Duration of mineralization and fluid-flow history of the Upper Mississippi Valley zinc-lead district

USGS Publications Warehouse

Rowan, E.L.; Goldhaber, M.B.

1995-01-01

Studies of fluid inclusions in sphalerite and biomarkers from the Upper Mississippi Valley zinc district show homogenization temperatures to be primarily between 90 and 150??C, yet show relatively low levels of thermal maturity. Numerical calculations are used to simulate fluid and heat flow through fracture-controlled ore zones and heat transfer to the adjacent rocks. Combining a best-fit path through fluid-inclusion data with measured thermal alteration of biomarkers, the time interval during which mineralizing fluids circulated through the Upper Mississippi Valley district was calculated to be on the order of 200 ka. Cambrian and Ordovician aquifers underlying the district, principally the St. Peter and Mt. Simon Sandstones, were the source of the mineralizing fluid. The duration of mineralization thus reflects the fluid-flow history of these regional aquifers. -from Authors

Lead Isotopes from the Upper Mississippi Valley District: A Regional Perspective

USGS Publications Warehouse

Millen, Timothy M.; Zartman, Robert E.; Heyl, Allen Van

1995-01-01

New lead isotopic data on galena from within and peripheral to the Upper Mississippi Valley lead-zinc district make it possible, by extending coverage to outlying locations, to trace the pathway traversed by the mineralizing fluids beyond the boundary of the main district. All but one of the samples exhibit elevated ratios of the radiogenic isotopes typical of the Upper Mississippi Valley ore deposits; 206PbP04Pb ranges from 19.38 to 24.46, 207PbP04Pb ranges from 15.73 to 16.24, and 208PbP04Pb ranges from 39.24 to 43.69. Galena from the Pints quarry near Waterloo, Iowa, has distinctly lower values of these ratios and may not be related paragenetically to the other samples. Otherwise, the lowest ratios are for samples in the southern part of the region in north-central Illinois, and the highest ratios are for samples to the northeast of the main district in the vicinity of Madison, Wisconsin. Thus, an isotopic pattern rather similar to that observed originally by Heyl and others (1966) prevails regionally, although the predominant fluid flow is now believed to have emanated from the Illinois Basin rather than from the Forest City Basin. Metal-bearing brines being driven northward out of the Illinois Basin probably played the key role in mineralization of the Upper Mississippi Valley district. Both the new and the previously reported lead ratios for the Upper Mississippi Valley district are plotted on 207PbP04Pb and Pb208/pb204Pb versus 206PbP04Pb diagrams, which permit their comparison and the calculation of refined slopes for the expanded data set. A two-stage model age for the time of mineralization can be determined from the 207PbP04Pb_Pb206/Pb204 slope, provided that the source age of the lead is known. With our limited know ledge of this source age, the time of mineralization cannot be tightly constrained but is permissive of a Permian or younger lateral secretion event, as suggested by other geochronological results.

Critical elements in sediment-hosted deposits (clastic-dominated Zn-Pb-Ag, Mississippi Valley-type Zn-Pb, sedimentary rock-hosted Stratiform Cu, and carbonate-hosted Polymetallic Deposits): A review: Chapter 12

USGS Publications Warehouse

Marsh, Erin; Hitzman, Murray W.; Leach, David L.

2016-01-01

Some sediment-hosted base metal deposits, specifically the clastic-dominated (CD) Zn-Pb deposits, carbonate-hosted Mississippi Valley-type (MVT) deposits, sedimentary-rock hosted stratiform copper deposits, and carbonate-hosted polymetallic (“Kipushi type”) deposits, are or have been important sources of critical elements including Co, Ga, Ge, and Re. The generally poor data concerning trace element concentrations in these types of sediment-hosted ores suggest that there may be economically important concentrations of critical elements yet to be recognized.

Database of significant deposits of gold, silver, copper, lead, and zinc in the United States

USGS Publications Warehouse

Long, Keith R.; DeYoung,, John H.; Ludington, Stephen

1998-01-01

It has long been recognized that the largest mineral deposits contain most of the known mineral endowment (Singer and DeYoung, 1980). Sometimes called giant or world-class deposits, these largest deposits account for a very large share of historic and current mineral production and resources in industrial society (Singer, 1995). For example, Singer (1995) shows that the largest 10 percent of the world’s gold deposits contain 86 percent of the gold discovered to date. Many mineral resource issues and investigations are more easily addressed if limited to the relatively small number of deposits that contain most of the known mineral resources. An estimate of known resources using just these deposits would normally be sufficient, because considering smaller deposits would not add significantly to the total estimate. Land-use planning should treat mainly with these deposits due to their relative scarcity, the large share of known resources they contain, and the fact that economies of scale allow minerals to be produced much more cheaply from larger deposits. Investigation of environmental and other hazards that result from mining operations can be limited to these largest deposits because they account for most of past and current production.The National Mineral Resource Assessment project of the U.S. Geological Survey (USGS) has compiled a database on the largest known deposits of gold, silver, copper, lead, and zinc in the United States to complement the 1996 national assessment of undiscovered deposits of these same metals (Ludington and Cox, 1996). The deposits in this database account for approximately 99 percent of domestic production of these metals and probably a similar share of identified resources. These data may be compared with results of the assessment of undiscovered resources to characterize the nation’s total mineral endowment for these metals. This database is a starting point for any national or regional mineral-resource or mineral

Phosphorite-hosted zinc and lead mineralization in the Sekarna deposit (Central Tunisia)

USGS Publications Warehouse

Garnit, Hechmi; Bouhel, Salah; Barca, Donatella; Johnson, Craig A.; Chtara, Chaker

2012-01-01

The Sekarna Zn–Pb deposit is located in Central Tunisia at the northeastern edge of the Cenozoic Rohia graben. Mineralization comprises two major ore types: (1) disseminated Zn–Pb sulfides that occur as lenses in sedimentary phosphorite layers and (2) cavity-filling zinc oxides (calamine-type ores) that crosscut Late Cretaceous and Early Eocene limestone. We studied Zn sulfide mineralization in the Saint Pierre ore body, which is hosted in a 5-m-thick sedimentary phosphorite unit of Early Eocene age. The sulfide mineralization occurs as replacements of carbonate cement in phosphorite. The ores comprise stratiform lenses rich in sphalerite with minor galena, Fe sulfides, and earlier diagenetic barite. Laser ablation–inductively coupled plasma mass spectrometry analyses of sphalerite and galena show a wide range of minor element contents with significant enrichment of cadmium in both sphalerite (6,000–20,000 ppm) and galena (12–189 ppm). The minor element enrichments likely reflect the influence of the immediate organic-rich host rocks. Fluid inclusions in sphalerite give homogenization temperatures of 80–130°C. The final ice melting temperatures range from −22°C to −11°C, which correspond to salinities of 15–24 wt.% NaCl eq. and suggest a basinal brine origin for the fluids. Sulfur isotope analyses show uniformly negative values for sphalerite (−11.2‰ to −9.3‰) and galena (−16‰ to −12.3‰). The δ34S of barite, which averages 25.1‰, is 4‰ higher than the value for Eocene seawater sulfate. The sulfur isotopic compositions are inferred to reflect sulfur derivation through bacterial reduction of contemporaneous seawater sulfate, possibly in restricted basins where organic matter was abundant. The Pb isotopes suggest an upper crustal lead source.

Phosphorite-hosted zinc and lead mineralization in the Sekarna deposit (Central Tunisia)

NASA Astrophysics Data System (ADS)

Garnit, Hechmi; Bouhlel, Salah; Barca, Donatella; Johnson, Craig A.; Chtara, Chaker

2012-06-01

The Sekarna Zn-Pb deposit is located in Central Tunisia at the northeastern edge of the Cenozoic Rohia graben. Mineralization comprises two major ore types: (1) disseminated Zn-Pb sulfides that occur as lenses in sedimentary phosphorite layers and (2) cavity-filling zinc oxides (calamine-type ores) that crosscut Late Cretaceous and Early Eocene limestone. We studied Zn sulfide mineralization in the Saint Pierre ore body, which is hosted in a 5-m-thick sedimentary phosphorite unit of Early Eocene age. The sulfide mineralization occurs as replacements of carbonate cement in phosphorite. The ores comprise stratiform lenses rich in sphalerite with minor galena, Fe sulfides, and earlier diagenetic barite. Laser ablation-inductively coupled plasma mass spectrometry analyses of sphalerite and galena show a wide range of minor element contents with significant enrichment of cadmium in both sphalerite (6,000-20,000 ppm) and galena (12-189 ppm). The minor element enrichments likely reflect the influence of the immediate organic-rich host rocks. Fluid inclusions in sphalerite give homogenization temperatures of 80-130°C. The final ice melting temperatures range from -22°C to -11°C, which correspond to salinities of 15-24 wt.% NaCl eq. and suggest a basinal brine origin for the fluids. Sulfur isotope analyses show uniformly negative values for sphalerite (-11.2‰ to -9.3‰) and galena (-16‰ to -12.3‰). The δ34S of barite, which averages 25.1‰, is 4‰ higher than the value for Eocene seawater sulfate. The sulfur isotopic compositions are inferred to reflect sulfur derivation through bacterial reduction of contemporaneous seawater sulfate, possibly in restricted basins where organic matter was abundant. The Pb isotopes suggest an upper crustal lead source.

Loading estimates of lead, copper, cadmium, and zinc in urban runoff from specific sources.

PubMed

Davis, A P; Shokouhian, M; Ni, S

2001-08-01

Urban stormwater runoff is being recognized as a substantial source of pollutants to receiving waters. A number of investigators have found significant levels of metals in runoff from urban areas, especially in highway runoff. As an initiatory study, this work estimates lead, copper, cadmium, and zinc loadings from various sources in a developed area utilizing information available in the literature, in conjunction with controlled experimental and sampling investigations. Specific sources examined include building siding and roofs; automobile brakes, tires, and oil leakage; and wet and dry atmospheric deposition. Important sources identified are building siding for all four metals, vehicle brake emissions for copper and tire wear for zinc. Atmospheric deposition is an important source for cadmium, copper, and lead. Loadings and source distributions depend on building and automobile density assumptions and the type of materials present in the area examined. Identified important sources are targeted for future comprehensive mechanistic studies. Improved information on the metal release and distributions from the specific sources, along with detailed characterization of watershed areas will allow refinements in the predictions.

Thermal and chemical variations of the Nigerian Benue trough lead-zinc-barite-fluorite deposits

NASA Astrophysics Data System (ADS)

Ogundipe, Ibukun Emmanuel

2017-08-01

The Benue trough is an intra-continental rift initiated in the Cretaceous during the opening of the South Atlantic Ocean. Lead-zinc-barite-fluorite mineralization occurs along the 600 km axis of the trough in three discrete sub-basins which coincide with the lower, middle and upper mineral districts of the Benue Valley. Lithologically these sub-basins are dominated by black carbonaceous shale in the Lower Benue, platform carbonates in the Middle Benue and sandstones in the Upper Benue. Micro-thermometric analysis of fluid inclusions in sphalerite, fluorite, barite and quartz have shown that each mineral district has its own unique thermal and chemical imprint. For example, the temperature can be bracketed between 109 °C and 160 °C for lower Benue, 89 °C-144 °C for the Middle Benue and 176 °C-254 °C for the Upper Benue. Chemical differentiation also exists between each mineral district with the Lower Benue having 22 wt % equivalent NaCl while the Middle and Upper Benue have 18 and 16 wt % equivalent NaCl respectively. This study shows that inter-district thermal and chemical variations exist between the ore-stage sulfide and post-sulfide gangue minerals of the entire Benue Valley. Similarly, intra-district thermal and chemical variations have also been observed among all the paragenetic minerals of each district. The thermal variations may be as a result of variations in the geothermal gradient accompanying continental rifting from one district to the other. The variations in the chemistry between the Lower Benue and the Upper Benue paragenic minerals may be as a result of the distinct lithological differences across the Benue Trough.

Distribution of glacial deposits, soils, and permafrost in Taylor Valley, Antarctica

USGS Publications Warehouse

Bockheim, James G.; Prentice, M.L.; McLeod, M.

2008-01-01

We provide a map of lower and central Taylor Valley, Antarctica, that shows deposits from Taylor Glacier, local alpine glaciers, and grounded ice in the Ross Embayment. From our electronic database, which includes 153 sites from the coast 50 km upvalley to Pearse Valley, we show the distribution of permafrost type and soil subgroups according to Soil Taxonomy. Soils in eastern Taylor Valley are of late Pleistocene age, cryoturbated due to the presence of ground ice or ice-cemented permafrost within 70 cm of the surface, and classified as Glacic and Typic Haploturbels. In central Taylor Valley, soils are dominantly Typic Anhyorthels of mid-Pleistocene age that have dry-frozen permafrost within the upper 70 cm. Salt-enriched soils (Salic Anhyorthels and Petrosalic Anhyorthels) are of limited extent in Taylor Valley and occur primarily on drifts of early Pleistocene and Pliocene age. Soils are less developed in Taylor Valley than in nearby Wright Valley, because of lesser salt input from atmospheric deposition and salt weathering. Ice-cemented permafrost is ubiquitous on Ross Sea, pre-Ross Sea, and Bonney drifts that occur within 28 km of the McMurdo coast. In contrast, dry-frozen permafrost is prevalent on older (???115 ky) surfaces to the west. ?? 2008 Regents of the University of Colorado.

Map showing mineral resource assessment for vein and replacement deposits of gold, silver, copper, lead, zinc, manganese, and tungsten in the Butte 1 degree by 2 degrees Quadrangle, Montana

USGS Publications Warehouse

Elliott, J.E.; Wallace, C.A.; Lee, G.K.; Antweiler, J.C.; Lidke, D.J.; Rowan, L.C.; Hanna, W.F.; Trautwein, C.M.; Dwyer, John L.; Moll, S.H.

1992-01-01

The purpose of this report is to assess the potential for undiscovered vein and replacement deposits of gold, silver, copper, lead, zinc, manganese, and tungsten in the Butte 1 °X2° quadrangle. This quadrangle, in west-central Montana, is one of the most mineralized and productive regions in the United States. Its mining districts, including the world famous Butte or Summit Valley district, have produced a variety of metallic and nonmetallic mineral commodities valued at more than $6.4 billion. Because of its importance as a mineral producing region, the Butte quadrangle was selected for study by the U.S. Geological Survey under the Conterminous United States Mineral Assessment Program (CUSMAP). Under this program, new data on geology, geochemistry, geophysics, geochronology, mineral resources, and remote sensing were collected and synthesized. The field and laboratory studies were also supported by funding from the Geologic Framework and Synthesis Program and the Wilderness Program. The methods used in resource assessment include a compilation of all data into data sets, the development of a descriptive model for vein and replacement deposits in the quadrangle, and the analysis of data using techniques provided by the Geographic Information System (GIS). This map is one of a number of reports and maps on the Butte 1 °X2° quadrangle. Other publications resulting from this study include U.S. Geological Survey Miscellaneous Investigations Series Maps 1-2050-A (Rowan and Segal, in press) and I-2050-B (Purdy and Rowan, in press); Miscellaneous Field Studies Map MF-1925 (Wallace, 1987); and Open-File Reports 86-292 (Wallace and others, 1986) and 86--0632 (Elliott and others, 1986). Reports on mineral resource assessment for several other types of deposits in the Butte quadrangle are in preparation.

Electrophoretic deposition of zinc-substituted hydroxyapatite coatings.

PubMed

Sun, Guangfei; Ma, Jun; Zhang, Shengmin

2014-06-01

Zinc-substituted hydroxyapatite nanoparticles synthesized by the co-precipitation method were used to coat stainless steel plates by electrophoretic deposition in n-butanol with triethanolamine as a dispersant. The effect of zinc concentration in the synthesis on the morphology and microstructure of coatings was investigated. It is found that the deposition current densities significantly increase with the increasing zinc concentration. The zinc-substituted hydroxyapatite coatings were analyzed by X-ray diffraction, scanning electron microscopy and Fourier transform infrared spectroscopy. It is inferred that hydroxyapatite and triethanolamine predominate in the chemical composition of coatings. With the increasing Zn/Ca ratios, the contents of triethanolamine decrease in the final products. The triethanolamine can be burnt out by heat treatment. The tests of adhesive strength have confirmed good adhesion between the coatings and substrates. The formation of new apatite layer on the coatings has been observed after 7days of immersion in a simulated body fluid. In summary, the results show that dense, uniform zinc-substituted hydroxyapatite coatings are obtained by electrophoretic deposition when the Zn/Ca ratio reaches 5%. Copyright © 2014 Elsevier B.V. All rights reserved.

Data Base for a National Mineral-Resource Assessment of Undiscovered Deposits of Gold, Silver, Copper, Lead, and Zinc in the Conterminous United States

USGS Publications Warehouse

Ludington, S.D.; Cox, D.P.; McCammon, R.B.

1996-01-01

For this assessment, the conterminous United States was divided into 12 regions Adirondack Mountains, Central and Southern Rocky Mountains, Colorado Plateau, East Central, Great Basin, Great Plains, Lake Superior, Northern Appalachians, Northern Rocky Mountains, Pacific Coast, Southern Appalachians, and Southern Basin and Range. The assessment, which was conducted by regional assessment teams of scientists from the USGS, was based on the concepts of permissive tracts and deposit models. Permissive tracts are discrete areas of the United States for which estimates of numbers of undiscovered deposits of a particular deposit type were made. A permissive tract is defined by its geographic boundaries such that the probability of deposits of the type delineated occurring outside the boundary is neglible. Deposit models, which are based on a compilation of worldwide literature and on observation, are sets of data in a convenient form that describe a group of deposits which have similar characteristics and that contain information on the common geologic attributes of the deposits and the environments in which they are found. Within each region, the assessment teams delineated permissive tracts for those deposit models that were judged to be appropriate and, when the amount of information warranted, estimated the number of undiscovered deposits. A total of 46 deposit models were used to assess 236 separate permissive tracts. Estimates of undiscovered deposits were limited to a depth of 1 km beneath the surface of the Earth. The estimates of the number of undiscovered deposits of gold, silver, copper, lead, and zinc were expressed in the form of a probability distribution. Commonly, the number of undiscovered deposits was estimated at the 90th, 50th, and 10th percentiles. A Monte Carlo simulation computer program was used to combine the probability distribution of the number of undiscovered deposits with the grade and tonnage data sets associated with each deposit model to

Zinc halogen battery electrolyte composition with lead additive

DOEpatents

Henriksen, Gary L.

1981-01-01

This disclosure relates to a zinc halogen battery electrolyte composition containing an additive providing improved zinc-on-zinc recyclability. The improved electrolyte composition involves the use of a lead additive to inhibit undesirable irregular plating and reduce nodular or dendritic growth on the electrode surface. The lead-containing electrolyte composition of the present invention appears to influence not only the morphology of the base plate zinc, but also the morphology of the zinc-on-zinc replate. In addition, such lead-containing electrolyte compositions appear to reduce hydrogen formation.

Possible role of zinc in diminishing lead-related occupational stress-a zinc nutrition concern.

PubMed

Wani, Ab Latif; Ahmad, Ajaz; Shadab, G G H A; Usmani, Jawed Ahmad

2017-03-01

Lead and zinc are mostly present at the same occupational source and usually found as co-contaminants. Lead is known to associate with detrimental effects to humans. Zinc however is an essential nutrient and its deficiency causes debilitating effects on growth and development. Besides, it acts as core ion of important enzymes and proteins. The purpose of this study was to examine if zinc concentrations are associated with blood lead levels and if zinc may prevent lead-induced DNA damage. Blood samples were collected from 92 workers as participants occupationally exposed to lead or lead and zinc and 38 comparison participants having no history of such exposure. Lead and zinc levels were determined from blood by atomic absorption spectrophotometry and genetic damage was assessed by comet assay. Correlation was calculated by Spearman's rho. Lead concentrations were observed to increase among workers with increase in years of exposure. There was a significant difference (p < 0.001) in blood lead levels between workers and controls. In addition, significant difference (p < 0.001) in the genetic damage was observed among workers and controls. A clear effect of increased occupational exposure was visible among workers. Multiple regression analysis further reveals the positive effect of lead, while as the inverse effect of zinc on DNA damage. The results suggest that zinc may influence body lead absorption and may have a role in preventing the genetic damage caused by lead.

Copper and zinc content in wild game shot with lead or non-lead ammunition - implications for consumer health protection.

PubMed

Schlichting, Daniela; Sommerfeld, Christine; Müller-Graf, Christine; Selhorst, Thomas; Greiner, Matthias; Gerofke, Antje; Ulbig, Ellen; Gremse, Carl; Spolders, Markus; Schafft, Helmut; Lahrssen-Wiederholt, Monika

2017-01-01

The aim of this study was to examine the contamination of game meat with copper and zinc and establish whether the use of alternative (non-lead) ammunition can lead to higher or unsafe levels of copper and zinc in the meat of roe deer, wild boar and red deer. The research project "Safety of game meat obtained through hunting" (LEMISI) was conducted in Germany with the purpose of examining the entry of lead as well as copper and zinc into the meat of hunted game when using either lead or non-lead ammunition. The outcome of this study shows that the usage of both lead-based ammunition and alternative non-lead ammunition results in the entry of copper and zinc into the edible parts of the game. Using non-lead ammunition does not entail dangerously elevated levels of copper and zinc, so replacing lead ammunition with alternative ammunition does not introduce a further health problem with regard to these metals. The levels of copper and zinc in game meat found in this study are in the range found in previous studies of game. The content of copper and zinc in game meat is also comparable to those regularly detected in meat and its products from livestock (pig, cattle, sheep) for which the mean human consumption rate is much higher. From the viewpoint of consumer health protection, the use of non-lead ammunition does not pose an additional hazard through copper and zinc contamination. A health risk due to the presence of copper and zinc in game meat at typical levels of consumer exposure is unlikely for both types of ammunition.

A salt diapir-related Mississippi Valley-type deposit: the Bou Jaber Pb-Zn-Ba-F deposit, Tunisia: fluid inclusion and isotope study

NASA Astrophysics Data System (ADS)

Bouhlel, Salah; Leach, David L.; Johnson, Craig A.; Marsh, Erin; Salmi-Laouar, Sihem; Banks, David A.

2016-08-01

evaporation of seawater to halite saturation and requires a dilution of more than two times by meteoric water. The higher K/Na values in fluid inclusions from barite suggest that the brines interacted with K-rich rocks in the basement or siliciclastic sediments in the basin. Carbonate gangue minerals (ankerite and calcite) have δ13C and δ18O values that are close to the carbonate host rock and indicate fluid equilibrium between carbonate host rocks and hydrothermal brines. The δ34S values for sphalerite and galena fall within a narrow range (1 to 10 ‰) with a bulk value of 7.5 ‰, indicating a homogeneous source of sulfur. The δ34S values of barite are also relatively homogeneous (22 ‰), with 6 ‰ higher than the δ34S of local and regional Triassic evaporites (15 ‰). The latter are believed to be the source of sulfate. Temperature of deposition together with sulfur isotope data indicate that the reduced sulfur in sulfides was derived through thermochemical sulfate reduction of Triassic sulfate via hydrocarbons produced probably from Late Cretaceous source rocks. The 87Sr/86Sr ratio in the Bou Jaber barite (0.709821 to 0.711408) together with the lead isotope values of Bou Jaber galena (206Pb/204Pb = 18.699 to 18.737; 207Pb/204Pb = 15.635 to 15.708 and 208Pb/204Pb = 38.321 to 38.947) show that metals were extracted from homogeneous crustal source(s). The tectonic setting of the Bou Jaber ore deposit, the carbonate nature of the host rocks, the epigenetic style of the mineralization and the mineral associations, together with sulfur and oxygen isotope data and fluid inclusion data show that the Bou Jaber lead-zinc mineralization has the major characteristics of a salt diapir-related Mississippi Valley-type (MVT) deposit with superimposed events of fluorite and of barite deposition. Field relations are consistent with mineral deposition during the Eocene-Miocene Alpine orogeny from multiple hydrothermal events: (1) Zn-Pb sulfides formed by mixing of two fluids: one

Late Cenozoic surficial deposits and valley evolution of unglaciated northern New Jersey

USGS Publications Warehouse

Stanford, S.D.

1993-01-01

Multiple alluvial, colluvial, and eolian deposits in unglaciated northern New Jersey, and the eroded bedrock surfaces on which they rest, provide evidence of both long-term valley evolution driven by sustained eustatic baselevel lowering and short-term filling and excavation of valleys during glacial and interglacial climate cycles. The long-term changes occur over durations of 106 years, the short-term features evolve over durations of 104 to 105 years. Direct glacial effects, including blockage of valleys by glacial ice and sediment, and valley gradient reversals induced by crustal depression, are relatively sudden changes that account for several major Pleistocene drainage shifts. After deposition of the Beacon Hill fluvial gravel in the Late Miocene, lowering of sea level, perhaps in response to growth of the Antarctic ice sheet, led to almost complete dissection of the gravel. A suite of alluvial, colluvial, and eolian sediments was deposited in the dissected landscape. The fluvial Bridgeton Formation was deposited in the Raritan lowland, in the Amboy-Trenton lowland, and in the Delaware valley. Following southeastward diversion of the main Bridgeton river, perhaps during Late Pliocene or Early Pleistocene glaciation, northeastward drainage was established on the inactive Bridgeton fluvial plain. About 30 to 45 m of entrenchment followed, forming narrow, incised valleys within which Late Pleistocene deposits rest. This entrenchment may have occurred in response to lowered sea level caused by growth of ice sheets in the northern hemisphere. Under periglacial conditions in the Middle and Late Pleistocene, valleys were partially filled with alluvium and colluvium. During interglacials slopes were stabilized by vegetation and the alluvial and colluvial valley-fill was excavated by gullying, bank erosion, and spring sapping. During Illinoian and late Wisconsinan glaciation, the lower Raritan River was diverted when glacial deposits blocked its valley, and the

Copper and zinc content in wild game shot with lead or non-lead ammunition – implications for consumer health protection

PubMed Central

Sommerfeld, Christine; Müller-Graf, Christine; Selhorst, Thomas; Greiner, Matthias; Gerofke, Antje; Ulbig, Ellen; Gremse, Carl; Spolders, Markus; Schafft, Helmut; Lahrssen-Wiederholt, Monika

2017-01-01

The aim of this study was to examine the contamination of game meat with copper and zinc and establish whether the use of alternative (non-lead) ammunition can lead to higher or unsafe levels of copper and zinc in the meat of roe deer, wild boar and red deer. The research project “Safety of game meat obtained through hunting” (LEMISI) was conducted in Germany with the purpose of examining the entry of lead as well as copper and zinc into the meat of hunted game when using either lead or non-lead ammunition. The outcome of this study shows that the usage of both lead-based ammunition and alternative non-lead ammunition results in the entry of copper and zinc into the edible parts of the game. Using non-lead ammunition does not entail dangerously elevated levels of copper and zinc, so replacing lead ammunition with alternative ammunition does not introduce a further health problem with regard to these metals. The levels of copper and zinc in game meat found in this study are in the range found in previous studies of game. The content of copper and zinc in game meat is also comparable to those regularly detected in meat and its products from livestock (pig, cattle, sheep) for which the mean human consumption rate is much higher. From the viewpoint of consumer health protection, the use of non-lead ammunition does not pose an additional hazard through copper and zinc contamination. A health risk due to the presence of copper and zinc in game meat at typical levels of consumer exposure is unlikely for both types of ammunition. PMID:28934259

Sources of lead and zinc associated with metal smelting activities in the Trail area, British Columbia, Canada.

PubMed

Goodarzi, Fariborz; Sanei, Hamed; Labonté, Marcel; Duncan, William F

2002-06-01

The spatial distribution and deposition of lead and zinc emitted from the Trail smelter, British Columbia, Canada, was studied by strategically locating moss bags in the area surrounding the smelter and monitoring the deposition of elements every three months. A combined diffusion/distribution model was applied to estimate the relative contribution of stack-emitted material and material emitted from the secondary sources (e.g., wind-blown dust from ore/slag storage piles, uncovered transportation/trucking of ore, and historical dust). The results indicate that secondary sources are the major contributor of lead and zinc deposited within a short distance from the smelter. Gradually, the stack emissions become the main source of Pb and Zn at greater distances from the smelter. Typical material originating from each source was characterized by SEM/EDX, which indicated a marked difference in their morphology and chemical composition.

The Reocín zinc-lead deposit, Spain: paleomagnetic dating of a late Tertiary ore body

USGS Publications Warehouse

Symons, David T. A.; Lewchuk, Michael T.; Kawasaki, Kazuo; Velasco, Francisco; Leach, David L.

2009-01-01

The Reocín mine in northern Spain’s Basque–Cantabrian basin exploited a world-class Mississippi Valley-type Zn–Pb deposit. Its epigenetic mineralization is in Urgonian 116 ± 1 Ma dolomitized limestones of the Santillana syncline, which was formed by Oligocene and mid Miocene pulses of the Pyrenean orogeny. Paleomagnetic results (22 sites, 274 specimens) in mineralization isolated a stable remanence (ChRM) in pyrrhotite and minor magnetite inclusions in ore specimens, Zn concentrate, and tailings. A fold test shows that the ChRM is substantially post-folding. The mineralization’s paleopole lies on the European apparent polar wander path and indicates that the mineralization was formed at 15 ± 10 Ma. We postulate that brines originated in underlying Triassic and Lower Cretaceous sedimentary rocks and were driven upward into the host rocks by the hydraulic gradient created by the nearby Asturian massif.

Zinc oxide nanorod clusters deposited seaweed cellulose sheet for antimicrobial activity.

PubMed

Bhutiya, Priyank L; Mahajan, Mayur S; Abdul Rasheed, M; Pandey, Manoj; Zaheer Hasan, S; Misra, Nirendra

2018-06-01

Seaweed cellulose was isolated from green seaweed Ulva fasciata using a common bleaching agent. Sheet containing porous mesh was prepared from the extracted seaweed crystalline cellulose along with zinc oxide (ZnO) nanorod clusters grown over the sheet by single step hydrothermal method. Seaweed cellulose and zinc oxide nanorod clusters deposited seaweed cellulose sheet was characterized by FT-IR, XRD, TGA, and SEM-EDX. Morphology showed that the diameter of zinc oxide nanorods were around 70nm. Zinc oxide nanorod clusters deposited on seaweed cellulose sheet gave remarkable antibacterial activity towards gram-positive (Staphylococcus aureus, Bacillus ceresus, Streptococcus thermophilis) and gram-negative (Escherichia coli, Pseudomonas aeruginous) microbes. Such deposited sheet has potential applications in pharmaceutical, biomedical, food packaging, water treatment and biotechnological industries. Copyright © 2018 Elsevier B.V. All rights reserved.

Texture and depositional history of near-surface alluvial deposits in the central part of the western San Joaquin Valley, California

USGS Publications Warehouse

Laudon, Julie; Belitz, Kenneth

1989-01-01

Saline conditions and associated high levels of selenium and other soluble trace elements in soil, shallow ground water, and agricultural drain water of the western San Joaquin Valley, California, have prompted a study of the texture of near-surface alluvial deposits in the central part of the western valley. Texture is characterized by the percentage of coarse-grained sediment present within a specified subsurface depth interval and is used as a basis for mapping the upper 50 feet of deposits. Resulting quantitative descriptions of the deposits are used to interpret the late Quaternary history of the area. Three hydrogeologic units--Coast Range alluvium, flood-basin deposits, and Sierran sand--can be recognized in the upper 50 feet of deposits in the central part of the western San Joaquin Valley. The upper 30 feet of Coast Range alluvium and the adjacent 5 to 35 feet of flood-basin deposits are predominantly fine grained. These fine-grained Coast Range deposits are underlain by coarse-grained channel deposits. The fine-grained flood basin deposits are underlain by coarse-grained Sierran sand. The extent and orientation of channel deposits below 20 feet in the Coast Range alluvium indicate that streams draining the Coast Range may have been tributary to the axial stream that deposited the Sierran sand and that streamflow may have been to the southeast. The fining-upward stratigraphic sequence in the upper 50 feet of deposits and the headward retreat of tributary stream channels from the valley trough with time support a recent hypothesis of climatic control of alluviation in the western San Joaquin Valley.

Assessment of Undiscovered Deposits of Gold, Silver, Copper, Lead, and Zinc in the United States: A Portable Document (PDF) Recompilation of USGS Open-File Report 96-96 and Circular 1178

USGS Publications Warehouse

U.S. Geological Survey National Mineral Resource Assessment Team Recompiled by Schruben, Paul G.

2002-01-01

This publication contains the results of a national mineral resource assessment study. The study (1) identifies regional tracts of ground believed to contain most of the nation's undiscovered resources of gold, silver, copper, lead, and zinc in conventional types of deposits; and (2) includes probabilistic estimates of the amounts of these undiscovered resources in most of the tracts. It also contains a table of the significant known deposits in the tracts, and includes descriptions of the mineral deposit models used for the assessment. The assessment was previously released in two major publications. The conterminous United States assessment was published in 1996 as USGS Open-File Report 96-96. Subsequently, the Alaska assessment was combined with the conterminous assessment in 1998 and released as USGS Circular 1178. This new recompilation was undertaken for several reasons. First, the graphical browser software used in Circular 1178 was ONLY compatible with the Microsoft Windows operating system. It was incompatible with the Macintosh operating system, Linux, and other types of Unix computers. Second, the browser on Circular 1178 is much less intuitive to operate, requiring most users to follow a tutorial to understand how to navigate the information on the CD. Third, this release corrects several errors and numbering inconsistencies in Circular 1178.

Ore genesis of the Wusihe carbonate-hosted Zn-Pb deposit in the Dadu River Valley district, Yangtze Block, SW China: evidence from ore geology, S-Pb isotopes, and sphalerite Rb-Sr dating

NASA Astrophysics Data System (ADS)

Xiong, Suo-Fei; Gong, Yong-Jun; Jiang, Shao-Yong; Zhang, Xiao-Jing; Li, Qian; Zeng, Guo-Ping

2018-01-01

The Wusihe carbonate-hosted Zn-Pb deposit (3.7 Mt. Zn + Pb at a grade of 8.6% Zn and 2.0% Pb) is the largest deposit in the Dadu River Valley district of the Sichuan-Yunnan-Guizhou metallogenic province of southwest China. Three types of orebodies occur: (1) stratiform, banded and lamellar, within dolomite of the Neoproterozoic Dengying Formation; (2) vein type; and (3) breccia type. Four stages of mineralization are distinguished: (i) pyrite stage, (ii) pyrite-pyrrhotite-galena-sphalerite-bitumen stage, (iii) sphalerite-galena stage, and (iv) bitumen-calcite stage. Sphalerite and galena from stages II and III show δ34S ranges from +7.1 to +9.7‰ and +9.1 to +13.1‰, respectively. High-precision in situ lead isotope analyses of sulfides show 208Pb/204Pb, 207Pb/204Pb, and 206Pb/204Pb ratios of 37.938 to 38.336, 15.579 to 15.682, and 17.951 to 18.195, respectively, which suggest a mixing of lead from the basement and the host rocks. Rb-Sr isotope analyses for six sphalerite samples of stage II yielded an isochron age of 411 ± 10 Ma (MSWD = 1.4). Combining all available ore geology and geochemical data, together with fluid inclusion data reported previously, we suggest that the Wusihe deposit is a Mississippi Valley-type (MVT) deposit.

Simultaneous Measurement of Zinc, Copper, Lead and Cadmium in Baby Weaning Food and Powder Milk by DPASV.

PubMed

Sadeghi, Naficeh; Oveisi, Mohammad Reza; Jannat, Behrooz; Hajimahmoodi, Mannan; Behfar, Abdolazim; Behzad, Masoomeh; Norouzi, Narges; Oveisi, Morvarid; Jannat, Behzad

2014-01-01

Apart from the breast milk, infant formula and baby weaning food have a special role in infant diet. Infants and young children are very susceptible to amount of trace elements. Copper and zinc are two elements that add in infant food. Lead and cadmium are heavy metals that enter to food chain unavoidably. DPASV is a benefit and applicable method for measurement of trace elements in food products. In this study, concentration of zinc, copper, lead and cadmium in four brands of baby food (rice and wheat based) and powder milk was analyzed with DPASV and polarograph set. Total Mean ± SE of zinc, copper, lead and cadmium in baby foods (n = 240) were 11.86 ± 1.474 mg/100g, 508.197 ± 83.154 μg/100g, 0.445 ± 0.006, 0.050 ± 0.005 mg/Kg respectively. Also these amount in powder milk (n = 240) were 3.621± 0.529 mg/100g, 403.822 ± 133.953 μg/100g, 0.007 ± 0.003, 0.060 ± 0.040 mg/Kg respectively. Zinc level in baby food type I was higher than lablled value (P = 0.030), but in other brands was not difference. Concentration of copper in all of samples was in labeled range (P > 0.05). In each four products, level of lead and cadmium were lower than the standard limit (P < 0.05). Amount of zinc and lead in baby food I, had difference versus other products. Concentration of zinc, camium in baby food type I, was higher than type II (P = 0.043, 0.001 respectively). Concentration of lead and cadmium in baby food type II, was higher than infant formulas, but are in standard limit.

Mass wasting deposits in the upper Sehonghong valley, eastern Lesotho: Late Pleistocene climate implications

NASA Astrophysics Data System (ADS)

Mills, S. C.; Grab, S. W.

2009-04-01

Despite considerable research attention on apparent periglacial, glacial and sedimentary phenomena in the Maluti-Drakensberg alpine environment, knowledge on the Quaternary environmental history of this important watershed and climate-divide is still rather rudimentary. The dearth of Quaternary environmental indicators (proxy data) in the high Drakensberg is partly owing to the harsh climate (e.g. high wind speeds and high seasonal precipitation), which offers a poor preservation of past biological remains (e.g. bones, dung, middens, pollen). Possibly the best opportunity to reconstruct high Drakensberg palaeoenvironments is from sedimentary sequences exposed along fluvially-incised valley fills. The upper Sehonghong River (3000 to 3200 m a.s.l.) flows in a westerly direction and is flanked by north- and south-facing slopes reaching 3465 m a.s.l. Sediment is exposed on both the north- and south-facing slopes along the river. Despite uniform regional environmental conditions (geology, topography, climate, vegetation), there is a notable absence of similar north-facing deposits in adjacent upper valley catchments to the north and south of Sehonghong Valley. The upper Sehonghong Valley thus presents somewhat ‘unique' evidence for palaeo-slope mass movement in this alpine region. Thick colluvial deposits are most prominent on the south-facing slopes along the Sehonghong River and occur at altitudes between 3100 m a.s.l. and 3150 m a.s.l. The colluvial mantles are approximately 7 m in thickness, however reach up to 13 m in some areas. Although the north-facing lower valley side-slopes are generally absent of deposits, the notable exception is the thick stratified deposit located a few kilometres upstream. Whilst the south-facing deposits are relatively uniform in nature, the north-facing deposits consist of alternating units of gravel and organic sediment, dated to 36 600 ± 1400 14C yrs BP, and reflecting environmental changes during the Late Pleistocene. Mass

Influence of lead ions on the macromorphology of electrodeposited zinc

DOE Office of Scientific and Technical Information (OSTI.GOV)

Tsuda, Tetsuaki; Tobias, Charles W.

1981-09-01

The morphology of zinc as it is electrodeposited from acid solutions demonstrates a remarkable imprint of electrolyte flow conditions. The development of macromorphology of zinc deposits has been investigated under galvanostatic conditions on a rotating plantinum disk electrode by use of photomacrography, scanning electron microscopy, electron probe microanalysis and Auger microprobe analysis. Logarithmic spiral markings, which reflect the hydrodynamic flow on a rotating disk, appear in a certain region of current density well below the limiting current density. Morphological observations revealed the major influence of trace lead ions on the amplifications of surface roughness through coalescence and preferred growth ofmore » initial protrusions. Results obtained from ultra-pure electrolyte suggest preferred crystal growth towards well-mixed orientation in the concentration field caused by slight differences in crystallization overpotential. A qualitative model involving a coupling mechanism between the evolving surface roughness and instability phenomena in the boundary layer is advanced to explain the formation of spiral patterns.« less

Brine history indicated by argon, krypton, chlorine, bromine, and iodine analyses of fluid inclusions from the Mississippi Valley type lead-fluorite-barite deposits at Hansonburg, New Mexico

USGS Publications Warehouse

Böhlke, J.K.; Irwin, J.J.

1992-01-01

Argon, krypton, chlorine, bromine, and iodine were measured in a homogeneous population of high-salinity hydrothermal fluid inclusions from the Tertiary-age Mississippi Valley-type (MVT) lead-fluorite-barite deposits at Hansonburg, New Mexico to establish new types of evidence for the history of both the fluid and the major dissolved salts. Noble gases and halogens in fluid inclusions containing 10−10–10−9 L of brine (Cl= 3 molal) were analyzed by laser microprobe noble-gas mass spectrometry (lmngms) on neutron-irradiated samples.The concentrations of36Ar (4.7 × 10−8 molal) and84Kr1.8 × 10−9 molal) in the fluid inclusions are equal to those of fresh surface waters in equilibrium with air at approximately20 ± 5°. The mole ratios ofBr/Cl (1.2 × 10−4) andI/Cl (1–2 × 10−6) are among the lowest measured in any natural waters, similar to those of modern brines formed by dissolution of Permian NaCl-bearing evaporites in southeast New Mexico.40Ar/36Ar ratios (600) are twice that of air, and indicate that the fluid inclusions had excess radiogenic40Ar (1.4 × 10−5 molal) when trapped. The amount of excess40Ar appears to be too large to have been acquired with Cl by congruent dissolution of halite-bearing evaporites, and possibly too small to have been acquired with Pb by congruent dissolution of granitic basement rocks with Proterozoic KAr ages.From thelmngms data, combined with published Pb and S isotope data, we infer the following sequence of events in the history of the Hansonburg MVT hydrothermal brine: (1) the brine originated as relatively dilute meteoric water, and it did not gain or lose atmospheric Ar or Kr after recharge; (2) the originally dilute fluid acquired the bulk of its Cl and sulfate in the subsurface after recharge by dissolving halite-bearing Permian? marine evaporites; (3) the high salinity brine then acquired most of its Pb and excess radiogenic40Ar from interactions with aquifer rocks other than evaporites, possibly clastic

Removal of lead and zinc ions from water by low cost adsorbents.

PubMed

Mishra, P C; Patel, R K

2009-08-30

In this study, activated carbon, kaolin, bentonite, blast furnace slag and fly ash were used as adsorbent with a particle size between 100 mesh and 200 mesh to remove the lead and zinc ions from water. The concentration of the solutions prepared was in the range of 50-100 mg/L for lead and zinc for single and binary systems which are diluted as required for batch experiments. The effect of contact time, pH and adsorbent dosage on removal of lead and zinc by adsorption was investigated. The equilibrium time was found to be 30 min for activated carbon and 3h for kaolin, bentonite, blast furnace slag and fly ash. The most effective pH value for lead and zinc removal was 6 for activated carbon. pH value did not effect lead and zinc removal significantly for other adsorbents. Adsorbent doses were varied from 5 g/L to 20 g/L for both lead and zinc solutions. An increase in adsorbent doses increases the percent removal of lead and zinc. A series of isotherm studies was undertaken and the data evaluated for compliance was found to match with the Langmuir and Freundlich isotherm models. To investigate the adsorption mechanism, the kinetic models were tested, and it follows second order kinetics. Kinetic studies reveals that blast furnace slag was not effective for lead and zinc removal. The bentonite and fly ash were effective for lead and zinc removal.

Lead and zinc intoxication in companion birds.

PubMed

Puschner, Birgit; Poppenga, Robert H

2009-01-01

Although the toxicity of lead and zinc to birds is widely recognized by veterinarians and bird owners, these metals are frequently found in the environments of pet and aviary birds, and intoxications are common. Clinical signs exhibited by intoxicated birds are often nonspecific, which makes early diagnosis difficult. Fortunately, lead and zinc analyses of whole blood and serum or plasma, respectively, are readily available and inexpensive; elevated concentrations can confirm intoxication. Once diagnosed, intoxication can be effectively treated by (1) preventing further exposure, (2) administering chelating drugs, and (3) providing symptomatic and supportive care.

Ion beam sputter deposited zinc telluride films

NASA Technical Reports Server (NTRS)

Gulino, D. A.

1986-01-01

Zinc telluride is of interest as a potential electronic device material, particularly as one component in an amorphous superlattice, which is a new class of interesting and potentially useful materials. Some structural and electronic properties of ZnTe films deposited by argon ion beam sputter deposition are described. Films (up to 3000 angstroms thick) were deposited from a ZnTe target. A beam energy of 1000 eV and a current density of 4 mA/sq cm resulted in deposition rates of approximately 70 angstroms/min. The optical band gap was found to be approximately 1.1 eV, indicating an amorphous structure, as compared to a literature value of 2.26 eV for crystalline material. Intrinsic stress measurements showed a thickness dependence, varying from tensile for thicknesses below 850 angstroms to compressive for larger thicknesses. Room temperature conductivity measurement also showed a thickness dependence, with values ranging from 1.86 x 10 to the -6th/ohm cm for 300 angstrom film to 2.56 x 10 to the -1/ohm cm for a 2600 angstrom film. Measurement of the temperature dependence of the conductivity for these films showed complicated behavior which was thickness dependent. Thinner films showed at least two distinct temperature dependent conductivity mechanisms, as described by a Mott-type model. Thicker films showed only one principal conductivity mechanism, similar to what might be expected for a material with more crystalline character.

Localized zinc distribution in shark vertebrae suggests differential deposition during ontogeny and across vertebral structures.

PubMed

Raoult, Vincent; Howell, Nicholas; Zahra, David; Peddemors, Victor M; Howard, Daryl L; de Jonge, Martin D; Buchan, Benjamin L; Williamson, Jane E

2018-01-01

The development of shark vertebrae and the possible drivers of inter- and intra-specific differences in vertebral structure are poorly understood. Shark vertebrae are used to examine life-history traits related to trophic ecology, movement patterns, and the management of fisheries; a better understanding of their development would be beneficial to many fields of research that rely on these calcified structures. This study used Scanning X-ray Fluorescence Microscopy to observe zinc distribution within vertebrae of ten shark species from five different orders. Zinc was mostly localised within the intermedialis and was generally detected at levels an order of magnitude lower in the corpus calcareum. In most species, zinc concentrations were higher pre-birth mark, indicating a high rate of pre-natal zinc deposition. These results suggest there are inter-specific differences in elemental deposition within vertebrae. Since the deposition of zinc is physiologically-driven, these differences suggest that the processes of growth and deposition are potentially different in the intermedialis and corpus calcareum, and that caution should be taken when extrapolating information such as annual growth bands from one structure to the other. Together these results suggest that the high inter-specific variation in vertebral zinc deposition and associated physiologies may explain the varying effectiveness of ageing methodologies applied to elasmobranch vertebrae.

Fluid inclusions and biomarkers in the Upper Mississippi Valley zinc-lead district; implications for the fluid-flow and thermal history of the Illinois Basin

USGS Publications Warehouse

Rowan, E. Lanier; Goldhaber, Martin B.

1996-01-01

The Upper Mississippi Valley zinc-lead district is hosted by Ordovician carbonate rocks at the northern margin of the Illinois Basin. Fluid inclusion temperature measurements on Early Permian sphalerite ore from the district are predominantly between 90?C and I50?C. These temperatures are greater than can be explained by their reconstructed burial depth, which was a maximum of approximately 1 km at the time of mineralization. In contrast to the temperatures of mineral formation derived from fluid inclusions, biomarker maturities in the Upper Mississippi Valley district give an estimate of total thermal exposure integrated over time. Temperatures from fluid inclusions trapped during ore genesis with biomarker maturities were combined to construct an estimate of the district's overall thermal history and, by inference, the late Paleozoic thermal and hydrologic history of the Illinois Basin. Circulation of groundwater through regional aquifers, given sufficient flow rates, can redistribute heat from deep in a sedimentary basin to its shallower margins. Evidence for regional-scale circulation of fluids is provided by paleomagnetic studies, regionally correlated zoned dolomite, fluid inclusions, and thermal maturity of organic matter. Evidence for igneous acti vity contemporaneous with mineralization in the vicinity of the Upper Mississippi Valley district is absent. Regional fluid and heat circulation is the most likely explanation for the elevated fluid inclusion temperatures (relative to maximum estimated burial depth) in the Upper Mississippi Valley district. One plausible driving mechanism and flow path for the ore-forming fluids is groundwater recharge in the late Paleozoic Appalachian-Ouachita mountain belt and northward flow through the Reelfoot rift and the proto- Illinois Basin to the Upper Mississippi Valley district. Warm fluid flowing laterally through Cambrian and Ordovician aquifers would then move vertically upward through the fractures that control

Magnetic properties of alluvial soils contaminated with lead, zinc and cadmium

NASA Astrophysics Data System (ADS)

Petrovský, E.; Kapička, A.; Jordanova, N.; Borůvka, L.

2001-09-01

Several proxy methods have been used recently to outline increased levels of pollution. One of them is based on measurements of the concentration of (ferri)magnetic minerals of anthropogenic origin. This method has been used recently in the mapping of both polluted and unpolluted areas. In order to validate this method, a more detailed study of links between magnetic parameters characterising the physical shape of magnetic minerals and concentrations of heavy metals is needed. In this study, we analysed the magnetic characteristics of alluvial soils, formed as a result of several breakdowns of wet deposit sink of ashes from a lead ore smelter. The soils were previously analysed for concentration of lead, zinc and cadmium. Our results show that in this case of a shared source of heavy metals and magnetic minerals, simple measurements of magnetic susceptibility discriminate well between polluted and clean areas. In addition, the concentration pattern agrees with the concentrations of the heavy metals studied in deeper soil layers that were not affected by post-depositional changes due to climate and remediation efforts.

Rapid, efficient charging of lead-acid and nickel-zinc traction cells

NASA Technical Reports Server (NTRS)

Smithrick, J. J.

1978-01-01

Lead-acid and nickel-zinc traction cells were rapidly and efficiently charged using a high rate tapered direct current (HRTDC) charge method which could possibly be used for on-the-road service recharge of electric vehicles. The HRTDC method takes advantage of initial high cell charge acceptance and uses cell gassing rate and temperature as an indicator of charging efficiency. On the average, in these preliminary tests, 300 amp-hour nickel-zinc traction cells were given a HRTDC (initial current 500 amps, final current 100 amps) to 78 percent of rated amp-hour capacity within 53 minutes at an amp-hour efficiency of 92 percent and an energy efficiency of 52 percent. Three hundred amp-hour lead-acid traction cells were charged to 69 percent of rated amp-hour capacity within 46 minutes at an amp-hour efficiency of 91 percent with an energy efficiency of 64 percent. In order to find ways to further decrease the recharge times, the effect of periodically (0 to 400 Hz) pulse discharging cells during a constant current charging process (94% duty cycle) was investigated. Preliminary data indicate no significant effect of this type of pulse discharging during charge on charge acceptance of lead-acid or nickel-zinc cells.

Histochemical detection of lead and zinc in plant tissues

DOE Office of Scientific and Technical Information (OSTI.GOV)

Tung, G.; Temple, P.J.

1975-01-01

Histochemical studies on uptake and localization of lead and zinc in plant tissues were carried out. A histochemical stain technique was developed to differentiate zinc from lead. Lead was detected in plant tissues by soaking fresh plant materials in freshly prepared sodium rhodizonate stain (0.2% Na rhodizonate acidified to pH3 with glacial acetic acid). Samples were evacuated 5 min and soaked for 30 min before embedding in the congealed stain, then sectioned with a cryostat and examined under a light microscope. Lead particles in plant tissues were stained scarlet-red. Gelatinous, proteinaceous or saccharic embedding materials normally used to prepare plantmore » sampled for sectioning in the cryostat interfered with the color reaction. Sectioning plant samples without staining whole tissues resulted in a weakened response to the stain. Color of stained sample materials were retained for several months if stored in a frozen condition. This technique was used to detect lead both inside and on the surface of plant samples collected in the vicinity of highway and industrial lead sources and to trace the pathways of lead uptake from the air or from contaminated soils. A sodium rhodizonate technique was also developed to be specific for zinc in plant tissues. Plant samples were soaked in a neutral Na-rhodizonate in phosphate buffer at pH 7.5 for observation. The color of zinc developed to produce a purplish or reddish-brown color.« less

Remediation of arsenic and lead with nanocrystalline zinc sulfide.

PubMed

Piquette, Alan; Cannon, Cody; Apblett, Allen W

2012-07-27

Nanocrystalline (1.7 ± 0.3 nm) zinc sulfide with a specific surface area up to 360 m(2) g(-1) was prepared from the thermal decomposition of a single-source precursor, zinc ethylxanthate. Zinc ethylxanthate decomposes to cubic zinc sulfide upon exposure to temperatures greater than or equal to 125 °C. The resulting zinc sulfide was tested as a water impurity extractant. The target impurities used in this study were As(5+), As(3+), and Pb(2+). The reaction of the nanocrystalline ZnS with Pb(2+) proceeds as a replacement reaction where solid PbS is formed and Zn(2+) is released into the aqueous system. Removal of lead to a level of less than two parts per billion is achievable. The results of a detailed kinetics experiment between the ZnS and Pb(2+) are included in this study. Unlike the instance of lead, both As(5+) and As(3+) adsorb on the surface of the ZnS extractant as opposed to an ion-exchange process. An uptake capacity of > 25 mg g(-1) for the removal of As(5+) is possible. The uptake of As(3+) appears to proceed by a slower process than that of the As(5+) with a capacity of nearly 20 mg g(-1). The nanocrystalline zinc sulfide was extremely successful for the removal of arsenic and lead from simulated oil sand tailing pond water.

Classification of mineral deposits into types using mineralogy with a probabilistic neural network

USGS Publications Warehouse

Singer, Donald A.; Kouda, Ryoichi

1997-01-01

In order to determine whether it is desirable to quantify mineral-deposit models further, a test of the ability of a probabilistic neural network to classify deposits into types based on mineralogy was conducted. Presence or absence of ore and alteration mineralogy in well-typed deposits were used to train the network. To reduce the number of minerals considered, the analyzed data were restricted to minerals present in at least 20% of at least one deposit type. An advantage of this restriction is that single or rare occurrences of minerals did not dominate the results. Probabilistic neural networks can provide mathematically sound confidence measures based on Bayes theorem and are relatively insensitive to outliers. Founded on Parzen density estimation, they require no assumptions about distributions of random variables used for classification, even handling multimodal distributions. They train quickly and work as well as, or better than, multiple-layer feedforward networks. Tests were performed with a probabilistic neural network employing a Gaussian kernel and separate sigma weights for each class and each variable. The training set was reduced to the presence or absence of 58 reported minerals in eight deposit types. The training set included: 49 Cyprus massive sulfide deposits; 200 kuroko massive sulfide deposits; 59 Comstock epithermal vein gold districts; 17 quartzalunite epithermal gold deposits; 25 Creede epithermal gold deposits; 28 sedimentary-exhalative zinc-lead deposits; 28 Sado epithermal vein gold deposits; and 100 porphyry copper deposits. The most common training problem was the error of classifying about 27% of Cyprus-type deposits in the training set as kuroko. In independent tests with deposits not used in the training set, 88% of 224 kuroko massive sulfide deposits were classed correctly, 92% of 25 porphyry copper deposits, 78% of 9 Comstock epithermal gold-silver districts, and 83% of six quartzalunite epithermal gold deposits were classed

Ion beam sputter deposited zinc telluride films

NASA Technical Reports Server (NTRS)

Gulino, D. A.

1985-01-01

Zinc telluride is of interest as a potential electronic device material, particularly as one component in an amorphous superlattice, which is a new class of interesting and potentially useful materials. Some structural and electronic properties of ZnTe films deposited by argon ion beam sputter depoairion are described. Films (up to 3000 angstroms thick) were deposited from a ZnTe target. A beam energy of 1000 eV and a current density of 4 mA/sq. cm. resulted in deposition rates of approximately 70 angstroms/min. The optical band gap was found to be approximately 1.1 eV, indicating an amorphous structure, as compared to a literature value of 2.26 eV for crystalline material. Intrinsic stress measurements showed a thickness dependence, varying from tensile for thicknesses below 850 angstroms to compressive for larger thicknesses. Room temperature conductivity measurement also showed a thickness dependence, with values ranging from 1.86 x to to the -6/ohm. cm. for 300 angstrom film to 2.56 x 10 to the -1/ohm. cm. for a 2600 angstrom film. Measurement of the temperature dependence of the conductivity for these films showed complicated behavior which was thickness dependent. Thinner films showed at least two distinct temperature dependent conductivity mechanisms, as described by a Mott-type model. Thicker films showed only one principal conductivity mechanism, similar to what might be expected for a material with more crystalline character.

Methods, quality assurance, and data for assessing atmospheric deposition of pesticides in the Central Valley of California

USGS Publications Warehouse

Zamora, Celia; Majewski, Michael S.; Foreman, William T.

2013-01-01

The U.S. Geological Survey monitored atmospheric deposition of pesticides in the Central Valley of California during two studies in 2001 and 2002–04. The 2001 study sampled wet deposition (rain) and storm-drain runoff in the Modesto, California, area during the orchard dormant-spray season to examine the contribution of pesticide concentrations to storm runoff from rainfall. In the 2002–04 study, the number and extent of collection sites in the Central Valley were increased to determine the areal distribution of organophosphate insecticides and other pesticides, and also five more sample types were collected. These were dry deposition, bulk deposition, and three sample types collected from a soil box: aqueous phase in runoff, suspended sediment in runoff, and surficial-soil samples. This report provides concentration data and describes methods and quality assurance of sample collection and laboratory analysis for pesticide compounds in all samples collected from 16 sites. Each sample was analyzed for 41 currently used pesticides and 23 pesticide degradates, including oxygen analogs (oxons) of 9 organophosphate insecticides. Analytical results are presented by sample type and study period. The median concentrations of both chloryprifos and diazinon sampled at four urban (0.067 micrograms per liter [μg/L] and 0.515 μg/L, respectively) and four agricultural sites (0.079 μg/L and 0.583 μg/L, respectively) during a January 2001 storm event in and around Modesto, Calif., were nearly identical, indicating that the overall atmospheric burden in the region appeared to be fairly similar during the sampling event. Comparisons of median concentrations in the rainfall to those in the McHenry storm-drain runoff showed that, for some compounds, rainfall contributed a substantial percentage of the concentration in the runoff; for other compounds, the concentrations in rainfall were much greater than in the runoff. For example, diazinon concentrations in rainfall were about

Controls on Mississippi Valley-Type Zn-Pb mineralization in Behabad district, Central Iran: Constraints from spatial and numerical analyses

NASA Astrophysics Data System (ADS)

Parsa, Mohammad; Maghsoudi, Abbas

2018-04-01

The Behabad district, located in the central Iranian microcontinent, contains numerous epigenetic stratabound carbonate-hosted Zn-Pb ore bodies. The mineralizations formed as fault, fracture and karst fillings in the Permian-Triassic formations, especially in Middle Triassic dolostones, and comprise mainly non-sulfides zinc ores. These are all interpreted as Mississippi Valley-type (MVT) base metal deposits. From an economic geological point of view, it is imperative to recognize the processes that have plausibly controlled the emplacement of MVT Zn-Pb mineralization in the Behabad district. To address the foregoing issue, analyses of the spatial distribution of mineral deposits comprising fry and fractal techniques and analysis of the spatial association of mineral deposits with geological features using distance distribution analysis were applied to assess the regional-scale processes that could have operated in the distribution of MVT Zn-Pb deposits in the district. The obtained results based on these analytical techniques show the main trends of the occurrences are NW-SE and NE-SW, which are parallel or subparallel to the major northwest and northeast trending faults, supporting the idea that these particular faults could have acted as the main conduits for transport of mineral-bearing fluids. The results of these analyses also suggest that Permian-Triassic brittle carbonate sedimentary rocks have served as the lithological controls on MVT mineralization in the Behabad district as they are spatially and temporally associated with mineralization.

Mineralogy and fluid inclusions study of carbonate-hosted Mississippi valley-type Ain Allega Pb-Zn-Sr-Ba ore deposit, Northern Tunisia

NASA Astrophysics Data System (ADS)

Abidi, R.; Slim-Shimi, N.; Somarin, A.; Henchiri, M.

2010-05-01

The Ain Allega Pb-Zn-Sr-Ba ore deposit is located in the flysch zone on the Eastern edge of the Triassic diapir of Jebel Hamra. It is part of the extrusive Triassic evaporate formation along the Ghardimaou-Cape Serrat faults. The ore body consists of argilic-dolomite breccias surrounded by argilo-gypsum Triassic formation, which forms the hanging wall of the deposit, and rimmed by the Paleocene marls. The ore minerals show a cap-rock type mineralization with different styles particularly impregnation in dolomite, cement of breccias, replacement ore and open space filling in the dissolution cavities and fractures. Ore minerals include sphalerite, galena, marcasite and pyrite. Principal gangue minerals are composed of barite, celestite, calcite, dolomite and quartz. The ore minerals are hosted by the Triassic carbonate rocks which show hydrothermal alteration, dissolution and brecciation. X-ray - crystallographic study of barite-celestite mineral series shows that pure barite and celestite are the abundant species, whereas strontianiferous barite (85-96.5% BaSO 4) and barian-celestite (95% SrSO 4) are minor. Primary and secondary mono-phase (liquid only) fluid inclusions are common in celestite. Microthermometric analyses in two-phases (liquid and vapour) fluid inclusions suggest that gangue and ore minerals were precipitated by a low-temperature (180 °C) saline (16.37 wt.% NaCl equivalent) solution originated possibly from a basinal brine with some input from magmatic or metamorphic fluid. Based on geology, mineralogy, texture and fluid characteristics, the Ain Allega deposit is classified as a carbonate-hosted Mississippi valley-type deposit.

