Variable Gap Conjugated Polymers

DTIC Science & Technology

2005-12-01

conducting gold interfacial layer interjected between the ITO glass electrode and the PEDOT/PSS hole transport layer . A family of low band gap, and near IR...which can be used as both electrochromics and as the hole transport layers in light emitting diodes. Hybrid electrochromic and electroluminescent (EC...MEH-PPV, P3HT, etc.) in order to blanket the solar spectrum. Initial device results on these multi-component blends are promising. In addition, we

Physics and applications of electrochromic devices

NASA Astrophysics Data System (ADS)

Pawlicka, Agnieszka; Avellaneda, Cesar O.

2003-07-01

Solid state electrochromic devices (ECD) are of considerable technological and commercial interest because of their controllable transmission, absorption and/or reflectance. For instance, a major application of these devices is in smart windows that can regulate the solar gains of buildings and also in glare attenuation in automobile rear view mirrors. Other applications include solar cells, small and large area flat panel displays, satellite temperature control, food monitoring, and document authentication. A typical electrochromic device has a five-layer structure: GS/TC/EC/IC/IS/TC/GS, where GS is a glass substrate, TC is a transparent conductor, generally ITO (indium tin oxide) or FTO (fluorine tin oxide), EC is an electrochromic coating, IC is an ion conductor (solid or liquid electrolyte) and IS is an ion storage coating. Generally, the EC and IS layers are deposited separately on the TC coatings and then jointed with the IC and sealed. The EC and IS are thin films that can be deposited by sputtering, CVD, sol-gel precursors, etc. There are different kinds of organic, inorganic and organic-inorganic films that can be used to make electrochromic devices. Thin electrochromic films can be: WO3, Nb2O5, Nb2O5:Li+ or Nb2O5-TiO2 coatings, ions storage films: CeO2-TiO2, CeO2-ZrO2 or CeO2-TiO2-ZrO2 and electrolytes like Organically Modified Electrolytes (Ormolytes) or polymeric films also based on natural polymers like starch or cellulose. These last are very interesting due to their high ionic conductivity, high transparency and good mechanical properties. This paper describes construction and properties of different thin oxide and polymeric films and also shows the optical response of an all sol-gel electrochromic device with WO3/Ormolyte/CeO2-TiO2 configuration.

Stand-alone photovoltaic (PV) powered electrochromic window

DOEpatents

Benson, David K.; Crandall, Richard S.; Deb, Satyendra K.; Stone, Jack L.

1995-01-01

A variable transmittance double pane window includes an electrochromic material that has been deposited on one pane of the window in conjunction with an array of photovoltaic cells deposited along an edge of the pane to produce the required electric power necessary to vary the effective transmittance of the window. A battery is placed in a parallel fashion to the array of photovoltaic cells to allow the user the ability to manually override the system when a desired transmittance is desired.

Stand-alone photovoltaic (PV) powered electrochromic window

DOEpatents

Benson, D.K.; Crandall, R.S.; Deb, S.K.; Stone, J.L.

1995-01-24

A variable transmittance double pane window includes an electrochromic material that has been deposited on one pane of the window in conjunction with an array of photovoltaic cells deposited along an edge of the pane to produce the required electric power necessary to vary the effective transmittance of the window. A battery is placed in a parallel fashion to the array of photovoltaic cells to allow the user the ability to manually override the system when a desired transmittance is desired. 11 figures.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Berland, Brian Spencer; Lanning, Bruce Roy; Stowell, Jr., Michael Wayne

This disclosure describes system and methods for creating an autonomous electrochromic assembly, and systems and methods for use of the autonomous electrochromic assembly in combination with a window. Embodiments described herein include an electrochromic assembly that has an electrochromic device, an energy storage device, an energy collection device, and an electrochromic controller device. These devices may be combined into a unitary electrochromic insert assembly. The electrochromic assembly may have the capability of generating power sufficient to operate and control an electrochromic device. This control may occur through the application of a voltage to an electrochromic device to change its opacitymore » state. The electrochromic assembly may be used in combination with a window.« less

Electrochromic device

DOEpatents

Schwendemanm, Irina G [Wexford, PA; Polcyn, Adam D [Pittsburgh, PA; Finley, James J [Pittsburgh, PA; Boykin, Cheri M [Kingsport, TN; Knowles, Julianna M [Apollo, PA

2011-03-15

An electrochromic device includes a first substrate spaced from a second substrate. A first conductive member is formed over at least a portion of the first substrate. A first electrochromic material is formed over at least a portion of the first conductive member. The first electrochromic material includes an organic material. A second conductive member is formed over at least a portion of the second substrate. A second electrochromic material is formed over at least a portion of the second conductive member. The second electrochromic material includes an inorganic material. An ionic liquid is positioned between the first electrochromic material and the second electrochromic material.

Thin film-based optically variable security devices: From passive to active

NASA Astrophysics Data System (ADS)

Baloukas, Bill

Counterfeiting costs the world economy billions of dollars every year. Aside from financial losses, counterfeiting also poses a great threat to the public's safety, for example through the existence of counterfeit passports (terrorism), pharmaceutical products (health hazards) and even airplane parts (safety issues). Optical security devices (OSDs) have therefore played a critical role in the fight against counterfeiting. It is the aim of the present thesis to show that through the use of metamerism and electrochromic materials, new types of active security devices with interesting features can be created; indeed, most present-day devices are passive in nature. I first demonstrate that the addition of metamerism in the design of interference filters can result in innovative features. Different structures which can be used in transmission and/or in reflection are designed, fabricated, and evaluated. The first structures which are presented here are based on a combination of two different metameric interference filters. Possessing widely different transmission spectra, these filters also offer different angular color shifts and, as a result, offer an opportunity of creating hidden image effects. Despite their interesting properties, such metameric devices are shown to be highly illuminant and observer sensitive; that is the color match is lost under most observation conditions. These issues are solved by a simpler structure based on the juxtaposition of an interference filter and a non-iridescent colored material. Throughout this study, I present the design approach, analyze the filters' sensitivity to deposition errors, and evaluate the performance of prototype devices prepared by dual ion beam sputtering. Following my work on passive metameric systems, I then propose to go one step further by implementing an active component using an electrochromic material. This novel concept, which is based on the joint use of a metameric filter and electrochromic device, offers the possibility of creating various surprising optical effects. Such a system is obviously more challenging to duplicate due to its complexity, but also adds a second level of authentication accessible to specialized personnel. By designing a metameric filter which matches either the bleached or colored state of an electrochromic device, I show that one can generate two hidden image effects: one which appears when the structure is tilted, and the other one which disappears when the electrochromic material is colored under an applied potential. In this specific study, I present an example of a filter that is metameric with the colored state of a tungsten-oxide-based Deb-type electrochromic device. A hybrid device such as presented in the previous study is clearly interesting from a prototype point of view. Unfortunately, having to design and fabricate two individual components would make such a security feature very expensive. Consequently, my goal was to combine both the color shift and electrochromic color change into a single structure. The following study thus demonstrates, that by designing and fabricating an interference filter based on dense and porous WO3, this goal can be achieved. Finally, a second method of fabricating electrochromic interference filters is proposed which results in a significant decrease in the total numbers of layers of the filters. Replacing the porous WO3 films by a WO 3/SiO2 composite allows for much lower refractive indices to be obtained thus resulting in a larger index contrast (0.61 versus 0.22 in the previous study). In this study, I first explore the physical and electrochromic properties of WO3/SiO2 mixtures. I then combine high and low index films in tandem configurations to observe the bleaching/ coloration dynamics. To account for the poor performance of the ITO|Composite|WO 3 film configuration, I also present an explanation based on the differences in electron diffusion coefficients of the films. I conclude this study with the demonstration of an 11 layer electrochromic interference filter based on the alternation of pure WO3 and (WO3)0.17(SiO 2)0.83 films (with a blue to purple angular color shift) as well as a short discussion on some possible solutions for the observed limitations. (Abstract shortened by UMI.).

Integrated device architectures for electrochromic devices

DOEpatents

Frey, Jonathan Mack; Berland, Brian Spencer

2015-04-21

This disclosure describes systems and methods for creating monolithically integrated electrochromic devices which may be a flexible electrochromic device. Monolithic integration of thin film electrochromic devices may involve the electrical interconnection of multiple individual electrochromic devices through the creation of specific structures such as conductive pathway or insulating isolation trenches.

Next-Generation Multifunctional Electrochromic Devices.

PubMed

Cai, Guofa; Wang, Jiangxin; Lee, Pooi See

2016-08-16

The rational design and exploration of electrochromic devices will find a wide range of applications in smart windows for energy-efficient buildings, low-power displays, self-dimming rear mirrors for automobiles, electrochromic e-skins, and so on. Electrochromic devices generally consist of multilayer structures with transparent conductors, electrochromic films, ion conductors, and ion storage films. Synthetic strategies and new materials for electrochromic films and transparent conductors, comprehensive electrochemical kinetic analysis, and novel device design are areas of active study worldwide. These are believed to be the key factors that will help to significantly improve the electrochromic performance and extend their application areas. In this Account, we present our strategies to design and fabricate electrochromic devices with high performance and multifunctionality. We first describe the synthetic strategies, in which a porous tungsten oxide (WO3) film with nearly ideal optical modulation and fast switching was prepared by a pulsed electrochemical deposition method. Multiple strategies, such as sol-gel/inkjet printing methods, hydrothermal/inkjet printing methods, and a novel hybrid transparent conductor/electrochromic layer have been developed to prepare high-performance electrochromic films. We then summarize the recent advances in transparent conductors and ion conductor layers, which play critial roles in electrochromic devices. Benefiting from the developments of soft transparent conductive substrates, highly deformable electrochromic devices that are flexible, foldable, stretchable, and wearable have been achieved. These emerging devices have great potential in applications such as soft displays, electrochromic e-skins, deformable electrochromic films, and so on. We finally present a concept of multifunctional smart glass, which can change its color to dynamically adjust the daylight and solar heat input of the building or protect the users' privacy during the daytime. Energy can also be stored in the smart windows during the daytime simultaneously and be discharged for use in the evening. These results reveal that the electrochromic devices have potential applications in a wide range of areas. We hope that this Account will promote further efforts toward fundamental research on electrochromic materials and the development of new multifunctional electrochromic devices to meet the growing demands for next-generation electronic systems.

Electrochromic nanocomposite films

DOEpatents

Milliron, Delia; Llordes, Anna; Buonsanti, Raffaella; Garcia, Guillermo

2018-04-10

The present invention provides an electrochromic nanocomposite film. In an exemplary embodiment, the electrochromic nanocomposite film, includes (1) a solid matrix of oxide based material and (2) transparent conducting oxide (TCO) nanostructures embedded in the matrix. In a further embodiment, the electrochromic nanocomposite film farther includes a substrate upon which the matrix is deposited. The present invention also provides a method of preparing an electrochromic nanocomposite film.

Couches minces electrochromiques d'oxyde de tungstene dense et poreux pour des applications de controle energetique

NASA Astrophysics Data System (ADS)

Camirand, Hubert

Nanotechnology has modified the landscape of energy generation, energy storage and energy saving devices. Architectural fenestration can extensively benefit from green nanotechnologies. Amongst them, active fenestration or "smart" windows are able to modify their coloration state upon the application of a small electrical voltage, when based on electrochromic materials. In fact, the amount of visible and near-infrared light that can penetrate through the window can be altered. Therefore, their implementation can allow for a significant reduction in energy consumption in buildings. Furthermore, the capability of optimizing indoor comfort is user-controlled, thus an additional degree of freedom is given by electrochromic-based technology. It is worth mentioning that such devices can be largely advantageous in countries with variable seasons, such as here in Canada. As a matter of fact, the large temperature difference between the hot and cold season influences the requirement of impeding or enabling visible and thermal radiation to pass through. This master's thesis is entirely devoted to tungsten trioxide (WO 3), which is the most widely studied electrochromic material. In the present case, WO3 thin films are synthesized by radiofrequency magnetron sputtering. By varying the deposition pressure and power, the porosity content/packing density of the films is modified. This work's main topic is the characterization of electrochromic samples by in situ spectroscopic ellipsometry simultaneously with the application of an electrical voltage in an aqueous electrolytic medium made of sulfuric acid (H2SO 4). The methodology developed here allows for an in-depth study of electro-active materials. To corroborate this, optical properties of WO3 are obtained for a wide range of coloration levels, and these are subsequently used to model the resulting coloration of electrochromic multilayer systems. However, the interface between the dense and porous films affects the coloration/bleaching dynamics. In this regard, interesting research avenues related to electrochromic interference filters are finally proposed.

Electrochromic WO[subscript 3] Films: Nanotechnology Experiments in Instrumental Analysis and Physical Chemistry Laboratories

ERIC Educational Resources Information Center

Hepel, Maria

2008-01-01

This experiment teaches students the methodology of investigating novel properties of materials using new instrumental techniques: atomic force microscopy (AFM), electrochemical quartz crystal nanobalance (EQCN), voltammetric techniques (linear potential scan and chronoamperometry), and light reflectance measurements. The unique capabilities of…

Review on electrochromic devices for automotive glazing

NASA Astrophysics Data System (ADS)

Demiryont, Hulya

1991-12-01

Electrochromic materials have been intensively studied for applications of various switchable optical systems. These materials exhibit adjustable optical absorption upon reversible oxidation/reduction processes. Since a reversible oxidation/reduction phenomenon is provided by electrically-driven electrochemical reactions, these materials are known as electrochromics. There are many publications including proceedings, books, and review articles written on electrochromic (EC) materials and their applications. This paper focuses on conventional and some new electrochromic devices (ECD), their specifications, and applications.

High-contrast and fast electrochromic switching enabled by plasmonics

PubMed Central

Xu, Ting; Walter, Erich C.; Agrawal, Amit; Bohn, Christopher; Velmurugan, Jeyavel; Zhu, Wenqi; Lezec, Henri J.; Talin, A. Alec

2016-01-01

With vibrant colours and simple, room-temperature processing methods, electrochromic polymers have attracted attention as active materials for flexible, low-power-consuming devices. However, slow switching speeds in devices realized to date, as well as the complexity of having to combine several distinct polymers to achieve a full-colour gamut, have limited electrochromic materials to niche applications. Here we achieve fast, high-contrast electrochromic switching by significantly enhancing the interaction of light—propagating as deep-subwavelength-confined surface plasmon polaritons through arrays of metallic nanoslits, with an electrochromic polymer—present as an ultra-thin coating on the slit sidewalls. The switchable configuration retains the short temporal charge-diffusion characteristics of thin electrochromic films, while maintaining the high optical contrast associated with thicker electrochromic coatings. We further demonstrate that by controlling the pitch of the nanoslit arrays, it is possible to achieve a full-colour response with high contrast and fast switching speeds, while relying on just one electrochromic polymer. PMID:26814453

High-contrast and fast electrochromic switching enabled by plasmonics

DOE PAGES

Xu, Ting; Walter, Erich C.; Agrawal, Amit; ...

2016-01-27

With vibrant colours and simple, room-temperature processing methods, electrochromic polymers have attracted attention as active materials for flexible, low-power-consuming devices. However, slow switching speeds in devices realized to date, as well as the complexity of having to combine several distinct polymers to achieve a full-colour gamut, have limited electrochromic materials to niche applications. Here we achieve fast, high-contrast electrochromic switching by significantly enhancing the interaction of light—propagating as deep-subwavelength-confined surface plasmon polaritons through arrays of metallic nanoslits, with an electrochromic polymer—present as an ultra-thin coating on the slit sidewalls. The switchable configuration retains the short temporal charge-diffusion characteristics of thinmore » electrochromic films, while maintaining the high optical contrast associated with thicker electrochromic coatings. In conclusion, we further demonstrate that by controlling the pitch of the nanoslit arrays, it is possible to achieve a full-colour response with high contrast and fast switching speeds, while relying on just one electrochromic polymer.« less

Nanostructured transparent conducting oxide electrochromic device

DOEpatents

Milliron, Delia; Tangirala, Ravisubhash; Llordes, Anna; Buonsanti, Raffaella; Garcia, Guillermo

2016-05-17

The embodiments described herein provide an electrochromic device. In an exemplary embodiment, the electrochromic device includes (1) a substrate and (2) a film supported by the substrate, where the film includes transparent conducting oxide (TCO) nanostructures. In a further embodiment, the electrochromic device further includes (a) an electrolyte, where the nanostructures are embedded in the electrolyte, resulting in an electrolyte, nanostructure mixture positioned above the substrate and (b) a counter electrode positioned above the mixture. In a further embodiment, the electrochromic device further includes a conductive coating deposited on the substrate between the substrate and the mixture. In a further embodiment, the electrochromic device further includes a second substrate positioned above the mixture.

Organic Synthetic Advanced Materials for Optoelectronic and Energy Applications (at Center for Condensed Matter Sciences)

DOE Office of Scientific and Technical Information (OSTI.GOV)

Yen, Hung-Ju

These slides cover Hung-Ju Yen's recent work in the synthesis and structural design of functional materials, which were further used for optoelectronic and energy applications, such as lithium ion battery, solar cell, LED, electrochromic, and fuel cells. This was for a job interview at Center for Condensed Matter Sciences. The following topics are detailed: current challenges for lithium-ion batteries; graphene, graphene oxide and nanographene; nanographenes with various functional groups; fine tune d-spacing through organic synthesis: varying functional group; schematic view of LIBs; nanographenes as LIB anode; rate performance (charging-discharging); electrochromic technology; electrochromic materials; advantages of triphenylamine; requirement of electrochromic materialsmore » for practical applications; low driving voltage and long cycle life; increasing the electroactive sites by multi-step synthetic procedures; synthetic route to starburst triarylamine-based polyamide; electrochromism ranging from visible to NIR region; transmissive to black electrochromism; RGB and CMY electrochromism.« less

Organic Synthetic Advanced Materials for Optoelectronic and Energy Applications (at National Taipei University of Technology)

DOE Office of Scientific and Technical Information (OSTI.GOV)

Yen, Hung-Ju

These slides cover Hung-Ju Yen's recent work in the synthesis and structural design of functional materials, which were further used for optoelectronic and energy applications, such as lithium ion battery, solar cell, LED, electrochromic, and fuel cells. This was for a job interview at National Taipei University of Technology. The following topics are detailed: current challenges for lithium-ion batteries; graphene, graphene oxide and nanographene; nanographenes with various functional groups; fine tune d-spacing through organic synthesis: varying functional group; schematic view of LIBs; nanographenes as LIB anode; rate performance (charging-discharging); electrochromic technology; electrochromic materials; advantages of triphenylamine; requirement of electrochromic materialsmore » for practical applications; low driving voltage and long cycle life; increasing the electroactive sites by multi-step synthetic procedures; synthetic route to starburst triarylamine-based polyamide; electrochromism ranging from visible to NIR region; transmissive to black electrochromism; RGB and CMY electrochromism.« less

Electrochromic projection and writing device

DOEpatents

Branz, Howard M.; Benson, David K.

2002-01-01

A display and projection apparatus includes an electrochromic material and a photoconductive material deposited in tandem used in conjunction with a light filtering means for filtering light transmitted through the electrochromic material. When an electric field is applied across the electrochromic material and the photoconductive material, light that is incident onto the photoconductive material through the surface of the projection apparatus causes the photoconductive material to conduct current locally in proportion to the amount of light incident on the photoconductive material. The flow of current causes the underlying portions of the electrochromic material to switch from an opaque state to a clear or transmissive state, thereby allowing back-light to propagate through the electrochromic material to create a visible image on the surface of the projection apparatus. Reversal of the electric field causes the electrochromic material to revert back to its opaque state, thereby blocking the transmission of back-light and effectively erasing the image from the surface of the projection apparatus.

Organic Synthetic Advanced Materials for Optoelectronic and Energy Applications (at National Sun Yat-sen University) 

DOE Office of Scientific and Technical Information (OSTI.GOV)

Yen, Hung-Ju

These slides cover Hung-Ju Yen's recent work in the synthesis and structural design of functional materials, which were further used for optoelectronic and energy applications, such as lithium ion battery, solar cell, LED, electrochromic, and fuel cells. This was for a job interview at National Sun Yat-sen University. The following topics are detailed: current challenges for lithium-ion batteries; graphene, graphene oxide and nanographene; nanographenes with various functional groups; fine tune d-spacing through organic synthesis: varying functional group; schematic view of LIBs; nanographenes as LIB anode; rate performance (charging-discharging); electrochromic technology; electrochromic materials; advantages of triphenylamine; requirement of electrochromic materials formore » practical applications; low driving voltage and long cycle life; increasing the electroactive sites by multi-step synthetic procedures; synthetic route to starburst triarylamine-based polyamide; electrochromism ranging from visible to NIR region; transmissive to black electrochromism; RGB and CMY electrochromism.« less

Nanocrystal-polymer nanocomposite electrochromic device

DOEpatents

Milliron, Delia; Runnerstrom, Evan; Helms, Brett; Llordes, Anna; Buonsanti, Raffaella; Garcia, Guillermo

2015-12-08

Described is an electrochromic nanocomposite film comprising a solid matrix of an oxide based material, the solid matrix comprising a plurality of transparent conducting oxide (TCO) nanostructures dispersed in the solid matrix and a lithium salt dispersed in the solid matrix. Also described is a near infrared nanostructured electrochromic device having a functional layer comprising the electrochromic nanocomposite film.

Electrochromic Salts, Solutions, and Devices

DOEpatents

Burrell, Anthony K.; Warner, Benjamin P.; McClesky, T. Mark

2008-11-11

Electrochromic salts. Electrochromic salts of dicationic viologens such as methyl viologen and benzyl viologen associated with anions selected from bis(trifluoromethylsulfonyl)imide, bis(perfluoroethylsulfonyl)imide, and tris(trifluoromethylsulfonyl)methide are produced by metathesis with the corresponding viologen dihalide. They are highly soluble in molten quarternary ammonium salts and together with a suitable reductant provide electrolyte solutions that are used in electrochromic windows.

Electrochromic salts, solutions, and devices

DOEpatents

Burrell, Anthony K [Los Alamos, NM; Warner, Benjamin P [Los Alamos, NM; McClesky,7,064,212 T. Mark

2006-06-20

Electrochromic salts. Electrochromic salts of dicationic viologens such as methyl viologen and benzyl viologen associated with anions selected from bis(trifluoromethylsulfonyl)imide, bis(perfluoroethylsulfonyl)imide, and tris(trifluoromethylsulfonyl)methide are produced by metathesis with the corresponding viologen dihalide. They are highly soluble in molten quarternary ammonium salts and together with a suitable reductant provide electrolyte solutions that are used in electrochromic windows.

Electrochromic Salts, Solutions, and Devices

DOEpatents

Burrell, Anthony K.; Warner, Benjamin P.; McClesky, T. Mark

2008-10-14

Electrochromic salts. Electrochromic salts of dicationic viologens such as methyl viologen and benzyl viologen associated with anions selected from bis(trifluoromethylsulfonyl)imide, bis(perfluoroethylsulfonyl)imide, and tris(trifluoromethylsulfonyl)methide are produced by metathesis with the corresponding viologen dihalide. They are highly soluble in molten quarternary ammonium salts and together with a suitable reductant provide electrolyte solutions that are used in electrochromic windows.

Electrochromic device using mercaptans and organothiolate compounds

DOEpatents

Lampert, Carl M.; Ma, Yan-ping; Doeff, Marca M.; Visco, Steven

1995-01-01

An electrochromic cell is disclosed which comprises an electrochromic layer and a composite ion counter electrode for transporting ions. The counter electrode further comprises a polymer electrolyte material and an organosulfur material in which, in its discharged state, the organosulfur material is further comprised of a mercaptan or an organothiolate. In one preferred embodiment, both the electrochromic electrode and the counter electrode are transparent either to visible light or to the entire electromagnetic spectrum in both charged and discharged states. An electrochromic device is disclosed which comprises one or more electrochromic electrodes encased in glass or plastic plates on the inner surface of each of which is formed a transparent electrically conductive film. Electrical contacts, which are in electrical contact with the conductive films, facilitate external electrical connection.

Electrochromic counter electrode

DOEpatents

Lee, Se-Hee; Tracy, C. Edwin; Pitts, J. Roland; Jorgensen, Gary J.

2005-02-22

The present invention discloses an amorphous material comprising nickel oxide doped with tantalum that is an anodically coloring electrochromic material. The material of the present invention is prepared in the form of an electrode (200) having a thin film (202) of an electrochromic material of the present invention residing on a transparent conductive film (203). The material of the present invention is also incorporated into an electrochromic device (100) as a thin film (102) in conjunction with a cathodically coloring prior art electrochromic material layer (104) such that the devices contain both anodically coloring (102) and cathodically coloring (104) layers. The materials of the electrochromic layers in these devices exhibit broadband optical complimentary behavior, ionic species complimentary behavior, and coloration efficiency complimentary behavior in their operation.

The optical and electrochemical properties of electrochromic films: WO3+xV2O5

NASA Astrophysics Data System (ADS)

Li, Zhuying; Liu, Hui; Liu, Ye; Yang, Shaohong; Liu, Yan; Wang, Chong

2010-05-01

Since Deb's experiment in 1973 on the electrochromic effect, transmissive electrochromic films exhibit outstanding potential as energy efficient window controls which allow dynamic control of the solar energy transmission. These films with non-volatile memory, once in the coloured state, remain in the same state even after removal of the field. The optical and electrochemical properties of electrochromic films using magnetron sputter deposition tungsten oxide thin films and vanadium oxide doped tungsten-vanadium oxide thin films on ITO coated glass were investigated. From the UV region of the transmittance spectra, the optical band gap energy from the fundamental absorption edge can be determined. And the Cyclic voltammograms of these thin films in 1 mol LiClO4 propylene carbonate electrolyte (LIPC) were measured and analysed. The anode electrochromic V2O5 doped cathode electrochromic WO3 could make films colour changing while the transmittance of films keeped invariance. These performance characteristics make tungstenvanadium oxide colour changeably thin films are suitable for electrochromic windows applications.

Electrochromic device using mercaptans and organothiolate compounds

DOEpatents

Lampert, C.M.; Ma, Y.P.; Doeff, M.M.; Visco, S.

1995-08-15

An electrochromic cell is disclosed which comprises an electrochromic layer and a composite ion counter electrode for transporting ions. The counter electrode further comprises a polymer electrolyte material and an organosulfur material in which, in its discharged state, the organosulfur material is further comprised of a mercaptan or an organothiolate. In one preferred embodiment, both the electrochromic electrode and the counter electrode are transparent either to visible light or to the entire electromagnetic spectrum in both charged and discharged states. An electrochromic device is disclosed which comprises one or more electrochromic electrodes encased in glass or plastic plates on the inner surface of each of which is formed a transparent electrically conductive film. Electrical contacts, which are in electrical contact with the conductive films, facilitate external electrical connection. 5 figs.

Hysteretic Tricolor Electrochromic Systems Based on the Dynamic Redox Properties of Unsymmetrically Substituted Dihydrophenanthrenes and Biphenyl-2,2'-Diyl Dications: Efficient Precursor Synthesis by a Flow Microreactor Method

PubMed Central

Ishigaki, Yusuke; Suzuki, Takanori; Nishida, Jun-ichi; Nagaki, Aiichiro; Takabayashi, Naofumi; Kawai, Hidetoshi; Fujiwara, Kenshu; Yoshida, Jun-ichi

2011-01-01

A series of biphenyl-2,2'-diylbis(diarylmethanol)s 3, which have two kinds of aryl groups at the bay region, were efficiently obtained by integrated flow microreactor synthesis. The diols 3NO/NX are the precursors of unsymmetric biphenylic dications 2NO/NX2+, which are transformed into the corresponding dihydrophenanthrenes 1NO/NX via 2NO/NX+• upon reduction, when they exhibit two-stage color changes. On the other hand, the steady-state concentration of the intermediate 2NO/NX+• is negligible during the oxidation of 1NO/NX to 2NO/NX2+, which reflects unique tricolor electrochromicity with a hysteretic pattern of color change [color 1→color 2→color 3→color 1]. PMID:28824114

Low voltage solid-state lateral coloration electrochromic device

DOEpatents

Tracy, C.E.; Benson, D.K.; Ruth, M.R.

1984-12-21

A solid-state transition metal oxide device comprising a plurality of layers having a predisposed orientation including an electrochromic oxide layer. Conductive material including anode and cathode contacts is secured to the device. Coloration is actuated within the electrochromic oxide layer after the application of a predetermined potential between the contacts. The coloration action is adapted to sweep or dynamically extend across the length of the electrochromic oxide layer.

Low voltage solid-state lateral coloration electrochromic device

DOEpatents

Tracy, C. Edwin; Benson, David K.; Ruth, Marta R.

1987-01-01

A solid-state transition metal oxide device comprising a plurality of lay having a predisposed orientation including an electrochromic oxide layer. Conductive material including anode and cathode contacts is secured to the device. Coloration is actuated within the electrochromic oxide layer after the application of a predetermined potential between the contacts. The coloration action is adapted to sweep or dynamically extend across the length of the electrochromic oxide layer.

Electrochromic device based on electrospun WO{sub 3} nanofibers

DOE Office of Scientific and Technical Information (OSTI.GOV)

Dulgerbaki, Cigdem; Maslakci, Neslihan Nohut; Komur, Ali Ihsan

2015-12-15

Highlights: • WO{sub 3} electrochromic nanofibers were prepared by electrospinning technique. • WO{sub 3} nanofibers switched reversibly from transparent to blue color. • Electrochromic device was assembled using ionic liquid based gel electrolyte. • Significant optical modulation and excellent cycling stability were achieved for ECD. - Abstract: The tungsten oxide (WO{sub 3}) nanofibers were grown directly onto an ITO-coated glass via an electrospinning method for electrochromic applications. The electrochromic properties of WO{sub 3} nanofibers were investigated in the presence of different electrolytes including a series of ionic liquids and classic LiClO{sub 4}-PC system. A significant optical modulation of 20.82% atmore » 760 nm, reversible coloration with efficiency of 64.58 cm{sup 2}/C and excellent cycling stability were achieved for the nanofiber electrochromic device (ECD) with ionic liquid based gel electrolyte.« less

Processing and property evaluation of tungsten-based mixed oxides for photovoltaics and optoelectronics

NASA Astrophysics Data System (ADS)

Vargas, Mirella

Tungsten Oxide (WO3) films and low-dimensional structures have proven to be promising candidates in the fields of photonics and electronics. WO3 is a well-established n-type semiconductor characterized by unique electrochromic behavior, an ideal optical band gap that permits transparency over a wide spectral range, and high chemical integrity. The plethora of diverse properties endow WO3 to be highly effective in applications related to electrochromism, gas sensing, and deriving economical energy. Compared to the bulk films, a materials system involving WO3 and a related species (elements or metal oxides) offer the opportunity to tailor the electrochromic response, and an overall enhancement of the physio-chemical and optical properties. In the present case, WO3 and TiO2 composite films have been fabricated by reactive magnetron sputtering employing W/Ti alloy targets, and individual W and Ti targets for co-sputtering. Composite WO3-TiO2 films were fabricated with variable chemical composition and the effect of variable bulk chemistry on film structure, surface/interface chemistry and chemical valence state of the W and Ti cations was investigated in detail. The process-property relationships between composition and physical properties for the films deposited by using W/Ti alloy targets of variable Ti content are associated with decreases in the deposition rate of the WO3-TiO2 films due to the lower sputter yield of the strongly bonded TiO2 formed on the target surface. Additionally, for the co-sputtered films using variable tungsten power, the optical properties demonstrate unique optical modulation. The changes associated with the physical color of the films demonstrate the potential to tailor the optical behavior for the design and fabrication of multilayer photovoltaic and catalytic devices. The process-structure-property correlation derived in this work will provide a road-map to optimize and produce W-Ti-O thin films with desired properties for a given technological application.

Application of Nanostructures in Electrochromic Materials and Devices: Recent Progress.

PubMed

Wang, Jin Min; Sun, Xiao Wei; Jiao, Zhihui

2010-11-26

The recent progress in application of nanostructures in electrochromic materials and devices is reviewed. ZnO nanowire array modified by viologen and WO₃, crystalline WO₃ nanoparticles and nanorods, mesoporous WO₃ and TiO₂, poly(3,4-ethylenedioxythiophene) nanotubes, Prussian blue nanoinks and nanostructures in switchable mirrors are reviewed. The electrochromic properties were significantly enhanced by applying nanostructures, resulting in faster switching responses, higher stability and higher optical contrast. A perspective on the development trends in electrochromic materials and devices is also proposed.

Electrochromic material and electro-optical device using same

DOEpatents

Cogan, Stuart F.; Rauh, R. David

1992-01-01

An oxidatively coloring electrochromic layer of composition M.sub.y CrO.sub.2+x (0.33.ltoreq.y.ltoreq.2.0 and x.ltoreq.2) where M=Li, Na or K with improved transmittance modulation, improved thermal and environmental stability, and improved resistance to degradation in organic liquid and polymeric electrolytes. The M.sub.y CrO.sub.2+x provides complementary optical modulation to cathodically coloring materials in thin-film electrochromic glazings and electrochromic devices employing polymeric Li.sup.+ ion conductors.

Electrochromic material and electro-optical device using same

DOEpatents

Cogan, S.F.; Rauh, R.D.

1992-01-14

An oxidatively coloring electrochromic layer of composition M[sub y]CrO[sub 2+x] (0.33[le]y[le]2.0 and x[le]2) where M=Li, Na or K with improved transmittance modulation, improved thermal and environmental stability, and improved resistance to degradation in organic liquid and polymeric electrolytes. The M[sub y]CrO[sub 2+x] provides complementary optical modulation to cathodically coloring materials in thin-film electrochromic glazings and electrochromic devices employing polymeric Li[sup +] ion conductors. 12 figs.

Light modulating device

DOEpatents

Rauh, R. David; Goldner, Ronald B.

1989-01-01

In a device for transmitting light, means for controlling the transmissivity of the device, including a ceramic, reversibly electrochromic, crystalline element having a highly reflective state when injected with electrons and charge compensating ions and a highly transmissive state when the electrons and ions are removed, the crystalline element being characterized as having a reflectivity of at least 50% in the reflective state and not greater than 10% in the transmissive state, and means for modulating the crystalline element between the reflective and transmissive states by injecting ions into the crystalline element in response to an applied electrical current of a first polarity and removing the ions in response to an applied electrical current of a second polarity.

Light modulating device

DOEpatents

Rauh, R.D.; Goldner, R.B.

1989-12-26

In a device for transmitting light, means for controlling the transmissivity of the device, including a ceramic, reversibly electrochromic, crystalline element having a highly reflective state when injected with electrons and charge compensating ions and a highly transmissive state when the electrons and ions are removed, the crystalline element being characterized as having a reflectivity of at least 50% in the reflective state and not greater than 10% in the transmissive state, and means for modulating the crystalline element between the reflective and transmissive states by injecting ions into the crystalline element in response to an applied electrical current of a first polarity and removing the ions in response to an applied electrical current of a second polarity are disclosed. 1 fig.

Electrochromic nickel oxide simultaneously doped with lithium and a metal dopant

DOEpatents

Gillaspie, Dane T; Weir, Douglas G

2014-04-01

An electrochromic device comprising a counter electrode layer comprised of lithium metal oxide which provides a high transmission in the fully intercalated state and which is capable of long-term stability, is disclosed. Methods of making an electrochromic device comprising such a counter electrode are also disclosed.

Electrochromic nickel oxide simultaneously doped with lithium and a metal dopant

DOEpatents

Gillaspie, Dane T.; Weir, Douglas Glenn John

2017-05-16

An electrochromic device comprising a counter electrode layer comprised of lithium metal oxide which provides a high transmission in the fully intercalated state and which is capable of long-term stability, is disclosed. Methods of making an electrochromic device comprising such a counter electrode are also disclosed.

Application of Nanostructures in Electrochromic Materials and Devices: Recent Progress

PubMed Central

Wang, Jinmin; Sun, Xiao Wei; Jiao, Zhihui

2010-01-01

The recent progress in application of nanostructures in electrochromic materials and devices is reviewed. ZnO nanowire array modified by viologen and WO3, crystalline WO3 nanoparticles and nanorods, mesoporous WO3 and TiO2, poly(3,4-ethylenedioxythiophene) nanotubes, Prussian blue nanoinks and nanostructures in switchable mirrors are reviewed. The electrochromic properties were significantly enhanced by applying nanostructures, resulting in faster switching responses, higher stability and higher optical contrast. A perspective on the development trends in electrochromic materials and devices is also proposed. PMID:28883368

Photochromic, electrochromic, photoelectrochromic and photovoltaic devices

DOEpatents

Kostecki, Robert; McLarnon, Frank R.

2000-01-01

A light activated photoelectrochromic device is formed of a two-component system formed of a photoactive charge carrier generating material and electrochromic material (plus an elecrolyte). Light interacts with a semiconductive material to generate hole-electron charge carriers which cause a redox reaction in the electrochromic material. One device is formed of hydrated nickel oxide as the electrochromic layer and polycrystalline titanium dioxide as the charge generating material. The materials may be formed as discrete layers or mixed together. Because of the direct charge transfer between the layers, a circuit to apply a voltage to drive the electrochromic reaction is not required, although one can be used to enhance the reaction. The hydrated nickel oxide-titanium dioxide materials can also be used to form a photovoltaic device for generating electricity.

Controllable Electrochromic Polyamide Film and Device Produced by Facile Ultrasonic Spray-coating.

PubMed

Liu, Huan-Shen; Chang, Wei-Chieh; Chou, Chin-Yen; Pan, Bo-Cheng; Chou, Yi-Shan; Liou, Guey-Sheng; Liu, Cheng-Liang

2017-09-20

Thermally stable TPA-OMe polyamide films with high transmittance modulation in response to applied potential are formed by facile ultrasonic spray-coating. Four processing conditions (Film A, Film B, Film C and Film D) through tuning both solution concentrations and deposition temperatures can be utilized for the formation of wet and dry deposited films with two film thickness intervals. The electrochromic results show that the dry deposited rough films at higher deposition temperature generally reveal a faster electrochromic response, lower charge requirements (Q) and less conspicuous color changes (smaller optical density change (ΔOD) and lightness change (ΔL*)) during the oxidation process as compared to the wet deposited smooth films at lower deposition temperature. Moreover, thicker electrochromic films from increased solution concentration exhibit more obvious changes between coloration and bleaching transition. All these four polyamide films display colorless-to-turquoise electrochromic switching with good redox stability. The large scale patterned electrochromic film and its application for assembled device (10 × 10 cm 2 in size) are also produced and reversibly operated for color changes. These represent a major solution-processing technique produced by ultrasonic spray-coating method towards scalable and cost-effective production, allowing more freedoms to facilitate the designed electrochromic devices as required.

Electrochromic Molecular Imprinting Sensor for Visual and Smartphone-Based Detections.

PubMed

Capoferri, Denise; Álvarez-Diduk, Ruslan; Del Carlo, Michele; Compagnone, Dario; Merkoçi, Arben

2018-05-01

Electrochromic effect and molecularly imprinted technology have been used to develop a sensitive and selective electrochromic sensor. The polymeric matrices obtained using the imprinting technology are robust molecular recognition elements and have the potential to mimic natural recognition entities with very high selectivity. The electrochromic behavior of iridium oxide nanoparticles (IrOx NPs) as physicochemical transducer together with a molecularly imprinted polymer (MIP) as recognition layer resulted in a fast and efficient translation of the detection event. The sensor was fabricated using screen-printing technology with indium tin oxide as a transparent working electrode; IrOx NPs where electrodeposited onto the electrode followed by thermal polymerization of polypyrrole in the presence of the analyte (chlorpyrifos). Two different approaches were used to detect and quantify the pesticide: direct visual detection and smartphone imaging. Application of different oxidation potentials for 10 s resulted in color changes directly related to the concentration of the analyte. For smartphone imaging, at fixed potential, the concentration of the analyte was dependent on the color intensity of the electrode. The electrochromic sensor detects a highly toxic compound (chlorpyrifos) with a 100 fM and 1 mM dynamic range. So far, to the best of our knowledge, this is the first work where an electrochromic MIP sensor uses the electrochromic properties of IrOx to detect a certain analyte with high selectivity and sensitivity.

Electroactive Polyurea Bearing Oligoaniline Pendants: Electrochromic and Anticorrosive Properties

DTIC Science & Technology

2014-12-26

unlimited. Electroactive polyurea bearing oligoaniline pendants: Electrochromic and anticorrosive properties The views, opinions and/or findings contained...Park, NC 27709-2211 oligoaniline, anticorrosive surfaces, conjugated surfaces REPORT DOCUMENTATION PAGE 11. SPONSOR/MONITOR’S REPORT NUMBER(S) 10...Durham, NH 03824 -2585 ABSTRACT Electroactive polyurea bearing oligoaniline pendants: Electrochromic and anticorrosive properties Report Title In this

An UV photochromic memory effect in proton-based WO3 electrochromic devices

NASA Astrophysics Data System (ADS)

Zhang, Yong; Lee, S.-H.; Mascarenhas, A.; Deb, S. K.

2008-11-01

We report an UV photochromic memory effect on a standard proton-based WO3 electrochromic device. It exhibits two memory states, associated with the colored and bleached states of the device, respectively. Such an effect can be used to enhance device performance (increasing the dynamic range), re-energize commercial electrochromic devices, and develop memory devices.

Characterization of dynamic thermal control schemes and heat transfer pathways for incorporating variable emissivity electrochromic materials into a space suit heat rejection system

NASA Astrophysics Data System (ADS)

Massina, Christopher James

The feasibility of conducting long duration human spaceflight missions is largely dependent on the provision of consumables such as oxygen, water, and food. In addition to meeting crew metabolic needs, water sublimation has long served as the primary heat rejection mechanism in space suits during extravehicular activity (EVA). During a single eight hour EVA, approximately 3.6 kg (8 lbm) of water is lost from the current suit. Reducing the amount of expended water during EVA is a long standing goal of space suit life support systems designers; but to date, no alternate thermal control mechanism has demonstrated the ability to completely eliminate the loss. One proposed concept is to convert the majority of a space suit's surface area into a radiator such that the local environment can be used as a radiative thermal sink for rejecting heat without mass loss. Due to natural variations in both internal (metabolic) loads and external (environmental) sink temperatures, radiative transport must be actively modulated in order to maintain an acceptable thermal balance. Here, variable emissivity electrochromic devices are examined as the primary mechanism for enabling variable heat rejection. This dissertation focuses on theoretical and empirical evaluations performed to determine the feasibility of using a full suit, variable emissivity radiator architecture for space suit thermal control. Operational envelopes are described that show where a given environment and/or metabolic load combination may or may not be supported by the evaluated thermal architecture. Key integration considerations and guidelines include determining allowable thermal environments, defining skin-to-radiator heat transfer properties, and evaluating required electrochromic performance properties. Analysis also considered the impacts of dynamic environmental changes and the architecture's extensibility to EVA on the Martian surface. At the conclusion of this work, the full suit, variable emissivity radiator architecture is considered to be at a technology readiness level of 3/4, indicating that analytical proof-of-concept and component level validation in a laboratory environment have been completed. While this is not a numeric increase from previous investigations, these contributions are a significant iteration within those levels. These results improve the understanding of the capabilities provided by the full suit, variable emissivity architecture.

Characterization of MAPLE deposited WO3 thin films for electrochromic applications

NASA Astrophysics Data System (ADS)

Boyadjiev, S. I.; Stefan, N.; Szilágyi, I. M.; Mihailescu, N.; Visan, A.; Mihailescu, I. N.; Stan, G. E.; Besleaga, C.; Iliev, M. T.; Gesheva, K. A.

2017-01-01

Tungsten trioxide (WO3) is a widely studied material for electrochromic applications. The structure, morphology and optical properties of WO3 thin films, grown by matrix assisted pulsed laser evaporation (MAPLE) from monoclinic WO3 nano-sized particles, were investigated for their possible application as electrochromic layers. A KrF* excimer (λ=248 nm, ζFWHM=25 ns) laser source was used in all experiments. The MAPLE deposited WO3 thin films were studied by atomic force microscopy (AFM), grazing incidence X-ray diffraction (GIXRD) and Fourier transform infrared spectroscopy (FTIR). Cyclic voltammetry measurements were also performed, and the coloring and bleaching were observed. The morpho-structural investigations disclosed the synthesis of single-phase monoclinic WO3 films consisting of crystalline nano-grains embedded in an amorphous matrix. All thin films showed good electrochromic properties, thus validating application of the MAPLE deposition technique for the further development of electrochromic devices.

Aligned coaxial tungsten oxide-carbon nanotube sheet: a flexible and gradient electrochromic film.

PubMed

Yao, Zhaojun; Di, Jiangtao; Yong, Zhenzhong; Zhao, Zhigang; Li, Qingwen

2012-08-25

We develop a simple dry wrapping method to fabricate a tungsten oxide (WO(3))/carbon nanotube (CNT) cable, in which WO(3) layers act as an electrochromic component while aligned CNTs as the core provide mechanical support and an anisotropic, continuous electron transport pathway. Interestingly, the resultant cable material exhibits an obvious gradient electrochromic phenomenon.

Self bleaching photoelectrochemical-electrochromic device

DOEpatents

Bechinger, Clemens S.; Gregg, Brian A.

2002-04-09

A photoelectrochemical-electrochromic device comprising a first transparent electrode and a second transparent electrode in parallel, spaced relation to each other. The first transparent electrode is electrically connected to the second transparent electrode. An electrochromic material is applied to the first transparent electrode and a nanoporous semiconductor film having a dye adsorbed therein is applied to the second transparent electrode. An electrolyte layer contacts the electrochromic material and the nanoporous semiconductor film. The electrolyte layer has a redox couple whereby upon application of light, the nanoporous semiconductor layer dye absorbs the light and the redox couple oxidizes producing an electric field across the device modulating the effective light transmittance through the device.

Zinc oxyfluoride transparent conductor

DOEpatents

Gordon, Roy G.

1991-02-05

Transparent, electrically conductive and infrared-reflective films of zinc oxyfluoride are produced by chemical vapor deposition from vapor mixtures of zinc, oxygen and fluorine-containing compounds. The substitution of fluorine for some of the oxygen in zinc oxide results in dramatic increases in the electrical conductivity. For example, diethyl zinc, ethyl alcohol and hexafluoropropene vapors are reacted over a glass surface at 400.degree. C. to form a visibly transparent, electrically conductive, infrared reflective and ultraviolet absorptive film of zinc oxyfluoride. Such films are useful in liquid crystal display devices, solar cells, electrochromic absorbers and reflectors, energy-conserving heat mirrors, and antistatic coatings.

Low-cost, highly transparent flexible low-e coating film to enable electrochromic windows with increased energy savings

DOE Office of Scientific and Technical Information (OSTI.GOV)

Berland, Brian; Hollingsworth, Russell

Five Quads of energy are lost through windows annually in the U.S. Low-e coatings are increasingly employed to reduce the wasted energy. Most commonly, the low-e coating is an oxide material applied directly to the glass at high temperature. With over 100,000,000 existing homes, a retrofit product is crucial to achieve widespread energy savings. Low-e films, i.e. coatings on polymeric substrates, are now also available to meet this need. However, the traditional oxide materials and process is incompatible with low temperature plastics. Alternate high performing low-e films typically incorporate materials that limit visible transmission to 35% or less. Further, themore » cost is high. The objective of this award was to develop a retrofit, integrated low-e/electrochromic window film to dramatically reduce energy lost through windows. While field testing of state-of-the-art electrochromic (EC) windows show the energy savings are maximized if a low-e coating is used in conjunction with the EC, available low-e films have a low visible transmission (~70% or less) that limits the achievable clear state and therefore, appearance and energy savings potential. Comprehensive energy savings models were completed at Lawrence Berkeley National Lab (LBNL). A parametric approach was used to project energy usage for windows with a large range of low-e properties across all U.S. climate zones, without limiting the study to materials that had already been produced commercially or made in a lab. The model enables projection of energy savings for low-e films as well as integrated low-e/EC products. This project developed a novel low-e film, optimized for compatibility with EC windows, using low temperature, high deposition rate processes for the growth of low-e coatings on plastic films by microwave plasma enhanced chemical vapor deposition. Silica films with good density and optical properties were demonstrated at deposition rates as high as 130Å/sec. A simple bi-layer low-e stack of silica and a transparent conductive oxide demonstrated 90% visible transmission with high thermal infrared reflectivity characteristic of conventional low-e coatings. A slightly more complex stack provided high solar infrared reflection without sacrificing visible transmission or thermal infrared reflection. Successful completion of the effort produced a prototype integrated low-e, dynamic window film with characterized energy saving potential. Cost modeling for the passive bi-layer, low-e film projects a manufacturing cost of ~$0.50/ft2 for a plant with 10M ft2/yr capacity. The novel thin film processes developed here enable high deposition rate (low cost), optical quality oxide coatings at low temperatures. When combined with engineered materials, ITN’s coating will result in low-cost, low-e films that reflect a high degree of infrared radiation without substantially reducing the visible transmission. The resultant window film will improve the U-value and achieve SHGC improvements over bare glass. The new low-e coating will be particularly attractive when combined with an electrochromic film. Low-e coating design guided by energy savings modeling allows customization of the product for different climate zones.« less

The photo- and electrophysical properties of curcumin in aqueous solution

NASA Astrophysics Data System (ADS)

Kim, Sung-Hoon; Gwon, Seon-Yeong; Burkinshaw, S. M.; Son, Young-A.

2010-08-01

An investigation of the photo- and electrophysical properties of curcumin (1,7-bis[4-hydroxy-3-methoxyphenyl]-1,6-heptadiene-3,5-dione) revealed well-defined color changes upon the addition of Hg 2+ or OH -. Curcumin exhibited high selectivity for Hg 2+ ions, as compared with Cu 2+, Fe 2+, Fe 3+, Zn 2+, Na + and Ni 2+ ions in DMSO/H 2O (5:1, v/v) which was attributed to the formation of a 4:1 Hg 2+-curcumin coordination complex. Spectral responses at λmax = 434 nm revealed that curcumin can function as a NOR logic gate with OH - and Hg 2+ as input variables. The electrochromic properties of curcumin were studied using an ITO/curcumin-Bu 4NClO 4/ITO cell. The electrochromic cell colored red at 3 V, but changed to yellow in open-circuit condition.

Linear topology in amorphous metal oxide electrochromic networks obtained via low-temperature solution processing

NASA Astrophysics Data System (ADS)

Llordés, Anna; Wang, Yang; Fernandez-Martinez, Alejandro; Xiao, Penghao; Lee, Tom; Poulain, Agnieszka; Zandi, Omid; Saez Cabezas, Camila A.; Henkelman, Graeme; Milliron, Delia J.

2016-12-01

Amorphous transition metal oxides are recognized as leading candidates for electrochromic window coatings that can dynamically modulate solar irradiation and improve building energy efficiency. However, their thin films are normally prepared by energy-intensive sputtering techniques or high-temperature solution methods, which increase manufacturing cost and complexity. Here, we report on a room-temperature solution process to fabricate electrochromic films of niobium oxide glass (NbOx) and `nanocrystal-in-glass’ composites (that is, tin-doped indium oxide (ITO) nanocrystals embedded in NbOx glass) via acid-catalysed condensation of polyniobate clusters. A combination of X-ray scattering and spectroscopic characterization with complementary simulations reveals that this strategy leads to a unique one-dimensional chain-like NbOx structure, which significantly enhances the electrochromic performance, compared to a typical three-dimensional NbOx network obtained from conventional high-temperature thermal processing. In addition, we show how self-assembled ITO-in-NbOx composite films can be successfully integrated into high-performance flexible electrochromic devices.

Functionalized Poly(3,4-ethylenedioxy bithiophene) Films for Tuning Electrochromic and Thermoelectric Properties.

PubMed

Hu, Yongjing; Liu, Xiaofang; Jiang, Fengxing; Zhou, Weiqiang; Liu, Congcong; Duan, Xuemin; Xu, Jingkun

2017-10-05

Conductive thiophene-based polymers have garnered great attention for use in organic electron materials such as electrochromic and thermoelectric materials. However, they suffer from poor electron transport properties and long-term stability, leading to limited development eventually. Here, we proposed a strategy of functionalized thiophene-based polymers with oligo(ethylene glycol) or alkyl side chains and synthesized a series of poly(3,4-ethylenedioxy bithiophene)s (PEDTs) to tune their electrochromic and thermoelectric properties. An alkyl group bearing electronic ability at the thiophene ring effectively achieved a large increase in the electrical conductivity with nearly invariable Seebeck coefficient, resulting in an enhancement by 1 order of magnitude for the thermoelectric power factor. Moreover, the electrochromic properties of functionalized PEDTs gained an effective improvement in the optical contrast and coloration efficiency as well as stability with multicolor changes between neutral and oxidized states. The functionalized PEDTs can be proposed as an alternative strategy to tune the electrochromic and thermoelectric properties for organic polymer materials.

Double-Sided Electrochromic Device Based on Metal-Organic Frameworks.

PubMed

Mjejri, Issam; Doherty, Cara M; Rubio-Martinez, Marta; Drisko, Glenna L; Rougier, Aline

2017-11-22

Devices displaying controllably tunable optical properties through an applied voltage are attractive for smart glass, mirrors, and displays. Electrochromic material development aims to decrease power consumption while increasing the variety of attainable colors, their brilliance, and their longevity. We report the first electrochromic device constructed from metal organic frameworks (MOFs). Two MOF films, HKUST-1 and ZnMOF-74, are assembled so that the oxidation of one corresponds to the reduction of the other, allowing the two sides of the device to simultaneously change color. These MOF films exhibit cycling stability unrivaled by other MOFs and a significant optical contrast in a lithium-based electrolyte. HKUST-1 reversibly changed from bright blue to light blue and ZnMOF-74 from yellow to brown. The electrochromic device associates the two MOF films via a PMMA-lithium based electrolyte membrane. The color-switching of these MOFs does not arise from an organic-linker redox reaction, signaling unexplored possibilities for electrochromic MOF-based materials.

DNA Based Electrochromic and Photovoltaic Cells

DTIC Science & Technology

2012-01-01

electrolyte/CeO2- TiO2 /ITO/glass configuration [29]. 2. Experimental 2.1 Gel polymeric electrolytes The electrolytes were prepared according to the...transparent membranes. Blend samples were also prepared by the addition of other macromolecules (gelatin), synthetic polymers, such as poly(ethylene...Electrochromic devices Electrochromic devices with the glass/ITO/WO3/DNA-based electrolyte/CeO2- TiO2 /ITO/glass configuration were obtained by assembling

Electrochromic Asymmetric Supercapacitor Windows Enable Direct Determination of Energy Status by the Naked Eye.

PubMed

Zhong, Ying; Chai, Zhisheng; Liang, Zhimin; Sun, Peng; Xie, Weiguang; Zhao, Chuanxi; Mai, Wenjie

2017-10-04

Because of the popularity of smart electronics, multifunctional energy storage devices, especially electrochromic supercapacitors (SCs), have attracted tremendous research interest. Herein, a solid-state electrochromic asymmetric SC (ASC) window is designed and fabricated by introducing WO 3 and polyaniline as the negative and positive electrodes, respectively. The two complementary materials contribute to the outstanding electrochemical and electrochromic performances of the fabricated device. With an operating voltage window of 1.4 V and an areal capacitance of 28.3 mF cm -2 , the electrochromic devices show a high energy density of 7.7 × 10 -3 mW h cm -2 . Meanwhile, they exhibit an obvious and reversible color transition between light green (uncharged state) and dark blue (charged state), with an optical transmittance change between 55 and 12% at a wavelength of 633 nm. Hence, the energy storage level of the ASC is directly related to its color and can be determined by the naked eye, which means it can be incorporated with other energy cells to visual display their energy status. Particularly, a self-powered and color-indicated system is achieved by combining the smart windows with commercial solar cell panels. We believe that the novel electrochromic ASC windows will have great potential application for both smart electronics and smart buildings.

Large-Scale Multifunctional Electrochromic-Energy Storage Device Based on Tungsten Trioxide Monohydrate Nanosheets and Prussian White.

PubMed

Bi, Zhijie; Li, Xiaomin; Chen, Yongbo; He, Xiaoli; Xu, Xiaoke; Gao, Xiangdong

2017-09-06

A high-performance electrochromic-energy storage device (EESD) is developed, which successfully realizes the multifunctional combination of electrochromism and energy storage by constructing tungsten trioxide monohydrate (WO 3 ·H 2 O) nanosheets and Prussian white (PW) film as asymmetric electrodes. The EESD presents excellent electrochromic properties of broad optical modulation (61.7%), ultrafast response speed (1.84/1.95 s), and great coloration efficiency (139.4 cm 2 C -1 ). In particular, remarkable cyclic stability (sustaining 82.5% of its initial optical modulation after 2500 cycles as an electrochromic device, almost fully maintaining its capacitance after 1000 cycles as an energy storage device) is achieved. The EESD is also able to visually detect the energy storage level via reversible and fast color changes. Moreover, the EESD can be combined with commercial solar cells to constitute an intelligent operating system in the architectures, which would realize the adjustment of indoor sunlight and the improvement of physical comfort totally by the rational utilization of solar energy without additional electricity. Besides, a scaled-up EESD (10 × 11 cm 2 ) is further fabricated as a prototype. Such promising EESD shows huge potential in practically serving as electrochromic smart windows and energy storage devices.

Photoresponsive Smart Coloration Electrochromic Supercapacitor.

PubMed

Yun, Tae Gwang; Kim, Donghyuk; Kim, Yong Ho; Park, Minkyu; Hyun, Seungmin; Han, Seung Min

2017-08-01

Electrochromic devices have been widely adopted in energy saving applications by taking advantage of the electrode coloration, but it is critical to develop a new electrochromic device that can undergo smart coloration and can have a wide spectrum in transmittance in response to input light intensity while also functioning as a rechargeable energy storage system. In this study, a photoresponsive electrochromic supercapacitor based on cellulose-nanofiber/Ag-nanowire/reduced-graphene-oxide/WO 3 -composite electrode that is capable of undergoing "smart" reversible coloration while simultaneously functioning as a reliable energy-storage device is developed. The fabricated device exhibits a high coloration efficiency of 64.8 cm 2 C -1 and electrochemical performance with specific capacitance of 406.0 F g -1 , energy/power densities of 40.6-47.8 Wh kg -1 and 6.8-16.9 kW kg -1 . The electrochromic supercapacitor exhibits excellent cycle reliability, where 75.0% and 94.1% of its coloration efficiency and electrochemical performance is retained, respectively, beyond 10 000 charge-discharge cycles. Cyclic fatigue tests show that the developed device is mechanically durable and suitable for wearable electronics applications. The smart electrochromic supercapacitor system is then integrated with a solar sensor to enable photoresponsive coloration where the transmittance changes in response to varying light intensity. © 2017 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Studies on the nature of the primary reactions of photosystem II in photosynthesis. I. The electrochromic 515 nm absorption change as an appropriate indicator for the functional state of the photochemical active centers of system II in DCMY poisoned chloroplasts.

PubMed

Renger, G; Wolff, C

1975-01-01

The field indicating electrochromic 515 nm absorption change has been measured under different excitation conditions in DCMU poisoned chloroplasts in the presence of benzylviologen as electron acceptor. It has been found: 1. The amplitude of the 515 nm absorption change is nearly completely suppressed under repetitive single turnover flash excitation conditions which kinetically block the back reaction around system II (P. Bennoun, Biochim. Biophys. Acta 216, 357 [1970]). 2. The amplitude of the 515 nm absorption change measured under repetitive single turnover flash excitation conditions which allow the completion of the back reaction during the dark time between the flashes (measuring light beam switched off) amounts in the presence of 2 mum DCMU nearly 50% of the electrochromic 515 nm amplitude obtained in the absence of DCMU. In DCMU poisoned chloroplasts this amplitude is significantly decreased by hydroxylaminhydrochloride, but nearly doubled in the presence of CDIP+ascorbate. 3. The dependence of the 515 nm amplitude on the time td between the flashes kinetically resembles the back reaction around system ?II. The time course of the back reaction can be fairly described either by a second order reaction or by a two phase exponential kinetics. 4. 1,3-dinitrobenzene (DNE) or alpha-bromo-alpha-benzylmalodinitril (BBMD) reduce the 515 nm amplitude in DCMU poisoned chloroplasts, but seem to influecne only slightly the kinetics of the back reaction. 5. The dependence of the 515 nm amplitude on the flash light intensity (the amplitude normalized to 1 at 100% flash light intensity) is not changed by DNB. Based on these experimental data it has been concluded that in DCMU poisoned chloroplasts the amplitude of the 515 nm absorption change reflects the functional state of photosystem II centers (designated as photoelectric dipole generators II) under suitable excitation conditions. Furthermore, it is inferred that in DCMU poisoned chlorplasts the photoelectric dipole generators II either cooperate (probably as twin-pairs) or exist in two functionally different forms. With respect to BBMD and DNB it is assumed that these agents transform the phtooelectric dipole generators II into powerful nonphotochemical quenchers, which significantly reduce the variable fluorescence in DCMU-poisoned chloroplasts.

Electrochromic switching in ionically self-assembled nanostructures

NASA Astrophysics Data System (ADS)

Janik, Jerzy A.; Heflin, James R.; Marciu, Daniela; Miller, Michael B.; Wang, Hong; Gibson, Harry W.; Davis, Rick M.

2001-11-01

Ionically self-assembled monolayers (ISAMs), fabricated by alternate adsorption of cationic and anionic components, yield exceptionally homogeneous thin films with sub- nanometer control of the thickness and relative special location of the component materials. Using organic electrochromic materials such as polyaniline, we report studies of electrochromic responses in ISAM films. Reversible changes in the absorption spectrum are observed with the application of voltages on the order of 1.0 V. Measurements are made using both liquid electrolytes and in all-solid state devices incorporating solid polyelectrolytes such as poly(2-acylamido 2-methyl propane sulfonic acid) (PAMPS). Due to the precise nanometer scale control of thickness and composition of the electrochromic composite system, switching times faster than 50 ms have been demonstrated.

Changes in H(+)-ATP Synthase Activity, Proton Electrochemical Gradient, and pH in Pea Chloroplast Can Be Connected with Variation Potential.

PubMed

Sukhov, Vladimir; Surova, Lyubov; Morozova, Ekaterina; Sherstneva, Oksana; Vodeneev, Vladimir

2016-01-01

Local stimulation induces generation and propagation of electrical signals, including the variation potential (VP) and action potential, in plants. Burning-induced VP changes the physiological state of plants; specifically, it inactivates photosynthesis. However, the mechanisms that decrease photosynthesis are poorly understood. We investigated these mechanisms by measuring VP-connected systemic changes in CO2 assimilation, parameters of light reactions of photosynthesis, electrochromic pigment absorbance shifts, and light scattering. We reveal that inactivation of photosynthesis in the pea, including inactivation of dark and light reactions, was connected with the VP. Inactivation of dark reactions decreased the rate constant of the fast relaxation of the electrochromic pigment absorbance shift, which reflected a decrease in the H(+)-ATP synthase activity. This decrease likely contributed to the acidification of the chloroplast lumen, which developed after VP induction. However, VP-connected decrease of the proton motive force across the thylakoid membrane, possibly, reflected a decreased pH in the stroma. This decrease may be another mechanism of chloroplast lumen acidification. Overall, stroma acidification can decrease electron flow through photosystem I, and lumen acidification induces growth of fluorescence non-photochemical quenching and decreases electron flow through photosystem II, i.e., pH decreases in the stroma and lumen, possibly, contribute to the VP-induced inactivation of light reactions of photosynthesis.

Robert Tenent | NREL

Science.gov Websites

improved electrochemical devices, in particular electrochromic windows and lithium ion batteries. At NREL Materials Design and Integration for Electrochromic Devices and Li-ion Batteries Gel/Solid Electrolyte

Electrochromic optical switching device

DOEpatents

Lampert, C.M.; Visco, S.J.

1992-08-25

An electrochromic cell is disclosed which comprises an electrochromic layer, a polymerizable organo-sulfur layer which comprises the counter electrode of the structure, and an ionically conductive electronically insulating material which comprises the separator between the electrodes. In a preferred embodiment, both the separator and the organo-sulfur electrode (in both its charged and uncharged states) are transparent either to visible light or to the entire solar spectrum. An electrochromic device is disclosed which comprises such electrodes and separator encased in glass plates on the inner surface of each of which is formed a transparent electrically conductive film in respective electrical contact with the electrodes which facilitates formation of an external electrical connection or contact to the electrodes of the device to permit electrical connection of the device to an external potential source. 3 figs.

Colorless triphenylamine-based aliphatic thermoset epoxy for multicolored and near-infrared electrochromic applications.

PubMed

Chuang, Ya-Wen; Yen, Hung-Ju; Wu, Jia-Hao; Liou, Guey-Sheng

2014-03-12

In this study, two novel colorless thermoset epoxy resins with anodically electrochromism were prepared from the thermal curing of two triphenylamine-based diamine monomers, 4,4'-diamino-4″-methoxytriphenylamine (1) and N,N'-bis(4-aminophenyl)-N,N'-di(4-methoxylphenyl)-1,4-phenylenediamine (2) with aliphatic epoxy triglycidyl isocyanurate, respectively. The resulting thermoset epoxy resins showed excellent softening temperature (Ts, 270 and 280 °C) due to the rigid structure and highly crosslinking density. In addition, novel colorless epoxy resin films revealed good reversible electrochemical oxidation and interesting multi-electrochromic behavior with high contrast ratio both in visible and near-infrared regions. The aliphatic thermoset epoxy resins also exhibited high transparency in visible region as colorless and great potential for practical electrochromic applications.

Electrochromic Behaviors of Water-Soluble Polyaniline with Covalently Bonded Acetyl Ferrocene

NASA Astrophysics Data System (ADS)

Xiong, Shanxin; Wang, Ru; Li, Shuaishuai; Wu, Bohua; Chu, Jia; Wang, Xiaoqin; Zhang, Runlan; Gong, Ming

2018-04-01

A novel ferrocene-containing hybrid electrochromic material was synthesized via copolymerization of aniline with p-phenylenediamine functionalized acetyl ferrocene in the presence of poly (styrene sulfonate) dopant in an aqueous medium, and neat polyaniline (PANI) was prepared for comparison. The polymerization characteristics and the structure of the copolymer were systematically studied by Fourier-transform infrared, meanwhile, their electrochromic properties and electrochemical behaviors were tested by UV-vis spectra, cyclic voltammetry and electrochemical impedance spectroscopy (EIS). It was found that the strong covalent bond and large conjugated system between PANI and ferrocene enhance the electron transfer rate and electron delocalization in the ferrocene-polyaniline (Fc-PANI) hybrid. In particular, the electrochromic device with Fc-PANI as the active layer shows significant enhancement in optical contrast over the PANI-based device.

