Sample records for w-na target bombarded

  1. Proton bombarded reactions of Calcium target nuclei

    NASA Astrophysics Data System (ADS)

    Tel, Eyyup; Sahan, Muhittin; Sarpün, Ismail Hakki; Kavun, Yusuf; Gök, Ali Armagan; Depedelen, Mesut

    2017-09-01

    In this study, proton bombarded nuclear reactions calculations of Calcium target nuclei have been investigated in the incident proton energy range of 1-50 MeV. The excitation functions for 40Ca target nuclei reactions have been calculated by using PCROSS nuclear reaction calculation code. Weisskopf-Ewing and the full exciton models were used for equilibrium and for pre-equilibrium calculations, respectively. The excitation functions for 40Ca target nuclei reactions (p,α), (p,n), (p,p) have been calculated using the semi-empirical formula Tel et al. [5].

  2. Reevaluation of secondary neutron spectra from thick targets upon heavy-ion bombardment

    NASA Astrophysics Data System (ADS)

    Satoh, D.; Kurosawa, T.; Sato, T.; Endo, A.; Takada, M.; Iwase, H.; Nakamura, T.; Niita, K.

    2007-12-01

    Previously published data of secondary neutron spectra from thick targets of C, Al, Cu and Pb bombarded with heavy ions from He to Xe are revised by using a new set of neutron-detection efficiency values for a liquid organic scintillator calculated with SCINFUL-QMD. Additional data have been measured for bombardment of C target by 400-MeV/nucleon C ions and 800-MeV/nucleon Si ions. The set of spectra are compared with the calculation results using a Monte-Carlo heavy-ion transport code, PHITS. It was found that PHITS is able to reproduce the secondary neutron spectra in a wide neutron-energy regime.

  3. Considerations about projectile and target X-rays induced during heavy ion bombardment

    NASA Astrophysics Data System (ADS)

    Fernandes, F.; Bauer, D. V.; Duarte, A.; Ferrari, T. M.; Niekraszewicz, L. A. B.; Amaral, L.; Dias, J. F.

    2018-02-01

    In this work we present some results concerning the X-rays emitted by heavy ions during target bombardment. In this case, Cl4+ and Cl5+ ions with energies from 4 MeV to 10 MeV were employed to irradiate vitreous carbon planchets. Moreover, total X-ray production cross sections of titanium X-rays induced by chlorine ions were obtained as well for the same energy range. Only inner shell transitions were considered in the present work. The titanium target consisted of a thin film deposited over vitreous carbon planchets. The results indicate that the projectile X-ray yields increase as a function of the bombarding energy for the present energy range. Effects due to projectile charge state appears to be of minor importance at these low ion velocities. It is shown that a simple exponential function can represent the continuum background of such complex spectra. The chlorine transition rates Kβ/Kα obtained from chlorine acting as a projectile interacting with a carbon target are about half the value when compared to the chlorine Kβ/Kα ratios obtained when a LiCl target is bombarded with C+ and C3+ ions with energies from 2 MeV to 6 MeV. As far as the total X-ray production cross sections of Ti induced by chlorine ions are concerned, the ECPSSR theory underestimates the Ti total X-rays production cross sections by several orders of magnitude. The role of electron capture and possible mechanisms responsible for these effects are discussed.

  4. Intense Non-Linear Soft X-Ray Emission from a Hydride Target during Pulsed D Bombardment

    NASA Astrophysics Data System (ADS)

    Miley, George H.; Yang, Yang; Lipson, Andrei; Haque, Munima; Percel, Ian; Romer, Michael

    Radiation emission from low-energy nuclear radiation (LENR) electrodes (both charged-particle and X-rays) represents an important feature of LENR in general. Here, calibration, measurement techniques, and soft X-ray emission results from deuterium bombardment of a Pd target (cathode) placed in a pulsed deuterium glow discharge (PGD) are described. An X-ray intensity of 13.4 mW/cm2 and a dose of 3.3 μJ/cm2 were calculated over a 0.5 ms pulse time from AXUV photodiode radiation detector measurements. A most striking feature is that X-ray energies >600 V are observed with a discharge voltage only about half of that value. To further investigate this phenomenon, emission during room temperature D-desorption from electrolytically loaded Pd:Dx cathodes was also studied. The X-ray emission energy observed was quite similar to the PGD case. However, the intensity in this case was almost 13 orders of magnitude lower due to the much lower deuterium fluxes involved.

  5. Scale-up of high specific activity 186gRe production using graphite-encased thick 186W targets and demonstration of an efficient target recycling process

    DOE PAGES

    Balkin, Ethan R.; Gagnon, Katherine; Dorman, Eric; ...

    2017-08-18

    Production of high specific activity 186gRe is of interest for development of theranostic radiopharmaceuticals. Previous studies have shown that high specific activity 186gRe can be obtained by cyclotron irradiation of enriched 186W via the 186W(d,2n) 186gRe reaction, but most irradiations were conducted at low beam currents and for short durations. In this paper, enriched 186W metal targets were irradiated at high incident deuteron beam currents to demonstrate production rates and contaminants produced when using thick targets. Full-stopping thick targets, as determined using SRIM, were prepared by uniaxial pressing of powdered natural abundance W metal or 96.86% enriched 186W metal encasedmore » between two layers of graphite flakes for target material stabilization. An assessment of structural integrity was made on each target preparation. To assess the performance of graphite-encased thick 186W metal targets, along with the impact of encasing on the separation chemistry, targets were first irradiated using a 22 MeV deuteron beam for 10 min at 10, 20, and 27 μA, with an estimated nominal deuteron energy of 18.7 MeV on the 186W target material (after energy degradation correction from top graphite layer). Gamma-ray spectrometry was performed post EOB on all targets to assess production yields and radionuclidic byproducts. The investigation also evaluated a method to recover and recycle enriched target material from a column isolation procedure. Material composition analyses of target materials, pass-through/wash solutions and recycling process isolates were conducted with SEM, FTIR, XRD, EDS and ICP-MS spectrometry. Finally, to demonstrate scaled-up production, a graphite-encased 186W target made from recycled 186W was irradiated for ~2 h with 18.7 MeV deuterons at a beam current of 27 μA to provide 0.90 GBq (24.3 mCi) of 186gRe, decay-corrected to the end of bombardment. ICP-MS analysis of the isolated 186gRe solution provided data that indicated the

  6. Scale-up of high specific activity 186gRe production using graphite-encased thick 186W targets and demonstration of an efficient target recycling process

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Balkin, Ethan R.; Gagnon, Katherine; Dorman, Eric

    Production of high specific activity 186gRe is of interest for development of theranostic radiopharmaceuticals. Previous studies have shown that high specific activity 186gRe can be obtained by cyclotron irradiation of enriched 186W via the 186W(d,2n) 186gRe reaction, but most irradiations were conducted at low beam currents and for short durations. In this paper, enriched 186W metal targets were irradiated at high incident deuteron beam currents to demonstrate production rates and contaminants produced when using thick targets. Full-stopping thick targets, as determined using SRIM, were prepared by uniaxial pressing of powdered natural abundance W metal or 96.86% enriched 186W metal encasedmore » between two layers of graphite flakes for target material stabilization. An assessment of structural integrity was made on each target preparation. To assess the performance of graphite-encased thick 186W metal targets, along with the impact of encasing on the separation chemistry, targets were first irradiated using a 22 MeV deuteron beam for 10 min at 10, 20, and 27 μA, with an estimated nominal deuteron energy of 18.7 MeV on the 186W target material (after energy degradation correction from top graphite layer). Gamma-ray spectrometry was performed post EOB on all targets to assess production yields and radionuclidic byproducts. The investigation also evaluated a method to recover and recycle enriched target material from a column isolation procedure. Material composition analyses of target materials, pass-through/wash solutions and recycling process isolates were conducted with SEM, FTIR, XRD, EDS and ICP-MS spectrometry. Finally, to demonstrate scaled-up production, a graphite-encased 186W target made from recycled 186W was irradiated for ~2 h with 18.7 MeV deuterons at a beam current of 27 μA to provide 0.90 GBq (24.3 mCi) of 186gRe, decay-corrected to the end of bombardment. ICP-MS analysis of the isolated 186gRe solution provided data that indicated the

  7. Projectile n distributions following charge transfer of Ar+ and Na+ in a Na Rydberg target

    NASA Astrophysics Data System (ADS)

    MacAdam, K. B.; Gray, L. G.; Rolfes, R. G.

    1990-11-01

    The n distributions produced by charge transfer of Ar+ and Na+ ions in a target of Na(nl) Rydberg atoms were extensively measured at intermediate velocities. The 60-2100-eV ions bombarded a laser-excited atomic-beam target. The projectiles were neutralized by capture into Rydberg states of Ar and Na and were analyzed by field ionization in an inhomogeneous-field detector whose response over states and energies was carefully mapped. The choice of initially prepared Na states, 24d, 25s, 28d, 29s, 33d, and 34s, allowed a comparison of l=0 and >=2 targets at nearly equal binding energies over a range of reduced velocity v~=0.187 to 1.95. Capture populates m sublevels broadly, not merely m~=0. Overlapping contributions from adiabatic and diabatic modes of field ionization were accommodated in the analysis, which used a maximum-entropy-principle parametric form to fit the observed final-state distributions. The peak of the distributions, nmax, shifts upward from a value less than the initial state ni to a value one to three units higher than ni at v~ between 0.7 and 0.9 and ultimately shifts downward below ni as v~ is further increased. The distributions become significantly sharper where the maximum upward shift occurs. Two ratios were defined to express the widths of final-state distributions in relative terms, one measuring the spread of orbital kinetic energy and the other the spread of Bohr-orbit velocity. By these ratios a universal behavior over energies, states, and projectile species is observed, and small differences between l=0 and >=2 targets may be seen. A theoretical understanding of the present results, which span velocities where both molecular and perturbative theories are normally used, will require a quantal formulation that models the free-ranging response that is a hallmark of the high-quantum-number limit.

  8. Nanoscale modulations in (KLa)(CaW)O-6 and (NaLa)(CaW)O-6

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Licurse, Mark; Borisevich, Albina Y; Davies, Peter

    2012-01-01

    Complex nanoscale modulations are identified in two new A-site ordered perovskites, (KLa)(CaW)O{sub 6} and (NaLa)(CaW)O{sub 6}. In (KLa)(CaW)O{sub 6}, selected-area electron diffraction (SAED) and high-resolution transmission electron microscopy (HRTEM) show an incommensurate nanocheckerboard modulation with {approx}9.4 x 9.4 a{sub p} periodicity (a{sub p} {approx} 4 {angstrom} for the cubic perovskite aristotype). For (NaLa)(CaW)O{sub 6} a one-dimensional modulation is observed with a {approx}16(1 1 0)a{sub p} repeat; the <1 1 0> orientation of the nanostripes is different from the <1 0 0> stripes observed in other mixed A-site systems. Studies using high temperature x-ray diffraction suggest the formation of the complexmore » modulations is associated with small deviations from the ideal 1:1:1:1 stoichiometry of the (A{sup +}La{sup 3+})(CaW)O{sub 6} phases. Z-contrast images acquired on an aberration-corrected microscope provide evidence for deviations from stoichiometry with a {approx}1:15 periodic arrangement of La{sub 4/3}(CaW)O{sub 6}:(NaLa)(CaW)O{sub 6} nano-phases.« less

  9. Development of a Ne gas target for {sup 22}Na production by proton irradiation

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Mandal, Bidhan Ch., E-mail: mechbidhan@gmail.com; Pal, Gautam; Barua, Luna

    2016-03-15

    The article presents the design and development of a neon gas target for the production of {sup 22}Na using a proton beam from the room temperature cyclotron in Variable Energy Cyclotron Centre, Kolkata. The target design is made to handle a beam power of 85 W (17 MeV, 5 μA). The design is based on simulation using the computer code FLUKA for the beam dump and CFD-CFX for target cooling. The target has been successfully used for the production of {sup 22}Na in a 6 day long 17 MeV, 5 μA proton irradiation run.

  10. Measurement of the neutron angular distribution from a beryllium target bombarded with a 345-MeV/u 238U beam at the RIKEN RI beam factory

    NASA Astrophysics Data System (ADS)

    Nakao, Noriaki; Uwamino, Yoshitomo; Tanaka, Kanenobu

    2018-05-01

    The angular distribution of neutrons produced from a 4-mm-thick beryllium target bombarded with a 345-MeV/u 238U beam was measured outside the target chamber using bismuth and aluminum activation detectors at angles of 4.5°, 10°, 30°, 60°, 70° and 90° from the beam axis. Following two hours of irradiation and photo-peak analyses, the production rates of the radionuclides were obtained for the 209Bi(n,xn)210-xBi(x = 4-12) and 27Al(n,α)24Na reactions. Using the Particle and Heavy Ion Transport code System (PHITS), a Monte Carlo simulation of the production rates was performed and the ratios of the calculated to the experimental results (C/E) ranged from 0.6 to 1.0 generally and 0.4 to 1.3 in worst cases.

  11. Nanoscale modulations in (KLa)(CaW)O{sub 6} and (NaLa)(CaW)O{sub 6}

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Licurse, Mark W., E-mail: mlicurse@seas.upenn.edu; Borisevich, Albina Y., E-mail: albinab@ornl.gov; Davies, Peter K., E-mail: davies@seas.upenn.edu

    2012-07-15

    Complex nanoscale modulations are identified in two new A-site ordered perovskites, (KLa)(CaW)O{sub 6} and (NaLa)(CaW)O{sub 6}. In (KLa)(CaW)O{sub 6}, selected-area electron diffraction (SAED) and high-resolution transmission electron microscopy (HRTEM) show an incommensurate nanocheckerboard modulation with {approx}9.4 Multiplication-Sign 9.4a{sub p} periodicity (a{sub p} Almost-Equal-To 4 A for the cubic perovskite aristotype). For (NaLa)(CaW)O{sub 6} a one-dimensional modulation is observed with a {approx}16(1 1 0)a{sub p} repeat; the Left-Pointing-Angle-Bracket 1 1 0 Right-Pointing-Angle-Bracket orientation of the nanostripes is different from the Left-Pointing-Angle-Bracket 1 0 0 Right-Pointing-Angle-Bracket stripes observed in other mixed A-site systems. Studies using high temperature x-ray diffraction suggest the formationmore » of the complex modulations is associated with small deviations from the ideal 1:1:1:1 stoichiometry of the (A{sup +}La{sup 3+})(CaW)O{sub 6} phases. Z-contrast images acquired on an aberration-corrected microscope provide evidence for deviations from stoichiometry with a {approx}1:15 periodic arrangement of La{sub 4/3}(CaW)O{sub 6}:(NaLa)(CaW)O{sub 6} nano-phases. - Graphical abstract: Complex nanoscale modulations are identified in two new A-site ordered perovskites, (KLa)(CaW)O{sub 6} and (NaLa)(CaW)O{sub 6}. In (KLa)(CaW)O{sub 6}, selected-area electron diffraction and high-resolution transmission electron microscopy show a two-dimensional, nanocheckerboard modulation. For (NaLa)(CaW)O{sub 6} a one-dimensional modulation is observed; the Left-Pointing-Angle-Bracket 1 1 0 Right-Pointing-Angle-Bracket orientation of the nanostripes is different from the Left-Pointing-Angle-Bracket 1 0 0 Right-Pointing-Angle-Bracket stripes observed in other mixed A-site systems. Highlights: Black-Right-Pointing-Pointer Two new A-site ordered perovskites were synthesized, (KLa)(CaW)O{sub 6} and (NaLa)(CaW)O{sub 6}. Black

  12. High energy γ-ray production from Be, C, and Al targets with 65 MeV 3He bombardment

    NASA Astrophysics Data System (ADS)

    Hosaka, M.; Ishii, K.; Ohura, M.; Terakawa, A.; Miyamoto, S.; Guan, Z.; Orihara, H.; Kasagi, J.

    1996-11-01

    High-energy γ rays from targets of Be, C, and Al bombarded with 65 MeV 3He ions have been measured by the use of a γ-ray detector system consisting of seven BaF2 scintillators. The energy spectra were obtained up to the maximum energy kinematically permitted in each collision at detection angles of 35°-144°. The experimental cross sections are compared with calculations of the potential bremsstrahlung on which the theory has been developed by Nakayama and Bertsch. It is shown that the prediction of potential bremsstrahlung can well reproduce the production cross sections of γ rays of energy near the kinematical maximum energy in collisions, while this result is contrary to the previous one of Tam et al. in α and d bombardments.

  13. Badania Ekologiczne Ryzyka Zachorowań Na Kleszczowe Zapalenie Mózgu W Polsce-Omówienie Metody

    PubMed Central

    Stefanoff, Paweł; Staszewska, Ewa; Ustrnul, Zbigniew; Rogalska, Justyna; Łankiewicz, Aleksandra; Rosińska, Magdalena

    2009-01-01

    W pracy omówiono metodologię aktualnie prowadzonych badań ekologicznych kleszczowego zapalenia mózgu (kzm) na terenie Polski. W celu oceny wpływu zróżnicowanych czynników środowiskowych, klimatycznych oraz społecznych na występowanie kzm w różnych regionach Polski zostanie przeprowadzona wieloczynnikoica analiza statystyczna na poziomie gmin dla lat 1999-2006. PMID:22320045

  14. Particle bombardment - mediated gene transfer and GFP transient expression in Seteria viridis.

    PubMed

    Mookkan, Muruganantham

    2018-04-03

    Setaria viridis is one of the most important model grasses in studying monocot plant biology. Transient gene expression study is a very important tool in plant biotechnology, functional genomics, and CRISPR-Cas9 genome editing technology via particle bombardment. In this study, a particle bombardment-mediated protocol was developed to introduce DNA into Setaria viridis in vitro leaf explants. In addition, physical and biological parameters, such as helium pressure, distance from stopping screen to the target tissues, DNA concentration, and number of bombardments, were tested and optimized. Optimum concentration of transient GFP expression was achieved using 1.5 ug plasmid DNA with 0.6 mm gold particles and 6 cm bombardment distance, using 1,100 psi. Doubling the bombardment instances provides the maximum number of foci of transient GFP expression. This simple protocol will be helpful for genomics studies in the S. viridis monocot model.

  15. Cereal transformation through particle bombardment

    NASA Technical Reports Server (NTRS)

    Casas, A. M.; Kononowicz, A. K.; Bressan, R. A.; Hasegawa, P. M.; Mitchell, C. A. (Principal Investigator)

    1995-01-01

    The review focuses on experiments that lead to stable transformation in cereals using microprojectile bombardment. The discussion of biological factors that affect transformation examines target tissues and vector systems for gene transfer. The vector systems include reporter genes, selectable markers, genes of agronomic interest, and vector constructions. Other topics include physical parameters that affect DNA delivery, selection of stably transformed cells and plant regeneration, and analysis of gene expression and transmission to the progeny.

  16. The production and sputtering of S2 by keV ion bombardment

    NASA Technical Reports Server (NTRS)

    Boring, J. W.; Chrisey, D. B.; Oshaughnessy, D. J.; Phipps, J. A.; Zhao, N.

    1986-01-01

    The ion bombardment of S-containing molecules in comets is simulated experimentally. Mass-analyzed 30-keV beams of Ar(+) and He(+) are directed at solid S, H2S, and CS2 targets at temperatures 15 K, and the neutral molecular species produced are ionized and analyzed using a quadrupole mass spectrometer. The dominant species detected are S1 and S2 for the S target, H2S and S2 for the H2S target, and S, CS, S2, and CS2 for the CS2 target. In the latter case, it is found that after about 10 to the 14th He(+) ions/sq cm have struck the target, further sputtering is prevented by formation of a dark brown deposit which is stable at room temperature; the residue forms more slowly when Ar(+) ions are used. These results, indicating relatively efficient S2 production by ion bombardment, are applied to theoretical models of S2 production and/or ejection by solar-wind, solar-flare, or cosmic-ray ions striking comets. It is found that direct solar-wind production of S2 by sputtering is unlikely at realistic bombardment rates, but that H2S-S2 conversion by energetic ions could be significant, with less stringent ice-temperature and irradiation-flux constraints than in the case of S2 production by photons.

  17. MD simulations of low energy deuterium irradiation on W, WC and W2C surfaces

    NASA Astrophysics Data System (ADS)

    Lasa, A.; Björkas, C.; Vörtler, K.; Nordlund, K.

    2012-10-01

    According to the present design beryllium (Be), tungsten (W) and carbon (C) will be the plasma facing materials in the ITER fusion reactor. Due to sputtering and subsequent re-deposition, mixing of these materials will occur. In this context, molecular dynamics simulations of cumulative, low energy and high flux D bombardment of pure W and tungsten carbides (WC, W2C) were carried out. The retention and sputtering properties as well as the structural deformation were analysed and comparisons to SDTrimSP simulations were made. Almost no tungsten is sputtered in the energy range considered and the D backscattering is lower in pure tungsten than in any of the tungsten carbides. In WC and W2C, the deuterium is mainly trapped forming small molecules, whereas mostly atomic D is present in pure W. The C sputtering increases with C content in the material, and shows a peak at the bombardment energy ˜50 eV, most likely due to the swift chemical sputtering mechanism. Pure W is seen to lose its crystallinity in the areas where D is present. After the D irradiation, the composition of both WC and W2C is mostly W in the topmost layers, due to preferential sputtering of C, an amorphous D-C mixture underneath and an undisturbed lattice in the rest of the cell.

  18. Reduced transition probabilities along the yrast line in 166W

    NASA Astrophysics Data System (ADS)

    Sayǧı, B.; Joss, D. T.; Page, R. D.; Grahn, T.; Simpson, J.; O'Donnell, D.; Alharshan, G.; Auranen, K.; Bäck, T.; Boening, S.; Braunroth, T.; Carroll, R. J.; Cederwall, B.; Cullen, D. M.; Dewald, A.; Doncel, M.; Donosa, L.; Drummond, M. C.; Ertuǧral, F.; Ertürk, S.; Fransen, C.; Greenlees, P. T.; Hackstein, M.; Hauschild, K.; Herzan, A.; Jakobsson, U.; Jones, P. M.; Julin, R.; Juutinen, S.; Konki, J.; Kröll, T.; Labiche, M.; Lopez-Martens, A.; McPeake, C. G.; Moradi, F.; Möller, O.; Mustafa, M.; Nieminen, P.; Pakarinen, J.; Partanen, J.; Peura, P.; Procter, M.; Rahkila, P.; Rother, W.; Ruotsalainen, P.; Sandzelius, M.; Sarén, J.; Scholey, C.; Sorri, J.; Stolze, S.; Taylor, M. J.; Thornthwaite, A.; Uusitalo, J.

    2017-08-01

    Lifetimes of excited states in the yrast band of the neutron-deficient nuclide 166W have been measured utilizing the DPUNS plunger device at the target position of the JUROGAM II γ -ray spectrometer in conjunction with the RITU gas-filled separator and the GREAT focal-plane spectrometer. Excited states in 166W were populated in the 92Mo(78Kr,4 p ) reaction at a bombarding energy of 380 MeV. The measurements reveal a low value for the ratio of reduced transitions probabilities for the lowest-lying transitions B (E 2 ;4+→2+) /B (E 2 ;2+→0+) =0.33 (5 ) , compared with the expected ratio for an axially deformed rotor (B4 /2 = 1.43).

  19. L-changing depopulation of Na s and p Rydberg states by ion impact

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Rolfes, R.G.; Smith, D.B.; MacAdam, K.B.

    1988-04-01

    Ar/sup +/ and Na/sup +/ ion beams bombarding Na ns and np Rydberg-state targets at impact velocities near the Bohr-orbital velocity of the target atoms (i.e., v-italic-tildeapprox. =1) induce transitions to (n-1)l states (lgreater than or equal to2) with larger-than-geometric cross sections. Depopulation of ns states proceeds directly into the full n-1, lgreater than or equal to2 manifold rather than populating the np or (n-1)p states as the first of a sequence of dipole-allowed steps. Depopulation of np states leads to a distribution of final states that is dominated by the nearer or high-l part of the n-1 manifold. nmore » dependences of the cross section for ns depopulation are given at several energies for n = 32--41 and at a single energy for np, n = 26--32. The absolute cross section for Na(36s) depopulation falls gradually but steadily for reduced velocities v-italic-tilde increasing from 0.3 to 1.35. Bombardment of Na 39s and 39p states in applied fields 0--18.5 V/cm reveals that the final-state distributions become narrower as manifold states are Stark shifted close to the initial states. No theoretical results are available for direct comparison with these experiments, but the method of coupled channels seems to be the most suitable candidate.« less

  20. Influence of Polycarboxylate Superplasticizers on Rheological Properties of Cement Slurries Used in Drilling Technologies / Wpływ Superplastyfikatorów Z Grupy Polikarboksylanów Na Właściwości Reologiczne Zaczynów Cementowych Stosowanych W Technologiach Wiertniczych

    NASA Astrophysics Data System (ADS)

    Stryczek, Stanisław; Wiśniowski, Rafał; Gonet, Andrzej; Złotkowski, Albert; Ziaja, Jan

    2013-09-01

    Sealing slurries, mainly the cement-based ones, are concentrated dispersive systems, containing solid particles of considerably developed specific surface. Rheologically, such systems are very complex. This also stems from the fact that the rheological properties have a significant effect on: • additives and admixtures modifying technological properties of fresh and set slurries, • chemically complex mechanism of hydration in a slurry in a function of time. Special attention should paid to plasticizing (plasticizers PL) and liquefying (traditional and new- -generation superplasticizers SP) admixtures affecting the modification and optimization of rheological properties of fresh cement slurries as far as providing efficiency of sealing of casing pipes is concerned. Laboratory analyses were focused on proving the following thesis: properly selected type of superplasticizer [by BASF Polska Sp.z o.o. (The Chemical Company) - Admixtures for Concrete Division] advantageously affects the rheological parameters of sealing slurry based on metallurgical cement CEM III /A 32,5. The following variables were used in the analyses: • type of superplasticizer, • type of batch fluid. The laboratory experiments were made on superplasticizers produced by BASF: • SKY 501, • SKY 503, • SKY 591, • ACE 430, • Glenium 115. The superplasticizer concentration in the slurry was 0.5 wt% (as compared with mass of dry cement). Water to cement ratio for the analyzed sealing slurries was equal to 0.5. The sealing slurries were made of metallurgical cement CEM III/A 32,5 N-LH/HSR/N Lafarge Cement S.A. in Małogoszcz. Zaczyny uszczelniające, a zwłaszcza typu cementowego, są skoncentrowanymi układami dyspersyjnymi, zawierającymi cząstki stałe o znacznie rozwiniętej powierzchni właściwej. Układy takie pod względem reologicznym należą do niezwykle złożonych. Wynika to między innymi z faktu, że na właściwości reologiczne w sposób istotny wpływają: • dodatki i

  1. Fast Atom Bombardment Mass Spectrometry.

    ERIC Educational Resources Information Center

    Rinehart, Kenneth L., Jr.

    1982-01-01

    Discusses reactions and characteristics of fast atom bombardment (FAB) mass spectroscopy in which samples are ionized in a condensed state by bombardment with xenon or argon atoms, yielding positive/negative secondary ions. Includes applications of FAB to structural problems and considers future developments using the technique. (Author/JN)

  2. The tungsten isotopic composition of the Earth's mantle before the terminal bombardment.

    PubMed

    Willbold, Matthias; Elliott, Tim; Moorbath, Stephen

    2011-09-07

    Many precious, 'iron-loving' metals, such as gold, are surprisingly abundant in the accessible parts of the Earth, given the efficiency with which core formation should have removed them to the planet's deep interior. One explanation of their over-abundance is a 'late veneer'--a flux of meteorites added to the Earth after core formation as a 'terminal' bombardment that culminated in the cratering of the Moon. Some 3.8 billion-year-old rocks from Isua, Greenland, are derived from sources that retain an isotopic memory of events pre-dating this cataclysmic meteorite shower. These Isua samples thus provide a window on the composition of the Earth before such a late veneer and allow a direct test of its importance in modifying the composition of the planet. Using high-precision (less than 6 parts per million, 2 standard deviations) tungsten isotope analyses of these rocks, here we show that they have a isotopic tungsten ratio (182)W/(184)W that is significantly higher (about 13 parts per million) than modern terrestrial samples. This finding is in good agreement with the expected influence of a late veneer. We also show that alternative interpretations, such as partial remixing of a deep-mantle reservoir formed in the Hadean eon (more than four billion years ago) or core-mantle interaction, do not explain the W isotope data well. The decrease in mantle (182)W/(184)W occurs during the Archean eon (about four to three billion years ago), potentially on the same timescale as a notable decrease in (142)Nd/(144)Nd (refs 3 and 6). We speculate that both observations can be explained if late meteorite bombardment triggered the onset of the current style of mantle convection.

  3. Analysis of a Neutronic Experiment on a Simulated Mercury Spallation Neutron Target Assembly Bombarded by Giga-Electron-Volt Protons

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Maekawa, Fujio; Meigo, Shin-ichiro; Kasugai, Yoshimi

    2005-05-15

    A neutronic benchmark experiment on a simulated spallation neutron target assembly was conducted by using the Alternating Gradient Synchrotron at Brookhaven National Laboratory and was analyzed to investigate the prediction capability of Monte Carlo simulation codes used in neutronic designs of spallation neutron sources. The target assembly consisting of a mercury target, a light water moderator, and a lead reflector was bombarded by 1.94-, 12-, and 24-GeV protons, and the fast neutron flux distributions around the target and the spectra of thermal neutrons leaking from the moderator were measured in the experiment. In this study, the Monte Carlo particle transportmore » simulation codes NMTC/JAM, MCNPX, and MCNP-4A with associated cross-section data in JENDL and LA-150 were verified based on benchmark analysis of the experiment. As a result, all the calculations predicted the measured quantities adequately; calculated integral fluxes of fast and thermal neutrons agreed approximately within {+-}40% with the experiments although the overall energy range encompassed more than 12 orders of magnitude. Accordingly, it was concluded that these simulation codes and cross-section data were adequate for neutronics designs of spallation neutron sources.« less

  4. A model for sputtering from solid surfaces bombarded by energetic clusters

    NASA Astrophysics Data System (ADS)

    Benguerba, Messaoud

    2018-04-01

    A model is developed to explain and predict the sputtering from solid surfaces bombarded by energetic clusters, on the basis of shock wave generated at the impact of cluster. Under the shock compression the temperature increases causing the vaporization of material that requires an internal energy behind the shock, at least, of about twice the cohesive energy of target. The sputtering is treated as a gas of vaporized particles from a hemispherical volume behind the shock front. The sputter yield per cluster atoms is given as a universal function depending on the ratio of target to cluster atomic density and the ratio of cluster velocity to the velocity calculated on the basis of an internal energy equals about twice cohesive energy. The predictions of the model for self sputter yield of copper, gold, tungsten and of silver bombarded by C60 clusters agree well, with the corresponding data simulated by molecular dynamics.

  5. Flexibility in Management of Modernization in Construction - Electrical Works/ Elastyczność W Zarządzaniu Modernizacją Obiektów Budowlanych Na Przykładzie Robót Elektrycznych

    NASA Astrophysics Data System (ADS)

    Nowotarski, Piotr; Pasławski, Jerzy

    2015-06-01

    The article presents the general principles of flexible approach, illustrated with case study regarding flexibility in modernization. Flexibility is understood in the present case as a skilful adaptation to changes in the dynamically changing environment. The essence of flexibility approach is being staged to make decisions based on environmental and process monitoring in progress. Presented case study of upgrading the electrical system in the multi-family housing in the common area is based on step by step procedure responding to damage state of this system. Simple analysis is based on cost comparison but there are other criteria (environmental, social etc.) and conflict solving situations taken into account in presented paper. Artykuł prezentuje możliwość zastosowania elastyczności w modernizacjach istniejących obiektów budowlanych na przykładzie instalacji oświetleniowej. Elastyczność jest rozumiana w tym przypadku jako umiejętne dostosowanie się do zmian w dynamicznie zmieniającym się środowisku. Istotą podejścia elastycznego jest podejmowanie odpowiednich decyzji w odpowiednim czasie opartych na monitoringu środowiska i procesu w toku. Prezentowane studium przypadku modernizacji instalacji elektrycznej w budownictwie wielorodzinnym w częściach wspólnych obiektu (korytarze, klatki schodowe, hala garażowa) opiera się na wymianie i modernizacji tylko tych punktów, które w danym momencie ulegają awarii. Prosta analiza oby typów modernizacji opiera się na porównaniu kosztów, natomiast trzeba zaznaczyć, że możliwe są także inne kryteria (środowiskowe, konfliktu społecznego, itp.), które będą przedmiotem kolejnych publikacji. Zastąpienie tradycyjnych żarówek rozwiązaniami opartymi na technologii LED z zastosowaniem czujników ruchu może prowadzić do znacznych oszczędności, ale może też oznaczać obniżenie komfortu dla użytkowników (np. dla osób starszych, którym jeden cykl działania oświetlenia nie jest

  6. MD and BCA simulations of He and H bombardment of fuzz in bcc elements

    NASA Astrophysics Data System (ADS)

    Klaver, T. P. C.; Zhang, S.; Nordlund, K.

    2017-08-01

    We present results of MD simulations of low energy He ion bombardment of low density fuzz in bcc elements. He ions can penetrate several micrometers into sparse fuzz, which allows for a sufficient He flux through it to grow the fuzz further. He kinetic energy falls off exponentially with penetration depth. A BCA code was used to carry out the same ion bombardment on the same fuzz structures as in MD simulations, but with simpler, 10 million times faster calculations. Despite the poor theoretical basis of the BCA at low ion energies, and the use of somewhat different potentials in MD and BCA calculations, the ion penetration depths predicted by BCA are only ∼12% less than those predicted by MD. The MD-BCA differences are highly systematic and trends in the results of the two methods are very similar. We have carried out more than 200 BCA calculation runs of ion bombardment of fuzz, in which parameters in the ion bombardment process were varied. For most parameters, the results show that the ion bombardment process is quite generic. The ion species (He or H), ion mass, fuzz element (W, Ta, Mo, Fe) and fuzz element lattice parameter turned out to have a modest influence on ion penetration depths at most. An off-normal angle of incidence strongly reduces the ion penetration depth. Increasing the ion energy increases the ion penetration, but the rate by which ion energy drops off at high ion energies follows the same exponential pattern as at lower energies.

  7. Zastosowanie oznaczeń nikotyny we włosach jako narzędzia do oceny narażenia na dym tytoniowy

    PubMed Central

    Koszowski, Bartosz; Czogała, Jan; Goniewicz, Maciej Łukasz; Sobczak, Andrzej; Kolasińska, Ewelina; Kośmider, Leon; Kuma, Tomasz

    2009-01-01

    Pierwsza praca dotycząca oznaczania nikotyny we włosach została opublikowana w 1983 roku przez Ishiyama i wsp. Od czasu tych pionierskich badań minęło już ponad 25 lat, a badanie zawartości nikotyny we włosach stało się cennym narzędziem służącym ocenie narażenia na liczne ksenobiotyki, w tym na dym tytoniowy. Niniejszy artykuł jest próbą zwięzłego przeglądu najważniejszych badań ostatnich lat, które wykorzystywały nikotynę we włosach jako biomarker. W artykule opisano także stosowane do oznaczeń nikotyny we włosach techniki laboratoryjne oraz przedstawiono wady i zalety włosów jako biomarkera narażenia na dym tytoniowy. PMID:19189581

  8. New insights from old spherules: Os-W isotope and HSE evidence for Paleoarchean meteorite bombardment of the Earth

    NASA Astrophysics Data System (ADS)

    Schulz, T.; Luguet, A. A.; Koeberl, C.

    2014-12-01

    Introduction: Although still debated, spherule beds in the Barberton Mountain Land (~3.4 Ga) are suspected to represent remnants of impact-generated and ballistically emplaced silicate melt droplets [e.g. 1]. Such deposits provide the only window into the late stages of the heavy meteorite bombardment on Earth as their source craters have long since been obliterated. In order to identify a possible meteoritic component and, if successful, to discuss potential projectile materials, we are performing a detailed Os-W isotope as well as HSE abundance study on spherule layers from the recently drilled ICDP BARB5 core (grid location 25°30`50.76``S, 31°33`10.08``E). Samples and Methods: Samples were taken from a spherule-containing meta-sedimentary core section discovered between 510 and 512 m depth. About 100 mg of homogenized sample powders were spiked with a mixed 190Os, 185Re, 191Ir and 194Pt tracer and treated in a high pressure asher using inverse aqua regia, followed by conventional extraction schemes for Os and the other HSEs [4]. Chemical and Os isotope measurements (via N-TIMS) were performed in Vienna, whereas HSE measurements were undertaken via ICP MS in Bonn. Results and Discussion: Our preliminary Os isotope data reveal a trend between samples exhibiting high spherule to matrix ratios (187Os/188Os ~0.106 and Os ~0.4 ppm) and samples with lower ones (187Os/188Os up to ~0.304 and Os ~0.008 ppm). Notably, the most unradiogenic samples exhibit carbonaceous-chondrite-like initial 187Os/188Os and HSE ratios, whereas all other samples are clear non-chondritic. These findings support an extraterrestrial contribution in the spherules and can be interpreted compared to conclusions drawn from a Cr isotope study performed on similar samples [3], possibly representing a different impact event and favouring a chondritic projectile. However, further considerations based on precise Os/W ratio determinations and high-precision 182W isotope data, will be presented at the

  9. Wpływ wybranych czynników środowiskowych na maksymalny przepływ nosowy wdechowy - część projektu ECAP (Epidemiologia Chorób Alergicznych w Polsce).

    PubMed

    Krzych-Fałta, Edyta; Furmańczyk, Konrad; Piekarska, Barbara; Sybilski, Adam; Samoliński, Bolesław

    2017-02-28

    Celem niniejszej pracy była próba określenia wpływu wybranych czynników/parametrów na wynik maksymalnego przepływu nosowego wdechowego (PNIF, ang. peak nasal inspiratory flow) w badanej populacji polskiej projektu Epidemiologia Chorób Alergicznych w Polsce (ECAP). Materiał/metody: Badaną populację stanowiła grupa dzieci w wieku 6-7 lat (n=1123), młodzieży w wieku 13-14 lat (n=1136) oraz dorosłych (n=1876) zamieszkałych w siedmiu dużych polskich miastach. W badaniu posłużono się pomiarem maksymalnego przepływu nosowego wdechowego (PNIF). Do oceny wpływu wybranych czynników na wartości PNIF wykorzystano przetłumaczone i walidowane kwestionariusze opracowane na potrzeby światowych badań ECRHS II (European Community Respiratory Health Survey II) i ISAAC (International Study of Asthma and Allergies in Childhood). Wyniki: Określone warunki wewnątrz gospodarstwa domowego, m.in. ogrzewanie węglem, drewnem lub piecem gazowym, istotnie zwiększają przekrwienie błony śluzowej nosa. W grupie biernych palaczy PNIF był niższy niż w grupie czynnych palaczy. Wskaźnik PNIF malał wraz ze wzrostem liczby domowników palących papierosy. Wnioski: Wybrane czynniki środowiska.

  10. Transmission sputtering under diatomic molecule bombardment. Model calculations

    NASA Astrophysics Data System (ADS)

    Bitensky, I. S.

    1996-04-01

    Transmission sputtering means that emission of secondary particles is studied from the downstream side of a bombarded foil. Nonlinear effects in sputtering manifest themselves as a deviation of sputtering yield under molecular ion bombardment from the sum of the yields induced by the constituents at the same velocity. In the reflection geometry the overlap of the spike regions reaches maximum, while in transmission the degree of overlap depends on the projectile and on the foil thickness. It has been shown that the transmission sputtering yield can be described by a function of a scaling parameter determined by beam-foil characteristics and a mechanism of nonlinear sputtering. Calculations of the transmission yield have been made in the thermal spike and shock wave models. The results of calculations are compared with experimental data on phenylalanine molecular ion desorption from organic targets induced by Au + and Au 2+ impact. Suggestions for further experimental study are made.

  11. The tourism resources and possibilities using of its for development of the town and commune of Nałęczów and the commune of Wojciechów

    NASA Astrophysics Data System (ADS)

    Świeca, Andrzej; Brzezińska-Wójcik, Teresa

    2009-01-01

    Structural part of the resources of the tourism potential of the town and commune of Nałęczów and the commune of Wojciechów was studied in this paper. In the study, the attractiveness of tourism resources of the communes was assessed based on 48 features grouped into four divisions: sightseeing assets, recreational and special assets, tourist infrastructure and environmental protection. A field survey (listing, query) and a quantitative evaluation of tourist resources, carried out by means of a multidimensional comparative analysis, indicated an appreciable difference in features between the commune of Nałęczów and commune of Wojciechów. The tourist attractiveness index determined for the commune of Nałęczów was 0.695, almost twice as high as the index for the commune of Wojciechów (0.349). In the light of carrying out of investigations, the tourist attractiveness of the commune of Nałęczów results primarily from its environmental (mineral springs, unique flora) and cultural assets (historic monuments) as well as recreational assets (bioclimate, forest complexes, ravines; more than half of the commune's territory is within the Kazimierz Landscape Park) and special assets (angling). The tourism potential of the commune of Wojciechów is primarily determined by its recreational assets (diverse land relief) and special assets (hunting). The commune of Nałęczów is superior with regard to tourist infrastructure and environmental protection. Owing to the diversity of tourist assets, different degrees of tourist infrastructure development and varying quality of the natural environment, various forms of tourism exist in the two communes, i.e. educational tourism (environmental, geotourism, ecotourism, cultural and festival tourism), recreational tourism (agritourism), adventure tourism (walking, cycling, skiing and cross-country skiing) as well as health tourism (health, spa and wellness tourism).

  12. 100-W 105-μm 0.15NA fiber coupled laser diode module

    NASA Astrophysics Data System (ADS)

    Karlsen, Scott R.; Price, R. Kirk; Reynolds, Mitch; Brown, Aaron; Mehl, Ron; Patterson, Steve; Martinsen, Robert J.

    2009-02-01

    We report on the development of a high brightness laser diode module capable of coupling over 100W of optical power into a 105 μm 0.15 NA fiber at 976 nm. This module, based on nLIGHT's Pearl product architecture, utilizes hard soldered single emitters packaged into a compact and passively-cooled package. In this system each diode is individually collimated in the fast and slow axes and free-space coupled into a single fiber. The high brightness module has an optical excitation under 0.13 NA, is virtually free of cladding modes, and has an electrical to optical efficiency greater than 40%. Additionally, this module is compatible with high power 7:1 fused fiber combiners, and initial experiments demonstrated 500W coupled into a 220 μm, 0.22 NA fiber. These modules address the need in the market for higher brightness diode lasers for pumping fiber lasers and direct material processing.

  13. Targets for the production of radioisotopes and method of assembly

    DOEpatents

    Quinby, Thomas C.

    1976-01-01

    A target for preparation of radioisotopes by nuclear bombardment, and a method for its assembly are provided. A metallic sample to be bombarded is enclosed within a metallic support structure and the resulting target subjected to heat and pressure to effect diffusion bonds therebetween. The bonded target is capable of withstanding prolonged exposure to nuclear bombardment without thermal damage to the sample.

  14. Synthesis, structure and optical properties of two isotypic crystals, Na{sub 3}MO{sub 4}Cl (M=W, Mo)

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Han, Shujuan; Bai, Chunyan; Zhang, Bingbing

    Two isotypic compounds, Na{sub 3}MO{sub 4}Cl (M = W, Mo) have been obtained from the high temperature solution, and their structures were determined by single-crystal X-ray diffraction. Both of them crystallize in the space group P4/nmm of tetragonal system with the unit cells: a=7.5181(15), c=5.360(2) for Na{sub 3}WO{sub 4}Cl and a=7.4942(12), c=5.3409(18) for Na{sub 3}MoO{sub 4}Cl. The structure exhibits a 3D network built up by the ClNa{sub 6} groups, and the MO{sub 4} groups reside in the tunnels of the 3D network. The structural similarities and differences between Na{sub 3}MO{sub 4}Cl (M=W, Mo) and Sr{sub 3}MO{sub 4}F (M=Al, Ga) havemore » been discussed. Meanwhile, detailed structure comparison analyses between Na{sub 3}MO{sub 4}Cl (M=W, Mo) and Na{sub 3}MO{sub 4}F (M=W, Mo) indicate that the different connection modes of ClNa{sub 6} and FNa{sub 6} make Na{sub 3}MO{sub 4}Cl and Na{sub 3}MO{sub 4}F crystallize in different structures. The IR spectra were used to verify the validity of the structure. The diffuse reflectance spectra show that the UV absorption edges are about 249 nm (4.99 eV) and 265 nm (4.69 eV) for Na{sub 3}WO{sub 4}Cl and Na{sub 3}MoO{sub 4}Cl, respectively. In addition, the first-principles theoretical studies are also carried out to aid the understanding of electronic structures and linear optical properties. - Graphical abstract: Two isotypic compounds, Na{sub 3}MO{sub 4}Cl (M=W, Mo) have been obtained from the high temperature solution. Both of them crystallize in the space group P4/nmm of tetragonal system. The structure exhibits a 3D network built up by the ClNa{sub 6} groups, and the MO{sub 4} groups reside in the tunnels of the 3D network. - Highlights: • Structure and properties of Na{sub 3}MO{sub 4}Cl (M=W, Mo) are reported for the first time. • They show a 3D network built by ClNa{sub 6}, and WO{sub 4} lies in the tunnels of the network. • IR spectra were used to verify the validity of the structure. • Band structures

  15. Assessment of Impact of the Rheological Parameters Change on Sensitivity of the Asphalt Strain Based on the Test Results / Ocena Wpływu Zmiany Parametrów Reologicznych Na Wrażliwość Deformacji Mieszanek Mineralno - Asfaltowych Na Podstawie Wyników Badań

    NASA Astrophysics Data System (ADS)

    Kurpiel, Artur; Wysokowski, Adam

    2015-03-01

    The creep test under the static loading, that allows to determine rheological properties of asphalt based on the creep curve, is the most effective test nowadays. Applied loads are non-destructive and allow to observe the course of the strain after the test load. The test can be carried out on compressing, shearing, bending as well as on triaxial test, that depends on the applied apparatus implementing different intensity [1, 2, 3, 4, 5, 6]. Based on the creep test, the stress of different properties can be specified. Among them there are valuable rheological properties based on selected viscoelascity models [1]. The properties of the viscoelascity models are relevant indexes depicting resistance to deformation. They can be used to forecast the wheel-truck in the accepted rheological model [1]. In this article it is shown the impact of different rheological properties of the viscoelacity model on the wheel-truck as well as the impact of different properties on shape and the course of the creep curve. The asphalt mixtures presented in this article are characterized by variable rheological properties. It is therefore difficult to determine which property mostly affects the size of the strain. However, the authors of this article attempted to analyse the change of the asphalt strain value of the different variables in particular rheological model, called Bürgers's model. Badanie pełzania pod obciążeniem statycznym jest obecnie najbardziej efektywnym badaniem pozwalającym na określenie reologicznych parametrów mieszanek mineralno - asfaltowych na podstawie krzywej pełzania. Stosowane obciążenia mają poziom nieniszczący i pozwalają na obserwację przebiegu odkształceń w czasie również po odciążeniu. Badanie może być realizowane przy ściskaniu, ścinaniu, rozciąganiu i zginaniu, a także w zakresie trójosiowym, w zależności od stosowanego aparatu realizującego zadany schemat naprężeń [1, 2, 3, 4, 5, 6]. Na podstawie badania pełzania można

  16. Targets for producing high purity I-123

    NASA Technical Reports Server (NTRS)

    Blue, J. W. (Inventor)

    1978-01-01

    Tellurium powder in improved targets is bombarded with a cyclotron beam to produce Xe-123. Flowing gas streams carry the Xe-123 through one cold trap which removes Xe-123 that subsequently decays to I-123. During this bombardment energy is deposited in the target material causing its temperature to rise. Some of the tellurium vaporizes and subsequently condenses on surfaces that are cooler than the vaporization temperature. Provision is made for the repeated bombardment of this condensed tellurium.

  17. NaK-nitrogen liquid metal MHD converter tests at 30 kW.

    NASA Technical Reports Server (NTRS)

    Cerini, D. J.

    1973-01-01

    Description of the tests performed and test results obtained in an experiment where a NaK-nitrogen liquid metal MHD converter was operated over a range of nozzle inlet pressures of 100 to 165 N per sq cm, NaK flow rates of 46 to 72 kg/sec, and nitrogen flow rates of 3.4 to 3.8 kg/sec. The test results indicate: (1) smooth and stable operation, (2) absence of unexpected electrical or flow losses, and (3) possibility of operation with the expected full power output of 30 kW.

  18. Inhibitory effects of α-Na8SiW11CoO40 on tyrosinase and its application in controlling browning of fresh-cut apples.

    PubMed

    Chen, Bing-Nian; Xing, Rui; Wang, Fang; Zheng, A-Ping; Wang, Li

    2015-12-01

    α-Na8SiW11CoO40 was synthesized and characterized. The inhibitory effects of α-Na8SiW11CoO40 on the activity of mushroom tyrosinase and the effects of α-Na8SiW11CoO40 on the browning of fresh-cut apples were studied. The Native-PAGE result showed that α-Na8SiW11CoO40 had a significant inhibitory effect on tyrosinase. Kinetic analyses showed that α-Na8SiW11CoO40 was an irreversible and competitive inhibitor. The inhibitor concentration leading to a 50% reduction in activity (IC50) was estimated to be 0.239 mM. Additionally, the results also showed that α-Na8SiW11CoO40 treatment could significantly decrease the browning process of apple slices and inhibit the polyphenol oxidase (PPO) activity. Moreover, application of α-Na8SiW11CoO40 resulted in higher peroxidase activity and promoted high amounts of phenolic compounds and ascorbic acid. This study may provide a promising method for the use of polyoxometalates to inhibit tyrosinase activity and control the browning of fresh-cut apples. Copyright © 2015 Elsevier Ltd. All rights reserved.

  19. EPR study of electron bombarded alkali- and alkaline-earth halide crystal surfaces

    NASA Technical Reports Server (NTRS)

    Fryburg, G. C.; Lad, R. A.

    1975-01-01

    An EPR study of electron bombarded LiF, NaCl, KCl, CaF2 and BaF2 polycrystalline surfaces has shown that small metal particles are formed on the surfaces of the crystals. Identification was made from CESR signals. The symmetric line-shape of the signals, even at 77 K, indicated that the particles were less than 0.5 micron in diameter. Signals due to F centers were observed in LiF but not in the other halides. Implications to metal deposition are considered.

  20. Investigation of the thermonuclear 18Ne(α,p)21Na reaction rate via resonant elastic scattering of 21Na + p

    NASA Astrophysics Data System (ADS)

    Zhang, L. Y.; He, J. J.; Parikh, A.; Xu, S. W.; Yamaguchi, H.; Kahl, D.; Kubono, S.; Mohr, P.; Hu, J.; Ma, P.; Chen, S. Z.; Wakabayashi, Y.; Wang, H. W.; Tian, W. D.; Chen, R. F.; Guo, B.; Hashimoto, T.; Togano, Y.; Hayakawa, S.; Teranishi, T.; Iwasa, N.; Yamada, T.; Komatsubara, T.; Zhang, Y. H.; Zhou, X. H.

    2014-01-01

    The 18Ne(α,p)21Na reaction is thought to be one of the key breakout reactions from the hot CNO cycles to the rp process in type I x-ray bursts. In this work, the resonant properties of the compound nucleus 22Mg have been investigated by measuring the resonant elastic scattering of 21Na + p. An 89-MeV 21Na radioactive beam delivered from the CNS Radioactive Ion Beam Separator bombarded an 8.8 mg/cm2 thick polyethylene (CH2)n target. The 21Na beam intensity was about 2×105 pps, with a purity of about 70% on target. The recoiled protons were measured at the center-of-mass scattering angles of θc.m.≈175.2∘, 152.2∘, and 150.5∘ by three sets of ΔE-E telescopes, respectively. The excitation function was obtained with the thick-target method over energies Ex(22Mg)=5.5-9.2 MeV. In total, 23 states above the proton-threshold in 22Mg were observed, and their resonant parameters were determined via an R-matrix analysis of the excitation functions. We have made several new Jπ assignments and confirmed some tentative assignments made in previous work. The thermonuclear 18Ne(α,p)21Na rate has been recalculated based on our recommended spin-parity assignments. The astrophysical impact of our new rate has been investigated through one-zone postprocessing x-ray burst calculations. We find that the 18Ne(α,p)21Na rate significantly affects the peak nuclear energy generation rate, reaction fluxes, and onset temperature of this breakout reaction in these astrophysical phenomena.

  1. Deposition of PTFE thin films by ion beam sputtering and a study of the ion bombardment effect

    NASA Astrophysics Data System (ADS)

    He, J. L.; Li, W. Z.; Wang, L. D.; Wang, J.; Li, H. D.

    1998-02-01

    Ion beam sputtering technique was employed to prepare thin films of Polytetrafluroethylene (PTFE). Simultaneous ion beam bombardment during film growth was also conducted in order to study the bombardment effects. Infrared absorption (IR), X-ray photoelectron spectroscopy (XPS) and X-ray diffraction (XRD) analysis was used to evaluate the material's integrity. It was found that PTFE thin films could be grown at room temperature by direct sputtering of a PTFE target. The film's composition and structure were shown to be dependent on the sputtering energy. Films deposited by single sputtering at higher energy (˜1500 eV) were structurally quite similar to the original PTFE material. Simultaneous ion beam bombarding during film growth caused defluorination and structural changes. Mechanism for sputtering deposition of such a polymeric material is also discussed.

  2. Assaying effector function in planta using double-barreled particle bombardment.

    PubMed

    Kale, Shiv D; Tyler, Brett M

    2011-01-01

    The biolistic transient gene expression assay is a beneficial tool for studying gene function in vivo. However, biolistic transient assay systems have inherent pitfalls that often cause experimental inaccuracies such as poor transformation efficiency, which can be confused with biological phenomena. The double-barreled gene gun device is an inexpensive and highly effective attachment that enables statistically significant data to be obtained with one-tenth the number of experimental replicates compared to conventional biolistic assays. The principle behind the attachment is to perform two simultaneous bombardments with control and test DNA preparations onto the same leaf. The control bombardment measures the efficiency of the transformation while the ratio of the test bombardment to the control bombardment measures the activity of the gene of interest. With care, the ratio between the pair of bombardments can be highly reproducible from bombardment to bombardment. The double-barreled attachment has been used to study plant resistance (R) gene-mediated responses to effectors, induction and suppression of cell death by a wide variety of pathogen and host molecules, and the role of oömycete effector RXLR motifs in cell reentry.

  3. MEASUREMENTS OF NEUTRON SPECTRA IN 0.8-GEV AND 1.6-GEV PROTON-IRRADIATED<2 OF 2>NA THICK TARGETS

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Titarenko, Y. E.; Batyaev, V. F.; Zhivun, V. M.

    2001-01-01

    Measurements of neutron spectra in W, and Na targets irradiated by 0.8 GeV and 1.6 GeV protons are presented. Measurements were made by the TOF techniques using the proton beam from ITEP U-10 synchrotron. Neutrons were detected with BICRON-511 liquid scintillator-based detectors. The neutron detection efficiency was calculated via the SCINFUL and CECIL codes. The W results are compared with the similar data obtained elsewhere. The measured neutron spectra are compared with the LAHET and CEM2k code simulations results. Attempt is made to explain some observed disagreements between experiments and simulations. The presented results are of interest both in termsmore » of nuclear data buildup and as a benchmark of the up-to-date predictive power of the simulation codes used in designing the hybrid accelerator-driven system (ADS) facilities with sodium-cooled tungsten targets.« less

  4. Czynniki ryzyka, czynniki chroniące i indeksy tych czynników w badaniach nad zachowaniami problemowymi nastolatków:

    PubMed Central

    Okulicz-Kozaryn, Katarzyna; Bobrowski, Krzysztof

    2009-01-01

    Streszczenie Opis i wyjaśnianie zachowań problemowych młodzieży jest w dużej mierze oparte na analizie czynników zwiększających ryzyko wystąpienia zaburzeń i czynników chroniących. Badania nad tymi czynnikami dostarczają wiele cennych danych, jednak ze względu na dużą liczbę i różnorodność analizowanych w badaniach zmiennych, często trudno jest uogólniać ich wyniki. Jednym ze sposobów radzenia sobie z tym problemem jest konstruowanie złożonych indeksów zmiennych, które określają ekspozycję jednostki na sumę czynników ryzyka i czynników chroniących. W niniejszym opracowaniu omówiono osiem badań, w których wyjaśniano zachowania problemowe młodzieży (głównie: używanie substancji psychoaktywnych) na podstawie analizy tworzonych indeksów czynników ryzyka i chroniących. Wyniki przeglądu pokazują, że na uzyskane w badaniach wyniki znaczący wpływ mają arbitralne decyzje autorów, dotyczące definiowania czynników ryzyka/chroniących, wyjściowej puli analizowanych zmiennych, sposobu ustalania istotnego natężenia danego czynnika. Najbardziej jednoznaczne są wyniki mówiące tym, że każdy z indeksów (ryzyka i ochrony), niezależnie od innych czynników, pozwala wyjaśnić aktualnie występujące zachowania problemowe nastolatków, co jest ważnym argumentem za wzmacnianiem czynników chroniących w działaniach profilaktycznych. Natomiast najpoważniejszym minusem badań, wykorzystujących indeksy, jest „uśrednianie” znaczenia poszczególnych czynników, przypisywanie im a priori identycznej wagi w wyjaśnianiu zachowań, co stoi w sprzeczności z wynikami badań, pokazujących duże zróżnicowanie znaczenia poszczególnych czynników. PMID:19390638

  5. Characterizing the Early Impact Bombardment

    NASA Technical Reports Server (NTRS)

    Bogard, Donald D.

    2005-01-01

    The early bombardment revealed in the larger impact craters and basins on the moon was a major planetary process that affected all bodies in the inner solar system, including the Earth and Mars. Understanding the nature and timing of this bombardment is a fundamental planetary problem. The surface density of lunar impact craters within a given size range on a given lunar surface is a measure of the age of that surface relative to other lunar surfaces. When crater densities are combined with absolute radiometric ages determined on lunar rocks returned to Earth, the flux of large lunar impactors through time can be estimated. These studies suggest that the flux of impactors producing craters greater than 1 km in diameter has been approximately constant over the past approx. 3 Gyr. However, prior to 3.0 - 3.5 Gyr the impactor flux was much larger and defines an early bombardment period. Unfortunately, no lunar surface feature older than approx. 4 Gyr is accurately dated, and the surface density of craters are saturated in most of the lunar highlands. This means that such data cannot define the impactor flux between lunar formation and approx. 4 Gyr ago.

  6. Secondary neutrons as the main source of neutron-rich fission products in the bombardment of a thick U target by 1 GeV protons

    NASA Astrophysics Data System (ADS)

    Barzakh, A. E.; Lhersonneau, G.; Batist, L. Kh.; Fedorov, D. V.; Ivanov, V. S.; Mezilev, K. A.; Molkanov, P. L.; Moroz, F. V.; Orlov, S. Yu.; Panteleev, V. N.; Volkov, Yu. M.; Alyakrinskiy, O.; Barbui, M.; Stroe, L.; Tecchio, L. B.

    2011-05-01

    The diffusion-effusion model has been used to analyse the release and yields of Fr and Cs isotopes from uranium carbide targets of very different thicknesses (6.3 and 148 g/cm2) bombarded by a 1 GeV proton beam. Release curves of several isotopes of the same element and production efficiency versus decay half-life are well fitted with the same set of parameters. Comparison of efficiencies for neutron-rich and neutron-deficient Cs isotopes enables separation of the contributions from the primary ( p + 238U) and secondary (n + 238U) reactions to the production of neutron-rich Cs isotopes. A rather simple calculation of the neutron contribution describes these data fairly well. The FLUKA code describes the primary and secondary-reaction contributions to the Cs isotopes production efficiencies for different targets quite well.

  7. A Shared Bombardment History

    NASA Image and Video Library

    2013-03-25

    Studying meteorites from the asteroid Vesta helps scientists understand the event known as the lunar cataclysm, when a repositioning of the gas giant planets destabilized a portion of the asteroid belt and triggered a solar-system-wide bombardment.

  8. Characteristics of W-26% Re Target Material(LCC-0103)

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Sunwoo, A.

    2003-10-07

    The W-26 wt-% Re alloy was selected as a Stanford Linear Collider (SLC) target material for its exceptional physics properties and for the high strength and good ductility at the anticipated target operating temperatures, above the DBTT. After several years of operation, the target failed catastrophically. A detailed microstructural and mechanical characterization of the non-irradiated disk indicates that the material has been PM processed, nonuniformly mechanically worked and stress relieved. As a result, the ductility of the material varies through the thickness of the disk, making it difficult to determine the DBTT. The results of tensile and fatigue properties aremore » reported with the corresponding fractography of the fracture surfaces.« less

  9. Carbon atom and cluster sputtering under low-energy noble gas plasma bombardment

    NASA Astrophysics Data System (ADS)

    Oyarzabal, E.; Doerner, R. P.; Shimada, M.; Tynan, G. R.

    2008-08-01

    Exit-angle resolved carbon atom and cluster (C2 and C3) sputtering yields are measured during different noble gas (Xe, Kr, Ar, Ne, and He) ion bombardments from a plasma, for low incident energies (75-225 eV). A quadrupole mass spectrometer (QMS) is used to detect the fraction of sputtered neutrals that is ionized in the plasma and to obtain the angular distribution by changing the angle between the target normal and the QMS aperture. A one-dimensional Monte Carlo code is used to simulate the interaction of the plasma and the sputtered particles in the region between the sample and the QMS. The effective elastic scattering cross sections of C, C2, and C3 with the different bombarding gas neutrals are obtained by varying the distance between the sample and the QMS and by performing a best fit of the simulation results to the experimental results. The total sputtering yield (C+C2+C3) for each bombarding gas is obtained from weight-loss measurements and the sputtering yield for C, C2, and C3 is then calculated from the integration of the measured angular distribution, taking into account the scattering and ionization of the sputtered particles between the sample and the QMS. We observe undercosine angular distributions of the sputtered atoms and clusters for all the studied bombarding gases and a clear decrease of the atom to cluster (C2 and C3) sputtering ratio as the incident ion mass increases, changing from a carbon atom preferential erosion for the lower incident ion masses (He, Ne, and Ar) to a cluster preferential erosion for the higher incident ion masses (Kr and Xe).

  10. Deuteron irradiation of W and WO 3 for production of high specific activity 186Re: Challenges associated with thick target preparation

    DOE PAGES

    Balkin, Ethan R.; Gagnon, Katherine; Strong, Kevin T.; ...

    2016-06-28

    This investigation evaluated target fabrication and beam parameters for scale-up production of high specific activity 186Re using deuteron irradiation of enriched 186W via the 186W(d,2n) 186Re reaction. Thick W and WO 3 targets were prepared, characterized and evaluated in deuteron irradiations. Full-thickness targets, as determined using SRIM, were prepared by uniaxi-ally pressing powdered natural abundance W and WO 3, or 96.86% enriched 186W, into Al target supports. Alternatively, thick targets were prepared by pressing 186W between two layers of graphite powder or by placing pre-sintered (1105°C, 12 hours) natural abundance WO 3 pellets into an Al target support. Assessments ofmore » structural integrity were made on each target pre-pared. Prior to irradiation, material composition analyses were conducted using SEM, XRD, and Raman spectroscopy. With-in a minimum of 24 hours post irradiation, gamma-ray spectroscopy was performed on all targets to assess production yields and radionuclidic byproducts. Problems were encountered with the structural integrity of some pressed W and WO 3 pellets before and during irradiation, and target material characterization results could be correlated with the structural integrity of the pressed target pellets. Under the conditions studied, the findings suggest that all WO 3 targets prepared and studied were unacceptable. By contrast, 186W metal was found to be a viable target material for 186Re production. Lastly, thick targets prepared with powdered 186W pressed between layers of graphite provided a particularly robust target configuration.« less

  11. Deuteron irradiation of W and WO3 for production of high specific activity (186)Re: Challenges associated with thick target preparation.

    PubMed

    Balkin, Ethan R; Gagnon, Katherine; Strong, Kevin T; Smith, Bennett E; Dorman, Eric F; Emery, Robert C; Pauzauskie, Peter J; Fassbender, Michael E; Cutler, Cathy S; Ketring, Alan R; Jurisson, Silvia S; Wilbur, D Scott

    2016-09-01

    This investigation evaluated target fabrication and beam parameters for scale-up production of high specific activity (186)Re using deuteron irradiation of enriched (186)W via the (186)W(d,2n)(186)Re reaction. Thick W and WO3 targets were prepared, characterized and evaluated in deuteron irradiations. Full-thickness targets, as determined using SRIM, were prepared by uniaxially pressing powdered natural abundance W and WO3, or 96.86% enriched (186)W, into Al target supports. Alternatively, thick targets were prepared by pressing (186)W between two layers of graphite powder or by placing pre-sintered (1105°C, 12h) natural abundance WO3 pellets into an Al target support. Assessments of structural integrity were made on each target prepared. Prior to irradiation, material composition analyses were conducted using SEM, XRD, and Raman spectroscopy. Within a minimum of 24h post irradiation, gamma-ray spectroscopy was performed on all targets to assess production yields and radionuclidic byproducts. Problems were encountered with the structural integrity of some pressed W and WO3 pellets before and during irradiation, and target material characterization results could be correlated with the structural integrity of the pressed target pellets. Under the conditions studied, the findings suggest that all WO3 targets prepared and studied were unacceptable. By contrast, (186)W metal was found to be a viable target material for (186)Re production. Thick targets prepared with powdered (186)W pressed between layers of graphite provided a particularly robust target configuration. Copyright © 2016 Elsevier Ltd. All rights reserved.

  12. Radionuclide production and dose rate estimation during the commissioning of the W-Ta spallation target

    NASA Astrophysics Data System (ADS)

    Yu, Q. Z.; Liang, T. J.

    2018-06-01

    China Spallation Neutron Source (CSNS) is intended to begin operation in 2018. CSNS is an accelerator-base multidisciplinary user facility. The pulsed neutrons are produced by a 1.6GeV short-pulsed proton beam impinging on a W-Ta spallation target, at a beam power of100 kW and a repetition rate of 25 Hz. 20 neutron beam lines are extracted for the neutron scattering and neutron irradiation research. During the commissioning and maintenance scenarios, the gamma rays induced from the W-Ta target can cause the dose threat to the personal and the environment. In this paper, the gamma dose rate distributions for the W-Ta spallation are calculated, based on the engineering model of the target-moderator-reflector system. The shipping cask is analyzed to satisfy the dose rate limit that less than 2 mSv/h at the surface of the shipping cask. All calculations are performed by the Monte carlo code MCNPX2.5 and the activation code CINDER’90.

  13. Spectroscopic study of the radionuclide 21Na for the astrophysical 17F(α ,p )20Ne reaction rate

    NASA Astrophysics Data System (ADS)

    Cha, S. M.; Chae, K. Y.; Ahn, S.; Bardayan, D. W.; Chipps, K. A.; Cizewski, J. A.; Howard, M. E.; Kozub, R. L.; Kwak, K.; Manning, B.; Matos, M.; O'Malley, P. D.; Pain, S. D.; Peters, W. A.; Pittman, S. T.; Ratkiewicz, A.; Smith, M. S.; Strauss, S.

    2017-08-01

    The 24Mg(p ,α )21Na reaction was measured at the Holifield Radioactive Ion Beam Facility of the Oak Ridge National Laboratory to study the spectroscopy of the radionuclide 21Na. A 31-MeV proton beam from the 25 MV tandem accelerator bombarded isotopically enriched 24Mg targets. Recoiling 4He particles were identified by an annular silicon strip detector array. Two energy levels at Ex=6.594 and 7.132 MeV were observed for the first time. By comparing the experimentally obtained angular distributions and distorted wave Born approximation calculations, the spins and parities of 21Na energy levels were constrained. The astrophysically-important 17F(α ,p )20Ne reaction rate was also calculated for the first time using resonance parameters for 12 energy levels.

  14. Destruction and Re-Accretion of Mid-Size Moons During an Outer Solar System Late Heavy Bombardment

    NASA Astrophysics Data System (ADS)

    Movshovitz, N.; Nimmo, F.; Korycansky, D. G.; Asphaug, E. I.; Owen, M.

    2014-12-01

    To explain the lunar Late Heavy Bombardment the Nice Model (Tsiganis, K., Gomes, R., Morbidelli, A., & Levison, H. 2005, Nature, 435, 459; Tsiganis, K., Gomes, R., Morbidelli, A., & Levison, H. 2005, Nature, 435, 459) invokes a period of dynamical instability, occurring long after planet formation, that destabilizes both the main asteroid belt and a remnant exterior planetesimal disk. As a side effect of explaining the lunar LHB, this model also predicts an LHB-like period in the outer Solar System. With higher collision probabilities and impact energies due to gravitational focusing by the giant planets the inner satellites of Jupiter, Saturn, and Uranus would have experienced a bombardment much more severe than the one supposedly responsible for the lunar basins. The concern is that such bombardment should have resulted in significant, even catastrophic modification of the mid-size satellites. Here we look at the problem of satellite survival during a hypothetical outer Solar System LHB. Using a Monte-Carlo approach we calculate, for 10 satellites of Saturn and Uranus, the probability of having experienced at least one catastrophic collision during an LHB. We use a scaling law for the energy required to disrupt a target in a gravity-dominated collision derived from new SPH simulations. These simulations extend the scaling law previously obtained by Benz & Asphaug (1999, Icarus, 142, 5) to larger targets. We then simulate randomized LHB impacts by drawing from appropriate size and velocity distributions, with the total delivered mass as a controlled parameter. We find that Mimas, Enceladus, Tethys, Hyperion, and Miranda experience at least one catastrophic impact in every simulation. In most simulations, Mimas, Enceladus, and Tethys experience multiple catastrophic impacts, including impacts with energies several times that required to completely disrupt the target. The implication is that these close-in, mid-size satellites could not have survived a Late Heavy

  15. Geopolymers in Construction / Zastosowanie Geopolimerów W Budownictwie

    NASA Astrophysics Data System (ADS)

    Błaszczyński, Tomasz Z.; Król, Maciej R.

    2015-03-01

    Within the framework of quests of supplementary and "healthier" binders to the production of concrete followed the development of geopolymers in construction. However the practical application of these materials is still very limited. The production of each ton of cement introduces one ton of CO2 into the atmosphere. According to various estimations, the synthesis of geopolymers absorbs 2-3 times less energy than the Portland cement and causes a generation of 4-8 times less of CO2. Geopolymeric concretes possess a high compressive strength, very small shrinkage and small creep, and they possess a high resistance to acid and sulphate corrosion. These concretes are also resistant to carbonate corrosion and possess a very high fire resistance and also a high resistance to UV radiation. W ramach poszukiwania zastępczych i "zdrowszych" spoiw do produkcji betonu nastąpił rozwój geopolimerów w budownictwie. Jednakże praktyczne zastosowanie tych materiałów jest jeszcze nadal bardzo ograniczone. Produkcja każdej tony cementu wprowadza do atmosfery tonę CO2. Według różnych szacunków, synteza geopolimerów pochłania 2-3 razy mniej energii, niż cementu portlandzkiego oraz powoduje wydzielenie 4-8 razy mniejszej ilości CO2. Do tego betony geopolimerowe posiadają wysoką wytrzymałość na ściskanie, bardzo mały skurcz i małe pełzanie oraz dają wysoką odporność na korozję kwasową i siarczanową. Betony te są także odporne na korozję węglanową i posiadają bardzo wysoką odporność ogniową, a także wysoką odporność na promieniowanie UV.

  16. Structure, stability, and photoluminescence in the anti-perovskites Na{sub 3}W{sub 1−x}Mo{sub x}O{sub 4}F (0≤x≤1)

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Sullivan, Eirin, E-mail: esulliv@ilstu.edu; Avdeev, Maxim; Blom, Douglas A.

    2015-10-15

    Single-phase ordered oxyfluorides Na{sub 3}WO{sub 4}F, Na{sub 3}MoO{sub 4}F and their mixed members Na{sub 3}W{sub 1−x}Mo{sub x}O{sub 4}F can be prepared via facile solid state reaction of Na{sub 2}MO{sub 4}·2H{sub 2}O (M=W, Mo) and NaF. Phases produced from incongruent melts are metastable, but lower temperatures allow for a facile one-step synthesis. In polycrystalline samples of Na{sub 3}W{sub 1−x}Mo{sub x}O{sub 4}F, the presence of Mo stabilizes the structure against decomposition to spinel phases. Photoluminescence studies show that upon excitation with λ=254 nm and λ=365 nm, Na{sub 3}WO{sub 4}F and Na{sub 3}MoO{sub 4}F exhibit broad emission maxima centered around 485 nm. Thesemore » materials constitute new members of the family of self-activating ordered oxyfluoride phosphors with anti-perovskite structures which are amenable to doping with emitters such as Eu{sup 3+}. - Graphical abstract: Directed synthesis of the ordered oxyfluorides Na{sub 3}W{sub 1−x}Mo{sub x}O{sub 4}F (0≤x≤1) has shown that a complete solid solution is attainable and provides the first example of photoluminescence in these materials. - Highlights: • Na{sub 3}W{sub 1−x}Mo{sub x}O{sub 4}F is a complete solid solution with hexagonal anti-perovskite structure. • The presence of even small amounts of Mo stabilizes the structure against decomposition. • Na{sub 3}W{sub 1−x}Mo{sub x}O{sub 4}F has broad emissions centered ≈485 nm (λ{sub ex}=254 nm and λ{sub ex}=365 nm). • These materials constitute a new family of self-activated oxyfluoride phosphors. • Na{sub 3}W{sub 1−x}Mo{sub x}O{sub 4}F materials are amenable to doping with emitters such as Eu{sup 3+}.« less

  17. Cardiotonic steroids-mediated Na+/K+-ATPase targeting could circumvent various chemoresistance pathways.

    PubMed

    Mijatovic, Tatjana; Kiss, Robert

    2013-03-01

    Many cancer patients fail to respond to chemotherapy because of the intrinsic resistance of their cancer to pro-apoptotic stimuli or the acquisition of the multidrug resistant phenotype during chronic treatment. Previous data from our groups and from others point to the sodium/potassium pump (the Na+/K+-ATPase, i.e., NaK) with its highly specific ligands (i.e., cardiotonic steroids) as a new target for combating cancers associated with dismal prognoses, including gliomas, melanomas, non-small cell lung cancers, renal cell carcinomas, and colon cancers. Cardiotonic steroid-mediated Na+/K+-ATPase targeting could circumvent various resistance pathways. The most probable pathways include the involvement of Na+/K+-ATPase β subunits in invasion features and Na+/K+-ATPase α subunits in chemosensitisation by specific cardiotonic steroid-mediated apoptosis and anoïkis-sensitisation; the regulation of the expression of multidrug resistant-related genes; post-translational regulation, including glycosylation and ubiquitinylation of multidrug resistant-related proteins; c-Myc downregulation; hypoxia-inducible factor downregulation; NF-κB downregulation and deactivation; the inhibition of the glycolytic pathway with a reduction of intra-cellular ATP levels and an induction of non-apoptotic cell death. The aims of this review are to examine the various molecular pathways by which the NaK targeting can be more deleterious to biologically aggressive cancer cells than to normal cells. Georg Thieme Verlag KG Stuttgart · New York.

  18. Bombarding Cancer: Biolistic Delivery of therapeutics using Porous Si Carriers

    PubMed Central

    Zilony, Neta; Tzur-Balter, Adi; Segal, Ester; Shefi, Orit

    2013-01-01

    A new paradigm for an effective delivery of therapeutics into cancer cells is presented. Degradable porous silicon carriers, which are tailored to carry and release a model anti-cancer drug, are biolistically bombarded into in-vitro cancerous targets. We demonstrate the ability to launch these highly porous microparticles by a pneumatic capillary gene gun, which is conventionally used to deliver cargos by heavy metal carriers. By optimizing the gun parameters e.g., the accelerating gas pressure, we have successfully delivered the porous carriers, to reach deep targets and to cross a skin barrier in a highly spatial resolution. Our study reveals significant cytotoxicity towards the target human breast carcinoma cells following the delivery of drug-loaded carriers, while administrating empty particles results in no effect on cell viability. The unique combination of biolistics with the temporal control of payload release from porous carriers presents a powerful and non-conventional platform for designing new therapeutic strategies. PMID:23975675

  19. Measurement of Thick Target Neutron Yields at 0-Degree Bombarded With 140-MeV, 250-MeV And 350-MeV Protons

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Iwamoto, Yosuke; /JAERI, Kyoto; Taniguchi, Shingo

    Neutron energy spectra at 0{sup o} produced from stopping-length graphite, aluminum, iron and lead targets bombarded with 140, 250 and 350 MeV protons were measured at the neutron TOF course in RCNP of Osaka University. The neutron energy spectra were obtained by using the time-of-flight technique in the energy range from 10 MeV to incident proton energy. To compare the experimental results, Monte Carlo calculations with the PHITS and MCNPX codes were performed using the JENDL-HE and the LA150 evaluated nuclear data files, the ISOBAR model implemented in PHITS, and the LAHET code in MCNPX. It was found that thesemore » calculated results at 0{sup o} generally agreed with the experimental results in the energy range above 20 MeV except for graphite at 250 and 350 MeV.« less

  20. Application of methods for area calculation of geodesic polygons on Polish administrative units / Zastosowanie metod obliczania pól powierzchni wieloboków geodezyjnych na przykładzie jednostek administracyjnych w Polsce

    NASA Astrophysics Data System (ADS)

    Pędzich, Paweł; Kuźma, Marta

    2012-11-01

    The paper presents methods of area calculation, which may be applied for big geodesic polygons on the ellipsoid. Proposal developed by the authors of this paper is discussed. The proposed methods are compared with other, alternative methods of area calculation of such polygons. Test calculations are performed for administrative units in Poland. The obtained results are also compared with areas of those units registered in statistical annals. Utilisation of the equal-area map projections of the ellipsoid onto a plane seems to be the best solution for the discussed task. In the case of small distances between points we may expect accurate results of calculations, since the area size is influenced by the projection reductions only, which are small in such cases. In some cases their influence on results of calculations may be neglected. Then, only re-calculation of co-ordinates from the GRS80 ellipsoid to the cartographic, equal-area projection is required. Umiejętność obliczania pól wieloboków geodezyjnych, czyli takich, których bokami są odcinki linii geodezyjnych, ma istotne znaczenie w praktyce geodezyjnej i kartograficznej. Jednym z podstawowych zadań wykonywanych przez geodetów i kartografów jest obliczanie pól różnych obiektów powierzchniowych takich jak gmina, województwo, obszary użytków gruntowych itp. Jeżeli zadanie sprowadza się tylko do powierzchni kuli lub płaszczyzny to rozwiązanie jest stosunkowo łatwe. Zadanie komplikuje się, jeżeli za powierzchnię odniesienia fizycznej powierzchni Ziemi przyjmiemy elipsoidę obrotową, ponieważ nie ma ścisłych wzorów, które pozwalałyby na realizację takiego zadania; są jedynie wzory przybliżone mające zastosowanie dla niewielkich obszarów. Trudności pojawiają się szczególnie w przypadku dużych wieloboków zlokalizowanych na elipsoidzie obrotowej spłaszczonej. W artykule przedstawiono metody obliczania pól powierzchni, które mogą być stosowane dla dużych wieloboków

  1. Critical Surface Parameters for the Oxidative Coupling of Methane over the Mn-Na-W/SiO2 Catalyst.

    PubMed

    Hayek, Naseem S; Lucas, Nishita S; Warwar Damouny, Christine; Gazit, Oz M

    2017-11-22

    The work here presents a thorough evaluation of the effect of Mn-Na-W/SiO 2 catalyst surface parameters on its performance in the oxidative coupling of methane (OCM). To do so, we used microporous dealuminated β-zeolite (Zeo), or mesoporous SBA-15 (SBA), or macroporous fumed silica (Fum) as precursors for catalyst preparation, together with Mn nitrate, Mn acetate and Na 2 WO 4 . Characterizing the catalysts by inductively coupled plasma-optical emission spectroscopy, N 2 physisorption, X-ray diffraction, high-resolution scanning electron microscopy-energy-dispersive spectroscopy, X-ray photoelectron spectroscopy, and catalytic testing enabled us to identify critical surface parameters that govern the activity and C 2 selectivity of the Mn-Na-W/SiO 2 catalyst. Although the current paradigm views the phase transition of silica to α-cristobalite as the critical step in obtaining dispersed and stable metal sites, we show that the choice of precursors is equally or even more important with respect to tailoring the right surface properties. Specifically, the SBA-based catalyst, characterized by relatively closed surface porosity, demonstrated low activity and low C 2 selectivity. By contrast, for the same composition, the Zeo-based catalyst showed an open surface pore structure, which translated up to fourfold higher activity and enhanced selectivity. By varying the overall composition of the Zeo catalysts, we show that reducing the overall W concentration reduces the size of the Na 2 WO 4 species and increases the catalytic activity linearly as much as fivefold higher than the SBA catalyst. This linear dependence correlates well to the number of interfaces between the Na 2 WO 4 and Mn 2 O 3 species. Our results combined with prior studies lead us to single out the interface between Na 2 WO 4 and Mn 2 O 3 as the most probable active site for OCM using this catalyst. Synergistic interactions between the various precursors used and the phase transition are discussed in

  2. Photon Counting Imaging with an Electron-Bombarded Pixel Image Sensor

    PubMed Central

    Hirvonen, Liisa M.; Suhling, Klaus

    2016-01-01

    Electron-bombarded pixel image sensors, where a single photoelectron is accelerated directly into a CCD or CMOS sensor, allow wide-field imaging at extremely low light levels as they are sensitive enough to detect single photons. This technology allows the detection of up to hundreds or thousands of photon events per frame, depending on the sensor size, and photon event centroiding can be employed to recover resolution lost in the detection process. Unlike photon events from electron-multiplying sensors, the photon events from electron-bombarded sensors have a narrow, acceleration-voltage-dependent pulse height distribution. Thus a gain voltage sweep during exposure in an electron-bombarded sensor could allow photon arrival time determination from the pulse height with sub-frame exposure time resolution. We give a brief overview of our work with electron-bombarded pixel image sensor technology and recent developments in this field for single photon counting imaging, and examples of some applications. PMID:27136556

  3. Enhanced End-Contacts by Helium Ion Bombardment to Improve Graphene-Metal Contacts

    PubMed Central

    Jia, Kunpeng; Su, Yajuan; Zhan, Jun; Shahzad, Kashif; Zhu, Huilong; Zhao, Chao; Luo, Jun

    2016-01-01

    Low contact resistance between graphene and metals is of paramount importance to fabricate high performance graphene-based devices. In this paper, the impact of both defects induced by helium ion (He+) bombardment and annealing on the contact resistance between graphene and various metals (Ag, Pd, and Pt) were systematically explored. It is found that the contact resistances between all metals and graphene are remarkably reduced after annealing, indicating that not only chemically adsorbed metal (Pd) but also physically adsorbed metals (Ag and Pt) readily form end-contacts at intrinsic defect locations in graphene. In order to further improve the contact properties between Ag, Pd, and Pt metals and graphene, a novel method in which self-aligned He+ bombardment to induce exotic defects in graphene and subsequent thermal annealing to form end-contacts was proposed. By using this method, the contact resistance is reduced significantly by 15.1% and 40.1% for Ag/graphene and Pd/graphene contacts with He+ bombardment compared to their counterparts without He+ bombardment. For the Pt/graphene contact, the contact resistance is, however, not reduced as anticipated with He+ bombardment and this might be ascribed to either inappropriate He+ bombardment dose, or inapplicable method of He+ bombardment in reducing contact resistance for Pt/graphene contact. The joint efforts of as-formed end-contacts and excess created defects in graphene are discussed as the cause responsible for the reduction of contact resistance. PMID:28335286

  4. Transmission of broad W/Rh and W/Al (target/filter) x-ray beams operated at 25-49 kVp through common shielding materials.

    PubMed

    Li, Xinhua; Zhang, Da; Liu, Bob

    2012-07-01

    To provide transmission data for broad 25-39 kVp (kilovolt peak) W/Rh and 25-49 kVp W/Al (target/filter, W-tungsten, Rh-rhodium, and Al-aluminum) x-ray beams through common shielding materials, such as lead, concrete, gypsum wallboard, wood, steel, and plate glass. The unfiltered W-target x-ray spectra measured on a Selenia Dimensions system (Hologic Inc., Bedford, MA) set at 20-49 kVp were, respectively, filtered using 50-μm Rh and 700-μm Al, and were subsequently used for Monte Carlo calculations. The transmission of broad x-ray beams through shielding materials was simulated using Geant4 low energy electromagnetic physics package with photon- and electron-processes above 250 eV, including photoelectric effect, Compton scattering, and Rayleigh scattering. The calculated transmission data were fitted using Archer equation with a robust fitting algorithm. The transmission of broad x-ray beams through the above-mentioned shielding materials was calculated down to about 10(-5) for 25-39 kVp W/Rh and 25-49 kVp W/Al. The fitted results of α, β, and γ in Archer equation were provided. The α values of kVp ≥ 40 were approximately consistent with those of NCRP Report No. 147. These data provide inputs for the shielding designs of x-ray imaging facilities with W-anode x-ray beams, such as from Selenia Dimensions.

