Condensation heat transfer correlation for water-ethanol vapor mixture flowing through a plate heat exchanger

NASA Astrophysics Data System (ADS)

Zhou, Weiqing; Hu, Shenhua; Ma, Xiangrong; Zhou, Feng

2018-04-01

Condensation heat transfer coefficient (HTC) as a function of outlet vapor quality was investigated using water-ethanol vapor mixture of different ethanol vapor concentrations (0%, 1%, 2%, 5%, 10%, 20%) under three different system pressures (31 kPa, 47 kPa, 83 kPa). A heat transfer coefficient was developed by applying multiple linear regression method to experimental data, taking into account the dimensionless numbers which represents the Marangoni condensation effects, such as Re, Pr, Ja, Ma and Sh. The developed correlation can predict the condensation performance within a deviation range from -22% to 32%. Taking PHE's characteristic into consideration and bringing in Ma number and Sh number, a new correlation was developed, which showed a much more accurate prediction, within a deviation from -3.2% to 7.9%.

Vapor Flow Patterns During a Start-Up Transient in Heat Pipes

NASA Technical Reports Server (NTRS)

Issacci, F.; Ghoniem, N, M.; Catton, I.

1996-01-01

The vapor flow patterns in heat pipes are examined during the start-up transient phase. The vapor core is modelled as a channel flow using a two dimensional compressible flow model. A nonlinear filtering technique is used as a post process to eliminate the non-physical oscillations of the flow variables. For high-input heat flux, multiple shock reflections are observed in the evaporation region. The reflections cause a reverse flow in the evaporation and circulations in the adiabatic region. Furthermore, each shock reflection causes a significant increase in the local pressure and a large pressure drop along the heat pipe.

Vapor-Phase Stoichiometry and Heat Treatment of CdTe Starting Material for Physical Vapor Transport

NASA Technical Reports Server (NTRS)

Su, Ching-Hua; Sha, Yi-Gao; Lehoczky, S. L.; Liu, Hao-Chieh; Fang, Rei; Brebrick, R. F.

1998-01-01

Six batches of CdTe, having total amounts of material from 99 to 203 g and gross mole fraction of Te, X(sub Te), 0.499954-0.500138, were synthesized from pure Cd and Te elements. The vapor-phase stoichiometry of the assynthesized CdTe batches was determined from the partial pressure of Te2, P(sub Te2) using an optical absorption technique. The measured vapor compositions at 870 C were Te-rich for all of the batches with partial pressure ratios of Cd to Te2, P(sub Cd)/P(sub Te2), ranging from 0.00742 to 1.92. After the heat treatment of baking under dynamic vacuum at 870 C for 8 min, the vapor-phase compositions moved toward that of the congruent sublimation, i.e. P(sub Cd)/P(sub Te2) = 2.0, with the measured P(sub Cd)/P(sub Te2) varying from 1.84 to 3.47. The partial pressure measurements on one of the heat-treated samples also showed that the sample remained close to the congruent sublimation condition over the temperature range 800-880 C.

Macroscopic modeling for heat and water vapor transfer in dry snow by homogenization.

PubMed

Calonne, Neige; Geindreau, Christian; Flin, Frédéric

2014-11-26

Dry snow metamorphism, involved in several topics related to cryospheric sciences, is mainly linked to heat and water vapor transfers through snow including sublimation and deposition at the ice-pore interface. In this paper, the macroscopic equivalent modeling of heat and water vapor transfers through a snow layer was derived from the physics at the pore scale using the homogenization of multiple scale expansions. The microscopic phenomena under consideration are heat conduction, vapor diffusion, sublimation, and deposition. The obtained macroscopic equivalent model is described by two coupled transient diffusion equations including a source term arising from phase change at the pore scale. By dimensional analysis, it was shown that the influence of such source terms on the overall transfers can generally not be neglected, except typically under small temperature gradients. The precision and the robustness of the proposed macroscopic modeling were illustrated through 2D numerical simulations. Finally, the effective vapor diffusion tensor arising in the macroscopic modeling was computed on 3D images of snow. The self-consistent formula offers a good estimate of the effective diffusion coefficient with respect to the snow density, within an average relative error of 10%. Our results confirm recent work that the effective vapor diffusion is not enhanced in snow.

An analysis of the vapor flow and the heat conduction through the liquid-wick and pipe wall in a heat pipe with single or multiple heat sources

NASA Technical Reports Server (NTRS)

Chen, Ming-Ming; Faghri, Amir

1990-01-01

A numerical analysis is presented for the overall performance of heat pipes with single or multiple heat sources. The analysis includes the heat conduction in the wall and liquid-wick regions as well as the compressibility effect of the vapor inside the heat pipe. The two-dimensional elliptic governing equations in conjunction with the thermodynamic equilibrium relation and appropriate boundary conditions are solved numerically. The solutions are in agreement with existing experimental data for the vapor and wall temperatures at both low and high operating temperatures.

Vapor Compression and Thermoelectric Heat Pumps for a Cascade Distillation Subsystem: Design and Experiment

NASA Technical Reports Server (NTRS)

Erickson, Lisa R.; Ungar, Eugene K.

2012-01-01

Humans on a spacecraft require significant amounts of water for drinking, food, hydration, and hygiene. Maximizing the reuse of wastewater while minimizing the use of consumables is critical for long duration space exploration. One of the more promising consumable-free methods of reclaiming wastewater is the distillation/condensation process used in the Cascade Distillation Subsystem (CDS). The CDS heats wastewater to the point of vaporization then condenses and cools the resulting water vapor. The CDS wastewater flow requires heating for evaporation and the product water flow requires cooling for condensation. Performing the heating and cooling processes separately would require two separate units, each of which would demand large amounts of electrical power. Mass, volume, and power efficiencies can be obtained by heating the wastewater and cooling the condensate in a single heat pump unit. The present work describes and compares two competing heat pump methodologies that meet the needs of the CDS: 1) a series of mini compressor vapor compression cycles and 2) a thermoelectric heat exchanger. In the paper, the CDS system level requirements are outlined, the designs of the two heat pumps are described in detail, and the results of heat pump analysis and performance tests are provided. The mass, volume, and power requirement for each heat pump option is compared and the advantages and disadvantages of each system are listed.

The development of a performance-enhancing additive for vapor-compression heat pumps

DOE Office of Scientific and Technical Information (OSTI.GOV)

Grzyll, L.R.; Scaringe, R.P.; Gottschlich, J.M.

1997-12-31

This paper describes the testing results of a vapor-compression heat pump operating with HFC-134a refrigerant and a performance-enhancing additive. Preliminary bench-top testing of this additive, when added to polyolester (POE) lubricant and HFC-134a refrigerant, showed surprising enhancements to system COP. To further investigate this finding, the authors designed and fabricated a vapor-compression heat pump test stand for the 3--5 ton range. The authors investigated the effect of different concentrations of this additive on various system performance parameters such as cooling capacity, compressor power requirement, pressure ratio, compressor pressure difference, compressor isentropic efficiency, refrigerant flow rate, and heat exchanger performance. Themore » authors investigated various heat source and heat sink conditions to simulate air-conditioning and heat pump operating conditions. To investigate the effect of this additive on compressor lubrication and life, the authors performed compressor life tests (with scroll and reciprocating compressors), and had lubrication wear tests performed with various concentrations of the additive in the POE lubricant.« less

Means and method for vapor generation

DOEpatents

Carlson, Larry W.

1984-01-01

A liquid, in heat transfer contact with a surface heated to a temperature well above the vaporization temperature of the liquid, will undergo a multiphase (liquid-vapor) transformation from 0% vapor to 100% vapor. During this transition, the temperature driving force or heat flux and the coefficients of heat transfer across the fluid-solid interface, and the vapor percentage influence the type of heating of the fluid--starting as "feedwater" heating where no vapors are present, progressing to "nucleate" heating where vaporization begins and some vapors are present, and concluding with "film" heating where only vapors are present. Unstable heating between nucleate and film heating can occur, accompanied by possibly large and rapid temperature shifts in the structures. This invention provides for injecting into the region of potential unstable heating and proximate the heated surface superheated vapors in sufficient quantities operable to rapidly increase the vapor percentage of the multiphase mixture by perhaps 10-30% and thereby effectively shift the multiphase mixture beyond the unstable heating region and up to the stable film heating region.

Means and method for vapor generation

DOEpatents

Carlson, L.W.

A liquid, in heat transfer contact with a surface heated to a temperature well above the vaporization temperature of the liquid, will undergo a multiphase (liquid-vapor) transformation from 0% vapor to 100% vapor. During this transition, the temperature driving force or heat flux and the coefficients of heat transfer across the fluid-solid interface, and the vapor percentage influence the type of heating of the fluid - starting as feedwater heating where no vapors are present, progressing to nucleate heating where vaporization begins and some vapors are present, and concluding with film heating where only vapors are present. Unstable heating between nucleate and film heating can occur, accompanied by possibly large and rapid temperature shifts in the structures. This invention provides for injecting into the region of potential unstable heating and proximate the heated surface superheated vapors in sufficient quantities operable to rapidly increase the vapor percentage of the multiphase mixture by perhaps 10 to 30% and thereby effectively shift the multiphase mixture beyond the unstable heating region and up to the stable film heating region.

Enhanced soil vapor extraction with radio frequency heating

DOE Office of Scientific and Technical Information (OSTI.GOV)

Bowders, J.J.; Daniel, D.E.

1997-12-31

A field demonstration of enhanced soil vapor extraction using radio frequency (RF) heating to remove semi-volatiles from the subsurface is nearing completion. The site, a fire training area consisting of a well-graded sand with silt, had initial petroleum hydrocarbon concentrations up to 22,000 mg/kg. The treatment volume contained approximately 80 kg of diesel range organics (DRO, C-12 to C-20). Vapors are extracted from a central well while RF energy is supplied by two applicators positioned in vertical wells on either side of the extraction well. Temperatures in the center of the treatment zone have reached 140{degrees}C and at the treatmentmore » perimeter (2m radius) have reached 100{degrees}C to 120{degrees}C. Analyses of the condensed offgas show the chromatogram matches that for DRO with constituents up to C-20. Preliminary mass balance indicates that more than 65 kg of DRO have been removed from the site. The first 77 days of RF heating operation are reported in this paper. The project is continuing and final results will be reported at a later time.« less

Heat treatment's effects on hydroxyapatite powders in water vapor and air atmosphere

NASA Astrophysics Data System (ADS)

Karabulut, A.; Baştan, F. E.; Erdoǧan, G.; Üstel, F.

2015-03-01

Hydroxyapatite (HA; Ca10(PO4)6(OH)2) is the main chemical constituent of bone tissue (~70%) as well as HA which is a calcium phosphate based ceramic material forms inorganic tissue of bone and tooth as hard tissues is used in production of prosthesis for synthetic bone, fractured and broken bone restoration, coating of metallic biomaterials and dental applications because of its bio compatibility. It is known that Hydroxyapatite decomposes with high heat energy after heat treatment. Therefore hydroxyapatite powders that heated in water vapor will less decomposed phases and lower amorphous phase content than in air atmosphere. In this study high purity hydroxyapatite powders were heat treated with open atmosphere furnace and water vapor atmosphere with 900, 1000, 1200 °C. Morphology of same powder size used in this process by SEM analyzed. Chemical structures of synthesized coatings have been examined by XRD. The determination of particle size and morphological structure of has been characterized by Particle Sizer, and SEM analysis, respectively. Weight change of sample was recorded by thermogravimetric analysis (TGA) during heating and cooling.

Vapor chamber with hollow condenser tube heat sink

NASA Astrophysics Data System (ADS)

Ong, K. S.; Haw, P. L.; Lai, K. C.; Tan, K. H.

2017-04-01

Heat pipes are heat transfer devices capable of transferring large quantities of heat effectively and efficiently. A vapor chamber (VC) is a flat heat pipe. A novel VC with hollow condenser tubes embedded on the top of it is proposed. This paper reports on the experimental thermal performance of three VC devices embedded with hollow tubes and employed as heat sinks. The first device consisted of a VC with a single hollow tube while the other two VCs had an array of multi-tubes with different tube lengths. All three devices were tested under natural and force air convection cooling. An electrical resistance heater was employed to provide power inputs of 10 and 40 W. Surface temperatures were measured with thermocouple probes at different locations around the devices. The results show that temperatures increased with heater input while total device thermal resistances decreased. Force convection results in lower temperatures and lower resistance. Dry-out occurs at high input power and with too much condensing area. There appears to be an optimum fill ratio which depended upon dimensions of the VC and also heating power.

Potential heat exchange fluids for use in sulfuric acid vaporizers

NASA Technical Reports Server (NTRS)

Lawson, D. D.; Petersen, G. R.

1981-01-01

A series of liquids have been screened as candidate heat exchange fluids for service in thermochemical cycles that involve the vaporization of sulfuric acid. The required chemical and physical criteria of the liquids is described with the results of some preliminary high temperature test data presented.

Simulation of the early startup period of high-temperature heat pipes from the frozen state by a rarefied vapor self-diffusion model

NASA Technical Reports Server (NTRS)

Cao, Y.; Faghri, A.

1993-01-01

The heat pipe startup process is described physically and is divided into five periods for convenience of analysis. The literature survey revealed that none of the previous attempts to simulate the heat pipe startup process numerically were successful, since the rarefied vapor flow in the heat pipe was not considered. Therefore, a rarefied vapor self-diffusion model is proposed, and the early startup periods, in which the rarefied vapor flow is dominant within the heat pipe, are first simulated numerically. The numerical results show that large vapor density gradients existed along the heat pipe length, and the vapor flow reaches supersonic velocities when the density is extremely low. The numerical results are compared with the experimental data of the early startup period with good agreement.

Effect of narrow band nonuniformity on unsteady heat up of water vapor under radiation-conduction combined heat transfer

DOE Office of Scientific and Technical Information (OSTI.GOV)

Okamoto, Tatsuyuki; Tanaka, Tomohiro; Morimune, Atsushi

Effect of narrow band nonuniformity on unsteady heat up process of water vapor under radiation-conduction combined heat transfer is examined by comparing the result of numerical simulations with and without incorporation of narrow band nonuniformity. The authors propose a rational and comprehensive computational approach for incorporating the narrow band nonuniformity into numerical simulations of radiative heat transfer when the considered field is nonisothermal. Results of examination exhibited that the contribution of radiative heat transfer to the heat up rate of water vapor may be almost twice overestimated, if the narrow band nonuniformity effect is neglected. Separate analyses of radiative energymore » attributed to wall emission and gas emission clarified that the absorption of wall emission is overestimated and, on the contrary, the absorption of radiation energy emitted by water vapor itself is underestimated if the narrow band nonuniformity is neglected. The reason why such over- or under-estimation is induced is understood by examining the influence of line overlap parameter on the transmittance averaged within a narrow band. Smaller value of line overlap parameter {gamma}/d means more violent narrow band nonuniformity. The broken lines show the narrow band transmittance for flat incident power spectrum, and the solid lines show that for the radiative emission from the absorbing gas itself. It is also clarified that the disregard of the narrow band nonuniformity give rise to serious error in the estimation of absorption rate of wall and gas emission even in the case where the disregard of narrow band nonuniformity bring little change to the temperature distribution. The results illustrated in this paper suggest that the narrow band nonuniformity should not be neglected.« less

A simple heat-pipe cell for X-ray absorption spectrometry of potassium vapor

NASA Astrophysics Data System (ADS)

Pres̆eren, R.; Kodre, A.; Arc̆on, I.; Padez̆nik Gomils̆ek, J.; Hribar, M.

1999-01-01

The construction and operation of a simple high-temperature X-ray absorption cell for potassium vapor is described. The principle of "spectroscopic heat pipe" is exploited to separate kapton windows, indispensable for good transmission in the low-energy region, from the hot and aggressive vapor. High-resolution spectrum of the K-edge region of atomic potassium reveals fingerprints of multielectron photoexcitations.

Molecular dynamic approach to the study of the intense heat and mass transfer processes on the vapor-liquid interface

NASA Astrophysics Data System (ADS)

Levashov, V. Yu; Kamenov, P. K.

2017-10-01

The paper is devoted to research of the heat and mass transfer processes on the vapor-liquid interface. These processes can be realized for example at metal tempering, accidents at nuclear power stations, followed by the release of the corium into the heat carrier, getting hot magma into the water during volcanic eruptions and other. In all these examples the vapor film can arise on the heated body surface. In this paper the vapor film formation process will be considered with help of molecular dynamics simulation methods. The main attention during this process modeling will be focused on the subject of the fluid and vapor interactions with the heater surface. Another direction of this work is to study of the processes inside the droplet that may take place as result of impact of the high-power laser radiation. Such impact can lead to intensive evaporation and explosive destruction of the droplet. At that the duration of heat and mass transfer processes in droplet substance is tens of femtoseconds. Thus, the methods of molecular dynamics simulation can give the possibilities describe the heat and mass transfer processes in the droplet and the vapor phase formation.

Induction heating pure vapor source of high temperature melting point materials on electron cyclotron resonance ion source.

PubMed

Kutsumi, Osamu; Kato, Yushi; Matsui, Yuuki; Kitagawa, Atsushi; Muramatsu, Masayuki; Uchida, Takashi; Yoshida, Yoshikazu; Sato, Fuminobu; Iida, Toshiyuki

2010-02-01

Multicharged ions that are needed are produced from solid pure material with high melting point in an electron cyclotron resonance ion source. We develop an evaporator by using induction heating (IH) with multilayer induction coil, which is made from bare molybdenum or tungsten wire without water cooling and surrounding the pure vaporized material. We optimize the shapes of induction coil and vaporized materials and operation of rf power supply. We conduct experiment to investigate the reproducibility and stability in the operation and heating efficiency. IH evaporator produces pure material vapor because materials directly heated by eddy currents have no contact with insulated materials, which are usually impurity gas sources. The power and the frequency of the induction currents range from 100 to 900 W and from 48 to 23 kHz, respectively. The working pressure is about 10(-4)-10(-3) Pa. We measure the temperature of the vaporized materials with different shapes, and compare them with the result of modeling. We estimate the efficiency of the IH vapor source. We are aiming at the evaporator's higher melting point material than that of iron.

Induction heating pure vapor source of high temperature melting point materials on electron cyclotron resonance ion sourcea)

NASA Astrophysics Data System (ADS)

Kutsumi, Osamu; Kato, Yushi; Matsui, Yuuki; Kitagawa, Atsushi; Muramatsu, Masayuki; Uchida, Takashi; Yoshida, Yoshikazu; Sato, Fuminobu; Iida, Toshiyuki

2010-02-01

Multicharged ions that are needed are produced from solid pure material with high melting point in an electron cyclotron resonance ion source. We develop an evaporator by using induction heating (IH) with multilayer induction coil, which is made from bare molybdenum or tungsten wire without water cooling and surrounding the pure vaporized material. We optimize the shapes of induction coil and vaporized materials and operation of rf power supply. We conduct experiment to investigate the reproducibility and stability in the operation and heating efficiency. IH evaporator produces pure material vapor because materials directly heated by eddy currents have no contact with insulated materials, which are usually impurity gas sources. The power and the frequency of the induction currents range from 100to900W and from 48to23kHz, respectively. The working pressure is about 10-4-10-3Pa. We measure the temperature of the vaporized materials with different shapes, and compare them with the result of modeling. We estimate the efficiency of the IH vapor source. We are aiming at the evaporator's higher melting point material than that of iron.

Potential heat exchange fluids for use in sulfuric acid vaporizers

NASA Technical Reports Server (NTRS)

Lawson, D. D.; Petersen, G. R.

1979-01-01

A series of perhalocarbons are proposed as candidate heat exchange fluids for service in thermochemical cycles for hydrogen production that involve direct contact of the fluid with sulfuric acid and vaporization of the acid. The required chemical and physical criteria of the liquids are described and the results of some preliminary high temperature test data are presented.

Operation characteristic of a heat pump of mechanical vapor recompression propelled by fans and its performance analysis applied to waste-water treatment

NASA Astrophysics Data System (ADS)

Weike, Pang; Wenju, Lin; Qilin, Pan; Wenye, Lin; Qunte, Dai; Luwei, Yang; Zhentao, Zhang

2014-01-01

In this paper, a set of heat pump (called as Mechanical Vapor Recompression, MVR) propelled by a centrifugal fan is tested and it shows some special characteristic when it works together with a falling film evaporator. Firstly, an analysis of the fan's suction and discharge parameters at stable state, such as its pressure and temperature, indicates that a phenomenon of wet compression is probably to appear during vapor compression. As a result, superheat after saturated vapor is compressed is eliminated, which reduces discharge temperature of the system. It is because drops boil away and absorb the super heat into their latent heat during vapor compression. Meanwhile, drops in the suction vapor add to the compressed vapor, which increase the given heat of the MVR heat pump. Next, assistant electric heat could adjust and keep steady of the operating pressure and temperature of an MVR heat pump. With the evaporation temperature up to be high, heat balance is broken and supplement heat needs to increase. Thirdly, the performance of an MVR heat pump is affect by the balance of falling film and evaporation that has an effect on heat transfer. Then, two parameters standing for the performance are measured as it runs in practical condition. The two important parameters are consumptive electricity power and productive water capacity. According to theoretical work in ideal condition by calculation and fan's input power by measure as running, adiabatic efficiency (ηad) of a centrifugal fan is calculated when it is applied in a heat pump of MVR. Following, based on ηad, practical SMER and COP of an MVR heat pump are discovered to be correlative with it. Finally, in dependence on productive water in theory and in practice, displacement efficiency (ηv) of centrifugal fans is obtained when compressing vapor, and so provide some references of matching a fan for an MVR heat pump. On the other hand, it is helpful to research and develop MVR heat pumps, and also to check

A numerical analysis of the effects of conjugate heat transfer, vapor compressibility, and viscous dissipation in heat pipes

NASA Astrophysics Data System (ADS)

Faghri, Amir; Chen, Ming-Ming

1989-10-01

The effects of conjugate heat transfer, vapor compressibility, and viscous dissipation in heat pipes are discussed. The accuracy of the partially parabolic versus the elliptic presentation of the governing equations is also examined. The results show that the axial wall conduction has a tendency to make the temperature distribution more uniform for heat pipes with large ratios of pipe wall to effective liquid-wick thermal conductivity. The compressible and incompressible models show very close agreement for the total pressure drop, while the local pressure variations along the heat pipe are quite different for these two models when the radial Reynolds number at the interface is high.

Vapor generator wand

NASA Technical Reports Server (NTRS)

Robelen, David B. (Inventor)

1996-01-01

A device for producing a stream of vapor for wind tunnel airflow visualization is described. An electrically conductive heating tube is used to resistively heat a vapor producing liquid. The heating and delivery systems are integrated to allow the device to present a small cross section to the air flow, thereby reducing disturbances due to the device. The simplicity of the design allows for inexpensive implementation and construction. The design is readily scaled for use in various wind tunnel applications. The device may also find uses in manufacturing, producing a vapor for deposition on a substrate.

Atmospheric solar heating rate in the water vapor bands

NASA Technical Reports Server (NTRS)

Chou, Ming-Dah

1986-01-01

The total absorption of solar radiation by water vapor in clear atmospheres is parameterized as a simple function of the scaled water vapor amount. For applications to cloudy and hazy atmospheres, the flux-weighted k-distribution functions are computed for individual absorption bands and for the total near-infrared region. The parameterization is based upon monochromatic calculations and follows essentially the scaling approximation of Chou and Arking, but the effect of temperature variation with height is taken into account in order to enhance the accuracy. Furthermore, the spectral range is extended to cover the two weak bands centered at 0.72 and 0.82 micron. Comparisons with monochromatic calculations show that the atmospheric heating rate and the surface radiation can be accurately computed from the parameterization. Comparisons are also made with other parameterizations. It is found that the absorption of solar radiation can be computed reasonably well using the Goody band model and the Curtis-Godson approximation.

Vapor bubble evolution on a heated surface containing open microchannels

NASA Astrophysics Data System (ADS)

Forster, Christopher J.; Glezer, Ari; Smith, Marc K.

2011-11-01

Power electronics require cooling technologies capable of high heat fluxes at or below the operating temperatures of these devices. Boiling heat transfer is an effective choice for such cooling, but it is limited by the critical heat flux (CHF), which is typically near 125 W/cm2 for pool boiling of water on a flat plate at standard pressure and gravity. One method of increasing CHF is to incorporate an array of microchannels into the heated surface. Microchannels have been experimentally shown to improve CHF, and the goal of this study is to determine the primary mechanisms associated with the microchannels that allow for the increased CHF. While the use of various microstructures is not new, the emphasis of previous work has been on heat transfer aspects, as opposed to the fluid dynamics inside and in the vicinity of the microchannels. This work considers the non-isothermal fluid motion during bubble growth and departure by varying channel geometry, spacing, and heat flux input using a level-set method including vaporization and condensation. These results and the study of the underlying mechanisms will aid in the design optimization of microchannel-based cooling devices. Supported by ONR.

DETERMINATION OF HEAT TRANSFER COEFFICIENTS FOR FRENCH PLASTIC SEMEN STRAW SUSPENDED IN STATIC NITROGEN VAPOR OVER LIQUID NITROGEN.

PubMed

Santo, M V; Sansinena, M; Chirife, J; Zaritzky, N

2015-01-01

The use of mathematical models describing heat transfer during the freezing process is useful for the improvement of cryopreservation protocols. A widespread practice for cryopreservation of spermatozoa of domestic animal species consists of suspending plastic straws in nitrogen vapor before plunging into liquid nitrogen. Knowledge of surface heat transfer coefficient (h) is mandatory for computational modelling; however, h values for nitrogen vapor are not available. In the present study, surface heat transfer coefficients for plastic French straws immersed in nitrogen vapor over liquid nitrogen was determined; vertical and horizontal positions were considered. Heat transfer coefficients were determined from the measurement of time-temperature curves and from numerical solution of heat transfer partial differential equation under transient conditions using finite elements. The h values experimentally obtained for horizontal and vertically placed straws were compared to those calculated using correlations based on the Nusselt number for natural convection. For horizontal straws the average obtained value was h=12.5 ± 1.2 W m(2) K and in the case of vertical straws h=16 ± 2.48 W m(2) K. The numerical simulation validated against experimental measurements, combined with accurate h values provides a reliable tool for the prediction of freezing curves of semen-filled straws immersed in nitrogen vapor. The present study contributes to the understanding of the cryopreservation techniques for sperm freezing based on engineering concepts, improving the cooling protocols and the manipulation of the straws.

What Is the Boiling Point and Heat of Vaporization of Sulfuric Acid?

ERIC Educational Resources Information Center

Myers, R. Thomas

1983-01-01

Discusses the values presented in various handbooks for the boiling point and heat of vaporization of sulfuric acid, noting discrepencies. Analyzes various approaches to data presentation, discussing the data on sulfuric acid in light of the Trouton constant. Points out the need for a more critical use of tables. (JM)

Pure Material Vapor Source by Induction Heating Evaporator for an Electron Cyclotron Resonance Ion Source

NASA Astrophysics Data System (ADS)

Matsui, Y.; Watanabe, T.; Satani, T.; Muramatsu, M.; Tanaka, K.; Kitagawa, A.; Yoshida, Y.; Sato, F.; Kato, Y.; Iida, T.

2008-11-01

Multiply charged iron ions are produced from solid pure material in an electron cyclotron resonance (ECR) ion source. We develop an evaporator by using induction heating with the induction coil which is made from bare molybdenum wire and surrounding the pure iron rod. We optimize the shape of induction heating coil and operation of rf power supply. We conduct experiment to investigate reproducibility and stability in the operation and heating efficiency. Induction heating evaporator produces pure material vapor, because materials directly heated by eddy currents have non-contact with insulated materials which are impurity gas sources. The power and the frequency of the induction currents range from 100 to 900 W and from 48 to 23 kHz, respectively. The working pressure is about 10-4 to 10-3 Pa. We measure temperature of iron rod and film deposition rate by depositing iron vapor to crystal oscillator. We confirm stability and reproducibility of evaporator enough to conduct experiment in ECR ion source. We can obtain required temperature of iron under maximum power of power supply. We are aiming the evaporator higher melting point material than iron.

Forced convection heat transfer to air/water vapor mixtures

NASA Technical Reports Server (NTRS)

Richards, D. R.; Florschuetz, L. W.

1984-01-01

Heat transfer coefficients were measured using both dry and humid air in the same forced convection cooling scheme and were compared using appropriate nondimensional parameters (Nusselt, Prandtl and Reynolds numbers). A forced convection scheme with a complex flow field, two dimensional arrays of circular jets with crossflow, was utilized with humidity ratios (mass ratio of water vapor to air) up to 0.23. The dynamic viscosity, thermal conductivity and specific heat of air, steam and air/steam mixtures are examined. Methods for determining gaseous mixture properties from the properties of their pure components are reviewed as well as methods for determining these properties with good confidence. The need for more experimentally determined property data for humid air is discussed. It is concluded that dimensionless forms of forced convection heat transfer data and empirical correlations based on measurements with dry air may be applied to conditions involving humid air with the same confidence as for the dry air case itself, provided that the thermophysical properties of the humid air mixtures are known with the same confidence as their dry air counterparts.

Condensation of vapor bubble in subcooled pool

NASA Astrophysics Data System (ADS)

Horiuchi, K.; Koiwa, Y.; Kaneko, T.; Ueno, I.

2017-02-01

We focus on condensation process of vapor bubble exposed to a pooled liquid of subcooled conditions. Two different geometries are employed in the present research; one is the evaporation on the heated surface, that is, subcooled pool boiling, and the other the injection of vapor into the subcooled pool. The test fluid is water, and all series of the experiments are conducted under the atmospheric pressure condition. The degree of subcooling is ranged from 10 to 40 K. Through the boiling experiment, unique phenomenon known as microbubble emission boiling (MEB) is introduced; this phenomenon realizes heat flux about 10 times higher than the critical heat flux. Condensation of the vapor bubble is the key phenomenon to supply ambient cold liquid to the heated surface. In order to understand the condensing process in the MEB, we prepare vapor in the vapor generator instead of the evaporation on the heated surface, and inject the vapor to expose the vapor bubble to the subcooled liquid. Special attention is paid to the dynamics of the vapor bubble detected by the high-speed video camera, and on the enhancement of the heat transfer due to the variation of interface area driven by the condensation.

Heat flow in vapor dominated areas of the Yellowstone Plateau volcanic field: implications for the thermal budget of the Yellowstone Caldera

USGS Publications Warehouse

Hurwitz, Shaul; Harris, Robert; Werner, Cynthia Anne; Murphy, Fred

2012-01-01

Characterizing the vigor of magmatic activity in Yellowstone requires knowledge of the mechanisms and rates of heat transport between magma and the ground surface. We present results from a heat flow study in two vapor dominated, acid-sulfate thermal areas in the Yellowstone Caldera, the 0.11 km2 Obsidian Pool Thermal Area (OPTA) and the 0.25 km2 Solfatara Plateau Thermal Area (SPTA). Conductive heat flux through a low permeability layer capping large vapor reservoirs is calculated from soil temperature measurements at >600 locations and from laboratory measurements of soil properties. The conductive heat output is 3.6 ± 0.4 MW and 7.5 ± 0.4 MW from the OPTA and the SPTA, respectively. The advective heat output from soils is 1.3 ± 0.3 MW and 1.2 ± 0.3 MW from the OPTA and the SPTA, respectively and the heat output from thermal pools in the OPTA is 6.8 ± 1.4 MW. These estimates result in a total heat output of 11.8 ± 1.4 MW and 8.8 ± 0.4 MW from OPTA and SPTA, respectively. Focused zones of high heat flux in both thermal areas are roughly aligned with regional faults suggesting that faults in both areas serve as conduits for the rising acid vapor. Extrapolation of the average heat flux from the OPTA (103 ± 2 W·m−2) and SPTA (35 ± 3 W·m−2) to the ~35 km2 of vapor dominated areas in Yellowstone yields 3.6 and 1.2 GW, respectively, which is less than the total heat output transported by steam from the Yellowstone Caldera as estimated by the chloride inventory method (4.0 to 8.0 GW).

Pressure intelligent control strategy of Waste heat recovery system of converter vapors

NASA Astrophysics Data System (ADS)

Feng, Xugang; Wu, Zhiwei; Zhang, Jiayan; Qian, Hong

2013-01-01

The converter gas evaporative cooling system is mainly used for absorbing heat in the high temperature exhaust gas which produced by the oxygen blowing reaction. Vaporization cooling steam pressure control system of converter is a nonlinear, time-varying, lagging behind, close coupling of multivariable control object. This article based on the analysis of converter operation characteristics of evaporation cooling system, of vaporization in a production run of pipe pressure variation and disturbance factors.For the dynamic characteristics of the controlled objects,we have improved the conventional PID control scheme.In Oxygen blowing process, we make intelligent control by using fuzzy-PID cascade control method and adjusting the Lance,that it can realize the optimization of the boiler steam pressure control.By design simulation, results show that the design has a good control not only ensures drum steam pressure in the context of security, enabling efficient conversion of waste heat.And the converter of 1800 flue gas through pipes and cool and dust removal also can be cooled to about 800. Therefore the converter haze evaporative cooling system has achieved to the converter haze temperature decrease effect and enhanced to the coal gas returns-ratio.

Stratified vapor generator

DOEpatents

Bharathan, Desikan [Lakewood, CO; Hassani, Vahab [Golden, CO

2008-05-20

A stratified vapor generator (110) comprises a first heating section (H.sub.1) and a second heating section (H.sub.2). The first and second heating sections (H.sub.1, H.sub.2) are arranged so that the inlet of the second heating section (H.sub.2) is operatively associated with the outlet of the first heating section (H.sub.1). A moisture separator (126) having a vapor outlet (164) and a liquid outlet (144) is operatively associated with the outlet (124) of the second heating section (H.sub.2). A cooling section (C.sub.1) is operatively associated with the liquid outlet (144) of the moisture separator (126) and includes an outlet that is operatively associated with the inlet of the second heating section (H.sub.2).

Improved efficiency and precise temperature control of low-frequency induction-heating pure iron vapor source on ECR ion source

NASA Astrophysics Data System (ADS)

Kato, Y.; Takenaka, T.; Yano, K.; Kiriyama, R.; Kurisu, Y.; Nozaki, D.; Muramatsu, M.; Kitagawa, A.; Uchida, T.; Yoshida, Y.; Sato, F.; Iida, T.

2012-11-01

Multiply charged ions to be used prospectively are produced from solid pure material in an electron cyclotron resonance ion source (ECRIS). Recently a pure iron source is also required for the production of caged iron ions in the fullerene in order to control cells in vivo in bio-nano science and technology. We adopt directly heating iron rod by induction heating (IH) because it has non-contact with insulated materials which are impurity gas sources. We choose molybdenum wire for the IH coils because it doesn't need water cooling. To improve power efficiency and temperature control, we propose to the new circuit without previously using the serial and parallel dummy coils (SPD) for matching and safety. We made the circuit consisted of inductively coupled coils which are thin-flat and helix shape, and which insulates the IH power source from the evaporator. This coupling coils circuit, i.e. insulated induction heating coil transformer (IHCT), can be move mechanically. The secondary current can be adjusted precisely and continuously. Heating efficiency by using the IHCT is much higher than those of previous experiments by using the SPD, because leakage flux is decreased and matching is improved simultaneously. We are able to adjust the temperature in heating the vapor source around melting point. And then the vapor pressure can be controlled precisely by using the IHCT. We can control ±10K around 1500°C by this method, and also recognize to controlling iron vapor flux experimentally in the extreme low pressures. Now we come into next stage of developing induction heating vapor source for materials with furthermore high temperature melting points above 2000K with the IHCT, and then apply it in our ECRIS.

Improvement of efficiency and temperature control of induction heating vapor source on electron cyclotron resonance ion source.

PubMed

Takenaka, T; Kiriyama, R; Muramatsu, M; Kitagawa, A; Uchida, T; Kurisu, Y; Nozaki, D; Yano, K; Yoshida, Y; Sato, F; Kato, Y; Iida, T

2012-02-01

An electron cyclotron resonance ion source (ECRIS) is used to generate multicharged ions for many kinds of the fields. We have developed an evaporator by using induction heating method that can generate pure vapor from solid state materials in ECRIS. We develop the new matching and protecting circuit by which we can precisely control the temperature of the induction heating evaporator. We can control the temperature within ±15 °C around 1400 °C under the operation pressure about 10(-4) Pa. We are able to use this evaporator for experiment of synthesizing process to need pure vapor under enough low pressure, e.g., experiment of generation of endohedral Fe-fullerene at the ECRIS.

Finalize field testing of cold climate heat pump (CCHP) based on tandem vapor injection compressors

DOE Office of Scientific and Technical Information (OSTI.GOV)

Shen, Bo; Baxter, Van D.; Abdelaziz, Omar

2017-03-01

This report describes the system diagram and control algorithm of a prototype air-source cold climate heat pump (CCHP) using tandem vapor injection (VI) compressors. The prototype was installed in Fairbanks, Alaska and underwent field testing starting in 09/2016. The field testing results of the past six months, including compressor run time fractions, measured COPs and heating capacities, etc., are presented as a function of the ambient temperature. Two lessons learned are also reported.

Method and apparatus for vapor detection

NASA Technical Reports Server (NTRS)

Lerner, Melvin (Inventor); Hood, Lyal V. (Inventor); Rommel, Marjorie A. (Inventor); Pettitt, Bruce C. (Inventor); Erikson, Charles M. (Inventor)

1980-01-01

The method disclosed herein may be practiced by passing the vapors to be sampled along a path with halogen vapor, preferably chlorine vapor, heating the mixed vapors to halogenate those of the sampled vapors subject to halogenation, removing unreacted halogen vapor, and then sensing the vapors for organic halogenated compounds. The apparatus disclosed herein comprises means for flowing the vapors, both sample and halogen vapors, into a common path, means for heating the mixed vapors to effect the halogenation reaction, means for removing unreacted halogen vapor, and a sensing device for sensing halogenated compounds. By such a method and means, the vapors of low molecular weight hydrocarbons, ketones and alcohols, when present, such as methane, ethane, acetone, ethanol, and the like are converted, at least in part, to halogenated compounds, then the excess halogen removed or trapped, and the resultant vapors of the halogenated compounds sensed or detected. The system is highly sensitive. For example, acetone in a concentration of 30 parts per billion (volume) is readily detected.

Suppression of the sonic heat transfer limit in high-temperature heat pipes

NASA Astrophysics Data System (ADS)

Dobran, Flavio

1989-08-01

The design of high-performance heat pipes requires optimization of heat transfer surfaces and liquid and vapor flow channels to suppress the heat transfer operating limits. In the paper an analytical model of the vapor flow in high-temperature heat pipes is presented, showing that the axial heat transport capacity limited by the sonic heat transfer limit depends on the working fluid, vapor flow area, manner of liquid evaporation into the vapor core of the evaporator, and lengths of the evaporator and adiabatic regions. Limited comparisons of the model predictions with data of the sonic heat transfer limits are shown to be very reasonable, giving credibility to the proposed analytical approach to determine the effect of various parameters on the axial heat transport capacity. Large axial heat transfer rates can be achieved with large vapor flow cross-sectional areas, small lengths of evaporator and adiabatic regions or a vapor flow area increase in these regions, and liquid evaporation in the evaporator normal to the main flow.

Calibrated vapor generator source

DOEpatents

Davies, John P.; Larson, Ronald A.; Goodrich, Lorenzo D.; Hall, Harold J.; Stoddard, Billy D.; Davis, Sean G.; Kaser, Timothy G.; Conrad, Frank J.

1995-01-01

A portable vapor generator is disclosed that can provide a controlled source of chemical vapors, such as, narcotic or explosive vapors. This source can be used to test and calibrate various types of vapor detection systems by providing a known amount of vapors to the system. The vapor generator is calibrated using a reference ion mobility spectrometer. A method of providing this vapor is described, as follows: explosive or narcotic is deposited on quartz wool, placed in a chamber that can be heated or cooled (depending on the vapor pressure of the material) to control the concentration of vapors in the reservoir. A controlled flow of air is pulsed over the quartz wool releasing a preset quantity of vapors at the outlet.

Calibrated vapor generator source

DOEpatents

Davies, J.P.; Larson, R.A.; Goodrich, L.D.; Hall, H.J.; Stoddard, B.D.; Davis, S.G.; Kaser, T.G.; Conrad, F.J.

1995-09-26

A portable vapor generator is disclosed that can provide a controlled source of chemical vapors, such as, narcotic or explosive vapors. This source can be used to test and calibrate various types of vapor detection systems by providing a known amount of vapors to the system. The vapor generator is calibrated using a reference ion mobility spectrometer. A method of providing this vapor is described, as follows: explosive or narcotic is deposited on quartz wool, placed in a chamber that can be heated or cooled (depending on the vapor pressure of the material) to control the concentration of vapors in the reservoir. A controlled flow of air is pulsed over the quartz wool releasing a preset quantity of vapors at the outlet. 10 figs.

Partitioning of sublimation and evaporation from Lake Bonney using water vapor isotope and latent heat fluxes

NASA Astrophysics Data System (ADS)

Bellagamba, A. W.; Berkelhammer, M. B.; Winslow, L.; Peter, D.; Myers, K. F.

2017-12-01

The landscapes of the McMurdo Dry Valleys in Antarctica are characterized by a series of frozen lakes. Although the conditions in this region are severe, the lakes share common characteristics with lakes at glacial termini elsewhere. Geochemical and geomorphological evidence suggest these lakes have experienced large historical changes indicative of changes water balances. While part of these shifts in lake volume arise from changes in glacial inflow, they likely also reflect changes in the latent heat flux from the lake surfaces. Here we present a joint analysis of the stable isotopic ratio of surface ice/water and the water vapor flux over Dry Valley frozen lakes to ascertain the processes controlling water losses from the lake surfaces. We compare the isotopic ratio of the latent heat flux with the surface water isotopes to derive a fractionation factor associated with latent flux. This data is then used to provide insight into how much of the water vapor flux is sublimated versus evaporated, as well as how the sublimation and evaporative components of the flux change with synoptic weather. We used a Picarro L2130-I isotopic water analyzer to measure humidity and the isotopic ratio of water vapor at three heights over Lake Bonney in Taylor Valley, Antarctica and used the flux-gradient approach to convert the isotopic ratio of the vapor to an "isoflux". An on-site meteorological station recorded temperature, relative humidity and wind direction/intensity at two different heights above the lake and an infrared radiometer recorded lake skin temperature. These data were used to calculate the sensible and latent heat fluxes. The fractionation factor was close to 0, which indicates that sublimation was the primary component of the flux although evaporation became increasingly prominent following a katabatic wind event. The results suggest this technique could be an effective tool to study the sensitivity of latent heat fluxes to weather here and in other similar

Buoyancy-Driven Heat Transfer During Application of a Thermal Gradient for the Study of Vapor Deposition at Low Pressure Using and Ideal Gas

NASA Technical Reports Server (NTRS)

Frazier, D. O.; Hung, R. J.; Paley, M. S.; Penn, B. G.; Long, Y. T.

1996-01-01

A mathematical model has been developed to determine heat transfer during vapor deposition of source materials under a variety of orientations relative to gravitational accelerations. The model demonstrates that convection can occur at total pressures as low as 10-2 mm Hg. Through numerical computation, using physical material parameters of air, a series of time steps demonstrates the development of flow and temperature profiles during the course of vapor deposition. These computations show that in unit gravity vapor deposition occurs by transport through a fairly complicated circulating flow pattern when applying heat to the bottom of the vessel with parallel orientation with respect to the gravity vector. The model material parameters for air predict the effect of kinematic viscosity to be of the same order as thermal diffusivity, which is the case for Prandtl number approx. 1 fluids. Qualitative agreement between experiment and the model indicates that 6-(2-methyl-4-nitroanilino)-2,4-hexadiyn-l-ol (DAMNA) at these pressures indeed approximates an ideal gas at the experiment temperatures, and may validate the use of air physical constants. It is apparent that complicated nonuniform temperature distribution in the vapor could dramatically affect the homogeneity, orientation, and quality of deposited films. The experimental test i's a qualitative comparison of film thickness using ultraviolet-visible spectroscopy on films generated in appropriately oriented vapor deposition cells. In the case where heating of the reaction vessel occurs from the top, deposition of vapor does not normally occur by convection due to a stable stratified medium. When vapor deposition occurs in vessels heated at the bottom, but oriented relative to the gravity vector between these two extremes, horizontal thermal gradients induce a complex flow pattern. In the plane parallel to the tilt axis, the flow pattern is symmetrical and opposite in direction from that where the vessel is

High-temperature multipass cell for infrared spectroscopy of heated gases and vapors.

PubMed

Bartlome, R; Baer, M; Sigrist, M W

2007-01-01

In absorption spectroscopy, infrared spectra of heated gases or condensed samples in the vapor phase are usually recorded with a single pass heated gas cell. This device exhibits two orders of magnitude lower sensitivity than the high-temperature multipass cell presented in this article. Our device is a novel type of compact long path absorption cell that can withstand aggressive chemicals in addition to temperatures up to 723 K. The construction of the cell and its technical features are described in detail, paying special attention to the mechanisms that compensate for thermal expansion and that allow the user to vary the optical path length under any thermal or vacuum condition. The cell may be used with a laser source or implemented within a Fourier transform infrared spectrometer. Its design is compatible with optical arrangements using astigmatic mirrors or spherical mirrors in a Herriott configuration. Here we implement a homebuilt Herriott-type cell with a total optical path length of up to 35 m. In order to demonstrate the feasibility of the cell, methane and water vapor absorption lines showing dissimilar temperature effects on line intensity were recorded with the help of a mid-infrared laser source tunable between 3 and 4 microm. Emphasis is put on lines that are too weak to be recorded with a single pass cell.

Heating systems for heating subsurface formations

DOEpatents

Nguyen, Scott Vinh [Houston, TX; Vinegar, Harold J [Bellaire, TX

2011-04-26

Methods and systems for heating a subsurface formation are described herein. A heating system for a subsurface formation includes a sealed conduit positioned in an opening in the formation and a heat source. The sealed conduit includes a heat transfer fluid. The heat source provides heat to a portion of the sealed conduit to change phase of the heat transfer fluid from a liquid to a vapor. The vapor in the sealed conduit rises in the sealed conduit, condenses to transfer heat to the formation and returns to the conduit portion as a liquid.

Propellant Vaporization as a Criterion for Rocket-Engine Design; Experimental Performance, Vaporization and Heat-Transfer Rates with Various Propellant Combinations

NASA Technical Reports Server (NTRS)

Clark, Bruce J.; Hersch, Martin; Priem, Richard J.

1959-01-01

Experimental combustion efficiencies of eleven propellant combinations were determined as a function of chamber length. Efficiencies were measured in terms of characteristic exhaust velocities at three chamber lengths and in terms of gas velocities. The data were obtained in a nominal 200-pound-thrust rocket engine. Injector and engine configurations were kept essentially the same to allow comparison of the performance. The data, except for those on hydrazine and ammonia-fluorine, agreed with predicted results based on the assumption that vaporization of the propellants determines the rate of combustion. Decomposition in the liquid phase may be.responsible for the anomalous behavior of hydrazine. Over-all heat-transfer rates were also measured for each combination. These rates were close to the values predicted by standard heat-transfer calculations except for the combinations using ammonia.

Investigation of Vapor Cooling Enhancements for Applications on Large Cryogenic Systems

NASA Technical Reports Server (NTRS)

Ameen, Lauren; Zoeckler, Joseph

2017-01-01

The need to demonstrate and evaluate the effectiveness of heat interception methods for use on a relevant cryogenic propulsion stage at a system level has been identified. Evolvable Cryogenics (eCryo) Structural Heat Intercept, Insulation and Vibration Evaluation Rig (SHIIVER) will be designed with vehicle specific geometries (SLS Exploration Upper Stage (EUS) as guidance) and will be subjected to simulated space environments. One method of reducing structure-born heat leak being investigated utilizes vapor-based heat interception. Vapor-based heat interception could potentially reduce heat leak into liquid hydrogen propulsion tanks, increasing potential mission length or payload capability. Due to the high number of unknowns associated with the heat transfer mechanism and integration of vapor-based heat interception on a realistic large-scale skirt design, a sub-scale investigation was developed. The sub-project effort is known as the Small-scale Laboratory Investigation of Cooling Enhancements (SLICE). The SLICE aims to study, design, and test sub-scale multiple attachments and flow configuration concepts for vapor-based heat interception of structural skirts. SLICE will focus on understanding the efficiency of the heat transfer mechanism to the boil-off hydrogen vapor by varying the fluid network designs and configurations. Various analyses were completed in MATLAB, Excel VBA, and COMSOL Multiphysics to understand the optimum flow pattern for heat transfer and fluid dynamics. Results from these analyses were used to design and fabricate test article subsections of a large forward skirt with vapor cooling applied. The SLICE testing is currently being performed to collect thermal mechanical performance data on multiple skirt heat removal designs while varying inlet vapor conditions necessary to intercept a specified amount of heat for a given system. Initial results suggest that applying vapor-cooling provides a 50 heat reduction in conductive heat transmission

7 CFR 305.24 - Vapor heat treatment schedules.

Code of Federal Regulations, 2010 CFR

2010-01-01

... increased using saturated water vapor at 112 °F until the approximate center of the fruit reaches 112 °F.... The temperature of the fruit must be increased using saturated water vapor at 117.5 °F until the pulp... be increased using saturated water vapor at 117.5 °F until the center of the fruit reaches 114.8 °F...

Macroscopic modeling of heat and water vapor transfer with phase change in dry snow based on an upscaling method: Influence of air convection

NASA Astrophysics Data System (ADS)

Calonne, N.; Geindreau, C.; Flin, F.