Electrochromic optical switching device

DOEpatents

Lampert, Carl M.; Visco, Steven J.

1992-01-01

An electrochromic cell is disclosed which comprises an electrochromic layer, a polymerizable organo-sulfur layer which comprises the counter electrode of the structure, and an ionically conductive electronically insulating material which comprises the separator between the electrodes. In a preferred embodiment, both the separator and the organo-sulfur electrode (in both its charged and uncharged states) are transparent either to visible light or to the entire solar spectrum. An electrochromic device is disclosed which comprises such electrodes and separator encased in glass plates on the inner surface of each of which is formed a transparent electrically conductive film in respective electrical contact with the electrodes which facilitates formation of an external electrical connection or contact to the electrodes of the device to permit electrical connection of the device to an external potential source.

Cation induced electrochromism in 2,4-dinitrophenylhydrazine (DNPH): Tuning optical properties of aromatic rings

NASA Astrophysics Data System (ADS)

Sanader, Željka; Brunet, Claire; Broyer, Michel; Antoine, Rodolphe; Dugourd, Philippe; Mitrić, Roland; Bonačić-Koutecký, Vlasta

2013-05-01

We have theoretically investigated the influence of protons and noble metal cations on optical properties of 2,4-dinitrophenylhydrazine (DNPH). We show that optical properties of aromatic rings can be tuned by cation-induced electrochromism in DNPH due to binding to specific NO2 groups. Our findings on cation-induced electrochromism in DNPH may open new routes in two different application areas, due to the fact that DNPH can easily bind to biological molecules and surface materials through carbonyl groups.

Li+ ions diffusion into sol-gel V2O5 thin films: electrochromic properties

NASA Astrophysics Data System (ADS)

Benmoussa, M.; Outzourhit, A.; Bennouna, A.; Ihlal, A.

2009-10-01

V{2}O{5} thin films were prepared by the sol-gel spin coating process. The Li+ ions insertion effect on optical and electrochromic properties of those films was studied. The diffusion coefficient was calculated using both cyclic voltammograms and chronoamperometric curves. The amount x of Li+ ions in LixV{2}O{5} was also calculated. Finally, the electrochromic performance evolution characteristics such as the reversibility, coloration efficiency, coloration memory stability and response time were studied.

Enhanced electrochromic properties of TiO2 nanoporous film prepared based on an assistance of polyethylene glycol

NASA Astrophysics Data System (ADS)

Xu, Shunjian; Luo, Xiaorui; Xiao, Zonghu; Luo, Yongping; Zhong, Wei; Ou, Hui; Li, Yinshuai

2017-01-01

Polyethylene glycol (PEG) was employed as pore-forming agent to prepare TiO2 nanoporous film based on spin-coating a TiO2 nanoparticle mixed paste on fluorine doped tin oxide (FTO) glass. The electrochromic and optical properties of the obtained TiO2 film were investigated by cyclic voltammetry (CV), chronoamperometry (CA) and UV-Vis spectrophotometer. The results show that the PEG in the mixed paste endows the TiO2 film with well-developed porous structure and improves the uniformity of the TiO2 film, which are helpful for the rapid intercalation and extraction of lithium ions within the TiO2 film and the strengthening of the diffuse reflection of visible light in the TiO2 film. As a result, the TiO2 film derived from the mixed paste with PEG displays higher electrochemical activity and more excellent electrochromic performances compared with the TiO2 film derived from the mixed paste without PEG. The switching times of coloration/bleaching are respectively 10.16/5.65 and 12.77/6.13 s for the TiO2 films with PEG and without PEG. The maximum value of the optical contrast of the TiO2 film with PEG is 21.2% while that of the optical contrast of the TiO2 film without PEG is 14.9%. Furthermore, the TiO2 film with PEG has better stability of the colored state than the TiO2 film without PEG.

Paper-based electrochemical sensing platform with integral battery and electrochromic read-out.

PubMed

Liu, Hong; Crooks, Richard M

2012-03-06

We report a battery-powered, microelectrochemical sensing platform that reports its output using an electrochromic display. The platform is fabricated based on paper fluidics and uses a Prussian blue spot electrodeposited on an indium-doped tin oxide thin film as the electrochromic indicator. The integrated metal/air battery powers both the electrochemical sensor and the electrochromic read-out, which are in electrical contact via a paper reservoir. The sample activates the battery and the presence of analyte in the sample initiates the color change of the Prussian blue spot. The entire system is assembled on the lab bench, without the need for cleanroom facilities. The applicability of the device to point-of-care sensing is demonstrated by qualitative detection of 0.1 mM glucose and H(2)O(2) in artificial urine samples.

High optical switching speed and flexible electrochromic display based on WO3 nanoparticles with ZnO nanorod arrays' supported electrode

NASA Astrophysics Data System (ADS)

Wang, Mingjun; Fang, Guojia; Yuan, Longyan; Huang, Huihui; Sun, Zhenhua; Liu, Nishuang; Xia, Shanhong; Zhao, Xingzhong

2009-05-01

The electrochromic (EC) property of WO3 nanoparticles grown on vertically self-aligned ZnO nanorods (ZNRs) is reported. An electrochromic character display based on WO3 nanoparticle-modified ZnO nanorod arrays on a flexible substrate has been fabricated and demonstrated. The ZNRs were first synthesized on ZnO-seed-coated In2O3:Sn (ITO) glass (1 cm2 cell) and polyethylene terephthalate (PET) (4 cm2 cell) substrates by a low temperature hydrothermal method, and then amorphous WO3 nanoparticles were grown directly on the surface of the ZNRs by the pulsed laser deposition (PLD) method. The ZNR-based EC device shows high transparence, good electrochromic stability and fast switching speed (4.2 and 4 s for coloration and bleaching, respectively, for a 1 cm2 cell). The good performance of the ZNR electrode-based EC display can be attributed to the large surface area, high crystallinity and good electron transport properties of the ZNR arrays. Its high contrast, fast switching, good memory and flexible characteristics indicate it is a promising candidate for flexible electrochromic displays or electronic paper.

Insertion of lithium into electrochromic devices after completion

DOEpatents

Berland, Brian Spencer; Lanning, Bruce Roy; Frey, Jonathan Mack; Barrett, Kathryn Suzanne; DuPont, Paul Damon; Schaller, Ronald William

2015-12-22

The present disclosure describes methods of inserting lithium into an electrochromic device after completion. In the disclosed methods, an ideal amount of lithium can be added post-fabrication to maximize or tailor the free lithium ion density of a layer or the coloration range of a device. Embodiments are directed towards a method to insert lithium into the main device layers of an electrochromic device as a post-processing step after the device has been manufactured. In an embodiment, the methods described are designed to maximize the coloration range while compensating for blind charge loss.

Electrochromic device containing metal oxide nanoparticles and ultraviolet blocking material

DOE Office of Scientific and Technical Information (OSTI.GOV)

Garcia, Guillermo; Koo, Bonil; Gregoratto, Ivano

An electrochromic device includes a nanostructured transition metal oxide bronze layer that includes one or more transition metal oxide and one or more dopant. The electrochromic device also includes nanoparticles containing one or more transparent conducting oxide (TCO), a solid state electrolyte, a counter electrode, and at least one protective layer to prevent degradation of the one or more nanostructured transition metal oxide bronze. The nanostructured transition metal oxide bronze selectively modulates transmittance of near-infrared (NIR) and visible radiation as a function of an applied voltage to the device.

Electrochromic devices

DOEpatents

Allemand, Pierre M.; Grimes, Randall F.; Ingle, Andrew R.; Cronin, John P.; Kennedy, Steve R.; Agrawal, Anoop; Boulton, Jonathan M.

2001-01-01

An electrochromic device is disclosed having a selective ion transport layer which separates an electrochemically active material from an electrolyte containing a redox active material. The devices are particularly useful as large area architectural and automotive glazings due to there reduced back reaction.

Citric acid induced W18O49 electrochromic films with enhanced optical modulation

NASA Astrophysics Data System (ADS)

Xie, Junliang; Song, Bin; Zhao, Gaoling; Han, Gaorong

2018-06-01

Electrochromic materials exhibit promising applications in energy-saving fields for their ability to control heat from outdoors. Nanostructured W18O49 has drawn attention for its one-dimensional structure to transfer charge efficiently as a remarkable electrochromic material. W18O49 bi-layer films were fabricated through a facile one-step solvothermal process with citric acid as a chelating agent. The addition of citric acid improved the deposition on the substance, and a nanostructured film with a denser layer at the bottom and a tussock-like upper layer was obtained. The bi-layer film exhibited an enhanced optical modulation of 68.7%, a coloration efficiency of 82.1 cm2/C with stability over 400 cycles, and fast response times (1.4 s and 2.3 s for bleaching and coloring), with expectation to be applied in the electrochromic field.

Eliminating degradation and uncovering ion-trapping dynamics in electrochromic WO3 thin films

PubMed Central

Wen, Rui-Tao; Granqvist, Claes G.; Niklasson, Gunnar A.

2015-01-01

Amorphous WO3 thin films are of keen interest as cathodic electrodes in transmittance-modulating electrochromic devices. However, these films suffer from ion-trapping-induced degradation of optical modulation and reversibility upon extended Li+-ion exchange. Here, we demonstrate that ion-trapping-induced degradation, which is commonly believed to be irreversible, can be successfully eliminated by constant-current-driven de-trapping, i.e., WO3 films can be rejuvenated and regain their initial highly reversible electrochromic performance. Pronounced ion-trapping occurs when x exceeds ~0.65 in LixWO3 during ion insertion. We find two main kinds of Li+-ion trapping sites (intermediate and deep) in WO3, where the intermediate ones are most prevalent. Li+-ions can be completely removed from intermediate traps but are irreversibly bound in deep traps. Our results provide a general framework for developing and designing superior electrochromic materials and devices. PMID:26259104

Thin film lithium-based batteries and electrochromic devices fabricated with nanocomposite electrode materials

DOEpatents

Gillaspie, Dane T; Lee, Se-Hee; Tracy, C. Edwin; Pitts, John Roland

2014-02-04

Thin-film lithium-based batteries and electrochromic devices (10) are fabricated with positive electrodes (12) comprising a nanocomposite material composed of lithiated metal oxide nanoparticles (40) dispersed in a matrix composed of lithium tungsten oxide.

Electrochromic Behavior of Ionically Self-Assembled Thin Films

NASA Astrophysics Data System (ADS)

Janik, J. A.; Heflin, J. R.; Marciu, D.; Miller, M. B.; Davis, R. M.

2001-03-01

Ionically self-assembled monolayers (ISAMs), fabricated by alternate adsorption of cationic and anionic components, yield exceptionally homogeneous thin films with sub-nanometer control of the thickness and relative special location of the component materials. Using organic electrochromic materials such as polyaniline, we report studies of electrochromic responses in ISAM films. Reversible changes in the absorption spectrum are observed with the application of voltages on the order of 1.0 V. Measurements are made using both liquid electrolytes and in all-solid state devices incorporating solid polyelectrolytes such as poly(2-acylamido 2-methyl propane sulfonic acid) (PAMPS).

Smart glass based on electrochromic polymers

NASA Astrophysics Data System (ADS)

Xu, Chunye; Kong, Xiangxing; Liu, Lu; Su, Fengyu; Kim, Sooyeun; Taya, Minoru

2006-03-01

Five-layer-structured electrochromic glass (window), containing a transparent conductive layer, an electrochromic layer, an ionic conductive layer, an ionic storage layer and a second conductive transparent layer, was fabricated. The electrochromic glass adopts the conjugated polymer, poly[3,3-dimethyl-3,4-dihydro-2H-thieno[3,4-b][1,4]dioxepine] (PProDOT-Me2), as a blue electrochromic active layer, vanadium pentaoxide film as an ion storage layer and polymer gel electrolyte as the ionic transport layer. Dimension of smart glass up to 12 x 20 inch was developed. UV curable sealant was applied for the sealing devices. Color changing or switching speed of 12 x 20 inch smart glass from dark state to the transparent state (or vise versa) is less than 15 seconds under applied 1.5 voltages. Besides the long open circuit memory (the colored state or transparent state remains the same state after the power is off), the smart window can be adjusted easily into the intermediate state between the dark state and the transparent state by just simply turn the power on or off. No space consuming or dirt collecting shades, curtains or blinds are needed. The applications of the smart window, e.g. in the aircrafts, automobiles and architectures were discussed as well.

Electrochromic devices based on lithium insertion

DOEpatents

Richardson, Thomas J.

2006-05-09

Electrochromic devices having as an active electrode materials comprising Sb, Bi, Si, Ge, Sn, Te, N, P, As, Ga, In, Al, C, Pb, I and chalcogenides are disclosed. The addition of other metals, i.e. Ag and Cu to the active electrode further enhances performance.

Titanium Dioxide Films Prepared by Screen-Printing Technique for Self-Powered Electrochromic Windows

NASA Astrophysics Data System (ADS)

Salleh, Muhamad Mat; Yahaya, Muhamad; Mursyidah

Electrochromic windows could reduce air-conditioning costs by being darkened to absorb sunlight and reject unwanted solar heat. These windows change their color and light transmissivity due to the action of an electric field and can change back to the original state by a field reversal. To save the cost, the electrical power may be supplied by a solar cell that integrated with the electrochromic window in a single device. This paper reports the potential of using titanium oxide, TiO2 as solar cells and as electrochromic windows. The TiO2 films were deposited by screen-printing a paste, consisting of TiO2 particles and an organic binder, onto ITO-covered glass substrates. Then the films were tempered at 400 °C to bum out the organic parts. A solar cell of ITO/TiO2/electrolyte/ITO was fabricated using a mixed ammonium iodide and iodine solution as electrolyte. The cell was illuminated through the TiO2 film. The cells showed rectifier properties in the dark and produced electrical current when illuminated. The short circuit photocurrent and the open circuit voltage of the cell in a 100-mW/cm2 tungsten light source were 2.3 μA and 17.0 mV respectively. The electrochromic behavior of the TiO2 films in a lithium perchlorate solution was examined. When the electrochromic film cell was given a forward bias potential of 5.0 V, the original colorless TiO2 film immediately changed to brown. The color of the film bleached to the original when the applied potential was reversed.

Synthesis and Performance of Highly Stable Star-Shaped Polyaniline Electrochromic Materials with Triphenylamine Core

NASA Astrophysics Data System (ADS)

Xiong, Shanxin; Li, Shuaishuai; Zhang, Xiangkai; Wang, Ru; Zhang, Runlan; Wang, Xiaoqin; Wu, Bohua; Gong, Ming; Chu, Jia

2018-02-01

The molecular architecture of conducting polymers has a significant impact on their conjugated structure and electrochemical properties. We have investigated the influence of star-shaped structure on the electrochemical and electrochromic properties of polyaniline (PANI). Star-shaped PANI (SPANI) was prepared by copolymerization of aniline with triphenylamine (TPA) using an emulsion polymerization method. With addition of less than 4.0 mol.% TPA, the resulting SPANI exhibited good solubility in xylene with dodecylbenzenesulfonic acid (DBSA) as doping acid. The structure and thermal stability of the SPANI were characterized using Fourier-transform infrared spectroscopy, Raman spectroscopy, and thermogravimetric analysis, and the electrochemical behavior was analyzed by cyclic voltammetry (CV). The electrochromic properties of SPANI were tested using an electrochemical workstation combined with an ultraviolet-visible (UV-Vis) spectrometer. The results show that, with increasing TPA loading, the thermal stability of SPANI increased. With addition of 4.0 mol.% TPA, the weight loss of SPANI was 36.9% at 700°C, much lower than the value of 71.2% for PANI at the same temperature. The low oxidation potential and large enclosed area of the CV curves indicate that SPANI possesses higher electrochemical activity than PANI. Enhanced electrochromic properties including higher optical contrast and better electrochromic stability of SPANI were also obtained. SPANI with 1.6 mol.% TPA loading exhibited the highest optical contrast of 0.71, higher than the values of 0.58 for PANI, 0.66 for SPANI-0.4%, or 0.63 for SPANI-4.0%. Overdosing of TPA resulted in slow switching speed due to slow ion transport in short branched chains of star-shaped PANI electrochromic material. Long-term stability testing confirmed that all the SPANI-based devices exhibited better stability than the PANI-based device.

Nanomaterials for LightManagement in Electro-Optical Devices

DOE Office of Scientific and Technical Information (OSTI.GOV)

Truong, Vo-Van; Singh, Jai; Tanemura, Sakae

2012-01-01

In the past decade, nanostructured materials and nanoparticles have emerged as the necessary ingredients for electrooptical applications and enhancement of device performance, in particular by making use of the light management aspects of the nanomaterials. The application areas that are being transformed profoundly include smart coating devices (e.g., electrochromic, photochromic, and thermochromic devices), solar energy, and sensing. Despite the large volume of work in the past on smart coating devices, and in particular on electrochromic devices and thermochromic fenestrations, for optical transmission or reflection control, applications remain limited because of slow response time and nonuniformity in the case of largemore » surfaces. Recent works in the field indicate that nanostructured electrochromic coatings would be an integral part of the solution to the above problem. One aspect that can thus be focused on would be the fabrication and characterization of the nanostructured smart coating materials and their compatibility with other layers in the overall smart coating device. In the area of solar photovoltaics, nanomaterials have been used in designing light-trapping schemes for inorganic as well as organic solar cells. One particular category of solar cells that has attracted much interest is the plasmonic solar cells in which metallic nanoparticles are incorporated, helping in enhancing their energy conversion efficiency. Nanostructured solar cells would eventually develop into a 'game changing' technology for making solar cells that are affordable and highly efficient, providing a sizeable alternative energy source for our ever-increasing energy needs. Sensors based on the optical properties of constituting nanostructures and nanoparticles also form a most interesting class of bio- and electrochemical sensing devices. The possibility of synthetizing nanoparticles and structures of specifically desired sizes and shapes has indeed opened a whole new range of sensing applications. In parallel to the experimental development of nanomaterials for light management in devices, theoretical modeling and analysis have also accomplished much progress, and different methods for simulating the optical properties of nanoparticles and structures have been proposed. This special issue of the Journal of Nanomaterials is thus dedicated to articles dealing with nanostructured materials that can be used for light management purpose in different applications. Silicon-rich oxide (SRO) is a dielectric material that contains Si nanoparticles and exhibits interesting physical characteristics for applications in optoelectronic devices. The work by Aceves-Mijares et al. examine, in detail the electro-, cathode- and photoluminescence properties of SRO and discuss the origin of light emission in this type of materials. SRO films, of high and medium silicon excess density, obtained by low-pressure chemical vapor deposition and annealed at 1,100 C have been studied. Results obtained by the authors have led to conclude that SRO emission properties are due to oxidation state nanoagglomerates rather than to nanocrystals, and the emission mechanism is similar to that in the donor-acceptor decay in semiconductors with a specific wide emission spectrum. Two papers are devoted to nanostructured electrochromic thin films, a category of materials most suitable for controlling light transmission or absorption in electrooptical devices, including smart window coatings. Dinh et al. have shown that by mixing nanostructured Ti and W oxides films, one can obtain devices with considerable enhancement of electrochromic efficiency and electrochemical stability as compared to the conventional nonnanostructured films. As large-area mixed Ti and W oxides can be prepared by the simple doctor blade technique followed by an electrochemical process, this type of nanostructured electrochromic films can be considered a good candidate for smart window applications. Djaoued et al. have presented their studies on the synthesis, characterization, and electrochromic applications of porous WO{sub 3} thin films with different nanocrystalline phases. Asymmetric type electrochromic devices have been constructed using hexagonal, monoclinic, and orthorhombic porous WO{sub 3} thin porous films, and their enhanced electrochromic functionality has been well demonstrated. The paper on smart materials by Chen et al. presents the synthesis of thermochromic W-doped VO{sub 2} (monoclinic/rutile) nanopowders using a novel and simple solution-based process as opposed to other conventional techniques such as excimer laser-assisted metal organic deposition and magnetron sputtering. This simple process is based on the reaction of ammonium metavanadate (NH{sub 4}VO{sub 3}) and oxalic acid dihydrate (C{sub 2}H{sub 2}O{sub 4} {center_dot} 2H{sub 2}O) followed by addition of appropriate ammonium tungstate (N{sub 5}H{sub 37}W{sub 6}O{sub 24} {center_dot} H{sub 2}O).« less

Characterization and Electrochromic Properties of Vanadium Oxide Thin Films Prepared via Spray Pyrolysis

NASA Astrophysics Data System (ADS)

Mousavi, M.; Kompany, A.; Shahtahmasebi, N.; Bagheri-Mohagheghi, M.-M.

2013-08-01

Vanadium oxide thin films were grown on glass substrates using spray pyrolysis technique. The effects of substrate temperature, vanadium concentration in the initial solution and the solution spray rate on the nanostructural and the electrochromic properties of deposited films are investigated. Characterization and the electrochromic measurements were carried out using X-ray diffraction, scanning electron microscopy and cyclic voltammogram. XRD patterns showed that the prepared films have polycrystalline structure and are mostly mixed phases of orthorhombic α-V2O5 along with minor β-V2O5 and V4O9 tetragonal structures. The preferred orientation of the deposited films was found to be along [101] plane. The cyclic voltammogram results obtained for different samples showed that only the films with 0.2 M solution concentration, 5 ml/min solution spray rate and 450°C substrate temperature exhibit two-step electrochromic properties. The results show a correlation between cycle voltammogram, morphology and resistance of the films.

Visualization of energy: light dose indicator based on electrochromic gyroid nano-materials

NASA Astrophysics Data System (ADS)

Wei, Di; Scherer, Maik R. J.; Astley, Michael; Steiner, Ullrich

2015-06-01

The typical applications of electrochromic devices do not make use of the charge-dependent, gradual optical response due to their slow voltage-sensitive coloration. However, in this paper we present a design for a reusable, self-powered light dose indicator consisting of a solar cell and a gyroid-structured nickel oxide (NiO) electrochromic display that measures the cumulative charge per se, making use of the efficient voltage-sensitive coloration of gyroid materials. To circumvent the stability issues associated with the standard aqueous electrolyte that is typically accompanied by water splitting and gas evolution, we investigate a novel nano-gyroid NiO electrochromic device based on organic solvents of 1,1,1,3,3,3-hexafluoropropan-2-ol, and room temperature ionic liquid (RTIL) triethylsulfonium bis(trifluoromethylsulfonyl) imide ([SET3][TFSI]) containing lithium bis(trifluoromethylsulfonyl) imide. We show that an effective light dose indicator can be enabled by nano-gyroid NiO with RTIL; this proves to be a reliable device since it does not involve solvent degradation or gas generation.

Dip-Coating Process Engineering and Performance Optimization for Three-State Electrochromic Devices

NASA Astrophysics Data System (ADS)

Wu, Lu; Yang, Dejiang; Fei, Lixun; Huang, Yue; Wu, Fang; Sun, Yiling; Shi, Jiayuan; Xiang, Yong

2017-06-01

Titanium dioxide (TiO2) nanoparticles were modified onto fluorine-doped tin oxide (FTO) via dip-coating technique with different nanoparticle sizes, lifting speeds, precursor concentrations, and dipping numbers. Electrodeposition-based electrochromic device with reversible three-state optical transformation (transparent, mirror, and black) was fabricated subsequently by sandwiching a suitable amount of gel electrolyte between modified FTO electrode and flat FTO electrode. Correlation between dip-coating process engineering, morphological features of TiO2 thin films, i.e., thickness and roughness, as well as performance of electrochromic devices, i.e., optical contrast, switching time, and cycling stability, were investigated. The modified device exhibits high optical contrast of 57%, the short coloration/bleaching switching time of 6 and 20 s, and excellent cycling stability after 1500 cycles of only 27% decrement rate by adjusting dip-coating processes engineering. The results in this study will provide valuable guidance for rational design of the electrochromic device with satisfactory performance.

Smart nickel oxide materials for the applications of energy efficiency and storage

NASA Astrophysics Data System (ADS)

Lin, Feng

The present dissertation studies nickel oxide-based materials for the application of electrochromic windows and lithium-air batteries. The materials were fabricated via radio frequency magnetron sputtering and subsequently post-treated with thermal evaporation and ozone exposure. The strategies to improve electrochromic performance of nickel oxide materials were investigated including compositional control, morphology tuning, modification of electronic structure and interface engineering (i.e., Li2O 2, graphene). The electrochemical properties of the resulting materials were characterized in lithium ion electrolytes. Extremely high performing nickel oxide-based electrochromic materials were obtained in terms of optical modulation, switching kinetics, bleached-state transparency and durability, which promise the implementation of these materials for practical smart windows. With the aid of advanced synchrotron X-ray absorption spectroscopy, it is reported for the first time that the electrochromic effect in multicomponent nickel oxide-based materials arises from the reversible formation of hole states in the NiO6 cluster accompanying with the reversible formation of Li2O2. The reversible formation of Li2O 2 was successfully leveraged with the study of electro-catalysts and cathode materials for lithium-air batteries. The reversibility of Li 2O2 was thoroughly investigated using soft X-ray absorption spectroscopy and theoretical simulation, which substantiates the promise of using electrochromic films as electro-catalysts and/or cathode materials in lithium-air batteries.

An Inexpensive Device for Studying Electrochromism

ERIC Educational Resources Information Center

Ibanez, Jorge G.; Puente-Caballero, Rodrigo; Torres-Perez, Jonatan; Bustos, Daniel; Carmona-Orbezo, Aranzazu; Sevilla, Fortunato B., III

2012-01-01

A novel procedure for the preparation of electrochromic WO[subscript 3] films from readily available materials is presented. It is based on the electrochemical preparation of potassium tungstate from tungsten filaments of incandescent light bulbs in a potassium hydroxide solution. Tungstic acid is then produced by proton exchange using a…

α,α'-N-Boc-substituted bi- and terthiophenes: fluorescent precursors for functional materials.

PubMed

Dong, Yanmei; Navarathne, Daminda; Bolduc, Andréanne; McGregor, Nicholas; Skene, W G

2012-06-15

Fluorescent α,α'-diamide substituted bi- and terthiophene derivatives were prepared by Stille and Suzuki couplings. Their one-pot deprotection and coupling with 2-thiophene carboxaldehyde led to stable conjugated azomethines. These exhibited electrochromic properties, and they were used to fabricate a working electrochromic device.

Thin Films of Antimony-Tin Oxide as Counter-Electrodes for Proton Working Electrochromic Devices

DTIC Science & Technology

2002-01-01

diffraction and transmission electron microscopy (TEM). Electrochromic behavior is studied by means of cyclic voltamperometry coupled with ex situ optical... analysis , we noted that the Sn/Sb atomic ratio was relatively well preserved between target and grown films. Structural characterizations: Figure 1 shows the

Silicon-tin oxynitride glassy composition and use as anode for lithium-ion battery

DOEpatents

Neudecker, Bernd J.; Bates, John B.

2001-01-01

Disclosed are silicon-tin oxynitride glassy compositions which are especially useful in the construction of anode material for thin-film electrochemical devices including rechargeable lithium-ion batteries, electrochromic mirrors, electrochromic windows, and actuators. Additional applications of silicon-tin oxynitride glassy compositions include optical fibers and optical waveguides.

Fully Screen-Printed, Large-Area, and Flexible Active-Matrix Electrochromic Displays Using Carbon Nanotube Thin-Film Transistors.

PubMed

Cao, Xuan; Lau, Christian; Liu, Yihang; Wu, Fanqi; Gui, Hui; Liu, Qingzhou; Ma, Yuqiang; Wan, Haochuan; Amer, Moh R; Zhou, Chongwu

2016-11-22

Semiconducting single-wall carbon nanotubes are ideal semiconductors for printed electronics due to their advantageous electrical and mechanical properties, intrinsic printability in solution, and desirable stability in air. However, fully printed, large-area, high-performance, and flexible carbon nanotube active-matrix backplanes are still difficult to realize for future displays and sensing applications. Here, we report fully screen-printed active-matrix electrochromic displays employing carbon nanotube thin-film transistors. Our fully printed backplane shows high electrical performance with mobility of 3.92 ± 1.08 cm 2 V -1 s -1 , on-off current ratio I on /I off ∼ 10 4 , and good uniformity. The printed backplane was then monolithically integrated with an array of printed electrochromic pixels, resulting in an entirely screen-printed active-matrix electrochromic display (AMECD) with good switching characteristics, facile manufacturing, and long-term stability. Overall, our fully screen-printed AMECD is promising for the mass production of large-area and low-cost flexible displays for applications such as disposable tags, medical electronics, and smart home appliances.

All-in-One Gel-Based Electrochromic Devices: Strengths and Recent Developments

PubMed Central

Viñuales, Ana; Rodriguez, Javier; Tena-Zaera, Ramón

2018-01-01

Electrochromic devices (ECDs) have aroused great interest because of their potential applicability in displays and smart systems, including windows, rearview mirrors, and helmet visors. In the last decades, different device structures and materials have been proposed to meet the requirements of commercial applications to boost market entry. To this end, employing simple device architectures and achieving a competitive electrolyte are crucial to accomplish easily implementable, high-performance ECDs. The present review outlines devices comprising gel electrolytes as a single electroactive layer (“all-in-one”) ECD architecture, highlighting some advantages and opportunities they offer over other electrochromic systems. In this context, gel electrolytes not only overcome the drawbacks of liquid and solid electrolytes, such as liquid’s low chemical stability and risk of leaking and soil’s slow switching and lack of transparency, but also exhibit further strengths. These include easier processability, suitability for flexible substrates, and improved stabilization of the chemical species involved in redox processes, leading to better cyclability and opening wide possibilities to extend the electrochromic color palette, as discussed herein. Finally, conclusions and outlook are provided. PMID:29534466

Large-scale fabrication of pseudocapacitive glass windows that combine electrochromism and energy storage.

PubMed

Yang, Peihua; Sun, Peng; Chai, Zhisheng; Huang, Langhuan; Cai, Xiang; Tan, Shaozao; Song, Jinhui; Mai, Wenjie

2014-10-27

Multifunctional glass windows that combine energy storage and electrochromism have been obtained by facile thermal evaporation and electrodeposition methods. For example, WO3 films that had been deposited on fluorine-doped tin oxide (FTO) glass exhibited a high specific capacitance of 639.8 F g(-1). Their color changed from transparent to deep blue with an abrupt decrease in optical transmittance from 91.3% to 15.1% at a wavelength of 633 nm when a voltage of -0.6 V (vs. Ag/AgCl) was applied, demonstrating its excellent energy-storage and electrochromism properties. As a second example, a polyaniline-based pseudocapacitive glass was also developed, and its color can change from green to blue. A large-scale pseudocapacitive WO3-based glass window (15×15 cm(2)) was fabricated as a prototype. Such smart pseudocapacitive glass windows show great potential in functioning as electrochromic windows and concurrently powering electronic devices, such as mobile phones or laptops. © 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Patterned polyaniline encapsulated in titania nanotubes for electrochromism.

PubMed

Lv, Haiming; Wang, Yi; Pan, Lei; Zhang, Leipeng; Zhang, Hangchuan; Shang, Lei; Qu, Huiying; Li, Na; Zhao, Jiupeng; Li, Yao

2018-02-21

In this article, we report the preparation of a TiO 2 nanotube array (TNA) film used as a transparent electrochromic material and a TNA/polyaniline patterned hybrid electrochromic film utilized as an information display material. The TNA film was fabricated by an anodizing process, and a surface patterned TNA with extreme wettability contrast (hydrophilic/hydrophobic) on a TNA surface through self-assembly (SAM) and photocatalytic lithography is fabricated. Then the TNA/polyaniline hybrid film was prepared by electrodeposition of aniline in an aqueous solution. Finally, the electrochromic properties of the TNA film and the TNA/polyaniline hybrid film were investigated. Compared with neat TNA film and polyaniline (PANI) films, the hybrid film shows a much higher optical contrast in the near infrared range. The TNA/polyaniline hybrid film shows higher coloration efficiencies of 24.4 cm 2 C -1 at a wavelength of 700 nm and 17.1 cm 2 C -1 at a wavelength of 1050 nm compared to the TNA coloration efficiency. The color switching time (20.9 s or 22.9 s) of TNA/polyaniline is faster than TNA.

Trace H2 O2 -Assisted High-Capacity Tungsten Oxide Electrochromic Batteries with Ultrafast Charging in Seconds.

PubMed

Zhao, Jinxiong; Tian, Yuyu; Wang, Zhen; Cong, Shan; Zhou, Di; Zhang, Qingzhu; Yang, Mei; Zhang, Weikun; Geng, Fengxia; Zhao, Zhigang

2016-06-13

A recent technological trend in the field of electrochemical energy storage is to integrate energy storage and electrochromism functions in one smart device, which can establish efficient user-device interactions based on a friendly human-readable output. This type of newly born energy storage technology has drawn tremendous attention. However, there is still plenty of room for technological and material innovation, which would allow advancement of the research field. A prototype Al-tungsten oxide electrochromic battery with interactive color-changing behavior is reported. With the assistance of trace amount of H2 O2 , the battery exhibits a specific capacity almost seven times that for the reported electrochromic batteries, up to 429 mAh g(-1) . Fast decoloration of the reduced tungsten oxide affords a very quick charging time of only eight seconds, which possibly comes from an intricate combination of structure and valence state changes of tungsten oxide. This unique combination of features may further advance the development of smart energy storage devices with suitability for user-device interactions. © 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Design and characterization of a durable and highly efficient energy-harvesting electrochromic window

NASA Astrophysics Data System (ADS)

Amasawa, Eri

With the growing global energy demands, electrochromic window (ECW) technology has attracted great attention for its ability to reversibly change the transmittance of incoming light through applied moderate potential. While ECW has a great potential to conserve energy from lighting and air conditioning in buildings, ECW still consumes energy; ECW should be self-powered for further energy conservation. In this study, a new design of energy-harvesting electrochromic window (EH-ECW) based on fusion of two technologies, organic electrochromic window and dye-sensitized solar cell (DSSC) is presented. Unlike other self-powered smart windows such as photoelectrochromic device that only contains two states (i.e. closed circuit colored state and open circuit bleaching state), EH-ECW allows active tuning of transmittance through varying applied potential and function as a photovoltaic cell based on DSSC. The resulting device demonstrates fast switching rate of 1 second in both bleaching and coloring process through the use of electrochromic polymer as a counter electrode layer. In order to increase the transmittance of the device, cobalt redox couple and light colored yet efficient organic dye are employed. The organic dye utilized contains polymeric structure, which contributes to high cyclic stability. The device exhibits power conversion efficiency (PCE) of 4.5 % under AM 1.5 irradiation (100 mW/cm2), change in transmittance (Delta T = Tmax - Tmin) of 34 % upon applied potential, and shows only 3 % degradation in PCE after 5000 cycles.

Aluminum doped nickel oxide thin film with improved electrochromic performance from layered double hydroxides precursor in situ pyrolytic route

DOE Office of Scientific and Technical Information (OSTI.GOV)

Shi, Jingjing; Lai, Lincong; Zhang, Ping

Electrochromic materials with unique performance arouse great interest on account of potential application values in smart window, low-power display, automobile anti-glare rearview mirror, and e-papers. In this paper, high-performing Al-doped NiO porous electrochromic film grown on ITO substrate has been prepared via a layered double hydroxides(LDHs) precursor in situ pyrolytic route. The Al{sup 3+} ions distributed homogenously within the NiO matrix can significantly influence the crystallinity of Ni-Al LDH and NiO:Al{sup 3+} films. The electrochromic performance of the films were evaluated by means of UV–vis absorption spectroscopy, cyclic voltammetry (CV), electrochemical impedance spectroscopy (EIS), and chronoamperometry(CA) measurements. In addition, themore » ratio of Ni{sup 3+}/Ni{sup 2+} also varies with Al content which can lead to different electrochemical performances. Among the as-prepared films, NiO film prepared from Ni-Al (19:1) LDH show the best electrochromic performance with a high transparency of 96%, large optical modulation range (58.4%), fast switching speed (bleaching/coloration times are 1.8/4.2 s, respectively) and excellent durability (30% decrease after 2000 cycles). The improved performance was owed to the synergy of large NiO film specific surface area and porous morphology, as well as Al doping stifled the formation of Ni{sup 3+} making bleached state more pure. This LDHs precursor pyrolytic method is simple, low-cost and environmental benign and is feasible for the preparation of NiO:Al and other Al-doped oxide thin film. - Graphical abstract: The ratio of Ni{sup 3+}/Ni{sup 2+} varies with Al content which can lead to different electrochemical performances. Among the as-prepared films, NiO film prepared from Ni-Al (19:1) LDH show the best electrochromic performance with a high transparency of 96%, large optical modulation range, fast switching speed and excellent durability. Display Omitted.« less

Electrochromic NiO thin films prepared by spin coating

NASA Astrophysics Data System (ADS)

Özütok, F.; Demiri, S.; Özbek, E.

2017-02-01

Recently, smart windows are very important because they are often being used in smart buildings and car glasses (windows). At this point, producing effective electrochromic materials is so necessary. In this study, we produced NiO thin films by using spin coating technique on In-doped SnO2 (ITO) substrate. Nickel proportions of these nickel oxide (NiO) films are 3, 5 and 7 %. Nickel acetate tetrahydrate is the initial solution and solvents are ethylene gl ycol and n-hexzane. Structural properties and surface images are investigated by using x-ray diffactometer (XRD) and scanning electron microscope (SEM) device, respectively. In addition, electrochemical behavior is investigated by cyclic voltammetry. A correlation between surface morphology and electrochromic performance was observed as well.

Low energy switching driver for printed electrochromic displays

NASA Astrophysics Data System (ADS)

Ionescu, Ciprian; Dobre, Robert Alexandru

2016-12-01

This paper continues our investigations in relatively new developed printed electrochromic displays (ECDs). There are some advantages of ECDs that recommend them for specific low end and short time disposable display applications, for instance the ECD devices present low power consumption (they are non-emissive, reflective, i.e. passive) and have a good viewing angle, looking like ink on paper. It is to note that these displays are still in research, and partly present on the market. There are a lot of papers regarding the chemistry and electro-chemistry of the device, but very few about concrete schematics for driving these displays. Due to their low penetration in applications, and due to lack of standardization, there are not yet realized custom drivers in form of integrated circuits. The driving of these circuits is not at all so simple. These are very sensitive devices in what it concerns exceeding the drive pulse duration and voltage level. In order to take full advantage of the low power consumption of this device, a good driver circuitry needs to be realized also in the "low power" class. We propose in this paper an original driving circuit, that has very low consumption and that can be even supplied by a supercapacitor or by a printed battery. The whole structure can be further integrated as a system on foil.

Switching electrochromic performance improvement enabled by highly developed mesopores and oxygen vacancy defects of Fe-doped WO3 films

NASA Astrophysics Data System (ADS)

Koo, Bon-Ryul; Kim, Kue-Ho; Ahn, Hyo-Jin

2018-09-01

In recent years, owing to the capability to reversibly adjust transparency, reflection, and color by the low electric field, electrochromic devices (ECDs) have received an extensive attention for their potential use in optoelectronic applications. However, considering that the performances of the ECDs, including coloration efficiency (CE, <30.0 cm2/C) and switching speed (>10.0 s), are still low for an effective applied use, critical efforts are needed to push the development of a unique nanostructure film to improve electrochromic (EC) performances. Specifically, as the large-scale applications (e.g. refrigerators, vehicles, and airplanes) of the ECDs have been recently developed, the study for improving switching speed is urgently needed for commercialization of the devices. In this context, the present study reports a novel nanostructure film of Fe-doped WO3 films with highly developed mesopores and oxygen vacancy defects, fabricated using the Fe agent and the camphene-assisted sol-gel method. Fe-doped WO3 films with highly developed mesopores and oxygen vacancy defects show remarkable EC performances with both fast switching speed (2.8 s for the coloration speed and 0.3 s for the bleaching speed) and high CE (71.1 cm2/C). These two aspects contribute to the synergistic effects of optimized Fe doping and camphene on the films and have outstanding values as compared to previously reported results of WO3-based materials. Specifically, the fast switching speed is attributed to the shortened Li+ diffusion pathway of the highly developed mesopores; and the other is the improved electrical conductivity of the highly increased oxygen vacancy defects. In addition, the high CE value is due to an efficient charge transport as the result of a more effective electroactive contact of the morphology with highly developed mesopores, resulting in a large transmittance modulation with a small intercalated charge density.

Evaluation of SAGE Electrochromic Devices: Cooperative Research and Development Final Report, CRADA Number CRD-15-579

DOE Office of Scientific and Technical Information (OSTI.GOV)

Tenent, Robert C.

2017-12-06

NREL will conduct durability testing of Sage Electrochromics dynamic windows products using American Society for Testing and Materials (ASTM) standard methods and drive parameters as defined by Sage. Window units will be tested and standard analysis performed. Data will be summarized and reported back to Sage at the end of the testing period.

Synergistic tungsten oxide/organic framework hybrid nanofibers for electrochromic device application

NASA Astrophysics Data System (ADS)

Dulgerbaki, Cigdem; Komur, Ali Ihsan; Nohut Maslakci, Neslihan; Kuralay, Filiz; Uygun Oksuz, Aysegul

2017-08-01

We report the first successful applications of tungsten oxide/conducting polymer hybrid nanofiber assemblies in electrochromic devices. Poly(3,4-ethylenedioxythiophene)/tungsten oxide (PEDOT/WO3) and polypyrrole/tungsten oxide (PPy/WO3) composites were prepared by an in situ chemical oxidative polymerization of monomers in different ionic liquids; 1-butyl-3-methylimidazolium tetrafluoroborate (BMIMBF4), 1-butyl-3-methylimidazolium hexafluorophosphate (BMIMPF6), 1-butyl-3-methylimidazolium bis(trifluoromethylsulfonyl) imide (BMIMTFSI) and 1-butyl-1-methylpyrrolidinium bis(trifluoromethylsulfonyl) imide (BMPTFSI). Electrospinning process was used to form hybrid nanofibers from chemically synthesized nanostructures. The electrospun hybrid samples were compared from both morphological and electrochemical perspectives. Importantly, deposition of nanofibers from chemically synthesized hybrids can be achieved homogenously, on nanoscale dimensions. The morphologies of these assemblies were evaluated by SEM, whereas their electroactivity was characterized by cyclic voltammetry. Electrochromic devices made from hybrid nanofiber electrodes exhibited highest chromatic contrast of 37.66% for PEDOT/WO3/BMIMPF6, 40.42% for PPy/WO3/BMIMBF4 and show a strong electrochromic color change from transparent to light brown. Furthermore, the nanofiber devices exhibit outstanding stability when color switching proceeds, which may ensure a versatile platform for color displays, rear-view mirrors and smart windows.

Electrochromic properties of poly (1-(phenyl)-2,5-di(2-thienyl)-1H-pyrrole-co-3,4-ethylenedioxy thiophene) and its application in electrochromic devices

NASA Astrophysics Data System (ADS)

Tarkuc, S.; Sahmetlioglu, E.; Tanyeli, C.; Akhmedov, I. M.; Toppare, L.

2008-06-01

Electrochemical copolymerization of 1-(phenyl)-2,5-di(2-thienyl)-1H-pyrrole (PTP) with 3,4-ethylenedioxy thiophene (EDOT) was carried out in acetonitrile (AN)/NaClO4/LiClO4 (0.1 M) solvent-electrolyte couple via potentiodynamic electrolysis. Characterizations of the resulting copolymer were performed via cyclic voltammetry (CV), Fourier transform infrared spectroscopy (FTIR), scanning electron microscopy (SEM), and spectroelectrochemical analysis. Spectroelectrochemical analyses show that the copolymer of PTP with EDOT has an electronic band gap (due to π to π∗ transition) of 1.9 eV at 480 nm, with a claret red in the fully reduced form and a blue color in the fully oxidized form. Via kinetic studies, the optical contrast (ΔT %) was found to be 8% for P(PTP-co-EDOT). Results showed that the time required to reach 95% of the ultimate transmittance was 1.7 s for the copolymer. The P(PTP-co-EDOT) film was used to construct a dual type polymer electrochromic device (ECDs) with poly(3,4-ethylenedioxy thiophene) (PEDOT). Spectroelectrochemistry, electrochromic switching and open circuit memory of the device were investigated.

A Paper-Based Electrochromic Array for Visualized Electrochemical Sensing.

PubMed

Zhang, Fengling; Cai, Tianyi; Ma, Liang; Zhan, Liyuan; Liu, Hong

2017-01-31

We report a battery-powered, paper-based electrochromic array for visualized electrochemical sensing. The paper-based sensing system consists of six parallel electrochemical cells, which are powered by an aluminum-air battery. Each single electrochemical cell uses a Prussian Blue spot electrodeposited on an indium-doped tin oxide thin film as the electrochromic indicator. Each electrochemical cell is preloaded with increasing amounts of analyte. The sample activates the battery for the sensing. Both the preloaded analyte and the analyte in the sample initiate the color change of Prussian Blue to Prussian White. With a reaction time of 60 s, the number of electrochemical cells with complete color changes is correlated to the concentration of analyte in the sample. As a proof-of-concept analyte, lactic acid was detected semi-quantitatively using the naked eye.

Absorption and electrochromic modulation of near-infrared light: realized by tungsten suboxide

NASA Astrophysics Data System (ADS)

Li, Guilian; Zhang, Shouhao; Guo, Chongshen; Liu, Shaoqin

2016-05-01

In the present study, needle-like tungsten suboxide W18O49 nanocrystals were fabricated as the optical active substance to realize the aim of optical control of near-infrared light. The W18O49 nanocrystals were selected in this regard due to their unique optical performance. As revealed by the powder absorption result, the needle-like W18O49 nanocrystals show strong and wide photoabsorption in the entire near infrared region of 780-2500 nm, from which thin films with the W18O49 nanocrystal coating thus benefits and can strongly shield off almost all near infrared irradiation, whereas transmitting the majority of visible light. To make it more tunable, the W18O49 nanocrystals were finally assembled onto an ITO glass via the layer-by-layer strategy for later electrochromic investigation. The nanostructured architectures of the W18O49 nanocrystal electrochromic films exhibit high contrast, faster switching response, higher coloration efficiencies (150 cm2 C-1 at 650 nm and 255 cm2 C-1 at 1300 nm), better long-term redox switching stability (reversibility of 98% after 500 cycles) and wide electrochromic spectrum coverage of both the visible and infrared regions.In the present study, needle-like tungsten suboxide W18O49 nanocrystals were fabricated as the optical active substance to realize the aim of optical control of near-infrared light. The W18O49 nanocrystals were selected in this regard due to their unique optical performance. As revealed by the powder absorption result, the needle-like W18O49 nanocrystals show strong and wide photoabsorption in the entire near infrared region of 780-2500 nm, from which thin films with the W18O49 nanocrystal coating thus benefits and can strongly shield off almost all near infrared irradiation, whereas transmitting the majority of visible light. To make it more tunable, the W18O49 nanocrystals were finally assembled onto an ITO glass via the layer-by-layer strategy for later electrochromic investigation. The nanostructured architectures of the W18O49 nanocrystal electrochromic films exhibit high contrast, faster switching response, higher coloration efficiencies (150 cm2 C-1 at 650 nm and 255 cm2 C-1 at 1300 nm), better long-term redox switching stability (reversibility of 98% after 500 cycles) and wide electrochromic spectrum coverage of both the visible and infrared regions. Electronic supplementary information (ESI) available. See DOI: 10.1039/c5nr09147k

Computationally Designed Oligomers for High Contrast Black Electrochromic Polymers

DTIC Science & Technology

2017-05-05

SUBJECT TERMS electrochromics, DFf, TDDFT, organic electronics , oligomer, organic polymers 16. SECURITY CLASSIFICATION OF: 17. LIMITATION OF 18. NUMBER... electron -withdrawing behaviors. Another finding was that the same dication was produced regardless of the color or peak morphology of the neutral 5...radical cation states present in the chromophore upon oxidation. The two-ring electron rich dioxythiophene portions of the chromophore (EAc) and/or the

Conjugated Polymers Atypically Prepared in Water

PubMed Central

Invernale, Michael A.; Pendergraph, Samuel A.; Yavuz, Mustafa S.; Ombaba, Matthew; Sotzing, Gregory A.

2010-01-01

Processability remains a fundamental issue for the implementation of conducting polymer technology. A simple synthetic route towards processable precursors to conducting polymers (main chain and side chain) was developed using commercially available materials. These soluble precursor systems were converted to conjugated polymers electrochemically in aqueous media, offering a cheaper and greener method of processing. Oxidative conversion in aqueous and organic media each produced equivalent electrochromics. The precursor method enhances the yield of the electrochromic polymer obtained over that of electrodeposition, and it relies on a less corruptible electrolyte bath. However, electrochemical conversion of the precursor polymers often relies on organic salts and solvents. The ability to achieve oxidative conversion in brine offers a less costly and a more environmentally friendly processing step. It is also beneficial for biological applications. The electrochromics obtained herein were evaluated for electronic, spectral, and morphological properties. PMID:20959869

NREL Electrochromic Window Research Wins Award

ScienceCinema

None

2017-12-09

Winners of the CO-LABS Governor's Award for High-Impact Research in Energy Efficiency, Dr. Satyen Deb at the U.S. Department of Energy's National Renewable Energy Laboratory (NREL) discovered that a small electrical charge can change the opacity of tungsten oxide from clear to tinted. He, Dr. Dane Gillaspie, and their fellow scientists at NREL then applied this knowledge to develop and transfer the technologies required to construct an electrochromic window, which can switch between clear and heavily tinted states. Electrochromic windows allow natural light in while adding tint to reduce summer heat and glare, and going clear to allow sunlight through in the winter. Broad adaptation of these windows could reduce US total energy use by four percent and reduce building cooling loads by 20%, much of this during expensive peak hours. Windows based on these discoveries are now being installed worldwide.

Photopatternable electrochromic materials from oxetane precursors.

PubMed

Leliège, Antoine; Barik, Satyananda; Skene, W G

2014-05-14

Conjugated thiophenoazomethine triads containing an acid sensitive oxetane group were prepared. The solution processable monomers were immobilized on glass and ITO coated glass substrates by photoacid induced cationic ring-opening polymerization (CROP) of the oxetane moiety. Photolithography using a photoacid generator and photosensitizer were used to pattern an electroactive polymer. Micro- and macroscale patterns ranging between 20 μm and 50 mm were possible with the electrochromic materials. The photopolymerized azomethine remained electroactive, and it could be repeatedly switched electrochemically between its neutral (mauve, λmax=535 nm) and oxidized (blue, λmax=585 nm) states without degradation. The electrochromic properties were evaluated in a simulated device where the colors were successfully cycled between blue (oxidized) and purple (neutral) states with applied biases of +0.6 V and -0.6 V vs Fc/Fc+ under ambient conditions without significant color fatigue or degradation.

Cyclic voltammetry on sputter-deposited films of electrochromic Ni oxide: Power-law decay of the charge density exchange

DOE Office of Scientific and Technical Information (OSTI.GOV)

Wen, Rui-Tao, E-mail: Ruitao.Wen@angstrom.uu.se; Granqvist, Claes G.; Niklasson, Gunnar A.

2014-10-20

Ni-oxide-based thin films were produced by reactive direct-current magnetron sputtering and were characterized by X-ray diffraction and Rutherford backscattering spectroscopy. Intercalation of Li{sup +} ions was accomplished by cyclic voltammetry (CV) in an electrolyte of LiClO{sub 4} in propylene carbonate, and electrochromism was documented by spectrophotometry. The charge density exchange, and hence the optical modulation span, decayed gradually upon repeated cycling. This phenomenon was accurately described by an empirical power law, which was valid for at least 10{sup 4} cycles when the applied voltage was limited to 4.1 V vs Li/Li{sup +}. Our results allow lifetime assessments for one of themore » essential components in an electrochromic device such as a “smart window” for energy-efficient buildings.« less

Electrochromic fiber-shaped supercapacitors.

PubMed

Chen, Xuli; Lin, Huijuan; Deng, Jue; Zhang, Ye; Sun, Xuemei; Chen, Peining; Fang, Xin; Zhang, Zhitao; Guan, Guozhen; Peng, Huisheng

2014-12-23

An electrochromic fiber-shaped super-capacitor is developed by winding aligned carbon nanotube/polyaniline composite sheets on an elastic fiber. The fiber-shaped supercapacitors demonstrate rapid and reversible chromatic transitions under different working states, which can be directly observed by the naked eye. They are also stretchable and flexible, and are woven into textiles to display designed signals in addition to storing energy. © 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Electrochromic Radiator Coupon Level Testing and Full Scale Thermal Math Modeling for Use on Altair Lunar Lander

NASA Technical Reports Server (NTRS)

Sheth, Rubik; Bannon, Erika; Bower, Chad

2009-01-01

In order to control system and component temperatures, many spacecraft thermal control systems use a radiator coupled with a pumped fluid loop to reject waste heat from the vehicle. Since heat loads and radiation environments can vary considerably according to mission phase, the thermal control system must be able to vary the heat rejection. The ability to "turn down" the heat rejected from the thermal control system is critically important when designing the system.. Electrochromic technology as a radiator coating is being investigated to vary the amount of heat being rejected by a radiator. Coupon level tests were performed to test the feasibility of the technology. Furthermore, thermal math models were developed to better understand the turndown ratios required by full scale radiator architectures to handle the various operation scenarios during a mission profile for Altair Lunar Lander. This paper summarizes results from coupon level tests as well as thermal math models developed to investigate how electrochromics can be used to provide the largest turn down ratio for a radiator. Data from the various design concepts of radiators and their architectures are outlined. Recommendations are made on which electrochromic radiator concept should be carried further for future thermal vacuum testing.

Electrochromic Radiator Coupon Level Testing and Full Scale Thermal Math Modeling for Use on Altair Lunar Lander

NASA Technical Reports Server (NTRS)

Bannon, Erika T.; Bower, Chad E.; Sheth, Rubik; Stephan, Ryan

2010-01-01

In order to control system and component temperatures, many spacecraft thermal control systems use a radiator coupled with a pumped fluid loop to reject waste heat from the vehicle. Since heat loads and radiation environments can vary considerably according to mission phase, the thermal control system must be able to vary the heat rejection. The ability to "turn down" the heat rejected from the thermal control system is critically important when designing the system. Electrochromic technology as a radiator coating is being investigated to vary the amount of heat rejected by a radiator. Coupon level tests were performed to test the feasibility of this technology. Furthermore, thermal math models were developed to better understand the turndown ratios required by full scale radiator architectures to handle the various operation scenarios encountered during a mission profile for the Altair Lunar Lander. This paper summarizes results from coupon level tests as well as the thermal math models developed to investigate how electrochromics can be used to increase turn down ratios for a radiator. Data from the various design concepts of radiators and their architectures are outlined. Recommendations are made on which electrochromic radiator concept should be carried further for future thermal vacuum testing.

Optics and materials research for controlled radiant energy transfer in buildings

NASA Astrophysics Data System (ADS)

Goldner, R. B.

1983-11-01

The overall objective of the Tufts research program was to identify and attempt to solve some of the key materials problems associated with practical approaches for achieving controlled radiant energy transfer (CRET) through building windows and envelopes, so as to decrease heating and cooling loads in buildings. Major accomplishments included: the identification of electrochromic (EC)-based structures as the preferred structures for achieving CRET; the identification of modulated reflectivity as the preferred mode of operation for EC-based structures; demonstration of the feasibility of operating EC-materials in a modulated R(lambda) mode; and demonstration of the applicability of free electron model to colored polycrystalline WO3 films.

Improved Electrochromic Characteristics of a Honeycomb-Structured Film Composed of NiO.

PubMed

Yang, Hyeeun; Lee, Yulhee; Kim, Dong In; Seo, Hyeon Jin; Yu, Jung-Hoon; Nam, Sang-Hun; Boo, Jin-Hyo

2018-09-01

Color changes controlled by electronic energies have been studied for many years in order to fabricate energy-efficient smart windows. Reduction and oxidization of nickel oxide under the appropriate voltage can change the color of a window. For a superior nickel oxide (NiO) electrochromic device (ECD), it is important to control the chemical and physical characteristics of the surface. In this study, we applied polystyrene bead templates to nickel oxide films to fabricate a honeycomb-structured electrochromic (EC) layer. We synthesized uniform polystyrene beads using the chemical wet method and placed them on substrates to create honeycomb-structured NiO films. Then, the EC characteristics of the nickel oxide films with a honeycomb structure were evaluated with UV-Visible and cyclic voltammetry. FE-SEM and AFM were used to measure the morphologies of the nanostructures and the efficiencies of the redox reactions related to the specific surface area.

Behaviour of one-step spray-coated carbon nanotube supercapacitor in ambient light harvester circuit with printed organic solar cell and electrochromic display.

PubMed

Tuukkanen, Sampo; Välimäki, Marja; Lehtimäki, Suvi; Vuorinen, Tiina; Lupo, Donald

2016-03-09

A printed energy harvesting and storage circuit powered by ambient office lighting and its use to power a printed display is reported. The autonomous device is composed of three printed electronic components: an organic photovoltaic module, a carbon-nanotubes-only supercapacitor and an electrochromic display element. Components are fabricated from safe and environmentally friendly materials, and have been fabricated using solution processing methods, which translate into low-cost and high-throughput manufacturing. A supercapacitor made of spray-coated carbon nanotube based ink and aqueous NaCl electrolyte was charged using a printed organic photovoltaic module exposed to office lighting conditions. The supercapacitor charging rate, self-discharge rate and display operation were studied in detail. The supercapacitor self-discharge rate was found to depend on the charging rate. The fully charged supercapacitor was used as a power source to run the electrochromic display over 50 times.

Eco-efficiency evaluation of a smart window prototype.

PubMed

Syrrakou, E; Papaefthimiou, S; Yianoulis, P

2006-04-15

An eco-efficiency analysis was conducted using indicators suitably defined to evaluate the performance of an electrochromic window acting as an energy saving component in buildings. Combining the indicators for various parameters (control scenario, expected lifetime, climatic type, purchase cost) significant conclusions are drawn for the development and the potential applications of the device compared to other commercial fenestration products. The reduction of the purchase cost (to 200 euros/m2) and the increase of the lifetime (above 15 years) are the two main targets for achieving both cost and environmental efficiency. An electrochromic device, implemented in cooling dominated areas and operated with an optimum control strategy for the maximum expected lifetime (25 years), can reduce the building energy requirements by 52%. Furthermore, the total energy savings provided will be 33 times more than the energy required for its production while the emission of 615 kg CO2 equivalent per electrochromic glazing unit can be avoided.

Charge Transfer Nanocomposites: The Effects of Scale-Hierarchy

DTIC Science & Technology

2006-12-31

of nanoparticles in the polymer. Further, the active electrochromic spectral window showed a bias dependant tuning and a broadened spectral response...750 1000 X(nm)X(nm) Figure 4.8. a) The bias dependant electrochromic properties of Ag+ PEDOT:PSS composite and b) that of Au+ PEDOT:PSS This report...these is intimately dependent on the local ordering of host and nanophase, as well as the meso- ordering of host and nanophase. And, each of these, self

Solar driven electrochromic photoelectrochemical fuel cells for simultaneous energy conversion, storage and self-powered sensing.

PubMed

Wang, Yanhu; Zhang, Lina; Cui, Kang; Xu, Caixia; Li, Hao; Liu, Hong; Yu, Jinghua

2018-02-15

One solar-driven electrochromic photoelectrochemical fuel cell (PFC) with highly efficient energy conversion and storage is easily constructed to achieve quantitative self-powered sensing. Layered bismuth oxyiodide-zinc oxide nanorod arrays (ZnO@BiOI NRA) with a core/shell p-n heterostructure are fabricated as the photoanode with electrochromic Prussian blue (PB) as the cathode. The core/shell p-n heterostructure for the ZnO@BiOI photoanode can effectively boost the photoelectrochemical (PEC) performance through the improvement of photon absorption and charge carrier separation. The optimal assembled PFC yields an open-circuit voltage (V OC ) of 0.48 V with the maximum power output density (P max ) as high as 155 μW cm -2 upon illumination. Benefitting from the interactive color-changing behavior of PB, the cathode not only exhibits cathodic catalytic activity in the PFC but also serves as an electrochromic display for self-powered sensing. The as-constructed PFC possesses multiple readable signal output nanochannels through the maximum power output density (P max ) of the PFC or the color change of PB. Meanwhile, the dual-signal-output makes the as-constructed self-powered sensor highly available in various operations demands with the enhanced reliability. With the advantages of high efficiency of PFCs, unique assay ability, and broad environmental suitability, the constructed self-powered platform shows broad application prospects as an integrated smart analytical device.

Stimulus-Responsive Micro-Supercapacitors with Ultrahigh Energy Density and Reversible Electrochromic Window.

PubMed

Zhang, Panpan; Zhu, Feng; Wang, Faxing; Wang, Jinhui; Dong, Renhao; Zhuang, Xiaodong; Schmidt, Oliver G; Feng, Xinliang

2017-02-01

Stimulus-responsive micro-supercapacitors (SR-MSCs) with ultrahigh volumetric energy density and reversible electrochromic effect are successfully fabricated by employing a vanadium pentoxide and electrochemical exfoliated graphene-based hybrid nanopaper and viologen as electrode and stimulus-responsive material, respectively. The fabricated high-performance SR-MSCs offer new opportunities for intuitively observing the working state of energy devices without the aid of extra equipment and techniques. © 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Optics and materials research for controlled radiant energy transfer in buildings

DOE Office of Scientific and Technical Information (OSTI.GOV)

Goldner, R.B.

1983-11-01

The overall objective of the Tufts research program was to identify and attempt to solve some of the key materials problems associated with practical approaches for achieving controlled radiant energy transfer (CRET) through building windows and envelopes, so as to decrease heating and cooling loads in buildings. Major accomplishments included: the identification of electrochromic (EC)-based structures as the preferred structures for achieving CRET the identification of modulated reflectivity as the preferred mode of operation for EC-based structures demonstration of the feasibility of operating EC-materials in a modulated R(lambda) mode and demonstration of the applicability of free electron model to coloredmore » polycrystalline WO3 films.« less

Sunlight-charged electrochromic battery based on hybrid film of tungsten oxide and polyaniline

NASA Astrophysics Data System (ADS)

Chang, Xueting; Hu, Ruirui; Sun, Shibin; Liu, Jingrong; Lei, Yanhua; Liu, Tao; Dong, Lihua; Yin, Yansheng

2018-05-01

Electrochromic (EC) energy storage devices that could realize the multifunctional integration of energy storage and electrochromism have gained much recent attention. Herein, an EC battery based on the hybrid film of W18O49 and polyaniline (PANI) is developed and assembled, which integrates energy storage and EC functions in one device. The W18O49/PANI-EC battery delivers a discharging capacity of 52.96 mA h g-1, which is about two times higher than that of the W18O49-EC battery. Sunlight irradiation could greatly promote the oxidation reactions of both W18O49 and PANI during the charging process of the W18O49/PANI-EC battery, thus effectively accelerating the charging rate. This work provides a green, convenient, environmentally friendly, and cost-free charging strategy for the EC energy systems and could further advance the development of the multifunctional EC devices based on the organic/inorganic composites.

Enhanced electrochromic and energy storage performance in mesoporous WO3 film and its application in a bi-functional smart window.

PubMed

Wang, Wei-Qi; Wang, Xiu-Li; Xia, Xin-Hui; Yao, Zhu-Jun; Zhong, Yu; Tu, Jiang-Ping

2018-05-03

Construction of multifunctional photoelectrochemical energy devices is of great importance to energy saving. In this study, we have successfully prepared a mesoporous WO3 film on FTO glass via a facile dip-coating sol-gel method; the designed mesoporous WO3 film exhibited advantages including high transparency, good adhesion and high porosity. Also, multifunctional integrated energy storage and optical modulation ability are simultaneously achieved by the mesoporous WO3 film. Impressively, the mesoporous WO3 film exhibits a noticeable electrochromic energy storage performance with a large optical modulation up to 75.6% at 633 nm, accompanied by energy storage with a specific capacity of 75.3 mA h g-1. Furthermore, a full electrochromic energy storage window assembled with the mesoporous WO3 anode and PANI nanoparticle cathode is demonstrated with large optical modulation and good long-term stability. Our research provides a new route to realize the coincident utilization of optical-electrochemical energy.

Electrochromic and optical properties of tungsten oxide films deposited with DC sputtering by introducing hydrogen.

PubMed

Chen, Hsi-Chao; Jan, Der-Jun; Luo, Yu-Siang; Huang, Kuo-Ting

2014-02-01

Research was undertaken to investigate the electrochromic and optical properties of tungsten oxide (WO3) films deposited by introducing hydrogen with a direct current (DC) and pulsed DC sputtering. The results show that WO3 films have optimum electrochromic properties at a hydrogen flow of 4 and 3 sccm for DC and pulsed DC, respectively. In the Raman spectra, the peak intensity increased with the increase of hydrogen flow at both 770  cm1 and 950  cm(-1) peaks, which resulted in bonds of W(6+)-O and W(6+)=O, respectively. Simultaneously, the transmittance (ΔT550  nm) variations were 65.6% and 64.4%, and the average transmittance (ΔT400-500  nm) variations were 56.7% and 56.4% for DC and pulsed DC, respectively. The bleached/colored ability of the cyclic voltammograms (CVs) was DC>pulsed DC, and the resistances of AC impedance were pulsed DC>DC.

A skin-integrated transparent and stretchable strain sensor with interactive color-changing electrochromic displays.