VALDRIFT 1.0: A valley atmospheric dispersion model with deposition

DOE Office of Scientific and Technical Information (OSTI.GOV)

Allwine, K.J.; Bian, X.; Whiteman, C.D.

1995-05-01

VALDRIFT version 1.0 is an atmospheric transport and diffusion model for use in well-defined mountain valleys. It is designed to determine the extent of ddft from aedal pesticide spraying activities, but can also be applied to estimate the transport and diffusion of various air pollutants in valleys. The model is phenomenological -- that is, the dominant meteorological processes goveming the behavior of the valley atmosphere are formulated explicitly in the model, albeit in a highly parameterized fashion. The key meteorological processes treated are: (1) nonsteady and nonhomogeneous along-valley winds and turbulent diffusivities, (2) convective boundary layer growth, (3) inversion descent,more » (4) noctumal temperature inversion breakup, and (5) subsidence. The model is applicable under relatively cloud-free, undisturbed synoptic conditions and is configured to operate through one diumal cycle for a single valley. The inputs required are the valley topographical characteristics, pesticide release rate as a function of time and space, along-valley wind speed as a function of time and space, temperature inversion characteristics at sunrise, and sensible heat flux as a function of time following sunrise. Default values are provided for certain inputs in the absence of detailed observations. The outputs are three-dimensional air concentration and ground-level deposition fields as a function of time.« less

Relative toxicity of lead and selected substitute shot types to game farm mallards

USGS Publications Warehouse

Irby, H.D.; Locke, L.N.; Bagley, George E.

1967-01-01

The acute toxicity of lead, three types of plastic-coated lead, two lead-magnesium alloys, iron, copper, zinc-coated iron, and molybdenum-coated iron shot were tested in year-old male game farm mallards. Mallards (Anus platyrhynchos) were fed eight number 6 shot of each type and observed for a period of 60 days. Ducks used totaled 230 and most shot types were tested in three replicates of 8 ducks each. Mortality and losses of body weight were the criteria used for judging toxicity. Three types of plastic-coated lead shot were as toxic (93 percent) as the commercial lead shot (96 percent). The average mortality in mallards fed lead-magnesium alloy shot was less (58 percent) than that occurring in birds fed commercial lead shot. Mortality among mallards fed iron, copper, zinc-coated iron or molybdenum-coated iron shot was significantly less than in birds fed lead shot, and was not significantly greater than the conrtols.

Chemical vapor deposition of fluorine-doped zinc oxide

DOEpatents

Gordon, Roy G.; Kramer, Keith; Liang, Haifan

2000-06-06

Fims of fluorine-doped zinc oxide are deposited from vaporized precursor compounds comprising a chelate of a dialkylzinc, such as an amine chelate, an oxygen source, and a fluorine source. The coatings are highly electrically conductive, transparent to visible light, reflective to infrared radiation, absorbing to ultraviolet light, and free of carbon impurity.

Lead Isotope Geochemistry of Mississippi Valley-Type Pb-Zn Deposits of the Ozark Region, U.S. Midcontinent: Constraints on the Origin of Ore Metals

NASA Astrophysics Data System (ADS)

Potra, A.

2015-12-01

The Ozark region of the U.S. midcontinent is one of the world's most important provinces of MVT mineralization, hosting world-class ore deposits. The ores in the Tri-State (TS) and Northern Arkansas (NA) districts, dominated by sphalerite, are mainly hosted by platform carbonate rocks and vary in age from Ordovician and Mississippian for NA and Mississippian for TS. The deposits are considered to have formed from a regional hydrothermal flow system consisting of sedimentary brines discharged from the Arkoma basin and adjacent platform during the Late Pennsylvanian to Early Permian Ouachita orogeny. New MC-ICP-MS Pb isotope analyses of sphalerites are presented in order to compare and contrast the isotopic signature of ores from the NA and TS districts with those from other MVT districts from central and eastern US and trace metal sources. The Pb isotope ratios of ores from the TS District (208Pb/204Pb between 40.7443 and 41.2626; 207Pb/204Pb between 15.8633 and 15.9571; 206Pb/204Pb between 21.8373 and 22.1956) plot in an area that is superimposed on the Pb isotope field defined by samples from the Central Missouri District, suggesting similar metal sources. The sphalerites are less radiogenic than samples from the Upper Mississippi Valley District, but more radiogenic than samples from any other MVT district. Sphalerites from the NA District have lower Pb isotope values (208Pb/204Pb between 39.4633 and 40.8863; 207Pb/204Pb between 15.8216 and 15.9176; 206Pb/204Pb between 20.2396 and 21.6438) than the TS District ores; they plot below the field defined by samples from the Illinois-Kentucky district and overlap the field defined by ores from the Southeast Missouri (Viburnum and Old Lead Belt) district, implying similar metal sources. Current data suggest that basement of Grenvillian age (1 - 1.2 by), thought to be present in Arkansas, to the south of the Viburnum Trend, may be a likely source of the radiogenic Pb component. Pb data from ores in the NA and the

25 CFR 215.25 - Other minerals and deep-lying lead and zinc minerals.

Code of Federal Regulations, 2010 CFR

2010-04-01

... 25 Indians 1 2010-04-01 2010-04-01 false Other minerals and deep-lying lead and zinc minerals. 215... LEAD AND ZINC MINING OPERATIONS AND LEASES, QUAPAW AGENCY § 215.25 Other minerals and deep-lying lead and zinc minerals. Except as provided in § 215.6(b), leases on Quapaw Indian lands, for mining...

25 CFR 215.25 - Other minerals and deep-lying lead and zinc minerals.

Code of Federal Regulations, 2011 CFR

2011-04-01

... 25 Indians 1 2011-04-01 2011-04-01 false Other minerals and deep-lying lead and zinc minerals. 215... LEAD AND ZINC MINING OPERATIONS AND LEASES, QUAPAW AGENCY § 215.25 Other minerals and deep-lying lead and zinc minerals. Except as provided in § 215.6(b), leases on Quapaw Indian lands, for mining...

25 CFR 215.21 - Payment of gross production tax on lead and zinc.

Code of Federal Regulations, 2013 CFR

2013-04-01

... 25 Indians 1 2013-04-01 2013-04-01 false Payment of gross production tax on lead and zinc. 215.21 Section 215.21 Indians BUREAU OF INDIAN AFFAIRS, DEPARTMENT OF THE INTERIOR ENERGY AND MINERALS LEAD AND ZINC MINING OPERATIONS AND LEASES, QUAPAW AGENCY § 215.21 Payment of gross production tax on lead and zinc. The superintendent of the Quapaw...

25 CFR 215.21 - Payment of gross production tax on lead and zinc.

Code of Federal Regulations, 2014 CFR

2014-04-01

... 25 Indians 1 2014-04-01 2014-04-01 false Payment of gross production tax on lead and zinc. 215.21 Section 215.21 Indians BUREAU OF INDIAN AFFAIRS, DEPARTMENT OF THE INTERIOR ENERGY AND MINERALS LEAD AND ZINC MINING OPERATIONS AND LEASES, QUAPAW AGENCY § 215.21 Payment of gross production tax on lead and zinc. The superintendent of the Quapaw...

Geochemical and mineralogical characterization of the abandoned Valzinco (lead-zinc) and Mitchell (gold) mine sites prior to reclamation, Spotsylvania County, Virginia

USGS Publications Warehouse

Hammarstrom, Jane M.; Johnson, Adam N.; Seal, Robert R.; Meier, Allen L.; Briggs, Paul L.; Piatak, Nadine M.

2006-01-01

The Virginia gold-pyrite belt, part of the central Virginia volcanic-plutonic belt, hosts numerous abandoned metal mines. The belt extends from about 50 km south of Washington, D.C., for approximately 175 km to the southwest into central Virginia. The rocks that comprise the belt include metamorphosed volcanic and clastic (noncarbonate) sedimentary rocks that were originally deposited during the Ordovician). Deposits that were mined can be classified into three broad categories: 1. volcanic-associated massive sulfide deposits, 2. low-sulfide quartz-gold vein deposits, 3. gold placer deposits, which result from weathering of the vein deposits The massive sulfide deposits were historically mined for iron and pyrite (sulfur), zinc, lead, and copper but also yielded byproduct gold and silver. The most intensely mineralized and mined section of the belt is southwest of Fredericksburg, in the Mineral district of Louisa and Spotsylvania counties. The Valzinco Piatak lead-zinc mine and the Mitchell gold prospect are abandoned sites in Spotsylvania County. As a result of environmental impacts associated with historic mining, both sites were prioritized for reclamation under the Virginia Orphaned Land Program administered by the Virginia Department of Mines, Minerals, and Energy (VDMME). This report summarizes geochemical data for all solid sample media, along with mineralogical data, and results of weathering experiments on Valzinco tailings and field experiments on sediment accumulation in Knights Branch. These data provide a framework for evaluating water-rock interactionsand geoenvironmental signatures of long-abandoned mines developed in massive sulfide deposits and low-sulfide gold-quartz vein deposits in the humid temperate ecosystem domain in the eastern United States.

Gigantic landslides versus glacial deposits: on origin of large hummock deposits in Alai Valley, Northern Pamir

NASA Astrophysics Data System (ADS)

Reznichenko, Natalya

2015-04-01

As glaciers are sensitive to local climate, their moraines position and ages are used to infer past climates and glacier dynamics. These chronologies are only valid if all dated moraines are formed as the result of climatically driven advance and subsequent retreat. Hence, any accurate palaeoenvironmental reconstruction requires thorough identification of the landform genesis by complex approach including geomorphological, sedimentological and structural landform investigation. Here are presented the implication of such approach for the reconstruction of the mega-hummocky deposits formation both of glacial and landslide origin in the glaciated Alai Valley of the Northern Pamir with further discussion on these and similar deposits validity for palaeoclimatic reconstructions. The Tibetan Plateau valleys are the largest glaciated regions beyond the ice sheets with high potential to provide the best geological record of glacial chronologies and, however, with higher probabilities of the numerous rock avalanche deposits including those that were initially considered of glacial origin (Hewitt, 1999). The Alai Valley is the largest intermountain depression in the upper reaches of the Amudarja River basin that has captured numerous unidentified extensive hummocky deposits descending from the Zaalai Range of Northern Pamir, covering area in more than 800 km2. Such vast hummocky deposits are usually could be formed either: 1) glacially by rapid glacial retreat due to the climate signal or triggered a-climatically glacial changes, such as glacial surge or landslide impact, or 2) during the landslide emplacement. Combination of sediment tests on agglomerates forming only in rock avalanche material (Reznichenko et al., 2012) and detailed geomorphological and sedimentological descriptions of these deposits allowed reconstructing the glacial deposition in the Koman and Lenin glacial catchments with identification of two gigantic rock avalanches and their relation to this glacial

Evidence for hot Mississippi Valley-type brines in the Reelfoot Rift complex, south-central United States, in Late Pennsylvanian-Early Permian

USGS Publications Warehouse

Leach, D.L.; Apodaca, L.E.; Repetski, J.E.; Powell, J.W.; Rowan, E.L.

1997-01-01

Petrographic and fluid inclusion studies of sparry dolomite cement from Upper Cambrian to Lower Ordovician rocks and conodont thermal-alteration indices provide evidence that hot mississippi valley-type brines were once present in the Reelfoot Rift complex. The cathodoluminescent microstratigraphy of sparry dolomite cement in the Reelfoot Rift resembles that of sparry dolomite cement associated with widespread mississippi valley-type deposition in the Ozark region. If correlative cathodoluminescent zones in the sparry dolomite from the Ozark and Reelfoot Rift regions indicate broadly contemporaneous dolomite deposition, then the results show that the Ozark MVT-type hydrothermal system extended into the Reelfoot region and onto the western flank of the Nashville Dome. Independent evidence supports migration of MVT-type brines into the Ozark region from the Reelfoot Rift complex in late Paleozoic time.

Paramagnetic dysprosium-doped zinc oxide thin films grown by pulsed-laser deposition

DOE Office of Scientific and Technical Information (OSTI.GOV)

Lo, Fang-Yuh, E-mail: fangyuhlo@ntnu.edu.tw; Ting, Yi-Chieh; Chou, Kai-Chieh

2015-06-07

Dysprosium(Dy)-doped zinc oxide (Dy:ZnO) thin films were fabricated on c-oriented sapphire substrate by pulsed-laser deposition with doping concentration ranging from 1 to 10 at. %. X-ray diffraction (XRD), Raman-scattering, optical transmission spectroscopy, and spectroscopic ellipsometry revealed incorporation of Dy into ZnO host matrix without secondary phase. Solubility limit of Dy in ZnO under our deposition condition was between 5 and 10 at. % according to XRD and Raman-scattering characteristics. Optical transmission spectroscopy and spectroscopic ellipsometry also showed increase in both transmittance in ultraviolet regime and band gap of Dy:ZnO with increasing Dy density. Zinc vacancies and zinc interstitials were identified by photoluminescencemore » spectroscopy as the defects accompanied with Dy incorporation. Magnetic investigations with a superconducting quantum interference device showed paramagnetism without long-range order for all Dy:ZnO thin films, and a hint of antiferromagnetic alignment of Dy impurities was observed at highest doping concentration—indicating the overall contribution of zinc vacancies and zinc interstitials to magnetic interaction was either neutral or toward antiferromagnetic. From our investigations, Dy:ZnO thin films could be useful for spin alignment and magneto-optical applications.« less

Formation of the Wiesloch Mississippi Valley-type Zn-Pb-Ag deposit in the extensional setting of the Upper Rhinegraben, SW Germany

USGS Publications Warehouse

Pfaff, Katharina; Hildebrandt, Ludwig H.; Leach, David L.; Jacob, Dorrit E.; Markl, Gregor

2010-01-01

The Mississippi Valley-type (MVT) Zn-Pb-Ag deposit in the Wiesloch area, Southwest Germany, is controlled by graben-related faults of the Upper Rhinegraben. Mineralization occurs as vein fillings and irregular replacement ore bodies consisting of sphalerite, banded sphalerite, galena, pyrite, sulfosalts (jordanite and geocronite), barite, and calcite in the Middle Triassic carbonate host rock. Combining paragenetic information, fluid inclusion investigations, stable isotope and mineral chemistry with thermodynamic modeling, we have derived a model for the formation of the Wiesloch deposit. This model involves fluid mixing between ascending hot brines (originating in the crystalline basement) with sedimentary formation waters. The ascending brines originally had a near-neutral pH (around 6) and intermediate oxidation state, reflecting equilibrium with granites and gneisses in the basement. During fluid ascent and cooling, the pH of the brine shifted towards more acidic (around 4) and the oxidation state increased to conditions above the hematite-magnetite buffer. These chemical characteristics contrast strongly with those of the pore and fracture fluid residing in the limestone aquifer, which had a pH between 8 and 9 in equilibrium with calcite and was rather reduced due to the presence of organic matter in the limestone. Mixing between these two fluids resulted in a strong decrease in the solubility of silver-bearing sphalerite and galena, and calcite. Besides Wiesloch, several Pb-Zn deposits are known along the Upper Rhinegraben, including hydrothermal vein-type deposits like Badenweiler and the Michael mine near Lahr. They all share the same fluid origin and formation process and only differ in details of their host rock and fluid cooling paths. The mechanism of fluid mixing also seems to be responsible for the formation of other MVT deposits in Europe (e.g., Reocin, Northern Spain; Treves, Southern France; and Cracow-Silesia, Poland), which show notable

Permissive tracts for sediment-hosted lead-zinc-silver deposits in Mauritania (phase V, deliverable 72): Chapter J1 in Second projet de renforcement institutionnel du secteur minier de la République Islamique de Mauritanie (PRISM-II)

USGS Publications Warehouse

Mauk, Jeffrey L.; Horton, John D.

2012-01-01

This report contains the USGS results of the PRISM-II Mauritania Minerals Project and is presented in cooperation with the Ministry of Petroleum, Energy, and Mines of the Islamic Republic of Mauritania. The Report is composed of separate chapters consisting of multidisciplinary interpretive reports with accompanying plates on the geology, structure, geochronology, geophysics, hydrogeology, geochemistry, remote sensing (Landsat TM and ASTER), and SRTM and ASTER digital elevation models of Mauritania. The syntheses of these multidisciplinary data formed the basis for additional chapters containing interpretive reports on 12 different commodities and deposit types known to occur in Mauritania, accompanied by countrywide mineral resource potential maps of each commodity/deposit type. The commodities and deposit types represented include: (1) Ni, Cu, PGE, and Cr deposits hosted in ultramafic rocks; (2) orogenic, Carlin-like, and epithermal gold deposits; (3) polymetallic Pb-Zn-Cu vein deposits; (4) sediment-hosted Pb-Zn-Ag deposits of the SEDEX and Mississippi Valley-type; (5) sediment-hosted copper deposits; ( 6) volcanogenic massive sulfide deposits; (7) iron oxide copper-gold deposits; (8) uranium deposits; (9) Algoma-, Superior-, and oolitic-type iron deposits; (10) shoreline Ti-Zr placer deposits; (11) incompatible element deposits hosted in pegmatites, alkaline rocks, and carbonatites, and; (12) industrial mineral deposits. Additional chapters include the Mauritanian National Mineral Deposits Database are accompanied by an explanatory text and the Mauritania Minerals Project GIS that contains all of the interpretive layers created by USGS scientists. Raw data not in the public domain may be obtained from the Ministry of Petroleum, Energy, and Mines in Nouakchott, Mauritania.

Nitrogen and sulfur deposition and forest nutrient status in the Valley of Mexico

Treesearch

M. E. Fenn; L. I. de Bauer; A. Quevedo-Nolasco; Rodriquez-Frausto-C.

1999-01-01

Mexico City experiences some of the most severe air pollution in the world. Ozone injury has been documented in sensitive tree species in urban and forested areas in the Valley of Mexico. However, little is known of the levels of other atmospheric pollutants and their ecological effects on forests in the Valley of Mexico. In this study bulk throughfall deposition of...

25 CFR 215.21 - Payment of gross production tax on lead and zinc.

Code of Federal Regulations, 2010 CFR

2010-04-01

... 25 Indians 1 2010-04-01 2010-04-01 false Payment of gross production tax on lead and zinc. 215.21... ZINC MINING OPERATIONS AND LEASES, QUAPAW AGENCY § 215.21 Payment of gross production tax on lead and zinc. The superintendent of the Quapaw Indian Agency is hereby authorized and directed to pay at the...

25 CFR 215.21 - Payment of gross production tax on lead and zinc.

Code of Federal Regulations, 2011 CFR

2011-04-01

... 25 Indians 1 2011-04-01 2011-04-01 false Payment of gross production tax on lead and zinc. 215.21... ZINC MINING OPERATIONS AND LEASES, QUAPAW AGENCY § 215.21 Payment of gross production tax on lead and zinc. The superintendent of the Quapaw Indian Agency is hereby authorized and directed to pay at the...

Release of iron, zinc, and lead from common iron construction bars and zinc metallic bars in water solutions and meals.

PubMed

Lechtig, Aarón; Lòpez de Romaña, Daniel; Boy, Erick; Vargas, Alejandro; Rosas del Portal, Mauricio; Huaylinos, María Luisa

2007-12-01

The use of iron pots has decreased the prevalence of anemia. To investigate the release of iron, zinc, and lead from metallic iron and zinc bars incubated in water and in meals. Iron, zinc, and lead concentrations were measured at different incubation conditions in water and in meals. The iron concentration in water was 1.26 mg/L after incubation with one iron bar at pH 7 and 100 degrees C for 20 minutes and in meals was 0.97 mg per 100 g of wet meals, rich in phytate, cooking at 100 degrees C during 20 minutes. The maximum contents were 7720 mg/L of iron and 1826 mg/L of zinc in vinegar at pH 3 and 20 degrees C after 90 and 32 days, respectively. Lead was released from the bars, but at concentrations well below the upper tolerable limits. In outreach populations, the use of iron and zinc metallic bars in water and meals could contribute to sustainable, very low-cost prevention of iron and zinc deficiencies, and home-fortified vinegar could be used for treatment of both deficiencies. Field trials should be performed to determine the impact that the use of iron and zinc metallic bars in water and meals might have on the iron and zinc status of population groups.

Accumulation of metals in fish from lead-zinc mining areas of southeastern Missouri, USA

USGS Publications Warehouse

Schmitt, Christopher J.; Brumbaugh, William G.; May, Thomas W.

2007-01-01

The potential effects of proposed lead-zinc mining in an ecologically sensitive area were assessed by studying a nearby mining district that has been exploited for about 30 yr under contemporary environmental regulations and with modern technology. Blood and liver samples representing fish of three species (largescale stoneroller, Campostoma oligolepis, n=91; longear sunfish, Lepomis megalotis, n=105; and northern hog sucker, Hypentelium nigricans, n=20) were collected from 16 sites representing a range of conditions relative to lead-zinc mining and ore beneficiation in southeastern Missouri. Samples were analyzed for lead, zinc, and cadmium, and for a suite of biomarkers (reported in a companion paper). A subset of the hog sucker (n=9) representing three sites were also analyzed for nickel and cobalt. Blood and liver lead concentrations were highly correlated (r=0.84-0.85, P < 0.01) in all three species and were significantly (ANOVA, P < 0.01) greater at sites < 10 km downstream of active lead-zinc mines and mills and in a historical lead-zinc mining area than at reference sites, including a site in the area proposed for new mining. Correlations between blood and liver cadmium concentrations were less evident than for lead but were nevertheless statistically significant (r=0.26-0.69, P < 0.01-0.07). Although blood and liver cadmium concentrations were highest in all three species at sites near mines, within-site variability was greater and mining-related trends were less evident than for lead. Blood and liver zinc concentrations were significantly correlated only in stoneroller (r=0.46, P < 0.01) and mining-related trends were not evident. Concentrations of cobalt and nickel in blood and liver were significantly higher (ANOVA, P < 0.01) at a site near an active mine than at a reference site and a site in the historical lead-zinc mining area. These findings confirm previous studies indicating that lead and other metals are released to streams from active lead-zinc

Accumulation of metals in fish from lead-zinc mining areas of southeastern Missouri, USA.

PubMed

Schmitt, Christopher J; Brumbaugh, William G; May, Thomas W

2007-05-01

The potential effects of proposed lead-zinc mining in an ecologically sensitive area were assessed by studying a nearby mining district that has been exploited for about 30 yr under contemporary environmental regulations and with modern technology. Blood and liver samples representing fish of three species (largescale stoneroller, Campostoma oligolepis, n=91; longear sunfish, Lepomis megalotis, n=105; and northern hog sucker, Hypentelium nigricans, n=20) were collected from 16 sites representing a range of conditions relative to lead-zinc mining and ore beneficiation in southeastern Missouri. Samples were analyzed for lead, zinc, and cadmium, and for a suite of biomarkers (reported in a companion paper). A subset of the hog sucker (n=9) representing three sites were also analyzed for nickel and cobalt. Blood and liver lead concentrations were highly correlated (r=0.84-0.85, P<0.01) in all three species and were significantly (ANOVA, P<0.01) greater at sites <10 km downstream of active lead-zinc mines and mills and in a historical lead-zinc mining area than at reference sites, including a site in the area proposed for new mining. Correlations between blood and liver cadmium concentrations were less evident than for lead but were nevertheless statistically significant (r=0.26-0.69, P <0.01-0.07). Although blood and liver cadmium concentrations were highest in all three species at sites near mines, within-site variability was greater and mining-related trends were less evident than for lead. Blood and liver zinc concentrations were significantly correlated only in stoneroller (r=0.46, P<0.01) and mining-related trends were not evident. Concentrations of cobalt and nickel in blood and liver were significantly higher (ANOVA, P<0.01) at a site near an active mine than at a reference site and a site in the historical lead-zinc mining area. These findings confirm previous studies indicating that lead and other metals are released to streams from active lead-zinc mines and

Massive deep-sea sulphide ore deposits discovered on the East Pacific Rise

USGS Publications Warehouse

Francheteau, Jean; Needham, H.D.; Choukroune, P.; Juteau, Tierre; Seguret, M.; Ballard, Richard D.; Fox, P.J.; Normark, William; Carranza, A.; Cordoba, D.; Guerrero, J.; Rangin, C.; Bougault, H.; Cambon, P.; Hekinian, R.

1979-01-01

Massive ore-grade zinc, copper and iron sulphide deposits have been found at the axis of the East Pacific Rise. Although their presence on the deep ocean-floor had been predicted there was no supporting observational evidence. The East Pacific Rise deposits represent a modern analogue of Cyprus-type sulphide ores associated with ophiolitic rocks on land. They contain at least 29% zinc metal and 6% metallic copper. Their discovery will provide a new focus for deep-sea exploration, leading to new assessments of the concentration of metals in the upper layers of the oceanic crust. ?? 1979 Nature Publishing Group.

25 CFR 215.25 - Other minerals and deep-lying lead and zinc minerals.

Code of Federal Regulations, 2014 CFR

2014-04-01

... 25 Indians 1 2014-04-01 2014-04-01 false Other minerals and deep-lying lead and zinc minerals. 215.25 Section 215.25 Indians BUREAU OF INDIAN AFFAIRS, DEPARTMENT OF THE INTERIOR ENERGY AND MINERALS LEAD AND ZINC MINING OPERATIONS AND LEASES, QUAPAW AGENCY § 215.25 Other minerals and deep-lying lead...

25 CFR 215.25 - Other minerals and deep-lying lead and zinc minerals.

Code of Federal Regulations, 2012 CFR

2012-04-01

... 25 Indians 1 2012-04-01 2011-04-01 true Other minerals and deep-lying lead and zinc minerals. 215.25 Section 215.25 Indians BUREAU OF INDIAN AFFAIRS, DEPARTMENT OF THE INTERIOR ENERGY AND MINERALS LEAD AND ZINC MINING OPERATIONS AND LEASES, QUAPAW AGENCY § 215.25 Other minerals and deep-lying lead...

25 CFR 215.25 - Other minerals and deep-lying lead and zinc minerals.

Code of Federal Regulations, 2013 CFR

2013-04-01

... 25 Indians 1 2013-04-01 2013-04-01 false Other minerals and deep-lying lead and zinc minerals. 215.25 Section 215.25 Indians BUREAU OF INDIAN AFFAIRS, DEPARTMENT OF THE INTERIOR ENERGY AND MINERALS LEAD AND ZINC MINING OPERATIONS AND LEASES, QUAPAW AGENCY § 215.25 Other minerals and deep-lying lead...

Research keeps lead and zinc viable in high-tech markets

NASA Astrophysics Data System (ADS)

Cole, Jerome F.

1989-08-01

Lead and zinc have long enjoyed widespread use in a variety of applications. To insure growing markets for the future, however, new applications for these durable metals must be developed. Currently, projects are underway to determine the capabilities of lead for such high-technology uses as earthquake damping and nuclear waste containment. Zinc's capabilities are being developed further, too, particularly in the areas of direct injection die casting, composites and the improvement of coating properties. Other ongoing research initiatives are attempting to better determine the health and environmental influences of these metals.

25 CFR 215.21 - Payment of gross production tax on lead and zinc.

Code of Federal Regulations, 2012 CFR

2012-04-01

... 25 Indians 1 2012-04-01 2011-04-01 true Payment of gross production tax on lead and zinc. 215.21 Section 215.21 Indians BUREAU OF INDIAN AFFAIRS, DEPARTMENT OF THE INTERIOR ENERGY AND MINERALS LEAD AND ZINC MINING OPERATIONS AND LEASES, QUAPAW AGENCY § 215.21 Payment of gross production tax on lead and...

Paragenetic and minor- and trace-element studies of Mississippi Valley-type ore deposits of the Silesian-Cracow district, Poland

USGS Publications Warehouse

Viets, J.G.; Leach, D.L.; Lichte, F.E.; Hopkins, R.T.; Gent, C.A.; Powell, J.W.

1996-01-01

Paragenetic and minor- and trace-element studies were conducted on samples of epigenetic ore and gangue minerals collected from mines and drill core in the Silesian-Cracow (S-C) district of southern Poland. Four discrete mineral suites representing four mineralizing stages can be identified throughout the district. The earliest epigenetic minerals deposited during stage 1 consist of a late dolomite cement together with minor pyrite and marcasite. Stage 2 was the first ore-forming stage and included repetitive deposition of sphalerite and galena in a variety of morphologies. Stage 3 abruptly followed the first ore stage and deposited marcasite and pyrite with variable amounts of late sphalerite and galena. In the samples studied, minerals deposited during stage 3 are predominately marcasite-pyrite with minor sphalerite and galena in the Pomorzany and Olkusz mines, whereas, at the Trzebionka mine, stage 3 mineralization deposited mostly galena and sphalerite with little marcasite or pyrite. Stage 4 minerals include contains barite, followed by calcite, with very minor pyrite and a rare, late granular sphalerite. Compared to other major Mississippi Valley-type (MVT) districts of the world, the Silesian-Cracow district contains sphalerite with the second largest range in Ag concentrations and the largest range in Fe and Cd concentrations of any district. Unlike in other districts, very wide ranges in minor- and trace-element concentrations are also observed in paragenetically equivalent samples collected throughout the district. This wide range indicates that the minor- and trace-element content of the ore-forming environment was highly variable, both spatially and temporally, and suggests that the hydrologic system that the ore fluids traversed from their basinal source was very complex. Throughout the district, a significant increase in Tl, Ge, and As concentrations is accompanied by a lightening of sulfur isotopes between stage 2 and stage 3 minerals. This change

LEAD AND COPPER CONTROL WITH NON-ZINC ORTHOPHOSPHATE

EPA Science Inventory

Successful application of orthophosphate formulations not containing zinc for achieving control of copper and lead corrosion requires careful consideration of the background water chemistry, particularly pH and DIC. Inhibitor performance is extremely dependent upon dosage and pH,...

Source of lead and mineralizing brines for rossie-type Pb-Zn veins in the Frontenac axis area, New York ( USA).

USGS Publications Warehouse

Ayuso, Robert; Foley, Nora K.; Brown, C. Erwin

1987-01-01

The present study of fluid inclusions and lead isotopes was done to understand better the nature and possible source of the mineralizing solutions for both vertical and gash veins and the possible origin of the lead and zinc mineralization. Large deposits of essentially syngenetic sphalerite with minor to trace galena occur in the Proterozoic rocks of this region (e.g., Balmat-Edwards, New York). Although none of these deposits are known in the immediate vicinity of Rossie veins, the possibility that Rossie veins contain remobilized metals from these older deposits was considered.

On the problem of zinc extraction from the slags of lead heat

NASA Astrophysics Data System (ADS)

Kozyrev, V. V.; Besser, A. D.; Paretskii, V. M.

2013-12-01

The possibilities of zinc extraction from the slags of lead heat are studied as applied to the ZAO Karat-TsM lead plant to be built for processing ore lead concentrates. The process of zinc extraction into commercial fumes using the technology of slag fuming by natural gas developed in Gintsvetmet is recommended for this purpose. Technological rules are developed for designing a commercial fuming plant, as applied to the conditions of the ZAO Karat-TsM plant.

Zinc and lead detoxifying abilities of humic substances relevant to environmental bacterial species.

PubMed

Perelomov, L V; Sarkar, Binoy; Sizova, O I; Chilachava, K B; Shvikin, A Y; Perelomova, I V; Atroshchenko, Y M

2018-04-30

The effect of humic substances (HS) and their different fractions (humic acids (HA) and hymatomelanic acids (HMA)) on the toxicity of zinc and lead to different strains of bacteria was studied. All tested bacteria demonstrated a lower resistance to zinc than lead showing minimum inhibitory concentrations of 0.1 - 0.3mM and 0.3-0.5mM, respectively. The highest resistance to lead was characteristic of Pseudomonas chlororaphis PCL1391 and Rhodococcus RS67, while Pseudomonas chlororaphis PCL1391 showed the greatest resistance to zinc. The combined fractions of HS and HA alone reduced zinc toxicity at all added concentrations of the organic substances (50 - 200mgL -1 ) to all microorganisms, while hymatomelanic acids reduced zinc toxicity to Pseudomonas chlororaphis PCL1391 at 200mgL -1 organic concentration only. The HS fractions imparted similar effects on lead toxicity also. This study demonstrated that heavy metal toxicity to bacteria could be reduced through complexation with HS and their fractions. This was particularly true when the metal-organic complexes held a high stability, and low solubility and bioavailability. Copyright © 2018 Elsevier Inc. All rights reserved.

Depositional environments of the uranium-bearing Cutler Formations, Lisbon Valley, Utah

USGS Publications Warehouse

Campbell, John A.; Steele-Mallory, Brenda A.

1979-01-01

The Cutler Formation in Lisbon Valley, San Juan County, Utah, is composed predominantly of fluvial arkosic sandstones, siltstones, shales, and mudstones that were deposited by meandering streams that flowed across a flood plain and tidal flat close to sea level. Two types of channel deposits are recognized from their sedimentary structures: meandering and distributary. The flood plain was occasionally transgressed by a shallow sea from the west, resulting in the deposition of several thin limestones and marine sandstones. The marine sandstones were deposited as longshore bars. Wind transported sand along the shoreline of the shallow sea, forming a coastal dune field. Marine sandstones and eolian sandstones are more common in the upper Cutler in the southern part of the area, whereas in the central and northern part of the area the formation is predominantly fluvial. Crossbed orientation indicates that Cutler streams flowed S. 67? W. on the the average, whereas marine currents moved sediment S. 36? E. and N. 24? W., and wind transported sand S. 800 E. The uranium in the Cutler is found in the central and northern part of the area, in the upper part of the formation, in small fluvial sandstone bodies that were deposited predominantly in a distributary environment. No uranium is known in the marine or eolian sandstones. Petrographically, the uranium-bearing sandstones are identical to other Cutler fluvial sandstones except that they contain less calcite and more clay and are slightly coarser grained. Ore formation has modified the host sandstones very little.

Toxicity to woodlice of zinc and lead oxides added to soil litter

USGS Publications Warehouse

Beyer, W.N.; Anderson, A.

1985-01-01

Previous studies have shown that high concentrations of metals in soil are associated with reductions in decomposer populations. We have here determined the relation between the concentrations of lead and zinc added as oxides to soil litter and the survival and reproduction of a decomposer population under controlled conditions. Laboratory populations of woodlice (Porcellio scaber Latr) were fed soil litter treated with lead or zinc at concentrations that ranged from 100 to 12,800 ppm. The survival of the adults, the maximum number of young alive, and the average number of young alive, were recorded over 64 weeks. Lead at 12,800 ppm and zinc at 1,600 ppm or more had statistically significant (p < 0.05) negative effects on the populations. These results agree with field observations suggesting that lead and zinc have reduced populations of decomposers in contaminated forest soil litter, and concentrations are similar to those reported to be associated with reductions in natural populations of decomposers. Poisoning of decomposers may disrupt nutrient cycling, reduce the numbers of invertebrates available to other wildlife for food, and contribute to the contamination of food chains.

An evaluation of airborne nickel, zinc, and lead exposure at hot dip galvanizing plants.

PubMed

Verma, D K; Shaw, D S

1991-12-01

Industrial hygiene surveys were conducted at three hot dip galvanizing plants to determine occupational exposure to nickel, zinc, and lead. All three plants employed the "dry process" and used 2% nickel, by weight, in their zinc baths. A total of 32 personal and area air samples were taken. The air samples were analyzed for nickel, zinc, and lead. Some samples were also analyzed for various species of nickel (i.e., metallic, soluble, and oxidic). The airborne concentrations observed for nickel and its three species, zinc, and lead at the three plants were all well below the current and proposed threshold limit values recommended by the American Conference of Governmental Industrial Hygienists (ACGIH).

Classification of Broken Hill-Type Pb-Zn-Ag Deposits: A Refinement

NASA Astrophysics Data System (ADS)

Spry, P. G.; Teale, G. S.; Steadman, J. A.

2009-05-01

deposits with BHT affinities, and Corruga-type deposits represent transitional deposits between BHT and SEDEX, VMS, and metamorphosed base metal calc-silicate deposits, respectively. Although the non-sulfide zinc deposits at Franklin Furnace and Sterling Hill, NJ, do not contain Pb, they resemble sulfur-poor BHT deposits.

Deposition of zinc sulfide thin films by chemical bath process

NASA Astrophysics Data System (ADS)

Oladeji, Isaiah O.; Chow, Lee

1996-11-01

Deposition of high quality zinc sulfide (ZnS) thin film over a large area is required if it is to be effectively used in electroluminescent devices, solar cells, and other optoelectronic devices. Of all deposition techniques, chemical bath deposition (CBD) is the least costly technique that meets the above requirements. Recently it is found that the growth of ZnS film, of thickness less than 100 nm in a single dip, by CBD is facilitated by the use of ammonia and hydrazine as complexing agents. Here we report that the thickness of the deposited ZnS film can be increased if ammonium salt is used as a buffer. We also present an analytical study to explain our results and to further understand the ZnS growth process in CBD.

Enhanced antibacterial activity and biocompatibility of zinc-incorporated organic-inorganic nanocomposite coatings via electrophoretic deposition.

PubMed

Huang, Pin; Ma, Kena; Cai, Xinjie; Huang, Dan; Yang, Xu; Ran, Jiabing; Wang, Fushi; Jiang, Tao

2017-12-01

Increased use of reconstruction procedures in orthopedics has improved the life of patients undergoing surgery. However, surgical site infection remains a major challenge. Efforts were made to fabricate antibacterial surfaces with good biocompatibility. This present study aimed to fabricate zinc-incorporated chitosan/gelatin (CS/G) nanocomposite coatings on the titanium substrates via electrophoretic deposition (EPD). Physicochemical characterization confirmed that zinc was successfully deposited in a metallic oxide/salt complex status. Transmission electron microscopic (TEM) results observed formation of core-shell nanosized particles released from the coatings. The selected-area electron diffraction (SAED) pattern of the particles presented faces of ZnO with organic background. Mechanical tests showed improved tensile and shear bond strength between substrates and zinc-incorporated coating surfaces. Zinc-incorporated CS/G coatings presented antibacterial abilities against both Gram-negative E. coli and Gram-positive S. aureus in a concentration-dependent manner. The generation of ZnO/Zn 2+ complex in the coatings may contribute to bacteria inhibition. In vitro study demonstrated that appropriate concentration of zinc could promote proliferative and osteogenic activities of rat bone marrow stromal cells. The present study suggested that zinc-incorporated CS/G coating was a promising candidate for surface modification of biomedical materials. Copyright © 2017 Elsevier B.V. All rights reserved.

Biosorption of lead, cadmium, and zinc by Citrobacter strain MCM B-181: Characterization studies

DOE Office of Scientific and Technical Information (OSTI.GOV)

Puranik, P.R.; Paknikar, K.M.

1999-03-01

The biosorption process for removal of lead, cadmium, and zinc by Citrobacter strain MCM B-181, a laboratory isolate, was characterized. Effects of environmental factors and growth conditions on metal uptake capacity were studied. Pretreatment of biomass with chemical agents increased cadmium sorption efficiency; however, there was no significant enhancement in lead and zinc sorption capacity. Metal sorption by Citrobacter strain MCM B-181 was found to be influenced by the pH of the solution, initial metal concentration, biomass concentration, and type of growth medium. The metal sorption process was not affected by the age of the culture or change in temperature.more » Equilibrium metal sorption was found to fit the Langmuir adsorption model. Kinetic studies showed that metal uptake by Citrobacter strain MCm B-181 was a fast process, requiring < 20 min to achieve > 90% adsorption efficiency. The presence of cations reduced lead, zinc, and cadmium sorption to the extent of 11.8%, 84.3%, and 33.4%, respectively. When biomass was exposed to multimetal solutions, metals were adsorbed in the order Co{sup 2+} < Ni{sup 2+} < Cd{sup 2+} < Cu{sup 2+}, Zn{sup 2+} < Pb{sup 2+}. A new mathematical model used for batch kinetic studies was found to be highly useful in prediction of experimentally obtained metal concentration profiles as a function of time.« less

Chemistry, mineralogy and origin of the clay-hill nitrate deposits, Amargosa River valley, Death Valley region, California, U.S.A.

USGS Publications Warehouse

Ericksen, G.E.; Hosterman, J.W.; St., Amand

1988-01-01

The clay-hill nitrate deposits of the Amargosa River valley, California, are caliche-type accumulations of water-soluble saline minerals in clay-rich soils on saline lake beds of Miocene, Pliocene(?) and Pleistocene age. The soils have a maximum thickness of ??? 50 cm, and commonly consist of three layers: (1) an upper 5-10 cm of saline-free soil; (2) an underlying 15-20 cm of rubbly saline soil; and (3) a hard nitrate-rich caliche, 10-20 cm thick, at the bottom of the soil profile. The saline constituents, which make up as much as 50% of the caliche, are chiefly Cl-, NO-3, SO2-4 and Na+. In addition are minor amounts of K+, Mg2+ and Ca2+, varying, though generally minor, amounts of B2O3 and CO2-3, and trace amounts of I (probably as IO-3), NO-2, CrO2-4 and Mo (probably as MoO2-4). The water-soluble saline materials have an I/Br ratio of ??? 1, which is much higher than nearly all other saline depostis. The principal saline minerals of the caliche are halite (NaCl), nitratite (NaNO3), darapskite (Na3(SO4)(NO3)??H2O), glauberite (Na2Ca(SO4)2), gypsum (CaSO4??2H2O) and anhydrite (CaSO4). Borax (Na2B4O5(OH)4??8H2O), tincalconite (Na2B4O5(OH)4??3H2O) and trona (Na3(CO3)(HCO3)??2H2O) are abundant locally. The clay-hill nitrate deposits are analogous to the well-known Chilean nitrate deposits, and probably are of similar origin. Whereas the Chilean deposits are in permeable soils of the nearly rainless Atacama Desert, the clay-hill deposits are in relatively impervious clay-rich soils that inhibited leaching by rain water. The annual rainfall in the Death Valley region of ??? 5 cm is sufficient to leach water-soluble minerals from the more permeable soils. The clay-hill deposits contain saline materials from the lake beds beneath the nitrate deposits are well as wind-transported materials from nearby clay-hill soils, playas and salt marshes. The nitrate is probably of organic origin, consisting of atmospheric nitrogen fixed as protein by photoautotrophic blue-green algae

Exploratory drilling in the Prairie du Chien group of the Wisconsin zinc-lead districts by the U.S. Geological Survey in 1949-1950

USGS Publications Warehouse

Heyl, Allen Van; Lyons, Erwin J.; Agnew, Allen F.

1951-01-01

The U. S. Geological Survey in cooperation with the Wisconsin Geological and Natural History Survey explored the Prairie du Chien group in the main productive area of the Wisconsin zinc-lead district during 1949-50. Eight properties--Crow Branch diggings, Leix, Harris, Spitzbarth, Kennedy, James, Raisbeck and Vinegar Hill Roaster--were explored using both diamond and churn drills. Twenty holes were drilled that totaled 8,582 feet in depth. The objectives of the exploration were to determine if the Prairie du Chien and other formations below the principal ore-bearing strata (Galena, Decorah, and Platteville formations) of the district are favorable for ore deposits, and to determine the type of ore deposits, if present. Lean deposits of sphalerite, marcasite, and pyrite were found in the Prairie du Chien on five properties--Crow Branch, Leix, Harris, Spitzbarth, and Vinegar Hill 1%ouster-and also in the Franconia sandstone on the Leix property. In the drilled area the sulfides in the Prairie du Chien group occur in certain more brittle or soluble dolomite beds that contain cavities formed by brecciation or solution.

Optimization Photodetectors from Zinc Sulfide Deposited on Porous Silicon with Different Doping Metals

NASA Astrophysics Data System (ADS)

Nayef, Uday Muhsin; Khalaf, Haider Amer

In this work, the structural properties of the zinc sulfide (ZnS) films have been investigated using X-ray diffraction (XRD) analysis which show an enhancement in the crystallite degree after doping with copper (Cu). Good matching between the ZnS and porous silicon (PS) structure was noted from the atomic force microscope (AFM) results. The reflectivity gave a clear observation of anti-reflected coating improvement for PS layer and more enhancements after the ZnS deposition. The optical properties show a blue shift in the bandgap for the ZnS deposited with higher substrate temperature and a red shift after doped with different elements. For ZnS/PS heterojunction, the electrical resistivity has been increased after PS layer formed and changed with the variation of the pore size and it was much higher after ZnS deposited on the PS. However, use of ZnS:Cu/PS photodetector showed much higher output current at the ultraviolet (UV) region compared to ZnS/PS. The ZnS:Cu/PS photodetector showed higher output current value than that of the ZnS/PS leading to improvement in the quantum efficiency of 42%.

Topographic, optical and chemical properties of zinc particle coatings deposited by means of atmospheric pressure plasma

NASA Astrophysics Data System (ADS)

Wallenhorst, L. M.; Loewenthal, L.; Avramidis, G.; Gerhard, C.; Militz, H.; Ohms, G.; Viöl, W.

2017-07-01

In this research, topographic, optical and chemical properties of zinc oxide layers deposited by a cold plasma-spray process were measured. Here, zinc micro particles were fed to the afterglow of a plasma spark discharge whereas the substrates were placed in a quite cold zone of the effluent plasma jet. In this vein, almost closed layers were realised on different samples. As ascertained by laser scanning and atomic force microscopic measurements the particle size of the basic layer is in the nanometre scale. Additionally, larger particles and agglomerates were found on its top. The results indicate a partial plasma-induced diminishment of the initial particles, most probably due to melting or vaporisation. It is further shown that the plasma gives rise to an increased oxidation of such particles as confirmed by X-ray photoelectron spectroscopy. Quantitative analysis of the resulting mixed layer was performed. It is shown that the deposited layers consist of zinc oxide and elemental zinc in approximately equal shares. In addition, the layer's band gap energy was determined by spectroscopic analysis. Here, considerable UV blocking properties of the deposited layers were observed. Possible underlying effects as well as potential applications are presented.

Copper, lead and zinc concentrations of human breast milk as affected by maternal dietary practices

DOE Office of Scientific and Technical Information (OSTI.GOV)

Umoren, J.; Kies, C.

1986-03-01

Maternal dietary practices have been found to affect the concentrations of some nutrients in human breast milk. Lead toxicity is a concern in young children. Lead, copper and zinc are thought to compete for intestinal absorption sites. The objective of the current project was to compare copper, lead and zinc contents of breast milk from practicing lacto-vegetarian and omnivore, lactating women at approximately four months post-partum. Analyses were done by atomic absorption spectrophotometry using a carbon rod attachment. Copper concentrations were higher in milk samples from lacto-ovo-vegetarians. Milk samples from the omnivores had the highest lead and zinc concentrations. Leadmore » and copper concentrations in milk were negatively correlated. The higher zinc concentrations in the milk of the omnivore women may have been related to better utilization of zinc from meat than from plant food sources.« less

Atomic absorption spectrometric determination of copper, zinc, and lead in geological materials

USGS Publications Warehouse

Sanzolone, R.F.; Chao, T.T.

1976-01-01

An atomic absorption spectrometric method is described for the determination of copper, zinc, and lead in geological materials. The sample is digested with HF-HCl-H2O2; the final solution for analysis is in 10 % (v/v) HCl. Copper and zinc are determined directly by aspirating the solution into an air-acetylene flame. A separate aliquot of the solution is used for determination of lead; lead is extracted into TOPO-MIBK from the acidic solution in the presence of iodide and ascorbic acid. For a 0.50-g sample, the limits of determination are 10-2000 p.p.m. for Cu and Zn, and 5-5000 p.p.m. for Pb. As much as 40 % Fe or Ca. and 10 % Al, Mg, or Mn in the sample do not interfere. The proposed method can be applied to the determination of copper, zinc, and lead in a wide range of geological materials including iron- and manganese-rich, calcareous and carbonate samples. ?? 1976.

An evaluation of the regional acid deposition model surface module for ozone uptake at three sites in the San Joaquin Valley of California

NASA Technical Reports Server (NTRS)

Massman, W. J.; Pederson, J.; Delany, A.; Grantz, D.; Hertog, G. Den; Neumann, H. H.; Oncley, S. P.; Pearson, R., Jr.; Shaw, R. H.

1994-01-01

Plants and soils act as major sinks for the destruction of tropospheric ozone, especially during daylight hours when plant stomata open and are thought to provide the dominant pathway for the uptake of ozone. The present study, part of the California Ozone Deposition Experiment, compares predictions of the regional acid deposition model ozone surface conductance module with surface conductance data derived from eddy covariance measurements of ozone flux taken at a grape, a cotton, and a grassland site in the San Joaquin Valley of California during the summer of 1991. Results indicate that the model (which was developed to provide long-term large-area estimates for the eastern United States) significantly overpredicts the surface conductance at all times of the day for at least two important types of plant cover of the San Joaquin Valley and that it incorrectly partitions the ozone flux between transpiring and nontranspiring components of the surface at the third site. Consequently, the model either overpredicts or inaccurately represents the observed deposition velocities. Other results indicate that the presence of dew does not reduce the rate of ozone deposition, contradicting to model assumptions, and that model assumptions involving the dependency of stomata upon environmental temperature are unnecessary. The effects of measurement errors and biases, arising from the presence of the roughness sublayer and possible photochemical reactions, are also discussed. A simpler model for ozone surface deposition (at least for the San Joaquin Valley) is proposed and evaluated.

Middle Pleistocene infill of Hinkley Valley by Mojave River sediment and associated lake sediment: Depositional architecture and deformation by strike-slip faults

USGS Publications Warehouse

Miller, David; Haddon, Elizabeth; Langenheim, Victoria; Cyr, Andrew J.; Wan, Elmira; Walkup, Laura; Starratt, Scott W.

2018-01-01

Hinkley Valley in the Mojave Desert, near Barstow about 140 km northeast of Los Angeles and midway between Victorville Valley and the Lake Manix basin, contains a thick sedimentary sequence delivered by the Mojave River. Our study of sediment cores drilled in the valley indicates that Hinkley Valley was probably a closed playa basin with stream inflow from four directions prior to Mojave River inflow. The Mojave River deposited thick and laterally extensive clastic wedges originating from the southern valley that rapidly filled much of Hinkley Valley. Sedimentary facies representing braided stream, wetland, delta, and lacustrine depositional environments all are found in the basin fill; in some places, the sequence is greater than 74 m (245 ft) thick. The sediment is dated in part by the presence of the ~631 ka Lava Creek B ash bed low in the section, and thus represents sediment deposition after Victorville basin was overtopped by sediment and before the Manix basin began to be filled. Evidently, upstream Victorville basin filled with sediment by about 650 ka, causing the ancestral Mojave River to spill to the Harper and Hinkley basins, and later to Manix basin.Initial river sediment overran wetland deposits in many places in southern Hinkley Valley, indicating a rapidly encroaching river system. These sediments were succeeded by a widespread lake (“blue” clay) that includes the Lava Creek B ash bed. Above the lake sediment lies a thick section of interlayered stream sediment, delta and nearshore lake sediment, mudflat and/or playa sediment, and minor lake sediment. This stratigraphic architecture is found throughout the valley, and positions of lake sediment layers indicate a successive northward progression in the closed basin. A thin overlapping sequence at the north end of the valley contains evidence for a younger late Pleistocene lake episode. This late lake episode, and bracketing braided stream deposits of the Mojave River, indicate that the river

Chemical Vapor Deposited Zinc Sulfide. SPIE Press Monograph

DOE Office of Scientific and Technical Information (OSTI.GOV)

McCloy, John S.; Tustison, Randal W.

2013-04-22

Zinc sulfide has shown unequaled utility for infrared windows that require a combination of long-wavelength infrared transparency, mechanical durability, and elevated-temperature performance. This book reviews the physical properties of chemical vapor deposited ZnS and their relationship to the CVD process that produced them. An in-depth look at the material microstructure is included, along with a discussion of the material's optical properties. Finally, because the CVD process itself is central to the development of this material, a brief history is presented.

A Rapid Deposition of Fluorine Doped Zinc Oxide Using the Atmospheric Pressure Chemical Vapour Deposition Method

NASA Astrophysics Data System (ADS)

Najafi, Navid; Rozati, S. M.

2018-03-01

Fluorine-doped zinc oxide (FZO) (ZnO:F) thin films were manufactured by atmospheric pressure chemical vapor deposition (APCVD) on glass substrates using zinc acetate dihydrate [C4H6O4Zn·2H2O, ZnAc] and ammonium fluoride (NH4F) as the source of fluorine with deposition duration of only 120 s for each sample. The effects of different amounts of fluorine as the dopant on the structural, electrical and optical properties of FZO thin films were investigated. The results show a polycrystalline structure at higher temperatures compared to amorphous structure at lower temperatures. The x-ray diffraction patterns of the polycrystalline films were identified as a hexagonal wurtzite structure of zinc oxide (ZnO) with the (002) preferred orientation. Also, the sheet resistance decreased from 17.8 MΩ/□ to 28.9 KΩ/□ for temperatures 325°C to 450°C, respectively. In order to further decrease the sheet resistance of the undoped ZnO thin films, fluorine was added using NH4F as the precursor, and again a drastic change in sheet resistance of only 17.7 Ω/□ was obtained. Based on the field emission scanning electron microscopy images, the fluorine concentration in CVD source is an important factor affecting the grain size and modifies electrical parameters. Ultraviolet-visible measurements revealed reduction of transparency of the layers with increasing fluorine as the dopant.

Luminescence dating of paleolake deltas and glacial deposits in Garwood Valley, Antarctica: Implications for climate, Ross ice sheet dynamics, and paleolake duration

USGS Publications Warehouse

Levy, Joseph S.; Rittenour, Tammy M.; Fountain, Andrew G.; O'Connor, Jim E.

2017-01-01

The formation of perched deltas and other lacustrine deposits in the McMurdo Dry Valleys of Antarctica is widely considered to be evidence of valley-filling lakes dammed by the grounded Ross Sea ice sheet during the local Last Glacial Maximum, with lake drainage interpreted as a record of grounding line retreat. We used luminescence dating to determine the age of paleolake deltas and glacial tills in Garwood Valley, a coastal dry valley that opens to the Ross Sea. Luminescence ages are stratigraphically consistent with radiocarbon results from algal mats within the same delta deposits but suggest radiocarbon dates from lacustrine carbonates may overestimate deposit ages by thousands of years. Results suggest that late Holocene delta deposition into paleolake Howard in Garwood Valley persisted until ca. 3.5 ka. This is significantly younger than the date when grounded ice is thought to have retreated from the Ross Sea. Our evidence suggests that the local, stranded ice-cored till topography in Garwood Valley, rather than regional ice-sheet dynamics, may have controlled lake levels for some McMurdo Dry Valleys paleolakes. Age control from the supraglacial Ross Sea drift suggests grounding and up-valley advance of the Ross Sea ice sheet into Garwood valley during marine oxygen isotope stage (MIS) 4 (71–78 ka) and the local Last Glacial Maximum (9–10 ka). This work demonstrates the power of combining luminescence dating with existing radiocarbon data sets to improve understanding of the relationships among paleolake formation, glacial position, and stream discharge in response to climate change.

Fuel regulation in inland navigation: reduced soil black carbon and PAH deposition in river valleys

NASA Astrophysics Data System (ADS)

Bläsing, M.; Schwark, L.; Amelung, W.; Lehndorff, E.

2016-12-01

Inland navigation (IN) is of increasing importance in the transport sector. Most inland waterways and inland ports are located in/near urban regions; hence many people are exposed to emissions from IN. However, its contribution to environmental quality is not yet known. Accordingly, we aimed at identifying IN emissions in the environment, and investigating consequences of the S-reduction in ship diesel (EU regulation 2009/30/EC) on IN emissions. To do so, topsoil samples were taken from vineyards in valley transects (perpendicular to rivers) at two German inland waterways (Rhine, Moselle) and one ship-free reference valley (Ahr) and analyzed for polycyclic aromatic hydrocarbons (PAHs) and black carbon (BC). To elucidate the effect of fuel regulation (effective since 2011), samplings were performed from 2010 to 2013. Additionally, the potential dispersal of IN emissions was simulated by a Lagrangian stochastic model. Before regulating the S-content of ship diesel by the EU directive soil samples indicated a clear impact of IN emissions on BC and PAH deposits, in at least 200 and 350 m distance to the Moselle and Rhine river, respectively. IN emissions accounted for approximately 30% of total soil BC. However, soils along waterways comprised only slightly more BC than soils in the ship-free Ahr Valley, with BC contents comparable to rural to suburban European soils. Contents of PAHs in river valleys compared to remote to urban pollution load. In the course of the fuel regulation, BC and PAH deposits in soil were reduced within three years by 30-60%, respectively. Also the quality of emissions changed to higher shares of low molecular weight PAHs and smaller proportions of soot-BC, indicating less deposition of IN emissions. The impact of the fuel regulation was more obvious at the Rhine Valley than at the Moselle Valley, likely because of higher ship traffic volume at the former. Overall, fuel regulation was effective in reducing IN emissions along inland waterways.

Influence of zinc, lead, and cadmium pollutants on the microflora of hawthorn leaves

DOE Office of Scientific and Technical Information (OSTI.GOV)

Bewley, R.J.F.; Campbell, R.

1980-01-01

Transect studies were conducted to determine the relative effects of zinc, lead, and cadmium pollution on microorganisms occurring on hawthorn leaves at varying distances from a smelting complex. Sporobolomyces roseus was absent from the most heavily contaminated leaves but, although lead was inhibitory, other environmental factors were also important in determining its overall population level. Conversely, Aureobasidium pullulans and nonpigmented yeasts showed a significant partial positive correlation with lead but were inhibited by zinc and/or cadmium. Numbers of bacterial colonies were only slightly reduced by the combined effect of all three metals, but total numbers of bacteria were highly negativelymore » correlated with lead. Filamentous fungi, isolated by leaf washing, were only slightly inhibited by all three metals, and the degree of mycelial proliferation on senescent leaves was little affected by heavy metal pollution. Computer-generated maps were produced of the distribution of A. pullulans in relation to zinc and lead fallout. 14 references, 7 figures, 2 tables.« less

Environmental pollution levels of lead and zinc in Ishiagu and Uburu communities of Ebonyi State, Nigeria.

PubMed

Oje, Obinna A; Uzoegwu, Peter N; Onwurah, Ikechukwu N E; Nwodo, Uchechukwu U

2010-09-01

Water and soil samples from the area were therefore analyzed for their lead and zinc content. Computation of pollution statuses of lead and zinc revealed topsoil lead geoaccumulation indices of -0.143 and -0.069 and zinc geoaccumulation indices of 1.168 and 0.713 for Ishiagu and Uburu respectively. The pollution indices were determined to be 0.499 and 0.3564 for soil in Ishiagu and Uburu respectively and also 5.11 and 2.42 for water in Ishiagu and Uburu communities respectively. Water/soil concentration ratio were found to be 0.0018 and 0.0014 for lead in Ishiagu and Uburu respectively. On the other hand, the water/soil concentration ratio for zinc was computed to be 0.001 and 0.0008 for Ishiagu and Uburu respectively. These results seem to suggest that the pollution of the environment by these heavy metals in the areas were as a result of the water being contaminated by lead and zinc not necessarily their concentrations in the soil.

Clay deposits of the Connecticut River Valley, Connecticut: a special problem in land management

USGS Publications Warehouse

Langer, William H.

1972-01-01

When man first settled the United States, two natural features favored settlement; flat land that was easy to build on and to farm, and a nearby river that could act as a source of water, transportation, and power. The Connecticut River Valley from Middletown, Ct. north past the Connecticut-Massachusetts state line satisfied these two needs, and was favored by many early Americans in New England. This area remains an area of rapid urbanization, partly because of the broad flat lowlands. The subdued topography of this area is due in large part to deposition of fine-grained materials into glacial Lake Hitchcock. This lake was formed during the Wisconsinan age when southward drainage in the Triassic valley of Connecticut was dammed by glacial drift in the area of Rocky Hill, Connecticut. Lake Hitchcock grew to and beyond St. Johnsbury, Vt. with much of the lake being filled with cyclical lake-bottom deposits during the 2,290 to 2,350 years of its life. Aside from the relative flatness inherent in the deposition of fine-grained lake-bottom deposits, these deposits present very few characteristics that are favorable for urbanization. Favorable characteristics are possible sources of clay for manufacturing and possible sources for waste storage sites. Unfavorable characteristics include low water yields resulting in poor urban water-supply sources, and very low flows in streams during dry periods; low percolation rates resulting In drainage and septic problems; and low or uneven bearing strength which create problems in construction. Fine-grained lake-bottom deposits have been mapped for six quadrangles in the Connecticut Valley lowlands; the quadrangles of Windsor Locks, Broad Brook, Hartford North, Manchester, Hartford South, and Glastonbury (all located in Connecticut). All the maps were prepared from existing information including well and test hole data on file at the Water Resources Division in Hartford, surficial geologic quadrangle maps, and bedrock contour

Radiocarbon dating loess deposits in the Mississippi Valley using terrestrial gastropod shells (Polygyridae, Helicinidae, and Discidae)

USGS Publications Warehouse

Pigati, Jeffery S.; McGeehin, John P.; Muhs, Daniel; Grimley, David A.; Nekola, Jeffery C.