2015-12-01

At the microscopic scale, i.e., pore scale, dry snow metamorphism is mainly driven by the heat and water vapor transfer and the sublimation-deposition process at the ice-air interface. Up to now, the description of these phenomena at the macroscopic scale, i.e., snow layer scale, in the snowpack models has been proposed in a phenomenological way. Here we used an upscaling method, namely, the homogenization of multiple-scale expansions, to derive theoretically the macroscopic equivalent modeling of heat and vapor transfer through a snow layer from the physics at the pore scale. The physical phenomena under consideration are steady state air flow, heat transfer by conduction and convection, water vapor transfer by diffusion and convection, and phase change (sublimation and deposition). We derived three different macroscopic models depending on the intensity of the air flow considered at the pore scale, i.e., on the order of magnitude of the pore Reynolds number and the Péclet numbers: (A) pure diffusion, (B) diffusion and moderate convection (Darcy's law), and (C) strong convection (nonlinear flow). The formulation of the models includes the exact expression of the macroscopic properties (effective thermal conductivity, effective vapor diffusion coefficient, and intrinsic permeability) and of the macroscopic source terms of heat and vapor arising from the phase change at the pore scale. Such definitions can be used to compute macroscopic snow properties from 3-D descriptions of snow microstructures. Finally, we illustrated the precision and the robustness of the proposed macroscopic models through 2-D numerical simulations.

Vapor Bubbles

NASA Astrophysics Data System (ADS)

Prosperetti, Andrea

2017-01-01

This article reviews the fundamental physics of vapor bubbles in liquids. Work on bubble growth and condensation for stationary and translating bubbles is summarized and the differences with bubbles containing a permanent gas stressed. In particular, it is shown that the natural frequency of a vapor bubble is proportional not to the inverse radius, as for a gas bubble, but to the inverse radius raised to the power 2/3. Permanent gas dissolved in the liquid diffuses into the bubble with strong effects on its dynamics. The effects of the diffusion of heat and mass on the propagation of pressure waves in a vaporous bubbly liquid are discussed. Other topics briefly touched on include thermocapillary flow, plasmonic nanobubbles, and vapor bubbles in an immiscible liquid.

Heat transfer system

DOEpatents

McGuire, Joseph C.

1982-01-01

A heat transfer system for a nuclear reactor. Heat transfer is accomplished within a sealed vapor chamber which is substantially evacuated prior to use. A heat transfer medium, which is liquid at the design operating temperatures, transfers heat from tubes interposed in the reactor primary loop to spaced tubes connected to a steam line for power generation purposes. Heat transfer is accomplished by a two-phase liquid-vapor-liquid process as used in heat pipes. Condensible gases are removed from the vapor chamber through a vertical extension in open communication with the chamber interior.

Protection against cold in prehospital care: evaporative heat loss reduction by wet clothing removal or the addition of a vapor barrier--a thermal manikin study.

PubMed

Henriksson, Otto; Lundgren, Peter; Kuklane, Kalev; Holmér, Ingvar; Naredi, Peter; Bjornstig, Ulf

2012-02-01

In the prehospital care of a cold and wet person, early application of adequate insulation is of utmost importance to reduce cold stress, limit body core cooling, and prevent deterioration of the patient's condition. Most prehospital guidelines on protection against cold recommend the removal of wet clothing prior to insulation, and some also recommend the use of a waterproof vapor barrier to reduce evaporative heat loss. However, there is little scientific evidence of the effectiveness of these measures. Using a thermal manikin with wet clothing, this study was conducted to determine the effect of wet clothing removal or the addition of a vapor barrier on thermal insulation and evaporative heat loss using different amounts of insulation in both warm and cold ambient conditions. A thermal manikin dressed in wet clothing was set up in accordance with the European Standard for assessing requirements of sleeping bags, modified for wet heat loss determination, and the climatic chamber was set to -15 degrees Celsius (°C) for cold conditions and +10°C for warm conditions. Three different insulation ensembles, one, two or seven woollen blankets, were chosen to provide different levels of insulation. Five different test conditions were evaluated for all three levels of insulation ensembles: (1) dry underwear; (2) dry underwear with a vapor barrier; (3) wet underwear; (4) wet underwear with a vapor barrier; and (5) no underwear. Dry and wet heat loss and thermal resistance were determined from continuous monitoring of ambient air temperature, manikin surface temperature, heat flux and evaporative mass loss rate. Independent of insulation thickness or ambient temperature, the removal of wet clothing or the addition of a vapor barrier resulted in a reduction in total heat loss of 19-42%. The absolute heat loss reduction was greater, however, and thus clinically more important in cold environments when little insulation is available. A similar reduction in total heat loss

High heat flux loop heat pipes

NASA Astrophysics Data System (ADS)

North, Mark T.; Sarraf, David B.; Rosenfeld, John H.; Maidanik, Yuri F.; Vershinin, Sergey

1997-01-01

Loop Heat Pipes (LHPs) can transport very large thermal power loads, over long distances, through flexible, small diameter tubes and against high gravitational heads. While recent LHPs have transported as much as 1500 W, the peak heat flux through a LHP's evaporator has been limited to about 0.07 MW/m2. This limitation is due to the arrangement of vapor passages next to the heat load which is one of the conditions necessary to ensure self priming of the device. This paper describes work aimed at raising this limit by threefold to tenfold. Two approaches were pursued. One optimized the vapor passage geometry for the high heat flux conditions. The geometry improved the heat flow into the wick and working fluid. This approach also employed a finer pored wick to support higher vapor flow losses. The second approach used a bidisperse wick material within the circumferential vapor passages. The bidisperse material increased the thermal conductivity and the evaporative surface area in the region of highest heat flux, while providing a flow path for the vapor. Proof-of-concept devices were fabricated and tested for each approach. Both devices operated as designed and both demonstrated operation at a heat flux of 0.70 MW/m2. This performance exceeded the known state of the art by a factor of more than six for both conventional heat pipes and for loop heat pipes using ammonia. In addition, the bidisperse-wick device demonstrated boiling heat transfer coefficients up to 100,000 W/m2.K, and the fine pored device demonstrated an orientation independence with its performance essentially unaffected by whether its evaporator was positioned above, below or level with the condenser.

The lithium vapor box divertor

DOE Office of Scientific and Technical Information (OSTI.GOV)

Goldston, R. J.; Myers, R.; Schwartz, J.

It has long been recognized that volumetric dissipation of the plasma heat flux from a fusion power system is preferable to its localized impingement on a material surface. Volumetric dissipation mitigates both the anticipated very high heat flux and intense particle-induced damage due to sputtering. Our recent projections to a tokamak demonstration power plant suggest an immense upstream parallel heat flux, of order 20 GW m -2, implying that fully detached operation may be a requirement for the success of fusion power. Building on pioneering work on the use of lithium by Nagayama et al and by Ono et almore » as well as earlier work on the gas box divertor by Watkins and Rebut, we present here a concept for a lithium vapor box divertor, in which lithium vapor extracts momentum and energy from a fusion-power-plant divertor plasma, using fully volumetric processes. Furthermore, at the high powers and pressures that are projected this requires a high density of lithium vapor, which must be isolated from the main plasma in order to avoid lithium build-up on the chamber walls or in the plasma. Isolation is achieved through a powerful multi-box differential pumping scheme available only for condensable vapors. The preliminary box-wise calculations are encouraging, but much more work is required in order to demonstrate the practical viability of this scheme, taking into account at least 2D plasma and vapor flows within and between the vapor boxes and out of the vapor boxes to the main plasma.« less

The lithium vapor box divertor

NASA Astrophysics Data System (ADS)

Goldston, R. J.; Myers, R.; Schwartz, J.

2016-02-01

It has long been recognized that volumetric dissipation of the plasma heat flux from a fusion power system is preferable to its localized impingement on a material surface. Volumetric dissipation mitigates both the anticipated very high heat flux and intense particle-induced damage due to sputtering. Recent projections to a tokamak demonstration power plant suggest an immense upstream parallel heat flux, of order 20 GW m-2, implying that fully detached operation may be a requirement for the success of fusion power. Building on pioneering work on the use of lithium by Nagayama et al and by Ono et al as well as earlier work on the gas box divertor by Watkins and Rebut, we present here a concept for a lithium vapor box divertor, in which lithium vapor extracts momentum and energy from a fusion-power-plant divertor plasma, using fully volumetric processes. At the high powers and pressures that are projected this requires a high density of lithium vapor, which must be isolated from the main plasma in order to avoid lithium build-up on the chamber walls or in the plasma. Isolation is achieved through a powerful multi-box differential pumping scheme available only for condensable vapors. The preliminary box-wise calculations are encouraging, but much more work is required to demonstrate the practical viability of this scheme, taking into account at least 2D plasma and vapor flows within and between the vapor boxes and out of the vapor boxes to the main plasma.

The lithium vapor box divertor

DOE PAGES

Goldston, R. J.; Myers, R.; Schwartz, J.

2016-01-13

It has long been recognized that volumetric dissipation of the plasma heat flux from a fusion power system is preferable to its localized impingement on a material surface. Volumetric dissipation mitigates both the anticipated very high heat flux and intense particle-induced damage due to sputtering. Our recent projections to a tokamak demonstration power plant suggest an immense upstream parallel heat flux, of order 20 GW m -2, implying that fully detached operation may be a requirement for the success of fusion power. Building on pioneering work on the use of lithium by Nagayama et al and by Ono et almore » as well as earlier work on the gas box divertor by Watkins and Rebut, we present here a concept for a lithium vapor box divertor, in which lithium vapor extracts momentum and energy from a fusion-power-plant divertor plasma, using fully volumetric processes. Furthermore, at the high powers and pressures that are projected this requires a high density of lithium vapor, which must be isolated from the main plasma in order to avoid lithium build-up on the chamber walls or in the plasma. Isolation is achieved through a powerful multi-box differential pumping scheme available only for condensable vapors. The preliminary box-wise calculations are encouraging, but much more work is required in order to demonstrate the practical viability of this scheme, taking into account at least 2D plasma and vapor flows within and between the vapor boxes and out of the vapor boxes to the main plasma.« less

Predicting the heat of vaporization of iron at high temperatures using time-resolved laser-induced incandescence and Bayesian model selection

NASA Astrophysics Data System (ADS)

Sipkens, Timothy A.; Hadwin, Paul J.; Grauer, Samuel J.; Daun, Kyle J.

2018-03-01

Competing theories have been proposed to account for how the latent heat of vaporization of liquid iron varies with temperature, but experimental confirmation remains elusive, particularly at high temperatures. We propose time-resolved laser-induced incandescence measurements on iron nanoparticles combined with Bayesian model plausibility, as a novel method for evaluating these relationships. Our approach scores the explanatory power of candidate models, accounting for parameter uncertainty, model complexity, measurement noise, and goodness-of-fit. The approach is first validated with simulated data and then applied to experimental data for iron nanoparticles in argon. Our results justify the use of Román's equation to account for the temperature dependence of the latent heat of vaporization of liquid iron.

Heat transfer system

DOEpatents

Not Available

1980-03-07

A heat transfer system for a nuclear reactor is described. Heat transfer is accomplished within a sealed vapor chamber which is substantially evacuated prior to use. A heat transfer medium, which is liquid at the design operating temperatures, transfers heat from tubes interposed in the reactor primary loop to spaced tubes connected to a steam line for power generation purposes. Heat transfer is accomplished by a two-phase liquid-vapor-liquid process as used in heat pipes. Condensible gases are removed from the vapor chamber through a vertical extension in open communication with the chamber interior.

Heat pump system

DOEpatents

Swenson, Paul F.; Moore, Paul B.

1983-01-01

An air heating and cooling system for a building includes an expansion type refrigeration circuit and a vapor power circuit. The refrigeration circuit includes two heat exchangers, one of which is communicated with a source of indoor air from the building and the other of which is communicated with a source of air from outside the building. The vapor power circuit includes two heat exchangers, one of which is disposed in series air flow relationship with the indoor refrigeration circuit heat exchanger and the other of which is disposed in series air flow relationship with the outdoor refrigeration circuit heat exchanger. Fans powered by electricity generated by a vapor power circuit alternator circulate indoor air through the two indoor heat exchangers and circulate outside air through the two outdoor heat exchangers. The system is assembled as a single roof top unit, with a vapor power generator and turbine and compressor thermally insulated from the heat exchangers, and with the indoor heat exchangers thermally insulated from the outdoor heat exchangers.

Heat pump system

DOEpatents

Swenson, Paul F.; Moore, Paul B.

1977-01-01

An air heating and cooling system for a building includes an expansion type refrigeration circuit and a vapor power circuit. The refrigeration circuit includes two heat exchangers, one of which is communicated with a source of indoor air from the building and the other of which is communicated with a source of air from outside the building. The vapor power circuit includes two heat exchangers, one of which is disposed in series air flow relationship with the indoor refrigeration circuit heat exchanger and the other of which is disposed in series air flow relationship with the outdoor refrigeration circuit heat exchanger. Fans powered by electricity generated by a vapor power circuit alternator circulate indoor air through the two indoor heat exchangers and circulate outside air through the two outdoor heat exchangers. The system is assembled as a single roof top unit, with a vapor power generator and turbine and compressor thermally insulated from the heat exchangers, and with the indoor heat exchangers thermally insulated from the outdoor heat exchangers.

Heat pump system

DOEpatents

Swenson, Paul F.; Moore, Paul B.

1983-06-21

An air heating and cooling system for a building includes an expansion type refrigeration circuit and a vapor power circuit. The refrigeration circuit includes two heat exchangers, one of which is communicated with a source of indoor air from the building and the other of which is communicated with a source of air from outside the building. The vapor power circuit includes two heat exchangers, one of which is disposed in series air flow relationship with the indoor refrigeration circuit heat exchanger and the other of which is disposed in series air flow relationship with the outdoor refrigeration circuit heat exchanger. Fans powered by electricity generated by a vapor power circuit alternator circulate indoor air through the two indoor heat exchangers and circulate outside air through the two outdoor heat exchangers. The system is assembled as a single roof top unit, with a vapor power generator and turbine and compressor thermally insulated from the heat exchangers, and with the indoor heat exchangers thermally insulated from the outdoor heat exchangers.

Experimental study of flash boiling spray vaporization through quantitative vapor concentration and liquid temperature measurements

NASA Astrophysics Data System (ADS)

Zhang, Gaoming; Hung, David L. S.; Xu, Min

2014-08-01

Flash boiling sprays of liquid injection under superheated conditions provide the novel solutions of fast vaporization and better air-fuel mixture formation for internal combustion engines. However, the physical mechanisms of flash boiling spray vaporization are more complicated than the droplet surface vaporization due to the unique bubble generation and boiling process inside a superheated bulk liquid, which are not well understood. In this study, the vaporization of flash boiling sprays was investigated experimentally through the quantitative measurements of vapor concentration and liquid temperature. Specifically, the laser-induced exciplex fluorescence technique was applied to distinguish the liquid and vapor distributions. Quantitative vapor concentration was obtained by correlating the intensity of vapor-phase fluorescence with vapor concentration through systematic corrections and calibrations. The intensities of two wavelengths were captured simultaneously from the liquid-phase fluorescence spectra, and their intensity ratios were correlated with liquid temperature. The results show that both liquid and vapor phase of multi-hole sprays collapse toward the centerline of the spray with different mass distributions under the flash boiling conditions. Large amount of vapor aggregates along the centerline of the spray to form a "gas jet" structure, whereas the liquid distributes more uniformly with large vortexes formed in the vicinity of the spray tip. The vaporization process under the flash boiling condition is greatly enhanced due to the intense bubble generation and burst. The liquid temperature measurements show strong temperature variations inside the flash boiling sprays with hot zones present in the "gas jet" structure and vortex region. In addition, high vapor concentration and closed vortex motion seem to have inhibited the heat and mass transfer in these regions. In summary, the vapor concentration and liquid temperature provide detailed information

Potential ability of zeolite to generate high-temperature vapor using waste heat

NASA Astrophysics Data System (ADS)

Fukai, Jun; Wijayanta, Agung Tri

2018-02-01

In various material product industries, a large amount of high temperature steam as heat sources are produced from fossil fuel, then thermal energy retained by condensed water at lower than 100°C are wasted. Thermal energies retained by exhaust gases at lower than 200°C are also wasted. Effective utilization of waste heat is believed to be one of important issues to solve global problems of energy and environment. Zeolite/water adsorption systems are introduced to recover such low-temperature waste heats in this study. Firstly, an adsorption steam recovery system was developed to generate high temperature steam from unused hot waste heat. The system used a new principle that adsorption heat of zeolite/water contact was efficiently extracted. A bench-scaled system was constructed, demonstrating contentious generation of saturated steam nearly 150°C from hot water at 80°C. Energy conservation is expected by returning the generated steam to steam lines in the product processes. Secondly, it was demonstrated that superheated steam/vapor at higher than 200°C could be generated from those at nearly 120°C using a laboratory-scaled setup. The maximum temperature and the time variation of output temperature were successfully estimated using macroscopic heat balances. Lastly, the maximum temperatures were estimated whose saturate air at the relative humidity 20-80% were heated by the present system. Theoretically, air at higher than 200°C was generated from saturate air at higher than 70°C. Consequently, zeolite/water adsorption systems have potential ability to regenerate thermal energy of waste water and exhaust gases.

Modeling and Validation of Microwave Ablations with Internal Vaporization

PubMed Central

Chiang, Jason; Birla, Sohan; Bedoya, Mariajose; Jones, David; Subbiah, Jeyam; Brace, Christopher L.

2014-01-01

Numerical simulation is increasingly being utilized for computer-aided design of treatment devices, analysis of ablation growth, and clinical treatment planning. Simulation models to date have incorporated electromagnetic wave propagation and heat conduction, but not other relevant physics such as water vaporization and mass transfer. Such physical changes are particularly noteworthy during the intense heat generation associated with microwave heating. In this work, a numerical model was created that integrates microwave heating with water vapor generation and transport by using porous media assumptions in the tissue domain. The heating physics of the water vapor model was validated through temperature measurements taken at locations 5, 10 and 20 mm away from the heating zone of the microwave antenna in homogenized ex vivo bovine liver setup. Cross-sectional area of water vapor transport was validated through intra-procedural computed tomography (CT) during microwave ablations in homogenized ex vivo bovine liver. Iso-density contours from CT images were compared to vapor concentration contours from the numerical model at intermittent time points using the Jaccard Index. In general, there was an improving correlation in ablation size dimensions as the ablation procedure proceeded, with a Jaccard Index of 0.27, 0.49, 0.61, 0.67 and 0.69 at 1, 2, 3, 4, and 5 minutes. This study demonstrates the feasibility and validity of incorporating water vapor concentration into thermal ablation simulations and validating such models experimentally. PMID:25330481

Vapor Jet Ejector Used to Generate Free Waste Heat Driven Cooling in Military Environmental Cooling Units

DTIC Science & Technology

2012-07-01

vap erant vapor is or by a J-tub essure side of using similar pressure incre ump in order o the diesel-e per heat excha recovered at to the exhaus...top of the a tering the com at exchanger. g of the conve id flow. A nit essure pulsati tor where the ed in the cool erature level. ger where wa

Vapor Pressure Data Analysis and Statistics

DTIC Science & Technology

2016-12-01

sublimation for solids), volatility, and entropy of volatilization. Vapor pressure can be reported several different ways, including tables of experimental ...account the variation in heat of vaporization with temperature, and accurately describes data over broad experimental ranges, thereby enabling...pressure is incorrect at temperatures far below the experimental temperature limit; the calculated vapor pressure becomes undefined when the

Sporicidal Activity of the KMT reagent in its vapor phase against Geobacillus stearothermophilus Spores.

PubMed

Kida, Nori; Mochizuki, Yasushi; Taguchi, Fumiaki

2007-01-01

In an investigation of the sporicidal activity of the KMT reagent, a vapor phase study was performed using five kinds of carriers contaminated with Geobacillus stearothermophilus spores. When 25 ml of the KMT reagent was vaporized in a chamber (capacity; approximately 95 liters), the 2-step heating method (vaporization by a combination of low temperature and high temperature) showed the most effective sporicidal activity in comparison with the 1-step heating method (rapid vaporization). The 2-step heating method appeared to be related to the sporicidal activity of vaporized KMT reagent, i.e., ethanol and iodine, which vaporized mainly when heated at a low temperature such as 55 C, and acidic water, which vaporized mainly when heated at a high temperature such as 300 C. We proposed that the KMT reagent can be used as a new disinfectant not only in the liquid phase but also in the vapor phase in the same way as peracetic acid and hydrogen peroxide.

Multi-leg heat pipe evaporator

NASA Technical Reports Server (NTRS)

Alario, J. P.; Haslett, R. A. (Inventor)

1986-01-01

A multileg heat pipe evaporator facilitates the use and application of a monogroove heat pipe by providing an evaporation section which is compact in area and structurally more compatible with certain heat exchangers or heat input apparatus. The evaporation section of a monogroove heat pipe is formed by a series of parallel legs having a liquid and a vapor channel and a communicating capillary slot therebetween. The liquid and vapor channels and interconnecting capillary slots of the evaporating section are connected to the condensing section of the heat pipe by a manifold connecting liquid and vapor channels of the parallel evaporation section legs with the corresponding liquid and vapor channels of the condensing section.

Drying of pulverized material with heated condensible vapor

DOEpatents

Carlson, L.W.

1984-08-16

Apparatus for drying pulverized material utilizes a high enthalpy condensable vapor such as steam for removing moisture from the individual particles of the pulverized material. The initially wet particulate material is tangentially delivered by a carrier vapor flow to an upper portion of a generally vertical cylindrical separation drum. The lateral wall of the separation drum is provided with a plurality of flow guides for directing the vapor tangentially therein in the direction of particulate material flow. Positioned concentrically within the separation drum and along the longitudinal axis thereof is a water-cooled condensation cylinder which is provided with a plurality of collection plates, or fines, on the outer lateral surface thereof. The cooled collection fines are aligned counter to the flow of the pulverized material and high enthalpy vapor mixture to maximize water vapor condensation thereon. The condensed liquid which includes moisture removed from the pulverized materials then flows downward along the outer surface of the coolant cylinder and is collected and removed. The particles travel in a shallow helix due to respective centrifugal and vertical acceleration forces applied thereto. The individual particles of the pulverized material are directed outwardly by the vortex flow where they contact the inner cylindrical surface of the separation drum and are then deposited at the bottom thereof for easy collection and removal. The pulverized material drying apparatus is particularly adapted for drying coal fines and facilitates the recovery of the pulverized coal. 2 figs.

Drying of pulverized material with heated condensible vapor

DOEpatents

Carlson, Larry W.

1986-01-01

Apparatus for drying pulverized material utilizes a high enthalpy condensable vapor such as steam for removing moisture from the individual particles of the pulverized material. The initially wet particulate material is tangentially delivered by a carrier vapor flow to an upper portion of a generally vertical cylindrical separation drum. The lateral wall of the separation drum is provided with a plurality of flow guides for directing the vapor tangentially therein in the direction of particulate material flow. Positioned concentrically within the separation drum and along the longitudinal axis thereof is a water-cooled condensation cylinder which is provided with a plurality of collection plates, or fins, on the outer lateral surface thereof. The cooled collection fins are aligned counter to the flow of the pulverized material and high enthalpy vapor mixture to maximize water vapor condensation thereon. The condensed liquid which includes moisture removed from the pulverized material then flows downward along the outer surface of the coolant cylinder and is collected and removed. The particles travel in a shallow helix due to respective centrifugal and vertical acceleration forces applied thereto. The individual particles of the pulverized material are directed outwardly by the vortex flow where they contact the inner cylindrical surface of the separation drum and are then deposited at the bottom thereof for easy collection and removal. The pulverized material drying apparatus is particularly adapted for drying coal fines and facilitates the recovery of the pulverized coal.

Liquid fuel vaporizer and combustion chamber having an adjustable thermal conductor

DOEpatents

Powell, Michael R; Whyatt, Greg A; Howe, Daniel T; Fountain, Matthew S

2014-03-04

The efficiency and effectiveness of apparatuses for vaporizing and combusting liquid fuel can be improved using thermal conductors. For example, an apparatus having a liquid fuel vaporizer and a combustion chamber can be characterized by a thermal conductor that conducts heat from the combustion chamber to the vaporizer. The thermal conductor can be a movable member positioned at an insertion depth within the combustion chamber that corresponds to a rate of heat conduction from the combustion chamber to the vaporizer. The rate of heat conduction can, therefore, be adjusted by positioning the movable member at a different insertion depth.

DSMC simulations of vapor transport toward development of the lithium vapor box divertor concept

NASA Astrophysics Data System (ADS)

Jagoe, Christopher; Schwartz, Jacob; Goldston, Robert

2016-10-01

The lithium vapor divertor box concept attempts to achieve volumetric dissipation of the high heat efflux from a fusion power system. The vapor extracts the heat of the incoming plasma by ionization and radiation, while remaining localized in the vapor box due to differential pumping based on rapid condensation. Preliminary calculations with lithium vapor at densities appropriate for an NSTX-U-scale machine give Knudsen numbers between 0.01 and 1, outside both the range of continuum fluid dynamics and of collisionless Monte Carlo. The direct-simulation Monte Carlo (DSMC) method, however, can simulate rarefied gas flows in this regime. Using the solver contained in the OpenFOAM package, pressure-driven flows of water vapor will be analyzed. The use of water vapor in the relevant range of Knudsen number allows for a flexible similarity experiment to verify the reliability of the code before moving to tests with lithium. The simulation geometry consists of chains of boxes on a temperature gradient, connected by slots with widths that are a representative fraction of the dimensions of the box. We expect choked flow, sonic shocks, and order-of-magnitude pressure and density drops from box to box, but this expectation will be tested in the simulation and then experiment. This work is supported by the Princeton Environmental Institute.

Boiler for generating high quality vapor

NASA Technical Reports Server (NTRS)

Gray, V. H.; Marto, P. J.; Joslyn, A. W.

1972-01-01

Boiler supplies vapor for use in turbines by imparting a high angular velocity to the liquid annulus in heated rotating drum. Drum boiler provides a sharp interface between boiling liquid and vapor, thereby, inhibiting the formation of unwanted liquid droplets.

Transient Response of Arc Temperature and Iron Vapor Concentration Affected by Current Frequency with Iron Vapor in Pulsed Arc

NASA Astrophysics Data System (ADS)

Tanaka, Tatsuro; Maeda, Yoshifumi; Yamamoto, Shinji; Iwao, Toru

2016-10-01

TIG arc welding is chemically a joining technology with melting the metallic material and it can be high quality. However, this welding should not be used in high current to prevent cathode melting. Thus, the heat transfer is poor. Therefore, the deep penetration cannot be obtained and the weld defect sometimes occurs. The pulsed arc welding has been used for the improvement of this defect. The pulsed arc welding can control the heat flux to anode. The convention and driving force in the weld pool are caused by the arc. Therefore, it is important to grasp the distribution of arc temperature. The metal vapor generate from the anode in welding. In addition, the pulsed current increased or decreased periodically. Therefore, the arc is affected by such as a current value and current frequency, the current rate of increment and the metal vapor. In this paper, the transient response of arc temperature and the iron vapor concentration affected by the current frequency with iron vapor in pulsed arc was elucidated by the EMTF (ElectroMagnetic Thermal Fluid) simulation. As a result, the arc temperature and the iron vapor were transient response as the current frequency increase. Thus, the temperature and the electrical conductivity decreased. Therefore, the electrical field increased in order to maintain the current continuity. The current density and electromagnetic force increased at the axial center. In addition, the electronic flow component of the heat flux increased at the axial center because the current density increased. However, the heat conduction component of the heat flux decreased.

Application of Molecular Dynamics Simulations in Molecular Property Prediction I: Density and Heat of Vaporization

PubMed Central

Wang, Junmei; Tingjun, Hou

2011-01-01

Molecular mechanical force field (FF) methods are useful in studying condensed phase properties. They are complementary to experiment and can often go beyond experiment in atomic details. Even a FF is specific for studying structures, dynamics and functions of biomolecules, it is still important for the FF to accurately reproduce the experimental liquid properties of small molecules that represent the chemical moieties of biomolecules. Otherwise, the force field may not describe the structures and energies of macromolecules in aqueous solutions properly. In this work, we have carried out a systematic study to evaluate the General AMBER Force Field (GAFF) in studying densities and heats of vaporization for a large set of organic molecules that covers the most common chemical functional groups. The latest techniques, such as the particle mesh Ewald (PME) for calculating electrostatic energies, and Langevin dynamics for scaling temperatures, have been applied in the molecular dynamics (MD) simulations. For density, the average percent error (APE) of 71 organic compounds is 4.43% when compared to the experimental values. More encouragingly, the APE drops to 3.43% after the exclusion of two outliers and four other compounds for which the experimental densities have been measured with pressures higher than 1.0 atm. For heat of vaporization, several protocols have been investigated and the best one, P4/ntt0, achieves an average unsigned error (AUE) and a root-mean-square error (RMSE) of 0.93 and 1.20 kcal/mol, respectively. How to reduce the prediction errors through proper van der Waals (vdW) parameterization has been discussed. An encouraging finding in vdW parameterization is that both densities and heats of vaporization approach their “ideal” values in a synchronous fashion when vdW parameters are tuned. The following hydration free energy calculation using thermodynamic integration further justifies the vdW refinement. We conclude that simple vdW parameterization

Thermal Design of Vapor Cooling of Flight Vehicle Structures Using LH2 Boil-Off

NASA Technical Reports Server (NTRS)

Wang, Xiao-Yen; Zoeckler, Joseph

2015-01-01

Using hydrogen boil-off vapor to cool the structure of a flight vehicle cryogenic upper stage can reduce heat loads to the stage and increase the usable propellant in the stage or extend the life of the stage. The hydrogen vapor can be used to absorb incoming heat as it increases in temperature before being vented overboard. In theory, the amount of heat leaking into the hydrogen tank from the structure will be reduced if the structure is cooled using the propellant boil-off vapor. However, the amount of boil-off vapor available to be used for cooling and the reduction in heat leak to the propellant tank are dependent to each other. The amount of heat leak reduction to the LH2 tank also depends on the total heat load on the stage and the vapor cooling configurations.

Numerical and Experimental Study of an Ambient Air Vaporizer Coupled with a Compact Heat Exchanger

NASA Astrophysics Data System (ADS)

Kimura, Randon

The University of Washington was tasked with designing a "21st century engine" that will make use of the thermal energy available in cryogenic gasses due to their coldness. There are currently large quantities of cryogenic gases stored throughout the U.S. at industrial facilities whereupon the regasification process, the potential for the fluid to do work is wasted. The engine proposed by the University of Washington will try to capture some of that wasted energy. One technical challenge that must be overcome during the regasification process is providing frost free operation. This thesis presents the numerical analysis and experimental testing of a passive heat exchange system that uses ambient vaporizers coupled with compact heat exchangers to provide frost free operation while minimizing pressure drop.

Process for vaporizing a liquid hydrocarbon fuel

DOEpatents

Szydlowski, Donald F.; Kuzminskas, Vaidotas; Bittner, Joseph E.

1981-01-01

The object of the invention is to provide a process for vaporizing liquid hydrocarbon fuels efficiently and without the formation of carbon residue on the apparatus used. The process includes simultaneously passing the liquid fuel and an inert hot gas downwardly through a plurality of vertically spaed apart regions of high surface area packing material. The liquid thinly coats the packing surface, and the sensible heat of the hot gas vaporizes this coating of liquid. Unvaporized liquid passing through one region of packing is uniformly redistributed over the top surface of the next region until all fuel has been vaporized using only the sensible heat of the hot gas stream.

Simultaneous determination of the heat and the quantity of vapor sorption using a novel microcalorimetric method.

PubMed

Lehto, V P; Laine, E

2000-06-01

In this study, instrumentation for measuring vapor sorption enthalpies and sorption uptakes simultaneously with an isothermal microcalorimeter is introduced. Various pharmaceutical model substances undergoing phase transitions when exposed to humid conditions (25 degrees C), were employed to evaluate the usefulness and sensitivity of the constructed experimental method. The sample is placed in the sample vessel of a RH cell and the moisture content of the air flow is controlled. From the RH cell the air flow is conducted into a subsequent perfusion cell in which a saturated salt solution has been loaded. The RH cell and perfusion cells are positioned in the sample sides of two twin calorimetric units. Depending on the moisture content in the outlet flow leaving the preceding RH cell, the heat flow signal from the subsequent perfusion cell will vary. By means of blank measurement with identical settings, the rate of water sorption can be calculated and, by integration, the amount of sorbed water is obtained. Amorphous lactose and cefadroxil undergo recrystallization when the moisture level in the surroundings exceeds the threshold values specific to each compound. During the sorption phase, heat is evolved fairly linearly as a function of consumed moisture, and also after the recrystallization, the heats indicate linear behavior. The heat values for the desorption phase of amorphous lactose and the adsorption of crystalline lactose coincide. With the different anhydrous forms of theophylline, the hydration takes place more rapidly in the metastable form 1, and generally, the process is more energetic in form 1. In all cases, the gravimetric results agree with the water sorption uptakes calculated from the calorimetric data. The technique introduced offers a rapid and sensitive method to gain new insights into the transitions in which vapors are involved. In addition, different kinds of surfaces with various energetics can now be studied more closely.

Air heating system

DOEpatents

Primeau, John J.

1983-03-01

A self-starting, fuel-fired, air heating system including a vapor generator, a turbine, and a condenser connected in a closed circuit such that the vapor output from the vapor generator is conducted to the turbine and then to the condenser where it is condensed for return to the vapor generator. The turbine drives an air blower which passes air over the condenser for cooling the condenser. Also, a condensate pump is driven by the turbine. The disclosure is particularly concerned with the provision of heat exchanger and circuitry for cooling the condensed fluid output from the pump prior to its return to the vapor generator.

Enhanced vacuum arc vapor deposition electrode

NASA Technical Reports Server (NTRS)

Weeks, Jack L. (Inventor); Todd, Douglas M. (Inventor)

1999-01-01

A process for forming a thin metal coating on a substrate wherein a gas stream heated by an electrical current impinges on a metallic target in a vacuum chamber to form a molten pool of the metal and then vaporize a portion of the pool, with the source of the heated gas stream being on one side of the target and the substrate being on the other side of the target such that most of the metallic vapor from the target is directed at the substrate.

Heat transfer within a flat micro heat pipe with extra liquid

NASA Astrophysics Data System (ADS)

Sprinceana, Silviu; Mihai, Ioan

2016-12-01

In the real functioning of flat micro heat pipe (FMHP), there can appear cases when the temperature from the vaporization zone can exceed a critical value caused by a sudden increase of the thermal flow. The heat transfer which is completed conductively through the copper wall of a FMHP vaporizer causes the vaporization of the work fluid. On the condenser, the condensation of the fluid vapors and the transfer of the condenser to the vaporizer can no longer be achieved. The solution proposed for enhancing heat transfer in the event of blockage phenomenon FMHP, it is the injection of a certain amount of working fluid in the vaporization zone. By this process the working fluid injected into the evaporator passes suddenly in the vapor, producing a cooling zone. The new product additional mass of vapor will leave the vaporization zone and will condense in condensation zone, thereby supplementing the amount of condensation. Thus resumes normal operating cycle of FMHP. For the experimental measurements made for the transfer of heat through the FMHP working fluid demineralized water, they were made two micro-capillary tubes of sintered copper layer. The first was filled with 1ml of demineralized water was dropped under vacuum until the internal pressure has reached a level of 1•104Pa. The second FMHP was filled with the same amount of working fluid was used and the same capillary inner layer over which was laid a polysynthetic material that will accrue an additional amount of fluid. In this case, the internal pressure was reduced to 1•104Pa.

Experiments of Transient Condensation Heat Transfer on the Heat Flux Senor

NASA Astrophysics Data System (ADS)

Wang, Xuwen; Liu, Qiusheng; Zhu, Zhiqiang; Chen, Xue

2015-09-01

The influence of transient heat transfer in different condensation condition was investigated experimentally in the present paper. Getting condensation heat and mass transfer regularity and characteristics in space can provide theoretical basis for thermodynamic device such as heat pipes, loop heat pipes and capillary pumped loops as well as other fluid management engineering designing. In order to study the condensation process in space, an experimental study has been carried out on the ground for space experiment. The results show that transit heat transfer coefficient of film condensation is related to the condensation film width, the flow condition near the two phase interface and the pressure of the vapor and non-condensable gas in chamber. On the ground, the condensation heat flux on vertical surface is higher than it on horizontal surface. The transit heat flux of film condensation is affected by the temperature of superheated vapor, the temperature of condensation surface and non-condensable gas pressure. Condensation heat flux with vapor forced convection is many times more than it with natural convection. All of heat flux for both vapor forced convection and natural convection condensation in limited chamber declines dramatically over time. The present experiment is preliminary work for our future space experiments of the condensation and heat transfer process onboard the Chinese Spacecraft "TZ-1" to be launched in 2016.

Cappuccino and Specific Heat Versus Heat of Vaporization

NASA Astrophysics Data System (ADS)

Hidden, Frits; Boomsma, Jorn; Schins, Anton; van den Berg, Ed

2012-02-01

A cappuccino is prepared by adding about 50 mL frothing, foaming milk to a cup of espresso. Whole milk is best for foaming and the ideal milk temperature when adding it to the espresso is 65 °C. The espresso itself may be warmer than that. During the heating the milk should not burn, as that would spoil the taste. The best way is to heat the milk slowly while stirring to froth the milk and create foam. But modern cappuccino machines in restaurants do not have time for slow heating. Could we heat the milk by just adding hot water?

Pumped two-phase heat transfer loop

NASA Technical Reports Server (NTRS)

Edelstein, Fred

1988-01-01

A pumped loop two-phase heat transfer system, operating at a nearly constant temperature throughout, includes several independently operating grooved capillary heat exchanger plates supplied with working fluid through independent flow modulation valves connected to a liquid supply line, a vapor line for collecting vapor from the heat exchangers, a condenser between the vapor and the liquid lines, and a fluid circulating pump between the condenser and the heat exchangers.

Transient thermohydraulic heat pipe modeling

NASA Astrophysics Data System (ADS)

Hall, Michael L.; Doster, Joseph M.

Many space based reactor designs employ heat pipes as a means of conveying heat. In these designs, thermal radiation is the principle means for rejecting waste heat from the reactor system, making it desirable to operate at high temperatures. Lithium is generally the working fluid of choice as it undergoes a liquid-vapor transformation at the preferred operating temperature. The nature of remote startup, restart, and reaction to threats necessitates an accurate, detailed transient model of the heat pipe operation. A model is outlined of the vapor core region of the heat pipe which is part of a large model of the entire heat pipe thermal response. The vapor core is modeled using the area averaged Navier-Stokes equations in one dimension, which take into account the effects of mass, energy and momentum transfer. The core model is single phase (gaseous), but contains two components: lithium gas and a noncondensible vapor. The vapor core model consists of the continuity equations for the mixture and noncondensible, as well as mixture equations for internal energy and momentum.

Role of entrapped vapor bubbles during microdroplet evaporation

NASA Astrophysics Data System (ADS)

Putnam, Shawn A.; Byrd, Larry W.; Briones, Alejandro M.; Hanchak, Michael S.; Ervin, Jamie S.; Jones, John G.

2012-08-01

On superheated surfaces, the air bubble trapped during impingement grows into a larger vapor bubble and oscillates at the frequency predicted for thermally induced capillary waves. In some cases, the entrapped vapor bubble penetrates the droplet interface, leaving a micron-sized coffee-ring pattern of pure fluid. Vapor bubble entrapment, however, does not influence the evaporation rate. This is also true on laser heated surfaces, where a laser can thermally excite capillary waves and induce bubble oscillations over a broad range of frequencies, suggesting that exciting perturbations in a pinned droplets interface is not an effective avenue for enhancing evaporative heat transfer.

Electrolyte vapor condenser

DOEpatents

Sederquist, Richard A.; Szydlowski, Donald F.; Sawyer, Richard D.

1983-01-01

A system is disclosed for removing electrolyte from a fuel cell gas stream. The gas stream containing electrolyte vapor is supercooled utilizing conventional heat exchangers and the thus supercooled gas stream is passed over high surface area passive condensers. The condensed electrolyte is then drained from the condenser and the remainder of the gas stream passed on. The system is particularly useful for electrolytes such as phosphoric acid and molten carbonate, but can be used for other electrolyte cells and simple vapor separation as well.

Electrolyte vapor condenser

DOEpatents

Sederquist, R.A.; Szydlowski, D.F.; Sawyer, R.D.

1983-02-08

A system is disclosed for removing electrolyte from a fuel cell gas stream. The gas stream containing electrolyte vapor is supercooled utilizing conventional heat exchangers and the thus supercooled gas stream is passed over high surface area passive condensers. The condensed electrolyte is then drained from the condenser and the remainder of the gas stream passed on. The system is particularly useful for electrolytes such as phosphoric acid and molten carbonate, but can be used for other electrolyte cells and simple vapor separation as well. 3 figs.

Pumped two-phase heat transfer loop

NASA Technical Reports Server (NTRS)

Edelstein, Fred (Inventor)

1987-01-01

A pumped loop two-phase heat transfer system, operating at a nearly constant temperature throughout, includes a plurality of independently operating grooved capillary heat exchanger plates supplied with working fluid through independent flow modulation valves connected to a liquid supply line, a vapor line for collecting vapor from the heat exchangers, a condenser between the vapor and the liquid lines, and a fluid circulating pump between the condenser and the heat exchangers.

Vapor Hydrogen Peroxide as Alternative to Dry Heat Microbial Reduction

NASA Technical Reports Server (NTRS)

Cash, Howard A.; Kern, Roger G.; Chung, Shirley Y.; Koukol, Robert C.; Barengoltz, Jack B.

2006-01-01

The Jet Propulsion Laboratory, in conjunction with the NASA Planetary Protection Officer, has selected vapor phase hydrogen peroxide (VHP) sterilization process for continued development as a NASA approved sterilization technique for spacecraft subsystems and systems. The goal is to include this technique, with appropriate specification, in NPG8020.12C as a low temperature complementary technique to the dry heat sterilization process. A series of experiments were conducted in vacuum to determine VHP process parameters that provided significant reductions in spore viability while allowing survival of sufficient spores for statistically significant enumeration. With this knowledge of D values, sensible margins can be applied in a planetary protection specification. The outcome of this study provided an optimization of test sterilizer process conditions: VHP concentration, process duration, a process temperature range for which the worst case D value may be imposed, a process humidity range for which the worst case D value may be imposed, and robustness to selected spacecraft material substrates.

AMTEC vapor-vapor series connected cells

NASA Technical Reports Server (NTRS)

Underwood, Mark L. (Inventor); Williams, Roger M. (Inventor); Ryan, Margaret A. (Inventor); Nakamura, Barbara J. (Inventor); Oconnor, Dennis E. (Inventor)

1995-01-01

An alkali metal thermoelectric converter (AMTEC) having a plurality of cells structurally connected in series to form a septum dividing a plenum into two chambers, and electrically connected in series, is provided with porous metal anodes and porous metal cathodes in the cells. The cells may be planar or annular, and in either case a metal alkali vapor at a high temperature is provided to the plenum through one chamber on one side of the wall and returned to a vapor boiler after condensation at a chamber on the other side of the wall in the plenum. If the cells are annular, a heating core may be placed along the axis of the stacked cells. This arrangement of series-connected cells allows efficient generation of power at high voltage and low current.

Dielectric and specific heat relaxations in vapor deposited glycerol

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kasina, A., E-mail: angeline.kasina@fys.kuleuven.be, E-mail: wubbenhorst@fys.kuleuven.be; Putzeys, T.; Wübbenhorst, M., E-mail: angeline.kasina@fys.kuleuven.be, E-mail: wubbenhorst@fys.kuleuven.be

2015-12-28

Recently [S. Capponi, S. Napolitano, and M. Wübbenhorst, Nat. Commun. 3, 1233 (2012)], vapor deposited glasses of glycerol have been found to recover their super-cooled liquid state via a metastable, ordered liquid (MROL) state characterized by a tremendously enhanced dielectric strength along with a slow-down of the relaxation rate of the structural relaxation. To study the calorimetric signature of this phenomenon, we have implemented a chip-based, differential AC calorimeter in an organic molecular beam deposition setup, which allows the simultaneous measurement of dielectric relaxations via interdigitated comb electrodes and specific heat relaxation spectra during deposition and as function of themore » temperature. Heating of the as-deposited glass just above the bulk T{sub g} and subsequent cooling/reheating revealed a step-wise increase in c{sub p} by in total 9%, indicating unambiguously that glycerol, through slow vapour deposition, forms a thermodynamically stable glass, which has a specific heat as low as that of crystalline glycerol. Moreover, these glasses were found to show excellent kinetic stability as well as evidenced by both a high onset-temperature and quasi-isothermal recovery measurements at −75 °C. The second goal of the study was to elucidate the impact of the MROL state on the specific heat and its relaxation to the super-cooled state. Conversion of “MROL glycerol” to its “normal” (ordinary liquid, OL) state revealed a second, small (∼2%) increase of the glassy c{sub p}, a little gain (<10%) in the relaxed specific heat, and no signs of deviations of τ{sub cal} from that of normal “bulk” glycerol. These findings altogether suggest that the MROL state in glycerol comprises largely bulk-type glycerol that coexist with a minor volume fraction (<10%) of PVD-induced structural anomalies with a crystal-like calorimetric signature. Based on the new calorimetric findings, we have proposed a new physical picture that assumes

Vapor hydrogen peroxide as alternative to dry heat microbial reduction

NASA Astrophysics Data System (ADS)

Chung, S.; Kern, R.; Koukol, R.; Barengoltz, J.; Cash, H.

2008-09-01

The Jet Propulsion Laboratory (JPL), in conjunction with the NASA Planetary Protection Officer, has selected vapor phase hydrogen peroxide (VHP) sterilization process for continued development as a NASA approved sterilization technique for spacecraft subsystems and systems. The goal was to include this technique, with an appropriate specification, in NASA Procedural Requirements 8020.12 as a low-temperature complementary technique to the dry heat sterilization process. The VHP process is widely used by the medical industry to sterilize surgical instruments and biomedical devices, but high doses of VHP may degrade the performance of flight hardware, or compromise material compatibility. The goal for this study was to determine the minimum VHP process conditions for planetary protection acceptable microbial reduction levels. Experiments were conducted by the STERIS Corporation, under contract to JPL, to evaluate the effectiveness of vapor hydrogen peroxide for the inactivation of the standard spore challenge, Geobacillus stearothermophilus. VHP process parameters were determined that provide significant reductions in spore viability while allowing survival of sufficient spores for statistically significant enumeration. In addition to the obvious process parameters of interest: hydrogen peroxide concentration, number of injection cycles, and exposure duration, the investigation also considered the possible effect on lethality of environmental parameters: temperature, absolute humidity, and material substrate. This study delineated a range of test sterilizer process conditions: VHP concentration, process duration, a process temperature range for which the worst case D-value may be imposed, a process humidity range for which the worst case D-value may be imposed, and the dependence on selected spacecraft material substrates. The derivation of D-values from the lethality data permitted conservative planetary protection recommendations.

Changes in bioactive compounds and oxidative enzymes of fresh-cut pomegranate arils during storage as affected by deficit irrigation and postharvest vapor heat treatments.

PubMed

Peña-Estévez, María E; Gómez, Perla A; Artés, Francisco; Aguayo, Encarna; Martínez-Hernández, Ginés Benito; Galindo, Alejandro; Torecillas, Arturo; Artés-Hernández, Francisco

2016-12-01

The effect of postharvest vapor heat treatments at 95℃ (4, 7, and 10 s) regarding a conventional sanitizing treatment with 100 mg NaClO l -1 on enzyme activities (phenylalanine ammonia lyase, polyphenol oxidase, and peroxidase), phenolic content, and total antioxidant capacity of fresh-cut pomegranates arils throughout 18 days at 5℃ was studied. Furthermore, the effect of two sustained deficit irrigation (SDI) strategies, compared to a standardly irrigated control (CTRL), was also studied on such quality parameters throughout storage. Arils from CTRL-irrigated fruit registered phenylalanine ammonia lyase, peroxidase, and polyphenol oxidase initial activities of 60.6, 382, and 14.4 U g -1  fw, respectively. Arils from sustained deficit irrigation fruit registered 46-58% lower phenylalanine ammonia lyase values while polyphenol oxidase and peroxidase activities did not register great variants (<9%) among both sustained deficit irrigation treatments. Postharvest vapor heat treatments enhanced phenylalanine ammonia lyase activity in those samples from sustained deficit irrigation fruit although no great peroxidase and polyphenol oxidase (<2-5%) increases were observed. Arils from SDI 1 fruit registered higher phenolic content than those values reported for CTRL samples. However, phenolic compounds decreased during storage, in a greater extent for sustained deficit irrigation samples, although 7 s arils achieved better phenolic compounds retention in sustained deficit irrigation samples. Vapor heat treatments reduced up to twofold the total antioxidant capacity losses observed in samples sanitized by conventional NaOCl treatment during shelf life. Conclusively, postharvest vapor heat treatment for 7 and 10 s used to extend the shelf life of pomegranate arils up to 18 days at 5℃ reduced the losses of health-promoting compounds during storage compared to conventional NaOCl sanitizing treatment. © The Author(s) 2016.

33 CFR 154.808 - Vapor control system, general.

Code of Federal Regulations, 2010 CFR

2010-07-01

... inerted vapors of cargoes containing sulfur, provisions must be made to control heating from pyrophoric iron sulfide deposits in the vapor collection line. [CGD 88-102, 55 FR 25429, June 21, 1990, as amended...

33 CFR 154.808 - Vapor control system, general.

Code of Federal Regulations, 2011 CFR

2011-07-01

... inerted vapors of cargoes containing sulfur, provisions must be made to control heating from pyrophoric iron sulfide deposits in the vapor collection line. [CGD 88-102, 55 FR 25429, June 21, 1990, as amended...

33 CFR 154.808 - Vapor control system, general.

Code of Federal Regulations, 2012 CFR

2012-07-01

... inerted vapors of cargoes containing sulfur, provisions must be made to control heating from pyrophoric iron sulfide deposits in the vapor collection line. [CGD 88-102, 55 FR 25429, June 21, 1990, as amended...

33 CFR 154.808 - Vapor control system, general.

Code of Federal Regulations, 2013 CFR

2013-07-01

... inerted vapors of cargoes containing sulfur, provisions must be made to control heating from pyrophoric iron sulfide deposits in the vapor collection line. [CGD 88-102, 55 FR 25429, June 21, 1990, as amended...