  5. Magnetospheric ion bombardment profiles of satellites - Europa and Dione

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Pospieszalska, M.K.; Johnson, R.E.

    1989-03-01

    Bombardment profiles generated by tracking ions in magnetospheric plasmas onto the surface of a satellite with a suitable description of the ion motion are used to calculate the spatial dependence across a satellite surface of the ion bombardment/implantation rate for satellites embedded in planetary magnetospheric plasmas. Attention is given to the results of a parameter study; a general dependency on ion gyroradius and pitch angle is noted, together with a strong dependence of access to the leading hemisphere on pitch-angle distribution. Gyromotion is found to cause differences in the bombardment of the inner and outer hemisphere. Reasonable speed and pitch-anglemore » distributions are used to calculate profiles for sulfur ions incident on Europa and oxygen ones incident on Dione. 28 references.« less

  6. Electron-bombarded 〈110〉-oriented tungsten tips for stable tunneling electron emission

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Yamada, T. K.; Abe, T.; Nazriq, N. M. K.

    A clean tungsten (W) tip apex with a robust atomic plane is required for producing a stable tunneling electron emission under strong electric fields. Because a tip apex fabricated from a wire by aqueous chemical etching is covered by impurity layers, heating treatment in ultra-high vacuum is experimentally known to be necessary. However, strong heating frequently melts the tip apex and causes unstable electron emissions. We investigated quantitatively the tip apex and found a useful method to prepare a tip with stable tunneling electron emissions by controlling electron-bombardment heating power. Careful characterizations of the tip structures were performed with combinationsmore » of using field emission I–V curves, scanning electron microscopy, X-ray diffraction (transmitted Debye-Scherrer and Laue) with micro-parabola capillary, field ion microscopy, and field emission microscopy. Tips were chemically etched from (1) polycrystalline W wires (grain size ∼1000 nm) and (2) long-time heated W wires (grain size larger than 1 mm). Heating by 10-40 W (10 s) was found to be good enough to remove oxide layers and produced stable electron emission; however, around 60 W (10 s) heating was threshold power to increase the tip radius, typically +10 ± 5 nm (onset of melting). Further, the grain size of ∼1000 nm was necessary to obtain a conical shape tip apex.« less

  7. Illusory Late Heavy Bombardments

    NASA Astrophysics Data System (ADS)

    Boehnke, P.; Harrison, M.

    2016-12-01

    The Late Heavy Bombardment (LHB), a hypothesized impact spike at 3.9 Ga, is one of the major scientific concepts to emerge from Apollo-era lunar exploration and a significant portion of the evidence now marshaled for its existence comes from histograms of 40Ar/39Ar "plateau" ages. Despite the lack of erosion and plate tectonics, the lunar crust does not retain a perfect impact record due to protracted crust formation, lunar volcanism, and overprinting from subsequent impact events. Indeed, virtually all Apollo-era samples show 40Ar/39Ar age spectrum disturbances due to later re-heating events. This provides evidence that partial 40Ar resetting is a significant feature of lunar 40Ar/39Ar analyses which could bias interpretation of bombardment histories due to "plateau" ages being misleadingly young. In order to examine the effects of partial resetting on the inference of bombardment histories from "plateau" ages, we combine chronologic information derived from the early heating steps of each 40Ar/39Ar analysis, as this represents a good approximation of the timing of the last reheating event, with a first-order physical model of 40Ar* diffusion in Apollo samples. We use this modeling framework and data compilation to examine the uniqueness of inverting "plateau" age histograms from synthetic impact histories. Our results show that "plateau" histograms tend to yield age peaks, even in those cases where the input impact history did not contain such a spike. That is, monotonically declining impact histories yield apparent episodes that could be misinterpreted as LHB-type events. Since H-chondrites and HED meteorites also show apparent impact spikes, we extend our conclusions to impact histories for meteorite parent bodies as well. We conclude that the assignment of apparent "plateau" ages bears an undesirably high degree of subjectivity. When compounded by inappropriately simplistic interpretations of histograms constructed from such "plateau" ages, impact spikes that

  8. AES, EELS and TRIM simulation method study of InP(100) subjected to Ar+, He+ and H+ ions bombardment.

    NASA Astrophysics Data System (ADS)

    Ghaffour, M.; Abdellaoui, A.; Bouslama, M.; Ouerdane, A.; Abidri, B.

    2012-06-01

    Auger Electron Spectroscopy (AES) and Electron Energy Loss Spectroscopy (EELS) have been performed in order to investigate the InP(100) surface subjected to ions bombardment. The InP(100) surface is always contaminated by carbon and oxygen revealed by C-KLL and O-KLL AES spectra recorded just after introduction of the sample in the UHV spectrometer chamber. The usually cleaning process of the surface is the bombardment by argon ions. However, even at low energy of ions beam (300 eV) indium clusters and phosphorus vacancies are usually formed on the surface. The aim of our study is to compare the behaviour of the surface when submitted to He+ or H+ ions bombardment. The helium ions accelerated at 500V voltage and for 45 mn allow removing contaminants but induces damaged and no stoichiometric surface. The proton ions were accelerated at low energy of 500 eV to bombard the InP surface at room temperature. The proton ions broke the In-P chemical bonds to induce the formation of In metal islands. Such a chemical reactivity between hydrogen and phosphorus led to form chemical species such as PH and PH3, which desorbed from the surface. The chemical susceptibly and the small size of H+ advantaged their diffusion into bulk. Since the experimental methods alone were not able to give us with accuracy the disturbed depth of the target by these ions. We associate to the AES and EELS spectroscopies, the TRIM (Transport and Range of Ions in Matter) simulation method in order to show the mechanism of interaction between Ar+, He+ or H+ ions and InP and determine the disturbed depth of the target by argon, helium or proton ions.

  9. High-power liquid-lithium jet target for neutron production

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Halfon, S.; Feinberg, G.; Racah Institute of Physics, Hebrew University, Jerusalem 91904

    2013-12-15

    A compact liquid-lithium target (LiLiT) was built and tested with a high-power electron gun at the Soreq Nuclear Research Center. The lithium target, to be bombarded by the high-intensity proton beam of the Soreq Applied Research Accelerator Facility (SARAF), will constitute an intense source of neutrons produced by the {sup 7}Li(p,n){sup 7}Be reaction for nuclear astrophysics research and as a pilot setup for accelerator-based Boron Neutron Capture Therapy. The liquid-lithium jet target acts both as neutron-producing target and beam dump by removing the beam thermal power (>5 kW, >1 MW/cm{sup 3}) with fast transport. The target was designed based onmore » a thermal model, accompanied by a detailed calculation of the {sup 7}Li(p,n) neutron yield, energy distribution, and angular distribution. Liquid lithium is circulated through the target loop at ∼200 °C and generates a stable 1.5 mm-thick film flowing at a velocity up to 7 m/s onto a concave supporting wall. Electron beam irradiation demonstrated that the liquid-lithium target can dissipate electron power areal densities of >4 kW/cm{sup 2} and volume power density of ∼2 MW/cm{sup 3} at a lithium flow of ∼4 m/s while maintaining stable temperature and vacuum conditions. The LiLiT setup is presently in online commissioning stage for high-intensity proton beam irradiation (1.91–2.5 MeV, 1–2 mA) at SARAF.« less

  10. Transmission of broad W/Rh and W/Al (target/filter) x-ray beams operated at 25-49 kVp through common shielding materials

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Li Xinhua; Zhang Da; Liu, Bob

    2012-07-15

    Purpose: To provide transmission data for broad 25-39 kVp (kilovolt peak) W/Rh and 25-49 kVp W/Al (target/filter, W-tungsten, Rh-rhodium, and Al-aluminum) x-ray beams through common shielding materials, such as lead, concrete, gypsum wallboard, wood, steel, and plate glass. Methods: The unfiltered W-target x-ray spectra measured on a Selenia Dimensions system (Hologic Inc., Bedford, MA) set at 20-49 kVp were, respectively, filtered using 50-{mu}m Rh and 700-{mu}m Al, and were subsequently used for Monte Carlo calculations. The transmission of broad x-ray beams through shielding materials was simulated using Geant4 low energy electromagnetic physics package with photon- and electron-processes above 250 eV,more » including photoelectric effect, Compton scattering, and Rayleigh scattering. The calculated transmission data were fitted using Archer equation with a robust fitting algorithm. Results: The transmission of broad x-ray beams through the above-mentioned shielding materials was calculated down to about 10{sup -5} for 25-39 kVp W/Rh and 25-49 kVp W/Al. The fitted results of {alpha}, {beta}, and {gamma} in Archer equation were provided. The {alpha} values of kVp Greater-Than-Or-Slanted-Equal-To 40 were approximately consistent with those of NCRP Report No. 147. Conclusions: These data provide inputs for the shielding designs of x-ray imaging facilities with W-anode x-ray beams, such as from Selenia Dimensions.« less

  11. Induction of antioxidant enzyme activity and lipid peroxidation level in ion-beam-bombarded rice seeds

    NASA Astrophysics Data System (ADS)

    Semsang, Nuananong; Yu, LiangDeng

    2013-07-01

    Low-energy ion beam bombardment has been used to mutate a wide variety of plant species. To explore the indirect effects of low-energy ion beam on biological damage due to the free radical production in plant cells, the increase in antioxidant enzyme activities and lipid peroxidation level was investigated in ion-bombarded rice seeds. Local rice seeds were bombarded with nitrogen or argon ion beams at energies of 29-60 keV and ion fluences of 1 × 1016 ions cm-2. The activities of the antioxidant enzymes; superoxide dismutase (SOD), catalase (CAT), ascorbate peroxidase (APX), dehydroascorbate reductase (DHAR), glutathione reductase (GR), glutathione S-transferase (GST) and lipid peroxidation level were assayed in the germinated rice seeds after ion bombardment. The results showed most of the enzyme activities and lipid peroxidation levels in both the argon and nitrogen bombarded samples were higher than those in the natural control. N-ion bombardment could induce higher levels of antioxidant enzyme activities in the rice samples than the Ar-ion bombardment. Additional effects due to the vacuum condition were found to affect activities of some antioxidant enzymes and lipid peroxidation level. This study demonstrates that ion beam bombardment and vacuum condition could induce the antioxidant enzyme activity and lipid peroxidation level which might be due to free radical production in the bombarded rice seeds.

  12. Variations in Mechanical Parameters of Rock Mass Affecting Shaft Lining / Zmiany Parametrów Mechanicznych Górotworu I Ich Wpływ Na Obudowę Szybową

    NASA Astrophysics Data System (ADS)

    Majcherczyk, Tadeusz; Niedbalski, Zbigniew; Wałach, Daniel

    2013-09-01

    początkowej długości. W otoczeniu głębionego szybu występują grunty spoiste, głównie w postaci glin z przerostami piasków oraz pyły. Taka litologia powoduje, że na różnych poziomach część warstw gruntu jest zawodniona. Wpływa to na dużą zmienność własności gruntów wokół szybu oraz zmiany tych własności w czasie. Przy dużym zawodnieniu grunt był wymywany zza obudowy, co prowadziło do lokalnej utraty kontaktu pomiędzy obudową a otaczającym gruntem oraz braku właści- wego podparcia dla stóp szybowych. Efektem tego było na niewielkim odcinku szybu pękanie obudowy. Podjęte działania, które sprowadziły się do wykonania iniekcji na pewnym odcinku szybu doprowadziły do przywrócenia właściwej współpracy obudowa - górotwór. Przeprowadzone badania gruntu zza obudowy posłużyły do podjęcia działań w celu zwiększenia nośności stóp szybowych. Badania gruntu wykazały, że kąt tarcia wewnętrznego oraz spójność zmieniają się nie tylko na poszczególnych głębokościach, ale także obserwuje się duże różnice dla próbek pobranych z tej samej głębokości ale z różnych punktów na obwodzie szybu. Badania wykazały także wzrost parametrów mechanicznych badanych gruntów wraz z oddalaniem się od obudowy, co świadczy o zmianie własności gruntów bezpośrednio w sąsiedztwie szybu. Duża liczba wykonanych badań pozwoliła na opracowanie zależności pomiędzy wilgotnością a kątem tarcia wewnętrznego i spójnością. Na podstawie uzyskanych zależności można szacować z dużą dokładnością zmianę własności gruntów pod wpływem działania wody. Zrealizowane wzmocnienia stóp szybowych z wykorzystaniem kotew gruntowych pozwoliły na podjęcie dalszego głębienia szybu. Przeprowadzone na analizowanym odcinku badania betonu z obudowy szybu wykazały wartości zgodne z projektem.

  13. Molybdenum and carbon atom and carbon cluster sputtering under low-energy noble gas plasma bombardment

    NASA Astrophysics Data System (ADS)

    Oyarzabal, Eider

    Exit-angle resolved Mo atom sputtering yield under Xe ion bombardment and carbon atom and cluster (C2 and C3) sputtering yields under Xe, Kr, Ar, Ne and He ion bombardment from a plasma are measured for low incident energies (75--225 eV). An energy-resolved quadrupole mass spectrometer (QMS) is used to detect the fraction of un-scattered sputtered neutrals that become ionized in the plasma; the angular distribution is obtained by changing the angle between the target and the QMS aperture. A one-dimensional Monte Carlo code is used to simulate the interaction of the plasma and the sputtered particles between the sample and the QMS. The elastic scattering cross-sections of C, C2 and C3 with the different bombarding gas neutrals is obtained by varying the distance between the sample and the QMS and by performing a best fit of the simulation results to the experimental results. Because the results obtained with the QMS are relative, the Mo atom sputtering results are normalized to the existing data in the literature and the total sputtering yield for carbon (C+C 2+C3) for each bombarding gas is obtained from weight loss measurements. The absolute sputtering yield for C, C2 and C 3 is then calculated from the integration of the measured angular distribution, taking into account the scattering and ionization of the sputtered particles between the sample and the QMS. The angular sputtering distribution for Mo has a maximum at theta=60°, and this maximum becomes less pronounced as the incident ion energy increases. The results of the Monte Carlo TRIDYN code simulation for the angular distribution of Mo atoms sputtered by Xe bombardment are in agreement with the experiments. For carbon sputtering under-cosine angular distributions of the sputtered atoms and clusters for all the studied bombarding gases are also observed. The C, C2 and C3 sputtering yield data shows a clear decrease of the atom to cluster (C/C2 and C/C3) sputtering ratio as the incident ion mass increases

  14. Surface layer modification of ion bombarded HDPE

    NASA Astrophysics Data System (ADS)

    Bielinski, D.; Lipinski, P.; Slusarski, L.; Grams, J.; Paryjczak, T.; Jagielski, J.; Turos, A.; Madi, N. K.

    2004-08-01

    Press-moulded, high density polyethylene (HDPE) samples were subjected to ion bombardment and effects of the modification studied. He + ions of energy 100 keV or Ar + ions of energy 130 keV were applied in the range of dose 1-30 × 10 15/cm 2 or 1-100 × 10 14/cm 2, respectively. This paper has been focused on structural changes of the surface layer. The consequences of the modification were studied with TOF-SIMS and FTIR-IRS techniques. The results point on two mechanisms taking place simultaneously: ionization of polymer macromolecules and chain scission--resulting in creation of macroradicals. Both of them produce oxidation and lead to significant release of hydrogen. The former diminishes for the highest ion doses, however, creation of molecular oxygen cannot be excluded. The latter in the case of Ar + ion bombardment is reflected by prevailing degradation of the surface layer of HDPE. Contrary to the effect of heavy ions, He + ion bombardment was found to produce significant increase of the material hardness, which was explained by crosslinking of polyethylene. A mechanism of polyacetylene formation, proceeding finally to cross-polymerization of the polymer was proposed. Apart from structural changes, the modification revealed additionally a possibility to improve the wettability of the polymer.

  15. A Unique Photon Bombardment System for Space Applications

    NASA Technical Reports Server (NTRS)

    Klein, E. J.

    1993-01-01

    The innovative Electromagnetic Radiation Collection and Concentration System (EMRCCS) described is the foundation for the development of a multiplicity of space and terrestrial system formats. The system capability allows its use in the visual, infrared, and ultraviolet ranges of the spectrum for EM collection, concentration, source/receptor tracking, and targeting. The nonimaging modular optical system uses a physically static position aperture for EM radiation collection. Folded optics provide the concentration of the radiation and source autotracking. The collected and concentrated electromagnetic radiation is utilized in many applications, e.g., solar spectrum in thermal and associative photon bombardment applications for hazardous waste management, water purification, metal hardening, hydrogen generation, photovoltaics, etc., in both space and terrestrial segment utilization. Additionally, at the high end of the concentration capability range, i.e., 60,000+, a solar-pulsed laser system is possible.

  16. Study and optimisation of SIMS performed with He+ and Ne+ bombardment

    NASA Astrophysics Data System (ADS)

    Pillatsch, L.; Vanhove, N.; Dowsett, D.; Sijbrandij, S.; Notte, J.; Wirtz, T.

    2013-10-01

    The combination of the high-brightness He+/Ne+ atomic level ion source with the detection capabilities of secondary ion mass spectrometry (SIMS) opens up the prospect of obtaining chemical information with high lateral resolution and high sensitivity on the Zeiss ORION helium ion microscope (HIM). A feasibility study with He+ and Ne+ ion bombardment is presented in order to determine the performance of SIMS analyses using the HIM. Therefore, the sputtering yields, useful yields and detection limits obtained for metallic (Al, Ni and W) as well as semiconductor samples (Si, Ge, GaAs and InP) were investigated. All the experiments were performed on a Cameca IMS4f SIMS instrument which was equipped with a caesium evaporator and oxygen flooding system. For most of the elements, useful yields in the range of 10-4 to 3 × 10-2 were measured with either O2 or Cs flooding. SIMS experiments performed directly on the ORION with a prototype secondary ion extraction and detection system lead to results that are consistent with those obtained on the IMS4f. Taking into account the obtained useful yields and the analytical conditions, such as the ion current and typical dwell time on the ORION HIM, detection limits in the at% range and better can be obtained during SIMS imaging at 10 nm lateral resolution with Ne+ bombardment and down to the ppm level when a lateral resolution of 100 nm is chosen. Performing SIMS on the HIM with a good detection limit while maintaining an excellent lateral resolution (<50 nm) is therefore very promising.

  17. Design study of 10 kW direct fission target for RISP project

    NASA Astrophysics Data System (ADS)

    Tshoo, K.; Jang, D. Y.; Woo, H. J.; Kang, B. H.; Kim, G. D.; Hwang, W.; Kim, Y. K.

    2014-03-01

    We are developing Isotope Separation On-Line (ISOL) target system, which consists of 1.3 mm-thick uranium-carbide multi-disks and cylindrical tantalum heater, to be installed in new facility for Rare Isotope Science Project in Korea. The intense neutron-rich nuclei are produced via the fission process using the uranium carbide targets with a 70 MeV proton beam. The fission rate was estimated to be ˜1.5 × 1013/sec for 10 kW proton beam. The target system has been designed to be operated at a temperature of ˜2000 °C so as to improve the release effciency.

  18. Human endogenous retrovirus W in brain lesions: Rationale for targeted therapy in multiple sclerosis.

    PubMed

    van Horssen, Jack; van der Pol, Susanne; Nijland, Philip; Amor, Sandra; Perron, Hervé

    2016-07-01

    Attempts to identify a causative agent of Multiple Sclerosis (MS) among environmental viruses have consistently failed suggesting that development of MS is a result from gene-environment interactions. A new pathogenic player within human genes, a human endogenous retrovirus (HERV) was identified from MS cells, named MS-associated retrovirus element (MSRV) and unveiled homologous multicopy HERVs (HERV-W). As independent studies revealed biological features of HERV-W on immune-mediated inflammation and on remyelinating cells, the present study characterized the presence of HERV-W envelope protein (MSRV-Env) at the cellular level, in different MS lesion stages to extend and validate previous studies. Immunohistological analysis of HERV-W envelope cellular expression in different lesion stages from a cohort of MS brains versus controls, using well-characterized and highly specific monoclonal antibodies. HERV-W envelope protein was detected in all MS brains and quite essentially in lesions. Immunohistochemistry showed dominant expression in macrophages and microglia, coinciding with areas of active demyelination, spread over the active lesions, or limited to the rim of active microglia in chronic active lesions or in few surviving astrocytes of inactive plaques. Weak expression was seen in MS normal appearing white matter. In active plaques, few lymphoid cells and astrocytes were also stained. This HERV-W expression was not observed in control brains. HERV-W was expressed in demyelinated lesions from MS brains, which were all positive for this endogenous pathogenic protein. Pronounced HERV-W immunoreactivity in active MS lesions was intimately associated with areas of active demyelination throughout the successive stages of lesion evolution in MS brains. Based on its pathogenic potential, this HERV-W (MSRV) endogenous toxin thus appears to be a novel therapeutic target in MS. It also has a unique positioning as an early and lifelong expressed pathogenic agonist, acting

  19. HYDROGEN ISOTOPE TARGETS

    DOEpatents

    Ashley, R.W.

    1958-08-12

    The design of targets for use in the investigation of nuclear reactions of hydrogen isotopes by bombardment with accelerated particles is described. The target con struction eomprises a backing disc of a metal selected from the group consisting of molybdenunn and tungsten, a eoating of condensed titaniunn on the dise, and a hydrogen isotope selected from the group consisting of deuterium and tritium absorbed in the coatiag. The proeess for preparing these hydrogen isotope targets is described.

  20. Continued improvement in reduced-mode (REM) diodes enable 272 W from 105 μm 0.15 NA beam

    NASA Astrophysics Data System (ADS)

    Kanskar, M.; Bao, L.; Chen, Z.; Dawson, D.; DeVito, M.; Dong, W.; Grimshaw, M.; Guan, X.; Hemenway, M.; Martinsen, R.; Urbanek, W.; Zhang, S.

    2017-02-01

    High-power, high-brightness diode lasers from 8xx nm to 9xx nm have been pursued in many applications including fiber laser pumping, materials processing, solid-state laser pumping, and consumer electronics manufacturing. In particular, 915 nm - 976 nm diodes are of interest as diode pumps for the kilowatt CW fiber lasers. Thus, there have been many technical efforts on driving the diode lasers to have both high power and high brightness to achieve high-performance and reduced manufacturing costs. This paper presents our continued progress in the development of high brightness fiber-coupled product platform, elementTM. In the past decade, the amount of power coupled into a single 105 μm and 0.15 NA fiber has increased by over a factor of ten through improved diode laser brilliance and the development of techniques for efficiently coupling multiple emitters into a single fiber. In this paper, we demonstrate the further brightness improvement and power-scaling enabled by both the rise in chip brightness/power and the increase in number of chips coupled into a given numerical aperture. We report a new x-REM design with brightness as high as 4.3 W/mm-mrad at a BPP of 3 mm-mrad. We also report the record 272W from a 2×9 elementTM with 105 μm/0.15 NA beam using x-REM diodes and a new product introduction at 200W output power from 105 μm/0.15 NA beam at 915 nm.

  1. Solid-state synthesis in the system Na 0.8Nb yW 1-yO 3 with 0⩽ y⩽0.4: A new phase, Na 0.5NbO 2.75, with perovskite-type structure

    NASA Astrophysics Data System (ADS)

    Debnath, Tapas; Rüscher, Claus H.; Gesing, Thorsten M.; Koepke, Jürgen; Hussain, Altaf

    2008-04-01

    Series of compounds in the system Na xNb yW 1-yO 3 were prepared according to the appropriate molar ratio of Na 2WO 4, WO 3, WO 2 and Nb 2O 5 with x=0.80 and 0.0⩽ y⩽0.4 at 600 °C in evacuated silica glass tubes. These compounds were investigated by X-ray powder diffraction, optical microscopy, microprobe analysis, Raman and optical microspectroscopy. A y-dependent separation into three distinct coloured crystallites with cubic perovskite-type structures is observed: (i) red-orange crystallites with composition Na xWO 3 with slightly decreasing x (i.e. 0.8-0.72) with increasing nominal y, (ii) bluish solid solution of composition Na xNb yW 1-yO 3 and (iii) white crystallites of a new phase having defect perovskite-type structure with composition Na 0.5NbO 2.75.

  2. Simulation of cosmic irradiation conditions in thick target arrangements

    NASA Technical Reports Server (NTRS)

    Theis, S.; Englert, P.; Reedy, R. C.; Arnold, J. R.

    1986-01-01

    One approach to simulate 2-pi irradiation conditions of planetary surfaces which has been widely applied in the past are bombardments of so called thick targets. A very large thick target was exposed recently to 2.1 GeV protons at the Bevatron-Bevalac in Berkeley. In a 100x100x180 cm steel-surrounded granodiorite target radioactive medium and high energy spallation products of the incident primary and of secondary particles were analyzed along the beam axis down to depths of 140 g/cm(2) in targets such as Cu, Ni, Co, Fe, T, Si, SiO2 and Al. Activities of these nuclides were exclusively determined via instrumental gamma-ray spectroscopy. Relative yields of neutron capture and spallation products induced in Co and Cu targets during the thick target bombardment are shown as a function of depth. The majority of the medium energy products such as Co-58 from Co targets exhibit a maximum at shallow depths of 40-60 g/cm(2) and then decrease exponentially. In a comparable 600 MeV proton bombarded thick target such a slight maximum for medium energy products was not observed. Rather, Co-58 activities in Co decreased steadily with the highest activity at the surface. The activities of the n-capture product Co-60 increase steadily starting at the surface. This indicates the rapidly growing flux of low energy neutrons within the target.

  3. Self-Assembled Gold Nano-Ripple Formation by Gas Cluster Ion Beam Bombardment.

    PubMed

    Tilakaratne, Buddhi P; Chen, Quark Y; Chu, Wei-Kan

    2017-09-08

    In this study, we used a 30 keV argon cluster ion beam bombardment to investigate the dynamic processes during nano-ripple formation on gold surfaces. Atomic force microscope analysis shows that the gold surface has maximum roughness at an incident angle of 60° from the surface normal; moreover, at this angle, and for an applied fluence of 3 × 10 16 clusters/cm², the aspect ratio of the nano-ripple pattern is in the range of ~50%. Rutherford backscattering spectrometry analysis reveals a formation of a surface gradient due to prolonged gas cluster ion bombardment, although the surface roughness remains consistent throughout the bombarded surface area. As a result, significant mass redistribution is triggered by gas cluster ion beam bombardment at room temperature. Where mass redistribution is responsible for nano-ripple formation, the surface erosion process refines the formed nano-ripple structures.

  4. Cuttings Transport with Foam in Highly Inclined Wells at Simulated Downhole Conditions / Transport urobku wiertniczego przy użyciu piany w silnie nachylonych otworach w symulowanych warunkach w otworze

    NASA Astrophysics Data System (ADS)

    Xu, Jiafu; Ozbayoglu, Evren; Miska, Stefan Z.; Yu, Mengjiao; Takach, Nicholas

    2013-06-01

    of this paper will help designers with the choice of optimal drilling fluid for drilling horizontal wells in unconventional (shale) gas/oil reservoirs. Równolegle ze stale rosnącym zapotrzebowaniem na prowadzenia prac udostępniających w złożach niekonwencjonalnych notuje się wzrost świadomości społecznej odnośnie zagadnień ochrony środowiska. Piana jako alternatywa dla tradycyjnej płuczki wiertniczej nabiera coraz większego znaczenia w górnictwie otworowym. Wiercenie przy użyciu piany pomogą ograniczać zniszczenia formacji geologicznych, redukuje zużycie wody, pozwala na zminimalizowanie oporów ruchu i momentów obrotowych silników. Ponadto, koszty piany są niższe a jej oddziaływanie na środowisko naturalne jest mniej znaczne niż w przypadku typowych płuczek opartych na olejach syntetycznych używanych w trakcie udostępniania trudnych w eksploatacji złóż, np. gazu łupkowego. Wiercenia odcinków poziomych lub prawie poziomych są już szeroko stosowane a zapotrzebowanie na takie odcinki wrasta, ważnym jest właściwe rozpoznanie problemów związanych z transportem urobku wiertniczego i czyszczeniem otworu w trakcie prowadzenia prac wiertniczych na tych odcinkach przy użyciu piany. Zespól badaczy z uniwersytetu w Tulsa zaangażowanych w projekt badawczy w dziedzinie wiertnictwa (TUDRP) przeprowadził serię eksperymentów mających na celu zbadanie wpływu zmiany kąta nachylenia otworu z 90 na 70 stopni na przebieg transportu urobku wiertniczego z wykorzystanie piany w warunkach podwyższonego ciśnienia i podwyższonych temperatur. Badania eksperymentalne i teoretyczne obejmowały także analizę pozostałych parametrów procesu: jakość piany, natężenie przepływu piany, stężenie polimerów, prędkość obrotowa przewodu wiertniczego. Nie stwierdzono znacznych różnic w stężeniu zwiercin ani utraty ciśnienia wskutek tarcia w trakcie zmiany kąta nachylenia z 90 na 70 stopni. Ponadto, dodatkowy wzrost prędkości ruchu

  5. Silver Film Surface Modification by Ion Bombardment Decreases Surface Plasmon Resonance Absorption.

    PubMed

    Fryauf, David M; Diaz Leon, Juan J; Phillips, Andrew C; Kobayashi, Nobuhiko P

    2017-05-10

    Silver thin films covered with dielectric films serving as protective coatings are desired for telescope mirrors, but durable coatings have proved elusive. As part of an effort to develop long-lived protected-silver mirrors, silver thin films were deposited by electron beam evaporation using a physical vapor deposition system at the University of California Observatories Astronomical Coatings Lab. The silver films were later covered with a stack of dielectric films utilizing silicon nitride and titanium dioxide deposited by ion-assisted electron beam evaporation to fabricate protected mirrors. In-situ argon ion bombardment was introduced after silver deposition and prior to the deposition of dielectric films to assess its effects on the performance of the mirrors. We found that ion bombardment of the silver influenced surface morphology and reflectivity, and these effects correlated with time between silver deposition and ion bombardment. The overall reflectivity at wavelengths in the range of 350-800 nm was found to improve due to ion bombardment, which was qualitatively interpreted as a result of decreased surface plasmon resonance coupling. We suggest that the observed decrease in coupling is caused by silver grain boundary pinning due to ion bombardment suppressing silver surface diffusion, forming smoother silver-dielectric interfaces.

  6. The 18Ne(α,p)21Na breakout reaction in x-ray bursts: Experimental determination of spin-parities for α resonances in 22Mg via resonant elastic scattering of 21Na+p

    NASA Astrophysics Data System (ADS)

    He, J. J.; Zhang, L. Y.; Parikh, A.; Xu, S. W.; Yamaguchi, H.; Kahl, D.; Kubono, S.; Hu, J.; Ma, P.; Chen, S. Z.; Wakabayashi, Y.; Sun, B. H.; Wang, H. W.; Tian, W. D.; Chen, R. F.; Guo, B.; Hashimoto, T.; Togano, Y.; Hayakawa, S.; Teranishi, T.; Iwasa, N.; Yamada, T.; Komatsubara, T.

    2013-07-01

    The 18Ne(α,p)21Na reaction provides a pathway for breakout from the hot CNO cycles to the rp process in type-I x-ray bursts. To better determine this astrophysical reaction rate, the resonance parameters of the compound nucleus 22Mg have been investigated by measuring the resonant elastic scattering of 21Na+p. An 89 MeV 21Na radioactive ion beam was produced at the CNS Radioactive Ion Beam Separator and bombarded an 8.8 mg/cm2 thick polyethylene target. The recoiled protons were measured at scattering angles of θc.m.≈175∘ and 152∘ by three ΔE-E silicon telescopes. The excitation function was obtained with a thick-target method over energies Ex(22Mg) = 5.5-9.2 MeV. The resonance parameters have been determined through an R-matrix analysis. For the first time, the Jπ values for ten states above the α threshold in 22Mg have been experimentally determined in a single consistent measurement. We have made three new Jπ assignments and confirmed seven of the ten tentative assignments in the previous work. The 18Ne(α,p)21Na reaction rate has been recalculated, and the astrophysical impact of our new rate has been investigated through one-zone postprocessing x-ray burst calculations. We find that the 18Ne(α,p)21Na rate significantly affects the peak nuclear energy generation rate and the onset temperature of this breakout reaction in these phenomena.

  7. Surface chemical reactions induced on pyrite by ion bombardment

    NASA Astrophysics Data System (ADS)

    Ruano, Gustavo; Pomiro, Fernando; Ferrón, Julio

    2018-01-01

    Through X-ray photoemission spectroscopy (XPS), we studied the chemical changes induced in a natural crystal of pyrite (FeS2) upon exposure to 4.5 keV He+ beam. We found an important reducing effect induced by ion bombardment leading to the production of iron embedded in the pyrite matrix. Through a combination of the usual Doniach-Sunjic treatment and Factor Analysis of XPS yields, we were able of analyzing the full Fe 2p XPS signal. We could in this way distinguish Fe compounds with the same binding energy for the Fe 2p3/2 yield. Our results show that He+ bombardment disrupts the ionic environment producing S2-2 and S0, Fe2+ and Fe3+ ions, and the reduction to metallic iron. The remaining pyrite matrix does not passivate the embedded iron structures, which are readily oxidized under air exposure. The oxide formed resembled that of magnetite from the XPS point of view. Further He+ bombardment proved to be efficient to reduce the iron oxide back to iron again.

  8. Sol-gel synthesis of red-phosphors [Na xGd 1-x/3-zEu z]Mo yW 1-yO 4 powers and luminescence properties

    NASA Astrophysics Data System (ADS)

    Cao, Fa-Bin; Li, Liao-Sha; Tian, Yan-Wen; Gao, Zhi-Fang; Chen, Yong-Jie; Xiao, Lin-Jiu; Wu, Xing-Rong

    2011-04-01

    In this work, we report on the sol-gel synthesis of red-phosphors [Na xGd 1-x/3-zEu z]Mo yW 1-yO 4 powders doped with several dopants and its luminescence properties at room temperature. X-ray diffraction patters indicated that red-phosphors powders present tetragonal symmetry and cubic structure. The red-phosphors [Na xGd 1-x/3-zEu z]Mo yW 1-yO 4 powders doped exhibit characteristic of a ultraviolet visible-light emission diode. The SEM images for [ NaGdEu0.043+]Mo 0.4W 0.6O 4 phosphor exhibits irregular morphology and cottonlike shape. The size of the particles is estimated to be about 1 μm. Luminescence properties showed that the maximum emission in red region lies in the arrange of 613 nm and 617 nm.

  9. Development of a double plasma gun device for investigation of effects of vapor shielding on erosion of PFC materials under ELM-like pulsed plasma bombardment

    NASA Astrophysics Data System (ADS)

    Sakuma, I.; Iwamoto, D.; Kitagawa, Y.; Kikuchi, Y.; Fukumoto, N.; Nagata, M.

    2012-10-01

    It is considered that thermal transient events such as type I edge localized modes (ELMs) could limit the lifetime of plasma-facing components (PFCs) in ITER. We have investigated surface damage of tungsten (W) materials under transient heat and particle loads by using a magnetized coaxial plasma gun (MCPG) device at University of Hyogo. The capacitor bank energy for the plasma discharge is 144 kJ (2.88 mF, 10 kVmax). Surface melting of a W material was clearly observed at the energy density of ˜2 MJ/m2. It is known that surface melting and evaporation during a transient heat load could generate a vapor cloud layer in front of the target material [1]. Then, the subsequent erosion could be reduced by the vapor shielding effect. In this study, we introduce a new experiment using two MCPG devices (MCPG-1, 2) to understand vapor shielding effects of a W surface under ELM-like pulsed plasma bombardment. The capacitor bank energy of MCPG-2 is almost same as that of MCPG-1. The second plasmoid is applied with a variable delay time after the plasmoid produced by MCPG-1. Then, a vapor cloud layer could shield the second plasma load. To verify the vapor shielding effects, surface damage of a W material is investigated by changing the delay time. In the conference, the preliminary experimental results will be shown.[4pt] [1] A. Hassanein et al., J. Nucl. Mater. 390-391, pp. 777-780 (2009).

  10. Simulation of carbon nanotube welding through Ar bombardment.

    PubMed

    Kucukkal, Mustafa U; Stuart, Steven J

    2017-04-01

    Single-walled carbon nanotubes show promise as nanoscale transistors for nanocomputing applications. This use will require appropriate methods for creating electrical connections between distinct nanotubes, analogous to welding of metallic wires at larger length scales, but methods for performing nanoscale chemical welding are not yet sufficiently understood. This study examines the effect of Ar bombardment on the junction of two crossed single-walled carbon nanotubes, to understand the value and limitations of this method for generating connections between nanotubes. A geometric criterion was used to assess the quality of the junctions formed, with the goal of identifying the most productive conditions for experimental ion bombardment. In particular, the effects of nanotube chirality, Ar impact kinetic energy, impact particle flux and fluence, and annealing temperature were considered. The most productive bombardment conditions, leading to the most crosslinking of the tubes with the smallest loss of graphitic (i.e., conductive) character, were found to be at relatively mild impact energies (100 eV), with low flux and high-temperature (3000 K) annealing. Particularly noteworthy for experimental application, a high junction quality is maintained for a relatively broad range of fluences, from 3 × 10 19  m -2 to at least 1 × 10 20  m -2 .

  11. Dating Howardite Melt Clasts: Evidence for an Extended Vestan Bombardment?

    NASA Technical Reports Server (NTRS)

    Cartwright, J. A.; Hodges, K. V.; Wadhwa, M.; Mittlefehldt, D. W.

    2016-01-01

    Howardites are polymict breccias that, together with eucrites and diogenites (HED), likely originate from the vestan surface (regolith/ megaregolith), and display a heterogeneous distribution of eucritic and diogenitic material. Melt clasts are also present alongside other regolithic features within howardites, and are noteworthy for their compositional variability and appearance. Melt clasts formed by impact events provide a snapshot of the timings and conditions of surface gardening and bombardment on the vestan surface. By dating such clasts, we aim to better constrain the timings of impact events on Vesta, and to establish whether the impact flux in the asteroid belt was similar to that on the Moon. As the Moon is used as the basis for characterising impact models of the inner solar system, it is necessary to verify that apparent wide-scale events are seen in other planetary bodies. In particular, the observed clustering of Apollo melt clast ages between 3.8-4.0 Ga has led to two hypotheses: 1) The Moon was subjected to a sudden event - 'Lunar Cataclysm' or period of 'Late Heavy Bombardment' (LHB), 2) The age cluster represents the end of an epoch of declining bombardment or 'Heavy Bombardment. No consensus has emerged regarding one or other hypothesis. We are testing these hypotheses by seeking evidence for such events in materials other than those derived from the Moon.

  12. JOVIAN EARLY BOMBARDMENT: PLANETESIMAL EROSION IN THE INNER ASTEROID BELT

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Turrini, D.; Coradini, A.; Magni, G., E-mail: diego.turrini@ifsi-roma.inaf.it

    The asteroid belt is an open window on the history of the solar system, as it preserves records of both its formation process and its secular evolution. The progenitors of the present-day asteroids formed in the Solar Nebula almost contemporary to the giant planets. The actual process producing the first generation of asteroids is uncertain, strongly depending on the physical characteristics of the Solar Nebula, and the different scenarios produce very diverse initial size-frequency distributions (SFDs). In this work, we investigate the implications of the formation of Jupiter, plausibly the first giant planet to form, on the evolution of themore » primordial asteroid belt. The formation of Jupiter triggered a short but intense period of primordial bombardment, previously unaccounted for, which caused an early phase of enhanced collisional evolution in the asteroid belt. Our results indicate that this Jovian Early Bombardment caused the erosion or the disruption of bodies smaller than a threshold size, which strongly depends on the SFD of the primordial planetesimals. If the asteroid belt was dominated by planetesimals less than 100 km in diameter, the primordial bombardment would have caused the erosion of bodies smaller than 200 km in diameter. If the asteroid belt was instead dominated by larger planetesimals, the bombardment would have resulted in the destruction of bodies as big as 500 km.« less

  13. Properties of Waste from Coal Gasification in Entrained Flow Reactors in the Aspect of Their Use in Mining Technology / Właściwości odpadów ze zgazowania węgla w reaktorach dyspersyjnych w aspekcie ich wykorzystania w technologiach górniczych

    NASA Astrophysics Data System (ADS)

    Pomykała, Radosław

    2013-06-01

    ęgla lub węgla z dodatkami: bitumin (żużel S1), czy biomasy (popiół A2, żużel S2). W polskim górnictwie podziemnym wyróżnić można kilka technologii podsadzkowych, w których do transportu materiału wykorzystywana jest woda. Tradycyjnie oraz ze względów historycznych, terminem "podsadzka hydrauliczna" określa się tę, która spełnia wymagania normy PN-93/G-11010. Do najważniejszych cech takiej podsadzki hydraulicznej zaliczyć należy wypełnienia uprzednio wydzielonej pustki poeksploatacyjnej, materiałem o jak najmniejszej ściśliwości oraz o jak największej wodoprzepuszczalności. Materiał taki, po odprowadzeniu wody ma stanowić mechaniczna podporę stropu, a proces podsadzania jest ściśle powiązany z procesem eksploatacji, jako sposób likwidacji zrobów. Najczęściej stosowanymi materiałami są piasek podsadzkowy oraz odpady górnicze lub hutnicze (Lisowski, 1997). Od ponad dwudziestu lat, w polskim górnictwie węgla kamiennego obecna jest również inna technologia podsadzkowa, w której do transportu materiałów wykorzystywana jest woda. W tym przypadku części stałe to materiały drobnoziarniste, najczęściej popioły różnych typów, które po wymieszaniu z wodą tworzą zawiesinę (stąd termin "zawiesiny popiołowo-wodne"). Polska norma PN-G-11011:1998 wyróżnia dwie odmiany takich zawiesin i definiuje je, jako "podsadzkę zestalaną" oraz "mieszaninę do doszczelniania zrobów". Podstawową ideą przyświecającą stosowaniu zawiesin drobnoziarnistych w technologiach górniczych była początkowo troska o zagospodarowaniu odpadów energetycznych, a następnie górniczych (Mazurkiewicz i in., 1998; Piotrowski i in., 2006; Piotrowski, 2010; Plewa i Mysłek, 2000; Plewa i Sobota, 2002). Obecnie technologia zawiesinowa na stałe zagościła w kopalniach węgla kamiennego stając się m.in. nieodzownym środkiem profilaktyki pożarowej i metanowej (Dziurzyński i Pomykała, 2006; Palarski, 2004; Pomykała, 2006). W artykule

  14. Ion bombardment experiments suggesting an origin for organic particles in pre-cometary and cometary ices

    NASA Technical Reports Server (NTRS)

    Wdowiak, Thomas J.; Robinson, Edward L.; Flickinger, Gregory C.; Boyd, David A.

    1989-01-01

    During the Giotto and Vega encounters with Comet Halley both organic particles called CHON and energetic ions were detected. The acceleration of ions to hundreds of keV in the vicinity of the bow shock and near the nucleus may be a demonstration of a situation occurring in the early solar system (perhaps during the T Tauri stage) that led to the formation of organic particles only now released. Utilizing a Van de Graaff accelerator and a target chamber having cryogenic and mass spectrometer capabilities, frozen gases were bombarded at 10 K with 175 keV protons with the result that fluffy solid material remains after sublimation of the ice. Initial experiments were carried out with a gas mixture in parts of 170 carbon monoxide, 170 argon, 25 water, 20 nitrogen, and 15 methane formulated to reflect an interstellar composition in experiments involving the freezing out of the products of a plasma. The plasma experiments resulted in a varnish-like film residue that exhibited luminescence when excited with ultraviolet radiation, while the ion bombardment created particulate material that was not luminescent.

  15. Illusory Late Heavy Bombardments

    NASA Astrophysics Data System (ADS)

    Boehnke, Patrick; Harrison, T. Mark

    2016-09-01

    The Late Heavy Bombardment (LHB), a hypothesized impact spike at ˜3.9 Ga, is one of the major scientific concepts to emerge from Apollo-era lunar exploration. A significant portion of the evidence for the existence of the LHB comes from histograms of 40Ar/39Ar “plateau” ages (i.e., regions selected on the basis of apparent isochroneity). However, due to lunar magmatism and overprinting from subsequent impact events, virtually all Apollo-era samples show evidence for 40Ar/39Ar age spectrum disturbances, leaving open the possibility that partial 40Ar* resetting could bias interpretation of bombardment histories due to plateaus yielding misleadingly young ages. We examine this possibility through a physical model of 40Ar* diffusion in Apollo samples and test the uniqueness of the impact histories obtained by inverting plateau age histograms. Our results show that plateau histograms tend to yield age peaks, even in those cases where the input impact curve did not contain such a spike, in part due to the episodic nature of lunar crust or parent body formation. Restated, monotonically declining impact histories yield apparent age peaks that could be misinterpreted as LHB-type events. We further conclude that the assignment of apparent 40Ar/39Ar plateau ages bears an undesirably high degree of subjectivity. When compounded by inappropriate interpretations of histograms constructed from plateau ages, interpretation of apparent, but illusory, impact spikes is likely.

  16. Illusory Late Heavy Bombardments

    PubMed Central

    Boehnke, Patrick; Harrison, T. Mark

    2016-01-01

    The Late Heavy Bombardment (LHB), a hypothesized impact spike at ∼3.9 Ga, is one of the major scientific concepts to emerge from Apollo-era lunar exploration. A significant portion of the evidence for the existence of the LHB comes from histograms of 40Ar/39Ar “plateau” ages (i.e., regions selected on the basis of apparent isochroneity). However, due to lunar magmatism and overprinting from subsequent impact events, virtually all Apollo-era samples show evidence for 40Ar/39Ar age spectrum disturbances, leaving open the possibility that partial 40Ar* resetting could bias interpretation of bombardment histories due to plateaus yielding misleadingly young ages. We examine this possibility through a physical model of 40Ar* diffusion in Apollo samples and test the uniqueness of the impact histories obtained by inverting plateau age histograms. Our results show that plateau histograms tend to yield age peaks, even in those cases where the input impact curve did not contain such a spike, in part due to the episodic nature of lunar crust or parent body formation. Restated, monotonically declining impact histories yield apparent age peaks that could be misinterpreted as LHB-type events. We further conclude that the assignment of apparent 40Ar/39Ar plateau ages bears an undesirably high degree of subjectivity. When compounded by inappropriate interpretations of histograms constructed from plateau ages, interpretation of apparent, but illusory, impact spikes is likely. PMID:27621460

  17. Types of Moulding and Methods of Eliminating Dry Rot in Historic Buildings: Example of Sobiescy Palace in Lublin (Based on Study by Mirosław Zaród)/ Zagrzybienia I Metody Odgrzybiania Obiektów Zabytkowych Na Przykładzie Pałacu Sobieskich W Lublinie (Na Podstawie Opracowania Dokonanego Przez M. Zaróda)

    NASA Astrophysics Data System (ADS)

    Wrana, Jan; Jarocka-Mikrut, Aleksandra

    2015-06-01

    By presenting Sobiescy Palace in Lublin as well as results of mycological research conducted in the said premises, the authors describe hazards and dangers arising from damp present in historic buildings for a long time. Results of mycological research quoted in this article indicate that differences in levels of damp depend on the cardinal direction a specific wall faces. The authors also pay attention to reasons for which the described premises suffer from damp and provide programmes of treatment and prevention. Furthermore, the article gives the reader a detailed insight into multiple opportunities for improving technical conditions of historic buildings and, at the same time, raising their functional standards. However, one must not forget to treat such premises with proper respect. W artykule przedstawiono zagrożenia tkwiące w długotrwałym narażeniu zabudowań historycznych na wilgoć na podstawie Pałacu Sobieskich w Lublinie oraz ekspertyzy mykologicznej. Zwrócono uwagę na różnice w wilgotności ścian oraz zależności wynikające z orientacji budowli względem stron świata. Opisano przyczyny występowania wilgoci w opisywanym założeniu jak również wskazano możliwości ich przeciwdziałaniu. Poprzez przedstawienie możliwych do zastosowania metod ochrony przed wspomnianymi czynnikami dowiedziono, iż możliwości poprawy stanu technicznego, a tym samym standardów funkcjonalnych obiektów zabytkowych jest wiele przy czym należy zachować szczególny szacunek do substancji zabytkowej

  18. Importance of ion bombardment during coverage of Au nanoparticles on their structural features and optical response

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Resta, V.; Peláez, R. J.; Afonso, C. N.

    2014-03-28

    This work studies the changes in the optical response and morphological features of 6 ± 1 nm diameter Au nanoparticles (NPs) when covered by a layer of a-Al{sub 2}O{sub 3} by pulsed laser deposition (PLD). The laser fluence used for ablating the Al{sub 2}O{sub 3} target is varied in order to modify the kinetic energy (KE) of the species bombarding the NPs during their coverage. When the ion KE < 200 eV, the structural features and optical properties of the NPs are close to those of uncovered ones. Otherwise, a shift to the blue and a strong damping of the surface plasmon resonance is observed asmore » fluence is increased. There are two processes responsible for these changes, both related to aluminum ions arriving to the substrate during the coverage process, i.e., sputtering of the metal and implantation of aluminum species in the metal. Both processes have been simulated using standard models for ion bombardment, the calculated effective implanted depths allow explaining the observed changes in the optical response, and the use of a size-dependent sputtering coefficient for the Au NPs predicts the experimental sputtering fractions. In spite of the work is based on PLD, the concepts investigated and conclusions can straightforwardly be extrapolated to other physical vapor deposition techniques or processes involving ion bombardment of metal NPs by ions having KE > 200 eV.« less

  19. Dithallium(III)-Containing 30-Tungsto-4-phosphate, [Tl2Na2(H2O)2(P2W15O56)2]16-: Synthesis, Structural Characterization, and Biological Studies.

    PubMed

    Ayass, Wassim W; Fodor, Tamás; Farkas, Edit; Lin, Zhengguo; Qasim, Hafiz M; Bhattacharya, Saurav; Mougharbel, Ali S; Abdallah, Khaled; Ullrich, Matthias S; Zaib, Sumera; Iqbal, Jamshed; Harangi, Sándor; Szalontai, Gábor; Bányai, István; Zékány, László; Tóth, Imre; Kortz, Ulrich

    2018-06-18

    Here we report on the synthesis and structural characterization of the dithallium(III)-containing 30-tungsto -4-phosphate [Tl 2 Na 2 (H 2 O) 2 {P 2 W 15 O 56 } 2 ] 16- (1) by a multitude of solid-state and solution techniques. Polyanion 1 comprises two octahedrally coordinated Tl 3+ ions sandwiched between two trilacunary {P 2 W 15 } Wells-Dawson fragments and represents only the second structurally characterized, discrete thallium-containing polyoxometalate to date. The two outer positions of the central rhombus are occupied by sodium ions. The title polyanion is solution-stable as shown by 31 P and 203/205 Tl NMR. This was also supported by Tl NMR spectra simulations including several spin systems of isotopologues with half-spin nuclei ( 203 Tl, 205 Tl, 31 P, 183 W). 23 Na NMR showed a time-averaged signal of the Na + counter cations and the structurally bonded Na + ions. 203/205 Tl NMR spectra also showed a minor signal tentatively attributed to the trithallium-containing derivative [Tl 3 Na(H 2 O) 2 (P 2 W 15 O 56 ) 2 ] 14- , which could also be identified in the solid state by single-crystal X-ray diffraction. The bioactivity of polyanion 1 was also tested against bacteria and Leishmania.

  20. Coulomb excitation of the proton-dripline nucleus Na20

    NASA Astrophysics Data System (ADS)

    Schumaker, M. A.; Cline, D.; Hackman, G.; Pearson, C. J.; Svensson, C. E.; Wu, C. Y.; Andreyev, A.; Austin, R. A. E.; Ball, G. C.; Bandyopadhyay, D.; Becker, J. A.; Boston, A. J.; Boston, H. C.; Buchmann, L.; Churchman, R.; Cifarelli, F.; Cooper, R. J.; Cross, D. S.; Dashdorj, D.; Demand, G. A.; Dimmock, M. R.; Drake, T. E.; Finlay, P.; Gallant, A. T.; Garrett, P. E.; Green, K. L.; Grint, A. N.; Grinyer, G. F.; Harkness, L. J.; Hayes, A. B.; Kanungo, R.; Lisetskiy, A. F.; Leach, K. G.; Lee, G.; Maharaj, R.; Martin, J.-P.; Moisan, F.; Morton, A. C.; Mythili, S.; Nelson, L.; Newman, O.; Nolan, P. J.; Orce, J. N.; Padilla-Rodal, E.; Phillips, A. A.; Porter-Peden, M.; Ressler, J. J.; Roy, R.; Ruiz, C.; Sarazin, F.; Scraggs, D. P.; Waddington, J. C.; Wan, J. M.; Whitbeck, A.; Williams, S. J.; Wong, J.

    2009-10-01

    The low-energy structure of the proton dripline nucleus Na20 has been studied using Coulomb excitation at the TRIUMF-ISAC radioactive ion beam facility. A 1.7-MeV/nucleon Na20 beam of ~5×106 ions/s was Coulomb excited by a 0.5-mg/cm2natTi target. Scattered beam and target particles were detected by the BAMBINO segmented Si detector while γ rays were detected by two TIGRESS HPGe clover detectors set perpendicular to the beam axis. Coulomb excitation from the 2+ ground state to the first excited 3+ and 4+ states was observed, and B(λL) values were determined using the 2+→0+ de-excitation in Ti48 as a reference. The resulting B(λL)↓ values are B(E2;3+→2+)=55±6e2fm4 (17.0±1.9 W.u.), B(E2;4+→2+)=35.7±5.7e2fm4 (11.1±1.8 W.u.), and B(M1;4+→3+)=0.154±0.030μN2 (0.086±0.017 W.u.). These measurements provide the first experimental determination of B(λL) values for this proton dripline nucleus of astrophysical interest.

  1. The impact of targeting repetitive BamHI-W sequences on the sensitivity and precision of EBV DNA quantification.

    PubMed

    Sanosyan, Armen; Fayd'herbe de Maudave, Alexis; Bollore, Karine; Zimmermann, Valérie; Foulongne, Vincent; Van de Perre, Philippe; Tuaillon, Edouard

    2017-01-01

    Viral load monitoring and early Epstein-Barr virus (EBV) DNA detection are essential in routine laboratory testing, especially in preemptive management of Post-transplant Lymphoproliferative Disorder. Targeting the repetitive BamHI-W sequence was shown to increase the sensitivity of EBV DNA quantification, but the variability of BamHI-W reiterations was suggested to be a source of quantification bias. We aimed to assess the extent of variability associated with BamHI-W PCR and its impact on the sensitivity of EBV DNA quantification using the 1st WHO international standard, EBV strains and clinical samples. Repetitive BamHI-W- and LMP2 single- sequences were amplified by in-house qPCRs and BXLF-1 sequence by a commercial assay (EBV R-gene™, BioMerieux). Linearity and limits of detection of in-house methods were assessed. The impact of repeated versus single target sequences on EBV DNA quantification precision was tested on B95.8 and Raji cell lines, possessing 11 and 7 copies of the BamHI-W sequence, respectively, and on clinical samples. BamHI-W qPCR demonstrated a lower limit of detection compared to LMP2 qPCR (2.33 log10 versus 3.08 log10 IU/mL; P = 0.0002). BamHI-W qPCR underestimated the EBV DNA load on Raji strain which contained fewer BamHI-W copies than the WHO standard derived from the B95.8 EBV strain (mean bias: - 0.21 log10; 95% CI, -0.54 to 0.12). Comparison of BamHI-W qPCR versus LMP2 and BXLF-1 qPCR showed an acceptable variability between EBV DNA levels in clinical samples with the mean bias being within 0.5 log10 IU/mL EBV DNA, whereas a better quantitative concordance was observed between LMP2 and BXLF-1 assays. Targeting BamHI-W resulted to a higher sensitivity compared to LMP2 but the variable reiterations of BamHI-W segment are associated with higher quantification variability. BamHI-W can be considered for clinical and therapeutic monitoring to detect an early EBV DNA and a dynamic change in viral load.

  2. The impact of targeting repetitive BamHI-W sequences on the sensitivity and precision of EBV DNA quantification

    PubMed Central

    Fayd’herbe de Maudave, Alexis; Bollore, Karine; Zimmermann, Valérie; Foulongne, Vincent; Van de Perre, Philippe; Tuaillon, Edouard

    2017-01-01

    Background Viral load monitoring and early Epstein-Barr virus (EBV) DNA detection are essential in routine laboratory testing, especially in preemptive management of Post-transplant Lymphoproliferative Disorder. Targeting the repetitive BamHI-W sequence was shown to increase the sensitivity of EBV DNA quantification, but the variability of BamHI-W reiterations was suggested to be a source of quantification bias. We aimed to assess the extent of variability associated with BamHI-W PCR and its impact on the sensitivity of EBV DNA quantification using the 1st WHO international standard, EBV strains and clinical samples. Methods Repetitive BamHI-W- and LMP2 single- sequences were amplified by in-house qPCRs and BXLF-1 sequence by a commercial assay (EBV R-gene™, BioMerieux). Linearity and limits of detection of in-house methods were assessed. The impact of repeated versus single target sequences on EBV DNA quantification precision was tested on B95.8 and Raji cell lines, possessing 11 and 7 copies of the BamHI-W sequence, respectively, and on clinical samples. Results BamHI-W qPCR demonstrated a lower limit of detection compared to LMP2 qPCR (2.33 log10 versus 3.08 log10 IU/mL; P = 0.0002). BamHI-W qPCR underestimated the EBV DNA load on Raji strain which contained fewer BamHI-W copies than the WHO standard derived from the B95.8 EBV strain (mean bias: - 0.21 log10; 95% CI, -0.54 to 0.12). Comparison of BamHI-W qPCR versus LMP2 and BXLF-1 qPCR showed an acceptable variability between EBV DNA levels in clinical samples with the mean bias being within 0.5 log10 IU/mL EBV DNA, whereas a better quantitative concordance was observed between LMP2 and BXLF-1 assays. Conclusions Targeting BamHI-W resulted to a higher sensitivity compared to LMP2 but the variable reiterations of BamHI-W segment are associated with higher quantification variability. BamHI-W can be considered for clinical and therapeutic monitoring to detect an early EBV DNA and a dynamic change in viral load

  3. Application of Relevance Maps in Multidimensional Classification of Coal Types / Zastosowanie Map Odniesienia W Wielowymiarowej Klasyfikacji Typów Węgla

    NASA Astrophysics Data System (ADS)

    Niedoba, Tomasz

    2015-03-01

    Multidimensional data visualization methods are a modern tool allowing to classify some analyzed objects. In the case of grained materials e.g. coal, many characteristics have an influence on the material quality. In case of coal, apart from most obvious features like particle size, particle density or ash contents there are many others which cause significant differences between considered types of material. The paper presents the possibility of applying visualization techniques for coal type identification and determination of significant differences between various types of coal. Author decided to apply relevance maps to achieve this purpose. Three types of coal - 31, 34.2 and 35 (according to Polish classification of coal types) were investigated, which were initially screened on sieves and then divided into density fractions. Then, each size-density fraction was chemically analyzed to obtain other characteristics. It was stated that the applied methodology allows to identify certain coal types efficiently and can be used as a qualitative criterion for grained materials. However, it was impossible to achieve such identification comparing all three types of coal together. The presented methodology is new way of analyzing data concerning widely understood mineral processing. Surowce mineralne, które podlegają wzbogacaniu w celu ich lepszego wykorzystania mogą być (charakteryzują się) charakteryzowane wieloma wskaźnikami opisującymi ich, interesujące przeróbkarza, cechy. Podstawowymi cechami są wielkość ziaren oraz ich gęstość, które decydują o przebiegu rozdziału zbiorów ziaren (nadaw) i efektach takiego rozdziału. Rozdział prowadzi się z reguły, w celu uzyskania produktów o zróżnicowanych wartościach średnich wybranej cechy, która zwykle charakteryzowana jest zawartością określonego składnika surowca wyznaczoną na drodze analiz chemicznych. Takie podejście do surowca mineralnego prowadzi do

  4. Liquid lithium target as a high intensity, high energy neutron source

    DOEpatents

    Parkin, Don M.; Dudey, Norman D.

    1976-01-01

    This invention provides a target jet for charged particles. In one embodiment the charged particles are high energy deuterons that bombard the target jet to produce high intensity, high energy neutrons. To this end, deuterons in a vacuum container bombard an endlessly circulating, free-falling, sheet-shaped, copiously flowing, liquid lithium jet that gushes by gravity from a rectangular cross-section vent on the inside of the container means to form a moving web in contact with the inside wall of the vacuum container. The neutrons are produced via break-up of the beam in the target by stripping, spallation and compound nuclear reactions in which the projectiles (deuterons) interact with the target (Li) to produce excited nuclei, which then "boil off" or evaporate a neutron.

  5. Impact of Ion Bombardment on the Structure and Magnetic Properties of Fe78Si13B9 Amorphous Alloy

    NASA Astrophysics Data System (ADS)

    Wu, Yingwei; Peng, Kun

    2018-06-01

    Amorphous Fe78Si13B9 alloy ribbons were bombarded by ion beams with different incident angles ( θ ). The evolution of the microstructure and magnetic properties of ribbons caused by ion beam bombardment was investigated by x-ray diffraction, transmission electron microscope and vibrating sample magnetometer analysis. Low-incident-angle bombardment led to atomic migration in the short range, and high-incident-angle bombardment resulted in the crystallization of amorphous alloys. Ion bombardment induces magnetic anisotropy and affects magnetic properties. The effective magnetic anisotropy was determined by applying the law of approach to saturation, and it increased with the increase of the ion bombardment angle. The introduction of effective magnetic anisotropy will reduce the permeability and increase the relaxation frequency. Excellent high-frequency magnetic properties can be obtained by selecting suitable ion bombardment parameters.

  6. In-situ studies on the micro-structure evolution of A2W2O7 (A=Li, Na, K) during melting by high temperature Raman spectroscopy and density functional theory.

    PubMed

    Wang, Jian; You, Jinglin; Wang, Min; Lu, Liming; Wan, Songming; Sobol, A A

    2017-10-05

    In-situ high temperature Raman spectroscopic (HTRS) technique in combination with density functional theory (DFT) analysis has been adopted to investigate the micro-structure of solid and molten A 2 W 2 O 7 (A=Li, Na, K). The [WO 6 ] octahedra were found to be connected to each other by corner and edge sharing in the crystalline Li 2 W 2 O 7 and K 2 W 2 O 7 compounds. In the crystal lattice of Na 2 W 2 O 7 , on the other hand, the [WO 4 ] tetrahedra and [WO 6 ] octahedra were found to coexist and paired by corner sharing. Although the structural diversity has clearly led to distinct Raman spectra of the crystalline A 2 W 2 O 7 compounds, the spectra of their melts tended to be analogous, showing the typical vibration modes of (W 2 O 7 ) 2- dimer. A mechanism was then proposed to explain the structure evolution occurring during the melting process of A 2 W 2 O 7 . The effect of A + cation on the Raman bands of (W 2 O 7 ) 2- dimer in molten A 2 W 2 O 7 has also been investigated. Both the wavenumber and full width at half-height (FWHH) of the characteristic band assigned to the symmetrical stretching vibration mode of WO nb (non-bridging oxygen) in (W 2 O 7 ) 2- were found to decrease in the sequence of Li + , Na + and K + , indicating the cation effect on the mean bond length and its distribution range of WO nb . In addition, the relative intensity of this band was also influenced by the cation and it was increased in the order of Li 2 W 2 O 7 , Na 2 W 2 O 7 and K 2 W 2 O 7 , which has been explained by the charge transfer process and confirmed by Mulliken overlap population analysis. Copyright © 2017 Elsevier B.V. All rights reserved.

  7. ANALYTICAL MODELING OF ELECTRON BACK-BOMBARDMENT INDUCED CURRENT INCREASE IN UN-GATED THERMIONIC CATHODE RF GUNS

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Edelen, J. P.; Sun, Y.; Harris, J. R.

    In this paper we derive analytical expressions for the output current of an un-gated thermionic cathode RF gun in the presence of back-bombardment heating. We provide a brief overview of back-bombardment theory and discuss comparisons between the analytical back-bombardment predictions and simulation models. We then derive an expression for the output current as a function of the RF repetition rate and discuss relationships between back-bombardment, fieldenhancement, and output current. We discuss in detail the relevant approximations and then provide predictions about how the output current should vary as a function of repetition rate for some given system configurations.

  8. Measurements of production cross sections of 10Be and 26Al by 120 GeV and 392 MeV proton bombardment of 89Y, 159Tb, and natCu targets

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Sekimoto, S.; Okumura, S.; Yashima, H.

    2015-08-12

    The production cross sections of 10Be and 26Al were measured by accelerator mass spectrometry using 89Y, 159Tb, and natCu targets bombarded by protons with energies E p of 120 GeV and 392 MeV. The production cross sections obtained for 10Be and 26Al were compared with those previously reported using E p = 50 MeV–24 GeV and various targets. It was found that the production cross sections of 10Be monotonically increased with increasing target mass number when the proton energy was greater than a few GeV. On the other hand, it was also found that the production cross sections of 10Bemore » decreased as the target mass number increased from that of carbon to those near the mass numbers of nickel and zinc when the proton energy was below approximately 1 GeV. They also increased as the target mass number increased from near those of nickel and zinc to that of bismuth, in the same proton energy range. Similar results were observed in the production cross sections of 26Al, though the absolute values were quite different between 10Be and 26Al. As a result, the difference between these production cross sections may depend on the impact parameter (nuclear radius) and/or the target nucleus stiffness.« less

  9. He + and Ar + bombardment induced chemical changes in CrOSi layers

    NASA Astrophysics Data System (ADS)

    Bertóti, I.; Tóth, A.; Mohai, M.; Kelly, R.; Marletta, G.

    1996-08-01

    The effects of 2 keV He + and Ar + bombardment on the surface composition and on the short range chemical structure of sputter deposited amorphous CrOSi layers (with approx. 1 : 1 : 1 atomic ratio) have been studied by XPS. It was found that Ar + bombardment causes an essentially complete reduction of chromium to metallic state (Cr 0) whereas it was partly oxidized in the as-received sample. At the same time about 30% of the oxidized silicon is converted to Si 0 which is stabilized by forming SiCr bonds. He + bombardment, on the contrary, leads to the disruption of SiCr bonds formed by the preceding Ar + bombardment, converting Cr 0 and Si 0 essentially to Cr 3+O, Cr 4+O and Si 4+O, and, at the same time raises the surface oxygen concentration up to three times of the nominal bulk value. The observed transformations are discussed, in connection with the great differences in energy deposition, in terms of direct energy transfer and of ion induced diffusion, together with a significant contribution from thermodynamic driving forces.

  10. A long-lived tritiated titanium target for fast neutron production

    NASA Astrophysics Data System (ADS)

    Hughey, B. J.

    1995-03-01

    Diagnostic techniques using neutron beams have a broad spectrum of applications in advanced manufacturing, explosives and contraband detection, medicine, and industry. The most suitable nuclear reaction for producing large fluxes of fast neutrons at low bombarding energy is the H(d,n)-3 He-4, i.e. d-T, reaction. The lifetime of currently used d-T neutron generators is limited by the gradual evolution of tritium gas from the target during bombardment. This paper is a report of work in progress to develop a method for inhibiting the replacement of tritium with beam deuterons and thus preventing the evolution of tritium gas leading to reduced neutron yield. It is anticipated that tritiated target lifetime can be increased by at least an order of magnitude by using a range-thin tritiated titanium target mounted on a substrate with a high hydrogen diffusivity, such as niobium. Lifetime can be further enhanced by increasing the deuteron beam bombarding energy from the typical value of 200 keV to 600 keV. The results of experiments demonstrating the effect of hydrogen diffusion coefficient on concentration of implanted beam deuterons in candidate substrate materials (Cu, Pd, and Nb) are presented, and issues relevant to the fabrication of a tritiated titanium target on a niobium substrate are discussed.

  11. Purity of targets prepared on Cu substrates

    NASA Astrophysics Data System (ADS)

    Méens, A.; Rossini, I.; Sens, J. C.

    1993-09-01

    The purity of several elemental self-supporting targets usually prepared by evaporation onto soluble Cu substrates has been studied. The targets were analysed by Rutherford backscattering and instrumental neutron activation analysis. Because of the high percentage of Cu observed in some Si targets, further measurements, including transmission electron microscopy, have been performed on Si targets deposited by e-gun bombardment onto Cu and ion-beam sputtering onto betaine.

  12. Gaussian ancillary bombardment

    NASA Astrophysics Data System (ADS)

    Grimmer, Daniel; Brown, Eric; Kempf, Achim; Mann, Robert B.; Martín-Martínez, Eduardo

    2018-05-01

    We analyze in full detail the time evolution of an open Gaussian quantum system rapidly bombarded by Gaussian ancillae. As a particular case this analysis covers the thermalization (or not) of a harmonic oscillator coupled to a thermal reservoir made of harmonic oscillators. We derive general results for this scenario and apply them to the problem of thermalization. We show that only a particular family of system-environment couplings will cause the system to thermalize to the temperature of its environment. We discuss that if we want to understand thermalization as ensuing from the Markovian interaction of a system with the individual microconstituents of its (thermal) environment then the process of thermalization is not as robust as one might expect.

  13. Precision targeting in guided munition using IR sensor and MmW radar

    NASA Astrophysics Data System (ADS)

    Sreeja, S.; Hablani, H. B.; Arya, H.

    2015-10-01

    Conventional munitions are not guided with sensors and therefore miss the target, particularly if the target is mobile. The miss distance of these munitions can be decreased by incorporating sensors to detect the target and guide the munition during flight. This paper is concerned with a Precision Guided Munition(PGM) equipped with an infrared sensor and a millimeter wave radar [IR and MmW, for short]. Three-dimensional flight of the munition and its pitch and yaw motion models are developed and simulated. The forward and lateral motion of a target tank on the ground is modeled as two independent second-order Gauss-Markov process. To estimate the target location on the ground and the line-of-sight rate to intercept it an Extended Kalman Filter is composed whose state vector consists of cascaded state vectors of missile dynamics and target dynamics. The line-of-sight angle measurement from the infrared seeker is by centroiding the target image in 40 Hz. The centroid estimation of the images in the focal plane is at a frequency of 10 Hz. Every 10 Hz, centroids of four consecutive images are averaged, yielding a time-averaged centroid, implying some measurement delay. The miss distance achieved by including by image processing delays is 1:45m.

  14. Stable transformation via particle bombardment in two different soybean regeneration systems.

    PubMed

    Sato, S; Newell, C; Kolacz, K; Tredo, L; Finer, J; Hinchee, M

    1993-05-01

    The Biolistics(®) particle delivery system for the transformation of soybean (Glycine max L. Merr.) was evaluated in two different regeneration systems. The first system was multiple shoot proliferation from shoot tips obtained from immature zygotic embryos of the cultivar Williams 82, and the second was somatic embryogenesis from a long term proliferative suspension culture of the cultivar Fayette. Bombardment of shoot tips with tungsten particles, coated with precipitated DNA containing the gene for β-glucuronidase (GUS), produced GUS-positive sectors in 30% of the regenerated shoots. However, none of the regenerants which developed into plants continued to produce GUS positive tissue. Bombardment of embryogenic suspension cultures produced GUS positive globular somatic embryos which proliferated into GUS positive somatic embryos and plants. An average of 4 independent transgenic lines were generated per bombarded flask of an embryogenic suspension. Particle bombardment delivered particles into the first two cell layers of either shoot tips or somatic embryos. Histological analysis indicated that shoot organogenesis appeared to involve more than the first two superficial cell layers of a shoot tip, while somatic embryo proliferation occurred from the first cell layer of existing somatic embryos. The different transformation results obtained with these two systems appeared to be directly related to differences in the cell types which were responsible for regeneration and their accessibility to particle penetration.

  15. High energy irradiations simulating cosmic-ray-induced planetary gamma ray production. I - Fe target

    NASA Technical Reports Server (NTRS)

    Metzger, A. E.; Parker, R. H.; Yellin, J.

    1986-01-01

    Two thick Fe targets were bombarded by a series of 6 GeV proton irradiations for the purpose of simulating the cosmic ray bombardment of planetary objects in space. Gamma ray energy spectra were obtained with a germanium solid state detector during the bombardment, and 46 of the gamma ray lines were ascribed to the Fe targets. A comparison between observed and predicted values showed good agreement for Fe lines from neutron inelastic scattering and spallation reactions, and less satisfactory agreement for neutron capture reactions, the latter attributed to the difference in composition between the Fe target and the mean lunar abundance used in the modeling. Through an analysis of the irradiation results together with continuum data obtained in lunar orbit, it was found that 100 hours of measurement with a current instrument should generate a spectrum containing approximately 20 lines due to Fe alone, with a 2-sigma sensitivity for detection of about 0.2 percent.

  16. Step edge sputtering yield at grazing incidence ion bombardment.

    PubMed

    Hansen, Henri; Polop, Celia; Michely, Thomas; Friedrich, Andreas; Urbassek, Herbert M

    2004-06-18

    The surface morphology of Pt(111) was investigated by scanning tunneling microscopy after 5 keV Ar+ ion bombardment at grazing incidence in dependence of the ion fluence and in the temperature range between 625 and 720 K. The average erosion rate was found to be strongly dependent on the ion fluence and the substrate temperature during bombardment. This dependence is traced back to the variation of step concentration with temperature and fluence. We develop a simple model allowing us to determine separately the constant sputtering yields for terraces and for impact area stripes in front of ascending steps. The experimentally determined yield of these stripes--the step-edge sputtering yield--is in excellent agreement with our molecular dynamics simulations performed for the experimental situation.

  17. Experimental Investigation of Neutral Species from Micrometeoroid Bombardment

    NASA Astrophysics Data System (ADS)

    Collette, A.; Sternovsky, Z.; Rocha, J. R.; Munsat, T. L.; Horanyi, M.

    2014-12-01

    Surface-boundary exospheres exist in a balance between source and loss processes. An important area of uncertainty, highlighted by the MESSENGER observations of Mg and Ca at Mercury, and the recently concluded LADEE observations at the Moon, is the role of micrometeoroid bombardment as a source process for liberating surface species. Unlike sputtering or photon stimulated desorption processes, the physics of micrometeoroid impacts are still poorly understood; in particular, no comprehensive model exists to predict partitioning of impact products between ejecta fragments, charged particles, and neutrals. We present initial experiments at the IMPACT dust accelerator facility (University of Colorado Boulder) aimed at directly measuring the fraction of neutral species liberated in micrometeoroid impacts. Simulated micrometeoroids (micron- and submicron-sized iron spheres) are fired at targets containing refractory elements, including fused silica (SiO2), sapphire (Al2O3), and magnesium fluoride (MgF2). Total quantities of specific impact-generated neutral species are measured using a mass spectrometer, as a function of impactor speed and mass, and compared with well-established scaling laws for charged particle production.

  18. Effects of low and high energy ion bombardment on ETFE polymer

    NASA Astrophysics Data System (ADS)

    Minamisawa, R. A.; De Almeida, A.; Abidzina, V.; Parada, M. A.; Muntele, I.; Ila, D.

    2007-04-01

    The polymer ethylenetetrafluoroethylene (ETFE) is used as anti-adherent coatings for food packages and radiation dosimeters. In this work, we compare the damage induced in ETFE bombarded with 100 keV Si ions with that induced by 1 MeV proton bombardment. The damage depends on the type, energy and intensity of the irradiation. Irradiated films were analyzed with optical absorption photospectrometry, Raman spectroscopy and Fourier transform infrared (FTIR) spectroscopy to determine the chemical nature of the structural changes caused by ion irradiation. Computer simulations were performed to evaluate the radiation damage.

  19. Antiphase boundaries on low-energy-ion bombarded Ge(001)

    NASA Astrophysics Data System (ADS)

    Zandvliet, H. J. W.; de Groot, E.

    1997-01-01

    Surface vacancy and adatom clusters have been created on Ge(001) by bombarding the surface with 800 eV argon ions at various substrate temperatures ranging from room temperature to 600 K. The vacancies preferentially annihilate at the ends rather than at the sides of the dimer rows, resulting in monolayer deep vacancy islands which are elongated in a direction of the dimer rows of the upper terrace. As vacancy islands nucleate and expand, the dimer rows in neighbouring vacancy islands need not, in general, align with each other. An antiphase boundary will develop if two growing vacancy islands meet, but their internal dimer rows are not in the same registry. In contrast to Si(001), where only one type of antiphase boundary is found, we have found three different types of antiphase boundaries on Ge(001). Higher dose (> several monolayers) room temperature ion bombardment followed by annealing at temperatures in the range 400-500 K results in a surface which contains a high density of valleys. In addition to the preference for the annihilation of dimer vacancies at descending versus ascending steps we also suggest that the development of antiphase boundaries drives the roughening of this surface. Finally, several atomic rearrangement events, which might be induced by the tunneling process, are observed after low-dose ion bombardment at room temperature.

  20. The Assessment of Susceptibility on Drainage in an Aquifer on the Basis of Pumping Tests in a Lignite Mine / Ocena Podatności Ośrodka Wodonośnego Na Odwodnienie Na Podstawie Próbnych Pompowań W Kopalni Węgla Brunatnego

    NASA Astrophysics Data System (ADS)

    Polak, Krzysztof; Kaznowska-Opala, Karolina; Pawlecka, Katarzyna; Różkowski, Kazimierz; Klich, Jerzy

    2015-03-01

    ężystej S, pozwala na wyznaczenie najbardziej korzystnych warunków eksploatacji studni. Wspomniane parametry hydrogeologiczne są składowymi równania opisującego hydrauliczną oporność ośrodka wodonośnego (12). Uogólniając, parametr B, może być kryterium wykorzystanym przy planowaniu i projektowaniu systemu odwodnienia studziennego, a także bieżącej oceny skuteczności współpracy systemu. Na rysunku 3. przedstawiono ideowo metodykę oznaczania tego parametru, za pomocą testu próbnego pompowania. Dotychczas interpretacja wyników próbnych pompowań koncentrowała się na ocenie technicznych warunków pracy otworów studziennych. W tym celu wykorzystywano współczynnik C występujący we wzorze Jacoba, który stanowił kryterium odbioru studni od wykonawcy. Zdaniem autorów niniejszej pracy wyniki próbnych pompowań należy interpretować w szerszym ujęciu, zwracając uwagę na parametr B, opisujący oporność hydrauliczną przy przepływie laminarnym wody w ośrodku wodonośnym. Analiza rozkładu przestrzennego zmian tego parametru pozwala na racjonalizację systemu odwodnienia studziennego w tym ocenę niezbędnych wyprzedzeń w zakresie wykonawstwa studni. W praktyce, ocenę geohydraulicznych warunków prowadzonego odwodnienia przeprowadzono przy wykorzystaniu zmodyfikowanej metody próbnych pompowań wielostopniowych opracowanych przez Klicha (1997). W pracy niniejszej przedstawiono wyniki próbnych pompowań w 27 studniach pracujących w kopalni odkrywkowej węgla brunatnego. Na rysunkach 5-9 przedstawiono wyniki oceny parametru B dla podstawowych kompleksów wodonośnych, dla których wykonano próbne pompowania badawcze. Podział wykresów wynika z przeznaczenia studni, co odpowiada podziałowi przedstawionemu na rysunku 4. Uzyskane wyniki pozwalają na sformułowanie wstępnych uogólnień. W tabeli 1. zaproponowano wstępną klasyfikację podatności ośrodka wodonośnego na prowadzone odwodnienie. Klasyfikacja może być wykorzystana do celów

  1. Evidence Supporting an Early as Well as Late Heavy Bombardment on the Moon

    NASA Technical Reports Server (NTRS)

    Frey, Herbert

    2015-01-01

    Evidence supporting an intense early bombardment on the Moon in addition to the traditional Late Heavy Bombardment at approx. 4 BY ago include the distribution of N(50) Crater Retention Ages (CRAs) for candidate basins, a variety of absolute age scenarios for both a "young" and an "old" Nectaris age, and the decreasing contrasts in both topographic relief and Bouguer gravity with increasing CRA.

  2. Microprojectile Bombardment Transformation of Date Palm Using the Insecticidal Cholesterol Oxidase (ChoA) Gene.

    PubMed

    Allam, Mai A; Saker, Mahmoud M

    2017-01-01

    The overall objective of this work is to optimize the transformation system for date palm as a first step toward production of date palm clones resistant to noxious pests. A construct harboring the cholesterol oxidase (ChoA) gene, which renders plant resistance against insect attack, is introduced into embryogenic date palm callus using the PDS-1000/He particle bombardment system. The process involves the establishment of embryogenic callus cultures as well as immature embryo-derived microcalli that are used as target tissues for shooting and optimization of transformation conditions. This chapter in addition explains molecular and histochemical assays conducted to confirm gene integration and expression.

  3. Fertile-to-fissile and fission measurements for depleted uranium bombarded by 800-MeV protons

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Russell, G.J.; Gilmore, J.S.; Robinson, H.

    Axial distributions of fertile-to-fissile conversions (/sup 238/U to /sup 239/Pu) and fissions have been measured for a thick depleted uranium target bombarded by 800-MeV protons. The /sup 239/Pu production was determined by measuring the amount of /sup 239/Np produced. The axial distributions were integrated to get the total conversions and fissions occurring in the target. Preliminary experimental results give 3.81 +- 0.19 /sup 239/Np atoms produced per incident proton and 5.59 +- 0.56 fissions per incident proton. Corresponding calculated results are 3.46 +- 0.05 and 3.93 +- 0.06. The computations did not include the effects of high-energy fission competition withmore » evaporation. Measured axial disributions of /sup 237/U and eleven fission products produced in the target are reported. Preliminary experimental data give 0.95 +- 0.05 /sup 237/U atoms made per incident proton.« less

  4. CO adsorption on ion bombarded Ni(111): characterization by photoemission from adsorbed xenon

    NASA Astrophysics Data System (ADS)

    Fu, Sabrina S.; Malafsky, Geoffrey P.; Hsu, David S. Y.

    1993-11-01

    The adsorption of CO on Ni(111), ion bombarded with various fluences of 1.0 keV Ar + ions, has been investigated using photoemission from adsorbed xenon (PAX). After ion bombardment of the Ni(111) surface, various amounts of CO were adsorbed, followed by adsorption of xenon at 85 K. Two pressures of xenon were used in examining the 3d {5}/{2} peak of xenon: 5 × 10 -6 and 7 × 10 -10 Torr. PAX data taken at both pressures show that CO selectively adsorbs onto the defect (step) sites created by ion bombardment. In addition, it was found that the amount of CO which could occupy a defect site previously occupied by one Xe atom varied from 10 to 2.5, depending on the ion fluence.

  5. HCN Production via Impact Ejecta Reentry During the Late Heavy Bombardment

    NASA Astrophysics Data System (ADS)

    Parkos, Devon; Pikus, Aaron; Alexeenko, Alina; Melosh, H. Jay

    2018-04-01

    Major impact events have shaped the Earth as we know it. The Late Heavy Bombardment is of particular interest because it immediately precedes the first evidence of life. The reentry of impact ejecta creates numerous chemical by-products, including biotic precursors such as HCN. This work examines the production of HCN during the Late Heavy Bombardment in more detail. We stochastically simulate the range of impacts on the early Earth and use models developed from existing studies to predict the corresponding ejecta properties. Using multiphase flow methods and finite-rate equilibrium chemistry, we then find the HCN production due to the resulting atmospheric heating. We use Direct Simulation Monte Carlo to develop a correction factor to account for increased yields due to thermochemical nonequilibrium. We then model 1-D atmospheric turbulent diffusion to find the time accurate transport of HCN to lower altitudes and ultimately surface water. Existing works estimate the necessary HCN molarity threshold to promote polymerization that is 0.01 M. For a mixing depth of 100 m, we find that the Late Heavy Bombardment will produce at least one impact event above this threshold with probability 24.1% for an oxidized atmosphere and 56.3% for a partially reduced atmosphere. For a mixing depth of 10 m, the probability is 79.5% for an oxidized atmosphere and 96.9% for a partially reduced atmosphere. Therefore, Late Heavy Bombardment impact ejecta is likely an HCN source sufficient for polymerization in shallow bodies of water, particularly if the atmosphere were in a partially reduced state.

