Sample records for waste characterization alternatives

  1. Alternative Radiological Characterization of Sealed Source TRU Waste for WIPP Disposal (LAUR-05-8776)

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Whitworth, J.; Pearson, M.; Feldman, A.

    2006-07-01

    The Offsite Source Recovery (OSR) Project at Los Alamos National Laboratory is now shipping transuranic (TRU) waste containers to the Waste Isolation Pilot Plant (WIPP) in New Mexico for disposal. Sealed source waste disposal has become possible in part because OSR personnel were able to obtain Environmental Protection Agency (EPA) and DOE-CBFO approval for an alternative radiological characterization procedure relying on acceptable knowledge (AK) and modeling, rather than on non-destructive assay (NDA) of each container. This is the first successful qualification of an 'alternate methodology' under the radiological characterization requirements of the WIPP Waste Acceptance Criteria (WAC) by any TRUmore » waste generator site. This paper describes the approach OSR uses to radiologically characterize its sealed source waste and the process by which it obtained certification of this approach. (authors)« less

  2. CHARACTERIZATION AND PH/EH-BASED LEACHING TESTS OF MINING WASTES CONTAINING MERCURY

    EPA Science Inventory

    This study was undertaken as a part of developing treatment alternatives for waste materials, primarily waste rock and roaster tailings, from sites contaminated with mercury (Hg) mining wastes. Leaching profiles of waste rock over a range of different pH and oxidation-reduction (...

  3. CHARACTERIZATION AND PH/EH-BASED LEACHING TESTS OF MINING WASTES CONTAINING MERCURY

    EPA Science Inventory

    This study was undertaken as a part of developing treatment alternatives for waste materials, primarily waste rock and roaster tailings, from sites contaminated with Mercury (Hg) mining wastes. Leaching profiles of waste rock over a range of different pH and oxidation-reduction ...

  4. Radiological Characterization Methodology of INEEL Stored RH-TRU Waste from ANL-E

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Rajiv N. Bhatt

    2003-02-01

    An Acceptable Knowledge (AK)-based radiological characterization methodology is being developed for RH TRU waste generated from ANL-E hot cell operations performed on fuel elements irradiated in the EBR-II reactor. The methodology relies on AK for composition of the fresh fuel elements, their irradiation history, and the waste generation and collection processes. Radiological characterization of the waste involves the estimates of the quantities of significant fission products and transuranic isotopes in the waste. Methods based on reactor and physics principles are used to achieve these estimates. Because of the availability of AK and the robustness of the calculation methods, the AK-basedmore » characterization methodology offers a superior alternative to traditional waste assay techniques. Using this methodology, it is shown that the radiological parameters of a test batch of ANL-E waste is well within the proposed WIPP Waste Acceptance Criteria limits.« less

  5. Radiological Characterization Methodology for INEEL-Stored Remote-Handled Transuranic (RH TRU) Waste from Argonne National Laboratory-East

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Kuan, P.; Bhatt, R.N.

    2003-01-14

    An Acceptable Knowledge (AK)-based radiological characterization methodology is being developed for RH TRU waste generated from ANL-E hot cell operations performed on fuel elements irradiated in the EBR-II reactor. The methodology relies on AK for composition of the fresh fuel elements, their irradiation history, and the waste generation and collection processes. Radiological characterization of the waste involves the estimates of the quantities of significant fission products and transuranic isotopes in the waste. Methods based on reactor and physics principles are used to achieve these estimates. Because of the availability of AK and the robustness of the calculation methods, the AK-basedmore » characterization methodology offers a superior alternative to traditional waste assay techniques. Using the methodology, it is shown that the radiological parameters of a test batch of ANL-E waste is well within the proposed WIPP Waste Acceptance Criteria limits.« less

  6. DOE Office of Scientific and Technical Information (OSTI.GOV)

    Mayberry, J.; Stelle, S.; O`Brien, M.

    The Mixed Waste Integrated Program Logic Diagram was developed to provide technical alternative for mixed wastes projects for the Office of Technology Development`s Mixed Waste Integrated Program (MWIP). Technical solutions in the areas of characterization, treatment, and disposal were matched to a select number of US Department of Energy (DOE) treatability groups represented by waste streams found in the Mixed Waste Inventory Report (MWIR).

  7. Characterization of the March 2017 Tank 15 Waste Removal Slurry Sample (Combination of Slurry Samples HTF-15-17-28 and HTF-15-17-29)

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Reboul, S. H.; King, W. D.; Coleman, C. J.

    2017-05-09

    Two March 2017 Tank 15 slurry samples (HTF-15-17-28 and HTF-15-17-29) were collected during the second bulk waste removal campaign and submitted to SRNL for characterization. At SRNL, the two samples were combined and then characterized by a series of physical, elemental, radiological, and ionic analysis methods. Sludge settling as a function of time was also quantified. The characterization results reported in this document are consistent with expectations based upon waste type, process knowledge, comparisons between alternate analysis techniques, and comparisons with the characterization results obtained for the November 2016 Tank 15 slurry sample (the sample collected during the first bulkmore » waste removal campaign).« less

  8. Screening tests for hazard classification of complex waste materials - Selection of methods

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Weltens, R., E-mail: reinhilde.weltens@vito.be; Vanermen, G.; Tirez, K.

    In this study we describe the development of an alternative methodology for hazard characterization of waste materials. Such an alternative methodology for hazard assessment of complex waste materials is urgently needed, because the lack of a validated instrument leads to arbitrary hazard classification of such complex waste materials. False classification can lead to human and environmental health risks and also has important financial consequences for the waste owner. The Hazardous Waste Directive (HWD) describes the methodology for hazard classification of waste materials. For mirror entries the HWD classification is based upon the hazardous properties (H1-15) of the waste which canmore » be assessed from the hazardous properties of individual identified waste compounds or - if not all compounds are identified - from test results of hazard assessment tests performed on the waste material itself. For the latter the HWD recommends toxicity tests that were initially designed for risk assessment of chemicals in consumer products (pharmaceuticals, cosmetics, biocides, food, etc.). These tests (often using mammals) are not designed nor suitable for the hazard characterization of waste materials. With the present study we want to contribute to the development of an alternative and transparent test strategy for hazard assessment of complex wastes that is in line with the HWD principles for waste classification. It is necessary to cope with this important shortcoming in hazardous waste classification and to demonstrate that alternative methods are available that can be used for hazard assessment of waste materials. Next, by describing the pros and cons of the available methods, and by identifying the needs for additional or further development of test methods, we hope to stimulate research efforts and development in this direction. In this paper we describe promising techniques and argument on the test selection for the pilot study that we have performed on different types of waste materials. Test results are presented in a second paper. As the application of many of the proposed test methods is new in the field of waste management, the principles of the tests are described. The selected tests tackle important hazardous properties but refinement of the test battery is needed to fulfil the a priori conditions.« less

  9. Destructive testings: dry drilling operations with TruPro system to collect samples in a powder form, from two hulls containing immobilized wastes in a hydraulic binder

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Pombet, Denis; Desnoyers, Yvon; Charters, Grant

    2013-07-01

    The TruPro{sup R} process enables to collect a significant number of samples to characterize radiological materials. This innovative and alternative technique is experimented for the ANDRA quality-control inspection of cemented packages. It proves to be quicker and more prolific than the current methodology. Using classical statistics and geo-statistics approaches, the physical and radiological characteristics of two hulls containing immobilized wastes (sludges or concentrates) in a hydraulic binder are assessed in this paper. The waste homogeneity is also evaluated in comparison to ANDRA criterion. Sensibility to sample size (support effect), presence of extreme values, acceptable deviation rate and minimum number ofmore » data are discussed. The final objectives are to check the homogeneity of the two characterized radwaste packages and also to validate and reinforce this alternative characterization methodology. (authors)« less

  10. Importance of geologic characterization of potential low-level radioactive waste disposal sites

    USGS Publications Warehouse

    Weibel, C.P.; Berg, R.C.

    1991-01-01

    Using the example of the Geff Alternative Site in Wayne County, Illinois, for the disposal of low-level radioactive waste, this paper demonstrates, from a policy and public opinion perspective, the importance of accurately determining site stratigraphy. Complete and accurate characterization of geologic materials and determination of site stratigraphy at potential low-level waste disposal sites provides the frame-work for subsequent hydrologic and geochemical investigations. Proper geologic characterization is critical to determine the long-term site stability and the extent of interactions of groundwater between the site and its surroundings. Failure to adequately characterize site stratigraphy can lead to the incorrect evaluation of the geology of a site, which in turn may result in a lack of public confidence. A potential problem of lack of public confidence was alleviated as a result of the resolution and proper definition of the Geff Alternative Site stratigraphy. The integrity of the investigation was not questioned and public perception was not compromised. ?? 1991 Springer-Verlag New York Inc.

  11. Emissions from Open Burning of Simulated Military Waste from Forward Operating Bases

    EPA Science Inventory

    Emissions from open burning of simulated military waste from forward operating bases (FOBs) were extensively characterized as an initial step in assessing potential inhalation exposure of FOB personnel and future disposal alternatives. Emissions from two different burning scenar...

  12. Valorization of titanium metal wastes as tanning agent used in leather industry

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Crudu, Marian, E-mail: mariancrudu@yahoo.com; Deselnicu, Viorica, E-mail: viorica.deselnicu@icpi.ro; Deselnicu, Dana Corina, E-mail: d_deselnicu@yahoo.com

    2014-10-15

    Highlights: • Valorization of titanium wastes which cannot be recycled in metallurgical industry. • Transferring Ti waste into raw materials for obtaining Ti based tanning agent. • Characterization of new Ti based tanning agents and leather tanned with them. • Characterization of sewage waste water and sludge resulted from leather manufacture. • Analysis of the impact of main metal component of Ti waste. - Abstract: The development of new tanning agents and new technologies in the leather sector is required to cope with the increasingly higher environmental pressure on the current tanning materials and processes such as tanning with chromiummore » salts. In this paper, the use of titanium wastes (cuttings) resulting from the process of obtaining highly pure titanium (ingots), for the synthesis of new tanning agent and tanning bovine hides with new tanning agent, as alternative to tanning with chromium salts are investigated. For this purpose, Ti waste and Ti-based tanning agent were characterized for metal content by inductively coupled plasma mass spectrometry (ICP-MS) and chemical analysis; the tanned leather (wet white leather) was characterized by Scanning Electron Microscope/Energy Dispersive Using X-ray (Analysis). SEM/EDX analysis for metal content; Differential scanning calorimetric (DSC), Micro-Hot-Table and standard shrinkage temperature showing a hydrothermal stability (ranged from 75.3 to 77 °C) and chemical analysis showing the leather is tanned and can be processed through the subsequent mechanical operations (splitting, shaving). On the other hand, an analysis of major minor trace substances from Ti-end waste (especially vanadium content) in new tanning agent and wet white leather (not detected) and residue stream was performed and showed that leachability of vanadium is acceptable. The results obtained show that new tanning agent obtained from Ti end waste can be used for tanning bovine hides, as eco-friendly alternative for chrome tanning.« less

  13. Proceedings of the tenth annual DOE low-level waste management conference: Session 2: Site performance assessment

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Not Available

    1988-12-01

    This document contains twelve papers on various aspects of low-level radioactive waste management. Topics of this volume include: performance assessment methodology; remedial action alternatives; site selection and site characterization procedures; intruder scenarios; sensitivity analysis procedures; mathematical models for mixed waste environmental transport; and risk assessment methodology. Individual papers were processed separately for the database. (TEM)

  14. Characterization of a polyhydroxyalkanoate obtained from pineapple peel waste using Ralsthonia eutropha.

    PubMed

    Vega-Castro, Oscar; Contreras-Calderon, Jose; León, Emilson; Segura, Almir; Arias, Mario; Pérez, León; Sobral, Paulo J A

    2016-08-10

    Agro-industrial waste can be the production source of biopolymers such as polyhydroxyalkanoates. The aim of this study was to produce and characterize Polyhydroxyalkanoates produced from pineapple peel waste fermentation processes. The methodology includes different pineapple peel waste fermentation conditions. The produced biopolymer was characterized using FTIR, GC-MS and NMR. The best fermentation condition for biopolymer production was obtained using pH 9, Carbon/Nitrogen 11, carbon/phosphorus 6 and fermentation time of 60h. FTIR analyzes showed PHB group characteristics, such as OH, CH and CO. In addition, GC-MS showed two monomers with 4 and 8 carbons, referred to PHB and PHBHV. H(1) NMR analysis showed 0.88-0.97 and 5.27ppm signals, corresponding to CH3 and CH, respectively. In conclusion, polyhydroxyalkanoate production from pineapple peels waste is an alternative for the treatment of waste generated in Colombia's fruit industry. Copyright © 2016 Elsevier B.V. All rights reserved.

  15. CHARACTERIZING SOILS FOR HAZAROUDS WASTE SITE ASSESSMENTS

    EPA Science Inventory

    The purpose of this paper is to provide guidance to Remedial Project Managers (RPM) and On-Scene Coordinators (OSC) concerning soil characterization data types required for decision-making in the CERCLA RI/FS process related to risk assessment and remedial alternative evaluation ...

  16. Production, characterization and fuel properties of alternative diesel fuel from pyrolysis of waste plastic grocery bags

    USDA-ARS?s Scientific Manuscript database

    Pyrolysis of HDPE waste grocery bags followed by distillation resulted in a liquid hydrocarbon mixture that consisted of saturated aliphatic paraffins (96.8%), aliphatic olefins (2.6%), and aromatics (0.6%) that corresponded to the boiling range of conventional petroleum diesel fuel (#1 diesel 182–2...

  17. The mixed low-level waste problem in BE/NWN capsule

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Hensley, D.C.

    1999-07-01

    The Boh Environmental, LLC (BE) and Northwest Nuclear, LLC (NWN) program addresses the problem of diminishing capacity in the United States to store mixed waste. A lack of an alternative program has caused the US Department of Energy (DOE) to indefinitely store all of its mixed waste in Resource Conservation and Recovery Act (RCRA) compliant storage facilities. Unfortunately, this capacity is fast approaching the administrative control limit. The combination of unique BE encapsulation and NWN waste characterization technologies provides an effective solution to DOE's mixed-waste dilemma. The BE ARROW-PAK technique encapsulates mixed low-level waste (MLLW) in extra-high molecular weight, high-densitymore » polyethylene, pipe-grade resin cylinders. ARROW-PAK applications include waste treatment, disposal, transportation (per 49 CFR 173), vault encasement, and interim/long-term storage for 100 to 300 yr. One of the first demonstrations of this treatment/storage technique successfully treated 880 mixed-waste debris drums at the DOE Hanford Site in 1997. NWN, deploying the APNea neutron assay technology, provides the screening and characterization capability necessary to ensure that radioactive waste is correctly categorized as either transuranic (TRU) or LLW. MLLW resulting from D and D activities conducted at the Oak Ridge East Tennessee Technology Park will be placed into ARROW-PAK containers following comprehensive characterization of the waste by NWN. The characterized and encapsulated waste will then be shipped to a commercial disposal facility, where the shipments meet all waste acceptance criteria of the disposal facility including treatment criteria.« less

  18. Development of Alternative Technetium Waste Forms

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Czerwinski, Kenneth

    2013-09-13

    The UREX+1 process is under consideration for the separation of transuranic elements from spent nuclear fuel. The first steps of this process extract the fission product technicium-99 ({sup 99}Tc) into an organic phase containing tributylphosphate together with uranium. Treatment of this stream requires the separation of Tc from U and placement into a suitable waste storage form. A potential candidate waste form involves immobilizing the Tc as an alloy with either excess metallic zirconium or stainless steel. Although Tc-Zr alloys seem to be promising waste forms, alternative materials must be investigated. Innovative studies related to the synthesis and behavior ofmore » a different class of Tc materials will increase the scientific knowledge related to development of Tc waste forms. These studies will also provide a better understanding of the behavior of {sup 99}Tc in repository conditions. A literature survey has selected promising alternative waste forms for further study: technetium metallic alloys, nitrides, oxides, sulfides, and pertechnetate salts. The goals of this project are to 1) synthesize and structurally characterize relevant technetium materials that may be considered as waste forms, 2) investigate material behavior in solution under different conditions of temperature, electrochemical potential, and radiation, and 3) predict the long-term behavior of these materials.« less

  19. Final report on cermet high-level waste forms

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Kobisk, E.H.; Quinby, T.C.; Aaron, W.S.

    1981-08-01

    Cermets are being developed as an alternate method for the fixation of defense and commercial high level radioactive waste in a terminal disposal form. Following initial feasibility assessments of this waste form, consisting of ceramic particles dispersed in an iron-nickel base alloy, significantly improved processing methods were developed. The characterization of cermets has continued through property determinations on samples prepared by various methods from a variety of simulated and actual high-level wastes. This report describes the status of development of the cermet waste form as it has evolved since 1977. 6 tables, 18 figures.

  20. DOE Office of Scientific and Technical Information (OSTI.GOV)

    Moghissi, A.A.; Blauvelt, R.K.; Benda, G.A.

    This volume contains the peer-reviewed and edited versions of papers submitted for presentation a the Second International Mixed Waste Symposium. Following the tradition of the First International Mixed Waste Symposium, these proceedings were prepared in advance of the meeting for distribution to participants. The symposium was organized by the Mixed Waste Committee of the American Society of Mechanical Engineers. The topics discussed at the symposium include: stabilization technologies, alternative treatment technologies, regulatory issues, vitrification technologies, characterization of wastes, thermal technologies, laboratory and analytical issues, waste storage and disposal, organic treatment technologies, waste minimization, packaging and transportation, treatment of mercury contaminatedmore » wastes and bioprocessing, and environmental restoration. Individual abstracts are catalogued separately for the data base.« less

  1. Combustion quality analysis of briquettes from variety of agricultural waste as source of alternative fuels

    NASA Astrophysics Data System (ADS)

    Suryaningsih, S.; Nurhilal, O.; Yuliah, Y.; Mulyana, C.

    2017-05-01

    The increasing in world population and the industrial sector led to increased demand for energy sources. To do this by utilizing the agricultural waste as a fuel source of alternative energy in the form of bio briquette. The aim at this study was to obtain data onto the characteristics of a wide variety of biomass briquettes from waste agricultural industry. The basic ingredients used are biomass waste from coconut husks, sawdust, rice husks and coffee husks. Each of these biomass residues are dried, crushed, then mixed with starch adhesives. This mixture is molded and dried using sunlight. Each type of briquettes was characterized and analyzed the physical-chemical properties, including calorific value, water content, fixed carbon content and the results were compared with charcoal and coal that was used as fuel in public. The results showed that bio briquettes from coconut husks get the highest calorific value of 4,451 cal/g.

  2. Targeted Health Assessment for Wastes Contained at the Niagara Falls Storage Site to Guide Planning for Remedial Action Alternatives - 13428

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Busse, John; Keil, Karen; Staten, Jane

    2013-07-01

    The U.S. Army Corps of Engineers (USACE) is evaluating potential remedial alternatives at the 191-acre Niagara Falls Storage Site (NFSS) in Lewiston, New York, under the Formerly Utilized Sites Remedial Action Program (FUSRAP). The Manhattan Engineer District (MED) and Atomic Energy Commission (AEC) brought radioactive wastes to the site during the 1940's and 1950's, and the U.S. Department of Energy (US DOE) consolidated these wastes into a 10-acre interim waste containment structure (IWCS) in the southwest portion of the site during the 1980's. The USACE is evaluating remedial alternatives for radioactive waste contained within the IWCS at the NFSS undermore » the Feasibility Study phase of the Comprehensive Environmental Response, Compensation, and Liability Act (CERCLA) process. A preliminary evaluation of the IWCS has been conducted to assess potential airborne releases associated with uncovered wastes, particularly during waste excavation, as well as direct exposures to uncovered wastes. Key technical issues for this assessment include: (1) limitations in waste characterization data; (2) representative receptors and exposure routes; (3) estimates of contaminant emissions at an early stage of the evaluation process; (4) consideration of candidate meteorological data and air dispersion modeling approaches; and (5) estimates of health effects from potential exposures to both radionuclides and chemicals that account for recent updates of exposure and toxicity factors. Results of this preliminary health risk assessment indicate if the wastes were uncovered and someone stayed at the IWCS for a number of days to weeks, substantial doses and serious health effects could be incurred. Current controls prevent such exposures, and the controls that would be applied to protect onsite workers during remedial action at the IWCS would also effectively protect the public nearby. This evaluation provides framing context for the upcoming development and detailed evaluation of remedial alternatives for the IWCS. (authors)« less

  3. Mixed waste focus area alternative technologies workshop

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Borduin, L.C.; Palmer, B.A.; Pendergrass, J.A.

    1995-05-24

    This report documents the Mixed Waste Focus Area (MWFA)-sponsored Alternative Technology Workshop held in Salt Lake City, Utah, from January 24--27, 1995. The primary workshop goal was identifying potential applications for emerging technologies within the Options Analysis Team (OAT) ``wise`` configuration. Consistent with the scope of the OAT analysis, the review was limited to the Mixed Low-Level Waste (MLLW) fraction of DOE`s mixed waste inventory. The Los Alamos team prepared workshop materials (databases and compilations) to be used as bases for participant review and recommendations. These materials derived from the Mixed Waste Inventory Report (MWIR) data base (May 1994), themore » Draft Site Treatment Plan (DSTP) data base, and the OAT treatment facility configuration of December 7, 1994. In reviewing workshop results, the reader should note several caveats regarding data limitations. Link-up of the MWIR and DSTP data bases, while representing the most comprehensive array of mixed waste information available at the time of the workshop, requires additional data to completely characterize all waste streams. A number of changes in waste identification (new and redefined streams) occurred during the interval from compilation of the data base to compilation of the DSTP data base with the end result that precise identification of radiological and contaminant characteristics was not possible for these streams. To a degree, these shortcomings compromise the workshop results; however, the preponderance of waste data was linked adequately, and therefore, these analyses should provide useful insight into potential applications of alternative technologies to DOE MLLW treatment facilities.« less

  4. Solid waste from leather industry as adsorbent of organic dyes in aqueous-medium.

    PubMed

    Oliveira, Luiz C A; Gonçalves, Maraísa; Oliveira, Diana Q L; Guerreiro, Mário C; Guilherme, Luiz R G; Dallago, Rogério M

    2007-03-06

    The industrial tanning of leather usually produces considerable amounts of chromium-containing solid waste and liquid effluents and raises many concerns on its environmental effect as well as on escalating landfill costs. Actually, these shortcomings are becoming increasingly a limiting factor to this industrial activity that claims for alternative methods of residue disposals. In this work, it is proposed a novel alternative destination of the solid waste, based on the removal of organic contaminants from the out coming aqueous-residue. The adsorption isotherm pattern for the wet blue leather from the Aurea tanning industry in Erechim-RS (Brazil) showed that these materials present high activity on adsorbing the reactive red textile dye as well as other compounds. The adsorbent materials were characterized by IR spectroscopy and SEM and tested for the dye adsorption (reactive textile and methylene blue dyes). The concentrations of dyes were measured by UV-vis spectrophotometry and the chromium extraction from leather waste was realized by basic hydrolysis and determined by atomic absorption. As a low cost abundant adsorbent material with high adsorption ability on removing dye methylene blue (80mgg(-1)) and textile dye reactive red (163mgg(-1)), the leather waste is revealed to be a interesting alternative relatively to more costly adsorbent materials.

  5. Anaerobic co-digestion of commercial food waste and dairy manure: Characterizing biochemical parameters and synergistic effects.

    PubMed

    Ebner, Jacqueline H; Labatut, Rodrigo A; Lodge, Jeffrey S; Williamson, Anahita A; Trabold, Thomas A

    2016-06-01

    Anaerobic digestion of commercial food waste is a promising alternative to landfilling commercial food waste. This study characterized 11 types of commercial food wastes and 12 co-digestion blends. Bio-methane potential, biodegradable fraction, and apparent first-order hydrolysis rate coefficients were reported based upon biochemical methane potential (BMP) assays. Food waste bio-methane potentials ranged from 165 to 496 mL CH4/g VS. Substrates high in lipids or readily degradable carbohydrates showed the highest methane production. Average bio-methane potential observed for co-digested substrates was -5% to +20% that of the bio-methane potential of the individual substrates weighted by VS content. Apparent hydrolysis rate coefficients ranged from 0.19d(-1) to 0.65d(-1). Co-digested substrates showed an accelerated apparent hydrolysis rate relative to the weighted average of individual substrate rates. These results provide a database of key bio-digestion parameters to advance modeling and utilization of commercial food waste in anaerobic digestion. Copyright © 2016 Elsevier Ltd. All rights reserved.

  6. Valorization of titanium metal wastes as tanning agent used in leather industry.

    PubMed

    Crudu, Marian; Deselnicu, Viorica; Deselnicu, Dana Corina; Albu, Luminita

    2014-10-01

    The development of new tanning agents and new technologies in the leather sector is required to cope with the increasingly higher environmental pressure on the current tanning materials and processes such as tanning with chromium salts. In this paper, the use of titanium wastes (cuttings) resulting from the process of obtaining highly pure titanium (ingots), for the synthesis of new tanning agent and tanning bovine hides with new tanning agent, as alternative to tanning with chromium salts are investigated. For this purpose, Ti waste and Ti-based tanning agent were characterized for metal content by inductively coupled plasma mass spectrometry (ICP-MS) and chemical analysis; the tanned leather (wet white leather) was characterized by Scanning Electron Microscope/Energy Dispersive Using X-ray (Analysis). SEM/EDX analysis for metal content; Differential scanning calorimetric (DSC), Micro-Hot-Table and standard shrinkage temperature showing a hydrothermal stability (ranged from 75.3 to 77°C) and chemical analysis showing the leather is tanned and can be processed through the subsequent mechanical operations (splitting, shaving). On the other hand, an analysis of major minor trace substances from Ti-end waste (especially vanadium content) in new tanning agent and wet white leather (not detected) and residue stream was performed and showed that leachability of vanadium is acceptable. The results obtained show that new tanning agent obtained from Ti end waste can be used for tanning bovine hides, as eco-friendly alternative for chrome tanning. Copyright © 2014 Elsevier Ltd. All rights reserved.

  7. Food waste and the food-energy-water nexus: A review of food waste management alternatives.

    PubMed

    Kibler, Kelly M; Reinhart, Debra; Hawkins, Christopher; Motlagh, Amir Mohaghegh; Wright, James

    2018-04-01

    Throughout the world, much food produced is wasted. The resource impact of producing wasted food is substantial; however, little is known about the energy and water consumed in managing food waste after it has been disposed. Herein, we characterize food waste within the Food-Energy-Water (FEW) nexus and parse the differential FEW effects of producing uneaten food and managing food loss and waste. We find that various food waste management options, such as waste prevention, landfilling, composting, anaerobic digestion, and incineration, present variable pathways for FEW impacts and opportunities. Furthermore, comprehensive sustainable management of food waste will involve varied mechanisms and actors at multiple levels of governance and at the level of individual consumers. To address the complex food waste problem, we therefore propose a "food-waste-systems" approach to optimize resources within the FEW nexus. Such a framework may be applied to devise strategies that, for instance, minimize the amount of edible food that is wasted, foster efficient use of energy and water in the food production process, and simultaneously reduce pollution externalities and create opportunities from recycled energy and nutrients. Characterization of FEW nexus impacts of wasted food, including descriptions of dynamic feedback behaviors, presents a significant research gap and a priority for future work. Large-scale decision making requires more complete understanding of food waste and its management within the FEW nexus, particularly regarding post-disposal impacts related to water. Copyright © 2018 Elsevier Ltd. All rights reserved.

  8. Life cycle comparison of waste-to-energy alternatives for municipal waste treatment in Chilean Patagonia.

    PubMed

    Bezama, Alberto; Douglas, Carla; Méndez, Jacqueline; Szarka, Nóra; Muñoz, Edmundo; Navia, Rodrigo; Schock, Steffen; Konrad, Odorico; Ulloa, Claudia

    2013-10-01

    The energy system in the Region of Aysén, Chile, is characterized by a strong dependence on fossil fuels, which account for up to 51% of the installed capacity. Although the implementation of waste-to-energy concepts in municipal waste management systems could support the establishment of a more fossil-independent energy system for the region, previous studies have concluded that energy recovery systems are not suitable from an economic perspective in Chile. Therefore, this work intends to evaluate these technical options from an environmental perspective, using life cycle assessment as a tool for a comparative analysis, considering Coyhaique city as a case study. Three technical alternatives were evaluated: (i) landfill gas recovery and flaring without energy recovery; (ii) landfill gas recovery and energy use; and (iii) the implementation of an anaerobic digestion system for the organic waste fraction coupled with energy recovery from the biogas produced. Mass and energy balances of the three analyzed alternatives have been modeled. The comparative LCA considered global warming potential, abiotic depletion and ozone layer depletion as impact categories, as well as required raw energy and produced energy as comparative regional-specific indicators. According to the results, the use of the recovered landfill gas as an energy source can be identified as the most environmentally appropriate solution for Coyhaique, especially when taking into consideration the global impact categories.

  9. Final Environmental Impact Statement for Treating Transuranic (TRU)/Alpha Low-level Waste at the Oak Ridge National Laboratory Oak Ridge, Tennessee

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    N /A

    2000-06-30

    The DOE proposes to construct, operate, and decontaminate/decommission a TRU Waste Treatment Facility in Oak Ridge, Tennessee. The four waste types that would be treated at the proposed facility would be remote-handled TRU mixed waste sludge, liquid low-level waste associated with the sludge, contact-handled TRU/alpha low-level waste solids, and remote-handled TRU/alpha low-level waste solids. The mixed waste sludge and some of the solid waste contain metals regulated under the Resource Conservation and Recovery Act and may be classified as mixed waste. This document analyzes the potential environmental impacts associated with five alternatives--No Action, the Low-Temperature Drying Alternative (Preferred Alternative), themore » Vitrification Alternative, the Cementation Alternative, and the Treatment and Waste Storage at Oak Ridge National Laboratory (ORNL) Alternative.« less

  10. Feasibility of disposing waste glyphosate neutralization liquor with cement rotary kiln.

    PubMed

    Bai, Y; Bao, Y B; Cai, X L; Chen, C H; Ye, X C

    2014-08-15

    The waste neutralization liquor generated during the glyphosate production using glycine-dimethylphosphit process is a severe pollution problem due to its high salinity and organic components. The cement rotary kiln was proposed as a zero discharge strategy of disposal. In this work, the waste liquor was calcinated and the mineralogical phases of residue were characterized by scanning electron microscope (SEM) and X-ray diffraction (XRD). The mineralogical phases and the strength of cement clinker were characterized to evaluate the influence to the products. The burnability of cement raw meal added with waste liquor and the calorific value of waste liquor were tested to evaluate the influence to the thermal state of the kiln system. The results showed that after the addition of this liquor, the differences of the main phases and the strength of cement clinker were negligible, the burnability of raw meal was improved; and the calorific value of this liquor was 6140 J/g, which made it could be considered as an alternative fuel during the actual production. Copyright © 2014 Elsevier B.V. All rights reserved.

  11. Characterization of Technetium Speciation in Cast Stone

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Um, Wooyong; Jung, Hun Bok; Wang, Guohui

    2013-11-11

    This report describes the results from laboratory tests performed at Pacific Northwest National Laboratory (PNNL) for the U.S. Department of Energy (DOE) EM-31 Support Program (EMSP) subtask, “Production and Long-Term Performance of Low Temperature Waste Forms” to provide additional information on technetium (Tc) speciation characterization in the Cast Stone waste form. To support the use of Cast Stone as an alternative to vitrification for solidifying low-activity waste (LAW) and as the current baseline waste form for secondary waste streams at the Hanford Site, additional understanding of Tc speciation in Cast Stone is needed to predict the long-term Tc leachability frommore » Cast Stone and to meet the regulatory disposal-facility performance requirements for the Integrated Disposal Facility (IDF). Characterizations of the Tc speciation within the Cast Stone after leaching under various conditions provide insights into how the Tc is retained and released. The data generated by the laboratory tests described in this report provide both empirical and more scientific information to increase our understanding of Tc speciation in Cast Stone and its release mechanism under relevant leaching processes for the purpose of filling data gaps and to support the long-term risk and performance assessments of Cast Stone in the IDF at the Hanford Site.« less

  12. Characterization of industrial wastes as raw materials for Emulsified Modified Bitumen (EMB) formulation

    NASA Astrophysics Data System (ADS)

    Najib Razali, Mohd; Isa, Syarifah Nur Ezatie Mohd; Salehan, Noor Adilah Md; Musa, Musfafikri; Aziz, Mohd Aizudin Abd; Nour, Abdurahman Hamid; Yunus, Rosli Mohd

    2018-04-01

    This study was conducted to characterize industrial wastes for formulation of emulsified modified bitumen (EMB) in relation to their physical characteristic and elemental composition. This analysis will give information either raw materials from industrial wastes can be used for EMB formulation. Bitumen is produced from crude oil that is extracted from the ground which categorizes the crude oil as one of the non-renewable form of product. A vast environmental problem issues arises in Malaysia cause by the excessive manufacturing activity that lead to a miss-management of industrial waste has leads to the used of industrial waste in the EMB formulation. Industrial waste such as polystyrene, polyethylene and used automotive oil can be used as alternative to formulate bitumen. Then a suitable emulsifier needs to be added to produce the final product which is EMB. The emulsifier will yield a charge depends on its properties to bind the oily bitumen with water. Physical characteristic studies were performed by thermogravimetric Analysis (TGA), differential scanning calorimetry (DSC), flash point test, density rest and moisture content test. Fourier Transform Infrared Spectroscopy (FTIR) analysis was measured to determine the material’s molecular composition and structure.

  13. Isolation and characterization of onion degrading bacteria from onion waste produced in South Buenos Aires province, Argentina.

    PubMed

    Rinland, María Emilia; Gómez, Marisa Anahí

    2015-03-01

    Onion production in Argentina generates a significant amount of waste. Finding an effective method to recycle it is a matter of environmental concern. Among organic waste reuse techniques, anaerobic digestion could be a valuable alternative to current practices. Substrate inoculation with appropriate bacterial strains enhances the rate-limiting step (hydrolysis) of anaerobic digestion of biomass wastes. Selection of indigenous bacteria with the ability to degrade onion waste could be a good approach to find a suitable bioaugmentation or pretreatment agent. We isolated bacterial strains from onion waste in different degradation stages and from different localities. In order to characterize and select the best candidates, we analyzed the growth patterns of the isolates in a medium prepared with onion juice as the main source of nutrients and we evaluated carbon source utilization. Nine strains were selected to test their ability to grow using onion tissue and the five most remarkable ones were identified by 16S rRNA gene sequencing. Strains belonged to the genera Pseudoxanthomonas, Bacillus, Micrococcus and Pseudomonas. Two strains, Bacillus subtilis subsp. subtillis MB2-62 and Pseudomonas poae VE-74 have characteristics that make them promising candidates for bioaugmentation or pretreatment purposes.

  14. Synthesis and characterization of black ceramic pigments by recycling of two hazardous wastes

    NASA Astrophysics Data System (ADS)

    Du, Minxing; Du, Yi; Chen, Zhongtao; Li, Zhongfu; Yang, Kai; Lv, Xingjie; Feng, Yibing

    2017-09-01

    In this study, two different industrial wastes, namely vanadium tailing and leather sludge, were used as less expensive alternative raw materials for the synthesis of black ceramic pigments to be used in commercial glazes. The pigments were based on hematite structure (FexCr1-x)2O3 and prepared by the common solid-state reaction method, under optimal formulation and processing conditions. The synthesized pigments were characterized in typical ceramic glazes and ceramic tile bodies. Optimal color development was achieved when the Fe/Cr mole ratios were 2.0 with 40 wt% content of vanadium tailing at 1200 °C. The coloring properties were similar to those imparted by a commercial black pigment.

  15. Marshall Space Flight Center solid waste characterization and recycling improvement study

    NASA Technical Reports Server (NTRS)

    Eley, Michael H.; Crews, Lavonne; Johnston, Ben; Lee, David; Colebaugh, James

    1995-01-01

    The MSFC Facilities Office, which is responsible for disposing of all waste generated by MSFC, issued a delivery order to the University of Alabama in Huntsville (UAH) to characterize current MSFC waste streams and to evaluate their existing recycling program. The purpose of the study was to define the nature, quantity, and types of waste produced and to generate ideas for improving the present recycling program. Specifically, the following tasks were to be performed: Identify various surplus and waste materials--as identified by the Contracting Officer's Technical Representative (COTR)--by source, location, and type; Analyze MSFC's current methods for handling, storage, transport, and disposition of waste and surplussed materials; Determine the composition of various surplus and waste materials as to type and quantities from various sources and locations; Analyze different methods for the disposition of various surplus and waste materials, including quality, quantity, preparation, transport cost, and value; Study possible alternatives to current methods of handling, storage, transport, and disposition of surplus and waste materials to improve the quality and quantities recycled or sold and to reduce and minimize the quantities of surplus and waste material currently being disposed of or stored; Provide recommendations for source and centralized segregation and aggregation of materials for recycling and/or disposition; and The analysis could include identification and laboratory level evaluation of methods and/or equipment, including capital costs, operating costs, maintenance requirements, life cycle and return on investment for systems to support the waste reduction program mission.

  16. Pyrolytic Waste Plastic Oil and Its Diesel Blend: Fuel Characterization.

    PubMed

    Khan, M Z H; Sultana, M; Al-Mamun, M R; Hasan, M R

    2016-01-01

    The authors introduced waste plastic pyrolysis oil (WPPO) as an alternative fuel characterized in detail and compared with conventional diesel. High density polyethylene, HDPE, was pyrolyzed in a self-designed stainless steel laboratory reactor to produce useful fuel products. HDPE waste was completely pyrolyzed at 330-490°C for 2-3 hours to obtain solid residue, liquid fuel oil, and flammable gaseous hydrocarbon products. Comparison of the fuel properties to the petrodiesel fuel standards ASTM D 975 and EN 590 revealed that the synthetic product was within all specifications. Notably, the fuel properties included a kinematic viscosity (40°C) of 1.98 cSt, density of 0.75 gm/cc, sulphur content of 0.25 (wt%), and carbon residue of 0.5 (wt%), and high calorific value represented significant enhancements over those of conventional petroleum diesel fuel.

  17. Pyrolytic Waste Plastic Oil and Its Diesel Blend: Fuel Characterization

    PubMed Central

    Sultana, M.; Al-Mamun, M. R.; Hasan, M. R.

    2016-01-01

    The authors introduced waste plastic pyrolysis oil (WPPO) as an alternative fuel characterized in detail and compared with conventional diesel. High density polyethylene, HDPE, was pyrolyzed in a self-designed stainless steel laboratory reactor to produce useful fuel products. HDPE waste was completely pyrolyzed at 330–490°C for 2-3 hours to obtain solid residue, liquid fuel oil, and flammable gaseous hydrocarbon products. Comparison of the fuel properties to the petrodiesel fuel standards ASTM D 975 and EN 590 revealed that the synthetic product was within all specifications. Notably, the fuel properties included a kinematic viscosity (40°C) of 1.98 cSt, density of 0.75 gm/cc, sulphur content of 0.25 (wt%), and carbon residue of 0.5 (wt%), and high calorific value represented significant enhancements over those of conventional petroleum diesel fuel. PMID:27433168

  18. 10 CFR 61.58 - Alternative requirements for waste classification and characteristics.

    Code of Federal Regulations, 2014 CFR

    2014-01-01

    ... LAND DISPOSAL OF RADIOACTIVE WASTE Technical Requirements for Land Disposal Facilities § 61.58 Alternative requirements for waste classification and characteristics. The Commission may, upon request or on... 10 Energy 2 2014-01-01 2014-01-01 false Alternative requirements for waste classification and...

  19. 10 CFR 61.58 - Alternative requirements for waste classification and characteristics.

    Code of Federal Regulations, 2012 CFR

    2012-01-01

    ... LAND DISPOSAL OF RADIOACTIVE WASTE Technical Requirements for Land Disposal Facilities § 61.58 Alternative requirements for waste classification and characteristics. The Commission may, upon request or on... 10 Energy 2 2012-01-01 2012-01-01 false Alternative requirements for waste classification and...

  20. 10 CFR 61.58 - Alternative requirements for waste classification and characteristics.

    Code of Federal Regulations, 2010 CFR

    2010-01-01

    ... LAND DISPOSAL OF RADIOACTIVE WASTE Technical Requirements for Land Disposal Facilities § 61.58 Alternative requirements for waste classification and characteristics. The Commission may, upon request or on... 10 Energy 2 2010-01-01 2010-01-01 false Alternative requirements for waste classification and...

  1. 10 CFR 61.58 - Alternative requirements for waste classification and characteristics.

    Code of Federal Regulations, 2013 CFR

    2013-01-01

    ... LAND DISPOSAL OF RADIOACTIVE WASTE Technical Requirements for Land Disposal Facilities § 61.58 Alternative requirements for waste classification and characteristics. The Commission may, upon request or on... 10 Energy 2 2013-01-01 2013-01-01 false Alternative requirements for waste classification and...

  2. 10 CFR 61.58 - Alternative requirements for waste classification and characteristics.

    Code of Federal Regulations, 2011 CFR

    2011-01-01

    ... LAND DISPOSAL OF RADIOACTIVE WASTE Technical Requirements for Land Disposal Facilities § 61.58 Alternative requirements for waste classification and characteristics. The Commission may, upon request or on... 10 Energy 2 2011-01-01 2011-01-01 false Alternative requirements for waste classification and...

  3. Annual Report, Fall 2016: Identifying Cost Effective Tank Waste Characterization Approaches

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Reboul, S. H.; DiPrete, D. P.

    2016-12-12

    This report documents the activities that were performed during the second year of a project undertaken to improve the cost effectiveness and timeliness of SRNL’s tank closure characterization practices. The activities performed during the first year of the project were previously reported in SRNL-STI-2015-00144. The scope of the second year activities was divided into the following three primary tasks: 1) develop a technical basis and strategy for improving the cost effectiveness and schedule of SRNL’s tank closure characterization program; 2) initiate the design and assembly of a new waste removal system for improving the throughput and reducing the personnel dosemore » associated with extraction chromatography radiochemical separations; and 3) develop and perform feasibility testing of three alternative radiochemical separation protocols holding promise for improving high resource demand/time consuming tank closure sample analysis methods.« less

  4. Production and characterization of rhamnolipid biosurfactant from waste frying coconut oil using a novel Pseudomonas aeruginosa D.

    PubMed

    George, S; Jayachandran, K

    2013-02-01

    To improve biosurfactant production economics by the utilization of potential low-cost materials. In an attempt to utilize cost-effective carbon sources in the fermentative production of biosurfactants, various pure and waste frying oils were screened by a standard biosurfactant producing strain. Considering the regional significance, easy availability and the economical advantages, waste frying coconut oil was selected as the substrate for further studies. On isolation of more competent strains that could use waste frying coconut oil efficiently as a carbon source, six bacterial strains were isolated on cetyltrimethyl ammonium bromide-methylene blue agar plate, from a soil sample collected from the premises of a coconut oil mill. Among these, Pseudomonas aeruginosa D was selected as the potential producer of rhamnolipid. Spectrophotometric method, TLC, methylene blue active substance assay, drop collapse technique, surface tension measurement by Du Nouy ring method and emulsifying test confirmed the rhamnolipid producing ability of the selected strain and various process parameters were optimized for the production of maximum amount of biosurfactant. Rhamnolipid components purified and separated by ethyl acetate extraction, preparative silica gel column chromatography, HPLC and TLC were characterized by fast atom bombardment mass spectrometry as a mixture of dirhamnolipids and monorhamnolipids. The rhamnolipid homologues detected were Rha-Rha-C(10) -C(10) , Rha-C(12) -C(10) and Rha-C(10) -C(8) /Rha-C(8) -C(10) . These results indicated the possibility of waste frying coconut oil to be used as a very effective alternate substrate for the economic production of rhamnolipid by a newly isolated Ps. aeruginosa D. Results of this study throws light on the alternate use of already used cooking oil as high-energy source for producing a high value product like rhamnolipid. This would provide options for the food industry other than the recycling and reuse of waste frying oils in cooking and also furthering the value of oil nuts. © 2012 The Society for Applied Microbiology.

  5. Regulatory Exclusions and Alternative Standards for the Recycling of Materials, Solid Wastes and Hazardous Wastes

    EPA Pesticide Factsheets

    Determining the Level of Regulation for Hazardous Waste Recycling, Recycled Materials that are not Subject to RCRA Hazardous Waste Regulation, Materials Subject to Alternative Regulatory Controls, Materials Subject to Full Hazardous Waste Regulations.

  6. Alternative Fuels Data Center: quasar energy group Turns Organic Waste into

    Science.gov Websites

    Renewable Energy in Ohio quasar energy group Turns Organic Waste into Renewable Energy in Ohio to someone by E-mail Share Alternative Fuels Data Center: quasar energy group Turns Organic Waste group Turns Organic Waste into Renewable Energy in Ohio on Twitter Bookmark Alternative Fuels Data

  7. Long-term high-level waste technology. Composite report

    NASA Astrophysics Data System (ADS)

    Cornman, W. R.

    1981-12-01

    Research and development studies on the immobilization of high-level wastes from the chemical reprocessing of nuclear reactor fuels are summarized. The reports are grouped under the following tasks: (1) program management and support; (2) waste preparation; (3) waste fixation; and (4) final handling. Some of the highlights are: leaching properties were obtained for titanate and tailored ceramic materials being developed at ICPP to immobilize zirconia calcine; comparative leach tests, hot-cell tests, and process evaluations were conducted of waste form alternatives to borosilicate glass for the immobilization of SRP high-level wastes, experiments were run at ANL to qualify neutron activation analysis and radioactive tracers for measuring leach rates from simulated waste glasses; comparative leach test samples of SYNROC D were prepared, characterized, and tested at LLNL; encapsulation of glass marbles with lead or lead alloys was demonstrated on an engineering scale at PNL; a canister for reference Commercial HLW was designed at PNL; a study of the optimization of salt-crete was completed at SRL; a risk assessment showed that an investment for tornado dampers in the interim storage building of the DWPF is unjustified.

  8. 30 CFR 47.53 - Alternative for hazardous waste.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 30 Mineral Resources 1 2010-07-01 2010-07-01 false Alternative for hazardous waste. 47.53 Section... waste. If the mine produces or uses hazardous waste, the operator must provide potentially exposed miners and designated representatives access to available information for the hazardous waste that— (a...

  9. Superfund Training/Tech Transfer

    EPA Pesticide Factsheets

    This asset includes a collection of information resources, training, and other media related to hazardous waste site cleanup and characterization. A major part of this asset is the CLU-IN System, which is a collection of websites designed to be the central reference library for the development, collection, evaluation, coordination, and dissemination of information relating to the utilization of alternative or innovative treatment technologies... for cleaning up hazardous waste sites (Title 42 Section 9660 (b)(8)). Information includes Best Practices for using innovative technologies, case studies and focus areas about characterization and remediation technologies, emerging issues, optimization, and green(ing) remediation. CLU-IN is available via web-based documentation, live events, podcasts, and videos. Additionally, the Technology Innovation and Field Services Division (TIFSD) supports both classroom and online training registration through Trainex.org. All EPA content is also posted on EPA's website.

  10. Direct waste heat recovery via thermoelectric materials - chosen issues of the thermodynamic description

    NASA Astrophysics Data System (ADS)

    Kolasiński, Piotr; Kolasińska, Ewa

    2016-02-01

    The effective waste heat recovery is one of the present-day challenges in the industry and power engineering. The energy systems dedicated for waste heat conversion into electricity are usually characterized by low efficiency and are complicated in the design. The possibility of waste heat recovery via thermoelectric materials may be an interesting alternative to the currently used technologies. In particular, due to their material characteristics, conducting polymers may be competitive when compared with the power machinery and equipment. These materials can be used in a wide range of the geometries e.g. the bulk products, thin films, pristine form or composites and the others. In this article, the authors present selected issues related to the mathematical and thermodynamic description of the heat transfer processes in the thermoelectric materials dedicated for the waste heat recovery. The link of these models with electrical properties of the material and a material solution based on a conducting polymer have also been presented in this paper.

  11. Industrial waste materials and by-products as thermal energy storage (TES) materials: A review

    NASA Astrophysics Data System (ADS)

    Gutierrez, Andrea; Miró, Laia; Gil, Antoni; Rodríguez-Aseguinolaza, Javier; Barreneche, Camila; Calvet, Nicolas; Py, Xavier; Fernández, A. Inés; Grágeda, Mario; Ushak, Svetlana; Cabeza, Luisa F.

    2016-05-01

    A wide variety of potential materials for thermal energy storage (TES) have been identify depending on the implemented TES method, Sensible, latent or thermochemical. In order to improve the efficiency of TES systems more alternatives are continuously being sought. In this regard, this paper presents the review of low cost heat storage materials focused mainly in two objectives: on the one hand, the implementation of improved heat storage devices based on new appropriate materials and, on the other hand, the valorisation of waste industrial materials will have strong environmental, economic and societal benefits such as reducing the landfilled waste amounts, reducing the greenhouse emissions and others. Different industrial and municipal waste materials and by products have been considered as potential TES materials and have been characterized as such. Asbestos containing wastes, fly ashes, by-products from the salt industry and from the metal industry, wastes from recycling steel process and from copper refining process and dross from the aluminium industry, and municipal wastes (glass and nylon) have been considered. This work shows a great revalorization of wastes and by-product opportunity as TES materials, although more studies are needed to achieve industrial deployment of the idea.

  12. Removal of batteries from solid waste using trommel separation.

    PubMed

    Lau, S T; Cheung, W H; Kwong, C K; Wan, C P; Choy, K K H; Leung, C C; Porter, J F; Hui, C W; Mc Kay, G

    2005-01-01

    This paper describes the design and testing of a trommel for separation of batteries from solid waste. A trommel is a cylindrical separation device that rotates and performs size separation. It has also been used in areas such as municipal solid waste (MSW) processing, classifying construction and demolition debris, screening mass-burn incinerator ash and compost processing. A trommel has been designed based on size separation to separate household batteries from solid waste, which can then be used as feedstock for alternative applications of solid waste combustion, particularly where the metal content of the product is also a critical parameter, such as the Co-Co process for integrated cement and power production. This trommel has been tested with batches of university office and restaurant wastes against various factors. The recovery efficiency of batteries increases with decreasing inclination angle of the trommel and decreasing rotational speed. A physical characterization of the university solid waste has been performed with a 20-kg sample of the tested waste. It was found that there is a trend of decreasing recovery of batteries with increasing paper composition, and a trend of increasing recovery of batteries with increasing organic materials composition.

  13. Evaluation of the Efficiency of Selective Collection in a Small Town on the State of Rio Grande do Sul - Brazil

    NASA Astrophysics Data System (ADS)

    Schneider, V. E.; Poletto, M.; Peresin, D.; Carra, S. H. Z.; Vanni, D.

    2017-07-01

    With the increase of population concentration in urban areas, there is an increase in the solid waste generation, which demands the search for alternatives and solutions for the environmentally correct destination of these. In this context, this work presents an evaluation on the forms of organic and selective domestic waste collection and the potential for the recyclability of the waste destined to the same, based on the physical characterization and gravimetric composition of the solid wastes generated in the town of Antônio Prado, located in the state of Rio Grande do Sul, Brazil, between 2014 and 2016. It is observed that the population has significant information regarding the correct disposal of waste in the selective collection, since 60% of the waste destined to the same is effectively recyclable. Plastic (24.8%), paper (10.9%), glass (8.8%) and cardboard (8.4%) are the most representative materials in recycled waste samples in the urban area. The importance of continuity and improvement of environmental education programs is essential, due to the evolution in the quantity and complexity of products and materials currently manufactured, and to the method of mechanized waste collection used by the municipality.

  14. Characterization of chitin and chitosan synthesized from red snapper (Lutjanus sp.) scale's waste

    NASA Astrophysics Data System (ADS)

    Takarina, N. D.; Fanani, A. A.

    2017-07-01

    Chitin and chitosan are natural biopolymer which are useful for industrial, medical and environmental field. Study about using fish scale sources especially saltwater fish is still limited. Red snapper (Lutjanus sp) is common tropical saltwater fish that known as important source of marine products, particularly in Indonesia. Correspondingly, the consumption of this species has generated significant amount of discarded scale wastes recently and hence can cause adverse impact on the environment. Utilizing the fish scale as alternative sources of chitin and chitosan can be one solution dealing with environmental problem. Therefore, this research aimed to characterize the chitin and chitosan derived from the red snapper scale wastes. Chitin were extracted by deproteination and demineralization while chitosan using deacetylation. Morphology of the chitin and chitosan were analyzed using electron dispersal spectroscopy (EDS) and scanning electron microscope (SEM), while degree of deacetylation using fourier transform infrared spectroscopy (FTIR). Proximate analysis showed that content of moisture, ash, and nitrogen in chitin were 3.20 %, 2.40 %, 0.04 %, respectively while in chitosan were 6.14 %, 1.18 %, 0.03 % respectively. Furthermore, amount of C, O, Na, Al, P and Ca elements were obtained from chitin and chitosan samples by energy dispersed spectroscopy respectively. The degree of deacetylation for both chitin and chitosan showed high value more than 75 %. Hence, by considering the chemical properties of red snapper scales, it confirms that this species is a promising alternative source for both chitin and chitosan.

  15. Quantitative comparison between PGNAA measurements and MCNP calculations in view of the characterization of radioactive wastes in Germany and France

    NASA Astrophysics Data System (ADS)

    Mauerhofer, E.; Havenith, A.; Carasco, C.; Payan, E.; Kettler, J.; Ma, J. L.; Perot, B.

    2013-04-01

    The Forschungszentrum Jülich GmbH (FZJ), together with the Aachen University Rheinisch-Westfaelische Technische Hochschule (RWTH) and the French Alternative Energies and Atomic Energy Commission (CEA Cadarache) are involved in a cooperation aiming at characterizing toxic and reactive elements in radioactive waste packages by means of Prompt Gamma Neutron Activation Analysis (PGNAA) [1]. The French and German waste management agencies have indeed defined acceptability limits concerning these elements in view of their projected geological repositories. A first measurement campaign was performed in the new Prompt Gamma Neutron Activation Analysis (PGNAA) facility called MEDINA, at FZJ, to assess the capture gamma-ray signatures of some elements of interest in large samples up to waste drums with a volume of 200 liter. MEDINA is the acronym for Multi Element Detection based on Instrumental Neutron Activation. This paper presents MCNP calculations of the MEDINA facility and quantitative comparison between measurement and simulation. Passive gamma-ray spectra acquired with a high purity germanium detector and calibration sources are used to qualify the numerical model of the crystal. Active PGNAA spectra of a sodium chloride sample measured with MEDINA then allow for qualifying the global numerical model of the measurement cell. Chlorine indeed constitutes a usual reference with reliable capture gamma-ray production data. The goal is to characterize the entire simulation protocol (geometrical model, nuclear data, and postprocessing tools) which will be used for current measurement interpretation, extrapolation of the performances to other types of waste packages or other applications, as well as for the study of future PGNAA facilities.

  16. Characterization of household waste in Greenland

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Eisted, Rasmus, E-mail: raei@env.dtu.dk; Christensen, Thomas H.

    2011-07-15

    The composition of household waste in Greenland was investigated for the first time. About 2 tonnes of household waste was sampled as every 7th bag collected during 1 week along the scheduled collection routes in Sisimiut, the second largest town in Greenland with about 5400 inhabitants. The collection bags were sorted manually into 10 material fractions. The household waste composition consisted primarily of biowaste (43%) and the combustible fraction (30%), including anything combustible that did not belong to other clean fractions as paper, cardboard and plastic. Paper (8%) (dominated by magazine type paper) and glass (7%) were other important materialmore » fractions of the household waste. The remaining approximately 10% constituted of steel (1.5%), aluminum (0.5%), plastic (2.4%), wood (1.0%), non-combustible waste (1.8%) and household hazardous waste (1.2%). The high content of biowaste and the low content of paper make Greenlandic waste much different from Danish household waste. The moisture content, calorific value and chemical composition (55 elements, of which 22 were below detection limits) were determined for each material fraction. These characteristics were similar to what has been found for material fractions in Danish household waste. The chemical composition and the calorific value of the plastic fraction revealed that this fraction was not clean but contained a lot of biowaste. The established waste composition is useful in assessing alternative waste management schemes for household waste in Greenland.« less

  17. Production and characterization of pyrolytic oils by pyrolysis of waste machinery oil.

    PubMed

    Sinağ, Ali; Gülbay, Selen; Uskan, Burçin; Uçar, Suat; Ozgürler, Sara Bilge

    2010-01-15

    The main objective of this work is to propose an alternative method for evaluation of the waste machinery oil which is an environmental problem in Turkey. For this purpose, pyrolysis of waste machinery oil was conducted in a tubular reactor. Effect of the experimental conditions (various temperatures, catalyst type) on the formation of pyrolytic oil, gas, and char was investigated. Nickel supported on silica and zeolite (HZSM-5) were used as catalysts. Properties of the pyrolytic oils were characterized by gas chromatograph equipped with a mass selective detector (GC-MS), gas chromatography with flame ionization detector (GC-FID for boiling point range distribution), nuclear magnetic resonance ((1)H NMR) spectroscopy, higher heating value measurement, and elemental analysis. The behavior of the metals in the waste machinery oil and the pyrolytic oil samples was also quantitatively detected by inductively coupled plasma (ICP) analysis. As, Cd and Cr contents of the all pyrolytic oils were found as <0.05 ppm, while Cu content of the pyrolytic oils varied between 0.3 ppm and 0.61 ppm. Only Vanadium contents of the pyrolytic oils obtained at 800 degrees C (0.342 ppm) and in the presence of HZSM5 (0.57 ppm) increased compared to that obtained by waste machinery oil (0.1 ppm). Lower metal contents of the pyrolytic oils reveal that pyrolysis of the waste machinery oils leads to the formation of environmental friendly pyrolytic oils with higher heating values.