Modeling water vapor and heat transfer in the normal and the intubated airways.

PubMed

Tawhai, Merryn H; Hunter, Peter J

2004-04-01

Intubation of the artificially ventilated patient with an endotracheal tube bypasses the usual conditioning regions of the nose and mouth. In this situation any deficit in heat or moisture in the air is compensated for by evaporation and thermal transfer from the pulmonary airway walls. To study the dynamics of heat and water transport in the intubated airway, a coupled system of nonlinear equations is solved in airway models with symmetric geometry and anatomically based geometry. Radial distribution of heat, water vapor, and velocity in the airway are described by power-law equations. Solution of the time-dependent system of equations yields dynamic airstream and mucosal temperatures and air humidity. Comparison of model results with two independent experimental studies in the normal and intubated airway shows a close correlation over a wide range of minute ventilation. Using the anatomically based model a range of spatially distributed temperature paths is demonstrated, which highlights the model's ability to predict thermal behavior in airway regions currently inaccessible to measurement. Accurate representation of conducting airway geometry is shown to be necessary for simulating mouth-breathing at rates between 15 and 100 l x min(-1), but symmetric geometry is adequate for the low minute ventilation and warm inspired air conditions that are generally supplied to the intubated patient.

Acoustically enhanced boiling heat transfer on a heated surface containing open microchannels

NASA Astrophysics Data System (ADS)

Boziuk, Thomas R.; Smith, Marc K.; Glezer, Ari

2011-11-01

Acoustic actuation is used to enhance boiling heat transfer on a submerged heated surface containing an array of open microchannels by controlling the formation and evolution of vapor bubbles and inhibiting the instability that leads to film boiling at the critical heat flux. The effect of actuation at millimeter and micrometer scales is investigated with emphasis on the behavior of bubble nucleation, growth, contact-line motion, condensation, and detachment. The results show that microchannels control the location of boiling and reduce the mean surface superheat. In addition, acoustic actuation increases the heat flux at a given surface temperature and leads to a significant increase in the critical heat flux, a reduction of the vapor mass above the surface, and the breakup of low-frequency vapor slug formation. Supported by ONR.

Numerical investigation of vessel heating using a copper vapor laser and a pulsed dye laser in treating vascular skin lesions

NASA Astrophysics Data System (ADS)

Pushkareva, A. E.; Ponomarev, I. V.; Isaev, A. A.; Klyuchareva, S. V.

2018-02-01

A computer simulation technique was employed to study the selective heating of a tissue vessel using emission from a pulsed copper vapor laser and a pulsed dye laser. The depth and size of vessels that could be selectively and safely removed were determined for the lasers under examination.

Large-capacity pump vaporizer for liquid hydrogen and nitrogen

NASA Technical Reports Server (NTRS)

Hauser, J. A.

1970-01-01

Pump vaporizer system delivers 500 standard cubic feet per minute of hydrogen or nitrogen, one system delivers both gases. Vacuum-jacketed pump discharges liquid hydrogen or liquid nitrogen into vaporizing system heated by ambient air. Principal characteristics of the flow and discharge system, pump, and vaporizer are given.

Solar vapor generation enabled by nanoparticles.

PubMed

Neumann, Oara; Urban, Alexander S; Day, Jared; Lal, Surbhi; Nordlander, Peter; Halas, Naomi J

2013-01-22

Solar illumination of broadly absorbing metal or carbon nanoparticles dispersed in a liquid produces vapor without the requirement of heating the fluid volume. When particles are dispersed in water at ambient temperature, energy is directed primarily to vaporization of water into steam, with a much smaller fraction resulting in heating of the fluid. Sunlight-illuminated particles can also drive H(2)O-ethanol distillation, yielding fractions significantly richer in ethanol content than simple thermal distillation. These phenomena can also enable important compact solar applications such as sterilization of waste and surgical instruments in resource-poor locations.

Expansion of effective wet bulb globe temperature for vapor impermeable protective clothing.

PubMed

Sakoi, Tomonori; Mochida, Tohru; Kurazumi, Yoshihito; Sawada, Shin-Ichi; Horiba, Yosuke; Kuwabara, Kohei

2018-01-01

The wet bulb globe temperature (WBGT) is an effective measure for risk screening to prevent heat dISOrders. However, a heat risk evaluation by WBGT requires adjustments depending on the clothing. In this study, we proposed a new effective WBGT (WBGT eff * ) for general vapor permeable clothing ensembles and vapor impermeable protective clothing that is applicable to occupants engaged in moderate intensity work with a metabolic heat production value of around 174W/m 2 . WBGT eff * enables the conversion of heat stress into the scale experienced by the occupant dressed in the basic clothing ensemble (work clothes) based on the heat balances for a human body. We confirmed that WBGT eff * was effective for expressing the critical thermal environments for the prescriptive zones for occupants wearing vapor impermeable protective clothing. Based on WBGT eff * , we succeeded in clarifying how the weights for natural wet bulb, globe, and air temperatures and the intercept changed depending on clothing properties and the surrounding environmental factors when heat stress is expressed by the weighted sum of natural wet bulb, globe, and air temperatures and the intercept. The weight of environmental temperatures (globe and air temperatures) for WBGT eff * for vapor impermeable protective clothing increased compared with that for general vapor permeable clothing, whereas that of the natural wet bulb temperature decreased. For WBGT eff * in outdoor conditions with a solar load, the weighting ratio of globe temperature increased and that of air temperature decreased with air velocity. Approximation equations of WBGT eff * were proposed for both general vapor permeable clothing ensembles and for vapor impermeable protective clothing. Copyright © 2017 Elsevier Ltd. All rights reserved.

Characteristics of Evaporator with a Lipuid-Vapor Separator

NASA Astrophysics Data System (ADS)

Ikeguchi, Masaki; Tanaka, Naoki; Yumikura, Tsuneo

Flow pattern of refrigerant in a heat exchanger tube changes depending on vapor quality, tube diameter, refrigerant flow rate and refrigerant properties. High flow rate causes mist flow where the quality is from 0.8 to 1.0. 1n this flow pattern, the liquid film detaches from the tube wall so that the heat flow is intervened. The heat transfer coefficient generally increases with the flow rate. But the pressure drop of refrigerant flow simultaneously increases and the region of the mist flow enlarges. In order to reduce the pressure drop and suppress the mist flow, we have developped a small liquid-vapor separator that removes the vapor from the evaporating refrigerant flow. This separator is equipped in the middle of the evaporator where the flow pattern is annular. The experiments to evaluate the effect of this separator were carried out and the following conclutions were obtained. (1) Average heat transfer coefficient increases by 30-60 %. (2) Pressure drop reduces by 20-30 %. (3) Cooling Capacity increases by 2-9 %.

Vacuum vapor deposition gun assembly

DOEpatents

Zeren, Joseph D.

1985-01-01

A vapor deposition gun assembly includes a hollow body having a cylindrical outer surface and an end plate for holding an adjustable heat sink, a hot hollow cathode gun, two magnets for steering the plasma from the gun into a crucible on the heat sink, and a shutter for selectively covering and uncovering the crucible.

Dynamics of vapor emissions at wire explosion thresholda)

NASA Astrophysics Data System (ADS)

Belony, Paul A.; Kim, Yong W.

2010-10-01

X-pinch plasmas have been actively studied in the recent years. Numerical simulation of the ramp-up of metallic vapor emissions from wire specimens shows that under impulsive Ohmic heating the wire core invariably reaches a supercritical state before explosion. The heating rate depends sensitively on the local wire resistance, leading to highly variable vapor emission flux along the wire. To examine the vapor emission process, we have visualized nickel wire explosions by means of shock formation in air. In a single explosion as captured by shadowgraphy, there usually appear several shocks with spherical or cylindrical wave front originating from different parts of the wire. Growth of various shock fronts in time is well characterized by a power-law scaling in one form or another. Continuum emission spectra are obtained and calibrated to measure temperature near the explosion threshold. Shock front structures and vapor plume temperature are examined.

Heat exchanger-accumulator

DOEpatents

Ecker, Amir L.

1980-01-01

What is disclosed is a heat exchanger-accumulator for vaporizing a refrigerant or the like, characterized by an upright pressure vessel having a top, bottom and side walls; an inlet conduit eccentrically and sealingly penetrating through the top; a tubular overflow chamber disposed within the vessel and sealingly connected with the bottom so as to define an annular outer volumetric chamber for receiving refrigerant; a heat transfer coil disposed in the outer volumetric chamber for vaporizing the liquid refrigerant that accumulates there; the heat transfer coil defining a passageway for circulating an externally supplied heat exchange fluid; transferring heat efficiently from the fluid; and freely allowing vaporized refrigerant to escape upwardly from the liquid refrigerant; and a refrigerant discharge conduit penetrating sealingly through the top and traversing substantially the length of the pressurized vessel downwardly and upwardly such that its inlet is near the top of the pressurized vessel so as to provide a means for transporting refrigerant vapor from the vessel. The refrigerant discharge conduit has metering orifices, or passageways, penetrating laterally through its walls near the bottom, communicating respectively interiorly and exteriorly of the overflow chamber for controllably carrying small amounts of liquid refrigerant and oil to the effluent stream of refrigerant gas.

The behavior of vapor bubbles during boiling enhanced with acoustics and open microchannels

NASA Astrophysics Data System (ADS)

Boziuk, Thomas; Smith, Marc K.; Glezer, Ari

2012-11-01

Boiling heat transfer on a submerged heated surface is enhanced by combining a grid of surface micromachined open channels and ultrasonic acoustic actuation to control the formation and evolution of vapor bubbles and to inhibit the instability that leads to film boiling at the critical heat flux (CHF). The microchannels provide nucleation sites for vapor bubble formation and enable the entrainment of bulk subcooled fluid to these sites for sustained evaporation. Acoustic actuation excites interfacial oscillations of the detached bubbles and leads to accelerated condensation in the bulk fluid, thereby limiting the formation of vapor columns that precede the CHF instability. The combined effects of microchannels and acoustic actuation are investigated experimentally with emphasis on bubble nucleation, growth, detachment, and condensation. It is shown that this hybrid approach leads to a significant increase in the critical heat flux, a reduction of the vapor mass above the surface, and the breakup of low-frequency vapor slug formation. A large-scale model of the microchannel grid reveals details of the flow near the nucleation site and shows that the presence of the microchannels decreases the surface superheat at a given heat flux. Supported by ONR.

Realizing controllable graphene nucleation by regulating the competition of hydrogen and oxygen during chemical vapor deposition heating.

PubMed

Zhang, Haoran; Zhang, Yaqian; Zhang, Yanhui; Chen, Zhiying; Sui, Yanping; Ge, Xiaoming; Deng, Rongxuan; Yu, Guanghui; Jin, Zhi; Liu, Xinyu

2016-08-24

Oxygen can passivate Cu surface active sites when graphene nucleates. Thus, the nucleation density is decreased. The CuO/Cu substrate was chosen for graphene domain synthesis in our study. The results indicate that the CuO/Cu substrate is beneficial for large-scale, single-crystal graphene domain synthesis. Graphene grown on the CuO/Cu substrate exhibits fewer nucleation sites than on Cu foils, suggesting that graphene follows an oxygen-dominating growth. Hydrogen treatment via a heating process could weaken the surface oxygen's role in limiting graphene nucleation under the competition of hydrogen and oxygen and could transfer the synthesis of graphene into a hydrogen-dominating growth. However, the competition only exists during the chemical vapor deposition heating process. For non-hydrogen heated samples, oxygen-dominating growth is experienced even though the samples are annealed in hydrogen for a long time after the heating process. With the temperature increases, the role of hydrogen gradually decreases. The balance of hydrogen and oxygen is adjusted by introducing hydrogen gas at a different heating temperatures. The oxygen concentration on the substrate surface is believed to determine the reactions mechanisms based on the secondary ion mass spectrometry test results. This study provides a new method for the controllable synthesis of graphene nucleation during a heating process.

Relation between heat of vaporization, ion transport, molar volume, and cation-anion binding energy for ionic liquids.

PubMed

Borodin, Oleg

2009-09-10

A number of correlations between heat of vaporization (H(vap)), cation-anion binding energy (E(+/-)), molar volume (V(m)), self-diffusion coefficient (D), and ionic conductivity for 29 ionic liquids have been investigated using molecular dynamics (MD) simulations that employed accurate and validated many-body polarizable force fields. A significant correlation between D and H(vap) has been found, while the best correlation was found for -log(DV(m)) vs H(vap) + 0.28E(+/-). A combination of enthalpy of vaporization and a fraction of the cation-anion binding energy was suggested as a measure of the effective cohesive energy for ionic liquids. A deviation of some ILs from the reported master curve is explained based upon ion packing and proposed diffusion pathways. No general correlations were found between the ion diffusion coefficient and molecular volume or the diffusion coefficient and cation/anion binding energy.

Model for the Vaporization of Mixed Organometallic Compounds in the Metalorganic Chemical Vapor Deposition of High Temperature Superconducting Films

NASA Technical Reports Server (NTRS)

Meng, Guangyao; Zhou, Gang; Schneider, Roger L.; Sarma, Bimal K.; Levy, Moises

1993-01-01

A model of the vaporization and mass transport of mixed organometallics from a single source for thin film metalorganic chemical vapor deposition is presented. A stoichiometric gas phase can be obtained from a mixture of the organometallics in the desired mole ratios, in spite of differences in the volatilities of the individual compounds. Proper film composition and growth rates are obtained by controlling the velocity of a carriage containing the organometallics through the heating zone of a vaporizer.

Vapor pressures and calculated heats of vaporization of concentrated nitric acid solutions in the composition range 71 to 89 percent nitrogen dioxide, 1 to 10 percent water, and in the temperature range 10 to 60 degrees C

NASA Technical Reports Server (NTRS)

Mckeown, A B; Belles, Frank E

1954-01-01

Total vapor pressures were measured for 16 acid mixtures of the ternary system nitric acid, nitrogen dioxide, and water within the temperature range 10 degrees to 60 degrees Celsius, and with the composition range 71 to 89 weight percent nitric acid, 7 to 20 weight percent nitrogen dioxide, and 1 to 10 weight percent water. Heats of vaporization were calculated from the vapor pressure measurements for each sample for the temperatures 25, 40, and 60 degrees Celsius. The ullage of the apparatus used for the measurements was 0.46. Ternary diagrams showing isobars as a function of composition of the system were constructed from experimental and interpolated data for the temperatures 25, 40, 45, and 60 degrees C and are presented herein.

Nonlinear dynamics of confined thin liquid-vapor bilayer systems with phase change

NASA Astrophysics Data System (ADS)

Kanatani, Kentaro; Oron, Alexander

2011-03-01

We numerically investigate the nonlinear evolution of the interface of a thin liquid-vapor bilayer system confined by rigid horizontal walls from both below and above. The lateral variation of the vapor pressure arising from phase change is taken into account in the present analysis. When the liquid (vapor) is heated (cooled) and gravity acts toward the liquid, the deflection of the interface monotonically grows, leading to a rupture of the vapor layer, whereas nonruptured stationary states are found when the liquid (vapor) is cooled (heated) and gravity acts toward the vapor. In the latter case, vapor-flow-driven convective cells are found in the liquid phase in the stationary state. The average vapor pressure and interface temperature deviate from their equilibrium values once the interface departs from the flat equilibrium state. Thermocapillarity does not have a significant effect near the thermodynamic equilibrium, but becomes important if the system significantly deviates from it.

Vapor-Generator Wand Helps To Reveal Airflow Patterns

NASA Technical Reports Server (NTRS)

Robelen, David B.

1993-01-01

In vapor-generator wand, liquid propylene glycol flows into electrically heated stainless-steel tube. Liquid boils in heated tube, and emerging vapor forms dense, smoke-like fog used to make airflow patterns visible. Built in variety of sizes, suitable for uses ranging from tabletop demonstrations to research in wind tunnels. For best viewing, plume illuminated by bright, focused incandescent spotlight at right angle to viewing direction. Viewing further enhanced by coating walls of test chamber with flat, dark color to minimize reflections and increase contrast.

Effects of Heat of Vaporization and Octane Sensitivity on Knock-Limited Spark Ignition Engine Performance

DOE Office of Scientific and Technical Information (OSTI.GOV)

Ratcliff, Matthew A; Burton, Jonathan L; Sindler, Petr

Knock-limited loads for a set of surrogate gasolines all having nominal 100 research octane number (RON), approximately 11 octane sensitivity (S), and a heat of vaporization (HOV) range of 390 to 595 kJ/kg at 25 degrees C were investigated. A single-cylinder spark-ignition engine derived from a General Motors Ecotec direct injection (DI) engine was used to perform load sweeps at a fixed intake air temperature (IAT) of 50 degrees C, as well as knock-limited load measurements across a range of IATs up to 90 degrees C. Both DI and pre-vaporized fuel (supplied by a fuel injector mounted far upstream ofmore » the intake valves and heated intake runner walls) experiments were performed to separate the chemical and thermal effects of the fuels' knock resistance. The DI load sweeps at 50 degrees C intake air temperature showed no effect of HOV on the knock-limited performance. The data suggest that HOV acts as a thermal contributor to S under the conditions studied. Measurement of knock-limited loads from the IAT sweeps for DI at late combustion phasing showed that a 40 vol% ethanol (E40) blend provided additional knock resistance at the highest temperatures, compared to a 20 vol% ethanol blend and hydrocarbon fuel with similar RON and S. Using the pre-vaporized fuel system, all the high S fuels produced nearly identical knock-limited loads at each temperature across the range of IATs studied. For these fuels RON ranged from 99.2 to 101.1 and S ranged from 9.4 to 12.2, with E40 having the lowest RON and highest S. The higher knock-limited loads for E40 at the highest IATs examined were consistent with the slightly higher S for this fuel, and the lower engine operating condition K values arising from use of this fuel. The study highlights how fuel HOV can affect the temperature at intake valve closing, and consequently the pressure-temperature history of the end gas leading to more negative values of K, thereby enhancing the effect of S on knock resistance.« less

Carbonyl Compounds Produced by Vaporizing Cannabis Oil Thinning Agents.

PubMed

Troutt, William D; DiDonato, Matthew D

2017-11-01

Cannabis use has increased in the United States, particularly the use of vaporized cannabis oil, which is often mixed with thinning agents for use in vaporizing devices. E-cigarette research shows that heated thinning agents produce potentially harmful carbonyls; however, similar studies have not been conducted (1) with agents that are commonly used in the cannabis industry and (2) at temperatures that are appropriate for cannabis oil vaporization. The goal of this study was to determine whether thinning agents used in the cannabis industry produce potentially harmful carbonyls when heated to a temperature that is appropriate for cannabis oil vaporization. Four thinning agents (propylene glycol [PG], vegetable glycerin [VG], polyethylene glycol 400 [PEG 400], and medium chain triglycerides [MCT]) were heated to 230°C and the resulting vapors were tested for acetaldehyde, acrolein, and formaldehyde. Each agent was tested three times. Testing was conducted in a smoking laboratory. Carbonyl levels were measured in micrograms per puff block. Analyses showed that PEG 400 produced significantly higher levels of acetaldehyde and formaldehyde than PG, MCT, and VG. Formaldehyde production was also significantly greater in PG compared with MCT and VG. Acrolein production did not differ significantly across the agents. PG and PEG 400 produced high levels of acetaldehyde and formaldehyde when heated to 230°C. Formaldehyde production from PEG 400 isolate was particularly high, with one inhalation accounting for 1.12% of the daily exposure limit, nearly the same exposure as smoking one cigarette. Because PG and PEG 400 are often mixed with cannabis oil, individuals who vaporize cannabis oil products may risk exposure to harmful formaldehyde levels. Although more research is needed, consumers and policy makers should consider these potential health effects before use and when drafting cannabis-related legislation.

Unsteady heat transfer performance of heat pipe with axially swallow-tailed microgrooves

NASA Astrophysics Data System (ADS)

Zhang, R. P.

2017-04-01

A mathematical model is developed for predicting the transient heat transfer and fluid flow of heat pipe with axially swallow-tailed microgrooves. The effects of liquid convective heat transfer in the microgrooves, liquid-vapor interfacial phase-change heat transfer and liquid-vapor interfacial shear stress are accounted for in the present model. The coupled non-linear control equations are solved numerically. Mass flow rate at the interface is obtained from the application of kinetic theory. Time variation of wall temperature is studied from the initial startup to steady state. The numerical results are verified by experiments. Time constants for startup and shutdown operation are defined to determine how fast a heat pipe responds to an applied input heat flux, which slightly decreases with increasing heat load.

Analysis of Thermally Denatured Depth in Laser Vaporization for Benign Prostatic Hyperplasia using a Simulation of Light Propagation and Heat Transfer (secondary publication)

PubMed Central

Takada, Junya; Honda, Norihiro; Hazama, Hisanao; Ioritani, Naomasa

2016-01-01

Background and Aims: Laser vaporization of the prostate is expected as a less invasive treatment for benign prostatic hyperplasia (BPH), via the photothermal effect. In order to develop safer and more effective laser vaporization of the prostate, it is essential to set optimal irradiation parameters based on quantitative evaluation of temperature distribution and thermally denatured depth in prostate tissue. Method: A simulation model was therefore devised with light propagation and heat transfer calculation, and the vaporized and thermally denatured depths were estimated by the simulation model. Results: The results of the simulation were compared with those of an ex vivo experiment and clinical trial. Based on the accumulated data, the vaporized depth strongly depended on the distance between the optical fiber and the prostate tissue, and it was suggested that contact laser irradiation could vaporize the prostate tissue most effectively. Additionally, it was suggested by analyzing thermally denatured depth comprehensively that laser irradiation at the distance of 3 mm between the optical fiber and the prostate tissue was useful for hemostasis. Conclusions: This study enabled quantitative and reproducible analysis of laser vaporization for BPH and will play a role in clarification of the safety and efficacy of this treatment. PMID:28765672

Control of flow through a vapor generator

DOEpatents

Radcliff, Thomas D.

2005-11-08

In a Rankine cycle system wherein a vapor generator receives heat from exhaust gases, provision is made to avoid overheating of the refrigerant during ORC system shut down while at the same time preventing condensation of those gases within the vapor generator when its temperature drops below a threshold temperature by diverting the flow of hot gases to ambient and to thereby draw ambient air through the vapor generator in the process. In one embodiment, a bistable ejector is adjustable between one position, in which the hot gases flow through the vapor generator, to another position wherein the gases are diverted away from the vapor generator. Another embodiment provides for a fixed valve ejector with a bias towards discharging to ambient, but with a fan on the downstream side of said vapor generator for overcoming this bias.

Suppressed beta relaxations and reduced heat capacity in ultrastable organic glasses prepared by physical vapor deposition

NASA Astrophysics Data System (ADS)

Ediger, Mark

Glasses play an important role in technology as a result of their macroscopic homogeneity (e.g., the clarity of window glass) and our ability to tune properties through composition changes. A problem with liquid-cooled glasses is that they exhibit marginal kinetic stability and slowly evolve towards lower energy glasses and crystalline states. In contrast, we have shown that physical vapor deposition can prepare glasses with very high kinetic stability. These materials have properties expected for ``million-year-old'' glasses, including high density, low enthalpy, and high mechanical moduli. We have used nanocalorimetry to show that these high stability glasses have lower heat capacities than liquid-cooled glasses for a number of molecular systems. Dielectric relaxation has been used to show that the beta relaxation can be suppressed by nearly a factor of four in vapor-deposited toluene glasses, indicating a very tight packing environment. Consistent with this view, computer simulations of high stability glasses indicate reduced Debye-Waller factors. These high stability materials raise interesting questions about the limiting properties of amorphous packing arrangements.

Analysis of a Flooded Heat Exchanger

ERIC Educational Resources Information Center

Fink, Aaron H.; Luyben, William L.

2015-01-01

Flooded heat exchangers are often used in industry to reduce the required heat-transfer area and the size of utility control valves. These units involve a condensing vapor on the hot side that accumulates as a liquid phase in the lower part of the vessel. The heat transfer occurs mostly in the vapor space, but the condensate becomes somewhat…

Expanding Taylor bubble under constant heat flux

NASA Astrophysics Data System (ADS)

Voirand, Antoine; Benselama, Adel M.; Ayel, Vincent; Bertin, Yves

2016-09-01

Modelization of non-isothermal bubbles expanding in a capillary, as a contribution to the understanding of the physical phenomena taking place in Pulsating Heat Pipes (PHPs), is the scope of this paper. The liquid film problem is simplified and solved, while the thermal problem takes into account a constant heat flux density applied at the capillary tube wall, exchanging with the liquid film surrounding the bubble and also with the capillary tube outside medium. The liquid slug dynamics is solved using the Lucas-Washburn equation. Mass and energy balance on the vapor phase allow governing equations of bubble expansion to be written. The liquid and vapor phases are coupled only through the saturation temperature associated with the vapor pressure, assumed to be uniform throughout the bubble. Results show an over-heating of the vapor phase, although the particular thermal boundary condition used here always ensures an evaporative mass flux at the liquid-vapor interface. Global heat exchange is also investigated, showing a strong decreasing of the PHP performance to convey heat by phase change means for large meniscus velocities.

Zeolite Y Adsorbents with High Vapor Uptake Capacity and Robust Cycling Stability for Potential Applications in Advanced Adsorption Heat Pumps.

PubMed

Li, Xiansen; Narayanan, Shankar; Michaelis, Vladimir K; Ong, Ta-Chung; Keeler, Eric G; Kim, Hyunho; McKay, Ian S; Griffin, Robert G; Wang, Evelyn N

2015-01-01

Modular and compact adsorption heat pumps (AHPs) promise an energy-efficient alternative to conventional vapor compression based heating, ventilation and air conditioning systems. A key element in the advancement of AHPs is the development of adsorbents with high uptake capacity, fast intracrystalline diffusivity and durable hydrothermal stability. Herein, the ion exchange of NaY zeolites with ingoing Mg 2+ ions is systematically studied to maximize the ion exchange degree (IED) for improved sorption performance. It is found that beyond an ion exchange threshold of 64.1%, deeper ion exchange does not benefit water uptake capacity or characteristic adsorption energy, but does enhance the vapor diffusivity. In addition to using water as an adsorbate, the uptake properties of Mg,Na-Y zeolites were investigated using 20 wt.% MeOH aqueous solution as a novel anti-freeze adsorbate, revealing that the MeOH additive has an insignificant influence on the overall sorption performance. We also demonstrated that the labscale synthetic scalability is robust, and that the tailored zeolites scarcely suffer from hydrothermal stability even after successive 108-fold adsorption/desorption cycles. The samples were analyzed using N 2 sorption, 27 Al/ 29 Si MAS NMR spectroscopy, ICP-AES, dynamic vapor sorption, SEM, Fick's 2 nd law and D-R equation regressions. Among these, close examination of sorption isotherms for H 2 O and N 2 adsorbates allows us to decouple and extract some insightful information underlying the complex water uptake phenomena. This work shows the promising performance of our modified zeolites that can be integrated into various AHP designs for buildings, electronics, and transportation applications.

Tubing For Sampling Hydrazine Vapor

NASA Technical Reports Server (NTRS)

Travis, Josh; Taffe, Patricia S.; Rose-Pehrsson, Susan L.; Wyatt, Jeffrey R.

1993-01-01

Report evaluates flexible tubing used for transporting such hypergolic vapors as those of hydrazines for quantitative analysis. Describes experiments in which variety of tubing materials, chosen for their known compatibility with hydrazine, flexibility, and resistance to heat.

Heat Sponge: A Concept for Mass-Efficient Heat Storage

NASA Technical Reports Server (NTRS)

Splinter, Scott C.; Blosser, Max L.; Gifford, Andrew R.

2008-01-01

The heat sponge is a device for mass-efficient storage of heat. It was developed to be incorporated in the substructure of a re-entry vehicle to reduce thermal- protection-system requirements. The heat sponge consists of a liquid/vapor mixture contained within a number of miniature pressure vessels that can be embedded within a variety of different types of structures. As temperature is increased, pressure in the miniature pressure vessels also increases so that heat absorbed through vaporization of the liquid is spread over a relatively large temperature range. Using water as a working fluid, the heat-storage capacity of the liquid/vapor mixture is many times higher than that of typical structural materials and is well above that of common phase change materials over a temperature range of 200 F to 700 F. The use of pure ammonia as the working fluid provides a range of application between 432 deg R and 730 deg R, or the use of the more practical water-ammonia solution provides a range of application between 432 deg R and 1160 deg R or in between that of water and pure ammonia. Prototype heat sponges were fabricated and characterized. These heat sponges consisted of 1.0-inch-diameter, hollow, stainless-steel spheres with a wall thickness of 0.020 inches which had varying percentages of their interior volumes filled with water and a water-ammonia solution. An apparatus to measure the heat stored in these prototype heat sponges was designed, fabricated, and verified. The heat-storage capacity calculated from measured temperature histories is compared to numerical predictions.

The Lithium Vapor Box Divertor

NASA Astrophysics Data System (ADS)

Goldston, Robert; Hakim, Ammar; Hammett, Gregory; Jaworski, Michael; Myers, Rachel; Schwartz, Jacob

2015-11-01

Projections of scrape-off layer width to a demonstration power plant suggest an immense parallel heat flux, of order 12 GW/m2, which will necessitate nearly fully detached operation. Building on earlier work by Nagayama et al. and by Ono et al., we propose to use a series of differentially pumped boxes filled with lithium vapor to isolate the buffering vapor from the main plasma chamber, allowing stable detachment. This powerful differential pumping is only available for condensable vapors, not conventional gases. We demonstrate the properties of such a system through conservation laws for vapor mass and enthalpy, and then include plasma entrainment and ultimately an estimate of radiated power. We find that full detachment should be achievable with little leakage of lithium to the main plasma chamber. We also present progress towards solving the Navier-Stokes equation numerically for the chain of vapor boxes, including self-consistent wall boundary conditions and fully-developed shocks, as well as concepts for an initial experimental demonstration-of-concept. This work supported by DOE Contract No. DE-AC02-09CH11466.

Capillary pumped loop body heat exchanger

NASA Technical Reports Server (NTRS)

Swanson, Theodore D. (Inventor); Wren, deceased, Paul (Inventor)

1998-01-01

A capillary pumped loop for transferring heat from one body part to another body part, the capillary pumped loop comprising a capillary evaporator for vaporizing a liquid refrigerant by absorbing heat from a warm body part, a condenser for turning a vaporized refrigerant into a liquid by transferring heat from the vaporized liquid to a cool body part, a first tube section connecting an output port of the capillary evaporator to an input of the condenser, and a second tube section connecting an output of the condenser to an input port of the capillary evaporator. A wick may be provided within the condenser. A pump may be provided between the second tube section and the input port of the capillary evaporator. Additionally, an esternal heat source or heat sink may be utilized.

Combined rankine and vapor compression cycles

DOEpatents

Radcliff, Thomas D.; Biederman, Bruce P.; Brasz, Joost J.

2005-04-19

An organic rankine cycle system is combined with a vapor compression cycle system with the turbine generator of the organic rankine cycle generating the power necessary to operate the motor of the refrigerant compressor. The vapor compression cycle is applied with its evaporator cooling the inlet air into a gas turbine, and the organic rankine cycle is applied to receive heat from a gas turbine exhaust to heat its boiler within one embodiment, a common condenser is used for the organic rankine cycle and the vapor compression cycle, with a common refrigerant, R-245a being circulated within both systems. In another embodiment, the turbine driven generator has a common shaft connected to the compressor to thereby eliminate the need for a separate motor to drive the compressor. In another embodiment, an organic rankine cycle system is applied to an internal combustion engine to cool the fluids thereof, and the turbo charged air is cooled first by the organic rankine cycle system and then by an air conditioner prior to passing into the intake of the engine.

A semiempirical correlation between enthalpy of vaporization and saturation concentration for organic aerosol.

PubMed

Epstein, Scott A; Riipinen, Ilona; Donahue, Neil M

2010-01-15

To model the temperature-induced partitioning of semivolatile organics in laboratory experiments or atmospheric models, one must know the appropriate heats of vaporization. Current treatments typically assume a constant value of the heat of vaporization or else use specific values from a small set of surrogate compounds. With published experimental vapor-pressure data from over 800 organic compounds, we have developed a semiempirical correlation between the saturation concentration (C*, microg m(-3)) and the heat of vaporization (deltaH(VAP), kJ mol(-1)) for organics in the volatility basis set. Near room temperature, deltaH(VAP) = -11 log(10)C(300)(*) + 129. Knowledge of the relationship between C* and deltaH(VAP) constrains a free parameter in thermodenuder data analysis. A thermodenuder model using our deltaH(VAP) values agrees well with thermal behavior observed in laboratory experiments.

Impact of air and water vapor environments on the hydrophobicity of surfaces.

PubMed

Weisensee, Patricia B; Neelakantan, Nitin K; Suslick, Kenneth S; Jacobi, Anthony M; King, William P

2015-09-01

Droplet wettability and mobility play an important role in dropwise condensation heat transfer. Heat exchangers and heat pipes operate at liquid-vapor saturation. We hypothesize that the wetting behavior of liquid water on microstructures surrounded by pure water vapor differs from that for water droplets in air. The static and dynamic contact angles and contact angle hysteresis of water droplets were measured in air and pure water vapor environments inside a pressure vessel. Pressures ranged from 60 to 1000 mbar, with corresponding saturation temperatures between 36 and 100°C. The wetting behavior was studied on four hydrophobic surfaces: flat Teflon-coated, micropillars, micro-scale meshes, and nanoparticle-coated with hierarchical micro- and nanoscale roughness. Static advancing contact angles are 9° lower in the water vapor environment than in air on a flat surface. One explanation for this reduction in contact angles is water vapor adsorption to the Teflon. On microstructured surfaces, the vapor environment has little effect on the static contact angles. In all cases, variations in pressure and temperature do not influence the wettability and mobility of the water droplets. In most cases, advancing contact angles increase and contact angle hysteresis decreases when the droplets are sliding or rolling down an inclined surface. Copyright © 2015 Elsevier Inc. All rights reserved.

Metal vapor laser including hot electrodes and integral wick

DOEpatents

Ault, Earl R.; Alger, Terry W.

1995-01-01

A metal vapor laser, specifically one utilizing copper vapor, is disclosed herein. This laser utilizes a plasma tube assembly including a thermally insulated plasma tube containing a specific metal, e.g., copper, and a buffer gas therein. The laser also utilizes means including hot electrodes located at opposite ends of the plasma tube for electrically exciting the metal vapor and heating its interior to a sufficiently high temperature to cause the metal contained therein to vaporize and for subjecting the vapor to an electrical discharge excitation in order to lase. The laser also utilizes external wicking arrangements, that is, wicking arrangements located outside the plasma tube.

Metal vapor laser including hot electrodes and integral wick

DOEpatents

Ault, E.R.; Alger, T.W.

1995-03-07

A metal vapor laser, specifically one utilizing copper vapor, is disclosed herein. This laser utilizes a plasma tube assembly including a thermally insulated plasma tube containing a specific metal, e.g., copper, and a buffer gas therein. The laser also utilizes means including hot electrodes located at opposite ends of the plasma tube for electrically exciting the metal vapor and heating its interior to a sufficiently high temperature to cause the metal contained therein to vaporize and for subjecting the vapor to an electrical discharge excitation in order to lase. The laser also utilizes external wicking arrangements, that is, wicking arrangements located outside the plasma tube. 5 figs.

Design and experimental study of an integrated vapor chamber-thermal energy storage system

NASA Astrophysics Data System (ADS)

Kota, Krishna M.

Future defense, aerospace and automotive technologies involve electronic systems that release high pulsed waste heat like during high power microwave and laser diode applications in tactical and combat aircraft, and electrical and electronic systems in hybrid electric vehicles, which will require the development of an efficient thermal management system. A key design issue is the need for fast charging so as not to overheat the key components. The goal of this work is to study the fabrication and technology implementation feasibility of a novel high energy storage, high heat flux passive heat sink. Key focus is to verify by theory and experiments, the practicability of using phase change materials as a temporary storage of waste heat for heat sink applications. The reason for storing the high heat fluxes temporarily is to be able to reject the heat at the average level when the heat source is off. Accordingly, a concept of a dual latent heat sink intended for moderate to low thermal duty cycle electronic heat sink applications is presented. This heat sink design combines the features of a vapor chamber with rapid thermal energy storage employing graphite foam inside the heat storage facility along with phase change materials and is attractive owing to its passive operation unlike some of the current thermal management techniques for cooling of electronics employing forced air circulation or external heat exchangers. In addition to the concept, end-application dependent criteria to select an optimized design for this dual latent heat sink are presented. A thermal resistance concept based design tool/model has been developed to analyze and optimize the design for experiments. The model showed that it is possible to have a dual latent heat sink design capable of handling 7 MJ of thermal load at a heat flux of 500 W/cm2 (over an area of 100 cm 2) with a volume of 0.072 m3 and weighing about 57.5 kg. It was also found that with such high heat flux absorption capability

Method for the generation of variable density metal vapors which bypasses the liquidus phase

DOEpatents

Kunnmann, Walter; Larese, John Z.

2001-01-01

The present invention provides a method for producing a metal vapor that includes the steps of combining a metal and graphite in a vessel to form a mixture; heating the mixture to a first temperature in an argon gas atmosphere to form a metal carbide; maintaining the first temperature for a period of time; heating the metal carbide to a second temperature to form a metal vapor; withdrawing the metal vapor and the argon gas from the vessel; and separating the metal vapor from the argon gas. Metal vapors made using this method can be used to produce uniform powders of the metal oxide that have narrow size distribution and high purity.

Methods for forming wellbores in heated formations

DOEpatents

Guimerans, Rosalvina Ramona; Mansure, Arthur James

2012-09-25

A method for forming a wellbore in a heated formation includes flowing liquid cooling fluid to a bottom hole assembly in a wellbore in a heated formation. At least a portion of the liquid cooling fluid is vaporized at or near a region to be cooled. Vaporizing the liquid cooling fluid absorbs heat from the region to be cooled.

Chemical vapor infiltration using microwave energy

DOEpatents

Devlin, David J.; Currier, Robert P.; Laia, Jr., Joseph R.; Barbero, Robert S.

1993-01-01

A method for producing reinforced ceramic composite articles by means of chemical vapor infiltration and deposition in which an inverted temperature gradient is utilized. Microwave energy is the source of heat for the process.

Re-evaluation of the reported experimental values of the heat of vaporization of N-methylacetamide

PubMed Central

MacKerell, Alexander D.; Shim, Ji Hyun; Anisimov, Victor M.

2010-01-01

The accuracy of empirical force fields is inherently related to the quality of the target data used for optimization of the model. With the heat of vaporization (ΔHvap) of N-methylacetamide (NMA), a range of values have been reported as target data for optimization of the nonbond parameters associated with the peptide bond in proteins. In the present work, the original experimental data and Antoine constants used for the determination of the ΔHvap of NMA are reanalyzed. Based on this analysis, the wide range of ΔHvap values reported in the literature are shown to be due to incorrect reporting of the temperatures at which the original values were extracted and limitations in the quality of experimental vapor pressure-temperature data over a wide range of temperatures. Taking these problems into account, a consistent ΔHvap value is extracted from three studies for which experimental data are available. This analysis suggests that the most reliable value for ΔHvap is 13.0±0.1 at 410 K for use in force field optimization studies. The present results also indicate that similar analyses, including analysis of Antoine constants alone, may be of utility when reported ΔHvap values are not consistent for a given neat liquid. PMID:20445813

The Heat and Mass Transfer Processes at the Cooling of Strong Heated Sphere in a Cold Liquid

NASA Astrophysics Data System (ADS)

Puzina, Yu Yu

2017-10-01

Some new experimental results of continuum mechanics problems in two-phase systems are described. The processes of heat and mass transfer during cooling of strong heated sphere in the subcooled liquid are studied. Due to high level of heater temperature the stable vapor film is formed on the sphere surface. Calculation of steady-state transport processes at vapor - water interface is carried out using methods of molecular-kinetic theory. Heat transfer in vapor by thermal conductivity and natural convection in liquid are considered. Pressure balance is provided by hydrostatic pressure and non-equilibrium boundary condition. The results of the calculations are analyzed by comparison with previous data and experimental results.

Chemical Vapor Deposition of Turbine Thermal Barrier Coatings

NASA Technical Reports Server (NTRS)

Haven, Victor E.

1999-01-01

Ceramic thermal barrier coatings extend the operating temperature range of actively cooled gas turbine components, therefore increasing thermal efficiency. Performance and lifetime of existing ceram ic coatings are limited by spallation during heating and cooling cycles. Spallation of the ceramic is a function of its microstructure, which is determined by the deposition method. This research is investigating metalorganic chemical vapor deposition (MOCVD) of yttria stabilized zirconia to improve performance and reduce costs relative to electron beam physical vapor deposition. Coatings are deposited in an induction-heated, low-pressure reactor at 10 microns per hour. The coating's composition, structure, and response to the turbine environment will be characterized.

Monogroove liquid heat exchanger

NASA Technical Reports Server (NTRS)

Brown, Richard F. (Inventor); Edelstein, Fred (Inventor)

1990-01-01

A liquid supply control is disclosed for a heat transfer system which transports heat by liquid-vapor phase change of a working fluid. An assembly (10) of monogroove heat pipe legs (15) can be operated automatically as either heat acquisition devices or heat discharge sources. The liquid channels (27) of the heat pipe legs (15) are connected to a reservoir (35) which is filled and drained by respective filling and draining valves (30, 32). Information from liquid level sensors (50, 51) on the reservoir (35) is combined (60) with temperature information (55) from the liquid heat exchanger (12) and temperature information (56) from the assembly vapor conduit (42) to regulate filling and draining of the reservoir (35), so that the reservoir (35) in turn serves the liquid supply/drain needs of the heat pipe legs (15), on demand, by passive capillary action (20, 28).

Modeling of a heat sink and high heat flux vapor chamber

NASA Astrophysics Data System (ADS)

Vadnjal, Aleksander

An increasing demand for a higher heat flux removal capability within a smaller volume for high power electronics led us to focus on a novel cold plate design. A high heat flux evaporator and micro channel heat sink are the main components of a cold plate which is capable of removing couple of 100 W/cm2. In order to describe performance of such porous media device a proper modeling has to be addressed. A universal approach based on the volume average theory (VAT) to transport phenomena in porous media is shown. An approach on how to treat the closure for momentum and energy equations is addressed and a proper definition for friction factors and heat transfer coefficients are discussed. A numerical scheme using a solution to Navier-Stokes equations over a representative elementary volume (REV) and the use of VAT is developed to show how to compute friction factors and heat transfer coefficients. The calculation show good agreement with the experimental data. For the heat transfer coefficient closure, a proper average for both fluid and solid is investigated. Different types of heating are also investigated in order to determine how it influences the heat transfer coefficient. A higher heat fluxes in small area condensers led us to the micro channels in contrast to the classical heat fin design. A micro channel can have various shapes to enhance heat transfer, but the shape that will lead to a higher heat flux removal with a moderate pumping power needs to be determined. The standard micro-channel terminology is usually used for channels with a simple cross section, e.g. square, round, triangle, etc., but here the micro channel cross section is going to be expanded to describe more complicated and interconnected micro scale channel cross sections. The micro channel geometries explored are pin fins (in-line and staggered) and sintered porous micro channels. The problem solved here is a conjugate problem involving two heat transfer mechanisms; (1) porous media

Explosive vapor detection payload for small robots

NASA Astrophysics Data System (ADS)

Stimac, Phil J.; Pettit, Michael; Wetzel, John P.; Haas, John W.

2013-05-01

Detection of explosive hazards is a critical component of enabling and improving operational mobility and protection of US Forces. The Autonomous Mine Detection System (AMDS) developed by the US Army RDECOM CERDEC Night Vision and Electronic Sensors Directorate (NVESD) is addressing this challenge for dismounted soldiers. Under the AMDS program, ARA has developed a vapor sampling system that enhances the detection of explosive residues using commercial-off-the-shelf (COTS) sensors. The Explosives Hazard Trace Detection (EHTD) payload is designed for plug-and-play installation and operation on small robotic platforms, addressing critical Army needs for more safely detecting concealed or exposed explosives in areas such as culverts, walls and vehicles. In this paper, we describe the development, robotic integration and performance of the explosive vapor sampling system, which consists of a sampling "head," a vapor transport tube and an extendable "boom." The sampling head and transport tube are integrated with the boom, allowing samples to be collected from targeted surfaces up to 7-ft away from the robotic platform. During sample collection, an IR lamp in the sampling head is used to heat a suspected object/surface and the vapors are drawn through the heated vapor transport tube to an ion mobility spectrometer (IMS) for detection. The EHTD payload is capable of quickly (less than 30 seconds) detecting explosives such as TNT, PETN, and RDX at nanogram levels on common surfaces (brick, concrete, wood, glass, etc.).

Heat pump evaluation for Space Station ATCS evolution

NASA Technical Reports Server (NTRS)

Ames, Brian E.; Petete, Patricia A.

1991-01-01

A preliminary feasibility assessment of the application of a vapor compression heat pump to the Active Thermal Control System (ATCS) of SSF is presented. This paper focuses on the methodology of raising the surface temperature of the radiators for improved heat rejection. Some of the effects of the vapor compression cycle on SSF examined include heat pump integration into ATCS, constraints on the heat pump operating parameters, and heat pump performance enhancements.

Nonazeotropic Heat Pump

NASA Technical Reports Server (NTRS)

Ealker, David H.; Deming, Glenn

1991-01-01

Heat pump collects heat from water circulating in heat-rejection loop, raises temperature of collected heat, and transfers collected heat to water in separate pipe. Includes sealed motor/compressor with cooling coils, evaporator, and condenser, all mounted in outer housing. Gradients of temperature in evaporator and condenser increase heat-transfer efficiency of vapor-compression cycle. Intended to recover relatively-low-temperature waste heat and use it to make hot water.

The impact of vaporized nanoemulsions on ultrasound-mediated ablation.

PubMed

Zhang, Peng; Kopechek, Jonathan A; Porter, Tyrone M

2013-01-01

The clinical feasibility of using high-intensity focused ultrasound (HIFU) for ablation of solid tumors is limited by the high acoustic pressures and long treatment times required. The presence of microbubbles during sonication can increase the absorption of acoustic energy and accelerate heating. However, formation of microbubbles within the tumor tissue remains a challenge. Phase-shift nanoemulsions (PSNE) have been developed as a means for producing microbubbles within tumors. PSNE are emulsions of submicron-sized, lipid-coated, and liquid perfluorocarbon droplets that can be vaporized into microbubbles using short (<1 ms), high-amplitude (>5 MPa) acoustic pulses. In this study, the impact of vaporized phase-shift nanoemulsions on the time and acoustic power required for HIFU-mediated thermal lesion formation was investigated in vitro. PSNE containing dodecafluoropentane were produced with narrow size distributions and mean diameters below 200 nm using a combination of sonication and extrusion. PSNE was dispersed in albumin-containing polyacrylamide gel phantoms for experimental tests. Albumin denatures and becomes opaque at temperatures above 58°C, enabling visual detection of lesions formed from denatured albumin. PSNE were vaporized using a 30-cycle, 3.2-MHz, at an acoustic power of 6.4 W (free-field intensity of 4,586 W/cm(2)) pulse from a single-element, focused high-power transducer. The vaporization pulse was immediately followed by a 15-s continuous wave, 3.2-MHz signal to induce ultrasound-mediated heating. Control experiments were conducted using an identical procedure without the vaporization pulse. Lesion formation was detected by acquiring video frames during sonication and post-processing the images for analysis. Broadband emissions from inertial cavitation (IC) were passively detected with a focused, 2-MHz transducer. Temperature measurements were acquired using a needle thermocouple. Bubbles formed at the HIFU focus via PSNE vaporization

Chemical heat pump

DOEpatents

Greiner, Leonard

1984-01-01

A chemical heat pump system is disclosed for use in heating and cooling structures such as residences or commercial buildings. The system is particularly adapted to utilizing solar energy, but also increases the efficiency of other forms of thermal energy when solar energy is not available. When solar energy is not available for relatively short periods of time, the heat storage capacity of the chemical heat pump is utilized to heat the structure, as during nighttime hours. The design also permits home heating from solar energy when the sun is shining. The entire system may be conveniently rooftop located. In order to facilitate installation on existing structures, the absorber and vaporizer portions of the system may each be designed as flat, thin wall, thin pan vessels which materially increase the surface area available for heat transfer. In addition, this thin, flat configuration of the absorber and its thin walled (and therefore relatively flexible) construction permits substantial expansion and contraction of the absorber material during vaporization and absorption without generating voids which would interfere with heat transfer.

Chemical heat pump

DOEpatents

Greiner, Leonard

1981-01-01

A chemical heat pump system is disclosed for use in heating and cooling structures such as residences or commercial buildings. The system is particularly adapted to utilizing solar energy, but also increases the efficiency of other forms of thermal energy when solar energy is not available. When solar energy is not available for relatively short periods of time, the heat storage capacity of the chemical heat pump is utilized to heat the structure, as during nighttime hours. The design also permits home heating from solar energy when the sun is shining. The entire system may be conveniently rooftop located. In order to facilitate installation on existing structures, the absorber and vaporizer portions of the system may each be designed as flat, thin wall, thin pan vessels which materially increase the surface area available for heat transfer. In addition, this thin, flat configuration of the absorber and its thin walled (and therefore relatively flexible) construction permits substantial expansion and contraction of the absorber material during vaporization and absorption without generating voids which would interfere with heat transfer.

Chemical heat pump

DOEpatents

Greiner, Leonard

1984-01-01

A chemical heat pump system is disclosed for use in heating and cooling structures such as residences or commercial buildings. The system is particularly adapted to utilizing solar energy, but also increases the efficiency of other forms of thermal energy when solar energy is not available. When solar energy is not available for relatively short periods of time, the heat storage capacity of the chemical heat pump is utilized to heat the structure, as during nighttime hours. The design also permits home heating from solar energy when the sun is shining. The entire system may be conveniently rooftop located. In order to facilitate intallation on existing structures, the absorber and vaporizer portions of the system may each be designed as flat, thin wall, thin pan vessels which materially increase the surface area available for heat transfer. In addition, this thin, flat configuration of the absorber and its thin walled (and therefore relatively flexible) construction permits substantial expansion and contraction of the absorber material during vaporization and absorption without generating voids which would interfere with heat transfer.

