in Na/Cl, (Ca+Mg)/Cl, electrical conductivity (EC) and sodium adsorption ratio (SAR). The reclaimed water was of the Na-Mg-Ca-HCO 3 -Cl type, and groundwater recharged by reclaimed water was of the Na-Mg-HCO 3 and Mg-Na-HCO 3 types. The hydrogeological conditions characterized by sand-clay alternation led to both total nitrogen (TN) and total phosphorus (TP) removal efficiencies >95%, and there was no significant difference in those contents between aquifers recharged by precipitation and reclamation water. >40years of long-term infiltration and recharge from sewage and reclaimed water did not cause groundwater contamination by nitrogen, phosphorus and heavy metals. These results indicate that characteristics of the study area, such as the lithologic structure with sand-clay alternation, relatively thick clay layer, and relatively large groundwater depth have a significant role in the high vulnerability. Copyright © 2016 Elsevier B.V. All rights reserved.
Wood, Petra; Ammer, Frank K.
2015-01-01
We studied 3 mountaintop mining–valley fill (MTMVF) complexes in southern West Virginia, USA to examine grasshopper sparrow (Ammodramus savannarum pratensis) demographic response to different age classes of mine land reclamation. For 71 nests monitored during the 2001–2002 breeding seasons, overall nest success (36%) was within the range of nest success rates previously reported for this species, but it was highest on more recently reclaimed sites (56%). Nest density and clutch size did not differ (P > 0.30) among reclamation age classes, whereas number of fledglings was greater (P = 0.01) on more recently reclaimed sites. We measured vegetation variables at 70 nest subplots and at 96 systematic subplots to compare nest vegetation with vegetation available on the plots. We found that nests occurred in areas with more bare ground near the nest, greater vegetation height–density surrounding the nest site, lower grass height, and fewer woody stems, similar to previous studies. As postreclamation age increased, vegetation height–density and maximum grass height increased, and sericea (Lespedeza cuneata) became more dominant. Nest success declined with increasing vegetation height–density at the nest. The grasslands available on these reclaimed mine complexes are of sufficient quality to support breeding populations of grasshopper sparrows, but nest success decreased on the older reclaimed areas. Without active management, grasslands on reclaimed MTMVF mines become less suitable for nesting grasshopper sparrows about 10 years after reclamation.
Hammarstrom, J.M.; Sibrell, P.L.; Belkin, H.E.
2003-01-01
Armoring of limestone is a common cause of failure in limestone-based acid-mine drainage (AMD) treatment systems. Limestone is the least expensive material available for acid neutralization, but is not typically recommended for highly acidic, Fe-rich waters due to armoring with Fe(III) oxyhydroxide coatings. A new AMD treatment technology that uses CO2 in a pulsed limestone bed reactor minimizes armor formation and enhances limestone reaction with AMD. Limestone was characterized before and after treatment with constant flow and with the new pulsed limestone bed process using AMD from an inactive coal mine in Pennsylvania (pH = 2.9, Fe = 150 mg/l, acidity = 1000 mg/l CaCO3). In constant flow experiments, limestone is completely armored with reddish-colored ochre within 48 h of contact in a fluidized bed reactor. Effluent pH initially increased from the inflow pH of 2.9 to over 7, but then decreased to 6 during operation. Limestone removed from a pulsed bed pilot plant is a mixture of unarmored, rounded and etched limestone grains and partially armored limestone and refractory mineral grains (dolomite, pyrite). The ???30% of the residual grains in the pulsed flow reactor that are armored have thicker (50- to 100-??m), more aluminous coatings and lack the gypsum rind that develops in the constant flow experiment. Aluminium-rich zones developed in the interior parts of armor rims in both the constant flow and pulsed limestone bed experiments in response to pH changes at the solid/solution interface. ?? 2003 Elsevier Ltd. All rights reserved.
Jing, Ming; Wang, Lei
2016-02-15
In the study, 454-pyrosequencing technology was employed to investigate the species of pathogenic bacteria and the proportion of each pathogen in secondary effluent. Culture-based, qPCR and Q-RT-PCR methods were employed to analyze the removal of indicator (E. coli) and pathogen (Salmonella and Mycobacterium) by ultraviolet (UV) disinfection at a dose of 60 mJ x Cm(-2). The results showed that 11 kinds of pathogenic bacteria were found and the most abundant potentially pathogenic bacteria in the secondary effluent were affiliated with the genera of Clostridium (2.96%), Arcobacter (0.82%) and Mycobacterium (0.36%). 99.9% of culturable E. coli and Salmonella were removed by UV disinfection (60 mJ x cm(-2), however, less than 90% of culturable Mycobacterium were removed. The removal efficiencies of viable E. coli, Salmonella and Mycobacterium were low. Q-RT-PCR seemed to be a promising method for evaluating viable microorganisms in samples. Besides, pathogenic bacteria entered into VBNC state at a UV dose of 60 mJ x cm(-2). Other advanced treatment processes were needed to ensure safe utilization of reclaimed water.
Chihuahua: a water reuse case in the desert.
Espino, M S; Navarro, C J; Pérez, J M
2004-01-01
Water supply for all kind of uses in Chihuahua is mainly groundwater. During the last decade this city has been damaged with a heavy hydrologic crisis because of a persistent drought. This came up with the overexploitation of groundwater aquifers; therefore a deficit between demand and offer was done. To minimize this problem the government authorities have started an integral plan of optimizing hydrologic resources which considers the treatment of wastewater and the use of reclaimed water. The secondary wastewater treatment facility of the city treats about 30,000 m3/d of a wastewater with high organic contents, and produces an effluent with low concentration of suspended solids, organic matter, fats, detergents, and metals. Reclaimed water is conveyed toward strategic sites for the irrigation of great green areas in sport clubs, educational institutions and industrial zones, besides of its utilization on some manufacturing processes, road service, and also over construction industry. The potential reuse of this water goes farther from those activities; the treatment of the secondary effluent until the required levels of the water-bearing recharge criteria are met for drinking water supply is considered as the next step to achieve through a suitable planning strategy for the best integral resource advantage.
Rothman, Jason A.; Dudley, Stacia L.; Jones, Michael B.; McFrederick, Quinn S.; Gan, Jay; Trumble, John T.
2017-01-01
Many countries are utilizing reclaimed wastewater for agriculture because drought, rising temperatures, and expanding human populations are increasing water demands. Unfortunately, wastewater often contains biologically active, pseudopersistent pharmaceuticals, even after treatment. Runoff from farms and output from wastewater treatment plants also contribute high concentrations of pharmaceuticals to the environment. This study assessed the effects of common pharmaceuticals on an agricultural pest, Trichoplusia ni (Lepidoptera: Noctuidae). Larvae were reared on artificial diets spiked with contaminants of emerging concern (CECs) at environmentally relevant concentrations. Trichoplusia ni showed increased developmental time and mortality when reared on artificial diets containing antibiotics, hormones, or a mixture of contaminants. Mortality was also increased when T. ni were reared on tomatoes grown hydroponically with the same concentrations of antibiotics. The antibiotic-treated plants translocated ciprofloxacin through their tissues to roots, shoots, and leaves. Microbial communities of T. ni changed substantially between developmental stages and when exposed to CECs in their diets. Our results suggest that use of reclaimed wastewater for irrigation of crops can affect the developmental biology and microbial communities of an insect of agricultural importance. PMID:29087336
NASA Astrophysics Data System (ADS)
Li, Qianjun; Xu, Dongyang; Wu, Yunxia; Yu, Jin
2017-01-01
Influence of the main components of decoking agent (magnesium nitrate, aluminum nitrate, copper nitrate, ammonium nitrate and actual decoking agent) on the activity of limestone is studied in laboratory by MET method. Results show that magnesium nitrate, ammonium nitrate and copper nitrate almost has no effect on the activity of limestone. With the concentration increasing, aluminum nitrate has an increasing inhibition on the dissolution of limestone. Fly ash has inhibition on dissolution of limestone due to the blockage of limestone pore by fly ash. The actual decoking agent has almost no effect on the limestone.
Performance of reclaimed asphalt pavement on unpaved roads.
DOT National Transportation Integrated Search
2011-10-01
The University of Wyoming's LTAP Center conducted a study examining the performance of reclaimed, recycled asphalt pavement (RAP) on unpaved roads in three Wyoming counties. Fifteen material and dust suppression treatment combinations were examined. ...
Fatigue performance of asphalt pavements containing RAS and RAP.
DOT National Transportation Integrated Search
2015-01-01
Rising oil and gas prices spurs development of methods and technologies for reducing fuel consumption and increased use of : recycled materials. With increased environmental awareness, using reclaimed asphalt pavement (RAP) and reclaimed asphalt : sh...
Preliminary investigation of RAP and RAS in HMAC.
DOT National Transportation Integrated Search
2010-02-01
laboratory study was undertaken to investigate how various proportions of reclaimed asphalt pavement (RAP) and reclaimed asphalt shingles (RAS) added to hot mixed asphalt concrete (HMAC) mixtures affect the Superpave performance grade of the blended ...
Evaluation of reclaimed asphalt pavement for surface mixtures.
DOT National Transportation Integrated Search
2012-03-01
The Indiana Department of Transportation has successfully used Reclaimed Asphalt Pavement (RAP) for decades because of its economic : and environmental benefits. Because of uncertainties regarding the types of aggregates contained in RAP and their re...
Edwin R. Ferguson; David L. Graney
1975-01-01
Field guides are presented for estimating site index on each of the three major soil groups in the Ozark Highland Province: limestone-dolomite, sandstone, and fragipan soils. Factors utilized vary by soil groups but include aspect, township, slope shape and depth to pan, with adjustments for hardwood competition. Tabular predictions were within ± 3 feet of measured...
NASA Technical Reports Server (NTRS)
1997-01-01
Patterned after the Cassini Resource Exchange (CRE), Sholtz and Associates established the Automated Credit Exchange (ACE), an Internet-based concept that automates the auctioning of "pollution credits" in Southern California. An early challenge of the Jet Propulsion Laboratory's Cassini mission was allocating the spacecraft's resources. To support the decision-making process, the CRE was developed. The system removes the need for the science instrument manager to know the individual instruments' requirements for the spacecraft resources. Instead, by utilizing principles of exchange, the CRE induces the instrument teams to reveal their requirements. In doing so, they arrive at an efficient allocation of spacecraft resources by trading among themselves. A Southern California RECLAIM air pollution credit trading market has been set up using same bartering methods utilized in the Cassini mission in order to help companies keep pollution and costs down.
Optimization of Limestone Feed Size of a Pressurized Fluidized Bed Combustor
NASA Astrophysics Data System (ADS)
Shimizu, Tadaaki; Saastamolnen, Jaakko
Limestone attrition is a major cause of loss of limestone during pressurized fluidized bed combustion. In the authors' previous works, the analysis of published results of solid attrition and desulfurization was conducted to determine the attrition rate expression. The specific attrition rate (rate of decrease in diameter) was estimated to be second order with respect to particle diameter in the previous work. This rate expression implies that reduction of feed size of limestone is effective for suppression of loss of limestone by attrition. However, too much grinding of raw limestone will increase the content of fine particles that are readily elutriated by gas stream and do not contribute to the sulfur capture. In this work, modeling works are conducted for particle attrition and desulfurization in order to predict the effect of feed size of limestone on total consumption of limestone and desulfurization is discussed. Optimum particle size to suppress limestone consumption was approximately 0.7 mm (as D p50 ). However, the control of solid drain rate from the bottom was found to have more influence on total limestone consumption rate. Emissions of SO2 from low sulfur coal (S=0.33%) could be sufficiently low irrespective of limestone feed size but SO2 emissions from coals with higher sulfur content than 0.5% were anticipated to increase drastically. Such drastic change in SO2 emissions with the change in sulfur content is attributable to non-linear nature of reaction rate for attrition-enhanced desulfurization by limestone.
40 CFR 421.245 - Pretreatment standards for existing sources.
Code of Federal Regulations, 2010 CFR
2010-07-01
... 24.410 12.850 Nickel 24.670 16.320 (b) Acid reclaim leaching filtrate. PSES for the Secondary Nickel... Nickel 9.590 6.344 (c) Acid reclaim leaching belt filter backwash PSES for the Secondary Nickel...
40 CFR 421.244 - Standards of performance for new sources.
Code of Federal Regulations, 2013 CFR
2013-07-01
... range of 7.5 to 10.0 at all times. (b) Acid reclaim leaching filtrate. NSPS for the Secondary Nickel... all times. (c) Acid reclaim leaching belt filter backwash. NSPS for the Secondary Nickel Subcategory...
40 CFR 421.245 - Pretreatment standards for existing sources.
Code of Federal Regulations, 2013 CFR
2013-07-01
... 24.410 12.850 Nickel 24.670 16.320 (b) Acid reclaim leaching filtrate. PSES for the Secondary Nickel... Nickel 9.590 6.344 (c) Acid reclaim leaching belt filter backwash PSES for the Secondary Nickel...
40 CFR 421.244 - Standards of performance for new sources.
Code of Federal Regulations, 2014 CFR
2014-07-01
... range of 7.5 to 10.0 at all times. (b) Acid reclaim leaching filtrate. NSPS for the Secondary Nickel... all times. (c) Acid reclaim leaching belt filter backwash. NSPS for the Secondary Nickel Subcategory...
40 CFR 421.245 - Pretreatment standards for existing sources.
Code of Federal Regulations, 2014 CFR
2014-07-01
... 24.410 12.850 Nickel 24.670 16.320 (b) Acid reclaim leaching filtrate. PSES for the Secondary Nickel... Nickel 9.590 6.344 (c) Acid reclaim leaching belt filter backwash PSES for the Secondary Nickel...
40 CFR 421.244 - Standards of performance for new sources.
Code of Federal Regulations, 2012 CFR
2012-07-01
... range of 7.5 to 10.0 at all times. (b) Acid reclaim leaching filtrate. NSPS for the Secondary Nickel... all times. (c) Acid reclaim leaching belt filter backwash. NSPS for the Secondary Nickel Subcategory...
40 CFR 421.245 - Pretreatment standards for existing sources.
Code of Federal Regulations, 2012 CFR
2012-07-01
... 24.410 12.850 Nickel 24.670 16.320 (b) Acid reclaim leaching filtrate. PSES for the Secondary Nickel... Nickel 9.590 6.344 (c) Acid reclaim leaching belt filter backwash PSES for the Secondary Nickel...
Ping, Xu; Jing, Wang; Yajun, Zhang; Jie, Wang; Shuai, Si
2015-01-01
Due to water shortage, municipal reclaimed water rather than surface water was replenished into recycling cooling water system in power plants in some cities in China. In order to understand the effects of the measure on carbon steel corrosion, characteristics of two kinds of foulant produced in different systems were studied in the paper. Differences between municipal reclaimed water and surface water were analyzed firstly. Then, the weight and the morphology of two kinds of foulant were compared. Moreover, other characteristics including the total number of bacteria, sulfate reducing bacteria, iron bacteria, extracellular polymeric substance (EPS), protein (PN), and polysaccharide (PS) in foulant were analyzed. Based on results, it could be concluded that microbial and corrosive risk would be increased when the system replenished by municipal reclaimed water instead of surface water. PMID:25893132
Water resources of Soledad, Poway, and Moosa basins, San Diego County, California
Evenson, K.D.
1989-01-01
Reclaimed water is being considered as as supplemental water supply in the Soledad, Poway, and Moosa basins, San Diego County. This report describes the geology, soils, hydrology, and cultural factors in each of the basins as they relate to use of reclaimed water. Imported water is currently the major water-supply source in the basins. Groundwater supplies are used to a limited extent for both agricultural and domestic needs. Surface water flows are intermittent and, therefore, have not been developed for use in the basins. All three of the basins have the potential for use of reclaimed water, but only the Moosa basin is currently implementing a plan for such use. Concentrations of dissolved solids, chloride, and sulfate in both ground and surface water commonly exceed local basin objectives. As of 1985, plans for use of reclaimed water are oriented toward improving the quality of the groundwater. (USGS)
Description and preliminary calibration results for the Langley hypersonic CF4 tunnel
NASA Technical Reports Server (NTRS)
Midden, R. E.; Miller, C. G.
1978-01-01
A detailed description of the hypersonic CF4 tunnel is presented along with discussion of the basic components, instrumentation, and operating procedure. Operational experience with the CF4 reclaimer and lead-bath heater is discussed. Comparison of measured and predicted shock detachment distance on a sphere and pressure distributions measured on a sharp leading-edge flat plate revealed the absence of significant flow nonuniformity and lent creditability to predicted free stream flow conditions. The economic operation of this facility centers about the CF4 reclaimer, which was designed to operate at an efficiency of 90 to 95 percent. A number of modifications were made to the reclaimer system to improve its performance, and presently, the system reclaims approximately 75 percent of the test gas. Even with current budgetary constraints, this efficiency permits the CF4 tunnel to be operated as a viable research wind tunnel.
NASA Astrophysics Data System (ADS)
Mount, G.; Comas, X.
2017-12-01
The karstic Miami Limestone of the Biscayne aquifer is characterized as having water flow that is controlled by the presence of dissolution enhanced porosity and mega-porous features. The dissolution features and other high porosity areas create horizontal preferential flow paths and high rates of ground water velocity, which may not be accurately conceptualized in groundwater flow models. In addition, recent research suggests the presence of numerous vertical dissolution features across Everglades National Park at Long Pine Key Trail, that may act as areas of direct recharge to the aquifer. These vertical features have been identified through ground penetrating radar (GPR) surveys as areas of velocity pull-down which have been modeled to have porosity values higher than the surrounding Miami Limestone. As climate change may induce larger and longer temporal variability between wet and dry times in the Everglades, a more comprehensive understanding of preferential flow pathways from the surface to the aquifer would be a great benefit to modelers and planners. This research utilizes near surface geophysical techniques, such as GPR, to identify these vertical dissolution features and then estimate the spatial variability of porosity using petrophysical models. GPR transects that were collected for several kilometers along the Long Pine Key Trail, show numerous pull down areas that correspond to dissolution enhanced porosity zones within the Miami Limestone. Additional 3D GPR surveys have attempted to delineate the boundaries of these features to elucidate their geometry for future modelling studies. We demonstrate the ability of near surface geophysics and petrophysical models to identify dissolution enhanced porosity in shallow karstic limestones to better understand areas that may act as zones of direct recharge into the Biscayne Aquifer.
DOE Office of Scientific and Technical Information (OSTI.GOV)
Rastorfer, J.R.
1981-12-01
Bryological surveys and collections were made in order to assess the natural colonization of mosses (and liverworts) on acid minesoils of a reclamation demonstration site located adjacent to Goose Lake Prairie State Park in northeastern Illinois. Four types of fine-textured mineral soils were recognized within the site; these were designated as abandoned (cultivated) field soil, oil minesoil (spoil), reclaimed minesoil 1972 to 1973, and reclaimed minesoil 1975 to 1976. The two reclaimed minesoils were distinguished by reclamation efforts begun in 1972 and 1975. Thirty moss taxa and one liverwort species were found on the site, and two additional moss speciesmore » were found in areas adjacent to the site. Of the 33 bryophyte taxa recognized, 14 species of mosses were new reports for Grundy County. Comparative distribution patterns indicate that the major pioneer species of mosses on reclaimed minesoil were Barbula unguiculata, Ceratodon purpureus, Ditrichum pallidum, and Funaria hygrometrica. On the other hand, Bryum caespiticium and Weissia controversa were considered later seral species rather than primary invaders. Distribution patterns also indicate that mosses were generally unable to colonize unshaded bare reclaimed minesoil. However, moss colonization was successful in those areas where the harsh microhabitat conditions were ameliorated by vascular vegetation. Shoots of both living and dead higher plants most likely affect the proliferation of mosses by shading the soil surface, which results in increased moisture and decreased temperature at the soil surface in contrast to conditions of fully exposed soil.« less
NASA Astrophysics Data System (ADS)
Khaska, Mahmoud; Le Gal La Salle, Corinne; Sassine, Lara; Cary, Lise; Bruguier, Olivier; Verdoux, Patrick
2018-03-01
One decade after closure of the Salsigne mine (SW France), As contamination persisted in surface water, groundwater and soil near and down-gradient from the reclaimed ore processing site (OPS). We assess the fate of As and other associated chalcophilic MTEs, and their transport in the surface-water/groundwater/soil continuum down-gradient from the reclaimed OPS, using Sr-isotopic fingerprinting. The Sr-isotope ratio was used as a tracer of transfer processes in this hydro-geosystem and was combined to sequential extraction of soil samples to evaluate the impact of contaminated soil on the underlying phreatic groundwater. The contrast in Sr isotope compositions of the different soil fractions reflects several Sr sources in the soil. In the complex hydro-geosystem around the OPS, the transport of As and MTEs is affected by a succession of factors, such as (1) Existence of a reducing zone in the aquifer below the reclaimed OPS, where groundwater shows relatively high As and MTEs contents, (2) Groundwater discharge into the stream near the reclaimed OPS causing an increase in As and MTE concentrations in surface water; (3) Partial co-precipitation of As with Fe-oxyhydroxides, contributing to some attenuation of As contents in surface water; (4) Infiltration of contaminated stream water into the unconfined aquifer down-gradient from the reclaimed OPS; (5) Accumulation of As and MTEs in soil irrigated with contaminated stream- and groundwater; (6) Release of As and MTEs from labile soil fractions to underlying the groundwater.
Moura, Daniel R; Silveira, Maria L; O'Connor, George A; Wise, William R
2011-09-01
Rapid infiltration basins (RIBs) are effective tools for wastewater treatment and groundwater recharge, but continuous application of wastewater can increase soil P concentrations and subsequently impact groundwater quality. The objectives of this study were to (1) investigate the effects of reclaimed water infiltration rate and "age" of RIBs on soil P concentrations at various depths, and (2) estimate the degree (percentage) of sorption equilibrium reached between effluent P and soil attained during reclaimed water application to different RIBs. The study was conducted in four contrasting cells of a RIB system with up to a 25 year history of secondary wastewater application. Soil samples were collected from 0 to 300 cm depth at 30 cm intervals and analyzed for water extractable phosphorus (WEP) and oxalate extractable P, Al, and Fe concentrations. Water extractable P and P saturation ratio (PSR) values were generally greater in the cells receiving reclaimed water compared to control soils, suggesting that reclaimed water P application can increase soil P concentrations and the risk of P movement to greater depths. Differences between treatment and control samples were more evident in cells with longer histories of reclaimed water application due to greater P loading. Data also indicated considerable spatial variability in WEP concentrations and PSR values, especially within cells from RIBs characterized by fast infiltration rates. This occurs because wastewater-P flows through surface soils much faster than the minimum time required for sorption equilibrium to occur. Studies should be conducted to investigate soil P saturation at deeper depths to assess possible groundwater contamination.
Improving the properties of reclaimed asphalt pavement for roadway base applications.
DOT National Transportation Integrated Search
2012-08-01
The objective of this study was to improve Reclaimed Asphalt Pavements (RAP) strength in base course : applications while reducing creep to an acceptable level using compaction techniques, fractionating, : blending with high quality base course ag...
Sibrell, P.L.; Watten, B.; Boone, T.; ,
2003-01-01
A new process utilizing pulsed fluidized limestone beds was tested for the remediation of acid mine drainage at the Friendship Hill National Historic Site, in southwestern Pennsylvania. A 230 liter-per-minute treatment system was constructed and operated over a fourteen-month period from June 2000 through September 2001. Over this period of time, 50,000 metric tons of limestone were used to treat 50 million liters of water. The influent water pH was 2.5 and acidity was 1000 mg/L as CaCO3. Despite the high potential for armoring at the site, effluent pH during normal plant operation ranged from 5.7 to 7.8 and averaged 6.8. As a result of the high influent acidity, sufficient CO2 was generated and recycled to provide a net alkaline discharge with about 50 mg/L as CaCO3 alkalinity. Additions of commercial CO2 increased effluent alkalinity to as high as 300 mg/L, and could be a useful process management tool for transient high flows or acidities. Metal removal rates were 95% for aluminum (60 mg/L in influent), 50 to 90% for iron (Fe), depending on the ratio of ferrous to ferric iron, which varied seasonally (200 mg/L in influent), and <10% of manganese (Mn) (10 mg/L in influent). Ferrous iron and Mn removal was incomplete because of the high pH required for precipitation of these species. Iron removal could be improved by increased aeration following neutralization, and Mn removal could be effected by a post treatment passive settling/oxidation pond. Metal hydroxide sludges were settled in settling tanks, and then hauled from the site for aesthetic purposes. Over 450 metric tons of sludge were removed from the water over the life of the project. The dried sludge was tested by the Toxicity Characteristics Leaching Protocol (TCLP) and was found to be non-hazardous. Treatment costs were $43,000 per year and $1.08 per m 3, but could be decreased to $22,000 and $0.51 per m3 by decreasing labor use and by onsite sludge handling. These results confirm the utility of the new process in treatment of acid impaired waters that were previously not amenable to low cost limestone treatment.
Biocalcifying Bacillus subtilis cells effectively consolidate deteriorated Globigerina limestone.
Micallef, Roderick; Vella, Daniel; Sinagra, Emmanuel; Zammit, Gabrielle
2016-07-01
Microbially induced calcite precipitation occurs naturally on ancient limestone surfaces in Maltese hypogea. We exploited this phenomenon and treated deteriorated limestone with biocalcifying bacteria. The limestone was subjected to various mechanical and physical tests to present a statistically robust data set to prove that treatment was indeed effective. Bacillus subtilis conferred uniform bioconsolidation to a depth of 30 mm. Drilling resistance values were similar to those obtained for freshly quarried limestone (9 N) and increased up to 15 N. Treatment resulted in a high resistance to salt deterioration and a slow rate of water absorption. The overall percentage porosity of treated limestone varied by ±6 %, thus the pore network was preserved. We report an eco-friendly treatment that closely resembles the mineral composition of limestone and that penetrates into the porous structure without affecting the limestones' natural properties. The treatment is of industrial relevance since it compares well with stone consolidants available commercially.
Hoffmann, John P.; Carruth, Rob; Meyer, William
1998-01-01
A study of the geology, ground-water occurrence, and estimated well yields from the Mariana Limestone was done to investigate ground-water availability in the Kagman area, Saipan. The Mariana and Tagpochau Limestone formations form the major aquifer in the Kagman drainage basin. The Mariana Limestone, which is the major water-bearing unit in the Kagman area, ranges in thickness from 300 to 500 feet and contains intermittent, thin clay stringers. The calcareous rocks of the Tagpochau Limestone range in thickness from 500 to 1,000 feet and are more sandy than those of the Mariana Limestone. Ground water is unconfined in the Mariana Limestone and ranges from unconfined to confined in the Tagpochau Limestone. The fresh ground-water lens (that part of the lens with less than 2-percent of the chloride-ion concentration in seawater) in the Mariana Limestone is relatively thin, ranging from about 15 to 21 feet. Altitude of the water table ranges from about 1.5 to 2.5 feet above mean sea level. Freshwater in the Mariana Limestone is underlain by seawater and is separated by a transition zone about 8 to 25 feet thick. Hydraulic conductivity and transmissivity of the Mariana Limestone were calculated from data collected at six test wells. Using the Newman method, estimated hydraulic conductivity and transmissivity range from 290 to 2,500 feet per day and 7,600 to 62,000 feet squared per day, respectively. The higher values probably are indicative of average conditions in the Mariana Limestone. The estimated storage coefficient of the Mariana Limestone is about 0.1. The availability of water from the Mariana Limestone is restricted by the thinness of the freshwater lens. Results of the study indicate that fresh ground water can be obtained from the Mariana Limestone when wells are designed for minimum drawdown, effectively skimming freshwater from the top of the lens. Wells that are shallow, widely spaced, and pumped at low uniform rates can prevent saltwater intrusion. Calculated long-term yields of wells are about 30 gallons per minute or less for potable water.
O'Reilly, Andrew M.
1998-01-01
Wastewater reclamation and reuse has become increasingly popular as water agencies search for alternative water-supply and wastewater-disposal options. Several governmental agencies in central Florida currently use the land-based application of reclaimed water (wastewater that has been treated beyond secondary treatment) as a management alternative to surface-water disposal of wastewater. Water Conserv II, a water reuse project developed jointly by Orange County and the City of Orlando, began operation in December 1986. In 1995, the Water Conserv II facility distributed approximately 28 Mgal/d of reclaimed water for discharge to rapid-infiltration basins (RIBs) and for use as agricultural irrigation. The Reedy Creek Improvement District (RCID) began operation of RIBs in September 1990, and in 1995 these RIBs received approximately 6.7 Mgal/d of reclaimed water. Analyses of existing data and data collected during the course of this study were combined with ground-water flow modeling and particle-tracking analyses to develop a process-oriented evaluation of the regional effects of reclaimed water applied by Water Conserv II and the RCID RIBs on the hydrology of west Orange and southeast Lake Counties. The ground-water flow system beneath the study area is a multi-aquifer system that consists of a thick sequence of highly permeable carbonate rocks overlain by unconsolidated sediments. The hydrogeologic units are the unconfined surficial aquifer system, the intermediate confining unit, and the confined Floridan aquifer system, which consists of two major permeable zones, the Upper and Lower Floridan aquifers, separated by the less permeable middle semiconfining unit. Flow in the surficial aquifer system is dominated regionally by diffuse downward leakage to the Floridan aquifer system and is affected locally by lateral flow systems produced by streams, lakes, and spatial variations in recharge. Ground water generally flows laterally through the Upper Floridan aquifer aquifer to the north and east. Many of the lakes in the study area are landlocked because the mantled karst environment precludes a well developed network of surface-water drainage. The USGS three-dimensional ground-water flow model MODFLOW was used to simulate ground-water flow in the surficial and Floridan aquifer systems. A steady-state calibration to average 1995 conditions was performed by using a parameter estimation program to vary values of surficial aquifer system hydraulic conductivity, intermediate confining unit leakance, and Upper Floridan aquifer transmissivity. The calibrated model generally produced simulated water levels in close agreement with measured water levels and was used to simulate the hydrologic effects of reclaimed-water application under current (1995) and proposed future conditions. In 1995, increases of up to about 40 ft in the water table and less than 5 ft in the Upper Floridan aquifer potentiometric surface had occurred as a result of reclaimed-water application. The largest increases were under RIB sites. An average traveltime of 10 years at Water Conserv II and 7 years at the RCID RIBs was required for reclaimed water to move from the water table to the top of the Upper Floridan aquifer. Approximately 67 percent of the reclaimed water applied at the RCID RIB site recharged the Floridan aquifer system, whereas 33 percent discharged from the surficial aquifer system to surface-water features; 99 percent of the reclaimed water applied at Water Conserv II recharged the Floridan aquifer system, whereas only 1 percent discharged from the surficial aquifer system to surface-water features. The majority of reclaimed water applied at both facilities probably will ultimately discharge from the Floridan aquifer system outside the model boundaries. Proposed future conditions were assumed to consist of an additional 11.7 Mgal/d of reclaimed water distributed by the Water Conserv II and RCID facilities. Increases of up to about 20 ft in the water
Studied the geomorphogy, soil and water resources in south Egypt using geoinformation technology
NASA Astrophysics Data System (ADS)
Fayed, Abdalla; Abdel Aziz, Belal
2010-05-01
The mean objective of this study was to study the geomorphology, soil and water resources in the studied area using remote sensing techniques and GIS. The studied located in between latitudes 24o 20' and 24o 40' N and longitudes 32o 45' and 33o 40' E in Kom Ombo , Aswan governorate. The climatic situation of the studied area is characterized by a long hot dry summer, a short mild winter with little rainfall, high evaporation and low relative humidity. Based on the interpretation of ETM remote data, GIS and 3Dview the following natural resources were detected. The geomorpholical unites in the studied were Nile valley and Kom Ombo plain. Soil types were clay soil is occurred in the old cultivated land. But it is medium to coarse grained fluvial sand with gravel in the reclaimed areas. The land use and land cover for the studied area were old cultivated land, urban area and channels. Three main groundwater aquifers were confirmed, these are the Nubian sandstones aquifer, the Eocene fissured limestone aquifer and the Quaternary alluvial aquifer. Kom Ombo is the ancient site of Ombos, which is from the ancient Egyptian word ‘nubt', or ‘City of Gold'. In ancient Egypt, the city was important to the caravan routes from Nubia and various gold mines. Keywords: Remote sensing, GIS, 3D model, Natural Resources Kom Ombo
Feasibility of reclaimed asphalt pavement as aggregate in portland cement concrete pavements.
DOT National Transportation Integrated Search
2013-11-01
This research effort was focused on evaluating the feasibility of using minimally processed reclaimed : asphalt pavement (RAP) as aggregate replacement in concrete pavements. This research demonstrated : that concretes with up to 50 percent of the fi...
Preliminary investigation of RAP and RAS in HMAC : final report, February 2010.
DOT National Transportation Integrated Search
2010-02-01
A laboratory study was undertaken to investigate how various proportions of reclaimed asphalt pavement (RAP) and reclaimed asphalt shingles (RAS) added to hot mixed asphalt concrete (HMAC) mixtures affect the Superpave performance grade of the blende...
Reclaiming Indigenous Representations and Knowledges
ERIC Educational Resources Information Center
Iseke-Barnes, Judy; Danard, Deborah
2007-01-01
This article explores contemporary Indigenous artists', activists', and scholars' use of the Internet to reclaim Indigenous knowledge, culture, art, history, and worldview; critique the political realities of dominant discourse; and address the genocidal history and ongoing repression of Indigenous peoples. Indigenous Internet examples include…
Method and system to reclaim functional sites on a sorbent contaminated by heat stable salts
Krutka, Holly; Sjostrom, Sharon; Morris, William J.
2016-03-08
The objective of this invention is to develop a method to reclaim functional sites on a CO.sub.2 sorbent that have reacted with an acid gas (other than CO.sub.2) to form heat stable salts (HSS). HSS are a significant concern for dry sorbent based CO.sub.2 capture because over time the buildup of HSS will reduce the overall functionality of the CO.sub.2 sorbent. A chemical treatment can remove the non-CO.sub.2 acid gas and reclaim functional sites that can then be used for further CO.sub.2 adsorption.
Process material management in the Space Station environment
NASA Technical Reports Server (NTRS)
Perry, J. L.; Humphries, W. R.
1988-01-01
The Space Station will provide a unique facility for conducting material-processing and life-science experiments under microgravity conditions. These conditions place special requirements on the U.S. Laboratory for storing and transporting chemicals and process fluids, reclaiming water from selected experiments, treating and storing experiment wastes, and providing vacuum utilities. To meet these needs and provide a safe laboratory environment, the Process Material Management System (PMMS) is being developed. Preliminary design requirements and concepts related to the PMMS are addressed, and the MSFC PMMS breadboard test facility and a preliminary plan for validating the overall system design are discussed.
CALCIUM CARBONATE DISSOLUTION RATE IN LIMESTONE CONTACTORS
The rate of carbonate mineral dissolution from limestone was studied using a rotating disk apparatus and samples of limestone of varied composition. The purpose of this study was to determine the effect of limestone composition on the kinetics of carbonate mineral dissolution. Th...
Geology of an area near Brentwood, Williamson County, Tennessee
Hanchar, D.W.
1988-01-01
The geology and structure of an area near Brentwood, Williamson County, Tennessee, were studied to define the potential aquifers and confining units that comprise the groundwater flow system of the area. Four different formations were identified. These formations are, in descending order, the Bigby-Cannon Limestone, the Hermitage Formation, the Carters Limestone, and the Lebanon Limestone. The Bigby-Cannon Limestone and the Hermitage Formation have been affected by recent erosion. Any variation of the Carters Limestone is controlled by pre-Carters erosion of the top of the Lebanon Limestone. The thickness of this formation ranges from 65 to 79 ft. A small scale anticline-syncline pair is evident. This structure is not a result of erosion and also occurs in the T-3 bentonite bed in the Carters Limestone. (USGS)
Development of a non-solvent based test method for evaluating reclaimed asphalt pavement mixes.
DOT National Transportation Integrated Search
2004-09-01
The percent of reclaimed asphalt pavement (RAP) used in hot mix asphalt (HMA) is currently established either by arbitrarily setting maximum percent limits, or alternatively, by evaluating both the virgin and recovered binder properties. The first ap...
7 CFR 160.4 - Reclaimed rosin.
Code of Federal Regulations, 2010 CFR
2010-01-01
... Regulations of the Department of Agriculture (Continued) AGRICULTURAL MARKETING SERVICE (Standards... contaminating component remaining from the waste material itself or from any article used in the recovery process is not sufficient to cause the physical or chemical properties of the reclaimed product to differ...
Improving the properties of reclaimed asphalt pavement for roadway base applications [summary].
DOT National Transportation Integrated Search
2012-01-01
Over 90 percent of : U.S. roads are paved : with asphalt, which : must be periodically : resurfaced. Milling : produces reclaimed : asphalt pavement (RAP), : which can be recycled : in hot-mix asphalt, : but at no more than : 25%. Therefore, much : R...
Fox, P; Narayanaswamy, K; Genz, A; Drewes, J E
2001-01-01
Water quality transformations during soil aquifer treatment at the Mesa Northwest Water Reclamation Plant (NWWRP) were evaluated by sampling a network of groundwater monitoring wells located within the reclaimed water plume. The Mesa Northwest Water Reclamation Plant has used soil aquifer treatment (SAT) since it began operation in 1990 and the recovery of reclaimed water from the impacted groundwater has been minimal. Groundwater samples obtained represent travel times from several days to greater than five years. Samples were analyzed for a wide range of organic and inorganic constituents. Sulfate was used as a tracer to estimate travel times and define reclaimed water plume movement. Dissolved organic carbon concentrations were reduced to approximately 1 mg/L after 12 to 24 months of soil aquifer treatment with an applied DOC concentration from the NWWRP of 5 to 7 mg/L. The specific ultraviolet absorbance (SUVA) increased during initial soil aquifer treatment on a time-scale of days and then decreased as longer term soil aquifer treatment removed UV absorbing compounds. The trihalomethane formation potential (THMFP) was a function of the dissolved organic carbon concentration and ranged from 50 to 65 micrograms THMFP/mg DOC. Analysis of trace organics revealed that the majority of trace organics were removed as DOC was removed with the exception of organic iodine. The majority of nitrogen was applied as nitrate-nitrogen and the reclaimed water plume had lower nitrate-nitrogen concentrations as compared to the background groundwater. The average dissolved organic carbon concentrations in the reclaimed water plume were less than 50% of the drinking water dissolved organic concentrations from which the reclaimed water originated.
Soil quality index for evaluation of reclaimed coal mine spoil.
Mukhopadhyay, S; Masto, R E; Yadav, A; George, J; Ram, L C; Shukla, S P
2016-01-15
Success in the remediation of mine spoil depends largely on the selection of appropriate tree species. The impacts of remediation on mine soil quality cannot be sufficiently assessed by individual soil properties. However, combination of soil properties into an integrated soil quality index provides a more holistic status of reclamation potentials of tree species. Remediation potentials of four tree species (Acacia auriculiformis, Cassia siamea, Dalbergia sissoo, and Leucaena leucocephala) were studied on reclaimed coal mine overburden dumps of Jharia coalfield, Dhanbad, India. Soil samples were collected under the canopies of the tree species. Comparative studies on the properties of soils in the reclaimed and the reference sites showed improvements in soil quality parameters of the reclaimed site: coarse fraction (-20.4%), bulk density (-12.8%), water holding capacity (+0.92%), pH (+25.4%), EC (+2.9%), cation exchange capacity (+46.6%), organic carbon (+91.5%), N (+60.6%), P (+113%), K (+19.9%), Ca (+49.6%), Mg (+12.2%), Na (+19.6%), S (+46.7%), total polycyclic aromatic hydrocarbons (-71.4%), dehydrogenase activity (+197%), and microbial biomass carbon (+115%). Principal component analysis (PCA) was used to identify key mine soil quality indicators to develop a soil quality index (SQI). Selected indicators include: coarse fraction, pH, EC, soil organic carbon, P, Ca, S, and dehydrogenase activity. The indicator values were converted into a unitless score (0-1.00) and integrated into SQI. The calculated SQI was significantly (P<0.001) correlated with tree biomass and canopy cover. Reclaimed site has 52-93% higher SQI compared to the reference site. Higher SQI values were obtained for sites reclaimed with D.sissoo (+93.1%) and C.siamea (+86.4%). Copyright © 2015 Elsevier B.V. All rights reserved.
[Study on the advanced pre-treatments of reclaimed water used for groundwater recharge].
Gao, Yu-Tuan; Zhang, Xue; Zhao, Xuan; Zhao, Gang
2012-03-01
To prevent groundwater contamination, pretreatments of reclaimed water are needed before the groundwater recharge. In this study, five treatments, including ultrafiltration (UF), ozonation, magnetic ion exchange (MIEX), UF coupled with ozonation and MIEX coupled with ozonation, were evaluated for their purification efficiencies of the reclaimed water and their influences on the following soil aquifer treatments. For organic matters in the secondary effluents, identified as dissolved organic carbon (DOC) and specific ultraviolet absorbance (SUVA), 20% DOC and 10% SUVA are removed by MIEX treatment with dose of 5 mL x L(-1), while only 10% DOC and no SUVA are removed by UF, but neither of these two pretreatments enhance the purification of soil aquifer treatments. Differently, SUVA of the secondary effluents are removed by 60%-79% by ozonation alone or coupled with UF/MIEX, increasing the biodegradability of the reclaimed water. These pretreatments significantly enhance the removal of organic matters by the following soil aquifer with DOC in the final effluents reducing to 1-2 mg x L(-1). For nitrogen, MIEX can remove 25% NO3(-) -N, and ozonation can remove 72% NH4(+) -N. The soil aquifer treatment could efficiently remove NH4(+) -N to below 0.5 mg x L(-1), while no obvious removal is detected for NO3(-) -N. In conclusion, more attentions should be paid to the organic matters and NO3(-) -N during the pretreatments of reclaimed water. Among all the pretreatments tested here, ozonation coupled with MIEX is capable of increasing the biodegradability of the reclaimed water and removing NO3(-) -N, which is a good choice for the pretreatment of groundwater recharge.
Aggregate-associated carbon and nitrogen in reclaimed sandy loam soils
DOE Office of Scientific and Technical Information (OSTI.GOV)
Wick, A.F.; Stahl, P.D.; Ingram, L.J.