  6. Ion-bombardment of nickel (110) at elevated temperature

    NASA Astrophysics Data System (ADS)

    Peddinti, Vijay Kumar

    The goal of this thesis is to study the behavior of ion-induced defects at the Y point on the Ni (110) surface at elevated temperatures. The electronic structure of the surface is examined using inverse photoemission spectroscopy (IPES), and the geometric structure is observed using low energy electron diffraction (LEED). These measurements lead to a better understanding of the surface properties. The clean Ni (110) surface exhibits a peak ˜ 2.6 eV above the Fermi level, indicating an unoccupied surface state near the Y point of the surface Brillouin zone (SBZ). Defects are induced by low energy ion bombardment at various temperatures, which result in a decrease of the peak intensity. The surface state eventually disappears when bombarded for longer times. We also observed that the surface heals faster when the crystal is being simultaneously sputtered and annealed at higher versus lower temperature. Finally the data for annealing while sputtering versus annealing after sputtering does not seem to exhibit much difference.

  7. MRPrimerW: a tool for rapid design of valid high-quality primers for multiple target qPCR experiments

    PubMed Central

    Kim, Hyerin; Kang, NaNa; An, KyuHyeon; Koo, JaeHyung; Kim, Min-Soo

    2016-01-01

    Design of high-quality primers for multiple target sequences is essential for qPCR experiments, but is challenging due to the need to consider both homology tests on off-target sequences and the same stringent filtering constraints on the primers. Existing web servers for primer design have major drawbacks, including requiring the use of BLAST-like tools for homology tests, lack of support for ranking of primers, TaqMan probes and simultaneous design of primers against multiple targets. Due to the large-scale computational overhead, the few web servers supporting homology tests use heuristic approaches or perform homology tests within a limited scope. Here, we describe the MRPrimerW, which performs complete homology testing, supports batch design of primers for multi-target qPCR experiments, supports design of TaqMan probes and ranks the resulting primers to return the top-1 best primers to the user. To ensure high accuracy, we adopted the core algorithm of a previously reported MapReduce-based method, MRPrimer, but completely redesigned it to allow users to receive query results quickly in a web interface, without requiring a MapReduce cluster or a long computation. MRPrimerW provides primer design services and a complete set of 341 963 135 in silico validated primers covering 99% of human and mouse genes. Free access: http://MRPrimerW.com. PMID:27154272

  8. Erosion and modification of SO2 ice by ion bombardment of the surface of Io

    NASA Technical Reports Server (NTRS)

    Johnson, R. E.; Garrett, J. W.; Boring, J. W.; Barton, L. A.; Brown, W. L.

    1984-01-01

    New measurements on the effect of slow ion bombardment of SO2 ice using Ar(+) in the 15-45 keV range are presented. Total yields for loss of SO2 are given along with the energy spectra of the ejected molecules and molecular fragments and information on the chemical changes induced by the ion bombardment. These data are used to estimate that the direct sputter ejection rate of sulfur into the Jovian plasma is of the order of 10 billion atoms/sq cm/s, that the erosion rate of fresh SO2 deposits due to sputtering is of the order of 0.001 cm/yr, and that a significant and possibly observable column density of SO3 can be produced in an SO2 front only for penetrating ion bombardment. Chemical activity occurs even in rather low-temperature SO2 ice bombardment by ions in the nuclear stopping region, and this activity is likely to increase with increasing temperature.

  9. Fertile-to-fissile and fission measurements for depleted uranium and thorium bombarded by 800-MeV protons

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Gilmore, J.S.; Russell, G.J.; Robinson, H.

    Axial distributions of fissions and of fertile-to-fissile conversions in thick depleted uranium and thorium targets bombarded by 800-MeV protons have been measured. The amounts of /sup 239/Pu and /sup 233/U produced were determined by measuring the yields of /sup 239/Np and /sup 233/Pa, respectively. The number of fissions was deduced from fission product mass-yield curves. Integration of the axial distributions gave the total number of conversions and fissions occurring in the targets. For the uranium target, experimental results were 5.90 +- 0.25 fissions and 3.81 +- 0.01 atoms of /sup 239/Pu produced per incident portion. Corresponding calculated results were 6.14more » +- 0.04 and 3.88 +- 0.03. In the thorium target, 1.56 +- 0.25 fissions and 1.25 +- 0.01 atoms of /sup 233/U per incident proton were measured; the calculated values were 1.54 +- 0.01 fissions and 1.27 +- 0.01 atom/proton.« less

  10. Differences between naïve and expert observers’ vergence and accommodative responses to a range of targets

    PubMed Central

    Horwood, Anna M; Riddell, Patricia M

    2015-01-01

    Purpose Vergence and accommodation studies often use adult participants with experience of vision science. Reports of infant and clinical responses are generally more variable and of lower gain, with the implication that differences lie in immaturity or sub-optimal clinical characteristics but expert /naïve differences are rarely considered or quantified. Methods Sixteen undergraduates, naïve to vision science were individually matched by age, visual acuity, refractive error, heterophoria, stereoacuity and near point of accommodation to 2nd & 3rd year orthoptics and optometry undergraduates (“experts”). Accommodation and vergence responses were assessed to targets moving between 33cm, 50 cm, 1m and 2m using a haploscopic device incorporating a PlusoptiX SO4 autorefractor. Disparity, blur and looming cues were separately available or minimised in all combinations. Instruction set was minimal. Results In all cases, vergence and accommodation response slopes (gain) were steeper and closer to 1.0 in the expert group (p=0.001), with the largest expert /naïve differences for both vergence and accommodation being for near targets (p=0.012). For vergence, the differences between expert and naïve response slopes increased with increasingly open-loop targets (linear trend p=0.025). Although we predicted that proximal cues would drive additional response in the experts, the proximity-only cue was the only condition that showed no statistical effect of experience. Conclusions Expert observers provide more accurate responses to near target demand than closely matched naïve observers. We suggest that attention, practice, voluntary and proprioceptive effects may enhance responses in experienced participants when compared to a more typical general population. Differences between adult reports and the developmental and clinical literature may partially reflect expert / naïve effects, as well as developmental change. If developmental and clinical studies are to be compared

  11. Maximum propellant utilization in an electron bombardment thruster

    NASA Technical Reports Server (NTRS)

    Kaufman, H. R.; Cohen, A. J.

    1971-01-01

    Current theory and experimental data on propellant utilization in electron bombardment ion thrusters are reviewed. Because the majority of investigations have been conducted with mercury, the presentation emphasizes that propellant. The results are presented in as general a form as possible to facilitate use in areas other than space propulsion.

  12. Functionalized NaA nanozeolites labeled with 224,225Ra for targeted alpha therapy.

    PubMed

    Piotrowska, Agata; Leszczuk, Edyta; Bruchertseifer, Frank; Morgenstern, Alfred; Bilewicz, Aleksander

    2013-01-01

    The 223 Ra, 224 Ra, and 225 Ra radioisotopes exhibit very attractive nuclear properties for application in radionuclide therapy. Unfortunately the lack of appropriate bifunctional ligand for radium is the reason why these radionuclides have not found application in receptor-targeted therapy. In the present work, the potential usefulness of the NaA nanozeolite as a carrier for radium radionuclides has been studied. 224 Ra and 225 Ra, α-particle emitting radionuclides, have been absorbed in the nanometer-sized NaA zeolite (30-70 nm) through simple ion exchange. 224,225 Ra-nanozeolites exhibited very high stability in solutions containing physiological salt, EDTA, amino acids, and human serum. To make NaA nanozeolite particles dispersed in water their surface was modified with a silane coupling agent containing poly(ethylene glycol) molecules. This functionalization approach let us covalently attach a biomolecule to the NaA nanozeolite surface.

  13. The Impact of the Estimation of the Parameters Values on the Accuracy of Predicting the Impacts of Mining Exploitation / Wpływ Oszacowania Wartości Parametrów Modelu Na Dokładność Prognozowania Wpływów Eksploatacji Górniczej

    NASA Astrophysics Data System (ADS)

    Niedojadło, Zygmunt; Gruszczyński, Wojciech

    2015-03-01

    The possibility of the assessment of the probability that the acceptable values of deformation indexes will be exceeded and the introduction of the coefficient of safety are more and more seriously considered in case of predicting the impacts of exploitation both on the surface and the shaft tube. This article presents the mentioned above issue focusing on the authors' project of the exploitation in the protective pillars of the shafts of the Legnica and Głogów Copper Area (LGOM). To assess the accuracy of the predicted deformation indexes Monte Carlo method (often used in statistics) was proposed as well as the strict and approximate analysis using the law of error propagation. The values of vertical strains were analysed, as the most important at the assessment of the state of deformation of the shaft tube. The comparison of the results obtained with different methods confirmed the correctness of the carried out calculations. The applied methods allowed the analysis of the impact of individual parameters of the model on the prediction of the accuracy of forecast. This article makes the continuation of the solutions of the article (Niedojadło & Gruszczyński, 2010) thus some contents essential for the continuity of understanding were repeated here. Możliwość oceny prawdopodobieństwa przekroczenia dopuszczalnych wartości wskaźników deformacji oraz wprowadzenie współczynnika bezpieczeństwa coraz częściej są brane pod uwagę w przypadku prognozowania wpływów eksploatacji tak na powierzchnię jak i rurę szybową. W niniejszym artykule przedstawiono powyższe zagadnienie na przykładzie autorskiego projektu eksploatacji w filarach ochronnych szybów LGOM. Do oceny dokładności prognozowanych wskaźników deformacji zaproponowano wykorzystywaną w statystyce metodę Monte Carlo oraz analizę ścisłą i przybliżoną wykorzystującą prawo przenoszenia się błędów średnich. Analizowano wartości odkształceń pionowych

  14. Improvement in reduced-mode (REM) diodes enable 315 W from 105-μm 0.15-NA fiber-coupled modules

    NASA Astrophysics Data System (ADS)

    Kanskar, M.; Bao, L.; Chen, Z.; Dawson, D.; DeVito, M.; Dong, W.; Grimshaw, M.; Guan, X.; Hemenway, M.; Martinsen, R.; Urbanek, W.; Zhang, S.

    2018-02-01

    High-power, high-brightness diode lasers have been pursued for many applications including fiber laser pumping, materials processing, solid-state laser pumping, and consumer electronics manufacturing. In particular, 915 nm - and 976 nm diodes are of interest as diode pumps for the kilowatt CW fiber lasers. As a result, there have been many technical thrusts for driving the diode lasers to have both high power and high brightness to achieve high-performance and reduced manufacturing costs. This paper presents our continued progress in the development of high brightness fiber-coupled product platform, nLIGHT element®. In the past decade, the power coupled into a single 105 μm and 0.15 NA fiber has increased by over a factor of ten through improved diode laser brightness and the development of techniques for efficiently coupling multiple emitters. In this paper, we demonstrate further brightness improvement and power-scaling enabled by both the rise in chip brightness/power and the increase in number of chips coupled into a given numerical aperture. We report a new chip technology using x-REM design with brightness as high as 4.3 W/mm-mrad at a BPP of 3 mm-mrad. We also report record 315 W output from a 2×12 nLIGHT element with 105 μm diameter fiber using x-REM diodes and these diodes will allow next generation of fiber-coupled product capable of 250W output power from 105 μm/0.15 NA beam at 915 nm.

  15. MRPrimerW: a tool for rapid design of valid high-quality primers for multiple target qPCR experiments.

    PubMed

    Kim, Hyerin; Kang, NaNa; An, KyuHyeon; Koo, JaeHyung; Kim, Min-Soo

    2016-07-08

    Design of high-quality primers for multiple target sequences is essential for qPCR experiments, but is challenging due to the need to consider both homology tests on off-target sequences and the same stringent filtering constraints on the primers. Existing web servers for primer design have major drawbacks, including requiring the use of BLAST-like tools for homology tests, lack of support for ranking of primers, TaqMan probes and simultaneous design of primers against multiple targets. Due to the large-scale computational overhead, the few web servers supporting homology tests use heuristic approaches or perform homology tests within a limited scope. Here, we describe the MRPrimerW, which performs complete homology testing, supports batch design of primers for multi-target qPCR experiments, supports design of TaqMan probes and ranks the resulting primers to return the top-1 best primers to the user. To ensure high accuracy, we adopted the core algorithm of a previously reported MapReduce-based method, MRPrimer, but completely redesigned it to allow users to receive query results quickly in a web interface, without requiring a MapReduce cluster or a long computation. MRPrimerW provides primer design services and a complete set of 341 963 135 in silico validated primers covering 99% of human and mouse genes. Free access: http://MRPrimerW.com. © The Author(s) 2016. Published by Oxford University Press on behalf of Nucleic Acids Research.

  16. Pico-level DNA sensing by hetero-polymetalate, Na10{Dy2W10O30(µ-S)6}·80H2O, cluster

    NASA Astrophysics Data System (ADS)

    Dutta, Taposhree; Ganguly, Jhuma; Sarkar, Sabyasachi

    2018-04-01

    The polyoxometalate dysprosium cluster, (Dy-S-W POM) , Na10[Dy2W10O30(µ-S)6]·80H2O, shows remarkable dsDNA denaturation property. In the presence of 0.22 µmol of this Dy-S-W POM, the melting temperature (Tm) of calf-thymus (CT) dsDNA is decreased to 62.35 °C. Dy-S-W POM shows bleaching of methylene blue (MB). Addition of CT-DNA in the MB bleached solution of Dy-S-W POM apparently intercalates MB. Such trapped MB by CT-DNA responds to its re-oxidation by elemental sulfur formed in the bleaching process involving Dy-S-W POM. This reduction-oxidation property of MB with Dy-S-W POM led to the detection of pico (13.20 pmol) level of DNA even by naked eye, which will be helpful for rapid trace DNA detection in forensic science and DNA-related diagnostics, complimenting time-consuming sophisticated methodology.

  17. Search for unbound nuclides and beam/fragment optics with the MoNA/LISA segmented target at NSCL

    NASA Astrophysics Data System (ADS)

    Gueye, Paul; Frank, Nathan; Thoennessen, Michael; Redpath, Thomas; MoNA Collaboration

    2017-09-01

    A multi-layered Si/Be segmented target consisting of three 700 mg/cm2 thick Be9 slabs and four 140 microns Si detectors was used by the MoNA Collaboration at the National Superconducting Cyclotron Laboratory of Michigan State University to study the O26 lifetime. This target provides unprecedented information on the incident beams and fragments (energy loss and position), thus allowing for better determination of the incident and outgoing energies and momenta of the detected particles compare to previous experiments conducted at this facility. With the availability of a newly developed Geant4 Monte Carlo simulation of the full N2 vault, we will present and discuss the performances of this target. Search for unbound nuclides and beam/fragment optics with the MoNA/LISA segmented target at NSCL.

  18. A monoclonal antibody that targets a NaV1.7 channel voltage sensor for pain and itch relief

    PubMed Central

    Lee, Jun-Ho; Park, Chul-Kyu; Chen, Gang; Han, Qingjian; Xie, Rou-Gang; Liu, Tong; Ji, Ru-Rong; Lee, Seok-Yong

    2014-01-01

    Summary Voltage-gated sodium (NaV) channels control the upstroke of the action potentials in excitable cells. Multiple studies have shown distinct roles of NaV channel subtypes in human physiology and diseases, but subtype-specific therapeutics are lacking and the current efforts have been limited to small molecules. Here we present a monoclonal antibody that targets the voltage-sensor paddle of NaV1.7, the subtype critical for pain sensation. This antibody not only inhibits NaV1.7 with high selectivity but also effectively suppresses inflammatory and neuropathic pain in mice. Interestingly, the antibody inhibits acute and chronic itch, despite well-documented differences in pain and itch modulation. Using this antibody, we discovered that NaV1.7 plays a key role in spinal cord nociceptive and pruriceptive synaptic transmission. Our studies reveal that NaV1.7 is a target for itch management and the antibody has therapeutic potential for suppressing pain and itch. Our antibody strategy may have broad applications for voltage-gated cation channels. PMID:24856969

  19. Determining Acceptable Explosive Charge Mass Under Different Geological Conditions / Problematyka Wyznaczania Dopuszczalnych Ładunków Mw W Zróżnicowanych Warunkach Geologicznych

    NASA Astrophysics Data System (ADS)

    Pyra, Józef; Sołtys, Anna; Winzer, Jan; Dworzak, Michał; Biessikirski, Andrzej

    2015-09-01

    This article presents a procedure for determining the safety of explosive charges for their surrounding environment, using a limestone mine as a case study. Varied geological structures, as well as other constructions in the surrounding area of a mine, sometimes necessitate the use of two or more ground vibration propagation equations, and thus a variety of explosive charges, depending on the area of rock blasting. This is a crucial issue for the contractor, as it is important to blast the rock as few times as possible, while using the maximum amount of explosive charge for each blast. Wykonywanie robót strzałowych w górnictwie polega na odpalaniu mas materiału wybuchowego (MW) celem uzyskania dużej ilości odpowiednio rozdrobnionego urobku. W momencie zwiększonego popytu na surowce skalne zakłady górnicze zmuszone są do zwielokrotnienia wykonywania prac strzałowych aby zapewnić regularne dostawy produktu. Konsekwencją takich działań jest ponoszenie dodatkowych kosztów operacyjnych. Celem ich minimalizacji oraz uzyskania jak największej efektywności prowadzonych robót strzałowych jest wydłużanie serii, a więc stosowanie coraz to większych mas ładunków materiałów wybuchowych. Efektem takiego postępowanie jest możliwość wystąpienia w otoczeniu oddziaływania o potencjalnie szkodliwym charakterze m. in. drgania parasejsmiczne. Aby wyeliminować powyższy problem oraz zapewnić niezbędny komfort mieszkańcom, Prawo geologiczne i górnicze, Prawo ochrony środowiska i rozporządzenia wykonawcze nakładają na podmiot wykonujący roboty strzałowe obowiązek ochrony otoczenia, poprzez prowadzenie działalności profilaktycznej w zakresie kontroli, monitorowania oraz wyznaczania dopuszczalnych mas ładunków MW. W momencie gdy nie ma możliwości ograniczenia niepożądanych wpływów dynamicznych po przez zmianę parametrów siatki strzałowej czy modyfikację struktury czasowo-częstotliwościowej drgań, jedyną możliwością staje si

  20. Confirming the key role of Ar+ ion bombardment in the growth feature of nanostructured carbon materials by PECVD

    NASA Astrophysics Data System (ADS)

    Liu, Yulin; Lin, Jinghuang; Jia, Henan; Chen, Shulin; Qi, Junlei; Qu, Chaoqun; Cao, Jian; Feng, Jicai; Fei, Weidong

    2017-11-01

    In order to confirm the key role of Ar+ ion bombardment in the growth feature of nanostructured carbon materials (NCMs), here we report a novel strategy to create different Ar+ ion states in situ in plasma enhanced chemical vapor deposition (PECVD) by separating catalyst film from the substrate. Different bombardment environments on either side of the catalyst film were created simultaneously to achieve multi-layered structural NCMs. Results showed that Ar+ ion bombardment is crucial and complex for the growth of NCMs. Firstly, Ar+ ion bombardment has both positive and negative effects on carbon nanotubes (CNTs). On one hand, Ar+ ions can break up the graphic structure of CNTs and suppress thin CNT nucleation and growth. On the other hand, Ar+ ion bombardment can remove redundant carbon layers on the surface of large catalyst particles which is essential for thick CNTs. As a result, the diameter of the CNTs depends on the Ar+ ion state. As for vertically oriented few-layer graphene (VFG), Ar+ ions are essential and can even convert the CNTs into VFG. Therefore, by combining with the catalyst separation method, specific or multi-layered structural NCMs can be obtained by PECVD only by changing the intensity of Ar+ ion bombardment, and these special NCMs are promising in many fields.

  1. Confirming the key role of Ar+ ion bombardment in the growth feature of nanostructured carbon materials by PECVD.

    PubMed

    Liu, Yulin; Lin, Jinghuang; Jia, Henan; Chen, Shulin; Qi, Junlei; Qu, Chaoqun; Cao, Jian; Feng, Jicai; Fei, Weidong

    2017-11-24

    In order to confirm the key role of Ar + ion bombardment in the growth feature of nanostructured carbon materials (NCMs), here we report a novel strategy to create different Ar + ion states in situ in plasma enhanced chemical vapor deposition (PECVD) by separating catalyst film from the substrate. Different bombardment environments on either side of the catalyst film were created simultaneously to achieve multi-layered structural NCMs. Results showed that Ar + ion bombardment is crucial and complex for the growth of NCMs. Firstly, Ar + ion bombardment has both positive and negative effects on carbon nanotubes (CNTs). On one hand, Ar + ions can break up the graphic structure of CNTs and suppress thin CNT nucleation and growth. On the other hand, Ar + ion bombardment can remove redundant carbon layers on the surface of large catalyst particles which is essential for thick CNTs. As a result, the diameter of the CNTs depends on the Ar + ion state. As for vertically oriented few-layer graphene (VFG), Ar + ions are essential and can even convert the CNTs into VFG. Therefore, by combining with the catalyst separation method, specific or multi-layered structural NCMs can be obtained by PECVD only by changing the intensity of Ar + ion bombardment, and these special NCMs are promising in many fields.

  2. Alteration of the UV-visible reflectance spectra of H2O ice by ion bombardment

    NASA Technical Reports Server (NTRS)

    Sack, N. J.; Boring, J. W.; Johnson, R. E.; Baragiola, R. A.; Shi, M.

    1991-01-01

    Satellite in the Jovian and Saturnian system exhibit differences in reflectivity between their 'leading' and 'trailing' surfaces which can affect the local vapor pressure. Since these differences are thought to be due to differences in the flux of bombarding magnetospheric ions, the influence of ion impact on the UV-visible reflectance of water ice surfaces (20-90 K) by keV ion bombardment was studied. An observed decrease in reflectance in the UV is attributed to rearrangement processes that affect the physical microstructure and surface 'roughness'. The ratio in reflectance of bombarded to freshly deposited films is compared to the ratio of the reflectance of the leading and trailing hemispheres for Europa and Ganymede.

  3. Direct thermal effects of the Hadean bombardment did not limit early subsurface habitability

    NASA Astrophysics Data System (ADS)

    Grimm, R. E.; Marchi, S.

    2018-03-01

    Intense bombardment is considered characteristic of the Hadean and early Archean eons, yet some detrital zircons indicate that near-surface water was present and thus at least intervals of clement conditions may have existed. We investigate the habitability of the top few kilometers of the subsurface by updating a prior approach to thermal evolution of the crust due to impact heating, using a revised bombardment history, a more accurate thermal model, and treatment of melt sheets from large projectiles (>100 km diameter). We find that subsurface habitable volume grows nearly continuously throughout the Hadean and early Archean (4.5-3.5 Ga) because impact heat is dissipated rapidly compared to the total duration and waning strength of the bombardment. Global sterilization was only achieved using an order of magnitude more projectiles in 1/10 the time. Melt sheets from large projectiles can completely resurface the Earth several times prior to ∼4.2 Ga but at most once since then. Even in the Hadean, melt sheets have little effect on habitability because cooling times are short compared to resurfacing intervals, allowing subsurface biospheres to be locally re-established by groundwater infiltration between major impacts. Therefore the subsurface is always habitable somewhere, and production of global steam or silicate-vapor atmospheres are the only remaining avenues to early surface sterilization by bombardment.

  4. Coulomb excitation of radioactive Na21 and its stable mirror Ne21

    NASA Astrophysics Data System (ADS)

    Schumaker, M. A.; Cline, D.; Hackman, G.; Morton, A. C.; Pearson, C. J.; Svensson, C. E.; Wu, C. Y.; Andreyev, A.; Austin, R. A. E.; Ball, G. C.; Bandyopadhyay, D.; Becker, J. A.; Boston, A. J.; Boston, H. C.; Buchmann, L.; Churchman, R.; Cifarelli, F.; Cooper, R. J.; Cross, D. S.; Dashdorj, D.; Demand, G. A.; Dimmock, M. R.; Drake, T. E.; Finlay, P.; Gallant, A. T.; Garrett, P. E.; Green, K. L.; Grint, A. N.; Grinyer, G. F.; Harkness, L. J.; Hayes, A. B.; Kanungo, R.; Leach, K. G.; Lee, G.; Maharaj, R.; Martin, J.-P.; Moisan, F.; Mythili, S.; Nelson, L.; Newman, O.; Nolan, P. J.; Orce, J. N.; Padilla-Rodal, E.; Phillips, A. A.; Porter-Peden, M.; Ressler, J. J.; Roy, R.; Ruiz, C.; Sarazin, F.; Scraggs, D. P.; Waddington, J. C.; Wan, J. M.; Whitbeck, A.; Williams, S. J.; Wong, J.

    2008-10-01

    The low-energy structures of the mirror nuclei Ne21 and radioactive Na21 have been examined by using Coulomb excitation at the TRIUMF-ISAC radioactive ion beam facility. Beams of ~5×106 ions/s were accelerated to 1.7 MeV/A and Coulomb excited in a 0.5 mg/cm2 natTi target. Scattered beam and target particles were detected by the segmented Si detector BAMBINO, while γ rays were observed by using two TIGRESS HPGe clover detectors perpendicular to the beam axis. For each isobar, Coulomb excitation from the (3)/(2)+ ground state to the first excited (5)/(2)+ state was observed and B(E2) values were determined by using the 2+→0+ de-excitation in Ti48 as a reference. The ϕ segmentation of BAMBINO was used to deduce tentative assignments for the signs of the mixing ratios between the E2 and M1 components of the transitions. The resulting B(E2)↑ values are 131±9e2 fm4 (25.4±1.7 W.u.) for Ne21 and 205±14e2 fm4 (39.7±2.7 W.u.) for Na21. The fit to the present data and the known lifetimes determined E2/M1 mixing ratios and B(M1)↓ values of δ=(-)0.0767±0.0027 and 0.1274±0.0025μN2 and δ=(+)0.0832±0.0028 and 0.1513±0.0017μN2 for Ne21 and Na21, respectively (with Krane and Steffen sign convention). By using the effective charges ep=1.5e and en=0.5e, the B(E2) values produced by the p-sd shell model are 30.7 and 36.4 W.u. for Ne21 and Na21, respectively. This analysis resolves a significant discrepancy between a previous experimental result for Na21 and shell-model calculations.

  5. Bombardment-induced segregation and redistribution

    NASA Astrophysics Data System (ADS)

    Lam, N. Q.; Wiedersich, H.

    During ion bombardment, a number of processes can alter the compositional distribution and microstructure in near-surface regions of alloys. The relative importance of each process depends principally on the target composition, temperature, and ion characteristics. In addition to displacement mixing leading to a randomization of atomic locations, and preferential loss of alloying elements by sputtering, which are dominant at relatively low temperatures, several thermally-activated processes, including radiation-enhanced diffusion, radiation-induced segregation and Gibbsian adsorption, also play important roles. At elevated temperatures, nonequilibrium point defects induced by ion impacts become mobile and tend to anneal out by recombination and diffusion to extended sinks, such as dislocations, grain boundaries and free surfaces. The high defect concentrations, far exceeding the thermodynamic equilibrium values, can enhance diffusion-controlled processes, while persistent defect fluxes, originating from the spatial non-uniformity in defect production and annihilation, give rise to local redistribution of alloy constituents because of radiation-induced segregation. Moreover, when the alloy is maintained at high temperature, Gibbsian adsorption, driven by the reduction in free energy of the system, occurs even without irradiation; it involves a compositional perturbation in a few atom layers near the alloy surface. The combination of these processes leads to the complex development of a compositionally-modified layer in the subsurface region. Considerable progress has been made recently in identifying and understanding the relative contributions from the individual processes under various irradiation conditions. In the present paper, selected examples of these different phenomena and their synergistic effects on the evolution of the near-surface compositions of alloys during sputtering and ion implantation at elevated temperatures are discussed.

  6. Molecular dynamics simulations of hydrogen bombardment of tungsten carbide surfaces

    NASA Astrophysics Data System (ADS)

    Träskelin, P.; Juslin, N.; Erhart, P.; Nordlund, K.

    2007-05-01

    The interaction between energetic hydrogen and tungsten carbide (WC) is of interest both due to the use of hydrogen-containing plasmas in thin-film manufacturing and due to the presence of WC in the divertor of fusion reactors. In order to study this interaction, we have carried out molecular dynamics simulations of the low-energy bombardment of deuterium impinging onto crystalline as well as amorphous WC surfaces. We find that prolonged bombardment leads to the formation of an amorphous WC surface layer, regardless of the initial structure of the WC sample. Loosely bound hydrocarbons, which can erode by swift chemical sputtering, are formed at the surface. Carbon-terminated surfaces show larger sputtering yields than tungsten-terminated surfaces. In both cumulative and noncumulative simulations, C is seen to sputter preferentially. Implications for mixed material erosion in ITER are discussed.

  7. A molecular dynamics study of helium bombardments on tungsten nanoparticles

    NASA Astrophysics Data System (ADS)

    Li, Min; Hou, Qing; Cui, Jiechao; Wang, Jun

    2018-06-01

    Molecular dynamics simulations were conducted to study the bombardment process of a single helium atom on a tungsten nanoparticle. Helium atoms ranging from 50 eV to 50 keV were injected into tungsten nanoparticles with a diameter in the range of 2-12 nm. The retention and reflection of projectiles and sputtering of nanoparticles were calculated at various times. The results were found to be relative to the nanoparticle size and projectile energy. The projectile energy of 100 eV contributes to the largest retention of helium atoms in tungsten nanoparticles. The most obvious difference in reflection exists in the range of 3-10 keV. Around 66% of sputtering atoms is in forward direction for projectiles with incident energy higher than 10 keV. Moreover, the axial direction of the nanoparticles was demonstrated to influence the bombardment to some degree.

  8. Energetic ion bombardment of Ag surfaces by C60+ and Ga+ projectiles.

    PubMed

    Sun, Shixin; Szakal, Christopher; Winograd, Nicholas; Wucher, Andreas

    2005-10-01

    The ion bombardment-induced release of particles from a metal surface is investigated using energetic fullerene cluster ions as projectiles. The total sputter yield as well as partial yields of neutral and charged monomers and clusters leaving the surface are measured and compared with corresponding data obtained with atomic projectile ions of similar impact kinetic energy. It is found that all yields are enhanced by about one order of magnitude under bombardment with the C60+ cluster projectiles compared with Ga+ ions. In contrast, the electronic excitation processes determining the secondary ion formation probability are unaffected. The kinetic energy spectra of sputtered particles exhibit characteristic differences which reflect the largely different nature of the sputtering process for both types of projectiles. In particular, it is found that under C60+ impact (1) the energy spectrum of sputtered atoms peaks at significantly lower kinetic energies than for Ga+ bombardment and (2) the velocity spectra of monomers and dimers are virtually identical, a finding which is in pronounced contrast to all published data obtained for atomic projectiles. The experimental findings are in reasonable agreement with recent molecular dynamics simulations.

  9. Canonical Variate Analysis of Chlorophyll Content in Plants Exposed to Different Lead Concentrations in Ambient Air Conditions/ Analiza Zmiennych Kanonicznych Zawatości Chlorofilu W Roślinach Eksponowanych Na Różne Stężenia Ołowiu W Powietrzu Atmosferycznym

    NASA Astrophysics Data System (ADS)

    Budka, Anna; Kayzer, Dariusz; Zbierska, Janina; Borowiak, Klaudia; Barałkiewicz, Danuta; Hanć, Anetta

    2014-09-01

    Praca prezentuje rezultaty biomonitoringu ołowiu w zróżnicowanych warunkach środowiskowych. Do oceny zawartości poziomu ołowiu wykorzystano rośliny życicy wielokwiatowej. Dodatkowo w liściach oznaczono zawartość chlorofilu (a+b, a oraz b) w świeżej masie. Rośliny eksponowano w okresie wegetacyjnym roku 2011 na pięciu stanowiskach badawczych różniących się parametrami środowiskowymi oraz w warunkach kontrolnych. Rośliny eksponowano w 28-dniowych okresach badawczych. Wyniki zawartości Pb oraz poziomów chlorofili w różnych miejscach ekspozycyjnych oraz seriach testowano z zastosowaniem wielowymiarowej analizy wariancji. Wykazano zmienność zawartości Pb oraz poziomów wszystkich form chlorofilu w różnych miejscach ekspozycyjnych i seriach. Najniższe zawartości ołowiu oraz najwyższe poziomy wszystkich form chlorofilu zaobserwowano na stanowisku podmiejskim. W pracy wykazano przydatność analizy zmiennych kanonicznych do graficznej prezentacji wyników biomonitoringu powietrza. This paper presents the results of biomonitoring of Pb in ambient air. For this purpose Italian ryegrass was used to evaluate Pb level. Additionally chlorophyll forms (a+b, a and b) were measured in leaves. Plants were exposed at 5 sites varying in environmental characteristics in the 2011 growing season. A similar set of plants was conducted in control conditions. Three 28-day long exposure series were performed. The aim of this study was to analyse the relation between Pb level and chlorophyll content in various exposure sites and series using multivariate analysis of variance. The analysis revealed variability of Pb and all chlorophyll forms contents in different exposure sites and series. The lowest level of Pb concentrations was noted at a sub-urban site together with the highest level of all chlorophyll forms contents. Canonical variate analysis could be a proper tool for a graphical data presentation of Pb level in plants exposed to various environmental

  10. Stress and PTSD Mechanisms as Targets for Pharmacotherapy of Alcohol Abuse, Addiction, and Relapse

    DTIC Science & Technology

    2015-10-01

    AWARD NUMBER: W81XWH-13-1-0126 TITLE: Stress and PTSD Mechanisms as Targets for Pharmacotherapy of Alcohol Abuse, Addiction, and Relapse...DATES COVERED 30 Sep 2014 - 29 Sep 2015 4. TITLE AND SUBTITLE Stress and PTSD Mechanisms as Targets for Pharmacotherapy of Alcohol Abuse, Addiction...demonstrated that alcohol -na"ive rats exhibiting high acoustic startle response (which is associated with increased anxiety-like behavior) develop

  11. ETFE polymer bombarded with 1 MeV proton

    NASA Astrophysics Data System (ADS)

    Parada, M. A.; de Almeida, A.; Muntele, I.; Muntele, C.; Delalez, N.; Ila, D.

    2005-12-01

    The ethylenetetrafluoroethylene (ETFE) is a polymer formed by alternating ethylene and tetrafluoroethylene segments. It has high impact resistance and useful mechanical properties. ETFE can be used as components of pumps, valves, tie wraps, and electrical components. It can also be applied in the field of medical physics as intra venous catheters and as radiation dosimeter. When a material is exposed to the ionizing radiation, it suffers damage that depends on the type, energy and intensity of the radiation. In order to determine the radiation damage mechanism, ETFE films were bombarded with 1 MeV protons to the fluence between 1 × 1011 and 1 × 1016 protons/cm2 and the chemical species emitted during the bombardment were measured with residual gas analysis (RGA) and show that HF gas is the entity preferentially emitted. Optical absorption photospectrometry (OAP) and attenuated total reflectometry fourier transform infrared (ATR-FTIR) shows quantitative chemical evidence of the damage. Our results show that damage is detectable at low proton fluence, but damage that can compromise the application in dosimetry occurs only for fluence greater than 1014 protons/cm2.

  12. Single mode low-NA step index Yb-doped fiber design for output powers beyond 4kW (Conference Presentation)

    NASA Astrophysics Data System (ADS)

    Beier, Franz; Proske, Fritz; Hupel, Christian; Kuhn, Stefan; Hein, Sigrun; Sattler, Bettina; Nold, Johannes; Haarlammert, Nicoletta; Schreiber, Thomas; Eberhardt, Ramona; Tünnermann, Andreas

    2017-03-01

    Fiber amplifiers are representing one of the most promising solid state laser concepts, due to the compact setup size, a simple thermal management and furthermore excellent beam quality. In this contribution, we report on the latest results from a low-NA, large mode area single mode fiber with a single mode output power beyond 4 kW without any indication of mode instabilities or nonlinear effects and high slope efficiency. Furthermore, we quantify the influence of the bending diameter of our manufactured low NA fiber on the average core loss by an OFDR measurement and determine the optimal bending diameter in comparison to a second fiber with a slightly changed NA. The fibers used in the experiments were fabricated by MCVD technology combined with the solution doping technique. The investigation indicates the limitation of the step index fiber design and its influence on the use in high power fiber amplifiers. We demonstrate, that even a slightly change in the core NA crucially influences the minimum bending diameter of the fiber and has to be taken into account in applications. The measured output power represents to the best of our knowledge the highest single mode output power of an amplifier fiber ever reported on.

  13. The (111) Surface of NaAu 2. Structure, Composition, and Stability

    DOE PAGES

    Kwolek, Emma J.; Widmer, Roland; Gröning, Oliver; ...

    2014-12-17

    The (111) surface of single-crystal NaAu 2 is a model for catalytically active, powdered NaAu 2. We prepare and characterize this surface with a broad suite of techniques. Preparation in ultrahigh vacuum consists of the traditional approach of ion bombardment (to remove impurities) and thermal annealing (to restore surface order). Both of these steps cause loss of sodium (Na), and repeated treatments eventually trigger conversion of the surface and near-surface regions to crystalline gold. The bulk has a limited ability to repopulate the surface Na. Under conditions where Na depletion is minimized, electron diffraction patterns are consistent with the bulk-terminatedmore » structure, and scanning tunneling microscopy reveals mesa-like features with lateral dimensions of a few tens of nanometers. The tops of the mesas do not possess fine structure characteristic of a periodic lattice, suggesting that the surface layer is disordered under the conditions of these experiments.« less

  14. Surface damage studies of ETFE polymer bombarded with low energy Si ions (⩽100 keV)

    NASA Astrophysics Data System (ADS)

    Minamisawa, Renato Amaral; Almeida, Adelaide De; Budak, Satilmis; Abidzina, Volha; Ila, Daryush

    2007-08-01

    Surface studies of ethylenetetrafluoroethylene (ETFE), bombarded with Si in a high-energy tandem Pelletron accelerator, have recently been reported. Si ion bombardment with a few MeV to a few hundred keV energies was shown to be sufficient to produce damage on ETFE film. We report here the use of a low energy implanter with Si ion energies lower than 100 keV, to induce changes on ETFE films. In order to determine the radiation damage, ETFE bombarded films were simulated with SRIM software and analyzed with optical absorption photometry (OAP), Raman and Fourier transform infrared-attenuated total reflectance (FTIR-ATR) spectroscopy to show quantitatively the physical and chemical property changes. Carbonization occurs following higher dose implantation, and hydroperoxides were formed following dehydroflorination of the polymer.

  15. Stable transformation of rice (Oryza sativa L.) via microprojectile bombardment of highly regenerative, green tissues derived from mature seed.

    PubMed

    Cho, M-J; Yano, H; Okamoto, D; Kim, H-K; Jung, H-R; Newcomb, K; Le, V K; Yoo, H S; Langham, R; Buchanan, B B; Lemaux, P G

    2004-02-01

    A highly efficient and reproducible transformation system for rice ( Oryza sativa L. cv. Taipei 309) was developed using microprojectile bombardment of highly regenerative, green tissues. These tissues were induced from mature seeds on NB-based medium containing 2,4-dichlorophenoxyacetic acid (2,4-D), 6-benzylaminopurine (BAP) and high concentrations of cupric sulfate under dim light conditions; germinating shoots and roots were completely removed. Highly regenerative, green tissues were proliferated on the same medium and used as transformation targets. From 431 explants bombarded with transgenes [i.e. a hygromycin phosphotransferase ( hpt) gene plus one of a wheat thioredoxin h ( wtrxh), a barley NADP-thioredoxin reductase ( bntr), a maize Mutator transposable element ( mudrB) or beta-glucuronidase ( uidA; gus) gene], 28 independent transgenic events were obtained after an 8- to 12-week selection period, giving a 6.5% transformation frequency. Of the 28 independent events, 17 (61%) were regenerable. Co-transformation of the second introduced transgene was detected in 81% of the transgenic lines tested. Stable integration and expression of the foreign genes in T(0) plants and T(1) progeny were confirmed by DNA hybridization, western blot analyses and germination tests.

  16. Manipulating the alkali metal charge compensation and tungsten oxide to continuously enhance the red fluorescence in (Li,Na,K)Ca(Mo,W)O4:Eu3+ solid solution compounds

    NASA Astrophysics Data System (ADS)

    Xie, Wei; Li, Jiaxin; Tian, Canxin; Wang, Zesong; Xie, Mubiao; Zou, Changwei; Sun, Guohuan; Kang, Fengwen

    2018-02-01

    When compared to other phosphors typically the blue and green phosphors, red phosphors, which can be used for white light-emitting diodes (wLEDs), always suffer from various problems such as higher cost, lower luminescence efficiency and bad thermal stability. And thus, great interests have been paid to how to enhance the red fluorescence intensity in the recent years. Here we report on a red-emitting solid solutions, (Li,Na,K)Ca(Mo,W)O4:Eu3+, which enable exhibiting continuous Eu3+ emission enhancement through manipulating the alkali metal ions and the relative content ratios between tungsten and molybdenum oxides. X-ray powder diffraction (XRD) has been employed to check the phase purity, and results show that all samples crystallize in a scheelite structure with space group of I41/a (No.88). A regular blue-shifting of XRD peaks, which indicates the increase of crystal plane spacing, appears as the alkali cationic radius increases from 0.92 Å (for Li), 1.18 Å (for Na) and to 1.38 Å (for K). Replacing Mo ion (0.41 Å) by W ion (0.42 Å) enables not only forming the solid solution compounds (Li,Na,K)Ca(Mo,W)O4:Eu3+, but also blue-shifting the XRD position. Similar to the XRD position shifting, our samples also exhibit the regular change in the photoluminescence (PL) spectra, in which the charge transfer (CT) band position as the alkali cationic radii increase from Li, Na and to K and further from Mo to W shows a continuous red-shifting behavior. As for the CT and Eu3+ intensity, our experimental results show that the alkali ion that corresponds to the maximum intensity is Li, and this intensity can be further enhanced by adding W. In coincidence with the change in the excitation spectral intensity, the continuous enhanced Eu3+ emission intensity can be observed up excitation at the CT band and Eu3+ lines. We have discussed the above CT band shifting and Eu3+ fluorescence enhancement and give a feasible mechanism profile that base on the energy transfer from CT

  17. Modification of W surfaces by exposure to hollow cathode plasmas

    NASA Astrophysics Data System (ADS)

    Stancu, C.; Stokker-Cheregi, F.; Moldovan, A.; Dinescu, M.; Grisolia, C.; Dinescu, G.

    2017-10-01

    In this work, we assess the surface modifications induced on W samples following exposure to He and He/H2 radiofrequency plasmas in hollow cathode discharge configuration. Our study addresses issues that relate to the use of W in next-generation fusion reactors and, therefore, the investigation of W surface degradation following exposure and heating by plasmas to temperatures above 1000 °C is of practical importance. For these experiments, we used commercially available tungsten samples having areas of 30 × 15 mm and 0.1 mm thickness. The hollow cathode plasma was produced using a radiofrequency (RF) generator (13.56 MHz) between parallel plate electrodes. The W samples were mounted as one of the electrodes. The He and He/H2 plasma discharges had a combined effect of heating and bombardment of the W surfaces. The surface modifications were studied for discharge powers between 200 and 300 W, which resulted in the heating of the samples to temperatures between 950 and 1230 °C, respectively. The samples were weighed prior and after plasma exposure, and loss of mass was measured following plasma exposure times up to 90 min. The analysis of changes in surface morphology was carried out by optical microscopy, scanning electron microscopy and atomic force microscopy. Additionally, optical emission spectra of the respective plasmas were recorded from the region localized inside the hollow cathode gap. We discuss the influence of experimental parameters on the changes in surface morphology.

  18. TU-H-BRC-06: Temperature Simulation of Tungsten and W25Re Targets to Deliver High Dose Rate 10 MV Photons

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Wang, J; Trovati, S; Loo, B

    Purpose: To study the impact of electron beam size, target thickness, and target temperature on the ability of the flattening filter-free mode (FFF) treatment head to deliver high-dose-rate irradiations. Methods: The dose distribution and transient temperature of the X-ray target under 10 MeV electron beam with pulse length of 5 microseconds, and repetition rate of 1000 Hz was studied. A MCNP model was built to calculate the percentage depth dose (PPD) distribution in a water phantom at a distance of 100 cm. ANSYS software was used to run heat transfer simulations. The PPD and temperature for both tungsten and W25Remore » targets for different electron beam sizes (FHWM 0.2, 0.5, 1 and 2 mm) and target thickness (0.2 to 2 mm) were studied. Results: Decreasing the target thickness from 1 mm to 0.5 mm, caused a surface dose increase about 10 percent. For both target materials, the peak temperature was about 1.6 times higher for 0.5 mm electron beam compared to the 1 mm beam after reaching their equilibrium. For increasing target thicknesses, the temperature rise caused by the first pulse is similar for all thicknesses, however the temperature difference for subsequent pulses becomes larger until a constant ratio is reached. The target peak temperature after reaching equilibrium can be calculated by adding the steady state temperature and the amplitude of the temperature oscillation. Conclusion: This work indicates the potential to obtain high dose rate irradiation by selecting target material, geometry and electron beam parameters. W25Re may not outperformed tungsten when the target is thick due to its relatively low thermal conductivity. The electron beam size only affects the target temperature but not the PPD. Thin target is preferred to obtain high dose rate and low target temperature, however, the resulting high surface dose is a major concern. NIH funding:R21 EB015957-01; DOD funding:W81XWH-13-1-0165 BL, PM, PB, and RF are founders of TibaRay, Inc. BL is also

  19. Adaptation of the South-West Wing of Collegium Chemicum of Adam Mickiewicz University in Poznań for Storage Facilities/ Adaptacja Południowo-Zachodniego Skrzydła Budynku Collegium Chemicum Uam W Poznaniu Na Cele Magazynowe

    NASA Astrophysics Data System (ADS)

    Ścigałło, Jacek

    2015-06-01

    The article refers to the problems of adaptation of Collegium Chemicum facilities belonging to Adam Mickiewicz Uniwersity in Poznań to its storage needs. The subject building is situated in Grunwaldzka Street in Poznań. In the introduction part, the building and its structural solutions are described. The results of the materials research and the measurements of the used reinforcement have been presented. The structure diagnostic analyses were performed basing on measurements and research. The analysis allowed the determination of the limit loads. The results of the performed analysis of the current state turned out to be unsatisfactory, not only in terms of the planned storage load but also in terms of the current load state, as was shown by the construction analysis. W pracy przedstawiono problemy związane z adaptacją budynku dydaktycznego Collegium Chemicum przy ul. Grunwaldzkiej w Poznaniu na cele magazynowe Biblioteki Głównej UAM. Na wstępie opisano badany budynek oraz scharakteryzowano zastosowane w nim rozwiązania konstrukcyjne. Przedstawiono wyniki wykonanych badań materiałowych oraz pomiarów inwentaryzacyjnych zastosowanego zbrojenia. Na podstawie wykonanych pomiarów i badań przeprowadzono analizę diagnostyczną konstrukcji, która pozwoliła na wyznaczenie dopuszczalnych wartości obciążeń powierzchni stropowych. Wyniki wykonanej analizy konstrukcji w stanie istniejącym okazały się dalece niezadowalające nie tylko z punktu widzenia planowanych, znacznych obciążeń magazynowych. Analiza wykazała bowiem, że konstrukcja jest już znacznie przeciążona w aktualnym stanie jej obciążenia

  20. The timeline of the lunar bombardment: Revisited

    NASA Astrophysics Data System (ADS)

    Morbidelli, A.; Nesvorny, D.; Laurenz, V.; Marchi, S.; Rubie, D. C.; Elkins-Tanton, L.; Wieczorek, M.; Jacobson, S.

    2018-05-01

    The timeline of the lunar bombardment in the first Gy of Solar System history remains unclear. Basin-forming impacts (e.g. Imbrium, Orientale), occurred 3.9-3.7 Gy ago, i.e. 600-800 My after the formation of the Moon itself. Many other basins formed before Imbrium, but their exact ages are not precisely known. There is an intense debate between two possible interpretations of the data: in the cataclysm scenario there was a surge in the impact rate approximately at the time of Imbrium formation, while in the accretion tail scenario the lunar bombardment declined since the era of planet formation and the latest basins formed in its tail-end. Here, we revisit the work of Morbidelli et al. (2012) that examined which scenario could be compatible with both the lunar crater record in the 3-4 Gy period and the abundance of highly siderophile elements (HSE) in the lunar mantle. We use updated numerical simulations of the fluxes of asteroids, comets and planetesimals leftover from the planet-formation process. Under the traditional assumption that the HSEs track the total amount of material accreted by the Moon since its formation, we conclude that only the cataclysm scenario can explain the data. The cataclysm should have started ∼ 3.95 Gy ago. However we also consider the possibility that HSEs are sequestered from the mantle of a planet during magma ocean crystallization, due to iron sulfide exsolution (O'Neil, 1991; Rubie et al., 2016). We show that this is likely true also for the Moon, if mantle overturn is taken into account. Based on the hypothesis that the lunar magma ocean crystallized about 100-150 My after Moon formation (Elkins-Tanton et al., 2011), and therefore that HSEs accumulated in the lunar mantle only after this timespan, we show that the bombardment in the 3-4 Gy period can be explained in the accretion tail scenario. This hypothesis would also explain why the Moon appears so depleted in HSEs relative to the Earth. We also extend our analysis of the

  1. Successful expression in pollen of various plant species of in vitro synthesized mRNA introduced by particle bombardment.

    PubMed

    Tanaka, T; Nishihara, M; Seki, M; Sakamoto, A; Tanaka, K; Irifune, K; Morikawa, H

    1995-05-01

    Gold particles coated with beta-glucuronidase (GUS) mRNA with a 5' cap structure that had been synthesized in vitro were introduced, by use of a pneumatic particle gun, into pollen grains of lily (Lilium longiflorum), freesia (Freesia refracta) and tulip (Tulipa gesneriana). A fluorometric assay for the GUS activity indicated that in vitro synthesized GUS mRNA introduced into these pollen cells by particle bombardment was successfully expressed. GUS activity in extracts of the bombarded lily pollen became detectable fluorometrically within 30 min after bombardment, peaked at 6 h, then gradually decreased. This activity changed as a function of the developmental stage of the pollen cell of lily.

  2. Bacterial spore survival after exposure to HZE particle bombardment -implication for the lithopanspermia hypothesis.

    NASA Astrophysics Data System (ADS)

    Moeller, Ralf; Berger, Thomas; Matthiä, Daniel; Okayasu, Ryuichi; Kitamura, H.; Reitz, Guenther

    transcriptional response during spore germination" (Moeller et al., 2008 [3]). To simulate the interplanetary journey of a meteorite, stacks of spore-samples on gabbro slides in different depths were exposed. Spore survival and the rate of the induced mutations (i.e., sporulation-deficiency (Spo-)) depended on the LET of the applied species of ions as well as on the location (and depth) of the irradiated spores in the artificial meteorite. The exposure to high LET iron ions led to a low level of spore survival and increased frequency of mutation to Spo-compared to low-energy charged particles compared to the low LET helium ions. In order to obtain insights on the role of DNA repair by nonhomologous end joining (NHEJ), homologous recombination (HR) and apurinic/apyrimidinic (AP) endonucleases in B. subtilis spore resistance to high-energy charged particles has been studied in parallel. Spores deficient in NHEJ and AP endonucleases were significantly more sensitive to HZE particle bombardment than were the HR-mutant and wild-type spores, indicating that NHEJ and AP endonucleases provide DNA break repair pathways during spore germination. ((References: [1] Arrhenius, S. 1903. Die Verbreitung des Lebens im Weltenraum. Umschau 7:481-485.; [2] Nicholson, W. L. 2009. Ancient micronauts: interplanetary transport of microbes by cosmic impacts. Trends Mi-crobiol. 17:243-250.; [3] Moeller, R., P. Setlow, G. Horneck, T. Berger, G. Reitz, P. Rettberg, A. J. Doherty, R. Okayasu, and W. L. Nicholson. 2008. Roles of the major, small, acid-soluble spore proteins and spore-specific and universal DNA repair mechanisms in resistance of Bacillus subtilis spores to ionizing radiation from X-rays and high-energy charged-particle bombardment. J. Bacteriol. 190:1134-1140.))

  3. Geotechnical Aspects of Revitalisation of Post-Mining Areas - An Example of the Adaptation of Katowice Hard Coal Mine for the New Silesian Museum / Geotechniczne aspekty rewitalizacji terenów pogórniczych - przykład adaptacji KWK "KATOWICE" na nowe muzeum śląskie

    NASA Astrophysics Data System (ADS)

    Cała, Marek; Ostręga, Anna

    2013-06-01

    południowej części terenu dawnej Kopalni "Katowice", na którym znajdują się zabytkowe obiekty przeznaczone do odrestaurowania i adaptacji dla nowych funkcji. Są to: - budynek maszyny wyciągowej Szybu "Warszawa" (MS-8), adaptowany dla celów gastronomicznych, - magazyn odzieżowy (MS-15), adaptowany dla celów wystawienniczych-Centrum Scenografii Polskiej, - wieża wyciągowa Szybu "Warszawa" (MS-79), adaptowana dla funkcji widokowych. Pozostała część terenu dawnej KWK "Katowice" wraz zabytkowymi obiektami, w miarę możliwości finansowych włączana będzie w kompleks Muzeum Śląskiego. Oparcie koncepcji na idei minimalnej ingerencji w urbanistyczny układ zabytkowej kopalni, a jednocześnie potrzeba zapewnienia odpowiednich przestrzeni wystawienniczych, administracyjnych i miejsc postojowych znalazły odzwierciedlenie w zastosowaniu następujących rozwiązań: - adaptacji historycznych obiektów dla funkcji wystawienniczych, gastronomicznych i widokowych; - ulokowania nowobudowanych obiektów pod powierzchnią terenu w bezpośrednim sąsiedztwie zabytkowych obiektów. W związku z powyższym koniecznym było wykonanie prac wzmacniających posadowienie historycznych budynków oraz geotechnicznych zabezpieczeń skarp wykopu. W artykule pokazano technologiczne rozwiązania jakie zastosowano dla zabezpieczenia zabytkowych budynków, wieży wyciągowej oraz wykopu pod nowe obiekty Muzeum Śląskiego. Geotechniczne metody zabezpieczenia poszczególnych obiektów zaprojektowano na podstawie rozpoznania warunków geologiczno-inżynierskich oraz wykonanych analiz, co pozwoliło na zaproponowanie rozwiązań optymalnych zarówno pod względem technicznym jak i ekonomicznym. Z uwagi na skomplikowane uwarunkowania geotechniczne i wartość obiektów znajdujących się w strefie oddziaływania wykopu, przewidziano zastosowanie technologii pozwalającej uzyskać efekt maksymalnego wzmocnienia wgłębnego masywu. Zaprojektowane technologie zabezpieczenia mają na

  4. Fast atom bombardment mass spectrometry of condensed tannin sulfonate derivatives

    Treesearch

    J.J. Karchesy; L.Y. Foo; Richard W. Hemingway; E. Barofsky; D.F. Barofsky

    1989-01-01

    Condensed tannin sulfonate derivatives were studied by fast atom bombardment mass spectrometry (FAB-MS) to assess the feasibility of using this technique for determining molecular weight and structural information about these compounds. Both positive- and negative-ion spectra provided useful data with regard to molecular weight, cation species present, and presence of...

  5. Hydroxyapatite Based 99Mo - 99Tc and 188W - 188Re Generator Systems

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Knapp Jr, Russ F; Monroy-Guzman, F.; Badillo, V. E.

    2006-01-01

    This paper describes studies evaluating the use of hydroxyapatite as the adsorbent material for both {sup 99}Mo-{sup 99m}Tc and {sup 188}W-{sup 188}Re generator systems. Hydroxyapatite is an insoluble solid with anion exchange properties. A study of the sorption behaviour of {sup 99}Mo, {sup 99m}Tc, {sup 188}W and {sup 188}Re on hydroxyapatite in NaCl medium was evaluated by batch experiments. The results demonstrated that while {sup 99}Mo, {sup 99m}Tc and {sup 188}Re are not adsorbed by the hydroxyapatite in NaCl solutions (Kd <5), {sup 188}W is strongly adsorbed (Kd >500). On the basis of these measurements, hydroxyapatite {sup 188}W-{sup 188}Re generatormore » systems were then constructed and eluted in NaCl solutions. The hydroxyapatite based {sup 188}W-{sup 188}Re generator performances are presented.« less

  6. Optimal control theory with continuously distributed target states: An application to NaK

    NASA Astrophysics Data System (ADS)

    Kaiser, Andreas; May, Volkhard

    2006-01-01

    Laser pulse control of molecular dynamics is studied theoretically by using optimal control theory. The control theory is extended to target states which are distributed in time as well as in a space of parameters which are responsible for a change of individual molecular properties. This generalized treatment of a control task is first applied to wave packet formation in randomly oriented diatomic systems. Concentrating on an ensemble of NaK molecules which are not aligned the control yield decreases drastically when compared with an aligned ensemble. Second, we demonstrate for NaK the maximization of the probe pulse transient absorption in a pump-probe scheme with an optimized pump pulse. These computations suggest an overall optical control scheme, whereby a flexible technique is suggested to form particular wave packets in the excited state potential energy surface. In particular, it is shown that considerable wave packet localization at the turning points of the first-excited Σ-state potential energy surfaces of NaK may be achieved. The dependency of the control yield on the probe pulse parameters is also discussed.

  7. Results from Dealing with Rock and Gas Outburst Prevention in The Czech Republic / Efekty Działań Mających Na Celu Zapobieganie Wybuchom Skał I Gazu, Podejmowanych W Republice Czeskiej

    NASA Astrophysics Data System (ADS)

    Hudeček, Vlastimil; Zapletal, Pavel; Stoniš, Milan; Sojka, Radislav

    2013-09-01

    In the Czech Republic, the prevention of rock and gas outbursts is carried out in the course of driving mine workings in seams and in sandstone and conglomerate beds classified into a category with the highest degree of rock and gas outburst hazard. It is a case of active methods that aim at prevention of rock and gas outbursts by creating a protection zone in front of and in sides of mine workings being driven and passive methods that mitigate the effects of outbursts (Hudeček et al., 2009, 2010). In this article, authors present recommendations and proposals for changes in rock and gas outburst prevention. These proposed changes should reflect in increased efficiency in coping with this anomalous geomechanical events. Działania w celu zapobiegania wybuchom skał i gazów w Republice czeskiej podejmowane są już na etapie drążenia wyrobisk w złożach oraz w piaskowcach oraz w pokładach zlepieńców sklasyfikowanych jako lokalizacje o najwyższym stopniu zagrożenia wybuchami skał i gazów. W tym przypadku mamy do dyspozycji metody aktywne, których celem jest zapobieżenie wybuchom skał i gazów poprzez stworzenie strefy ochronnej w części czołowej i bocznych częściach wyrobiska oraz metody bierne, mające na celu złagodzenie skutków wybuchu (Hudecek et al., 2009, 2010). W artykule autor rekomenduje i zaleca dokonanie pewnych zmian w systemie zapobiegania wybuchom skał i gazów. Proponowane zmiany skutkować powinny zwiększoną skutecznością działania w przypadku wystąpienia zjawisk geomechanicznych uznawanych za anomalie.

  8. The distribution of cotransformed transgenes in particle bombardment-mediated transformed wheat

    USDA-ARS?s Scientific Manuscript database

    Although particle bombardment is the predominant method of foreign DNA direct transfer, whether transgene is integrated randomly into the genome has not been determined. In this study, we identified the distribution of transgene loci in 45 transgenic wheat (Triticum aestivum L.) lines containing c...

  9. Study of the surface activation of ETFE by low energy (keV) Si and N bombardment

    NASA Astrophysics Data System (ADS)

    Parada, M. A.; de Almeida, A.; Muntele, C.; Muntele, I.; Delalez, N.; Ila, D.

    2005-12-01

    The ethylenetetrafluoroethylene (ETFE) is a polymer formed by alternating ethylene and tetrafluoroethylene segments. It can be applied in the field of medical physics as intra venous catheters and as radiation dosimeters. The increasing application of polymeric materials in technological and scientific fields has motivated the use of surface treatments to modify the physical and chemical properties of polymer surfaces. When a material is exposed to ionizing radiation, it suffers damage leading to surface activation depending on the type, energy and intensity of the applied radiation. In order to determine the radiation damage and the surface activation mechanism ETFE films were bombarded with keV Si and N at various fluences. The bombarded film was also analyzed with optical absorption photospectrometry (OAP), Raman and Fourier transform infrared-attenuated total reflectance (FTIR-ATR) spectroscopy showing quantitatively the chemical nature at the damage caused by the Si and N bombardment.

  10. Al K x-ray production for incident /sup 16/O ions: The influence of target thickness effects on observed target x-ray yields

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Gray, T.J.; Richard, P.; Gealy, G.

    1979-04-01

    Thin solid Al targets ranging in thickness from approx. 1 to 30 ..mu..g/cm/sup 2/ were bombarded by /sup 16/O ions wih incident energies from 0.25 to 2.25 MeV/amu. The effects of target thickness on the measured Al K x-ray yield for ions incident without an initial K-shell vacancy were determined. Comparisons of the data for Al K x-ray production in vanishingly thin targets (and 29-..mu..g/cm/sup 2/ targets) were made to perturbed-stationary-state calculations (PSS) for O ions on Al targets. The PSS calculations contained corrections for Coulomb deflection and binding energy (PSS(CB)) and for Coulomb deflection, binding energy, and polarization (PSS(CBP)).more » Further, two different PSS calculation procedures were employed: calculations without radial cutoffs employed in the binding-energy contribution (PSS), and calculations with radial cutoffs employed in the binding-energy correction (NPSS). The PSS(CBP) calculations agree with the measured Al K x-ray production cross section for data taken in the limit of a vanishingly thin target. The NPSS(CBP) calculations agree with the data taken for a 29-..mu..g/cm/sup 2/ Al target. The latter agreement is fortuitous, as the increase observed in the measured target x-ray yield for the 29-..mu..g/cm/sup 2/ target, in comparison to the yield extracted as rhox ..-->.. 0 at each bombarding energy, is due to K-shell--to--K-shell charge exchange. Comparisons are made with previously published data for /sup 16/O ions incident on finite-thickness Al targets.« less

  11. Efficient neutron production from sub-nanosecond laser pulse accelerating deuterons on target front side

    NASA Astrophysics Data System (ADS)

    Klir, D.; Krasa, J.; Cikhardt, J.; Dudzak, R.; Krousky, E.; Pfeifer, M.; Rezac, K.; Sila, O.; Skala, J.; Ullschmied, J.; Velyhan, A.

    2015-09-01

    Neutron-producing experiments have been carried out on the Prague Asterix Laser System. At the fundamental wavelength of 1.315 μm, the laser pulse of a 600 J energy and 300 ps duration was focused on a thick deuterated-polyethylene target. Neutron yields reached (4.1 ± 0.8) × 108 at the peak intensity of ≈3 × 1016 W/cm2. A more detailed analysis of neutron time-of-flight signals showed that a significant fraction of neutron yields was produced both by the 2H(d,n)3He reaction and by other neutron-producing reactions. Neutron energies together with delayed neutron and gamma emission showed that MeV deuterons escaped from a laser-produced plasma and interacted ≈50 ns later with a borosilicate blast-shield glass. In order to increase DD neutron yields and to characterize deuteron beams via nuclear reactions, a secondary deuterated polyethylene target was used in a pitcher-catcher scheme at the target front side. In this experimental arrangement, the neutron yield reached (2.0 ± 0.5) × 109 with the peak neutron fluence of (2.5 ± 0.5) × 108 n/sr. From the neutron yield, it was calculated that the secondary target was bombarded by 2 × 1014 deuterons in the 0.5-2.0 MeV energy range. The neutron yield of 2 × 109 at the laser energy of 600 J implied the production efficiency of 3 × 106 n/J. A very important result is that the efficient neutron production was achieved with the low contrast, sub-nanosecond laser pulse of the intensity of 1016 W/cm2. The latter parameters can be achieved in a rep-rate mode more easily than ultra-high intensities and contrasts.

  12. In vivo and in vitro gene transfer to mammalian somatic cells by particle bombardment.

    PubMed Central

    Yang, N S; Burkholder, J; Roberts, B; Martinell, B; McCabe, D

    1990-01-01

    Chimeric chloramphenicol acetyltransferase and beta-galactosidase marker genes were coated onto fine gold particles and used to bombard a variety of mammalian tissues and cells. Transient expression of the genes was obtained in liver, skin, and muscle tissues of rat and mouse bombarded in vivo. Similar results were obtained with freshly isolated ductal segments of rat and human mammary glands and primary cultures derived from these explants. Gene transfer and transient expression were also observed in eight human cell culture lines, including cells of epithelial, endothelial, fibroblast, and lymphocyte origin. Using CHO and MCF-7 cell cultures as models, we obtained stable gene transfer at frequencies of 1.7 x 10(-3) and 6 x 10(-4), respectively. The particle bombardment technology thus provides a useful means to transfer foreign genes into a variety of mammalian somatic cell systems. The method is applicable to tissues in vivo as well as to isolated cells in culture and has proven effective with all cell or tissue types tested thus far. This technology may therefore prove to be applicable in various aspects of gene therapy. Images PMID:2175906

  13. Modifying exchange bias effects of Mn/NiFe bilayers by in-situ Ar+ bombardment

    NASA Astrophysics Data System (ADS)

    Causer, G. L.; Manna, P. K.; Chiu, C.-C.; van Lierop, J.; Ionescu, M.; Lin, K.-W.; Klose, F.

    2017-10-01

    In this work, we present a procedure to modify the exchange bias (EB) properties of antiferromagnetic Mn/ferromagnetic NiFe bilayers by in-situ low energy Ar+ bombardment of the Mn layer during sample deposition. We present structural and magnetic results for unassisted and Ar+ assisted Mn/NiFe bilayers. X-ray diffraction, transmission electron microscopy and electron diffraction results establish different preferred Mn orientation directions between the two samples as a result of the Ar+ bombardment process. Hysteresis loops taken over several temperatures reveal that samples assisted with Ar+ ions during the Mn layer deposition had suppressed EB properties at low temperature as compared to samples grown without Ar+ assistance.

  14. Schistosoma mansoni miracidia transformed by particle bombardment infect Biomphalaria glabrata snails and develop into transgenic sporocysts.

    PubMed

    Heyers, Oliver; Walduck, Anna K; Brindley, Paul J; Bleiss, Wilfrid; Lucius, Richard; Dorbic, Tomislav; Wittig, Burghardt; Kalinna, Bernd H

    2003-10-01

    Miracidia (and adults) of Schistosoma mansoni which had been subjected to particle bombardment with a plasmid DNA encoding enhanced green fluorescent protein (EGFP) under control of the S. mansoni heat shock protein 70 (HSP70) promoter and termination elements were shown to express the reporter gene. Bombarded miracidia were able to penetrate and establish in Biomphalaria glabrata the intermediate host snail. Gold particles could be detected in the germ balls of parasites in paraffin-sections of snail tissue. The bombarded miracidia were able to develop normally and to transform into mother sporocysts. Reporter gene activity could be determined at 10 days post-infection by RT-PCR in snail tissues, but not by microscopy or Western blot which probably reflected sub-optimal expression levels of constructs. Our findings indicated that it is feasible to return transgenic miracidia to the life cycle, a crucial step for the establishment of a transgenesis system for schistosomes.

  15. Surface Morphologies of Ti and Ti-Al-V Bombarded by 1.0-MeV Au+ Ions

    NASA Astrophysics Data System (ADS)

    Garcia, M. A.; Rickards, J.; Cuerno, R.; Trejo-Luna, R.; Cañetas-Ortega, J.; de la Vega, L. R.; Rodríguez-Fernández, L.

    2017-12-01

    Ion implantation is known to enhance the mechanical properties of biomaterials such as, e.g., the wear resistance of orthopedic joints. Increasing the surface area of implants may likewise improve their integration with, e.g., bone tissue, which requires surface features with sizes in the micron range. Ion implantation of biocompatible metals has recently been demonstrated to induce surface ripples with wavelengths of a few microns. However, the physical mechanisms controlling the formation and characteristics of these patterns are yet to be understood. We bombard Ti and Ti-6Al-4V surfaces with 1.0-MeV Au+ ions. Analysis by scanning electron and atomic force microscopies shows the formation of surface ripples with typical dimensions in the micron range, with potential indeed for biomedical applications. Under the present specific experimental conditions, the ripple properties are seen to strongly depend on the fluence of the implanted ions while being weakly dependent on the target material. Moreover, by examining experiments performed for incidence angle values θ =8 ° , 23°, 49°, and 67°, we confirm the existence of a threshold incidence angle for (ripple) pattern formation. Surface indentation is also used to study surface features under additional values of θ , agreeing with our single-angle experiments. All properties of the surface structuring process are very similar to those found in the production of surface nanopatterns under low-energy ion bombardment of semiconductor targets, in which the stopping power is dominated by nuclear contributions, as in our experiments. We consider a continuum model that combines the effects of various physical processes as originally developed in that context, with parameters that we estimate under a binary-collision approximation. Notably, reasonable agreement with our experimental observations is achieved, even under our high-energy conditions. Accordingly, in our system, ripple formation is determined by mass

  16. Simultaneous lidar observation of peculiar sporadic K and Na layers at São José dos Campos (23.1°S, 45.9°W), Brazil

    NASA Astrophysics Data System (ADS)

    Jiao, Jing; Yang, Guotao; Cheng, Xuewu; Liu, Zhengkuan; Wang, Jihong; Yan, Zhenzhong; Wang, Chi; Batista, Paulo; Pimenta, Alexandre; Andrioli, Vânia; Denardini, C. M.

    2018-04-01

    We present the first simultaneous observation of mesopause sodium (Na) and potassium (K) layer by a lidar which has Na and K channel simultaneously at the South Hemisphere site, São José dos Campos (23.1°S, 45.9°W). Measurements reported here were conducted on two nights with 3.5 and 8 h of observations in November 2016. On 20 November 2016, sporadic layers in both Na and K layer occurred above 100 km, and the higher layers corresponded well with sporadic E (Es) layer. And the density of Na at 100-105 km is higher than that at main layer around 90 km, but K density around 100 km is at least 3 times smaller compared with the K density around 90 km for the similar period. On 21 November 2016, both sporadic layers occurred in main layer height with obvious descending variations with time, which seems like tidal induced. Notably, the peak K/Na ratio slowly increased with time. And Na layer and K layer showed different processes along with time with K density reaching its maximum 1 h later than that of Na. Correlations of Na/K density, Es, and winds were also discussed.

  17. Potencjał turystyczny Lublina jako czynnik rozwoju miasta na przestrzeni wieków

    NASA Astrophysics Data System (ADS)

    Kociuba, Dagmara; Kociuba, Waldemar

    2009-01-01

    Lublin is situated on eastern border of Nałęczów Plateau at three rivers' confluence, it is the very picturesque city with beautiful panoramic sights. On touristic attractiveness of city influence both the natural as well cultural values, in peculiarity the objects of the material culture which are the heritage of men of different nationalities and religions living here over the centuries. The touristic potential of Lublin showed the large changeability in time. It structural and functional supplies were changed. The division into periods of city's popularity was marked, from very large in XV-XVI and XIX-XXI century to smaller in period of the XVIII century. Last years the touristic policy activation was noticed which manifesting the intensification of marketing actings having on aim the enlargement the touristic attractiveness of city e.g. creating the mark of Lublin and the projects in frames of the Bug Euroregion. They are effective of elevation of the rank of cultural output e.g. acknowledgement of the Lublin's historical town-planning complex the title of Monument History, inclusion of Lublin to European programme "Intercultural Cities", or trying about acknowledgement in 2016 r. the title of European Capital of Culture.

  18. A cryostat to hold frozen-spin polarized HD targets in CLAS. HDice-II

    DOE PAGES

    Lowry, Michael M.; Bass, Christopher D.; D'Angelo, Annalisa; ...

    2016-01-07

    The design, fabrication, operation, and performance of a helium-3/4 dilution refrigerator and superconducting magnet system for holding a frozen-spin polarized hydrogen deuteride target in the Jefferson Laboratory CLAS detector during photon beam running is reported. The device operates both vertically (for target loading) and horizontally (for target bombardment). Moreover, the device proves capable of maintaining a base temperature of 50 mK and a holding field of 1 Tesla for extended periods.

  19. The terrestrial record of Late Heavy Bombardment

    NASA Astrophysics Data System (ADS)

    Lowe, Donald R.; Byerly, Gary R.

    2018-04-01

    Until recently, the known impact record of the early Solar System lay exclusively on the surfaces of the Moon, Mars, and other bodies where it has not been erased by later weathering, erosion, impact gardening, and/or tectonism. Study of the cratered surfaces of these bodies led to the concept of the Late Heavy Bombardment (LHB), an interval from about 4.1 to 3.8 billion years ago (Ga) during which the surfaces of the planets and moons in the inner Solar System were subject to unusually high rates of bombardment followed by a decline to present low impact rates by about 3.5 Ga. Over the past 30 years, however, it has become apparent that there is a terrestrial record of large impacts from at least 3.47 to 3.22 Ga and from 2.63 to 2.49 Ga. The present paper explores the earlier of these impact records, providing details about the nature of the 8 known ejecta layers that constitute the evidence for large terrestrial impacts during the earlier of these intervals, the inferred size of the impactors, and the potential effects of these impacts on crustal development and life. The existence of this record implies that LHB did not end abruptly at 3.8-3.7 Ga but rather that high impact rates, either continuous or as impact clusters, persisted until at least the close of the Archean at 2.5 Ga. It implies that the shift from external, impact-related controls on the long-term development of the surface system on the Earth to more internal, geodynamic controls may have occurred much later in geologic history than has been supposed previously.

  20. In situ study of emerging metallicity on ion-bombarded SrTiO3 surface

    NASA Astrophysics Data System (ADS)

    Gross, Heiko; Bansal, Namrata; Kim, Yong-Seung; Oh, Seongshik

    2011-10-01

    We report how argon bombardment induces metallic states on the surface of insulating SrTiO3 at different temperatures by combining in situ conductance measurements and model calculations. At cryogenic temperatures, ionic bombardment created a thin-but much thicker than the argon-penetration depth-steady-state oxygen-vacant layer, leading to a highly-concentric metallic state. Near room temperatures, however, significant thermal diffusion occurred and the metallic state continuously diffused into the bulk, leaving only low concentration of electron carriers on the surface. Analysis of the discrepancy between the experiments and the models also provided evidence for vacancy clustering, which seems to occur during any vacancy formation process and affects the observed conductance.

  1. Effect of plasma ion bombardment on the reflectance of Io's trailing and leading hemispheres

    NASA Technical Reports Server (NTRS)

    Sack, N. J.; Baragiola, R. A.; Johnson, R. E.

    1993-01-01

    The possible effect of a net difference in the ion bombardment flux to the surface of Io on the ratio of the reflectance spectra is investigated. Io's vapor-deposited surface layers are simulated by a laboratory-produced film of vapor-deposited SO2 with a small admixture (about 3 percent) of H2S and (about 0.1 percent) H2O. It is shown that the reflectance ratio in the UV/visible of the surface bombarded by keV ions to the unbombarded surface is surprisingly similar to the observed ratio of Io's trailing to leading hemispherical reflectance. The changes produced are either structural or involve products of species originally present in the sample.

  2. Effects of Na2MoO4 and Na2WO4 on molybdenum and tungsten electrodes for the alkali metal thermoelectric converter (AMTEC)

    NASA Technical Reports Server (NTRS)

    Williams, R. M.; Wheeler, B. L.; Jeffries-Nakamura, B.; Loveland, M. E.; Bankston, C. P.

    1988-01-01

    The effects of adding Na2MoO4 and Na2WO4 to porous Mo and W electrodes, respectively, on the performance and impedance characteristics of the electrodes in an alkali metal thermoelectric converter (AMTEC) were investigated. It was found that corrosion of the porous electrode by Na2MoO4 or Na2WO4 to form Na2MO3O6 and WO2, respectively, and recrystallization of the Mo or W as the salt evaporates, result in major morphological changes including a loss of columnar structure and a significant increase in porosity. This effect is more pronounced in Na2MoO4/Mo electrodes, due to the lower stability of Na2MoO4.

  3. Corrosion behavior of aluminum doped diamond-like carbon thin films in NaCl aqueous solution.

    PubMed

    Khun, N W; Liu, E

    2010-07-01

    Aluminum doped diamond-like carbon (DLC:Al) thin films were deposited on n-Si(100) substrates by co-sputtering a graphite target under a fixed DC power (650 W) and an aluminum target under varying DC power (10-90 W) at room temperature. The structure, adhesion strength and surface morphology of the DLC:Al films were characterized by X-ray photoelectron spectroscopy (XPS), micro-scratch testing and atomic force microscopy (AFM), respectively. The corrosion performance of the DLC:Al films was investigated by means of potentiodynamic polarization testing in a 0.6 M NaCl aqueous solution. The results showed that the polarization resistance of the DLC:Al films increased from about 18 to 30.7 k(omega) though the corrosion potentials of the films shifted to more negative values with increased Al content in the films.

  4. A Study on the Failure of Conventional Deterrence: The Case Study of the Bombardment of Yeonpyeong in 2010

    DTIC Science & Technology

    2016-12-01

    December 2016 3. REPORT TYPE AND DATES COVERED Master’s thesis 4. TITLE AND SUBTITLE A STUDY ON THE FAILURE OF CONVENTIONAL DETERRENCE: THE CASE ...Approved for public release. Distribution is unlimited A STUDY ON THE FAILURE OF CONVENTIONAL DETERRENCE: THE CASE STUDY OF THE BOMBARDMENT OF...necessary to analyze these diverse elements comprehensively. E. RESEARCH DESIGN This thesis focuses on a single case study about the bombardment of

  5. Shoot Na+ Exclusion and Increased Salinity Tolerance Engineered by Cell Type–Specific Alteration of Na+ Transport in Arabidopsis[W][OA

    PubMed Central

    Møller, Inge S.; Gilliham, Matthew; Jha, Deepa; Mayo, Gwenda M.; Roy, Stuart J.; Coates, Juliet C.; Haseloff, Jim; Tester, Mark

    2009-01-01

    Soil salinity affects large areas of cultivated land, causing significant reductions in crop yield globally. The Na+ toxicity of many crop plants is correlated with overaccumulation of Na+ in the shoot. We have previously suggested that the engineering of Na+ exclusion from the shoot could be achieved through an alteration of plasma membrane Na+ transport processes in the root, if these alterations were cell type specific. Here, it is shown that expression of the Na+ transporter HKT1;1 in the mature root stele of Arabidopsis thaliana decreases Na+ accumulation in the shoot by 37 to 64%. The expression of HKT1;1 specifically in the mature root stele is achieved using an enhancer trap expression system for specific and strong overexpression. The effect in the shoot is caused by the increased influx, mediated by HKT1;1, of Na+ into stelar root cells, which is demonstrated in planta and leads to a reduction of root-to-shoot transfer of Na+. Plants with reduced shoot Na+ also have increased salinity tolerance. By contrast, plants constitutively expressing HKT1;1 driven by the cauliflower mosaic virus 35S promoter accumulated high shoot Na+ and grew poorly. Our results demonstrate that the modification of a specific Na+ transport process in specific cell types can reduce shoot Na+ accumulation, an important component of salinity tolerance of many higher plants. PMID:19584143

  6. Erosion and re-deposition of lithium and boron coatings under high-flux plasma bombardment

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Abrams, Tyler Wayne

    2015-01-01

    Lithium and boron coatings are applied to the walls of many tokamaks to enhance performance and protect the underlying substrates. Li and B-coated high-Z substrates are planned for use in NSTX-U and are a candidate plasma-facing component (PFC) for DEMO. However, previous measurements of Li evaporation and thermal sputtering on low-flux devices indicate that the Li temperature permitted on such devices may be unacceptably low. Thus it is crucial to characterize gross and net Li erosion rates under high-flux plasma bombardment. Additionally, no quantitative measurements have been performed of the erosion rate of a boron-coated PFC during plasma bombardment. Amore » realistic model for the compositional evolution of a Li layer under D bombardment was developed that incorporates adsorption, implantation, and diffusion. A model was developed for temperature-dependent mixed-material Li-D erosion that includes evaporation, physical sputtering, chemical sputtering, preferential sputtering, and thermal sputtering. The re-deposition fraction of a Li coating intersecting a linear plasma column was predicted using atomic physics information and by solving the Li continuity equation. These models were tested in the Magnum-PSI linear plasma device at ion fluxes of 10^23-10^24 m^-2 s^-1 and Li surface temperatures less than 800 degrees C. Li erosion was measured during bombardment with a neon plasma that will not chemically react with Li and the results agreed well with the erosion model. Next the ratio of the total D fluence to the areal density of the Li coating was varied to quantify differences in Li erosion under D plasma bombardment as a function of the D concentration. The ratio of D/Li atoms was calculated using the results of MD simulations and good agreement is observed between measurements and the predictions of the mixed-material erosion model. Li coatings are observed to disappear from graphite much faster than from TZM Mo, indicating that fast Li diffusion into

  7. Thermo-mechanical design aspects of mercury bombardment ion thrusters.

    NASA Technical Reports Server (NTRS)

    Schnelker, D. E.; Kami, S.

    1972-01-01

    The mechanical design criteria are presented as background considerations for solving problems associated with the thermomechanical design of mercury ion bombardment thrusters. Various analytical procedures are used to aid in the development of thruster subassemblies and components in the fields of heat transfer, vibration, and stress analysis. Examples of these techniques which provide computer solutions to predict and control stress levels encountered during launch and operation of thruster systems are discussed. Computer models of specific examples are presented.

  8. Formation of a highly doped ultra-thin amorphous carbon layer by ion bombardment of graphene.

    PubMed

    Michałowski, Paweł Piotr; Pasternak, Iwona; Ciepielewski, Paweł; Guinea, Francisco; Strupiński, Włodek

    2018-07-27

    Ion bombardment of graphene leads to the formation of defects which may be used to tune properties of the graphene based devices. In this work, however, we present that the presence of the graphene layer on a surface of a sample has a significant impact on the ion bombardment process: broken sp 2 bonds react with the incoming ions and trap them close to the surface of the sample, preventing a standard ion implantation. For an ion bombardment with a low impact energy and significant dose (in the range of 10 14 atoms cm -2 ) an amorphization of the graphene layer is observed but at the same time, most of the incoming ions do not penetrate the sample but stop at the surface, thus forming a highly doped ultra-thin amorphous carbon layer. The effect may be used to create thin layers containing desired atoms if no other technique is available. This approach is particularly useful for secondary ion mass spectrometry where a high concentration of Cs at the surface of a sample significantly enhances the negative ionization probability, allowing it to reach better detection limits.

  9. Formation of a highly doped ultra-thin amorphous carbon layer by ion bombardment of graphene

    NASA Astrophysics Data System (ADS)

    Piotr Michałowski, Paweł; Pasternak, Iwona; Ciepielewski, Paweł; Guinea, Francisco; Strupiński, Włodek

    2018-07-01

    Ion bombardment of graphene leads to the formation of defects which may be used to tune properties of the graphene based devices. In this work, however, we present that the presence of the graphene layer on a surface of a sample has a significant impact on the ion bombardment process: broken sp2 bonds react with the incoming ions and trap them close to the surface of the sample, preventing a standard ion implantation. For an ion bombardment with a low impact energy and significant dose (in the range of 1014 atoms cm‑2) an amorphization of the graphene layer is observed but at the same time, most of the incoming ions do not penetrate the sample but stop at the surface, thus forming a highly doped ultra-thin amorphous carbon layer. The effect may be used to create thin layers containing desired atoms if no other technique is available. This approach is particularly useful for secondary ion mass spectrometry where a high concentration of Cs at the surface of a sample significantly enhances the negative ionization probability, allowing it to reach better detection limits.

  10. Optimisation of the manufacturing process of tritide and deuteride targets used for neutron production

    NASA Astrophysics Data System (ADS)

    Monnin, Carole; Bach, Pierre; Tulle, Pierre Alain; van Rompay, Marc; Ballanger, Anne

    2002-03-01

    As a neutron tube manufacturer, SODERN is now in charge of manufacturing tritium targets for accelerators, in cooperation with CEA/DAM/DTMN in Valduc. Specific deuterium and tritium targets are manufactured on request, according to the requirements of the users, starting from titanium targets on copper substrates, and going to more sophisticated devices. The range of possible uses is wide, including thin targets for neutron calibration, thick targets with controlled loading of deuterium and tritium, rotating targets or large size rotating targets for higher lifetimes. The activity of the targets ranges from 3.7×10 10 to 3.7×10 13 Bq (1-1000 Ci), the diameter being up to 30 cm. Sodern and the CEA/Valduc centre have developed different technologies for tritium target manufacture, allowing the selection of the best configuration for each kind of use. In order to optimize the production of high energy neutrons, the performance of tritide and deuteride titanium targets made by different processes has been studied experimentally by bombardment with 120 and 350 kV deuterons provided by electrostatic accelerators. It is then possible to optimize either neutron output or lifetime and stability or thermal behaviour. The importance of the deposit evaporation conditions on the efficiency of neutron emission is clearly demonstrated, as well as the thermomechanical stability of the Ti thin film under deuteron bombardment. The main parameters involved in the target performance are discussed from a thermodynamical approach.