Chemical heat pump

DOEpatents

Greiner, Leonard

1984-01-01

A chemical heat pump system is disclosed for use in heating and cooling structures such as residences or commercial buildings. The system is particularly adapted to utilizing solar energy, but also increases the efficiency of other forms of thermal energy when solar energy is not available. When solar energy is not available for relatively short periods of time, the heat storage capacity of the chemical heat pump is utilized to heat the structure, as during nighttime hours. The design also permits home heating from solar energy when the sun is shining. The entire system may be conveniently rooftop located. In order to faciliate installation on existing structures, the absorber and vaporizer portions of the system may each be designed as flat, thin wall, thin pan vessels which materially increase the surface area available for heat transfer. In addition, this thin, flat configuration of the absorber and its thin walled (and therefore relatively flexible) construction permits substantial expansion and contraction of the absorber material during vaporization and absorption without generating voids which would interfere with heat transfer.

Combined heat and mass transfer device for improving separation process

DOEpatents

Tran, Thanh Nhon

1999-01-01

A two-phase small channel heat exchange matrix simultaneously provides for heat transfer and mass transfer between the liquid and vapor phases of a multi-component mixture at a single, predetermined location within a separation column, significantly improving the thermodynamic efficiency of the separation process. The small channel heat exchange matrix is composed of a series of channels having a hydraulic diameter no greater than 5.0 millimeters for conducting a two-phase coolant. In operation, the matrix provides the liquid-vapor contacting surfaces within the separation column, such that heat and mass are transferred simultaneously between the liquid and vapor phases. The two-phase coolant allows for a uniform heat transfer coefficient to be maintained along the length of the channels and across the surface of the matrix. Preferably, a perforated, concave sheet connects each channel to an adjacent channel to facilitate the flow of the liquid and vapor phases within the column and to increase the liquid-vapor contacting surface area.

Combined heat and mass transfer device for improving separation process

DOEpatents

Tran, T.N.

1999-08-24

A two-phase small channel heat exchange matrix simultaneously provides for heat transfer and mass transfer between the liquid and vapor phases of a multi-component mixture at a single, predetermined location within a separation column, significantly improving the thermodynamic efficiency of the separation process. The small channel heat exchange matrix is composed of a series of channels having a hydraulic diameter no greater than 5.0 millimeters for conducting a two-phase coolant. In operation, the matrix provides the liquid-vapor contacting surfaces within the separation column, such that heat and mass are transferred simultaneously between the liquid and vapor phases. The two-phase coolant allows for a uniform heat transfer coefficient to be maintained along the length of the channels and across the surface of the matrix. Preferably, a perforated, concave sheet connects each channel to an adjacent channel to facilitate the flow of the liquid and vapor phases within the column and to increase the liquid-vapor contacting surface area. 12 figs.

Assessing Near-surface Heat, Water Vapor and Carbon Dioxide Exchange Over a Coastal Salt-marsh

NASA Astrophysics Data System (ADS)

Bogoev, I.; O'Halloran, T. L.; LeMoine, J.

2017-12-01

Coastal ecosystems play an important role in mitigating the effects of climate change by storing significant quantities of carbon. A growing number of studies suggest that vegetated estuarine habitats, specifically salt marshes, have high long-term rates of carbon sequestration, perhaps even higher than mature tropical and temperate forests. Large amounts of carbon, accumulated over thousands of years, are stored in the plant materials and sediment. Improved understanding of the factors that control energy and carbon exchange is needed to better guide restoration and conservation management practices. To that end, we recently established an observation system to study marsh-atmosphere interactions within the North Inlet-Winyah Bay National Estuarine Research Reserve. Near-surface fluxes of heat, water vapor (H2O) and carbon dioxide (CO2) were measured by an eddy-covariance system consisting of an aerodynamic open-path H2O / CO2 gas analyzer with a spatially integrated 3D sonic anemometer/thermometer (IRGASON). The IRGASON instrument provides co-located and highly synchronized, fast response H2O, CO2 and air- temperature measurements, which eliminates the need for spectral corrections associated with the separation between the sonic anemometer and the gas analyzer. This facilitates calculating the instantaneous CO2 molar mixing ratio relative to dry air. Fluxes computed from CO2 and H2O mixing ratios, which are conserved quantities, do not require post-processing corrections for air-density changes associated with temperature and water vapor fluctuations. These corrections are particularly important for CO2, because they could be even larger than the measured flux. Here we present the normalized frequency spectra of air temperature, water vapor and CO2, as well as their co-spectra with the co-located vertical wind. We also show mean daily cycles of sensible, latent and CO2 fluxes and analyze correlations with air/water temperature, wind speed and light availability.

Copper vapor laser precision processing

NASA Astrophysics Data System (ADS)

Nikonchuk, Michail O.

1991-05-01

Copper vapor laser (CVL) was designed on the basis master oscillator (MO) - spatial filter - amplifier (AMP) system which is placed in thermostable volume. Processing material is moved by means of CNC system GPM-AP-400 with +/- 5 micrometers accuracy. Several cutting parameters are considered which define the quality and productivity of vaporization cutting: efficiency, cutwidth, height of upper and lower burr, roughness, laser and heat affected zones. Estimates are made for some metals with thickness 0.02 - 0.3 mm and cutwidth 0.01 - 0.03 mm. The examples of workpieces produced by CVL are presented.

Senstitivity analysis of horizontal heat and vapor transfer coefficients for a cloud-topped marine boundary layer during cold-air outbreaks. M.S. Thesis

NASA Technical Reports Server (NTRS)

Chang, Y. V.

1986-01-01

The effects of external parameters on the surface heat and vapor fluxes into the marine atmospheric boundary layer (MABL) during cold-air outbreaks are investigated using the numerical model of Stage and Businger (1981a). These fluxes are nondimensionalized using the horizontal heat (g1) and vapor (g2) transfer coefficient method first suggested by Chou and Atlas (1982) and further formulated by Stage (1983a). In order to simplify the problem, the boundary layer is assumed to be well mixed and horizontally homogeneous, and to have linear shoreline soundings of equivalent potential temperature and mixing ratio. Modifications of initial surface flux estimates, time step limitation, and termination conditions are made to the MABL model to obtain accurate computations. The dependence of g1 and g2 in the cloud topped boundary layer on the external parameters (wind speed, divergence, sea surface temperature, radiative sky temperature, cloud top radiation cooling, and initial shoreline soundings of temperature, and mixing ratio) is studied by a sensitivity analysis, which shows that the uncertainties of horizontal transfer coefficients caused by changes in the parameters are reasonably small.

Laser vaporization of trace explosives for enhanced non-contact detection

NASA Astrophysics Data System (ADS)

Furstenberg, Robert; Papantonakis, Michael; Kendziora, Christopher A.; Bubb, Daniel M.; Corgan, Jeffrey; McGill, R. Andrew

2010-04-01

Trace explosives contamination is found primarily in the form of solid particulates on surfaces, due to the low vapor pressure of most explosives materials. Today, the standard sampling procedure involves physical removal of particulate matter from surfaces of interest. A variety of collection methods have been used including air-jetting or swabbing surfaces of interest. The sampled particles are typically heated to generate vapor for analysis in hand held, bench top, or portal detection systems. These sampling methods are time-consuming (and hence costly), require a skilled technician for optimal performance, and are inherently non-selective, allowing non-explosives particles to be co-sampled and analyzed. This can adversely affect the sensitivity and selectivity of detectors, especially those with a limited dynamic range. We present a new approach to sampling solid particles on a solid surface that is targeted, non-contact, and which selectively enhances trace explosive signatures thus improving the selectivity and sensitivity of existing detectors. Our method involves the illumination of a surface of interest with infrared laser light with a wavelength that matches a distinctive vibrational mode of an explosive. The resonant coupling of laser energy results in rapid heating of explosive particles and rapid release of a vapor plume. Neighboring particles unrelated to explosives are generally not directly heated as their vibrational modes are not resonant with the laser. As a result, the generated vapor plume includes a higher concentration of explosives than if the particles were heated with a non-selective light source (e.g. heat lamp). We present results with both benchtop infrared lasers as well as miniature quantum cascade lasers.

Heat pipe dynamic behavior

NASA Technical Reports Server (NTRS)

Issacci, F.; Roche, G. L.; Klein, D. B.; Catton, I.

1988-01-01

The vapor flow in a heat pipe was mathematically modeled and the equations governing the transient behavior of the core were solved numerically. The modeled vapor flow is transient, axisymmetric (or two-dimensional) compressible viscous flow in a closed chamber. The two methods of solution are described. The more promising method failed (a mixed Galerkin finite difference method) whereas a more common finite difference method was successful. Preliminary results are presented showing that multi-dimensional flows need to be treated. A model of the liquid phase of a high temperature heat pipe was developed. The model is intended to be coupled to a vapor phase model for the complete solution of the heat pipe problem. The mathematical equations are formulated consistent with physical processes while allowing a computationally efficient solution. The model simulates time dependent characteristics of concern to the liquid phase including input phase change, output heat fluxes, liquid temperatures, container temperatures, liquid velocities, and liquid pressure. Preliminary results were obtained for two heat pipe startup cases. The heat pipe studied used lithium as the working fluid and an annular wick configuration. Recommendations for implementation based on the results obtained are presented. Experimental studies were initiated using a rectangular heat pipe. Both twin beam laser holography and laser Doppler anemometry were investigated. Preliminary experiments were completed and results are reported.

Measuring the Heats of Water.

ERIC Educational Resources Information Center

Hunt, James L.; Tegart, Tracy L.

1994-01-01

Uses common equipment (tea kettle and vacuum bottles) to precisely measure the specific heat, latent heat of fusion, and latent heat of vaporization of water. Provides descriptions for all three experiments. (MVL)

Filter vapor trap

DOEpatents

Guon, Jerold

1976-04-13

A sintered filter trap is adapted for insertion in a gas stream of sodium vapor to condense and deposit sodium thereon. The filter is heated and operated above the melting temperature of sodium, resulting in a more efficient means to remove sodium particulates from the effluent inert gas emanating from the surface of a liquid sodium pool. Preferably the filter leaves are precoated with a natrophobic coating such as tetracosane.

Condensation of acetol and acetic acid vapor with sprayed liquid

USDA-ARS?s Scientific Manuscript database

A cellulose-derived fraction of biomass pyrolysis vapor was simulated by evaporating acetol and acetic acid (AA) from flasks on a hot plate. The liquid in the flasks was infused with heated nitrogen. The vapor/nitrogen stream was superheated in a tube oven and condensed by contact with a cloud of ...

Large-scale fabrication of linear low density polyethylene/layered double hydroxides composite films with enhanced heat retention, thermal, mechanical, optical and water vapor barrier properties

DOE Office of Scientific and Technical Information (OSTI.GOV)

Xie, Jiazhuo; Zhang, Kun; Zhao, Qinghua

Novel LDH intercalated with organic aliphatic long-chain anion was large-scale synthesized innovatively by high-energy ball milling in one pot. The linear low density polyethylene (LLDPE)/layered double hydroxides (LDH) composite films with enhanced heat retention, thermal, mechanical, optical and water vapor barrier properties were fabricated by melt blending and blowing process. FT IR, XRD, SEM results show that LDH particles were dispersed uniformly in the LLDPE composite films. Particularly, LLDPE composite film with 1% LDH exhibited the optimal performance among all the composite films with a 60.36% enhancement in the water vapor barrier property and a 45.73 °C increase in themore » temperature of maximum mass loss rate compared with pure LLDPE film. Furthermore, the improved infrared absorbance (1180–914 cm{sup −1}) of LLDPE/LDH films revealed the significant enhancement of heat retention. Therefore, this study prompts the application of LLDPE/LDH films as agricultural films with superior heat retention. - Graphical abstract: The fabrication process of LLDPE/LDH composite films. - Highlights: • LDH with basal spacing of 4.07 nm was synthesized by high-energy ball milling. • LLDPE composite films with homogeneous LDH dispersion were fabricated. • The properties of LLDPE/LDH composite films were improved. • LLDPE/LDH composite films show superior heat retention property.« less

Numerical simulation of water injection into vapor-dominated reservoirs

DOE Office of Scientific and Technical Information (OSTI.GOV)

Pruess, K.

1995-01-01

Water injection into vapor-dominated reservoirs is a means of condensate disposal, as well as a reservoir management tool for enhancing energy recovery and reservoir life. We review different approaches to modeling the complex fluid and heat flow processes during injection into vapor-dominated systems. Vapor pressure lowering, grid orientation effects, and physical dispersion of injection plumes from reservoir heterogeneity are important considerations for a realistic modeling of injection effects. An example of detailed three-dimensional modeling of injection experiments at The Geysers is given.

Chemical vapor deposition reactor. [providing uniform film thickness

NASA Technical Reports Server (NTRS)

Chern, S. S.; Maserjian, J. (Inventor)

1977-01-01

An improved chemical vapor deposition reactor is characterized by a vapor deposition chamber configured to substantially eliminate non-uniformities in films deposited on substrates by control of gas flow and removing gas phase reaction materials from the chamber. Uniformity in the thickness of films is produced by having reactive gases injected through multiple jets which are placed at uniformally distributed locations. Gas phase reaction materials are removed through an exhaust chimney which is positioned above the centrally located, heated pad or platform on which substrates are placed. A baffle is situated above the heated platform below the mouth of the chimney to prevent downdraft dispersion and scattering of gas phase reactant materials.

Vapor Grown Carbon Fiber/Phenolic Matrix Composites for Rocket Nozzles and Heat Shields

NASA Technical Reports Server (NTRS)

Patton, R. D.; Pittman, C. U., Jr.; Wang, L.; Day, A.; Hill, J. R.

2001-01-01

The ablation and mechanical and thermal properties of vapor grown carbon fiber (VGCF)/phenolic resin composites were evaluated to determine the potential of using this material in solid rocket motor nozzles. Composite specimens with varying VGCF loading (30%-50% wt) including one sample with ex-rayon carbon fiber plies were prepared and exposed to a plasma torch for 20 s with a heat flux of 16.5 MW/sq m at approximately 1650 C. Low erosion rates and little char formation were observed, confirming that these materials were promising for rocket motor nozzle materials. When fiber loadings increased, mechanical properties and ablative properties improved. The VGCF composites had low thermal conductivities (approximately 0.56 W/m-C) indicating they were good insulating materials. If a 65% fiber loading in VGCF composite can be achieved, then ablative properties are projected to be comparable to or better than the composite material currently used on the Space Shuttle Reusable Solid Rocket Motor (RSRM).

Towards a Lithium Radiative / Vapor-Box Divertor

NASA Astrophysics Data System (ADS)

Goldston, Robert; Constantin, Marius; Jaworski, Michael; Myers, Rachel; Ono, Masayuki; Schwartz, Jacob; Scotti, Filippo; Qu, Zhaonan

2014-10-01

Recent research has indicated that the peak perpendicular heat flux on reactor divertor targets will be hundreds of MW/m2 in the absence of dissipation and/or spatial spreading. Thus we are attracted to both enhanced radiative cooling and continuous vapor shielding. Lithium particle lifetimes <=100 micro-sec enhance radiation efficiency at T < 10 eV, while lithium charge-exchange with neutral hydrogen may enhance radiative efficiency for T > 10 eV and n0/ni > 0.1. We are examining if the latter mechanism plays a role in the narrowing of the heat-flux footprint in lithiated NSTX discharges. In parallel we are investigating the possibility of immersing a reactor divertor leg in a channel of lithium vapor. If we approximate the vapor channel as in local equilibrium with lithium-wetted walls ranging from 300 oC at the entrance point to 950 oC 10m downstream in the parallel direction, we find that the vapor can both balance reactor levels of upstream plasma pressure and stop energetic ions and electrons with energies up to at least 25 keV, as might be produced in ELMs. Each 10 l/sec of lithium evaporated deep in the channel and recondensed in cooler regions spreads 100 MW over a much wider area than the original strike point. This work supported by US DOE Contract DE-AC02-09CH11466.

Nanoscale heat transfer and phase transformation surrounding intensely heated nanoparticles

NASA Astrophysics Data System (ADS)

Sasikumar, Kiran

Over the last decade there has been significant ongoing research to use nanoparticles for hyperthermia-based destruction of cancer cells. In this regard, the investigation of highly non-equilibrium thermal systems created by ultrafast laser excitation is a particularly challenging and important aspect of nanoscale heat transfer. It has been observed experimentally that noble metal nanoparticles, illuminated by radiation at the plasmon resonance wavelength, can act as localized heat sources at nanometer-length scales. Achieving biological response by delivering heat via nanoscale heat sources has also been demonstrated. However, an understanding of the thermal transport at these scales and associated phase transformations is lacking. A striking observation made in several laser-heating experiments is that embedded metal nanoparticles heated to extreme temperatures may even melt without an associated boiling of the surrounding fluid. This unusual phase stability is not well understood and designing experiments to understand the physics of this phenomenon is a challenging task. In this thesis, we will resort to molecular dynamics (MD) simulations, which offer a powerful tool to investigate this phenomenon, without assumptions underlying continuum-level model formulations. We present the results from a series of steady state and transient non-equilibrium MD simulations performed on an intensely heated nanoparticle immersed in a model liquid. For small nanoparticles (1-10 nm in diameter) we observe a stable liquid phase near the nanoparticle surface, which can be at a temperature well above the boiling point. Furthermore, we report the existence of a critical nanoparticle size (4 nm in diameter) below which we do not observe formation of vapor even when local fluid temperatures exceed the critical temperature. Instead, we report the existence of a stable fluid region with a density much larger than that of the vapor phase. We explain this stability in terms of the

[Clothing and heat disorder].

PubMed

Satsumoto, Yayoi

2012-06-01

The influence of the clothing material properties(like water absorbency and rapid dryness, water vapor absorption, water vapor permeability and air permeability) and the design factor of the clothing(like opening condition and fitting of clothing), which contributed to prevent heat disorder, was outlined. WBGT(wet-bulb globe temperature) is used to show a guideline for environmental limitation of activities to prevent heat disorder. As the safety function is more important than thermal comfort for some sportswear and protective clothing with high cover area, clothing itself increases the risk of heat disorder. WBGT is corrected by CAF (clothing adjustment factor) in wearing such kind of protective clothing.

Studies of oscillatory combustion and fuel vaporization

NASA Technical Reports Server (NTRS)

Borman, G. L.; Myers, P. S.; Uyehara, O. A.

1972-01-01

Research projects involving oscillatory combustion and fuel vaporization are reported. Comparisons of experimental and theoretical droplet vaporization histories under ambient conditions such that the droplet may approach its thermodynamic critical point are presented. Experimental data on instantaneous heat transfer from a gas to a solid surface under conditions of oscillatory pressure with comparisons to an unsteady one-dimensional model are analyzed. Droplet size and velocity distribution in a spray as obtained by use of a double flash fluorescent method were investigated.

Staged regenerative sorption heat pump

NASA Technical Reports Server (NTRS)

Jones, Jack A. (Inventor)

1995-01-01

A regenerative adsorbent heat pump process and system for cooling and heating a space. A sorbent is confined in a plurality of compressors of which at least four are first stage and at least four are second stage. The first stage operates over a first pressure region and the second stage over a second pressure region which is higher than the first. Sorbate from the first stage enters the second stage. The sorbate loop includes a condenser, expansion valve, evaporator and the compressors. A single sorbate loop can be employed for single-temperature-control such as air conditioning and heating. Two sorbate loops can be used for two-temperature-control as in a refrigerator and freezer. The evaporator temperatures control the freezer and refrigerator temperatures. Alternatively the refrigerator temperature can be cooled by the freezer with one sorbate loop. A heat transfer fluid is circulated in a closed loop which includes a radiator and the compressors. Low temperature heat is exhausted by the radiator. High temperature heat is added to the heat transfer fluid entering the compressors which are desorbing vapor. Heat is transferred from compressors which are sorbing vapor to the heat transfer fluid, and from the heat transfer fluid to the compressors which are desorbing vapor. Each compressor is subjected to the following phases, heating to its highest temperature, cooling down from its highest temperature, cooling to its lowest temperature, and warming up from its lowest temperature. The phases are repeated to complete a cycle and regenerate heat.

Steady boiling of vapor bubbles in rectangular channels

NASA Astrophysics Data System (ADS)

Ajaev, Vladimir S.; Homsy, George M.

2000-11-01

We consider vapor bubbles in microchannels in which the vapor is produced by a heater element and condenses in cooler parts of the interface. The free boundary problem is formulated for a long steady-state bubble in a rectangular channel with a heated bottom. The shape of the liquid-vapor interface is described using lubrication-type equations in the regime in which the vapor phase fills most of the cross-section. Contact lines may be present, marking the transitions between molecularly thin films and macroscopic ones. The main parameters are the differences between heater, saturation, and top wall temperatures. The equations are solved numerically over a range of parameter values with an integral condition requiring the evaporation near the heater to balance condensation in colder areas of the interface. Depending on the temperature, the side walls can be either dry or covered with a liquid film; we identify criteria for these two different regimes. The asymptotic method breaks down in the limit when capillary condensation becomes important near the bubble top and a different approach is used to determine the shape of the bubble in this limit. Solutions here involve localized regions of large mass fluxes, which are asymptotically matched to capillary-statics regions where the heat transfer is negligible.

The impact of vaporized nanoemulsions on ultrasound-mediated ablation

PubMed Central

2013-01-01

Background The clinical feasibility of using high-intensity focused ultrasound (HIFU) for ablation of solid tumors is limited by the high acoustic pressures and long treatment times required. The presence of microbubbles during sonication can increase the absorption of acoustic energy and accelerate heating. However, formation of microbubbles within the tumor tissue remains a challenge. Phase-shift nanoemulsions (PSNE) have been developed as a means for producing microbubbles within tumors. PSNE are emulsions of submicron-sized, lipid-coated, and liquid perfluorocarbon droplets that can be vaporized into microbubbles using short (<1 ms), high-amplitude (>5 MPa) acoustic pulses. In this study, the impact of vaporized phase-shift nanoemulsions on the time and acoustic power required for HIFU-mediated thermal lesion formation was investigated in vitro. Methods PSNE containing dodecafluoropentane were produced with narrow size distributions and mean diameters below 200 nm using a combination of sonication and extrusion. PSNE was dispersed in albumin-containing polyacrylamide gel phantoms for experimental tests. Albumin denatures and becomes opaque at temperatures above 58°C, enabling visual detection of lesions formed from denatured albumin. PSNE were vaporized using a 30-cycle, 3.2-MHz, at an acoustic power of 6.4 W (free-field intensity of 4,586 W/cm2) pulse from a single-element, focused high-power transducer. The vaporization pulse was immediately followed by a 15-s continuous wave, 3.2-MHz signal to induce ultrasound-mediated heating. Control experiments were conducted using an identical procedure without the vaporization pulse. Lesion formation was detected by acquiring video frames during sonication and post-processing the images for analysis. Broadband emissions from inertial cavitation (IC) were passively detected with a focused, 2-MHz transducer. Temperature measurements were acquired using a needle thermocouple. Results Bubbles formed at the HIFU focus via

Carbothermic Reduction Kinetics of Phosphorous Vaporization from Tri-calcium Phosphate (TCP) Under Microwave Rapid Heating With/Without the Presence of Fe3O4

NASA Astrophysics Data System (ADS)

Yoshikawa, Noboru; Sunako, Manami; Kawahira, Keita; Suzuki, Koki; Miyamoto, Kazunori; Taniguchi, Shoji

2018-06-01

The kinetics of vapor phase dephosphorization from tri-calcium phosphate (TCP) by carbothermic reduction was studied with and without the presence of Fe3O4. Microwave heating was utilized to obtain large variations in the heating rate (HR). In the reduction of TCP alone, the phosphorous removal fraction (RF; equal to ΔP2O5/P2O 5 0 , where ΔP2O5 is the weight change and P2O 5 0 is the P2O5 weight before heating) decreased as the HR increased. In other words, a shorter residence time at a high temperature resulted in a smaller reduction fraction of TCP. An apparently third-order reaction was postulated to account for the kinetics using a fitting simulation based on the additive law of the reaction progress. On the other hand, the phosphorous removal (dephosphorization) rate (RR; equal to ΔP2O3/ t MW, where tMW is the microwave heating time period) increased as the HR increased above 1200 °C. The reduction ratio of Fe3O4 above 1100 °C is higher than 97 pct regardless of the heating rate. The reduction of TCP in the presence of Fe3O4 showed that RF increased slightly with increasing HR despite a shorter residence time at a high temperature. The RR also increased with the HR even though RF decreased to half of the values observed in the cases without Fe3O4 for temperatures above 1200 °C. The practicality and optimal operation conditions of phosphorus vapor removal were discussed.

IITRI RADIO FREQUENCY HEATING TECHNOLOGY - INNOVATIVE TECHNOLOGY EVALUATION REPORT

EPA Science Inventory

IITRI's patented in situ RFH technology enhances the removal of volatile and semi-volatile organics by soil vapor extraction (SVE). Electromagnetic energy heats the soil resulting in increased contaminant vapor pressures and potentially higher soil permeability. RFH heats soil us...

The Observed Properties of Liquid Helium at the Saturated Vapor Pressure

NASA Astrophysics Data System (ADS)

Donnelly, Russell J.; Barenghi, Carlo F.

1998-11-01

The equilibrium and transport properties of liquid 4He are deduced from experimental observations at the saturated vapor pressure. In each case, the bibliography lists all known measurements. Quantities reported here include density, thermal expansion coefficient, dielectric constant, superfluid and normal fluid densities, first, second, third, and fourth sound velocities, specific heat, enthalpy, entropy, surface tension, ion mobilities, mutual friction, viscosity and kinematic viscosity, dispersion curve, structure factor, thermal conductivity, latent heat, saturated vapor pressure, thermal diffusivity and Prandtl number of helium I, and displacement length and vortex core parameter in helium II.

Physics of heat pipe rewetting

NASA Technical Reports Server (NTRS)

Chan, S. H.

1994-01-01

This is the final report which summarizes the research accomplishments under the project entitled 'Physics of Heat Pipe Rewetting' under NASA Grant No. NAG 9-525, Basic, during the period of April 1, 1991 to January 31, 1994. The objective of the research project was to investigate both analytically and experimentally the rewetting characteristics of the heated, grooved plate. The grooved plate is to simulate the inner surface of the vapor channel in monogroove heat pipes for space station design. In such designs, the inner surface of the vapor channel is threaded with monogrooves. When the heat pipe is thermally overloaded, dryout of the monogroove surface occurs. Such a dryout surface should be promptly rewetted to prevent the failure of the heat pipe operation in the thermal radiator of the space station.

Suppression of ENSO in a coupled model without water vapor feedback

NASA Astrophysics Data System (ADS)

Hall, A.; Manabe, S.

We examine 800-year time series of internally generated variability in both a coupled ocean-atmosphere model where water vapor anomalies are not allowed to interact with longwave radiation and one where they are. The ENSO-like phenomenon in the experiment without water vapor feedback is drastically suppressed both in amplitude and geographic extent relative to the experiment with water vapor feedback. Surprisingly, the reduced amplitude of ENSO-related sea surface temperature anomalies in the model without water vapor feedback cannot be attributed to greater longwave damping of sea surface temperature. (Differences between the two experiments in radiative feedback due to clouds counterbalance almost perfectly the differences in radiative feedback due to water vapor.) Rather, the interaction between water vapor anomalies and longwave radiation affects the ENSO-like phenomenon through its influence on the vertical structure of radiative heating: Because of the changes in water vapor associated with it, a given warm equatorial Pacific sea surface temperature anomaly is associated with a radiative heating profile that is much more gravitationally unstable when water vapor feedback is present. The warm sea surface temperature anomaly therefore results in more convection in the experiment with water vapor feedback. The increased convection, in turn, is related to a larger westerly wind-stress anomaly, which creates a larger decrease in upwelling of cold water, thereby enhancing the magnitude of the original warm sea surface temperature anomaly. In this manner, the interaction between water vapor anomalies and longwave radiation magnifies the air-sea interactions at the heart of the ENSO phenomenon; without this interaction, the coupling between sea surface temperature and wind stress is effectively reduced, resulting in smaller amplitude ENSO episodes with a more limited geographical extent.

Water vapor diffusion membrane development

NASA Technical Reports Server (NTRS)

Tan, M. K.

1977-01-01

An application of the water vapor diffusion technique is examined whereby the permeated water vapor is vented to space vacuum to alleviate on-board waste storage and provide supplemental cooling. The work reported herein deals primarily with the vapor diffusion-heat rejection (VD-HR) as it applies to the Space Shuttle. A stack configuration was selected, designed and fabricated. An asymmetric cellulose acetate membrane, used in reverse osmosis application was selected and a special spacer was designed to enhance mixing and promote mass transfer. A skid-mount unit was assembled from components used in the bench unit although no attempt was made to render it flight-suitable. The operating conditions of the VD-HR were examined and defined and a 60-day continuous test was carried out. The membranes performed very well throughout the test; no membrane rupture and no unusual flux decay was observed. In addition, a tentative design for a flight-suitable VD-HR unit was made.

Small-scale experimental study of vaporization flux of liquid nitrogen released on water.

PubMed

Gopalaswami, Nirupama; Olewski, Tomasz; Véchot, Luc N; Mannan, M Sam

2015-10-30

A small-scale experimental study was conducted using liquid nitrogen to investigate the convective heat transfer behavior of cryogenic liquids released on water. The experiment was performed by spilling five different amounts of liquid nitrogen at different release rates and initial water temperatures. The vaporization mass fluxes of liquid nitrogen were determined directly from the mass loss measured during the experiment. A variation of initial vaporization fluxes and a subsequent shift in heat transfer mechanism were observed with changes in initial water temperature. The initial vaporization fluxes were directly dependent on the liquid nitrogen spill rate. The heat flux from water to liquid nitrogen determined from experimental data was validated with two theoretical correlations for convective boiling. It was also observed from validation with correlations that liquid nitrogen was found to be predominantly in the film boiling regime. The substantial results provide a suitable procedure for predicting the heat flux from water to cryogenic liquids that is required for source term modeling. Copyright © 2015 Elsevier B.V. All rights reserved.

Binary vapor cycle method of electrical power generation

DOE Office of Scientific and Technical Information (OSTI.GOV)

Humiston, G.F.

1982-04-13

A binary vapor cycle method of electrical power generation is disclosed wherein two refrigerant fluids can be used to operate an apparatus for the generation of mechanical power as well as electrical power generation. This method, which is essentially a dual heat pump system, offers an approach to utilizing the advantages of two different refrigerants within a single apparatus. This advantage is particularly advantageous in the ulitization of low specific energy sources, such as two water sources which exist in close proximity to each other, but at different temperatures. Thus, water, which itself is a heat pump fluid, can bemore » used as a means of transmitting heat energy to a second heat pump fluid, or refrigerant, without incurring the disadvantages of water, or water vapors, as a means to produce power, because of its high specific volume and low saturation pressures at low temperatures. Additionally, since the warm water source of energy most commonly available is in the form of reservoirs, such as the ocean waters, and the utilization of barometric legs to bring the warm water into contact with the process, eliminates the use of expensive heat exchangers, which is the case of ocean water, are subject to fouling and loss of efficiency due to clinging microorganisms.« less

Acoustic Behavior of Vapor Bubbles

NASA Technical Reports Server (NTRS)

Prosperetti, Andrea; Oguz, Hasan N.

1996-01-01

In a microgravity environment vapor bubbles generated at a boiling surface tend to remain near it for a long time. This affects the boiling heat transfer and in particular promotes an early transition to the highly inefficient film boiling regime. This paper describes the physical basis underlying attempts to remove the bubbles by means of pressure radiation forces.

Vapor Transport Through Fractures and Other High-Permeability Paths: Its Role in the Drift Scale Test at Yucca Mountain, Nevada

NASA Astrophysics Data System (ADS)

Mukhopadhyay, S.; Tsang, Y. W.

2001-12-01

Heating unsaturated fractured tuff sets off a series of complicated thermal-hydrological (TH) processes, which result in large-scale redistribution of moisture in the host rock. Moisture redistribution arises from boiling of water near heat sources, transport of vapor away from those heat sources, condensation of that vapor in cooler rock, and subsequent gravity drainage of condensate through fractures. Vapor transport through high-permeability paths, which include both the fractures in the rock and other conduits, contributes to the evolution of these TH processes in two ways. First, the highly permeable natural fractures provide easy passage for vapor away from the heat sources. Second, these fractures and other highly permeable conduits allow vapor (and the associated energy) to escape the rock through open boundaries of the test domain. The overall impact of vapor transport on the evolution of the TH processes can be more easily understood in the context of the Drift Scale Test (DST), the largest ever in situ heater test in unsaturated fractured tuff. The DST, in which a large volume of rock has been heated for four years now, is located in the middle nonlithophysal (Tptpmn) stratigraphic unit of Yucca Mountain, Nevada. The fractured tuff in Tptpmn contains many well-connected fractures. In the DST, heating is provided by nine cannister heaters placed in a five-meter-diameter Heated Drift (HD) and fifty wing heaters installed orthogonal to the axis of the HD. The test has many instrumentation boreholes, some of which are not sealed by packers or grout and may provide passage for vapor and energy. Of these conduits, the boreholes housing the wing heaters are most important for vapor transport because of their proximity to heat sources. While part of the vapor generated by heating moves away from the heat sources through the fractures and condenses elsewhere in the rock, the rest of the vapor, under gas-pressure difference, enters the HD by way of the high

Controlled boiling on Enceladus. 1. Model of the vapor-driven jets

NASA Astrophysics Data System (ADS)

Nakajima, Miki; Ingersoll, Andrew P.

2016-07-01

Plumes of water vapor and ice particles have been observed from the so-called tiger stripes at the south polar terrain (SPT) of Saturn's satellite, Enceladus. The observed high salinity (∼0.5-2%) of the ice particles in the plumes may indicate that the plumes originate from a subsurface liquid ocean. Additionally, the SPT is the source of strong infrared radiation (∼4.2 GW), which is especially intense near (within tens of meters) the tiger stripes. This could indicate that the radiation is associated with plume activity, but the connection remains unclear. Here we investigate the constraints that plume observations place on the widths of the cracks, the depth to the liquid-vapor interface, and the mechanisms controlling plume variability. We solve the fluid dynamics of the flow in the crack and the interaction between the flow and ice walls assuming that the flows of water vapor and ice particles originate from a few kilometers deep liquid ocean. For a crack with a uniform width, we find that our model could explain the observed vapor mass flow rate of the plumes when the crack width is 0.05-0.075 m. A wider crack is not favorable because it would produce a higher vapor mass flow rate than the observed value, but it may be allowed if there are some flows that do not reach the surface of Enceladus either due to condensation on the icy walls or the tortuosity of the crack. The observed heat flow can be explained if the total crack length is approximately 1.7 × 500 km. A tapering crack (a crack which is ∼1 m wide at the bottom of the flow and sharply becomes 0.05-0.075 m at shallower depths) can also explain the observed vapor mass flow rate and heat flow. Widths of 1 m or more are necessary to avoid freezing at the liquid-vapor interface, as shown in our paired paper (Ingersoll and Nakajima [2016] Icarus). The observed intense heat flow along the tiger stripes can be explained by the latent heat release due to vapor condensation onto the ice walls near the

A numerical analysis of high-temperature heat pipe startup from the frozen state

NASA Technical Reports Server (NTRS)

Cao, Y.; Faghri, A.

1993-01-01

Continuum and rarefied vapor flows co-exist along the heat pipe length for most of the startup period. A two-region model is proposed in which the vapor flow in the continuum region is modeled by the compressible Navier-Stokes equations, and the vapor flow in the rarefied region is simulated by a self-diffusion model. The two vapor regions are linked with appropriate boundary conditions, and heat pipe wail, wick, and vapor flow are solved as a conjugate problem. The numerical solutions for the entire heat pipe startup process from the frozen state are compared with the corresponding experimental data with good agreement.

A Numerical Study of Heat and Water Vapor Transfer in MDCT-Based Human Airway Models

PubMed Central

Wu, Dan; Tawhai, Merryn H.; Hoffman, Eric A.; Lin, Ching-Long

2014-01-01

A three-dimensional (3D) thermo-fluid model is developed to study regional distributions of temperature and water vapor in three multi-detector row computed-tomography (MDCT)-basedhuman airwayswith minute ventilations of 6, 15 and 30 L/min. A one-dimensional (1D) model is also solved to provide necessary initial and boundary conditionsforthe 3D model. Both 3D and 1D predicted temperature distributions agree well with available in vivo measurement data. On inspiration, the 3D cold high-speed air stream is split at the bifurcation to form secondary flows, with its cold regions biased toward the inner wall. The cold air flowing along the wall is warmed up more rapidly than the air in the lumen center. The repeated splitting pattern of air streams caused by bifurcations acts as an effective mechanism for rapid heat and mass transfer in 3D. This provides a key difference from the 1D model, where heating relies largely on diffusion in the radial direction, thus significantly affecting gradient-dependent variables, such as energy flux and water loss rate. We then propose the correlations for respective heat and mass transfer in the airways of up to 6 generations: Nu=3.504(ReDaDt)0.277, R = 0.841 and Sh=3.652(ReDaDt)0.268, R = 0.825, where Nu is the Nusselt number, Sh is the Sherwood number, Re is the branch Reynolds number, Da is the airway equivalent diameter, and Dt is the tracheal equivalentdiameter. PMID:25081386

Preliminary characterization of a water vaporizer for resistojet applications

NASA Technical Reports Server (NTRS)

Morren, W. Earl

1992-01-01

A series of tests was conducted to explore the characteristics of a water vaporizer intended for application to resistojet propulsion systems. The objectives of these tests were to (1) observe the effect of orientation with respect to gravity on vaporizer stability, (2) characterize vaporizer efficiency and outlet conditions over a range of flow rates, and (3) measure the thrust performance of a vaporizer/resistojet thruster assembly. A laboratory model of a forced-flow, once-through water vaporizer employing a porous heat exchange medium was built and characterized over a range of flow rates and power levels of interest for application to water resistojets. In a test during which the vaporizer was rotated about a horizontal axis normal to its own axis, the outlet temperature and mass flow rate through the vaporizer remained steady. Throttlability to 30 percent of the maximum flow rate tested was demonstrated. The measured thermal efficiency of the vaporizer was near 0.9 for all tests. The water vaporizer was integrated with an engineering model multipropellant resistojet. Performance of the vaporizer/thruster assembly was measured over a narrow range of operating conditions. The maximum specific impulse measured was 234 s at a mass flow rate and specific power level (vaporizer and thruster combined) of 154 x 10(exp-6)kg/s and 6.8 MJ/kg, respectively.

Vapor shielding models and the energy absorbed by divertor targets during transient events

DOE Office of Scientific and Technical Information (OSTI.GOV)

Skovorodin, D. I., E-mail: dskovorodin@gmail.com; Arakcheev, A. S.; Pshenov, A. A.

2016-02-15

The erosion of divertor targets caused by high heat fluxes during transients is a serious threat to ITER operation, as it is going to be the main factor determining the divertor lifetime. Under the influence of extreme heat fluxes, the surface temperature of plasma facing components can reach some certain threshold, leading to an onset of intense material evaporation. The latter results in formation of cold dense vapor and secondary plasma cloud. This layer effectively absorbs the energy of the incident plasma flow, turning it into its own kinetic and internal energy and radiating it. This so called vapor shieldingmore » is a phenomenon that may help mitigating the erosion during transient events. In particular, the vapor shielding results in saturation of energy (per unit surface area) accumulated by the target during single pulse of heat load at some level E{sub max}. Matching this value is one of the possible tests to verify complicated numerical codes, developed to calculate the erosion rate during abnormal events in tokamaks. The paper presents three very different models of vapor shielding, demonstrating that E{sub max} depends strongly on the heat pulse duration, thermodynamic properties, and evaporation energy of the irradiated target material. While its dependence on the other shielding details such as radiation capabilities of material and dynamics of the vapor cloud is logarithmically weak. The reason for this is a strong (exponential) dependence of the target material evaporation rate, and therefore the “strength” of vapor shield on the target surface temperature. As a result, the influence of the vapor shielding phenomena details, such as radiation transport in the vapor cloud and evaporated material dynamics, on the E{sub max} is virtually completely masked by the strong dependence of the evaporation rate on the target surface temperature. However, the very same details define the amount of evaporated particles, needed to provide an effective

Heat driven pulse pump

NASA Technical Reports Server (NTRS)

Benner, Steve M (Inventor); Martins, Mario S. (Inventor)

2000-01-01

A heat driven pulse pump includes a chamber having an inlet port, an outlet port, two check valves, a wick, and a heater. The chamber may include a plurality of grooves inside wall of the chamber. When heated within the chamber, a liquid to be pumped vaporizes and creates pressure head that expels the liquid through the outlet port. As liquid separating means, the wick, disposed within the chamber, is to allow, when saturated with the liquid, the passage of only liquid being forced by the pressure head in the chamber, preventing the vapor from exiting from the chamber through the outlet port. A plurality of grooves along the inside surface wall of the chamber can sustain the liquid, which is amount enough to produce vapor for the pressure head in the chamber. With only two simple moving parts, two check valves, the heat driven pulse pump can effectively function over the long lifetimes without maintenance or replacement. For continuous flow of the liquid to be pumped a plurality of pumps may be connected in parallel.

Method and apparatus for producing thermal vapor stream

DOEpatents

Cradeur, Robert R.; Sperry, John S.; Krajicek, Richard W.

1979-01-01

Method and apparatus for producing a thermal vapor stream for injecting into a subterranean formation for the recovery of liquefiable minerals therefrom, including a pressure vessel containing a high pressure combustion chamber for producing a heating gas for introduction into a heating gas injector. The heating gas injector is partly immersed in a steam generating section of the pressure vessel such that the heating gas is passed through the steam generating section to produce steam and combustion products which are directed between the pressure vessel and the combustion chamber for simultaneously cooling of the combustion chamber by further heating of the steam and combustion gases.

Fuel cell system with combustor-heated reformer

DOEpatents

Pettit, William Henry

2000-01-01

A fuel cell system including a fuel reformer heated by a catalytic combustor fired by anode effluent and/or fuel from a liquid fuel supply providing fuel for the fuel cell. The combustor includes a vaporizer section heated by the combustor exhaust gases for vaporizing the fuel before feeding it into the combustor. Cathode effluent is used as the principle oxidant for the combustor.

Vapor phase elemental sulfur amendment for sequestering mercury in contaminated soil

DOEpatents

Looney, Brian B.; Denham, Miles E.; Jackson, Dennis G.

2014-07-08

The process of treating elemental mercury within the soil is provided by introducing into the soil a heated vapor phase of elemental sulfur. As the vapor phase of elemental sulfur cools, sulfur is precipitated within the soil and then reacts with any elemental mercury thereby producing a reaction product that is less hazardous than elemental mercury.

Analysis of a membrane-based condesate recovery heat exchanger (CRX)

NASA Technical Reports Server (NTRS)

Newbold, D.D.

1993-01-01

The development of a temperature and humidity control system that can remove heat and recover water vapor is key to the development of an Environmental Control and Life Support System (ECLSS). Large quantities of water vapor must be removed from air, and this operation has proven difficult in the absense of gravity. This paper presents the modeling results from a program to develop a novel membrane-based heat exchanger known as the condensate recovery heat exchanger (CRX). This device cools and dehumidifies humid air and simultaneously recovers water-vapor condensate. In this paper, the CRX is described and the results of an analysis of the heat- and mass-transfer characteristics of the device are given.

Cappuccino and Specific Heat versus Heat of Vaporization

ERIC Educational Resources Information Center

Hidden, Frits; Boomsma, Jorn; Schins, Anton; van den Berg, Ed

2012-01-01

A cappuccino is prepared by adding about 50 mL frothing, foaming milk to a cup of espresso. Whole milk is best for foaming and the ideal milk temperature when adding it to the espresso is 65 [degrees]C. The espresso itself may be warmer than that. During the heating the milk should not burn, as that would spoil the taste. The best way is to heat…

Pressurization of a Flightweight, Liquid Hydrogen Tank: Evaporation & Condensation at a Liquid/Vapor Interface

NASA Technical Reports Server (NTRS)

Stewart, Mark E. M.

2017-01-01

This paper presents an analysis and simulation of evaporation and condensation at a motionless liquid/vapor interface. A 1-D model equation, emphasizing heat and mass transfer at the interface, is solved in two ways, and incorporated into a subgrid interface model within a CFD simulation. Simulation predictions are compared with experimental data from the CPST Engineering Design Unit tank, a cryogenic fluid management test tank in 1-g. The numerical challenge here is the physics of the liquid/vapor interface; pressurizing the ullage heats it by several degrees, and sets up an interfacial temperature gradient that transfers heat to the liquid phase-the rate limiting step of condensation is heat conducted through the liquid and vapor. This physics occurs in thin thermal layers O(1 mm) on either side of the interface which is resolved by the subgrid interface model. An accommodation coefficient of 1.0 is used in the simulations which is consistent with theory and measurements. This model is predictive of evaporation/condensation rates, that is, there is no parameter tuning.

Heat storage system utilizing phase change materials government rights

DOEpatents

Salyer, Ival O.

2000-09-12

A thermal energy transport and storage system is provided which includes an evaporator containing a mixture of a first phase change material and a silica powder, and a condenser containing a second phase change material. The silica powder/PCM mixture absorbs heat energy from a source such as a solar collector such that the phase change material forms a vapor which is transported from the evaporator to the condenser, where the second phase change material melts and stores the heat energy, then releases the energy to an environmental space via a heat exchanger. The vapor is condensed to a liquid which is transported back to the evaporator. The system allows the repeated transfer of thermal energy using the heat of vaporization and condensation of the phase change material.

Analysis of the thermal performance of heat pipe radiators

NASA Technical Reports Server (NTRS)

Boo, J. H.; Hartley, J. G.

1990-01-01

A comprehensive mathematical model and computational methodology are presented to obtain numerical solutions for the transient behavior of a heat pipe radiator in a space environment. The modeling is focused on a typical radiator panel having a long heat pipe at the center and two extended surfaces attached to opposing sides of the heat pipe shell in the condenser section. In the set of governing equations developed for the model, each region of the heat pipe - shell, liquid, and vapor - is thermally lumped to the extent possible, while the fin is lumped only in the direction normal to its surface. Convection is considered to be the only significant heat transfer mode in the vapor, and the evaporation and condensation velocity at the liquid-vapor interface is calculated from kinetic theory. A finite-difference numerical technique is used to predict the transient behavior of the entire radiator in response to changing loads.

Heat pipe with embedded wick structure

DOEpatents

Adkins, Douglas Ray; Shen, David S.; Tuck, Melanie R.; Palmer, David W.; Grafe, V. Gerald

1998-01-01

A heat pipe has an embedded wick structure that maximizes capillary pumping capability. Heat from attached devices such as integrated circuits evaporates working fluid in the heat pipe. The vapor cools and condenses on a heat dissipation surface. The condensate collects in the wick structure, where capillary pumping returns the fluid to high heat areas.

Heat pipe with embedded wick structure

DOEpatents

Adkins, Douglas Ray; Shen, David S.; Tuck, Melanie R.; Palmer, David W.; Grafe, V. Gerald

1999-01-01

A heat pipe has an embedded wick structure that maximizes capillary pumping capability. Heat from attached devices such as integrated circuits evaporates working fluid in the heat pipe. The vapor cools and condenses on a heat dissipation surface. The condensate collects in the wick structure, where capillary pumping returns the fluid to high heat areas.

A heat receiver design for solar dynamic space power systems

NASA Technical Reports Server (NTRS)

Baker, Karl W.; Dustin, Miles O.; Crane, Roger

1990-01-01

An advanced heat pipe receiver designed for a solar dynamic space power system is described. The power system consists of a solar concentrator, solar heat receiver, Stirling heat engine, linear alternator and waste heat radiator. The solar concentrator focuses the sun's energy into a heat receiver. The engine and alternator convert a portion of this energy to electric power and the remaining heat is rejected by a waste heat radiator. Primary liquid metal heat pipes transport heat energy to the Stirling engine. Thermal energy storage allows this power system to operate during the shade portion of an orbit. Lithium fluoride/calcium fluoride eutectic is the thermal energy storage material. Thermal energy storage canisters are attached to the midsection of each heat pipe. The primary heat pipes pass through a secondary vapor cavity heat pipe near the engine and receiver interface. The secondary vapor cavity heat pipe serves three important functions. First, it smooths out hot spots in the solar cavity and provides even distribution of heat to the engine. Second, the event of a heat pipe failure, the secondary heat pipe cavity can efficiently transfer heat from other operating primary heat pipes to the engine heat exchanger of the defunct heat pipe. Third, the secondary heat pipe vapor cavity reduces temperature drops caused by heat flow into the engine. This unique design provides a high level of reliability and performance.

Startup analysis for a high temperature gas loaded heat pipe

NASA Technical Reports Server (NTRS)

Sockol, P. M.

1973-01-01

A model for the rapid startup of a high-temperature gas-loaded heat pipe is presented. A two-dimensional diffusion analysis is used to determine the rate of energy transport by the vapor between the hot and cold zones of the pipe. The vapor transport rate is then incorporated in a simple thermal model of the startup of a radiation-cooled heat pipe. Numerical results for an argon-lithium system show that radial diffusion to the cold wall can produce large vapor flow rates during a rapid startup. The results also show that startup is not initiated until the vapor pressure p sub v in the hot zone reaches a precise value proportional to the initial gas pressure p sub i. Through proper choice of p sub i, startup can be delayed until p sub v is large enough to support a heat-transfer rate sufficient to overcome a thermal load on the heat pipe.

Metal vapor arc switch electromagnetic accelerator technology

NASA Technical Reports Server (NTRS)

Mongeau, P. P.