2009-11-15
Minimal research has been conducted on aggregate, C, and N in coarse-textured soils used to reclaim surface coal mine lands. Furthermore, little is known about the contribution different plant communities make to the recovery of aggregation in these soils. Two chronosequences of semiarid reclaimed sites with sandy loam soils were sampled under shrub- and grass-dominated communities. Aggregation, aggregate fractions, and associated C and N were measured. No definitive trends of increasing macroaggregates between sites were observed undershrubs; however, macro- and microaggregation was greater in the 16-yr-old (0.20 and 0.23 kg aggregate kg{sup -1} soil, respectively) than in the 5-yr-old soilsmore » (0.02 and 0.08 kg aggregate kg{sup -1} soil, respectively) under grasses. Although C and N concentrations were drastically reduced (50-75%) with mining activity between the <1-yr-old and native soils, aggregate C and N concentrations tinder shrubs and grasses were similar to each other and to the native soils in the 5-yr-old site. Sods under grass in the 16-yr-old site had lower available and aggregate-occluded C and N concentrations than the 5-yr-old site, while C and N concentrations did not change between 5- and 16-yr-old soils under shrubs. Conversely, aggregate C and N pool sizes under shrubs and grasses both increased with site age to conditions similar to those observed in the native soil. Reclaimed shrub site soils had consistently higher C concentrations in the older reclaimed sites (10 and 16 yr old) than the soils under grasses, indicating greater accumulation and retention of C and N in organic material under shrub than grass communities in semiarid reclaimed sites.« less
Exploration for limestone deposit at Onigbedu, South-Western Nigeria
NASA Astrophysics Data System (ADS)
Oyedele, Kayode F.; Oladele, Sunday; Emakpor, Charles A.
2016-09-01
The Onigbedu limestone deposit was investigated using the aeromagnetic data, resistivity soundings and borings with the aim of characterizing the limestone deposit and estimating its reserves. The subsurface structural features and depth to basement were identified with the analysis of aeromagnetic data. Twenty nine boreholes were drilled for subsurface appraisal and correlation of the limestone deposit. Eighty nine Vertical Electrical Sounding (VES) were acquired using the Schlumberger array. The results showed NE-SW trending lineaments that segmented the limestone. Depth to basement varied from 144.2 m to 1090 m. The VES results showed four to six layers indicating the topsoil (7-315 Ωm), clay (2-25 Ωm), shale (6-31 Ωm), limestone (20-223 Ωm), sandstone (>200 Ωm) and sandy materials. The VES results correlated well with the lithological unit delineated from the borehole. The overburden thickness ranged from 3.3 m to 28 m, while the limestone thickness varies between 18.1 m and 48.3 m. The limestone reserve was estimated at 1.9 × 109 t. This study concluded that the study area had vast occurrence of the limestone deposits, which would be of economic importance, if exploited.
DOE Office of Scientific and Technical Information (OSTI.GOV)
Bizzozero, Julien, E-mail: julien.bizzozero@gmail.com; Scrivener, Karen L.
This paper reports a study of ternary blends composed of calcium aluminate cement, calcium sulfate hemihydrate and limestone. Compressive strength tests and hydration kinetics were studied as a function of limestone and calcium sulfate content. The phase evolution and the total porosity were followed and compared to thermodynamic simulation to understand the reactions involved and the effect of limestone on these binders. The reaction of limestone leads to the formation of hemicarboaluminate and monocarboaluminate. Increasing the ratio between sulfate and aluminate decreases the extent of limestone reaction.
Science Discovers the Reclaiming Approach
ERIC Educational Resources Information Center
Brown, Darren
2008-01-01
Pioneers in reclaiming youth sought to build relationships and environments that responded to the needs of "wayward youth." Now, neuroscience and trauma research show the primacy of human connections in assessment, treatment, and youth development. Interventions with challenging children and youth are now being evaluated against principles…
DOT National Transportation Integrated Search
2015-10-01
Each year, the US highway : industry produces : over 100 million tons : of reclaimed asphalt : pavement (RAP) through : standard rehabilitation and : construction of the nations : roads. Although this product : has been reused in several : applica...
40 CFR 428.96 - Pretreatment standards for new sources.
Code of Federal Regulations, 2012 CFR
2012-07-01
... GUIDELINES AND STANDARDS (CONTINUED) RUBBER MANUFACTURING POINT SOURCE CATEGORY Pan, Dry Digestion, and... this section and attributable to pan, dry digestion, and mechanical reclaimed rubber processes which are integrated with a wet digestion reclaimed rubber process, which may be discharged to a publicly...
40 CFR 428.96 - Pretreatment standards for new sources.
Code of Federal Regulations, 2014 CFR
2014-07-01
... GUIDELINES AND STANDARDS (CONTINUED) RUBBER MANUFACTURING POINT SOURCE CATEGORY Pan, Dry Digestion, and... this section and attributable to pan, dry digestion, and mechanical reclaimed rubber processes which are integrated with a wet digestion reclaimed rubber process, which may be discharged to a publicly...
40 CFR 428.96 - Pretreatment standards for new sources.
Code of Federal Regulations, 2013 CFR
2013-07-01
... GUIDELINES AND STANDARDS (CONTINUED) RUBBER MANUFACTURING POINT SOURCE CATEGORY Pan, Dry Digestion, and... this section and attributable to pan, dry digestion, and mechanical reclaimed rubber processes which are integrated with a wet digestion reclaimed rubber process, which may be discharged to a publicly...
Effect of Reclaimed Asphalt Pavement on Binder Properties Using the Superpave System
DOT National Transportation Integrated Search
1998-09-01
While the use of reclaimed asphalt pavement (RAP) in asphalt mixes is common practice within many state departments of transportation, the evolution of the Superpave system has prompted a need for specific Superpave guidelines for the use of RAP. In ...
JSC ECLSS R/T Program Overview
NASA Technical Reports Server (NTRS)
Behrend, A. F.
1990-01-01
Viewgraphs on Johnson Space Center Environmental Control and Life Support System (ECLSS) research and technology program overview are presented. Topics covered include: advancements in electrochemical CO2 removal; supercritical water waste oxidation; electrooxidation for post-treatment of reclaimed water; and photocatalytic post-treatment of reclaimed water.
SOURCE ASSESSMENT: RECLAIMING OF WASTE SOLVENTS, STATE OF THE ART
This document reviews the state of the art of air emissions from the reclaiming of waste solvents. The composition, quantity, and rate of emissions are described. Waste solvents are organic dissolving agents which are contaminated with suspended and dissolved solids, organics, wa...
DOT National Transportation Integrated Search
2015-10-01
This research was focused on evaluating the feasibility of using minimally processed reclaimed asphalt pavement (RAP) as : aggregate replacement in concrete pavements. An initial phase of research demonstrated that concretes with up to 50 percent : o...
DOT National Transportation Integrated Search
2015-04-01
In this study, a total of 28 mixture combinations were designed and evaluated to : determine the maximum allowable amount of reclaimed asphalt pavement (RAP) : material in friction courses without jeopardizing pavement cracking performance. The : exp...
Bayat, Ali Esfandyari; Junin, Radzuan; Shamshirband, Shahaboddin; Chong, Wen Tong
2015-09-16
Engineered aluminum oxide (Al2O3), titanium dioxide (TiO2), and silicon dioxide (SiO2) nanoparticles (NPs) are utilized in a broad range of applications; causing noticeable quantities of these materials to be released into the environment. Issues of how and where these particles are distributed into the subsurface aquatic environment remain as major challenges for those in environmental engineering. In this study, transport and retention of Al2O3, TiO2, and SiO2 NPs through various saturated porous media were investigated. Vertical columns were packed with quartz-sand, limestone, and dolomite grains. The NPs were introduced as a pulse suspended in aqueous solutions and breakthrough curves in the column outlet were generated using an ultraviolet-visible spectrophotometer. It was found that Al2O3 and TiO2 NPs are easily transported through limestone and dolomite porous media whereas NPs recoveries were achieved two times higher than those found in the quartz-sand. The highest and lowest SiO2-NPs recoveries were also achieved from the quartz-sand and limestone columns, respectively. The experimental results closely replicated the general trends predicted by the filtration and DLVO calculations. Overall, NPs mobility through a porous medium was found to be strongly dependent on NP surface charge, NP suspension stability against deposition, and porous medium surface charge and roughness.
Irrigation water quality influences heavy metal uptake by willows in biosolids.
Laidlaw, W Scott; Baker, Alan J M; Gregory, David; Arndt, Stefan K
2015-05-15
Phytoextraction is an effective method to remediate heavy metal contaminated landscapes but is often applied for single metal contaminants. Plants used for phytoextraction may not always be able to grow in drier environments without irrigation. This study investigated if willows (Salix x reichardtii A. Kerner) can be used for phytoextraction of multiple metals in biosolids, an end-product of the wastewater treatment process, and if irrigation with reclaimed and freshwater influences the extraction process. A plantation of willows was established directly onto a tilled stockpile of metal-contaminated biosolids and irrigated with slightly saline reclaimed water (EC ∼2 dS/cm) at a wastewater processing plant in Victoria, Australia. Biomass was harvested annually and analysed for heavy metal content. Phytoextraction of cadmium, copper, nickel and zinc was benchmarked against freshwater irrigated willows. The minimum irrigation rate of 700 mm per growing season was sufficient for willows to grow and extract metals. Increasing irrigation rates produced no differences in total biomass and also no differences in the extraction of heavy metals. The reclaimed water reduced both the salinity and the acidity of the biosolids significantly within the first 12 months after irrigation commenced and after three seasons the salinity of the biosolids had dropped to <15% of initial values. A flushing treatment to remove excess salts was therefore not necessary. Irrigation had an impact on biosolids attributes such as salinity and pH, and that this had an influence on metal extraction. Reclaimed water irrigation reduced the biosolid pH and this was associated with reductions of the extraction of Ni and Zn, it did not influence the extraction of Cu and enhanced the phytoextraction of Cd, which was probably related to the high chloride content of the reclaimed water. Our results demonstrate that flood-irrigation with reclaimed water was a successful treatment to grow willows in a dry climate. However, the reclaimed water can also change biosolids properties, which will influence the effectiveness of willows to extract different metals. Copyright © 2015 Elsevier Ltd. All rights reserved.
BESIII physical offline data analysis on virtualization platform
NASA Astrophysics Data System (ADS)
Huang, Q.; Li, H.; Kan, B.; Shi, J.; Lei, X.
2015-12-01
In this contribution, we present an ongoing work, which aims at benefiting BESIII computing system for higher resource utilization and more efficient job operations brought by cloud and virtualization technology with Openstack and KVM. We begin with the architecture of BESIII offline software to understand how it works. We mainly report the KVM performance evaluation and optimization from various factors in hardware and kernel. Experimental results show the CPU performance penalty of KVM can be approximately decreased to 3%. In addition, the performance comparison between KVM and physical machines in aspect of CPU, disk IO and network IO is also presented. Finally, we present our development work, an adaptive cloud scheduler, which allocates and reclaims VMs dynamically according to the status of TORQUE queue and the size of resource pool to improve resource utilization and job processing efficiency.
Test results on reuse of reclaimed shower water - A summary
NASA Technical Reports Server (NTRS)
Verostko, Charles E.; Garcia, Rafael; Sauer, Richard; Reysa, Richard P.; Linton, Arthur T.
1989-01-01
Results are presented from tests to evaluate a microgravity whole body shower and waste water recovery system design for possible use on the Space Station. Several water recovery methods were tested, including phase change distillation, a thermoelectric hollow fiber membrane evaporation subsystem, and a reverse osmosis dynamic membrane system. Consideration is given to the test hardware, the types of soaps evaluated, the human response to showering with reclaimed water, chemical treatment for microbial control, the procedures for providing hygienic water, and the quality of water produced by the systems. All three of the waste water recovery systems tested successfully produced reclaimed water for reuse.
Reinvasion of small mammals, reptiles, amphibians and insects on a reclaimed coal strip-mine
DOE Office of Scientific and Technical Information (OSTI.GOV)
Ireland, T.T.; Schemnitz, S.D.; Wolters, G.L.
1990-12-31
We conducted wildlife and vegetation sampling on sites reclaimed in 1979, 1982, and 1986, as well as unmined sites, on The Pittsburgh & Midway (P&M) Coal Mining Co.`s McKinley Mine in McKinley County, New Mexico. In June, July, and August 1988 and 1989 we samples small mammals, reptiles, amphibians and insects. Soil and vegetation sampling was conducted in July and September 1988, respectively. We found several significant differences (P < 0.05) among plant and animal data that may have suggested differences between study sites. Recent reclamation procedures conducted or proposed by P&M promise increased wildlife value of reclaimed sites.
Dugas, D.L.; Cravotta, C.A.; Saad, D.A.
1993-01-01
Water-quality and other hydrologic data for two surface coal mines in Clarion County, Pa., were collected during 1983-89 as part of studies conducted by the U.S. Geological Survey in cooperation with the Pennsylvania Department of Environmental Resources. Water samples were collected from streams, seeps, monitor wells, and lysimeters on a monthly basis to evaluate changes in water quality resulting from the addition of alkaline waste or urban sewage sludge to the reclaimed mine-spoil surface. The mines are about 3.5 miles apart and were mined for bituminous coal of the upper and lower Clarion seams of the Allegheny Group of Pennsylvanian age. The coal had high sulfur (greater than 2 weight percent) concentrations. Acidic mine drainage is present at both mines. At one mine, about 8 years after mining was completed, large quantities (greater than 400 tons per acre) of alkaline waste consisting of limestone and lime-kiln flue dust were applied on two 2.5-acre plots within the 65-acre mine area. Water-quality data for the alkaline-addition plots and surrounding area were collected for 1 year before and 3 years after application of the alkaline additives (May 1983-July 1987). Data collected for the alkaline-addition study include ground-water level, surface-water discharge rate, temperature, specific conductance, pH, and concentrations of alkalinity, acidity, sulfate, iron (total and ferrous), manganese, aluminum, calcium, and magnesium. At the other mine, about 3.5 years after mining was completed, urban sewage sludge was applied over 60 acres within the 150-acre mine area. Waterquality data for the sludge-addition study were collected for 3.5 years after the application of the sludge (June 1986-December 1989). Data collected for the sludge-addition study include the above constituents plus dissolved oxygen, redox potential (Eh), and concentrations of dissolved solids, phosphorus, nitrogen species, sulfide, chloride, silica, sodium, potassium, cyanide, arsenic, barium, boron, cadmium, chromium, copper, lead, mercury, molybdenum, nickel, selenium, strontium, and zinc. Climatic data, including monthly average temperature and cumulative precipitation, from a nearby weather station for the period January 1983 through December 1989 also are reported.
Mineralogical characterization of the Shelburne marble and the Salem limestone
DOE Office of Scientific and Technical Information (OSTI.GOV)
McGee, E.S.
Samples of Shelburne marble and Salem limestone were selected to represent marbles and limestones used in buildings and monuments. The Royal variety of Shelburne marble is a white marble predominantly composed of calcite but has heterogeneously distributed gray inclusions. The select buff Salem limestone is a beige, homogeneous, fossiliferous limestone, predominantly composed of fragments of echinoderms and bryozoans. The author reports that both samples are appropriate test stones for the National Acid Precipitation Assessment Program stone exposure studies.
Organic amendments and nutrient leaching in soil columns
USDA-ARS?s Scientific Manuscript database
The lack of nutrient build up in reclaimed coal mine soils would therefore require additional inputs to maintain plant productivity and establishment of a healthy ecosystem. In a greenhouse experiment, reclaimed coal mine soil were amended with fresh and composted poultry manure at the rates based ...
Reclaiming Accountability in Teacher Education
ERIC Educational Resources Information Center
Cochran-Smith, Marilyn; Carney, Molly Cummings; Keefe, Elizabeth Stringer; Burton, Stephani; Chang, Wen-Chia; Fernández, M. Beatriz; Miller, Andrew F.; Sánchez, Juan Gabriel; Baker, Megina
2018-01-01
Teacher accountability has been a major strategy for "fixing" education for the last 2 decades. In this book, Cochran-Smith and her research team argue that it is time for teacher educators to reclaim accountability by adopting a new approach that features intelligent professional responsibility, challenges the structures and processes…
DOT National Transportation Integrated Search
2014-11-01
This study investigated the effect of added asphalt : binder content on the performance and volumetric p : roperties of : asphalt concrete mixtures containing reclaimed asph : alt pavement (RAP) in the amounts of 0%, 20%, and 4 : 0%. A laboratory- : ...
Levi’s Stadium Reuses Redwood From Hangar One
2016-02-02
The San Francisco 49ers used recycled redwood in their new stadium that was reclaimed during the deskinning of Moffett Field's Hangar One. By including locally sourced and reclaimed material, Levi's Stadium was granted LEED Gold certification, becoming the first football stadium to achieve that sustainability status.
DOT National Transportation Integrated Search
2001-01-01
This manual is a reference guide for mix design and field testing technicians who deal with reclaimed asphalt pavement (RAP) in Superpave mixtures. It will provide detailed descriptions and examples of each step involved in designing and testing a Su...
Feasibility of reclaimed asphalt pavement (RAP) use as road base and subbase material.
DOT National Transportation Integrated Search
2015-01-01
The purpose of this study was to investigate the current state of the practice with regard to the use of reclaimed asphalt : pavement (RAP) material for road base and subbase applications and the potential for such use by the Virginia Department of :...
NASA Astrophysics Data System (ADS)
Thanya, I. N. A.; Suweda, I. W.; Putra, G. K.
2018-03-01
Demands on natural aggregate materials for road pavement can be reduced by utilizing reclaimed asphalt pavement (RAP). This research was aimed at evaluating the performance of AC-WC mixture using RAP materials from cold milling, bound with 80/100 pen asphalt. The RAP aggregate gradation was adjusted by adding the required amount of natural aggregates to meet the specification in Indonesia. The RAP and added aggregates were hotmixed and compacted with Marshall hummer at 2×75 blows. The asphalt content were varied. It was found that the optimum asphalt content was 6.05 % with the following Marshall characteristics: stability 1237.08 kg; flow 3.36 mm; Marshall quotient 324,73kg/mm; void in mix (VIM) 3,360%; void in mineral aggregate (VMA) 15.103; and void filled with bitumen (VFB) 77.759% and residual stability 91.04; all met the Indonesian specification. The cantabro abration loss (CAL) at 30°C was 9,02%. The indirect tensile stiffness modulus (ITSM) at 20 °C was 7961.4 MPa; dynamic creep with 100 kPa pressure at 40°C gave slope 0.0112 microsstrain/pulse which is suitable for heavy load traffic. The fatigue test results was obtained at increased stress level, i.e. at 900, 1100, and 1300 kPa. Based on the equation derived from the fatigue strain and repeated loading relationship, at 100 microstrain (με) the repeated load was 434,661.58 times, and at one million (106) repeated loading, the samples could withstand strain of 92,38 microstrain. The performance of the samples were overall better than AC-WC mixture using virgin aggregates bound with 60/70 pen asphalt.
Recovery of Navy distillate fuel from reclaimed product. Volume II. Literature review
DOE Office of Scientific and Technical Information (OSTI.GOV)
Brinkman, D.W.; Whisman, M.L.
In an effort to assist the Navy to better utilize its waste hydrocarbons, NIPER, with support from the US Department of Energy, is conducting research designed to ultimately develop a practical technique for converting Reclaimed Product (RP) into specification Naval Distillate Fuel (F-76). This first phase of the project was focused on reviewing the literature and available information from equipment manufacturers. The literature survey has been carefully culled for methodology applicable to the conversion of RP into diesel fuel suitable for Navy use. Based upon the results of this study, a second phase has been developed and outlined in whichmore » experiments will be performed to determine the most practical recycling technologies. It is realized that the final selection of one particular technology may be site-specific due to vast differences in RP volume and available facilities. A final phase, if funded, would involve full-scale testing of one of the recommended techniques at a refueling depot. The Phase I investigations are published in two volumes. Volume 1, Technical Discussion, includes the narrative and Appendices I and II. Appendix III, a detailed Literature Review, includes both a narrative portion and an annotated bibliography containing about 800 references and abstracts. This appendix, because of its volume, has been published separately as Volume 2.« less
Huang, Xingru; Xiong, Wei; Liu, Wei; Guo, Xiaoyu
2017-05-01
In order to evaluate the impact of reclaimed water on the ecology of bacterial communities in the Typha angustifolia L. rhizosphere soil, bacterial community structure was investigated using a combination of terminal restriction fragment length polymorphism and 16S rRNA gene clone library. The results revealed significant spatial variation of bacterial communities along the river from upstream and downstream. For example, a higher relative abundance of γ-Proteobacteria, Firmicutes, Chloroflexi and a lower proportion of β-Proteobacteria and ε-Proteobacteria was detected at the downstream site compared to the upstream site. Additionally, with an increase of the reclaimed water interference intensity, the rhizosphere bacterial community showed a decrease in taxon richness, evenness and diversity. The relative abundance of bacteria closely related to the resistant of heavy-metal was markedly increased, while the bacteria related for carbon/nitrogen/phosphorus/sulfur cycling wasn't strikingly changed. Besides that, the pathogenic bacteria markedly increased in the downstream rhizosphere soil since reclaimed water supplement, while the possible plant growth-promoting rhizobacteria obviously reduced in the downstream sediment. Together these data suggest cause and effect between reclaimed water input into the wetland, shift in bacterial communities through habitat change, and alteration of capacity for biogeochemical cycling of contaminants. Copyright © 2016. Published by Elsevier B.V.
Latif-Eugenín, Fadua; Beaz-Hidalgo, Roxana; Silvera-Simón, Carolina; Fernandez-Cassi, Xavi; Figueras, María J
2017-04-01
Wastewater is increasingly being recognized as a key water resource, and reclaimed water (or treated wastewater) is used for irrigating vegetables destined for human consumption. The aim of the present study was to determine the diversity and prevalence of Aeromonas spp. both in reclaimed water used for irrigation and in the three types of vegetables irrigated with that water. Seven of the 11 (63.6%) samples of reclaimed water and all samples of vegetables were positive for the presence of Aeromonas. A total of 216 Aeromonas isolates were genotyped and corresponded to 132 different strains that after identification by sequencing the rpoD gene belonged to 10 different species. The prevalence of the species varied depending on the type of sample. In the secondary treated reclaimed water A. caviae and A. media dominated (91.4%) while A. salmonicida, A. media, A. allosaccharophila and A. popoffii represented 74.0% of the strains in the irrigation water. In vegetables, A. caviae (75.0%) was the most common species, among which a strain isolated from lettuce had the same genotype (ERIC pattern) as a strain recovered from the irrigation water. Furthermore, the same genotype of the species A. sanarellii was recovered from parsley and tomatoes demonstrating that irrigation water was the source of contamination and confirming the risk for public health. Copyright © 2017 Elsevier Inc. All rights reserved.
Cui, Yong; Liu, Shuming; Smith, Kate; Yu, Kanghua; Hu, Hongying; Jiang, Wei; Li, Yuhong
2016-01-01
To reveal corrosion behavior of stainless steel delivery pipe used in reclaimed water treatment, this research focused on the morphological, mineralogical and chemical characteristics of stainless steel corrosion scale and corroded passive film. Corrosion scale and coupon samples were taken from a type 304 pipe delivering reclaimed water to a clear well in service for more than 12 years. Stainless steel corrosion scales and four representative pipe coupons were investigated using mineralogy and material science research methods. The results showed corrosion scale was predominantly composed of goethite, lepidocrocite, hematite, magnetite, ferrous oxide, siderite, chrome green and chromite, the same as that of corroded pipe coupons. Hence, corrosion scale can be identified as podiform chromite deposit. The loss of chromium in passive film is a critical phenomenon when stainless steel passive film is damaged by localized corrosion. This may provide key insights toward improving a better comprehension of the formation of stainless steel corrosion scale and the process of localized corrosion. The localized corrosion behavior of stainless steel is directly connected with reclaimed water quality parameters such as residual chlorine, DO, Cl(-) and SO4(2-). In particular, when a certain amount of residual chlorine in reclaimed water is present as an oxidant, ferric iron is the main chemical state of iron minerals. Copyright © 2015 Elsevier Ltd. All rights reserved.
How partial nitrification could improve reclaimed wastewater transport in long pipes.
Delgado, S; Alvarez, M; Rodríguez-Gómez, L E; Elmaleh, S; Aguiar, E
2001-01-01
Reclaimed wastewater transport is studied in a concrete-lined cast iron pipe, where a nitrification-denitrification process occurs. The pipe is part of the Reuse System of Reclaimed Wastewater of South Tenerife (Spain), 0.6 m in diameter and 61 km long. In order to improve wastewater quality, at 10 km from the inlet there is injection of fresh water saturated in dissolved oxygen (DO), after which a fast nitrification process usually appears (less than two hours of space time). The amount of oxidized nitrogen compounds produced varies between 0.8 and 4.4 mg/l NOx(-)-N. When DO has disappeared, a denitrification process begins. The removal of nitrite is complete at the end of the pipe, whereas the nitrate does not disappear completely, leaving a concentration of about 0.4-0.5 mg/l. For a COD/NOx(-)-N ratio higher than 5, a first order nitrification rate in NOx(-)-N has resulted, with the constant k20 = 0.079 h-1, for a NOx(-)-N concentration range of 0.8-4.4 mg/l. Finally the following temperature dependency for the first order denitrification rate constant has been found: k = k20 x 1 x 15T-20. Although nitrogen could be used as nutrient in the agricultural reuse, its removal from reclaimed wastewater could be useful in order to diminish the chlorine needs for reclaimed wastewater disinfection.
Heavy Metal Contaminated Soil Treatment: Conceptual Development
1987-02-01
utilized, particularly for trivalent chromium . ’Breakthrough did eventually occur, due to the coating of the crushed limestone, with only partial...characterizations indicated that several Army installations had elevated total metal concentrations in their soils and Chromium , Cadmium and Lead were the most...2,2000 F) were effective in reducing chromium levels below 1 mg/L in both boiling water and weak acid (pH 5; H2 SO 4) extractions. These extractions were
DOE Office of Scientific and Technical Information (OSTI.GOV)
McGee, E.S.
The Salem Limestone and the Shelburne Marble are representative of limestones and marbles commonly used in buildings and monuments. Both stones are composed predominantly of calcite. The Salem Limestone is homogeneous in composition and mineralogic characteristics throughout the test block. The Shelburne Marble has compositionally homogeneous mineral phases, but the distribution of those phases within the test block is random. The mineralogy and physical characteristics of the Shelburne Marble and Salem Limestone test blocks described in the study provide a baseline for future studies of the weathering behavior of these stones. Because the Shelburne Marble and the Salem Limestone aremore » representative of typical commercial marbles and limestones, they are likely to be useful in a consortium study of the effects of acid precipitation on these two types of building stones.« less
Buono, A.; Rutledge, A.T.
1978-01-01
This map depicts the approximate top of the rock that composes the Floridan aquifer. The contours represent the elevation of the top of the Floridan aquifer to mean sea level. Rock units recognized to be part of the Floridan aquifer are limestone and dolomite ranging from middle Eocene to early Miocene. They are Lake City Limestone, Avon Park Limestone, Ocala Limestone, Suwannee Limestone, and Tampa Limestone. In this report, the top of the Floridan aquifer is a limestone defined as the first consistent rock of early Miocene age or older below which occur no clay confining beds. Although the Hawthorn formation of middle Miocene is considered part of the Floridan aquifer when it is in direct hydrologic contact with lower lying rock units, it is not considered here because of a lack of detailed delineation of areas where contact exists. (Woodard-USGS)
Dry and stable excavations in limestones of the greater Kansas City area of Missouri and Kansas
DOE Office of Scientific and Technical Information (OSTI.GOV)
Goebel, E.D.; Parizek, E.J.; Stauffer, T.P.
In the Greater Kansas City area of Missouri and Kansas the bedrock consists largely of a thick sequence of limestone and shale formations of Pennsylvanian age. Three formations are of interest in this report. The Swope Formation contains the Bethany Falls Limestone, the Wyandotte Formation contains the Argentine Limestone and the Farley Limestone, and the Oread Formation contains the Plattsmouth Limestone. Underground workings have been developed by industry in these three formations for a variety of uses, including factories, offices and warehouses. The Bethany Falls Limestone is the unit most widely developed for secondary underground use. The industries which design,more » excavate, and occupy this man-made underground space consider it to be essentially dry and stable. Identification and description of the geologic, topographic, hydrologic, and possible other unique features which allow this operational decision is the primary goal of this investigation.« less
40 CFR Table 4 to Subpart Kkkkk of... - Requirements for Performance Tests
Code of Federal Regulations, 2010 CFR
2010-07-01
... block average pressure drop values for the three test runs, and determine and record the 3-hour block... limit for the limestone feeder setting Data from the limestone feeder during the performance test You must ensure that you maintain an adequate amount of limestone in the limestone hopper, storage bin...
21 CFR 184.1409 - Ground limestone.
Code of Federal Regulations, 2011 CFR
2011-04-01
... 21 Food and Drugs 3 2011-04-01 2011-04-01 false Ground limestone. 184.1409 Section 184.1409 Food... Specific Substances Affirmed as GRAS § 184.1409 Ground limestone. (a) Ground limestone consists essentially (not less than 94 percent) of calcium carbonate (CaCO3) and is prepared by the crushing, grinding, and...
21 CFR 184.1409 - Ground limestone.
Code of Federal Regulations, 2010 CFR
2010-04-01
... 21 Food and Drugs 3 2010-04-01 2009-04-01 true Ground limestone. 184.1409 Section 184.1409 Food... Specific Substances Affirmed as GRAS § 184.1409 Ground limestone. (a) Ground limestone consists essentially (not less than 94 percent) of calcium carbonate (CaCO3) and is prepared by the crushing, grinding, and...
Wang, Xiao-Yong
2017-01-26
Limestone is widely used in the construction industry to produce Portland limestone cement (PLC) concrete. Systematic evaluations of hydration kinetics, compressive strength development, and carbonation resistance are crucial for the rational use of limestone. This study presents a hydration-based model for evaluating the influences of limestone on the strength and carbonation of concrete. First, the hydration model analyzes the dilution effect and the nucleation effect of limestone during the hydration of cement. The degree of cement hydration is calculated by considering concrete mixing proportions, binder properties, and curing conditions. Second, by using the gel-space ratio, the compressive strength of PLC concrete is evaluated. The interactions among water-to-binder ratio, limestone replacement ratio, and strength development are highlighted. Third, the carbonate material contents and porosity are calculated from the hydration model and are used as input parameters for the carbonation model. By considering concrete microstructures and environmental conditions, the carbon dioxide diffusivity and carbonation depth of PLC concrete are evaluated. The proposed model has been determined to be valid for concrete with various water-to-binder ratios, limestone contents, and curing periods.
Wang, Xiao-Yong
2017-01-01
Limestone is widely used in the construction industry to produce Portland limestone cement (PLC) concrete. Systematic evaluations of hydration kinetics, compressive strength development, and carbonation resistance are crucial for the rational use of limestone. This study presents a hydration-based model for evaluating the influences of limestone on the strength and carbonation of concrete. First, the hydration model analyzes the dilution effect and the nucleation effect of limestone during the hydration of cement. The degree of cement hydration is calculated by considering concrete mixing proportions, binder properties, and curing conditions. Second, by using the gel–space ratio, the compressive strength of PLC concrete is evaluated. The interactions among water-to-binder ratio, limestone replacement ratio, and strength development are highlighted. Third, the carbonate material contents and porosity are calculated from the hydration model and are used as input parameters for the carbonation model. By considering concrete microstructures and environmental conditions, the carbon dioxide diffusivity and carbonation depth of PLC concrete are evaluated. The proposed model has been determined to be valid for concrete with various water-to-binder ratios, limestone contents, and curing periods. PMID:28772472
Field trial of a pulsed limestone diversion well
Sibrell, Philip L.; Denholm, C.; Dunn, Margaret
2013-01-01
The use of limestone diversion wells to treat acid mine drainage (AMD) is well-known, but in many cases, acid neutralization is not as complete as would be desired. Reasons for this include channeling of the water through the limestone bed, and the slow reaction rate of the limestone gravel. A new approach to improve the performance of the diversion well was tested in the field at the Jennings Environmental Education Center, near Slippery Rock, PA. In this approach, a finer size distribution of limestone was used so as to allow fluidization of the limestone bed, thus eliminating channeling and increasing particle surface area for faster reaction rates. Also, water flow was regulated through the use of a dosing siphon, so that consistent fluidization of the limestone sand could be achieved. Testing began late in the summer of 2010, and continued through November of 2011. Initial system performance during the 2010 field season was good, with the production of net alkaline water, but hydraulic problems involving air release and limestone sand retention were observed. In the summer of 2011, a finer size of limestone sand was procured for use in the system. This material fluidized more readily, but acid neutralization tapered off after several days. Subsequent observations indicated that the hydraulics of the system was compromised by the formation of iron oxides in the pipe leading to the limestone bed, which affected water distribution and flow through the bed. Although results from the field trial were mixed, it is believed that without the formation of iron oxides and plugging of the pipe, better acid neutralization and treatment would have occurred. Further tests are being considered using a different hydraulic configuration for the limestone sand fluidized bed.
Diagenesis and porosity preservation in Eocene microporous limestones, South Florida, USA
NASA Astrophysics Data System (ADS)
Maliva, Robert G.; Missimer, Thomas M.; Clayton, Edward A.; Dickson, J. A. D.
2009-05-01
Microporous limestones may contain immobile, capillary-bound (irreducible) water that is only in diffusional contact with mobile pore waters or in some reservoirs may contain producible hydrocarbons. The preservation and distribution of microporosity impact both subsurface fluid flow and solute transport. The diagenesis of microporous limestones has received relatively little attention because their very fine grains and cements are not amenable to standard analytical methods. The Ocala Limestone (Upper Eocene) and upper Avon Park Formation (Middle Eocene) in South Florida contain microporous micritic limestones (mudstones to packstones) that are at an intermediate stage of diagenesis. The limestones have been exposed to the active near-surface environment, but have not yet reached a burial depth sufficient for intense chemical compaction and associated porosity reduction. Nuclear magnetic resonance (NMR) logging allowed for the quantification of total porosity, pore-size distribution, and permeability. The Ocala Limestone and Avon Park Formation have different predominant microfacies and porosity size distributions, but yet both retain total porosities predominantly between 35% and 37%. Estimated microporosities range mostly between 12% and 45%. The mudstones and wackestones of the Ocala Limestone have significantly lower permeabilities (mostly 3 to 12 md) than the wackestones to grainstones of the Avon Park Formation (commonly in the 100 to 3000 md range), which have more mixed and overall coarser pore sizes. Computer modeling using carbon and oxygen stable data indicates that the studied microporous limestones underwent only a low degree of chemical diagenetic alteration, despite likely experiencing episodes of freshwater flushing associated with post-depositional sea-level lowstands. The Ocala Limestone and Avon Park Formation limestones illustrate the general concept that total porosity is often largely preserved through early diagenesis (although may undergo intra-formational redistribution) and that confined aquifers are diagenetic quiescent environments.
Cravotta, C.A.; Ward, S.J.; Hammarstrom, J.M.
2008-01-01
Acidic mine drainage (AMD) containing elevated concentrations of dissolved iron and other metals can be neutralized to varying degrees by reactions with limestone in passive treatment systems. We evaluated the chemical and mineralogical characteristics and the effectiveness of calcitic and dolomitic limestone for the neutralization of net-acidic, oxic, iron-laden AMD from a flooded anthracite mine. The calcitic limestone, with CaCO3 and MgCO3 contents of 99.8 and <0.1 wt%, respectively, and the dolomitic limestone, with CaCO3 and MgCO3 contents of 60.3 and 40.2 wt%, were used to construct a downflow treatment system in 2003 at the Bell Mine, a large source of AMD and baseflow to the Schuylkill River in the Southern Anthracite Coalfield, in east-central Pennsylvania. In the winter of 2002-2003, laboratory neutralization-rate experiments evaluated the evolution of effluent quality during 2 weeks of continuous contact between AMD from the Bell Mine and the crushed calcitic or dolomitic limestone in closed, collapsible containers (cubitainers). The cubitainer tests showed that: (1) net-alkaline effluent could be achieved with detention times greater than 3 h, (2) effluent alkalinities and associated dissolution rates were equivalent for uncoated and Fe(OH)3-coated calcitic limestone, and (3) effluent alkalinities and associated dissolution rates for dolomitic limestone were about half those for calcitic limestone. The dissolution rate data for the cubitainer tests were used with data on the volume of effuent and surface area of limestone in the treatment system at the Bell Mine to evaluate the water-quality data for the first 1.5 years of operation of the treatment system. These rate models supported the interpretation of field results and indicated that treatment benefits were derived mainly from the dissolution of calcitic limestone, despite a greater quantity of dolomitic limestone within the treatment system. The dissolution-rate models were extrapolated on a decadal scale to indicate the expected decreases in the mass of limestone and associated alkalinities resulting from the long-term reaction of AMD with the treatment substrate. The models indicated the calcitic limestone would need to be replenished approaching the 5-year anniversary of treatment operations to maintain net-alkaline effluent quality. ?? 2008 Springer-Verlag.
21 CFR 176.260 - Pulp from reclaimed fiber.
Code of Federal Regulations, 2013 CFR
2013-04-01
... 21 Food and Drugs 3 2013-04-01 2013-04-01 false Pulp from reclaimed fiber. 176.260 Section 176.260 Food and Drugs FOOD AND DRUG ADMINISTRATION, DEPARTMENT OF HEALTH AND HUMAN SERVICES (CONTINUED) FOOD FOR HUMAN CONSUMPTION (CONTINUED) INDIRECT FOOD ADDITIVES: PAPER AND PAPERBOARD COMPONENTS Substances...
21 CFR 176.260 - Pulp from reclaimed fiber.
Code of Federal Regulations, 2012 CFR
2012-04-01
... 21 Food and Drugs 3 2012-04-01 2012-04-01 false Pulp from reclaimed fiber. 176.260 Section 176.260 Food and Drugs FOOD AND DRUG ADMINISTRATION, DEPARTMENT OF HEALTH AND HUMAN SERVICES (CONTINUED) FOOD FOR HUMAN CONSUMPTION (CONTINUED) INDIRECT FOOD ADDITIVES: PAPER AND PAPERBOARD COMPONENTS Substances...
21 CFR 176.260 - Pulp from reclaimed fiber.
Code of Federal Regulations, 2010 CFR
2010-04-01
... 21 Food and Drugs 3 2010-04-01 2009-04-01 true Pulp from reclaimed fiber. 176.260 Section 176.260 Food and Drugs FOOD AND DRUG ADMINISTRATION, DEPARTMENT OF HEALTH AND HUMAN SERVICES (CONTINUED) FOOD FOR HUMAN CONSUMPTION (CONTINUED) INDIRECT FOOD ADDITIVES: PAPER AND PAPERBOARD COMPONENTS Substances...
21 CFR 176.260 - Pulp from reclaimed fiber.
Code of Federal Regulations, 2011 CFR
2011-04-01
... 21 Food and Drugs 3 2011-04-01 2011-04-01 false Pulp from reclaimed fiber. 176.260 Section 176.260 Food and Drugs FOOD AND DRUG ADMINISTRATION, DEPARTMENT OF HEALTH AND HUMAN SERVICES (CONTINUED) FOOD FOR HUMAN CONSUMPTION (CONTINUED) INDIRECT FOOD ADDITIVES: PAPER AND PAPERBOARD COMPONENTS Substances...
21 CFR 176.260 - Pulp from reclaimed fiber.
Code of Federal Regulations, 2014 CFR
2014-04-01
... 21 Food and Drugs 3 2014-04-01 2014-04-01 false Pulp from reclaimed fiber. 176.260 Section 176.260 Food and Drugs FOOD AND DRUG ADMINISTRATION, DEPARTMENT OF HEALTH AND HUMAN SERVICES (CONTINUED) INDIRECT FOOD ADDITIVES: PAPER AND PAPERBOARD COMPONENTS Substances for Use Only as Components of Paper and...
Reclaiming Adolescence: A Roma Youth Perspective
ERIC Educational Resources Information Center
Bhabha, Jacqueline; Fuller, Arlan; Matache, Margareta; Vranješevic, Jelena; Chernoff, Miriam C.; Spasic, Boris; Ivanis, Jelena
2017-01-01
In this article, the authors present data gathered in the Reclaiming Adolescence research project, which investigated the educational hardships of Roma youth by comparing their experiences with their non-Roma peers' in Belgrade, Serbia. Serious inequalities in access to secondary and tertiary education affect the life and career opportunities of…
Federal Register 2010, 2011, 2012, 2013, 2014
2010-08-19
... supply (i.e., reclaimed effluent from municipal wastewater treatment) pipeline, a natural gas pipeline... the reclaimed effluent, natural gas, and CO 2 pipelines may cause temporary direct impacts to the... target today's most pressing environmental challenges, including reducing mercury and greenhouse gas (GHG...
30 CFR 77.211 - Draw-off tunnels; stockpiling and reclaiming operations; general.
Code of Federal Regulations, 2010 CFR
2010-07-01
... 30 Mineral Resources 1 2010-07-01 2010-07-01 false Draw-off tunnels; stockpiling and reclaiming operations; general. 77.211 Section 77.211 Mineral Resources MINE SAFETY AND HEALTH ADMINISTRATION... WORK AREAS OF UNDERGROUND COAL MINES Surface Installations § 77.211 Draw-off tunnels; stockpiling and...
Microbiological quality of spinach irrigated with reclaimed wastewater and roof-harvest water
USDA-ARS?s Scientific Manuscript database
Aims: The effect of reclaimed wastewater (RCW) and roof-harvest rainwater (RHW) on microbiological quality of irrigated spinach was investigated. Methods and Results: Spinach grown in controlled environment chamber was irrigated by RCW, RHW, or creek water (CW; control water) for four weeks, and th...
USDA-ARS?s Scientific Manuscript database
Background and Aims Selenium contamination and accumulation in vegetation have resulted in Se toxicity in livestock and wildlife in reclaimed phosphate mine soils in Southeastern Idaho. Methods Plant and soil samples were collected from five study sites near phosphate mines. Soil physiochemical pr...
Emergy and economic methods were used to evaluate and compare a traditional tropical fruit cultivation system, for bananas, and three newly introduced fruit cultivation systems, for papaya, guava and wampee, on reclaimed wetlands of the Pearl River Estuary, China. The evaluations...
USDA-ARS?s Scientific Manuscript database
Wastewater reclamation for municipal irrigation is an increasingly attractive option for extending water supplies. However, public health concerns include the potential for development of antibiotic resistance (AR) in soil bacteria after exposure to residual pharmaceuticals in reclaimed water. Thoug...
16 CFR 300.28 - Undetermined quantities of reclaimed fibers.
Code of Federal Regulations, 2011 CFR
2011-01-01
... 16 Commercial Practices 1 2011-01-01 2011-01-01 false Undetermined quantities of reclaimed fibers. 300.28 Section 300.28 Commercial Practices FEDERAL TRADE COMMISSION REGULATIONS UNDER SPECIFIC ACTS OF CONGRESS RULES AND REGULATIONS UNDER THE WOOL PRODUCTS LABELING ACT OF 1939 Labeling § 300.28 Undetermined...
40 CFR 421.246 - Pretreatment standards for new sources.
Code of Federal Regulations, 2011 CFR
2011-07-01
... wastewater pollutants in secondary nickel process wastewater introduced into a POTW shall not exceed the... slag input to reclaim process Chromium (total) 5.653 2.313 Copper 24.410 12.850 Nickel 24.670 16.320 (b) Acid reclaim leaching filtrate. PSNS for the Secondary Nickel Subcategory Pollutant or pollutant...