2014-01-01

Small terrestrial gastropod shells (mainly Succineidae) have been used successfully to date late Quaternary loess deposits in Alaska and the Great Plains. However, Succineidae shells are less common in loess deposits in the Mississippi Valley compared to those of the Polygyridae, Helicinidae, and Discidae families. In this study, we conducted several tests to determine whether shells of these gastropods could provide reliable ages for loess deposits in the Mississippi Valley. Our results show that most of the taxa that we investigated incorporate small amounts (1–5%) of old carbon from limestone in their shells, meaning that they should yield ages that are accurate to within a few hundred years. In contrast, shells of the genus Mesodon(Mesodon elevatus and Mesodon zaletus) contain significant and variable amounts of old carbon, yielding ages that are up to a couple thousand 14C years too old. Although terrestrial gastropod shells have tremendous potential for 14C dating loess deposits throughout North America, we acknowledge that accuracy to within a few hundred years may not be sufficient for those interested in developing high-resolution loess chronologies. Even with this limitation, however, 14C dating of terrestrial gastropod shells present in Mississippi Valley loess deposits may prove useful for researchers interested in processes that took place over multi-millennial timescales or in differentiating stratigraphic units that have significantly different ages but similar physical and geochemical properties. The results presented here may also be useful to researchers studying loess deposits outside North America that contain similar gastropod taxa..

Lead inhibition of DNA-binding mechanism of Cys(2)His(2) zinc finger proteins.

PubMed

Hanas, J S; Rodgers, J S; Bantle, J A; Cheng, Y G

1999-11-01

The association of lead with chromatin in cells suggests that deleterious metal effects may in part be mediated through alterations in gene function. To elucidate if and how lead may alter DNA binding of cysteine-rich zinc finger proteins, lead ions were analyzed for their ability to alter the DNA binding mechanism of the Cys(2)His(2) zinc finger protein transcription factor IIIA (TFIIIA). As assayed by DNase I protection, the interaction of TFIIIA with the 50-bp internal control region of the 5S ribosomal gene was partially inhibited by 5 microM lead ions and completely inhibited by 10 to 20 microM lead ions. Preincubation of free TFIIIA with lead resulted in DNA-binding inhibition, whereas preincubation of a TFIIIA/5S RNA complex with lead did not result in DNA-binding inhibition. Because 5S RNA binds TFIIIA zinc fingers, this result is consistent with an inhibition mechanism via lead binding to zinc fingers. The complete loss of DNase I protection on the 5S gene indicates the mechanism of inhibition minimally involves the N-terminal fingers of TFIIIA. Inhibition was not readily reversible and occurred in the presence of an excess of beta-mercaptoethanol. Inhibition kinetics were fast, progressing to completion in approximately 5 min. Millimolar concentrations of sulfhydryl-specific arsenic ions were not inhibitory for TFIIIA binding. Micromolar concentrations of lead inhibited DNA binding by Sp1, another Cys(2)His(2) finger protein, but not by the nonfinger protein AP2. Inhibition of Cys(2)His(2) zinc finger transcription factors by lead ions at concentrations near those known to have deleterious physiological effects points to new molecular mechanisms for lead toxicity in promoting disease.

Germanium and indium

USGS Publications Warehouse

Shanks, W.C. Pat; Kimball, Bryn E.; Tolcin, Amy C.; Guberman, David E.; Schulz, Klaus J.; DeYoung,, John H.; Seal, Robert R.; Bradley, Dwight C.

2017-12-19

Germanium and indium are two important elements used in electronics devices, flat-panel display screens, light-emitting diodes, night vision devices, optical fiber, optical lens systems, and solar power arrays. Germanium and indium are treated together in this chapter because they have similar technological uses and because both are recovered as byproducts, mainly from copper and zinc sulfides.The world’s total production of germanium in 2011 was estimated to be 118 metric tons. This total comprised germanium recovered from zinc concentrates, from fly ash residues from coal burning, and from recycled material. Worldwide, primary germanium was recovered in Canada from zinc concentrates shipped from the United States; in China from zinc residues and coal from multiple sources in China and elsewhere; in Finland from zinc concentrates from the Democratic Republic of the Congo; and in Russia from coal.World production of indium metal was estimated to be about 723 metric tons in 2011; more than one-half of the total was produced in China. Other leading producers included Belgium, Canada, Japan, and the Republic of Korea. These five countries accounted for nearly 95 percent of primary indium production.Deposit types that contain significant amounts of germanium include volcanogenic massive sulfide (VMS) deposits, sedimentary exhalative (SEDEX) deposits, Mississippi Valley-type (MVT) lead-zinc deposits (including Irish-type zinc-lead deposits), Kipushi-type zinc-lead-copper replacement bodies in carbonate rocks, and coal deposits.More than one-half of the byproduct indium in the world is produced in southern China from VMS and SEDEX deposits, and much of the remainder is produced from zinc concentrates from MVT deposits. The Laochang deposit in Yunnan Province, China, and the VMS deposits of the Murchison greenstone belt in Limpopo Province, South Africa, provide excellent examples of indium-enriched deposits. The SEDEX deposits at Bainiuchang, China (located in

Atomic layer deposition of tin oxide and zinc tin oxide using tetraethyltin and ozone

DOE Office of Scientific and Technical Information (OSTI.GOV)

Warner, Ellis J.; Gladfelter, Wayne L., E-mail: wlg@umn.edu; Johnson, Forrest

Silicon or glass substrates exposed to sequential pulses of tetraethyltin (TET) and ozone (O{sub 3}) were coated with thin films of SnO{sub 2}. Self-limiting deposition was found using 8 s pulse times, and a uniform thickness per cycle (TPC) of 0.2 nm/cycle was observed in a small, yet reproducible, temperature window from 290 to 320 °C. The as-deposited, stoichiometric SnO{sub 2} films were amorphous and transparent above 400 nm. Interspersing pulses of diethylzinc and O{sub 3} among the TET:O{sub 3} pulses resulted in deposition of zinc tin oxide films, where the fraction of tin, defined as [at. % Sn/(at. % Sn + at. %more » Zn)], was controlled by the ratio of TET pulses, specifically n{sub TET}:(n{sub TET} + n{sub DEZ}) where n{sub TET} and n{sub DEZ} are the number of precursor/O{sub 3} subcycles within each atomic layer deposition (ALD) supercycle. Based on film thickness and composition measurements, the TET pulse time required to reach saturation in the TPC of SnO{sub 2} on ZnO surfaces was increased to >30 s. Under these conditions, film stoichiometry as a function of the TET pulse ratio was consistent with the model devised by Elliott and Nilsen. The as-deposited zinc tin oxide (ZTO) films were amorphous and remained so even after annealing at 450 °C in air for 1 h. The optical bandgap of the transparent ZTO films increased as the tin concentration increased. Hall measurements established that the n-type ZTO carrier concentration was 3 × 10{sup 17} and 4 × 10{sup 18} cm{sup −3} for fractional tin concentrations of 0.28 and 0.63, respectively. The carrier mobility decreased as the concentration of tin increased. A broken gap pn junction was fabricated using ALD-deposited ZTO and a sputtered layer of cuprous oxide. The junction demonstrated ohmic behavior and low resistance consistent with similar junctions prepared using sputter-deposited ZTO.« less

Rock avalanche deposits in Alai Valley, Central Asia: misinterpretation of glacial record

NASA Astrophysics Data System (ADS)

Reznichenko, Natalya; Davies, Tim; Robinson, Tom; De Pascale, Gregory

2013-04-01

The reconstruction of Quaternary glaciations has been restricted by conventional approaches with resulting contradictions in interpretation of the regional glacial record, that recently have been subjected to critical re-evaluation. Along with uncertainties in dating techniques and their applicability to particular landforms (Kirkbride and Winkler, 2012), it has recently been demonstrated that the presence of rock avalanche debris in a landform can be unequivocally detected; this allows for the first time definitive identification of and distinction between glacial moraines and landslide deposits. It also identifies moraines that have formed due to rock avalanche deposition on glaciers, possibly with no associated climatic signal (Reznichenko et al., 2012). Confusion between landslide deposits and moraines is evident for ranges in Central Asia (e.g., Hewitt, 1999) where the least-studied glacial record is selectively correlated with established glacial chronologies in Alpine ranges, which in turn masks the actual glacial extent and their responses to climate change, tectonics and landsliding activity. We describe examples in the glaciated Alai Valley, large intermountain depression between the Zaalay Range of the Northern Pamir and the Alay Range of the Southern Tien-Shan, showing that some large Quaternary deposits classically interpreted as moraines are of rock avalanche origin. Sediment from these deposits has been tested for the presence of agglomerates that are only produced under high stress conditions during rock avalanche motion, and are absent from glacial sediments (Reznichenko et al., 2012). This reveals that morphologically-similar deposits have radically different geneses: rock avalanche origin for a deposit in the Komansu river catchment and glacial origin for deposits in the Ashiktash and Kyzylart catchments. The enormous Komansu rock avalanche deposit, probably triggered by a rupture of the Main Pamir thrust, currently covers about 100 km2 with a

Sedimentology and reservoir heterogeneity of a valley-fill deposit-A field guide to the Dakota Sandstone of the San Rafael Swell, Utah

USGS Publications Warehouse

Kirschbaum, Mark A.; Schenk, Christopher J.

2010-01-01

Valley-fill deposits form a significant class of hydrocarbon reservoirs in many basins of the world. Maximizing recovery of fluids from these reservoirs requires an understanding of the scales of fluid-flow heterogeneity present within the valley-fill system. The Upper Cretaceous Dakota Sandstone in the San Rafael Swell, Utah contains well exposed, relatively accessible outcrops that allow a unique view of the external geometry and internal complexity of a set of rocks interpreted to be deposits of an incised valley fill. These units can be traced on outcrop for tens of miles, and individual sandstone bodies are exposed in three dimensions because of modern erosion in side canyons in a semiarid setting and by exhumation of the overlying, easily erodible Mancos Shale. The Dakota consists of two major units: (1) a lower amalgamated sandstone facies dominated by large-scale cross stratification with several individual sandstone bodies ranging in thickness from 8 to 28 feet, ranging in width from 115 to 150 feet, and having lengths as much as 5,000 feet, and (2) an upper facies composed of numerous mud-encased lenticular sandstones, dominated by ripple-scale lamination, in bedsets ranging in thickness from 5 to 12 feet. The lower facies is interpreted to be fluvial, probably of mainly braided stream origin that exhibits multiple incisions amalgamated into a complex sandstone body. The upper facies has lower energy, probably anastomosed channels encased within alluvial and coastal-plain floodplain sediments. The Dakota valley-fill complex has multiple scales of heterogeneity that could affect fluid flow in similar oil and gas subsurface reservoirs. The largest scale heterogeneity is at the formation level, where the valley-fill complex is sealed within overlying and underlying units. Within the valley-fill complex, there are heterogeneities between individual sandstone bodies, and at the smallest scale, internal heterogeneities within the bodies themselves. These

[The morphofunctional state of the bone marrow in lead and zinc intoxication].

PubMed

Vladimtseva, T M; Pashkevich, I A; Salmina, A B

2006-01-01

The nucleolus is a compulsory nuclear structure of all cells of eukaryotes. The quantitative and qualitative characteristics of nuclei show the functional activity of a cell, the rate of its synthesis of RNA and portents, and its metabolic state. Heavy metals (zinc chloride and lead acetate) were comparatively investigated for their effects on the nucleolar apparatus of bone marrow cells in in vivo experiments. Zinc chloride and lead acetate were ascertained to damage the nucleolar apparatus of cells, thus decreasing their transcriptional activity or irreversibly damaging them.

Recent trends and current practices for secondary processing of zinc and lead. Part II: zinc recovery from secondary sources.

PubMed

Sahu, Kamala Kanta; Agrawal, Archana; Pandey, Banshi Dhar

2004-08-01

Almost all metallurgical processes are associated with the generation of wastes and residues that may be hazardous or non-hazardous in nature depending upon the criteria specified by institutions such as the US Environment Protection Agency, etc. Wastes containing heavy and toxic metals such as arsenic, cadmium, chromium, nickel, lead, copper, mercury, zinc, etc., that are present beyond permissible limits deemed to be treated or disposed of, and non-hazardous wastes can be utilized for metal recovery or safe disposal. Zinc is in growing demand all over the world. In India, a major amount of zinc is imported and therefore processing of zinc secondaries will assist in satisfying the gap between demand and supply to some extent. This report mainly focuses on the current practices and recent trends on the secondary processing of zinc. Attempts made by various laboratories to develop ecofriendly processes for the recovery of zinc from secondary raw materials are also described and discussed.

Morphology control of zinc regeneration for zinc-air fuel cell and battery

NASA Astrophysics Data System (ADS)

Wang, Keliang; Pei, Pucheng; Ma, Ze; Xu, Huachi; Li, Pengcheng; Wang, Xizhong

2014-12-01

Morphology control is crucial both for zinc-air batteries and for zinc-air fuel cells during zinc regeneration. Zinc dendrite should be avoided in zinc-air batteries and zinc pellets are yearned to be formed for zinc-air fuel cells. This paper is mainly to analyze the mechanism of shape change and to control the zinc morphology during charge. A numerical three-dimensional model for zinc regeneration is established with COMSOL software on the basis of ionic transport theory and electrode reaction electrochemistry, and some experiments of zinc regeneration are carried out. The deposition process is qualitatively analyzed by the kinetics Monte Carlo method to study the morphological change from the electrocrystallization point of view. Morphological evolution of deposited zinc under different conditions of direct currents and pulse currents is also investigated by simulation. The simulation shows that parametric variables of the flowing electrolyte, the surface roughness and the structure of the electrode, the charging current and mode affect morphological evolution. The uniform morphology of deposited zinc is attained at low current, pulsating current or hydrodynamic electrolyte, and granular morphology is obtained by means of an electrode of discrete columnar structure in combination with high current and flowing electrolyte.

Low-fluorine Stockwork Molybdenite Deposits

USGS Publications Warehouse

Ludington, Steve; Hammarstrom, Jane; Piatak, Nadine M.

2009-01-01

Low-fluorine stockwork molybdenite deposits are closely related to porphyry copper deposits, being similar in their tectonic setting (continental volcanic arc) and the petrology (calc-alkaline) of associated igneous rock types. They are mainly restricted to the Cordillera of western Canada and the northwest United States, and their distribution elsewhere in the world may be limited. The deposits consist of stockwork bodies of molybdenite-bearing quartz veinlets that are present in and around the upper parts of intermediate to felsic intrusions. The deposits are relatively low grade (0.05 to 0.2 percent Mo), but relatively large, commonly >50 million tons. The source plutons for these deposits range from granodiorite to granite in composition; the deposits primarily form in continental margin subduction-related magmatic arcs, often concurrent with formation of nearby porphyry copper deposits. Oxidation of pyrite in unmined deposits or in tailings and waste rock during weathering can lead to development of acid-rock drainage and limonite-rich gossans. Waters associated with low-fluorine stockwork molybdenite deposits tend to be nearly neutral in pH; variable in concentrations of molybdenum (10,000 ug/L); below regulatory guidelines for copper, iron, lead, zinc, and mercury; and locally may exceed guidelines for arsenic, cadmium, and selenium.

Nature, diversity of deposit types and metallogenic relations of South China

USGS Publications Warehouse

Zaw, K.; Peters, S.G.; Cromie, P.; Burrett, C.; Hou, Z.

2007-01-01

the 'Northern Golden Triangle' of China. These deposits are mostly epigenetic hydrothermal micron-disseminated gold deposits with associated As, Hg, Sb + Tl mineralisation similar to Carlin-type deposits in USA. The important deposits in the Southern Golden Triangle are Jinfeng (Lannigou), Zimudang, Getang, Yata and Banqi in Guizhou Province, and the Jinya and Gaolong deposits in Guangxi District. The most important deposits in the Northern Golden Triangle are the Dongbeizhai and Qiaoqiaoshang deposits. Many porphyry-related polymetallic copper-lead-zinc and gold skarn deposits occur in South China. These deposits are related to Indosinian (Triassic) and Yanshanian (Jurassic to Cretaceous) magmatism associated with collision of the South China and North China Cratons and westward subduction of the Palaeo-Pacific Plate. Most of these deposits are distributed along the Lower to Middle Yangtze River metallogenic belt. The most significant deposits are Tonglushan, Jilongshan, Fengshandong, Shitouzui and Jiguanzui. Au-(Ag-Mo)-rich porphyry-related Cu-Fe skarn deposits are also present (Chengmenshan and Wushan in Jiangxi Province and Xinqiao, Mashan-Tianmashan, Shizishan and Huangshilaoshan in Anhui Province). The South China fold belt extending from Fujian to Zhejiang Provinces is characterised by well-developed Yanshanian intrusive to subvolcanic rocks associated with porphyry to epithermal type mineralisation and mesothermal vein deposits. The largest porphyry copper deposit in China, Dexing, occurs in Jiangxi Province and is hosted by Yanshanian granodiorite. The high-sulphidation epithermal system occurs at the Zijinshan district in Fujian Province and epithermal to mesothermal vein-type deposits are also found in the Zhejiang Province (e.g., Zhilingtou). Part of Shandong Province is located at the northern margin of the South China Craton and the province has unique world class granite-hosted orogenic gold deposits. Occurrences of Pt-Pd-Ni-Cu-Co are found in Permian

Behavior of lead and zinc in plasma, erythrocytes, and urine and ALAD in erythrocytes following intravenous infusion of CaEDTA in lead workers.

PubMed

Araki, S; Aono, H; Fukahori, M; Tabuki, K

1984-01-01

To evaluate the effect of calcium disodium ethylenediamine tetraacetate (CaEDTA) on concentrations of lead and zinc in plasma, erythrocytes, whole blood, and urine, we administered CaEDTA by intravenous infusion for 1 hr to seven lead workers with blood lead concentrations of 46-67 micrograms/100 g (mean 54 micrograms/100 g). The plasma lead concentration (PPb) and the mobilization yield of lead in urine by CaEDTA were highest during the period between 1 and 2 hr after the infusion was started. In contrast, the lead concentration in erythrocytes (EPb) and in whole blood (BPb) remained unchanged during the 24 hr following infusion. Plasma zinc concentration (PZn) also fell rapidly following CaEDTA infusion; the decline was followed by a gradual rise in the zinc concentration in erythrocytes (EZn) without alteration in the zinc in whole blood. The mobilization yield of zinc in urine by CaEDTA (MZn) reached its highest level within 1 hr after the start of the infusion. Delta-aminolevulinic acid dehydratase (ALAD) activity in erythrocytes gradually increased for 5 hr following CaEDTA infusion. These observations suggest that (1) PPb concentration is a more sensitive indicator of the body burden of chelatable lead than is either BPb or EPb; (2) MZn is mobilized mostly from plasma during the first several hours following the start of CaEDTA infusion, and the fall in PZn concentration following infusion is compensated first by a rise in EZn concentration and then by an immediate redistribution of zinc in other organs to the blood; and (3) Pb-inhibited ALAD activity is reactivated by the increased EZn during and shortly after CaEDTA infusion.

Epigenetic lead, zinc, silver, antimony, tin, and gold veins in Boulder Basin, Blaine and Custer counties, Idaho; potential for economic tin mineralization

USGS Publications Warehouse

Ratchford, Michael E.

2002-01-01

Boulder Basin is in a northwest-trending belt of allochthonous Paleozoic rocks in the Boulder Mountains of central Idaho. Regional Tertiary extension resulted in widespread normal faulting and coeval emplacement of shallow-level intrusions and extrusive rocks of the Challis Volcanic Group. Epigenetic lead-zinc-silver-antimony-tin-gold vein deposits formed during Tertiary extension and are hosted within Paleozoic strata. The major orebodies are in the lower plate of the Boulder Basin thrust fault, in massive quartzite of the Middle Pennsylvanian to Lower Permian Wood River Formation. Anomalous concentrations of tin are present in the base-metal mineral assemblage of the Boulder Basin ore deposits. The tin-bearing veins in Boulder Basin are strikingly similar to Bolivian tin deposits. The deposit model for Bolivian tin deposits identifies buried tin porphyry below the tin-bearing vein system.

Low zinc serum levels and high blood lead levels among school-age children in coastal area

NASA Astrophysics Data System (ADS)

Pramono, Adriyan; Panunggal, Binar; Rahfiludin, M. Zen; Swastawati, Fronthea

2017-02-01

The coverage of environmental lead toxicant was quiet wide. Lead exposure recently has been expected to be associated with zinc deficiency and blood indices disturbance. Emphasizing on children, which could absorb more than 50 % of lead that enters the body. Lead became the issue on the coastal area due to it has polluted the environment and waters as the source of fisheries products. This was a cross sectional study to determined nutritional status, blood lead levels, zinc serum levels, blood indices levels, fish intake among school children in coastal region of Semarang. This study was carried out on the school children aged between 8 and 12 years old in coastal region of Semarang. Nutritional status was figured out using anthropometry measurement. Blood lead and zinc serum levels were analyzed using the Atomic Absorbent Spectrophotometry (AAS) at a wavelength of 213.9 nm for zinc serum and 283.3 nm for blood lead. Blood indices was measured using auto blood hematology analyzer. Fish intake was assessed using 3-non consecutive days 24-hours food recall. The children had high lead levels (median 34.86 μg/dl, range 11.46 - 58.86 μg/dl) compared to WHO cut off. Zinc serum levels was low (median 18.10 μg/dl, range 10.25 - 41.39 μg/dl) compared to the Joint WHO/UNICEF/IAEA/IZiNCG cut off. Approximately 26.4% of children were anemic. This study concluded that all school children had high blood lead levels, low zinc serum, and presented microcytic hypochromic anemia. This phenomenon should be considered as public health concern.

Effect of Zinc Oxide Film Deposition Position on the Characteristics of Zinc Oxide Thin Film Transistors Fabricated by Low-Temperature Magnetron Sputtering

NASA Astrophysics Data System (ADS)

Takechi, Kazushige; Nakata, Mitsuru; Eguchi, Toshimasa; Otsuki, Shigeyoshi; Yamaguchi, Hirotaka; Kaneko, Setsuo

2008-09-01

We report on the effect of zinc oxide (ZnO) film deposition position on the characteristics of ZnO thin-film transistors (TFTs) fabricated by magnetron sputtering with no intentional heating of the substrate. We evaluate the properties of ZnO (channel semiconductor) films deposited at various positions with respect to the target position. We show that the film deposition at a position off-centered from the target results in good TFT characteristics. This might be due to the fact that the off-centered deposition position is effective for suppressing the effect of energetic negative ions in the plasma.

Fuel regulation in inland navigation: Reduced soil black carbon deposition in river valleys in Germany

NASA Astrophysics Data System (ADS)

Bläsing, M.; Shao, Y.; Lehndorff, E.

2015-11-01

Inland navigation is of increasing economic and ecological interest, however its contribution to environmental quality is hardly known. We hypothesized that i) inland navigation emits considerable amounts of soot-Black Carbon (BC) as a product of incomplete combustion of diesel fuel, which is then deposited on soils along river valleys, that ii) improvement of fuel quality by sulfur reduction in 2011 decreased BC inputs to soil, and that iii) this provides a tracer for the spatial impact of inland navigation emissions. The spatial and temporal patterns of soil BC deposits from inland navigation were investigated yearly (2010-2013) working within transects perpendicular to the rivers Rhine, Moselle and Ahr, Germany (the Ahr Valley is free of shipping and served as a reference). In rural areas at inland waterways navigation likely represented the dominant BC emitter. Topsoils (0-10 cm depth) were sampled in vineyards. Their BC content and composition was determined via oxidation of bulk soil organic matter to benzene polycarboxylic acids (BPCAs). The highly trafficked Rhine Valley yielded only little more BC (64.7 ± 12 g BC kg-1 soil organic carbon (SOC) compared to 51.7 ± 9 at the Moselle, and 53.6 ± 6 at the reference Ahr Valley). At both inland waterways soil BC increased towards the river, following the simulated dispersal of ship-derived BC using a Lagrangian model. In the course of ship fuel regulation, soil BC deposits at the Rhine and Moselle waterways decreased significantly from 70.2 ± 3.2 to 47.9 ± 1.1 and 57.6 ± 1.3 to 41.7 ± 0.9 g BC kg-1 SOC within 3 years. Even more pronounced was the change in BC composition, i.e., the ratio of pentacarboxylated to mellitic acid increased from 0.75 to 1.3 (Rhine) and 1 to 1.4 (Moselle) during this time span. From this we calculated that ∼30% less BC was deposited by inland navigation likely due to reduced BC emissions after sulfur regulation in ship diesel.

Optimal Magnetorheological Fluid for Finishing of Chemical-Vapor-Deposited Zinc Sulfide

NASA Astrophysics Data System (ADS)

Salzman, Sivan

Magnetorheological finishing (MRF) of polycrystalline, chemical-vapor- deposited zinc sulfide (ZnS) optics leaves visible surface artifacts known as "pebbles". These artifacts are a direct result of the material's inner structure that consists of cone-like features that grow larger (up to a few millimeters in size) as deposition takes place, and manifest on the top deposited surface as "pebbles". Polishing the pebble features from a CVD ZnS substrate to a flat, smooth surface to below 10 nm root-mean-square is challenging, especially for a non-destructive polishing process such as MRF. This work explores ways to improve the surface finish of CVD ZnS processed with MRF through modification of the magnetorheological (MR) fluid's properties. A materials science approach is presented to define the anisotropy of CVD ZnS through a combination of chemical and mechanical experiments and theoretical predictions. Magnetorheological finishing experiments with single crystal samples of ZnS, whose cuts and orientations represent most of the facets known to occur in the polycrystalline CVD ZnS, were performed to explore the influence of material anisotropy on the material removal rate during MRF. By adjusting the fluid's viscosity, abrasive type concentration, and pH to find the chemo-mechanical conditions that equalize removal rates among all single crystal facets during MRF, we established an optimized, novel MR formulation to polish CVD ZnS without degrading the surface finish of the optic.

Arsenite binding-induced zinc loss from PARP-1 is equivalent to zinc deficiency in reducing PARP-1 activity, leading to inhibition of DNA repair

DOE Office of Scientific and Technical Information (OSTI.GOV)

Sun, Xi; Zhou, Xixi; Du, Libo

2014-01-15

Inhibition of DNA repair is a recognized mechanism for arsenic enhancement of ultraviolet radiation-induced DNA damage and carcinogenesis. Poly(ADP-ribose) polymerase-1 (PARP-1), a zinc finger DNA repair protein, has been identified as a sensitive molecular target for arsenic. The zinc finger domains of PARP-1 protein function as a critical structure in DNA recognition and binding. Since cellular poly(ADP-ribosyl)ation capacity has been positively correlated with zinc status in cells, we hypothesize that arsenite binding-induced zinc loss from PARP-1 is equivalent to zinc deficiency in reducing PARP-1 activity, leading to inhibition of DNA repair. To test this hypothesis, we compared the effects ofmore » arsenite exposure with zinc deficiency, created by using the membrane-permeable zinc chelator TPEN, on 8-OHdG formation, PARP-1 activity and zinc binding to PARP-1 in HaCat cells. Our results show that arsenite exposure and zinc deficiency had similar effects on PARP-1 protein, whereas supplemental zinc reversed these effects. To investigate the molecular mechanism of zinc loss induced by arsenite, ICP-AES, near UV spectroscopy, fluorescence, and circular dichroism spectroscopy were utilized to examine arsenite binding and occupation of a peptide representing the first zinc finger of PARP-1. We found that arsenite binding as well as zinc loss altered the conformation of zinc finger structure which functionally leads to PARP-1 inhibition. These findings suggest that arsenite binding to PARP-1 protein created similar adverse biological effects as zinc deficiency, which establishes the molecular mechanism for zinc supplementation as a potentially effective treatment to reverse the detrimental outcomes of arsenic exposure. - Highlights: • Arsenite binding is equivalent to zinc deficiency in reducing PARP-1 function. • Zinc reverses arsenic inhibition of PARP-1 activity and enhancement of DNA damage. • Arsenite binding and zinc loss alter the conformation of

78 FR 46948 - Proposed Agreement Regarding Site Costs and Covenants Not To Sue for American Lead and Zinc Mill...

Federal Register 2010, 2011, 2012, 2013, 2014

2013-08-02

... Not To Sue for American Lead and Zinc Mill Site, Ouray County, Colorado AGENCY: Environmental... provides for Settling Party's payment of certain response costs incurred at the American Lead and Zinc Mill... reference the American Lead and Zinc Mill Site, the EPA Docket No. CERCLA-08-2013- 0004. The Agency's...

Chronology, sedimentology, and microfauna of groundwater discharge deposits in the central Mojave Desert, Valley Wells, California

USGS Publications Warehouse

Pigati, J.S.; Miller, D.M.; Bright, J.E.; Mahan, S.A.; Nekola, J.C.; Paces, J.B.

2011-01-01

groundwater supported persistent and long-lived desert wetlands in many broad valleys and basins in the American Southwest. When active, these systems provided important food and water sources for local fauna, supported hydrophilic and phreatophytic vegetation, and acted as catchments for eolian and alluvial sediments. Desert wetlands are represented in the geologic record by groundwater discharge deposits, which are also called spring or wetland deposits. Groundwater discharge deposits contain information on the timing and magnitude of past changes in water-table levels and, thus, are a source of paleohydrologic and paleoclimatic information. Here, we present the results of an investigation of extensive groundwater discharge deposits in the central Mojave Desert at Valley Wells, California. We used geologic mapping and stratigraphic relations to identify two distinct wetland sequences at Valley Wells, which we dated using radiocarbon, luminescence, and uranium-series techniques. We also analyzed the sediments and microfauna (ostracodes and gastropods) to reconstruct the specific environments in which they formed. Our results suggest that the earliest episode of high water-table conditions at Valley Wells began ca. 60 ka (thousands of calendar yr B.P.), and culminated in peak discharge between ca. 40 and 35 ka. During this time, cold (4-12 ??C) emergent groundwater supported extensive wetlands that likely were composed of a wet, sedge-rush-tussock meadow mixed with mesic riparian forest. After ca. 35 ka, the water table dropped below the ground surface but was still shallow enough to support dense stands of phreatophytes through the Last Glacial Maximum (LGM). The water table dropped further after the LGM, and xeric conditions prevailed until modest wetlands returned briefly during the Younger Dryas cold event (13.0-11.6 ka). We did not observe any evidence of wet conditions during the Holocene at Valley Wells. The timing of these fluctuations is consistent with

Chronology, sedimentology, and microfauna of groundwater discharge deposits in the central Mojave Desert, Valley Wells, California

USGS Publications Warehouse

Pigati, Jeffrey S.; Miller, David M.; Bright, Jordon E.; Mahan, Shannon; Nekola, Jeffrey C.; Paces, James B.

2011-01-01

During the late Pleistocene, emergent groundwater supported persistent and long-lived desert wetlands in many broad valleys and basins in the American Southwest. When active, these systems provided important food and water sources for local fauna, supported hydrophilic and phreatophytic vegetation, and acted as catchments for eolian and alluvial sediments. Desert wetlands are represented in the geologic record by groundwater discharge deposits, which are also called spring or wetland deposits. Groundwater discharge deposits contain information on the timing and magnitude of past changes in water-table levels and, thus, are a source of paleohydrologic and paleoclimatic information. Here, we present the results of an investigation of extensive groundwater discharge deposits in the central Mojave Desert at Valley Wells, California. We used geologic mapping and stratigraphic relations to identify two distinct wetland sequences at Valley Wells, which we dated using radiocarbon, luminescence, and uranium-series techniques. We also analyzed the sediments and microfauna (ostracodes and gastropods) to reconstruct the specific environments in which they formed. Our results suggest that the earliest episode of high water-table conditions at Valley Wells began ca. 60 ka (thousands of calendar yr B.P.), and culminated in peak discharge between ca. 40 and 35 ka. During this time, cold (4–12 °C) emergent groundwater supported extensive wetlands that likely were composed of a wet, sedge-rush-tussock meadow mixed with mesic riparian forest. After ca. 35 ka, the water table dropped below the ground surface but was still shallow enough to support dense stands of phreatophytes through the Last Glacial Maximum (LGM). The water table dropped further after the LGM, and xeric conditions prevailed until modest wetlands returned briefly during the Younger Dryas cold event (13.0–11.6 ka). We did not observe any evidence of wet conditions during the Holocene at Valley Wells. The timing

[XANES study of lead speciation in duckweed].

PubMed

Chu, Bin-Bin; Luo, Li-Qiang; Xu, Tao; Yuan, Jing; Sun, Jian-Ling; Zeng, Yuan; Ma, Yan-Hong; Yi, Shan

2012-07-01

Qixiashan lead-zinc mine of Nanjing was one of the largest lead zinc deposits in East China Its exploitation has been over 50 years, and the environmental pollution has also been increasing. The lead concentration in the local environment was high, but lead migration and toxic mechanism has not been clear. Therefore, biogeochemistry research of the lead zinc mine was carried out. Using ICP-MS and Pb-L III edge XANES, lead concentration and speciation were analyzed respectively, and duckweed which can tolerate and enriched heavy metals was found in the pollution area. The results showed that the lead concentration of duckweed was 39.4 mg x kg(-1). XANES analysis and linear combination fit indicated that lead stearate and lead sulfide accounted for 65% and 36.9% respectively in the lead speciation of duckweed, suggesting that the main lead speciation of duckweed was sulfur-containing lead-organic acid.

Correlations in distribution and concentration of calcium, copper and iron with zinc in isolated extracellular deposits associated with age-related macular degeneration

USGS Publications Warehouse

Flinn, Jane M; Kakalec, Peter; Tappero, Ryan; Jones, Blair F.; Lengyel, Imre

2014-01-01

Zinc (Zn) is abundantly enriched in sub-retinal pigment epithelial (RPE) deposits, the hallmarks of age-related macular degeneration (AMD), and is thought to play a role in the formation of these deposits. However, it is not known whether Zn is the only metal relevant for sub-RPE deposit formation. Because of their involvement in the pathogenesis of AMD, we determined the concentration and distribution of calcium (Ca), iron (Fe) and copper (Cu) and compared these with Zn in isolated and sectioned macular (MSD), equatorial (PHD) and far peripheral (FPD) sub-RPE deposits from an 86 year old donor eye with post mortem diagnosis of early AMD. The sections were mounted on Zn free microscopy slides and analyzed by microprobe synchrotron X-ray fluorescence (μSXRF). Metal concentrations were determined using spiked sectioned sheep brain matrix standards, prepared the same way as the samples. The heterogeneity of metal distributions was examined using pixel by pixel comparison. The orders of metal concentrations were Ca ⋙ Zn > Fe in all three types of deposits but Cu levels were not distinguishable from background values. Zinc and Ca were consistently present in all deposits but reached highest concentration in MSD. Iron was present in some but not all deposits and was especially enriched in FPD. Correlation analysis indicated considerable variation in metal distribution within and between sub-RPE deposits. The results suggest that Zn and Ca are the most likely contributors to deposit formation especially in MSD, the characteristic risk factor for the development of AMD in the human eye.

Zinc, iron, and lead: relations to head start children's cognitive scores and teachers' ratings of behavior.

PubMed

Hubbs-Tait, Laura; Kennedy, Tay Seacord; Droke, Elizabeth A; Belanger, David M; Parker, Jill R

2007-01-01

The objective of this study was to conduct a preliminary investigation of lead, zinc, and iron levels in relation to child cognition and behavior in a small sample of Head Start children. The design was cross-sectional and correlational. Participants were 42 3- to 5-year-old children attending rural Head Start centers. Nonfasting blood samples of whole blood lead, plasma zinc, and ferritin were collected. Teachers rated children's behavior on the California Preschool Social Competency Scale, Howes' Sociability subscale, and the Preschool Behavior Questionnaire. Children were tested individually with the McCarthy Scales of Children's Abilities. Hierarchical regression analyses revealed that zinc and ferritin jointly explained 25% of the variance in McCarthy Scales of Children's Abilities verbal scores. Lead levels explained 25% of the variance in teacher ratings of girls' sociability and 20% of the variance in teacher ratings of girls' classroom competence. Zinc levels explained 39% of the variance in teacher ratings of boys' anxiety. Univariate analysis of variance revealed that the four children low in zinc and iron had significantly higher blood lead (median=0.23 micromol/L [4.73 microg/dL]) than the 31 children sufficient in zinc or iron (median=0.07 micromol/L [1.54 microg/dL]) or the 7 children sufficient in both (median=0.12 micromol/L [2.52 microg/dL]), suggesting an interaction among the three minerals. Within this small low-income sample, the results imply both separate and interacting effects of iron, zinc, and lead. They underscore the importance of studying these three minerals in larger samples of low-income preschool children to make more definitive conclusions.

A special issue devoted to gold deposits in northern Nevada: Part 2. Carlin-type Deposits

USGS Publications Warehouse

Hofstra, Albert H.; John, David A.; Theodore, Ted G.

2003-01-01

Despite the similar age, tectonic setting, alteration types, mineral parageneses, and geochemical signatures of the deposits studied, these papers do not lead to consensus regarding genetic models for Carlin-type deposits. Rather, the separate investigations by different workers, utilizing both similar and unlike approaches, result in markedly different conclusions. Some of this disparity probably is due to real differences in the origin of different districts; however, the opposing conclusions arrived at by investigations on neighboring deposits in a single district are more problematic and most likely are due to difficulties resulting from the superposition of different types and ages of gold mineralization or to substantial variations in the hydrology and proportions of fluid components derived from deep and shallow sources in each deposit. Further work is needed to validate and understand the significance of these differences.

Cobalt—Styles of deposits and the search for primary deposits

USGS Publications Warehouse

Hitzman, Murray W.; Bookstrom, Arthur A.; Slack, John F.; Zientek, Michael L.

2017-11-30

Cobalt (Co) is a potentially critical mineral. The vast majority of cobalt is a byproduct of copper and (or) nickel production. Cobalt is increasingly used in magnets and rechargeable batteries. More than 50 percent of primary cobalt production is from the Central African Copperbelt. The Central African Copperbelt is the only sedimentary rock-hosted stratiform copper district that contains significant cobalt. Its presence may indicate significant mafic-ultramafic rocks in the local basement. The balance of primary cobalt production is from magmatic nickel-copper and nickel laterite deposits. Cobalt is present in several carbonate-hosted lead-zinc and copper districts. It is also variably present in Besshi-type volcanogenic massive sulfide and siliciclastic sedimentary rock-hosted deposits in back arc and rift environments associated with mafic-ultramafic rocks. Metasedimentary cobalt-copper-gold deposits (such as Blackbird, Idaho), iron oxide-copper-gold deposits, and the five-element vein deposits (such as Cobalt, Ontario) contain different amounts of cobalt. None of these deposit types show direct links to mafic-ultramafic rocks; the deposits may result from crustal-scale hydrothermal systems capable of leaching and transporting cobalt from great depths. Hydrothermal deposits associated with ultramafic rocks, typified by the Bou Azzer district of Morocco, represent another type of primary cobalt deposit.In the United States, exploration for cobalt deposits may focus on magmatic nickel-copper deposits in the Archean and Proterozoic rocks of the Midwest and the east coast (Pennsylvania) and younger mafic rocks in southeastern and southern Alaska; also, possibly basement rocks in southeastern Missouri. Other potential exploration targets include—The Belt-Purcell basin of British Columbia (Canada), Idaho, Montana, and Washington for different styles of sedimentary rock-hosted cobalt deposits;Besshi-type VMS deposits, such as the Greens Creek (Alaska) deposit and

Sediment-hosted Pb-Zn Deposits: a global perspective

USGS Publications Warehouse

Leach, David L.; Sangster, Donald F.; Kelley, Karen D.; Large, R; Garven, G.; Allen, Craig R.

2005-01-01

Sediment-hosted Pb-Zn deposits contain the world's greatest lead and zinc resources and dominate world production of these metals. They are a chverse group of ore deposits hosted by a wide variety of carbonate and siliciclastic roch that have no obviolls genetic association with igneous activity. A nmge of ore-fortl1ing processes in a vmiety of geologic and tectonic environments created these deposits over at least two billion years of Earth history. The metals were precipitated by basinal brines in synsedimentary and early diagenetic to low-grade metamorphic environments. The deposits display a broad range of relationships to enclosing host rocks that includes stratiform, strata-bound, and discordant ores. These ores are divided into two broad subt)1Jes: Mississippi Valley-type (MVT) and sedimentmy exhalative (SEDEX), Despite the "exhalative" component inherent in the term "SEDEX," in this manusclipt, direct evidence of an exhalite in the ore or alteration component is not essential for a deposit to be classified as SEDEX. The presence of laminated sulfides parallel to bedding is assumed to be permissive evidence for exhalative ores. The chstinction between some SEDEX and MVT depOSits can be quite subjective because some SEDEX ores replaced carbonate, whereas some MVT depOSits formed in an early diagenetic environment and display laminated ore textures. Geologic and resource information are presented for 248 depositS that provide a framework to describe ,mel compare these deposits. Nine of tlle 10 largest sediment-hosted Pb-Zn deposits are SEDEX, Of the deposits that contain at least 2.5 million metric tons (Mt), there are 35 SEDEX (excluding Broken Hill-type) deposits and 15 MVT (excluding Iris-type) deposits. Despite the skewed distribution of the deposit size, the two deposits types have an excellent correlation between total tonnage and tonnage of contained metal (Pb + Zn), with a fairly consistent ratio of about lO/l, regardless of the size of the deposit or

Zinc and sulfur isotope variation in sphalerite from carbonate-hosted zinc deposits, Cantabria, Spain

NASA Astrophysics Data System (ADS)

Pašava, Jan; Tornos, Fernando; Chrastný, Vladislav

2014-10-01

We studied zinc and sulfur isotopes and the chemical composition of sphalerite samples from Picos de Europa (Aliva mine) and sphalerite and hydrozincite samples from La Florida mine, two carbonate-hosted Mississippi Valley-type (MVT) deposits located in northern Spain; despite being close, they are hosted in carbonatic rocks of different ages, Lower Carboniferous and Lower Cretaceous, respectively. The two generations of sphalerite at Picos de Europa show different δ66Zn values (stage 1 sphalerite +0.24 per mil and stage 2 sphalerite from -0.75 to +0.08 per mil). Both generations also differ in the sulfur isotope composition (stage 1 has δ34S = +6.6 and stage 2 has δ34S = -0.9 to +2.9 per mil) and the chemical composition (stage 1 sphalerite, compared to stage 2 sphalerite, is significantly enriched in Pb, As, Mn, Sb, slightly enriched in Ag, Ni, and Cu and depleted in Co, Ga, Tl, Te, Ge, and Sn). We suggest that Zn isotope fractionation was controlled predominantly by pH and T changes. High Zn isotope values reflect rapid precipitation of sphalerite from higher-temperature acidic fluids that carried Zn mostly as chloride species after interaction with carbonate rocks while lower Zn isotope values most likely resulted from a longer precipitation process from fluid at higher pH and decreasing T that carried dominantly Zn sulfide species. At La Florida, sphalerite samples show light 66Zn-depleted signatures with δ66Zn values from -0.80 to -0.01 per mil (mostly between -0.80 and -0.24 per mil) and δ34S values from +10.7 to +15.7 per mil without any relationship between the δ66Zn and δ34S values. Here, the variation in Zn isotope values is interpreted as related to mixing of fluids from two reservoirs. The Zn was carried by a single deep-seated and higher T (~250-320 °C) fluid, and precipitation took place after mixing with a connate S-rich fluid in a system with mH2S > mZn2+ as a result of change in pH, T, and Zn predominant species. The light δ66Zn

Distribution of trace elements in drilling chip samples around a roll-type uranium deposit, San Juan Basin, New Mexico

USGS Publications Warehouse

Day, H.C.; Spirakis, C.S.; Zech, R.S.; Kirk, A.R.

1983-01-01

Chip samples from rotary drilling in the vicinity of a roll-type uranium deposit in the southwestern San Juan Basin were split into a whole-washed fraction, a clay fraction, and a heavy mineral concentrate fraction. Analyses of these fractions determined that cutting samples could be used to identify geochemical halos associated with this ore deposit. In addition to showing a distribution of selenium, uranium, vanadium, and molybdenum similar to that described by Harshman (1974) in uranium roll-type deposits in Wyoming, South Dakota, and Texas, the chemical data indicate a previously unrecognized zinc anomaly in the clay fraction downdip of the uranium ore.

Hydrogeologic framework and estimates of groundwater storage for the Hualapai Valley, Detrital Valley, and Sacramento Valley basins, Mohave County, Arizona

USGS Publications Warehouse

Truini, Margot; Beard, L. Sue; Kennedy, Jeffrey; Anning, Dave W.

2013-01-01

We have investigated the hydrogeology of the Hualapai Valley, Detrital Valley, and Sacramento Valley basins of Mohave County in northwestern Arizona to develop a better understanding of groundwater storage within the basin fill aquifers. In our investigation we used geologic maps, well-log data, and geophysical surveys to delineate the sedimentary textures and lithology of the basin fill. We used gravity data to construct a basin geometry model that defines smaller subbasins within the larger basins, and airborne transient-electromagnetic modeled results along with well-log lithology data to infer the subsurface distribution of basin fill within the subbasins. Hydrogeologic units (HGUs) are delineated within the subbasins on the basis of the inferred lithology of saturated basin fill. We used the extent and size of HGUs to estimate groundwater storage to depths of 400 meters (m) below land surface (bls). The basin geometry model for the Hualapai Valley basin consists of three subbasins: the Kingman, Hualapai, and southern Gregg subbasins. In the Kingman subbasin, which is estimated to be 1,200 m deep, saturated basin fill consists of a mixture of fine- to coarse-grained sedimentary deposits. The Hualapai subbasin, which is the largest of the subbasins, contains a thick halite body from about 400 m to about 4,300 m bls. Saturated basin fill overlying the salt body consists predominately of fine-grained older playa deposits. In the southern Gregg subbasin, which is estimated to be 1,400 m deep, saturated basin fill is interpreted to consist primarily of fine- to coarse-grained sedimentary deposits. Groundwater storage to 400 m bls in the Hualapai Valley basin is estimated to be 14.1 cubic kilometers (km3). The basin geometry model for the Detrital Valley basin consists of three subbasins: northern Detrital, central Detrital, and southern Detrital subbasins. The northern and central Detrital subbasins are characterized by a predominance of playa evaporite and fine

Adsorption by and artificial release of zinc and lead from porous concrete for recycling of adsorbed zinc and lead and of porous concrete to reduce urban non-point heavy metal runoff.

PubMed

Harada, Shigeki; Yanbe, Miyu

2018-04-01

This report describes the use of porous concrete at the bottom of a sewage trap to prevent runoff of non-point heavy metals into receiving waters, and, secondarily, to reduce total runoff volume during heavy rains in urbanized areas while simultaneously increasing the recharge volume of heavy-metal-free water into underground aquifers. This idea has the advantage of preventing clogging, which is fundamentally very important when using pervious materials. During actual field experiments, two important parameters were identified: maximum adsorption weight of lead and zinc by the volume of porous concrete, and heavy metal recovery rate by artificial acidification after adsorption. To understand the effect of ambient heavy metal concentration, a simple mixing system was used to adjust the concentrations of lead and zinc solutions. The concrete blocks used had been prepared for a previous study by Harada & Komuro (2010). The results showed that maximum adsorption depended on the ambient concentration, expressed as the linear isothermal theory, and that recovery depended on the final pH value (0.5 or 0.0). The dependence on pH is very important for recycling the porous concrete. A pH of 0.5 is important for recycling both heavy metals, especially zinc, (8.0-22.1% of lead and 42-74% of zinc) and porous concrete because porous concrete has not been heavily damaged by acid. However, at a pH of 0.0, the heavy metals could be recovered: 30-60% of the lead and 75-125% of the zinc. At a higher pH, such as 2.0, no release of heavy metals occurred, indicating the safety to the environment of using porous concrete, because the lowest recorded pH of rainfall in Japan is. 4.0. Copyright © 2018 Elsevier Ltd. All rights reserved.

Phanerozoic Rifting Phases And Mineral Deposits

NASA Astrophysics Data System (ADS)

Hassaan, Mahmoud

2016-04-01

In North Africa occur Mediterranean and Red Sea metallogenic provinces. In each province distribute 47 iron- manganese- barite and lead-zinc deposits with tectonic-structural control. The author presents in this paper aspects of position of these deposits in the two provinces with Phanerozoic rifting . The Mediterranean Province belongs to two epochs, Hercynian and Alpine. The Hercynian Epoch manganese deposits in only Moroccoa- Algeria belong to Paleozoic tectonic zones and Proterozoic volcanics. The Alpine Epoch iron-manganese deposits are of post-orogenic exhalative-sedimentary origin. Manganese deposits in southern Morocco occur in Kabil-Rief quartz-chalcedony veins controlled by faults in andesitic sheets and in bedded pelitic tuffs, strata-form lenses and ore veins, in Precambrian schist and in Triassic and Cretaceous dolomites. Disseminated manganese with quartz and barite and effusive hydrothermal veins are hosted in Paleocene volcanics. Manganese deposits in Algeria are limited and unrecorded in Tunisia. Strata-form iron deposits in Atlas Heights are widespread in sub-rift zone among Jurassic sediments inter-bedding volcanic rocks. In Algeria, Group Beni-Saf iron deposits are localized along the Mediterranean coast in terrigenous and carbonate rocks of Jurassic, Cretaceous and Eocene age within faults and bedding planes. In Morocco strata-form hydrothermal lead-zinc deposits occur in contact zone of Tertiary andesite inter-bedding Cambrian shale, Lias dolomites and Eocene andesite. In both Algeria and Tunisia metasomatic Pb-Zn veins occur in Campanian - Maastrichtian carbonates, Triassic breccia, Jurassic limestone, Paleocene sandstones and limestone and Neogene conglomerates and sandstones. The Red Sea metallogenic province belongs to the Late Tertiary-Miocene times. In Wadi Araba hydrothermal iron-manganese deposits occur in Cretaceous sediments within 320°and 310 NW faults related to Tertiary basalt. Um-Bogma iron-manganese deposits are closely

Flexible and High-Performance Amorphous Indium Zinc Oxide Thin-Film Transistor Using Low-Temperature Atomic Layer Deposition.

PubMed

Sheng, Jiazhen; Lee, Hwan-Jae; Oh, Saeroonter; Park, Jin-Seong

2016-12-14

Amorphous indium zinc oxide (IZO) thin films were deposited at different temperatures, by atomic layer deposition (ALD) using [1,1,1-trimethyl-N-(trimethylsilyl)silanaminato]indium (INCA-1) as the indium precursor, diethlzinc (DEZ) as the zinc precursor, and hydrogen peroxide (H 2 O 2 ) as the reactant. The ALD process of IZO deposition was carried by repeated supercycles, including one cycle of indium oxide (In 2 O 3 ) and one cycle of zinc oxide (ZnO). The IZO growth rate deviates from the sum of the respective In 2 O 3 and ZnO growth rates at ALD growth temperatures of 150, 175, and 200 °C. We propose growth temperature-dependent surface reactions during the In 2 O 3 cycle that correspond with the growth-rate results. Thin-film transistors (TFTs) were fabricated with the ALD-grown IZO thin films as the active layer. The amorphous IZO TFTs exhibited high mobility of 42.1 cm 2 V -1 s -1 and good positive bias temperature stress stability. Finally, flexible IZO TFT was successfully fabricated on a polyimide substrate without performance degradation, showing the great potential of ALD-grown TFTs for flexible display applications.

Zinc doping of large-area MoS2 films via chemical vapor deposition

NASA Astrophysics Data System (ADS)

Xu, Enzhi; Liu, Haoming; Park, Kyungwha; Li, Zhen; Losovyj, Yaroslav; Starr, Matthew; Werbianskyj, Madilynn; Fertig, Herbert; Zhang, Shixiong

Atomically thin molybdenum disulfide (MoS2) has attracted significant attention because of its great potential for electronic and optoelectronic applications. Undoped MoS2 is n-type presumably due to the formation of native defects, and realizing p-type conduction has often turned out to be challenging. In this work, we report on the synthesis and characterizations of large-area Zn-doped MoS2 thin films in which the zinc dopant is demonstrated to be p-type. The films were grown by chemical vapor deposition and are monolayers or bilayers with a lateral dimension on the order of millimeters. The p-type nature of Zn dopants was evidenced by the suppression of n-type conduction and a downward shift of the Fermi level with doping. Density-functional-theory calculations were carried out to demonstrate the stability of the Zn dopants and to determine the impurity states. A p-type gate transfer characteristic was observed after the Zn-MoS2 film was thermally annealed in a sulfur atmosphere. This work is supported by the NSF through Grant Nos. DMR-1506460, DMR-1506263, and DMR-1206354, the San Diego Supercomputer Center (SDSC) Gordon under DMR060009N, and by the US-Israel Binational Science Foundation.

Main and interaction effects of iron, zinc, lead, and parenting on children's cognitive outcomes.

PubMed

Hubbs-Tait, Laura; Mulugeta, Afework; Bogale, Alemtsehay; Kennedy, Tay S; Baker, Eric R; Stoecker, Barbara J

2009-01-01

This study examined relations of blood lead < 10 microg/dL, iron, zinc, and parenting to Head Start children's (N = 112) scores on Peabody Picture Vocabulary Test-III (PPVT-III) and McCarthy Scales of Children's Abilities (MSCA). Venous whole blood and plasma samples were analyzed for lead and zinc by ICP-MS and iron status was assessed by serum transferrin receptors. Hierarchical regressions revealed significant effects of lead on MSCA perceptual scores and iron on PPVT-III and MSCA verbal scores. Children with lead > 2.5 microg/dL had significantly lower MSCA perceptual scores than children < 2.5 microg/dL. Permissive parenting significantly exacerbated negative effects of higher lead or lower iron on children's perceptual or verbal scores, respectively.

Biomarkers of metals exposure in fish from lead-zinc mining areas of Southeastern Missouri, USA

USGS Publications Warehouse

Schmitt, C.J.; Whyte, J.J.; Roberts, A.P.; Annis, M.L.; May, T.W.; Tillitt, D.E.

2007-01-01

The potential effects of proposed lead-zinc mining in an ecologically sensitive area were assessed by studying a nearby mining district that has been exploited for about 30 y under contemporary environmental regulations and with modern technology. Blood and liver samples representing fish of three species (largescale stoneroller, Campostoma oligolepis, n=91; longear sunfish, Lepomis megalotis, n=105; and northern hog sucker, Hypentelium nigricans, n=20) from 16 sites representing a range of conditions relative to mining activities were collected. Samples were analyzed for metals (also reported in a companion paper) and for biomarkers of metals exposure [erythrocyte ??-aminolevulinic acid dehydratase (ALA-D) activity; concentrations of zinc protoporphyrin (ZPP), iron, and hemoglobin (Hb) in blood; and hepatic metallothionein (MT) gene expression and lipid peroxidation]. Blood lead concentrations were significantly higher and ALA-D activity significantly lower in all species at sites nearest to active lead-zinc mines and in a stream contaminated by historical mining than at reference or downstream sites. ALA-D activity was also negatively correlated with blood lead concentrations in all three species but not with other metals. Iron and Hb concentrations were positively correlated in all three species, but were not correlated with any other metals in blood or liver in any species. MT gene expression was positively correlated with liver zinc concentrations, but neither MT nor lipid peroxidase differences among fish grouped according to lead concentrations were statistically significant. ZPP was not detected by hematofluorometry in most fish, but fish with detectable ZPP were from sites affected by mining. Collectively, these results confirm that metals are released to streams from active lead-zinc mining sites and are accumulated by fish. ?? 2007 Elsevier Inc. All rights reserved.

Modelling drivers and distribution of lead and zinc concentrations in soils of an urban catchment (Sydney estuary, Australia).

PubMed

Johnson, L E; Bishop, T F A; Birch, G F

2017-11-15

The human population is increasing globally and land use is changing to accommodate for this growth. Soils within urban areas require closer attention as the higher population density increases the chance of human exposure to urban contaminants. One such example of an urban area undergoing an increase in population density is Sydney, Australia. The city also possesses a notable history of intense industrial activity. By integrating multiple soil surveys and covariates into a linear mixed model, it was possible to determine the main drivers and map the distribution of lead and zinc concentrations within the Sydney estuary catchment. The main drivers as derived from the model included elevation, distance to main roads, main road type, soil landscape, population density (lead only) and land use (zinc only). Lead concentrations predicted using the model exceeded the established guideline value of 300mgkg -1 over a large portion of the study area with concentrations exceeding 1000mgkg -1 in the south of the catchment. Predicted zinc did not exceed the established guideline value of 7400mgkg -1 ; however concentrations were higher to the south and west of the study area. Unlike many other studies we considered the prediction uncertainty when assessing the contamination risk. Although the predictions indicate contamination over a large area, the broadness of the prediction intervals suggests that in many of these areas we cannot be sure that the site is contaminated. More samples are required to determine the contaminant distribution with greater precision, especially in residential areas where contamination was highest. Managing sources and addressing areas of elevated lead and zinc concentrations in urban areas has the potential to reduce the impact of past human activities and improve the urban environment of the future. Copyright © 2017 Elsevier B.V. All rights reserved.

Energy Balance, Evapo-transpiration and Dew deposition in the Dead Sea Valley

NASA Astrophysics Data System (ADS)

Metzger, Jutta; Corsmeier, Ulrich

2016-04-01

The Dead Sea is a unique place on earth. It is a terminal hypersaline lake, located at the lowest point on earth with a lake level of currently -429 m above mean sea level (amsl). It is located in a transition zone of semiarid to arid climate conditions, which makes it highly sensible to climate change (Alpert1997, Smiatek2011). The Virtual Institute DEad SEa Research Venue (DESERVE) is an international project funded by the German Helmholtz Association and was established to study coupled atmospheric hydrological, and lithospheric processes in the changing environment of the Dead Sea. At the moment the most prominent environmental change is the lake level decline of approximately 1 m / year due to anthropogenic interferences (Gertman, 2002). This leads to noticeable changes in the fractions of the existing terrestrial surfaces - water, bare soil and vegetated areas - in the valley. Thus, the partitioning of the net radiation in the valley changes as well. To thoroughly study the atmospheric and hydrological processes in the Dead Sea valley, which are driven by the energy balance components, sound data of the energy fluxes of the different surfaces are necessary. Before DESERVE no long-term monitoring network simultaneously measuring the energy balance components of the different surfaces in the Dead Sea valley was available. Therefore, three energy balance stations were installed at three characteristic sites at the coast-line, over bare soil, and within vegetation, measuring all energy balance components by using the eddy covariance method. The results show, that the partitioning of the energy into sensible and latent heat flux on a diurnal scale is totally different at the three sites. This results in gradients between the sites, which are e.g. responsible for the typical diurnal wind systems at the Dead Sea. Furthermore, driving forces of evapo-transpiration at the sites were identified and a detailed analysis of the daily evaporation and dew deposition rates

Properties of zinc tin oxide thin film by aerosol assisted chemical vapor deposition (AACVD)

NASA Astrophysics Data System (ADS)

Riza, Muhammad Arif; Rahman, Abu Bakar Abd; Sepeai, Suhaila; Ludin, Norasikin Ahmad; Teridi, Mohd Asri Mat; Ibrahim, Mohd Adib

2018-05-01

This study focuses on the properties of ZTO which have been deposited by a low-cost method namely aerosol assisted chemical vapor deposition (AACVD). The precursors used in this method were zinc acetate dihidrate and tin chloride dihydrate for ZTO thin film deposition. Both precursors were mixed and stirred until fully dissolved before deposition. The ZTO was deposited on borosilicate glass substrate for the investigation of optical properties. The films deposited have passed the scotch tape adherence test. XRD revealed that the crystal ZTO is slightly in the form of perovskite structure but several deteriorations were also seen in the spectrum. The UV-Vis analysis showed high transmittance of ˜85% and the band gap was calculated to be 3.85 eV. The average thickness of the film is around 284 nm. The results showed that the ZTO thin films have been successfully deposited by the utilization of AACVD method.

Temporal and spatial variations of copper, cadmium, lead, and zinc in Ten Mile Creek in South Florida, USA.