1984-01-01

A multielectrode device housed in an insulator vacuum vessel, the metal vapor vacuum switch has high power capability and can hold off voltages up to the 100 kilovolt level. Such switches can be electronically triggered and can interrupt or commutate at a zero current crossing. The physics of arc initiation, arc conduction, and interruption are examined, including material considerations; inefficiencies; arc modes; magnetic field effects; passive and forced extinction; and voltage recovery. Heating, electrode lifetime, device configuration, and external circuit configuration are discussed. The metal vapor vacuum switch is compared with SCRs, GTOs, spark gaps, ignitrons, and mechanical breakers.

Thermal-hydraulic behaviors of vapor-liquid interface due to arrival of a pressure wave

DOE Office of Scientific and Technical Information (OSTI.GOV)

Inoue, Akira; Fujii, Yoshifumi; Matsuzaki, Mitsuo

In the vapor explosion, a pressure wave (shock wave) plays a fundamental role for triggering, propagation and enhancement of the explosion. Energy of the explosion is related to the magnitude of heat transfer rate from hot liquid to cold volatile one. This is related to an increasing rate of interface area and to an amount of transient heat flux between the liquids. In this study, the characteristics of transient heat transfer and behaviors of vapor film both on the platinum tube and on the hot melt tin drop, under same boundary conditions have been investigated. It is considered that theremore » exists a fundamental mechanism of the explosion in the initial expansion process of the hot liquid drop immediately after arrival of pressure wave. The growth rate of the vapor film is much faster on the hot liquid than that on the solid surface. Two kinds of roughness were observed, one due to the Taylor instability, by rapid growth of the explosion bubble, and another, nucleation sites were observed at the vapor-liquid interface. Based on detailed observation of early stage interface behaviors after arrival of a pressure wave, the thermal fragmentation mechanism is proposed.« less

Interfacial nonequilibrium and Bénard-Marangoni instability of a liquid-vapor system

NASA Astrophysics Data System (ADS)

Margerit, J.; Colinet, P.; Lebon, G.; Iorio, C. S.; Legros, J. C.

2003-10-01

We study Bénard-Marangoni instability in a system formed by a horizontal liquid layer and its overlying vapor. The liquid is lying on a hot rigid plate and the vapor is bounded by a cold parallel plate. A pump maintains a reduced pressure in the vapor layer and evacuates the vapor. This investigation is undertaken within the classical quasisteady approximation for both the vapor and the liquid phases. The two layers are separated by a deformable interface. Temporarily frozen temperature and velocity distributions are employed at each instant for the stability analysis, limited to infinitesimal disturbances (linear regime). We use irreversible thermodynamics to model the phase change under interfacial nonequilibrium. Within this description, the interface appears as a barrier for transport of both heat and mass. Hence, in contrast with previous studies, we consider the possibility of a temperature jump across the interface, as recently measured experimentally. The stability analysis shows that the interfacial resistances to heat and mass transfer have a destabilizing influence compared to an interface that is in thermodynamic equilibrium. The role of the fluctuations in the vapor phase on the onset of instability is discussed. The conditions to reduce the system to a one phase model are also established. Finally, the influence of the evaporation parameters and of the presence of an inert gas on the marginal stability curves is discussed.

Theoretical evaluation of the vapor compression cycle with a liquid-line/suction-line heat exchanger, economizer, and ejector

DOE Office of Scientific and Technical Information (OSTI.GOV)

Domanski, P.A.

1995-03-01

The report presents a theoretical analysis of three vapor compression cycles which are derived from the Rankine cycle by incorporating a liquid-line/suction-line heat exchanger, economizer, or ejector. These addendums to the basic cycle reduce throttling losses using different principles, and they require different mechanical hardware of different complexity and cost. The theoretical merits of the three modified cycles were evaluated in relation to the reversed Carnot and Rankine cycle. Thirty-eight fluids were included in the study using the Carnahan-Starling-DeSantis equation of state. In general, the benefit of these addendums increases with the amount of the throttling losses realized by themore » refrigerant in the Rankine cycle.« less

Improvements to water vapor transmission and capillary absorption measurements in porous materials

Treesearch

Samuel L. Zelinka; Samuel V. Glass; Charles R. Boardman

2016-01-01

The vapor permeability (or equivalently the vapor diffusion resistance factor) and the capillary absorption coefficient are frequently used as inputs to hygrothermal or heat, air, and moisture (HAM) models. However, it has been well documented that the methods used to determine these properties are sensitive to the operator, and wide variations in the properties have...

Vapors-liquid phase separator. [infrared telescope heat sink

NASA Technical Reports Server (NTRS)

Frederking, T. H. K.; Brown, G. S.; Chuang, C.; Kamioka, Y.; Kim, Y. I.; Lee, J. M.; Yuan, S. W. K.

1980-01-01

The use of porous plugs, mostly with in the form of passive devices with constant area were considered as vapor-liquid phase separators for helium 2 storage vessels under reduced gravity. The incorporation of components with variable cross sectional area as a method of flow rate modification was also investigated. A particular device which uses a shutter-type system for area variation was designed and constructed. This system successfully permitted flor rate changes of up to plus or minus 60% from its mean value.

Heat pipe with embedded wick structure

DOEpatents

Adkins, D.R.; Shen, D.S.; Tuck, M.R.; Palmer, D.W.; Grafe, V.G.

1998-06-23

A heat pipe has an embedded wick structure that maximizes capillary pumping capability. Heat from attached devices such as integrated circuits evaporates working fluid in the heat pipe. The vapor cools and condenses on a heat dissipation surface. The condensate collects in the wick structure, where capillary pumping returns the fluid to high heat areas. 7 figs.

Laser beam interactions with vapor plumes during Nd:YAG laser welding on aluminum

NASA Astrophysics Data System (ADS)

Peebles, H. C.; Russo, A. J.; Hadley, G. R.; Akau, R. L.

Welds produced on pure aluminum targets using pulsed Nd:YAG lasers can be accurately described using a relatively simple conduction mode heat transfer model provided that the fraction of laser energy absorbed is known and the amount of metal vaporized is smalled however at laser fluences commonly used in many production welding schedules significant aluminum vaporization does occur. The possible mechanisms have been identified which could result in laser beam attenuation by the vapor plume.

The influence of chemical composition of LNG on the supercritical heat transfer in an intermediate fluid vaporizer

NASA Astrophysics Data System (ADS)

Xu, Shuangqing; Chen, Xuedong; Fan, Zhichao; Chen, Yongdong; Nie, Defu; Wu, Qiaoguo

2018-04-01

A three-dimensional transient computational fluid dynamics (CFD) model has been established for the simulations of supercritical heat transfer of real liquefied natural gas (LNG) mixture in a single tube and a tube bundle of an intermediate fluid vaporizer (IFV). The influence of chemical composition of LNG on the thermal performance has been analyzed. The results have also been compared with those obtained from the one-dimensional steady-state calculations using the distributed parameter model (DPM). It is found that the current DPM approach can give reasonable prediction accuracy for the thermal performance in the tube bundle but unsatisfactory prediction accuracy for that in a single tube as compared with the corresponding CFD data. As benchmarked against pure methane, the vaporization of an LNG containing about 90% (mole fraction) of methane would lead to an absolute deviation of 5.5 K in the outlet NG temperature and a maximum relative deviation of 11.4% in the tube side HTC in a bundle of about 816 U tubes at the inlet pressure of 12 MPa and mass flux of 200 kg·m-2·s-1. It is concluded that the influence of LNG composition on the thermal performance should be taken into consideration in order to obtain an economic and reliable design of an IFV.

Multileg Heat-Pipe Evaporator

NASA Technical Reports Server (NTRS)

Alario, J. P.; Haslett, R. A.

1986-01-01

Parallel pipes provide high heat flow from small heat exchanger. Six parallel heat pipes extract heat from overlying heat exchanger, forming evaporator. Vapor channel in pipe contains wick that extends into screen tube in liquid channel. Rods in each channel hold wick and screen tube in place. Evaporator compact rather than extended and more compatible with existing heat-exchanger geometries. Prototype six-pipe evaporator only 0.3 m wide and 0.71 m long. With ammonia as working fluid, transports heat to finned condenser at rate of 1,200 W.

Energy recovery during expansion of compressed gas using power plant low-quality heat sources

DOEpatents

Ochs, Thomas L [Albany, OR; O'Connor, William K [Lebanon, OR

2006-03-07

A method of recovering energy from a cool compressed gas, compressed liquid, vapor, or supercritical fluid is disclosed which includes incrementally expanding the compressed gas, compressed liquid, vapor, or supercritical fluid through a plurality of expansion engines and heating the gas, vapor, compressed liquid, or supercritical fluid entering at least one of the expansion engines with a low quality heat source. Expansion engines such as turbines and multiple expansions with heating are disclosed.

Water-Assisted Vapor Deposition of PEDOT Thin Film.

PubMed

Goktas, Hilal; Wang, Xiaoxue; Ugur, Asli; Gleason, Karen K

2015-07-01

The synthesis and characterization of poly(3,4-ethylenedioxythiophene) (PEDOT) using water-assisted vapor phase polymerization (VPP) and oxidative chemical vapor deposition (oCVD) are reported. For the VPP PEDOT, the oxidant, FeCl3 , is sublimated onto the substrate from a heated crucible in the reactor chamber and subsequently exposed to 3,4-ethylenedioxythiophene (EDOT) monomer and water vapor in the same reactor. The oCVD PEDOT was produced by introducing the oxidant, EDOT monomer, and water vapor simultaneously to the reactor. The enhancement of doping and crystallinity is observed in the water-assisted oCVD thin films. The high doping level observed at UV-vis-NIR spectra for the oCVD PEDOT, suggests that water acts as a solubilizing agent for oxidant and its byproducts. Although the VPP produced PEDOT thin films are fully amorphous, their conductivities are comparable with that of the oCVD produced ones. © 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Method and apparatus for operating a self-starting air heating system

DOEpatents

Heinrich, Charles E.

1983-12-06

A self-starting, fuel fired, air heating system including a fuel burner fired vapor generator, a turbine, and a condenser connected in a closed circuit such that the vapor output from the vapor generator is conducted to the turbine and then to the condenser where it is condensed for return to the vapor generator. The turbine drives an air blower which passes air over the condenser for cooling the condenser and heating the air. Also, a condensate pump is driven by the turbine. The disclosure is particularly concerned with a method and apparatus which on start-up prevents the vapor generator's vapor output from being conducted to the turbine until a predetermined pressure differential has been achieved. However, after the vapor flow is once permitted, it cannot again be prevented until after the fuel burner has been shut off and restarted.

VAPOR PRESSURE ISOTOPE EFFECTS IN THE MEASUREMENT OF ENVIRONMENTAL TRITIUM SAMPLES.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kuhne, W.

2012-12-03

Standard procedures for the measurement of tritium in water samples often require distillation of an appropriate sample aliquot. This distillation process may result in a fractionation of tritiated water and regular light water due to the vapor pressure isotope effect, introducing either a bias or an additional contribution to the total tritium measurement uncertainty. The magnitude of the vapor pressure isotope effect is characterized as functions of the amount of water distilled from the sample aliquot and the heat settings for the distillation process. The tritium concentration in the distillate is higher than the tritium concentration in the sample earlymore » in the distillation process, it then sharply decreases due to the vapor pressure isotope effect and becomes lower than the tritium concentration in the sample, until the high tritium concentration retained in the boiling flask is evaporated at the end of the process. At that time, the tritium concentration in the distillate again overestimates the sample tritium concentration. The vapor pressure isotope effect is more pronounced the slower the evaporation and distillation process is conducted; a lower heat setting during the evaporation of the sample results in a larger bias in the tritium measurement. The experimental setup used and the fact that the current study allowed for an investigation of the relative change in vapor pressure isotope effect in the course of the distillation process distinguish it from and extend previously published measurements. The separation factor as a quantitative measure of the vapor pressure isotope effect is found to assume values of 1.034 {+-} 0.033, 1.052 {+-} 0.025, and 1.066 {+-} 0.037, depending on the vigor of the boiling process during distillation of the sample. A lower heat setting in the experimental setup, and therefore a less vigorous boiling process, results in a larger value for the separation factor. For a tritium measurement in water samples, this implies

Headspace vapor characterization of Hanford Waste Tank 241-BY-108: Results from samples collected January 23, 1996. Tank Vapor Characterization Project

DOE Office of Scientific and Technical Information (OSTI.GOV)

Pool, K.H.; Evans, J.C.; Thomas, B.L.

1996-07-01

This report describes the results of vapor samples obtained to compare vapor sampling of the tank headspace using the Vapor Sampling System (VSS) and In Situ Vapor Sampling System (ISVS) with and without particulate prefiltration. Samples were collected from the headspace of waste storage tank 241-BY-108 (Tank BY-108) at the Hanford Site in Washington State. Pacific Northwest National Laboratory (PNNL) was contracted by Westinghouse Hanford Company (WHC) to provide sampling devices and analyze samples for water, ammonia, permanent gases, total nonmethane hydrocarbons (TNMHCs, also known as TO-12), and organic analytes in samples collected in SUMMA{trademark} canisters and on triple sorbentmore » traps (TSTs) from the tank headspace. The analytical work was performed by the PNNL Vapor Analytical Laboratory (VAL) by the Tank Vapor Characterization Project. Work performed was based on a sampling and analysis plan (SAP) prepared by WHC. The SAP provided job-specific instructions for samples, analyses, and reporting. The SAP for this sample job was {open_quotes}Sampling and Analysis Plan for Tank Vapor Sampling Comparison Test{close_quotes}, and the sample jobs were designated S6004, S6005, and S6006. Samples were collected by WHC on January 23, 1996, using the VSS, a truck-based sampling method using a heated probe; and the ISVS with and without particulate prefiltration.« less

Adsorption equilibrium of organic vapors on single-walled carbon nanotubes

USGS Publications Warehouse

Agnihotri, S.; Rood, M.J.; Rostam-Abadi, M.

2005-01-01

Gravimetric techniques were employed to determine the adsorption capacities of commercially available purified electric arc and HiPco single-walled carbon nanotubes (SWNTs) for organic compounds (toluene, methyl ethyl ketone (MEK), hexane and cyclohexane) at relative pressures, p/p0, ranging from 1 ?? 10-4 to 0.95 and at isothermal conditions of 25, 37 and 50 ??C. The isotherms displayed both type I and type II characteristics. Adsorption isotherm modeling showed that SWNTs are heterogeneous adsorbents, and the Freundlich equation best describes the interaction between organic molecules and SWNTs. The heats of adsorption were 1-4 times the heats of vaporization, which is typical for physical adsorption of organic vapors on porous carbons. ?? 2005 Elsevier Ltd. All rights reserved.

Chemical vapor deposition of group IIIB metals

DOEpatents

Erbil, Ahmet

1989-01-01

Coatings of Group IIIB metals and compounds thereof are formed by chemical vapor deposition, in which a heat decomposable organometallic compound of the formula (I) ##STR1## where M is a Group IIIB metal, such as lanthanum or yttrium and R is a lower alkyl or alkenyl radical containing from 2 to about 6 carbon atoms, with a heated substrate which is above the decomposition temperature of the organometallic compound. The pure metal is obtained when the compound of the formula I is the sole heat decomposable compound present and deposition is carried out under nonoxidizing conditions. Intermetallic compounds such as lanthanum telluride can be deposited from a lanthanum compound of formula I and a heat decomposable tellurium compound under nonoxidizing conditions.

Chemical vapor deposition of group IIIB metals

DOEpatents

Erbil, A.

1989-11-21

Coatings of Group IIIB metals and compounds thereof are formed by chemical vapor deposition, in which a heat decomposable organometallic compound of the formula given in the patent where M is a Group IIIB metal, such as lanthanum or yttrium and R is a lower alkyl or alkenyl radical containing from 2 to about 6 carbon atoms, with a heated substrate which is above the decomposition temperature of the organometallic compound. The pure metal is obtained when the compound of the formula 1 is the sole heat decomposable compound present and deposition is carried out under nonoxidizing conditions. Intermetallic compounds such as lanthanum telluride can be deposited from a lanthanum compound of formula 1 and a heat decomposable tellurium compound under nonoxidizing conditions.

Method for converting heat energy to mechanical energy with 1,2-dichloro-1,1-difluoroethane

DOE Office of Scientific and Technical Information (OSTI.GOV)

Li, C.C.; Stiel, L.I.

1980-09-30

1,2-dichloro-1,1-difluoroethane is useful as a power fluid with particular suitability for moderate scale Rankine cycle applications based on systems with moderate temperature heat sources. The fluid is utilized in a Rankine cycle application by vaporizing the fluid by passing the same in heat exchange relationship with a heat source and utilizing the kinetic energy of the resulting expanding vapors to perform work. In this manner heat energy is converted to mechanical energy. The fluid is particularly advantageous in a dual cycle system consisting of a Rankine power cycle combined with a vapor compression cooling or heating cycle.

Solar-powered Rankine heat pump for heating and cooling

NASA Technical Reports Server (NTRS)

Rousseau, J.

1978-01-01

The design, operation and performance of a familyy of solar heating and cooling systems are discussed. The systems feature a reversible heat pump operating with R-11 as the working fluid and using a motor-driven centrifugal compressor. In the cooling mode, solar energy provides the heat source for a Rankine power loop. The system is operational with heat source temperatures ranging from 155 to 220 F; the estimated coefficient of performance is 0.7. In the heating mode, the vapor-cycle heat pump processes solar energy collected at low temperatures (40 to 80 F). The speed of the compressor can be adjusted so that the heat pump capacity matches the load, allowing a seasonal coefficient of performance of about 8 to be attained.

Capillary Pumped Heat Transfer (CHT) Experiment

NASA Technical Reports Server (NTRS)

Hallinan, Kevin P.; Allen, J. S.

1998-01-01

The operation of Capillary Pumped Loops (CPL's) in low gravity has generally been unable to match ground-based performance. The reason for this poorer performance has been elusive. In order to investigate the behavior of a CPL in low-gravity, an idealized, glass CPL experiment was constructed. This experiment, known as the Capillary-driven Heat Transfer (CHT) experiment, was flown on board the Space Shuttle Columbia in July 1997 during the Microgravity Science Laboratory mission. During the conduct of the CHT experiment an unexpected failure mode was observed. This failure mode was a result of liquid collecting and then eventually bridging the vapor return line. With the vapor return line blocked, the condensate was unable to return to the evaporator and dry-out subsequently followed. The mechanism for this collection and bridging has been associated with long wavelength instabilities of the liquid film forming in the vapor return line. Analysis has shown that vapor line blockage in present generation CPL devices is inevitable. Additionally, previous low-gravity CPL tests have reported the presence of relatively low frequency pressure oscillations during erratic system performance. Analysis reveals that these pressure oscillations are in part a result of long wavelength instabilities present in the evaporator pores, which likewise lead to liquid bridging and vapor entrapment in the porous media. Subsequent evaporation to the trapped vapor increases the vapor pressure. Eventually the vapor pressure causes ejection of the bridged liquid. Recoil stresses depress the meniscus, the vapor pressure rapidly increases, and the heated surface cools. The process then repeats with regularity.

Vaporization Would Cool Primary Battery

NASA Technical Reports Server (NTRS)

Bhandari, Pradeep; Miyake, Robert N.

1991-01-01

Temperature of discharging high-power-density primary battery maintained below specified level by evaporation of suitable liquid from jacket surrounding battery, according to proposal. Pressure-relief valve regulates pressure and boiling temperature of liquid. Less material needed in cooling by vaporization than in cooling by melting. Technique used to cool batteries in situations in which engineering constraints on volume, mass, and location prevent attachment of cooling fins, heat pipes, or like.

Chemical heat pump

DOEpatents

Greiner, Leonard

1980-01-01

A chemical heat pump system is disclosed for use in heating and cooling structures such as residences or commercial buildings. The system is particularly adapted to utilizing solar energy, but also increases the efficiency of other forms of thermal energy when solar energy is not available. When solar energy is not available for relatively short periods of time, the heat storage capacity of the chemical heat pump is utilized to heat the structure as during nighttime hours. The design also permits home heating from solar energy when the sun is shining. The entire system may be conveniently rooftop located. In order to facilitate installation on existing structures, the absorber and vaporizer portions of the system may each be designed as flat, thin wall, thin pan vessels which materially increase the surface area available for heat transfer. In addition, this thin, flat configuration of the absorber and its thin walled (and therefore relatively flexible) construction permits substantial expansion and contraction of the absorber material during vaporization and absorption without generating voids which would interfere with heat transfer. The heat pump part of the system heats or cools a house or other structure through a combination of evaporation and absorption or, conversely, condensation and desorption, in a pair of containers. A set of automatic controls change the system for operation during winter and summer months and for daytime and nighttime operation to satisfactorily heat and cool a house during an entire year. The absorber chamber is subjected to solar heating during regeneration cycles and is covered by one or more layers of glass or other transparent material. Daytime home air used for heating the home is passed at appropriate flow rates between the absorber container and the first transparent cover layer in heat transfer relationship in a manner that greatly reduce eddies and resultant heat loss from the absorbant surface to ambient atmosphere.

Exploring the Relationship Between Octane Sensitivity and Heat-of-Vaporization

DOE Office of Scientific and Technical Information (OSTI.GOV)

Sluder, C. Scott; Szybist, James P.; McCormick, Robert L.

2016-04-05

The latent heat-of-vaporization (HoV) of blends of biofuel and hydrocarbon components into gasolines has recently experienced expanded interest because of the potential for increased HoV to increase fuel knock resistance in direct-injection (DI) engines. Several studies have been conducted, with some studies identifying an additional anti-knock benefit from HoV and others failing to arrive at the same conclusion. Consideration of these studies holistically shows that they can be grouped according to the level of fuel octane sensitivity variation within their fuel matrices. When comparing fuels of different octane sensitivity significant additional anti-knock benefits associated with HoV are sometimes observed. Studiesmore » that fix the octane sensitivity find that HoV does not produce additional anti-knock benefit. New studies were performed at ORNL and NREL to further investigate the relationship between HoV and octane sensitivity. Three fuels were formulated for the ORNL study with matched RON and octane sensitivity, but with differing HoV. Experiments with these fuels in a 1.6-liter GTDI engine showed that the fuels exhibited very similar combustion phasing under knock-limited spark advance (KLSA) conditions. Fuels having a range of RON, octane sensitivity, and HoV were tested at NREL in a single-cylinder GDI engine under conditions where octane sensitivity has little effect on knock resistance. KLSA was found to be well correlated with RON. These results reinforce the concept that HoV anti-knock effects can be viewed as a contributor to octane sensitivity. From this viewpoint, HoV effects manifest themselves as increases in octane sensitivity.« less

Bulk Growth of Wide Band Gap II-VI Compound Semiconductors by Physical Vapor Transport

NASA Technical Reports Server (NTRS)

Su, Ching-Hua

1997-01-01

The mechanism of physical vapor transport of II-VI semiconducting compounds was studied both theoretically, using a one-dimensional diffusion model, as well as experimentally. It was found that the vapor phase stoichiometry is critical in determining the vapor transport rate. The experimental heat treatment methods to control the vapor composition over the starting materials were investigated and the effectiveness of the heat treatments was confirmed by partial pressure measurements using an optical absorption technique. The effect of residual (foreign) gas on the transport rate was also studies theoretically by the diffusion model and confirmed experimentally by the measurements of total pressure and compositions of the residual gas. An in-situ dynamic technique for the transport rate measurements and a further extension of the technique that simultaneously measured the partial pressures and transport rates were performed and, for the first time, the experimentally determined mass fluxes were compared with those calculated, without any adjustable parameters, from the diffusion model. Using the information obtained from the experimental transport rate measurements as guideline high quality bulk crystal of wide band gap II-VI semiconductor were grown from the source materials which undergone the same heat treatment methods. The grown crystals were then extensively characterized with emphasis on the analysis of the crystalline structural defects.

Process to produce silicon carbide fibers using a controlled concentration of boron oxide vapor

NASA Technical Reports Server (NTRS)

Barnard, Thomas Duncan (Inventor); Lipowitz, Jonathan (Inventor); Nguyen, Kimmai Thi (Inventor)

2001-01-01

A process for producing polycrystalline silicon carbide by heating an amorphous ceramic fiber that contains silicon and carbon in an environment containing boron oxide vapor. The boron oxide vapor is produced in situ by the reaction of a boron containing material such as boron carbide and an oxidizing agent such as carbon dioxide, and the amount of boron oxide vapor can be controlled by varying the amount and rate of addition of the oxidizing agent.

Process to produce silicon carbide fibers using a controlled concentration of boron oxide vapor

NASA Technical Reports Server (NTRS)

Barnard, Thomas Duncan (Inventor); Lipowitz, Jonathan (Inventor); Nguyen, Kimmai Thi (Inventor)

2000-01-01

A process for producing polycrystalline silicon carbide includes heating an amorphous ceramic fiber that contains silicon and carbon in an environment containing boron oxide vapor. The boron oxide vapor is produced in situ by the reaction of a boron containing material such as boron carbide and an oxidizing agent such as carbon dioxide, and the amount of boron oxide vapor can be controlled by varying the amount and rate of addition of the oxidizing agent.

Optical droplet vaporization of nanoparticle-loaded stimuli-responsive microbubbles

DOE Office of Scientific and Technical Information (OSTI.GOV)

Si, Ting; Department of Biomedical Engineering, The Ohio State University, Columbus, Ohio 43210; Li, Guangbin

2016-03-14

A capillary co-flow focusing process is developed to generate stimuli-responsive microbubbles (SRMs) that comprise perfluorocarbon (PFC) suspension of silver nanoparticles (SNPs) in a lipid shell. Upon continuous laser irradiation at around their surface plasmon resonance band, the SNPs effectively absorb electromagnetic energy, induce heat accumulation in SRMs, trigger PFC vaporization, and eventually lead to thermal expansion and fragmentation of the SRMs. This optical droplet vaporization (ODV) process is further simulated by a theoretical model that combines heat generation of SNPs, phase change of PFC, and thermal expansion of SRMs. The model is validated by benchtop experiments, where the ODV processmore » is monitored by microscopic imaging. The effects of primary process parameters on behaviors of ODV are predicted by the theoretical model, indicating the technical feasibility for process control and optimization in future drug delivery applications.« less

Chemical heat pump and chemical energy storage system

DOEpatents

Clark, Edward C.; Huxtable, Douglas D.

1985-08-06

A chemical heat pump and storage system employs sulfuric acid and water. In one form, the system includes a generator and condenser, an evaporator and absorber, aqueous acid solution storage and water storage. During a charging cycle, heat is provided to the generator from a heat source to concentrate the acid solution while heat is removed from the condenser to condense the water vapor produced in the generator. Water is then stored in the storage tank. Heat is thus stored in the form of chemical energy in the concentrated acid. The heat removed from the water vapor can be supplied to a heat load of proper temperature or can be rejected. During a discharge cycle, water in the evaporator is supplied with heat to generate water vapor, which is transmitted to the absorber where it is condensed and absorbed into the concentrated acid. Both heats of dilution and condensation of water are removed from the thus diluted acid. During the discharge cycle the system functions as a heat pump in which heat is added to the system at a low temperature and removed from the system at a high temperature. The diluted acid is stored in an acid storage tank or is routed directly to the generator for reconcentration. The generator, condenser, evaporator, and absorber all are operated under pressure conditions specified by the desired temperature levels for a given application. The storage tanks, however, can be maintained at or near ambient pressure conditions. In another form, the heat pump system is employed to provide usable heat from waste process heat by upgrading the temperature of the waste heat.

Characterization and Evaluation of a Mass Efficient Heat Storage Device.

NASA Technical Reports Server (NTRS)

Splinter, Scott C.; Blosser, Max L.; Gifford, Andrew R.

2007-01-01

The heat sponge is a device for mass-efficient storage of heat. It was developed to be incorporated in the substructure of a reentry or hypersonic vehicle to reduce thermal protection system requirements. The heat sponge consists of a liquid-vapor mixture contained within a number of miniature pressure vessels that can be embedded within a variety of different types of structures. As temperature is increased, pressure in the miniature pressure vessels also increases so that heat absorbed through vaporization of the liquid is spread over a relatively large temperature range. Using water as a working fluid, the heat storage capacity of the liquid-vapor mixture is many times higher than that of typical structural materials and is well above that of common phase change materials over the temperature range of 660oR to 1160oR. Prototype heat sponges were fabricated and characterized. These heat sponges consisted of 1.0 inch diameter hollow stainless steel spheres with a wall thickness of 0.020 inches which had varying percentages of their interior volumes filled with water. An apparatus to measure the heat stored in these prototype heat sponges was designed, fabricated, and verified. The heat storage capacity calculated from measured temperature histories is compared to numerical predictions.

Headspace vapor characterization of Hanford Waste Tank 241-S-102: Results from samples collected on January 26, 1996. Tank Vapor Characterization Project

DOE Office of Scientific and Technical Information (OSTI.GOV)

Evans, J.C.; Thomas, B.L.; Pool, K.H.

1996-07-01

This report describes the results of vapor samples obtained to compare vapor sampling of the tank headspace using the Vapor Sampling System (VSS) and In Situ Vapor Sampling System (ISVS) with and without particulate prefiltration. Samples were collected from the headspace of waste storage tank 241-S-102 (Tank S-102) at the Hanford Site in Washington State. Pacific Northwest National Laboratory (PNNL) was contracted by Westinghouse Hanford Company (WHC) to provide sampling devices and analyze samples for water, ammonia, permanent gases, total nonmethane hydrocarbons (TNMHCs, also known as TO-12), and organic analytes in samples collected in SUMMA{trademark} canisters and on triple sorbentmore » traps (TSTs) from the tank headspace. The analytical work was performed by the PNNL Vapor Analytical Laboratory (VAL) by the Tank Vapor Characterization Project. Work performed was based on a sampling and analysis plan (SAP) prepared by WHC. The SAP provided job-specific instructions for samples, analyses, and reporting. The SAP for this sample job was {open_quotes}Sampling and Analysis Plan for Tank Vapor Sampling Comparison Test{close_quote}, and the sample jobs were designated S6007, S6008, and S6009. Samples were collected by WHC on January 26, 1996, using the VSS, a truck-based sampling method using a heated probe; and the ISVS with and without particulate prefiltration.« less

Water, heat, and vapor flow in a deep vadose zone under arid and hyper-arid conditions: a numerical study.

NASA Astrophysics Data System (ADS)

Madi, Raneem; de Rooij, Gerrit H.

2017-04-01

Groundwater recharge in arid regions is notoriously difficult to quantify. One reason is data scarcity: reliable weather records (rainfall, potential evapotranspiration rate, temperature) are typically lacking, the soil properties over the entire extent of the often very deep vadose zone are usually unknown, and the effect of sparse vegetation, wadis, (biological) soil crusts, and hard pans on infiltration and evaporation is difficult to quantify. Another reason is the difficulty of modeling the intricately coupled relevant processes over extended periods of time: coupled flow of liquid water, water vapor, and heat in a very deep soil in view of considerable uncertainty at the soil surface as indicated above, and over large spatial extents. In view of this myriad of problems, we limited ourselves to the simulation of 1-dimensional coupled flow of water, heat, and vapor in an unvegetated deep vadose zone. The conventional parameterizations of the soil hydraulic properties perform poorly under very dry conditions. We therefore selected an alternative that was developed specifically for dry circumstances and modified another to eliminate the physically implausible residual water content that rendered it of limited use for desert environments. The issue of data scarcity was resolved by using numerically generated rainfall records combined with a simple model for annual and daily temperature fluctuations. The soil was uniform, and the groundwater depth was constant at 100 m depth, which provided the lower boundary condition. The geothermal gradient determined the temperature at the groundwater level. We generated two scenarios with 120 years of weather in an arid and a hyper-arid climate. The initial condition was established by first starting with a somewhat arbitrary unit gradient initial condition corresponding to a small fraction of the annual average rainfall and let the model run through the 120-year atmospheric forcing. The resulting profile of matric potential

Heat recovery from sorbent-based CO.sub.2 capture

DOEpatents

Jamal, Aqil; Gupta, Raghubir P

2015-03-10

The present invention provides a method of increasing the efficiency of exothermic CO.sub.2 capture processes. The method relates to withdrawing heat generated during the exothermic capture of CO.sub.2 with various sorbents via heat exchange with a working fluid. The working fluid is provided at a temperature and pressure such that it is in the liquid state, and has a vaporization temperature in a range such that the heat arising from the reaction of the CO.sub.2 and the sorbent causes a phase change from liquid to vapor state in whole or in part and transfers heat from to the working fluid. The resulting heated working fluid may subsequently be used to generate power.

Vapor-dominated zones within hydrothermal systems: evolution and natural state

USGS Publications Warehouse

Ingebritsen, S.E.; Sorey, M.L.

1988-01-01

Three conceptual models illustrate the range of hydrothermal systems in which vapor-dominated conditions are found. The first model (model I) represents a system with an extensive near-vaporstatic vapor-dominated zone and limited liquid throughflow and is analogous to systems such as The Geysers, California. Models II and III represent systems with significant liquid throughflow and include steam-heated discharge features at higher elevations and high-chloride springs at lower elevations connected to and fed by a single circulation system at depth. In model II, as in model I, the vapor-dominated zone has a near-vaporstatic vertical pressure gradient and is generally underpressured with respect to local hydrostatic pressure. The vapor-dominated zone in model III is quite different, in that phase separation takes place at pressures close to local hydrostatic and the overall pressure gradient is near hydrostatic. -from Authors

Testing and Results of Human Metabolic Simulation Utilizing Ultrasonic Nebulizer Technology for Water Vapor Generation

NASA Technical Reports Server (NTRS)

Stubbe, Matthew; Curley, Su

2010-01-01

Life support technology must be evaluated thoroughly before ever being implemented into a functioning design. A major concern during that evaluation is safety. The ability to mimic human metabolic loads allows test engineers to evaluate the effectiveness of new technologies without risking injury to any actual humans. The main function of most life support technologies is the removal of carbon dioxide (CO2) and water (H2O) vapor. As such any good human metabolic simulator (HMS) will mimic the human body s ability to produce these items. Introducing CO2 into a test chamber is a very straightforward process with few unknowns so the focus of this particular new HMS design was on the much more complicated process of introducing known quantities of H2O vapor on command. Past iterations of the HMS have utilized steam which is very hard to keep in vapor phase while transporting and injecting into a test chamber. Also steam adds large quantities of heat to any test chamber, well beyond what an actual human does. For the new HMS an alternative approach to water vapor generation was designed utilizing ultrasonic nebulizers as a method for creating water vapor. Ultrasonic technology allows water to be vibrated into extremely tiny pieces (2-5 microns) and evaporate without requiring additional heating. Doing this process inside the test chamber itself allows H2O vapor generation without the unwanted heat and the challenging process of transporting water vapor. This paper presents the design details as well as results of all initial and final acceptance system testing. Testing of the system was performed at a range of known human metabolic rates in both sea-level and reduced pressure environments. This multitude of test points fully defines the systems capabilities as they relate to actual environmental systems testing.

Energy Savings Potential and RD&D Opportunities for Non-Vapor-Compression HVAC Technologies

DOE Office of Scientific and Technical Information (OSTI.GOV)

none,

While vapor-compression technologies have served heating, ventilation, and air-conditioning (HVAC) needs very effectively, and have been the dominant HVAC technology for close to 100 years, the conventional refrigerants used in vapor-compression equipment contribute to global climate change when released to the atmosphere. This Building Technologies Office report: --Identifies alternatives to vapor-compression technology in residential and commercial HVAC applications --Characterizes these technologies based on their technical energy savings potential, development status, non-energy benefits, and other factors affecting end-user acceptance and their ability to compete with conventional vapor-compression systems --Makes specific research, development, and deployment (RD&D) recommendations to support further development ofmore » these technologies, should DOE choose to support non-vapor-compression technology further.« less

Heat-transfer characteristics of the R113 annular two-phase closed thermosyphon - Heat transfer in the condenser

NASA Astrophysics Data System (ADS)

Maezawa, Saburo; Tsuchida, Akira; Takuma, Masao

1988-08-01

Visual observation of flow patterns in the condenser and heat transfer measurements were conducted for heat transfer rate ranges of 18-800 W using a vertical annular device with various quantities of R113 as a working fluid. As a result of visual observations, it was shown that ripples (interfacial waves) were generated on the condensate film surface when the condensate film Reynolds number exceeded approximately 20, and the condensation heat transfer was prompted. A simple theoretical analysis was presented in which the effects of interfacial waves and vapor drag were both considered. This analysis agreed very well with experimental results when the working fluid quantity was small enough so that the two-phase mixture generated by boiling the working fluid did not reach the condenser. The effects of interfacial waves and vapor drag on condensation heat transfer were also investigated theoretically.

Evaluation of energy in heated water vapor for the application of lung volume reduction in patients with severe emphysema.

PubMed

Henne, Erik; Kesten, Steven; Herth, Felix J F

2013-01-01

A method of achieving endoscopic lung volume reduction for emphysema has been developed that utilizes precise amounts of thermal energy in the form of water vapor to ablate lung tissue. This study evaluates the energy output and implications of the commercial InterVapor system and compares it to the clinical trial system. Two methods of evaluating the energy output of the vapor systems were used, a direct energy measurement and a quantification of resultant thermal profile in a lung model. Direct measurement of total energy and the component attributable to gas (vapor energy) was performed by condensing vapor in a water bath and measuring the temperature and mass changes. Infrared images of a lung model were taken after vapor delivery. The images were quantified to characterize the thermal profile. The total energy and vapor energy of the InterVapor system was measured at various dose levels and compared to the clinical trial system at a dose of 10.0 cal/g. An InterVapor dose of 8.5 cal/g was found to have the most similar vapor energy output with the smallest associated reduction in total energy. This was supported by characterization of the thermal profile in the lung model that demonstrated the profile of InterVapor at 8.5 cal/g to not exceed the profile of the clinical trial system. Considering both total energy and vapor energy is important during the development of clinical vapor applications. For InterVapor, a closer study of both energy types justified a reduced target vapor-dosing range for lung volume reduction. The clinical implication is a potential improvement for benefiting the risk profile. Copyright © 2013 S. Karger AG, Basel.

Thermal Analysis of Heat Pipe Radiators with A Rectangular Groove Wick Structure

DTIC Science & Technology

1990-06-01

heat pipe inside radius r, .... heat pipe vapor core radius R ..... radiosity R, . Reynolds number of vapor flow Rf .... reduction factor t ..... one...The radiosity of the fin element, R(x), consists of the emission from the surface of the fin element plus the reflected irradiation from both...the radiosity received from both heat pipe condensers, i.e., heat pipe condenser 1 and condenser 2. It can 2-12 be expressed as I(x)wedx = l R(O2)Fi

The cluster model of a hot dense vapor

NASA Astrophysics Data System (ADS)

Zhukhovitskii, D. I.

2015-04-01

We explore thermodynamic properties of a vapor in the range of state parameters where the contribution to thermodynamic functions from bound states of atoms (clusters) dominates over the interaction between the components of the vapor in free states. The clusters are assumed to be light and sufficiently "hot" for the number of bonds to be minimized. We use the technique of calculation of the cluster partition function for the cluster with a minimum number of interatomic bonds to calculate the caloric properties (heat capacity and velocity of sound) for an ideal mixture of the lightest clusters. The problem proves to be exactly solvable and resulting formulas are functions solely of the equilibrium constant of the dimer formation. These formulas ensure a satisfactory correlation with the reference data for the vapors of cesium, mercury, and argon up to moderate densities in both the sub- and supercritical regions. For cesium, we extend the model to the densities close to the critical one by inclusion of the clusters of arbitrary size. Knowledge of the cluster composition of the cesium vapor makes it possible to treat nonequilibrium phenomena such as nucleation of the supersaturated vapor, for which the effect of the cluster structural transition is likely to be significant.

The cluster model of a hot dense vapor

DOE Office of Scientific and Technical Information (OSTI.GOV)

Zhukhovitskii, D. I., E-mail: dmr@ihed.ras.ru

2015-04-28

We explore thermodynamic properties of a vapor in the range of state parameters where the contribution to thermodynamic functions from bound states of atoms (clusters) dominates over the interaction between the components of the vapor in free states. The clusters are assumed to be light and sufficiently “hot” for the number of bonds to be minimized. We use the technique of calculation of the cluster partition function for the cluster with a minimum number of interatomic bonds to calculate the caloric properties (heat capacity and velocity of sound) for an ideal mixture of the lightest clusters. The problem proves tomore » be exactly solvable and resulting formulas are functions solely of the equilibrium constant of the dimer formation. These formulas ensure a satisfactory correlation with the reference data for the vapors of cesium, mercury, and argon up to moderate densities in both the sub- and supercritical regions. For cesium, we extend the model to the densities close to the critical one by inclusion of the clusters of arbitrary size. Knowledge of the cluster composition of the cesium vapor makes it possible to treat nonequilibrium phenomena such as nucleation of the supersaturated vapor, for which the effect of the cluster structural transition is likely to be significant.« less

Contribution for Iron Vapor and Radiation Distribution Affected by Current Frequency of Pulsed Arc

NASA Astrophysics Data System (ADS)

Shimokura, Takuya; Mori, Yusuke; Iwao, Toru; Yumoto, Motoshige

Pulsed GTA welding has been used for improvement of stability, weld speed, and heat input control. However, the temperature and radiation power of the pulsed arc have not been elucidated. Furthermore, arc contamination by metal vapor changes the arc characteristics, e.g. by increasing radiation power. In this case, the metal vapor in pulsed GTA welding changes the distribution of temperature and radiation power as a function of time. This paper presents the relation between metal vapor and radiation power at different pulse frequencies. We calculate the Fe vapor distribution of the pulsed current. Results show that the Fe vapor is transported at fast arc velocity during the peak current period. During the base current period, the Fe vapor concentration is low and distribution is diffuse. The transition of Fe vapor distribution does not follow the pulsed current; the radiation power density distribution differs for high frequencies and low frequencies. In addition, the Fe vapor and radiation distribution are affected by the pulsed arc current frequency.

Curvature induced phase stability of an intensely heated liquid

NASA Astrophysics Data System (ADS)

Sasikumar, Kiran; Liang, Zhi; Cahill, David G.; Keblinski, Pawel

2014-06-01

We use non-equilibrium molecular dynamics simulations to study the heat transfer around intensely heated solid nanoparticles immersed in a model Lennard-Jones fluid. We focus our studies on the role of the nanoparticle curvature on the liquid phase stability under steady-state heating. For small nanoparticles we observe a stable liquid phase near the nanoparticle surface, which can be at a temperature well above the boiling point. Furthermore, for particles with radius smaller than a critical radius of 2 nm we do not observe formation of vapor even above the critical temperature. Instead, we report the existence of a stable fluid region with a density much larger than that of the vapor phase. We explain the stability in terms of the Laplace pressure associated with the formation of a vapor nanocavity and the associated effect on the Gibbs free energy.

Heat Pipes Reduce Engine-Exhaust Emissions

NASA Technical Reports Server (NTRS)

Schultz, D. F.

1986-01-01

Increased fuel vaporization raises engine efficiency. Heat-pipe technology increased efficiency of heat transfer beyond that obtained by metallic conduction. Resulted in both improved engine operation and reduction in fuel consumption. Raw material conservation through reduced dependence on strategic materials also benefit from this type of heat-pipe technology. Applications result in improved engine performance and cleaner environment.

Preliminary endurance tests of water vaporizers for resistojet applications

NASA Technical Reports Server (NTRS)

Morren, W. Earl; Macrae, Gregory S.

1993-01-01

Three water vaporizers designed for resistojet applications were built and tested for periods up to 500 h and 250 thermal cycles. Two of the vaporizers were not sensitive to orientation with respect to gravity, an indication of likely compatibility with low-gravity environments. Some temperatures and pressures in the third were impacted by orientation, although operation was always stable. The pressure drop across the sand-filled version increased by 147 percent in 38 h and 19 thermal cycles. Bonding of the sand granules in the downstream end of the heat exchanger was the suspected cause of failure of this vaporizer. Pressure drops across the two sintered stainless steel-filled versions were more gradual. One, with a pore size of 60 microns, showed an 80 percent increase in 500 h and 250 thermal cycles and another, with a 10 microns poresize, showed a 29 percent increase in 350 h and 175 thermal cycles. Testing of the latter metal-filled vaporizer was ongoing as of this writing. Oxidation of the porous metal packing materials in these vaporizers, with subsequent deposition of oxide particles within the pores, was believed to have caused the observed increases in pressure drops.

Rationale for the development and the mechanism of action of endoscopic thermal vapor ablation (InterVapor) for the treatment of emphysema.

PubMed

Kesten, Steven; Anderson, Joseph C; Tuck, Stephanie A

2012-07-01

Emphysema remains a disabling disease despite current treatment. Novel approaches to the underlying physiological abnormalities responsible for symptom generation are warranted. A review of current hypotheses and preclinical and clinical data on the utility of endoscopic thermal vapor ablation (InterVapor) in the treatment of emphysema. In animal studies, thermal energy in the form of heated water vapor both in healthy and in papain-induced emphysema in dogs and sheep leads to an inflammatory response followed by healing with airway and parenchymal fibrosis. The fibrosis and associated distal atelectasis result in volume reduction. The amount of thermal energy delivered has been based on the amount of target tissue mass determined from a high-resolution computed tomogram. Early human studies indicated the feasibility of InterVapor with 5 cal/g tissue; however, the dose appeared insufficient to induce lobar volume reduction. A study using 10 cal/g to 1 upper lobe (n=44) induced a mean of 46% lobar volume reduction at 12 months along with significant improvements in the physiology and health outcomes. InterVapor induces lung volume reduction in patients with emphysema. The mechanism of action is through a thermally induced inflammatory response followed by healing with subsequent remodeling of tissue (fibrosis and distal atelectasis).

SITE TECHNOLOGY CAPSULE: KAI RADIO FREQUENCY HEATING TECHNOLOGY

EPA Science Inventory

KAI developed a patented, in situ RFH technology to enhance the removal of volatile and semi-volatile organics by soil vapor extraction (SVE). Electromagnetic energy heats the soil resulting in increased contaminant vapor pressures and soil permeability that may increase with dry...

Nano-Pervaporation Membrane with Heat Exchanger Generates Medical-Grade Water

NASA Technical Reports Server (NTRS)

Tsai, Chung-Yi; Alexander, Jerry

2009-01-01

A nanoporous membrane is used for the pervaporation process in which potable water is maintained, at atmospheric pressure, on the feed side of the membrane. The water enters the non-pervaporation (NPV) membrane device where it is separated into two streams -- retentate water and permeated water. The permeated pure water is removed by applying low vapor pressure on the permeate side to create water vapor before condensation. This permeated water vapor is subsequently condensed by coming in contact with the cool surface of a heat exchanger with heat being recovered through transfer to the feed water stream.

Role of Co-Vapors in Vapor Deposition Polymerization

PubMed Central

Lee, Ji Eun; Lee, Younghee; Ahn, Ki-Jin; Huh, Jinyoung; Shim, Hyeon Woo; Sampath, Gayathri; Im, Won Bin; Huh, Yang–Il; Yoon, Hyeonseok

2015-01-01

Polypyrrole (PPy)/cellulose (PPCL) composite papers were fabricated by vapor phase polymerization. Importantly, the vapor-phase deposition of PPy onto cellulose was assisted by employing different co-vapors namely methanol, ethanol, benzene, water, toluene and hexane, in addition to pyrrole. The resulting PPCL papers possessed high mechanical flexibility, large surface-to-volume ratio, and good redox properties. Their main properties were highly influenced by the nature of the co-vaporized solvent. The morphology and oxidation level of deposited PPy were tuned by employing co-vapors during the polymerization, which in turn led to change in the electrochemical properties of the PPCL papers. When methanol and ethanol were used as co-vapors, the conductivities of PPCL papers were found to have improved five times, which was likely due to the enhanced orientation of PPy chain by the polar co-vapors with high dipole moment. The specific capacitance of PPCL papers obtained using benzene, toluene, water and hexane co-vapors was higher than those of the others, which is attributed to the enlarged effective surface area of the electrode material. The results indicate that the judicious choice and combination of co-vapors in vapor-deposition polymerization (VDP) offers the possibility of tuning the morphological, electrical, and electrochemical properties of deposited conducting polymers. PMID:25673422

Influence of phase transition on the instability of a liquid-vapor interface in a gravitational field

NASA Astrophysics Data System (ADS)

Konovalov, V. V.; Lyubimov, D. V.; Lyubimova, T. P.

2017-06-01

This study is concerned with the linear stability of the horizontal interface between thick layers of a viscous heat-conducting liquid and its vapor in a gravitational field subject to phase transition. We consider the case when the hydrostatic base state is consistent with a balanced heat flux at the liquid-vapor interface. The corrections to the growth rate of the most dangerous perturbations and cutoff wave number, characterizing the influence of phase transition on the Rayleigh-Taylor instability, are found to be different from the data in the literature. Most of the previous results were obtained in the framework of a quasiequilibrium approximation, which had been shown to conform to the limit of thin media layers under equality of the interface temperature to a saturation temperature. The main difference from the results obtained with the quasiequilibrium approach is new values of the proportionality coefficients that correlate our corrections with the intensity of weak heating. Moreover, at large values of the heat flux rate, when deviations from the approximate linear law are important, the effect of phase transition is limited and does not exceed the size of the vapor viscosity effect.

Transition process leading to microbubble emission boiling on horizontal circular heated surface in subcooled pool

NASA Astrophysics Data System (ADS)

Ueno, Ichiro; Ando, Jun; Horiuchi, Kazuna; Saiki, Takahito; Kaneko, Toshihiro

2016-11-01

Microbubble emission boiling (MEB) produces a higher heat flux than critical heat flux (CHF) and therefore has been investigated in terms of its heat transfer characteristics as well as the conditions under which MEB occurs. Its physical mechanism, however, is not yet clearly understood. We carried out a series of experiments to examine boiling on horizontal circular heated surfaces of 5 mm and of 10 mm in diameter, in a subcooled pool, paying close attention to the transition process to MEB. High-speed observation results show that, in the MEB regime, the growth, condensation, and collapse of the vapor bubbles occur within a very short time. In addition, a number of fine bubbles are emitted from the collapse of the vapor bubbles. By tracking these tiny bubbles, we clearly visualize that the collapse of the vapor bubbles drives the liquid near the bubbles towards the heated surface, such that the convection field around the vapor bubbles under MEB significantly differs from that under nucleate boiling. Moreover, the axial temperature gradient in a heated block (quasi-heat flux) indicates a clear difference between nucleate boiling and MEB. A combination of quasi-heat flux and the measurement of the behavior of the vapor bubbles allows us to discuss the transition to MEB. This work was financially supported by the 45th Research Grant in Natural Sciences from The Mitsubishi Foundation (2014 - 2015), and by Research Grant for Boiler and Pressurized Vessels from The Japan Boiler Association (2016).