American elm in mine land reforestation
M.B. Adams; P. Angel; C. Barton; J. Slavicek
2015-01-01
Reforestation of mined land in the Appalachians realizes many important benefits and provides important ecosystem services. Because much of the reclaimed mine lands in Appalachia were previously in forest, reclaiming these drastically disturbed areas to forests is desirable, feasible and cost-effective. The Forestry Reclamation Approach (FRA) provides a five-step...
DOT National Transportation Integrated Search
2012-06-01
A recent rise in asphalt binder prices has led state agencies and contractors to use higher quantities of Reclaimed : Asphalt Pavement (RAP). Besides being economic, sustainable, and environmentally friendly, RAP can be replaced : for a portion of ag...
30 CFR 77.209 - Surge and storage piles.
Code of Federal Regulations, 2010 CFR
2010-07-01
... Mineral Resources MINE SAFETY AND HEALTH ADMINISTRATION, DEPARTMENT OF LABOR COAL MINE SAFETY AND HEALTH MANDATORY SAFETY STANDARDS, SURFACE COAL MINES AND SURFACE WORK AREAS OF UNDERGROUND COAL MINES Surface... a reclaiming area or in any other area at or near a surge or storage pile where the reclaiming...
USDA-ARS?s Scientific Manuscript database
The availability of water for crop irrigation is decreasing due to droughts, population growth, and pollution. The Food Safety and Modernization Act (FSMA) standards for irrigation water may also discourage growers to use poor microbial quality water for produce crop irrigation. Reclaimed water use ...
USDA-ARS?s Scientific Manuscript database
The availability of water for crop irrigation is decreasing due to droughts, population growth, and pollution. Food Safety and Modernization Act (FSMA) for irrigation water standards may also discourage growers to use poor microbial quality water for produce crop irrigation. Reclaimed water use for ...
NASA Astrophysics Data System (ADS)
Ali, Ahmed; Wagreich, Michael
2017-06-01
Mineralogical, major, minor, REE and trace element analyses of rock samples were performed on Middle Miocene limestones (Leitha limestones, Badenian) collected from four localities from Austria (Mannersdorf, Wöllersdorf, Kummer and Rosenberg quarries) and the Fertőrákos quarry in Hungary. Impure to pure limestones (i.e. limited by Al2O3 contents above or below 0.43 wt. %) were tested to evaluate the applicability of various geochemical proxies and indices in regard to provenance and palaeoenvironmental interpretations. Pure and impure limestones from Mannersdorf and Wöllersdorf (southern Vienna Basin) show signs of detrital input (REEs = 27.6 ± 9.8 ppm, Ce anomaly = 0.95 ± 0.1 and the presence of quartz, muscovite and clay minerals in impure limestones) and diagenetic influence (low contents of, e.g., Sr = 221 ± 49 ppm, Na is not detected, Ba = 15.6 ± 8.8 ppm in pure limestones). Thus, in both limestones the reconstruction of original sedimentary palaeoenvironments by geochemistry is hampered. The Kummer and Fertőrákos (Eisenstadt-Sopron Basin) comprise pure limestones (e.g., averages Sr = 571 ± 139 ppm, Na = 213 ± 56 ppm, Ba = 21 ± 4 ppm, REEs = 16 ± 3 ppm and Ce anomaly = 0.62 ± 0.05 and composed predominantly of calcite) exhibiting negligible diagenesis. Deposition under a shallow-water, well oxygenated to intermittent dysoxic marine environment can be reconstructed. Pure to impure limestones at Rosenberg-Retznei (Styrian Basin) are affected to some extent by detrital input and volcano-siliciclastic admixture. The Leitha limestones at Rosenberg have the least diagenetic influence among the studied localities (i.e. averages Sr = 1271 ± 261 ppm, Na = 315 ± 195 ppm, Ba = 32 ± 15 ppm, REEs = 9.8 ± 4.2 ppm and Ce anomaly = 0.77 ± 0.1 and consist of calcite, minor dolomite and quartz). The siliciclastic sources are characterized by immobile elemental ratios (i.e. La/Sc and Th/Co) which apply not only for the siliciclastics, but also for marls and impure limestones. At Mannersdorf the detrital input source varies between intermediate to silicic igneous rocks, while in Kummer and Rosenberg the source is solely silicic igneous rocks. The Chemical Index of Alteration (CIA) is only applicable in the shale-contaminated impure limestones. CIA values of the Leitha limestones from Mannersdorf indicate a gradual transition from warm to temperate palaeoclimate within the limestone succession of the Badenian.
Lithostratigraphy of Upper Ordovician strata exposed in Kentucky
Weir, Gordon Whitney; Peterson, Warren Lee; Swadley, W.C.
1984-01-01
Ordovician formations above the Lexington Limestone crop out in the Blue Grass region of Kentucky and along the Cumberland River and its tributaries. The formations are all conformable and in places intertongue and intergrade. The major Ordovician units above the Lexington Limestone in the Blue Grass region are: The Clays Ferry Formation, the Kope Formation, the Garrard Siltstone, the Fairview Formation, the Calloway Creek Limestone, the Grant Lake Limestone, the Ashlock Formation, the Bull Fork Formation, and the Drakes Formation. The Clays Ferry Formation is made up of subequal amounts of fossiliferous limestone and shale and minor siltstone; the Clays Ferry is as much as 300 ft thick and intertongues with the Lexington Limestone and the Kope Formation. The Kope Formation resembles the partly equivalent Clays Ferry but has a higher shale content (60-80 percent) and thicker layers of shale; the Kope, as much as 275 ft thick, is mostly restricted to the northern part of the State. The Garrard Siltstone, which consists of very calcitic siltstone and minor shale, overlies the Clays Ferry Formation in the southeastern part of the Blue Grass region; the Garrard, as much as 100 ft thick, feathers out into the upper part of the Clays Ferry in southern central and northern east-central Kentucky. The Fairview Formation is characterized by even-bedded limestone interlayered with nearly equal amounts of shale and minor siltstone. The Fairview crops out in the northern part of the Blue Grass region, where it generally overlies the Kope Formation or the Garrard Siltstone; it grades southward into the Calloway Creek Limestone. The Calloway Creek contains more limestone (generally at least 70 percent) and is more irregularly and thinner bedded than the Fairview. The Grant Lake Limestone is composed of nodular-bedded limestone (70-90 percent), interlayered and intermixed with shale; it overlies the Fairview Formation in the northern part of the Blue Grass region and the Calloway Creek Limestone in the western and central parts. In east-central Kentucky, the Grant Lake is classified as a member of the Ashlock Formation, an assemblage of lithologically distinct units that were combined to facilitate mapping in the southeastern and southern part of the region. The Ashlock consists of the following members, in ascending order: The Tate (calcitic and dolomitic mudstone), the Grant Lake, the Gilbert (micrograined limestone and shale), the Stingy Creek (nodular-bedded mudstone and limestone), the Terrill (dolomitic and calcitic mudstone), the Sunset (micrograined limestone), and the Reba (nodular-bedded limestone and shale). The Bull Fork Formation, which overlies the Grant Lake Limestone, is made up of subequal amounts of thin-bedded highly fossiliferous limestone and shale; limestone makes up about 80 percent of the basal part of the formation and decreases in abundance irregularly upward to only 20 percent of the top part. On the east side of the Blue Grass region, the Bull Fork grades into the Reba Member of the Ashlock Formation; on the west side, it grades into the Grant Lake. The uppermost formation in the region is the Drakes Formation, which in east-central Kentucky consists of the Rowland Member (calcitic to dolomitic mudstone) overlain by the Preachersville Member (dolomitic to calcitic mudstone and dolomite and dolomitic siltstone). In northeast Kentucky, the Drakes is represented by only the Preachersville Member. In most of central and north-central Kentucky, the formation consists of three members: the Rowland at the base (dolomitic mudstone to muddy limestone), the Bardstown (fossiliferous limestone and shale), and the Saluda Dolomite (dolomite, in part calcitic and muddy). In northern north-central Kentucky, the Drakes is represented by only the Saluda Dolomite Member. The top of the Ordovician sequence in the Blue Grass region is generally formed by members of the Drakes Formation, which are overlain by str
Li, Yuanyuan; Wen, Hongyu; Chen, Longqian; Yin, Tingting
2014-01-01
The growing concern about the effectiveness of reclamation strategies has motivated the evaluation of soil properties following reclamation. Recovery of belowground microbial community is important for reclamation success, however, the response of soil bacterial communities to reclamation has not been well understood. In this study, PCR-based 454 pyrosequencing was applied to compare bacterial communities in undisturbed soils with those in reclaimed soils using chronosequences ranging in time following reclamation from 1 to 20 year. Bacteria from the Proteobacteria, Chloroflexi, Actinobacteria, Acidobacteria, Planctomycetes and Bacteroidetes were abundant in all soils, while the composition of predominant phyla differed greatly across all sites. Long-term reclamation strongly affected microbial community structure and diversity. Initial effects of reclamation resulted in significant declines in bacterial diversity indices in younger reclaimed sites (1, 8-year-old) compared to the undisturbed site. However, bacterial diversity indices tended to be higher in older reclaimed sites (15, 20-year-old) as recovery time increased, and were more similar to predisturbance levels nearly 20 years after reclamation. Bacterial communities are highly responsive to soil physicochemical properties (pH, soil organic matter, Total N and P), in terms of both their diversity and community composition. Our results suggest that the response of soil microorganisms to reclamation is likely governed by soil characteristics and, indirectly, by the effects of vegetation restoration. Mixture sowing of gramineae and leguminosae herbage largely promoted soil geochemical conditions and bacterial diversity that recovered to those of undisturbed soil, representing an adequate solution for soil remediation and sustainable utilization for agriculture. These results confirm the positive impacts of reclamation and vegetation restoration on soil microbial diversity and suggest that the most important phase of microbial community recovery occurs between 15 and 20 years after reclamation. PMID:25502754
Cravotta, Charles A.; Ward, S.J.; Koury, Daniel J.; Koch, R.D.
2004-01-01
Limestone drains were constructed in 1995, 1997, and 2000 to treat acidic mine drainage (AMD) from the Orchard, Buck Mtn., and Hegins discharges, respectively, in the Swatara Creek Basin, Southern Anthracite Coalfield, east-central Pennsylvania. This report summarizes the construction characteristics and performance of each of the limestone drains on the basis of influent and effluent quality and laboratory tests of variables affecting limestone dissolution rates. Data for influent and effluent indicate substantial alkalinity production by the Orchard and Buck Mtn. limestone drains and only marginal benefits from the Hegins drain. Nevertheless, the annual alkalinity loading rates have progressively declined with age of all three systems. Collapsible-container (cubitainer) testing was conducted to evaluate current scenarios and possible options for reconstruction and maintenance of the limestone drains to optimize their long-term performance. The cubitainer tests indicated dissolution rates for the current configurations that were in agreement with field flux data (net loading) for alkalinity and dissolved calcium. The dissolution rates in cubitainers were larger for closed conditions than open conditions, but the rates were comparable for coated and uncoated limestone for a given condition. Models developed on the basis of the cubitainer testing indicate (1) exponential declines in limestone mass and corresponding alkalinity loading rates with increased age of limestone drains and (2) potential for improved performance with enlargement, complete burial, and/or regular flushing of the systems.
Puerto Rican Karst-A Vital Resource
Ariel E. Lugo; Leopoldo Miranda Castro; Abel Vale; Tania del Mar López; Enrique Hernández Prieto; Andrés García Martinó; Alberto R. Puente Rolón; Adrianne G. Tossas; Donald A. McFarlane; Tom Miller; Armando Rodríguez; Joyce Lundberg; John Thomlinson; José Colón; Johannes H. Schellekens; Olga Ramos; Eileen Helmer
2001-01-01
The limestone region of Puerto Rico covers about 27.5 percent of the islandâs surface and is subdivided into the northern, southern, and dispersed limestone areas. All limestone areas have karst features. The karst belt is that part of the northern limestone with the most spectacular surficial karst landforms. It covers 142,544 ha or 65 percent of the northern...
Alaska research natural areas: 2. Limestone jags.
G.P. Juday
1989-01-01
The 2083-hectare Limestone Jags Research Natural Area in the White Mountains National Recreation Area of central Alaska contains old limestone terrain featuresââcaves, natural bridges, disappearing streams, and cold springs in a subarctic setting. A limestone dissolution joint-type cave in the area is one of the largest reported in high-latitude North America. A...
NASA Technical Reports Server (NTRS)
Rogers, R. H. (Principal Investigator); Pettyjohn, W. A.
1975-01-01
The author has identified the following significant results. Computer techniques were applied to process ERTS tapes acquired over coal mining operations in southeastern Ohio on 21 August 1972 and 3 September 1973. ERTS products obtained included geometrically correct map overlays showing stripped earth, partially reclaimed earth, water, and natural vegetation. Computer-generated tables listing the area covered by each land-water category in square kilometers and acres were produced. By comparing these mapping products, the study demonstrates the capability of ERTS to monitor changes in the extent of stripping, success of reclamation, and the secondary effects of mining on the environment.
reClaiming Space & Dialogue in Adult Education
ERIC Educational Resources Information Center
Kawalilak, Colleen A.
2006-01-01
This paper critiques current trends in adult education against a backdrop of practice that was once testimony to an educational model that extended beyond formal learning and a business and industry agenda. Adult educators are called upon to reclaim an identity as leaders, in support of a shift in perspective and practice, more aligned to…
Engineering properties of douglas-fir lumber reclaimed from deconstructed buildings
Robert Falk; Derek Maul; Steven Cramer; James Evans; Victoria Herian
2008-01-01
A vast wood resource exists in our Nation's wood-framed building infrastructure. As the buildings in this infrastructure age and are remodeled or removed for redevelopment, the wood framing residing in these buildings has the potential to be recovered for reuse. However, little technical information exists on the residual engineering properties of reclaimed...
Richard D. Bergman; Hongmei Gu; Robert H. Falk; Thomas R. Napier
2010-01-01
With green building concepts becoming widespread in the construction field, building practices and materials are being examined for their environmental impact. Reusing building materials has a distinct advantage over using newly manufactured materials because these reclaimed materials avoid greenhouse gas emissions associated with new (virgin) material manufacturing....
40 CFR 421.245 - Pretreatment standards for existing sources.
Code of Federal Regulations, 2011 CFR
2011-07-01
... existing sources. The mass of wastewater pollutants in secondary nickel process wastewater introduced into.../kg (pounds per million pounds) of slag input to reclaim process Chromium (total) 5.653 2.313 Copper 24.410 12.850 Nickel 24.670 16.320 (b) Acid reclaim leaching filtrate. PSES for the Secondary Nickel...
Beautiful Walls: Reclaiming Urban Space through Mural Making
ERIC Educational Resources Information Center
Welch, Bethany J.
2016-01-01
During the nearly sixteen years she has lived and worked in inner city neighborhoods in New York, Delaware, and Philadelphia, Bethany Welch has seen communities reclaim these spaces by tackling the most visible things first. This includes clearing trash strewn vacant lots and creating murals on expansive exterior walls stained with marks of time.…
Reclaiming Reading: Teachers, Students, and Researchers Regaining Spaces for Thinking and Action
ERIC Educational Resources Information Center
Meyer, Richard J., Ed.; Whitmore, Kathryn F., Ed.
2011-01-01
Inviting teachers back to the role of reflective advocates for thoughtful reading instruction, this book presents theory and pedagogical possibilities to reclaim and build upon the knowledge base that was growing when government mandates, scripted commercial programs, and high stakes tests took over as the dominant agenda for reading instruction…
Quality requirements for reclaimed/recycled water
NASA Technical Reports Server (NTRS)
Janik, Daniel S.; Sauer, Richard L.; Pierson, Duane L.; Thorstenson, Yvonne R.
1987-01-01
Water used during current and previous space missions has been either carried or made aloft. Future human space endeavors will require some form of water reclamation and recycling. There is little experience in the U.S. space program with this technology. Water reclamation and recycling constitute engineering challenges of the broadest nature that will require an intensive research and development effort if this technology is to mature in time for practical use on the proposed U.S. Space Station. In order for this to happen, reclaimed/recycled water specifications will need to be devised to guide engineering development. Present NASA Potable Water Specifications are not applicable to reclaimed or recycled water. Adequate specifications for ensuring the quality of the reclaimed or recycled potable water system is reviewed, limitations of present water specifications are examined, world experience with potable water reclamation/recycling systems and systems analogs is reviewed, and an approach to developing pertinent biomedical water specifications for spacecraft is presented. Space Station water specifications should be designed to ensure the health of all likely spacecraft inhabitants including man, animals, and plants.
Assessment and management of the performance risk of a pilot reclaimed water disinfection process.
Zhou, Guangyu; Zhao, Xinhua; Zhang, Lei; Wu, Qing
2013-10-01
Chlorination disinfection has been widely used in reclaimed water treatment plants to ensure water quality. In order to assess the downstream quality risk of a running reclaimed water disinfection process, a set of dynamic equations was developed to simulate reactions in the disinfection process concerning variables of bacteria, chemical oxygen demand (COD), ammonia and monochloramine. The model was calibrated by the observations obtained from a pilot disinfection process which was designed to simulate the actual process in a reclaimed water treatment plant. A Monte Carlo algorithm was applied to calculate the predictive effluent quality distributions that were used in the established hierarchical assessment system for the downstream quality risk, and the key factors affecting the downstream quality risk were defined using the Regional Sensitivity Analysis method. The results showed that the seasonal upstream quality variation caused considerable downstream quality risk; the effluent ammonia was significantly influenced by its upstream concentration; the upstream COD was a key factor determining the process effluent risk of bacterial, COD and residual disinfectant indexes; and lower COD and ammonia concentrations in the influent would mean better downstream quality.
DOE Office of Scientific and Technical Information (OSTI.GOV)
Galligan, E.W.; DeVault, T.L.; Lima, S.L.
2006-12-15
Reclaimed surface coal mines in southwestern Indiana support many grassland and shrub/savanna bird species of conservation concern. We examined the nesting success of birds on these reclaimed mines to assess whether such 'unnatural' places represent productive breeding habitats for such species. We established eight study sites on two large, grassland-dominated mines in southwestern Indiana and classified them into three categories (open grassland, shrub/savanna, and a mixture of grassland and shrub/savanna) based on broad vegetation and landscape characteristics. During the 1999 and 2000 breeding seasons, we found and monitored 911 nests of 31 species. Daily nest survival for the most commonlymore » monitored grassland species ranged from 0.903 (Dickcissel, Spiza americana) to 0.961 (Grasshopper Sparrow, Ammodramus savannarum). Daily survival estimates for the dominant shrub/savanna nesting species ranged from 0.932 (Brown Thrasher, Toxostoma rufum) to 0.982 (Willow Flycatcher, Empidonax traillii). Vegetation and landscape effects on nesting success were minimal, and only Eastern Meadowlarks (Sturnella magna) showed a clear time-of-season effect, with greater nesting success in the first half of the breeding season. Rates of Brown-headed Cowbird (Molothrus ater) parasitism were only 2.1% for grassland species and 12.0% for shrub/savanna species. The nesting success of birds on reclaimed mine sites was comparable to that in other habitats, indicating that reclaimed habitats on surface mines do not necessarily represent reproductive traps for birds.« less
Williams, Jennifer M.; Brown, Donald J.; Wood, Petra B.
2017-01-01
Mountaintop removal mining is a large-scale surface mining technique that removes entire floral and faunal communities, along with soil horizons located above coal seams. In West Virginia, the majority of this mining occurs on forested mountaintops. However, after mining ceases the land is typically reclaimed to grasslands and shrublands, resulting in novel ecosystems. In this study, we examined responses of herpetofauna to these novel ecosystems 10–28 y postreclamation. We quantified differences in species-specific habitat associations, (sub)order-level abundances, and habitat characteristics in four habitat types: reclaimed grassland, reclaimed shrubland, forest fragments in mined areas, and nonmined intact forest. Habitat type accounted for 33.2% of the variation in species-specific captures. With few exceptions, forest specialists were associated with intact forest and fragmented forest sites, while habitat generalists were either associated with grassland and shrubland sites or were distributed among all habitat types. At the (sub)order level, salamander (Order Urodela) captures were highest at fragmented and intact forest sites, frog and toad (Order Anura) captures were lowest at intact forest sites, and snake (Suborder Serpentes) captures were highest at shrubland sites. Habitat type was a strong predictor for estimated total abundance of urodeles, but not for anurans or snakes. Tree stem densities in grasslands differed from the other three habitat types, and large trees (>38 cm diameter at breast height) were only present at forest sites. Overstory vegetation cover was greater in forested than in reclaimed habitat types. Ground cover in reclaimed grasslands was distinct from forest treatments with generally less woody debris and litter cover and more vegetative cover. It is important to consider the distributions of habitat specialists of conservation concern when delineating potential mountaintop mine sites, as these sites will likely contain unsuitable habitat for forest specialists for decades or centuries when reclaimed to grassland or shrubland.
NASA Astrophysics Data System (ADS)
Cudlín, Ondřej; Řehák, Zdeněk; Cudlín, Pavel
2016-10-01
The aim of this study was to compare soil characteristics, plant communities and the rate of selected ecosystem function performance on reclaimed and unreclaimed plots (left for spontaneous succession) of different age on spoil heaps. Twelve spoil heaps (three circle plots of radius 12.5 m) near the town Kladno in north-west direction from Prague, created after deep coal mining, were compared. Five mixed soil samples from organo-mineral horizons in each plot were analysed for total content of carbon, nitrogen and phosphorus. In addition, active soil pH (pHH2O) was determined. Plant diversity was determined by vegetation releves. The biodiversity value of the habitat according to the Habitat Valuation Method was assessed and the rate of evapotranspiration function by the Method of Valuation Functions and Services of Ecosystems in the Czech Republic were determined. The higher organo-mineral layers and higher amount of total nitrogen content were found on the older reclaimed and unreclaimed plots than in younger plots. The number of plant species and the total contents of carbon and nitrogen were significantly higher at the unreclaimed plots compared to reclaimed plots. The biodiversity values and evapotranspiration function rate were also higher on unreclaimed plots. From this perspective, it is possible to recommend using of spontaneous succession, together with routine reclamation methods to restore habitats after coal mining. Despite the relatively high age of vegetation in some of selected plots (90 years), both the reclaimed and unreclaimed plots have not reached the stage of potential vegetation near to natural climax. Slow development of vegetation was probably due to unsuitable substrate of spoil heaps and a lack of plant and tree species of natural forest habitats in this area. However, it is probable that vegetation communities on observed spoil heaps in both type of management (reclaimed and unreclaimed) will achieve the stage of natural climax and they will provide ecosystem functions more effectively in the future.
Sun, Jie; Zhang, Rui; Qin, Long; Zhu, Haixiao; Huang, Yu; Xue, Yingang; An, Shuqing; Xie, Xianchuan; Li, Aimin
2017-03-01
To further treat the reclaimed municipal wastewater and rehabilitate the aquatic ecosystem of polluted urban rivers, an 18.5-km field-scale ecological restoration project was constructed along Jialu River, a polluted urban river which receives only reclaimed municipal wastewater from Zhengzhou City without natural upland water dilution. This study investigated the potential efficiency of water quality improvement, as well as genotoxicity and cytotoxicity reduction along the ecological restoration project of this polluted urban river. Results showed that the chemical oxygen demand (COD) and ammonia nitrogen (NH 3 -N) of the reclaimed municipal effluent were reduced by more than 45 and 70%, respectively, meeting the Chinese surface water environmental quality standard level IV, while the total phosphorus and metal concentrations had no significant reduction along the restoration project, and Pb concentrations in all river water samples exceeded permissible limit in drinking water set by WHO (2006) and China (GB5749-2006). The in vitro SOS/umu assay showed 4-nitroquinoline-1-oxide equivalent (4-NQO-EQ) values of reclaimed municipal wastewater of 0.69 ± 0.05 μg/L in April and 0.68 ± 0.06 μg/L in December, respectively, indicating the presence of genotoxic compounds. The results of 8-hydroxy-2'-deoxyguanosine (8-OHdG) and hepatic cell apoptosis in zebrafish after a chorionic long-term (21 days) in vivo exposure also demonstrated that the reclaimed municipal wastewater caused significant DNA oxidative damage and cytotoxicity. After the ecological purification of 18.5-km field-scale restoration project, the genotoxicity assessed by in vitro assay was negligible, while the DNA oxidative damage and cytotoxicity in exposed fish were still significantly elevated. The mechanisms of DNA oxidative damage and cytotoxicity caused by the reclaimed municipal wastewater need further study.
NASA Technical Reports Server (NTRS)
Townsend, Philip A.; Helmers, David P.; Kingdon, Clayton C.; McNeil, Brenden E.; de Beurs, Kirsten M.; Eshleman, Keith N.
2009-01-01
Surface mining and reclamation is the dominant driver of land cover land use change (LCLUC) in the Central Appalachian Mountain region of the Eastern U.S. Accurate quantification of the extent of mining activities is important for assessing how this LCLUC affects ecosystem services such as aesthetics, biodiversity, and mitigation of flooding.We used Landsat imagery from 1976, 1987, 1999 and 2006 to map the extent of surface mines and mine reclamation for eight large watersheds in the Central Appalachian region of West Virginia, Maryland and Pennsylvania. We employed standard image processing techniques in conjunction with a temporal decision tree and GIS maps of mine permits and wetlands to map active and reclaimed mines and track changes through time. For the entire study area, active surface mine extent was highest in 1976, prior to implementation of the Surface Mine Control and Reclamation Act in 1977, with 1.76% of the study area in active mines, declining to 0.44% in 2006. The most extensively mined watershed, Georges Creek in Maryland, was 5.45% active mines in 1976, declining to 1.83% in 2006. For the entire study area, the area of reclaimed mines increased from 1.35% to 4.99% from 1976 to 2006, and from 4.71% to 15.42% in Georges Creek. Land cover conversion to mines and then reclaimed mines after 1976 was almost exclusively from forest. Accuracy levels for mined and reclaimed cover was above 85% for all time periods, and was generally above 80% for mapping active and reclaimed mines separately, especially for the later time periods in which good accuracy assessment data were available. Among other implications, the mapped patterns of LCLUC are likely to significantly affect watershed hydrology, as mined and reclaimed areas have lower infiltration capacity and thus more rapid runoff than unmined forest watersheds, leading to greater potential for extreme flooding during heavy rainfall events.
DOE Office of Scientific and Technical Information (OSTI.GOV)
Thomas Parris; Michael Solis; Kathryn Takacs
2009-12-31
Using soil gas chemistry to detect leakage from underground reservoirs (i.e. microseepage) requires that the natural range of soil gas flux and chemistry be fully characterized. To meet this need, soil gas flux (CO{sub 2}, CH{sub 4}) and the bulk (CO{sub 2}, CH{sub 4}) and isotopic chemistry ({delta}{sup 13}C-CO2) of shallow soil gases (<1 m, 3.3 ft) were measured at 25 locations distributed among two active oil and gas fields, an active strip mine, and a relatively undisturbed research forest in eastern Kentucky. The measurements apportion the biologic, atmospheric, and geologic influences on soil gas composition under varying degrees ofmore » human surface disturbance. The measurements also highlight potential challenges in using soil gas chemistry as a monitoring tool where the surface cover consists of reclaimed mine land or is underlain by shallow coals. For example, enrichment of ({delta}{sup 13}C-CO2) and high CH{sub 4} concentrations in soils have been historically used as indicators of microseepage, but in the reclaimed mine lands similar soil chemistry characteristics likely result from dissolution of carbonate cement in siliciclastic clasts having {delta}{sup 13}C values close to 0{per_thousand} and degassing of coal fragments. The gases accumulate in the reclaimed mine land soils because intense compaction reduces soil permeability, thereby impeding equilibration with the atmosphere. Consequently, the reclaimed mine lands provide a false microseepage anomaly. Further potential challenges arise from low permeability zones associated with compacted soils in reclaimed mine lands and shallow coals in undisturbed areas that might impede upward gas migration. To investigate the effect of these materials on gas migration and composition, four 10 m (33 ft) deep monitoring wells were drilled in reclaimed mine material and in undisturbed soils with and without coals. The wells, configured with sampling zones at discrete intervals, show the persistence of some of the aforementioned anomalies at depth. Moreover, high CO{sub 2} concentrations associated with coals in the vadose zone suggest a strong affinity for adsorbing CO{sub 2}. Overall, the low permeability of reclaimed mine lands and coals and CO2 adsorption by the latter is likely to reduce the ability of surface geochemistry tools to detect a microseepage signal.« less
Cravotta,, Charles A.; Watzlaf, George R.
2002-01-01
Data on the construction characteristics and the composition of influent and effluent at 13 underground, limestone-filled drains in Pennsylvania and Maryland are reported to evaluate the design and performance of limestone drains for the attenuation of acidity and dissolved metals in acidic mine drainage. On the basis of the initial mass of limestone, dimensions of the drains, and average flow rates, the initial porosity and average detention time for each drain were computed. Calculated porosity ranged from 0.12 to 0.50 with corresponding detention times at average flow from 1.3 to 33 h. The effectiveness of treatment was dependent on influent chemistry, detention time, and limestone purity. At two sites where influent contained elevated dissolved Al (>5 mg/liter), drain performance declined rapidly; elsewhere the drains consistently produced near-neutral effluent, even when influent contained small concentrations of dissolved Fe^+ (<5 mg/liter). Rates of limestone dissolution computed on the basis of average long-term Ca ion flux normalized by initial mass and purity of limestone at each of the drains ranged from 0.008 to 0.079 year-1. Data for alkalinity concentration and flux during 11-day closed-container tests using an initial mass of 4kg crushed limestone and a solution volume of 2.3 liter yielded dissolution rate constants that were comparable to these long-term field rates. An analytical method is proposed using closed-container test data to evaluate long-term performance (longevity) or to estimate the mass of limestone needed for a limestone treatment. This method condisers flow rate, influent alkalinity, steady-state alkalinity of effluent, and desired effluent alkalinity or detention time at a future time(s) and aplies first-order rate laws for limestone dissolution (continuous) and production of alkalinity (bounded).
NASA Astrophysics Data System (ADS)
Mahmud, K.; Mariethoz, G.; Baker, A.; Treble, P. C.; Markowska, M.; McGuire, E.
2016-01-01
Limestone aeolianites constitute karstic aquifers covering much of the western and southern Australian coastal fringe. They are a key groundwater resource for a range of industries such as winery and tourism, and provide important ecosystem services such as habitat for stygofauna. Moreover, recharge estimation is important for understanding the water cycle, for contaminant transport, for water management, and for stalagmite-based paleoclimate reconstructions. Caves offer a natural inception point to observe both the long-term groundwater recharge and the preferential movement of water through the unsaturated zone of such limestone. With the availability of automated drip rate logging systems and remote sensing techniques, it is now possible to deploy the combination of these methods for larger-scale studies of infiltration processes within a cave. In this study, we utilize a spatial survey of automated cave drip monitoring in two large chambers of Golgotha Cave, south-western Western Australia (SWWA), with the aim of better understanding infiltration water movement and the relationship between infiltration, stalactite morphology, and unsaturated zone recharge. By applying morphological analysis of ceiling features from Terrestrial LiDAR (T-LiDAR) data, coupled with drip time series and climate data from 2012 to 2014, we demonstrate the nature of the relationships between infiltration through fractures in the limestone and unsaturated zone recharge. Similarities between drip rate time series are interpreted in terms of flow patterns, cave chamber morphology, and lithology. Moreover, we develop a new technique to estimate recharge in large-scale caves, engaging flow classification to determine the cave ceiling area covered by each flow category and drip data for the entire observation period, to calculate the total volume of cave discharge. This new technique can be applied to other cave sites to identify highly focussed areas of recharge and can help to better estimate the total recharge volume.
NASA Astrophysics Data System (ADS)
Mahmud, K.; Mariethoz, G.; Baker, A.; Treble, P. C.; Markowska, M.; McGuire, E.
2015-09-01
Limestone aeolianites constitute karstic aquifers covering much of the western and southern Australian coastal fringe. They are a key groundwater resource for a range of industries such as winery and tourism, and provide important ecosystem services such as habitat for stygofauna. Moreover, recharge estimation is important for understanding the water cycle, for contaminant transport, for water management and for stalagmite-based paleoclimate reconstructions. Caves offer a natural inception point to observe both the long-term groundwater recharge and the preferential movement of water through the unsaturated zone of such limestone. With the availability of automated drip rate logging systems and remote sensing techniques, it is now possible to deploy the combination of these methods for larger scale studies of infiltration processes within a cave. In this study, we utilize a spatial survey of automated cave drip monitoring in two large chambers of the Golgotha Cave, South-West Western Australia (SWWA), with the aim of better understanding infiltration water movement and the relationship between infiltration, stalactite morphology and unsaturated zone recharge. By applying morphological analysis of ceiling features from Terrestrial LiDAR (T-LiDAR) data, coupled with drip time series and climate data from 2012-2014, we demonstrate the nature of the relationships between infiltration through fractures in the limestone and unsaturated zone recharge. Similarities between drip-rate time series are interpreted in terms of flow patterns, cave chamber morphology and lithology. Moreover, we develop a new technique to estimate recharge in large scale caves, engaging flow classification to determine the cave ceiling area covered by each flow category and drip data for the entire observation period, to calculate the total volume of cave discharge. This new technique can be applied to other cave sites to identify highly focused areas of recharge and can help to better estimate the total recharge volume.
Foon, Junn Kitt; Clements, Gopalasamy Reuben; Liew, Thor-Seng
2017-01-01
Abstract Limestone hills are now gaining global conservation attention as hotspots for short-range endemic species. Levels of land snail endemism can be high at limestone hills, especially at hill clusters that are geographically isolated. In the State of Perak, Peninsular Malaysia, limestone hills have been opportunistically surveyed for land snails in the past, but the majority have yet to be surveyed. To address this knowledge gap, we systematically surveyed the terrestrial malacofauna of 12 limestone hills that, based on our opinion, are a representation of the limestone land snail assemblages within the State. Our inventory yielded high sampling completeness (>85%). We found 122 species of land snails, of which 34 species were unique to one of the surveyed hills. We identified 30 species that are potentially new to science. The number of land snail species recorded at each hill ranged between 39 and 63 species. Four of the sampled limestone hills namely, Prk 01 G. Tempurung, Prk 55 G. Pondok, Prk 47 Kanthan, and Prk 64 Bt Kepala Gajah, have high levels of species richness and unique species, representing 91% of the total species recorded in this study. We identified two clusters of limestone hills in central Perak with distinct differences in land snail species composition – a northern hill cluster on elevated granite bedrock and southern hill cluster in a low-lying valley surrounded by alluvial soils. As limestone hills continue to be quarried to meet the cement demand, the four identified limestone hills, along with other hills from the two clusters, warrant urgent conservation attention in order to maintain high species diversity within Perak’s terrestrial malacofauna. PMID:28769723
Esfandyari Bayat, Ali; Junin, Radzuan; Shamshirband, Shahaboddin; Tong Chong, Wen
2015-01-01
Engineered aluminum oxide (Al2O3), titanium dioxide (TiO2), and silicon dioxide (SiO2) nanoparticles (NPs) are utilized in a broad range of applications; causing noticeable quantities of these materials to be released into the environment. Issues of how and where these particles are distributed into the subsurface aquatic environment remain as major challenges for those in environmental engineering. In this study, transport and retention of Al2O3, TiO2, and SiO2 NPs through various saturated porous media were investigated. Vertical columns were packed with quartz-sand, limestone, and dolomite grains. The NPs were introduced as a pulse suspended in aqueous solutions and breakthrough curves in the column outlet were generated using an ultraviolet-visible spectrophotometer. It was found that Al2O3 and TiO2 NPs are easily transported through limestone and dolomite porous media whereas NPs recoveries were achieved two times higher than those found in the quartz-sand. The highest and lowest SiO2-NPs recoveries were also achieved from the quartz-sand and limestone columns, respectively. The experimental results closely replicated the general trends predicted by the filtration and DLVO calculations. Overall, NPs mobility through a porous medium was found to be strongly dependent on NP surface charge, NP suspension stability against deposition, and porous medium surface charge and roughness. PMID:26373598
Interim report on the ground-water resources of Manatee County, Florida
Peek, Harry M.; Anders, Robert B.
1955-01-01
Manatee County comprises an area of about 800 square miles adjacent to the Gulf of Mexico in the southwestern part of the Florida peninsula. The county is underlain at depths ranging from about 200 to 350 feet by a series of limestone formations of Tertiary age having a total thickness of several thousand feet. The upper part of the limestone section consists of the Ocala group of Eocene age, the Suwannee limestone of Oligocene age, and the Tampa formation of early Miocene age. These limestone formations are overlain by the Hawthorn formation of middle Miocene age which consists of interbedded clay, limestone, and sand. The Hawthorn is overlain by undifferentiated deposits of sand, limestone, and shell of Pliocene(?) and Pleistocene age that range in thickness from a few feet to about 75 feet.
Size and performance of anoxic limestone drains to neutralize acdic mine drainagei
Cravotta, C.A.
2003-01-01
Acidic mine drainage (AMD) can be neutralized effectively in underground, anoxic limestone drains (ALDs). Owing to reaction between the AMD and limestone (CaCO3), the pH and concentrations of alkalinity and calcium increase asymptotically with detention time in the ALD, while concentrations of sulfate, ferrous iron, and manganese typically are unaffected. This paper introduces a method to predict the alkalinity produced within an ALD and to estimate the mass of limestone required for its construction on the basis of data from short-term, closed-container (cubitainer) tests. The cubitainer tests, which used an initial mass of 4 kg crushed limestone completely inundated with 2.8 L AMD, were conducted for 11 to 16 d and provided estimates for the initial and maximum alkalinities and corresponding rates of alkalinity production and limestone dissolution. Long-term (5-11 yr) data for alkalinity and CaCO3 flux at the Howe Bridge, Morrison, and Buck Mountain ALDs in Pennsylvania, USA, indicate that rates of alkalinity production and limestone dissolution under field conditions were comparable with those in cubitainers filled with limestone and AMD from each site. The alkalinity of effluent and intermediate samples along the flow path through the ALDs and long-term trends in the residual mass of limestone and the effluent alkalinity were estimated as a function of the computed detention time within the ALD and second-order dissolution rate models for cubitainer tests. Thus, cubitainer tests can be a useful tool for designing ALDs and predicting their performance.
USDA-ARS?s Scientific Manuscript database
Introduction: If conventionally treated reclaimed water (RW) is to be adopted as analternative to freshwater irrigation, it is necessary to investigate reuse site-based mitigation options that can further reduce contaminantssuch as foodborne pathogens andpharmaceuticals and personal care products (P...
Return on Investment in College Education. The Guardians Initiative: Reclaiming the Public Trust
ERIC Educational Resources Information Center
Association of Governing Boards of Universities and Colleges, 2017
2017-01-01
"Return on Investment in College Education" is the second publication in a series of informational briefings developed as part of The Guardians Initiative: Reclaiming the Public Trust, an effort to educate and engage trustees as advocates on key issues in higher education. What is the return on investment (ROI) in college education?…
The Business of Higher Education. The Guardians Initiative: Reclaiming the Public Trust
ERIC Educational Resources Information Center
Association of Governing Boards of Universities and Colleges, 2017
2017-01-01
This report is first in a series of informational briefings developed as part of "The Guardians Initiative: Reclaiming the Public Trust," an effort to educate and engage trustees as advocates on key issues in higher education. While the tone of public criticism of higher education has sharpened, public understanding about the sector's…
30 CFR 77.209 - Surge and storage piles.
Code of Federal Regulations, 2014 CFR
2014-07-01
... 30 Mineral Resources 1 2014-07-01 2014-07-01 false Surge and storage piles. 77.209 Section 77.209... Installations § 77.209 Surge and storage piles. No person shall be permitted to walk or stand immediately above a reclaiming area or in any other area at or near a surge or storage pile where the reclaiming...
30 CFR 77.209 - Surge and storage piles.
Code of Federal Regulations, 2012 CFR
2012-07-01
... 30 Mineral Resources 1 2012-07-01 2012-07-01 false Surge and storage piles. 77.209 Section 77.209... Installations § 77.209 Surge and storage piles. No person shall be permitted to walk or stand immediately above a reclaiming area or in any other area at or near a surge or storage pile where the reclaiming...
Langer, William H.; San, Juan A.; Rau, Greg H.; Caldeira, Ken
2009-01-01
Large amounts of limestone fines co-produced during the processing of crushed limestone may be useful in the sequestration of carbon dioxide (CO2). Accelerated weathering of limestone (AWL) is proposed as a low-tech method to capture and sequester CO2 from fossil fuel-fired power plants and other point sources such as cement manufacturing. AWL reactants are readily available, inexpensive and environmentally benign. Waste CO2 is hydrated with water to produce carbonic acid. This reacts with and is neutralized by limestone fines, thus converting CO2 gas to dissolved calcium bicarbonate.
0-6686 : improving DMS 9210 requirements for limestone rock asphalt : [project summary].
DOT National Transportation Integrated Search
2013-08-01
Limestone rock asphalt (LRA) mixtures have : been produced and placed for several decades : using specification requirements currently listed : under DMS 9210, Limestone Rock Asphalt (LRA). : Several Texas Department of Transportation : (TxDOT) distr...
Toxicity of acid mine pit lake water remediated with limestone and phosphorus.
Neil, Luke L; McCullough, Clint D; Lund, Mark A; Evans, Louis H; Tsvetnenko, Yuri
2009-11-01
Pit lakes are increasingly common worldwide and have potential to provide many benefits. However, lake water toxicity may require remediation before beneficial end uses can be realised. Three treatments to remediate AMD (pH approximately 4.8) pit lake water containing elevated concentrations of Al and Zn from Collie, Western Australia were tested in mesocosms. Treatments were: (a) limestone neutralisation (L), (b) phosphorus amendment (P), and (c) combined limestone neutralisation and phosphorus amendment (L+P). Laboratory bioassays with Ceriodaphnia cf. dubia, Chlorella protothecoides and Tetrahymena thermophila assessed remediation. Limestone neutralisation increased pH and reduced heavy metal concentrations by 98% (Al) to 14% (Mg), removing toxicity to the three test species within 2 months. Phosphorus amendment removed toxicity after 6 months of treatment. However, phosphorus amendment to prior limestone neutralisation failed to reduce toxicity more than limestone neutralisation alone. Low concentrations of both phosphorus and nitrogen appear to limit phytoplankton population growth in all treatments.
Effects of sorbent attrition on utilization
DOE Office of Scientific and Technical Information (OSTI.GOV)
Keener, T.C.; Khang, Soon-Jai; Lee, S.K.