PubMed

Yang, Yuangen; He, Zhenli; Lin, Youjian; Phlips, Edward J; Stoffella, Peter J; Powell, Charles A

2009-01-01

Lead (Pb), zinc (Zn), copper (Cu), and cadmium (Cd) often seriously deteriorate water quality. Spatial and temporal fluctuations of the metal concentrations in the Ten Mile Creek (Florida) (TMC) were monitored on a weekly basis at 7 sampling sites, from June 2005 to September 2007. River sediment samples were also collected from these sites in April, June, and October 2006 and January 2007, and analyzed for water, Mehlich 1 (M1), and Mehlich 3 (M3)-extractable metals (Mehlich, 1953, 1984), to examine the role of sediments as sources or sinks of the metals. The concentrations of lead, zinc, copper, and cadmium in the water samples were lead (zinc (6.45 microg/L), copper (2.53 microg/L), and cadmium (lead, 120 microg/L for zinc, 9.0 microg/L for copper, and 0.25 microg/L for cadmium), pulse concentrations of the metals significantly exceeded these limits. Correlations of lead, zinc, copper, and cadmium concentrations in the TMC to other environmental factors, including the results of principal component analysis, suggest that there are different sources of metals. These sources include surface runoff from agricultural lands or urban wastewater, geological backgrounds, and tidal flow. Water-, M1-, and M3-extractable lead, zinc, copper, and cadmium concentrations in river sediments indicate the possibility that river sediment serves as an internal source of the metals for the TMC. This hypothesis was supported by positive correlations between concentrations of copper, lead, and zinc in the river water and their respective water-extractable concentrations in the sediments.

Quantitative study on the chemical solution deposition of zinc oxysulfide

DOE PAGES

Reinisch, Michael; Perkins, Craig L.; Steirer, K. Xerxes

2015-11-21

Zinc Oxysulfide (ZnOS) has demonstrated potential in the last decade to replace CdS as a buffer layer material since it is a wide-band-gap semiconductor with performance advantages over CdS (E g = 2.4 eV) in the near UV-range for solar energy conversion. However, questions remain on the growth mechanisms of chemical bath deposited ZnOS. In this study, a detailed model is employed to calculate solubility diagrams that describe simple conditions for complex speciation control using only ammonium hydroxide without additional base. For these conditions, ZnOS is deposited via aqueous solution deposition on a quartz crystal microbalance in a continuous flowmore » cell. Data is used to analyze the growth rate dependence on temperature and also to elucidate the effects of dimethylsulfoxide (DMSO) when used as a co-solvent. Activation energies (EA) of ZnOS are calculated for different flow rates and solution compositions. As a result, the measured EA relationships are affected by changes in the primary growth mechanism when DMSO is included.« less

Digital Map of Surficial Geology, Wetlands, and Deepwater Habitats, Coeur d'Alene River Valley, Idaho

USGS Publications Warehouse

Bookstrom, Arthur A.; Box, Stephen E.; Jackson, Berne L.; Brandt, Theodore R.; Derkey, Pamela D.; Munts, Steven R.

1999-01-01

The Coeur d'Alene (CdA) River channel and its floodplain in north Idaho are mostly covered by metal-enriched sediments, partially derived from upstream mining, milling and smelting wastes. Relative to uncontaminated sediments of the region, metal-enriched sediments are highly enriched in silver, lead, zinc, arsenic, antimony and mercury, copper, cadmium, manganese, and iron. Widespread distribution of metal-enriched sediments has resulted from over a century of mining in the CdA mining district (upstream), poor mine-waste containment practices during the first 80 years of mining, and an ongoing series of over-bank floods. Previously deposited metal-enriched sediments continue to be eroded and transported down-valley and onto the floodplain during floods. The centerpiece of this report is a Digital Map Surficial Geology, Wetlands and Deepwater Habitats of the Coeur d'Alene (CdA) River valley (sheets 1 and 2). The map covers the river, its floodplain, and adjacent hills, from the confluence of the North and South Forks of the CdA River to its mouth and delta front on CdA Lake, 43 linear km (26 mi) to the southwest (river distance 58 km or 36 mi). Also included are the following derivative theme maps: 1. Wetland System Map; 2. Wetland Class Map; 3. Wetland Subclass Map; 4. Floodplain Map; 5. Water Regime Map; 6. Sediment-Type Map; 7. Redox Map; 8. pH Map; and 9. Agricultural Land Map. The CdA River is braided and has a cobble-gravel bottom from the confluence to Cataldo Flats, 8 linear km (5 mi) down-valley. Erosional remnants of up to four alluvial terraces are present locally, and all are within the floodplain, as defined by the area flooded in February of 1996. High-water (overflow) channels and partly filled channel scars braid across some alluvial terraces, toward down-valley marshes and (or) oxbow ponds, which drain back to the river. Near Cataldo Flats, the river gradient flattens, and the river coalesces into a single channel with a large friction

[Effects of Different Modifier Concentrations on Lead-Zinc Tolerance, Subcellular Distribution and Chemical Forms for Four Kinds of Woody Plants].

PubMed

Chen, Yong-hua; Zhang, Fu-yun; Wu, Xiao-fu; Liang, Xi; Yuan, Si-wen

2015-10-01

Four kinds of lead-zinc tolerant woody plants: Nerium oleander, Koelreuteria paniculata, Paulownia and Boehmeria were used as materials to estimate their enrichment and transferable capacity of lead (Pb) and zinc (Zn) and analyze the subcellular distribution and chemical speciation of Zn and Ph in different parts of plants, under different modifier concentrations (CK group: 100% lead-zinc slag plus a small amount of phosphate fertilizer, improved one: 85% of lead-zinc slag ± 10% peat ± 5% bacterial manure plus a small amount of phosphate fertilizer, improved two: 75% lead-zinc slag ± 20% peat ± 5% bacterial manure ± a small amount of phosphate). Results showed that: (1) The content of Pb, Zn in matrix after planting four kinds of plants was lower than before, no significant difference between improved one and improved two of Nerium oleander and Boehmeria was found, but improved two was better than improved one of Paulownia, while improved one was better than improved two of Koelreuteria paniculata; Four plants had relatively low aboveground enrichment coefficient of Pb and Zn, but had a high transfer coefficient, showed that the appropriate modifier concentration was able to improve the Pb and Zn enrichment and transfer ability of plants. (2) In subcellular distribution, most of Pb and Zn were distributed in plant cell wall components and soluble components while the distribution in cell organelles such as mitochondria, chloroplasts and nucleus component were less. Compared with CK group, two improved group made soluble components of the cell walls of Pb fixation and retention of zinc role in the enhancement. (3) As for the chemical forms of Pb and Zn in plants, the main chemical forms of Pb were hydrochloric acid, sodium chloride and ethanol extractable forms, while other chemical form contents were few, the main chemical forms of Zn were different based on plant type. Compared with CK group, the proportion of the active Pb chemical form in different plant

Contamination of wells completed in the Roubidoux aquifer by abandoned zinc and lead mines, Ottawa County, Oklahoma

USGS Publications Warehouse

Christenson, Scott C.

1995-01-01

The Roubidoux aquifer in Ottawa County Oklahoma is used extensively as a source of water for public supplies, commerce, industry, and rural water districts. Water in the Roubidoux aquifer in eastern Ottawa County has relatively low dissolved-solids concentrations (less than 200 mg/L) with calcium, magnesium, and bicarbonate as the major ions. The Boone Formation is stratigraphically above the Roubidoux aquifer and is the host rock for zinc and lead sulfide ores, with the richest deposits located in the vicinity of the City of Picher. Mining in what became known as the Picher mining district began in the early 1900's and continued until about 1970. The water in the abandoned zinc and lead mines contains high concentrations of calcium, magnesium, bicarbonate, sulfate, fluoride, cadmium, copper, iron, lead, manganese, nickel, and zinc. Water from the abandoned mines is a potential source of contamination to the Roubidoux aquifer and to wells completed in the Roubidoux aquifer. Water samples were collected from wells completed in the Roubidoux aquifer in the Picher mining district and from wells outside the mining district to determine if 10 public supply wells in the mining district are contaminated. The chemical analyses indicate that at least 7 of the 10 public supply wells in the Picher mining district are contaminated by mine water. Application of the Mann-Whitney test indicated that the concentrations of some chemical constituents that are indicators of mine-water contamination are different in water samples from wells in the mining area as compared to wells outside the mining area. Application of the Wilcoxon signed-rank test showed that the concentrations of some chemical constituents that are indicators of mine-water contamination were higher in current (1992-93) data than in historic (1981-83) data, except for pH, which was lower in current than in historic data. pH and sulfate, alkalinity, bicarbonate, magnesium, iron, and tritium concentrations consistently

The effects of CaEDTA injection on lead, zinc, copper and ALAD in erythrocyte, plasma and urine in lead-exposed workers: a 24-h observation.

PubMed

Aono, H; Araki, S

1984-01-01

To evaluate the effects of calcium disodium ethylenediamine tetraacetate (CaEDTA) on the concentrations of lead, zinc and copper in plasma, erythrocyte and urine, and the delta-aminolevulinic acid dehydratase (ALAD) activity in erythrocyte, we administered CaEDTA in 1-h intravenous infusion to ten male gun metal founders with blood-lead concentration of 39 to 64 micrograms/dl (mean 49 micrograms/dl). We found that the plasma concentration of lead, following a rapid rise within the first 3 h, fell temporarily to the level significantly lower than the initial level 19 h after start of the infusion. The plasma concentration of zinc fell to the minimal level 5 h after the infusion; and the erythrocyte concentration of zinc and the ALAD activity concurrently rose to the maximal level 5 h after the infusion. By contrast, no significant alteration was observed in the concentrations of copper in plasma and erythrocyte. The maximal level of urinary metal excretion was attained during the period between 1 and 2 h after start of CaEDTA infusion for lead; within 2 h for zinc; and between 2 and 4 h for copper. The urinary metal excretion returned to the initial level 14 to 24 h after infusion for zinc and copper; but lead excretion was still higher than the initial level during this period. The difference in the kinetics of the three metals following CaEDTA injection is discussed in the light of these findings.

Determination of Cadmium, Lead and Zinc in Vegetables in Jaipur (India).

PubMed

Kumar, Ashok; Verma, P S

2014-01-01

An atomic absorption spectroscopic method was used for the determination of Lead, Cadmium and Zinc in vegetables grown in and around Jaipur food stuffs irrigated with industrial waste water. Vegetable samples were collected after maturity, and analyzed, such as spinach (Spinacia oleracea), ladyfinger (Abelmoschus esulentus), pepper mint (Menthe pipereta), brinjal (Solanum melongena), coriander (Coriandrum sativum), cauliflower (Brassica oleracea), onion (Allium cepa), radish (Raphanus sativus), pointedgourd (Trichosanthes dioica), bottlegourd (Lagenaria siceraria), chilies (Capsicum annum), ribbedgourd (Luffa acutangula) and pumpkin (Curcurbites pepo). The concentration of Lead ranged between 1.40-71.06 ppm, Cadmium 0.61-34.48 ppm and Zinc 0.39-187.26 ppm in vegetable samples. The results reveal that urban consumers are at greater risk of purchasing fresh vegetables with high levels of heavy metal, beyond the permissible limits, as defined by the Indian Prevention of Food Adulteration Act, 1954 and WHO.

Chelating ionic liquids for reversible zinc electrochemistry.

PubMed

Kar, Mega; Winther-Jensen, Bjorn; Forsyth, Maria; MacFarlane, Douglas R

2013-05-21

Advanced, high energy-density, metal-air rechargeable batteries, such as zinc-air, are of intense international interest due to their important role in energy storage applications such as electric and hybrid vehicles, and to their ability to deal with the intermittency of renewable energy sources such as solar and wind. Ionic liquids offer a number of ideal thermal and physical properties as potential electrolytes in such large-scale energy storage applications. We describe here the synthesis and characterisation of a family of novel "chelating" ILs designed to chelate and solubilize the zinc ions to create electrolytes for this type of battery. These are based on quaternary alkoxy alkyl ammonium cations of varying oligo-ether side chains and anions such as p-toluene sulfonate, bis(trifluoromethylsulfonyl)amide and dicyanoamides. This work shows that increasing the ether chain length in the cation from two to four oxygens can increase the ionic conductivity and reduce the melting point from 67 °C to 15 °C for the tosylate system. Changing the anion also plays a significant role in the nature of the zinc deposition electrochemistry. We show that zinc can be reversibly deposited from [N(222(20201))][NTf2] and [N(222(202020201))][NTf2] beginning at -1.4 V and -1.7 V vs. SHE, respectively, but not in the case of tosylate based ILs. This indicates that the [NTf2] is a weaker coordinating anion with the zinc cation, compared to the tosylate anion, allowing the coordination of the ether chain to dominate the behavior of the deposition and stripping of zinc ions.

Zinc electrode and rechargeable zinc-air battery

DOEpatents

Ross, Jr., Philip N.

1989-01-01

An improved zinc electrode is disclosed for a rechargeable zinc-air battery comprising an outer frame and a porous foam electrode support within the frame which is treated prior to the deposition of zinc thereon to inhibit the formation of zinc dendrites on the external surface thereof. The outer frame is provided with passageways for circulating an alkaline electrolyte through the treated zinc-coated porous foam. A novel rechargeable zinc-air battery system is also disclosed which utilizes the improved zinc electrode and further includes an alkaline electrolyte within said battery circulating through the passageways in the zinc electrode and an external electrolyte circulation means which has an electrolyte reservoir external to the battery case including filter means to filter solids out of the electrolyte as it circulates to the external reservoir and pump means for recirculating electrolyte from the external reservoir to the zinc electrode.

Geomorphological characteristics of increased landslide activity in the Gudbrandsdalen valley, Norway

NASA Astrophysics Data System (ADS)

Heyerdahl, Håkon; Høydal, Øyvind

2016-04-01

The Gudbrandsdalen valley in Eastern Norway lies in a region where annual precipitation is generally low (down to 300 mm/year). The landslide activity has consequently historically been low, although the lower part of the valley sides generally is draped with thick layers of Quaternary deposits, primarily of glacial or glaciofluvial origin. The perception of natural hazards in the valley was previously primarily connected to flooding in the main river in the valley bottom during early summer, due to large discharges resulting from snowmelt in the mountainous regions west and east of the valley. However, several high-intensity events have changed the image of the region. Starting with a localized, but intense, landslide event in the Northern part of the valley in year 2008, two larger events covering almost the entire valley occurred in the years 2011 and 2013. A high number of landslides was triggered in all these events, including many flash floods and debris flows/debris slides in small and steep tributary rivers along the valley slopes. Landslide triggering covers different release mechanisms: In 2008, landslides were triggered without precipitation in not-frozen soil deposits without snow cover in the lower part of the valley. Groundwater flow through the permeable bedrock ("Otta schist") resulting from snow-melt in the elevated mountainous areas caused landslide triggering due to positive pore-water pressures forming at the bedrock surface below soil deposits, or at depressions in the terrain. Subsequent rainfall resulted in even more landslides being released. In later events (years 2011 and 2013) many landslides were caused by surface water taking new paths downslope, often due to man-made changes in existing waterways (typically poorly planned drainage solutions or new roads). Relatively small discharges in slopes with unconsolidated and easily erodible glacial deposits (typically lateral moraine) in many cases lead to small initial slides that down

Subsurface geology of the late Tertiary and Quaternary water-bearing deposits of the southern part of the San Joaquin Valley, California

USGS Publications Warehouse

Croft, M.G.

1972-01-01

The study area, which includes about 5,000 square miles of the southern part of the San Joaquin Valley, is a broad structural trough of mostly interior drainage. The Sierra Nevada on the east is composed of consolidated igneous and metamorphic rocks of pre-Tertiary age. The surface of these rocks slopes 4?-6? southwestward from the foothills and underlies the valley. The Coast Ranges on the west consist mostly of complexly folded and faulted consolidated marine and nonmarine sedimentary rocks of Jurassic, Cretaceous, and Tertiary age, which dip eastward and overlie the basement complex. Unconsolidated deposits, of late Pliocene to Holocene age, blanket the underlying consolidated rocks in the valley and are the source of most of the fresh ground water. The unconsolidated deposits, the subject of this report, are divided into informal stratigraphic units on the basis of source of sediment, environment of deposition, and texture. Flood-basin, lacustrine, and marsh deposits are fine grained and underlie the valley trough. They range in age from late Pliocene to Holocene. These deposits, consisting of nearly impermeable gypsiferous fine sand, silt, and clay, are more than 3,000 feet thick beneath parts of Tulare Lake bed. In other parts of the trough, flood-basin, lacustrine, and marsh deposits branch into clayey or silty clay tongues designated by the letter symbols A to F. Three of these tongues, the E, C, and A clays, lie beneath large areas of the southern part of the valley. The E clay includes the Corcoran Clay Member of the Tulare Formation, the most extensive hydrologic confining layer in the valley. The E clay underlies about 3,500 square miles of bottom land and western slopes. The beds generally are dark-greenish-gray mostly diatomaceous silty clay of Pleistocene age. Marginally, the unit bifurcates into an upper and a lower stratum that contains thin beds of moderately yellowish-brown silt and sand. The E clay is warped into broad, gentle northwesterly

Natural Attenuation of Arsenic, Cadmium, Lead, and Zinc Using Hydrograph Separation

NASA Astrophysics Data System (ADS)

Burrows, J. E.; Peters, S. C.

2009-12-01

Strategies for remediating contaminated sites range from complete removal of the contaminated soil to in-situ monitored natural attenuation. The decision to let a property naturally attenuate is partially based on the estimated time it will take to return to ambient conditions. The Lehigh Gap Wildlife Refuge at Palmerton, PA was historically contaminated with arsenic, cadmium, lead, and zinc from a zinc smelting operation that ceased emissions twenty-nine years ago. This property provides an opportunity to assess whether the length of time required for the natural attenuation of metals in soil has been achieved using a watershed mass balance approach, focusing particularly on perturbations observed in the concentration-discharge relationships of contaminants compared to the conservative tracers sodium and chloride, and silicon as an indicator of rock-water interactions. Water samples were collected from 3 springs in the Wildlife Refuge for approximately 4 days following the onset of storm events and analyzed for cation and anion concentrations. Preliminary results show that while the concentrations of arsenic and lead were below detection limits, the fluxes of zinc and cadmium increase corresponding with the peak in the hydrograph relative to the fluxes of the tracers, indicating the solutes are being released from adsorption sites located in an unsaturated zone that is temporarily inundated during storm events. In comparison, the flux of the tracers remains constant, indicative of a steady-state leakage of the solutes from their respective reservoirs in the soil. Along with flux, the concentrations of zinc and cadmium also increase following the rise in discharge after storm events, further suggesting that these contaminants are being mobilized out of the soil profile.

Single and Combined Exposure to Zinc- and Copper-Containing Welding Fumes Lead to Asymptomatic Systemic Inflammation.

PubMed

Markert, Agnieszka; Baumann, Ralf; Gerhards, Benjamin; Gube, Monika; Kossack, Veronika; Kraus, Thomas; Brand, Peter

2016-02-01

Recently, it has been shown that exposure to welding fumes containing both zinc and copper leads to asymptomatic systemic inflammation in humans as shown by an increase of blood C-reactive protein. In the present study, it was investigated which metal is responsible for this effect. Fifteen healthy male subjects were exposed under controlled conditions to welding fumes containing either zinc, or copper, or copper and zinc. For each exposure blood C-reactive protein increased. Copper- and zinc-containing welding fumes are able to induce systemic inflammation.

Arsenic in midwestern glacial deposits? Occurrence and relation to selected hydrogeologic and geochemical factors

USGS Publications Warehouse

Thomas, Mary Ann

2003-01-01

Ground-water-quality data collected as part of 12 U.S. Geological Survey National Water-Quality Assessment studies during 1996-2001 were analyzed to (1) document arsenic occurrence in four types of gla-cial deposits that occur in large areas of the Midwest, (2) identify hydrogeologic or geochemical factors asso-ciated with elevated arsenic concentrations, and (3) search for clues as to arsenic source(s) or mechanism(s) of mobilization that could be useful for designing future studies. Arsenic and other water-quality constituents were sampled in 342 monitor and domestic wells in parts of Illinois Indiana Ohio Michigan and Wisconsin. Arsenic was detected (at a concentration >1 ?g/L) in one-third of the samples. The maximum concentration was 84 ?g/L, and the median was less than 1 ?g/L. Eight percent of samples had arsenic concentrations that exceeded the U.S. Environmental Protection Agency Maximum Contaminant Level (MCL) of 10?g/L. Samples were from four aquifer types?confined valley fill, unconfined valley fill, outwash plain, and till with sand lenses. Highest arsenic concentrations were found in reducing waters from valley-fill depos-its. In confined valley fill, all waters were reducing and old (recharged before 1953), and almost half of sam-ples had arsenic concentrations greater than the MCL. In unconfined valley fill, redox conditions and ages were varied, and elevated arsenic concentrations were sporadic. In both types of valley fill, elevated arsenic concentrations are linked to the underlying bedrock on the basis of spatial relations and geochemical correla-tions. In shallow (150 ft), all deep wells were from a distinctive aquifer type (confined valley fill). It is not known whether wells at similar depths in other aquifer types would produce waters with simi-larly high arsenic concentrations. Correlations of arsenic with fluoride, strontium, and barium suggest that arsenic might be related to epi-genetic (Mississippi Valley-type) sulfide deposits in

Occurrence and variability of mining-related lead and zinc in the Spring River flood plain and tributary flood plains, Cherokee County, Kansas, 2009--11

USGS Publications Warehouse

Juracek, Kyle E.

2013-01-01

Historical mining activity in the Tri-State Mining District (TSMD), located in parts of southeast Kansas, southwest Missouri, and northeast Oklahoma, has resulted in a substantial ongoing input of cadmium, lead, and zinc to the environment. To provide some of the information needed to support remediation efforts in the Cherokee County, Kansas, superfund site, a 4-year study was begun in 2009 by the U.S. Geological Survey that was requested and funded by the U.S. Environmental Protection Agency. A combination of surficial-soil sampling and coring was used to investigate the occurrence and variability of mining-related lead and zinc in the flood plains of the Spring River and several tributaries within the superfund site. Lead- and zinc-contaminated flood plains are a concern, in part, because they represent a long-term source of contamination to the fluvial environment. Lead and zinc contamination was assessed with reference to probable-effect concentrations (PECs), which represent the concentrations above which adverse aquatic biological effects are likely to occur. The general PECs for lead and zinc were 128 and 459 milligrams per kilogram, respectively. The TSMD-specific PECs for lead and zinc were 150 and 2,083 milligrams per kilogram, respectively. Typically, surficial soils in the Spring River flood plain had lead and zinc concentrations that were less than the general PECs. Lead and zinc concentrations in the surficial-soil samples were variable with distance downstream and with distance from the Spring River channel, and the largest lead and zinc concentrations usually were located near the channel. Lead and zinc concentrations larger than the general or TSMD-specific PECs, or both, were infrequent at depth in the Spring River flood plain. When present, such contamination typically was confined to the upper 2 feet of the core and frequently was confined to the upper 6 inches. Tributaries with few or no lead- and zinc-mined areas in the basin—Brush Creek

Low-Resistivity Zinc Selenide for Heterojunctions

NASA Technical Reports Server (NTRS)

Stirn, R. J.

1986-01-01

Magnetron reactive sputtering enables doping of this semiconductor. Proposed method of reactive sputtering combined with doping shows potential for yielding low-resistivity zinc selenide films. Zinc selenide attractive material for forming heterojunctions with other semiconductor compounds as zinc phosphide, cadmium telluride, and gallium arsenide. Semiconductor junctions promising for future optoelectronic devices, including solar cells and electroluminescent displays. Resistivities of zinc selenide layers deposited by evaporation or chemical vapor deposition too high to form practical heterojunctions.

Ages and sources of components of Zn-Pb, Cu, precious metal, and platinum group element deposits in the goodsprings district, Clark County, Nevada

USGS Publications Warehouse

Vikre, Peter G.; Browne, Quentin J.; Fleck, Robert J.; Hofstra, Albert H.; Wooden, Joseph L.

2011-01-01

The Goodsprings district, Clark County, Nevada, includes zinc-dominant carbonate replacement deposits of probable late Paleozoic age, and lead-dominant carbonate replacement deposits, copper ± precious metal-platinum group element (PGE) deposits, and gold ± silver deposits that are spatially associated with Late Triassic porphyritic intrusions. The district encompasses ~500 km2 although the distribution of all deposits has been laterally condensed by late Mesozoic crustal contraction. Zinc, Pb, and Cu production from about 90 deposits was ~160,000 metric tons (t) (Zn > Pb >> Cu), 2.1 million ounces (Moz) Ag, 0.09 Moz Au, and small amounts of PGEs—Co, V, Hg, Sb, Ni, Mo, Mn, Ir, and U—were also recovered.Zinc-dominant carbonate replacement deposits (Zn > Pb; Ag ± Cu) resemble Mississippi Valley Type (MVT) Zn-Pb deposits in that they occur in karst and fault breccias in Mississippian limestone where the southern margin of the regional late Paleozoic foreland basin adjoins Proterozoic crystalline rocks of the craton. They consist of calcite, dolomite, sphalerite, and galena with variably positive S isotope compositions (δ34S values range from 2.5–13‰), and highly radiogenic Pb isotope compositions (206Pb/204Pb >19), typical of MVT deposits above crystalline Precambrian basement. These deposits may have formed when southward flow of saline fluids, derived from basinal and older sedimentary rocks, encountered thinner strata and pinch-outs against the craton, forcing fluid mixing and mineral precipitation in karst and fault breccias. Lead-dominant carbonate replacement deposits (Pb > Zn, Ag ± Cu ± Au) occur among other deposit types, often near porphyritic intrusions. They generally contain higher concentrations of precious metals than zinc-dominant deposits and relatively abundant iron oxides after pyrite. They share characteristics with copper ± precious metal-PGE and gold ± silver deposits including fine-grained quartz replacement of carbonate minerals

Hot-spring sinter deposits in the Alvord-Pueblo Valley, Harney County, Oregon

DOE Office of Scientific and Technical Information (OSTI.GOV)

Cummings, M.L.; St. John, A.M.

1993-04-01

Silica sinter deposits occur at Borax Lake, Alvord Hot Springs, and Mickey Springs in the Alvord-Pueblo Valley. Although the sinter deposits occur in areas of active hot springs, sinter is not being deposited. Hot springs are localized along faults that have been active since the Pleistocene. The sinter deposits formed after the drying of glacial Lake Alvord, but before and during extensive wind deflation of glacial-lacustrine sediments. At Mickey Springs, sinter rests directly on unaltered, unconsolidated lithic-rich sand. At Borax Lake, sinter overlies unaltered diatomite, but some armoring, presumably by silica, of the 30 m vent has developed. Field relationsmore » suggest rapid dumping of silica from solution without alteration of the country rock at the vent. Discharge of thermal fluids and cold groundwater along the same structure may have produced colloidal silica carried in a solution stripped of dissolved silica. Sinter is composed of opal-a, traces of detrital feldspar and quartz, and evaporation-related boracite. The concentration of Sb is similar among the three sinter deposits (20 to 70 ppm); however, As, Cs, and Br are highest at Borax Lake (5 to 560 ppm; 26 to 118 ppm; 5 to 1,040 ppm) while Hg is highest at Mickey Springs (1.0 to 5.2 ppm).« less

Numerical modeling of incised-valley deposits in Tokyo lowland for the last 13 kyrs

NASA Astrophysics Data System (ADS)

Kubo, Y.; Syvitski, J. P.; Hutton, E. W.; Tanabe, S.

2006-12-01

A coupled-simulation by the hydrologic model HydroTrend and the stratigraphic model SedFlux is applied to the incised-valley-fill deposits in the Tokyo lowland for the last 13,000 years. The postglacial sediments supplied by paleo Tonegawa River have formed deltaic deposits controlled by eustatic sea-level rise after LGM. The effects of changes in sea level, climate, and morphology on the resultant architecture of the deposits are simulated and analyzed by the numerical models. Synthetic sediment flux from the paleo Tonegawa is computed by the hydrologic model HydroTrend. The model predicts variation in average rate of sediment production over geological time scale from changes in drainage area, precipitation, temperature and morphology. Random variation based on statistic climate data is added to the predicted average values to provide daily sediment discharge. The model prediction indicates that, despite 80% increase in drainage area in the past, competing effects of decreased precipitation resulted in relatively stable sediment discharge over the last 13,000 years. On the other hand, variation in daily sediment discharge shows drastic increase during infrequent storm events. Possible occurrence of hyperpycnal flows at the river mouth was indicated during such storms, which produced daily sediment load ten times larger than average yearly sediment discharge. The estimated sediment supply is used as input to the process-based forward-model 2D-SedFlux. SedFlux is able to simulate transport and deposition of sediments by such processes as river plume, bedload dumping and ocean storms with changing boundary conditions of sea level and basement morphology. The simulation is based on the initial paleo-morphology reconstructed from integrated core analysis from the area. 2D-SedFlux successfully predicts the formation of transgressive deposits and subsequent prograding delta deposits, and the results are comparable to general architecture of incised-valley fills in the

Zinc isotopes in sphalerite from base metal deposits in the Red Dog district, northern Alaska

USGS Publications Warehouse

Kelley, K.D.; Wilkinson, J.J.; Chapman, J.B.; Crowther, H.L.; Weiss, D.J.

2009-01-01

Analyses of sphalerite samples from shale-hosted massive sulfide and stratigraphically underlying vein breccia deposits in the Red Dog district in northern Alaska show a range ??66Zn values from zero to 0.60 per mil. The lowest values are observed in the vein breccia deposits, and the stratigraphically overlying (but structurally displaced) shale-hosted massive sulfide deposits show a systematic trend of increasing ??66Zn values from south to north (Main-Aqqaluk-Paalaaq-Anarraaq). The ??66Zn values are inversely correlated with sphalerite Fe/Mn ratio and also tend to be higher in low Cu sphalerite, consistent with precipitation of lower ??66Zn sphalerite closer to the principal hydrothermal fluid conduits. The most likely control on isotopic variation is Rayleigh fractionation during sulfide precipitation, with lighter zinc isotopes preferentially incorporated in the earliest sphalerite to precipitate from ore fluids at deeper levels (vein breccias) and close to the principal fluid conduits in the orebodies, followed by precipitation of sulfides with higher ??66Zn values in shallower and/or more distal parts of the flow path. There is no systematic variation among the paragenetic stages of sphalerite from a single deposit, suggesting an isotopically homogeneous zinc source and consistent transport-deposition conditions and/or dissolution-reprecipitation of earlier sphalerite without significant fractionation. Decoupled Zn and S isotope compositions are best explained by mixing of separate metal- and sulfur-bearing fluids at the depositional site. The results confirm that Zn isotopes may be a useful tracer for distinguishing between the central and distal parts of large hydrothermal systems as previously suggested and could therefore be of use in exploration. ?? 2009 by Economic Geology.

Early Permian conodont fauna and stratigraphy of the Garden Valley Formation, Eureka County, Nevada

USGS Publications Warehouse

Wardlaw, Bruce R.; Gallegos, Dora M.; Chernykh, Valery V.; Snyder, Walter S.

2015-01-01

The lower Part of the Garden Valley Formation yields two distinct conodont faunas. One of late Asselian age dominated by Mesogondolella and Streptognathodus and one of Artinskian age dominated by Sweetognathus with Mesogondolella. The Asselian fauna contains the same species as those found in the type area of the Asselian in the southern Urals including Mesogondolella dentiseparata, described for the first time outside of the Urals. Apparatuses for Sweetognathus whitei, Diplognathodus stevensi, and Idioprioniodus sp. are described. The Garden Valley Formation represents a marine pro-delta basin and platform, and marine and shore fan delta complex deposition. The fan-delta complex was most likely deposited from late Artinskian to lateWordian. The Garden Valley Formation records tremendous swings in depositional setting from shallow-water to basin to shore.

Early Permian conodont fauna and stratigraphy of the Garden Valley Formation, Eureka County, Nevada

USGS Publications Warehouse

Wardlaw, Bruce R.; Gallegos, Dora M.; Chernykh, Valery V.; Snyder, Walter S.

2015-01-01

The lower part of the Garden Valley Formation yields two distinct conodont faunas. One of late Asselian age dominated by Mesogondolella and Streptognathodus and one of Artinskian age dominated by Sweetognathus with Mesogondolella. The Asselian fauna contains the same species as those found in the type area of the Asselian in the southern Urals including Mesogondolella dentiseparata, described for the first time outside of the Urals. Apparatuses for Sweetognathus whitei, Diplognathodus stevensi, and Idioprioniodus sp. are described. The Garden Valley Formation represents a marine pro-delta basin and platform, and marine and shore fan delta complex deposition. The fan-delta complex was most likely deposited from late Artinskian to late Wordian. The Garden Valley Formation records tremendous swings in depositional setting from shallow-water to basin to shore.

Effects of lead and zinc mining contamination on bacterial community diversity and enzyme activities of vicinal cropland.

PubMed

Qu, Juanjuan; Ren, Guangming; Chen, Bao; Fan, Jinghua; E, Yong

2011-11-01

In the process of mining activity, many kinds of heavy metals enter into soils with dust, causing serious contamination to the environment. In this study, six soils were sampled from cropland at different distances from a lead/zinc mine in Heilongjiang Province, China. The total contents of lead and zinc in the vicinal cropland exceeded the third level of environmental quality standard for soil in China, which indicated that soils in this area were moderately contaminated. Bacterial community diversity and population were greatly decreased when the concentrations of lead and zinc were beyond 1,500 and 995 mg kg(-1), respectively, as analyzed by plate counting and polymerase chain reaction-denaturing gradient gel electrophoresis (PCR-DGGE). The bands of DGGE patterns varied with the degree of contamination. The activities of soil urease, phosphatase, and dehydrogenase were negatively correlated with the concentrations of lead and zinc. The highest inhibitory effect of heavy metals on soil enzyme activities was observed in urease. It was noted that PCR-DGGE patterns combined with soil enzyme activity analysis can be indices for the soil quality assessment by heavy metal contamination.

Pulsed direct flame deposition and thermal annealing of transparent amorphous indium zinc oxide films as active layers in field effect transistors.

PubMed

Kilian, Daniel; Polster, Sebastian; Vogeler, Isabell; Jank, Michael P M; Frey, Lothar; Peukert, Wolfgang

2014-08-13

Indium-zinc oxide (IZO) films were deposited via flame spray pyrolysis (FSP) by pulsewise shooting a Si/SiO2 substrate directly into the combustion area of the flame. Based on UV-vis measurements of thin-films deposited on glass substrates, the optimal deposition parameters with respect to low haze values and film thicknesses of around 100 nm were determined. Thermal annealing of the deposited films at temperatures between 300 and 700 °C was carried out and staggered bottom gate thin-film transistors (TFT) were fabricated. The thin films were investigated by scanning electron microscopy, atomic force microscopy, X-ray diffraction, Fourier transformed infrared spectroscopy, and room-temperature photoluminescence measurements. The outcome of these investigations lead to two major requirements in order to implement a working TFT: (i) organic residues from the deposition process need to be removed and (ii) the net free charge carrier concentration has to be minimized by controlling the trap states in the semiconductor. The optimal annealing temperature was 300 °C as both requirements are fulfilled best in this case. This leads to field effect transistors with a low hysteresis, a saturation mobility of μSat = 0.1 cm(2)/(V s), a threshold voltage of Vth = -18.9 V, and an Ion/Ioff ratio on the order of 10(7). Depending on thermal treatment, the defect density changes significantly strongly influencing the transfer characteristics of the device.

Legacy sediment, lead, and zinc storage in channel and floodplain deposits of the Big River, Old Lead Belt Mining District, Missouri, USA

NASA Astrophysics Data System (ADS)

Pavlowsky, Robert T.; Lecce, Scott A.; Owen, Marc R.; Martin, Derek J.

2017-12-01

The Old Lead Belt of southeastern Missouri was one of the leading producers of Pb ore for more than a century (1869-1972). Large quantities of contaminated mine waste have been, and continue to be, supplied to local streams. This study assessed the magnitude and spatial distribution of mining-contaminated legacy sediment stored in channel and floodplain deposits of the Big River in the Ozark Highlands of southeastern Missouri. Although metal concentrations decline downstream from the mine sources, the channel and floodplain sediments are contaminated above background levels with Pb and Zn along its entire 171-km length below the mine sources. Mean concentrations in floodplain cores > 2000 mg kg- 1 for Pb and > 1000 mg kg- 1 for Zn extend 40-50 km downstream from the mining area in association with the supply of fine tailings particles that were easily dispersed downstream in the suspended load. Mean concentrations in channel bed and bar sediments ranging from 1400 to 1700 mg kg- 1 for Pb extend 30 km below the mines, while Zn concentrations of 1000-3000 mg kg- 1 extend 20 km downstream. Coarse dolomite fragments in the 2-16 mm channel sediment fraction provide significant storage of Pb and Zn, representing 13-20% of the bulk sediment storage mass in the channel and can contain concentrations of > 4000 mg kg- 1 for Pb and > 1000 mg kg- 1 for Zn. These coarse tailings have been transported a maximum distance of only about 30 km from the source over a period of 120 years for an average of about 250 m/y. About 37% of the Pb and 9% of the Zn that was originally released to the watershed in tailings wastes is still stored in the Big River. A total of 157 million Mg of contaminated sediment is stored along the Big River, with 92% of it located in floodplain deposits that are typically contaminated to depths of 1.5-3.5 m. These contaminated sediments store a total of 188,549 Mg of Pb and 34,299 Mg of Zn, of which 98% of the Pb and 95% of the Zn are stored in floodplain

Geologic Criteria for the Assessment of Sedimentary Exhalative (Sedex) Zn-Pb-Ag Deposits

USGS Publications Warehouse

Emsbo, Poul

2009-01-01

Sedex deposits account for more than 50 percent of the world's zinc and lead reserves and furnish more than 25 percent of the world's production of these two metals. This report draws on previous syntheses as well as on topical studies of deposits in sedex basins to determine the characteristics and processes that produced sedex deposits. This analysis also uses studies of the tectonic, sedimentary, and fluid evolution of modern and ancient sedimentary basins and mass balance constraints to identify the hydrothermal processes that are required to produce sedex deposits. This report demonstrates how a genetic model can be translated into geologic criteria that can be used in the U.S. Geological Survey National Assessments for sedex zinc-lead-silver deposits to define permissive tracts, assess the relative prospectivity of permissive tracts, and map favorability within permissive tracts.

Annual trace-metal load estimates and flow-weighted concentrations of cadmium, lead, and zinc in the Spokane River basin, Idaho and Washington, 1999-2004

USGS Publications Warehouse

Donato, Mary M.

2006-01-01

differences in the two regression models, 1999-2001 and 1999-2004. Flow-weighted concentrations (FWCs) calculated from the estimated loads for 1999-2004 were examined to aid interpretation of metal load estimates, which were influenced by large spatial and temporal variations in streamflow. FWCs of total cadmium ranged from 0.04 micrograms per liter (?g/L) at Enaville to 14 ?g/L at Ninemile Creek. Total lead FWCs were lowest at Long Lake (1.3 ?g/L) and highest at Ninemile Creek (120 ?g/L). Elevated total lead FWCs at Harrison confirmed that the high total lead loads at this station were not simply due to higher streamflow. Conversely, relatively low total lead loads combined with high total lead FWCs at Ninemile and Canyon Creeks reflected low streamflow but high concentrations of total lead. Very low total lead FWCs (1.3 to 2.7 ?g/L) at the stations downstream of Coeur d'Alene Lake are a result both of deposition of lead-laden sediments in the lake and dilution by additional streamflow. Total zinc FWCs also demonstrated the effect of streamflow on load calculations, and highlighted source areas for zinc in the basin. Total zinc FWCs at Canyon and Ninemile Creeks, 1,600 ?g/L and 2,200 ?g/L, respectively, were by far the highest in the basin but contributed among the lowest total zinc loads due to their relatively low streamflow. Total zinc FWCs ranged from 38 to 67 ?g/L at stations downstream of Coeur d'Alene Lake, but total zinc load estimates at these stations were relatively high because of high mean streamflow compared to other stations in the basin. Long-term regression models for 1991 to 2003 or 2004 were developed and annual trace-metal loads and FWCs were estimated for Pinehurst, Enaville, Harrison, and Post Falls to better understand the variability of metal loading with time. Long-term load estimates are similar to the results for 1999-2004 in terms of spatial distribution of metal loads throughout the basin. LOADEST results for 1991-2004 indicated that

Regional stratigraphy and distribution of epigenetic stratabound celestine, fluorite, barite and Pb-Zn deposits in the MVT province of northeastern Mexico

NASA Astrophysics Data System (ADS)

González-Sánchez, Francisco; Camprubí, Antoni; González-Partida, Eduardo; Puente-Solís, Rafael; Canet, Carles; Centeno-García, Elena; Atudorei, Viorel

2009-04-01

Northeastern Mexico hosts numerous epigenetic stratabound carbonate-hosted low-temperature hydrothermal deposits of celestine, fluorite, barite and zinc-lead, which formed by replacement of Mesozoic evaporites or carbonate rocks. Such deposits can be permissively catalogued as Mississippi Valley-type (MVT) deposits. The deposits studied in the state of Coahuila are associated with granitic and metasedimentary basement highs (horsts) marginal or central to the Mesozoic Sabinas Basin. These horsts controlled the stratigraphy of the Mesozoic basins and subsequently influenced the Laramide structural pattern. The Sabinas Basin consists of ~6,000-m-thick Jurassic to Cretaceous siliciclastic, carbonate and evaporitic series. The MVT deposits are mostly in Barremian and in Aptian-Albian to Cenomanian formations and likely formed from basinal brines that were mobilized during the Laramide orogeny, although earlier diagenetic replacement of evaporite layers (barite and celestine deposits) and lining of paleokarstic cavities in reef carbonates (Zn-Pb deposits) is observed. Fluid inclusion microthermometry and isotopic studies suggest ore formation due to mixing of basinal brines and meteoric water. Homogenization temperatures of fluid inclusions range from 45°C to 210°C; salinities range from 0 to 26 wt.% NaCl equiv., and some inclusions contain hydrocarbons or bitumen. Sulfur isotope data suggest that most of the sulfur in barite and celestine is derived from Barremian to Cenomanian evaporites. Regional geology and a compilation of metallogenic features define the new MVT province of northeastern Mexico, which comprises most of the state of Coahuila and portions of the neighboring states of Nuevo León, Durango and, perhaps extends into Zacatecas and southern Texas. This province exhibits a regional metal zonation, with celestine deposits to the south, fluorite deposits to the north and barite and Zn-Pb deposits mostly in the central part.

Low-cost zinc-plated photoanode for fabric-type dye-sensitized solar cells

NASA Astrophysics Data System (ADS)

Kong, Lingfeng; Bao, Yunna; Guo, Wanwan; Cheng, Li; Du, Jun; Liu, Renlong; Wang, Yundong; Fan, Xing; Tao, Changyuan

2016-02-01

Fabric-type flexible solar cells have been recently proposed as a very promising power source for wearable electronics. To increase the photocurrent of fabric-type flexible solar cells, low-cost zinc-plated wire and mesh photoanodes are assembled for the first time through a mild wet process. Given the protection of the compact protection layer, the DSSC device could benefit from the low work function of Zn and self-repairing behavior on the Zn/ZnO interface. An evident current increase by ∼6 mA/cm2 could be observed after coating a layer of metal Zn on various metal substrates, such as traditional stainless steel wire. Given the self-repairing behavior on Zn/ZnO interface, the Zn layer can help to improve the interfacial carrier transfer, leading to better photovoltaic performance, for both liquid-type and solid-type cells.

Relative toxicity of lead and five proposed substitute shot types to pen-reared mallards

USGS Publications Warehouse

Grandy, John W.; Locke, Louis N.; Bagley, George E.

1968-01-01

A 30-day toxicity test was made to determine the relative toxicity of lead, a tin-lead alloy, zinc, nickel, teflon-coated steel, and tin, all in shot form, to pen-reared mallard drakes. All of the 15 ducks dosed with lead died. Twenty-seven percent of 15 dosed with alloy, and 20 percent of 15 dosed with zinc also died. Ten of the remaining zinc-dosed ducks showed signs of distress, including losses of muscular control and body weight. There were no deaths among 15 ducks dosed with nickel, 15 dosed with teflon-coated steel, and 15 dosed with tin. Seventy-three percent of those dosed with nickel shot eliminated all shot before the end of the 30-day period. Acid-fast intranuclear inclusion bodies were present in the kidneys of mallards dosed with commercial lead shot, or with tin-lead alloy shot, but not in the kidneys of birds given nickel, tin, or teflon-coated steel shot. Atypical, pale, acid-fast bodies were found in kidneys of 1 of 15 birds dosed with zinc. An iron-containing pigment, which stained positive with the Prussian blue technique, was present in variable amounts in almost all livers. Zinc-dosed ducks that died or were killed while still showing signs of zinc intoxication had higher iron levels in the liver than ducks that had recovered from zinc intoxication.

Plant taphonomy in incised valleys: Implications for interpreting paleoclimate from fossil plants

USGS Publications Warehouse

Demko, T.M.; Dubiel, R.F.; Parrish, Judith T.

1998-01-01

Paleoclimatic interpretations of the Upper Triassic Chinle Formation (Colorado Plateau) based on plants conflict with those based on the sedimentary rocks. The plants are suggestive of a humid, equable climate, whereas the rocks are more consistent with deposition under highly seasonal precipitation and ground-water conditions. Fossil plant assemblages are limited to the lower members of the Chinle Formation, which were deposited within incised valleys that were cut into underlying Lower to Middle Triassic and older rocks. In contrast, the upper members of the formation, which were deposited across the fluvial plain after the incised valleys were filled, have few preserved fossil plants. The taphonomic characteristics of the plant fossil assemblages, within the stratigraphic and hydrologic context of the incised valley-fill sequence, explain the vertical and lateral distribution of these assemblages. The depositional, hydrological, and near-surface geochemical conditions were more conducive to preservation of the plants. Fossil plant assemblages in fully terrestrial incised-valley fills should be taphonomically biased toward riparian wetland environments. If those assemblages are used to interpret paleoclimate, the paleoclimatic interpretations will also be biased. The bias may be particularly strong in climates such as those during deposition of the Chinle Formation, when the riparian wetlands may reflect local hydrologic conditions rather than regional climate, and should be taken into account when using these types of plant assemblages in paleoclimatic interpretations.

Identification of sources of lead in children in a primary zinc-lead smelter environment.

PubMed Central

Gulson, Brian L; Mizon, Karen J; Davis, Jeff D; Palmer, Jacqueline M; Vimpani, Graham

2004-01-01

We compared high-precision lead isotopic ratios in deciduous teeth and environmental samples to evaluate sources of lead in 10 children from six houses in a primary zinc-lead smelter community at North Lake Macquarie, New South Wales, Australia. Teeth were sectioned to allow identification of lead exposure in utero and in early childhood. Blood lead levels in the children ranged from 10 to 42 micro g/dL and remained elevated for a number of years. For most children, only a small contribution to tooth lead can be attributed to gasoline and paint sources. In one child with a blood lead concentration of 19.7 microg/dL, paint could account for about 45% of lead in her blood. Comparison of isotopic ratios of tooth lead levels with those from vacuum cleaner dust, dust-fall accumulation, surface wipes, ceiling (attic) dust, and an estimation of the smelter emissions indicates that from approximately 55 to 100% of lead could be derived from the smelter. For a blood sample from another child, > 90% of lead could be derived from the smelter. We found varying amounts of in utero-derived lead in the teeth. Despite the contaminated environment and high blood lead concentrations in the children, the levels of lead in the teeth are surprisingly low compared with those measured in children from other lead mining and smelting communities. PMID:14698931

Metalliferous deposits of the greater Helena mining region, Montana

USGS Publications Warehouse

Pardee, Joseph Thomas; Schrader, F.C.

1933-01-01

characterized by the accumulation of marine sediments and the later by mountain building and erosion. The later period began with folding and elevation in late Cretaceous or early Eocene time, followed by overthrust faulting and the intrusion of the Boulder batholith. Next, there ensued a period of crustal stability, during which erosion reduced the region to a surface of low relief and cut away at least 10,000 feet of strata in the area north of Helena. In Oligocene, Miocene, and Pliocene (?) time sediments composed of land waste and volcanic ash were deposited, and this event was followed by warping and faulting that elevated the present mountains. During Pliocene and Pleistocene time the mountains were maturely dissected, and in middle and late Pleistocene time local glaciers formed in the higher mountains and large valley glaciers invaded the extreme northern part of the region. The ore deposits include lodes and placers that have yielded gold, silver, lead, copper, and zinc to a value of at least $176,860,000. The placers were formed mostly during interglacial stages of the Pleistocene. They have been almost entirely exhausted. Most of the lodes are classified as regards age in two groups, an older and a younger. The older lodes are related in origin to the Boulder batholith or some of the neighboring intrusive granitic bodies and were probably formed during early Eocene time. The younger lodes were formed after dacite of probable Miocene age was erupted. They are possibly related in origin to some unexposed intrusive granitic rock. For convenience in description the region is divided into three parts districts north of Helena, districts in the Belt Mountains, and districts south of Helena. The districts north of Helena include a 50-mile stretch of the Continental Divide that forms a broad ridge surmounted with considerable areas of flat or gently sloping surface at a general altitude of 7,000 feet. Narrow valleys 1,000 to 2,000 feet deep are cut into this surface and lead

Assimilation of zinc, cadmium, lead, copper, and iron by the spider Dysdera crocata, a predator of woodlice

DOE Office of Scientific and Technical Information (OSTI.GOV)

Hopkin, S.P.; Martin, M.H.

1985-02-01

In this paper, an experiment is described on the assimilation of zinc, cadmium, lead, copper and iron by Dysdera crocata collected from a site in central Bristol. The spiders were fed on woodlice from their own site, and on woodlice from a site contaminated by a smelting works which contained much higher levels of zinc, cadmium and lead than the spiders would have been used to in their normal diet.

Preparation and adsorption characteristics for heavy metals of active silicon adsorbent from leaching residue of lead-zinc tailings.

PubMed

Lei, Chang; Yan, Bo; Chen, Tao; Xiao, Xian-Ming

2018-05-19

To comprehensively reuse the leaching residue obtained from lead-zinc tailings, an active silicon adsorbent (ASA) was prepared from leaching residue and studied as an adsorbent for copper(II), lead(II), zinc(II), and cadmium(II) in this paper. The ASA was prepared by roasting the leaching residue with either a Na 2 CO 3 /residue ratio of 0.6:1 at 700 °C for 1 h or a CaCO 3 /residue ratio of 0.8:1 at 800 °C for 1 h. Under these conditions, the available SiO 2 content of the ASA was more than 20%. The adsorption behaviors of the metal ions onto the ASA were investigated and the Langmuir, Freundlich, and Dubinin-Radushkevich isotherm models were used to analyze the adsorption isotherm. The result showed that the maximum adsorption capacities of copper(II), lead(II), cadmium(II), and zinc(II) calculated by the Langmuir model were 3.40, 2.83, 0.66, and 0.62 mmol g -1 , respectively. The FT-IR spectra of the ASA and the mean free adsorption energies indicated that ion exchange was the mechanism of copper(II), lead(II), and cadmium(II) adsorption and that chemical reaction was the mechanism of zinc(II) adsorption. These results provide a method for reusing the leaching residue obtained from lead-zinc tailings and show that the ASA is an effective adsorbent for heavy metal pollution remediation.

Assessment of water resources in lead-zinc mined areas in Cherokee County, Kansas, and adjacent areas

USGS Publications Warehouse

Spruill, Timothy B.

1987-01-01

allowed oxidation of ore deposits which, on saturation with water, resulted in poor-quality water that generally contains large concentrations of sulfate and trace metals. Water from mines in the eastern area contained dissolved-solids concentrations of less than 500 mg/L (milligrams per liter), a median pH of 3.9, sulfate concentrations that ranged between 98 and 290 mg/L, and median concentrations for zinc of 37,600 micrograms/L (micrograms per liter), for lead of 240 micrograms/L, for cadmium of 180 micrograms/L, for iron of 70 micrograms/L, for manganese of 240 micrograms/L, and for silica of 15 mg/L. Water from mines in the western area contained dissolved-solids concentrations of generally more than 500 mg/L, a median pH of 6.8, sulfate concentrations that ranged between 170 and 2,150 mg/L, and median concentrations for zinc of 3,200 micrograms/L, for lead of 0 micrograms/L (minimum detection limit is 10 micrograms/L), for cadmium of 6 micrograms/L, for iron of 840 micrograms/L, for manganese of 440 micrograms/L, and for silica of 11 mg/L. No conclusive evidence of lateral migration of water from the mines into domestic well-water supplies in the shallow aquifer was found in the study area in Kansas. Analyses of water from public-supply wells tapping the deep aquifer did not indicate contamination with trace metals, although chemical analyses from four of six wells exhibited increasing trends through time in sulfate concentrations. These increases probably reflect localized leakage of water from the shallow aquifer along corroded or leaky well casings. Effects of abandoned lead and zinc mines on tributaries of the Spring River in the eastern area are most severe in Short Creek. Compared with water samples from three other major streams in the eastern area, a sample collected from Short Creek, 2 miles west of Galena, Kansas, during August 1981, contained the largest concentrations of dissolved sulfate (240 mg/L), zinc (25,000 micrograms/L), ca

Zinc electrodeposition from flowing alkaline zincate solutions: Role of hydrogen evolution reaction

NASA Astrophysics Data System (ADS)

Dundálek, Jan; Šnajdr, Ivo; Libánský, Ondřej; Vrána, Jiří; Pocedič, Jaromír; Mazúr, Petr; Kosek, Juraj

2017-12-01

The hydrogen evolution reaction is known as a parasitic reaction during the zinc electrodeposition from alkaline zincate solutions and is thus responsible for current efficiency losses during the electrolysis. Besides that, the rising hydrogen bubbles may cause an extra convection within a diffusion layer, which leads to an enhanced mass transport of zincate ions to an electrode surface. In this work, the mentioned phenomena were studied experimentally in a flow through electrolyzer and the obtained data were subsequently evaluated by mathematical models. The results prove the indisputable influence of the rising hydrogen bubbles on the additional mixing of the diffusion layer, which partially compensates the drop of the current efficiency of the zinc deposition at higher current flows. Moreover, the results show that the current density ratio (i.e., the ratio of an overall current density to a zinc limiting current density) is not suitable for the description of the zinc deposition, because the hydrogen evolution current density is always involved in the overall current density.

Geochemical Modeling of Zinc Silicate Ore Formation from Sedimentary Hydrothermal Fluids

NASA Astrophysics Data System (ADS)

Appold, M. S.

2008-12-01

, more oxidizing, dilute, and basic fluid. This scenario was investigated further with reaction path and reactive transport modeling. In these models, a more complex ore fluid was used that was assumed to have a major element composition similar to the global average for Mississippi Valley-type (MVT) deposits determined from the literature, modified by heating from 150 to 300° C, saturated with respect to dolomite and quartz, moderately acidic, and an oxidation potential near the value defined by magnetite-hematite equilibrium. The ore fluid was allowed to mix with a second, possibly meteoric fluid with about three orders of magnitude lower salinity, neutral pH, and a temperature of 50° C. The modeling results showed general agreement with the mineral assemblage observed at Vazante, and confirmed the need for a strong pH increase to induce willemite precipitation, and no more than a moderate increase in oxidation potential to allow some sphalerite to precipitate. The localization of mineralization within a shear zone was found to depend strongly on the shear zone having acted as a high permeability conduit for the ore fluid from deeper parts of the sedimentary basin.

Mineral deposits of Central America, with a section on manganese deposits of Panama

USGS Publications Warehouse

Roberts, Ralph Jackson; Irving, Earl Montgomery; Simons, F.S.

1957-01-01

The mineral deposits of Central America were studied between 1942 and 1945, in cooperation with the United States Department of State and the Foreign Economic Administration. Emphasis was originally placed on the study of strategic-mineral deposits, especially of antimony, chromite, manganese, quartz, and mica, but deposits of other minerals that offered promise of significant future production were also studied. A brief appraisal of the base-metal deposits was made, and deposits of iron ore in Honduras and of lead and zinc ores in Guatemala were mapped. In addition, studies were made of the regional geology of some areas, data were collected from many sources, and a new map of the geology of Central America was compiled.

Mohawk Lake or Mohawk meadow Sedimentary facies and stratigraphy of Quaternary deposits in Mohawk Valley, upper Middle Fork of the Feather River, California

DOE Office of Scientific and Technical Information (OSTI.GOV)

Yount, J.C.; Harwood, D.S.; Bradbury, J.P.

1993-04-01

Mohawk Valley (MV) contain thick, well-exposed sections of Quaternary basin-fill sediments, with abundant interbedded tephra and a diverse assemblage of sedimentary facies. The eastern arm of MV, extending from Clio to Portola, contains as much as 100 m of trough cross-bedded cobble to pebble gravel and planar and trough cross-bedded coarse and medium sand, interpreted as braided stream deposits. Sections exposed in the western arm of MV consist in their lower parts of massive organic-rich silt and clay interbedded with blocky to fissile peat beds up to 1 m thick. Diatom assemblages are dominated by benthic species indicating fresh marshmore » environments with very shallow water depths of one meter or less. Proglacial lacustrine deposits of limited lateral extent are present within the outwash complexes as evidenced by varved fine sand and silt couplets, poorly sorted quartz-rich silt beds containing dropstones, and contorted beds of diamict grading laterally into slump blocks surrounded by wood-bearing silt and silty sand. The Rockland Ash (400 ka) is a prominent marker in the middle or lower part of many sections throughout MV, indicating that at least half of the basin-fill sequence is Late Quaternary in age. A log buried in diamict slumped into a proglacial lake lying approximately 3 km downstream from the Tioga Stage ice termini in Jamison and Gray Eagle Creeks yields an age of 18,715 [+-]235 C[sup 14] years BP. Previous interpretations of MV deposits originating in a large, deep lake with water depths in excess of 150 m are untenable given the sedimentary facies and diatom floras that dominate the valley. Unexhumed valleys such as Sierra Valley to the east and Long Valley to the northwest which contain large meadows traversed by braided streams are probably good analogs for the conditions that existed during the accumulation of the Mohawk Valley deposits.« less

Assessment of water resources in lead-zinc mined areas in Cherokee County, Kansas, and adjacent areas

USGS Publications Warehouse

Spruill, Timothy B.

1984-01-01

.Mining allowed oxidation of ore deposits which, on saturation with water, resulted in poor-quality water that generally contains large concentrations of sulfate and trace metals. Water from mines in the eastern area contained dissolved-solids concentrations of less than 500 mg/L (milligrams per liter), a median pH of 3.9, sulfate concentrations that ranged between 98 and 290 mg/L, and median concentrations for zinc of 37,600 pg/L (micrograms per liter), for lead of 240 pg/L, for cadmium of 180 ug/L, for iron of 70 pg/L, for manganese of 240 pg/L, and for silica of 15 mg/L. Water from mines in the western area contained dissolved-solids concentrations of generally more than 500 mg/L, a median pH of 6.8, sulfate concentrations that ranged between 170 and 2,150 mg/L, and median concentrations for zinc of 3,200 pg/L, for lead of 0 pg/L (minimum detection limit is 10 pg/L), for cadmium of 6 pg/L, for iron of 840 pg/L, for manganese of 440 ug/L, and for silica of 11 mg/L.No conclusive evidence of lateral migration of water from the mines into domestic well-water supplies in the shallow aquifer was found in the study area in Kansas. Analyses of water from public-supply wells tapping the deep aquifer did not indicate contamination with trace metals, although chemical analyses from four of six wells exhibited increasing trends through time in sulfate concentrations. These increases probably reflect localized leakage of water from the shallow aquifer along corroded or leaky well casings.Effects of abandoned lead and zinc mines on tributaries of the Spring River in the eastern area are most severe in Short Creek. Compared with water samples from three other major streams in the eastern area, a sample collected from Short Creek, 2 miles west of Galena, Kansas, during August 1981, contained the largest concentrations of dissolved sulfate (240 mg/L), zinc (25,000 pg/L), cadmium (170 pg/L), manganese (1,700 ug/L), and the lowest pH (6.0). Concentrations of these constituents are due primarily

Depositional and provenance record of the Paleogene transition from foreland to hinterland basin evolution during Andean orogenesis, northern Middle Magdalena Valley Basin, Colombia

NASA Astrophysics Data System (ADS)

Moreno, Christopher J.; Horton, Brian K.; Caballero, Victor; Mora, Andrés; Parra, Mauricio; Sierra, Jair

2011-10-01

The Central Cordillera and Eastern Cordillera of the northern Andes form the topographic flanks of the north-trending Magdalena Valley Basin. Constraining the growth of these ranges and intervening basin has implications for Andean shortening and the transformation from a foreland to hinterland basin configuration. We present sedimentological, paleocurrent, and sandstone petrographic results from Cenozoic type localities to provide insights into the tectonic history of the northern Middle Magdalena Valley Basin of Colombia. In the Nuevo Mundo Syncline, the mid-Paleocene transition from marine to nonmarine deposystems of the Lisama Formation corresponds with a paleocurrent shift from northward to eastward transport. These changes match detrital geochronological evidence for a contemporaneous shift from cratonic (Amazonian) to orogenic (Andean) provenance, suggesting initial shortening-related uplift of the Central Cordillera and foreland basin generation in the Magdalena Valley by mid-Paleocene time. Subsequent establishment of a meandering fluvial system is recorded in lower-middle Eocene strata of the lower La Paz Formation. Eastward paleocurrents in mid-Paleocene through uppermost Eocene fluvial deposits indicate a continuous influence of western sediment source areas. However, at the upper middle Eocene (˜40 Ma) boundary between the lower and upper La Paz Formation, sandstone compositions show a drastic decrease in lithic content, particularly lithic volcanic fragments. This change is accompanied by a facies shift from mixed channel and overbank facies to thick, amalgamated braided fluvial deposits of possible fluvial megafans, reflecting changes in both the composition and proximity of western sediment sources. We attribute these modifications to the growing influence of exhumed La Cira-Infantas paleohighs in the axial Magdalena Valley, features presently buried beneath upper Eocene-Quaternary basin fill along the western flank of the Nuevo Mundo Syncline. In

Chemical and thermal stability of the characteristics of filtered vacuum arc deposited ZnO, SnO2 and zinc stannate thin films

NASA Astrophysics Data System (ADS)

Çetinörgü, E.; Goldsmith, S.