Heat transfer evaluation in a plasma core reactor

NASA Technical Reports Server (NTRS)

Smith, D. E.; Smith, T. M.; Stoenescu, M. L.

1976-01-01

Numerical evaluations of heat transfer in a fissioning uranium plasma core reactor cavity, operating with seeded hydrogen propellant, was performed. A two-dimensional analysis is based on an assumed flow pattern and cavity wall heat exchange rate. Various iterative schemes were required by the nature of the radiative field and by the solid seed vaporization. Approximate formulations of the radiative heat flux are generally used, due to the complexity of the solution of a rigorously formulated problem. The present work analyzes the sensitivity of the results with respect to approximations of the radiative field, geometry, seed vaporization coefficients and flow pattern. The results present temperature, heat flux, density and optical depth distributions in the reactor cavity, acceptable simplifying assumptions, and iterative schemes. The present calculations, performed in cartesian and spherical coordinates, are applicable to any most general heat transfer problem.

Liquid-Infused Smooth Surface for Improved Condensation Heat Transfer.

PubMed

Tsuchiya, Hirotaka; Tenjimbayashi, Mizuki; Moriya, Takeo; Yoshikawa, Ryohei; Sasaki, Kaichi; Togasawa, Ryo; Yamazaki, Taku; Manabe, Kengo; Shiratori, Seimei

2017-09-12

Control of vapor condensation properties is a promising approach to manage a crucial part of energy infrastructure conditions. Heat transfer by vapor condensation on superhydrophobic coatings has garnered attention, because dropwise condensation on superhydrophobic surfaces with rough structures leads to favorable heat-transfer performance. However, pinned condensed water droplets within the rough structure and a high thermodynamic energy barrier for nucleation of superhydrophobic surfaces limit their heat-transfer increase. Recently, slippery liquid-infused surfaces (SLIPS) have been investigated, because of their high water sliding ability and surface smoothness originating from the liquid layer. However, even on SLIPS, condensed water droplets are eventually pinned to degrade their heat-transfer properties after extended use, because the rough base layer is exposed as infused liquid is lost. Herein, we report a liquid-infused smooth surface named "SPLASH" (surface with π electron interaction liquid adsorption, smoothness, and hydrophobicity) to overcome the problems derived from the rough structures in previous approaches to obtain stable, high heat-transfer performance. The SPLASH displayed a maximum condensation heat-transfer coefficient that was 175% higher than that of an uncoated substrate. The SPLASH also showed higher heat-transfer performance and more stable dropwise condensation than superhydrophobic surfaces and SLIPS from the viewpoints of condensed water droplet mobility and the thermodynamic energy barrier for nucleation. The effects of liquid-infused surface roughness and liquid viscosity on condensation heat transfer were investigated to compare heat-transfer performance. This research will aid industrial applications using vapor condensation.

Effects of capillary heterogeneity on vapor-liquid counterflow in porous media

NASA Astrophysics Data System (ADS)

Stubos, A. K.; Satik, C.; Yortsos, Y. C.

1992-06-01

Based on a continuum description, the effect of capillary heterogeneity, induced by variation in permeability, on the steady state, countercurrent, vapor-liquid flow in porous media is analyzed. It is shown that the heterogeneity acts as a body force that may enhance or diminish gravity effects on heat pipes. Selection rules that determine the steady states reached in homogeneous, gravity-driven heat pipes are also formulated. It is shown that the 'infinite' two-phase zone may terminate by a substantial change in the permeability somewhere in the medium. The two possible sequences, liquid-liquid dominated-dry, or liquid-vapor dominated-dry find applications in geothermal systems. Finally, it is shown that although weak heterogeneity affects only gravity controlled flows, stronger variations in permeability can give rise to significant capillary effects.

High heat transfer oxidizer heat exchanger design and analysis. [RL10-2B engine

NASA Technical Reports Server (NTRS)

Kmiec, Thomas D.; Kanic, Paul G.; Peckham, Richard J.

1987-01-01

The RL10-2B engine, a derivative of the RL10, is capable of multimode thrust operation. This engine operates at two low thrust levels: tank head idle (THI), which is approximately 1 to 2% of full thrust, and pumped idle (PI), which is 10% of full thrust. Operation at THI provides vehicle propellant settling thrust and efficient engine thermal conditioning; PI operation provides vehicle tank pre-pressurization and maneuver thrust for low-g deployment. Stable combustion of the RL10-2B engine during the low thrust operating modes can be accomplished by using a heat exchanger to supply gaseous oxygen to the propellant injector. The oxidizer heat exchanger (OHE) vaporizes the liquid oxygen using hydrogen as the energy source. The design, concept verification testing and analysis for such a heat exchanger is discussed. The design presented uses a high efficiency compact core to vaporize the oxygen, and in the self-contained unit, attenuates any pressure and flow oscillations which result from unstable boiling in the core. This approach is referred to as the high heat transfer design. An alternative approach which prevents unstable boiling of the oxygen by limiting the heat transfer is referred to as the low heat transfer design and is reported in Pratt & Whitney report FR-19135-2.

Thermodynamic Properties of Nitrogen Including Liquid and Vapor Phases from 63K to 2000K with Pressures to 10,000 Bar

NASA Technical Reports Server (NTRS)

Jacobsen, Richard T.; Stewart, Richard B.

1973-01-01

Tables of thermodynamic properties of nitrogen are presented for the liquid and vapor phases for temperatures from the freezing line to 2000K and pressures to 10,000 bar. The tables include values of density, internal energy, enthalpy, entropy, isochoric heat capacity, isobaric heat capacity velocity of sound, the isotherm derivative, and the isochor derivative. The thermodynamic property tables are based on an equation of state, P=P (p,T), which accurately represents liquid and gaseous nitrogen for the range of pressures and temperatures covered by the tables. Comparisons of property values calculated from the equation of state with measured values for P-p-T, heat capacity, enthalpy, latent heat, and velocity of sound are included to illustrate the agreement between the experimental data and the tables of properties presented here. The coefficients of the equation of state were determined by a weighted least squares fit to selected P-p-T data and, simultaneously, to isochoric heat capacity data determined by corresponding states analysis from oxygen data, and to data which define the phase equilibrium criteria for the saturated liquid and the saturated vapor. The vapor pressure equation, melting curve equation, and an equation to represent the ideal gas heat capacity are also presented. Estimates of the accuracy of the equation of state, the vapor pressure equation, and the ideal gas heat capacity equation are given. The equation of state, derivatives of the equation, and the integral functions for calculating derived thermodynamic properties are included.

Chemical vapor deposition of sialon

DOEpatents

Landingham, Richard L.; Casey, Alton W.

1982-01-01

A laminated composite and a method for forming the composite by chemical vapor deposition. The composite includes a layer of sialon and a material to which the layer is bonded. The method includes the steps of exposing a surface of the material to an ammonia containing atmosphere; heating the surface to at least about 1200.degree. C.; and impinging a gas containing in a flowing atmosphere of air N.sub.2, SiCl.sub.4, and AlCl.sub.3 on the surface.

Chemical vapor deposition of sialon

DOEpatents

Landingham, R.L.; Casey, A.W.

A laminated composite and a method for forming the composite by chemical vapor deposition are described. The composite includes a layer of sialon and a material to which the layer is bonded. The method includes the steps of exposing a surface of the material to an ammonia containing atmosphere; heating the surface to at least about 1200/sup 0/C; and impinging a gas containing N/sub 2/, SiCl/sub 4/, and AlCl/sub 3/ on the surface.

Performance of a hybrid chemical/mechanical heat pump

NASA Technical Reports Server (NTRS)

Silvestri, John J.; Scaringe, Robert P.; Grzyll, Lawrence R.

1990-01-01

The authors present the design and preliminary results of the performance of a hybrid chemical/mechanical, low-lift (20 C) heat pump. Studies have indicated that this heat pump has several advantages over the traditional single fluid vapor compression (reverse Rankine) heat pump. Included in these benefits are: 1) increased COPc due to the approximation of the cycle to the Lorenz cycle and due to the availability of the heat of solution, along with the heat of vaporization, to provide cooling; and 2) ease of variation in system cooling capacity by changing the fluid composition. The system performance is predicted for a variety of refrigerant-absorbent pairs. Cooling capacity is determined for systems operating with ammonia as the refrigerant and lithium nitrate and sodium thiocyanate as the absorbents and also with water as the refrigerant and magnesium chloride, potassium hydroxide, lithium bromide, sodium hydroxide, and sulfuric acid as the absorbents. Early indications have shown that the systems operating with water as the refrigerant operate at 2-4 times the capacity of the ammonia-refrigerant-based systems. Using existing working fluids in the proposed innovative design, a coefficient-of-performance improvement of 21 percent is possible when compared to the best vapor compression systems analyzed.

Experimental study of a constrained vapor bubble fin heat exchanger in the absence of external natural convection.

PubMed

Basu, Sumita; Plawsky, Joel L; Wayner, Peter C

2004-11-01

In preparation for a microgravity flight experiment on the International Space Station, a constrained vapor bubble fin heat exchanger (CVB) was operated both in a vacuum chamber and in air on Earth to evaluate the effect of the absence of external natural convection. The long-term objective is a general study of a high heat flux, low capillary pressure system with small viscous effects due to the relatively large 3 x 3 x 40 mm dimensions. The current CVB can be viewed as a large-scale version of a micro heat pipe with a large Bond number in the Earth environment but a small Bond number in microgravity. The walls of the CVB are quartz, to allow for image analysis of naturally occurring interference fringes that give the pressure field for liquid flow. The research is synergistic in that the study requires a microgravity environment to obtain a low Bond number and the space program needs thermal control systems, like the CVB, with a large characteristic dimension. In the absence of natural convection, operation of the CVB may be dominated by external radiative losses from its quartz surface. Therefore, an understanding of radiation from the quartz cell is required. All radiative exchange with the surroundings occurs from the outer surface of the CVB when the temperature range renders the quartz walls of the CVB optically thick (lambda > 4 microns). However, for electromagnetic radiation where lambda < 2 microns, the walls are transparent. Experimental results obtained for a cell charged with pentane are compared with those obtained for a dry cell. A numerical model was developed that successfully simulated the behavior and performance of the device observed experimentally.

Comparison of vapor formation of water at the solid/water interface to colloidal solutions using optically excited gold nanostructures.

PubMed

Baral, Susil; Green, Andrew J; Livshits, Maksim Y; Govorov, Alexander O; Richardson, Hugh H

2014-02-25

The phase transformation properties of liquid water to vapor is characterized by optical excitation of the lithographically fabricated single gold nanowrenches and contrasted to the phase transformation properties of gold nanoparticles located and optically excited in a bulk solution system [two and three dimensions]. The 532 nm continuous wave excitation of a single gold nanowrench results in superheating of the water to the spinodal decomposition temperature of 580 ± 20 K with bubble formation below the spinodal decomposition temperature being a rare event. Between the spinodal decomposition temperature and the boiling point liquid water is trapped into a metastable state because a barrier to vapor nucleation exists that must be overcome before the thermodynamically stable state is realized. The phase transformation for an optically heated single gold nanowrench is different from the phase transformation of optically excited colloidal gold nanoparticles solution where collective heating effects dominates and leads to the boiling of the solution exactly at the boiling point. In the solution case, the optically excited ensemble of nanoparticles collectively raises the ambient temperature of water to the boiling point where liquid is converted into vapor. The striking difference in the boiling properties of the single gold nanowrench and the nanoparticle solution system can be explained in terms of the vapor-nucleation mechanism, the volume of the overheated liquid, and the collective heating effect. The interpretation of the observed regimes of heating and vaporization is consistent with our theoretical modeling. In particular, we explain with our theory why the boiling with the collective heating in a solution requires 3 orders of magnitude less intensity compared to the case of optically driven single nanowrench.

Chemical vapor deposition of epitaxial silicon

DOEpatents

Berkman, Samuel

1984-01-01

A single chamber continuous chemical vapor deposition (CVD) reactor is described for depositing continuously on flat substrates, for example, epitaxial layers of semiconductor materials. The single chamber reactor is formed into three separate zones by baffles or tubes carrying chemical source material and a carrier gas in one gas stream and hydrogen gas in the other stream without interaction while the wafers are heated to deposition temperature. Diffusion of the two gas streams on heated wafers effects the epitaxial deposition in the intermediate zone and the wafers are cooled in the final zone by coolant gases. A CVD reactor for batch processing is also described embodying the deposition principles of the continuous reactor.

Rotary Vapor Compression Cycle Final Report.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kariya, Arthur; Staats, Wayne; Koplow, Jeffrey P.

While there are several heat pump technologies such thermoelectric, adsorption and magnetocaloric cycles, the oldest and most widely used is the vapor compression cycle (VCC). Currently, thermoelectric cycles have not yet achieved efficiencies nor cooling capacities comparable to VCCs. Adsorption cycles offer the benefit of using low-quality heat as the energy input, but are significantly more complex and expensive and are therefore limited to certain niche applications. Magnetocaloric cycles are still in the research phase. Consequently, improvements made for VCCs will likely have the most immediate and encompassing impact. The objective of this work is to develop an alternative VCCmore » topology to reduce the above inefficiencies.« less

Temperature-difference-driven mass transfer through the vapor from a cold to a warm liquid.

PubMed

Struchtrup, Henning; Kjelstrup, Signe; Bedeaux, Dick

2012-06-01

Irreversible thermodynamics provides interface conditions that yield temperature and chemical potential jumps at phase boundaries. The interfacial jumps allow unexpected transport phenomena, such as the inverted temperature profile [Pao, Phys. Fluids 14, 306 (1971)] and mass transfer from a cold to a warm liquid driven by a temperature difference across the vapor phase [Mills and Phillips, Chem. Phys. Lett. 372, 615 (2002)]. Careful evaluation of the thermodynamic laws has shown [Bedeaux et al., Physica A 169, 263 (1990)] that the inverted temperature profile is observed for processes with a high heat of vaporization. In this paper, we show that cold to warm mass transfer through the vapor from a cold to a warm liquid is only possible when the heat of evaporation is sufficiently small. A necessary criterium for the size of the mass transfer coefficient is given.

Method for removing metal vapor from gas streams

DOEpatents

Ahluwalia, R.K.; Im, K.H.

1996-04-02

A process for cleaning an inert gas contaminated with a metallic vapor, such as cadmium, involves withdrawing gas containing the metallic contaminant from a gas atmosphere of high purity argon; passing the gas containing the metallic contaminant to a mass transfer unit having a plurality of hot gas channels separated by a plurality of coolant gas channels; cooling the contaminated gas as it flows upward through the mass transfer unit to cause contaminated gas vapor to condense on the gas channel walls; regenerating the gas channels of the mass transfer unit; and, returning the cleaned gas to the gas atmosphere of high purity argon. The condensing of the contaminant-containing vapor occurs while suppressing contaminant particulate formation, and is promoted by providing a sufficient amount of surface area in the mass transfer unit to cause the vapor to condense and relieve supersaturation buildup such that contaminant particulates are not formed. Condensation of the contaminant is prevented on supply and return lines in which the contaminant containing gas is withdrawn and returned from and to the electrorefiner and mass transfer unit by heating and insulating the supply and return lines. 13 figs.

Method for removing metal vapor from gas streams

DOEpatents

Ahluwalia, R. K.; Im, K. H.

1996-01-01

A process for cleaning an inert gas contaminated with a metallic vapor, such as cadmium, involves withdrawing gas containing the metallic contaminant from a gas atmosphere of high purity argon; passing the gas containing the metallic contaminant to a mass transfer unit having a plurality of hot gas channels separated by a plurality of coolant gas channels; cooling the contaminated gas as it flows upward through the mass transfer unit to cause contaminated gas vapor to condense on the gas channel walls; regenerating the gas channels of the mass transfer unit; and, returning the cleaned gas to the gas atmosphere of high purity argon. The condensing of the contaminant-containing vapor occurs while suppressing contaminant particulate formation, and is promoted by providing a sufficient amount of surface area in the mass transfer unit to cause the vapor to condense and relieve supersaturation buildup such that contaminant particulates are not formed. Condensation of the contaminant is prevented on supply and return lines in which the contaminant containing gas is withdrawn and returned from and to the electrorefiner and mass transfer unit by heating and insulating the supply and return lines.

Secondhand Exposure to Vapors From Electronic Cigarettes

PubMed Central

Czogala, Jan; Fidelus, Bartlomiej; Zielinska-Danch, Wioleta; Travers, Mark J.; Sobczak, Andrzej

2014-01-01

Introduction: Electronic cigarettes (e-cigarettes) are designed to generate inhalable nicotine aerosol (vapor). When an e-cigarette user takes a puff, the nicotine solution is heated and the vapor is taken into lungs. Although no sidestream vapor is generated between puffs, some of the mainstream vapor is exhaled by e-cigarette user. The aim of this study was to evaluate the secondhand exposure to nicotine and other tobacco-related toxicants from e-cigarettes. Materials and Methods: We measured selected airborne markers of secondhand exposure: nicotine, aerosol particles (PM2.5), carbon monoxide, and volatile organic compounds (VOCs) in an exposure chamber. We generated e-cigarette vapor from 3 various brands of e-cigarette using a smoking machine and controlled exposure conditions. We also compared secondhand exposure with e-cigarette vapor and tobacco smoke generated by 5 dual users. Results: The study showed that e-cigarettes are a source of secondhand exposure to nicotine but not to combustion toxicants. The air concentrations of nicotine emitted by various brands of e-cigarettes ranged from 0.82 to 6.23 µg/m3. The average concentration of nicotine resulting from smoking tobacco cigarettes was 10 times higher than from e-cigarettes (31.60±6.91 vs. 3.32±2.49 µg/m3, respectively; p = .0081). Conclusions: Using an e-cigarette in indoor environments may involuntarily expose nonusers to nicotine but not to toxic tobacco-specific combustion products. More research is needed to evaluate health consequences of secondhand exposure to nicotine, especially among vulnerable populations, including children, pregnant women, and people with cardiovascular conditions. PMID:24336346

Micrometeorological observations of carbon, water vapor and heat exchanges on the California Academy of Sciences' living roof using eddy covariance

NASA Astrophysics Data System (ADS)

Lavender, S.; Oliphant, A. J.; Thorp, R.

2014-12-01

Living roofs have very different surface energy, water and carbon budgets than conventional roofs. Since roofs cover approximately one third of the planimetric surface area of cities, they are a significant driver of the urban boundary layer. Living roofs have been thought to be beneficial for reducing the urban heat island through increased latent heat exchange, uptake of atmospheric carbon dioxide and storage in soil and plant matter, building energy conservation through soil heat storage and latent heat fluxes and reduction in runoff. Here we present evidence of some of these through ongoing observations of surface energy, water and carbon budget estimates for the extensive living roof of the California Academy of Sciences building in Golden Gate Park, San Francisco, California. Micrometeorological measurements including the eddy covariance approach are used to estimate CO2, water vapor and both ground and atmospheric heat fluxes. The California Academy's roof encompasses an area of 18,000 m2. Vegetation surveys were conducted in the spring; beach strawberry (Fragaria chiloensis) and California bentgrass (Agrostis) were found to dominate the project footprint out of the 26 species observed. Eddy covariance measurements are made about one meter above the 10-20 cm tall vegetation on the downwind side of the building. Approximately 50% of data are rejected due to less than 80% of the flux source area being contained in the roof or due to low friction velocity. Nevertheless, we are able to develop robust diurnal ensemble fluxes, and will present data from a nine month period. During summer, the roof acted as a carbon sink of approximately 1.5 gC m-2 d-1. Turbulent heat fluxes were dominated by sensible heat flux with a mean Bowen ratio of approximately 1.5 and daily evapotranspiration rates of about 1.8 mm d-1. The role of seasonality and meteorology on surface microclimate characteristics will also be discussed.

Development of a hybrid chemical/mechanical heat pump

NASA Technical Reports Server (NTRS)

Grzyll, Lawrence R.; Silvestri, John J.; Scaringe, Robert P.

1991-01-01

The authors present the current development status of a hybrid chemical/mechanical heat pump for low-lift applications. The heat pump provides electronics cooling by evaporating a pure refrigerant from an absorbent/refrigerant mixture in a generator/cold plate. The current development focused on evaluation of absorbent/refrigerant pairs, corrosion testing, pump and compressor design, and electronic cold plate design. Two cycle configurations were considered. The first configuration utilized a standard mechanical compressor and pump. The second cycle configuration investigated pumps and compressors with non-moving parts. An innovative generator/cold plate design is also presented. The development to date shows that this cycle has about the same performance as standard vapor compression heat pumps with standard refrigerants but may have some performance and reliability advantages over vapor compression heat pumps.

Production of higher quality bio-oils by in-line esterification of pyrolysis vapor

DOEpatents

Hilten, Roger Norris; Das, Keshav; Kastner, James R; Bibens, Brian P

2014-12-02

The disclosure encompasses in-line reactive condensation processes via vapor phase esterification of bio-oil to decease reactive species concentration and water content in the oily phase of a two-phase oil, thereby increasing storage stability and heating value. Esterification of the bio-oil vapor occurs via the vapor phase contact and subsequent reaction of organic acids with ethanol during condensation results in the production of water and esters. The pyrolysis oil product can have an increased ester content and an increased stability when compared to a condensed pyrolysis oil product not treated with an atomized alcohol.

Vapor-phase interactions and diffusion of organic solvents in the unsaturated zone

USGS Publications Warehouse

Roy, W.R.; Griffin, R.A.

1990-01-01

This article presents an analysis of the interactions and static movement of 37 organic solvents as vapors through the unsaturated soil zone. The physicochemical interactions of the organic vapors with unsaturated soil materials were emphasized with focus on diffusive, and adsorptive interactions. Fick's Law and porous media diffusion coefficients for most of the solvent vapors were either compiled or estimated; coefficients were not available for some of the fluorinated solvents. The adsorption of some of the solvent vapors by silica was concluded to be due to hydrogen bond formation with surface silanol groups. Heats of adsorption data for different adsorbents were also compiled. There were very few data on the adsorption of these solvent vapors by soils, but it appears that the magnitude of adsorption of nonpolar solvents is reduced as the relative humidity of the vapor-solid system is increased. Consequently, the interaction of the vapors may then separated into two processes; (1) gas-water partitioning described by Henry's Law constants, and (2) solid-water adsorption coefficients which may be estimated from liquid-solid partition coefficients (Kd values). ?? 1990 Springer-Verlag New York Inc.

Vaporization chambers and associated methods

DOEpatents

Turner, Terry D.; Wilding, Bruce M.; McKellar, Michael G.; Shunn, Lee P.

2017-02-21

A vaporization chamber may include at least one conduit and a shell. The at least one conduit may have an inlet at a first end, an outlet at a second end and a flow path therebetween. The shell may surround a portion of each conduit and define a chamber surrounding the portion of each conduit. Additionally, a plurality of discrete apertures may be positioned at longitudinal intervals in a wall of each conduit, each discrete aperture of the plurality of discrete apertures sized and configured to direct a jet of fluid into each conduit from the chamber. A liquid may be vaporized by directing a first fluid comprising a liquid into the inlet at the first end of each conduit, directing jets of a second fluid into each conduit from the chamber through discrete apertures in a wall of each conduit and transferring heat from the second fluid to the first fluid.

Cirrus and Water Vapor Transport in the Tropical Tropopause Layer

NASA Astrophysics Data System (ADS)

Dinh, Tra Phuong

Simulations of tropical-tropopause-layer (TTL) cirrus under the influence of a large-scale equatorial Kelvin wave have been performed in two dimensions. These simulations show that, even under the influence of the large-scale wave, radiatively induced dynamics in TTL cirrus plays an important role in the transport of water vapor in the vertical direction. In a typical TTL cirrus, the heating that results from absorption of radiation by ice crystals induces a mesoscale circulation. Advection of ice and water vapor by the radiatively induced circulation leads to the persistence of the cloud and upward advection of the cloudy air. Upward advection of the cloudy air is equivalent to upward transport of water vapor when the air above the cloud is drier than the cloudy air, and downward transport otherwise. In TTL cirrus, microphysical processes also contribute to transport of water vapor in the vertical direction. Ice nucleation and growth, followed by sedimentation and sublimation, always lead to downward transport of water vapor. The magnitude of the downward transport by microphysical processes increases with the relative humidity of the air surrounding the cloud. Moisture in the surrounding environment is important because there is continuous interactions between the cloudy and environmental air throughout the cloud boundary. In our simulations, when the air surrounding the cloud is subsaturated, hence drier than the cloudy air, the magnitude of the downward transport due to microphysical processes is smaller than that of the upward transport due to the radiatively induced advection of water vapor. The net result is upward transport of water vapor, and equivalently hydration of the lower stratosphere. On the other hand, when the surrounding air is supersaturated, hence moister than the cloudy air, microphysical and radiatively induced dynamical processes work in concert to induce downward transport of water vapor, that is dehydration of the lower stratosphere. TTL

Mass spectrometry for water vapor measurements in the UT/LS

NASA Astrophysics Data System (ADS)

Kaufmann, S.; Voigt, C.; Schäuble, D.; Schäfler, A.; Schlager, H.; Thornberry, T. D.; Fahey, D. W.

2012-12-01

Water vapor in the lower stratosphere plays a crucial role for the atmospheric radiation budget (Solomon et al., 2011). However, large uncertainties remain in measuring atmospheric water vapor mixing ratios below 10 ppmv typical for the lower stratosphere. To this end, we have developed the Atmospheric Ionization Mass Spectrometer (AIMS) for the accurate and fast detection of water vapor in the UT/LS from aircraft. In the AIMS instrument atmospheric air is directly ionized in a discharge ion source and the resulting water vapor clusters H3O+(H2O)n (n = 0..3) are detected with a linear quadrupole mass spectrometer as a direct measure of the atmospheric water vapor mixing ratio. AIMS is calibrated in-flight with a H2O calibration source using the catalytic reaction of H2 and O2 on a heated platinum surface to form gaseous H2O. This calibration setup combined with the water vapor mass spectrometry offers a powerful technical development in atmospheric hygrometry, enriching existing H2O measurement techniques by a new independent method. Here, we present AIMS water vapor measurements performed during the CONCERT2011 campaign (Contrail and Cirrus Experiment) with the DLR research aircraft Falcon. In September 2011 a deep stratospheric intrusion was probed over northern Europe with a dynamical tropopause lowered down to 6 km. We found sharp humidity gradients between tropospheric and stratospheric air at the edge of the tropopause fold, which we crossed 4 times at altitudes between 6 and 11 km. In the center of the tropopause fold, we measured water vapor mixing ratios down to 4 ppmv. The observed water vapor distribution is compared to water vapor analysis fields of the ECMWF's Integrated Forecast System (IFS) to evaluate the representation water vapor in this specific meteorological situation.

Heat Pipe Technology: A bibliography with abstracts

NASA Technical Reports Server (NTRS)

1974-01-01

This bibliography lists 149 references with abstracts and 47 patents dealing with applications of heat pipe technology. Topics covered include: heat exchangers for heat recovery; electrical and electronic equipment cooling; temperature control of spacecraft; cryosurgery; cryogenic, cooling; nuclear reactor heat transfer; solar collectors; laser mirror cooling; laser vapor cavitites; cooling of permafrost; snow melting; thermal diodes variable conductance; artery gas venting; and venting; and gravity assisted pipes.

Investigation of Body Force Effects on Flow Boiling Critical Heat Flux

NASA Technical Reports Server (NTRS)

Zhang, Hui; Mudawar, Issam; Hasan, Mohammad M.

2002-01-01

The bubble coalescence and interfacial instabilities that are important to modeling critical heat flux (CHF) in reduced-gravity systems can be sensitive to even minute body forces. Understanding these complex phenomena is vital to the design and safe implementation of two-phase thermal management loops proposed for space and planetary-based thermal systems. While reduced gravity conditions cannot be accurately simulated in 1g ground-based experiments, such experiments can help isolate the effects of the various forces (body force, surface tension force and inertia) which influence flow boiling CHF. In this project, the effects of the component of body force perpendicular to a heated wall were examined by conducting 1g flow boiling experiments at different orientations. FC-72 liquid was boiled along one wall of a transparent rectangular flow channel that permitted photographic study of the vapor-liquid interface at conditions approaching CHF. High-speed video imaging was employed to capture dominant CHF mechanisms. Six different CHF regimes were identified: Wavy Vapor Layer, Pool Boiling, Stratification, Vapor Counterflow, Vapor Stagnation, and Separated Concurrent Vapor Flow. CHF showed great sensitivity to orientation for flow velocities below 0.2 m/s, where very small CHF values where measured, especially with downflow and downward-facing heated wall orientations. High flow velocities dampened the effects of orientation considerably. Figure I shows representative images for the different CHF regimes. The Wavy Vapor Layer regime was dominant for all high velocities and most orientations, while all other regimes were encountered at low velocities, in the downflow and/or downward-facing heated wall orientations. The Interfacial Lift-off model was modified to predict the effects of orientation on CHF for the dominant Wavy Vapor Layer regime. The photographic study captured a fairly continuous wavy vapor layer travelling along the heated wall while permitting liquid

THERMODYNAMIC EVALUATION OF FIVE ALTERNATIVE REFRIGERANTS IN VAPOR-COMPRESSION CYCLES

EPA Science Inventory

The paper gives results of a thermodynamic evaluation of five alternative refrigerants in a vapor-compression refrigeration cycle, utilizing throttling, super-heating, and combined throttling and superheating. ive alternative refrigerants (R32, R125, R134a, R143a, and R152a) were...

Heat-transfer thermal switch

NASA Technical Reports Server (NTRS)

Friedell, M. V.; Anderson, A. J.

1974-01-01

Thermal switch maintains temperature of planetary lander, within definite range, by transferring heat. Switch produces relatively large stroke and force, uses minimum electrical power, is lightweight, is vapor pressure actuated, and withstands sterilization temperatures without damage.

Ultrahigh Flux Thin Film Boiling Heat Transfer Through Nanoporous Membranes.

PubMed

Wang, Qingyang; Chen, Renkun

2018-05-09

Phase change heat transfer is fundamentally important for thermal energy conversion and management, such as in electronics with power density over 1 kW/cm 2 . The critical heat flux (CHF) of phase change heat transfer, either evaporation or boiling, is limited by vapor flux from the liquid-vapor interface, known as the upper limit of heat flux. This limit could in theory be greater than 1 kW/cm 2 on a planar surface, but its experimental realization has remained elusive. Here, we utilized nanoporous membranes to realize a new "thin film boiling" regime that resulted in an unprecedentedly high CHF of over 1.2 kW/cm 2 on a planar surface, which is within a factor of 4 of the theoretical limit, and can be increased to a higher value if mechanical strength of the membranes can be improved (demonstrated with 1.85 kW/cm 2 CHF in this work). The liquid supply is achieved through a simple nanoporous membrane that supports the liquid film where its thickness automatically decreases as heat flux increases. The thin film configuration reduces the conductive thermal resistance, leads to high frequency bubble departure, and provides separate liquid-vapor pathways, therefore significantly enhances the heat transfer. Our work provides a new nanostructuring approach to achieve ultrahigh heat flux in phase change heat transfer and will benefit both theoretical understanding and application in thermal management of high power devices of boiling heat transfer.

Active microchannel heat exchanger

DOEpatents

Tonkovich, Anna Lee Y [Pasco, WA; Roberts, Gary L [West Richland, WA; Call, Charles J [Pasco, WA; Wegeng, Robert S [Richland, WA; Wang, Yong [Richland, WA

2001-01-01

The present invention is an active microchannel heat exchanger with an active heat source and with microchannel architecture. The microchannel heat exchanger has (a) an exothermic reaction chamber; (b) an exhaust chamber; and (c) a heat exchanger chamber in thermal contact with the exhaust chamber, wherein (d) heat from the exothermic reaction chamber is convected by an exothermic reaction exhaust through the exhaust chamber and by conduction through a containment wall to the working fluid in the heat exchanger chamber thereby raising a temperature of the working fluid. The invention is particularly useful as a liquid fuel vaporizer and/or a steam generator for fuel cell power systems, and as a heat source for sustaining endothermic chemical reactions and initiating exothermic reactions.

Anomalous heat transport and condensation in convection of cryogenic helium

PubMed Central

Urban, Pavel; Schmoranzer, David; Hanzelka, Pavel; Sreenivasan, Katepalli R.; Skrbek, Ladislav

2013-01-01

When a hot body A is thermally connected to a cold body B, the textbook knowledge is that heat flows from A to B. Here, we describe the opposite case in which heat flows from a colder but constantly heated body B to a hotter but constantly cooled body A through a two-phase liquid–vapor system. Specifically, we provide experimental evidence that heat flows through liquid and vapor phases of cryogenic helium from the constantly heated, but cooler, bottom plate of a Rayleigh–Bénard convection cell to its hotter, but constantly cooled, top plate. The bottom plate is heated uniformly, and the top plate is cooled by heat exchange with liquid helium maintained at 4.2 K. Additionally, for certain experimental conditions, a rain of helium droplets is detected by small sensors placed in the cell at about one-half of its height. PMID:23576759

Mass and heat transfer model of Tubular Solar Still

DOE Office of Scientific and Technical Information (OSTI.GOV)

Ahsan, Amimul; Fukuhara, Teruyuki

2010-07-15

In this paper, a new mass and heat transfer model of a Tubular Solar Still (TSS) was proposed incorporating various mass and heat transfer coefficients taking account of the humid air properties inside the still. The heat balance of the humid air and the mass balance of the water vapor in the humid air were formulized for the first time. As a result, the proposed model enabled to calculate the diurnal variations of the temperature, water vapor density and relative humidity of the humid air, and to predict the hourly condensation flux besides the temperatures of the water, cover andmore » trough, and the hourly evaporation flux. The validity of the proposed model was verified using the field experimental results carried out in Fukui, Japan and Muscat, Oman in 2008. The diurnal variations of the calculated temperatures and water vapor densities had a good agreement with the observed ones. Furthermore, the proposed model can predict the daily and hourly production flux precisely. (author)« less

Preconcentrator with high volume chiller for high vapor pressure particle detection

DOEpatents

Linker, Kevin L

2013-10-22

Apparatus and method for collecting particles of both high and low vapor pressure target materials entrained in a large volume sample gas stream. Large volume active cooling provides a cold air supply which is mixed with the sample gas stream to reduce the vapor pressure of the particles. In embodiments, a chiller cools air from ambient conditions to 0-15.degree. C. with the volumetric flow rate of the cold air supply being at least equal to the volumetric flow rate of the sample gas stream. In further embodiments an adsorption media is heated in at least two stages, a first of which is below a threshold temperature at which decomposition products of the high vapor pressure particle are generated.

Dehumidifying Heat Pipe

NASA Technical Reports Server (NTRS)

Khattar, Mukesh K.

1993-01-01

U-shaped heat pipe partly dehumidifies air leaving air conditioner. Fits readily in air-handling unit of conditioner. Evaporator and condenser sections of heat pipe consist of finned tubes in comb pattern. Each tube sealed at one end and joined to manifold at other. Sections connected by single pipe carrying vapor to condenser manifold and liquid to evaporator manifold. Simple on/off or proportional valve used to control flow of working fluid. Valve actuated by temperature/humidity sensor.

Characterization of Single Phase and Two Phase Heat and Momentum Transport in a Spiraling Radial Inow Microchannel Heat Sink

NASA Astrophysics Data System (ADS)

Ruiz, Maritza

Thermal management of systems under high heat fluxes on the order of hundreds of W/cm2 is important for the safety, performance and lifetime of devices, with innovative cooling technologies leading to improved performance of electronics or concentrating solar photovoltaics. A novel, spiraling radial inflow microchannel heat sink for high flux cooling applications, using a single phase or vaporizing coolant, has demonstrated enhanced heat transfer capabilities. The design of the heat sink provides an inward swirl flow between parallel, coaxial disks that form a microchannel of 1 cm radius and 300 micron channel height with a single inlet and a single outlet. The channel is heated on one side through a conducting copper surface, and is essentially adiabatic on the opposite side to simulate a heat sink scenario for electronics or concentrated photovoltaics cooling. Experimental results on the heat transfer and pressure drop characteristics in the heat sink, using single phase water as a working fluid, revealed heat transfer enhancements due to flow acceleration and induced secondary flows when compared to unidirectional laminar fully developed flow between parallel plates. Additionally, thermal gradients on the surface are small relative to the bulk fluid temperature gain, a beneficial feature for high heat flux cooling applications. Heat flux levels of 113 W/cm2 at a surface temperature of 77 deg C were reached with a ratio of pumping power to heat rate of 0.03%. Analytical models on single phase flow are used to explore the parametric trends of the flow rate and passage geometry on the streamlines and pressure drop through the device. Flow boiling heat transfer and pressure drop characteristics were obtained for this heat sink using water at near atmospheric pressure as the working fluid for inlet subcooling levels ranging from 20 to 80 deg C and mean mass flux levels ranging from 184-716 kg/m. 2s. Flow enhancements similar to singlephase flow were expected, as well

Effect of the Thermocouple on Measuring the Temperature Discontinuity at a Liquid-Vapor Interface.

PubMed

Kazemi, Mohammad Amin; Nobes, David S; Elliott, Janet A W

2017-07-18

The coupled heat and mass transfer that occurs in evaporation is of interest in a large number of fields such as evaporative cooling, distillation, drying, coating, printing, crystallization, welding, atmospheric processes, and pool fires. The temperature jump that occurs at an evaporating interface is of central importance to understanding this complex process. Over the past three decades, thermocouples have been widely used to measure the interfacial temperature jumps at a liquid-vapor interface during evaporation. However, the reliability of these measurements has not been investigated so far. In this study, a numerical simulation of a thermocouple when it measures the interfacial temperatures at a liquid-vapor interface is conducted to understand the possible effects of the thermocouple on the measured temperature and features in the temperature profile. The differential equations of heat transfer in the solid and fluids as well as the momentum transfer in the fluids are coupled together and solved numerically subject to appropriate boundary conditions between the solid and fluids. The results of the numerical simulation showed that while thermocouples can measure the interfacial temperatures in the liquid correctly, they fail to read the actual interfacial temperatures in the vapor. As the results of our numerical study suggest, the temperature jumps at a liquid-vapor interface measured experimentally by using a thermocouple are larger than what really exists at the interface. For a typical experimental study of evaporation of water at low pressure, it was found that the temperature jumps measured by a thermocouple are overestimated by almost 50%. However, the revised temperature jumps are still in agreement with the statistical rate theory of interfacial transport. As well as addressing the specific application of the liquid-vapor temperature jump, this paper provides significant insight into the role that heat transfer plays in the operation of thermocouples

Experimental Investigation of Heat Pipe Startup Under Reflux Mode

NASA Technical Reports Server (NTRS)

Ku, Jentung

2018-01-01

In the absence of body forces such as gravity, a heat pipe will start as soon as its evaporator temperature reaches the saturation temperature. If the heat pipe operates under a reflux mode in ground testing, the liquid puddle will fill the entire cross sectional area of the evaporator. Under this condition, the heat pipe may not start when the evaporator temperature reaches the saturation temperature. Instead, a superheat is required in order for the liquid to vaporize through nucleate boiling. The amount of superheat depends on several factors such as the roughness of the heat pipe internal surface and the gravity head. This paper describes an experimental investigation of the effect of gravity pressure head on the startup of a heat pipe under reflux mode. In this study, a heat pipe with internal axial grooves was placed in a vertical position with different tilt angles relative to the horizontal plane. Heat was applied to the evaporator at the bottom and cooling was provided to the condenser at the top. The liquid-flooded evaporator was divided into seven segments along the axial direction, and an electrical heater was attached to each evaporator segment. Heat was applied to individual heaters in various combinations and sequences. Other test variables included the condenser sink temperature and tilt angle. Test results show that as long as an individual evaporator segment was flooded with liquid initially, a superheat was required to vaporize the liquid in that segment. The amount of superheat required for liquid vaporization was a function of gravity pressure head imposed on that evaporator segment and the initial temperature of the heat pipe. The most efficient and effective way to start the heat pipe was to apply a heat load with a high heat flux to the lowest segment of the evaporator.

Determination of saturation pressure and enthalpy of vaporization of semi-volatile aerosols: the integrated volume mentod

EPA Science Inventory

This study presents the integrated volume method for estimating saturation pressure and enthalpy of vaporization of a whole aerosol distribution. We measure the change of total volume of an aerosol distribution between a reference state and several heated states, with the heating...

Experimental evidence of the vapor recoil mechanism in the boiling crisis.

PubMed

Nikolayev, V S; Chatain, D; Garrabos, Y; Beysens, D

2006-11-03

Boiling crisis experiments are carried out in the vicinity of the liquid-gas critical point of H2. A magnetic gravity compensation setup is used to enable nucleate boiling at near critical pressure. The measurements of the critical heat flux that defines the threshold for the boiling crisis are carried out as a function of the distance from the critical point. The obtained power law behavior and the boiling crisis dynamics agree with the predictions of the vapor recoil mechanism and disagree with the classical vapor column mechanism.

Open-type miniature heat pipes

DOE Office of Scientific and Technical Information (OSTI.GOV)

Vasiliev, L.L.

1994-01-01

The hypothesis that systems of thermoregulation, similar to open-type micro heat pipes, exist in nature (soils, living organisms, plants) and in a number of technological processes (drying, thermodynamic cycles on solid adsorbents) is considered. The hydrodynamics and heat transfer in such thermoregulation systems differ from the hydrodynamics and heat transfer in classical heat pipes, since their geometrical dimensions are extremely small (dozens of microns), adhesion forces are powerful, the effect of the field of capillary and gravitational forces is significant, and strong interaction between counter-current flows of vapor and liquid takes place.

Post-Dryout Heat Transfer to a Refrigerant Flowing in Horizontal Evaporator Tubes

NASA Astrophysics Data System (ADS)

Mori, Hideo; Yoshida, Suguru; Kakimoto, Yasushi; Ohishi, Katsumi; Fukuda, Kenichi

Studies of the post-dryout heat transfer were made based on the experimental data for HFC-134a flowing in horizontal smooth and spiral1y grooved (micro-fin) tubes and the characteristics of the post-dryout heat transfer were c1arified. The heat transfer coefficient at medium and high mass flow rates in the smooth tube was lower than the single-phase heat transfer coefficient of the superheated vapor flow, of which mass flow rate was given on the assumption that the flow was in a thermodynamic equilibrium. A prediction method of post-dryout heat transfer coefficient was developed to reproduce the measurement satisfactorily for the smooth tube. The post dryout heat transfer in the micro-fin tube can be regarded approximately as a superheated vapor single-phase heat transfer.

Overview of chemical vapor infiltration

DOE Office of Scientific and Technical Information (OSTI.GOV)

Besmann, T.M.; Stinton, D.P.; Lowden, R.A.

1993-06-01

Chemical vapor infiltration (CVI) is developing into a commercially important method for the fabrication of continuous filament ceramic composites. Current efforts are focused on the development of an improved understanding of the various processes in CVI and its modeling. New approaches to CVI are being explored, including pressure pulse infiltration and microwave heating. Material development is also proceeding with emphasis on improving the oxidation resistance of the interfacial layer between the fiber and matrix. This paper briefly reviews these subjects, indicating the current state of the science and technology.

Effectiveness of a heat exchanger in a heat pump clothes dryer

NASA Astrophysics Data System (ADS)

Nasution, A. H.; Sembiring, P. G.; Ambarita, H.

2018-02-01

This paper deals with study on a heat pump clothes dryer coupled with a heat exchanger. The objective is to explore the effects of the heat exchanger on the performance of the heat pump dryer. The heat pump dryer consists of a vapor compression cycle and integrated with a drying room with volume 1 m3. The power of compressor is 800 Watt and the refrigerant of the cycle is R22. The heat exchanger is a flat plate type with dimensions of 400 mm × 400 mm × 400 mm. The results show the present of the heat exchanger increase the performance of the heat pump dryer. In the present experiment the COP, TP and SMER increase 15.11%, 4.81% and 58.62%, respectively. This is because the heat exchanger provides a better drying condition in the drying room with higher temperature and lower relative humidity in comparison with heat pump dryer without heat exchanger. The effectiveness of the heat exchanger is also high, it is above 50%. It is suggested to install a heat exchanger in a heat pump dryer.

SITE TECHNOLOGY CAPSULE: IITRI RADIO FREQUENCY HEATING TECHNOLOGY

EPA Science Inventory

Radio frequency heating (RFH) technologies use electromagnetic energy in the radio frequency i(RF) band to heat soil in-situ, thereby potentially enhancing the performances of standard soil vapor extraction (SVE) technologies. ontaminants are removed from in situ soils and transf...

DEMONSTRATION BULLETIN: RADIO FREQUENCY HEATING - IIT RESEARCH INSTITUTE

EPA Science Inventory

Radio frequency heating (RFH) is a process that uses electromagnetic energy generated by radio waves to heat soil in situ, thereby potentially enhancing the performance of standard soil vapor extraction (SVE) technologies. An RFH system developed by the IIT Research Institute ...

SITE TECHNOLOGY CAPSULE: IITRI RADIO FREQUENCY HEATING TECHNOLOGY

EPA Science Inventory

Radio frequency heating (RFH) technologies use electromagnetic energy in the radio frequency (RF) band to heat soil in situ, thereby potentially enhancing the performance of standard soil vapor extraction (SVE) technologies. Contaminants are removed from in situ soils and transfe...

Evaporation on/in Capillary Structures of High Heat Flux Two-Phase Devices

NASA Technical Reports Server (NTRS)

Faghri, Amir; Khrustalev, Dmitry

1996-01-01

Two-phase devices (heat pipes, capillary pumped loops, loop heat pipes, and evaporators) have become recognized as key elements in thermal control systems of space platforms. Capillary and porous structures are necessary and widely used in these devices, especially in high heat flux and zero-g applications, to provide fluid transport and enhanced heat transfer during vaporization and condensation. However, some unexpected critical phenomena, such as dryout in long heat pipe evaporators and high thermal resistance of loop heat pipe evaporators with high heat fluxes, are possible and have been encountered in the use of two-phase devices in the low gravity environment. Therefore, a detailed fundamental investigation is proposed to better understand the fluid behavior in capillary-porous structures during vaporization at high heat fluxes. The present paper addresses some theoretical aspects of this investigation.

Developmental toxicity evaluation of unleaded gasoline vapor in the rat.

PubMed

Roberts, L; White, R; Bui, Q; Daughtrey, W; Koschier, F; Rodney, S; Schreiner, C; Steup, D; Breglia, R; Rhoden, R; Schroeder, R; Newton, P

2001-01-01

To evaluate the potential of unleaded gasoline vapor for developmental toxicity, a sample was prepared by slowly heating API 94-02 (1990 industry average gasoline) and condensing the vapor. The composition of this vapor condensate, which comprises 10.4% by volume of the starting gasoline, is representative of real-world exposure to gasoline vapor encountered at service stations and other occupational settings and consists primarily of volatile short chain (C4-C6) aliphatic hydrocarbons (i.e. paraffins) with small amounts of cycloparaffins and aromatic hydrocarbons. A preliminary study in rats and mice resulted in no developmental toxicity in either species. However, a slight reduction in maternal body weight gain in rats led to the selection of rats for this guideline study. Groups of pregnant rats (n = 24/group) were exposed to unleaded gasoline vapor at concentrations of 0, 1000, 3000, or 9000 (75% lower explosive limit) ppm equivalent to 0, 2653, 7960, or 23,900 mg/m3, for 6 h/day on gestation days 6-19. All rats were sacrificed on gestation day 20. No maternal toxicity was observed. Developmentally, there were no differences between treated and control groups in malformations, total variations, resorptions, fetal body weight, or viability. The maternal and developmental NOAEL is 9000 ppm. Under conditions of this study, unleaded gasoline vapors did not produce evidence of developmental toxicity.

The Collapse of Vapor Bubbles in a Spatially Non-Uniform Flow

NASA Technical Reports Server (NTRS)

Hao, Y.; Prosperetti, A.

2000-01-01

Pressure gradients act differently on liquid particles and suspended bubbles and are, therefore, capable of inducing a relative motion between the phases even when no relative velocity initially exists. As a consequence of the enhanced heat transfer in the presence of convection, this fact may have a major impact on the evolution of a vapor bubble. The effect is particularly strong in the case of a collapsing bubble for which, due to the conservation of the system's impulse, the induced relative velocity tends to be magnified when the bubble volume shrinks. A practical application could be, for instance, the enhancement of the condensation rate of bubbles downstream of a heated region, thereby reducing the quality of a flowing liquid-vapor mixture. A simple model of the process, in which the bubble is assumed to be spherical and the flow potential, is developed in the paper.

Vaporization thermodynamics of K2S and K2SO3

NASA Technical Reports Server (NTRS)

Bennet, J. E.

1982-01-01

The vaporization reactions, vapor pressures, and thermodynamics of potassium sulfide and potassium sulfite were studied for purposes of providing fundamental data for the seed cycle in magnetohydrodynamic electric power generation. Rate of effusion studies, supported by tube furnace experiments, X-ray powder diffraction, mass spectrometry and appropriate chemical analyses and tests, revealed that potassium sulfite disproportionates at high temperatures to form potassium sulfide and potassium sulfate. Potassium sulfide was observed to vaporize incongruently, the initial vapors beng predominantly potassium atoms, with minor species being S2 and various K-S molecules. The ratio of K/S2 in the vapor is very large initially and decreases steadily with prolonged heating. Several materials were evaluated for purposes of containing K2S/K2SO3 at temperatures or = 800 C: Pt, Mo, W, quartz, machinable glass, BN, high density graphite, pyrolytic coated graphite, and alumina. Of these, only alumina was observed to be chemically inert to both K2S but reacted with K2SO3. The other materials were not suitable for either substance. Thermodynamic calculations based on measured vapor pressures and approximate free energy functions are described. Results from isothermal total mass loss experiments and from thermogravimetric experiments are also included.