  18. Environmentally Sound Processing Technology: JANNAF Safety and Environmental Protection Subcommittee and Propellant Development and Characterization Subcommittee Joint Workshop

    NASA Technical Reports Server (NTRS)

    Pickett, Lorri A. (Editor)

    1995-01-01

    Topics covered include: Risk assessment of hazardous materials, Automated systems for pollution prevention and hazardous materials elimination, Study design for the toxicity evaluation of ammonium perchlorate, Plasma sprayed bondable stainless surface coatings, Development of CFC-free cleaning processes, New fluorinated solvent alternatives to ozone depleting solvents, Cleaning with highly fluorinated liquids, Biotreatment of propyleneglycol nitrate by anoxic denitrification, Treatment of hazardous waste with white rot fungus, Hydrothermal oxidation as an environmentally benign treatment technology, Treatment of solid propellant manufacturing wastes by base hydrolysis, Design considerations for cleaning using supercritical fluid technology, and Centrifugal shear carbon dioxide cleaning.

  19. Characterizing the proposed geologic repository for high-level radioactive waste at Yucca Mountain, Nevada--hydrology and geochemistry

    USGS Publications Warehouse

    Stuckless, John S.; Levich, Robert A.

    2012-01-01

    This hydrology and geochemistry volume is a companion volume to the 2007 Geological Society of America Memoir 199, The Geology and Climatology of Yucca Mountain and Vicinity, Southern Nevada and California, edited by Stuckless and Levich. The work in both volumes was originally reported in the U.S. Department of Energy regulatory document Yucca Mountain Site Description, for the site characterization study of Yucca Mountain, Nevada, as the proposed U.S. geologic repository for high-level radioactive waste. The selection of Yucca Mountain resulted from a nationwide search and numerous committee studies during a period of more than 40 yr. The waste, largely from commercial nuclear power reactors and the government's nuclear weapons programs, is characterized by intense penetrating radiation and high heat production, and, therefore, it must be isolated from the biosphere for tens of thousands of years. The extensive, unique, and often innovative geoscience investigations conducted at Yucca Mountain for more than 20 yr make it one of the most thoroughly studied geologic features on Earth. The results of these investigations contribute extensive knowledge to the hydrologic and geochemical aspects of radioactive waste disposal in the unsaturated zone. The science, analyses, and interpretations are important not only to Yucca Mountain, but also to the assessment of other sites or alternative processes that may be considered for waste disposal in the future. Groundwater conditions, processes, and geochemistry, especially in combination with the heat from radionuclide decay, are integral to the ability of a repository to isolate waste. Hydrology and geochemistry are discussed here in chapters on unsaturated zone hydrology, saturated zone hydrology, paleohydrology, hydrochemistry, radionuclide transport, and thermally driven coupled processes affecting long-term waste isolation. This introductory chapter reviews some of the reasons for choosing to study Yucca Mountain as a repository site.

  20. Characterizing the proposed geologic repository for high-level radioactive waste at Yucca Mountain, Nevada: hydrology and geochemistry

    USGS Publications Warehouse

    Stuckless, John S.; Levich, Robert A.

    2012-01-01

    This hydrology and geochemistry volume is a companion volume to the 2007 Geological Society of America Memoir 199, The Geology and Climatology of Yucca Mountain and Vicinity, Southern Nevada and California, edited by Stuckless and Levich. The work in both volumes was originally reported in the U.S. Department of Energy regulatory document Yucca Mountain Site Description, for the site characterization study of Yucca Mountain, Nevada, as the proposed U.S. geologic repository for high-level radioactive waste. The selection of Yucca Mountain resulted from a nationwide search and numerous committee studies during a period of more than 40 yr. The waste, largely from commercial nuclear power reactors and the government's nuclear weapons programs, is characterized by intense penetrating radiation and high heat production, and, therefore, it must be isolated from the biosphere for tens of thousands of years. The extensive, unique, and often innovative geoscience investigations conducted at Yucca Mountain for more than 20 yr make it one of the most thoroughly studied geologic features on Earth. The results of these investigations contribute extensive knowledge to the hydrologic and geochemical aspects of radioactive waste disposal in the unsaturated zone. The science, analyses, and interpretations are important not only to Yucca Mountain, but also to the assessment of other sites or alternative processes that may be considered for waste disposal in the future. Groundwater conditions, processes, and geochemistry, especially in combination with the heat from radionuclide decay, are integral to the ability of a repository to isolate waste. Hydrology and geochemistry are discussed here in chapters on unsaturated zone hydrology, saturated zone hydrology, paleohydrology, hydrochemistry, radionuclide transport, and thermally driven coupled processes affecting long-term waste isolation. This introductory chapter reviews some of the reasons for choosing to study Yucca Mountain as a repository site.

  1. Alternative High-Performance Ceramic Waste Forms

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Sundaram, S. K.

    This final report (M5NU-12-NY-AU # 0202-0410) summarizes the results of the project titled “Alternative High-Performance Ceramic Waste Forms,” funded in FY12 by the Nuclear Energy University Program (NEUP Project # 12-3809) being led by Alfred University in collaboration with Savannah River National Laboratory (SRNL). The overall focus of the project is to advance fundamental understanding of crystalline ceramic waste forms and to demonstrate their viability as alternative waste forms to borosilicate glasses. We processed single- and multiphase hollandite waste forms based on simulated waste streams compositions provided by SRNL based on the advanced fuel cycle initiative (AFCI) aqueous separation process developed in the Fuel Cycle Research and Development (FCR&D). For multiphase simulated waste forms, oxide and carbonate precursors were mixed together via ball milling with deionized water using zirconia media in a polyethylene jar for 2 h. The slurry was dried overnight and then separated from the media. The blended powders were then subjected to melting or spark plasma sintering (SPS) processes. Microstructural evolution and phase assemblages of these samples were studied using x-ray diffraction (XRD), scanning electron microscopy (SEM), energy dispersion analysis of x-rays (EDAX), wavelength dispersive spectrometry (WDS), transmission electron spectroscopy (TEM), selective area x-ray diffraction (SAXD), and electron backscatter diffraction (EBSD). These results showed that the processing methods have significant effect on the microstructure and thus the performance of these waste forms. The Ce substitution into zirconolite and pyrochlore materials was investigated using a combination of experimental (in situ XRD and x-ray absorption near edge structure (XANES)) and modeling techniques to study these single phases independently. In zirconolite materials, a transition from the 2M to the 4M polymorph was observed with increasing Ce content. The resulting powders were consolidated via SPS. Ce was reduced to the trivalent oxidation state and the zirconolite was converted into undesirable perovskite. The zirconolite polymorphs found in the synthesized powders were recovered after a post-SPS heat treatment in air. These results demonstrated the potential of processing in controlling the phase assemblage in these waste forms. Hollandites with Cr 3+ trivalent cations were identified as potential hosts for Cs immobilization and are being investigated for Cs retention properties. Series of compositions Ba 1.15-xCs 2xCr 2.3Ti 5.7O 16, with increasing Cs loadings, were prepared by sol-gel process and characterized for structural parameters. Structural characterization was performed by a combination of powder XRD and neutron powder diffraction. Phase pure hollandite adapting monoclinic symmetry (I2/m) was observed for 0 ≤ x ≤ 0.55. These results were used to develop a new structural model to interpret Cs immobilization in these hollandites. Performance of these waste forms were evaluated for chemical durability and radiation resistance. Product consistency testing (PCT) and vapor hydration testing (VHT) were used for testing of chemical durability. Radiation resistance was tested using He + ions to simulatemore » $$\\alpha$$ particles and heavy ions such as Au 3+ to simulate a recoil. These results showed that these waste forms were chemically durable. The waste forms also amorphized to various degrees on exposure to simulated radiation.« less

  2. Waste Characterization Methods

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Vigil-Holterman, Luciana R.; Naranjo, Felicia Danielle

    2016-02-02

    This report discusses ways to classify waste as outlined by LANL. Waste Generators must make a waste determination and characterize regulated waste by appropriate analytical testing or use of acceptable knowledge (AK). Use of AK for characterization requires several source documents. Waste characterization documentation must be accurate, sufficient, and current (i.e., updated); relevant and traceable to the waste stream’s generation, characterization, and management; and not merely a list of information sources.

  3. Alternative soilless media for growing Petunia x hybrida and Impatiens wallerana: physical behavior, effect of fertilization and nitrate losses.

    PubMed

    Chavez, Walter; Di Benedetto, Adalberto; Civeira, Gabriela; Lavado, Raúl

    2008-11-01

    The use of alternative soilless media for the production of potted plants requires knowledge of their physical and chemical characteristics to result in the best conditions for plant growth. We investigated the use of alternative soilless media based on river waste and Sphagnun sp. and Carex sp. from Argentinean peatlands on Petuniaxhybrida and Impatiens wallerana production at two fertilization levels (200 and 400mgl(-1)N). River waste or 'temperate peat' is the name given to a material, resulting from the accumulation of aquatic plant residues under an anaerobic subtropical environment, which is dredged from river banks. Our results showed that alternative substrates based on river waste can be used to grow high quality plants. This result was not fully explained on the basis of established methods to evaluate substrate quality. Highly concentrated fertigation solution decreased the substrate quality parameters and plant growth. Nitrate leaching from the alternative substrates containing river waste was lower than the standard peat-based materials, which makes river waste desirable from a sustainable pot production system perspective. River waste and Carex peat are suitable alternatives to Sphagnum peat from the Northern Hemisphere.

  4. Quantitative comparison between PGNAA measurements and MCNP calculations in view of the characterization of radioactive wastes in Germany and France

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Mauerhofer, E.; Havenith, A.; Kettler, J.

    The Forschungszentrum Juelich GmbH (FZJ), together with the Aachen University Rheinisch-Westfaelische Technische Hochschule (RWTH) and the French Alternative Energies and Atomic Energy Commission (CEA Cadarache) are involved in a cooperation aiming at characterizing toxic and reactive elements in radioactive waste packages by means of Prompt Gamma Neutron Activation Analysis (PGNAA). The French and German waste management agencies have indeed defined acceptability limits concerning these elements in view of their projected geological repositories. A first measurement campaign was performed in the new Prompt Gamma Neutron Activation Analysis (PGNAA) facility called MEDINA, at FZJ, to assess the capture gamma-ray signatures of somemore » elements of interest in large samples up to waste drums with a volume of 200 liter. MEDINA is the acronym for Multi Element Detection based on Instrumental Neutron Activation. This paper presents MCNP calculations of the MEDINA facility and quantitative comparison between measurement and simulation. Passive gamma-ray spectra acquired with a high purity germanium detector and calibration sources are used to qualify the numerical model of the crystal. Active PGNAA spectra of a sodium chloride sample measured with MEDINA then allow for qualifying the global numerical model of the measurement cell. Chlorine indeed constitutes a usual reference with reliable capture gamma-ray production data. The goal is to characterize the entire simulation protocol (geometrical model, nuclear data, and postprocessing tools) which will be used for current measurement interpretation, extrapolation of the performances to other types of waste packages or other applications, as well as for the study of future PGNAA facilities.« less

  5. RESULTS OF THE ENVIRONMENTAL MANAGEMENT (EM) CORPORATE PROJECT TEAM DISPOSING WASTE & REDUCING RISK

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    SHRADER, T.A.; KNERR, R.

    2005-01-31

    In 2002, the US Department of Energy's (DOE) Office of Environmental Management (EM) released the Top-To-Bottom Review of cognizant clean-up activities around the DOE Complex. The review contained a number of recommendations for changing the way EM operates in order to reduce environmental risk by significantly accelerating clean-up at the DOE-EM sites. In order to develop and implement these recommendations, a number of corporate project teams were formed to identify, evaluate, and initiate implementation of alternatives for the different aspects of clean-up. In August 2002, a corporate team was formed to review all aspects of the management, treatment, and disposalmore » of low level radioactive waste (LLW), mixed low level radioactive waste (MLLW), transuranic waste (TRU), and hazardous waste (HW). Over the next 21 months, the Corporate Project Team: Disposing Waste, Reducing Risk, developed a number of alternatives for implementing the recommendations of the Top-To-Bottom Review based on information developed during numerous site visits and interviews with complex and industry personnel. With input from over a dozen EM sites at various stages of clean-up, the team identified the barriers to the treatment and disposal of low level waste, mixed low level waste, and transuranic waste. Once identified, preliminary design alternatives were developed and presented to the Acquisition Authority (for this project, the Assistant Secretary for Environmental Management) for review and approval. Once the preliminary design was approved, the team down selected to seven key alternatives which were subsequently fully developed in the Project Execution Plan. The seven most viable alternatives were: (1) creation of an Executive Waste Disposal Board; (2) projectizing the disposal of low level waste and mixed low level waste; (3) creation of a National Consolidation and Acceleration Facility for waste; (4) improvements to the Broad Spectrum contract; (5) improvements to the Toxic Substance Control Act (TSCA) Incinerator contract and operations; (6) development of a policy for load management of waste shipments to the Waste Isolation Pilot Plant (WIPP); and (7) development of a complex-wide fee incentive for transuranic waste disposal. The alternatives were further refined and a plan developed for institutionalizing the alternatives in various site contracts. In order to focus the team's efforts, all team activities were conducted per the principles of DOE Order 413.3, Program and Project Management for the Acquisition of Capital Assets. Although the Order was developed for construction projects, the principles were adapted for use on this ''soft'' project in which the deliverables were alternatives for the way work was performed. The results of the team's investigation and the steps taken during the project are presented along with lessons learned.« less

  6. Optical and spectroscopic studies on tannery wastes as a possible source of organic semiconductors

    NASA Astrophysics Data System (ADS)

    Nashy, El-Shahat H. A.; Al-Ashkar, Emad; Abdel Moez, A.

    2012-02-01

    Tanning industry produces a large quantity of solid wastes which contain hide proteins in the form of protein shavings containing chromium salts. The chromium wastes are the main concern from an environmental stand point of view, because chrome wastes posses a significant disposal problem. The present work is devoted to investigate the possibility of utilizing these wastes as a source of organic semi-conductors as an alternative method instead of the conventional ones. The chemical characterization of these wastes was determined. In addition, the Horizontal Attenuated Total Reflection (HATR) FT-IR spectroscopic analysis and optical parameters were also carried out for chromated samples. The study showed that the chromated samples had suitable absorbance and transmittance in the wavelength range (500-850 nm). Presence of chromium salt in the collagen samples increases the absorbance which improves the optical properties of the studied samples and leads to decrease the optical energy gap. The obtained optical energy gap gives an impression that the environmentally hazardous chrome shavings wastes can be utilized as a possible source of natural organic semiconductors with direct and indirect energy gap. This work opens the door to use some hazardous wastes in the manufacture of electronic devices such as IR-detectors, solar cells and also as solar cell windows.

  7. Utilization of Waste Biomass (Kitchen Waste) Hydrolysis Residue as Adsorbent for Dye Removal: Kinetic, Equilibrium, and Thermodynamic Studies.

    PubMed

    Li, Panyu; Chen, Xi; Zeng, Xiaotong; Zeng, Yu; Xie, Yi; Li, Xiang; Wang, Yabo; Xie, Tonghui; Zhang, Yongkui

    2018-02-02

    Kitchen waste hydrolysis residue (KWHR), which is produced in the bioproduction process from kitchen waste (KW), is usually wasted with potential threats to the environment. Herein, experiments were carried out to evaluate the potential of KWHR as adsorbent for dye (methylene blue, MB) removal from aqueous solution. The adsorbent was characterized using FT-IR and SEM. Adsorption results showed that the operating variables had great effects on the removal efficiency of MB. Kinetic study indicated pseudo-second-order model was suitable to describe the adsorption process. Afterwards, the equilibrium data were well fitted by using Langmuir isotherm model, suggesting a monolayer adsorption. The Langmuir monolayer adsorption capacity was calculated to be 110.13 mg/g, a level comparable to some other low-cost adsorbents. It was found that the adsorption process of MB onto KWHR was spontaneous and exothermic through the estimation of thermodynamic parameters. Thus, KWHR was of great potential to be an alternative adsorbent material to improve the utilization efficiency of bioresource (KW) and lower the cost of adsorbent for color treatment.

  8. ENGINEERING STUDY FOR THE 200 AREA EFFLUENT TREATMENT FACILITY (ETF) SECONDARY WASTE TREATMENT OF PROJECTED FUTURE WASTE FEEDS

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    LUECK, K.J.

    2004-10-18

    This report documents an engineering study conducted to evaluate alternatives for treating secondary waste in the secondary treatment train (STT) of the Hanford Site 200 Area Effluent Treatment Facility (ETF). The study evaluates ETF STT treatment alternatives and recommends preferred alternatives for meeting the projected future missions of the ETF. The preferred alternative(s) will process projected future ETF influents to produce a solid waste acceptable for final disposal on the Hanford Site. The main text of this report summarizes the ETF past and projected operations, lists the assumptions about projected operations that provide the basis for the engineering evaluation, andmore » summarizes the evaluation process. The evaluation process includes identification of available modifications to the current ETF process, screens those modifications for technical viability, evaluates the technically viable alternatives, and provides conclusions and recommendations based on that evaluation.« less

  9. Alternative approaches for better municipal solid waste management in Mumbai, India

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Rathi, Sarika

    2006-07-01

    Waste is an unavoidable by product of human activities. Economic development, urbanization and improving living standards in cities, have led to an increase in the quantity and complexity of generated waste. Rapid growth of population and industrialization degrades the urban environment and places serious stress on natural resources, which undermines equitable and sustainable development. Inefficient management and disposal of solid waste is an obvious cause of degradation of the environment in most cities of the developing world. Municipal corporations of the developing countries are not able to handle increasing quantities of waste, which results in uncollected waste on roads andmore » in other public places. There is a need to work towards a sustainable waste management system, which requires environmental, institutional, financial, economic and social sustainability. This study explores alternative approaches to municipal solid waste (MSW) management and estimates the cost of waste management in Mumbai, India. Two alternatives considered in the paper are community participation and public private partnership in waste management. Data for the present study are from various non-governmental organizations (NGOs) and from the private sector involved in waste management in Mumbai. Mathematical models are used to estimate the cost per ton of waste management for both of the alternatives, which are compared with the cost of waste management by Municipal Corporation of Greater Mumbai (MCGM). It is found that the cost per ton of waste management is Rs. 1518 (US$35) with community participation; Rs. 1797 (US$41) with public private partnership (PPP); and Rs. 1908 (US$44) when only MCGM handles the waste. Hence, community participation in waste management is the least cost option and there is a strong case for comprehensively involving community participation in waste management.« less

  10. 75 FR 54631 - Proposed Approval of the Central Characterization Project's Transuranic Waste Characterization...

    Federal Register 2010, 2011, 2012, 2013, 2014

    2010-09-08

    ... Central Characterization Project's Transuranic Waste Characterization Program at the Hanford Site AGENCY...) waste characterization program implemented by the Central Characterization Project (CCP) at the Hanford... characterization of TRU debris waste from Hanford-CCP during an inspection conducted on April 27-29, 2010. Using...

  11. Straight-chain halocarbon forming fluids for TRISO fuel kernel production - Tests with yttria-stabilized zirconia microspheres

    NASA Astrophysics Data System (ADS)

    Baker, M. P.; King, J. C.; Gorman, B. P.; Braley, J. C.

    2015-03-01

    Current methods of TRISO fuel kernel production in the United States use a sol-gel process with trichloroethylene (TCE) as the forming fluid. After contact with radioactive materials, the spent TCE becomes a mixed hazardous waste, and high costs are associated with its recycling or disposal. Reducing or eliminating this mixed waste stream would not only benefit the environment, but would also enhance the economics of kernel production. Previous research yielded three candidates for testing as alternatives to TCE: 1-bromotetradecane, 1-chlorooctadecane, and 1-iodododecane. This study considers the production of yttria-stabilized zirconia (YSZ) kernels in silicone oil and the three chosen alternative formation fluids, with subsequent characterization of the produced kernels and used forming fluid. Kernels formed in silicone oil and bromotetradecane were comparable to those produced by previous kernel production efforts, while those produced in chlorooctadecane and iodododecane experienced gelation issues leading to poor kernel formation and geometry.

  12. Eco-Friendly Extraction of Biopolymer Chitin and Carotenoids from Shrimp Waste

    NASA Astrophysics Data System (ADS)

    Prameela, K.; Venkatesh, K.; Divya vani, K.; Sudesh Kumar, E.; Mohan, CH Murali

    2017-08-01

    Astaxanthin a nutraceutical and chitin a natural biopolymer present in shrimp waste. In current chemical extraction methods HCl and NaOH are used for extraction and these chemicals are introduced into aquatic ecosystems are spoiling aquatic flora and fauna, pollute the environment and destroy astaxanthin. Lactobacillus species were isolated from gut of Solenocera melantho and characterized phenotypically and genotypically. Initial screening experiments have shown to be an effective and identified as Lactobacillus plantaram based on morphological, biochemical characteristics and molecular analysis. Efficiency of fermentation has shown with good yield of astaxanthin and recovery of chitin. Hence this alternative microbial process is having advantage than existing hazardous, non-economical chemical process.

  13. ANALYSIS OF THE POTENTIAL EFFECTS OF TOXICS ON MUNICIPAL SOLID WASTE MANGEMENT OPTIONS

    EPA Science Inventory

    Many alternative waste management practices and strategies are available to manage the large quantities of MSW generated every year. These management alternatives include recycling, composting, waste-to-fuel/energy recovery, and landfilling. In choosing the best possible manageme...

  14. ANALYSIS OF THE POTENTIAL EFFECTS OF TOXICS ON MUNICIPAL SOLID WASTE MANAGEMENT OPTIONS

    EPA Science Inventory

    Many alternative waste management practices and strategies are available to manage the large quantities of MSW generated every year. hese management alternatives include recycling, composting, waste-to-fuel/energy recovery, and landfilling. n choosing the best possible management...

  15. 77 FR 11112 - Proposed Approval of the Central Characterization Project's Remote-Handled Transuranic Waste...

    Federal Register 2010, 2011, 2012, 2013, 2014

    2012-02-24

    ... Central Characterization Project's Remote-Handled Transuranic Waste Characterization Program at the...-handled (RH), transuranic (TRU) waste characterization program implemented by the Central Characterization... Criteria, EPA evaluated the characterization of RH TRU debris waste from SRS-CCP during an inspection on...

  16. 40 CFR Appendix IV to Part 268 - Wastes Excluded From Lab Packs Under the Alternative Treatment Standards of § 268.42(c)

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES (CONTINUED) LAND DISPOSAL RESTRICTIONS Pt. 268, App. IV Appendix IV to Part 268—Wastes Excluded From Lab Packs Under the Alternative Treatment... 40 Protection of Environment 28 2013-07-01 2013-07-01 false Wastes Excluded From Lab Packs Under...

  17. 40 CFR Appendix IV to Part 268 - Wastes Excluded From Lab Packs Under the Alternative Treatment Standards of § 268.42(c)

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES (CONTINUED) LAND DISPOSAL RESTRICTIONS Pt. 268, App. IV Appendix IV to Part 268—Wastes Excluded From Lab Packs Under the Alternative Treatment... 40 Protection of Environment 28 2012-07-01 2012-07-01 false Wastes Excluded From Lab Packs Under...

  18. 40 CFR Appendix IV to Part 268 - Wastes Excluded From Lab Packs Under the Alternative Treatment Standards of § 268.42(c)

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES (CONTINUED) LAND DISPOSAL RESTRICTIONS Pt. 268, App. IV Appendix IV to Part 268—Wastes Excluded From Lab Packs Under the Alternative Treatment... 40 Protection of Environment 27 2011-07-01 2011-07-01 false Wastes Excluded From Lab Packs Under...

  19. 40 CFR Appendix IV to Part 268 - Wastes Excluded From Lab Packs Under the Alternative Treatment Standards of § 268.42(c)

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES (CONTINUED) LAND DISPOSAL RESTRICTIONS Pt. 268, App. IV Appendix IV to Part 268—Wastes Excluded From Lab Packs Under the Alternative Treatment... 40 Protection of Environment 26 2010-07-01 2010-07-01 false Wastes Excluded From Lab Packs Under...

  20. 40 CFR Appendix IV to Part 268 - Wastes Excluded From Lab Packs Under the Alternative Treatment Standards of § 268.42(c)

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES (CONTINUED) LAND DISPOSAL RESTRICTIONS Pt. 268, App. IV Appendix IV to Part 268—Wastes Excluded From Lab Packs Under the Alternative Treatment... 40 Protection of Environment 27 2014-07-01 2014-07-01 false Wastes Excluded From Lab Packs Under...

  1. RCRA Facility Investigation report for Waste Area Grouping 6 at Oak Ridge National Laboratory, Oak Ridge, Tennessee. Volume 1. Sections 1 through 3

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    None

    1991-09-01

    WAG 6 comprises a shallow land burial facility used for disposal of low-level radioactive wastes (LLW) and, until recently, chemical wastes. As such, the site is subject to regulation under RCRA and the Comprehensive Environmental Response Compensation and Liability Act (CERCLA). To comply with these regulations, DOE, in conjunction with the Environmental Protection Agency (EPA) and the Tennessee Department of Environment and Conservation (TDEC), developed a strategy for closure and remediation of WAG 6 by 1997. A key component of this strategy was to complete an RFI by September 1991. The primary objectives of the RFI were to evaluate themore » site's potential human health and environmental impacts and to develop a preliminary list of alternatives to mitigate these impacts. The WAG 6 one of three solid waste management units evaluated Oak Ridge National Laboratory (ORNL) existing waste disposal records and sampling data and performed the additional sampling and analysis necessary to: describe the nature and extent of contamination; characterize key contaminant transport pathways; and assess potential risks to human health and the environment by developing and evaluating hypothetical receptor scenarios. Estimated excess lifetime cancer risks as a result for exposure to radionuclides and chemicals were quantified for each hypothetical human receptor. For environmental receptors, potential impacts were qualitatively assessed. Taking into account regulatory requirements and base line risk assessment results, preliminary site closure and remediation objectives were identified, and a preliminary list of alternatives for site closure and remediation was developed.« less

  2. ECONOMICS OF DISPOSAL OF LIME/LIMESTONE SCRUBBING WASTES: UNTREATED AND CHEMICALLY TREATED WASTES

    EPA Science Inventory

    The report gives results of a detailed, comparative economic evaluation of four alternatives available to the utility industry for the disposal of wastes from flue gas desulfurization using limestone or lime slurry scrubbing. The alternatives are untreated sludge (pond or landfil...

  3. Environmental and Geotechnical Assessment of the Steel Slags as a Material for Road Structure.

    PubMed

    Sas, Wojciech; Głuchowski, Andrzej; Radziemska, Maja; Dzięcioł, Justyna; Szymański, Alojzy

    2015-07-30

    Slags are the final solid wastes from the steel industry. Their production from waste and associated materials is a proper implementation of the basic objectives and principles of the waste management. This study aims to investigate the chemical and selected significant geotechnical parameters of steel slag as the alternative materials used in road construction. These investigations are strongly desired for successful application in engineering. Young's modules E , and resilient modules M r showed that their values corresponding with requirements for subbase (principal or auxiliary) and riding surface as well. Tested mechanical properties were conducted in soaked and un-soaked (optimal moisture content) conditions. The designated high content of chromium and zinc are strongly associated with the internal crystal structure of steel slag. The results do not lead to threats when they are applied in roads' structures. Mechanical characterization was obtained by performing California bearing ratio (CBR) tests for steel slag in fixed compaction and moisture content conditions. Moreover, cyclic loading of steel slag was conducted with the application of cyclic California bearing ratio (cCBR) apparatus to characterization of this material as a controlled low-strength material. Finally, field studies that consist of static load plate VSS tests were presented.

  4. 76 FR 62062 - Proposed Approval of the Central Characterization Project's Remote-Handled Transuranic Waste...

    Federal Register 2010, 2011, 2012, 2013, 2014

    2011-10-06

    ... Central Characterization Project's Remote-Handled Transuranic Waste Characterization Program at Sandia..., remote-handled (RH), transuranic (TRU) waste characterization program implemented by the Central Characterization Project (CCP) at Sandia National Laboratory (SNL) in Albuquerque, New Mexico. This waste is...

  5. 76 FR 33277 - Proposed Approval of the Central Characterization Project's Remote-Handled Transuranic Waste...

    Federal Register 2010, 2011, 2012, 2013, 2014

    2011-06-08

    ... Central Characterization Project's Remote-Handled Transuranic Waste Characterization Program at Bettis... radioactive remote-handled (RH) transuranic (TRU) waste characterization program implemented by the Central Characterization Project (CCP) at Bettis Atomic Power Laboratory (BAPL) in West Mifflin, Pennsylvania. This waste...

  6. Environmental evaluation of alternatives for long-term management of Defense high-level radioactive wastes at the Idaho Chemical Processing Plant

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Not Available

    1982-09-01

    The U.S. Department of Energy (DOE) is considering the selection of a strategy for the long-term management of the defense high-level wastes at the Idaho Chemical Processing Plant (ICPP). This report describes the environmental impacts of alternative strategies. These alternative strategies include leaving the calcine in its present form at the Idaho National Engineering Laboratory (INEL), or retrieving and modifying the calcine to a more durable waste form and disposing of it either at the INEL or in an offsite repository. This report addresses only the alternatives for a program to manage the high-level waste generated at the ICPP. 24more » figures, 60 tables.« less

  7. Performance Test on Compression Ignition Engine by Blending Ethanol and Waste Plastic Pyrolysis Oil with Cetane Additive

    NASA Astrophysics Data System (ADS)

    Padmanabhan, S.; Ganesan, S.; Jeswin Arputhabalan, J.; Chithrala, Varun; Ganesh Bairavan, P.

    2017-05-01

    The demand for diesel fuel is higher than that of petrol throughout the world hence seeking alternative to mineral diesel is a natural choice. Alternative fuels should be easily available at lower cost, environment friendly and fulfill energy needs without modifying engine’s operational parameters. Waste to energy is the trend in the selection of alternate fuels. In this work, Waste Plastic Pyrolysis oil (WPPO), Ethanol, Diesel blend with Cetane additive has been attempted as an alternative fuel. A Twin cylinder, Direct Injection engine was used to assess the engine performance and emission characteristics of waste plastic pyrolysis oil with cetane additive. Experimental results of blended plastic fuel and diesel fuel were compared.

  8. Adequacy of a Small Quantity Site RH-TRU Waste Program in Meeting Proposed WIPP Characterization Objectives

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Biedscheid, J.; Stahl, S.; Devarakonda, M.

    2002-02-26

    The first remote-handled transuranic (RH-TRU) waste is expected to be permanently disposed of at the Waste Isolation Pilot Plant (WIPP) during Fiscal Year (FY) 2003. The first RH-TRU waste shipments are scheduled from the Battelle Columbus Laboratories (BCL) to WIPP in order to facilitate compliance with BCL Decommissioning Project (BCLDP) milestones. Milestones requiring RH-TRU waste containerization and removal from the site by 2004 in order to meet a 2006 site closure goal, established by Congress in the Defense Facilities Closure Projects account, necessitated the establishment and implementation of a site-specific program to direct the packaging of BCLDP RH-TRU waste priormore » to the finalization of WIPP RH-TRU waste characterization requirements. The program was designed to collect waste data, including audio and videotape records of waste packaging, such that upon completion of waste packaging, comprehensive data records exist from which compliance with final WIPP RH-TRU waste characterization requirements can be demonstrated. With the BCLDP data records generated to date and the development by the U.S. Department of Energy (DOE)-Carlsbad Field Office (CBFO) of preliminary documents proposing the WIPP RH-TRU waste characterization program, it is possible to evaluate the adequacy of the BCLDP program with respect to meeting proposed characterization objectives. The BCLDP characterization program uses primarily acceptable knowledge (AK) and visual examination (VE) during waste packaging to characterize RH-TRU waste. These methods are used to estimate physical waste parameters, including weight percentages of metals, cellulosics, plastics, and rubber in the waste, and to determine the absence of prohibited items, including free liquids. AK combined with computer modeling is used to estimate radiological waste parameters, including total activity on a waste container basis, for the majority of BCLDP RH-TRU waste. AK combined with direct analysis is used to characterize radiological parameters for the small populations of the RH-TRU waste generated by the BCLDP. All characterization based on AK is verified. Per its design for comprehensive waste data collection, the BCLDP characterization program using AK and waste packaging procedures, including VE during packaging, meets the proposed WIPP RH-TRU waste characterization objectives. The conservative program design implemented generates certification data that will be adequate to meet any additional program requirements that may be imposed by the CBFO.« less

  9. Comparative lifecycle assessment of alternatives for waste management in Rio de Janeiro - Investigating the influence of an attributional or consequential approach.

    PubMed

    Bernstad Saraiva, A; Souza, R G; Valle, R A B

    2017-10-01

    The environmental impacts from three management alternatives for organic fraction of municipal solid waste were compared using lifecycle assessment methodology. The alternatives (sanitary landfill, selective collection of organic waste for anaerobic digestion and anaerobic digestion after post-separation of organic waste) were modelled applying an attributional as well as consequential approach, in parallel with the aim of identifying if and how these approaches can affect results and conclusions. The marginal processes identified in the consequential modelling were in general associated with higher environmental impacts than average processes modelled with an attributional approach. As all investigated waste management alternatives result in net-substitution of energy and in some cases also materials, the consequential modelling resulted in lower absolute environmental impacts in five of the seven environmental impact categories assessed in the study. In three of these, the chosen modelling approach can alter the hierarchy between compared waste management alternatives. This indicates a risk of underestimating potential benefits from efficient energy recovery from waste when applying attributional modelling in contexts in which electricity provision historically has been dominated by technologies presenting rather low environmental impacts, but where projections point at increasing impacts from electricity provision in coming years. Thus, in the present case study, the chosen approach affects both absolute and relative results from the comparison. However, results were largely related to the processes identified as affected by investigated changes, and not merely the chosen modelling approach. The processes actually affected by future choices between different waste management alternatives are intrinsically uncertain. The study demonstrates the benefits of applying different assumptions regarding the processes affected by investigated choices - both for provision of energy and materials substituted by waste management processes in consequential LCA modelling, in order to present outcomes that are relevant as decision support within the waste management sector. Copyright © 2017 Elsevier Ltd. All rights reserved.

  10. Prospects of pyrolysis oil from plastic waste as fuel for diesel engines: A review

    NASA Astrophysics Data System (ADS)

    Mangesh, V. L.; Padmanabhan, S.; Ganesan, S.; PrabhudevRahul, D.; Reddy, T. Dinesh Kumar

    2017-05-01

    The purpose ofthis study is to review the existing literature about chemical recycling of plastic waste and its potential as fuel for diesel engines. This is a review covering on the field of converting waste plastics into liquid hydrocarbon fuels for diesel engines. Disposal and recycling of waste plastics have become an incremental problem and environmental threat with increasing demand for plastics. One of the effective measures is by converting waste plastic into combustible hydrocarbon liquid as an alternative fuel for running diesel engines. Continued research efforts have been taken by researchers to convert waste plastic in to combustible pyrolysis oil as alternate fuel for diesel engines. An existing literature focuses on the study of chemical structure of the waste plastic pyrolysis compared with diesel oil. Converting waste plastics into fuel oil by different catalysts in catalytic pyrolysis process also reviewed in this paper. The methodology with subsequent hydro treating and hydrocracking of waste plastic pyrolysis oil can reduce unsaturated hydrocarbon bonds which would improve the combustion performance in diesel engines as an alternate fuel.

  11. Vegetation cover and long-term conservation of radioactive waste packages: the case study of the CSM waste disposal facility (Manche District, France).

    PubMed

    Petit-Berghem, Yves; Lemperiere, Guy

    2012-03-01

    The CSM is the first French waste disposal facility for radioactive waste. Waste material is buried several meters deep and protected by a multi-layer cover, and equipped with a drainage system. On the surface, the plant cover is a grassland vegetation type. A scientific assessment has been carried out by the Géophen laboratory, University of Caen, in order to better characterize the plant cover (ecological groups and associated soils) and to observe its medium and long term evolution. Field assessments made on 10 plots were complemented by laboratory analyses carried out over a period of 1 year. The results indicate scenarios and alternative solutions which could arise, in order to passively ensure the long-term safety of the waste disposal system. Several proposals for a blanket solution are currently being studied and discussed, under the auspices of international research institutions in order to determine the most appropriate materials for the storage conditions. One proposal is an increased thickness of these materials associated with a geotechnical barrier since it is well adapted to the forest plants which are likely to colonize the site. The current experiments that are carried out will allow to select the best option and could provide feedback for other waste disposal facility sites already being operated in France (CSFMA waste disposal facility, Aube district) or in other countries.

  12. Optical and spectroscopic studies on tannery wastes as a possible source of organic semiconductors.

    PubMed

    Nashy, El-Shahat H A; Al-Ashkar, Emad; Moez, A Abdel

    2012-02-01

    Tanning industry produces a large quantity of solid wastes which contain hide proteins in the form of protein shavings containing chromium salts. The chromium wastes are the main concern from an environmental stand point of view, because chrome wastes posses a significant disposal problem. The present work is devoted to investigate the possibility of utilizing these wastes as a source of organic semi-conductors as an alternative method instead of the conventional ones. The chemical characterization of these wastes was determined. In addition, the Horizontal Attenuated Total Reflection (HATR) FT-IR spectroscopic analysis and optical parameters were also carried out for chromated samples. The study showed that the chromated samples had suitable absorbance and transmittance in the wavelength range (500-850 nm). Presence of chromium salt in the collagen samples increases the absorbance which improves the optical properties of the studied samples and leads to decrease the optical energy gap. The obtained optical energy gap gives an impression that the environmentally hazardous chrome shavings wastes can be utilized as a possible source of natural organic semiconductors with direct and indirect energy gap. This work opens the door to use some hazardous wastes in the manufacture of electronic devices such as IR-detectors, solar cells and also as solar cell windows. Copyright © 2011 Elsevier B.V. All rights reserved.

  13. WIPP Hazardous Waste Facility Permit Update

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Kehrman, B.; Most, W.

    2006-07-01

    The Waste Isolation Pilot Plant (WIPP) Hazardous Waste Facility Permit (HWFP) was issued on October 27, 1999 [1]. Since that time, the WIPP has sought modifications to clarify the permit language, provide alternative methods for meeting permit requirements and to update permit conditions. Significant advancements have been made in transuranic (TRU) waste management as the result of modifications to the HWFP. Among these advancements is a modification to obtain a drum age criteria (DAC) value to perform headspace gas sampling on drums to be super-compacted and placed in a 100-gallon overpack drum. In addition, the Section 311 permit modification requestmore » that would allow for more efficient waste characterization, and the modification to authorize the shipment and disposal of Remote-Handled (RH) TRU waste were merged together and submitted to the regulator as the Consolidated Permit Modification Request (PMR). The submittal of the Consolidated PMR came at the request of the regulator as part of responses to Notices of Deficiency (NODs) for the separate PMRs which had been submitted in previous years. Section 311 of the fiscal year 2004 Energy and Water Developments Appropriations Act (Public Law 108-137) [2] directs the Department of Energy to submit a permit modification that limits waste confirmation to radiography or visual examination of a statistical subpopulation of containers. Section 311 also specifically directs that disposal room performance standards be to be met by monitoring for volatile organic compounds in the underground disposal rooms. This statute translates into the elimination of other waste confirmation methods such as headspace gas sampling and analysis and solids sampling and analysis. These methods, as appropriate, will continue to be used by the generator sites during hazardous waste determinations or characterization activities. This modification is expected to reduce the overall cost of waste analysis by hundreds of millions of dollars [3]. Combining both the chap. 311 and RH TRU waste permit modification requests allows for both the regulator and DOE to expedite action on the modification requests. The Combined PMR reduces costs by having only one administrative process for both modification requests. (authors)« less

  14. 33 Shafts Category of Transuranic Waste Stored Below Ground within Area G

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Hargis, Kenneth Marshall; Monk, Thomas H

    This report compiles information to support the evaluation of alternatives and analysis of regulatory paths forward for the 33 shafts. The historical information includes a form completed by waste generators for each waste package (Reference 6) that included a waste description, estimates of Pu-239 and uranium-235 (U-235) based on an accounting technique, and calculations of mixed fission products (MFP) based on radiation measurements. A 1979 letter and questionnaire (Reference 7) provides information on waste packaging of hot cell waste and the configuration of disposal shafts as storage in the 33 Shafts was initiated. Tables of data by waste package weremore » developed during a review of historical documents that was performed in 2005 (Reference 8). Radiological data was coupled with material-type data to estimate the initial isotopic content of each waste package and an Oak Ridge National Laboratory computer code was used to calculate 2009 decay levels. Other sources of information include a waste disposal logbook for the 33 shafts (Reference 9), reports that summarize remote-handled waste generated at the CMR facility (Reference 10) and placement of waste in the 33 shafts (Reference 11), a report on decommissioning of the LAMPRE reactor (Reference 12), interviews with an employee and manager involved in placing waste in the 33 shafts (References 13 and 14), an interview with a long-time LANL employee involved in waste operations (Reference 15), a 2002 plan for disposition of remote-handled TRU waste (Reference 16), and photographs obtained during field surveys of several shafts in 2007. The WIPP Central Characterization Project (CCP) completed an Acceptable Knowledge (AK) summary report for 16 canisters of remote-handled waste from the CMR Facility that contains information relevant to the 33 Shafts on hot-cell operations and timeline (Reference 17).« less

  15. Fact Sheet on How to Get Started Managing Hazardous Waste Laboratory Waste Under the Alternative Set of Generator Regulations

    EPA Pesticide Factsheets

    Fact sheet to help academic laboratories decide whether to opt into the alternate set of hazardous waste requirements for eligible academic laboratories found in RCRA subpart K, how to plan for the transition to subpart K, and what first steps to take.

  16. Radioactive Waste Characterization Strategies; Comparisons Between AK/PK, Dose to Curie Modeling, Gamma Spectroscopy, and Laboratory Analysis Methods- 12194

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Singledecker, Steven J.; Jones, Scotty W.; Dorries, Alison M.

    2012-07-01

    In the coming fiscal years of potentially declining budgets, Department of Energy facilities such as the Los Alamos National Laboratory (LANL) will be looking to reduce the cost of radioactive waste characterization, management, and disposal processes. At the core of this cost reduction process will be choosing the most cost effective, efficient, and accurate methods of radioactive waste characterization. Central to every radioactive waste management program is an effective and accurate waste characterization program. Choosing between methods can determine what is classified as low level radioactive waste (LLRW), transuranic waste (TRU), waste that can be disposed of under an Authorizedmore » Release Limit (ARL), industrial waste, and waste that can be disposed of in municipal landfills. The cost benefits of an accurate radioactive waste characterization program cannot be overstated. In addition, inaccurate radioactive waste characterization of radioactive waste can result in the incorrect classification of radioactive waste leading to higher disposal costs, Department of Transportation (DOT) violations, Notice of Violations (NOVs) from Federal and State regulatory agencies, waste rejection from disposal facilities, loss of operational capabilities, and loss of disposal options. Any one of these events could result in the program that mischaracterized the waste losing its ability to perform it primary operational mission. Generators that produce radioactive waste have four characterization strategies at their disposal: - Acceptable Knowledge/Process Knowledge (AK/PK); - Indirect characterization using a software application or other dose to curie methodologies; - Non-Destructive Analysis (NDA) tools such as gamma spectroscopy; - Direct sampling (e.g. grab samples or Surface Contaminated Object smears) and laboratory analytical; Each method has specific advantages and disadvantages. This paper will evaluate each method detailing those advantages and disadvantages including; - Cost benefit analysis (basic materials costs, overall program operations costs, man-hours per sample analyzed, etc.); - Radiation Exposure As Low As Reasonably Achievable (ALARA) program considerations; - Industrial Health and Safety risks; - Overall Analytical Confidence Level. The concepts in this paper apply to any organization with significant radioactive waste characterization and management activities working to within budget constraints and seeking to optimize their waste characterization strategies while reducing analytical costs. (authors)« less

  17. Pretest characterization of WIPP experimental waste

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Johnson, J.; Davis, H.; Drez, P.E.

    The Waste Isolation Pilot Plant (WIPP) near Carlsbad, New Mexico, is an underground repository designed for the storage and disposal of transuranic (TRU) wastes from US Department of Energy (DOE) facilities across the country. The Performance Assessment (PA) studies for WIPP address compliance of the repository with applicable regulations, and include full-scale experiments to be performed at the WIPP site. These experiments are the bin-scale and alcove tests to be conducted by Sandia National Laboratories (SNL). Prior to conducting these experiments, the waste to be used in these tests needs to be characterized to provide data on the initial conditionsmore » for these experiments. This characterization is referred to as the Pretest Characterization of WIPP Experimental Waste, and is also expected to provide input to other programmatic efforts related to waste characterization. The purpose of this paper is to describe the pretest waste characterization activities currently in progress for the WIPP bin-scale waste, and to discuss the program plan and specific analytical protocols being developed for this characterization. The relationship between different programs and documents related to waste characterization efforts is also highlighted in this paper.« less

  18. ORNL Remedial Action Program strategy (FY 1987-FY 1992)

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Trabalka, J.R.; Myrick, T.E.

    1987-12-01

    Over 40 years of Oak Ridge National Laboratory (ORNL) operations have produced a diverse legacy of contaminated inactive facilities, research areas, and waste disposal areas that are potential candidates for remedial action. The ORNL Remedial Action Program (RAP) represents a comprehensive effort to meet new regulatory requirements and ensure adequate protection of on-site workers, the public, and the environment by providing appropriate corrective measures at over 130 sites contaminated historically with radioactive, hazardous chemical, or mixed wastes. A structured path of program planning, site characterization, alternatives assessment, technology development, engineering design, continued site maintenance and surveillance, interim corrective action, andmore » eventual site closure or decommissioning is required to meet these objectives. This report documents the development of the Remedial Action Program, through its preliminary characterization, regulatory interface, and strategy development activities. It provides recommendations for a comprehensive, long-term strategy consistent with existing technical, institutional, and regulatory information, along with a six-year plan for achieving its initial objectives. 53 refs., 8 figs., 12 tabs.« less

  19. Assessment of the state of food waste treatment in the United States and Canada.

    PubMed

    Levis, J W; Barlaz, M A; Themelis, N J; Ulloa, P

    2010-01-01

    Currently in the US, over 97% of food waste is estimated to be buried in landfills. There is nonetheless interest in strategies to divert this waste from landfills as evidenced by a number of programs and policies at the local and state levels, including collection programs for source separated organic wastes (SSO). The objective of this study was to characterize the state-of-the-practice of food waste treatment alternatives in the US and Canada. Site visits were conducted to aerobic composting and two anaerobic digestion facilities, in addition to meetings with officials that are responsible for program implementation and financing. The technology to produce useful products from either aerobic or anaerobic treatment of SSO is in place. However, there are a number of implementation issues that must be addressed, principally project economics and feedstock purity. Project economics varied by region based on landfill disposal fees. Feedstock purity can be obtained by enforcement of contaminant standards and/or manual or mechanical sorting of the feedstock prior to and after treatment. Future SSO diversion will be governed by economics and policy incentives, including landfill organics bans and climate change mitigation policies. 2010 Elsevier Ltd. All rights reserved.

  20. Enhancement of biofuels production by means of co-pyrolysis of Posidonia oceanica (L.) and frying oil wastes: Experimental study and process modeling.

    PubMed

    Zaafouri, Kaouther; Ben Hassen Trabelsi, Aida; Krichah, Samah; Ouerghi, Aymen; Aydi, Abdelkarim; Claumann, Carlos Alberto; André Wüst, Zibetti; Naoui, Silm; Bergaoui, Latifa; Hamdi, Moktar

    2016-05-01

    Energy recovery from lignocellulosic solid marine wastes, Posidonia oceanica wastes (POW) with slow pyrolysis responds to the growing trend of alternative energies as well as waste management. Physicochemical, thermogravimetric (TG/DTG) and spectroscopic (FTIR) characterizations of POW were performed. POW were first converted by pyrolysis at different temperatures (450°C, 500°C, 550°C and 600°C) using a fixed-bed reactor. The obtained products (bio-oil, syngas and bio char) were analyzed. Since the bio-oil yield obtained from POW pyrolysis is low (2wt.%), waste frying oil (WFO) was added as a co-substrate in order to improve of biofuels production. The co-pyrolysis gave a better yield of liquid organic fraction (37wt.%) as well as syngas (CH4,H2…) with a calorific value around 20MJ/kg. The stoichiometric models of both pyrolysis and co-pyrolysis reactions were performed according to the biomass formula: CαHβOγNδSε. The thermal kinetic decomposition of solids was validated through linearized Arrhenius model. Copyright © 2016 Elsevier Ltd. All rights reserved.

  1. Waste Generation Overview, Course 23263

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Simpson, Lewis Edward

    This course, Waste Generation Overview Live (COURSE 23263), provides an overview of federal and state waste management regulations, as well as Los Alamos National Laboratory (LANL) policies and procedures for waste management operations. The course covers the activities involved in the cradle-to-grave waste management process and focuses on waste characterization, waste compatibility determinations and classification, and the storage requirements for temporary waste accumulation areas at LANL. When you have completed this course, you will be able to recognize federal, state, and LANL environmental requirements and their impact on waste operations; recognize the importance of the cradle-to-grave waste management process; identifymore » the roles and responsibilities of key LANL waste management personnel (e.g., Waste Generator, Waste Management Coordinator, Waste Stream Profile approver, and Waste Certification Official); characterize a waste stream to determine whether it meets the definition of a hazardous waste, as well as characterize the use and minimum requirements for use of acceptable knowledge (AK) for waste characterization and waste compatibility documentation requirements; and identify the requirements for setting up and managing temporary waste accumulation areas.« less

  2. Treatment and disposal alternatives for health-care waste in developing countries--a case study in Istanbul, Turkey.

    PubMed

    Alagöz, B Aylin Zeren; Kocasoy, Günay

    2007-02-01

    Efficient health-care waste management is crucial for the prevention of the exposure of health-care workers, patients, and the community to infections, toxic wastes and injuries as well as the protection of the environment (Safe Management of Wastes from Health-care Activities. World Health Organization, Geneva). The amount of health-care waste produced in the Istanbul Metropolitan City in Turkey is 30 ton day(-1) in total. The method used for the final disposal of most of the health-care waste of Istanbul is incineration. However, a great portion of the infectious waste is disposed of with the domestic waste into the sanitary landfill because of improper segregation practices applied in the health-care institutions. Therefore the alternatives for the treatment and disposal of health-care waste were evaluated. The technical information related to the available treatment technologies including incineration, microwave irradiation, mobile or stationary sterilization, etc. were also investigated. The capital investment cost, transportation/operational costs for each alternative method and the different locations for installation were compared. When the data collected were evaluated, it was found that separate handling and disposal of health-care waste generated on the European and the Asian sides of the city was the most economic and practicable solution. As a result, it was concluded that the capacity of the Kemerburgaz-Odayeri incineration plant is enough to incinerate the health-care waste generated on the European side of Istanbul, the construction of a new incineration plant or a stationary sterilization unit for the disposal of health-care waste generated on the Asian side was the most effective alternative.

  3. Solid rocket propellant waste disposal/ingredient recovery study

    NASA Technical Reports Server (NTRS)

    Mcintosh, M. J.

    1976-01-01

    A comparison of facility and operating costs of alternate methods shows open burning to be the lowest cost incineration method of waste propellant disposal. The selection, development, and implementation of an acceptable alternate is recommended. The recovery of ingredients from waste propellant has the probability of being able to pay its way, and even show a profit, when large consistent quantities of composite propellant are available. Ingredients recovered from space shuttle waste propellant would be worth over $1.5 million. Open and controlled burning are both energy wasteful.

  4. Economic aspects of thermal treatment of solid waste in a sustainable WM system

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Massarutto, Antonio

    2015-03-15

    Highlights: • Provides a comprehensive review of the applied economic literature dedicated to WtE. • Offers a detailed discussion of the main assumptions that characterize alternative positions. • Highlights the most robust achievements obtained by the applied economic research in this field. • Compares economic and non-economic valuation techniques. - Abstract: This paper offers a systematic review of the literature of the last 15 years, which applies economic analysis and theories to the issue of combustion of solid waste. Waste incineration has attracted the interest of economists in the first place concerning the comparative assessment of waste management options, withmore » particular reference to external costs and benefits. A second important field of applied economic research concerns the market failures associated with the provision of thermal treatment of waste, that justify some deviation from the standard competitive market model. Our analysis discusses the most robust achievements and the more controversial areas. All in all, the economic perspective seems to confirm the desirability of assigning a prominent role to thermal treatments in an integrated waste management strategy. Probably the most interesting original contribution it has to offer concerns the refusal of categorical assumptions and too rigid priority ladders, emphasizing instead the need to consider site-specific circumstances that may favor one or another solution.« less

  5. Agricultural utilization of biosolids: A review on potential effects on soil and plant grown.

    PubMed

    Sharma, Bhavisha; Sarkar, Abhijit; Singh, Pooja; Singh, Rajeev Pratap

    2017-06-01

    Environmental and economic implications linked with the proper ecofriendly disposal of modern day wastes, has made it essential to come up with alternative waste management practices that reduce the environmental pressures resulting from unwise disposal of such wastes. Urban wastes like biosolids are loaded with essential plant nutrients. In this view, agricultural use of biosolids would enable recycling of these nutrients and could be a sustainable approach towards management of this hugely generated waste. Therefore biosolids i.e. sewage sludge can serve as an important resource for agricultural utilization. Biosolids are characterized by the occurrence of beneficial plant nutrients (essential elements and micro and macronutrients) which can make help them to work as an effective soil amendment, thereby minimizing the reliance on chemical fertilizers. However, biosolids might contain toxic heavy metals that may limit its usage in the cropland. Heavy metals at higher concentration than the permissible limits may lead to food chain contamination and have fatal consequences. Biosolids amendment in soil can improve physical and nutrient property of soil depending on the quantity and portion of the mixture. Hence, biosolids can be a promising soil ameliorating supplement to increase plant productivity, reduce bioavailability of heavy metals and also lead to effective waste management. Copyright © 2017 Elsevier Ltd. All rights reserved.

  6. Waste management facility accident analysis (WASTE ACC) system: software for analysis of waste management alternatives

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Kohout, E.F.; Folga, S.; Mueller, C.

    1996-03-01

    This paper describes the Waste Management Facility Accident Analysis (WASTE{underscore}ACC) software, which was developed at Argonne National Laboratory (ANL) to support the US Department of Energy`s (DOE`s) Waste Management (WM) Programmatic Environmental Impact Statement (PEIS). WASTE{underscore}ACC is a decision support and database system that is compatible with Microsoft{reg_sign} Windows{trademark}. It assesses potential atmospheric releases from accidents at waste management facilities. The software provides the user with an easy-to-use tool to determine the risk-dominant accident sequences for the many possible combinations of process technologies, waste and facility types, and alternative cases described in the WM PEIS. In addition, its structure willmore » allow additional alternative cases and assumptions to be tested as part of the future DOE programmatic decision-making process. The WASTE{underscore}ACC system demonstrates one approach to performing a generic, systemwide evaluation of accident risks at waste management facilities. The advantages of WASTE{underscore}ACC are threefold. First, the software gets waste volume and radiological profile data that were used to perform other WM PEIS-related analyses directly from the WASTE{underscore}MGMT system. Second, the system allows for a consistent analysis across all sites and waste streams, which enables decision makers to understand more fully the trade-offs among various policy options and scenarios. Third, the system is easy to operate; even complex scenario runs are completed within minutes.« less

  7. Emissions from open burning of simulated military waste from forward operating bases.

    PubMed

    Aurell, Johanna; Gullett, Brian K; Yamamoto, Dirk

    2012-10-16

    Emissions from open burning of simulated military waste from forward operating bases (FOBs) were extensively characterized as an initial step in assessing potential inhalation exposure of FOB personnel and future disposal alternatives. Emissions from two different burning scenarios, so-called "burn piles/pits" and an air curtain burner/"burn box", were compared using simulated FOB waste from municipal and commercial sources. A comprehensive array of emissions was quantified, including CO(2), PM(2.5), volatile organic compounds (VOCs), polyaromatic hydrocarbons (PAHs), polychlorinated dibenzodioxins and -furans (PCDDs/PCDFs), polybrominated dibenzodioxins and -furans (PBDDs/PBDFs), and metals. In general, smoldering conditions in the burn box and the burn pile led to similar emissions. However, when the burn box underwent periodic waste charging to maintain sustained combustion, PM(2.5), VOCs, and PAH emissions dropped considerably compared to smoldering conditions and the overall burn pile results. The PCDD/PCDF and PBDD/PBDF emission factors for the burn piles were 50 times higher than those from the burn box likely due to the dominance of smoldering combustion in the burn piles.