  11. The Problem of Form in Objects under Redevelopment (On the Basis of Bytom Market Square Redevelopment Design) / Problem Formy W Obiektach Przebudowywanych (Na Przykładzie Projektu Realizacyjnego Przebudowy Bytomskiego Rynku)

    NASA Astrophysics Data System (ADS)

    Maryńczuk, Paweł

    2015-03-01

    The author believes that if a designer has performed many design or research works entailing solutions to various problems, it is recommendable to consider and become aware of previously used methods whose application might have been unwitting or instinctive. The outcome of such reflection can be worth describing and recording in order to formulate a set of guidelines useful in the future. Such methods, being intuitive in nature, are often tied to the designer's subconsciousness, thus are rarely expressed in a clear manner. By using own methods a designer can prove that space should be composed in a given way in order to address specific needs and defined objectives. All this is aimed at preventing accidental formation of space. An example of reasoning serving the aforementioned purpose can be found in a method referred to as CQC or Composition Quality Control, the application of which facilitates intentional shaping of an architectural piece of work. Autor uważa uważa, że jeśli projektant ma za sobą wiele prac projektowych lub też prac badawczych, które połączone były z rozwiązywaniem różnych problemów, to warto zastanowić się i uświadomić sobie sposoby, które dotychczas - może nieświadomie lub odruchowo - były stosowane. Wynik refleksji warto opisać i zapisać po to, żeby ująć go w układ wskazań na przyszłość. Metody te, mając charakter intuicyjny, często związane są z podświadomością projektanta, w związku z tym rzadko można spotkać je jako wyrażone w sposób wyraźny. Stosując metody własne można dowieść, że przestrzeń winna być komponowana tak, a nie inaczej dla określonych potrzeb i wytyczonych celów tak, aby jej forma nie była przypadkowa. Przykładem takiego rozumowania jest przyjeta metoda KJK, której zastosowanie pomaga w swiadomym kształtowaniu dzieła architektonicznego.

  12. Improvement of electricity generating performance and life expectancy of MCFC stack by applying Li/Na carbonate electrolyte. Test results and analysis of 0.44 m 2/10 kW- and 1.03 m 2/10 kW-class stack

    NASA Astrophysics Data System (ADS)

    Yoshiba, Fumihiko; Morita, Hiroshi; Yoshikawa, Masahiro; Mugikura, Yoshihiro; Izaki, Yoshiyuki; Watanabe, Takao; Komoda, Mineo; Masuda, Yuji; Zaima, Nobuyuki

    Following the development of a 10 kW-class MCFC stack with a reactive area of 0.44 and 1.03 m 2, which applies a Li/Na carbonate electrolyte and a press stamping separator, many tests have now been carried out. In the installation tests, the observed cell voltages of the 0.44 m 2/10 kW-class stack agreed with the voltage predicted from the test results of the 100 cm 2 bench scale cell. This agreement proves that the installing procedure of the bench scale cell can be applied to the 0.44 m 2/10 kW-class stacks. The temperature distribution analysis model applied to the 100 kW-class stack was modified to calculate the temperature distribution of the 0.44 m 2/10 kW-class stack. Taking the heat loss and the heat transfer effect of the stack holder into account, the calculated temperature was close to the measured temperature; this result proves that the modification was adequate for the temperature analysis model. In the high current density operating tests on the 0.44 m 2/10 kW-class stack, an electrical power density of 2.46 kW/m 2 was recorded at an operating current density of 3000 A/m 2. In the endurance test on the 0.44 m 2/10 kW-class stack, however, unexpected Ni shortening occurred during the operating period 2500-4500 h, which had been caused by a defective formation of the electrolyte matrix. The shortening seems to have been caused by the crack, which appeared in the electrolyte matrix. The voltage degradation rate of the 0.44 m 2/10 kW-class stack was 0.52% over 1000 h, which proves that the matrix was inadequate for a long life expectancy of the MCFC stack. A final endurance test was carried out on the 1.03 m 2/10 kW-class stack, of which the matrix had been revised. The fuel utilisation and the leakage of anode gas never changed during the 10,000 h operating test. This result suggests that no shortening occurred during the 10,000 h endurance test. The cell voltage degradation rate was around 0.2-0.3% over 1000 h in the 1.03 m 2/10 kW-class stack

  13. Aluminum work function: Effect of oxidation, mechanical scraping and ion bombardment

    NASA Technical Reports Server (NTRS)

    Vinet, P.; Lemogne, T.; Montes, H.

    1985-01-01

    Surface studies have been performed on aluminum polycrystalline surfaces which have been mechanically scraped. Such studies were initiated in order to understand surface effects occurring in tribological processes which involve rubbing surfaces and the effects of adsorption of oxygen. To characterize the surfaces, the following three different experimental approaches have been used: (1) X.P.S. (X-ray photoelectron spectroscopy), in order to check the cleanliness of the surfaces and follow the adsorption and oxidation kinetics; (2) Analysis of the work function changes by following the energy spectra of secondary electrons emitted under low energy electron bombardment; and (3) Analysis of photoemission intensities under U.V. excitation. The reference state being chosen to be the surface cleaned by ion bombardment and exposures to oxygen atmospheres have been shown to lower the work function of clean polycrystalline aluminum by 1.2 eV. The oxygen pressure is found to affect only the kinetics of these experiments. Mechanical scraping has been shown to induce a decrease ( 0.3 eV) in the work function, which could sharply modify the kinetics of adsorption on the surface.

  14. A Reliable Method of Completing and Compensating the Results of Measurements of Flow Parameters in a Network of Headings / O Pewnej Metodzie Uzupełniania I Wyrównywania Wyników Pomiarów Parametrów Przepływu W Sieci Wyrobisk Górniczych

    NASA Astrophysics Data System (ADS)

    Dziurzyński, Wacław; Krach, Andrzej; Pałka, Teresa

    2015-03-01

    pressure values on the basis of the available results of measurements carried out in adjacent nodes, as well as the pressure value calculated on the basis of the heading geometry and the given volumetric flow rate. The present paper discusses the methodology of compensating and balancing the volumetric air flow rates within a network of headings (Chapter 2) and the methodology of determining pressure values (Chapter 3) in the nodes of the network. The developed calculation algorithms - verified by means of sample calculations performed for a selected area of a mine ventilation network - were introduced into the VentGraph software system. The calculation results were presented in tabular form. The Summary section discusses the minuses and pluses of the adopted methodology. Podstawą prognozy procesu przewietrzania jest posługiwanie się zwalidowanym programem komputerowym (Dziurzyński i in., 2011; Pritchard, 2010) oraz poprawnie przygotowaną bazą danych zawierającą parametry opisujące przepływ powietrza i gazów, zgodną z przyjętym modelem matematycznym w programie komputerowym VentGraph (Dziurzyński, 2002). Dysponując bazą danych pomiarowych oraz przyjętym do obliczeń komputerowych i symulacji procesu przewietrzania modelem matematycznym przystępujemy do opracowania modelu numerycznego dla wybranej sieci wyrobisk kopalni. Przygotowanie modelu numerycznego sieci wentylacyjnej danej kopalni wymaga dostarczenia zestawu danych dotyczących struktury sieci i własności fizycznych jej elementów, tj. wyrobisk, wentylatorów, tam, a przy symulacji pożaru dodatkowo wymagane jest podanie parametrów opisujących ognisko pożaru oraz własności skał górotworu. Obecna praktyka postępowania polega na tym, że wykonuje się ręczne pomiary wentylacyjne w wyrobiskach górniczych, a uzyskane wyniki stanowią podstawę do wyznaczenia parametrów fizycznych takich jak: opór aerodynamiczny wyrobiska, gęstość przepływającego powietrza i

  15. Efficiency of Particle-Bombardment-Mediated Transformation Is Influenced by Cell Cycle Stage in Synchronized Cultured Cells of Tobacco 1

    PubMed Central

    Iida, Asako; Yamashita, Toshiya; Yamada, Yasuyuki; Morikawa, Hiromichi

    1991-01-01

    Plasmid DNA pB1221 harboring β-glucuronidase gene was delivered to synchronized cultured tobacco (Nicotiana tabacum L. cv Bright Yellow-2) cells of different cell cycle stages by a pneumatic particle gun. The cells bombarded at M and G2 phases gave 4 to 6 times higher transformation efficiency than those bombarded at the S and G1 phases. ImagesFigure 2 PMID:16668589

  16. Electron Bombardment Ion Thruster

    NASA Image and Video Library

    1970-08-21

    Researchers at the Lewis Research Center had been studying different methods of electric rocket propulsion since the mid-1950s. Harold Kaufman created the first successful engine, the electron bombardment ion engine, in the early 1960s. Over the ensuing decades Lewis researchers continued to advance the original ion thruster concept. A Space Electric Rocket Test (SERT) spacecraft was launched in June 1964 to test Kaufman’s engine in space. SERT I had one cesium engine and one mercury engine. The suborbital flight was only 50 minutes in duration but proved that the ion engine could operate in space. This was followed in 1966 by the even more successful SERT II, which operated on and off for over ten years. Lewis continued studying increasingly more powerful ion thrusters. These electric engines created and accelerated small particles of propellant material to high exhaust velocities. Electric engines have a very small amount of thrust and are therefore not capable of lifting a spaceship from the surface of the Earth. Once lofted into orbit, however, electric engines are can produce small, continuous streams of thrust for several years.

  17. Slow positron beam production by a 14 MeV C.W. electron accelerator

    NASA Astrophysics Data System (ADS)

    Begemann, M.; Gräff, G.; Herminghaus, H.; Kalinowsky, H.; Ley, R.

    1982-10-01

    A 14 MeV c.w. electron accelerator is used for pair production in a tungsten target of 0.7 radiation lengths thickness. A small fraction of the positrons is thermalized and diffuses out of the surface ofsurface of a well annealed tungsten foil coated with MgO which is positioned immediately behind the target. The slow positrons are extracted from the target region and magnetically guided over a distance of 10 m onto a channelplate multiplier at the end of an S-shaped solenoid. The positrons are identified by their annihilation radiation using two NaI-detectors. The intensity of the slow positrons is proportional to the accelerator electron beam current. The maximum intensity of 2.2 × 10 5 slow positrons per second reaching thedetector at an accelerator current of 15 μA was limited by the power deposited in the uncooled target. The energy of the positrons is concentrated in a small region at about 1 eV and clearly demonstrates the emission of thermal positrons.

  18. Feasibility Analysis of Groundwater Abstraction for Gas Shale Fracturing in the Lublin Basin (Eastern Poland) / Ocena Możliwości Poboru Wód Podziemnych Do Szczelinowania Łupków Gazonośnych W Basenie Lubelskim (Wschodnia Polska)

    NASA Astrophysics Data System (ADS)

    Duda, Robert; Macuda, Jan

    2015-03-01

    szczelinowania skał. Zabiegi te realizowane są przy wykorzystaniu dużych ilości cieczy szczelinujących, które w 90.5% składają się z wody, 9.0% piasku podsadzkowego (proppant) oraz 0.5% różnych substancji chemicznych, niezbędnych do utrzymania właściwych parametrów technologicznych cieczy. Zapotrzebowanie na wodę do szczelinowania wzrasta wraz ze zwiększeniem zwięzłości i głębokości zalegania łupków gazonośnych. W związku z tym właściciele koncesji na eksploatację gazu ze skał łupkowych oczekują informacji o możliwościach poboru wód podziemnych w celu szczelinowania. W pracy przedstawiono ocenę realnych możliwości poboru wód podziemnych do przygotowania cieczy szczelinujących dla otworów eksploatacyjnych gazu niekonwencjonalnego w obszarze basenu lubelskiego, będącego rejonem perspektywicznej eksploatacji gazu z łupków ordowiku i syluru (dolny paleozoik). Możliwości poboru wody zbadano na podstawie oczekiwanych wydajności jednostkowych studni ujmujących wody głównego użytkowego poziomu wodonośnego (GUPW) w rejonie badań. GUPW na przeważającej części tego obszaru związany jest ze skałami górnej kredy - spękanymi marglami, kredą, opokami, wapieniami i gezami, a także utworami czwartorzędu i trzeciorzędu. Znajomość wartości wydatku jednostkowego umożliwia zaprojektowanie ujęcia stosownie do określonych potrzeb. Witczak et al. (1999) proponują przyjęcie wydatku jednostkowego studni (q), jako obiektywnej danej empirycznej cechującej się wysokim wskaźnikiem pewności, w celu charakterystyki wodonośności poziomów wodonośnych w skali regionalnej. Przestrzenną ocenę wartości q oparto na danych zestawionych w 7 arkuszach Mapy hydrogeologicznej Polski w skali 1:200,000 (MHP). Dane dotyczyły q uzyskiwanych przy określonych maksymalnych depresjach poziomu wody. Obliczono q studni ujmujących wodę z GUPW w formacjach kredy górnej, trzeciorzędu i czwartorzędu, w granicach obszarów arkuszy MHP lub ich cz

  19. Treatment of PVC using an alternative low energy ion bombardment procedure

    NASA Astrophysics Data System (ADS)

    Rangel, Elidiane C.; dos Santos, Nazir M.; Bortoleto, José Roberto R.; Durrant, Steven F.; Schreiner, Wido H.; Honda, Roberto Y.; Rangel, Rita de Cássia C.; Cruz, Nilson C.

    2011-12-01

    In many applications, polymers have progressively substituted traditional materials such as ceramics, glasses, and metals. Nevertheless, the use of polymeric materials is still limited by their surface properties. Frequently, selective modifications are necessary to suit the surface to a given application. Amongst the most common treatments, plasma immersion ion implantation (PIII) has attracted the attention of many researchers owing to its versatility and practicality. This method, however, requires a power supply to provide high voltage (tens of kV) negative pulses, with a controlled duty cycle, width and frequency. Owing to this, the implementation of PIII on the industrial scale can become economically inviable. In this work, an alternative plasma treatment that enables low energy ion bombardment without the need of a high voltage pulse generator is presented. To evaluate the efficiency of the treatment of polymers, polyvinylchloride, PVC, specimens were exposed to 5 Pa argon plasmas for 3600 s, at excitation powers, P, of between 10 and 125 W. Through contact angle and atomic force microscopy data, the influence of P on the wettability, surface free energy and roughness of the samples was studied. Surface chemical composition was measured by X-ray photoelectron spectroscopy, XPS. To evaluate the effect of aging under atmospheric conditions, contact angle and XPS measurements were performed one and 1334 days after the treatment. The plasma potential and ion density around the driven electrode were determined from Langmuir probe measurements while the self-bias potential was derived with the aid of an oscilloscope. From these data it was possible to estimate the mean energy of ions bombarding the PVC surface. Chlorine, carbon and oxygen contamination were detected on the surface of the as-received PVC. Upon exposure to the plasma, the proportion of chlorine was observed to decrease while that of oxygen increased. Consequently, the wettability and surface energy

  20. The State Policy for Natural Gas Sector / Sektor Gazu Ziemnego W Polityce Państwa

    NASA Astrophysics Data System (ADS)

    Szurlej, Adam

    2013-09-01

    This article reviews the state policy for natural gas sector. A particular attention has been given to how the assumptions of gas demand, import volumes and gas production from domestic reserves have developed in strategic documents. The restructuring of natural gas sector has been brought closer on the example of PGNiG S.A. (Polish Oil and Gas Company), and changes in the domestic gas market resulting from the implementation of EU law have been discussed as well. Major changes in the domestic gas market in the period of 1990-2011 have been presented along with the cooperation between Poland and Russia regarding the natural gas supply for the Polish market. W artykule dokonano przeglądu polityki państwa wobec sektora gazu ziemnego. W sposób szczególny przeanalizowano jak kształtowały się w dokumentach strategicznych prognozy w zakresie zapotrzebowania na gaz, wielkości importu i wydobycia gazu ze złóż krajowych. Przybliżono także restrukturyzację sektora gazu ziemnego na przykładzie PGNiG oraz zmiany na krajowym rynku gazu wynikające z implementacji prawa UE. Wskazano najważniejsze zmiany na krajowym rynku gazu ziemnego w latach 1990-2011 oraz scharakteryzowano współpracę polsko - rosyjską w zakresie dostaw gazu do Polski.

  1. High energy primary knock-on process in metal deuterium systems initiated by bombardment with noble gas ions

    NASA Astrophysics Data System (ADS)

    Gann, V. V.; Tolstolutskaya, G. D.

    2008-08-01

    An experimental study confirms the possibility of nuclear fusion reactions initiating in metal-deuterium targets by bombarding them with ions that are not the reagents of the fusion reaction, in particular, with noble gas ions. The yields of (d,d) and (d,t) reactions were measured as functions of energy (0.4-3.2 MeV) and mass of incident ions (He +, Ne +, Ar +, Kr + and Xe +). Irradiation by heavy ions produced a number of energetic deuterium atoms in the deuteride and deuterium + tritium metal targets. At ion energies of ˜0.1-1 MeV the d-d reaction yields are relatively high. A model of nuclear fusion reaction cross-sections in atomic collision cascades initiated by noble gas ion beam in metal-deuterium target is developed. The method for calculation tritium or deuterium recoil fluxes and the yield of d-d fusion reaction in subsequent collisions was proposed. It was shown that D(d,p)t and D(t,n) 4He reactions mainly occur in energy region of the recoiled D-atom from 10 keV to 250 keV. The calculated probabilities of d-d and d-t fusion reactions were found to be in a good agreement with the experimental data.

  2. Stability Assessment of the High Safety Pillars in Slovenian Natural Stone Mines / Ocena Stabilności Wysokich Filarów Bezpieczeństwa W Kopalniach Kamieni Naturalnych W Słowenii

    NASA Astrophysics Data System (ADS)

    Kortnik, Jože

    2015-03-01

    (wapień), w 2008 kamieniołom Lipica I (wapień), w roku 2009 wapień pozyskiwać także zaczęto z kamieniołomu w Dolinie. Działo się to głównie z uwagi na strukturę geologiczną w tych miejscach, warunki geologiczne kamieniołomów, potencjalnie grube warstwy nadkładu w przypadku rozszerzania działalności w części odkrywkowej kamieniołomu, a także rosnący popyt na te surowce (kamień naturalny). Podziemne wydobycie kamieni naturalnych we wszystkich tych lokalizacjach odbywa się za pomocą zmodyfikowanej metody filarowo- komorowej, dostosowanej do uwarunkowań poszczególnych lokalizacji, z wykorzystaniem układu mniej lub bardziej regularnie rozmieszczonych filarów zabezpieczających. Ponieważ podziemne wydobycie naturalnych bloków skalnych odbywa się stosunkowo płytko pod powierzchnią, (na głębokościach rzędu 10-40 m), to wartości pierwotnego naprężenia pionowego są stosunkowo niewielkie (poniżej 1.0 MPa). Wskutek tego powstaje poważne ryzyko odrywania się od stropu bloków skalnych w kształcie klinów, zwłaszcza w dużych, otwartych komorach podziemnych. W latach ubiegłych instalowano układy monitorujące stan naprężeń i odkształceń, wykorzystywane przy planowaniu wymiarów (szerokości i wysokości) dużych, otwartych, przestrzennych komór podziemnych oraz wymiarów filarów zabezpieczających, a także układy zapewniające stałą kontrolę i wykrywanie niestabilności w obrębie stropu oraz w ścianach bocznych komór. Niniejsza praca zawiera przegląd metod i urządzeń wykorzystywanych do optymalizacji i bezpieczeństwa monitorowania stanu filarów zabezpieczających w podziemnych kopalniach kamieni naturalnych w Słowenii.

  3. Neutron production for 250 MeV protons bombarding on thick grain-made tungsten target

    NASA Astrophysics Data System (ADS)

    Zhang, Xueying; Zhang, Yanbin; Ma, Fei; Ju, Yongqin; Chen, Liang; Zhang, Hongbin; Li, Yanyan; Wan, Bo; Wang, Jianguo; Ge, Honglin

    2015-08-01

    Neutron yield for 250 MeV protons incident on a tungsten target has been measured using the water bath method. The target was made of many randomly placed tungsten grains. Through analyzing the activity of Au foils, the neutron flux distribution in water was obtained. The neutrons slowing down process shows that the neutrons from tungsten have an average energy lower than neutrons from the lead target. The neutron yield was experimentally determined to be 2.02 ± 0.15 neutron/proton. Detailed simulation was also performed with the Geant4 toolkit. Comparison has been made with the experimentally derived neutron yield. It was found that, around 250 MeV, experimental results were described satisfactorily with a combination of high-energy spallation, low-energy neutron reaction and scattering. It was shown that the grain-packed target does not affect much the main neutronic properties, which are of crucial importance for the design of the spallation target.

  4. In-Situ atomic force microscopic observation of ion beam bombarded plant cell envelopes

    NASA Astrophysics Data System (ADS)

    Sangyuenyongpipat, S.; Yu, L. D.; Brown, I. G.; Seprom, C.; Vilaithong, T.

    2007-04-01

    A program in ion beam bioengineering has been established at Chiang Mai University (CMU), Thailand, and ion beam induced transfer of plasmid DNA molecules into bacterial cells (Escherichia coli) has been demonstrated. However, a good understanding of the fundamental physical processes involved is lacking. In parallel work, onion skin cells have been bombarded with Ar+ ions at energy 25 keV and fluence1-2 × 1015 ions/cm2, revealing the formation of microcrater-like structures on the cell wall that could serve as channels for the transfer of large macromolecules into the cell interior. An in-situ atomic force microscope (AFM) system has been designed and installed in the CMU bio-implantation facility as a tool for the observation of these microcraters during ion beam bombardment. Here we describe some of the features of the in-situ AFM and outline some of the related work.

  5. Demonstration of a high-intensity neutron source based on a liquid-lithium target for Accelerator based Boron Neutron Capture Therapy.

    PubMed

    Halfon, S; Arenshtam, A; Kijel, D; Paul, M; Weissman, L; Berkovits, D; Eliyahu, I; Feinberg, G; Kreisel, A; Mardor, I; Shimel, G; Shor, A; Silverman, I; Tessler, M

    2015-12-01

    A free surface liquid-lithium jet target is operating routinely at Soreq Applied Research Accelerator Facility (SARAF), bombarded with a ~1.91 MeV, ~1.2 mA continuous-wave narrow proton beam. The experiments demonstrate the liquid lithium target (LiLiT) capability to constitute an intense source of epithermal neutrons, for Accelerator based Boron Neutron Capture Therapy (BNCT). The target dissipates extremely high ion beam power densities (>3 kW/cm(2), >0.5 MW/cm(3)) for long periods of time, while maintaining stable conditions and localized residual activity. LiLiT generates ~3×10(10) n/s, which is more than one order of magnitude larger than conventional (7)Li(p,n)-based near threshold neutron sources. A shield and moderator assembly for BNCT, with LiLiT irradiated with protons at 1.91 MeV, was designed based on Monte Carlo (MCNP) simulations of BNCT-doses produced in a phantom. According to these simulations it was found that a ~15 mA near threshold proton current will apply the therapeutic doses in ~1h treatment duration. According to our present results, such high current beams can be dissipated in a liquid-lithium target, hence the target design is readily applicable for accelerator-based BNCT. Copyright © 2015 Elsevier Ltd. All rights reserved.

  6. Ion bombardment and adsorption studies on ilmenite (FeTiO3) by X-ray photoelectron spectroscopy

    NASA Technical Reports Server (NTRS)

    Schulze, P. D.

    1983-01-01

    The effects of 5 KeV argon and oxygen ion bombardment on FeTiO3 (ilmenite) at low temperatures have been studied using X-ray photoelectron spectroscopy (XPS). Also, using this same technique, the adsorption of O2, NO, N2O, and CO at 300 K and the adsorption of O2 and D2O at 150K have been studied. Argon and oxygen ion bombardment of ilmenite have confirmed earlier studies on metal oxides that argon ions generally reduce the anion species while oxygen ions generally oxidize the anion species. The two iron states involved were Fe sup +2 and Fe sup O. The reduction of Ti sup +4 was not verified although a significant shift in the Ti(2p1,3) binding energies toward the metallic state was observed after oxygen ion bombardment at low temperatures. At temperatures above 150K, O2 adsorbs dissociatively on ilmenite while D2O adsorbs molecularly below 170K. Above 300 K No, N2O, and CO do not appear to adsorb dissociatively. Low temperature adsorption of D2O was found to be inhibited by predosing the ilmenite with O2.

  7. Packaging of wavelength stabilized 976nm 100W 105µm 0.15 NA fiber coupled diode lasers

    NASA Astrophysics Data System (ADS)

    Jiang, Xiaochen; Liu, Rui; Gao, Yanyan; Zhang, Tujia; He, Xiaoguang; Zhu, Jing; Zhang, Qiang; Yang, Thomas; Zhang, Cuipeng

    2016-03-01

    Fiber coupled diode lasers are widely used in many fields now especially as pumps in fiber laser systems. In many fiber laser applications, high brightness pumps are essential to achieve high brightness fiber lasers. Furthermore, 976nm wavelength absorption band is narrow with Yb3+ doped fiber lasers which is more challenging for controlling wavelength stabilized in diode laser modules. This study designed and implemented commercial available high brightness and narrow wavelength width lasers to be able to use in previous mentioned applications. Base on multiple single emitters using spatial and polarization beam combining as well as fiber coupling techniques, we report a wavelength stabilized, 105μm NA 0.15 fiber coupled diode laser package with 100W of optical output power at 976 nm, which are 14 emitters inside each multiple single emitter module. The emitting aperture of the combined lasers output are designed and optimized for coupling light into a 105μm core NA 0.15 fiber. Volume Bragg grating technology has been used to improve spectral characteristics of high-power diode lasers. Mechanical modular design and thermal simulation are carried out to optimize the package. The spectral width is roughly 0.5 nm (FWHM) and the wavelength shift per °C < 0.02nm. The output spectrum is narrowed and wavelength is stabilized using Volume Bragg gratings (VBGs). The high brightness package has an electrical to optical efficiency better than 45% and power enclosure more than 90% within NA 0.12. Qualification tests have been included on this kind of package. Mechanical shock, vibration and accelerated aging tests show that the package is reliability and the MTTF is calculated to be more than 100k hours at 25°C.

  8. X-ray microscopy using reflection targets based on SEM with tungsten filament

    NASA Astrophysics Data System (ADS)

    Liu, Junbiao; Ma, Yutian; Zhao, Weixia; Niu, Geng; Chu, Mingzhang; Yin, Bohua; Han, Li; Liu, Baodong

    2016-10-01

    X-ray MicroandNano imaging is developed based on the conventional x-ray tomography, it can not only provide nondestructive testing with higher resolution measurement, but also be used to examine the material or the structure with low atomic number and low density. The source with micro-focal spot size is one of the key components of x-ray MicroandNano imaging. The focused electron beam from SEM bombarding the metal target can generate x-ray with ultra-small size. It is convenient to set up x-ray microscopy based on SEM for laboratory use. This paper describes a new x-ray microscopy using reflection targets based on FEI Quanta600 SEM with tungsten filament. The flat panel detector is placed outside of the vacuum chamber with 300μm thickness Be-window to isolate vacuum from the air. A stage with 3 DOFs is added to adjust the positions of the target, the SEM's sample stage is used to move sample. And the shape of target is designed as cone with 60° half cone angle to get the maximum x-ray dosage. The attenuation coefficient of Bewindow for x-ray is about 25%. Finally, the line pair card is used to evaluate the resolution and the result shows that the resolution of the system can receive less than 750nm, when the acceleration voltage is 30keV, the beam current is 160nA, the SEM working distance is 5mm and the acquisition time of the detector is 60s.

  9. FTIR and Vis-FUV real time spectroscopic ellipsometry studies of polymer surface modifications during ion beam bombardment

    NASA Astrophysics Data System (ADS)

    Laskarakis, A.; Gravalidis, C.; Logothetidis, S.

    2004-02-01

    The continuously increasing application of polymeric materials in many scientific and technological fields has motivated an extensive use of polymer surface treatments, which modify the physical and chemical properties of polymer surfaces leading to surface activation and promotion of the surface adhesion. Fourier transform IR spectroscopic ellipsometry (FTIRSE) and phase modulated ellipsometry (PME) in the IR and Vis-FUV spectral regions respectively have been employed for in situ and real time monitoring of the structural changes on the polymer surface obtained by Ar + ion bombardment. The polymers were industrially supplied polyethylene terephthalate (PET) and polyethylene naphthalate (PEN) membranes. The Ar + ion bombardment has found to change the chemical bonding of the films and especially the amount of the CO, C-C and CC groups. The detailed study of the FTIRSE spectra reveals important information about the effect of the Ar + ion bombardment on each of the above bonding groups. Also, the modification of the characteristic features, attributed to electronic transitions in specific bonds of PET and PEN macromolecules, has been studied using PME.

  10. A review of electron bombardment thruster systems/spacecraft field and particle interfaces

    NASA Technical Reports Server (NTRS)

    Byers, D. C.

    1978-01-01

    Information on the field and particle interfaces of electron bombardment ion thruster systems was summarized. Major areas discussed were the nonpropellant particles, neutral propellant, ion beam, low energy plasma, and fields. Spacecraft functions and subsystems reviewed were solar arrays, thermal control systems, optical sensors, communications, science, structures and materials, and potential control.

  11. Metal-assisted SIMS and cluster ion bombardment for ion yield enhancement

    NASA Astrophysics Data System (ADS)

    Heile, A.; Lipinsky, D.; Wehbe, N.; Delcorte, A.; Bertrand, P.; Felten, A.; Houssiau, L.; Pireaux, J.-J.; De Mondt, R.; Van Vaeck, L.; Arlinghaus, H. F.

    2008-12-01

    In addition to structural information, a detailed knowledge of the local chemical environment proves to be of ever greater importance, for example for the development of new types of materials as well as for specific modifications of surfaces and interfaces in multiple fields of materials science or various biomedical and chemical applications. But the ongoing miniaturization and therefore reduction of the amount of material available for analysis constitute a challenge to the detection limits of analytical methods. In the case of time-of-flight secondary ion mass spectrometry (TOF-SIMS), several methods of secondary ion yield enhancement have been proposed. This paper focuses on the investigation of the effects of two of these methods, metal-assisted SIMS and polyatomic primary ion bombardment. For this purpose, thicker layers of polystyrene (PS), both pristine and metallized with different amounts of gold, were analyzed using monoatomic (Ar +, Ga +, Xe +, Bi +) and polyatomic (SF 5+, Bi 3+, C 60+) primary ions. It was found that polyatomic ions generally induce a significant increase of the secondary ion yield. On the other hand, with gold deposition, a yield enhancement can only be detected for monoatomic ion bombardment.

  12. Simulation-Assisted Evaluation of Grinding Circuit Flowsheet Design Alternatives: Aghdarreh Gold Ore Processing Plant / Ocena Alternatywnych Schematów Technologicznych Procesu Rozdrabniania W Zakładach Przeróbki Rud Złota W Aghdarreh, Z Wykorzystaniem Metod Symulacji

    NASA Astrophysics Data System (ADS)

    Farzanegan, A.; Ghalaei, A. Ebtedaei

    2015-03-01

    modification. Surowy urobek z kopalni rud złota Aghdarreh musi najpierw zostać poddany rozdrobnieniu, aby zapewnić efektywniejsze uwalnianie cząsteczek złota. W chwili obecnej obiegi rozdrabniania obejmują kruszenie jednostopniowe z wykorzystaniem kruszarek szczękowych oraz kruszenie jednostopniowe z użyciem kruszarek półautomatycznych w obiegu zamkniętym z hydrocyklonem. Odzysk złota odbywa się przy zastosowaniu procesu ługowania, z zastosowaniem metody cyjankowej w szeregu mieszalników. W pracy tej przeprowadzono optymalizację procesu rozdrabniania rud w zakładach przeróbczych Aghdarreh prowadzonego w celu zmniejszenia rozmiarów uzyskiwanych cząsteczek złota (Ps0) z 70 μm do ok. 40 μm poprzez zapewnienie ciągłości procesu, z wykorzystaniem metod modelowania i symulacji. Na podstawie dwóch zestawów próbek z ciągu technologicznego rozdrabniania, rozkłady wielkości cząstek zostały statystycznie zrównoważone z wykorzystaniem oprogramowania NorBal. Pierwszy i drugi zbiór danych otrzymanych na podstawie dwóch zestawów próbek wykorzystany został do kalibracji i walidacji modeli, przed przystąpieniem do właściwych badań symulacyjnych z użyciem oprogramowania MODSIM. Symulacje komputerowe przeprowadzono w celu oceny wydajności dwóch proponowanych ciągów technologicznych. Pierwszy ciąg obejmuje istniejące kruszarki półautomatyczne i nowo proponowaną kruszarkę kulową pracującą w obiegu zamkniętym z hydrocyklonem. Drugi rozważany ciąg stanowi istniejąca kruszarka półautomatyczna, następnie proponowana kruszarka kulowa pracująca w obiegu zamkniętym z istniejącym hydrocyklonem. We wszystkich symulacjach bazowano na modelach SAGT, CYCL i MILL do symulacji pracy kruszarek półautomatycznych, pakietu hydrocyklonu oraz pojedynczych kruszarek. Modele SAGT i MILL oparte są na modelu zrównoważonej populacji w procesie rozdrabniania. Model CYCL opiera się na empirycznym modelu klasyfikacji Plitta

  13. Effects of ion irradiation on the mechanical properties of SiNa wO xC yH z sol-gel derived thin films

    NASA Astrophysics Data System (ADS)

    Lucca, D. A.; Qi, Y.; Harriman, T. A.; Prenzel, T.; Wang, Y. Q.; Nastasi, M.; Dong, J.; Mehner, A.

    2010-10-01

    A study of the effects of ion irradiation of hybrid organic/inorganic modified silicate thin films on their mechanical properties is presented. NaOH catalyzed SiNa wO xC yH z thin films were synthesized by sol-gel processing from tetraethylorthosilicate (TEOS) and methyltriethoxysilane (MTES) precursors and spin-coated onto Si substrates. After drying at 300 °C, the films were irradiated with 125 keV H + or 250 keV N 2+ at fluences ranging from 1 × 10 14 to 2.5 × 10 16 ions/cm 2. Nanoindentation was used to characterize the films. Changes in hardness and reduced elastic modulus were examined as a function of ion fluence and irradiating species. The resulting increases in hardness and reduced elastic modulus are compared to similarly processed acid catalyzed silicate thin films.

  14. Encapsulation methods for solid radionuclide production targets at a medium-energy cyclotron facility

    NASA Astrophysics Data System (ADS)

    Steyn, Gideon; Vermeulen, Christiaan; Isaacs, Eugene

    2018-05-01

    The techniques employed at iThemba LABS for the encapsulation of solid radionuclide production targets, based on cold indentation welding, electron beam welding and laser welding, are described. Some aspects of the target holders and cooling requirements to bombard targets in a tandem configuration with a 66 MeV proton beam, with intensities up to nominally 250 A, are also briefly discussed. These techniques are inter alia suitable for a production regimen compatible with the new generation of commercial, high-intensity 70 MeV cyclotrons.

  15. Electron-bombarded CCD detectors for ultraviolet atmospheric remote sensing

    NASA Technical Reports Server (NTRS)

    Carruthers, G. R.; Opal, C. B.

    1983-01-01

    Electronic image sensors based on charge coupled devices operated in electron-bombarded mode, yielding real-time, remote-readout, photon-limited UV imaging capability are being developed. The sensors also incorporate fast-focal-ratio Schmidt optics and opaque photocathodes, giving nearly the ultimate possible diffuse-source sensitivity. They can be used for direct imagery of atmospheric emission phenomena, and for imaging spectrography with moderate spatial and spectral resolution. The current state of instrument development, laboratory results, planned future developments and proposed applications of the sensors in space flight instrumentation is described.

  16. Cosmogenic 180W variations in meteorites and re-assessment of a possible 184Os-180W decay system

    NASA Astrophysics Data System (ADS)

    Cook, David L.; Kruijer, Thomas S.; Leya, Ingo; Kleine, Thorsten

    2014-09-01

    We measured tungsten (W) isotopes in 23 iron meteorites and the metal phase of the CB chondrite Gujba in order to ascertain if there is evidence for a large-scale nucleosynthetic heterogeneity in the p-process isotope 180W in the solar nebula as recently suggested by Schulz et al. (2013). We observed large excesses in 180W (up to ≈ 6 ε) in some irons. However, significant within-group variations in magmatic IIAB and IVB irons are not consistent with a nucleosynthetic origin, and the collateral effects on 180W from an s-deficit in IVB irons cannot explain the total variation. We present a new model for the combined effects of spallation and neutron capture reactions on 180W in iron meteorites and show that at least some of the observed within-group variability is explained by cosmic ray effects. Neutron capture causes burnout of 180W, whereas spallation reactions lead to positive shifts in 180W. These effects depend on the target composition and cosmic-ray exposure duration; spallation effects increase with Re/W and Os/W ratios in the target and with exposure age. The correlation of 180W/184W with Os/W ratios in iron meteorites results in part from spallogenic production of 180W rather than from 184Os decay, contrary to a recent study by Peters et al. (2014). Residual ε180W excesses after correction for an s-deficit and for cosmic ray effects may be due to ingrowth of 180W from 184Os decay, but the magnitude of this ingrowth is at least a factor of ≈2 smaller than previously suggested. These much smaller effects strongly limit the applicability of the putative 184Os-180W system to investigate geological problems.

  17. Origin of the cataclysmic Late Heavy Bombardment period of the terrestrial planets.

    PubMed

    Gomes, R; Levison, H F; Tsiganis, K; Morbidelli, A

    2005-05-26

    The petrology record on the Moon suggests that a cataclysmic spike in the cratering rate occurred approximately 700 million years after the planets formed; this event is known as the Late Heavy Bombardment (LHB). Planetary formation theories cannot naturally account for an intense period of planetesimal bombardment so late in Solar System history. Several models have been proposed to explain a late impact spike, but none of them has been set within a self-consistent framework of Solar System evolution. Here we propose that the LHB was triggered by the rapid migration of the giant planets, which occurred after a long quiescent period. During this burst of migration, the planetesimal disk outside the orbits of the planets was destabilized, causing a sudden massive delivery of planetesimals to the inner Solar System. The asteroid belt was also strongly perturbed, with these objects supplying a significant fraction of the LHB impactors in accordance with recent geochemical evidence. Our model not only naturally explains the LHB, but also reproduces the observational constraints of the outer Solar System.

  18. Effects of lithium-implantation on the hydrogen retention in both a-C:H and a-SiC:H materials submitted to deuterium bombardment

    NASA Astrophysics Data System (ADS)

    Barbier, G.; Ross, G. G.; El Khakani, M. A.; Chevarier, N.; Chevarier, A.

    1997-02-01

    The hydrogen release in plasma facing materials is a challenging problem for the hydrogen recycling. The hydrogen desorption from the a-C:H and a-SiC:H materials induced by deuterium bombardment has been investigated. Prior to the deuterium bombardment, both materials were implanted with different fluences of lithium ions. Before and after each irradiation, depth profiles of H, Li and deuterium were determined by nuclear microanalysis. After deuterium bombardment, it is shown that the retention of the initial hydrogen in both materials was enhanced by increasing the total dose of the implanted Li. For the a-C:H samples, the hydrogen desorption under deuterium bombardment was strongly reduced by lithium implantation. This effect was also evidenced in a-SiC:H samples, even though it is less spectacular than in a-C:H. Also, nuclear analyses showed that the retained dose of deuterium decreases when the lithium concentration increases. This could be a result of the formation of LiH bonds which occurs to the detriment of deuterium retention in both a-C:H and a-SiC:H materials. Preliminary results of both materials exposed to TdeV tokamak discharges confirms the role of Li in hydrogen retention, already observed in deuterium bombardment exposure.

  19. Co-Precipitation Synthesis and Optical Properties of Mn4+-Doped Hexafluoroaluminate w-LED Phosphors

    PubMed Central

    Geitenbeek, Robin G.; Meijerink, Andries

    2017-01-01

    Mn4+-activated hexafluoroaluminates are promising red-emitting phosphors for white light emitting diodes (w-LEDs). Here, we report the synthesis of Na3AlF6:Mn4+, K3AlF6:Mn4+ and K2NaAlF6:Mn4+ phosphors through a simple two-step co-precipitation method. Highly monodisperse large (~20 μm) smoothed-octahedron shaped crystallites are obtained for K2NaAlF6:Mn4+. The large size, regular shape and small size distribution are favorable for application in w-LEDs. All Mn4+-doped hexafluoroaluminates show bright red Mn4+ luminescence under blue light excitation. We compare the optical properties of Na3AlF6:Mn4+, K3AlF6:Mn4+ and K2NaAlF6:Mn4+ at room temperature and 4 K. The luminescence measurements reveal that multiple Mn4+ sites exist in M3AlF6:Mn4+ (M = Na, K), which is explained by the charge compensation that is required for Mn4+ on Al3+ sites. Thermal cycling experiments show that the site distribution changes after annealing. Finally, we investigate thermal quenching and show that the luminescence quenching temperature is high, around 460–490 K, which makes these Mn4+-doped hexafluoroaluminates interesting red phosphors for w-LEDs. The new insights reported on the synthesis and optical properties of Mn4+ in the chemically and thermally stable hexafluoroaluminates can contribute to the optimization of red-emitting Mn4+ phosphors for w-LEDs. PMID:29149083

  20. Report on the deuterium retention in CVD coated W on SiC in support of the Ultramet Company’s Small Business Innovation Research (SBIR) project: SOW DE-FG02-07ER84941

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Masashi Shimada

    2012-06-01

    A tungsten (W) coated (0.0005-inch thickness) silicon carbide (SiC) (1.0-inch diameter and 0.19-inch thickness) sample was exposed to a divertor relevant high-flux (~1022 m-2s-1) deuterium plasma at 200 and 400°C in the Idaho National Laboratory’s (INL’s) Tritium Plasma Experiment (TPE), and the total deuterium retention was subsequently measured via the thermal desorption spectroscopy (TDS) method. The deuterium retentions were 6.4x1019 m-2 and 1.7x1020 m-2, for 200 and 400°C exposure, respectively. The Tritium Migration Analysis Program (TMAP) was used to analyze the measured TDS spectrum to investigate the deuterium behavior in the W coated SiC, and the results indicated that mostmore » of the deuterium was trapped in the W coated layer even at 400°C. This thin W layer (0.0005-inch ~ 13µm thickness) prevented deuterium ions from bombarding directly into the SiC substrate, minimizing erosion of SiC and damage creation via ion bombardment. The shift in the D desorption peak in the TDS spectra from 200 C to 400°C can be attributed to D migration to the bulk material. This unexpectedly low deuterium retention and short migration might be due to the porous nature of the tungsten coating, which can decrease the solution concentration of deuterium atoms.« less

  1. Summary of Test Results From a 1 kW(sub e)-Class Free-Piston Stirling Power Convertor Integrated With a Pumped NaK Loop

    NASA Technical Reports Server (NTRS)

    Briggs, Maxwell H.; Geng, Steven M.; Pearson, J. Boise; Godfroy, Thomas J.

    2010-01-01

    As a step towards development of Stirling power conversion for potential use in Fission Surface Power (FSP) systems, a pair of commercially available 1 kW class free-piston Stirling convertors was modified to operate with a NaK liquid metal pumped loop for thermal energy input. This was the first-ever attempt at powering a free-piston Stirling engine with a pumped liquid metal heat source and is a major FSP project milestone towards demonstrating technical feasibility. The tests included performance mapping the convertors over various hot and cold-end temperatures, piston amplitudes and NaK flow rates; and transient test conditions to simulate various start-up and fault scenarios. Performance maps of the convertors generated using the pumped NaK loop for thermal input show increases in power output over those measured during baseline testing using electric heating. Transient testing showed that the Stirling convertors can be successfully started in a variety of different scenarios and that the convertors can recover from a variety of fault scenarios.

  2. The SPES High Power ISOL production target

    NASA Astrophysics Data System (ADS)

    Andrighetto, A.; Corradetti, S.; Ballan, M.; Borgna, F.; Manzolaro, M.; Scarpa, D.; Monetti, A.; Rossignoli, M.; Silingardi, R.; Mozzi, A.; Vivian, G.; Boratto, E.; De Ruvo, L.; Sattin, N.; Meneghetti, G.; Oboe, R.; Guerzoni, M.; Margotti, A.; Ferrari, M.; Zenoni, A.; Prete, G.

    2016-11-01

    SPES (Selective Production of Exotic Species) is a facility under construction at INFN-LNL (Istituto Nazionale di Fisica Nucleare - Laboratori Nazionali di Legnaro), aimed to produce intense neutron-rich radioactive ion beams (RIBs). These will be obtained using the ISOL (Isotope Separation On-Line) method, bombarding a uranium carbide target with a proton beam of 40MeV energy and currents up to 200μA. The target configuration was designed to obtain a high number of fissions, up to 1013 per second, low power deposition and fast release of the produced isotopes. The exotic isotopes generated in the target are ionized, mass separated and re-accelerated by the ALPI superconducting LINAC at energies of 10AMeV and higher, for masses in the region of A = 130 amu , with an expected rate on the secondary target up to 109 particles per second. In this work, recent results on the R&D activities regarding the SPES RIB production target-ion source system are reported.

  3. ATR-FTIR spectroscopy for the determination of Na4EDTA in detergent aqueous solutions.

    PubMed

    Suárez, Leticia; García, Roberto; Riera, Francisco A; Diez, María A

    2013-10-15

    Fourier transform infrared spectroscopy in the attenuated total reflectance mode (ATR-FTIR) combined with partial last square (PLS) algorithms was used to design calibration and prediction models for a wide range of tetrasodium ethylenediaminetetraacetate (Na4EDTA) concentrations (0.1 to 28% w/w) in aqueous solutions. The spectra obtained using air and water as a background medium were tested for the best fit. The PLS models designed afforded a sufficient level of precision and accuracy to allow even very small amounts of Na4EDTA to be determined. A root mean square error of nearly 0.37 for the validation set was obtained. Over a concentration range below 5% w/w, the values estimated from a combination of ATR-FTIR spectroscopy and a PLS algorithm model were similar to those obtained from an HPLC analysis of NaFeEDTA complexes and subsequent detection by UV absorbance. However, the lowest detection limit for Na4EDTA concentrations afforded by this spectroscopic/chemometric method was 0.3% w/w. The PLS model was successfully used as a rapid and simple method to quantify Na4EDTA in aqueous solutions of industrial detergents as an alternative to HPLC-UV analysis which involves time-consuming dilution and complexation processes. © 2013 Elsevier B.V. All rights reserved.

  4. Determination of Critical Conditions of Spontaneous Combustion of Coal in Longwall Gob Areas / Wyznaczanie Warunków Krytycznych Samozapalania Węgla W Zrobach Ścian

    NASA Astrophysics Data System (ADS)

    Cygankiewicz, Janusz

    2015-09-01

    Decades of experience in the fight against endogenous fire hazard in coal mines indicate a major influence of certain conditions in a given area of the mine on the possibility of fire occurrence, such as: susceptibility of coals to spontaneous combustion, oxygen content in the air incoming to the self-heating coal, conditions of heat exchange between the self-heating coal mass and the environment This paper presents a numerical method for determining the critical conditions of spontaneous combustion of coal in longwall gob areas, i.e. conditions under which spontaneous combustion may occur. It has been assumed that crushed coal in the gob has a shape of a flat layer adjacent from the roof and floor side to the rocks. Our considerations have been limited to coals containing small amount of moisture. A simple model of oxidation kinetics on the coal surface expressed by the Arrhenius equation has been adopted. This model assumes that oxidation rate is independent of the amount of oxygen absorbed by coal. The rate of reaction depends only on temperature, with the parameters of the equation changing after the coal has reached the critical temperature. The article presents also a mathematical model of spontaneous heating of the coal layer in the gob area. It describes the heat balance in the coal as well as the oxygen and heat balance in the flowing gases. The model consists of a system of differential equations which are solved using numerical techniques. The developed computer program enables to perform the relevant calculations. In this paper, on the example of coal from a seam 405, we present the method for determining the following critical parameters of the layer of crushed coal: thickness of the layer, oxygen content in a stream of gases flowing through the layer and thermal conductivity of surrounding rocks. Wieloletnie doświadczenie w zakresie zwalczania zagrożenia pożarem endogenicznym w kopalniach wskazują na zasadniczy wpływ na możliwość zaistnienia

  5. DiMES Tests of W Leading Edge Power Loading in DIII-D

    NASA Astrophysics Data System (ADS)

    Nygren, R. E.; Watkins, J. G.; Rudakov, D. L.; Lasnier, C. J.; Pitts, R. A.; Stangeby, P. C.

    2015-11-01

    In a transient melt experiment in JET, the power to a ~1-mm-high leading edge on a W lamella in the bulk-W outer divertor was lower than expected from the geometry by factors of 5 and 2 for L-mode and H-mode discharges, respectively. We checked this surprising result in DIII-D with 3 W blocks (10 mm square) mounted radially side-by-side in DiMES with leading edges of 0.0, 0.3, 1.0 mm, single null L-mode plasmas, OSP just outside ``0.0'' block, limited scans (NBI+ECH), B-field incident at 1.5° or 2.5°, and viewed, as in JET, from above with 0.2mm/pixel resolution IRTV. Langmuir probes measured parallel power to the target. We compared probe and IR data with a detailed thermal model of the blocks and concluded provisionally that we did not reproduce the power deficit found in JET. Blurred IR images complicated fitting of temperature distributions from the thermal model. We plan an experiment with both L- and H-mode He plasmas before the APS meeting. Supported by US DOE under DE-AC04-94AL85000, 44500007360, DE-AC52-07NA27344, and DE-FC02-04ER54698.

  6. Engineering catalytic activity via ion beam bombardment of catalyst supports for vertically aligned carbon nanotube growth

    NASA Astrophysics Data System (ADS)

    Islam, A. E.; Nikolaev, P.; Amama, P. B.; Zakharov, D.; Sargent, G.; Saber, S.; Huffman, D.; Erford, M.; Semiatin, S. L.; Stach, E. A.; Maruyama, B.

    2015-09-01

    Carbon nanotube growth depends on the catalytic activity of metal nanoparticles on alumina or silica supports. The control on catalytic activity is generally achieved by variations in water concentration, carbon feed, and sample placement on a few types of alumina or silica catalyst supports obtained via thin film deposition. We have recently expanded the choice of catalyst supports by engineering inactive substrates like c-cut sapphire via ion beam bombardment. The deterministic control on the structure and chemistry of catalyst supports obtained by tuning the degree of beam-induced damage have enabled better regulation of the activity of Fe catalysts only in the ion beam bombarded areas and hence enabled controllable super growth of carbon nanotubes. A wide range of surface characterization techniques were used to monitor the catalytically active surface engineered via ion beam bombardment. The proposed method offers a versatile way to control carbon nanotube growth in patterned areas and also enhances the current understanding of the growth process. With the right choice of water concentration, carbon feed and sample placement, engineered catalyst supports may extend the carbon nanotube growth yield to a level that is even higher than the ones reported here, and thus offers promising applications of carbon nanotubes in electronics, heat exchanger, and energy storage.

  7. Plasma properties in electron-bombardment ion thrusters

    NASA Technical Reports Server (NTRS)

    Matossian, J. N.; Beattie, J. R.

    1987-01-01

    The paper describes a technique for computing volume-averaged plasma properties within electron-bombardment ion thrusters, using spatially varying Langmuir-probe measurements. Average values of the electron densities are defined by integrating the spatially varying Maxwellian and primary electron densities over the ionization volume, and then dividing by the volume. Plasma properties obtained in the 30-cm-diameter J-series and ring-cusp thrusters are analyzed by the volume-averaging technique. The superior performance exhibited by the ring-cusp thruster is correlated with a higher average Maxwellian electron temperature. The ring-cusp thruster maintains the same fraction of primary electrons as does the J-series thruster, but at a much lower ion production cost. The volume-averaged predictions for both thrusters are compared with those of a detailed thruster performance model.

  8. Prospection for Copper Mineralization with Contribution of Remote Sensing, Geochemical and Mineralographical Data in Abhar 1:100,000 Sheet, NW Iran / Poszukiwania ZASOBÓW Rud Miedzi Z Zastosowaniem Zdalnych Technik WYKORZYSTUJĄCYCH Dane Geochemiczne i Mineralogiczne W POKŁADZIE Geologicznym Abhar 1:100,000 W PÓŁNOCNO-ZACHODNIM Iranie

    NASA Astrophysics Data System (ADS)

    Nouri, Reza; Jafari, Mohammadreza; Arian, Mehran; Feizi, Faranak; Afzal, Peyman

    2013-12-01

    Abhar 1:100,000 sheet is located within the Cenozoic Tarom volcano-plutonic belt, NW Iran. The present study is based on the integration of remote sensing techniques on Advanced Spaceborne Thermal Emission and Reflection Radiometer (ASTER), geochemical data analysis consisting of stream sediment and lithogeochemical samples, within geological field observations and mineralographical studies to identify Cu prospect. On ASTER data; using a number of selected methods including band ratio, Least Square Fit (LS-Fit) and Minimum Noise Fraction (MNF) distinguished alternation zones. These methods revealed that three types of alterations: argillic, phyllic, and iron oxide zones occurring at the NE and SE of Abhar sheet, while the propylitic and silica zones are developed in NW and SW of the studied area. Lineaments were identified by aid of false color composite, high pass filters and hill-shade DEM techniques that two NW-SE and NE-SW major trends were determined. Geochemical anomalies were separated by number-size (N-S) method. Interpretation of N-S log-log plots of Cu in the area may be a result of the three steps of enrichment, i.e., mineralization and later dispersions. Field checks and Mineralgraphical studies also confirm the existence of suitable copper mineralization. Pokład geologiczny Abhar 1:100,100 zlokalizowany jest w obrębie kenozoicznego pasa skał magmowych pochodzenia wulkanicznego Tarom w północno-zachodnim Iranie. W pracy przedstawiono połączenie zastosowań metod zdalnych wykorzystujących technologię ASTER (Advanced Spaceborne Thermal Emission and Refelection Radiometer), analizę danych geochemicznych zebranych na podstawie osadów dennych ze strumieni oraz próbek skał w obrębie pola obserwacji a także danych mineralogicznych w celu rozpoznania skupisk rud miedzi. Na podstawie danych uzyskanych przy użyciu technologiiASTER i poddanych obróbce przy użyciu różnorodnych technik: badanie układu pasm, dopasowanie metodę najmniejszych

  9. Transformation of triploid bermudagrass (Cynodon dactylon x C. transvaalensis cv. TifEagle) by means of biolistic bombardment.

    PubMed

    Zhang, G; Lu, S; Chen, T A; Funk, C R; Meyer, W A

    2003-06-01

    A transformation system for triploid bermudagrass ( Cynodon dactylon x C. transvaalensis cv. TifEagle) was established with a biolistic bombardment delivery system. Embryogenic callus was induced from stolons and maintained on Murashige and Skoog's medium supplemented with 30 microM dicamba, 20 microM benzylaminopurine, and 100 mg/l myo-inositol. Using the hygromycin phosphotransferase ( hpt) gene as the selectable marker gene, we obtained 75 transgenic lines from 18 petri dishes bombarded. Integration of the hpt gene into genomic DNA and transcription of hpt was confirmed by Southern and Northern blot analyses, respectively. Through suspension culture screening, we obtained homogeneously transformed plants showing stable transcription of the hpt gene.

  10. Angular distributions of absorbed dose of Bremsstrahlung and secondary electrons induced by 18-, 28- and 38-MeV electron beams in thick targets.

    PubMed

    Takada, Masashi; Kosako, Kazuaki; Oishi, Koji; Nakamura, Takashi; Sato, Kouichi; Kamiyama, Takashi; Kiyanagi, Yoshiaki

    2013-03-01

    Angular distributions of absorbed dose of Bremsstrahlung photons and secondary electrons at a wide range of emission angles from 0 to 135°, were experimentally obtained using an ion chamber with a 0.6 cm(3) air volume covered with or without a build-up cap. The Bremsstrahlung photons and electrons were produced by 18-, 28- and 38-MeV electron beams bombarding tungsten, copper, aluminium and carbon targets. The absorbed doses were also calculated from simulated photon and electron energy spectra by multiplying simulated response functions of the ion chambers, simulated with the MCNPX code. Calculated-to-experimental (C/E) dose ratios obtained are from 0.70 to 1.57 for high-Z targets of W and Cu, from 15 to 135° and the C/E range from 0.6 to 1.4 at 0°; however, the values of C/E for low-Z targets of Al and C are from 0.5 to 1.8 from 0 to 135°. Angular distributions at the forward angles decrease with increasing angles; on the other hand, the angular distributions at the backward angles depend on the target species. The dependences of absorbed doses on electron energy and target thickness were compared between the measured and simulated results. The attenuation profiles of absorbed doses of Bremsstrahlung beams at 0, 30 and 135° were also measured.

  11. Visualization of Multidimensional Data in Purpose of Qualitative Classification of Various Types of Coal / Wizualizacja Wielowymiarowych Danych W Celu Klasyfikacji JAKOŚCIOWEJ RÓŻNYCH TYPÓW WĘGLA

    NASA Astrophysics Data System (ADS)

    Niedoba, Tomasz; Jamróz, Dariusz

    2013-12-01

    . Surowce mineralne, które podlegają wzbogacaniu w celu ich lepszego wykorzystania mogą być (charakteryzują się) charakteryzowane wieloma wskaźnikami opisującymi ich, interesujące przeróbkarza, cechy. Podstawowymi cechami są wielkość ziaren oraz ich gęstość, które decydują o przebiegu rozdziału zbiorów ziaren (nadaw) i efektach takiego rozdziału. Rozdział prowadzi się z reguły, w celu uzyskania produktów o zróżnicowanych wartościach średnich wybranej cechy, która zwykle charakteryzowana jest zawartością określonego składnika surowca wyznaczoną na drodze analiz chemicznych. Takie podejście do surowca mineralnego prowadzi do potraktowania go jako wielowymiarowego wektora X = [X1, …, Xn]. Zasadniczym problemem jest także wybór jednostki populacji generalnej (ziarno, jednostka objętości lub masy), co może decydować o kierunkach charakteryzowania wielowymiarowych powiązań cech wektora X. Takimi kierunkami charakteryzowania mogą być: - wielowymiarowe rozkłady wektora losowego X wraz ze wszystkimi konsekwencjami metody (Lyman, 1993; Niedoba, 2009; 2011; Olejnik et al., 2010; Niedoba & Surowiak, 2012); - wielowymiarowe równania regresji wraz z analizą macierzy współczynników korelacji liniowej oraz korelacji cząstkowej (Niedoba, 2013); - analiza czynnikowa (Tumidajski & Saramak, 2009); - inne metody, w tym wizualizacja metodą tuneli obserwacyjnych (Jamróz, 2001), osi równoległych oraz wizualizacja zależności pomiędzy wielowymiarowymi bryłami (Jamróz, 2009). Wielowymiarowe rozkłady wektora X traktowanego jako wektor losowy, mają już swoją bogatą literaturę i praktyczne ich zastosowanie i nie będą przedmiotem tej publikacji. Pozostałe metody są ze sobą w pewien sposób powiązane, co skrótowo zostało przedstawione w artykule. Macierze współczynników korelacji liniowej i współczynników korelacji cząstkowej są związane, z reguły, z istniejącymi modelami liniowymi zależności występujących mi

  12. Simulation Based Investigation of Different Fleet Management Paradigms in Open Pit Mines-A Case Study of Sungun Copper Mine / Symulacje I Badania Różnych Paradygmatów Wykorzystania Floty Pojazdów I Urządzeń W Kopalniach Odkrywkowych. Studium Przypadku: Kopalnia Miedzi W Sungun

    NASA Astrophysics Data System (ADS)

    Hashemi, Ali Saadatmand; Sattarvand, Javad

    2015-03-01

    Using simulation modeling, different management systems of the open pit mining equipment including non-dispatching, dispatching and blending solutions have been studied for the Sungun copper mine. Developed model has the capability of considering detailed features of both loading and hauling equipment. Productivity assessment scenarios have been established on the constructed model and the outputs revealed the noteworthy impact of the match factor of the trucks to the loaders on the production rate by over 40%. A dispatching simulation model with the objective function of minimizing truck waiting times have been developed and 7.8% improvement obtained by applying a flexible assignment of the trucks for the loaders compared to the fixed assignment system. Finally ore grade blending control unit has been introduced into the model. Getting the advantages of the newly added module it became possible to monitor the portion of material excavated from different operating benches and control truck dispatching rules for keeping the overall ore grade exactly at desired value. Przy użyciu modeli symulacyjnych zbadano różnorodne systemy zarządzania flotą pojazdów i urządzeń w kopalni odkrywkowej (wydawanie dyspozycji przewozu, wstrzymywanie przewozu oraz rozwiązania kwestii mieszania o rud o różnej zawartości pierwiastka użytecznego) na przykładzie kopalni miedzi Sungun. Opracowany model uwzględnia szczegółowe cechy sprzętu przeładunkowego oraz transportowego. Na podstawie modelu opracowano następnie scenariusze oceny wydajności, a wyniki jednoznacznie wykazały wielką wagę odpowiedniego skojarzenia ilości pojazdów i ładowarek. Opracowano model symulacyjny kierowania urządzeń do pracy, jako funkcję celu przyjmujący minimalizacje czasu przestoju ciężarówek. Uzyskano wynik lepszy o 7.8% poprzez elastyczne przydzielania pojazdów do ładowarek w porównaniu do systemu trwałego ich do siebie przypisania. W ostatnim etapie

  13. Enhanced upconversion emission in colloidal (NaYF4:Er(3+))/NaYF4 core/shell nanoparticles excited at 1523 nm.

    PubMed

    Shao, Wei; Chen, Guanying; Damasco, Jossana; Wang, Xianliang; Kachynski, Aliaksandr; Ohulchanskyy, Tymish Y; Yang, Chunhui; Ågren, Hans; Prasad, Paras N

    2014-03-15

    In this work, we report on efficient visible and near-IR upconversion emissions in colloidal hexagonal-phase core/shell NaYF4:Er(3+)/NaYF4 nanoparticles (∼38  nm) under IR laser excitation at 1523 nm. Varying amounts of Er(3+) dopants were introduced into the core NaYF4:Er(3+) nanoparticles, revealing an optimized Er(3+) concentration of 10% for the highest luminescent efficiency. An inert epitaxial shell layer of NaYF4 grown onto the core of the NaYF4:Er(3+) 10% nanoparticle increased its upconversion emission intensity fivefold due to suppression of surface-related quenching mechanisms, yielding the absolute upconversion efficiency to be as high as ∼3.9±0.3% under an excitation density of 18  W/cm(2). The dependence of the intensity of upconversion emission peaks on laser excitation density in the core/shell nanoparticle displayed "saturation effects" at low excitation density in the range of 1.5-18  W/cm(2), which again demonstrates high upconversion efficiency.

  14. Efficient pump module coupling >1kW from a compact detachable fiber

    NASA Astrophysics Data System (ADS)

    Dogan, M.; Chin, R. H.; Fulghum, S.; Jacob, J. H.; Chin, A. K.

    2018-02-01

    In the most developed fiber amplifiers, optical pump power is introduced into the 400μm-diameter, 0.46NA first cladding of the double-clad, Yb-doped, gain fiber, using a (6+1):1 multi-mode fiber combiner. For this configuration, the core diameter and numerical aperture of the pump delivery fibers have maximum values of 225μm and 0.22, respectively. This paper presents the first fiber-coupled laser-diode pump module emitting more than 1kW of claddingmode- stripped power from a detachable 225μm, 0.22NA delivery fiber at 976nm. The electrical-to-optical power conversion efficiency at 1kW is 50%. The FWHM spectral width at 1kW output is 4nm and has an excellent overlap with the narrow absorption spectrum of ytterbium in glass. Six of these pump modules attached to a (6+1):1 multimode combiner enable a 5-6kW, single-mode, Yb-doped fiber amplifier.

  15. The effects of energetic proton bombardment on polymeric materials: Experimental studies and degradation models

    NASA Technical Reports Server (NTRS)

    Coulter, D. R.; Gupta, A.; Smith, M. V.; Fornes, R. E.

    1986-01-01

    This report describes 3 MeV proton bombardment experiments on several polymeric materials of interest to NASA carried out on the Tandem Van De Graff Accelerator at the California Institute of Technology's Kellogg Radiation Laboratory. Model aromatic and aliphatic polymers such as poly(1-vinyl naphthalene) and poly(methyl methacrylate), as well as polymers for near term space applications such as Kapton, Epoxy and Polysulfone, have been included in this study. Chemical and physical characterization of the damage products have been carried out in order to develop a model of the interaction of these polymers with the incident proton beam. The proton bombardment methodology developed at the Jet Propulsion Laboratory and reported here is part of an ongoing study on the effects of space radiation on polymeric materials. The report is intended to provide an overview of the mechanistic, as well as the technical and experimental, issues involved in such work rather than to serve as an exhaustive description of all the results.

  16. Adsorption Site of Gas Molecules on Defective Armchair Graphene Nanoribbon Formed Through Ion Bombardment

    NASA Astrophysics Data System (ADS)

    Auzar, Zuriana; Johari, Zaharah; Sakina, S. H.; Alias, N. Ezaila

    2018-02-01

    High sensitivity and selectivity is desired in sensing devices. The aim of this study is to investigate the use of the ion bombardment process in creating a defect on graphene nanoribbons (GNR), which significantly affects sensing properties, in particular adsorption energy, charge transfer and sensitivity. A process has been developed to form the defect on the GNR surface using molecular dynamic (MD) with a reactive force field with nitrogen ion. The sensing properties were calculated using the extended Huckel theory when oxygen (O2) and ammonia (NH3) molecules are exposed to different areas on the defective site. Through simulation, it was found that the ion bombardment process formed various types of defects on the GNR surface. Most notably, molecules adsorbed on the ripple area considerably improve the sensitivity by more than 50%. This indicates that the defect on the armchair graphene nanoribbon (AGNR) surface can be a method to enhance graphene-based sensing performance.

  17. Engineering catalytic activity via ion beam bombardment of catalyst supports for vertically aligned carbon nanotube growth

    DOE PAGES

    Islam, A. E.; Zakharov, D.; Stach, E. A.; ...

    2015-09-16

    Carbon nanotube growth depends on the catalytic activity of metal nanoparticles on alumina or silica supports. The control on catalytic activity is generally achieved by variations in water concentration, carbon feed, and sample placement on a few types of alumina or silica catalyst supports obtained via thin film deposition. We have recently expanded the choice of catalyst supports by engineering inactive substrates like c-cut sapphire via ion beam bombardment. The deterministic control on the structure and chemistry of catalyst supports obtained by tuning the degree of beam-induced damage have enabled better regulation of the activity of Fe catalysts only inmore » the ion beam bombarded areas and hence enabled controllable super growth of carbon nanotubes. A wide range of surface characterization techniques were used to monitor the catalytically active surface engineered via ion beam bombardment. The proposed method offers a versatile way to control carbon nanotube growth in patterned areas and also enhances the current understanding of the growth process. As a result, with the right choice of water concentration, carbon feed and sample placement, engineered catalyst supports may extend the carbon nanotube growth yield to a level that is even higher than the ones reported here, and thus offers promising applications of carbon nanotubes in electronics, heat exchanger, and energy storage.« less

  18. Study of the Radiative Recombination of Free Carriers Produced by Electron Bombardment in Cadmium Sulfide (thesis); ETUDE DE LA RECOMBINAISON RADIATIVE DES PORTEURS LIBRES PRODUITS PAR UN BOMBARDEMENT ELECTRONIQUE DANS LE SULFURE DE CADMIUM (THESES)

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    de Gaalon, G.

    1962-01-01

    The structure of the blue emission at the temperature of liquid nitrogen was studied using improved apparatus. The observations were carried to the temperature of liquid He in order to deduce the mechanism of the recombination of the free carriers. Before analysis of the light emitted by CdS single crystals exposed to electron bombardment and before a description of the experimental apparatus, the interaction of electron beams with the crystal and the resultant formation of free carriers are studied theoretically. The experimental study showed that the structure of the emission situated at the absorption limit, obtained by electron bombardment, doesmore » not differ basically from that observed under uv irradiation. However, the existence at 4 deg K of radiation (not observed with uv irradiation) with wave lengths less than 4.856 A was shown. (J.S.R.)« less

  19. High-power fiber-coupled 100W visible spectrum diode lasers for display applications

    NASA Astrophysics Data System (ADS)

    Unger, Andreas; Küster, Matthias; Köhler, Bernd; Biesenbach, Jens

    2013-02-01

    Diode lasers in the blue and red spectral range are the most promising light sources for upcoming high-brightness digital projectors in cinemas and large venue displays. They combine improved efficiency, longer lifetime and a greatly improved color space compared to traditional xenon light sources. In this paper we report on high-power visible diode laser sources to serve the demands of this emerging market. A unique electro-optical platform enables scalable fiber coupled sources at 638 nm with an output power of up to 100 W from a 400 μm NA0.22 fiber. For the blue diode laser we demonstrate scalable sources from 5 W to 100 W from a 400 μm NA0.22 fiber.

  20. Transient expression of GUS in bombarded embryogenic longleaf, loblolly, and eastern white pine

    Treesearch

    Alex M. Diner; Allan Zipf; Rufina Ward; Yinghua Huang; George Brown

    1999-01-01

    Embryogenic tissue cultures derived from immature zygotic embryos of longleaf, loblolly, and eastern white pine were maintained in culture for up to 2 years, then bombarded with gold particles coated with a gene construct containing the GUS reporter gene fused to an adenine methyltransferase promoter from an algal virus. Physiological expression of GUS was observed in...

  1. 120W, NA_0.15 fiber coupled LD module with 125-μm clad/NA 0.22 fiber by spatial coupling method

    NASA Astrophysics Data System (ADS)

    Ishige, Yuta; Kaji, Eisaku; Katayama, Etsuji; Ohki, Yutaka; Gajdátsy, Gábor; Cserteg, András.

    2018-02-01

    We have fabricated a fiber coupled semiconductor laser diode module by means of spatial beam combining of single emitter broad area semiconductor laser diode chips in the 9xx nm band. In the spatial beam multiplexing method, the numerical aperture of the output light from the optical fiber increases by increasing the number of laser diodes coupled into the fiber. To reduce it, we have tried the approach to improving assembly process technology. As a result, we could fabricate laser diode modules having a light output power of 120W or more and 95% power within NA of 0.15 or less from a single optical fiber with 125-μm cladding diameter. Furthermore, we have obtained that the laser diode module maintaining high coupling efficiency can be realized even around the fill factor of 0.95. This has been achieved by improving the optical alignment method regarding the fast axis stack pitch of the laser diodes in the laser diode module. Therefore, without using techniques such as polarization combining and wavelength combining, high output power was realized while keeping small numerical aperture. This contributes to a reduction in unit price per light output power of the pumping laser diode module.

  2. RMP effects on the W and C erosion/deposition balance on W test samples in DIII-D

    NASA Astrophysics Data System (ADS)

    Hinson, E. T.; Frerichs, H.; Schmitz, O.; Evans, T. E.; Guo, H. Y.; Thomas, D. M.; Rudakov, D. L.; Abrams, T.; Unterberg, E. A.; Briesemeister, A.; Lasnier, C. J.; McLean, A. G.; Makowski, M.; Wampler, W. R.; Watkins, J. G.; Wang, H. Q.

    2016-10-01

    Clear evidence for alteration of the W and C erosion by resonant magnetic perturbation (RMP) fields has been obtained in an experiment exposing W-coated DiMES samples in the DIII-D divertor to outer strike point (OSP) sweeps in comparable series of discharges with and without the application of RMP. Gross erosion measurements of W and C during these sweeps using the S/XB method show that the 3-D boundary induced by the RMP significantly alters the erosion rate from DiMES. In particular, application of RMP smooths radial W erosion anisotropy seen for the axisymmetric case, where the W erosion rate for the OSP sweep in the outward direction significantly exceeds the erosion rate observed for the subsequent inward radial sweep over the sample. This finding is likely related to a change in the W/C erosion and redeposition balance in the C-dominated wall environment at DIII-D. Moreover, non-axisymmetric plasma structure on the W sample has to be considered. This challenge will be further examined by comparison of experimental results to EMC3-EIRENE modeling. Work supported by US DOE DE-SC0013911, DE-FC02-04ER54698, DE-FH02-07ER54917, DE-AC05-06OR23100, DE-AC05-00OR22725, DE-AC52-07NA27344, and DE-AC04-94AL85000.

  3. Merging W W and W W + jet with Minlo

    DOE PAGES

    Hamilton, Keith; Melia, Tom; Monni, Pier Francesco; ...

    2016-09-12

    We present a simulation program for the production of a pair of W bosons in association with a jet, that can be used in conjunction with general-purpose shower Monte Carlo generators, according to the Powheg method. We have further adapted and implemented the Minlo ' method on top of the NLO calculation underlying our W + W - + jet generator. Thus, the resulting simulation achieves NLO accuracy not only for inclusive distributions in W + W - + jet production but also W + W - production, i.e. when the associated jet is not resolved, without the introduction ofmore » any unphysical merging scale. This work represents the first extension of the Minlo ' method, in its original form, to the case of a genuine underlying 2 → 2 process, with non-trivial virtual corrections.« less

  4. Crystallization of D-mannitol in binary mixtures with NaCl: phase diagram and polymorphism.

    PubMed

    Telang, Chitra; Suryanarayanan, Raj; Yu, Lian

    2003-12-01

    To study the crystallization, polymorphism, and phase behavior of D-mannitol in binary mixtures with NaCl to better understand their interactions in frozen aqueous solutions. Differential scanning calorimetry, hot-stage microscopy, Raman microscopy, and variable-temperature X-ray diffractometry were used to characterize D-mannitol-NaCl mixtures. NaCl and D-mannitol exhibited significant melt miscibility (up to 7.5% w/w or 0.20 mole fraction of NaCl) and a eutectic phase diagram (eutectic composition 7.5% w/w NaCl; eutectic temperature 150 degrees C for the alpha and beta polymorphs of D-mannitol and 139 degrees C for the delta). The presence of NaCl did not prevent mannitol from crystallizing but, depending on sample size, affected the polymorph crystallized: below 10 mg, delta was obtained; above 100 mg, alpha was obtained. Pure mannitol crystallized under the same conditions first as the delta polymorph and then as the a polymorph, with the latter nucleating on the former. KCl showed similar eutectic points and melt miscibility with D-mannitol as NaCl. LiCl yielded lower eutectic melting points, inhibited the crystallization of D-mannitol during cooling, and enabled the observation of its glass transition. Despite their structural dissimilarity, significant melt miscibility exists between D-mannitol and NaCl. Their phase diagram has been determined and features polymorph-dependent eutectic points. NaCl influences the polymorphic behavior of mannitol, and the effect is linked to the crystallization of mannitol in two polymorphic stages.

  5. Correlation of Risk Analysis Method Results with Numerical and Limit Equilibrium Methods in Overall Slope Stability Analysis of Southern Wall of Chadormalu Iron Open Pit Mine-Iran / Korelacja wyników analizy ryzyka z wynikami obliczeń numerycznych oraz wynikami uzyskanymi w oparciu o metodę równowagi granicznej zastosowanych do badania stabilności wyrobiska pochyłego na południowej ścianie odkrywkowej kopalni rud żelaza w chadormalu w Iranie

    NASA Astrophysics Data System (ADS)

    Ahangari, Kaveh; Paji, Arman Gholinezhad; Behdani, Alireza Siami

    2013-06-01

    trzech spośród tych metod: metody numerycznej, równowagi granicznej oraz metody probabilistycznej, do analizy stabilności wyrobiska pochyłego na południowej ścianie kopalni rud żelaza w Chadormalu w Iranie. Oprogramowanie wykorzystane w badaniach analitycznych to pakiet FLAK przy metodzie numerycznej, oprogramowanie SLIDE oraz wykresy kołowe przy metodzie równowagi granicznej oraz jakościowe drzewa określające występowanie uskoków i pół-jakościowe macierze ryzyka przy metodzie probabilistycznej. Wyniki uzyskane w oparciu o trzy wyżej wymienione metody wykazały wystąpienie zawalenia się skał metasomatycznych na poziomie od 1405 do 1525 m. Głównymi czynnikami warunkującymi zawalenie się skał w tym regionie była obecność licznych pęknięć oraz uskoków. Wskaźniki bezpieczeństwa uzyskane przy pomocy metod numerycznych, wykresu kołowego oraz oprogramowanie SLIDE wyniosły kolejno: 1.16, 1.25, 1.27. W odniesieniu do niestabilności w rejonie skał metasomatycznych, aby uczynić tę strefę bardziej stabilną należy uwzględnić takie czynniki jak kąt nachylenia ławy oraz obniżenie wysokości. Analiza przeprowadzona w oparciu o macierze ryzyka wykazała, że strefa ta jest strefą wysokiego ryzyka, zaś wyniki analizy numerycznej oraz wyników uzyskanych przy pomocy metody równowagi granicznej w pełni ten wniosek potwierdziły.

  6. Microbial habitability of the Hadean Earth during the late heavy bombardment.

    PubMed

    Abramov, Oleg; Mojzsis, Stephen J

    2009-05-21

    Lunar rocks and impact melts, lunar and asteroidal meteorites, and an ancient martian meteorite record thermal metamorphic events with ages that group around and/or do not exceed 3.9 Gyr. That such a diverse suite of solar system materials share this feature is interpreted to be the result of a post-primary-accretion cataclysmic spike in the number of impacts commonly referred to as the late heavy bombardment (LHB). Despite its obvious significance to the preservation of crust and the survivability of an emergent biosphere, the thermal effects of this bombardment on the young Earth remain poorly constrained. Here we report numerical models constructed to probe the degree of thermal metamorphism in the crust in the effort to recreate the effect of the LHB on the Earth as a whole; outputs were used to assess habitable volumes of crust for a possible near-surface and subsurface primordial microbial biosphere. Our analysis shows that there is no plausible situation in which the habitable zone was fully sterilized on Earth, at least since the termination of primary accretion of the planets and the postulated impact origin of the Moon. Our results explain the root location of hyperthermophilic bacteria in the phylogenetic tree for 16S small-subunit ribosomal RNA, and bode well for the persistence of microbial biospheres even on planetary bodies strongly reworked by impacts.

  7. Note: Development of target changeable palm-top pyroelectric x-ray tube

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Imashuku, Susumu; Kawai, Jun

    2012-01-15

    A target changeable palm-top size x-ray tube was realized using pyroelectric crystal and detachable vacuum flanges. The target metals can be exchanged easily by attaching them on the brass stage with carbon tape. When silver and titanium palates (area: 10 mm{sup 2}) were used as targets, silver L{alpha} and titanium K lines were clearly observed by bombarding electrons on the targets for 90 s. The intensities were the same or higher than those of previously reported pyroelectric x-ray tubes. Chromium, iron, nickel, copper, and zinc K lines in the x-ray tube (stainless steel and brass) disappeared by replacing the brassmore » stage and the stainless steel vacuum flange with a carbon stage and a glass tube, respectively.« less

  8. Na, K-ATPase α3 is a death target of Alzheimer patient amyloid-β assembly.

    PubMed

    Ohnishi, Takayuki; Yanazawa, Masako; Sasahara, Tomoya; Kitamura, Yasuki; Hiroaki, Hidekazu; Fukazawa, Yugo; Kii, Isao; Nishiyama, Takashi; Kakita, Akiyoshi; Takeda, Hiroyuki; Takeuchi, Akihide; Arai, Yoshie; Ito, Akane; Komura, Hitomi; Hirao, Hajime; Satomura, Kaori; Inoue, Masafumi; Muramatsu, Shin-ichi; Matsui, Ko; Tada, Mari; Sato, Michio; Saijo, Eri; Shigemitsu, Yoshiki; Sakai, Satoko; Umetsu, Yoshitaka; Goda, Natsuko; Takino, Naomi; Takahashi, Hitoshi; Hagiwara, Masatoshi; Sawasaki, Tatsuya; Iwasaki, Genji; Nakamura, Yu; Nabeshima, Yo-ichi; Teplow, David B; Hoshi, Minako

    2015-08-11

    Neurodegeneration correlates with Alzheimer's disease (AD) symptoms, but the molecular identities of pathogenic amyloid β-protein (Aβ) oligomers and their targets, leading to neurodegeneration, remain unclear. Amylospheroids (ASPD) are AD patient-derived 10- to 15-nm spherical Aβ oligomers that cause selective degeneration of mature neurons. Here, we show that the ASPD target is neuron-specific Na(+)/K(+)-ATPase α3 subunit (NAKα3). ASPD-binding to NAKα3 impaired NAKα3-specific activity, activated N-type voltage-gated calcium channels, and caused mitochondrial calcium dyshomeostasis, tau abnormalities, and neurodegeneration. NMR and molecular modeling studies suggested that spherical ASPD contain N-terminal-Aβ-derived "thorns" responsible for target binding, which are distinct from low molecular-weight oligomers and dodecamers. The fourth extracellular loop (Ex4) region of NAKα3 encompassing Asn(879) and Trp(880) is essential for ASPD-NAKα3 interaction, because tetrapeptides mimicking this Ex4 region bound to the ASPD surface and blocked ASPD neurotoxicity. Our findings open up new possibilities for knowledge-based design of peptidomimetics that inhibit neurodegeneration in AD by blocking aberrant ASPD-NAKα3 interaction.

  9. Effects of particle size, helium gas pressure and microparticle dose on the plasma concentration of indomethacin after bombardment of indomethacin-loaded poly-L-lactic acid microspheres using a Helios gun system.

    PubMed

    Uchida, Masaki; Natsume, Hideshi; Kobayashi, Daisuke; Sugibayashi, Kenji; Morimoto, Yasunori

    2002-05-01

    We investigated the effects of the particle size of indomethacin-loaded poly-L-lactic acid microspheres (IDM-loaded PLA MS), the helium pressure used to accelerate the particles, and the bombardment dose of PLA MS on the plasma concentration of IDM after bombarding with IDM-loaded PLA MS of different particle size ranges, 20-38, 44-53 and 75-100 microm, the abdomen of hairless rats using the Helios gene gun system (Helios gun system). Using larger particles and a higher helium pressure, produced an increase in the plasma IDM concentration and the area under the plasma concentration-time curve (AUC) and resultant F (relative bioavailability with respect to intracutaneous injection) of IDM increased by an amount depending on the particle size and helium pressure. Although a reduction in the bombardment dose led to a decrease in C(max) and AUC, F increased on decreasing the bombardment dose. In addition, a more efficient F was obtained after bombarding with IDM-loaded PLA MS of 75-100 microm in diameter at each low dose in different sites of the abdomen compared with that after bolus bombardment with a high dose (dose equivalent). These results suggest that the bombardment injection of drug-loaded microspheres by the Helios gun system is a very useful tool for delivering a variety of drugs in powder form into the skin and systemic circulation.

  10. "Man in Danger" Media Festival in Łódź - the structure and motivations of the festival visitors / Festiwal Medialny w Łodzi - "Człowiek w niebezpieczeństwie" - struktura i motywacje festiwalowych gości

    NASA Astrophysics Data System (ADS)

    Cudny, Waldemar; Stanik, Ewelina

    2013-06-01

    Artykuł przedstawia problemy dotyczące rozwoju festiwali sztuki miejskiej w miastach postsocjalistycznych na przykładzie Łodzi - jednego z największych miast Polski. Autorzy przeprowadzili ankietę podczas Festiwalu Medialnego "Człowiek w niebezpieczeństwie", zorganizowanego w Łodzi, a poświęconego głównie filmom dokumentalnym. Rozważania dotyczą zjawisk z dziedziny geografii kulturowej i miejskiej, analizowanych w badaniach nad wydarzeniami kulturalnymi, a także oceny tych wydarzeń i motywacji uczestnictwa w nich. Uczestnikami są głównie młodzi mieszkańcy Łodzi, z których wielu jest studentami szkoły filmowej. Głównymi czynnikami motywującymi uczestnictwo w "evencie" są potrzeba doznań kulturalnych i nowych doświadczeń, ciekawość oraz chęć rozwijania kontaktów towarzyskich. Na podstawie analizy autorzy przedstawiają wnioski dotyczące roli wydarzeń kulturalnych w rozwoju kultury w mieście i spełnieniu potrzeb mieszkańców. Badanie ukazuje, że festiwal odgrywa znaczącą rolę w zaspokajaniu potrzeb kulturalnych, pogłębianiu zainteresowań oraz tworzeniu kapitału społecznego.