2007-09-01

ZnO, SnO2 and zinc stannate thin films were deposited on commercial microscope glass and UV fused silica substrates using filtered vacuum arc deposition system. During the deposition, the substrate temperature was at room temperature (RT) or at 400 °C. The film structure and composition were determined using x-ray diffraction and x-ray photoelectron spectroscopy, respectively. The transmission of the films in the VIS was 85% to 90%. The thermal stability of the film electrical resistance was determined in air as a function of the temperature in the range 28 °C (RT) to 200 °C. The resistance of ZnO increased from ~ 5000 to 105 Ω when heated to 200 °C, that of SnO2 films increased from 500 to 3900 Ω, whereas that of zinc stannate thin films increased only from 370 to 470 Ω. During sample cooling to RT, the resistance of ZnO and SnO2 thin films continued to rise considerably; however, the increase in the zinc stannate thin film resistance was significantly lower. After cooling to RT, ZnO and SnO2 thin films became practically insulators, while the resistance of zinc stannate was 680 Ω. The chemical stability of the films was determined by immersing in acidic and basic solutions up to 27 h. The SnO2 thin films were more stable in the HCl solution than the ZnO and the zinc stannate thin films; however, SnO2 and zinc stannate thin films that were immersed in the NaOH solution did not dissolve after 27 h.

Evaluation of novel reactive MgO activated slag binder for the immobilisation of lead and zinc.

PubMed

Jin, Fei; Al-Tabbaa, Abir

2014-12-01

Although Portland cement is the most widely used binder in the stabilisation/solidification (S/S) processes, slag-based binders have gained significant attention recently due to their economic and environmental merits. In the present study, a novel binder, reactive MgO activated slag, is compared with hydrated lime activated slag in the immobilisation of lead and zinc. A series of lead or zinc-doped pastes and mortars were prepared with metal to binder ratio from 0.25% to 1%. The hydration products and microstructure were studied by X-ray diffraction, thermogravimetric analysis and scanning electron microscopy. The major hydration products were calcium silicate hydrate and hydrotalcite-like phases. The unconfined compressive strength was measured up to 160 d. Findings show that lead had a slight influence on the strength of MgO-slag paste while zinc reduced the strength significantly as its concentration increased. Leachate results using the TCLP tests revealed that the immobilisation degree was dependent on the pH and reactive MgO activated slag showed an increased pH buffering capacity, and thus improved the immobilisation efficiency compared to lime activated slag. It was proposed that zinc was mainly immobilised within the structure of the hydrotalcite-like phases or in the form of calcium zincate, while lead was primarily precipitated as the hydroxide. It is concluded, therefore, that reactive MgO activated slag can serve as clinker-free alternative binder in the S/S process. Copyright © 2014 Elsevier Ltd. All rights reserved.

Variation in Soil Respiration across Soil and Vegetation Types in an Alpine Valley

PubMed Central

Rubin, Aurélie

2016-01-01

Background and Aims Soils of mountain regions and their associated plant communities are highly diverse over short spatial scales due to the heterogeneity of geological substrates and highly dynamic geomorphic processes. The consequences of this heterogeneity for biogeochemical transfers, however, remain poorly documented. The objective of this study was to quantify the variability of soil-surface carbon dioxide efflux, known as soil respiration (Rs), across soil and vegetation types in an Alpine valley. To this aim, we measured Rs rates during the peak and late growing season (July-October) in 48 plots located in pastoral areas of a small valley of the Swiss Alps. Findings Four herbaceous vegetation types were identified, three corresponding to different stages of primary succession (Petasition paradoxi in pioneer conditions, Seslerion in more advanced stages and Poion alpinae replacing the climactic forests), as well as one (Rumicion alpinae) corresponding to eutrophic grasslands in intensively grazed areas. Soils were developed on calcareous alluvial and colluvial fan deposits and were classified into six types including three Fluvisols grades and three Cambisols grades. Plant and soil types had a high level of co-occurrence. The strongest predictor of Rs was soil temperature, yet we detected additional explanatory power of sampling month, showing that temporal variation was not entirely reducible to variations in temperature. Vegetation and soil types were also major determinants of Rs. During the warmest month (August), Rs rates varied by over a factor three between soil and vegetation types, ranging from 2.5 μmol m-2 s-1 in pioneer environments (Petasition on Very Young Fluvisols) to 8.5 μmol m-2 s-1 in differentiated soils supporting nitrophilous species (Rumicion on Calcaric Cambisols). Conclusions Overall, this study provides quantitative estimates of spatial and temporal variability in Rs in the mountain environment, and demonstrates that estimations of

Recycling of Zinc- and Lead-Bearing Residues with Pyrolysis Gas

NASA Astrophysics Data System (ADS)

Pichler, C.; Antrekowitsch, J.

2015-09-01

Efforts in the metallurgical industry for an approximation to the zero waste concept has led to many different investigations. Together with the greenhouse effect, CO2 emissions have caused additional costs for different process steps in the industry. For this reason, alternative carbon carriers have been sought, and charcoal was found to be an ideal substitute, due to its CO2 neutrality. In order to use it in the metallurgical industry, an optimization of the charcoal production through a carbonization process must be carried out. Beside the charcoal, pyrolysis gas also occurs during the heating of wood or agricultural wastes under the exclusion of air. Because of combustible compounds in this gas, it is possible to use it as a reduction agent instead of fossil carbon carriers. Together with the idea of preventing landfilling of metallurgical by-products, an investigation was carried out to treat zinc- and lead-containing materials. For this issue a special process concept was designed and developed. The main aspect was to recycle the zinc- and lead-containing Waelz slag, which results from the processing of steel mill dusts, in a vertical retort. Two different sizes of facilities were constructed to perform the reaction system of the solid Waelz slag with the gaseous reduction agent of pyrolysis gas.

Multivariate statistical assessment of heavy metal pollution sources of groundwater around a lead and zinc plant.

PubMed

Zamani, Abbas Ali; Yaftian, Mohammad Reza; Parizanganeh, Abdolhossein

2012-12-17

The contamination of groundwater by heavy metal ions around a lead and zinc plant has been studied. As a case study groundwater contamination in Bonab Industrial Estate (Zanjan-Iran) for iron, cobalt, nickel, copper, zinc, cadmium and lead content was investigated using differential pulse polarography (DPP). Although, cobalt, copper and zinc were found correspondingly in 47.8%, 100.0%, and 100.0% of the samples, they did not contain these metals above their maximum contaminant levels (MCLs). Cadmium was detected in 65.2% of the samples and 17.4% of them were polluted by this metal. All samples contained detectable levels of lead and iron with 8.7% and 13.0% of the samples higher than their MCLs. Nickel was also found in 78.3% of the samples, out of which 8.7% were polluted. In general, the results revealed the contamination of groundwater sources in the studied zone. The higher health risks are related to lead, nickel, and cadmium ions. Multivariate statistical techniques were applied for interpreting the experimental data and giving a description for the sources. The data analysis showed correlations and similarities between investigated heavy metals and helps to classify these ion groups. Cluster analysis identified five clusters among the studied heavy metals. Cluster 1 consisted of Pb, Cu, and cluster 3 included Cd, Fe; also each of the elements Zn, Co and Ni was located in groups with single member. The same results were obtained by factor analysis. Statistical investigations revealed that anthropogenic factors and notably lead and zinc plant and pedo-geochemical pollution sources are influencing water quality in the studied area.

Multivariate statistical assessment of heavy metal pollution sources of groundwater around a lead and zinc plant

PubMed Central

2012-01-01

The contamination of groundwater by heavy metal ions around a lead and zinc plant has been studied. As a case study groundwater contamination in Bonab Industrial Estate (Zanjan-Iran) for iron, cobalt, nickel, copper, zinc, cadmium and lead content was investigated using differential pulse polarography (DPP). Although, cobalt, copper and zinc were found correspondingly in 47.8%, 100.0%, and 100.0% of the samples, they did not contain these metals above their maximum contaminant levels (MCLs). Cadmium was detected in 65.2% of the samples and 17.4% of them were polluted by this metal. All samples contained detectable levels of lead and iron with 8.7% and 13.0% of the samples higher than their MCLs. Nickel was also found in 78.3% of the samples, out of which 8.7% were polluted. In general, the results revealed the contamination of groundwater sources in the studied zone. The higher health risks are related to lead, nickel, and cadmium ions. Multivariate statistical techniques were applied for interpreting the experimental data and giving a description for the sources. The data analysis showed correlations and similarities between investigated heavy metals and helps to classify these ion groups. Cluster analysis identified five clusters among the studied heavy metals. Cluster 1 consisted of Pb, Cu, and cluster 3 included Cd, Fe; also each of the elements Zn, Co and Ni was located in groups with single member. The same results were obtained by factor analysis. Statistical investigations revealed that anthropogenic factors and notably lead and zinc plant and pedo-geochemical pollution sources are influencing water quality in the studied area. PMID:23369182

P-Type Transparent Cu-Alloyed ZnS Deposited at Room Temperature

DOE PAGES

Woods-Robinson, Rachel; Cooper, Jason K.; Xu, Xiaojie; ...

2016-03-16

All transparent conducting materials (TCMs) of technological practicality are n-type; the inferior conductivity of p-type TCMs has limited their adoption. Additionally, many relatively high-performing p-type TCMs require synthesis temperatures > 400 °C. Here, room-temperature pulsed laser deposition of copper-alloyed zinc sulfide (Cu x Zn 1- x S) thin films (0 ≤ x ≤ 0.75) is reported. For 0.09 ≤ x ≤ 0.35, Cu x Zn 1- x S has high p-type conductivity, up to 42 S cm -1 at x = 0.30, with an optical band gap tunable from ≈3.0–3.3 eV and transparency, averaged over the visible, of 50%–71% formore » 200–250 nm thick films. In this range, synchrotron X-ray and electron diffraction reveal a nanocrystalline ZnS structure. Secondary crystalline Cu y S phases are not observed, and at higher Cu concentrations, x > 0.45, films are amorphous and poorly conducting. Furthermore, within the TCM regime, the conductivity is temperature independent, indicating degenerate hole conduction. A decrease in lattice parameter with Cu content suggests that the hole conduction is due to substitutional incorporation of Cu onto Zn sites. This hole-conducting phase is embedded in a less conducting amorphous Cu y S, which dominates at higher Cu concentrations. Finally, the combination of high hole conductivity and optical transparency for the peak conductivity Cu x Zn 1- x S films is among the best reported to date for a room temperature deposited p-type TCM.« less

Climax-Type Porphyry Molybdenum Deposits

USGS Publications Warehouse

Ludington, Steve; Plumlee, Geoffrey S.

2009-01-01

Climax-type porphyry molybdenum deposits, as defined here, are extremely rare; thirteen deposits are known, all in western North America and ranging in age from Late Cretaceous to mainly Tertiary. They are consistently found in a postsubduction, extensional tectonic setting and are invariably associated with A-type granites that formed after peak activity of a magmatic cycle. The deposits consist of ore shells of quartz-molybdenite stockwork veins that lie above and surrounding the apices of cupola-like, highly evolved, calc-alkaline granite and subvolcanic rhyolite-porphyry bodies. These plutons are invariably enriched in fluorine (commonly >1 percent), rubidium (commonly >500 parts per million), and niobium-tantalum (Nb commonly >50 parts per million). The deposits are relatively high grade (typically 0.1-0.3 percent Mo) and may be very large (typically 100-1,000 million tons). Molybdenum, as MoS2, is the primary commodity in all known deposits. The effect on surface-water quality owing to natural influx of water or sediment from a Climax-type mineralized area can extend many kilometers downstream from the mineralized area. Waste piles composed of quartz-silica-pyrite altered rocks will likely produce acidic drainage waters. The potential exists for concentrations of fluorine or rare metals in surface water and groundwater to exceed recommended limits for human consumption near both mined and unmined Climax-type deposits.

Photoluminescence of Porous Silicon-Zinc Oxide Hybrid structures

NASA Astrophysics Data System (ADS)

Olenych, I. B.; Monastyrskii, L. S.; Luchechko, A. P.

2017-03-01

Arrays of ZnO nanostructures, which are optically transparent in the visible range, were grown on the surface of porous silicon by electrochemical deposition. Photoluminescence excitation and emission spectra of the obtained hybrid structures were investigated in 220-450 and 400-800 nm regions, respectively. It is established that multicolor emission is formed by combining the luminescence bands of porous silicon and zinc oxide. The possibility of controlling the photoluminescence spectra by changing the excitation energy is demonstrated. It is revealed that thermal annealing has an effect on the luminescent properties of porous silicon/zinc oxide hybrid structures. Thermal processing at 500°C leads to a sharp decrease of long-wavelength luminescence associated with porous silicon and to an increase of short-wavelength luminescence intensity related to zinc oxide.

Hydrogeologic Framework and Ground Water in Basin-Fill Deposits of the Diamond Valley Flow System, Central Nevada

USGS Publications Warehouse

Tumbusch, Mary L.; Plume, Russell W.

2006-01-01

The Diamond Valley flow system, an area of about 3,120 square miles in central Nevada, consists of five hydrographic areas: Monitor, Antelope, Kobeh, and Diamond Valleys and Stevens Basin. Although these five areas are in a remote part of Nevada, local government officials and citizens are concerned that the water resources of the flow system eventually could be further developed for irrigation or mining purposes or potentially for municipal use outside the study area. In order to better understand the flow system, the U.S. Geological Survey in cooperation with Eureka, Lander, and Nye Counties and the Nevada Division of Water Resources, is conducting a multi-phase study of the flow system. The principal aquifers of the Diamond Valley flow system are in basin-fill deposits that occupy structural basins comprised of carbonate rocks, siliciclastic sedimentary rocks, igneous intrusive rocks, and volcanic rocks. Carbonate rocks also function as aquifers, but their extent and interconnections with basin-fill aquifers are poorly understood. Ground-water flow in southern Monitor Valley is from the valley margins toward the valley axis and then northward to a large area of discharge by evapotranspiration (ET) that is formed south of a group of unnamed hills near the center of the valley. Ground-water flow from northern Monitor Valley, Antelope Valley, and northern and western parts of Kobeh Valley converges to an area of ground-water discharge by ET in central and eastern Kobeh Valley. Prior to irrigation development in the 1960s, ground-water flow in Diamond Valley was from valley margins toward the valley axis and then northward to a large discharge area at the north end of the valley. Stevens Basin is a small upland basin with internal drainage and is not connected with other parts of the flow system. After 40 years of irrigation pumping, a large area of ground-water decline has developed in southern Diamond Valley around the irrigated area. In this part of Diamond

Production of zinc pellets

DOEpatents

Cooper, J.F.

1996-11-26

Uniform zinc pellets are formed for use in batteries having a stationary or moving slurry zinc particle electrode. The process involves the cathodic deposition of zinc in a finely divided morphology from battery reaction product onto a non-adhering electrode substrate. The mossy zinc is removed from the electrode substrate by the action of gravity, entrainment in a flowing electrolyte, or by mechanical action. The finely divided zinc particles are collected and pressed into pellets by a mechanical device such as an extruder, a roller and chopper, or a punch and die. The pure zinc pellets are returned to the zinc battery in a pumped slurry and have uniform size, density and reactivity. Applications include zinc-air fuel batteries, zinc-ferricyanide storage batteries, and zinc-nickel-oxide secondary batteries. 6 figs.

Production of zinc pellets

DOEpatents

Cooper, John F.

1996-01-01

Uniform zinc pellets are formed for use in batteries having a stationary or moving slurry zinc particle electrode. The process involves the cathodic deposition of zinc in a finely divided morphology from battery reaction product onto a non-adhering electrode substrate. The mossy zinc is removed from the electrode substrate by the action of gravity, entrainment in a flowing electrolyte, or by mechanical action. The finely divided zinc particles are collected and pressed into pellets by a mechanical device such as an extruder, a roller and chopper, or a punch and die. The pure zinc pellets are returned to the zinc battery in a pumped slurry and have uniform size, density and reactivity. Applications include zinc-air fuel batteries, zinc-ferricyanide storage batteries, and zinc-nickel-oxide secondary batteries.

Zinc supplementation suppresses the progression of bile duct ligation-induced liver fibrosis in mice.

PubMed

Shi, Fang; Sheng, Qin; Xu, Xinhua; Huang, Wenli; Kang, Y James

2015-09-01

Metallothionein (MT) gene therapy leads to resolution of liver fibrosis in mouse model, in which the activation of collagenases is involved in the regression of liver fibrosis. MT plays a critical role in zinc sequestration in the liver suggesting its therapeutic effect would be mediated by zinc. The present study was undertaken to test the hypothesis that zinc supplementation suppresses liver fibrosis. Male Kunming mice subjected to bile duct ligation (BDL) resulted in liver fibrosis as assessed by increased α-smooth muscle actin (α-SMA) and collagen I production/deposition in the liver. Zinc supplementation was introduced 4 weeks after BDL surgery via intragastric administration once daily for 2 weeks resulting in a significant reduction in the collagen deposition in the liver and an increase in the survival rate. Furthermore, zinc suppressed gene expression of α-SMA and collagen I and enhanced the capacity of collagen degradation, as determined by the increased activity of total collagenases and elevated mRNA and protein levels of MMP13. Therefore, the results demonstrate that zinc supplementation suppresses BDL-induced liver fibrosis through both inhibiting collagen production and enhancing collagen degradation. © 2014 by the Society for Experimental Biology and Medicine.

Massive sulfide deposition and trace element remobilization in the Middle Valley sediment-hosted hydrothermal system, northern Juan de Fuca Rdge

USGS Publications Warehouse

Houghton, J.L.; Shanks, Wayne C.; Seyfried, W.E.

2004-01-01

The Bent Hill massive sulfide deposit and ODP Mound deposit in Middle Valley at the northernmost end of the Juan de Fuca Ridge are two of the largest modern seafloor hydrothermal deposits yet explored. Trace metal concentrations of sulfide minerals, determined by laser-ablation ICP-MS, were used in conjunction with mineral paragenetic studies and thermodynamic calculations to deduce the history of fluid-mineral reactions during sulfide deposition. Detailed analyses of the distribution of metals in sulfides indicate significant shifts in the physical and chemical conditions responsible for the trace element variability observed in these sulfide deposits. Trace elements (Mn, Co, Ni, As, Se, Ag, Cd, Sb, Pb, and Bi) analyzed in a representative suite of 10 thin sections from these deposits suggest differences in conditions and processes of hydrothermal alteration resulting in mass transfer of metals from the center of the deposits to the margins. Enrichments of some trace metals (Pb, Sb, Cd, Ag) in sphalerite at the margins of the deposits are best explained by dissolution/reprecipitation processes consistent with secondary remineralization. Results of reaction-path models clarify mechanisms of mass transfer during remineralization of sulfide deposits due to mixing of hydrothermal fluids with seawater. Model results are consistent with patterns of observed mineral paragenesis and help to identify conditions (pH, redox, temperature) that may be responsible for variations in trace metal concentrations in primary and secondary minerals. Differences in trace metal distributions throughout a single deposit and between nearby deposits at Middle Valley can be linked to the history of metal mobilization within this active hydrothermal system that may have broad implications for sulfide ore formation in other sedimented and unsedimented ridge systems. ?? 2004 Elsevier Ltd.

Photocatalysis of zinc oxide nanotip array/titanium oxide film heterojunction prepared by aqueous solution deposition

NASA Astrophysics Data System (ADS)

Lee, Ming-Kwei; Lee, Bo-Wei; Kao, Chen-Yu

2017-05-01

A TiO2 film was prepared on indium tin oxide (ITO)/glass by aqueous solution deposition (ASD) with precursors of ammonium hexafluoro-titanate and boric acid at 40 °C. The photocatalysis of annealed TiO2 film increases with increasing growth time and decreases with increasing growth times longer than 60 min. A ZnO nanotip array was prepared on ZnO seed layer/TiO2 film/glass by aqueous solution deposition with precursors of zinc nitrate and ammonium hydroxide at 70 °C. The photocatalysis of ASD-ZnO/ASD-TiO2 film/ITO glass can be better than that of P25.

Deformation of ``Villafranchian'' lacustrine sediments in the Chisone Valley (Western Alps, Italy)

NASA Astrophysics Data System (ADS)

Collo, Giovanni; Giardino, Marco

1997-09-01

The Chisone Valley is located in the internal NW Alps, in the Pinerolese District, an area characterized by present low to medium seismicity. Fine-grained sediments (sand, silt and clay with interbedded gravel) crop out in the lower Chisone Valley: they were first interpreted as glaciolacustrine deposits, and then as a lacustrine infilling of the valley floor probably due to differential uplifting of the valley mouth. Review of this data, together with new field and palynological observations, lead us to refer the lacustrine deposits to approximately the Lower Pleistocene (Villafranchian). In many outcrops, the lacustrine deposits show strong soft-sediment deformation such as convolute laminations, water-escape structures and disrupted beds, some of them associated with folds and faults (cm to dm in size); only two sites show metric to decametric folds and faults trending E-W and N-S. Detailed structural analysis conducted along a recently exposed section (Rio Gran Dubbione site) shows several soft-sediment deformation features on the limbs of mesoscale folds. Because of their intimate structural association, the origin of these minor structures seems to be connected to synsedimentary activity on reverse and normal faults (m to dm in size) affecting the lacustrine deposits in the same locality. Soft-sediment deformation features can be interpreted as possible paleoseismites. If so, the present seismicity of the Pinerolese District, which is the major area of such activity in NW Italy, cannot be considered an isolated episode in the geological evolution of the region; even if there is no supporting evidence for continuous seismicity, the deformations in the lacustrine sediments of the Chisone Valley testify to Early Pleistocene seismic activity, probably related to the recent tectonic evolution of the internal side of the NW Alps.

Valley dependent transport in graphene L junction

NASA Astrophysics Data System (ADS)

Chan, K. S.

2018-05-01

We studied the valley dependent transport in graphene L junctions connecting an armchair lead and a zigzag lead. The junction can be used in valleytronic devices and circuits. Electrons injected from the armchair lead into the junction is not valley polarized, but they can become valley polarized in the zigzag lead. There are Fermi energies, where the current in the zigzag lead is highly valley polarized and the junction is an efficient generator of valley polarized current. The features of the valley polarized current depend sensitively on the widths of the two leads, as well as the number of dimers in the armchair lead, because this number has a sensitive effect on the band structure of the armchair lead. When an external potential is applied to the junction, the energy range with high valley polarization is enlarged enhancing its function as a generator of highly valley polarized current. The scaling behavior found in other graphene devices is also found in L junctions, which means that the results presented here can be extended to junctions with larger dimensions after appropriate scaling of the energy.

Viral RNA annealing activities of human immunodeficiency virus type 1 nucleocapsid protein require only peptide domains outside the zinc fingers.

PubMed Central

De Rocquigny, H; Gabus, C; Vincent, A; Fournié-Zaluski, M C; Roques, B; Darlix, J L

1992-01-01

The nucleocapsid (NC) of human immunodeficiency virus type 1 consists of a large number of NC protein molecules, probably wrapping the dimeric RNA genome within the virion inner core. NC protein is a gag-encoded product that contains two zinc fingers flanked by basic residues. In human immunodeficiency virus type 1 virions, NCp15 is ultimately processed into NCp7 and p6 proteins. During virion assembly the retroviral NC protein is necessary for core formation and genomic RNA encapsidation, which are essential for virus infectivity. In vitro NCp15 activates viral RNA dimerization, a process most probably linked in vivo to genomic RNA packaging, and replication primer tRNA(Lys,3) annealing to the initiation site of reverse transcription. To characterize the domains of human immunodeficiency virus type 1 NC protein necessary for its various functions, the 72-amino acid NCp7 and several derived peptides were synthesized in a pure form. We show here that synthetic NCp7 with or without the two zinc fingers has the RNA annealing activities of NCp15. Further deletions of the N-terminal 12 and C-terminal 8 amino acids, leading to a 27-residue peptide lacking the finger domains, have little or no effect on NC protein activity in vitro. However deletion of short sequences containing basic residues flanking the first finger leads to a complete loss of NC protein activity. It is proposed that the basic residues and the zinc fingers cooperate to select and package the genomic RNA in vivo. Inhibition of the viral RNA binding and annealing activities associated with the basic residues flanking the first zinc finger of NC protein could therefore be used as a model for the design of antiviral agents. Images PMID:1631144

Viral RNA annealing activities of human immunodeficiency virus type 1 nucleocapsid protein require only peptide domains outside the zinc fingers.

PubMed

De Rocquigny, H; Gabus, C; Vincent, A; Fournié-Zaluski, M C; Roques, B; Darlix, J L

1992-07-15

The nucleocapsid (NC) of human immunodeficiency virus type 1 consists of a large number of NC protein molecules, probably wrapping the dimeric RNA genome within the virion inner core. NC protein is a gag-encoded product that contains two zinc fingers flanked by basic residues. In human immunodeficiency virus type 1 virions, NCp15 is ultimately processed into NCp7 and p6 proteins. During virion assembly the retroviral NC protein is necessary for core formation and genomic RNA encapsidation, which are essential for virus infectivity. In vitro NCp15 activates viral RNA dimerization, a process most probably linked in vivo to genomic RNA packaging, and replication primer tRNA(Lys,3) annealing to the initiation site of reverse transcription. To characterize the domains of human immunodeficiency virus type 1 NC protein necessary for its various functions, the 72-amino acid NCp7 and several derived peptides were synthesized in a pure form. We show here that synthetic NCp7 with or without the two zinc fingers has the RNA annealing activities of NCp15. Further deletions of the N-terminal 12 and C-terminal 8 amino acids, leading to a 27-residue peptide lacking the finger domains, have little or no effect on NC protein activity in vitro. However deletion of short sequences containing basic residues flanking the first finger leads to a complete loss of NC protein activity. It is proposed that the basic residues and the zinc fingers cooperate to select and package the genomic RNA in vivo. Inhibition of the viral RNA binding and annealing activities associated with the basic residues flanking the first zinc finger of NC protein could therefore be used as a model for the design of antiviral agents.

Geology and ground water in Russian River Valley areas and in Round, Laytonville, and Little Lake Valleys, Sonoma and Mendocino Counties, California

USGS Publications Warehouse

Cardwell, G.T.

1965-01-01

This report describes the occurrence, availability, and quality of ground water in seven valley areas along the course of the Russian River in Sonoma and Mendocino Counties, Calif., and in three valleys in the upper drainage reach of the Eel River in Mendocino County. Except for the westward-trending lower Russian River valley, the remaining valley areas along the Russian River (Healdsburg, Alexander, Cloverdale, Sanel, Ukiah, and Potter Valleys) lie in northwest-trending structurally controlled depressions formed in marine rocks of Jurassic and Cretaceous age. The principal aquifer in all the valleys is the alluvium of Recent age, which includes highly permeable channel deposits of gravel and sand. Water for domestic, irrigation, industrial, and other uses is developed by (1) direct diversion from the Russian River and its tributaries, (2) withdrawal of ground water and river water from shallow wells near the river, and (3) withdrawals of ground water from wells in alluvial deposits at varying distances from the river. Surface water in the Russian River and most tributaries is of good chemical quality. The water is a calcium magnesium bicarbonate type and contains 75,200 parts per million of dissolved solids. Ground water is also of good chemical quality throughout most of the drainage basin, but the concentration of dissolved solids (100-300 parts per million) is somewhat higher than that in the surface water. Round, Laytonville, and Little Lake Valleys are in central and northern Mendocino County in the drainage basin of the northwestward flowing Eel River. In Round Valley the alluvium of Recent age yields water of good chemical quality in large quantities. Yields are lower and the chemical quality poorer in Laytonville Valley. Ground water in Little Lake Valley is relatively undeveloped. Selected descriptions of wells, drillers' logs, chemical analyses, and hydrographs showing water-level fluctuations are included in the report. Accompanying maps show the

Quaternary Geochronology, Paleontology, and Archaeology of the Upper San Pedro River Valley, Sonora, Mexico

NASA Astrophysics Data System (ADS)

Gaines, E. P.

2013-12-01

This poster presents the results of multi-disciplinary investigations of the preservation and extent of Quaternary fossil-bearing strata in the San Pedro River Valley in Sonora, Mexico. Geologic deposits in the portions of the San Pedro Valley in southern Arizona contain one of the best late Cenozoic fossil records known in North America and the best record of early humans and extinct mammals on the continent. The basin in the U.S. is one of the type locations for the Blancan Land Mammal Age. Hemiphilian and Irvingtonian fossils are common. Rancholabrean remains are widespread. Strata in the valley adjacent to the international border with Mexico have yielded the densest concentration of archaeological mammoth-kill sites known in the western hemisphere. Despite more than 60 years of research in the U.S., however, and the fact that over one third of the San Pedro River lies south of the international boundary, little has been known about the late Cenozoic geology of the valley in Mexico. The study reported here utilized extensive field survey, archaeological documentation, paleontological excavations, stratigraphic mapping and alluvial geochronology to determine the nature and extent of Quaternary fossil-bearing deposits in the portions of the San Pedro Valley in Sonora, Mexico. The results demonstrate that the Plio-Pleistocene fossil -bearing formations known from the valley in Arizona extend into the uppermost reaches of the valley in Mexico. Several new fossil sites were discovered that yielded the remains of Camelids, Equus, Mammuthus, and other Proboscidean species. Late Pleistocene archaeological remains were found on the surface of the surrounding uplands. AMS radiocarbon dating demonstrates the widespread preservation of middle- to late- Holocene deposits. However, the late Pleistocene deposits that contain the archaeological mammoth-kill sites in Arizona are absent in the valley in Mexico, and are now known to be restricted to relatively small portions of

Use of natural clinoptilolite for the removal of lead, copper and zinc in fixed bed column.

PubMed

Stylianou, Marinos A; Hadjiconstantinou, Michalis P; Inglezakis, Vasilis J; Moustakas, Konstantinos G; Loizidou, Maria D

2007-05-08

This work deals with the removal of lead, copper and zinc from aqueous solutions by using natural zeolite (clinoptilolite). Fixed bed experiments were performed, using three different volumetric flow rates of 5, 7 and 10bed volume/h, under a total normality of 0.01N, at initial pH of 4 and ambient temperature (25 degrees C). The removal efficiency increased when decreasing the flow rate and the following selectivity series was found: Pb(2+)>Zn(2+)> or =Cu(2+). Conductivity measurements showed that lead removal follows mainly ion exchange mechanism, while copper and zinc removal follows ion exchange and sorption mechanism as well.

Metalorganic chemical vapor deposition and characterization of ZnO materials

NASA Astrophysics Data System (ADS)

Sun, Shangzu; Tompa, Gary S.; Hoerman, Brent; Look, David C.; Claflin, Bruce B.; Rice, Catherine E.; Masaun, Puneet

2006-04-01

Zinc oxide is attracting growing interest for potential applications in electronics, optoelectronics, photonics, and chemical and biochemical sensing, among other applications. We report herein our efforts in the growth and characterization of p- and n-type ZnO materials by metalorganic chemical vapor deposition (MOCVD), focusing on recent nitrogen-doped films grown using diethyl zinc as the zinc precursor and nitric oxide (NO) as the dopant. Characterization results, including resistivity, Hall measurements, photoluminescence, and SIMS, are reported and discussed. Electrical behavior was observed to be dependent on illumination, atmosphere, and heat treatment, especially for p-type material.

Nature and origin of the nonsulfide zinc deposits in the Sierra Mojada District, Coahuila, Mexico: constraints from regional geology, petrography, and isotope analyses

NASA Astrophysics Data System (ADS)

Kyle, J. Richard; Ahn, Hyein; Gilg, H. Albert

2018-02-01

The Sierra Mojada District comprises multiple types of near-surface mineral concentrations ranging from polymetallic sulfide zones, "nonsulfide Zn" (NSZ) deposits, and a silver-rich Pb carbonate deposit hosted by lower Cretaceous carbonate strata. Hypogene concentrations of Fe-Zn-Pb-Cu-Ag sulfides and sulfosalts are locally preserved and are associated with hydrothermal dolomite and silica. Alteration mineralogy and sulfur isotope data suggest primary Zn-Pb-Ag mineralization from circa 200 °C hydrothermal fluids. The NSZ deposits dominantly consist of smithsonite and hemimorphite associated with local Mn-Fe oxides. The Red Zinc Zone consists of strata-bound zones dominantly of hemimorphite that fills pores in residual and resedimented Fe oxides. The White Zinc Zone shows local dissolution features, including internal sediments interbanded with and cemented by smithsonite. Similar Pb isotopic compositions of smithsonite, hemimorphite, and cerussite to Sierra Mojada galena document that the NSZ deposits originated from polymetallic carbonate-replacement sulfide deposits, with flow of metal-bearing groundwater being controlled by local topography and structural features in this extensional terrane. Oxygen isotope values for Sierra Mojada smithsonite are relatively constant (δ18OVSMOW = 20.9 to 23.3‰) but are unusually low compared to other supergene smithsonites. Using δ18OVSMOW (- 8‰) of modern groundwater at nearby Cuatrociénegas, smithsonite formational temperatures are calculated to have been between 26 to 35 °C. Smithsonite precipitation was favored by near-neutral conditions typical of carbonate terranes, whereas hemimorphite precipitated by reaction with wallrock silica and locally, or episodically, more acidic conditions resulting from sulfide oxidation. Transition to, and stabilization of, the modern desert climate over the past 9000 years from the Late Pleistocene wetter, cooler climate of northern Mexico resulted in episodic drawdown of the water

Levels of iron, silver, zinc, and lead in oranges and avocados from two gold-rich towns compared with levels in an adjacent gold-deficient town

DOE Office of Scientific and Technical Information (OSTI.GOV)

Golow, A.A.; Laryea, J.N.

1994-09-01

Fruits such as oranges and avocados are important sources of drinks and food in the Ghanaian Society. If such fruits contain various types of metals they may augument the types and amounts of them in the human body. The metals in fruits may depend on what is in the soils from which they are grown. If the soils contain toxic metals like lead, mercury and cadmium then the consumers may be poisoned as happened in the [open quotes]Ouchi - ouchi[close quotes], disease in Japan and similar episodes. In the area under study, the Geological Survey indicates the presence of 2.5more » ppm of lead, 10 - 20 ppm of copper and less than 15 ppm of nickel. Silver, not reported in commercial amounts, is a byproduct of gold productions at Obuasi. Since copper and nickel are presented in the area traces of silver will certainly occur. In the same manner zinc is usually associated with lead as sulphide of zinc blend trace amounts of it are likely to occur in the area. Of the four metals measured, iron and zinc essential for citrus. The extractable iron and zinc in the area of study were 90 and 1.8 mg/kg, levels on the low side for the healthy growth of crops. The investigation reported here is the comparison of the levels of some metals in oranges and avocados from farms in Obuasi and Konongo with those from farms in Kumasi City. This is a part of a project aimed at finding out differences in the metal contents of various food crops grown in various regions of the country. Konongo and Obuasi have soils which are rich in gold but Kumasi city, which is not too distant from these towns, does not have gold in its soil. 18 refs., 1 tab.« less

Crystal Structure Characterization of Thin Layer Zinc Oxide

NASA Astrophysics Data System (ADS)

Doyan, Aris; Susilawati; Azizatul Fitri, Siti; Ahzan, Sukainil

2017-05-01

In this research the characterization of the crystal structure of a thin layer of ZnO (zinc oxide) were synthesized by sol - gel method and spin coating deposited on a glass substrate. The samples were divided into three sol concentrations of 0.1, 0.3, 0.5 Molar and two deposition temperature is 350 °C, and 550 °C. UV-Vis. spectrophotometer results showed that in the spectrum of visible light (wavelength range 300-800 nm) has a transmittance value of which increases with increasing concentration and temperature deposition of zinc oxide, otherwise the value of the absorption and the band gap energy decreases with the addition of concentration and deposition temperature. The transmittances value of the highest and lowest absorption was 93.5% and 0.03 is at a concentration of 0.1 M and zinc oxide deposition temperature of 550 °C, with a value of band gap energy of 2.98 eV. The XRD results showed that the zinc oxide crystal orientation in the field of 013 with a crystal grain size 14.4472 nm. SEM results showed the surface morphology of zinc oxide such as rod-like.

Book review: Current perspectives on zinc deposits

USGS Publications Warehouse

Kelley, Karen D.

2016-01-01

This book, published in 2015 by the Irish Association for Economic Geology (IAEG), is a compilation of papers and abstracts written by selected authors who attended the ZINC 2010 Conference in Cork, Ireland. Unlike most books produced each decade by the IAEG, which are focused primarily on achievements of the Irish and European mineral sectors, this book has a global perspective of a single commodity—zinc. As stated in the Preface, the theme of the conference and book was quite relevant for the IAEG because Ireland has the highest concentration of zinc per square kilometer on the planet. The book contains 7 full papers and 5 extended abstracts by keynote speakers, followed by 17 extended abstracts by other presenters, plus an Appendix (reprint) of a previously published paper.

Geomorphological map and preliminary analysis of Quaternary sediments in the Planica-Tamar valley (Julian Alps, NW Slovenia)

NASA Astrophysics Data System (ADS)

Novak, Andrej; Šmuc, Andrej

2016-04-01

The Planica-Tamar valley is located in the Julian Alps in north-west Slovenia. The Planica-Tamar valley represents typical mountain glacial valley bounded by steep, mainly carbonate cliffs with some glacial deposits still preserved. The valley is currently being filled with numerous Holocene sediments deposited by rock falls, landslides, mass gravity flows and fluvial flows. These deposits are forming active or inactive interfingering talus slopes, alluvial and debris-flow fans, all of them with a complex history of sedimentation and erosion forming unconformity bounded sedimentary units. In order to make a thorough analysis of these deposits a detailed geomorphological map in a scale of 1:10 000 has been made. Six different types of sedimentary deposits were defined and mapped. These are moraines, lacustrine sediments, fluvio-glacial deposits, talus slopes, debris fans and alluvial fans. Other mapped features also include shape of ravines, their depths, ridges and direction of sedimentary flow. Additionally areas of active, semi-active and inactive sedimentation were marked. Moraines forms a ridge in the bottom of the valleys and are composed of unconsolidated, poorly sorted, subangular grains ranging from clay size to a few cubic meters big blocks. Lacustrine sediments are represented by laminated well sorted sand and silt, while fluvio-glacial deposits are composed of washed out subrounded sands and gravels. Talus slope deposits are characterised by clast-supported poorly sorted very angular gravel. Debris flow fans are represented by extremely poorly sorted matrix-supported gravels with grain size ranging from clay to few cubic meters big blocks. Alluvial fans are composed by variety of sedimentary textures. Sediments at the fan apex are clast-supported poorly sorted very angular gravels with up to a few cubic meters big block. In the middle part of the fan the sieve deposits are common, while in the distal parts a few centimeters thick layers of sand and

Zinc oxyfluoride transparent conductor

DOEpatents

Gordon, Roy G.

1991-02-05

Transparent, electrically conductive and infrared-reflective films of zinc oxyfluoride are produced by chemical vapor deposition from vapor mixtures of zinc, oxygen and fluorine-containing compounds. The substitution of fluorine for some of the oxygen in zinc oxide results in dramatic increases in the electrical conductivity. For example, diethyl zinc, ethyl alcohol and hexafluoropropene vapors are reacted over a glass surface at 400.degree. C. to form a visibly transparent, electrically conductive, infrared reflective and ultraviolet absorptive film of zinc oxyfluoride. Such films are useful in liquid crystal display devices, solar cells, electrochromic absorbers and reflectors, energy-conserving heat mirrors, and antistatic coatings.

Zinc Status and Risk of Cardiovascular Diseases and Type 2 Diabetes Mellitus—A Systematic Review of Prospective Cohort Studies

PubMed Central

Chu, Anna; Foster, Meika; Samman, Samir

2016-01-01

Zinc is an essential trace element with proposed therapeutic effects in Type 2 diabetes mellitus (DM), however, the associations between zinc status and the prospective risks of cardiovascular diseases (CVD) and Type 2 DM have not been evaluated. The current systematic review aims to determine the relationships between zinc intake or plasma/serum zinc levels and prospective incidence of CVD and Type 2 DM. Fourteen papers describing prospective cohort studies were included, reporting either CVD (n = 91,708) and/or Type 2 DM (n = 334,387) outcomes. Primary analyses from four out of five studies reported no association between zinc intake and CVD events, when adjusted for multiple variables. Higher serum zinc level was associated with lower risk of CVD in three out of five studies; pronounced effects were observed in vulnerable populations, specifically those with Type 2 DM and patients referred to coronary angiography. The limited evidence available suggests no association between zinc status and Type 2 DM risk. Further investigations into the mechanisms of zinc’s action on the pathogenesis of chronic diseases and additional evidence from observational studies are required to establish a recommendation for dietary zinc in relation to the prevention of CVD and Type 2 DM. PMID:27827959

Zinc oxide nanoparticles as a substitute for zinc oxide or colistin sulfate: Effects on growth, serum enzymes, zinc deposition, intestinal morphology and epithelial barrier in weaned piglets

PubMed Central

Zhang, Ligen; Su, Weipeng; Ying, Zhixiong; He, Jintian; Zhang, Lili; Zhong, Xiang; Wang, Tian

2017-01-01

The objective of this study was to evaluate effects of zinc oxide nanoparticles (nano-ZnOs) as a substitute for colistin sulfate (CS) and/or zinc oxide (ZnO) on growth performance, serum enzymes, zinc deposition, intestinal morphology and epithelial barrier in weaned piglets. A total of 216 crossbred Duroc×(Landrace×Yorkshire) piglets weaned at 23 days were randomly assigned into 3 groups, which were fed with basal diets supplemented with 20 mg/kg CS (CS group), 20mg/kg CS+3000 mg/kg ZnO (CS+ZnO group), and 1200 mg/kg nano-ZnOs (nano-ZnO group) for 14 days. Results indicated that compared to CS group, supplementation of 1200 mg/kg nano-ZnOs (about 30 nm) significantly increased final body weight and average daily gain, and 3000 mg/kg ZnO plus colistin sulfate significantly increased average daily gain and decreased diarrhea rate in weaned piglets. There was no significant difference in growth performance and diarrhea rate between nano-ZnO and CS+ZnO groups. Supplementation of nano-ZnOs did not affect serum enzymes (glutamic oxalacetic transaminase, glutamic-pyruvic transaminase, and lactate dehydrogenase), but significantly increased plasma and tissue zinc concentrations (liver, tibia), improved intestinal morphology (increased duodenal and ileal villus length, crypt depth, and villus surface), enhanced mRNA expression of ZO-1 in ileal mucosa, and significantly decreased diamine oxidase activity in plasma, total aerobic bacterial population in MLN as compared to CS group. Effects of nano-ZnOs on serum enzymes, intestinal morphology, and mRNA expressions of tight junction were similar to those of high dietary ZnO plus colistin sulfate, while nano-ZnOs significantly reduced zinc concentrations of liver, tibia, and feces, and decreased total aerobic bacterial population in MLN as compared to CS+ZnO group. These results suggested that nano-ZnOs (1200 mg/kg) might be used as a substitute for colistin sulfate and high dietary ZnO in weaned piglets. PMID:28704517

Zinc oxide nanoparticles as a substitute for zinc oxide or colistin sulfate: Effects on growth, serum enzymes, zinc deposition, intestinal morphology and epithelial barrier in weaned piglets.

PubMed

Wang, Chao; Zhang, Ligen; Su, Weipeng; Ying, Zhixiong; He, Jintian; Zhang, Lili; Zhong, Xiang; Wang, Tian

2017-01-01

The objective of this study was to evaluate effects of zinc oxide nanoparticles (nano-ZnOs) as a substitute for colistin sulfate (CS) and/or zinc oxide (ZnO) on growth performance, serum enzymes, zinc deposition, intestinal morphology and epithelial barrier in weaned piglets. A total of 216 crossbred Duroc×(Landrace×Yorkshire) piglets weaned at 23 days were randomly assigned into 3 groups, which were fed with basal diets supplemented with 20 mg/kg CS (CS group), 20mg/kg CS+3000 mg/kg ZnO (CS+ZnO group), and 1200 mg/kg nano-ZnOs (nano-ZnO group) for 14 days. Results indicated that compared to CS group, supplementation of 1200 mg/kg nano-ZnOs (about 30 nm) significantly increased final body weight and average daily gain, and 3000 mg/kg ZnO plus colistin sulfate significantly increased average daily gain and decreased diarrhea rate in weaned piglets. There was no significant difference in growth performance and diarrhea rate between nano-ZnO and CS+ZnO groups. Supplementation of nano-ZnOs did not affect serum enzymes (glutamic oxalacetic transaminase, glutamic-pyruvic transaminase, and lactate dehydrogenase), but significantly increased plasma and tissue zinc concentrations (liver, tibia), improved intestinal morphology (increased duodenal and ileal villus length, crypt depth, and villus surface), enhanced mRNA expression of ZO-1 in ileal mucosa, and significantly decreased diamine oxidase activity in plasma, total aerobic bacterial population in MLN as compared to CS group. Effects of nano-ZnOs on serum enzymes, intestinal morphology, and mRNA expressions of tight junction were similar to those of high dietary ZnO plus colistin sulfate, while nano-ZnOs significantly reduced zinc concentrations of liver, tibia, and feces, and decreased total aerobic bacterial population in MLN as compared to CS+ZnO group. These results suggested that nano-ZnOs (1200 mg/kg) might be used as a substitute for colistin sulfate and high dietary ZnO in weaned piglets.

Low-Temperature-Processed Zinc Oxide Thin-Film Transistors Fabricated by Plasma-Assisted Atomic Layer Deposition

NASA Astrophysics Data System (ADS)

Kawamura, Yumi; Tani, Mai; Hattori, Nozomu; Miyatake, Naomasa; Horita, Masahiro; Ishikawa, Yasuaki; Uraoka, Yukiharu

2012-02-01

We investigated zinc oxide (ZnO) thin films prepared by plasma assisted atomic layer deposition (PA-ALD), and thin-film transistors (TFTs) with the ALD ZnO channel layer for application to next-generation displays. We deposited the ZnO channel layer by PA-ALD at 100 or 300 °C, and fabricated TFTs. The transfer characteristic of the 300 °C-deposited ZnO TFT exhibited high mobility (5.7 cm2 V-1 s-1), although the threshold voltage largely shifted toward the negative (-16 V). Furthermore, we deposited Al2O3 thin film as a gate insulator by PA-ALD at 100 °C for the low-temperature TFT fabrication process. In the case of ZnO TFTs with the Al2O3 gate insulator, the shift of the threshold voltage improved (-0.1 V). This improvement of the negative shift seems to be due to the negative charges of the Al2O3 film deposited by PA-ALD. On the basis of the experimental results, we confirmed that the threshold voltage of ZnO TFTs is controlled by PA-ALD for the deposition of the gate insulator.

Maps showing mineral resource assessment for porphyry and stockwork deposits of copper, molybdenum, and tungsten and for stockwork and disseminated deposits of gold and silver in the Butte 1 degree by 2 degrees Quadrangle, Montana

USGS Publications Warehouse

Elliott, J.E.; Moll, S.H.; Wallace, C.A.; Lee, G.K.; Antweiler, J.C.; Lidke, D.J.; Rowan, L.C.; Hanna, W.F.; Trautwein, C.M.; Dwyer, John L.

1993-01-01

This report documents the assessment for potential occurrences of undiscovered porphyry and stockwork deposits of copper, molybdenum, and tungsten (porphyry Cu-Mo-W) and stockwork and disseminated deposits of gold and silver (disseminated Au-Ag) in the Butte 1 °X2° quadrangle. The Butte quadrangle, in west-central Montana, is one of the best known mineral producing regions in the U.S. Mining districts in the quadrangle, including the world famous Butte or Summit Valley district, have produced a variety of metallic and nonmetallic mineral commodities valued at more than $6.4 billion (at the time of production). Because of its importance as a mineral producing region, the Butte quadrangle was selected for study by the U.S. Geological Survey under the Conterminous United States Mineral Assessment Program (CUSMAP). Under this program, new data on geology, geochemistry, geophysics, geochronology, mineral resources, and remote sensing were collected and synthesized. The field and laboratory studies were supported, in part, by funding from the Geologic Framework and Synthesis Program and the Wilderness Program. The methods used in this resource assessment for porphyry Cu-Mo-W and disseminated Au-Ag deposits in the quadrangle include a compilation of all data, the development of descriptive occurrence models, and the analysis of data using techniques provided by a Geographic Information System (GIS). This map is one of several maps on the Butte 1 °X2° quadrangle. Other deposit types have been assessed for the Butte quadrangle, and maps (U.S. Geological Survey (USGS) Miscellaneous Investigation Series Maps) for each of the following have been prepared: Vein and replacement deposits of gold, silver, copper, lead, zinc, manganese, and tungsten (Elliott, Wallace, and others, 1992a) and skarn deposits of gold, silver, copper, tungsten, and iron (Elliott and others, 1992b ). Other publications resulting from this study include linear features map (Rowan and others, 1991

Electrochemical behavior of lead dioxide deposited on reticulated vitreous carbon (RVC)

NASA Astrophysics Data System (ADS)

Czerwiński, Andrzej; Żelazowska, Malgorzata

The electrochemical performance of lead dioxide deposited on reticulated vitreous carbon (RVC) has been investigated in basic and acidic solutions (0.1 M NaOH, 0.1 M Na 2BB 4OO 7 and 0.5 M H 2SSO 4)). For comparison, pure lead and lead dioxide deposited on platinized RVC (Pt/ RVC) were also included in the study. Our results indicate that the behavior of RVC covered with lead dioxide (without platinum) resembles that of lead dioxide generated electrochemically on metallic lead.

Electrodeposition of zinc hydroxysulfate nanosheets and reduction to zinc metal microdendrites on polypyrrole films.

PubMed

Andreoli, Enrico; Rooney, Denise A; Redington, Wynette; Gunning, Robert; Breslin, Carmel B

2012-01-01

Nanothin sheets made of zinc sulfate hydroxide hydrate, ZnSO4[Zn(OH)2]3 x 5H2O, are easily and quickly prepared using an innovative electrochemical route onto polypyrrole-polystyrene sulfonate (PPy-PSS) films. The sheets are characterized using a range of experimental techniques. The deposits are formed on the film surface with instantaneous nucleation to grow into a network of entangled nanosheets. The effect of the experimental conditions on the deposition is reported. Interestingly, the formation of the nanosheets is observed on PPy-PSS films only, and not on films doped with other sulfate/sulfonate dopants. The zinc nanosheets can be easily electrochemically reduced to metallic zinc microdentrites.

SAR Imagery Applied to the Monitoring of Hyper-Saline Deposits: Death Valley Example (CA)

NASA Technical Reports Server (NTRS)

Lasne, Yannick; Paillou, Philippe; Freeman, Anthony; Chapman, Bruce

2009-01-01

The present study aims at understanding the influence of salinity on the dielectric constant of soils and then on the backscattering coeff cients recorded by airborne/spaceborne SAR systems. Based on dielectric measurements performed over hyper-saline deposits in Death Valley (CA), as well as laboratory electromagnetic characterization of salts and water mixtures, we used the dielectric constants as input parameters of analytical IEM simulations to model both the amplitude and phase behaviors of SAR signal at C, and L-bands. Our analytical simulations allow to reproduce specif c copolar signatures recorded in SAR data, corresponding to the Cottonball Basin saltpan. We also propose the copolar backscattering ratio and phase difference as indicators of moistened and salt-affected soils. More precisely, we show that these copolar indicators should allow to monitor the seasonal variations of the dielectric properties of saline deposits.

Acid production potentials of massive sulfide minerals and lead-zinc mine tailings: a medium-term study.

PubMed

Çelebi, Emin Ender; Öncel, Mehmet Salim; Kobya, Mehmet

2018-01-01

Weathering of sulfide minerals is a principal source of acid generation. To determine acid-forming potentials of sulfide-bearing materials, two basic approaches named static and kinetic tests are available. Static tests are short-term, and easily undertaken within a few days and in a laboratory. In contrast, kinetic tests are long-term procedures and mostly carried out on site. In this study, experiments were conducted over a medium-term period of 2 months, not as short as static tests and also not as long as kinetic tests. As a result, pH and electrical conductivity oscillations as a function of time, acid-forming potentials and elemental contents of synthetically prepared rainwater leachates of massive sulfides and sulfide-bearing lead-zinc tailings from abandoned and currently used deposition areas have been determined. Although the lowest final pH of 2.70 was obtained in massive pyrite leachate, massive chalcopyrite leachate showed the highest titrable acidity of 1.764 g H 2 SO 4 /L. On the other hand, a composite of currently deposited mine tailings showed no acidic characteristic with a final pH of 7.77. The composite abandoned mine tailing leachate had a final pH of 6.70, close to the final pH of massive galena and sphalerite leachates, and produced a slight titrable acidity of 0.130 g H 2 SO 4 /L.

Occurrence of silver minerals in a silver-rich pocket in the massive sulfide zinc-lead ores in the Edwards mine, New York

DOE Office of Scientific and Technical Information (OSTI.GOV)

Serviss, C.R.; Grout, C.M.; Hagni, R.D.

1985-01-01

Ore microscopic examination of uncommon silver-rich ores from the Edwards mine has detected three silver minerals, native silver, freibergite, and argentite, that were previously unreported in the literature from the Balmat-Edwards district. The zinc-lead ore deposits of the Balmat-Edwards District in northern New York are composed of very coarse-grained massive sulfides, principally sphalerite, galena, and pyrite. The typical ores contain small amounts of silver in solid solution galena. Galena concentrates produced from those ores have contained an average of 15 ounces of silver per ton of 60% lead concentrates. In contrast to the typical ore a silver-rich pocket, that measuredmore » three feet by three feet on the vertical mine face and was the subject of this study, contained nearly 1% silver in a zinc ore. Ore microscopic study shows that this ore is especially characterized by abundant, relatively fine-grained chalcopyrite with anhedral pyrite inclusions. Fine-grained sphalerite, native silver, argentite, freibergite and arsenopyrite occur in association with the chalcopyrite and as fracture-fillings in gangue minerals. Geochemically anomalous amounts of tin, barium, chromium, and nickel also are present in the silver-rich pocket. The silver-rich pocket may mark the locus of an early feeder vent or alternatively it may record a hydrothermal event that was superimposed upon the event responsible for the metamorphic ore textures.« less

Removal of metals from lead-zinc mine tailings using bioleaching and followed by sulfide precipitation.

PubMed

Ye, Maoyou; Li, Guojian; Yan, Pingfang; Ren, Jie; Zheng, Li; Han, Dajian; Sun, Shuiyu; Huang, Shaosong; Zhong, Yujian

2017-10-01

Mine tailings often contain significant amounts of metals and sulfide, many traditional operations used to minerals was not as good as those currently available. This study investigated metals removal from lead-zinc mine tailings using bioleaching and followed by sulfide precipitation. Metals were dissolved from the tailings by the bacteria in a bioleaching reactor. During a 10% pulp density bioleaching experiment, approximately 0.82% Pb, 97.38% Zn, and 71.37% Fe were extracted after 50 days. With the pulp density of 10% and 20%, the dissolution of metals followed shrinking core kinetic model. Metals (Pb, Zn, and Fe) present in the pregnant bioleaching leachate. Metals were next precipitated as a sulfide phase using sodium sulfide (Na 2 S). Metal precipitations were selectively and quantitatively produced from the bioleaching leachate by adding Na 2 S. More than 99% of the zinc and 75% of the iron was precipitated using 25 g/L Na 2 S in the bioleaching leachate. The results in the study were to provide useful information for recovering or removing metals from lead-zinc mine tailings. Copyright © 2017 Elsevier Ltd. All rights reserved.

Cryostratigraphy and the Sublimation Unconformity in Permafrost from an Ultraxerous Environment, University Valley, McMurdo Dry Valleys of Antarctica

NASA Technical Reports Server (NTRS)

Lapalme, Caitlin M.; Fortier, Daniel; Pollard, Wayne; Lacelle, Denis; Davila, Alfonso; McKay, Christopher P.

2017-01-01

The cryostratigraphy of permafrost in ultraxerous environments is poorly known. In this study, icy permafrost cores from University Valley (McMurdo Dry Valleys, Antarctica) were analyzed for sediment properties, ground-ice content, types and distribution of cryostructures, and presence of unconformities. No active layer exists in the valley, but the ice table, a sublimation unconformity, ranges from 0 to 60 cm depth. The sediments are characterized as a medium sand, which classifies them as low to non-frost susceptible. Computed tomography (CT) scan images of the icy permafrost cores revealed composite cryostructures that included the structureless, porous visible, suspended and crustal types. These cryostructures were observed irrespective of ground-ice origin (vapour deposited and freezing of snow meltwater), suggesting that the type and distribution of cryostructures could not be used as a proxy to infer the mode of emplacement of ground ice. Volumetric ice content derived from the CT scan images underestimated measured volumetric ice content, but approached measured excess ice content. A palaeo-sublimation unconformity could not be detected from a change in cryostructures, but could be inferred from an increase in ice content at the maximum predicted ice table depth. This study highlights some of the unique ground-ice processes and cryostructures in ultraxerous environments.

Erosion of steepland valleys by debris flows

USGS Publications Warehouse

Stock, J.D.; Dietrich, W.E.

2006-01-01

Episodic debris flows scour the rock beds of many steepland valleys. Along recent debris-flow runout paths in the western United States, we have observed evidence for bedrock lowering, primarily by the impact of large particles entrained in debris flows. This evidence may persist to the point at which debris-flow deposition occurs, commonly at slopes of less than ???0.03-0.10. We find that debris-flow-scoured valleys have a topographic signature that is fundamentally different from that predicted by bedrock river-incision models. Much of this difference results from the fact that local valley slope shows a tendency to decrease abruptly downstream of tributaries that contribute throughgoing debris flows. The degree of weathering of valley floor bedrock may also decrease abruptly downstream of such junctions. On the basis of these observations, we hypothesize that valley slope is adjusted to the long-term frequency of debris flows, and that valleys scoured by debris flows should not be modeled using conventional bedrock river-incision laws. We use field observations to justify one possible debris-flow incision model, whose lowering rate is proportional to the integral of solid inertial normal stresses from particle impacts along the flow and the number of upvalley debris-flow sources. The model predicts that increases in incision rate caused by increases in flow event frequency and length (as flows gain material) downvalley are balanced by rate reductions from reduced inertial normal stress at lower slopes, and stronger, less weathered bedrock. These adjustments lead to a spatially uniform lowering rate. Although the proposed expression leads to equilibrium long-profiles with the correct topographic signature, the crudeness with which the debris-flow dynamics are parameterized reveals that we are far from a validated debris-flow incision law. However, the vast extent of steepland valley networks above slopes of ???0.03-0.10 illustrates the need to understand debris

Indium Doped Zinc Oxide Thin Films Deposited by Ultrasonic Chemical Spray Technique, Starting from Zinc Acetylacetonate and Indium Chloride

PubMed Central

Biswal, Rajesh; Maldonado, Arturo; Vega-Pérez, Jaime; Acosta, Dwight Roberto; Olvera, María De La Luz

2014-01-01

The physical characteristics of ultrasonically sprayed indium-doped zinc oxide (ZnO:In) thin films, with electrical resistivity as low as 3.42 × 10−3 Ω·cm and high optical transmittance, in the visible range, of 50%–70% is presented. Zinc acetylacetonate and indium chloride were used as the organometallic zinc precursor and the doping source, respectively, achieving ZnO:In thin films with growth rate in the order of 100 nm/min. The effects of both indium concentration and the substrate temperature on the structural, morphological, optical, and electrical characteristics were measured. All the films were polycrystalline, fitting well with hexagonal wurtzite type ZnO. A switching in preferential growth, from (002) to (101) planes for indium doped samples were observed. The surface morphology of the films showed a change from hexagonal slices to triangle shaped grains as the indium concentration increases. Potential applications as transparent conductive electrodes based on the resulting low electrical resistance and high optical transparency of the studied samples are considered. PMID:28788118

Indium Doped Zinc Oxide Thin Films Deposited by Ultrasonic Chemical Spray Technique, Starting from Zinc Acetylacetonate and Indium Chloride.