  8. Closure Report for Corrective Action Unit 151: Septic Systems and Discharge Area, Nevada Test Site, Nevada

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    NSTec Environmental Restoration

    2008-04-01

    Corrective Action Unit (CAU) 151 is identified in the Federal Facility Agreement and Consent Order (FFACO) as Septic Systems and Discharge Area. CAU 151 consists of the following eight Corrective Action Sites (CASs), located in Areas 2, 12, and 18 of the Nevada Test Site, approximately 65 miles northwest of Las Vegas, Nevada: (1) CAS 02-05-01, UE-2ce Pond; (2) CAS 12-03-01, Sewage Lagoons (6); (3) CAS 12-04-01, Septic Tanks; (4) CAS 12-04-02, Septic Tanks; (5) CAS 12-04-03, Septic Tank; (6) CAS 12-47-01, Wastewater Pond; (7) CAS 18-03-01, Sewage Lagoon; and (8) CAS 18-99-09, Sewer Line (Exposed). CAU 151 closure activitiesmore » were conducted according to the FFACO (FFACO, 1996; as amended February 2008) and the Corrective Action Plan for CAU 151 (U.S. Department of Energy, National Nuclear Security Administration Nevada Site Office, 2007) from October 2007 to January 2008. The corrective action alternatives included no further action, clean closure, and closure in place with administrative controls. CAU 151 closure activities are summarized in Table 1. Closure activities generated liquid remediation waste, sanitary waste, hydrocarbon waste, and mixed waste. Waste generated was appropriately managed and disposed. Waste that is currently staged onsite is being appropriately managed and will be disposed under approved waste profiles in permitted landfills. Waste minimization activities included waste characterization sampling and segregation of waste streams. Some waste exceeded land disposal restriction limits and required offsite treatment prior to disposal. Other waste meeting land disposal restrictions was disposed of in appropriate onsite or offsite landfills. Waste disposition documentation is included as Appendix C.« less

  9. 40 CFR 60.50c - Applicability and delegation of authority.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ...) Cement kilns firing hospital waste and/or medical/infectious waste are not subject to this subpart. (h... when using controls other than those listed in Sec. 60.56c(d). (2) Approval of alternative methods of... major alternatives to test methods; (3) Approval of major alternatives to monitoring; (4) Waiver of...

  10. Alternative bioenergy through the utilization of Kappaphycus alvarezii waste as a substitution of substrate for biogas products

    NASA Astrophysics Data System (ADS)

    Yulita, R.; Agustono; Pujiastuti, D. Y.; Alamsjah, M. A.

    2018-04-01

    Biogas is one of the renewable energy resources which are able to be developed by providing some sufficient renewable substances and manufactured from the fermentation process of organic substances metabolized by anaerobic bacteria. In this research, Kappaphycus alvarezii seaweed waste from carrageenan processing and contents of rumen were used. This research aims to comprehend the carrageenan processing waste of macroalga K. alvarezii can be used as alternative source generating biogas. The research method is P0 (100 % of the contents of rumen), P1 (75 % of the contents of rumen and 25 % of seaweed waste), P2 (50 % of the contents of rumen and 50 % of seaweed waste), and P3 (25 % of the contents of rumen and 75 % of seaweed waste), and P4 (100 % of seaweed waste). The result showed that according to the quality determination of biogas based on SNI (Indonesia National Standard) 8019:2014, the K. alvarezii seaweed waste from carrageenan processing can be utilized as the alternative source of manufacturing biogas and got the methane gas resulted from the comparison method is P2 (50 % of the contents of rumen and 50 % of seaweed waste), with value of 58.61 %.

  11. DOE Office of Scientific and Technical Information (OSTI.GOV)

    Banar, Mufide; Cokaygil, Zerrin; Ozkan, Aysun

    Life cycle assessment (LCA) methodology was used to determine the optimum municipal solid waste (MSW) management strategy for Eskisehir city. Eskisehir is one of the developing cities of Turkey where a total of approximately 750 tons/day of waste is generated. An effective MSW management system is needed in this city since the generated MSW is dumped in an unregulated dumping site that has no liner, no biogas capture, etc. Therefore, five different scenarios were developed as alternatives to the current waste management system. Collection and transportation of waste, a material recovery facility (MRF), recycling, composting, incineration and landfilling processes weremore » considered in these scenarios. SimaPro7 libraries were used to obtain background data for the life cycle inventory. One ton of municipal solid waste of Eskisehir was selected as the functional unit. The alternative scenarios were compared through the CML 2000 method and these comparisons were carried out from the abiotic depletion, global warming, human toxicity, acidification, eutrophication and photochemical ozone depletion points of view. According to the comparisons and sensitivity analysis, composting scenario, S3, is the more environmentally preferable alternative. In this study waste management alternatives were investigated only on an environmental point of view. For that reason, it might be supported with other decision-making tools that consider the economic and social effects of solid waste management.« less

  12. DOE Office of Scientific and Technical Information (OSTI.GOV)

    Lee, S.Y.; Valenti, J.C.; Tabor, D.G.

    The use of waste wood as fuel for producing energy is a promising supplement to fossil fuels for many regions of the country. In addition to recovering energy and conserving landfill space, burning waste wood fuels also mitigates global warming created by fossil fuel combustion. However, the environmental consequences resulting from emissions generated by combustion of waste wood which contains paints, resins, or preservatives are not well understood. The combustion of waste wood treated with chemicals may produce potentially hazardous products of incomplete combustion (PIC) emissions such as dioxins. Characterization of PIC emissions from the combustion of waste wood previouslymore » treated with pentachlorophenol is reported in this study. Utility poles and crossbars are typically treated with a preservative such as pentachlorophenol in order to prolong their service life. They are disposed of by landfilling after being taken out of service. Burning such wood waste in boilers for steam generation becomes an increasingly attractive waste management alternative as it contains substantial energy value and reduces landfilling costs. Pilot-scale combustion tests were conducted under well controlled conditions in a 0.58 MW (2 million Btu/hr) combustor to compare PIC emissions from burning untreated wood and pentachlorophenol-treated wood. Sampling and analyses for a wide variety of PICs, including volatile organic compounds (VOCs), semivolatile organic compounds, and dioxins and furans, were performed to assess the effect of pentachlorophenol preservative present in wood on PIC emissions.« less

  13. Recycling the product of thermal transformation of cement-asbestos for the preparation of calcium sulfoaluminate clinker.

    PubMed

    Viani, Alberto; Gualtieri, Alessandro F

    2013-09-15

    According to recent resolutions of the European Parliament (2012/2065(INI)), the need for environmentally friendly alternative solutions to landfill disposal of hazardous wastes, such as asbestos-containing materials, prompts their recycling as secondary raw materials (end of waste concept). In this respect, for the first time, we report the recycling of the high temperature product of cement-asbestos, in the formulation of calcium sulfoaluminate cement clinkers (novel cementitious binders designed to reduce CO₂ emissions), as a continuation of a previous work on their systematic characterization. Up to 29 wt% of the secondary raw material was successfully introduced into the raw mix. Different clinker samples were obtained at 1250 °C and 1300 °C, reproducing the phase composition of industrial analogues. As an alternative source of Ca and Si, this secondary raw material allows for a reduction of the CO₂ emissions in cement production, mitigating the ecological impact of cement manufacturing, and reducing the need for natural resources. Copyright © 2013 Elsevier B.V. All rights reserved.

  14. SOLVENT WASTE REDUCTION ALTERNATIVES

    EPA Science Inventory

    This publication contains edited versions of presentations on this subject made at five Technology Transfer seminars in 1988. Chapters are included on land disposal regulations and requirements; waste solvent disposal alternatives from various industries such as process equipment...

  15. Defense Remote Handled Transuranic Waste Cost/Schedule Optimization Study

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Pierce, G.D.; Beaulieu, D.H.; Wolaver, R.W.

    1986-11-01

    The purpose of this study is to provide the DOE information with which it can establish the most efficient program for the long management and disposal, in the Waste Isolation Pilot Plant (WIPP), of remote handled (RH) transuranic (TRU) waste. To fulfill this purpose, a comprehensive review of waste characteristics, existing and projected waste inventories, processing and transportation options, and WIPP requirements was made. Cost differences between waste management alternatives were analyzed and compared to an established baseline. The result of this study is an information package that DOE can use as the basis for policy decisions. As part ofmore » this study, a comprehensive list of alternatives for each element of the baseline was developed and reviewed with the sites. The principle conclusions of the study follow. A single processing facility for RH TRU waste is both necessary and sufficient. The RH TRU processing facility should be located at Oak Ridge National Laboratory (ORNL). Shielding of RH TRU to contact handled levels is not an economic alternative in general, but is an acceptable alternative for specific waste streams. Compaction is only cost effective at the ORNL processing facility, with a possible exception at Hanford for small compaction of paint cans of newly generated glovebox waste. It is more cost effective to ship certified waste to WIPP in 55-gal drums than in canisters, assuming a suitable drum cask becomes available. Some waste forms cannot be packaged in drums, a canister/shielded cask capability is also required. To achieve the desired disposal rate, the ORNL processing facility must be operational by 1996. Implementing the conclusions of this study can save approximately $110 million, compared to the baseline, in facility, transportation, and interim storage costs through the year 2013. 10 figs., 28 tabs.« less

  16. Evaluation of final waste forms and recommendations for baseline alternatives to group and glass

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Bleier, A.

    1997-09-01

    An assessment of final waste forms was made as part of the Federal Facilities Compliance Agreement/Development, Demonstration, Testing, and Evaluation (FFCA/DDT&E) Program because supplemental waste-form technologies are needed for the hazardous, radioactive, and mixed wastes of concern to the Department of Energy and the problematic wastes on the Oak Ridge Reservation. The principal objective was to identify a primary waste-form candidate as an alternative to grout (cement) and glass. The effort principally comprised a literature search, the goal of which was to establish a knowledge base regarding four areas: (1) the waste-form technologies based on grout and glass, (2) candidatemore » alternatives, (3) the wastes that need to be immobilized, and (4) the technical and regulatory constraints on the waste-from technologies. This report serves, in part, to meet this goal. Six families of materials emerged as relevant; inorganic, organic, vitrified, devitrified, ceramic, and metallic matrices. Multiple members of each family were assessed, emphasizing the materials-oriented factors and accounting for the fact that the two most prevalent types of wastes for the FFCA/DDT&E Program are aqueous liquids and inorganic sludges and solids. Presently, no individual matrix is sufficiently developed to permit its immediate implementation as a baseline alternative. Three thermoplastic materials, sulfur-polymer cement (inorganic), bitumen (organic), and polyethylene (organic), are the most technologically developed candidates. Each warrants further study, emphasizing the engineering and economic factors, but each also has limitations that regulate it to a status of short-term alternative. The crystallinity and flexible processing of sulfur provide sulfur-polymer cement with the highest potential for short-term success via encapsulation. Long-term immobilization demands chemical stabilization, which the thermoplastic matrices do not offer. Among the properties of the remaining candidates, those of glass-ceramics (devitrified matrices) represent the best compromise for meeting the probable stricter disposal requirements in the future.« less

  17. Arsenic: a roadblock to potential animal waste management solutions.

    PubMed

    Nachman, Keeve E; Graham, Jay P; Price, Lance B; Silbergeld, Ellen K

    2005-09-01

    The localization and intensification of the poultry industry over the past 50 years have incidentally created a largely ignored environmental management crisis. As a result of these changes in poultry production, concentrated animal feeding operations (CAFOs) produce far more waste than can be managed by land disposal within the regions where it is produced. As a result, alternative waste management practices are currently being implemented, including incineration and pelletization of waste. However, organic arsenicals used in poultry feed are converted to inorganic arsenicals in poultry waste, limiting the feasibility of waste management alternatives. The presence of inorganic arsenic in incinerator ash and pelletized waste sold as fertilizer creates opportunities for population exposures that did not previously exist. The removal of arsenic from animal feed is a critical step toward safe poultry waste management.

  18. Characterization of urban solid waste in Chihuahua, Mexico.

    PubMed

    Gomez, Guadalupe; Meneses, Montserrat; Ballinas, Lourdes; Castells, Francesc

    2008-12-01

    The characterization of urban solid waste generation is fundamental for adequate decision making in the management strategy of urban solid waste in a city. The objective of this study is to characterize the waste generated in the households of Chihuahua city, and to compare the results obtained in areas of the city with three different socioeconomic levels. In order to identify the different socioeconomic trends in waste generation and characterization, 560 samples of solid waste were collected during 1 week from 80 households in Chihuahua and were hand sorted and classified into 15 weighted fractions. The average waste generation in Chihuahua calculated in this study was 0.676 kg per capita per day in April 2006. The main fractions were: organic (48%), paper (16%) and plastic (12%). Results show an increased waste generation associated with the socioeconomic level. The characterization in amount and composition of urban waste is the first step needed for the successful implementation of an integral waste management system.

  19. High-level waste program progress report, April 1, 1980-June 30, 1980

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    None

    1980-08-01

    The highlights of this report are on: waste management analysis for nuclear fuel cycles; fixation of waste in concrete; study of ceramic and cermet waste forms; alternative high-level waste forms development; and high-level waste container development.

  20. Corrective Action Decision Document for Corrective Action Unit 428: Area 3 Septic Waste Systems 1 and 5, Tonopah Test Range, Nevada

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    U.S. Department of Energy, Nevada Operations Office

    2000-02-08

    This Corrective Action Decision Document identifies and rationalizes the US Department of Energy, Nevada Operations Office's selection of a recommended corrective action alternative (CAA) appropriate to facilitate the closure of Corrective Action Unit (CAU) 428, Septic Waste Systems 1 and 5, under the Federal Facility Agreement and Consent Order. Located in Area 3 at the Tonopah Test Range (TTR) in Nevada, CAU 428 is comprised of two Corrective Action Sites (CASs): (1) CAS 03-05-002-SW01, Septic Waste System 1 and (2) CAS 03-05-002- SW05, Septic Waste System 5. A corrective action investigation performed in 1999 detected analyte concentrations that exceeded preliminarymore » action levels; specifically, contaminants of concern (COCs) included benzo(a) pyrene in a septic tank integrity sample associated with Septic Tank 33-1A of Septic Waste System 1, and arsenic in a soil sample associated with Septic Waste System 5. During this investigation, three Corrective Action Objectives (CAOs) were identified to prevent or mitigate exposure to contents of the septic tanks and distribution box, to subsurface soil containing COCs, and the spread of COCs beyond the CAU. Based on these CAOs, a review of existing data, future use, and current operations in Area 3 of the TTR, three CAAs were developed for consideration: Alternative 1 - No Further Action; Alternative 2 - Closure in Place with Administrative Controls; and Alternative 3 - Clean Closure by Excavation and Disposal. These alternatives were evaluated based on four general corrective action standards and five remedy selection decision factors. Based on the results of the evaluation, the preferred CAA was Alternative 3. This alternative meets all applicable state and federal regulations for closure of the site and will eliminate potential future exposure pathways to the contaminated soils at the Area 3 Septic Waste Systems 1 and 5.« less

  1. Environmental and Geotechnical Assessment of the Steel Slags as a Material for Road Structure

    PubMed Central

    Sas, Wojciech; Głuchowski, Andrzej; Radziemska, Maja; Dzięcioł, Justyna; Szymański, Alojzy

    2015-01-01

    Slags are the final solid wastes from the steel industry. Their production from waste and associated materials is a proper implementation of the basic objectives and principles of the waste management. This study aims to investigate the chemical and selected significant geotechnical parameters of steel slag as the alternative materials used in road construction. These investigations are strongly desired for successful application in engineering. Young’s modules E, and resilient modules Mr showed that their values corresponding with requirements for subbase (principal or auxiliary) and riding surface as well. Tested mechanical properties were conducted in soaked and un-soaked (optimal moisture content) conditions. The designated high content of chromium and zinc are strongly associated with the internal crystal structure of steel slag. The results do not lead to threats when they are applied in roads’ structures. Mechanical characterization was obtained by performing California bearing ratio (CBR) tests for steel slag in fixed compaction and moisture content conditions. Moreover, cyclic loading of steel slag was conducted with the application of cyclic California bearing ratio (cCBR) apparatus to characterization of this material as a controlled low-strength material. Finally, field studies that consist of static load plate VSS tests were presented. PMID:28793477

  2. Alternative fuels for multiple-hearth furnaces

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Bracken, B.D.; Lawson, T.U.

    1980-04-01

    A study of alternative procedures for reducing the consumption of No. 2 fuel oil at the Lower Molonglo Water Quality Control Centre near Canberra, Aust., indicated that in comparison with the present system of incineration with heat supplied by burning fuel oil, the installation of a sludge drying operation, consisting of a rotary dryer heated by furnace exhaust gases with the dried sludge used to fuel the furnace, would become economically desirable by 1985 if afterburning is not required, and would be justified immediately if afterburning is required to meet air pollution control regulations. The substitution of any of fourmore » waste fuels (refuse-derived fuel, waste paper, wood waste, or waste oil) or of coal for the No. 2 fuel oil would not be cost-effective through 1989. The furnace system, including afterburning and fuel oil requirements, the envisioned alternative fuel use systems, sludge processing alternatives, heat balance results, and economics are discussed.« less

  3. 40 CFR Appendix D to Part 63 - Alternative Validation Procedure for EPA Waste and Wastewater Methods

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 40 Protection of Environment 14 2010-07-01 2010-07-01 false Alternative Validation Procedure for EPA Waste and Wastewater Methods D Appendix D to Part 63 Protection of Environment ENVIRONMENTAL... POLLUTANTS FOR SOURCE CATEGORIES (CONTINUED) Pt. 63, App. D Appendix D to Part 63—Alternative Validation...

  4. 40 CFR Appendix D to Part 63 - Alternative Validation Procedure for EPA Waste and Wastewater Methods

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 40 Protection of Environment 14 2011-07-01 2011-07-01 false Alternative Validation Procedure for EPA Waste and Wastewater Methods D Appendix D to Part 63 Protection of Environment ENVIRONMENTAL... POLLUTANTS FOR SOURCE CATEGORIES (CONTINUED) Pt. 63, App. D Appendix D to Part 63—Alternative Validation...

  5. 40 CFR Appendix D to Part 63 - Alternative Validation Procedure for EPA Waste and Wastewater Methods

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 40 Protection of Environment 15 2014-07-01 2014-07-01 false Alternative Validation Procedure for EPA Waste and Wastewater Methods D Appendix D to Part 63 Protection of Environment ENVIRONMENTAL... POLLUTANTS FOR SOURCE CATEGORIES (CONTINUED) Pt. 63, App. D Appendix D to Part 63—Alternative Validation...

  6. 40 CFR Appendix D to Part 63 - Alternative Validation Procedure for EPA Waste and Wastewater Methods

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 40 Protection of Environment 15 2013-07-01 2013-07-01 false Alternative Validation Procedure for EPA Waste and Wastewater Methods D Appendix D to Part 63 Protection of Environment ENVIRONMENTAL... POLLUTANTS FOR SOURCE CATEGORIES (CONTINUED) Pt. 63, App. D Appendix D to Part 63—Alternative Validation...

  7. 40 CFR Appendix D to Part 63 - Alternative Validation Procedure for EPA Waste and Wastewater Methods

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... 40 Protection of Environment 15 2012-07-01 2012-07-01 false Alternative Validation Procedure for EPA Waste and Wastewater Methods D Appendix D to Part 63 Protection of Environment ENVIRONMENTAL... POLLUTANTS FOR SOURCE CATEGORIES (CONTINUED) Pt. 63, App. D Appendix D to Part 63—Alternative Validation...

  8. West Valley demonstration project: Alternative processes for solidifying the high-level wastes

    NASA Astrophysics Data System (ADS)

    Holton, L. K.; Larson, D. E.; Partain, W. L.; Treat, R. L.

    1981-10-01

    Two pretreatment approaches and several waste form processes for radioactive wastes were selected for evaluation. The two waste treatment approaches were the salt/sludge separation process and the combined waste process. Both terminal and interim waste form processes were studied.

  9. Utilization of waste cooking oil as an alternative fuel for Turkey.

    PubMed

    Arslan, Ridvan; Ulusoy, Yahya

    2017-04-03

    This study is based on three essential considerations concerning biodiesel obtained from waste cooking oil: diesel engine emissions of biodiesel produced from waste cooking oil, its potential in Turkey, and policies of the Turkish government about environmentally friendly alternative fuels. Emission tests have been realized with 35.8 kW, four-cylinder, four-stroke, direct injection diesel tractor engine. Test results are compared with Euro non-road emission standards for diesel fuel and five different blends of biodiesel production from waste cooking oil. The results of the experimental study show that the best blends are B10 and B20 as they show the lowest emission level. The other dimensions of the study include potential analysis of waste cooking oil as diesel fuels, referring to fuel price policies applied in the past, and proposed future policies about the same issues. It was also outlined some conclusions and recommendations in connection with recycling of waste oils as alternative fuels.

  10. Deoxygenation of waste cooking oil and non-edible oil for the production of liquid hydrocarbon biofuels.

    PubMed

    Romero, M J A; Pizzi, A; Toscano, G; Busca, G; Bosio, B; Arato, E

    2016-01-01

    Deoxygenation of waste cooking vegetable oil and Jatropha curcas oil under nitrogen atmosphere was performed in batch and semi-batch experiments using CaO and treated hydrotalcite (MG70) as catalysts at 400 °C. In batch conditions a single liquid fraction (with yields greater than 80 wt.%) was produced containing a high proportion of hydrocarbons (83%). In semi-batch conditions two liquid fractions (separated by a distillation step) were obtained: a light fraction and an intermediate fraction containing amounts of hydrocarbons between 72-80% and 85-88% respectively. In order to assess the possible use of the liquid products as alternative fuels a complete chemical characterization and measurement of their properties were carried out. Copyright © 2015 Elsevier Ltd. All rights reserved.

  11. Hybrid life-cycle assessment (LCA) of CO2 emission with management alternatives for household food wastes in Japan.

    PubMed

    Inaba, Rokuta; Nansai, Keisuke; Fujii, Minoru; Hashimoto, Seiji

    2010-06-01

    In this study, we conducted a hybrid life-cycle assessment (LCA) to evaluate reductions in CO(2) emissions by food waste biogasification of household food wastes in Japan. Two alternative scenarios were examined. In one alternative (Ref), all combustible municipal solid wastes (MSWs), including food waste, are incinerated. In the other (Bio), food waste is biogasified, while the other combustible wastes are incinerated. An inventory analysis of energy and material flow in the MSW management system was conducted. Subsequently, the inventory data were summarized into an input-output format, and a make-use input-output framework was applied. Furthermore, a production equilibrium model was established using a matrix representing the input- output relationship of energy and materials among the processes and sectors. Several levels of power generation efficiency from incineration were applied as a sensitivity analysis. The hybrid LCA indicated that the difference between the Bio and Ref scenarios, from the perspective of CO( 2) emissions, is relatively small. However, a 13-14% reduction of CO(2) emissions of the total waste management sector in Japan may be achieved by improving the efficiency of power generation from incineration from 10% to 25%.

  12. Vehicle routing for the eco-efficient collection of household plastic waste.

    PubMed

    Bing, Xiaoyun; de Keizer, Marlies; Bloemhof-Ruwaard, Jacqueline M; van der Vorst, Jack G A J

    2014-04-01

    Plastic waste is a special category of municipal solid waste. Plastic waste collection is featured with various alternatives of collection methods (curbside/drop-off) and separation methods (source-/post-separation). In the Netherlands, the collection routes of plastic waste are the same as those of other waste, although plastic is different than other waste in terms of volume to weight ratio. This paper aims for redesigning the collection routes and compares the collection options of plastic waste using eco-efficiency as performance indicator. Eco-efficiency concerns the trade-off between environmental impacts, social issues and costs. The collection problem is modeled as a vehicle routing problem. A tabu search heuristic is used to improve the routes. Collection alternatives are compared by a scenario study approach. Real distances between locations are calculated with MapPoint. The scenario study is conducted based on real case data of the Dutch municipality Wageningen. Scenarios are designed according to the collection alternatives with different assumptions in collection method, vehicle type, collection frequency and collection points, etc. Results show that the current collection routes can be improved in terms of eco-efficiency performance by using our method. The source-separation drop-off collection scenario has the best performance for plastic collection assuming householders take the waste to the drop-off points in a sustainable manner. The model also shows to be an efficient decision support tool to investigate the impacts of future changes such as alternative vehicle type and different response rates. Crown Copyright © 2014. Published by Elsevier Ltd. All rights reserved.

  13. INVESTIGATION OF WASTE RAG GENERATION AT NAVAL STATION MAYPORT

    EPA Science Inventory

    This report presents the results of an investigation examining pollution prevention alternatives for reducing the volume of waste rags generated at Naval Station Mayport, located near Jacksonville Beach, Florida. he report recommends five specific pollution prevention alternative...

  14. AAFES Shopping Center Environmental Assessment

    DTIC Science & Technology

    2009-08-01

    Plan H2S Hydrogen Sulfide SO2 Sulfur Dioxide HWMP Hazardous Waste Management Plan SMW Strategic Missile Wing ICBM Intercontinental Ballistic Missile...the no-action alternative. Land Management and Use. A waiver would be needed prior to construction to change the land use designation from Open...occur under the no-action alternative. Hazardous Materials and Waste Management . No changes to hazardous materials or waste streams would occur

  15. Waste Reduction Model

    EPA Pesticide Factsheets

    To help solid waste planners and organizations track/report GHG emissions reductions from various waste management practices. To assist in calculating GHG emissions of baseline and alternative waste management practices and provide the history of WARM.

  16. Development of characterization protocol for mixed liquid radioactive waste classification

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Zakaria, Norasalwa, E-mail: norasalwa@nuclearmalaysia.gov.my; Wafa, Syed Asraf; Wo, Yii Mei

    2015-04-29

    Mixed liquid organic waste generated from health-care and research activities containing tritium, carbon-14, and other radionuclides posed specific challenges in its management. Often, these wastes become legacy waste in many nuclear facilities and being considered as ‘problematic’ waste. One of the most important recommendations made by IAEA is to perform multistage processes aiming at declassification of the waste. At this moment, approximately 3000 bottles of mixed liquid waste, with estimated volume of 6000 litres are currently stored at the National Radioactive Waste Management Centre, Malaysia and some have been stored for more than 25 years. The aim of this studymore » is to develop a characterization protocol towards reclassification of these wastes. The characterization protocol entails waste identification, waste screening and segregation, and analytical radionuclides profiling using various analytical procedures including gross alpha/ gross beta, gamma spectrometry, and LSC method. The results obtained from the characterization protocol are used to establish criteria for speedy classification of the waste.« less

  17. Wastes and by-products - alternatives for agricultural use

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Boles, J.L.; Craft, D.J.; Parker, B.R.

    1994-10-01

    Top address a growing national problem with generation of wastes and by-products, TVA has been involved for several years with developing and commercializing environmentally responsible practices for eliminating, minimizing, or utilizing various wastes/by-products. In many cases, reducing waste generation is impractical, but the wastes/by-products can be converted into other environmentally sound products. In some instances, conversion of safe, value-added agricultural products in the best or only practical alternative. TVA is currently involved with a diversity of projects converting wastes/by-products into safe, economical, and agriculturally beneficial products. Environmental improvement projects have involved poultry litter, cellulosic wastes, used battery acid, ammonium sulfatemore » fines, lead smelting effluents, deep-welled sulfuric acid/ammonium bisulfate solutions, wood ash, waste magnesium ammonium sulfate slurry from recording tape production, and ammunition plant waste sodium nitrate/ammonium nitrate streams.« less

  18. RH-TRU Waste Inventory Characterization by AK and Proposed WIPP RH-TRU Waste Characterization Objectives

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Most, W. A.; Kehrman, R.; Gist, C.

    2002-02-26

    The U.S. Department of Energy (DOE)-Carlsbad Field Office (CBFO) has developed draft documentation to present the proposed Waste Isolation Pilot Plant (WIPP) remote-handled (RH-) transuranic (TRU) waste characterization program to its regulators, the U.S. Environmental Protection Agency and the New Mexico Environment Department. Compliance with Title 40, Code of Federal Regulations, Parts 191 and 194; the WIPP Land Withdrawal Act (PL 102-579); and the WIPP Hazardous Waste Facility Permit, as well as the Certificates of Compliance for the 72-B and 10-160B Casks, requires that specific waste parameter limits be imposed on DOE sites disposing of TRU waste at WIPP. Themore » DOE-CBFO must control the sites' compliance with the limits by specifying allowable characterization methods. As with the established WIPP contact handled TRU waste characterization program, the DOE-CBFO has proposed a Remote-Handled TRU Waste Acceptance Criteria (RH-WAC) document consolidating the requirements from various regulatory drivers and proposed allowable characterization methods. These criteria are consistent with the recommendation of a recent National Academy Sciences/National Research Council to develop an RH-TRU waste characterization approach that removes current self imposed requirements that lack a legal or safety basis. As proposed in the draft RH-WAC and other preliminary documents, the DOE-CBFO RH-TRU waste characterization program proposes the use of acceptable knowledge (AK) as the primary method for obtaining required characterization information. The use of AK involves applying knowledge of the waste in light of the materials or processes used to generate the waste. Documentation, records, or processes providing information about various attributes of a waste stream, such as chemical, physical, and radiological properties, may be used as AK and may be applied to individual waste containers either independently or in conjunction with radiography, visual examination, assay, and other sampling and analytical data. RH-TRU waste cannot be shipped to WIPP on the basis of AK alone if documentation demonstrating that all of the prescribed limits in the RH-WAC are met is not available, discrepancies exist among AK source documents describing the same waste stream and the most conservative assumptions regarding those documents indicates that a limit will not be met, or all required data are not available for a given waste stream.« less

  19. 40 CFR 262.213 - Laboratory clean-outs.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... waste or more than 100 kg/month of hazardous waste (i.e., the conditionally exempt small quantity... 262.213 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES (CONTINUED) STANDARDS APPLICABLE TO GENERATORS OF HAZARDOUS WASTE Alternative Requirements for Hazardous Waste...

  20. 40 CFR 262.213 - Laboratory clean-outs.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... waste or more than 100 kg/month of hazardous waste (i.e., the conditionally exempt small quantity... 262.213 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES (CONTINUED) STANDARDS APPLICABLE TO GENERATORS OF HAZARDOUS WASTE Alternative Requirements for Hazardous Waste...

  1. HOUSEHOLD HAZARDOUS WASTE CHARACTERIZATION STUDY FOR PALM BEACH COUNTY, FLORIDA - A MITE PROGRAM EVALUATION

    EPA Science Inventory

    The objectives of the Household Hazardous Waste Characterization Study (the HHW Study) were to: 1) Quantity the annual household hazardous waste (HHW) tonnages disposed in Palm Beach County Florida’s (the County) residential solid waste (characterized in this study as municipal s...

  2. Alternative disposal options for transuranic waste

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Loomis, G.G.

    1994-12-31

    Three alternative concepts are proposed for the final disposal of stored and retrieved buried transuranic waste. These proposed options answer criticisms of the existing U.S. Department of Energy strategy of directly disposing of stored transuranic waste in deep, geological salt formations at the Waste Isolation Pilot Plant (WIPP) in Carlsbad, New Mexico. The first option involves enhanced stabilization of stored waste by thermal treatment followed by convoy transportation and internment in the existing WIPP facility. This concept could also be extended to retrieved buried waste with proper permitting. The second option involves in-state, in situ internment using an encapsulating lensmore » around the waste. This concept applies only to previously buried transuranic waste. The third option involves sending stored and retrieved waste to the Nevada Test Site and configuring the waste around a thermonuclear device from the U.S. or Russian arsenal in a specially designed underground chamber. The thermonuclear explosion would transmute plutonium and disassociate hazardous materials while entombing the waste in a national sacrifice area.« less

  3. SELENIUM TREATMENT/REMOVAL ALTERNATIVES DEMONSTRATION PROJECT - MINE WASTE TECHNOLOGY PROGRAM ACTIVITY III, PROJECT 20

    EPA Science Inventory

    This document is the final report for EPA's Mine WAste Technology Program (MWTP) Activity III, Project 20--Selenium Treatment/Removal Alternatives Demonstration project. Selenium contamination originates from many sources including mining operations, mineral processing, abandoned...

  4. Examples of Disposition Alternatives for WTP Solid Secondary Waste

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Seitz, R.

    The Hanford Waste Treatment and Immobilization Plant is planned to produce a variety of solid secondary wastes that will require disposal at the Integrated Disposal Facility on the Hanford Site. Solid secondary wastes include a variety of waste streams that are a result of waste treatment and processing activities.

  5. Landfill alternative offers powerful case.

    PubMed

    Baillie, Jonathan

    2011-04-01

    With many of Europe's landfill sites now close to capacity, and the EU Landfill Directive requiring that, by 2020, the amount of waste sent to landfill should be just 35% of the volume similarly disposed of in 1995, pressure is mounting to find environmentally acceptable waste disposal alternatives. At a recent IHEEM waste seminar, Gary Connelly, a technical consultant at environmental technology consultancy the Cameron Corporation, described a technology which he explained can effectively convert 85% of the European Waste Catalogue of materials into an inert residue, is "cleaner and cheaper" than incineration, and can generate both electricity an waste heat. As HEJ editor Jonathan Baillie reports, a key target market is healthcare facilities.

  6. Prompt gamma neutron activation analysis of toxic elements in radioactive waste packages.

    PubMed

    Ma, J-L; Carasco, C; Perot, B; Mauerhofer, E; Kettler, J; Havenith, A

    2012-07-01

    The French Alternative Energies and Atomic Energy Commission (CEA) and National Radioactive Waste Management Agency (ANDRA) are conducting an R&D program to improve the characterization of long-lived and medium activity (LL-MA) radioactive waste packages. In particular, the amount of toxic elements present in radioactive waste packages must be assessed before they can be accepted in repository facilities in order to avoid pollution of underground water reserves. To this aim, the Nuclear Measurement Laboratory of CEA-Cadarache has started to study the performances of Prompt Gamma Neutron Activation Analysis (PGNAA) for elements showing large capture cross sections such as mercury, cadmium, boron, and chromium. This paper reports a comparison between Monte Carlo calculations performed with the MCNPX computer code using the ENDF/B-VII.0 library and experimental gamma rays measured in the REGAIN PGNAA cell with small samples of nickel, lead, cadmium, arsenic, antimony, chromium, magnesium, zinc, boron, and lithium to verify the validity of a numerical model and gamma-ray production data. The measurement of a ∼20kg test sample of concrete containing toxic elements has also been performed, in collaboration with Forschungszentrum Jülich, to validate the model in view of future performance studies for dense and large LL-MA waste packages. Copyright © 2012 Elsevier Ltd. All rights reserved.

  7. CORRRECTIVE ACTION DECISION DOCUMENT FOR CORRECTIVE ACTION UNIT 427: AREA 3 SEPTIC WASTE SYSTEMS 2 AND 6, TONOPAH TEST RANGE, NEVADA, REVISION 0, JUNE 1998

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    ITLV.

    1998-06-01

    This Corrective Action Decision Document has been prepared for the Area 3 Septic Waste Systems 2 and 6 (Corrective Action Unit 427) in accordance with the Federal Facility Agreement and Consent Order of 1996 (FFACO, 1996). Corrective Action Unit 427 is located at the Tonopah Test Range, Nevada, and is comprised of the following Corrective Action Sites, each an individual septic waste system (DOE/NV, 1996a): Septic Waste System 2 is Corrective Action Site Number 03-05-002-SW02. Septic Waste System 6 is Corrective Action Site Number 03-05-002-SW06. The purpose of this Corrective Action Decision Document is to identify and provide a rationalemore » for the selection of a recommended corrective action alternative for each Corrective Action Site. The scope of this Correction Action Decision Document consists of the following tasks: Develop corrective action objectives. Identify corrective action alternative screening criteria. Develop corrective action alternatives. Perform detailed and comparative evaluations of the corrective action alternatives in relation to the corrective action objectives and screening criteria. Recommend and justify a preferred corrective action alternative for each CAS. From November 1997 through January 1998, a corrective action investigation was performed as set forth in the Corrective Action Investigation Plan for Corrective Action Unit No. 427: Area 3 Septic Waste System Numbers 2 and 6, Tonopah Test Range, Nevada (DOE/NV, 1997b). Details can be found in Appendix A of this document. The results indicated that contamination is present in some portions of the CAU and not in others as described in Table ES-1 and shown in Figure A.2-2 of Appendix A. Based on the potential exposure pathways, the following corrective action objectives have been identified for Corrective Action Unit 427: Prevent or mitigate human exposure to subsurface soils containing TPH at concentrations greater than 100 milligrams per kilogram (NAC, 1996b). Close Septic Tank 33-5 in accordance with Nevada Administrative Code 459 (NAC, 1996c). Prevent adverse impacts to groundwater quality. Based on the review of existing data, future land use, and current operations at the Tonopah Test Range, the following alternatives were developed for consideration at the Area 3 Septic Waste Systems 2 and 6: Alternative 1 - No Further Action Alternative 2 - Closure of Septic Tank 33-5 and Administrative Controls Alternative 3 - Closure of Septic Tank 33-5, Excavation, and Disposal The corrective action alternatives were evaluated based on four general corrective action standards and five remedy selection decision factors. Based on the results of this evaluation, the preferred alternative for Corrective Action Unit 427 is Alternative 2, Closure of Septic Tank 33-5 and Administrative Controls. The preferred corrective action alternative was evaluated on technical merit, focusing on performance, reliability, feasibility, and safety. The alternative was judged to meet all requirements for the technical components evaluated. The alternative meets all applicable state and federal regulations for closure of the site and will reduce potential future exposure pathways to the contaminated soils. During corrective action implementation, this alternative will present minimal potential threat to site workers who come in contact with the waste. However, procedures will be developed and implemented to ensure worker health and safety.« less

  8. High-level radioactive waste management alternatives

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    None

    1974-05-01

    A summary of a comprehensive overview study of potential alternatives for long-term management of high-level radioactive waste is presented. The concepts studied included disposal in geologic formations, disposal in seabeds, disposal in ice caps, disposal into space, and elimination by transmutation. (TFD)

  9. SOCIOECONOMIC ANALYSIS OF HAZARDOUS WASTE MANAGEMENT ALTERNATIVES: METHOLOLOGY AND DEMONSTRATION

    EPA Science Inventory

    A methodology for analyzing economic and social effects of alternatives in hazardous waste management is presented and demonstrated. The approach includes the use of environmental threat scenarios and evaluation of effects on and responses by parties-at-interest. The methodology ...

  10. Economic and employment potential in textile waste management of Faisalabad.

    PubMed

    Noman, Muhammad; Batool, Syeda Adila; Chaudhary, Muhammad Nawaz

    2013-05-01

    The aim of this study is to characterize the waste from the textile industry, to identify the sources and types of waste generation and to find out the economic and employment potential in this sector. Textile waste, its management, and the economic and employment potential in this sector are unrevealed facts in developing countries such as Pakistan. The textile industry is ranked first in export earning in Pakistan. Textile export of yarn and cloth from Faisalabad is US$3 billion per year. On average 161 325 people are employed in the textile sector in Faisalabad, of which 11 860 are involved in solid waste handling and management. The textile industries generate solid wastes such as fibre, metal, plastic and paper waste. A total of 794 209 kg day(-1) (289 886 285 kg year(-1)) solid waste is produced from this sector and purchased by cotton waste junkshop owners at US$125 027 day(-1) (US$45 634 855 year(-1)). Only pre-consumer textile waste is considered. Interestingly no waste is sent to landfill. The waste is first segregated into different categories/ types by hand and then weighed. Cotton waste is sold to brick kilns where it is used as an alternative fuel as it is cheaper than wood/coal. Iron scrap is sold in the junk market from where it is resold to recycling industries. Paper waste is recycled, minimizing the virgin material used for producing new paper products. Iron and plastic drums are returned to the chemical industries for refilling, thus decreasing the cost of dyes and decreasing the demand for new drums. Cutting rags are used for making different things such as ropes and underlay, it is also shredded and used as fillings for pillows and mattresses, thus improving waste management, reducing cost and minimizing the need for virgin material. As no system of quality control and no monitoring of subsequent products exist there is a need to carry out quality control and monitoring.

  11. Waste valorization by biotechnological conversion into added value products.

    PubMed

    Liguori, Rossana; Amore, Antonella; Faraco, Vincenza

    2013-07-01

    Fossil fuel reserves depletion, global warming, unrelenting population growth, and costly and problematic waste recycling call for renewable resources of energy and consumer products. As an alternative to the 100 % oil economy, production processes based on biomass can be developed. Huge amounts of lignocellulosic wastes are yearly produced all around the world. They include agricultural residues, food farming wastes, "green-grocer's wastes," tree pruning residues, and organic and paper fraction of urban solid wastes. The common ways currently adopted for disposal of these wastes present environmental and economic disadvantages. As an alternative, processes for adding value to wastes producing high added products should be developed, that is the upgrading concept: adding value to wastes by production of a product with desired reproducible properties, having economic and ecological advantages. A wide range of high added value products, such as enzymes, biofuels, organic acids, biopolymers, bioelectricity, and molecules for food and pharmaceutical industries, can be obtained by upgrading solid wastes. The most recent advancements of their production by biotechnological processes are overviewed in this manuscript.

  12. Argonne National Laboratory Expedited Site Characterization: First International Symposium on Integrated Technical Approaches to Site Characterization - Proceedings Volume

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    NONE

    1998-06-08

    Laboratory applications for the analysis of PCBS (polychlorinated biphenyls) in environmental matrices such as soil/sediment/sludge and oil/waste oil were evaluated for potential reduction in waste, source reduction, and alternative techniques for final determination. As a consequence, new procedures were studied for solvent substitution, miniaturization of extraction and cleanups, minimization of reagent consumption, reduction of cost per analysis, and reduction of time. These new procedures provide adequate data that meet all the performance requirements for the determination of PCBS. Use of the new procedures reduced costs for all sample preparation techniques. Time and cost were also reduced by combining the newmore » sample preparation procedures with the power of fast gas chromatography. Separation of Aroclor 1254 was achieved in less than 6 min by using DB-1 and SPB-608 columns. With the greatly shortened run times, reproducibility can be tested quickly and consequently with low cost. With performance-based methodology, the applications presented here can be applied now, without waiting for regulatory approval.« less

  13. Evaluation of healthcare waste treatment/disposal alternatives by using multi-criteria decision-making techniques.

    PubMed

    Özkan, Aysun

    2013-02-01

    Healthcare waste should be managed carefully because of infected, pathological, etc. content especially in developing countries. Applied management systems must be the most appropriate solution from a technical, environmental, economic and social point of view. The main objective of this study was to analyse the current status of healthcare waste management in Turkey, and to investigate the most appropriate treatment/disposal option by using different decision-making techniques. For this purpose, five different healthcare waste treatment/disposal alternatives including incineration, microwaving, on-site sterilization, off-site sterilization and landfill were evaluated according to two multi-criteria decision-making techniques: analytic network process (ANP) and ELECTRE. In this context, benefits, costs and risks for the alternatives were taken into consideration. Furthermore, the prioritization and ranking of the alternatives were determined and compared for both methods. According to the comparisons, the off-site sterilization technique was found to be the most appropriate solution in both cases.

  14. Low-Activity Radioactive Wastes

    EPA Pesticide Factsheets

    In 2003 EPA published an Advance Notice of Proposed Rulemaking (ANPR) to collect public comment on alternatives for disposal of waste containing low concentrations of radioactive material ('low-activity' waste).

  15. Waste management in the Irkutsk region, Siberia, Russia: An environmental assessment of alternative development scenarios.

    PubMed

    Starostina, Vlada; Damgaard, Anders; Eriksen, Marie K; Christensen, Thomas H

    2018-04-01

    The current waste management system, handling around 500,000 t of household, commercial, and institutional waste annually in the Irkutsk region, Siberia, is based on landfilling in an old landfill with no controls of leachate and gas. Life-cycle assessment modelling of the current system shows that it is a major load on the environment, while the simulation of seven alternative systems results in large savings in many impact categories. With respect to climate change, it is estimated that a saving of about 1200 kg CO 2 equivalents is possible per year, per inhabitant, which is a significant reduction in greenhouse gas emissions. The best alternatives involve efficient energy recovery from waste and recycling by source separation for commercial and institutional waste, the major waste type in the Irkutsk region. Recycling of household waste seems less attractive, and it is therefore recommended only to consider this option after experience has been gained with the commercial and institutional waste. Sensitivity analysis shows that recovery of energy - in particular electricity, heat, and steam - from waste is crucial to the environmental performance of the waste management system. This relates to the efficiencies of energy recovery as well as what the recovered energy substitutes, that is, the 'dirtier' the off-set energy, the higher the environmental savings for the waste management system. Since recovered energy may be utilised by only a few energy grids or industrial users, it is recommended to perform additional local assessments of the integration of the waste energy into existing systems and facilities.

  16. Alternative Processes for Water Reclamation and Solid Waste Processing in a Physical/chemical Bioregenerative Life Support System

    NASA Technical Reports Server (NTRS)

    Rogers, Tom D.

    1990-01-01

    Viewgraphs on alternative processes for water reclamation and solid waste processing in a physical/chemical-bioregenerative life support system are presented. The main objective is to focus attention on emerging influences of secondary factors (i.e., waste composition, type and level of chemical contaminants, and effects of microorganisms, primarily bacteria) and to constructively address these issues by discussing approaches which attack them in a direct manner.

  17. Draft Site Treatment Plan (DSTP), Volumes I and II

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    D`Amelio, J.

    1994-08-30

    Site Treatment Plans (STP) are required for facilities at which the DOE generates or stores mixed waste. This Draft Site Treatment Plan (DSTP) the second step in a three-phase process, identifies the currently preferred options for treating mixed waste at the Savannah River Site (SRS) or for developing treatment technologies where technologies do not exist or need modification. The DSTP reflects site-specific preferred options, developed with the state`s input and based on existing available information. To the extent possible, the DSTP identifies specific treatment facilities for treating the mixed waste and proposes schedules. Where the selection of specific treatment facilitiesmore » is not possible, schedules for alternative activities such as waste characterization and technology assessment are provided. All schedule and cost information presented is preliminary and is subject to change. The DSTP is comprised of two volumes: this Compliance Plan Volume and the Background Volume. This Compliance Plan Volume proposes overall schedules with target dates for achieving compliance with the land disposal restrictions (LDR) of RCRA and procedures for converting the target dates into milestones to be enforced under the Order. The more detailed discussion of the options contained in the Background Volume is provided for informational purposes only.« less

  18. Physical, Hydraulic, and Transport Properties of Sediments and Engineered Materials Associated with Hanford Immobilized Low-Activity Waste

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Rockhold, Mark L.; Zhang, Z. F.; Meyer, Philip D.

    2015-02-28

    Current plans for treatment and disposal of immobilized low-activity waste (ILAW) from Hanford’s underground waste storage tanks include vitrification and storage of the glass waste form in a nearsurface disposal facility. This Integrated Disposal Facility (IDF) is located in the 200 East Area of the Hanford Central Plateau. Performance assessment (PA) of the IDF requires numerical modeling of subsurface flow and reactive transport processes over very long periods (thousands of years). The models used to predict facility performance require parameters describing various physical, hydraulic, and transport properties. This report provides updated estimates of physical, hydraulic, and transport properties and parametersmore » for both near- and far-field materials, intended for use in future IDF PA modeling efforts. Previous work on physical and hydraulic property characterization for earlier IDF PA analyses is reviewed and summarized. For near-field materials, portions of this document and parameter estimates are taken from an earlier data package. For far-field materials, a critical review is provided of methodologies used in previous data packages. Alternative methods are described and associated parameters are provided.« less

  19. 40 CFR 194.24 - Waste characterization.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... system. (e) Waste may be emplaced in the disposal system only if the emplaced components of such waste... 40 Protection of Environment 26 2012-07-01 2011-07-01 true Waste characterization. 194.24 Section... PROGRAMS CRITERIA FOR THE CERTIFICATION AND RE-CERTIFICATION OF THE WASTE ISOLATION PILOT PLANT'S...

  20. 40 CFR 194.24 - Waste characterization.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... system. (e) Waste may be emplaced in the disposal system only if the emplaced components of such waste... 40 Protection of Environment 26 2013-07-01 2013-07-01 false Waste characterization. 194.24 Section... PROGRAMS CRITERIA FOR THE CERTIFICATION AND RE-CERTIFICATION OF THE WASTE ISOLATION PILOT PLANT'S...

  1. 40 CFR 194.24 - Waste characterization.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... system. (e) Waste may be emplaced in the disposal system only if the emplaced components of such waste... 40 Protection of Environment 25 2011-07-01 2011-07-01 false Waste characterization. 194.24 Section... PROGRAMS CRITERIA FOR THE CERTIFICATION AND RE-CERTIFICATION OF THE WASTE ISOLATION PILOT PLANT'S...

  2. 40 CFR 194.24 - Waste characterization.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... system. (e) Waste may be emplaced in the disposal system only if the emplaced components of such waste... 40 Protection of Environment 25 2014-07-01 2014-07-01 false Waste characterization. 194.24 Section... PROGRAMS CRITERIA FOR THE CERTIFICATION AND RE-CERTIFICATION OF THE WASTE ISOLATION PILOT PLANT'S...

  3. Multi-level multi-criteria analysis of alternative fuels for waste collection vehicles in the United States.

    PubMed

    Maimoun, Mousa; Madani, Kaveh; Reinhart, Debra

    2016-04-15

    Historically, the U.S. waste collection fleet was dominated by diesel-fueled waste collection vehicles (WCVs); the growing need for sustainable waste collection has urged decision makers to incorporate economically efficient alternative fuels, while mitigating environmental impacts. The pros and cons of alternative fuels complicate the decisions making process, calling for a comprehensive study that assesses the multiple factors involved. Multi-criteria decision analysis (MCDA) methods allow decision makers to select the best alternatives with respect to selection criteria. In this study, two MCDA methods, Technique for Order Preference by Similarity to Ideal Solution (TOPSIS) and Simple Additive Weighting (SAW), were used to rank fuel alternatives for the U.S. waste collection industry with respect to a multi-level environmental and financial decision matrix. The environmental criteria consisted of life-cycle emissions, tail-pipe emissions, water footprint (WFP), and power density, while the financial criteria comprised of vehicle cost, fuel price, fuel price stability, and fueling station availability. The overall analysis showed that conventional diesel is still the best option, followed by hydraulic-hybrid WCVs, landfill gas (LFG) sourced natural gas, fossil natural gas, and biodiesel. The elimination of the WFP and power density criteria from the environmental criteria ranked biodiesel 100 (BD100) as an environmentally better alternative compared to other fossil fuels (diesel and natural gas). This result showed that considering the WFP and power density as environmental criteria can make a difference in the decision process. The elimination of the fueling station and fuel price stability criteria from the decision matrix ranked fossil natural gas second after LFG-sourced natural gas. This scenario was found to represent the status quo of the waste collection industry. A sensitivity analysis for the status quo scenario showed the overall ranking of diesel and fossil natural gas to be more sensitive to changing fuel prices as compared to other alternatives. Copyright © 2016 Elsevier B.V. All rights reserved.

  4. Defining alternative rules in water and sanitation.

    PubMed

    Robert, J

    1995-11-01

    While the conventional water and sanitation package remains most prominent, alternatives exist to conventional waterworks and sanitation practices. Some alternate courses of action are considered. Promising an unprecedented availability of piped water, water development projects foster a pump-and-dump mentality even before they are completed. Often simply announcing the impending implementation of such projects encourages the intention among future beneficiaries to waste water resources. Alternatives to the domestic waste of water must be sought and implemented. Disestablishing water development, styles of alternative water technologies, decision-making and decision-makers, water policy scale, regenerating community access to sources, and water pricing are discussed.

  5. Dose potential of sludge contaminated and/or TRU contaminated waste in B-25s for tornado and straight wind events

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Aponte, C.I.

    F and H Tank Farms generate supernate and sludge contaminated Low-Level Waste. The waste is collected, characterized, and packaged for disposal. Before the waste can be disposed of, however, it must be properly characterized. Since the radionuclide distribution in typical supernate is well known, its characterization is relatively straight forward and requires minimal effort. Non-routine waste, including potentially sludge contaminated, requires much more effort to effectively characterize. The radionuclide distribution must be determined. In some cases the waste can be contaminated by various sludge transfers with unique radionuclide distributions. In these cases, the characterization can require an extensive effort. Evenmore » after an extensive characterization effort, the container must still be prepared for shipping. Therefore a significant amount of time may elapse from the time the waste is generated until the time of disposal. During the time it is possible for a tornado or high wind scenario to occur. The purpose of this report is to determine the effect of a tornado on potential sludge contaminated waste, or Transuranic (TRU) waste in B-25s [large storage containers], to evaluate the potential impact on F and H Tank Farms, and to help establish a B-25 control program for tornado events.« less

  6. Low-level radioactive waste disposal. Study of a conceptual nuclear energy center at Green River, Utah

    NASA Astrophysics Data System (ADS)

    Card, D. H.; Hunter, P. H.; Barg, D.; Desouza, F.; Felthauser, K.; Winkler, V.; White, R.

    1982-02-01

    The ramifications of constructing a nuclear energy center in an arid western region were studied. The alternatives for disposing of the low level waste on the site are compared with the alternative of transporting the waste to the nearest commercial waste disposal site for permanent disposal. Both radiological and nonradiological impacts on the local socioeconomic infrastructure and the environment are considered. Disposal on the site was found to cost considerably less than off site disposal with only negligible impacts associated with the disposal option on either mankind or the environment.

  7. Waste Treatment And Immobilization Plant U. S. Department Of Energy Office Of River Protection Submerged Bed Scrubber Condensate Disposition Project - Abstract # 13460

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Yanochko, Ronald M; Corcoran, Connie

    The Hanford Waste Treatment and Immobilization Plant (WTP) will generate an off-gas treatment system secondary liquid waste stream [submerged bed scrubber (SBS) condensate], which is currently planned for recycle back to the WTP Low Activity Waste (LAW) melter. This SBS condensate waste stream is high in Tc-99, which is not efficiently captured in the vitrified glass matrix. A pre-conceptual engineering study was prepared in fiscal year 2012 to evaluate alternate flow paths for melter off-gas secondary liquid waste generated by the WTP LAW facility. This study evaluated alternatives for direct off-site disposal of this SBS without pre-treatment, which mitigates potentialmore » issues associated with recycling.« less

  8. Treatment of clinical solid waste using a steam autoclave as a possible alternative technology to incineration.

    PubMed

    Hossain, Md Sohrab; Balakrishnan, Venugopal; Rahman, Nik Norulaini Nik Ab; Sarker, Md Zaidul Islam; Kadir, Mohd Omar Ab

    2012-03-01

    A steam autoclave was used to sterilize bacteria in clinical solid waste in order to determine an alternative to incineration technology in clinical solid waste management. The influence of contact time (0, 5, 15, 30 and 60 min) and temperature (111 °C, 121 °C and 131 °C) at automated saturated steam pressure was investigated. Results showed that with increasing contact time and temperature, the number of surviving bacteria decreased. The optimum experimental conditions as measured by degree of inactivation of bacteria were 121 °C for 15 minutes (min) for Gram negative bacteria, 121 °C and 131 °C for 60 and 30 min for Gram positive bacteria, respectively. The re-growth of bacteria in sterilized waste was also evaluated in the present study. It was found that bacterial re-growth started two days after the inactivation. The present study recommends that the steam autoclave cannot be considered as an alternative technology to incineration in clinical solid waste management.

  9. Treatment of Clinical Solid Waste Using a Steam Autoclave as a Possible Alternative Technology to Incineration

    PubMed Central

    Hossain, Md. Sohrab; Balakrishnan, Venugopal; Rahman, Nik Norulaini Nik Ab; Sarker, Md. Zaidul Islam; Kadir, Mohd Omar Ab

    2012-01-01

    A steam autoclave was used to sterilize bacteria in clinical solid waste in order to determine an alternative to incineration technology in clinical solid waste management. The influence of contact time (0, 5, 15, 30 and 60 min) and temperature (111 °C, 121 °C and 131 °C) at automated saturated steam pressure was investigated. Results showed that with increasing contact time and temperature, the number of surviving bacteria decreased. The optimum experimental conditions as measured by degree of inactivation of bacteria were 121 °C for 15 minutes (min) for Gram negative bacteria, 121 °C and 131 °C for 60 and 30 min for Gram positive bacteria, respectively. The re-growth of bacteria in sterilized waste was also evaluated in the present study. It was found that bacterial re-growth started two days after the inactivation. The present study recommends that the steam autoclave cannot be considered as an alternative technology to incineration in clinical solid waste management. PMID:22690168

  10. Assessing the environmental burdens of anaerobic digestion in comparison to alternative options for managing the biodegradable fraction of municipal solid wastes.

    PubMed

    Haight, M

    2005-01-01

    Biological treatment processes including anaerobic digestion (biogasification) and composting are increasingly being considered by waste management officials and planners as alternatives for managing the mainly organic residues of municipal solid wastes (MSW). The integrated waste management model which is based upon the application of life-cycle analysis was employed to compare the environmental burdens of landfilling, composting and anaerobic digestion of MSW at a mid-sized Canadian community. Energy consumption (or recovery), residue recoveries and emissions to air and water were quantified. Scenario comparisons were analyzed to demonstrate that the environmental burdens associated with anaerobic digestion are reduced in comparison with the alternative options. The major benefit occurs as a result of the electricity produced from burning the biogas and then supplying the 'green power' to the local electrical grid.