1992-03-01
Attrition of surface product levers of sulfite/sulfate may be the key to substantially increasing sorbent utilization in new dry scrubbing processes. This conclusion has been reached from research results obtained from new gas/solid contacting methods such as the Circulating Fluidized Bed Absorber and the Limestone Emission Control method. An additional savings may be reduced by the use of large initial sorbent, particle sizes which greatly reduces the cost of grinding and sorbent preparation. The objectives of project 1.7 were then to study attrition of sorbent particles in a systematic fashion in order to determine how to use attrition to increasemore » sorbent utilization. This was to be carried out by the construction of a bench scale fluidized bed where a series of experiments were to be conducted to measure attrition of lime and limestone samples. This has been accomplished and the project proceeded as anticipated. The results indicate that attrition differs for wet and dry conditions for certain sorbents and that these differences are substantial. Under dry conditions, the results of attrition tests on carefully characterized lime samples indicate that mechanical abrasion is the primary attrition mechanism. The rate of attrition is seen to be similar to a first order chemical reaction where the bed mass (or total surface area) is analagous to reactant concentration. A model for mechanical attrition is presented which expresses the rate constant in an Arrhenius type form proportional to a pseudo attrition activation energy and excess gas energy above a minimum level. The value of this pseudo attrition activation energy for lime has been found to be 106 KJ/KG. For the attrition of wetted lime particles in a fluidized bed. the attrition rate has been found to be directly related to the volumetric flow rate of injected water.« less
Retention and transport of graphene oxide in water-saturated limestone media.
Dong, Shunan; Sun, Yuanyuan; Gao, Bin; Shi, Xiaoqing; Xu, Hongxia; Wu, Jianfeng; Wu, Jichun
2017-08-01
In this work, column experiments were conducted to investigate the transport characteristics of graphene oxide (GO) nanoparticles in limestone media under various electrolytes, solution pH, and humic acid (HA) concentration conditions. In the limestone media, GO exhibited relatively low mobility with the mass recovery rate lower than 65.2%, even when solution ionic strength was low. The presence of HA enhanced its mobility. In addition, the presence of S 2- , a divalent anion, also promoted GO transport in limestone media compared to Cl - under similar ionic strength conditions through neutralizing more positive charge and thus diminishing the cation bridging. Solution pH showed slight effect on the transport of GO in limestone with the mass recovery range from 40.3% to 51.7%. Over all, decreases in solution pH, HA concentration and increases in solution ionic strength reduced the mobility of GO in the limestone media under the tested conditions. These results indicated both environmental conditions and media characteristics played important roles in controlling GO fate and transport in porous media. The one-site kinetic deposition model was applied to describe the interactions between the GO and limestone media and model simulations fitted the observed experimental data very well. As limestone is an important component of aquiferous media in subsurface, findings from this study elucidated the key factors and processes controlling the fate of GO particles in limestone media, which can inform the prediction and assessment of the risks of GO in groundwater environment. Copyright © 2017 Elsevier Ltd. All rights reserved.
NASA Astrophysics Data System (ADS)
Leanza, H. A.; Mazzini, A.; Corfu, F.; Llambías, E. J.; Svensen, H.; Planke, S.; Galland, O.
2013-03-01
New radiometric U-Pb ages obtained on zircon crystals from Early Jurassic ash layers found within beds of the Chachil Limestone at its type locality in the Chachil depocentre (southern Neuquén Basin) confirm a Pliensbachian age (186.0 ± 0.4 Ma). Additionally, two ash layers found in limestone beds in Chacay Melehue at the Cordillera del Viento depocentre (central Neuquén Basin) gave Early Pliensbachian (185.7 ± 0.4 Ma) and earliest Toarcian (182.3 ± 0.4 Ma) U-Pb zircon ages. Based on these new datings and regional geological observations, we propose that the limestones cropping out at Chacay Melehue are correlatable with the Chachil Limestone. Recent data by other authors from limestones at Serrucho creek in the upper Puesto Araya Formation (Valenciana depocentre, southern Mendoza) reveal ages of 182.16 ± 0.6 Ma. Based on these new evidences, we consider the Chachil Limestone an important Early Jurassic stratigraphic marker, representing an almost instantaneous widespread flooding episode in western Gondwana. The unit marks the initiation in the Neuquén Basin of the Cuyo Group, followed by widespread black shale deposition. Accordingly, these limestones can be regarded as the natural seal of the Late Triassic -earliest Jurassic Precuyano Cycle, which represents the infill of halfgrabens and/or grabens related to a strong extensional regime. Paleontological evidence supports that during Pliensbachian-earliest Toarcian times these limestones were deposited in western Gondwana in marine warm water environments.
Inelastic Compaction in High-Porosity Limestone Monitored Using Acoustic Emissions
NASA Astrophysics Data System (ADS)
Baud, Patrick; Schubnel, Alexandre; Heap, Michael; Rolland, Alexandra
2017-12-01
We performed a systematic investigation of mechanical compaction and strain localization in Saint-Maximin limestone, a quartz-rich, high-porosity (37%) limestone from France. Our new data show that the presence of a significant proportion of secondary mineral (i.e., quartz) did not impact the mechanical strength of the limestone in both the brittle faulting and cataclastic flow regimes, but that the presence of water exerted a significant weakening effect. In contrast to previously published studies on deformation in limestones, inelastic compaction in Saint-Maximin limestone was accompanied by abundant acoustic emission (AE) activity. The location of AE hypocenters during triaxial experiments revealed the presence of compaction localization. Two failure modes were identified in agreement with microstructural analysis and X-ray computed tomography imaging: compactive shear bands developed at low confinement and complex diffuse compaction bands formed at higher confinement. Microstructural observations on deformed samples suggest that the recorded AE activity associated with inelastic compaction, unusual for a porous limestone, could have been due to microcracking at the quartz grain interfaces. Similar to published data on high-porosity macroporous limestones, the crushing of calcite grains was the dominant micromechanism of inelastic compaction in Saint-Maximin limestone. New P wave velocity data show that the effect of microcracking was dominant near the yield point and resulted in a decrease in P wave velocity, while porosity reduction resulted in a significant increase in P wave velocity beyond a few percent of plastic volumetric strain. These new data highlight the complex interplay between mineralogy, rock microstructure, and strain localization in porous rocks.
The reliability evaluation of reclaimed water reused in power plant project
NASA Astrophysics Data System (ADS)
Yang, Jie; Jia, Ru-sheng; Gao, Yu-lan; Wang, Wan-fen; Cao, Peng-qiang
2017-12-01
The reuse of reclaimed water has become one of the important measures to solve the shortage of water resources in many cities, But there is no unified way to evaluate the engineering. Concerning this issue, it took Wanneng power plant project in Huai city as a example, analyzed the reliability of wastewater reuse from the aspects of quality in reclaimed water, water quality of sewage plant, the present sewage quantity in the city and forecast of reclaimed water yield, in particular, it was necessary to make a correction to the actual operation flow rate of the sewage plant. the results showed that on the context of the fluctuation of inlet water quality, the outlet water quality of sewage treatment plants is basically stable, and it can meet the requirement of circulating cooling water, but suspended solids(SS) and total hardness in boiler water exceed the limit, and some advanced treatment should be carried out. In addition, the total sewage discharge will reach 13.91×104m3/d and 14.21×104m3/d respectively in the two planning level years of the project. They are greater than the normal collection capacity of the sewage system which is 12.0×104 m3/d, and the reclaimed water yield can reach 10.74×104m3/d, which is greater than the actual needed quantity 8.25×104m3/d of the power plant, so the wastewater reuse of this sewage plant are feasible and reliable to the power plant in view of engineering.
Code of Federal Regulations, 2010 CFR
2010-07-01
... County Lawrence County Lee County Limestone County Lowndes County Macon County Madison County Marengo... Lauderdale County Lawrence County Lee County Limestone County Lowndes County Macon County Madison County... Lamar County Lauderdale County Lawrence County Lee County Limestone County Lowndes County Macon County...
Code of Federal Regulations, 2011 CFR
2011-07-01
... County Lawrence County Lee County Limestone County Lowndes County Macon County Madison County Marengo... County Houston County Jackson County Lamar County Lauderdale County Lawrence County Lee County Limestone... County Houston County Jackson County Lamar County Lauderdale County Lawrence County Lee County Limestone...
Recovery of Navy distillate fuel from reclaimed product. Volume I. Technical discussion
DOE Office of Scientific and Technical Information (OSTI.GOV)
Brinkman, D.W.; Whisman, M.L.
1984-11-01
In an effort to assist the Navy to better utilize its waste hydrocarbons, NIPER, with support from the US Department of Energy, is conducting research designed to ultimately develop a practical technique for converting Reclaimed Product (RP) into specification Naval Distillate Fuel (F-76). The first phase of the project was focused on reviewing the literature and available information from equipment manufacturers. The literature survey has been carefully culled for methodology applicable to the conversion of RP into diesel fuel suitable for Navy use. Based upon the results of this study, a second phase has been developed and outlined in whichmore » experiments will be performed to determine the most practical recycling technologies. It is realized that the final selection of one particular technology may be site-specific due to vast differences in RP volume and available facilities. A final phase, if funded, would involve full-scale testing of one of the recommended techniques at a refueling depot. The Phase I investigations are published in two volumes. Volume 1, Technical Discussion, includes the narrative and Appendices I and II. Appendix III, a detailed Literature Review, includes both a narrative portion and an annotated bibliography containing about 800 referenvces and abstracts. This appendix, because of its volume, has been published separately as Volume 2. 18 figures, 4 tables.« less
Analysis of medieval limestone sculpture from southwestern France and the Paris Basin by NAA
DOE Office of Scientific and Technical Information (OSTI.GOV)
Holmes, L.; Harbottle, G.
1994-12-31
Compositional characterization of limestone from sources known to medieval craftsmen and from the monuments they built can be used in conjunction with stylistic and iconographic criteria to infer geographic origin of sculptures that have lost their histories. Limestone from 47 quarrying locations in France and from numerous medieval monuments have been subjected to neutron activation analysis (NAA) to form the nucleus of the Brookhaven Limestone Database. Even though the method and techniques of NAA are well established, this paper briefly summarizes the parameters and experimental conditions useful for determining those concentration variables for which limestone from different sources exhibits significantmore » and reproducible differences.« less
John J. Janowiak; Robert H. Falk; Brad A. Gething; John A. Tsirigotis
2014-01-01
This study determined the mechanical properties of nail-laminated (nail-lam) posts manufactured from reclaimed chromated copper arsenate (CCA)âtreated decking lumber. Though CCA-treated lumber is no longer accepted for use in residential applications, it is permitted in agricultural and industrial applications where health and environmental impacts are deemed to be...
Reforestation species study on a reclaimed surface mine in western Maryland
Jay A. Engle
1980-01-01
Westvaco Forest Research established a species comparison test including eighteen species of trees in the spring of 1978 on a recently reclaimed surface mine in Garrett County, Maryland. After two growing seasons height growth of all species has not been impressive. Seven species have better than 75 percent survival with pitch pine being best. Seven other species have...
ERIC Educational Resources Information Center
Rudolph, Michael Allen
2014-01-01
"Reclaiming Ga?" is a curious title for readers oblivious to the fact that the meaning of "?a?" has been lost. Indeed, "?a?" is but one of several linguistic signals of Koine Greek that allude the grasp of the modern scholar. This has created an environment within NT studies described here as conjunctive…
Leidos Reclaims Defelice Cup at Annual Golf Tournament | Poster
By Ashley DeVine, Staff Writer Leidos Biomedical Research reclaimed the Defelice Cup trophy from NCI at the eighth annual Ronald H. Defelice golf tournament, held October 14. The final score was 15–7, with Leidos Biomed tying the series 4 to 4. Fourteen players on each team battled it out at Rattlewood golf course in Mount Airy, Md.
ERIC Educational Resources Information Center
Ebrahim, H. B.; Verbeek, D. C.; Mashiya, J. N.
2011-01-01
In developing the Advanced Certificate in Teaching (ACT) as a professional qualification for continuing teacher education for early schooling at the University of KwaZulu-Natal we asked the following: "What are the enabling roles foundation phase teachers need to play in order to reclaim their space as agents who significantly influence their…
The biological costs of not reclaiming bentonite mine spoils
Carolyn Hull Sieg; Daniel W. Uresk; Richard M. Hansen
1982-01-01
Bentonite clay has been mined in the northern Great Plains for more than 80 years. Until the late 1960's, mine spoil materials were left in steep piles and no effort was made to restore biological productivity to these disturbed sites. As a result, unreclaimed spoils are barren and eroded. The biological costs of not reclaiming these spoils are examined in this...
ERIC Educational Resources Information Center
Chapin, Rosemary K.; Sergeant, Julie F.; Landry, Sarah; Leedahl, Skye N.; Rachlin, Roxanne; Koenig, Terry; Graham, Annette
2013-01-01
Purpose: Stigma and lack of access to providers create barriers to mental health treatment for older adults living in the community. In order to address these barriers, we developed and evaluated a peer support intervention for older adults receiving Medicaid services. Design and Methods: Reclaiming Joy is a mental health intervention that pairs…
Response of transplanted aspen to irrigation and weeding on a Colorado reclaimed surface coal mine
Robert C. Musselman; Wayne D. Shepperd; Frederick W. Smith; Lance A. Asherin; Brian W. Gee
2012-01-01
Successful re-establishment of aspen (Populus tremuloides Michx.) on surface-mined lands in the western United States is problematic because the species generally regenerates vegetatively by sprouting from parent roots in the soil; however, topsoil is removed in the mining process. Previous attempts to plant aspen on reclaimed mine sites have failed because...
The Passionate Learner: How Teachers and Parents Can Help Children Reclaim the Joy of Discovery.
ERIC Educational Resources Information Center
Fried, Robert L.
This book is a guide to reclaiming students' passionate engagement in learning. It uses stories from classrooms; the voices of teachers, parents, and students; and practical suggestions to advocate a view of curriculum as a web of relationships. There are 16 chapters in four parts. Part 1, "The Promise of Passionate Learning," includes…
Estimating degradation-related settlement in two landfill-reclaimed soils by sand-salt analogues.
McDougall, J R; Fleming, I R; Thiel, R; Dewaele, P; Parker, D; Kelly, D
2018-04-25
Landfill reclaimed soil here refers to largely degraded materials excavated from old landfill sites, which after processing can be reinstated as more competent fill, thereby restoring the former landfill space. The success of the process depends on the presence of remaining degradable particles and their influence on settlement. Tests on salt-sand mixtures, from which the salt is removed, have been used to quantify the impact of particle loss on settlement. Where the amount of particle loss is small, say 10% by mass or less, settlements are small and apparently independent of lost particle size. A conceptual model is presented to explain this behaviour in terms of nestling particles and strong force chains. At higher percentages of lost particles, greater rates of settlement together with some sensitivity to particle size were observed. The conceptual model was then applied to two landfill reclaimed soils, the long-term settlements of which were found to be consistent with the conceptual model suggesting that knowledge of particle content and relative size are sufficient to estimate the influence of degradable particles in landfill reclaimed soils. Copyright © 2018 Elsevier Ltd. All rights reserved.
Pan, Neng; Hou, Zhen-An; Chen, Wei-Ping; Jiao, Wen-Tao; Peng, Chi; Liu, Wen
2012-12-01
The physicochemical properties of soils might be changed under the long-term reclaimed water irrigation. Its effects on soil biological activities have received great attentions. We collected surface soil samples from urban green spaces and suburban farmlands of Beijing. Soil microbial biomass carbon (SMBC), five types of soil enzyme activities (urease, alkaline phosphatase, invertase, dehydrogenase and catalase) and physicochemical indicators in soils were measured subsequently. SMBC and enzyme activities from green land soils irrigated with reclaimed water were higher than that of control treatments using drinking water, but the difference is not significant in farmland. The SMBC increased by 60.1% and 14.2% than those control treatments in 0-20 cm soil layer of green land and farmland, respectively. Compared with their respective controls, the activities of enzymes in 0-20 cm soil layer of green land and farmland were enhanced by an average of 36.7% and 7.4%, respectively. Investigation of SMBC and enzyme activities decreased with increasing of soil depth. Significantly difference was found between 0-10 cm and 10-20 cm soil layer in green land. Soil biological activities were improved with long-term reclaimed water irrigation in Beijing.
Aquifers in coastal reclaimed lands - real world assessments
NASA Astrophysics Data System (ADS)
Saha, A.; Bironne, A.; Vonhögen-Peeters, L.; Lee, W. K.; Babovic, V. M.; Vermeulen, P.; van Baaren, E.; Karaoulis, M.; Blanchais, F.; Nguyen, M.; Pauw, P.; Doornenbal, P.
2017-12-01
Climate change and population growth are significant concerns in coastal regions around the world, where more than 30% of the world's population reside. The numbers continue to rise as coastal areas are increasingly urbanized. Urbanization creates land shortages along the coasts, which has spurred coastal reclamation activities as a viable solution. In this study, we focus on these reclamation areas; reclaimed areas in Singapore, and in the Netherlands, and investigate the potential of these reclaimed bodies as artificial aquifers that could attenuate water shortage problems in addition to their original purpose. We compare how the reclamation methods determine the hydrogeological characteristics of these manmade aquifers. We highlight similarities in freshwater lens development in the artificial shallow aquifers under natural recharge under diverse conditions, i.e. tropical and temperate zones, using numerical models. The characteristics and responses of these aquifers with dynamic freshwater-saltwater interface are contrasted against naturally occurring coastal aquifers where equilibrium was disturbed by anthropogenic activities. Finally, we assess the risks associated with subsidence and saltwater intrusion, combining measurements and numerical models, in case these aquifers are planned for Aquifer Storage and Recovery (ASR) or Managed Aquifer Recharge (MAR) strategies. Relative performances of some ASR schemes are simulated and compared in the reclaimed lands.
DOE Office of Scientific and Technical Information (OSTI.GOV)
Zevenhoven, C.A.P.; Yrjas, K.P.; Hupa, M.M.
1998-07-01
Fluidized bed combustion or gasification allows for in-bed sulfur capture with a calcium-based sorbent such as limestone or dolomite. Sorbent particle size, porosity, internal surface, and their variation during conversion have great influence on the conversion of the sorbent. The uptake of SO{sub 2} and H{sub 2}S by five physically different limestones is discussed, for typical pressurized fluidized bed combustor or gasifier conditions: 850/950 C, 15/20 bar. Tests were done in a pressurized thermogravimetric apparatus (P-TGA), the size of the limestone particles was 250--300 {micro}m. It is stressed that the limestones remain uncalcined. A changing internal structure (CIS) model ismore » presented in which reaction kinetics and product layer diffusion are related to the intraparticle surface of reaction, instead of the outer particle surface as in unreacted shrinking core (USC)-type models. The random pore model was used for describing the changing internal pore and reaction surfaces. Rate parameters were extracted for all five limestones using the CIS model and a USC model with variable effective diffusivity. Differences in the sulfur capture performance of the limestones were evaluated. Plots of the CaSO{sub 4} or CaS product layer thickness as a function of conversion are given, and the relative importance of limestone porosity and internal surface is discussed.« less
Research on wastewater reuse planning in Beijing central region.
Jia, H; Guo, R; Xin, K; Wang, J
2005-01-01
The need to implement wastewater reuse in Beijing is discussed. Based on the investigation of the built wastewater reuse projects in Beijing, the differences between small wastewater reuse system and large systems were analyzed according to the technical, economical and social issues. The advantages and disadvantages of the small system and the large system were then given. In wastewater reuse planning in Beijing urban region, the large system was adopted. The rations of reclaimed water for difference land use type, including industrial reuse, municipal reuse, grass irrigation, and scenes water reuse were determined. Then according to the land use information in every block in central Beijing, using GIS techniques, the amounts of the reclaimed water needed in every block were calculated, and the main pipe system of reclaimed water was planned.
Yeap, Kong Seng; Mohd Yaacob, Naziaty; Rao, Sreenivasaiah Purushothama; Hashim, Nor Rasidah
2012-12-01
This article presents lessons learned from a design project that explored the possibility of incorporating waste into the design of a school prototype. The authors worked with professional architects, a waste artist, environmental scientists and local waste operators to uncover new uses and applications for discarded items. As a result, bottles, aluminium cans, reclaimed doors, crushed concrete and second-hand bricks, etc. were identified, explored and integrated into the architectural design. This article serves as a catalyst that advocates the use of reclaimed materials in the field of design and planning. In particular, it highlights the challenges and issues that need to be addressed in carrying out design work with waste. Designers and practitioners interested in minimizing waste generation by proposing the use of reclaimed materials will find this article useful.
Karklins, O.L.
1984-01-01
The Lexington Limestone and the Clays Ferry Formation of Kentucky contain an abundant and diversified fossil invertebrate fauna. This report is concerned with the trepostome and cystoporate bryozoans that constitute a major part of that fauna. The Lexington Limestone, largely a biofragmental fossiliferous limestone, rests disconformably on the Tyrone Limestone (Middle Ordovician). The Clays Ferry Formation consists of approximately equal amounts of biofragmentallimestone and shale, and it overlies conformably, or intertongues with, the upper part of the Lexington Limestone. The Clays Ferry Formation is overlain by the Garrard Siltstone (Upper Ordovician) in central Kentucky and intertongues with the Kope Formation (Upper Ordovician) in northern Kentucky. The MiddleUpper Ordovician boundary falls within the upper part of the Lexington Limestone and laterally equivalent strata of the Clays Ferry Formation. The Lexington Limestone has been divided into 12 members, consisting of calcarenites, calcisiltites, calcilutites, nodular limestones, and shales in various amounts, that intertongue complexly. Because of the great abundance of bryozoans this study is generally limited to bryozoans recovered from, in ascending order, the Grier Limestone Member, the Perryville Limestone Member, the Brannon Member, the Tanglewood Limestone Member, and the Millersburg Member of the Lexington Limestone and from the Clays Ferry Formation and its Point Pleasant Tongue. The trepostome and cystoporate bryozoans discussed are referred to 36 species belonging to 22 genera. The trepostome component includes 29 species belonging to 16 genera: Amplexopora, Atactoporella, Balticopora, Batostoma, Cyphotrypa, Dekayia, Eridotrypa, Hetero-_ trypa, Homotrypa, Homotrypella, Mesotrypa, Parvohallopora, Peronopora, Prasopora, Stigmatella, and Tarphophragma, a new genus. Five of the trepostome species are new: Balticopora arcuatilis, Cyphotrypa switzeriensis, Dekayia epetrima, Eridotrypa sadievillensis, and Homotrypa cressmani. The cystoporate bryozoans include 7 species belonging to 6 genera: Acanthoceramoporella, Ceramophylla, Ceramoporella, Constellaria, Crepipora, and Papillalunaria. One cystoporate species is new: Acanthoceramoporella valliensis. The trepostome and cystoporate fauna on the generic level is, with few exceptions, cosmopolitan. Five genera, Eridotrypa, Parvohallopora, Heterotrypa, Constellaria, and Peronopora, dominate the fauna, comprising about 77 percent of the thin-sectioned specimens. On the species level the fauna is endemic to the Ordovician of eastern North America and is biostratigraphically restricted to strata of late Blackriveran Stage (Middle Ordovician) to early Maysvillian Stage (middle Late Ordovician). In Kentucky the species of this fauna are restricted to strata between the base of the Lexington Limestone (Kirkfieldian Stage, Middle Ordovician) and the top of the Clays Ferry Formation and its lateral equivalent the Kope Formation (Edenian Stage, lower Upper Ordovician), with few species ranging into strata of early Maysvillian Stage (middle Late Ordovician) in adjacent areas of Indiana and Ohio. On the basis of the known geographic distribution of the various species, the fauna in Kentucky consists of an intermingling of immigrant and endemic species. The immigrant component (11 species) is generally limited to the lower half of the Lexington-Clays Ferry depositional sequence and permits the establishment of a degree of biostratigraphic equivalence with outcrop areas in Minnesota-Iowa and New York. On the species level the fauna in Kentucky is dominated by four: Constellaria teres, Heterotrypa foliacea, Parvohallopora nodulosa, and Eridotrypa mutabilis, in decreasing relative abundance. The first three species are restricted to the upper part of the Lexington Limestone and the Clays Ferry Formation. Eridotrypa mutabilis is restricted to the middle part of the Lexington Limestone and the lower half of the Clays Fer
Cravotta, Charles A.
2010-01-01
A variety of passive and semi-passive treatment systems were constructed by state and local agencies to neutralize acidic mine drainage (AMD) and reduce the transport of dissolved metals in the upper Swatara Creek Basin in the Southern Anthracite Coalfield in eastern Pennsylvania. To evaluate the effectiveness of selected treatment systems installed during 1995–2001, the US Geological Survey collected water-quality data at upstream and downstream locations relative to each system eight or more times annually for a minimum of 3 years at each site during 1996–2007. Performance was normalized among treatment types by dividing the acid load removed by the size of the treatment system. For the limestone sand, open limestone channel, oxic limestone drain, anoxic limestone drain (ALD), and limestone diversion well treatment systems, the size was indicated by the total mass of limestone; for the aerobic wetland systems, the size was indicated by the total surface area of ponds and wetlands. Additionally, the approximate cost per tonne of acid treated over an assumed service life of 20 years was computed. On the basis of these performance metrics, the limestone sand, ALD, oxic limestone drain, and limestone diversion wells had similar ranges of acid-removal efficiency and cost efficiency. However, the open limestone channel had lower removal efficiency and higher cost per ton of acid treated. The wetlands effectively attenuated metals transport but were relatively expensive considering metrics that evaluated acid removal and cost efficiency. Although the water-quality data indicated that all treatments reduced the acidity load from AMD, the ALD was most effective at producing near-neutral pH and attenuating acidity and dissolved metals. The diversion wells were effective at removing acidity and increasing pH of downstream water and exhibited unique potential to treat moderate to high flows associated with storm flow conditions.
Sustainable Blended Cements-Influences of Packing Density on Cement Paste Chemical Efficiency.
Knop, Yaniv; Peled, Alva
2018-04-18
This paper addresses the development of blended cements with reduced clinker amount by partial replacement of the clinker with more environmentally-friendly material (e.g., limestone powders). This development can lead to more sustainable cements with reduced greenhouse gas emission and energy consumption during their production. The reduced clicker content was based on improved particle packing density and surface area of the cement powder by using three different limestone particle diameters: smaller (7 µm, 3 µm) or larger (70 µm, 53 µm) than the clinker particles, or having a similar size (23 µm). The effects of the different limestone particle sizes on the chemical reactivity of the blended cement were studied by X-ray diffraction (XRD), thermogravimetry and differential thermogravimetry (TG/DTG), loss on ignition (LOI), isothermal calorimetry, and the water demand for reaching normal consistency. It was found that by blending the original cement with limestone, the hydration process and the reactivity of the limestone itself were increased by the increased surface area of the limestone particles. However, the carbonation reaction was decreased with the increased packing density of the blended cement with limestone, having various sizes.
STEAM INJECTION INTO FRACTURED LIMESTONE AT LORING AIR FORCE BASE
A research project on steam injection for the remediation of spent chlorinated solvents from fractured limestone was recently undertaken at the former Loring AFB in Limestone, ME. Participants in the project include the Maine Department of Environmental Protection, EPA Region I,...
Structure of the top of the Karnak Limestone Member (Ste. Genevieve) in Illinois
DOE Office of Scientific and Technical Information (OSTI.GOV)
Bristol, H.M.; Howard, R.H.
1976-01-01
To facilitate petroleum exploration in Illinois, the Illinois State Geological Survey presents a structure map (for most of southern Illinois) of the Karnak Limestone Member--a relatively pure persistent limestone unit (generally 10 to 35 ft thick) in the Ste. Genevieve Limestone of Genevievian age. All available electric logs and selected studies of well cuttings were used in constructing the map. Oil and gas development maps containing Karnak-structure contours are on open file at the ISGS.
11. PUMP HOUSE AND WEIGHING ROOM Fish were pumped from ...
11. PUMP HOUSE AND WEIGHING ROOM Fish were pumped from floating hoppers, to the pump house (on the far right). From there they were either lifted by conveyor belt to the weighing room (top center) and thence to the holding tanks, or were washed through sealers, weighed and then sluiced to holding tanks. The process used depended upon the type and size of fish. The square cement vat (center) was to be a settling tank from which fish oil, reclaimed from the reduction process, was to be pumped into the round metal tank (above the vat). This process however, was never fully utilized before the sardines ran out. - Hovden Cannery, 886 Cannery Row, Monterey, Monterey County, CA
Marshall, Andrew J; Salas, Leonardo A; Stephens, Suzette; Engström, Linda; Meijaard, Erik; Stanley, Scott A
2007-02-01
The Indonesian province of East Kalimantan is home to some of the largest remaining contiguous tracts of lowland Dipterocarp forest on the island of Borneo. Nest surveys recently conducted in these forests indicated the presence of a substantial population of Eastern Bornean orangutans (Pongo pygmaeus morio) in the Berau and East Kutai regencies in the northern half of the province. The Sangkulirang Peninsula contains extensive limestone karst forests in close proximity to the lowland Dipterocarp forests inhabited by orangutans in these regencies. Orangutans have been sighted in these limestone karst forests, but the importance of this forest type for orangutans has been unclear. Therefore, we conducted 49 km of nest surveys in limestone karst forest to obtain the first quantitative estimates of orangutan densities in this habitat, and walked 28 km of surveys in nearby lowland Dipterocarp forests for comparison. We also gathered basic ecological data along our transects in an attempt to identify correlates of orangutan abundance across these habitat types. Undisturbed limestone karst forests showed the lowest orangutan densities (147 nests/km(2), 0.82 indiv/km(2)), disturbed limestone forests had intermediate densities (301 nests/km(2), 1.40 indiv/km(2)), and undisturbed lowland Dipterocarp forests contained the highest density (987 nests/km(2), 5.25 indiv/km(2)), significantly more than the undisturbed limestone karst forests. This difference was not correlated with variation in liana abundance, fig stem density, or stump density (an index of forest disturbance). Therefore, other factors, such as the relatively low tree species diversity of limestone karst forests, may explain why orangutans appear to avoid these areas. We conclude that limestone karst forests are of low relevance for safeguarding the future of orangutans in East Kalimantan.
Generalized thickness of the Floridan aquifer, Southwest Florida Water Management District
Wolansky, R.M.; Garbade, J.M.
1981-01-01
This map report presents the thickness of the Floridan aquifer in the Southwest Florida Water Management District. The Floridan aquifer ranges in thickness from 600 feet in the northern part of the District to 2,400 feet in the southern part. It is composed chiefly of limestone and dolomite beds that range in age from early Miocene to middle Eocene. For this investigation, the formations considered to be part of the Floridan aquifer are: Lake City and Avon Park Limestones of middle Eocene age; Ocala Limestone of late Eocene age; Suwannee Limestone of Oligocene age; and permeable parts of the Tampa Limestone and Hawthorn Formation of Miocene age that are in hydrologic contact with the rest of the aquifer. (USGS)
Chapter 9: Planting hardwood tree seedlings on reclaimed mine land in the Appalachian region
V. Davis; J. Franklin; C. Zipper; P. Angel
2017-01-01
The Forestry Reclamation Approach (FRA) is a method of reclaiming surface coal mines to forested postmining land use (Chapter 2, this volume). "Use proper tree planting techniques" is Step 5 of the FRA; when used with the other FRA steps, proper tree planting can help to ensure successful reforestation. Proper care and planting of tree seedlings is essential...
ERIC Educational Resources Information Center
Strathdee, Rob
2013-01-01
This paper uses Habermas' theory of the state and his idea of legitimation crisis to critically evaluate recent reforms in New Zealand designed to engage young people (16-24 years of age) in paid employment and/or education and training. The paper identifies three broad strategies adopted by the state to reclaim the disengaged and hence, resolve…
Infectious Cryptosporidium parvum oocysts in final reclaimed effluent
Gennaccaro, A.L.; McLaughlin, M.R.; Quintero-Betancourt, W.; Huffman, D.E.; Rose, J.B.
2003-01-01
Water samples collected throughout several reclamation facilities were analyzed for the presence of infectious Cryptosporidium parvum by the focus detection method-most-probable-number cell culture technique. Results revealed the presence of infectious C. parvum oocysts in 40% of the final disinfected effluent samples. Sampled effluent contained on average seven infectious oocysts per 100 liters. Thus, reclaimed water is not pathogen free but contains infectious C. parvum.
Shiv Hiremath; Kirsten Lehtoma; Jenise M. Bauman
2013-01-01
We have been planting blight resistant American chestnut seedlings on reclaimed coal mined areas in Southeastern Ohio, which was once within the natural range of the American chestnut. Towards the goal of restoring the American chestnut, we are testing suitable sites that can aid survival, growth and establishment of planted seedlings pre-inoculated with...
Potential Material Sources for Board Products: Used Pallets and Wastewood at Landfills
Philip A. Araman; Robert J. Bush; Vijay S. Reddy
1997-01-01
Millions of tons of pallets and other types of wood waste are being sent to landfills every year. At many landfills wood is or could be reclaimed. One potential use for this material is as furnish for board products. To evaluate the potential to reclaim wood waste for useful products we surveyed municipal solid waste (MSW) and construction and demolition (C&D)...
Hybrid poplar pulpwood and lumber from a reclaimed strip-mine
Walter H. Davidson
1979-01-01
A 2-acre hybrid poplar planting on a reclaimed strip-mine was harvested at age 16. The commercial clearcut yielded 90 tons of pulpwood and 9,400 board feet of lumber. This is equal to a growth rate of approximately 2 cords per acre per year. Selected physical properties of the hybrid poplars were compared with those of other commercial eastern species.
Use of limestone screenings in S-5 surface mixes : final report.
DOT National Transportation Integrated Search
1982-01-01
It is often practical to use limestone screenings in non-polishing S-5 surface mixes in some western areas of Virginia. Also, there has been some conjecture that limestone increases the durability of these mixes. Although the fine aggregate usually h...
Restoring the Nitrogen Cycle in the Boreal Forest - a Case Study from Northern Alberta
NASA Astrophysics Data System (ADS)
Masse, Jacynthe; Grayston, Sue; Prescott, Cindy; Quideau, Sylvie
2014-05-01
The Athabasca oil sands deposit, located in the boreal forests of Northern Alberta, is one of the largest single oil deposits in the world. This deposit rests underneath 40,200 square kilometres of land. To date, an area of about 715 square kilometres has been disturbed by oil sands mining activity (Government of Alberta, 2013). Following surface mining, companies have the legal obligation to restore soil-like profiles that can support the previous land capabilities (Powter et al., 2012). Because of its importance for site productivity, re-establishment of the nitrogen cycle between these reconstructed soils and plants is one of the most critical factors required to insure long term sustainability of reclaimed boreal landscape. High nitrogen deposition recorded in the oil sands area combined with the high level of nitrate found in reclaimed soils raised concerns about the possibility of these reclaimed soils being in early stages of N saturation (Laxton et al 2010; Hemsley, 2012), although little evidence of net nitrification in these reclaimed soils suggests the contrary (Laxton et al. 2012). To date, results on the behaviour of the nitrogen cycle in the reclaimed sites are contradictory. A systematic study of the nitrogen cycle, and especially rates of gross mineralization, nitrification and denitrification, is needed. Our research aimed at 1) measuring the gross rates of nitrogen transformations under different vegetation treatments in both reclaimed and naturally-disturbed (fire) sites and 2) characterizing the microbial communities participating in the nitrogen cycle within the same soils. A series of 20 soils, covering different vegetation treatments (plots planted with aspen (Populus tremuloides), spruce (Picea glauca) and grassland) were investigated. Gross nitrogen transformation rates were measured using 15N pool-dilution (Müller et al. 2007). Microbial communities participating in the N-cycle were characterized using qPCR and pyrosequencing. Differences between nitrogen cycling processes in the different vegetation treatments and in the naturally disturbed sites were found. The reasons for these variances will be discussed. The oil sands will be Canada's environmental legacy for the next several hundred years and recreating functional soils is fundamental to our ability to restore boreal ecosystems after disturbance.
Kulkarni, Prachi; Olson, Nathan D; Paulson, Joseph N; Pop, Mihai; Maddox, Cynthia; Claye, Emma; Rosenberg Goldstein, Rachel E; Sharma, Manan; Gibbs, Shawn G; Mongodin, Emmanuel F; Sapkota, Amy R
2018-10-15
Water recycling continues to expand across the United States, from areas that have access to advanced, potable-level treated reclaimed water, to those having access only to reclaimed water treated at conventional municipal wastewater treatment plants. This expansion makes it important to further characterize the microbial quality of these conventionally-treated water sources. Therefore, we used 16S rRNA gene sequencing to characterize total bacterial communities present in differentially-treated wastewater and reclaimed water (n = 67 samples) from four U.S. wastewater treatment plants and one associated spray irrigation site conducting on-site ultraviolet treatment and open-air storage. The number of observed operational taxonomic units was significantly lower (p < 0.01) in effluent, compared to influent, after conventional treatment. Effluent community structure was influenced more by treatment method than by influent community structure. The abundance of Legionella spp. increased as treatment progressed in one treatment plant that performed chlorination and in another that seasonally chlorinated. Overall, the alpha-diversity of bacterial communities in reclaimed water decreased (p < 0.01) during wastewater treatment and spray irrigation site ultraviolet treatment (p < 0.01), but increased (p < 0.01) after open-air storage at the spray irrigation site. The abundance of Legionella spp. was higher at the sprinkler system pumphouse at the spray irrigation site than in the influent from the treatment plant supplying the site. Legionella pneumophila was detected in conventionally treated effluent samples and in samples collected after ultraviolet treatment at the spray irrigation site, while Legionella feeleii persisted throughout on-site treatment at the spray irrigation site, and, along with Mycobacterium gordonae, was also detected at the sprinkler system pumphouse at the spray irrigation site. These data could inform the development of future treatment technologies and reuse guidelines that address a broader assemblage of the bacterial community of reclaimed water, resulting in reuse practices that may be more protective of public health. Copyright © 2018 Elsevier B.V. All rights reserved.
Toxicity of acid mine pit lake water remediated with limestone and phosphorus
DOE Office of Scientific and Technical Information (OSTI.GOV)
Neil, L.L.; McCullough, C.D.; Lund, M.A.
2009-11-15
Pit lakes are increasingly common worldwide and have potential to provide many benefits. However, lake water toxicity may require remediation before beneficial end uses can be realised. Three treatments to remediate AMD (pH similar to 4.8) pit lake water containing elevated concentrations of Al and Zn from Collie, Western Australia were tested in mesocosms. Treatments were: (a) limestone neutralisation (L), (b) phosphorus amendment (P), and c) combined limestone neutralisation and phosphorus amendment (L+P). Laboratory bioassays with Ceriodaphnia cf. dubia, Chlorella protothecoides and Tetrahymena thermophila assessed remediation. Limestone neutralisation increased pH and reduced heavy metal concentrations by 98% (Al) to 14%more » (Mg), removing toxicity to the three test species within 2 months. Phosphorus amendment removed toxicity after 6 months of treatment. However, phosphorus amendment to prior limestone neutralisation failed to reduce toxicity more than limestone neutralisation alone. Low concentrations of both phosphorus and nitrogen appear to limit phytoplankton population growth in all treatments.« less
Collapse of caves at shallow depth in Gaziantep city center, Turkey: a case study
NASA Astrophysics Data System (ADS)
Canakci, Hanifi
2007-12-01
This paper focuses on an investigation of the possible causes for the collapse of limestone caves in Gaziantep, Turkey. The city contains a lot of man-made caves, at a shallow depth, of various width and length. These caves were mainly excavated to provide work or storage space. As the city has been growing fast with increased population, many structures were constructed over these caves. Recently, two caves collapsed and five houses were damaged. These caves are all made of limestone and it was observed after the collapse that the limestone was saturated with water due to sewer pipe leakage and surface water. Tests were carried out on the limestone and it was determined that the compressive strength of limestone decreases by about 50% and the tensile strength decreased by about 80% when saturated with water. It was concluded that the reduced strength of the limestone combined with additional loads due to the factors mentioned above seem to be the main reason for these collapses.
Stratigraphy of the Sarkisla area, Sivas basin, eastern central Anatolia
DOE Office of Scientific and Technical Information (OSTI.GOV)
Bilgic, T.; Sumengen, M.; Terlemez, I.
1988-08-01
The stratigraphy of the Sarkisla area, southeastern Central Anatolian Massif, is characterized by a succession of rock units ranging from late Paleocene to Pliocene in age. The Caldag group mostly consists of deep-water units and forms the base of the Tertiary rocks. However, its relation to the basement rocks is not observed in the area. This group is represented by late Paleocene-Lutetian-age turbiditic pyroclastics and limestones, andesitic lavas and pyroclastics topped with reefal limestones, and turbiditic limestones and pyroclastics alternating with limestone blocks. During Lutetian to early Priabonian time, shallow marine clastics were deposited along the southern margin of themore » basin, while continental clastics and platform limestones accumulated along the northern margin. Late Priabonian to early Oligocene time is represented by gypsiferous deposits followed by late Oligocene-age fluvial clastics. The gypsiferous deposits conformably overlie the shallow marine formations but rest on the Caldag group unconformably. During early to middle Miocene time, alternating lacustrine limestones, gypsum, and basalts formed on the fluvial clastics; to the north, basalts formed on the platform limestones. The uppermost sequence of the basin, composed of Tortonian-early Pliocene-age fluvial clastics, lacustrine limestones, and fan deposits, unconformably overlies the older formations. The stratigraphy of the study area is similar to the Ulukisla basin, southwestern Central Anatolian Massif. Therefore, this basin can be considered to be the prolongation of the Ulukisla basin offset by the Ecemis fault.« less
Eang, Khy Eam; Igarashi, Toshifumi; Fujinaga, Ryota; Kondo, Megumi; Tabelin, Carlito Baltazar
2018-03-06
Groundwater flow and its geochemical evolution in mines are important not only in the study of contaminant migration but also in the effective planning of excavation. The effects of groundwater on the stability of rock slopes and other mine constructions especially in limestone quarries are crucial because calcite, the major mineral component of limestone, is moderately soluble in water. In this study, evolution of groundwater in a limestone quarry located in Chichibu city was monitored to understand the geochemical processes occurring within the rock strata of the quarry and changes in the chemistry of groundwater, which suggests zones of deformations that may affect the stability of rock slopes. There are three distinct geological formations in the quarry: limestone layer, interbedded layer of limestone and slaty greenstone, and slaty greenstone layer as basement rock. Although the hydrochemical facies of all groundwater samples were Ca-HCO 3 type water, changes in the geochemical properties of groundwater from the three geological formations were observed. In particular, significant changes in the chemical properties of several groundwater samples along the interbedded layer were observed, which could be attributed to the mixing of groundwater from the limestone and slaty greenstone layers. On the rainy day, the concentrations of Ca 2+ and HCO 3 - in the groundwater fluctuated notably, and the groundwater flowing along the interbedded layer was dominated by groundwater from the limestone layer. These suggest that groundwater along the interbedded layer may affect the stability of rock slopes.
Stratigraphy and sedimentology of the Upper Cretaceous (Campanian) Anacacho Limestone, Texas, USA
Swezey, C.S.; Sullivan, E.C.