Hybrid joule heating/electro-osmosis process for extracting contaminants from soil layers

DOEpatents

Carrigan, Charles R.; Nitao, John J.

2003-06-10

Joule (ohmic) heating and electro-osmosis are combined in a hybrid process for removal of both water-soluble contaminants and non-aqueous phase liquids from contaminated, low-permeability soil formations that are saturated. Central to this hybrid process is the partial desaturation of the formation or layer using electro-osmosis to remove a portion of the pore fluids by induction of a ground water flow to extraction wells. Joule heating is then performed on a partially desaturated formation. The joule heating and electro-osmosis operations can be carried out simultaneously or sequentially if the desaturation by electro-osmosis occurs initially. Joule heating of the desaturated formation results in a very effective transfer or partitioning of liquid state contaminants to the vapor phase. The heating also substantially increases the vapor phase pressure in the porous formation. As a result, the contaminant laden vapor phase is forced out into soil layers of a higher permeability where other conventional removal processes, such as steam stripping or ground water extraction can be used to capture the contaminants. This hybrid process is more energy efficient than joule heating or steam stripping for cleaning low permeability formations and can share electrodes to minimize facility costs.

Multiple source heat pump

DOEpatents

Ecker, Amir L.

1983-01-01

A heat pump apparatus for conditioning a fluid characterized by a fluid handler and path for circulating a fluid in heat exchange relationship with a refrigerant fluid, at least three refrigerant heat exchangers, one for effecting heat exchange with the fluid, a second for effecting heat exchange with a heat exchange fluid, and a third for effecting heat exchange with ambient air; a compressor for compressing the refrigerant; at least one throttling valve connected at the inlet side of a heat exchanger in which liquid refrigerant is vaporized; a refrigerant circuit; refrigerant; a source of heat exchange fluid; heat exchange fluid circuit and pump for circulating the heat exchange fluid in heat exchange relationship with the refrigerant; and valves or switches for selecting the heat exchangers and directional flow of refrigerant therethrough for selecting a particular mode of operation. Also disclosed are a variety of embodiments, modes of operation, and schematics therefor.

Pressurization of a Flightweight, Liquid Hydrogen Tank: Evaporation and Condensation at a Liquid Vapor Interface

NASA Technical Reports Server (NTRS)

Stewart, Mark

2017-01-01

Evaporation and condensation at a liquid-vapor interface is important for long-term, in-space cryogenic propellant storage. Yet the current understanding of inter-facial physics does not consistently predict behavior of evaporation or condensation rates. The proposed paper will present a physical model, based on the 1-D Heat equation and Schrage's equation, which demonstrates thin thermal layers at the fluid vapor interface.

Enhanced heat transfer using nanofluids

DOEpatents

Choi, Stephen U. S.; Eastman, Jeffrey A.

2001-01-01

This invention is directed to a method of and apparatus for enhancing heat transfer in fluids such as deionized water. ethylene glycol, or oil by dispersing nanocrystalline particles of substances such as copper, copper oxide, aluminum oxide, or the like in the fluids. Nanocrystalline particles are produced and dispersed in the fluid by heating the substance to be dispersed in a vacuum while passing a thin film of the fluid near the heated substance. The fluid is cooled to control its vapor pressure.

DEMONSTRATION BULLETIN: RADIO FREQUENCY HEATING - KAI TECHNOLOGIES, INC.

EPA Science Inventory

Radio frequency heating (RFH) is a process that uses electromagnetic energy in the radio frequency (RF) band to heat soil in situ, thereby potentially enhancing the performance of standard soil vapor extraction (SVE) technologies. An RFH system developed by KAI Technologies, I...

NASA Lewis steady-state heat pipe code users manual

NASA Technical Reports Server (NTRS)

Tower, Leonard K.; Baker, Karl W.; Marks, Timothy S.

1992-01-01

The NASA Lewis heat pipe code was developed to predict the performance of heat pipes in the steady state. The code can be used as a design tool on a personal computer or with a suitable calling routine, as a subroutine for a mainframe radiator code. A variety of wick structures, including a user input option, can be used. Heat pipes with multiple evaporators, condensers, and adiabatic sections in series and with wick structures that differ among sections can be modeled. Several working fluids can be chosen, including potassium, sodium, and lithium, for which monomer-dimer equilibrium is considered. The code incorporates a vapor flow algorithm that treats compressibility and axially varying heat input. This code facilitates the determination of heat pipe operating temperatures and heat pipe limits that may be encountered at the specified heat input and environment temperature. Data are input to the computer through a user-interactive input subroutine. Output, such as liquid and vapor pressures and temperatures, is printed at equally spaced axial positions along the pipe as determined by the user.

NASA Lewis steady-state heat pipe code users manual

NASA Astrophysics Data System (ADS)

Tower, Leonard K.; Baker, Karl W.; Marks, Timothy S.

1992-06-01

The NASA Lewis heat pipe code was developed to predict the performance of heat pipes in the steady state. The code can be used as a design tool on a personal computer or with a suitable calling routine, as a subroutine for a mainframe radiator code. A variety of wick structures, including a user input option, can be used. Heat pipes with multiple evaporators, condensers, and adiabatic sections in series and with wick structures that differ among sections can be modeled. Several working fluids can be chosen, including potassium, sodium, and lithium, for which monomer-dimer equilibrium is considered. The code incorporates a vapor flow algorithm that treats compressibility and axially varying heat input. This code facilitates the determination of heat pipe operating temperatures and heat pipe limits that may be encountered at the specified heat input and environment temperature. Data are input to the computer through a user-interactive input subroutine. Output, such as liquid and vapor pressures and temperatures, is printed at equally spaced axial positions along the pipe as determined by the user.

Evolution of steam-water flow structure under subcooled water boiling at smooth and structured heating surfaces

NASA Astrophysics Data System (ADS)

Vasiliev, N. V.; Zeigarnik, Yu A.; Khodakov, K. A.

2017-11-01

Experimentally studying of subcooled water boiling in rectangular channel electrically heated from one side was conducted. Flat surfaces, both smooth and coated by microarc oxidation technology, were used as heating surfaces. The tests were conducted at atmospheric pressure in the range of mass flow rate from 650 to 1300 kg/(m2 s) and water subcooling relative to saturation temperature from 23 to 75 °C. Using high-speed filming a change in the two-phase flow structure and its statistic characteristics (nucleation sites density, vapor bubble distribution by size, etc.) were studied. With an increase in the heat flux density (with the mass flow rate and subcooling being the same) and amount and size of the vapor bubbles increased also. At a relatively high heat flux density, non-spherical vapor agglomerates appeared at the heating surface as a result of coalescence of small bubbles. They originated in chaotic manner in arbitrary points of the heating surface and then after random evolution in form and size collapsed. The agglomerate size reached several millimeters and their duration of life was several milliseconds. After formation of large vapor agglomerates, with a further small increase in heat flux density a burnout of the heating surface occurred. In most cases the same effect took place if the large agglomerates were retained for several minutes.

Adsorptive Water Removal from Dichloromethane and Vapor-Phase Regeneration of a Molecular Sieve 3A Packed Bed

PubMed Central

2017-01-01

The drying of dichloromethane with a molecular sieve 3A packed bed process is modeled and experimentally verified. In the process, the dichloromethane is dried in the liquid phase and the adsorbent is regenerated by water desorption with dried dichloromethane product in the vapor phase. Adsorption equilibrium experiments show that dichloromethane does not compete with water adsorption, because of size exclusion; the pure water vapor isotherm from literature provides an accurate representation of the experiments. The breakthrough curves are adequately described by a mathematical model that includes external mass transfer, pore diffusion, and surface diffusion. During the desorption step, the main heat transfer mechanism is the condensation of the superheated dichloromethane vapor. The regeneration time is shortened significantly by external bed heating. Cyclic steady-state experiments demonstrate the feasibility of this novel, zero-emission drying process. PMID:28539701

Vapor compression heat pump system field tests at the TECH complex

NASA Astrophysics Data System (ADS)

Baxter, V. D.

1985-07-01

The Tennessee Energy Conservation In Housing (TECH) complex has been utilized since 1977 as a field test site for several novel and conventional heat pump systems for space conditioning and water heating. Systems tested include the Annual Cycle Energy System (ACES), solar assisted heat pumps (SAHP) both parallel and series, two conventional air-to-air heat pumps, an air-to-air heat pump with desuperheater water heater, and horizontal coil and multiple shallow vertical coil ground-coupled heat pumps (GCHP). A direct comparison of the measured annual performance of the test systems was not possible. However, a cursory examination revealed that the ACES had the best performance. However, its high cost makes it unlikely that it will achieve widespread use. Costs for the SAHP systems are similar to those of the ACES but their performance is not as good. Integration of water heating and space conditioning functions with a desuperheater yielded significant efficiency improvement at modest cost. The GCHP systems performed much better for heating than for cooling and may well be the most efficient alternative for residences in cold climates.

Vapor compression heat pump system field tests at the tech complex

NASA Astrophysics Data System (ADS)

Baxter, Van D.

1985-11-01

The Tennessee Energy Conservation In Housing (TECH) complex has been utilized since 1977 as a field test site for several novel and conventional heat pump systems for space conditioning and water heating. Systems tested include the Annual Cycle Energy System (ACES), solar assisted heat pumps (SAHP) both parallel and series, two conventional air-to-air heat pumps, an air-to-air heat pump with desuperheater water heater, and horizontal coil and multiple shallow vertical coil ground-coupled heat pumps (GCHP). A direct comparison of the measured annual performance of the test systems was not possible. However, a cursory examination revealed that the ACES had the best performance, however, its high cost makes it unlikely that it will achieve wide-spread use. Costs for the SAHP systems are similar to those of the ACES but their performance is not as good. Integration of water heating and space conditioning functions with a desuperheater yielded significant efficiency improvement at modest cost. The GCHP systems performed much better for heating than for cooling and may well be the most efficient alternative for residences in cold climates.

Transient characteristics of a grooved water heat pipe with variable heat load

NASA Technical Reports Server (NTRS)

Jang, Jong Hoon

1990-01-01

The transient characteristics of a grooved water heat pipe were studied by using variable heat load. First, the effects of the property variations of the working fluid with temperature were investigated by operating the water heat pipe at several different temperatures. The experimental results show that, even for the same heat input profile and heat pipe configuration, the heat pipe transports more heat at higher temperature within the tested temperature range. Adequate liquid return to the evaporator due to decreasing viscosity of the working fluid permits continuous vaporization of water without dry-out. Second, rewetting of the evaporator was studied after the evaporator had experienced dry-out. To rewet the evaporator, the elevation of the condenser end was the most effective way. Without elevating the condenser end, rewetting is not straight-forward even with power turned off unless the heat pipe is kept at isothermal condition for sufficiently long time.

Motion of liquid plugs between vapor bubbles in capillary tubes: a comparison between fluids

NASA Astrophysics Data System (ADS)

Bertossi, Rémi; Ayel, Vincent; Mehta, Balkrishna; Romestant, Cyril; Bertin, Yves; Khandekar, Sameer

2017-11-01

Pulsating heat pipes (PHP) are now well-known devices in which liquid/vapor slug flow oscillates in a capillary tube wound between hot and cold sources. In this context, this paper focuses on the motion of the liquid plug, trapped between vapor bubbles, moving in capillary tubes, to try to better understand the thermo-physical phenomena involved in such devices. This study is divided into three parts. In the first part, an experimental study presents the evolution of the vapor pressure during the evaporation process of a liquid thin film deposited from a liquid plug flowing in a heated capillary tube: it is found that the behavior of the generated and removed vapor can be very different, according to the thermophysical properties of the fluids. In the second part, a transient model allows to compare, in terms of pressure and duration, the motion of a constant-length liquid plug trapped between two bubbles subjected to a constant difference of vapor pressure: the results highlight that the performances of the four fluids are also very different. Finally, a third model that can be considered as an improvement of the second one, is also presented: here, the liquid slug is surrounded by two vapor bubbles, one subjected to evaporation, the pressure in both bubbles is now a result of the calculation. This model still allows comparing the behaviors of the fluid. Even if our models are quite far from a complete model of a real PHP, results do indicate towards the applicability of different fluids as suitable working fluids for PHPs, particularly in terms of the flow instabilities which they generate.

Vaporization of the prototypical ionic liquid BMImNTf₂ under equilibrium conditions: a multitechnique study.

PubMed

Brunetti, Bruno; Ciccioli, Andrea; Gigli, Guido; Lapi, Andrea; Misceo, Nicolaemanuele; Tanzi, Luana; Vecchio Ciprioti, Stefano

2014-08-07

The vaporization behaviour and thermodynamics of the ionic liquid 1-butyl-3-methylimidazolium bis(trifluoromethyl)sulfonylimide (BMImNTf2) were studied by combining the Knudsen Effusion Mass Loss (KEML) and Knudsen Effusion Mass Spectrometry (KEMS) techniques. KEML studies were carried out in a large temperature range (398-567) K by using effusion orifices with 0.3, 1, and 3 mm diameters. The vapor pressures so measured revealed no kinetically hindered vaporization effects and provided second-law vaporization enthalpies at the mean experimental temperatures in close agreement with literature. By exploiting the large temperature range covered, the heat capacity change associated with vaporization was estimated, resulting in a value of -66.8 J K(-1) mol(-1), much lower than that predicted from calorimetric measurements on the liquid phase and theoretical calculations on the gas phase. The conversion of the high temperature vaporization enthalpy to 298 K was discussed and the value Δ(l)(g)H(m)(298 K) = (128.6 ± 1.3) kJ mol(-1) assessed on the basis of data from literature and present work. Vapor pressure data were also processed by the third-law procedure using different estimations for the auxiliary thermal functions, and a Δ(l)(g)H(m)(298 K) consistent with the assessed value was obtained, although the overall agreement is sensitive to the accuracy of heat capacity data. KEMS measurements were carried out in the lower temperature range (393-467) K and showed that the largely prevailing ion species is BMIm(+), supporting the common view of BMImNTf2 vaporizing as individual, neutral ion pairs also under equilibrium conditions. By monitoring the mass spectrometric signal of this ion as a function of temperature, a second-law Δ(l)(g)H(m)(298 K) of 129.4 ± 7.3 kJ mol(-1) was obtained, well consistent with KEML and literature results. Finally, by combining KEML and KEMS measurements, the electron impact ionization cross section of BMIm(+) was estimated.

Computational Simulation of a Water-Cooled Heat Pump

NASA Technical Reports Server (NTRS)

Bozarth, Duane

2008-01-01

A Fortran-language computer program for simulating the operation of a water-cooled vapor-compression heat pump in any orientation with respect to gravity has been developed by modifying a prior general-purpose heat-pump design code used at Oak Ridge National Laboratory (ORNL).

Performance of heated humidifiers with a heated wire according to ventilatory settings.

PubMed

Nishida, T; Nishimura, M; Fujino, Y; Mashimo, T

2001-01-01

Delivering warm, humidified gas to patients is important during mechanical ventilation. Heated humidifiers are effective and popular. The humidifying efficiency is influenced not only by performance and settings of the devices but the settings of ventilator. We compared the efficiency of humidifying devices with a heated wire and servo-controlled function under a variety of ventilator settings. A bench study was done with a TTL model lung. The study took place in the laboratory of the University Hospital, Osaka, Japan. Four devices (MR290 with MR730, MR310 with MR730; both Fisher & Paykel, ConchaTherm IV; Hudson RCI, and HummaxII; METRAN) were tested. Hummax II has been developed recently, and it consists of a heated wire and polyethylene microporous hollow fiber. Both wire and fiber were put inside of an inspiratory circuit, and water vapor is delivered throughout the circuit. The Servo 300 was connected to the TTL with a standard ventilator circuit. The ventilator settings were as follows; minute ventilation (V(E)) 5, 10, and 15 L/min, a respiratory rate of 10 breaths/min, I:E ratio 1:1, 1:2, and 1:4, and no applied PEEP. Humidifying devices were set to maintain the temperature of airway opening at 32 degrees C and 37 degrees C. The greater V(E) the lower the humidity with all devices except Hummax II. Hummax II delivered 100% relative humidity at all ventilator and humidifier settings. When airway temperature control of the devices was set at 32 degrees C, the ConchaTherm IV did not deliver 30 mg/L of vapor, which is the value recommended by American National Standards at all V(E) settings. At 10 and 15 L/min of V(E) settings MR310 with MR730 did not deliver recommended vapor, either. In conclusion, airway temperature setting of the humidifying devices influenced the humidity of inspiratory gas greatly. Ventilatory settings also influenced the humidity of inspiratory gas. The Hummax II delivered sufficient water vapor under a variety of minute ventilation.

Numerical Modeling of Physical Vapor Transport in Contactless Crystal Growth Geometry

NASA Technical Reports Server (NTRS)

Palosz, W.; Lowry, S.; Krishnam, A.; Przekwas, A.; Grasza, K.

1998-01-01

Growth from the vapor under conditions of limited contact with the walls of the growth ampoule is beneficial for the quality of the growing crystal due to reduced stress and contamination which may be caused by interactions with the growth container. The technique may be of a particular interest for studies on crystal growth under microgravity conditions: elimination of some factors affecting the crystal quality may make interpretation of space-conducted processes more conclusive and meaningful. For that reason, and as a part of our continuing studies on 'contactless' growth technique, we have developed a computational model of crystal growth process in such system. The theoretical model was built, and simulations were performed using the commercial computational fluid dynamics code, (CFD) ACE. The code uses an implicit finite volume formulation with a gray discrete ordinate method radiation model which accounts for the diffuse absorption and reflection of radiation throughout the furnace. The three-dimensional model computes the heat transfer through the crystal, quartz, and gas both inside and outside the ampoule, and mass transport from the source to the crystal and the sink. The heat transport mechanisms by conduction, natural convection, and radiation, and mass transport by diffusion and convection are modeled simultaneously and include the heat of the phase transition at the solid-vapor interfaces. As the thermal boundary condition, temperature profile along the walls of the furnace is used. For different thermal profiles and furnace and ampoule dimensions, the crystal growth rate and development of the crystal-vapor and source-vapor interfaces (change of the interface shape and location with time) are obtained. Super/under-saturation in the ampoule is determined and critical factors determining the 'contactless' growth conditions are identified and discussed. The relative importance of the ampoule dimensions and geometry, the furnace dimensions and its

Situ soil sampling probe system with heated transfer line

DOEpatents

Robbat, Jr., Albert

2002-01-01

The present invention is directed both to an improved in situ penetrometer probe and to a heated, flexible transfer line. The line and probe may be implemented together in a penetrometer system in which the transfer line is used to connect the probe to a collector/analyzer at the surface. The probe comprises a heater that controls a temperature of a geologic medium surrounding the probe. At least one carrier gas port and vapor collection port are located on an external side wall of the probe. The carrier gas port provides a carrier gas into the geologic medium, and the collection port captures vapors from the geologic medium for analysis. In the transfer line, a flexible collection line that conveys a collected fluid, i.e., vapor, sample to a collector/analyzer. A flexible carrier gas line conveys a carrier gas to facilitate the collection of the sample. A system heating the collection line is also provided. Preferably the collection line is electrically conductive so that an electrical power source can generate a current through it so that the internal resistance generates heat.

Loop Heat Pipe Temperature Oscillation Induced by Gravity Assist and Reservoir Heating

NASA Technical Reports Server (NTRS)

Ku, Jentung; Garrison, Matthew; Patel, Deepak; Robinson, Franklin; Ottenstein, Laura

2015-01-01

The Laser Thermal Control System (LCTS) for the Advanced Topographic Laser Altimeter System (ATLAS) to be installed on NASA's Ice, Cloud, and Land Elevation Satellite (ICESat-2) consists of a constant conductance heat pipe and a loop heat pipe (LHP) with an associated radiator. During the recent thermal vacuum testing of the LTCS where the LHP condenser/radiator was placed in a vertical position above the evaporator and reservoir, it was found that the LHP reservoir control heater power requirement was much higher than the analytical model had predicted. Even with the control heater turned on continuously at its full power, the reservoir could not be maintained at its desired set point temperature. An investigation of the LHP behaviors found that the root cause of the problem was fluid flow and reservoir temperature oscillations, which led to persistent alternate forward and reversed flow along the liquid line and an imbalance between the vapor mass flow rate in the vapor line and liquid mass flow rate in the liquid line. The flow and temperature oscillations were caused by an interaction between gravity and reservoir heating, and were exacerbated by the large thermal mass of the instrument simulator which modulated the net heat load to the evaporator, and the vertical radiator/condenser which induced a variable gravitational pressure head. Furthermore, causes and effects of the contributing factors to flow and temperature oscillations intermingled.

Superfluid helium 2 liquid-vapor phase separation: Technology assessment

NASA Technical Reports Server (NTRS)

Lee, J. M.

1984-01-01

A literature survey of helium 2 liquid vapor phase separation is presented. Currently, two types of He 2 phase separators are being investigated: porous, sintered metal plugs and the active phase separator. The permeability K(P) shows consistency in porous plug geometric characterization. Both the heat and mass fluxes increase with K(P). Downstream pressure regulation to adjust for varying heat loads and both temperatures is possible. For large dynamic heat loads, the active phase separator shows a maximum heat rejection rate of up to 2 W and bath temperature stability of 0.1 mK. Porous plug phase separation performance should be investigated for application to SIRTF and, in particular, that plugs of from 10 to the minus ninth square centimeters to 10 to the minus eighth square centimeters in conjunction with downstream pressure regulation be studied.

Theory of supercompression of vapor bubbles and nanoscale thermonuclear fusion

NASA Astrophysics Data System (ADS)

Nigmatulin, Robert I.; Akhatov, Iskander Sh.; Topolnikov, Andrey S.; Bolotnova, Raisa Kh.; Vakhitova, Nailya K.; Lahey, Richard T.; Taleyarkhan, Rusi P.

2005-10-01

This paper provides the theoretical basis for energetic vapor bubble implosions induced by a standing acoustic wave. Its primary goal is to describe, explain, and demonstrate the plausibility of the experimental observations by Taleyarkhan et al. [Science 295, 1868 (2002); Phys. Rev. E 69, 036109 (2004)] of thermonuclear fusion for imploding cavitation bubbles in chilled deuterated acetone. A detailed description and analysis of these data, including a resolution of the criticisms that have been raised, together with some preliminary HYDRO code simulations, has been given by Nigmatulin et al. [Vestnik ANRB (Ufa, Russia) 4, 3 (2002); J. Power Energy 218-A, 345 (2004)] and Lahey et al. [Adv. Heat Transfer (to be published)]. In this paper a hydrodynamic shock (i.e., HYDRO) code model of the spherically symmetric motion for a vapor bubble in an acoustically forced liquid is presented. This model describes cavitation bubble cluster growth during the expansion period, followed by a violent implosion during the compression period of the acoustic cycle. There are two stages of the bubble dynamics process. The first, low Mach number stage, comprises almost all the time of the acoustic cycle. During this stage, the radial velocities are much less than the sound speeds in the vapor and liquid, the vapor pressure is very close to uniform, and the liquid is practically incompressible. This process is characterized by the inertia of the liquid, heat conduction, and the evaporation or condensation of the vapor. The second, very short, high Mach number stage is when the radial velocities are the same order, or higher, than the sound speeds in the vapor and liquid. In this stage high temperatures, pressures, and densities of the vapor and liquid take place. The model presented herein has realistic equations of state for the compressible liquid and vapor phases, and accounts for nonequilibrium evaporation/condensation kinetics at the liquid/vapor interface. There are interacting

Heat and Mass Transfer of Ammonia Gas Absorption into Falling Liquid Film on a Horizontal Tube

NASA Astrophysics Data System (ADS)

Inoue, Norihiro; Yabuuchi, Hironori; Goto, Masao; Koyama, Shigeru

Heat and mass transfer coefficients during ammonia gas absorption into a falling liquid film formed by distilled water on a horizontal tube were obtained experimentally. The test absorber consists of 200 mm i.d., 600 mm long stainless steel shell, a 1 7.3 mm o.d., 14.9 mm i.d. stainless steel test tube with 600 mm working length mounted along the axis of shell, and a 12.7 mm o.d. pipe manifold of supplying the absorbent. In this paper, it was clear that heat and mass transfer coefficient could be enhanced by increasing the flow rate of absorbent and temperature difference between inlet absorbent and ammonia gas, also heat driven by the temperature difference have an effect on heat transfer of the fa1ling liquid film and mass transfer of vapor side. And the new correlation of heat transfer in dimensionless form was proposed by the temperature difference which was considered heat driven of vapor and liquid film side using a interface temperature of vapor and liquid phase. The new correlations of mass transfer on a interface of vapor and liquid phase in dimensionless form were proposed by using effect factors could be suppose from absorption phenomena.

Critical heat flux in subcooled flow boiling

NASA Astrophysics Data System (ADS)

Hall, David Douglas

The critical heat flux (CHF) phenomenon was investigated for water flow in tubes with particular emphasis on the development of methods for predicting CHF in the subcooled flow boiling regime. The Purdue University Boiling and Two-Phase Flow Laboratory (PU-BTPFL) CHF database for water flow in a uniformly heated tube was compiled from the world literature dating back to 1949 and represents the largest CHF database ever assembled with 32,544 data points from over 100 sources. The superiority of this database was proven via a detailed examination of previous databases. The PU-BTPFL CHF database is an invaluable tool for the development of CHF correlations and mechanistic models that are superior to existing ones developed with smaller, less comprehensive CHF databases. In response to the many inaccurate and inordinately complex correlations, two nondimensional, subcooled CHF correlations were formulated, containing only five adjustable constants and whose unique functional forms were determined without using a statistical analysis but rather using the parametric trends observed in less than 10% of the subcooled CHF data. The correlation based on inlet conditions (diameter, heated length, mass velocity, pressure, inlet quality) was by far the most accurate of all known subcooled CHF correlations, having mean absolute and root-mean-square (RMS) errors of 10.3% and 14.3%, respectively. The outlet (local) conditions correlation was the most accurate correlation based on local CHF conditions (diameter, mass velocity, pressure, outlet quality) and may be used with a nonuniform axial heat flux. Both correlations proved more accurate than a recent CHF look-up table commonly employed in nuclear reactor thermal hydraulic computer codes. An interfacial lift-off, subcooled CHF model was developed from a consideration of the instability of the vapor-liquid interface and the fraction of heat required for liquid-vapor conversion as opposed to that for bulk liquid heating. Severe

Investigation of local evaporation flux and vapor-phase pressure at an evaporative droplet interface.

PubMed

Duan, Fei; Ward, C A

2009-07-07

In the steady-state experiments of water droplet evaporation, when the throat was heating at a stainless steel conical funnel, the interfacial liquid temperature was found to increase parabolically from the center line to the rim of the funnel with the global vapor-phase pressure at around 600 Pa. The energy conservation analysis at the interface indicates that the energy required for evaporation is maintained by thermal conduction to the interface from the liquid and vapor phases, thermocapillary convection at interface, and the viscous dissipation globally and locally. The local evaporation flux increases from the center line to the periphery as a result of multiple effects of energy transport at the interface. The local vapor-phase pressure predicted from statistical rate theory (SRT) is also found to increase monotonically toward the interface edge from the center line. However, the average value of the local vapor-phase pressures is in agreement with the measured global vapor-phase pressure within the measured error bar.

Scalable graphene coatings for enhanced condensation heat transfer.

PubMed

Preston, Daniel J; Mafra, Daniela L; Miljkovic, Nenad; Kong, Jing; Wang, Evelyn N

2015-05-13

Water vapor condensation is commonly observed in nature and routinely used as an effective means of transferring heat with dropwise condensation on nonwetting surfaces exhibiting heat transfer improvement compared to filmwise condensation on wetting surfaces. However, state-of-the-art techniques to promote dropwise condensation rely on functional hydrophobic coatings that either have challenges with chemical stability or are so thick that any potential heat transfer improvement is negated due to the added thermal resistance of the coating. In this work, we show the effectiveness of ultrathin scalable chemical vapor deposited (CVD) graphene coatings to promote dropwise condensation while offering robust chemical stability and maintaining low thermal resistance. Heat transfer enhancements of 4× were demonstrated compared to filmwise condensation, and the robustness of these CVD coatings was superior to typical hydrophobic monolayer coatings. Our results indicate that graphene is a promising surface coating to promote dropwise condensation of water in industrial conditions with the potential for scalable application via CVD.

An approximate analysis of the diffusing flow in a self-controlled heat pipe.

NASA Technical Reports Server (NTRS)

Somogyi, D.; Yen, H. H.

1973-01-01

Constant-density two-dimensional axisymmetric equations are presented for the diffusing flow of a class of self-controlled heat pipes. The analysis is restricted to the vapor space. Condensation of the vapor is related to its mass fraction at the wall by the gas kinetic formula. The Karman-Pohlhausen integral method is applied to obtain approximate solutions. Solutions are presented for a water heat pipe with neon control gas.

A high performance cocurrent-flow heat pipe for heat recovery applications

NASA Technical Reports Server (NTRS)

Saaski, E. W.; Hartl, J. C.

1980-01-01

By the introduction of a plate-and-tube separator assembly into a heat pipe vapor core, it has been demonstrated that axial transport capacity in reflux mode can be improved by up to a factor of 10. This improvement is largely the result of eliminating the countercurrent shear that commonly limits reflux heat pipe axial capacity. With benzene, axial heat fluxes up to 1800 W/sq cm were obtained in the temperature range 40 to 80 C, while heat flux densities up to 3000 W/sq cm were obtained with R-11 over the temperature range 40 to 80 C. These very high axial capacities compare favorably with liquid metal limits; the sonic limit for liquid sodium, for example, is 3000 W/sq cm at 657 C. Computational models developed for these cocurrent flow heat pipes agreed with experimental data within + or - 25%.

Film Condensation with and Without Body Force in Boundary-Layer Flow of Vapor Over a Flat Plate

NASA Technical Reports Server (NTRS)

Chung, Paul M.

1961-01-01

Laminar film condensation under the simultaneous influence of gas-liquid interface shear and body force (g force) is analyzed over a flat plate. Important parameters governing condensation and heat transfer of pure vapor are determined. Mixtures of condensable vapor and noncondensable gas are also analyzed. The conditions under which the body force has a significant influence on condensation are determined.

Explosive Boiling at Very Low Heat Fluxes: A Microgravity Phenomenon

NASA Technical Reports Server (NTRS)

Hasan, M. M.; Lin, C. S.; Knoll, R. H.; Bentz, M. D.

1993-01-01

The paper presents experimental observations of explosive boiling from a large (relative to bubble sizes) flat heating surface at very low heat fluxes in microgravity. The explosive boiling is characterized as either a rapid growth of vapor mass over the entire heating surface due to the flashing of superheated liquid or a violent boiling spread following the appearance of single bubbles on the heating surface. Pool boiling data with saturated Freon 113 was obtained in the microgravity environment of the space shuttle. The unique features of the experimental results are the sustainability of high liquid superheat for long periods and the occurrence of explosive boiling at low heat fluxes (0.2 to 1.2 kW/sq m). For a heat flux of 1.0 kW/sq m a wall superheat of 17.9 degrees C was attained in ten minutes of heating. This was followed by an explosive boiling accompanied with a pressure spike and a violent bulk liquid motion. However, at this heat flux the vapor blanketing the heating surface could not be sustained. Stable nucleate boiling continued following the explosive boiling.

Development of a Computational Chemical Vapor Deposition Model: Applications to Indium Nitride and Dicyanovinylaniline

NASA Technical Reports Server (NTRS)

Cardelino, Carlos

1999-01-01

A computational chemical vapor deposition (CVD) model is presented, that couples chemical reaction mechanisms with fluid dynamic simulations for vapor deposition experiments. The chemical properties of the systems under investigation are evaluated using quantum, molecular and statistical mechanics models. The fluid dynamic computations are performed using the CFD-ACE program, which can simulate multispecies transport, heat and mass transfer, gas phase chemistry, chemistry of adsorbed species, pulsed reactant flow and variable gravity conditions. Two experimental setups are being studied, in order to fabricate films of: (a) indium nitride (InN) from the gas or surface phase reaction of trimethylindium and ammonia; and (b) 4-(1,1)dicyanovinyl-dimethylaminoaniline (DCVA) by vapor deposition. Modeling of these setups requires knowledge of three groups of properties: thermodynamic properties (heat capacity), transport properties (diffusion, viscosity, and thermal conductivity), and kinetic properties (rate constants for all possible elementary chemical reactions). These properties are evaluated using computational methods whenever experimental data is not available for the species or for the elementary reactions. The chemical vapor deposition model is applied to InN and DCVA. Several possible InN mechanisms are proposed and analyzed. The CVD model simulations of InN show that the deposition rate of InN is more efficient when pulsing chemistry is used under conditions of high pressure and microgravity. An analysis of the chemical properties of DCVA show that DCVA dimers may form under certain conditions of physical vapor transport. CVD simulations of the DCVA system suggest that deposition of the DCVA dimer may play a small role in the film and crystal growth processes.

Enthalpy and high temperature relaxation kinetics of stable vapor-deposited glasses of toluene

DOE Office of Scientific and Technical Information (OSTI.GOV)

Bhattacharya, Deepanjan; Sadtchenko, Vlad, E-mail: vlad@gwu.edu

Stable non-crystalline toluene films of micrometer and nanometer thicknesses were grown by vapor deposition at distinct rates and probed by fast scanning calorimetry. Fast scanning calorimetry is shown to be extremely sensitive to the structure of the vapor-deposited phase and was used to characterize simultaneously its kinetic stability and its thermodynamic properties. According to our analysis, transformation of vapor-deposited samples of toluene during heating with rates in excess 10{sup 5} K s{sup −1} follows the zero-order kinetics. The transformation rate correlates strongly with the initial enthalpy of the sample, which increases with the deposition rate according to sub-linear law. Analysismore » of the transformation kinetics of vapor-deposited toluene films of various thicknesses reveal a sudden increase in the transformation rate for films thinner than 250 nm. The change in kinetics seems to correlate with the surface roughness scale of the substrate. The implications of these findings for the formation mechanism and structure of vapor-deposited stable glasses are discussed.« less

Gas-evaporation in low-gravity field (cogelation mechanism of metal vapors) (M-14)

NASA Technical Reports Server (NTRS)

Wada, N.

1993-01-01

When metal and alloy compounds are heated and vaporized in a rare gas such as helium, argon, or xenon, the vaporized substances diffused in the rare gas are supersaturated resulting in a smoke of fine particles of the material congealing as snow or fog. The gas vaporizing method is a fine particle generation method. Though the method has a variety of applications, the material vapor flow is disturbed by gravitational convection on Earth. The inability to elucidate the fine particle generation mechanism results in an obstruction to improving the method to mass production levels. As no convection occurs in microgravity in space, the fine particle generation mechanism influenced only by diffusion can be investigated. Investigators expect that excellent particles with homogeneous diameter distribution can be obtained. Experiment data and facts will assist in improving efficiency, quality, and scale or production processes including element processes such as vaporization, diffusion, and condensation. The objective of this experiment is to obtain important information related to the mechanism of particle formation in the gas atmosphere (smoke particles) and the production of submicron powders of extremely uniform size.

A Study of the Constrained Vapor Bubble Thermosyphon

NASA Technical Reports Server (NTRS)

Wayner, Peter C., Jr.; Plawsky, J. L.

2000-01-01

The objective of this effort is to better understand the physics of evaporation, condensation, and fluid flow as they affect the heat transfer processes in a constrained vapor bubble heat exchanger (CVBHX). This CVBHX consists of a small enclosed container with a square cross section (inside dimensions. 3 x 3 x 40 mm) partially filled with a liquid. The major portion of the liquid is in the corners, which act as arteries. When a temperature difference is applied to the ends of the CVBHX, evaporation occurs at the hot end and condensation at the cold end resulting in a very effective heat transfer device with great potential in space applications. Liquid is returned by capillary flow in the corners. A complete description of the system and the results obtained to date are given in the papers listed.

Influence of different heating types on the pumping performance of a bubble pump

NASA Astrophysics Data System (ADS)

Bierling, Bernd; Schmid, Fabian; Spindler, Klaus

2017-11-01

This study presents an experimental investigation of the influence of different heating types on the pumping performance of a bubble pump. A test rig was set up at the Institute of Thermodynamics and Thermal Engineering (ITW), University of Stuttgart. The vertical lift tube is made of copper with an inner diameter of 8 mm and a length of 1.91 m. The working fluid is demineralized water. The test rig offers the possibility to vary the supplied heat flow (0 W - 750 W), the resulting supplied heat flux and the location of the heating. Investigations were carried out using spot heating, partial-length heating and full-length heating. A Coriolis mass flowmeter was successfully implemented which measures the vapor mass flow rate continuously. The improvement of the vapor mass flow rate measurement by using the continuous measurement method compared to a discontinuous one is discussed. Furthermore, the influence of an unstable inlet temperature of the working fluid entering the lift tube on the pumping performance is investigated. The focus of this publication lies on the build-up of the test rig with the measurement setup and the analysis of the pumping performance for the three heating types. The measurement results show a big influence of the heating type on the pumping performance. The lower the relative length of the heating, the higher is the pumping ratio which is defined as the lifted liquid mass flow rate in relation to the generated vapor mass flow rate.

Vapor-Liquid-Solid Etch of Semiconductor Surface Channels by Running Gold Nanodroplets.

PubMed

Nikoobakht, Babak; Herzing, Andrew; Muramoto, Shin; Tersoff, Jerry

2015-12-09

We show that Au nanoparticles spontaneously move across the (001) surface of InP, InAs, and GaP when heated in the presence of water vapor. As they move, the particles etch crystallographically aligned grooves into the surface. We show that this process is a negative analogue of the vapor-liquid-solid (VLS) growth of semiconductor nanowires: the semiconductor dissolves into the catalyst and reacts with water vapor at the catalyst surface to create volatile oxides, depleting the dissolved cations and anions and thus sustaining the dissolution process. This VLS etching process provides a new tool for directed assembly of structures with sublithographic dimensions, as small as a few nanometers in diameter. Au particles above 100 nm in size do not exhibit this process but remain stationary, with oxide accumulating around the particles.

New configurations of a heat recovery absorption heat pump integrated with a natural gas boiler for boiler efficiency improvement

DOE Office of Scientific and Technical Information (OSTI.GOV)

Qu, Ming; Abdelaziz, Omar; Yin, Hongxi

2014-11-01

Conventional natural gas-fired boilers exhaust flue gas direct to the atmosphere at 150 200 C, which, at such temperatures, contains large amount of energy and results in relatively low thermal efficiency ranging from 70% to 80%. Although condensing boilers for recovering the heat in the flue gas have been developed over the past 40 years, their present market share is still less than 25%. The major reason for this relatively slow acceptance is the limited improvement in the thermal efficiency of condensing boilers. In the condensing boiler, the temperature of the hot water return at the range of 50 60more » C, which is used to cool the flue gas, is very close to the dew point of the water vapor in the flue gas. Therefore, the latent heat, the majority of the waste heat in the flue gas, which is contained in the water vapor, cannot be recovered. This paper presents a new approach to improve boiler thermal efficiency by integrating absorption heat pumps with natural gas boilers for waste heat recovery (HRAHP). Three configurations of HRAHPs are introduced and discussed. The three configurations are modeled in detail to illustrate the significant thermal efficiency improvement they attain. Further, for conceptual proof and validation, an existing hot water-driven absorption chiller is operated as a heat pump at operating conditions similar to one of the devised configurations. An overall system performance and economic analysis are provided for decision-making and as evidence of the potential benefits. These three configurations of HRAHP provide a pathway to achieving realistic high-efficiency natural gas boilers for applications with process fluid return temperatures higher than or close to the dew point of the water vapor in the flue gas.« less

HPTAM, a two-dimensional Heat Pipe Transient Analysis Model, including the startup from a frozen state

NASA Technical Reports Server (NTRS)

Tournier, Jean-Michel; El-Genk, Mohamed S.

1995-01-01

A two-dimensional Heat Pipe Transient Analysis Model, 'HPTAM,' was developed to simulate the transient operation of fully-thawed heat pipes and the startup of heat pipes from a frozen state. The model incorporates: (a) sublimation and resolidification of working fluid; (b) melting and freezing of the working fluid in the porous wick; (c) evaporation of thawed working fluid and condensation as a thin liquid film on a frozen substrate; (d) free-molecule, transition, and continuum vapor flow regimes, using the Dusty Gas Model; (e) liquid flow and heat transfer in the porous wick; and (f) thermal and hydrodynamic couplings of phases at their respective interfaces. HPTAM predicts the radius of curvature of the liquid meniscus at the liquid-vapor interface and the radial location of the working fluid level (liquid or solid) in the wick. It also includes the transverse momentum jump condition (capillary relationship of Pascal) at the liquid-vapor interface and geometrically relates the radius of curvature of the liquid meniscus to the volume fraction of vapor in the wick. The present model predicts the capillary limit and partial liquid recess (dryout) in the evaporator wick, and incorporates a liquid pooling submodel, which simulates accumulation of the excess liquid in the vapor core at the condenser end.

Studies of material and process compatibility in developing compact silicon vapor chambers

NASA Astrophysics Data System (ADS)

Cai, Qingjun; Bhunia, Avijit; Tsai, Chialun; Kendig, Martin W.; DeNatale, Jeffrey F.

2013-06-01

The performance and long-term reliability of a silicon vapor chamber (SVC) developed for thermal management of high-power electronics critically depend on compatibility of the component materials. A hermetically sealed SVC presented in this paper is composed of bulk silicon, glass-frit as a bonding agent, lead/tin solder as an interface sealant and a copper charging tube. These materials, in the presence of a water/vapor environment, may chemically react and release noncondensable gas (NCG), which can weaken structural strength and degrade the heat transfer performance with time. The present work reports detailed studies on chemical compatibility of the components and potential solutions to avoid the resulting thermal performance degradation. Silicon surface oxidation and purification of operating liquid are necessary steps to reduce performance degradation in the transient period. A lead-based solder with its low reflow temperature is found to be electrochemically stable in water/vapor environment. High glazing temperature solidifies molecular bonding in glass-frit and mitigates PbO precipitation. Numerous liquid flushes guarantee removal of chemical residual after the charging tube is soldered to SVC. With these improvements on the SVC material and process compatibility, high effective thermal conductivity and steady heat transfer performance are obtained.

Design and Operation of a Cryogenic Nitrogen Pulsating Heat Pipe

NASA Astrophysics Data System (ADS)

Diego Fonseca, Luis; Miller, Franklin; Pfotenhauer, John

2015-12-01

We report the design, experimental setup and successful test results using an innovative passive cooling system called a “Pulsating Heat Pipe” (PHP) operating at temperatures ranging from 77 K to 80 K and using nitrogen as the working fluid. PHPs, which transfer heat by two phase flow mechanisms through a closed loop tubing have the advantage that no electrical pumps are needed to drive the fluid flow. In addition, PHPs have an advantage over copper straps and thermal conductors since they are lighter in weight, exhibit lower temperature gradients and have higher heat transfer rates. PHPs consist of an evaporator section, thermally anchored to a solid, where heat is received at the saturation temperature where the liquid portion of the two-phase flow evaporates, and a condenser where heat is rejected at the saturation temperature where the vapor is condensed. The condenser section in our experiment has been thermally interfaced to a CT cryocooler from SunPower that has a cooling capacity of 10 W at 77 K. Alternating regions of liquid slugs and small vapor plugs fill the capillary tubing, with the vapor regions contracting in the condenser section and expanding in the evaporator section due to an electric heater that will generate heat loads up to 10 W. This volumetric expansion and contraction provides the oscillatory flow of the fluid throughout the capillary tubing thereby transferring heat from one end to the other. The thermal performance and temperature characteristics of the PHP will be correlated as a function of average condenser temperature, PHP fill liquid ratio, and evaporator heat load. The experimental data show that the heat transfer between the evaporator and condenser sections can produce an effective thermal conductivity up to 35000 W/m-K at a 3.5 W heat load.

Liquid over-feeding refrigeration system and method with integrated accumulator-expander-heat exchanger

DOEpatents

Mei, Viung C.; Chen, Fang C.

1997-01-01

A refrigeration system having a vapor compression cycle utilizing a liquid over-feeding operation with an integrated accumulator-expander-heat exchanger. Hot, high-pressure liquid refrigerant from the condenser passes through one or more lengths of capillary tubing substantially immersed in a pool liquid refrigerant in the accumulator-expander-heat exchanger for simultaneously sub-cooling and expanding the liquid refrigerant while vaporizing liquid refrigerant from the pool for the return thereof to the compressor as saturated vapor. The sub-cooling of the expanded liquid provides for the flow of liquid refrigerant into the evaporator for liquid over-feeding the evaporator and thereby increasing the efficiency of the evaporation cycle.

Causes of Potential Urban Heat Island Space Using Heat flux Budget Under Urban Canopy

NASA Astrophysics Data System (ADS)

Kwon, Y. J.; Lee, D. K.

2017-12-01

Raised concerns about possible contribution from urban heat island to global warming is about 30 percent. Therefore, mitigating urban heat island became one of major issues to solve among urban planners, urban designers, landscape architects, urban affair decision makers and etc. Urban heat island effect on a micro-scale is influenced by factors such as wind, water vapor and solar radiation. Urban heat island effect on a microscale is influenced by factors like wind, water vapor and solar radiation. These microscopic climates are also altered by factors affecting the heat content in space, like SVF and aspect ratio depending on the structural characteristics of various urban canyon components. Indicators of heat mitigation in urban design stage allows us to create a spatial structure considering the heat balance budget. The spatial characteristics affect thermal change by varying heat storage, emitting or absorbing the heat. The research defines characteristics of the space composed of the factors affecting the heat flux change as the potential urban heat island space. Potential urban heat island spaces are that having higher heat flux than periphery space. The study is to know the spatial characteristics that affects the subsequent temperature rise by the heat flux. As a research method, four types of potential heat island space regions were analyzed. I categorized the spatial types by comparing parameters' value of energy balance in day and night: 1) day severe areas, 2) day comfort areas, 3) night severe areas, 4) night comfort areas. I have looked at these four types of potential urban heat island areas from a microscopic perspective and investigated how various forms of heat influences on higher heat flux areas. This research was designed to investigate the heat indicators to be reflected in the design of urban canyon for heat mitigation. As a result, severe areas in daytime have high SVF rate, sensible heat is generated. Day comfort areas have shadow effect

Hydrogeologic controls on saturation profiles in heat-pipe-like hydrothermal systems: numerical study

NASA Astrophysics Data System (ADS)

Pervin, Mollika; Ghergut, Iulia; Graf, Thomas; Peche, Aaron

2016-04-01

Most geothermal reservoirs are of the liquid-dominated type, and their unexploited-state pressure profile approximately follows the hydrostatic gradient. In very hot liquid-dominated systems, temperature typically follows a boiling-point-for-depth (BPD) relationship. By contrast, vapor-dominated systems exhibit (in their unexploited state) surprisingly small vertical gradients of temperature and pressure, such that a constantly high temperature is encountered over a large vertical thickness, while their pressure approximately follows vapour pressure, pvap(T°). This implies that (Pruess 1985, Truesdell and White 1973): (i) for a vapor-dominated reservoir to exist, it must be sealed laterally - otherwise it would be flooded by neighboring groundwaters with hydrostatic p profile, and (ii) liquid water should somehow be present in the whole system - otherwise p values would not be constrained by the pvap(T°) relationship for water. Historically, one of the most puzzling aspects of vapor-dominated systems was the large amount of heat flowing upwards, while vertical T° gradients remained negligible. This mechanism was deemed as 'heat pipe'(HP) (Eastman 1968): In the central zone of a vapor-dominated system, both vapor and liquid are mobile; vapor flows upwards, condenses at shallower depth, and the liquid condensate flows downwards. Due to the large amount of latent enthalpy released in vapor condensation, the vapor-liquid counter-flow can generate large rates of heat flow with negligible net mass transport (Pruess 1985). In order to be able to exploit two-phase (including vapor-dominated) reservoirs in a sustainable manner, one first needs to understand the conditions under which a two-phase (or a vapor-dominated) system has evolved naturally, and which have led to its present (quasi-) steady undisturbed state. Past studies have found that HP can exist in two distinct states, corresponding to liquid-dominated and vapor-dominated p profiles, respectively. Within this

Plasma-Powder Feedstock Interaction During Plasma Spray-Physical Vapor Deposition

NASA Astrophysics Data System (ADS)

Anwaar, Aleem; Wei, Lianglinag; Guo, Hongbo; Zhang, Baopeng

2017-02-01

Plasma spray-physical vapor deposition is a new process developed to produce coatings from the vapor phase. To achieve deposition from the vapor phase, the plasma-feedstock interaction inside the plasma torch, i.e., from the powder injection point to the nozzle exit, is critical. In this work, the plasma characteristics and the momentum and heat transfer between the plasma and powder feedstock at different torch input power levels were investigated theoretically to optimize the net plasma torch power, among other important factors such as the plasma gas composition, powder feed rate, and carrier gas. The plasma characteristics were calculated using the CEA2 code, and the plasma-feedstock interaction was studied inside the torch nozzle at low-pressure (20-25 kPa) conditions. A particle dynamics model was introduced to compute the particle velocity, coupled with Xi Chen's drag model for nonevaporating particles. The results show that the energy transferred to the particles and the coating morphology are greatly influenced by the plasma gas characteristics and the particle dynamics inside the nozzle. The heat transfer between the plasma gas and feedstock material increased with the net torch power up to an optimum at 64 kW, at which a maximum of 3.4% of the available plasma energy was absorbed by the feedstock powder. Experimental results using agglomerated 7-8 wt.% yttria-stabilized zirconia (YSZ) powder as feedstock material confirmed the theoretical predictions.