PubMed

Park, Heun; Kim, Dong Sik; Hong, Soo Yeong; Kim, Chulmin; Yun, Jun Yeong; Oh, Seung Yun; Jin, Sang Woo; Jeong, Yu Ra; Kim, Gyu Tae; Ha, Jeong Sook

2017-06-08

In this study, we report on the development of a stretchable, transparent, and skin-attachable strain sensor integrated with a flexible electrochromic device as a human skin-inspired interactive color-changing system. The strain sensor consists of a spin-coated conductive nanocomposite film of poly(vinyl alcohol)/multi-walled carbon nanotube/poly(3,4-ethylenedioxythiophene):poly(styrenesulfonate) on a polydimethylsiloxane substrate. The sensor exhibits excellent performance of high sensitivity, high durability, fast response, and high transparency. An electrochromic device (ECD) made of electrochemically synthesized polyaniline nanofibers and V 2 O 5 on an indium-tin-oxide-coated polyethylene terephthalate film experiences a change in color from yellow to dark blue on application of voltage. The strain sensor and ECD are integrated on skin via an Arduino circuit for an interactive color change with the variation of the applied strain, which enables a real-time visual display of body motion. This integrated system demonstrates high potential for use in interactive wearable devices, military applications, and smart robots.

Behaviour of one-step spray-coated carbon nanotube supercapacitor in ambient light harvester circuit with printed organic solar cell and electrochromic display

PubMed Central

Tuukkanen, Sampo; Välimäki, Marja; Lehtimäki, Suvi; Vuorinen, Tiina; Lupo, Donald

2016-01-01

A printed energy harvesting and storage circuit powered by ambient office lighting and its use to power a printed display is reported. The autonomous device is composed of three printed electronic components: an organic photovoltaic module, a carbon-nanotubes-only supercapacitor and an electrochromic display element. Components are fabricated from safe and environmentally friendly materials, and have been fabricated using solution processing methods, which translate into low-cost and high-throughput manufacturing. A supercapacitor made of spray-coated carbon nanotube based ink and aqueous NaCl electrolyte was charged using a printed organic photovoltaic module exposed to office lighting conditions. The supercapacitor charging rate, self-discharge rate and display operation were studied in detail. The supercapacitor self-discharge rate was found to depend on the charging rate. The fully charged supercapacitor was used as a power source to run the electrochromic display over 50 times. PMID:26957019

Patternable PEDOT nanofilms with grid electrodes for transparent electrochromic devices targeting thermal camouflage.

PubMed

Kim, Bumsoo; Koh, Jong Kwan; Park, Junyong; Ahn, Changui; Ahn, Joonmo; Kim, Jong Hak; Jeon, Seokwoo

2015-01-01

This paper reports a new type of transmitting mode electrochromic device that uses the high-contrast electrochromism of poly(3,4-ethylenedioxythiophene) (PEDOT) and operates at long-wavelength infrared (8-12 μm) . To maximize the transmittance contrast and transmittance contrast ratio of the device for thermal camouflage, we control the thickness of the thin PEDOT layer from 25 nm to 400 nm and develop a design of grid-type counter electrodes. The cyclability can be greatly improved by selective deposition of the PEDOT film on grid electrodes as an ion storage layer without any loss of overall transmittance. The device with optimized architectures shows a high transmittance contrast ratio of 83 % at a wavelength of 10 μm with a response rate under 1.4 s when alternating voltage is applied. Captured images of an LED lamp behind the device prove the possibility of active, film-type camouflage against thermal detection.

Spectroscopic optimization of all-solid-state electrochromic devices using PANI

NASA Astrophysics Data System (ADS)

Hugot-Le Goff, Anne; Bernard, Marie-Claude; Bich, Vu T.; Binh, Nguyen T.; Zeng, Wen

1997-12-01

The interesting optical properties of polyaniline (PANI) allowed its utilization in all solid-state electrochromic devices. Using a sulfonic acid polymer as solid electrolyte gave to PANI an unusual optical behavior leading to electrochromic properties very superior to the properties that it has in any liquid inorganic electrolyte. The improved conductivity of PANI doped with AMP-sulfonate is displayed by the presence of a free-carriers tail even at pH as high as 4.5. The free-carriers tail is studied using UV/vis/near IR spectroscopy, and the kinetics of coloration/bleaching are studied using Optical Multichannel Analysis in the 1.5 - 3 eV range. The modifications of the PANI optical features by solid-state doping are examined. The possibility to still improve the performances of these devices--in particular their rate of color change--by using `secondarily doped' PANI is investigated, which requires a preliminary spectrochemical analysis of PANI films doped with camphorsulfonic acid and treated in m-cresol during their electrochemical polarization.

Optical, structural and electrochromic behavior studies on nanocomposite thin film of aniline, o-toluidine and WO3

NASA Astrophysics Data System (ADS)

Najafi-Ashtiani, Hamed; Bahari, Ali

2016-08-01

In the field of materials for electrochromic (EC) applications much attention was paid to the derivatives of aniline. We report on the optical, structural and electrochromic properties of electrochromic thin film based on composite of WO3 nanoparticles and copolymer of aniline and o-toluidine prepared by electrochemical polymerization method on fluorine doped tin oxide (FTO) coated glass. The thin film was studied by X-ray diffraction (XRD) and Fourier transforms infrared (FTIR) spectroscopy. The morphology of prepared thin film was characterized by field emission scanning electron microscopy (FESEM), atomic force microscopy (AFM) and the thermal gravimetric analysis (TGA) as well. The optical spectra of nanocomposite thin film were characterized in the 200-900 nm wavelength range and EC properties of nanocomposite thin film were studied by cyclic voltammetry (CV). The calculation of optical band gaps of thin film exhibited that the thin film has directly allowed transition with the values of 2.63 eV on first region and 3.80 eV on second region. Dispersion parameters were calculated based on the single oscillator model. Finally, important parameters such as dispersion energy, oscillator energy and lattice dielectric constant were determined and compared with the data from other researchers. The nonlinear optical properties such as nonlinear optical susceptibility, nonlinear absorption coefficient and nonlinear refractive index were extracted. The obtained results of nanocomposite thin film can be useful for the optoelectronic applications.

Self-Stacked Reduced Graphene Oxide Nanosheets Coated with Cobalt-Nickel Hydroxide by One-Step Electrochemical Deposition toward Flexible Electrochromic Supercapacitors.

PubMed

Grote, Fabian; Yu, Zi-You; Wang, Jin-Long; Yu, Shu-Hong; Lei, Yong

2015-09-01

The implementation of an optical function into supercapacitors is an innovative approach to make energy storage devices smarter and to meet the requirements of smart electronics. Here, it is reported for the first time that nickel-cobalt hydroxide on reduced graphene oxide can be utilized for flexible electrochromic supercapacitors. A new and straightforward one-step electrochemical deposition process is introduced that is capable of simultaneously reducing GO and depositing amorphous Co(1-x)Ni(x)(OH)2 on the rGO. It is shown that the rGO nanosheets are homogeneously coated with metal hydroxide and are vertically stacked. No high temperature processes are used so that flexible polymer-based substrates can be coated. The synthesized self-stacked rGO-Co(1-x)Ni(x)(OH)2 nanosheet material exhibits pseudocapacitive charge storage behavior with excellent rate capability, high Columbic efficiency, and nondiffusion limited behavior. It is shown that the electrochemical behavior of the Ni(OH)2 can be modulated, by simultaneously depositing nickel and cobalt hydroxide, into broad oxidization and reduction bands. Further, the material exhibits electrochromic property and can switch between a bleached and transparent state. Literature comparison reveals that the performance characteristics of the rGO-Co(1-x)Ni(x)(OH)2 nanosheet material, in terms of gravimetric capacitance, areal capacitance, and long-term cycling stability, are among the highest reported values of supercapacitors with electrochromic property. © 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Printable organic and inorganic materials for flexible electrochemical devices

NASA Astrophysics Data System (ADS)

Wojcik, Pawel Jerzy

The growing demand of consumer printed electronics such as smart cards, smart packaging, automotive displays, electronic paper and others led to the increased interest in fully printed electrochemical devices. These components are expected to be developed based on printed thin films derived from cheap and widely accessible compounds. This dissertation presents the long stretch of technical research that was performed to realize printed energy efficient concepts such as electrochromic displays and smart-windows. Within this broad theme, the presented study had a number of specific objectives, however, the overall aim was to develop low-cost material systems (i.e. printable mixtures) at a lab-scale, which would be compatible with large-scale roll-to-roll processing. Presented results concern three main topics: (i) dual-phase inorganic electrochromic material processed at low temperature, (ii) enhancement in electrochromic performance via metaloxide nanoparticles engineering, and (iii) highly conductive and mechanically stable solid-state electrolyte. First two topics are related to crystallographic structure of metal-oxide films derived from sol-gel precursor, which is shown to be critical for electrochemical performance. The proposed method of microstructure control enables development of electrochromic films which outperform their amorphous or nanocrystalline analogues presented in the state-of-the-art due to their superior chemical and physical properties. Developed materials and processes resulted in electrochemical devices exhibiting optical density on the level of 0.82 and switching time shorter than 3 seconds, reaching performance at practical level. Third topic concerns a new concept of solid state electrolyte based on plastic crystal doped with lithium salt, dispersed in a thermosetting polymer resin network. This soft matter printable electrolyte meets requirements for electrochromic applications, exhibiting ionic conductivities of 10. -6 - 10. -4 S cm-1 at ambient temperature, Young'sModulus in the range of 0.1 - 1.4 MPa and operational temperature up to 115°C. In order to extract information from massive computational data, model developed material systems and optimize composition, an efficient mathematical methodology based on statistical techniques was applied. This approach significantly reduces the number of experiments to be realized, while maintaining a high accuracy of the analysis. Using this approach the number of experiments has been reduced from 162 down to 30 in case of dual-phase electrochromic films, and from 729 down to 28 in study on solid-state electrolyte (when comparing to classical three-level full factorial approach). Coupling of statistical methods with formulation of electrochemically active materials shows the potential to maximize the capabilities of these systems.

Ionically self-assembled monolayers (ISAMs)

NASA Astrophysics Data System (ADS)

Janik, John

2001-04-01

Ionically self-assembled monolayers (ISAMs), fabricated by alternate adsorption of cationic and anionic components, yield exceptionally homogeneous thin films with sub-nanometer control of the thickness and relative special location of the component materials. Using organic electrochromic materials such as polyaniline, we report studies of electrochromic responses in ISAM films. Reversible changes in the absorption spectrum are observed with the application of voltages on the order of 1.0 V. Measurements are made using both liquid electrolytes and in all-solid state devices incorporating solid polyelectrolytes such as poly(2-acylamido 2-methyl propane sulfonic acid) (PAMPS).

Doping, Ionic Conductivity and Photothermal Stability of Functionalized DNA for Solar Energy Conversion and Electrochromic Applications

DTIC Science & Technology

2011-06-01

and coworkers 1,2,3,4 . They are renewable and biodegradable materials, recovered from waste in food industry (fruits, animal and fish meat waste) and...charges leads to the change of its absorption spectrum, or in other words to a change of its color . However in most cases the electrolyte used is in...electrodes (cf. Fig. 25). CeO2- TiO2 BK7 BK7 SOLID ELECTROLYTE ITO WO3 ITO Fig. 25. Structure of the used electrochromic cell 21 Figure 26

Electrodeposited non-stoichiometric tungstic acid for electrochromic applications: film growth modes, crystal structure, redox behavior and stability

NASA Astrophysics Data System (ADS)

Pugolovkin, Leonid V.; Cherstiouk, Olga V.; Plyasova, Lyudmila M.; Molina, Irina Yu.; Kardash, Tatyana Yu.; Stonkus, Olga A.; Yatsenko, Dmitriy A.; Kaichev, Vasily V.; Tsirlina, Galina A.

2016-12-01

Bath composition for cathodic electrodeposition of non-stoichiometric hydrated tungstic acid with high electrochromic efficiency is optimized with account for selective electroreduction of certain isopolytungstates. XRD data for thin electrodeposited films and chemically synthesized bulk tungstic acid dihydrate are compared in the context of reversible oxidation and reduction in hydrogen atmosphere, in presence of Pt catalyst. XPS and TEM techniques are attracted to understand the nature of reversible and less reversible transformations of films in the course of their storage and operation.

Design of electrochromic window technology with single and multi-color patterns

NASA Astrophysics Data System (ADS)

Kim, Sooyeun

The electrochromic window (ECW) technology has gained a lot of attention due to its current and potential applications for office, vehicle and aircraft windows. Center for Intelligent Materials and System (CIMS) at University of Washington has proposed the new design of an ECW for its high contrast, rapid switching speed and long cyclic lifetime. Three primary components of the ECW are an electrochromic (EC) layer, an ion conducting layer and an ion storage layer. A V2O5-TiO2 (V/Ti=70/30) film, fabricated by a sol-gel electrophoretic deposition, was proposed as an ion storage layer. The film was characterized by X-ray diffraction, a scanning probe microscope and impedance spectroscopy. Its optical and electrochemical properties were investigated. The poly-(3,3-dimethy1-3,4-dihydro-2H-thieno[3,4-b][1,4]dioxepine) film was suggested as an EC layer. Its electropolymerization kinetics and optical and electrochemical properties were reported. The V2O 5-TiO2 film based ECW was successfully fabricated and examined. The ECW exhibited its high electrochromic contrast, rapid switching speed and long-term cyclic durability. Its contrast (Delta%T = Tmax-T min) was 68%T with a minimum transmittance of 1% at 580 nm wavelength. The ECW took five seconds for complete coloration, while it did four seconds for complete bleaching. Its asymmetric switching behavior was explained by modeling the ECW as a simple equivalent circuit. The cyclic durability of the ECW was measured over 150,000 cycles. It revealed the contrast degradation of only 2% at 580 nm wavelength. The ECW dimensions were scaled up to 300 x 300 mm2, demonstrating their high contrast and long-term electrochemical cycle stability. Multi-color pattern electrochromic window technology was considered to evolve toward higher definition devices. Patterning of electrodes was essential to fabricate multi-color pattern ECWs which required the separation of adjacent electrodes. New fabrication procedures to create a pattern electrode were challenged. Two monomers were selectively electropolymerized on the pattern electrode in order to display a set of colors. The successful construction of a two-color pattern ECW was based on the sandwich-type configuration.

Black-to-Transmissive Electrochromism with Visible-to-Near-Infrared Switching of a Co(II)-Based Metallo-Supramolecular Polymer for Smart Window and Digital Signage Applications.

PubMed

Hsu, Chih-Yu; Zhang, Jian; Sato, Takashi; Moriyama, Satoshi; Higuchi, Masayoshi

2015-08-26

Black-to-transmissive electrochromism has been obtained with a Co(II)-based metallo-supramolecular polymer (polyCo). Thin films of polyCo, based on bisterpyridine ligand assembled with Co(II) metal ion, were constructed by spray casting the polymer onto ITO glass. With such simple fabricating means to form good-quality films, polyCo films show stable switching at the central metal ion of the Co(II)/Co(I) redox reaction when immersed in aqueous solution. With an increase in the pH of the aqueous electrolyte solution from neutral, the film exhibits a color response due to the interaction between the d-orbital electron and hydroxide ions affecting the d-d* transition. As a result, a nearly transparent-to-black electrochromic performance can be achieved with a transmittance difference at 550 nm of 74.3% (81.9-7.6%) in pH 13 solution. The light absorption of the film can be tuned over light regions from visible to near-infrared with a large attenuation.

Durable electrooptic devices comprising ionic liquids

DOEpatents

Agrawal, Anoop; Cronin, John P.; Tonazzi, Juan C. L.; Warner, Benjamin P.; McCleskey, T. Mark; Burrell, Anthony K.

2005-11-01

Electrolyte solutions for electrochromic devices such as rear view mirrors and displays with low leakage currents are prepared using inexpensive, low conductivity conductors. Preferred electrolytes include bifunctional redox dyes and molten salt solvents with enhanced stability toward ultraviolet radiation. The solvents include lithium or quaternary ammonium cations, and perfluorinated sulfonylimide anions selected from trifluoromethylsulfonate (CF3SO3-), bis(trifluoromethylsulfonyl)imide ((CF3SO2)2N-), bis(perfluoroethylsulfonyl)imide ((CF3CF2SO2)2N-) and tris(trifluoromethylsulfonyl)methide ((CF3SO2)3C-). Electroluminescent, electrochromic and photoelectrochromic devices with nanostructured electrodes include ionic liquids with bifunctional redox dyes.

Electrochemistry of poly(3,4-ethylenedioxythiophene)-polyaniline/ Prussian blue electrochromic devices containing an ionic liquid based gel electrolyte film.

PubMed

Deepa, Melepurath; Awadhia, Arvind; Bhandari, Shweta

2009-07-21

Electrochromic devices based on poly(3,4-ethylenedioxythiophene) (PEDOT) as the cathodic coloring electrode and polyaniline (PANI) or Prussian blue (PB) as the counter electrode containing a highly conductive, self-supporting, distensible and transparent polymer-gel electrolyte film encapsulating an ionic liquid, 1-butyl-1-methylpyrrolidiniumbis-(trifluoromethylsulfonyl)imide, have been fabricated. Polarization, charge transfer and diffusion processes control the electrochemistry of the functional electrodes during coloration and bleaching and these phenomena differ when PEDOT and PANI/PB were employed alternately as working electrodes. While the electrochemical impedance response shows good similitude for PEDOT and PANI electrodes, the responses of PEDOT and PB were significantly different in the PEDOT-PB device, especially during reduction of PB, wherein the overall amplitude of the impedance response is enormous. Large values of the coloration efficiency maxima of 281 cm2 C(-1) (lambda = 583 nm) and 274 cm2 C(-1) (lambda = 602 nm), achieved at -1.0 and -1.5 V for the PEDOT PANI and PEDOT-PB devices have been correlated to the particularly low magnitude of charge transfer resistance and high polarization capacitance operative at the PEDOT ionic liquid based electrolyte interface at these dc potentials, thus allowing facile ion-transport and consequently resulting in enhanced absorption modulation. Moderately fast switching kinetics and the ability of these devices to sustain about 2500 cycles of clear-to-dark and dark-to-clear without incurring major losses in the optical contrast, along with the ease of construction of these cells in terms of high scalability and reproducibility of the synthetic procedure for fabrication of the electrochromic films and the ionic liquid based gel electrolyte film, are indicators of the promise these devices hold for practical applications like electrochromic windows and displays.

Modeling electrochromic poly-dioxythiophene-containing materials through TDDFT.

PubMed

Wheeler, D L; Rainwater, L E; Green, A R; Tomlinson, A L

2017-08-02

A DFT/TDDFT model was developed to predict the chemical properties for three colored to nearly transmissive electrochromic polymers synthesized by the John Reynolds's group. Using a functional-basis set pairing of mPW1PBE/cc-PVDZ along with the conductor polarizable calculation model (CPCM), simulated neutral spectra showed a strong correlation to the experimental UV-Vis data where the largest absolute peak maximum difference was 14 nm. Frontier molecular orbitals, electronic transitions, and ground-state geometries of these systems were evaluated to provide further information about the oxidative process the polymers undergo. Here we report the first colorimetric model using this level of theory.

Electrochromic TiO2 Thin Film Prepared by Dip-Coating Technique

NASA Astrophysics Data System (ADS)

Suriani, S.; Kamisah, M. M.

2002-12-01

Titanium dioxide (TiO2) thin films were prepared by using sol-gel dip coating technique. The coating solutions were prepared by reacting titanium isopropoxide as precursors and ethanol as solvent. The films were formed on transparent ITO-coated glass by a dip coating technique and final dried at various temperatures up to 600 °C for 30 minutes. The films were characterized with the UV-Vis-NIR Spectrometer, Scanning Electron Microscopy (SEM) and X-ray diffractometer (XRD). XRD results show that the films dried at 600 °C form anatase structure. From the spectroscopic studies, the sample shows electrochromic property.

Ultra-large optical modulation of electrochromic porous WO3 film and the local monitoring of redox activity† †Electronic supplementary information (ESI) available. See DOI: 10.1039/c5sc03727a

PubMed Central

Cai, Guofa; Cui, Mengqi; Kumar, Vipin; Darmawan, Peter; Wang, Jiangxin; Wang, Xu; Lee-Sie Eh, Alice; Qian, Kai

2016-01-01

Porous WO3 films with ultra-high transmittance modulation were successfully fabricated on different substrates by a novel, facile and economical pulsed electrochemical deposited method with 1.1 s interval time between each pulse. The near ideal optical modulation (97.7% at 633 nm), fast switching speed (6 and 2.7 s), high coloration efficiency (118.3 cm2 C–1), and excellent cycling stability are achieved by the porous WO3 on ITO-coated glass. The outstanding electrochromic performances of the porous WO3 film were mainly attributed to the porous structure, which facilitates the charge-transfer, promotes the electrolyte infiltration and alleviates the expansion of the WO3 during H+ insertion compared to that of the compact structure. In addition, the relationships between the structural and electrochemical activity of the electrochromic WO3 films were further explored by the scanning electrochemical microscopy. These results testify that the porous structure can promote the infiltration of electrolyte and reduce the diffusion path, which consequently enhance the electrochemical activity. PMID:29910894

Assembling tungsten oxide hydrate nanocrystal colloids formed by laser ablation in liquid into fast-response electrochromic films.

PubMed

Wang, Shalong; Dou, Kang; Zou, Yousheng; Dong, Yuhang; Li, Jubin; Ju, Dan; Zeng, Haibo

2017-03-01

High-performance electrochromic films based on tungsten oxide hydrate ([WO 2 (O 2 )H 2 O]·1.66H 2 O) colloidal nanocrystals with fast switching speed were fabricated by laser ablation in a mixture of water and hydrogen peroxide followed by electrophoretic methods. Through electrophoretic deposition, the nanoparticles in the colloids synthesized by laser ablation aggregated onto the FTO coated glass substrate forming a lager cell with a uniform size of around 200nm, which subsequently self-assembled into a porous tungsten oxide hydrate film. By optimizing the electrophoretic time (800s) and voltage (-0.5V), the mesh-like porous tungsten oxide hydrate film achieved a wide optical modulation of 32% at 632nm, fast coloration and bleaching response speed of 7.8 s and 1.7s respectively due to the synergetic effect of the unique atomic structure of [WO 2 (O 2 )H 2 O]·1.66H 2 O and porous structure with large surface area that facilitates the ion insertion/extraction. Thus the tungsten oxide hydrate can be a promising electrochromic material for practical applications. Copyright © 2016 Elsevier Inc. All rights reserved.

Electrochemical synthesis, characterization and electrochromic properties of a copolymer based on 1,4-bis(2-thienyl)naphthalene and pyrene

NASA Astrophysics Data System (ADS)

Wang, Bin; Zhao, Jinsheng; Cui, Chuansheng; Wang, Min; Wang, Zhong; He, Qingpeng

2012-05-01

Electrochemical copolymerization of 1,4-bis(2-thienyl)naphthalene (BTN) with pyrene is carried out in acetonitrile (ACN) solution containing sodium perchlorate (NaClO4) as a supporting electrolyte. Characterizations of the resulting copolymer P(BTN-co-pyrene) are performed by cyclic voltammetry (CV), UV-vis spectroscopy, Fourier transform infrared spectroscopy (FT-IR) and scanning electron microscopy (SEM). The P(BTN-co-pyrene) film has distinct electrochromic properties and exhibits three different colors (yellowish green, green and blue) under various potentials. Maximum contrast (ΔT%) and response time of the copolymer film are measured as 37.8% and 1.71 s at 687 nm. An electrochromic device (ECD) based on P(BTN-co-pyrene) and poly(3,4-ethylenedioxythiophene) (PEDOT) is constructed and characterized. Neutral state of device shows green color while oxidized state reveals blue color. This ECD shows a maximum optical contrast (ΔT%) of 24.4% with a response time of 0.43 s at 635 nm. The coloration efficiency (CE) of the device is calculated to be 349 cm2 C-1 at 635 nm. In addition, the ECD also has satisfactory optical memories and redox stability.

Defect engineering of two-dimensional WO3 nanosheets for enhanced electrochromism and photoeletrochemical performance

NASA Astrophysics Data System (ADS)

Zhou, Xiaofang; Zheng, Xiaoli; Yan, Bo; Xu, Tao; Xu, Qun

2017-04-01

The capability of introduction of oxygen vacancies in a controlled way has emerged as the heart of modern transition metal oxide semiconductor chemistry. As chemical defects, the oxygen vacancies have been proposed as electron donors, which are prone to increase carrier density and promote charge carrier separation. Herein, we have successfully prepared 2D WO3 ultrathin nanosheets with abundant surface oxygen vacancies by a combination of facile solvothermal reaction and hydrogenation method. The resultant hydrogenated WO3 ultrathin nanosheets exhibit remarkable electrochromism and photocatalytic performances compared with the non-hydrogenated samples, mainly due to their increased oxygen vacancies, narrowed band gap coupled with fast charge transfer and enhanced adsorption of visible light.

Durable electrooptic devices comprising ionic liquids

DOEpatents

Warner, Benjamin P [Los Alamos, NM; McCleskey, T Mark [Los Alamos, NM; Burrell, Anthony K [Los Alamos, NM

2006-10-10

Electrolyte solutions for electrochromic devices such as rear view mirrors and displays with low leakage currents are prepared using inexpensive, low conductivity conductors. Preferred electrolytes include bifunctional redox dyes and molten salt solvents with enhanced stability toward ultraviolet radiation. The solvents include lithium or quaternary ammonium cations, and perfluorinated sulfonylimide anions selected from trifluoromethylsulfonate (CF.sub.3SO.sub.3.sup.-), bis(trifluoromethylsulfonyl)imide ((CF.sub.3SO.sub.2).sub.2N.sup.-), bis(perfluoroethylsulfonyl)imide ((CF.sub.3CF.sub.2SO.sub.2).sub.2N.sup.-) and tris(trifluoromethylsulfonyl)methide ((CF.sub.3SO.sub.2).sub.3C.sup.-). Electroluminescent, electrochromic and photoelectrochromic devices with nanostructured electrodes include ionic liquids with bifunctional redox dyes.

Improvement of the electrochromic response of a low-temperature sintered dye-modified porous electrode using low-resistivity indium tin oxide nanoparticles

DOE Office of Scientific and Technical Information (OSTI.GOV)

Watanabe, Yuichi, E-mail: yuichi.watanabe@aist.go.jp; Suemori, Kouji; Hoshino, Satoshi

2016-06-15

An indium tin oxide (ITO) nanoparticle-based porous electrode sintered at low temperatures was investigated as a transparent electrode for electrochromic displays (ECDs). The electrochromic (EC) response of the dye-modified ITO porous electrode sintered at 150 °C, which exhibited a generally low resistivity, was markedly superior to that of a conventional dye-modified TiO{sub 2} porous electrode sintered at the same temperature. Moreover, the EC characteristics of the dye-modified ITO porous electrode sintered at 150 °C were better than those of the high-temperature (450 °C) sintered conventional dye-modified TiO{sub 2} porous electrode. These improvements in the EC characteristics of the dye-modified ITO porous electrode aremore » attributed to its lower resistivity than that of the TiO{sub 2} porous electrodes. In addition to its sufficiently low resistivity attained under the sintering conditions required for flexible ECD applications, the ITO porous film had superior visible-light transparency and dye adsorption capabilities. We conclude that the process temperature, resistivity, optical transmittance, and dye adsorption capability of the ITO porous electrode make it a promising transparent porous electrode for flexible ECD applications.« less

Novel morphology changes from 3D ordered macroporous structure to V2O5 nanofiber grassland and its application in electrochromism

PubMed Central

Tong, Zhongqiu; Lv, Haiming; Zhang, Xiang; Yang, Haowei; Tian, Yanlong; Li, Na; Zhao, Jiupeng; Li, Yao

2015-01-01

Because vanadium pentoxide (V2O5) is the only oxide that shows both anodic and cathodic coloration electrochromism, the reversible lithium ion insertion/extraction processes in V2O5 lead to not only reversible optical parameter changes but also multicolor changes for esthetics. Because of the outstanding electrochemical properties of V2O5 nanofibers, they show great potential to enhance V2O5 electrochromism. However, the development and practical application of V2O5 nanofibers are still lacking, because traditional preparation approaches have several drawbacks, such as multiple processing steps, unsatisfactory electrical contact with the substrate, expensive equipment, and rigorous experimental conditions. Herein, we first report a novel and convenient strategy to prepare grass-like nanofiber-stacked V2O5 films by a simple annealing treatment of an amorphous, three-dimensionally ordered macroporous vanadia film. The V2O5 nanofiber grassland exhibits promising transmittance modulation, fast switching responses, and high color contrast because of the outstanding electrochemical properties of V2O5 nanofibers as well as the high Li-ion diffusion coefficients and good electrical contact with the substrate. Moreover, the morphology transformation mechanism is investigated in detail. PMID:26578383

A transparent electrochromic metal-insulator switching device with three-terminal transistor geometry

NASA Astrophysics Data System (ADS)

Katase, Takayoshi; Onozato, Takaki; Hirono, Misako; Mizuno, Taku; Ohta, Hiromichi

2016-05-01

Proton and hydroxyl ion play an essential role for tuning functionality of oxides because their electronic state can be controlled by modifying oxygen off-stoichiometry and/or protonation. Tungsten trioxide (WO3), a well-known electrochromic (EC) material for smart window, is a wide bandgap insulator, whereas it becomes a metallic conductor HxWO3 by protonation. Although one can utilize electrochromism together with metal-insulator (MI) switching for one device, such EC-MI switching cannot be utilized in current EC devices because of their two-terminal structure with parallel-plate configuration. Here we demonstrate a transparent EC-MI switchable device with three-terminal TFT-type structure using amorphous (a-) WO3 channel layer, which was fabricated on glass substrate at room temperature. We used water-infiltrated nano-porous glass, CAN (calcium aluminate with nano-pores), as a liquid-leakage-free solid gate insulator. At virgin state, the device was fully transparent in the visible-light region. For positive gate voltage, the active channel became dark blue, and electrical resistivity of the a-WO3 layer drastically decreased with protonation. For negative gate voltage, deprotonation occurred and the active channel returned to transparent insulator. Good cycleability of the present transparent EC-MI switching device would have potential for the development of advanced smart windows.

Direct Growth of Crystalline Tungsten Oxide Nanorod Arrays by a Hydrothermal Process and Their Electrochromic Properties

NASA Astrophysics Data System (ADS)

Lu, Chih-Hao; Hon, Min Hsiung; Leu, Ing-Chi

2017-04-01

Transparent crystalline tungsten oxide nanorod arrays for use as an electrochromic layer have been directly prepared on fluorine-doped tin oxide-coated glass via a facile tungsten film-assisted hydrothermal process using aqueous tungsten hexachloride solution. X-ray diffraction analysis and field-emission scanning electron microscopy were used to characterize the phase and morphology of the grown nanostructures. Arrays of tungsten oxide nanorods with diameter of ˜22 nm and length of ˜240 nm were obtained at 200°C after 8 h of hydrothermal reaction. We propose a growth mechanism for the deposition of the monoclinic tungsten oxide phase in the hydrothermal environment. The tungsten film was first oxidized to tungsten oxide to provide seed sites for crystal growth and address the poor connection between the growing tungsten oxide and substrate. Aligned tungsten oxide nanorod arrays can be grown by a W thin film-assisted heterogeneous nucleation process with NaCl as a structure-directing agent. The fabricated electrochromic device demonstrated optical modulation (coloration/bleaching) at 632.8 nm of ˜41.2% after applying a low voltage of 0.1 V for 10 s, indicating the potential of such nanorod array films for use in energy-saving smart windows.

Atomistic Conversion Reaction Mechanism of WO 3 in Secondary Ion Batteries of Li, Na, and Ca

DOE Office of Scientific and Technical Information (OSTI.GOV)

He, Yang; Gu, Meng; Xiao, Haiyan

2016-04-13

Reversible insertion and extraction of ionic species into a host lattice governs the basic operating principle for both rechargeable battery (such as lithium batteries) and electrochromic devices (such as ANA Boeing 787-8 Dreamliner electrochromic window). Intercalation and/or conversion are two fundamental chemical processes for some materials in response to the ion insertion. The interplay between these two chemical processes has never been established. It is speculated that the conversion reaction is initiated by ion intercalation. However, experimental evidence of intercalation and subsequent conversion remains unexplored. Here, using in situ HRTEM and spectroscopy, we captured the atomistic conversion reaction processes duringmore » lithium, sodium and calcium ion insertion into tungsten trioxide (WO3) single crystal model electrodes. An intercalation step right prior to conversion is explicitly revealed at atomic scale for the first time for these three ion species. Combining nanoscale diffraction and ab initio molecular dynamics simulations, it is found that, beyond intercalation, the inserted ion-oxygen bonding formation destabilized the transition-metal framework which gradually shrunk, distorted and finally collapsed to a pseudo-amorphous structure. This study provides a full atomistic picture on the transition from intercalation to conversion, which is of essential for material applications in both secondary ion batteries and electrochromic devices.« less

Caracterizacion y optimizacion electroquimica de dispositivos electrocromicos duales basados en polimeros conductores

NASA Astrophysics Data System (ADS)

Padilla Martinez, Javier

The aim of this thesis is to emphasize the existing relations between electrochemical processes, or electrochemical magnitudes, and colour changes. The work is focused on two aspects: individual spectroelectrochemical characterization of the constituent materials followed by an electrochemical and optical study of the performance of the dual system constructed with those materials. The objective is the optimization of both electrochemical and optical processes in dual conducting polymer systems, obtaining experimental methodologies able to characterize, predict, and finally design optimal dual electrochromic devices. The first part of the study is focused on the development of the proper methodology to obtain an optical characterization of any electrochromic material as a function of its electrochemical properties. Materials used were poly((3,4-ethylenedioxy)thiophene) (PEDOT) and poly-(3,6-bis(2-(3,4-ethylenedioxy)thienyl)-N-methylcarbazole) (PBEDOT-NMCz). PEDOT films are coloured under reduction, while PBEDOT-NMCz are coloured under oxidation, showing complementary colouration, and so they can be used to construct a dual electrochromic device. Based on the obtained experimental results, a theoretical study was undertaken to establish the optical responses of a system comprising several electrochromic layers. The theoretically obtained relations were experimentally proved. Relations obtained allow the prediction of the maximum contrast configuration for a dual system, as a function of the individual electrochemical properties of each constituent material. The system studied was PEDOT/PBEDOT-NMCz. The third chapter deals with the proposal and development of a new experimental methodology able to register the individual oxidation states of each electrode during operation of a dual device, obtaining then direct information about device performance. This methodology allows the study of the influence of different physical and chemical variables, like ratio of redox charge between both constituent films, applied potential to the device and initial oxidation state of the constituent polymer films, on the device performance. The final objective of this work is the construction of electrochromic devices that can be use in real applications out of research or academic contexts. It is necessary then, for safety purposes, to use solid electrolytes in the cell. For final applications it is also required to construct devices of appropriate dimensions. In the fourth chapter, the construction and study of large dimensions and solid state devices for the system PEDOT/PBEDOT-NMCz was carried out. The information obtained in previous sections was used to determine maximum contrast combinations. Problems related to electrodeposition of conducting polymers on large surfaces (around 30 cm2) are discussed, together with the optimization of switching speeds when a solid electrolyte is used. Finally the ability to tune colour states and retain them in the absence of an external potential applied was studied and discussed. The last section deals with the study of two new cathodically colouring polymers, poly(3-(Biphenyl-4-ylmethoxymethyl)-3,4-dihydro-2H-thieno(3,4-b)-(1,2)dioxepine) (BPMOM-ProDOT) and poly-dibenzylProDOT (PDiBz-ProDOT), which have been reported to show larger contrasts than PEDOT. For this reason, dual cells were constructed and checked by combination of these two polymers with PBEDOT-NMCz. The methodology previously developed and used to characterize PEDOT and PBEDOT-NMCz was applied to these polymers. The developed theoretical equations were used to determine the maximum contrast for both systems. Finally, the use of standard optical magnitudes as photopic values is emphasized. Photopic values are standardized by the Commission Internationale de l'Eclairage (CIE), and correspond to real sensations perceived by the human eye, whose sensitivity is different for each wavelength. In this sense the use of photopic values, instead of values corresponding to a single wavelength, is encouraged. (Abstract shortened by UMI.)

Toward Plastic Smart Windows: Optimization of Indium Tin Oxide Electrodes for the Synthesis of Electrochromic Devices on Polycarbonate Substrates.

PubMed

Laurenti, Marco; Bianco, Stefano; Castellino, Micaela; Garino, Nadia; Virga, Alessandro; Pirri, Candido F; Mandracci, Pietro

2016-03-01

Plastic smart windows are becoming one of the key elements in view of the fabrication of inexpensive, lightweight electrochromic (EC) devices to be integrated in the new generation of high-energy-efficiency buildings and automotive applications. However, fabricating electrochromic devices on polymer substrates requires a reduction of process temperature, so in this work we focus on the development of a completely room-temperature deposition process aimed at the preparation of ITO-coated polycarbonate (PC) structures acting as transparent and conductive plastic supports. Without providing any substrate heating or surface activation pretreatments of the polymer, different deposition conditions are used for growing indium tin oxide (ITO) thin films by the radiofrequency magnetron sputtering technique. According to the characterization results, the set of optimal deposition parameters is selected to deposit ITO electrodes having high optical transmittance in the visible range (∼90%) together with low sheet resistance (∼8 ohm/sq). The as-prepared ITO/PC structures are then successfully tested as conductive supports for the fabrication of plastic smart windows. To this purpose, tungsten trioxide thin films are deposited by the reactive sputtering technique on the ITO/PC structures, and the resulting single electrode EC devices are characterized by chronoamperometric experiments and cyclic voltammetry. The fast switching response between colored and bleached states, together with the stability and reversibility of their electrochromic behavior after several cycling tests, are considered to be representative of the high quality of the EC film but especially of the ITO electrode. Indeed, even if no adhesion promoters, additional surface activation pretreatments, or substrate heating were used to promote the mechanical adhesion among the electrode and the PC surface, the observed EC response confirmed that the developed materials can be successfully employed for the fabrication of lightweight and inexpensive plastic EC devices.

High optical and switching performance electrochromic devices based on a zinc oxide nanowire with poly(methyl methacrylate) gel electrolytes

DOE Office of Scientific and Technical Information (OSTI.GOV)

Chun, Young Tea; Chu, Daping, E-mail: dpc31@cam.ac.uk; Neeves, Matthew

2014-11-10

High performance electrochromic devices have been fabricated and demonstrated utilizing a solid polymer electrolyte and zinc oxide (ZnO) nanowire (NW) array counter electrode. The poly(methyl methacrylate) based polymer electrolyte was spin coated upon hydrothermally grown ZnO NW array counter electrodes, while electron beam evaporated NiO{sub x} thin films formed the working electrodes. Excellent optical contrast and switching speeds were observed in the fabricated devices with active areas of 2 cm{sup 2}, exhibiting an optical contrast of 73.11% at the wavelength of 470 nm, combined with a fast switching time of 0.2 s and 0.4 s for bleaching and coloration, respectively.

Large-area flexible monolithic ITO/WO3/Nb2O5/NiVOχ/ITO electrochromic devices prepared by using magnetron sputter deposition

NASA Astrophysics Data System (ADS)

Tang, Chien-Jen; Ye, Jia-Ming; Yang, Yueh-Ting; He, Ju-Liang

2016-05-01

Electrochromic devices (ECDs) have been applied in smart windows to control the transmission of sunlight in green buildings, saving up to 40-50% electricity consumption and ultimately reducing carbon dioxide emissions. However, the high manufacturing costs and difficulty of transportation of conventional massive large area ECDs has limited widespread applications. A unique design replacing the glass substrate commonly used in the ECD windows with inexpensive, light-weight and flexible polymeric substrate materials would accelerate EC adoption allowing them to be supplemented for regular windows without altering window construction. In this study, an ITO/WO3/Nb2O5/NiVOχ/ITO all-solid-state monolithic ECD with an effective area of 24 cm × 18 cm is successfully integrated on a PET substrate by using magnetron sputter deposition. The electrochromic performance and bending durability of the resultant material are also investigated. The experimental results indicate that the ultimate response times for the prepared ECD is 6 s for coloring at an applied voltage of -3 V and 5 s for bleaching at an applied voltage of +3 V, respectively. The optical transmittances for the bleached and colored state at a wavelength of 633 nm are 53% and 11%, respectively. The prepared ECD can sustain over 8000 repeated coloring and bleaching cycles, as well as tolerate a bending radius of curvature of 7.5 cm.

Low-Temperature Ozone Exposure Technique to Modulate the Stoichiometry of WO(x) Nanorods and Optimize the Electrochromic Performance

DOE Office of Scientific and Technical Information (OSTI.GOV)

Lin, F.; Li, C. P.; Chen, G.

A low-temperature ozone exposure technique was employed for the post-treatment of WO{sub x} nanorod thin films fabricated from hot-wire chemical vapor deposition (HWCVD) and ultrasonic spray deposition (USD) techniques. The resulting films were characterized with x-ray diffraction (XRD), transmission electron microscopy (TEM), Raman spectroscopy, UV-vis-NIR spectroscopy and x-ray photoelectron spectroscopy (XPS). The stoichiometry and surface crystallinity of the WO{sub x} thin films were subsequently modulated upon ozone exposure and thermal annealing without particle growth. The electrochromic performance was studied in a LiClO{sub 4}-propylene carbonate electrolyte, and the results suggest that the low-temperature ozone exposure technique is superior to the traditionalmore » high-temperature thermal annealing (employed to more fully oxidize the WO{sub x}). The optical modulation at 670 nm was improved from 35% for the as-deposited film to 57% for the film after ozone exposure at 150 C. The coloration efficiency was improved and the switching speed to the darkened state was significantly accelerated from 18.0 s for the as-deposited film to 11.8 s for the film after the ozone exposure. The process opens an avenue for low-temperature and cost-effective manufacturing of electrochromic films, especially on flexible polymer substrates.« less

A Pilot Demonstration of Electrochromic and Thermochromic Windows in the Denver Federal Center, Building 41, Denver, Colorado

DOE Office of Scientific and Technical Information (OSTI.GOV)

Lee, Eleanor S.; Fernandes, Luis L.; Goudey, Chad Howdy

Chromogenic glazing materials are emerging technologies that tint reversibly from a clear to dark tinted state either passively in response to environmental conditions or actively in response to a command from a switch or building automation system. Switchable coatings on glass manage solar radiation and visible light while enabling unobstructed views to the outdoors. Building energy simulations estimate that actively controlled, near-term chromogenic glazings can reduce perimeter zone heating, ventilation, and airconditioning (HVAC) and lighting energy use by 10-20% and reduce peak electricity demand by 20-30%, achieving energy use levels that are lower than an opaque, insulated wall. This projectmore » demonstrates the use of two types of chromogenic windows: thermochromic and electrochromic windows. By 2013, these windows will begin production in the U.S. by multiple vendors at high-volume manufacturing plants, enabling lower cost and larger area window products to be specified. Both technologies are in the late R&D stage of development, where cost reductions and performance improvements are underway. Electrochromic windows have been installed in numerous buildings over the past four years, but monitored energy-efficiency performance has been independently evaluated in very limited applications. Thermochromic windows have been installed in one other building with an independent evaluation, but results have not yet been made public.« less

One material, multiple functions: graphene/Ni(OH)2 thin films applied in batteries, electrochromism and sensors

PubMed Central

Neiva, Eduardo G. C.; Oliveira, Marcela M.; Bergamini, Márcio F.; Marcolino, Luiz H.; Zarbin, Aldo J. G.

2016-01-01

Different nanocomposites between reduced graphene oxide (rGO) and Ni(OH)2 nanoparticles were synthesized through modifications in the polyol method (starting from graphene oxide (GO) dispersion in ethylene glycol and nickel acetate), processed as thin films through the liquid-liquid interfacial route, homogeneously deposited over transparent electrodes and spectroscopically, microscopically and electrochemically characterized. The thin and transparent nanocomposite films (112 to 513 nm thickness, 62.6 to 19.9% transmittance at 550 nm) consist of α-Ni(OH)2 nanoparticles (mean diameter of 4.9 nm) homogeneously decorating the rGO sheets. As a control sample, neat Ni(OH)2 was prepared in the same way, consisting of porous nanoparticles with diameter ranging from 30 to 80 nm. The nanocomposite thin films present multifunctionality and they were applied as electrodes to alkaline batteries, as electrochromic material and as active component to electrochemical sensor to glycerol. In all the cases the nanocomposite films presented better performances when compared to the neat Ni(OH)2 nanoparticles, showing energy and power of 43.7 W h kg−1 and 4.8 kW kg−1 (8.24 A g−1) respectively, electrochromic efficiency reaching 70 cm2 C−1 and limit of detection as low as 15.4 ± 1.2 μmol L−1. PMID:27654065

Electrochemical DNA hybridization sensors based on conducting polymers.

PubMed

Rahman, Md Mahbubur; Li, Xiao-Bo; Lopa, Nasrin Siraj; Ahn, Sang Jung; Lee, Jae-Joon

2015-02-05

Conducting polymers (CPs) are a group of polymeric materials that have attracted considerable attention because of their unique electronic, chemical, and biochemical properties. This is reflected in their use in a wide range of potential applications, including light-emitting diodes, anti-static coating, electrochromic materials, solar cells, chemical sensors, biosensors, and drug-release systems. Electrochemical DNA sensors based on CPs can be used in numerous areas related to human health. This review summarizes the recent progress made in the development and use of CP-based electrochemical DNA hybridization sensors. We discuss the distinct properties of CPs with respect to their use in the immobilization of probe DNA on electrode surfaces, and we describe the immobilization techniques used for developing DNA hybridization sensors together with the various transduction methods employed. In the concluding part of this review, we present some of the challenges faced in the use of CP-based DNA hybridization sensors, as well as a future perspective.

Effects of oxidation potential and retention time on electrochromic stability of poly (3-hexyl thiophene) films

NASA Astrophysics Data System (ADS)

Kim, Tae-Ho; Hyun Song, Seok; Kim, Hyo-Jae; Oh, Seong-Hyeon; Han, Song-Yi; Kim, Goung; Nah, Yoon-Chae

2018-06-01

Herein, we report the effects of applied voltage on the electrochromic (EC) stability of poly(3-hexylthiophene) (P3HT) films during EC reactions. The transmittance difference and cycling stability of these films were monitored to optimize the oxidation voltage, and their chemical compositions were analyzed by X-ray photoelectron spectroscopy after long-term electrochemical cycling. High oxidation voltages increased the color contrast of P3HT films but decreased their cycling stability due to facilitating chemical degradation. Furthermore, at an optimized oxidation voltage, the retention time during potential pulsing was adjusted utilizing the optical memory of P3HT, revealing that the decreased voltage application time reduced power consumption by 9.6% and enhanced EC stability without loss of color contrast.

Integrated electrochromic aperture diaphragm

NASA Astrophysics Data System (ADS)

Deutschmann, T.; Oesterschulze, E.

2014-05-01

In the last years, the triumphal march of handheld electronics with integrated cameras has opened amazing fields for small high performing optical systems. For this purpose miniaturized iris apertures are of practical importance because they are essential to control both the dynamic range of the imaging system and the depth of focus. Therefore, we invented a micro optical iris based on an electrochromic (EC) material. This material changes its absorption in response to an applied voltage. A coaxial arrangement of annular rings of the EC material is used to establish an iris aperture without need of any mechanical moving parts. The advantages of this device do not only arise from the space-saving design with a thickness of the device layer of 50μm. But it also benefits from low power consumption. In fact, its transmission state is stable in an open circuit, phrased memory effect. Only changes of the absorption require a voltage of up to 2 V. In contrast to mechanical iris apertures the absorption may be controlled on an analog scale offering the opportunity for apodization. These properties make our device the ideal candidate for battery powered and space-saving systems. We present optical measurements concerning control of the transmitted intensity and depth of focus, and studies dealing with switching times, light scattering, and stability. While the EC polymer used in this study still has limitations concerning color and contrast, the presented device features all functions of an iris aperture. In contrast to conventional devices it offers some special features. Owing to the variable chemistry of the EC material, its spectral response may be adjusted to certain applications like color filtering in different spectral regimes (UV, optical range, infrared). Furthermore, all segments may be switched individually to establish functions like spatial Fourier filtering or lateral tunable intensity filters.

Durable electrooptic devices comprising ionic liquids

DOEpatents

Burrell, Anthony K [Los Alamos, NM; Agrawal, Anoop [Tucson, AZ; Cronin,; John, P [Tucson, AZ; Tonazzi, Juan C. L. [Tucson, AZ; Warner, Benjamin P [Los Alamos, NM; McCleskey, T Mark [Los Alamos, NM

2009-12-15

Electrolyte solutions for electrochromic devices such as rear view mirrors and displays with low leakage currents are prepared using inexpensive, low conductivity conductors. Preferred electrolytes include bifunctional redox dyes and molten salt solvents with enhanced stability toward ultraviolet radiation. The solvents include lithium or quaternary ammonium cations, and perfluorinated sulfonylimide anions selected from trifluoromethylsulfonate (CF.sub.3SO.sub.3.sup.-), bis(trifluoromethylsulfonyl)imide ((CF.sub.3SO.sub.2).sub.2N.sup.-), bis(perfluoroethylsulfonyl)imide ((CF.sub.3CF.sub.2SO.sub.2).sub.2N.sup.-) and tris(trifluoromethylsulfonyl)methide ((CF.sub.3SO.sub.2).sub.3C.sup.-). Electroluminescent, electrochromic and photoelectrochromic devices with nanostructured electrodes include ionic liquids with bifunctional redox dyes. Some of the electrolyte solutions color to red when devices employing the solutions are powered, leading to red or neutral electrooptic devices.

Multi-layer electrode for high contrast electrochromic devices

DOEpatents

Schwendeman, Irina G [Wexford, PA; Finley, James J [Pittsburgh, PA; Polcyn, Adam D [Pittsburgh, PA; Boykin, Cheri M [Wexford, PA

2011-11-01

An electrochromic device includes a first substrate spaced from a second substrate. A first transparent conductive electrode is formed over at least a portion of the first substrate. A polymeric anode is formed over at least a portion of the first conductive electrode. A second transparent conductive electrode is formed over at least a portion of the second substrate. In one aspect of the invention, a multi-layer polymeric cathode is formed over at least a portion of the second conductive electrode. In one non-limiting embodiment, the multi-layer cathode includes a first cathodically coloring polymer formed over at least a portion of the second conductive electrode and a second cathodically coloring polymer formed over at least a portion of the first cathodically coloring polymer. An ionic liquid is positioned between the anode and the cathode.

IN2 Profile: Polyceed Electrochromic Window Technology Expected to Lower Energy Costs

DOE Office of Scientific and Technical Information (OSTI.GOV)

Tenent, Rob; Achour, Maha

Through the Wells Fargo Innovation Incubator (IN²) program, Polyceed will validate their electrochromic window technology. The technology is expected to provide customers with 75% lower cost than conventional dynamic windows and offer small residences $200 a year of cost savings for energy consumption. The IN² program launched in October 2014 and is part of Wells Fargo’s 2020 Environmental Commitment to provide $100 million to environmentally-focused nonprofits and universities. The goal is to create an ecosystem that fosters and accelerates the commercialization of promising commercial buildings technologies that can provide scalable solutions to reduce the energy impact of buildings. According tomore » the Department of Energy, nearly 40 percent of energy consumption in the U.S. today comes from buildings at an estimated cost of $413 billion.« less

Durable Electrooptic Devices Comprising Ionic Liquids

DOEpatents

Burrell, Anthony K.; Agrawal, Anoop; Cronin, John P.; Tonazzi, Juan C. L.; Warner, Benjamin P.; McCleskey, T. Mark

2008-11-11

Electrolyte solutions for electrochromic devices such as rear view mirrors and displays with low leakage currents are prepared using inexpensive, low conductivity conductors. Preferred electrolytes include bifunctional redox dyes and molten salt solvents with enhanced stability toward ultraviolet radiation. The solvents include lithium or quaternary ammonium cations, and perfluorinated sulfonylimide anions selected from trifluoromethylsulfonate (CF.sub.3SO.sub.3.sup.-), bis(trifluoromethylsulfonyl)imide ((CF.sub.3SO.sub.2).sub.2N.sup.-), bis(perfluoroethylsulfonyl)imide ((CF.sub.3CF.sub.2SO.sub.2).sub.2N.sup.-) and tris(trifluoromethylsulfonyl)methide ((CF.sub.3SO.sub.2).sub.3C.sup.-). Electroluminescent, electrochromic and photoelectrochromic devices with nanostructured electrodes include ionic liquids with bifunctional redox dyes. Some of the electrolyte solutions color to red when devices employing the solutions are powered, leading to red or neutral electrooptic devices.

Self-powered fluorescence display devices based on a fast self-charging/recharging battery (Mg/Prussian blue).

PubMed

Zhang, Hui; Yu, You; Zhang, Lingling; Zhai, Yiwen; Dong, Shaojun

2016-11-01

Stimuli-responsive (such as voltage and/or light) fluorescence display systems have attracted particular attention in their promising fields of application. However, there are few examples of self-powered fluorescence display devices. Here we designed and fabricated a self-powered fluorescence display device based on a fast-charging/recharging battery. The specially designed battery was composed of a Prussian blue (PB) cathode and a magnesium metal anode with a high theoretical redox potential difference (∼2.8 V). Moreover, smartly adding a trace amount of NaClO in the electrolyte could realize oxidizing PW to PB ∼480 times faster than when oxidizing without NaClO, leading to the fast self-charging and high power density (maximum power density of 13.34 mW cm -2 , about two to three orders of magnitude larger than previous bio-fuel cells) of the Mg/PB battery. Most importantly, PB was used as not only the cathodic catalyst but also as an electrochromic material, making it possible to construct a self-powered and rechargeable electrochromic fluorescence display with only two electrodes. Besides, fluorescent [Ru(bpy) 3 ] 2+ -doped silica nanoparticles (Ru@SiO 2 ), were selected as the fluorescence resonance energy transfer (FRET) donor to match PB (FRET acceptor). To the best of our knowledge, we demonstrated a self-powered and rechargeable electrochromic fluorescence display with only two electrodes for the first time.

High ionic conductivity P(VDF-TrFE)/PEO blended polymer electrolytes for solid electrochromic devices.

PubMed

Nguyen, Chien A; Xiong, Shanxin; Ma, Jan; Lu, Xuehong; Lee, Pooi See

2011-08-07

Solid polymer electrolytes with excellent ionic conductivity (above 10(-4) S cm(-1)), which result in high optical modulation for solid electrochromic (EC) devices are presented. The combination of a polar host matrix poly(vinylidene fluoride-trifluoroethylene) P(VDF-TrFE) and a solid plasticized of a low molecular weight poly(ethylene oxide) (PEO) (M(w)≤ 20,000) blended polymer electrolyte serves to enhance both the dissolution of lithium salt and the ionic transport. Calorimetric measurement shows a reduced crystallization due to a better intermixing of the polymers with small molecular weight PEO. Vibrational spectroscopy identifies the presence of free ions and ion pairs in the electrolytes with PEO of M(w)≤ 8000. The ionic dissolution is improved using PEO as a plasticizer when compared to liquid propylene carbonate, evidently shown in the transference number analysis. Ionic transport follows the Arrhenius equation with a low activation energy (0.16-0.2 eV), leading to high ionic conductivities. Solid electrochromic devices fabricated with the blended P(VDF-TrFE)/PEO electrolytes and polyaniline show good spectroelectrochemical performance in the visible (300-800 nm) and near-infrared (0.9-2.4 μm) regions with a modulation up to 60% and fast switching speed of below 20 seconds. The successful introduction of the solid polymer electrolytes with its best harnessed qualities helps to expedite the application of various electrochemical devices. This journal is © the Owner Societies 2011

A chameleon-inspired stretchable electronic skin with interactive colour changing controlled by tactile sensing

PubMed Central

Chou, Ho-Hsiu; Nguyen, Amanda; Chortos, Alex; To, John W.F.; Lu, Chien; Mei, Jianguo; Kurosawa, Tadanori; Bae, Won-Gyu; Tok, Jeffrey B.-H.; Bao, Zhenan

2015-01-01

Some animals, such as the chameleon and cephalopod, have the remarkable capability to change their skin colour. This unique characteristic has long inspired scientists to develop materials and devices to mimic such a function. However, it requires the complex integration of stretchability, colour-changing and tactile sensing. Here we show an all-solution processed chameleon-inspired stretchable electronic skin (e-skin), in which the e-skin colour can easily be controlled through varying the applied pressure along with the applied pressure duration. As such, the e-skin's colour change can also be in turn utilized to distinguish the pressure applied. The integration of the stretchable, highly tunable resistive pressure sensor and the fully stretchable organic electrochromic device enables the demonstration of a stretchable electrochromically active e-skin with tactile-sensing control. This system will have wide range applications such as interactive wearable devices, artificial prosthetics and smart robots. PMID:26300307

Very low band gap thiadiazoloquinoxaline donor-acceptor polymers as multi-tool conjugated polymers.

PubMed

Steckler, Timothy T; Henriksson, Patrik; Mollinger, Sonya; Lundin, Angelica; Salleo, Alberto; Andersson, Mats R

2014-01-29

Here we report on the synthesis of two novel very low band gap (VLG) donor-acceptor polymers (Eg ≤ 1 eV) and an oligomer based on the thiadiazoloquinoxaline acceptor. Both polymers demonstrate decent ambipolar mobilities, with P1 showing the best performance of ∼10(-2) cm(2) V(-1) s(-1) for p- and n-type operation. These polymers are among the lowest band gap polymers (≲0.7 eV) reported, with a neutral λmax = 1476 nm (P2), which is the farthest red-shifted λmax reported to date for a soluble processable polymer. Very little has been done to characterize the electrochromic aspects of VLG polymers; interestingly, these polymers actually show a bleaching of their neutral absorptions in the near-infrared region and have an electrochromic contrast up to 30% at a switching speed of 3 s.

A chameleon-inspired stretchable electronic skin with interactive colour changing controlled by tactile sensing.

PubMed

Chou, Ho-Hsiu; Nguyen, Amanda; Chortos, Alex; To, John W F; Lu, Chien; Mei, Jianguo; Kurosawa, Tadanori; Bae, Won-Gyu; Tok, Jeffrey B-H; Bao, Zhenan

2015-08-24

Some animals, such as the chameleon and cephalopod, have the remarkable capability to change their skin colour. This unique characteristic has long inspired scientists to develop materials and devices to mimic such a function. However, it requires the complex integration of stretchability, colour-changing and tactile sensing. Here we show an all-solution processed chameleon-inspired stretchable electronic skin (e-skin), in which the e-skin colour can easily be controlled through varying the applied pressure along with the applied pressure duration. As such, the e-skin's colour change can also be in turn utilized to distinguish the pressure applied. The integration of the stretchable, highly tunable resistive pressure sensor and the fully stretchable organic electrochromic device enables the demonstration of a stretchable electrochromically active e-skin with tactile-sensing control. This system will have wide range applications such as interactive wearable devices, artificial prosthetics and smart robots.

Smart responsive phosphorescent materials for data recording and security protection.

PubMed

Sun, Huibin; Liu, Shujuan; Lin, Wenpeng; Zhang, Kenneth Yin; Lv, Wen; Huang, Xiao; Huo, Fengwei; Yang, Huiran; Jenkins, Gareth; Zhao, Qiang; Huang, Wei

2014-04-07

Smart luminescent materials that are responsive to external stimuli have received considerable interest. Here we report ionic iridium (III) complexes simultaneously exhibiting mechanochromic, vapochromic and electrochromic phosphorescence. These complexes share the same phosphorescent iridium (III) cation with a N-H moiety in the N^N ligand and contain different anions, including hexafluorophosphate, tetrafluoroborate, iodide, bromide and chloride. The anionic counterions cause a variation in the emission colours of the complexes from yellow to green by forming hydrogen bonds with the N-H proton. The electronic effect of the N-H moiety is sensitive towards mechanical grinding, solvent vapour and electric field, resulting in mechanochromic, vapochromic and electrochromic phosphorescence. On the basis of these findings, we construct a data-recording device and demonstrate data encryption and decryption via fluorescence lifetime imaging and time-gated luminescence imaging techniques. Our results suggest that rationally designed phosphorescent complexes may be promising candidates for advanced data recording and security protection.

A polymer/semiconductor write-once read-many-times memory

NASA Astrophysics Data System (ADS)

Möller, Sven; Perlov, Craig; Jackson, Warren; Taussig, Carl; Forrest, Stephen R.

2003-11-01

Organic devices promise to revolutionize the extent of, and access to, electronics by providing extremely inexpensive, lightweight and capable ubiquitous components that are printed onto plastic, glass or metal foils. One key component of an electronic circuit that has thus far received surprisingly little attention is an organic electronic memory. Here we report an architecture for a write-once read-many-times (WORM) memory, based on the hybrid integration of an electrochromic polymer with a thin-film silicon diode deposited onto a flexible metal foil substrate. WORM memories are desirable for ultralow-cost permanent storage of digital images, eliminating the need for slow, bulky and expensive mechanical drives used in conventional magnetic and optical memories. Our results indicate that the hybrid organic/inorganic memory device is a reliable means for achieving rapid, large-scale archival data storage. The WORM memory pixel exploits a mechanism of current-controlled, thermally activated un-doping of a two-component electrochromic conducting polymer.

Composite WO 3/TiO 2 nanostructures for high electrochromic activity

DOE PAGES

Reyes-Gil, Karla R.; Stephens, Zachary D.; Stavila, Vitalie; ...

2015-01-06

A composite material consisting of TiO 2 nanotubes (NT) with WO 3 electrodeposited on its surface has been fabricated, detached from its Ti substrate, and attached to a fluorine-doped tin oxide (FTO) film on glass for application to electrochromic (EC) reactions. Several adhesion layers were tested, finding that a paste of TiO 2 made from commercially available TiO 2 nanoparticles creates an interface for the TiO 2 NT film to attach to the FTO glass, which is conductive and does not cause solution-phase ions in an electrolyte to bind irreversibly with the material. The effect of NT length and WOmore » 3 concentration on the EC performance were studied. As a result, the composite WO 3/TiO 2 nanostructures showed higher ion storage capacity, better stability, enhanced EC contrast, and longer memory time compared with the pure WO 3 and TiO 2 materials« less

Electroactive semi-interpenetrating polymer networks architecture with tunable IR reflectivity

NASA Astrophysics Data System (ADS)

Chevrot, C.; Teyssié, D.; Verge, P.; Goujon, L.; Tran-Van, F.; Vidal, F.; Aubert, P. H.; Peralta, S.; Sauques, L.

2011-04-01

A promising alternative of multi-layered devices showing electrochromic properties results from the design of a self-supported semi-interpenetrating polymer network (semi-IPN) including an electronic conductive polymer (ECP) formed within. The formation of the ECP in the network has already been described by oxidative polymerization using iron trichloride as an oxidant and leading to conducting semi-IPN with mixed electronic and ionic conductivities as well as convenient mechanical properties. This presentation relates to the elaboration of such semi-IPN using polyethyleneoxide (PEO) network or a PEO/NBR (Nitrile Butadiene Rubber) IPN in which a linear poly (3,4-ethylenedioxythiophene) (PEDOT) is formed symmetrically and selectively as very thin layers very next to the two main faces of the film matrix. PEO/PEDOT semi-IPNs lead to interesting optical reflective properties in the IR between 0.8 and 25 μm. Reflectance contrasts up to 35 % is observed when, after swelling in an ionic liquid, a low voltage is applied between the two main faces of the film. However the low flexibility and brittleness of the film and a slow degradation in air at temperature up from 60°C prompted to replace the PEO matrix by a flexible PEO/NBR IPN one. Indeed, the combination of NBR and PEO in an IPN leads to materials possessing flexible properties, good ionic conductivity at 25°C as well as a better resistance to thermal ageing. Finally, NBR/PEO/PEDOT semi-IPNs allow observing comparable reflectance contrast in the IR range than those shown by PEO/PEDOT semi-IPNs.

Electrochemical DNA Hybridization Sensors Based on Conducting Polymers

PubMed Central

Rahman, Md. Mahbubur; Li, Xiao-Bo; Lopa, Nasrin Siraj; Ahn, Sang Jung; Lee, Jae-Joon

2015-01-01

Conducting polymers (CPs) are a group of polymeric materials that have attracted considerable attention because of their unique electronic, chemical, and biochemical properties. This is reflected in their use in a wide range of potential applications, including light-emitting diodes, anti-static coating, electrochromic materials, solar cells, chemical sensors, biosensors, and drug-release systems. Electrochemical DNA sensors based on CPs can be used in numerous areas related to human health. This review summarizes the recent progress made in the development and use of CP-based electrochemical DNA hybridization sensors. We discuss the distinct properties of CPs with respect to their use in the immobilization of probe DNA on electrode surfaces, and we describe the immobilization techniques used for developing DNA hybridization sensors together with the various transduction methods employed. In the concluding part of this review, we present some of the challenges faced in the use of CP-based DNA hybridization sensors, as well as a future perspective. PMID:25664436

Thin film ion conducting coating

DOEpatents

Goldner, Ronald B.; Haas, Terry; Wong, Kwok-Keung; Seward, George

1989-01-01

Durable thin film ion conducting coatings are formed on a transparent glass substrate by the controlled deposition of the mixed oxides of lithium:tantalum or lithium:niobium. The coatings provide durable ion transport sources for thin film solid state storage batteries and electrochromic energy conservation devices.

Electrochromic Adaptive Infrared Camouflage

DTIC Science & Technology

2005-12-01

H.M. van Driel, Nature 405 (2000) 437. [14] M. Holgado , F. Garcia-Santamaria, A.Blanco, M. Ibisate, A. Cintas, H. Miguez, C.J...Quantum Electronics 34: 27-36, 2002. [20] A. Reynolds, F. Lopez-Tejeira, D. Cassagne, F.J. Garcia-Vidal, C. Jouanin, J. Sanchez

Effect of Post-annealing on the Electrochromic Properties of Layer-by-Layer Arrangement FTO-WO3-Ag-WO3-Ag

NASA Astrophysics Data System (ADS)

Hoseinzadeh, S.; Ghasemiasl, R.; Bahari, A.; Ramezani, A. H.