PubMed

Biswal, Rajesh; Maldonado, Arturo; Vega-Pérez, Jaime; Acosta, Dwight Roberto; De La Luz Olvera, María

2014-07-04

The physical characteristics of ultrasonically sprayed indium-doped zinc oxide (ZnO:In) thin films, with electrical resistivity as low as 3.42 × 10 -3 Ω·cm and high optical transmittance, in the visible range, of 50%-70% is presented. Zinc acetylacetonate and indium chloride were used as the organometallic zinc precursor and the doping source, respectively, achieving ZnO:In thin films with growth rate in the order of 100 nm/min. The effects of both indium concentration and the substrate temperature on the structural, morphological, optical, and electrical characteristics were measured. All the films were polycrystalline, fitting well with hexagonal wurtzite type ZnO. A switching in preferential growth, from (002) to (101) planes for indium doped samples were observed. The surface morphology of the films showed a change from hexagonal slices to triangle shaped grains as the indium concentration increases. Potential applications as transparent conductive electrodes based on the resulting low electrical resistance and high optical transparency of the studied samples are considered.

One-stage pulsed laser deposition of conductive zinc oxysulfide layers

NASA Astrophysics Data System (ADS)

Bereznev, Sergei; Kocharyan, Hrachya; Maticiuc, Natalia; Naidu, Revathi; Volobujeva, Olga; Tverjanovich, Andrey; Kois, Julia

2017-12-01

Zinc oxysulfide - Zn(O,S) is one of the prospective materials for substitution of conventional CdS buffer layer in complete optoelectronic devices due to its optimal bandgap and low toxicity. In this work Zn(O,S) thin films have been prepared by one-step pulsed laser deposition technique. The films with a thickness of 650 nm were deposited onto the FTO/glass substrates at different substrate temperatures from room temperature to 400 °C. Zn(O,S) layers were characterized by means of scanning electron microscopy, energy dispersive spectroscopy, Raman, X-ray diffraction, UV-vis spectroscopy and Van der Pauw technique. It was found, that obtained Zn(O,S) layers are mainly polycrystalline, highly uniform, transparent, electrically conductive and demonstrate good adhesion to the FTO/glass substrates. In addition, we show that elemental composition of PLD Zn(O,S) films depends on the substrate temperature. For the first time high quality single phase conductive Zn(O,S) layers were prepared by one stage PLD in high vacuum at relatively low temperature 200 °C without any post treatment. The properties of prepared Zn(O,S) films suggest that these films can be applied as buffer layer in optoelectronic devices.

Fossil and active fumaroles in the 1912 eruptive deposits, Valley of ten thousand smokes, Alaska

USGS Publications Warehouse

Keith, T.E.C.

1991-01-01

Fumaroles in the ash-flow sheet emplaced during the 1912 eruption of Novarupta were intensely active throughout the Valley of Ten Thousand Smokes (VTTS) when first studied in 1917. Fumarole temperatures recorded in 1919 were as hot as 645??C. Influx of surface waters into the hot ash-flow sheet provided the fluid flow to sustain the fumaroles but also enhanced cooling so that by the mid-1930's vigorous activity survived only in the vent region. Configuration and distribution of high-temperature fissure fumaroles tens of meters long, that are prevalent in the middle and upper VTTS, were controlled largely by sintering and degree of welding, which in turn controlled fracturing and permeability of the ash-flow tuff. One fracture type developed parallel to the enclosing valley walls during compaction of the ash-flow sheet. Another type extends across the VTTS nearly perpendicular to the flow direction. A third type of randomly oriented fractures developed as cooling contraction cracks during vapor-phase devitrification. In distal parts of the ash-flow sheet where the tuff is nonwelded, prominent fumaroles have irregular funnel-shaped morphologies. Fumarole distribution in the nonwelded part of the ash-flow sheet is concentrated above pre-emplacement river channels. The hottest, longest-lived fumaroles occurred in the upper VTTS near the 1912 vent where the ash-flow sheet is thicker, more indurated, and on average more mafic (richer in dacite and andesite) in contrast to the thinner, nonwelded rhyolitic tuff in the distal part of the sheet. Fumarolic activity was less intense in the distal part of the tuff because of lower emplacement temperatures, more diffuse fumarole conduits in the nonwelded tuff, and the thinness of the ash-flow sheet. Chemical leaching of ash-flow tuff by hot rising fluids took place adjacent to fumarolic conduits in deep parts of the fumaroles. Deposition of incrustation minerals, the components of which were carried upward by fumarolic gases

INFLUENCE OF SNOWFALL ON BLOOD LEAD LEVELS OF FREE-FLYING BALD EAGLES (HALIAEETUS LEUCOCEPHALUS) IN THE UPPER MISSISSIPPI RIVER VALLEY.

PubMed

Lindblom, Ronald A; Reichart, Letitia M; Mandernack, Brett A; Solensky, Matthew; Schoenebeck, Casey W; Redig, Patrick T

2017-10-01

Lead poisoning of scavenging raptors occurs primarily via consumption of game animal carcasses containing lead, which peaks during fall firearm hunting seasons. We hypothesized that snowfall would mitigate exposure by concealing carcasses. We categorized blood lead level (BLL) for a subsample of Bald Eagles (Haliaeetus leucocephalus) from the Upper Mississippi River Valley and described BLL with respect to age, sex, and snowfall. We captured Bald Eagles overwintering in the Upper Mississippi River Valley (n=55) between December 1999 and January 2002. Individual BLL ranged from nondetectable to 335 μg/dL, with 73% of the samples testing positive for acute exposure to lead. Eagle BLL did not significantly differ between age or sex, but levels were higher immediately following the hunting season, and they were lower when the previous month's snowfall was greater than 11 cm. This study suggests a window of time between the white-tailed deer (Odocoileus virginianus) hunting season and the onset of snow when the population experienced peak exposure to lead. Combining these findings with existing research, we offer a narrative of the annual lead exposure cycle of Upper Mississippi River Valley Bald Eagles. These temporal associations are necessary considerations for accurate collection and interpretation of BLL.

Discrimination of bullet types using analysis of lead isotopes deposited in gunshot entry wounds.

PubMed

Wunnapuk, Klintean; Minami, Takeshi; Durongkadech, Piya; Tohno, Setsuko; Ruangyuttikarn, Werawan; Moriwake, Yumi; Vichairat, Karnda; Sribanditmongkol, Pongruk; Tohno, Yoshiyuki

2009-01-01

In order to discriminate bullet types used in firearms, of which the victims died, the authors investigated lead isotope ratios in gunshot entry wounds from nine lead (unjacketed) bullets, 15 semi-jacketed bullets, and 14 full-jacketed bullets by inductively coupled plasma-mass spectrometry. It was found that the lead isotope ratio of 207/206 in gunshot entry wounds was the highest with lead bullets, and it decreased in order from full-jacketed to semi-jacketed bullets. Lead isotope ratios of 208/206 or 208/207 to 207/206 at the gunshot entry wound were able to discriminate semi-jacketed bullets from lead and full-jacketed ones, but it was difficult to discriminate between lead and full-jacketed bullets. However, a combination of element and lead isotope ratio analyses in gunshot entry wounds enabled discrimination between lead, semi-jacketed, and full-jacketed bullets.

The sensitivity of the electron transport within bulk zinc-blende gallium nitride to variations in the crystal temperature, the doping concentration, and the non-parabolicity coefficient associated with the lowest energy conduction band valley

DOE Office of Scientific and Technical Information (OSTI.GOV)

Siddiqua, Poppy; O'Leary, Stephen K., E-mail: stephen.oleary@ubc.ca

2016-09-07

Within the framework of a semi-classical three-valley Monte Carlo simulation approach, we analyze the steady-state and transient electron transport that occurs within bulk zinc-blende gallium nitride. In particular, we examine how the steady-state and transient electron transport that occurs within this material changes in response to variations in the crystal temperature, the doping concentration, and the non-parabolicity coefficient associated with the lowest energy conduction band valley. These results are then contrasted with those corresponding to a number of other compound semiconductors of interest.

VO2+ ions in zinc lead borate glasses studied by EPR and optical absorption techniques.

PubMed

Prakash, P Giri; Rao, J Lakshmana

2005-09-01

Electron paramagnetic resonance (EPR) and optical absorption spectra of vanadyl ions in zinc lead borate (ZnO-PbO-B2O3) glass system have been studied. EPR spectra of all the glass samples exhibit resonance signals characteristic of VO2+ ions. The values of spin-Hamiltonian parameters indicate that the VO2+ ions in zinc lead borate glasses were present in octahedral sites with tetragonal compression and belong to C4V symmetry. The spin-Hamiltonian parameters g and A are found to be independent of V2O5 content and temperature but changing with ZnO content. The decrease in Deltag( parallel)/Deltag( perpendicular) value with increase in ZnO content indicates that the symmetry around VO2+ ions is more octahedral. The decrease in intensity of EPR signal above 10 mol% of V2O5 is attributed to a fall in the ratio of the number of V4+ ions (N4) to the number of V5+ ions (N5). The number of spins (N) participating in resonance was calculated as a function of temperature for VO2+ doped zinc lead borate glass sample and the activation energy was calculated. From the EPR data, the paramagnetic susceptibility was calculated at various temperatures and the Curie constant was evaluated from the 1/chi-T graph. The optical absorption spectra show single absorption band due to VO2+ ions in tetragonally distorted octahedral sites.

Gravity survey of Dixie Valley, west-central Nevada

USGS Publications Warehouse

Schaefer, Donald H.

1983-01-01

Dixie Valley, a northeast-trending structural trough typical of valleys in the Basin and Range Province, is filled with a maximum of about 10,000 feet of alluvial and lacustrine deposits , as estimated from residual-gravity measurements obtained in this study. On the basis of gravity measurements at 300 stations on nine east-west profiles, the gravity residuals reach a maximum of 30 milligals near the south-central part of the valley. Results from a three-dimensional inversion model indicate that the central depression of the valley is offset to the west of the geographic axis. This offset is probably due to major faulting along the west side of the valley adjacent to the Stillwater Range. Comparison of depths to bedrock obtained during this study and depths obtained from a previous seismic-refraction study indicates a reasonably good correlation. A heterogeneous distribution of densities within the valley-fill deposits would account for differing depths determined by the two methods. (USGS)

Maps showing mineral resource assessment for skarn deposits of gold, silver, copper, tungsten, and iron in the Butte 1 degree by 2 degrees Quadrangle, Montana

USGS Publications Warehouse

Elliott, J.E.; Wallace, C.A.; Lee, G.K.; Antweiler, J.C.; Lidke, D.J.; Rowan, L.C.; Hanna, W.F.; Trautwein, C.M.; Dwyer, John L.; Moll, S.H.

1992-01-01

The purpose of this report is to assess the potential for undiscovered skarn deposits of gold, silver, copper, tungsten, and iron in the Butte 1 °X2° quadrangle. Other deposit types have been assessed and reports for each of the following have been prepared: Vein and replacement deposits of gold, silver, copper, lead, zinc, ·manganese, and tungsten; porphyry-stockwork deposits of copper, molybdenum, and tungsten; stockwork-disseminated deposits of gold and silver; placer deposits of gold; and miscellaneous deposit types including strata-bound deposits of copper and silver in rocks of the Middle Proterozoic Belt Supergroup, phosphate deposits in the Permian Phosporia Formation, and deposits of barite and fluorite. The Butte quadrangle, in west-central Montana, is one of the most mineralized and productive mining regions in the U.S. Its mining districts, including the world famous Butte or Summit Valley district, have produced a variety of metallic and nonmetallic mineral commodities valued at more than $6.4 billion (at the time of production). Because of its importance as a mineral producing region, the Butte quadrangle was selected for study by the U.S. Geological Survey under the Conterminous United States Mineral Assessment Program (CUSMAP). Under this program, new data on geology, geochemistry, geophysics, geochronology, mineral resources, and remote sensing were collected and synthesized. The field and laboratory studies were supported, in part, by funding from the Geologic Framework and Synthesis Program and the Wilderness Program. The methods used in resource assessment include a compilation of all data into data sets, the development of an occurrence model for skarn deposits in the quadrangle, and the analysis of data using techniques provided by a Geographic Information System (GIS). This map is one of a number of reports and maps on the Butte 1 °X2° quadrangle. Other publications resulting from this study include U.S. Geological Survey (USGS

Electrochemical behavior of zinc particles with silica based coatings as anode material for zinc air batteries with improved discharge capacity

NASA Astrophysics Data System (ADS)

Schmid, M.; Willert-Porada, M.

2017-05-01

Silica coatings on zinc particles as anode material for alkaline zinc air batteries are expected to reduce early formation of irreversible ZnO passivation layers during discharge by controlling zinc dissolution and precipitation of supersaturated zincates, Zn(OH)42-. Zinc particles were coated with SiO2 (thickness: 15 nm) by chemical solution deposition and with Zn2SiO4 (thickness: 20 nm) by chemical vapor deposition. These coatings formed a Si(OH)4 gel in aqueous KOH and retarded hydrogen evolution by 40%. By treatment in aqueous KOH and drying afterwards, the silica coatings were changed into ZnO-K2O·SiO2 layers. In this work, the electrochemical performance of such coated zinc particles is investigated by different electrochemical methods in order to gain a deeper understanding of the mechanisms of the coatings, which reduce zinc passivation. In particular, zinc utilization and changes in internal resistance are investigated. Moreover, methods for determination of diffusion coefficients, charge carrier numbers and activation energies for electrochemical oxidation are determined. SiO2-coated zinc particles show improved discharge capacity (CVD-coated zinc: 69% zinc utilization, CSD-coated zinc: 62% zinc utilization) as compared to as-received zinc (57% zinc utilization) at C/20 rate, by reducing supersaturation of zincates. Additionally, KOH-modified SiO2-coated zinc particles enhance rechargeability after 100% depth-of-discharge.

Preliminary report on deposit models for sand and gravel in the Cache la Poudre River valley

USGS Publications Warehouse

Langer, W.H.; Lindsey, D.A.

1999-01-01

The stratigraphy, sedimentary features, and physical characteristics of gravel deposits in the Cache la Poudre River valley were studied to establish geologic models for these deposits. Because most of the gravel mined in the valley is beneath the low terraces and floodplain, the quality of these deposits for aggregate was studied in detail at eight sites in a 25.5-mile reach between Fort Collins and Greeley, Colorado. Aggregate quality was determined by field and laboratory measurements on samples collected under a consistent sampling plan. The Broadway terrace is underlain by Pleistocene alluvium and, at some places, by fine-grained wind-blown deposits. The Piney Creek terrace, low terraces, and floodplain are primarily underlain by Holocene alluvium. Pleistocene alluvium may underlie these terraces at isolated locations along the river. Gravels beneath the Piney Creek terrace, low terraces, and floodplain are divisible into two units that are poorly distinguishable at the upstream end of the study area, but are readily distinguishable about 7 miles downstream. Where distinguished, the two gravel units are separated by a sharp, locally erosional, contact. The upper gravel is probably of Holocene age, but the lower gravel is considered to be Holocene and Pleistocene. The primary variation in particle size of the gravels beneath the floodplain and low terraces of the Cache la Poudre River valley is the downstream decrease in the proportion of particles measuring 3/4 inch and larger. Above Fort Collins, about 60 pct of the gravel collects on the 3/4 inch sieve, whereas about 50 pct of gravel collects on the same sieve size at Greeley. For 1.5-inch sieves, the corresponding values are about 50 pct for Fort Collins and only about 30 pct for Greeley. Local differences in particle size and sorting between the upper and lower gravel units were observed in the field, but only the coarsest particle sizes appear to have been concentrated in the lower unit. Field

Zinc Chloride and Lead Acetate-Induced Passive Avoidance Memory Retention Deficits Reversed by Nicotine and Bucladesine in Mice.

PubMed

Tabrizian, Kaveh; Yazdani, Abdolmajid; Baheri, Behnam; Payandemehr, Borna; Sanati, Mehdi; Hashemzaei, Mahmoud; Miri, Abdolhossein; Zandkarimi, Majid; Belaran, Maryam; Fanoudi, Sahar; Sharifzadeh, Mohammad

2016-01-01

It is very important to investigate the neurotoxic effects of metals on learning and memory processes. In this study, we tried to investigate the effects and time course properties of oral administration of zinc chloride (25, 50, and 75 mg/kg, for 2 weeks), lead acetate (250, 750, 1,500, and 2,500 ppm for 4, 6 and 8 weeks), and their possible mechanisms on a model of memory function. For this matter, we examined the intra-peritoneal injections of nicotine (0.25, 0.5, 1, and 1.5 mg/kg) and bucladesine (50, 100, 300, and 600 nM/mouse) for 4 days alone and in combination with mentioned metals in the step-through passive avoidance task. Control animals received saline, drinking water, saline, and DMSO (dimethyl sulfoxide)/deionized water (1:9), respectively. At the end of each part of studies, animals were trained for 1 day in step-through task. The avoidance memory retention alterations were evaluated 24 and 48 h later in singular and combinational studies. Zinc chloride (75 mg/kg) oral gavage for 2 weeks decreased latency times compared to control animals. Also, lead acetate (750 ppm oral administrations for 8 weeks) caused significant lead blood levels and induced avoidance memory retention impairments. Four-days intra-peritoneal injection of nicotine (1 mg/kg) increased latency time compared to control animals. Finally, findings of this research showed that treatment with intra-peritoneal injections of nicotine (1 mg/kg) and/or bucladesine (600 nM/mouse) reversed zinc chloride- and lead acetate-induced avoidance memory retention impairments. Taken together, these results showed the probable role of cholinergic system and protein kinase A pathways in zinc chloride- and lead acetate-induced avoidance memory alterations.

Deposition of Zinc Oxide on Different Polymer Textiles and Their Antibacterial Properties.

PubMed

Fiedot-Toboła, Marta; Ciesielska, Magdalena; Maliszewska, Irena; Rac-Rumijowska, Olga; Suchorska-Woźniak, Patrycja; Teterycz, Helena; Bryjak, Marek

2018-04-30

A surface modification of polyamide 6 (PA), polyethylene terephthalate (PET) and polypropylene (PP) textiles was performed using zinc oxide to obtain antibacterial layer. ZnO microrods were synthesized on ZnO nanoparticles (NPs) as a nucleus centers by chemical bath deposition (CBD) process. Scanning Electron Microscopy (SEM) and X-ray diffraction (XRD) indicated that wurzite ZnO microrods were obtained on every sample. Differential Scanning Calorimetry (DSC), Fourier Transform Infrared Spectroscopy (FTIR), Atomic Force Microscopy (AFM) and Liquid Absorption Capacity (LAC) analysis indicate that the amount and structure of antibacterial layer is dependent on roughness and wettability of textile surface. The rougher and more hydrophilic is the material, the more ZnO were deposited. All studied textiles show significant bactericidal activity against Escherichia coli ( E. coli ) and Staphylococcus aureus ( S. aureus ). A possible mechanism and difference in sensitivity between Gram-negative and Gram-positive bacteria to ZnO is discussed. Considering that antibacterial activity of ZnO is caused by Reactive Oxygen Species (ROS) generation, an influence of surface to volume ratio and crystalline parameters is also discussed.

High sensitive formaldehyde graphene gas sensor modified by atomic layer deposition zinc oxide films

DOE Office of Scientific and Technical Information (OSTI.GOV)

Mu, Haichuan; Zhang, Zhiqiang; Wang, Keke

2014-07-21

Zinc oxide (ZnO) thin films with various thicknesses were fabricated by Atomic Layer Deposition on Chemical Vapor Deposition grown graphene films and their response to formaldehyde has been investigated. It was found that 0.5 nm ZnO films modified graphene sensors showed high response to formaldehyde with the resistance change up to 52% at the concentration of 9 parts-per-million (ppm) at room temperature. Meanwhile, the detection limit could reach 180 parts-per-billion (ppb) and fast response of 36 s was also obtained. The high sensitivity could be attributed to the combining effect from the highly reactive, top mounted ZnO thin films, and high conductivemore » graphene base network. The dependence of ZnO films surface morphology and its sensitivity on the ZnO films thickness was also investigated.« less

Luminescence ages for alluvial-fan deposits in Southern Death Valley: Implications for climate-driven sedimentation along a tectonically active mountain front

USGS Publications Warehouse

Sohn, M.F.; Mahan, S.A.; Knott, J.R.; Bowman, D.D.

2007-01-01

Controversy exists over whether alluvial-fan sedimentation along tectonically active mountain fronts is driven by climatic changes or tectonics. Knowing the age of sedimentation is the key to understanding the relationship between sedimentation and its cause. Alluvial-fan deposits in Death Valley and throughout the arid southwestern United States have long been the subjects of study, but their ages have generally eluded researchers until recently. Most mapping efforts have recognized at least four major relative-age groupings (Q1 (oldest), Q2, Q3, and Q4 (youngest)), using observed changes in surface soils and morphology, relation to the drainage net, and development of desert pavement. Obtaining numerical age determinations for these morphologic stages has proven challenging. We report the first optically stimulated luminescence (OSL) ages for three of these four stages deposited within alluvial-fans along the tectonically active Black Mountains of Death Valley. Deposits showing distinct, remnant bar and swale topography (Q3b) have OSL ages from 7 to 4 ka., whereas those with moderate to poorly developed desert pavement and located farther above the active channel (Q3a) have OSL ages from 17 to 11 ka. Geomorphically older deposits with well-developed desert pavement (Q2d) have OSL ages ???25 ka. Using this OSL-based chronology, we note that alluvial-fan deposition along this tectonically active mountain front corresponds to both wet-to-dry and dry-to-wet climate changes recorded globally and regionally. These findings underscore the influence of climate change on alluvial fan deposition in arid and semi-arid regions. ?? 2007 Elsevier Ltd and INQUA.

Simultaneous determination of thorium, niobium, lead, and zinc by photon-induced x-ray fluorescence of lateritic material

DOE Office of Scientific and Technical Information (OSTI.GOV)

LaBrecque, J.J.; Adames, D.; Parker, W.C.

1981-01-01

A rapid method is presented for the simultaneous determinations of thorium, niobium, lead, and zinc in lateritic material from Cerro Impacto, Estado Bolivar, Venezuela. This technique uses a PDP - 11/05 processor - based photon induced x-ray fluorescence system. The total variations of approximately 5% for concentrations of approximately 1 and 10% for concentrations of approximately 0.1% were obtained with only 500 s of fluorescent time. The values obtained by this method were in agreement with values measured by conventional flame atomic absorption spectroscopy for lead and zinc. The values for thorium measured were in agreement with the reported valuesmore » for the reference materials supplied by NBL.« less

Holocene loess deposition and soil formation as competing processes, Matanuska Valley, southern Alaska

USGS Publications Warehouse

Muhs, D.R.; McGeehin, J.P.; Beann, J.; Fisher, E.

2004-01-01

Although loess-paleosol sequences are among the most important records of Quaternary climate change and past dust deposition cycles, few modern examples of such sedimentation systems have been studied. Stratigraphic studies and 22 new accelerator mass spectrometry radiocarbon ages from the Matanuska Valley in southern Alaska show that loess deposition there began sometime after ???6500 14C yr B.P. and has continued to the present. The silts are produced through grinding by the Matanuska and Knik glaciers, deposited as outwash, entrained by strong winds, and redeposited as loess. Over a downwind distance of ???40 km, loess thickness, sand content, and sand-plus-coarse-silt content decrease, whereas fine-silt content increases. Loess deposition was episodic, as shown by the presence of paleosols, at distances >10 km from the outwash plain loess source. Stratigraphic complexity is at a maximum (i.e., the greatest number of loesses and paleosols) at intermediate (10-25 km) distances from the loess source. Surface soils increase in degree of development with distance downwind from the source, where sedimentation rates are lower. Proximal soils are Entisols or Inceptisols, whereas distal soils are Spodosols. Ratios of mobile CaO, K2O, and Fe2O3 to immobile TiO2 show decreases in surface horizons with distance from the source. Thus, as in China, where loess deposition also takes place today, eolian sedimentation and soil formation are competing processes. Study of loess and paleosols in southern Alaska shows that particle size can vary over short distances, loess deposition can be episodic over limited time intervals, and soils developed in stabilized loess can show considerable variability under the same vegetation. ?? 2004 University of Washington. All rights reserved.

Growth, intermixing, and surface phase formation for zinc tin oxide nanolaminates produced by atomic layer deposition

DOE Office of Scientific and Technical Information (OSTI.GOV)

Hägglund, Carl, E-mail: carl.hagglund@angstrom.uu.se; Grehl, Thomas; Brongersma, Hidde H.

2016-03-15

A broad and expanding range of materials can be produced by atomic layer deposition at relatively low temperatures, including both oxides and metals. For many applications of interest, however, it is desirable to grow more tailored and complex materials such as semiconductors with a certain doping, mixed oxides, and metallic alloys. How well such mixed materials can be accomplished with atomic layer deposition requires knowledge of the conditions under which the resulting films will be mixed, solid solutions, or laminated. The growth and lamination of zinc oxide and tin oxide is studied here by means of the extremely surface sensitivemore » technique of low energy ion scattering, combined with bulk composition and thickness determination, and x-ray diffraction. At the low temperatures used for deposition (150 °C), there is little evidence for atomic scale mixing even with the smallest possible bilayer period, and instead a morphology with small ZnO inclusions in a SnO{sub x} matrix is deduced. Postannealing of such laminates above 400 °C however produces a stable surface phase with a 30% increased density. From the surface stoichiometry, this is likely the inverted spinel of zinc stannate, Zn{sub 2}SnO{sub 4}. Annealing to 800 °C results in films containing crystalline Zn{sub 2}SnO{sub 4}, or multilayered films of crystalline ZnO, Zn{sub 2}SnO{sub 4}, and SnO{sub 2} phases, depending on the bilayer period.« less

Geomorphology and Geology of the Southwestern Margaritifer Sinus and Argyre Regions of Mars. Part 3: Valley Types and Distribution

NASA Technical Reports Server (NTRS)

Parker, T. J.; Pieri, D. C.

1985-01-01

Three major valley tapes were identified in the SW Margaritefer Sinus and Argyre regions. Two are restricted to specific geologic units while the third is independent of the geology. The first type (the small valley networks) are found within the channeled and subdued plains unit in the eastern half of the map, in the grooved and channeled plains unit north of Nirgal Vallis, and in scattered instances in the cratered plateau unit north of Argyre. The even smaller valleys just inside Argyre's rim and on the inner slopes of many large craters are not directly related to the processes which formed the small valleys but are a result, instead, of post-impact modification of the crater walls. The second type of valley network is represented by Nirgal Vallis and the similar, shorter continuation of it to the west. This type is found only in the smooth plains material west of Uzboi Vallis in the map area. The third type of valley network is that of the Uzbol-Holden-Ladon valles system. This system is related to catastrophic outflow from Argyre Basin and is topographically rather than geologically controlled.

Fabrication and Characterization of N-Type Zinc Oxide/P-Type Boron Doped Diamond Heterojunction

NASA Astrophysics Data System (ADS)

Marton, Marián; Mikolášek, Miroslav; Bruncko, Jaroslav; Novotný, Ivan; Ižák, Tibor; Vojs, Marian; Kozak, Halyna; Varga, Marián; Artemenko, Anna; Kromka, Alexander

2015-09-01

Diamond and ZnO are very promising wide-bandgap materials for electronic, photovoltaic and sensor applications because of their excellent electrical, optical, physical and electrochemical properties and biocompatibility. In this contribution we show that the combination of these two materials opens up the potential for fabrication of bipolar heterojunctions. Semiconducting boron doped diamond (BDD) thin films were grown on Si and UV grade silica glass substrates by HFCVD method with various boron concentration in the gas mixture. Doped zinc oxide (ZnO:Al, ZnO:Ge) thin layers were deposited by diode sputtering and pulsed lased deposition as the second semiconducting layer on the diamond films. The amount of dopants within the films was varied to obtain optimal semiconducting properties to form a bipolar p-n junction. Finally, different ZnO/BDD heterostructures were prepared and analyzed. Raman spectroscopy, SEM, Hall constant and I-V measurements were used to investigate the quality, structural and electrical properties of deposited heterostructures, respectively. I-V measurements of ZnO/BDD diodes show a rectifying ratio of 55 at ±4 V. We found that only very low dopant concentrations for both semiconducting materials enabled us to fabricate a functional p-n junction. Obtained results are promising for fabrication of optically transparent ZnO/BDD bipolar heterojunction.

From valley to marginal glaciation in alpine-type relief: Lateglacial glacier advances in the Pięć Stawów Polskich/Roztoka Valley, High Tatra Mountains, Poland

NASA Astrophysics Data System (ADS)

Zasadni, Jerzy; Kłapyta, Piotr

2016-01-01

The Pięć Stawów Polskich-Roztoka Valley in the High Tatras (Western Carpathians) features typical alpine-type relief with a deeply incised glacial trough and large, compound trough head cirque. The prominent hypsographic maximum in the valley (1680-2000 m) along with a broad cirque bottom had provided a vast space for recording glacial and periglacial landforms, specifically the most recent Lateglacial advances. The valley has been intensively studied before in the context of glacial chronology. In this paper, we re-establish the post-Last Glacial Maximum (LGM) glacial chronology of the valley via detailed geomorphologic mapping, equilibrium line altitude (ELA) reconstruction, and Schmidt hammer (SH) dating, along with a critical review of previously published cosmogenic exposure age data (36Cl) and lacustrine sediment chronology. Our results indicate that the first four of the five distinguished Lateglacial stages (Roztoka I-III, Pusta I) occurred before the Bølling/Allerød (B/A) interstadial; thus, virtually the entire valley became deglaciated in course of the Oldest Dryas cold phase. A distinct reorganization of deglacial patterns from valley-type to marginal-type occurred before B/A warming when the ELA increased above the valley hypsographic maximum concentrated at the cirque bottom elevation. It shows that noticeable deglaciation step can be caused due to topographic reason with a minimal climate forcing. This points also to an important role of glaciated valley hypsography in regulating the distribution of moraines which is rarely taken into account in paleoglaciological reconstructions. We infer that glaciers vanished in the Tatra Mountains during the B/A interstadial. Later, a renewed advance during the Younger Dryas (Pusta II) formed a nearly continuous, festoon shaped pattern of moraines and rock glaciers in close distance to cirque backwalls. Furthermore, we discus some paleoenvironmental significance of the geomorphological record in the valley

Interactions of dietary calcium with toxic levels of lead and zinc in pigs

DOE Office of Scientific and Technical Information (OSTI.GOV)

Hsu, F.A.; Krook, L.; Pond, W.G.

1975-01-01

Twenty-four weanling Yorkshire pigs were used in a 2 x 2 x 2 factorial arrangement of treatments to determine their response to high levels of dietary lead (Pb) (1000 ppm) and zinc (Zn) (4000 ppm) (as lead acetate and zinc oxide), to investigate the influence of high dietary calcium (Ca) (1.1%) on the biochemical and morphological manifestations of Pb and Zn toxicity, and to determine the effect of excess Zn on Pb toxicity. Clinical signs of Pb toxicity included behavioral changes, lameness, and anorexia. Pb content of blood, soft tissues, and bone was increased markedly by 1000 ppm Pb inmore » the diet during the 13-week experiment. Zn and Pb fed together, as compared with Pb alone, tended to increase Pb levels in blood, soft tissues, and bone and to enhance the toxic effects of Pb as shown by reduced weight gains, severe clinical signs, and pathological changes. High Ca reduced blood and bone Zn and Pb concentrations. The results indicate that high dietary Ca has a protective effect against the adverse effects of diet Pb and Zn, and that Zn aggravates Pb toxicity in growing pigs.« less

Lead in tissues of mallard ducks dosed with two types of lead shot

USGS Publications Warehouse

Finley, M.T.; Dieter, M.P.; Locke, L.N.

1976-01-01

Mallard ducks (Anas platyrhynchos) were sacrificed one month after ingesting one number 4 all-lead shot or one number 4 lead-iron shot. Livers, kidneys, blood, wingbones, and eggs were analyzed for lead by atomic absorption. Necropsy of sacrificed ducks failed to reveal any of the tissue lesions usually associated with lead poisoning in waterfowl. Lead levels in ducks given all-lead shot averaged about twice those in ducks given lead-iron shot, reflecting the amount of lead in the two types of shot. Lead in the blood of ducks dosed with all-lead shot averaged 0.64 ppm, and 0.28 ppm in ducks given lead-iron shot. Lead residues in livers and kidneys of females given all-lead shot were significantly higher than in males. In both dosed groups, lead levels in wingbones of females were about 10 times those in males, and were significantly correlated with the number of eggs laid after dosage. Lead levels in contents and shells of eggs laid by hens dosed with all-lead shot were about twice those in eggs laid by hens dosed with lead-iron shot. Eggshells were found to best reflect levels of lead in the blood. Our results indicate that mallards maintained on a balanced diet and dosed with one lead shot may not accumulate extremely high lead levels in the liver and kidney. However, extremely high lead deposition may result in the bone of laying hens after ingesting sublethal amounts of lead shot as a result of mobilization of calcium from the bone during eggshell formation.

[Improvement in zinc nutrition due to zinc transporter-targeting strategy].

PubMed

Kambe, Taiho

2016-07-01

Adequate intake of zinc from the daily diet is indispensable to maintain health. However, the dietary zinc content often fails to fulfill the recommended daily intake, leading to zinc deficiency and also increases the risk of developing chronic diseases, particularly in elderly individuals. Therefore, increased attention is required to overcome zinc deficiency and it is important to improve zinc nutrition in daily life. In the small intestine, the zinc transporter, ZIP4, functions as a component that is essential for zinc absorption. In this manuscript, we present a brief overview regarding zinc deficiency. Moreover, we review a novel strategy, called "ZIP4-targeting", which has the potential to enable efficient zinc absorption from the diet. ZIP4-targeting strategy is possibly a major step in preventing zinc deficiency and improving human health.

The Chemical Vapor Deposition of Thin Metal Oxide Films

NASA Astrophysics Data System (ADS)

Laurie, Angus Buchanan

1990-01-01

Chemical vapor deposition (CVD) is an important method of preparing thin films of materials. Copper (II) oxide is an important p-type semiconductor and a major component of high T_{rm c} superconducting oxides. By using a volatile copper (II) chelate precursor, copper (II) bishexafluoroacetylacetonate, it has been possible to prepare thin films of copper (II) oxide by low temperature normal pressure metalorganic chemical vapor deposition. In the metalorganic CVD (MOCVD) production of oxide thin films, oxygen gas saturated with water vapor has been used mainly to reduce residual carbon and fluorine content. This research has investigated the influence of water-saturated oxygen on the morphology of thin films of CuO produced by low temperature chemical vapor deposition onto quartz, magnesium oxide and cubic zirconia substrates. ZnO is a useful n-type semiconductor material and is commonly prepared by the MOCVD method using organometallic precursors such as dimethyl or diethylzinc. These compounds are difficult to handle under atmospheric conditions. In this research, thin polycrystalline films of zinc oxide were grown on a variety of substrates by normal pressure CVD using a zinc chelate complex with zinc(II) bishexafluoroacetylacetonate dihydrate (Zn(hfa)_2.2H _2O) as the zinc source. Zn(hfa) _2.2H_2O is not moisture - or air-sensitive and is thus more easily handled. By operating under reduced-pressure conditions (20-500 torr) it is possible to substantially reduce deposition times and improve film quality. This research has investigated the reduced-pressure CVD of thin films of CuO and ZnO. Sub-micron films of tin(IV) oxide (SnO _2) have been grown by normal pressure CVD on quartz substrates by using tetraphenyltin (TPT) as the source of tin. All CVD films were characterized by X-ray powder diffraction (XRPD), scanning electron microscopy (SEM) and electron probe microanalysis (EPMA).

Zinc Transport Differs in Rat Spermatogenic Cell Types and Is Affected by Treatment with Cyclophosphamide1

PubMed Central

Downey, Anne Marie; Hales, Barbara F.; Robaire, Bernard

2016-01-01

Adequate zinc levels are required for proper cellular functions and for male germ cell development. Zinc transport is accomplished by two families of zinc transporters, the ZIPs and the ZnTs, that increase and decrease cytosolic zinc levels, respectively. However, very little is known about zinc transport in the testis. Furthermore, whether cytotoxic agents such as cyclophosphamide (CPA), a known male germ cell toxicant, can affect zinc transport and homeostasis is unknown. We examined zinc transporter expression and zinc transport in pachytene spermatocytes (PS) and round spermatids (RS) in a normal state and after exposure to CPA. We observed differences in the expression of members of the ZnT and ZIP families in purified populations of PS and RS. We also observed that RS accumulate more zinc over time than PS. The expression of many zinc binding genes was altered after CPA treatment. Interestingly, we found that the expression levels of ZIP5 and ZIP14 were increased in PS from animals treated daily with 6 mg/kg CPA for 4 wk but not in RS. This up-regulation led to an increase in zinc uptake in PS but not in RS from treated animals compared to controls. These data suggest that CPA treatment may alter zinc homeostasis in male germ cells leading to an increased need for zinc. Altered zinc homeostasis may disrupt proper germ cell development and contribute to infertility and effects on progeny. PMID:27281708

The composition of fluid inclusions in ore and gangue minerals from the Silesian-Cracow Mississippi Valley-type Zn-Pb deposits Poland: Genetic and environmental implications

USGS Publications Warehouse

Viets, J.G.; Hofstra, A.H.; Emsbo, P.; Kozlowski, A.

1996-01-01

late minerals. The early fluids may have reacted primarily with Devonian and Lower Carboniferous carbonate aquifers deeper in the basin, whereas the later fluids appear to have had extensive contact with organic-rich rocks, probably the shallower Middle and Upper Carboniferous flysch associated with coal measures. High concentrations of toxic Tl and As occur in the readily oxidized marcasite and pyrite minerals deposited by the later fluids. In general, the geochemistry of both the early and late fluids may be explained by an evaporite related origin or by water-rock modification of a saline basinal brine. When compared to the composition of fluid inclusions in Mississippi Valley-type (MVT) ore minerals from the Ozark region of the United States, fluid inclusions in minerals from Silesian-Cracow are fundamentally different, containing more Ca2+, Mg2+, NH+4, Br-, Sr2+ and acetate in all mineral stages with significantly more K+ in later stage minerals. The differences in ore fluid chemistry between the two regions are consistent with the lithologic differences of the respective basins thought to be the source of the mineralizing brines.

Interrelationships among mediators of cellular zinc homeostasis in healthy and type 2 diabetes mellitus populations.

PubMed

Chu, Anna; Foster, Meika; Hancock, Dale; Petocz, Peter; Samman, Samir

2017-04-01

The involvement of zinc in multiple physiological systems requires tight control of cellular zinc concentration. This study aims to explore the relationships among selected mediators of cellular zinc homeostasis in an apparently healthy (AH) population and a cohort with type 2 diabetes mellitus (T2DM). Baseline data of three trials forming two cohorts, AH (n = 70) and T2DM (n = 42), were used for multivariate analyses to identify groupings within ten zinc transporter and metallothionein (MT) gene expressions, stratified by health status. Multiple regression models were used to explore relationships among zinc transporter/MT groupings and plasma zinc. Gene expression of zinc transporters and MTs, with the exception of ZnT6, were significantly lower in the T2DM cohort (p < 0.01). Cluster analysis showed that the groupings of zinc transporters and MTs were largely similar between the two cohorts, with the exception for ZnT1 and ZIP7. Zinc transporters and MTs were significant determinants of plasma zinc (r 2 = 0.48, p = 0.001) in the AH cohort, but not in the T2DM cohort. The current study suggests altered cellular zinc homeostasis in T2DM and supports the use of multiple zinc transporters and MTs groupings to further understand zinc homeostasis in health and T2DM. © 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Lead-isotopic, sulphur-isotopic, and trace-element studies of galena from the Silesian-Cracow Zn-Pb ores, polymetallic veins from the Gory Swietokrzyskie MTS, and the Myszkow porphyry copper deposit, Poland

USGS Publications Warehouse

Church, S.E.; Vaughn, R.B.; Gent, C.A.; Hopkins, R.T.

1996-01-01

Lead-isotopic data on galena samples collected from a paragenetically constrained suite of samples from the Silesian-Cracow ore district show no regional or paragenetically controlled lead-isotopic trends within the analytical reproducibility of the measurements. Furthermore, the new lead-isotopic data agree with previously reported lead-isotopic results (R. E. Zartman et al., 1979). Sulfur-isotopic analyses of ores from the Silesian-Cracow district as well as from vein ore from the Gory Swietokrzyskie Mts. and the Myszkow porphyry copper deposit, when coupled with trace-element data from the galena samples, clearly discriminate different hydrothermal ore-forming events. Lead-isotopic data from the Permian and Miocene evaporite deposits in Poland indicate that neither of these evaporite deposits were a source of metals for the Silesian-Cracow district ores. Furthermore, lead-isotopic data from these evaporite deposits and the shale residues from the Miocene halite samples indicate that the crustal evolution of lead in the central and western European platform in southern Poland followed normal crustal lead-isotopic growth, and that the isotopic composition of crustal lead had progressed beyond the lead-isotopic composition of lead in the Silesian-Cracow ores by Permian time. Thus, Mesozoic and Tertiary sedimentary flysch rocks can be eliminated as viable source rocks for the metals in the Silesian-Cracow Mississippi Valley-type (MVT) deposits. The uniformity of the isotopic composition of lead in the Silesian-Cracow ores, when coupled with the geologic evidence that mineralization must post-date Late Jurassic faulting (E. Gorecka, 1991), constrains the geochemical nature of the source region. The source of the metals is probably a well-mixed, multi-cycle molasse sequence of sedimentary rocks that contains little if any Precambrian metamorphic or granitic clasts (S. E. Church, R. B. Vaughn, 1992). If ore deposition was post Late Jurassic (about 150 m. y.) or later

Giant landslide deposits in northwest Argentina

DOE Office of Scientific and Technical Information (OSTI.GOV)

Fauque, L.; Strecker, M.R.; Bloom, A.L.

1985-01-01

Giant Quaternary landslide deposits occur along mountain fronts in the structural transition zone between the high-angle reverse-fault-bounded Sierras Pampeanas and the low-angle thrust belt of the Sierras Subandinas. There are two modes of occurrence: (1) chaotic masses without distinct geometry, and (2) masses with distinct lobate geometry similar to glacial moraines. Type (1) deposits occur where the moving rock mass followed a narrow valley and blocked the drainage. Many of these caused subsequent formation of lakes and changed the sedimentation processes on pediments at the mountain fronts. In type (2) deposits, lateral and frontal ridges are up to 10 mmore » higher than the interior parts; in some places pressure ridges within the lobes are well preserved. Type (2) deposits show reverse grading and were deposited on relatively smooth pediments or alluvial fans. The lobate geometry strongly suggests that type (2) deposits are a product of flowage and are debris stream or sturzstrom deposits (sense of Heim, 1932 and Hsu, 1975). All investigated deposits occur in areas of demonstrated Quaternary faulting and are interpreted as the result of tectonic movements, although structural inhomogeneities in the source area may have been a significant factor for some of the landslides. No datable materials have yet been found associated with the deposits.« less

Thin-Film Transistors Fabricated Using Sputter Deposition of Zinc Oxide

NASA Astrophysics Data System (ADS)

Xiao, Nan

2013-01-01

Development of thin film transistors (TFTs) with conventional channel layer materials, such as amorphous silicon (a-Si) and polysilicon (poly-Si), has been extensively investigated. A-Si TFT currently serves the large flat panel industry; however advanced display products are demanding better TFT performance because of the associated low electron mobility of a-Si. This has motivated interest in semiconducting metal oxides, such as Zinc Oxide (ZnO), for TFT backplanes. This work involves the fabrication and characterization of TFTs using ZnO deposited by sputtering. An overview of the process details and results from recently fabricated TFTs following a full-factorial designed experiment will be presented. Material characterization and analysis of electrical results will be described. The investigated process variables were the gate dielectric and ZnO sputtering process parameters including power density and oxygen partial pressure. Electrical results showed clear differences in treatment combinations, with certain I-V characteristics demonstrating superior performance to preliminary work. A study of device stability will also be discussed.

A new model for tabular-type uranium deposits

USGS Publications Warehouse

Sanford, R.F.

1992-01-01

Tabular-type uranium deposits occur as tabular, originally subhorizontal bodies entirely within reduced fluvial sandstones of Late Silurian age or younger. This paper proposes that belts of tabular-type uranium deposits formed in areas of mixed local and regional groundwater discharge shortly after deposition of the host sediments. The general characteristics of tabular-type uranium deposits indicate that their essential feature was the formation at a density-stratified ground-water interface in areas of local and regional ground-water discharge. Reconstruction of the paleohydrogeology is the key to understanding the formation of these deposits. Geologic ground-water controls that favor discharge, such as the pinch-out of major aquifers, are also favorable for uranium ore. The combination of topographic and geologic features that both cause discharge is most favorable for ore deposition. -from Author

Pliocene transpressional modification of depositional basins by convergent thrusting adjacent to the "Big Bend" of the San Andreas fault: An example from Lockwood Valley, southern California

USGS Publications Warehouse

Kellogg, K.S.; Minor, S.A.

2005-01-01

The "Big Bend" of the San Andreas fault in the western Transverse Ranges of southern California is a left stepping flexure in the dextral fault system and has long been recognized as a zone of relatively high transpression compared to adjacent regions. The Lockwood Valley region, just south of the Big Bend, underwent a profound change in early Pliocene time (???5 Ma) from basin deposition to contraction, accompanied by widespread folding and thrusting. This change followed the recently determined initiation of opening of the northern Gulf of California and movement along the southern San Andreas fault at about 6.1 Ma, with the concomitant formation of the Big Bend. Lockwood Valley occupies a 6-km-wide, fault-bounded structural basin in which converging blocks of Paleoproterozoic and Cretaceous crystalline basement and upper Oligocene and lower Miocene sedimentary rocks (Plush Ranch Formation) were thrust over Miocene and Pliocene basin-fill sedimentary rocks (in ascending order, Caliente Formation, Lockwood Clay, and Quatal Formation). All the pre-Quatal sedimentary rocks and most of the Pliocene Quatal Formation were deposited during a mid-Tertiary period of regional transtension in a crustal block that underwent little clockwise vertical-axis rotation as compared to crustal blocks to the south. Ensuing Pliocene and Quaternary transpression in the Big Bend region began during deposition of the poorly dated Quatal Formation and was marked by four converging thrust systems, which decreased the areal extent of the sedimentary basin and formed the present Lockwood Valley structural basin. None of the thrusts appears presently active. Estimated shortening across the center of the basin was about 30 percent. The fortnerly defined eastern Big Pine fault, now interpreted to be two separate, oppositely directed, contractional reverse or thrust faults, marks the northwestern structural boundary of Lockwood Valley. The complex geometry of the Lockwood Valley basin is similar

Trace metal depositional patterns from an open pit mining activity as revealed by archived avian gizzard contents.

PubMed

Bendell, L I

2011-02-15

Archived samples of blue grouse (Dendragapus obscurus) gizzard contents, inclusive of grit, collected yearly between 1959 and 1970 were analyzed for cadmium, lead, zinc, and copper content. Approximately halfway through the 12-year sampling period, an open-pit copper mine began activities, then ceased operations 2 years later. Thus the archived samples provided a unique opportunity to determine if avian gizzard contents, inclusive of grit, could reveal patterns in the anthropogenic deposition of trace metals associated with mining activities. Gizzard concentrations of cadmium and copper strongly coincided with the onset of opening and the closing of the pit mining activity. Gizzard zinc and lead demonstrated significant among year variation; however, maximum concentrations did not correlate to mining activity. The archived gizzard contents did provide a useful tool for documenting trends in metal depositional patterns related to an anthropogenic activity. Further, blue grouse ingesting grit particles during the time of active mining activity would have been exposed to toxicologically significant levels of cadmium. Gizzard lead concentrations were also of toxicological significance but not related to mining activity. This type of "pulse" toxic metal exposure as a consequence of open-pit mining activity would not necessarily have been revealed through a "snap-shot" of soil, plant or avian tissue trace metal analysis post-mining activity. Copyright © 2010 Elsevier B.V. All rights reserved.

Zinc, copper, and lead in mid-ocean ridge basalts and the source rock control on Zn/Pb in ocean-ridge hydrothermal deposits

USGS Publications Warehouse

Doe, B.R.

1994-01-01

The contents of Zn, Cu, and Pb in mid-ocean ridge basalts (MORB) and the MORB source-rock control on Zn/Pb in ocean-ridge hydrothermal deposits are examined. The values of Zn, Cu, and Pb for submarine mid-ocean ridge basalts (MORB) are, respectively (in ppm): average MORB-75, 75, and 0.7; West Valley, Juan de Fuca Ridge (JFR)-87, 64, and 0.5; southern JFR-120 and 0.5; and 21??N, East Pacific Rise (EPR)-73, 78, and 0.5. Values of Zn/Pb range from about 100-240 and Cu/ Pb from 100-156. In this study, Zn is found to correlate positively with TiO2 + FeO (mean square of weighted deviates, MSWD, of 1.6 for JFR basalt), and inversely with Mg number (MSWD of 3.5). Therefore, contrary to statements in the literature that Zn should be compatible in MORB, Zn is a mildly incompatible element and must be enriched in the glass phase relative to olivine as Zn does not fit into the other major phenocryst phase, plagioclase. In the source of MORB, Zn likely is most enriched in oxides: spinel, magnetite, and titanomagnetite. Copper generally does not correlate well with other elements in most MORB data examined. When differentiation is dominated by olivine, Cu has a tendency to behave incompatibly (e.g., at Mg numbers > 70), but, overall, Cu shows some tendency towards being a compatible element, particularly along the Mid-Atlantic Ridge, a behavior presumably due to separation of sulfides in which Cu (but not Zn) is markedly enriched. Copper thus may be in dispersed sulfides in the source of MORB. Ocean ridges provide important data on source-rock controls for sulfide deposits because, in sediment-starved ridges, much is known about the possible source rocks and mineralization is presently occurring. In contrast to Zn/Pb ~5 in continental hot Cl-rich brines, Zn/Pb in the hottest sediment-starved ridge black smoker hydrothermal fluids at 21 ??N, EPR is about 110, similar to local MORB (145), but Cu/Pb is closer to 30, possibly due to subsurface deposition of Cu. At the JFR, the best

Preliminary Metallogenic Map of North America; a listing of deposits by commodity

USGS Publications Warehouse

Lee, Michael P.; Guild, Philip White; Schruben, Paul G.

1987-01-01

The 4,215 ore deposits shown on the Preliminary Metallogenic Map of North America and contained in the Metallogenic Map file have been sorted by their principal (first-listed) commodities and grouped into metallic and nonmetallic categories. Deposit listings for 56 individual metals and minerals have been assembled using the data base and are arranged alphabetically by country, political subdivision (for the larger countries), and deposit name. Map numbers, major and minor constituents, geographic coordinates, and a geologic code are given for each deposit; additionally, the relative size and deposit class have been derived from the code and are listed separately. The frequencies of individual commodities and commodity groups by type, geographic distribution, and geologic occurrence are summarized in tables, and the relationships of associated commodities to principal commodities in the data base are emphasized in both tables and brief texts. In all, 49 metals and minerals are listed as principal (first or only) commodities and 7 more are shown as 'major' but not principal commodities. (Commodities listed as 'minor' in the data base were not sorted or tabulated separately.) Metals, divided into six subgroups, predominate over nonmetallic minerals by a ratio of about 7 to 1, although in terms of quantities and value the disparity is not so great. Within the metals group, the ranking according to frequency is as follows: base, precious, iron and alloying, other (antimony, beryllium, and others), nuclear-fuel, and light metals. The most frequently occurring commodity in the Metallogenic Map file is gold. Copper is ranked second, both in number of occurrences and as the principal commodity in deposits. Silver is ranked third in frequency of occurrence; lead and zinc are ranked fourth and fifth, respectively. Iron, ranked sixth in frequency of occurrence as a major commodity, is the third most reported principal commodity in the data base, ahead of silver (ranked fourth

Atmospheric lead deposition to Okefenokee Swamp, Georgia, USA

USGS Publications Warehouse

Jackson, B.P.; Winger, P.V.; Lasier, P.J.

2004-01-01

'Capsule:' Coal combustion emissions appear to be a major source of Pb in the Okefenokee wetland. Contamination of the environment from atmospheric deposition during the twentieth century is pervasive even in areas ostensibly considered pristine or remote from point sources. In this study, Pb concentrations in a Pb-210-dated peat core collected from the Okefenokee Swamp, GA were used to assess historical contaminant input via atmospheric deposition. Lead isotope ratios were determined by dynamic reaction cell ICP-MS (DRC-ICP-MS). Increases in Pb concentration occurred in the late nineteenth century and a marked rise in Pb concentrations pre-dated the widespread use of leaded gasoline within the US. The Pb-206/Pb-207 ratios of 1.19 during this period were consistent with coal combustion emissions. A later increase in Pb concentration, concurrent with a trend toward more radiogenic Pb-206/Pb-207 ratios in gasoline is consistent with an increased input of Pb from leaded gasoline emissions. However, it appears that coal combustion emissions remain a major source of Pb to the Okefenokee.

Eluted zinc ions stimulate osteoblast differentiation and mineralization in human dental pulp stem cells for bone tissue engineering.

PubMed

Yusa, Kazuyuki; Yamamoto, Osamu; Iino, Mitsuyoshi; Takano, Hiroshi; Fukuda, Masayuki; Qiao, Zhiwei; Sugiyama, Toshihiro

2016-11-01

Zinc is an essential element for proliferation, differentiation and survival in various cell types. In a previous study, we found that zinc ions released from zinc-modified titanium surfaces (eluted zinc ions; EZ) stimulate cell viability, osteoblast marker gene expression and calcium deposition in human bone marrow-derived mesenchymal cells (hBMCs). The aim of the present study was to investigate the effects of EZ on osteoblast differentiation among dental pulp stem cells (DPSCs) in vitro. In this study, we evaluated the effects of EZ on osteogenesis in DPSCs. Osteoblast and osteoclast marker gene expression was evaluated by real-time PCR. We also evaluated alkaline phosphatase (ALP) staining and calcium deposition. We found that EZ stimulated osteoblast marker gene (type I collagen, alkaline phosphatase (ALP), osteocalcin (OCN) and Runx2) expression, vascular endothelial growth factor A (VEGF-A), and TGF-beta signaling pathway-related gene expression after 7days of incubation. Osteoclastogenesis occurs in a receptor for activated nuclear-factor kappa B ligand (RANKL)/osteoprotegerin (OPG)-independent manner. Real-time PCR analysis revealed that EZ did not affect RANKL or OPG mRNA expression. It was also revealed that EZ induced alkaline phosphatase (ALP) staining and calcium deposition in DPSCs. Collectively, these results demonstrate the potential for clinical application to prospective treatment of bone diseases. Copyright © 2016 Elsevier Ltd. All rights reserved.

Correlation between the Severity and Type of Acne Lesions with Serum Zinc Levels in Patients with Acne Vulgaris

PubMed Central

Rostami Mogaddam, Majid; Safavi Ardabili, Nastaran; Soflaee, Maedeh

2014-01-01

Acne vulgaris is the most common cutaneous disorder affecting adolescents and young adults. Some studies have reported an association between serum zinc levels and acne vulgaris. We aimed to evaluate the serum zinc level in patients with acne vulgaris and compare it with healthy controls. One hundred patients with acne vulgaris and 100 healthy controls were referred to our clinic. Acne severity was classified according to Global Acne Grading System (GAGS). Atomic absorption spectrophotometry was used to measure serum zinc levels. Mean serum level of zinc in acne patients and controls was 81.31 ± 17.63 μg/dl and 82.63 ± 17.49 μg/dl, respectively. Although the mean serum zinc level was lower in acne group, it was not statistically significant (P = 0.598). There was a correlation between serum zinc levels with severity and type of acne lesions. The results of our study suggest that zinc levels may be related to the severity and type of acne lesions in patients with acne vulgaris. Relative decrease of serum zinc level in acne patients suggests a role for zinc in the pathogenesis of acne vulgaris. PMID:25157359

Correlation between the severity and type of acne lesions with serum zinc levels in patients with acne vulgaris.

PubMed

Rostami Mogaddam, Majid; Safavi Ardabili, Nastaran; Maleki, Nasrollah; Soflaee, Maedeh

2014-01-01

Acne vulgaris is the most common cutaneous disorder affecting adolescents and young adults. Some studies have reported an association between serum zinc levels and acne vulgaris. We aimed to evaluate the serum zinc level in patients with acne vulgaris and compare it with healthy controls. One hundred patients with acne vulgaris and 100 healthy controls were referred to our clinic. Acne severity was classified according to Global Acne Grading System (GAGS). Atomic absorption spectrophotometry was used to measure serum zinc levels. Mean serum level of zinc in acne patients and controls was 81.31 ± 17.63 μg/dl and 82.63 ± 17.49 μg/dl, respectively. Although the mean serum zinc level was lower in acne group, it was not statistically significant (P = 0.598). There was a correlation between serum zinc levels with severity and type of acne lesions. The results of our study suggest that zinc levels may be related to the severity and type of acne lesions in patients with acne vulgaris. Relative decrease of serum zinc level in acne patients suggests a role for zinc in the pathogenesis of acne vulgaris.

[Remediation Pb, Cd contaminated soil in lead-zinc mining areas by hydroxyapatite and potassium chloride composites].

PubMed

Wang, Li; Li, Yong-Hua; Ji, Yan-Fang; Yang, Lin-Sheng; Li, Hai-Rong; Zhang, Xiu-Wu; Yu, Jiang-Ping

2011-07-01

The composite agents containing potassium chloride (KCl) and Hydroxyapatite (HA) were used to remediate the lead and cadmium contaminated soil in Fenghuang lead-zinc mining-smelting areas, Hunan province. The objective of this study was to identify and evaluate the influence of Cl- to the fixing efficiency of Pb and Cd by HA. Two types of contaminated soil (HF-1, HF-2) were chosen and forty treatments were set by five different Hydroxyapatite (HA) dosages and four different Cl- dosages. The toxicity characteristic leaching procedure (TCLP) was used to evaluate the results. It showed that HA could efficiently fix the Pb and Cd from TCLP form. The maximum Pb-fixing efficiency and Cd-fixing efficiency of two types of soil were 83.3%, 97.27% and 35.96%, 57.82% when the HA: Pb: KCl molar ratio was 8: 1: 2. Compared to the fixing efficiency without KCl, KCl at the KCl: Pb molar ratio of 2 improved Pb-fixing efficiency and Cd-fixing efficiency by 6.26%, 0.33% and 7.74%, 0.83% respectively when the HA: Pb molar ratio was 8. Generally, Cl- can improve the Pb/Cd-fixing efficiency in heavy metal contaminated soil by Hydroxyapatite.

Enhanced Detection of Sub-Retinal Pigment Epithelial Cell Layer Deposits in Human and Murine Tissue: Imaging Zinc as a Biomarker for Age-Related Macular Degeneration (An American Ophthalmological Society Thesis).

PubMed

van Kuijk, Frederik J G M; McPherson, Scott W; Roehrich, Heidi

2017-08-01

Understanding the apparent paradoxical role of zinc in the pathogenesis and prevention of age-related macular degeneration (AMD) has been limited by the lack of animal models for its detection in sub-retinal epithelial deposits (drusen), a definitive early hallmark of AMD. In-vitro studies using Zinpyr-1 showed drusen contained high levels of zinc, but the probe was not suitable for in-vivo studies. This study compares Zinpyr-1 to ZPP1, a new fluorescein-based probe for zinc, to assess the potential of ZPP1 for in-vivo detection of zinc in drusen. Flat mounts of human sub-RPE tissue using the probes were analyzed by fluorescence and confocal microscopy. Flat mounts of sub-RPE tissue from mice deficient in superoxide dismutase isoform-1 (CuZn-SOD-KO) or isoform-2 (Mn-SOD-RPE-KO) were analyzed with sub-RPE deposits confirmed by histology. Drusen are detected in greater numbers and intensity with ZPP1 compared to Zinpyr-1. Using ZPP1, drusen was detected in a sample from a 46-year old human donor without ocular history, suggesting that ZPP1 might be sensitive enough to detect drusen at an early stage. With CuZn-SOD KO mice, ZPP1 detected sub-RPE deposits at 10 months of age, whereas Zinpyr-1 required 14 months. Detection of sub-RPE deposits by ZPP1 was greatly enhanced compared to Zinpyr-1. This enhanced sensitivity will allow for more insightful analysis of zinc in AMD using human specimens and mouse models. This could result in the development of a sensitive in-vivo probe to enhance research on the role zinc in drusen formation and the early clinical diagnosis of AMD.