2004-01-01
The Upper Cretaceous Anacacho Limestone is exposed in outcrops between the cities of San Antonio and Del Rio, Texas. A detailed study of four outcrops (Blanco Creek section, Sabinal River section, Seco Creek section, Hondo Creek section) shows that the Anacacho Limestone rests on the Upson Clay (which contains fauna of early Campanian age) and is overlain by the Corsicana Marl (which contains fauna of early Maastrichtian age). An unconformity within the Anacacho Limestone is used herein to separate the limestone into a lower member and an upper member. The lower Anacacho member contains fauna of early Campanian age, whereas the upper Anacacho member contains fauna of middle Campanian age. The lower Anacacho member consists predominantly of wackestones to packstones, which are overlain by packstones to grainstones capped by the unconformity. This unconformity is interpreted as a marine flooding surface, delineating a transition from carbonate grainstones deposited in shallow water (<30 m depth) to a chalk deposited in deeper water. Above the unconformity, the upper Anacacho member is characterized by a chalk, overlain by wackestones and packstones. The uppermost section of the Anacacho Limestone consists of packstones and grainstones with abundant and diverse fossils. Most of the Anacacho Limestone developed in relatively shallow water (<50 m depth) leeward of a large carbonate build-up (possibly a rudistid reef) that now comprises the Anacacho Mountains. The environment, however, was open to marine water throughout deposition of the Anacacho Limestone. ?? 2004 Elsevier Ltd. All rights reserved.
DOE Office of Scientific and Technical Information (OSTI.GOV)
Richmann, D.L.; Luke, K.W.; Terry, J.C.
1984-07-01
The results of a study to determine the relative grindability of US limestones and to relate grindability to petrographic properties are presented in this report. A laboratory ball mill test was developed to provide a quick and simple measure of grindability. These values were then used to explore possible correlations between grindability and the chemical and physical properties of the limestones. Chemical analyses and thin section petrographic analyses were used to characterize the limestone samples. The results of the laboratory ball mill test were compared to the results of an industrial grinding test, the Bond Work Index, for six samplesmore » which covered the grindability range. The two tests compared well with a correlation coefficient greater than 0.9. While the laboratory test is not sufficient to provide ball mill design specifications, it can be used as a screening and quality control test. The grinding results, expressed as a grindability index, ranged in values from 2 to 15. This represents a seven-fold range in the relative difficulties to grind for the limestones tested. From the petrographic analysis results, a strong correlation was found between the grindability and the fraction of macrocrystalline (> 5 ..mu..m) carbonate minerals present in the limestone. However, based on the high degree of variability characteristic of most limestone deposits, petrographic information should, in general, only be used to qualitatively predict the grindability of a specific limestone. An actual grinding test is recommended for a quantitative evaluation.« less
DOSAGE DES ELEMENTS EN TRACE DES CALCAIRES AU SERVICE DE L'ARCHEOLOGIE
DOE Office of Scientific and Technical Information (OSTI.GOV)
BLANC,A.; HOLMES,L.; HARBOTTLE,G.
1998-05-01
Numerous quarries in the Lutetian limestone formations of the Paris Basin provided stone for the building and the decoration of monuments from antiquity to the present. To determine the origin of stone used for masonry and sculptures in these monuments, a team of geologists and archaeologists has investigated 300 quarries and collected 2,300 samples. Petrographic and paleontologic examination of thin sections allows geologists to distinguish Lutetian limestones from Jurassic and Cretaceous limestones. Geologists also seek to formulate hypotheses regarding the origin of Lutetian limestones used for building and sculpture in the Paris region. In the search for the sources ofmore » building and sculptural stone, the analytical methods of geologists are limited because often several quarries produce the same lithofacies. A new tool is now available, however, to attack questions of provenance raised by art historians. Because limestones from different sources have distinctive patterns of trace-element concentrations, compositional analysis by neutron activation allows them to compare building or sculptural stone from one monument with stone from quarries or other monuments. This analytical method subjects a powdered limestone sample to standard neutron activation analysis procedures at Brookhaven National Laboratory. With the help of computer programs, the compositional fingerprints of Lutetian limestones can be determined and stored in a database. The limestone database contains data for approximately 2,100 samples from monuments, sculptures and quarries. It is particularly rich in samples from the Paris Basin.« less
Harwood, Valerie J.; Levine, Audrey D.; Scott, Troy M.; Chivukula, Vasanta; Lukasik, Jerzy; Farrah, Samuel R.; Rose, Joan B.
2005-01-01
The validity of using indicator organisms (total and fecal coliforms, enterococci, Clostridium perfringens, and F-specific coliphages) to predict the presence or absence of pathogens (infectious enteric viruses, Cryptosporidium, and Giardia) was tested at six wastewater reclamation facilities. Multiple samplings conducted at each facility over a 1-year period. Larger sample volumes for indicators (0.2 to 0.4 liters) and pathogens (30 to 100 liters) resulted in more sensitive detection limits than are typical of routine monitoring. Microorganisms were detected in disinfected effluent samples at the following frequencies: total coliforms, 63%; fecal coliforms, 27%; enterococci, 27%; C. perfringens, 61%; F-specific coliphages, ∼40%; and enteric viruses, 31%. Cryptosporidium oocysts and Giardia cysts were detected in 70% and 80%, respectively, of reclaimed water samples. Viable Cryptosporidium, based on cell culture infectivity assays, was detected in 20% of the reclaimed water samples. No strong correlation was found for any indicator-pathogen combination. When data for all indicators were tested using discriminant analysis, the presence/absence patterns for Giardia cysts, Cryptosporidium oocysts, infectious Cryptosporidium, and infectious enteric viruses were predicted for over 71% of disinfected effluents. The failure of measurements of single indicator organism to correlate with pathogens suggests that public health is not adequately protected by simple monitoring schemes based on detection of a single indicator, particularly at the detection limits routinely employed. Monitoring a suite of indicator organisms in reclaimed effluent is more likely to be predictive of the presence of certain pathogens, and a need for additional pathogen monitoring in reclaimed water in order to protect public health is suggested by this study. PMID:15933017
NASA Astrophysics Data System (ADS)
Sun, Lei; Khan, Shuhab D.; Sarmiento, Sergio; Lakshmikantha, M. R.; Zhou, Huawei
2017-12-01
Petroleum geoscientists have been using cores and well logs to study source rocks and reservoirs, however, the inherent discontinuous nature of these data cannot account for horizontal heterogeneities. Modern exploitation requires better understanding of important source rocks and reservoirs at outcrop scale. Remote sensing of outcrops is becoming a first order tool for reservoir analog studies including horizontal heterogeneities. This work used ground-based hyperspectral imaging, terrestrial laser scanning (TLS), and high-resolution photography to study a roadcut of the Boone Formation at Bella Vista, northwest Arkansas, and developed an outcrop model for reservoir analog analyses. The petroliferous Boone Formation consists of fossiliferous limestones interbedded with chert of early Mississippian age. We used remote sensing techniques to identify rock types and to collect 3D geometrical data. Mixture tuned matched filtering classification of hyperspectral data show that the outcrop is mostly limestones with interbedded chert nodules. 1315 fractures were classified according to their strata-bounding relationships, among these, larger fractures are dominantly striking in ENE - WSW directions. Fracture extraction data show that chert holds more fractures than limestones, and both vertical and horizontal heterogeneities exist in chert nodule distribution. Utilizing ground-based remote sensing, we have assembled a virtual outcrop model to extract mineral composition as well as fracture data from the model. We inferred anisotropy in vertical fracture permeability based on the dominancy of fracture orientations, the preferential distribution of fractures and distribution of chert nodules. These data are beneficial in reservoir analogs to study rock mechanics and fluid flow, and to improve well performances.
SOXAL{trademark} pilot plant demonstration at Niagara Mohawk`s Dunkirk Station
DOE Office of Scientific and Technical Information (OSTI.GOV)
Strangway, P.K.
The Clean Air Act Amendments of 1990 made it necessary to accelerate the development of scrubber systems for use by some utilities burning sulfur-containing fuels, primarily coal. While many types of Flue Gas Desulfurization (FGD) systems operate based on lime and limestone scrubbing, these systems have drawbacks when considered for incorporation into long-term emissions control plans. Although the costs associated with disposal of large amounts of scrubber sludge may be manageable today, the trend is toward increased disposal costs. Many new SO{sub 2} control technologies are being pursued in the hope of developing an economical regenerable FGD system did recoversmore » the SO{sub 2} as a saleable commercial product, thus minimizing the formation of disposal waste. Some new technologies include the use of exotic chemical absorbents which are alien to the utility industry and utilities` waste treatment facilities. These systems present utilities with new environmental issues. The SOXAL{trademark} process has been developed so as to eliminate such issues.« less
Carter, J.M.
1999-01-01
This report presents selected data on wells and test holes that were used in the construction of structure-contour maps of selected formations that contain major aquifers in the Black Hills area of western South Dakota. Altitudes of the top of the Inyan Kara Group, Minnekahta Limestone, Minnelusa Formation, Madison Limestone, and Deadwood Formation are presented for the wells and test holes presented in this report.
Limestone - A Crucial and Versatile Industrial Mineral Commodity
Bliss, James D.; Hayes, Timothy S.; Orris, Greta J.
2008-01-01
Limestone, as used by the minerals industry, is any rock composed mostly of calcium carbonate (CaCO3). Although limestone is common in many parts of the United States, it is critically absent from some. Limestone is used to produce Portland cement, as aggregate in concrete and asphalt, and in an enormous array of other products, making it a truly versatile commodity. Portland cement is essential to the building industry, but despite our Nation's abundance of limestone, there have been cement shortages in recent years. These have been caused in part by a need to find new areas suitable for quarrying operations. To help manage our Nation's resources of such essential mineral commodities, the U.S. Geological Survey (USGS) provides crucial data and scientific information to industry, policymakers, and the public.
Influence of limestone characteristics on mercury re-emission in WFGD systems.
Ochoa-González, Raquel; Díaz-Somoano, Mercedes; Martínez-Tarazona, M Rosa
2013-03-19
This work evaluates the influence of the effect of the properties of limestones on their reactivity and the re-emission of mercury under typical wet scrubber conditions. The influence of the composition, particle size, and porosity of limestones on their reactivity and the effect of sorbent concentration, pH, redox potential, and the sulphite and iron content of the slurry on Hg(0) re-emission was assessed. A small particle size, a high porosity and a low magnesium content increased the high reactivity of the limestones. Moreover, it was found that the higher the reactivity of the sample the greater the amount of mercury captured in the scrubber. Although sulphite ions did not cause the re-emission of mercury from the suspensions of the gypsums, the limestones enriched in iron increased Hg(0) re-emission under low oxygen conditions. It was observed that the low pH values of the gypsum suspensions favored the cocapture of mercury because Fe(2+) formation was avoided. The partitioning of the mercury in the byproducts of the scrubber depended on the impurities of the limestones rather than on their particle size. No leaching of mercury from the gypsum samples occurred suggesting that mercury was either tightly bound to the impurities of the limestone or was transformed into insoluble mercury species.
NASA Astrophysics Data System (ADS)
Aalil, Issam; Chaaba, Ali; Cherkaoui, Khalid; Brunetaud, Xavier; Beck, Kevin; Al-Mukhtar, Muzahim
2015-04-01
Volubilis is the most excavated and the best preserved archaeological site of Morocco. Located about thirty kilometres north of Meknes, it was a Mauritanian capital founded in the 3rd century B.C., and became an important outpost of the Roman Empire. Volubilis monuments are constructed with five regional lithotypes of limestone. A grey massive limestone and beige-yellowish calcarenite limestone are the two most largely used on Volubilis site, representing respectively about 30% and 60 % of the total volume of building stones. Field observations showed that the calcarenite limestone is more decayed than the massive limestone and is mainly affected by scaling, alveolization and sanding. This work aims to estimate the role of environmental conditions on the decay of the calcarenite stone through the effect of thermal stresses and freezing-thawing action. Air temperature data of Meknes station is analysed. Furthermore, mineralogical composition of the calcarenite limestone and its intrinsic properties required for stress calculation are determined. The results of this study show that the calcarenite limestone is a quite soft carbonate stone, contains about 71 % of calcite, 18 % of quartz and others accessory minerals. Besides, there is no risk of damage due to freezing-thawing processes. Nonetheless, thermal stresses may have an important role in the decay of calcarenite stones of the Volubilis site.
Uranium in the Mayoworth area, Johnson County, Wyoming - a preliminary report
Love, J.D.
1954-01-01
The uranium mineral, metatyuyamunite, occurs in the basal limestone of the Sundance formation of late Jurassic age along the east flank of the Bighorn Mountains, about 2 miles southwest of the abandoned Mayoworth post office. This occurrence is of particular interest because it is the first uranium mineralization reported from a marine limestone in Wyoming. The discovery uranium claims were filed in July 1953, by J.S. Masek, Dan Oglesby, and Jack Emery of Casper, Wyo. Subsequent reconnaissance investigations have been made by private individuals and geologists of the U.S. Geological Survey and Atomic Energy Commission. The metatyuyamunite is concentrated in a hard gray oolitic limestone that forms the basal bed of the Sundance formation. A selected sample of limestone from a fresh face in the northernmost deposit known at the time of the field examination contained 0.70 percent equivalent uranium and 0.71 percent uranium. Eight samples of the limestone taken at the sample place by the Atomic Energy Commission contained from 0.007 to 0.22 percent uranium. A chip sample from the weathered outcrop at the top of this limestone half a mile to the southeast contained 0.17 percent equivalent uranium and 0.030 percent uranium. A dinosaur bone from the middle part of the Morrison formation contained 0.044 percent equivalent uranium and 0.004 percent uranium. metatyuyamunite forms a conspicuous yellow coating along fracture planes cutting the oolitic limestone and has also replaced many of the oolites within the solid limestone and has also replaced many of the oolites within the solid limestone even where fractures are not present. Many radioactive spots in the basal limestone of the Sundance formation were examined in a reconnaissance fashion along the outcrop for a distance of half a mile south of the initial discovery. Samples were taken for analysis only at the northern and southern margins of this interval. Outcrops farther north and south were not studied. There are not sufficient data to make even rough estimates of tonnage and grade of the occurrences. The extent of the limestone, the approximate boundaries of the area of above-normal radioactivity, and the possibilities of other radioactive zones have not been thoroughly investigated. Although dinosaur bones in the Morrison formation were radioactive wherever they were tested, no significant amount of radioactivity was observed in rocks adjacent to the bones.
Comparative study of porous limestones used in heritage structures in Cyprus and in Hungary
NASA Astrophysics Data System (ADS)
Theodoridou, Magdalini; Ioannou, Ioannis; Rozgonyi-Boissinot, Nikoletta; Török, Ákos
2015-04-01
Porous limestone is widely used as construction material in the monuments of Cyprus and Hungary. The present study compares the physical properties of a bioclastic limestone from Cyprus and an oolitic limestone from Hungary. Petra Gerolakkou is a Pliocene limestone from Cyprus that originates from the district of Nicosia, the island's capital. It has been extensively used throughout the years in construction and restoration projects, particularly in the Nicosia area. Distinctive examples of its use can be found in the majority of the most important historic monuments in Nicosia, such as the Venetian walls and fortifications, churches (e.g. the Agia Sofia Cathedral), the archbishop and presidential palaces and a high number of other traditional buildings. The studied Miocene limestone from Hungary was exploited from Sóskút quarry (15-20 km W-SW to Budapest). The quarry provided stone for emblematic monuments of the capital of Hungary such as the Parliament building, Mathias Church, the Opera House and Citadella. In this study, mechanical parameters for both aforementioned stones, such as uniaxial compressive and tensile strengths, were tested under laboratory conditions. Their density, porosity and water absorption were also compared. The studied limestone from Cyprus exhibits porosity values within the range of 48-51%, apparent density between 1340 and 1400 kg/m3 and strength values under uniaxial compressive load between 1.2 and 2.8 MPa. This lithotype is also considered susceptible to salt decay, since an approximate mass loss of 12.5% is noted after 15 salt crystallization artificial weathering cycles. The porosity of the Hungarian limestone is in the order of 16-35%, the bulk density is 1600-1950 kg/m3, while the compressive strength is 2.5-15 MPa. Durability tests indicate that even after 10 freeze-thaw cycles the loss in strength is dramatic. Test results indicate that use of porous limestone in both countries is common and fabric strongly controls the properties of limestone. The climatic conditions and trigger mechanisms of limestone decay are different in the two countries; therefore durability tests have different focus areas: salt-related decay is most common in Cyprus, while freeze-thaw action causes the major damage in Hungary. The proper selection of lithologies for different structural elements has to consider both fabric differences and potential mechanisms of decay.
Nomination of the Globigerina Limestone of the Maltese Islands as a "Global Heritage Stone Resource"
NASA Astrophysics Data System (ADS)
Cassar, JoAnn
2016-04-01
The Maltese Islands consist of two main islands, Malta and Gozo, as well as a small number of islets, and lie in the central Mediterranean Sea approximately 90 km south of Sicily. Although only 316 square kilometres in size, the Islands contain a rich concentration of archaeological sites and historic buildings, as well as vernacular architecture and modern buildings, for the most part built of the local Globigerina Limestone, which is one of the few natural resources of the Islands. This stone can be described as a typical "soft limestone", very easy to carve and shape. It forms part of the large family of Oligo-Miocene "soft limestones" widely diffused in the Mediterranean Basin. The Maltese Globigerina Limestone Formation is one of five main Formations, and varies in thickness from 20 to over 200 m. The material used for building is located stratigraphically in the lower part of the Globigerina Limestone Formation, called the Lower Globigerina Limestone. This Formation is stratified into thick beds at outcrop. Sections where bioturbation is concentrated often also occur. This limestone is fine-grained, yellow to pale grey in colour, almost wholly composed of the tests of globigerinid planktonic foraminifera. Petrographically, Globigerina Limestone can be described as a bioclastic packstone, with bioclastic wackestones also occurring. This limestone has always been used as the predominant building material in the Islands. The Maltese prehistoric Temples, which were constructed approximately 6000 years ago, bear testimony to this. Between 1530 and 1798 the Order of the Knights of St John built kilometres of fortifications in this same material to protect the Island from the expanding Ottoman Empire. Fortifications, impressive churches, auberges and palaces were built of this stone during this period. The capital city of Valletta, a rich and dense manifestation of Baroque architecture in Globigerina Limestone, is included on the UNESCO World Heritage List, as are the prehistoric Temples. Even today, this local building stone is still much in demand, with many modern buildings still being constructed in this material; it is also widely used for the repair and restoration of historic buildings and many local quarries are still active, with this stone even today being a keystone of the local economy. This stone is thus being nominated as a suitable "Global Heritage Stone Resource".
Khaska, Mahmoud; Le Gal La Salle, Corinne; Verdoux, Patrick; Boutin, René
2015-01-01
Arsenic contamination of stream waters and groundwater is a real issue in Au-As mine environments. At the Salsigne Au-As mine, southern France, arsenic contamination persists after closure and remediation of the site. In this study, natural and anthropogenic arsenic inputs in surface water and groundwater are identified based on (87)Sr/(86)Sr, and δ(18)O and δ(2)H isotopic composition of water. In the wet season, downstream of the remediated zone, the arsenic contents in stream water and alluvial aquifer groundwater are high, with values in the order of 36 μg/L and 40 μg/L respectively, while upstream natural background average concentrations are around 4 μg/L. Locally down-gradient of the reclaimed area, arsenic concentrations in stream water showed 2 peaks, one during an important rainy event (101 mm) in the wet season in May, and a longer one over the dry period, reaching 120 and 110 μg/L respectively. The temporal variations in arsenic content in stream water can be explained i) during the dry season, by release of arsenic stored in the alluvial sediments through increased contribution from base flow and decreased stream flow and ii) during major rainy events, by mobilization of arsenic associated with important surface runoff. The (87)Sr/(86)Sr ratios associated with increasing arsenic content in stream waters downstream of the reclaimed area are significantly lower than that of the natural Sr inherited from Variscan formations. These low (87)Sr/(86)Sr ratios are likely to be associated with the decontaminating water treatment processes, used in the past and still at present, where CaO, produced from marine limestone and therefore showing a low (87)Sr/(86)Sr ratios, is used to precipitate Ca3(AsO4)2. The low Sr isotope signatures will then impact on the Sr isotope ratio of (1) the Ca-arsenate stored in tailing dams, (2) effluent currently produced by water treatment process and (3) groundwater draining from the overall site. Furthermore, Δ(2)H shows that the low (87)Sr/(86)Sr ratio, arsenic rich water is characterized by an evaporated signature suggesting a potential influence of water impacted by evaporation during storage in decantation lagoons. This study shows the suitability of Sr and stable isotopes of water as tracers to differentiate natural and anthropogenic sources of arsenic release or other trace elements from mining context where CaO is used for water treatment. Copyright © 2015 Elsevier B.V. All rights reserved.
NASA Astrophysics Data System (ADS)
Khaska, Mahmoud; Le Gal La Salle, Corinne; Verdoux, Patrick; Boutin, René
2015-06-01
Arsenic contamination of stream waters and groundwater is a real issue in Au-As mine environments. At the Salsigne Au-As mine, southern France, arsenic contamination persists after closure and remediation of the site. In this study, natural and anthropogenic arsenic inputs in surface water and groundwater are identified based on 87Sr/86Sr, and δ18O and δ2H isotopic composition of water. In the wet season, downstream of the remediated zone, the arsenic contents in stream water and alluvial aquifer groundwater are high, with values in the order of 36 μg/L and 40 μg/L respectively, while upstream natural background average concentrations are around 4 μg/L. Locally down-gradient of the reclaimed area, arsenic concentrations in stream water showed 2 peaks, one during an important rainy event (101 mm) in the wet season in May, and a longer one over the dry period, reaching 120 and 110 μg/L respectively. The temporal variations in arsenic content in stream water can be explained i) during the dry season, by release of arsenic stored in the alluvial sediments through increased contribution from base flow and decreased stream flow and ii) during major rainy events, by mobilization of arsenic associated with important surface runoff. The 87Sr/86Sr ratios associated with increasing arsenic content in stream waters downstream of the reclaimed area are significantly lower than that of the natural Sr inherited from Variscan formations. These low 87Sr/86Sr ratios are likely to be associated with the decontaminating water treatment processes, used in the past and still at present, where CaO, produced from marine limestone and therefore showing a low 87Sr/86Sr ratios, is used to precipitate Ca3(AsO4)2. The low Sr isotope signatures will then impact on the Sr isotope ratio of (1) the Ca-arsenate stored in tailing dams, (2) effluent currently produced by water treatment process and (3) groundwater draining from the overall site. Furthermore, Δ2H shows that the low 87Sr/86Sr ratio, arsenic rich water is characterized by an evaporated signature suggesting a potential influence of water impacted by evaporation during storage in decantation lagoons. This study shows the suitability of Sr and stable isotopes of water as tracers to differentiate natural and anthropogenic sources of arsenic release or other trace elements from mining context where CaO is used for water treatment.
R .C. Musselman; F. W. Smith; W. D. Shepperd; L. A. Asherin; B. W. Gee
2009-01-01
A study was initiated to determine the effectiveness of landscape fabric and supplemental irrigation in survival and growth of woody perennials planted on reclaimed surface coal mine lands. The study compared growth and survival of nursery grown potted aspen and serviceberry planted with or without landscape fabric, and with or without biweekly supplemental irrigation...
Water Reuse and Wastewater Recycling at U.S. Army Installations: Policy Implications
2011-06-01
Definition Blackwater Water captured from toilets and urinals along with kitchen waste. Direct potable reuse The introduction of highly treated reclaimed...reused. It does not include water from kitchen sinks or dishwashers. Indirect potable reuse The planned incorporation of reclaimed water into a raw...industrial cooling. * Some organizations do accept a definition of “graywater” that does include kitchen and dishwasher waste- water along with wastewater
Josh Brinks; John Lhotka; Chris. Barton
2011-01-01
The establishment of intensively managed woody energy crops on reclaimed surface mine lands provides an opportunity to diversify domestic biomass sources, while increasing the productivity and economic value of underutilized land. Our objective is to test the effect of fertilization on the growth and biomass accumulation of American sycamore (Platanus...
NASA Astrophysics Data System (ADS)
Joniec, Jolanta; Frąc, Magdalena
2017-10-01
The aim of the study was to evaluate microbial functional diversity based on community level physiological profiling and β-glucosidase activity changes in soil degraded by sulphur mining and subjected to reclamation with various waste. The experiment was set up in the area of the former `Jeziórko' Sulphur Mine (Poland), on a soilless substrate with a particle size distribution of slightly loamy sand. The experimental variants included the application of post-flotation lime, sewage sludge and mineral wool. The analyses of soil samples included the assessment of the following microbiological indices: β-glucosidase activity and functional diversity average well color development and richness). The results indicate that sewage sludge did not exert a significant impact on the functional diversity of microorganisms present in the reclaimed soil. In turn, the application of other types of waste contributed to a significant increase in the parameters of total metabolic activity and functional diversity of the reclaimed soil. However, the temporal analysis of the metabolic profile of soil microorganisms demonstrated that a single application of waste did not yield a durable, stable metabolic profile in the reclaimed soil. Still, there was an increase in β-glucosidase activity, especially in objects treated with sewage sludge.
Kinney, C.A.; Furlong, E.T.; Werner, S.L.; Cahill, J.D.
2006-01-01
Three sites in the Front Range of Colorado, USA, were monitored from May through September 2003 to assess the presence and distribution of pharmaceuticals in soil irrigated with reclaimed water derived from urban wastewater. Soil cores were collected monthly, and 19 pharmaceuticals, all of which were detected during the present study, were measured in 5-cm increments of the 30-cm cores. Samples of reclaimed water were analyzed three times during the study to assess the input of pharmaceuticals. Samples collected before the onset of irrigation in 2003 contained numerous pharmaceuticals, likely resulting from the previous year's irrigation. Several of the selected pharmaceuticals increased in total soil concentration at one or more of the sites. The four most commonly detected pharmaceuticals were erythromycin, carbamazepine, fluoxetine, and diphenhydramine. Typical concentrations of the individual pharmaceuticals observed were low (0.02-15 ??g/kg dry soil). The existence of subsurface maximum concentrations and detectable concentrations at the lowest sampled soil depth might indicate interactions of soil components with pharmaceuticals during leaching through the vadose zone. Nevertheless, the present study demonstrates that reclaimed-water irrigation results in soil pharmaceutical concentrations that vary through the irrigation season and that some compounds persist for months after irrigation. ?? 2006 SETAC.
Microbiological Impact of the Use of Reclaimed Wastewater in Recreational Parks
Palacios, Oskar A.; Zavala-Díaz de la Serna, Francisco J.; Ballinas-Casarrubias, María de Lourdes; Espino-Valdés, María S.
2017-01-01
Reclaimed wastewater for irrigation is an opportunity for recovery of this natural resource. In this study, microbial risk from the use of treated wastewater for irrigation of recreational parks in the city of Chihuahua, evaluating the effect of distribution distance, season, and presence of storage tanks, was analyzed. Escherichia coli, Salmonella, and multidrug-resistant bacteria were recovered from samples of reclaimed water and soils at recreational parks in Chihuahua by the membrane filtration method, using selected agars for microbial growth. Samples were taken at three different seasons. No correlation in the presence of microbial indicators and multidrug-resistant bacteria (p > 0.05) was found between the distance from the wastewater treatment plant to the point of use. Presence of storage tanks in parks showed a significant effect (p < 0.05) with a higher level of E. coli. The highest count in wastewater occurred in summer. We isolated 392 multidrug-resistant bacteria from water and soil; cluster analysis showed that the microorganisms at each location were of different origins. Irrigation with reclaimed wastewater did not have a negative effect on the presence of microbial indicators of the quality of soils in the parks. However, the prevalence of multidrug-resistant bacteria still represents a potential risk factor for human health. PMID:28869549
Endotoxins: The Critical Risk Factor in Reclaimed Water via Inhalation Exposure.
Xue, Jinling; Zhang, Jinshan; Xu, Bi; Xie, Jiani; Wu, Wenzhao; Lu, Yun
2016-11-01
The use of reclaimed water for nonpotable uses requires consideration of potential adverse health effects. Considering that inhalation can be a significant route of transmission of microorganisms and inflammatory agents, this study used a mouse model to test the possible adverse effects of reclaimed water use during car washing where aerosols are generated. Intensive innate immune responses were found in the lungs after acute exposure, and the lavage polymorphonuclear cell proportion was the most sensitive end point. Four types of evidence are presented to demonstrate that the main risk factor that initiates innate inflammation is the free endotoxin. (1) Small molecules (<10 kDa) cannot induce inflammation. (2) The endotoxin levels of 11 water samples from five different plants showed positive correlations with inflammatory responses. (3) Actual water samples showed similar activities with free endotoxins other than bacterially bound endotoxins. (4) Specific removal of endotoxins with polymyxin B affinity chromatography further confirmed the role of free endotoxins. It is noteworthy that 62.9% of the investigated tertiary-treated water had endotoxin levels higher than the allowable acute threshold (120 endotoxin units/mL) under the hypothesized car wash condition, which strongly suggests the need to carefully consider the water treatment steps required to produce safe water for various reclaimed water end uses.
Effective use of fly ash slurry as fill material.
Horiuchi, S; Kawaguchi, M; Yasuhara, K
2000-09-15
A lot of effort has been put into increasing coal ash utilization; however, 50% of total amount is disposed of on land and in the sea. Several attempts have been reported recently concerning slurried coal fly ash use for civil engineering materials, such as for structural fill and backfill. The authors have studied this issue for more than 15 years and reported its potential for (1) underwater fills, (2) light weight backfills, and (3) light weight structural fills, through both laboratory tests and construction works. This paper is an overview of the results obtained for slurry, focusing on the following. (1) Coal fly ash reclaimed by slurry placement shows lower compressibility, higher ground density, and higher strength than by the other methods. This higher strength increases stability against liquefaction during earthquake. (2) Higher stability of the fly ash ground formed by slurry placement is caused by higher density and its self-hardening property. (3) Stability of fly ash reclaimed ground can be increased by increasing density and also by strength enhancement by cement addition. (4) Technical data obtained through a man-made island construction project shows the advantages of fly ash slurry in terms of mechanical properties such as higher stability against sliding failure, sufficient ground strength, and also in terms of cost saving. (5) Concentration in leachates from the placed slurry is lower than the Japanese environmental law. (6) In order to enlarge the fly ash slurry application toward a lightweight fill, mixtures of air foam, cement and fly ash were examined. Test results shows sufficient durability of this material against creep failure. This material was then used as lightweight structural fill around a high-rise building, and showed sufficient quality. From the above data, it can be concluded that coal fly ash slurry can be effectively utilized in civil engineering projects.
NASA Astrophysics Data System (ADS)
Kochman, Alicja; Matyszkiewicz, Jacek
2013-12-01
Kochman, A. and Matyszkiewicz, J. 2013. Experimental method for estimation of compaction in the Oxfordian bedded limestones of the southern Krakow-Częstochowa Upland, Southern Poland. Acta Geologica Polonica, 63
Effective stress law for the permeability and deformation of four porous limestones
NASA Astrophysics Data System (ADS)
Wang, Y.; Meng, F.; Wang, X.; Baud, P.; Wong, T. F.
2017-12-01
The effective stress behavior of a rock is related to the geometric of its pore space. In a microscopically homogeneous assemblage, effective stress coefficients for permeability, volumetric strain and porosity change are predicted to be equal to or less than unity. Experimental measurements are in basic agreement with this prediction, with exceptions particularly in clay-rich sandstones, for which effective stress coefficient for permeability up to 7 was documented. Little is known about carbonates, but Ghabezloo et al. [2009] studied the permeability of an oolitic limestone (from Nimes, France) with 17% porosity and reported effective stress coefficients up to 2.4. We investigated this phenomenon in Indiana, Leitha, Purbeck, and Thala limestones with porosities of 13-30%. Measurements were made at room temperature on water-saturated samples at confining and pore pressures of 7-15 MPa and 1-3 MPa, respectively. Unlike previous studies limited to the permeability, we also determined the effective stress coefficients for volumetric strain and porosity change. Indiana limestone is oolitic, and not surprisingly its behaviour was similar to Nimes limestone, with an effective stress coefficient for permeability of 2.5. Our Indiana limestone data showed that whereas the effective stress coefficient for volumetric strain was <1, that for porosity change was >1. Measurements on Purbeck and Thala limestones are consistent with these inequalities, with effective stress coefficients for permeability and porosity change >1 and that for volumetric strain <1. Even though Purbeck and Thala limestones are micritic with appreciable amount of quartz and dolomite, microstructural and mercury porosimetry data showed that their pore spaces are similar to the oolitic limestones, in that the pore size distribution is bimodal with significant fractions of both macropores and micropores. Berryman [1992] analyzed theoretically a rock made up of two porous constituents. Our new data are in agreement with inequalities he derived for these effective stress coefficients. For comparison, we also studied Leitha limestone predominately made up of macropores. Our measurements showed that in this case all three effective stress coefficients were <1, as predicted for a microscopically homogeneous assemblage.
Drenov Grič black limestone as a heritage stone from Slovenia
NASA Astrophysics Data System (ADS)
Kramar, Sabina; Rožič, Boštjan; Žbona, Nina; Bedjanič, Mojca; Mladenović, Ana
2016-04-01
The limestone known as Drenov Grič black limestone is considered one of the most beautiful Slovenian natural stones due to its homogenous black colour interwoven with white veins. Over the centuries it has been exploited from three major quarries west of Ljubljana, with the main quarry at Drenov Grič playing the primary role in supplying building material for the central parts of Slovenia. All the quarries are currently not active. In the area of Drenov grič, one locality of black limestone is protected - Kuclerjev kamnolom quarry. It has the status of 'valuable natural feature of national importance' and is protected as a natural monument. This well-stratified micritic limestone of Triassic (Carnian) age occurs in 10-80 cm thick beds, with thin marl interlayers. The stone contains abundant fossil bivalves and ostracods. Apart from calcite as the main component, dolomite, quartz, illite/muscovite and pyrite are also present. The limestone is relatively rich in carbonaceous and bituminous organic matter, which is responsible for the black colour of the stone. This component does not have any adverse effect on mechanical and physical characteristics. As the lime¬stone is dense, thus facilitating a good polish, it has been commercially considered as marble. The stone has been widely used in Slovenian monuments, not only in Ljubljana but also in other regions of Slovenia. Many inner and outdoor architectural elements were made of this limestone, particularly in the baroque period, which was known for the extensive use of black limestones also in other European countries. The most significant use of this limestone has been recorded in sculptured portals and altars. Some of the important buildings decorated utilising this stone, are the Ljubljana Cathedral, the St. James's Parish Church, and the Franciscan Church of the Annunciation, all of which are located in Ljubljana, some of them having been declared as cultural monuments of local or national importance. When exposed to climatic influences, chromatic weathering and salt weathering are recognized as the main deterioration phenomena of this limestone on monuments.
NASA Astrophysics Data System (ADS)
Sellers, T.; Geissman, J. W.; Jackson, J.
2015-12-01
We are testing the hypothesis that depositional processes of the mid-Cretaceous Greenhorn Limestone were influenced by orbitally-driven climate variations using rock magnetic data. Correlation of the data, including anhysteretic remanent magnetization (ARM), magnetic susceptibility, isothermal remanent magnetization in different DC fields to saturation, and hysteresis properties, from three continuously exposed sections of the full Greenhorn Limestone provides detailed spatial distribution for the depositional processes and magnetic mineral climate encoding. The Greenhorn Limestone includes the Lincoln Limestone, Hartland Shale, and the Bridge Creek Limestone members and consists of calcareous shales and limestones representing near maximum depths in the Cretaceous interior seaway. The sections, each about 30 m thick, extend from the upper Graneros Shale, through the Greenhorn Formation, to the lower Carlisle Shale, with samples collected at a two to five cm interval and are located at Badito, CO; north of Redwing, CO; and at the Global boundary Stratotype Section and Point (GSSP) at Lake Pueblo, CO. Our over 1000 samples were hand crushed to granule size pieces and packed into 7cc IODP boxes. Bulk magnetic susceptibility, anhysteretic remanent magnetization (ARM) intensity at different peak AF levels, and isothermal remanent magnetization (IRM) intensity record variations in magnetic mineral concentration and are proxies to determine orbital scale cycles and precise stratigraphic correlation between sections. ARM intensities in a peak field of 100 mT at both sites range between 1.2 x 10-3 and 1.3 x 10-4 A/m and better define periodic variation within the Greenhorn Limestone displaying differences in ferromagnetic mineral content of detrital origin. Magnetic susceptibility, which ranges from 3.5 x 10-2 to 2.86 x 10-3, also shows periodic variation with a strong correlation among the three sections. Saturation IRM at 100 mT ranges from 3.2 x 10-1 to 1.1x 10-2 A/m shows periodic variation with the greatest variability in the Bridge Creek Member. Preliminary spectral analysis of each data set indicates a dominant cyclicity that is of considerably lower frequency than the limestone/shale couplets characteristic of Greenhorn Limestone.
Steam Cured Self-Consolidating Concrete and the Effects of Limestone Filler
NASA Astrophysics Data System (ADS)
Aqel, Mohammad A.
The purpose of this thesis is to determine the effect and the mechanisms associated with replacing 15% of the cement by limestone filler on the mechanical properties and durability performance of self-consolidating concrete designed and cured for precast/prestressed applications. This study investigates the role of limestone filler on the hydration kinetics, mechanical properties (12 hours to 300 days), microstructural and durability performance (rapid chloride permeability, linear shrinkage, sulfate resistance, freeze-thaw resistance and salt scaling resistance) of various self-consolidating concrete mix designs containing 5% silica fume and steam cured at a maximum holding temperature of 55°C. This research also examines the resistance to delayed ettringite formation when the concrete is steam cured at 70°C and 82°C and its secondary consequences on the freeze-thaw resistance. The effect of several experimental variables related to the concrete mix design and also the curing conditions are examined, namely: limestone filler fineness, limestone filler content, cement type, steam curing duration and steam curing temperature. In general, the results reveal that self-consolidating concrete containing 15% limestone filler, steam cured at 55°C, 70°C and 82°C, exhibited similar or superior mechanical and transport properties as well as long term durability performance compared to similar concrete without limestone filler. When the concrete is steam cured at 55°C, the chemical reactivity of limestone filler has an important role in enhancing the mechanical properties at 16 hours (compared to the concrete without limestone filler) and compensating for the dilution effect at 28 days. Although, at 300 days, the expansion of all concrete mixes are below 0.05%, the corresponding freeze-thaw durability factors vary widely and are controlled by the steam curing temperature and the chemical composition of the cement. Overall, the material properties indicate that the use of 15% limestone filler as cement replacement is a viable option for the precast/prestressed concrete applications, and in addition, would also have economic and environmental benefits.
DOE Office of Scientific and Technical Information (OSTI.GOV)
Sevelsted, Tine F.; Herfort, Duncan; Skibsted, Jørgen, E-mail: jskib@chem.au.dk
2013-10-15
{sup 13}C isotropic chemical shifts and chemical shift anisotropy parameters have been determined for a number of inorganic carbonates relevant in cement chemistry from slow-speed {sup 13}C MAS or {sup 13}C({sup 1}H) CP/MAS NMR spectra (9.4 T or 14.1 T) for {sup 13}C in natural abundance. The variation in the {sup 13}C chemical shift parameters is relatively small, raising some doubts that different carbonate species in Portland cement-based materials may not be sufficiently resolved in {sup 13}C MAS NMR spectra. However, it is shown that by combining {sup 13}C MAS and {sup 13}C({sup 1}H) CP/MAS NMR carbonate anions in anhydrousmore » and hydrated phases can be distinguished, thereby providing valuable information about the reactivity of limestone in cement blends. This is illustrated for three cement pastes prepared from an ordinary Portland cement, including 0, 16, and 25 wt.% limestone, and following the hydration for up to one year. For these blends {sup 29}Si MAS NMR reveals that the limestone filler accelerates the hydration for alite and also results in a smaller fraction of tetrahedrally coordinated Al incorporated in the C-S-H phase. The latter result is more clearly observed in {sup 27}Al MAS NMR spectra of the cement–limestone blends and suggests that dissolved aluminate species in the cement–limestone blends readily react with carbonate ions from the limestone filler, forming calcium monocarboaluminate hydrate. -- Highlights: •{sup 13}C chemical shift anisotropies for inorganic carbonates from {sup 13}C MAS NMR. •Narrow {sup 13}C NMR chemical shift range (163–171 ppm) for inorganic carbonates. •Anhydrous and hydrated carbonate species by {sup 13}C MAS and {sup 13}C({sup 1}H) CP/MAS NMR. •Limestone accelerates the hydration for alite in Portland – limestone cements. •Limestone reduces the amount of aluminium incorporated in the C-S-H phase.« less
NASA Astrophysics Data System (ADS)
Léonide, Philippe; Fournier, François; Reijmer, John J. G.; Vonhof, Hubert; Borgomano, Jean; Dijk, Jurrien; Rosenthal, Maelle; van Goethem, Manon; Cochard, Jean; Meulenaars, Karlien
2014-06-01
The Urgonian limestones of Late Barremian/Early Aptian from Provence (SE, France) are characterized by the occurrence of microporous limestones at regional scale alternating with tight carbonates. This study, based on petrographical (sediment texture, facies) and diagenetical analyses (cement stratigraphy, porosity and isotope geochemistry) of more than 800 limestone samples provides insight into the parameters controlling the genesis, preservation or occlusion of microporosity along an inner platform to outer shelf transect. The tight and microporous Urgonian limestones from Provence can be grouped into 5 rock-types based on textures, associated depositional environments, porosity and pore-type, being: (1) tight inner-platform: TIP; (2) porous inner platform: PIP; (3) tight outer platform: TOP; (4) porous outer platform: POP and (5) tight outer shelf: TOS. In tight (TIP, TOP and TOS types) limestones intergranular and intragranular pore spaces were entirely occluded by early marine and/or early meteoric cementation, whereas in microporous (PIP, POP) limestones a significant fraction of the intergranular macroporosity was preserved during early and shallow burial diagenesis. Micrite neomorphism (hybrid Ostwald ripening process) occurred during meteoric shallow burial diagenesis in PIP and POP limestones during the regional Durancian Uplift event (Albian-Lower Cenomanian). This process resulted in microporosity enhancement and preservation. Circulation of meteoric fluids during exhumation produces intercrystalline microporosity enhancement and moldic porosity development. The present study documents the important role that both early diagenetic and depositional cycles and long-term tectonic processes have on pore space evolution and distribution in Mesozoic platform carbonates.
2006-09-01
Richardson, in review). Figure 1 shows the lithostratigraphic setting for Eocene through Miocene strata, and the occurrence of hydrostratigraphic units of...basal Haw- thorn unit lies unconformably on lithologies informally called “ Eocene limestones,” which consist of Suwannee Limestone, Ocala Limestone
This report details a research project on Steam Enhanced Remediation (SER) for the recovery of volatile organic compounds from fractured limestone that was carried out at the Quarry at the former Loring Air Force Base in Limestone, Maine. This project was carried out by USEPA, Ma...