  11. Production and separation of (186g)Re from proton bombardment of (186)WC.

    PubMed

    Richards, Vernal N; Rath, Nigam; Lapi, Suzanne E

    2015-06-01

    A proof of concept study was undertaken where non-carrier added (186 g)Re was produced from the cyclotron bombardment of (186)WC. (186)WC was carbo-thermally generated from a novel precursor synthesized from (186)WO3, aqueous ammonia and hexamethyltetramine. The inherent high electrical and thermal conductivity of this material, coupled with its high melting point, made it an ideal candidate for proton bombardment for production of (186)Re. An18 μA irradiation for 3h and processing via thermo-chromatography, (186)WC yielded 0.93 mCi of (186 g)Re which corresponds to 89% of the calculated theoretical yields. The radiochemical purity of the desired (186 g)Re species was found to be between 95 and 97% with small contaminants of (186)ReO2. The radiochemistry utility of the product was investigated using S-benzoyl-MAG3, and 100% complexation was achieved with stability being maintained for 96 h. The re-oxidation of (186)WC back to(186)WO3 by oxygen in the thermo-chromatography method of processing ensured that the starting material was regenerated and recovered from the process in 94-98% yield. Copyright © 2015 Elsevier Inc. All rights reserved.

  12. Production of Mg and Al Auger electrons by noble gas ion bombardment of Mg and Al surfaces

    NASA Technical Reports Server (NTRS)

    Ferrante, J.; Pepper, S. V.

    1976-01-01

    Relative production efficiencies of Mg and Al Auger electrons by He, Ne, Ar, Kr, and Xe ion bombardment are reported as a function of ion energy for energies not exceeding 3 keV. The experimental apparatus employed consisted of a LEED-Auger system equipped with an ion gun and a four-grid retarding-potential analyzer. It is found that: (1) the shape of the ion-excited Auger signal was independent of the rare gas and quite symmetric; (2) the Al signal was about an order of magnitude smaller than the Mg signal for a given bombarding species and ion-gun voltage; (3) no signal was observed for He(+) bombardment under any of the experimental conditions; (4) signal strengths were independent of temperature and ion dose; (5) the Auger production efficiencies differed by no more than a factor of two among the different gases - except for He(+) - on a given metal; (6) all the signal strengths increased with increasing ion-gun voltage, with no maximum exhibited; and (7) the apparent threshold energy for the Al signal was higher than that for the Mg signal. The differences between the results for the two metals are attributed to the fact that the Al 2p orbital lies deeper in energy and closer to the nucleus than the corresponding Mg orbital.

  13. Multiple-target tracking implementation in the ebCMOS camera system: the LUSIPHER prototype

    NASA Astrophysics Data System (ADS)

    Doan, Quang Tuyen; Barbier, Remi; Dominjon, Agnes; Cajgfinger, Thomas; Guerin, Cyrille

    2012-06-01

    The domain of the low light imaging systems progresses very fast, thanks to detection and electronic multiplication technology evolution, such as the emCCD (electron multiplying CCD) or the ebCMOS (electron bombarded CMOS). We present an ebCMOS camera system that is able to track every 2 ms more than 2000 targets with a mean number of photons per target lower than two. The point light sources (targets) are spots generated by a microlens array (Shack-Hartmann) used in adaptive optics. The Multiple-Target-Tracking designed and implemented on a rugged workstation is described. The results and the performances of the system on the identification and tracking are presented and discussed.

  14. Near-UV and blue wavelength excitable Mg{sub 0.6}Ca{sub 2.16}Mo{sub 0.2}W{sub 0.8}O{sub 6}: Eu{sub 0.12}{sup 3+}/Na{sub 0.12}{sup +} high efficiency red phosphors

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Khanna, A.; Electrical Computer and Systems Engineering, Rensselaer Polytechnic Institute, Troy, NY 12180; Dutta, P.S., E-mail: duttap@rpi.edu

    Red phosphors with narrow emission around 615 nm (with FWHM~5–10 nm) having chemical compositions of A{sub 0.6}Ca{sub 2.16}Mo{sub 0.2}W{sub 0.8}O{sub 6}: Eu{sub 0.12}{sup 3+}/Na{sub 0.12}{sup +} (A=Mg, Sr) have been found to exhibit the highest luminescence amongst the molybdate–tungstate family when excited by sources in the 380–420 nm wavelength range. Thus they are most suitable for enhancing color rendering index and lowering color temperature in phosphor converted white LEDs (pc-WLEDs) with near-UV/blue LED excitation sources. The excitation band edge in the near UV/blue wavelength in the reported phosphor has been attributed to the coordination environment of the transition metal ionmore » (Mo{sup 6+}, W{sup 6+}) and host crystal structure. Furthermore the quantum efficiency of the phosphors has been enhanced by adjusting activator concentration, suitable compositional alloying using substitutional alkaline earth metal cations and charge compensation mechanisms. - Graphical abstract: The charge transfer excitation of orthorhombic Mg{sub 0.6}Ca{sub 2.16}Mo{sub 0.2}W{sub 0.8}O{sub 6}: Eu{sub 0.12}{sup 3+}/Na{sub 0.12}{sup +} is significantly higher than tetragonal CaMoO{sub 4}: Eu{sup 3+} phosphors making Mg{sub 0.6}Ca{sub 2.16}Mo{sub 0.2}W{sub 0.8}O{sub 6}: Eu{sub 0.12}{sup 3+}/Na{sub 0.12}{sup +} prime candidates for fabrication of warm white phosphor-converted LEDs. - Highlights: • LED excitable Mg{sub 0.6}Ca{sub 2.16}Mo{sub 0.2}W{sub 0.8}O{sub 6}: Eu{sub 0.12}{sup 3+}/Na{sub 0.12}{sup +} phosphors were synthesized. • These phosphors are 10 times more intense than CaMoO{sub 4}: Eu{sup 3+} red phosphors. • Their intensity and efficiency were enhanced by materials optimization techniques. • Such techniques include compositional alloying, charge compensation, etc.« less

  15. Mesoscale energy deposition footprint model for kiloelectronvolt cluster bombardment of solids.

    PubMed

    Russo, Michael F; Garrison, Barbara J

    2006-10-15

    Molecular dynamics simulations have been performed to model 5-keV C60 and Au3 projectile bombardment of an amorphous water substrate. The goal is to obtain detailed insights into the dynamics of motion in order to develop a straightforward and less computationally demanding model of the process of ejection. The molecular dynamics results provide the basis for the mesoscale energy deposition footprint model. This model provides a method for predicting relative yields based on information from less than 1 ps of simulation time.

  16. Proton acceleration to above 5.5 MeV by interaction of 1017 W/cm2 laser pulse with H2O nano-wire targets

    NASA Astrophysics Data System (ADS)

    Schleifer, E.; Bruner, N.; Eisenmann, S.; Botton, M.; Pikuz, S. A., Jr.; Faenov, A. Y.; Gordon, D.; Zigler, A.

    2011-05-01

    Compact sources of high energy protons (50-500MeV) are expected to be key technology in a wide range of scientific applications 1-8. Particularly promising is the target normal sheah acceleration (TNSA) scheme 9,10, holding record level of 67MeV protons generated by a peta-Watt laser 11. In general, laser intensity exceeding 1018 W/cm2 is required to produce MeV level protons. Enhancing the energy of generated protons using compact laser sources is very attractive task nowadays. Recently, nano-scale targets were used to accelerate ions 12,13. Here we report on the first generation of 5.5-7.5MeV protons by modest laser intensities (4.5 × 1017 W/cm2) interacting with H2O nano-wires (snow) deposited on a Sapphire substrate. In this setup, the plasma near the tip of the nano-wire is subject to locally enhanced laser intensity with high spatial gradients, and confined charge separation is obtained. Electrostatic fields of extremely high intensities are produced, and protons are accelerated to MeV-level energies. Nano-wire engineered targets will relax the demand of peak energy from laser based sources.

  17. Changes of electronic properties of p-GaN(0 0 0 1) surface after low-energy N+-ion bombardment

    NASA Astrophysics Data System (ADS)

    Grodzicki, M.; Mazur, P.; Ciszewski, A.

    2018-05-01

    The p-GaN(0 0 0 1) crystal with a relatively low acceptor concentration of 5 × 1016 cm-3 is used in these studies, which are carried out in situ under ultrahigh vacuum (UHV) by ultraviolet photoelectron spectroscopy (UPS), X-ray photoelectron spectroscopy (XPS) and low-energy electron diffraction (LEED). The p-GaN(0 0 0 1)-(1 × 1) surface is achieved by thermal cleaning. N+-ion bombardment by a 200 eV ion beam changes the surface stoichiometry, enriches it with nitrogen, and disorders it. Such modified surface layer inverts its semiconducting character from p- into n-type. The electron affinity for the already cleaned p-GaN surface and that just after bombardment shows a shift from 2.2 eV to 3.2 eV, as well as an increase of band bending at the vacuum/surface interface from 1.4 eV to 2.5 eV. Proper post-bombardment heating of the sample restores the initial atomic order of the modified layer, leaving its n-type semiconducting character unchanged. The results of the measurements are discussed based on two types of surface states concepts.

  18. Ion time-of-flight determinations of doubly to singly ionized mercury ion ratios from a mercury electron bombardment discharge

    NASA Technical Reports Server (NTRS)

    Sellen, J. M., Jr.; Kemp, R. F.; Hall, D. F.

    1973-01-01

    Doubly to singly charged mercury ion ratios in electron bombardment ion thruster exhaust beams have been determined as functions of bombardment discharge potential, thrust beam current, thrust beam radial position, acceleration-deceleration voltage ratio, and propellant utilization fraction. A mathematical model for two-step ionization processes has been derived, and calculated ion ratios are compared to observed ratios. Production of Hg(++) appears to result primarily from sequential ionization of Hg(+) in the discharge. Experimental and analytical results are presented, and design, construction, and operation features of an electrostatic deflection ion time-of-flight analyzer for the determination of the above-mentioned ratios are reviewed.

  19. Genetic Transformation of Metroxylon sagu (Rottb.) Cultures via Agrobacterium-Mediated and Particle Bombardment

    PubMed Central

    Ibrahim, Evra Raunie

    2014-01-01

    Sago palm (Metroxylon sagu) is a perennial plant native to Southeast Asia and exploited mainly for the starch content in its trunk. Genetic improvement of sago palm is extremely slow when compared to other annual starch crops. Urgent attention is needed to improve the sago palm planting material and can be achieved through nonconventional methods. We have previously developed a tissue culture method for sago palm, which is used to provide the planting materials and to develop a genetic transformation procedure. Here, we report the genetic transformation of sago embryonic callus derived from suspension culture using Agrobacterium tumefaciens and gene gun systems. The transformed embryoids cells were selected against Basta (concentration 10 to 30 mg/L). Evidence of foreign genes integration and function of the bar and gus genes were verified via gene specific PCR amplification, gus staining, and dot blot analysis. This study showed that the embryogenic callus was the most suitable material for transformation as compared to the fine callus, embryoid stage, and initiated shoots. The gene gun transformation showed higher transformation efficiency than the ones transformed using Agrobacterium when targets were bombarded once or twice using 280 psi of helium pressure at 6 to 8 cm distance. PMID:25295258

  20. 50 kW laser weapon demonstrator of Rheinmetall Waffe munition

    NASA Astrophysics Data System (ADS)

    Ludewigt, K.; Riesbeck, Th.; Graf, A.; Jung, M.

    2013-10-01

    We will present the setup of a 50 kW Laser Weapon Demonstrator (LWD) and results achieved with this system. The LWD is a ground based Air Defence system consisting of a Skyguard sensor unit for target acquisition and two laser equipped weapon turrets. The weapon turrets used are standard air defence turrets of Rheinmetall Air Defence which were equipped with several 10 kW Laser Weapon Modules (LWM). Each LWM consists of one 10 kW fiber laser and a beam forming unit (BFU). Commercial of the shelf fiber laser were modified for our defence applications. The BFU providing diffraction limited beam focusing, target imaging and fine tracking of the target was developed. The LWD was tested in a firing campaign at Rheinmetall test ground in Switzerland. All laser beams of both weapon turrets were superimposed on stationary and dynamic targets. Test results of the LWD for the scenarios Air Defence and C-RAMM (counter rockets, artillery, mortar and missiles) will be presented. An outlook for the next development stage towards a 100 kW class laser weapon on RWM will be given.

  1. Extremely high-brightness kW-class fiber coupled diode lasers with wavelength stabilization

    NASA Astrophysics Data System (ADS)

    Huang, Robin K.; Chann, Bien; Glenn, John D.

    2011-06-01

    TeraDiode has produced ultra-high brightness fiber-coupled direct diode lasers. A fiber-coupled direct diode laser with a power level of 1,040 W from a 200 μm core diameter, 0.18 numerical aperture (NA) output fiber at a single center wavelength was demonstrated. This was achieved with a novel beam combining and shaping technique using COTS diode lasers. The fiber-coupled output corresponds to a Beam Parameter Product (BPP) of 18 mm-mrad and is the lowest BPP kW-class direct diode laser yet reported. The laser has been used to demonstrate laser cutting and welding of steel sheet metal up to 6.65 mm thick. Higher brightness fiber-coupled diode lasers, including a module with 418 W of power coupled to a 100 μm, 0.15 NA fiber, have also been demonstrated.

  2. Stability of Selected PAHs in Sewage Sludge/ Stabilność Wybranych Wwa W Osadach Ściekowych

    NASA Astrophysics Data System (ADS)

    Włodarczyk-Makuła, Maria

    2014-09-01

    The aim of the investigations was to estimate the half-life of selected PAHs in sewage sludge. Five hydrocarbons selected from 16 PAHs- EPA were chosen. In this study, the quantity changes in the concentration 3- and 4-ring of PAHs in sewage sludges were investigated. Sewage sludges were stored under aerobic conditions for 12 weeks. At the same time the sewage sludges with the added sodium azide, in order to deactivate the microorganisms (abiotic samples), were also stored. Gas chromatography-mass spectrometry was used to qualify and quantify PAHs in 2-week intervals. Sewage sludges were taken from a municipal wastewater treatment plant. Under experimental conditions the half-lives of individual compounds were diversed. In biotic samples halflife of hydrocarbons was in the range of 19 to 368 days. Half-life of PAHs in abiotic sewage sludges was in the range of 31 to 2961 days. The most persistent were phenanthrene. Celem badań była ocena trwałości WWA w warunkach składowania poprzez wyznaczenie czasu połowicznego rozpadu. Określono zmiany ilościowe WWA w osadach przechowywanych w warunkach tlenowych przez 12 tygodni. W tych samych warunkach pozostawały także osady, w których zahamowano aktywność mikroorganizmów poprzez dodatek azydku sodu. Ilościową analizę WWA prowadzono z wykorzystaniem zestawu GC-MS w odstępach 2-tygodniowych równolegle w osadach biotycznych i abiotycznych. Oznaczano pięć WWA (fluoren, fenentren, antracen, fluoranten, piren), które znajdują się wśród 16 związków podanych na liście EPA. Osady pobrano dwukrotnie z oczyszczalni ścieków komunalnych, które w praktyce kierowane są na składowisko. Zawartość początkowa WWA w osadach była na poziomie 346μg/kg.s.m. W warunkach prowadzonego eksperymentu czas połowicznego rozkładu był zróżnicowany dla poszczególnych związków. W osadach aktywnych biologicznie czas połowicznego rozpadu badanych węglowodorów był w granicach od 19 do 368 dób. Czas po

  3. Registration of untypical 3D objects in Polish cadastre - do we need 3D cadastre? / Rejestracja nietypowych obiektów 3D w polskim katastrze - czy istnieje potrzeba wdrożenia katastru 3D?

    NASA Astrophysics Data System (ADS)

    Marcin, Karabin

    2012-11-01

    Polish cadastral system consists of two registers: cadastre and land register. The cadastre register data on cadastral objects (land, buildings and premises) in particular location (in a two-dimensional coordinate system) and their attributes as well as data about the owners. The land register contains data concerned ownerships and other rights to the property. Registration of a land parcel without spatial objects located on the surface is not problematic. Registration of buildings and premises in typical cases is not a problem either. The situation becomes more complicated in cases of multiple use of space above the parcel and with more complex construction of the buildings. The paper presents rules concerning the registration of various untypical 3D objects located within the city of Warsaw. The analysis of the data concerning those objects registered in the cadastre and land register is presented in the paper. And this is the next part of the author's detailed research. The aim of this paper is to answer the question if we really need 3D cadastre in Poland. Polski system katastralny składa się z dwóch rejestrów: ewidencji gruntów i budynków (katastru nieruchomosci) oraz ksiąg wieczystych. W ewidencji gruntów i budynków (katastrze nieruchomości) rejestrowane są dane o położeniu (w dwuwymiarowym układzie współrzędnych), atrybuty oraz dane o właścicielach obiektów katastralnych (działek, budynków i lokali), w księgach wieczystych oprócz danych właścicielskich, inne prawa do nieruchomości. Rejestracja działki bez obiektów przestrzennych położonych na jej powierzchni nie stanowi problemu. Także rejestracja budynków i lokali w typowych przypadkach nie stanowi trudności. Sytuacja staje się bardziej skomplikowana w przypadku wielokrotnego użytkowania przestrzeni powyzej lub poniżej powierzchni działki oraz w przypadku budynków o złożonej konstrukcji. W artykule przedstawiono zasady związane z rejestracją nietypowych obiektów 3

  4. Highly efficient extraction and oxidative desulfurization system using Na7H2LaW10O36⋅32 H2O in [bmim]BF4 at room temperature.

    PubMed

    Xu, Junhua; Zhao, Shen; Chen, Wei; Wang, Miao; Song, Yu-Fei

    2012-04-10

    Highly efficient, deep desulfurization of model oil containing dibenzothiophene (DBT), benzothiophene (BT), or 4,6-dimethyldibenzothiophene (4,6-DMDBT) has been achieved under mild conditions by using an extraction and catalytic oxidative desulfurization system (ECODS) in which a lanthanide-containing polyoxometalate Na(7)H(2)LnW(10)O(36)⋅32 H(2)O (LnW(10); Ln = Eu, La) acts as catalyst, [bmim]BF(4) (bmim = 1-butyl-3-methylimidazolium) as extractant, and H(2)O(2) as oxidant. Sulfur removal follows the order DBT>4,6-DMDBT>BT at 30 °C. DBT can be completely oxidized to the corresponding sulfone in 25 min under mild conditions, and the LaW(10)/[bmim]BF(4) system could be recycled for ten times with only slight decrease in activity. Thus, LaW(10) in [bmim]BF(4) is one of the most efficient systems for desulfurization using ionic liquids as extractant reported so far. Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  5. Moderate temperature rechargeable NaNiS2 cells

    NASA Technical Reports Server (NTRS)

    Abraham, K. M.

    1983-01-01

    A rechargeable sodium battery of the configuration, liquid Na/beta double prime -Al2O3/molten NaAlCl4, NiS2, operating in the temperature range of 170 to 190 C, is described. This battery is capable of delivering or = to 50 W-hr/1b and 1000 deep discharge/charge cycles.

  6. Efficient neutron production from sub-nanosecond laser pulse accelerating deuterons on target front side

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Klir, D.; Institute of Plasma Physics, ASCR, Za Slovankou 3, 182 00 Prague 8; Institute of Physics, ASCR, Na Slovance 2, 182 21 Prague 8

    2015-09-15

    Neutron-producing experiments have been carried out on the Prague Asterix Laser System. At the fundamental wavelength of 1.315 μm, the laser pulse of a 600 J energy and 300 ps duration was focused on a thick deuterated-polyethylene target. Neutron yields reached (4.1 ± 0.8) × 10{sup 8} at the peak intensity of ≈3 × 10{sup 16 }W/cm{sup 2}. A more detailed analysis of neutron time-of-flight signals showed that a significant fraction of neutron yields was produced both by the {sup 2}H(d,n){sup 3}He reaction and by other neutron-producing reactions. Neutron energies together with delayed neutron and gamma emission showed that MeV deuterons escaped from a laser-produced plasma and interacted ≈50 nsmore » later with a borosilicate blast-shield glass. In order to increase DD neutron yields and to characterize deuteron beams via nuclear reactions, a secondary deuterated polyethylene target was used in a pitcher-catcher scheme at the target front side. In this experimental arrangement, the neutron yield reached (2.0 ± 0.5) × 10{sup 9} with the peak neutron fluence of (2.5 ± 0.5) × 10{sup 8 }n/sr. From the neutron yield, it was calculated that the secondary target was bombarded by 2 × 10{sup 14} deuterons in the 0.5–2.0 MeV energy range. The neutron yield of 2 × 10{sup 9} at the laser energy of 600 J implied the production efficiency of 3 × 10{sup 6 }n/J. A very important result is that the efficient neutron production was achieved with the low contrast, sub-nanosecond laser pulse of the intensity of 10{sup 16 }W/cm{sup 2}. The latter parameters can be achieved in a rep-rate mode more easily than ultra-high intensities and contrasts.« less

  7. Radiation damage calculations for the SINQ Target 5

    NASA Astrophysics Data System (ADS)

    Wechsler, Monroe S.; Lu, Wei; Dai, Yong

    2003-03-01

    Calculations are underway of radiation damage (production of displacements, helium, and hydrogen) at Target 5 of the SINQ spallation neutron source at the Paul Scherrer Institute in Switzerland. The target is bombarded by 575-MeV protons, and the spallation-neutron-producing target material is liquid lead. The calculations employ the Monte Carlo code MCNPX (version 2.3.0). The peak proton and neutron fluxes at the aluminum-alloy entrance window are determined to be about 1.9E14 protons/cm2s per mA of incident proton current and 2.4E13 neutrons/cm2s per mA. For a beam exposure of 10 Ahr, the peak damage sustained at the entrance window due to protons and neutrons combined is calculated to be 7.8 dpa, 2000 appmHe, and 4000 appmH. The significance of the damage results for the entrance window and components within Target 5 will be discussed.

  8. Use of Cad Systems in Testing the Collision of Underground Transportation Means / Zastosowanie systemów Cad w badaniach kolizyjności środków transportu podziemnego

    NASA Astrophysics Data System (ADS)

    Dudek, Marek

    2013-06-01

    A concept of use of CAD systems in testing collision of underground transportation means is presented. Reasons for undertaking this problem are given with end users identified. The concept of the system for collision analyses of transported loads is described. Examples of collision analysis during transportation of powered roof support are given. Presented system is designed to aid planning, organizational and training activities undertaken in management of transportation safety in mines. It will be also possible to use software resources, developed within the system as the didactic material as regards safe transportation process, which include hazards to the employees working in the area of transportation operations. Developed prototype of a system for testing the collision of underground transportation means was positively assessed by employees of the Coal Company, JSC - industrial partner of KOMAG. This prototype is continuously improved and adapted for commercial implementation in the selected coal mines. W pracy przedstawiono koncepcję zastosowania systemów CAD w badaniach kolizyjności środków transportu podziemnego. Określono przyczyny podjęcia tematu oraz zidentyfikowano końcowych użytkowników. Zaprezentowano koncepcję systemu do analiz kolizyjności transportowanych ładunków. Pokazano przykłady analizy kolizyjności podczas transportu sekcji obudowy zmechanizowanej. Przedstawiony system przeznaczony jest do wspomagania działań planistycznych, organizacyjnych i szkoleniowych podejmowanych w zarządzaniu bezpieczeństwem transportu w zakładach górniczych. Opracowane w ramach systemu zasoby programowe będzie można również wykorzystać jako materiał dydaktyczny z zakresu bezpieczeństwa pracy w transporcie, uwzględniający zagrożenia dla pracowników pracujących w bezpośredniej strefie prac transportowych. Opracowany prototyp systemu do badania kolizyjności środków transportu podziemnego został pozytywnie oceniony przez pracowników

  9. Combustion of Coal-Mule Briquettes / Spalanie Brykietów Z Mułu Węglowego

    NASA Astrophysics Data System (ADS)

    Kijo-Kleczkowska, Agnieszka

    2013-09-01

    Combustion technologies coal-mule fuels create a number of new possibilities for organising combustion processes so that they fulfil contemporary requirements (e.g., in terms of the environment protection- related issues). The paper describes the problems of coal-mule fuel combustion that have acquired a wider significance as the quality requirements of coal combustion in power plants have been growing. Coal mines that want to fulfill expectations of power industry workers have been forced to develop and modernize plants of coal wet cleaning. It all results in the growing amount of waste arising in the process of coal wet cleaning which contains smaller and smaller coal undersizes. In this situation the concept of direct combustion of the above mentioned waste and their co-combustion with other fuels, coal and biomass, seems to be attractive. Biomass is one from the most promising sources of renewable energy. The main aim of the paper is to identify the mechanism and kinetics of combustion of coal-mule fuels and their co- -combustion with coal and biomass in the briquettes form based on extensive experimental research in air. Niekorzystny bilans paliwowy naszego kraju powoduje nadmierne obciążenie środowiska, wywołane emisją CO2, NOx, SO2 i pyłów, a także powiększeniem powierzchni koniecznych na składowanie wciąż narastających stałych odpadów paleniskowych. Górnictwo, od którego energetyka oczekuje coraz lepszego paliwa, musi stosować głębsze wzbogacanie węgla. Powoduje to ciągłą produkcję odpadów w postaci mułów poflotacyjnych. Najlepszą metodą utylizacji tych mułów jest ich spalanie w postaci zawiesin, a także ich współspalanie z innymi paliwami, węglem czy biomasą. Biomasa jest bowiem jednym z najbardziej obiecujących źródeł OZE, a jej współspalanie z paliwami węglowymi znajduje w ostatnich latach coraz szersze zastosowanie zarówno w kraju, jak i na świecie. W tej sytuacji istotne jest prowadzenie badań naukowych

  10. Emission properties and back-bombardment for CeB{sub 6} compared to LaB{sub 6}

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Bakr, Mahmoud, E-mail: m-a-bakr@iae.kyoto-u.ac.jp; Kawai, M.; Kii, T.

    The emission properties of CeB{sub 6} compared to LaB{sub 6} thermionic cathodes have been measured using an electrostatic DC gun. Obtaining knowledge of the emission properties is the first step in understanding the back-bombardment effect that limits wide usage of thermionic radio-frequency electron guns. The effect of back-bombardment electrons on CeB{sub 6} compared to LaB{sub 6} was studied using a numerical simulation model. The results show that for 6 μs pulse duration with input radio-frequency power of 8 MW, CeB{sub 6} should experience 14% lower temperature increase and 21% lower current density rise compared to LaB{sub 6}. We conclude that CeB{submore » 6} has the potential to become the future replacement for LaB{sub 6} thermionic cathodes in radio-frequency electron guns.« less

  11. Na, K-ATPase α3 is a death target of Alzheimer patient amyloid-β assembly

    PubMed Central

    Ohnishi, Takayuki; Yanazawa, Masako; Sasahara, Tomoya; Kitamura, Yasuki; Hiroaki, Hidekazu; Fukazawa, Yugo; Kii, Isao; Nishiyama, Takashi; Kakita, Akiyoshi; Takeda, Hiroyuki; Takeuchi, Akihide; Arai, Yoshie; Ito, Akane; Komura, Hitomi; Hirao, Hajime; Satomura, Kaori; Inoue, Masafumi; Muramatsu, Shin-ichi; Matsui, Ko; Tada, Mari; Sato, Michio; Saijo, Eri; Shigemitsu, Yoshiki; Sakai, Satoko; Umetsu, Yoshitaka; Goda, Natsuko; Takino, Naomi; Takahashi, Hitoshi; Hagiwara, Masatoshi; Sawasaki, Tatsuya; Iwasaki, Genji; Nakamura, Yu; Nabeshima, Yo-ichi; Teplow, David B.; Hoshi, Minako

    2015-01-01

    Neurodegeneration correlates with Alzheimer’s disease (AD) symptoms, but the molecular identities of pathogenic amyloid β-protein (Aβ) oligomers and their targets, leading to neurodegeneration, remain unclear. Amylospheroids (ASPD) are AD patient-derived 10- to 15-nm spherical Aβ oligomers that cause selective degeneration of mature neurons. Here, we show that the ASPD target is neuron-specific Na+/K+-ATPase α3 subunit (NAKα3). ASPD-binding to NAKα3 impaired NAKα3-specific activity, activated N-type voltage-gated calcium channels, and caused mitochondrial calcium dyshomeostasis, tau abnormalities, and neurodegeneration. NMR and molecular modeling studies suggested that spherical ASPD contain N-terminal-Aβ–derived “thorns” responsible for target binding, which are distinct from low molecular-weight oligomers and dodecamers. The fourth extracellular loop (Ex4) region of NAKα3 encompassing Asn879 and Trp880 is essential for ASPD–NAKα3 interaction, because tetrapeptides mimicking this Ex4 region bound to the ASPD surface and blocked ASPD neurotoxicity. Our findings open up new possibilities for knowledge-based design of peptidomimetics that inhibit neurodegeneration in AD by blocking aberrant ASPD–NAKα3 interaction. PMID:26224839

  12. Low-NA fiber laser pumps powered by high-brightness single emitters

    NASA Astrophysics Data System (ADS)

    Yanson, Dan; Levy, Moshe; Peleg, Ophir; Rappaport, Noam; Shamay, Moshe; Dahan, Nir; Klumel, Genady; Berk, Yuri; Baskin, Ilya

    2015-03-01

    Fiber laser manufacturers demand high-brightness laser diode pumps delivering optical pump energy in both a compact fiber core and narrow angular content. A pump delivery fiber of a 105 μm core and 0.22 numerical aperture (NA) is typically used, where the fiber NA is under-filled to ease the launch of laser diode emission into the fiber and make the fiber tolerant to bending. At SCD, we have developed high-brightness NEON multi-emitter fiber-coupled pump modules that deliver 50 W output from a 105 μm, 0.15 NA fiber enabling low-NA power delivery to a customer's fiber laser network. Brightness-enhanced single emitters are engineered with ultra-low divergence for compatibility with the low-NA delivery fiber, with the latest emitters delivering 14 W with 95% of the slow-axis energy contained within an NA of 0.09. The reduced slow-axis divergence is achieved with an optimized epitaxial design, where the peak optical intensity is reduced to both lessen filamentation within the laser cavity and reduce the power density on the output facet thus increasing the emitter reliability. The low mode filling of the fiber allows it to be coiled with diameters down to 70 mm at full operating power despite the small NA and further eliminates the need for mode-stripping at fiber combiners and splices downstream from our pump modules. 50W fiber pump products at 915, 950 and 975 nm wavelengths are presented, including a wavelengthstabilized version at 976 nm.

  13. Non-Steroid Anti-Infflamatory Drugs in Municipal Wastewater and Surface Waters/ Niesteroidowe Leki Przeciwzaplane W Ściekach Mieskich I Wodach Powierzchniowych

    NASA Astrophysics Data System (ADS)

    Płuciennik-Koropczuk, Ewelina

    2014-09-01

    Increased production and consumption of drugs influences the pollution pharmaceuticals. Recent years have seen a significant increase in the consumption of non-prescription medicines, among which, are a large group of non-steroidal anti-inflammatory drugs (NSAIDs). Research conducted in Poland and abroad showed the presence of NSAIDs, both in treated wastewater in surface waters and drinking waters. One of the most frequently detected drugs in the environment is diclofenac, belongs to NSAID. Its concentration in surface waters range from 9 to 3363 ng/L. Traditional wastewater treatment plants are not specialized enough in removing the pharmaceuticals and their metabolites, and with purified wastewater are introduced into surface waters. Diclofenac concentrations in treated wastewater range from 0.29 to 2.5 μg/L, the average removal efficiency is about 40%. Wzrost produkcji i spożycia leków wpływa na zanieczyszczenie środowiska farmaceutykami. W ostatnich latach zaobserwowano zdecydowany wzrost spożycia leków dostępnych bez recepty, wśród których znaczną grupę stanowią niesteroidowe leki przeciwzapalne (NLPZ). Badania prowadzone na świecie i w Polsce wykazały obecność niesteroidowych leków przeciwzapalnych zarówno w ściekach oczyszczonych, w wodach powierzchniowych oraz w wodach pitnych. Jednym z najczęściej wykrywanych leków w środowisku jest diklofenak należący NLPZ. Jego stężenia w wodach powierzchniowych wynoszą od 9 do 3633 ng/dm3. Tradycyjne układy technologiczne oczyszczania nie eliminują zupełnie farmaceutyków i ich metabolitów i wraz ze ściekami oczyszczonymi są one wprowadzane do wód powierzchniowych. Stężenia diklofenaku w ściekach oczyszczonych wynoszą od 0,29 do 2,5 μg/dm3, a średnia skuteczność usuwania jest na poziomie ok 40%. Należy zaznaczyć, że dane te nie odzwierciedlają stanu rzeczywistego, gdyż badania są prowadzone wyrywkowo. W 2013 r. Komisja Europejska w dyrektywie Parlamentu Europejskiego i

  14. CO dissociation and CO hydrogenation on smooth and ion-bombarded Pd(1 1 1): SFG and XPS spectroscopy at mbar pressures

    NASA Astrophysics Data System (ADS)

    Rupprechter, G.; Kaichev, V. V.; Unterhalt, H.; Morkel, M.; Bukhtiyarov, V. I.

    2004-07-01

    The CO dissociation probability on transition metals is often invoked to explain the product distribution (selectivity) of catalytic CO hydrogenation. Along these lines, we have investigated CO adsorption and dissociation on smooth and ion-bombarded Pd(1 1 1) at pressures up to 1 mbar using vibrational sum frequency generation (SFG) and X-ray photoelectron spectroscopy (XPS). Under high pressure, CO adsorbate structures were observed that were identical to high-coverage structures in UHV. On ion-bombarded surfaces an additional species was detected which was attributed to CO bridge bonded to defect (low-coordinated) sites. On both surfaces, no indications of CO dissociation were found even after hours of 0.1 mbar CO exposure. However, exposing CO/H 2 mixtures to ion-bombarded Pd(1 1 1) produced carbonaceous deposits suggesting CH xO species as precursors for CO bond cleavage and that the formation of CH xO is facilitated by surface defects. The relevance of the observations for CO hydrogenation on Pd catalysts is discussed.

  15. High e+/e– ratio dense pair creation with 10 21W.cm –2 laser irradiating solid targets

    DOE PAGES

    Liang, E.; Clarke, T.; Henderson, A.; ...

    2015-09-14

    In this study, we report results of new pair creation experiments using ~100 Joule pulses of the Texas Petawatt Laser to irradiate solid gold and platinum targets, with intensities up to ~1.9 × 10 21 W.cm –2 and pulse durations as short as ~130 fs. Positron to electron (e+/e–) ratios >15% were observed for many thick disk and rod targets, with the highest e+/e– ratio reaching ~50% for a Pt rod. The inferred pair yield was ~ few ×10 10 with emerging pair density reaching ~10 15/cm 3 so that the pair skin depth becomes < pair jet transverse size.more » These results represent major milestones towards the goal of creating a significant quantity of dense pair-dominated plasmas with e+/e– approaching 100% and pair skin depth << pair plasma size, which will have wide-ranging applications to astrophysics and fundamental physics.« less

  16. Electrical isolation, thermal stability and rf loss in a multilayer GaAs planar doped barrier diode structure bombarded by H+ and Fe+ ions

    NASA Astrophysics Data System (ADS)

    Vo, V. T.; Koon, K. L.; Hu, Z. R.; Dharmasiri, C. N.; Subramaniam, S. C.; Rezazadeh, A. A.

    2004-04-01

    Electrical isolation in multilayer GaAs planar doped barrier (PDB) diode structures produced by H+ and Fe+ ion implantation were investigated. For an H+ bombardment with a dose of 1×1015cm-2, a sheet resistivity as high as 3×108 Ω/sq and thermal stability up to 400 °C has been achieved. For samples bombarded by Fe+ ions, a similar high sheet resistivity has also been achieved although a longer annealing time (15 min) and a higher annealing temperature (550 °C) were needed. The rf dissipation losses of coplanar waveguide (CPW) "thru" lines fabricated on bombarded multilayer PDBD structure samples were also examined. The measured rf losses were 1.65 dB/cm at 10 GHz and 3 dB/cm at 40 GHz, similar to the values that a CPW line exhibits on a semi-isolating GaAs substrate.

  17. 33 CFR 334.950 - Pacific Ocean at San Clemente Island, California; Navy shore bombardment areas.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 33 Navigation and Navigable Waters 3 2014-07-01 2014-07-01 false Pacific Ocean at San Clemente... REGULATIONS § 334.950 Pacific Ocean at San Clemente Island, California; Navy shore bombardment areas. (a) The danger zones. (1) The waters of the Pacific Ocean within an area beginning at China Point Light...

  18. 33 CFR 334.950 - Pacific Ocean at San Clemente Island, California; Navy shore bombardment areas.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... 33 Navigation and Navigable Waters 3 2012-07-01 2012-07-01 false Pacific Ocean at San Clemente... REGULATIONS § 334.950 Pacific Ocean at San Clemente Island, California; Navy shore bombardment areas. (a) The danger zones. (1) The waters of the Pacific Ocean within an area beginning at China Point Light...

  19. 33 CFR 334.950 - Pacific Ocean at San Clemente Island, California; Navy shore bombardment areas.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 33 Navigation and Navigable Waters 3 2013-07-01 2013-07-01 false Pacific Ocean at San Clemente... REGULATIONS § 334.950 Pacific Ocean at San Clemente Island, California; Navy shore bombardment areas. (a) The danger zones. (1) The waters of the Pacific Ocean within an area beginning at China Point Light...

  20. Production of copper-64 and gallium-68 with a medical cyclotron using liquid targets

    NASA Astrophysics Data System (ADS)

    Alves, F.; Alves, V. H. P.; Do Carmo, S. J. C.; Neves, A. C. B.; Silva, M.; Abrunhosa, A. J.

    2017-06-01

    This work describes the production of two clinically relevant metal radioisotopes 64Cu and 68Ga with a medical cyclotron by the irradiation of liquid targets. New results are presented for the implementation of this methodology in a fully automated system, using commercially available equipment. Liquid target solutions containing enriched 64Ni and 68Zn were loaded, bombarded and transferred to synthesis modules where a purified solution containing the desired radiometal is obtained and can then be used to further radiolabeling within only one hour after End-Of-Bombardment (EOB). Typical production runs using enriched material lead to the production of 5 GBq and 6 GBq (0.14 MBq/(μAh ṡ mg) and 1.5 MBq/(μAh ṡ mg)) of 64Cu and 68Ga; although the technique can be used to obtain up to 25 GBq and 40 GBq, respectively, by simply scaling up the amount of the enriched material. Purified solutions containing 64Cu and 68Ga were obtained within 30 min after EOB and used to produce 64Cu-ATSM and 68Ga-DOTA-NOC, respectively, with quality parameters suitable for human use.

  1. Cooling field and ion-beam bombardment effects on exchange bias behavior in NiFe/(Ni,Fe)O bilayers.

    PubMed

    Lin, K W; Wei, M R; Guo, J Y

    2009-03-01

    The dependence of the cooling field and the ion-beam bombardment on the exchange bias effects in NiFe/(Ni,Fe)O bilayers were investigated. The positive exchange bias was found in the zero-field-cooled (ZFC) process whereas a negative exchange bias occurred in the FC process. The increased exchange field, H(ex) with increasing (Ni,Fe)O thicknesses indicates the thicker the AF (Ni,Fe)O, the stronger the exchange coupling between the NiFe layer and the (Ni,Fe)O layer. In addition, the dependence of the H(ex) (ZFC vs. FC) on the (Ni,Fe)O thicknesses reflects the competition between the applied magnetic field and the (Ni,Fe)O surface layer exchange coupled to the NiFe layer. Further, an unusual oscillating exchange bias was observed in NiFe/(Ni,Fe)O bilayers that results from the surface of the (Ni,Fe)O layer being bombarded with different Ar-ion energies using End-Hall deposition voltages (V(EH)) from 0 to 150 V. The behavior of the H(ex) and the H(c) with the V(EH) is attributed to the surface spin reorientation that is due to moderate ion-beam bombardment effects on the surface of the (Ni,Fe)O layer. Whether the (Ni,Fe)O antiferromagnetic spins are coupled to the NiFe moments antiferromagnetically or ferromagnetically changes the sign of the exchange bias.

  2. Plant Type Selection for Reclamation of Sarcheshmeh Copper Mine Using Fuzzy-Topsis Approach / Wybór Gatunków Roślin Do Wykorzystania W Projekcie Rekultywacji Terenów Kopalni Miedzi Sarcheshmeh Z Wykorzystaniem Metod Logiki Rozmytej Topsis

    NASA Astrophysics Data System (ADS)

    Ebrahimabadi, Arash; Alavi, Iraj

    2013-09-01

    ę niewystarczające w przypadku nieprecyzyjnej oceny i nie w pełni zdefiniowanych określeń językowych. W celu przezwyciężenia tych trudności, zaproponowano wielo-kryterialną metodę decyzyjną wykorzystującą logikę rozmytą. Celem tego opracowania jest ukazanie zastosowania podejścia rozmytego do uzyskania kolejnych przybliżeń do rozwiązania idealnego (F.TOPSIS) przy wyborze odpowiednich gatunków roślin do użycia w projekcie rekultywacji terenów kopalni. Wybór gatunków roślin i ich kultywacja dla zapewnienia ochrony środowiska i projektu rekultywacji terenu pogórniczego to bardzo ważne zagadnienia. Głównym celem obecnego studium jest wybór odpowiednich gatunków roślin do wykorzystania projekcie rekultywacji terenów kopalni miedzi Sarcheshmeh z wykorzystaniem metod logiki rozmytej TOPSIS. W pierwszym rzędzie przeprowadzono badania gruntów wokół kopalni miedzi Sarchesmeh, w pobliżu miejscowości Kerman w Iranie (jednej z dziesięciu największych na świecie kopalni miedzi) w celu wyboru najlepszych typów roślin do wykorzystania do rekultywacji naruszonych działalnością górniczą terenów. Określono podstawowe kryteria wyboru, biorąc pod uwagę plan rekultywacji: sposoby wykorzystania terenu, klimat oraz rodzaje gleb. Otrzymano macierze porównawcze uzyskane na podstawie opinii ekspertów, następnie dokonano określenia priorytetów dla poszczególnych roślin przy pomocy metody TOPSIS, wykorzystującej logikę rozmytą. W analizie uwzględniono następujące czynniki drugorzędne: perspektywy dla regionu, odporność na choroby i owady szkodniki, wytrzymałość i sposób uprawy, dostępność danego gatunku roślin, wydajność ekonomiczna, ochrona gleb, zdolność zatrzymywania wody, zapobieganie zanieczyszczeniom. W końcowym etapie dokonano wyboru najkorzystniejszych dla danego terenu górniczego gatunków roślin, podając kolejno: Amygdalus scoparia, Tamarix, Pistachio Wild, Ephedra, Astragalus, Salsola.

  3. Impact-induced concerted mass transport on W surfaces by a voidion mechanism

    NASA Astrophysics Data System (ADS)

    Mazilova, T. I.; Sadanov, E. V.; Voyevodin, V. N.; Ksenofontov, V. A.; Mikhailovskij, I. M.

    2018-03-01

    Using low-temperature field ion microscope techniques, we studied at the atomic level morphological evolution of the W surface through bombardment by a beam of several keV He atoms. This technique allows the direct observation of the results of the high energy He atom impact on the elementary damage stages. The formation of the 〈110〉 and 〈100〉 linear vacancy chains and the high relaxation of the near-neighbors of the surface vacancy clusters were revealed. Performed molecular dynamics simulations shows that a single He atom impact triggers the relaxation process of the linear vacancy chain by a substantial decrease of the distance between atoms at both sides of the chain. The observed inward relaxations in W and Mo are an order of magnitude more than that for a single vacancy. It was revealed a novel highly cooperative impact-induced mass transport mechanism on the stepped surface: the formation and motion of a surface spatially delocalized vacancies (voidions). Surface voidions are extremely mobile: the mean velocity of atoms in voidions equals to a substantial portion of the sound velocity. Successive collective translations of the 〈111〉 lines of atoms in adjacent voidions give rise to a concerted gliding motion of great atomic clusters.

  4. Value of Antiquity in the Restoration Process of the Art Nouveau Villa Duelfer in Barlinek/ Wartość Dawności W Procesie Renowacji Secesyjnej Willi Architekta W Barlinku

    NASA Astrophysics Data System (ADS)

    Rutyna, Halina

    2015-06-01

    The value assigned to time-worn objects and buildings seems crucial to a conservator's theoretical beliefs. The notion of antiquity is almost imprinted in the structure of the building itself, as well as in the concept of the time that has lapsed since the erection of the building. The head of the restoration project of the 1908 art nouveau Villa Duelfer, in Barlinek, which gradually fell into ruin after the war, presents how, in practice, this idea of antiquity was respected in that project. On the hundredth anniversary of the construction of the villa, the building, commonly referred to as the `Pałacyk Cebulowy`, has lived to see its revival by sustaining its primary residential function, its architectural form and its historic values, in an urban context. Kluczowa dla poglądów konserwatora zabytków architektury jawi się idea wartości dawności. Jest ona niejako odciśnięta w strukturze budowli i w wyobrażeniu o czasie, jaki upłynął od chwili powstania. Dobrym przykładem ilustrującym zagadnienie dawności zabytku jest ostatnia renowacja Willi Duelfera w Barlinku, wzniesionej w 1908 roku i potocznie zwanej "Pałacykiem Cebulowym". Po wojnie popadającej w ruinę, W 2008 roku w wyniku konsultacji z konserwatorem zabytków właściciel postanowił przywrócić jej symetrię i dobudować z lewej strony dodatkowe pomieszczenie. Podjęto także rozbudowę wilii od strony zachodniej poprzez dostawienie klatki schodowej i dodanie balkonu opartego na kolumnach na wzór elewacji wschodniej. Dokonano również renowacji zdobień elewacji i odtworzono brakujące elementy od frontu i z tyłu obiektu. Prace przebiegały w szybkim tempie i trwały zaledwie dwa lata, choć budynek był bardzo zniszczony.

  5. Hydrothermal synthesis and structural characterization of an organic–inorganic hybrid sandwich-type tungstoantimonate [Cu(en){sub 2}(H{sub 2}O)]{sub 4}[Cu(en){sub 2}(H{sub 2}O){sub 2}][Cu{sub 2}Na{sub 4}(α-SbW{sub 9}O{sub 33}){sub 2}]·6H{sub 2}O

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Liu, Yingjie; College of Medicine, Henan University, Kaifeng, Henan 475004; Cao, Jing

    An organic–inorganic hybrid sandwich-type tungstoantimonate [Cu(en){sub 2}(H{sub 2}O)]{sub 4}[Cu(en){sub 2}(H{sub 2}O){sub 2}][Cu{sub 2}Na{sub 4}(α-SbW{sub 9}O{sub 33}){sub 2}]·6H{sub 2}O (1) has been synthesized by reaction of Sb{sub 2}O{sub 3}, Na{sub 2}WO{sub 4}·2H{sub 2}O, CuCl{sub 2}·2H{sub 2}O with en (en=ethanediamine) under hydrothermal conditions and structurally characterized by elemental analysis, inductively coupled plasma atomic emission spectrometry, IR spectrum and single-crystal X-ray diffraction. 1 displays a centric dimeric structure formed by two equivalent trivacant Keggin [α-SbW{sub 9}O{sub 33}]{sup 9−} subunits sandwiching a hexagonal (Cu{sub 2}Na{sub 4}) cluster. Moreover, those related hexagonal hexa-metal cluster sandwiched tungstoantimonates have been also summarized and compared. The variable-temperature magneticmore » measurements of 1 exhibit the weak ferromagnetic exchange interactions within the hexagonal (Cu{sub 2}Na{sub 4}) cluster mediated by the oxygen bridges. - Graphical abstract: An organic–inorganic hybrid (Cu{sub 2}Na{sub 4}) sandwiched tungstoantimonate [Cu(en){sub 2}(H{sub 2}O)]{sub 4}[Cu (en){sub 2}(H{sub 2}O){sub 2}][Cu{sub 2}Na{sub 4}(α-SbW{sub 9}O{sub 33}){sub 2}]·6H{sub 2}O was synthesized and magnetic properties was investigated. Display Omitted - Highlights: • Organic–inorganic hybrid sandwich-type tungstoantimonate. • (Cu{sub 2}Na{sub 4} sandwiched) tungstoantimonate [Cu{sub 2}Na{sub 4}(α-SbW{sub 9}O{sub 33}){sub 2}]{sup 10−}. • Ferromagnetic tungstoantimonate.« less

  6. Reducing Energy Degradation Due to Back-bombardment Effect with Modulated RF Input in S-band Thermionic RF Gun

    NASA Astrophysics Data System (ADS)

    Kii, Toshiteru; Nakai, Yoko; Fukui, Toshio; Zen, Heishun; Kusukame, Kohichi; Okawachi, Norihito; Nakano, Masatsugu; Masuda, Kai; Ohgaki, Hideaki; Yoshikawa, Kiyoshi; Yamazaki, Tetsuo

    2007-01-01

    Energy degradation due to back-bombardment effect is quite serious to produce high-brightness electron beam with long macro-pulse with thermionic rf gun. To avoid the back-bombardment problem, a laser photo cathode is used at many FEL facilities, but usually it costs high and not easy to operate. Thus we have studied long pulse operation of the rf gun with thermionic cathode, which is inexpensive and easy to operate compared to the photocathode rf gun. In this work, to reduce the energy degradation, we controlled input rf power amplitude by controlling pulse forming network of the power modulator for klystron. We have successfully increased the pulse duration up to 4 μs by increasing the rf power from 7.8 MW to 8.5 MW during the macro pulse.

  7. Thermochemical Properties of the Lattice Oxygen in W,Mn-Containing Mixed Oxide Catalysts for the Oxidative Coupling of Methane

    NASA Astrophysics Data System (ADS)

    Lomonosov, V. I.; Gordienko, Yu. A.; Sinev, M. Yu.; Rogov, V. A.; Sadykov, V. A.

    2018-03-01

    Mixed NaWMn/SiO2 oxide, samples containing individual components (Na, W, Mn) and their double combinations (Na-W, Na-Mn, W-Mn) supported on silica were studied by temperature programmed reduction (TPR) and desorption (TPD), and heat flow calorimetry during their reoxidation with molecular oxygen in pulse mode. The NaWMn/SiO2 mixed oxide was shown to contain two different types of reactive lattice oxygen. The weakly-bonded oxygen can be reversibly released from the oxide in a flow of inert gas in the temperature range of 575‒900°C, while the strongly-bonded oxygen can be removed during the reduction of the sample with hydrogen at 700-900°C. The measured thermal effect of oxygen consumption for these two oxygen forms are 185 and 350 kJ/mol, respectively. The amount of oxygen removed at reduction ( 443 μmol/g) considerably exceeded the amount desorbed in an inert gas flow ( 56 μmol/g). The obtained results suggest that the reversible oxygen desorption is due to the redox process in which manganese ions are involved, while during the temperature programmed reduction, mainly oxygen bonded with tungsten is removed.

  8. Desorption isotherms of salted minced pork using K-lactate as a substitute for NaCl.

    PubMed

    Muñoz, I; Arnau, J; Costa-Corredor, A; Gou, P

    2009-12-01

    The aim of this study was to obtain and compare water desorption isotherms of ground meat containing NaCl (0.107kg NaCl/kg raw-meat dry matter) and/or K-lactate as NaCl substitute at two different levels of molar substitution (30% and 100%). A thin layer of salted ground meat was dried and sampled at pre-determined times. The moisture content of the samples and their water activities (a(w)) were measured at 5°C and 25°C. Results showed that ground meat with NaCl and/or different K-lactate contents had a similar water desorption isotherm for a(w) ranging from 0.7 to 1.0. Below 0.7, the water equilibrium content fell with small decreases in a(w) faster for meat with NaCl than for meat with K-lactate. K-lactate could reduce the excessive hardening at the surface of salted meat products. Experimental desorption isotherms were compared to those estimated using two approaches of the Ross equation. Models provided a good fit for the experimental data.

  9. The Application of Modern Techniques and Measurement Devices for Identification of Copper Ore Types and Their Properties / Wykorzystanie nowoczesnych technik i urządzeń pomiarowych do identyfikacji typów rud miedzi i ich właściwości

    NASA Astrophysics Data System (ADS)

    Krawczykowska, Aldona; Trybalski, Kazimierz; Krawczykowski, Damian

    2013-06-01

    The paper concerns the application of modern methods and research techniques for investigations of copper ore properties. It presents the procedure and tools which, when put together, can constitute a source of information on properties of different products of processing and, simultaneously, can be used in the process control and optimization. The copper ore of one of the branches of the KHGM Polska Miedz plc was investigated. The ore samples represented each of the three lithological types occurring in the Polish deposits, i.e. carbonate, shale and sandstone ores. The paper presents the results of microscopic analyses, image analysis of scanning photographs and application procedures of the obtained information for the identification of ore types (application of neuron networks to the recognition of lithological compositions). The present publication will present sample results of modelling of classification identifying two types of ores, i.e. carbonate-shale and sandstone. Summing up the predictions of ore type fractions in respective mixtures for the considered problem of classification it can be stated that the prediction results are good and confirm the lithological predominance of certain ore types in the investigated mixtures. The experimental part comprised the determination of mineralogical and lithological composition of ores (optical microscope) and also elemental composition in the microareas of analysed samples (scanning microscope). Next, the image analysis was performed and subsequently the models classifying the ore types were made. W rudzie miedzi przerabianej w zakładach wzbogacania O/ZWR KGHM Polska Miedź S.A. można wyróżnić trzy typy litologiczne: rudę węglanową, łupkową i piaskowcową. Typy te różnią się właściwościami między innymi takimi jak: rodzaj i zawartość minerałów miedzi, rodzaj minerałów nieużytecznych, zawartość miedzi, twardość i podatność na rozdrabnianie, ale także wielkością i kształtem ziaren

  10. N(50) Crater Retention Ages for an Expanded Inventory of Lunar Basins: Evidence for an Early Heavy Bombardment and a Late Heavy Bombardment?

    NASA Technical Reports Server (NTRS)

    Frey, Herbert; Burgess, Emily

    2012-01-01

    LOLA topography and LOLA-derived crustal thickness data provide evidence for a population of impact basins on the Moon that is likely a factor 2 larger than the classical lists based on photogeology. Frey (2012) determined N(50) crater retention ages (CRAs) for 83 candidate basins > 300 km in diameter by counting LOLA-identified craters superimposed over the whole area of the basins. For some basins identified in topography or model crustal thickness it is not possible to unambiguously identify the crater rim as is traditionally done. Also, Quasi-Circular Depressions (QCDs) > 50 km in diameter are recognizable in the mare-filled centers of many basins. Even though these are not apparent in image data, they likely represent buried impact craters superimposed on the basin floor prior to mare infilling and so should be counted in determining the age of the basin. Including these as well as the entire area of the basins improves the statistics, though the error bars are still large when using only craters > 50 km in diameter. The distribution of N(50) CRAs had two distinct peaks which did not depend on whether the basins were named (based on photogeology) or recognized first in topography or crustal thickness data. It also did not depend on basin diameters (both larger and smaller basins made up both peaks) and both peaks persisted even when weaker candidates were excluded. Burgess (2012, unpublished data) redid the counts for 85 basins but improved on the earlier effort by adjusting the counting area where basins overlap. The two peak distribution of N(50) ages was confirmed, with a younger peak at N(50) 40-50 and an older peak at N(50) 80-90 (craters > 50 km diameter per million square km). We suggest this could represent two distinct populations of impactors on the Moon: one producing an Early Heavy Bombardment (EHB) that predates Nectaris and the second responsible for the more widely recognized Late Heavy Bombardment (LHB).

  11. Diode-Pumped Narrow Linewidth Multi-kW Metalized Yb Fiber Amplifier

    DTIC Science & Technology

    2016-10-01

    multi-kW Yb fiber amplifier in a bi-directional pumping configuration. Each pump outputs 2 kW in a 200 µm, 0.2 NA multi-mode fiber. Gold -coated...multi-mode instability, with 90% O-O efficiency 12 GHz Linewidth and M2 < 1.15. OCIS codes: (140.3510) Lasers , fiber; (140.3615) Lasers , ytterbium...060.2430) Fibers, single-mode. 1. INTRODUCTION Yb-doped fiber laser has experienced exponential growth over the past decade. The output power

  12. Fentanyl-related designer drugs W-18 and W-15 lack appreciable opioid activity in vitro and in vivo.

    PubMed

    Huang, Xi-Ping; Che, Tao; Mangano, Thomas J; Le Rouzic, Valerie; Pan, Ying-Xian; Majumdar, Susruta; Cameron, Michael D; Baumann, Michael H; Pasternak, Gavril W; Roth, Bryan L

    2017-11-16

    W-18 (4-chloro-N-[1-[2-(4-nitrophenyl)ethyl]-2-piperidinylidene]-benzenesulfonamide) and W-15 (4-chloro-N-[1-(2-phenylethyl)-2-piperidinylidene]-benzenesulfonamide) represent two emerging drugs of abuse chemically related to the potent opioid agonist fentanyl (N-(1-(2-phenylethyl)-4-piperidinyl)-N-phenylpropanamide). Here, we describe the comprehensive pharmacological profiles of W-18 and W-15, as examination of their structural features predicted that they might lack opioid activity. We found W-18 and W-15 to be without detectible activity at μ, δ, κ, and nociception opioid receptors in a variety of assays. We also tested W-18 and W-15 for activity as allosteric modulators at opioid receptors and found them devoid of significant positive or negative allosteric modulatory activity. Comprehensive profiling at essentially all the druggable GPCRs in the human genome using the PRESTO-Tango platform revealed no significant activity. Weak activity at the sigma receptors and the peripheral benzodiazepine receptor was found for W-18 (Ki = 271 nM). W-18 showed no activity in either the radiant heat tail-flick or the writhing assays and also did not induce classical opioid behaviors. W-18 is extensively metabolized, but its metabolites also lack opioid activity. Thus, although W-18 and W-15 have been suggested to be potent opioid agonists, our results reveal no significant activity at these or other known targets for psychoactive drugs.

  13. Geotechnical Risk Classification for Underground Mines / Klasyfikacja Poziomu Zagrożenia Geotechnicznego W Kopalniach Podziemnych

    NASA Astrophysics Data System (ADS)

    Mishra, Ritesh Kumar; Rinne, Mikael

    2015-03-01

    poważne straty finansowe. Wykorzystanie przepisowych metod oceny ryzyka w przeszłości wykazało ich istotną rolę w przewidywaniu i zapobieganiu wypadkom i zagrożeniom w dziedzinach najbardziej na nie narażonych, a więc w przemyśle naftowym, jądrowym oraz w lotnictwie. W niniejszej pracy zaproponowano system klasyfikacji operacji w górnictwie podziemnym w oparciu o poziom zagrożenia geotechnicznego. Klasyfikacji dokonano uwzględniając zastosowana metodę urabiania oraz rodzaj urabianego górotworu. Przedstawiono kategorie metod urabiania o podobnym poziomie zagrożenia geotechnicznego. Zaproponowano klasyfikację górotworu na podstawie właściwości wytrzymałościowych określanych rutynowo na etapie planowania kopalni. Klasyfikacja ta podzielona jest na kilka pod-etapów odpowiadającym etapom planowania kopalni, tak by uwzględnić zakres dostępnych na każdym etapie danych. Zastosowano kodowanie alfanumeryczne dla wskazania metody urabiania w oparciu o dane o zwięzłości skały i ryzyko zagrożenia geotechnicznego. Kodowanie alfanumeryczne zostało następnie rozszerzone dla identyfikacji operacji górniczych w ramach kategorii "Poziom zagrożenia geotechnicznego". Wskaźnik ten wykorzystywany jest jako wstępne narzędzie oceny ryzyka wystąpienia zagrożenia oraz klasyfikacji poziomu zagrożenia związanego z działalnością górniczą. Celem takiej klasyfikacji jest jej wykorzystanie jako wytycznych i uzasadnienia dla stosowania formalnych metod oceny ryzyka geotechnicznego.

  14. Impact Characteristics of Different Rocks in a Pulsed Laser Irradiation Experiment: Simulation of Micrometeorite Bombardment on the Moon

    NASA Astrophysics Data System (ADS)

    Wu, Yanxue; Li, Xiongyao; Yao, Wenqing; Wang, Shijie

    2017-10-01

    Without the protection of the atmosphere, the soils on lunar surfaces undergo a series of optical, physical, and chemical changes during micrometeorite bombardment. To simulate the micrometeorite bombardment process and analyze the impact characteristics, four types of rocks, including terrestrial basalt and anorthosite supposed to represent lunar rock, an H-type chondrite (the Huaxi ordinary chondrite), and an iron meteorite (the Gebel Kamil iron meteorite) supposed to represent micrometeorite impactors, are irradiated by a nanosecond pulse laser in a high vacuum chamber. Based on laser irradiation experiments, the laser pits are found to be of different shapes and sizes which vary with the rock type. Many melt and vapor deposits are found on the mineral surfaces of all the samples, and nanophase iron (npFe) or Fe-Ni alloy particles are typically distributed on the surfaces of ilmenite, kamacite, or other minerals near kamacite. By analyzing the focused ion beam ultrathin slices of laser pits with a transmission electron microscope, the results show that the subsurface structures can be divided into three classes and that npFe can be easily found in Fe-bearing minerals. These differences in impact characteristics will help determine the source material of npFe and infer the type of micrometeorite impactors. During micrometeorite bombardment, in the mare regions, the npFe are probably produced simultaneously from lunar basalt and micrometeorites with iron-rich minerals, while the npFe in the highlands regions mainly come from micrometeorites.

  15. Application of Rqd-Number and Rqd-Volume Multifractal Modelling to Delineate Rock Mass Characterisation in Kahang Cu-Mo Porphyry Deposit, Central Iran / Zastosowanie Metod Modelowania Numerycznego Oraz Modelowania Fraktalnego do Analizy JAKOŚCI SKAŁ W Celu OKREŚLENIA Charakterystyki GÓROTWORU W Obszarze ZŁOŻA Cu-Mo W Kahang, ŚRODKOWY Iran

    NASA Astrophysics Data System (ADS)

    Yasrebi, Amir Bijan; Wetherelt, Andrew; Foster, Patrick J.; Afzal, Peyman; Coggan, John; Ahangaran, Dariush Kaveh

    2013-12-01

    Identification of rock mass properties in terms of Rock Quality Designation (RQD) plays a significant role in mine planning and design. This study aims to separate the rock mass characterisation based on RQD data analysed from 48 boreholes in Kahang Cu-Mo porphyry deposit situated in the central Iran utilising RQD-Volume (RQD-V) and RQD-Number (RQD-N) fractal models. The log-log plots for RQD-V and RQD-N models show four rock mass populations defined by RQD thresholds of 3.55, 25.12 and 89.12% and 10.47, 41.68 and 83.17% respectively which represent very poor, poor, good and excellent rocks based on Deere and Miller rock classification. The RQD-V and RQD-N models indicate that the excellent rocks are situated in the NW and central parts of this deposit however, the good rocks are located in the most parts of the deposit. The results of validation of the fractal models with the RQD block model show that the RQD-N fractal model of excellent rock quality is better than the RQD-V fractal model of the same rock quality. Correlation between results of the fractal and the geological models illustrates that the excellent rocks are associated with porphyric quartz diorite (PQD) units. The results reveal that there is a multifractal nature in rock characterisation with respect to RQD for the Kahang deposit. The proposed fractal model can be intended for the better understanding of the rock quality for purpose of determination of the final pit slope. Identyfikacja właściwości górotworu odgrywa zasadniczą rolę w planowaniu wydobycia i projektowaniu kopalni. Praca niniejsza ma na celu określenie charakterystyki górotworu w oparciu o dane o jakości skał zebrane na podstawie próbek uzyskanych z 48 odwiertów wykonanych w złożu porfiru Cu-Mo w Kahang, zalegającym w środkowym Iranie przy użyciu modeli fraktalnych RQD-V - Rock Quality Determination-Volume [Określenie jakości skał-objętość]) i RQD-N (Rock Quality Determination-Number [Określenie jakości ska

  16. Temperature-dependent change in the nature of glass fracture under electron bombardment

    NASA Astrophysics Data System (ADS)

    Kravchenko, A. A.

    1991-04-01

    We report the experimental discovery of a temperature-dependent change in the nature of glass fracture under low-energy (<10 keV) electron bombardment. This is shown to depend on the transition from the thermal-shock to the thermalfluctuation mechanism of fracture at the limiting temperature T1 = (Tg - 150) °C. The high-temperature cleavage fracture of K8 and TF1 glasses was studied and the threshold value of the critical power initiating cleavage fracture was determined (for the glasses studied Θthr = 50 70 W·sec·cm-2).

  17. First search for a dark matter annual modulation signal with NaI(Tl) in the Southern Hemisphere by DM-Ice17

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Barbosa de Souza, E.; Cherwinka, J.; Cole, A.

    The first search for a dark matter annual modulation signal with NaI(Tl) target material in the Southern Hemisphere conducted with the DM-Ice17 experiment is presented. DM-Ice17 consists of 17 kg of NaI(Tl) scintillating crystal under 2200 m.w.e. overburden of Antarctic glacial ice. The analysis presented here utilizes a 60.8 kg yr exposure. While unable to exclude the signal reported by DAMA/LIBRA, the DM-Ice17 data are consistent with no modulation in the energy range of 4-20 keV, providing the strongest limits on WIMP candidates from a direct detection experiment located in the Southern Hemisphere. Additionally, the successful deployment and stable operationmore » of 17 kg of NaI(Tl) crystal over 3.5 years establishes the South Pole ice as a viable location for future underground, low-background experiments.« less

  18. Self-vapor cooled targets for production of I-123 at high current accelerators. [using Xe-123 production

    NASA Technical Reports Server (NTRS)

    Blue, J. W.; Scholz, K. L.; Sodd, V. J.

    1974-01-01

    The basic elements of the vapor cooled target system are shown. This system can be operated as a heat pipe or as a conventional condenser. The choice of target fluid is based on the specific nuclear reaction chosen to produce Xe-123. The reaction using I-127 was studied and shown to have a significant yield for bombarding energies from 47 to 63 MeV. The Cs-133 reaction is also included. Xenon-123 is applied to I-123 production in a purer form for thyroid studies.

  19. Characterization and fabrication of target materials for RIB generation

    NASA Astrophysics Data System (ADS)

    Welton, R. F.; Janney, M. A.; Mueller, P. E.; Ortman, W. K.; Rauniyar, R.; Stracener, D. W.; Williams, C. L.

    2001-07-01

    This report discusses two techniques developed at the Oak Ridge National Laboratory (ORNL) that are employed for the fabrication and characterization of targets used in the production of Radioactive Ion Beams (RIBs). First, our method of in-house fabrication of uranium carbide targets is discussed. We have found that remarkably uniform coatings of UC2 can be formed on the microstructure of porous C matrices. The technique has been used to form UC2 layers on highly thermally conductive graphitic foams. Targets fabricated in this fashion have been tested under low-intensity proton bombardment and yields of selected radioactive species are reported. This report also describes an off-line test stand for the investigation of effusive and diffusive transport in RIB target/ion sources. Permeation rates of gases and vapors passing through a high temperature membrane or through an effusive channel constructed from the material under investigation are recorded. Diffusion coefficients and adsorption enthalpies, which characterize the interaction of RIB species with materials of the target/ion source, are extracted from the time profile of the recorded data. Examples of diffusion, effusion, and conductance measurements are provided.

  20. 800-MeV proton irradiation of thorium and depleted uranium targets

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Russell, G.J.; Brun, T.O.; Pitcher, E.J.

    As part of the Los Alamos Fertile-to-Fissile-Conversion (FERFICON) program in the late 1980`s, thick targets of the fertile materials thorium and depleted uranium were bombarded by 800-MeV protons to produce the fissile materials {sup 233}U and {sup 239}Pu, respectively. The amount of {sup 233}U made was determined by measuring the {sup 233}Pa activity, and the yield of {sup 239}Pu was deduced by measuring the activity of {sup 239}Np. For the thorium target, 4 spallation products and 34 fission products were also measured. For the depleted uranium target, 3 spallation products and 16 fission products were also measured. The number ofmore » fissions in each target was deduced from fission product mass-yield curves. In actuality, axial distributions of the products were measured, and the distributions were then integrated over the target volume to obtain the total number of products for each reaction.« less

  1. Accuracy Estimation of the Approximated Methods Used for Assessing Risk of Buildings Damage Under the Influence of Underground Exploitation in the Light of World's and Polish Experience - Part 2 / Analiza Dokładności Przybliżonych Metod Oceny Zagrożenia Budynków Wpływami Podziemnej Eksploatacji Stosowanych W Świecie I Polskiej Metody Punktowej - Część 2

    NASA Astrophysics Data System (ADS)

    Malinowska, Agnieszka

    2013-09-01

    This paper is a continuation of theoretical analyses of World's methods used for assessing damage risk to buildings with continuous strains, which were presented in Part 1. The authors focus only on those methods in which the scale of damage to buildings can be approximated. Selected methods were tested on 100 random objects sited in hard coal excavation-induced areas. The efficiency and effectiveness of those methods was evaluated. The damage risk was also verified with the use of a method currently used in Poland. The efficiency results obtained for World's methods and the one used in Poland turned out to be comparable. Practical studies were made to evaluate the adaptability of those methods in the underground exploitation-induced conditions in Poland. Artykuł stanowi kontynuację badań teoretycznych zaprezentowanych w części pierwszej, dotyczących oceny możliwości wykorzystania metod stosowanych na świecie do oceny zagrożenia budynków deformacjami ciągłymi. Skoncentrowano się jedynie na metodach pozwalających na przybliżoną ocenę stopnia uszkodzenia obiektów. Wybrane metody przetestowano na 100 losowo wybranych obiektach z terenu poddanego wpływom eksploatacji węgla kamiennego. Przyjęty tok postępowania pozwolił na ocenę efektywności oraz skuteczności tych metod. Ocenę zagrożenia budynków przeprowadzono również przy wykorzystaniu metody stosowanej obecnie w Polsce. Wyniki ewaluacji zagrożenia metodami światowymi można było porównać z efektywnością Polskiej metody. Badania praktyczne pozwoliły na ocenę możliwości adaptacji tych metod w warunkach eksploatacji podziemnej w Polsce.

  2. Combined effect of Pt and W alloying elements on Ni-silicide formation

    NASA Astrophysics Data System (ADS)

    Luo, T.; Mangelinck, D.; Descoins, M.; Bertoglio, M.; Mouaici, N.; Hallén, A.; Girardeaux, C.

    2018-03-01

    A combinatorial study of the combined effect of Pt and W on Ni silicide formation is performed. Ni(Pt, W) films with thickness and composition gradients were prepared by a co-deposition composition spread technique using sputtering deposition from Pt, W, and Ni targets. The deposited Ni(Pt,W) films were characterized by X-ray diffraction, X-ray reflectivity, Rutherford backscattering, and atom probe tomography. The maximum content of alloying elements is close to 27 at. %. Simulations of the thickness and composition were carried out and compared with experimental results. In situ X-ray diffraction and atom probe tomography were used to study the phase formation. Both additive alloying elements (Pt + W) slow down the Ni consumption and the effect of W is more pronounced than the one of Pt. Regarding the effect of alloying elements on Ni silicides formation, three regions could be distinguished in the Ni(Pt,W)/Si wafer. For the region close to the Ni target, the low contents of alloying elements (Pt + W) have little impact on the phase sequence (δ-Ni2Si is the first silicide and NiSi forms when Ni is entirely consumed) but the kinetics of silicide formation slows down. The region close to the Pt target has high contents of (Pt + W) and is rich in Pt and a simultaneous phase formation of δ-Ni2Si and NiSi is observed. For the high (Pt + W) contents and W-rich region, NiSi forms unexpectedly before δ-Ni2Si and the subsequent growth of δ-Ni2Si is accompanied by the NiSi consumption. When Ni is entirely consumed, NiSi regrows at the expense of δ-Ni2Si.

  3. Band gap engineering of NaTaO3 using density functional theory: a charge compensated codoping strategy.

    PubMed

    Modak, Brindaban; Srinivasu, K; Ghosh, Swapan K

    2014-08-28

    In this theoretical study, we employ a codoping strategy to reduce the band gap of NaTaO3 aimed at improving the photocatalytic activity under visible light. The systematic study includes the effects of metal (W) and nonmetal (N) codoping on the electronic structure of NaTaO3 in comparison to the effect of individual dopants. The feasibility of the introduction of N into the NaTaO3 crystal structure is found to be enhanced in the presence of W, as indicated by the calculated formation energy. This codoping leads to formation of a charge compensated system, beneficial for the minimization of vacancy related defect formation. The electronic structure calculations have been carried out using a hybrid density functional for an accurate description of the proposed system. The introduction of W in place of Ta leads to the appearance of donor states below the conduction band, while N doping in place of oxygen introduces isolated acceptor states above the valence band. The codoping of N and W also passivates undesirable discrete midgap states. This feature is not observed in the case of (Cr, N) codoped NaTaO3 in spite of its charge compensated nature. We have also studied charge non-compensated codoping using several dopant pairs, including anion-anion and cation-anion pairs. However, this non-compensated codoping introduces localized states in between the valence band and the conduction band, and hence may not be effective in enhancing the photocatalytic properties of NaTaO3. The optical spectrum shows that the absorption curve for the (W, N)-codoped NaTaO3 is extended to the visible region due to narrowing of the band gap to 2.67 eV. Moreover, its activity for the photo decomposition of water to produce both H2 and O2 remains intact. Hence, based on the present investigation we can propose (W, N) codoped NaTaO3 as a promising photocatalyst for visible light driven water splitting.

  4. Energy Carriers Use in the World: Natural Gas - Conventional and Unconventional Gas Resources / Wykorzystanie Nośników Energii w Świecie: Zasoby Gazu Ziemnego w Złożach Konwencjonalnych i Niekonwencjonalnych

    NASA Astrophysics Data System (ADS)

    Siemek, Jakub; Nagy, Stanisław

    2012-11-01

    This paper discusses forecasts of energy carrier use with particular emphasis on the changing position of natural gas due to global climatic conditions and the increasing role of unconventional natural gas reservoirs. Allocation of natural gas resources in the world are discussed as well as global gas consumption and conditions for development of transport infrastructure and storage. The most important indicators of the energy security of countries are presented. The basic properties of unconventional deposits, and differences in the production/extraction of gas from the conventional and unconventional fields are given. In the paper are also discussed natural gas reserves in Poland, including possible non-conventional resources in the fields and issues of increasing the role of gas as an energy carrier in Poland in the background of the energy changes in Europe and the world. W pracy omówiono prognozy energetyczne wykorzystania energii ze szczególnym uwzględnieniem zmieniającej się pozycji gazu ziemnego z uwagi na uwarunkowania klimatyczne oraz wzrastającą role niekonwencjonalnych złóż gazu ziemnego. Omówiono alokację zasobów gazu ziemnego w świecie, zużycie gazu w regionach oraz warunki rozbudowy infrastruktury transportu i magazynowania. Przedstawiono najważniejsze wskaźniki dotyczące bezpieczeństwa energetycznego krajów. Omówiono podstawowe własności złóż niekonwencjonalnych oraz różnice w charakterze wydobycia gazu ze złóż konwencjonalnych i niekonwencjonalnych. Omówiono zasoby gazu w Polsce, w tym możliwe zasoby w złożach niekonwencjonalnych oraz zagadnienia zwiększenia roli gazu jako nośnika energii w Polsce w tle energetycznych zmian Europy i świata.

  5. 330 W Cryocooler Developments and Testing

    NASA Astrophysics Data System (ADS)

    Emery, N.; Caughley, A.; Nation, M.; Kimber, A.; Allpress, N.; Reynolds, H.; Boyle, C.; Meier, J.; Tanchon, J.

    2015-12-01

    Fabrum Solutions in association with Callaghan Innovation and Absolut System has developed a 330 W pulse tube cryocooler based on Callaghan Innovation's novel diaphragm pressure wave generators (DPWG). A cost-effective, long life and robust cryocooler has been achieved due to the pulse tube's lack of moving parts and the DPWG's metal diaphragms separating the working gas from the oil lubricated drive mechanism. A 330 cc DPWG was designed and manufactured to run with an inline pulse tube. Absolut System carried out the pulse tube design; manufacture was by Fabrum Solutions, with integration and testing by Callaghan Innovation. The 330 W pulse tubes were run as cryocoolers mounted to 330 cc DPWG's. 480 W of cooling power at 77 K was achieved (target was 330 W at 77 K) from 7kW PV power and 12 kW of electrical input power. An endurance cryocooler was assembled with the left over parts from the optimization exercise. The endurance cryocooler was assembled to run as a liquefier. Calculation showed that 1 litre per hour of liquid nitrogen production was possible from 91 W of cooling power at 83 K. 1 litre per hour of liquid nitrogen was successfully produced for every 100 W of cooling power at 83 K, in a commercial application. Three more 330 W pulse tubes have been mounted to a single 1000 cc DPWG to produce > 1 kW of cooling power at 77 K. The commercialisation of the 1000 W cryocooler is the topic of another paper presented at this conference. Details of the design, development, testing and integration of the 330 W cryocooler are presented in this paper.

  6. Preparation and surface characteristics of Re3W matrix scandate cathode: An experimental and theoretical study

    NASA Astrophysics Data System (ADS)

    Lai, Chen; Wang, Jinshu; Zhou, Fan; Liu, Wei; Hu, Peng; Wang, Changhao; Wang, Ruzhi; Miao, Naihua

    2018-05-01

    The Scandia doped thermionic cathodes have received great attention owing to their high electron emission density in past two decades. Here, Scandia doped Re3W matrix scandate (RS) cathodes are fabricated by using Sc2O3 doped Re3W powders that prepared by spray drying method. The micromorphology, surface composition and chemical states of RS cathode are investigated with various modern technologies. It reveals that the reduction temperature of RS powders is dramatically increased by Sc2O3. On the surface of RS cathode, a certain amount of Sc2O3 nanoparticles and barium salt submicron particles are observed. According to the in situ Auger electron spectroscopy analysis, the concentration ratio of Ba:Sc:O is determined to be 2.9:1.1:2.7. The X-ray photoelectron spectroscopy data indicates that low oxidation state of Sc is clearly observed in scandate cathodes. The high atomic ratio of Ba on RS cathode surface is suggested due to the high adsorption of Re3W to Ba. Moreover, RS cathode shows better adsorption to Sc by comparison with conventional tungsten matrix scandate cathode. For RS cathode, the main depletion of Sc is suggested to -OSc desorbing from RS cathode surface. RS cathode is expected to be an impressive thermionic cathode with good emission properties and ion anti-bombarding insensitivity.

  7. TADPOLE satellite. [low cost synchronous orbit satellite to evaluate small mercury bombardment ion thruster applications

    NASA Technical Reports Server (NTRS)

    1974-01-01

    A low cost synchronous orbit satellite to evaluate small mercury bombardment ion thruster applications is described. The ion thrusters provide the satellite with precise north-south and east-west stationkeeping capabilities. In addition, the thrusters are used to unload the reaction wheels used for attitude control and for other purposes described in the report. The proposed satellite is named TADPOLE. (Technology Application Demonstration Program of Low Energy).

  8. Unique Project of Single-Cutting Head Longwall Shearer Used for Thin Coal Seams Exploitation / Projekt Jednoorganowego Kombajnu ŚCIANOWEGO O Specjalnej Konstrukcji Przeznaczonego do Eksploatacji POKŁADÓW Cienkich

    NASA Astrophysics Data System (ADS)

    Bołoz, Łukasz

    2013-12-01

    Problem of thin hard coal seams exploitation, including chosen data related with their resources in Poland, has been discussed in the introduction of the present study. On the basis of actually operated machines the assumptions, which should be satisfied by the longwall shearer used for exploitation of thin hard coal seams, have been made. A project of such longwall shearer combined with band conveyor and mechanized longwall support, including description of the machine operation technology and analysis of possible day output achievement, have been presented. Polska dysponuje stosunkowo dużymi zasobami surowców energetycznych, a ciągle rosnące zapotrzebowanie na energię skłania do ich racjonalnego wykorzystywania. Jedną z możliwości takiego racjonalnego gospodarowania zasobami naturalnymi jest eksploatacja węgla kamiennego z pokładów cienkich. W związku z wybieraniem coraz cieńszych pokładów węgla, zalegających bardzo głęboko, w trudnych warunkach górniczo-geologicznych napotyka się na duże problemy związane z uzyskaniem wymaganej wydajności wydobycia przy użyciu stosowanych aktualnie metod. Przyjmuje się, ze pokłady cienkie to takie o miąższości od 1.0 m do 1.5 m i właśnie ta niewielka wysokość wyrobiska ścianowego powoduje szereg ograniczeń związanych z efektywną eksploatacją węgla. Na podstawie dostępnych danych określono, że ilości węgla kamiennego w cienkich pokładach wynosi około 600 mln Mg. Znaczna część pokładów cienkich w ostatnich latach została przeklasyfikowana na nieprzemysłowe, co pozwala stwierdzić, że rzeczywista ilość węgla w pokładach cienkich jest znacznie większa. Na podstawie analizy wad i zalet jak i danych technicznych produkowanych obecnie maszyn, określono wytyczne i założenia do nowego rozwiązania maszyny urabiającej przeznaczonej do wydobywania węgla w ścianach niskich. Kombajn do eksploatacji cienkich pokładów powinien spełniać następujące wymagania (Bołoz, 2012

  9. Functionalized NbS2 as cathode for Li- and Na-ion batteries

    NASA Astrophysics Data System (ADS)

    Zhu, Jiajie; Alshareef, Husam N.; Schwingenschlögl, Udo

    2017-07-01

    Cathodes of Li- and Na-ion batteries usually have capacities <200 mAh/g, significantly less than the anodes. Two-dimensional materials can overcome this limitation but suffer from low voltages. In this context, we investigate NbS2 functionalized by O, F, and Cl as a cathode material by first-principles calculations, considering both the conversion and intercalation mechanisms. NbS2O2 shows a higher voltage than NbS2 for both Li and Na, but the voltage decreases drastically for increasing ion coverage. Even higher voltages and favorable dependences on the ion coverage are achieved by F and Cl functionalization. We obtain NbS2F2 and NbS2Cl2 energy densities of 1223 mW h/g and 823 mW h/g for lithiation and 1086 mW h/g and 835 mW h/g for sodiation, respectively. These values are higher than those for most state-of-the-art cathode materials ( ˜600 mW h/g). In addition, low diffusion barriers enable high cycling rates.

  10. Analytical Method of Designing and Selecting Take-Up Systems for Mining Belt Conveyors / Analityczna Metoda Projektowania i Doboru UKŁADÓW Napinania Dla GÓRNICZYCH PRZENOŚNIKÓW TAŚMOWYCH

    NASA Astrophysics Data System (ADS)

    Kulinowski, Piotr

    2013-12-01

    This article presents a method developed to design and select tensioning systems which makes use of standard calculations. It describes procedures for selecting and analysing the operation of devices tensioning the belt, which procedures are based on the static characteristics of these devices, and a proposal for introducing a substitute belt elasticity modulus that would make the calculations of the tensioning stroke length account for the value of the initial force tensioning the belt and for its sag between sets of idlers. Static characteristics of tensioning systems have been used to describe their operation and present the advantages and disadvantages of individual design solutions W artykule przedstawiono opracowaną metodę projektowania i doboru układów napinania taśmy wykorzystującą stosowane standardowe procedury obliczeniowe uzupełnione o zależności analityczne uwzględniające zwis taśmy między zestawami krążnikowymi i charakterystyki statyczne urządzeń napinających taśmę. W pierwszej części publikacji opisano analityczną metodę doboru układu napinania taśmy bazującą na wynikach obliczeń sił w taśmie i szacunkowych kalkulacjach drogi napinania taśmy stosowanych obecnie w standardowych procedurach obliczeniowych (Golka i in., 2007; Gładysiewicz, 2003; Żur i Hardygóra, 1996). Następnie przedstawiono propozycję uzupełnienia stosowanej metody analitycznej o wprowadzenie diagramu drogi napinania i uwzględnienie zastępczego modułu sprężystości taśmy (Kulinowski, 2012). W obliczeniach standardowych przyjmuje się, że długość odcinka taśmy pomiędzy zestawami krążnikowymi jest równa ich rozstawowi. W rzeczywistych warunkach może się zdarzyć, że na niektórych odcinkach złożonego profilu trasy przenośnika wartość zwisu taśmy przekracza wartości dopuszczalne, wtedy długość taśmy między zestawami krążnikowymi jest znacząco większa od rozstawu zestawów. W takich przypadkach wartość modułu spr

  11. Using the Geminids to Characterize the Surface Response of an Airless Body to Meteoroid Bombardment

    NASA Astrophysics Data System (ADS)

    Szalay, J.; Pokorny, P.; Jenniskens, P. M. M.; Horanyi, M.