2018-03-01

In the current study, composites of tungsten trioxide (W03) and silver (Ag) are deposited in a layer-by-layer electrochromic (EC) arrangement onto a fluorine-doped tin oxide coated glass substrate. Tungsten oxide nanoparticles are an n-type semiconductor that can be used as EC cathode material. Nano-sized silver is a metal that can serve as an electron trap center that facilitates charge departure. In this method, the WO3 and Ag nanoparticle powder were deposited by physical vapor deposition onto the glass substrate. The fabricated electrochromic devices (ECD) were post-annealed to examine the effect of temperature on their EC properties. The morphology of the thin film was characterized by scanning electron microscopy and atomic force microscopy. Structural analysis showed that the addition of silver dopant increased the size of the aggregation of the film. The film had an average approximate roughness of about 17.8 nm. The electro-optical properties of the thin film were investigated using cyclic voltammetry and UV-visible spectroscopy to compare the effects of different post-annealing temperatures. The ECD showed that annealing at 200°C provided better conductivity (maximum current of about 90 mA in the oxidation state) and change of transmittance (ΔT = 90% at the continuous switching step) than did the other thin films. The optical band gaps of the thin film showed that it allowed direct transition at 3.85 eV. The EC properties of these combinations of coloration efficiency and response time indicate that the WO3-Ag-WO3-Ag arrangement is a promising candidate for use in such ECDs.

Solid lithium-ion electrolyte

DOEpatents

Zhang, Ji-Guang; Benson, David K.; Tracy, C. Edwin

1998-01-01

The present invention relates to the composition of a solid lithium-ion electrolyte based on the Li.sub.2 O--CeO.sub.2 --SiO.sub.2 system having good transparent characteristics and high ion conductivity suitable for uses in lithium batteries, electrochromic devices and other electrochemical applications.

Aerosol-jet-printed, 1 volt H-bridge drive circuit on plastic with integrated electrochromic pixel.

PubMed

Ha, Mingjing; Zhang, Wei; Braga, Daniele; Renn, Michael J; Kim, Chris H; Frisbie, C Daniel

2013-12-26

In this report, we demonstrate a printed, flexible, and low-voltage circuit that successfully drives a polymer electrochromic (EC) pixel as large as 4 mm(2) that is printed on the same substrate. All of the key components of the drive circuitry, namely, resistors, capacitors, and transistors, were aerosol-jet-printed onto a plastic foil; metallic electrodes and interconnects were the only components prepatterned on the plastic by conventional photolithography. The large milliampere drive currents necessary to switch a 4 mm(2) EC pixel were controlled by printed electrolyte-gated transistors (EGTs) that incorporate printable ion gels for the gate insulator layers and poly(3-hexylthiophene) for the semiconductor channels. Upon application of a 1 V input pulse, the circuit switches the printed EC pixel ON (red) and OFF (blue) two times in approximately 4 s. The performance of the circuit and the behavior of the individual resistors, capacitors, EGTs, and the EC pixel are analyzed as functions of the printing parameters and operating conditions.

Composite WO3/TiO2 nanostructures for high electrochromic activity.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Reyes, Karla Rosa; Stephens, Zachary Dan.; Robinson, David B.

2013-05-01

A composite material consisting of TiO2 nanotubes (NTs) with WO3 electrodeposited homogeneously on its surface has been fabricated, detached from its substrate, and attached to a fluorine-doped tin oxide film on glass for application to electrochromic (EC) reactions. A paste of TiO2 made from commercially available TiO2 nanoparticles creates an interface for the TiO2 NT film to attach to the FTO glass, which is conductive and does not cause solution-phase ions in an electrolyte to bind irreversibly with the material. The effect of NT length on the current density and the EC contrast of the material were studied. The ECmore » redox reaction seen in this material is diffusion- limited, having relatively fast reaction rates at the electrode surface. The composite WO3/TiO2 nanostructures showed higher ion storage capacity, better stability, enhanced EC contrast and longer memory time compared with the pure WO3 and TiO2.« less

Ion-Transport Design for High-Performance Na+-Based Electrochromics.

PubMed

Li, Ran; Li, Kerui; Wang, Gang; Li, Lei; Zhang, Qiangqiang; Yan, Jinhui; Chen, Yao; Zhang, Qinghong; Hou, Chengyi; Li, Yaogang; Wang, Hongzhi

2018-04-24

Sodium ion (Na + )-based electrochemical systems have been extensively investigated in batteries and supercapacitors and also can be quality candidates for electrochromic (EC) devices. However, poor diffusion kinetics and severe EC performance degradation occur during the intercalation/deintercalation processes because the ionic radii of Na + are larger than those of conventional intercalation ions. Here, through intentional design of ion-transport channels in metal-organic frameworks (MOFs), Na + serves as an efficient intercalation ion for incorporation into a nanostructured electrode with a high diffusion coefficient of approximately 10 -8 cm 2 s -1 . As a result, the well-designed MOF-based EC device demonstrates desirable Na + EC performance, including fast switching speed, multicolor switching, and high stability. A smart "quick response code" display is fabricated using a mask-free laser writing method for application in the "Internet of Things". In addition, the concept of ion transport pathway design can be widely adopted for fabricating high-performance ion intercalation materials and devices for consumer electronics.

BIPV-powered smart windows utilizing photovoltaic and electrochromic devices.

PubMed

Ma, Rong-Hua; Chen, Yu-Chia

2012-01-01

A BIPV-powered smart window comprising a building-integrated photovoltaic (BIPV) panel and an all-solid-state electrochromic (EC) stack is proposed. In the proposed device, the output voltage of the BIPV panel varies in accordance with the intensity of the incident light and is modulated in such a way as to generate the EC stack voltage required to maintain the indoor illuminance within a specified range. Two different EC stacks are fabricated and characterized, namely one stack comprising ITO/WO(3)/Ta(2)O(5)/ITO and one stack comprising ITO/WO(3)/lithium-polymer electrolyte/ITO. It is shown that of the two stacks, the ITO/WO(3)/lithium-polymer electrolyte/ITO stack has a larger absorptance (i.e., approximately 99% at a driving voltage of 3.5 V). The experimental results show that the smart window incorporating an ITO/WO(3)/lithium-polymer electrolyte/ITO stack with an electrolyte thickness of 1.0 μm provides an indoor illuminance range of 750-1,500 Lux under typical summertime conditions in Taiwan.

Properties of WO3-x Electrochromic Thin Film Prepared by Reactive Sputtering with Various Post Annealing Temperatures

NASA Astrophysics Data System (ADS)

Kim, Min Hong; Choi, Hyung Wook; Kim, Kyung Hwan

2013-11-01

The WO3-x thin films were prepared on indium tin oxide (ITO) coated glass at 0.7 oxygen flow ratio [O2/(Ar+O2)] using the facing targets sputtering (FTS) system at room temperature. In order to obtain the annealing effect, as-deposited thin films were annealed at temperatures of 100, 200, 300, 400, and 500 °C for 1 h in open air. The structural properties of the WO3-x thin film were measured using an X-ray diffractometer. The WO3-x thin films annealed at up to 300 °C indicated amorphous properties, while those annealed above 400 °C indicated crystalline properties. The electrochemical and optical properties of WO3-x thin films were measured using cyclic voltammetry and a UV/vis spectrometer. The maximum value of coloration efficiency obtained was 34.09 cm2/C for thin film annealed at 200 °C. The WO3-x thin film annealed at 200 °C showed superior electrochromic properties.

Pairing of near-ultraviolet solar cells with electrochromic windows for smart management of the solar spectrum

NASA Astrophysics Data System (ADS)

Davy, Nicholas C.; Sezen-Edmonds, Melda; Gao, Jia; Lin, Xin; Liu, Amy; Yao, Nan; Kahn, Antoine; Loo, Yueh-Lin

2017-08-01

Current smart window technologies offer dynamic control of the optical transmission of the visible and near-infrared portions of the solar spectrum to reduce lighting, heating and cooling needs in buildings and to improve occupant comfort. Solar cells harvesting near-ultraviolet photons could satisfy the unmet need of powering such smart windows over the same spatial footprint without competing for visible or infrared photons, and without the same aesthetic and design constraints. Here, we report organic single-junction solar cells that selectively harvest near-ultraviolet photons, produce open-circuit voltages eclipsing 1.6 V and exhibit scalability in power generation, with active layers (10 cm2) substantially larger than those typical of demonstration organic solar cells (0.04-0.2 cm2). Integration of these solar cells with a low-cost, polymer-based electrochromic window enables intelligent management of the solar spectrum, with near-ultraviolet photons powering the regulation of visible and near-infrared photons for natural lighting and heating purposes.

Roll-to-Roll Production of Transparent Silver-Nanofiber-Network Electrodes for Flexible Electrochromic Smart Windows.

PubMed

Lin, Sen; Bai, Xiaopeng; Wang, Haiyang; Wang, Haolun; Song, Jianan; Huang, Kai; Wang, Chang; Wang, Ning; Li, Bo; Lei, Ming; Wu, Hui

2017-11-01

Electrochromic smart windows (ECSWs) are considered as the most promising alternative to traditional dimming devices. However, the electrode technology in ECSWs remains stagnant, wherein inflexible indium tin oxide and fluorine-doped tin oxide are the main materials being used. Although various complicated production methods, such as high-temperature calcination and sputtering, have been reported, the mass production of flexible and transparent electrodes remains challenging. Here, a nonheated roll-to-roll process is developed for the continuous production of flexible, extralarge, and transparent silver nanofiber (AgNF) network electrodes. The optical and mechanical properties, as well as the electrical conductivity of these products (i.e., 12 Ω sq -1 at 95% transmittance) are comparable with those AgNF networks produced via high-temperature sintering. Moreover, the as-prepared AgNF network is successfully assembled into an A4-sized ECSW with short switching time, good coloration efficiency, and flexibility. © 2017 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Transparent Wood Smart Windows: Polymer Electrochromic Devices Based on Poly(3,4-Ethylenedioxythiophene):Poly(Styrene Sulfonate) Electrodes.

PubMed

Lang, Augustus W; Li, Yuanyuan; De Keersmaecker, Michel; Shen, D Eric; Österholm, Anna M; Berglund, Lars; Reynolds, John R

2018-03-09

Transparent wood composites, with their high strength and toughness, thermal insulation, and excellent transmissivity, offer a route to replace glass for diffusely transmitting windows. Here, conjugated-polymer-based electrochromic devices (ECDs) that switch on-demand are demonstrated using transparent wood coated with poly(3,4-ethylenedioxythiophene):poly(styrene sulfonate) (PEDOT:PSS) as a transparent conducting electrode. These ECDs exhibit a vibrant magenta-to-clear color change that results from a remarkably colorless bleached state. Furthermore, they require low energy and power inputs of 3 mWh m -2 at 2 W m -2 to switch due to a high coloration efficiency (590 cm 2  C -1 ) and low driving voltage (0.8 V). Each device component is processed with high-throughput methods, which highlights the opportunity to apply this approach to fabricate mechanically robust, energy-efficient smart windows on a large scale. © 2018 The Authors. Published by Wiley-VCH Verlag GmbH & Co. KGaA.

Parametric Study of Variable Emissivity Radiator Surfaces

NASA Technical Reports Server (NTRS)

Grob, Lisa M.; Swanson, Theodore D.

2000-01-01

The goal of spacecraft thermal design is to accommodate a high function satellite in a low weight and real estate package. The extreme environments that the satellite is exposed during its orbit are handled using passive and active control techniques. Heritage passive heat rejection designs are sized for the hot conditions and augmented for the cold end with heaters. The active heat rejection designs to date are heavy, expensive and/or complex. Incorporating an active radiator into the design that is lighter, cheaper and more simplistic will allow designers to meet the previously stated goal of thermal spacecraft design Varying the radiator's surface properties without changing the radiating area (as with VCHP), or changing the radiators' views (traditional louvers) is the objective of the variable emissivity (vary-e) radiator technologies. A parametric evaluation of the thermal performance of three such technologies is documented in this paper. Comparisons of the Micro-Electromechanical Systems (MEMS), Electrochromics, and Electrophoretics radiators to conventional radiators, both passive and active are quantified herein. With some noted limitations, the vary-e radiator surfaces provide significant advantages over traditional radiators and a promising alternative design technique for future spacecraft thermal systems.

Solid lithium-ion electrolyte

DOEpatents

Zhang, J.G.; Benson, D.K.; Tracy, C.E.

1998-02-10

The present invention relates to the composition of a solid lithium-ion electrolyte based on the Li{sub 2}O--CeO{sub 2}--SiO{sub 2} system having good transparent characteristics and high ion conductivity suitable for uses in lithium batteries, electrochromic devices and other electrochemical applications. 12 figs.

Thin film method of conducting lithium-ions

DOEpatents

Zhang, J.G.; Benson, D.K.; Tracy, C.E.

1998-11-10

The present invention relates to the composition of a solid lithium-ion electrolyte based on the Li{sub 2}O-CeO{sub 2}-SiO{sub 2} system having good transparent characteristics and high ion conductivity suitable for uses in lithium batteries, electrochromic devices and other electrochemical applications. 12 figs.

Preparation of Conducting Polymers by Electrochemical Methods and Demonstration of a Polymer Battery

ERIC Educational Resources Information Center

Goto, Hiromasa; Yoneyama, Hiroyuki; Togashi, Fumihiro; Ohta, Reina; Tsujimoto, Akitsu; Kita, Eiji; Ohshima, Ken-ichi

2008-01-01

The electrochemical polymerization of aniline and pyrrole, and demonstrations of electrochromism and the polymer battery effect, are presented as demonstrations suitable for high school and introductory chemistry at the university level. These demonstrations promote student interest in the electrochemical preparation of conducting polymers, where…

Thermo- and electro-dual responsive poly(ionic liquid) electrolyte based smart windows.

PubMed

Chen, Fei; Ren, Yongyuan; Guo, Jiangna; Yan, Feng

2017-01-31

Thermo- and electro-dual responsive poly(ionic liquid) (PIL) based electrolytes were synthesized by co-polymerization of N-isopropylacrylamide (NIPAM) with (or without) 3-butyl-1-vinyl-imidazolium bromide ([BVIm][Br]) using diallyl-viologen (DAV) as both the cross-linking agent and electrochromic material.

Thin film method of conducting lithium-ions

DOEpatents

Zhang, Ji-Guang; Benson, David K.; Tracy, C. Edwin

1998-11-10

The present invention relates to the composition of a solid lithium-ion electrolyte based on the Li.sub.2 O--CeO.sub.2 --SiO.sub.2 system having good transparent characteristics and high ion conductivity suitable for uses in lithium batteries, electrochromic devices and other electrochemical applications.

In Situ Techniques for Monitoring Electrochromism: An Advanced Laboratory Experiment

ERIC Educational Resources Information Center

Saricayir, Hakan; Uce, Musa; Koca, Atif

2010-01-01

This experiment employs current technology to enhance and extend existing lab content. The basic principles of spectroscopic and electroanalytical techniques and their use in determining material properties are covered in some detail in many undergraduate chemistry programs. However, there are limited examples of laboratory experiments with in…

Functional organic materials for electronics industries

NASA Technical Reports Server (NTRS)

Shibayama, K.; Ono, H.

1982-01-01

Topics closely related with organic, high molecular weight material synthesis are discussed. These are related to applications such as display, recording, sensors, semiconductors, and I.C. correlation. New materials are also discussed. General principles of individual application are not included. Materials discussed include color, electrochromic, thermal recording, organic photoconductors for electrophotography, and photochromic materials.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Mattox, Tracy M.; Koo, Bonil; Garcia, Guillermo

An electrochromic device includes a nanostructured transition metal oxide bronze layer that includes one or more transition metal oxide and one or more dopant, a solid state electrolyte, and a counter electrode. The nanostructured transition metal oxide bronze selectively modulates transmittance of near-infrared (NIR) spectrum and visible spectrum radiation as a function of an applied voltage to the device.

Electrochromic materials, devices and process of making

DOEpatents

Richardson, Thomas J.

2003-11-11

Thin films of transition metal compositions formed with magnesium that are metals, alloys, hydrides or mixtures of alloys, metals and/or hydrides exhibit reversible color changes on application of electric current or hydrogen. Thin films of these materials are suitable for optical switching elements, thin film displays, sun roofs, rear-view mirrors and architectural glass.

Energy Efficient Window Coatings that Please the Eye - Continuum Magazine

Science.gov Websites

voltage polarity reverses the lithium-ion flow, decreasing the glass tint and allowing more light to be transparent contact layers bookending a counterelectrode layer, ion-conducting layer, and electrochromic layer . Low voltage applied across the stacked layers causes lithium ions to migrate out of the

Preparation of electrochromic thin films by transformation of manganese(II) carbonate

NASA Astrophysics Data System (ADS)

Stojkovikj, Sasho; Najdoski, Metodija; Koleva, Violeta; Demiri, Sani

2013-10-01

A new chemical bath method for deposition of manganese(II) carbonate thin film on electroconductive FTO glass substrates is designed. The homogeneous thin films with thickness in the range of 70 to 500 nm are deposited at about 98 °C from aqueous solution containing urea and MnCl2. The chemical process is based on a low temperature hydrolysis of the manganese complexes with urea. Three types of films are under consideration: as-deposited, annealed and electrochemically transformed thin films. The structure of the films is studied by XRD, IR and Raman spectroscopy. Electrochemical and optical properties are examined in eight different electrolytes (neutral and alkaline) and the best results are achieved in two component aqueous solution of 0.1 M KNO3 and 0.01 M KOH. It is established that the as-deposited MnCO3 film undergoes electrochemically transformation into birnessite-type manganese(IV) oxide films, which exhibit electrochromic color changes (from bright brown to pale yellow and vice versa) with 30% difference in the transmittance of the colored and bleached state at 400 nm.

Preparation, structure, and unique redox properties of mono-, bis-, and Tris(diarylmethylene)-1,3,5-trithianes and related compounds

PubMed

Suzuki; Yoshino; Nishida; Ohkita; Tsuji

2000-09-08

A series of 1,3,5-trithianes 1-3 having diarylmethylene units were designed as novel electron donors giving highly colored cationic species upon oxidation. They were prepared along with the dithiane and dithiazine derivatives 4-6 by the reactions of lithiated heterocycles with diaryl ketones followed by dehydration. Voltammetric analyses indicate that a large structural change and/or transannular bonding are induced during their electrochemical oxidation. Mono(diarylmethylene) derivative 1a exhibits electrochromism with vivid change in color from faintly yellow to deep blue with concomitant rotation around the exocyclic bond. Both of the strongly colored salts obtained upon oxidation of 2,4-bis- and 2,4,6-tris(diarylmethylene)-1,3,5-trithianes (2aa and 3) consist of the dications with a 1,2,4-trithiane ring, suggesting the easy skeletal rearrangement of the transannular dications with a trithiabicylo[3.1.0]hexane ring. Upon reduction of these salts were obtained bright yellow 12 and 13, respectively, with high electron-donating properties due to the tetraarylbutadiene-type conjugation, thus giving another class of electrochromic compounds.

Design and construction of hierarchical TiO2 nanorod arrays by combining layer-by-layer and hydrothermal crystallization techniques for electrochromic application

NASA Astrophysics Data System (ADS)

Chen, Yongbo; Li, Xiaomin; Bi, Zhijie; He, Xiaoli; Li, Guanjie; Xu, Xiaoke; Gao, Xiangdong

2018-05-01

The hierarchical TiO2 (H-TiO2) nanorod arrays (NRAs) composed of single-crystalline nanorods and nanocrystals were finely designed and successfully constructed for electrochromic (EC) application. By combining layer-by-layer (LBL) method and hydrothermal crystallization technique, the superfine nanocrystals (5-7 nm), which can provide abundant active sites and facilitate ion insertion/extraction during EC reactions, were uniformly and conformally assembled on the surface of single-crystalline TiO2 (SC-TiO2) NRAs. The as-formed H-TiO2 NRAs integrate the advantages of one-dimensional NRAs with fast kinetics and superfine nanocrystals with high ion capacity, showing highly enhanced EC performance. Large optical contrast (40.3%), shorter coloring/bleaching time (22/4 s), high coloration efficiency (11.2 cm2 C-1), and excellent cycling stability can be achieved in H-TiO2 NRAs, superior to the pristine SC-TiO2 NRAs and nanocrystalline TiO2 films. This work provides a feasible and well-designed strategy to explore high-performance materials for EC application.

Optimization of PEDOT films in ionic liquid supercapacitors: demonstration as a power source for polymer electrochromic devices.

PubMed

Österholm, Anna M; Shen, D Eric; Dyer, Aubrey L; Reynolds, John R

2013-12-26

We report on the optimization of the capacitive behavior of poly(3,4-ethylenedioxythiophene) (PEDOT) films as polymeric electrodes in flexible, Type I electrochemical supercapacitors (ESCs) utilizing ionic liquid (IL) and organic gel electrolytes. The device performance was assessed based on figures of merit that are critical to evaluating the practical utility of electroactive polymer ESCs. PEDOT/IL devices were found to be highly stable over hundreds of thousands of cycles and could be reversibly charged/discharged at scan rates between 500 mV/s and 2 V/s depending on the polymer loading. Furthermore, these devices exhibit leakage currents and self-discharge rates that are comparable to state of the art electrochemical double-layer ESCs. Using an IL as device electrolyte allowed an extension of the voltage window of Type I ESCs by 60%, resulting in a 2.5-fold increase in the energy density obtained. The efficacies of tjese PEDOT ESCs were assessed by using them as a power source for a high-contrast and fast-switching electrochromic device, demonstrating their applicability in small organic electronic-based devices.

Synthesis of solution-processable poly(3,4 propylenedioxythiophene) nanobelts for electrochromic device applications

NASA Astrophysics Data System (ADS)

Raghavan, Siju Cherikkattil; Shivaprakash, N. Channegowda; Sindhu, Sukumaran Nair

2017-11-01

A new derivative of di-4-isopropyl benzyl substituted propylenedioxythiophene (ProDOT-IPBz2) monomer was synthesized and its resultant polymer was prepared by chemical and electrochemical methods. The chemical polymerization was carried out in a hexane/water reverse microemulsion system using sodium bis(2-ethylhexyl) sulfosuccinate (AOT) as self-assembling template. Chemically synthesized PProDOT-IPBz2 was formed as thin nanobelts with high aspect ratio (3:100), and it was found to be soluble in common organic solvents. The electrochemical and electrochromic (EC) properties of PProDOT-IPBz2 films were studied and it was found that PProDOT-IPBz2 films showed high transparency at oxidized state (+1.0 V) and dark purple color formed at reduced state (-1.0 V). The color contrast of solution cast film was calculated to be 37% T at 550 nm, however electropolymerized PProDOT-IPBz2 film exhibited a color contrast of 48% at 550 nm with switching speed of ∼1 s, and the coloration efficiency was calculated to be 305 cm2C-1.

Flash-induced nanowelding of silver nanowire networks for transparent stretchable electrochromic devices.

PubMed

Lee, Chihak; Oh, Youngsu; Yoon, In Seon; Kim, Sun Hong; Ju, Byeong-Kwon; Hong, Jae-Min

2018-02-09

Electrochromic devices (ECDs) are emerging as a novel technology for various applications like commercialized smart window glasses, and auto-dimming rear-view mirrors. Recently, the development of low-power, lightweight, flexible, and stretchable devices has been accelerated to meet the growing demand in the new wearable devices market. Silver nanowires (AgNWs) can become new primary transparent conducting electrode (TCE) materials to replace indium tin oxide (ITO) for ECDs. However, issues such as substrate adhesion, delamination, and higher resistance still exist with AgNWs. Herein, we report a high-performance stretchable flash-induced AgNW-network-based TCE on surface-treated polydimethylsiloxane (PDMS) substrates. A Xe flash light method was used to create nanowelded networks of AgNWs. Surface silane treatments increased the adhesion and durability of the films as well. Finally, ECDs were fabricated under the optimal conditions and examined under strained conditions to demonstrate the resistance and mechanical behaviours of the devices. Results showed a flexible and durable film maintaining a high level of conductivity and reversible resistance behaviour, beyond those currently achievable with standard ITO/PET flexible TCEs.

BIPV-Powered Smart Windows Utilizing Photovoltaic and Electrochromic Devices

PubMed Central

Ma, Rong-Hua; Chen, Yu-Chia

2012-01-01

A BIPV-powered smart window comprising a building-integrated photovoltaic (BIPV) panel and an all-solid-state electrochromic (EC) stack is proposed. In the proposed device, the output voltage of the BIPV panel varies in accordance with the intensity of the incident light and is modulated in such a way as to generate the EC stack voltage required to maintain the indoor illuminance within a specified range. Two different EC stacks are fabricated and characterized, namely one stack comprising ITO/WO3/Ta2O5/ITO and one stack comprising ITO/WO3/lithium-polymer electrolyte/ITO. It is shown that of the two stacks, the ITO/WO3/lithium-polymer electrolyte/ITO stack has a larger absorptance (i.e., approximately 99% at a driving voltage of 3.5 V). The experimental results show that the smart window incorporating an ITO/WO3/lithium-polymer electrolyte/ITO stack with an electrolyte thickness of 1.0 μm provides an indoor illuminance range of 750–1,500 Lux under typical summertime conditions in Taiwan. PMID:22368474

Synthesis and optoelectronic properties of new polyarylates with 2-naphthyldiphenylamine units

NASA Astrophysics Data System (ADS)

Cai, Wanan; Wu, Xiaotong; Xiao, Tiandi; Niu, Haijun; Bai, Xuduo; Wang, Cheng; Wang, Wen; Zhang, Yanhong

2018-02-01

Herein, five kinds of soluble electrochromic polyarylates were synthesized from the reaction of N,N'-bis(4-carboxyphenyl)-N,N'-di-2-naphthyl-1,4-phenylenediamine with five bisphenols via direct polycondensation process, respectively. These new materials showed no significant decomposition below 400 °C in nitrogen atmosphere. The maximum UV-vis absorption bands of these polyarylates located at 328-348 nm and 327-353 nm for solid films and DMSO solution, respectively. The polyarylate 6a, as an example, exhibited not only aggregation-induced emission (AIE) effect in different fraction tetrahydrofuran/water solution, but also solvatochromism in various polar solvents, markedly. Two reversible pairs of distinct redox peaks were associated with noticeable color changed from original colorless to yellowish orange and green for polymeric film could be observed in the cyclic voltammetry (CV) test. New absorption peaks emerged in near-infrared (NIR) region with increasing voltage in the UV-vis spectra, which indicates these polyarylates can be used as NIR electrochromic materials. These polyarylates performed high contrast of optical transmittance change around 42-53% with the highest coloration efficiency up to 236 cm2C-1.

Towards electrochromic devices having visible color switching using electronic push-push and push-pull cinnamaldehyde derivatives.

PubMed

Navarathne, Daminda; Skene, W G

2013-12-11

A series of symmetric and unsymmetric conjugated azomethines derived from cinnamaldehyde and 2,5-diaminothiophene-3,4-dicarboxylic acid diethyl ester were prepared. The optical, electrochemical, and spectroelectrochemical properties of the electronic push-pull and push-push triads were investigated. Their properties could be tuned contingent on the cinnamaldehyde's electron withdrawing and donating substituents. The push-push symmetric derivative exhibited positive solvatochromism with the absorbance spanning some 31 nm, depending on the solvent polarity. Solvent dependent spectroelectrochemistry was also found for the symmetric push-push azomethine. The color of the neutral state and radical cation spanned 215 nm. The most pronounced color transition of the purple colored material was found in dimethyl sulfoxide (DMSO), where the color bleached with electrochemical oxidation. This was a result of the absorbance shifting into the near infrared (NIR) and not from decomposition of the azomethine. Electrochromic devices with the azomethines possessing desired reversible oxidation and color changes in the visible were fabricated and tested to demonstrate the applicability of these azomethine triads in devices.

A Resettable Keypad Lock with Visible Readout Based on Closed Bipolar Electrochemistry and Electrochromic Poly(3-methylthiophene) Films.

PubMed

Wang, Lei; Lian, Wenjing; Liu, Hongyun

2016-03-24

A closed bipolar electrode (BPE) system was developed with electrochromic poly(3-methylthiophene) (PMT) films electropolymerized on the ITO/rGO electrode as one pole of BPE in the reporting reservoir and the bare ITO electrode as another pole of BPE in the analyte reservoir, in which rGO represents reduced graphene oxide. Under a suitable driving voltage (Vtot), the electrochemical reduction/oxidation of electroactive probes, such as H2O2/glutathione (Glu), in the analyte reservoir could induce the reversible color change of PMT films in the reporting reservoir between blue and red. Based on this, a keypad lock with H2O2 , Glu, and Vtot =-3.0 V as the three inputs and the color change of PMT films as the visible output was established. This system was easily operated and did not need to synthesize the complex compounds or DNA molecules. The security system was easy to reset and could be used repeatedly. © 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Controlling Variable Emittance (MEMS) Coatings for Space Applications

NASA Technical Reports Server (NTRS)

Farrar, D.; Schneider, W.; Osiander, R.; Champion, J. L.; Darrin, A. G.; Douglas, Donya; Swanson, Ted D.

2003-01-01

Small spacecraft, including micro and nanosats, as they are envisioned for future missions, will require an alternative means to achieve thermal control due to their small power and mass budgets. One of the proposed alternatives is Variable Emittance (Vari-E) Coatings for spacecraft radiators. Space Technology-5 (ST-5) is a technology demonstration mission through NASA Goddard Space Flight Center (GSFC) that will utilize Vari-E Coatings. This mission involves a constellation of three (3) satellites in a highly elliptical orbit with a perigee altitude of approximately 200 kilometers and an apogee of approximately 38,000 kilometers. Such an environment will expose the spacecraft to a wide swing in the thermal and radiation environment of the earth's atmosphere. There are three (3) different technologies associated with this mission. The three technologies are electrophoretic, electrochromic, and Micro ElectroMechanical Systems (MEMS). The ultimate goal is to make use of Van-E coatings, in order to achieve various levels of thermal control. The focus of this paper is to highlight the Vari-E Coating MEMS instrument, with an emphasis on the Electronic Control Unit responsible for operating the MEMS device. The Test & Evaluation approach, along with the results, is specific for application on ST-5, yet the information provides a guideline for future experiments and/or thermal applications on the exterior structure of a spacecraft.

Layer-by-Layer Assembly of a pH-Responsive and Electrochromic Thin Film

ERIC Educational Resources Information Center

Schmidt, Daniel J.; Pridgen, Eric M.; Hammond, Paula T.; Love, J. Christopher

2010-01-01

This article summarizes an experiment on thin-film fabrication with layer-by-layer assembly that is appropriate for undergraduate laboratory courses. The purpose of this experiment is to teach students about self-assembly in the context of thin films and to expose students to the concepts of functional polymeric coatings. Students dip coat…

Tunable Optical Polymer Systems

DTIC Science & Technology

2004-10-29

effected , the amount of energy required to achieve optical tunability, satisfactory color contrasts, durability, the processability of the chromogenic...moieties. However, this interaction is not strong enough to cause a pronounced effect in its photophysics. As a result of this slight interaction...oxidation accompanied by a color change. The reduction behavior is unstable and causes loss of the electrochromic effect . The PPTZPQ

End-group-directed self-assembly of organic compounds useful for photovoltaic applications

DOEpatents

Beaujuge, Pierre M.; Lee, Olivia P.; Yiu, Alan T.; Frechet, Jean M.J.

2016-05-31

The present invention provides for an organic compound comprising electron deficient unit covalently linked to two or more electron rich units. The present invention also provides for a device comprising the organic compound, such as a light-emitting diode, thin-film transistor, chemical biosensor, non-emissive electrochromic, memory device, photovoltaic cells, or the like.

Exploring Electrochromics: A Series of Eye-Catching Experiments to Introduce Students to Multidisciplinary Research

ERIC Educational Resources Information Center

Small, Leo J.; Wolf, Steven; Spoerke, Erik D.

2014-01-01

Introducing students to a multidisciplinary research laboratory presents challenges in terms of learning specific technical skills and concepts but also with respect to integrating different technical elements to form a coherent picture of the research. Here we present a multidisciplinary series of experiments we have developed in the Electronic,…

A Modular Framework for 3 Way Electrochromic Switches

DTIC Science & Technology

2017-09-01

Department of the Army position unless so designated by other authorized documents. Citation of manufacturer’s or trade names does not constitute an...spectroscopy, molecular design 44 B Christopher Rinderspacher 410-306-2811Unclassified Unclassified Unclassified UU ii Approved for public release...Deprotonated spectral data compared for lowest energy conformer. Superscripts N and D denote the neutral and deprotonated values, respectively

Adaptive chromogenic materials and devices

NASA Astrophysics Data System (ADS)

Sixou, Pierre; Guillard, H.; Labonne, L.; Gandolfo, V.

2003-03-01

Electrically controllable glasses can be used to control daylight and solar energy in buildings and in automotives in order to improve quality of life and to save energy spent on lighting, cooling and heating. The paper discusses the case of switchable glazings using liquid crystal/polymer micro-composites. A comparison with other technologies (like inorganic electrochromics, thermotropic gels and dispersed particles) is drawn.

Three-Dimensional Conductive Nanocomposites Based on Multiwalled Carbon Nanotube Networks and PEDOT:PSS as a Flexible Transparent Electrode for Optoelectronics.

PubMed

Cho, Er-Chieh; Li, Chiu-Ping; Huang, Jui-Hsiung; Lee, Kuen-Chan; Huang, Jen-Hsien

2015-06-03

We have synthesized conductive nanocomposites composed of multiwalled carbon nanotubes (MWCNTs) and Au nanoparticles (NPs). The Au NPs with an average size of approximately 4.3 nm are uniformly anchored on the MWCNT. After being exposed to microwave (MW) plasma irradiation, the anchored Au NPs melt and fuse, leading to larger aggregates (34 nm) that can connect the MWCNT forming a three-dimensional conducting network. The formation of a continuous MWCNT network can produce more a conductive pathway, leading to lower sheet resistance. When the Au-MWCNT is dispersed in the highly conductive polymer, poly(ethylene dioxythiophene):polystyrenesulfonate ( PSS), we can obtain solution-processable composite formulations for the preparation of a flexible transparent electrode. The resulting Au-MWCNT/PEDOT:PSS hybrid films possess a sheet resistance of 51 Ω/sq with a transmittance of 86.2% at 550 nm. We also fabricate flexible organic solar cells and electrochromic devices to demonstrate the potential use of the as-prepared composite electrodes. Compared with the indium tin oxide-based devices, both the solar cells and electrochromic devices with the composites incorporated as a transparent electrode deliver comparable performance.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Luo Yuanyuan; Duan Guotao; Li Guanghai

Flower-like Ni(OH){sub 2} nanoarchitectures have been synthesized through a one-step mild hydrothermal reaction with the aid of ethylenediamine in NiCl{sub 2} aqueous solution. The flower with the size of several micrometers in diameter is composed of the ultra-thin nanosheets of several nanometers in thickness. It was found the ethylenediamine is vital to the formation of the flower-like nanoarchitectures. The influence of the concentration of the ethylenediamine and the reaction temperature on the formation of the flowers was analyzed and the formation mechanism of the flowers was proposed. Such flower-like {beta}-Ni(OH){sub 2} nanoarchitectures will find potential applications in the fields, suchmore » as electrode, or will be used as a starting material to produce NiO, which is widely used in the magnetic, catalysts, sensor and electrochromic devices. - Graphical abstract: Flower-like Ni(OH){sub 2} nanoarchitectures were synthesized by a one-step mild hydrothermal reaction with the aid of ethylenediamine in NiCl{sub 2} aqueous solution. The flower with the size of several micrometers in diameter is composed of the ultra-thin nanosheets of several nanometers in thickness. The flowers could be in catalysts, sensor and electrochromic devices, and alkaline rechargeable batteries.« less

Preparation of ordered mesoporous alumina-doped titania films with high thermal stability and their application to high-speed passive-matrix electrochromic displays.

PubMed

Jiang, Xiangfen; Bastakoti, Bishnu Prasad; Weng, Wu; Higuchi, Tetsuya; Oveisi, Hamid; Suzuki, Norihiro; Chen, Wei-Jung; Huang, Yu-Tzu; Yamauchi, Yusuke

2013-08-12

Ordered mesoporous alumina-doped titania thin films with anatase crystalline structure were prepared by using triblock copolymer Pluronic P123 as structure-directing agent. Uniform Al doping was realized by using aluminum isopropoxide as a dopant source which can be hydrolyzed together with titanium tetraisopropoxide. Aluminum doping into the titania framework can prevent rapid crystallization to the anatase phase, thereby drastically increasing thermal stability. With increasing Al content, the crystallization temperatures tend to increase gradually. Even when the Al content doped into the framework was increased to 15 mol %, a well-ordered mesoporous structure was obtained, and the mesostructural ordering was still maintained after calcination at 550 °C. During the calcination process, large uniaxial shrinkage occurred along the direction perpendicular to the substrate with retention of the horizontal mesoscale periodicity, whereby vertically oriented nanopillars were formed in the film. The resulting vertical porosity was successfully exploited to fabricate a high-speed and high-quality passive-matrix electrochromic display by using a leuco dye. The vertical nanospace in the films can effectively prevent drifting of the leuco dye. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

From Broadband to Electrochromic Notch Filters with Printed Monochiral Carbon Nanotubes

PubMed Central

2018-01-01

Dense layers of semiconducting single-walled carbon nanotubes (SWNTs) serve as electrochromic (EC) materials in the near-infrared with high optical density and high conductivity. EC cells with tunable notch filter properties instead of broadband absorption are created via highly selective dispersion of specific semiconducting SWNTs through polymer-wrapping followed by deposition of thick films by aerosol-jet printing. A simple planar geometry with spray-coated mixed SWNTs as the counter electrode renders transparent metal oxides redundant and facilitates complete bleaching within a few seconds through iongel electrolytes with high ionic conductivities. Monochiral (6,5) SWNT films as working electrodes exhibit a narrow absorption band at 997 nm (full width at half-maximum of 55–73 nm) with voltage-dependent optical densities between 0.2 and 4.5 and a modulation depth of up to 43 dB. These (6,5) SWNT notch filters can retain more than 95% of maximum bleaching for several hours under open-circuit conditions. In addition, different levels of transmission can be set by applying constant low voltage (1.5 V) pulses with modulated width or by a given number of fixed short pulses. PMID:29521086

An electrochemically-driven dual-mode display device with both reflective and emissive modes using poly(p-phenylenevinylene) derivatives

NASA Astrophysics Data System (ADS)

Tsuneyasu, Shota; Jin, Lu; Nakamura, Kazuki; Kobayashi, Norihisa

2016-04-01

We demonstrate a novel electrochemical dual-mode displaying (DMD) device, which enables control of both coloration and light emission using an electrochemical reaction. The coloration control of the DMD device was based on an electrochromic (EC) reaction, whereas the light emission of the device was caused by an electrochemiluminescence (ECL) mechanism. This novel DMD device consisted of a pair of facing conductive polymer-modified electrodes: comb-shaped interdigitated Au electrodes modified with poly[2-methoxy-5-(2-ethylhexyloxy)-1,4-phenylenevinylene] (MEH-PPV) layers and poly(2,3-dihydrothieno-1,4-dioxin)-poly(styrene sulfonate) (PEDOT/PSS) film-modified indium tin oxide (ITO) electrodes. When a bias voltage was applied between the PEDOT/PSS film-modified ITO electrode and the comb-shaped electrodes, a color change of the device was observed by the EC reaction of the MEH-PPV and PEDOT/PSS. On the other hand, an emission was obtained when the bias voltage was applied between two comb-shaped interdigitated electrodes. The orange emission was ascribed to the ECL reaction of the MEH-PPV layer, which resulted from the formation of a p-i-n junction in this layer.

JPRS Report, Science & Technology: Europe.

DTIC Science & Technology

1992-11-10

Electrochromic, photochromic, and thermochromic layers , which provide targeted control over the degree of transparency; the latter includes the...22 Research Into Reducing Eastern German Air Pollution Advances [Bonn BMFT JOURNAL, No 4, Aug 92] 22 German Institute: Solar Hydrogen Will Reduce...the aerodynam- icists will have to rely on the trick of boundary layer control at the rudder unit in order to achieve the longest possible laminar

A preliminary study of flat-panel displays

NASA Technical Reports Server (NTRS)

Yancey, K. E.

1986-01-01

Six display technologies that might be of future value in a spacelab workstation are discussed. Some have been developed to the point where they could be used as a computer display while others have not. The display technologies studied are electroluminescents, light-emitting didodes, gas plasma, liquid crystal, electrochromic, and electrophoretic. An explanation of each mechanism is provided along with the state-of-the-art development.

Multicolor Electrochromic Displays Exploratory Development

DTIC Science & Technology

1989-07-01

Electrodes with PEG Plasticizers in KCI ...................... 42 6. Electrodes in KCI-AMPS and KCI-PolyAMPS Electrolytes .. 43 7. Orange/Blue Cycling...ethylene glycol) ( PEG ) preparations with average molecular weights of 300 and 3350 were from J.T. Baker Chemical Co. 3. Conductive Substrates Most of...crystallization of the dye. Poly(ethylene glycols) of molecular weights 300 and 3350 were introduced by incorporating them in the IM KCI electrolyte

Engineering of Metal Oxide Nanoparticles for Application in Electrochemical Devices

NASA Astrophysics Data System (ADS)

Santos, Lidia Sofia Leitao

The growing demand for materials and devices with new functionalities led to the increased interest in the field of nanomaterials and nanotechnologies. Nanoparticles, not only present a reduced size as well as high reactivity, which allows the development of electronic and electrochemical devices with exclusive properties, when compared with thin films. This dissertation aims to explore the development of several nanostructured metal oxides by solvothermal synthesis and its application in different electrochemical devices. Within this broad theme, this study has a specific number of objectives: a) research of the influence of the synthesis parameters to the structure and morphology of the nanoparticles; b) improvement of the performance of the electrochromic devices with the application of the nanoparticles as electrode; c) application of the nanoparticles as probes to sensing devices; and d) production of solution-pro-cessed transistors with a nanostructured metal oxide semiconductor. Regarding the results, several conclusions can be exposed. Solvothermal synthesis shows to be a very versatile method to control the growth and morphology of the nanoparticles. The electrochromic device performance is influenced by the different structures and morphologies of WO3 nanoparticles, mainly due to the surface area and conductivity of the materials. The deposition of the electrochromic layer by inkjet printing allows the patterning of the electrodes without wasting material and without any additional steps. Nanostructured WO3 probes were produced by electrodeposition and drop casting and applied as pH sensor and biosensor, respectively. The good performance and sensitivity of the devices is explained by the high number of electrochemical reactions occurring at the surface of the na-noparticles. GIZO nanoparticles were deposited by spin coating and used in electrolyte-gated transistors, which promotes a good interface between the semiconductor and the dielectric. The produced transistors work at low potential and with improved ON-OFF current ratio, up to 6 orders of mag-nitude. To summarize, the low temperatures used in the production of the devices are compatible with flexible substrates and additionally, the low cost of the techniques involved can be adapted for disposable devices.

Variable Emissivity Through MEMS Technology

NASA Technical Reports Server (NTRS)

Darrin, Ann Garrison; Osiander, Robert; Champion, John; Swanson, Ted; Douglas, Donya; Grob, Lisa M.; Powers, Edward I. (Technical Monitor)

2000-01-01

This paper discusses a new technology for variable emissivity (vari-e) radiator surfaces, which has significant advantages over traditional radiators and promises an alternative design technique for future spacecraft thermal control systems. All spacecraft rely on radiative surfaces to dissipate waste heat. These radiators have special coatings, typically with a low solar absorptivity and a high infrared-red emissivity, that are intended to optimize performance under the expected heat load and thermal sink environment. The dynamics of the heat loads and thermal environment make it a challenge to properly size the radiator and often require some means of regulating the heat rejection rate of the radiators in order to achieve proper thermal balance. Specialized thermal control coatings, which can passively or actively adjust their emissivity offer an attractive solution to these design challenges. Such systems would allow intelligent control of the rate of heat loss from a radiator in response to heat load and thermal environmental variations. Intelligent thermal control through variable emissivity systems is well suited for nano and pico spacecraft applications where large thermal fluctuations are expected due to the small thermal mass and limited electric resources. Presently there are three different types of vari-e technologies under development: Micro ElectroMechanical Systems (MEMS) louvers, Electrochromic devices, and Electrophoretic devices. This paper will describe several prototypes of micromachined (MEMS) louvers and experimental results for the emissivity variations measured on theses prototypes. It will further discuss possible actuation mechanisms and space reliability aspects for different designs. Finally, for comparison parametric evaluations of the thermal performances of the new vari-e technology and standard thermal control systems are presented in this paper.

Fabricating Electrochromic Thin Films Based on Metallo-Polymers Using Layer-by-Layer Self-Assembly: An Attractive Laboratory Experiment

ERIC Educational Resources Information Center

Schott, Marco; Beck, Matthias; Winkler, Franziska; Lorrmann, Henning; Kurth, Dirk G.

2015-01-01

Metallo-supramolecular polyelectrolytes (MEPE) based on iron(II)-acetate and 1,4-bis(2,2':6',2?-terpyridin-4'-yl)benzene are assembled by layer-by-layer deposition on transparent electrode surfaces. When a potential is applied, the color of the film can be switched from blue to transparent. Due to the strong absorption and the fast switching…

Thermal Control Using Electrochromism

NASA Technical Reports Server (NTRS)

Vaidyanathan, Hari; Rao, Gopalakrishna

1998-01-01

The applicability of a charge balanced electrochromic device to modulate the frequencies in the thermal infra red region is examined in this study. The device consisted of a transparent conductor, WO3 anode, PMMA/LiClO4, electrolyte, V2O5, cathode and transparent conductor. The supporting structure in the device is SnO2 coated glass and the edges are sealed with epoxy to reduce moisture absorption. The performance evaluation comprised of cyclic voltammetric measurements and determination of transmittance at various wavelengths. The device was subjected to anodic and cathodic polarization by sweeping the potential at a rate of 10 mV/sec from -0.8 V to 1.8 V. The current versus voltage profile indicated no reaction between -0.5 and +0.5 V. The device is colored green at 1.8 V with a transmittance of 5% at a wavelength, lambda = 900 nm and colorless at -0.8 V with a transmittance of 74% at X = 500 nm. The optical modulation is limited to 400-1500 nm and there is no activity in the thermal infrared. The switching time is 75 seconds for transmittance to decrease from 74% to 50%. The device yielded reproducible values for transmittance when cycled between colored and bleached states by application of 1.8 V and -0.8 V, respectively.

Thermal Control Using Electrochromism

NASA Technical Reports Server (NTRS)

Vaidyanathan, Hari; Rao, Gopalakrishna

1999-01-01

The applicability of a charge balanced electrochromic device to modulate the frequencies in the thermal infrared region is examined in this study. The device consisted of a transparent conductor, WO3, anode, PMMA/LiClO4 electrolyte, V2O5 cathode and transparent conductor. The supporting structure in the device is SnO2 coated glass and the edges are sealed with epoxy to reduce moisture absorption. The performance evaluation comprised of cyclic voltammetric measurements and determination of transmittance at various wavelengths. The device was subjected to anodic and cathodic polarization by sweeping the potential at a rate of 10 mV/sec from -0.8V to 1.8V. The current versus voltage profile indicated no reaction between -0.5 and +0.5 V. The device is colored green at 1.8 V with a transmittance of 5% at a wavelength, lambda = 900 nm and colorless at -0.8 V with a transmittance of 74% at lambda = 500 nm. The optical modulation is limited to 400-1500 nm and there is no activity in the thermal infrared. The switching time is a function of temperature and time for coloring reaction was slower than the bleaching reaction. The device yielded reproducible values for transmittance when cycled between colored and bleached states by application of 1.8V and -0.8V, respectively.

Thermal Control using Electrochromism

NASA Technical Reports Server (NTRS)

Vaidyanathan, Hari; Rao, Gopalakrishna

1998-01-01

The applicability of a charge balanced electrochromic device to modulate the frequencies in the thermal infrared region is examined in this study. The device consisted of a transparent conductor, WO3 anode, PMMA/LiClO4 electrolyte, V2O5 cathode and transparent conductor. The supporting structure in the device is SnO2 coated glass and the edges are sealed with epoxy to reduce moisture absorption. The performance evaluation comprised of cyclic voltammetric measurements and determination of transmittance at various wavelengths. The device was subjected to anodic and cathodic polarization by sweeping the potential at a rate of 10 mV/sec from -0.8V to 1.8V. The current versus voltage profile indicated no reaction between -0.5 and +0.5 V. The device is colored green at 1.8V with a transmittance of 5% at a wavelength, lambda=900 nm and colorless at -0.8V with a transmittance of 74% at lambda=500 nm. The optical modulation is limited to 400-1500 nm and there is no activity in the thermal infrared. The switching time is 75 seconds for transmittance to decrease from 74% to 50%. The device yielded reproducible values for transmittance when cycled between colored and bleached states by application of 1.8V and -0.8V, respectively.

In situ measurements of the optical absorption of dioxythiophene-based conjugated polymers

NASA Astrophysics Data System (ADS)

Hwang, J.; Schwendeman, I.; Ihas, B. C.; Clark, R. J.; Cornick, M.; Nikolou, M.; Argun, A.; Reynolds, J. R.; Tanner, D. B.

2011-05-01

Conjugated polymers can be reversibly doped by electrochemical means. This doping introduces new subband-gap optical absorption bands in the polymer while decreasing the band-gap absorption. To study this behavior, we have prepared an electrochemical cell allowing in situ measurements of the optical properties of the polymer. The cell consists of a thin polymer film deposited on gold-coated Mylar behind which is another polymer that serves as a counterelectrode. An infrared transparent window protects the upper polymer from ambient air. By adding a gel electrolyte and making electrical connections to the polymer-on-gold films, one may study electrochromism in a wide spectral range. As the cell voltage (the potential difference between the two electrodes) changes, the doping level of the conjugated polymer films is changed reversibly. Our experiments address electrochromism in poly(3,4-ethylenedioxythiophene) (PEDOT) and poly(3,4-dimethylpropylenedioxythiophene) (PProDOT-Me2). This closed electrochemical cell allows the study of the doping induced subband-gap features (polaronic and bipolaronic modes) in these easily oxidized and highly redox switchable polymers. We also study the changes in cell spectra as a function of polymer thickness and investigate strategies to obtain cleaner spectra, minimizing the contributions of water and gel electrolyte features.

Microstructure, optical, and electrochromic properties of sol-gel nanoporous tungsten oxide films

NASA Astrophysics Data System (ADS)

Djaoued, Yahia; Ashrit, P. V.; Badilescu, S.; Bruning, R.

2003-08-01

Porous tungsten oxide films have been prepared by a nonhydrolitic sol-gel method using poly(ethylene glycol) (PEG) as a structure directing agent. The method entails the hydrolysis of an ethanolic solution of tungsten ethoxide (formed by the reaction of WCl6 with ethanol) followed by condensation and polymerization at the PEG-tungsten oxide oligometers interface. A highly porous WO3 framework was obtained after PEG was burned off by calcination at a relativley low temperature. AFM images of the films treated thermally show an ordered material rather than microscopic particulates. Both fibrilar nanostructures and striped phase can be obtained via this approach, depending on the concentration of PEG in the coating solution. XRD data from the fibrils indicate that they are crystalline with very small crystals, whereas the striped phases obtained with 20% PEG correspond to two crystalline phases, one, the stoichiometric WO3 and the other one an oxygen deficient phase, containing larger crystals (~28 nm). The results show that PEG promotes the formation of oxygen deficient phases and delays crystallization. Compared to WO3 with no PEG, the optical and electrochromic properties of the macroporous tungsten oxide films appear to be significantly improved. The formation of organized nanostructures is tentatively accounted for by the strong hydrogen bonding interactions between PEG and the tungsten oxide oligomers.

Low-Cost and Facile Synthesis of the Vanadium Oxides V2O3, VO2, and V2O5 and Their Magnetic, Thermochromic and Electrochromic Properties.

PubMed

Mjejri, Issam; Rougier, Aline; Gaudon, Manuel

2017-02-06

In this study, vanadium sesquioxide (V 2 O 3 ), dioxide (VO 2 ), and pentoxide (V 2 O 5 ) were all synthesized from a single polyol route through the precipitation of an intermediate precursor: vanadium ethylene glycolate (VEG). Various annealing treatments of the VEG precursor, under controlled atmosphere and temperature, led to the successful synthesis of the three pure oxides, with sub-micrometer crystallite size. To the best of our knowledge, the synthesis of the three oxides V 2 O 5 , VO 2 , and V 2 O 3 from a single polyol batch has never been reported in the literature. In a second part of the study, the potentialities brought about by the successful preparation of sub-micrometer V 2 O 5 , VO 2 , and V 2 O 3 are illustrated by the characterization of the electrochromic properties of V 2 O 5 films, a discussion about the metal to insulator transition of VO 2 on the basis of in situ measurements versus temperature of its electrical and optical properties, and the characterization of the magnetic transition of V 2 O 3 powder from SQUID measurements. For the latter compound, the influence of the crystallite size on the magnetic properties is discussed.

Roll-to-Roll sputtered ITO/Cu/ITO multilayer electrode for flexible, transparent thin film heaters and electrochromic applications.

PubMed

Park, Sung-Hyun; Lee, Sang-Mok; Ko, Eun-Hye; Kim, Tae-Ho; Nah, Yoon-Chae; Lee, Sang-Jin; Lee, Jae Heung; Kim, Han-Ki

2016-09-22

We fabricate high-performance, flexible, transparent electrochromic (EC) films and thin film heaters (TFHs) on an ITO/Cu/ITO (ICI) multilayer electrode prepared by continuous roll-to-roll (RTR) sputtering of ITO and Cu targets. The RTR-sputtered ICI multilayer on a 700 mm wide PET substrate at room temperature exhibits a sheet resistance of 11.8 Ω/square and optical transmittance of 73.9%, which are acceptable for the fabrication of flexible and transparent EC films and TFHs. The effect of the Cu interlayer thickness on the electrical and optical properties of the ICI multilayer was investigated in detail. The bending and cycling fatigue tests demonstrate that the RTR-sputtered ICI multilayer was more flexible than a single ITO film because of high strain failure of the Cu interlayer. The flexible and transparent EC films and TFHs fabricated on the ICI electrode show better performances than reference EC films and TFHs with a single ITO electrode. Therefore, the RTR-sputtered ICI multilayer is the best substitute for the conventional ITO film electrode in order to realize flexible, transparent, cost-effective and large-area EC devices and TFHs that can be used as flexible and smart windows.

Roll-to-Roll sputtered ITO/Cu/ITO multilayer electrode for flexible, transparent thin film heaters and electrochromic applications

NASA Astrophysics Data System (ADS)

Park, Sung-Hyun; Lee, Sang-Mok; Ko, Eun-Hye; Kim, Tae-Ho; Nah, Yoon-Chae; Lee, Sang-Jin; Lee, Jae Heung; Kim, Han-Ki

2016-09-01

We fabricate high-performance, flexible, transparent electrochromic (EC) films and thin film heaters (TFHs) on an ITO/Cu/ITO (ICI) multilayer electrode prepared by continuous roll-to-roll (RTR) sputtering of ITO and Cu targets. The RTR-sputtered ICI multilayer on a 700 mm wide PET substrate at room temperature exhibits a sheet resistance of 11.8 Ω/square and optical transmittance of 73.9%, which are acceptable for the fabrication of flexible and transparent EC films and TFHs. The effect of the Cu interlayer thickness on the electrical and optical properties of the ICI multilayer was investigated in detail. The bending and cycling fatigue tests demonstrate that the RTR-sputtered ICI multilayer was more flexible than a single ITO film because of high strain failure of the Cu interlayer. The flexible and transparent EC films and TFHs fabricated on the ICI electrode show better performances than reference EC films and TFHs with a single ITO electrode. Therefore, the RTR-sputtered ICI multilayer is the best substitute for the conventional ITO film electrode in order to realize flexible, transparent, cost-effective and large-area EC devices and TFHs that can be used as flexible and smart windows.

New thin films of NiO doped with V2O5 for electrochromic applications

NASA Astrophysics Data System (ADS)

Azevedo, Cristiane F.; Balboni, Raphael D. C.; Cholant, Camila M.; Moura, Elton A.; Lemos, Rafaela M. J.; Pawlicka, Agnieszka; Gündel, Andre; Flores, Wladimir H.; Pereira, Marcelo; Avellaneda, César O.

2017-11-01

This paper reports on synthesis and characterization of new electrochromic thin films of NiO doped with V2O5 that were prepared by the sol-gel method and deposited by the spin coating technique. The confirmation of the presence of the dopant in the structure of the films was given by energy-dispersive X-ray spectroscopy (EDX). The effect of the addition of vanadium to the films of NiO was evaluated by electrochemical techniques such as cyclic voltammetry, chronocoulometry, and chronoamperometry in 0.5 mol/L KOH electrolyte. The morphology and the structure of the films, determined by microscopies (SEM and AFM), reveal smooth and slightly rough surfaces. The addition of vanadium as a dopant does not produce changes in the host NiO matrix as evidenced by X-ray diffractometry (XRD). However, the addition of the dopant causes a significant improvement in a charge density values of the films that increase more than twice from 25.5 mC/cm2 for NiO to 52.8 mC/cm2 for NiO with 10 mol% of V2O5. V2O5 doping of NiO films also improved their optical properties as well as kinetics of insertion and extraction processes.

Electrochromic Graphene Molecules

DOE PAGES

Ji, Zhiqiang; Doorn, Stephen K.; Sykora, Milan

2015-03-13

Polyclic aromatic hydrocarbons, also called Graphene Molecules (GMs), with chemical composition C 132H 36(COOH) 2 were synthesized in-situ on the surface of transparent nanocrystaline indium tin oxide (nc-ITO) electrodes. Their electronic structure was studied electrochemically and spectro-electrochemically. Variations in the potential applied onto the nc-ITO/GM electrodes induce only small changes in the observed current but they produce dramatic changes in the absorption of the GMs, which are associated with their oxidation and reduction. Analysis of the absorption changes using modified Nernst equation is used to determine standard potentials associated with the individual charge transfer processes. For the GMs prepared heremore » these were found to be E 1,ox 0 = 0.77± 0.01 V and E 2,ox 0 = 1.24 ± 0.02 V vs. NHE for the first and second oxidation and E 1,red 0 = -1.50 ± 0.04 V for the first reduction. The charge transfer processes are found to be non-ideal. The non-ideality factors associated with the oxidation and reduction processes suggest presence of strong interactions between the GM redox centers. Under the conditions of potential cycling GMs show rapid (seconds) color change with high contrast and stability. An electrochromic application is demonstrated wherein the GMs are used as the optically active component.« less

Integration of graphene sensor with electrochromic device on modulus-gradient polymer for instantaneous strain visualization

NASA Astrophysics Data System (ADS)

Yang, Tingting; Zhong, Yujia; Tao, Dashuai; Li, Xinming; Zang, Xiaobei; Lin, Shuyuan; Jiang, Xin; Li, Zhihong; Zhu, Hongwei

2017-09-01

In nature, some animals change their deceptive coloration for camouflage, temperature preservation or communication. This astonishing function has inspired scientists to replicate the color changing abilities of animals with artificial skin. Recently, some studies have focused on the smart materials and devices with reversible color changing or light-emitting properties for instantaneous strain visualization. However, most of these works only show eye-detectable appearance change when subjected to large mechanical deformation (100%-500% strain), and conspicuous color change at small strain remains rarely explored. In the present study, we developed a user-interactive electronic skin with human-readable optical output by assembling a highly sensitive resistive strain sensor with a stretchable organic electrochromic device (ECD) together. We explored the substrate effect on the electromechanical behavior of graphene and designed a strategy of modulus-gradient structure to employ graphene as both the highly sensitive strain sensing element and the insensitive stretchable electrode of the ECD layer. Subtle strain (0-10%) was enough to evoke an obvious color change, and the RGB value of the color quantified the magnitude of the applied strain. Such high sensitivity to smaller strains (0-10%) with color changing capability will potentially enhance the function of wearable devices, robots and prosthetics in the future.

Roll-to-Roll sputtered ITO/Cu/ITO multilayer electrode for flexible, transparent thin film heaters and electrochromic applications

PubMed Central

Park, Sung-Hyun; Lee, Sang-Mok; Ko, Eun-Hye; Kim, Tae-Ho; Nah, Yoon-Chae; Lee, Sang-Jin; Lee, Jae Heung; Kim, Han-Ki

2016-01-01

We fabricate high-performance, flexible, transparent electrochromic (EC) films and thin film heaters (TFHs) on an ITO/Cu/ITO (ICI) multilayer electrode prepared by continuous roll-to-roll (RTR) sputtering of ITO and Cu targets. The RTR-sputtered ICI multilayer on a 700 mm wide PET substrate at room temperature exhibits a sheet resistance of 11.8 Ω/square and optical transmittance of 73.9%, which are acceptable for the fabrication of flexible and transparent EC films and TFHs. The effect of the Cu interlayer thickness on the electrical and optical properties of the ICI multilayer was investigated in detail. The bending and cycling fatigue tests demonstrate that the RTR-sputtered ICI multilayer was more flexible than a single ITO film because of high strain failure of the Cu interlayer. The flexible and transparent EC films and TFHs fabricated on the ICI electrode show better performances than reference EC films and TFHs with a single ITO electrode. Therefore, the RTR-sputtered ICI multilayer is the best substitute for the conventional ITO film electrode in order to realize flexible, transparent, cost-effective and large-area EC devices and TFHs that can be used as flexible and smart windows. PMID:27653830

Electrochemical properties of thin films of V2O5 doped with TiO2

NASA Astrophysics Data System (ADS)

Moura, E. A.; Cholant, C. M.; Balboni, R. D. C.; Westphal, T. M.; Lemos, R. M. J.; Azevedo, C. F.; Gündel, A.; Flores, W. H.; Gomez, J. A.; Ely, F.; Pawlicka, A.; Avellaneda, C. O.

2018-08-01

The paper presents a systematic study of the electrochromic properties of thin films of V2O5:TiO2 for a possible utilization as counter-electrode in electrochromic devices. The V2O5:TiO2 thin films were prepared by the sol-gel process and deposited on a substrate of fluorine-tin oxide transparent electrode (FTO) using the dip coating technique and heat treatment at 350 °C for 30 min. The films were characterized by chronocoulometry, cyclic voltammetry (CV), UV-Vis, scanning electron microscopy (SEM), energy dispersive spectroscopy (EDS), atomic force microscopy (AFM), profilometry, and X-ray diffraction (XRD). The best results were obtained for the film of V2O5 with 7.5 mol% of TiO2, which presented highest ion storage capacity of ∼106 mC cm-2 and redox reversibility of 1. The diffusion of the Li+ ions into the thin films was modeled by solving Fick equations with appropriate boundary conditions for a plane sheet geometry. Besides that, these films showed optical modulation of 35% at 633 nm after coloration and bleaching. The XRD patterns revealed that the films have an orthorhombic crystal structure; the AFM and the profilometry confirmed roughness and thickness of 16.76 and 617 nm, respectively.

Visible-to-NIR Electrochromic Device Prepared from a Thermally Polymerizable Electroactive Organic Monomer.

PubMed

Wałęsa-Chorab, Monika; Skene, W G

2017-06-28

A monomer (1) consisting of a benzothiadiazole core flanked by two triphenylamines and two styrene pendant moieties was prepared. The monomer was fluorescent with its emission spanning 145 nm in the visible, contingent on the organic solvent used for the measurement. In addition to its positive solvatochromism, the absolute fluorescence quantum yield (Φ fl ) was consistently >20% with values >80% being measured in hexane, toluene, diethyl ether, and toluene. 1 could be reversibly oxidized with an oxidation potential of 880 mV vs SCE. The monomer could be immobilized on ITO-coated glass substrates. The resulting 425 nm thick immobilized film (poly-1) was 15% thinner than the monomer coating deposited by spray- and spin-coating. The electroactive film did not delaminate from the electrode upon either washing or cycling electrochemically between its oxidized and neutral states. Its absorption at 460 nm bleached upon electrochemical oxidation with the formation of a strong absorption at 880 nm and in the NIR, similar to 1. The perceived reversible color change with applied potential switched between yellow and gray. The fluorescence intensity of poly-1 could be switched with applied potentials. A passive transmissive device prepared from poly-1 was both electrochromic and fluorochromic, exhibiting reversible color change and fluorescence quenching.

Statistical mixture design and multivariate analysis of inkjet printed a-WO3/TiO2/WOX electrochromic films.

PubMed

Wojcik, Pawel Jerzy; Pereira, Luís; Martins, Rodrigo; Fortunato, Elvira

2014-01-13

An efficient mathematical strategy in the field of solution processed electrochromic (EC) films is outlined as a combination of an experimental work, modeling, and information extraction from massive computational data via statistical software. Design of Experiment (DOE) was used for statistical multivariate analysis and prediction of mixtures through a multiple regression model, as well as the optimization of a five-component sol-gel precursor subjected to complex constraints. This approach significantly reduces the number of experiments to be realized, from 162 in the full factorial (L=3) and 72 in the extreme vertices (D=2) approach down to only 30 runs, while still maintaining a high accuracy of the analysis. By carrying out a finite number of experiments, the empirical modeling in this study shows reasonably good prediction ability in terms of the overall EC performance. An optimized ink formulation was employed in a prototype of a passive EC matrix fabricated in order to test and trial this optically active material system together with a solid-state electrolyte for the prospective application in EC displays. Coupling of DOE with chromogenic material formulation shows the potential to maximize the capabilities of these systems and ensures increased productivity in many potential solution-processed electrochemical applications.

Star-Shaped Conjugated Molecules with Oxa- or Thiadiazole Bithiophene Side Arms.