OPTIMIZATION OF A PULSED LIMESTONE BED REACTOR AT THE ARGO TUNNEL IN IDAHO SPRINGS, COLORADO
Acid Mine Drainage (AMD) is an unintended consequence of coal and metal mining that adversely affects thousands of miles of streams both in the eastern and western regions of the U.S. A novel AMD treatment process based on limestone based on limestone neutralization has been dev...
Method for producing H.sub.2 using a rotating drum reactor with a pulse jet heat source
Paulson, Leland E.
1990-01-01
A method of producing hydrogen by an endothermic steam-carbon reaction using a rotating drum reactor and a pulse jet combustor. The pulse jet combustor uses coal dust as a fuel to provide reaction temperatures of 1300.degree. to 1400.degree. F. Low-rank coal, water, limestone and catalyst are fed into the drum reactor where they are heated, tumbled and reacted. Part of the reaction product from the rotating drum reactor is hydrogen which can be utilized in suitable devices.
Method of production H/sub 2/ using a rotating drum reactor with a pulse jet heat source
Paulson, L.E.
1988-05-13
A method of producing hydrogen by an endothermic steam-carbon reaction using a rotating drum reactor and a pulse jet combustor. The pulse jet combustor uses coal dust as a fuel to provide reaction temperatures of 1300/degree/ to 1400/degree/F. Low-rank coal, water, limestone and catalyst are fed into the drum reactor where they are heated, tumbled and reacted. Part of the reaction product from the rotating drum reactor is hydrogen which can be utilized in suitable devices. 1 fig.
Clark, Allan K.
2004-01-01
The Trinity aquifer is a regional water source in the Hill Country of south-central Texas that supplies water for agriculture, commercial, domestic, and stock purposes. Rocks of the Glen Rose Limestone, which compose the upper zone and upper part of the middle zone of the Trinity aquifer, crop out at the Camp Stanley Storage Activity (CSSA), a U.S. Army weapons and munitions supply, maintenance, and storage facility in northern Bexar County (San Antonio area) (fig. 1). On its northeastern, eastern, and southern boundaries, the CSSA abuts the Camp Bullis Training Site, a U.S. Army field training site for military and Federal government agencies. During 2003, the U.S. Geological Survey (USGS), in cooperation with the U.S. Army, studied the outcropping Glen Rose Limestone at the CSSA and immediately adjacent area (Camp Stanley study area, fig. 1) to identify and map the hydrogeologic subdivisions and faults of the Glen Rose Limestone at the facility. The results of the study are intended to help resource managers improve their understanding of the distribution of porosity and permeability of the outcropping rocks, and thus the conditions for recharge and the potential for contaminants to enter the Glen Rose Limestone. This study followed a similar study done by the USGS at Camp Bullis (Clark, 2003). The purpose of this report is to present the geologic framework and hydrogeologic characteristics of the Glen Rose Limestone in the study area. The hydrogeologic nomenclature follows that introduced by Clark (2003) for the outcropping Glen Rose Limestone at Camp Bullis in which the upper member of the Glen Rose Limestone (hereinafter, upper Glen Rose Limestone), which is coincident with the upper zone of the Trinity aquifer, is divided into five intervals on the basis of observed lithologic and hydrogeologic properties. An outcrop map, two generalized sections, related illustrations, and a table summarize the description of the framework and distribution of characteristics.
NASA Astrophysics Data System (ADS)
Brühwiler, Thomas; Goudemand, Nicolas; Galfetti, Thomas; Bucher, Hugo; Baud, Aymon; Ware, David; Hermann, Elke; Hochuli, Peter A.; Martini, Rossanna
2009-12-01
The Lower Triassic sedimentary and carbonate/organic carbon isotope records from the Tulong area (South Tibet) are documented in their integrality for the first time. New age control is provided by ammonoid and conodont biostratigraphy. The basal Triassic series consists of Griesbachian dolomitic limestones, similar to the Kathwai Member in the Salt Range (Pakistan) and to the Otoceras Beds in Spiti (India). The overlying thin-bedded limestones of Dienerian age strongly resemble the Lower Ceratite Limestone of the Salt Range. They are followed by a thick series of dark green, silty shales of Dienerian-early Smithian age without fauna that strikingly resemble the Ceratite Marls of the Salt Range. This interval is overlain by thin-bedded, light grey fossil-rich limestones of middle to late Smithian age, resembling the Upper Ceratite Limestone of the Salt Range. These are followed by a shale interval of early Spathian age that has no direct counterpart in other Tethyan sections. Carbonate production resumes during the late early and middle Spathian with the deposition of red, bioclastic nodular limestone ("Ammonitico Rosso" type facies). Apart from its colour this facies is similar to the one of the Niti Limestone in Spiti and of the Spathian nodular limestone in Guangxi (South China). As in other Tethyan localities such as Spiti, the early-middle Anisian part of the Tulong section is strongly condensed and is characterized by grey, thin-bedded limestones with phosphatized ammonoids. As for many other Tethyan localities the carbon isotope record from Tulong is characterized by a late Griesbachian-Dienerian positive δ13C carb excursion (2‰), and a very prominent positive excursion (5‰) at the Smithian-Spathian boundary, thus confirming the well-documented perturbations of the global carbon cycle following the Permian-Triassic mass extinction event.
NASA Astrophysics Data System (ADS)
Mosthaf, Klaus; Brauns, Bentje; Fjordbøge, Annika S.; Rohde, Magnus M.; Kerrn-Jespersen, Henriette; Bjerg, Poul L.; Binning, Philip J.; Broholm, Mette M.
2018-06-01
Limestone aquifers are of great interest as a drinking water resource in many countries. They often have a complex crushed and fractured geology, which makes the analysis and description of flow and transport processes in such aquifers a challenging task. In this study, the solute transport behavior including fracture-matrix interaction in hydrogeological units of a limestone aquifer in eastern Denmark was characterized by designing, conducting and interpreting six depth-specific tracer tests involving natural- and forced-gradient conditions with multiple tracers representing different diffusion properties. To determine flow parameters, the tracer tests were complemented by a comprehensive set of depth-specific borehole and hydraulic tests. Based on the tests, a new and stronger conceptual understanding was developed for the different aquifer units. The investigated limestone aquifer is composed of a glacially crushed unit and two fractured units, with calcarenitic and bryozoan limestone of similar hydraulic properties. Hydraulic tests revealed that the crushed unit has a lower hydraulic conductivity than the fractured limestone units, likely due to the crushed conditions with small limestone clusters and small-aperture fractures potentially filled with fine material. In the fractured limestone units, a distinct preferential flow and primary transport along major horizontal fractures was inferred from the tracer tests under forced-gradient conditions. The dominant horizontal fractures were identified on impeller flow logs and appear connected between wells, having an extent of up to several hundred meters. Connectivity between the aquifer units was investigated with a long-term pumping test and tracer tests, revealing restricted vertical flow and transport. A very pronounced hydraulic conductivity contrast between major fractures and matrix could also be inferred from the borehole and hydraulic tests, which is consistent with the findings from the tracer tests. The difference in the matrix diffusion behavior of the simultaneously injected tracers and a long tailing in the breakthrough curves revealed that matrix diffusion has a strong influence on the solute transport in the fractured limestone.
EXTERIOR OVERVIEW, LOOKING NORTH, OF THIS 400' DEEP LIMESTONE QUARRY ...
EXTERIOR OVERVIEW, LOOKING NORTH, OF THIS 400' DEEP LIMESTONE QUARRY PIT ('THE OLD PIT') WITH LEDGE PREPARED FOR LIMESTONE EXTRACTION. AN ELEVEN-HOLE SHOT WILL DISLODGE APPROXIMATELY 25,000 TONS OF LIMESTONE WHICH, AFTER LOADING AND CRUSHING, WILL BE USED FOR ROAD CONSTRUCTION. THE CALERA QUARRY IS ONE OF FOUR ACTIVE VULCAN MATERIALS COMPANY QUARRIES IN THE DISTRICT. VULCAN MATERIALS, A FORTUNE 500 FIRM, ESTABLISHED IN BIRMINGHAM IN 1906 AS BIRMINGHAM SLAG COMPANY, VULCAN MATERIALS IS THE NATION'S FOREMOST PRODUCER OF CONSTRUCTION AGGREGATE AND A LEADING CHEMICALS MANUFACTURER. - Vulcan Material Company, Calera Quarry, 1614 Highway 84, Calera, Shelby County, AL
EXTERIOR OVERVIEW, LOOKING NORTH, OF THIS 400' DEEP LIMESTONE QUARRY ...
EXTERIOR OVERVIEW, LOOKING NORTH, OF THIS 400' DEEP LIMESTONE QUARRY PIT ("THE OLD PIT") WITH LEDGE PREPARED FOR LIMESTONE EXTRACTION. AN ELEVEN-HOLE SHOT WILL DISLODGE APPROXIMATELY 25,000 TONS OF LIMESTONE WHICH, AFTER LOADING AND CRUSHING, WILL BE USED FOR ROAD CONSTRUCTION. THE CALERA QUARRY IS ONE OF FOUR ACTIVE VULCAN MATERIALS COMPANY QUARRIES IN THE DISTRICT. VULCAN MATERIALS, A FORTUNE 500 FIRM, ESTABLISHED IN BIRMINGHAM IN 1906 AS BIRMINGHAM SLAG COMPANY, VULCAN MATERIALS IS THE NATION'S FOREMOST PRODUCER OF CONSTRUCTION AGGREGATE AND A LEADING CHEMICALS MANUFACTURER - Vulcan Material Company, Calera Quarry, 1614 Highway 84, Calera, Shelby County, AL
NASA Astrophysics Data System (ADS)
Mahmud, Kashif; Mariethoz, Gregoire; Baker, Andy; Treble, Pauline C.
2018-02-01
Cave drip water response to surface meteorological conditions is complex due to the heterogeneity of water movement in the karst unsaturated zone. Previous studies have focused on the monitoring of fractured rock limestones that have little or no primary porosity. In this study, we aim to further understand infiltration water hydrology in the Tamala Limestone of SW Australia, which is Quaternary aeolianite with primary porosity. We build on our previous studies of the Golgotha Cave system and utilize the existing spatial survey of 29 automated cave drip loggers and a lidar-based flow classification scheme, conducted in the two main chambers of this cave. We find that a daily sampling frequency at our cave site optimizes the capture of drip variability with the least possible sampling artifacts. With the optimum sampling frequency, most of the drip sites show persistent autocorrelation for at least a month, typically much longer, indicating ample storage of water feeding all stalactites investigated. Drip discharge histograms are highly variable, showing sometimes multimodal distributions. Histogram skewness is shown to relate to the wetter-than-average 2013 hydrological year and modality is affected by seasonality. The hydrological classification scheme with respect to mean discharge and the flow variation can distinguish between groundwater flow types in limestones with primary porosity, and the technique could be used to characterize different karst flow paths when high-frequency automated drip logger data are available. We observe little difference in the coefficient of variation (COV) between flow classification types, probably reflecting the ample storage due to the dominance of primary porosity at this cave site. Moreover, we do not find any relationship between drip variability and discharge within similar flow type. Finally, a combination of multidimensional scaling (MDS) and clustering by k means is used to classify similar drip types based on time series analysis. This clustering reveals four unique drip regimes which agree with previous flow type classification for this site. It highlights a spatial homogeneity in drip types in one cave chamber, and spatial heterogeneity in the other, which is in agreement with our understanding of cave chamber morphology and lithology.
Fate and Transport of TCE Solvents Through Saturated Karst Aquifer
NASA Astrophysics Data System (ADS)
Padilla, I. Y.; Carmona, M.; Anaya, A. A.
2014-12-01
Dense Nonaqueous-Phase Liquids (DNAPLs) are a group of organic compounds that have been a serious problem for groundwater pollution in karst. The industrial production and utilization of these chemicals spread since 1940, and are present at tens of thousands of contaminated sites worldwide. The physic-chemical properties of DNAPLs in conjunction with the hydraulic properties of the karst systems create the perfect condition for DNAPLs to penetrate the epikarst, reach the groundwater, and more within the karst system to zones of potential exposure, such as wells, streams and wetlands. Trichloroethylene (TCE) is the most common DNPAL found in the subsurface environment. This research studies the fate and transport of TCE DNAPL in a karstified limestone physical model (KLPM). Experiments are carried out in KLPM. The KLPM is an enclosed stainless steel tank packed with a rectangular limestone block (15cm x 15cm x 76cm) that simulates a saturated confine karst aquifer. DNAPL experiment involve the injection of 40 ml of pure TCE into steady groundwater flow at the upstream boundary of the KLPM model, while sampling spatially and temporally along the block. Samples are analyzed for TCE on the pure and dissolved phase. Pure TCE is analyzed volumetrically and dissolved phase concentrations are analyze using a High Performance Liquid Chromatography (HPLC). TCE data is used to construct temporal distributions curves (TDCs) at different spatial locations. Results show that pure TCE volumes are collected at the beginnings of the experiment in sampling ports located near the injection port and along preferential flow paths. TCE concentration TDCs show spatial variations related to the limestone block heterogeneously. Rapid response to TCE concentrations is associated with preferential flow paths. Slow response and long tailing of TCE of TCE concentration are associated with diffusive transport in rock matrix and mass transport rates limitations. Bimodal distributions are associated with multiple flow path connectivity. Overall, results show that karstified limestone has a high capacity to rapidly transport, as well as store and slowly release TCE pure and dissolved phase. Response times to TCE concentrations depend on the mode of transport, and region of flow paths.
Illusion Of Defeat: Egyptian Strategic Thinking And The 1973 Yom Kippur War
2016-06-04
jump-start a stalled political process, reclaim the Sinai Peninsula, and ultimately achieve peace with Israel. Egypt had lost tactically, but won...Israeli vulnerability, jump-start a stalled political process, reclaim the Sinai Peninsula, and ultimately achieve peace with Israel. Egypt had lost...New York: Free Press, 1990), 95. 2 William Burr, ed., “The October War and U.S. Policy,” The National Security Archive at The George Washington
Claiming space for an engaged anthropology: spatial inequality and social exclusion.
Low, Setha M
2011-01-01
I use the concept of “engaged anthropology” to frame a discussion of how “spatializing culture” uncovers systems of exclusion that are hidden or naturalized and thus rendered invisible to other methodological approaches. “Claiming Space for an Engaged Anthropology” is doubly meant: to claim more intellectual and professional space for engagement and to propose that anthropology include the dimension of space as a theoretical construct. I draw on three fieldwork examples to illustrate the value of the approach: (1) a Spanish American plaza, reclaimed from a Eurocentric past, for indigenous groups and contemporary cultural interpretation; (2) Moore Street Market, an enclosed Latino food market in Brooklyn, New York, reclaimed for a translocal set of social relations rather than a gentrified redevelopment project; (3) gated communities in Texas and New York and cooperatives in New York, reclaiming public space and confronting race and class segregation created by neoliberal enclosure and securitization.
DOE Office of Scientific and Technical Information (OSTI.GOV)
Guernsey, J L; Brown, L A; Perry, A O
1978-02-01
This case study examines the reclamation practices of the Georgia Kaolin's American Industrial Clay Company Division, a kaolin producer centered in Twiggs, Washington, and Wilkinson Counties, Georgia. The State of Georgia accounts for more than one-fourth of the world's kaolin production and about three-fourths of U.S. kaolin output. The mining of kaolin in Georgia illustrates the effects of mining and reclaiming lands disturbed by area surface mining. The disturbed areas are reclaimed under the rules and regulations of the Georgia Surface Mining Act of 1968. The natural conditions influencing the reclamation methodologies and techniques are markedly unique from those ofmore » other mining operations. The environmental disturbances and procedures used in reclaiming the kaolin mined lands are reviewed and implications for planners are noted.« less
Life Cycle Energy Analysis of Reclaimed Water Reuse Projects in Beijing.
Fan, Yupeng; Guo, Erhui; Zhai, Yuanzheng; Chang, Andrew C; Qiao, Qi; Kang, Peng
2018-01-01
To illustrate the benefits of water reuse project, the process-based life cycle analysis (LCA) could be combined with input-output LCA to evaluate the water reuse project. Energy is the only evaluation parameter used in this study. Life cycle assessment of all energy inputs (LCEA) is completed mainly by the life cycle inventory (LCI), taking into account the full life cycle including the construction, the operation, and the demolition phase of the project. Assessment of benefit from water reuse during the life cycle should focus on wastewater discharge reduction and water-saving benefits. The results of LCEA of Beijing water reuse project built in 2014 in a comprehensive way shows that the benefits obtained from the reclaimed water reuse far exceed the life cycle energy consumption. In this paper, the authors apply the LCEA model to estimate the benefits of reclaimed water reuse projects quantitatively.
Recent developments in water quality monitoring for Space Station reclaimed wastewaters
NASA Technical Reports Server (NTRS)
Small, John W.; Verostko, Charles E.; Linton, Arthur T.; Burchett, Ray
1987-01-01
This paper discusses the recent developments in water quality monitoring for Space Station reclaimed wastewaters. A preprototype unit that contains an ultraviolet absorbance organic carbon monitor integrated with pH and conductivity sensors is presented. The preprototype has provisions for automated operation and is a reagentless flow-through system without any gas/liquid interfaces. The organic carbon monitor detects by utraviolet absorbance the organic impurities in reclaimed wastewater which may be correlated to the organic carbon content of the water. A comparison of the preprototype organic carbon detection values with actual total organic carbon measurements is presented. The electrolyte double junction concept for the pH sensor and fixed electrodes for both the pH and conductivity sensors are discussed. In addition, the development of a reagentless organic carbon analyzer that incorporates ultraviolet oxidation and infrared detection is presented. Detection sensitivities, hardware development, and operation are included.
Elhaddad, Farid; Carrascosa, Luis A M; Mosquera, Maria J
2018-04-28
A novel alkoxysilane-based product was applied on limestone samples from a Roman archaeological site. The study consisted of an initial phase to evaluate site environmental conditions in order to choose the most suitable product type to be applied. The decay that was produced in the site is mainly caused by natural action, with water being the main vehicle for the decay agents. Thus, the effectiveness of an innovative product with hydrophobic/consolidant properties and two commercial products (consolidant and hydrophobic agent) were evaluated on limestone from Acinipo site, under laboratory conditions. Next, the long-term effectiveness of the three products under study was evaluated by the exposure of limestone samples in the archaeological site for a period of three years. Since the recognized incompatibility between alkoxysilanes and pure carbonate stones, the interaction between the products and the limestones was widely investigated. The results that were obtained allow for it to be concluded that the innovative product presents adequate compatibility and adherence to the limestone under study, producing a long-term effective, homogeneous, and continuous coating with a depth of penetration of up to 10 mm. However, the commercial products produced discontinuous aggregates on the limestone surface, did not penetrate into its porous structure and it did not produce long-lasting effects.
A Metagenomic Survey of Limestone Hill in Taiwan
NASA Astrophysics Data System (ADS)
Hsu, Y. W.; Li, K. Y.; Chen, Y. W.; Huang, T. Y.; Chen, W. J.; Shih, Y. J.; Chen, J. S.; Fan, C. W.; Hsu, B. M.
2016-12-01
The limestone of Narro-Sky in Tainliao, Taiwan is of Pleistocene reef limestones interbedded in clastic layers that covered the Takangshan anticlines. Understanding how microbial relative abundance was changed in response to changes of environmental factors may contribute to better comprehension of roles that microorganisms play in altering the landscape structures. In this study, microorganisms growing on the wall of limestone, in the water dripping from the limestone wall and of soil underneath the wall were collected from different locations where the environmental factors such as daytime illumination, humidity, or pH are different. Next generation sequencing (NGS) was carried out to examine the compositions and richness of microbial community. The metagenomics were clustered into operational taxonomic units (OTUs) to analyze relative abundance, diversities and principal coordinates analysis (PCoA). Our results showed the soil sample has the highest alpha diversity while water sample has the lowest. Four major phyla, which are Proteobacteria, Acidobacteria, Actinobacteria, and Cyanobacteria, account for 80 % of total microbial biomass in all groups. Cyanobacteria were found most abundantly in limestone wall instead of water or soil of weathering limestone. The PCoA dimensional patterns of each phylum showed a trace of microbial community dynamic changes, which might be affected by environmental factors. This study provides the insights to understand how environmental factors worked together with microbial community to shape landscape structures.
DOT National Transportation Integrated Search
2013-11-01
In 2009, ASTM and AASHTO permitted the use of up to 5% interground limestone in ordinary portland cement (OPC) as a part of ASTM : C150/AASHTO M85. When this project was initiated a new proposal was being discussed that would enable up to 15% intergr...
Ten Fingers, Keely
2005-01-01
The history and legacy of Western, colonial research methodologies and policy frameworks continue to create and maintain dichotomies of superior/inferior, and valued/not valued between Western and First Nations cultures, peoples and knowledge. This article was written to awaken discussion on how First Nations are working to shape the direction of research and policy development. It draws upon the author's personal observations and experiences of Western and Indigenous frameworks. The author also draws upon the growing body of work on this issue presented by indigenous researchers and scholars. The Health Information Research Committee of the Assembly of Manitoba Chiefs rejects colonial research frameworks and promotes and supports culturally-respectful research. The Dakota in Manitoba are identifying our own Quality of Life indicators and developing policies based on our own cultural values. The Mohawk of Akwesasne have developed research ethics and protocols based on their cultural principles of skennen (peace), kariwiio (good word), and kasastensera (strength). First Nations people in Canada and the world are increasingly rejecting Western, colonial frameworks of research and policy development. Instead, we are reclaiming our right to be who we are, and we are revitalizing our cultures through promotion and utilization of indigenous research methodologies and development of culturally-rooted policy. Though the response of researchers and policy-makers is not yet known, these developments will continue into the future due to the commitment and work of First Nations people.
DOE Office of Scientific and Technical Information (OSTI.GOV)
Erickson, W.R.; Carlson, K.E.
The Pittsburg & Midway Coal Mining Co.`s ({open_quotes}P&M{close_quotes}) Midway Mine lies 50 miles south of Kansas City, Kansas, straddling the border of Kansas and Missouri. P&M actively mined the area until 1989, when the mine was closed and reclaimed. Approximately 3,750 acres of surface mined land were topsoiled and revegetated to cool season fescue/legume pasture. Various pasture management methods are being utilized to meet reclamation success standards and achieve final bond release. The effectiveness and costs of various cool season fescue/legume pasture management methods are evaluated and contrasted. These methods include sharecropping, bush hogging, burning and livestock grazing. It presentsmore » guidelines used to develop a site specific rotational livestock grazing programs with land owners or contractors, and local, state and federal agencies. Rotational grazing uses both cow/calf or feeder livestock operations. Key managerial elements used to control grazing activities, either by the landowner or a contractor, are reviewed. Methods used to determine stocking levels for successful rotational grazing on this type of pasture are presented. Rotational grazing of livestock has proven to be the most effective method for managing established cool season fescue/legume pastures at this site. Initial stocking rates of 1 A.U.M. per 5 acres have been modified to a current stocking rate of 1 A.U.M. per 2.5 acres. Supporting physical and chemical data are presented and discussed.« less
NASA Astrophysics Data System (ADS)
Dodd, J. Robert; Nelson, Campbell S.
1998-10-01
Mississippian limestones exposed in Indiana, U.S.A., were deposited in a shallow tropical ocean. However, many properties of these limestones are more like those of modern and Cenozoic non-tropical limestones such as those found in New Zealand. The dominant skeletal grains in the Indiana limestones are calcitic echinoderms, bryozoans, and brachiopods. The dominant skeletal grains in most Cenozoic limestones of New Zealand are calcitic bryozoans, echinoderms, bivalve molluscs, and foraminifera. In contrast, modern and Cenozoic tropical limestones contain an abundance of aragonitic green algae, corals, and molluscs. Early in diagenesis the metastable aragonite dissolves and reprecipitates as calcite, causing early cementation of the sediments. Originally aragonitic fossils that have dissolved can be identified as molds that are commonly filled with secondary calcite. Because they contained little aragonite, most of the Indiana and New Zealand limestones did not have an abundant source of early cement. Except for local cases in which grains were cemented in contact with carbonate supersaturated seawater, grainstones were relatively deeply buried with little cement between the grains. This resulted in mechanical and chemical compaction of skeletal grains, producing a `fitted fabric' with greatly reduced pore space, either open or filled with cement between the grains. Cement in these aragonite-poor grainstones comes largely from pressure dissolution between grains and along stylolitic seams in the rock, features that are common only after burial beyond a few hundred meters. The final product of deeply buried (up to 2000 m) Cenozoic New Zealand grainstones is similar to the Mississippian grainstones of Indiana. In the Indiana limestones we have only the final product of this extensive burial diagenesis. However, the New Zealand sediments and rocks reveal all steps of formation of the final deeply buried limestone. The reason for the scarcity of originally aragonitic fossil grains in Paleozoic rocks worldwide is unknown. Organisms with aragonitic skeletons such as some molluscan groups and calcareous green algae were present, but seldom in much abundance. The aragonitic scleractinian corals had not yet evolved. Previous researchers have noted that non-skeletal precipitates such as ooids and cements have at times during the Paleozoic been predominantly aragonite and at other times calcite. They have attributed this difference to secular variation in seawater chemistry (icehouse vs. greenhouse seas). Abundance of aragonitic and calcitic skeletal grains does not follow this pattern.
Cravotta, C.A.; Ward, S.J.
2008-01-01
Passive-treatment systems that route acidic mine drainage (AMD) through crushed limestone and/or organic-rich substrates have been used to remove the acidity and metals from various AMD sources, with a wide range of effects. This study evaluates treatment of net-acidic, oxic, iron-laden AMD with limestone alone, and with organic-rich compost layered with the limestone. In the fall of 2003, a treatment system consisting of two parallel, 500-m2 downflow cells followed by a 400-m2 aerobic settling pond and wetland was installed to neutralize the AMD from the Bell Mine, a large source of AMD and baseflow to the Schuylkill River in the Southern Anthracite Coalfield, in east-central Pennsylvania. Each downflow cell consisted of a lower substrate layer of 1,090 metric tons (t) of dolomitic limestone (60 wt% CaCO3) and an upper layer of 300 t of calcitic limestone (95 wt% CaCO3); one of the downflow cells also included a 0.3 m thick layer of mushroom compost over the limestone. AMD with pH of 3.5-4.3, dissolved oxygen of 6.6-9.9 mg/L, iron of 1.9-5.4 mg/L, and aluminum of 0.8-1.9 mg/L flooded each cell to a depth 0.65 m above the treatment substrates, percolated through the substrates to underlying, perforated outflow pipes, and then flowed through the aerobic pond and wetland before discharging to the Schuylkill River. Data on the flow rates and chemistry of the effluent for the treatment system indicated substantial neutralization by the calcitic limestone but only marginal effects from the dolomitic limestone or compost. Because of its higher transmissivity, the treatment cell containing only limestone neutralized greater quantities of acidity than the cell containing compost and limestone. On average, the treatment system removed 62% of the influent acidity, 47% of the dissolved iron, 34% of the dissolved aluminum, and 8% of the dissolved manganese. Prior to treatment of the Bell Discharge, the Schuylkill River immediately below its confluence with the discharge had pH as low as 4.1 and supported few, if any, fish. However, within the first year of treatment, the pH was maintained at values of 5.0 or greater and native brook trout were documented immediately below the treatment system, though not above. ?? 2008 Springer-Verlag.
Anwar, M N; Ravindran, V; Morel, P C H; Ravindran, G; Cowieson, A J
2016-10-01
The purpose of this study was to determine the effect of limestone particle size and calcium (Ca) to non-phytate phosphorus (P) ratio on the true ileal Ca digestibility of limestone for broiler chickens. A limestone sample was passed through a set of sieves and separated into fine (<0.5 mm) and coarse (1-2 mm) particles. The analysed Ca concentration of both particle sizes was similar (420 g/kg). Six experimental diets were developed using each particle size with Ca:non-phytate P ratios of 1.5:1, 2.0:1 and 2.5:1, with ratios being adjusted by manipulating the dietary Ca concentrations. A Ca-free diet was also developed to determine the basal ileal endogenous Ca losses. Titanium dioxide (3 g/kg) was incorporated in all diets as an indigestible marker. Each experimental diet was randomly allotted to 6 replicate cages (8 birds per cage) and fed from d 21 to 24 post hatch. Apparent ileal digestibility of Ca was calculated using the indicator method and corrected for basal endogenous losses to determine the true Ca digestibility. The basal ileal endogenous Ca losses were determined to be 127 mg/kg of dry matter intake. Increasing Ca:non-phytate P ratios reduced the true Ca digestibility of limestone. The true Ca digestibility coefficients of limestone with Ca:non-phytate P ratios of 1.5, 2.0 and 2.5 were 0.65, 0.57 and 0.49, respectively. Particle size of limestone had a marked effect on the Ca digestibility, with the digestibility being higher in coarse particles (0.71 vs. 0.43).
Attrition of limestone by impact loading in fluidized beds
DOE Office of Scientific and Technical Information (OSTI.GOV)
Fabrizio Scala; Fabio Montagnaro; Piero Salatino
2007-09-15
The present study addresses limestone attrition and fragmentation associated with impact loading, a process which may occur extensively in various regions of fluidized bed (FB) combustors/gasifiers, primarily the jetting region of the bottom bed, the exit region of the riser, and the cyclone. An experimental protocol for the characterization of the propensity of limestone to undergo attrition/fragmentation by impact loading is reported. The application of the protocol is demonstrated with reference to an Italian limestone whose primary fragmentation and attrition by surface wear have already been characterized in previous studies. The experimental procedure is based on the characterization of themore » amount and particle size distribution of the debris generated upon the impact of samples of sorbent particles against a target. Experiments were carried out at a range of particle impact velocities between 10 and 45 m/s, consistent with jet velocities corresponding to typical pressure drops across FB gas distributors. The protocol has been applied to either raw or preprocessed limestone samples. In particular, the effect of calcination, sulfation, and calcination/recarbonation cycles on the impact damage suffered by sorbent particles has been assessed. The measurement of particle voidage and pore size distribution by mercury intrusion was also accomplished to correlate fragmentation with the structural properties of the sorbent samples. Fragmentation by impact loading of the limestone is significant. Lime displays the largest propensity to undergo impact damage, followed by the sorbent sulfated to exhaustion, the recarbonated sorbent, and the raw limestone. Fragmentation of the raw limestone and of the sulfated lime follows a pattern typical of the failure of brittle materials. The fragmentation behavior of lime and recarbonated lime better conforms to a disintegration failure mode, with an extensive generation of very fine fragments. 27 refs., 9 figs. 1 tab.« less
The public health significance of trace chemicals in waste water utilization
Shuval, Hillel I.
1962-01-01
The practice of waste water utilization has grown considerably in recent years, owing to the growing demand for water for agricultural, industrial and domestic purposes. Such utilization presents certain problems in respect of the quality of the reclaimed water, on account of the presence of certain trace chemicals in the waste waters to be re-used. The presence of these trace chemicals may have important consequences in the agricultural or industrial utilization of waste waters, but from the public health point of view it is in the re-use of waste waters for domestic purposes that their presence has most importance, owing to their possible toxic effects. This paper discusses the public health significance of trace chemicals in water, with special reference to some of the newer complex synthetic organic compounds that are appearing in ever-increasing numbers in industrial wastes. Current information on the acute and chronic toxicity of these substances is reviewed and related to possible methods of treatment of waste waters. In conclusion, the author points out that the problem of trace chemicals is not confined only to direct waste-water reclamation projects, but arises in all cases where surface waters polluted with industrial wastes are used as a source of domestic supply. PMID:13988826
NASA Astrophysics Data System (ADS)
Durand-Delga, Michel; Esteras, Manuel; Gardin, Silvia; Paquet, Hélène
2005-07-01
The originality of the Malm-Cretaceous series of the Tariquides (Gibraltar arc), as compared to those of the Rifian-Betic 'Dorsale' (Alboran domain), and especially with the Penibetic (Iberia) domain, is emphasized. In the Los Pastores Group, near Algeciras, Upper Tithonian nodular limestones directly lie on the Dogger and are followed by Aptychus-bearing limestones (Late Berriasian to Barremian). In the Musa Group, Rif, radiolarites are followed by siliceous limestones (Kimmeridgian-Tithonian), then by karst and massflow breccias connected to a Berriasian tectonics, by Aptychus-bearing marly limestones, then by karst filled by Turonian limestones, and finally by Maastrichtian-Palaeocene polychrome pelites, whose micropalaeontological and mineral compositions (clay minerals, Fe sbnd Mn nodules) refer to a deep-sea, probably infra-CCD, sedimentation. To cite this article: M. Durand-Delga et al., C. R. Geoscience 337 (2005).
NASA Astrophysics Data System (ADS)
Dona, Obie Mario; Ibrahim, Eddy; Susilo, Budhi Kuswan
2017-11-01
The research objective is to describe potential, to analyze the quality and quantity of limestone, and to know the limit distribution of rocks based on the value of resistivity, the pattern of distribution of rocks by drilling, the influence mineral growing on rock against resistivity values, the model deposition of limestone based on the value resistivity of rock and drilling, and the comparison between the interpretation resistivity values based on petrographic studies by drilling. Geologic Formations study area consists of assays consisting of altered sandstone, phyllite, slate, siltstone, grewake, and inset limestone. Local quartz sandstone, schist, genealogy, which is Member of Mersip Stylists Formation, consists of limestone that formed in shallow seas. Stylists Formation consists of slate, shale, siltstone and sandstone. This research methodology is quantitative using experimental observation by survey. This type of research methodology by its nature is descriptive analysis.
Managing Scarce Water Resources in China's Coal Power Industry.
Zhang, Chao; Zhong, Lijin; Fu, Xiaotian; Zhao, Zhongnan
2016-06-01
Coal power generation capacity is expanding rapidly in the arid northwest regions in China. Its impact on water resources is attracting growing concerns from policy-makers, researchers, as well as mass media. This paper briefly describes the situation of electricity-water conflict in China and provides a comprehensive review on a variety of water resources management policies in China's coal power industry. These policies range from mandatory regulations to incentive-based instruments, covering water withdrawal standards, technological requirements on water saving, unconventional water resources utilization (such as reclaimed municipal wastewater, seawater, and mine water), water resources fee, and water permit transfer. Implementing these policies jointly is of crucial importance for alleviating the water stress from the expanding coal power industry in China.
Managing Scarce Water Resources in China's Coal Power Industry
NASA Astrophysics Data System (ADS)
Zhang, Chao; Zhong, Lijin; Fu, Xiaotian; Zhao, Zhongnan
2016-06-01
Coal power generation capacity is expanding rapidly in the arid northwest regions in China. Its impact on water resources is attracting growing concerns from policy-makers, researchers, as well as mass media. This paper briefly describes the situation of electricity-water conflict in China and provides a comprehensive review on a variety of water resources management policies in China's coal power industry. These policies range from mandatory regulations to incentive-based instruments, covering water withdrawal standards, technological requirements on water saving, unconventional water resources utilization (such as reclaimed municipal wastewater, seawater, and mine water), water resources fee, and water permit transfer. Implementing these policies jointly is of crucial importance for alleviating the water stress from the expanding coal power industry in China.
NASA Technical Reports Server (NTRS)
Hester, J. C.; Brandon, C. A.
1972-01-01
A feasibility demonstration of a hyperfiltration technique to determine its capability to reclaim shower wastewater at elevated temperature was conducted. Approximately twenty (20) gallons of typical shower water were processed through a dynamically formed membrane at a temperature of 167 F. Chemical and bacterial analyses of the product water are presented which show compliance with all potable water requirements established for extended manned space missions. In addition, subsystem characteristics and capabilities are discussed.
Muhammad, Siti Nurjaliah; Kusin, Faradiella Mohd; Md Zahar, Mohd Syakirin; Mohamat Yusuff, Ferdaus; Halimoon, Normala
2017-08-01
Passive bioremediation of metal- and sulfate-containing acid mine drainage (AMD) has been investigated in a batch study. Multiple substrates were used in the AMD remediation using spent mushroom compost (SMC), limestone, activated sludge (AS), and woodchips (WC) under anoxic conditions suitable for bacterial sulfate reduction (BSR). Limestones used were of crushed limestone (CLS) and uncrushed limestone, provided at two different ratios in mixed substrates treatment and varied by the proportion of SMC and limestone. The SMC greatly assisted the removals of sulfate and metals and also acted as an essential carbon source for BSR. The mixed substrate composed of 40% CLS, 30% SMC, 20% AS, and 10% WC was found to be effective for metal removal. Mn, Cu, Pb, and Zn were greatly removed (89-100%) in the mixed substrates treatment, while Fe was only removed at 65%. Mn was found to be removed at a greatly higher rate than Fe, suggesting important Mn adsorption onto organic materials, that is, greater sorption affinity to the SMC. Complementary with multiple treatment media was the main mechanism assisting the AMD treatment through microbial metal reduction reactions.
DOE Office of Scientific and Technical Information (OSTI.GOV)
Shim, Moo Joon; Choi, Byoung Young; Lee, Giehyeon
To determine the long-term effectiveness of the limestone treatment for acid mine drainage (AMD) in Gangneung, Korea, we investigated the elemental distribution in streams impacted by AMD and compared the results of previous studies before and approximately 10 years after the addition of limestone. Addition of limestone in 1999 leads to a pH increase in 2008, and with the exception of Ca, the elemental concentrations (e.g., Fe, Mn, Mg, Sr, Ni, Zn, S) in the streams decreased. The pH was 2.5–3 before the addition of limestone and remained stable at around 4.5–5 from 2008 to 2011, suggesting the reactivity ofmore » the added limestone was diminished and that an alternative approach is needed to increase the pH up to circumneutral range and maintain effective long-term treatment. To identify the processes causing the decrease in the elemental concentrations, we also examined the spatial (approximately 7 km) distribution over three different types of streams affected by the AMD. Lastly, the elemental distribution was mainly controlled by physicochemical processes including redox reactions, dilution on mixing, and co-precipitation/adsorption with Fe (hydr)oxides.« less
Effect of limestone reactivity and percent on production by dairy cows in early lactation.
Nocek, J E; Braund, D G; English, J E
1983-12-01
Seventy-two Holstein cows (16 first lactation) were assigned to four treatments: A) normal-grind limestone (800 to 1000 mu) added to provide .77% calcium (total ration dry basis); B) fine-grind limestone (less than 150 mu) at .77% calcium; C) normal-grind at 1.15% calcium; and D) fine-grind limestone at 1.15% calcium. Cows fed diets containing .77% calcium had higher percent milk fat and fat yield than those fed 1.15% calcium diets, and cows fed fine-grind limestone had greater percent fat and fat yield than those fed normal-grind limestone. Four percent fat-corrected milk was higher for cows fed .77% calcium diets. Trends were similar for heifers in first lactation. Dry matter intake was higher for cows fed .77% calcium diets, and nutrient efficiency for milk synthesis favored cows fed fine-grind 1.15% calcium. Fecal pH was higher during wk 4 on treatment for cows fed high calcium diets; however, 8 wk were not different. Fecal starch and calcium and phosphorus in plasma were not different between treatments: however, heifers fed fine-grind 1.15% calcium showed a decrease of fecal starch with time.
Modifying the properties of finely ground limestone by tumbling granulation
NASA Astrophysics Data System (ADS)
Macho, Oliver; Eckert, Maroš; Tomášová, Barbora; Peciar, Peter; Ščasný, Martin; Fekete, Roman; Peciar, Marián
2016-06-01
Calcium carbonate in the form of finely ground limestone is a material that has found its application in a wide range of industries, in the chemical, rubber, agricultural, and paper industries, is used for desulfurization of boilers and other. In civil engineering, ground limestone is used for the production of building materials, plaster and mortar mixtures, as a filler in concrete mixtures, in road construction, and as an essential component of mastic asphalt. This paper deals with examining the modification of the properties of finely ground limestone by the tumbling agglomeration method. It has been shown that the components of concrete with a round grain have a positive effect on the pumping of concrete in comparison with an elongated grain or the rough surface of crushed stone. The experiments will be carried out on a granulation plate using a variety of granulation liquid. The agglomerates and their properties were compared with untreated finely ground limestone, with a focus on detecting changes in compressibility, density and particle size. The output of this paper is a description and graphical representation of the changes in the properties of ground limestone before and after the agglomeration process.
Shim, Moo Joon; Choi, Byoung Young; Lee, Giehyeon; ...
2015-09-28
To determine the long-term effectiveness of the limestone treatment for acid mine drainage (AMD) in Gangneung, Korea, we investigated the elemental distribution in streams impacted by AMD and compared the results of previous studies before and approximately 10 years after the addition of limestone. Addition of limestone in 1999 leads to a pH increase in 2008, and with the exception of Ca, the elemental concentrations (e.g., Fe, Mn, Mg, Sr, Ni, Zn, S) in the streams decreased. The pH was 2.5–3 before the addition of limestone and remained stable at around 4.5–5 from 2008 to 2011, suggesting the reactivity ofmore » the added limestone was diminished and that an alternative approach is needed to increase the pH up to circumneutral range and maintain effective long-term treatment. To identify the processes causing the decrease in the elemental concentrations, we also examined the spatial (approximately 7 km) distribution over three different types of streams affected by the AMD. Lastly, the elemental distribution was mainly controlled by physicochemical processes including redox reactions, dilution on mixing, and co-precipitation/adsorption with Fe (hydr)oxides.« less
Nimaichand, Salam; Devi, Asem Mipeshwaree; Tamreihao, K.; Ningthoujam, Debananda S.; Li, Wen-Jun
2015-01-01
Studies on actinobacterial diversity in limestone habitats are scarce. This paper reports profiling of actinobacteria isolated from Hundung limestone samples in Manipur, India using ARDRA as the molecular tool for preliminary classification. A total of 137 actinobacteria were clustered into 31 phylotypic groups based on the ARDRA pattern generated and representative of each group was subjected to 16S rRNA gene sequencing. Generic diversity of the limestone isolates consisted of Streptomyces (15 phylotypic groups), Micromonospora (4), Amycolatopsis (3), Arthrobacter (3), Kitasatospora (2), Janibacter (1), Nocardia (1), Pseudonocardia (1) and Rhodococcus (1). Considering the antimicrobial potential of these actinobacteria, 19 showed antimicrobial activities against at least one of the bacterial and candidal test pathogens, while 45 exhibit biocontrol activities against at least one of the rice fungal pathogens. Out of the 137 actinobacterial isolates, 118 were found to have at least one of the three biosynthetic gene clusters (PKS-I, PKS-II, NRPS). The results indicate that 86% of the strains isolated from Hundung limestone deposit sites possessed biosynthetic gene clusters of which 40% exhibited antimicrobial activities. It can, therefore, be concluded that limestone habitat is a promising source for search of novel secondary metabolites. PMID:25999937
NASA Astrophysics Data System (ADS)
Rozgonyi-Boissinot, Nikoletta; Agárdi, Tamás; Karolina Cebula, Ágnes; Török, Ákos
2017-04-01
The water absorption of weathering sensitive stones is a critical parameter that influences durability. The current paper compares different methods of water absorption tests by using on site and laboratory tests. The aims of the tests were to assess the water absorption of un-weathered quarry stones and various weathering forms occurring on porous limestone monuments. For the tests a Miocene porous limestone was used that occurs in Central and Western Hungary and especially near and in Budapest. Besides the Hungarian occurrences the same or very similar porous limestones are found in Austria, Slovakia and in the Czech Republic. Several quarries were operating in these countries. Due to the high workability the stone have been intensively used as construction material from the Roman period onward. The most prominent monuments made of this stone were built in Vienna and in Budapest during the 18th -19th century and in the early 20th century. The high porosity and the micro-fabric of the stone make it prone to frost- and salt weathering. Three different limestone types were tested representing coarse-, medium- and fine grained lithologies. The test methods included Rilem tube (Karsten tube) tests and capillary water absorption tests. The latter methodology has been described in detail in EN 1925:2000. The test results of on-site tests of weathered porous limestone clearly show that the water absorption of dissolved limestone surfaces and crumbling or micro-cracked limestone is similar. The water absorption curves have similar inclinations marking high amount of absorbed water. To the contrary, the white weathering crusts covered stone blocks and black crusts have significantly lower water absorptions and many of these crusts are considered as very tight almost impermeable surfaces. Capillary water absorption tests in the laboratory allowed the determination of maximum water absorption of quarried porous limestone. Specimens were placed in 3 mm of water column and the absorbed amount of water was detected. The obtained 29-30m% water absorption values compared to the 30-35m% of the total porosity of the stone, clearly suggest that the pores can be saturated with water under standard barometric pressure and therefore the tested porous Miocene limestones are very prone to salt attack.