    2017-12-01

    All airless bodies in the solar system are exposed to the continual bombardment by interplanetary meteoroids. These impacts can eject orders of magnitude more mass than the primary impactors, sustaining bound and/or unbound ejecta clouds that vary both spatially and temporally from changes in impactor fluxes. The dust environment in the vicinity of an airless body provides both a scientific resource and a hazard for exploration. Characterizing the spatial and temporal variability of the dust environment of airless planetary bodies provides a novel way to understand their meteoroid environment by effectively using these objects as large surface area meteoroid detectors. Additionally, were a dust detector with chemical sensing capability to be flown near such a body, it would be able to directly measure the composition of the body without requiring the mission design complexity involved in landing and sampling surface material. Paramount to understanding the current and future impact ejecta measurements is a sufficient understanding of the impact ejecta processes at the surface. In this presentation, we focus on data taken by the Lunar Dust Experiment (LDEX), an impact ionization dust detector onboard the Lunar Atmosphere and Dust Environment Explorer (LADEE) mission, designed to measure impact ejecta around the Moon. We use the Geminids meteoroid shower as a well constrained input function, and via comparison to existing ground-based measurements of this shower, to "calibrate" the response of the lunar surface to meteoroid bombardment. Understanding the response of the lunar surface to meteoroid bombardment can by extension allow us to better understand the ejecta response at other regolith airless bodies in the solar system. Future missions equipped with dust detectors sent to the Moon, large Near Earth Asteroids, the Martian moons Phobos and Deimos, or many other airless bodies in the solar system would greatly improve our knowledge of their local meteoroid

  12. Using GRIDVIEW to Better Understand the Early Bombardment History of the Moon, Mars and Earth

    NASA Technical Reports Server (NTRS)

    Frey, Herbert

    2012-01-01

    For more than a decade we have used GRIDVIEW to help analyze topographic and related data for Mars and more recently for the Moon. Our focus has been to employ the stretching, contouring, profiling, circle-fitting and other capabilities of GRIDVIEW to search for Quasi-Circular Depressions (CTAs) in MOLA, LOLA and other topographic data, and for Circular Thin Areas (CTAs) in Mars and Moon model crustal thickness data. Both QCDs and CTAs likely represent buried or obscured impact craters not readily visible in image data. We found clear evidence for a much larger population of buried impact craters in the northern lowlands of Mars (Frey et al. 2002), suggesting that part of the Red Planet is not significantly younger than the southern highlands. Edgar and Frey (2008) found that the N(300) crater retention ages of both areas were essentially identical, a conclusion confirmed by Wyatt (unpublished data) using more recent crustal thickness data for Mars. MOLA topographic data and MOLA-derived crustal thickness data were used to both identify a large number of previously unrecognized very large impact basins (D> 1000 km) on Mars and to determine relative crater retention ages for them (Frey, 2008). The distribution of N(300) CRAs suggested most formed in a relatively short interval of time. This dating also suggested the main magnetic field of Mars disappeared during this period (Lillis et al., 2008), because only the youngest basins systematically lack a remagnetized signature. Similar QCD and CTA analysis of first Clementine (Frey, 2011) and more recently LOLA topographic and LOLA-derived crustal thickness data for the Moon (Frey et al., 2011) revealed a significantly larger population of impact basins > 300 km in diameter than previously known. N(50) CRAs suggest a two-peak distribution of ages (Frey, 2012). An improved counting process confirms the two peaks, perhaps indicating both a pre-Nectaris Early Heavy Bombardment (EHB) as well as a Late Heavy Bombardment (LHB

  13. Evaluation of large format electron bombarded virtual phase CCDs as ultraviolet imaging detectors

    NASA Technical Reports Server (NTRS)

    Opal, Chet B.; Carruthers, George R.

    1989-01-01

    In conjunction with an external UV-sensitive cathode, an electron-bombarded CCD may be used as a high quantum efficiency/wide dynamic range photon-counting UV detector. Results are presented for the case of a 1024 x 1024, 18-micron square pixel virtual phase CCD used with an electromagnetically focused f/2 Schmidt camera, which yields excellent simgle-photoevent discrimination and counting efficiency. Attention is given to the vacuum-chamber arrangement used to conduct system tests and the CCD electronics and data-acquisition systems employed.

  14. Three cobalt(II)-linked {P8W48} network assemblies: syntheses, structures, and magnetic and photocatalysis properties.

    PubMed

    Jiao, Yan-Qing; Qin, Chao; Wang, Xin-Long; Wang, Chun-Gang; Sun, Chun-Yi; Wang, Hai-Ning; Shao, Kui-Zhan; Su, Zhong-Min

    2014-02-01

    Three cobalt(II)-containing tungstophosphate compounds, Na8Li8Co5[Co5.5(H2O)19P8W48.5O184]⋅60 H2O (1), K2Na4Li11Co5[Co7(H2O)28P8W48O184]Cl⋅ 59 H2O (2), and K2Na4LiCo11[Co8(H2O)32P8W48O184](CH3COO)4Cl⋅47 H2O (3), have been synthesized and characterized by IR spectroscopy, thermogravimetric analysis, elemental analyses, and magnetic measurements. The pH value impacts the formation of distinct cobalt-linked frameworks. The cyclic cavity of the polyanion accommodates 5.5, 7, and 8 cobalt ions in 1, 2, and 3, respectively. In compounds 1 and 2, each {Co5.5P8W48} and {Co7P8W48} fragment links to four others through multiple {Co-O-W} coordination bonds to generate a two-dimensional network. Compound 3 can be considered as a 3D network based on the {Co-O-W} coordination bonds and the {Co3(CH3COO)2(H2O)10} linkers between the {P8W48} fragments. Interestingly, acetate ligands have been employed to form the {Co3(CH3COO)2(H2O)10} unit, thereby inducing the construction of a 12-connected framework. To the best of our knowledge, compound 3 contains the largest-ever number of cobalt ions in a {P8W48}-based polyoxometalate when counterions are taken into account and the {P8W48} unit shows the highest number of connections thanks to the carboxyl bridges. The UV/Vis diffuse reflectance spectra of these powder samples indicate that the corresponding well-defined optical absorption associated with Eg can be assessed at 2.58, 2.48, and 2.73 eV and reveal the presence of an optical band gap. The photocatalytic H2 evolution activities of these {P8W48}-based compounds are evaluated. Copyright © 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  15. Fabrication and characterization of carbon-backed thin 208Pb targets.

    PubMed

    Thakur, Meenu; Dubey, R; Abhilash, S R; Behera, B R; Mohanty, B P; Kabiraj, D; Ojha, Sunil; Duggal, Heena

    2016-01-01

    Thin carbon-backed isotopically enriched 208 Pb targets were required for our experiment aimed to study the reaction dynamics for 48 Ti +  208 Pb system, populating the near super-heavy nucleus 256 Rf, through mass-energy correlation of the fission fragments. Purity and thickness of the targets are of utmost importance in such studies as these factors have strong influence on the measurement accuracy of mass and energy distribution of fission fragments. 208 Pb targets with thickness ranging from 60 μg/cm 2 to 250 μg/cm 2 have been fabricated in high vacuum environment using physical vapor deposition method. Important points in the method are as follows: • 208 Pb was deposited using resistive heating method, whereas carbon (backing foil) deposition was performed by using the electron beam bombardment technique.•Different characterization techniques such as Particle Induced X-ray Emission (PIXE), Energy Dispersive X-Ray Fluorescence (EDXRF) and Rutherford Backscattering Spectrometry (RBS) were used to assert the purity and thickness of the targets.•These targets have successfully been used to accomplish our experimental objectives.

  16. Finding the Best-Fit Polynomial Approximation in Evaluating Drill Data: the Application of a Generalized Inverse Matrix / Poszukiwanie Najlepszej ZGODNOŚCI W PRZYBLIŻENIU Wielomianowym Wykorzystanej do Oceny Danych Z ODWIERTÓW - Zastosowanie UOGÓLNIONEJ Macierzy Odwrotnej

    NASA Astrophysics Data System (ADS)

    Karakus, Dogan

    2013-12-01

    In mining, various estimation models are used to accurately assess the size and the grade distribution of an ore body. The estimation of the positional properties of unknown regions using random samples with known positional properties was first performed using polynomial approximations. Although the emergence of computer technologies and statistical evaluation of random variables after the 1950s rendered the polynomial approximations less important, theoretically the best surface passing through the random variables can be expressed as a polynomial approximation. In geoscience studies, in which the number of random variables is high, reliable solutions can be obtained only with high-order polynomials. Finding the coefficients of these types of high-order polynomials can be computationally intensive. In this study, the solution coefficients of high-order polynomials were calculated using a generalized inverse matrix method. A computer algorithm was developed to calculate the polynomial degree giving the best regression between the values obtained for solutions of different polynomial degrees and random observational data with known values, and this solution was tested with data derived from a practical application. In this application, the calorie values for data from 83 drilling points in a coal site located in southwestern Turkey were used, and the results are discussed in the context of this study. W górnictwie wykorzystuje się rozmaite modele estymacji do dokładnego określenia wielkości i rozkładu zawartości pierwiastka użytecznego w rudzie. Estymację położenia i właściwości skał w nieznanych obszarach z wykorzystaniem próbek losowych o znanym położeniu przeprowadzano na początku z wykorzystaniem przybliżenia wielomianowego. Pomimo tego, że rozwój technik komputerowych i statystycznych metod ewaluacji próbek losowych sprawiły, że po roku 1950 metody przybliżenia wielomianowego straciły na znaczeniu, nadal teoretyczna powierzchnia

  17. Compositional Evolution of Saturn's Rings Due to Meteoroid Bombardment

    NASA Technical Reports Server (NTRS)

    Cuzzi, J.; Estrada, P.; Young, Richard E. (Technical Monitor)

    1997-01-01

    In this paper we address the question of compositional evolution in planetary ring systems subsequent to meteoroid bombardment. The huge surface area to mass ratio of planetary rings ensures that this is an important process, even with current uncertainties on the meteoroid flux. We develop a new model which includes both direct deposition of extrinsic meteoritic "pollutants", and ballistic transport of the increasingly polluted ring material as impact ejecta. Our study includes detailed radiative transfer modeling of ring particle spectral reflectivities based on refractive indices of realistic constituents. Voyager data have shown that the lower optical depth regions in Saturn's rings (the C ring and Cassini Division) have darker and less red particles than the optically thicken A and B rings. These coupled structural-compositional groupings have never been explained; we present and explore the hypothesis that global scale color and compositional differences in the main rings of Saturn arise naturally from extrinsic meteoroid bombardment of a ring system which was initially composed primarily, but not entirely, of water ice. We find that the regional color and albedo differences can be understood if all ring material was initially identical (primarily water ice, based on other data, but colored by tiny amounts of intrinsic reddish, plausibly organic, absorber) and then evolved entirely by addition and mixing of extrinsic, nearly neutrally colored. plausibly carbonaceous material. We further demonstrate that the detailed radial profile of color across the abrupt B ring - C ring boundary can.constrain key unknown parameters in the model. Using new alternates of parameter values, we estimate the duration of the exposure to extrinsic meteoroid flux of this part of the rings, at least, to be on the order of 10(exp 8) years. This conclusion is easily extended by inference to the Cassini Division and its surroundings as well. This geologically young "age" is compatible

  18. Formation of the 50-Year Element 94 from Deuteron Bombardment of U{sup 238}

    DOE R&D Accomplishments Database

    Kennedy, J. W.; Perlman, M. L.; Segre, E.; Wahl, A. C.

    1942-06-01

    It has been shown by bombardment with deuterons of a sample of U{sup 238}, greatly depleted in U{sup 235} and U{sup 234}, that the 50-year 94 activity and 2.0 day 93 activity are formed in approximately the same yield as with the natural mixture of uranium isotopes. The activities are thus shown to arise from the U{sup 238} nucleus, and from considerations of the energy of the compound nucleus (U{sup 238} + d).

  19. Uranium carbide fission target R&D for RIA - an update

    NASA Astrophysics Data System (ADS)

    Greene, J. P.; Levand, A.; Nolen, J.; Burtseva, T.

    2004-12-01

    For the Rare Isotope Accelerator (RIA) facility, ISOL targets employing refractory compounds of uranium are being developed to produce radioactive ions for post-acceleration. The availability of refractory uranium compounds in forms that have good thermal conductivity, relatively high density, and adequate release properties for short-lived isotopes remains an important issue. Investigations using commercially obtained uranium carbide material and prepared into targets involving various binder materials have been carried out at ANL. Thin sample pellets have been produced for measurements of thermal conductivity using a new method based on electron bombardment with the thermal radiation observed using a two-color optical pyrometer and performed on samples as a function of grain size, pressing pressure and sintering temperature. Manufacture of uranium carbide powder has now been achieved at ANL. Simulations have been carried out on the thermal behavior of the secondary target assembly incorporating various heat shield configurations.

  20. Targeted Nanoparticles for Kidney Cancer Therapy

    DTIC Science & Technology

    2013-10-01

    AD_________________ Award Number: W81XWH-10-1-0434 TITLE: Targeted Nanoparticles for Kidney Cancer Therapy PRINCIPAL...Targeted Nanoparticles for Kidney Cancer Therapy 5b. GRANT NUMBER W81XWH-10-1-0434 5c. PROGRAM ELEMENT NUMBER 6. AUTHOR(S) 5d. PROJECT...lines following treatment with D5 nanotubes. Tthermoablation will be studied initially. Human kidney cancer cells will be injected into the kidney

  1. 100W high-brightness multi-emitter laser pump

    NASA Astrophysics Data System (ADS)

    Duesterberg, Richard; Xu, Lei; Skidmore, Jay A.; Guo, James; Cheng, Jane; Du, Jihua; Johnson, Brad; Vecht, David L.; Guerin, Nicolas; Huang, Benlih; Yin, Dongliang; Cheng, Peter; Raju, Reddy; Lee, Kong Weng; Cai, Jason; Rossin, Victor; Zucker, Erik P.

    2011-03-01

    We report results of a spatially-multiplexed broad area laser diode platform designed for efficient pumping of fiber lasers or direct-diode systems. Optical output power in excess of 100W from a 105μm core, 0.15NA fiber is demonstrated with high coupling efficiency. The compact form factor and low thermal resistance enable tight packing densities needed for kW-class fiber laser systems. Broad area laser diodes have been optimized to reduce near- and far-field performance and prevent blooming without sacrificing other electro-optic parameters. With proper lens optimization this produces ~5% increase in coupling / wall plug efficiency for our design. In addition to performance characteristics, an update on long term reliability testing of 9XX nm broad area laser diode is provided that continues to show no wear out under high acceleration. Under nominal operating conditions of 12W ex-facet power at 25C, the diode mean time to failure (MTTF) is forecast to be ~ 480 kh.

  2. Ada Compiler Validation Summary Report: Harris Corporation, Harris Ada Compiler, Version 4.0, Harris HCX-9 (Host) and (Target), 880603W1.09059

    DTIC Science & Technology

    1988-06-06

    TYPE Of REPORT & PERIOD COVERED Ada Compiler Validation Summary Report : Harris 6 June 1988 to 6 June 1988 Corporation, Harris Ada Compiler, Version...4.0, Harris 1 PERFORINGDRG REPORT NUMBER HCX-9 (Host) and (Target), 880603W1.09059 7. AUTHOR(s) S. CONTRACT OR 6RANT NUMBER(s) Wright-Patterson AFB...88-03-02-HAR Ada COMPILER VALIDATION SUMMARY REPORT : Certificate Number: 880603WI.09059 A Harris Corporation AccessionFor Harris Ada Compiler, Version

  3. The Modernization of the Energy Sector in Poland vs. Poland's Energy Security / Modernizacja sektora energii w polsce a bezpieczeństwo energetyczne Polski

    NASA Astrophysics Data System (ADS)

    Frączek, Paweł; Kaliski, Maciej; Siemek, Paweł

    2013-06-01

    The paper discusses the essence of Poland's energy security, decisive factors for its attainment and the structure of primary energy sources of the country. It describes the main problem areas in functioning of the energy sector in Poland, as well as the conditions for its modernization. The issues of increasing the natural gas share in the country's structure of primary energy sources and a construction of the first nuclear power plant in Poland have been particularly emphasised. The paper stresses that without modernizing actions it will be impossible for Poland to fulfil international obligations concerning changes in the functioning of the energy sector. The study, analysing the conditions for increasing the role of natural gas in Poland, points at the necessity to expand the gas infrastructure, to increase a scale of gas production from domestic deposits and to complete liberalization of the energy industry. It also emphasises that a potential delay in the construction of the country's first nuclear power plant may limit competitiveness of the economy. W artykule omówiono istotę bezpieczeństwa energetycznego Polski, czynniki decydujące o jego osiągnięciu oraz strukturę źródeł energii pierwotnej w kraju. Przedstawiono główne problemy funkcjonowania sektora energii w Polsce oraz uwarunkowania jego modernizacji. Szczególny nacisk położono na kwestie zwiększenia udziału gazu ziemnego w krajowej strukturze źródeł energii pierwotnej oraz budowy pierwszej elektrownii atomowej w Polsce. Podkreślono, że bez podjęcia działań modernizacyjnych niemożliwe będzie wypełnienie zobowiązań międzynarodowych Polski dotyczących zmian w sposobie funkcjonowania sektora energii. Analizując uwarunkowania zwiększenia znaczenia gazu ziemnego w Polsce, wskazano na konieczność rozbudowy infrastruktury gazowniczej, zwiększenia skali wydobycia gazu ziemnego z krajowych złóż oraz na kwestię dokończenia liberalizacji branży. Podkreślono, że dla zwi

  4. Ion induced electron emission statistics under Agm- cluster bombardment of Ag

    NASA Astrophysics Data System (ADS)

    Breuers, A.; Penning, R.; Wucher, A.

    2018-05-01

    The electron emission from a polycrystalline silver surface under bombardment with Agm- cluster ions (m = 1, 2, 3) is investigated in terms of ion induced kinetic excitation. The electron yield γ is determined directly by a current measurement method on the one hand and implicitly by the analysis of the electron emission statistics on the other hand. Successful measurements of the electron emission spectra ensure a deeper understanding of the ion induced kinetic electron emission process, with particular emphasis on the effect of the projectile cluster size to the yield as well as to emission statistics. The results allow a quantitative comparison to computer simulations performed for silver atoms and clusters impinging onto a silver surface.

  5. Examples of Solutions for Steel-Concrete Composite Structures in Bridge Engineering / Przykłady Konstrukcji Zespolonych W Budownictwie Mostowym

    NASA Astrophysics Data System (ADS)

    Flaga, Kazimierz; Furtak, Kazimierz

    2015-03-01

    The aim of the article [1] was to discuss the application of steel-concrete composite structures in bridge engineering in the aspect of structural design, analysis and execution. It was pointed out that the concept of steel-concrete structural composition is far from exhausted and new solutions interesting from the engineering, scientific and aesthetic points of view of are constantly emerging. These latest trends are presented against the background of the solutions executed in Poland and abroad. Particular attention is focused on structures of double composition and steel-concrete structures. Concrete filled steel tubular (CFST) structures are highlighted. W artykule [1] omówiono problemy konstrukcyjne, obliczeniowe i realizacyjne, związane z zastosowaniem konstrukcji zespolonych stal-beton w mostownictwie. Wskazano tam, że idea konstrukcyjnego zespolenia stali z betonem jest jeszcze daleka do wyczerpania i że wciąż pojawiają się nowe rozwiązania interesujące z inżynierskiego, naukowego i estetycznego punktu widzenia. W artykule niniejszym pokazano te nowoczesne trendy na tle rozwiązań zrealizowanych w Polsce i na świecie. Szczególną uwagę poświęcono konstrukcjom podwójnie zespolonym oraz konstrukcjom stalowobetonowym. Wyeksponowano tu szczególnie konstrukcje z rur stalowych wypełnionych betonem, typu CFST. Dają one nadzieję na ich szersze zastosowanie w warunkach polskich.

  6. Preparation of clean surfaces and Se vacancy formation in Bi2Se3 by ion bombardment and annealing

    NASA Astrophysics Data System (ADS)

    Zhou, Weimin; Zhu, Haoshan; Valles, Connie M.; Yarmoff, Jory A.

    2017-08-01

    Bismuth Selenide (Bi2Se3) is a topological insulator (TI) with a structure consisting of stacked quintuple layers. Single crystal surfaces are commonly prepared by mechanical cleaving. This work explores the use of low energy Ar+ ion bombardment and annealing (IBA) as an alternative method to produce reproducible and stable Bi2Se3 surfaces under ultra-high vacuum (UHV). It is found that a clean and well-ordered surface can be prepared by a single cycle of 1 keV Ar+ ion bombardment and 30 min of annealing. Low energy electron diffraction (LEED) and detailed low energy ion scattering (LEIS) measurements show no differences between IBA-prepared surfaces and those prepared by in situ cleaving in UHV. Analysis of the LEED patterns shows that the optimal annealing temperature is 450 °C. Angular LEIS scans reveal the formation of surface Se vacancies when the annealing temperature exceeds 520 °C.

  7. Effect of Bombardment with Oxygen Ions on the Surface Composition of Polycrystalline Silver

    NASA Astrophysics Data System (ADS)

    Ashkhotov, O. G.; Khubezhov, S. A.; Aleroev, M. A.; Magkoev, T. T.; Grigorkina, G. S.

    2018-07-01

    Surface layers of polycrystalline silver bombarded with oxygen ions having energies from 100 to 300 eV are studied via Auger electron and X-ray photoelectron spectroscopies. Atomic and molecular oxygen together with silver in the zero-valence state are found in AgO and Ag2O after such treatment in silver surface layers. In addition, there is positive displacement of the Ag 3 d 3/2 peak by 0.5 eV, indicating an increase in spin-orbit splitting for Ag 3 d 5/2-Ag 3 d 3/2.

  8. Development of multiple W/O/W emulsions as dermal carrier system for oligonucleotides: effect of additives on emulsion stability.

    PubMed

    Schmidts, T; Dobler, D; Schlupp, P; Nissing, C; Garn, H; Runkel, F

    2010-10-15

    Multiple water-in-oil-in-water (W/O/W) emulsions are of major interest as potential skin delivery systems for water-soluble drugs like oligonucleotides due to their distinct encapsulation properties. However, multiple emulsions are highly sensitive in terms of variations of the individual components. The presence of osmotic active ingredients in the inner water phase is crucial for the generation of stable multiple emulsions. In order to stabilize the emulsions the influence of NaCl, MgSO(4), glucose and glycine and two cellulose derivatives was investigated. Briefly, multiple W/O/W emulsions using Span 80 as a lipophilic emulsifier and different hydrophilic emulsifiers (PEG-40/50 stearate, steareth-20 and polysorbate 80) were prepared. Stability of the emulsions was analyzed over a period of time using rheological measurements, droplet size observations and conductivity analysis. In this study we show that additives strongly influence the properties stability of multiple emulsions. By increasing the concentration of the osmotic active ingredients, smaller multiple droplets are formed and the viscosity is significantly increased. The thickening agents resulted in a slightly improved stability. The most promising emulsions were chosen and further evaluated for their suitability and compatibility to incorporate a DNAzyme oligonucleotide as active pharmaceutical ingredient. Copyright 2010 Elsevier B.V. All rights reserved.

  9. Pulse Current Electrodeposition and Anticorrosion Performance of Ni-W-Mica Composite Coatings

    NASA Astrophysics Data System (ADS)

    Yang, Qiangbin; He, Yi; Fan, Yi; Li, Han; Xu, Wei; Zhan, Yingqing

    2017-03-01

    Ni-W-mica composite coatings were prepared on C45 steel via pulse electrodeposition from a Watts bath containing mica. The mica particles were co-deposited into the Ni-W coating matrix, and the structures, morphologies and mechanical performances of the coatings were investigated. Scanning electron microscopy and energy dispersive x-ray spectroscopy revealed that a small amount of mica caused the Ni-W-mica coating to form of a compact and uniform surface structure. The electrochemical behaviors of the coatings were evaluated by potentiodynamic polarization measurements and electrochemical impedance spectroscopy in 3.5 wt.% NaCl solutions at pH 7 and under typical engineering application environments. The results revealed that the addition of mica to the Ni-W coating could improve the corrosion resistance of the coating.

  10. Fabrication of low thermal expansion SiC/ZrW2O8 porous ceramics

    NASA Astrophysics Data System (ADS)

    Poowancum, A.; Matsumaru, K.; Juárez-Ramírez, I.; Torres-Martínez, L. M.; Fu, Z. Y.; Lee, S. W.; Ishizaki, K.

    2011-03-01

    Low or zero thermal expansion porous ceramics are required for several applications. In this work near zero thermal expansion porous ceramics were fabricated by using SiC and ZrW2O8 as positive and negative thermal expansion materials, respectively, bonded by soda lime glass. The mixture of SiC, ZrW2O8 and soda lime glass was sintered by Pulsed Electric Current Sintering (PECS, or sometimes called Spark Plasma Sintering, SPS) at 700 °C. Sintered samples with ZrW2O8 particle size smaller than 25 μm have high thermal expansion coefficient, because ZrW2O8 has the reaction with soda lime glass to form Na2ZrW3O12 during sintering process. The reaction between soda lime glass and ZrW2O8 is reduced by increasing particle size of ZrW2O8. Sintered sample with ZrW2O8 particle size 45-90 μm shows near zero thermal expansion.

  11. NPF MECHANICAL CELL NaK DISPOSAL AND FUME ABATEMENT

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Rey, G.

    Some of the fuels originally scheduled for processing in the nonproduction fuel (NPF) processing program incorporated sodium or sodium- potassium alloy (NaK) as the bonding material between stainless-steel cladding and the uranium or uranium-molybdenum alloy core. Because of the special hazards involved in handling NaK, studies were made to determine safe methods for processing NaK-containing fuels. An underwater NaK dispensing system was installed, and tests were made to determine the characteristics of the NaK-water reaction. The equipment consisted of a dispenser, reaction pan, and off-gas scrubber. After initinl studies, a prototype test was made wherein U-Mo canned slugs containing NaKmore » reservoirs were hack sawed underwater. The studies demonstrated that the NaK reservoirs can be safely deactivated by hack sawing under a submerged hood in a shallow water bath. (W.L.H.)« less

  12. Large-scale studies of ion acceleration in laser-generated plasma at intensities from 1010 W/cm2 to 1019 W/cm2

    NASA Astrophysics Data System (ADS)

    Torrisi, L.

    2018-02-01

    A large-scale study of ion acceleration in laser-generated plasma, extended to intensities from 1010 W/cm2 up to 1019 W/cm2, is presented. Aluminium thick and thin foils were irradiated in high vacuum using different infrared lasers and pulse durations from ns up to fs scale. Plasma was monitored mainly using SiC detectors employed in time-of-flight configuration. Protons and aluminium ions, at different energies and yields, were measured as a function of the laser intensity. The discontinuity region between particle acceleration from both the backward plasma (BPA) in thick targets and the forward plasma in thin foils in the target normal sheath acceleration (TNSA) regimes were investigated.

  13. Measurements and parameterization of neutron energy spectra from targets bombarded with 120 GeV protons

    NASA Astrophysics Data System (ADS)

    Kajimoto, T.; Shigyo, N.; Sanami, T.; Iwamoto, Y.; Hagiwara, M.; Lee, H. S.; Soha, A.; Ramberg, E.; Coleman, R.; Jensen, D.; Leveling, A.; Mokhov, N. V.; Boehnlein, D.; Vaziri, K.; Sakamoto, Y.; Ishibashi, K.; Nakashima, H.

    2014-10-01

    The energy spectra of neutrons were measured by a time-of-flight method for 120 GeV protons on thick graphite, aluminum, copper, and tungsten targets with an NE213 scintillator at the Fermilab Test Beam Facility. Neutron energy spectra were obtained between 25 and 3000 MeV at emission angles of 30°, 45°, 120°, and 150°. The spectra were parameterized as neutron emissions from three moving sources and then compared with theoretical spectra calculated by PHITS and FLUKA codes. The yields of the theoretical spectra were substantially underestimated compared with the yields of measured spectra. The integrated neutron yields from 25 to 3000 MeV calculated with PHITS code were 16-36% of the experimental yields and those calculated with FLUKA code were 26-57% of the experimental yields for all targets and emission angles.

  14. Molecular Targets for Antiepileptic Drug Development

    PubMed Central

    Meldrum, Brian S.; Rogawski, Michael A.

    2007-01-01

    Summary This review considers how recent advances in the physiology of ion channels and other potential molecular targets, in conjunction with new information on the genetics of idiopathic epilepsies, can be applied to the search for improved antiepileptic drugs (AEDs). Marketed AEDs predominantly target voltage-gated cation channels (the α subunits of voltage-gated Na+ channels and also T-type voltage-gated Ca2+ channels) or influence GABA-mediated inhibition. Recently, α2–δ voltage-gated Ca2+ channel subunits and the SV2A synaptic vesicle protein have been recognized as likely targets. Genetic studies of familial idiopathic epilepsies have identified numerous genes associated with diverse epilepsy syndromes, including genes encoding Na+ channels and GABAA receptors, which are known AED targets. A strategy based on genes associated with epilepsy in animal models and humans suggests other potential AED targets, including various voltage-gated Ca2+ channel subunits and auxiliary proteins, A- or M-type voltage-gated K+ channels, and ionotropic glutamate receptors. Recent progress in ion channel research brought about by molecular cloning of the channel subunit proteins and studies in epilepsy models suggest additional targets, including G-protein-coupled receptors, such as GABAB and metabotropic glutamate receptors; hyperpolarization-activated cyclic nucleotide-gated cation (HCN) channel subunits, responsible for hyperpolarization-activated current Ih; connexins, which make up gap junctions; and neurotransmitter transporters, particularly plasma membrane and vesicular transporters for GABA and glutamate. New information from the structural characterization of ion channels, along with better understanding of ion channel function, may allow for more selective targeting. For example, Na+ channels underlying persistent Na+ currents or GABAA receptor isoforms responsible for tonic (extrasynaptic) currents represent attractive targets. The growing understanding of the

  15. High-NA optical CD metrology on small in-cell targets enabling improved higher order dose control and process control for logic

    NASA Astrophysics Data System (ADS)

    Cramer, Hugo; Mc Namara, Elliott; van Laarhoven, Rik; Jaganatharaja, Ram; de la Fuente, Isabel; Hsu, Sharon; Belletti, Filippo; Popadic, Milos; Tu, Ward; Huang, Wade

    2017-03-01

    The logic manufacturing process requires small in-device metrology targets to exploit the full dose correction potential of the modern scanners and process tools. A high-NA angular resolved scatterometer (YieldStar S-1250D) was modified to demonstrate the possibility of OCD measurements on 5x5µm2 targets. The results obtained on test wafers in a logic manufacturing environment, measured after litho and after core etch, showed a good correlation to larger reference targets and AEI to ADI intra-field CDU correlation, thereby demonstrating the feasibility of OCD on such small targets. The data was used to determine a reduction potential of 55% for the intra-field CD variation, using 145 points per field on a few inner fields, and 33% of the process induced across wafer CD variation using 16 points per field full wafer. In addition, the OCD measurements reveal valuable information on wafer-to-wafer layer height variations within a lot.

  16. Effective defect diffusion lengths in Ar-ion bombarded 3C-SiC

    DOE PAGES

    Bayu Aji, L. B.; Wallace, J. B.; Shao, L.; ...

    2016-04-14

    Above room temperature, SiC exhibits pronounced processes of diffusion and interaction of radiation-generated point defects. Here, we use the recently developed pulsed ion beam method to measure effective defect diffusion lengths in 3C-SiC bombarded in the temperature range of 25–200 °C with 500 keV Ar ions. Results reveal a diffusion length of ~10 nm, which exhibits a weak temperature dependence, changing from 9 to 13 nm with increasing temperature. Lastly, these results have important implications for understanding and predicting radiation damage in SiC and for the development of radiation-resistant materials via interface-mediated defect reactions.

  17. Effective defect diffusion lengths in Ar-ion bombarded 3C-SiC

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Bayu Aji, L. B.; Wallace, J. B.; Shao, L.

    Above room temperature, SiC exhibits pronounced processes of diffusion and interaction of radiation-generated point defects. Here, we use the recently developed pulsed ion beam method to measure effective defect diffusion lengths in 3C-SiC bombarded in the temperature range of 25–200 °C with 500 keV Ar ions. Results reveal a diffusion length of ~10 nm, which exhibits a weak temperature dependence, changing from 9 to 13 nm with increasing temperature. Lastly, these results have important implications for understanding and predicting radiation damage in SiC and for the development of radiation-resistant materials via interface-mediated defect reactions.

  18. BCL-W has a fundamental role in B cell survival and lymphomagenesis.

    PubMed

    Adams, Clare M; Kim, Annette S; Mitra, Ramkrishna; Choi, John K; Gong, Jerald Z; Eischen, Christine M

    2017-02-01

    Compromised apoptotic signaling is a prerequisite for tumorigenesis. The design of effective therapies for cancer treatment depends on a comprehensive understanding of the mechanisms that govern cell survival. The antiapoptotic proteins of the BCL-2 family are key regulators of cell survival and are frequently overexpressed in malignancies, leading to increased cancer cell survival. Unlike BCL-2 and BCL-XL, the closest antiapoptotic relative BCL-W is required for spermatogenesis, but was considered dispensable for all other cell types. Here, however, we have exposed a critical role for BCL-W in B cell survival and lymphomagenesis. Loss of Bcl-w conferred sensitivity to growth factor deprivation-induced B cell apoptosis. Moreover, Bcl-w loss profoundly delayed MYC-mediated B cell lymphoma development due to increased MYC-induced B cell apoptosis. We also determined that MYC regulates BCL-W expression through its transcriptional regulation of specific miR. BCL-W expression was highly selected for in patient samples of Burkitt lymphoma (BL), with 88.5% expressing BCL-W. BCL-W knockdown in BL cell lines induced apoptosis, and its overexpression conferred resistance to BCL-2 family-targeting BH3 mimetics. Additionally, BCL-W was overexpressed in diffuse large B cell lymphoma and correlated with decreased patient survival. Collectively, our results reveal that BCL-W profoundly contributes to B cell lymphoma, and its expression could serve as a biomarker for diagnosis and aid in the development of better targeted therapies.

  19. BCL-W has a fundamental role in B cell survival and lymphomagenesis

    PubMed Central

    Adams, Clare M.; Kim, Annette S.; Mitra, Ramkrishna; Choi, John K.; Gong, Jerald Z.; Eischen, Christine M.

    2017-01-01

    Compromised apoptotic signaling is a prerequisite for tumorigenesis. The design of effective therapies for cancer treatment depends on a comprehensive understanding of the mechanisms that govern cell survival. The antiapoptotic proteins of the BCL-2 family are key regulators of cell survival and are frequently overexpressed in malignancies, leading to increased cancer cell survival. Unlike BCL-2 and BCL-XL, the closest antiapoptotic relative BCL-W is required for spermatogenesis, but was considered dispensable for all other cell types. Here, however, we have exposed a critical role for BCL-W in B cell survival and lymphomagenesis. Loss of Bcl-w conferred sensitivity to growth factor deprivation–induced B cell apoptosis. Moreover, Bcl-w loss profoundly delayed MYC-mediated B cell lymphoma development due to increased MYC-induced B cell apoptosis. We also determined that MYC regulates BCL-W expression through its transcriptional regulation of specific miR. BCL-W expression was highly selected for in patient samples of Burkitt lymphoma (BL), with 88.5% expressing BCL-W. BCL-W knockdown in BL cell lines induced apoptosis, and its overexpression conferred resistance to BCL-2 family–targeting BH3 mimetics. Additionally, BCL-W was overexpressed in diffuse large B cell lymphoma and correlated with decreased patient survival. Collectively, our results reveal that BCL-W profoundly contributes to B cell lymphoma, and its expression could serve as a biomarker for diagnosis and aid in the development of better targeted therapies. PMID:28094768

  20. Renovation and Modernization of Residential Structures in Gliwice Based on Survey of the Environment Built from the Years 1848-2014 / Renowacja I Modernizacja Struktury Mieszkaniowej W Gliwicach Na Podstawie Badań Ankietowych Środowiska Zbudowanego Z Lat 1848-2014

    NASA Astrophysics Data System (ADS)

    Cibis, Jerzy; Serdyńska, Joanna

    2015-03-01

    The subject of the survey carried out in 2013-2014 are changes in Gliwice residential substance in relation to the two fundamental issues:how proceeded transformation of the existing housing stock, which changes has it undergone during operation. The range of changes within the housing illustrates all the positive and negative solutions characteristic for each of the periods. In the selection of research technique decision was made to form the survey. The quantitative data collected during the survey are the basis for building applications and also from grouped and developed characteristics for the surveyed collections. The test results help to identify regularities concerning the scope of the changes made in each period and - indirectly - give evidence to evaluate the built environment in terms of meeting the expectations and needs of the residents. Analysis of the assumptions also draws attention to the life cycles of the apartment, as the original part undergoing transformation during the adaptation, modernization and reconstruction of housing environment to changing needs during operational requirements. The scope of the changes introduced by them within the housing allows to evaluate the accuracy of functional and spatial, technical and technological solutions characteristic of the period in which they developed. Przedmiotem badania przeprowadzonego w latach 2013-2014 są zmiany zachodzące w substancji mieszkaniowej Gliwic w odniesieniu do dwu zasadniczych kwestii: jak przebiegała transformacja istniejących zasobów mieszkaniowych, jakim zmianom została ona poddana w czasie eksploatacji. Zakres zmian w obrębie mieszkania ilustruje wszelkie pozytywne i negatywne rozwiązania charakterystyczne dla każdego z badanych okresów. W doborze techniki badawczej zdecydowano się na formę badania ankietowego. Dane ilościowe zebrane podczas badań ankietowych są podstawą do budowania wniosków i tez z pogrupowanych i opracowanych cech charakterystycznych dla

  1. Ranolazine vs phenytoin: greater effect of ranolazine on the transient Na(+) current than on the persistent Na(+) current in central neurons.

    PubMed

    Terragni, Benedetta; Scalmani, Paolo; Colombo, Elisa; Franceschetti, Silvana; Mantegazza, Massimo

    2016-11-01

    Voltage-gated Na(+) channels (NaV) are involved in pathologies and are important targets of drugs (NaV-blockers), e.g. some anti-epileptic drugs (AEDs). Besides the fast inactivating transient Na(+) current (INaT), they generate a slowly inactivating "persistent" current (INaP). Ranolazine, a NaV-blocker approved for treatment of angina pectoris, is considered a preferential inhibitor of INaP and has been proposed as a novel AED. Although it is thought that classic NaV-blockers used as AEDs target mainly INaT, they can also reduce INaP. It is important to disclose specific features of novel NaV-blockers, which could be necessary for their effect as AEDs in drug resistant patients. We have compared the action of ranolazine and of the classic AED phenytoin in transfected cells expressing the neuronal NaV1.1 Na(+) channel and in neurons of neocortical slices. Our results show that the relative block of INaT versus INaP of ranolazine and phenytoin is variable and depends on Na(+) current activation conditions. Strikingly, ranolazine blocks with less efficacy INaP and more efficacy INaT than phenytoin in conditions mimicking pathological states (i.e. high frequency firing and long lasting depolarizations). The effects are consistent with binding of ranolazine to both open/pre-open and inactivated states; larger INaT block at high stimulation frequencies is caused by the induction of a slow inactivated state. Thus, contrary than expected, ranolazine is not a better INaP blocker than phenytoin in central neurons, and phenytoin is not a better INaT blocker than ranolazine. Nevertheless, they show a complementary action and could differentially target specific pathological dysfunctions. Copyright © 2016 Elsevier Ltd. All rights reserved.

  2. Targeting ESR1-Mutant Breast Cancer

    DTIC Science & Technology

    2015-09-01

    AWARD NUMBER: W81XWH-14-1-0359 TITLE: Targeting ESR1 -Mutant Breast Cancer PRINCIPAL INVESTIGATOR: Dr. Sarat Chandarlapaty CONTRACTING...31 Aug 2015 4. TITLE AND SUBTITLE Targeting ESR1 -Mutant Breast Cancer 5a. CONTRACT NUMBER 5b. GRANT NUMBER W81XWH-14-1-0359 5c. PROGRAM ELEMENT...Distribution Unlimited 13. SUPPLEMENTARY NOTES 14. ABSTRACT The hypothesis of this proposal is that LBD mutations in ESR1 promote resistance to

  3. Novel Therapeutic Targets for Chronic Migraine

    DTIC Science & Technology

    2014-11-01

    Award Number: W81XWH-11-1-0647 TITLE: Novel Therapeutic Targets for Chronic Migraine PRINCIPAL INVESTIGATORS: Peter Goadsby CONTRACTING...Therapeutic Targets for Chronic Migraine 5a. CONTRACT NUMBER 5b. GRANT NUMBER W81XWH-11-1-0647 5c. PROGRAM ELEMENT NUMBER 6. AUTHOR(S) Peter Goadsby, M.D...ABSTRACT Chronic migraine is a disabling disorder that affects millions of individuals worldwide, and may result from traumatic brain injury. The purpose of

  4. Experimental study of the astrophysically important Na 23 ( α , p ) Mg 26 and Na 23 ( α , n ) Al 26 reactions

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Avila, M. L.; Rehm, K. E.; Almaraz-Calderon, S.

    The 23Na(α,p) 26Mg and 23Na(α,n) 26Al reactions are important for our understanding of the 26Al abundance in massive stars. The aim of this work is to report on a direct and simultaneous measurement of these astrophysically important reactions using an active target system. The reactions were investigated in inverse kinematics using 4He as the active target gas in the detector. We measured the excitation functions in the energy range of about 2 to 6 MeV in the center of mass. We have found that the cross sections of the 23Na(α,p) 26Mg and the 23Na(α,n) 26Al reactions are in good agreementmore » with previous experiments and with statistical-model calculations. As a result, the astrophysical reaction rate of the 23Na(α,n) 26Al reaction has been reevaluated and it was found to be larger than the recommended rate.« less

  5. Experimental study of the astrophysically important Na 23 ( α , p ) Mg 26 and Na 23 ( α , n ) Al 26 reactions

    DOE PAGES

    Avila, M. L.; Rehm, K. E.; Almaraz-Calderon, S.; ...

    2016-12-19

    The 23Na(α,p) 26Mg and 23Na(α,n) 26Al reactions are important for our understanding of the 26Al abundance in massive stars. The aim of this work is to report on a direct and simultaneous measurement of these astrophysically important reactions using an active target system. The reactions were investigated in inverse kinematics using 4He as the active target gas in the detector. We measured the excitation functions in the energy range of about 2 to 6 MeV in the center of mass. We have found that the cross sections of the 23Na(α,p) 26Mg and the 23Na(α,n) 26Al reactions are in good agreementmore » with previous experiments and with statistical-model calculations. As a result, the astrophysical reaction rate of the 23Na(α,n) 26Al reaction has been reevaluated and it was found to be larger than the recommended rate.« less

  6. New evaporator station for the center for accelerator target science

    NASA Astrophysics Data System (ADS)

    Greene, John P.; Labib, Mina

    2018-05-01

    As part of an equipment grant provided by DOE-NP for the Center for Accelerator Target Science (CATS) initiative, the procurement of a new, electron beam, high-vacuum deposition system was identified as a priority to insure reliable and continued availability of high-purity targets. The apparatus is designed to contain TWO electron beam guns; a standard 4-pocket 270° geometry source as well as an electron bombardment source. The acquisition of this new system allows for the replacement of TWO outdated and aging vacuum evaporators. Also included is an additional thermal boat source, enhancing our capability within this deposition unit. Recommended specifications for this system included an automated, high-vacuum pumping station, a deposition chamber with a rotating and heated substrate holder for uniform coating capabilities and incorporating computer-controlled state-of-the-art thin film technologies. Design specifications, enhanced capabilities and the necessary mechanical modifications for our target work are discussed.

  7. 75 FR 10026 - Proposed Collection; Comment Request for Forms W-2, W-2c, W-2AS, W-2GU, W-2VI, W-3, W-3c, W-3cPR...

    Federal Register 2010, 2011, 2012, 2013, 2014

    2010-03-04

    ... Wage and Tax Statements), W-3PR (Informe de Comprobantes de Retencion), W-3cPR (Transmission de Comprobantes de Retencion Corregidos), and W-3SS (transmittal of Wage and Tax Staements). OMB Number: 1545-0008... Actions: There are no changes being made to the form at this time. Type of Review: Extension of a...

  8. Two Higgs doublet model with vectorlike leptons and contributions to pp → W W and H → W W

    NASA Astrophysics Data System (ADS)

    Dermíšek, Radovan; Lunghi, Enrico; Shin, Seodong

    2016-02-01

    We study a two Higgs doublet model extended by vectorlike leptons mixing with one family of standard model leptons. Generated flavor violating couplings between heavy and light leptons can dramatically alter the decay patterns of heavier Higgs bosons. We focus on pp → H → ν 4 ν μ → W μν μ , where ν 4 is a new neutral lepton, and study possible effects of this process on the measurements of pp → W W and H → W W since it leads to the same final states. We discuss predictions for contributions to pp → W W and H → WW and their correlations from the region of the parameter space that satisfies all available constraints including precision electroweak observables and from pair production of vectorlike leptons. Large contributions, close to current limits, favor small tan β region of the parameter space. We find that, as a result of adopted cuts in experimental analyses, the contribution to pp → W W can be an order of magnitude larger than the contribution to H → W W . Thus, future precise measurements of pp → W W will further constrain the parameters of the model. In addition, we also consider possible contributions to pp → W W from the heavy Higgs decays into a new charged lepton e 4 ( H → e 4 μ → W μν μ ), exotic SM Higgs decays, and pair production of vectorlike leptons.

  9. Excitation energies, radiative and autoionization rates, dielectronic satellite lines, and dielectronic recombination rates for excited states of Na-like W from Ne-like W

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Safronova, U.I.; Safronova, A.S.; Beiersdorfer, P.

    Energy levels, radiative transition probabilities, and autoionization rates for 1s{sup 2}2s{sup 2}2p{sup 5}3l{sup '}nl,1s{sup 2}2s2p{sup 6}3l{sup '}nl(n=3-7,l{<=}n-1) and 1s{sup 2}2s{sup 2}2p{sup 5}4l{sup '}nl,1s{sup 2}2s2p{sup 6}4l{sup '}nl(n=4-6,l{<=}n-1) states in Na-like tungsten (W{sup 63+}) are calculated. Cowan's relativistic Hartree-Fock method, the relativistic multiconfiguration method implemented in the Hebrew University Lawrence Livermore Atomic Code, and the relativistic many-body perturbation theory method, are used. Autoionizing levels above the threshold 1s{sup 2}2s{sup 2}2p{sup 6} are considered. It is found that configuration mixing [3sns+3pnp+3dnd],[3snp+3pns+3pnd+3dnp] plays an important role for all atomic characteristics. Also strong mixing between states with 2s and 2p holes (1s{sup 2}2s{sup 2}2p{sup 5}3l{submore » 1}nl{sub 2}+1s{sup 2}2s2p{sup 6}3l{sub 3}nl{sub 4}) occurs. Branching ratios relative to the first threshold and intensity factors are calculated for satellite lines, and dielectronic recombination (DR) rate coefficients are determined for the excited 1s{sup 2}2s{sup 2}2p{sup 6}nl(n=3-7,l{<=}n-1) states. It is shown that the contribution of the highly excited states is very important for calculation of total DR rates. Contributions from the autoionizing states 1s{sup 2}2s{sup 2}2p{sup 5}3l{sup '}nl,1s{sup 2}2s2p{sup 6}3l{sup '}nl(n{>=}8) and 1s{sup 2}2s{sup 2}2p{sup 5}4l{sup '}nl,1s{sup 2}2s2p{sup 6}4l{sup '}nl(n{>=}7) to the DR rate coefficients are estimated by extrapolation of all atomic parameters. The orbital angular momentum (l) distribution of the rate coefficients shows a peak at l=2. The total DR rate coefficient is derived as a function of electron temperature. The dielectronic satellite spectra of W{sup 63+} are important for L-shell diagnostics of very high-temperature laboratory plasmas such as future ITER fusion plasmas.« less

  10. Increased delivery of condensation nuclei during the Late Heavy Bombardment to the terrestrial and martian atmospheres

    NASA Astrophysics Data System (ADS)

    Losiak, Anna

    2014-05-01

    LHB should be taken into account when constructing models of terrestrial and Martian climates around 4 Ga. Bland P.A., Artemieva N.A. (2006) Meteorit.Planet.Sci. 41:607-631. Bottke W.F. et al. (2012) Nature 485: 78-81. Fassett C.I., Minton D.A. (2013) Nat.Geosci. 6:520-524 (2013). Hunten D.M. et al. (1980) J.Atmos.Sci. 37:1342-1357. Haberle R.M. et al. (1999) J.Geophys.Res. 104:8957-8974. Ivanov B.A., Hartmann W.K. (2009) Planets and Moons: Treatise on Geophysics (eds. Spohn T.): 207-243. Michaels T.I. et al. (2006) Geophys.Res.Lett. 33:L16201. Montmessin F. et al. (2004) J.Geophys.Res. 109:E10004. Ogurtsov M.G., Raspopov O.M. (2011) Geomagnetism&Aeronomy 51:275-283. Rosen J.M. (1968) Space Sci.Rev. 9:58-89. Ryder G. (2002) J.Geophys.Res. 107: doi:10.1029/2001JE001583. Segura T.L. et al. (2002) Science 298:1977-1980. Segura T.L. et al. (2012) Icarus 220:144-148. Sleep N.S. et al. (1989) Nature 342:139-142. Tegen I. (2003) Quat.Sci.Rev. 22:1821-1834. Urata R.A., Toon O.B. (2013) Icarus 226:229-250. Wordsworth R. et al. (2012) Icarus 222:1-19.

  11. Reduced levels of skeletal muscle Na+K+ -ATPase in McArdle disease

    NASA Technical Reports Server (NTRS)

    Haller, R. G.; Clausen, T.; Vissing, J.; Blomqvist, C. G. (Principal Investigator)

    1998-01-01

    We evaluated the hypothesis that impaired sarcolemmal function associated with exaggerated potassium release, impaired potassium uptake, or both may contribute to exertional fatigue and abnormal circulatory responses to exercise in McArdle disease (MD). The cellular mechanism of exertional fatigue and muscle injury in MD is unknown but likely involves impaired function of the ATPases that couple ATP hydrolysis to cellular work, including the muscle sodium potassium pump (Na+K+-ATPase). However, the concentration of muscle Na+K+ pumps in MD is not known, and no studies have related exercise increases in blood potassium concentrations to muscle Na+K+ pump levels. We measured muscle Na+K+ pumps (3H-ouabain binding) and plasma K+ in response to 20 minutes of cycle exercise in six patients with MD and in six sex-, age-, and weight-matched sedentary individuals. MD patients had lower levels of 3H-ouabain binding (231 +/- 18 pmol/g w.w., mean +/- SD, range, 210 to 251) than control subjects (317 +/- 37, range, 266 to 371, p < 0.0004), higher peak increases in plasma potassium in response to 45 +/- 7 W cycle exercise (MD, 1.00 +/- 0.15 mmol/L; control subjects, 0.48 +/- 0.09; p < 0.0001), and mean exercise heart rate responses to exercise that were 45 +/- 12 bpm greater than control subjects. Our results indicate that Na+K+ pump levels are low in MD patients compared with healthy subjects and identify a limitation of potassium reuptake that could result in sarcolemmal failure during peak rates of membrane activation and may promote exaggerated potassium-activated circulatory responses to submaximal exercise. The mechanism of the low Na+K+ pump concentrations in MD is unknown but may relate to deconditioning or to disruption of a close functional relationship between membrane ion transport and glycolysis.

  12. Two Higgs doublet model with vectorlike leptons and contributions to pp → W W and H → W W

    DOE PAGES

    Dermíšek, Radovan; Lunghi, Enrico; Shin, Seodong

    2016-02-18

    In this paper, we study a two Higgs doublet model extended by vectorlike leptons mixing with one family of standard model leptons. Generated flavor violating couplings between heavy and light leptons can dramatically alter the decay patterns of heavier Higgs bosons. We focus on pp → H → ν 4ν μ → W μν μ, where ν 4 is a new neutral lepton, and study possible effects of this process on the measurements of pp → W W and H → W W since it leads to the same final states. We discuss predictions for contributions to pp → Wmore » W and H →WW and their correlations from the region of the parameter space that satisfies all available constraints including precision electroweak observables and from pair production of vectorlike leptons. Large contributions, close to current limits, favor small tan β region of the parameter space. We find that, as a result of adopted cuts in experimental analyses, the contribution to pp → W W can be an order of magnitude larger than the contribution to H → W W . Thus, future precise measurements of pp → W W will further constrain the parameters of the model. Also, we also consider possible contributions to pp → W W from the heavy Higgs decays into a new charged lepton e 4 (H → e 4μ → W μν μ), exotic SM Higgs decays, and pair production of vectorlike leptons.« less

  13. First-principles investigation of the physical properties of cubic and orthorhombic phase Na3UO4

    NASA Astrophysics Data System (ADS)

    Chen, Haichuan; Tian, Wenyan

    2017-11-01

    The anisotropic elastic properties, Vickers hardness, Debye temperature and the minimum thermal conductivity of c-Na3UO4 and o-Na3UO4 have been investigated by means of the first principles calculations. The lattice parameters are in good agreement with the available experimental data and the theoretical results. The elastic constants satisfy the mechanical stability criteria show that both of them are mechanically stable. The value of B / G and Cauchy pressure reveal that the c-Na3UO4 holds a ductile behavior while the o-Na3UO4 behaves a brittle manner. The elastic anisotropy of c-Na3UO4 is less weak than that of o-Na3UO4. The hardness shows that both of them can be classified as ;soft materials;. Finally, the Debye temperature is 452.6 K and 388.4 K, and the minimum thermal conductivities kmin is 0.883 W m-1 K-1 and 0.753 W m-1 K-1 of c-Na3UO4 and o-Na3UO4, respectively. Due to relatively lower thermal conductivity, and thereby they are suitable to be used as thermal insulating materials.

  14. Evaluation of computational models and cross sections used by MCNP6 for simulation of characteristic X-ray emission from thick targets bombarded by kiloelectronvolt electrons

    NASA Astrophysics Data System (ADS)

    Poškus, A.

    2016-09-01

    This paper evaluates the accuracy of the single-event (SE) and condensed-history (CH) models of electron transport in MCNP6.1 when simulating characteristic Kα, total K (=Kα + Kβ) and Lα X-ray emission from thick targets bombarded by electrons with energies from 5 keV to 30 keV. It is shown that the MCNP6.1 implementation of the CH model for the K-shell impact ionization leads to underestimation of the K yield by 40% or more for the elements with atomic numbers Z < 15 and overestimation of the Kα yield by more than 40% for the elements with Z > 25. The Lα yields are underestimated by more than an order of magnitude in CH mode, because MCNP6.1 neglects X-ray emission caused by electron-impact ionization of L, M and higher shells in CH mode (the Lα yields calculated in CH mode reflect only X-ray fluorescence, which is mainly caused by photoelectric absorption of bremsstrahlung photons). The X-ray yields calculated by MCNP6.1 in SE mode (using ENDF/B-VII.1 library data) are more accurate: the differences of the calculated and experimental K yields are within the experimental uncertainties for the elements C, Al and Si, and the calculated Kα yields are typically underestimated by (20-30)% for the elements with Z > 25, whereas the Lα yields are underestimated by (60-70)% for the elements with Z > 49. It is also shown that agreement of the experimental X-ray yields with those calculated in SE mode is additionally improved by replacing the ENDF/B inner-shell electron-impact ionization cross sections with the set of cross sections obtained from the distorted-wave Born approximation (DWBA), which are also used in the PENELOPE code system. The latter replacement causes a decrease of the average relative difference of the experimental X-ray yields and the simulation results obtained in SE mode to approximately 10%, which is similar to accuracy achieved with PENELOPE. This confirms that the DWBA inner-shell impact ionization cross sections are significantly more

  15. Practical experience and challenges in the operation of medical cyclotron.

    PubMed

    Kumar, Rajeev; Sonkawade, Rajendra G; Pandey, Anil K; Tripathi, Madhavi; Damle, Nishikant A; Kumar, Praveen; Bal, Chandra S

    2017-01-01

    The aim of this article was to share 10 years of operational experience of medical cyclotron and to provide working knowledge on the same. This experience has helped us gain working knowledge on cyclotron operation with practical points, which may help in improving F yield, minimizing the breakdown time, and help in the prevention of the occurrence of unusual events. Our facility has a self-shielded radioisotope delivery system eclipse 111 medical cyclotron with an 11 MeV proton beam in use for the past 10 years to produce positron emitters - namely, F, N, and F-2 gas - for PET imaging. During F production, we have followed a set protocol comprising the following: monitoring target pressure, rinsing the target with O water just immediately after bombardment, ion source feedback, radiofrequency (RF) feedback, and recording any unusual events that occurred during the operation. Besides this, enrichment of O water, target volume, target current, energy of the beam, variation in argon pressure on the target, bombardment duration, target status (new or old target or total number of previous bombardments on the same target), status of the delivery lines from target to the radiochemistry module (old or new) were also recorded. Rinsing with O water immediately after bombardment increases the life of the target and delivery line. The frequent problems encountered were with the ion source, RF, and target foil rupture. These problems were solved by rebuilding the ion source, changing the fuse of RF, and rebuilding the target. F yield can be increased by rinsing with O water immediately after bombardment. The effect of target leak - that is, rupture of vacuum window - can be avoided by immediate stoppage of bombardment.

  16. 29 CFR Appendix A to Subpart W to... - Figures W-14 through W-28

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 29 Labor 8 2010-07-01 2010-07-01 false Figures W-14 through W-28 A Appendix A to Subpart W to part 1926 Labor Regulations Relating to Labor (Continued) OCCUPATIONAL SAFETY AND HEALTH ADMINISTRATION...; Overhead Protection Pt. 1926, Subpt. W, App. A Appendix A to Subpart W to part 1926—Figures W-14 through W...

  17. Randomly distilling W-class states into general configurations of two-party entanglement

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Cui, W.; Chitambar, E.; Lo, H. K.

    2011-11-15

    In this article we obtain results for the task of converting a single N-qubit W-class state (of the form {radical}(x{sub 0})|00...0>+{radical}(x{sub 1})|10...0>+{center_dot}{center_dot}{center_dot}+{radical}(x{sub N})|00...1>) into maximum entanglement shared between two random parties. Previous studies in random distillation have not considered how the particular choice of target pairs affects the transformation, and here we develop a strategy for distilling into general configurations of target pairs. We completely solve the problem of determining the optimal distillation probability for all three-qubit configurations and most four-qubit configurations when x{sub 0}=0. Our proof involves deriving new entanglement monotones defined on the set of four-qubit W-class states.more » As an additional application of our results, we present new upper bounds for converting a generic W-class state into the standard W state |W{sub N}>={radical}((1/N))(|10...0>+{center_dot}{center_dot}{center_dot}+|00...1>).« less

  18. 22 W average power multiterawatt femtosecond laser chain enabling 1019 W/cm2 at 100 Hz

    NASA Astrophysics Data System (ADS)

    Clady, R.; Azamoum, Y.; Charmasson, L.; Ferré, A.; Utéza, O.; Sentis, M.

    2018-05-01

    We measure the wavefront distortions of a high peak power ultrashort (23 fs) laser system under high average power load. After 6 min—100 Hz operation of the laser at full average power (> 22 W after compression), the thermally induced wavefront distortions reach a steady state and the far-field profile of the laser beam no longer changes. By means of a deformable mirror located after the vacuum compressor, we apply a static pre-compensation to correct those aberrations allowing us to demonstrate a dramatic improvement of the far-field profile at 100 Hz with the reduction of the residual wavefront distortions below λ/16 before focusing. The applied technique provides 100 Hz operation of the femtosecond laser chain with stable pulse characteristics, corresponding to peak intensity above 1019 W/cm2 and average power of 19 W on target, which enables the study of relativistic optics at high repetition rate using a moderate f-number focusing optics ( f/4.5).

  19. Laboratory study of hyper-elocity impact-driven chemical reactions and surface evolution in icy targets.

    NASA Astrophysics Data System (ADS)

    Ulibarri, Z.; Munsat, T.; Dee, R.; Horanyi, M.; James, D.; Kempf, S.; Nagle, M.; Sternovsky, Z.

    2017-12-01

    Although ice is prevalent in the solar system and the long-term evolution of many airless icy bodies is affected by hypervelocity micrometeoroid bombardment, there has been little experimental investigation into these impact phenomena, especially at the impact speeds encountered in space. For example, there is little direct information about how dust impacts alter the local chemistry, and dust impacts may be an important mechanism for creating complex organic molecules necessary for life. Laser ablation and light-gas gun experiments simulating dust impacts have successfully created amino acid precursors from base components in ice surfaces. Additionally, the Cassini mission revealed CO2 deposits in icy satellites of Saturn, which may have been created by dust impacts. With the creation of a cryogenically cooled ice target for the dust accelerator facility at the NASA SSERVI-funded Institute for Modeling Plasma, Atmospheres, and Cosmic Dust (IMPACT), it is now possible to study the effects of micrometeoroid impacts in a controlled environment under conditions and at energies typically encountered in nature. Complex ice-target mixtures are created with a flash-freezing target which allows for homogeneous mixtures to be frozen in place even with salt mixtures that otherwise would form inhomogeneous ice surfaces. Coupled with the distinctive capabilities of the IMPACT dust facility, highly valuable data concerning the evolution of icy bodies under hypervelocity bombardment and the genesis of complex organic chemistry on these icy bodies can be gathered in unique and tightly controlled experiments. Results from recent and ongoing investigations will be presented.

  20. Identification of number and type of cations in water-soluble Cs+ and Na+ calix[4]arene-bis-crown-6 complexes by using ESI-TOF-MS.

    PubMed

    Kumagai, Shogo; Hayashi, Kotaro; Kameda, Tomohito; Morohashi, Naoya; Hattori, Tetsutaro; Yoshioka, Toshiaki

    2018-04-01

    The treatment of cesium-contaminated wastewater has become one of the biggest issues. The selective Cs + removal from wastewater containing competitive alkali metal ions such as Na + is desired to reduce the volume of sludge. Therefore, the present work focused on water-soluble calix[4]arene-bis-crown-6 (W-BisC6) to selectively capture Cs + . For characterization of the complex, UV-vis spectroscopy is commonly used, however, due to the limited availability of information it can be hard to quickly identify the specific structures of some complexes. In this work, the electrospray ionization time of flight spectrometry (ESI-TOF-MS) is successfully utilized to identify the number and type of cations in W-BisC6-cation complexes. ESI-TOF-MS accurately recognized 4 types of complex (W-BisC6-Na + , W-BisC6-Cs + , W-BisC6-2Na + , W-BisC6-Na + -Cs + ), and the experimental and simulated results were almost perfectly matched. It also revealed the difficulty of W-BisC6-2Cs + complex formation under the present conditions. Thus, this technique is significantly helpful for rapid identification of the specific structures of complexes during Cs + -contaminated wastewater treatment. Copyright © 2018 Elsevier Ltd. All rights reserved.

  1. Elastic and inelastic scattering of /sup 58/Ni+/sup 208/Pb at bombarding energies from 598 to 1011 MeV

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Beckerman, M.; Auble, R.L.; Bertrand, F.E.

    1987-08-01

    High-resolution measurements have been made of elastic and inelastic scattering of /sup 58/Ni+ /sup 208/Pb at four bombarding energies from 10.3 to 17.4 MeV/nucleon. The considerable inelastic strength observed for excitation energies up to at least 7 MeV is dominated by Coulomb-driven quadrupole transitions. Analyses were done using both the distorted-wave Born approximation and coupled-channels models. At the highest bombarding energies the data can be described equally well by distorted-wave Born approximations and coupled channels analyses. We find that B(E2) = 0.062 e/sup 2/b/sup 2/ for the 1.454 MeV 2/sup +/ state in /sup 58/Ni and B(E2) = 0.34 e/supmore » 2/b/sup 2/ for the 4.09 MeV 2/sup +/ state in /sup 208/Pb.« less

  2. Design of a liquid membrane target for high repetition rate neutron generation

    NASA Astrophysics Data System (ADS)

    Poole, Patrick; Andereck, C. David; Storm, Mike; Schumacher, Douglass

    2013-10-01

    Ultra-bright, pulsed, spatially-small sources of energetic neutrons have applications in radiography and non-destructive remote sensing. Neutrons can be generated by a process wherein ions accelerated from a laser-irradiated primary target subsequently bombard a converter material, causing neutron-producing nuclear reactions, such as 7Li(d,n)8Be. Deuterons from this process are suppressed by contamination that builds up on the rear of the solid primary target. To eliminate this issue we propose a self-replenishing liquid membrane target consisting of heavy water and deuterated surfactant, formed in-vacuum within a moveable wire frame. In addition to removing issues associated with solid target positioning and collateral damage, this apparatus provides flow rate and target thickness control, and allows for the high repetition rates required to generate desired neutron fluxes with a portable laser-based system. The apparatus design will be presented, as well as a novel interferometric method that measures the membrane thickness using tightly-focused light. This work was performed with support from DARPA.

  3. Cyclotron production of 61Cu using natural Zn & enriched 64Zn targets

    NASA Astrophysics Data System (ADS)

    Asad, A. H.; Smith, S. V.; Chan, S.; Jeffery, C. M.; Morandeau, L.; Price, R. I.

    2012-12-01

    Copper-61 (61Cu) shares with 64Cu certain advantages for PET diagnostic imaging, but has a shorter half-life (3.4hr vs. 12.7hr) and a greater probability of positron production per disintegration (61% vs. 17.9%). One important application is for in vivo imaging of hypoxic tissue. In this study 61Cu was produced using the 64Zn(p,α)61Cu reaction on natural Zn or enriched 64Zn targets. The enriched 64Zn (99.82%) was electroplated onto high purity gold or silver foils or onto thin Al discs. A typical target bombardment used 30μA; at 11.7, 14.5 or 17.6MeV over 30-60min. The 61Cu (radiochemical purity of >95%) was separated using a combination of cation and anion exchange columns. The 64Zn target material was recovered after each run, for re-use. In a direct comparison with enriched 64Zn-target results, 61Cu production using the cheaper natZn target proved to be an effective alternative.

  4. Thermomechanical and chemical properties of porous W/liquid Li hybrid systems as plasma-facing self-healing surfaces

    NASA Astrophysics Data System (ADS)

    Kapat, Aveek; Lang, Eric; Neff, Anton; Allain, Jean Paul

    2017-10-01

    The environmental conditions at the plasma-material interface of a future nuclear fusion reactor interacting will be extreme. The incident plasma will carry heat fluxes of the order of 100's of MWm-2 and particle fluxes that can average 1024 m-2s-1. The fusion reactor wall would need to operate at high temperatures near 800 C and the incident energy of particles will vary from a few eV ions to MeV neutrons. A hybrid system, inspired by self-healing solid-state concepts, combines the ductile phase of liquid Li within a solid phase porous W. The liquid Li serves to control hydrogen retention and provide vapor shielding, within the framework of a tunable porosity to optimize edge plasma conditions [2]. Additionally, the porous interface can also provide for effective defect sinks for high duty cycle neutron damage. The surface chemistry of liquid Li on a porous surface varied with D irradiation is studied and its effect on retention. Prior results with refractory alloys have demonstrated effective wetting properties [3]. These hybrid systems, as well as traditional W samples, are bombarded with 500eV D2+and Ar+ at 230oC and 300oC. The Li, O, and C XPS peaks were examined and compared to controls. Additionally, the porous W is characterized for thermo-mechanical properties. Work supported by USDOE Contract DE- DE-SC0014267.

  5. Fast atom bombardment tandem mass spectrometry of carotenoids

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    van Breeman, R.B.; Schmitz, H.H.; Schwartz, S.J.

    Positive ion fast atom bombardment (FAB) tandem mass spectrometry (MS-MS) using a double-focusing mass spectrometer with linked scanning at constant B/E and high-energy collisionally activated dissociation (CAD) was used to differentiate 17 different cartenoids, including {beta}-apo-8{prime}- carotenal, astaxanthin, {alpha}-carotene, {beta}-carotene, {gamma}-carotene, {zeta}-carotene, canthaxanthin, {beta}-cryptoxanthin, isozeaxanthin bis (pelargonate), neoxanthin, neurosporene, nonaprene, lutein, lycopene, phytoene, phytofluene, and zeaxanthin. The carotenoids were either synthetic or isolated from plant tissues. The use of FAB ionization minimized degradation or rearrangement of the carotenoid structures due to the inherent thermal instability generally ascribed to these compounds. Instead of protonated molecules, both polar xanthophylls and nonpolar carotenesmore » formed molecular ions, M{sup {center_dot}+}, during FAB ionization. Following collisionally activated dissociation, fragment ions of selected molecular ion precursors showed structural features indicative of the presence of hydroxyl groups, ring systems, ester groups, and aldehyde groups and the extent of aliphatic polyene conjugation. The fragmentation patterns observed in the mass spectra herein may be used as a reference for the structural determination of carotenoids isolated from plant and animal tissues. 18 refs., 4 figs.« less

  6. Back-bombardment compensation in microwave thermionic electron guns

    NASA Astrophysics Data System (ADS)

    Kowalczyk, Jeremy M. D.; Madey, John M. J.

    2014-12-01

    The development of capable, reliable, and cost-effective compact electron beam sources remains a long-standing objective of the efforts to develop the accelerator systems needed for on-site research and industrial applications ranging from electron beam welding to high performance x-ray and gamma ray light sources for element-resolved microanalysis and national security. The need in these applications for simplicity, reliability, and low cost has emphasized solutions compatible with the use of the long established and commercially available pulsed microwave rf sources and L-, S- or X-band linear accelerators. Thermionic microwave electron guns have proven to be one successful approach to the development of the electron sources for these systems providing high macropulse average current beams with picosecond pulse lengths and good emittance out to macropulse lengths of 4-5 microseconds. But longer macropulse lengths are now needed for use in inverse-Compton x-ray sources and other emerging applications. We describe in this paper our approach to extending the usable macropulse current and pulse length of these guns through the use of thermal diffusion to compensate for the increase in cathode surface temperature due to back-bombardment.

  7. 77 FR 51589 - ReconTrust Company, N.A., et al.; Notice of Application and Temporary Order

    Federal Register 2010, 2011, 2012, 2013, 2014

    2012-08-24

    ... SECURITIES AND EXCHANGE COMMISSION [Release No. IC-30174; 812-14068] ReconTrust Company, N.A., et... entered against ReconTrust Company, N.A. (``ReconTrust'') on August 20, 2012 by the United States District.... ReconTrust Company, N.A. No. 2:11-cv- 1460 (W.D. Wash. August 20, 2012). \\3\\ The Complaint was initially...

  8. Preliminary results of the mission profile life test of a 30 cm Hg bombardment thruster

    NASA Technical Reports Server (NTRS)

    Bechtel, R. T.; James, E. L.

    1979-01-01

    Long term tests were performed on a 30 cm Hg bombardment thruster and a power processing unit to determine lifetime characteristics. The thruster performance data and other operational characteristics taken at various times during the test segment are presented and evaluated with the life limiting mechanisms: discharge chamber erosion, deposition and spalling, external erosion, cathode degradation, and propellant isolator leakage. The control algorithms for thruster start up, steady state operation, throttle, detection and correction of off normal conditions, and shutdown are discussed.

  9. Simultaneous qubit-loss-free fusion of three multiple W states

    NASA Astrophysics Data System (ADS)

    Wang, Meiyu; Hao, Quanzhi; Yan, Fengli; Gao, Ting

    2018-05-01

    Qubit-loss-free fusion for two W states introduced by Li K et al (2016 Phys. Rev. A 94 062315) clearly increases the final size of the obtained W state and greatly reduces the number of fusion steps to achieve a W state of a target size. Motivated by this idea, we propose a qubit-loss-free fusion scheme for fusing three polarization entangled W states simultaneously. The elements of a two-outcome positive-operator valued measurement and the appropriate joint unitary operation for realizing a positive-operator valued measurement measurement are given. As an example, with the assistance of weak cross-Kerr nonlinearities, an optical setup for fusing three W states is proposed. We analyze the success probability of the scheme and the resource cost of the present scheme, as compared to previous work.

  10. Microbiological changes occurring in trout fillets (Oncorhynchus mykiss W. 1792) salted and treated with potassium sorbate during production and storage.

    PubMed

    Oksüztepe, Gülsüm; Gürel Inanli, Ayşe

    2007-08-15

    In this study, microbiological changes during processing and storage of salted-cured trout fillets treated with potassium sorbate were investigated. For this purpose, 10 and 15% (w/w) NaCl and 1, 5 and 10% (w/v) potassium sorbate were applied to the fillets. The processed fillets were vacuum-packed and storage at 4 degrees C. The samples were analyzed in some periods of production and in the storage days of 7, 14, 28, 42, 56, 70 and 84 for numbers of total mesophilic aerob, psycrophylic, yeast and mould. In conclusion, the microbiological quality of all samples treated with 15% NaCl and potassium sorbate were found better. Consequently, it can be concluded that the usage of potassium sorbate may be useful and a synergistic effect between salt and potassium sorbate determined.

  11. Micro-channel-based high specific power lithium target

    NASA Astrophysics Data System (ADS)

    Mastinu, P.; Martın-Hernández, G.; Praena, J.; Gramegna, F.; Prete, G.; Agostini, P.; Aiello, A.; Phoenix, B.

    2016-11-01

    A micro-channel-based heat sink has been produced and tested. The device has been developed to be used as a Lithium target for the LENOS (Legnaro Neutron Source) facility and for the production of radioisotope. Nevertheless, applications of such device can span on many areas: cooling of electronic devices, diode laser array, automotive applications etc. The target has been tested using a proton beam of 2.8MeV energy and delivering total power shots from 100W to 1500W with beam spots varying from 5mm2 to 19mm2. Since the target has been designed to be used with a thin deposit of lithium and since lithium is a low-melting-point material, we have measured that, for such application, a specific power of about 3kW/cm2 can be delivered to the target, keeping the maximum surface temperature not exceeding 150° C.

  12. Use of Bifunctional Immunotherapeutic Agents to Target Breast Cancer

    DTIC Science & Technology

    2007-07-01

    Science 270, 1500–1502. 32. Pasqualini , R., Koivunen, E., and Ruoslahti, E. (1997) v integrins as receptors for tumor targeting by circulating ligands...Nat. Biotech- nol. 15, 542–546. 33. Arap, W., Pasqualini , R., and Ruoslahti, E. (1998) Cancer treatment by targeted drug delivery to tumor...Cancer Res. 2, 663–673. 47. Arap, W., Pasqualini , R., and Ruoslahti, E. (1998) Cancer treatment by targeted drug delivery to tumor vasculature in a

  13. Novel Targeted Therapies for Inflammatory Breast Cancer

    DTIC Science & Technology

    2017-10-01

    AWARD NUMBER: W81XWH-16-1-0461 TITLE: Novel Targeted Therapies for Inflammatory Breast Cancer PRINCIPAL INVESTIGATOR: Jose Silva CONTRACTING...CONTRACT NUMBER Novel Targeted Therapies for Inflammatory Breast Cancer 5b. GRANT NUMBER W81XWH-16-1-0461 5c. PROGRAM ELEMENT NUMBER 6. AUTHOR(S) l 5d...NOTES 14. ABSTRACT Inflammatory breast cancer (IBC, ~5% of all breast cancers ) is the most lethal form of breast cancer , presenting a 5- year

  14. TEM observations of radiation damage in tungsten irradiated by 20 MeV W ions

    NASA Astrophysics Data System (ADS)

    Ciupiński, Ł.; Ogorodnikova, O. V.; Płociński, T.; Andrzejczuk, M.; Rasiński, M.; Mayer, M.; Kurzydłowski, K. J.

    2013-12-01

    Polycrystalline, recrystallized W targets were subjected to implantation with 20 MeV W6+ ions in order to simulate radiation damage caused by fusion neutrons. Three samples with cumulative damage of 0.01, 0.1 and 0.89 dpa were produced. The near-surface zone of each sample has been analyzed by transmission electron microscopy (TEM). To this end, lamellae oriented perpendicularly to the targets implanted surface were milled out using focused ion beam (FIB). A reference lamella from non-irradiated, recrystallized W target was also prepared to estimate the damage introduced during FIB processing. TEM studies revealed a complex microstructure of the damaged zones as well as its evolution with cumulative damage level. The experimentally observed damage depth agrees very well with the one calculated using the Stopping and Range of Ions in Matter (SRIM) software.

  15. An apparatus for the preparation of [15O]-H2O for rapid repetitive PET studies

    NASA Astrophysics Data System (ADS)

    Dahl, J. R.; Chaly, T. C.; Matacchieri, R. A.; Yee, A.; Dhawan, V.; Horowitz, S.; Jespersen, K.; Margouleff, D.; Eidelberg, D.

    1999-06-01

    The use of [15O]-H2O to follow changes in cerebral blood flow using PET has become frequent and widespread, requiring an apparatus easily operated by personnel unfamiliar with the physics and chemistry involved. Oxygen-15 is prepared by the 14N(d,n)15O nuclear reaction using a target of UHP nitrogen with 1% UHP hydrogen added, contained in a target chamber similar to that reported for the preparation of [18F]-F2. Nucleogenic 15O reacts with hydrogen in the target gas to produce [15O]-H2O. Some of the N target reacts with hydrogen to produce NH3, which must be removed. At the end of bombardment (minimum 6 min.) the target gas is released through a small amount of parenteral water which then flows through approximately 50 mg Dowex 50W-X8 resin (100-200 mesh) to remove the NH3. Sufficient 23.4% NaCl solution is added to produce an isotonic solution. The isotonic solution is sterilized by filtration through a 0.22 micron filter into an injection syringe which is sent via pneumatic transport to the PET imaging room. The apparatus, which uses a programmable logic controller and four switches to allow the operator to select standby, refill, collect activity, or deliver dose operations of the production process, provides doses of [15O]-H2O up to 35 mCi/dose at intervals as frequent as seven minutes with minimal radiation exposure to the operators.

  16. Production of Ne Auger electrons by Ne/+/ bombardment of Mg and Al surfaces

    NASA Technical Reports Server (NTRS)

    Ferrante, J.; Pepper, S. V.

    1976-01-01

    A description is given of experiments which provide evidence for the production of an inner shell vacancy in the Ne by the asymmetric Ne-Mg and Ne-Al collision. In addition, autoionization states of neutral Ne have been observed. These states are to be distinguished from the more usual case in Auger electron spectroscopy of de-excitation of an ion with a core vacancy. The experiments involved the bombardment of Mg and Al surfaces with Ne(+) ions. A LEED-Auger system equipped with an ion gun and a four-grid retarding potential analyzer operated in the usual dN(E)/dE mode was used.

  17. Sensitivity of 30-cm mercury bombardment ion thruster characteristics to accelerator grid design

    NASA Technical Reports Server (NTRS)

    Rawlin, V. K.

    1978-01-01

    The design of ion optics for bombardment thrusters strongly influences overall performance and lifetime. The operation of a 30 cm thruster with accelerator grid open area fractions ranging from 43 to 24 percent, was evaluated and compared with experimental and theoretical results. Ion optics properties measured included the beam current extraction capability, the minimum accelerator grid voltage to prevent backstreaming, ion beamlet diameter as a function of radial position on the grid and accelerator grid hole diameter, and the high energy, high angle ion beam edge location. Discharge chamber properties evaluated were propellant utilization efficiency, minimum discharge power per beam amp, and minimum discharge voltage.

  18. Compact Torus plasma ring accelerator: a new type driver for inertial confinement fusion

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Hartman, C.W.; Eddleman, J.L.; Hammer, J.H.

    1986-08-22

    We discuss the acceleration of magnetically-confined plasma rings to provide a driver for ICF. The acceleration of plasma rings is predicted to be efficient and following focusing, to generate ion-bombardment power in the range 10/sup 15/ to 10/sup 16/ W/cm/sup 2/ at a total deposition energy of multimegajoules. The simplicity of plasma ring accelerator suggests that a 5 MJ (on target) driver would cost in the range 1 to 5 $/joule. First experimental tests of the accelerator are described.

  19. Atomic Number Dependence of Hadron Production at Large Transverse Momentum in 300 GeV Proton--Nucleus Collisions

    DOE R&D Accomplishments Database

    Cronin, J. W.; Frisch, H. J.; Shochet, M. J.; Boymond, J. P.; Mermod, R.; Piroue, P. A.; Sumner, R. L.

    1974-07-15

    In an experiment at the Fermi National Accelerator Laboratory we have compared the production of large transverse momentum hadrons from targets of W, Ti, and Be bombarded by 300 GeV protons. The hadron yields were measured at 90 degrees in the proton-nucleon c.m. system with a magnetic spectrometer equipped with 2 Cerenkov counters and a hadron calorimeter. The production cross-sections have a dependence on the atomic number A that grows with P{sub 1}, eventually leveling off proportional to A{sup 1.1}.

  20. Target and beam-target spin asymmetries in exclusive pion electroproduction for Q2>1 GeV2. II. e p →e π0p

    NASA Astrophysics Data System (ADS)

    Bosted, P. E.; Kim, A.; Adhikari, K. P.; Adikaram, D.; Akbar, Z.; Amaryan, M. J.; Anefalos Pereira, S.; Avakian, H.; Badui, R. A.; Ball, J.; Balossino, I.; Battaglieri, M.; Bedlinskiy, I.; Biselli, A. S.; Boiarinov, S.; Briscoe, W. J.; Brooks, W. K.; Bültmann, S.; Burkert, V. D.; Cao, T.; Carman, D. S.; Celentano, A.; Chandavar, S.; Charles, G.; Chetry, T.; Ciullo, G.; Clark, L.; Colaneri, L.; Cole, P. L.; Contalbrigo, M.; Cortes, O.; Crede, V.; D'Angelo, A.; Dashyan, N.; De Vita, R.; De Sanctis, E.; Deur, A.; Djalali, C.; Dupre, R.; Egiyan, H.; El Alaoui, A.; El Fassi, L.; Elouadrhiri, L.; Eugenio, P.; Fanchini, E.; Fedotov, G.; Fegan, S.; Fersch, R.; Filippi, A.; Fleming, J. A.; Forest, T. A.; Fradi, A.; Ghandilyan, Y.; Gilfoyle, G. P.; Girod, F. X.; Glazier, D. I.; Gohn, W.; Golovatch, E.; Gothe, R. W.; Griffioen, K. A.; Guidal, M.; Guler, N.; Hakobyan, H.; Guo, L.; Hafidi, K.; Hakobyan, H.; Hanretty, C.; Harrison, N.; Hattawy, M.; Heddle, D.; Hicks, K.; Hollis, G.; Holtrop, M.; Hughes, S. M.; Ireland, D. G.; Isupov, E. L.; Jenkins, D.; Jiang, H.; Jo, H. S.; Joo, K.; Keller, D.; Khachatryan, G.; Khandaker, M.; Kim, W.; Klei, A.; Klein, F. J.; Koirala, S.; Kubarovsky, V.; Kuhn, S. E.; Lanza, L.; Lenisa, P.; Livingston, K.; Lu, H. Y.; MacGregor, I. J. D.; Markov, N.; Mayer, M.; McCracken, M. E.; McKinnon, B.; Mineeva, T.; Mirazita, M.; Mokeev, V. I.; Montgomery, R. A.; Movsisyan, A.; Munoz Camacho, C.; Murdoch, G.; Nadel-Turonski, P.; Ni, A.; Niccolai, S.; Niculescu, G.; Osipenko, M.; Ostrovidov, A. I.; Paolone, M.; Paremuzyan, R.; Park, K.; Pasyuk, E.; Phelps, W.; Pisano, S.; Pogorelko, O.; Price, J. W.; Prok, Y.; Protopopescu, D.; Puckett, A. J. R.; Raue, B. A.; Ripani, M.; Rizzo, A.; Rosner, G.; Rossi, P.; Roy, P.; Sabatié, F.; Saini, M. S.; Schumacher, R. A.; Seder, E.; Sharabian, Y. G.; Skorodumina, Iu.; Smith, G. D.; Sokhan, D.; Sparveris, N.; Stankovic, I.; Stepanyan, S.; Stoler, P.; Strakovsky, I. I.; Strauch, S.; Taiuti, M.; Tian, Ye; Torayev, B.; Ungaro, M.; Voskanyan, H.; Voutier, E.; Walford, N. K.; Watts, D. P.; Wei, X.; Weinstein, L. B.; Zachariou, N.; Zhang, J.; Zhao, Z. W.; Zonta, I.; CLAS Collaboration

    2017-03-01

    Beam-target double-spin asymmetries and target single-spin asymmetries were measured for the exclusive π0 electroproduction reaction γ*p →p π0 , expanding an analysis of the γ*p →n π+ reaction from the same experiment. The results were obtained from scattering of 6-GeV longitudinally polarized electrons off longitudinally polarized protons using the CEBAF Large Acceptance Spectrometer at Jefferson Laboratory. The kinematic ranges covered are 1.1 <W <3 GeV and 1 W , Q2, cos(θ*) , and ϕ*. The beam-target asymmetries were found to generally be greater than zero, with relatively modest ϕ* dependence. The target asymmetries exhibit very strong ϕ* dependence, with a change in sign occurring between results at low W and high W , in contrast to π+ electroproduction. Reasonable agreement is found with phenomenological fits to previous data for W <1.6 GeV, but significant differences are seen at higher W . When combined with cross-sectional measurements, as well as π+ observables, the present results will provide powerful constraints on nucleon resonance amplitudes at moderate and large values of Q2, for resonances with masses as high as 2.4 GeV.