  11. Material and energy recovery in integrated waste management systems: a life-cycle costing approach.

    PubMed

    Massarutto, Antonio; de Carli, Alessandro; Graffi, Matteo

    2011-01-01

    A critical assumption of studies assessing comparatively waste management options concerns the constant average cost for selective collection regardless the source separation level (SSL) reached, and the neglect of the mass constraint. The present study compares alternative waste management scenarios through the development of a desktop model that tries to remove the above assumption. Several alternative scenarios based on different combinations of energy and materials recovery are applied to two imaginary areas modelled in order to represent a typical Northern Italian setting. External costs and benefits implied by scenarios are also considered. Scenarios are compared on the base of the full cost for treating the total waste generated in the area. The model investigates the factors that influence the relative convenience of alternative scenarios. Copyright © 2011 Elsevier Ltd. All rights reserved.

  12. Site characterization design and techniques used at the Southern Shipbuilding Corporation site

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Mueller, J.P.; Geraghty, C.A.; Moore, G.W.

    1995-12-31

    The Southern Shipbuilding Corporation (SSC) site is an inactive barge/ship manufacturing and repair facility situated on approximately 54 acres in Slidell, St. Tammany Parish, Louisiana. Two unlined surface impoundments (North and South impoundments) are situated on the northwest portion of the site and are surrounded on three sides by Bayou Bonfouca. These impoundments are the sources of carcinogenic polynuclear aromatic hydrocarbon (CPAH) contamination at the site. Inadequate containment has resulted in the release of impoundment wastes into the bayou. To evaluate potential response alternatives for the site, an Engineering Evaluation/Cost Analysis (EE/CA) field investigation was conducted from July through Octobermore » 1994. A two phase sampling approach was used in combination with innovative and traditional sampling techniques, field screening technologies, and exploitation of the visual characteristics of the waste to determine the extent of waste migration with limited off-site laboratory confirmation. A skid-mounted mobile drilling unit, secured to a specialized sampling platform designed for multiple applications, was used for collection of sediment cores from the bayou as well as tarry sludge cores from the impoundments. Field screening of core samples was accomplished on site using an organic vapor analyzer and a total petroleum hydrocarbon (TPH) field analyzer. Pollutants of concern include metals, cyanide, dioxin, and organic compounds. This paper presents details on the sampling design and characterization techniques used to accomplish the EE/CA field investigation.« less

  13. Increased productivity through waste reduction effort in oil and gas company

    NASA Astrophysics Data System (ADS)

    Hidayati, J.; Silviana, NA; Matondang, RA

    2018-02-01

    National companies engaged in oil and gas activities in the upstream sector. In general, the on going operations include drilling, exploration, and production activities with the result being crude oil channelled for shipment. Production activities produce waste gas (flare) of 0.58 MMSCFD derived from 17.05% of natural gas produced. Gas flares are residual gases that have been burning through flare stacks to avoid toxic gases such as H2S and CO that are harmful to human health and the environment. Therefore, appropriate environmental management is needed; one of them is by doing waste reduction business. Through this approach, it is expected that waste reduction efforts can affect the improvement of environmental conditions while increasing the productivity of the company. In this research begins by identifying the existence of problems on the company related to the amount of waste that is excessive and potentially to be reduced. Alternative improvements are then formulated and selected by their feasibility to be implemented through financial analysis, and the estimation of alternative contributions to the level of productivity. The result of this research is an alternative solution to solve the problem of the company by doing technological based engineering by reusing gas flare into fuel for incinerator machine. This alternative contributes to the increased productivity of material use by 23.32%, humans 83.8%, capital 10.13 %, and waste decreased by 0.11%.

  14. Cost/Benefits of Solid Waste Reuse

    ERIC Educational Resources Information Center

    Schulz, Helmut W.

    1975-01-01

    Municipalities and industry are being forced to seek alternatives to sanitary landfills and incineration as means of eliminating solid wastes. Based on the Columbia study, the two most cost-effective, environmentally acceptable alternatives are the high temperature, oxygen-fed pyrolysis process and the co-combustion of refuse-derived fuel in…

  15. Managing previously disposed waste to today's standards

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Not Available

    1990-01-01

    A Radioactive Waste Management Complex (RWMC) was established at the Idaho National Engineering Laboratory (INEL) in 1952 for controlled disposal of radioactive waste generated at the INEL. Between 1954 and 1970 waste characterized by long lived, alpha emitting radionuclides from the Rocky Flats Plant was also buried at this site. Migration of radionuclides and other hazardous substances from the buried Migration of radionuclides and other hazardous substances from the buried waste has recently been detected. A Buried Waste Program (BWP) was established to manage cleanup of the buried waste. This program has four objectives: (1) determine contaminant sources, (2) determinemore » extent of contamination, (3) mitigate migration, and (4) recommend an alternative for long term management of the waste. Activities designed to meet these objectives have been under way since the inception of the program. The regulatory environment governing these activities is evolving. Pursuant to permitting activities under the Resource Conservation and Recovery Act (RCRA), the Department of Energy (DOE) and the Environmental Protection Agency (EPA) entered into a Consent Order Compliance Agreement (COCA) for cleanup of past practice disposal units at the INEL. Subsequent to identification of the RWMC as a release site, cleanup activities proceeded under dual regulatory coverage of RCRA and the Atomic Energy Act. DOE, EPA, and the State of Idaho are negotiating a RCRA/Comprehensive Environmental Response, Compensation, and Liability Act (CERCLA) Interagency Agreement (IAG) for management of waste disposal sites at the INEL as a result of the November 1989 listing of the INEL on the National Priority List (NPL). Decision making for selection of cleanup technology will be conducted under the CERCLA process supplemented as required to meet the requirements of the National Environmental Policy Act (NEPA). 7 figs.« less

  16. Investigating the Partitioning of Inorganic Elements Consumed by Humans between the Various Fractions of Human Wastes: An Alternative Approach

    NASA Technical Reports Server (NTRS)

    Wignarajah, Kanapathipillai; Pisharody, Suresh; Fisher, John W.

    2003-01-01

    The elemental composition of food consumed by astronauts is well defined. The major elements carbon, hydrogen, oxygen, nitrogen and sulfur are taken up in large amounts and these are often associated with the organic fraction (carbohydrates, proteins, fats etc) of human tissue. On the other hand, a number of the elements are located in the extracellular fluids and can be accounted for in the liquid and solid waste fraction of humans. These elements fall into three major categories - cationic macroelements (e.g. Ca, K, Na, Mg and Si), anionic macroelements (e.g. P, S and Cl and 17 essential microelements, (e.g. Fe, Mn, Cr, Co, Cu, Zn, Se and Sr). When provided in the recommended concentrations to an adult healthy human, these elements should not normally accumulate in humans and will eventually be excreted in the different human wastes. Knowledge of the partitioning of these elements between the different human waste fractions is important in understanding (a) developing waste separation technologies, (b) decision-making on how these elements can be recovered for reuse in space habitats, and (c) to developing the processors for waste management. Though considerable literature exists on these elements, there is a lack of understanding and often conflicting data. Two major reasons for these problems include the lack of controlled experimental protocols and the inherently large variations between human subjects (Parker and Gallagher, 1988). We have used the existing knowledge of human nutrition and waste from the available literature and NASA documentation to build towards a consensus to typify and chemically characterize the various human wastes. It is our belief, that this could be a building block towards integrating a human life support and waste processing in a closed system.

  17. Quantitative study of controlled substance bedside wasting, disposal and evaluation of potential ecologic effects.

    PubMed

    Mankes, Russell F; Silver, Charles D

    2013-02-01

    Drugs in wastewater arise from many sources. For health care, these include excretion and direct disposal (bedside wasting). The present study reports on the dispensing and wasting of 15 controlled substances (CS) at two health care facilities in Albany, NY over a nearly two year period. The study considered measures of ecotoxicity, drug metabolism, excretion and disposal of these CS. Potential alternatives to flushing of CS into wastewaters from healthcare facilities are discussed. Drug medication and waste collection records (12,345) included: numbers of drugs dispensed, returned and wasted. Overall, 8528 g of 15 CS were wasted. Three (midazolam, acetaminophen-codeine and fentanyl) accounted for 87.5% of the total wasted. Wasting varied by hospital, 14 CS at the academic medical center hospital and 8 at the surgical care center were wasted. Liquids were more frequently wasted than tablets or pills. Some combination drugs (acetaminophen (APAP)-codeine) were frequently (50% of drug dispensed) wasted while others were less wasted (APAP-hydrocodone-6.3%; APAP-oxycodone-1.3%). The 8 CS judged more hazardous to aquatic life were: APAP-codeine, APAP-hydrocodone, APAP-oxycodone, alprazolam, diazepam, fentanyl, midazolam, and testosterone. Ketamine, morphine, oxycodone and zolpidem were of lesser acute toxicity based on available LC50 values. These CS might provide a therapeutically equivalent alternative to the more environmentally harmful drugs. In health care facilities, professionals dispose of CS by bedside wasting into water or other receptacles. This can be avoided by returning CS to the hospital's pharmacy department, thence to a licensed distributor. Study of this process of drug wasting can identify opportunities for process improvements. We found 3 CS (APAP-codeine, midazolam and testosterone) where ½ to 1/3 of the drug was wasted and 5 others with 30 to 13% wasted. Knowledge of the adverse impacts from the release of highly toxic drugs into the environment might influence CS selection and disposal alternatives. Copyright © 2012 Elsevier B.V. All rights reserved.

  18. Uncertainty quantification applied to the radiological characterization of radioactive waste.

    PubMed

    Zaffora, B; Magistris, M; Saporta, G; Chevalier, J-P

    2017-09-01

    This paper describes the process adopted at the European Organization for Nuclear Research (CERN) to quantify uncertainties affecting the characterization of very-low-level radioactive waste. Radioactive waste is a by-product of the operation of high-energy particle accelerators. Radioactive waste must be characterized to ensure its safe disposal in final repositories. Characterizing radioactive waste means establishing the list of radionuclides together with their activities. The estimated activity levels are compared to the limits given by the national authority of the waste disposal. The quantification of the uncertainty affecting the concentration of the radionuclides is therefore essential to estimate the acceptability of the waste in the final repository but also to control the sorting, volume reduction and packaging phases of the characterization process. The characterization method consists of estimating the activity of produced radionuclides either by experimental methods or statistical approaches. The uncertainties are estimated using classical statistical methods and uncertainty propagation. A mixed multivariate random vector is built to generate random input parameters for the activity calculations. The random vector is a robust tool to account for the unknown radiological history of legacy waste. This analytical technique is also particularly useful to generate random chemical compositions of materials when the trace element concentrations are not available or cannot be measured. The methodology was validated using a waste population of legacy copper activated at CERN. The methodology introduced here represents a first approach for the uncertainty quantification (UQ) of the characterization process of waste produced at particle accelerators. Copyright © 2017 Elsevier Ltd. All rights reserved.

  19. Activated carbons from waste of oil-palm kernel shells, sawdust and tannery leather scraps and application to chromium(VI), phenol, and methylene blue dye adsorption.

    PubMed

    Montoya-Suarez, Sergio; Colpas-Castillo, Fredy; Meza-Fuentes, Edgardo; Rodríguez-Ruiz, Johana; Fernandez-Maestre, Roberto

    2016-01-01

    Phenol, chromium, and dyes are continuously dumped into water bodies; the adsorption of these contaminants on activated carbon is a low-cost alternative for water remediation. We synthesized activated carbons from industrial waste of palm oil seed husks (kernel shells), sawdust, and tannery leather scraps. These materials were heated for 24 h at 600, 700 or 800°C, activated at 900°C with CO2 and characterized by proximate analysis and measurement of specific surface area (Brunauer-Emmett-Teller (BET) and Langmuir), and microporosity (t-plot). Isotherms showed micropores and mesopores in activated carbons. Palm seed activated carbon showed the highest fixed carbon content (96%), and Langmuir specific surface areas up to 1,268 m2/g, higher than those from sawdust (581 m2/g) and leather scraps (400 m2/g). The carbons were applied to adsorption of Cr(VI), phenol, and methylene blue dye from aqueous solutions. Phenol adsorption on activated carbons was 78-82 mg/g; on palm seed activated carbons, Cr(VI) adsorption at pH 7 was 0.35-0.37 mg/g, and methylene blue adsorption was 40-110 mg/g, higher than those from sawdust and leather scraps. Activated carbons from palm seed are promising materials to remove contaminants from the environment and represent an alternative application for vegetal wastes instead of dumping into landfills.

  20. Alternative Fuels Data Center: Seattle's Waste Haulers are Going Green

    Science.gov Websites

    -hauling companies in the Puget Sound region, Waste Management and CleanScapes, were the first two private revolution in Washington's waste-hauling industry. Eager to win the Seattle contract, both Waste Management per year of greenhouse gas emissions reductions. Waste Management continues to rise to the challenge

  1. Successful approaches to recycling urban wood waste

    Treesearch

    Solid Waste Association of North America

    2002-01-01

    This report presents eight case studies of successful urban wood waste recycling projects and businesses. These studies document the success of recovered products such as lumber and lumber products, mulch, boiler fuel, and alternative cover for landfills. Overall, wood waste accounts for about 17% of the total waste received at municipal solid waste landfills in the...

  2. Bioremediation and degradation of CCA-treated wood waste.

    Treesearch

    Barbara L Illman; Vina W. Yang

    2004-01-01

    Bioprocessing CCA wood waste is an efficient and economical alternative to depositing the waste in landfills, especially if landfill restrictions on CCA waste are imposed nation wide. We have developed bioremediation and degradation technologies for microbial processing of CCA waste. The technologies are based on specially formulated inoculum of wood decay fungi,...

  3. Solid waste generation and characterization in the University of Lagos for a sustainable waste management.

    PubMed

    Adeniran, A E; Nubi, A T; Adelopo, A O

    2017-09-01

    Waste characterization is the first step to any successful waste management policy. In this paper, the characterization and the trend of solid waste generated in University of Lagos, Nigeria was carried out using ASTM D5231-92 and Resource Conservation Reservation Authority RCRA Waste Sampling Draft Technical Guidance methods. The recyclable potential of the waste is very high constituting about 75% of the total waste generated. The estimated average daily solid waste generation in Unilag Akoka campus was estimated to be 32.2tons. The solid waste characterization was found to be: polythene bags 24% (7.73tons/day), paper 15% (4.83tons/day), organic matters 15%, (4.83tons/day), plastic 9% (2.90tons/day), inert materials 8% (2.58tons/day), sanitary 7% (2.25tons/day), textile 7% (2.25tons/day), others 6% (1.93tons/day), leather 4% (1.29tons/day) metals 3% (0.97tons/day), glass 2% (0.64tons/day) and e-waste 0% (0.0tons/day). The volume and distribution of polythene bags generated on campus had a positive significant statistical correlation with the distribution of commercial and academic structures on campus. Waste management options to optimize reuse, recycling and reduce waste generation were discussed. Copyright © 2017 Elsevier Ltd. All rights reserved.

  4. I-NERI-2007-004-K, DEVELOPMENT AND CHARACTERIZATION OF NEW HIGH-LEVEL WASTE FORMS FOR ACHIEVING WASTE MINIMIZATION FROM PYROPROCESSING

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    S.M. Frank

    Work describe in this report represents the final year activities for the 3-year International Nuclear Energy Research Initiative (I-NERI) project: Development and Characterization of New High-Level Waste Forms for Achieving Waste Minimization from Pyroprocessing. Used electrorefiner salt that contained actinide chlorides and was highly loaded with surrogate fission products was processed into three candidate waste forms. The first waste form, a high-loaded ceramic waste form is a variant to the CWF produced during the treatment of Experimental Breeder Reactor-II used fuel at the Idaho National Laboratory (INL). The two other waste forms were developed by researchers at the Korean Atomicmore » Energy Research Institute (KAERI). These materials are based on a silica-alumina-phosphate matrix and a zinc/titanium oxide matrix. The proposed waste forms, and the processes to fabricate them, were designed to immobilize spent electrorefiner chloride salts containing alkali, alkaline earth, lanthanide, and halide fission products that accumulate in the salt during the processing of used nuclear fuel. This aspect of the I-NERI project was to demonstrate 'hot cell' fabrication and characterization of the proposed waste forms. The outline of the report includes the processing of the spent electrorefiner salt and the fabrication of each of the three waste forms. Also described is the characterization of the waste forms, and chemical durability testing of the material. While waste form fabrication and sample preparation for characterization must be accomplished in a radiological hot cell facility due to hazardous radioactivity levels, smaller quantities of each waste form were removed from the hot cell to perform various analyses. Characterization included density measurement, elemental analysis, x-ray diffraction, scanning electron microscopy and the Product Consistency Test, which is a leaching method to measure chemical durability. Favorable results from this demonstration project will provide additional options for fission product immobilization and waste management associated the electrochemical/pyrometallurgical processing of used nuclear fuel.« less

  5. Evaluation of two different alternatives of energy recovery from municipal solid waste in Brazil.

    PubMed

    Medina Jimenez, Ana Carolina; Nordi, Guilherme Henrique; Palacios Bereche, Milagros Cecilia; Bereche, Reynaldo Palacios; Gallego, Antonio Garrido; Nebra, Silvia Azucena

    2017-11-01

    Brazil has a large population with a high waste generation. The municipal solid waste (MSW) generated is deposited mainly in landfills. However, a considerable fraction of the waste is still improperly disposed of in dumpsters. In order to overcome this inadequate deposition, it is necessary to seek alternative routes. Between these alternatives, it is possible to quote gasification and incineration. The objective of this study is to compare, from an energetic and economic point of view, these technologies, aiming at their possible implementation in Brazilian cities. A total of two configurations were evaluated: (i) waste incineration with energy recovery and electricity production in a steam cycle; and (ii) waste gasification, where the syngas produced is used as fuel in a boiler of a steam cycle for electricity production. Simulations were performed assuming the same amount of available waste for both configurations, with a composition corresponding to the MSW from Santo André, Brazil. The thermal efficiencies of the gasification and incineration configurations were 19.3% and 25.1%, respectively. The difference in the efficiencies was caused by the irreversibilities associated with the gasification process, and the additional electricity consumption in the waste treatment step. The economic analysis presented a cost of electrical energy produced of 0.113 (US$ kWh -1 ) and 0.139 (US$ kWh -1 ) for the incineration and gasification plants respectively.

  6. Department of Energy Technology Readiness Assessments - Process Guide and Training Plan

    DTIC Science & Technology

    2008-09-12

    Hanford Waste Treatment and Immobilization Plant ( WTP ) Analytical Laboratory, Low Activity Waste (LAW) Facility and Balance of Facilities (3 TRAs... WTP High-Level Waste (HLW) Facility – WTP Pre-Treatment (PT) Facility – Hanford River Protection Project Low Activity Waste Treatment Alternatives

  7. Minimally processed beetroot waste as an alternative source to obtain functional ingredients.

    PubMed

    Costa, Anne Porto Dalla; Hermes, Vanessa Stahl; Rios, Alessandro de Oliveira; Flôres, Simone Hickmann

    2017-06-01

    Large amounts of waste are generated by the minimally processed vegetables industry, such as those from beetroot processing. The aim of this study was to determine the best method to obtain flour from minimally processed beetroot waste dried at different temperatures, besides producing a colorant from such waste and assessing its stability along 45 days. Beetroot waste dried at 70 °C originates flour with significant antioxidant activity and higher betalain content than flour produced from waste dried at 60 and 80 °C, while chlorination had no impact on the process since microbiological results were consistent for its application. The colorant obtained from beetroot waste showed color stability for 20 days and potential antioxidant activity over the analysis period, thus it can be used as a functional additive to improve nutritional characteristics and appearance of food products. These results are promising since minimally processed beetroot waste can be used as an alternative source of natural and functional ingredients with high antioxidant activity and betalain content.

  8. The flow of E-waste material in the Asian region and a reconsideration of international trade policies on E-waste

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Shinkuma, Takayoshi; Nguyen Thi Minh Huong

    End-of-life home appliances discarded in Japan are reused in Southeast Asia; end-of-life computers are reused in China. E-waste scrap generated in Asia is recycled in China, especially in Guangdong Province. The informal sector in that province has been recycling E-waste scrap and its improper recycling methods have caused serious pollution. In response to this problem, there is wide support for a total ban on E-waste trade, including secondhand items and E-waste scrap. Alternatively, we recommend the establishment of an alternative proper recycling system in Asia that needs cooperation among all Asian countries. First, China is urged to promote proper domesticmore » recycling activities by providing a subsidy for proper recycling. Second, Japan, as a main exporter of E-waste, should establish a traceability system that ensures E-waste scrap exported from Japan will be recycled at proper recycling facilities in China.« less

  9. Assessment of plastic waste generation and its potential recycling of household solid waste in Can Tho City, Vietnam.

    PubMed

    Thanh, Nguyen Phuc; Matsui, Yasuhiro; Fujiwara, Takeshi

    2011-04-01

    Plastic solid waste has become a serious problem when considering the disposal alternatives following the sequential hierarchy of sound solid waste management. This study was undertaken to assess the quantity and composition of household solid waste, especially plastic waste to identify opportunities for waste recycling. A 1-month survey of 130 households was carried out in Can Tho City, the capital city of the Mekong Delta region in southern Vietnam. Household solid waste was collected from each household and classified into ten physical categories; especially plastic waste was sorted into 22 subcategories. The average household solid waste generation rate was 281.27 g/cap/day. The compostable and recyclable shares respectively accounted for high percentage as 80.74% and 11%. Regarding plastic waste, the average plastic waste generation rate was 17.24 g/cap/day; plastic packaging and plastic containers dominated with the high percentage, 95.64% of plastic waste. Plastic shopping bags were especially identified as the major component, accounting for 45.72% of total plastic waste. Relevant factors such as household income and household size were found to have an existing correlation to plastic waste generation in detailed composition. The household habits and behaviors of plastic waste discharge and the aspects of environmental impacts and resource consumption for plastic waste disposal alternatives were also evaluated.

  10. Thatcher Bay, Washington, Nearshore Restoration Assessment

    USGS Publications Warehouse

    Breems, Joel; Wyllie-Echeverria, Sandy; Grossman, Eric E.; Elliott, Joel

    2009-01-01

    The San Juan Archipelago, located at the confluence of the Puget Sound, the Straits of Juan de Fuca in Washington State, and the Straits of Georgia, British Columbia, Canada, provides essential nearshore habitat for diverse salmonid, forage fish, and bird populations. With 408 miles of coastline, the San Juan Islands provide a significant portion of the available nearshore habitat for the greater Puget Sound and are an essential part of the regional efforts to restore Puget Sound (Puget Sound Shared Strategy 2005). The nearshore areas of the San Juan Islands provide a critical link between the terrestrial and marine environments. For this reason the focus on restoration and conservation of nearshore habitat in the San Juan Islands is of paramount importance. Wood-waste was a common by-product of historical lumber-milling operations. To date, relatively little attention has been given to the impact of historical lumber-milling operations in the San Juan Archipelago. Thatcher Bay, on Blakely Island, located near the east edge of the archipelago, is presented here as a case study on the restoration potential for a wood-waste contaminated nearshore area. Case study components include (1) a brief discussion of the history of milling operations. (2) an estimate of the location and amount of the current distribution of wood-waste at the site, (3) a preliminary examination of the impacts of wood-waste on benthic flora and fauna at the site, and (4) the presentation of several restoration alternatives for the site. The history of milling activity in Thatcher Bay began in 1879 with the construction of a mill in the southeastern part of the bay. Milling activity continued for more than 60 years, until the mill closed in 1942. Currently, the primary evidence of the historical milling operations is the presence of approximately 5,000 yd3 of wood-waste contaminated sediments. The distribution and thickness of residual wood-waste at the site was determined by using sediment coring and GIS-based interpolation techniques. Additionally, pilot studies were conducted to characterize in place sediment redox, organic composition, and sulfide impacts to nearshore flora and fauna. We found that the presence of wood-waste in Thatcher Bay may alter the quality of the benthic habitat by contributing to elevated levels of total organic composition (TOC) of the sediment. Increased TOC favors anaerobic respiration in marine sediments, and sulfide, a toxic by-product of this process, was found at levels as high as 17.5 mg L-1 in Thatcher Bay. The Thatcher Bay sulfide levels are several orders of magnitude higher than those known to impact benthic invertebrates. Eelgrass, Zostera marina, located on the western margin of Thatcher Bay, was surveyed by using underwater video surveys. This baseline distribution will in part be used to measure the impact of any future remediation efforts. Additionally, the distribution and survey data can provide an estimate of propagule source for future colonization of restored sediment. Three restoration alternatives were considered, and a ranking matrix was developed to score each alternative against site-specific and regional criteria. The process identified the removal of wood-waste from a water-based platform as the preferred alternative. Our multidisciplinary investigation identified the location, thickness, and potential impacts of wood-waste that has persisted in the nearshore environment of Thatcher Bay since at least 1942. We also provide a process to efficiently evaluate alternatives to remediate the impact of this historical disturbance and to potentially contribute to an increase of nearshore diversity and productivity at this site. Elements of this approach could inform restoration planning at similarly impacted sites throughout the region.

  11. Ecological sustainability of alternative biomass feedstock production for environmental benefits and bioenergy

    Treesearch

    Ronald S., Jr. Zalesny; Jill A. Zalesny; Edmund O. Bauer

    2007-01-01

    The incorporation of intensive forestry with waste management fills a much-needed niche throughout numerous phytotechnology applications. There is a growing opportunity to incorporate sustainable recycling of waste waters as irrigation and fertilization for alternative biomass feedstock production systems. However, the success of short rotation woody crops is largely...

  12. 10 CFR 61.54 - Alternative requirements for design and operations.

    Code of Federal Regulations, 2013 CFR

    2013-01-01

    ... Section 61.54 Energy NUCLEAR REGULATORY COMMISSION (CONTINUED) LICENSING REQUIREMENTS FOR LAND DISPOSAL OF RADIOACTIVE WASTE Technical Requirements for Land Disposal Facilities § 61.54 Alternative requirements for... other than those set forth in §§ 61.51 through 61.53 for the segregation and disposal of waste and for...

  13. 10 CFR 61.54 - Alternative requirements for design and operations.

    Code of Federal Regulations, 2012 CFR

    2012-01-01

    ... Section 61.54 Energy NUCLEAR REGULATORY COMMISSION (CONTINUED) LICENSING REQUIREMENTS FOR LAND DISPOSAL OF RADIOACTIVE WASTE Technical Requirements for Land Disposal Facilities § 61.54 Alternative requirements for... other than those set forth in §§ 61.51 through 61.53 for the segregation and disposal of waste and for...

  14. 10 CFR 61.54 - Alternative requirements for design and operations.

    Code of Federal Regulations, 2014 CFR

    2014-01-01

    ... Section 61.54 Energy NUCLEAR REGULATORY COMMISSION (CONTINUED) LICENSING REQUIREMENTS FOR LAND DISPOSAL OF RADIOACTIVE WASTE Technical Requirements for Land Disposal Facilities § 61.54 Alternative requirements for... other than those set forth in §§ 61.51 through 61.53 for the segregation and disposal of waste and for...

  15. 10 CFR 61.54 - Alternative requirements for design and operations.

    Code of Federal Regulations, 2010 CFR

    2010-01-01

    ... Section 61.54 Energy NUCLEAR REGULATORY COMMISSION (CONTINUED) LICENSING REQUIREMENTS FOR LAND DISPOSAL OF RADIOACTIVE WASTE Technical Requirements for Land Disposal Facilities § 61.54 Alternative requirements for... other than those set forth in §§ 61.51 through 61.53 for the segregation and disposal of waste and for...

  16. 10 CFR 61.54 - Alternative requirements for design and operations.

    Code of Federal Regulations, 2011 CFR

    2011-01-01

    ... Section 61.54 Energy NUCLEAR REGULATORY COMMISSION (CONTINUED) LICENSING REQUIREMENTS FOR LAND DISPOSAL OF RADIOACTIVE WASTE Technical Requirements for Land Disposal Facilities § 61.54 Alternative requirements for... other than those set forth in §§ 61.51 through 61.53 for the segregation and disposal of waste and for...

  17. Environmental assessment of alternative municipal solid waste management strategies. A Spanish case study.

    PubMed

    Bovea, M D; Ibáñez-Forés, V; Gallardo, A; Colomer-Mendoza, F J

    2010-11-01

    The aim of this study is to compare, from an environmental point of view, different alternatives for the management of municipal solid waste generated in the town of Castellón de la Plana (Spain). This town currently produces 207 ton of waste per day and the waste management system employed today involves the collection of paper/cardboard, glass and light packaging from materials banks and of rest waste at street-side containers. The proposed alternative scenarios were based on a combination of the following elements: selective collection targets to be accomplished by the year 2015 as specified in the Spanish National Waste Plan (assuming they are reached to an extent of 50% and 100%), different collection models implemented nationally, and diverse treatments of both the separated biodegradable fraction and the rest waste to be disposed of on landfills. This resulted in 24 scenarios, whose environmental behaviour was studied by applying the life cycle assessment methodology. In accordance with the ISO 14040-44 (2006) standard, an inventory model was developed for the following stages of the waste management life cycle: pre-collection (bags and containers), collection, transport, pre-treatment (waste separation) and treatment/disposal (recycling, composting, biogasification+composting, landfill with/without energy recovery). Environmental indicators were obtained for different impact categories, which made it possible to identify the key variables in the waste management system and the scenario that offers the best environmental behaviour. Finally, a sensitivity analysis was used to test some of the assumptions made in the initial life cycle inventory model. Copyright © 2010 Elsevier Ltd. All rights reserved.

  18. Alternatives evaluation and decommissioning study on shielded transfer tanks at Oak Ridge National Laboratory, Oak Ridge, Tennessee

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    DeVore, J.R.; Hinton, R.R.

    1994-08-01

    The shielded transfer tanks (STTs) are five obsolete cylindrical shipping casks which were used to transport high specific activity radioactive solutions by rail during the 1960s and early 1970s. The STTs are currently stored at the Oak Ridge National Laboratory under a shed roof. This report is an evaluation to determine the preferred alternative for the final disposition of the five STTs. The decommissioning alternatives assessed include: (1) the no action alternative to leave the STTs in their present location with continued surveillance and maintenance; (2) solidification of contents within the tanks and holding the STTs in long term retrievablemore » storage; (3) sale of one or more of the used STTs to private industry for use at their treatment facility with the remaining STTs processed as in Alternative 4; and (4) removal of tank contents for de-watering/retrievable storage, limited decontamination to meet acceptance criteria, smelting the STTs to recycle the metal through the DOE contaminated scrap metal program, and returning the shielding lead to the ORNL lead recovery program because the smelting contractor cannot reprocess the lead. To completely evaluate the alternatives for the disposition of the STTs, the contents of the tanks must be characterized. Shielding and handling requirements, risk considerations, and waste acceptance criteria all require that the radioactive inventory and free liquids residual in the STTs be known. Because characterization of the STT contents in the field was not input into a computer model to predict the probable inventory and amount of free liquid. The four alternatives considered were subjected to a numerical scoring procedure. Alternative 4, smelting the STTs to recycle the metal after removal/de-watering of the tank contents, had the highest score and is, therefore, recommended as the preferred alternative. However, if a buyer for one or more STT could be found, it is recommended that Alternative 3 be reconsidered.« less

  19. Effect of first and second generation biodiesel blends on engine performance and emission

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Azad, A. K., E-mail: azad.cqu@gmail.com, E-mail: a.k.azad@cqu.edu.au; Rasul, M. G., E-mail: m.rasul@cqu.edu.au; Bhuiya, M. M. K., E-mail: m.bhuiya@cqu.edu.au

    The biodiesel is a potential source of alternative fuel which can be used at different proportions with diesel fuel. This study experimentally investigated the effect of blend percentage on diesel engine performance and emission using first generation (soybean) and second generation (waste cooking) biodiesel. The characterization of the biodiesel was done according to ASTM and EN standards and compared with ultralow sulfur diesel (ULSD) fuel. A multi-cylinder test bed engine coupled with electromagnetic dynamometer and 5 gas analyzer were used for engine performance and emission test. The investigation was made using B5, B10 and B15 blends for both biodiesels. Themore » study found that brake power (BP) and brake torque (BT) slightly decreases and brake specific fuel consumption (BSFC) slightly increases with an increase in biodiesel blends ratio. Besides, a significant reduction in exhaust emissions (except NO{sub x} emission) was found for both biodiesels compared to ULSD. Soybean biodiesel showed better engine performance and emissions reduction compared with waste cooking biodiesel. However, NO{sub x} emission for B5 waste cooking biodiesel was lower than soybean biodiesel.« less

  20. Bioconversion of shrimp waste Penaeus merguiensis using lactic acid fermentation: An alternative procedure for chemical extraction of chitin and chitosan.

    PubMed

    Sedaghat, Fatemeh; Yousefzadi, Morteza; Toiserkani, Hojjat; Najafipour, Sohrab

    2017-11-01

    Chitin extraction from shrimp wastes by biological treatment, using the Pseudomonas aeruginosa was a positive and simple method. In order to look for the optimal conditions, the wastes were incubated at 30°C and 100rpm in different glucose (0%, 10%, 15% and 20%) and inoculation (10%, 15% and 20%) concentrations for 4 and 6days. At the end of fermentation, Protease activity was investigated at different temperatures and temperature 50°C was considered as the optimum. The results obtained also showed a direct relationship between the concentration of different parameters and deproteinization and demineralization rates, so that the optimal conditions were 20% glucose, 20% inoculation and 6days fermentation. These conditions led to 82% demineralization, 92% deproteinization and chitin yield of 47%. Then, chitin was converted to chitosan using microwave, autoclave and traditional methods. The highest yield (87%) was obtained with autoclave method. At the end, the chitin and chitosan were characterized by elemental analysis and FTIR. Copyright © 2017 Elsevier B.V. All rights reserved.

  1. An investigation on the fuel savings potential of hybrid hydraulic refuse collection vehicles.

    PubMed

    Bender, Frank A; Bosse, Thomas; Sawodny, Oliver

    2014-09-01

    Refuse trucks play an important role in the waste collection process. Due to their typical driving cycle, these vehicles are characterized by large fuel consumption, which strongly affects the overall waste disposal costs. Hybrid hydraulic refuse vehicles offer an interesting alternative to conventional diesel trucks, because they are able to recuperate, store and reuse braking energy. However, the expected fuel savings can vary strongly depending on the driving cycle and the operational mode. Therefore, in order to assess the possible fuel savings, a typical driving cycle was measured in a conventional vehicle run by the waste authority of the City of Stuttgart, and a dynamical model of the considered vehicle was built up. Based on the measured driving cycle and the vehicle model including the hybrid powertrain components, simulations for both the conventional and the hybrid vehicle were performed. Fuel consumption results that indicate savings of about 20% are presented and analyzed in order to evaluate the benefit of hybrid hydraulic vehicles used for refuse collection. Copyright © 2014 Elsevier Ltd. All rights reserved.

  2. TECHNICAL RESOURCE DOCUMENT: TREATMENT TECHNOLOGIES FOR CORROSIVE-CONTAINING WASTES. VOLUME 2

    EPA Science Inventory

    The Technical Resource Document (TRD) for wastes containing corrosives is one in a series of five documents which evaluate waste management alternatives to land disposal. In addition to this TRD for corrosive wastes, the other four TRDs in the series address land disposal alterna...

  3. INFLUENCE OF PH AND OXIDATION-REDUCTION POTENTIAL (EH) ON THE DISSOLUTION OF MERCURY-CONTAINING MINE WASTES FROM THE SULFUR BANK MERCURY MINE

    EPA Science Inventory

    This study was undertaken as a part of developing treatment alternatives for waste materials, primarily waste rock and roaster tailings, from sites contaminated with mercury (Hg) mining wastes. Leaching profiles of waste rock over a range of different pH and oxidation-reduction (...

  4. Use of municipal solid waste incineration bottom ash and crop by-product for producing lightweight aggregate

    NASA Astrophysics Data System (ADS)

    Giro-Paloma, J.; Ribas-Manero, V.; Maldonado-Alameda, A.; Formosa, J.; Chimenos, J. M.

    2017-10-01

    Due to the growing amount of residues in Europe, it is mandatory to provide a viable alternative for managing wastes contributing to the efficient use of resources. Besides, it is also essential to move towards a low carbon economy, priority EU by 2050. Among these, it is important to highlight the development of sustainable alternatives capable of incorporating different kind of wastes in their formulations.Municipal Solid Waste Incineration (MSWI) is estimated to increase in Europe, where the accessibility of landfill is restricted. Bottom ash (BA) is the most significant by-product from MSWI as it accounts for 85 - 95 % of the solid product resulting from combustion. BA is a mixture of calcium-rich compounds and others silicates enriched in iron and sodium. In addition, it is categorized as non-hazardous waste which can be revalorized as secondary material in construction or civil engineering fields, previous weathering stabilization during 2 - 3 months. Taking into account the relative proportion of each size fraction and the corresponding material characterization, the content of glass (primary and secondary) is estimated to be around 60 wt%. Furthermore, as a renewable resource and according to waste management European policies, residual agricultural biomass has attracted attention in preparation of advanced materials for various applications, due to their low cost, abundance, and environment friendliness. Among this residual biomass, rice husk is a by-product of rice milling industry which has high content of silica and has been widely used in buildings as natural thermal insulation material.Weathered BA (WBA) with a particle size less than 30 mm was milled under 100 μm, mixed with 2.0 - 5.0 mm rice husk, formed into ball-shaped pellets and sintered by different thermal treatments, which remove the organic matter content generating a large porosity. Physico-chemical analysis and mechanical behavior of the manufactured lightweight aggregates were tested. The obtained results provide a suitable physico-mechanical formulation using WBA as silica source, as well as a common crop by-product.

  5. 77 FR 20387 - Agency Information Collection Activities; Submission to OMB for Review and Approval; Comment...

    Federal Register 2010, 2011, 2012, 2013, 2014

    2012-04-04

    ... waste incinerators, hazardous waste cement kilns, hazardous waste lightweight aggregate kilns, hazardous..., notification if the owner or operator elects to comply with alternative requirements, initial performance tests...

  6. Alternatives Generation and Analysis for Heat Removal from High Level Waste Tanks

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    WILLIS, W.L.

    This document addresses the preferred combination of design and operational configurations to provide heat removal from high-level waste tanks during Phase 1 waste feed delivery to prevent the waste temperature from exceeding tank safety requirement limits. An interim decision for the preferred method to remove the heat from the high-level waste tanks during waste feed delivery operations is presented herein.

  7. Quantifying the transport impacts of domestic waste collection strategies.

    PubMed

    McLeod, Fraser; Cherrett, Tom

    2008-11-01

    This paper models the effects of three different options for domestic waste collection using data from three Hampshire authorities: (i) joint working between neighbouring waste collection authorities; (ii) basing vehicles at waste disposal sites; and (iii) alternate weekly collection of residual waste and dry recyclables. A vehicle mileage savings of 3% was modelled for joint working, where existing vehicle allocations to depots were maintained, which increased to 5.9% when vehicles were re-allocated to depots optimally. Vehicle mileage was reduced by 13.5% when the collection rounds were based out of the two waste disposal sites rather than out of the existing depots, suggesting that the former could be the most effective place to keep vehicles providing that travel arrangements for the crews could be made. Alternate weekly collection was modelled to reduce vehicle mileage by around 8% and time taken by 14%, when compared with a typical scenario of weekly collection of residual and fortnightly collection of recyclable waste. These results were based on an assumption that 20% of the residual waste would be directly diverted into the dry recyclables waste stream.

  8. Report: landfill alternative daily cover: conserving air space and reducing landfill operating cost.

    PubMed

    Haughey, R D

    2001-02-01

    Title 40, Part 258 of the Code of Federal Regulations, Solid Waste Disposal Facility Criteria, commonly referred to as Subtitle D, became effective on October 9, 1993. It establishes minimum criteria for solid waste disposal facility siting, design, operations, groundwater monitoring and corrective action, and closure and postclosure maintenance, while providing EPA-approved state solid waste regulatory programs flexibility in implementing the criteria. Section 258.21(a) [40 CFR 258.21(a)] requires owners or operators of municipal solid waste landfill (MSWLF) units to cover disposed solid waste with 30cm of earthen material at the end of the operating day, or at more frequent intervals, if necessary, to control disease vectors, fires, odours, blowing litter, and scavenging. This requirement is consistent with already existing solid waste facility regulations in many states. For many MSWLFs, applying daily cover requires the importation of soil which increases landfill operating costs. Daily cover also uses valuable landfill air space, reducing potential operating revenue and the landfill's operating life. 40 CFR 258.21 (b) allows the director of an approved state to approve alternative materials of an alternative thickness if the owner or operator demonstrates that the alternative material and thickness will control disease vectors, fires, odours, blowing litter, and scavenging without presenting a threat to human health and the environment. Many different types of alternative daily cover (ADC) are currently being used, including geosynthetic tarps, foams, garden waste, and auto shredder fluff. These materials use less air space than soil and can reduce operating costs. This paper discusses the variety of ADCs currently being used around the country and their applicability to different climates and operating conditions, highlighting the more unusual types of ADC, the types of demonstrations necessary to obtain approval of ADC, and the impact on landfill air space and operating costs of ADC use.

  9. DOE Office of Scientific and Technical Information (OSTI.GOV)

    Elicio, Andy U.

    My ERM 593 applied project will provide guidance for the Los Alamos National Laboratory Waste Stream Profile reviewer (i.e. RCRA reviewer) in regards to Reviewing and Approving a Waste Stream Profile in the Waste Compliance and Tracking System. The Waste Compliance and Tracking system is called WCATS. WCATS is a web-based application that “supports the generation, characterization, processing and shipment of LANL radioactive, hazardous, and industrial waste.” The LANL generator must characterize their waste via electronically by filling out a waste stream profile (WSP) in WCATS. Once this process is completed, the designated waste management coordinator (WMC) will perform amore » review of the waste stream profile to ensure the generator has completed their waste stream characterization in accordance with applicable state, federal and LANL directives particularly P930-1, “LANL Waste Acceptance Criteria,” and the “Waste Compliance and Tracking System User's Manual, MAN-5004, R2,” as applicable. My guidance/applied project will describe the purpose, scope, acronyms, definitions, responsibilities, assumptions and guidance for the WSP reviewer as it pertains to each panel and subpanel of a waste stream profile.« less

  10. HEPA Filter Disposal Write-Up 10/19/16

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Loll, C.

    Process knowledge (PK) collection on HEPA filters is handled via the same process as other waste streams at LLNL. The Field technician or Characterization point of contact creates an information gathering document (IGD) in the IGD database, with input provided from the generator, and submits it for electronic approval. This document is essentially a waste generation profile, detailing the physical, chemical as well as radiological characteristics, and hazards, of a waste stream. It will typically contain a general, but sometimes detailed, description of the work processes which generated the waste. It will contain PK as well as radiological and industrialmore » hygiene analytical swipe results, and any other analytical or other supporting knowledge related to characterization. The IGD goes through an electronic approval process to formalize the characterization and to ensure the waste has an appropriate disposal path. The waste generator is responsible for providing initial process knowledge information, and approves the IGD before it routed to chemical and radiological waste characterization professionals. This is the standard characterization process for LLNL-generated HEPA Filters.« less

  11. Microstructural characterization of catalysis product of nanocement based materials: A review

    NASA Astrophysics Data System (ADS)

    Sutan, Norsuzailina Mohamed; Izaitul Akma Ideris, Nur; Taib, Siti Noor Linda; Lee, Delsye Teo Ching; Hassan, Alsidqi; Kudnie Sahari, Siti; Mohamad Said, Khairul Anwar; Rahman Sobuz, Habibur

    2018-03-01

    Cement as an essential element for cement-based products contributed to negative environmental issues due to its high energy consumption and carbon dioxide emission during its production. These issues create the need to find alternative materials as partial cement replacement where studies on the potential of utilizing silica based materials as partial cement replacement come into picture. This review highlights the effectiveness of microstructural characterization techniques that have been used in the studies that focus on characterization of calcium hydroxide (CH) and calcium silicate hydrate (C-S-H) formation during hydration process of cement-based product incorporating nano reactive silica based materials as partial cement replacement. Understanding the effect of these materials as cement replacement in cement based product focusing on the microstructural development will lead to a higher confidence in the use of industrial waste as a new non-conventional material in construction industry that can catalyse rapid and innovative advances in green technology.

  12. DOE's Remote-Handled TRU Waste Characterization Program: Implementation Plan

    EPA Pesticide Factsheets

    Remote-handled (RH) transuranic (TRU) waste characterization, which involves obtaining chemical, radiological, and physical data, is a primary component of ensuring compliance of the Waste Isolation Pilot Plant (WIPP) with regulatory requirements.

  13. Analysis of space systems for the space disposal of nuclear waste follow-on study. Volume 1: Executive summary

    NASA Technical Reports Server (NTRS)

    1982-01-01

    The impact on space systems of three alternative waste mixes was evaluated as part of an effort to investigate the disposal of certain high-level nuclear wastes in space as a complement to mined geologic repositories. A brief overview of the study background, objectives, scope, approach and guidelines, and limitations is presented. The effects of variations in waste mixes on space system concepts were studied in order to provide data for determining relative total system risk benefits resulting from space disposal of the alternative waste mixes. Overall objectives of the NASA-DOE sustaining-level study program are to investigate space disposal concepts which can provide information to support future nuclear waste terminal storage programmatic decisions and to maintain a low level of research activity in this area to provide a baseline for future development should a decision be made to increase the emphasis on this option.

  14. Final environmental impact statement. Waste Isolation Pilot Plant

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Not Available

    1980-10-01

    This volume contains the appendices for the Final Environmental Impact Statement for the Waste Isolation Pilot Plant (WIPP). Alternative geologic environs are considered. Salt, crystalline rock, argillaceous rock, and tuff are discussed. Studies on alternate geologic regions for the siting of WIPP are reviewed. President Carter's message to Congress on the management of radioactive wastes and the findings and recommendations of the interagency review group on nuclear waste management are included. Selection criteria for the WIPP site including geologic, hydrologic, tectonic, physicochemical compatability, and socio-economic factors are presented. A description of the waste types and the waste processing procedures aremore » given. Methods used to calculate radiation doses from radionuclide releases during operation are presented. A complete description of the Los Medanos site, including archaeological and historic aspects is included. Environmental monitoring programs and long-term safety analysis program are described. (DMC)« less

  15. A Review on Landfill Management in the Utilization of Plastic Waste as an Alternative Fuel

    NASA Astrophysics Data System (ADS)

    Hidayah, Nurul; Syafrudin

    2018-02-01

    Wastes from landfills originate from many spheres of life. These are produces as a result of human activities either domestically or industrially. The global plastic production increased over years due to the vast applications of plastics in many sectors. The continuous demand of plastics caused the plastic wastes accumulation in the landfill consumed a lot of spaces that contributed to the environmental. In addition, economic growth and development also increased our demand and dependency on plastics which leads to its accumulation in landfills imposing risk on human health, animals and cause environmental pollution problems such as ground water contamination, sanitary related issues, etc. The management and disposal of plastic waste have become a major concern, especially in developing cities. The idea of waste to energy recovery is one of the promising techniques used for managing the waste of plastic. Hence, this paper aims review at utilizing of plastic as an alternative fuel.

  16. Data summary of municipal solid waste management alternatives. Volume 12, Numerically indexed bibliography

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    None

    1992-10-01

    This appendix contains the numerically indexed bibliography for the complete group of reports on municipal solid waste management alternatives. The list references information on the following topics: mass burn technologies, RDF technologies, fluidized bed combustion, pyrolysis and gasification of MSW, materials recovery- recycling technologies, sanitary landfills, composting and anaerobic digestion of MSW.

  17. Data summary of municipal solid waste management alternatives. Volume 11, Alphabetically indexed bibliography

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    None

    1992-10-01

    This appendix contains the alphabetically indexed bibliography for the complete group of reports on municipal waste management alternatives. The references are listed for each of the following topics: mass burn technologies, RDF technologies, fluidized-bed combustion, pyrolysis and gasification of MSW, materials recovery- recycling technologies, sanitary landfills, composting, and anaerobic digestion of MSW.

  18. 78 FR 29124 - Draft Environmental Impact Statement (EIS) for the Implementation of Energy, Water, and Solid...

    Federal Register 2010, 2011, 2012, 2013, 2014

    2013-05-17

    ... plant (Alternative 4); construction and operation of a geothermal energy facility (Alternative 5); and... Implementation of Energy, Water, and Solid Waste Sustainability Initiatives at Fort Bliss, Texas and New Mexico... proposes to implement Net Zero energy, water and waste initiatives by 2020 at Fort Bliss to meet mandates...

  19. Data sharing report characterization of the surveillance and maintenance project miscellaneous process inventory waste items Oak Ridge National Laboratory, Oak Ridge, TN

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Weaver, Phyllis C.

    2013-12-12

    The U.S. Department of Energy (DOE) Oak Ridge Office of Environmental Management (EM-OR) requested Oak Ridge Associated Universities (ORAU), working under the Oak Ridge Institute for Science and Education (ORISE) contract, to provide technical and independent waste management planning support under the American Recovery and Reinvestment Act (ARRA). Specifically, DOE EM-OR requested ORAU to plan and implement a sampling and analysis campaign to target certain items associated with URS|CH2M Oak Ridge, LLC (UCOR) surveillance and maintenance (S&M) process inventory waste. Eight populations of historical and reoccurring S&M waste at the Oak Ridge National Laboratory (ORNL) have been identified in themore » Waste Handling Plan for Surveillance and Maintenance Activities at the Oak Ridge National Laboratory, DOE/OR/01-2565&D2 (WHP) (DOE 2012) for evaluation and processing for final disposal. This waste was generated during processing, surveillance, and maintenance activities associated with the facilities identified in the process knowledge (PK) provided in Appendix A. A list of items for sampling and analysis were generated from a subset of materials identified in the WHP populations (POPs) 4, 5, 6, 7, and 8, plus a small number of items not explicitly addressed by the WHP. Specifically, UCOR S&M project personnel identified 62 miscellaneous waste items that would require some level of evaluation to identify the appropriate pathway for disposal. These items are highly diverse, relative to origin; composition; physical description; contamination level; data requirements; and the presumed treatment, storage, and disposal facility (TSDF). Because of this diversity, ORAU developed a structured approach to address item-specific data requirements necessary for acceptance in a presumed TSDF that includes the Environmental Management Waste Management Facility (EMWMF)—using the approved Waste Lot (WL) 108.1 profile—the Y-12 Sanitary Landfill (SLF) if appropriate; EnergySolutions Clive; and the Nevada National Security Site (NNSS) (ORAU 2013b). Finally, the evaluation of these wastes was more suited to a judgmental sampling approach rather than a statistical design, meaning data were collected for each individual item, thereby providing information for item-byitem disposition decisions. ORAU prepared a sampling and analysis plan (SAP) that outlined data collection strategies, methodologies, and analytical guidelines and requirements necessary for characterizing targeted items (ORAU 2013b). The SAP described an approach to collect samples that allowed evaluation as to whether or not the waste would be eligible for disposal at the EMWMF. If the waste was determined not to be eligible for EMWMF disposal, then there would be adequate information collected that would allow the waste to be profiled for one of the alternate TSDFs listed above.« less

  20. Going green by reducing red. New alternative medical waste treatment technologies.

    PubMed

    Zanoni, P

    1998-01-01

    The field of medical waste disposal is changing rapidly. Over the past decade, there has been increasing public health concern over health care's red bag waste. The health care industry must routinely contend with a complex set of regulations covering occupational safety, transportation and packaging, medical waste disposal management, and now environmental regulations for medical waste incinerators.

  1. Application of analytic hierarchy process in a waste treatment technology assessment in Mexico.

    PubMed

    Taboada-González, Paul; Aguilar-Virgen, Quetzalli; Ojeda-Benítez, Sara; Cruz-Sotelo, Samantha

    2014-09-01

    The high per capita generation of solid waste and the environmental problems in major rural communities of Ensenada, Baja California, have prompted authorities to seek alternatives for waste treatment. In the absence of a selection methodology, three technologies of waste treatment with energy recovery (an anaerobic digester, a downdraft gasifier, and a plasma gasifier) were evaluated, taking the broader social, political, economic, and environmental issues into considerations. Using the scientific literature as a baseline, interviews with experts, decision makers and the community, and waste stream studies were used to construct a hierarchy that was evaluated by the analytic hierarchy process. In terms of the criteria, judgments, and assumptions made in the model, the anaerobic digester was found to have the highest rating and should consequently be selected as the waste treatment technology for this area. The study results showed low sensitivity, so alternative scenarios were not considered. The methodology developed in this study may be useful for other governments who wish to assess technologies to select waste treatment.

  2. The composition, leaching, and sorption behavior of some alternative sources of phosphorus for soils.

    PubMed

    Stutter, Marc I

    2015-03-01

    Concerns about the sustainability of inorganic fertilizers necessitate the characterization of alternative P source materials for agronomic P-efficiencies and P losses via leaching. Firstly, this study examined nutrient compositions including P speciation of seven soil amendments: sewage sludge (SS), anaerobic digestate (AD), green compost (GC), food waste compost (FWC), chicken manure (CM), biochar, and seaweed. Secondly, soil P leaching and availability was studied on a subset of four materials (SS, AD, GC, and CM). Sorption of extracts onto columns of a test soil showed strong P retention for SS and compost, but weak P sorption for CM and especially AD, suggesting short-term leaching risks for soil applied AD. Limited P desorption with water or citrate indicated sorbed P was strongly fixed, potentially limiting crop availability. These data indicate that variation in P forms and environmental behavior should be understood to maximize P usage, but minimize leaching and soil P accumulation. Hence, different alternative P source materials need differing recommendations for their agronomic management.

  3. Analysis of alternatives for immobilized low activity waste disposal

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Burbank, D.A.

    This report presents a study of alternative disposal system architectures and implementation strategies to provide onsite near-surface disposal capacity to receive the immobilized low-activity waste produced by the private vendors. The analysis shows that a flexible unit strategy that provides a suite of design solutions tailored to the characteristics of the immobilized low-activity waste will provide a disposal system that best meets the program goals of reducing the environmental, health, and safety impacts; meeting the schedule milestones; and minimizing the life-cycle cost of the program.

  4. Standards Applicable to Generators of Hazardous Waste; Alternative Requirements for Hazardous Waste Determination and Accumulation of Unwanted Material at Laboratories Owned by Colleges and Universities and Other Eligible Academic Entities Formally Affiliated With Colleges and Universities. Final Rule. Federal Register, Environmental Protection Agency. 40 CFR Parts 261 and 262. Part II

    ERIC Educational Resources Information Center

    National Archives and Records Administration, 2008

    2008-01-01

    The Environmental Protection Agency (EPA or the Agency) is finalizing an alternative set of generator requirements applicable to laboratories owned by eligible academic entities, as defined in this final rule. The rule provides a flexible and protective set of regulations that address the specific nature of hazardous waste generation and…

  5. Ultra(high)-pressure liquid chromatography-electrospray ionization-time-of-flight-ion mobility-high definition mass spectrometry for the rapid identification and structural characterization of flavonoid glycosides from cauliflower waste.

    PubMed

    Gonzales, Gerard Bryan; Raes, Katleen; Coelus, Sofie; Struijs, Karin; Smagghe, Guy; Van Camp, John

    2014-01-03

    In this paper, a strategy for the detection and structural elucidation of flavonoid glycosides from a complex matrix in a single chromatographic run using U(H)PLC-ESI-IMS-HDMS/MS(E) is presented. This system operates using alternative low and high energy voltages that is able to perform the task of conventional MS/MS in a data-independent way without re-injection of the sample, which saves analytical time. Also, ion mobility separation (IMS) was employed as an additional separation technique for compounds that are co-eluting after U(H)PLC separation. First, the fragmentation of flavonoid standards were analyzed and criteria was set for structural elucidation of flavonoids in a plant extract. Based on retention times, UV spectra, exact mass, and MS fragment characteristics, such as abundances of daughter ions and the presence of radical ions ([Y0-H](-)), a total 19 flavonoid glycosides, of which 8 non-acylated and 11 acylated, were detected and structurally characterized in a cauliflower waste extract. Kaempferol and quercetin were the main aglycones detected while sinapic and ferulic acid were the main phenolic acids. C-glycosides were also found although their structure could not be elucidated. The proposed method can be used as a rapid screening test for flavonoid identification and for routine analysis of plant extracts, such as these derived from cauliflower waste. The study also confirms that agroindustrial wastes, such as cauliflower leaves, could be seen as a valuable source of different bioactive phenolic compounds. Copyright © 2013 Elsevier B.V. All rights reserved.

  6. Solid-state fermentation and composting as alternatives to treat hair waste: A life-cycle assessment comparative approach.

    PubMed

    Catalán, Eva; Komilis, Dimitrios; Sánchez, Antoni

    2017-07-01

    One of the wastes associated with leather production in tannery industries is the hair residue generated during the dehairing process. Hair wastes are mainly dumped or managed through composting but recent studies propose the treatment of hair wastes through solid-state fermentation (SSF) to obtain proteases and compost. These enzymes are suitable for its use in an enzymatic dehairing process, as an alternative to the current chemical dehairing process. In the present work, two different scenarios for the valorization of the hair waste are proposed and assessed by means of life-cycle assessment: composting and SSF for protease production. Detailed data on hair waste composting and on SSF protease production are gathered from previous studies performed by our research group and from a literature survey. Background inventory data are mainly based on Ecoinvent version 3 from software SimaPro® 8. The main aim of this study was to identify which process results in the highest environmental impact. The SSF process was found to have lower environmental impacts than composting, due to the fact that the enzyme use in the dehairing process prevents the use of chemicals traditionally used in the dehairing process. This permits to reformulate an industrial process from the classical approach of waste management to a novel alternative based on circular economy.