PubMed

Kotwica, Kamil; Kostyuchenko, Anastasia S; Data, Przemyslaw; Marszalek, Tomasz; Skorka, Lukasz; Jaroch, Tomasz; Kacka, Sylwia; Zagorska, Malgorzata; Nowakowski, Robert; Monkman, Andrew P; Fisyuk, Alexander S; Pisula, Wojciech; Pron, Adam

2016-08-08

Star-shaped conjugated molecules, consisting of a benzene central unit symmetrically trisubstituted with either oxa- or thiadiazole bithiophene groups, were synthesized as promising molecules and building blocks for application in (opto)electronics and electrochromic devices. Their optical (Eg (opt)) as well as electrochemical (Eg (electro)) band gaps depended on the type of the side arm and the number of solubilizing alkyl substituents. Oxadiazole derivatives showed Eg (opt) slightly below 3 eV and by 0.2 eV larger than those determined for thiadiazole-based compounds. The presence of alkyl substituents in the arms additionally lowered the band gap. The obtained compounds were efficient electroluminophores in guest/host-type light-emitting diodes. They also showed a strong tendency to self-organize in monolayers deposited on graphite, as evidenced by scanning tunneling microscopy. The structural studies by X-ray scattering revealed the formation of supramolecular columnar stacks in which the molecules were organized. Differences in macroscopic alignment in the specimen indicated variations in the self-assembly mechanism between the molecules. The compounds as trifunctional monomers were electrochemically polymerized to yield the corresponding polymer network. As shown by UV/Vis-NIR spectroelectrochemical studies, these networks exhibited reversible electrochromic behavior both in the oxidation and in the reduction modes. © 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Printable Organic Nanoelectronics for Memory, Sensors and Display

DTIC Science & Technology

2014-02-01

central ion but associated with ring- based processes during oxidation and reduction. The electrochromic behaviour of the film was examined by cyclic...Fluorine-doped tin oxide 12  satDI Saturation current 9 scI Short circuit current 10 LiClO4 Lithium perchlorate 14 NADH reduced nicotinamide...resistor R and capacitor C , connected in parallel. The net current I is the sum of the circulating current and displacement components in the form

Temporal Variability of Observed and Simulated Hyperspectral Earth Reflectance

NASA Technical Reports Server (NTRS)

Roberts, Yolanda; Pilewskie, Peter; Kindel, Bruce; Feldman, Daniel; Collins, William D.

2012-01-01

The Climate Absolute Radiance and Refractivity Observatory (CLARREO) is a climate observation system designed to study Earth's climate variability with unprecedented absolute radiometric accuracy and SI traceability. Observation System Simulation Experiments (OSSEs) were developed using GCM output and MODTRAN to simulate CLARREO reflectance measurements during the 21st century as a design tool for the CLARREO hyperspectral shortwave imager. With OSSE simulations of hyperspectral reflectance, Feldman et al. [2011a,b] found that shortwave reflectance is able to detect changes in climate variables during the 21st century and improve time-to-detection compared to broadband measurements. The OSSE has been a powerful tool in the design of the CLARREO imager and for understanding the effect of climate change on the spectral variability of reflectance, but it is important to evaluate how well the OSSE simulates the Earth's present-day spectral variability. For this evaluation we have used hyperspectral reflectance measurements from the Scanning Imaging Absorption Spectrometer for Atmospheric Cartography (SCIAMACHY), a shortwave spectrometer that was operational between March 2002 and April 2012. To study the spectral variability of SCIAMACHY-measured and OSSE-simulated reflectance, we used principal component analysis (PCA), a spectral decomposition technique that identifies dominant modes of variability in a multivariate data set. Using quantitative comparisons of the OSSE and SCIAMACHY PCs, we have quantified how well the OSSE captures the spectral variability of Earth?s climate system at the beginning of the 21st century relative to SCIAMACHY measurements. These results showed that the OSSE and SCIAMACHY data sets share over 99% of their total variance in 2004. Using the PCs and the temporally distributed reflectance spectra projected onto the PCs (PC scores), we can study the temporal variability of the observed and simulated reflectance spectra. Multivariate time series analysis of the PC scores using techniques such as Singular Spectrum Analysis (SSA) and Multichannel SSA will provide information about the temporal variability of the dominant variables. Quantitative comparison techniques can evaluate how well the OSSE reproduces the temporal variability observed by SCIAMACHY spectral reflectance measurements during the first decade of the 21st century. PCA of OSSE-simulated reflectance can also be used to study how the dominant spectral variables change on centennial scales for forced and unforced climate change scenarios. To have confidence in OSSE predictions of the spectral variability of hyperspectral reflectance, it is first necessary for us to evaluate the degree to which the OSSE simulations are able to reproduce the Earth?s present-day spectral variability.

The effect of polymer architecture on the interdiffusion in thin polymer films

NASA Astrophysics Data System (ADS)

Caglayan, Ayse; Yuan, Guangcui; Satija, Sushil K.; Uhrig, David; Hong, Kunlun; Akgun, Bulent

Branched polymer chains have been traditionally used in industrial applications as additives. Recently they have found applications in electrochromic displays, lithography, biomedical coatings and targeting multidrug resistant bacteria. In some of these applications where they are confined in thin layers, it is important to understand the relation between the mobility and polymer chain architecture to optimize the processing conditions. Earlier interdiffusion measurements on linear and cyclic polymer chains demonstrated the key role of chain architecture on mobility. We have determined the vertical diffusion coefficients of the star polystyrene chains in thin films as a function of number of polymer arms, molecular weight per arm, and film thickness using neutron reflectivity (NR) and compare our results with linear chains of identical total molecular weight. Bilayer samples of 4-arm and 8-arm protonated polystyrenes (hPS) and deuterated polystyrenes (dPS) were used to elucidate the effect of polymer chain architecture on polymer diffusion. NR measurements indicate that the mobility of polymer chains in thin films get faster as the number of polymer arms increases and the arm molecular weight decreases. Both star polymers showed faster interdiffusion compared to their linear analog. Diffusion coefficient of branched PS chains has a weak dependence on the film thickness.

Template-Free Mesoporous Electrochromic Films on Flexible Substrates from Tungsten Oxide Nanorods

DOE PAGES

Heo, Sungyeon; Kim, Jongwook; Ong, Gary K.; ...

2017-08-08

Low-temperature processed mesoporous nanocrystal thin films are platforms for fabricating functional composite thin films on flexible substrates. Using a random arrangement of anisotropic nanocrystals can be a facile solution to generate pores without templates. However, the tendency for anisotropic particles to spontaneously assemble into a compact structure must be overcome. Here in this paper, we present a method to achieve random networking of nanorods during solution phase deposition by switching their ligand-stabilized colloidal nature into a charge-stabilized nature by a ligand-stripping chemistry. Ligand-stripped tungsten suboxide (WO 2.72) nanorods result in uniform mesoporous thin films owing to repulsive electrostatic forces preventingmore » nanorods from densely packing. Porosity and pore size distribution of thin films are controlled by changing the aspect ratio of the nanorods. This template-free mesoporous structure, achieved without annealing, provides a framework for introducing guest components, therefore enabling our fabrication of inorganic nanocomposite electrochromic films on flexible substrates. Following infilling of niobium polyoxometalate clusters into pores and successive chemical condensation, a WO x–NbO x composite film is produced that selectively controls visible and near-infrared light transmittance without any annealing required. The composite shows rapid switching kinetics and can be stably cycled between optical states over 2000 times. This simple strategy of using anisotropic nanocrystals gives insight into mesoporous thin film fabrication with broader applications for flexible devices.« less

Template-Free Mesoporous Electrochromic Films on Flexible Substrates from Tungsten Oxide Nanorods

DOE Office of Scientific and Technical Information (OSTI.GOV)

Heo, Sungyeon; Kim, Jongwook; Ong, Gary K.

Low-temperature processed mesoporous nanocrystal thin films are platforms for fabricating functional composite thin films on flexible substrates. Using a random arrangement of anisotropic nanocrystals can be a facile solution to generate pores without templates. However, the tendency for anisotropic particles to spontaneously assemble into a compact structure must be overcome. Here in this paper, we present a method to achieve random networking of nanorods during solution phase deposition by switching their ligand-stabilized colloidal nature into a charge-stabilized nature by a ligand-stripping chemistry. Ligand-stripped tungsten suboxide (WO 2.72) nanorods result in uniform mesoporous thin films owing to repulsive electrostatic forces preventingmore » nanorods from densely packing. Porosity and pore size distribution of thin films are controlled by changing the aspect ratio of the nanorods. This template-free mesoporous structure, achieved without annealing, provides a framework for introducing guest components, therefore enabling our fabrication of inorganic nanocomposite electrochromic films on flexible substrates. Following infilling of niobium polyoxometalate clusters into pores and successive chemical condensation, a WO x–NbO x composite film is produced that selectively controls visible and near-infrared light transmittance without any annealing required. The composite shows rapid switching kinetics and can be stably cycled between optical states over 2000 times. This simple strategy of using anisotropic nanocrystals gives insight into mesoporous thin film fabrication with broader applications for flexible devices.« less

Multistate Redox Switching and Near-Infrared Electrochromism Based on a Star-Shaped Triruthenium Complex with a Triarylamine Core

NASA Astrophysics Data System (ADS)

Tang, Jian-Hong; He, Yan-Qin; Shao, Jiang-Yang; Gong, Zhong-Liang; Zhong, Yu-Wu

2016-10-01

A star-shaped cyclometalated triruthenium complex 2(PF6)n (n = 3 and 4) with a triarylamine core was synthesized, which functions as a molecular switch with five well-separated redox states in both solution and film states. The single-crystal X-ray structure of 2(PF6)3 is presented. This complex displays four consecutive one-electron redox waves at +0.082, +0.31, +0.74, and +1.07 V vs Ag/AgCl. In each redox state, it shows significantly different NIR absorptions with λmax of 1590 nm for 24+, 1400 nm for 25+, 1060 nm for 26+, and 740 nm for 27+, respectively. Complex 24+ shows a single-line EPR signal at g = 2.060, while other redox states are all EPR inactive. The spin density distributions and NIR absorptions in different redox states were rationalized by DFT and TDDFT calculations. A vinyl-substituted triruthenium analogous 3(PF6)4 was prepared, which was successfully polymerized on ITO glass electrode surfaces by reductive electropolymerization. The obtained poly-3n+/ITO film was characterized by FTIR, AFM, and SEM analysis. It shows four well-defined redox couples and reversible multistate NIR electrochromism. In particular, a contrast ratio (ΔT%) up to 63% was achieved at the optic telecommunication wavelength (1550 nm).

Redox doping behaviour of poly(3,4-ethylenedithiothiophene) - The counterion effect

NASA Astrophysics Data System (ADS)

Domagala, Wojciech; Palutkiewicz, Dawid; Cortizo-Lacalle, Diego; Kanibolotsky, Alexander L.; Skabara, Peter J.

2011-07-01

Poly(3,4-ethylenedithiothiophene) - PEDTT, an alkylene sulphur derivative of PEDOT, presents itself as an interesting polymer with a number of disparate redox and chromic properties compared to its close analogue - PEDOT. In this study we present the results of an investigation into the electrochemical doping process of PEDTT, using four different electrolyte solutions, differing in anion content of the chosen salt. The results show that the anion identity plays a key role in the redox reactions accompanying these processes in what could be interpreted as anion ionochromism. In situ UV-Vis spectroelectrochemical experiments reveal an intriguing double electrochromic transition of PEDTT films during their oxidative doping, going from golden-yellow through green to pomegranate - a quality not so common within the family of electroactive conjugated polymers. The evolution of each UV-Vis spectrum over a potential range indicates that different redox states of the polymer are responsible for the chromatic changes. In the reduction half-cycle, the dedoping process of PEDTT appears to follow a path dissimilar to the p-doping one, featuring only one, direct electrochromic transition of the film's colour, bypassing the green state, and a distinct two-step bleaching process of doping-induced charge carrier bands. The observed electrochemical and spectral phenomena have been accredited to the specific redox behaviour of doping-induced radical cation and cationic defect states interacting with the dithioalkylene sulphur atom.

Electrolyte materials containing highly dissociated metal ion salts

DOEpatents

Lee, H.S.; Geng, L.; Skotheim, T.A.

1996-07-23

The present invention relates to metal ion salts which can be used in electrolytes for producing electrochemical devices, including both primary and secondary batteries, photoelectrochemical cells and electrochromic displays. The salts have a low energy of dissociation and may be dissolved in a suitable polymer to produce a polymer solid electrolyte or in a polar aprotic liquid solvent to produce a liquid electrolyte. The anion of the salts may be covalently attached to polymer backbones to produce polymer solid electrolytes with exclusive cation conductivity. 2 figs.

Novel high contrast electrochromic polymer materials based on 3,4-propylenedioxythiophene

NASA Astrophysics Data System (ADS)

Sahoo, Rabindra; Mishra, Sarada P.; Kumar, Anil; Sindhu, S.; Narasimha Rao, K.; Gopal, E. S. R.

2007-09-01

Mono and di allyl and napthyl substituted 3,4-propylenedioxythiophenes were synthesized and polymerized electrochemically. All the monomers were characterized for their molecular structures, and the polymers were characterized for their electrochemical properties. The disubstituted derivatives showed higher contrast than the corresponding mono substituted derivatives. The allyl substituted polymers showed higher contrast and faster switching time than corresponding napthyl substituted derivatives. The presence of the allyl group as the pendant can be used for further functionalization of the polymer.

34 CFR 685.208 - Repayment plans.

Code of Federal Regulations, 2013 CFR

2013-07-01

... amount may be adjusted to reflect changes in the variable interest rate identified in § 685.202(a). (c... be adjusted to reflect changes in the variable interest rate identified in § 685.202(a). (e) Extended... adjusted to reflect changes in the variable interest rate identified in § 685.202(a). (f) Graduated...

34 CFR 685.208 - Repayment plans.

Code of Federal Regulations, 2014 CFR

2014-07-01

... amount may be adjusted to reflect changes in the variable interest rate identified in § 685.202(a). (c... be adjusted to reflect changes in the variable interest rate identified in § 685.202(a). (e) Extended... adjusted to reflect changes in the variable interest rate identified in § 685.202(a). (f) Graduated...

Relation of agronomic and multispectral reflectance characteristics of spring wheat canopies

NASA Technical Reports Server (NTRS)

Bauer, M. E. (Principal Investigator); Ahlrichs, J. S.

1982-01-01

The relationships between crop canopy variables such as leaf area index (LAI) and their multispectral reflectance properties were investigated along with the potential for estimating canopy variables from remotely sensed reflectance measurements. Reflectance spectra over the 0.4 to 2.5 micron wavelength range were acquired during each of the major development stages of spring wheat canopies at Williston, North Dakota, during three seasons. Treatments included planting date, N fertilization, cultivar, and soil moisture. Agronomic measurements included development stage, biomass, LAI, and percent soil cover. High correlations were found between reflectance and percent cover, LAI, and biomass. A near infrared wavelength band, 0.76 to 0.90 microns, was most important in explaining variation in LAI and percent cover, while a middle infrared band, 2.08 to 2.35 microns, explained the most variation in biomass and plant water content. Transformations, including the near infrared/red reflectance ratio and greenness index, were also highly correlated to canopy variables. The relationship of canopy variables to reflectance decreased as the crop began to ripen. the canopy variables could be accurately predicted using measurements from three to five wavelength bands. The wavelength bands proposed for the thematic mapper sensor were more strongly related to the canopy variables than the LANDSAT MSS bands.

Organic-inorganic hybrid polymer electrolytes based on polyether diamine, alkoxysilane, and trichlorotriazine: Synthesis, characterization, and electrochemical applications

NASA Astrophysics Data System (ADS)

Saikia, Diganta; Wu, Cheng-Gang; Fang, Jason; Tsai, Li-Duan; Kao, Hsien-Ming

2014-12-01

A new type of highly conductive organic-inorganic hybrid polymer electrolytes has been synthesized by the reaction of poly(propylene glycol)-block-poly(ethylene glycol)-block-poly(propylene glycol) bis(2-aminopropyl ether), 2,4,6-trichloro-1,3,5-triazine and alkoxysilane precursor 3-(glycidyloxypropyl)trimethoxysilane, followed by doping of LiClO4. The 13C and 29Si solid-sate NMR results confirm the successful synthesis of the organic-inorganic hybrid structure. The solid hybrid electrolyte thus obtained exhibits a maximum ionic conductivity of 1.6 × 10-4 S cm-1 at 30 °C, which is the highest among the organic-inorganic hybrid electrolytes. The hybrid electrolytes are electrochemically stable up to 4.2 V. The prototype electrochromic device with such a solid hybrid electrolyte demonstrates a good coloration efficiency value of 183 cm2 C-1 with a cycle life over 200 cycles. For the lithium-ion battery test, the salt free solid hybrid membrane is swelled with a LiPF6-containing electrolyte solution to reach an acceptable ionic conductivity value of 6.5 × 10-3 S cm-1 at 30 °C. The battery cell carries an initial discharge capacity of 100 mAh g-1 at 0.2C-rate and a coulombic efficiency of about 95% up to 30 cycles without the sign of cell failure. The present organic-inorganic hybrid electrolytes hold promise for applications in electrochromic devices and lithium ion batteries.

Electrochromic enhancement of latent fingerprints by poly(3,4-ethylenedioxythiophene).

PubMed

Brown, Rachel M; Hillman, A Robert

2012-06-28

Spatially selective electrodeposition of poly-3,4-ethylenedioxythiophene (PEDOT) thin films on metallic surfaces is shown to be an effective means of visualizing latent fingerprints. The technique exploits the fingerprint deposit as an insulating mask, such that electrochemical processes (here, polymer deposition) may only take place on deposit-free areas of the surface between the ridges of the fingerprint deposit; the end result is a negative image of the fingermark. Use of a surfactant (sodium dodecylsulphate, SDS) to solubilise the EDOT monomer allows the use of an aqueous electrolyte. Electrochemical (coulometric) data provide a total assay of deposited material, yielding spatially averaged film thicknesses, which are commensurate with substantive filling of the trenches between fingerprint deposit ridges, but not overfilling to the extent that the ridge detail is covered. This is confirmed by optical microscopy and AFM images, which show continuous polymer deposition within the trenches and good definition at the ridge edges. Stainless steel substrates treated in this manner and transferred to background electrolyte (aqueous sulphuric acid) showed enhanced fingerprints when the contrast between the polymer background and fingerprint deposit was optimised using the electrochromic properties of the PEDOT films. The facility of the method to reveal fingerprints of various ages and subjected to plausible environmental histories was demonstrated. Comparison of this enhancement methodology with commonly used fingerprint enhancement methods (dusting with powder, application of wet powder suspensions and cyanoacrylate fuming) showed promising performance in selected scenarios of practical interest.

Effect of fluorine doping on highly transparent conductive spray deposited nanocrystalline tin oxide thin films

NASA Astrophysics Data System (ADS)

Moholkar, A. V.; Pawar, S. M.; Rajpure, K. Y.; Bhosale, C. H.; Kim, J. H.

2009-09-01

The undoped and fluorine doped thin films are synthesized by using cost-effective spray pyrolysis technique. The dependence of optical, structural and electrical properties of SnO 2 films, on the concentration of fluorine is reported. Optical absorption, X-ray diffraction, scanning electron microscope (SEM) and Hall effect studies have been performed on SnO 2:F (FTO) films coated on glass substrates. The film thickness varies from 800 to 1572 nm. X-ray diffraction pattern reveals the presence of cassiterite structure with (2 0 0) preferential orientation for FTO films. The crystallite size varies from 35 to 66 nm. SEM and AFM study reveals the surface of FTO to be made of nanocrystalline particles. The electrical study reveals that the films are degenerate and exhibit n-type electrical conductivity. The 20 wt% F doped film has a minimum resistivity of 3.8 × 10 -4 Ω cm, carrier density of 24.9 × 10 20 cm -3 and mobility of 6.59 cm 2 V -1 s -1. The sprayed FTO film having minimum resistance of 3.42 Ω/cm 2, highest figure of merit of 6.18 × 10 -2 Ω -1 at 550 nm and 96% IR reflectivity suggest, these films are useful as conducting layers in electrochromic and photovoltaic devices and also as the passive counter electrode.

Automotive applications of chromogenic materials

NASA Astrophysics Data System (ADS)

Lynam, Niall R.

1990-03-01

Automobiles present both opportunities and challenges for large-area chromogenics. Opportunities include optical and thermal control of vehicle glazing along with optical control of rearview mirrors and privacy glass. Challenges include cost-effectively meeting automotive safety, performance, and reliability standards. Worldwide automobile production' for 1987 is listed in Table 1. Of the roughly 33 million cars produced annually, approximately 8% are luxury models which are candidates for features such as auto- matically dimming rearview mirrors or variable opacity sunroofs. Thus copious commercial opportunities await whatever chromogenic technologies qualify for use in automobiles. This review will describe the performance, safety, and reliability/durability required for automotive use. Commercial opportunities and challenges will be discussed including cost factors and specifications. Chromogenic technologies such as electrochromism, liquid crystals and thermochromism will be reviewed in terms of how publicly announced technical developments match automotive needs and expectations. Construction and performance of ex- isting or imminent chromogenic devices will be described. Finally, how opportunities and challenges of the automotive environment translate to other applications for chromogenic materials such as architectural or information display devices will be discussed. The objective is to generally review the applications, the technologies appropriate to these applications, and the automotive chromogenic devices available at the time of writing to match these applications.

Electrochromic Glasses.

DTIC Science & Technology

1980-07-31

this glass and that dipole-dipole correlations contribute to the "ferroelectric-like" character of this amorphous system. The TeO2 -W03 glasses can only...shows the dielectric constant and Fig. I(b) glass from pure TeO2 ot pure WO. In addition, glass the tan 8 of the WO glass as a function of temperature... glasses containing WO, in various glass forming nitworks of LifO-B1O0, Na:O-BzO,, and TeO2 were prepared from reagent grade oxides at 800 C - 9SO C in

A Study of Colors in Lutetium Diphthalocyanine Electrochromic Displays.

DTIC Science & Technology

1982-10-01

34 TES CHAR OMM"OCP RESOWTIO M TETCHR IWA BEM" OF PMUK*4g63A IAA - ~ MICROCOP RESOLUTIO TES CHAR NMTID SUM OF STAOM-WA M" -- ---- I1. F L EIJ E4,U/ C...technology based on the rare-earth diphthalocyanine dyes offers exceptional promise for such applications.(’-𔃿) A film of a single compound within...slope of -180 m. Apparently three protons were added for each electron transferred to the dye. This could occur by formation of an addition compound with

Quantitative Targeted Proteomics and Electrochromic Shift for Measuring Photosystem Content of Marine Phytoplankton

NASA Astrophysics Data System (ADS)

Brown, C. M.; Bailleul, B.; Melanson, J. R.; Campbell, D. A.; Cockshutt, A. M.; Cardol, P.

2016-02-01

Abundance and stoichiometry data for the photosystems, the intersystem electron transport complexes and the Calvin cycle enzymes are rich in information about light and nutrient acclimation. Quantifying these complexes is essential for understanding limitations on and capacities for photosynthesis. Targeted quantitative immunodetections of conserved subunits (eg. PsbA for PSII; PsaC for PSI) are becoming an established method for absolute measurement of these complexes. An advantage of protein measurements is that they can be done with non-living flash-frozen samples and processed post-field. A pitfall of physical versus functional measures is that in some scenarios, such as during photoinhibition of photosystem II (PSII), physical and functional measures give different values, but such disparities are often meaningful, informing targeted studies of regulation, repair and enzyme kinetics. Electrochromic Shift (ECS) is an alternative, fast and noninvasive method which can be exploited to determine functional PSI:PSII ratios in living cells. The basis for ECS is that pigments in the photosynthetic membrane exhibit a shift in their absorption spectra when the electric component of the proton motive force is generated across the membrane in the light. Cross-validation of methods by independent measures builds confidence in results from both approaches and can be useful for ground truthing of underway or high-throughput optical measurements or functional measurements from bioassays. We present comparative data from immunoquantitation and ECS for an array of diatom taxa. The physical data fall within established ranges. The basis for similarities and disparities in the photosystem stoichiometries between the methods are discussed.

Facile Solution Synthesis of Tungsten Trioxide Doped with Nanocrystalline Molybdenum Trioxide for Electrochromic Devices.

PubMed

Hasani, Amirhossein; Le, Quyet Van; Nguyen, Thang Phan; Choi, Kyoung Soon; Sohn, Woonbae; Kim, Jang-Kyo; Jang, Ho Won; Kim, Soo Young

2017-10-16

A facile, highly efficient approach to obtain molybdenum trioxide (MoO 3 )-doped tungsten trioxide (WO 3 ) is reported. An annealing process was used to transform ammonium tetrathiotungstate [(NH 4 ) 2 WS 4 ] to WO 3 in the presence of oxygen. Ammonium tetrathiomolybdate [(NH 4 ) 2 MoS 4 ] was used as a dopant to improve the film for use in an electrochromic (EC) cell. (NH 4 ) 2 MoS 4 at different concentrations (10, 20, 30, and 40 mM) was added to the (NH 4 ) 2 WS 4 precursor by sonication and the samples were annealed at 500 °C in air. Raman, X-ray diffraction, and X-ray photoelectron spectroscopy measurements confirmed that the (NH 4 ) 2 WS 4 precursor decomposed to WO 3 and the (NH 4 ) 2 MoS 4 -(NH 4 ) 2 WS 4 precursor was transformed to MoO 3 -doped WO 3 after annealing at 500 °C. It is shown that the MoO 3 -doped WO 3 film is more uniform and porous than pure WO 3 , confirming the doping quality and the privileges of the proposed method. The optimal MoO 3 -doped WO 3 used as an EC layer exhibited a high coloration efficiency of 128.1 cm 2 /C, which is larger than that of pure WO 3 (74.5 cm 2 /C). Therefore, MoO 3 -doped WO 3 synthesized by the reported method is a promising candidate for high-efficiency and low-cost smart windows.

Ratiometric fluorescence measurements and imaging of the dipole potential in cell plasma membranes

NASA Astrophysics Data System (ADS)

Shynkar, Vasyl V.; Klymchenko, Andrey S.; Duportail, Guy; Demchenko, Alexander P.; Mély, Yves

2004-09-01

Development of fluorescence microscopic methods is limited by the application of new dyes, the response of which could be sensitive to different functional states in the living cells, and, in particular, to electrostatic potentials on their plasma membranes. Recently, we showed that newly designed 3-hydroxyflavone fluorescence dyes are highly electrochromic and show a strong two-band ratiometric response to electric dipole potential in lipid membranes. In the present report we extend these observations and describe a new generation of these dyes as electrochromic probes in biomembrane research. Modification of the membrane dipole potential was achieved by addition of 6-ketocholestanol (6-KC), cholesterol and phloretin. The dipole potential was also estimated by the reference probe di-8-ANEPPS. As an example, we show that on addition of 6-KC there occurs a dramatic change of the intensity ratio of the two emission bands, which is easily detected as a change of color. We describe in detail the applications of one of these dyes, PPZ8, to the studies of cells in suspension or attached to the glass surface. Confocal microscopy demonstrates strong preference of the probe for the cell plasma membrane, which allows us to apply this dye for studying electrostatic and other biomembrane properties. We demonstrate that the two-color response provides a direct and convenient way to measure the dipole potential in the plasma membrane. Applying PPZ8 in confocal microcopy and two-photon microspectroscopy allowed us to provide two-color imaging of the membrane dipole potential on the level of a single cell.

Fabrication of transparent conductive tri-composite film for electrochromic application

NASA Astrophysics Data System (ADS)

Choi, Dahyun; Lee, Minji; Kim, Hyungsub; Chu, Won-shik; Chun, Doo-man; Ahn, Sung-Hoon; Lee, Caroline Sunyong

2017-12-01

A transparent conductive electrode (TCE) based on poly(3,4-ethylenedioxythiophene):poly(styrenesulfonate) (PEDOT:PSS) was developed using a dry deposition method for application as an electrochromic (EC) device. To improve its electrical conductivity and stable EC performance, AgNW and TiO2 nanoparticles were included in the TCE film. The resulting TiO2/AgNW/PEDOT:PSS hybrid film showed electrical sheet resistivity of 23 Ω/sq., similar to that of a commercial TCE film. When +2.0 V was applied to the hybrid film, the response current was stable, maintaining a value of 2.0 mA. We found that the hybrid film could be used as an EC device, without using commercial TCE film. Antimony-doped tin oxide on indium-doped tin oxide-glass as an ion-storage layer was combined with the hybrid film, with 1-ethyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide (EMIM-TFSI) injected into the EC device as an ionic liquid electrolyte. The optical transmittance difference between the colored and bleached states was 23% at 630 nm; under applied voltages of -2.0 V and +2.0 V, the coloration efficiency was 127.83 cm2/C. Moreover, cyclic transmittance with switching voltage for 3 h showed stable optical transmittance of 31% at 630 nm. Cyclic voltammetry measurements indicated stable behavior over 50 cycles. Thus, the proposed TCE configuration (TiO2/AgNW/PEDOT:PSS) shows great potential as a substitute for commercial TCEs, the cost of which depends on the availability of rare-earth materials.

New solely Prussian-blue EC configurations

NASA Astrophysics Data System (ADS)

Rosseinsky, David R.; Soutar, Andrew M.; Annergren, Ingegerd F.; Glidle, Andrew

2001-11-01

The long-established ferric ferrocyanide chromophore Prussian Blue (PB) has often been studied for electrochromic use. New observations and conclusions are now presented. Detailed analyses, chemical and by means of EDX, of films deposited on Pt in a variety of conditions and solution compositions, are presented, and a remarkably efficient uptake of Cs+ noted. In particular, the pH for stablest film from KCl- containing solution should be high, ca 4-5. Details of the electrodeposition on ITO glass were examined, where earlier suppositions regarding the nature of the foundation layers are confirmed by direct observation. Unexpectedly, this is substantially of ferric-ferricyanide composition. The spectroscopic shifts of the intervalence charge-transfer absorption on incorporation of different univalent cations into PB are reported and analysed. The preparative precautions needed for deposition on larger (10 x 10 cm2) ITO glass electrodes are thoroughly examined. The electrochromic response of a dual-PB electrode setup in which one electrode can be switched to clear Prussian White and the other to the deep yellow of Prussian Yellow, presents an unlikely prospect for windows or other intensity-attenuation applications, but may serve e.g. in displays. In an alternative dual-PB array a metallic silver electrode is peripherally interposed, to act as a silver/silver- chloride counter electrode. The response time in the 10 x 10 cm2 system is approximately 90 s and is accompanied by a pronounced iris (racoon) effect. The assembly provides an interesting example of two-electrode operation of a larger (cf lab-scale) device. Two-electrode operation is discussed and clarified.

Efficient synthesis of tungsten oxide hydrate-based nanocomposites for applications in bifunctional electrochromic-energy storage devices

NASA Astrophysics Data System (ADS)

Chang, Xueting; Hu, Ruirui; Sun, Shibin; Lu, Tong; Liu, Tao; Lei, Yanhua; Dong, Lihua; Yin, Yansheng; Zhu, Yanqiu

2018-05-01

In this work, we realized the large-scale synthesis of WO3 · H2O nanoflakes (NFs), g-C3N4/WO3 · H2O nanocomposite (NC) and graphene (G)/WO3 · H2O NC via a sonochemical process with tungsten salt as the precursor, g-C3N4 or G sheets as the supports, and distilled water as the solvent. Both the g-C3N4/WO3 · H2O NC and G/WO3 · H2O NC exhibited much better electrochromic (EC) performance (higher coloration efficiencies and faster response times) than that of the WO3 · H2O NFs. Using the WO3 · H2O-based materials as electrode materials, EC batteries that integrate the energy storage and EC functions in one device have been assembled. The energy status of the EC batteries could be visually indicated by the reversible color variations. Compared with the plain WO3 · H2O-based EC batteries, the NC-based EC batteries possessed a lower color contrast between the charged and discharged conditions but much longer discharge durations. The EC batteries could be quickly charged in a few seconds by adding H2O2, and the charged batteries exhibited significantly-enhanced discharging durations in comparison with the initial ones. The g-C3N4/WO3 · H2O NC-EC batteries charged by a small amount of H2O2 could produce a long discharging duration up to 760 min.

Integrated MEMS-based variable optical attenuator and 10Gb/s receiver

NASA Astrophysics Data System (ADS)

Aberson, James; Cusin, Pierre; Fettig, H.; Hickey, Ryan; Wylde, James

2005-03-01

MEMS devices can be successfully commercialized in favour of competing technologies only if they offer an advantage to the customer in terms of lower cost or increased functionality. There are limited markets where MEMS can be manufactured cheaper than similar technologies due to large volumes: automotive, printing technology, wireless communications, etc. However, success in the marketplace can also be realized by adding significant value to a system at minimal cost or leverging MEMS technology when other solutions simply will not work. This paper describes a thermally actuated, MEMS based, variable optical attenuator that is co-packaged with existing opto-electronic devices to develop an integrated 10Gb/s SONET/SDH receiver. The configuration of the receiver opto-electronics and relatively low voltage availability (12V max) in optical systems bar the use of LCD, EO, and electro-chromic style attenuators. The device was designed and fabricated using a silicon-on-insulator (SOI) starting material. The design and performance of the device (displacement, power consumption, reliability, physical geometry) was defined by the receiver parameters geometry. This paper will describe how these design parameters (hence final device geometry) were determined in light of both the MEMS device fabrication process and the receiver performance. Reference will be made to the design tools used and the design flow which was a joint effort between the MEMS vendor and the end customer. The SOI technology offered a robust, manufacturable solution that gave the required performance in a cost-effective process. However, the singulation of the devices required the development of a new singulation technique that allowed large volumes of silicon to be removed during fabrication yet still offer high singulation yields.

Relation between lung function, exercise capacity, and exposure to asbestos cement.

PubMed Central

Wollmer, P; Eriksson, L; Jonson, B; Jakobsson, K; Albin, M; Skerfving, S; Welinder, H

1987-01-01

A group of 137 male workers with known exposure (mean 20 fibre years per millilitre) to asbestos cement who had symptoms or signs of pulmonary disease was studied together with a reference group of 49 healthy industrial workers with no exposure to asbestos. Lung function measurements were made at rest and during exercise. Evidence of lung fibrosis was found as well as of obstructive airways disease in the exposed group compared with the reference group. Asbestos cement exposure was related to variables reflecting lung fibrosis but not to variables reflecting airflow obstruction. Smoking was related to variables reflecting obstructive lung disease. Exercise capacity was reduced in the exposed workers and was related to smoking and to lung function variables, reflecting obstructive airways disease. There was no significant correlation between exercise capacity and exposure to asbestos cement. PMID:3651353

Improved Electrochemical Cycling Durability in a Nickel Oxide Double-Layered Film.

PubMed

Hou, Shuai; Zhang, Xiang; Tian, Yanlong; Zhao, Jiupeng; Geng, Hongbin; Qu, Huiying; Zhang, Hangchuan; Zhang, Kun; Wang, Binsheng; Gavrilyuk, Alexander; Li, Yao

2017-11-16

For the first time, a crystalline-amorphous double-layered NiO x film has been prepared by reactive radio frequency magnetron sputtering. This film has exhibited improved electrochemical cycling durability, whereas other electrochromic parameters have been maintained at the required level, namely, a short coloration/bleaching time (0.8 s/1.1 s) and an enhanced transmittance modulation range (62.2 %) at λ=550 nm. Additionally, the double-layered film has shown better reversibility than that of amorphous and crystalline single-layered films. © 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

Evaluation of 3D printed optofluidic smart glass prototypes.

PubMed

Wolfe, Daniel; Goossen, K W

2018-01-22

Smart glass or smart windows are an innovative technology used for thermal management, energy efficiency, and privacy applications. Notable commercially available smart glass relies on an electric stimuli to modulate the glass from a transparent to a translucent mode of operation. However, the current market technologies, such as electrochromic, polymer dispersed liquid crystal, and suspended particle devices are expensive and suffer from solar absorption, poor transmittance modulation, and in some cases, continuous power consumption. The authors of this paper present a novel optofluidic smart glass prototype capable of modulating visible light transmittance from 8% to 85%.

Electrode with transparent series resistance for uniform switching of optical modulation devices

DOEpatents

Tench, D Morgan [Camarillo, CA; Cunningham, Michael A [Thousand Oaks, CA; Kobrin, Paul H [Newbury Park, CA

2008-01-08

Switching uniformity of an optical modulation device for controlling the propagation of electromagnetic radiation is improved by use of an electrode comprising an electrically resistive layer that is transparent to the radiation. The resistive layer is preferably an innerlayer of a wide-bandgap oxide sandwiched between layers of indium tin oxide or another transparent conductor, and may be of uniform thickness, or may be graded so as to provide further improvement in the switching uniformity. The electrode may be used with electrochromic and reversible electrochemical mirror (REM) smart window devices, as well as display devices based on various technologies.

Thin Rechargeable Batteries for CMOS SRAM Memory Protection

NASA Technical Reports Server (NTRS)

Crouse, Dennis N.

1993-01-01

New rechargeable battery technology is described and compared with classical primary battery back-up of SRAM PC cards. Thin solid polymer electrolyte cells with the thickness of TSOP memory components (1 mm nominal, 1.1 mm max) and capacities of 14 mAh/sq cm can replace coin cells. The SRAM PC cards with permanently installed rechargeable cells and optional electrochromic low battery voltage indicators will free the periodic PC card user from having to 'feed' their PC cards with coin cells and will allow a quick visual check of stored cards for their battery voltage status.

Programmable Analog Memory Resistors For Electronic Neural Networks

NASA Technical Reports Server (NTRS)

Ramesham, Rajeshuni; Thakoor, Sarita; Daud, Taher; Thakoor, Anilkumar P.

1990-01-01

Electrical resistance of new solid-state device altered repeatedly by suitable control signals, yet remains at steady value when control signal removed. Resistance set at low value ("on" state), high value ("off" state), or at any convenient intermediate value and left there until new value desired. Circuits of this type particularly useful in nonvolatile, associative electronic memories based on models of neural networks. Such programmable analog memory resistors ideally suited as synaptic interconnects in "self-learning" neural nets. Operation of device depends on electrochromic property of WO3, which when pure is insulator. Potential uses include nonvolatile, erasable, electronically programmable read-only memories.

Continuous ECS-indicated recording of the proton-motive charge flux in leaves.

PubMed

Klughammer, Christof; Siebke, Katharina; Schreiber, Ulrich

2013-11-01

Technical features and examples of application of a special emitter-detector module for highly sensitive measurements of the electrochromic pigment absorbance shift (ECS) via dual-wavelength (550-520 nm) transmittance changes (P515) are described. This device, which has been introduced as an accessory of the standard, commercially available Dual-PAM-100 measuring system, not only allows steady-state assessment of the proton motive force (pmf) and its partitioning into ΔpH and ΔΨ components, but also continuous recording of the overall charge flux driven by photosynthetic light reactions. The new approach employs a double-modulation technique to derive a continuous signal from the light/dark modulation amplitude of the P515 signal. This new, continuously measured signal primarily reflects the rate of proton efflux via the ATP synthase, which under quasi-stationary conditions corresponds to the overall rate of proton influx driven by coupled electron transport. Simultaneous measurements of charge flux and CO2 uptake as a function of light intensity indicated a close to linear relationship in the light-limited range. A linear relationship between these two signals was also found for different internal CO2 concentrations, except for very low CO2, where the rate of charge flux distinctly exceeded the rate of CO2 uptake. Parallel oscillations in CO2 uptake and charge flux were induced by high CO2 and O2. The new device may contribute to the elucidation of complex regulatory mechanisms in intact leaves.

Interpreting vegetation reflectance measurements as a function of solar zenith angle

NASA Technical Reports Server (NTRS)

Kimes, D. S.; Smith, J. A.; Ranson, K. J.

1979-01-01

Spectral hemispherical-conical reflectances of a nadir looking sensor were taken throughout the day for a lodgepole pine and two grass canopies. Mathematical simulations of both spectral hemispherical-conical and bi-hemispherical reflectances were performed for two theoretical canopies of contrasting geometric structure. These results and comparisons with literature studies showed a great amount of variability of vegetation canopy reflectances as a function of solar zenith angle. Explanations for this variability are discussed and recommendations for further measurements are proposed.

Electric-field control of tri-state phase transformation with a selective dual-ion switch

NASA Astrophysics Data System (ADS)

Lu, Nianpeng; Zhang, Pengfei; Zhang, Qinghua; Qiao, Ruimin; He, Qing; Li, Hao-Bo; Wang, Yujia; Guo, Jingwen; Zhang, Ding; Duan, Zheng; Li, Zhuolu; Wang, Meng; Yang, Shuzhen; Yan, Mingzhe; Arenholz, Elke; Zhou, Shuyun; Yang, Wanli; Gu, Lin; Nan, Ce-Wen; Wu, Jian; Tokura, Yoshinori; Yu, Pu

2017-06-01

Materials can be transformed from one crystalline phase to another by using an electric field to control ion transfer, in a process that can be harnessed in applications such as batteries, smart windows and fuel cells. Increasing the number of transferrable ion species and of accessible crystalline phases could in principle greatly enrich material functionality. However, studies have so far focused mainly on the evolution and control of single ionic species (for example, oxygen, hydrogen or lithium ions). Here we describe the reversible and non-volatile electric-field control of dual-ion (oxygen and hydrogen) phase transformations, with associated electrochromic and magnetoelectric effects. We show that controlling the insertion and extraction of oxygen and hydrogen ions independently of each other can direct reversible phase transformations among three different material phases: the perovskite SrCoO3-δ (ref. 12), the brownmillerite SrCoO2.5 (ref. 13), and a hitherto-unexplored phase, HSrCoO2.5. By analysing the distinct optical absorption properties of these phases, we demonstrate selective manipulation of spectral transparency in the visible-light and infrared regions, revealing a dual-band electrochromic effect that could see application in smart windows. Moreover, the starkly different magnetic and electric properties of the three phases—HSrCoO2.5 is a weakly ferromagnetic insulator, SrCoO3-δ is a ferromagnetic metal, and SrCoO2.5 is an antiferromagnetic insulator—enable an unusual form of magnetoelectric coupling, allowing electric-field control of three different magnetic ground states. These findings open up opportunities for the electric-field control of multistate phase transformations with rich functionalities.

RF Magnetron Sputtering Deposited W/Ti Thin Film For Smart Window Applications

NASA Astrophysics Data System (ADS)

Oksuz, Lutfi; Kiristi, Melek; Bozduman, Ferhat; Uygun Oksuz, Aysegul

2014-10-01

Electrochromic (EC) devices can change reversible and persistent their optical properties in the visible region (400-800 nm) upon charge insertion/extraction according to the applied voltage. A complementary type EC is a device containing two electrochromic layers, one of which is anodically colored such as vanadium oxide (V2 O5) while the other cathodically colored such as tungsten oxide (WO3) which is separated by an ionic conduction layer (electrolyte). The use of a solid electrolyte such as Nafion eliminates the need for containment of the liquid electrolyte, which simplifies the cell design, as well as improves safety and durability. In this work, the EC device was fabricated on a ITO/glass slide. The WO3-TiO2 thin film was deposited by reactive RF magnetron sputtering using a 2-in W/Ti (9:1%wt) target with purity of 99.9% in a mixture gas of argon and oxygen. As a counter electrode layer, V2O5 film was deposited on an ITO/glass substrate using V2O3 target with the same conditions of reactive RF magnetron sputtering. Modified Nafion was used as an electrolyte to complete EC device. The transmittance spectra of the complementary EC device was measured by optical spectrophotometry when a voltage of +/-3 V was applied to the EC device by computer controlled system. The surface morphology of the films was characterized by scanning electron microscopy (SEM) and atomic force microscopy (AFM) (Fig. 2). The cyclic voltammetry (CV) for EC device was performed by sweeping the potential between +/-3 V at a scan rate of 50 mV/s.

Spectral engineering in π-conjugated polymers with intramolecular donor-acceptor interactions.

PubMed

Beaujuge, Pierre M; Amb, Chad M; Reynolds, John R

2010-11-16

With the development of light-harvesting organic materials for solar cell applications and molecular systems with fine-tuned colors for nonemissive electrochromic devices (e.g., smart windows, e-papers), a number of technical challenges remain to be overcome. Over the years, the concept of "spectral engineering" (tailoring the complex interplay between molecular physics and the various optical phenomena occurring across the electromagnetic spectrum) has become increasingly relevant in the field of π-conjugated organic polymers. Within the spectral engineering toolbox, the "donor-acceptor" approach uses alternating electron-rich and electron-deficient moieties along a π-conjugated backbone. This approach has proved especially valuable in the synthesis of dual-band and broadly absorbing chromophores with useful photovoltaic and electrochromic properties. In this Account, we highlight and provide insight into a present controversy surrounding the origin of the dual band of absorption sometimes encountered in semiconducting polymers structured using the "donor-acceptor" approach. Based on empirical evidence, we provide some schematic representations to describe the possible mechanisms governing the evolution of the two-band spectral absorption observed on varying the relative composition of electron-rich and electron-deficient substituents along the π-conjugated backbone. In parallel, we draw attention to the choice of the method employed to estimate and compare the absorption coefficients of polymer chromophores exhibiting distinct repeat unit lengths, and containing various extents of solubilizing side-chains along their backbone. Finally, we discuss the common assumption that "donor-acceptor" systems should have systematically lower absorption coefficients than their "all-donor" counterparts. The proposed models point toward important theoretical parameters which could be further explored at the macromolecular level to help researchers take full advantage of the complex interactions taking place in π-conjugated polymers with intramolecular "donor-acceptor" characteristics.

Use of electrochromic materials in adaptive optics.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kammler, Daniel R.; Sweatt, William C.; Verley, Jason C.

Electrochromic (EC) materials are used in 'smart' windows that can be darkened by applying a voltage across an EC stack on the window. The associated change in refractive index (n) in the EC materials might allow their use in tunable or temperature-insensitive Fabry-Perot filters and transmissive-spatial-light-modulators (SLMs). The authors are conducting a preliminary evaluation of these materials in many applications, including target-in-the-loop systems. Data on tungsten oxide, WO{sub 3}, the workhorse EC material, indicate that it's possible to achieve modest changes in n with only slight increases in absorption between the visible and {approx}10 {micro}m. This might enable construction ofmore » a tunable Fabry-Perot filter consisting of an active EC layer (e.g. WO{sub 3}) and a proton conductor (e.g.Ta{sub 2}O{sub 5}) sandwiched between two gold electrodes. A SLM might be produced by replacing the gold with a transparent conductor (e.g. ITO). This SLM would allow broad-band operation like a micromirror array. Since it's a transmission element, simple optical designs like those in liquid-crystal systems would be possible. Our team has fabricated EC stacks and characterized their switching speed and optical properties (n, k). We plan to study the interplay between process parameters, film properties, and performance characteristics associated with the FP-filter and then extend what we learn to SLMs. Our goals are to understand whether the changes in absorption associated with changes in n are acceptable, and whether it's possible to design an EC-stack that's fast enough to be interesting. We'll present our preliminary findings regarding the potential viability of EC materials for target-in-the-loop applications.« less

Bio-inspired materials for electrochemical devices

NASA Astrophysics Data System (ADS)

Pawlicka, A.; Firmino, A.; Sentanin, F.; Sabadini, R. C.; Jimenez, D. E. Q.; Jayme, C. C.; Mindroiu, M.; Zgarian, R. G.; Tihan, G. T.; Rau, I.; Silva, M. M.; Nogueira, A. F.; Kanicki, J.; Kajzar, F.

2015-10-01

Natural macromolecules are very promising row materials to be used in modern technology including security and defense. They are abundant in nature, easy to extract and possess biocompatibility and biodegradability properties. These materials can be modified throughout chemical or physical processes, and can be doped with lithium and rare earth salts, ionic liquids, organic and inorganic acids. In this communication samples of DNA and modified DNA were doped with Prussian Blue (PB), poly(ethylene dioxythiophene) (PEDOT), europium and erbium triflate and organic dyes such as Nile Blue (NB), Disperse Red 1 (DR1) and Disperse Orange 3 (DO3). The colored or colorless membranes were characterized by electrochemical and spectroscopic measurements, and they were applied in electrochromic devices (ECDs) and dye sensitized solar cells (DSSC). ECDs change the color under applied potential, so they can modulate the intensity of transmitted light of 15 to 35%. As the electrochromic materials, WO3 or Prussian blue (PB), are usually blue colored, the color change is from transparent to blue. DNA, and the complexes: DNA-CTMA, DNA-DODA and DNAPEDOT: PSS were also investigated as either hole carrier material (HTM) or polymer electrolyte in dye-sensitized solar cells (DSSC). The DNA-based samples as HTM in small DSSCs revealed a solar energy conversion efficiency of 0.56%. Polymer electrolytes of DNA-CTMA and DNA-DODA, both with 10 wt% of LiI/I2, applied in small DSSC, exhibited the efficiencies of 0.18 and 0.66%, respectively. The obtained results show that natural macromolecules-based membranes are not only environmentally friendly but are also promising materials to be investigated for several electrochemical devices. However, to obtain better performances more research is still needed.

Synthesis and characterization of mesoporous materials

NASA Astrophysics Data System (ADS)

Cheng, Wei

Mesoporous materials are highly porous solids with pore sizes in the range of 20 to 500 A and a narrow pore size distribution. Creating a mesoporous morphology in transition metal oxides is expected to increase the kinetics of electrochemical photoelectrochemical processes due to the improved accessibility of electrolyte to electrode. The objective of the dissertation research is to prepare functional mesoporous materials based on transition metal oxides and to determine the effects of the mesoporous structure on the resulting charge transfer, electrochromism, and optical properties. In this dissertation, mesoporous tungsten oxide and niobium oxide were synthesized by incorporating tri-block copolymer surfactant templates into the sol-gel synthesis procedure. Both mesoporous materials have surface areas in the range of 130 m2/g with a narrow pore size distribution centered at ˜45A. Their electrochromic properties were characterized and found to be strongly influenced by the mesoporous morphology. Both mesoporous systems exhibit better electrochemical and optical reversibilities than the analogous sol-gel materials (without using surfactant) and the kinetics of bleaching is substantially faster. Coloration efficiencies for the mesoporous tungsten oxide and niobium oxide films are in the range of 16--37 cm 2/C and 12--16 cm2/C, respectively. Dye sensitized solar cells (DSSC) were fabricated using mesoporous niobium oxide as electrodes. Due to the higher surface area, the mesoporous electrodes have greater dye adsorption and electrolyte penetration compared to sol-gel electrodes, which leads to better electron injection, faster dye regeneration and thus, better cell performance. The mesoporous DSSC exhibits photocurrents of 2.9 mA and fill factors of 0.61. Open circuit voltages of the mesoporous DSSC are in the range of 0.6--0.83V.

Connectivity of the intracytoplasmic membrane of Rhodobacter sphaeroides: a functional approach.

PubMed

Verméglio, André; Lavergne, Jérôme; Rappaport, Fabrice

2016-01-01

The photosynthetic apparatus in the bacterium Rhodobacter sphaeroides is mostly present in intracytoplasmic membrane invaginations. It has long been debated whether these invaginations remain in topological continuity with the cytoplasmic membrane, or form isolated chromatophore vesicles. This issue is revisited here by functional approaches. The ionophore gramicidin was used as a probe of the relative size of the electro-osmotic units in isolated chromatophores, spheroplasts, or intact cells. The decay of the membrane potential was monitored from the electrochromic shift of carotenoids. The half-time of the decay induced by a single channel in intact cells was about 6 ms, thus three orders of magnitude slower than in isolated chromatophores. In spheroplasts obtained by lysis of the cell wall, the single channel decay was still slower (~23 ms) and the sensitivity toward the gramicidin concentration was enhanced 1,000-fold with respect to isolated chromatophores. These results indicate that the area of the functional membrane in cells or spheroplasts is about three orders of magnitude larger than that of isolated chromatophores. Intracytoplasmic vesicles, if present, could contribute to at most 10% of the photosynthetic apparatus in intact cells of Rba. sphaeroides. Similar conclusions were obtained from the effect of a ∆pH-induced diffusion potential in intact cells. This caused a large electrochromic response of carotenoids, of similar amplitude as the light-induced change, indicating that most of the system is sensitive to a pH change of the external medium. A single internal membrane and periplasmic space may offer significant advantages concerning renewal of the photosynthetic apparatus and reallocation of the components shared with other bioenergetic pathways.

Spectral variability of sea surface skylight reflectance and its effect on ocean color.

PubMed

Cui, Ting-Wei; Song, Qing-Jun; Tang, Jun-Wu; Zhang, Jie

2013-10-21

In this study, sea surface skylight spectral reflectance ρ(λ) was retrieved by means of the non-linear spectral optimization method and a bio-optical model. The spectral variability of ρ(λ) was found to be mainly influenced by the uniformity of the incident skylight, and a model is proposed to predict the ρ(λ) spectral dependency based on skylight reflectance at 750 nm. It is demonstrated that using the spectrally variable ρ(λ), rather than a constant, yields an improved agreement between the above-water remote sensing reflectance R(rs)(λ) estimates and concurrent profiling ones. The findings of this study highlight the necessity to re-process the relevant historical above-water data and update ocean color retrieval algorithms accordingly.

Study of the Variability of the Reflection Component in Seyfert 1 Galaxies: Connecting the Fe K Variability with the Compton Hump

NASA Astrophysics Data System (ADS)

Ponti, G.; Miniutti, G.; Malaguti, G.; Gallo, L.; Goldwurm, A.

2009-05-01

We present preliminary results of an ongoing project devoted to the study of the continuum and Fe K band variability in a sample of bright AGNs. These kind of studies may break the spectral degeneracy between the different absorption/emission models, allowing ``safe'' measurements of the disc and black hole properties from the broad line shapes. In fact, the Fe K band, alone, allows a first separation between the different components. Here we show the case of NGC 3783 which shows both a constant and a variable reflection component as well as strong ionized absorption. We show that a fundamental contribution will be given by Simbol-X that will allow to simultaneously measure not only the Fe K variability, but also the connected reflection hump variations.

Variable frequency microwave heating apparatus

DOEpatents

Bible, Don W.; Lauf, Robert J.; Johnson, Arvid C.; Thigpen, Larry T.

1999-01-01

A variable frequency microwave heating apparatus (10) designed to allow modulation of the frequency of the microwaves introduced into a multi-mode microwave cavity (34) for testing or other selected applications. The variable frequency microwave heating apparatus (10) includes a microwave signal generator (12) and a high-power microwave amplifier (20) or a high-power microwave oscillator (14). A power supply (22) is provided for operation of the high-power microwave oscillator (14) or microwave amplifier (20). A directional coupler (24) is provided for detecting the direction and amplitude of signals incident upon and reflected from the microwave cavity (34). A first power meter (30) is provided for measuring the power delivered to the microwave furnace (32). A second power meter (26) detects the magnitude of reflected power. Reflected power is dissipated in the reflected power load (28).

Coronal Mass Ejection early-warning mission by solar-photon sailcraft

NASA Astrophysics Data System (ADS)

Vulpetti, Giovanni; Circi, Christian; Pino, Tommaso

2017-11-01

A preliminary investigation of the early warning of solar storms caused by Coronal Mass Ejection has been carried out. A long warning time could be obtained with a sailcraft synchronous with the Earth-Moon barycenter, and stationed well below the L1 point. In this paper, the theory of heliocentric synchronous sailcraft is set up, its perturbed orbit is analyzed, and a potential solution capable of providing an annual synchrony is carried out. A simple analysis of the response from a low-mass electrochromic actuator for the realization of station-keeping attitude maneuvers is put forwards, and an example of propellantless re-orientation maneuver is studied.

Method for filling the cavities of cells with a chromogenic fluid

DOEpatents

Tonazzi, J.C.L.; Kucharczyk, J.E. Jr.; Agrawal, A.

1999-01-05

A method and apparatus are disclosed for filling a cell cavity positioned between a first substrate and a second substrate with a cell filling liquid. The method entails forming at least one evacuation cavity encompassing at least a portion of an outer surface of each of the first and second substrates of a cell containing a cell cavity and isolating the cell cavity from the evacuation cavity; reducing a pressure in each of the evacuation cavity and the cell cavity; and dispensing the cell filling fluid into the cell cavity. The application is to the fabrication of electrochromic windows. 22 figs.

VARIABLE TIME DELAY MEANS

DOEpatents

Clemensen, R.E.

1959-11-01

An electrically variable time delay line is described which may be readily controlled simuitaneously with variable impedance matching means coupied thereto such that reflections are prevented. Broadly, the delay line includes a signal winding about a magnetic core whose permeability is electrically variable. Inasmuch as the inductance of the line varies directly with the permeability, the time delay and characteristic impedance of the line both vary as the square root of the permeability. Consequently, impedance matching means may be varied similariy and simultaneously w:th the electrically variable permeability to match the line impedance over the entire range of time delay whereby reflections are prevented.

X-Ray Quasi-periodic Oscillations in the Lense–Thirring Precession Model. I. Variability of Relativistic Continuum

NASA Astrophysics Data System (ADS)

You, Bei; Bursa, Michal; Życki, Piotr T.

2018-05-01

We develop a Monte Carlo code to compute the Compton-scattered X-ray flux arising from a hot inner flow that undergoes Lense–Thirring precession. The hot flow intercepts seed photons from an outer truncated thin disk. A fraction of the Comptonized photons will illuminate the disk, and the reflected/reprocessed photons will contribute to the observed spectrum. The total spectrum, including disk thermal emission, hot flow Comptonization, and disk reflection, is modeled within the framework of general relativity, taking light bending and gravitational redshift into account. The simulations are performed in the context of the Lense–Thirring precession model for the low-frequency quasi-periodic oscillations, so the inner flow is assumed to precess, leading to periodic modulation of the emitted radiation. In this work, we concentrate on the energy-dependent X-ray variability of the model and, in particular, on the evolution of the variability during the spectral transition from hard to soft state, which is implemented by the decrease of the truncation radius of the outer disk toward the innermost stable circular orbit. In the hard state, where the Comptonizing flow is geometrically thick, the Comptonization is weakly variable with a fractional variability amplitude of ≤10% in the soft state, where the Comptonizing flow is cooled down and thus becomes geometrically thin, the fractional variability of the Comptonization is highly variable, increasing with photon energy. The fractional variability of the reflection increases with energy, and the reflection emission for low spin is counterintuitively more variable than the one for high spin.

The variability puzzle in human memory.

PubMed

Kahana, Michael J; Aggarwal, Eash V; Phan, Tung D

2018-04-26

Memory performance exhibits a high level of variability from moment to moment. Much of this variability may reflect inadequately controlled experimental variables, such as word memorability, past practice and subject fatigue. Alternatively, stochastic variability in performance may largely reflect the efficiency of endogenous neural processes that govern memory function. To help adjudicate between these competing views, the authors conducted a multisession study in which subjects completed 552 trials of a delayed free-recall task. Applying a statistical model to predict variability in each subject's recall performance uncovered modest effects of word memorability, proactive interference, and other variables. In contrast to the limited explanatory power of these experimental variables, performance on the prior list strongly predicted current list recall. These findings suggest that endogenous factors underlying successful encoding and retrieval drive variability in performance. (PsycINFO Database Record (c) 2018 APA, all rights reserved).

Transparent anodic TiO2 nanotube arrays on plastic substrates for disposable biosensors and flexible electronics.

PubMed

Farsinezhad, Samira; Mohammadpour, Arash; Dalrymple, Ashley N; Geisinger, Jared; Kar, Piyush; Brett, Michael J; Shankar, Karthik

2013-04-01

Exploitation of anodically formed self-organized TiO2 nanotube arrays in mass-manufactured, disposable biosensors, rollable electrochromic displays and flexible large-area solar cells would greatly benefit from integration with transparent and flexible polymeric substrates. Such integration requires the vacuum deposition of a thin film of titanium on the desired substrate, which is then anodized in suitable media to generate TiO2 nanotube arrays. However the challenges associated with control of Ti film morphology, nanotube array synthesis conditions, and film adhesion and transparency, have necessitated the use of substrate heating during deposition to temperatures of at least 300 degrees C and as high as 500 degrees C to generate highly ordered open-pore nanotube arrays, thus preventing the use of polymeric substrates. We report on a film growth technique that exploits atomic peening to achieve high quality transparent TiO2 nanotube arrays with lengths up to 5.1 microm at room temperature on polyimide substrates without the need for substrate heating or substrate biasing or a Kauffman ion source. The superior optical quality and uniformity of the nanotube arrays was evidenced by the high specular reflectivity and the smooth pattern of periodic interferometric fringes in the transmission spectra of the nanotube arrays, from which the wavelength-dependent effective refractive index was extracted for the air-TiO2 composite medium. A fluorescent immunoassay biosensor constructed using 5.1 microm-long transparent titania nanotube arrays (TTNAs) grown on Kapton substrates detected human cardiac troponin I at a concentration of 0.1 microg ml(-1).

The Nustar Spectrum of Mrk 335: Extreme Relativistic Effects Within Two Gravitational Radii of the Event Horizon?

NASA Technical Reports Server (NTRS)

Parker, M. L.; Wilkins, D. R.; Fabian, A. C.; Grupe, D.; Dauser, T.; Matt, G.; Harrison, F. A.; Brenneman, L.; Boggs, S. E.; Christensen, F. E.;

All printed touchless human-machine interface based on only five functional materials

NASA Astrophysics Data System (ADS)

Scheipl, G.; Zirkl, M.; Sawatdee, A.; Helbig, U.; Krause, M.; Kraker, E.; Andersson Ersman, P.; Nilsson, D.; Platt, D.; Bodö, P.; Bauer, S.; Domann, G.; Mogessie, A.; Hartmann, Paul; Stadlober, B.

2012-02-01

We demonstrate the printing of a complex smart integrated system using only five functional inks: the fluoropolymer P(VDF:TrFE) (Poly(vinylidene fluoride trifluoroethylene) sensor ink, the conductive polymer PEDOT:PSS (poly(3,4 ethylenedioxythiophene):poly(styrene sulfonic acid) ink, a conductive carbon paste, a polymeric electrolyte and SU8 for separation. The result is a touchless human-machine interface, including piezo- and pyroelectric sensor pixels (sensitive to pressure changes and impinging infrared light), transistors for impedance matching and signal conditioning, and an electrochromic display. Applications may not only emerge in human-machine interfaces, but also in transient temperature or pressure sensing used in safety technology, in artificial skins and in disposable sensor labels.

Size Dependent Cation Channel in Nanoporous Prussian Blue Lattice

NASA Astrophysics Data System (ADS)

Moritomo, Yutaka; Igarashi, Kazuhiro; Kim, Jungeun; Tanaka, Hiroshi

2009-08-01

Cation and/or molecule transfer within nanoporous materials can be utilized in, for example, electrochromic devices, hydrogen storage, molecular sensors, and molecular filters. Here, we investigated the mobilities of cations, Na+, K+, and Rb+, in vacancy-controlled Prussian blue film, NaxCo[Fe(CN)6]1-vzH2O (v is vacancy concentration) with a jungle gym structure. We found that only the smallest Na+ ions pass through the cubic planes of the lattice, while the larger cations, i.e., K+ and Rb+, take a detour channel along the [Fe(CN)6] vacancy. The size-dependent cation channel is well understood in terms of the potential curve derived by an ab initio total energy calculation.

One-Dimensional Metal-Oxide Nanostructures for Solar Photocatalytic Water-Splitting

NASA Astrophysics Data System (ADS)

Wang, Fengyun; Song, Longfei; Zhang, Hongchao; Luo, Linqu; Wang, Dong; Tang, Jie

2017-08-01

Because of their unique physical and chemical properties, one-dimensional (1-D) metal-oxide nanostructures have been extensively applied in the areas of gas sensors, electrochromic devices, nanogenerators, and so on. Solar water-splitting has attracted extensive research interest because hydrogen generated from solar-driven water splitting is a clean, sustainable, and abundant energy source that not only solves the energy crisis, but also protects the environment. In this comprehensive review, the main synthesis methods, properties, and especially prominent applications in solar water splitting of 1-D metal-oxides, including titanium dioxide (TiO2), zinc oxide (ZnO), tungsten trioxide (WO3), iron oxide (Fe2O3), and copper oxide (CuO) are fully discussed.

Ion conducting organic/inorganic hybrid polymers

NASA Technical Reports Server (NTRS)

Meador, Maryann B. (Inventor); Kinder, James D. (Inventor)

2010-01-01

This invention relates to a series of organic/inorganic hybrid polymers that are easy to fabricate into dimensionally stable films with good ion-conductivity over a wide range of temperatures for use in a variety of applications. The polymers are prepared by the reaction of amines, preferably diamines and mixtures thereof with monoamines with epoxy-functionalized alkoxysilanes. The products of the reaction are polymerized by hydrolysis of the alkoxysilane groups to produce an organic-containing silica network. Suitable functionality introduced into the amine and alkoxysilane groups produce solid polymeric membranes which conduct ions for use in fuel cells, high-performance solid state batteries, chemical sensors, electrochemical capacitors, electro-chromic windows or displays, analog memory devices and the like.

Will algorithms modified with soil and weather information improve in-field reflectance-sensing corn nitrogen applications?

USDA-ARS?s Scientific Manuscript database

Nitrogen (N) needs to support corn (Zea mays L.) production can be highly variable within fields. Canopy reflectance sensing for assessing crop N health has been implemented on many farmers’ fields to side-dress or top-dress variable-rate N application, but at times farmers report the performance of...

Empirical Models for the Shielding and Reflection of Jet Mixing Noise by a Surface

NASA Technical Reports Server (NTRS)

Brown, Clifford A.

2016-01-01

Empirical models for the shielding and reflection of jet mixing noise by a nearby surface are described and the resulting models evaluated. The flow variables are used to non-dimensionalize the surface position variables, reducing the variable space and producing models that are linear function of non-dimensional surface position and logarithmic in Strouhal frequency. A separate set of coefficients are determined at each observer angle in the dataset and linear interpolation is used to for the intermediate observer angles. The shielding and reflection models are then combined with existing empirical models for the jet mixing and jet-surface interaction noise sources to produce predicted spectra for a jet operating near a surface. These predictions are then evaluated against experimental data.

Spectral-agronomic relationships of corn, soybean and wheat canopies

NASA Technical Reports Server (NTRS)

Bauer, M. E. (Principal Investigator); Daughtry, C. S. T.; Vanderbilt, V. C.

1981-01-01

During the past six years several thousand reflectance spectra of corn, soybean, and wheat canopies were acquired and analyzed. The relationships of biophysical variables, including leaf area index, percent soil cover, chlorophyll and water content, to the visible and infrared reflectance of canopies are described. The effects on reflectance of cultural, environmental, and stress factors such as planting data, seeding rate, row spacing, cultivar, soil type and nitrogen fertilization are also examined. The conclusions are that several key agronomic variables including leaf area index, development stage and degree of stress are strongly related to spectral reflectance and that it should be possible to estimate these descriptions of crop condition from satellite acquired multispectral data.