  1. Proton Energy Optimization and Spatial Distribution Analysis from a Thickness Study Using Liquid Crystal Targets

    NASA Astrophysics Data System (ADS)

    Willis, Christopher; Poole, Patrick; Schumacher, Douglas; Freeman, Richard; van Woerkom, Linn

    2016-10-01

    Laser-accelerated ions from thin targets have been widely studied for applications including secondary radiation sources and cancer therapy, with recent studies trending towards thinner targets which can provide improved ion energies and yields. Here we discuss results from an experiment on the Scarlet laser at OSU using variable thickness liquid crystal targets. On this experiment, the spatial and spectral distributions of accelerated ions were measured along target normal and laser axes at varying thicknesses from 150nm to 2000nm at a laser intensity of 1 ×1020W /cm2 . Maximum ion energy was observed for targets in the 600 - 800nm thickness range, with proton energies reaching 24MeV . The ions were further characterized using radiochromic film, revealing an unusual spatial distribution on many laser shots. Here, the peak ion yield falls in an annular ring surrounding the target normal, with an increasing divergence angle as a function of ion energy. Details of these spatial and spectral ion distributions will be presented, including spectral deconvolution of the RCF data, revealing additional trends in the accelerated ion distributions. Supported by the DARPA PULSE program through a Grant from AMRDEC, and by the NNSA under contract DE-NA0001976.

  2. Study Into Combustion of Sewage Sludge as Energetic Fuel / Badania Spalania OSADÓW ŚCIEKOWYCH Jako Paliwa Energetycznego

    NASA Astrophysics Data System (ADS)

    Kijo-Kleczkowska, Agnieszka; Środa, Katarzyna; Otwinowski, Henryk

    2013-12-01

    Along with the development of civilisation, it can be observed that the amount of waste of different type is growing and the preparation process for further usage of the waste or the utilization process differs. What is to be focused on is municipal sewage sludge which, due to its energetic properties, constitutes a valuable fuel. The problem of usage of municipal sewage sludge remains still unsolved, which stems both from the increasing amount of such waste, and from the lack of properly adjusted systems for thermal processing thereof. What is of an additional obstacle are the increasingly stricter legal regulations regarding disposal of sewage sludge after the year 2013; hence, it is necessary to consider various benefits resulting from thermal processing of such waste. This work presents an overview of methods of disposal of sewage sludge, taking into consideration, in particular, thermal methods including the process of combustion and co-combustion as a means of successful utilization. The research section of the work presents the results of study into the mechanism and kinetics of combustion of sewage sludge in various conditions of the process carried out in air flow. Combustion of sewage sludge has been compared against combustion of coal and biomass. Wraz z rozwojem cywilizacji zaobserwować można postępujące powstawanie różnego rodzaju odpadów różniących się, m.in. sposobem przygotowania do dalszego wykorzystania, czy procesem utylizacji. Na szczególną uwagę zasługują komunalne osady ściekowe, które z uwagi na właściwości energetyczne stanowią cenne paliwo. Problem wykorzystania komunalnych osadów ściekowych jest nadal otwarty, a wynika to zarówno z rosnącej produkcji tych odpadów, jak i braku odpowiednio przystosowanych instalacji do termicznego ich przekształcania. Dodatkowym utrudnieniem są zaostrzające się przepisy prawne dotyczące składowania osadów ściekowych po 2013 r. skłaniające tym samym do rozważań nad korzy

  3. Processing of sputter targets using current activated pressure assisted densification

    NASA Astrophysics Data System (ADS)

    Chaney, Neil Russell

    Thin Film deposition is a process that has been around since the beginning of the twentieth century and has become an integral part of the microfabrication and nanofabrication industries. Sputter deposition is a method of physical vapor deposition (PVD) in which a target is bombarded with ions and atoms are ejected and deposited as a thin film on a substrate. Despite extensive research on the direct process of sputtering thin films from targets to substrates, not much work has been done on studying the effect of processing on the microstructure of a target. In the first part of this work, the development of a PVD chamber is explored along with a few modifications and improvements developed along the way. A multiple process PVD chamber was equipped with three different types of PVD processes: sputtering, evaporation, and electron-beam deposition. In the second part of this work, the effect of processing of sputter targets on deposited films is explored. Multiple targets of Copper and yttria stabilized zirconia were produced using CAPAD. The effect of the processing on the microstructure of the targets was determined. The targets were then sputtered into films to study the effects of the target grain size on their properties. The effect of power and pressure were also measured. Increased power led to increased deposition rates while higher vacuum caused deposition rates to decrease.

  4. Impact and effects of simultaneous MeV-ion irradiation and helium plasma exposure to the formation of tungsten nano-tendrils

    NASA Astrophysics Data System (ADS)

    Wright, Graham; Kesler, Leigh Ann; Whyte, Dennis

    2013-10-01

    The extrusion of nano-tendrils from high temperature (>1000 K) tungsten (W) targets exposed to helium (He) plasma ions remains a concern for future fusion reactors. Previous work on the Alcator C-Mod tokamak has demonstrated it is possible to form these structures in a tokamak environment. However, one area where Alcator C-Mod and a fusion reactor differ is total neutron flux at the wall and the displacement damage these neutrons produce in the plasma-facing materials. This dsiplacement damage may affect the size and number He bubbles precipitating in the W target, which is a key factor in the formation and growth of the nano-tendrils. The DIONISOS experiment directly measures the impact of the displacement damage by simultaneously bombarding high temperature W targets with MeV-range ions (to simulate the displacement damage caused by neutron flux) and high flux of He plasma ions. Different combinations of irradiating ion species and W target temperatures are used to vary the different processes and rates that are involved such as He trapping rate, vacancy production and annealing rates, and nano-tendril growth rate. The nano-tendril growth is characterized by SEM imaging and focused ion beam (FIB) cross-sectioning and compared to nano-tendril formation without the presence of the irradiating ion beam. This work is supported by US DOE award DE-SC00-02060.

  5. Qweak Data Analysis for Target Modeling Using Computational Fluid Dynamics

    NASA Astrophysics Data System (ADS)

    Moore, Michael; Covrig, Silviu

    2015-04-01

    The 2.5 kW liquid hydrogen (LH2) target used in the Qweak parity violation experiment is the highest power LH2 target in the world and the first to be designed with Computational Fluid Dynamics (CFD) at Jefferson Lab. The Qweak experiment determined the weak charge of the proton by measuring the parity-violating elastic scattering asymmetry of longitudinally polarized electrons from unpolarized liquid hydrogen at small momentum transfer (Q2 = 0 . 025 GeV2). This target met the design goals of < 1 % luminosity reduction and < 5 % contribution to the total asymmetry width (the Qweak target achieved 2 % or 55 ppm). State of the art time dependent CFD simulations are being developed to improve the predictions of target noise on the time scale of the electron beam helicity period. These predictions will be bench-marked with the Qweak target data. This work is an essential ingredient in future designs of very high power low noise targets like MOLLER (5 kW, target noise asymmetry contribution < 25 ppm) and MESA (4.5 kW).

  6. Efficient and stable transformation of hop (Humulus lupulus L.) var. Eroica by particle bombardment.

    PubMed

    Batista, Dora; Fonseca, Sandra; Serrazina, Susana; Figueiredo, Andreia; Pais, Maria Salomé

    2008-07-01

    To the best of our knowledge, this is the first accurate and reliable protocol for hop (Humulus lupulus L.) genetic transformation using particle bombardment. Based on the highly productive regeneration system previously developed by us for hop var. Eroica, two efficient transformation protocols were established using petioles and green organogenic nodular clusters (GONCs) bombarded with gusA reporter and hpt selectable genes. A total of 36 hygromycin B-resistant (hyg(r)) plants obtained upon continuous selection were successfully transferred to the greenhouse, and a first generation group of transplanted plants was followed after spending a complete vegetative cycle. PCR analysis showed the presence of one of both transgenes in 25 plants, corresponding to an integration frequency of 69.4% and an overall transformation efficiency of 7.5%. Although all final transformants were GUS negative, the integration frequency of gusA gene was higher than that of hpt gene. Petiole-derived transgenic plants showed a higher co-integration rate of 76.9%. Real-time PCR analysis confirmed co-integration in 86% of the plants tested and its stability until the first generation, and identified positive plants amongst those previously assessed as hpt (+) only by conventional PCR. Our results suggest that the integration frequencies presented here, as well as those of others, may have been underestimated, and that PCR results should be taken with precaution not only for false positives, but also for false negatives. The protocols here described could be very useful for future introduction of metabolic or resistance traits in hop cultivars even if slight modifications for other genotypes are needed.

  7. Spectroscopic measurements and modeling of tungsten erosion in the DIII-D divertor

    NASA Astrophysics Data System (ADS)

    Abrams, T. D.; Ding, R.; Guo, H. Y.; Leonard, A. W.; Thomas, D. M.; Allen, S. L.; McLean, A. G.; Briesemeister, A. R.; Unterberg, E. A.; Chrobak, C.; Doerner, R. P.; Rudakov, D. L.; Elder, J. D.; Stangeby, P. C.; Wampler, W. R.; Watkins, J. G.

    2015-11-01

    In situ time-resolved measurements of the gross W erosion rate have been performed in DIII-D by monitoring W/I (400.9 nm) emission in the divertor via a filtered camera and high-resolution spectrometer. The erosion rate of a thin W coating on DiMES, inferred via the S/XB method, was found to be ~ 0.7 nm/s during deuterim L-mode exposure, in fair agreement with post-mortem IBA analysis but lower than REDEP/WBC modeling. During H-mode He bombardment of W disks, average erosion rates of ~ 2.9 nm/s and ~ 9.0 nm/s were estimated during the inter-ELM and intra-ELM phases, using ne and Te from divertor Thomson scattering and Langmuir probes. Results will also be presented from additional W erosion experiments in preparation for the DIII-D mini-campaign to measure high-Z transport in the edge plasma. Comparisons will be made with ERO modeling Supported by US DOE DE-AC05-06OR23100, DE-FC02-04ER54698, DE-AC52-07NA27344, DE-AC05-00OR22725, DE-SC0001961, DE-AC04-94AL85000.

  8. Renovation of Large-Panel Buildings in Context of Urban Renewal/ Remonty Budynków Wielkopłytowych, Jako Element Rewitalizacji Miast

    NASA Astrophysics Data System (ADS)

    Ligęza, Wiesław

    2015-06-01

    The article presents issues connected with renovating multi-storey precast concrete buildings, resulting from the consequences of construction defects occurring over the course of the building process and use of the buildings, as well as design flaws and construction defects when insulating external partitions. Analyses and conclusions which stem from them cover issues of renovation in the light of: damage in the vertical and horizontal joints, damage to the connection of layers in three-layer load-bearing and curtain walls, the effect of the damage on the possibilities of carrying out functional modernization of residential units, the effect of the damage on the effectiveness of thermo-modernization - new problems related to faulty insulation W artykule przedstawiono zagadnienia remontowe w budynkach wielkopłytowych wynikające ze skutków wad budowlanych powstałych w czasie budowy i eksploatacji oraz wad projektowych i wykonawczych przy realizacji docieplenia przegród zewnętrznych. Analizy i wynikające z nich wnioski obejmują zagadnienia remontowe w świetle: uszkodzeń w złączach pionowych i poziomych, uszkodzeń połączenia warstw w ścianach trójwarstwowych nośnych i osłonowych, wpływu uszkodzeń na możliwości modernizacji funkcjonalnej lokali mieszkalnych, wpływu uszkodzeń na skuteczność termomodernizacji - nowe problemy w aspekcie źle wykonanego ocieplenia.

  9. The Effectiveness of Organic Pollutants Removal in Constructed Wetland with Horizontal Sub-Surface Flow / Efektywność Usuwania Zanieczyszczeń Organicznych W Oczyszczalni Hydrofitowej

    NASA Astrophysics Data System (ADS)

    Jakubaszek, Anita; Sadecka, Zofia

    2015-03-01

    This paper presents the results of the research work related to the removal efficiency from wastewater organic pollutants and suspended solids at HSSF (horizontal subsurface flow) constructed wetland. The average effectiveness defined as loss of value COD in wastewater has reached 77%, for BOD5 - 80% and TOC - 82%. The effect of seasonal temperature changes and the period of plant vegetation and rest on the effectiveness of wastewater treatment were also analyzed. The results of the presented research showed a decrease in the efficiency of removing organic pollutants from wastewater and suspended solids in the autumn and winter. During the vegetation the object in Małyszyn has been characterized by the effectiveness of wastewater treatment at the level of 78% for COD, 82% for BOD5, and in the non-vegetation period the effectiveness has decreased up to 75% for COD and 74% for BOD5. During the plants growth the total suspension was removed in 88%, whereas during the plants rest efficiency of removing lowered to 69%. W pracy przedstawiono wyniki badań dotyczące efektywności usuwania ze ścieków zanieczyszczeń organicznych w oczyszczalni hydrofitowej. Średnia skuteczność oczyszczania wyrażona jako obniżenie wartości ChZT w ściekach była na poziomie 77%, dla BZT5 80%, a dla OWO 82%. Analizowano również wpływ sezonowych zmian temperatury oraz okresu wegetacji i spoczynku roślin na skuteczność oczyszczania ścieków. Wyniki badań wykazały obniżenie efektywności usuwania zanieczyszczeń organicznych ze ścieków wyrażonych przez ChZT i BZT5 oraz zawiesiny ogólnej w okresie jesienno-zimowym. W okresie wegetacyjnym obiekt w Małyszynie charakteryzował się efektywnością oczyszczania ścieków na poziomie: 78% dla ChZT, 82% dla BZT5, a w sezonie pozawegetacyjnym skuteczność uległa obniżeniu do 75% w przypadku ChZT oraz 74% dla BZT5. Zawiesina ogólna w okresie wegetacji trzciny usuwana była w 88%, a w okresie powegetacyjnym w 69%.

  10. Lepton Number Violating e-W+ → e+W- → W-W- Processes in the Left-Right Gauge Model

    NASA Astrophysics Data System (ADS)

    Doi, M.

    1999-03-01

    As new tests of the nature of neutrinos, lepton number violating e-W+a → e+W-b and e-e- → W-a W-b processes are studied within the SU(2)L × SU(2)R × U(1)B-L gauge model. They take place via exchange of a Majorana neutrino and a doubly charged Higgs particle. Differential cross sections are derived in the most general form. The angular distribution of the former process becomes resonant at cos θj= -1+2(Ma2Mb2 -mj2s)/ (s-Ma2) (s-Mb2), from which the neutrino mass mj can be deduced. Differential cross sections are estimated by using present bounds on the parameters. The cross section of the former process is about 102 times larger than the latter. Another process, e-p → e+W-n, which includes e-W+ → e+ W- as a sub-process, is also discussed, and orders of magnitude of the cross section are estimated.

  11. Production of W + W - pairs via γ * γ * → W + W - subprocess with photon transverse momenta

    NASA Astrophysics Data System (ADS)

    Łuszczak, Marta; Schäfer, Wolfgang; Szczurek, Antoni

    2018-05-01

    We discuss production of W + W - pairs in proton-proton collisions induced by two-photon fusion including, for a first time, transverse momenta of incoming photons. The unintegrated inelastic fluxes (related to proton dissociation) of photons are calculated based on modern parametrizations of deep inelastic structure functions in a broad range of their arguments ( x and Q 2). In our approach we can get separate contributions of different W helicities states. Several one- and two-dimensional differential distributions are shown and discussed. The present results are compared to the results of previous calculations within collinear factorization approach. Similar results are found except of some observables such as e.g. transverse momentum of the pair of W + and W -. We find large contributions to the cross section from the region of large photon virtualities. We show decomposition of the total cross section as well as invariant mass distribution into the polarisation states of both W bosons. The role of the longitudinal F L structure function is quantified. Its inclusion leads to a 4-5% decrease of the cross section, almost independent of M WW .

  12. Compact Electron Gun Based on Secondary Emission Through Ionic Bombardment

    PubMed Central

    Diop, Babacar; Bonnet, Jean; Schmid, Thomas; Mohamed, Ajmal

    2011-01-01

    We present a new compact electron gun based on the secondary emission through ionic bombardment principle. The driving parameters to develop such a gun are to obtain a quite small electron gun for an in-flight instrument performing Electron Beam Fluorescence measurements (EBF) on board of a reentry vehicle in the upper atmosphere. These measurements are useful to characterize the gas flow around the vehicle in terms of gas chemical composition, temperatures and velocity of the flow which usually presents thermo-chemical non-equilibrium. Such an instrument can also be employed to characterize the upper atmosphere if placed on another carrier like a balloon. In ground facilities, it appears as a more practical tool to characterize flows in wind tunnel studies or as an alternative to complex electron guns in industrial processes requiring an electron beam. We describe in this paper the gun which has been developed as well as its different features which have been characterized in the laboratory. PMID:22163896

  13. Arsenic treatment and power generation with a dual-chambered fuel cell with anionic and cationic membranes using NaHCO3 anolyte and HCl or NaCl catholyte.

    PubMed

    Maitlo, Hubdar Ali; Kim, Jung Hwan; Park, Joo Yang

    2017-04-01

    Dual-chambered fuel cells with an iron anode and an air-carbon cathode separated by an ion exchange membranes have been used to treat arsenate during power production. To select an effective catholyte, the dual-chambered fuel cell consisted 90 mL of 0.1 M HCl or 0.5 M NaCl as the catholyte and 1 L of 0.1 M NaHCO 3 as the anolyte at an initial pH 5. The 0.1 M HCl was an effective catholyte, with which 1 ppm arsenate in 1 L of anolyte was reduced to 5 ppb in 1 h, and the maximum power density was about 6.3 w/m 2 with an anion exchange membrane fuel cell (AEM_FC) and 4.4 w/m 2 with a cation exchange membrane fuel cell (CEM_FC). Therefore, 90 mL of 0.1 M HCl was used as a catholyte to treat 20 L of 0.1 M NaHCO 3 anolyte containing 1 ppm arsenate at an initial pH of 5 or 7. The arsenate level at pH 5 decreased to less than 5 ppb in 4 h, and the maximum power density was 5.9 W/m 2 and 4.7 W/m 2 with AEM_FC and CEM_FC, respectively. When using 0.01 M NaHCO 3 as the anolyte at pH 5, arsenate was reduced to less than 5 ppb in 8 and 24 h for AEC_FC and CEM_FC, respectively. However, when using an anolyte at pH 7, arsenate could not be effectively removed in 24 h. Therefore, when using carbonate as an anolyte, the solution should be adjusted to a weakly acidic pH in order to remove arsenate. Copyright © 2017 Elsevier Ltd. All rights reserved.

  14. New constraints on the Paleoarchean meteorite bombardment of the Earth - Geochemistry and Re-Os isotope signatures of spherule layers in the BARB5 ICDP drill core from the Barberton Greenstone Belt, South Africa

    NASA Astrophysics Data System (ADS)

    Schulz, Toni; Koeberl, Christian; Luguet, Ambre; van Acken, David; Mohr-Westheide, Tanja; Ozdemir, Seda; Reimold, Wolf Uwe

    2017-08-01

    Archean spherule layers, resulting from impacts by large extraterrestrial objects, to date represent the only remnants of the early meteorite, asteroid, and comet bombardment of the Earth. Only few Archean impact debris layers have been documented, all of them embedded in the 3.23-3.47 billion year old successions of the Barberton Greenstone Belt (BGB) in South Africa and the Pilbara Craton in Western Australia. Some of them might be correlated with each other. Given the scarcity of Archean spherule deposits, four spherule layer intersections from the recently recovered BARB5 drill core from the central Barberton Greenstone Belt, analyzed in this study, provide an opportunity to gain new insight into the early terrestrial impact bombardment. Despite being hydrothermally overprinted, siderophile element abundance signatures of spherule-rich samples from the BARB5 drill core, at least in part, retained a meteoritic fingerprint. The impact hypothesis for the generation of the BARB5 spherule layers is supported by correlations between the abundances of moderately (Cr, Co, Ni) and highly siderophile (Re, Os, Ir, Pt, Ru and Pd) elements, whose peak concentrations and interelement ratios are within the range of those for chondrites. Rhenium-Osmium isotope evidence further support the impact hypothesis. Collectively, this study provides evidence for extraterrestrial admixtures ranging between ∼40 and up to 100% to three of the four analyzed BARB5 spherule layers, and a scenario for their genesis involving (i) impact of a chondritic bolide into a sedimentary target, (ii) varying admixtures of meteoritic components to target materials, (iii) spherule formation via condensation in an impact vapor plume, (iv) transportation of the spherules and sedimentation under submarine conditions, followed by (v) moderate post-impact remobilization of transition metals and highly siderophile elements.

  15. On the history of the early meteoritic bombardment of the Moon: Was there a terminal lunar cataclysm?

    NASA Astrophysics Data System (ADS)

    Michael, Greg; Basilevsky, Alexander; Neukum, Gerhard

    2018-03-01

    the considered histograms and relative probability plots not only the 3.87 Ga peak (due to Imbrium basin), but also several secondary peaks caused by the formation of other basins distributed between 3.87 and 4.25 Ga. The lunar terminal cataclysm hypothesis is in disagreement with the distribution of K-Ar ages for the highland rocks of the lunar meteorites. The population of lunar meteorites representing localities randomly distributed over the lunar surface, and thus free from the mentioned sampling bias, shows no ∼3.9 Ga peak as it should, if the cataclysm did occur. We conclude that the statistics of sample ages contradict the terminal cataclysm scenario in the bombardment of the Moon. We also see evidence for the formation of several impact basins between 3.87 and 4.25 Ga which is likewise incompatible with the hypothesis of a short interval cataclysm. There remain other basins, including the largest South Pole - Aitken, the ages of which should be determined in future studies to further clarify the impact history. Sample-return missions targeted to date several key basins need to be planned, and the continued study of lunar meteorites may also bring new details to the general view of the impact bombardment of the Moon.

  16. Transmitting Memory between and beyond Generations: The Rotterdam Bombardment in Local Memory Culture and Education from 1980 to 2015

    ERIC Educational Resources Information Center

    Hogervorst, Susan

    2015-01-01

    This article analyses three local educational projects about the Nazi bombing of Rotterdam in May 1940, all of which took place from 1980 to the present day in the context of the dynamic memory culture of the bombardment. These three contexts testify to a process by which memory, increasingly derived from authentic locations and objects instead of…

  17. Size analysis of nanoparticles extracted from W/O emulsions.

    PubMed

    Nagelreiter, C; Kotisch, H; Heuser, T; Valenta, C

    2015-07-05

    Nanosized particles are frequently used in many different applications, especially TiO2 nanoparticles as physical filters in sunscreens to protect the skin from UV radiation. However, concerns have arisen about possible health issues caused by nanoparticles and therefore, the assessment of the occurrence of nanoparticles is important in pharmaceutical and cosmetic formulations. In a previous work of our group, a method was presented to extract nanoparticles from O/W emulsions. But to respond to the needs of dry and sensitive skin, sunscreens of the water-in-oil emulsion type are available. In these, assessment of present nanoparticles is also an important issue, so the present study offers a method for extracting nanoparticles from W/O emulsions. Both methods emanate from the same starting point, which minimizes both effort and cost before the beginning of the assessment. By addition of NaOH pellets and centrifugation, particles were extracted from W/O emulsions and measured for their size and surface area by laser diffraction. With the simple equation Q=A/S a distinction between nanoparticles and microparticles was achieved in W/O emulsions, even in commercially available samples. The present method is quick and easy to implement, which makes it cost-effective. Copyright © 2015 Elsevier B.V. All rights reserved.

  18. Channeling effect in polycrystalline deuterium-saturated CVD diamond target bombarded by deuterium ion beam

    NASA Astrophysics Data System (ADS)

    Bagulya, A. V.; Dalkarov, O. D.; Negodaev, M. A.; Rusetskii, A. S.; Chubenko, A. P.; Ralchenko, V. G.; Bolshakov, A. P.

    2015-07-01

    At the ion accelerator HELIS at LPI, the neutron yield is investigated in DD reactions within a strongly textured polycrystalline deuterium-saturated CVD diamond under irradiation by a deuterium ion beam with the energy of less than 30 keV. The measurements of the neutron flux in the beam direction are performed using a multichannel detector based on 3He counters, in dependence on the target angle, β, with respect to the beam axis. A significant anisotropy in the neutron yield is observed. At β = 0° the yield is higher by a factor of 3 as compared to that at β = ±45°. The possible reasons for the anisotropy, including ion channeling, are discussed.

  19. wALADin benzimidazoles differentially modulate the function of porphobilinogen synthase orthologs.

    PubMed

    Lentz, Christian S; Halls, Victoria S; Hannam, Jeffrey S; Strassel, Silke; Lawrence, Sarah H; Jaffe, Eileen K; Famulok, Michael; Hoerauf, Achim; Pfarr, Kenneth M

    2014-03-27

    The heme biosynthesis enzyme porphobilinogen synthase (PBGS) is a potential drug target in several human pathogens. wALADin1 benzimidazoles have emerged as species-selective PBGS inhibitors against Wolbachia endobacteria of filarial worms. In the present study, we have systematically tested wALADins against PBGS orthologs from bacteria, protozoa, metazoa, and plants to elucidate the inhibitory spectrum. However, the effect of wALADin1 on different PBGS orthologs was not limited to inhibition: several orthologs were stimulated by wALADin1; others remained unaffected. We demonstrate that wALADins allosterically modulate the PBGS homooligomeric equilibrium with inhibition mediated by favoring low-activity oligomers, while 5-aminolevulinic acid, Mg(2+), or K(+) stabilized high-activity oligomers. Pseudomonas aeruginosa PBGS could be inhibited or stimulated by wALADin1 depending on these factors and pH. We have defined the wALADin chemotypes responsible for either inhibition or stimulation, facilitating the design of tailored PBGS modulators for potential application as antimicrobial agents, herbicides, or drugs for porphyric disorders.

  20. Human leukemia antigen-A*0201-restricted epitopes of human endogenous retrovirus W family envelope (HERV-W env) induce strong cytotoxic T lymphocyte responses.

    PubMed

    Tu, Xiaoning; Li, Shan; Zhao, Lijuan; Xiao, Ran; Wang, Xiuling; Zhu, Fan

    2017-08-01

    Human endogenous retrovirus W family (HERV-W) envelope (env) has been reported to be related to several human diseases, including autoimmune disorders, and it could activate innate immunity. However, there are no reports investigating whether human leukemia antigen (HLA)-A*0201 + restriction is involved in the immune response caused by HERV-W env in neuropsychiatric diseases. In the present study, HERV-W env-derived epitopes presented by HLA-A*0201 are described with the potential for use in adoptive immunotherapy. Five peptides displaying HLA-A*0201-binding motifs were predicted using SYFEPITHI and BIMAS, and synthesized. A CCK-8 assay showed peptides W, Q and T promoted lymphocyte proliferation. Stimulation of peripheral blood mononuclear cells from HLA-A*0201 + donors with each of these peptides induced peptide-specific CD8 + T cells. High numbers of IFN-γ-secreting T cells were also detectable after several weekly stimulations with W, Q and T. Besides lysis of HERV-W env-loaded target cells, specific apoptosis was also observed. These data demonstrate that human T cells can be sensitized toward HERV-W env peptides (W, Q and T) and, moreover, pose a high killing potential toward HERV-W env-expressing U251 cells. In conclusion, peptides W Q and T, which are HERV-W env antigenic epitopes, have both antigenicity and immunogenicity, and can cause strong T cell immune responses. Our data strengthen the view that HERV-W env should be considered as an autoantigen that can induce autoimmunity in neuropsychiatric diseases, such as multiple sclerosis and schizophrenia. These data might provide an experimental foundation for a HERV-W env peptide vaccine and new insight into the treatment of neuropsychiatric diseases.

  1. Design of 20 W fiber-coupled green laser diode by Zemax

    NASA Astrophysics Data System (ADS)

    Qi, Yunfei; Zhao, Pengfei; Wu, Yulong; Chen, Yongqi; Zou, Yonggang

    2017-09-01

    We represent a design of a 20 W, fiber-coupled diode laser module based on 26 single emitters at 520 nm. The module can produce more than 20 W output power from a standard fiber with core diameter of 400 μm and numerical aperture (NA) of 0.22. To achieve a 20 W laser beam, the spatial beam combination and polarization beam combination by polarization beam splitter are used to combine output of 26 single emitters into a single beam, and then an aspheric lens is used to couple the combined beam into an optical fiber. The simulation shows that the total coupling efficiency is more than 95%. Project supported by the National Key R& D Program of China (No. 2016YFB0402105), the Key Deployment Program of the Chinese Academy of Sciences (No. KGZD-SW-T01-2), and the National Natural Science Foundation of China (No. 61404135).

  2. Blast-Wave Generation and Propagation in Rapidly Heated Laser-Irradiated Targets

    NASA Astrophysics Data System (ADS)

    Ivancic, S. T.; Stillman, C. R.; Nilson, P. M.; Solodov, A. A.; Froula, D. H.

    2017-10-01

    Time-resolved extreme ultraviolet (XUV) spectroscopy was used to study the creation and propagation of a >100-Mbar blast wave in a target irradiated by an intense (>1018WWcm2 cm2) laser pulse. Blast waves provide a platform to generate immense pressures in the laboratory. A temporal double flash of XUV radiation was observed when viewing the rear side of the target, which is attributed to the emergence of a blast wave following rapid heating by a fast-electron beam generated from the laser pulse. The time-history of XUV emission in the photon energy range of 50 to 200 eV was recorded with an x-ray streak camera with 7-ps temporal resolution. The heating and expansion of the target was simulated with an electron transport code coupled to 1-D radiation-hydrodynamics simulations. The temporal delay between the two flashes measured in a systematic study of target thickness and composition was found to evolve in good agreement with a Sedov-Taylor blast-wave solution. This material is based upon work supported by the Department of Energy National Nuclear Security Administration under Award Number DE-NA0001944 and Department of Energy Office of Science Award Number DE-SC-0012317.

  3. Underground Lead-Zinc Mine Production Planning Using Fuzzy Stochastic Inventory Policy / Planowanie Wydobycia Cynku I Ołowiu W Kopalniach Podziemnych Z Wykorzystaniem Podejścia Stochastycznego Z Elementami Logiki Rozmytej Do Określania Niezbędnego Poziomu Zapasów

    NASA Astrophysics Data System (ADS)

    Gligoric, Zoran; Beljic, Cedomir; Gluscevic, Branko; Cvijovic, Cedomir

    2015-03-01

    Methodology for long-term underground lead-zinc mine planning based on fuzzy inventory theory is presented in this paper. We developed a fuzzy stochastic model of inventory control problem for planning lead-zinc ore production under uncertainty. The final purpose of this article is to find the optimal quantity of mined ore that should be stockpiled, in order to enable "feeding" of mineral processing plant in cases when the production in underground mine is interrupted, by using Possibilistic mean value of fuzzy number for defuzzing the fuzzy total annual inventory costs, and by using Extension of the Lagrangean method for solving inequality constrain problem. The different types of costs involved in mined ore inventory problems affect the efficiency of production scheduling. Dynamic nature of lead and zinc metal price is described by Ornstein-Uhlenbeck stochastic mean reverting process. The model is illustrated with a numerical example. W pracy przedstawiono metodologię długoterminowego wydobycia cynku i ołowiu w kopalniach podziemnych z wykorzystaniem podejścia stochastycznego z elementami logiki rozmytej do określania wymaganego poziomu zapasów. Opracowaliśmy model stochastyczny z wykorzystaniem elementów logiki rozmytej do kontroli zapasów w planowaniu wydobycia cynku i ołowiu w warunkach niepewności. Celem końcowym pracy jest określenie optymalnej ilości wydobywanej rudy, którą należy zachować jako zapas tak aby zapewnić odpowiednie jej dostawy do zakładu przeróbczego nawet w przypadku przerwania wydobycia w kopalni podziemnej, opierając się na posybilistycznej wartości średniej liczby rozmytej i wyostrzeniu całkowitych rocznych kosztów zapasów. Wykorzystano także rozszerzenie metody Lagrange'a do rozwiązywania problemu więzów w nierówności. Różnorakie koszty związane ze składowaniem zapasów wydobywanej rudy mają wpływ na wydajność planowanej produkcji. Dynamiczne zmiany cen cynku i o

  4. Identification of Molecular Receptors for Therapeutic Targeting in Prostate Cancer

    DTIC Science & Technology

    2009-12-01

    125:385–398. 11. Arap W, et al. (2002) Steps toward mapping the human vasculature by phage display. Nat Med 8:121–127. 12. Arap W, Pasqualini R...surface expression of the stress response chaperone GRP78 enables tumor targeting by circulating ligands. Cancer Cell 6:275–284. 14. Pasqualini R...Ruoslahti E (1996) Organ targeting in vivo using phage display peptide libraries. Nature 380:364–366. 15. Pasqualini R, Arap W, Rajotte D, Ruoslahti E (2001

  5. Bridge Busters: The 397th Bombardment Group (Medium) and the B-26 Marauder in World War II

    DTIC Science & Technology

    2015-06-01

    up largely of new pilots from the training pipeline, these established groups transitioned from flying other aircraft. Unfortunately, four fatal...The 322 BG became the first of four initial B-26 groups to join the Eighth AF’s Third Bombardment Wing. With its first aircraft arriving in England...AF refused the suggestion. Marauders continued in the medium bombing role.101 In October 1943, the AAF transferred all four B-26 groups in

  6. Target and beam-target spin asymmetries in exclusive pion electroproduction for Q2>1 GeV2 . I. e p →e π+n

    NASA Astrophysics Data System (ADS)

    Bosted, P. E.; Amaryan, M. J.; Anefalos Pereira, S.; Avakian, H.; Badui, R. A.; Ball, J.; Baltzell, N. A.; Battaglieri, M.; Batourine, V.; Bedlinskiy, I.; Biselli, A. S.; Briscoe, W. J.; Bültmann, S.; Burkert, V. D.; Carman, D. S.; Celentano, A.; Chandavar, S.; Charles, G.; Ciullo, G.; Clark, L.; Colaneri, L.; Cole, P. L.; Contalbrigo, M.; Crede, V.; D'Angelo, A.; De Vita, R.; Deur, A.; De Sanctis, E.; Djalali, C.; Dupre, R.; Egiyan, H.; El Alaoui, A.; El Fassi, L.; Elouadrhiri, L.; Eugenio, P.; Fanchini, E.; Fedotov, G.; Filippi, A.; Fleming, J. A.; Forest, T.; Fradi, A.; Gevorgyan, N.; Ghandilyan, Y.; Gilfoyle, G. P.; Girod, F. X.; Gleason, C.; Gohn, W.; Golovatch, E.; Gothe, R. W.; Griffioen, K. A.; Guidal, M.; Hakobyan, H.; Hattawy, M.; Hicks, K.; Holtrop, M.; Hughes, S. M.; Ilieva, Y.; Ireland, D. G.; Ishkhanov, B. S.; Isupov, E. L.; Jiang, H.; Jo, H. S.; Joo, K.; Joosten, S.; Khachatryan, G.; Khandaker, M.; Kim, A.; Kim, W.; Klein, F. J.; Koirala, S.; Kubarovsky, V.; Kuhn, S. E.; Lanza, L.; Net, L. A.; Lenisa, P.; Livingston, K.; MacGregor, I. J. D.; McCracken, M. E.; McKinnon, B.; Meyer, C. A.; Mirazita, M.; Mokeev, V. I.; Montgomery, R. A.; Munevar, E.; Munoz Camacho, C.; Murdoch, G.; Nadel-Turonski, P.; Niccolai, S.; Osipenko, M.; Ostrovidov, A. I.; Park, K.; Pasyuk, E.; Peng, P.; Phelps, W.; Pisano, S.; Pogorelko, O.; Price, J. W.; Prok, Y.; Protopopescu, D.; Puckett, A. J. R.; Raue, B. A.; Ripani, M.; Rosner, G.; Rossi, P.; Schumacher, R. A.; Seder, E.; Skorodumina, Iu.; Smith, G. D.; Sokhan, D.; Sparveris, N.; Stankovic, I.; Stepanyan, S.; Strakovsky, I. I.; Strauch, S.; Taiuti, M.; Tian, Ye; Torayev, B.; Ungaro, M.; Voskanyan, H.; Voutier, E.; Walford, N. K.; Wei, X.; Weinstein, L. B.; Zachariou, N.; Zhang, J.; Zhao, Z. W.; Zonta, I.; CLAS Collaboration

    2017-03-01

    Beam-target double-spin asymmetries and target single-spin asymmetries were measured for the exclusive π+ electroproduction reaction γ*p →n π+ . The results were obtained from scattering of 6-GeV longitudinally polarized electrons off longitudinally polarized protons using the CEBAF Large Acceptance Spectrometer at Jefferson Laboratory. The kinematic range covered is 1.1 <W <3 GeV and 1 W , Q2, cos(θ*) , and ϕ*. Except at forward angles, very large target-spin asymmetries are observed over the entire W region. Reasonable agreement is found with phenomenological fits to previous data for W <1.6 GeV, but very large differences are seen at higher values of W . A generalized parton distributions (GPD)-based model is in poor agreement with the data. When combined with cross-sectional measurements, the present results provide powerful constraints on nucleon resonance amplitudes at moderate and large values of Q2, for resonances with masses as high as 2.4 GeV.

  7. Target and beam-target spin asymmetries in exclusive pion electroproduction for Q 2 > 1 GeV 2 . I. e p → e π + n

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Bosted, P. E.; Amaryan, M. J.; Anefalos Pereira, S.

    2017-03-20

    Beam-target double-spin asymmetries and target single-spin asymmetries were measured for the exclusive π+ electroproduction reaction γ*p → nπ +. The results were obtained from scattering of 6-GeV longitudinally polarized electrons off longitudinally polarized protons using the CEBAF Large Acceptance Spectrometer at Jefferson Laboratory. The kinematic range covered is 1.1 < W < 3 GeV and 1 < Q 2 < 6GeV 2. Results were obtained for about 6000 bins in W, Q 2, cos(θ*), and Φ*. Except at forward angles, very large target-spin asymmetries are observed over the entire W region. Reasonable agreement is found with phenomenological fits to previousmore » data for W < 1.6 GeV, but very large differences are seen at higher values of W. Finally, a generalized parton distributions (GPD)-based model is in poor agreement with the data. When combined with cross-sectional measurements, the present results provide powerful constraints on nucleon resonance amplitudes at moderate and large values of Q 2, for resonances with masses as high as 2.4 GeV.« less

  8. Tuning Gene Activity by Inducible and Targeted Regulation of Gene Expression in Minimal Bacterial Cells.

    PubMed

    Mariscal, Ana M; Kakizawa, Shigeyuki; Hsu, Jonathan Y; Tanaka, Kazuki; González-González, Luis; Broto, Alicia; Querol, Enrique; Lluch-Senar, Maria; Piñero-Lambea, Carlos; Sun, Lijie; Weyman, Philip D; Wise, Kim S; Merryman, Chuck; Tse, Gavin; Moore, Adam J; Hutchison, Clyde A; Smith, Hamilton O; Tomita, Masaru; Venter, J Craig; Glass, John I; Piñol, Jaume; Suzuki, Yo

    2018-05-22

    Functional genomics studies in minimal mycoplasma cells enable unobstructed access to some of the most fundamental processes in biology. Conventional transposon bombardment and gene knockout approaches often fail to reveal functions of genes that are essential for viability, where lethality precludes phenotypic characterization. Conditional inactivation of genes is effective for characterizing functions central to cell growth and division, but tools are limited for this purpose in mycoplasmas. Here we demonstrate systems for inducible repression of gene expression based on clustered regularly interspaced short palindromic repeats-mediated interference (CRISPRi) in Mycoplasma pneumoniae and synthetic Mycoplasma mycoides, two organisms with reduced genomes actively used in systems biology studies. In the synthetic cell, we also demonstrate inducible gene expression for the first time. Time-course data suggest rapid kinetics and reversible engagement of CRISPRi. Targeting of six selected endogenous genes with this system results in lowered transcript levels or reduced growth rates that agree with lack or shortage of data in previous transposon bombardment studies, and now produces actual cells to analyze. The ksgA gene encodes a methylase that modifies 16S rRNA, rendering it vulnerable to inhibition by the antibiotic kasugamycin. Targeting the ksgA gene with CRISPRi removes the lethal effect of kasugamycin and enables cell growth, thereby establishing specific and effective gene modulation with our system. The facile methods for conditional gene activation and inactivation in mycoplasmas open the door to systematic dissection of genetic programs at the core of cellular life.

  9. DOR activation inhibits anoxic/ischemic Na+ influx through Na+ channels via PKC mechanisms in the cortex.

    PubMed

    Chao, Dongman; He, Xiaozhou; Yang, Yilin; Bazzy-Asaad, Alia; Lazarus, Lawrence H; Balboni, Gianfranco; Kim, Dong H; Xia, Ying

    2012-08-01

    Activation of delta-opioid receptors (DOR) is neuroprotective against hypoxic/ischemic injury in the cortex, which is at least partially related to its action against hypoxic/ischemic disruption of ionic homeostasis that triggers neuronal injury. Na(+) influx through TTX-sensitive voltage-gated Na(+) channels may be a main mechanism for hypoxia-induced disruption of K(+) homeostasis, with DOR activation attenuating the disruption of ionic homeostasis by targeting voltage-gated Na(+) channels. In the present study we examined the role of DOR in the regulation of Na(+) influx in anoxia and simulated ischemia (oxygen-glucose deprivation) as well as the effect of DOR activation on the Na(+) influx induced by a Na(+) channel opener without anoxic/ischemic stress and explored a potential PKC mechanism underlying the DOR action. We directly measured extracellular Na(+) activity in mouse cortical slices with Na(+) selective electrodes and found that (1) anoxia-induced Na(+) influx occurred mainly through TTX-sensitive Na(+) channels; (2) DOR activation inhibited the anoxia/ischemia-induced Na(+) influx; (3) veratridine, a Na(+) channel opener, enhanced the anoxia-induced Na(+) influx; this could be attenuated by DOR activation; (4) DOR activation did not reduce the anoxia-induced Na(+) influx in the presence of chelerythrine, a broad-spectrum PKC blocker; and (5) DOR effects were blocked by PKCβII peptide inhibitor, and PKCθ pseudosubstrate inhibitor, respectively. We conclude that DOR activation inhibits anoxia-induced Na(+) influx through Na(+) channels via PKC (especially PKCβII and PKCθ isoforms) dependent mechanisms in the cortex. Copyright © 2012 Elsevier Inc. All rights reserved.

  10. Novel Therapeutic Target for the Treatment of Lupus

    DTIC Science & Technology

    2014-09-01

    AWARD NUMBER: W81XWH-12-1-0205 TITLE: Novel Therapeutic Target for the Treatment of Lupus PRINCIPAL INVESTIGATOR: Lisa Laury-Kleintop...SUBTITLE 5a. CONTRACT NUMBER Novel Therapeutic Target for the Treatment of Lupus 5b. GRANT NUMBER W81XWH-12-1-0205 5c. PROGRAM ELEMENT NUMBER 6...Systemic lupus erythematosus, autoantibodies. 16. SECURITY CLASSIFICATION OF: 17. LIMITATION OF ABSTRACT 18. NUMBER OF PAGES 7 19a. NAME OF

  11. Targeting Histone Abnormality in Triple Negative Breast Cancer

    DTIC Science & Technology

    2015-08-01

    Casero RA, Davidson NE. Molecular mechanisms of polyamine analogues in cancer cells. Anti - Cancer Drugs, 16(3): 229-241, 2005. PMID: 15711175 18 3...1 AWARD NUMBER: W81XWH-14-1-0237 TITLE: Targeting Histone Abnormality in Triple-Negative Breast Cancer PRINCIPAL INVESTIGATOR: Yi...TITLE AND SUBTITLE 5a. CONTRACT NUMBER Targeting Histone Abnormality in Triple-Negative Breast Cancer 5b. GRANT NUMBER W81XWH-14-1-0237 5c

  12. 24Mg(p, α) 21Na reaction study for spectroscopy of 21Na

    DOE PAGES

    Cha, S. M.; Chae, K. Y.; Kim, A.; ...

    2015-11-03

    The Mg-24(p, alpha)Na-21 reaction was measured at the Holifield Radioactive Ion Beam Facility at Oak Ridge National Laboratory in order to better constrain the spins and parities of the energy levels in Na-21 for the astrophysically important F-17(alpha, p)Ne-20 reaction rate calculation. 31-MeV proton beams from the 25-MV tandem accelerator and enriched Mg-24 solid targets were used. When recoiling He-4 particles from the Mg-24(p, alpha)Na-21 reaction we used a highly segmented silicon detector array to detect them; it measured the yields of He-4 particles over a range of angles simultaneously. A observed a new level at 6661 ± 5 keVmore » in the present work. The extracted angular distributions for the first four levels of Na-21 and the results from distorted wave Born approximation (DWBA) calculations were compared to verify and extract the angular momentum transfer.« less

  13. Ultra-high brightness wavelength-stabilized kW-class fiber coupled diode laser

    NASA Astrophysics Data System (ADS)

    Huang, Robin K.; Chann, Bien; Glenn, John D.

    2011-03-01

    TeraDiode has produced a fiber-coupled direct diode laser with a power level of 1,040 W from a 200 μm core diameter, 0.18 numerical aperture (NA) output fiber at a single center wavelength. This was achieved with a novel beam combining and shaping technique using COTS diode lasers. The fiber-coupled output corresponds to a Beam Parameter Product (BPP) of 18 mm-mrad and is the lowest BPP kW-class direct diode laser yet reported. The laser has been used to demonstrate laser cutting and welding of steel sheet metal up to 6.65 mm thick. Further advances of these ultra-bright lasers are also projected.

  14. Alkalis in Coal and Coal Cleaning Products / Alkalia W Węglu I Productach Jego Wzbogacania

    NASA Astrophysics Data System (ADS)

    Bytnar, Krzysztof; Burmistrz, Piotr

    2013-09-01

    In the coking process, the prevailing part of the alkalis contained in the coal charge goes to coke. The content of alkalis in coal (and also in coke) is determined mainly by the content of two elements: sodium and potasium. The presence of these elements in coal is connected with their occurrence in the mineral matter and moisture of coal. In the mineral matter and moisture of the coals used for the coke production determinable the content of sodium is 26.6 up to 62. per cent, whereas that of potassium is 37.1 up to 73.4 per cent of the total content of alkalis. Major carriers of alkalis are clay minerals. Occasionally alkalis are found in micas and feldspars. The fraction of alkalis contained in the moisture of the coal used for the production of coke in the total amount of alkalis contained there is 17.8 up to 62.0 per cent. The presence of sodium and potassium in the coal moisture is strictly connected with the presence of the chloride ions. The analysis of the water drained during process of the water-extracting from the flotoconcentrate showed that the Na to K mass ratio in the coal moisture is 20:1. Increased amount of the alkalis in the coal blends results in increased content of the alkalis in coke. This leads to the increase of the reactivity (CRI index), and to the decrease of strength (CSR index) determined with the Nippon Steel Co. method. W procesie koksowania przeważająca część zawartych we wsadzie węglowym alkaliów przechodzi do koksu. Zawartość alkaliów w węglu, a co za tym idzie i w koksie determinowana jest głównie zawartością dwóch pierwiastków: sodu i potasu. Obecność tych pierwiastków w węglu wiąże się z występowaniem ich w substancji mineralnej i wilgoci węgla. W substancji mineralnej oraz wilgoci węgli stosowanych do produkcji koksu, oznaczona zawartość sodu wynosi od 26.6 do 62.9%, a zawartość potasu od 37.1 do 73.4% alkaliów ogółem. Głównymi nośnikami alkaliów w substancji mineralnej są minera

  15. High-Flux Neutron Generator Facility for Geochronology and Nuclear Physics Research

    NASA Astrophysics Data System (ADS)

    Waltz, Cory; HFNG Collaboration

    2015-04-01

    A facility based on a next-generation, high-flux D-D neutron generator (HFNG) is being commissioned at UC Berkeley. The generator is designed to produce monoenergetic 2.45 MeV neutrons at outputs exceeding 1011 n/s. The HFNG is designed around two RF-driven multi-cusp ion sources that straddle a titanium-coated copper target. D + ions, accelerated up to 150 keV from the ion sources, self-load the target and drive neutron generation through the d(d,n)3 He fusion reaction. A well-integrated cooling system is capable of handling beam power reaching 120 kW impinging on the target. The unique design of the HFNG target permits experimental samples to be placed inside the target volume, allowing the samples to receive the highest neutron flux (1011 cm-2 s-1) possible from the generator. In addition, external beams of neutrons will be available simultaneously, ranging from thermal to 2.45 MeV. Achieving the highest neutron yields required carefully designed schemes to mitigate back-streaming of high energy electrons liberated from the cathode target by deuteron bombardment. The proposed science program is focused on pioneering advances in the 40 Ar/39 Ar dating technique for geochronology, new nuclear data measurements, basic nuclear science, and education. An end goal is to become a user facility for researchers. This work is supported by NSF Grant No. EAR-0960138, U.S. DOE LBNL Contract No. DE-AC02-05CH11231, U.S. DOE LLNL Contract No. DE-AC52-07NA27344, and UC Office of the President Award 12-LR-238745.

  16. Capture of shrinking targets with realistic shrink patterns.

    PubMed

    Hoffmann, Errol R; Chan, Alan H S; Dizmen, Coskun

    2013-01-01

    Previous research [Hoffmann, E. R. 2011. "Capture of Shrinking Targets." Ergonomics 54 (6): 519-530] reported experiments for capture of shrinking targets where the target decreased in size at a uniform rate. This work extended this research for targets having a shrink-size versus time pattern that of an aircraft receding from an observer. In Experiment 1, the time to capture the target in this case was well correlated in terms of Fitts' index of difficulty, measured at the time of capture of the target, a result that is in agreement with the 'balanced' model of Johnson and Hart [Johnson, W. W., and Hart, S. G. 1987. "Step Tracking Shrinking Targets." Proceedings of the human factors society 31st annual meeting, New York City, October 1987, 248-252]. Experiment 2 measured the probability of target capture for varying initial target sizes and target shrink rates constant, defined as the time for the target to shrink to half its initial size. Data of shrink time constant for 50% probability of capture were related to initial target size but did not greatly affect target capture as the rate of target shrinking decreased rapidly with time.

  17. Argon hollow cathode. M.S. Thesis; [propellants for ion bombardment thrusters

    NASA Technical Reports Server (NTRS)

    Rehn, L. A.

    1976-01-01

    An interest in alternate propellants for ion-bombardment thrusters, together with ground applications of this technology, has prompted consideration of argon. Several variations of conventional hollow cathode designs were tried, but the bulk of the testing used a hollow tube with an internal tungsten emitter and an orifice at one end. The optimum cathode tube diameter was found to be in the range of 1.0-2.5 cm, somewhat larger than those used for cesium and mercury. Optimum orifice diameter depended on operating conditions, and varied from 0.5 to 5 mm. Biasing the internal emitter negative relative to the cathode chamber reduced the external coupling voltage and should therefore improve orifice lifetime. The expected effect of this bias on emitter lifetime was less clear. Lifetime tests were not conducted as part of this investigation, but several designs show promise of long lifetime in specific applications.

  18. Comet impacts and chemical evolution on the bombarded earth

    NASA Technical Reports Server (NTRS)

    Oberbeck, Verne R.; Aggarwal, Hans

    1992-01-01

    Amino acids yields for previously published shock tube experiments are used with minimum Cretaceous-Tertiary (K/T) impactor mass and comet composition to predict AIB amino acid K/T boundary sediment column density. The inferred initial concentration of all amino acids in the K/T sea and in similar primordial seas just after 10 km comet impacts would have been at least 10 exp -7 M. However, sinks for amino acids must also be considered in calculating amino acid concentrations after comet impacts and in assessing the contribution of comets to the origin of life. The changing concentration of cometary amino acids due to ultraviolet light is compared with the equilibrium concentration of amino acids produced in the sea from corona discharge in the atmosphere, deposition in water, and degradation by ultraviolet light. Comets could have been more important than endogenous agents for initial evolution of amino acids. Sites favorable for chemical evolution of amino acids are examined, and it is concluded that chemical evolution could have occurred at or above the surface even during periods of intense bombardment of earth before 3.8 billion years ago.

  19. Target and beam-target spin asymmetries in exclusive pion electroproduction for Q 2 > 1 GeV 2 . II. e p → e π 0 p

    DOE PAGES

    Bosted, P. E.; Amaryan, M. J.; Anefalos Pereira, S.; ...

    2017-03-20

    Beam-target double-spin asymmetries and target single-spin asymmetries were measured for the exclusive π + electroproduction reaction γ*p→nπ +. The results were obtained from scattering of 6-GeV longitudinally polarized electrons off longitudinally polarized protons using the CEBAF Large Acceptance Spectrometer at Jefferson Laboratory. The kinematic range covered is 1.1 < W < 3 GeV and 1 < Q 2 < 6GeV 2. Results were obtained for about 6000 bins in W, Q 2, cos(θ*), and Φ*. Except at forward angles, very large target-spin asymmetries are observed over the entire W region. Reasonable agreement is found with phenomenological fits to previous datamore » for W < 1.6 GeV, but very large differences are seen at higher values of W. A generalized parton distributions (GPD)-based model is in poor agreement with the data. As a result, when combined with cross-sectional measurements, the present results provide powerful constraints on nucleon resonance amplitudes at moderate and large values of Q 2, for resonances with masses as high as 2.4 GeV.« less

  20. Silibinin prevents prostate cancer cell-mediated differentiation of naïve fibroblasts into cancer-associated fibroblast phenotype by targeting TGF β2.

    PubMed

    Ting, Harold J; Deep, Gagan; Jain, Anil K; Cimic, Adela; Sirintrapun, Joseph; Romero, Lina M; Cramer, Scott D; Agarwal, Chapla; Agarwal, Rajesh

    2015-09-01

    Tumor microenvironment (TM) is an essential element in prostate cancer (PCA), offering unique opportunities for its prevention. TM includes naïve fibroblasts that are recruited by nascent neoplastic lesion and altered into 'cancer-associated fibroblasts' (CAFs) that promote PCA. A better understanding and targeting of interaction between PCA cells and fibroblasts and inhibiting CAF phenotype through non-toxic agents are novel approaches to prevent PCA progression. One well-studied cancer chemopreventive agent is silibinin, and thus, we examined its efficacy against PCA cells-mediated differentiation of naïve fibroblasts into a myofibroblastic-phenotype similar to that found in CAFs. Silibinin's direct inhibitory effect on the phenotype of CAFs derived directly from PCA patients was also assessed. Human prostate stromal cells (PrSCs) exposed to control conditioned media (CCM) from human PCA PC3 cells showed more invasiveness, with increased alpha-smooth muscle actin (α-SMA) and vimentin expression, and differentiation into a phenotype we identified in CAFs. Importantly, silibinin (at physiologically achievable concentrations) inhibited α-SMA expression and invasiveness in differentiated fibroblasts and prostate CAFs directly, as well as indirectly by targeting PCA cells. The observed increase in α-SMA and CAF-like phenotype was transforming growth factor (TGF) β2 dependent, which was strongly inhibited by silibinin. Furthermore, induction of α-SMA and CAF phenotype by CCM were also strongly inhibited by a TGFβ2-neutralizing antibody. The inhibitory effect of silibinin on TGFβ2 expression and CAF-like biomarkers was also observed in PC3 tumors. Together, these findings highlight the potential usefulness of silibinin in PCA prevention through targeting the CAF phenotype in the prostate TM. © 2014 Wiley Periodicals, Inc.

  1. Investigation of the W and Q 2 dependence of charged pion distributions in μ p scattering

    NASA Astrophysics Data System (ADS)

    Arneodo, M.; Arvidson, A.; Aubert, J. J.; Badelek, B.; Beaufays, J.; Bee, C. P.; Benchouk, C.; Berghoff, G.; Bird, I.; Blum, D.; Böhm, E.; de Bouard, X.; Brasse, F. W.; Braun, H.; Broll, C.; Brown, S.; Brück, H.; Calen, H.; Chima, J. S.; Ciborowski, J.; Clifft, R.; Coignet, G.; Combley, F.; Coughlan, J.; D'Agostini, G.; Dahlgren, S.; Dengler, F.; Derado, I.; Dreyer, T.; Drees, J.; Düren, M.; Eckardt, V.; Edwards, A.; Ernst, T.; Eszes, G.; Favier, J.; Ferrero, M. I.; Figiel, J.; Flauger, W.; Foster, J.; Gabathuler, E.; Gajewski, J.; Gamet, R.; Gayler, J.; Geddes, N.; Giubellino, P.; Grafström, P.; Grard, F.; Haas, J.; Hagberg, E.; Hasert, F. J.; Hayman, P.; Heusse, P.; Hoppe, C.; Jaffré, M.; Jacholkowska, A.; Janata, F.; Jancso, G.; Johnson, A. S.; Kabuss, E. M.; Kellner, G.; Korbel, V.; Krüger, J.; Kullander, S.; Landgraf, U.; Lanske, D.; Loken, J.; Long, K.; Maire, M.; Malecki, P.; Manz, A.; Maselli, S.; Mohr, W.; Montanet, F.; Montgomery, H. E.; Nagy, E.; Nassalski, J.; Norton, P. R.; Oakham, F. G.; Osborne, A. M.; Pascaud, C.; Pawlik, B.; Payre, P.; Peroni, C.; Pessard, H.; Pettingale, J.; Pietrzyk, B.; Pönsgen, B.; Pötsch, M.; Renton, P.; Ribarics, P.; Rith, K.; Rondio, E.; Scheer, M.; Schlagböhmer, A.; Schiemann, H.; Schmitz, N.; Schneegans, M.; Scholz, M.; Schröder, T.; Schouten, M.; Schultze, K.; Sloan, T.; Stier, H. E.; Studt, M.; Taylor, G. N.; Thénard, J. M.; Thompson, J. C.; de La Torre, A.; Toth, J.; Urban, L.; Wallucks, W.; Whalley, M.; Wheeler, S.; Williams, W. S. C.; Wimpenny, S. J.; Windmolders, R.; Wolf, G.

    1986-03-01

    The W and Q 2 dependence of the fragmentation functions and of the average multiplicity of charged pions is investigated, using data from the NA9 experiment at the CERN SPS on muon-proton scattering at 280 GeV. A significant increase of pion production with increasing W is observed at fixed Q 2, leading to a rise of the average charged pion multiplicity, linear in ln W 2, and of the pion fragmentation function in the central region, i.e. at small | x F |. This increase can be understood from the kinematic widening of the cms rapidity range proportional to ln W 2 and the observed W independent height of the rapidity distribution. At fixed W, a rise of the average charged pion multiplicity with Q 2 is observed. This rise appears to be weaker than that observed for all charged hadrons implying a stronger rise with Q 2 for kaons and protons.

  2. An experimental investigation of Na incorporation in cordierite in low P/high T metapelites

    NASA Astrophysics Data System (ADS)

    Tropper, Peter; Wyhlidal, Stefan; Haefeker, Udo A.; Mirwald, Peter W.

    2018-04-01

    The aim of this experimental study was to investigate the incorporation of Na in cordierite in metapelites as a function of temperature and pressure using natural quartzphyllite rocks as starting materials. The experiments were performed in a hydrothermal apparatus as well as a piston-cylinder apparatus with two natural quartzphyllite samples, which represent the protolith rocks of the hornfelses from the Brixen Granite contact aureole near Franzensfeste. Sample W shows high muscovite contents (57 wt%) and only accessory plagioclase while sample SP5 has high plagioclase (16 wt%) and lower muscovite contents (20 vol%). The experiments were done dry at pressures of 0.15, 0.3 and 0.6 GPa in a temperature range of 550 °C to 780 °C. The Na content of the newly formed cordierites shows a systematic variation and decreases linearly with increasing temperatures and no influence of pressure and melting on the Na contents of cordierite was observed. The experiments also show that the difference in mineral assemblage considerably shifts the obtained Na contents of cordierite. The P-independent temperature correlations for both sets of experiments can be described with the linear relationships: T (°C) = (Na [apfu] - 0.4052)/(-0.000487); R2 = 0.96; (±20 °C, calibration W) and T (°C) = (Na [apfu] - 0.3671)/(-0.000383); R2 = 0.94; (±15 °C, calibration SP5). The difference between the two temperatures is large and the SP5 experiments yield temperatures that are up to 100 °C higher. This is not unexpected since theoretical phase relations in the system NMASH predict different Na contents depending on the buffering assemblage (plagioclase vs. paragonite). On the other hand these T differences could also reflect disequilibrium behaviour in the SP5 experiments. Detailed micro-Raman spectroscopic investigations reveal that cordierites from both experiments show disordered structures but the SP5 experiments show a much higher degree of Si-Al disorder and the elevated Na

  3. Electron linear accelerator production and purification of scandium-47 from titanium dioxide targets.

    PubMed

    Rotsch, David A; Brown, M Alex; Nolen, Jerry A; Brossard, Thomas; Henning, Walter F; Chemerisov, Sergey D; Gromov, Roman G; Greene, John

    2018-01-01

    The photonuclear production of no-carrier-added (NCA) 47 Sc from solid Nat TiO 2 and the subsequent chemical processing and purification have been developed. Scandium-47 was produced by the 48 Ti(γ,p) 47 Sc reaction with Bremsstrahlung photons produced from the braking of electrons in a high-Z (W or Ta) convertor. Production yields were simulated with the PHITS code (Particle and Heavy Ion Transport-code System) and compared to experimental results. Irradiated TiO 2 targets were dissolved in fuming H 2 SO 4 in the presence of Na 2 SO 4 and 47 Sc was purified using the commercially available Eichrom DGA resin. Typical 47 Sc recovery yields were >90% with excellent specific activity for small batches (<185 MBq batches). Copyright © 2017 Elsevier Ltd. All rights reserved.

  4. Electron linear accelerator production and purification of scandium-47 from titanium dioxide targets

    DOE PAGES

    Rotsch, David A.; Brown, M. Alex; Nolen, Jerry A.; ...

    2017-11-06

    Here, the photonuclear production of no-carrier-added (NCA) 47Sc from solid NatTiO 2 and the subsequent chemical processing and purification have been developed. Scandium-47 was produced by the 48Ti(γ,p) 47Sc reaction with Bremsstrahlung photons produced from the braking of electrons in a high-Z (W or Ta) convertor. Production yields were simulated with the PHITS code (Particle and Heavy Ion Transport-code System) and compared to experimental results. Irradiated TiO 2 targets were dissolved in fuming H 2SO 4 in the presence of Na 2SO 4 and 47Sc was purified using the commercially available Eichrom DGA resin. Typical 47Sc recovery yields were >90%more » with excellent specific activity for small batches (<185 MBq batches).« less

  5. Electron linear accelerator production and purification of scandium-47 from titanium dioxide targets

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Rotsch, David A.; Brown, M. Alex; Nolen, Jerry A.

    Here, the photonuclear production of no-carrier-added (NCA) 47Sc from solid NatTiO 2 and the subsequent chemical processing and purification have been developed. Scandium-47 was produced by the 48Ti(γ,p) 47Sc reaction with Bremsstrahlung photons produced from the braking of electrons in a high-Z (W or Ta) convertor. Production yields were simulated with the PHITS code (Particle and Heavy Ion Transport-code System) and compared to experimental results. Irradiated TiO 2 targets were dissolved in fuming H 2SO 4 in the presence of Na 2SO 4 and 47Sc was purified using the commercially available Eichrom DGA resin. Typical 47Sc recovery yields were >90%more » with excellent specific activity for small batches (<185 MBq batches).« less

  6. LONG-LIVED ALUMINUM-26 (thesis)

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Rightmire, R.A.

    1957-06-01

    Theoretical and experimental evidence has indicated a level in Al/sup 26/ below the 6 sec 0/sup +/ level. The ground state lies 4.01 plus or minus 0.02 Mev above that of Mg/sup 26/, has 5/sup +/ con figuration, and evidently is very long-lived. Al/sup 26/ and Na/sup 22/ are produced simultaneously by deuteron and proton bombardment of magnesium targets. Chemical procedures for isolating each nuclide in carrier-free and radiochemically pure state were developed. The maximum positron energy of the long-lived ground state of Al/sup 26/ was determined to be 1.16 plus or minus 0.02 Mev. The scintillation gamma spectrum showsmore » four full-energy peaks. The most intense, at 0.51 Mev, is due to positron annihilation. A strong peak at 1.83 Mev and two weak peaks at 1.14 and 2.97 Mev correspond to transitions from the known Mg/sup 26/ first and second excited states. The relative intensities of the annihilation and gamma radiations indicate that Al/sup 26/ undergoes 85.5 plus or minus 1.8% positron emission to the 1.83 Mev state of Mg/sup 26/; 11.5 P 1.9% electron capture to the same state; 3.7 plus or minus 0.3% electron capture to the 2.97 Mev state followed by emmission of 1.14 and 1.83 Mev gamma rays; 0.30 plus or minus 0.06% electron capture to the same state followed by 2.97 Mev radiation. The resulting disintegration scheme is shown. Thick target bombardment yields of natural magnesium with 16-Mev deuterons were determined to be: Al/sup 26/, (1.4 plus or minus 0.13) dis/min/ mu ah; Na/sup 22/, (4.6 plus or minus 0.3) x 10/sup 6/ ds/ mia/ mu ah. Yields using 20.8 Mev protons gave: Al/sup 26/, (3.5 plus or minus 0.4) ds/min/ mu ah; Na/sup 22/, (1.92 plus or minus 0.19) x 10/sup 6/ ds/min/ mu ah. A total of 2300 plus or minus 300 dis/min of Al/sup 26/ was isolated from an aluminum sheet exposed to 8 x 10/sup 20/ neutrons/cm/sup 2/ in a reactor. The halflife of Al/sup 26/ was estimated at 1 x 10/sup 6/ yrs from the ratio of Al/sup 26/ activity to Nazi activity. A

  7. wALADin Benzimidazoles Differentially Modulate the Function of Porphobilinogen Synthase Orthologs

    PubMed Central

    2015-01-01

    The heme biosynthesis enzyme porphobilinogen synthase (PBGS) is a potential drug target in several human pathogens. wALADin1 benzimidazoles have emerged as species-selective PBGS inhibitors against Wolbachia endobacteria of filarial worms. In the present study, we have systematically tested wALADins against PBGS orthologs from bacteria, protozoa, metazoa, and plants to elucidate the inhibitory spectrum. However, the effect of wALADin1 on different PBGS orthologs was not limited to inhibition: several orthologs were stimulated by wALADin1; others remained unaffected. We demonstrate that wALADins allosterically modulate the PBGS homooligomeric equilibrium with inhibition mediated by favoring low-activity oligomers, while 5-aminolevulinic acid, Mg2+, or K+ stabilized high-activity oligomers. Pseudomonas aeruginosa PBGS could be inhibited or stimulated by wALADin1 depending on these factors and pH. We have defined the wALADin chemotypes responsible for either inhibition or stimulation, facilitating the design of tailored PBGS modulators for potential application as antimicrobial agents, herbicides, or drugs for porphyric disorders. PMID:24568185

  8. Acquisition, Conservation, and Loss of Dual-Targeted Proteins in Land Plants1[W][OA

    PubMed Central

    Xu, Lin; Carrie, Chris; Law, Simon R.; Murcha, Monika W.; Whelan, James

    2013-01-01

    The dual-targeting ability of a variety of proteins from Physcomitrella patens, rice (Oryza sativa), and Arabidopsis (Arabidopsis thaliana) was tested to determine when dual targeting arose and to what extent it was conserved in land plants. Overall, the targeting ability of over 80 different proteins from rice and P. patens, representing 42 dual-targeted proteins in Arabidopsis, was tested. We found that dual targeting arose early in land plant evolution, as it was evident in many cases with P. patens proteins that were conserved in rice and Arabidopsis. Furthermore, we found that the acquisition of dual-targeting ability is still occurring, evident in P. patens as well as rice and Arabidopsis. The loss of dual-targeting ability appears to be rare, but does occur. Ascorbate peroxidase represents such an example. After gene duplication in rice, individual genes encode proteins that are targeted to a single organelle. Although we found that dual targeting was generally conserved, the ability to detect dual-targeted proteins differed depending on the cell types used. Furthermore, it appears that small changes in the targeting signal can result in a loss (or gain) of dual-targeting ability. Overall, examination of the targeting signals within this study did not reveal any clear patterns that would predict dual-targeting ability. The acquisition of dual-targeting ability also appears to be coordinated between proteins. Mitochondrial intermembrane space import and assembly protein40, a protein involved in oxidative folding in mitochondria and peroxisomes, provides an example where acquisition of dual targeting is accompanied by the dual targeting of substrate proteins. PMID:23257241

  9. Predicting the Noise of High Power Fluid Targets Using Computational Fluid Dynamics

    NASA Astrophysics Data System (ADS)

    Moore, Michael; Covrig Dusa, Silviu

    The 2.5 kW liquid hydrogen (LH2) target used in the Qweak parity violation experiment is the highest power LH2 target in the world and the first to be designed with Computational Fluid Dynamics (CFD) at Jefferson Lab. The Qweak experiment determined the weak charge of the proton by measuring the parity-violating elastic scattering asymmetry of longitudinally polarized electrons from unpolarized liquid hydrogen at small momentum transfer (Q2 = 0 . 025 GeV2). This target satisfied the design goals of < 1 % luminosity reduction and < 5 % contribution to the total asymmetry width (the Qweak target achieved 2 % or 55ppm). State of the art time dependent CFD simulations are being developed to improve the predictions of target noise on the time scale of the electron beam helicity period. These predictions will be bench-marked with the Qweak target data. This work is an essential component in future designs of very high power low noise targets like MOLLER (5 kW, target noise asymmetry contribution < 25 ppm) and MESA (4.5 kW).

  10. Pulse electrodeposition of self-lubricating Ni-W/PTFE nanocomposite coatings on mild steel surface

    NASA Astrophysics Data System (ADS)

    Sangeetha, S.; Kalaignan, G. Paruthimal; Anthuvan, J. Tennis

    2015-12-01

    Ni-W/PTFE nanocomposite coatings with various contents of PTFE (polytetafluoroethylene) particles were prepared by pulse current (PC) electrodeposition from the Ni-W plating bath containing self lubricant PTFE particles to be co-deposited. Co-deposited PTFE particulates were uniformly distributed in the Ni-W alloy matrix. The coatings were characterized by Scanning Electron Microscopy (SEM), Energy Dispersive X-Ray Analysis (EDAX), X-ray Diffractometry (XRD) and Vicker's micro hardness tester. Tafel Polarization and electrochemical Impedance methods were used to evaluate the corrosion resistance behaviour of the nanocomposite coatings in 3.5% NaCl solution. It was found that, the Ni-W/PTFE nanocomposite coating has better corrosion resistance than the Ni-W alloy coating. Surface roughness and friction coefficient of the coated samples were assessed by Mitutoyo Surftest SJ-310 (ISO1997) and Scratch tester TR-101-M4 respectively. The contact angle (CA) of a water droplet on the surface of nanocomposite coating was measured by Optical Contact Goniometry (OCA 35). These results indicated that, the addition of PTFE in the Ni-W alloy matrix has resulted moderate microhardness, smooth surface, less friction coefficient, excellent water repellency and enhanced corrosion resistance of the nanocomposite coatings.

  11. Nanocrystal Targeting In Vivo

    DTIC Science & Technology

    2002-08-01

    Shearwater Polymers , Huntsville, AL) was thiolated with iminothiolane. Thiolated PEG was directly added to a solution of mercaptoacetic acid- coated qdots...Nanocrystal targeting in vivo Maria E. Åkerman*†‡, Warren C. W. Chan†‡, Pirjo Laakkonen*, Sangeeta N. Bhatia†, and Erkki Ruoslahti*§ *Cancer Research...set out to explore the feasibility of in vivo targeting by using semiconductor quantum dots (qdots). Qdots are small (᝺ nm) inorganic nanocrystals

  12. Measurements of W Erosion using UV Emission from DIII-D and CTH

    NASA Astrophysics Data System (ADS)

    Johnson, Curtis; Ennis, David; Loch, Stuart; Balance, Connor; Victor, Brian; Allen, Steve; Samuell, Cameron; Abrams, Tyler; Unterberg, Ezekial

    2017-10-01

    of Plasma Facing Components (PFCs) will play a critical role in establishing the performance of reactor-relevant fusion devices, particularly for tungsten (W) divertor targets. Erosion can be diagnosed from spectral line emission together with atomic coefficients representing the `ionizations per photon' (S/XB). Emission from W I is most intense in the UV region. Thus, UV survey spectrometers (200-400 nm) are used to diagnose W PFCs erosion in the DIII-D divertor and from a W tipped probe in the CTH experiment. Nineteen W emission lines in the UV region are identified between the two experiments, allowing for multiple S/XB erosion measurements. Initial W erosion measurements are compared to erosion using the 400.9 nm W I line. Complete UV spectra will be presented and compared to synthetic spectra for varying plasma conditions. Analysis of the metastable states impact on the S/XB will be presented as well as possible electron temperature and density diagnosis from W I line ratios. Work supported by USDOE Grants DE-SC0015877 & DE-FC02-04ER54698.

  13. Effect of different bile salts on the relative hypoglycemia of witepsol W35 suppositories containing insulin in diabetic Beagle dogs.

    PubMed

    Hosny, E A; Al-Shora, H I; Elmazar, M M

    2001-09-01

    Insulin suppositories were formulated using Witepsol W35 as a base to investigate the effect of various bile salts/acids on the plasma glucose concentration of diabetic beagle dogs. Comparison of the effect of these formulations was made with that produced by insulin subcutaneous injections. Of the bile salts/acids studied, incorporation of 100 mg of deoxycholic acid (DCA), sodium cholate (NaC), or sodium deoxycholate (NaDC) with insulin (10 U/Kg) showed that suppositories containing NaDC produced the highest area under the curve (AUC) and relative hypoglycemia (RH) of 290 +/- 83 mg%h and 28% +/- 8.1%, respectively. To study the optimum amount of NaDC in insulin suppositories to produce the highest RH, 50-200 mg/suppository were used, and we found that 150 mg NaDC produced 35% +/- 13% RH. We also studied the influence of different doses of insulin (5-20 U/kg) in the presence of NaDC (100 mg). It was found that increase of the insulin dose was accompanied by an increase in AUC and maximum reduction in plasma glucose level Cmax. A combination of NaDC (100 mg) and NaC (50 mg) produced an AUC of 252 +/- 13mg%h and an RH of 49% +/- 2.6%, which were higher than produced by either of its individual components (NaC 50 mg or NaDC 100 mg) when used alone or when compared with an equivalent amount of NaDC (150 mg). When the effect of sodium taurocholate (NaTC) and sodium taurodeoxycholate (NaTDC) was studied, it was found that an insulin suppository containing 100 mg of either NaTC or NaTDC produced an RH equivalent to that produced previouslY with a mixture of NaDC (100 mg) and NaC (50 mg). On the other hand, NaC (50 mg) did not improve the hypoglycemic effect of NaTC any further. In conclusion, a relative hYpoglycemia of about 50% can be reached using insulin suppositories containing Witepsol W35 as a base and NaDC plus NaC (100 mg plus 50 mg, respectively), NaTDC (100mg), or NaTC (100 mg) as rectal absorption enhancers of insulin. A desirable hypoglycemia, expressed as

  14. Thermoelectric Figures of Merit of Zn4Sb3 and Zrnisn-based Half-heusler Compounds Influenced by Mev Ion-beam Bombardments

    NASA Astrophysics Data System (ADS)

    Budak, S.; Guner, S.; Muntele, C. I.; Ila, D.

    Semiconducting β-Zn4Sb3 and ZrNiSn-based half-Heusler compound thin films with applications as thermoelectric (TE) materials were prepared using ion beam assisted deposition (IBAD). High-purity solid zinc (Zn) and antimony (Sb) were evaporated by electron beam to grow the β-Zn4Sb3 thin film while high-purity zirconium (Zr) powder and nickel (Ni) tin (Sn) powders were evaporated by electron beam to grow the ZrNiSn-based half-Heusler compound thin film. Rutherford backscattering spectrometry (RBS) was used to analyze the composition of the thin films. The grown thin films were subjected to 5 MeV Si ions bombardment for generation of nanostructures in the films. We measured the thermal conductivity, Seebeck coefficient, and electrical conductivity of these two systems before and after 5 MeV Si ions beam bombardment. The two material systems have been identified as promising TE materials for the application of thermal-to-electrical energy conversion, but the efficiency still limits their applications. The electronic energy deposited due to ionization in the track of MeV ion beam couldcause localized crystallization. The nanostructures produced by MeV ion beam can cause significant change in both the electrical and the thermal conductivity of thin films, thereby improving the efficiency. We used the 3ω-method (3rd harmonic) measurement system to measure the cross-plane thermal conductivity, the van der Pauw measurement system to measure the electrical conductivity, and the Seebeck-coefficient measurement system to measure the cross-plane Seebeck coefficient. The thermoelectric figures of merit of the two material systems were then derived by calculations using the measurement results. The MeV ion-beam bombardment was found to decrease the thermal conductivity of thin films and increase the efficiency of thermal-to-electrical energy conversion.

  15. Targeting the Kinase-Independent Pro-survival Function of EGFR in Prostate Cancer

    DTIC Science & Technology

    2013-06-01

    AD AWARD NUMBER: W81XWH-09-1-0343 TITLE: Targeting the Kinase-Independent Pro -survival Function of EGFR in Prostate Cancer...SUBTITLE Targeting the Kinase-Independent, Pro -survival Function of EGFR in Prostate Cancer 5a. CONTRACT NUMBER 5b. GRANT NUMBER W81XWH-09-1...Unlimited 13. SUPPLEMENTARY NOTES 14. ABSTRACT The proposed study, targeting the kinase independent pro -survival function of EGFR in prostate

  16. Improved algorithms in the CE-QUAL-W2 water-quality model for blending dam releases to meet downstream water-temperature targets

    USGS Publications Warehouse

    Rounds, Stewart A.; Buccola, Norman L.

    2015-01-01

    Water-quality models allow water resource professionals to examine conditions under an almost unlimited variety of potential future scenarios. The two-dimensional (longitudinal, vertical) water-quality model CE-QUAL-W2, version 3.7, was enhanced and augmented with new features to help dam operators and managers explore and optimize potential solutions for temperature management downstream of thermally stratified reservoirs. Such temperature management often is accomplished by blending releases from multiple dam outlets that access water of different temperatures at different depths. The modified blending algorithm in version 3.7 of CE-QUAL-W2 allows the user to specify a time-series of target release temperatures, designate from 2 to 10 floating or fixed-elevation outlets for blending, impose minimum and maximum head and flow constraints for any blended outlet, and set priority designations for each outlet that allow the model to choose which outlets to use and how to balance releases among them. The modified model was tested with a variety of examples and against a previously calibrated model of Detroit Lake on the North Santiam River in northwestern Oregon, and the results compared well. These updates to the blending algorithms will allow more complicated dam-operation scenarios to be evaluated somewhat automatically with the model, with decreased need for multiple model runs or preprocessing of model inputs to fully characterize the operational constraints.

  17. Experimental Study on Steel Tank Model Using Shaking Table/ Badania Eksperymentalne Modelu Zbiornika Stalowego Na Stole Sejsmicznym

    NASA Astrophysics Data System (ADS)

    Burkacki, Daniel; Jankowski, Robert

    2014-09-01

    Cylindrical steel tanks are very popular structures used for storage of products of chemical and petroleum industries. Earthquakes are the most dangerous and also the most unpredictable dynamic loads acting on such structures. On the other hand, mining tremors are usually considered to be less severe due to lower acceleration levels observed. The aim of the present paper is to show the results of the experimental study which has been conducted on a scaled model of a real tank located in Poland. The investigation has been carried out under different dynamic excitations (earthquakes and mining tremors) using the shaking table. The results of the study indicate that stored product may significantly influence the values of dynamic parameters and confirm that the level of liquid filling is really essential in the structural analysis. The comparison of the response under moderate earthquakes and mining tremors indicate that the second excitation may be more severe in some cases. Stalowe zbiorniki walcowe są bardzo popularnymi konstrukcjami używanymi do magazynowania produktów przemysłu chemicznego i naftowego. Ich bezpieczeństwo i niezawodność są kluczowe, ponieważ każde uszkodzenie może nieść za sobą bardzo poważne konsekwencje. Trzęsienia ziemi są najbardziej niebezpiecznymi, a zarazem najbardziej nieprzewidywalnymi obciążeniami dynamicznymi, które mogą oddziaływać na tego typu konstrukcje. Z drugiej strony ruchy podłoża związane ze wstrząsami górniczymi są uważane za mniej groźne z powodu osiągania niższych poziomów wartości przyspieszeń. Celem niniejszego artykułu jest przedstawienie wyników badań eksperymentalnych, które przeprowadzono na wykonanym w skali modelu rzeczywistego zbiornika zlokalizowanego na terenie Polski. Badania wykonano przy użyciu stołu sejsmicznego. Zakres badań obejmował testy harmoniczne właściwości dynamicznych oraz zachowanie się stalowego zbiornika walcowego podczas trzęsień ziemi oraz wstrząsów

  18. Status of Kilowatt-Class Stirling Power Conversion Using a Pumped NaK Loop for Thermal Input

    NASA Technical Reports Server (NTRS)

    Briggs, Maxwell H.; Geng, Steven M.; Robbie, Malcolm G.

    2010-01-01

    Free-piston Stirling power conversion has been identified as a viable option for potential Fission Surface Power (FSP) systems on the Moon and Mars. Proposed systems consist of two or more Stirling convertors, in a dual-opposed configuration, coupled to a low-temperature uranium-dioxide-fueled, liquid-metal-cooled reactor. To reduce developmental risks associated with liquid-metal loop integration, a test rig has been built to evaluate the performance of a pair of 1-kW free-piston Stirling convertors using a pumped sodium-potassium (NaK) loop for thermal energy input. Baseline performance maps have been generated at the Glenn Research Center (GRC) for these 1-kW convertors operating with an electric heat source. Each convertor was then retrofitted with a custom-made NaK heater head and integrated into a pumped NaK system at the Marshall Space Flight Center (MSFC). This paper documents baseline testing at GRC as well as the progress made in integrating the Stirling convertors into the pumped NaK loop.

  19. Control of the wrinkle structure on surface-reformed poly(dimethylsiloxane) via ion-beam bombardment

    NASA Astrophysics Data System (ADS)

    Park, Hong-Gyu; Jeong, Hae-Chang; Jung, Yoon Ho; Seo, Dae-Shik

    2015-07-01

    We investigated the surface reformation of poly(dimethylsiloxane) (PDMS) elastomers by means of ion beam bombardment for fabricating wrinkle structures. Oxidation on the PDMS surface formed a silica-like outer layer that interacted with the inner PDMS layer, leading to the formation of wrinkle structures that minimized the combined bending energy of the outer layer and stretching energy of the inner layer. In addition, we controlled the amplitude and period of the wrinkle structures by adjusting the PDMS annealing temperature. As the PDMS annealing temperature was increased, the amplitude and period of the wrinkles formed by IB irradiation changed from 604.35 to 69.01 nm and from 3.07 to 0.80 μm, respectively.

  20. Spallation yield of neutrons produced in thick lead target bombarded with 250 MeV protons

    NASA Astrophysics Data System (ADS)

    Chen, L.; Ma, F.; Zhanga, X. Y.; Ju, Y. Q.; Zhang, H. B.; Ge, H. L.; Wang, J. G.; Zhou, B.; Li, Y. Y.; Xu, X. W.; Luo, P.; Yang, L.; Zhang, Y. B.; Li, J. Y.; Xu, J. K.; Liang, T. J.; Wang, S. L.; Yang, Y. W.; Gu, L.

    2015-01-01

    The neutron yield from thick target of Pb irradiated with 250 MeV protons has been studied experimentally. The neutron production was measured with the water-bath gold method. The thermal neutron distributions in the water were determined according to the measured activities of Au foils. Corresponding results calculated with the Monte Carlo code MCNPX were compared with the experimental data. It was found out that the Au foils with cadmium cover significantly changed the spacial distribution of the thermal neutron field. The corrected neutron yield was deduced to be 2.23 ± 0.19 n/proton by considering the influence of the Cd cover on the thermal neutron flux.