  7. 40 CFR 262.207 - Training.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES (CONTINUED) STANDARDS APPLICABLE TO GENERATORS OF HAZARDOUS WASTE Alternative Requirements for Hazardous Waste Determination and... experiment; or (2) Formal classroom training; or (3) Electronic/written training; or (4) On-the-job training...

  8. 40 CFR 262.207 - Training.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES (CONTINUED) STANDARDS APPLICABLE TO GENERATORS OF HAZARDOUS WASTE Alternative Requirements for Hazardous Waste Determination and... experiment; or (2) Formal classroom training; or (3) Electronic/written training; or (4) On-the-job training...

  9. Alternative Fuels

    EPA Pesticide Factsheets

    Alternative fuels include gaseous fuels such as hydrogen, natural gas, and propane; alcohols such as ethanol, methanol, and butanol; vegetable and waste-derived oils; and electricity. Overview of alternative fuels is here.

  10. Enclosure (from letter from EPA to DOE sent 3/26/04) - Technical and Regulatory Support Document: EPA's Remote Handled Waste Characterization Determination

    EPA Pesticide Factsheets

    Based on the requirements presented in 40 CFR 194.24(c )(2) to (4) and 194.22(a)(1) and using experience gained as part of the CH waste characterization program, EPA examined the DOE's RH Waste Characterization Proposal as presented in the WCPIP.

  11. WCATS: Waste Documentation, Course No. 8504

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Simpson, Sandy

    2016-04-14

    This course was developed for individuals at Los Alamos National Laboratory (LANL) who characterize and document waste streams in the Waste Compliance and Tracking System (WCATS) according to Environmental Protection Agency (EPA) Department of Transportation (DOT) regulations, Department of Energy Orders, and other applicable criteria. When you have completed this course, you will be able to recognize how waste documentation enables LANL to characterize and classify hazardous waste for compliant treatment, storage, and disposal, identify the purpose of the waste stream profile (WSP), identify the agencies that provide guidance for waste management, and more.

  12. 40 CFR 262.215 - Unwanted material that is not solid or hazardous waste.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 40 Protection of Environment 26 2011-07-01 2011-07-01 false Unwanted material that is not solid or... (CONTINUED) SOLID WASTES (CONTINUED) STANDARDS APPLICABLE TO GENERATORS OF HAZARDOUS WASTE Alternative... Eligible Academic Entities § 262.215 Unwanted material that is not solid or hazardous waste. (a) If an...

  13. 40 CFR 262.215 - Unwanted material that is not solid or hazardous waste.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 40 Protection of Environment 25 2010-07-01 2010-07-01 false Unwanted material that is not solid or... (CONTINUED) SOLID WASTES (CONTINUED) STANDARDS APPLICABLE TO GENERATORS OF HAZARDOUS WASTE Alternative... Eligible Academic Entities § 262.215 Unwanted material that is not solid or hazardous waste. (a) If an...

  14. Nuclear waste

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Not Available

    1991-09-01

    Radioactive waste is mounting at U.S. nuclear power plants at a rate of more than 2,000 metric tons a year. Pursuant to statute and anticipating that a geologic repository would be available in 1998, the Department of Energy (DOE) entered into disposal contracts with nuclear utilities. Now, however, DOE does not expect the repository to be ready before 2010. For this reason, DOE does not want to develop a facility for monitored retrievable storage (MRS) by 1998. This book is concerned about how best to store the waste until a repository is available, congressional requesters asked GAO to review themore » alternatives of continued storage at utilities' reactor sites or transferring waste to an MRS facility, GAO assessed the likelihood of an MRSA facility operating by 1998, legal implications if DOE is not able to take delivery of wastes in 1998, propriety of using the Nuclear Waste Fund-from which DOE's waste program costs are paid-to pay utilities for on-site storage capacity added after 1998, ability of utilities to store their waste on-site until a repository is operating, and relative costs and safety of the two storage alternatives.« less

  15. Assessment of remote sensing technologies to discover and characterize waste sites

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    NONE

    1992-03-11

    This report presents details about waste management practices that are being developed using remote sensing techniques to characterize DOE waste sites. Once the sites and problems have been located and characterized and an achievable restoration and remediation program have been established, efforts to reclaim the environment will begin. Special problems to be considered are: concentrated waste forms in tanks and pits; soil and ground water contamination; ground safety hazards for workers; and requirement for long-term monitoring.

  16. Mechanical recycling of waste electric and electronic equipment: a review.

    PubMed

    Cui, Jirang; Forssberg, Eric

    2003-05-30

    The production of electric and electronic equipment (EEE) is one of the fastest growing areas. This development has resulted in an increase of waste electric and electronic equipment (WEEE). In view of the environmental problems involved in the management of WEEE, many counties and organizations have drafted national legislation to improve the reuse, recycling and other forms of recovery of such wastes so as to reduce disposal. Recycling of WEEE is an important subject not only from the point of waste treatment but also from the recovery of valuable materials.WEEE is diverse and complex, in terms of materials and components makeup as well as the original equipment's manufacturing processes. Characterization of this waste stream is of paramount importance for developing a cost-effective and environmentally friendly recycling system. In this paper, the physical and particle properties of WEEE are presented. Selective disassembly, targeting on singling out hazardous and/or valuable components, is an indispensable process in the practice of recycling of WEEE. Disassembly process planning and innovation of disassembly facilities are most active research areas. Mechanical/physical processing, based on the characterization of WEEE, provides an alternative means of recovering valuable materials. Mechanical processes, such as screening, shape separation, magnetic separation, Eddy current separation, electrostatic separation, and jigging have been widely utilized in recycling industry. However, recycling of WEEE is only beginning. For maximum separation of materials, WEEE should be shredded to small, even fine particles, generally below 5 or 10mm. Therefore, a discussion of mechanical separation processes for fine particles is highlighted in this paper. Consumer electronic equipment (brown goods), such as television sets, video recorders, are most common. It is very costly to perform manual dismantling of those products, due to the fact that brown goods contain very low-grade precious metals and copper. It is expected that a mechanical recycling process will be developed for the upgrading of low metal content scraps.

  17. Evaluation of alternative nonflame technologies for destruction of hazardous organic waste

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Schwinkendorf, W.E.; Musgrave, B.C.; Drake, R.N.

    1997-04-01

    The US Department of Energy`s Mixed Waste Focus Area (MWFA) commissioned an evaluation of mixed waste treatment technologies that are alternatives to incineration for destruction of hazardous organic wastes. The purpose of this effort is to evaluate technologies that are alternatives to open-flame, free-oxygen combustion (as exemplified by incinerators), and recommend to the Waste Type Managers and the MWFA which technologies should be considered for further development. Alternative technologies were defined as those that have the potential to: destroy organic material without use of open-flame reactions with free gas-phase oxygen as the reaction mechanism; reduce the offgas volume and associatedmore » contaminants (metals, radionuclides, and particulates) emitted under normal operating conditions; eliminate or reduce the production of dioxins and furans; and reduce the potential for excursions in the process that can lead to accidental release of harmful levels of chemical or radioactive materials. Twenty-three technologies were identified that have the potential for meeting these requirements. These technologies were rated against the categories of performance, readiness for deployment, and environment safety, and health. The top ten technologies that resulted from this evaluation are Steam Reforming, Electron Beam, UV Photo-Oxidation, Ultrasonics, Eco Logic reduction process, Supercritical Water oxidation, Cerium Mediated Electrochemical Oxidation, DETOX{sup SM}, Direct Chemical Oxidation (peroxydisulfate), and Neutralization/Hydrolysis.« less

  18. Biological nutrients removal from the supernatant originating from the anaerobic digestion of the organic fraction of municipal solid waste.

    PubMed

    Malamis, S; Katsou, E; Di Fabio, S; Bolzonella, D; Fatone, F

    2014-09-01

    This study critically evaluates the biological processes and techniques applied to remove nitrogen and phosphorus from the anaerobic supernatant produced from the treatment of the organic fraction of municipal solid waste (OFMSW) and from its co-digestion with other biodegradable organic waste (BOW) streams. The wide application of anaerobic digestion for the treatment of several organic waste streams results in the production of high quantities of anaerobic effluents. Such effluents are characterized by high nutrient content, because organic and particulate nitrogen and phosphorus are hydrolyzed in the anaerobic digestion process. Consequently, adequate post-treatment is required in order to comply with the existing land application and discharge legislation in the European Union countries. This may include physicochemical and biological processes, with the latter being more advantageous due to their lower cost. Nitrogen removal is accomplished through the conventional nitrification/denitrification, nitritation/denitritation and the complete autotrophic nitrogen removal process; the latter is accomplished by nitritation coupled with the anoxic ammonium oxidation process. As anaerobic digestion effluents are characterized by low COD/TKN ratio, conventional denitrification/nitrification is not an attractive option; short-cut nitrogen removal processes are more promising. Both suspended and attached growth processes have been employed to treat the anaerobic supernatant. Specifically, the sequencing batch reactor, the membrane bioreactor, the conventional activated sludge and the moving bed biofilm reactor processes have been investigated. Physicochemical phosphorus removal via struvite precipitation has been extensively examined. Enhanced biological phosphorus removal from the anaerobic supernatant can take place through the sequencing anaerobic/aerobic process. More recently, denitrifying phosphorus removal via nitrite or nitrate has been explored. The removal of phosphorus from the anaerobic supernatant of OFMSW is an interesting research topic that has not yet been explored. At the moment, standardization in the design of facilities that treat anaerobic supernatant produced from the treatment of OFMSW is still under development. To move toward this direction, it is first necessary to assess the performance of alternative treatment options. It study concentrates existing data regarding the characteristics of the anaerobic supernatant produced from the treatment of OFMSW and from their co-digestion with other BOW. This provides data documenting the effect of the anaerobic digestion operating conditions on the supernatant quality and critically evaluates alternative options for the post-treatment of the liquid fraction produced from the anaerobic digestion process.

  19. The role of acceptable knowledge in transuranic waste disposal operations - 11117

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Chancellor, Christopher John; Nelson, Roger

    2010-11-08

    The Acceptable Knowledge (AK) process plays a key role in the delineation of waste streams destined for the Waste Isolation Pilot Plant (WIPP). General Electric's Vallecitos Nuclear Center (GEVNC) provides for an ideal case study of the application of AK in a multiple steward environment. In this review we will elucidate the pivotal role Acceptable Knowledge played in segregating Department of Energy (DOE) responsibilities from a commercial facility. The Acceptable Knowledge process is a necessary component of waste characterization that determines whether or not a waste stream may be considered for disposal at the WIPP site. This process may bemore » thought of as an effort to gain a thorough understanding of the waste origin, chemical content, and physical form gleaned by the collection of documentation that concerns generator/storage site history, mission, and operations; in addition to waste stream specific information which includes the waste generation process, the waste matrix, the quantity of waste concerned, and the radiological and chemical make up of the waste. The collection and dissemination of relevant documentation is the fundamental requirement for the AK process to work. Acceptable Knowledge is the predominant process of characterization and, therefore, a crucial part of WIPP's transuranic waste characterization program. This characterization process, when conducted to the standards set forth in WIPP's operating permit, requires confirmation/verification by physical techniques such as Non-Destructive Examination (NDE), Visual Examination (VE), and Non-Destructive Assay (NDA). These physical characterization techniques may vary in their appropriateness for a given waste stream; however, nothing will allow the substitution or exclusion of AK. Beyond the normal scope of operations, AK may be considered, when appropriate, a surrogate for the physical characterization techniques in a procedure that appeals to concepts such As Low As Reasonably Achievable (ALARA) and budgetary savings. This substitution is referred to as an Acceptable Knowledge Sufficiency Determination. With a Sufficiency Determination Request, AK may supplant the need for one or all of the physical analysis methods. This powerful procedure may be used on a scale as small as a single container to that of a vast waste stream. Only under the most stringent requirements will an AK Sufficiency Determination be approved by the regulators and, to date, only six such Sufficiency Determinations have been approved. Although Acceptable Knowledge is legislated into the operational procedures of the WIPP facility there is more to it than compliance. AK is not merely one of a long list of requirements in the characterization and verification of transuranic (TRU) waste destined for the WIPP. Acceptable Knowledge goes beyond the regulatory threshold by offering a way to reduce risk, cost, time, and uncertainty on its own laurels. Therefore, AK alone can be argued superior to any other waste characterization technique.« less

  20. Characterization and quantification of geochemical reaction rates in mine waste piles using unsaturated zone gases

    NASA Astrophysics Data System (ADS)

    Birkham, T.; Hendry, J.; Kirkland, R.; Bradley, S.; Mendoza, C.; Wassenaar, L.

    2003-04-01

    From 1997 to the present, we have installed and monitored 240 gas probes (maximum depth of 43 m) in unsaturated waste rock, overburden and tailings piles at a uranium mine in northern Saskatchewan, Canada and an oil sands mine in northern Alberta, Canada. Depth profiles of O2, CO2, N2 and CH4 pore-gas concentrations, temperature, and moisture content were measured in the field and used to characterize and quantifyin situ geochemical reaction rates. An innovative field-portable GC system has been developed to monitor pore-gas concentrations. At most sites, gas migration has been attributed to diffusion. At sites where advective transport may be important, subsurface total pressure measurements have been used to assess the contribution of advection to gas migration. The stable isotopes of molecular O2 (16O2 and 18O16O) and C in CO2 (12CO2 and 13CO2) have also been measured and modeled. At the uranium mine, the modelling of the O2, CO2, δ18OO2, and δ13CCO2 depth profiles was used to identify an alternative mechanism of O2 consumption and CO2 production in mine waste-rock piles. At the oil sands mine, a complex and unique system involving O2, CO2, and CH4 fluxes in the unsaturated zone and across the capillary fringe has been identified and is currently being modeled.

  1. Wastes as Aggregates, Binders or Additions in Mortars: Selecting Their Role Based on Characterization.

    PubMed

    Farinha, Catarina Brazão; de Brito, Jorge; Veiga, Rosário; Fernández, J M; Jiménez, J R; Esquinas, A R

    2018-03-20

    The production of waste has increased over the years and, lacking a recycle or recovery solution, it is forwarded to landfill. The incorporation of wastes in cement-based materials is a solution to reduce waste deposition. In this regard, some researchers have been studying the incorporation of wastes with different functions: aggregate, binder and addition. The incorporation of wastes should take advantage of their characteristics. It requires a judicious analysis of their particles. This research involves the analysis of seven industrial wastes: biomass ashes, glass fibre, reinforced polymer dust, sanitary ware, fluid catalytic cracking, acrylic fibre, textile fibre and glass fibre. The main characteristics and advantages of each waste are enunciated and the best type of introduction in mortars is discussed. The characterization of the wastes as particles is necessary to identify the most suitable incorporation in mortars. In this research, some wastes are studied with a view to their re-use or recycling in mortars. Thus, this research focuses on the chemical, physical and mechanical characterization of industrial wastes and identification of the potentially most advantageous type of incorporation.

  2. Wastes as Aggregates, Binders or Additions in Mortars: Selecting Their Role Based on Characterization

    PubMed Central

    de Brito, Jorge; Veiga, Rosário

    2018-01-01

    The production of waste has increased over the years and, lacking a recycle or recovery solution, it is forwarded to landfill. The incorporation of wastes in cement-based materials is a solution to reduce waste deposition. In this regard, some researchers have been studying the incorporation of wastes with different functions: aggregate, binder and addition. The incorporation of wastes should take advantage of their characteristics. It requires a judicious analysis of their particles. This research involves the analysis of seven industrial wastes: biomass ashes, glass fibre, reinforced polymer dust, sanitary ware, fluid catalytic cracking, acrylic fibre, textile fibre and glass fibre. The main characteristics and advantages of each waste are enunciated and the best type of introduction in mortars is discussed. The characterization of the wastes as particles is necessary to identify the most suitable incorporation in mortars. In this research, some wastes are studied with a view to their re-use or recycling in mortars. Thus, this research focuses on the chemical, physical and mechanical characterization of industrial wastes and identification of the potentially most advantageous type of incorporation. PMID:29558418

  3. 40 CFR 265.118 - Post-closure plan; amendment of plan.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... the wastes, application of advanced technology, or alternative disposal, treatment, or re-use.... 265.118 Section 265.118 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES (CONTINUED) INTERIM STATUS STANDARDS FOR OWNERS AND OPERATORS OF HAZARDOUS WASTE TREATMENT...

  4. Data summary of municipal solid waste management alternatives. Volume 4, Appendix B: RDF technologies

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    None

    1992-10-01

    This appendix contains background information, technical descriptions, economic data, mass and energy balances, and information on environmental releases for the refuse derived fuels (RDF) option in municipal solid waste management alternatives. Demonstration programs at St. Louis, Missouri; Franklin, Ohio; and Delaware are discussed. Information on pellet production and cofiring with coal is also presented.

  5. Land Application of Wastes: An Educational Program. Non-Crop and Forest Systems - Module 13, Objectives, and Script.

    ERIC Educational Resources Information Center

    Clarkson, W. W.; And Others

    This module discusses the characteristics of alternate sites and management schemes and attempts to evaluate the efficiency of each alternative in terms of waste treatment. Three types of non-crop land application are discussed: (1) forest lands; (2) park and recreational application; and (3) land reclamation in surface or strip mined areas. (BB)

  6. REVIEW OF ALTERNATIVE ENHANCED CHEMICAL CLEANING OPTIONS FOR SRS WASTE TANKS

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Hay, M.; Koopman, D.

    2009-08-01

    A literature review was conducted to support the Task Technical and Quality Assurance Plan for Alternative Enhanced Chemical Cleaning (AECC) for sludge heel removal funded as part of the EM-21 Engineering and Technology program. The goal was to identify potential technologies or enhancements to the baseline oxalic acid cleaning process for chemically dissolving or mobilizing Savannah River Site (SRS) sludge heels. The issues with the potentially large volume of oxalate solids generated from the baseline process have driven an effort to find an improved or enhanced chemical cleaning technology for the tank heels. This literature review builds on a previousmore » review conducted in 2003. A team was charged with evaluating the information in these reviews and developing recommendations of alternative technologies to pursue. The new information in this report supports the conclusion of the previous review that oxalic acid remains the chemical cleaning agent of choice for dissolving the metal oxides and hydroxides found in sludge heels in carbon steel tanks. The potential negative impact of large volumes of sodium oxalate on downstream processes indicates that the amount of oxalic acid used for chemical cleaning needs to be minimized as much as possible or the oxalic acid must be destroyed prior to pH adjustment in the receipt tank. The most straightforward way of minimizing the volume of oxalic acid needed for chemical cleaning is through more effective mechanical cleaning. Using a mineral acid to adjust the pH of the sludge prior to adding oxalic acid may also help to minimize the volume of oxalic acid used in chemical cleaning. If minimization of oxalic acid proves insufficient in reducing the volume of oxalate salts, several methods were found that could be used for oxalic acid destruction. For some waste tank heels, another acid or even caustic treatment (or pretreatment) might be more appropriate than the baseline oxalic acid cleaning process. Caustic treatment of high aluminum sludge heels may be appropriate as a means of reducing oxalic acid usage. Reagents other than oxalic acid may also be needed for removing actinide elements from the tank heels. A systems engineering evaluation (SEE) was performed on the various alternative chemical cleaning reagents and organic oxidation technologies discussed in the literature review. The objective of the evaluation was to develop a short list of chemical cleaning reagents and oxalic acid destruction methods that should be the focus of further research and development. The results of the SEE found that eight of the thirteen organic oxidation technologies scored relatively close together. Six of the chemical cleaning reagents were also recommended for further investigation. Based on the results of the SEE and plan set out in the TTQAP the following broad areas are recommended for future study as part of the AECC task: (1) Basic Chemistry of Sludge Dissolution in Oxalic Acid: A better understanding of the variables effecting dissolution of sludge species is needed to efficiently remove sludge heels while minimizing the use of oxalic acid or other chemical reagents. Tests should investigate the effects of pH, acid concentration, phase ratios, temperature, and kinetics of the dissolution reactions of sludge components with oxalic acid, mineral acids, and combinations of oxalic/mineral acids. Real waste sludge samples should be characterized to obtain additional data on the mineral phases present in sludge heels. (2) Simulant Development Program: Current sludge simulants developed by other programs for use in waste processing tests, while compositionally similar to real sludge waste, generally have more hydrated forms of the major metal phases and dissolve more easily in acids. Better simulants containing the mineral phases identified by real waste characterization should be developed to test chemical cleaning methods. (3) Oxalic Acid Oxidation Technologies: The two Mn based oxidation methods that scored highly in the SEE should be studied to evaluate long term potential. One of the AOP's (UV/O{sub 3}/Solids Separator) is currently being implemented by the SRS liquid waste organization for use in tank heel chemical cleaning. (4) Corrosion Issues: A program will be needed to address potential corrosion issues from the use of low molarity mineral acids and mixtures of oxalic/mineral acids in the waste tanks for short durations. The addition of corrosion inhibitors to the acids to reduce corrosion rates should be investigated.« less

  7. Integrated nonthermal treatment system study

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Biagi, C.; Bahar, D.; Teheranian, B.

    1997-01-01

    This report presents the results of a study of nonthermal treatment technologies. The study consisted of a systematic assessment of five nonthermal treatment alternatives. The treatment alternatives consist of widely varying technologies for safely destroying the hazardous organic components, reducing the volume, and preparing for final disposal of the contact-handled mixed low-level waste (MLLW) currently stored in the US Department of Energy complex. The alternatives considered were innovative nonthermal treatments for organic liquids and sludges, process residue, soil and debris. Vacuum desorption or various washing approaches are considered for treatment of soil, residue and debris. Organic destruction methods include mediatedmore » electrochemical oxidation, catalytic wet oxidation, and acid digestion. Other methods studied included stabilization technologies and mercury separation of treatment residues. This study is a companion to the integrated thermal treatment study which examined 19 alternatives for thermal treatment of MLLW waste. The quantities and physical and chemical compositions of the input waste are based on the inventory database developed by the US Department of Energy. The Integrated Nonthermal Treatment Systems (INTS) systems were evaluated using the same waste input (2,927 pounds per hour) as the Integrated Thermal Treatment Systems (ITTS). 48 refs., 68 figs., 37 tabs.« less

  8. Technoeconomic aspects of alternative municipal solid wastes treatment methods.

    PubMed

    Economopoulos, Alexander P

    2010-04-01

    This paper considers selected treatment technologies for comingled domestic and similar wastes and provides technoeconomic data and information, useful for the development of strategic management plans. For this purpose, treatment technologies of interest are reviewed and representative flow diagrams, along with material and energy balances, are presented for the typical composition of wastes in Greece; possible difficulties in the use of treatment products, along with their management implications, are discussed, and; cost functions are developed, allowing assessment of the initial capital investment and annual operating costs. Based on the latter, cost functions are developed for predicting the normalized treatment costs of alternative methods (in euro/t of MSW treated), as function of the quantity of MSW processed by plants built and operated (a) by municipality associations, and (b) by private enterprises. Finally, the alternative technologies considered are evaluated on the basis of their cost aspects, product utilization and compatibility with the EU waste framework Directive 2008/98. Copyright 2009 Elsevier Ltd. All rights reserved.

  9. Waste-based alternative adsorbents for the remediation of pharmaceutical contaminated waters: Has a step forward already been taken?

    PubMed

    Silva, Carla Patrícia; Jaria, Guilaine; Otero, Marta; Esteves, Valdemar I; Calisto, Vânia

    2018-02-01

    When adsorption is considered for water treatment, commercial activated carbon is usually the chosen adsorbent for the removal of pollutants from the aqueous phase, particularly pharmaceuticals. In order to decrease costs and save natural resources, attempts have been made to use wastes as raw materials for the production of alternative carbon adsorbents. This approach intends to increase efficiency, cost-effectiveness, and also to propose an alternative and sustainable way for the valorization/management of residues. This review aims to provide an overview on waste-based adsorbents used on pharmaceuticals' adsorption. Experimental facts related to the adsorption behaviour of each adsorbent/pharmaceutical pair and some key factors were addressed. Also, research gaps that subsist in this research area, as well as future needs, were identified. Simultaneously, this review aims to clarify the current status of the research on pharmaceuticals' adsorption by waste-based adsorbents in order to recognize if the right direction is being taken. Copyright © 2017 Elsevier Ltd. All rights reserved.

  10. 40 CFR 35.917-5 - Public participation.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... identification and evaluation of locations for waste water treatment facilities and of alternative treatment... treatment, reduce waste water volume, and encourage multiple use of facilities; (3) The evaluation of social... planning issues and decisions. (b) Basic Public Participation Program. Since waste water treatment...

  11. 10 CFR 60.18 - Review of site characterization activities. 2

    Code of Federal Regulations, 2011 CFR

    2011-01-01

    ... developed, and on the progress of waste form and waste package research and development. The semiannual... of site characterization will be established. Other topics related to site characterization shall...

  12. 10 CFR 60.18 - Review of site characterization activities. 2

    Code of Federal Regulations, 2012 CFR

    2012-01-01

    ... developed, and on the progress of waste form and waste package research and development. The semiannual... of site characterization will be established. Other topics related to site characterization shall...

  13. 10 CFR 60.18 - Review of site characterization activities. 2

    Code of Federal Regulations, 2013 CFR

    2013-01-01

    ... developed, and on the progress of waste form and waste package research and development. The semiannual... of site characterization will be established. Other topics related to site characterization shall...

  14. 10 CFR 60.18 - Review of site characterization activities. 2

    Code of Federal Regulations, 2014 CFR

    2014-01-01

    ... developed, and on the progress of waste form and waste package research and development. The semiannual... of site characterization will be established. Other topics related to site characterization shall...

  15. Uncertainty and the Conceptual Site Model

    NASA Astrophysics Data System (ADS)

    Price, V.; Nicholson, T. J.

    2007-12-01

    Our focus is on uncertainties in the underlying conceptual framework upon which all subsequent steps in numerical and/or analytical modeling efforts depend. Experienced environmental modelers recognize the value of selecting an optimal conceptual model from several competing site models, but usually do not formally explore possible alternative models, in part due to incomplete or missing site data, as well as relevant regional data for establishing boundary conditions. The value in and approach for developing alternative conceptual site models (CSM) is demonstrated by analysis of case histories. These studies are based on reported flow or transport modeling in which alternative site models are formulated using data that were not available to, or not used by, the original modelers. An important concept inherent to model abstraction of these alternative conceptual models is that it is "Far better an approximate answer to the right question, which is often vague, than the exact answer to the wrong question, which can always be made precise." (Tukey, 1962) The case histories discussed here illustrate the value of formulating alternative models and evaluating them using site-specific data: (1) Charleston Naval Site where seismic characterization data allowed significant revision of the CSM and subsequent contaminant transport modeling; (2) Hanford 300-Area where surface- and ground-water interactions affecting the unsaturated zone suggested an alternative component to the site model; (3) Savannah River C-Area where a characterization report for a waste site within the modeled area was not available to the modelers, but provided significant new information requiring changes to the underlying geologic and hydrogeologic CSM's used; (4) Amargosa Desert Research Site (ADRS) where re-interpretation of resistivity sounding data and water-level data suggested an alternative geologic model. Simple 2-D spreadsheet modeling of the ADRS with the revised CSM provided an improved match to vapor-phase tritium migration. Site-specific monitoring coupled to these alternative CSM's greatly assists in conducting uncertainty assessments. (Work supported by USNRC contract NRC-04-03-061.)

  16. U.S. Geological Survey research in radioactive waste disposal - Fiscal years 1986-1990

    USGS Publications Warehouse

    Trask, N.J.; Stevens, P.R.

    1991-01-01

    The report summarizes progress on geologic and hydrologic research related to the disposal of radioactive wastes. The research efforts are categorized according to whether they are related most directly to: (1) high-level wastes, (2) transuranic wastes, (3) low-level and mixed low-level and hazardous wastes, or (4) uranium mill tailings. Included is research applicable to the identification and geohydrologic characterization of waste-disposal sites, to investigations of specific sites where wastes have been stored, to development of techniques and methods for characterizing disposal sites, and to studies of geologic and hydrologic processes related to the transport and/or retention of waste radionuclides.

  17. 40 CFR 62.14570 - What must I do if I plan to permanently close my CISWI unit?

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... POLLUTANTS Federal Plan Requirements for Commercial and Industrial Solid Waste Incineration Units That... alternative waste treatment technology before you shut down your CISWI (1) Date when you will enter into a... evaluation of the option to transport your waste offsite to a commercial or municipal waste treatment and/or...

  18. 40 CFR 62.14570 - What must I do if I plan to permanently close my CISWI unit?

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... POLLUTANTS Federal Plan Requirements for Commercial and Industrial Solid Waste Incineration Units That... alternative waste treatment technology before you shut down your CISWI (1) Date when you will enter into a... evaluation of the option to transport your waste offsite to a commercial or municipal waste treatment and/or...

  19. Compatibility analysis of material and energy recovery in a regional solid waste management system.

    PubMed

    Chang, Ying-Hsi; Chang, Ni-Bin

    2003-01-01

    The rising prices of raw materials and concerns about energy conservation have resulted in an increasing interest in the simultaneous recovery of materials and energy from waste streams. Compatibility exists for several economic, environmental, and managerial reasons. Installing an on-site or off-site presorting facility before an incinerator could be a feasible alternative to achieve both goals if household recycling programs cannot succeed in local communities. However, the regional impacts of presorting solid waste on a waste-to-energy facility remain unclear because of the inherent complexity of solid waste compositions and properties over different areas. This paper applies a system-based approach to assess the impact of installing a refuse-derived fuel (RDF) process before an incinerator. Such an RDF process, consisting of standard unit operations of shredding, magnetic separation, trommel screening, and air classification, might be useful for integrating the recycling and presorting efforts for a large-scale municipal incinerator from a regional sense. An optimization modeling analysis is performed to characterize such integration potential so that the optimal size of the RDF process and associated shipping patterns for flow control can be foreseen. It aims at exploring how the waste inflows with different rates of generation, physical and chemical compositions, and heating values collected from differing administrative districts can be processed by either a centralized presorting facility or an incinerator to meet both the energy recovery and throughput requirements. A case study conducted in Taipei County, which is one of the most densely populated metropolitan areas in Taiwan, further confirms the application potential of such a cost-benefit analysis.

  20. Formation of PCDD and PCDF in the thermal treatment of footwear leather wastes.

    PubMed

    Godinho, Marcelo; Marcilio, Nilson Romeu; Masotti, Leonardo; Martins, Celso Brisolara; Ritter, Diego Elias; Wenzel, Bruno München

    2009-08-15

    The leather waste generated by the footwear industry is considered dangerous due to the presence of trivalent chromium, derived from the salt utilized to tan hides. In Brazil, the majority of this waste is disposed on landfills and only about 3% are recycled. The thermal treatment is an alternative method for purification of such residues. By using this technique it is possible to generate energy and recover the chromium present in the ash for the production of basic chromium sulfate (tanning industry), high carbon ferrochromium or carbon-free ferrochromium (steel industry). In the last 10 years, the gasification and combustion of footwear leather waste have been intensively studied at the Federal University of Rio Grande do Sul. The research experiment for characterization of the emissions of polychlorinated dibenzo-p-dioxins and dibenzofurans (PCDD/F) were carried out in a semi-pilot unit (350 kW(th)). From new investments the thermal capacity of the unit will increase to 600 kW(th). The unit will produce power from the heat generated in the combustion. The experimental results indicated that during the thermal treatment of footwear leather wastes, the formation mechanism of PCDD/F is the de novo synthesis. Most of PCDD/F were found in the particulate phase (>95%). A kinetic model was used for discussion of the achieved experimental results. The model is based in the carbon gasification, PCDD/F formation, desorption and degradation. From the conclusions obtained in this work will be possible minimize the PCDD/F formation in process of combustion of footwear leather wastes.

  1. Waste certification program plan for Oak Ridge National Laboratory. Revision 1

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Orrin, R.C.

    1997-05-01

    This document defines the waste certification program developed for implementation at Oak Ridge National Laboratory (ORNL). The document describes the program structure, logic, and methodology for certification of ORNL wastes. The purpose of the waste certification program is to provide assurance that wastes are properly characterized and that the Waste Acceptance Criteria (WAC) for receiving facilities are met. The program meets the waste certification requirements outlined in US Department of Energy (DOE) Order 5820.2A, Radioactive Waste Management, and ensures that 40 CFR documentation requirements for waste characterization are met for mixed (both radioactive and hazardous) and hazardous (including polychlorinated biphenyls)more » waste. Program activities will be conducted according to ORNL Level 1 document requirements.« less

  2. Using liquid waste streams as the moisture source during the hydrothermal carbonization of municipal solid wastes.

    PubMed

    Li, Liang; Hale, McKenzie; Olsen, Petra; Berge, Nicole D

    2014-11-01

    Hydrothermal carbonization (HTC) is a thermal conversion process that can be an environmentally beneficial approach for the conversion of municipal solid wastes to value-added products. The influence of using activated sludge and landfill leachate as initial moisture sources during the carbonization of paper, food waste and yard waste over time at 250°C was evaluated. Results from batch experiments indicate that the use of activated sludge and landfill leachate are acceptable alternative supplemental liquid sources, ultimately imparting minimal impact on carbonization product characteristics and yields. Regression results indicate that the initial carbon content of the feedstock is more influential than any of the characteristics of the initial liquid source and is statistically significant when describing the relationship associated with all evaluated carbonization products. Initial liquid-phase characteristics are only statistically significant when describing the solids energy content and the mass of carbon in the gas-phase. The use of these alternative liquid sources has the potential to greatly increase the sustainability of the carbonization process. A life cycle assessment is required to quantify the benefits associated with using these alternative liquid sources. Copyright © 2014 Elsevier Ltd. All rights reserved.

  3. Assessing recycling versus incineration of key materials in municipal waste: The importance of efficient energy recovery and transport distances

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Merrild, Hanna; Larsen, Anna W., E-mail: awla@env.dtu.dk; Christensen, Thomas H.

    Highlights: Black-Right-Pointing-Pointer We model the environmental impact of recycling and incineration of household waste. Black-Right-Pointing-Pointer Recycling of paper, glass, steel and aluminium is better than incineration. Black-Right-Pointing-Pointer Recycling and incineration of cardboard and plastic can be equally good alternatives. Black-Right-Pointing-Pointer Recyclables can be transported long distances and still have environmental benefits. Black-Right-Pointing-Pointer Paper has a higher environmental benefit than recyclables found in smaller amounts. - Abstract: Recycling of materials from municipal solid waste is commonly considered to be superior to any other waste treatment alternative. For the material fractions with a significant energy content this might not be the casemore » if the treatment alternative is a waste-to-energy plant with high energy recovery rates. The environmental impacts from recycling and from incineration of six material fractions in household waste have been compared through life cycle assessment assuming high-performance technologies for material recycling as well as for waste incineration. The results showed that there are environmental benefits when recycling paper, glass, steel and aluminium instead of incinerating it. For cardboard and plastic the results were more unclear, depending on the level of energy recovery at the incineration plant, the system boundaries chosen and which impact category was in focus. Further, the environmental impact potentials from collection, pre-treatment and transport was compared to the environmental benefit from recycling and this showed that with the right means of transport, recyclables can in most cases be transported long distances. However, the results also showed that recycling of some of the material fractions can only contribute marginally in improving the overall waste management system taking into consideration their limited content in average Danish household waste.« less

  4. A Nuclear Waste Management Cost Model for Policy Analysis

    NASA Astrophysics Data System (ADS)

    Barron, R. W.; Hill, M. C.

    2017-12-01

    Although integrated assessments of climate change policy have frequently identified nuclear energy as a promising alternative to fossil fuels, these studies have often treated nuclear waste disposal very simply. Simple assumptions about nuclear waste are problematic because they may not be adequate to capture relevant costs and uncertainties, which could result in suboptimal policy choices. Modeling nuclear waste management costs is a cross-disciplinary, multi-scale problem that involves economic, geologic and environmental processes that operate at vastly different temporal scales. Similarly, the climate-related costs and benefits of nuclear energy are dependent on environmental sensitivity to CO2 emissions and radiation, nuclear energy's ability to offset carbon emissions, and the risk of nuclear accidents, factors which are all deeply uncertain. Alternative value systems further complicate the problem by suggesting different approaches to valuing intergenerational impacts. Effective policy assessment of nuclear energy requires an integrated approach to modeling nuclear waste management that (1) bridges disciplinary and temporal gaps, (2) supports an iterative, adaptive process that responds to evolving understandings of uncertainties, and (3) supports a broad range of value systems. This work develops the Nuclear Waste Management Cost Model (NWMCM). NWMCM provides a flexible framework for evaluating the cost of nuclear waste management across a range of technology pathways and value systems. We illustrate how NWMCM can support policy analysis by estimating how different nuclear waste disposal scenarios developed using the NWMCM framework affect the results of a recent integrated assessment study of alternative energy futures and their effects on the cost of achieving carbon abatement targets. Results suggest that the optimism reflected in previous works is fragile: Plausible nuclear waste management costs and discount rates appropriate for intergenerational cost-benefit analysis produce many scenarios where nuclear energy is economically unattractive.

  5. Acceptable knowledge document for INEEL stored transuranic waste -- Rocky Flats Plant waste. Revision 2

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    NONE

    1998-01-23

    This document and supporting documentation provide a consistent, defensible, and auditable record of acceptable knowledge for waste generated at the Rocky Flats Plant which is currently in the accessible storage inventory at the Idaho National Engineering and Environmental Laboratory. The inventory consists of transuranic (TRU) waste generated from 1972 through 1989. Regulations authorize waste generators and treatment, storage, and disposal facilities to use acceptable knowledge in appropriate circumstances to make hazardous waste determinations. Acceptable knowledge includes information relating to plant history, process operations, and waste management, in addition to waste-specific data generated prior to the effective date of the RCRAmore » regulations. This document is organized to provide the reader a comprehensive presentation of the TRU waste inventory ranging from descriptions of the historical plant operations that generated and managed the waste to specific information about the composition of each waste group. Section 2 lists the requirements that dictate and direct TRU waste characterization and authorize the use of the acceptable knowledge approach. In addition to defining the TRU waste inventory, Section 3 summarizes the historical operations, waste management, characterization, and certification activities associated with the inventory. Sections 5.0 through 26.0 describe the waste groups in the inventory including waste generation, waste packaging, and waste characterization. This document includes an expanded discussion for each waste group of potential radionuclide contaminants, in addition to other physical properties and interferences that could potentially impact radioassay systems.« less

  6. Characterization of Class A low-level radioactive waste 1986--1990. Volume 6: Appendices G--J

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Dehmel, J.C.; Loomis, D.; Mauro, J.

    1994-01-01

    Under contract to the US Nuclear Regulatory Commission, Office of Nuclear Regulatory Research, the firms of S. Cohen & Associates, Inc. (SC&A) and Eastern Research Group (ERG) have compiled a report that describes the physical, chemical, and radiological properties of Class-A low-level radioactive waste. The report also presents information characterizing various methods and facilities used to treat and dispose non-radioactive waste. A database management program was developed for use in accessing, sorting, analyzing, and displaying the electronic data provided by EG&G. The program was used to present and aggregate data characterizing the radiological, physical, and chemical properties of the wastemore » from descriptions contained in shipping manifests. The data thus retrieved are summarized in tables, histograms, and cumulative distribution curves presenting radionuclide concentration distributions in Class-A waste as a function of waste streams, by category of waste generators, and regions of the United States. The report also provides information characterizing methods and facilities used to treat and dispose non-radioactive waste, including industrial, municipal, and hazardous waste regulated under Subparts C and D of the Resource Conservation and Recovery Act (RCRA). The information includes a list of disposal options, the geographical locations of the processing and disposal facilities, and a description of the characteristics of such processing and disposal facilities. Volume 1 contains the Executive Summary, Volume 2 presents the Class-A waste database, Volume 3 presents the information characterizing non-radioactive waste management practices and facilities, and Volumes 4 through 7 contain Appendices A through P with supporting information.« less

  7. Comparing Waste-to-Energy technologies by applying energy system analysis.

    PubMed

    Münster, Marie; Lund, Henrik

    2010-07-01

    Even when policies of waste prevention, re-use and recycling are prioritised, a fraction of waste will still be left which can be used for energy recovery. This article asks the question: How to utilise waste for energy in the best way seen from an energy system perspective? Eight different Waste-to-Energy technologies are compared with a focus on fuel efficiency, CO(2) reductions and costs. The comparison is carried out by conducting detailed energy system analyses of the present as well as a potential future Danish energy system with a large share of combined heat and power as well as wind power. The study shows potential of using waste for the production of transport fuels. Biogas and thermal gasification technologies are hence interesting alternatives to waste incineration and it is recommended to support the use of biogas based on manure and organic waste. It is also recommended to support research into gasification of waste without the addition of coal and biomass. Together the two solutions may contribute to alternate use of one third of the waste which is currently incinerated. The remaining fractions should still be incinerated with priority to combined heat and power plants with high electric efficiency. Copyright (c) 2009 Elsevier Ltd. All rights reserved.

  8. EVALUATION OF RISKS AND WASTE CHARACTERIZATION REQUIREMENTS FOR THE TRANSURANIC WASTE EMPLACED IN WIPP DURING 1999

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Channell, J.K.; Walker, B.A.

    2000-05-01

    Specifically this report: 1. Compares requirements of the WAP that are pertinent from a technical viewpoint with the WIPP pre-Permit waste characterization program, 2. Presents the results of a risk analysis of the currently emplaced wastes. Expected and bounding risks from routine operations and possible accidents are evaluated; and 3. Provides conclusions and recommendations.

  9. Development of the Use of Alternative Cements for the Treatment of Intermediate Level Waste

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Hayes, M.; Godfrey, I.H.

    2007-07-01

    This paper describes initial development studies undertaken to investigate the potential use of alternative, non ordinary Portland cement (OPC) based encapsulation matrices to treat historic legacy wastes within the UK's Intermediate Level Waste (ILW) inventory. Currently these wastes are encapsulated in composite OPC cement systems based on high replacement with blast furnace slag of pulverised fuel ash. However, the high alkalinity of these cements can lead to high corrosion rates with reactive metals found in some wastes releasing hydrogen and forming expansive corrosion products. This paper therefore details preliminary results from studies on two commercial products, calcium sulfo-aluminate (CSA) andmore » magnesium phosphate (MP) cement which react with a different hydration chemistry, and which may allow wastes containing these metals to be encapsulated with lower reactivity. The results indicate that grouts can be formulated from both cements over a range of water contents and reactant ratios that have significantly improved fluidity in comparison to typical OPC cements. All designed mixes set in 24 hours with zero bleed and the pH values in the plastic state were in the range 10-11 for CSA and 5-7 for MP cements. In addition, a marked reduction in aluminium corrosion rate has been observed in both types of cements compared to a composite OPC system. These results therefore provide encouragement that both cement types can provide a possible alternative to OPC in the immobilisation of reactive wastes, however further investigation is needed. (authors)« less

  10. Review of comparative LCAs of food waste management systems - Current status and potential improvements

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Bernstad, A., E-mail: anna.bernstad@chemeng.lth.se; Cour Jansen, J. la

    2012-12-15

    Highlights: Black-Right-Pointing-Pointer GHG-emissions from different treatment alternatives vary largely in 25 reviewed comparative LCAs of bio-waste management. Black-Right-Pointing-Pointer System-boundary settings often vary largely in reviewed studies. Black-Right-Pointing-Pointer Existing LCA guidelines give varying recommendations in relation to several key issues. - Abstract: Twenty-five comparative cycle assessments (LCAs) addressing food waste treatment were reviewed, including the treatment alternatives landfill, thermal treatment, compost (small and large scale) and anaerobic digestion. The global warming potential related to these treatment alternatives varies largely amongst the studies. Large differences in relation to setting of system boundaries, methodological choices and variations in used input data were seenmore » between the studies. Also, a number of internal contradictions were identified, many times resulting in biased comparisons between alternatives. Thus, noticed differences in global warming potential are not found to be a result of actual differences in the environmental impacts from studied systems, but rather to differences in the performance of the study. A number of key issues with high impact on the overall global warming potential from different treatment alternatives for food waste were identified through the use of one-way sensitivity analyses in relation to a previously performed LCA of food waste management. Assumptions related to characteristics in treated waste, losses and emissions of carbon, nutrients and other compounds during the collection, storage and pretreatment, potential energy recovery through combustion, emissions from composting, emissions from storage and land use of bio-fertilizers and chemical fertilizers and eco-profiles of substituted goods were all identified as highly relevant for the outcomes of this type of comparisons. As the use of LCA in this area is likely to increase in coming years, it is highly relevant to establish more detailed guidelines within this field in order to increase both the general quality in assessments as well as the potentials for cross-study comparisons.« less

  11. Toxic Overload: The Waste Disposal Dilemma.

    ERIC Educational Resources Information Center

    Knox, Robert J.

    1991-01-01

    The role of the Environmental Protection Agency as ombudsman concerning waste disposal is examined with respect to both the current options of source reduction and recycling as pollution prevention, and alternative approaches that expand upon these current options, particularly with respect to toxic and medical waste. (JJK)

  12. 40 CFR 35.918 - Individual systems.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... localized treatment and disposal of wastewater with minimal or no conveyance of untreated waste water... plant. (5) Alternative waste water treatment works. A waste water conveyance and/or treatment system... STATE AND LOCAL ASSISTANCE Grants for Construction of Treatment Works-Clean Water Act § 35.918...

  13. Sustainable construction in rural Guatemala.

    PubMed

    Temple, Ericka K; Rose, Elizabeth

    2011-11-01

    Waste management is a significant problem in Guatemala, as elsewhere in the developing world. The inappropriate disposal of solid waste produces pollution and places the environment and human health at risk. Environmental risk factors, including inadequate disposal of solid waste, are implicated in 25-30% of disease worldwide with children bearing a disproportionate burden of those diseases. Therefore, economic development which reduces inappropriate disposal of waste and affords economic opportunities may help reduce the global burden of disease on children. In the indigenous highlands of central Guatemala, a community supported non-profit organisation called Long Way Home (http://www.longwayhomeinc.org) is employing alternative construction techniques to build a vocational school complex. The construction of the school from waste materials demonstrates the use and principles of re-purposing materials, helps clean the environment and affords further educational and vocational opportunities. This article will outline the health problems inherent in an indigenous area of a developing country and will offer an alternative solution to reverse environmental risk factors associated with solid waste pollution and also actively improve child health.

  14. Partial replacement of non renewable fossil fuels energy by the use of waste materials as alternative fuels

    NASA Astrophysics Data System (ADS)

    Indrawati, V.; Manaf, A.; Purwadi, G.

    2009-09-01

    This paper reports recent investigations on the use of biomass like rice husk, palm kernel shell, saw dust and municipal waste to reduce the use of fossil fuels energy in the cement production. Such waste materials have heat values in the range approximately from 2,000 to 4,000 kcal/kg. These are comparable to the average value of 5800 kcal/kg from fossil materials like coals which are widely applied in many industrial processing. Hence, such waste materials could be used as alternative fuels replacing the fossil one. It is shown that replacement of coals with such waste materials has a significant impact on cost effectiveness as well as sustainable development. Variation in moisture content of the waste materials, however should be taken into account because this is one of the parameter that could not be controlled. During fuel combustion, some amount of the total energy is used to evaporate the water content and thus the net effective heat value is less.

  15. Idaho National Engineering Laboratory code assessment of the Rocky Flats transuranic waste

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    NONE

    1995-07-01

    This report is an assessment of the content codes associated with transuranic waste shipped from the Rocky Flats Plant in Golden, Colorado, to INEL. The primary objective of this document is to characterize and describe the transuranic wastes shipped to INEL from Rocky Flats by item description code (IDC). This information will aid INEL in determining if the waste meets the waste acceptance criteria (WAC) of the Waste Isolation Pilot Plant (WIPP). The waste covered by this content code assessment was shipped from Rocky Flats between 1985 and 1989. These years coincide with the dates for information available in themore » Rocky Flats Solid Waste Information Management System (SWIMS). The majority of waste shipped during this time was certified to the existing WIPP WAC. This waste is referred to as precertified waste. Reassessment of these precertified waste containers is necessary because of changes in the WIPP WAC. To accomplish this assessment, the analytical and process knowledge available on the various IDCs used at Rocky Flats were evaluated. Rocky Flats sources for this information include employee interviews, SWIMS, Transuranic Waste Certification Program, Transuranic Waste Inspection Procedure, Backlog Waste Baseline Books, WIPP Experimental Waste Characterization Program (headspace analysis), and other related documents, procedures, and programs. Summaries are provided of: (a) certification information, (b) waste description, (c) generation source, (d) recovery method, (e) waste packaging and handling information, (f) container preparation information, (g) assay information, (h) inspection information, (i) analytical data, and (j) RCRA characterization.« less

  16. Alternative methods of salt disposal at the seven salt sites for a nuclear waste repository

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Not Available

    1987-02-01

    This study discusses the various alternative salt management techniques for the disposal of excess mined salt at seven potentially acceptable nuclear waste repository sites: Deaf Smith and Swisher Counties, Texas; Richton and Cypress Creek Domes, Mississippi; Vacherie Dome, Louisiana; and Davis and Lavender Canyons, Utah. Because the repository development involves the underground excavation of corridors and waste emplacement rooms, in either bedded or domed salt formations, excess salt will be mined and must be disposed of offsite. The salt disposal alternatives examined for all the sites include commercial use, ocean disposal, deep well injection, landfill disposal, and underground mine disposal.more » These alternatives (and other site-specific disposal methods) are reviewed, using estimated amounts of excavated, backfilled, and excess salt. Methods of transporting the excess salt are discussed, along with possible impacts of each disposal method and potential regulatory requirements. A preferred method of disposal is recommended for each potentially acceptable repository site. 14 refs., 5 tabs.« less

  17. Removal or storage of environmental pollutants and alternative fuel sources with inorganic adsorbents via host–guest encapsulation

    DOE PAGES

    Cramer, Alisha J.; Cole, Jacqueline M.

    2017-05-08

    The ever-increasing demands of the modern world continue to place substantial strain on the environment. To help alleviate the damage done to the natural world, the encapsulation of small molecules or ions (guests) into porous inorganic structural frameworks (hosts) provides a potential remedy for some of the environmental concerns facing us today. These concerns include the removal of harmful pollutants from water or air, the safe entrapment of nuclear waste materials, or the purification and storage of small molecules that act as alternative fuel sources. For this study, we review the trends in using inorganic materials as hostmedia for themore » removal or storage of various wastes and alternative fuels. In conclusion, we cover the treatment of water contaminated with dyes or heavy metals, air pollution alleviation via CO 2, SO x, NO x, and volatile organic compound containment, nuclear waste immobilization, and storage for H 2 and methane as alternative fuels.« less

  18. Characterization of the solid low level mixed waste inventory for the solid waste thermal treatment activity - III

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Place, B.G., Westinghouse Hanford

    1996-09-24

    The existing thermally treatable, radioactive mixed waste inventory is characterized to support implementation of the commercial, 1214 thermal treatment contract. The existing thermally treatable waste inventory has been identified using a decision matrix developed by Josephson et al. (1996). Similar to earlier waste characterization reports (Place 1993 and 1994), hazardous materials, radionuclides, physical properties, and waste container data are statistically analyzed. In addition, the waste inventory data is analyzed to correlate waste constituent data that are important to the implementation of the commercial thermal treatment contract for obtaining permits and for process design. The specific waste parameters, which were analyzed,more » include the following: ``dose equivalent`` curie content, polychlorinated biphenyl (PCB) content, identification of containers with PA-related mobile radionuclides (14C, 12 79Se, 99Tc, and U isotopes), tritium content, debris and non-debris content, container free liquid content, fissile isotope content, identification of dangerous waste codes, asbestos containers, high mercury containers, beryllium dust containers, lead containers, overall waste quantities, analysis of container types, and an estimate of the waste compositional split based on the thermal treatment contractor`s proposed process. A qualitative description of the thermally treatable mixed waste inventory is also provided.« less

  19. Utilizing TEMPO surface estimates to determine changes in emissions, community exposure and environmental impacts from cement kilns across North America using alternative fuels

    NASA Astrophysics Data System (ADS)

    Pegg, M. J.; Gibson, M. D.; Asamany, E.

    2015-12-01

    A major problem faced by all North American (NA) Governments is managing solid waste from residential and non-residential sources. One way to mitigate the need to expand landfill sites across NA is waste diversion for use as alternative fuel in industries such as cement manufacture. Currently, waste plastic, tires, waste shingles and other high carbon content waste destined for landfill are being explored, or currently used, as an alternative supplemental fuels for use in cement kilns across NA. While this is an attractive, environmentally sustainable solution, significant knowledge gaps remain in our fundamental understanding of whether these alternative fuels may lead to increased air pollution emissions from cement kilns across NA. The long-term objective of using TEMPO is to advance fundamental understanding of uncharacterized air pollution emissions and to assess the actual or potential environmental and health impacts of these emissions from cement kilns across NA. TEMPO measurements will be made in concert with in-situ observations augmented by air dispersion, land-use regression and receptor modelling. This application of TEMPO follows on from current research on a series of bench scale and pilot studies for Lafarge Canada Inc., that investigated the change in combustion emissions from various mixtures of coal (C), petroleum coke (PC) and non-recyclable alternative fuels. From our work we demonstrated that using an alternative fuel mixture in a cement kiln has potential to reduce emissions of CO2 by 34%; reduce NOx by 80%, and reduce fuel SO2 emissions by 98%. We also provided evidence that there would be a significant reduction in the formation of secondary ground-level ozone (O3) and secondary PM2.5 in downwind stack plumes if alternative waste derived fuels are used. The application of air dispersion, source apportionment, land use regression; together with remote sensing offers a powerful set of tools with the potential to improve air pollution community exposure research in NA. The application of the new NASA TEMPO satellite to track the dispersion of SO2, PM2.5 and NO2 in plumes and secondary O3 and aerosol formation downwind of cement kilns opens up an exciting new avenue of air pollution research in NA.

  20. Utilization of agricultural and forest industry waste and residues in natural fiber-polymer composites: A review.

    PubMed

    Väisänen, Taneli; Haapala, Antti; Lappalainen, Reijo; Tomppo, Laura

    2016-08-01

    Natural fiber-polymer composites (NFPCs) are becoming increasingly utilized in a wide variety of applications because they represent an ecological and inexpensive alternative to conventional petroleum-derived materials. On the other hand, considerable amounts of organic waste and residues from the industrial and agricultural processes are still underutilized as low-value energy sources. Organic materials are commonly disposed of or subjected to the traditional waste management methods, such as landfilling, composting or anaerobic digestion. The use of organic waste and residue materials in NFPCs represents an ecologically friendly and a substantially higher value alternative. This is a comprehensive review examining how organic waste and residues could be utilized in the future as reinforcements or additives for NFPCs from the perspective of the recently reported work in this field. Copyright © 2016 Elsevier Ltd. All rights reserved.

  1. Solid waste characterization in Ketao, a rural town in Togo, West Africa.

    PubMed

    Edjabou, Maklawe Essonanawe; Møller, Jacob; Christensen, Thomas H

    2012-07-01

    In Africa the majority of solid waste data is for big cities. Small and rural towns are generally neglected and waste data from these areas are often unavailable, which makes planning a proper solid waste management difficult. This paper presents the results from two waste characterization projects conducted in Kétao, a rural town in Togo during the rainy season and the dry season in 2010. The seasonal variation has a significant impact on the waste stream. The household waste generation rate was estimated at 0.22 kg person(-1) day(-1) in the dry season and 0.42 in the rainy season. Likewise, the waste moisture content was 4% in the dry season while it was 33-63% in the rainy season. The waste consisted mainly of soil and dirt characterized as 'other' (41%), vegetables and putrescibles (38%) and plastic (11%). In addition to these fractions, considerable amounts of material are either recycled or reused locally and do not enter the waste stream. The study suggests that additional recycling is not feasible, but further examination of the degradability of the organic fraction is needed in order to assess whether the residual waste should be composed or landfilled.

  2. Vermi composting--organic waste management and disposal.

    PubMed

    Kumar, J Sudhir; Subbaiah, K Venkata; Rao, P V V Prasada

    2012-01-01

    Solid waste is an unwanted byproduct of modern civilization. Landfills are the most common means of solid waste disposal. But the increasing amount of solid waste is rapidly filling existing landfills, and new sites are difficult to establish. Alternatives to landfills include the use of source reduction, recycling, composting and incineration, as well as use of landfills. Incineration is most economical if it includes energy recovery from the waste. Energy can be recovered directly from waste by incineration or the waste can be processed to produce storable refuse derived fuel (RDF). Information on the composition of solid wastes is important in evaluating alternative equipment needs, systems, management programs and plans. Pulverization of municipal solid waste is done and the pulverized solid waste is dressed to form a bed and the bed is fed by earthworms which convert the bed into vermi compost. The obtained vermi compost is sent to Ministry of Environment & Forests (MoEF) recognized lab for estimating the major nutrients, i.e. Potassium (K), Phosphorous (P), Nitrogen (N) and Micro-nutrient values. It is estimated that 59 - 65 tons of wet waste can be collected in a town per day and if this wet waste is converted to quality compost, around 12.30 tons of vermi compost can be generated. If a Municipal Corporation manages this wet waste an income of over (see text symbol) for 0.8 9 crore per anum can be earned which is a considerable amount for providing of better services to public.