Geologic controls on cave development in Burnsville Cove, Bath and Highland Counties, Virginia
Swezey, Christopher; Haynes, John T.; Lucas, Philip C.; Lambert, Richard A.
2017-01-01
Burnsville Cove in Bath and Highland Counties (Virginia, USA) is a karst region in the Valley and Ridge Province of the Appalachian Mountains. The region contains many caves in Silurian to Devonian limestone, and is well suited for examining geologic controls on cave location and cave passage morphology. In Burnsville Cove, many caves are located preferentially near the axes of synclines and anticlines. For example, Butler Cave is an elongate cave where the trunk channel follows the axis of Sinking Creek syncline and most of the side passages follow joints at right angles to the syncline axis. In contrast, the Water Sinks Subway Cave, Owl Cave, and Helictite Cave have abundant maze patterns, and are located near the axis of Chestnut Ridge anticline. The maze patterns may be related to fact that the anticline axis is the site of the greatest amount of flexure, leading to more joints and (or) greater enlargement of joints. Many of the larger caves of Burnsville Cove (e.g., Breathing Cave, Butler Cave–Sinking Creek Cave System, lower parts of the Water Sinks Cave System) are developed in the Silurian Tonoloway Limestone, the stratigraphic unit with the greatest surface exposure in the area. Other caves are developed in the Silurian to Devonian Keyser Limestone of the Helderberg Group (e.g., Owl Cave, upper parts of the Water Sinks Cave System) and in the Devonian Shriver Chert and (or) Licking Creek Limestone of the Helderberg Group (e.g., Helictite Cave). Within the Tonoloway Limestone, the larger caves are developed in the lower member of the Tonoloway Limestone immediately below a bed of silica-cemented sandstone. In contrast, the larger caves in the Keyser Limestone are located preferentially in limestone beds containing stromatoporoid reefs, and some of the larger caves in the Licking Creek Limestone are located in beds of cherty limestone below the Devonian Oriskany Sandstone. Geologic controls on cave passage morphology include joints, bedding planes, and folds. The influence of joints results in tall and narrow cave passages, whereas the influence of bedding planes results in cave passages with flat ceilings and (or) floors. The influence of folds is less common, but a few cave passages follow fold axes and have distinctive arched ceilings.
The Significance of Podpe limestone in the Cultural Heritage of Slovenia
NASA Astrophysics Data System (ADS)
Kramar, Sabina; Bedjanič, Mojca; Mirtič, Breda; Mladenović, Ana; Rožič, Boštjan; Skaberne, Dragomir; Zupančič, Nina
2013-04-01
Podpeč limestone is characterized by its dark grey, or nearly black colour, with white fossil shells of the Lithiotis. These beds, which have been dated as Lower Jurassic, occur in southern and south-western Slovenia, and are particularly common in areas southwest of Ljubljana. The main quarry, which is not active, is located next to the village of Podpeč near Ljubljana, and has been declared as a geological natural value of national importance; as such, it is officially protected as a natural monument. In the close vicinity of the village there are some other smaller quarries, but all of them have been abandoned. With its very low porosity (0.9%) and water absorption (0.13 - 0.30 % by mass), but relatively high compressive strength (185 MPa), this limestone is quite durable, although its colouring becomes somewhat bleached when situated outdoors. The use of Podpeč limestone was first documented in the case of the Roman period in Slovenia, when it was used for funerary stelae, votive altars, boundary stones, and other artefacts. At the end of the 5th Century AD, with the fall of the Roman Empire, stone-cutting ceased at Podpeč for the next few centuries. Before 1850 Podpeč limestone had no special value. Only very few portals or pilasters made of this stone are known, and no evidence has been found in churches. However, towards the end of the 19th Century Podpeč limestone became better-known, although before the first half of the 20th Century there were no significant stonecutting workshops in Podpeč. After this, stone was supplied progressively from the main quarry. Large numbers of buildings in Ljubljana and central Slovenia have sills, lintels and jambs made of Podpeč limestone. Production stopped in 1967. The internationally renowned Slovenian architect Jože Plečnik (1872-1957) used Podpeč limestone in various Slovenian buildings - the central stadium in Ljubljana, the National University Library, many altars and churches (Bogojina, the Ši\\vska and Bežigrad districts of Ljubljana), parts of the Parliament of the Republic of Slovenia (Ljubljana), and Ljubljana's first skyscraper. With the exception of the Antonius Church in Belgrade, which was constructed by Plečnik, where part of the altar was made of Podpeč limestone, the international use of Podpeč limestone is not known.
NASA Astrophysics Data System (ADS)
Kozlovcev, Petr; Přikryl, Richard
2014-05-01
Prague Basin, making part of the Barrandian area (Bohemian Massif, Czech Republic), is a rift-like depression filled with non-metamorphosed sedimentary series of Upper Proterozoic - Lower Palaeozoic age. Among other sedimentary rocks, different types of limestones are present. These limestone were historically exploited and used for various purposes including natural and decorative stone, common construction material, and also a raw material for firing of inorganic binders: aerial lime, hydraulic lime and/or, more recently, Ordinary Portland Cement (OPC). Lithotypes with higher amount of silica and/or clay component were of special interest due to the hydraulicity of fired product known as "pasta di Praga" in Baroque. However, our recent knowledge of these limestones is incomplete in terms of the contribution of mineralogical, geochemical, and petrographical characteristics on the properties of fired hydraulic lime. In the recent study, representative samples of 4 facies of the Lower Devonian limestone (Kosoř ls., Řeporyje ls., Dvorce-Prokop ls., and Zlíchov ls.) were subjected to a detailed mineralogical and petrographic study of raw material by means of polarizing microscopy, cathodoluminiscence of thin sections and scanning electron microscopy with an energy dispersive spectrometer (SEM-EDS). X-ray diffraction (XRD) of insoluble residues obtained by treatment with both the hydrochloric acid and the acetic acid solution was used. Wet silicate analysis provided data on the content of major elements from which standard cement and lime indexes and modules were calculated. Laboratory firing experiments of these limestone were performed by a calcination at temperature ranging from 850 to 1200°C (after 50°C). XRD of fired products shows that limestones with high content of silica (some of the Dvorce-Prokop ls.) produced binder with high amount of newly formed calcium silicates (larnite). Gehlenite and others calcium aluminates and aluminosilicates are typical for firing of limestones with higher content of clay minerals (illite and kaolinite) which are common in Kosoř ls., Řeporyje ls., and Dvorce-Prokop ls. Brownmillerite was formed in limestones exhibiting higher proportion of Fe-oxihydroxides (specifically Řeporyje ls). Presence of free lime and portlandite correlates with decreasing content of non-carbonate material (some varieties of the Dvorce-Prokop ls. from Bráník Rocks).
Livestock impacts for management of reclaimed land at Navajo Mine: The decision-making process
DOE Office of Scientific and Technical Information (OSTI.GOV)
Estrada, O.J.; Grogan, S.; Gadzia, K.L.
1997-12-31
Livestock grazing is the post-mining use for reclaimed land at Navajo Mine, a large surface coal mine on the Navajo Nation in northwest New Mexico. The Navajo Mine Grazing Management Program (GMP) uses holistic management on approximately 2,083 ha of reclaimed land to plan for final liability release and return of the land to the Navajo Nation, and to minimize the potential for post-release liability. The GMP began in 1991 to establish that livestock grazing on the reclaimed land is sustainable. Assuming that sustainability requires alternatives to conventional land management practices, the GMP created a Management Team consisting of companymore » staff, local, Navajo Nation, and Federal government officials, and technical advisors. Community members contributed to the formation of a holistic goal for the GMP that articulates their values and their desire for sustainable grazing. Major decisions (e.g., artificial insemination, water supply, supplemental feed) are tested against the goal. Biological changes in the land and the grazing animals are monitored daily to provide early feedback to managers, and annually to document the results of grazing. To date, the land has shown resilience to grazing and the animals have generally prospered. Community participation in the GMP and public statements of support by local officials indicate that the GMP`s strategy is likely to succeed.« less
Reclaimed water as an alternative source of water for the city of Bulawayo, Zimbabwe
NASA Astrophysics Data System (ADS)
Taigbenu, Akpofure E.; Ncube, Mthokozisi
Perennial water problems, precipitated by increased water demand in Bulawayo, the second largest city in Zimbabwe, has prompted the consideration of a wide array of strategies from demand management and water conservation measures to exploitation of alternative water sources. One of such strategies in the latter category includes recycling of blue water for both potable and non-potable purposes. This paper examines the existing reclaimed water system with a view at revamping the existing infrastructure to maximise reclaimed water use for purposes that are amenable to water of lower quality. It is a generally accepted practice to avoid the use of water of high quality for purposes that can tolerate a lower grade, unless it is in excess in amount [ Okun, D.A., 1973. Planning for water reuse. Journal of AWWA 65(10)]. The reclaimed water is assessed in terms of its quality and quantity vis-à-vis possible uses. Perceptions and expectations of both current and identified prospective consumers are examined and discussed, in addition to the feasibility of accommodating these identified prospective consumers in an expanded network. Apart from enhancement of the existing infrastructure, the paper highlights the need for social marketing and education in order to realise the optimum benefits of this alternative water source. The cost implications of implementing the proposed project are evaluated, including suggestions on suitable tariff structure and an allocation distribution that achieves equity.
Wang, Shiyu; Liu, Fei; Wu, Wenyong; Hu, Yaqi; Liao, Renkuan; Chen, Gaoting; Wang, Jiulong; Li, Jialin
2018-04-12
Reclaimed water reuse has become an important means of alleviating agricultural water shortage worldwide. However, the presence of endocrine disrupters has roused up considerable attention. Barrel test in farmland was conducted to investigate the migration of nonylphenol (NP) and bisphenol A (BPA) in soil-winter wheat system simulating reclaimed water irrigation. Additionally, the health risks on humans were assessed based on US EPA risk assessment model. The migration of NP and BPA decreased from the soil to the winter wheat; the biological concentration factors (BCFs) of NP and BPA in roots, stems, leaves, and grains all decreased with their added concentrations in soils. The BCFs of NP and BPA in roots were greatest (0.60-5.80 and 0.063-1.45, respectively). The average BCFs of NP and BPA in winter wheat showed negative exponential relations to their concentrations in soil. The amounts of NP and BPA in soil-winter wheat system accounted for 8.99-28.24% and 2.35-4.95%, respectively, of the initial amounts added into the soils. The hazard quotient (HQ) for children and adults ranged between 10 -6 and 1, so carcinogenic risks could be induced by ingesting winter wheat grains under long-term reclaimed water irrigation. Copyright © 2018 Elsevier Inc. All rights reserved.
Reclaimed mineland curve number response to temporal distribution of rainfall
Warner, R.C.; Agouridis, C.T.; Vingralek, P.T.; Fogle, A.W.
2010-01-01
The curve number (CN) method is a common technique to estimate runoff volume, and it is widely used in coal mining operations such as those in the Appalachian region of Kentucky. However, very little CN data are available for watersheds disturbed by surface mining and then reclaimed using traditional techniques. Furthermore, as the CN method does not readily account for variations in infiltration rates due to varying rainfall distributions, the selection of a single CN value to encompass all temporal rainfall distributions could lead engineers to substantially under- or over-size water detention structures used in mining operations or other land uses such as development. Using rainfall and runoff data from a surface coal mine located in the Cumberland Plateau of eastern Kentucky, CNs were computed for conventionally reclaimed lands. The effects of temporal rainfall distributions on CNs was also examined by classifying storms as intense, steady, multi-interval intense, or multi-interval steady. Results indicate that CNs for such reclaimed lands ranged from 62 to 94 with a mean value of 85. Temporal rainfall distributions were also shown to significantly affect CN values with intense storms having significantly higher CNs than multi-interval storms. These results indicate that a period of recovery is present between rainfall bursts of a multi-interval storm that allows depressional storage and infiltration rates to rebound. ?? 2010 American Water Resources Association.
DOE Office of Scientific and Technical Information (OSTI.GOV)
Crisp, T.E.; Nairn, R.W.; Strevett, K.A.
1998-12-31
A column study was conducted to evaluate the feasibility of using of coal combustion by-products (CCB) as alkaline materials in a field scale downflow constructed wetlands for acid mine drainage treatment. Five columns (15.24 cm in diameter and 91.44 cm high) were constructed and filled with a combination of spent mushroom substrate (SMS) and one of three alkaline materials (limestone, hydrated fly ash, or fluidized bed ash). The five mixtures utilized were 10% fluidized bed ash/40% limestone (FBA/LS), 10% fluidized bed ash (FBA), 50% limestone (LS), 50% hydrated fly ash (HFA),m and 50% sieved (>1.5 cm) hydrated fly ash (S.more » HFA) with the remainder as SMS on a w/w basis. Column received synthetic acid mine drainage containing: 400 mg/L iron, 59 mg/L aluminum, 11 mg/L manganese, 50% mg/L magnesium, 40 mg/L calcium, and 1200 mg/L sulfate for 5 months. Anoxic conditions in the influent reservoirs were maintained by a positive nitrogen pressure head. Flow rates of 2.0 mL/minute to each column were maintained by a multichannel peristaltic pump. For all columns, effluent acidity concentrations were less than influent acidity concentration (877{sup {minus}}30, n = 75f). Mean effluent acidity concentrations were 241 mg/L (FBA/LS), 186 mg/L (FBA), 419 mg/L (LS), {minus}28.5 mg/L (HFA), and 351 mg/L (S. HFA), respectively. While all column produced measurable alkalinity, only the HFA column produced a net alkaline discharge. The results of these column studies are applicable to the design and sizing of innovative field scale systems using alkaline-rich CCB`s.« less
Reducing energy-related CO2 emissions using accelerated weathering of limestone
Rau, Greg H.; Knauss, Kevin G.; Langer, William H.; Caldeira, Ken
2007-01-01
The use and impacts of accelerated weathering of limestone (AWL; reaction: CO2+H2O+CaCO3→Ca2++2(HCO3-) is explored as a CO2 capture and sequestration method. It is shown that significant limestone resources are relatively close to a majority of CO2-emitting power plants along the coastal US, a favored siting location for AWL. Waste fines, representing more than 20% of current US crushed limestone production (>109 tonnes/yr), could provide an inexpensive or free source of AWL carbonate. With limestone transportation then as the dominant cost variable, CO2 mitigation costs of $3-$4/tonne appear to be possible in certain locations. Perhaps 10–20% of US point–source CO2 emissions could be mitigated in this fashion. It is experimentally shown that CO2 sequestration rates of 10-6 to 10-5 moles/sec per m2 of limestone surface area are achievable, with reaction densities on the order of 10-2 tonnes CO2 m-3day-1, highly dependent on limestone particle size, solution turbulence and flow, and CO2 concentration. Modeling shows that AWL would allow carbon storage in the ocean with significantly reduced impacts to seawater pH relative to direct CO2 disposal into the atmosphere or sea. The addition of AWL-derived alkalinity to the ocean may itself be beneficial for marine biota.
Identification of an Archean marine oxygen oasis
DOE Office of Scientific and Technical Information (OSTI.GOV)
Riding, Dr Robert E; Fralick, Dr Philip; Liang, Liyuan
2014-01-01
The early Earth was essentially anoxic. A number of indicators suggest the presence of oxygenic photosynthesis 2700 3000 million years (Ma) ago, but direct evidence for molecular oxygen (O2) in seawater has remained elusive. Here we report rare earth element (REE) analyses of 2800 million year old shallowmarine limestones and deep-water iron-rich sediments at Steep Rock Lake, Canada. These show that the seawater from which extensive shallow-water limestones precipitated was oxygenated, whereas the adjacent deeper waters where iron-rich sediments formed were not. We propose that oxygen promoted limestone precipitation by oxidative removal of dissolved ferrous iron species, Fe(II), to insolublemore » Fe(III) oxyhydroxide, and estimate that at least 10.25 M oxygen concentration in seawater was required to accomplish this at Steep Rock. This agrees with the hypothesis that an ample supply of dissolved Fe(II) in Archean oceans would have hindered limestone formation. There is no direct evidence for the oxygen source at Steep Rock, but organic carbon isotope values and diverse stromatolites in the limestones suggest the presence of cyanobacteria. Our findings support the view that during the Archean significant oxygen levels first developed in protected nutrient-rich shallow marine habitats. They indicate that these environments were spatially restricted, transient, and promoted limestone precipitation. If Archean marine limestones in general reflect localized oxygenic removal of dissolved iron at the margins of otherwise anoxic iron-rich seas, then early oxygen oases are less elusive than has been assumed.« less
Treatment of highly polluted groundwater by novel iron removal process.
Sim, S J; Kang, C D; Lee, J W; Kim, W S
2001-01-01
The removal of ferrous iron (Fe(II)) in groundwater has been generally achieved by simple aeration, or the addition of an oxidizing agent. Aeration has been shown to be very efficient in insolubilization ferrous iron at a pH level greater than 6.5. In this study, pH was maintained over 6.5 using limestone granules under constant aeration to oxidize ferrous iron in groundwater in a limestone packed column. A sedimentation unit coupled with a membrane filtration was also developed to precipitate and filtrate the oxidized ferric compound simultaneously. Several bench-scale studies, including the effects of the limestone granule sizes, amounts and hydraulic retention time on iron removal in the limestone packed column were investigated. It was found that 550 g/L of the 7-8 mesh size limestone granules, and 20 min of hydraulic retention time in the limestone packed column, were necessary for the sufficient oxidation of 40 mg/L of iron(II) in groundwater. Long-term operation was successfully achieved in contaminated waters by removing the iron deposits on the surface of the limestone granule by continuous aeration from the bottom of the column. Periodic reverse flow helped to remove caking and fouling of membrane surface caused by the continuous filtration. Recycling of the treated water from the membrane right after reverse flow operation made possible an admissible limit of iron concentration of the treated water for drinking. The pilot-scale process was constructed and has been tested in the rural area of Korea.
Oxic limestone drains for treatment of dilute, acidic mine drainage
Cravotta, Charles A.
1998-01-01
Limestone treatment systems can be effective for remediation of acidic mine drainage (AMD) that contains moderate concentrations of dissolved O2 , Fe3+ , or A13+ (1‐5 mg‐L‐1 ). Samples of water and limestone were collected periodically for 1 year at inflow, outflow, and intermediate points within underground, oxic limestone drains (OLDs) in Pennsylvania to evaluate the transport of dissolved metals and the effect of pH and Fe‐ and Al‐hydrolysis products on the rate of limestone dissolution. The influent was acidic and relatively dilute (pH <4; acidity < 90 mg‐L‐1 ) but contained 1‐4 mg‐L‐1 Of O2 , Fe3+ , A13+ , and Mn2+ . The total retention time in the OLDs ranged from 1.0 to 3.1 hours. Effluent remained oxic (02 >1 mg‐L‐1 ) but was near neutral (pH = 6.2‐7.0); Fe and Al decreased to less than 5% of influent concentrations. As pH increased near the inflow, hydrous Fe and Al oxides precipitated in the OLDs. The hydrous oxides, nominally Fe(OH)3 and AI(OH)3, were visible as loosely bound, orange‐yellow coatings on limestone near the inflow. As time elapsed, Fe(OH)3 and AI(OH)3 particles were transported downflow. During the first 6 months of the experiment, Mn 2+ was transported conservatively through the OLDs; however, during the second 6 months, concentrations of Mn in effluent decreased by about 50% relative to influent. The accumulation of hydrous oxides and elevated pH (>5) in the downflow part of the OLDs promoted sorption and coprecipitation of Mn as indicated by its enrichment relative to Fe in hydrous‐oxide particles and coatings on limestone. Despite thick (~1 mm) hydrous‐oxide coatings on limestone near the inflow, CaCO3 dissolution was more rapid near the inflow than at downflow points within the OLD where the limestone was not coated. The rate of limestone dissolution decreased with increased residence time, pH, and concentrations of Ca2+ and HCO3‐ and decreased PCO2. The following overall reaction shows alkalinity as an ultimate product of the iron hydrolysis reaction in an OLD:Fe2+ + 0.25 O2 +CaCO3 + 2.5 H2O --> Fe(OH)3 + 2 Ca2+ + 2 HCO3-where 2 moles of CaCO3 dissolve for each mole of Fe(OH)3 produced. Hence, in an OLD, rapidly dissolving limestone surfaces are not stable substrates for Fe(OH)3 attachment and armoring. Because overall efficiency is increased by combining neutralization and hydrolysis reactions, an OLD followed by a settling pond requires less land area than needed for a two‐stage treatment system consisting of an anoxic limestone drain an oxidation‐settling pond or wetland. To facilitate removal of hydrous‐oxide sludge, a perforated‐pipe subdrain can be installed within an OLD.
NASA Astrophysics Data System (ADS)
Solak, Cemile; Taslı, Kemal; Koç, Hayati
2017-04-01
The Upper Cretaceous succession outcropping in the area known as Anamas-Akseki Autochton or Geyikdaǧı Unit, which is situated western part of the Central Taurides, consists of approximately 500 m thick purely platform carbonate sediments. Integrated microfacies/facies studies and biostratigraphic analysis of the Kuyucak stratigraphic section provided to recognise depositional settings and benthic foraminiferal biozones. The Upper Cretaceous begins with Cenomanian limestones intercalated with limestone breccias (Unit 1) containing mainly Pseudorhapydionina dubia, Cuneolina pavonia, Nezzazata simplex (Association 1) and unconformably overlies the Lower Cretaceous (Barremian-Aptian) limestones with Vercorsella laurentii, Praechrysalidina infracretacea and Salpingoporella hasi. The Cenomanian limestones include benthic foraminiferal packstone/wackestone, peloidal packstone/wackestone and mudstone microfacies deposited restricted platform conditions. Intercalations of emersion breccias suggest sporadic subaerial exposure of the platform. The Cenomanian succession are truncated by an unconformity characterised by locale bauxite infills. Immediately above the unconformable surface, dolomitic limestones and rudistid limestones (Unit 2) are assigned to the upper Campanian based on the benthic foraminiferal assemblage (Association 2) comprising mainly Murciella cuvillieri, Pseudocyclammina sphaeroidea, Accordiella conica, Scandonea samnitica and Fleuryana adriatica. The upper Campanian limestones composed of dominantly benthic foraminiferal packstone/wackestone microfacies deposited in shallow water environments with low water energy, subjected to restriction in water circulation, The following limestones of the Unit 2 is characterised by sporadic intercalation of "open shelf" Orbitoides, Omphalocyclus, Siderolites assemblage (Association 3), assigned to the Maastrichtian, in addition to pre-existing "restricted platform" species. Pseudedomia hekimhanensis and Helenocyclina beotica are occasionally accompanied this association. In the upper half of this biozone, the Rhapydionina liburnica subzone (Association 3b) is distinguished by the first occurences of Valvulina aff. triangularis, Loftusia minor as well as the nominal species. The Maastrichtian limestones with sporadically open marine influence consist mostly of bioclastic/microbioclastic (rudist-bearing) wackestone/packstone/grainstone, benthic foraminiferal packstone/wackestone with rudist fragments and peloidal/intraclastic packstone/wackestone microfacies deposited in shallow subtidal-subtidal (lagoonal) environments characterised by different hydrodynamic regimes (low to high energy). The Upper Cretaceous succession passes upwardly into 70 meters thick limestones and clayey limestones (Unit 3) which do not contain rudists and pre-existing foraminiferal assemblage with one exception Valvulina aff. triangularis. Variable amounts of ostracoda, Discorbidae, Miliolidae, dasycladacean algae and Stomatorbina sp. (Association 4) occur into muddy-rich microfacies suggesting restricted conditions with low water energy. A probable Paleocene age is proposed for the Unit 3 based on the occurence of Valvulina aff. triangularis and Stomatorbina sp. which were previously recorded from Paleocene of peri-Tethian platforms. The Upper Cretaceous-Paleocene(?) platform carbonate succession is unconformably overlain by conglomerate, limestone with Nummulites and siliciclastic sediments of the Eocene age. We thank to the Scientific and Technological Research Council of Turkey (TUBITAK) for a financial support with project no:115Y130.
NASA Astrophysics Data System (ADS)
Frouz, Jan
2015-04-01
Soil biota community (macrofauna, nematodes and microbial community studied by PLFA) was studied together with soil development in post-mining chronosequences along climatic gradient in the USA, covering hardwood forest (TN, IN), tallgrass prairie (IL), or shortgrass prairie (WY). Post mining sites reclaimed according recent regulation which includes topsoil application and vegetation establishment were compared to local climax. Both young and old restoration sites were much closer to the climax condition in shortgrass prairie than in the other sites. The shortgrass prairie soil community contained abundant root-feeding organisms, which may establish quicker than the saprophagous fauna that was abundant at the other sites. Absence of saprophagous groups, and especially earthworms, resulted in the absence of bioturbation in shortgrass prairie sites while in chronosequences other than the one in shortgrass prairie, bioturbation played an important role in topsoil formation resulting in more complex soil profile development compare to shortgrass prairie. This may contribute to faster recovery communities in shortgrass prairie in comparison with tallgrass prairie and forest as At the same time sites that were reclaimed according recent regulation (topsoil application and vegetation establishment) were compare to unreclaimed sites both about 30 years old in TN IL and WY. It TN soil and soil biota seems to approach fasted to climax in unreclaimed than reclaimed sites. In IL this differences between reclaimed and unreclaimed sites was not so clear. While in WY reclaimed sites seems to approach to climax community fasted than unreclaimed one. This suggests that effect of reclamation vary along climatic gradient. In drier sites, formation of soil matrix from parent material is probably much slower and topsoil application speed up soil community recovery substantially while this effect is less pronounces in more wet sites, where soil compaction due to restoration may in some cases even slow recovery.
Jamro, Ghulam Murtaza; Chang, Scott X; Naeth, M Anne; Duan, Min; House, Jason
2015-10-01
Open-pit mining activities in the oil sands region of Alberta, Canada, create disturbed lands that, by law, must be reclaimed to a land capability equivalent to that existed before the disturbance. Re-establishment of forest cover will be affected by the production and turnover rate of fine roots. However, the relationship between fine root dynamics and tree growth has not been studied in reclaimed oil sands sites. Fine root properties (root length density, mean surface area, total root biomass, and rates of root production, turnover, and decomposition) were assessed from May to October 2011 and 2012 using sequential coring and ingrowth core methods in lodgepole pine (Pinus contorta Dougl.) and white spruce (Picea glauca (Moench.) Voss) stands. The pine and spruce stands were planted on peat mineral soil mix placed over tailings sand and overburden substrates, respectively, in reclaimed oil sands sites in Alberta. We selected stands that form a productivity gradient (low, medium, and high productivities) of each tree species based on differences in tree height and diameter at breast height (DBH) increments. In lodgepole pine stands, fine root length density and fine root production, and turnover rates were in the order of high > medium > low productivity sites and were positively correlated with tree height and DBH and negatively correlated with soil salinity (P < 0.05). In white spruce stands, fine root surface area was the only parameter that increased along the productivity gradient and was negatively correlated with soil compaction. In conclusion, fine root dynamics along the stand productivity gradients were closely linked to stand productivity and were affected by limiting soil properties related to the specific substrate used for reconstructing the reclaimed soil. Understanding the impact of soil properties on fine root dynamics and overall stand productivity will help improve land reclamation outcomes.
Zhu, Yong-heng; Li, Ke-zhong; Zhang, Heng; Han, Fei; Zhou, Ju-hua; Gao, Ting-ting
2015-02-01
A survey was carried out to investigate soil nematode communities in the plant associations of gramineae (Arthraxon lanceolatus, AL; Imperata cylindrica, IC) and leguminosae (Glycine soja, GS) in reclaimed land of copper-mine-tailings and in the plant associations of gramineae (Digitaria chrysoblephara, DC-CK) of peripheral control in Fenghuang Mountain, Tongling City. A total of 1277 nematodes were extracted and sorted into 51 genera. The average individual density of the nematodes was 590 individuals · 100 g(-1) dry soil. In order to analyze the distribution character- istics of soil nematode communities in reclaimed land of copper-mine-tailings, Shannon community diversity index and soil food web structure indices were applied in the research. The results showed that the total number of nematode genus and the Shannon community diversity index of soil nematode in the three plant associations of AL, IC and GS were less than that in the plant associations of DC-CK. Compared with the ecological indices of soil nematode communities among the different plant associations in reclaimed land of copper-mine-tailings and peripheral natural habitat, we found that the structure of soil food web in the plant associations of GS was more mature, with bacterial decomposition being dominant in the soil organic matter decomposition, and that the soil ecosystem in the plant associations of GS was not stable with low interference. This indicated that the soil food web in the plant associations of leguminosae had a greater development potential to improve the ecological stability of the reclaimed land of copper-mine-tailings. On the other hand, the structure of soil food web in the plant associations of AL and IC were relatively stable in a structured state with fungal decomposition being dominant in the decomposition of soil organic matter. This indicated that the soil food web in the plant associations of gramineae was at a poor development level.
DOE Office of Scientific and Technical Information (OSTI.GOV)
Goreau, T.J.; Hilbertz, W.
Electrolysis of seawater is used to precipitate limestone on top of underwater steel structures to create growing artificial reefs to enhance coral growth, restore coral reef habitat, provide shelter for fish, shellfish, and other marine organisms, generate white sand for beach replenishment, and protect shore lines from wave erosion. Films and slides will be shown of existing structures in Jamaica, Panama, and the Maldives, and projects being developed in these and other locations will be evaluated. The method is unique because it creates the only artificial reef structures that generate the natural limestone substrate from which corals and coral reefsmore » are composed, speeding the settlement and growth of calcareous organisms, and attracting the full range of other reef organisms. The structures are self-repairing and grow stronger with age. Power sources utilized include batteries, battery chargers, photovoltaic panels, and windmills. The cost of seawalls and breakwaters produced by this method is less than one tenth that of conventional technology. Because the technology is readily scaled up to build breakwaters and artificial islands able to keep pace with rising sea level it is capable of playing an important role in protecting low lying coastal areas from the effects of global climate change.« less
Municipal water supplies in Lee County, Florida, 1974
O'Donnell, T. H.
1977-01-01
In 1974 the total pumpage for Lee County, Fla., municipal supplies reached 5,700 Mgal (million gallons annually), an increase of 54 percent over 1970 levels. Pumpage from individual sources included: Caloosahatchee River, 1,312 Mgal; water-table aquifer, 2,171 Mgal; the water-bearing zone in the Tamiami Formation, 340 Mgal; the water-bearing zone in the upper part of the Hawthorn Formation, 1,399 Mgal; the saline water zones in the lower part of the Hawthorn Formation and the Suwannee Limestone, 483 Mgal. Among the various sources, the water-table aquifer showed the greatest increase in municipal pumpage over 1970 levels (60 percent) while the saline zones in the lower part of the Hawthorn Formation and Suwannee Limestone showed the least (40 percent). Intensive pumpage from the water bearing zone in the upper part of the Hawthorn Formation has caused a progressive decline in water levels in wells tapping that zone. The quality of fresh ground water in areas unaffected by intrusion of saline water, generally meets all the recommended limits of the Environmental Protection Agency. The chemical treatment processes utilized by water plants in the county are generally effective in producing finished water that meets EPA preliminary drinking water standards. (Woodard-USGS)
Reducing Energy-Related CO2 Emissions Using Accelerated Limestone Weathering
DOE Office of Scientific and Technical Information (OSTI.GOV)
Rau, G H; Knauss, K G; Langer, W H
2004-04-27
Following earlier descriptions, the use and impacts of accelerated weathering of limestone AWL; reaction: CO{sub 2} + H{sub 2}O + CaCO{sub 3} {yields} Ca{sup 2+} + 2(HCO{sub 3}{sup -}) as a CO{sub 2} capture and sequestration method is further explored. Since ready access to the ocean is likely an essential requirement for AWL, it is shown that significant limestone resources are relatively close to a majority of CO{sub 2}-emitting power plants along the coastal US. Furthermore, waste fines, representing more than 20% of current US crushed limestone production (>10{sup 9} tonnes/yr), could be used in many instances as an inexpensivemore » or free source of AWL carbonate. With limestone transportation to coastal sites then as the dominant cost variable, CO{sub 2} sequestration (plus capture) costs of $3-$4/tonne are achievable in certain locations. While there is vastly more limestone and water on earth than that required for AWL to capture and sequester all fossil fuel CO{sub 2} production, the transportation cost of bringing limestone, seawater, and waste CO{sub 2} into contact likely limits the method's applicability to perhaps 10-20% of US point-source emissions. Using a bench-scale laboratory reactor, it is shown that CO{sub 2} sequestration rates of 10{sup -6} to 10{sup -5} moles/sec per m{sup 2} of limestone surface area are readily achievable using seawater. This translates into reaction densities as high as 2 x 10{sup -2} tonnes CO{sub 2} m{sup -3}day{sup -1}, highly dependent on limestone particle size, solution turbulence and flow, and CO{sub 2} concentration. Modeling of AWL end-solution disposal in the ocean shows significantly reduced effects on ocean pH and carbonate chemistry relative to those caused by direct CO{sub 2} disposal into the atmosphere or ocean. In fact the increase in ocean Ca{sup 2+} and bicarbonate offered by AWL should significantly enhance the growth of corals and other marine calcifiers whose health is currently being threatened by anthropogenic CO{sub 2} invasion and pH reduction in the ocean.« less
NASA Astrophysics Data System (ADS)
Korpás, L.; Lantos, M.; Nagymarosy, A.
1999-01-01
Sedimentological, biostratigraphic and magnetostratigraphic studies were carried out on five Late Eocene-Early Oligocene profiles in the Buda Hills, Hungary. The Szépvölgy Limestone Formation accumulated on the pre-Eocene basement. Basal strata of the limestone consist of a thin conglomerate followed by a coralgal limestone. The overlying limestone contains abundant Nummulites, Discocyclina. The contact between these two members is sharp. The Szépvölgy Limestone body, covering 60-65 km 2, is considered a carbonate bank. Above the limestone, the siliciclastic slope deposits of the pelagic and turbiditic Buda Marl, and the euxinic Tard Clay accumulated. A huge multiphase hydrothermal cave system developed in the Szépvölgy Limestone resulting in a long-term composite palaeokarstic evolution lasting from the Late Eocene to the Quaternary. The first palaeokarst phase during the Late Eocene is represented by two generations of early marine cavity filling sediments of caymanite-type, deposited at sea-level. The earlier, carbonate infilling is conformable while the younger, siliciclastic one is disconformable with the bedding of the host rock. Bio- and magnetostratigraphic studies indicate that deposition of the caymanites-bearing palaeokarst host sequence started in the Late Eocene, during Chron C15r (35.3 Ma) and terminated in the Early Oligocene during Chron C13n (33 Ma). Two marker horizons are present, the first is between the Szépvölgy Limestone and Buda Marl at ˜34.6 Ma, and the second horizon is between the Buda Marl and the Tard Clay at 33.5 Ma. The Szépvölgy Limestone, deposited on a mobile shelf, represents a deepening upward sequence, interrupted by two lowstand events. They can be correlated with the PHd event of Keller et al., 1987 (Global distribution of late Palaeogene hiatuses. Geology 15, 199-203) and resulted in marine palaeokarstification. The carbonate shelf with the infillings drowned at 34.6 Ma. The caymanites accumulated at about 35.2-35.0 Ma and represent short-term palaeokarstic events. Their deposition record was estimated in several thousand years.
NASA Astrophysics Data System (ADS)
Cabaleri, Nora G.; Benavente, Cecilia A.
2013-02-01
The Las Chacritas Member is the lower part of the Cañadón Asfalto Formation (Jurassic). The unit is a completely continental limestone succession with volcanic contributions that were deposited during the development of the Cañadón Asfalto Rift Basin (Chubut province, Patagonia, Argentina). A detailed sedimentological analysis was performed in the Fossati depocenter to determine the paleoenvironments that developed in the context of this rift. The Las Chacritas Member represents a carbonate paleolake system with ramp-shaped margins associated with wetlands that were eventually affected by subaerial exposure and pedogenesis. This process is represented by three main subenvironments: a) a lacustrine setting sensu stricto (lacustrine limestone facies association), represented by Mudstones/Wackestones containing porifera spicules (F1), Intraclastic packstones (F6) and Tabular stromatolites (F10) in which deposition and diagenesis were entirely subaqueous; b) a palustrine setting (palustrine limestone facies association) containing Microbial Mudstones (F2), Intraclastic sandy packstone with ostracode remains (F3), Oncolitic packstone (F5), Brecciated limestone (F7) and Nodular-Mottled limestone (F8) representing shallow marginal areas affected by groundwater fluctuations and minor subaerial exposure; and c) a pedogenic paleoenvironment (pedogenic limestone facies association) including Intraclastic limestone (F4) and Packstones containing Microcodium (F9) facies displaying the major features of subaerial exposure, pedogenic diagenesis and the development of paleosols. The fluvial-palustrine-lacustrine succession shows a general shallow upward trend in which contraction-expansion cycles are represented (delimited by exposure and surface erosion). The variations in the successive formations reflect the responses to fluctuations in a combination of two major controls, the tectonic and local climatic variables. The predominance of the palustrine facies associations was determined by its accommodation space as well as the local climate conditions. The variations in the lacustrine limestone facies associations reflect differential patterns of subsidence within the sub-basin. The diagnostic features of the palustrine limestone facies associations (organic matter (OM) content, microinvertebrate fauna, abundant mud cracks, brecciation, presence of evaporitic minerals) frame the sub-basin in a climatic context intermediate between arid and subhumid conditions.
Effects of sorbent attrition on utilization. Final report, June 1, 1990--June 30, 1991
DOE Office of Scientific and Technical Information (OSTI.GOV)
Keener, T.C.; Khang, Soon-Jai; Lee, S.K.
1992-03-01
Attrition of surface product levers of sulfite/sulfate may be the key to substantially increasing sorbent utilization in new dry scrubbing processes. This conclusion has been reached from research results obtained from new gas/solid contacting methods such as the Circulating Fluidized Bed Absorber and the Limestone Emission Control method. An additional savings may be reduced by the use of large initial sorbent, particle sizes which greatly reduces the cost of grinding and sorbent preparation. The objectives of project 1.7 were then to study attrition of sorbent particles in a systematic fashion in order to determine how to use attrition to increasemore » sorbent utilization. This was to be carried out by the construction of a bench scale fluidized bed where a series of experiments were to be conducted to measure attrition of lime and limestone samples. This has been accomplished and the project proceeded as anticipated. The results indicate that attrition differs for wet and dry conditions for certain sorbents and that these differences are substantial. Under dry conditions, the results of attrition tests on carefully characterized lime samples indicate that mechanical abrasion is the primary attrition mechanism. The rate of attrition is seen to be similar to a first order chemical reaction where the bed mass (or total surface area) is analagous to reactant concentration. A model for mechanical attrition is presented which expresses the rate constant in an Arrhenius type form proportional to a pseudo attrition activation energy and excess gas energy above a minimum level. The value of this pseudo attrition activation energy for lime has been found to be 106 KJ/KG. For the attrition of wetted lime particles in a fluidized bed. the attrition rate has been found to be directly related to the volumetric flow rate of injected water.« less
Geological applications of Nimbus radiation data in the Middle East
NASA Technical Reports Server (NTRS)
Allison, L. J.
1977-01-01
Large plateaus of Eocene limestone and exposed limestone escarpments, in Egypt and Saudi Arabia, respectively, were indicated by cool brightness temperatures recorded by the Nimbus-5 electrically scanning microwave radiometer (ESMR), over a 2-year period. Nubian sandstone, desert eolian sand, and igneous-metamorphic rock of the Pliocene, Miocene, Oligocene, and Cretaceous periods were differentiated from these limestone areas by warm T sub B values. These brightness temperature differences are a result of seasonal in-situ ground temperatures and differential emissivity of limestone and sand, sandstone and granite, whose dielectric constants are 6 to 8.9 and 2.9 and 4.2 to 5.3, respectively, at 19.35 GHz.
Devonian-Carboniferous boundary succession in Eastern Taurides, Turkey
NASA Astrophysics Data System (ADS)
Atakul-Özdemir, Ayşe; Altıner, Demir; Özkan-Altıner, Sevinç
2015-04-01
The succession covering the Devonian-Carboniferous boundary in Eastern Taurides comprises mainly limestones, shales and siltstones. The studied section starts at the base with bioturbated limestones alternating with shales and is followed upwards by platy limestones, and continues with the alternations of bioturbated and platy limestones. Towards the upper part of the succession the alternations of limestone, shales and siltstones reappear again and the top of the section is capped by quartz arenitic sandstone. The studied section spanning the Uppermost Devonian-Lower Carboniferous interval yields a not very abundant, but quite important assemblage of conodont taxa including species of Bispathodus, Polygnathus, Palmatolepis, Spathognathodus and Vogelgnathus. The uppermost Devonian part of the succession is characterized by the presence of Bispathodus costatus, Bispathodus aculeatus aculeatus, Polygnathus communis communis, Palmatolepis gracilis gracilis and Spathognathodus sp.. The Lower Carboniferous in the studied section is represented by the appearance of Polygnathus inornatus and Polygnathus communis communis. Based on the recovered conodont assemblages, Devonian-Carboniferous boundary in Eastern Turides has been determined by the appearance and disappearance of major conodont species.