Enhanced Detection of Sub-Retinal Pigment Epithelial Cell Layer Deposits in Human and Murine Tissue: Imaging Zinc as a Biomarker for Age-Related Macular Degeneration (An American Ophthalmological Society Thesis)

PubMed Central

van Kuijk, Frederik J.G.M.; McPherson, Scott W.; Roehrich, Heidi

2017-01-01

Purpose Understanding the apparent paradoxical role of zinc in the pathogenesis and prevention of age-related macular degeneration (AMD) has been limited by the lack of animal models for its detection in sub-retinal epithelial deposits (drusen), a definitive early hallmark of AMD. In-vitro studies using Zinpyr-1 showed drusen contained high levels of zinc, but the probe was not suitable for in-vivo studies. This study compares Zinpyr-1 to ZPP1, a new fluorescein-based probe for zinc, to assess the potential of ZPP1 for in-vivo detection of zinc in drusen. Methods Flat mounts of human sub-RPE tissue using the probes were analyzed by fluorescence and confocal microscopy. Flat mounts of sub-RPE tissue from mice deficient in superoxide dismutase isoform-1 (CuZn-SOD-KO) or isoform-2 (Mn-SOD-RPE-KO) were analyzed with sub-RPE deposits confirmed by histology. Results Drusen are detected in greater numbers and intensity with ZPP1 compared to Zinpyr-1. Using ZPP1, drusen was detected in a sample from a 46-year old human donor without ocular history, suggesting that ZPP1 might be sensitive enough to detect drusen at an early stage. With CuZn-SOD KO mice, ZPP1 detected sub-RPE deposits at 10 months of age, whereas Zinpyr-1 required 14 months. Conclusion Detection of sub-RPE deposits by ZPP1 was greatly enhanced compared to Zinpyr-1. This enhanced sensitivity will allow for more insightful analysis of zinc in AMD using human specimens and mouse models. This could result in the development of a sensitive in-vivo probe to enhance research on the role zinc in drusen formation and the early clinical diagnosis of AMD. PMID:29021717

AVIRIS study of Death Valley evaporite deposits using least-squares band-fitting methods

NASA Technical Reports Server (NTRS)

Crowley, J. K.; Clark, R. N.

1992-01-01

Minerals found in playa evaporite deposits reflect the chemically diverse origins of ground waters in arid regions. Recently, it was discovered that many playa minerals exhibit diagnostic visible and near-infrared (0.4-2.5 micron) absorption bands that provide a remote sensing basis for observing important compositional details of desert ground water systems. The study of such systems is relevant to understanding solute acquisition, transport, and fractionation processes that are active in the subsurface. Observations of playa evaporites may also be useful for monitoring the hydrologic response of desert basins to changing climatic conditions on regional and global scales. Ongoing work using Airborne Visible/Infrared Imaging Spectrometer (AVIRIS) data to map evaporite minerals in the Death Valley salt pan is described. The AVIRIS data point to differences in inflow water chemistry in different parts of the Death Valley playa system and have led to the discovery of at least two new North American mineral occurrences. Seven segments of AVIRIS data were acquired over Death Valley on 31 July 1990, and were calibrated to reflectance by using the spectrum of a uniform area of alluvium near the salt pan. The calibrated data were subsequently analyzed by using least-squares spectral band-fitting methods, first described by Clark and others. In the band-fitting procedure, AVIRIS spectra are fit compared over selected wavelength intervals to a series of library reference spectra. Output images showing the degree of fit, band depth, and fit times the band depth are generated for each reference spectrum. The reference spectra used in the study included laboratory data for 35 pure evaporite spectra extracted from the AVIRIS image cube. Additional details of the band-fitting technique are provided by Clark and others elsewhere in this volume.

Holocene hillslope processes and deposits in two U-shaped mountain valleys in western Norway

NASA Astrophysics Data System (ADS)

Laute, K.; Beylich, A. A.

2012-04-01

.g. installed nets for collecting freshly accumulated rockfall debris, continuous photo-monitoring of rapid mass movement events (avalanches, slush- and debris flows) as well as installed temperature loggers both in rock walls and talus slopes for analysing rock temperatures and mechanical weathering is applied at selected hillslope test sites within the two valley systems. The overall tendency of landscape development is a Postglacial modification of the defined U-shaped valley morphometry (valley widening) throughout rockwall retreat and connected accumulation of debris material beneath these rockwalls. Active fluvial material removal at the base of slopes is almost negligible due to a very limited hillslope-channel coupling in both valleys. Results regarding the spatio-temporal variability of Holocene hillslope development show Holocene rockwall retreat rates for the two valleys which are in a comparable range with other estimates of rockwall retreat rates in other cold mountain environments worldwide. Further on the findings indicate probably higher accumulation rates of slope deposits mainly throughout an enhanced rockfall activity shortly after the glacier retreat as compared to subrecent and contemporary rates. Within the LIA period a recognizable modification of hillslopes in proximity to the outlet glaciers of the Jostedalsbreen is noticeable. A more complex hillslope morphometry (steepening of lower hillslope segments) as well as a more complex composition (inherited by a combination of debris from gravitational processes and lateral moraine ridges) of loose material generating a higher intensity of currently acting slope processes within the hillslope systems located inside of the LIA glacial advance limit as compared to hillslopes situated outside of this limit is found.

Characteristics of zinc oxide nanorod array/titanium oxide film heterojunction prepared by aqueous solution deposition

NASA Astrophysics Data System (ADS)

Lee, Ming-Kwei; Hong, Min-Hsuan; Li, Bo-Wei

2016-07-01

The characteristics of a ZnO nanorod array/TiO2 film heterojunction were investigated. A TiO2 film was prepared on glass by aqueous solution deposition with precursors of ammonium hexafluorotitanate and boric acid at 40 °C. Then, a ZnO seed layer was prepared on a TiO2 film/glass substrate by RF sputtering. A vertically oriented ZnO nanorod array was grown on a ZnO seed layer/TiO2 film/glass substrate by aqueous solution deposition with precursors of zinc nitrate and hexamethylenetetramine (HMT) at 70 °C. After thermal annealing in N2O ambient at 300 °C, this heterojunction used as an oxygen gas sensor shows much better rise time, decay time, and on/off current ratio than as-grown and annealed ZnO nanorods.

Review of Lead-Zinc Mining Impact on Landscape in the Tri-State Mining District using Small Unmanned Aerial Vehicles.

NASA Astrophysics Data System (ADS)

Bhakta, K. D.; Yeboah-Forson, A.

2015-12-01

The Tri-State lead and zinc mining district in SW Missouri, SE Kansas, and NE Oklahoma encompasses nearly 2,500 sq. miles of land and at its peak accounted for half of the US zinc (23,000,000 tons) production that surpassed one billion dollars in economic value. Once these lead and zinc rich ores were extracted, mining and milling sites were abandoned leaving behind a new landscape with numerous environmental challenges. Since 1970, most of the sites have been targeted for remediation and reclamation by federal and state agencies including the EPA. In order to capture the full extent of the impact of lead and zinc mining in the Tri-State area, numerous geoscientific approaches including data from small unmanned aerial vehicle (UAV) were employed to investigate the influence of mining in the study area. The study presented here is focused on observational assessment of the existing landscape using multiple commercial high-definitions data from UAVs to study different sites across areas of concern in the three states. Primary results (images) gathered and analyzed DEM and GIS data from abandoned mines showed the potential to provide a quick snapshot of successful or unsuccessful remediated areas. Although research and remediation of the Tri-State mining district are a continuous process, evidence from this geomorphic study suggest that UAVs can provide a quick overview of the remediated landscape or serve as a primary background tool for a more detail site-specific environmental study.

Origine du soufre associé aux minéralisations Pb-Zn de type Mississippi Valley de la chaîne des Beni Snassen orientaux (Maroc nord-oriental)

NASA Astrophysics Data System (ADS)

Bouabdellah, Mohammed; Boudchiche, Lahbib; Ouahhabi, Benali; Naciri, Tayeb

2008-12-01

Sulfur isotope data measured on samples of galena from the main Mississippi Valley-type prospects of the eastern Beni Snassen belt preclude an igneous source for sulfur, pointing instead to a sedimentary source. Negative δ 34S values are interpreted to being derived from bacteriogenic reduction of Jurassic seawater sulphate. Positive δ 34S values are considered to be hydrothermal sulfide transported with metal-bearing fluid. Mixing of these two fluids resulted in the deposition of the Pb ore.

Interactions among forest age, valley and channel morphology, and log jams regulate animal production in mountain streams

NASA Astrophysics Data System (ADS)

Walters, D. M.; Venarsky, M. P.; Hall, R. O., Jr.; Herdrich, A.; Livers, B.; Winkelman, D.; Wohl, E.

2014-12-01

Forest age and local valley morphometry strongly influence the form and function of mountain streams in Colorado. Streams in valleys with old growth forest (>350 years) have extensive log jam complexes that create multi-thread channel reaches with extensive pool habitat and large depositional areas. Streams in younger unmanaged forests (e.g., 120 years old) and intensively managed forests have much fewer log jams and lower wood loads. These are single-thread streams dominated by riffles and with little depositional habitat. We hypothesized that log jam streams would retain more organic matter and have higher metabolism, leading to greater production of stream macroinvertebrates and trout. Log jam reaches should also have greater emergence of adult aquatic insects, and consequently have higher densities of riparian spiders taking advantage of these prey. Surficial organic matter was 3-fold higher in old-growth streams, and these streams had much higher ecosystem respiration. Insect production (g m2 y-1) was similar among forest types, but fish density was four times higher in old-growth streams with copious log jams. However, at the valley scale, insect production (g m-1 valley-1) and trout density (number m-1 valley-1) was 2-fold and 10-fold higher, respectively, in old growth streams. This finding is because multi-thread reaches created by log jams have much greater stream area and stream length per meter of valley than single-thread channels. The more limited response of macroinvertebrates may be related to fish predation. Trout in old growth streams had similar growth rates and higher fat content than fish in other streams in spite of occurring at higher densities and higher elevation/colder temperatures. This suggests that the positive fish effect observed in old growth streams is related to greater availability of invertebrate prey, which is consistent with our original hypothesis. Preliminary analyses suggest that spider densities do not respond strongly to

Structure evolution of zinc oxide thin films deposited by unbalance DC magnetron sputtering

DOE Office of Scientific and Technical Information (OSTI.GOV)

Aryanto, Didik, E-mail: didi027@lipi.go.id; Materials Research Group, Physics Department, Universitas Negeri Semarang, Gunungpati, Semarang 50229 Jawa Tengah; Marwoto, Putut

Zinc oxide (ZnO) thin films are deposited on corning glass substrates using unbalanced DC magnetron sputtering. The effect of growth temperature on surface morphology and crystallographic orientation of ZnO thin film is studied using atomic force microscopy (AFM) and X-ray diffraction (XRD) techniques. The surface morphology and crystallographic orientation of ZnO thin film are transformed against the increasing of growth temperature. The mean grain size of film and the surface roughness are inversely and directly proportional towards the growth temperature from room temperature to 300 °C, respectively. The smaller grain size and finer roughness of ZnO thin film are obtainedmore » at growth temperature of 400 °C. The result of AFM analysis is in good agreement with the result of XRD analysis. ZnO thin films deposited in a series of growth temperatures have hexagonal wurtzite polycrystalline structures and they exhibit transformations in the crystallographic orientation. The results in this study reveal that the growth temperature strongly influences the surface morphology and crystallographic orientation of ZnO thin film.« less

Quantitative estimation of dust fall and smoke particles in Quetta Valley*

PubMed Central

Sami, Muhammad; Waseem, Amir; Akbar, Sher

2006-01-01

Tightening of air quality standards for populated urban areas has led to increasing attention to assessment of air quality management areas, where violation of air quality standards occurs, and development of control strategies to eliminate such violation of air quality standards. The Quetta urban area is very densely built and has heavy motorized traffic. The increase of emissions mainly from traffic and industry are responsible for the increase in atmospheric pollution levels during the last years. The dust examined in the current study was collected by both deposit gauge and Petri dish methods at various sites of Quetta Valley. Smoke particles were obtained by bladder method from the exhausts of various types of motor vehicles. The concentration of lead found in the smoke ranged from 1.5×10−6 to 4.5×10−6. PMID:16773727

Zinc-ion implanted and deposited titanium surfaces reduce adhesion of Streptococccus mutans

NASA Astrophysics Data System (ADS)

Xu, Juan; Ding, Gang; Li, Jinlu; Yang, Shenhui; Fang, Bisong; Sun, Hongchen; Zhou, Yanmin

2010-10-01

While titanium (Ti) is a commonly used dental implant material with advantageous biocompatible and mechanical properties, native Ti surfaces do not have the ability to prevent bacterial colonization. The objective of this study was to evaluate the chemical composition and bacterial adhesive properties of zinc (Zn) ion implanted and deposited Ti surfaces (Zn-PIIID-Ti) as potential dental implant materials. Surfaces of pure Ti (cp-Ti) were modified with increasing concentrations of Zn using plasma immersion ion implantation and deposition (PIIID), and elemental surface compositions were characterized by X-ray photoelectron spectrometry (XPS). To evaluate bacterial responses, Streptococcus mutans were seeded onto the modifiedTi surfaces for 48 h and subsequently observed by scanning electron microscopy. Relative numbers of bacteria on each surface were assessed by collecting the adhered bacteria, reculturing and counting colony forming units after 48 h on bacterial grade plates. Ti, oxygen and carbon elements were detected on all surfaces by XPS. Increased Zn signals were detected on Zn-PIIID-Ti surfaces, correlating with an increase of Zn-deposition time. Substantial numbers of S. mutans adhered to cp-Ti samples, whereas bacterial adhesion on Zn-PIIID-Ti surfaces signficantly decreased as the Zn concentration increased ( p < 0.01). In conclusion, PIIID can successfully introduce Zn onto a Ti surface, forming a modified surface layer bearing Zn ions that consequently deter adhesion of S. mutans, a common bacterium in the oral environment.

Zinc Signals and Immunity.

PubMed

Maywald, Martina; Wessels, Inga; Rink, Lothar

2017-10-24

Zinc homeostasis is crucial for an adequate function of the immune system. Zinc deficiency as well as zinc excess result in severe disturbances in immune cell numbers and activities, which can result in increased susceptibility to infections and development of especially inflammatory diseases. This review focuses on the role of zinc in regulating intracellular signaling pathways in innate as well as adaptive immune cells. Main underlying molecular mechanisms and targets affected by altered zinc homeostasis, including kinases, caspases, phosphatases, and phosphodiesterases, will be highlighted in this article. In addition, the interplay of zinc homeostasis and the redox metabolism in affecting intracellular signaling will be emphasized. Key signaling pathways will be described in detail for the different cell types of the immune system. In this, effects of fast zinc flux, taking place within a few seconds to minutes will be distinguish from slower types of zinc signals, also designated as "zinc waves", and late homeostatic zinc signals regarding prolonged changes in intracellular zinc.

Zinc Signals and Immunity

PubMed Central

Maywald, Martina; Wessels, Inga; Rink, Lothar

2017-01-01

Zinc homeostasis is crucial for an adequate function of the immune system. Zinc deficiency as well as zinc excess result in severe disturbances in immune cell numbers and activities, which can result in increased susceptibility to infections and development of especially inflammatory diseases. This review focuses on the role of zinc in regulating intracellular signaling pathways in innate as well as adaptive immune cells. Main underlying molecular mechanisms and targets affected by altered zinc homeostasis, including kinases, caspases, phosphatases, and phosphodiesterases, will be highlighted in this article. In addition, the interplay of zinc homeostasis and the redox metabolism in affecting intracellular signaling will be emphasized. Key signaling pathways will be described in detail for the different cell types of the immune system. In this, effects of fast zinc flux, taking place within a few seconds to minutes will be distinguish from slower types of zinc signals, also designated as “zinc waves”, and late homeostatic zinc signals regarding prolonged changes in intracellular zinc. PMID:29064429

Dry atmospheric deposition rates of metals along a coastal transect in southern California

NASA Astrophysics Data System (ADS)

Sabin, Lisa D.; Schiff, Kenneth C.

While recent studies indicate atmospheric deposition is a significant source of metals to the Santa Monica Bay and coastal river systems of the Los Angeles area, the spatial extent of the atmospheric source along the entire southern California coast has not been measured in 30 years. This study provides measurements of dry atmospheric deposition of chromium, copper, lead, nickel and zinc at eight sites located along the coast between Santa Barbara and San Diego, and compares these data to historic measurements from the 1970s. Median dry deposition fluxes across sites ranged between 0.23 and 3.6 (chromium), 0.21 and 5.4 (nickel), 0.52 and 14 (lead), 0.89 and 29 (copper), and 4.8 and 160 (zinc) μg m -2 day -1. Differences in metal dry deposition rates observed between sites were dominated by proximity to urban areas and/or other nearby sources, with the highest metal fluxes observed near the Los Angeles Harbor (LAH) and San Diego Bay (SDB) sites. Compared with data from the 1970s, lead fluxes were typically one to two orders of magnitude lower in the present study (2006), indicating atmospheric sources of this metal have decreased over the past three decades in southern California. Chromium fluxes were also lower in 2006 compared with the 1970s, although to a lesser extent than for lead. In contrast, copper and zinc fluxes were typically within the same order of magnitude between the two time periods, with some higher measurements observed in 2006 compared with the 1970s at the LAH and SDB sites. This result indicates atmospheric sources of copper and zinc have not decreased over the past three decades in southern California, and have increased near our harbor/urban sites. Differences in sampling conditions (e.g., Santa Ana winds) and measurement techniques may also explain, in part, the differences observed in metal flux rates for these time periods. However, these limitations were most important for those metals with the smallest difference in flux rates measured

Evolution of Zinc Oxide Nanostructures from Non-Equilibrium Deposition Conditions

DTIC Science & Technology

2016-07-11

pressure and temperature in the chamber by a rough estimation using PV = nRT. The deposition area is the internal surface of the tubular chamber, D...J. Wang, L. Zhang, T.L. Andrew, M.S. Arnold, X.D. Wang “Development of Lead Iodide Perovskite Solar Cells Using Three-Dimensional Titanium Dioxide...Andrew, M.S. Arnold, X.D. Wang "Development of Lead Iodide Perovskite Solar Cells Using Three-Dimensional Titanium Dioxide Nanowire Architectures" ACS

Orbital and Rover-based Exploration of Perseverance Valley, Endeavour Crater, Mars

NASA Astrophysics Data System (ADS)

Morgan, A. M.; Arvidson, R. E.; Duran Vinent, O.; Craddock, R. A.; Holo, S.; Gadal, C.; Blois, G.; Palucis, M. C.; Goudge, T. A.; Morgan, A. M.; Day, M.; Sullivan, R. J., Jr.; Umurhan, O. M.; Pähtz, T.; Birch, S.; Morgan, A. M.; Goudge, T. A.; Palucis, M. C.; Arvidson, R. E.; Duran Vinent, O.; Craddock, R. A.; Holo, S.; Blois, G.; Gadal, C.; Morgan, A. M.; Sullivan, R. J., Jr.; Day, M.; Arvidson, R. E.

2017-12-01

Perseverance Valley, based on orbital observations from the Mars Reconnaisance Orbiter HiRISE image data, is a 180 m long, 20 m wide anastomosing shallow channel system superimposed on the Cape Byron rim segment of the 22 km diameter Noachian-age Endeavour Crater on Mars. Several impact craters are superimposed on the valley system, indicating antiquity, although the valley's high degree of preservation indicates that it formed after significant regional-scale fluvial erosion and diffusive smoothing of Endeavour and its rim segments. The valley cuts into the inner, eastern rim on a 10˚ to 15˚ slope, and starts at a local low area on the rim crest. A set of shallow channels, some lined with perimeter rocks, extends from the west to meet the entrance to the valley. The western rim tilts to the west 0.8˚ and thus the channels tilt away from the valley entrance. The Mars Rover Opportunity has explored the western shallow channels leading up to the entrance to the valley. As of this writing Opportunity is located on the southern side of the valley entrance, with the Athena Science Team waiting until after solar conjunction to command the rover to descend into the valley to search for geomorphic and sedimentologic evidence related to valley formation. Wind erosion along radial fractures extending into and down Cape Byron is a possibility. Debris flows are also under consideration, perhaps enabled by melting ice at the rim crest. Dry avalanches are unlikely due to the low slopes. A fluvial origin is a strong contender based on models that show it is possible to have had a western catchment present when the Burns formation hydrated sulfates were being emplaced, followed by self-compaction of these sediments that tilted the western plains away from the rim crest. The key to testing among the various hypotheses for formation of the valley and shallow channels leading into the entrance will be the detailed stereo and multispectral imaging observations Opportunity will make

Critical rate of electrolyte circulation for preventing zinc dendrite formation in a zinc-bromine redox flow battery

NASA Astrophysics Data System (ADS)

Yang, Hyeon Sun; Park, Jong Ho; Ra, Ho Won; Jin, Chang-Soo; Yang, Jung Hoon

2016-09-01

In a zinc-bromine redox flow battery, a nonaqueous and dense polybromide phase formed because of bromide oxidation in the positive electrolyte during charging. This formation led to complicated two-phase flow on the electrode surface. The polybromide and aqueous phases led to different kinetics of the Br/Br- redox reaction; poor mixing of the two phases caused uneven redox kinetics on the electrode surface. As the Br/Br- redox reaction was coupled with the zinc deposition reaction, the uneven redox reaction on the positive electrode was accompanied by nonuniform zinc deposition and zinc dendrite formation, which degraded battery stability. A single-flow cell was operated at varying electrolyte circulation rates and current densities. Zinc dendrite formation was observed after cell disassembly following charge-discharge testing. In addition, the flow behavior in the positive compartment was observed by using a transparent version of the cell. At low rate of electrolyte circulation, the polybromide phase clearly separated from the aqueous phase and accumulated at the bottom of the flow frame. In the corresponding area on the negative electrode, a large amount of zinc dendrites was observed after charge-discharge testing. Therefore, a minimum circulation rate should be considered to avoid poor mixing of the positive electrolyte.

Concentrations and sources of cadmium, copper, lead and zinc in house dust in Christchurch, New Zealand.

PubMed

Kim, N; Fergusson, J

1993-09-30

The amounts (microgram m-2) and concentrations (microgram g-1) of cadmium, copper, lead and zinc have been measured in house dust in Christchurch, New Zealand. For 120 houses surveyed the geometric mean concentrations of the four metals are 4.24 micrograms g-1, 165 micrograms g-1, 573 micrograms g-1 and 10,400 micrograms g-1, respectively. In addition eleven variables, such as house age, carpet wear and traffic density, were recorded for each property and the results analysed with respect to their effects on the amounts and concentrations of the four elements. The amounts of all the metals were highly correlated with the overall dustiness of the houses, which was found to be predominantly determined by the degree of carpet wear. No one dominant source of cadmium was identified, although several minor sources including carpet wear, galvanized iron roofs and red/orange/yellow coloured carpets were implicated. Petrol lead and lead-based paints were identified as significant sources of lead in house dust. Rubber carpet underlays or backings were identified as a significant source of zinc, with some contribution from galvanized iron roofs. Road traffic and probably the existence of a fire place appear to contribute to the copper levels.

Aeromagnetic survey map of Sacramento Valley, California

USGS Publications Warehouse

Langenheim, Victoria E.

2015-01-01

Three aeromagnetic surveys were flown to improve understanding of the geology and structure in the Sacramento Valley. The resulting data serve as a basis for geophysical interpretations, and support geological mapping, water and mineral resource investigations, and other topical studies. Local spatial variations in the Earth's magnetic field (evident as anomalies on aeromagnetic maps) reflect the distribution of magnetic minerals, primarily magnetite, in the underlying rocks. In many cases the volume content of magnetic minerals can be related to rock type, and abrupt spatial changes in the amount of magnetic minerals commonly mark lithologic or structural boundaries. Bodies of serpentinite and other mafic and ultramafic rocks tend to produce the most intense positive magnetic anomalies (for example, in the northwest part of the map). These rock types are the inferred sources, concealed beneath weakly magnetic, valley-fill deposits, of the most prominent magnetic features in the map area, the magnetic highs that extend along the valley axis. Cenozoic volcanic rocks are also an important source of magnetic anomalies and coincide with short-wavelength anomalies that can be either positive (strong central positive anomaly flanked by lower-amplitude negative anomalies) or negative (strong central negative anomaly flanked by lower-amplitude positive anomalies), reflecting the contribution of remanent magnetization. Rocks with more felsic compositions or even some sedimentary units also can cause measurable magnetic anomalies. For example, the long, linear, narrow north-trending anomalies (with amplitudes of <50 nanoteslas [nT]) along the western margin of the valley coincide with exposures of the Mesozoic Great Valley sequence. Note that isolated, short-wavelength anomalies, such as those in the city of Sacramento and along some of the major roads, are caused by manmade features.

Sputter deposition of indium tin oxide onto zinc pthalocyanine: Chemical and electronic properties of the interface studied by photoelectron spectroscopy

NASA Astrophysics Data System (ADS)

Gassmann, Jürgen; Brötz, Joachim; Klein, Andreas

2012-02-01

The interface chemistry and the energy band alignment at the interface formed during sputter deposition of transparent conducting indium tin oxide (ITO) onto the organic semiconductor zinc phtalocyanine (ZnPc), which is important for inverted, transparent, and stacked organic light emitting diodes, is studied by in situ photoelectron spectroscopy (XPS and UPS). ITO was sputtered at room temperature and a low power density with a face to face arrangement of the target and substrate. With these deposition conditions, no chemical reaction and a low barrier height for charge injection at this interface are observed. The barrier height is comparable to those observed for the reverse deposition sequence, which also confirms the absence of sputter damage.

Valley-fill sequences and onlap geometries, Lower Cretaceous Muddy Sandstone, Kitty Field, Powder River basin, Wyoming

DOE Office of Scientific and Technical Information (OSTI.GOV)

Gardner, M.H.; Gustason, E.R.

1987-05-01

The Muddy Sandstone at Kitty field is a valley-fill sequence that records a late Albian sea level rise and accompanying transgression. The valley was cut during a preceding sea level lowstand. Stratal geometries and facies successions within the valley fill demonstrate the history of transgression was not gradual and progressive. Rather, the valley fill comprises a series of discrete, time-bounded, depositional units which onlap the erosional surface. Five time-bounded depositional units were defined by facies successions and were used to define onlap geometries. Facies successions within individual units record progressive shoaling. Capping each succession, there may be a planar disconformity,more » a thin bioturbated interval, or the deepest water facies of the next depositional event. Thus, the termination of each depositional event is marked by an episode of rapid deepening. At a single geographic location, stratal successions within older depositional units represent more landward facies than those within younger units. Therefore, the onlap geometry of the valley-fill sequence consists of a landward-stepping arrangement of depositional units. The primary reservoirs within the valley-fill sequence, at Kitty field, are laterally coalesced, channel-belt sandstones at the base and barrier island sandstones at the top. Reservoir sandstones of lesser quality occur within the intermediate estuarine facies. The stacking pattern, developed by onlap of the units, results in multiple pay zones within mid-valley reaches. The boundaries of each depositional unit define a high-resolution, chronostratigraphic correlation of valley-fill strata, a correlation corroborated by bentonites. This correlation method gives an accurate description of the internal geometry of valley-fill strata and, therefore, provides a basis for understanding the process of transgressive onlap.« less

Histopathology of mallards dosed with lead and selected substitute shot

USGS Publications Warehouse

Locke, L.N.; Irby, H.D.; Bagley, George E.

1967-01-01

The histopathological response of male game farm mallards fed lead, three types of plastic-coated lead, two lead-magnesium alloys, iron, copper, zinc-coated iron, and molybdenum-coated iron shot was studied. Mallards fed lead, plastic-coated lead, or lead-magnesium alloy shot developed a similar pathological response, including the formation of acid-fast intranuclear inclusion bodies in the kidneys. Birds fed iron or molybdenum-coated iron shot developed hemosiderosis of the liver. Two of four mallards fed zinc-coated iron shot also developed hemosiderosis of the liver. No lesions were found in mallards fed copper shot.

Zinc in Infection and Inflammation.

PubMed

Gammoh, Nour Zahi; Rink, Lothar

2017-06-17

Micronutrient homeostasis is a key factor in maintaining a healthy immune system. Zinc is an essential micronutrient that is involved in the regulation of the innate and adaptive immune responses. The main cause of zinc deficiency is malnutrition. Zinc deficiency leads to cell-mediated immune dysfunctions among other manifestations. Consequently, such dysfunctions lead to a worse outcome in the response towards bacterial infection and sepsis. For instance, zinc is an essential component of the pathogen-eliminating signal transduction pathways leading to neutrophil extracellular traps (NET) formation, as well as inducing cell-mediated immunity over humoral immunity by regulating specific factors of differentiation. Additionally, zinc deficiency plays a role in inflammation, mainly elevating inflammatory response as well as damage to host tissue. Zinc is involved in the modulation of the proinflammatory response by targeting Nuclear Factor Kappa B (NF-κB), a transcription factor that is the master regulator of proinflammatory responses. It is also involved in controlling oxidative stress and regulating inflammatory cytokines. Zinc plays an intricate function during an immune response and its homeostasis is critical for sustaining proper immune function. This review will summarize the latest findings concerning the role of this micronutrient during the course of infections and inflammatory response and how the immune system modulates zinc depending on different stimuli.

VASQUEZ PEAK WILDERNESS STUDY AREA, AND ST. LOUIS PEAK, AND WILLIAMS FORK ROADLESS AREAS, COLORADO.

USGS Publications Warehouse

Theobald, P.K.; Bielski, A.M.

1984-01-01

A mineral-resource survey was conducted during the years 1979-82 in the Vasquez Peak Wilderness Study Area and in the St. Louis Peak and Williams Fork Roadless Areas, central Front Range, Colorado. Probable resource potential for the occurrence of copper, lead, zinc, and silver in massive sulfide deposits has been identified in calcareous metamorphic rocks in the northern part of the St. Louis Peak Roadless Area and in the southern part of the Williams Fork Roadless Area. A probable resource potential for vein-type uranium deposits is identified along the Berthoud Pass fault zone in the eastern part of the Vasquez Peak Wilderness Study Area. A large area encompassing the eastern and southeastern part of each of the three areas has probable and substantiated potential for either high-grade lead-zinc-silver vein deposits, or larger, lower-grade clustered vein deposits. A probable resource potential for stockwork molybdenum deposits related to porphyry molybdenum type mineralization exists beneath the lead-zinc-silver-rich veins. The nature of the geologic terrane indicates little likelihood for the occurrence of organic fuels.

Chronic sensitivity of white sturgeon (Acipenser transmontanus) and rainbow trout (Oncorhynchus mykiss) to cadmium, copper, lead, or zinc in laboratory water-only exposures

USGS Publications Warehouse

Wang, Ning; Ingersoll, Christopher G.; Dorman, Rebecca A.; Brumbaugh, William G.; Mebane, Christopher A.; Kunz, James L.; Hardesty, Douglas K.

2014-01-01

Chronic toxicity of cadmium, copper, lead, or zinc to white sturgeon (Acipenser transmontanus) and rainbow trout (Oncorhynchus mykiss) was evaluated in water-only exposures started with newly hatched larvae or approximately 1-mo-old juveniles. The 20% effect concentration (EC20) for cadmium from the sturgeon tests was higher than the EC20 from the trout tests, whereas the EC20 for copper, lead, or zinc for the sturgeon were lower than those EC20s for the trout. When the EC20s from the present study were included in compiled toxicity databases for all freshwater species, species mean chronic value for white sturgeon was in a relatively low percentile of the species sensitivity distribution for copper (9th percentile) and in the middle percentile for cadmium (55th percentile), zinc (40th percentile), or lead (50th percentile). However, the species mean chronic value for rainbow trout was in a high percentile for copper, lead, and zinc (∼68th–82nd percentile), but in a low percentile for cadmium (23rd percentile). The trout EC20s for each of the 4 metals and the sturgeon EC20s for cadmium or lead were above US Environmental Protection Agency chronic ambient water quality criteria (AWQC) or Washington State chronic water quality standards (WQS), whereas the sturgeon EC20s for copper or zinc were approximately equal to or below the chronic AWQC and WQS. In addition, acute 50% effect concentrations (EC50s) for copper obtained in the first 4 d of the chronic sturgeon test were below the final acute value used to derive acute AWQC and below acute WQS for copper.

Hybrid inorganic–organic superlattice structures with atomic layer deposition/molecular layer deposition

DOE Office of Scientific and Technical Information (OSTI.GOV)

Tynell, Tommi; Yamauchi, Hisao; Karppinen, Maarit, E-mail: maarit.karppinen@aalto.fi

2014-01-15

A combination of the atomic layer deposition (ALD) and molecular layer deposition (MLD) techniques is successfully employed to fabricate thin films incorporating superlattice structures that consist of single layers of organic molecules between thicker layers of ZnO. Diethyl zinc and water are used as precursors for the deposition of ZnO by ALD, while three different organic precursors are investigated for the MLD part: hydroquinone, 4-aminophenol and 4,4′-oxydianiline. The successful superlattice formation with all the organic precursors is verified through x-ray reflectivity studies. The effects of the interspersed organic layers/superlattice structure on the electrical and thermoelectric properties of ZnO are investigatedmore » through resistivity and Seebeck coefficient measurements at room temperature. The results suggest an increase in carrier concentration for small concentrations of organic layers, while higher concentrations seem to lead to rather large reductions in carrier concentration.« less

Differential toxicity of copper, zinc, and lead during the embryonic development of Chasmagnathus granulatus (Brachyura, Varunidae).

PubMed

Lavolpe, Mariano; Greco, Laura López; Kesselman, Daniela; Rodríguez, Enrique

2004-04-01

Ovigerous females of the estuarine crab Chasmagnathus granulatus were exposed to copper (0.01 and 1 mg/L), zinc (0.05, 1, and 10 mg/L), or lead (0.01 and 1 mg/L) during early, late, or whole embryonic development. None of the assayed heavy metals produced a significant mortality of females, neither a decrease in the number of hatched larvae nor a decrease in the egg incubation time, but several morphological abnormalities were detected in hatched larvae. The abnormalities were classified in three categories: eye, body pigmentary, and body morphological abnormalities. Those larvae with eye and body pigmentary abnormalities, particularly those involving retinal pigments and chromatophores, showed the highest incidence by exposure to the assayed metals. In addition, embryos were more susceptible to copper and zinc during the late period of development, whereas the effect of lead was greater during the early period of embryogenesis. Some teratogenic effects observed in C. granulatus embryos exposed to heavy metals, particularly the hypertrophy and hypopigmentation of eyes observed in the laboratory at a lead concentration as low as that reported for the natural environment, could be considered as sensitive biomarkers for this kind of pollutant.

Zinc induces long-term upregulation of T-type calcium current in hippocampal neurons in vivo.

PubMed

Ekstein, Dana; Benninger, Felix; Daninos, Moshe; Pitsch, Julika; van Loo, Karen M J; Becker, Albert J; Yaari, Yoel

2012-11-15

Extracellular zinc can induce numerous acute and persistent physiological and toxic effects in neurons by acting at their plasma membrane or intracellularly following permeation or uptake into them. Zinc acutely and reversibly blocks T-type voltage-gated calcium current (I(CaT)), but the long-term effect of zinc on this current has not been studied. Because chemically induced status epilepticus (SE) results in the release of zinc into the extracellular space, as well as in a long-lasting increase in I(CaT) in CA1 pyramidal cells, we hypothesized that zinc may play a causative role in I(CaT) upregulation. We tested this hypothesis by monitoring for 18 days the effects of zinc and ibotenic acid (a neurotoxic agent serving as control for zinc), injected into the right lateral ventricle, on I(CaT) in rat CA1 pyramidal cells. Both zinc and ibotenic acid caused marked hippocampal lesions on the side of injection, but only minor damage to contralateral hippocampi. Zinc, but not ibotenic acid, caused upregulation of a nickel-sensitive I(CaT) in a subset of contralateral CA1 pyramidal cells, appearing 2 days after injection and lasting for about 2 weeks thereafter. In contrast, acute application of zinc to CA1 pyramidal cells promptly blocked I(CaT). These data indicate that extracellular zinc has a dual effect on I(CaT), blocking it acutely while causing its long-term upregulation. Through the latter effect, zinc may regulate the intrinsic excitability of principal neurons, particularly in pathological conditions associated with enhanced release of zinc, such as SE.

ELECTRO-DEPOSITION OF NICKEL ALLOYS FROM THE PYROPHOSPHATE BATH: NICKEL- ZINC AND NICKEL-MOLYBDENUM ALLOYS

DOE Office of Scientific and Technical Information (OSTI.GOV)

Panikkar, S.K.; Char, T.L.R.

1958-02-01

Results of studies on the electrodeposition of nickel-zinc and nickel-- molybdenum alloys in a pyrophosphate bath using platinium electrodes are presented. The fects of varying current density and metal contents of the electrolyte on alloy deposit composition, cathode efficiency, and cathode potential are presented in tabular form. (J.R.D.) l2432 A study was made of the effect of homogenization on the mechanical properties of solution-treated and aged aluminum and the quantitative effects of several variables on hardness. The effect of alloying elements on the increase in hardness of aluminum is shown. (J.E.D.)

A p-Type Zinc-Based Metal-Organic Framework.

PubMed

Shang, Congcong; Gautier, Romain; Jiang, Tengfei; Faulques, Eric; Latouche, Camille; Paris, Michael; Cario, Laurent; Bujoli-Doeuff, Martine; Jobic, Stéphane

2017-06-05

An original concept for the property tuning of semiconductors is demonstrated by the synthesis of a p-type zinc oxide (ZnO)-like metal-organic framework (MOF), (ZnC 2 O 3 H 2 ) n , which can be regarded as a possible alternative for ZnO, a natural n-type semiconductor. When small oxygen-rich organic linkers are introduced to the Zn-O system, oxygen vacancies and a deep valence-band maximum, the two obstacles for generating p-type behavior in ZnO, are restrained and raised, respectively. Further studies of this material on the doping and photoluminescence behaviors confirm its resemblance to metal oxides (MOs). This result answers the challenges of generating p-type behavior in an n-type-like system. This concept reveals that a new category of hybrid materials, with an embedded continuous metal-oxygen network, lies between the MOs and MOFs. It provides concrete support for the development of p-type hybrid semiconductors in the near future and, more importantly, the enrichment of tuning possibilities in inorganic semiconductors.

Bandgap-Engineered Zinc-Tin-Oxide Thin Films for Ultraviolet Sensors.

PubMed

Cheng, Tien-Hung; Chang, Sheng-Po; Chang, Shoou-Jinn

2018-07-01

Zinc-tin-oxide thin-film transistors were prepared by radio frequency magnetron co-sputtering, while an identical zinc-tin-oxide thin film was deposited simultaneously on a clear glass substrate to facilitate measurements of the optical properties. When we adjusted the deposition power of ZnO and SnO2, the bandgap of the amorphous thin film was dominated by the deposition power of SnO2. Since the thin-film transistor has obvious absorption in the ultraviolet region owing to the wide bandgap, the drain current increases with the generation of electron-hole pairs. As part of these investigations, a zinc-tin-oxide thin-film transistor has been fabricated that appears to be very promising for ultraviolet applications.

Valley aggradation in the San Gabriel Mountains, California: climate change versus catastrophic landslide

NASA Astrophysics Data System (ADS)

Scherler, D.; Lamb, M. P.; Rhodes, E. J.; Avouac, J. P.

2014-12-01

The San Gabriel Mountains (SGM) in Southern California, rate amongst the most rapidly uplifting and eroding mountains in the United States. Their steep slopes and sensitivity to wildfires, flash floods, landslides, and debris flows account for imminent hazards to nearby urban areas that might be accentuated by climatic and other environmental changes. Previous studies suggested that river terraces along the North Fork of the San Gabriel River, record temporal variations in sediment supply and river transport capacity that are representative for the SGM and related to climatic changes during the Quaternary. Based on field observations, digital topographic analysis, and dating of Quaternary deposits, we suggest that valley aggradation in the North Fork San Gabriel Canyon was spatially confined and a consequence of the sudden supply of unconsolidated material to upstream reaches by one of the largest known landslides in the SGM. New 10Be-derived surface exposure ages from the landslide deposits, previously assumed to be early to middle Pleistocene in age, indicate at least three Holocene events at ~8-9 ka, ~4-5 ka, and ~0.5-1 ka. The oldest landslide predates the valley aggradation period, which is constrained by existing 14C ages and new luminescence ages to ~7-8 ka. The spatial distribution, morphology, and sedimentology of the river terraces are consistent with deposition from far-travelling debris flows that originated within the landslide deposits. Valley aggradation in the North Fork San Gabriel Canyon therefore resulted from locally enhanced sediment supply that temporarily overwhelmed river capacity but the lack of similar deposits in other parts of the SGM argues against a regional climatic signal. So far, there exists no evidence that in the San Gabriel Mountains, climatic changes can cause sustained increases in hillslope sediment supply that lead to river aggradation and terrace formation.

Transformation and birth processes of the transient luminous phenomena's in the low atmosphere of the Hessdalen valley, Norway.

NASA Astrophysics Data System (ADS)

Gitle Hauge, Bjørn; Strand, Erling

2013-04-01

Transient louminous phenomenas has been observed in and over the Hessdalen valley for over 100 years. These phenomena's has been nicknamed "Hessdalen phenomenas", HP, and has been under permanent scientific investigation since 1998, when Norwegian, Italian and later French researchers installed different types of monitoring equipment in the valley. The earth's magnetic field, electromagnetic radiation in different bands, radioactive radiation, electrical resistance in the ground, ultrasound, and seismic activity are some of the signals/parameters that has been monitored. The valley has also been surveillanced by radar, optical spectrometers and automatic video recording devices. So far no electromagnetic radiation, except in the optical band, has been detected that can be coupled to the HP. The phenomenon is characterized by its horizontal movement, intense optical radiation when a transformation process occurs, different colours where white/yellow dominates, no sound, high speed, unpredictable flight patterns, seen by radar while optical invisible and often observed with continuous optical spectrum. The phenomena have been seen touching ground, without leaving burning marks and flying in higher altitudes over the valley apparently ignoring wind/weather conditions. The Hessdalen valley is located in the middle of Norway and is famous for its mines with iron, zinc and copper ore. Big deposits of ore still reside inside the valley, and the mountains are penetrated by several mineshafts, some has depth down to 1000m. No exact birthplace has been located and the phenomenon seems to emerge "out of thin air" anywhere in the valley. Any activity coupled to mineshafts has not been observed. In September 2006 a birth and transformation process was observed and several optical spectrums was obtained. The phenomena appear as a big white light possibly not more than some hundred meters above the ground in a desolated area. The phenomenon starts a transformation process

The relationship between bone health and plasma zinc, copper lead and cadmium concentration in osteoporotic women.

PubMed

Sadeghi, Naficeh; Oveisi, Mohammad Reza; Jannat, Behrooz; Hajimahmoodi, Mannan; Behzad, Masoomeh; Behfar, Abdolazim; Sadeghi, Fatemeh; Saadatmand, Sahereh

2014-01-01

Osteoporosis is a multi factorial disease with dimension of genetic and nutritional considerations. The aim of this study was to present data from the association of plasma zinc, copper and toxic elements of lead and cadmium levels with bone mineral density in Iranian women. 135 women gave their information and enrolled. Fasting plasma was used for measurement of trace elements and heavy metals by Differential Pulse Anodic Stripping Voltammetry. Control group (n = 51) were normal in both lumbar spine (L1-L4) and femoral neck density (T-score ≥ -1), but just femoral neck T-score was considered as criterion in selection of patient group (n = 49, Tscore < -1). No differences were found in the nutritional status, number of diseases, drugs and functional activities between these groups. Plasma Zn, Cu, Pb, Cd levels were analyzed by, a method of voltammetry. Mean ± SD levels of copper and zinc was 1.168 ± 0.115, 1.097 ± 0.091 μg/ml in control group, 1.394 ± 0.133, 1.266 ± 0.11 μg/ml in total patient (TP) and 1.237 ± 0.182, 1.127 ± 0.176 μg/ml in Mild patients(-1 > T-score > -1.7), 1.463 ± 0.174, 1.327 ± 0.147 μg/ml in Severe patient group (T-score < -1.7); respectively. Mean ± SD plasma level of lead and cadmium was 168.42 ± 9.61 ng/l, 2.91 ± 0.18 ng/ml in control group, 176.13 ± 8.64 ng/l, 2.97 ± 0.21 ng/ml in TP, 176.43 ± 13.2 ng/l, 2.99 ± 0.1 ng/ml in mild patients, 221.44 ± 20 ng/l and 3.80 ± 0.70 ng/ml in severe patient group, respectively. In this study plasma zinc, copper, lead & cadmium concentrations were higher in the patients than in the control, though differences were not significant. However, differences were higher between the controls and patients with severe disease (T-score < -1.7). In addition adjusted T-score of femur with age and BMI showed negative significant correlation with plasma levels of zinc and lead in total participants (p < 0.05, r = -0.201, p = 0.044, r = -0.201). It seems that more extensive study with larger

Zinc lozenges and the common cold: a meta-analysis comparing zinc acetate and zinc gluconate, and the role of zinc dosage.

PubMed

Hemilä, Harri

2017-05-01

To compare the efficacy of zinc acetate lozenges with zinc gluconate lozenges in common cold treatment and to examine the dose-dependency of the effect. Meta-analysis. Placebo-controlled zinc lozenge trials, in which the zinc dose was > 75 mg/day. The pooled effect of zinc lozenges on common cold duration was calculated by using inverse-variance random-effects method. Seven randomised trials with 575 participants with naturally acquired common colds. Duration of the common cold. The mean common cold duration was 33% (95% CI 21% to 45%) shorter for the zinc groups of the seven included trials. Three trials that used lozenges composed of zinc acetate found that colds were shortened by 40% and four trials that used zinc gluconate by 28%. The difference between the two salts was not significant: 12 percentage points (95% CI: -12 to + 36). Five trials used zinc doses of 80-92 mg/day, common cold duration was reduced by 33%, and two trials used zinc doses of 192-207 mg/day and found an effect of 35%. The difference between the high-dose and low-dose zinc trials was not significant: 2 percentage points (95% CI: -29 to + 32). Properly composed zinc gluconate lozenges may be as effective as zinc acetate lozenges. There is no evidence that zinc doses over 100 mg/day might lead to greater efficacy in the treatment of the common cold. Common cold patients may be encouraged to try zinc lozenges for treating their colds. The optimal lozenge composition and dosage scheme need to be investigated further.

TOP VIEW OF CYANIDE PLANT FOUNDATIONS. ZINC BOXES, TANKS, AND ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

TOP VIEW OF CYANIDE PLANT FOUNDATIONS. ZINC BOXES, TANKS, AND TAILINGS PILES, LOOKING SOUTHWEST FROM MAIN ACCESS ROAD. THE FOUNDATIONS AT CENTER SUPPORTED SIX 25 FT. OR GREATER DIAMETER SETTLING TANKS. IN THE FOREGROUND ARE REMAINS OF TWO PREPARATION TANKS AT LEFT NEXT TO A BUILDING FOOTPRINT AT RIGHT. ZINC BOXES ARE JUST ABOVE THE PREPARATION TANKS ON LEFT. THE WATER TANK AT CENTER IS NEARBY A SHAFT. THE COLLAPSED TANK JUST IN FRONT OF THE WATER TANK IS ANOTHER WATER HOLDING TANK THAT CONNECTS DIRECTLY TO THE PIPELINE THAT CARRIED WATER FROM A NEARBY SPRING A QUARTER MILE OFF TO THE RIGHT (SEE CA-291-41 FOR DETAIL). THE LEFT OF THE CENTER WATER TANK IS A LARGE TAILINGS PILE. DEATH VALLEY IS IN THE DISTANCE. SEE CA-291-40 FOR IDENTICAL B&W NEGATIVE. - Keane Wonder Mine, Park Route 4 (Daylight Pass Cutoff), Death Valley Junction, Inyo County, CA

TOP VIEW OF CYANIDE PLANT FOUNDATIONS, ZINC BOXES, TANKS, AND ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

TOP VIEW OF CYANIDE PLANT FOUNDATIONS, ZINC BOXES, TANKS, AND TAILINGS PILES, LOOKING SOUTHWEST FROM MAIN ACCESS ROAD. THE FOUNDATIONS AT CENTER SUPPORTED SIX 25 FT. OR GREATER DIAMETER SETTLING TANKS. IN THE FOREGROUND ARE REMAINS OF TWO PREPARATION TANKS AT LEFT NEXT TO A BUILDING FOOTPRINT AT RIGHT. ZINC BOXES ARE JUST ABOVE THE PREPARATION TANKS ON LEFT. THE WATER TANK AT CENTER IS NEARBY A SHAFT. THE COLLAPSED TANK JUST IN FRONT OF THE WATER TANK IS ANOTHER WATER HOLDING TANK THAT CONNECTS DIRECTLY TO THE PIPELINE THAT CARRIED WATER FROM A NEARBY SPRING A QUARTER MILE OFF TO THE RIGHT (SEE CA-291-41 FOR DETAIL). THE LEFT OF THE CENTER WATER TANK IS A LARGE TAILINGS PILE. DEATH VALLEY IS IN THE DISTANCE. SEE CA-291-53 (CT) FOR IDENTICAL COLOR TRANSPARENCY. - Keane Wonder Mine, Park Route 4 (Daylight Pass Cutoff), Death Valley Junction, Inyo County, CA

Adverse health effects in Canada geese (Branta canadensis) associated with waste from zinc and lead mines in the Tri-State Mining District (Kansas, Oklahoma, and Missouri, USA).

PubMed

van der Merwe, Deon; Carpenter, James W; Nietfeld, Jerome C; Miesner, John F

2011-07-01

Lead and zinc poisoning have been recorded in a variety of bird species, including migrating waterfowl such as Canada Geese (Branta canadensis), at sites contaminated with mine waste from lead and zinc mines in the Tri-State Mining District, Kansas, Oklahoma, and Missouri, USA. The adverse health impacts from mine waste on these birds may, however, be more extensive than is apparent from incidental reports of clinical disease. To characterize health impacts from mine waste on Canada Geese that do not have observable signs of poisoning, four to eight apparently healthy birds per site were collected from four contaminated sites and an uncontaminated reference site, and examined for physical and physiologic evidence of metals poisoning. Tissue concentrations of silver, aluminum, arsenic, barium, cadmium, cobalt, chromium, copper, iron, magnesium, manganese, molybdenum, nickel, lead, selenium, thallium, vanadium, and zinc were determined by inductively coupled plasma mass spectroscopy. Adverse health effects due to lead were characterized by assessing blood δ-aminolevulinic acid dehydratase (ALAD) enzyme activity. Adverse effects associated with zinc poisoning were determined from histologic examination of pancreas tissues. Elevated tissue lead concentrations and inhibited blood ALAD enzyme activities were consistently found in birds at all contaminated sites. Histopathologic signs of zinc poisoning, including fibrosis and vacuolization, were associated with elevated pancreatic zinc concentrations at one of the study sites. Adverse health effects associated with other analyzed elements, or tissue concentrations indicating potentially toxic exposure levels to these elements, were not observed.

Zinc finger proteins in cancer progression.

PubMed

Jen, Jayu; Wang, Yi-Ching

2016-07-13

Zinc finger proteins are the largest transcription factor family in human genome. The diverse combinations and functions of zinc finger motifs make zinc finger proteins versatile in biological processes, including development, differentiation, metabolism and autophagy. Over the last few decades, increasing evidence reveals the potential roles of zinc finger proteins in cancer progression. However, the underlying mechanisms of zinc finger proteins in cancer progression vary in different cancer types and even in the same cancer type under different types of stress. Here, we discuss general mechanisms of zinc finger proteins in transcription regulation and summarize recent studies on zinc finger proteins in cancer progression. In this review, we also emphasize the importance of further investigations in elucidating the underlying mechanisms of zinc finger proteins in cancer progression.

Preparation of silver-activated zinc sulfide thin films

NASA Technical Reports Server (NTRS)

Feldman, C.; Swindells, F. E.

1968-01-01

Silver improves luminescence and reduces contamination of zinc sulfide phosphors. The silver is added after the zinc sulfide phosphors are deposited in thin films by vapor evaporation, but before calcining, by immersion in a solution of silver salt.

Reservoir performance of Late Eocene incised valley fills, Cusiana Field, Llanos Foothills, Eastern Colombia

DOE Office of Scientific and Technical Information (OSTI.GOV)

Pulham, A.; Edward, W.; App, J.

1996-12-31

The Cusiana Field is located in the Llanos Foothills of Eastern Colombia. The principal reservoir is the late Eocene Mirador Formation which comprises >50% of reserves. Currently the Mirador reservoir is providing nearly all of the 150,00bopd of production from the Cusiana Field. The Mirador reservoir comprises a stack of incised valley deposits. The fills of the valleys are dominated by quartz arenite sandstones. The average porosity of the valley sandstones is 8% which reflects abundant quartz cement ({approximately}14%) and significant compaction during deep burial ({approximately}20,000feet). Single valleys are up to 70 feet thick and exhibit a distinctive bipartite fillmore » that reflects changing energy conditions during filling. Bases of valleys have the coarsest grain size and have sedimentological and trace fossil evidence for deposition in highly stressed, brackish water environments. The upper parts of the valleys are typically finer grained and were deposited in more saline settings. Despite the low porosity of the Mirador valleys, drill stem tests and production log data show that they have phenomenal performance characteristics. Rates of {ge}10,000bopd are achieved from single valleys. Bases of the valley fills are the key contributors to flow. Integration of detailed core and pore system analysis with the reservoir performance data shows that the permeability fabric of the Mirador can be explained by original depositional architecture and simple loss of primary porosity. Comparison of Cusiana with other quartz-rich sandstones from around the world suggests that it`s low porosity/high performance is predictable.« less

When the same hydraulics conditions lead to different depositional patterns: case of an idealised delta

NASA Astrophysics Data System (ADS)

Peltier, Yann; Erpicum, Sébastien; Archambeau, Pierre; Pirotton, Michel; Dewals, Benjamin

2016-04-01

Deltas are complex hydrosystems and ecosystems resulting from the interactions of a river system with a water body almost at rest. Anthropogenic factors (hydropower, flood management, development in the floodplains) lead to dramatic changes in sediment transport in the rivers and in sediment management practice. From continuous, the sediment transport becomes increasingly intermittent, with long periods of deficit in the sediment supply and short periods characterized by large supplies. Understanding how these intermittencies in the sediment supply affect the delta morphodynamics is of paramount importance for predicting the possible evolution and functioning of deltas. Deltas can reasonably be idealised as a reservoir, with an inlet channel representing the river and the sudden enlargement of the reservoir representing the water body at rest. Using such an ideal configuration enables the assessment of the influence of individual geometric and hydraulic parameters on the depositional patterns responsible for the morphodynamic evolution of the delta. Recent literature has shown that for very similar hydraulic boundary conditions, two very different types of flow fields may develop ("straight jet" vs. "meandering jet"), leading to totally different depositional patterns. In turn, these distinct depositional patterns affect the flow itself through a two-way coupling between the hydrodynamics and the morphodynamics of the deposits. These complex processes will be discussed in the proposed presentation, based on the results of over 160 experimental tests and corresponding numerical simulations.

Clay-bearing Fluvial Deposits in Western Ladon Basin, Mars

NASA Astrophysics Data System (ADS)

Weitz, C. M.; Grant, J. A.; Irwin, R. P.; Wilson, S. A.

2013-12-01

More than a dozen outcrops of light-toned layered deposits occur in the uplands to the west of Ladon basin in Margaritifer Terra, Mars. We are evaluating the morphology, mineralogy, and distribution of these sedimentary deposits and associated valley systems that dissect the local Noachian bedrock to understand how they reflect source materials and record environmental and climatic conditions during their emplacement. Several craters, including secondary craters from the Holden impact event, also contain sedimentary deposits, suggesting at least some of the deposits are younger than Mid-to-Late Hesperian. All the deposits appear confined within basins, valleys or craters that are breached by valleys. The deposits typically show numerous beds with variable lithologies, suggesting multiple episodes of deposition and/or changing aqueous conditions over time. CRISM spectra extracted from the deposits typically have absorption features around 1.93 and 2.29 μm, consistent with Fe/Mg-smectites. Several deposits within Arda Valles may have been emplaced when the system was blocked at the eastern end by topography associated with two unnamed craters. Deposition emplaced the clay-bearing layered sediments before an outlet was established, enabling drainage onto the lower-lying floor of Ladon basin and formation of an inverted channel within one of the valleys (Figure 1). All the deposits are located 0.5-2 km above clay-bearing deposits found on the Ladon basin floor, including within Ladon Valles, thereby indicating they were not associated with a lake within the basin or late-stage discharge from Ladon Valles. Instead, their sources appear to be localized and associated with the rim materials of the ancient impact structures or nearby weathered bedrock. The upland deposits may have formed concurrently with deposits found to the south in Eberswalde and Holden craters, indicating precipitation and/or snow melt across much of Margaritifer Terra during the Late Hesperian to

Zinc in Infection and Inflammation

PubMed Central

Gammoh, Nour Zahi; Rink, Lothar

2017-01-01

Micronutrient homeostasis is a key factor in maintaining a healthy immune system. Zinc is an essential micronutrient that is involved in the regulation of the innate and adaptive immune responses. The main cause of zinc deficiency is malnutrition. Zinc deficiency leads to cell-mediated immune dysfunctions among other manifestations. Consequently, such dysfunctions lead to a worse outcome in the response towards bacterial infection and sepsis. For instance, zinc is an essential component of the pathogen-eliminating signal transduction pathways leading to neutrophil extracellular traps (NET) formation, as well as inducing cell-mediated immunity over humoral immunity by regulating specific factors of differentiation. Additionally, zinc deficiency plays a role in inflammation, mainly elevating inflammatory response as well as damage to host tissue. Zinc is involved in the modulation of the proinflammatory response by targeting Nuclear Factor Kappa B (NF-κB), a transcription factor that is the master regulator of proinflammatory responses. It is also involved in controlling oxidative stress and regulating inflammatory cytokines. Zinc plays an intricate function during an immune response and its homeostasis is critical for sustaining proper immune function. This review will summarize the latest findings concerning the role of this micronutrient during the course of infections and inflammatory response and how the immune system modulates zinc depending on different stimuli. PMID:28629136

Geology and water resources of Owens Valley, California

USGS Publications Warehouse

Hollett, Kenneth J.; Danskin, Wesley R.; McCaffrey, William F.; Walti, Caryl L.

1991-01-01

Owens Valley, a long, narrow valley located along the east flank of the Sierra Nevada in east-central California, is the main source of water for the city of Los Angeles. The city diverts most of the surface water in the valley into the Owens River-Los Angeles Aqueduct system, which transports the water more than 200 miles south to areas of distribution and use. Additionally, ground water is pumped or flows from wells to supplement the surface-water diversions to the river-aqueduct system. Pumpage from wells needed to supplement water export has increased since 1970, when a second aqueduct was put into service, and local concerns have been expressed that the increased pumpage may have had a detrimental effect on the environment and the indigenous alkaline scrub and meadow plant communities in the valley. The scrub and meadow communities depend on soil moisture derived from precipitation and the unconfined part of a multilayered aquifer system. This report, which describes the hydrogeology of the aquifer system and the water resources of the valley, is one in a series designed to (1) evaluate the effects that groundwater pumping has on scrub and meadow communities and (2) appraise alternative strategies to mitigate any adverse effects caused by, pumping. Two principal topographic features are the surface expression of the geologic framework--the high, prominent mountains on the east and west sides of the valley and the long, narrow intermountain valley floor. The mountains are composed of sedimentary, granitic, and metamorphic rocks, mantled in part by volcanic rocks as well as by glacial, talus, and fluvial deposits. The valley floor is underlain by valley fill that consists of unconsolidated to moderately consolidated alluvial fan, transition-zone, glacial and talus, and fluvial and lacustrine deposits. The valley fill also includes interlayered recent volcanic flows and pyroclastic rocks. The bedrock surface beneath the valley fill is a narrow, steep-sided graben

Venusian channels and valleys - Distribution and volcanological implications

NASA Technical Reports Server (NTRS)

Komatsu, Goro; Baker, Victor R.; Gulick, Virginia C.; Parker, Timothy J.

1993-01-01

An updated map is presented which shows the distribution of more than 200 channels and valleys on Venus. A large number of channels are concentrated in equatorial regions characterized by highlands, rift and fracture zones, an associated volcanic features. Many channels associated with flow deposits are similar to typical terrestrial lava drainage channels. They are associated with a wide range of volcanic edifices. More than half of the sinuous rilles are associated with coronae, coronalike features, or arachnoids. Corona volcanism driven by mantle plume events may explain this association. Many valley network are observed in highlands and in association with coronae, coronalike features, or arachnoids. This indicates that highlands and coronae provided fractures and flow-viscosity lavas, both of which seem to be required for network formation by lava sapping processes. Canali-type channels have a unique distribution limited to some plains regions.

Zinc-mediated Allosteric Inhibition of Caspase-6*

PubMed Central

Velázquez-Delgado, Elih M.; Hardy, Jeanne A.