  3. 40 CFR 270.230 - May I perform remediation waste management activities under a RAP at a location removed from the...

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... assumed to be in compliance with this requirement. (e) These alternative locations are remediation waste... 40 Protection of Environment 27 2011-07-01 2011-07-01 false May I perform remediation waste management activities under a RAP at a location removed from the area where the remediation wastes originated...

  4. 40 CFR 270.230 - May I perform remediation waste management activities under a RAP at a location removed from the...

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... assumed to be in compliance with this requirement. (e) These alternative locations are remediation waste... 40 Protection of Environment 27 2014-07-01 2014-07-01 false May I perform remediation waste management activities under a RAP at a location removed from the area where the remediation wastes originated...

  5. Comparison of different target material options for the European Spallation Source based on certain aspects related to the final disposal

    NASA Astrophysics Data System (ADS)

    Kókai, Zsófia; Török, Szabina; Zagyvai, Péter; Kiselev, Daniela; Moormann, Rainer; Börcsök, Endre; Zanini, Luca; Takibayev, Alan; Muhrer, Günter; Bevilacqua, Riccardo; Janik, József

    2018-02-01

    Different target options have been examined for the European Spallation Source, which is under construction in Lund, Sweden. During the design update phase, parameters and characteristics for the target design have been optimized not only for neutronics but also with respect to the waste characteristics related to the final disposal of the target. A rotating, solid tungsten target was eventually selected as baseline concept; the other options considered included mercury and lead-bismuth (LBE) targets suitable for a pulsed source. Since the licensee is obliged to present a decommissioning plan even before the construction phase starts, the radioactive waste category of the target after full operation time is of crucial importance. The results obtained from a small survey among project partners of 7th Framework Program granted by EU 202247 contract have been used. Waste characteristics of different potential spallation target materials were compared. Based on waste index, the tungsten target is the best alternative and the second one is the mercury target. However, all alternatives have HLW category after a 10 year cooling. Based on heat generation alone all of the options would be below the HLW limit after this cooling period. The LBE is the least advantageous alternative based on waste index and heat generation comparison. These results can be useful in compiling the licensing documents of the ESS facility as the target alternatives can be compared from various aspects related to their disposal.

  6. Microbiological Safety of Animal Wastes Processed by Physical Heat Treatment: An Alternative To Eliminate Human Pathogens in Biological Soil Amendments as Recommended by the Food Safety Modernization Act.

    PubMed

    Chen, Zhao; Jiang, Xiuping

    2017-03-01

    Animal wastes have high nutritional value as biological soil amendments of animal origin for plant cultivation in sustainable agriculture; however, they can be sources of some human pathogens. Although composting is an effective way to reduce pathogen levels in animal wastes, pathogens may still survive under certain conditions and persist in the composted products, which potentially could lead to fresh produce contamination. According to the U.S. Food and Drug Administration Food Safety Modernization Act, alternative treatments are recommended for reducing or eliminating human pathogens in raw animal manure. Physical heat treatments can be considered an effective method to inactivate pathogens in animal wastes. However, microbial inactivation in animal wastes can be affected by many factors, such as composition of animal wastes, type and physiological stage of the tested microorganism, and heat source. Following some current processing guidelines for physical heat treatments may not be adequate for completely eliminating pathogens from animal wastes. Therefore, this article primarily reviews the microbiological safety and economic value of physically heat-treated animal wastes as biological soil amendments.

  7. Biogas production from livestock waste anaerobic digesters: evaluation and optimization

    USDA-ARS?s Scientific Manuscript database

    Livestock wastes can serve as the feedstock for biogas production (mainly methane) that could be used as alternative energy source. The green energy derived from animal wastes is considered to be carbon neutral and offsetting those generated from fossil fuels. However, feedstocks from livestock re...

  8. GUIDE TO TREATMENT TECHNOLOGIES FOR HAZARDOUS WASTES AT SUPERFUND SITES

    EPA Science Inventory

    Over the past fewyears, it has become increasinsly evident that land disposal of hazardous wastes is at least only a temporary solution for much of the wastes present at Superfund sites. The need for more Iong-term, permanent "treatment solutions as alternatives to land disposal ...

  9. Waste: A Hidden Resource.

    ERIC Educational Resources Information Center

    Keep America Beautiful, Inc., New York, NY.

    Corporations, government agencies, communities, and individuals are involved in waste management. Education about waste--where it comes from, how we dispose of it, and management alternatives--is needed. This document provides a series of educational resources which deal with these issues. Using these factsheets, lesson plans, lists of sources for…

  10. Tank characterization report for single-shell tank 241-C-109

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Simpson, B.C.

    1997-05-23

    One of the major functions of the Tank Waste Remediation System (TWRS) is to characterize wastes in support of waste management and disposal activities at the Hanford Site. Analytical data from sampling and analysis, along with other available information about a tank, are compiled and maintained in a tank characterization report (TCR). This report and its appendices serve as the TCR for single-shell tank 241-C-109. The objectives of this report are: (1) to use characterization data in response to technical issues associated with tank 241 C-109 waste; and (2) to provide a standard characterization of this waste in terms ofmore » a best-basis inventory estimate. The response to technical issues is summarized in Section 2.0, and the best-basis inventory estimate is presented in Section 3.0. Recommendations regarding safety status and additional sampling needs are provided in Section 4.0. Supporting data and information are contained in the appendices.« less

  11. [Cultivation of a permanent fish cell line in serum-free media special experiences with a cytotoxicity test for waste water samples

    PubMed

    Kohlpoth, Martin; Rusche, Brigitte

    1997-01-01

    The use of fetal calf serum (FCS) as standard medium additive for the cell cultivation must be regarded critically from the point of view of animal welfare as well as for scientific reasons and makes it necessary to look for alternatives. In the last years an in vitro cytotoxicity assay for the testing of industrial waste waters with the permanent fish cell line RTG-2 was established and pre-validated as an alternative to the fish test with the golden orfe. The application of FCS is also a special problem with regard to the testing of waste waters in a cytotoxicity test so that FCS-alternatives were tested. The RTG-2 cells were successfully adapted to the two solvents Basal Medium Supplement (BMS) and Ultroser-G (U-G) that are used to replace serum. The characterisation of these adapted cell lines showed no significant differences in growth rate, adhesion rate, viability and sensitivity to chemicals in comparison to the original RTG-2 cells. On the determination of the cytotoxicity of industrial waste waters the RTG-2 cells adapted to the BMS medium indicated a clearly higher toxicity of the waste water samples than the original RTG-2 cells. This result confirms the thesis that serum components react with waste water elements and thus change the bio-availability of toxic compounds.

  12. Characterization of Leachate at Simpang Renggam Landfill Site, Johor, Malaysia

    NASA Astrophysics Data System (ADS)

    Zailani, L. W. M.; Amdan, N. S. M.; Zin, N. S. M.

    2018-04-01

    Nowadays, the world facing a major problem in managed solid waste due to the increasing of solid waste. Malaysia, one of the country also involves in this matter which is 296 landfills are open to overcome this problem. Currently, the best alternative option to manage solid waste is by using landfilling method because it has low costing advantages. The disadvantage of landfill method, it might cause a pollution by producing leachate that will give an effect to the ground and surface water resources. This study focuses on analysing the leachate composition at Simpang Renggam Landfill(SRL) site for seven parameters such as COD, BOD, SS, turbidity, pH, BOD5/COD, and ammonia (NH3-N). All the data obtained were compared with previous researcher and Malaysia Environmental Quality Act 1974. From the result, SRL site was categorized as partially stabilized leachate with the parameter of BOD5/COD > 0.1. The SRL site is recommended to use a physical-chemical method for a better treatment because the leachate composition is classified as old leachate and aerated lagoon method are not satisfied to be used in treating the aging leachate at SRL site.

  13. Recovery of MSWI and soil washing residues as concrete aggregates.

    PubMed

    Sorlini, Sabrina; Abbà, Alessandro; Collivignarelli, Carlo

    2011-02-01

    The aim of the present work was to study if municipal solid waste incinerator (MSWI) residues and aggregates derived from contaminated soil washing could be used as alternative aggregates for concrete production. Initially, chemical, physical and geometric characteristics (according to UNI EN 12620) of municipal solid waste incineration bottom ashes and some contaminated soils were evaluated; moreover, the pollutants release was evaluated by means of leaching tests. The results showed that the reuse of pre-treated MSWI bottom ash and washed soil is possible, either from technical or environmental point of view, while it is not possible for the raw wastes. Then, the natural aggregate was partially and totally replaced with these recycled aggregates for the production of concrete mixtures that were characterized by conventional mechanical and leaching tests. Good results were obtained using the same dosage of a high resistance cement (42.5R calcareous Portland cement instead of 32.5R); the concrete mixture containing 400 kg/m(3) of washed bottom ash and high resistance cement was classified as structural concrete (C25/30 class). Regarding the pollutants leaching, all concrete mixtures respected the limit values according to the Italian regulation. Copyright © 2010 Elsevier Ltd. All rights reserved.

  14. Project Management Plan for the Idaho National Engineering Laboratory Waste Isolation Pilot Plant Experimental Test Program

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Connolly, M.J.; Sayer, D.L.

    1993-11-01

    EG&G Idaho, Inc. and Argonne National Laboratory-West (ANL-W) are participating in the Idaho National Engineering Laboratory`s (INEL`s) Waste Isolation Pilot Plant (WIPP) Experimental Test Program (WETP). The purpose of the INEL WET is to provide chemical, physical, and radiochemical data on transuranic (TRU) waste to be stored at WIPP. The waste characterization data collected will be used to support the WIPP Performance Assessment (PA), development of the disposal No-Migration Variance Petition (NMVP), and to support the WIPP disposal decision. The PA is an analysis required by the Code of Federal Regulations (CFR), Title 40, Part 191 (40 CFR 191), whichmore » identifies the processes and events that may affect the disposal system (WIPP) and examines the effects of those processes and events on the performance of WIPP. A NMVP is required for the WIPP by 40 CFR 268 in order to dispose of land disposal restriction (LDR) mixed TRU waste in WIPP. It is anticipated that the detailed Resource Conservation and Recovery Act (RCRA) waste characterization data of all INEL retrievably-stored TRU waste to be stored in WIPP will be required for the NMVP. Waste characterization requirements for PA and RCRA may not necessarily be identical. Waste characterization requirements for the PA will be defined by Sandia National Laboratories. The requirements for RCRA are defined in 40 CFR 268, WIPP RCRA Part B Application Waste Analysis Plan (WAP), and WIPP Waste Characterization Program Plan (WWCP). This Project Management Plan (PMP) addresses only the characterization of the contact handled (CH) TRU waste at the INEL. This document will address all work in which EG&G Idaho is responsible concerning the INEL WETP. Even though EG&G Idaho has no responsibility for the work that ANL-W is performing, EG&G Idaho will keep a current status and provide a project coordination effort with ANL-W to ensure that the INEL, as a whole, is effectively and efficiently completing the requirements for WETP.« less

  15. A new approach to characterize very-low-level radioactive waste produced at hadron accelerators.

    PubMed

    Zaffora, Biagio; Magistris, Matteo; Chevalier, Jean-Pierre; Luccioni, Catherine; Saporta, Gilbert; Ulrici, Luisa

    2017-04-01

    Radioactive waste is produced as a consequence of preventive and corrective maintenance during the operation of high-energy particle accelerators or associated dismantling campaigns. Their radiological characterization must be performed to ensure an appropriate disposal in the disposal facilities. The radiological characterization of waste includes the establishment of the list of produced radionuclides, called "radionuclide inventory", and the estimation of their activity. The present paper describes the process adopted at CERN to characterize very-low-level radioactive waste with a focus on activated metals. The characterization method consists of measuring and estimating the activity of produced radionuclides either by experimental methods or statistical and numerical approaches. We adapted the so-called Scaling Factor (SF) and Correlation Factor (CF) techniques to the needs of hadron accelerators, and applied them to very-low-level metallic waste produced at CERN. For each type of metal we calculated the radionuclide inventory and identified the radionuclides that most contribute to hazard factors. The methodology proposed is of general validity, can be extended to other activated materials and can be used for the characterization of waste produced in particle accelerators and research centres, where the activation mechanisms are comparable to the ones occurring at CERN. Copyright © 2017 Elsevier Ltd. All rights reserved.

  16. Waste Generated from LMR-AMTEC Reactor Concept

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Hasan, Ahmed; Mohamed, Yasser, T.; Mohammaden, Tarek, F.

    2003-02-25

    The candidate Liquid Metal Reactor-Alkali Metal Thermal -to- Electric Converter (LMR-AMTEC) is considered to be the first reactor that would use pure liquid potassium as a secondary coolant, in which potassium vapor aids in the conversion of thermal energy to electric energy. As with all energy production, the thermal generation of electricity produces wastes. These wastes must be managed in ways which safeguard human health and minimize their impact on the environment. Nuclear power is the only energy industry, which takes full responsibility for all its wastes. Based on the candidate design of the LMR-AMTEC components and the coolant types,more » different wastes will be generated from LMR. These wastes must be classified and characterized according to the U.S. Code of Federal Regulation, CFR. This paper defines the waste generation and waste characterization from LMR-AMTEC and reviews the applicable U.S. regulations that govern waste transportation, treatment, storage and final disposition. The wastes generated from LMR-AMTEC are characterized as: (1) mixed waste which is generated from liquid sodium contaminated by fission products and activated corrosion products; (2) hazardous waste which is generated from liquid potassium contaminated by corrosion products; (3) spent nuclear fuel; and (4) low-level radioactive waste which is generated from the packing materials (e.g. activated carbon in cold trap and purification units). The regulations and management of these wastes are summarized in this paper.« less

  17. The Advancement of Public Awareness, Concerning TRU Waste Characterization, Using a Virtual Document

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    West, T. B.; Burns, T. P.; Estill, W. G.

    2002-02-28

    Building public trust and confidence through openness is a goal of the DOE Carlsbad Field Office for the Waste Isolation Pilot Plant (WIPP). The objective of the virtual document described in this paper is to give the public an overview of the waste characterization steps, an understanding of how waste characterization instrumentation works, and the type and amount of data generated from a batch of drums. The document is intended to be published on a web page and/or distributed at public meetings on CDs. Users may gain as much information as they desire regarding the transuranic (TRU) waste characterization program,more » starting at the highest level requirements (drivers) and progressing to more and more detail regarding how the requirements are met. Included are links to: drivers (which include laws, permits and DOE Orders); various characterization steps required for transportation and disposal under WIPP's Hazardous Waste Facility Permit; physical/chemical basis for each characterization method; types of data produced; and quality assurance process that accompanies each measurement. Examples of each type of characterization method in use across the DOE complex are included. The original skeleton of the document was constructed in a PowerPoint presentation and included descriptions of each section of the waste characterization program. This original document had a brief overview of Acceptable Knowledge, Non-Destructive Examination, Non-Destructive Assay, Small Quantity sites, and the National Certification Team. A student intern was assigned the project of converting the document to a virtual format and to discuss each subject in depth. The resulting product is a fully functional virtual document that works in a web browser and functions like a web page. All documents that were referenced, linked to, or associated, are included on the virtual document's CD. WIPP has been engaged in a variety of Hazardous Waste Facility Permit modification activities. During the public meetings, discussion centered on proposed changes to the characterization program. The philosophy behind the virtual document is to show the characterization process as a whole, rather than as isolated parts. In addition to public meetings, other uses for the information might be as a training tool for new employees at the WIPP facility to show them where their activities fit into the overall scheme, as well as an employee review to help prepare for waste certification audits.« less

  18. Environmental control technology (ECT) for geothermal processes

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Katz, G.

    1982-01-01

    The objectives of the environmental control technology (ECT) program are to develop research priorities, research new and alternative technologies and to improve economics and performance of ECT systems. The Interagency Geothermal Coordinating Council, Environmental Control Panel developed priorities and obtained industry input during 1980. H/sub 2/S controls, injection monitoring, solid waste characterization and control and subsidence were reviewed as high priority while noise controls were considered low priority. Since geothermal technology is still developing there is a need to continue researching new and alternative ECT. Often ECT systems must be designed for site specific applications and need modification for usemore » of other sites. Most of the US geothermal experience is found at the Geysers, California where H/sub 2/S abatement is required. Various systems have been tested with mixed results. The bottom line is that the economics and performance of H/sub 2/S abatement systems are less than desirable.« less

  19. 1998 report on Hanford Site land disposal restrictions for mixed waste

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Black, D.G.

    1998-04-10

    This report was submitted to meet the requirements of Hanford Federal Facility Agreement and Consent Order (Tri-Party Agreement) Milestone M-26-01H. This milestone requires the preparation of an annual report that covers characterization, treatment, storage, minimization, and other aspects of managing land-disposal-restricted mixed waste at the Hanford Facility. The US Department of Energy, its predecessors, and contractors on the Hanford Facility were involved in the production and purification of nuclear defense materials from the early 1940s to the late 1980s. These production activities have generated large quantities of liquid and solid mixed waste. This waste is regulated under authority of bothmore » the Resource Conservation and Recovery Act of l976 and the Atomic Energy Act of 1954. This report covers only mixed waste. The Washington State Department of Ecology, US Environmental Protection Agency, and US Department of Energy have entered into the Tri-Party Agreement to bring the Hanford Facility operations into compliance with dangerous waste regulations. The Tri-Party Agreement required development of the original land disposal restrictions (LDR) plan and its annual updates to comply with LDR requirements for mixed waste. This report is the eighth update of the plan first issued in 1990. The Tri-Party Agreement requires and the baseline plan and annual update reports provide the following information: (1) Waste Characterization Information -- Provides information about characterizing each LDR mixed waste stream. The sampling and analysis methods and protocols, past characterization results, and, where available, a schedule for providing the characterization information are discussed. (2) Storage Data -- Identifies and describes the mixed waste on the Hanford Facility. Storage data include the Resource Conservation and Recovery Act of 1976 dangerous waste codes, generator process knowledge needed to identify the waste and to make LDR determinations, quantities stored, generation rates, location and method of storage, an assessment of storage-unit compliance status, storage capacity, and the bases and assumptions used in making the estimates.« less

  20. Alternative management structures for municipal waste collection services: the influence of economic and political factors.

    PubMed

    Plata-Díaz, Ana María; Zafra-Gómez, José Luis; Pérez-López, Gemma; López-Hernández, Antonio Manuel

    2014-11-01

    Identifying and characterising the factors that determine why a local authority opts for a particular way of managing its waste collection service is an important issue, warranting research interest in the field of municipal solid waste (MSW) management. This paper presents empirical evidence spanning a broad time horizon (2002-2010) showing that economic and political factors impact in different ways on the provision of waste management services. We examine five alternatives in this area, including public and private service delivery formulas and, within each field, individual and joint options. Our findings highlight the importance of the service cost and that of the various indicators of fiscal stress as determinant factors of management decisions regarding the provision of MSW management services. Copyright © 2014 Elsevier Ltd. All rights reserved.

  1. Environmental Assessment for the Operation of the Glass Melter Thermal Treatment Unit at the US Department of Energy`s Mound Plant, Miamisburg, Ohio

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    NONE

    1995-06-01

    The glass melter would thermally treat mixed waste (hazardous waste contaminated with radioactive constituents largely tritium, Pu-238, and/or Th-230) that was generated at the Mound Plant and is now in storage, by stabilizing the waste in glass blocks. Depending on the radiation level of the waste, the glass melter may operate for 1 to 6 years. Two onsite alternatives and seven offsite alternatives were considered. This environmental assessment indicates that the proposed action does not constitute a major Federal action significantly affecting the human environment according to NEPA, and therefore the finding of no significant impact is made, obviating themore » need for an environmental impact statement.« less

  2. Flame retardant emission from e-waste recycling operation in northern Vietnam: environmental occurrence of emerging organophosphorus esters used as alternatives for PBDEs.

    PubMed

    Matsukami, Hidenori; Tue, Nguyen Minh; Suzuki, Go; Someya, Masayuki; Tuyen, Le Huu; Viet, Pham Hung; Takahashi, Shin; Tanabe, Shinsuke; Takigami, Hidetaka

    2015-05-01

    Three oligomeric organophosphorus flame retardants (o-PFRs), eight monomeric PFRs (m-PFRs), tetrabromobisphenol A (TBBPA), and polybrominated diphenyl ethers (PBDEs) were identified and quantified in surface soils and river sediments around the e-waste recycling area in Bui Dau, northern Vietnam. Around the e-waste recycling workshops, 1,3-phenylene bis(diphenyl phosphate) (PBDPP), bisphenol A bis(diphenyl phosphate) (BPA-BDPP), triphenyl phosphate (TPHP), TBBPA, and PBDEs were dominant among the investigated flame retardants (FRs). The respective concentrations of PBDPP, BPA-BDPP, TPHP, TBBPA and the total PBDEs were 6.6-14000 ng/g-dry, <2-1500 ng/g-dry, 11-3300 ng/g-dry, <5-2900 ng/g-dry, and 67-9200 ng/g-dry in surface soils, and 4.4-78 ng/g-dry, <2-20 ng/g-dry, 7.3-38 ng/g-dry, 6.0-44 ng/g-dry and 100-350 ng/g-dry in river sediments. Near the open burning site of e-waste, tris(methylphenyl) phosphate (TMPP), (2-ethylhexyl)diphenyl phosphate (EHDPP), TPHP, and the total PBDEs were abundantly with respective concentrations of <2-190 ng/g-dry, <2-69 ng/g-dry, <3-51 ng/g-dry and 1.7-67 ng/g-dry in surface soils. Open storage and burning of e-waste have been determined to be important factors contributing to the emissions of FRs. The environmental occurrence of emerging FRs, especially o-PFRs, indicates that the alternation of FRs addition in electronic products is shifting in response to domestic and international regulations of PBDEs. The emissions of alternatives from open storage and burning of e-waste might become greater than those of PBDEs in the following years. The presence and environmental effects of alternatives should be regarded as a risk factor along with e-waste recycling. Copyright © 2015 Elsevier B.V. All rights reserved.

  3. Results For The Fourth Quarter 2014 Tank 50 WAC Slurry Sample: Chemical And Radionuclide Contaminants

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Crawford, C.

    2015-09-30

    This report details the chemical and radionuclide contaminant results for the characterization of the Calendar Year (CY) 2014 Fourth Quarter sampling of Tank 50 for the Saltstone Waste Acceptance Criteria (WAC) in effect at that time. Information from this characterization will be used by DWPF & Saltstone Facility Engineering (DSFE) to support the transfer of low-level aqueous waste from Tank 50 to the Salt Feed Tank in the Saltstone Facility in Z-Area, where the waste will be immobilized. This information is also used to update the Tank 50 Waste Characterization System.

  4. Evaluation of biochemical factors from mixed animal wastes feedstock in biogas production

    USDA-ARS?s Scientific Manuscript database

    Animal wastes can serve as the feedstock for biogas production (mainly methane) that could be used as alternative energy source. The green energy derived from animal wastes is considered to be carbon neutral and offsetting those generated from fossil fuels. In this study, an evaluation of methane ...

  5. 40 CFR 63.1215 - What are the health-based compliance alternatives for total chlorine?

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... SOURCE CATEGORIES National Emission Standards for Hazardous Air Pollutants from Hazardous Waste... chlorine under the procedures prescribed in this section for your hazardous waste combustors other than... concentration (ppmv) expressed as chloride (Cl(−)) equivalent for each on site hazardous waste combustor. You...

  6. 40 CFR 264.342 - Principal organic hazardous constituents (POHCs).

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... (CONTINUED) SOLID WASTES (CONTINUED) STANDARDS FOR OWNERS AND OPERATORS OF HAZARDOUS WASTE TREATMENT, STORAGE... feed to be burned. This specification will be based on the degree of difficulty of incineration of the... results of waste analyses and trial burns or alternative data submitted with part B of the facility's...

  7. Safety in the Chemical Laboratory: Contracts to Dispose of Laboratory Waste.

    ERIC Educational Resources Information Center

    Fischer, Kenneth E.

    1985-01-01

    Presents a sample contract for disposing of hazardous wastes in an environmentally sound, timely manner in accordance with all federal, state, and local requirements. Addresses situations where hazardous waste must be disposed of outside the laboratory and where alternate disposal methods are not feasible. (JN)

  8. Effect of biochemical factors from mixed animal wastes feedstock in biogas production

    USDA-ARS?s Scientific Manuscript database

    Animal wastes can serve as the feedstock for biogas production (mainly methane) that could be used as alternative energy source. The green energy derived from animal wastes is considered to be carbon neutral and offsetting those generated from fossil fuels. In this study, an evaluation of methane...

  9. Development of an Alternative Treatment Scheme for Sr/TRU Removal: Permanganate Treatment of AN-107 Waste

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    RT Hallen; SA Bryan; FV Hoopes

    A number of Hanford tanks received waste containing organic complexants, which increase the volubility of Sr-90 and transuranic (TRU) elements. Wastes from these tanks require additional pretreatment to remove Sr-90 and TRU for immobilization as low activity waste (Waste Envelope C). The baseline pretreatment process for Sr/TRU removal was isotopic exchange and precipitation with added strontium and iron. However, studies at both Battelle and Savannah River Technology Center (SRTC) have shown that the Sr/Fe precipitates were very difficult to filter. This was a result of the formation of poor filtering iron solids. An alternate treatment technology was needed for Sr/TRUmore » removal. Battelle had demonstrated that permanganate treatment was effective for decontaminating waste samples from Hanford Tank SY-101 and proposed that permanganate be examined as an alternative Sr/TRU removal scheme for complexant-containing tank wastes such as AW107. Battelle conducted preliminary small-scale experiments to determine the effectiveness of permanganate treatment with AN-107 waste samples that had been archived at Battelle from earlier studies. Three series of experiments were performed to evaluate conditions that provided adequate Sr/TRU decontamination using permanganate treatment. The final series included experiments with actual AN-107 diluted feed that had been obtained specifically for BNFL process testing. Conditions that provided adequate Sr/TRU decontamination were identified. A free hydroxide concentration of 0.5M provided adequate decontamination with added Sr of 0.05M and permanganate of 0.03M for archived AN-107. The best results were obtained when reagents were added in the sequence Sr followed by permanganate with the waste at ambient temperature. The reaction conditions for Sr/TRU removal will be further evaluated with a 1-L batch of archived AN-107, which will provide a large enough volume of waste to conduct crossflow filtration studies (Hallen et al. 2000a).« less

  10. CHARACTERIZATION OF ORGANIC EMISSIONS FROM HAZARDOUS WASTE INCINERATION PROCESSES UNDER THE NEW EPA DRAFT RISK BURN GUIDANCE: MEASUREMENT ISSUES

    EPA Science Inventory

    The paper discusses measurement issues relating to the characterization of organic emissions from hazardous waste incineration processes under EPA's new risk burn guidance. The recently published draft quidance recommends that hazardous waste combustion facilities complete a mass...

  11. EVALUATION OF EMISSIONS FROM THE OPEN BURNING OF HOUSEHOLD WASTE IN BARRELS - VOLUME 1. TECHNICAL REPORT

    EPA Science Inventory

    The report gives results of a detailed emissions characterization study undertaken to examine, characterize, and quantify emissions from the simulated burning of household waste in barrels. The study evaluated two waste streams: that of an avid recycler, who removed most of the r...

  12. EVALUATION OF EMISSIONS FROM THE OPEN BURNING OF HOUSEHOLD WASTES IN BARRELS - VOLUME 2. APPENDICES

    EPA Science Inventory

    The report gives results of a detailed emissions characterization study undertaken to examine, characterize, and quantify emissions from the simulated burning of household waste in barrels. The study evaluated two waste streams: that of an avid recycler, who removed most of the r...

  13. Experimental investigations on a diesel engine operated with fuel blends derived from a mixture of Pakistani waste tyre oil and waste soybean oil biodiesel.

    PubMed

    Qasim, Muhammad; Ansari, Tariq Mahmood; Hussain, Mazhar

    2017-10-18

    The waste tyre and waste cooking oils have a great potential to be used as alternative fuels for diesel engines. The aim of this study was to convert light fractions of pyrolysis oil derived from Pakistani waste vehicle tyres and waste soybean oil methyl esters into valuable fuel and to reduce waste disposal-associated environmental problems. In this study, the waste tyre pyrolysis liquid (light fraction) was collected from commercial tyre pyrolysis plant and biodiesel was prepared from waste soybean oil. The fuel blends (FMWO10, FMWO20, FMWO30, FMWO40 and FMWO50) were prepared from a 30:70 mixture of waste tyre pyrolysis liquid and waste soybean oil methyl esters with different proportions of mineral diesel. The mixture was named as the fuel mixture of waste oils (FMWO). FT-IR analysis of the fuel mixture was carried out using ALPHA FT-IR spectrometer. Experimental investigations on a diesel engine were carried out with various FMWO blends. It was observed that the engine fuel consumption was marginally increased and brake thermal efficiency was marginally decreased with FMWO fuel blends. FMWO10 has shown lowest NOx emissions among all the fuel blends tested. In addition, HC, CO and smoke emissions were noticeably decreased by 3.1-15.6%, 16.5-33.2%, and 1.8-4.5%, respectively, in comparison to diesel fuel, thereby qualifying the blends to be used as alternative fuel for diesel engines.

  14. Use of recycled plastic in concrete: a review.

    PubMed

    Siddique, Rafat; Khatib, Jamal; Kaur, Inderpreet

    2008-01-01

    Numerous waste materials are generated from manufacturing processes, service industries and municipal solid wastes. The increasing awareness about the environment has tremendously contributed to the concerns related with disposal of the generated wastes. Solid waste management is one of the major environmental concerns in the world. With the scarcity of space for landfilling and due to its ever increasing cost, waste utilization has become an attractive alternative to disposal. Research is being carried out on the utilization of waste products in concrete. Such waste products include discarded tires, plastic, glass, steel, burnt foundry sand, and coal combustion by-products (CCBs). Each of these waste products has provided a specific effect on the properties of fresh and hardened concrete. The use of waste products in concrete not only makes it economical, but also helps in reducing disposal problems. Reuse of bulky wastes is considered the best environmental alternative for solving the problem of disposal. One such waste is plastic, which could be used in various applications. However, efforts have also been made to explore its use in concrete/asphalt concrete. The development of new construction materials using recycled plastics is important to both the construction and the plastic recycling industries. This paper presents a detailed review about waste and recycled plastics, waste management options, and research published on the effect of recycled plastic on the fresh and hardened properties of concrete. The effect of recycled and waste plastic on bulk density, air content, workability, compressive strength, splitting tensile strength, modulus of elasticity, impact resistance, permeability, and abrasion resistance is discussed in this paper.

  15. Roadmap for disposal of Electrorefiner Salt as Transuranic Waste.

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Rechard, Robert P.; Trone, Janis R.; Kalinina, Elena Arkadievna

    The experimental breeder reactor (EBR-II) used fuel with a layer of sodium surrounding the uranium-zirconium fuel to improve heat transfer. Disposing of EBR-II fuel in a geologic repository without treatment is not prudent because of the potentially energetic reaction of the sodium with water. In 2000, the US Department of Energy (DOE) decided to treat the sodium-bonded fuel with an electrorefiner (ER), which produces metallic uranium product, a metallic waste, mostly from the cladding, and the salt waste in the ER, which contains most of the actinides and fission products. Two waste forms were proposed for disposal in a minedmore » repository; the metallic waste, which was to be cast into ingots, and the ER salt waste, which was to be further treated to produce a ceramic waste form. However, alternative disposal pathways for metallic and salt waste streams may reduce the complexity. For example, performance assessments show that geologic repositories can easily accommodate the ER salt waste without treating it to form a ceramic waste form. Because EBR-II was used for atomic energy defense activities, the treated waste likely meets the definition of transuranic waste. Hence, disposal at the Waste Isolation Pilot Plant (WIPP) in southern New Mexico, may be feasible. This report reviews the direct disposal pathway for ER salt waste and describes eleven tasks necessary for implementing disposal at WIPP, provided space is available, DOE decides to use this alternative disposal pathway in an updated environmental impact statement, and the State of New Mexico grants permission.« less

  16. Final environmental impact statement. Management of commercially generated radioactive waste. Volume 1 of 3

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Not Available

    1980-10-01

    This EIS analyzes the significant environmental impacts that could occur if various technologies for management and disposal of high-level and transuranic wastes from commercial nuclear power reactors were to be developed and implemented. This EIS will serve as the environmental input for the decision on which technology, or technologies, will be emphasized in further research and development activities in the commercial waste management program. The action proposed in this EIS is to (1) adopt a national strategy to develop mined geologic repositories for disposal of commercially generated high-level and transuranic radioactive waste (while continuing to examine subseabed and very deepmore » hole disposal as potential backup technologies) and (2) conduct a R and D program to develop such facilities and the necessary technology to ensure the safe long-term containment and isolation of these wastes. The Department has considered in this statement: development of conventionally mined deep geologic repositories for disposal of spent fuel from nuclear power reactors and/or radioactive fuel reprocessing wastes; balanced development of several alternative disposal methods; and no waste disposal action. This EIS reflects the public review of and comments offered on the draft statement. Included are descriptions of the characteristics of nuclear waste, the alternative disposal methods under consideration, and potential environmental impacts and costs of implementing these methods. Because of the programmatic nature of this document and the preliminary nature of certain design elements assumed in assessing the environmental consequences of the various alternatives, this study has been based on generic, rather than specific, systems. At such time as specific facilities are identified for particular sites, statements addressing site-specific aspects will be prepared for public review and comment.« less

  17. Monitoring radionuclide contamination in the unsaturated zone - Lessons learned at the Amargosa Desert Research Site, Nye County, Nevada

    USGS Publications Warehouse

    Stonestrom, David A.; Abraham, Jared D.; Andraski, Brian J.; Baker, Ronald J.; Mayers, C. Justin; Michel, Robert L.; Prudic, David E.; Striegl, Robert G.; Walvoord, Michelle Ann

    2004-01-01

    Contaminant-transport processes are being investigated at the U.S. Geological Survey’s Amargosa Desert Research Site (A DRS), adjacent to the Nation’s first commercial disposal facility for low-level radioactive waste. Gases containing tritium and radiocarbon are migrating through a 110-m thick unsaturated zone from unlined trenches that received waste from 1962 to 1992. Results relevant to long- term monitoring of radionuclides are summarized as follows. Contaminant plumes have unexpected histories and spatial configurations due to uncertainties in the: (1) geologic framework, (2) biochemical reactions involving waste components, (3) interactions between plume components and unsaturated-zone materials, (4) disposal practices, and (5) physical transport processes. Information on plume dynamics depends on ex-situ wet-chemical techniques because in-situ sensors for the radionuclides of interest do not exist. As at other radioactive-waste disposal facilities, radionuclides at the ADRS are mixed with varying amounts of volatile organic compounds (VOCs). Carbon-dioxide and VOC anomalies provide proxies for radioactive contamination. Contaminants in the unsaturated zone migrate along preferential pathways. Effective monitoring thus requires accurate geologic characterization. Direct- current electrical-resistivity imaging successfully mapped geologic units controlling preferential transport at the ADRS. Direct sampling of water from the unsaturated zone is complex and time consuming. Sampling plant water is an efficient alternative for mapping shallow tritium contamination.

  18. Characterizing variable biogeochemical changes during the treatment of produced oilfield waste.

    PubMed

    Hildenbrand, Zacariah L; Santos, Inês C; Liden, Tiffany; Carlton, Doug D; Varona-Torres, Emmanuel; Martin, Misty S; Reyes, Michelle L; Mulla, Safwan R; Schug, Kevin A

    2018-09-01

    At the forefront of the discussions about climate change and energy independence has been the process of hydraulic fracturing, which utilizes large amounts of water, proppants, and chemical additives to stimulate sequestered hydrocarbons from impermeable subsurface strata. This process also produces large amounts of heterogeneous flowback and formation waters, the subsurface disposal of which has most recently been linked to the induction of anthropogenic earthquakes. As such, the management of these waste streams has provided a newfound impetus to explore recycling alternatives to reduce the reliance on subsurface disposal and fresh water resources. However, the biogeochemical characteristics of produced oilfield waste render its recycling and reutilization for production well stimulation a substantial challenge. Here we present a comprehensive analysis of produced waste from the Eagle Ford shale region before, during, and after treatment through adjustable separation, flocculation, and disinfection technologies. The collection of bulk measurements revealed significant reductions in suspended and dissolved constituents that could otherwise preclude untreated produced water from being utilized for production well stimulation. Additionally, a significant step-wise reduction in pertinent scaling and well-fouling elements was observed, in conjunction with notable fluctuations in the microbiomes of highly variable produced waters. Collectively, these data provide insight into the efficacies of available water treatment modalities within the shale energy sector, which is currently challenged with improving the environmental stewardship of produced water management. Copyright © 2018 Elsevier B.V. All rights reserved.

  19. Methylene blue biosorption by pericarp of corn, alfalfa, and agave bagasse wastes.

    PubMed

    Rosas-Castor, José M; Garza-González, María T; García-Reyes, Refugio B; Soto-Regalado, Eduardo; Cerino-Córdova, Felipe J; García-González, Alcione; Loredo-Medrano, José A

    2014-01-01

    The presence of dyes in effluent is a matter of concern due to their toxicologic and aesthetical effects. In this research, locally available agro-industrial wastes (Zea mays pericarp, ZMP; Agave tequilana bagasse, ATB; and Medicago sativa waste, MSW) were used as alternative low-cost adsorbents for the removal of methylene blue (MB) from aqueous solutions. The adsorbents were characterized physically and chemically by Fourier transform infrared, scanning electron microscopy, potentiometric titrations, and N2 physisorption. MB adsorption experiments were carried out in batch systems and experimental data were used to calculate the adsorption isotherm model parameters (Langmuir, Freundlich, and Temkin) and the adsorption kinetic model parameters (pseudo-first- and pseudo-second-order models). MB-loaded biosorbents were desorbed with deionized water, ethanol (10% and 50% v/v), hydrochloric acid (0.01 and 0.05 N), and sodium hydroxide (0.1 N) at room temperature, and the best eluent was used in various adsorption-desorption cycles. The selected agricultural wastes can be considered as promising adsorbents for dye uptake from water since they exhibit considerable MB adsorption capacity (MSW 202.6 mg g(-1), ATB 156.2mg g(-1), and ZMP 110.9mg g(-1)), but it is lower than that reported for activated carbon; however, the biosorbents show higher adsorption rate than powdered activated carbon. Furthermore, the adsorbents can be economically regenerated with HCl solutions and reused for seven adsorption-desorption cycles.

  20. Life-cycle assessment of municipal solid waste management alternatives with consideration of uncertainty: SIWMS development and application.

    PubMed

    Hanandeh, Ali El; El-Zein, Abbas

    2010-05-01

    This paper describes the development and application of the Stochastic Integrated Waste Management Simulator (SIWMS) model. SIWMS provides a detailed view of the environmental impacts and associated costs of municipal solid waste (MSW) management alternatives under conditions of uncertainty. The model follows a life-cycle inventory approach extended with compensatory systems to provide more equitable bases for comparing different alternatives. Economic performance is measured by the net present value. The model is verified against four publicly available models under deterministic conditions and then used to study the impact of uncertainty on Sydney's MSW management 'best practices'. Uncertainty has a significant effect on all impact categories. The greatest effect is observed in the global warming category where a reversal of impact direction is predicted. The reliability of the system is most sensitive to uncertainties in the waste processing and disposal. The results highlight the importance of incorporating uncertainty at all stages to better understand the behaviour of the MSW system. Copyright (c) 2010 Elsevier Ltd. All rights reserved.

  1. Radiological characterization of skyshine from a retired, low-level, radioactive liquid effluent disposal facility at Hanford

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Brown, R.C.; Perkins, C.J.

    1991-02-01

    The 1301-N Liquid Waste Disposal Facility, located on the Hanford Site received N Reactor low-level radioactive liquid process effluent from 1962 to 1985. Radiation emanating from the top of the trench sections was not significant because of the sediments were normally under several meters of water, which provided the necessary shielding. Following retirement of the facility, the liquid in the trench sections percolated into the ground leaving the residual radioactively contaminated sediments unshielded along the bottom and sides of the trench sections. The radioactive constituents of the contaminated sediments include the gamma-emitting isotopes Co-60 and Cs-137. Because of the lackmore » of water covering, some of the gamma photons that were emitted upward were scattered downward due to Compton interaction with atmospheric constituents. This phenomenon is known as skyshine.'' A radiological characterization was required to provide guidance for determining the effectiveness of interim stabilization alternatives that would not adversely affect future Resource Conservation and Recovery Act site closure activities, (e.g., filling in trench sections with spoils from excavation activities). A noninvasive radiological characterization of this disposal facility and the affected area of the Columbia River shoreline was conducted. This characterization confirmed that skyshine is the cause of the elevated shoreline exposure rates and provided a model that could be used to rate the effectiveness of alternative interim stabilization measures. 4 refs., 5 figs.« less

  2. Let's Reduce and Recycle: Curriculum for Solid Waste Awareness. Lesson Plans for Grades K-6 and 7-12. Revised.

    ERIC Educational Resources Information Center

    Environmental Protection Agency, Washington, DC.

    The purpose of this guide is to educate young people about the problems associated with solid waste. The activities encourage them to think about options for reducing the amount of waste they generate and how they can help by recycling and learning about other waste management alternatives. The lesson plans deal specifically with garbage and…

  3. DOE Office of Scientific and Technical Information (OSTI.GOV)

    Lee, Uisung; Han, Jeongwoo; Wang, Michael

    The amount of municipal solid waste (MSW) generated in the United States was estimated at 254 million wet tons in 2013, and around half of that generated waste was landfilled. There is a huge potential in recovering energy from that waste, since around 60% of landfilled material is biomass-derived waste that has high energy content. In addition, diverting waste for fuel production avoids huge fugitive emissions from landfills, especially uncontrolled CH 4 emissions, which are the third largest anthropogenic CH 4 source in the United States. Lifecycle analysis (LCA) is typically used to evaluate the environmental impact of alternative fuelmore » production pathways. LCA of transportation fuels is called well-to-wheels (WTW) and covers all stages of the fuel production pathways, from feedstock recovery (well) to vehicle operation (wheels). In this study, the Greenhouse Gases, Regulated Emissions, and Energy Use in Transportation (GREET ®) model developed by Argonne National Laboratory is used to evaluate WTW greenhouse gas (GHG) emissions and fossil fuel consumption of waste-derived fuels. Two waste-to-energy (WTE) pathways have been evaluated – one for compressed natural gas (CNG) production using food waste via anaerobic digestion, and the other for ethanol production from yard trimmings via fermentation processes. Because the fuel production pathways displace current waste management practices (i.e., landfilling waste), we use a marginal approach that considers only the differences in emissions between the counterfactual case and the alternative fuel production case.« less

  4. U.S. Geological Survey research in radioactive waste disposal - Fiscal years 1983, 1984, and 1985

    USGS Publications Warehouse

    Dinwiddie, G.A.; Trask, N.J.

    1986-01-01

    The report summarizes progress on geologic and hydrologic research related to the disposal of radioactive wastes. The research is described according to whether it is related most directly to: (1) high-level and transuranic wastes, (2) low-level wastes, or (3) uranium mill tailings. Included is research applicable to the identification and geohydrologic characterization of waste-disposal sites, to investigations of specific sites where wastes have been stored, and to studies of regions or environments where waste-disposal sites might be located. A significant part of the activity is concerned with techniques and methods for characterizing disposal sites and studies of geologic and hydrologic processes related to the transport and (or) retention of waste radionuclides.

  5. DOE Office of Scientific and Technical Information (OSTI.GOV)

    Osmanlioglu, Ahmet Erdal

    Pre-treatment of radioactive waste is the first step in waste management program that occurs after waste generation from various applications in Turkey. Pre-treatment and characterization practices are carried out in Radioactive Waste Management Unit (RWMU) at Cekmece Nuclear Research and Training Center (CNRTC) in Istanbul. This facility has been assigned to take all low-level radioactive wastes generated by nuclear applications in Turkey. The wastes are generated from research and nuclear applications mainly in medicine, biology, agriculture, quality control in metal processing and construction industries. These wastes are classified as low- level radioactive wastes. Pre-treatment practices cover several steps. In thismore » paper, main steps of pre-treatment and characterization are presented. Basically these are; collection, segregation, chemical adjustment, size reduction and decontamination operations. (author)« less

  6. Assessment of multiple geophysical techniques for the characterization of municipal waste deposit sites

    NASA Astrophysics Data System (ADS)

    Gaël, Dumont; Tanguy, Robert; Nicolas, Marck; Frédéric, Nguyen

    2017-10-01

    In this study, we tested the ability of geophysical methods to characterize a large technical landfill installed in a former sand quarry. The geophysical surveys specifically aimed at delimitating the deposit site horizontal extension, at estimating its thickness and at characterizing the waste material composition (the moisture content in the present case). The site delimitation was conducted with electromagnetic (in-phase and out-of-phase) and magnetic (vertical gradient and total field) methods that clearly showed the transition between the waste deposit and the host formation. Regarding waste deposit thickness evaluation, electrical resistivity tomography appeared inefficient on this particularly thick deposit site. Thus, we propose a combination of horizontal to vertical noise spectral ratio (HVNSR) and multichannel analysis of the surface waves (MASW), which successfully determined the approximate waste deposit thickness in our test landfill. However, ERT appeared to be an appropriate tool to characterize the moisture content of the waste, which is of prior information for the organic waste biodegradation process. The global multi-scale and multi-method geophysical survey offers precious information for site rehabilitation studies, water content mitigation processes for enhanced biodegradation or landfill mining operation planning.

  7. EPA's Review of DOE's Inventory Tracking for TRU Wastes at Waste Control Specialists

    EPA Pesticide Factsheets

    On April 9, 2014, EPA's Waste Isolation Pilot Plant (WIPP) waste characterization team visited Waste Control Specialists (WCS) to determine whether DOE was meeting EPA's waste inventory tracking requirements at 40 CFR 194.24(c)(4).

  8. Characterization of the fine fraction of the argon oxygen decarburization with lance (AOD-L) sludge generated by the stainless steelmaking industry.

    PubMed

    Majuste, Daniel; Mansur, Marcelo Borges

    2008-05-01

    The argon oxygen decarburization with lance (AOD-L) sludge generated by the stainless steelmaking industry is a hazardous waste due to the presence of chromium. While its coarse fraction is usually recycled into the own industrial process, the fine fraction is normally disposed in landfills. Techniques such as briquetting or magnetic separation were found to be inadequate to treat it for reuse purposes. So, in this work, the fine fraction of the AOD-L sludge was characterized aiming to find alternative methods to treat it. This sludge consists of a fine powder (mean diameter of 1 microm) containing 34 +/- 2% (w/w) of iron, 10.2 +/- 0.9% (w/w) of chromium and 1.4 +/- 0.1% (w/w) of nickel. The main crystalline phases identified in this study were chromite (FeCr(2)O(4)), magnetite (Fe(3)O(4)), hematite (Fe(2)O(3)) and calcite (CaCO(3)). In the digestion tests, the addition of HClO(4) has favored the dissolution of chromite which is a very stable oxide in aqueous media. Nickel was found in very fine particles, probably in the metallic form or associated with iron and oxygen. The sludge was classified as hazardous waste, so its disposal in landfills should be avoided.

  9. Cost/Benefit Analysis of the Heat Recovery Incinerator (HRI).

    DTIC Science & Technology

    1985-09-01

    management opportunities such as the use of nearby resource recovery facilities that have been f’manced I mm~ and erected by private operators or civic...Engineering Command policy regarding HRI construc- ftpy tion at Navy activities is to seek alternative waste management opportunities such as the use ...Command policy regarding HRI construc- tion at Navy activities is to seek alternative waste management opportunities such as the use of nearby resource

  10. Vegetative covers for waste containment.

    PubMed

    Rock, Steven A

    2003-01-01

    Disposal of municipal and hazardous waste in the United States is primarily accomplished by containment in lined and capped landfills. Evapotranspiration cover systems offer an alternative to conventional landfill cap systems. These covers work on completely different principles than traditional covers do, and that difference may slow understanding and acceptance by site owners, regulators, and stakeholders. This chapter provides an introduction to this alternative technique and explains some of the common concerns regarding its implementation.

  11. Use of food waste-recycling wastewater as an alternative carbon source for denitrification process: A full-scale study.

    PubMed

    Kim, Eunji; Shin, Seung Gu; Jannat, Md Abu Hanifa; Tongco, Jovale Vincent; Hwang, Seokhwan

    2017-12-01

    Using organic wastes as an alternative to commercial carbon sources could be beneficial by reducing costs and environmental impacts. In this study, food waste-recycling wastewater (FRW) was evaluated as an alternative carbon source for biological denitrification over a period of seven months in a full-scale sewage wastewater treatment plant. The denitrification performance was stable with a mean nitrate removal efficiency of 97.2%. Propionate was initially the most persistent volatile fatty acid, but was completely utilized after 19days. Eubacteriacea, Saprospiraceae, Rhodocyclaceae and Comamonadaceae were the major bacterial families during FRW treatment and were regarded as responsible for hydrolysis (former two) and nitrate removal (latter two) of FRW. These results demonstrate that FRW can be an effective external carbon source; process stabilization was linked to the acclimation and function of bacterial populations to the change of carbon source. Copyright © 2017 Elsevier Ltd. All rights reserved.

  12. DOE Office of Scientific and Technical Information (OSTI.GOV)

    Cramer, Alisha J.; Cole, Jacqueline M.

    The ever-increasing demands of the modern world continue to place substantial strain on the environment. To help alleviate the damage done to the natural world, the encapsulation of small molecules or ions (guests) into porous inorganic structural frameworks (hosts) provides a potential remedy for some of the environmental concerns facing us today. These concerns include the removal of harmful pollutants from water or air, the safe entrapment of nuclear waste materials, or the purification and storage of small molecules that act as alternative fuel sources. For this study, we review the trends in using inorganic materials as hostmedia for themore » removal or storage of various wastes and alternative fuels. In conclusion, we cover the treatment of water contaminated with dyes or heavy metals, air pollution alleviation via CO 2, SO x, NO x, and volatile organic compound containment, nuclear waste immobilization, and storage for H 2 and methane as alternative fuels.« less

  13. Application of Anthocyanins from Blackcurrant ( Ribes nigrum L.) Fruit Waste as Renewable Hair Dyes.

    PubMed

    Rose, Paul M; Cantrill, Victoria; Benohoud, Meryem; Tidder, Alenka; Rayner, Christopher M; Blackburn, Richard S

    2018-05-29

    There is much concern about the toxicological effects of synthetic hair dyes. As an alternative approach, renewable waste blackcurrant ( Ribes nigrum L.) fruit skins from the fruit pressing industry were extracted using acidified water with a solid-phase purification stage. Anthocyanin colorants were isolated in good yields (2-3% w/ w) and characterized by HPLC. Sorption of anthocyanins onto hair followed a Freundlich isotherm; anthocyanin-anthocyanin aggregation interactions enabled high buildup on the substrate. Sorption energy of cyanidin-3- O-glucoside (monosaccharide) > cyanidin-3- O-rutinoside (disaccharide), but sorption properties of different anthocyanin glucosides were very similar. Intense blue-colored dyeing on hair could be achieved with λ max-vis at 580 nm, typical of the anionic quinonoid base; it is suggested that hair provides an environment that enables the stabilization of the anionic quinonoid base on adsorption through association with cations in the hair and copigmentation effects. Dyeings were stable to multiple washes.

  14. Overview of IEA biomass combustion activities

    NASA Astrophysics Data System (ADS)

    Hustad, J. E.

    1994-07-01

    The objectives of the International Energy Agency (IEA) bioenergy program are: (1) to encourage cooperative research, development and use of energy and the increased utilization of alternatives to oil; and (2) to establish increased program and project cooperation between participants in the whole field of bioenergy. There are four Task Annexes to the Implementing Agreement during the period 1992-1994: Efficient and Environmentally Sound Biomass Production Systems; Harvesting and Supply of Woody Biomass for Energy; Biomass Utilization; and Conversion of Municipal Solid Waste Feedstock to Energy. The report describes the following biomass combustion activities during the period 1992-1994: Round robin test of a wood stove; Emissions from biomass combustion; A pilot project cofiring biomass with oil to reduce SO2 emissions; Small scale biomass chip handling; Energy from contaminated wood waste combustion; Modeling of biomass combustion; Wood chip cogeneration; Combustion of wet biomass feedstocks, ash reinjection and carbon burnout; Oxidation of wet biomass; Catalytic combustion in small wood burning appliances; Characterization of biomass fuels and ashes; Measurement techniques (FTIR).

  15. Ecotoxicological characterization of hazardous wastes.

    PubMed

    Wilke, B-M; Riepert, F; Koch, Christine; Kühne, T

    2008-06-01

    In Europe hazardous wastes are classified by 14 criteria including ecotoxicity (H 14). Standardized methods originally developed for chemical and soil testing were adapted for the ecotoxicological characterization of wastes including leachate and solid phase tests. A consensus on which tests should be recommended as mandatory is still missing. Up to now, only a guidance on how to proceed with the preparation of waste materials has been standardized by CEN as EN 14735. In this study, tests including higher plants, earthworms, collembolans, microorganisms, duckweed and luminescent bacteria were selected to characterize the ecotoxicological potential of a boiler slag, a dried sewage sludge, a thin sludge and a waste petrol. In general, the instructions given in EN 14735 were suitable for all wastes used. The evaluation of the different test systems by determining the LC/EC(50) or NOEC-values revealed that the collembolan reproduction and the duckweed frond numbers were the most sensitive endpoints. For a final classification and ranking of wastes the Toxicity Classification System (TCS) using EC/LC(50) values seems to be appropriate.

  16. Anaerobic co-digestion of recalcitrant agricultural wastes: Characterizing of biochemical parameters of digestate and its impacts on soil ecosystem.

    PubMed

    Muscolo, Adele; Settineri, Giovanna; Papalia, Teresa; Attinà, Emilio; Basile, Carmelo; Panuccio, Maria Rosaria

    2017-05-15

    Anaerobic digestion (AD) of organic wastes is a promising alternative to landfilling for reducing Greenhouse Gas Emission (GHG) and it is encouraged by current regulation in Europe. Biogas-AD produced, represents a useful source of green energy, while its by-product (digestate) is a waste, that needs to be safely disposal. The sustainability of anaerobic digestion plants partly depends on the management of their digestion residues. This study has been focused on the environmental and economic benefits of co-digest recalcitrant agricultural wastes such olive wastes and citrus pulp, in combination with livestock wastes, straw and cheese whey for biogas production. The aim of this work was to investigate the effects of two different bioenergy by-products on soil carbon stock, enzymes involved in nutrient cycling and microbial content. The two digestates were obtained from two plants differently fed: the first plant (Uliva) was powered with 60% of recalcitrant agricultural wastes, and 40% of livestock manure milk serum and maize silage. The second one (Fattoria) was fed with 40% of recalcitrant agricultural wastes and 60% of livestock manure, milk serum and maize silage. Each digestate, separated in liquid and solid fractions, was added to the soil at different concentrations. Our results evidenced that mixing and type of input feedstock affected the composition of digestates. Three months after treatments, our results showed that changes in soil chemical and biochemical characteristics depended on the source of digestate, the type of fraction and the concentration used. The mainly affected soil parameters were: Soil Organic Matter (SOM), Microbial Biomass Carbon (MBC), Fluorescein Diacetate Hydrolysis (FDA), Water Soluble Phenol (WSP) and Catalase (CAT) that can be used to assess the digestate agronomical feasibility. These results show that the agronomic quality of a digestate is strictly dependent on percentage and type of feedstocks that will be used to power the digester. Copyright © 2017 Elsevier B.V. All rights reserved.

  17. Contaminated waste incinerator modification study. Final report

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Wolf, F.

    1995-08-01

    An explosive waste incinerator (EWI) can be installed in the existing Badger AAP Contaminated Waste Processor (CWP). An engineering evaluation of installing a rotary kiln furnace to dispose of waste energetic material has shown the installation to be possible. An extensive literature search was completed to develop the known proven methods of energetic waste disposal. Current incineration practice including thermal treatment alternatives was investigated. Existing and new equipment was reviewed for adequacy. Current CWP operations and hazardous waste to be disposed of were determined. Comparisons were made with other AAP`s EWI.

  18. Stabilization and Solidification of Nitric Acid Effluent Waste at Y-12

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Singh, Dileep; Lorenzo-Martin, Cinta

    Consolidated Nuclear Security, LLC (CNS) at the Y-12 plant is investigating approaches for the treatment (stabilization and solidification) of a nitric acid waste effluent that contains uranium. Because the pH of the waste stream is 1-2, it is a difficult waste stream to treat and stabilize by a standard cement-based process. Alternative waste forms are being considered. In this regard, Ceramicrete technology, developed at Argonne National Laboratory, is being explored as an option to solidify and stabilize the nitric acid effluent wastes.

  19. 76 FR 53897 - EPA Seeking Input Materials Measurement; Municipal Solid Waste (MSW), Recycling, and Source...

    Federal Register 2010, 2011, 2012, 2013, 2014

    2011-08-30

    ... stakeholder input regarding the efficacy and scope of the MSW Characterization Report called ``Municipal Solid Waste in the United States'' as part of a broader discussion about sustainable materials management... efficacy and scope of the MSW Characterization Report called ``Municipal Solid Waste in the United States...