Insight, rumination, and self-reflection as predictors of well-being.

PubMed

Harrington, Rick; Loffredo, Donald A

2011-01-01

Dispositional private self-focused attention variables such as insight, internal self-awareness (ISA), and self-reflectiveness (SR) have been found to relate to well-being. The present study sought to determine which dispositional private self-focused attention variables have the most predictive power for subjective well-being as measured by the Satisfaction With Life Scale (E. Diener, R. A. Emmons, R. J. Larsen, & S. Griffin, 1985) and for a eudaemonic form of well-being as measured by the Psychological Well-Being Scale (C. D. Ryff, 1989). A total of 121 college student participants completed an online version of the Self-Consciousness Scale-Revised, the Rumination-Reflection Questionnaire, the Self-Reflection and Insight Scale, the Satisfaction With Life Scale, and the Psychological WellBeing Scale. Results of a multivariate regression analysis using the Self-Consciousness Scale-Revised's (M. F. Scheier & C. S. Carver, 1985) subfactors of SR and ISA, the Rumination-Reflection Questionnaire's (P. D. Trapnell & J. D. Campbell, 1999) subscales of Rumination and Reflection, and the Self-Reflection and Insight Scale's (A. M. Grant, J. Franklin, & P. Langford, 2002) Self-Reflection and Insight subscales revealed that the Insight subscale was the only statistically significant predictor (a positive predictor) for all 6 dimensions of psychological well-being. Insight was also the only significant positive predictor for satisfaction with life. The Rumination subscale was a significant negative predictor for 3 dimensions of psychological well-being, and the Reflection subscale was a significant positive predictor for 1 dimension. Implications of dispositional self-awareness variables and their relation to dimensions of well-being are discussed.

A model of genetic variation for Pinus ponderosa in the Inland Northwest (U.S.A.): applications in gene resource management

Treesearch

Gerald Rehfeldt

1991-01-01

Models were developed to describe genetic variation among 201 seedling populations of Pinus ponderosa var. ponderosa in the Inland Northwest of the United States. Common-garden studies provided three variables Jhat reflected growth and development in field environments and three principal components of six variables that reflected patterns of shoot elongation....

Apparatus and method for microwave processing of materials

DOEpatents

Johnson, A.C.; Lauf, R.J.; Bible, D.W.; Markunas, R.J.

1996-05-28

Disclosed is a variable frequency microwave heating apparatus designed to allow modulation of the frequency of the microwaves introduced into a furnace cavity for testing or other selected applications. The variable frequency heating apparatus is used in the method of the present invention to monitor the resonant processing frequency within the furnace cavity depending upon the material, including the state thereof, from which the workpiece is fabricated. The variable frequency microwave heating apparatus includes a microwave signal generator and a high-power microwave amplifier or a microwave voltage-controlled oscillator. A power supply is provided for operation of the high-power microwave oscillator or microwave amplifier. A directional coupler is provided for detecting the direction and amplitude of signals incident upon and reflected from the microwave cavity. A first power meter is provided for measuring the power delivered to the microwave furnace. A second power meter detects the magnitude of reflected power. Reflected power is dissipated in the reflected power load. 10 figs.

Quantitative Comparison of the Variability in Observed and Simulated Shortwave Reflectance

NASA Technical Reports Server (NTRS)

Roberts, Yolanda, L.; Pilewskie, P.; Kindel, B. C.; Feldman, D. R.; Collins, W. D.

2013-01-01

The Climate Absolute Radiance and Refractivity Observatory (CLARREO) is a climate observation system that has been designed to monitor the Earth's climate with unprecedented absolute radiometric accuracy and SI traceability. Climate Observation System Simulation Experiments (OSSEs) have been generated to simulate CLARREO hyperspectral shortwave imager measurements to help define the measurement characteristics needed for CLARREO to achieve its objectives. To evaluate how well the OSSE-simulated reflectance spectra reproduce the Earth s climate variability at the beginning of the 21st century, we compared the variability of the OSSE reflectance spectra to that of the reflectance spectra measured by the Scanning Imaging Absorption Spectrometer for Atmospheric Cartography (SCIAMACHY). Principal component analysis (PCA) is a multivariate decomposition technique used to represent and study the variability of hyperspectral radiation measurements. Using PCA, between 99.7%and 99.9%of the total variance the OSSE and SCIAMACHY data sets can be explained by subspaces defined by six principal components (PCs). To quantify how much information is shared between the simulated and observed data sets, we spectrally decomposed the intersection of the two data set subspaces. The results from four cases in 2004 showed that the two data sets share eight (January and October) and seven (April and July) dimensions, which correspond to about 99.9% of the total SCIAMACHY variance for each month. The spectral nature of these shared spaces, understood by examining the transformed eigenvectors calculated from the subspace intersections, exhibit similar physical characteristics to the original PCs calculated from each data set, such as water vapor absorption, vegetation reflectance, and cloud reflectance.

Retrieval of seasonal dynamics of forest understory reflectance from semi-arid to boreal forests using MODIS BRDF data

NASA Astrophysics Data System (ADS)

Pisek, Jan; Chen, Jing; Kobayashi, Hideki; Rautiainen, Miina; Schaepman, Michael; Karnieli, Arnon; Sprintsin, Michael; Ryu, Youngryel; Nikopensius, Maris; Raabe, Kairi

2016-04-01

Ground vegetation (understory) provides an essential contribution to the whole-stand reflectance signal in many boreal, sub-boreal, and temperate forests. Accurate knowledge about forest understory reflectance is urgently needed in various forest reflectance modelling efforts. However, systematic collections of understory reflectance data covering different sites and ecosystems are almost missing. Measurement of understory reflectance is a real challenge because of an extremely high variability of irradiance at the forest floor, weak signal in some parts of the spectrum, spectral separability issues of over- and understory and its variable nature. Understory can consist of several sub-layers (regenerated tree, shrub, grasses or dwarf shrub, mosses, lichens, litter, bare soil), it has spatially-temporally variable species composition and ground coverage. Additional challenges are introduced by patchiness of ground vegetation, ground surface roughness, and understory-overstory relations. Due to this variability, remote sensing might be the only means to provide consistent data at spatially relevant scales. In this presentation, we report on retrieving seasonal courses of understory Normalized Difference Vegetation Index (NDVI) from multi-angular MODIS BRDF/Albedo data. We compared satellite-based seasonal courses of understory NDVI against an extended collection of different types of forest sites with available in-situ understory reflectance measurements. These sites are distributed along a wide latitudinal gradient on the Northern hemisphere: a sparse and dense black spruce forests in Alaska and Canada, a northern European boreal forest in Finland, hemiboreal needleleaf and deciduous stands in Estonia, a mixed temperate forest in Switzerland, a cool temperate deciduous broadleaf forest in Korea, and a semi-arid pine plantation in Israel. Our results indicated the retrieval method performs well particularly over open forests of different types. We also demonstrated the limitations of the method for closed canopies, where the understory signal retrieval is much attenuated. The retrieval of understory signal can be used e.g. to improve the estimates of leaf area index (LAI), fAPAR in sparsely vegetated areas, and also to study the phenology of understory layer. Our results are particularly useful to producing Northern hemisphere maps of seasonal dynamics of forests, allowing to separately retrieve understory variability, being a main contributor to spring emergence and fall senescence uncertainty. The inclusion of understory variability in ecological models will ultimately improve prediction and forecast horizons of vegetation dynamics.

Predicting High Quality AFQT with Youth Attitude Tracking Study Data

DTIC Science & Technology

1991-12-01

for propensities. The history of the art of mental aptitude and psychological testing is long and convoluted. Names like Sir Francis Galton of England...Qualification Test . The explanatory variables reflect individual demographic, educational and labor market characteristics at the time of YATS interview. The...the fiftieth percentile on the Armed Forces Qualification Test . The explanatory variables reflect individual demographic, educational and labor market

Retrieval of seasonal dynamics of forest understory reflectance over a set of boreal, sub-boreal and temperate forests using MODIS BRDF data

NASA Astrophysics Data System (ADS)

Pisek, J.; Lang, M.; Kuusk, J.; Kobayashi, H.; Suzuki, R.; Rautiainen, M.; Schaepman, M. E.; Nikopensius, M.; Raabe, K.

2013-12-01

Since ground vegetation (understory) has an essential contribution to the whole-stand reflectance signal in many boreal, sub-boreal and temperate forests, its reflectance spectra are urgently needed in various forest reflectance modelling efforts. However, systematic reflectance data covering different site types are almost missing. Measurement of understory reflectance is a real challenge because of extremely high variability of irradiance at the forest floor, weak signal in some parts of the spectrum and its variable nature. Understory consists of several sub-layers (tree regeneration, shrub, grasses or dwarf shrub, mosses or lichens, litter, bare soil), it has spatially-temporally variable species composition and ground coverage. Additional problems are introduced by patchiness of ground vegetation, ground surface roughness and understory-overstory relations. Due to this variability, remote sensing might be the only technology to provide consistent data at the required spatially extensive scales. Here we follow on our previous effort at mapping understory reflectance dynamics using multi-angle remote sensing observations (Pisek et al. (2012). Retrieval of seasonal dynamics of forest understory reflectance in a Northern European boreal forest from MODIS BRDF data. Remote Sensing of Environment, 117, 464-468). This presentation will focus on the validation of this approach against an extended collection of different types of forest sites with available in-situ understory reflectance measurements distributed along a wide latitudinal gradient: a sparse black spruce forest in Alaska (Poker range; 65.12 N), a northern European boreal forest (Hyytiala; 61.85 N), hemiboreal needleleaf and deciduous stands in Estonia (Jarvselja; 58.27 N), a temperate deciduous forest in Switzerland (Laegeren; 47.48 N), and a dense black spruce forest in Canada (Sudbury; 47.16 N). Our results are pertinent to the ultimate goal of production of circumpolar maps of seasonal dynamics of forest understory over boreal forests using the MODIS BRDF data, starting from 2000. This will allow us to assess the changes in seasonal dynamics of boreal forest understory over the full decade.

2D and 3D photonic crystal materials for photocatalysis and electrochemical energy storage and conversion.

PubMed

Collins, Gillian; Armstrong, Eileen; McNulty, David; O'Hanlon, Sally; Geaney, Hugh; O'Dwyer, Colm

2016-01-01

This perspective reviews recent advances in inverse opal structures, how they have been developed, studied and applied as catalysts, catalyst support materials, as electrode materials for batteries, water splitting applications, solar-to-fuel conversion and electrochromics, and finally as photonic photocatalysts and photoelectrocatalysts. Throughout, we detail some of the salient optical characteristics that underpin recent results and form the basis for light-matter interactions that span electrochemical energy conversion systems as well as photocatalytic systems. Strategies for using 2D as well as 3D structures, ordered macroporous materials such as inverse opals are summarized and recent work on plasmonic-photonic coupling in metal nanoparticle-infiltrated wide band gap inverse opals for enhanced photoelectrochemistry are provided.

2D and 3D photonic crystal materials for photocatalysis and electrochemical energy storage and conversion

PubMed Central

Collins, Gillian; Armstrong, Eileen; McNulty, David; O’Hanlon, Sally; Geaney, Hugh; O’Dwyer, Colm

2016-01-01

Abstract This perspective reviews recent advances in inverse opal structures, how they have been developed, studied and applied as catalysts, catalyst support materials, as electrode materials for batteries, water splitting applications, solar-to-fuel conversion and electrochromics, and finally as photonic photocatalysts and photoelectrocatalysts. Throughout, we detail some of the salient optical characteristics that underpin recent results and form the basis for light-matter interactions that span electrochemical energy conversion systems as well as photocatalytic systems. Strategies for using 2D as well as 3D structures, ordered macroporous materials such as inverse opals are summarized and recent work on plasmonic–photonic coupling in metal nanoparticle-infiltrated wide band gap inverse opals for enhanced photoelectrochemistry are provided. PMID:27877904

Development and applications of transparent conductive nanocellulose paper

NASA Astrophysics Data System (ADS)

Li, Shaohui; Lee, Pooi See

2017-12-01

Increasing attention has been paid to the next generation of 'green' electronic devices based on renewable nanocellulose, owing to its low roughness, good thermal stability and excellent optical properties. Various proof-of-concept transparent nanopaper-based electronic devices have been fabricated; these devices exhibit excellent flexibility, bendability and even foldability. In this review, we summarize the recent progress of transparent nanopaper that uses different types of nanocellulose, including pure nanocellulose paper and composite nanocellulose paper. The latest development of transparent and flexible nanopaper electronic devices are illustrated, such as electrochromic devices, touch sensors, solar cells and transistors. Finally, we discuss the advantages of transparent nanopaper compared to conventional flexible plastic substrate and the existing challenges to be tackled in order to realize this promising potential.

CO2 Capture Using Electric Fields: Low-Cost Electrochromic Film on Plastic for Net-Zero Energy Building

DOE Office of Scientific and Technical Information (OSTI.GOV)

None

2010-01-01

Broad Funding Opportunity Announcement Project: Two faculty members at Lehigh University created a new technique called supercapacitive swing adsorption (SSA) that uses electrical charges to encourage materials to capture and release CO2. Current CO2 capture methods include expensive processes that involve changes in temperature or pressure. Lehigh University’s approach uses electric fields to improve the ability of inexpensive carbon sorbents to trap CO2. Because this process uses electric fields and not electric current, the overall energy consumption is projected to be much lower than conventional methods. Lehigh University is now optimizing the materials to maximize CO2 capture and minimize themore » energy needed for the process.« less

Investigating broadband variability of the TeV blazar 1ES 1959+650

DOE Office of Scientific and Technical Information (OSTI.GOV)

Aliu, E.; Archambault, S.; Arlen, T.

We summarize broadband observations of the TeV-emitting blazar 1ES 1959 650, including optical R-band observations by the robotic telescopes Super-LOTIS and iTelescope, UV observations by Swift UVOT, X-ray observations by the Swift X-ray Telescope, high-energy gamma-ray observations with the Fermi Large Area Telescope, and very-high-energy (VHE) gamma-ray observations by VERITAS above 315 GeV, all taken between 2012 April 17 and 2012 June 1 (MJD 56034 and 56079). The contemporaneous variability of the broadband spectral energy distribution is explored in the context of a simple synchrotron self Compton (SSC) model. In the SSC emission scenario, we find that the parameters requiredmore » to represent the high state are significantly different than those in the low state. Motivated by possible evidence of gas in the vicinity of the blazar, we also investigate a reflected emission model to describe the observed variability pattern. This model assumes that the non-thermal emission from the jet is reflected by a nearby cloud of gas, allowing the reflected emission to re-enter the blob and produce an elevated gamma-ray state with no simultaneous elevated synchrotron flux. The model applied here, although not required to explain the observed variability pattern, represents one possible scenario which can describe the observations. As applied to an elevated VHE state of 66% of the Crab Nebula flux, observed on a single night during the observation period, the reflected emission scenario does not support a purely leptonic non-thermal emission mechanism. The reflected model does, however, predict a reflected photon field with sufficient energy to enable elevated gamma-ray emission via pion production with protons of energies between 10 and 100 TeV.« less

INVESTIGATING BROADBAND VARIABILITY OF THE TeV BLAZAR 1ES 1959+650

DOE Office of Scientific and Technical Information (OSTI.GOV)

Aliu, E.; Archambault, S.; Arlen, T.

We summarize broadband observations of the TeV-emitting blazar 1ES 1959+650, including optical R-band observations by the robotic telescopes Super-LOTIS and iTelescope, UV observations by Swift Ultraviolet and Optical Telescope, X-ray observations by the Swift X-ray Telescope, high-energy gamma-ray observations with the Fermi Large Area Telescope, and very-high-energy (VHE) gamma-ray observations by VERITAS above 315 GeV, all taken between 2012 April 17 and 2012 June 1 (MJD 56034 and 56079). The contemporaneous variability of the broadband spectral energy distribution is explored in the context of a simple synchrotron self Compton (SSC) model. In the SSC emission scenario, we find that themore » parameters required to represent the high state are significantly different than those in the low state. Motivated by possible evidence of gas in the vicinity of the blazar, we also investigate a reflected emission model to describe the observed variability pattern. This model assumes that the non-thermal emission from the jet is reflected by a nearby cloud of gas, allowing the reflected emission to re-enter the blob and produce an elevated gamma-ray state with no simultaneous elevated synchrotron flux. The model applied here, although not required to explain the observed variability pattern, represents one possible scenario which can describe the observations. As applied to an elevated VHE state of 66% of the Crab Nebula flux, observed on a single night during the observation period, the reflected emission scenario does not support a purely leptonic non-thermal emission mechanism. The reflected emission model does, however, predict a reflected photon field with sufficient energy to enable elevated gamma-ray emission via pion production with protons of energies between 10 and 100 TeV.« less

INVESTIGATING BROADBAND VARIABILITY OF THE TeV BLAZAR 1ES 1959+650

DOE Office of Scientific and Technical Information (OSTI.GOV)

Aliu, E.; Archambault, S.; Arlen, T.

We summarize broadband observations of the TeV-emitting blazar 1ES 1959+650, including optical R-band observations by the robotic telescopes Super-LOTIS and iTelescope, UV observations by Swift Ultraviolet and Optical Telescope, X-ray observations by the Swift X-ray Telescope, high-energy gamma-ray observations with the Fermi Large Area Telescope, and very-high-energy (VHE) gamma-ray observations by VERITAS above 315 GeV, all taken between 2012 April 17 and 2012 June 1 (MJD 56034 and 56079). The contemporaneous variability of the broadband spectral energy distribution is explored in the context of a simple synchrotron self Compton (SSC) model. In the SSC emission scenario, we find that themore » parameters required to represent the high state are significantly different than those in the low state. Motivated by possible evidence of gas in the vicinity of the blazar, we also investigate a reflected emission model to describe the observed variability pattern. This model assumes that the non-thermal emission from the jet is reflected by a nearby cloud of gas, allowing the reflected emission to re-enter the blob and produce an elevated gamma-ray state with no simultaneous elevated synchrotron flux. The model applied here, although not required to explain the observed variability pattern, represents one possible scenario which can describe the observations. As applied to an elevated VHE state of 66% of the Crab Nebula flux, observed on a single night during the observation period, the reflected emission scenario does not support a purely leptonic non-thermal emission mechanism. The reflected emission model does, however, predict a reflected photon field with sufficient energy to enable elevated gamma-ray emission via pion production with protons of energies between 10 and 100 TeV.« less

Investigating broadband variability of the TeV blazar 1ES 1959+650

DOE PAGES

Aliu, E.; Archambault, S.; Arlen, T.; ...

2014-12-03

We summarize broadband observations of the TeV-emitting blazar 1ES 1959 650, including optical R-band observations by the robotic telescopes Super-LOTIS and iTelescope, UV observations by Swift UVOT, X-ray observations by the Swift X-ray Telescope, high-energy gamma-ray observations with the Fermi Large Area Telescope, and very-high-energy (VHE) gamma-ray observations by VERITAS above 315 GeV, all taken between 2012 April 17 and 2012 June 1 (MJD 56034 and 56079). The contemporaneous variability of the broadband spectral energy distribution is explored in the context of a simple synchrotron self Compton (SSC) model. In the SSC emission scenario, we find that the parameters requiredmore » to represent the high state are significantly different than those in the low state. Motivated by possible evidence of gas in the vicinity of the blazar, we also investigate a reflected emission model to describe the observed variability pattern. This model assumes that the non-thermal emission from the jet is reflected by a nearby cloud of gas, allowing the reflected emission to re-enter the blob and produce an elevated gamma-ray state with no simultaneous elevated synchrotron flux. The model applied here, although not required to explain the observed variability pattern, represents one possible scenario which can describe the observations. As applied to an elevated VHE state of 66% of the Crab Nebula flux, observed on a single night during the observation period, the reflected emission scenario does not support a purely leptonic non-thermal emission mechanism. The reflected model does, however, predict a reflected photon field with sufficient energy to enable elevated gamma-ray emission via pion production with protons of energies between 10 and 100 TeV.« less

Lexical and phonological variability in preschool children with speech sound disorder.

PubMed

Macrae, Toby; Tyler, Ann A; Lewis, Kerry E

2014-02-01

The authors of this study examined relationships between measures of word and speech error variability and between these and other speech and language measures in preschool children with speech sound disorder (SSD). In this correlational study, 18 preschool children with SSD, age-appropriate receptive vocabulary, and normal oral motor functioning and hearing were assessed across 2 sessions. Experimental measures included word and speech error variability, receptive vocabulary, nonword repetition (NWR), and expressive language. Pearson product–moment correlation coefficients were calculated among the experimental measures. The correlation between word and speech error variability was slight and nonsignificant. The correlation between word variability and receptive vocabulary was moderate and negative, although nonsignificant. High word variability was associated with small receptive vocabularies. The correlations between speech error variability and NWR and between speech error variability and the mean length of children's utterances were moderate and negative, although both were nonsignificant. High speech error variability was associated with poor NWR and language scores. High word variability may reflect unstable lexical representations, whereas high speech error variability may reflect indistinct phonological representations. Preschool children with SSD who show abnormally high levels of different types of speech variability may require slightly different approaches to intervention.

On the relationship between ecosystem-scale hyperspectral reflectance and CO2 exchange in European mountain grasslands

NASA Astrophysics Data System (ADS)

Balzarolo, M.; Vescovo, L.; Hammerle, A.; Gianelle, D.; Papale, D.; Tomelleri, E.; Wohlfahrt, G.

2015-05-01

In this paper we explore the skill of hyperspectral reflectance measurements and vegetation indices (VIs) derived from these in estimating carbon dioxide (CO2) fluxes of grasslands. Hyperspectral reflectance data, CO2 fluxes and biophysical parameters were measured at three grassland sites located in European mountain regions using standardized protocols. The relationships between CO2 fluxes, ecophysiological variables, traditional VIs and VIs derived using all two-band combinations of wavelengths available from the whole hyperspectral data space were analysed. We found that VIs derived from hyperspectral data generally explained a large fraction of the variability in the investigated dependent variables but differed in their ability to estimate midday and daily average CO2 fluxes and various derived ecophysiological parameters. Relationships between VIs and CO2 fluxes and ecophysiological parameters were site-specific, likely due to differences in soils, vegetation parameters and environmental conditions. Chlorophyll and water-content-related VIs explained the largest fraction of variability in most of the dependent variables. Band selection based on a combination of a genetic algorithm with random forests (GA-rF) confirmed that it is difficult to select a universal band region suitable across the investigated ecosystems. Our findings have major implications for upscaling terrestrial CO2 fluxes to larger regions and for remote- and proximal-sensing sampling and analysis strategies and call for more cross-site synthesis studies linking ground-based spectral reflectance with ecosystem-scale CO2 fluxes.

Developmental Differences in Intra-Individual Variability in Children with ADHD and ASD

ERIC Educational Resources Information Center

Belle, Janna; van Hulst, Branko M.; Durston, Sarah

2015-01-01

Background: Intra-individual variability reflects temporal variation within an individual's performance on a cognitive task. Children with developmental disorders, such as ADHD and ASD show increased levels of intra-individual variability. In typical development, intra-individual variability decreases sharply between the ages 6 and 20. The tight…

Apparatus and method for microwave processing of materials

DOEpatents

Johnson, Arvid C.; Lauf, Robert J.; Bible, Don W.; Markunas, Robert J.

1996-01-01

A variable frequency microwave heating apparatus (10) designed to allow modulation of the frequency of the microwaves introduced into a furnace cavity (34) for testing or other selected applications. The variable frequency heating apparatus (10) is used in the method of the present invention to monitor the resonant processing frequency within the furnace cavity (34) depending upon the material, including the state thereof, from which the workpiece (36) is fabricated. The variable frequency microwave heating apparatus (10) includes a microwave signal generator (12) and a high-power microwave amplifier (20) or a microwave voltage-controlled oscillator (14). A power supply (22) is provided for operation of the high-power microwave oscillator (14) or microwave amplifier (20). A directional coupler (24) is provided for detecting the direction and amplitude of signals incident upon and reflected from the microwave cavity (34). A first power meter (30) is provided for measuring the power delivered to the microwave furnace (32). A second power meter (26) detects the magnitude of reflected power. Reflected power is dissipated in the reflected power load (28).

Microphysical variability of Amazonian deep convective cores observed by CloudSat and simulated by a multi-scale modeling framework

NASA Astrophysics Data System (ADS)

Brant Dodson, J.; Taylor, Patrick C.; Branson, Mark

2018-05-01

Recently launched cloud observing satellites provide information about the vertical structure of deep convection and its microphysical characteristics. In this study, CloudSat reflectivity data is stratified by cloud type, and the contoured frequency by altitude diagrams reveal a double-arc structure in deep convective cores (DCCs) above 8 km. This suggests two distinct hydrometeor modes (snow versus hail/graupel) controlling variability in reflectivity profiles. The day-night contrast in the double arcs is about four times larger than the wet-dry season contrast. Using QuickBeam, the vertical reflectivity structure of DCCs is analyzed in two versions of the Superparameterized Community Atmospheric Model (SP-CAM) with single-moment (no graupel) and double-moment (with graupel) microphysics. Double-moment microphysics shows better agreement with observed reflectivity profiles; however, neither model variant captures the double-arc structure. Ultimately, the results show that simulating realistic DCC vertical structure and its variability requires accurate representation of ice microphysics, in particular the hail/graupel modes, though this alone is insufficient.

Visual Inspection of Surfaces

NASA Technical Reports Server (NTRS)

Hughes, David; Perez, Xavier

2007-01-01

This presentation evaluates the parameters that affect visual inspection of cleanliness. Factors tested include surface reflectance, surface roughness, size of the largest particle, exposure time, inspector and distance from sample surface. It is concluded that distance predictions were not great, particularly because the distance at which contamination is seen may depend on more variables than those tested. Most parameters estimates had confidence of 95% or better, except for exposure and reflectance. Additionally, the distance at which surface is visibly contaminated decreases with increasing reflectance, roughness, and exposure. The distance at which the surface is visually contaminated increased with the largest particle size. These variables were only slightly affected the observer.

Effect of carbon limitation on photosynthetic electron transport in Nannochloropsis oculata.

PubMed

Zavřel, Tomáš; Szabó, Milán; Tamburic, Bojan; Evenhuis, Christian; Kuzhiumparambil, Unnikrishnan; Literáková, Petra; Larkum, Anthony W D; Raven, John A; Červený, Jan; Ralph, Peter J

2018-04-01

This study describes the impacts of inorganic carbon limitation on the photosynthetic efficiency and operation of photosynthetic electron transport pathways in the biofuel-candidate microalga Nannochloropsis oculata. Using a combination of highly-controlled cultivation setup (photobioreactor), variable chlorophyll a fluorescence and transient spectroscopy methods (electrochromic shift (ECS) and P 700 redox kinetics), we showed that net photosynthesis and effective quantum yield of Photosystem II (PSII) decreased in N. oculata under carbon limitation. This was accompanied by a transient increase in total proton motive force and energy-dependent non-photochemical quenching as well as slightly elevated respiration. On the other hand, under carbon limitation the rapid increase in proton motive force (PMF, estimated from the total ECS signal) was also accompanied by reduced conductivity of ATP synthase to protons (estimated from the rate of ECS decay in dark after actinic illumination). This indicates that the slow operation of ATP synthase results in the transient build-up of PMF, which leads to the activation of fast energy dissipation mechanisms such as energy-dependent non-photochemical quenching. N. oculata also increased content of lipids under carbon limitation, which compensated for reduced NAPDH consumption during decreased CO 2 fixation. The integrated knowledge of the underlying energetic regulation of photosynthetic processes attained with a combination of biophysical methods may be used to identify photo-physiological signatures of the onset of carbon limitation in microalgal cultivation systems, as well as to potentially identify microalgal strains that can better acclimate to carbon limitation. Copyright © 2018 Elsevier B.V. All rights reserved.

Unmanned aerial system nadir reflectance and MODIS nadir BRDF-adjusted surface reflectances intercompared over Greenland

NASA Astrophysics Data System (ADS)

Faulkner Burkhart, John; Kylling, Arve; Schaaf, Crystal B.; Wang, Zhuosen; Bogren, Wiley; Storvold, Rune; Solbø, Stian; Pedersen, Christina A.; Gerland, Sebastian

2017-07-01

Albedo is a fundamental parameter in earth sciences, and many analyses utilize the Moderate Resolution Imaging Spectroradiometer (MODIS) bidirectional reflectance distribution function (BRDF)/albedo (MCD43) algorithms. While derivative albedo products have been evaluated over Greenland, we present a novel, direct comparison with nadir surface reflectance collected from an unmanned aerial system (UAS). The UAS was flown from Summit, Greenland, on 210 km transects coincident with the MODIS sensor overpass on board the Aqua and Terra satellites on 5 and 6 August 2010. Clear-sky acquisitions were available from the overpasses within 2 h of the UAS flights. The UAS was equipped with upward- and downward-looking spectrometers (300-920 nm) with a spectral resolution of 10 nm, allowing for direct integration into the MODIS bands 1, 3, and 4. The data provide a unique opportunity to directly compare UAS nadir reflectance with the MODIS nadir BRDF-adjusted surface reflectance (NBAR) products. The data show UAS measurements are slightly higher than the MODIS NBARs for all bands but agree within their stated uncertainties. Differences in variability are observed as expected due to different footprints of the platforms. The UAS data demonstrate potentially large sub-pixel variability of MODIS reflectance products and the potential to explore this variability using the UAS as a platform. It is also found that, even at the low elevations flown typically by a UAS, reflectance measurements may be influenced by haze if present at and/or below the flight altitude of the UAS. This impact could explain some differences between data from the two platforms and should be considered in any use of airborne platforms.

The relationship between language use and depression: illuminating the importance of self-reflection, self-rumination, and the need for absolute truth.

PubMed

Şimşek, Ömer Faruk

2013-01-01

The main aim of the present study was to provide additional knowledge about the mediatory processes through which language relates to depression. Although previous research gave clear evidence that language is closely related to depression, the research on intervening variables in the relationship has been limited. The present investigation tested a structural equation model in which self-concept clarity and self-consciousness mediated the relationship between personal perceptions of language and depression. Since "the need for absolute truth" construct has been shown to be important in providing greater consistency in estimates of the relationships among the variables, it has been added to the model as a control variable. The results supported the model and showed that personal perceptions of language predicted self-concept clarity, which in turn predicted the participants' self-reflection and self-rumination. Self-reflection and self-rumination, in turn, predicted depression.

Characterization of Surface Reflectance Variation Effects on Remote Sensing

NASA Technical Reports Server (NTRS)

Pearce, W. A.

1984-01-01

The use of Monte Carlo radiative transfer codes to simulate the effects on remote sensing in visible and infrared wavelengths of variables which affect classification is examined. These variables include detector viewing angle, atmospheric aerosol size distribution, aerosol vertical and horizontal distribution (e.g., finite clouds), the form of the bidirectional ground reflectance function, and horizontal variability of reflectance type and reflectivity (albedo). These simulations are used to characterize the sensitivity of observables (intensity and polarization) to variations in the underlying physical parameters both to improve algorithms for the removal of atmospheric effects and to identify techniques which can improve classification accuracy. It was necessary to revise and validate the simulation codes (CTRANS, ARTRAN, and the Mie scattering code) to improve efficiency and accommodate a new operational environment, and to build the basic software tools for acquisition and off-line manipulation of simulation results. Initial calculations compare cases in which increasing amounts of aerosol are shifted into the stratosphere, maintaining a constant optical depth. In the case of moderate aerosol optical depth, the effect on the spread function is to scale it linearly as would be expected from a single scattering model. Varying the viewing angle appears to provide the same qualitative effect as modifying the vertical optical depth (for Lambertian ground reflectance).

Some Insights of Spectral Optimization in Ocean Color Inversion

NASA Technical Reports Server (NTRS)

Lee, Zhongping; Franz, Bryan; Shang, Shaoling; Dong, Qiang; Arnone, Robert

2011-01-01

In the past decades various algorithms have been developed for the retrieval of water constituents from the measurement of ocean color radiometry, and one of the approaches is spectral optimization. This approach defines an error target (or error function) between the input remote sensing reflectance and the output remote sensing reflectance, with the latter modeled with a few variables that represent the optically active properties (such as the absorption coefficient of phytoplankton and the backscattering coefficient of particles). The values of the variables when the error reach a minimum (optimization is achieved) are considered the properties that form the input remote sensing reflectance; or in other words, the equations are solved numerically. The applications of this approach implicitly assume that the error is a monotonic function of the various variables. Here, with data from numerical simulation and field measurements, we show the shape of the error surface, in a way to justify the possibility of finding a solution of the various variables. In addition, because the spectral properties could be modeled differently, impacts of such differences on the error surface as well as on the retrievals are also presented.

Validity of a Residualized Dependent Variable after Pretest Covariance Adjustments: Still the Same Variable?

ERIC Educational Resources Information Center

Nimon, Kim; Henson, Robin K.

2015-01-01

The authors empirically examined whether the validity of a residualized dependent variable after covariance adjustment is comparable to that of the original variable of interest. When variance of a dependent variable is removed as a result of one or more covariates, the residual variance may not reflect the same meaning. Using the pretest-posttest…

Temporal, Spatial, and Spectral Variability at Ivanpah Playa Vicarious Calibration Site

DOE Office of Scientific and Technical Information (OSTI.GOV)

Villa-Aleman, E.

2003-01-07

The Savannah River Technology Center (SRTC) conducted four reflectance vicarious calibrations at Ivanpah Playa, California since July 2000 in support of the MTI satellite. The multi-year study shows temporal, spatial and spectral variability at the playa. The temporal variability in the wavelength dependent reflectance and emissivity across the playa suggests a dependency with precipitation during the winter and early spring seasons. Satellite imagery acquired on September and November 2000, May 2001 and March 2002 in conjunction with ground truth during the September, May and March campaigns and water precipitation records were used to demonstrate the correlation observed at the playa

Sensitivity of the normalized difference vegetation index to subpixel canopy cover, soil albedo, and pixel scale

NASA Technical Reports Server (NTRS)

Jasinski, Michael F.

1990-01-01

An analytical framework is provided for examining the physically based behavior of the normalized difference vegetation index (NDVI) in terms of the variability in bulk subpixel landscape components and with respect to variations in pixel scales, within the context of the stochastic-geometric canopy reflectance model. Analysis focuses on regional scale variability in horizontal plant density and soil background reflectance distribution. Modeling is generalized to different plant geometries and solar angles through the use of the nondimensional solar-geometric similarity parameter. Results demonstrate that, for Poisson-distributed plants and for one deterministic distribution, NDVI increases with increasing subpixel fractional canopy amount, decreasing soil background reflectance, and increasing shadows, at least within the limitations of the geometric reflectance model. The NDVI of a pecan orchard and a juniper landscape is presented and discussed.

Does the estimation of light attenuation in tissue increase the accuracy of reflectance pulse oximetry at low oxygen saturations in vivo?

PubMed

Kisch-Wedel, H; Bernreuter, P; Kemming, G; Albert, M; Zwissler, B

2009-09-01

A new technique was validated in vivo in reflectance pulse oximetry for measuring low oxygen saturations. Two pairs of light emitter/detector diodes allow for estimation of light attenuation (LA) in tissue, which is assumed to be responsible for the inaccuracy of pulse oximetry at less than 70 % arterial oxygen saturation. For validation, 17 newborn piglets were desaturated stepwise from 21 % to 1.25 % inspiratory oxygen concentration during general anesthesia, and arterial oxygen saturation was measured with the reflectance pulse oximeter adjusted for LA in tissue, with a standard transmission pulse oximeter and a hemoximeter. LA in tissue could be quantified and was different between snout and foreleg (probability level (p) < 0.05). At arterial oxygen saturations above 70 %, the bias between the methods was at 0 %-1 % and the variability 4 %-5 %. From 2 % to 100 % arterial oxygen saturation, the reflectance pulse oximeter estimated oxyhemoglobin saturation more accurately than a conventional transmission pulse oximeter (p < 0.05). At low oxygen saturations below 70 %, the bias and variability of the reflectance pulse oximeter calibration were closer to the hemoximeter measurements than the transmission pulse oximeter (p < 0.05). The variability of the reflectance pulse oximeter was slightly lower than the traditional oximeter by taking into account the LA in tissue (9 % versus 11 % -15 %, ns), and thus, the quality of the individual calibration lines improved (correlation coefficient, p < 0.05).

Optical Constituents Along a River Mouth and Inlet: Variability and Signature in Remotely Sensed Reflectance, and: Optical Constituents at the Mouth of the Columbia River: Variability and Signature in Remotely Sensed Reflectance

DTIC Science & Technology

2013-09-30

Vision Floc Camera (MVFC), a Sequoia Scientific LISST 100x Type B, an RBR CTD, and two pressure-actuated Niskin bottles. The Niskin bottles were...Eco bb2fl, that measures 3 backscattering at 532 and 650 nm and CDOM fluorescence, a WetLabs WetStar CDOM fluorometer, a Sequoia Scientific flow

A high-density relativistic reflection origin for the soft and hard X-ray excess emission from Mrk 1044

NASA Astrophysics Data System (ADS)

Mallick, L.; Alston, W. N.; Parker, M. L.; Fabian, A. C.; Pinto, C.; Dewangan, G. C.; Markowitz, A.; Gandhi, P.; Kembhavi, A. K.; Misra, R.

2018-06-01

We present the first results from a detailed spectral-timing analysis of a long (˜130 ks) XMM-Newton observation and quasi-simultaneous NuSTAR and Swift observations of the highly-accreting narrow-line Seyfert 1 galaxy Mrk 1044. The broadband (0.3-50 keV) spectrum reveals the presence of a strong soft X-ray excess emission below ˜1.5 keV, iron Kα emission complex at ˜6 -7 keV and a `Compton hump' at ˜15 -30 keV. We find that the relativistic reflection from a high-density accretion disc with a broken power-law emissivity profile can simultaneously explain the soft X-ray excess, highly ionized broad iron line and the Compton hump. At low frequencies ([2 - 6] × 10-5 Hz), the power-law continuum dominated 1.5-5 keV band lags behind the reflection dominated 0.3-1 keV band, which is explained with a combination of propagation fluctuation and Comptonization processes, while at higher frequencies ([1 - 2] × 10-4 Hz), we detect a soft lag which is interpreted as a signature of X-ray reverberation from the accretion disc. The fractional root-mean-squared (rms) variability of the source decreases with energy and is well described by two variable components: a less variable relativistic disc reflection and a more variable direct coronal emission. Our combined spectral-timing analyses suggest that the observed broadband X-ray variability of Mrk 1044 is mainly driven by variations in the location or geometry of the optically thin, hot corona.

Development and applications of transparent conductive nanocellulose paper

PubMed Central

Li, Shaohui; Lee, Pooi See

2017-01-01

Abstract Increasing attention has been paid to the next generation of ‘green’ electronic devices based on renewable nanocellulose, owing to its low roughness, good thermal stability and excellent optical properties. Various proof-of-concept transparent nanopaper-based electronic devices have been fabricated; these devices exhibit excellent flexibility, bendability and even foldability. In this review, we summarize the recent progress of transparent nanopaper that uses different types of nanocellulose, including pure nanocellulose paper and composite nanocellulose paper. The latest development of transparent and flexible nanopaper electronic devices are illustrated, such as electrochromic devices, touch sensors, solar cells and transistors. Finally, we discuss the advantages of transparent nanopaper compared to conventional flexible plastic substrate and the existing challenges to be tackled in order to realize this promising potential. PMID:28970870

Flake like V{sub 2}O{sub 5} nanoparticles for ethanol sensing at room temperature

DOE Office of Scientific and Technical Information (OSTI.GOV)

Chitra, M.; Uthayarani, K.; Rajasekaran, N.

2016-05-23

The versatile redox property of vanadium oxide explores it in various applications like catalysis, electrochromism, electrochemistry, energy storage, sensors, microelectronics, batteries etc., In this present work, vanadium oxide was prepared via hydrothermal route followed by calcination. The structural and lattice parameters were analysed from the powder X-ray diffraction (XRD) pattern. The morphology and the composition of the sample were obtained from Field emission Scanning electron microscopic (FeSEM) and Energy Dispersive X-ray (EDAX) Spectrometric analysis respectively. The sensitivity, response – recovery time of the sample towards ethanol (0 ppm – 300 ppm) sensing at room temperature was measured and the present investigation onmore » vanadium oxide nanoparticles over the flakes shows better sensitivity (30%) at room temperature.« less

Properties of mixed molybdenum oxide iridium oxide thin films synthesized by spray pyrolysis

NASA Astrophysics Data System (ADS)

Patil, P. S.; Kawar, R. K.; Sadale, S. B.; Inamdar, A. I.; Deshmukh, H. P.

2006-09-01

Molybdenum-doped iridium oxide thin films have been deposited onto corning glass- and fluorine-doped tin oxide coated corning glass substrates at 350 °C by using a pneumatic spray pyrolysis technique. An aqueous solution of 0.01 M ammonium molybdate was mixed with 0.01 M iridium trichloride solution in different volume proportions and the resultant solution was used as a precursor solution for spraying. The as-deposited samples were annealed at 600 °C in air medium for 1 h. The structural, electrical and optical properties of as-deposited and annealed Mo-doped iridium oxide were studied and values of room temperature electrical resistivity, and thermoelectric power were estimated. The as-deposited samples with 2% Mo doping exhibit more pronounced electrochromism than other samples, including pristine Ir oxide.

Excited states and electrochromism of radical cation of the carotenoid astaxanthin

NASA Astrophysics Data System (ADS)

Krawczyk, Stanisław

1998-09-01

Radical cations of the carotenoid astaxanthin were generated by chemical oxidation with Fe(Cl) 3, and their absorption and electroabsorption (Stark) spectra at temperatures about 150 K were recorded in the spectral range from 5900 to 26000 cm -1 (380 to 1700 nm), covering two absorptive electronic transitions from D 0 (ground) to D 1 and D 2 excited states. The changes in static polarizability are negative and equal -40±10 A 3 for D 0→D 1 and -105±15 A 3 for D 0→D 2, pointing that dominant contribution to polarizabilities results from the coupling of D 1 and D 2 with the ground state. An approximate localization of the next excited state with ground-state parity is estimated based on arguments from perturbation theory.

Room-temperature processed films of colloidal carved rod-shaped nanocrystals of reduced tungsten oxide as interlayers for perovskite solar cells.

PubMed

Masi, Sofia; Mastria, Rosanna; Scarfiello, Riccardo; Carallo, Sonia; Nobile, Concetta; Gambino, Salvatore; Sibillano, Teresa; Giannini, Cinzia; Colella, Silvia; Listorti, Andrea; Cozzoli, P Davide; Rizzo, Aurora

2018-04-25

Thanks to their high stability, good optoelectronic and extraordinary electrochromic properties, tungsten oxides are among the most valuable yet underexploited materials for energy conversion applications. Herein, colloidal one-dimensional carved nanocrystals of reduced tungsten trioxide (WO3-x) are successfully integrated, for the first time, as a hole-transporting layer (HTL) into CH3NH3PbI3 perovskite solar cells with a planar inverted device architecture. Importantly, the use of such preformed nanocrystals guarantees the facile solution-cast-only deposition of a homogeneous WO3-x thin film at room temperature, allowing achievement of the highest power conversion efficiency ever reported for perovskite solar cells incorporating raw and un-doped tungsten oxide based HTL.

Anodic iridium oxide films: An UPS study of emersed electrodes

NASA Astrophysics Data System (ADS)

Kötz, E. R.; Neff, H.

1985-09-01

Formation of anodic iridium oxide films has been monitored using Ultraviolet Photoemission Spectroscopy (UPS) of the emersed electrodes. The potential dependent valence band spectra clearly show the onset of oxide formation at about 0.6 V versus SCE. The density of states at the Fermi level and the positron of the Fermi level with respect to the maximum of the t 2g band of the oxide indicates a transition from metallic to semiconducting behaviour of the oxide. Protonation of the oxide is associated with increased emission from OH species. A linear correlation between electrode potential and workfunction change is observed for the metal as well as for the oxide. Our results confirm known band theory models and provide a fundamental understanding of the electrochromism of anodic iridium oxide films.

A photometric high-throughput method for identification of electrochemically active bacteria using a WO3 nanocluster probe.

PubMed

Yuan, Shi-Jie; He, Hui; Sheng, Guo-Ping; Chen, Jie-Jie; Tong, Zhong-Hua; Cheng, Yuan-Yuan; Li, Wen-Wei; Lin, Zhi-Qi; Zhang, Feng; Yu, Han-Qing

2013-01-01

Electrochemically active bacteria (EAB) are ubiquitous in environment and have important application in the fields of biogeochemistry, environment, microbiology and bioenergy. However, rapid and sensitive methods for EAB identification and evaluation of their extracellular electron transfer ability are still lacking. Herein we report a novel photometric method for visual detection of EAB by using an electrochromic material, WO(3) nanoclusters, as the probe. This method allowed a rapid identification of EAB within 5 min and a quantitative evaluation of their extracellular electron transfer abilities. In addition, it was also successfully applied for isolation of EAB from environmental samples. Attributed to its rapidness, high reliability, easy operation and low cost, this method has high potential for practical implementation of EAB detection and investigations.

Variability of the reflectance coefficient of skylight from the ocean surface and its implications to ocean color.

PubMed

Gilerson, Alexander; Carrizo, Carlos; Foster, Robert; Harmel, Tristan

2018-04-16

The value and spectral dependence of the reflectance coefficient (ρ) of skylight from wind-roughened ocean surfaces is critical for determining accurate water leaving radiance and remote sensing reflectances from shipborne, AERONET-Ocean Color and satellite observations. Using a vector radiative transfer code, spectra of the reflectance coefficient and corresponding radiances near the ocean surface and at the top of the atmosphere (TOA) are simulated for a broad range of parameters including flat and windy ocean surfaces with wind speeds up to 15 m/s, aerosol optical thicknesses of 0-1 at 440nm, wavelengths of 400-900 nm, and variable Sun and viewing zenith angles. Results revealed a profound impact of the aerosol load and type on the spectral values of ρ. Such impacts, not included yet in standard processing, may produce significant inaccuracies in the reflectance spectra retrieved from above-water radiometry and satellite observations. Implications for satellite cal/val activities as well as potential changes in measurement and data processing schemes are discussed.

Variability of adjacency effects in sky reflectance measurements.

PubMed

Groetsch, Philipp M M; Gege, Peter; Simis, Stefan G H; Eleveld, Marieke A; Peters, Steef W M

2017-09-01

Sky reflectance R sky (λ) is used to correct in situ reflectance measurements in the remote detection of water color. We analyzed the directional and spectral variability in R sky (λ) due to adjacency effects against an atmospheric radiance model. The analysis is based on one year of semi-continuous R sky (λ) observations that were recorded in two azimuth directions. Adjacency effects contributed to R sky (λ) dependence on season and viewing angle and predominantly in the near-infrared (NIR). For our test area, adjacency effects spectrally resembled a generic vegetation spectrum. The adjacency effect was weakly dependent on the magnitude of Rayleigh- and aerosol-scattered radiance. The reflectance differed between viewing directions 5.4±6.3% for adjacency effects and 21.0±19.8% for Rayleigh- and aerosol-scattered R sky (λ) in the NIR. Under which conditions in situ water reflectance observations require dedicated correction for adjacency effects is discussed. We provide an open source implementation of our method to aid identification of such conditions.

Quantifying the Significance of Heterogeneity in Supraglacial Reflectance Characteristics for Meltwater Production in Southwest Greenland

NASA Astrophysics Data System (ADS)

Irvine-Fynn, T. D.; Bunting, P.; Cook, J.; Hardy, A. J.; Hodson, A. J.; Holt, T.; Hubbard, A.; Naegeli, K.; Nilsson, J.; Ryan, J.; Roberts, O.; Tedstone, A.; Tranter, M.; Williamson, C.

2017-12-01

The seasonal melt on the southwestern margin of the Greenland Ice Sheet has been enhanced due to processes affecting the ablation area's ice surface reflectance (albedo). Recent trends in surface reflectance in the region suggest a decline potentially linked to an albedo-feedback associated with regional climate warming, emergence of organic and mineral particulates, and expansion of melt area. However, the heterogeneity of reflectance over bare ice areas in space and time has remained relatively poorly characterised. Numerous surface mass balance models utilise albedo products derived from remote sensing platforms with coarse scale resolution. Such products provide reasonable albedo estimates, but quantification of local variability in reflectance remains lacking. Consequently, there is a need to better define the distribution and representativeness of ice surface reflectance at and below the scale of satellite sensor pixel footprints to facilitate examination of albedo parameterisations. Here, we present reflectance data repeatedly collected in SW Greenland during the 2016 summer melt season over a 0.0625 km2 area proximate to the IMAU K-transect site S6 (67°04.5'N, 49°21.0'W). The Moderate Resolution Imaging Spectrometer (MODIS) albedo product MOD10A1(c6) for the study site was compared to reflectance data from Sentinel-2, centimetre resolution calibrated 12Mpix optical imagery collected using an Unmanned Aerial Vehicle (UAV) flown at a height of 70 m above the ice surface, and ground-based reflectance survey data acquired using a StellarNet Red-Dwarf/Blue-Wave visible-infrared dual system (250-1700nm) at 30 sites distributed over the area of interest. Our data highlight variability in the spatial distribution of ice surface reflectance characteristics over time. Specifically, data demonstrate marked changes in the distribution of reflectance values, despite maintaining a broadly equitable mean and median during July and August. The influence of the varied surface heterogeneity is explored further using surface energy balance modelling to quantify the impact of such changes on melt production. The findings determine the necessity to account for local variability underlying the pixel-averaged values retrieved from remote sensing platforms such as MODIS.

UV reflectance is associated with environmental conditions in Palaearctic Pieris napi (Lepidoptera: Pieridae).

PubMed

Stella, David; Pecháček, Pavel; Meyer-Rochow, Victor Benno; Kleisner, Karel

2018-06-01

The subject of our investigation was the visual features of wing color with special focus on the UV reflectance in the green-veined white butterfly (Pieris napi). Previous studies had concluded that UV reflectance on dorsal wing surfaces is found only in the female P. napi. Based on UV sensitive photography, we analyzed a correlation between 12 geographic and environmental factors and UV reflectance patterns on 3 patches on the forewings of 407 P. napi specimens from the Palaearctic region. Results had shown that females significantly differ from males: they exhibit a 25% higher UV reflectance. To investigate whether and how UV reflectance levels on the forewings and hindwings of both sexes are influenced by the environment, we performed a principal component analysis (PCA) with several environmental variables. For several variables (in particular, latitude and longitude, mean annual temperature and precipitation, and temperature annual range and altitude), the generalized linear model (GLM) model revealed a significant correlation in both sexes. This suggests a link between UV reflectance levels and the environment and distribution of P. napi. We found that stronger UV reflectance is associated with generally more hostile environments and concluded that large-scale environmental factors influence the UV reflectance on the forewings of both male and female green-veined white butterflies. © 2016 Institute of Zoology, Chinese Academy of Sciences.

Adjustment of prior constraints for an improved crop monitoring with the Earth Observation Land Data Assimilation System (EO-LDAS)

NASA Astrophysics Data System (ADS)

Truckenbrodt, Sina C.; Gómez-Dans, José; Stelmaszczuk-Górska, Martyna A.; Chernetskiy, Maxim; Schmullius, Christiane C.

2017-04-01

Throughout the past decades various satellite sensors have been launched that record reflectance in the optical domain and facilitate comprehensive monitoring of the vegetation-covered land surface from space. The interaction of photons with the canopy, leaves and soil that determines the spectrum of reflected sunlight can be simulated with radiative transfer models (RTMs). The inversion of RTMs permits the derivation of state variables such as leaf area index (LAI) and leaf chlorophyll content from top-of-canopy reflectance. Space-borne data are, however, insufficient for an unambiguous derivation of state variables and additional constraints are required to resolve this ill-posed problem. Data assimilation techniques permit the conflation of various information with due allowance for associated uncertainties. The Earth Observation Land Data Assimilation System (EO-LDAS) integrates RTMs into a dynamic process model that describes the temporal evolution of state variables. In addition, prior information is included to further constrain the inversion and enhance the state variable derivation. In previous studies on EO-LDAS, prior information was represented by temporally constant values for all investigated state variables, while information about their phenological evolution was neglected. Here, we examine to what extent the implementation of prior information reflecting the phenological variability improves the performance of EO-LDAS with respect to the monitoring of crops on the agricultural Gebesee test site (Central Germany). Various routines for the generation of prior information are tested. This involves the usage of data on state variables that was acquired in previous years as well as the application of phenological models. The performance of EO-LDAS with the newly implemented prior information is tested based on medium resolution satellite imagery (e.g., RapidEye REIS, Sentinel-2 MSI, Landsat-7 ETM+ and Landsat-8 OLI). The predicted state variables are validated against in situ data from the Gebesee test site that were acquired with a weekly to fortnightly resolution throughout the growing seasons of 2010, 2013, 2014 and 2016. Furthermore, the results are compared with the outcome of using constant values as prior information. In this presentation, the EO-LDAS scheme and results obtained from different prior information are presented.

Understanding the contribution of phytoplankton phase functions to uncertainties in the water colour signal.

PubMed

Lain, Lisl Robertson; Bernard, Stewart; Matthews, Mark W

2017-02-20

The accurate description of a water body's volume scattering function (VSF), and hence its phase functions, is critical to the determination of the constituent inherent optical properties (IOPs), the associated spectral water-leaving reflectance, and consequently the retrieval of phytoplankton functional type (PFT) information. The equivalent algal populations (EAP) model has previously been evaluated for phytoplankton-dominated waters, and offers the ability to provide phytoplankton population-specific phase functions, unveiling a new opportunity to further understanding of the causality of the PFT signal. This study presents and evaluates the wavelength dependent, spectrally variable EAP particle phase functions and the subsequent effects on water-leaving reflectance. Comparisons are made with frequently used phase function approximations e.g. the Fournier Forand formulation, as well as with phase functions inferred from measured VSFs in coastal waters. Relative differences in shape and magnitude are quantified. Reflectance modelled with the EAP phase functions is then compared against measured reflectance data from phytoplankton-dominated waters. Further examples of modelled phytoplankton-dominated waters are discussed with reference to choice of phase function for two PFTs (eukaryote and prokaryote) across a range of biomass. Finally a demonstration of the sensitivity of reflectance due to the choice of phase function is presented. The EAP model phase functions account for both spectral and angular variability in phytoplankton backscattering i.e. they display variability which is both spectral and shape-related. It is concluded that phase functions modelled in this way are necessary for investigating the effects of assemblage variability on the ocean colour signal, and should be considered for model closure even in relatively low scattering conditions where phytoplankton dominate the IOPs.

Experimental demonstration of localized Brillouin gratings with low off-peak reflectivity established by perfect Golomb codes.

PubMed

Antman, Yair; Yaron, Lior; Langer, Tomi; Tur, Moshe; Levanon, Nadav; Zadok, Avi

2013-11-15

Dynamic Brillouin gratings (DBGs), inscribed by comodulating two writing pump waves with a perfect Golomb code, are demonstrated and characterized experimentally. Compared with pseudo-random bit sequence (PRBS) modulation of the pump waves, the Golomb code provides lower off-peak reflectivity due to the unique properties of its cyclic autocorrelation function. Golomb-coded DBGs allow the long variable delay of one-time probe waveforms with higher signal-to-noise ratios, and without averaging. As an example, the variable delay of return-to-zero, on-off keyed data at a 1 Gbit/s rate, by as much as 10 ns, is demonstrated successfully. The eye diagram of the reflected waveform remains open, whereas PRBS modulation of the pump waves results in a closed eye. The variable delay of data at 2.5 Gbit/s is reported as well, with a marginally open eye diagram. The experimental results are in good agreement with simulations.

Trinuclear ruthenium dioxolene complexes based on the bridging ligand hexahydroxytriphenylene: electrochemistry, spectroscopy, and near-infrared electrochromic behaviour associated with a reversible seven-membered redox chain.

PubMed

Grange, Christopher S; Meijer, Anthony J H M; Ward, Michael D

2010-01-07

The trinuclear complexes [{(R2bipy)2Ru}3(mu3-HHTP)](PF6)3 [1(PF6)3, R = H; 2(PF6)3, R = 4-tBu] contain three {Ru(R2bipy)2}2+ fragments connected to the triangular tris-chelating ligand hexahydroxytriphenylene (H6HHTP). This bridging ligand contains three dioxolene-type binding sites, each of which can reversibly convert between dianionic catecholate (cat), monoanionic semiquinone (sq) or neutral quinone (q) redox states. The bridging ligand as a whole can therefore exist in seven different redox states from fully reduced [cat,cat,cat]6- through to fully oxidised, neutral [q,q,q]. Cyclic voltammetry of 1(PF6)3 in MeCN reveals six redox processes of which the three at more positive potentials (the sq/q couples) are reversible but the three at more negative potentials (the sq/cat couples) are irreversible with distorted wave shapes due to the insolubility of the reduced forms of the complex. In contrast, the more soluble complex 2(PF6)3 displays six reversible one-electron redox processes making all components of a seven-membered redox chain accessible. UV/Vis/NIR spectro-electrochemical studies reveal rich spectroscopic behaviour, with--in particular--very intense transitions in the near-IR region in many of the oxidation states associated with Ru(II)-->(dioxolene) MLCT and bridging ligand centred pi-pi* transitions. TDDFT calculations were used to analyse the electronic spectra in all seven oxidation states; the calculated spectra generally show very good agreement with experiment, which has allowed a fairly complete assignment of the low-energy transitions. The strong electrochromism of the complexes in the near-IR region has formed the basis of an optical window in which a thin film of 1(PF6)3 or 2(PF6)3 on a conductive glass surface can be reversibly and rapidly switched between redox states that alternate between strongly absorbing or near-transparent at 1100 nm, with--for 2(PF6)3--the switching being stable and reversible in water over thousands of cycles.

Relationship between reflection ability and clinical performance: a cross-sectional and retrospective-longitudinal correlational cohort study in midwifery.

PubMed

Embo, M; Driessen, E; Valcke, M; van der Vleuten, C P M

2015-01-01

increasingly, reflection is highlighted as integral to core practice competencies but empirical research into the relationship between reflection and performance in the clinical workplace is scarce. this study investigated the relationship between reflection ability and clinical performance. we designed a cross-sectional and a retrospective-longitudinal cohort study. Data from first, second and third year midwifery students were collected to study the variables 'clinical performance' and 'reflection ability'. Data were analysed with SPSS for Windows, Release 20.0. Descriptive statistics, Pearson׳s Product Moment Correlation Coefficients (r) and r² values were computed to investigate associations between the research variables. the results showed a moderate observed correlation between reflection ability and clinical performance scores. When adopting a cross-sectional perspective, all correlation values were significant (p<0.01) and above 0.4, with the exception of the third year correlations. Assuming perfect reliability in the measurement, the adjusted correlations, for year 2 and year 3 indicated a high association between reflection ability and clinical performance (>0.6). The results based on the retrospective-longitudinal data set explained a moderate proportion of the variance after correction for attenuation. Finally, the results indicate that 'reflection ability' scores of earlier years are significant related with 'clinical performance' scores of subsequent years. These results suggest that (1) reflection ability is linked to clinical performance; (2) that written reflections are an important, but not the sole way to assess professional competence and that (3) reflection is a contributor to clinical performance improvement. the data showed a moderate but significant relationship between 'reflection ability' and 'clinical performance' scores in clinical practice of midwifery students. Reflection therefore seems an important component of professional competence. Copyright © 2014 Elsevier Ltd. All rights reserved.

Perceiver and relationship effects on perceptions of HIV status: A naturalistic study in a high drug use sample.

PubMed

Montoya, Isaac D; Bell, David C

2006-11-01

This article examines the effect of target, perceiver, and relationship characteristics on the perceiver's assessment that the target may be HIV seropositive (HIV+). A sample of 267 persons was recruited from low income, high drug use neighborhoods. Respondents (perceivers) were asked to name people (targets) with whom they had a social, drug sharing, or sexual relationship. Perceivers described 1,640 such relationships. Perceivers were asked about the targets' age, gender, and race/ethnicity, whether the targets were good-looking, their level of trust with the target, and how long they had known them. Perceivers were then asked to evaluate the chances that the target mentioned was HIV+. Two regression models were estimated on the 1,640 relationships mentioned. Model 1 included variables reflecting only target characteristics as independent variables. Model 2 included variables reflecting target characteristics as well as variables reflecting perceivers and perceiver-target relationship characteristics. The results showed that targets that were female, younger, and good-looking were perceived as being less likely to be HIV+. However, when accounting for perceiver and relationship effects, some of the target characteristic effects disappeared. Copyright 2006 APA, all rights reserved.

The conceptualization and measurement of cognitive reserve using common proxy indicators: Testing some tenable reflective and formative models.

PubMed

Ikanga, Jean; Hill, Elizabeth M; MacDonald, Douglas A

2017-02-01

The examination of cognitive reserve (CR) literature reveals a lack of consensus regarding conceptualization and pervasive problems with its measurement. This study aimed at examining the conceptual nature of CR through the analysis of reflective and formative models using eight proxies commonly employed in the CR literature. We hypothesized that all CR proxies would significantly contribute to a one-factor reflective model and that educational and occupational attainment would produce the strongest loadings on a single CR factor. The sample consisted of 149 participants (82 male/67 female), with 18.1 average years of education and ages of 45-99 years. Participants were assessed for eight proxies of CR (parent socioeconomic status, intellectual functioning, level of education, health literacy, occupational prestige, life leisure activities, physical activities, and spiritual and religious activities). Primary statistical analyses consisted of confirmatory factor analysis (CFA) to test reflective models and structural equation modeling (SEM) to evaluate multiple indicators multiple causes (MIMIC) models. CFA did not produce compelling support for a unitary CR construct when using all eight of our CR proxy variables in a reflective model but fairly cogent evidence for a one-factor model with four variable proxies. A second three-factor reflective model based upon an exploratory principal components analysis of the eight proxies was tested using CFA. Though all eight indicators significantly loaded on their assigned factors, evidence in support of overall model fit was mixed. Based upon the results involving the three-factor reflective model, two alternative formative models were developed and evaluated. While some support was obtained for both, the model in which the formative influences were specified as latent variables appeared to best account for the contributions of all eight proxies to the CR construct. While the findings provide partial support for our hypothesis regarding CR as a one-dimensional reflective construct, the results strongly suggest that the construct is more complex than what can be captured in a reflective model alone. There is a need for theory to better identify and differentiate formative from reflective indicators and to articulate the mechanisms by which CR develops and operates.

Technique for ship/wake detection

DOEpatents

Roskovensky, John K [Albuquerque, NM

2012-05-01

An automated ship detection technique includes accessing data associated with an image of a portion of Earth. The data includes reflectance values. A first portion of pixels within the image are masked with a cloud and land mask based on spectral flatness of the reflectance values associated with the pixels. A given pixel selected from the first portion of pixels is unmasked when a threshold number of localized pixels surrounding the given pixel are not masked by the cloud and land mask. A spatial variability image is generated based on spatial derivatives of the reflectance values of the pixels which remain unmasked by the cloud and land mask. The spatial variability image is thresholded to identify one or more regions within the image as possible ship detection regions.

Metacognitive self-reflectivity moderates the relationship between distress tolerance and empathy in schizophrenia.

PubMed

Bonfils, Kelsey A; Minor, Kyle S; Leonhardt, Bethany L; Lysaker, Paul H

2018-07-01

Deficits in empathy seen in schizophrenia are thought to play a major role in the social dysfunction seen in the disorder. However, little work has investigated potential determinants of empathic deficits. This study aimed to fill that gap by examining the effects of two variables on empathy - distress tolerance and metacognitive self-reflectivity. Fifty-four people with schizophrenia-spectrum disorders receiving services at an urban VA or community mental health center were assessed for empathy, metacognition, and distress tolerance. Bivariate correlations and moderation methods were used to ascertain associations amongst these variables and examine interactions. Results revealed that, against hypotheses, empathy was not related at the bivariate level to either distress tolerance or metacognitive self-reflectivity. However, consistent with hypotheses, moderation analyses revealed that participants with higher self-reflectivity showed no relationship between distress tolerance and empathy, while those with lower self-reflectivity showed a relationship such that reduced ability to tolerate distress predicted reduced empathy. Taken together, results of this study suggest that lack of distress tolerance can negatively affect empathy in people with schizophrenia with lesser capacity for metacognitive self-reflection; thus, fostering self-reflectivity may help overcome that negative impact. Future work is needed investigating the impact of metacognitively-tailored interventions on empathy in this population. Copyright © 2018. Published by Elsevier B.V.

Safety parameters for avoiding acute ocular damage from the reflected CO2 (10.6 microns) laser beam.

PubMed

Friedman, N R; Saleeby, E R; Rubin, M G; Sandu, T; Krull, E A

1987-11-01

Reflections from instruments in the surgical field involving the CO2 laser beam present a serious ocular hazard. In addition to the use of plastic or glass protective eyewear, this hazard can be minimized by utilizing anodized instruments and recognizing the specific distances at which various reflections are no longer hazardous depending upon certain variables, including laser output wattage, emergent beam lengths, and surface characteristics of the reflecting instruments.

Radiative transfer in shrub savanna sites in Niger: Preliminary results from HAPEX-Sahel. Part 1: Modelling surface reflectance using a geometric-optical approach

NASA Technical Reports Server (NTRS)

Franklin, Janet; Duncan, Jeff; Huete, Alfredo R.; vanLeeuwen, W. J. D.; Li, Xiaowen; Begue, Agnes

1994-01-01

To use optical remote sensing to monitor land surface-climate interactions over large areas, algorithms must be developed to relate multispectral measurements to key variables controlling the exchange of matter (water, carbon dioxide) and energy between the land surface and the atmosphere. The proportion of the ground covered by vegetation and the interception of photosynthetically active radiation (PAR) by vegetation are examples of two variables related to evapotranspiration and primary production, respectively. An areal-proportion model of the multispectral reflectance of shrub savanna, composed of scattered shrubs with a grass, forb or soil understory, predicted the reflectance of two 0.5 km(exp 2) sites as the area-weighted average of the shrub and understory or 'background' reflectances. Although the shaded crown and shaded background have darker reflectances, ignoring them in the area-weighted model is not serious when shrub cover is low and solar zenith angle is small. A submodel predicted the reflectance of the shrub crown as a function of the foliage reflectance and amount of plant material within the crown, and the background reflectance scattered or transmitted through canopy gaps (referred to as a soil-plant 'spectral interaction' term). One may be able to combine these two models to estimate both the fraction of vegetation cover and interception of PAR by green vegetation in a shrub savanna.