  1. Crystal structures of human cholinesterases in complex with huprine W and tacrine: elements of specificity for anti-Alzheimer's drugs targeting acetyl- and butyryl-cholinesterase.

    PubMed

    Nachon, Florian; Carletti, Eugénie; Ronco, Cyril; Trovaslet, Marie; Nicolet, Yvain; Jean, Ludovic; Renard, Pierre-Yves

    2013-08-01

    The multifunctional nature of Alzheimer's disease calls for MTDLs (multitarget-directed ligands) to act on different components of the pathology, like the cholinergic dysfunction and amyloid aggregation. Such MTDLs are usually on the basis of cholinesterase inhibitors (e.g. tacrine or huprine) coupled with another active molecule aimed at a different target. To aid in the design of these MTDLs, we report the crystal structures of hAChE (human acetylcholinesterase) in complex with FAS-2 (fasciculin 2) and a hydroxylated derivative of huprine (huprine W), and of hBChE (human butyrylcholinesterase) in complex with tacrine. Huprine W in hAChE and tacrine in hBChE reside in strikingly similar positions highlighting the conservation of key interactions, namely, π-π/cation-π interactions with Trp86 (Trp82), and hydrogen bonding with the main chain carbonyl of the catalytic histidine residue. Huprine W forms additional interactions with hAChE, which explains its superior affinity: the isoquinoline moiety is associated with a group of aromatic residues (Tyr337, Phe338 and Phe295 not present in hBChE) in addition to Trp86; the hydroxyl group is hydrogen bonded to both the catalytic serine residue and residues in the oxyanion hole; and the chlorine substituent is nested in a hydrophobic pocket interacting strongly with Trp439. There is no pocket in hBChE that is able to accommodate the chlorine substituent.

  2. A novel W1999S mutation and non-target site resistance impact on acetyl-CoA carboxylase inhibiting herbicides to varying degrees in a UK Lolium multiflorum population.

    PubMed

    Kaundun, Shiv Shankhar; Bailly, Geraldine C; Dale, Richard P; Hutchings, Sarah-Jane; McIndoe, Eddie

    2013-01-01

    Acetyl-CoA carboxylase (ACCase) inhibiting herbicides are important products for the post-emergence control of grass weed species in small grain cereal crops. However, the appearance of resistance to ACCase herbicides over time has resulted in limited options for effective weed control of key species such as Lolium spp. In this study, we have used an integrated biological and molecular biology approach to investigate the mechanism of resistance to ACCase herbicides in a Lolium multiflorum Lam. from the UK (UK21). The study revealed a novel tryptophan to serine mutation at ACCase codon position 1999 impacting on ACCase inhibiting herbicides to varying degrees. The W1999S mutation confers dominant resistance to pinoxaden and partially recessive resistance to cycloxydim and sethoxydim. On the other hand, plants containing the W1999S mutation were sensitive to clethodim and tepraloxydim. Additionally population UK21 is characterised by other resistance mechanisms, very likely non non-target site based, affecting several aryloxyphenoxyproprionate (FOP) herbicides but not the practical field rate of pinoxaden. The positive identification of wild type tryptophan and mutant serine alleles at ACCase position 1999 could be readily achieved with an original DNA based derived cleaved amplified polymorphic sequence (dCAPS) assay that uses the same PCR product but two different enzymes for positively identifying the wild type tryptophan and mutant serine alleles identified here. This paper highlights intrinsic differences between ACCase inhibiting herbicides that could be exploited for controlling ryegrass populations such as UK21 characterised by compound-specific target site and non-target site resistance.

  3. Rebmab200, a humanized monoclonal antibody targeting the sodium phosphate transporter NaPi2b displays strong immune mediated cytotoxicity against cancer: a novel reagent for targeted antibody therapy of cancer.

    PubMed

    Lopes dos Santos, Mariana; Yeda, Fernanda Perez; Tsuruta, Lilian Rumi; Horta, Bruno Brasil; Pimenta, Alécio A; Degaki, Theri Leica; Soares, Ibere C; Tuma, Maria Carolina; Okamoto, Oswaldo Keith; Alves, Venancio A F; Old, Lloyd J; Ritter, Gerd; Moro, Ana Maria

    2013-01-01

    NaPi2b, a sodium-dependent phosphate transporter, is highly expressed in ovarian carcinomas and is recognized by the murine monoclonal antibody MX35. The antibody had shown excellent targeting to ovarian cancer in several early phase clinical trials but being murine the antibody's full therapeutic potential could not be explored. To overcome this impediment we developed a humanized antibody version named Rebmab200, expressed in human PER.C6® cells and cloned by limiting dilution. In order to select a clone with high therapeutic potential clones were characterized using a series of physicochemical assays, flow cytometry, real-time surface plasmon resonance, glycosylation analyses, immunohistochemistry, antibody-dependent cell-mediated cytotoxicity, complement-dependent-cytotoxicity assays and quantitative PCR. Comparative analyses of Rebmab200 and MX35 monoclonal antibodies demonstrated that the two antibodies had similar specificity for NaPi2b by flow cytometry with a panel of 30 cell lines and maintained similar kinetic parameters. Robust and high producer cell clones potentially suitable for use in manufacturing were obtained. Rebmab200 antibodies were assessed by immunohistochemistry using a large panel of tissues including human carcinomas of ovarian, lung, kidney and breast origin. An assessment of its binding towards 33 normal human organs was performed as well. Rebmab200 showed selected strong reactivity with the tested tumor types but little or no reactivity with the normal tissues tested confirming its potential for targeted therapeutics strategies. The remarkable cytotoxicity shown by Rebmab200 in OVCAR-3 cells is a significant addition to the traits of stability and productivity displayed by the top clones of Rebmab200. Antibody-dependent cell-mediated toxicity functionality was confirmed in repeated assays using cancer cell lines derived from ovary, kidney and lung as targets. To explore use of this antibody in clinical trials, GMP production of Rebmab

  4. Rebmab200, a Humanized Monoclonal Antibody Targeting the Sodium Phosphate Transporter NaPi2b Displays Strong Immune Mediated Cytotoxicity against Cancer: A Novel Reagent for Targeted Antibody Therapy of Cancer

    PubMed Central

    dos Santos, Mariana Lopes; Yeda, Fernanda Perez; Tsuruta, Lilian Rumi; Horta, Bruno Brasil; Pimenta, Alécio A.; Degaki, Theri Leica; Soares, Ibere C.; Tuma, Maria Carolina; Okamoto, Oswaldo Keith; Alves, Venancio A. F.; Ritter, Gerd; Moro, Ana Maria

    2013-01-01

    NaPi2b, a sodium-dependent phosphate transporter, is highly expressed in ovarian carcinomas and is recognized by the murine monoclonal antibody MX35. The antibody had shown excellent targeting to ovarian cancer in several early phase clinical trials but being murine the antibody's full therapeutic potential could not be explored. To overcome this impediment we developed a humanized antibody version named Rebmab200, expressed in human PER.C6® cells and cloned by limiting dilution. In order to select a clone with high therapeutic potential clones were characterized using a series of physicochemical assays, flow cytometry, real-time surface plasmon resonance, glycosylation analyses, immunohistochemistry, antibody-dependent cell-mediated cytotoxicity, complement-dependent-cytotoxicity assays and quantitative PCR. Comparative analyses of Rebmab200 and MX35 monoclonal antibodies demonstrated that the two antibodies had similar specificity for NaPi2b by flow cytometry with a panel of 30 cell lines and maintained similar kinetic parameters. Robust and high producer cell clones potentially suitable for use in manufacturing were obtained. Rebmab200 antibodies were assessed by immunohistochemistry using a large panel of tissues including human carcinomas of ovarian, lung, kidney and breast origin. An assessment of its binding towards 33 normal human organs was performed as well. Rebmab200 showed selected strong reactivity with the tested tumor types but little or no reactivity with the normal tissues tested confirming its potential for targeted therapeutics strategies. The remarkable cytotoxicity shown by Rebmab200 in OVCAR-3 cells is a significant addition to the traits of stability and productivity displayed by the top clones of Rebmab200. Antibody-dependent cell-mediated toxicity functionality was confirmed in repeated assays using cancer cell lines derived from ovary, kidney and lung as targets. To explore use of this antibody in clinical trials, GMP production of Rebmab

  5. Theranostics Targeting Metastatic Breast Cancer

    DTIC Science & Technology

    2017-10-01

    AWARD NUMBER: W81XWH-15-1-0389 TITLE: Theranostics Targeting Metastatic Breast Cancer PRINCIPAL INVESTIGATOR: Kevin Burgess CONTRACTING...ADDRESS. 1. REPORT DATE October 2017 2. REPORT TYPE Annual 3. DATES COVERED 4. TITLE AND SUBTITLE Theranostics Targeting Metastatic Breast Cancer 5a...safe and effective interventions; (ii) elimination of mortality associated with metastatic breast cancer ; and, (iii) distinguishing aggressive breast

  6. Analysis of The Rayleigh Number in the Area of Steel Rectangular Sections in the Conditions of Stedy and Unstedy Heat Flow/ Analiza Liczby Rayleigha W Obszarze Stalowych Profili Prostokątnych W Warunkach Ustalonego I Nieustalonego Przepływu Ciepła

    NASA Astrophysics Data System (ADS)

    Wyczółkowski, Rafał

    2014-09-01

    The paper presents the experimental measurements dedicated to the research for the Rayleigh number (Ra) in the area of rectangular steel sections. This problem is associated with the analysis of the free convection which takes place in the heating of sections bundles during the heat treatment. The study was conducted for both steady and transient heat transfer. The values of the Ra number obtained for the tested sections allow to describe the phenomenon of convection on the basis of a very simple criterial dependence. It greatly simplifies the mathematical description of the heat transfer phenomenon in the concerned charges. W artykule przedstawiono wyniki badań eksperymentalnych, których celem było określonie liczby Rayleigha (Ra) dla profili prostokątnch, nagrzewanych w warunkach ustalonej i nieustalonej wymiany ciepła. Analizie poddano trzy rodzaje profili: 40×20 mm, 60×60 mm oraz 80×80 mm. Badania dla warunków ustalonych przeprowadzono w komorze grzewczej stanowiska do pomiarów efektywnej przewodności cieplnej wsadów porowatych. Natomiast badania w warunkach nieustalonych przeprowadzono w elektrycznym piecu komorowym. Charakter zmian liczby Ra w funkcji temperatury, dla obu sposobów nagrzewania jest podobny. W każdym z przypadków, maksymalną wartość parametr Ra uzyskuje w przedziale temperatury około 100÷200°C. Dla profili 80×80 mm parametr ten jest około sześciokrotnie większy w porównaniu z profilami 60×60 mm. W przypadku nieustalonego przepływu ciepła, bezwzględne wartości parametru Ra są o rząd wielkości większe od wartości uzyskanych dla warunków ustalonych. Odnotowane liczby Ra nie przekroczyły wartości 107. Maksymalna wartość tego parametru wyniosła około 1,2×106. Zatem przy nagrzewaniu analizowanych profili, występujacą w ich wnętrzu konwekcję, można traktować jako intensyfikację przewodzenia w wypełniającym je powietrzu. Wyniki przedstawionych badań posłużą do analizy wpływu występującej wewn

  7. Thermodynamic Processes Involving Liquefied Natural Gas at the LNG Receiving Terminals / Procesy termodynamiczne z wykorzystaniem skroplonego gazu ziemnego w terminalach odbiorczych LNG

    NASA Astrophysics Data System (ADS)

    Łaciak, Mariusz

    2013-06-01

    The increase in demand for natural gas in the world, cause that the production of liquefied natural gas (LNG) and in consequences its regasification becoming more common process related to its transportation. Liquefied gas is transported in the tanks at a temperature of about 111K at atmospheric pressure. The process required to convert LNG from a liquid to a gas phase for further pipeline transport, allows the use of exergy of LNG to various applications, including for electricity generation. Exergy analysis is a well known technique for analyzing irreversible losses in a separate process. It allows to specify the distribution, the source and size of the irreversible losses in energy systems, and thus provide guidelines for energy efficiency. Because both the LNG regasification and liquefaction of natural gas are energy intensive, exergy analysis process is essential for designing highly efficient cryogenic installations. Wzrost zapotrzebowania na gaz ziemny na świecie powoduje, że produkcja skroplonego gazu ziemnego (LNG), a w konsekwencji jego regazyfikacja, staje się coraz bardziej powszechnym procesem związanym z jego transportem. Skroplony gaz transportowany jest w zbiornikach w temperaturze około 111K pod ciśnieniem atmosferycznym. Przebieg procesu regazyfikacji niezbędny do zamiany LNG z fazy ciekłej w gazową dla dalszego transportu w sieci, umożliwia wykorzystanie egzergii LNG do różnych zastosowań, między innymi do produkcji energii elektrycznej. Analiza egzergii jest znaną techniką analizowania nieodwracalnych strat w wydzielonym procesie. Pozwala na określenie dystrybucji, źródła i wielkości nieodwracalnych strat w systemach energetycznych, a więc ustalić wytyczne dotyczące efektywnego zużycia energii. Ponieważ zarówno regazyfikacja LNG jak i skraplanie gazu ziemnego są energochłonne, proces analizy egzergii jest niezbędny do projektowania wysoce wydajnych instalacji kriogenicznych.

  8. Targeting Cell Polarity Machinery to Exhaust Breast Cancer Stem Cells

    DTIC Science & Technology

    2016-10-01

    AWARD NUMBER: W81XWH-15-1-0644 TITLE: Targeting Cell Polarity Machinery to Exhaust Breast Cancer Stem Cells PRINCIPAL INVESTIGATOR: Chun-Ju...U.S. Army Medical Research and Materiel Command Fort Detrick, Maryland 21702-5012 DISTRIBUTION STATEMENT: Approved for Public Release...Targeting Cell Polarity Machinery to Exhaust Breast Cancer Stem Cells 5a. CONTRACT NUMBER 5b. GRANT NUMBER W81XWH-15-1-0644 5c. PROGRAM ELEMENT

  9. Identification of Molecular Receptors for Therapeutic Targeting in Prostate Cancer

    DTIC Science & Technology

    2006-12-01

    prostate cancer: potential role of androgen and ErbB receptor signal transduction crosstalk. Neoplasia. 5, 99-109 (2003). 10. Kolonin, M., Pasqualini , R...and Arap, W. Molecular addresses in blood vessels as targets for therapy. Curr. Opin. Chem. Biol. 5, 308-313 (2001). 11. Pasqualini , R., and...Ruoslahti, E. Organ targeting in vivo using phage display peptide libraries. Nature 380, 364-366 (1996). 12. Arap, W., Pasqualini , R., and Ruoslahti, E

  10. Targeting Sphingosine-1-Phosphate Axis in Obesity-Promoted Breast Cancer

    DTIC Science & Technology

    2016-05-01

    AWARD NUMBER: W81XWH-14-1-0071 TITLE: Targeting Sphingosine-1-Phosphate Axis in Obesity -Promoted Breast Cancer PRINCIPAL INVESTIGATOR...5a. CONTRACT NUMBER Targeting Sphingosine-1-Phosphate Axis in Obesity -Promoted Breast Cancer 5b. GRANT NUMBER W81XWH-14-1-0071 5c. PROGRAM ELEMENT...13. SUPPLEMENTARY NOTES 14. ABSTRACT Obesity , which induces low-grade inflammation, is a known risk factor for worse prognosis in many cancers

  11. Identifying Molecular Targets for PTSD Treatment Using Single Prolonged Stress

    DTIC Science & Technology

    2015-10-01

    1 AWARD NUMBER: W81XWH-13-1-0377 TITLE: Identifying Molecular Targets For PTSD Treatment Using Single Prolonged Stress PRINCIPAL...TITLE AND SUBTITLE 5a. CONTRACT NUMBER W81XWH-13-1-0377 Identifying Molecular Targets For PTSD Treatment Using Single Prolonged Stress 5b. GRANT...brain GR and β-AR expression alters glutamatergic and GABAergic function in neural circuits that mediate SPS-induced deficits in extinction retention

  12. Targeting Ovarian Cancer with Porphysome Nanotechnology

    DTIC Science & Technology

    2014-10-01

    AWARD NUMBER: W81XWH-13-1-0442 TITLE: Targeting Ovarian Cancer with Porphysome Nanotechnology PRINCIPAL INVESTIGATOR: Gang Zheng CONTRACTING...Ovarian Cancer with Porphysome Nanotechnology 5b. GRANT NUMBER W81XWH-13-1-0442 5c. PROGRAM ELEMENT NUMBER 6. AUTHOR(S) 5d. PROJECT NUMBER Gang Zheng...the intrinsic multimodal nature of porphyrin-assembled nanoparticles confers high potential for cancer theranostics and clinical translation

  13. In Situ Study of CO2 and H2O Partitioning Between Na-Montmorillonite and Variably Wet Supercritical Carbon Dioxide

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Loring, John S.; Ilton, Eugene S.; Chen, Jeffrey

    Shale formations play fundamental roles in large-scale geologic carbon sequestration (GCS) aimed primarily to mitigate climate change, and in smaller-scale GCS targeted mainly for CO2-enhanced gas recovery operations. In both technologies, CO2 is injected underground as a supercritical fluid (scCO2), where interactions with shale minerals could influence successful GCS implementation. Reactive components of shales include expandable clays, such as montmorillonites and mixed-layer illite/smectite clays. In this work, we used in situ X-ray diffraction (XRD) and in situ infrared (IR) spectroscopy to investigate the swelling/shrinkage and water/CO2 sorption of a pure montmorillonite, Na-SWy-2, when the clay is exposed to variably hydratedmore » scCO2 at 50 °C and 90 bar. Measured interlayer spacings and sorbed water concentrations at varying levels of scCO2 hydration are similar to previously reported values measured in air at ambient pressure over a range of relative humidities. IR spectra show evidence of both water and CO2 intercalation, and variations in peak shapes and positions suggest multiple sorbed types with distinct chemical environments. Based on the intensity of the asymmetric CO stretching band of the CO2 associated with the Na-SWy-2, we observed a significant increase in sorbed CO2 as the clay expands from a 0W to a 1W state, suggesting that water props open the interlayer so that CO2 can enter. However, as the clay transitions from a 1W to a 2W state, CO2 desorbs sharply. These observations were placed in the context of two conceptual models concerning hydration mechanisms for expandable clays and were also discussed in light of recent theoretical studies on CO2-H2O-clay interactions. The swelling/shrinkage of expandable clays could affect solid volume, porosity, and permeability of shales. Consequently, the results from this work could aid predictions of shale caprock integrity in large-scale GCS, as well as methane transmissivity in enhanced gas

  14. Emulsifying properties and oil/water (O/W) interface adsorption behavior of heated soy proteins: effects of heating concentration, homogenizer rotating speed, and salt addition level.

    PubMed

    Cui, Zhumei; Chen, Yeming; Kong, Xiangzhen; Zhang, Caimeng; Hua, Yufei

    2014-02-19

    The adsorption of heat-denatured soy proteins at the oil/water (O/W) interface during emulsification was studied. Protein samples were prepared by heating protein solutions at concentrations of 1-5% (w/v) and were then diluted to 0.3% (w/v). The results showed that soy proteins that had been heated at higher concentrations generated smaller droplet size of emulsion. Increase in homogenizer rotating speed resulted in higher protein adsorption percentages and lower surface loads at the O/W interface. Surface loads for both unheated and heated soy proteins were linearly correlated with the unadsorbed proteins' equilibrium concentration at various rotating speeds. With the rise in NaCl addition level, protein adsorption percentage and surface loads of emulsions increased, whereas lower droplet sizes were obtained at the ionic strength of 0.1 M. The aggregates and non-aggregates displayed different adsorption behaviors when rotating speed or NaCl concentration was varied.

  15. Production of thorium-229 using helium nuclei

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Mirzadeh, Saed; Garland, Marc Alan

    A method for producing .sup.229Th includes the steps of providing .sup.226Ra as a target material, and bombarding the target material with alpha particles, helium-3, or neutrons to form .sup.229Th. When neutrons are used, the neutrons preferably include an epithermal neutron flux of at least 1.times.10.sup.13 n s.sup.-1cm.sup.-2. .sup.228Ra can also be bombarded with thermal and/or energetic neutrons to result in a neutron capture reaction to form .sup.229Th. Using .sup.230Th as a target material, .sup.229Th can be formed using neutron, gamma ray, proton or deuteron bombardment.

  16. Exploring the engineering limit of heat flux of a W/RAFM divertor target for fusion reactors

    NASA Astrophysics Data System (ADS)

    Mao, X.; Fursdon, M.; Chang, X. B.; Zhang, J. W.; Liu, P.; Ellwood, G.; Qian, X. Y.; Qin, S. J.; Peng, X. B.; Barrett, T. R.; Liu, P.

    2018-06-01

    The design and development of a fusion reactor divertor plasma facing component (PFC) is one of the many challenging issues on the road to commercial use of fusion energy. The divertor PFC is expected to exhaust steady state heat loads in the region of 10 MW m‑2 while keeping temperatures and thermo-mechanical stresses in its structure within the allowable limits. For ITER (International Thermo-Nuclear Experimental Reactor) a water cooled W/CuCrZr divertor PFC concept has been developed. However, this concept is not necessarily assured for use in future fusion reactors mainly because the neutron radiation dose would be at least an order magnitude higher, resulting in limited thermo-mechanical performance and considerably more activated waste products. In the present study, a water cooled divertor PFC using reduced activation ferritic-martensitic (RAFM) steel as the heat sink pipe has been designed with pressurised water reactor-like cooling conditions (pressure of 15.5 MPa, velocity of 10–20 m s‑1 and temperature of 300 °C). The PFC is made up of a number of rectangular tungsten tiles, each with an inner circular hole (so-called monoblocks), joined onto a RAFM steel pipe with copper interlayers. The thermo-mechanical performance of the PFC has been studied in detail. The heat transfer coefficient between the RAFM pipe inner surface and the water was calculated using published correlations. Geometric parameters and water velocity were optimized with finite element (FE) thermal analysis, to achieve acceptable temperatures in the structure given the target exhaust heat load of 10 MW m‑2. Under this heat load and the optimised thermal design parameters, the structure of the PFC was further assessed by mechanical analysis. We find that under these conditions the RAFM steel pipe experiences cyclic plasticity, and fails the common linear elastic ratchetting (3 Sm) rule. Nevertheless, the designed W/RAFM divertor PFU can withstand 10 MW m‑2 heat load, albeit

  17. Quantitative evaluation of high-energy O- ion particle flux in a DC magnetron sputter plasma with an indium-tin-oxide target

    NASA Astrophysics Data System (ADS)

    Suyama, Taku; Bae, Hansin; Setaka, Kenta; Ogawa, Hayato; Fukuoka, Yushi; Suzuki, Haruka; Toyoda, Hirotaka

    2017-11-01

    O- ion flux from the indium tin oxide (ITO) sputter target under Ar ion bombardment is quantitatively evaluated using a calorimetry method. Using a mass spectrometer with an energy analyzer, O- energy distribution is measured with spatial dependence. Directional high-energy O- ion ejected from the target surface is observed. Using a calorimetry method, localized heat flux originated from high-energy O- ion is measured. From absolute evaluation of the heat flux from O- ion, O- particle flux in order of 1018 m-2 s-1 is evaluated at a distance of 10 cm from the target. Production yield of O- ion on the ITO target by one Ar+ ion impingement at a kinetic energy of 244 eV is estimated to be 3.3  ×  10-3 as the minimum value.

  18. Target and beam-target spin asymmetries in exclusive π+ and π- electroproduction with 1.6- to 5.7-GeV electrons

    NASA Astrophysics Data System (ADS)

    Bosted, P. E.; Biselli, A. S.; Careccia, S.; Dodge, G.; Fersch, R.; Guler, N.; Kuhn, S. E.; Pierce, J.; Prok, Y.; Zheng, X.; Adhikari, K. P.; Adikaram, D.; Akbar, Z.; Amaryan, M. J.; Anefalos Pereira, S.; Asryan, G.; Avakian, H.; Badui, R. A.; Ball, J.; Baltzell, N. A.; Battaglieri, M.; Batourine, V.; Bedlinskiy, I.; Boiarinov, S.; Briscoe, W. J.; Bültmann, S.; Burkert, V. D.; Cao, T.; Carman, D. S.; Celentano, A.; Chandavar, S.; Charles, G.; Chetry, T.; Ciullo, G.; Clark, L.; Colaneri, L.; Cole, P. L.; Contalbrigo, M.; Cortes, O.; Crede, V.; D'Angelo, A.; Dashyan, N.; De Vita, R.; Deur, A.; Djalali, C.; Dupre, R.; Egiyan, H.; El Alaoui, A.; El Fassi, L.; Eugenio, P.; Fanchini, E.; Fedotov, G.; Filippi, A.; Fleming, J. A.; Forest, T. A.; Fradi, A.; Garçon, M.; Gevorgyan, N.; Ghandilyan, Y.; Gilfoyle, G. P.; Giovanetti, K. L.; Girod, F. X.; Gleason, C.; Gohn, W.; Golovatch, E.; Gothe, R. W.; Griffioen, K. A.; Guo, L.; Hafidi, K.; Hanretty, C.; Harrison, N.; Hattawy, M.; Heddle, D.; Hicks, K.; Holtrop, M.; Hughes, S. M.; Ilieva, Y.; Ireland, D. G.; Ishkhanov, B. S.; Isupov, E. L.; Jenkins, D.; Jiang, H.; Jo, H. S.; Joo, K.; Joosten, S.; Keller, D.; Khandaker, M.; Kim, W.; Klein, A.; Klein, F. J.; Kubarovsky, V.; Kuleshov, S. V.; Lanza, L.; Lenisa, P.; Livingston, K.; Lu, H. Y.; MacGregor, I. J. D.; Markov, N.; McCracken, M. E.; McKinnon, B.; Meyer, C. A.; Minehart, R.; Mirazita, M.; Mokeev, V.; Movsisyan, A.; Munevar, E.; Munoz Camacho, C.; Nadel-Turonski, P.; Net, L. A.; Ni, A.; Niccolai, S.; Niculescu, G.; Niculescu, I.; Osipenko, M.; Ostrovidov, A. I.; Paremuzyan, R.; Park, K.; Pasyuk, E.; Peng, P.; Phelps, W.; Pisano, S.; Pogorelko, O.; Price, J. W.; Procureur, S.; Protopopescu, D.; Puckett, A. J. R.; Raue, B. A.; Ripani, M.; Rizzo, A.; Rosner, G.; Rossi, P.; Roy, P.; Sabatié, F.; Salgado, C.; Schumacher, R. A.; Seder, E.; Sharabian, Y. G.; Simonyan, A.; Skorodumina, Iu.; Smith, G. D.; Sparveris, N.; Stankovic, Ivana; Stepanyan, S.; Strakovsky, I. I.; Strauch, S.; Sytnik, V.; Taiuti, M.; Tian, Ye; Torayev, B.; Ungaro, M.; Voskanyan, H.; Voutier, E.; Walford, N. K.; Watts, D. P.; Wei, X.; Weinstein, L. B.; Wood, M. H.; Zachariou, N.; Zana, L.; Zhang, J.; Zhao, Z. W.; Zonta, I.; CLAS Collaboration

    2016-11-01

    Beam-target double-spin asymmetries and target single-spin asymmetries in exclusive π+ and quasiexclusive π- electroproduction were obtained from scattering of 1.6- to 5.7-GeV longitudinally polarized electrons from longitudinally polarized protons (for π+) and deuterons (for π-) using the CEBAF Large Acceptance Spectrometer (CLAS) at Jefferson Lab. The kinematic range covered is 1.1 <W <2.6 GeV and 0.05 W <1.7 GeV and Q2<0.5 GeV2 , with discrepancies increasing at higher values of Q2, especially for W >1.5 GeV. Very large target-spin asymmetries are observed for W >1.6 GeV. When combined with cross-section measurements, the present results can provide powerful constraints on nucleon resonance amplitudes at moderate and large values of Q2, for resonances with masses as high as 2.3 GeV.

  19. Target and beam-target spin asymmetries in exclusive π + and π - electroproduction with 1.6- to 5.7-GeV electrons

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Bosted, P. E.; Biselli, A. S.; Careccia, S.

    Beam-target double-spin asymmetries and target single-spin asymmetries in exclusive pi(+) and quasiexclusive pi(-) electroproduction were obtained from scattering of 1.6- to 5.7-GeV longitudinally polarized electrons from longitudinally polarized protons (for pi(+)) and deuterons (for pi(-)) using the CEBAF Large Acceptance Spectrometer (CLAS) at Jefferson Lab. The kinematic range covered is 1.1 < W < 2.6 GeV and 0.05 < Q(2) < 5 GeV2, with good angular coverage in the forward hemisphere. The asymmetry results were divided into approximately 40 000 kinematic bins for pi(+) from free protons and 15 000 bins for pi(-) production from bound nucleons in the deuteron.more » The present results are found to be in reasonable agreement with fits to previous world data for W < 1.7 GeV and Q(2) < 0.5 GeV2, with discrepancies increasing at higher values of Q(2), especially for W > 1.5 GeV. Very large target-spin asymmetries are observed for W > 1.6 GeV. When combined with cross-section measurements, the present results can provide powerful constraints on nucleon resonance amplitudes at moderate and large values of Q(2), for resonances with masses as high as 2.3 GeV.« less

  20. Geology, mineralization, and fluid inclusion characteristics of the Skrytoe reduced-type W skarn and stockwork deposit, Sikhote-Alin, Russia

    NASA Astrophysics Data System (ADS)

    Soloviev, Serguei G.; Kryazhev, Sergey G.

    2017-08-01

    The Skrytoe deposit (>145 Kt WO3, average grade 0.449% WO3) in the Sikhote-Alin orogenic system (Eastern Russia) is situated in a metallogenic belt of W, Sn-W, Au, and Au-W deposits formed in a late to post-collisional tectonic environment after cessation of active subduction. It is localized within a mineralized district of reduced-type skarn W and veined Au (±W) deposits and occurrences related to the Early Cretaceous ilmenite-series plutonic suite. The deposit incorporates large stockworks of scheelite-bearing veinlets related to propylitic (amphibole, chlorite, quartz) and phyllic (quartz, sericite, albite, apatite, and carbonate) hydrothermal alteration. The stockwork cuts flat-lying mafic volcanic rocks and limestone partially replaced by pyroxene skarn that host the major W orebodies. Scheelite is associated with pyrrhotite and/or arsenopyrite, with minor chalcopyrite and other sulfide minerals; the late phyllic stage assemblages hosts Bi and Au mineralization. The fluid evolution included low-salinity moderate-temperature, moderate-pressure (˜370-390 °C, ˜800 bars) methane-dominated carbonic-aqueous fluids that formed post-skarn propylitic alteration assemblages. Then, at the phyllic stage, there has been an evolution from methane-dominated, moderate-temperature (330-360 °C), low-salinity (<12.3 wt% NaCl equiv.) fluids forming the early quartz-sericite-albite-arsenopyrite assemblage, through lower temperature (290-330 °C) methane-dominated, low-salinity (˜9-10 wt% NaCl equiv.) fluids forming the intermediate quartz-sericite-albite-scheelite-pyrrhotite assemblage, to yet lower temperature (245-320 °C) CO2-dominated carbonic-aqueous low-salinity (˜1-7 wt% NaCl equiv.) fluids forming the late quartz-sericite-sulfide-Bi-Au assemblage. Recurrent fluid immiscibility (phase separation) and cooling probably affected W solubility and promoted scheelite deposition. The stable isotope data support a sedimentary source of carbon (δ13Cfluid = ˜-21 to -10

  1. Thermal Power Of The TS-300B Refrigerator in the Aspects of Statistical Research / Moc Cieplna Chłodziarki TS-300B W Aspekcie Badań Statystycznych

    NASA Astrophysics Data System (ADS)

    Nowak, Bernard; Łuczak, Rafał

    2015-09-01

    refrigerator, both on the test stand in the manufacturer's laboratory and in the workings of underground mines. The evaluation of the measurement data distributions, as well as an analysis of the basic descriptive statistics of the mentioned variables were carried out, determining their measures of central tendency, location, dispersion and asymmetry. Artykuł dotyczy poprawy cieplnych warunków pracy w wyrobiskach górniczych kopalń podziemnych stosujących lokalne systemy chłodnicze. Rozważa się w nim skuteczność schładzania powietrza chłodziarką sprężarkową bezpośredniego działania typu TS-300B. Bardzo często, w wyniku niedotrzymania wymaganych warunków pracy wymienionego systemu chłodzenia powietrza, występują rozbieżności między prognozowanymi, a więc oczekiwanymi efektami jego pracy a rzeczywistością. Dlatego, dla poprawy skuteczności pracy tego systemu, opracowano, pod kątem efektywnego wykorzystania mocy chłodniczej parownika takiej chłodziarki, łatwe w zastosowaniu praktycznym kryteria jakości. Otrzymano je w postaci modeli statystycznych określających wpływ zmiennych niezależnych, tj. parametrów powietrza wlotowego do parownika (temperatury, wilgotności i wydatku objętościowego) oraz parametrów wody chłodzącej skraplacz (temperatury i wydatku objętościowego) na moc cieplną chłodnicy powietrza traktowaną jako zmienna zależna. Równania statystyczne opisujące pracę rozważanego systemu chłodzenia powietrza wyznaczono na podstawie wielorakiej regresji liniowej i nieliniowej. Utworzone funkcje zmodyfikowano poprzez zmianę wartości współczynników w przypadku regresji liniowej oraz współczynników i wykładników w przypadku regresji nieliniowej, przy zmiennych niezależnych. Otrzymano w ten sposób funkcje dogodniejsze w praktycznych wykorzystaniach. Korzystając z metod statystyki klasycznej oceniono jakość dopasowania funkcji regresji do danych eksperymentalnych. Porównano także wartości mocy cieplnych

  2. kW-class direct diode laser for sheet metal cutting based on commercial pump modules

    NASA Astrophysics Data System (ADS)

    Witte, U.; Schneider, F.; Holly, C.; Di Meo, A.; Rubel, D.; Boergmann, F.; Traub, M.; Hoffmann, D.; Drovs, S.; Brand, T.; Unger, A.

    2017-02-01

    We present a direct diode laser with an optical output power of more than 800 W ex 100 μm with an NA of 0.17. The system is based on 6 commercial pump modules that are wavelength stabilized by use of VBGs. Dielectric filters are used for coarse and dense wavelength multiplexing. Metal sheet cutting tests were performed in order to prove system performance and reliability. Based on a detailed analysis of loss mechanisms, we show that the design can be easily scaled to output powers in the range of 2 kW and to an optical efficiency of 80%.

  3. Targeting Cytosolic Nucleic Acid-Sensing Pathways for Cancer Immunotherapies.

    PubMed

    Iurescia, Sandra; Fioretti, Daniela; Rinaldi, Monica

    2018-01-01

    The innate immune system provides the first line of defense against pathogen infection though also influences pathways involved in cancer immunosurveillance. The innate immune system relies on a limited set of germ line-encoded sensors termed pattern recognition receptors (PRRs), signaling proteins and immune response factors. Cytosolic receptors mediate recognition of danger damage-associated molecular patterns (DAMPs) signals. Once activated, these sensors trigger multiple signaling cascades, converging on the production of type I interferons and proinflammatory cytokines. Recent studies revealed that PRRs respond to nucleic acids (NA) released by dying, damaged, cancer cells, as danger DAMPs signals, and presence of signaling proteins across cancer types suggests that these signaling mechanisms may be involved in cancer biology. DAMPs play important roles in shaping adaptive immune responses through the activation of innate immune cells and immunological response to danger DAMPs signals is crucial for the host response to cancer and tumor rejection. Furthermore, PRRs mediate the response to NA in several vaccination strategies, including DNA immunization. As route of double-strand DNA intracellular entry, DNA immunization leads to expression of key components of cytosolic NA-sensing pathways. The involvement of NA-sensing mechanisms in the antitumor response makes these pathways attractive drug targets. Natural and synthetic agonists of NA-sensing pathways can trigger cell death in malignant cells, recruit immune cells, such as DCs, CD8 + T cells, and NK cells, into the tumor microenvironment and are being explored as promising adjuvants in cancer immunotherapies. In this minireview, we discuss how cGAS-STING and RIG-I-MAVS pathways have been targeted for cancer treatment in preclinical translational researches. In addition, we present a targeted selection of recent clinical trials employing agonists of cytosolic NA-sensing pathways showing how these pathways

  4. Solvation of Na^+ in water from first-principles molecular dynamics

    NASA Astrophysics Data System (ADS)

    White, J. A.; Schwegler, E.; Galli, G.; Gygi, F.

    2000-03-01

    We have carried out ab initio molecular dynamics (MD) simulations of the Na^+ ion in water with an MD cell containing a single alkali ion and 53 water molecules. The electron-electron and electron-ion interactions were modeled by density functional theory with a generalized gradient approximation for the exchange-correlation functional. The computed radial distribution functions, coordination numbers, and angular distributions are consistent with available experimental data. The first solvation shell contains 5.2±0.6 water molecules, with some waters occasionally exchanging with those of the second shell. The computed Na^+ hydration number is larger than that from calculations for water clusters surrounding an Na^+ ion, but is consistent with that derived from x-ray measurements. Our results also indicate that the first hydration shell is better defined for Na^+ than for K^+ [1], as indicated by the first minimum in the Na-O pair distribution function. [1] L.M. Ramaniah, M. Bernasconi, and M. Parrinello, J. Chem. Phys. 111, 1587 (1999). This work was performed for DOE under contract W-7405-ENG-48.

  5. Use of immobilized exopeptidases and volatile buffers for analysis of peptides by fast atom bombardment mass spectrometry.

    PubMed

    Wagner, R M; Fraser, B A

    1987-05-01

    beta-Lipotrophin (62-77) or Ac-gastrin releasing peptide was incubated with immobilized carboxypeptidase Y or aminopeptidase M. Subsequent aliquots of each incubation mixture were analysed by fast atom bombardment mass spectrometry using a dithiothreitol/dithioerythritol liquid matrix. The use of immobilized enzymes and volatile buffers for exopeptidase digestions enabled rapid and facile separation of enzyme from digestion products. This approach to mass spectral peptide analysis reduced spectral background arising from a glycerol matrix, buffer salts, or enzyme proteins and contaminants, enabling analysis of as little as 200 picomoles of a suitable peptide.

  6. Femtosecond laser fluence based nanostructuring of W and Mo in ethanol

    NASA Astrophysics Data System (ADS)

    Bashir, Shazia; Rafique, Muhammad Shahid; Nathala, Chandra Sekher; Ajami, Ali Asghar; Husinsky, Wolfgang

    2017-05-01

    The effect of femtosecond laser fluence on nanostructuring of Tungsten (W) and Molybdenum (Mo) has been investigated after ablation in ethanol environment. A Ti: Sapphire laser (800 nm, 30 fs) at fluences ranging from 0.6 to 5.7 J cm-2 was employed to ablate targets. The growth of structures on the surface of irradiated targets is investigated by Field Emission Scanning Electron Microscope (FESEM) analysis. The SEM was performed for both central as well as the peripheral ablated regions. It is observed that both the development and shape of nanoscale features is dependent upon deposited energies to the target surface as well as nature of material. Nanostructures grown on Mo are more distinct and well defined as compared to W. At central ablated areas of W, unorganized Laser Induced Periodic Surface Structures (LIPSS) are grown at low fluences, whereas, nonuniform melting along with cracking is observed at higher fluences. In case of Mo, well-defined and organized LIPSS are observed for low fluences. With increasing fluence, LIPSS become unorganized and broken with an appearance of cracks and are completely vanished with the formation of nanoscale cavities and conical structures. In case of peripheral ablated areas broken and bifurcated LIPSS are grown for all fluences for both materials. The, ablated diameter, ablation depth, ablation rate and the dependence of periodicity of LIPSS on the laser fluence are also estimated for both W and Mo. Parametric instabilities of laser-induced plasma along with generation and scattering of surface plasmons is considered as a possible cause for the formation of LIPSS. For ethanol assisted ablation, the role of bubble cavitation, precipitation, confinement and the convective flow is considered to be responsible for inducing increased hydrodynamic instabilities at the liquid-solid interface.

  7. The EMEP MSC-W chemical transport model - technical description

    NASA Astrophysics Data System (ADS)

    Simpson, D.; Benedictow, A.; Berge, H.; Bergström, R.; Emberson, L. D.; Fagerli, H.; Flechard, C. R.; Hayman, G. D.; Gauss, M.; Jonson, J. E.; Jenkin, M. E.; Nyíri, A.; Richter, C.; Semeena, V. S.; Tsyro, S.; Tuovinen, J.-P.; Valdebenito, Á.; Wind, P.

    2012-08-01

    The Meteorological Synthesizing Centre-West (MSC-W) of the European Monitoring and Evaluation Programme (EMEP) has been performing model calculations in support of the Convention on Long Range Transboundary Air Pollution (CLRTAP) for more than 30 years. The EMEP MSC-W chemical transport model is still one of the key tools within European air pollution policy assessments. Traditionally, the model has covered all of Europe with a resolution of about 50 km × 50 km, and extending vertically from ground level to the tropopause (100 hPa). The model has changed extensively over the last ten years, however, with flexible processing of chemical schemes, meteorological inputs, and with nesting capability: the code is now applied on scales ranging from local (ca. 5 km grid size) to global (with 1 degree resolution). The model is used to simulate photo-oxidants and both inorganic and organic aerosols. In 2008 the EMEP model was released for the first time as public domain code, along with all required input data for model runs for one year. The second release of the EMEP MSC-W model became available in mid 2011, and a new release is targeted for summer 2012. This publication is intended to document this third release of the EMEP MSC-W model. The model formulations are given, along with details of input data-sets which are used, and a brief background on some of the choices made in the formulation is presented. The model code itself is available at target="_blank">www.emep.int, along with the data required to run for a full year over Europe.

  8. Pyrazoleamide compounds are potent antimalarials that target Na+ homeostasis in intraerythrocytic Plasmodium falciparum

    PubMed Central

    Vaidya, Akhil B.; Morrisey, Joanne M.; Zhang, Zhongsheng; Das, Sudipta; Daly, Thomas M.; Otto, Thomas D.; Spillman, Natalie J.; Wyvratt, Matthew; Siegl, Peter; Marfurt, Jutta; Wirjanata, Grennady; Sebayang, Boni F.; Price, Ric N.; Chatterjee, Arnab; Nagle, Advait; Stasiak, Marcin; Charman, Susan A.; Angulo-Barturen, Iñigo; Ferrer, Santiago; Belén Jiménez-Díaz, María; Martínez, María Santos; Gamo, Francisco Javier; Avery, Vicky M.; Ruecker, Andrea; Delves, Michael; Kirk, Kiaran; Berriman, Matthew; Kortagere, Sandhya; Burrows, Jeremy; Fan, Erkang; Bergman, Lawrence W.

    2014-01-01

    The quest for new antimalarial drugs, especially those with novel modes of action, is essential in the face of emerging drug-resistant parasites. Here we describe a new chemical class of molecules, pyrazoleamides, with potent activity against human malaria parasites and showing remarkably rapid parasite clearance in an in vivo model. Investigations involving pyrazoleamide-resistant parasites, whole-genome sequencing and gene transfers reveal that mutations in two proteins, a calcium-dependent protein kinase (PfCDPK5) and a P-type cation-ATPase (PfATP4), are necessary to impart full resistance to these compounds. A pyrazoleamide compound causes a rapid disruption of Na+ regulation in blood-stage Plasmodium falciparum parasites. Similar effect on Na+ homeostasis was recently reported for spiroindolones, which are antimalarials of a chemical class quite distinct from pyrazoleamides. Our results reveal that disruption of Na+ homeostasis in malaria parasites is a promising mode of antimalarial action mediated by at least two distinct chemical classes. PMID:25422853

  9. Endocannabinoids as a Target for the Treatment of Traumatic Brain Injury

    DTIC Science & Technology

    2014-11-01

    Award Number: W81XWH-11-2-0011 TITLE: Endocannabinoids as a Target for the Treatment of Traumatic Brain Injury PRINCIPAL INVESTIGATOR...Oct 2014 4. TITLE AND SUBTITLE Endocannabinoids as a Target for the Treatment of Traumatic Brain Injury 5a. CONTRACT NUMBER 5b. GRANT NUMBER W81XWH...fluid percussion, traumatic brain injury, blood brain barrier, neuroinflammation, neurological dysfunction, endocannabinoids , microglia and 16

  10. "I Feel like I'm Being Hit from All Directions": Enduring the Bombardment as a Mature-Age Learner Returning to Formal Learning

    ERIC Educational Resources Information Center

    Willans, Julie; Seary, Karen

    2011-01-01

    The mature-age learner's re-engagement with a formal learning environment may be somewhat akin to the novice Paintball player who, unless well positioned and attuned to the rules of the combative game, is bombarded and worn down by constant "hits". For the mature-age learner, such "hits" may come in the form of tensions…

  11. Sputtering erosion in ion and plasma thrusters

    NASA Technical Reports Server (NTRS)

    Ray, Pradosh K.

    1995-01-01

    An experimental set-up to measure low-energy (below 1 keV) sputtering of materials is described. The materials to be bombarded represent ion thruster components as well as insulators used in the stationary plasma thruster. The sputtering takes place in a 9 inch diameter spherical vacuum chamber. Ions of argon, krypton and xenon are used to bombard the target materials. The sputtered neutral atoms are detected by a secondary neutral mass spectrometer (SNMS). Samples of copper, nickel, aluminum, silver and molybdenum are being sputtered initially to calibrate the spectrometer. The base pressure of the chamber is approximately 2 x 10(exp -9) Torr. the primary ion beam is generated by an ion gun which is capable of delivering ion currents in the range of 20 to 500 nA. The ion beam can be focused to a size approximately 1 mm in diameter. The mass spectrometer is positioned 10 mm from the target and at 90 deg angle to the primary ion beam direction. The ion beam impinges on the target at 45 deg. For sputtering of insulators, charge neutralization is performed by flooding the sample with electrons generated from an electron gun. Preliminary sputtering results, methods of calculating the instrument response function of the spectrometer and the relative sensitivity factors of the sputtered elements will be discussed.

  12. A PDS Archive for Observations of Mercury's Na Exosphere

    NASA Astrophysics Data System (ADS)

    Backes, C.; Cassidy, T.; Merkel, A. W.; Killen, R. M.; Potter, A. E.

    2016-12-01

    We present a data product consisting of ground-based observations of Mercury's sodium exosphere. We have amassed a sizeable dataset of several thousand spectral observations of Mercury's exosphere from the McMath-Pierce solar telescope. Over the last year, a data reduction pipeline has been developed and refined to process and reconstruct these spectral images into low resolution images of sodium D2 emission. This dataset, which extends over two decades, will provide an unprecedented opportunity to analyze the dynamics of Mercury's mid to high-latitude exospheric emissions, which have long been attributed to solar wind ion bombardment. This large archive of observations will be of great use to the Mercury science community in studying the effects of space weather on Mercury's tenuous exosphere. When completely processed, images in this dataset will show the observed spatial distribution of Na D2 in the Mercurian exosphere, have measurements of this sodium emission per pixel in units of kilorayleighs, and be available through NASA's Planetary Data System. The overall goal of the presentation will be to provide the Planetary Science community with a clear picture of what information and data this archival product will make available.

  13. A Novel W1999S Mutation and Non-Target Site Resistance Impact on Acetyl-CoA Carboxylase Inhibiting Herbicides to Varying Degrees in a UK Lolium multiflorum Population

    PubMed Central

    Kaundun, Shiv Shankhar; Bailly, Geraldine C.; Dale, Richard P.; Hutchings, Sarah-Jane; McIndoe, Eddie

    2013-01-01

    Background Acetyl-CoA carboxylase (ACCase) inhibiting herbicides are important products for the post-emergence control of grass weed species in small grain cereal crops. However, the appearance of resistance to ACCase herbicides over time has resulted in limited options for effective weed control of key species such as Lolium spp. In this study, we have used an integrated biological and molecular biology approach to investigate the mechanism of resistance to ACCase herbicides in a Lolium multiflorum Lam. from the UK (UK21). Methodology/Principal Findings The study revealed a novel tryptophan to serine mutation at ACCase codon position 1999 impacting on ACCase inhibiting herbicides to varying degrees. The W1999S mutation confers dominant resistance to pinoxaden and partially recessive resistance to cycloxydim and sethoxydim. On the other hand, plants containing the W1999S mutation were sensitive to clethodim and tepraloxydim. Additionally population UK21 is characterised by other resistance mechanisms, very likely non non-target site based, affecting several aryloxyphenoxyproprionate (FOP) herbicides but not the practical field rate of pinoxaden. The positive identification of wild type tryptophan and mutant serine alleles at ACCase position 1999 could be readily achieved with an original DNA based derived cleaved amplified polymorphic sequence (dCAPS) assay that uses the same PCR product but two different enzymes for positively identifying the wild type tryptophan and mutant serine alleles identified here. Conclusion/Significance This paper highlights intrinsic differences between ACCase inhibiting herbicides that could be exploited for controlling ryegrass populations such as UK21 characterised by compound-specific target site and non-target site resistance. PMID:23469130

  14. Modified Stability Charts for Rock Slopes Based on the Hoek-Brown Failure Criterion / Zmodyfikowane Diagramy Stabilności Skalistych Zboczy Otrzymane W Oparciu O Warunek Wytrzymałości Hoeka-Browna

    NASA Astrophysics Data System (ADS)

    Nekouei, Mahdi; Ahangari, Kaveh

    2013-09-01

    Only an article rendered by Lia et al. in 2008 has represented charts based on Hoek-Brown criterion for rock slopes, however, these charts are not precise and efficient. Because of this problem, a modification is suggested for the mentioned charts in this study. The new charts are calculated according to four methods. Among the methods, one relates to finite element method using Phase2 software. The other three methods are Janbu, Bishop and Fellenius that belong to limit equilibrium method by using Slide software. For each slope angle, the method having high correlation coefficient is selected as the best one. Then, final charts are rendered according to the selected method and its specific equations. Among forty equations, twenty-five ones or 62.5% relate to numerical method and Phase2 software, six ones or 15% belong to Fellenius limit equilibrium, six ones or 15% relate to Bishop limit equilibrium, and three ones or 7.5% belong to Janbu limit equilibrium. In order to validate new charts, slope stability analysis is carried out for several sections of Chadormalu iron ore open pit mine, Iran. The error percentage of new charts in limit equilibrium method using Slide software and in Bishop method for slopes of Chadormalu iron ore mine are rendered and compared. The charts on a basis of Hoek-Brown failure criterion for rock slopes show less than ±4% error. This indicates that these charts are appropriate tools and their safety factor is optimal for rock slopes. Diagramy stabilności skalistych zboczy otrzymane w oparciu o warunek wytrzymałości Hoeka- Browna znaleźć można jedynie w pracy Lia et al. (2008), choć wykresy te nie są absolutnie dokładne i jasne. Dlatego też w niniejszym artykule zaproponowano pewną modyfikację diagramów. Nowe wykresu sporządzono w oparciu o cztery metody. Jedna z metod opiera się na metodzie elementów skończonych i wykorzystuje oprogramowanie Phase2. Pozostałe trzy podejścia to metody Janbu, Bishopa i Felleniusa bazuj

  15. Observations and light curve solutions of a selection of middle-contact W UMa binaries

    NASA Astrophysics Data System (ADS)

    Kjurkchieva, Diana Petrova; Popov, Velimir Angelov; Lyubenova Vasileva, Doroteya; Petrov, Nikola Ivanov

    2018-04-01

    Photometric observations in Sloan g‧ and i‧ bands of W UMa binaries NSVS 4340949, T-Dra0–00959, GSC 03950–00707, NSVS 4665041, NSVS 4803568, MM Peg, MM Com and NSVS 4751449 are presented. The light curve solutions revealed that the components of each target are of G and K spectral types. The binaries of the sample have middle-contact configurations whose fillout factors are within the range 0.2–0.4. The only exception is NSVS 4751449 which is in deeper contact (fillout factor of 0.55). It precisely obeys the relation between mass ratio and fillout factor for deep, low mass ratio overcontact binaries. One of the eclipses of almost all targets (except MM Peg) is an occultation and their photometric mass ratios and solutions could be accepted with confidence. We found that the target components have almost equal temperatures but differ considerably in size and mass. The components of the partially-eclipsed MM Peg have close parameters. Our solutions reveal that NSVS 4340949, T-Dra0–00959, NSVS 4803568 and MM Com are of W subtype while GSC 03950–00707, NSVS 4665041, MM Peg and NSVS 4751449 are of A subtype. This subclassification is well-determined for all totally-eclipsed binaries. The targets confirm the trends in which W-subtype systems have smaller periods and lower temperatures than A subtype binaries.

  16. W/O/W multiple emulsions with diclofenac sodium.

    PubMed

    Lindenstruth, Kai; Müller, Bernd W

    2004-11-01

    The disperse oil droplets of W/O/W multiple emulsions contain small water droplets, in which drugs could be incorporated, but the structure of these emulsions is also the reason for possible instability. Due to the middle oil phase which acts as a 'semipermeable' membrane the passage of water across the oil phase can take place. However, the emulsions have been produced in a two-step-production process so not only the leakage of encapsulated drug molecules out of the inner water phase during storage but also a production-induced reduction of the encapsulation rate should be considered. The aim of this study was to ascertain how far the production-induced reduction of the encapsulation rate relates to the size of inner water droplets and to evaluate the relevance of multiple emulsions as drug carrier for diclofenac sodium. Therefore multiple emulsions were produced according to a central composite design. During the second production step it was observed that the parameters pressure and temperature have an influence on the size of the oil droplets in the W/O/W multiple emulsions. Further experiments with different W/O emulsions resulted in W/O/W multiple emulsions with different encapsulation rates of diclofenac sodium, due to the different sizes of the inner water droplets, which were obtained in the first production step.

  17. Target and beam-target spin asymmetries in exclusive π + and π – electroproduction with 1.6- to 5.7-GeV electrons

    DOE PAGES

    Bosted, P. E.; Biselli, A. S.; Careccia, S.; ...

    2016-11-01

    Here, beam-target double-spin asymmetries and target single-spin asymmetries in exclusive π + and quasiexclusive π – electroproduction were obtained from scattering of 1.6- to 5.7-GeV longitudinally polarized electrons from longitudinally polarized protons (for π +) and deuterons (for π –) using the CEBAF Large Acceptance Spectrometer (CLAS) at Jefferson Lab. The kinematic range covered is 1.1 < W < 2.6 GeV and 0.05 < Q 2 < 5GeV 2, with good angular coverage in the forward hemisphere. The asymmetry results were divided into approximately 40 000 kinematic bins for π + from free protons and 15 000 bins for πmore » – production from bound nucleons in the deuteron. The present results are found to be in reasonable agreement with fits to previous world data for W < 1.7 GeV and Q 2 < 0.5GeV 2, with discrepancies increasing at higher values of Q 2, especially for W > 1.5 GeV. Very large target-spin asymmetries are observed for W > 1.6 GeV. When combined with cross-section measurements, the present results can provide powerful constraints on nucleon resonance amplitudes at moderate and large values of Q 2, for resonances with masses as high as 2.3 GeV.« less

  18. Cyclotron production of {sup 61}Cu using natural Zn and enriched {sup 64}Zn targets

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Asad, A. H.; Smith, S. V.; Chan, S.

    2012-12-19

    Copper-61 ({sup 61}Cu) shares with {sup 64}Cu certain advantages for PET diagnostic imaging, but has a shorter half-life (3.4hr vs. 12.7hr) and a greater probability of positron production per disintegration (61% vs. 17.9%). One important application is for in vivo imaging of hypoxic tissue. In this study {sup 61}Cu was produced using the {sup 64}Zn(p,{alpha}){sup 61}Cu reaction on natural Zn or enriched {sup 64}Zn targets. The enriched {sup 64}Zn (99.82%) was electroplated onto high purity gold or silver foils or onto thin Al discs. A typical target bombardment used 30{mu}A; at 11.7, 14.5 or 17.6MeV over 30-60min. The {sup 61}Cumore » (radiochemical purity of >95%) was separated using a combination of cation and anion exchange columns. The {sup 64}Zn target material was recovered after each run, for re-use. In a direct comparison with enriched {sup 64}Zn-target results, {sup 61}Cu production using the cheaper {sup nat}Zn target proved to be an effective alternative.« less

  19. Differential Evolution Optimization for Targeting Spacecraft Maneuver Plans

    NASA Technical Reports Server (NTRS)

    Mattern, Daniel

    2016-01-01

    Previous analysis identified specific orbital parameters as being safer for conjunction avoidance for the TDRS fleet. With TDRS-9 being considered an at-risk spacecraft, a potential conjunction concern was raised should TDRS-9 fail while at a longitude of 12W. This document summarizes the analysis performed to identify if these specific orbital parameters could be targeted using the remaining drift-termination maneuvers for the relocation of TDRS-9 from 41W longitude to 12W longitude.

  20. Effect of Ni +-ION bombardment on nickel and binary nickel alloys

    NASA Astrophysics Data System (ADS)

    Roarty, K. B.; Sprague, J. A.; Johnson, R. A.; Smidt, F. A.

    1981-03-01

    Pure nickel and four binary nickel alloys have been subjected to high energy Ni ion bombardment at 675, 625 and 525°C. After irradiation, each specimen was studied by transmission electron microscopy. The pure nickel control was found to swell appreciably (1 to 5%) and the Ni-Al and the Ni-Ti samples were found to swell at all temperatures, but to a lesser degree (0.01 to 0.35%). The Ni-Mo contained a significant density of voids only at 525° C, while swelling was suppressed at all temperatures in the Ni-Si alloy. The dislocation structure progressed from loops to tangles as temperature increased in all materials except the Ni-Ti, in which there was an absence of loops at all temperatures. Dislocation densities decreased as temperature increased in all samples. These results do not correlate well with the relative behavior of the same alloys observed after neutron irradiation at 455°C. The differences between these two sets of data appear to be caused by different mechanisms controlling void nucleation in ion and neutron irradiation of these alloys.

  1. Suppression of self-organized surface nanopatterning on GaSb/InAs multilayers induced by low energy oxygen ion bombardment by using simultaneously sample rotation and oxygen flooding

    NASA Astrophysics Data System (ADS)

    Beainy, Georges; Cerba, Tiphaine; Bassani, Franck; Martin, Mickaël; Baron, Thierry; Barnes, Jean-Paul

    2018-05-01

    Time of flight secondary ion mass spectrometry (ToF-SIMS) is a well-adapted analytical method for the chemical characterization of concentration profiles in layered or multilayered materials. However, under ion beam bombardment, initially smooth material surface becomes morphologically unstable. This leads to abnormal secondary ion yields and depth profile distortions. In this contribution, we explore the surface topography and roughening evolution induced by O2+ ion bombardment on GaSb/InAs multilayers. We demonstrate the formation of nanodots and ripples patterning according to the ion beam energy. Since the latter are undesirable for ToF-SIMS analysis, we managed to totally stop their growth by using simultaneously sample rotation and oxygen flooding. This unprecedented coupling between these two latter mechanisms leads to a significant enhancement in depth profiles resolution.

  2. Method of Generating Transient Equivalent Sink and Test Target Temperatures for Swift BAT

    NASA Technical Reports Server (NTRS)

    Choi, Michael K.

    2004-01-01

    The NASA Swift mission has a 600-km altitude and a 22 degrees maximum inclination. The sun angle varies from 45 degrees to 180 degrees in normal operation. As a result, environmental heat fluxes absorbed by the Burst Alert Telescope (BAT) radiator and loop heat pipe (LHP) compensation chambers (CCs) vary transiently. Therefore the equivalent sink temperatures for the radiator and CCs varies transiently. In thermal performance verification testing in vacuum, the radiator and CCs radiated heat to sink targets. This paper presents an analytical technique for generating orbit transient equivalent sink temperatures and a technique for generating transient sink target temperatures for the radiator and LHP CCs. Using these techniques, transient target temperatures for the radiator and LHP CCs were generated for three thermal environmental cases: worst hot case, worst cold case, and cooldown and warmup between worst hot case in sunlight and worst cold case in the eclipse, and three different heat transport values: 128 W, 255 W, and 382 W. The 128 W case assumed that the two LHPs transport 255 W equally to the radiator. The 255 W case assumed that one LHP fails so that the remaining LHP transports all the waste heat from the detector array to the radiator. The 382 W case assumed that one LHP fails so that the remaining LHP transports all the waste heat from the detector array to the radiator, and has a 50% design margin. All these transient target temperatures were successfully implemented in the engineering test unit (ETU) LHP and flight LHP thermal performance verification tests in vacuum.

  3. The formation of giant planets and its effects on protoplanetary disks: the case of Jupiter and the Jovian Early Bombardment

    NASA Astrophysics Data System (ADS)

    Turrini, D.; ISSI Team "Vesta, the key to the origins of the Solar System"; EChO "Planetary Formation" Working Group

    The formation of giant planets is accompanied by a short but intense primordial bombardment \\citep{safronov69,weidenschilling75,weidenschilling01,turrini11}: the prototype for this class of events is the Jovian Early Bombardment (JEB) caused by the formation of Jupiter in the Solar System \\citep{turrini11,turrini12}. The JEB affected the collisional evolution of the minor bodies in the inner Solar System by inflicting mass loss to planetesimals \\citep{turrini12,turrini14a,turrini14b} due to cratering erosion and, at the same time, delivering water and volatile materials to the asteroid belt \\citep{turrini14b}. The JEB also resulted in a significant number of collisions between Jupiter and planetesimals formed over a wide orbital range, delivering volatile and refractory materials to the giant planet and its circumplanetary disk \\citep{turrini14c}. In this talk I'll discuss how the study of the effects of the JEB on Vesta can be used to constrain the early evolution of the Solar System \\citep{turrini14a,turrini14b} and how these constraints can, in turn, provide insight on the composition of Jupiter and of its satellites. Finally, I'll discuss the implications of the JEB model for extrasolar planets \\citep{turrini14c}.

  4. Identification of NaK-ATPase inhibitors in human plasma as nonesterified fatty acids and lysophospholipids.

    PubMed

    Kelly, R A; O'Hara, D S; Mitch, W E; Smith, T W

    1986-09-05

    Elevated plasma levels of factors with cardiac glycoside-like activity have been implicated in the response to volume expansion in animals and in the pathogenesis of certain human diseases. We recently described four fractions (IR1, EI1, EI2, EI3) from normal human plasma that inhibit NaK-ATPase, displace ouabain from the enzyme, and exhibit digoxin-like immunoreactivity (Kelly, R. A., O'Hara, D. S., Canessa, M. L., Mitch, W. E., and Smith, T. W. (1985) J. Biol. Chem. 260, 11396-11405). In this report, we identify the active component of these plasma fractions as long-chain nonesterified fatty acids (NEFA) and lysophospholipids. These lipids were present in fractions EI1, EI2, and EI3 in quantities sufficient to account for all of the NaK-ATPase inhibitory activity. The digoxin-like immunoreactivity in fraction IR1 could be attributed to hydrocortisone and other endogenous steroids. To explore the nature of the lipid-NaK-ATPase interactions, we examined the effects of various ATP or sodium concentrations on the NaK-ATPase activity measured in the presence of NEFA. Varying sodium did not affect the inhibition of NaK-ATPase by linoleic acid. At less than 0.15 mM ATP, linoleic acid stimulated NaK-ATPase, but at higher ATP concentrations, the enzyme was progressively inhibited. In summary, NEFA and lysophospholipids, at levels similar to those occurring in human plasma, may account for all of the NaK-ATPase inhibitory activity observed in human plasma fractions. These lipids probably do not directly regulate NaK-ATPase in vivo under normal physiologic conditions, but may alter the sodium pump in disease states characterized by abnormalities in lipid metabolism or plasma protein binding.

  5. A mathematical analysis of multiple-target SELEX.

    PubMed

    Seo, Yeon-Jung; Chen, Shiliang; Nilsen-Hamilton, Marit; Levine, Howard A

    2010-10-01

    SELEX (Systematic Evolution of Ligands by Exponential Enrichment) is a procedure by which a mixture of nucleic acids can be fractionated with the goal of identifying those with specific biochemical activities. One combines the mixture with a specific target molecule and then separates the target-NA complex from the resulting reactions. The target-NA complex is separated from the unbound NA by mechanical means (such as by filtration), the NA is eluted from the complex, amplified by PCR (polymerase chain reaction), and the process repeated. After several rounds, one should be left with the nucleic acids that best bind to the target. The problem was first formulated mathematically in Irvine et al. (J. Mol. Biol. 222:739-761, 1991). In Levine and Nilsen-Hamilton (Comput. Biol. Chem. 31:11-25, 2007), a mathematical analysis of the process was given. In Vant-Hull et al. (J. Mol. Biol. 278:579-597, 1998), multiple target SELEX was considered. It was assumed that each target has a single nucleic acid binding site that permits occupation by no more than one nucleic acid. Here, we revisit Vant-Hull et al. (J. Mol. Biol. 278:579-597, 1998) using the same assumptions. The iteration scheme is shown to be convergent and a simplified algorithm is given. Our interest here is in the behavior of the multiple target SELEX process as a discrete "time" dynamical system. Our goal is to characterize the limiting states and their dependence on the initial distribution of nucleic acid and target fraction components. (In multiple target SELEX, we vary the target component fractions, but not their concentrations, as fixed and the initial pool of nucleic acids as a variable starting condition). Given N nucleic acids and a target consisting of M subtarget component species, there is an M × N matrix of affinities, the (i,j) entry corresponding to the affinity of the jth nucleic acid for the ith subtarget. We give a structure condition on this matrix that is equivalent to the following

  6. Stable Transformation of Ferns Using Spores as Targets: Pteris vittata and Ceratopteris thalictroides1[W][OPEN

    PubMed Central

    Muthukumar, Balasubramaniam; Joyce, Blake L.; Elless, Mark P.; Stewart, C. Neal

    2013-01-01

    Ferns (Pteridophyta) are very important members of the plant kingdom that lag behind other taxa with regards to our understanding of their genetics, genomics, and molecular biology. We report here, to our knowledge, the first instance of stable transformation of fern with recovery of transgenic sporophytes. Spores of the arsenic hyperaccumulating fern Pteris vittata and tetraploid ‘C-fern Express’ (Ceratopteris thalictroides) were stably transformed by Agrobacterium tumefaciens with constructs containing the P. vittata actin promoter driving a GUSPlus reporter gene. Reporter gene expression assays were performed on multiple tissues and growth stages of gametophytes and sporophytes. Southern-blot analysis confirmed stable transgene integration in recovered sporophytes and also confirmed that no plasmid from A. tumefaciens was present in the sporophyte tissues. We recovered seven independent transformants of P. vittata and four independent C. thalictroides transgenics. Inheritance analyses using β-glucuronidase (GUS) histochemical staining revealed that the GUS transgene was stably expressed in second generation C. thalictroides sporophytic tissues. In an independent experiment, the gusA gene that was driven by the 2× Cauliflower mosaic virus 35S promoter was bombarded into P. vittata spores using biolistics, in which putatively stable transgenic gametophytes were recovered. Transformation procedures required no tissue culture or selectable marker genes. However, we did attempt to use hygromycin selection, which was ineffective for recovering transgenic ferns. This simple stable transformation method should help facilitate functional genomics studies in ferns. PMID:23933990

  7. Influenza A Virus Hemagglutinin and Neuraminidase Mutually Accelerate Their Apical Targeting through Clustering of Lipid Rafts

    PubMed Central

    Ohkura, Takashi; Momose, Fumitaka; Ichikawa, Reiko; Takeuchi, Kaoru

    2014-01-01

    ABSTRACT In polarized epithelial cells, influenza A virus hemagglutinin (HA) and neuraminidase (NA) are intrinsically associated with lipid rafts and target the apical plasma membrane for viral assembly and budding. Previous studies have indicated that the transmembrane domain (TMD) and cytoplasmic tail (CT) of HA and NA are required for association with lipid rafts, but the raft dependencies of their apical targeting are controversial. Here, we show that coexpression of HA with NA accelerated their apical targeting through accumulation in lipid rafts. HA was targeted to the apical plasma membrane even when expressed alone, but the kinetics was much slower than that of HA in infected cells. Coexpression experiments revealed that apical targeting of HA and NA was accelerated by their coexpression. The apical targeting of HA was also accelerated by coexpression with M1 but not M2. The mutations in the outer leaflet of the TMD and the deletion of the CT in HA and NA that reduced their association with lipid rafts abolished the acceleration of their apical transport, indicating that the lipid raft association is essential for efficient apical trafficking of HA and NA. An in situ proximity ligation assay (PLA) revealed that HA and NA were accumulated and clustered in the cytoplasmic compartments only when both were associated with lipid rafts. Analysis with mutant viruses containing nonraft HA/NA confirmed these findings. We further analyzed lipid raft markers by in situ PLA and suggest a possible mechanism of the accelerated apical transport of HA and NA via clustering of lipid rafts. IMPORTANCE Lipid rafts serve as sites for viral entry, particle assembly, and budding, leading to efficient viral replication. The influenza A virus utilizes lipid rafts for apical plasma membrane targeting and particle budding. The hemagglutinin (HA) and neuraminidase (NA) of influenza virus, key players for particle assembly, contain determinants for apical sorting and lipid raft

  8. Electric Vehicle Technologies and Targets | Transportation Research | NREL

    Science.gov Websites

    . Table showing 2022 targets for decreases in battery cost ($125/kWh) and increases in battery capacity exchanger. Table showing 2022 targets for decreases in power electronics cost ($8/kW, $440 system cost) and , high performing, and long lasting. DOE has targeted a 75% reduction in battery cost and a 75% increase

  9. Hundreds MeV monoenergetic proton bunch from interaction of 10{sup 20-21} W/cm{sup 2} circularly polarized laser pulse with tailored complex target

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Zhang, Z. M.; Laser Fusion Research Center, CAEP, Mianyang 621900; He, X. T.

    A complex target (CT) configuration tailored for generating high quality proton bunch by circularly polarized laser pulses at intensities of 10{sup 20-21} W/cm{sup 2} is proposed. Two-dimensional particle-in-cell simulations show that both the collimation and mono-energetic qualities of the accelerated proton bunch obtained using a front-shaped thin foil can be greatly enhanced by the backside inhomogeneous plasma layer. The main mechanisms for improving the accelerated protons are identified and discussed. These include stabilization of the photon cavity, providing hole-boring supplementary acceleration and suppressing the thermal-electron effects. A theory for tailoring the CT parameters is also presented.

  10. Targeting BRAF V600E and Autophagy in Pediatric Brain Tumors

    DTIC Science & Technology

    2015-10-01

    AWARD NUMBER: W81XWH-14-1-0414 TITLE: Targeting BRAF V600E and Autophagy in Pediatric Brain Tumors PRINCIPAL INVESTIGATOR: Jean Mulcahy...29 Sep 2015 4. TITLE AND SUBTITLE 5a. CONTRACT NUMBER W81XWH-14-1-0414 Targeting BRAF V600E and Autophagy in Pediatric Brain Tumors 5b. GRANT...ABSTRACT 200 words most significant findings 15. SUBJECT TERMS autophagy , BRAF, brain tumor. pediatric 16. SECURITY CLASSIFICATION OF: 17

  11. Irritable bowel syndrome patients have SCN5A channelopathies that lead to decreased NaV1.5 current and mechanosensitivity.

    PubMed

    Strege, Peter R; Mazzone, Amelia; Bernard, Cheryl E; Neshatian, Leila; Gibbons, Simon J; Saito, Yuri A; Tester, David J; Calvert, Melissa L; Mayer, Emeran A; Chang, Lin; Ackerman, Michael J; Beyder, Arthur; Farrugia, Gianrico

    2018-04-01

    The SCN5A-encoded voltage-gated mechanosensitive Na + channel Na V 1.5 is expressed in human gastrointestinal smooth muscle cells and interstitial cells of Cajal. Na V 1.5 contributes to smooth muscle electrical slow waves and mechanical sensitivity. In predominantly Caucasian irritable bowel syndrome (IBS) patient cohorts, 2-3% of patients have SCN5A missense mutations that alter Na V 1.5 function and may contribute to IBS pathophysiology. In this study we examined a racially and ethnically diverse cohort of IBS patients for SCN5A missense mutations, compared them with IBS-negative controls, and determined the resulting Na V 1.5 voltage-dependent and mechanosensitive properties. All SCN5A exons were sequenced from somatic DNA of 252 Rome III IBS patients with diverse ethnic and racial backgrounds. Missense mutations were introduced into wild-type SCN5A by site-directed mutagenesis and cotransfected with green fluorescent protein into HEK-293 cells. Na V 1.5 voltage-dependent and mechanosensitive functions were studied by whole cell electrophysiology with and without shear force. Five of 252 (2.0%) IBS patients had six rare SCN5A mutations that were absent in 377 IBS-negative controls. Six of six (100%) IBS-associated Na V 1.5 mutations had voltage-dependent gating abnormalities [current density reduction (R225W, R433C, R986Q, and F1293S) and altered voltage dependence (R225W, R433C, R986Q, G1037V, and F1293S)], and at least one kinetic parameter was altered in all mutations. Four of six (67%) IBS-associated SCN5A mutations (R225W, R433C, R986Q, and F1293S) resulted in altered Na V 1.5 mechanosensitivity. In this racially and ethnically diverse cohort of IBS patients, we show that 2% of IBS patients harbor SCN5A mutations that are absent in IBS-negative controls and result in Na V 1.5 channels with abnormal voltage-dependent and mechanosensitive function. NEW & NOTEWORTHY The voltage-gated Na + channel Na V 1.5 contributes to smooth muscle physiology and electrical

  12. G W (Γ ) method without the Bethe-Salpeter equation for photoabsorption energies of spin-polarized systems

    NASA Astrophysics Data System (ADS)

    Isobe, Tomoharu; Kuwahara, Riichi; Ohno, Kaoru

    2018-06-01

    The one-shot G W method, beginning with the local density approximation (LDA), enables one to calculate photoemission and inverse photoemission spectra. In order to calculate photoabsorption spectra, one had to additionally solve the Bethe-Salpeter equation (BSE) for the two-particle (electron-hole) Green's function, which doubly induces evaluation errors. It has been recently reported that the G W +BSE method significantly underestimates the experimental photoabsorption energies (PAEs) of small molecules. In order to avoid these problems, we propose to apply the G W (Γ ) method not to the neutral ground state but to the cationic state to calculate PAEs without solving the BSE, which allows a rigorous one-to-one correspondence between the photoabsorption peak and the "extended" quasiparticle level. We applied the self-consistent linearized G W Γ method including the vertex correction Γ to our method, and found that this method gives the PAEs of B, Na3, and Li3 to within 0.1 eV accuracy.

  13. The radical SAM protein HemW is a heme chaperone.

    PubMed

    Haskamp, Vera; Karrie, Simone; Mingers, Toni; Barthels, Stefan; Alberge, François; Magalon, Axel; Müller, Katrin; Bill, Eckhard; Lubitz, Wolfgang; Kleeberg, Kirstin; Schweyen, Peter; Bröring, Martin; Jahn, Martina; Jahn, Dieter

    2018-02-16

    Radical S -adenosylmethionine (SAM) enzymes exist in organisms from all kingdoms of life, and all of these proteins generate an adenosyl radical via the homolytic cleavage of the S-C(5') bond of SAM. Of particular interest are radical SAM enzymes, such as heme chaperones, that insert heme into respiratory enzymes. For example, heme chaperones insert heme into target proteins but have been studied only for the formation of cytochrome c -type hemoproteins. Here, we report that a radical SAM protein, the heme chaperone HemW from bacteria, is required for the insertion of heme b into respiratory chain enzymes. As other radical SAM proteins, HemW contains three cysteines and one SAM coordinating an [4Fe-4S] cluster, and we observed one heme per subunit of HemW. We found that an intact iron-sulfur cluster was required for HemW dimerization and HemW-catalyzed heme transfer but not for stable heme binding. A bacterial two-hybrid system screen identified bacterioferritins and the heme-containing subunit NarI of the respiratory nitrate reductase NarGHI as proteins that interact with HemW. We also noted that the bacterioferritins potentially serve as heme donors for HemW. Of note, heme that was covalently bound to HemW was actively transferred to a heme-depleted, catalytically inactive nitrate reductase, restoring its nitrate-reducing enzyme activity. Finally, the human HemW orthologue radical SAM domain-containing 1 (RSAD1) stably bound heme. In conclusion, our findings indicate that the radical SAM protein family HemW/RSAD1 is a heme chaperone catalyzing the insertion of heme into hemoproteins. © 2018 by The American Society for Biochemistry and Molecular Biology, Inc.

  14. Origin of Si(LMM) Auger Electron Emission from Silicon and Si-Alloys by keV Ar+ Ion Bombardment

    NASA Astrophysics Data System (ADS)

    Iwami, Motohiro; Kim, Su Chol; Kataoka, Yoshihide; Imura, Takeshi; Hiraki, Akio; Fujimoto, Fuminori

    1980-09-01

    Si(LMM) Auger electrons emitted from specimens of pure silicon and several Si-alloys (Ni-Si, Pd-Si and Cu-Si) under keV Ar+ ion bombardment, were examined. In the Auger spectra from all specimens studied there were four peaks at energies of 92, 86, 76 and 66 eV. The Auger signal intensity varied considerably with both the incident angle and the energy of the primary ion beam. It is proposed that the Auger electrons are emitted from silicon atoms (or ions) just beneath the specimen surface but free from the bulk network.

  15. Exploring the Structure of the Voltage-gated Na+ Channel by an Engineered Drug Access Pathway to the Receptor Site for Local Anesthetics*

    PubMed Central

    Lukacs, Peter; Gawali, Vaibhavkumar S.; Cervenka, Rene; Ke, Song; Koenig, Xaver; Rubi, Lena; Zarrabi, Touran; Hilber, Karlheinz; Stary-Weinzinger, Anna; Todt, Hannes

    2014-01-01

    Despite the availability of several crystal structures of bacterial voltage-gated Na+ channels, the structure of eukaryotic Na+ channels is still undefined. We used predictions from available homology models and crystal structures to modulate an external access pathway for the membrane-impermeant local anesthetic derivative QX-222 into the internal vestibule of the mammalian rNaV1.4 channel. Potassium channel-based homology models predict amino acid Ile-1575 in domain IV segment 6 to be in close proximity to Lys-1237 of the domain III pore-loop selectivity filter. The mutation K1237E has been shown previously to increase the diameter of the selectivity filter. We found that an access pathway for external QX-222 created by mutations of Ile-1575 was abolished by the additional mutation K1237E, supporting the notion of a close spatial relationship between sites 1237 and 1575. Crystal structures of bacterial voltage-gated Na+ channels predict that the side chain of rNaV1.4 Trp-1531 of the domain IV pore-loop projects into the space between domain IV segment 6 and domain III pore-loop and, therefore, should obstruct the putative external access pathway. Indeed, mutations W1531A and W1531G allowed for exceptionally rapid access of QX-222. In addition, W1531G created a second non-selective ion-conducting pore, bypassing the outer vestibule but probably merging into the internal vestibule, allowing for control by the activation gate. These data suggest a strong structural similarity between bacterial and eukaryotic voltage-gated Na+ channels. PMID:24947510

  16. Novel Therapeutic Targets for Chronic Migraine

    DTIC Science & Technology

    2014-11-01

    A D Award Number: W81XWH-11-1-0646 TITLE: Novel Therapeutic Targets for Chronic Migraine PRINCIPAL INVESTIGATORS: Andrew Charles CONTRACTING...for Chronic Migraine 5a. CONTRACT NUMBER 5b. GRANT NUMBER W81XWH-11-1-0646 5c. PROGRAM ELEMENT NUMBER 6. AUTHOR(S) Andrew Charles, M.D. and Peter...Chronic migraine is a disabling disorder that affects millions of individuals worldwide, and may result from traumatic brain injury. The purpose of this

  17. Can T1 w/T2 w ratio be used as a myelin-specific measure in subcortical structures? Comparisons between FSE-based T1 w/T2 w ratios, GRASE-based T1 w/T2 w ratios and multi-echo GRASE-based myelin water fractions.

    PubMed

    Uddin, Md Nasir; Figley, Teresa D; Marrie, Ruth Ann; Figley, Chase R

    2018-03-01

    Given the growing popularity of T 1 -weighted/T 2 -weighted (T 1 w/T 2 w) ratio measurements, the objective of the current study was to evaluate the concordance between T 1 w/T 2 w ratios obtained using conventional fast spin echo (FSE) versus combined gradient and spin echo (GRASE) sequences for T 2 w image acquisition, and to compare the resulting T 1 w/T 2 w ratios with histologically validated myelin water fraction (MWF) measurements in several subcortical brain structures. In order to compare these measurements across a relatively wide range of myelin concentrations, whole-brain T 1 w magnetization prepared rapid acquisition gradient echo (MPRAGE), T 2 w FSE and three-dimensional multi-echo GRASE data were acquired from 10 participants with multiple sclerosis at 3 T. Then, after high-dimensional, non-linear warping, region of interest (ROI) analyses were performed to compare T 1 w/T 2 w ratios and MWF estimates (across participants and brain regions) in 11 bilateral white matter (WM) and four bilateral subcortical grey matter (SGM) structures extracted from the JHU_MNI_SS 'Eve' atlas. Although the GRASE sequence systematically underestimated T 1 w/T 2 w values compared to the FSE sequence (revealed by Bland-Altman and mountain plots), linear regressions across participants and ROIs revealed consistently high correlations between the two methods (r 2 = 0.62 for all ROIs, r 2 = 0.62 for WM structures and r 2 = 0.73 for SGM structures). However, correlations between either FSE-based or GRASE-based T 1 w/T 2 w ratios and MWFs were extremely low in WM structures (FSE-based, r 2 = 0.000020; GRASE-based, r 2 = 0.0014), low across all ROIs (FSE-based, r 2 = 0.053; GRASE-based, r 2 = 0.029) and moderate in SGM structures (FSE-based, r 2 = 0.20; GRASE-based, r 2 = 0.17). Overall, our findings indicated a high degree of correlation (but not equivalence) between FSE-based and GRASE-based T 1 w/T 2 w ratios, and low correlations between T 1 w/T 2 w ratios and MWFs. This

  18. Liquid Hydrogen Target Experience at SLAC

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Weisend, J.G.; Boyce, R.; Candia, A.

    2005-08-29

    Liquid hydrogen targets have played a vital role in the physics program at SLAC for the past 40 years. These targets have ranged from small ''beer can'' targets to the 1.5 m long E158 target that was capable of absorbing up to 800 W without any significant density changes. Successful use of these targets has required the development of thin wall designs, liquid hydrogen pumps, remote positioning and alignment systems, safety systems, control and data acquisition systems, cryogenic cooling circuits and heat exchangers. Detailed operating procedures have been created to ensure safety and operational reliability. This paper surveys the evolutionmore » of liquid hydrogen targets at SLAC and discusses advances in several of the enabling technologies that made these targets possible.« less

  19. Qubit-loss-free fusion of atomic W states via photonic detection

    NASA Astrophysics Data System (ADS)

    Ding, Cheng-Yun; Kong, Fan-Zhen; Yang, Qing; Yang, Ming; Cao, Zhuo-Liang

    2018-06-01

    In this paper, we propose two new qubit-loss-free (QLF) fusion schemes for W states in cavity QED system. Resonant interactions between atoms and single cavity mode constitute the main fusion mechanism, with which atomic |W_{n+m}> and |W_{n+m+q}> states can be generated, respectively, from a |Wn> and a |Wm>; and from a |Wn>, a |Wm> and a |Wq>, by detecting the cavity mode. The QLF property of the schemes makes them more efficient and simpler than the currently existing ones, and fewer intermediate steps and memory resources are required for generating a target large-scale W state. Furthermore, the fusion of atomic states can be realized via the detection on cavity mode rather than the much complicated atomic detection, which makes our schemes feasible. In addition, the analyses of the optimal resource cost and the experimental feasibility indicate that the present schemes are simple and efficient, and maybe implementable within the current experimental techniques.

  20. EphB1 as a Novel Drug Target to Combat Pain and Addiction

    DTIC Science & Technology

    2017-09-01

    AWARD NUMBER: W81XWH-14-1-0220 TITLE: EphB1 as a Novel Drug Target to Combat Pain and Addiction PRINCIPAL INVESTIGATOR: Mark Henkemeyer...as a Novel Drug Target to Combat Pain and Ad 5a. CONTRACT NUMBER EphB1 as a Novel Drug Target to Combat Pain and Addiction 5b. GRANT NUMBER W81XWH...identify small molecular weight drug -like compounds from a >200,000 complex library that antagonize EphB1 protein-protein interactions. While we