  20. Thermochemical valorization and characterization of household biowaste.

    PubMed

    Vakalis, S; Sotiropoulos, A; Moustakas, K; Malamis, D; Vekkos, K; Baratieri, M

    2017-12-01

    Valorization of municipal solid waste (MSW), by means of energy and material recovery, is considered to be a crucial step for sustainable waste management. A significant fraction of MSW is comprised from food waste, the treatment of which is still a challenge. Therefore, the conventional disposal of food waste in landfills is being gradually replaced by recycling aerobic treatment, anaerobic digestion and waste-to-energy. In principle, thermal processes like combustion and gasification are preferred for the recovery of energy due to the higher electrical efficiency and the significantly less time required for the process to be completed when compared to biological process, i.e. composting, anaerobic digestion and transesterification. Nonetheless, the high water content and the molecular structure of biowaste are constraining factors in regard to the application of thermal conversion pathways. Investigating alternative solutions for the pre-treatment and more energy efficient handling of this waste fraction may provide pathways for the optimization of the whole process. In this study, by means of utilizing drying/milling as an intermediate step, thermal treatment of household biowaste has become possible. Household biowaste has been thermally processed in a bench scale reactor by means of torrefaction, carbonization and high temperature pyrolysis. According to the operational conditions, fluctuating fractions of biochar, bio-oil (tar) and syngas were recovered. The thermochemical properties of the feedstock and products were analyzed by means of Simultaneous Thermal Analysis (STA), Ultimate and Proximate analysis and Attenuated Total Reflectance (ATR). The analysis of the products shows that torrefaction of dried household biowaste produces an energy dense fuel and high temperature pyrolysis produces a graphite-like material with relatively high yield. Copyright © 2016 Elsevier Ltd. All rights reserved.

  1. 40 CFR 191.04 - Alternative standards.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... PROGRAMS ENVIRONMENTAL RADIATION PROTECTION STANDARDS FOR MANAGEMENT AND DISPOSAL OF SPENT NUCLEAR FUEL, HIGH-LEVEL AND TRANSURANIC RADIOACTIVE WASTES Environmental Standards for Management and Storage § 191.04 Alternative standards. (a) The Administrator may issue alternative standards from those standards...

  2. DOE Office of Scientific and Technical Information (OSTI.GOV)

    Paul, Johannes G., E-mail: jp.aht.p3@gmail.com; Arce-Jaque, Joan; Ravena, Neil

    The integration of the informal sector into municipal solid waste management is a challenge many developing countries face. In Iloilo City, Philippines around 220 tons of municipal solid waste are collected every day and disposed at a 10 ha large dumpsite. In order to improve the local waste management system the Local Government decided to develop a new Waste Management Center with integrated landfill. However, the proposed area is adjacent to the presently used dumpsite where more than 300 waste pickers dwell and depend on waste picking as their source of livelihood. The Local Government recognized the hidden threat imposedmore » by the waste picker's presence for this development project and proposed various measures to integrate the informal sector into the municipal solid waste management (MSWM) program. As a key intervention a Waste Workers Association, called USWAG Calahunan Livelihood Association Inc. (UCLA) was initiated and registered as a formal business enterprise in May 2009. Up to date, UCLA counts 240 members who commit to follow certain rules and to work within a team that jointly recovers wasted materials. As a cooperative they are empowered to explore new livelihood options such as the recovery of Alternative Fuels for commercial (cement industry) and household use, production of compost and making of handicrafts out of used packages. These activities do not only provide alternative livelihood for them but also lessen the generation of leachate and Greenhouse Gases (GHG) emissions from waste disposal, whereby the life time of the proposed new sanitary landfill can be extended likewise.« less

  3. Alternative Electrochemical Salt Waste Forms, Summary of FY11-FY12 Results

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Riley, Brian J.; Mccloy, John S.; Crum, Jarrod V.

    2014-01-17

    The Fuel Cycle Research and Development Program, sponsored by the U.S. Department of Energy Office of Nuclear Energy, is currently investigating alternative waste forms for wastes generated from nuclear fuel processing. One such waste results from an electrochemical separations process, called the “Echem” process. The Echem process utilizes a molten KCl-LiCl salt to dissolve the fuel. This process results in a spent salt containing alkali, alkaline earth, lanthanide halides and small quantities of actinide halides, where the primary halide is chloride with a minor iodide fraction. Pacific Northwest National Laboratory (PNNL) is concurrently investigating two candidate waste forms for themore » Echem spent-salt: high-halide minerals (i.e., sodalite and cancrinite) and tellurite (TeO2)-based glasses. Both of these candidates showed promise in fiscal year (FY) 2009 and FY2010 with a simplified nonradioactive simulant of the Echem waste. Further testing was performed on these waste forms in FY2011 and FY2012 to assess the possibility of their use in a sustainable fuel cycle. This report summarizes the combined results from FY2011 and FY2012 efforts.« less

  4. A study on synthesis of energy fuel from waste plastic and assessment of its potential as an alternative fuel for diesel engines.

    PubMed

    Kaimal, Viswanath K; Vijayabalan, P

    2016-05-01

    The demand for plastic is ever increasing and has produced a huge amount of plastic waste. The management and disposal of plastic waste have become a major concern, especially in developing cities. The idea of waste to energy recovery is one of the promising techniques used for managing the waste plastic. This paper assesses the potential of using Waste Plastic Oil (WPO), synthesized using pyrolysis of waste plastic, as an alternative for diesel fuel. In this research work, the performance and emission characteristics of a single cylinder diesel engine fuelled with WPO and its blends with diesel are studied. In addition to neat plastic oil, three blends (PO25, PO50 and PO75) were prepared on a volumetric basis and the engine was able to run on neat plastic oil. Brake thermal efficiency of blends was lower compared to diesel, but PO25 showed similar performance to that of diesel. The emissions were reduced considerably while using blends when compared to neat plastic oil. The smoke and NOX were reduced by 22% and 17.8% respectively for PO25 than that of plastic oil. Copyright © 2016 Elsevier Ltd. All rights reserved.

  5. 10 CFR 62.13 - Contents of a request for emergency access: Alternatives.

    Code of Federal Regulations, 2010 CFR

    2010-01-01

    ... radioactive waste in a licensed storage facility; (3) Obtaining access to a disposal facility by voluntary... disposal at a Federal low-level radioactive waste disposal facility in the case of a Federal or defense... EMERGENCY ACCESS TO NON-FEDERAL AND REGIONAL LOW-LEVEL WASTE DISPOSAL FACILITIES Request for a Commission...

  6. Waste. Choices for Communities.

    ERIC Educational Resources Information Center

    Knaus, Andy; And Others

    The purpose of this booklet is to provide an introduction to the many complex issues of waste management in the United States. It is designed to raise public awareness of the serious impact of current waste generation and disposal practices and to promote alternatives. It encourages citizens to involve themselves in decisions about the way waste…

  7. 40 CFR 62.14471 - When must I comply with this subpart if I plan to shut down?

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... FACILITIES AND POLLUTANTS Federal Plan Requirements for Hospital/Medical/Infectious Waste Incinerators... documentation must include an evaluation of the option to transport your waste offsite to a commercial medical... an onsite alternative waste treatment technology before you shut down your HMIWI, Date when you will...

  8. Less is Better. Laboratory Chemical Management for Waste Reduction.

    ERIC Educational Resources Information Center

    American Chemical Society, Washington, DC.

    An objective of the American Chemical Society is to promote alternatives to landfilling for the disposal of laboratory chemical wastes. One method is to reduce the amount of chemicals that become wastes. This is the basis for the "less is better" philosophy. This bulletin discusses various techniques involved in purchasing control,…

  9. The effect of system parameters on the biogas production from anaerobic digestion of livestock wastes

    USDA-ARS?s Scientific Manuscript database

    Animal wastes can serve as the feedstock for biogas production (mainly methane) that could be used as alternative energy source. The green energy derived from animal wastes is considered to be carbon neutral and offsetting those generated from fossil fuels. In this study, an evaluation of system p...

  10. Evaluation of potato anaerobic digestate as a renewable alternative to peat moss in horticultural substrates

    USDA-ARS?s Scientific Manuscript database

    Potato peels and other low-value wastes from potato processing are currently being used as cattle feed or fermented to produce fuel-grade ethanol. The anaerobic fermentation of food wastes, including potato processing wastes, produces biogas (principally methane), which can be used directly for heat...

  11. 40 CFR 266.204 - Standards applicable to emergency responses.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ...) SOLID WASTES (CONTINUED) STANDARDS FOR THE MANAGEMENT OF SPECIFIC HAZARDOUS WASTES AND SPECIFIC TYPES OF HAZARDOUS WASTE MANAGEMENT FACILITIES Military Munitions § 266.204 Standards applicable to emergency... CFR 262.10(i), 263.10(e), 264.1(g)(8), 265.1(c)(11), and 270.1(c)(3), or alternatively to 40 CFR 270...

  12. 40 CFR 266.204 - Standards applicable to emergency responses.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ...) SOLID WASTES (CONTINUED) STANDARDS FOR THE MANAGEMENT OF SPECIFIC HAZARDOUS WASTES AND SPECIFIC TYPES OF HAZARDOUS WASTE MANAGEMENT FACILITIES Military Munitions § 266.204 Standards applicable to emergency... CFR 262.10(i), 263.10(e), 264.1(g)(8), 265.1(c)(11), and 270.1(c)(3), or alternatively to 40 CFR 270...

  13. 40 CFR 266.204 - Standards applicable to emergency responses.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ...) SOLID WASTES (CONTINUED) STANDARDS FOR THE MANAGEMENT OF SPECIFIC HAZARDOUS WASTES AND SPECIFIC TYPES OF HAZARDOUS WASTE MANAGEMENT FACILITIES Military Munitions § 266.204 Standards applicable to emergency... CFR 262.10(i), 263.10(e), 264.1(g)(8), 265.1(c)(11), and 270.1(c)(3), or alternatively to 40 CFR 270...

  14. Economic evaluation of an electrochemical process for the recovery of metals from electronic waste.

    PubMed

    Diaz, Luis A; Lister, Tedd E

    2018-04-01

    As the market of electronic devices continues to evolve, the waste stream generated from antiquated technology is increasingly view as an alternative to substitute primary sources of critical a value metals. Nevertheless, the sustainable recovery of materials can only be achieved by environmentally friendly processes that are economically competitive with the extraction from mineral ores. Hence, This paper presents the techno-economic assessment for a comprehensive process for the recovery of metals and critical materials from e-waste, which is based in an electrochemical recovery (ER) technology. Economic comparison is performed with the treatment of e-waste via smelting, which is currently the primary route for recycling metals from electronics. Results indicate that the electrochemical recovery process is a competitive alternative for the recovery of value from electronic waste when compared with the traditional black Cu smelting process. A significantly lower capital investment, 2.9 kg e-waste per dollar of capital investment, can be achieved with the ER process vs. 1.3 kg per dollar in the black Cu smelting process. Copyright © 2017 Elsevier Ltd. All rights reserved.

  15. The efficacy of subsurface flow reed bed treatment in the removal of Campylobacter spp., faecal coliforms and Escherichia coli from poultry litter.

    PubMed

    Duggan, J; Bates, M P; Phillips, C A

    2001-06-01

    The use of poultry waste as a fertiliser on arable land is an accepted method of waste treatment. However, run-off from such practices may result in contamination of the watercourse by human pathogens. In this study the effectiveness of using constructed wetlands as an alternative treatment for poultry manure waste was evaluated. Enumeration of Campylobacter spp., Escherichia coli, total coliforms and total aerobes were carried out on influent and effluent samples from reed beds loaded with poultry waste. For both sequential loading and continuous loading there was a statistically significant mean log reduction of 3.56 and 4.25 for E. coli, 3.2 and 3.88 for coliforms, 3.85 and 4.2 for total aerobic counts and 3.13 and 2.96 for Campylobacter spp., respectively. This method, which has been previously recognised as cost-effective and environmentally acceptable, provides an efficient method for reducing numbers of these bacteria in poultry waste and therefore an effective alternative treatment for such waste or waters containing run off from land previously spread with poultry manure.

  16. Tank characterization report for single-shell tank 241-S-111

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Conner, J.M.

    1997-04-28

    One of the major functions of the Tank Waste Remediation System (TWRS) is to characterize wastes in support of waste management and disposal activities at the Hanford Site. Analytical data from sampling and analysis, along with other available information about a tank, are compiled and maintained in a tank characterization report (TCR). This report and its appendices serve as the TCR for single-shell tank 241-S-111. The objectives of this report are: (1) to use characterization data to address technical issues associated with tank 241-S-111 waste; and (2) to provide a standard characterization of this waste in terms of a best-basismore » inventory estimate. The response to technical issues is summarized in Section 2.0, and the best-basis inventory estimate is presented in Section 3.0. Recommendations regarding safety status and additional sampling needs are provided in Section 4.0. Supporting data and information are contained in the appendices. This report also supports the requirements of Hanford Federal Facility Agreement and Consent Order (Ecology et al. 1996) milestone M-44-10.« less

  17. Sodium Bearing Waste Processing Alternatives Analysis

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Murphy, James Anthony; Palmer, Brent J; Perry, Keith Joseph

    2003-12-01

    A multidisciplinary team gathered to develop a BBWI recommendation to DOE-ID on the processing alternatives for the sodium bearing waste in the INTEC Tank Farm. Numerous alternatives were analyzed using a rigorous, systematic approach. The data gathered were evaluated through internal and external peer reviews for consistency and validity. Three alternatives were identified to be top performers: Risk-based Calcination, MACT to WIPP Calcination and Cesium Ion Exchange. A dual-path through early Conceptual design is recommended for MACT to WIPP Calcination and Cesium Ion Exchange since Risk-based Calcination does not require design. If calcination alternatives are not considered based on givingmore » Type of Processing criteria significantly greater weight, the CsIX/TRUEX alternative follows CsIX in ranking. However, since CsIX/TRUEX shares common uncertainties with CsIX, reasonable backups, which follow in ranking, are the TRUEX and UNEX alternatives. Key uncertainties must be evaluated by the decision-makers to choose one final alternative. Those key uncertainties and a path forward for the technology roadmapping of these alternatives is provided.« less

  18. Frequent Questions About Managing Hazardous Waste at Academic Laboratories

    EPA Pesticide Factsheets

    FAQs about Alternative Requirements for Hazardous Waste Determination and Accumulation of Unwanted Material for Laboratories Owned by Colleges and Universities and Other Eligible Academic Entities Formally Affiliated with Colleges and Universities.

  19. Defense Waste Processing Facility Process Enhancements

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Bricker, Jonathan

    2010-11-01

    Jonathan Bricker provides an overview of process enhancements currently being done at the Defense Waste Processing Facility (DWPF) at SRS. Some of these enhancements include: melter bubblers; reduction in water use, and alternate reductant.

  20. Informal processing of electronic waste at Agbogbloshie, Ghana: workers' knowledge about associated health hazards and alternative livelihoods.

    PubMed

    Yu, Emily A; Akormedi, Matthew; Asampong, Emmanuel; Meyer, Christian G; Fobil, Julius N

    2017-12-01

    This study was conducted to investigate the electronic waste workers' knowledge about the potential health hazards associated with their work as well as the livelihood alternatives that they would prefer if they were given the opportunity. A qualitative cross-sectional study was conducted to gather empirical information on e-waste workers' knowledge about the potential hazards associated with their work and the livelihood alternatives to e-waste recycling with a sample consisting of twenty all-male electronic waste workers at the Agbogbloshie scrap metal yard in Accra, Ghana. Electronic waste workers at Agbogbloshie were found to be exposed to a variety of injuries and illnesses. The workers' knowledge of the association between their health status and their work was generally poor. Apart from the physical injuries, they did not believe their work played any negative role in their health conditions. They preferred occupations such as farming or professional driving located in the northern region of Ghana to be closer to their families. The study concludes that the low knowledge level of the workers on the hazards that are associated with their work has implications for them accepting technologies to protect them and the natural environment from contamination. It is therefore imperative for any intervention to consider the current low level of knowledge and actively educate the workers to raise their awareness level, taking into account the provision of opportunities for workers to acquire applicable skills for future employment in other fields.

  1. Evaluating environmental impacts of alternative construction waste management approaches using supply-chain-linked life-cycle analysis.

    PubMed

    Kucukvar, Murat; Egilmez, Gokhan; Tatari, Omer

    2014-06-01

    Waste management in construction is critical for the sustainable treatment of building-related construction and demolition (C&D) waste materials, and recycling of these wastes has been considered as one of the best strategies in minimization of C&D debris. However, recycling of C&D materials may not always be a feasible strategy for every waste type and therefore recycling and other waste treatment strategies should be supported by robust decision-making models. With the aim of assessing the net carbon, energy, and water footprints of C&D recycling and other waste management alternatives, a comprehensive economic input-output-based hybrid life-cycle assessment model is developed by tracing all of the economy-wide supply-chain impacts of three waste management strategies: recycling, landfilling, and incineration. Analysis results showed that only the recycling of construction materials provided positive environmental footprint savings in terms of carbon, energy, and water footprints. Incineration is a better option as a secondary strategy after recycling for water and energy footprint categories, whereas landfilling is found to be as slightly better strategy when carbon footprint is considered as the main focus of comparison. In terms of construction materials' environmental footprint, nonferrous metals are found to have a significant environmental footprint reduction potential if recycled. © The Author(s) 2014.

  2. An Industrial Ecology Approach to Municipal Solid Waste ...

    EPA Pesticide Factsheets

    The organic fraction of municipal solid waste provides abundant opportunities for industrial ecology-based symbiotic use. Energy production, economics, and environmental aspects are analyzed for four alternatives based on different technologies: incineration with energy recovery, gasification, anaerobic digestion, and fermentation. In these cases electricity and ethanol are the products considered, but other products and attempts at symbiosis can be made. The four technologies are in various states of commercial development. To highlight their relative complexities some adjustable parameters which are important for the operability of each process are discussed. While these technologies need to be considered for specific locations and circumstances, generalized economic and environmental information suggests relative comparisons for newly conceptualized processes. The results of industrial ecology-based analysis suggest that anaerobic digestion may improve seven emission categories, while fermentation, gasification, and incineration successively improve fewer emissions. A conceptual level analysis indicates that gasification, anaerobic digestion, and fermentation alternatives lead to positive economic results. In each case the alternatives and their assumptions need further analysis for any particular community. Presents information useful for analyzing the sustainability of alternatives for the management of municipal solid waste.

  3. Greater-than-Class C low-level radioactive waste characterization: Estimated volumes, radionuclide activities, and other characteristics

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Hulse, R.A.

    1991-08-01

    Planning for storage or disposal of greater-than-Class C low-level radioactive waste (GTCC LLW) requires characterization of that waste to estimate volumes, radionuclide activities, and waste forms. Data from existing literature, disposal records, and original research were used to estimate the characteristics and project volumes and radionuclide activities to the year 2035. GTCC LLW is categorized as: nuclear utilities waste, sealed sources waste, DOE-held potential GTCC LLW; and, other generator waste. It has been determined that the largest volume of those wastes, approximately 57%, is generated by nuclear power plants. The Other Generator waste category contributes approximately 10% of the totalmore » GTCC LLW volume projected to the year 2035. Waste held by the Department of Energy, which is potential GTCC LLW, accounts for nearly 33% of all waste projected to the year 2035; however, no disposal determination has been made for that waste. Sealed sources are less than 0.2% of the total projected volume of GTCC LLW.« less

  4. Air pollution control residues from waste incineration: current UK situation and assessment of alternative technologies.

    PubMed

    Rani, D Amutha; Boccaccini, A R; Deegan, D; Cheeseman, C R

    2008-11-01

    Current disposal options for APC residues in the UK and alternative treatment technologies developed world-wide have been reviewed. APC residues are currently landfilled in the UK where they undergo in situ solidification, although the future acceptability of this option is uncertain because the EU waste acceptance criteria (WAC) introduce strict limits on leaching that are difficult to achieve. Other APC residue treatment processes have been developed which are reported to reduce leaching to below relevant regulatory limits. The Ferrox process, the VKI process, the WES-PHix process, stabilisation/solidification using cementitious binders and a range of thermal treatment processes are reviewed. Thermal treatment technologies convert APC residues combined with other wastes into inert glass or glass-ceramics that encapsulate heavy metals. The waste management industry will inevitably use the cheapest available option for treating APC residues and strict interpretation and enforcement of waste legislation is required if new, potentially more sustainable technologies are to become commercially viable.

  5. Healthcare waste management practice in the West Black Sea Region, Turkey: A comparative analysis with the developed and developing countries.

    PubMed

    Ciplak, Nesli; Kaskun, Songul

    2015-12-01

    The need for proper healthcare waste management has been a crucial issue in many developing countries as it is in Turkey. The regulation regarding healthcare wastes in Turkey was updated in 2005 in accordance with the European Union (EU) waste directives, but it still falls behind meeting the requirements of current waste treatment technologies. Therefore, this study aims to reveal deficiencies, inconsistencies, and improper applications of healthcare waste management in the western part of the Turkish Black Sea Region. In this study, it was revealed that nearly 1 million people live in the region, resulting in 5 million hospital admissions annually. All the healthcare waste produced (1000 tons yr(-1)) is treated in an autoclave plant. However, treating some categories of healthcare wastes in autoclave units mismatches with the EU waste regulations, as alternative treatment technologies are not technically able to treat all types of healthcare wastes. A proper waste management system, therefore, requires an internal segregation scheme to divert these wastes from the main healthcare waste stream. The existing malpractice in the region could cause serious health problems if no measure is taken urgently. It is expected that healthcare waste management in the region and then all across Turkey will be improved with the significant deficiencies and inconsistencies pointed out in this research. In developed countries, specific rules and regulations have already been implemented along with the recommendations for handling of healthcare waste. However, in Turkey, these wastes are treated in autoclave units, which mismatches with the European Union waste regulations, as alternative treatment technologies are not technically capable to treat all types of healthcare wastes. The existing malpractice could cause serious health problems if no measure is taken urgently. The authors demonstrated the existing status of Turkish waste management and revealed deficiencies, inconsistencies, and improper applications in comparison with developed and developing nations to align Turkish practice to European Union requirements.

  6. DOE Office of Scientific and Technical Information (OSTI.GOV)

    Dehmel, J.C.; Loomis, D.; Mauro, J.

    Under contract to the US Nuclear Regulatory Commission, Office of Nuclear Regulatory Research, the firms of S. Cohen & Associates, Inc. (SC&A) and Eastern Research Group (ERG) have compiled a report that describes the physical, chemical, and radiological properties of Class-A low-level radioactive waste. The report also presents information characterizing various methods and facilities used to treat and dispose non-radioactive waste. A database management program was developed for use in accessing, sorting, analyzing, and displaying the electronic data provided by EG&G. The program was used to present and aggregate data characterizing the radiological, physical, and chemical properties of the wastemore » from descriptions contained in shipping manifests. The data thus retrieved are summarized in tables, histograms, and cumulative distribution curves presenting radionuclide concentration distributions in Class-A waste as a function of waste streams, by category of waste generators, and regions of the United States. The report also provides information characterizing methods and facilities used to treat and dispose non-radioactive waste, including industrial, municipal, and hazardous waste regulated under Subparts C and D of the Resource Conservation and Recovery Act (RCRA). The information includes a list of disposal options, the geographical locations of the processing and disposal facilities, and a description of the characteristics of such processing and disposal facilities. Volume 1 contains the Executive Summary, Volume 2 presents the Class-A waste database, Volume 3 presents the information characterizing non-radioactive waste management practices and facilities, and Volumes 4 through 7 contain Appendices A through P with supporting information.« less

  7. Buried transuranic wastes at ORNL: Review of past estimates and reconciliation with current data

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Trabalka, J.R.

    1997-09-01

    Inventories of buried (generally meaning disposed of) transuranic (TRU) wastes at Oak Ridge National Laboratory (ORNL) have been estimated for site remediation and waste management planning over a period of about two decades. Estimates were required because of inadequate waste characterization and incomplete disposal records. For a variety of reasons, including changing definitions of TRU wastes, differing objectives for the estimates, and poor historical data, the published results have sometimes been in conflict. The purpose of this review was (1) to attempt to explain both the rationale for and differences among the various estimates, and (2) to update the estimatesmore » based on more recent information obtained from waste characterization and from evaluations of ORNL waste data bases and historical records. The latter included information obtained from an expert panel`s review and reconciliation of inconsistencies in data identified during preparation of the ORNL input for the third revision of the Baseline Inventory Report for the Waste Isolation Pilot Plant. The results summarize current understanding of the relationship between past estimates of buried TRU wastes and provide the most up-to-date information on recorded burials thereafter. The limitations of available information on the latter and thus the need for improved waste characterization are highlighted.« less

  8. Evaluation of the potential of different high calorific waste fractions for the preparation of solid recovered fuels.

    PubMed

    Garcés, Diego; Díaz, Eva; Sastre, Herminio; Ordóñez, Salvador; González-LaFuente, José Manuel

    2016-01-01

    Solid recovered fuels constitute a valuable alternative for the management of those non-hazardous waste fractions that cannot be recycled. The main purpose of this research is to assess the suitability of three different wastes from the landfill of the local waste management company (COGERSA), to be used as solid recovered fuels in a cement kiln near their facilities. The wastes analyzed were: End of life vehicles waste, packaging and bulky wastes. The study was carried out in two different periods of the year: November 2013 and April 2014. In order to characterize and classify these wastes as solid recovered fuels, they were separated into homogeneous fractions in order to determine different element components, such as plastics, cellulosic materials, packagings or textile compounds, and the elemental analysis (including chlorine content), heavy metal content and the heating value of each fraction were determined. The lower heating value of the waste fractions on wet basis varies between 10 MJ kg(-1) and 42 MJ kg(-1). One of the packaging wastes presents a very high chlorine content (6.3 wt.%) due to the presence of polyvinylchloride from pipe fragments, being the other wastes below the established limits. Most of the wastes analyzed meet the heavy metals restrictions, except the fine fraction of the end of life vehicles waste. In addition, none of the wastes exceed the mercury limit content, which is one of the parameters considered for the solid recovered fuels classification. A comparison among the experimental higher heating values and empirical models that predict the heating value from the elemental analysis data was carried out. Finally, from the three wastes measured, the fine fraction of the end of life vehicles waste was discarded for its use as solid recovered fuels due to the lower heating value and its high heavy metals content. From the point of view of the heating value, the end of life vehicles waste was the most suitable residue with a lower heating value of 35.89 MJ kg(-1), followed by the packaging waste and the bulky waste, respectively. When mixing the wastes studied a global waste was obtained, whose classification as solid recovered fuels was NCV 1 Cl 3 Hg 3. From the empirical models used for calculating higher heating value from elemental content, Scheurer-Kestner was the model that best fit the experimental data corresponding to the wastes collected in November 2013, whereas Chang equation was the most approximate to the experimental heating values for April 2014 fractions. This difference is due to higher chlorine content of the second batch of wastes, since Chang equation is the only one that incorporates the chlorine content. Copyright © 2015 Elsevier Ltd. All rights reserved.

  9. Characterization of selected municipal solid waste components to estimate their biodegradability.

    PubMed

    Bayard, R; Benbelkacem, H; Gourdon, R; Buffière, P

    2018-06-15

    Biological treatments of Residual Municipal Solid Waste (RMSW) allow to divert biodegradable materials from landfilling and recover valuable alternative resources. The biodegradability of the waste components needs however to be assessed in order to design the bioprocesses properly. The present study investigated complementary approaches to aerobic and anaerobic biotests for a more rapid evaluation. A representative sample of residual MSW was collected from a Mechanical Biological Treatment (MBT) plant and sorted out into 13 fractions according to the French standard procedure MODECOM™. The different fractions were analyzed for organic matter content, leaching behavior, contents in biochemical constituents (determined by Van Soest's acid detergent fiber method), Biochemical Oxygen Demand (BOD) and Bio-Methane Potential (BMP). Experimental data were statistically treated by Principal Components Analysis (PCA). Cumulative oxygen consumption from BOD tests and cumulative methane production from BMP tests were found to be positively correlated in all waste fractions. No correlation was observed between the results from BOD or BMP bioassays and the contents in cellulose-like, hemicelluloses-like or labile organic compounds. No correlation was observed either with the results from leaching tests (Soluble COD). The contents in lignin-like compounds, evaluated as the non-extracted RES fraction in Van Soest's method, was found however to impact negatively the biodegradability assessed by BOD or BMP tests. Since cellulose, hemicelluloses and lignin are the polymers responsible for the structuration of lignocellulosic complexes, it was concluded that the structural organization of the organic matter in the different waste fractions was more determinant on biodegradability than the respective contents in individual biopolymers. Copyright © 2017 Elsevier Ltd. All rights reserved.

  10. Biomass Briquette Investigation from Pterocarpus Indicus Leaves Waste as an Alternative Renewable Energy

    NASA Astrophysics Data System (ADS)

    Anggono, Willyanto; Sutrisno; Suprianto, Fandi D.; Evander, Jovian

    2017-10-01

    Indonesia is a tropical country located in Southeast Asia. Indonesia has a lot of variety of plant species which are very useful for life. Pterocarpus indicus are commonly used as greening and easily found everywhere in Surabaya city because of its characteristics that they have dense leaves and rapid growth. Pterocarpus indicus leaves waste would be a problem for residents of Surabaya and disturbing the cleanliness of the Surabaya city. Therefore, the Pterocarpus indicus leaves waste would be used as biomass briquettes. This research investigated the calorific value of biomass briquettes from the Pterocarpus indicus leaves waste, the effect of tapioca as an adhesive material to the calorific value of biomass briquettes from the Pterocarpus indicus leaves waste, the optimum composition for Pterocarpus indicus leaves waste biomass briquette as an alternative renewable fuel and the property of the optimum resulted biomass briquette using ultimate analysis and proximate analysis based on the ASTM standard. The calorific value biomass briquettes from the Pterocarpus indicus leaves waste were performed using an oxygen bomb calorimeter at various composition of Pterocarpus indicus from 50% to 90% rising by 10% for each experiment. The experimental results showed that the 90% raw materials (Pterocarpus indicus leaves waste)-10% adhesive materials (tapioca) mixtures is the optimum composition for biomass briquette Pterocarpus indicus leaves waste. The lower the percentage of the mass of tapioca in the biomass briquettes, the higher calorific value generated.

  11. Comparing the greenhouse gas emissions from three alternative waste combustion concepts.

    PubMed

    Vainikka, Pasi; Tsupari, Eemeli; Sipilä, Kai; Hupa, Mikko

    2012-03-01

    Three alternative condensing mode power and combined heat and power (CHP) waste-to-energy concepts were compared in terms of their impacts on the greenhouse gas (GHG) emissions from a heat and power generation system. The concepts included (i) grate, (ii) bubbling fluidised bed (BFB) and (iii) circulating fluidised bed (CFB) combustion of waste. The BFB and CFB take advantage of advanced combustion technology which enabled them to reach electric efficiency up to 35% and 41% in condensing mode, respectively, whereas 28% (based on the lower heating value) was applied for the grate fired unit. A simple energy system model was applied in calculating the GHG emissions in different scenarios where coal or natural gas was substituted in power generation and mix of fuel oil and natural gas in heat generation by waste combustion. Landfilling and waste transportation were not considered in the model. GHG emissions were reduced significantly in all of the considered scenarios where the waste combustion concepts substituted coal based power generation. With the exception of condensing mode grate incinerator the different waste combustion scenarios resulted approximately in 1 Mton of fossil CO(2)-eq. emission reduction per 1 Mton of municipal solid waste (MSW) incinerated. When natural gas based power generation was substituted by electricity from the waste combustion significant GHG emission reductions were not achieved. Copyright © 2011 Elsevier Ltd. All rights reserved.

  12. Bisphenol A and its structural analogues in household waste paper.

    PubMed

    Pivnenko, K; Pedersen, G A; Eriksson, E; Astrup, T F

    2015-10-01

    Bisphenol A (BPA) is an industrial chemical produced in large volumes. Its main use is associated with polycarbonate plastic, epoxy resins and thermal paper. In contrast to other applications, thermal paper contains BPA in its un-reacted form as an additive, which is subjected to migration. Receiving a significant amount of attention from the scientific community and beyond, due to its controversial endocrine-disrupting effects, the industry is attempting to substitute BPA in variety of applications. Alternative phenolic compounds have been proposed for use in thermal paper; however, information to what extent BPA alternatives have been used in paper is sparse. The aim of the present work was to quantify BPA and its alternatives (bisphenol S (BPS), bisphenol E (BPE), bisphenol B (BPB), 4-cumylphenol (HPP) and bisphenol F (BPF)) in waste paper and board from Danish households, thermal paper receipts, non-carbon copy paper and conventional printer paper. BPA was found in all waste paper samples analysed, while BPS was identified in 73% of them. Only BPB was not identified in any of the samples. BPA and BPS were found in the majority of the receipts, which contained no measurable concentrations of the remaining alternatives. Although receipts showed the highest concentrations of BPA and BPS, office paper, flyers and corrugated boxes, together with receipts, represented the major flux of the two compounds in waste paper streams. Copyright © 2015 Elsevier Ltd. All rights reserved.

  13. Risk Assessment Methodology for Hazardous Waste Management (1998)

    EPA Pesticide Factsheets

    A methodology is described for systematically assessing and comparing the risks to human health and the environment of hazardous waste management alternatives. The methodology selects and links appropriate models and techniques for performing the process.

  14. VEGETATIVE COVERS FOR WASTE CONTAINMENT

    EPA Science Inventory

    Disposal of municipal ahd hazardous waste in the United States is primarily accomplished by containment in lined and capped landfills. Evapotranspiration cover systems offer an alternative to conventional landfill cap systems. These covers work on completely different principles ...

  15. Climate impact analysis of waste treatment scenarios--thermal treatment of commercial and pretreated waste versus landfilling in Austria.

    PubMed

    Ragossnig, A M; Wartha, C; Pomberger, R

    2009-11-01

    A major challenge for modern waste management lies in a smart integration of waste-to-energy installations in local energy systems in such a way that the energy efficiency of the waste-to-energy plant is optimized and that the energy contained in the waste is, therefore, optimally utilized. The extent of integration of thermal waste treatment processes into regular energy supply systems plays a major role with regard to climate control. In this research, the specific waste management situation looked at scenarios aiming at maximizing the energy recovery from waste (i.e. actual scenario and waste-to-energy process with 75% energy efficiency [22.5% electricity, 52.5% heat]) yield greenhouse gas emission savings due to the fact that more greenhouse gas emissions are avoided in the energy sector than caused by the various waste treatment processes. Comparing dedicated waste-to-energy-systems based on the combined heat and power (CHP) process with concepts based on sole electricity production, the energy efficiency proves to be crucial with regard to climate control. This underlines the importance of choosing appropriate sites for waste-to-energy-plants. This research was looking at the effect with regard to the climate impact of various waste management scenarios that could be applied alternatively by a private waste management company in Austria. The research is, therefore, based on a specific set of data for the waste streams looked at (waste characteristics, logistics needed, etc.). Furthermore, the investigated scenarios have been defined based on the actual available alternatives with regard to the usage of treatment plants for this specific company. The standard scenarios for identifying climate impact implications due to energy recovery from waste are based on the respective marginal energy data for the power and heat generation facilities/industrial processes in Austria.

  16. Investigation of bioaerosols released from swine farms using conventional and alternative waste treatment and management technologies

    USGS Publications Warehouse

    Ko, G.; Simmons, O. D.; Likirdopulos, C.A.; Worley-Davis, L.; Williams, M.; Sobsey, M.D.

    2008-01-01

    Microbial air pollution from concentrated animal feeding operations (CAFOs) has raised concerns about potential public health and environmental impacts. We investigated the levels of bioaerosols released from two swine farms using conventional lagoon-sprayfield technology and ten farms using alternative waste treatment and management technologies in the United States. In total, 424 microbial air samples taken at the 12 CAFOs were analyzed for several indicator and pathogenic microorganisms, including culturable bacteria and fungi, fecal coliform, Escherichia coli, Clostridium perfringens, bacteriophage, and Salmonella. At all of the investigated farms, bacterial concentrations at the downwind boundary were higher than those at the upwind boundary, suggesting that the farms are sources of microbial air contamination. In addition, fecal indicator microorganisms were found more frequently near barns and treatment technology sites than upwind or downwind of the farms. Approximately 4.5% (19/424), 1.2% (5/424), 22.2% (94/424), and 12.3% (53/424) of samples were positive for fecal coliform, E. coli, Clostridium, and total coliphage, respectively. Based on statistical comparison of airborne fecal indicator concentrations at alternative treatment technology farms compared to control farms with conventional technology, three alternative waste treatment technologies appear to perform better at reducing the airborne release of fecal indicator microorganisms during on-farm treatment and management processes. These results demonstrate that airborne microbial contaminants are released from swine farms and pose possible exposure risks to farm workers and nearby neighbors. However, the release of airborne microorganisms appears to decrease significantly through the use of certain alternative waste management and treatment technologies. ?? 2008 American Chemical Society.

  17. WIPP Remote-Handled TRU Waste Program Update

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Most, W.; Kehrman, B.

    2006-07-01

    There are two major regulatory approval milestones necessary in order to commence disposal operations for remote-handled transuranic (RH TRU) waste at the Waste Isolation Pilot Plant (WIPP)-the RH TRU hazardous waste permit modification request [1] and the radiological characterization plan [2]. One of those milestones has been achieved. The US Environmental Protection Agency (EPA) issued its final decision to approve the Department of Energy's (DOE) RH TRU radiological characterization plan along with the RH TRU Waste Characterization Program Implementation Plan [3], on March 26, 2004. The RH TRU hazardous waste permit modification request still awaits agency approval. In EPA's decisionmore » to approve the DOE's RH TRU radiological characterization plan, the EPA also set forth the process for approving site-specific RH TRU waste characterization programs. Included in the March 29, 2005, RH TRU second Notice of Deficiency [4] (NOD) on the Class 3 Permit Modification Request for RH TRU Waste, the New Mexico Environment Department (NMED) requested that the Permittees combine their responses for the RH TRU Waste NOD with the Section 311 permit modification request NOD. The Combined Response Document was submitted April 28, 2005 [5]. Another NOD [6] was issued by the NMED on September 1, 2005, to clarify the Permittees' proposal and submit these clarifications to the administrative record. Combining both the chap. 311 [7] and RH TRU waste permit modification requests allows for both the regulator and Permittees to expedite action on the modification requests. The Combined Response Document preserves human resources and costs by having only one administrative process for both modification requests. Facility readiness requirements of the RH TRU waste final permit [8] must be implemented to declare that the WIPP is ready to receive RH TRU waste for storage and disposal. To demonstrate readiness, the WIPP is preparing for an Operational Readiness Review (ORR) of the RH TRU waste management equipment, system, and procedures. Required by DOE Order, the ORR demonstrates the capability of managing RH TRU waste. The Management and Operating Contractor (MOC) for the WIPP must first perform a Line Management Assessment. Upon successful completion of the Line Management Assessment, the MOC performs the Contractor ORR and presents the results to the local DOE office. At that time, the local DOE office performs its own ORR to declare readiness to DOE Headquarters. (authors)« less

  18. 78 FR 15358 - DOE's Preferred Alternative for Certain Tanks Evaluated in the Final Tank Closure and Waste...

    Federal Register 2010, 2011, 2012, 2013, 2014

    2013-03-11

    ... SUPPLEMENTARY INFORMATION.) \\1\\ Transuranic (TRU) waste is waste that contains alpha particle-emitting... available on the DOE NEPA Web site at http://energy.gov/nepa . Additional information on the Final TC & WM... INFORMATION CONTACT: For further information on the Final TC & WM EIS, contact Ms. Burandt as listed in...

  19. 10 CFR 62.13 - Contents of a request for emergency access: Alternatives.

    Code of Federal Regulations, 2011 CFR

    2011-01-01

    ... EMERGENCY ACCESS TO NON-FEDERAL AND REGIONAL LOW-LEVEL WASTE DISPOSAL FACILITIES Request for a Commission... following: (1) Storage of low-level radioactive waste at the site of generation; (2) Storage of low-level... disposal at a Federal low-level radioactive waste disposal facility in the case of a Federal or defense...

  20. Considerations for Net Zero Waste Installations: Treatment of Municipal Solid Waste

    DTIC Science & Technology

    2015-09-01

    plastic) containers or reusable drink containers (such as thermoses) can reduce the amount of metals in the waste stream. Foun- tain drink loyalty ...alternatives are needed to give customers outlets to safely dispose of unwanted HHHW. Periodic turn-in days can be valuable for this pur- pose... restaurants , schools, hospitals, and dining halls) and family housing areas where food waste is continually generated. ERDC/CERL TR-15-21 24

  1. Plasma for environment

    NASA Astrophysics Data System (ADS)

    Van Oost, G.

    2017-11-01

    Human activity is associated with the permanent emergence of a very wide range of waste streams. The most widely used treatment of waste is thermal processing such as incineration. An alternative environmentally friendly process is based on thermal plasma technology which is a very flexible tool because it allows to operate in a wide temperature range with almost any chemical composition of waste and chemicals needed for processing this waste, and to convert organic waste into energy or chemical substances as well as to destroy toxic organic compounds, and to vitrify radioactive waste in a scenario that for each specific type of waste can be considered optimal, both in terms of energy efficiency and environmental safety.

  2. Production and characterization of a composite insulation material from waste polyethylene teraphtalates

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Kurtulmus, Erhan; Karaboyacı, Mustafa; Yigitarslan, Sibel

    2013-12-16

    The pollution of polyethylene teraphtalate (PET) is in huge amounts due to the most widely usage as a packaging material in several industries. Regional pumice has several desirable characteristics such as porous structure, low-cost and light-weight. Considering the requirements approved by the Ministry of Public Works on isolation, composite insulation material consisting of PET and pumice was studied. Sheets of composites differing both in particle size of pumice and composition of polymer were produced by hot-molding technique. Characterization of new composite material was achieved by measuring its weight, density, flammability, endurance against both to common acids and bases, and tomore » a force applied, heat insulation and water adsorption capacity. The results of the study showed that produced composite material is an alternative building material due to its desirable characteristics; low weight, capability of low heat conduction.« less

  3. Waste-water characterization and hazardous-waste technical assistance survey, Bergstrom AFB tTxas. Final report, 6-15 March 1989

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Hedgecock, N.S.

    1990-01-01

    At the request of 67 Combat Support Group/DEEV the Air Force Occupational and Environmental Health Laboratory conducted a waste-water characterization and hazardous-waste technical assistance survey at Bergstrom AFB (BAFB) from 6-15 Mar 89. The scope of the waste-water survey was to characterize the effluent exiting the base and the effluent from 23 industrial facilities and 10 food-serving facilities. The scope of the hazardous-waste survey was to address hazardous-waste-management practices and explore opportunities for hazardous waste minimization. Specific recommendations from the survey include: (1) Accompany City of Austin personnel during waste-water sampling procedures; (2) Sample at the manhole exiting the mainmore » lift station rather than at the lift station wet well; (3) Split waste-water samples with the City of Austin for comparison of results; (4) Ensure that oil/water separators and grease traps are functioning properly and are cleaned out regularly; (5) Limit the quantity of soaps and solvents discharged down the drain to the sanitary sewer; (6) Establish a waste disposal contract for the removal of wastes in the Petroleum Oils and Lubricants underground storage tanks. (7) Remove, analyze, and properly dispose of oil contaminated soil from accumulation sites. (8) Move indoors or secure, cover, and berm the aluminum sign reconditioning tank at 67 Civil Engineering Squadron Protective Coating. (9) Connect 67 Combat Repair Squadron Test Cell floor drains to the sanitary sewer.« less

  4. RH-TRU Waste Characterization by Acceptable Knowledge at the Idaho National Engineering and Environmental Laboratory

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Schulz, C.; Givens, C.; Bhatt, R.

    2003-02-24

    Idaho National Engineering and Environmental Laboratory (INEEL) is conducting an effort to characterize approximately 620 drums of remote-handled (RH-) transuranic (TRU) waste currently in its inventory that were generated at the Argonne National Laboratory-East (ANL-E) Alpha Gamma Hot Cell Facility (AGHCF) between 1971 and 1995. The waste was generated at the AGHCF during the destructive examination of irradiated and unirradiated fuel pins, targets, and other materials from reactor programs at ANL-West (ANL-W) and other Department of Energy (DOE) reactors. In support of this effort, Shaw Environmental and Infrastructure (formerly IT Corporation) developed an acceptable knowledge (AK) collection and management programmore » based on existing contact-handled (CH)-TRU waste program requirements and proposed RH-TRU waste program requirements in effect in July 2001. Consistent with Attachments B-B6 of the Waste Isolation Pilot Plant (WIPP) Hazardous Waste Facility Permit (HWFP) and th e proposed Class 3 permit modification (Attachment R [RH-WAP] of this permit), the draft AK Summary Report prepared under the AK procedure describes the waste generating process and includes determinations in the following areas based on AK: physical form (currently identified at the Waste Matrix Code level); waste stream delineation; applicability of hazardous waste numbers for hazardous waste constituents; and prohibited items. In addition, the procedure requires and the draft summary report contains information supporting determinations in the areas of defense relationship and radiological characterization.« less

  5. Results for the First, Second, and Third Quarter Calendar Year 2015 Tank 50H WAC slurry samples chemical and radionuclide contaminants

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Crawford, C.

    2016-02-18

    This report details the chemical and radionuclide contaminant results for the characterization of the Calendar Year (CY) 2015 First, Second, and Third Quarter sampling of Tank 50H for the Saltstone Waste Acceptance Criteria (WAC) in effect at that time. Information from this characterization will be used by Defense Waste Processing Facility (DWPF) & Saltstone Facility Engineering (D&S-FE) to support the transfer of low-level aqueous waste from Tank 50H to the Salt Feed Tank in the Saltstone Facility in Z-Area, where the waste will be immobilized. This information is also used to update the Tank 50H Waste Characterization System. Previous memorandamore » documenting the WAC analyses results have been issued for these three samples.« less

  6. Speciation and Characterization of E-Waste, Using Analytical Techniques

    NASA Astrophysics Data System (ADS)

    López, C. Cortés; Cruz, V. E. Reyes; Rodríguez, M. A. Veloz; Ávila, J. Hernández; Badillo, J. Flores; Murcia, J. A. Cobos

    Electronic waste (e-waste), have a high potential as a source of precious metals, since they can contain metals like silver, gold, platinum, copper, zinc, nickel, tin and others. In this paper some e-waste were characterized using several analytical techniques as Scanning Electron Microscopy (SEM), X-ray diffraction (XRD) and inductively coupled plasma (ICP) in addition to the thermodynamic study by Pourbaix diagrams of silver (Ag), gold (Au), platinum (Pt), copper (Cu), nickel (Ni), tin (Sn) and zinc (Zn); considering an average low concentration of HNO3 (10% v/v). With results of the characterization was determined that the e-waste is an ideal source for the recovery of valuable metals. Similarly, the thermodynamic studies showed that it is possible to obtain all metallic species except Pt, in a potential window of 1.45V to 2.0V vs SCE.

  7. 40 CFR 761.260 - Applicability.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... Site Characterization Sampling for PCB Remediation Waste in Accordance with § 761.61(a)(2) § 761.260 Applicability. This subpart provides a method for collecting new data for characterizing a PCB remediation waste...

  8. Transshipment site selection using the AHP and TOPSIS approaches under fuzzy environment.

    PubMed

    Onüt, Semih; Soner, Selin

    2008-01-01

    Site selection is an important issue in waste management. Selection of the appropriate solid waste site requires consideration of multiple alternative solutions and evaluation criteria because of system complexity. Evaluation procedures involve several objectives, and it is often necessary to compromise among possibly conflicting tangible and intangible factors. For these reasons, multiple criteria decision-making (MCDM) has been found to be a useful approach to solve this kind of problem. Different MCDM models have been applied to solve this problem. But most of them are basically mathematical and ignore qualitative and often subjective considerations. It is easier for a decision-maker to describe a value for an alternative by using linguistic terms. In the fuzzy-based method, the rating of each alternative is described using linguistic terms, which can also be expressed as triangular fuzzy numbers. Furthermore, there have not been any studies focused on the site selection in waste management using both fuzzy TOPSIS (technique for order preference by similarity to ideal solution) and AHP (analytical hierarchy process) techniques. In this paper, a fuzzy TOPSIS based methodology is applied to solve the solid waste transshipment site selection problem in Istanbul, Turkey. The criteria weights are calculated by using the AHP.

  9. Alternative management structures for municipal waste collection services: The influence of economic and political factors

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Plata-Díaz, Ana María, E-mail: amplata@ugr.es; Zafra-Gómez, José Luis, E-mail: jlzafra@ugr.es; Pérez-López, Gemma, E-mail: gemmapl@ugr.es

    2014-11-15

    Highlights: • We analyzed the factors that influence on the restructuring of MSW services. • We evaluated five different alternatives for public and private service. • Our analysis covers a broad time horizon, 2002–2010. • We used a conditional fixed-effects logistic regression as the evaluation method. • Municipalities tend to contract out the MSW service in the presence of high costs and fiscal stress. - Abstract: Identifying and characterising the factors that determine why a local authority opts for a particular way of managing its waste collection service is an important issue, warranting research interest in the field of municipalmore » solid waste (MSW) management. This paper presents empirical evidence spanning a broad time horizon (2002–2010) showing that economic and political factors impact in different ways on the provision of waste management services. We examine five alternatives in this area, including public and private service delivery formulas and, within each field, individual and joint options. Our findings highlight the importance of the service cost and that of the various indicators of fiscal stress as determinant factors of management decisions regarding the provision of MSW management services.« less

  10. DOE Office of Scientific and Technical Information (OSTI.GOV)

    Onuet, Semih; Soner, Selin

    Site selection is an important issue in waste management. Selection of the appropriate solid waste site requires consideration of multiple alternative solutions and evaluation criteria because of system complexity. Evaluation procedures involve several objectives, and it is often necessary to compromise among possibly conflicting tangible and intangible factors. For these reasons, multiple criteria decision-making (MCDM) has been found to be a useful approach to solve this kind of problem. Different MCDM models have been applied to solve this problem. But most of them are basically mathematical and ignore qualitative and often subjective considerations. It is easier for a decision-maker tomore » describe a value for an alternative by using linguistic terms. In the fuzzy-based method, the rating of each alternative is described using linguistic terms, which can also be expressed as triangular fuzzy numbers. Furthermore, there have not been any studies focused on the site selection in waste management using both fuzzy TOPSIS (technique for order preference by similarity to ideal solution) and AHP (analytical hierarchy process) techniques. In this paper, a fuzzy TOPSIS based methodology is applied to solve the solid waste transshipment site selection problem in Istanbul, Turkey. The criteria weights are calculated by using the AHP.« less

  11. Multi-criteria analysis for municipal solid waste management in a Brazilian metropolitan area.

    PubMed

    Santos, Simone Machado; Silva, Maisa Mendonça; Melo, Renata Maciel; Gavazza, Savia; Florencio, Lourdinha; Kato, Mario T

    2017-10-15

    The decision-making process involved in municipal solid waste management (MSWM) must consider more than just financial aspects, which makes it a difficult task in developing countries. The Recife Metropolitan Region (RMR) in the Northeast of Brazil faces a MSWM problem that has been ongoing since the 1970s, with no common solution. In order to direct short-term solutions, three MSWM alternatives were outlined for the RMR, considering the current and future situations, the time and cost involved and social/environmental criteria. A multi-criteria approach, based on the Preference Ranking Organization Method for Enrichment Evaluations (PROMETHEE), was proposed to rank these alternatives. The alternative that included two private landfill sites and seven transfer, sorting and composting stations was confirmed as the most suitable and stable option for short-term MSWM, considering the two scenarios for the criteria weights. Sensitivity analysis was also performed to support the robustness of the results. The implementation of separate collections would minimize the amount of waste buried, while maximizing the useful life of landfill sites and increasing the timeframe of the alternative. Overall, the multi-criteria analysis was helpful and accurate during the alternative selection process, considering the similarities and restrictions of each option, which can lead to difficulties during the decision-making process.

  12. Feasibility study of tank leakage mitigation using subsurface barriers

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Treat, R.L.; Peters, B.B.; Cameron, R.J.

    1994-09-21

    The US Department of Energy (DOE) has established the Tank Waste Remediation System (TWRS) to satisfy manage and dispose of the waste currently stored in the underground storage tanks. The retrieval element of TWRS includes a work scope to develop subsurface impermeable barriers beneath SSTs. The barriers could serve as a means to contain leakage that may result from waste retrieval operations and could also support site closure activities by facilitating cleanup. Three types of subsurface barrier systems have emerged for further consideration: (1) chemical grout, (2) freeze walls, and (3) desiccant, represented in this feasibility study as a circulatingmore » air barrier. This report contains analyses of the costs and relative risks associated with combinations retrieval technologies and barrier technologies that from 14 alternatives. Eight of the alternatives include the use of subsurface barriers; the remaining six nonbarrier alternative are included in order to compare the costs, relative risks and other values of retrieval with subsurface barriers. Each alternative includes various combinations of technologies that can impact the risks associated with future contamination of the groundwater beneath the Hanford Site to varying degrees. Other potential risks associated with these alternatives, such as those related to accidents and airborne contamination resulting from retrieval and barrier emplacement operations, are not quantitatively evaluated in this report.« less

  13. MUNICIPAL WASTE COMBUSTION ASSESSMENT: MEDICAL WASTE COMBUSTION PRACTICES AT MUNICIPAL WASTE COMBUSTION FACILITIES

    EPA Science Inventory

    The report defines and characterizes types of medical waste, discusses the impacts of burning medical waste on combustor emissions, and outlines important handling and operating considerations. Facility-specific design, handling, and operating practiced are also discussed for mun...

  14. State of Practice for Emerging Waste Conversion Technologies

    EPA Science Inventory

    New technologies to convert municipal and other waste streams into fuels and chemical commodities, termed conversion technologies, are rapidly developing. Conversion technologies are garnering increasing interest and demand due primarily to alternative energy initiatives. These t...

  15. Phenotypic and genotypic characterization of clinically relevant bacteria isolated from dental waste and waste workers' hands, mucosas and coats.

    PubMed

    Tagliaferri, T L; Vieira, C D; de Carvalho, M A R; Ladeira, L C D; Magalhães, P P; de Macêdo Farias, L; Dos Santos, S G

    2017-10-01

    Infectious wastes are potential sources of pathogenic micro-organisms, which may represent a risk to the professionals who manage them. In this study, we aimed to characterize the infectious bacteria present in dental waste and waste workers. The dental waste produced over 24 h was collected and waste workers were sampled by swabbing. Isolate resistance profiles were characterized by Vitek ® and PCR and biofilm formation by Congo Red agar, string test and microtitre assay. To assess similarity between the waste and the workers' samples, a random amplified polymorphic DNA test was used. Twenty-eight bacteria were identified as clinically relevant. The most frequent gene was bla TEM present in five Gram-negative micro-organisms, and one bla SHV in Klebsiella pneumoniae. All Pseudomonas aeruginosa were positive to extracellular polymeric substances formation, except one isolated from a worker. Klebsiella pneumoniae had negative results for the string test. Pseudomonas aeruginosa showed better adherence at 25°C after 48 h of incubation and K. pneumonia had the best biofilm formation at the same temperature, after 24 h. The similarity between P. aeruginosa recovered from dental waste and from workers was low, however, it is important to note that a pathogen was found on a worker's hands and that improvements in biosafety are required. Infectious dental waste can contain clinically relevant bacteria with important resistance and biofilm profiles. These micro-organisms could be transmitted to waste workers, other professionals and patients if the principles of biosafety measures are neglected. To our knowledge, no study has ever evaluated the microbial characterization and the potential contamination risk of dental infectious waste and waste handlers. The presence of clinically relevant bacteria in the hands and nasal mucosa of waste workers highlights the need for studies in this field to clarify the risk of these pathogens in dental healthcare services, and to stress the need for an efficient waste management. © 2017 The Society for Applied Microbiology.

  16. Municipal Development of Anaerobic Digestion/ Combined Heat and Power in Massachusetts

    NASA Astrophysics Data System (ADS)

    Pike, Brenda

    With a commercial food waste ban going into effect in Massachusetts in October 2014, businesses, institutions, and municipalities are considering alternatives to landfills and incinerators for organic waste. Anaerobic digestion is one such alternative. Similar to composting, but in an environment devoid of oxygen, anaerobic digestion produces byproducts such as methane (which can be burned for heat or electricity) and liquid or solid digestate (which can be used as fertilizer, cattle bedding, and more). Thus, disposal of food waste and other organic materials can become a source of revenue rather than just an expense. Municipalities interested in developing anaerobic digestion/combined heat and power (AD/CHP) facilities have the benefit of desirable options for sites, such as landfill gas facilities and wastewater treatment plants, and potential feedstocks in source-separated residential or municipal food waste or wastewater. This thesis examines the opportunities and challenges for municipal development of AD/CHP facilities in Massachusetts.