A climatology of visible surface reflectance spectra

NASA Astrophysics Data System (ADS)

Zoogman, Peter; Liu, Xiong; Chance, Kelly; Sun, Qingsong; Schaaf, Crystal; Mahr, Tobias; Wagner, Thomas

2016-09-01

We present a high spectral resolution climatology of visible surface reflectance as a function of wavelength for use in satellite measurements of ozone and other atmospheric species. The Tropospheric Emissions: Monitoring of Pollution (TEMPO) instrument is planned to measure backscattered solar radiation in the 290-740 nm range, including the ultraviolet and visible Chappuis ozone bands. Observation in the weak Chappuis band takes advantage of the relative transparency of the atmosphere in the visible to achieve sensitivity to near-surface ozone. However, due to the weakness of the ozone absorption features this measurement is more sensitive to errors in visible surface reflectance, which is highly variable. We utilize reflectance measurements of individual plant, man-made, and other surface types to calculate the primary modes of variability of visible surface reflectance at a high spectral resolution, comparable to that of TEMPO (0.6 nm). Using the Moderate-resolution Imaging Spectroradiometer (MODIS) Bidirection Reflectance Distribution Function (BRDF)/albedo product and our derived primary modes we construct a high spatial resolution climatology of wavelength-dependent surface reflectance over all viewing scenes and geometries. The Global Ozone Monitoring Experiment-2 (GOME-2) Lambertian Equivalent Reflectance (LER) product provides complementary information over water and snow scenes. Preliminary results using this approach in multispectral ultraviolet+visible ozone retrievals from the GOME-2 instrument show significant improvement to the fitting residuals over vegetated scenes.

Millennial-scale climate variations recorded in Early Pliocene colour reflectance time series from the lacustrine Ptolemais Basin (NW Greece)

NASA Astrophysics Data System (ADS)

Steenbrink, J.; Kloosterboer-van Hoeve, M. L.; Hilgen, F. J.

2003-03-01

Quaternary climate proxy records show compelling evidence for climate variability on time scales of a few thousand years. The causes for these millennial-scale or sub-Milankovitch cycles are still poorly understood, not least due to the complex feedback mechanisms of large ice sheets during the Quaternary. We present evidence of millennial-scale climate variability in Early Pliocene lacustrine sediments from the intramontane Ptolemais Basin in northwestern Greece. The sediments are well exposed in a series of open-pit lignite mines and exhibit a distinct millennial-scale sedimentary cyclicity of alternating lignites and lacustrine marl beds that resulted from precession-induced variations in climate. The higher-frequency, millennial-scale cyclicity is particularly prominent within the grey-coloured marl segment of individual cycles. A stratigraphic interval of ˜115 ka, covering five precession-induced sedimentary cycles, was studied in nine parallel sections from two open-pit lignite mines located several km apart. High-resolution colour reflectance records were used to quantify the within-cycle variability and to determine its lateral continuity. Much of the within-cycle variability could be correlated between the parallel sections, even in fine detail, which suggests that these changes reflect basin-wide variations in environmental conditions related to (regional) climate fluctuations. Interbedded volcanic ash beds demonstrate the synchronicity of these fluctuations and spectral analysis of the reflectance time series shows a significant concentration of within-cycle variability at periods of ˜11, ˜5.5 and ˜2 ka. The occurrence of variability at such time scales at times before the intensification of the Northern Hemisphere glaciation suggests that they cannot solely have resulted from internal ice-sheet dynamics. Possible candidates include harmonics or combination tones of the main orbital cycles, variations in solar output or periodic motions of the Earth and Moon.

Drought monitoring using remote sensing of evapotranspiration

USDA-ARS?s Scientific Manuscript database

Drought assessment is a complex endeavor, requiring monitoring of deficiencies in multiple components of the hydrologic budget. Precipitation anomalies reflect variability in water supply to the land surface, while soil moisture (SM), ground and surface water anomalies reflect deficiencies in moist...

Assessment of Oco-2 Target Mode Vulnerability Against Horizontal Variability of Surface Reflectivity Neglected in the Operational Forward Model

NASA Astrophysics Data System (ADS)

Davis, A. B.; Qu, Z.

2014-12-01

The main goal of NASA's OCO-2 mission is to perform XCO2 column measurements from space with an unprecedented (~1 ppm) precision and accuracy that will enable modelers to globally map CO2 sources and sinks. To achieve this goal, the mission is critically dependent on XCO2product validation that, in turn, is highly dependent on successful use of OCO-2's "target mode" data acquisition. In target mode, OCO-2 rotates in such a way that, as long as it is above the horizon, it looks at a Total Carbon Column Observing Network (TCCON) station equipped with a powerful Fourier Transform spectrometer. TCCON stations measure, among other things, XCO2by looking straight at the Sun. This translates to a far simpler forward model for TCCON than for OCO-2. In the ideal world, OCO-2's spectroscopic signals result from the cumulative gaseous absorption for one direct transmission of sunlight to the ground (like for TCCON), followed by one diffuse reflection, and one direct transmission to the instrument—at a variety of viewing angles in traget mode. In the real world, all manner of multiple surface reflections and/or scatterings contribute to the signal. See figure. In the idealized world of the OCO-2 operational forward model (used in nadir, glint and target modes), the horizontal variability of the scattering atmosphere and reflecting surface are ignored, leading to the adoption of a 1D vector radiative transfer (vRT) model. This is the source of forward model error that we are investigating, with a focus on target mode. In principle, atmospheric variability in the horizontal plane—largely due to clouds—can be avoided by careful screening. Also, it is straightforward to account for angular variability of the surface reflection model in the 1D vRT framework. But it is not clear how unavoidable horizontal variations of the surface reflectivity affects the OCO-2 signal, even if the reflection was isotropic (Lambertian). To characterize this OCO-2 "adjacency" effect, we use a simple surface variability model with a single spatial frequency in each direction, and a single albedo contrast at a time for realistic aerosol and gaseous profiles. This specific 3D RT error is compared with other documented forward model errors and translated into XCO2 error in ppm, for programatic consideration and eventual mitigation.

Polarization and long-term variability of Sgr A* X-ray echo

NASA Astrophysics Data System (ADS)

Churazov, E.; Khabibullin, I.; Ponti, G.; Sunyaev, R.

2017-06-01

We use a model of the molecular gas distribution within ˜100 pc from the centre of the Milky Way (Kruijssen, Dale & Longmore) to simulate time evolution and polarization properties of the reflected X-ray emission, associated with the past outbursts from Sgr A*. While this model is too simple to describe the complexity of the true gas distribution, it illustrates the importance and power of long-term observations of the reflected emission. We show that the variable part of X-ray emission observed by Chandra and XMM-Newton from prominent molecular clouds is well described by a pure reflection model, providing strong support of the reflection scenario. While the identification of Sgr A* as a primary source for this reflected emission is already a very appealing hypothesis, a decisive test of this model can be provided by future X-ray polarimetric observations, which will allow placing constraints on the location of the primary source. In addition, X-ray polarimeters (like, e.g. XIPE) have sufficient sensitivity to constrain the line-of-sight positions of molecular complexes, removing major uncertainty in the model.

Dissociation in Response to Methylphenidate on Response Variability in a Group of Medication Naive Children with ADHD

ERIC Educational Resources Information Center

Johnson, Katherine A.; Barry, Edwina; Bellgrove, Mark A.; Cox, Marie; Kelly, Simon P.; Daibhis, Aoife; Daly, Michael; Keavey, Michelle; Watchorn, Amy; Fitzgerald, Michael; McNicholas, Fiona; Kirley, Aiveen; Robertson, Ian H.; Gill, Michael

2008-01-01

Increased variability in reaction time (RT) has been proposed as a cardinal feature of attention deficit hyperactivity disorder (ADHD). Increased variability during sustained attention tasks may reflect inefficient fronto-striatal and fronto-parietal circuitry; activity within these circuits is modulated by the catecholamines. A disruption to…

Investigation of Acoustic Vector Sensor Data Processing in the Presence of Highly Variable Bathymetry

DTIC Science & Technology

2014-06-01

shelf 10 region to the north of the canyon. The impact of this 3-dimensional (3D) variable bathymetry, which may be combined with the effects of...weaker arrivals at large negative angles, consistent with the earliest bottom reflections on the left. The impact of the bottom-path reflections from...nzout*(nrout+1)*ny))),’bof’); for ifr =1:64, for ir=1:nrout+1, for iy=1:ny, data=fread(fid3,2*nzout,’float32’); fwrite(fid,data

No Photon Left Behind: Advanced Optics at ARPA-E for Buildings and Solar Energy

NASA Astrophysics Data System (ADS)

Branz, Howard M.

2015-04-01

Key technology challenges in building efficiency and solar energy utilization require transformational optics, plasmonics and photonics technologies. We describe advanced optical technologies funded by the Advanced Research Projects Agency - Energy. Buildings technologies include a passive daytime photonic cooler, infra-red computer vision mapping for energy audit, and dual-band electrochromic windows based on plasmonic absorption. Solar technologies include novel hybrid energy converters that combine high-efficiency photovoltaics with concentrating solar thermal collection and storage. Because the marginal cost of thermal energy storage is low, these systems enable generation of inexpensive and dispatchable solar energy that can be deployed when the sun doesn't shine. The solar technologies under development include nanoparticle plasmonic spectrum splitting, Rugate filter interference structures and photovoltaic cells that can operate efficiently at over 400° C.

Method for preparing dioxyheterocycle-based electrochromic polymers

DOE Office of Scientific and Technical Information (OSTI.GOV)

Reynolds, John R.; Estrada, Leandro; Deininger, James

A method for preparing a conjugated polymer involves a DHAP polymerization of a 3,4-dioxythiophene, 3,4-dioxyfuran, or 3,4-dioxypyrrole and, optionally, at least one second conjugated monomer in the presence of a Pd or Ni comprising catalyst, an aprotic solvent, a carboxylic acid at a temperature in excess of 120.degree. C. At least one of the monomers is substituted with hydrogen reactive functionalities and at least one of the monomers is substituted with a Cl, Br, and/or I. The polymerization can be carried out at temperature of 140.degree. C. or more, and the DHAP polymerization can be carried out without a phosphinemore » ligand or a phase transfer agent. The resulting polymer can display dispersity less than 2 and have a degree of polymerization in excess of 10.« less

Imaging voltage in neurons

PubMed Central

Peterka, Darcy S.; Takahashi, Hiroto; Yuste, Rafael

2011-01-01

In the last decades, imaging membrane potential has become a fruitful approach to study neural circuits, especially in invertebrate preparations with large, resilient neurons. At the same time, particularly in mammalian preparations, voltage imaging methods suffer from poor signal to noise and secondary side effects, and they fall short of providing single-cell resolution when imaging of the activity of neuronal populations. As an introduction to these techniques, we briefly review different voltage imaging methods (including organic fluorophores, SHG chromophores, genetic indicators, hybrid, nanoparticles and intrinsic approaches), and illustrate some of their applications to neuronal biophysics and mammalian circuit analysis. We discuss their mechanisms of voltage sensitivity, from reorientation, electrochromic or electro-optical phenomena, to interaction among chromophores or membrane scattering, and highlight their advantages and shortcomings, commenting on the outlook for development of novel voltage imaging methods. PMID:21220095

DOE Office of Scientific and Technical Information (OSTI.GOV)

Jiang, Qinglong; Chen, Mingming; Li, Junqiang

Halide perovskites have recently been investigated for various solution-processed optoelectronic devices. The majority of studies have focused on using intrinsic halide perovskites, and the intentional incoporation of dopants has not been well explored. In this work, we discovered that small alkali ions, including lithium and sodium ions, could be electrochemically intercalated into a variety of halide and pseudohalide perovskites. The ion intercalation caused a lattice expansion of the perovskite crystals and resulted in an n-type doping of the perovskites. Such electrochemical doping improved the conductivity and changed the color of the perovskites, leading to an electrochromism with more than 40%more » reduction of transmittance in the 450–850 nm wavelength range. The doped perovskites exhibited improved electron injection efficiency into the pristine perovskite crystals, resulting in bright light-emitting diodes with a low turn-on voltage.« less

Electrochemical Doping of Halide Perovskites with Ion Intercalation.

PubMed

Jiang, Qinglong; Chen, Mingming; Li, Junqiang; Wang, Mingchao; Zeng, Xiaoqiao; Besara, Tiglet; Lu, Jun; Xin, Yan; Shan, Xin; Pan, Bicai; Wang, Changchun; Lin, Shangchao; Siegrist, Theo; Xiao, Qiangfeng; Yu, Zhibin

2017-01-24

Halide perovskites have recently been investigated for various solution-processed optoelectronic devices. The majority of studies have focused on using intrinsic halide perovskites, and the intentional incoporation of dopants has not been well explored. In this work, we discovered that small alkali ions, including lithium and sodium ions, could be electrochemically intercalated into a variety of halide and pseudohalide perovskites. The ion intercalation caused a lattice expansion of the perovskite crystals and resulted in an n-type doping of the perovskites. Such electrochemical doping improved the conductivity and changed the color of the perovskites, leading to an electrochromism with more than 40% reduction of transmittance in the 450-850 nm wavelength range. The doped perovskites exhibited improved electron injection efficiency into the pristine perovskite crystals, resulting in bright light-emitting diodes with a low turn-on voltage.

Chromogenic switchable glazing: Towards the development of the smart window

DOE Office of Scientific and Technical Information (OSTI.GOV)

Lampert, C.M.

1995-06-01

The science and technology of chromogenic materials for switchable glazings in building applications is discussed. These glazings can be used for dynamic control of solar and visible energy. Currently many researchers and engineers are involved with the development of products in this field. A summary of activities in Japan, Europe, Australia, USA and Canada is made. The activities of the International Energy Agency are included. Both non-electrically activated and electrically activated glazings are discussed. Technologies covered in the first category are photochromics, and thermochromics and thermotropics. A discussion of electrically activated chromogenic glazings includes dispersed liquid crystals, dispersed particles andmore » electrochromics. A selection of device structures and performance characteristics are compared. A discussion of transparent conductors is presented. Technical issues concerning large-area development of smart windows are discussed.« less

Comparison of laboratory and field remote sensing methods to measure forage quality.

PubMed

Guo, Xulin; Wilmshurst, John F; Li, Zhaoqin

2010-09-01

Recent research in range ecology has emphasized the importance of forage quality as a key indicator of rangeland condition. However, we lack tools to evaluate forage quality at scales appropriate for management. Using canopy reflectance data to measure forage quality has been conducted at both laboratory and field levels separately, but little work has been conducted to evaluate these methods simultaneously. The objective of this study is to find a reliable way of assessing grassland quality through measuring forage chemistry with reflectance. We studied a mixed grass ecosystem in Grasslands National Park of Canada and surrounding pastures, located in southern Saskatchewan. Spectral reflectance was collected at both in-situ field level and in the laboratory. Vegetation samples were collected at each site, sorted into the green grass portion, and then sent to a chemical company for measuring forage quality variables, including protein, lignin, ash, moisture at 135 °C, Neutral Detergent Fiber (NDF), Acid Detergent Fiber (ADF), Total Digestible, Digestible Energy, Net Energy for Lactation, Net Energy for Maintenance, and Net Energy for Gain. Reflectance data were processed with the first derivative transformation and continuum removal method. Correlation analysis was conducted on spectral and forage quality variables. A regression model was further built to investigate the possibility of using canopy spectral measurements to predict the grassland quality. Results indicated that field level prediction of protein of mixed grass species was possible (r² = 0.63). However, the relationship between canopy reflectance and the other forage quality variables was not strong.

Physically-based parameterization of spatially variable soil and vegetation using satellite multispectral data

NASA Technical Reports Server (NTRS)

Jasinski, Michael F.; Eagleson, Peter S.

1989-01-01

A stochastic-geometric landsurface reflectance model is formulated and tested for the parameterization of spatially variable vegetation and soil at subpixel scales using satellite multispectral images without ground truth. Landscapes are conceptualized as 3-D Lambertian reflecting surfaces consisting of plant canopies, represented by solid geometric figures, superposed on a flat soil background. A computer simulation program is developed to investigate image characteristics at various spatial aggregations representative of satellite observational scales, or pixels. The evolution of the shape and structure of the red-infrared space, or scattergram, of typical semivegetated scenes is investigated by sequentially introducing model variables into the simulation. The analytical moments of the total pixel reflectance, including the mean, variance, spatial covariance, and cross-spectral covariance, are derived in terms of the moments of the individual fractional cover and reflectance components. The moments are applied to the solution of the inverse problem: The estimation of subpixel landscape properties on a pixel-by-pixel basis, given only one multispectral image and limited assumptions on the structure of the landscape. The landsurface reflectance model and inversion technique are tested using actual aerial radiometric data collected over regularly spaced pecan trees, and using both aerial and LANDSAT Thematic Mapper data obtained over discontinuous, randomly spaced conifer canopies in a natural forested watershed. Different amounts of solar backscattered diffuse radiation are assumed and the sensitivity of the estimated landsurface parameters to those amounts is examined.

The structure of red-infrared scattergrams of semivegetated landscapes

NASA Technical Reports Server (NTRS)

Jasinski, Michael F.; Eagleson, Peter S.

1988-01-01

A physically based linear stochastic geometric canopy soil reflectance model is presented for characterizing spatial variability of semivegetated landscapes at subpixel and regional scales. Landscapes are conceptualized as stochastic geometric surfaces, incorporating not only the variability in geometric elements, but also the variability in vegetation and soil background reflectance which can be important in some scenes. The model is used to investigate several possible mechanisms which contribute to the often observed characteristic triangular shape of red-infrared scattergrams of semivegetated landscapes. Scattergrams of simulated and semivegetated scenes are analyzed with respect to the scales of the satellite pixel and subpixel components. Analysis of actual aerial radiometric data of a pecan orchard is presented in comparison with ground observations as preliminary confirmation of the theoretical results.

The structure of red-infrared scattergrams of semivegetated landscapes

NASA Technical Reports Server (NTRS)

Jasinski, Michael F.; Eagleson, Peter S.

1989-01-01

A physically based linear stochastic geometric canopy soil reflectance model is presented for characterizing spatial variability of semivegetated landscapes at subpixel and regional scales. Landscapes are conceptualized as stochastic geometric surfaces, incorporating not only the variability in geometric elements, but also the variability in vegetation and soil background reflectance which can be important in some scenes. The model is used to investigate several possible mechanisms which contribute to the often observed characteristic triangular shape of red-infrared scattergrams of semivegetated landscapes. Scattergrams of simulated semivegetated scenes are analyzed with respect to the scales of the satellite pixel and subpixel components. Analysis of actual aerial radiometric data of a pecan orchard is presented in comparison with ground observations as preliminary confirmation of the theoretical results.

Justifying scale type for a latent variable: Formative or reflective?

NASA Astrophysics Data System (ADS)

Liu, Hao; Bahron, Arsiah; Bagul, Awangku Hassanal Bahar Pengiran

2015-12-01

The study attempted to explore the possibilities to create a procedure at the experimental level to double confirm whether manifest variables scale type is formative or reflective. Now, the criteria of making such a decision are heavily depended on researchers' judgment at the conceptual and operational level. The study created an experimental procedure that seems could double confirm the decisions from the conceptual and operational level judgments. The experimental procedure includes the following tests, Variance Inflation Factor (VIF), Tolerance (TOL), Ridge Regression, Cronbach's alpha, Dillon-Goldstein's rho, and first and second eigenvalue. The procedure considers manifest variables' both multicollinearity and consistency. As the result, the procedure received the same judgment with the carefully established decision making at the concept and operational level.

Self-absorption paradox is not a paradox: illuminating the dark side of self-reflection.

PubMed

Simsek, Omer Faruk

2013-01-01

Although considered an important component of a healthy personality, self-reflection has not so far been shown to have any specific benefits for mental health. This research addresses this issue by taking into consideration two important suppressor variables, self-rumination and the need for absolute truth. The latter is an innovative variable, defined and presented in this research. The first two studies aimed to validate a new measure that acts as an operational definition of the need for absolute truth. The first study was conducted with two group of participants; the first group consisted of 129 females and 67 males, mean age = 20 years, and the second 182 females and 104 males, mean age = 27. In the second study, participants were 22 females and 18 males, mean age = 20.5. In the final study, conducted with 296 female, 163 male participants (mean age = 37), suppressor effects were tested using structural equation modeling. The results showed that by taking account of these two suppressor variables, particularly the need for absolute truth, the expected relationship between self-reflection and mental health was revealed. The need for absolute truth was shown to be crucial for understanding the effects of self-reflection on mental health, therefore it should be considered in all processes of psychotherapy.

Variables separation of the spectral BRDF for better understanding color variation in special effect pigment coatings.

PubMed

Ferrero, Alejandro; Rabal, Ana María; Campos, Joaquín; Pons, Alicia; Hernanz, María Luisa

2012-06-01

A type of representation of the spectral bidirectional reflectance distribution function (BRDF) is proposed that distinctly separates the spectral variable (wavelength) from the geometrical variables (spherical coordinates of the irradiation and viewing directions). Principal components analysis (PCA) is used in order to decompose the spectral BRDF in decorrelated spectral components, and the weight that they have at every geometrical configuration of irradiation/viewing is established. This method was applied to the spectral BRDF measurement of a special effect pigment sample, and four principal components with relevant variance were identified. These four components are enough to reproduce the great diversity of spectral reflectances observed at different geometrical configurations. Since this representation is able to separate spectral and geometrical variables, it facilitates the interpretation of the color variation of special effect pigments coatings versus the geometrical configuration of irradiation/viewing.

Adolescent cigarette smoking: health-related behavior or normative transgression?

PubMed

Turbin, M S; Jessor, R; Costa, F M

2000-09-01

Relations among measures of adolescent behavior were examined to determine whether cigarette smoking fits into a structure of problem behaviors-behaviors that involve normative transgression-or a structure of health-related behaviors, or both. In an ethnically and socioeconomically diverse sample of 1782 male and female high school adolescents, four first-order problem behavior latent variables-sexual intercourse experience, alcohol abuse, illicit drug use, and delinquency-were established and together were shown to reflect a second-order latent variable of problem behavior. Four first-order latent variables of health-related behaviors-unhealthy dietary habits, sedentary behavior, unsafe behavior, and poor dental hygiene-were also established and together were shown to reflect a second-order latent variable of health-compromising behavior. The structure of relations among those latent variables was modeled. Cigarette smoking had a significant and substantial loading only on the problem-behavior latent variable; its loading on the health-compromising behavior latent variable was essentially zero. Adolescent cigarette smoking relates strongly and directly to problem behaviors and only indirectly, if at all, to health-compromising behaviors. Interventions to prevent or reduce adolescent smoking should attend more to factors that influence problem behaviors.

Modeling of vegetation canopy reflectance: Status, issues and recommended future strategy

NASA Technical Reports Server (NTRS)

Goel, N. S. (Editor)

1982-01-01

Various technical issues related to mapping of vegetative type, condition and stage of maturity, utilizing remotely sensed spectral data are reviewed. The existing knowledge base of models, especially of radiative properties of the vegetation canopy and atmosphere, is reviewed to establish the state of the art for addressing the problem of vegetation mapping. Activities to advance the state of the art are recommended. They include working on canopy reflectance and atmospheric scattering models, and field measurements of canopy reflectance as well as of canopy components. Leaf area index (LAI) and solar radiation interception (SRI) are identified as the two most important vegetation variables requiring further investigation. It is recommended that activities related to sensing them or understanding their relationships with measurable variables, should be encouraged and supported.

The influence of grazing on surface climatological variables of tallgrass prairie

NASA Technical Reports Server (NTRS)

Seastedt, T. R.; Dyer, M. I.; Turner, Clarence L.

1992-01-01

Mass and energy exchange between most grassland canopies and the atmosphere are mediated by grazing activities. Ambient temperatures can be increased or decreased by grazers. Data have been assembled from simulated grazing experiments on Konza Prairie Research Natural Area and observations on adjacent pastures grazed by cattle show significant changes in primary production, nutrient content, and bidirectional reflectance characteristics as a function of grazing intensity. The purpose of this research was to provide algorithms that would allow incorporation of grazing effects into models of energy budgets using remote sensing procedures. The approach involved: (1) linking empirical measurements of plant biomass and grazing intensities to remotely sensed canopy reflectance, and (2) using a higher resolution, mechanistic grazing model to derive plant ecophysiological parameters that influence reflectance and other surface climatological variables.

Integrating satellite remote sensing data and field data to predict rangeland structural indicators at the continental scale

NASA Astrophysics Data System (ADS)

Zhang, J.; Okin, G.

2016-12-01

Rangelands provide a variety of important ecosystem goods and services across drylands globally. They are also the most important emitters of dust across the globe. Field data collection based on points does not represent spatially continuous information about surface variables and, given the vast size of the world's rangelands, cannot cover even a small fraction of their area. Remote sensing is potentially a labor- and time-saving method to observe important rangeland vegetation variables at both temporal and spatial scales. Information on vegetation cover, bare gap size, and plant height provide key rangeland vegetation variables in arid and semiarid rangelands, in part because they strongly impact dust emission and determine wildlife habitat characteristics. This study reports on relationships between remote sensing in the reflected solar spectrum and field measures related to these three variables, and shows how these relationships can be extended to produce spatially and temporally continuous datasets coupled with quantitative estimates of error. Field data for this study included over 3,800 Assessment, Inventory, and Monitoring (AIM) measurements on Bureau of Land Management (BLM) lands throughout the western US. Remote sensing data were derived from MODIS nadir BRDF-adjusted reflectance (NBAR) and Landsat 8 OLI surface reflectance. Normalized bare gap size, total foliar cover, herbaceous cover and herbaceous height exhibit the greatest predictability from remote sensing variables with physically-reasonable relationships between remote sensing variables and field measures. Data fields produced using these relationships across the western US exhibit good agreement with independent high-resolution imagery.

The Microphysical Structure of Extreme Precipitation as Inferred from Ground-Based Raindrop Spectra.

NASA Astrophysics Data System (ADS)

Uijlenhoet, Remko; Smith, James A.; Steiner, Matthias

2003-05-01

The controls on the variability of raindrop size distributions in extreme rainfall and the associated radar reflectivity-rain rate relationships are studied using a scaling-law formalism for the description of raindrop size distributions and their properties. This scaling-law formalism enables a separation of the effects of changes in the scale of the raindrop size distribution from those in its shape. Parameters controlling the scale and shape of the scaled raindrop size distribution may be related to the microphysical processes generating extreme rainfall. A global scaling analysis of raindrop size distributions corresponding to rain rates exceeding 100 mm h1, collected during the 1950s with the Illinois State Water Survey raindrop camera in Miami, Florida, reveals that extreme rain rates tend to be associated with conditions in which the variability of the raindrop size distribution is strongly number controlled (i.e., characteristic drop sizes are roughly constant). This means that changes in properties of raindrop size distributions in extreme rainfall are largely produced by varying raindrop concentrations. As a result, rainfall integral variables (such as radar reflectivity and rain rate) are roughly proportional to each other, which is consistent with the concept of the so-called equilibrium raindrop size distribution and has profound implications for radar measurement of extreme rainfall. A time series analysis for two contrasting extreme rainfall events supports the hypothesis that the variability of raindrop size distributions for extreme rain rates is strongly number controlled. However, this analysis also reveals that the actual shapes of the (measured and scaled) spectra may differ significantly from storm to storm. This implies that the exponents of power-law radar reflectivity-rain rate relationships may be similar, and close to unity, for different extreme rainfall events, but their prefactors may differ substantially. Consequently, there is no unique radar reflectivity-rain rate relationship for extreme rain rates, but the variability is essentially reduced to one free parameter (i.e., the prefactor). It is suggested that this free parameter may be estimated on the basis of differential reflectivity measurements in extreme rainfall.

Initial Stability Assessment of S-NPP VIIRS Reflective Solar Band Calibration Using Invariant Desert and Deep Convective Cloud Targets

NASA Technical Reports Server (NTRS)

Bhatt, Rajendra; Doelling, David R.; Wu, Aisheng; Xiong, Xiaoxiong (Jack); Scarino, Benjamin R.; Haney, Conor O.; Gopalan, Arun

2014-01-01

The latest CERES FM-5 instrument launched onboard the S-NPP spacecraft will use the VIIRS visible radiances from the NASA Land Product Evaluation and Analysis Tool Elements (PEATE) product for retrieving the cloud properties associated with its TOA flux measurement. In order for CERES to provide climate quality TOA flux datasets, the retrieved cloud properties must be consistent throughout the record, which is dependent on the calibration stability of the VIIRS imager. This paper assesses the NASA calibration stability of the VIIRS reflective solar bands using the Libya-4 desert and deep convective clouds (DCC). The invariant targets are first evaluated for temporal natural variability. It is found for visible (VIS) bands that DCC targets have half of the variability of Libya-4. For the shortwave infrared (SWIR) bands, the desert has less variability. The brief VIIRS record and target variability inhibits high confidence in identifying any trends that are less than 0.6yr for most VIS bands, and 2.5yr for SWIR bands. None of the observed invariant target reflective solar band trends exceeded these trend thresholds. Initial assessment results show that the VIIRS data have been consistently calibrated and that the VIIRS instrument stability is similar to or better than the MODIS instrument.

Error in the Sampling Area of an Optical Disdrometer: Consequences in Computing Rain Variables

PubMed Central

Fraile, R.; Castro, A.; Fernández-Raga, M.; Palencia, C.; Calvo, A. I.

2013-01-01

The aim of this study is to improve the estimation of the characteristic uncertainties of optic disdrometers in an attempt to calculate the efficient sampling area according to the size of the drop and to study how this influences the computation of other parameters, taking into account that the real sampling area is always smaller than the nominal area. For large raindrops (a little over 6 mm), the effective sampling area may be half the area indicated by the manufacturer. The error committed in the sampling area is propagated to all the variables depending on this surface, such as the rain intensity and the reflectivity factor. Both variables tend to underestimate the real value if the sampling area is not corrected. For example, the rainfall intensity errors may be up to 50% for large drops, those slightly larger than 6 mm. The same occurs with reflectivity values, which may be up to twice the reflectivity calculated using the uncorrected constant sampling area. The Z-R relationships appear to have little dependence on the sampling area, because both variables depend on it the same way. These results were obtained by studying one particular rain event that occurred on April 16, 2006. PMID:23844393

Random variable transformation for generalized stochastic radiative transfer in finite participating slab media

NASA Astrophysics Data System (ADS)

El-Wakil, S. A.; Sallah, M.; El-Hanbaly, A. M.

2015-10-01

The stochastic radiative transfer problem is studied in a participating planar finite continuously fluctuating medium. The problem is considered for specular- and diffusly-reflecting boundaries with linear anisotropic scattering. Random variable transformation (RVT) technique is used to get the complete average for the solution functions, that are represented by the probability-density function (PDF) of the solution process. In the RVT algorithm, a simple integral transformation to the input stochastic process (the extinction function of the medium) is applied. This linear transformation enables us to rewrite the stochastic transport equations in terms of the optical random variable (x) and the optical random thickness (L). Then the transport equation is solved deterministically to get a closed form for the solution as a function of x and L. So, the solution is used to obtain the PDF of the solution functions applying the RVT technique among the input random variable (L) and the output process (the solution functions). The obtained averages of the solution functions are used to get the complete analytical averages for some interesting physical quantities, namely, reflectivity and transmissivity at the medium boundaries. In terms of the average reflectivity and transmissivity, the average of the partial heat fluxes for the generalized problem with internal source of radiation are obtained and represented graphically.

Modeling and analysis of LWIR signature variability associated with 3D and BRDF effects

NASA Astrophysics Data System (ADS)

Adler-Golden, Steven; Less, David; Jin, Xuemin; Rynes, Peter

2016-05-01

Algorithms for retrieval of surface reflectance, emissivity or temperature from a spectral image almost always assume uniform illumination across the scene and horizontal surfaces with Lambertian reflectance. When these algorithms are used to process real 3-D scenes, the retrieved "apparent" values contain the strong, spatially dependent variations in illumination as well as surface bidirectional reflectance distribution function (BRDF) effects. This is especially problematic with horizontal or near-horizontal viewing, where many observed surfaces are vertical, and where horizontal surfaces can show strong specularity. The goals of this study are to characterize long-wavelength infrared (LWIR) signature variability in a HSI 3-D scene and develop practical methods for estimating the true surface values. We take advantage of synthetic near-horizontal imagery generated with the high-fidelity MultiService Electro-optic Signature (MuSES) model, and compare retrievals of temperature and directional-hemispherical reflectance using standard sky downwelling illumination and MuSES-based non-uniform environmental illumination.

Model specification in oral health-related quality of life research.

PubMed

Kieffer, Jacobien M; Verrips, Erik; Hoogstraten, Johan

2009-10-01

The aim of this study was to analyze conventional wisdom regarding the construction and analysis of oral health-related quality of life (OHRQoL) questionnaires and to outline statistical complications. Most methods used for developing and analyzing questionnaires, such as factor analysis and Cronbach's alpha, presume psychological constructs to be latent, inferring a reflective measurement model with the underlying assumption of local independence. Local independence implies that the latent variable explains why the variables observed are related. Many OHRQoL questionnaires are analyzed as if they were based on a reflective measurement model; local independence is thus assumed. This assumption requires these questionnaires to consist solely of items that reflect, instead of determine, OHRQoL. The tenability of this assumption is the main topic of the present study. It is argued that OHRQoL questionnaires are a mix of both a formative measurement model and a reflective measurement model, thus violating the assumption of local independence. The implications are discussed.

Variable path length spectrophotometric probe

DOEpatents

O'Rourke, Patrick E.; McCarty, Jerry E.; Haggard, Ricky A.

1992-01-01

A compact, variable pathlength, fiber optic probe for spectrophotometric measurements of fluids in situ. The probe comprises a probe body with a shaft having a polished end penetrating one side of the probe, a pair of optic fibers, parallel and coterminous, entering the probe opposite the reflecting shaft, and a collimating lens to direct light from one of the fibers to the reflecting surface of the shaft and to direct the reflected light to the second optic fiber. The probe body has an inlet and an outlet port to allow the liquid to enter the probe body and pass between the lens and the reflecting surface of the shaft. A linear stepper motor is connected to the shaft to cause the shaft to advance toward or away from the lens in increments so that absorption measurements can be made at each of the incremental steps. The shaft is sealed to the probe body by a bellows seal to allow freedom of movement of the shaft and yet avoid leakage from the interior of the probe.

Structural, Linguistic and Topic Variables in Verbal and Computational Problems in Elementary Mathematics.

ERIC Educational Resources Information Center

Beardslee, Edward C.; Jerman, Max E.

Five structural, four linguistic and twelve topic variables are used in regression analyses on results of a 50-item achievement test. The test items are related to 12 topics from the third-grade mathematics curriculum. The items reflect one of two cases of the structural variable, cognitive level; the two levels are characterized, inductive…

Abbreviation as a Reflection of Terms Variability in Language for Specific Purposes: Translational Features (Terminology Case Study in German, English, Kazakh, and Russia)

ERIC Educational Resources Information Center

Beisembayeva, Gulshat Z.; Yeskindirova, Manshuk Z.; Tulebayeva, Samal A.

2016-01-01

The range of modern dynamic social changes, globalization of world powers' economic cooperation, acceleration of technocratic processes have widespread impact on term systems' variability in language, in particular, on terminological variability for specific purposes. This globalized extra-linguistic factor provokes avalanche growth of…

Consolidated fuel reprossing program: The implications of force reflection for teleoperation in space

NASA Technical Reports Server (NTRS)

Draper, John V.; Herndon, Joseph N.; Moore, Wendy E.

1987-01-01

Previous research on teleoperator force feedback is reviewed and results of a testing program which assessed the impact of force reflection on teleoperator task performance are reported. Force relection is a type of force feedback in which the forces acting on the remote portion of the teleoperator are displayed to the operator by back-driving the master controller. The testing program compared three force reflection levels: 4 to 1 (four units of force on the slave produce one unit of force at the master controller), 1 to 1, and infinity to 1 (no force reflection). Time required to complete tasks, rate of occurrence of errors, the maximum force applied to tasks components, and variability in forces applied to components during completion of representative remote handling tasks were used as dependent variables. Operators exhibited lower error rates, lower peak forces, and more consistent application of forces using force relection than they did without it. These data support the hypothesis that force reflection provides useful information for teleoperator users. The earlier literature and the results of the experiment are discussed in terms of their implications for space based teleoperator systems. The discussion described the impact of force reflection on task completion performance and task strategies, as suggested by the literature. It is important to understand the trade-offs involved in using telerobotic systems with and without force reflection.

Variable frequency microwave furnace system

DOE Office of Scientific and Technical Information (OSTI.GOV)

Bible, D.W.; Lauf, R.J.

1994-06-14

A variable frequency microwave furnace system designed to allow modulation of the frequency of the microwaves introduced into a furnace cavity for testing or other selected applications. The variable frequency microwave furnace system includes a microwave signal generator or microwave voltage-controlled oscillator for generating a low-power microwave signal for input to the microwave furnace. A first amplifier may be provided to amplify the magnitude of the signal output from the microwave signal generator or the microwave voltage-controlled oscillator. A second amplifier is provided for processing the signal output by the first amplifier. The second amplifier outputs the microwave signal inputmore » to the furnace cavity. In the preferred embodiment, the second amplifier is a traveling-wave tube (TWT). A power supply is provided for operation of the second amplifier. A directional coupler is provided for detecting the direction of a signal and further directing the signal depending on the detected direction. A first power meter is provided for measuring the power delivered to the microwave furnace. A second power meter detects the magnitude of reflected power. Reflected power is dissipated in the reflected power load. 5 figs.« less

Variable frequency microwave furnace system

DOEpatents

Bible, D.W.; Lauf, R.J.

1994-06-14

A variable frequency microwave furnace system designed to allow modulation of the frequency of the microwaves introduced into a furnace cavity for testing or other selected applications. The variable frequency microwave furnace system includes a microwave signal generator or microwave voltage-controlled oscillator for generating a low-power microwave signal for input to the microwave furnace. A first amplifier may be provided to amplify the magnitude of the signal output from the microwave signal generator or the microwave voltage-controlled oscillator. A second amplifier is provided for processing the signal output by the first amplifier. The second amplifier outputs the microwave signal input to the furnace cavity. In the preferred embodiment, the second amplifier is a traveling-wave tube (TWT). A power supply is provided for operation of the second amplifier. A directional coupler is provided for detecting the direction of a signal and further directing the signal depending on the detected direction. A first power meter is provided for measuring the power delivered to the microwave furnace. A second power meter detects the magnitude of reflected power. Reflected power is dissipated in the reflected power load. 5 figs.

Using IKONOS Imagery to Estimate Surface Soil Property Variability in Two Alabama Physiographies

NASA Technical Reports Server (NTRS)

Sullivan, Dana; Shaw, Joey; Rickman, Doug

2005-01-01

Knowledge of surface soil properties is used to assess past erosion and predict erodibility, determine nutrient requirements, and assess surface texture for soil survey applications. This study was designed to evaluate high resolution IKONOS multispectral data as a soil- mapping tool. Imagery was acquired over conventionally tilled fields in the Coastal Plain and Tennessee Valley physiographic regions of Alabama. Acquisitions were designed to assess the impact of surface crusting, roughness and tillage on our ability to depict soil property variability. Soils consisted mostly of fine-loamy, kaolinitic, thermic Plinthic Kandiudults at the Coastal Plain site and fine, kaolinitic, thermic Rhodic Paleudults at the Tennessee Valley site. Soils were sampled in 0.20 ha grids to a depth of 15 cm and analyzed for % sand (0.05 - 2 mm), silt (0.002 -0.05 mm), clay (less than 0.002 mm), citrate dithionite extractable iron (Fe(sub d)) and soil organic carbon (SOC). Four methods of evaluating variability in soil attributes were evaluated: 1) kriging of soil attributes, 2) co-kriging with soil attributes and reflectance data, 3) multivariate regression based on the relationship between reflectance and soil properties, and 4) fuzzy c-means clustering of reflectance data. Results indicate that co-kriging with remotely sensed data improved field scale estimates of surface SOC and clay content compared to kriging and regression methods. Fuzzy c-means worked best using RS data acquired over freshly tilled fields, reducing soil property variability within soil zones compared to field scale soil property variability.

Forecasting defoliation by the gypsy moth in oak stands

Treesearch

Robert W. Campbell; Joseph P. Standaert

1974-01-01

A multiple-regression model is presented that reflects statistically significant correlations between defoliation by the gypsy moth, the dependent variable, and a series of biotic and physical independent variables. Both possible uses and shortcomings of this model are discussed.

Field potential soil variability index to identify precision agriculture opportunity

USDA-ARS?s Scientific Manuscript database

Precision agriculture (PA) technologies used for identifying and managing within-field variability are not widely used despite decades of advancement. Technological innovations in agronomic tools, such as canopy reflectance or electrical conductivity sensors, have created opportunities to achieve a ...

Professional Development through Formative Evaluation

ERIC Educational Resources Information Center

Nsibande, Rejoice; Garraway, James

2011-01-01

Formative evaluation and its associated methodology of reflection on practice are used extensively in academic staff development. In reflecting on formative evaluation processes in both more traditional and newer programmes conducted at a university of technology, a number of variables reported in the literature were observed to have influenced…

Reflectance spectroscopy of ferric sulfate-bearing montmorillonites as Mars soil analog materials

NASA Technical Reports Server (NTRS)

Bishop, J. L.; Pieters, C. M.; Burns, R. G.; Edwards, J. O.; Mancinelli, R. L.; Froschl, H.

1995-01-01

Spectroscopic analyses have shown that smectites enhanced in the laboratory with additional ferric species exhibit important similarities to those of the soils on Mars. Ferrihydrite in these chemically treated smectites has features in the visible to near-infrared region that resemble the energies and band strengths of features in reflectance spectra observed for several bright regions on Mars. New samples have been prepared with sulfate as well, because S was found by Viking to be a major component in the surface material on Mars. A suite of ferrihydrite-bearing and ferric sulfate-bearing montmorillonites, prepared with variable Fe3+ and S concentrations and variable pH conditions, has been analyzed using reflectance spectroscopy in the visible and infrared regions, Mossbauer spectroscopy at room temperature and 4 K, differential thermal analysis, and X-ray diffraction. These analyses support the formation of ferrihydrite of variable crystallinity in the ferrihydrite-bearing montmorillonites and a combination of schwertmannite and ferrihydrite in the ferric sulfate-bearing montmorillonites. Small quantities of poorly crystalline or nanophase forms of other ferric materials may also be present in these samples. The chemical formation conditions of the ferrihydrite-bearing and ferric sulfate-bearing montmorillonites influence the character of the low temperature Mossbauer sextets and the visible reflectance spectra. An absorption minimum is observed at 0.88-0.89 micrometers in spectra of the ferric sulfate-bearing samples, and at 0.89-0.92 micrometers in spectra of the ferrihydrate-bearing montmorillonites. Mossbauer spectra of the ferric sulfate-bearing montmorillonites indicate variable concentrations of ferrihydrite and schwertmannite in the interlaminar spaces and along grain surfaces. Dehydration under reduced atmospheric pressure conditions induces a greater effect on the adsorbed and interlayer water in ferrihydrite-bearing montmorillonite than on the water in ferric sulfate-bearing montmorillonite. Reflectance spectra of ferric sulfate-bearing montmorillonite include a strong 3-micrometers band that is more resistant to dry atmospheric conditions than the 3-micrometers band in spectra of similarly prepared ferrihydrite-bearing montmorillonites.

Continuous-variable entanglement and quantum-state teleportation between optical and macroscopic vibrational modes through radiation pressure

DOE Office of Scientific and Technical Information (OSTI.GOV)

Pirandola, Stefano; Mancini, Stefano; Vitali, David

2003-12-01

We study an isolated, perfectly reflecting, mirror illuminated by an intense laser pulse. We show that the resulting radiation pressure efficiently entangles a mirror vibrational mode with the two reflected optical sideband modes of the incident carrier beam. The entanglement of the resulting three-mode state is studied in detail and it is shown to be robust against the mirror mode temperature. We then show how this continuous-variable entanglement can be profitably used to teleport an unknown quantum state of an optical mode onto the vibrational mode of the mirror.

On the X-ray spectra of luminous, inhomogeneous accretion flows

NASA Astrophysics Data System (ADS)

Merloni, A.; Malzac, J.; Fabian, A. C.; Ross, R. R.

2006-08-01

We discuss the expected X-ray spectral and variability properties of black hole accretion discs at high luminosity, under the hypothesis that radiation-pressure-dominated discs are subject to violent clumping instabilities and, as a result, have a highly inhomogeneous two-phase structure. After deriving the full accretion disc solutions explicitly in terms of the parameters of the model, we study their radiative properties both with a simple two-zone model, treatable analytically, and with radiative transfer simulations which account simultaneously for energy balance and Comptonization in the hot phase, together with reflection, reprocessing, ionization and thermal balance in the cold phase. We show that, if not only the density, but also the heating rate within these flows is inhomogeneous, then complex reflection-dominated spectra can be obtained for a high enough covering fraction of the cold phase. In general, large reflection components in the observed X-ray spectra should be associated with strong soft excesses, resulting from the combined emission of ionized atomic emission lines. The variability properties of such systems are such that, even when contributing to a large fraction of the hard X-ray spectrum, the reflection component is less variable than the power-law-like emission originating from the hot Comptonizing phase, in agreement with what is observed in many Narrow Line Seyfert 1 galaxies and bright Seyfert 1. Our model falls within the family of those trying to explain the complex X-ray spectra of bright AGN with ionized reflection, but presents an alternative, specific, physically motivated, geometrical set-up for the complex multiphase structure of the inner regions of near-Eddington accretion flows.

Monitoring MRK 509: The Origin of the Reprocessor and Broad Band X-ray Spectrum of Narrow Line Seyfert 1 AKN 564

NASA Technical Reports Server (NTRS)

Halpern, Jules P.; Leighly, Karen M.

1998-01-01

The ten monitoring observations of Mrk 509 were made successfully between October 20 and November 26 last year. These observations were simultaneously with RXTE observations. A preliminary analysis of the RXTE observations has been done, and the light curve is shown in figure 1. Our aim in this experiment is to determine the location of the emission region of the reflection component by reverberation mapping. This component could be emitted from the accretion disk, within 100 Scwartzschild radii (R(sub s)) from the source. Note that the monitoring interval of 2.5 days corresponds to 100 R(sub s) for a 2 x 10(exp 8) solar mass black hole, which may be appropriate for this luminous object. In that case, we would expect the reflected component to vary along the direct flux, and there should be no spectral variability between observations. Alternatively, the reflected emission could come from the molecular torus, several parsecs from the nucleus. In that case, the reflection component flux should not vary. The light curve in figure 1 shows that during the monitoring period, the target varied in an ideal way, since significant variability was observed between observations and yet the most rapid variability is apparently sampled. The analysis of this data is not yet completed. The measurement of the reflection component in the combined ASCa and RXTE spectra depends critically on the RXTE background subtraction and calibration, but these have not yet progressed to the point where the analysis can be done.

A Long Look at MCG-5-23-16 with NuSTAR . I. Relativistic Reflection and Coronal Properties

DOE Office of Scientific and Technical Information (OSTI.GOV)

Zoghbi, Abderahmen; Miller, J. M.; Matt, G.

MCG-5-23-16 was targeted in early 2015 with a half mega-second observing campaign using NuSTAR . Here we present the spectral analysis of these data sets along with an earlier observation and study the relativistic reflection and the primary coronal source. The data show strong reflection features in the form of both narrow and broad iron lines plus a Compton reflection hump. A cutoff energy is significantly detected in all exposures. The shape of the reflection spectrum does not change in the two years spanned by the observations, suggesting a stable geometry. A strong positive correlation is found between the cutoffmore » energy and both the hard X-ray flux and spectral index. The measurements imply that the coronal plasma is not at the runaway electron–positron pair limit, and instead contains mostly electrons. The observed variability in the coronal properties is driven by a variable optical depth. A constant heating-to-cooling ratio is measured, implying that there is a feedback mechanism in which a significant fraction of the photons cooling the corona are due to reprocessed hard X-rays.« less

A Long Look at MCG-5-23-16 with NuSTAR. I. Relativistic Reflection and Coronal Properties

NASA Technical Reports Server (NTRS)

Zoghbi, Abderahmen; Matt, G.; Miller, J. M.; Lohfink, A. M.; Walton, D. J.; Ballantyne, D. R.; Garcia, J. A.; Stern, D.; Koss, M. J.; Farrah, D.;

Analysis of Specular Reflections Off Geostationary Satellites

NASA Astrophysics Data System (ADS)

Jolley, A.

2016-09-01

Many photometric studies of artificial satellites have attempted to define procedures that minimise the size of datasets required to infer information about satellites. However, it is unclear whether deliberately limiting the size of datasets significantly reduces the potential for information to be derived from them. In 2013 an experiment was conducted using a 14 inch Celestron CG-14 telescope to gain multiple night-long, high temporal resolution datasets of six geostationary satellites [1]. This experiment produced evidence of complex variations in the spectral energy distribution (SED) of reflections off satellite surface materials, particularly during specular reflections. Importantly, specific features relating to the SED variations could only be detected with high temporal resolution data. An update is provided regarding the nature of SED and colour variations during specular reflections, including how some of the variables involved contribute to these variations. Results show that care must be taken when comparing observed spectra to a spectral library for the purpose of material identification; a spectral library that uses wavelength as the only variable will be unable to capture changes that occur to a material's reflected spectra with changing illumination and observation geometry. Conversely, colour variations with changing illumination and observation geometry might provide an alternative means of determining material types.

The impacts of environmental variables on water reflectance measured using a lightweight unmanned aerial vehicle (UAV)-based spectrometer system

NASA Astrophysics Data System (ADS)

Zeng, Chuiqing; Richardson, Murray; King, Douglas J.

2017-08-01

Remote sensing methods to study spatial and temporal changes in water quality using satellite or aerial imagery are limited by the inherently low reflectance signal of water across the visible and near infrared spectrum, as well as environmental variables such as surface scattering effects (sun glint), substrate and aquatic vegetation reflectance, and atmospheric effects. This study exploits the low altitude, high-resolution remote sensing capabilities of unmanned aerial vehicle (UAV) platforms to examine the major environmental variables that affect water reflectance acquisition, without the confounding influence of atmospheric effects typical of higher-altitude platforms. After observation and analysis, we found: (1) multiple water spectra measured at the same location had a standard deviation of 10.4%; (2) water spectra changes associated with increasing altitude from 20 m to 100 m were negligible; (3) the difference between mean reflectance at three off-shore locations in an urban water body reached 29.9%; (4) water bottom visibility increased water reflectance by 20.1% in near shore areas compared to deep water spectra in a clear water lake; (5) emergent plants caused the water spectra to shift towards a shape that is characteristic of vegetation, whereas submerged vegetation showed limited effect on water spectra in the studied lake; (6) cloud and sun glint had major effects and caused water spectra to change abruptly; while glint and shadow effects on spectra may balance each other under certain conditions, the water reflectance can also be unpredictable at times due to wave effects and their effects on lines-of-site to calm water; (7) water spectra collected under a variety of different conditions (e.g. multiple locations, waves) resulted in weaker regression models compared to spectra collected under ideal conditions (e.g. single location, no wave), although the resulting model coefficients were relatively stable. The methods and results from this study contribute to better understanding of water reflectance acquisition using remote sensing, and can be applied in UAV-based water quality assessment or to aid in validation of higher altitude imagery.

Variable density thinning promotes variable structural responses 14 years after treatment in the Pacific Northwest

Treesearch

John L. Willis; Scott D. Roberts; Constance A. Harrington

2018-01-01

Young stands are commonly assumed to require centuries to develop into late-successional forest habitat. This viewpoint reflects the fact that young stands often lack many of the structural features that define late-successional habitat, and that these features derive from complex stand dynamics that are difficult to mimic with forest management. Variable density...

Further Mythological Evidence for Ancient Knowledge of Variable Stars

NASA Astrophysics Data System (ADS)

Wilk, Stephen R.

1999-10-01

I suggest that the variability of Betelgeuse (alpha Orionis) was known in pre-classical Greece, and that this knowldge is reflected in the myths associated with Orion and other figures in Greek mythology. There is corroboration in parallelmyths from other cultures.

Preservice Teachers' Understandings of Caring.

ERIC Educational Resources Information Center

Goldstein, Lisa S.; Lake, Vickie E.

This study examined preservice elementary teachers' understandings of the role of caring in educational contexts. Rather than attending to process variables (the teachers' emergent practices), the study focused on presage variables (the teachers' beliefs and understandings) and the teachers' reflections on their classroom experiences. Participants…

Fusing corn nitrogen recommendation tools for an improved canopy reflectance sensor performance

USDA-ARS?s Scientific Manuscript database

Nitrogen (N) rate recommendation tools are utilized to help producers maximize corn grain yield production. Many of these tools provide recommendations at field scales but often fail when corn N requirements are variable across the field. Canopy reflectance sensors are capable of capturing within-fi...

Estimation of the probability of success in petroleum exploration

USGS Publications Warehouse

Davis, J.C.

1977-01-01

A probabilistic model for oil exploration can be developed by assessing the conditional relationship between perceived geologic variables and the subsequent discovery of petroleum. Such a model includes two probabilistic components, the first reflecting the association between a geologic condition (structural closure, for example) and the occurrence of oil, and the second reflecting the uncertainty associated with the estimation of geologic variables in areas of limited control. Estimates of the conditional relationship between geologic variables and subsequent production can be found by analyzing the exploration history of a "training area" judged to be geologically similar to the exploration area. The geologic variables are assessed over the training area using an historical subset of the available data, whose density corresponds to the present control density in the exploration area. The success or failure of wells drilled in the training area subsequent to the time corresponding to the historical subset provides empirical estimates of the probability of success conditional upon geology. Uncertainty in perception of geological conditions may be estimated from the distribution of errors made in geologic assessment using the historical subset of control wells. These errors may be expressed as a linear function of distance from available control. Alternatively, the uncertainty may be found by calculating the semivariogram of the geologic variables used in the analysis: the two procedures will yield approximately equivalent results. The empirical probability functions may then be transferred to the exploration area and used to estimate the likelihood of success of specific exploration plays. These estimates will reflect both the conditional relationship between the geological variables used to guide exploration and the uncertainty resulting from lack of control. The technique is illustrated with case histories from the mid-Continent area of the U.S.A. ?? 1977 Plenum Publishing Corp.

Modeling the light-induced electric potential difference (ΔΨ), the pH difference (ΔpH) and the proton motive force across the thylakoid membrane in C3 leaves.

PubMed

Lyu, Hui; Lazár, Dušan

2017-01-21

A model was constructed which includes electron transport (linear and cyclic and Mehler type reaction) coupled to proton translocation, counter ion movement, ATP synthesis, and Calvin-Benson cycle. The focus is on modeling of the light-induced total electric potential difference (ΔΨ) which in this model originates from the bulk phase electric potential difference (ΔΨ b ), the localized electric potential difference (ΔΨ c ), as well as the surface electric potential difference (ΔΨ s ). The measured dual wavelength transmittance signal (ΔA515-560nm, electrochromic shift) was used as a proxy for experimental ΔΨ. The predictions for theoretical ΔΨ vary with assumed contribution of ΔΨ s , which might imply that the measured ΔA515-560nm trace on a long time scale reflects the interplay of the ΔΨ components. Simulations also show that partitioning of proton motive force (pmf) to ΔΨ b and ΔpH components is sensitive to the stoichiometric ratio of H + /ATP, energy barrier for ATP synthesis, ionic strength, buffer capacity and light intensity. Our model shows that high buffer capacity promotes the establishment of ΔΨ b , while the formation of pH i minimum is not 'dissipated' but 'postponed' until it reaches the same level as that for low buffer capacity. Under physiologically optimal conditions, the output of the model shows that at steady state in light, the ΔpH component is the main contributor to pmf to drive ATP synthesis while a low ΔΨ b persists energizing the membrane. Our model predicts 11mV as the resting electric potential difference across the thylakoid membrane in dark. We suggest that the model presented in this work can be integrated as a module into a more comprehensive model of oxygenic photosynthesis. Copyright © 2016 Elsevier Ltd. All rights reserved.

Method for improving the durability of ion insertion materials

DOEpatents

Lee, Se-Hee; Tracy, C. Edwin; Cheong, Hyeonsik M.

2002-01-01

The invention provides a method of protecting an ion insertion material from the degradative effects of a liquid or gel-type electrolyte material by disposing a protective, solid ion conducting, electrically insulating, layer between the ion insertion layer and the liquid or gel-type electrolyte material. The invention further provides liquid or gel-type electrochemical cells having improved durability having a pair of electrodes, a pair of ion insertion layers sandwiched between the pair of electrodes, a pair of solid ion conducting layers sandwiched between the ion insertion layers, and a liquid or gel-type electrolyte material disposed between the solid ion conducting layers, where the solid ion conducting layer minimizes or prevents degradation of the faces of the ion insertion materials facing the liquid or gel-type electrolyte material. Electrochemical cells of this invention having increased durability include secondary lithium batteries and electrochromic devices.

Photoacoustic spectroscopy and the in situ characterization of the electrochemical interface

DOE Office of Scientific and Technical Information (OSTI.GOV)

Vallet, C.E.

1988-01-01

Photoacoustics is a new spectroscopic method which has been used for in situ characterization of the electrochemical interface during the past ten years. The basic principles of the photoacoustic effect and the principal results of the Rosencwaig-Gersho theory are discussed in light of the usefulness of the method in electrochemical studies. Different experimental arrangements suitable for in situ electrode studies are presented. A review of the use to date of photoacoustics in electrochemistry includes studies of electrochromic systems, semiconductor electrodes, passivation layers, and of electrocatalytic mixed oxides. These works demonstrated that, with relatively simple apparatus, it was possible to detectmore » and to characterize very thin layers formed on electrodes. It is still not clear whether in most cases photoacoustic spectroscopy has an overwhelming advantage over well-established optical methods for adsorption measurements; however, all the potentialities of the method have yet to be explored. 73 refs., 6 figs.« less

Role of salt concentration in blend polymer for energy storage conversion devices

DOE Office of Scientific and Technical Information (OSTI.GOV)

Arya, Anil; Sharma, A. L., E-mail: alsharmaiitkgp@gmail.com; Sadiq, M.

2016-05-06

Solid Polymer Electrolytes (SPE) are materials of considerable interest worldwide, which serves dual purpose of electrolyte and separator between electrode compartments in renewable energy conversion/storage devices such as; high energy density batteries, electrochromic display devices, and supercapacitors. Polymer blend electrolytes are prepared for various concentration of salt (Ö/Li) with the constant ratio (0.5 gm) of each PEO and PAN polymers (blend polymer) using solution casting technique. Solid polymeric ionic conductor as a separator is the ultimate substitute to eliminate the drawback related to liquid and gel polymer ionic conductors. In the present work, solid polymer electrolyte film consisting of PEO,more » PAN and LiPF{sub 6} are examined for various concentration of lithium salt by keeping PEO/PAN blend ratio as a constant with a view to optimize the dominant salt concentration which could give the maximum conductivity at ambient temperature.« less

Options for reducing carbon dioxide emissions

NASA Astrophysics Data System (ADS)

Rosenfeld, Arthur H.; Price, Lynn

1992-03-01

Improvements in energy efficiency can significantly reduce the annual growth in greenhouse gas emissions. Such improvements occur when energy intensity is reduced; no reduction in energy services is required. Using the concept of ``cost of conserved energy'' to develop conservation supply curves similar to resource supply curves, researchers consistently find that electricity and natural gas savings of nearly 50% of current consumption are possible for U.S. buildings. Such reductions in energy consumption directly reduce emissions of greenhouse gases. To capture these savings, we must continue to develop energy-efficient technologies and strategies. This paper describes three recent energy-efficient technologies that benefitted from energy conservation research and development (R&D) funding: high-frequency ballasts, compact fluorescent lamps, and low-emissivity windows. Other advanced technologies and strategies of spectrally selective windows, superwindows, electrochromic windows, advanced insulation, low-flow showerheads, improved recessed lamp fixtures, whitening surfaces and planting urban trees, daylighting, and thermal energy storage are also discussed.

A Dual-Stimuli-Responsive Sodium-Bromine Battery with Ultrahigh Energy Density.

PubMed

Wang, Faxing; Yang, Hongliu; Zhang, Jian; Zhang, Panpan; Wang, Gang; Zhuang, Xiaodong; Cuniberti, Gianaurelio; Feng, Xinliang

2018-06-01

Stimuli-responsive energy storage devices have emerged for the fast-growing popularity of intelligent electronics. However, all previously reported stimuli-responsive energy storage devices have rather low energy densities (<250 Wh kg -1 ) and single stimuli-response, which seriously limit their application scopes in intelligent electronics. Herein, a dual-stimuli-responsive sodium-bromine (Na//Br 2 ) battery featuring ultrahigh energy density, electrochromic effect, and fast thermal response is demonstrated. Remarkably, the fabricated Na//Br 2 battery exhibits a large operating voltage of 3.3 V and an energy density up to 760 Wh kg -1 , which outperforms those for the state-of-the-art stimuli-responsive electrochemical energy storage devices. This work offers a promising approach for designing multi-stimuli-responsive and high-energy rechargeable batteries without sacrificing the electrochemical performance. © 2018 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Strain Accommodation By Facile WO6 Octahedral Distortion and Tilting During WO3 Heteroepitaxy on SrTiO3(001)

DOE Office of Scientific and Technical Information (OSTI.GOV)

Du, Yingge; Gu, Meng; Varga, Tamas

2014-08-27

In this paper, we show that compared to other BO6 octahedra in ABO3 structured perovskite oxides, the WO6 octahedra in tungsten trioxide (WO3) can withstand a much larger degree of distortion and tilting to accommodate interfacial strain, which in turn strongly impact the nucleation, structure, and defect formation during the epitaxial growth of WO3 on SrTiO3(001). A meta-stable tetragonal phase can be stabilized by epitaxy and a thickness dependent phase transition (tetragonal to monoclinic) is observed. In contrast to misfit dislocations to accommodate the interfacial stain, the facial WO6 octahedral distortion and tilting give rise to three types of planarmore » defects that affect more than 15 monolayers from the interface. These atomically resolved, unusual interfacial defects may significantly alter the electronic, electrochromic, and mechanical properties of the epitaxial films.« less

Magnetoelectrical control of nonreciprocal microwave response in a multiferroic helimagnet

NASA Astrophysics Data System (ADS)

Iguchi, Yusuke; Nii, Yoichi; Onose, Yoshinori

Control of physical property in terms of external fields is essential for contemporary technologies. The conductance can be controlled by a gate electric field in a field effect transistor, which is a main component of the integrated circuit. Optical phenomena induced by an electric field such as electroluminescence and electrochromism are useful for display and other technologies. Control of microwave propagation seems also imperative for future wireless communication technology. Microwave properties in solids are dominated mostly by magnetic excitations, which cannot be easily controlled by an electric field. One of the solutions for this problem is utilizing magnetically induced ferroelectrics (multiferroics). Here we show that microwave nonreciprocity, which is difference between oppositely propagating microwaves, can be reversed by the external electric field in a multiferroic helimagnet Ba2Mg2Fe12O22. This result offers a new avenue for the electrical control of microwave properties.

Magnetoelectrical control of nonreciprocal microwave response in a multiferroic helimagnet

NASA Astrophysics Data System (ADS)

Iguchi, Y.; Nii, Y.; Onose, Y.

2017-05-01

The control of physical properties by external fields is essential in many contemporary technologies. For example, conductance can be controlled by a gate electric field in a field effect transistor, which is a main component of integrated circuits. Optical phenomena induced by an electric field such as electroluminescence and electrochromism are useful for display and other technologies. Control of microwave propagation is also important for future wireless communication technology. Microwave properties in solids are dominated mostly by magnetic excitations, which cannot be easily controlled by an electric field. One solution to this problem is to use magnetically induced ferroelectrics (multiferroics). Here we show that microwave nonreciprocity, that is, different refractive indices for microwaves propagating in opposite directions, could be reversed by an external electric field in a multiferroic helimagnet Ba2Mg2Fe12O22. This approach offers an avenue for the electrical control of microwave properties.

Molybdenum, molybdenum oxides, and their electrochemistry.

PubMed

Saji, Viswanathan S; Lee, Chi-Woo

2012-07-01

The electrochemical behaviors of molybdenum and its oxides, both in bulk and thin film dimensions, are critical because of their widespread applications in steels, electrocatalysts, electrochromic materials, batteries, sensors, and solar cells. An important area of current interest is electrodeposited CIGS-based solar cells where a molybdenum/glass electrode forms the back contact. Surprisingly, the basic electrochemistry of molybdenum and its oxides has not been reviewed with due attention. In this Review, we assess the scattered information. The potential and pH dependent active, passive, and transpassive behaviors of molybdenum in aqueous media are explained. The major surface oxide species observed, reversible redox transitions of the surface oxides, pseudocapacitance and catalytic reduction are discussed along with carefully conducted experimental results on a typical molybdenum glass back contact employed in CIGS-based solar cells. The applications of molybdenum oxides and the electrodeposition of molybdenum are briefly reviewed. Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Test-retest reliability of jump execution variables using mechanography: A comparison of jump protocols

USDA-ARS?s Scientific Manuscript database

Mechanography during the vertical jump test allows for evaluation of force-time variables reflecting jump execution, which may enhance screening for functional deficits that reduce physical performance and determining mechanistic causes underlying performance changes. However, utility of jump mechan...

Solution of the finite Milne problem in stochastic media with RVT Technique

NASA Astrophysics Data System (ADS)

Slama, Howida; El-Bedwhey, Nabila A.; El-Depsy, Alia; Selim, Mustafa M.