NASA Astrophysics Data System (ADS)
El-Sorogy, Abdelbaset S.; Ismail, Abdelmoneim; Youssef, Mohamed; Nour, Hamdy
2016-12-01
The Campanian Hajajah Limestone Member of the Aruma Formation was formed during two regressive episodes. Each of them formed of three depositional facies, from base to top: 1) intra-shelf basin facies, made up of fossiliferous green shale and mudstone with ostracods and badly preserved foraminifers. 2) fore-reef facies, consists of hard, massive, marly coralline limestone. The upper part is rich with low divers, badly to moderate preserved, solitary and colonial corals, and, 3) back reef and near-shore facies, consists of fossiliferous sandy dolomitized, bioturbated limestone with abundant reworked corals, bivalves, gastropods, and aggregate grains. On the basis of field observations, micro-and macrofossils and microfacies analysis, the Hajajah Limestone Member was deposited in distal marine settings below storm wave base in a low-energy environment changed upward to fore-reef framework in an open marine environment with moderate to high energy conditions and terminated with shallow marine facies with accumulation of skeletal grains by storms during regression.
NASA Astrophysics Data System (ADS)
Bhonde, Uday; Desai, Bhawanisingh G.
2011-08-01
The Okha Shell Limestone Member of Chaya Formation is the coarse grained, shell rich deposit commonly recognized as the beach rocks. It has been age bracketed between Late Pleistocene and Holocene. Late Quaternary sea level changes have been studied with beach rocks along the Saurashtra coastal region. The present study has been carried out in the Okhamandal area of the Saurashtra peninsula especially on the Okha Shell Limestone Member as exposed at various locations along the coast from north to south. Temporal and spatial correlations of the observations have revealed three events in the Okha Shell Limestone Member of Chaya Formation that are correlated laterally. The events show depositional breaks represented by discontinuity surfaces, the taphofacies varieties and ichnological variations. The present study in the context of available geochrnological data of the region suggests a prominent depositional break representing low sea level stand (regression) during an Early Holocene during the deposition of Okha Shell Limestone Member.
CO2 mitigation via accelerated limestone weathering
Rau, Greg H.; Knauss, Kevin G.; Langer, William H.; Caldeira,
2004-01-01
We evaluate accelerated weathering of limestone (AWL: CO2 + CaCO3 + H2O=> Ca2+ + 2HCO3-) as a low-tech, inexpensive, high-capacity, environmentally-friendly CO2 capture and sequestration technology. With access to seawater and limestone being essential to this approach, significant limestone resources are close to most CO2-emitting power plants along the coastal US. Waste fines, representing more than 20% of current US crushed limestone production (>109 tonnes/yr), could be used as an inexpensive source of AWL carbonate. Under such circumstances CO2 mitigation cost could be as low as $3-$4/tonne. More broadly, 10-20% of US point-source CO2 emissions could be treated at $20-$30/tonne CO2. AWL end-solution disposal in the ocean would significantly reduce effects on ocean pH and carbonate chemistry relative to those caused by direct atmospheric or ocean CO2 disposal. Indeed, the increase in ocean Ca2+ and bicarbonate offered by AWL should enhance growth of corals and other calcifying marine organisms.
Geological applications of Nimbus radiation data in Middle East
NASA Technical Reports Server (NTRS)
Allison, L. J.
1976-01-01
Plateaus of Eocene limestone and exposed limestone escarpments, in Egypt and Saudi Arabia respectively, were indicated by cool brightness temperatures T sub B (less than 240 to 265 K) by the Nimbus 5 electrically scanning microwave radiometer (ESMR) over a 2-year period. Nubian sandstone, desert eolian sand and igneous metamorphic rocks were differentiated from these limestone areas by warm T sub B values (more than 265 to 300 K). Cool T sub B values in the form of a V were found over broad areas of the Nile Valley and in the western desert of central Egypt. Similar cool T sub B values were shown over limestone-dolomitic hills of the interior Homocline and the Hadramawt plateau of Saudi Arabia. Nimbus 5 and 6 ESMR T sub B values selectively identified intermediate dense rock types (limestone versus sandstone/granite) in the Lake Nasser region whose thermal inertia ranged from 0.035 to 0.06 cal cm to minus 2 C sec 1/2 to minus one half.
NASA Astrophysics Data System (ADS)
Ross, M.; Knab, L.
1984-07-01
The selection, procurement, and description of the Salem Limestone to be used in field exposure tests to assess the effects of acid rain on building stone are described. The rationale for choosing Salem Limestone is given and a brief geological description of the stone is provided. Preparation of the stone samples for field exposure, including cutting, surface finishing and labelling is presented.
Sedimentology and diagenesis of Miocene Lirio Limestone, Isla de Mona, Puerto Rico
DOE Office of Scientific and Technical Information (OSTI.GOV)
Ruiz, H.; Gonzalez, L.A.; Budd, A.F.
1991-03-01
Isla de Mona is a carbonate plateau, 50 mi west of Puerto Rico. The island lies on the southern portion of the Mona Platform. It is composed mostly of two Miocene carbonate units: Isla de Mona Dolomite overlain by Lirio Limestone. The Lirio Limestone was deposited on a sloping erosional surface over the Isla de Mona Dolomite. The Miocene Lirio Limestone consists mostly of backreef sands (packstones) with a reefal sequence (boundstones and grainstones) present in the southwestern portion of the island. The reefal sequence is made up mostly of Stylophora, Porites, and Millepora. Thin, discreet pockets of carbonate mud,more » rich in planktonic foraminifera and radiolarians and mixed with shallow benthic fauna/flora (foraminifera, echinoderms, red algae, and corals) interpreted as storm deposits, are found throughout the unit. An extensive reefal zone can be inferred to be present throughout the southwestern to southern portions of the Mona Platform. The Lirio Limestone is heavily karstified and is riddled with sinkholes on the plateau surfaces and caves around the periphery of the island. Caves are exposed around the periphery of the island, radiating from a depression in the central portions of the Lirio Limestone, near contacts with the Isla de Mona Dolomite, are partially dolomitized. The southwestern outcrops exhibit partial dolomitization throughout. The distribution of sinkholes, seaward caverns, and partial dolomitization of the lowermost Lirio Limestone suggests diagenetic modifications by meteoric fluids in central exposed portions of the island and by marine-meteoric fluids in the lowermost portions of the phreatic lens.« less
NASA Astrophysics Data System (ADS)
Mount, Gregory J.; Comas, Xavier
2014-10-01
Subsurface water flow in South Florida is largely controlled by the heterogeneous nature of the karst limestone in the Biscayne aquifer and its upper formation, the Miami Limestone. These heterogeneities are amplified by dissolution structures that induce changes in the aquifer's material and physical properties (i.e., porosity and dielectric permittivity) and create preferential flow paths. Understanding such patterns are critical for the development of realistic groundwater flow models, particularly in the Everglades, where restoration of hydrological conditions is intended. In this work, we used noninvasive ground penetrating radar (GPR) to estimate the spatial variability in porosity and the dielectric permittivity of the solid phase of the limestone at centimeter-scale resolution to evaluate the potential for field-based GPR studies. A laboratory setup that included high-frequency GPR measurements under completely unsaturated and saturated conditions was used to estimate changes in electromagnetic wave velocity through Miami Limestone samples. The Complex Refractive Index Model was used to derive estimates of porosity and dielectric permittivity of the solid phase of the limestone. Porosity estimates of the samples ranged between 45.2 and 66.0% and showed good correspondence with estimates of porosity using analytical and digital image techniques. Solid dielectric permittivity values ranged between 7.0 and 13.0. This study shows the ability of GPR to image the spatial variability of porosity and dielectric permittivity in the Miami Limestone and shows potential for expanding these results to larger scales and other karst aquifers.
Sun, Jiaji; Chen, Lei; Rene, Eldon R; Hu, Qian; Ma, Weifang; Shen, Zhenyao
2018-07-01
The main aim of this study was to remove nitrogen compounds from reclaimed water and reuse the water in semi-arid riverine lake systems. In order to assess the nitrogen removal efficiencies in different natural environments, laboratory scale column experiments were performed using sterilized soil (SS), silty clay (SC), soil with submerged plant (SSP) and biochar amendment soil (BCS). The initial concentration of NO 3 - -N and the flow rate was maintained constant at 15 mg L -1 and 0.6 ± 0.1 m d -1 , respectively. Among the tested columns, both SSP and BCS were able to achieve NO 3 - -N levels <0.2 mg L -1 in the treated reclaimed water. The results from bacterial community structure analysis, using 454 pyrosequencing of 16s rRNA genes, showed that the dominant denitrifier was Bacillus at the genera level. Copyright © 2018 Elsevier Ltd. All rights reserved.
DOE Office of Scientific and Technical Information (OSTI.GOV)
Not Available
1994-01-01
These hearings investigate the RECLAIM program in Southern California which would use market forces to reduce the emissions from large polluters. The program applies only to nitrogen oxides and sulfur dioxide. Questions exist about whether the long-term goals are realistic; fairness both from the standpoint of the emissions allocation and for the potential for packing pollution into minority and lower-income communities; and whether or not RECLAIM meets the requirements of the Clean Air Act. Representatives of several interested parties from California (including S. Coast Metal Coalition; S. Cal. Edison; Ca. Air resources Board; S. Coast Air Quality Management District; S.more » Ca. Gas) testify along with Director of the Center for Energy Efficiency and Renewable technologies; Western States Petroleum Ass., regulatory Flexibility Group; Coalition for Clean Air.« less
Stand characteristics and productivity potential of Indiana surface mines reclaimed under SMCRA
DOE Office of Scientific and Technical Information (OSTI.GOV)
Groninger, J.W.; Fillmore, S.D.; Rathfon, R.A.
The Surface Mining Control and Reclamation Act of 1977 (SMCRA) addresses a wide range of environmental concerns. However, its impacts on forest stand development and productive potential have only recently been investigated. We surveyed the vegetation and forest productivity on 22 surface mine sites throughout the coal-bearing region of Indiana that were reclaimed to forest cover under the provisions of SMCRA 7-14 years prior to sampling. Black locust (Robinia pseudoacacia) and green ash (Fraxinus pennsylvanica) were the most widely occurring tree species. Tall fescue and goldenrod were the most widely occurring nonarborescent species. Median site index (base age 50 formore » black oak) was 30 ft. Although satisfying forest cover stocking requirements for bond release, these reclaimed surface mines almost always displayed a level of productivity far below those of native forests typical of this region. Reclamation techniques differing from those used on these study sites are needed to restore forest productivity to surface-mined lands while still complying with SMCRA.« less
NASA Astrophysics Data System (ADS)
Cui, Xiao; Yuqing, Zhao; Cui, Jiantao; Zheng, Qian; Bo, Wang
2018-02-01
The following paper reported and discussed a nitrite ion optical sensing platform based on a core-shell structure, using superamagnetic nanoparticles as the core, a silica molecular sieve MCM-41 as the shell and two rhodamine derivatives as probe, respectively. This superamagnetic core made this sensing platform reclaimable after finishing nitrite ion sensing procedure. This sensing platform was carefully characterized by means of electron microscopy images, porous structure analysis, magnetic response, IR spectra and thermal stability analysis. Detailed analysis suggested that the emission of these composite samples was quenchable by nitrite ion, showing emission turn off effect. A static sensing mechanism based on an additive reaction between chemosensors and nitrite ion was proposed. These composite samples followed Demas quenching equation against different nitrite ion concentrations. Limit of detection value was obtained as low as 0.4 μM. It was found that, after being quenched by nitrite ion, these composite samples could be reclaimed and recovered by sulphamic acid, confirming their recyclability.
Optimization and thermoeconomics research of a large reclaimed water source heat pump system.
Zhang, Zi-ping; Du, Fang-hui
2013-01-01
This work describes a large reclaimed water source heat pump system (RWSHPS) and elaborates on the composition of the system and its design principles. According to the characteristics of the reclaimed water and taking into account the initial investment, the project is divided into two stages: the first stage adopts distributed heat pump heating system and the second adopts the combination of centralized and decentralized systems. We analyze the heating capacity of the RWSHPS, when the phase II project is completed, the system can provide hydronic heating water with the supply and return water temperature of 55°C/15°C and meet the hydronic heating demand of 8 million square meters of residential buildings. We make a thermal economics analysis by using Thermal Economics theory on RWSHPS and gas boiler system, it is known that the RWSHPS has more advantages, compared with the gas boiler heating system; both its thermal efficiency and economic efficiency are relatively high. It provides a reference for future applications of the RWSHPS.
Reinterpretation of the peninsular Florida oligocene: An integrated stratigraphic approach
Brewster-Wingard, G. L.; Scott, T.M.; Edwards, L.E.; Weedman, S.D.; Simmons, K.R.
1997-01-01
A very thick (> 300 m) nearly continuous Oligocene section exists in southern peninsular Florida, as revealed by lithostratigraphic, biostratigraphic (mollusks and dinocysts), chronostratigraphic (Sr isotopes) and petrographic analyses of twelve cores and two quarries. The Oligocene deposits in the subsurface of southern Florida are the thickest documented in the southeastern U.S., and they also may represent the most complete record of Oligocene deposition in this region. No major unconformities within the Oligocene section are detected in the southern portion of the peninsula; hiatuses at the Eocene-Oligocene boundary, the early Oligocene-late Oligocene boundary, and the late Oligocene-Miocene boundary, are of limited duration if they exist at all. No significant disconformity is recognized between the Suwannee Limestone and the Arcadia Formation in southern Florida. However, on the east coast of Florida a hiatus of more than 12 m.y., spanning from at least the middle of the early Oligocene to early Miocene is present. The Suwannee Limestone was deposited during the early Oligocene. The top of the Suwannee Limestone appears to be diachronous across the platform. The 'Suwannee' Limestone, previously identified incorrectly as a late Oligocene unit, is herein documented to be early Oligocene and is encompassed in the lower Oligocene Suwannee Limestone. An unnamed limestone, found on the east coast of the peninsula is, at least in part, correlative with the Suwannee Limestone. The Arcadia Formation, basal Hawthorn Group, accounts for a large portion of the Oligocene deposition in southern Florida, spanning the interval from the middle of the early Oligocene to at least the early Miocene. Comparisons of the depositional patterns, and the distribution of dolomite and phosphate within the Suwannee Limestone and the Arcadia Formation, suggest fluctuating sea levels and that the paleo-Gulf Stream played a role in determining the nature and extent of Oligocene deposition in peninsular Florida.
Use of nanotomographic images for structure analysis of carbonate rocks
DOE Office of Scientific and Technical Information (OSTI.GOV)
Nagata, Rodrigo; Appoloni, Carlos Roberto
Carbonate rocks store more than 50% of world's petroleum. These rocks' structures are highly complex and vary depending on many factors regarding their formation, e.g., lithification and diagenesis. In order to perform an effective extraction of petroleum it is necessary to know petrophysical parameters, such as total porosity, pore size and permeability of the reservoir rocks. Carbonate rocks usually have a range of pore sizes that goes from nanometers to meters or even dozen of meters. The nanopores and micropores might play an important role in the pores connectivity of carbonate rocks. X-ray computed tomography (CT) has been widely usedmore » to analyze petrophysical parameters in recent years. This technique has the capability to generate 2D images of the samples' inner structure and also allows the 3D reconstruction of the actual analyzed volume. CT is a powerful technique, but its results depend on the spatial resolution of the generated image. Spatial resolution is a measurement parameter that indicates the smallest object that can be detected. There are great difficulties to generate images with nanoscale resolution (nanotomographic images). In this work three carbonate rocks, one dolomite and two limestones (that will be called limestone A and limestone B) were analyzed by nanotomography. The measurements were performed with the SkyScan2011 nanotomograph, operated at 60 kV and 200 μA to measure the dolomite sample and 40 kV and 200 μA to measure the limestone samples. Each sample was measured with a given spatial resolution (270 nm for the dolomite sample, 360 nm for limestone A and 450 nm for limestone B). The achieved results for total porosity were: 3.09 % for dolomite, 0.65% for limestone A and 3.74% for limestone B. This paper reports the difficulties to acquire nanotomographic images and further analysis about the samples' pore sizes.« less
NASA Astrophysics Data System (ADS)
Xueyan, L.; Gao, B.; Sun, Y.; Wu, J.
2017-12-01
Perfluorooctanoic acid (PFOA) has been used in a wide variety of industrial and consumer product applications. PFOA has been detected around the world at ng/L to μg/L levels in groundwater, and at ng/g levels in soil.The physicochemical properties of porous media were proven to play pivotal roles in determining the transport behavior of various pollutants. It is anticipated that physicochemical properties of porous media will strongly influence the transport behavior of PFOA. In addition, previous investigations have revealed that input concentration significantly influence the transport behavior of nanoparticles and antibiotics. Thus, this study was designed experimentally and fundamentally to gain insight into transport and retention of PFOA in various porous medias at different input concentrations, solution IS and cation type. Unlike in quartz sand porous media, the BTCs in limestone porous media exhibited increasing retention rate and high degree of tailing in limestone porous media. Results showed that higher relative retention occurred in limestone porous media than in quartz sand porous media under the same solution chemistry. This result was attributed to the less negative zeta-potentials, rougher surface and larger specific surface area, and the presence of hydroxyl groups and organic matters of limestone grains. Higher ionic strength and Ca2+ had little impact on the mobility of PFOA in quartz sand porous media, but significantly enhanced the retention of PFOA in limestone porous media. The difference is likely due to the compression of the electrical double layer, and the surface-charge neutralization and cation-bridging effect of Ca2+. Higher input concentration resulted in lower relative PFOA retention in limestone porous media, but the influence were insignificant in quartz sand porous media. This effect is likely because attachment sites in limestone responced to the variety of input concentration differently than quartz.
High sodium coal-firing experiences at Basin Electric Power Cooperative's Leland Olds Station
DOE Office of Scientific and Technical Information (OSTI.GOV)
Laning, V.R.; Bartle, M.L.
1982-12-01
This paper describes some of the efforts made at the Leland Olds Station to cope with the problems created from high sodium content coals. Such coals have historically presented superheater fouling problems for utilities; ash deposits from high sodium coals have a very high sintering strength and are very difficult to remove by conventional methods. It is reported that the addition of limestone in the pulverizer unit at Leland Olds and vermiculite ore in the cyclone unit has helped reduce the fouling characteristics of high sodium lignites in North Dakota at an affordable cost.
NASA Astrophysics Data System (ADS)
Schaffhauser, Maria; Krainer, Karl; Sanders, Diethard Gerald; Spötl, Christoph
2010-05-01
The Trogkofel massif in the Carnic Alps, Austria/Italy, consists of a succession up to 400 m thick of limestones deposited along a platform margin (Trogkofel Limestone; Artinskian). The top of the Trogkofel Limestone is erosively overlain by the Tarvis Breccia. Up-section, the Trogkofel Limestone consists of well-bedded shallow-water bioclastic limestones with intercalated mud mounds, overlain by thick-bedded to unbedded limestones (bioclastic grainstones, packstones, rudstones) and cementstone mounds rich in phylloid algae, Tubiphytes, bryozoans and Archaeolithoporella. In the cementstone mounds, bioclasts are coated by thick fringes and botryoids of fibrous calcite, and of calcite spar that probably represents calcitized aragonite. Primary and intrinsic pores are filled by microbialite, and/or by mudstone to bioclastic wackestone. Shallow-water bioclastic grainstones are cemented by isopachous fringes of fibrous calcite, or by sparry calcite. Throughout the succession, evidence for meteoric-vadose dissolution is present. The Trogkofel Limestone is riddled by palaeokarstic dykes and caverns filled by (a) isopachous cement fringes up to a few decimetres thick, and/or (b) by red, geopetally-laminated lime mudstone to bio-lithoclastic wackestone; geopetal laminasets locally display convolute bedding. Small dissolution cavities are filled by grey internal sediment, or by crystal silt. Brecciated internal sediments overlain by unbrecciated, geopetally-laminated infillings record deformation during or after deposition of the Trogkofel Limestone. Polyphase fractures cemented by calcite may cross-cut both internal sediments and host rock. In the Trogkofel Limestone, local dolomitization is common. Replacement dolomites show a wide range of shapes and fabrics, including: (a) fine-crystalline anhedral xenotopic fabric, (b) coarse-crystalline subhedral to euhedral, hypidiotopic to idiotopic fabric of turbid or optically zoned crystals, and (c) saddle dolomite as replacement and filling of fractures. Closely below the erosional surface at the top of the Trogkofel Limestone, the dolomite is characterized by vuggy porosity. The Tarvis Breccia, which represents coarse alluvial fan deposits, in turn, is thick-bedded, poorly sorted, typically clast-supported, and consists of angular lithoclasts embedded in a matrix of former lime mudstone. Both, matrix as well as lithoclasts, are dolomitized. Various types of cement (isopachous, botryoidal, microbialite, calcite spar), karstic cavity fills (isopachous cements, internal sediments), and replacement dolomites of the Trogkofel section, as well as of the Tarvis Breccia were analysed for their stable isotopic composition. δ18O and δ13C data produced so far allow to differentiate between replacement dolomites and saddle dolomite of the Trogkofel Limestone and the Tarvis Breccia. Saddle dolomite shows the most depleted oxygen isotope values, suggesting formation during relatively high temperatures. Carbon isotope values are invariably positive in all dolomite types indicating lacking influence of organic diagenesis on the alkalinity of the deep-burial pore water. Matrix dolomite from the Tarvis Breccia shows slightly positive δ18O values. Calcite cements show a wide range in δ18O values (ca. -1 to -7 permil VPDB), which overlaps the composition of unaltered brachiopod shells (ca. -3 permil VPDB). Oxygen isotope values of calcite cements reveal a trend towards depleted δ18O values. This trend is reflecting most likely increasing temperature.
Lu, Jian; Wu, Jun; Stoffella, Peter J; Wilson, P Chris
2015-01-01
The potential uptake and distribution of bisphenol A (BPA) and nonylphenol (NP) (from reclaimed irrigation water) in edible crops was investigated. BPA and NP were spiked into simulated reclaimed water at environmentally relevant concentrations. Two crops (lettuce, Lactuca sativa and tomato, Lycopersicon esculentum) were grown hydroponically in a greenhouse using the spiked irrigation water under two irrigation exposure scenarios (overhead foliar exposure and subsurface root exposure). BPA concentrations in tomato fruit were 26.6 ± 5.8 (root exposure) and 18.3 ± 3.5 (foliar exposure) μg kg(-1), while concentrations in lettuce leaves were 80.6 ± 23.1 (root exposure) and 128.9 ± 17.4 (foliar exposure) μg kg(-1). NP concentrations in tomato fruit were 46.1 ± 6.6 (root exposure) and 24.6 ± 6.4 (foliar exposure) μg kg(-1), while concentrations in lettuce leaves were 144.1 ± 9.2 (root exposure) and 195.0 ± 16.9 (foliar exposure) μg kg(-1). BPA was relatively mobile in lettuce plants regardless of exposure route. Limited mobility was observed for NP in both crops and BPA in tomatoes. The estimated daily intake of BPA and NP through consumption of vegetables irrigated with reclaimed water ranged from 8.9-62.9 to 11.9-95.1 μg, respectively, depending on the exposure route. Copyright © 2014 Elsevier B.V. All rights reserved.
Test results on re-use of reclaimed shower water: Summary. [space stations
NASA Technical Reports Server (NTRS)
Verostko, C. E.; Garcia, R.; Sauer, R.; Linton, A. T.; Elms, T.; Reysa, R. P.
1988-01-01
A microgravity whole body shower (WBS) and waste water recovery systems (WWRS) were evaluated in three separate closed loop tests. Following a protocol similar to that anticipated for the U.S. Space Station, test subjects showered in a prototype whole body shower. The WWRS processes evaluated during the test series were phase change and reverse osmosis (RO). A preprototype Thermoelectric Integrated Hollow Fiber Membrane Evaporation Subsystem phase change process was used for the initial test with chemical pretreatment of the shower water waste input. The second and third tests concentrated on RO technologies. The second test evaluated a dynamic RO membrane consisting of zirconium oxide polyacrylic acid (ZOPA) membranes deposited on the interior diameter of 316L porous stainless steel tubes while the final test employed a thin semipermeable RO membrane deposited on the interior surface of polysulfone hollow fibers. All reclaimed water was post-treated for purity using ion exchange and granular activated carbon beds immediately followed by microbial control treatment using both heat and iodine. The test hardware, controls exercised for whole body showering, types of soaps evaluated, shower subject response to reclaimed water showering, and shower water collection and chemical pretreatment (if required) for microbial control are described. The WWRS recovered water performance and the effectiveness of the reclaimed water post-treatment techniques used for maintaining water purity and microorganism control are compared. Results on chemical and microbial impurity content of the water samples obtained from various locations in the shower water reuse system are summarized.
Reuse of bituminous pavements: A mini-review of research, regulations and modelling.
Anthonissen, Joke; Van den Bergh, Wim; Braet, Johan
2017-04-01
Bituminous pavement can be recycled - even multiple times - by reusing it in new bituminous mixtures. If the mechanical properties of the binder get worse, this reclaimed asphalt is often used in the sub-structure of the road. Apparently, up till now, no end-of-life phase exists for the material. Actually, defining the end-of-life and the end-of-waste stage of a material is important for life cycle assessment modelling. Various standards and scientific studies on modelling life cycle assessment are known, but the crucial stages are not yet defined for reclaimed asphalt pavement. Unlike for iron, steel and aluminium scrap, at this moment, no legislative end-of-waste criteria for aggregates are formulated by the European Commission. More research is necessary in order to develop valuable end-of-life criteria for aggregates. This contribution is a mini-review article of the current regulations, standards and studies concerning end-of-life and end-of-waste of reclaimed asphalt pavement. The existing methodology in order to define end-of-waste criteria, a case study on aggregates and the argumentation used in finished legislative criteria are the basis to clarify some modelling issues for reclaimed asphalt material. Hence, this contribution elucidates the assignment of process environmental impacts to a life cycle stage as defined by EN15804, that is, end-of-life stage (C) and the supplementary information Module D with benefits and loads beyond the system boundary.
Permeability hysterisis of limestone during isotropic compression.
Selvadurai, A P S; Głowacki, A
2008-01-01
The evolution of permeability hysterisis in Indiana Limestone during application of isotropic confining pressures up to 60 MPa was measured by conducting one-dimensional constant flow rate tests. These tests were carried out either during monotonic application of the confining pressure or during loading-partial unloading cycles. Irreversible permeability changes occurred during both monotonic and repeated incremental compression of the limestone. Mathematical relationships are developed for describing the evolution of path-dependent permeability during isotropic compression.
Hanchar, Dorothea Withington
1989-01-01
Thirty-four observation wells were installed at 17 sites in the area of a hazardous-waste disposal site near Brentwood, in Williamson County, Tennessee. These wells were installed to supplement data collected from domestic wells in the area, to help define the geology of the study area and to determine the water levels. Both lithologic and geophysical logs were obtained for each well drilled to help define the formations encountered. Four limestone units, corresponding to the Bigby-Cannon limestone, the Hermitage Formation, the Carters Limestone (including the T-3 bentonite), and the Lebanon Limestone, were described from well cuttings and borehole geophysical logs. Water levels have been collected at both the shallow and deep wells at each site. (USGS)
Development of Policies, Institutions and Procedures for Water Reuse
NASA Astrophysics Data System (ADS)
Demouche, L.; Pfiefer, J.; Hanson, A.; Skaggs, R.
2009-12-01
In the arid, water scarce region of New Mexico and West Texas there is growing interest in the potential for water reuse to extend existing supplies and mitigate drought shortage impacts. There are no new sources of water in New Mexico, except reclaimed water. Communities and individuals are uncertain about and have many unanswered questions about polices, institutions involved (agencies), legal and regulatory requirements, and procedures governing water reuse. Issues to be addressed by this project include: the legal ability to reuse water, ownership of water rights, downstream or third party impacts, regulatory and procedural requirements, water quality concerns, state and local agency involvement, and cost effectiveness of water reuse compared to alternative sources. Presently, there is very little implementation or directives in New Mexico policy that addresses reuse, reclamation, or recycled water. The only regulations pertaining to reuse is New Mexico Environmental Department currently allows the use of reclaimed domestic wastewater for irrigation of golf courses and green spaces, which is listed in the Policy for the Above Ground Use of Reclaimed Domestic Wastewater (NMED, 2003). This document identifies the various reclaimed quality classifications that are required for specific applications and the permits required for application. This document does not identify or address policy applications on the distribution, ownership, or trading of reclaimed water. Even though reclaimed water reuse projects are currently being implemented in many cities in the U.S., mainly for commercial and municipal irrigation (golf courses and green space), its potential has not yet been exploited. A policy analysis matrix (PAM) is being designed to identify and examine the policy framework and consequences of non-policy implementation for decision makers and interest groups and assist them in understanding the consequences of policy actions and project outcomes if no laws or regulations are created. The clarity of definitions is critical in policy analysis. Good economic analysis is fascinating for economist, frustrating for noneconomist, and relevant for everyone because it focuses on linkages within an economy—on why one group’s actions influence others in the system. The water reuse PAM is being used to identify the legality of water reuse, ownership of water rights, downstream or third party impacts, regulatory and procedural requirements, water quality concerns, state and local agency involvement, and cost effectiveness of water reuse compared to alternative sources. This project hopes to identify everyone involved in water reuse policy and provide them with clarity about the issues to help in evaluating and making sound policy decisions.
Habitat manipulation influences northern bobwhite resource selection on a reclaimed surface mine
Brooke, Jarred M.; Peters, David C.; Unger, Ashley M.; Tanner, Evan P.; Harper, Craig A.; Keyser, Patrick D.; Clark, Joseph D.; Morgan, John J.
2015-01-01
More than 600,000 ha of mine land have been reclaimed in the eastern United States, providing large contiguous tracts of early successional vegetation that can be managed for northern bobwhite (Colinus virginianus). However, habitat quality on reclaimed mine land can be limited by extensive coverage of non-native invasive species, which are commonly planted during reclamation. We used discrete-choice analysis to investigate bobwhite resource selection throughout the year on Peabody Wildlife Management Area, a 3,330-ha reclaimed surface mine in western Kentucky. We used a treatment-control design to study resource selection at 2 spatial scales to identify important aspects of mine land vegetation and whether resource selection differed between areas with habitat management (i.e., burning, disking, herbicide; treatment) and unmanaged units (control). Our objectives were to estimate bobwhite resource selection on reclaimed mine land and to estimate the influence of habitat management practices on resource selection. We used locations from 283 individuals during the breeding season (1 Apr–30 Sep) and 136 coveys during the non-breeding season (1 Oct–Mar 31) from August 2009 to March 2014. Individuals were located closer to shrub cover than would be expected at random throughout the year. During the breeding season, individuals on treatment units used areas with smaller contagion index values (i.e., greater interspersion) compared with individuals on control units. During the non-breeding season, birds selected areas with greater shrub-open edge density compared with random. At the microhabitat scale, individuals selected areas with increased visual obstruction >1 m aboveground. During the breeding season, birds were closer to disked areas (linear and non-linear) than would be expected at random. Individuals selected non-linear disked areas during winter but did not select linear disked areas (firebreaks) because they were planted to winter wheat each fall and lacked cover during the non-breeding season. Individuals also selected areas treated with herbicide to control sericea lespedeza (Lespedeza cuneata) throughout the year. During the breeding season, bobwhites avoided areas burned during the previous dormant season. Habitat quality of reclaimed mine lands may be limited by a lack of shrub cover and extensive coverage of non-native herbaceous vegetation. Managers aiming to increase bobwhite abundance should focus on increasing interspersion of shrub cover, with no area >100 m from shrub cover. We suggest disking and herbicide application to control invasive species and improve the structure and composition of vegetation for bobwhites.
NASA Astrophysics Data System (ADS)
Pavia Rico, Ana; Lopez-Baeza, Ernesto; Matieu, Pierre-Philippe; Hernandez Sancho, Francesc; Loarte, Edwin
Lack of water is being a big problem in semi-arid areas to make agricultural profits. Most of Mediterranean countries like Spain, Italy, Greece or Cyprus and other countries like Morocco, the Arab United Emirates, South-American countries or China are starting to reuse wastewater as adaptation to climate change water scarcity. Drought areas are nowadays increasing, thus making fertile areas unproductive. For this reason, the European trend is to work on reusing wastewater as a solution to water scarcity in agriculture. Moreover, since population is growing fast, wastewater production is increasing as well as drinkable water demand, thus making reclaimed water as the water guarantee for irrigation and better agricultural management. This work represents a preliminary initiative to check, analyse and monitor the land by using remote sensing techniques to identify and determine the potential lands that used to be productive in the past, are now abandoned, and we want to recuperate to obtain socio-economic benefits. On top of this, this initiative will clearly enhance the adaption capacity of rural/agricultural lands to climate change. Alternatively to reclaimed water, greenhouses, desalination plants or transboarding water do not really eliminate the problem but only offer a temporary solution, make spending plenty of money and always provoking irreversible damages to the environment. The pilot area to first develop this research is the Valencia and Murcia Autonomous Communities located in the Spanish Mediterranean Coastline. An added value of this work will be to develop a methodology transferable to other potential countries with similar climatic characteristics and difficulties for irrigation, by using remote sensing methods and techniques. The remote sensing products obtained provide full information about the current state of the potential lands to grow crops. Potential areas are then being selected to carry out a socio-economic analysis leading to: (i) determining potential wastewater treatment plants to supply reclaimed water, based on pre-established criteria such as effluent quality, distance to the target land, existence of infrastructures to transport reclaimed water, etc. (ii) an analysis of the efficiency of the treatment plants selected taking into account that their possible inefficiency will probably derive into an increase in the cost of the reclaimed water. (iii) a feasibility analysis on cost (fixed and variable) and potential benefits (monetary and environmental). Monetary benefits will be estimated after analysing the most profitable crop type for each potential land
Code of Federal Regulations, 2012 CFR
2012-04-01
..., cinders, granite, building stone, limestone, clay, silt, or any other energy or non-energy mineral... treatment of minerals; Provided, when sand, gravel, pumice, cinders, granite, building stone, limestone...
Code of Federal Regulations, 2014 CFR
2014-04-01
..., cinders, granite, building stone, limestone, clay, silt, or any other energy or non-energy mineral... treatment of minerals; Provided, when sand, gravel, pumice, cinders, granite, building stone, limestone...
The EPA is providing notice of a proposed Administrative Penalty Assessment against Kerford Limestone Company, for alleged violations at the facility located at 36111 Fletcher Avenue, Weeping Water NE 68463.
Gorokhovich, Yuri; Reid, Matthew; Mignone, Erica; Voros, Andrew
2003-10-01
Coal mine reclamation projects are very expensive and require coordination of local and federal agencies to identify resources for the most economic way of reclaiming mined land. Location of resources for mine reclamation is a spatial problem. This article presents a methodology that allows the combination of spatial data on resources for the coal mine reclamation and uses GIS analysis to develop a priority list of potential mine reclamation sites within contiguous United States using the method of extrapolation. The extrapolation method in this study was based on the Bark Camp reclamation project. The mine reclamation project at Bark Camp, Pennsylvania, USA, provided an example of the beneficial use of fly ash and dredged material to reclaim 402,600 sq mi of a mine abandoned in the 1980s. Railroads provided transportation of dredged material and fly ash to the site. Therefore, four spatial elements contributed to the reclamation project at Bark Camp: dredged material, abandoned mines, fly ash sources, and railroads. Using spatial distribution of these data in the contiguous United States, it was possible to utilize GIS analysis to prioritize areas where reclamation projects similar to Bark Camp are feasible. GIS analysis identified unique occurrences of all four spatial elements used in the Bark Camp case for each 1 km of the United States territory within 20, 40, 60, 80, and 100 km radii from abandoned mines. The results showed the number of abandoned mines for each state and identified their locations. The federal or state governments can use these results in mine reclamation planning.
Trlica, Andrew; Brown, Sally
2013-07-02
The interrelation between urban areas and land use options for greenhouse gas mitigation was evaluated by assessing the utility of urban residuals for soil reclamation. Long-term impacts on soil C storage for mine lands restored with urban organic residuals were quantified by sampling historic sites reclaimed both conventionally and with residuals-based amendments. Use of amendments resulted in greater C storage compared to conventional practices for all sites sampled, with increases ranging from 14.2 Mg C ha(-1) in a coalmine in WA to 38.4 Mg C ha(-1) for a copper mine in British Columbia. Expressed as Mg C per Mg amendment, effective C increases ranged from 0.03 to 0.31 Mg C per Mg amendment. Results were applied to three alternative land-use scenarios to model the net GHG balance for a site restored to forest or low-density development. The model included construction of 3.9 243 m(2)-homes, typical of urban sprawl. Emissions for home and road construction and use over a 30-year period resulted in net emissions of 1269 Mg CO2. In contrast, conventional reclamation to forestland or reclamation with 100 Mg of residuals resulted in net GHG reductions of -293 and -475 Mg CO2. Construction of an equivalent number of smaller homes in an urban core coupled with restoration of 1 ha with amendments was close to carbon neutral. These results indicate that targeted use of urban residuals for forest reclamation, coupled with high-density development, can increase GHG mitigation across both sectors.
Novel Hydroxyapatite Coatings for the Conservation of Marble and Limestone
NASA Astrophysics Data System (ADS)
Naidu, Sonia
Marble and limestone are calcite-based materials used in the construction of various structures, many of which have significant artistic and architectural value. Unfortunately, due to calcite's high dissolution rate, these stones are susceptible to chemically-induced weathering in nature. Limestone, due to its inherent porosity, also faces other environmental weathering processes that cause weakening from disintegration at grain boundaries. The treatments presently available are all deficient in one way or another. The aim of this work is to examine the feasibility of using hydroxyapatite (HAP) as a novel protective coating for marble and limestone, with two goals: i) to reduce acid corrosion of marble and ii) to consolidate physically weathered limestone. The motivation for using HAP is its low dissolution rate and structural compatibility with calcite. Mild, wet chemical synthesis routes, in which inorganic phosphate-based solutions were reacted with marble and limestone, alone and with other precursors, were used to produce HAP films. Film nucleation, growth and phase evolution were studied on marble to understand film formation and determine the optimal synthesis route. An acid resistance test was developed to investigate the attack mechanism on marble and quantify the efficacy of HAP-based coatings. Film nucleation and growth were dependent on substrate surface roughness and increased with calcium and carbonate salt additions during synthesis. Acid attack on marble occurred via simultaneous dissolution at grain boundaries, twin boundaries and grain surfaces. HAP provided intermediate protection against acid attack, when compared to two conventional treatments. Its ability to protect the stone from acid was not as significant as predicted from dissolution kinetics and this was attributed to incomplete coverage and residual porosity within the film, arising from its flake-like crystal growth habit, which enabled acid to access the underlying substrate. The effectiveness of HAP as a consolidant for weathered limestone, alone and coupled with a commercially available consolidant (ConservareRTM OH-100), was also investigated. To artificially weather limestone in the lab, a reproducible thermal degradation technique was utilised. The dynamic elastic modulus, water sorptivity and coating composition of treated stones were evaluated. HAP was found to be an effective consolidant for limestone, as it restored the elastic modulus of damaged stones to their original values and exhibited superior performance to ConservareRTM OH-100.
Li, W.; Angel, R.; Kim, S.-W.; Jiménez-Moreno, E.; Proszkowiec-Weglarz, M.; Iglesias, B. F.; Wilkinson, S. J.; Cowieson, A. J.
2014-01-01
A study was done to determine whether broilers can regulate Ca intake when limestone is provided separately or mixed with a crumbled feed of variable Ca and P content, and the influence of this on performance and apparent ileal digestibility (AID) of Ca and P (AIDP). Twelve crumbled diets were fed from 10 to 20 d of age (8 replicates, 8 broilers/replicate). Diets A to D contained 0.28% nonphytate P (nPP) and 0.27, 0.51, 0.77, and 1.02% Ca, respectively. Diets E to H contained 0.48% nPP and 0.41, 0.51, 0.77, and 1.02% Ca, respectively. A large particle size limestone was mixed manually to the crumbled diet on a daily basis to achieve 1.02% total Ca in diets A to H. Diets I to L had the same Ca and nPP as diets A to D, but limestone was provided in a separate feeder to assess spatial importance of limestone supply. Limestone consumption, provided in a separate feeder, decreased as Ca concentration increased in the crumble diet (P < 0.05). Calcium intake increased as Ca concentration in crumbled diets increased (P < 0.05). Increased tibia ash and decreased AIDP were observed as Ca intake increased (P < 0.05). When limestone was added to diets containing 0.28% nPP postcrumble, Ca intake (6.38 g/bird), tibia ash (717 mg/bone), and AIDP (39.78%) were not affected by crumbled diet Ca concentration or consumed Ca. Broilers fed diets containing 0.48% nPP and limestone mixed with the crumble, Ca intake changed (5.96, 6.93, 6.59, and 6.04 g/bird for crumble diet with 0.41, 0.51, 0.77, and 1.02% Ca, respectively). Increasing Ca concentration in the crumble from 0.41 to 1.02% resulted in greater tibia ash (875 mg/bone) but lower AIDP (P < 0.05), although Ca intake was similar. In conclusion, when large particle size limestone was provided ad libitum, the ability of broilers to select for Ca was not sufficient to meet their requirement when crumble Ca was less than 0.77%. The AIDP was highest in birds fed the 0.27% Ca concentration diet. PMID:25085931
Carbonate chemistry of surface waters in a temperate karst region: the southern Yorkshire Dales, UK
NASA Astrophysics Data System (ADS)
Pentecost, Allan
1992-11-01
A detailed study of surface water chemistry is described from an important limestone region in northern England. Major ions and pH were determined for 485 sites (springs, seeps, streams, rivers and lakes) during summertime. The saturation state of the waters with respect to calcite was determined as the calcite saturation ratio (Ω). An unexpectedly large number of samples were found to be supersaturated (65.5% of the 268 km of watercourses surveyed). As a consequence, several streams entering major cave systems were incapable of further limestone solution, at least during periods of low flow. Many waters were supersaturated from their source and some deposited travertine. A significant negative correlation was found between spring discharge and both (Ω) and pH. Supersaturation was caused primarily by atmospheric degassing, with some contribution from aquatic plant photosynthesis. The median total dissolved inorganic carbon and Ca concentrations were 2.49 and 1.35 millimoles 1 -1 respectively. Calcium originated exclusively from limestone, and carbon dioxide mainly from the soil and dissolved limestone. South facing catchments provided springwaters with significantly higher levels of TDIC and Ca when compared with north facing catchments. The study suggests that acid rain made a measurable contribution to limestone dissolution. Carboniferous limestone denudation rates were estimated as 54 to 63 m 3 km -2 a -1 (54 to 63 mm 1000 years -1). About 50% of the Mg came from limestone and the remainder, together with most K, Na, SO 4 and Cl from precipitation. Concentrations of dissolved nutrients were low, medians for NO 3, NH 4, total PO 4 and SiO 3 were 24 μmol, 1.4 μmol, 0.64 μmol and 15.5 μmol 1 -1 respectively. The concentration of a further 23 trace elements was determined.