Hurricanes as Heat Engines: Two Undergraduate Problems

ERIC Educational Resources Information Center

Pyykko, Pekka

2007-01-01

Hurricanes can be regarded as Carnot heat engines. One reason that they can be so violent is that thermodynamically, they demonstrate large efficiency, [epsilon] = (T[subscript h] - T[subscript c]) / T[subscript h], which is of the order of 0.3. Evaporation of water vapor from the ocean and its subsequent condensation is the main heat transfer…

Enthalpy of Vaporization and Vapor Pressures: An Inexpensive Apparatus

ERIC Educational Resources Information Center

Battino, Rubin; Dolson, David A.; Hall, Michael A.; Letcher, Trevor M.

2007-01-01

A simple and inexpensive method to determine the enthalpy of vaporization of liquids by measuring vapor pressure as a function of temperature is described. The vapor pressures measured with the stopcock cell were higher than the literature values and those measured with the sidearm rubber septum cell were both higher and lower than literature…

Steady State Vapor Bubble in Pool Boiling

PubMed Central

Zou, An; Chanana, Ashish; Agrawal, Amit; Wayner, Peter C.; Maroo, Shalabh C.

2016-01-01

Boiling, a dynamic and multiscale process, has been studied for several decades; however, a comprehensive understanding of the process is still lacking. The bubble ebullition cycle, which occurs over millisecond time-span, makes it extremely challenging to study near-surface interfacial characteristics of a single bubble. Here, we create a steady-state vapor bubble that can remain stable for hours in a pool of sub-cooled water using a femtosecond laser source. The stability of the bubble allows us to measure the contact-angle and perform in-situ imaging of the contact-line region and the microlayer, on hydrophilic and hydrophobic surfaces and in both degassed and regular (with dissolved air) water. The early growth stage of vapor bubble in degassed water shows a completely wetted bubble base with the microlayer, and the bubble does not depart from the surface due to reduced liquid pressure in the microlayer. Using experimental data and numerical simulations, we obtain permissible range of maximum heat transfer coefficient possible in nucleate boiling and the width of the evaporating layer in the contact-line region. This technique of creating and measuring fundamental characteristics of a stable vapor bubble will facilitate rational design of nanostructures for boiling enhancement and advance thermal management in electronics. PMID:26837464

Equilibrium temperature in a clump of bacteria heated in fluid.

PubMed Central

Davey, K R

1990-01-01

A theoretical model was developed and used to estimate quantitatively the "worst case", i.e., the longest, time to reach equilibrium temperature in the center of a clump of bacteria heated in fluid. For clumps with 10 to 10(6) cells heated in vapor, such as dry and moist air, and liquid fluids such as purees and juices, predictions show that temperature equilibrium will occur with sterilization temperatures up to 130 degrees C in under 0.02 s. Model development highlighted that the controlling influence on time for heating up the clump is the surface convection thermal resistance and that the internal conduction resistance of the clump mass is negligible by comparison. The time for a clump to reach equilibrium sterilization temperature was therefore decreased with relative turbulence (velocity) of the heating fluid, such as occurs in many process operations. These results confirm widely held suppositions that the heat-up time of bacteria in vapor or liquid is not significant with usual sterilization times. PMID:2306095

Vapor spill pipe monitor

DOEpatents

Bianchini, G.M.; McRae, T.G.

1983-06-23

The invention is a method and apparatus for continually monitoring the composition of liquefied natural gas flowing from a spill pipe during a spill test by continually removing a sample of the LNG by means of a probe, gasifying the LNG in the probe, and sending the vaporized LNG to a remote ir gas detector for analysis. The probe comprises three spaced concentric tubes surrounded by a water jacket which communicates with a flow channel defined between the inner and middle, and middle and outer tubes. The inner tube is connected to a pump for providing suction, and the probe is positioned in the LNG flow below the spill pipe with the tip oriented partly downward so that LNG is continuously drawn into the inner tube through a small orifice. The probe is made of a high thermal conductivity metal. Hot water is flowed through the water jacket and through the flow channel between the three tubes to provide the necessary heat transfer to flash vaporize the LNG passing through the inner channel of the probe. The gasified LNG is transported through a connected hose or tubing extending from the probe to a remote ir sensor which measures the gas composition.

Representative shuttle evaporative heat sink

NASA Technical Reports Server (NTRS)

Hixon, C. W.

1978-01-01

The design, fabrication, and testing of a representative shuttle evaporative heat sink (RSEHS) system which vaporizes an expendable fluid to provide cooling for the shuttle heat transport fluid loop is reported. The optimized RSEHS minimum weight design meets or exceeds the shuttle flash evaporator system requirements. A cold trap which cryo-pumps flash evaporator exhaust water from the CSD vacuum chamber test facility to prevent water contamination of the chamber pumping equipment is also described.

Theoretical analysis for condensation heat transfer of binary refrigerant mixtures with annular flow in horizontal mini-tubes

NASA Astrophysics Data System (ADS)

Zhang, Hui-Yong; Li, Jun-Ming; Sun, Ji-Liang; Wang, Bu-Xuan

2016-01-01

A theoretical model is developed for condensation heat transfer of binary refrigerant mixtures in mini-tubes with diameter about 1.0 mm. Condensation heat transfer of R410A and R32/R134a mixtures at different mass fluxes and saturated temperatures are analyzed, assuming that the phase flow pattern is annular flow. The results indicate that there exists a maximum interface temperature at the beginning of condensation process for azeotropic and zeotropic mixtures and the corresponding vapor quality to the maximum value increases with mass flux. The effects of mass flux, heat flux, surface tension and tube diameter are analyzed. As expected, the condensation heat transfer coefficients increase with mass flux and vapor quality, and increase faster in high vapor quality region. It is found that the effects of heat flux and surface tension are not so obvious as that of tube diameter. The characteristics of condensation heat transfer of zeotropic mixtures are consistent to those of azeotropic refrigerant mixtures. The condensation heat transfer coefficients increase with the concentration of the less volatile component in binary mixtures.

Numerical analysis of heat and mass transfer for water recovery in an evaporative cooling tower

NASA Astrophysics Data System (ADS)

Lee, Hyunsub; Son, Gihun

2017-11-01

Numerical analysis is performed for water recovery in an evaporative cooling tower using a condensing heat exchanger, which consists of a humid air channel and an ambient dry air channel. The humid air including water vapor produced in an evaporative cooling tower is cooled by the ambient dry air so that the water vapor is condensed and recovered to the liquid water. The conservation equations of mass, momentum, energy and vapor concentration in each fluid region and the energy equation in a solid region are simultaneously solved with the heat and mass transfer boundary conditions coupled to the effect of condensation on the channel surface of humid air. The present computation demonstrates the condensed water film distribution on the humid air channel, which is caused by the vapor mass transfer between the humid air and the colder water film surface, which is coupled to the indirect heat exchange with the ambient air. Computations are carried out to predict water recovery rate in parallel, counter and cross-flow type heat exchangers. The effects of air flow rate and channel interval on the water recovery rate are quantified.

Determination of the dispersion constant in a constrained vapor bubble thermosyphon

NASA Technical Reports Server (NTRS)

Dasgupta, Sunando; Plawsky, Joel L.; Wayner, Peter C., Jr.

1995-01-01

The isothermal profiles of the extended meniscus in a quartz cuvette were measured in a gravitational field using an image analyzing interferometer which is based on computer enhanced video microscopy of the naturally occurring interference fringes. The experimental results for heptane and pentane menisci were analyzed using the extended Young Laplace Equation. These isothermal results characterized the interfacial force field in-siru at the start of the heat transfer experiments by quantifying the dispersion constant, which is a function of the liquid-solid system and cleaning procedures. The experimentally obtained values of the disjoining pressure and the dispersion constants were compared to that predicted from the DLP theory and good agreements were obtained. The measurements are critical to the subsequent non-isothermal experiments because one of the major variables in the heat sink capability of the Constrained Vapor Bubble Thermosyphon, CVBT, is the dispersion constant. In all previous studies of micro heat pipes the value of the dispersion constant has been 'estimated'. One of the major advantages of the current glass cell is the ability to view the extended meniscus at all times. Experimentally, we find that the extended Young-Laplace Equation is an excellent model for the force field at the solid-liquid-vapor interfaces.

Delivery of Epinephrine in the Vapor Phase for the Treatment of Croup.

PubMed

Leung, Kitty; Newth, Christopher J L; Hotz, Justin C; O'Brien, Kevin C; Fink, James B; Coates, Allan L

2016-04-01

The Vapotherm system delivers high humidity to the airway of patients by using semipermeable tubules where heated liquid water is in contact with air. The humidified air is conducted to the patient via a heated tube. Preliminary clinical observations in infants with croup suggested that epinephrine added to the water supplying the humidity was delivered successfully in the vapor phase. The purpose of this study was to evaluate the efficiency of the delivery of epinephrine in the vapor phase and to develop the feasibility criteria for a clinical pilot study. Thirty milligrams of epinephrine in a 1-L bag of sterile water was used as the humidification source for a Vapotherm 2000i. The output of the heated circuit was condensed and collected into a small Erlenmeyer flask via a metal coil while the whole collection system was submerged in an ice slurry to maintain the outflow temperature from the flask between 0°C and 2°C. The in vitro system was tested at 40°C with flows of 5, 10, and 15 L/min and L-epinephrine concentrations of 15, 30, and 60 mg/L. Each test was duplicated at each of the six conditions. Academic children's hospital research laboratory. None. None. The system recovered more than 90% of the water vapor from the fully saturated air at 40°C. The epinephrine concentration recovery quantified by ultraviolet-visible spectrophotometry was 23.9% (27.5-20.4%) (mean and range) of the initial concentration. At flows of 5, 10, and 15 L/min, the delivery of epinephrine would be 1.8, 3.6, and 4.2 μg/min, respectively, which is in the therapeutic range used for parenteral infusion in young children. The Vapotherm system can be used to deliver epinephrine in pharmacological doses to the respiratory system as a vapor and thus as an alternative to droplets by conventional nebulization.

Toward an operational water vapor remote sensing system using the global positioning system

DOE Office of Scientific and Technical Information (OSTI.GOV)

Gutman, S.I.; Chadwick, R.B.; Wolf, d.W.

1995-04-01

Water vapor is one of the most important constituents of the free atmosphere since it is the principal mechanism by which moisture and latent heat are transported and cause weather. Recent experiments have demonstrated that data from Global Positioning System (GPS) satellites can be used to monitor precipitable water vapor (PWV) with millimeter accuracy and sub-hourly temporal resolution. Major advantages of GPS-based systems include the following: they work under virtually all weather conditions; individual systems do not have to be calibrated; and, they are relatively inexpensive.

Seasonal performance for Heat pump with vertical ground heat exchanger in Riga

NASA Astrophysics Data System (ADS)

Jaundālders, S.; Stanka, P.; Rusovs, D.

2017-10-01

Experimental measurements of Seasonal Coefficient of Performance (SCOP) for heating of 160 m2 household in Riga were conducted for operation of brine-water heat pump with vertical ground heat exchangers (GHE). Data regarding heat and electrical power consumption were recorded during three-year period from 2013 to 2016. Vapor compression heat pump has heat energy output of 8 kW. GHE consists of three boreholes. Each borehole is 60 m deep. Data regarding brine temperature for borehole input and output were presented and discussed. As far as house had floor heating, there were presented data about COP for B0/W35 and its dependence from room and outdoor temperature during heating season. Empirical equation was created. Average heat energy consumption during one year for heating was 72 kWh/m2 measured by heat meter. Detected primary energy consumption (electrical energy from grid) was 21 kWh/m2 which resulted in SCOP=3.8. These data were compared with SCOP for air-to-water heat pump in Latvia and available configuration software for heat pumps operation. Good agreement between calculated performance and reported experimental data were founded.

The impact of water vapor diodes on soil water redistribution

NASA Astrophysics Data System (ADS)

Wang, Zhuangji; Ankeny, Mark; Horton, Robert

2017-09-01

Diurnal soil temperature fluctuations are the prime cause for subsurface water vapor fluxes. In arid and semi-arid areas, water vapor flux is the dominant means of soil water redistribution. The directions of water vapor flux shift from upward to downward diurnally following the variations of the soil thermal gradient. A water vapor diode (WVD), acting as a check valve, allows water vapor flux in one direction but heat flux in both directions. By installing a subsurface WVD, it is possible to impose direction-controlled vapor fluxes, and WVDs can be used to accumulate or remove water in particular soil layers. The egg carton shape, with pores situated at selected peaks and valleys, is a possible design for WVDs. In this study, we provide the concept and the properties of the ideal WVDs, and we discuss four WVD configurations to control soil water redistribution. Numerical simulation is used to evaluate the impacts of the ideal WVDs. The results indicate that WVDs can increase local water contents by at least 0.1 m3m-3 in a silt loam. For a fixed initial water and thermal condition, the effect of WVDs is related to the deployment depth and distance between two consecutive WVDs. WVDs can be used to manipulate soil water redistribution and accumulate water at specific depths to support plant growth. The numerical simulation results indicate the potential effectiveness of the ideal WVDs, and field tests should be performed to determine their function under specific soil conditions.

Absorption of solar radiation by alkali vapors. [for efficient high temperature energy converters

NASA Technical Reports Server (NTRS)

Mattick, A. T.

1978-01-01

A theoretical study of the direct absorption of solar radiation by the working fluid of high temperature, high efficiency energy converters has been carried out. Alkali vapors and potassium vapor in particular were found to be very effective solar absorbers and suitable thermodynamically for practical high temperature cycles. Energy loss via reradiation from a solar boiler was shown to reduce the overall efficiency of radiation-heated energy converters, although a simple model of radiation transfer in a potassium vapor solar boiler revealed that self-trapping of the reradiation may reduce this loss considerably. A study was also made of the requirements for a radiation boiler window. It was found that for sapphire, one of the best solar transmitting materials, the severe environment in conjunction with high radiation densities will require some form of window protection. An aerodynamic shield is particularly advantageous in this capacity, separating the window from the absorbing vapor to prevent condensation and window corrosion and to reduce the radiation density at the window.

Performance Measurements and Mapping of a R-407C Vapor Injection Scroll Compressor

NASA Astrophysics Data System (ADS)

Lumpkin, Domenique; Spielbauer, Niklas; Groll, Eckhard

2017-08-01

Environmental conditions significantly define the performance of HVAC&R systems. Vapor compression systems in hot climates tend to operate at higher pressure ratios, leading to increased discharge temperatures. Higher discharge temperatures can lead to higher irreversibilities in the compression process, lower specific enthalpies differences across the evaporator, and possibly a reduction in the compressor life due to the breakdown of the oil used for lubrication. To counter these effects, the use of economized, vapor injection compressors is proposed for vapor compression systems in high temperature climates. Such compressors are commercially available for refrigeration applications, in particular, supermarket refrigeration systems. However, compressor maps for vapor injection compressors are limited and none exist for R-407C. Through calorimeter testing, a compressor map for a single-port vapor injection compressor using R-407C was developed. A standard correlation for mapping single-port vapor injection compressors is proposed and validated using the compressor test results. The system and compressor performance with and without vapor injection was considered. As expected, with vapor injection there was a reduction in compressor discharge temperatures and an increase in the system coefficient of performance. The proposed dimensionless correlation is more accurate than the AHRI polynomial for mapping the injection ratio, discharge temperature, and compressor heat loss. The predicted volumetric efficiency values from the dimensionless correlation is within 1% of the measured valued. Similarly, the predicted isentropic efficiency values are within 2% of the measured values.

Wettability modified nanoporous ceramic membrane for simultaneous residual heat and condensate recovery.

PubMed

Hu, H W; Tang, G H; Niu, D

2016-06-07

Recovery of both latent heat and condensate from boiler flue gas is significant for improving boiler efficiency and water conservation. The condensation experiments are carried out to investigate the simultaneous heat and mass transfer across the nanoporous ceramic membranes (NPCMs) which are treated to be hydrophilic and hydrophobic surfaces using the semicontinuous supercritical reactions. The effects of typical parameters including coolant flow rate, vapor/nitrogen gas mixture temperature, water vapor volume fraction and transmembrane pressure on heat and mass transfer performance are studied. The experimental results show that the hydrophilic NPCM exhibits higher performances of condensation heat transfer and condensate recovery. However, the hydrophobic modification results in remarkable degradation of heat and condensate recovery from the mixture. Molecular dynamics simulations are conducted to establish a hydrophilic/hydrophobic nanopore/water liquid system, and the infiltration characteristics of the single hydrophilic/hydrophobic nanopore is revealed.

Wettability modified nanoporous ceramic membrane for simultaneous residual heat and condensate recovery

NASA Astrophysics Data System (ADS)

Hu, H. W.; Tang, G. H.; Niu, D.

2016-06-01

Recovery of both latent heat and condensate from boiler flue gas is significant for improving boiler efficiency and water conservation. The condensation experiments are carried out to investigate the simultaneous heat and mass transfer across the nanoporous ceramic membranes (NPCMs) which are treated to be hydrophilic and hydrophobic surfaces using the semicontinuous supercritical reactions. The effects of typical parameters including coolant flow rate, vapor/nitrogen gas mixture temperature, water vapor volume fraction and transmembrane pressure on heat and mass transfer performance are studied. The experimental results show that the hydrophilic NPCM exhibits higher performances of condensation heat transfer and condensate recovery. However, the hydrophobic modification results in remarkable degradation of heat and condensate recovery from the mixture. Molecular dynamics simulations are conducted to establish a hydrophilic/hydrophobic nanopore/water liquid system, and the infiltration characteristics of the single hydrophilic/hydrophobic nanopore is revealed.

Petroleum Vapor Intrusion

EPA Pesticide Factsheets

One type of vapor intrusion is PVI, in which vapors from petroleum hydrocarbons such as gasoline, diesel, or jet fuel enter a building. Intrusion of contaminant vapors into indoor spaces is of concern.

Sensitivity study of the monogroove with screen heat pipe design

NASA Technical Reports Server (NTRS)

Evans, Austin L.; Joyce, Martin

1988-01-01

The present sensitivity study of design variable effects on the performance of a monogroove-with-screen heat pipe obtains performance curves for maximum heat-transfer rates vs. operating temperatures by means of a computer code; performance projections for both 1-g and zero-g conditions are obtainable. The variables in question were liquid and vapor channel design, wall groove design, and the number of feed lines in the evaporator and condenser. The effect on performance of three different working fluids, namely ammonia, methanol, and water, were also determined. Greatest sensitivity was to changes in liquid and vapor channel diameters.

Method and apparatus for simulating atomospheric absorption of solar energy due to water vapor and CO.sub.2

DOEpatents

Sopori, Bhushan L.

1995-01-01

A method and apparatus for improving the accuracy of the simulation of sunlight reaching the earth's surface includes a relatively small heated chamber having an optical inlet and an optical outlet, the chamber having a cavity that can be filled with a heated stream of CO.sub.2 and water vapor. A simulated beam comprising infrared and near infrared light can be directed through the chamber cavity containing the CO.sub.2 and water vapor, whereby the spectral characteristics of the beam are altered so that the output beam from the chamber contains wavelength bands that accurately replicate atmospheric absorption of solar energy due to atmospheric CO.sub.2 and moisture.

A MASS-SPECTROMETRIC INVESTIGATION OF SULFUR VAPOR AS A FUNCTION OF TEMPERATURE (thesis)

DOE Office of Scientific and Technical Information (OSTI.GOV)

Zietz, M.C.

1960-06-15

A mass-spectrometric investigation was performed on sulfur vapor in equilibrium with the condensed phase at 120 to 210 gas-cooled C. It was found that, in this temperature range, equilibrium sulfur vapor contains appreciable quantities of S/sub 8/, S/sub 7/, S/sub 6/, and S/sub 5/ only. The sulfur vapor emanated as a small well-collimated molecular beam from a specially constructed source into an ionization chamber which was designed to exclude from analysis any sulfur vapor that had impinged on the walls or the hot electron filament. Essential identical ionization potentials were determined for S/sub 8/ , S/sub 7/, S/sub 6/, andmore » S/sub 5/ of 9.8 0.4 ev. The heat of vaporizati on of S/sub 7/ was calculated to be approximately 2.5 kcal greater than that of S/ sub 8/. Upper limits for S/sub 8/ and S/sub 7/ composition in S vapor at 120 gas- cooled C were determined to be 86% and 14%, respectively. It is proposed thst S/sub 8/ is the vaporizing species, that S/sub 7/, S/sub 6/, and S/sub 5/ result from dissociation of S/sub 8/. and that all four molecules have a ring configuration. (auth)« less

Enhanced two phase flow in heat transfer systems

DOEpatents

Tegrotenhuis, Ward E; Humble, Paul H; Lavender, Curt A; Caldwell, Dustin D

2013-12-03

A family of structures and designs for use in devices such as heat exchangers so as to allow for enhanced performance in heat exchangers smaller and lighter weight than other existing devices. These structures provide flow paths for liquid and vapor and are generally open. In some embodiments of the invention, these structures can also provide secondary heat transfer as well. In an evaporate heat exchanger, the inclusion of these structures and devices enhance the heat transfer coefficient of the evaporation phase change process with comparable or lower pressure drop.

The Intrinsic Variability in the Water Vapor Saturation Ratio due to Turbulence

NASA Astrophysics Data System (ADS)

Anderson, J. C.; Cantrell, W. H.; Chandrakar, K. K.; Kostinski, A. B.; Niedermeier, D.; Shaw, R. A.

2017-12-01

In the atmosphere, the concentration of water vapor plays an important role in Earth's weather and climate. The mean concentration of water vapor is key to its efficiency as a greenhouse gas; the fluctuations about the mean are important for heat fluxes near the surface of earth. In boundary layer clouds, fluctuations in the water vapor concentration are linked to turbulence. Conditions representative of boundary layer clouds are simulated in Michigan Tech's multiphase, turbulent reaction chamber, the ∏ chamber, where the boundary conditions are controlled and repeatable. Measurements for temperature and water vapor concentration were recorded under forced Rayleigh-Bénard convection. As expected, the distributions for temperature and water vapor concentration broaden as the turbulence becomes more vigorous. From these two measurements the saturation ratio can be calculated. The fluctuations in the water vapor concentration are more important to the variability in the saturation ratio than fluctuations in temperature. In a cloud, these fluctuations in the saturation ratio can result in some cloud droplets experiencing much higher supersaturations. Those "lucky" droplets grow by condensation at a faster rate than other cloud droplets. The difference in the droplet growth rate could contribute to a broadened droplet distribution, which leads to the onset of collision-coalescence. With more intense turbulence these effect will become more pronounced as the fluctuations about the mean saturation ratio become more pronounced.

Force Field Benchmark of Organic Liquids: Density, Enthalpy of Vaporization, Heat Capacities, Surface Tension, Isothermal Compressibility, Volumetric Expansion Coefficient, and Dielectric Constant.

PubMed

Caleman, Carl; van Maaren, Paul J; Hong, Minyan; Hub, Jochen S; Costa, Luciano T; van der Spoel, David

2012-01-10

The chemical composition of small organic molecules is often very similar to amino acid side chains or the bases in nucleic acids, and hence there is no a priori reason why a molecular mechanics force field could not describe both organic liquids and biomolecules with a single parameter set. Here, we devise a benchmark for force fields in order to test the ability of existing force fields to reproduce some key properties of organic liquids, namely, the density, enthalpy of vaporization, the surface tension, the heat capacity at constant volume and pressure, the isothermal compressibility, the volumetric expansion coefficient, and the static dielectric constant. Well over 1200 experimental measurements were used for comparison to the simulations of 146 organic liquids. Novel polynomial interpolations of the dielectric constant (32 molecules), heat capacity at constant pressure (three molecules), and the isothermal compressibility (53 molecules) as a function of the temperature have been made, based on experimental data, in order to be able to compare simulation results to them. To compute the heat capacities, we applied the two phase thermodynamics method (Lin et al. J. Chem. Phys.2003, 119, 11792), which allows one to compute thermodynamic properties on the basis of the density of states as derived from the velocity autocorrelation function. The method is implemented in a new utility within the GROMACS molecular simulation package, named g_dos, and a detailed exposé of the underlying equations is presented. The purpose of this work is to establish the state of the art of two popular force fields, OPLS/AA (all-atom optimized potential for liquid simulation) and GAFF (generalized Amber force field), to find common bottlenecks, i.e., particularly difficult molecules, and to serve as a reference point for future force field development. To make for a fair playing field, all molecules were evaluated with the same parameter settings, such as thermostats and barostats

Force Field Benchmark of Organic Liquids: Density, Enthalpy of Vaporization, Heat Capacities, Surface Tension, Isothermal Compressibility, Volumetric Expansion Coefficient, and Dielectric Constant

PubMed Central

2011-01-01

The chemical composition of small organic molecules is often very similar to amino acid side chains or the bases in nucleic acids, and hence there is no a priori reason why a molecular mechanics force field could not describe both organic liquids and biomolecules with a single parameter set. Here, we devise a benchmark for force fields in order to test the ability of existing force fields to reproduce some key properties of organic liquids, namely, the density, enthalpy of vaporization, the surface tension, the heat capacity at constant volume and pressure, the isothermal compressibility, the volumetric expansion coefficient, and the static dielectric constant. Well over 1200 experimental measurements were used for comparison to the simulations of 146 organic liquids. Novel polynomial interpolations of the dielectric constant (32 molecules), heat capacity at constant pressure (three molecules), and the isothermal compressibility (53 molecules) as a function of the temperature have been made, based on experimental data, in order to be able to compare simulation results to them. To compute the heat capacities, we applied the two phase thermodynamics method (Lin et al. J. Chem. Phys.2003, 119, 11792), which allows one to compute thermodynamic properties on the basis of the density of states as derived from the velocity autocorrelation function. The method is implemented in a new utility within the GROMACS molecular simulation package, named g_dos, and a detailed exposé of the underlying equations is presented. The purpose of this work is to establish the state of the art of two popular force fields, OPLS/AA (all-atom optimized potential for liquid simulation) and GAFF (generalized Amber force field), to find common bottlenecks, i.e., particularly difficult molecules, and to serve as a reference point for future force field development. To make for a fair playing field, all molecules were evaluated with the same parameter settings, such as thermostats and barostats

Liquid over-feeding refrigeration system and method with integrated accumulator-expander-heat exchanger

DOEpatents

Mei, V.C.; Chen, F.C.

1997-04-22

A refrigeration system is described having a vapor compression cycle utilizing a liquid over-feeding operation with an integrated accumulator-expander-heat exchanger. Hot, high-pressure liquid refrigerant from the condenser passes through one or more lengths of capillary tubing substantially immersed in a pool liquid refrigerant in the accumulator-expander-heat exchanger for simultaneously sub-cooling and expanding the liquid refrigerant while vaporizing liquid refrigerant from the pool for the return thereof to the compressor as saturated vapor. The sub-cooling of the expanded liquid provides for the flow of liquid refrigerant into the evaporator for liquid over-feeding the evaporator and thereby increasing the efficiency of the evaporation cycle. 4 figs.

Theoretical studies in support of the 3M-vapor transport (PVTOS-) experiments

NASA Technical Reports Server (NTRS)

Rosner, Daniel E.; Keyes, David E.

1989-01-01

Results are reported for a preliminary theoretical study of the coupled mass-, momentum-, and heat-transfer conditions expected within small ampoules used to grow oriented organic solid (OS-) films, by physical vapor transport (PVT) in microgravity environments. It is show that previous studies made restrictive assumptions (e.g., smallness of delta T/T, equality of molecular diffusivities) not valid under PVTOS conditions, whereas the important phenomena of sidewall gas creep, Soret transport of the organic vapor, and large vapor phase supersaturations associated with the large prevailing temperature gradients were not previously considered. Rational estimates are made of the molecular transport properties relevant to copper-phthalocyanine monomeric vapor in a gas mixture containing H2(g) and Xe(g). Efficient numerical methods have been developed and are outlined/illustrated here to making steady axisymmetric gas flow calculations within such ampoules, allowing for realistic realistic delta T/T(sub)w-values, and even corrections to Navier-Stokes-Fourier 'closure' for the governing continuum differential equations. High priority follow-on studies are outlined based on these new results.

High efficiency vapor-fed AMTEC system for direct conversion. Final report

DOE Office of Scientific and Technical Information (OSTI.GOV)

Anderson, W.G.; Bland, J.J.

1997-05-23

The Alkali Metal Thermal to Electric Converter (AMTEC) is a high temperature, high efficiency system for converting thermal to electrical energy, with no moving parts. It is based on the unique properties of {beta}{double_prime}-alumina solid electrolyte (BASE), which is an excellent conductor of sodium ions, but an extremely poor conductor of electrons. When the inside of the BASE is maintained at a higher temperature and pressure, a concentration gradient is created across the BASE. Electrons and sodium atoms cannot pass through the BASE. However, the sodium atoms are ionized, and the sodium ions move through the BASE to the lowermore » potential (temperature) region. The electrons travel externally to the AMTEC cell, providing power. There are a number of potential advantages to a wick-pumped, vapor-fed AMTEC system when compared with other designs. A wick-pumped system uses capillary forces to passively return liquid to the evaporator, and to distribute the liquid in the evaporator. Since the fluid return is self-regulating, multiple BASE tubes can use a single remote condenser, potentially improving efficiency in advanced AMTEC designs. Since the system is vapor-fed, sodium vapor is supplied at a uniform temperature and flux to the BASE tube, even with non-uniform heat fluxes and temperatures at the evaporator. The primary objective of the Phase 2 program was to develop wick-pumped AMTEC cells. During the program, procedures to fabricate wicks with smaller pore sizes were developed, to allow operation of an AMTEC cell at 800 C. A revised design was made for a High-Temperature, Wick-Fed AMTEC cell. In addition to the smaller wick pore size, several other changes were made to increase the cell efficiency: (1) internal artery return of condensate; (2) high temperature electrical feedthrough; and (3) separate heat pipe for providing heat to the BASE.« less

Temperature Oscillations in Loop Heat Pipes - A Revisit

NASA Technical Reports Server (NTRS)

Ku, Jentung

2018-01-01

Three types of temperature oscillation have been observed in the loop heat pipes. The first type is an ultra-high frequency temperature oscillation with a period on the order of seconds or less. This type of temperature oscillation is of little significance in spacecraft thermal control because the amplitude is in the noise level. The second type is a high frequency, low amplitude temperature oscillation with a period on the order of seconds to minutes and an amplitude on the order of one Kelvin. It is caused by the back-and-forth movement of the vapor front near the inlet or outlet of the condenser. The third type is a low frequency, high amplitude oscillation with a period on the order of hours and an amplitude on the order of tens of Kelvin. It is caused by the modulation of the net heat load into the evaporator by the attached large thermal mass which absorbs and releases energy alternately. Several papers on LHP temperature oscillation have been published. This paper presents a further study on the underlying physical processes during the LHP temperature oscillation, with an emphasis on the third type of temperature oscillation. Specifically, equations governing the thermal and hydraulic behaviors of LHP operation will be used to describe interactions among LHP components, heat source, and heat sink. The following sequence of events and their interrelationship will also be explored: 1) maxima and minima of reservoir and thermal mass temperatures; 2) the range of the vapor front movement inside the condenser; 3) rates of change of the reservoir and thermal mass temperatures; 4) the rate of heat absorption and heat release by the thermal mass and the rate of vapor front movement; and 5) inflection points of the reservoir and thermal mass temperatures.

Multiphoton laser ionization for energy conversion in barium vapor

NASA Astrophysics Data System (ADS)

Makdisi, Y.; Kokaj, J.; Afrousheh, K.; Mathew, J.; Nair, R.; Pichler, G.

2013-03-01

We have studied the ion detection of barium atoms in special heated ovens with a tungsten rod in the middle of the stainless steel tube. The tungsten rod was heated indirectly by the oven body heaters. A bias voltage between the cell body and the tungsten rod of 9 V was used to collect electrons, after the barium ions had been created. However, we could collect the electrons even without the bias voltage, although with ten times less efficiency. We studied the conditions for the successful bias-less thermionic signal detection using excimer/dye laser two-photon excitation of Rydberg states below and above the first ionization limit (two-photon wavelength at 475.79 nm). We employed a hot-pipe oven and heat-pipe oven (with inserted mesh) in order to generate different barium vapor distributions inside the oven. The thermionic signal increased by a factor of two under heat-pipe oven conditions.

Preliminary design package for solar heating and cooling systems

NASA Technical Reports Server (NTRS)

1978-01-01

Summarized preliminary design information on activities associated with the development, delivery and support of solar heating and cooling systems is given. These systems are for single family dwellings and commercial applications. The heating/cooling system use a reversible vapor compression heat pump that is driven in the cooling mode by a Rankine power loop, and in the heating mode by a variable speed electric motor. The heating/cooling systems differ from the heating-only systems in the arrangement of the heat pump subsystem and the addition of a cooling tower to provide the heat sink for cooling mode operation.

Development of an integrated heat pipe-thermal storage system for a solar receiver

NASA Technical Reports Server (NTRS)

Keddy, E. S.; Sena, J. T.; Merrigan, M. A.; Heidenreich, G.; Johnson, S.

1987-01-01

The Organic Rankine Cycle (ORC) Solar Dynamic Power System (SDPS) is one of the candidates for Space Station prime power application. In the low Earth orbit of the Space Station approximately 34 minutes of the 94-minute orbital period is spent in eclipse with no solar energy input to the power system. For this period the SDPS will use thermal energy storage (TES) material to provide a constant power output. An integrated heat-pipe thermal storage receiver system is being developed as part of the ORC-SDPS solar receiver. This system incorporates potassium heat pipe elements to absorb and transfer the solar energy within the receiver cavity. The heat pipes contain the TES canisters within the potassium vapor space with the toluene heater tube used as the condenser region of the heat pipe. During the insolation period of the Earth orbit, solar energy is delivered to the heat pipe in the ORC-SDPS receiver cavity. The heat pipe transforms the non-uniform solar flux incident in the heat pipe surface within the receiver cavity to an essentially uniform flux at the potassium vapor condensation interface in the heat pipe. During solar insolation, part of the thermal energy is delivered to the heater tube and the balance is stored in the TES units. During the eclipse period of the orbit, the balance stored in the TES units is transferred by the potassium vapor to the toluene heater tube.

Design, fabrication and test of a hydrogen heat pipe. [extruding and grooving 6063-T6 aluminum tubes for cryogenic heat pipes

NASA Technical Reports Server (NTRS)

Alario, J.

1979-01-01

Re-entrant groove technology was extended to hydrogen heat pipes. Parametric analyses are presented which optimize the theoretical design while considering the limitations of state-of-the-art extrusion technology. The 6063-T6 aluminum extrusion is 14.6 mm OD with a wall thickness of 1.66 mm and contains 20 axial grooves which surround a central 9.3 mm diameter vapor core. Each axial groove is 0.775 mm diameter with a 0.33 mm opening. An excess vapor reservoir is provided at the evaporator to minimize the pressure containment hazard during ambient storage. Modifications to the basic re-entrant groove profile resulted in improved overall performance. While the maximum heat transport capacity decreased slightly to 103 w-m the static wicking height increased markedly to 4.5 cm. The heat pipe became operational between 20 and 30 K after a cooldown from 77 K without any difficulty. Steady state performance data taken over a 19 to 23 K temperature range indicated: (1) maximum heat transport capacity of 5.4 w-m; (2) static wicking height of 1.42 cm; and (3) overall heat pipe conductance of 1.7 watts/deg C.

Vapor phase pyrolysis

NASA Technical Reports Server (NTRS)

Steurer, Wolfgang

1992-01-01

The vapor phase pyrolysis process is designed exclusively for the lunar production of oxygen. In this concept, granulated raw material (soil) that consists almost entirely of metal oxides is vaporized and the vapor is raised to a temperature where it dissociates into suboxides and free oxygen. Rapid cooling of the dissociated vapor to a discrete temperature causes condensation of the suboxides, while the oxygen remains essentially intact and can be collected downstream. The gas flow path and flow rate are maintained at an optimum level by control of the pressure differential between the vaporization region and the oxygen collection system with the aid of the environmental vacuum.

Fixation of nitrogen in the presence of water vapor

DOEpatents

Harteck, Paul

1984-01-01

A process for the fixation of nitrogen is disclosed which comprises combining a mixture of nitrogen, oxygen, metal oxide and water vapor, initially heating the combination to initiate a reaction which forms nitrate, but at a temperature and pressure range below the dissociation pressure of the nitrate. With or without the water component, the yield of fixed nitrogen is increased by the use of a Linde Molecular Sieve Catalyst.

Sulfur determination in coal using molecular absorption in graphite filter vaporizer.

PubMed

Jim, Gibson; Katskov, Dmitri; Tittarelli, Paolo

2011-02-15

The vaporization of sulfur containing samples in graphite vaporizers for atomic absorption spectrometry is accompanied by modification of sulfur by carbon and, respectively, appearance at high temperature of structured molecular absorption in 200-210 nm wavelength range. It has been proposed to employ the spectrum for direct determination of sulfur in coal; soundness of the suggestion is evaluated by analysis of coal slurry using low resolution CCD spectrometer with continuum light source coupled to platform or filter furnace vaporizers. For coal in platform furnace losses of the analyte at low temperature and strong spectral background from the coal matrix hinder the determination. Both negative effects are significantly reduced in filter furnace, in which sample vapor efficiently interacts with carbon when transferred through the heated graphite filter. The method is verified by analysis of coals with sulfur content within 0.13-1.5% (m/m) range. The use of coal certified reference material for sulfur analyte addition to coal slurry permitted determination with random error 5-12%. Absolute and relative detection limits for sulfur in coal are 0.16 μg and 0.02 mass%, respectively. Copyright © 2010 Elsevier B.V. All rights reserved.

Heat Exchanger With Internal Pin Elements

DOEpatents

Gerstmann, Joseph; Hannon, Charles L.

2004-01-13

A heat exchanger/heater comprising a tubular member having a fluid inlet end, a fluid outlet end and plurality of pins secured to the interior wall of the tube. Various embodiments additionally comprise a blocking member disposed concentrically inside the pins, such as a core plug or a baffle array. Also disclosed is a vapor generator employing an internally pinned tube, and a fluid-heater/heat-exchanger utilizing an outer jacket tube and fluid-side baffle elements, as well as methods for heating a fluid using an internally pinned tube.

Ground-based research of crystal growth of II-VI compound semiconductors by physical vapor transport

NASA Technical Reports Server (NTRS)

Volz, M. P.; Gillies, D. C.; Szofran, F. R.; Lehoczky, S. L.; Su, Ching-Hua; Sha, Yi-Gao; Zhou, W.; Dudley, M.; Liu, Hao-Chieh; Brebrick, R. F.;

Dielectric Spectroscopy Study of ZnSe Grown by Physical Vapor Transport

NASA Technical Reports Server (NTRS)

Kokan, J.; Gerhardt, R.; Su, Ching-Hua

1997-01-01

The dielectric properties of ZnSe samples grown by physical vapor transport were measured as a function of frequency. Differences can be seen in the dielectric properties of samples grown under different conditions. The spectra of heat treated samples were also acquired and were found to exhibit significant deviations from those of the as grown crystals.

Wettability modified nanoporous ceramic membrane for simultaneous residual heat and condensate recovery

PubMed Central

Hu, H. W.; Tang, G. H.; Niu, D.

2016-01-01

Recovery of both latent heat and condensate from boiler flue gas is significant for improving boiler efficiency and water conservation. The condensation experiments are carried out to investigate the simultaneous heat and mass transfer across the nanoporous ceramic membranes (NPCMs) which are treated to be hydrophilic and hydrophobic surfaces using the semicontinuous supercritical reactions. The effects of typical parameters including coolant flow rate, vapor/nitrogen gas mixture temperature, water vapor volume fraction and transmembrane pressure on heat and mass transfer performance are studied. The experimental results show that the hydrophilic NPCM exhibits higher performances of condensation heat transfer and condensate recovery. However, the hydrophobic modification results in remarkable degradation of heat and condensate recovery from the mixture. Molecular dynamics simulations are conducted to establish a hydrophilic/hydrophobic nanopore/water liquid system, and the infiltration characteristics of the single hydrophilic/hydrophobic nanopore is revealed. PMID:27270997

Oxidative vaporization kinetics of chromium (III) oxide in oxygen from 1270 to 1570 K

NASA Technical Reports Server (NTRS)

Stearns, C. A.; Kohl, F. J.; Fryburg, G. C.

1974-01-01

Rates of oxidative vaporization of Cr2O3 on preoxidized resistively heated chromium were determined in flowing oxygen at 0.115 torr for temperatures from 1270 to 1570 K. Reaction controlled rates were obtained from experimental rates by a gold calibration technique. These rates were shown to agree with those predicted by thermochemical analysis. The activation energy obtained for the oxidative vaporation reaction corresponded numerically with the thermochemical enthalpy of the reaction. A theoretical equation is given for calculating the rate from thermodynamic data by using boundary layer theory.

Role of chalcogen vapor annealing in inducing bulk superconductivity in Fe 1+yTe 1-xSe x [How does annealing in chalcogen vapor induce superconductivity in Fe 1+yTe -xSe x?

DOE PAGES

Lin, Wenzhi; Ganesh, P.; Gianfrancesco, Anthony; ...

2015-02-27

Recent investigations have shown that Fe 1+yTe 1-xSe x can be made superconducting by annealing it in Se and O vapors. The current lore is that these chalcogen vapors induce superconductivity by removing the magnetic excess Fe atoms. To investigate this phenomenon we performed a combination of magnetic susceptibility, specific heat and transport measurements together with scanning tunneling microscopy and spectroscopy and density functional theory calculations on Fe 1+yTe 1-xSe x treated with Te vapor. We conclude that the main role of the Te vapor is to quench the magnetic moments of the excess Fe atoms by forming FeTe mmore » (m ≥ 1) complexes. We show that the remaining FeTe m complexes are still damaging to the superconductivity and therefore that their removal potentially could further improve superconductive properties in these compounds.« less

Parametric study of graphite foam fins and application in heat exchangers

NASA Astrophysics Data System (ADS)

Collins, Michael

This thesis focuses on the simulation and experimental studies of finned graphite foam extended surfaces to test their heat transfer characteristics and potential applications in condensers. Different fin designs were developed to conduct a parametric study on the thermal effectiveness with respect to thickness, spacing and fin offset angle. Each fin design was computationally simulated to estimate the heat transfer under specific conditions. The simulations showed that this optimal fin configuration could conduct more than 297% the amount of thermal energy as compared to straight aluminum fins. Graphite foam fins were then implemented into a simulation of the condenser system. The condenser was simulated with six different orientations of baffles to examine the incoming vapor and resulting two-phase flow patterns. The simulations showed that using both horizontal and vertical baffling provided the configuration with the highest heat transfer and minimized the bypass regions where the vapor would circumvent the graphite foam. This baffle configuration increased the amount of vapor flow through the inner graphite fins and cold water pipes, which gave this configuration the highest heat transfer. The results from experimental tests using the condenser system confirmed that using three baffles will increase performance consistent with the simulation results. The experimental data showed that the condenser using graphite foam had five times the heat transfer compared to the condenser using only aluminum fins. Incorporating baffles into the condenser using graphite foam enabled this system to conduct nearly ten times more heat transfer than the condenser system which only had aluminum fins without baffles. The results from this research indicate that graphite foam is a far superior material heat transfer enhancement material for heat transfer compared to aluminum used as an extended surface. The longitudinal and horizontal baffles incorporated into the condenser system

Viscous hydrodynamic instability theory of the peak and minimum pool boiling heat fluxes

NASA Technical Reports Server (NTRS)

Dhir, V. K.

1972-01-01

Liquid viscosity was included in the Bellman-Pennington theory of the Taylor wave in a liquid vapor interface. Predictions of the most susceptible wavelength, and of the wave frequency, were made as a function of a liquid viscosity parameter and the Bond number. The stability of a gas jet in a viscous liquid was studied and the result is used to predict the peak heat flux on large horizontal heaters. Experimental measurements of the dominant Taylor wave and its growth rate were made during the film boiling of cyclohexanol on cylindrical heaters. The results bear out the predictions quite well. The thickness of the vapor blanket surrounding a cylindrical heater was measured and a correlation suggested. The effect of large fluxes of vapor volume on the dominant wavelength was also noted. Theoretical results of the peak heat flux are compared with the experimental data, and the effect of finite geometry of flat plate heaters on the peak heat flux is also discussed.

Vacuum vapor deposition

NASA Technical Reports Server (NTRS)

Poorman, Richard M. (Inventor); Weeks, Jack L. (Inventor)

1995-01-01

A method and apparatus is described for vapor deposition of a thin metallic film utilizing an ionized gas arc directed onto a source material spaced from a substrate to be coated in a substantial vacuum while providing a pressure differential between the source and the substrate so that, as a portion of the source is vaporized, the vapors are carried to the substrate. The apparatus includes a modified tungsten arc welding torch having a hollow electrode through which a gas, preferably inert, flows and an arc is struck between the electrode and the source. The torch, source, and substrate are confined within a chamber within which a vacuum is drawn. When the arc is struck, a portion of the source is vaporized and the vapors flow rapidly toward the substrate. A reflecting shield is positioned about the torch above the electrode and the source to ensure that the arc is struck between the electrode and the source at startup. The electrode and the source may be confined within a vapor guide housing having a duct opening toward the substrate for directing the vapors onto the substrate.

Numerical simulation of supersonic water vapor jet impinging on a flat plate

NASA Astrophysics Data System (ADS)

Kuzuu, Kazuto; Aono, Junya; Shima, Eiji

2012-11-01

We investigated supersonic water vapor jet impinging on a flat plate through numerical simulation. This simulation is for estimating heating effect of a reusable sounding rocket during vertical landing. The jet from the rocket bottom is supersonic, M=2 to 3, high temperature, T=2000K, and over-expanded. Atmospheric condition is a stationary standard air. The simulation is base on the full Navier-Stokes equations, and the flow is numerically solved by an unstructured compressible flow solver, in-house code LS-FLOW-RG. In this solver, the transport properties of muti-species gas and mass conservation equations of those species are considered. We employed DDES method as a turbulence model. For verification and validation, we also carried out a simulation under the condition of air, and compared with the experimental data. Agreement between our results and the experimental data are satisfactory. Through this simulation, we calculated the flow under some exit pressure conditions, and discuss the effects of pressure ratio on flow structures, heat transfer and so on. Furthermore, we also investigated diffusion effects of water vapor, and we confirmed that these phenomena are generated by the interaction of atmospheric air and affects the heat transfer to the surrounding environment.

Preparation of membranes using solvent-less vapor deposition followed by in-situ polymerization

DOEpatents

O'Brien, Kevin C [San Ramon, CA; Letts, Stephan A [San Ramon, CA; Spadaccini, Christopher M [Oakland, CA; Morse, Jeffrey C [Pleasant Hill, CA; Buckley, Steven R [Modesto, CA; Fischer, Larry E [Los Gatos, CA; Wilson, Keith B [San Ramon, CA

2012-01-24

A system of fabricating a composite membrane from a membrane substrate using solvent-less vapor deposition followed by in-situ polymerization. A first monomer and a second monomer are directed into a mixing chamber in a deposition chamber. The first monomer and the second monomer are mixed in the mixing chamber providing a mixed first monomer and second monomer. The mixed first monomer and second monomer are solvent-less vapor deposited onto the membrane substrate in the deposition chamber. The membrane substrate and the mixed first monomer and second monomer are heated to produce in-situ polymerization and provide the composite membrane.

Preparation of membranes using solvent-less vapor deposition followed by in-situ polymerization

DOEpatents

O'Brien, Kevin C [San Ramon, CA; Letts, Stephan A [San Ramon, CA; Spadaccini, Christopher M [Oakland, CA; Morse, Jeffrey C [Pleasant Hill, CA; Buckley, Steven R [Modesto, CA; Fischer, Larry E [Los Gatos, CA; Wilson, Keith B [San Ramon, CA

2010-07-13

A system of fabricating a composite membrane from a membrane substrate using solvent-less vapor deposition followed by in-situ polymerization. A first monomer and a second monomer are directed into a mixing chamber in a deposition chamber. The first monomer and the second monomer are mixed in the mixing chamber providing a mixed first monomer and second monomer. The mixed first monomer and second monomer are solvent-less vapor deposited onto the membrane substrate in the deposition chamber. The membrane substrate and the mixed first monomer and second monomer are heated to produce in-situ polymerization and provide the composite membrane.

Vapor-liquid equilibrium thermodynamics of N2 + CH4 - Model and Titan applications

NASA Technical Reports Server (NTRS)

Thompson, W. R.; Zollweg, John A.; Gabis, David H.

1992-01-01

A thermodynamic model is presented for vapor-liquid equilibrium in the N2 + CH4 system, which is implicated in calculations of the Titan tropospheric clouds' vapor-liquid equilibrium thermodynamics. This model imposes constraints on the consistency of experimental equilibrium data, and embodies temperature effects by encompassing enthalpy data; it readily calculates the saturation criteria, condensate composition, and latent heat for a given pressure-temperature profile of the Titan atmosphere. The N2 content of condensate is about half of that computed from Raoult's law, and about 30 percent greater than that computed from Henry's law.

Nonlinear dynamics of a vapor bubble expanding in a superheated region of finite size

DOE Office of Scientific and Technical Information (OSTI.GOV)

Annenkova, E. A., E-mail: a-a-annenkova@yandex.ru; Kreider, W.; Sapozhnikov, O. A.

2015-10-28

Growth of a vapor bubble in a superheated liquid is studied theoretically. Contrary to the typical situation of boiling, when bubbles grow in a uniformly heated liquid, here the superheated region is considered in the form of a millimeter-sized spherical hot spot. An initial micron-sized bubble is positioned at the hot spot center and a theoretical model is developed that is capable of studying bubble growth caused by vapor pressure inside the bubble and corresponding hydrodynamic and thermal processes in the surrounding liquid. Such a situation is relevant to the dynamics of vapor cavities that are created in soft biologicalmore » tissue in the focal region of a high-intensity focused ultrasound beam with a shocked pressure waveform. Such beams are used in the recently proposed treatment called boiling histotripsy. Knowing the typical behavior of vapor cavities during boiling histotripsy could help to optimize the therapeutic procedure.« less

Capillary Limit in a Loop Heat Pipe with Dual Evaporators