2017-12-01

This paper presents the solution to the Milne problem in the steady state with isotropic scattering phase function. The properties of the medium are considered as stochastic ones with Gaussian or exponential distributions and hence the problem treated as a stochastic integro-differential equation. To get an explicit form for the radiant energy density, the linear extrapolation distance, reflectivity and transmissivity in the deterministic case the problem is solved using the Pomraning-Eddington method. The obtained solution is found to be dependent on the optical space variable and thickness of the medium which are considered as random variables. The random variable transformation (RVT) technique is used to find the first probability density function (1-PDF) of the solution process. Then the stochastic linear extrapolation distance, reflectivity and transmissivity are calculated. For illustration, numerical results with conclusions are provided.

Photometric variability in earthshine observations.

PubMed

Langford, Sally V; Wyithe, J Stuart B; Turner, Edwin L

2009-04-01

The identification of an extrasolar planet as Earth-like will depend on the detection of atmospheric signatures or surface non-uniformities. In this paper we present spatially unresolved flux light curves of Earth for the purpose of studying a prototype extrasolar terrestrial planet. Our monitoring of the photometric variability of earthshine revealed changes of up to 23% per hour in the brightness of Earth's scattered light at around 600 nm, due to the removal of specular reflection from the view of the Moon. This variability is accompanied by reddening of the spectrum and results from a change in surface properties across the continental boundary between the Indian Ocean and Africa's east coast. Our results based on earthshine monitoring indicate that specular reflection should provide a useful tool in determining the presence of liquid water on extrasolar planets via photometric observations.

Investigation of techniques for inventorying forested regions. Volume 2: Forestry information system requirements and joint use of remotely sensed and ancillary data

NASA Technical Reports Server (NTRS)

Nalepka, R. F. (Principal Investigator); Cicone, R. C.; Malila, W. A.; Crist, E. P.

1977-01-01

The author has identified the following significant results. Effects of terrain topography in mountainous forested regions on LANDSAT signals and classifier training were found to be significant. The aspect of sloping terrain relative to the sun's azimuth was the major cause of variability. A relative insolation factor could be defined which, in a single variable, represents the joint effects of slope and aspect and solar geometry on irradiance. Forest canopy reflectances were bound, both through simulation, and empirically, to have nondiffuse reflectance characteristics. Training procedures could be improved by stratifying in the space of ancillary variables and training in each stratum. Application of the Tasselled-Cap transformation for LANDSAT data acquired over forested terrain could provide a viable technique for data compression and convenient physical interpretations.

Developmental differences in intra-individual variability in children with ADHD and ASD.

PubMed

van Belle, Janna; van Hulst, Branko M; Durston, Sarah

2015-12-01

Intra-individual variability reflects temporal variation within an individual's performance on a cognitive task. Children with developmental disorders, such as ADHD and ASD show increased levels of intra-individual variability. In typical development, intra-individual variability decreases sharply between the ages 6 and 20. The tight link between intra-individual variability and age has led to the suggestion that it may be marker of neural development. As there is accumulating evidence that ADHD and ASD are characterised by atypical neurodevelopmental trajectories, we set out to explore developmental changes in intra-individual variability in subjects with ADHD and ASD. We used propensity score matching to match a cross-sectional sample of children with ADHD, ASD and control subjects (N = 405, aged 6-19 years old) for age, IQ and gender. We used ex-Gaussian distribution parameters to characterise intra-individual variability on fast responses (sigma) and slow responses (tau). Results showed that there was a similar decrease in mean response times with age across groups, and an interaction between age and group for measures of variability, where there was a much lower rate of change in the variability parameters (sigma and tau) for subjects with ASD compared with the other two groups. Subjects with ADHD had higher intra-individual variability, reflected by both sigma and tau, but the rate of decrease in variability with age was similar to that of the controls. These results suggest that subjects with ADHD, ASD and controls differ in the rate at which intra-individual variability decreases during development, and support the idea that intra-individual variability may be a marker of neural development, mimicking the neurodevelopmental changes in these disorders. © 2015 Association for Child and Adolescent Mental Health.

Remote-sensing reflectance determinations in the coastal ocean environment: impact of instrumental characteristics and environmental variability.

PubMed

Toole, D A; Siegel, D A; Menzies, D W; Neumann, M J; Smith, R C

2000-01-20

Three independent ocean color sampling methodologies are compared to assess the potential impact of instrumental characteristics and environmental variability on shipboard remote-sensing reflectance observations from the Santa Barbara Channel, California. Results indicate that under typical field conditions, simultaneous determinations of incident irradiance can vary by 9-18%, upwelling radiance just above the sea surface by 8-18%, and remote-sensing reflectance by 12-24%. Variations in radiometric determinations can be attributed to a variety of environmental factors such as Sun angle, cloud cover, wind speed, and viewing geometry; however, wind speed is isolated as the major source of uncertainty. The above-water approach to estimating water-leaving radiance and remote-sensing reflectance is highly influenced by environmental factors. A model of the role of wind on the reflected sky radiance measured by an above-water sensor illustrates that, for clear-sky conditions and wind speeds greater than 5 m/s, determinations of water-leaving radiance at 490 nm are undercorrected by as much as 60%. A data merging procedure is presented to provide sky radiance correction parameters for above-water remote-sensing reflectance estimates. The merging results are consistent with statistical and model findings and highlight the importance of multiple field measurements in developing quality coastal oceanographic data sets for satellite ocean color algorithm development and validation.

Reflective Learning and Prospective Teachers' Conceptual Understanding, Critical Thinking, Problem Solving, and Mathematical Communication Skills

ERIC Educational Resources Information Center

Junsay, Merle L.

2016-01-01

This is a quasi-experimental study that explored the effects of reflective learning on prospective teachers' conceptual understanding, critical thinking, problem solving, and mathematical communication skills and the relationship of these variables. It involved 60 prospective teachers from two basic mathematics classes of an institution of higher…

An Examination of Geography Teachers' Reflective Thinking Tendencies

ERIC Educational Resources Information Center

Yildirim, Tahsin

2017-01-01

This study is a descriptive research study executed using a scanning model with the purpose of examining geography teachers' tendencies towards reflective thinking according to different variables. The study group consisted of 218 geography teachers serving in schools under the Ministry of National Education in the 2016/2017 education period. For…

Evidence of Reflective Thinking across the Curriculum: College Experience versus Individual Courses

ERIC Educational Resources Information Center

Sargent, Carol Springer

2015-01-01

This study investigated how individual and course-level variables across the curriculum at a four-year college (college here refers to a higher education institution that offers undergraduate education but not graduate degrees) in the southeastern US impacted student reflective thinking as measured by Kember and colleagues' [2000. Development of a…

Variability and Spectral Studies of Luminous Seyfert 1 Galaxy Fairall 9. Search for the Reflection Component is a Quasar: RXTE and ASCA Observation of a Nearby Radio-Quiet Quasar MR 2251-178

NASA Technical Reports Server (NTRS)

Leighly, Karen M.

1999-01-01

Monitoring observations with interval of 3 days using RXTE (X Ray Timing Explorer) of the luminous Seyfert 1 galaxy Fairall 9 were performed for one year. The purpose of the observations were to study the variability of Fairall 9 and compare the results with those from the radio-loud object 3C 390.3. The data has been received and analysis is underway, using the new background model. An observation of the quasar MR 2251-178 was made in order to determine whether or not it has a reflection component. Older background models gave an unacceptable subtraction and analysis is underway using the new background model. The observation of NGC 6300 showed that the X-ray spectrum from this Seyfert 2 galaxy appears to be dominated by Compton reflection.

Bayesian estimation of seasonal course of canopy leaf area index from hyperspectral satellite data

NASA Astrophysics Data System (ADS)

Varvia, Petri; Rautiainen, Miina; Seppänen, Aku

2018-03-01

In this paper, Bayesian inversion of a physically-based forest reflectance model is investigated to estimate of boreal forest canopy leaf area index (LAI) from EO-1 Hyperion hyperspectral data. The data consist of multiple forest stands with different species compositions and structures, imaged in three phases of the growing season. The Bayesian estimates of canopy LAI are compared to reference estimates based on a spectral vegetation index. The forest reflectance model contains also other unknown variables in addition to LAI, for example leaf single scattering albedo and understory reflectance. In the Bayesian approach, these variables are estimated simultaneously with LAI. The feasibility and seasonal variation of these estimates is also examined. Credible intervals for the estimates are also calculated and evaluated. The results show that the Bayesian inversion approach is significantly better than using a comparable spectral vegetation index regression.

Recovery of components of memory in post-traumatic amnesia.

PubMed

Leach, Kathleen; Kinsella, Glynda; Jackson, Martin; Matyas, Tom

2006-11-01

Post-traumatic amnesia by definition indicates significant impairment of new learning ability, however very few studies have, examined the natural history and resolution of memory and new learning during PTA. Those studies which have, tended to examine orientation separately from the memory processes required to achieve orientation. Analysis of the order of recovery of the items of the Westmead PTA scale was used to examine recovery of memory and new learning capacity. The results of daily assessment of 34 patients with traumatic brain injury (TBI) on the Westmead PTA scale were analysed for order of recovery. The pattern of rank order of item recovery indicated that Date of Birth recovered consistently first. There was variability in the remaining items, however items reflecting long-term memory tended to recover second and items reflecting simple new learning followed. Recall of all three pictures reflecting complex new learning recovered last. The pattern of recovery of memory and new learning during PTA reflects a number of complex, inter-related variables including; the familiarity with the information, amount of rehearsal both before and since the accident and the number of cues available in the environment.

Reflecting Solutions of High Order Elliptic Differential Equations in Two Independent Variables Across Analytic Arcs. Ph.D. Thesis

NASA Technical Reports Server (NTRS)

Carleton, O.

1972-01-01

Consideration is given specifically to sixth order elliptic partial differential equations in two independent real variables x, y such that the coefficients of the highest order terms are real constants. It is assumed that the differential operator has distinct characteristics and that it can be factored as a product of second order operators. By analytically continuing into the complex domain and using the complex characteristic coordinates of the differential equation, it is shown that its solutions, u, may be reflected across analytic arcs on which u satisfies certain analytic boundary conditions. Moreover, a method is given whereby one can determine a region into which the solution is extensible. It is seen that this region of reflection is dependent on the original domain of difinition of the solution, the arc and the coefficients of the highest order terms of the equation and not on any sufficiently small quantities; i.e., the reflection is global in nature. The method employed may be applied to similar differential equations of order 2n.

Variability in Global Top-of-Atmosphere Shortwave Radiation Between 2000 and 2005

NASA Technical Reports Server (NTRS)

Loebe, Norman G.; Wielicki, Bruce A.; Rose, Fred G.; Doelling, David R.

2007-01-01

Measurements from various instruments and analysis techniques are used to directly compare changes in Earth-atmosphere shortwave (SW) top-of-atmosphere (TOA) radiation between 2000 and 2005. Included in the comparison are estimates of TOA reflectance variability from published ground-based Earthshine observations and from new satellite-based CERES, MODIS and ISCCP results. The ground-based Earthshine data show an order-of-magnitude more variability in annual mean SW TOA flux than either CERES or ISCCP, while ISCCP and CERES SW TOA flux variability is consistent to 40%. Most of the variability in CERES TOA flux is shown to be dominated by variations global cloud fraction, as observed using coincident CERES and MODIS data. Idealized Earthshine simulations of TOA SW radiation variability for a lunar-based observer show far less variability than the ground-based Earthshine observations, but are still a factor of 4-5 times more variable than global CERES SW TOA flux results. Furthermore, while CERES global albedos exhibit a well-defined seasonal cycle each year, the seasonal cycle in the lunar Earthshine reflectance simulations is highly variable and out-of-phase from one year to the next. Radiative transfer model (RTM) approaches that use imager cloud and aerosol retrievals reproduce most of the change in SW TOA radiation observed in broadband CERES data. However, assumptions used to represent the spectral properties of the atmosphere, clouds, aerosols and surface in the RTM calculations can introduce significant uncertainties in annual mean changes in regional and global SW TOA flux.

Variability in global top-of-atmosphere shortwave radiation between 2000 and 2005

NASA Astrophysics Data System (ADS)

Loeb, Norman G.; Wielicki, Bruce A.; Rose, Fred G.; Doelling, David R.

2007-02-01

Measurements from various instruments and analysis techniques are used to directly compare changes in Earth-atmosphere shortwave (SW) top-of-atmosphere (TOA) radiation between 2000 and 2005. Included in the comparison are estimates of TOA reflectance variability from published ground-based Earthshine observations and from new satellite-based CERES, MODIS and ISCCP results. The ground-based Earthshine data show an order-of-magnitude more variability in annual mean SW TOA flux than either CERES or ISCCP, while ISCCP and CERES SW TOA flux variability is consistent to 40%. Most of the variability in CERES TOA flux is shown to be dominated by variations global cloud fraction, as observed using coincident CERES and MODIS data. Idealized Earthshine simulations of TOA SW radiation variability for a lunar-based observer show far less variability than the ground-based Earthshine observations, but are still a factor of 4-5 times more variable than global CERES SW TOA flux results. Furthermore, while CERES global albedos exhibit a well-defined seasonal cycle each year, the seasonal cycle in the lunar Earthshine reflectance simulations is highly variable and out-of-phase from one year to the next. Radiative transfer model (RTM) approaches that use imager cloud and aerosol retrievals reproduce most of the change in SW TOA radiation observed in broadband CERES data. However, assumptions used to represent the spectral properties of the atmosphere, clouds, aerosols and surface in the RTM calculations can introduce significant uncertainties in annual mean changes in regional and global SW TOA flux.

Mechanism of variable structural colour in the neon tetra: quantitative evaluation of the Venetian blind model.

PubMed

Yoshioka, S; Matsuhana, B; Tanaka, S; Inouye, Y; Oshima, N; Kinoshita, S

2011-01-06

The structural colour of the neon tetra is distinguishable from those of, e.g., butterfly wings and bird feathers, because it can change in response to the light intensity of the surrounding environment. This fact clearly indicates the variability of the colour-producing microstructures. It has been known that an iridophore of the neon tetra contains a few stacks of periodically arranged light-reflecting platelets, which can cause multilayer optical interference phenomena. As a mechanism of the colour variability, the Venetian blind model has been proposed, in which the light-reflecting platelets are assumed to be tilted during colour change, resulting in a variation in the spacing between the platelets. In order to quantitatively evaluate the validity of this model, we have performed a detailed optical study of a single stack of platelets inside an iridophore. In particular, we have prepared a new optical system that can simultaneously measure both the spectrum and direction of the reflected light, which are expected to be closely related to each other in the Venetian blind model. The experimental results and detailed analysis are found to quantitatively verify the model.

Variable frequency microwave furnace system

DOEpatents

Bible, Don W.; Lauf, Robert J.

1994-01-01

A variable frequency microwave furnace system (10) designed to allow modulation of the frequency of the microwaves introduced into a furnace cavity (34) for testing or other selected applications. The variable frequency microwave furnace system (10) includes a microwave signal generator (12) or microwave voltage-controlled oscillator (14) for generating a low-power microwave signal for input to the microwave furnace. A first amplifier (18) may be provided to amplify the magnitude of the signal output from the microwave signal generator (12) or the microwave voltage-controlled oscillator (14). A second amplifier (20) is provided for processing the signal output by the first amplifier (18). The second amplifier (20) outputs the microwave signal input to the furnace cavity (34). In the preferred embodiment, the second amplifier (20) is a traveling-wave tube (TWT). A power supply (22) is provided for operation of the second amplifier (20). A directional coupler (24) is provided for detecting the direction of a signal and further directing the signal depending on the detected direction. A first power meter (30) is provided for measuring the power delivered to the microwave furnace (32). A second power meter (26) detects the magnitude of reflected power. Reflected power is dissipated in the reflected power load (28).

The X-ray variability history of Markarian 3

NASA Astrophysics Data System (ADS)

Guainazzi, M.; La Parola, V.; Miniutti, G.; Segreto, A.; Longinotti, A. L.

2012-11-01

Context. The unified scenario for active galactic nuclei (AGN) postulates that our orientation with respect to a parsec-scale azimuthally-symmetric gas and dust system causes the difference in their phenomenology in the optical/UV and X-ray bands. Only recently have high-resolution radio (VLBI) and IR interferometric observations provided direct constraints on the size and structure of this obscuring system (known historically as the "torus"). On the other hand, variability in optically-thick X-ray absorption and reprocessing in heavily obscured AGN often probe smaller scales, down to the broad line region and beyond. Aims: We aim at constraining the geometry of the reprocessing matter in the nearby prototypical Seyfert 2 Galaxy Markarian 3 by studying the time evolution of the spectral components associated to the primary AGN emission and to its Compton-scattering. Methods: We analyzed archival spectroscopic observations of Markarian 3 taken over the last ≃ 12 years with the XMM-Newton, Suzaku and Swift observatories, as well as data taken during a monitoring campaign activated by us in 2012. Results: The timescale of the Compton-reflection component variability (originally discovered by ASCA in the mid-'90s) is ≲ 64 days. This upper limit improves by more than a factor of 15 on previous estimates of the Compton-reflection variability timescale for this source. When the light curve of the Compton-reflection continuum in the 4-5 keV band is correlated with the 15-150 keV Swift/BAT curve, a delay ≳1200 days is found. The cross-correlation results depend on the model used to fit the spectra, although the detection of the Compton-reflection component variability is independent of the range of models employed to fit the data. Reanalysis of an archival Chandra image of Markarian 3 indicates that the Compton-reflection and the Fe Kα emitting regions are extended to the north up to ≃300 pc. The combination of these findings suggests that the optically-thick reprocessor in Markarian 3 is clumpy. Conclusions: There is mounting experimental evidence that the structure of the optically-thick gas and dust in the nuclear environment of nearby heavily obscured AGN is extended and complex. We discuss possible modifications to the standard unification scenarios encompassing this complexity. Markarian 3, which exhibits X-ray absorption and reprocessing on widely different spatial scales, is an ideal laboratory to test these models.

Detection and evaluation of ventricular repolarization alternans: an approach to combined ECG, thoracic impedance, and beat-to-beat heart rate variability analysis.

PubMed

Kriščiukaitis, Algimantas; Šimoliūnienė, Renata; Macas, Andrius; Petrolis, Robertas; Drėgūnas, Kęstutis; Bakšytė, Giedrė; Pieteris, Linas; Bertašienė, Zita; Žaliūnas, Remigijus

2014-01-01

Beat-to-beat alteration in ventricles repolarization reflected by alternans of amplitude and/or shape of ECG S-T,T segment (TWA) is known as phenomena related with risk of severe arrhythmias leading to sudden cardiac death. Technical difficulties have caused limited its usage in clinical diagnostics. Possibilities to register and analyze multimodal signals reflecting heart activity inspired search for new technical solutions. First objective of this study was to test whether thoracic impedance signal and beat-to-beat heart rate reflect repolarization alternans detected as TWA. The second objective was revelation of multimodal signal features more comprehensively representing the phenomena and increasing its prognostic usefulness. ECG, and thoracic impedance signal recordings made during 24h follow-up of the patients hospitalized in acute phase of myocardial infarction were used for investigation. Signal morphology variations reflecting estimates were obtained by the principal component analysis-based method. Clinical outcomes of patients (survival and/or rehospitalization in 6 and 12 months) were compared to repolarization alternans and heart rate variability estimates. Repolarization alternans detected as TWA was also reflected in estimates of thoracic impedance signal shape and variation in beat-to-beat heart rate. All these parameters showed correlation with clinical outcomes of patients. The strongest significant correlation showed magnitude of alternans in estimates of thoracic impedance signal shape. The features of ECG, thoracic impedance signal and beat-to-beat variability of heart rate, give comprehensive estimates of repolarization alternans, which correlate, with clinical outcomes of the patients and we recommend using them to improve diagnostic reliability. Copyright © 2014 Lithuanian University of Health Sciences. Production and hosting by Elsevier Urban & Partner Sp. z o.o. All rights reserved.

40 CFR 63.1207 - What are the performance testing requirements?

Code of Federal Regulations, 2010 CFR

2010-07-01

... operating conditions that are most likely to reflect daily maximum operating variability, similar to a... operating variability, similar to a dioxin/furan compliance test; (B) You have not changed the design or... document the temperature location measurement in the comprehensive performance test plan, as required by...

Spatio-temporal response of maize yield to edaphic and meteorological conditions in a saline farmland

USDA-ARS?s Scientific Manuscript database

Spatio-temporal variability of crop production strongly depends on soil heterogeneity, meteorological conditions, and their interaction. Canopy reflectance can be used to describe crop status and yield spatial variability. The objectives of this work were to understand the spatio-temporal variabilit...

Climate variability and plant response at the Santa Rita Experimental Range, Arizona

Treesearch

Michael A. Crimmins; Theresa M. Mau-Crimmins

2003-01-01

Climatic variability is reflected in differential establishment, persistence, and spread of plant species. Although studies have investigated these relationships for some species and functional groups, few have attempted to characterize the specific sequences of climatic conditions at various temporal scales (subseasonal, seasonal, and interannual) associated with...

Improving canopy sensor algorithms with soil and weather information

USDA-ARS?s Scientific Manuscript database

Nitrogen (N) need to support corn (Zea mays L.) production can be highly variable within fields. Canopy reflectance sensing for assessing crop N health has been implemented on many farmers’ fields to side-dress or top-dress variable-rate N application, but at times farmers report the performance of ...

Predictive models for Escherichia coli concentrations at inland lake beaches and relationship of model variables to pathogen detection

EPA Science Inventory

Methods are needed improve the timeliness and accuracy of recreational water‐quality assessments. Traditional culture methods require 18–24 h to obtain results and may not reflect current conditions. Predictive models, based on environmental and water quality variables, have been...

Variability of human corticospinal excitability tracks the state of action preparation.

PubMed

Klein-Flügge, Miriam C; Nobbs, David; Pitcher, Julia B; Bestmann, Sven

2013-03-27

Task-evoked trial-by-trial variability is a ubiquitous property of neural responses, yet its functional role remains largely unclear. Recent work in nonhuman primates shows that the temporal structure of neural variability in several brain regions is task-related. For example, trial-by-trial variability in premotor cortex tracks motor preparation with increasingly consistent firing rates and thus a decline in variability before movement onset. However, whether noninvasive measures of the variability of population activity available from humans can similarly track the preparation of actions remains unknown. We tested this by using single-pulse transcranial magnetic stimulation (TMS) over primary motor cortex (M1) to measure corticospinal excitability (CSE) at different times during action preparation. First, we established the basic properties of intrinsic CSE variability at rest. Then, during the task, responses (left or right button presses) were either directly instructed (forced choice) or resulted from a value decision (choice). Before movement onset, we observed a temporally specific task-related decline in CSE variability contralateral to the responding hand. This decline was stronger in fast-response compared with slow-response trials, consistent with data in nonhuman primates. For the nonresponding hand, CSE variability also decreased, but only in choice trials, and earlier compared with the responding hand, possibly reflecting choice-specific suppression of unselected actions. These findings suggest that human CSE variability measured by TMS over M1 tracks the state of motor preparation, and may reflect the optimization of preparatory population activity. This provides novel avenues in humans to assess the dynamics of action preparation but also more complex processes, such as choice-to-action transformations.

Refractive Index Imaging of Cells with Variable-Angle Near-Total Internal Reflection (TIR) Microscopy.

PubMed

Bohannon, Kevin P; Holz, Ronald W; Axelrod, Daniel

2017-10-01

The refractive index in the interior of single cells affects the evanescent field depth in quantitative studies using total internal reflection (TIR) fluorescence, but often that index is not well known. We here present method to measure and spatially map the absolute index of refraction in a microscopic sample, by imaging a collimated light beam reflected from the substrate/buffer/cell interference at variable angles of incidence. Above the TIR critical angle (which is a strong function of refractive index), the reflection is 100%, but in the immediate sub-critical angle zone, the reflection intensity is a very strong ascending function of incidence angle. By analyzing the angular position of that edge at each location in the field of view, the local refractive index can be estimated. In addition, by analyzing the steepness of the edge, the distance-to-substrate can be determined. We apply the technique to liquid calibration samples, silica beads, cultured Chinese hamster ovary cells, and primary culture chromaffin cells. The optical technique suffers from decremented lateral resolution, scattering, and interference artifacts. However, it still provides reasonable results for both refractive index (~1.38) and for distance-to-substrate (~150 nm) for the cells, as well as a lateral resolution to about 1 µm.

Pollen-based reconstruction of Holocene climate variability in the Eifel region evaluated with stable isotopes

NASA Astrophysics Data System (ADS)

Kühl, Norbert; Moschen, Robert; Wagner, Stefanie

2010-05-01

Pollen as well as stable isotopes have great potential as climate proxy data. While variability in these proxy data is frequently assumed to reflect climate variability, other factors than climate, including human impact and statistical noise, can often not be excluded as primary cause for the observed variability. Multiproxy studies offer the opportunity to test different drivers by providing different lines of evidence for environmental change such as climate variability and human impact. In this multiproxy study we use pollen and peat humification to evaluate to which extent stable oxygen and carbon isotope series from the peat bog "Dürres Maar" reflect human impact rather than climate variability. For times before strong anthropogenic vegetation change, isotope series from Dürres Maar were used to validate quantitative reconstructions based on pollen. Our study site is the kettle hole peat bog "Dürres Maar" in the Eifel low mountain range, Germany (450m asl), which grew 12m during the last 10,000 years. Pollen was analysed with a sum of at least 1000 terrestrial pollen grains throughout the profile to minimize statistical effects on the reconstructions. A recently developed probabilistic indicator taxa method ("pdf-method") was used for the quantitative climate estimates (January and July temperature) based on pollen. For isotope analysis, attention was given to use monospecific Sphagnum leaves whenever possible, reducing the potential of a species effect and any potential artefact that can originate from selective degradation of different morphological parts of Sphagnum plants (Moschen et al., 2009). Pollen at "Dürres Maar" reflect the variable and partly strong human impact on vegetation during the last 4000 years. Stable isotope time series were apparently not influenced by human impact at this site. This highlights the potential of stable isotope investigations from peat for climatic interpretation, because stable isotope series from lacustrine sediments might strongly react to anthropogenic deforestation, as carbon isotope time series from the adjacent Lake Holzmaar suggest. Reconstructions based on pollen with the pdf-method are robust to the human impact during the last 4000 years, but do not reproduce the fine scale climate variability that can be derived from the stable isotope series (Kühl et al., in press). In contrast, reconstructions on the basis of pollen data show relatively pronounced climate variability (here: January temperature) during the Mid-Holocene, which is known from many other European records. The oxygen isotope time series as available now indicate that at least some of the observed variability indeed reflects climate variability. However, stable carbon isotopes show little concordance. At this stage our results point in the direction that 1) the isotopic composition might reflect a shift in influencing factors during the Holocene, 2) climate trends can robustly be reconstructed with the pdf method and 3) fine scale climate variability can potentially be reconstructed using the pdf-method, given that climate sensitive taxa at their distribution limit are present. The latter two conclusions are of particular importance for the reconstruction of climatic trends and variability of interglacials older than the Holocene, when sites are rare and pollen is often the only suitable proxy in terrestrial records. Kühl, N., Moschen, R., Wagner, S., Brewer, S., Peyron, O., in press. A multiproxy record of Late Holocene natural and anthropogenic environmental change from the Sphagnum peat bog Dürres Maar, Germany: implications for quantitative climate reconstructions based on pollen. J. Quat. Sci., DOI: 10.1002/jqs.1342. Available online. Moschen, R., Kühl, N., Rehberger, I., Lücke, A., 2009. Stable carbon and oxygen isotopes in sub-fossil Sphagnum: Assessment of their applicability for palaeoclimatology. Chemical Geology 259, 262-272.

Estimation of Nitrogen Vertical Distribution by Bi-Directional Canopy Reflectance in Winter Wheat

PubMed Central

Huang, Wenjiang; Yang, Qinying; Pu, Ruiliang; Yang, Shaoyuan

2014-01-01

Timely measurement of vertical foliage nitrogen distribution is critical for increasing crop yield and reducing environmental impact. In this study, a novel method with partial least square regression (PLSR) and vegetation indices was developed to determine optimal models for extracting vertical foliage nitrogen distribution of winter wheat by using bi-directional reflectance distribution function (BRDF) data. The BRDF data were collected from ground-based hyperspectral reflectance measurements recorded at the Xiaotangshan Precision Agriculture Experimental Base in 2003, 2004 and 2007. The view zenith angles (1) at nadir, 40° and 50°; (2) at nadir, 30° and 40°; and (3) at nadir, 20° and 30° were selected as optical view angles to estimate foliage nitrogen density (FND) at an upper, middle and bottom layer, respectively. For each layer, three optimal PLSR analysis models with FND as a dependent variable and two vegetation indices (nitrogen reflectance index (NRI), normalized pigment chlorophyll index (NPCI) or a combination of NRI and NPCI) at corresponding angles as explanatory variables were established. The experimental results from an independent model verification demonstrated that the PLSR analysis models with the combination of NRI and NPCI as the explanatory variables were the most accurate in estimating FND for each layer. The coefficients of determination (R2) of this model between upper layer-, middle layer- and bottom layer-derived and laboratory-measured foliage nitrogen density were 0.7335, 0.7336, 0.6746, respectively. PMID:25353983

Estimation of nitrogen vertical distribution by bi-directional canopy reflectance in winter wheat.

PubMed

Huang, Wenjiang; Yang, Qinying; Pu, Ruiliang; Yang, Shaoyuan

2014-10-28

Timely measurement of vertical foliage nitrogen distribution is critical for increasing crop yield and reducing environmental impact. In this study, a novel method with partial least square regression (PLSR) and vegetation indices was developed to determine optimal models for extracting vertical foliage nitrogen distribution of winter wheat by using bi-directional reflectance distribution function (BRDF) data. The BRDF data were collected from ground-based hyperspectral reflectance measurements recorded at the Xiaotangshan Precision Agriculture Experimental Base in 2003, 2004 and 2007. The view zenith angles (1) at nadir, 40° and 50°; (2) at nadir, 30° and 40°; and (3) at nadir, 20° and 30° were selected as optical view angles to estimate foliage nitrogen density (FND) at an upper, middle and bottom layer, respectively. For each layer, three optimal PLSR analysis models with FND as a dependent variable and two vegetation indices (nitrogen reflectance index (NRI), normalized pigment chlorophyll index (NPCI) or a combination of NRI and NPCI) at corresponding angles as explanatory variables were established. The experimental results from an independent model verification demonstrated that the PLSR analysis models with the combination of NRI and NPCI as the explanatory variables were the most accurate in estimating FND for each layer. The coefficients of determination (R2) of this model between upper layer-, middle layer- and bottom layer-derived and laboratory-measured foliage nitrogen density were 0.7335, 0.7336, 0.6746, respectively.

Predicting the In-Hospital Responsiveness to Treatment of Alcoholics. Social Factors as Predictors of Outcome. Brain Damage as a Factor in Treatment Outcome of Chronic Alcoholic Patients.

ERIC Educational Resources Information Center

Mascia, George V.; And Others

The authors attempt to locate predictor variables associated with the outcome of alcoholic treatment programs. Muscia's study focuses on the predictive potential of: (1) response to a GSR conditioning procedure; (2) several personality variables; and (3) age and IQ measures. Nine variables, reflecting diverse perspectives, were selected as a basis…

Normal aging reduces motor synergies in manual pointing.

PubMed

Verrel, Julius; Lövdén, Martin; Lindenberger, Ulman

2012-01-01

Depending upon its organization, movement variability may reflect poor or flexible control of a motor task. We studied adult age-related differences in the structure of postural variability in manual pointing using the uncontrolled manifold (UCM) method. Participants from 2 age groups (younger: 20-30 years; older: 70-80 years; 12 subjects per group) completed a total of 120 pointing trials to 2 different targets presented according to 3 schedules: blocked, alternating, and random. The age groups were similar with respect to basic kinematic variables, end point precision, as well as the accuracy of the biomechanical forward model of the arm. Following the uncontrolled manifold approach, goal-equivalent and nongoal-equivalent components of postural variability (goal-equivalent variability [GEV] and nongoal-equivalent variability [NGEV]) were determined for 5 time points of the movements (start, 10%, 50%, 90%, and end) and used to define a synergy index reflecting the flexibility/stability aspect of motor synergies. Toward the end of the movement, younger adults showed higher synergy indexes than older adults. Effects of target schedule were not reliable. We conclude that normal aging alters the organization of common multidegree-of-freedom movements, with older adults making less flexible use of motor abundance than younger adults. Copyright © 2012 Elsevier Inc. All rights reserved.

[Gene method for inconsistent hydrological frequency calculation. I: Inheritance, variability and evolution principles of hydrological genes].

PubMed

Xie, Ping; Wu, Zi Yi; Zhao, Jiang Yan; Sang, Yan Fang; Chen, Jie

2018-04-01

A stochastic hydrological process is influenced by both stochastic and deterministic factors. A hydrological time series contains not only pure random components reflecting its inheri-tance characteristics, but also deterministic components reflecting variability characteristics, such as jump, trend, period, and stochastic dependence. As a result, the stochastic hydrological process presents complicated evolution phenomena and rules. To better understand these complicated phenomena and rules, this study described the inheritance and variability characteristics of an inconsistent hydrological series from two aspects: stochastic process simulation and time series analysis. In addition, several frequency analysis approaches for inconsistent time series were compared to reveal the main problems in inconsistency study. Then, we proposed a new concept of hydrological genes origined from biological genes to describe the inconsistent hydrolocal processes. The hydrologi-cal genes were constructed using moments methods, such as general moments, weight function moments, probability weight moments and L-moments. Meanwhile, the five components, including jump, trend, periodic, dependence and pure random components, of a stochastic hydrological process were defined as five hydrological bases. With this method, the inheritance and variability of inconsistent hydrological time series were synthetically considered and the inheritance, variability and evolution principles were fully described. Our study would contribute to reveal the inheritance, variability and evolution principles in probability distribution of hydrological elements.

RMS Spectral Modelling - a powerful tool to probe the origin of variability in Active Galactic Nuclei

NASA Astrophysics Data System (ADS)

Mallick, Labani; Dewangan, Gulab chand; Misra, Ranjeev

2016-07-01

The broadband energy spectra of Active Galactic Nuclei (AGN) are very complex in nature with the contribution from many ingredients: accretion disk, corona, jets, broad-line region (BLR), narrow-line region (NLR) and Compton-thick absorbing cloud or TORUS. The complexity of the broadband AGN spectra gives rise to mean spectral model degeneracy, e.g, there are competing models for the broad feature near 5-7 keV in terms of blurred reflection and complex absorption. In order to overcome the energy spectral model degeneracy, the most reliable approach is to study the RMS variability spectrum which connects the energy spectrum with temporal variability. The origin of variability could be pivoting of the primary continuum, reflection and/or absorption. The study of RMS (Root Mean Square) spectra would help us to connect the energy spectra with the variability. In this work, we study the energy dependent variability of AGN by developing theoretical RMS spectral model in ISIS (Interactive Spectral Interpretation System) for different input energy spectra. In this talk, I would like to present results of RMS spectral modelling for few radio-loud and radio-quiet AGN observed by XMM-Newton, Suzaku, NuSTAR and ASTROSAT and will probe the dichotomy between these two classes of AGN.

Relationships between diffuse reflectance and vegetation canopy variables based on the radiative transfer theory

NASA Technical Reports Server (NTRS)

Park, J. K.; Deering, D. W.

1981-01-01

Out of the lengthy original expression of the diffuse reflectance formula, simple working equations were derived by employing characteristic parameters, which are independent of the canopy coverage and identifiable by field observations. The typical asymptotic nature of reflectance data that is usually observed in biomass studies was clearly explained. The usefulness of the simplified equations was demonstrated by the exceptionally close fit of the theoretical curves to two separately acquired data sets for alfalfa and shortgrass prairie canopies.

The role of personal values, urban form, and auto availability in the analysis of walking for transportation.

PubMed

Coogan, Matthew A; Karash, Karla H; Adler, Thomas; Sallis, James

2007-01-01

To examine the association of personal values, the built environment, and auto availability with walking for transportation. Participants were drawn from 11 U.S. metropolitan areas with good transit services. 865 adults who had recently made or were contemplating making a residential move. Respondents reported if walking was their primary mode for nine trip purposes. "Personal values" reflected ratings of 15 variables assessing attitudes about urban and environmental attributes, with high reliability (ot = 0.85). Neighborhood form was indicated by a three-item scale. Three binary variables were created to reflect (1) personal values, (2) neighborhood form, and (3) auto availability. The association with walking was reported for each of the three variables, each combination of two variables, and the combination of three variables. An analysis of covariance was applied, and a hierarchic linear regression model was developed. All three variables were associated with walking, and all three variables interacted. The standardized coefficients were 0.23for neighborhood form, 0.21 for autos per person, and 0.18 for personal values. Positive attitudes about urban attributes, living in a supportive neighborhood, and low automobile availability significantly predicted more walking for transportation. A framework for further research is proposed in which a factor representing the role of the automobile is examined explicitly in addition to personal values and urban form.

The intermediate-age pre-cataclysmic variables SDSS J172406+562003 and RE J2013+4002

NASA Astrophysics Data System (ADS)

Shimansky, V. V.; Borisov, N. V.; Nurtdinova, D. N.; Mitrofanova, A. A.; Vlasyuk, V. V.; Spiridonova, O. I.

2012-06-01

We have analyzed the physical status of the pre-cataclysmic variables SDSSJ172406+562003 and RE J2013+4002, which have evolved after their common-envelope stage a time t = 106-107 years. Spectroscopy and photometry of these systems were performed with the 6-m and 1-m telescopes of the Special Astrophysical Observatory. We demonstrate that emission lines in the spectra were formed solely by the reflection of radiation emitted by the white dwarfs on the surfaces of their cool companions, under conditions close to local thermodynamic equilibrium. These effects are also responsible for most of the objects' photometric variability amplitude. However, comparing the light curves of SDSS 172406 from different epochs, we find aperiodic brightness variations, probably due to spottedness of the surface of the secondary. Jointly analyzing the spectra, radial-velocity curves, and light curves of the pre-cataclysmic variables and modeling the reflection effects, we have derived their fundamental parameters. We demonstrate that the secondaries in these systems are consistent with evolutionary models for main-sequence stars and do not have the luminosity excesses characteristic of cool stars in young pre-cataclysmic variables.

Determinants of nursing competence of nursing students in Taiwan: the role of self-reflection and insight.

PubMed

Eng, Cheng-Joo; Pai, Hsiang-Chu

2015-03-01

A nursing practicum course is critical to strengthening the nursing competence of nursing students. Research has found that practice stress and coping behaviors can have either a negative or positive influence on the learning and practice performance of nursing students. Nevertheless, there are few evidence-based studies related to the relationship between self-reflection and insight and nursing competence in Taiwanese nursing students. To test the determinants and the effect of self-reflection and insight on nursing competence in nursing students during the first 2 months of their practice experience. Cross-sectional and correlational research designs were employed. From September to November 2013, a total of 312 nursing students at a junior college in southern Taiwan served as participants in this study. Four questionnaires were used to collect data: Self-reflection and Insight Scale (SRIS), Perceived Stress Scale (PSS), Coping Behavior Inventory (CBI), and Holistic Nursing Competence Scale (HNCS). The research model was evaluated through structural equation modeling (SEM), with the use of the partial least squares (PLS) method. Results indicated that self-reflection and insight, practice stress, and practice coping behavior were statistically significantly associated with nursing competence. In addition, self-reflection and insight were significantly and positively associated with practice coping behavior and negatively associated with practice stress. Students' coping behavior partially mediates the effect of self-reflection and stress on nursing competence. Overall, these variables explained 39.4% of the variance in these students' nursing competence. Self-reflection and insight affected nursing competence during the practice period. These variables have not only had a direct influence on nursing competence but also an indirect effect through the mediating effect of coping behavior and stress. Copyright © 2014 Elsevier Ltd. All rights reserved.

Endorsement of formal leaders: an integrative model.

PubMed

Michener, H A; Lawler, E J

1975-02-01

This experiment develops an integrative, path-analytic model for the endorsement accorded formal leaders. The model contains four independent variables reflecting aspects of group structure (i.e., group success-failure, the payoff distribution, the degree of support by others members for the leader, and the vulnerability of the leader). Also included are two intervening variables reflecting perceptual processes (attributed competence and attributed fairness), and one dependent variable endorsement). The results indicate that endorsement is greater when the group's success is high, when the payoff distribution is flat rather than hierarchial, and when the leader is not vulnerable to removal from office. Other support had no significant impact on endorsement. Analyses further demonstrate that the effect of success-failure on endorsement is mediated by attributed competence, while the effect of the payoff distributed is mediated by attributed fairness. These results suggest that moral and task evaluations are distinct bases of endorsement.

Variable temperature, variable-gap Otto prism coupler for use in a vacuum environment

NASA Astrophysics Data System (ADS)

Cairns, G. F.; O'Prey, S. M.; Dawson, P.

2000-11-01

The field of surface polariton physics really took off with the prism coupling techniques developed by Kretschmann and Raether, and by Otto. This article reports on the construction and operation of a rotatable, in vacuo, variable temperature, Otto coupler with a coupling gap that can be varied by remote control. The specific design attributes of the system offer additional advantages to those of standard Otto systems of (i) temperature variation (ambient to 85 K), and (ii) the use of a valuable, additional reference point, namely the gap-independent reflectance at the Brewster angle at any given, fixed temperature. The instrument is placed firmly in a historical context of developments in the field. The efficacy of the coupler is demonstrated by sample attenuated total reflectance results on films of platinum, niobium, and yttrium barium copper oxide and on aluminum/gallium arsenide (Al/GaAs) Schottky diode structures.

Systems, methods, and software for determining spatially variable distributions of the dielectric properties of a heterogeneous material

DOE Office of Scientific and Technical Information (OSTI.GOV)

Farrington, Stephen P.

Systems, methods, and software for measuring the spatially variable relative dielectric permittivity of materials along a linear or otherwise configured sensor element, and more specifically the spatial variability of soil moisture in one dimension as inferred from the dielectric profile of the soil matrix surrounding a linear sensor element. Various methods provided herein combine advances in the processing of time domain reflectometry data with innovations in physical sensing apparatuses. These advancements enable high temporal (and thus spatial) resolution of electrical reflectance continuously along an insulated waveguide that is permanently emplaced in contact with adjacent soils. The spatially resolved reflectance ismore » directly related to impedance changes along the waveguide that are dominated by electrical permittivity contrast due to variations in soil moisture. Various methods described herein are thus able to monitor soil moisture in profile with high spatial resolution.« less

Higher locus coeruleus MRI contrast is associated with lower parasympathetic influence over heart rate variability

PubMed Central

Mather, Mara; Yoo, Hyun Joo; Clewett, David V.; Lee, Tae-Ho; Greening, Steven G.; Ponzio, Allison; Min, Jungwon; Thayer, Julian F.

2017-01-01

The locus coeruleus (LC) is a key node of the sympathetic nervous system and suppresses parasympathetic activity that would otherwise increase heart rate variability. In the current study, we examined whether LC-MRI contrast reflecting neuromelanin accumulation in the LC was associated with high-frequency heart rate variability (HF-HRV), a measure reflecting parasympathetic influences on the heart. Recent evidence indicates that neuromelanin, a byproduct of catecholamine metabolism, accumulates in the LC through young and mid adulthood, suggesting that LC-MRI contrast may be a useful biomarker of individual differences in habitual LC activation. We found that, across younger and older adults, greater LC-MRI contrast was negatively associated with HF-HRV during fear conditioning and spatial detection tasks. This correlation was not accounted for by individual differences in age or anxiety. These findings indicate that individual differences in LC structure relate to key cardiovascular parameters. PMID:28215623

Thematic Mapper Analysis of Blue Oak (Quercus douglasii) in Central California

Treesearch

Paul A. Lefebvre Jr.; Frank W. Davis; Mark Borchert

1991-01-01

Digital Thematic Mapper (TM) satellite data from September 1986 and December 1985 were analyzed to determine seasonal reflectance properties of blue oak rangeland in the La Panza mountains of San Luis Obispo County. Linear regression analysis was conducted to examine relationships between TM reflectance and oak canopy cover, basal area, and site topographic variables....

Singing-Related Activity in Anterior Forebrain of Male Zebra Finches Reflects Courtship Motivation for Target Females

PubMed Central

Iwasaki, Mai; Poulsen, Thomas M.; Oka, Kotaro; Hessler, Neal A.

2013-01-01

A critical function of singing by male songbirds is to attract a female mate. Previous studies have suggested that the anterior forebrain system is involved in this courtship behavior. Neural activity in this system, including the striatal Area X, is strikingly dependent on the function of male singing. When males sing to attract a female bird rather than while alone, less variable neural activity results in less variable song spectral features, which may be attractive to the female. These characteristics of neural activity and singing thus may reflect a male's motivation for courtship. Here, we compared the variability of neural activity and song features between courtship singing directed to a female with whom a male had previously formed a pair-bond or to other females. Surprisingly, across all units, there was no clear tendency for a difference in variability of neural activity or song features between courtship of paired females, nonpaired females, or dummy females. However, across the population of recordings, there was a significant relationship between the relative variability of syllable frequency and neural activity: when syllable frequency was less variable to paired than nonpaired females, neural activity was also less variable (and vice-versa). These results show that the lower variability of neural activity and syllable frequency during directed singing is not a binary distinction from undirected singing, but can vary in intensity, possibly related to the relative preference of a male for his singing target. PMID:24312344

Influence of bulk microphysics schemes upon Weather Research and Forecasting (WRF) version 3.6.1 nor'easter simulations

NASA Astrophysics Data System (ADS)

Nicholls, Stephen D.; Decker, Steven G.; Tao, Wei-Kuo; Lang, Stephen E.; Shi, Jainn J.; Mohr, Karen I.

2017-03-01

This study evaluated the impact of five single- or double-moment bulk microphysics schemes (BMPSs) on Weather Research and Forecasting model (WRF) simulations of seven intense wintertime cyclones impacting the mid-Atlantic United States; 5-day long WRF simulations were initialized roughly 24 h prior to the onset of coastal cyclogenesis off the North Carolina coastline. In all, 35 model simulations (five BMPSs and seven cases) were run and their associated microphysics-related storm properties (hydrometer mixing ratios, precipitation, and radar reflectivity) were evaluated against model analysis and available gridded radar and ground-based precipitation products. Inter-BMPS comparisons of column-integrated mixing ratios and mixing ratio profiles reveal little variability in non-frozen hydrometeor species due to their shared programming heritage, yet their assumptions concerning snow and graupel intercepts, ice supersaturation, snow and graupel density maps, and terminal velocities led to considerable variability in both simulated frozen hydrometeor species and radar reflectivity. WRF-simulated precipitation fields exhibit minor spatiotemporal variability amongst BMPSs, yet their spatial extent is largely conserved. Compared to ground-based precipitation data, WRF simulations demonstrate low-to-moderate (0.217-0.414) threat scores and a rainfall distribution shifted toward higher values. Finally, an analysis of WRF and gridded radar reflectivity data via contoured frequency with altitude diagrams (CFADs) reveals notable variability amongst BMPSs, where better performing schemes favored lower graupel mixing ratios and better underlying aggregation assumptions.

Influence of Bulk Microphysics Schemes upon Weather Research and Forecasting (WRF) Version 3.6.1 Nor'easter Simulations.

PubMed

Nicholls, Stephen D; Decker, Steven G; Tao, Wei-Kuo; Lang, Stephen E; Shi, Jainn J; Mohr, Karen I

2017-01-01

This study evaluated the impact of five, single- or double- moment bulk microphysics schemes (BMPSs) on Weather Research and Forecasting model (WRF) simulations of seven, intense winter time cyclones impacting the Mid-Atlantic United States. Five-day long WRF simulations were initialized roughly 24 hours prior to the onset of coastal cyclogenesis off the North Carolina coastline. In all, 35 model simulations (5 BMPSs and seven cases) were run and their associated microphysics-related storm properties (hydrometer mixing ratios, precipitation, and radar reflectivity) were evaluated against model analysis and available gridded radar and ground-based precipitation products. Inter-BMPS comparisons of column-integrated mixing ratios and mixing ratio profiles reveal little variability in non-frozen hydrometeor species due to their shared programming heritage, yet their assumptions concerning snow and graupel intercepts, ice supersaturation, snow and graupel density maps, and terminal velocities lead to considerable variability in both simulated frozen hydrometeor species and radar reflectivity. WRF-simulated precipitation fields exhibit minor spatio-temporal variability amongst BMPSs, yet their spatial extent is largely conserved. Compared to ground-based precipitation data, WRF-simulations demonstrate low-to-moderate (0.217-0.414) threat scores and a rainfall distribution shifted toward higher values. Finally, an analysis of WRF and gridded radar reflectivity data via contoured frequency with altitude (CFAD) diagrams reveals notable variability amongst BMPSs, where better performing schemes favored lower graupel mixing ratios and better underlying aggregation assumptions.

Influence of Bulk Microphysics Schemes upon Weather Research and Forecasting (WRF) Version 3.6.1 Nor'easter Simulations

PubMed Central

Nicholls, Stephen D.; Decker, Steven G.; Tao, Wei-Kuo; Lang, Stephen E.; Shi, Jainn J.; Mohr, Karen I.

2018-01-01

This study evaluated the impact of five, single- or double- moment bulk microphysics schemes (BMPSs) on Weather Research and Forecasting model (WRF) simulations of seven, intense winter time cyclones impacting the Mid-Atlantic United States. Five-day long WRF simulations were initialized roughly 24 hours prior to the onset of coastal cyclogenesis off the North Carolina coastline. In all, 35 model simulations (5 BMPSs and seven cases) were run and their associated microphysics-related storm properties (hydrometer mixing ratios, precipitation, and radar reflectivity) were evaluated against model analysis and available gridded radar and ground-based precipitation products. Inter-BMPS comparisons of column-integrated mixing ratios and mixing ratio profiles reveal little variability in non-frozen hydrometeor species due to their shared programming heritage, yet their assumptions concerning snow and graupel intercepts, ice supersaturation, snow and graupel density maps, and terminal velocities lead to considerable variability in both simulated frozen hydrometeor species and radar reflectivity. WRF-simulated precipitation fields exhibit minor spatio-temporal variability amongst BMPSs, yet their spatial extent is largely conserved. Compared to ground-based precipitation data, WRF-simulations demonstrate low-to-moderate (0.217–0.414) threat scores and a rainfall distribution shifted toward higher values. Finally, an analysis of WRF and gridded radar reflectivity data via contoured frequency with altitude (CFAD) diagrams reveals notable variability amongst BMPSs, where better performing schemes favored lower graupel mixing ratios and better underlying aggregation assumptions. PMID:29697705

Influence of Bulk Microphysics Schemes upon Weather Research and Forecasting (WRF) Version 3.6.1 Nor'easter Simulations

NASA Technical Reports Server (NTRS)

Nicholls, Stephen D.; Decker, Steven G.; Tao, Wei-Kuo; Lang, Stephen E.; Shi, Jainn J.; Mohr, Karen Irene

2017-01-01

This study evaluated the impact of five single- or double-moment bulk microphysics schemes (BMPSs) on Weather Research and Forecasting model (WRF) simulations of seven intense wintertime cyclones impacting the mid-Atlantic United States; 5-day long WRF simulations were initialized roughly 24 hours prior to the onset of coastal cyclogenesis off the North Carolina coastline. In all, 35 model simulations (five BMPSs and seven cases) were run and their associated microphysics-related storm properties (hydrometer mixing ratios, precipitation, and radar reflectivity) were evaluated against model analysis and available gridded radar and ground-based precipitation products. Inter-BMPS comparisons of column-integrated mixing ratios and mixing ratio profiles reveal little variability in non-frozen hydrometeor species due to their shared programming heritage, yet their assumptions concerning snow and graupel intercepts, ice supersaturation, snow and graupel density maps, and terminal velocities led to considerable variability in both simulated frozen hydrometeor species and radar reflectivity. WRF-simulated precipitation fields exhibit minor spatiotemporal variability amongst BMPSs, yet their spatial extent is largely conserved. Compared to ground-based precipitation data, WRF simulations demonstrate low-to-moderate (0.217 to 0.414) threat scores and a rainfall distribution shifted toward higher values. Finally, an analysis of WRF and gridded radar reflectivity data via contoured frequency with altitude (CFAD) diagrams reveals notable variability amongst BMPSs, where better performing schemes favored lower graupel mixing ratios and better underlying aggregation assumptions.

Study of Tropospheric Ozone and UV Reflectivity Using TOMS Data

NASA Technical Reports Server (NTRS)

Yung, Yuk L.

2002-01-01

Perhaps the single most important result from the study of Chuang and Yung is that the interannual variability of the Earth's albedo (especially in Spring) on land is dominated by snow/ice, and not by clouds. This interannual variability could be the major driver of changes in the atmosphere and the biosphere. It is plausible that the interannual variability of snow/ice, through interactions with the atmosphere and biosphere, is responsible for the interannual variability of atmospheric CO2. By carefully studying the albedo variations off the Peru coast, we found evidence for indirect aerosol effect on clouds. Based on a detailed analysis of the cloud data obtained by the International Satellite Cloud Climatology Project (SCCP) in the years 1983-1991, we show that besides the reported 3 % variation in global cloudiness, the global mean cloud optical thickness (MCOT) also has significant variation which is out of phase with that of the global cloudiness. The combined effect of the two opposing variations may be a null effect on the cloud reflectivity. These results are consistent with the Total Ozone Mapping Spectrometer (TOMS) reflectively measurements. The MCOT variation is further shown to be correlated with both the solar cycle and the ENSO (El Nino Southern Oscillation) cycle. Our present analysis cannot distinguish which of the above two provides better correlation, although independent data from the High resolution Infrared Radiation Sounder (HIRS) from 1990 to 1996 favor the solar cycle. Future data are needed to identify the true cause of these changes.

The Soft State of Cygnus X-1 Observed with NuSTAR: A Variable Corona and a Stable Inner Disk

NASA Technical Reports Server (NTRS)

Walton, D. J.; Tomsick, J. A.; Madsen, K. K.; Grinberg, V.; Barret, D.; Boggs, S. E.; Christensen, F. E.; Clavel, M.; Craig, W. W.; Fabian, A. C.;

Millennial-scale Climate Variations Recorded As Far Back As The Early Pliocene

NASA Astrophysics Data System (ADS)

Steenbrink, J.; Hilgen, F. J.; Lourens, L. J.

Quaternary climate proxy records show compelling evidence for climate variability on time scales of a few thousand years. The causes for these millennial-scale or sub- Milankovitch cycles are yet poorly understood, not in the least due to the complex feedback mechanisms of large ice-sheets during the Quaternary. We present evidence of millennial-scale climate variability in Early Pliocene lacustrine sediments from the intramontane Ptolemais Basin in northwestern Greece. The sediments are well ex- posed in a series of open-pit lignite mines and exhibit a distinct m-scale sedimentary cyclicity of alternating lignites and lacustrine marl beds that result from precession- induced variations in climate. A higher-frequency cyclicity is particular prominent within the marl segment of individual cycles. A stratigraphic interval of~115 kyr, cov- ering five precession-induced sedimentary cycles, was studied in nine parallel sections from two quarries located several km apart. Colour reflectance records were used to quantify the within-cycle variability and to determine its lateral continuity. Much of the within-cycle variability could be correlated between the parallel sections, even in fine detail, which suggests that these changes reflect basin-wide variations in environ- mental conditions related to (regional) climate fluctuations. Interbedded volcanic ash beds demonstrate the synchronicity of these fluctuations and spectral analysis of the reflectance time series shows a significant concentration of variability at periods of ~11,~5.5 and~2 kyr. Their occurrence at times before the intensification of the North- ern Hemisphere glaciation suggests that they cannot solely have resulted from internal ice-sheet dynamics. Possible candidates include harmonics or combination tones of the main orbital cycles, variations in solar output or periodic motions of the Earth and moon.

The Soft State of Cygnus X-1 Observed with NuSTAR: A Variable Corona and a Stable Inner Disk

NASA Astrophysics Data System (ADS)

Walton, D. J.; Tomsick, J. A.; Madsen, K. K.; Grinberg, V.; Barret, D.; Boggs, S. E.; Christensen, F. E.; Clavel, M.; Craig, W. W.; Fabian, A. C.; Fuerst, F.; Hailey, C. J.; Harrison, F. A.; Miller, J. M.; Parker, M. L.; Rahoui, F.; Stern, D.; Tao, L.; Wilms, J.; Zhang, W.

2016-07-01

We present a multi-epoch hard X-ray analysis of Cygnus X-1 in its soft state based on four observations with the Nuclear Spectroscopic Telescope Array (NuSTAR). Despite the basic similarity of the observed spectra, there is clear spectral variability between epochs. To investigate this variability, we construct a model incorporating both the standard disk-corona continuum and relativistic reflection from the accretion disk, based on prior work on Cygnus X-1, and apply this model to each epoch independently. We find excellent consistency for the black hole spin and the iron abundance of the accretion disk, which are expected to remain constant on observational timescales. In particular, we confirm that Cygnus X-1 hosts a rapidly rotating black hole, 0.93≲ {a}* ≲ 0.96, in broad agreement with the majority of prior studies of the relativistic disk reflection and constraints on the spin obtained through studies of the thermal accretion disk continuum. Our work also confirms the apparent misalignment between the inner disk and the orbital plane of the binary system reported previously, finding the magnitude of this warp to be ˜10°-15°. This level of misalignment does not significantly change (and may even improve) the agreement between our reflection results and the thermal continuum results regarding the black hole spin. The spectral variability observed by NuSTAR is dominated by the primary continuum, implying variability in the temperature of the scattering electron plasma. Finally, we consistently observe absorption from ionized iron at ˜6.7 keV, which varies in strength as a function of orbital phase in a manner consistent with the absorbing material being an ionized phase of the focused stellar wind from the supergiant companion star.

Measurement and Modeling of the Optical Scattering Properties of Crop Canopies

NASA Technical Reports Server (NTRS)

Vanderbilt, V. C. (Principal Investigator)

1985-01-01

The specular reflection process is shown to be a key aspect of radiation transfer by plant canopies. Polarization measurements are demonstrated as the tool for determining the specular and diffuse portions of the canopy radiance. The magnitude of the specular fraction of the reflectance is significant compared to the magnitude of the diffuse fraction. Therefore, it is necessary to consider specularly reflected light in developing and evaluating light-canopy interaction models for wheat canopies. Models which assume leaves are diffuse reflectors correctly predict only the diffuse fraction of the canopy reflectance factor. The specular reflectance model, when coupled with a diffuse leaf model, would predict both the specular and diffuse portions of the reflectance factor. The specular model predicts and the data analysis confirms that the single variable, angle of incidence of specularly reflected sunlight on the leaf, explains much of variation in the polarization data as a function of view-illumination directions.

Variable area light reflecting assembly

DOEpatents

Howard, T.C.

1986-12-23

Device is described for tracking daylight and projecting it into a building. The device tracks the sun and automatically adjusts both the orientation and area of the reflecting surface. The device may be mounted in either a wall or roof of a building. Additionally, multiple devices may be employed in a light shaft in a building, providing daylight to several different floors. The preferred embodiment employs a thin reflective film as the reflecting device. One edge of the reflective film is fixed, and the opposite end is attached to a spring-loaded take-up roller. As the sun moves across the sky, the take-up roller automatically adjusts the angle and surface area of the film. Additionally, louvers may be mounted at the light entrance to the device to reflect incoming daylight in an angle perpendicular to the device to provide maximum reflective capability when daylight enters the device at non-perpendicular angles. 9 figs.

Variable area light reflecting assembly

DOEpatents

Howard, Thomas C.

1986-01-01

Device for tracking daylight and projecting it into a building. The device tracks the sun and automatically adjusts both the orientation and area of the reflecting surface. The device may be mounted in either a wall or roof of a building. Additionally, multiple devices may be employed in a light shaft in a building, providing daylight to several different floors. The preferred embodiment employs a thin reflective film as the reflecting device. One edge of the reflective film is fixed, and the opposite end is attached to a spring-loaded take-up roller. As the sun moves across the sky, the take-up roller automatically adjusts the angle and surface area of the film. Additionally, louvers may be mounted at the light entrance to the device to reflect incoming daylight in an angle perpendicular to the device to provide maximum reflective capability when daylight enters the device at non-perpendicular angles.

Intra-Individual Reaction Time Variability in Schizophrenia, Depression and Borderline Personality Disorder

ERIC Educational Resources Information Center

Kaiser, Stefan; Roth, Alexander; Rentrop, Mirjam; Friederich, Hans-Christoph; Bender, Stephan; Weisbrod, Matthias

2008-01-01

Intra-individual reaction time variability (IIV) in neuropsychological task performance reflects short term fluctuations in performance. Increased IIV has been reported in patients with schizophrenia and could be related to a deficient neural timing mechanism, but the role of IIV in adult patients with other psychiatric disorders has not been…

The Transtheoretical Model's Stages and Processes of Change and Their Relation to Premature Termination.

ERIC Educational Resources Information Center

Smith, Kevin J., And Others

1995-01-01

Explores the issue of premature termination of therapy using the client readiness variables reflected in the stages and processes of change and proposed in Prochaska and DiClemente's transtheoretical model. This study used these variables to distinguish between premature and nonpremature terminators in a college counseling. Results indicated that…

Associations between Adolescents' Perceptions of Alcohol Norms and Alcohol Behaviors: Incorporating Within-School Variability

ERIC Educational Resources Information Center

François, Amir; Lindstrom Johnson, Sarah; Waasdorp, Tracy E.; Parker, Elizabeth M.; Bradshaw, Catherine P.

2017-01-01

Background: Social norm interventions have been implemented in schools to address concerns of alcohol use among high school students; however, research in this area has not incorporated measures of variability that may better reflect the complexity of social influences. Purpose: To examine the association between perceived alcohol norms, the…

Are Attractive Men's Faces Masculine or Feminine? The Importance of Controlling Confounds in Face Stimuli

ERIC Educational Resources Information Center

Debruine, Lisa M.; Jones, Benedict C.; Smith, Finlay G.; Little, Anthony C.

2010-01-01

Women's preferences for male masculinity are highly variable. Although many researchers explain this variability as reflecting systematic individual differences in how women resolve the tradeoff between the costs and benefits of choosing a masculine partner, others suggest that methodological differences between studies are responsible. A recent…

Does Response Variability Predict Distractibility among Adults with Attention-Deficit/Hyperactivity Disorder?

ERIC Educational Resources Information Center

Adams, Zachary W.; Roberts, Walter M.; Milich, Richard; Fillmore, Mark T.

2011-01-01

Increased intraindividual variability in response time (RTSD) has been observed reliably in attention-deficit/hyperactivity disorder (ADHD) and has often been used as a measure of inattention. RTSD is assumed to reflect attentional lapses and distractibility, though evidence for the validity of this connection is lacking. We assessed whether RTSD…

Profiles of the evaluators: impact of psychographic variables on the consumer-oriented quality assessment of mobile television

NASA Astrophysics Data System (ADS)

Jumisko-Pyykkö, Satu; Häkkinen, Jukka

2008-02-01

In the product development of services it is important to adjust mobile video quality according to the quality requirements of potential users. Therefore, a careful participant selection is very important. However, in the literature the details of participant selection are often handled without great detail. This is also reflected in the handling of experimental results, where the impact of psychographic factors on quality is rarely reported. As the user attributes potentially have a large effect to the results, we investigated the role of various psychographical variables on the subjective evaluation of audiovisual video quality in two different experiments. The studied variables were age, gender, education, professionalism, television consumption, experiences of different digital video qualities, and attitude towards technology. The results showed that quality evaluations were affected by almost all background factors. The most significant variables were age, professionalism, knowledge of digital quality features and attitude towards technology. The knowledge of these factors can be exploited in careful participant selection, which will in turn increase the validity of results as the subjective evaluations reflect better the requirements of potential users.

Barycentric parameterizations for isotropic BRDFs.

PubMed

Stark, Michael M; Arvo, James; Smits, Brian

2005-01-01

A bidirectional reflectance distribution function (BRDF) is often expressed as a function of four real variables: two spherical coordinates in each of the the "incoming" and "outgoing" directions. However, many BRDFs reduce to functions of fewer variables. For example, isotropic reflection can be represented by a function of three variables. Some BRDF models can be reduced further. In this paper, we introduce new sets of coordinates which we use to reduce the dimensionality of several well-known analytic BRDFs as well as empirically measured BRDF data. The proposed coordinate systems are barycentric with respect to a triangular support with a direct physical interpretation. One coordinate set is based on the BRDF model proposed by Lafortune. Another set, based on a model of Ward, is associated with the "halfway" vector common in analytical BRDF formulas. Through these coordinate sets we establish lower bounds on the approximation error inherent in the models on which they are based. We present a third set of coordinates, not based on any analytical model, that performs well in approximating measured data. Finally, our proposed variables suggest novel ways of constructing and visualizing BRDFs.

A Protective Factors Model for Alcohol Abuse and Suicide Prevention among Alaska Native Youth

PubMed Central

Allen, James; Mohatt, Gerald V.; Fok, Carlotta Ching Ting; Henry, David; Burkett, Rebekah

2014-01-01

This study provides an empirical test of a culturally grounded theoretical model for prevention of alcohol abuse and suicide risk with Alaska Native youth, using a promising set of culturally appropriate measures for the study of the process of change and outcome. This model is derived from qualitative work that generated an heuristic model of protective factors from alcohol (Allen at al., 2006; Mohatt, Hazel et al., 2004; Mohatt, Rasmus et al., 2004). Participants included 413 rural Alaska Native youth ages 12-18 who assisted in testing a predictive model of Reasons for Life and Reflective Processes about alcohol abuse consequences as co-occurring outcomes. Specific individual, family, peer, and community level protective factor variables predicted these outcomes. Results suggest prominent roles for these predictor variables as intermediate prevention strategy target variables in a theoretical model for a multilevel intervention. The model guides understanding of underlying change processes in an intervention to increase the ultimate outcome variables of Reasons for Life and Reflective Processes regarding the consequences of alcohol abuse. PMID:24952249