2012-01-01

Zinc and caspase-6 have independently been implicated in several neurodegenerative disorders. Depletion of zinc intracellularly leads to apoptosis by an unknown mechanism. Zinc inhibits cysteine proteases, including the apoptotic caspases, leading to the hypothesis that zinc-mediated inhibition of caspase-6 might contribute to its regulation in a neurodegenerative context. Using inductively coupled plasma optical emission spectroscopy, we observed that caspase-6 binds one zinc per monomer, under the same conditions where the zinc leads to complete loss of enzymatic activity. To understand the molecular details of zinc binding and inhibition, we performed an anomalous diffraction experiment above the zinc edge. The anomalous difference maps showed strong 5σ peaks, indicating the presence of one zinc/monomer bound at an exosite distal from the active site. Zinc was not observed bound to the active site. The zinc in the exosite was liganded by Lys-36, Glu-244, and His-287 with a water molecule serving as the fourth ligand, forming a distorted tetrahedral ligation sphere. This exosite appears to be unique to caspase-6, as the residues involved in zinc binding were not conserved across the caspase family. Our data suggest that binding of zinc at the exosite is the primary route of inhibition, potentially locking caspase-6 into the inactive helical conformation. PMID:22891250

Microstructure and electroluminescent performance of chemical vapor deposited zinc sulfide doped with manganese films for integration in thin film electroluminescent devices

NASA Astrophysics Data System (ADS)

Topol, Anna Wanda

Zinc sulfide (ZnS) doped with manganese (Mn), ZnS:Mn, is widely recognized as the brightest and most effective electroluminescent (EL) phosphor used in current thin film electroluminescent (TFEL) devices. ZnS acts as a host lattice for the luminescent activator, Mn, leading to a highly efficient yellow-orange EL emission, and resulting in a wide array of applications in monochrome, multi-color and full color displays. Although this wide band dap (3.7 eV) material can be prepared by several deposition techniques, the chemical vapor deposition (CVD) is the most promising for TFEL applications in terms of viable deposition rates, high thickness and composition uniformity, and excellent yield over large area panels. This study describes the development and optimization of a CVD ZnS:Mn process using diethylzinc [(C2H5)2Zn, DEZ], di-pi-cyclopentadienylmanganese [(C5H5)2Mn, CPMn], and hydrogen sulfide [H2S] as the chemical sources for, respectively, Zn, Mn, and S. The effects of key deposition parameters on resulting Film microstructure and performance are discussed, primarily in the context of identifying an optimized process window for best electroluminescence behavior. In particular, substrate temperature was observed to play a key role in the formation of high quality crystalline ZnS:Mn films leading to improved brightness and EL efficiency. Further investigations of the influence of temperature treatment on the structural characteristics and EL performance of the CVD ZnS:Mn film were carried out. In this study, the influence of post-deposition annealing both in-situ and ex-situ annealing processes, on chemical, structural, and electroluminescent characteristics of the phosphor layer are described. The material properties of the employed dielectric are among the key factors determining the performance, stability and reliability of the TFEL display and therefore, the choice of dielectric material for use in ACTFEL displays is crucial. In addition, the luminous

Comparison of methods for measuring atmospheric deposition of arsenic, cadmium, nickel and lead.

PubMed

Aas, Wenche; Alleman, Laurent Y; Bieber, Elke; Gladtke, Dieter; Houdret, Jean-Luc; Karlsson, Vuokko; Monies, Christian

2009-06-01

A comprehensive field intercomparison at four different types of European sites (two rural, one urban and one industrial) comparing three different collectors (wet only, bulk and Bergerhoff samplers) was conducted in the framework of the European Committee for Standardization (CEN) to create an European standard for the deposition of the four elements As, Cd, Ni and Pb. The purpose was to determine whether the proposed methods lead to results within the uncertainty required by the EU's daughter directive (70%). The main conclusion is that a different sampling strategy is needed for rural and industrial sites. Thus, the conclusions on uncertainties and sample approach are presented separately for the different approaches. The wet only and bulk collector ("bulk bottle method") are comparable at wet rural sites where the total deposition arises mainly from precipitation, the expanded uncertainty when comparing these two types of sampler are below 45% for As, Cd and Pb, 67% for Ni. At industrial sites and possibly very dry rural and urban sites it is necessary to use Bergerhoff samplers or a "bulk bottle+funnel method". It is not possible to address the total deposition estimation with these methods, but they will give the lowest estimate of the total deposition. The expanded uncertainties when comparing the Bergerhoff and the bulk bottle+funnel methods are below 50% for As and Cd, and 63% for Pb. The uncertainty for Ni was not addressed since the bulk bottle+funnel method did not include a full digestion procedure which is necessary for sites with high loads of undissolved metals. The lowest estimate can however be calculated by comparing parallel Bergerhoff samplers where the expanded uncertainty for Ni was 24%. The reproducibility is comparable to the between sampler/method uncertainties. Sampling and sample preparation were proved to be the main factors in the uncertainty budget of deposition measurements.

Precambrian Sulphide Deposits

NASA Astrophysics Data System (ADS)

Doe, Bruce R.

1984-04-01

This book is dedicated to Howard S. Robinson, who was born and educated in the United States, but who spent his professional career in Canada with McIntyre Porcupine Mines, concentrating on Precambrian mineral deposits. Although his career in mineral exploration was distinguished, his major contribution to earth science was probably as one of the founders of the Geological Association of Canada, an institution to which he made a bequest in his will. With this background, the strong emphasis on Canadian Precambrian mineral deposits should come as no surprise; of the 23 papers in this book, 21 are solely or primarily devoted to Canadian deposits. The two exceptions—those describing the Balmat, N.Y., zinc mines (at times the largest zinc producer in the United States) and the Crandon, Wisconsin, volcanogenic zinc-copper massive-sulfide deposit (the largest deposit of its kind found in the 1970s)—are each within a couple of hundred kilometers of the Canadian border. Although the title of the book is more expansive than the actual topics discussed, Canada is rich in Precambrian rocks and ore bodies, and Canadian scientists have been especially alert to tectonic influences in the formation of mineral deposits. These features, plus the fact that the country contains a very well exposed expanse of Archean rocks which is the largest in the world, facilitate the study of early crustal evolution and make the book of particular interest to geophysicists.

Structure and Internal Stress of Tin-Doped Indium Oxide and Indium-Zinc Oxide Films Deposited by DC Magnetron Sputtering

NASA Astrophysics Data System (ADS)

Nishimura, Eriko; Sasabayashi, Tomoko; Ito, Norihiro; Sato, Yasushi; Utsumi, Kentaro; Yano, Koki; Kaijo, Akira; Inoue, Kazuyoshi; Shigesato, Yuzo

2007-12-01

Representative transparent conductive oxide films, such as tin-doped indium oxide (ITO) and indium-zinc oxide (IZO) films, were deposited by dc magnetron sputtering using corresponding oxide targets under various total gas pressures (Ptot) ranging from 0.3 to 3.0 Pa. The ITO films deposited at a Ptot lower than 0.7 Pa were polycrystalline and were found to have a large compressive stress of about 1.5 × 109 Pa, whereas the ITO films deposited at 1.5-3.0 Pa were amorphous and had a low tensile stress. In contrast, all the IZO films deposited at a Ptot range of 0.3-3.0 Pa showed an entirely amorphous structure, where the compressive stress in the IZO films deposited at a Ptot lower than 1.5 Pa was lower than that in the ITO films. Such compressive stress was considered to be generated by the atomic peening effect of high-energy neutrals (Ar0) recoiled from the target or high-energy negative ions (O-) accelerated in the cathode sheath toward the film surface.

p-type zinc-blende GaN on GaAs substrates

NASA Astrophysics Data System (ADS)

Lin, M. E.; Xue, G.; Zhou, G. L.; Greene, J. E.; Morkoç, H.

1993-08-01

We report p-type cubic GaN. The Mg-doped layers were grown on vicinal (100) GaAs substrates by plasma-enhanced molecular beam epitaxy. Thermally sublimed Mg was, with N2 carrier gas, fed into an electron-cyclotron resonance source. p-type zinc-blende-structure GaN films were achieved with hole mobilities as high as 39 cm2/V s at room temperature. The cubic nature of the films were confirmed by x-ray diffractometry. The depth profile of Mg was investigated by secondary ions mass spectroscopy.

Valley-dependent band structure and valley polarization in periodically modulated graphene

NASA Astrophysics Data System (ADS)

Lu, Wei-Tao

2016-08-01

The valley-dependent energy band and transport property of graphene under a periodic magnetic-strained field are studied, where the time-reversal symmetry is broken and the valley degeneracy is lifted. The considered superlattice is composed of two different barriers, providing more degrees of freedom for engineering the electronic structure. The electrons near the K and K' valleys are dominated by different effective superlattices. It is found that the energy bands for both valleys are symmetric with respect to ky=-(AM+ξ AS) /4 under the symmetric superlattices. More finite-energy Dirac points, more prominent collimation behavior, and new crossing points are found for K' valley. The degenerate miniband near the K valley splits into two subminibands and produces a new band gap under the asymmetric superlattices. The velocity for the K' valley is greatly renormalized compared with the K valley, and so we can achieve a finite velocity for the K valley while the velocity for the K' valley is zero. Especially, the miniband and band gap could be manipulated independently, leading to an increase of the conductance. The characteristics of the band structure are reflected in the transmission spectra. The Dirac points and the crossing points appear as pronounced peaks in transmission. A remarkable valley polarization is obtained which is robust to the disorder and can be controlled by the strain, the period, and the voltage.

Paleogeomorphology of the early Colorado River inferred from relationships in Mohave and Cottonwood Valleys, Arizona, California and Nevada

USGS Publications Warehouse

Pearthree, Philip; House, P. Kyle

2014-01-01

Geologic investigations of late Miocene–early Pliocene deposits in Mohave and Cottonwood valleys provide important insights into the early evolution of the lower Colorado River system. In the latest Miocene these valleys were separate depocenters; the floor of Cottonwood Valley was ∼200 m higher than the floor of Mohave Valley. When Colorado River water arrived from the north after 5.6 Ma, a shallow lake in Cottonwood Valley spilled into Mohave Valley, and the river then filled both valleys to ∼560 m above sea level (asl) and overtopped the bedrock divide at the southern end of Mohave Valley. Sediment-starved water spilling to the south gradually eroded the outlet as siliciclastic Bouse deposits filled the lake upstream. When sediment accumulation reached the elevation of the lowering outlet, continued erosion of the outlet resulted in recycling of stored lacustrine sediment into downstream basins; depth of erosion of the outlet and upstream basins was limited by the water levels in downstream basins. The water level in the southern Bouse basin was ∼300 m asl (modern elevation) at 4.8 Ma. It must have drained and been eroded to a level <150 m asl soon after that to allow for deep erosion of bedrock divides and basins upstream, leading to removal of large volumes of Bouse sediment prior to massive early Pliocene Colorado River aggradation. Abrupt lowering of regional base level due to spilling of a southern Bouse lake to the Gulf of California could have driven observed upstream river incision without uplift. Rapid uplift of the entire region immediately after 4.8 Ma would have been required to drive upstream incision if the southern Bouse was an estuary.

Hydrogeologic framework and occurrence, movement, and chemical characterization of groundwater in Dixie Valley, west-central Nevada

USGS Publications Warehouse

Huntington, Jena M.; Garcia, C. Amanda; Rosen, Michael R.

2014-01-01

Dixie Valley, a primarily undeveloped basin in west-central Nevada, is being considered for groundwater exportation. Proposed pumping would occur from the basin-fill aquifer. In response to proposed exportation, the U.S. Geological Survey, in cooperation with the Bureau of Reclamation and Churchill County, conducted a study to improve the understanding of groundwater resources in Dixie Valley. The objective of this report is to characterize the hydrogeologic framework, the occurrence and movement of groundwater, the general water quality of the basin-fill aquifer, and the potential mixing between basin-fill and geothermal aquifers in Dixie Valley. Various types of geologic, hydrologic, and geochemical data were compiled from previous studies and collected in support of this study. Hydrogeologic units in Dixie Valley were defined to characterize rocks and sediments with similar lithologies and hydraulic properties influencing groundwater flow. Hydraulic properties of the basin-fill deposits were characterized by transmissivity estimated from aquifer tests and specific-capacity tests. Groundwater-level measurements and hydrogeologic-unit data were combined to create a potentiometric surface map and to characterize groundwater occurrence and movement. Subsurface inflow from adjacent valleys into Dixie Valley through the basin-fill aquifer was evaluated using hydraulic gradients and Darcy flux computations. The chemical signature and groundwater quality of the Dixie Valley basin-fill aquifer, and potential mixing between basin-fill and geothermal aquifers, were evaluated using chemical data collected from wells and springs during the current study and from previous investigations. Dixie Valley is the terminus of the Dixie Valley flow system, which includes Pleasant, Jersey, Fairview, Stingaree, Cowkick, and Eastgate Valleys. The freshwater aquifer in the study area is composed of unconsolidated basin-fill deposits of Quaternary age. The basin-fill hydrogeologic unit

[Reduced zinc concentration in expressed prostatic secretion relates to the pain symptoms of types Ⅲ and Ⅳ prostatitis].

PubMed

Mo, Lin-Jian; Chen, Xi; Wang, Xiao-Ming; Li, Guang-Yu; Zhang, Xun; Huang, Shan; Xie, Zhi-Bin; Mo, Zeng-Nan

2016-06-01

To determine the zinc levels in the expressed prostatic secretion (EPS) of the patients with different types of chronic nonbacterial prostatitis, and explore the reference value of zinc concentration in EPS in the diagnosis and treatment of prostatitis. We collected EPS samples from 35 healthy men and 173 patients with chronic nonbacterial prostatitis, including 65 cases of type ⅢA, 69 cases of type ⅢB, and 39 cases of type Ⅳ, according to the National Institutes of Health Chronic Prostatitis Symptom Index (NIH-CPSI). We compared the zinc levels in the EPS samples among different groups and analyzed the correlations of zinc concentration with the NIH-CPSI scores, WBC count, pH value, and age of the subjects. The participants were aged 17－65 (32.5±8.5) years. The zinc concentrations in the EPS were significantly lower in the ⅢA (［162.2±10.8］ μg/ml) and ⅢB (［171.2±12.0］ μg/ml) than in the Ⅳ (［234.6±17.9］ μg/ml) (P<0.05 ) and the control group (［259.5±14.6］ μg/ml) (P<0.05 ). The zinc level was correlated negatively with the NIH-CPSI pain score (r=－0.248, P<0.01), quality of life score (r=－0.232, P<0.01), severity score (r=－0.270, P<0.01), total NIH-CPSI score (r=－0.281, P<0.01), and the pH value in EPS (r=－0.208, P<0.01), but showed no correlation with the WBC count and age of the subjects. The reduced zinc concentration in the EPS of the patients with chronic nonbacterial prostatitis may be associated with the pain symptoms of the disease, which suggests the potential reference value of measuring the zinc concentration in EPS in the diagnosis and treatment of prostatitis.

The effect of the solution flow rate on the properties of zinc oxide (ZnO) thin films deposited by ultrasonic spray

NASA Astrophysics Data System (ADS)

Attaf, A.; Benkhetta, Y.; Saidi, H.; Bouhdjar, A.; Bendjedidi, H.; Nouadji, M.; Lehraki, N.

2015-03-01

In this work, we used a system based on ultrasonic spray pyrolysis technique. By witch, we have deposited thin films of zinc oxide (ZnO) with the variation of solution flow rate from 50 ml / h to 150 ml / h, and set other parameters such as the concentration of the solution, the deposition time, substrate temperature and the nozzel -substrate distance. In order to study the influence of the solution flow rate on the properties of the films produced, we have several characterization techniques such as X-ray diffraction to determine the films structure, the scanning electron microscopy SEM for the morphology of the surfaces, EDS spectroscopy for the chemical composition, UV-Visible-Nir spectroscopy for determination the optical proprieties of thin films.The experimental results show that: the films have hexagonal structure at the type (wurtzite), the average size of grains varies from 20.11 to 32.45 nm, the transmittance of the films equals 80% in visible rang and the band gap is varied between 3.274 and 3.282 eV, when the solution flow rate increases from 50 to 150 ml/h.

Characterisation of zinc delivery from a nipple shield delivery system using a breastfeeding simulation apparatus

PubMed Central

Bruggraber, Sylvaine F. A.; Gerrard, Stephen E.; Kendall, Richard A.; Tuleu, Catherine; Slater, Nigel K. H.

2017-01-01

Zinc delivery from a nipple shield delivery system (NSDS), a novel platform for administering medicines to infants during breastfeeding, was characterised using a breastfeeding simulation apparatus. In this study, human milk at flow rates and pressures physiologically representative of breastfeeding passed through the NSDS loaded with zinc-containing rapidly disintegrating tablets, resulting in release of zinc into the milk. Inductively coupled plasma optical emission spectrometry was used to detect the zinc released, using a method that does not require prior digestion of the samples and that could be applied in other zinc analysis studies in breast milk. Four different types of zinc-containing tablets with equal zinc load but varying excipient compositions were tested in the NSDS in vitro. Zinc release measured over 20 minutes ranged from 32–51% of the loaded dose. Total zinc release for sets tablets of the same composition but differing hardness were not significantly different from one another with P = 0.3598 and P = 0.1270 for two tested pairs using unpaired t tests with Welch’s correction. By the same test total zinc release from two sets of tablets having similar hardness but differing composition were also not significantly significant with P = 0.2634. Future zinc tablet composition and formulation optimisation could lead to zinc supplements and therapeutics with faster drug release, which could be administered with the NSDS during breastfeeding. The use of the NSDS to deliver zinc could then lead to treatment and prevention of some of the leading causes of child mortality, including diarrheal disease and pneumonia. PMID:28158283

Characterisation of zinc delivery from a nipple shield delivery system using a breastfeeding simulation apparatus.

PubMed

Scheuerle, Rebekah L; Bruggraber, Sylvaine F A; Gerrard, Stephen E; Kendall, Richard A; Tuleu, Catherine; Slater, Nigel K H

2017-01-01

Zinc delivery from a nipple shield delivery system (NSDS), a novel platform for administering medicines to infants during breastfeeding, was characterised using a breastfeeding simulation apparatus. In this study, human milk at flow rates and pressures physiologically representative of breastfeeding passed through the NSDS loaded with zinc-containing rapidly disintegrating tablets, resulting in release of zinc into the milk. Inductively coupled plasma optical emission spectrometry was used to detect the zinc released, using a method that does not require prior digestion of the samples and that could be applied in other zinc analysis studies in breast milk. Four different types of zinc-containing tablets with equal zinc load but varying excipient compositions were tested in the NSDS in vitro. Zinc release measured over 20 minutes ranged from 32-51% of the loaded dose. Total zinc release for sets tablets of the same composition but differing hardness were not significantly different from one another with P = 0.3598 and P = 0.1270 for two tested pairs using unpaired t tests with Welch's correction. By the same test total zinc release from two sets of tablets having similar hardness but differing composition were also not significantly significant with P = 0.2634. Future zinc tablet composition and formulation optimisation could lead to zinc supplements and therapeutics with faster drug release, which could be administered with the NSDS during breastfeeding. The use of the NSDS to deliver zinc could then lead to treatment and prevention of some of the leading causes of child mortality, including diarrheal disease and pneumonia.

Angiotensin II potentiates zinc-induced cortical neuronal death by acting on angiotensin II type 2 receptor.

PubMed

Park, Mi-Ha; Kim, Ha Na; Lim, Joon Seo; Ahn, Jae-Sung; Koh, Jae-Young

2013-12-01

The angiotensin system has several non-vascular functions in the central nervous system. For instance, inhibition of the brain angiotensin system results in a reduction in neuronal death following acute brain injury such as ischemia and intracerebral hemorrhage, even under conditions of constant blood pressure. Since endogenous zinc has been implicated as a key mediator of ischemic neuronal death, we investigated the possibility that the angiotensin system affects the outcome of zinc-triggered neuronal death in cortical cell cultures. Exposure of cortical cultures containing neurons and astrocytes to 300 μM zinc for 15 min induced submaximal death in both types of cells. Interestingly, addition of angiotensin II significantly enhanced the zinc-triggered neuronal death, while leaving astrocytic cell death relatively unchanged. Both type 1 and 2 angiotensin II receptors (AT1R and AT2R, respectively) were expressed in neurons as well as astrocytes. Zinc neurotoxicity was substantially attenuated by PD123319, a specific inhibitor of AT2R, and augmented by CGP42112, a selective activator of AT2R, indicating a critical role for this receptor subtype in the augmentation of neuronal cell death.Because zinc toxicity occurs largely through oxidative stress, the levels of superoxides in zinc-treated neurons were assessed by DCF fluorescence microscopy. Combined treatment with zinc and angiotensin II substantially increased the levels of superoxides in neurons compared to those induced by zinc alone. This increase in oxidative stress by angiotensin II was completely blocked by the addition of PD123319. Finally, since zinc-induced oxidative stress may be caused by induction and/or activation of NADPH oxidase, the activation status of Rac and the level of the NADPH oxidase subunit p67phox were measured. Angiotensin II markedly increased Rac activity and the levels of p67phox in zinc-treated neurons and astrocytes in a PD123319-dependent manner. The present study shows that the

Remobilisation of industrial lead depositions in ash during Australian wildfires.

PubMed

Wu, Liqin; Taylor, Mark Patrick; Handley, Heather K

2017-12-01

This study examined the recycling of lead (Pb) in ash from wildfires, its source and potential contribution to environmental contamination. Ash from wildfires was collected from four Australian sites following uncontrolled fires during 2012 to 2013 close to major urban populations in Sydney (New South Wales), Hobart (Tasmania) and Adelaide (South Australia). The samples were analysed for their total Pb concentration and Pb isotopic composition to determine the sources of Pb and the extent, if any, of industrial contamination and its recycling into the ecosystem. Median ash concentrations (23mg/kg) released from a wildfire close to Australia's largest city, Sydney, exceeded the median ash Pb concentrations from wildfires from the less populated locations of Hobart, Adelaide and NSW Central Coast. Lead isotopic compositions of Duffys Forest wildfire ash demonstrate that anthropogenic inputs from legacy leaded petrol depositions were the predominant source of contamination. Despite the cessation of leaded petrol use in Australia in 2002, historic petrol Pb deposits continue to be a substantial source of contamination in ash: petrol Pb contributed 35% of the Pb in the Woy Woy ash, 73% in Duffys Forest ash, 39% in Forcett ash and 5% in Cherryville ash. The remobilisation of legacy industrial Pb depositions by wildfires in ash results in it being a persistent and problematic contaminant in contemporary environmental systems because of its known toxicity. Copyright © 2017 Elsevier B.V. All rights reserved.

Origin, Extent, and Thickness of Quaternary Geologic Units in the Willamette Valley, Oregon

USGS Publications Warehouse

O'Connor, Jim E.; Sarna-Wojcicki, Andrei M.; Wozniak, Karl C.; Polette, Danial J.; Fleck, Robert J.

2001-01-01

Stratigraphic and chronologic information collected for Quaternary deposits in the Willamette Valley, Oregon, provides a revised stratigraphic framework that serves as a basis for a 1:250,000-scale map, as well as for thickness estimates of widespread Quaternary geologic units. We have mapped 11 separate Quaternary units that are differentiated on the basis of stratigraphic, topographic, pedogenic, and hydrogeologic properties. In summation, these units reflect four distinct episodes in the Quaternary geologic development of the Willamette Valley: 1) Fluvial sands and gravels that underlie terraces flanking lowland margins and tributary valleys were probably deposited between 2.5 and 0.5 million years ago. They are the oldest widespread surficial Quaternary deposits in the valley. Their present positions and preservation are undoubtedly due to postdepositional tectonic deformation - either by direct tectonic uplift of valley margins, or by regional tectonic controls on local base level. 2) Tertiary and Quaternary excavation or tectonic lowering of the Willamette Valley accommodated as much as 500 m (meters) of lacustrine and fluvial fill. Beneath the lowland floor, much of the upper 10 to 50 m of fill is Quaternary sand and gravel deposited by braided channel systems in subhorizontal sheets 2 to 10 m thick. These deposits grade to gravel fans 40 to 100 m thick where major Cascade Range rivers enter the valley and are traced farther upstream as much thinner valley trains of coarse gravel. The sand and gravel deposits have ages that range from greater than 420,000 to about 12,000 years old. A widely distributed layer of sand and gravel deposited at about 12 ka (kiloannum, thousands of years before the present) is looser and probably more permeable than older sand and gravel. Stratigraphic exposures and drillers' logs indicate that this late Pleistocene unit is mostly between 5 and 20 m thick where it has not been subsequently eroded by the Willamette River and its

Influence of sputtering deposition parameters on electrical and optical properties of aluminium-doped zinc oxide thin films for photovoltaic applications

NASA Astrophysics Data System (ADS)

Krawczak, Ewelina; Agata, Zdyb; Gulkowski, Slawomir; Fave, Alain; Fourmond, Erwann

2017-11-01

Transparent Conductive Oxides (TCOs) characterized by high visible transmittance and low electrical resistivity play an important role in photovoltaic technology. Aluminum doped zinc oxide (AZO) is one of the TCOs that can find its application in thin film solar cells (CIGS or CdTe PV technology) as well as in other microelectronic applications. In this paper some optical and electrical properties of ZnO:Al thin films deposited by RF magnetron sputtering method have been investigated. AZO layers have been deposited on the soda lime glass substrates with use of variable technological parameters such as pressure in the deposition chamber, power applied and temperature during the process. The composition of AZO films has been investigated by EDS method. Thickness and refraction index of the deposited layers in dependence on certain technological parameters of sputtering process have been determined by spectroscopic ellipsometry. The measurements of transmittance and sheet resistance were also performed.

Hydrogeologic framework of Antelope Valley and Bedell Flat, Washoe County, west-central Nevada

USGS Publications Warehouse

Berger, D.L.; Ponce, D.A.; Ross, W.C.

2001-01-01

Description of the hydrogeologic framework of Antelope Valley and Bedell Flat in west-central Nevada adds to the general knowledge of regional ground-water flow north of the Reno-Sparks metropolitan area. The hydrogeologic framework is defined by the rocks and deposits that transmit ground water or impede its movement and by the combined thickness of Cenozoic deposits. When data are lacking about the subsurface geology of an area, geophysical methods can be used to provide additional information. In this study, gravimetric and seismic-refraction methods were used to infer the form of structural features and to estimate the thickness of Cenozoic deposits in each of the two valleys. In Antelope Valley, the thickness of these deposits probably does not exceed about 300 feet, suggesting that ground-water storage in the basin-fill aquifer is limited. Beneath Bedell Flat is an elongated, northeast-trending structural depression in the pre-Cenozoic basement; the maximum thickness of Cenozoic deposits is about 2,500 feet beneath the south-central part of the valley. Shallow ground water in the northwest corner of Bedell Flat may be a result of decreasing depth to the pre-Cenozoic basement.

Post-glacial rock avalanches in the Obersee Valley, Glarner Alps, Switzerland

NASA Astrophysics Data System (ADS)

Nagelisen, Jan; Moore, Jeffrey R.; Vockenhuber, Christoph; Ivy-Ochs, Susan

2015-06-01

The geological record of prehistoric rock avalanches provides invaluable data for assessing the hazard posed by these rare but destructive mass movements. Here we investigate two large rock avalanches in the Obersee valley of the Glarner Alps, Switzerland, providing detailed mapping of landslide and related Quaternary phenomena, revised volume estimates for each event, and surface exposure dating of rock avalanche deposits. The Rautispitz rock avalanche originated from the southern flank of the Obersee valley, releasing approximately 91 million m3 of limestone on steeply-dipping bedding planes. Debris had maximum horizontal travel distance of ~ 5000 m, a fahrboeschung angle (relating fall height to length) of 18°, and was responsible for the creation of Lake Obersee; deposits are more than 130 m thick in places. The Platten rock avalanche encompassed a source volume of 11 million m3 sliding from the northern flank of the Obersee valley on similar steeply-dipping limestone beds (bedrock forms a syncline under the valley). Debris had a maximum horizontal travel distance of 1600 m with a fahrboeschung angle of 21°, and is more than 80 m thick in places. Deposits of the Platten rock avalanche are superposed atop those from the Rautispitz event at the end of the Obersee valley where they dam Lake Haslensee. Runout for both events was simulated using the dynamic analysis code DAN3D; results showed excellent match to mapped deposit extents and thickness and helped confirm the hypothesized single-event failure scenarios. 36Cl cosmogenic nuclide surface exposure dating of 13 deposited boulders revealed a Younger Dryas age of 12.6 ± 1.0 ka for the Rautispitz rock avalanche and a mid-Holocene age of 6.1 ± 0.8 ka for the Platten rock avalanche. A seismological trigger is proposed for the former event due to potentially correlated turbidite deposits in nearby Lake Zurich.

Syn-deformational features of Carlin-type Au deposits

USGS Publications Warehouse

Peters, S.G.

2004-01-01

Syn-deformational ore deposition played an important role in some Carlin-type Au deposits according to field and laboratory evidence, which indicates that flow of Au-bearing fluids was synchronous with regional-scale deformation events. Gold-related deformation events linked to ore genesis were distinct from high-level, brittle deformation that is typical of many epithermal deposits. Carlin-type Au deposits, with brittle-ductile features, most likely formed during tectonic events that were accompanied by significant fluid flow. Interactive deformation-fluid processes involved brittle-ductile folding, faulting, shearing, and gouge development that were focused along illite-clay and dissolution zones caused by hydrothermal alteration. Alteration along these deformation zones resulted in increased porosity and enhancement of fluid flow, which resulted in decarbonated, significant dissolution, collapse, and volume and mass reduction. Carlin-type Au deposits commonly are hosted in Paleozoic and Mesozoic sedimentary rocks (limestone, siltstone, argillite, shale, and quartzite) on the margins of cratons. The sedimentary basins containing the host rocks underwent tectonic events that influenced the development of stratabound, structurally controlled orebodies. Published by Elsevier Ltd.

The effects of enhanced zinc on spatial memory and plaque formation in transgenic mice

USGS Publications Warehouse

Linkous, D.H.; Adlard, P.A.; Wanschura, P.B.; Conko, K.M.; Flinn, J.M.

2009-01-01

There is considerable evidence suggesting that metals play a central role in the pathogenesis of Alzheimer's disease. Reports suggest that elevated dietary metals may both precipitate and potentiate an Alzheimer's disease phenotype. Despite this, there remain few studies that have examined the behavioral consequences of elevated dietary metals in wild type and Alzheimer's disease animals. To further investigate this in the current study, two separate transgenic models of AD (Tg2576 and TgCRND8), together with wild type littermates were administered 10 ppm (0.153 mM) Zn. Tg2576 animals were maintained on a zinc-enriched diet both pre- and postnatally until 11 months of age, while TgCRND8 animals were treated for five months following weaning. Behavioral testing, consisting of "Atlantis" and "moving" platform versions of the Morris water maze, were conducted at the end of the study, and tissues were collected for immunohistochemical analysis of amyloid-β burden. Our data demonstrate that the provision of a zinc-enriched diet potentiated Alzheimer-like spatial memory impairments in the transgenic animals and was associated with reduced hippocampal amyloid-β plaque deposits. Zinc-related behavioral deficits were also demonstrated in wild type mice, which were sometimes as great as those present in the transgenic animals. However, zinc-related cognitive impairments in transgenic mice were greater than the summation of zinc effects in the wild type mice and the transgene effects.

Assessment of Lead and Beryllium deposition and adsorption to exposed stream channel sediments

NASA Astrophysics Data System (ADS)

Pawlowski, E.; Karwan, D. L.

2016-12-01

The fallout radionuclides Beryllium-7 and Lead-210 have been shown to be effective sediment tracers that readily bind to particles. The adsorption capacity has primarily been assessed in marine and coastal environments with an important assumption being the radionuclides' uniform spatial distribution as fallout from the atmosphere. This neglects localized storm events that may mine stratospheric reserves creating variable distributions. To test this assumption atmospheric deposition is collected at the University of Minnesota St. Paul Campus weather station during individual storm events and subsequently analyzed for Beryllium-7 and Lead-210. This provides further insight into continental effects on radionuclide deposition. The study of Beryllium-7 and Lead-210 adsorption in marine and coastal environments has provided valuable insights into the processes that influence the element's binding to particles but research has been limited in freshwater river environments. These environments have greater variation in pH, iron oxide content, and dissolved organic carbon (DOC) levels which have been shown to influence the adsorption of Beryllium and Lead in marine settings. This research assesses the adsorption of Beryllium and Lead to river sediments collected from in-channel deposits by utilizing batch experiments that mimic the stream conditions from which the deposits were collected. Soils were collected from Difficult Run, VA, and the West Swan River, MN. Agitating the soils in a controlled solution of known background electrolyte and pH while varying the level of iron oxides and DOC in step provides a better understanding of the sorption of Lead and Beryllium under the conditions found within freshwater streams. Pairing the partitioning of Lead and Beryllium with their inputs to streams via depositional processes, from this study and others, allows for their assessment as possible sediment tracers and age-dating tools within the respective watersheds.

Behavior and impact of sulfur incorporation in Zinc Oxysulfide alloy grown by metal organic chemical vapor deposition

NASA Astrophysics Data System (ADS)

Ma, Jingrui; Tang, Kun; Mao, Haoyuan; Ye, Jiandong; Zhu, Shunming; Xu, Zhonghua; Yao, Zhengrong; Gu, Shulin; Zheng, Youdou

2018-03-01

Highly mismatched ZnO1-xSx:N alloy films with various x were deposited on c-plane sapphire substrates by a near-equilibrium method, metal-organic chemical vapor deposition. The sulfur concentration in the films could be tuned by changing the flow rate of H2S during the growth process. The films that could maintain single phase have an upper limit for x ∼ 0.15, which is smaller than the x values obtained from other non-equilibrium-grown samples (x ∼ 0.23). When x > 0.15, phases other than the wurtzite ZnO (W-ZnO) one appeared. Those phases were ascribed to the sulfur-diluted W-ZnO like phase, low x W-ZnO like phase, and high x W-ZnS like phase. The S contents in different phase has been determined by using Vegard's law and the X-ray photoelectron spectroscopy. Meanwhile, the compositional dependence of the bandgap energy in the ZnO1-xSx alloyed material has been investigated and studied comparing with other reported results. The dispersed bowing parameter b and the mechanism of the phase separation in samples grown by both the near-equilibrium method and the non-equilibrium one have also been discussed based on the difference of the atomic radius and electronegativity of the oxygen and sulfur atoms. Furthermore, the Raman and photoluminescence spectra have shown that the sulfur incorporation may suppress zinc interstitials related defects, while the oxygen vacancies related defects may be easily formed at the same time. These results indicate that ZnO1-xSx films could be beneficial to the realization of p-type doping in ZnO, although no obvious p-type characteristic has been attained in the work yet.

Magnesium, zinc, and chromium levels in children, adolescents, and young adults with type 1 diabetes.

PubMed

Lin, Ching-Chiang; Tsweng, Guey-Ju; Lee, Cheng-Fa; Chen, Bai-Hsiun; Huang, Yeou-Lih

2016-08-01

Several trace elements are involved in insulin signal transduction and glucose metabolism. Our aim for this present study was to determine the levels of three important elements-magnesium, chromium, and zinc-as well as one oxidative stress marker-malondialdehyde (MDA)-in young type 1 diabetic patients at different periods of their growth, and to realize the relationships between trace elements, oxidative stress, and growth stages. A total of 88 patients with type 1 diabetes mellitus in different growth stages and 76 gender- and age-matched healthy subjects were included in this study. The levels of MDA were measured through HPLC using a C-18 column. Zinc, magnesium, and chromium concentrations in serum were assessed using atomic absorption spectrophotometry. We found higher levels of blood malondialdehyde (MDA; p < 0.001), significantly lower levels of magnesium (p < 0.001), and no differences in zinc and chromium levels (p = 0.153 and 0.515, respectively) in younger type 1 diabetic subjects relative to those of control subjects. Only 3.4% (3/88) of younger diabetic subjects exhibited hypomagnesemia; similar results were obtained when comparing different subgroups: children, adolescents, and adults. We also observed no differences in the levels of the three elements between the genders and among the growth stages (p > 0.05) of the diabetic subjects. There were no correlations between the three trace elements and HbA1C, diabetes duration, and insulin dose/BMI (all p > 0.05), but there was a significant difference between zinc levels and insulin dose/BMI (p = 0.043) in the diabetic patients. We found elevated blood MDA, decreased magnesium, and no changes in zinc and chromium levels in younger type 1 diabetic subjects relative to those of control subjects. Only 3.4% of younger diabetic subjects exhibited hypomagnesemia. Whether magnesium supplementation is suitable for improving insulin sensitivity and decreasing oxidative stress and inflammation will

NORTH END ROADLESS AREA, ARIZONA.

USGS Publications Warehouse

Drewes, Harald; Bigsby, P.R.

1984-01-01

Studies conducted in the North End Roadless Area, Arizona indicate probable or substantiated metallic mineral-resource potential in about one-fifth of the area. The area has potential for disseminated or stockwork-type molybdenum mineralization, copper-lead-zinc-silver veins, lead-zinc-silver limestone replacement deposits, and tungsten-bearing contact metamorphic skarn deposits. The area also contains cement rock and marble dimension stone, but has only slight promise for the occurrence of petroleum and natural gas.

Placer tin deposits in central Alaska

USGS Publications Warehouse

Chapman, Robert Mills; Coats, Robert Roy; Payne, Thomas G.

1963-01-01

Placer tin, in the form of cassiterite (Sn02) and (or) tinstone (fragments including cassiterite and some vein or rock material), is known or reported in deposits that have been prospected or mined for placer gold in four areas adjacent to the Yukon River in central Alaska, 120 to 240 miles west of Fairbanks. These areas are: the Morelock Creek area, on the north side of the Yukon River about 30 miles upstream from Tanana; the Moran Dome area, about 16 miles north of the Yukon River and 25 miles northwest of Tanana; the Mason Creek area, on the north side of the Yukon River about 36 miles west of Tanana; and the Ruby-Long area, on the south side of the Yukon River near Ruby and about 40 miles east of Galena. The only extensive placer mining in these areas has been in the Ruby-Long area. Other placer deposits including some cassiterite are known in central Alaska but are not discussed in this report. Bedrock in these areas is predominantly schist of various types with some associated greenstone and other metamorphic rocks. Some granite is exposed in the Moran Dome and Ruby-Long areas and in areas close to Morelock and Mason Creeks. Barren, milky quartz veins and veinlets transecting the metamorphic rocks are common. No cassiterite was found in the bedrock, and no bedrock source of the tin has been reported. In the Moran Dome and Mason Creek areas, and in part of the Ruby-Long area, tourmaline is present in the rocks of the tin-bearing drainage basins, and apparently absent elsewhere in these areas. The placer deposits are in both valley floor and bench alluvium, which are predominantly relatively thin, rarely exceeding a thickness of 30 feet. Most of the alluvium deposits are not perennially frozen. In the Morelock Creek area tin-bearing deposits are 5 to 5? miles above the mouth of the creek, and meager evidence indicates that cassiterite and gold are present in Morelock Creek valley and some of the tributaries both upstream and downstream from these deposits. The

The Zinc Transporter Zip5 (Slc39a5) Regulates Intestinal Zinc Excretion and Protects the Pancreas against Zinc Toxicity

PubMed Central

Geiser, Jim; De Lisle, Robert C.; Andrews, Glen K.

2013-01-01

Background ZIP5 localizes to the baso-lateral membranes of intestinal enterocytes and pancreatic acinar cells and is internalized and degraded coordinately in these cell-types during periods of dietary zinc deficiency. These cell-types are thought to control zinc excretion from the body. The baso-lateral localization and zinc-regulation of ZIP5 in these cells are unique among the 14 members of the Slc39a family and suggest that ZIP5 plays a role in zinc excretion. Methods/Principal Findings We created mice with floxed Zip5 genes and deleted this gene in the entire mouse or specifically in enterocytes or acinar cells and then examined the effects on zinc homeostasis. We found that ZIP5 is not essential for growth and viability but total knockout of ZIP5 led to increased zinc in the liver in mice fed a zinc-adequate (ZnA) diet but impaired accumulation of pancreatic zinc in mice fed a zinc-excess (ZnE) diet. Loss-of-function of enterocyte ZIP5, in contrast, led to increased pancreatic zinc in mice fed a ZnA diet and increased abundance of intestinal Zip4 mRNA. Finally, loss-of-function of acinar cell ZIP5 modestly reduced pancreatic zinc in mice fed a ZnA diet but did not impair zinc uptake as measured by the rapid accumulation of 67zinc. Retention of pancreatic 67zinc was impaired in these mice but the absence of pancreatic ZIP5 sensitized them to zinc-induced pancreatitis and exacerbated the formation of large cytoplasmic vacuoles containing secretory protein in acinar cells. Conclusions These studies demonstrate that ZIP5 participates in the control of zinc excretion in mice. Specifically, they reveal a paramount function of intestinal ZIP5 in zinc excretion but suggest a role for pancreatic ZIP5 in zinc accumulation/retention in acinar cells. ZIP5 functions in acinar cells to protect against zinc-induced acute pancreatitis and attenuate the process of zymophagy. This suggests that it may play a role in autophagy. PMID:24303081

The zinc dyshomeostasis hypothesis of Alzheimer's disease.

PubMed

Craddock, Travis J A; Tuszynski, Jack A; Chopra, Deepak; Casey, Noel; Goldstein, Lee E; Hameroff, Stuart R; Tanzi, Rudolph E

2012-01-01

Alzheimer's disease (AD) is the most common form of dementia in the elderly. Hallmark AD neuropathology includes extracellular amyloid plaques composed largely of the amyloid-β protein (Aβ), intracellular neurofibrillary tangles (NFTs) composed of hyper-phosphorylated microtubule-associated protein tau (MAP-tau), and microtubule destabilization. Early-onset autosomal dominant AD genes are associated with excessive Aβ accumulation, however cognitive impairment best correlates with NFTs and disrupted microtubules. The mechanisms linking Aβ and NFT pathologies in AD are unknown. Here, we propose that sequestration of zinc by Aβ-amyloid deposits (Aβ oligomers and plaques) not only drives Aβ aggregation, but also disrupts zinc homeostasis in zinc-enriched brain regions important for memory and vulnerable to AD pathology, resulting in intra-neuronal zinc levels, which are either too low, or excessively high. To evaluate this hypothesis, we 1) used molecular modeling of zinc binding to the microtubule component protein tubulin, identifying specific, high-affinity zinc binding sites that influence side-to-side tubulin interaction, the sensitive link in microtubule polymerization and stability. We also 2) performed kinetic modeling showing zinc distribution in extra-neuronal Aβ deposits can reduce intra-neuronal zinc binding to microtubules, destabilizing microtubules. Finally, we 3) used metallomic imaging mass spectrometry (MIMS) to show anatomically-localized and age-dependent zinc dyshomeostasis in specific brain regions of Tg2576 transgenic, mice, a model for AD. We found excess zinc in brain regions associated with memory processing and NFT pathology. Overall, we present a theoretical framework and support for a new theory of AD linking extra-neuronal Aβ amyloid to intra-neuronal NFTs and cognitive dysfunction. The connection, we propose, is based on β-amyloid-induced alterations in zinc ion concentration inside neurons affecting stability of polymerized

Dendrite-Free Nanocrystalline Zinc Electrodeposition from an Ionic Liquid Containing Nickel Triflate for Rechargeable Zn-Based Batteries.

PubMed

Liu, Zhen; Cui, Tong; Pulletikurthi, Giridhar; Lahiri, Abhishek; Carstens, Timo; Olschewski, Mark; Endres, Frank

2016-02-18

Metallic zinc is a promising anode material for rechargeable Zn-based batteries. However, the dendritic growth of zinc has prevented practical applications. Herein it is demonstrated that dendrite-free zinc deposits with a nanocrystalline structure can be obtained by using nickel triflate as an additive in a zinc triflate containing ionic liquid. The formation of a thin layer of Zn-Ni alloy (η- and γ-phases) on the surface and in the initial stages of deposition along with the formation of an interfacial layer on the electrode strongly affect the nucleation and growth of zinc. A well-defined and uniform nanocrystalline zinc deposit with particle sizes of about 25 nm was obtained in the presence of Ni(II) . Further, it is shown that the nanocrystalline Zn exhibits a high cycling stability even after 50 deposition/stripping cycles. This strategy of introducing an inorganic metal salt in ionic liquid electrolytes can be considered as an efficient way to obtain dendrite-free zinc. © 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

The Type VI Secretion System Engages a Redox-Regulated Dual-Functional Heme Transporter for Zinc Acquisition.

PubMed

Si, Meiru; Wang, Yao; Zhang, Bing; Zhao, Chao; Kang, Yiwen; Bai, Haonan; Wei, Dawei; Zhu, Lingfang; Zhang, Lei; Dong, Tao G; Shen, Xihui

2017-07-25

The type VI secretion system was recently reported to be involved in zinc acquisition, but the underlying mechanism remains unclear. Here, we report that Burkholderia thailandensis T6SS4 is involved in zinc acquisition via secretion of a zinc-scavenging protein, TseZ, that interacts with the outer membrane heme transporter HmuR. We find that HmuR is a redox-regulated dual-functional transporter that transports heme iron under normal conditions but zinc upon sensing extracellular oxidative stress, triggered by formation of an intramolecular disulfide bond. Acting as the first line of defense against oxidative stress, HmuR not only guarantees an immediate response to the changing environment but also provides a fine-tuned mechanism that allows a gradual response to perceived stress. The T6SS/HmuR-mediated active zinc transport system is also involved in bacterial virulence and contact-independent bacterial competition. We describe a sophisticated bacterial zinc acquisition mechanism affording insights into the role of metal ion transport systems. Copyright © 2017 The Author(s). Published by Elsevier Inc. All rights reserved.

Grizzly Valley fault system, Sierra Valley, CA

USGS Publications Warehouse

Gold, Ryan; Stephenson, William; Odum, Jack; Briggs, Rich; Crone, Anthony; Angster, Steve

2012-01-01

The Grizzly Valley fault system (GVFS) strikes northwestward across Sierra Valley, California and is part of a network of active, dextral strike-slip faults in the northern Walker Lane (Figure 1). To investigate Quaternary motion across the GVFS, we analyzed high-resolution (0.25 m) airborne LiDAR data (Figure 2) in combination with six, high-resolution, P-wave, seismic-reflection profiles [Gold and others, 2012]. The 0.5- to 2.0-km-long seismic-reflection profiles were sited orthogonal to suspected tectonic lineaments identified from previous mapping and our analysis of airborne LiDAR data. To image the upper 400–700 m of subsurface stratigraphy of Sierra Valley (Figure 3), we used a 230-kg accelerated weight drop source. Geophone spacing ranged from 2 to 5 m and shots were co-located with the geophones. The profiles reveal a highly reflective, deformed basal marker that we interpret to be the top of Tertiary volcanic rocks, overlain by a 120- to 300-m-thick suite of subhorizontal reflectors we interpret as Plio-Pleistocene lacustrine deposits. Three profiles image the principle active trace of the GVFS, which is a steeply dipping fault zone that offsets the volcanic rocks and the basin fill (Figures 4 & 5).

Low zinc in drinking water is associated with the risk of type 1 diabetes in children.

PubMed

Samuelsson, Ulf; Oikarinen, Sami; Hyöty, Heikki; Ludvigsson, Johnny

2011-05-01

To explore if drinking water may influence the development of type 1 diabetes in children, either via enterovirus spread via drinking water or quality of drinking water related to acidity or concentration of certain minerals. One hundred and forty-two families with a child with diabetes and who lived either in seven municipalities with a high annual diabetes incidence during 1977-2001 and in six municipalities with the lowest incidence during those 25 yr were asked to participate. Three hundred and seventy-three families in these communities were used as controls. The families filled a 200-mL plastic bottle with their tap drinking water and returned it by mail. The water samples were analyzed for pH, zinc, iron, nitrate, nitrite, nitrate-nitrogen and nitrite-nitrogen, and occurrence of enterovirus RNA. Enterovirus RNA was not found in the tap water samples. The concentration of zinc, nitrate, and nitrate-nitrogen was lower in the municipalities with high incidence of type 1 diabetes. The water samples from families with a child with diabetes had lower concentration of zinc than water samples from control families. Low zinc in drinking water is associated with the risk of developing type 1 diabetes during childhood. Enterovirus does not seem to be spread via drinking water in a country with modern water works. © 2010 John Wiley & Sons A/S.

Mapping Aquifer Systems with Airborne Electromagnetics in the Central Valley of California

NASA Astrophysics Data System (ADS)

Knight, R. J.; Smith, R.; Asch, T. H.; Abraham, J.; Cannia, J.; Fogg, G. E.; Viezzoli, A.

2016-12-01

The Central Valley of California is an important agricultural region struggling to meet the need for irrigation water. Recent periods of drought have significantly reduced the delivery of surface water, resulting in extensive pumping of groundwater. This has exacerbated an already serious problem in the Central Valley, where a number of areas have experienced declining water levels for several decades leading to ongoing concerns about depletion of aquifers and impacts on ecosystems, as well as subsidence of the ground surface. The overdraft has been so significant, that there are now approximately140 million acre-feet (MAF) of unused groundwater storage in the Central Valley, storage that could be used to complement the 42 MAF of surface storage. The alluvial sedimentary geology of the Central Valley is typically composed of more than 50 to 70 percent fine-grained deposits dominated by silt and clay beds. These fine grained deposits can block potential recharge, and are associated with the large amount of observed subsidence. Fortunately, the geologic processes that formed the region created networks of sand and gravel which provide both a supply of water and pathways for recharge from the surface to the aquifers. The challenge is to find these sand and gravel deposits and thus identify optimal locations for surface spreading techniques so that recharge could be dramatically increased, and re-pressurization of the confined aquifer networks could be accomplished. We have acquired 100 line kilometers of airborne electromagnetic data over an area in the San Joaquin Valley, imaging the subsurface hydrostratigraphy to a depth of 500 m with spatial resolution on the order of meters to tens of meters. Following inversion of the data to obtain resistivity models along the flight lines, we used lithology logs in the area to transform the models to images displaying the distribution of sand and gravel, clay, and mixed fine and coarse materials. The quality of the data and

40 CFR 440.100 - Applicability; description of the copper, lead, zinc, gold, silver, and molybdenum ores subcategory.

Code of Federal Regulations, 2013 CFR

2013-07-01

... process alone or in conjunction with other processes, for the beneficiation of copper, lead, zinc, gold, silver, or molybdenum ores, or any combination of these ores; (3) Mines and mills that use dump, heap, in-situ leach, or vat-leach processes to extract copper from ores or ore waste materials; and (4) Mills...

40 CFR 440.100 - Applicability; description of the copper, lead, zinc, gold, silver, and molybdenum ores subcategory.

Code of Federal Regulations, 2012 CFR

2012-07-01

... process alone or in conjunction with other processes, for the beneficiation of copper, lead, zinc, gold, silver, or molybdenum ores, or any combination of these ores; (3) Mines and mills that use dump, heap, in-situ leach, or vat-leach processes to extract copper from ores or ore waste materials; and (4) Mills...

40 CFR 440.100 - Applicability; description of the copper, lead, zinc, gold, silver, and molybdenum ores subcategory.

Code of Federal Regulations, 2014 CFR

2014-07-01

... process alone or in conjunction with other processes, for the beneficiation of copper, lead, zinc, gold, silver, or molybdenum ores, or any combination of these ores; (3) Mines and mills that use dump, heap, in-situ leach, or vat-leach processes to extract copper from ores or ore waste materials; and (4) Mills...

Relation of morphology of electrodeposited zinc to ion concentration profile

NASA Technical Reports Server (NTRS)

May, C. E.; Kautz, H. E.; Sabo, B. B.

1977-01-01

The morphology of electrodeposited zinc was studied with special attention to the ion concentration profile. The initial concentrations were 9M hydroxide ion and 1.21M zincate. Current densities were 6.4 to 64 mA/sq cm. Experiments were run with a horizontal cathode which was observed in situ using a microscope. The morphology of the zinc deposit was found to be a function of time as well as current density; roughly, the log of the transition time from mossy to large crystalline type deposit is inversely proportional to current density. Probe electrodes indicated that the electrolyte in the cathode chamber was mixed by self inducted convection. However, relatively large concentration gradients of the involved species existed across the boundary layer of the cathode. Analysis of the data suggests that the morphology converts from mossy to large crystalline when the hydroxide activity on the cathode surface exceeds about 12 M. Other experiments show that the pulse discharge technique had no effect on the morphology in the system where the bulk concentration of the electrolyte was kept homogeneous via self induced convection.

Determination of silver, bismuth, cadmium, copper, lead, and zinc in geologic materials by atomic absorption spectrometry with tricaprylylmethylammonium chloride

USGS Publications Warehouse

Viets, J.G.

1978-01-01

Interferences commonly encountered in the determination of silver, bismuth, cadmium, copper, lead, and zinc at crustal abundance levels are effectively eliminated using a rapid, sensitive, organic extraction technique. A potassium chlorate-hydrochloric acid digestion solubilizes the metals not tightly bound in the silicate lattice of rocks, soils, and stream sediments. The six metals are selectively extracted into a 10% Aliquat 336-MIBK organic phase in the presence of ascorbic acid and potassium iodide. Metals in the organic extract are determined by flame atomic absorption spectrometry to the 0.02-ppm level for silver, cadmium, copper, and zinc and to the 0.2-ppm level for bismuth and lead with a maximum relative standard deviation of 18.8% for known reference samples. An additional hydrofluoric acid digestion may be used to determine metals substituted in the silicate lattice.

Amorphous indium-tin-zinc oxide films deposited by magnetron sputtering with various reactive gases: Spatial distribution of thin film transistor performance

DOE Office of Scientific and Technical Information (OSTI.GOV)

Jia, Junjun; Torigoshi, Yoshifumi; Shigesato, Yuzo, E-mail: yuzo@chem.aoyama.ac.jp

This work presents the spatial distribution of electrical characteristics of amorphous indium-tin-zinc oxide film (a-ITZO), and how they depend on the magnetron sputtering conditions using O{sub 2}, H{sub 2}O, and N{sub 2}O as the reactive gases. Experimental results show that the electrical properties of the N{sub 2}O incorporated a-ITZO film has a weak dependence on the deposition location, which cannot be explained by the bombardment effect of high energy particles, and may be attributed to the difference in the spatial distribution of both the amount and the activity of the reactive gas reaching the substrate surface. The measurement for themore » performance of a-ITZO thin film transistor (TFT) also suggests that the electrical performance and device uniformity of a-ITZO TFTs can be improved significantly by the N{sub 2}O introduction into the deposition process, where the field mobility reach to 30.8 cm{sup 2} V{sup –1} s{sup –1}, which is approximately two times higher than that of the amorphous indium-gallium-zinc oxide TFT.« less

Mercury Wet Scavenging and Deposition Differences by Precipitation Type.

PubMed

Kaulfus, Aaron S; Nair, Udaysankar; Holmes, Christopher D; Landing, William M

2017-03-07

We analyze the effect of precipitation type on mercury wet deposition using a new database of individual rain events spanning the contiguous United States. Measurements from the Mercury Deposition Network (MDN) containing single rainfall events were identified and classified into six precipitation types. Mercury concentrations in surface precipitation follow a power law of precipitation depth that is modulated by precipitation system morphology. After controlling for precipitation depth, the highest mercury deposition occurs in supercell thunderstorms, with decreasing deposition in disorganized thunderstorms, quasi-linear convective systems (QLCS), extratropical cyclones, light rain, and land-falling tropical cyclones. Convective morphologies (supercells, disorganized, and QLCS) enhance wet deposition by a factor of at least 1.6 relative to nonconvective morphologies. Mercury wet deposition also varies by geographic region and season. After controlling for other factors, we find that mercury wet deposition is greater over high-elevation sites, seasonally during summer, and in convective precipitation.

Hydrogeologic framework of the Wood River Valley aquifer system, south-central Idaho

USGS Publications Warehouse

Bartolino, James R.; Adkins, Candice B.

2012-01-01

metamorphosed to some degree, thus rock types and their relationships vary over distance. Quaternary-age sediment and basalt compose the primary source of groundwater in the Wood River Valley aquifer system. These Quaternary deposits can be divided into three units: a coarse-grained sand and gravel unit, a fine-grained silt and clay unit, and a single basalt unit. The fine- and coarse-grained units were primarily deposited as alluvium derived from glaciation in the surrounding mountains and upper reaches of tributary canyons. The basalt unit is found in the southeastern Bellevue fan area and is composed of two flows of different ages. Most of the groundwater produced from the Wood River Valley aquifer system is from the coarse-grained deposits. The altitude of the pre-Quaternary bedrock surface in the Wood River Valley was compiled from about 1,000 well-driller reports for boreholes drilled to bedrock and about 70 Horizontal-to-Vertical Spectral Ratio (HVSR) ambient-noise measurements. The bedrock surface generally mimics the land surface by decreasing down tributary canyons and the main valley from north to south; it ranges from more than 6,700 feet in Baker Creek to less than 4,600 feet in the central Bellevue fan. Most of the south-central portion of the Bellevue fan is underlain by an apparent topographically closed area on the bedrock surface that appears to drain to the southwest towards Stanton Crossing. Quaternary sediment thickness ranges from less than a foot on main and tributary valley margins to about 350 feet in the central Bellevue fan. Hydraulic conductivity for 81 wells in the study area was estimated from well-performance tests reported on well-driller reports. Estimated hydraulic conductivity for 79 wells completed in alluvium ranges from 1,900 feet per day (ft/d) along Warm Springs Creek to less than 1 ft/d in upper Croy Canyon. A well completed in bedrock had an estimated hydraulic conductivity value of 10 ft/d, one well completed in basalt had a value of

Neogene palaeochannel deposits in Sudan - Remnants of a trans-Saharan river system?

NASA Astrophysics Data System (ADS)

Bussert, Robert; Eisawi, Ali A. M.; Hamed, Basher; Babikir, Ibrahim A. A.

2018-05-01

The start of Nile-type trans-Saharan drainage systems in NE Africa during the Cenozoic is disputed. Stratigraphical and sedimentological data in Egypt are partly in conflict with the uplift history of potential source areas of water and sediment in East Africa. Here, we investigate outcrops of the Wadi Awatib Conglomerate in Sudan that provide the first evidence of northerly flowing Neogene rivers in the region. Dimension and relief of basal erosion surfaces, overall geometry of deposits and palaeocurrent indicators demonstrate that the deposits represent the fill of northward-oriented incised valleys. The conglomerates were deposited in deep gravel-bed rivers, by hyperconcentrated flows, tractions carpets and gravel bars, primarily during heavily sediment-laden floods of probably monsoonal origin. Stratigraphical and geomorphological relationships show that the deposits are between Eocene and Pliocene in age. Considering the structural history of the region and periods in the Cenozoic with palaeoclimatic conditions suitable for the production and transport of gravels, we hypothesize that the dramatic base-level fall during the Late Miocene Messinian salinity crisis in combination with a favorable palaeoclimate caused the incision of valleys and their subsequent filling with conglomerates. Sea-level change in the Mediterranean Sea and headward erosion of streams that were connected to the Egyptian Nile might have been the primary cause of valley incision and deposition of conglomerates, despite a location far inland from the coastline. We suggest that the deposits document a relatively young Neogene (Messinian to early Pliocene) trans-Saharan river system unrelated to uplift of the Ethiopian Plateau.

Isotope geochemistry of mercury in source rocks, mineral deposits and spring deposits of the California Coast Ranges, USA

NASA Astrophysics Data System (ADS)

Smith, Christopher N.; Kesler, Stephen E.; Blum, Joel D.; Rytuba, James J.

2008-05-01

We present here the first study of the isotopic composition of mercury in rocks, ore deposits, and active spring deposits from the California Coast Ranges, a part of Earth's crust with unusually extensive evidence of mercury mobility and enrichment. The Franciscan Complex and Great Valley Sequence, which form the bedrock in the California Coast Ranges, are intruded and overlain by Tertiary volcanic rocks including the Clear Lake Volcanic Sequence. These rocks contain two types of mercury deposits, hot-spring deposits that form at shallow depths (< 300 m) and silica-carbonate deposits that extend to depths of 1000 m. Active springs and geothermal areas continue to precipitate Hg and Au and are modern analogues to the fossil hydrothermal systems preserved in the ore deposits. The Franciscan Complex and Great Valley Sequence contain clastic sedimentary rocks with higher concentrations of mercury than volcanic rocks of the Clear Lake Volcanic Field. Mean mercury isotopic compositions ( δ202Hg) for all three rock units are similar, although the range of values in Franciscan Complex rocks is greater than in either Great Valley or Clear Lake rocks. Hot spring and silica-carbonate mercury deposits have similar average mercury isotopic compositions that are indistinguishable from averages for the three rock units, although δ202Hg values for the mercury deposits have a greater variance than the country rocks. Precipitates from spring and geothermal waters in the area have similarly large variance and a mean δ202Hg value that is significantly lower than the ore deposits and rocks. These observations indicate that there is little or no isotopic fractionation (< ± 0.5‰) during release of mercury from its source rocks into hydrothermal solutions. Isotopic fractionation does appear to take place during transport and concentration of mercury in deposits, however, especially in their uppermost parts. Boiling of hydrothermal fluids, separation of a mercury-bearing CO 2 vapor