  17. Should we pretreat solid waste prior to anaerobic digestion? An assessment of its environmental cost.

    PubMed

    Carballa, Marta; Duran, Cecilia; Hospido, Almudena

    2011-12-15

    Many studies have shown the effectiveness of pretreatments prior to anaerobic digestion of solid wastes, but to our knowledge, none analyzes their environmental consequences/costs. In this work, seven different pretreatments applied to two types of waste (kitchen waste and sewage sludge) have been environmentally evaluated by using life cycle assessment (LCA) methodology. The results show that the environmental burdens associated to the application of pretreatments prior to anaerobic digestion cannot be excluded. Among the options tested, the pressurize-depressurize and chemical (acid or alkaline) pretreatments could be recommended on the basis of their beneficial net environmental performance, while thermal and ozonation alternatives require energy efficiency optimization to reduce their environmental burdens. Reconciling operational, economic and environmental aspects in a holistic approach for the selection of the most sustainable option, mechanical (e.g., pressurize-depressurize) and chemical methods appear to be the most appropriate alternatives at this stage.

  18. WIPP waste characterization program sampling and analysis guidance manual

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Not Available

    1991-01-01

    The Waste Isolation Pilot Plant (WIPP) Waste Characterization Program Sampling and Analysis Guidance Manual (Guidance Manual) provides a unified source of information on the sampling and analytical techniques that enable Department of Energy (DOE) facilities to comply with the requirements established in the current revision of the Quality Assurance Program Plan (QAPP) for the WIPP Experimental-Waste Characterization Program (the Program). This Guidance Manual includes all of the sampling and testing methodologies accepted by the WIPP Project Office (DOE/WPO) for use in implementing the Program requirements specified in the QAPP. This includes methods for characterizing representative samples of transuranic (TRU) wastesmore » at DOE generator sites with respect to the gas generation controlling variables defined in the WIPP bin-scale and alcove test plans, as well as waste container headspace gas sampling and analytical procedures to support waste characterization requirements under the WIPP test program and the Resource Conservation and Recovery Act (RCRA). The procedures in this Guidance Manual are comprehensive and detailed and are designed to provide the necessary guidance for the preparation of site specific procedures. The use of these procedures is intended to provide the necessary sensitivity, specificity, precision, and comparability of analyses and test results. The solutions to achieving specific program objectives will depend upon facility constraints, compliance with DOE Orders and DOE facilities' operating contractor requirements, and the knowledge and experience of the TRU waste handlers and analysts. With some analytical methods, such as gas chromatography/mass spectrometry, the Guidance Manual procedures may be used directly. With other methods, such as nondestructive/destructive characterization, the Guidance Manual provides guidance rather than a step-by-step procedure.« less

  19. 77 FR 58416 - Comparative Environmental Evaluation of Alternatives for Handling Low-Level Radioactive Waste...

    Federal Register 2010, 2011, 2012, 2013, 2014

    2012-09-20

    ... NUCLEAR REGULATORY COMMISSION [NRC-2012-0218] Comparative Environmental Evaluation of Alternatives... public comment the Draft Comparative Environmental Evaluation of Alternatives for Handling Low-Level.... Availability of Documents ADAMS Accession No. Document title ML12256A965 Draft Comparative Environmental...

  20. 40 CFR 63.1219 - What are the replacement standards for hazardous waste incinerators?

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... Combustors Replacement Emissions Standards and Operating Limits for Incinerators, Cement Kilns, and... significant figures to document compliance. (e) Alternative to the particulate matter standard—(1) General. In... the following alternative metal emission control requirement: (2) Alternative metal emission control...

  1. 40 CFR 63.1219 - What are the replacement standards for hazardous waste incinerators?

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... Combustors Replacement Emissions Standards and Operating Limits for Incinerators, Cement Kilns, and... significant figures to document compliance. (e) Alternative to the particulate matter standard.—(1) General... with the following alternative metal emission control requirement: (2) Alternative metal emission...

  2. 40 CFR 268.46 - Alternative treatment standards based on HTMR.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 40 Protection of Environment 26 2010-07-01 2010-07-01 false Alternative treatment standards based on HTMR. 268.46 Section 268.46 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES (CONTINUED) LAND DISPOSAL RESTRICTIONS Treatment Standards § 268.46 Alternative treatment...

  3. Bioenergy and bioproducts from municipal organic waste as alternative to landfilling: a comparative life cycle assessment with prospective application to Mexico.

    PubMed

    Escamilla-Alvarado, Carlos; Poggi-Varaldo, Héctor M; Ponce-Noyola, M Teresa

    2017-11-01

    A life cycle assessment (LCA) of a four-stage biorefinery concept, coined H-M-Z-S, that converts 1 t of organic fraction of municipal solid waste (OFMSW) into bioenergy and bioproducts was performed in order to determine whether it could be an alternative to common disposal of OFMSW in landfills in the Mexican reality. The OFMSW is first fermented for hydrogen production, then the fermentates are distributed 40 % to the methane production, 40 % to enzyme production, and 20 % to the saccharification stage. From hydrogen and methane, up to 267 MJ and 204 kWh of gross heat and electricity were produced. The biorefinery proved to be self-sustainable in terms of power (95 kWh net power), but it presented a deficit of energy for heating services (-155 MJ), which was partially alleviated by digesting the wastes from the bioproducts stages (-84 MJ). Compared to landfill, biorefinery showed lower environmental impacts in global warming (down to -128 kg CO 2 -eq), ozone layer depletion (2.96 × 10 -6  kg CFC 11 -eq), and photochemical oxidation potentials (0.011 kg C 2 H 4 -eq). The landfarming of the digestates increased significantly the eutrophication impacts, up to 20 % below the eutrophication from landfilling (1.425 kg PO 4 -eq). These results suggest that H-M-Z-S biorefinery could be an attractive alternative compared to conventional landfilling for the management of municipal solid wastes, although new alternatives and uses of co-products and wastes should be explored and tested. Moreover, the biorefinery system would benefit from the integration into the market chain of the bioproducts, i.e., enzymes and hydrolysates among others.

  4. DOE Office of Scientific and Technical Information (OSTI.GOV)

    Not Available

    This volume contains appendices for the following: Rocky Flats Plant and Idaho National Engineering Laboratory waste process information; TRUPACT-II content codes (TRUCON); TRUPACT-II chemical list; chemical compatibility analysis for Rocky Flats Plant waste forms; chemical compatibility analysis for waste forms across all sites; TRU mixed waste characterization database; hazardous constituents of Rocky Flats Transuranic waste; summary of waste components in TRU waste sampling program at INEL; TRU waste sampling program; and waste analysis data.

  5. Characterization of the Old Hydrofracture Facility (OHF) waste tanks located at ORNL

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Keller, J.M.; Giaquinto, J.M.; Meeks, A.M.

    1997-04-01

    The Old Hydrofracture Facility (OHF) is located in Melton Valley within Waste Area Grouping (WAG) 5 and includes five underground storage tanks (T1, T2, T3, T4, and T9) ranging from 13,000 to 25,000 gal. capacity. During the period of 1996--97 there was a major effort to re-sample and characterize the contents of these inactive waste tanks. The characterization data summarized in this report was needed to address waste processing options, examine concerns dealing with the performance assessment (PA) data for the Waste Isolation Pilot Plant (WIPP), evaluate the waste characteristics with respect to the waste acceptance criteria (WAC) for WIPPmore » and Nevada Test Site (NTS), address criticality concerns, and to provide the data needed to meet DOT requirements for transporting the waste. This report discusses the analytical characterization data collected on both the supernatant and sludge samples taken from three different locations in each of the OHF tanks. The isotopic data presented in this report supports the position that fissile isotopes of uranium ({sup 233}U and {sup 235}U) do not satisfy the denature ratios required by the administrative controls stated in the ORNL LLLW waste acceptance criteria (WAC). The fissile isotope of plutonium ({sup 239}Pu and {sup 241}Pu) are diluted with thorium far above the WAC requirements. In general, the OHF sludge was found to be hazardous (RCRA) based on total metal content and the transuranic alpha activity was well above the 100 nCi/g limit for TRU waste. The characteristics of the OHF sludge relative to the WIPP WAC limits for fissile gram equivalent, plutonium equivalent activity, and thermal power from decay heat were estimated from the data in this report and found to be far below the upper boundary for any of the remote-handled transuranic waste (RH-TRU) requirements for disposal of the waste in WIPP.« less

  6. Study of plasma off-gas treatment from spent ion exchange resin pyrolysis.

    PubMed

    Castro, Hernán Ariel; Luca, Vittorio; Bianchi, Hugo Luis

    2017-03-23

    Polystyrene divinylbenzene-based ion exchange resins are employed extensively within nuclear power plants (NPPs) and research reactors for purification and chemical control of the cooling water system. To maintain the highest possible water quality, the resins are regularly replaced as they become contaminated with a range of isotopes derived from compromised fuel elements as well as corrosion and activation products including 14 C, 60 Co, 90 Sr, 129 I, and 137 Cs. Such spent resins constitute a major proportion (in volume terms) of the solid radioactive waste generated by the nuclear industry. Several treatment and conditioning techniques have been developed with a view toward reducing the spent resin volume and generating a stable waste product suitable for long-term storage and disposal. Between them, pyrolysis emerges as an attractive option. Previous work of our group suggests that the pyrolysis treatment of the resins at low temperatures between 300 and 350 °C resulted in a stable waste product with a significant volume reduction (>50%) and characteristics suitable for long-term storage and/or disposal. However, another important issue to take into account is the complexity of the off-gas generated during the process and the different technical alternatives for its conditioning. Ongoing work addresses the characterization of the ion exchange resin treatment's off-gas. Additionally, the application of plasma technology for the treatment of the off-gas current was studied as an alternative to more conventional processes utilizing oil- or gas-fired post-combustion chambers operating at temperatures in excess of 1000 °C. A laboratory-scale flow reactor, using inductively coupled plasma, operating under sub-atmospheric conditions was developed. Fundamental experiments using model compounds have been performed, demonstrating a high destruction and removal ratio (>99.99%) for different reaction media, at low reactor temperatures and moderate power consumption. The role of H 2 O as an important participant of the oxidation mechanisms in plasma conditions was established. The combination of both processes could represent a simple, safe, and effective alternative for treating spent ion exchange resins with a large reduction of generated gaseous byproducts in fuel cycle facilities where processes that utilize open flames are undesirable.

  7. Potential application of microsensor technology in radioactive waste management with emphasis on headspace gas detection.

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Davis, Chad Edward; Thomas, Michael Loren; Wright, Jerome L.

    2004-09-01

    Waste characterization is probably the most costly part of radioactive waste management. An important part of this characterization is the measurements of headspace gas in waste containers in order to demonstrate the compliance with Resource Conservation and Recovery Act (RCRA) or transportation requirements. The traditional chemical analysis methods, which include all steps of gas sampling, sample shipment and laboratory analysis, are expensive and time-consuming as well as increasing worker's exposure to hazardous environments. Therefore, an alternative technique that can provide quick, in-situ, and real-time detections of headspace gas compositions is highly desirable. This report summarizes the results obtained from amore » Laboratory Directed Research & Development (LDRD) project entitled 'Potential Application of Microsensor Technology in Radioactive Waste Management with Emphasis on Headspace Gas Detection'. The objective of this project is to bridge the technical gap between the current status of microsensor development and the intended applications of these sensors in nuclear waste management. The major results are summarized below: {sm_bullet} A literature review was conducted on the regulatory requirements for headspace gas sampling/analysis in waste characterization and monitoring. The most relevant gaseous species and the related physiochemical environments were identified. It was found that preconcentrators might be needed in order for chemiresistor sensors to meet desired detection {sm_bullet} A long-term stability test was conducted for a polymer-based chemresistor sensor array. Significant drifts were observed over the time duration of one month. Such drifts should be taken into account for long-term in-situ monitoring. {sm_bullet} Several techniques were explored to improve the performance of sensor polymers. It has been demonstrated that freeze deposition of black carbon (CB)-polymer composite can effectively eliminate the so-called 'coffee ring' effect and lead to a desirable uniform distribution of CB particles in sensing polymer films. The optimal ratio of CB/polymer has been determined. UV irradiation has been shown to improve sensor sensitivity. {sm_bullet} From a large set of commercially available polymers, five polymers were selected to form a sensor array that was able to provide optimal responses to six target-volatile organic compounds (VOCs). A series of tests on the response of sensor array to various VOC concentrations have been performed. Linear sensor responses have been observed over the tested concentration ranges, although the responses over a whole concentration range are generally nonlinear. {sm_bullet} Inverse models have been developed for identifying individual VOCs based on sensor array responses. A linear solvation energy model is particularly promising for identifying an unknown VOC in a single-component system. It has been demonstrated that a sensor array as such we developed is able to discriminate waste containers for their total VOC concentrations and therefore can be used as screening tool for reducing the existing headspace gas sampling rate. {sm_bullet} Various VOC preconcentrators have been fabricated using Carboxen 1000 as an absorbent. Extensive tests have been conducted in order to obtain optimal configurations and parameter ranges for preconcentrator performance. It has been shown that use of preconcentrators can reduce the detection limits of chemiresistors by two orders of magnitude. The life span of preconcentrators under various physiochemical conditions has also been evaluated. {sm_bullet} The performance of Pd film-based H2 sensors in the presence of VOCs has been evaluated. The interference of sensor readings by VOC has been observed, which can be attributed to the interference of VOC with the H2-O2 reaction on the Pd alloy surface. This interference can be eliminated by coating a layer of silicon dioxide on sensing film surface. Our work has demonstrated a wide range of applications of gas microsensors in radioactive waste management. Such applications can potentially lead to a significant cost saving and risk reduction for waste characterization.« less

  8. A facile hydrothermal recovery of nano sealed MnO2 particle from waste batteries: An advanced material for electrochemical and environmental applications

    NASA Astrophysics Data System (ADS)

    Mylarappa, M.; Venkata Lakshmi, V.; Vishnu Mahesh, K. R.; Nagaswarupa, H. P.; Raghavendra, N.

    2016-09-01

    This work deliberates a method for manganese (Mn) recovery as manganese oxide obtained by leaching of waste batteries with 3M sulphuric acid. The Experimental test for the recovery of Mn present within the waste dry cell batteries were carried out by a reductive leachant. Elemental composition of leached sample was confirmed by Energy Dispersive X-ray analysis (EDAX), and Surface morphology of the recovered MnO2 was examined by using Scanning Electron microscopy (SEM). Phase composition was confirmed from X-ray Diffractro meter (XRD). The obtained leached solution was treated with 4M NaOH, yielded to Manganese Dioxide with high extraction degree, while it do not touches the Zn content within the solutions. The recovered samples were characterized using XRD, EDAX, SEM and Fourier transform infrared spectrometry (FTIR). The electrochemical properties of the as-recovered sample from leached solution was examined used cyclic voltammetry (CV) and electrochemical impedance spectroscopy (EIS). Remarkably, the 80 wt.% MnO2 displays reversibility, diffusion constant, smaller equivalent series resistance and charge transfer resistance in 0.5M NaOH showed superior results as compared to alternative electrolytes. The ideal capacitive behaviour of MnO2 electrode and nano particle was applied to photocatalytic degradation of dyes.

  9. Environmental Measurement-While-Drilling System and Horizontal Directional Drilling Technology Demonstration, Hanford Site

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Williams, C.V.; Lockwood, G.J.; Normann, R.A.

    1999-06-01

    The Environmental Measurement-While-Drilling (EMWD) system and Horizontal Directional Drilling (HDD) were successfully demonstrated at the Mock Tank Leak Simulation Site and the Drilling Technology Test Site, Hanford, Washington. The use of directional drilling offers an alternative to vertical drilling site characterization. Directional drilling can develop a borehole under a structure, such as a waste tank, from an angled entry and leveling off to horizontal at the desired depth. The EMWD system represents an innovative blend of new and existing technology that provides the capability of producing real-time environmental and drill bit data during drilling operations. The technology demonstration consisted ofmore » the development of one borehole under a mock waste tank at a depth of {approximately} {minus}8 m ({minus}27 ft.), following a predetermined drill path, tracking the drill path to within a radius of {approximately}1.5 m (5 ft.), and monitoring for zones of radiological activity using the EMWD system. The purpose of the second borehole was to demonstrate the capability of drilling to a depth of {approximately} {minus}21 m ({minus}70 ft.), the depth needed to obtain access under the Hanford waste tanks, and continue drilling horizontally. This report presents information on the HDD and EMWD technologies, demonstration design, results of the demonstrations, and lessons learned.« less

  10. The slag original from the process of sewage sludge incineration selected properties characteristic

    NASA Astrophysics Data System (ADS)

    Głowacka, Anna; Rucińska, Teresa; Kiper, Justyna

    2017-11-01

    This work characterizes the physical and chemical properties of slag from combustion of municipal sewage sludge in "Pomorzany" waste treatment plant in Szczecin. The technology of sludge management is based on drying the sludge in low-temperature belt driers, to a content level of at least 90%, dry mass., and then burning in a grate boiler with mobile grate. The research of the slag resulting from combustion of municipal sewage sludge was conducted using reference methods, presenting images from a scanning electron microscope. The tested waste contained from 16.300 to 23.150% P2O5 completely soluble in strong acids, pH 8.03, mineral substance 98.73% dry mass. The content of heavy metals did not exceed the permissible amount specified in the Regulation of the Minister of Agriculture and Rural Development of 18 June 2008 on the implementation of certain provisions of the Act on fertilizers and fertilization (Journal of Laws of 2008 No. 119, item. 765). The screening trials showed that 48.4% are fractions of 630 µm-1.25 mm. The results show that the waste code 19 01 12 may be used as: alternative source of phosphorus for direct application to soil treatment, for production of organic - mineral fertilizers and as construction aggregate for production of concrete mortars.

  11. Ion exchangers in radioactive waste management: natural Iranian zeolites.

    PubMed

    Nilchi, A; Maalek, B; Khanchi, A; Ghanadi Maragheh, M; Bagheri, A; Savoji, K

    2006-01-01

    Five samples of natural zeolites from different parts of Iran were chosen for this study. In order to characterize and determine their structures, X-ray diffraction and infrared spectrometry were carried out for each sample. The selective absorption properties of each zeolite were found by calculating the distribution coefficient (K(d)) of various simulated wastes which were prepared by spiking the radionuclides with (131)I, (99)Mo, (153)Sm, (140)La and (147)Nd. All the zeolite samples used in this study had extremely high absorption value towards (140)La; clinoptolite from Mianeh and analsite from Ghalehkhargoshi showed good absorption for (147)Nd; clinoptolite from Semnan and clinoptolite from Firozkoh showed high absorption for (153)Sm; mesolite from Arababad Tabas showed good absorption for (99)Mo; and finally mesolite from Arababad Tabas, clinoptolite from Semnan and clinoptolite from Firozkoh could be used to selectively absorb (131)I from the stimulated waste which was prepared. The natural zeolites chosen for these studies show a similar pattern to those synthetic ion exchangers in the literature and in some cases an extremely high selectivity towards certain radioactive elements. Hence the binary separation of radioactive elements could easily be carried out. Furthermore, these zeolites, which are naturally occurring ion exchangers, are viable economically and extremely useful alternatives in this industry.

  12. Low-level radioactive waste management: transitioning to off-site disposal at Los Alamos National Laboratory

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Dorries, Alison M

    2010-11-09

    Facing the closure of nearly all on-site management and disposal capability for low-level radioactive waste (LLW), Los Alamos National Laboratory (LANL) is making ready to ship the majority of LLW off-site. In order to ship off-site, waste must meet the Treatment, Storage, and Disposal Facility's (TSDF) Waste Acceptance Criteria (WAC). In preparation, LANL's waste management organization must ensure LANL waste generators characterize and package waste compliantly and waste characterization documentation is complete and accurate. Key challenges that must be addressed to successfully make the shift to off-site disposal of LLW include improving the detail, accuracy, and quality of process knowledgemore » (PK) and acceptable knowledge (AK) documentation, training waste generators and waste management staff on the higher standard of data quality and expectations, improved WAC compliance for off-site facilities, and enhanced quality assurance throughout the process. Certification of LANL generators will allow direct off-site shipping of LLW from their facilities.« less

  13. MICRO AUTO GASIFICATION SYSTEM: EMISSIONS ...

    EPA Pesticide Factsheets

    A compact, CONEX-housed waste to energy unit, Micro Auto Gasification System (MAGS), was characterized for air emissions from burning of military waste types. The MAGS unit is a dual chamber gasifier with a secondary diesel-fired combustor. Eight tests were conducted with multiple waste types in a 7-day period at the Kilauea Military Camp in Hawai’i. The emissions characterized were chosen based on regulatory emissions limits as well as their ability to cause adverse health effects on humans: particulate matter (PM), mercury, heavy metals, volatile organic compounds (VOCs), polyaromatic hydrocarbons (PAHs), and polychlorinated dibenzo-p-dioxins (PCDDs) and polychlorinated dibenzofurans (PCDFs). Three military waste feedstock compositions reflecting the variety of wastes to be encountered in theatre were investigated: standard waste (SW), standard waste with increased plastic content (HP), standard waste without SW food components but added first strike ration (FSR) food and packaging material (termed FSR). A fourth waste was collected from the Kilauea dumpster that served the dining facility and room lodging (KMC). Limited scrubber water and solid ash residue samples were collected to obtain a preliminary characterization of these effluents/residues.Gasifying SW, HP, and KMC resulted in similar PCDD/PCDF stack concentrations, 0.26-0.27 ng TEQ/m3 at 7% O2, while FSR waste generated a notably higher stack concentration of 0.68 ng TEQ/m3 at 7% O2. The PM emission

  14. Characterization of the MVST waste tanks located at ORNL

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Keller, J.M.; Giaquinto, J.M.; Meeks, A.M.

    During the fall of 1996 there was a major effort to sample and analyze the Active Liquid Low-Level Waste (LLLW) tanks at ORNL which include the Melton Valley Storage Tanks (MVST) and the Bethel Valley Evaporator Service Tanks (BVEST). The characterization data summarized in this report was needed to address waste processing options, address concerns of the performance assessment (PA) data for the Waste Isolation Pilot Plant (WIPP), evaluate the characteristics with respect to the waste acceptance criteria (WAC) for WIPP and Nevada Test Site (NTS), address criticality concerns, and meet DOT requirements for transporting the waste. This report onlymore » discusses the analytical characterization data for the MVST waste tanks. The isotopic data presented in this report support the position that fissile isotopes of uranium and plutonium were ``denatured`` as required by administrative controls. In general, MVST sludge was found to be both hazardous by RCRA characteristics and the transuranic alpha activity was well about the limit for TRU waste. The characteristics of the MVST sludge relative to the WIPP WAC limits for fissile gram equivalent, plutonium equivalent activity, and thermal power from decay heat, were estimated from the data in this report and found to be far below the upper boundary for any of the remote-handled transuranic waste requirements for disposal of the waste in WIPP.« less

  15. MELiSSA Food Characterization general approach and current status

    NASA Astrophysics Data System (ADS)

    Weihreter, Martin; Chaerle, Laury; Secco, Benjamin; Molders, Katrien; van der Straeten, Dominique; Duliere, Eric; Pieters, Serge; Maclean, Heather; Dochain, Denis; Quinet, Muriel; Lutts, Stanley; Graham, Thomas; Stasiak, Michael; Rondeau Vuk, Theresa; Zheng, Youbin; Dixon, Mike; Laniau, Martine; Larreture, Alain; Timsit, Michel; Aronne, Giovanna; Barbieri, Giancarlo; Buonomo, Roberta; Veronica; Paradiso, Roberta; de Pascale, Stafania; Galbiati, Massimo; Troia, A. R.; Nobili, Matteo; Bucchieri, Lorenzo; Page, Valérie; Feller, Urs; Lasseur, Christophe

    Higher plants play an important role in closed ecological life support systems as oxygen pro-ducers, carbon dioxide and water recyclers, and as a food source. For an integration of higher plant chambers into the MELiSSA (Micro Ecological Life Support System Alternative) loop, a detailed characterization and optimization of the full food production and preparation chain is needed. This implies the prediction and control of the nutritional quality of the final products consumed by the crew, the prediction of the wastes quality and quantity produced along the chain for further waste treatment (MELiSSA waste treatment) and the optimization of overall efficiencies. To reach this goal several issues have to be studied in an integrated manner: the physiological responses of crops to a range of environmental parameters, crop yield efficiencies and respective ratio and composition of edible and inedible biomass, the processability and storability of the produced food and last but not least composition of wastes in view of further degradation (fiber content). Within the Food Characterization (FC) project several compar-ative plant growth bench tests were carried out to obtain preliminary data regarding these aspects. Four pre-selected cultivars of each of the four energy-rich crops with worldwide usage -wheat, durum wheat, potato and soybean -were grown under well-characterized environmental conditions. The different cultivars of each species are screened for their performance in view of a closed loop application by parameter ranking. This comprises the characterization of edi-ble/inedible biomass ratio, nutritional quality, processability and overall performance under the specific conditions of hydroponic cultivation and artificial illumination. A second closely linked goal of the FC project is to develop a mechanistic physiological plant model, which will ease the integration of higher plants compartments in the MELiSSA concept by virtue of its predictive abilities. Available MELiSSA closed environment crop growth data were used to develop a first photosynthetic model representing the basic carbon fixation mechanisms. This model will be further elaborated in the course of this study to predict yield, oxygen production and transpi-ration. As an ultimate goal the model is intended to simulate the composition of the different plant organs (root, shoot, fruit/seed or tuber) for each crop under various conditions. For the validation of this model an extensive amount of data sets are needed. Current plant growth bench test setups will provide part of the required data. To gain more precise and detailed datasets, a highly closed plant growth chamber (Plant Characterization Unit, PCU) is under development. The PCU will provide accurate mass balances for carbon, water, oxygen and other elements with statistical reliability. This reliability is achieved through a high degree of closure and environment homogeneity. The PCU will also provide data for the above described plant characterization studies. The general work approach, the current status and future steps will be illustrated.

  16. Waste Generation Overview Refresher, Course 21464

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Simpson, Lewis Edward

    This course, Waste Generation Overview Refresher (COURSE 21464), provides an overview of federal and state waste management regulations, as well as Los Alamos National Laboratory (LANL) policies and procedures for waste management operations. The course covers the activities involved in the cradle-to- grave waste management process and focuses on waste characterization, waste compatibility determinations and classification, and the storage requirements for temporary waste accumulation areas at LANL.

  17. A system dynamics approach for healthcare waste management: a case study in Istanbul Metropolitan City, Turkey.

    PubMed

    Ciplak, Nesli; Barton, John R

    2012-06-01

    Healthcare waste consists of various types of waste materials generated at hospitals, medical research centres, clinics and laboratories. Although 75-90% of this waste is classified as 'domestic' in nature, 20-25% is deemed to be hazardous, which if not disposed of appropriately, poses a risk to healthcare workers, patients, the environment and even the whole community. As long as healthcare waste is mixed with municipal waste and not segregated prior to disposal, costs will increase substantially. In this study, healthcare waste increases along with the potential to decrease the amounts by implementing effective segregation at healthcare facilities are projected to 2040. Our long-term aim is to develop a system to support selection and planning of the future treatment capacity. Istanbul in Turkey was used as the case study area. In order to identify the factors affecting healthcare waste generation in Istanbul, observations were made and interviews conducted in Istanbul over a 3 month period. A system dynamics approach was adopted to build a healthcare waste management model using a software package, Vensim Ple Plus. Based on reported analysis, the non-hazardous municipal fraction co-disposed with healthcare waste is around 65%. Using the projected waste generation flows, reducing a municipal fraction to 30% has the potential to avoid some 8000 t year(-1) of healthcare waste by 2025 and almost 10 000 t year(-1) by 2035. Furthermore, if segregation practices ensured healthcare waste requiring incineration was also selectively managed, 77% of healthcare waste could be diverted to alternative treatment technologies. As the throughput capacity of the only existing healthcare waste treatment facility in Istanbul, Kemerburgaz Incinerator, has already been exceeded, it is evident that improved management could not only reduce overall flows and costs but also permit alternative and cheaper treatment systems (e.g. autoclaving) to be adopted for the healthcare waste.

  18. Ceramics in nuclear waste management

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Chikalla, T D; Mendel, J E

    1979-05-01

    Seventy-three papers are included, arranged under the following section headings: national programs for the disposal of radioactive wastes, waste from stability and characterization, glass processing, ceramic processing, ceramic and glass processing, leaching of waste materials, properties of nuclear waste forms, and immobilization of special radioactive wastes. Separate abstracts were prepared for all the papers. (DLC)

  19. Waste Treatment and Immobilization Plant U. S. Department of Energy Office of River Protection Submerged Bed Scrubber Condensate Disposition Project - 13460

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Yanochko, Ronald M.; Corcoran, Connie

    The Hanford Waste Treatment and Immobilization Plant (WTP) will generate an off-gas treatment system secondary liquid waste stream [submerged bed scrubber (SBS) condensate], which is currently planned for recycle back to the WTP Low Activity Waste (LAW) melter. This SBS condensate waste stream is high in Tc-99, which is not efficiently captured in the vitrified glass matrix [1]. A pre-conceptual engineering study was prepared in fiscal year 2012 to evaluate alternate flow paths for melter off-gas secondary liquid waste generated by the WTP LAW facility [2]. This study evaluated alternatives for direct off-site disposal of this SBS without pre-treatment, whichmore » mitigates potential issues associated with recycling. This study [2] concluded that SBS direct disposal is a viable option to the WTP baseline. The results show: - Off-site transportation and disposal of the SBS condensate is achievable and cost effective. - Reduction of approximately 4,325 vitrified WTP Low Activity Waste canisters could be realized. - Positive WTP operational impacts; minimal WTP construction impacts are realized. - Reduction of mass flow from the LAW Facility to the Pretreatment Facility by 66%. - Improved Double Shell Tank (DST) space management is a benefit. (authors)« less

  20. Waste Sampling & Characterization Facility (WSCF) Complex Safety Analysis

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    MELOY, R.T.

    2002-04-01

    This document was prepared to analyze the Waste Sampling and Characterization Facility for safety consequences by: Determining radionuclide and highly hazardous chemical inventories; Comparing these inventories to the appropriate regulatory limits; Documenting the compliance status with respect to these limits; and Identifying the administrative controls necessary to maintain this status. The primary purpose of the Waste Sampling and Characterization Facility (WSCF) is to perform low-level radiological and chemical analyses on various types of samples taken from the Hanford Site. These analyses will support the fulfillment of federal, Washington State, and Department of Energy requirements.

  1. Assessing recycling versus incineration of key materials in municipal waste: The importance of efficient energy recovery and transport distances.

    PubMed

    Merrild, Hanna; Larsen, Anna W; Christensen, Thomas H

    2012-05-01

    Recycling of materials from municipal solid waste is commonly considered to be superior to any other waste treatment alternative. For the material fractions with a significant energy content this might not be the case if the treatment alternative is a waste-to-energy plant with high energy recovery rates. The environmental impacts from recycling and from incineration of six material fractions in household waste have been compared through life cycle assessment assuming high-performance technologies for material recycling as well as for waste incineration. The results showed that there are environmental benefits when recycling paper, glass, steel and aluminium instead of incinerating it. For cardboard and plastic the results were more unclear, depending on the level of energy recovery at the incineration plant, the system boundaries chosen and which impact category was in focus. Further, the environmental impact potentials from collection, pre-treatment and transport was compared to the environmental benefit from recycling and this showed that with the right means of transport, recyclables can in most cases be transported long distances. However, the results also showed that recycling of some of the material fractions can only contribute marginally in improving the overall waste management system taking into consideration their limited content in average Danish household waste. Copyright © 2012 Elsevier Ltd. All rights reserved.

  2. Recycling and reuse of waste from electricity distribution networks as reinforcement agents in polymeric composites.

    PubMed

    Zimmermann, Matheus V G; Zattera, Ademir J

    2013-07-01

    Of the waste generated from electricity distribution networks, wooden posts treated with chromated copper arsenate (CCA) and ceramic insulators make up the majority of the materials for which no effective recycling scheme has been developed. This study aims to recycle and reuse this waste as reinforcement elements in polymer composites and hybrid composites, promoting an ecologically and economically viable alternative for the disposal of this waste. The CCA wooden posts were cut, crushed and recycled via acid leaching using 0.2 and 0.4N H2SO4 in triplicate at 70°C and then washed and dried. The ceramic insulators were fragmented in a hydraulic press and separated by particle size using a vibrating sieve. The composites were mixed in a twin-screw extruder and injected into the test specimens, which were subjected to physical, mechanical, thermal and morphological characterization. The results indicate that the acid treatment most effective for removing heavy metals in the wood utilizes 0.4NH2SO4. However, the composites made from wood treated with 0.2NH2SO4 exhibited the highest mechanical properties of the composites, whereas the use of a ceramic insulator produces composites with better thermal stability and impact strength. This study is part of the research and development project of ANEEL (Agência Nacional de Energia Elétrica) and funded by CPFL (Companhia Paulista de Força e Luz). Copyright © 2013 Elsevier Ltd. All rights reserved.

  3. Changing Waste in Changing Times: Solid Waste and Natural Resource Issues in Rural Alaska--A Teacher's Guide.

    ERIC Educational Resources Information Center

    Moses, Shirley

    This guide was developed to present activities which inform the teacher and students of solid waste management problems that are becoming commonplace in villages. The lessons included present alternatives for taking care of the environment and contains methods to make not only school children more sensitive to environmental problems, but hopefully…

  4. Centralized treatment of industrial wastes

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Saltzberg, E.R.

    1982-08-01

    A low-cost and effective alternative to on-site treatment of industrial wastes which can be used by firms in many areas of the country is described. Under the CWT approach, firms send their wastes to a common processing plant. In the right situations and with the proper kind of inexpensive retrofitting measures, CWT can drastically reduce the cost of treating industrial wastewater because of economies of scale. As well as saving money, CWT has several environmental advantages. First, these facilities are operated by professional waste handlers who should be able to treat and manage the waste more effectively than the generatingmore » firms. Second, the CWT can dramatically increase the potential for recovery of chemicals, which not only reduces the firm's wastewater costs but also the burdens of sludge handling and disposal. EPA, consultants, and local communities have been working on this concept for the last three years. During that time, they have been studying the feasibility of several CWT alternatives already in use in foreign countries for treating electroplating wastewater. In addition to waste treatment, CWT can also provide cogeneration of power, common laboratory facilities and, probably a bulk purchasing cooperative. 3 figures. (JMT)« less

  5. 40 CFR 61.351 - Alternative standards for tanks.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 40 Protection of Environment 9 2014-07-01 2014-07-01 false Alternative standards for tanks. 61.351... Waste Operations § 61.351 Alternative standards for tanks. (a) As an alternative to the standards for tanks specified in § 61.343 of this subpart, an owner or operator may elect to comply with one of the...

  6. 40 CFR 61.351 - Alternative standards for tanks.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 40 Protection of Environment 9 2013-07-01 2013-07-01 false Alternative standards for tanks. 61.351... Waste Operations § 61.351 Alternative standards for tanks. (a) As an alternative to the standards for tanks specified in § 61.343 of this subpart, an owner or operator may elect to comply with one of the...

  7. Force Provider Solid Waste Characterization Study

    DTIC Science & Technology

    2004-08-01

    energy converter (WEC) and/or composter . For a five-day period in June 2000, the solid waste generated by soldiers at the Force Provider Training Module...MATERIALS REDUCTION WASTE DISPOSAL MILITARY FACILITIES SANITARY ENGINEERING DISPOSAL FORCE PROVIDER FIELD FEEDING COMPOSTS WASTES GARBAGE WASTE RECYCLING...waste reduction through onsite waste-to-energy conversion and/or composting . The work was performed by Hughes Associates, Inc., 3610 Commerce

  8. 40 CFR 761.326 - Conducting the comparison study.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 40 Protection of Environment 30 2010-07-01 2010-07-01 false Conducting the comparison study. 761...-liquid PCB Remediation Waste Samples § 761.326 Conducting the comparison study. Extract or analyze the comparison study samples using the alternative method. For an alternative extraction method or alternative...

  9. 40 CFR 761.326 - Conducting the comparison study.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 40 Protection of Environment 31 2011-07-01 2011-07-01 false Conducting the comparison study. 761...-liquid PCB Remediation Waste Samples § 761.326 Conducting the comparison study. Extract or analyze the comparison study samples using the alternative method. For an alternative extraction method or alternative...

  10. 40 CFR 61.353 - Alternative means of emission limitation.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... for Benzene Waste Operations § 61.353 Alternative means of emission limitation. (a) If, in the Administrator's judgment, an alternative means of emission limitation will achieve a reduction in benzene emissions at least equivalent to the reduction in benzene emissions from the source achieved by the...

  11. Challenges to diagnosis of HIV-associated wasting.

    PubMed

    Kotler, Donald

    2004-12-01

    There is a wide variability in the clinical presentation of the protein energy malnutrition often characterized as wasting in patients infected with HIV. Moreover, the clinical presentation has evolved over time. Initially, protein energy malnutrition was characterized by profound weight loss and depletion of body cell mass (BCM). Recently, unrelated concurrent metabolic abnormalities, such as lipodystrophy, may complicate the diagnosis of HIV wasting. Although measures of BCM are relatively accurate for the diagnosis of HIV wasting, the optimal tools for assessing BCM are not necessarily available to the clinician. From the practical standpoint, HIV wasting may be a self-evident diagnosis in advanced stages, but effective interpretation of the early signs of HIV wasting requires familiarity with other complications included in the differential diagnosis.

  12. Activation and characterization of waste coffee grounds as bio-sorbent

    NASA Astrophysics Data System (ADS)

    Mariana; Marwan; Mulana, F.; Yunardi; Ismail, T. A.; Hafdiansyah, M. F.

    2018-03-01

    As the city well known for its culture of coffee drinkers, modern and traditional coffee shops are found everywhere in Banda Aceh, Indonesia. High number of coffee shops in the city generates large quantities of spent coffee grounds as waste without any effort to convert them as other valuable products. In an attempt to reduce environmental problems caused by used coffee grounds, this research was conducted to utilize waste coffee grounds as an activated carbon bio-sorbent. The specific purpose of this research is to improve the performance of coffee grounds bio-sorbent through chemical and physical activation, and to characterize the produced bio-sorbent. Following physical activation by carbonization, a chemical activation was achieved by soaking the carbonized waste coffee grounds in HCl solvent and carbonization process. The activated bio-sorbent was characterized for its morphological properties using Scanning Electron Microscopy (SEM), its functional groups by Fourier Transform Infra-Red Spectrophotometer (FTIR), and its material characteristics using X-Ray Diffraction (XRD). Characterization of the activated carbon prepared from waste coffee grounds shows that it meets standard quality requirement in accordance with Indonesian National Standard, SNI 06-3730-1995. Activation process has modified the functional groups of the waste coffee grounds. Comparing to natural waste coffee grounds, the resulted bio-sorbent demonstrated a more porous surface morphology following activation process. Consequently, such bio-sorbent is a potential source to be used as an adsorbent for various applications.

  13. Invention, design and performance of coconut agrowaste fiberboards for ecologically efficacious buildings

    NASA Astrophysics Data System (ADS)

    Lokko, Mae-ling Jovenes

    As global quantities of waste by-products from food production as well as the range of their applications increase, researchers are realizing critical opportunities to transform the burden of underutilized wastes into ecological profits. Within the tropical hot-humid region, where half the world's current and projected future population growth is concentrated, there is a dire demand for building materials to meet ambitious development schemes and rising housing deficits. However, the building sector has largely overlooked the potential of local agricultural wastes to serve as alternatives to energy-intensive, imported building technologies. Industrial ecologists have recently investigated the use of agrowaste biocomposites to replace conventional wood products that use harmful urea-formaldehyde, phenolic and isocyanate resins. Furthermore, developments in the performance of building material systems with respect to cost, energy, air quality management and construction innovation have evolved metrics about what constitutes material 'upcycling' within building life cycle. While these developments have largely been focused on technical and cost performance, much less attention has been paid to addressing deeply-seated social and cultural barriers to adoption that have sedimented over decades of importation. This dissertation evaluates the development coconut agricultural building material systems in four phases: (i) non-toxic, low-energy production of medium-high density boards (500-1200 kg/m3) from coconut fibers and emerging biobinders; (ii) characterization and evaluation of coconut agricultural building materials hygrothermal performance (iii) scaled-up design development of coconut modular building material systems and (iv) development of a value translation framework for the bottom-up distribution of value to stakeholders within the upcycling framework. This integrated design methodological approach is significant to develop ecological thinking around agrowaste building materials, influence social and cultural acceptability and create value translation frameworks that sufficiently characterize the composite value proposition of upcycled building systems.

  14. Laser ablation/ionization characterization of solids: Second interim progress report of the strategic environmental research development program

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Hess, W.P.; Bushaw, B.A.; McCarthy, M.I.

    1996-10-01

    The Department of Energy is undertaking the enormous task of remediating defense wastes and environmental insults which have occurred over 50 years of nuclear weapons production. It is abundantly clear that significant technology advances are needed to characterize, process, and store highly radioactive waste and to remediate contaminated zones. In addition to the processing and waste form issues, analytical technologies needed for the characterization of solids, and for monitoring storage tanks and contaminated sites do not exist or are currently expensive labor-intensive tasks. This report describes progress in developing sensitive, rapid, and widely applicable laser-based mass spectrometry techniques for analysismore » of mixed chemical wastes and contaminated soils.« less

  15. Status of waste tyres and management practice in Botswana.

    PubMed

    Mmereki, Daniel; Machola, Bontle; Mokokwe, Kentlafetse

    2017-02-22

    Waste tyres (WTs) are becoming a significant environmental, economical and technological challenge due to their high contents of combustible composition and potential for valuable materials and energy resources. Fewer studies in developing and even developed countries have been carried out to assess the challenges regarding waste tyres management, and suggested the best alternative solutions for managing this waste stream. While developed countries made progress in waste tyres management needs by implementing more efficient innovative recovery and recycling methods, and restrictive regulations regarding the management of used tyres, in many developing countries the management of waste tyres has not received adequate interest, and the processing, treatment and disposal of waste tyre is still nascent. In recent years, worldwide, several methods for managing used tyres, including other principal alternatives for managing end-of-life tyres defined in the 4Rs, reduction, re-use, recovery and recycling have been adopted and applied to minimize serious threats to both the natural environment environment and human. The paper attempted to establish stakeholders' action that has the responsibility in waste tyre management in Botswana. This study also analyzed important aspects on waste tyres management in Botswana. A synthesis of approaches was employed in the present investigation to determine the factors influencing effective performance of waste tyres management practice in Botswana. Data for the present study was obtained using relevant published literature, scientific journals, other third sector sources, academic sources, and research derived from governments and other agencies and field observations. Group discussions with the participants and semi-structured interviews with professionals were carried out. The outcomes of this investigation are a wide-range outline concerning the participants that are important in waste tyres management, and a set of aspects affecting the management of waste tyres. The information provided by this study is very critical for reviewing and updating the methods and tools to update waste tyres data and trends to improve waste tyres management efficiency, suggesting innovative methods of recovering and recycling this waste stream in Botswana.

  16. Reclamation of landfills and dumps of municipal solid waste in a energy efficient waste management system: methodology and practice

    NASA Astrophysics Data System (ADS)

    Orlova, Tatyana; Melnichuk, Aleksandr; Klimenko, Kseniya; Vitvitskaya, Valentina; Popovych, Valentina; Dunaieva, Ielizaveta; Terleev, Vitaly; Nikonorov, Aleksandr; Togo, Issa; Volkova, Yulia; Mirschel, Wilfried; Garmanov, Vitaly

    2017-10-01

    The article considers the methodological and practical aspects of reclamation of landfills and dumps of municipal solid waste in a waste management system. The general tendencies of system development in the context of elements of the international concept of waste hierarchy are analyzed. Statistics of the formation and burial of domestic waste indicate a strategic non-alternative to the rejection of landfill technologies in favor of environmentally, energy efficient and economically expedient ways of utilization of municipal waste as a world trend. Practical approaches to the study of territories on which there are dumps and landfills are considered to justify the design solutions for reclamation.

  17. Evaluation of composting as a strategy for managing organic wastes from a municipal market in Nicaragua.

    PubMed

    Aulinas Masó, Montserrat; Bonmatí Blasi, August

    2008-07-01

    A pilot-scale study was undertaken to evaluate alternatives to the solid waste management of a Central American municipal market located in Estelí, Nicaragua. The municipal solid waste from the local market is the second largest contributor to the municipal solid waste (MSW) stream. Waste from the market without any previous sorting or treatment is open dumped. The options evaluated in this study were windrow composting, windrow composting with yard waste, bokashi and vermicompost. Significant differences between the properties of composts produced were found; however, all of them reduce the initial waste volume and are potential useful agronomic products for a survival agrarian milieu.

  18. Nuclear waste management. Semiannual progress report, October 1982-March 1983

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Chikalla, T.D.; Powell, J.A.

    1983-06-01

    This document is one of a series of technical progress reports designed to report radioactive waste management programs at the Pacific Northwest Laboratory. Accomplishments in the following programs are reported: waste stabilization; Materials Characterization Center; waste isolation; low-level waste management; remedial action; and supporting studies.

  19. Corrective Action Investigation Plan for Corrective Action Unit 168: Areas 25 and 26 Contaminated Materials and Waste Dumps, Nevada Test Site, Nevada (Rev. 0) includes Record of Technical Change No. 1 (dated 8/28/2002), Record of Technical Change No. 2 (dated 9/23/2002), and Record of Technical Change No. 3 (dated 6/2/2004)

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    U.S. Department of Energy, National Nuclear Security Administration Nevada

    This Corrective Action Investigation Plan contains the U.S. Department of Energy, National Nuclear Security Administration Nevada Operations Office's approach to collect data necessary to evaluate corrective action alternatives appropriate for the closure of Corrective Action Unit 168 under the Federal Facility Agreement and Consent Order. Corrective Action Unit 168 consists of a group of twelve relatively diverse Corrective Action Sites (CASs 25-16-01, Construction Waste Pile; 25-16-03, MX Construction Landfill; 25-19-02, Waste Disposal Site; 25-23-02, Radioactive Storage RR Cars; 25-23-18, Radioactive Material Storage; 25-34-01, NRDS Contaminated Bunker; 25-34-02, NRDS Contaminated Bunker; CAS 25-23-13, ETL - Lab Radioactive Contamination; 25-99-16, USW G3;more » 26-08-01, Waste Dump/Burn Pit; 26-17-01, Pluto Waste Holding Area; 26-19-02, Contaminated Waste Dump No.2). These CASs vary in terms of the sources and nature of potential contamination. The CASs are located and/or associated wit h the following Nevada Test Site (NTS) facilities within three areas. The first eight CASs were in operation between 1958 to 1984 in Area 25 include the Engine Maintenance, Assembly, and Disassembly Facility; the Missile Experiment Salvage Yard; the Reactor Maintenance, Assembly, and Disassembly Facility; the Radioactive Materials Storage Facility; and the Treatment Test Facility Building at Test Cell A. Secondly, the three CASs located in Area 26 include the Project Pluto testing area that operated from 1961 to 1964. Lastly, the Underground Southern Nevada Well (USW) G3 (CAS 25-99-16), a groundwater monitoring well located west of the NTS on the ridgeline of Yucca Mountain, was in operation during the 1980s. Based on site history and existing characterization data obtained to support the data quality objectives process, contaminants of potential concern (COPCs) for CAU 168 are primarily radionuclide; however, the COPCs for several CASs were not defined. To address COPC uncertainty, the analytical program for most CASs will include volatile organic compounds, semivolatile organic compounds, Resource Conservation and Recovery Act metals, total petroleum hydrocarbons, polychlorinated biphenyls, and radionuclides. Upon reviewing historical data and current site conditions, it has been determined that no further characterization is required at USW G3 (CAS 25-99-16) to select the appropriate corrective action. A cesium-137 source was encased in cement within the vadous zone during the drilling of the well (CAS 25-99-16). A corrective action of closure in place with a land-use restriction for drilling near USW G3 is appropriate. This corrective action will be documented in the Corrective Action Decision Document (CADD) for CAU 168. The results of the remaining field investigation will support a defensible evaluation of corrective action alternatives for the other CASs within CAU 168 in this CADD.« less

  20. A Life Cycle Assessment (LCA) comparison of three management options for waste papers: bioethanol production, recycling and incineration with energy recovery.

    PubMed

    Wang, Lei; Templer, Richard; Murphy, Richard J

    2012-09-01

    This study uses Life Cycle Assessment (LCA) to assess the environmental profiles and greenhouse gas (GHG) emissions for bioethanol production from waste papers and to compare them with the alternative waste management options of recycling or incineration with energy recovery. Bioethanol production scenarios both with and without pre-treatments were conducted. It was found that an oxidative lime pre-treatment reduced GHG emissions and overall environmental burdens for a newspaper-to-bioethanol process whereas a dilute acid pre-treatment raised GHG emissions and overall environmental impacts for an office paper-to-bioethanol process. In the comparison of bioethanol production systems with alternative management of waste papers by different technologies, it was found that the environmental profiles of each system vary significantly and this variation affects the outcomes of the specific comparisons made. Overall, a number of configurations of bioethanol production from waste papers offer environmentally favourable or neutral profiles when compared with recycling or incineration. Copyright © 2012 Elsevier Ltd. All rights reserved.

  1. DOE Office of Scientific and Technical Information (OSTI.GOV)

    Kara, Mustafa, E-mail: mustafa.kara@mam.gov.t; Guenay, Esin; Tabak, Yasemin

    Municipal solid waste (MSW) is one of the most important environmental problems arising from rapid urbanization and industrialization. The use of alternative fuels in rotary kilns of cement plants is very important for reducing cost, saving fossil fuels and also eliminating waste materials, accumulated during production or after using these materials. Cement industries has an important potential for supplying preferable solutions to the waste management. Energy recovery from waste is also important for the reduction of CO{sub 2} emissions. This paper presents an investigation of the development of refuse derived fuel (RDF) materials from non-recycling wastes and the determination ofmore » its potential use as an alternative fuel in cement production in Istanbul, Turkey. RDF produced from MSW was analyzed and its effects on cement production process were examined. For this purpose, the produced RDF was mixed with the main fuel (LPG) in ratios of 0%, 5%, 10%, 15% and 20%. Then chemical and mineralogical analyses of the produced clinker were carried out. It is believed that successful results of this study will be a good example for municipalities and cement industries in order to achieve both economic and environmental benefits.« less

  2. ECONOMIC ASSESSMENT OF WASTE WATER AQUACULTURE TREATMENT SYSTEMS

    EPA Science Inventory

    This study attempted to ascertain the economic viability of aquaculture as an alternative to conventional waste water treatment systems for small municipalities in the Southwestern region of the United States. A multiple water quality objective level cost-effectiveness model was ...

  3. 40 CFR 273.1 - Scope.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES (CONTINUED) STANDARDS FOR UNIVERSAL WASTE MANAGEMENT General § 273.1 Scope. (a) This part establishes requirements for managing the... an alternative set of management standards in lieu of regulation under 40 CFR parts 260 through 272...

  4. ECONOMICS OF GROUND FREEZING FOR MANAGEMENT OF UNCONTROLLED HAZARDOUS WASTE SITES

    EPA Science Inventory

    Ground freezing for hazardous waste containment is an alternative to the traditional and expensive slurry wall or grout curtain barrier technologies. The parameters quantified in this analysis of it include thermal properties, refrigeration line spacing, equipment mobilization an...

  5. Active and passive computed tomography mixed waste focus area final report

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Roberson, G P

    1998-08-19

    The Mixed Waste Focus Area (MWFA) Characterization Development Strategy delineates an approach to resolve technology deficiencies associated with the characterization of mixed wastes. The intent of this strategy is to ensure the availability of technologies to support the Department of Energy's (DOE) mixed waste low-level or transuranic (TRU) contaminated waste characterization management needs. To this end the MWFA has defined and coordinated characterization development programs to ensure that data and test results necessary to evaluate the utility of non-destructive assay technologies are available to meet site contact handled waste management schedules. Requirements used as technology development project benchmarks are basedmore » in the National TRU Program Quality Assurance Program Plan. These requirements include the ability to determine total bias and total measurement uncertainty. These parameters must be completely evaluated for waste types to be processed through a given nondestructive waste assay system constituting the foundation of activities undertaken in technology development projects. Once development and testing activities have been completed, Innovative Technology Summary Reports are generated to provide results and conclusions to support EM-30, -40, or -60 end user/customer technology selection. The Active and Passive Computed Tomography non-destructive assay system is one of the technologies selected for development by the MWFA. Lawrence Livermore National Laboratory's (LLNL) is developing the Active and Passive Computed Tomography (A&PCT) nondestructive assay (NDA) technology to identify and accurately quantify all detectable radioisotopes in closed containers of waste. This technology will be applicable to all types of waste regardless of .their classification; low level, transuranic or provide results and conclusions to support EM-30, -40, or -60 end user/customer technology selection. The Active and Passive Computed Tomography non-destructive assay system is one of the technologies selected for development by the MWFA. Lawrence Livermore National Laboratory's (LLNL) is developing the Active and Passive Computed Tomography (A&PCT) nondestructive assay (NDA) technology to identify and accurately quantify all detectable radioisotopes in closed containers of waste. This technology will be applicable to all types of waste regardless of .their classification; low level, transuranic or mixed, which contains radioactivity and hazardous organic species. The scope of our technology is to develop a non-invasive waste-drum scanner that employs the principles of computed tomography and gamma-ray spectral analysis to identify and quantify all of the detectable radioisotopes. Once this and other applicable technologies are developed, waste drums can be non- destructively and accurately characterized to satisfy repository and regulatory guidelines prior to disposal.« less

  6. Plasma for environment

    NASA Astrophysics Data System (ADS)

    Van Oost, G.

    2017-12-01

    Human activity is associated with the permanent emergence of a very wide range of waste streams. The most widely used treatment of waste is thermal processing such as incineration. An alternative environmentally friendly process is based on thermal plasma technology which is a very flexible tool because it allows to operate in a wide temperature range with almost any chemical composition of waste and chemicals needed for processing this waste. It allows the conversion of organic waste into energy or chemical substances as well as the destruction of toxic organic compounds in a scenario that for each specific type of waste can be considered optimal, both in terms of energy efficiency and environmental safety.

  7. DOE Office of Scientific and Technical Information (OSTI.GOV)

    Not Available

    The possible need to develop a solid waste management/resource recovery facility in Christian County, Kentucky is assessed. The present solid waste management operations are described and an outline of options available in the area of resource recovery and cost estimates for waste management alternatives are given. The construction of a transfer station to handle wastes hauled from a distance is discussed. Specific incineration waste heat recovery systems discussed briefly are: modular controlled air incinerators, modular refractory incinerators, rotary waterwall combustor-boiler, and waterwall incineration - unprocessed waste units. Environmental impacts are considered. An investigation was conducted on separating the raw refusemore » into its major components and recycling materials of value. (MCW)« less

  8. Chemical composition and methane potential of commercial food wastes.

    PubMed

    Lopez, Victoria M; De la Cruz, Florentino B; Barlaz, Morton A

    2016-10-01

    There is increasing interest in anaerobic digestion in the U.S. However, there is little information on the characterization of commercial food waste sources as well as the effect of waste particle size on methane yield. The objective of this research was to characterize four commercial food waste sources: (1) university dining hall waste, (2) waste resulting from prepared foods and leftover produce at a grocery store, (3) food waste from a hotel and convention center, and (4) food preparation waste from a restaurant. Each sample was tested in triplicate 8L batch anaerobic digesters after shredding and after shredding plus grinding. Average methane yields for the university dining, grocery store, hotel, and restaurant wastes were 363, 427, 492, and 403mL/dry g, respectively. Starch exhibited the most complete consumption and particle size did not significantly affect methane yields for any of the tested substrates. Lipids represented 59-70% of the methane potential of the fresh substrates. Copyright © 2016 Elsevier Ltd. All rights reserved.

  9. Screening and Spectral Summing of LANL Empty Waste Drums - 13226

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Gruetzmacher, Kathleen M.; Bustos, Roland M.; Ferran, Scott G.

    2013-07-01

    Empty 55-gallon drums that formerly held transuranic (TRU) waste (often over-packed in 85- gallon drums) are generated at LANL and require radiological characterization for disposition. These drums are typically measured and analyzed individually using high purity germanium (HPGe) gamma detectors. This approach can be resource and time intensive. For a project requiring several hundred drums to be characterized in a short time frame, an alternative approach was developed. The approach utilizes a combination of field screening and spectral summing that was required to be technically defensible and meet the Nevada Nuclear Security Site (NNSS) Waste Acceptance Criteria (WAC). In themore » screening phase of the operation, the drums were counted for 300 seconds (compared to 600 seconds for the typical approach) and checked against Low Level (LL)/TRU thresholds established for each drum configuration and detector. Multiple TRU nuclides and multiple gamma rays for each nuclide were evaluated using an automated spreadsheet utility that can process data from up to 42 drums at a time. Screening results were reviewed by an expert analyst to confirm the field LL/TRU determination. The spectral summing analysis technique combines spectral data (channel-by-channel) associated with a group of individual waste containers producing a composite spectrum. The grouped drums must meet specific similarity criteria. Another automated spreadsheet utility was used to spectral sum data from an unlimited number of similar drums grouped together. The composite spectrum represents a virtual combined drum for the group of drums and was analyzed using the SNAP{sup TM}/Radioassay Data Sheet (RDS)/Batch Data Report (BDR) method. The activity results for a composite virtual drum were divided equally amongst the individual drums to generate characterization results for each individual drum in the group. An initial batch of approximately 500 drums were measured and analyzed in less than 2 months in 2011. A second batch of approximately 500 more drums were measured and analyzed during the following 2 1/2 months. Four different HPGe detectors were employed for the operation. The screening and spectral summing approach can reduce the overall measurement and analysis time required. However, developing the technical details and automation spreadsheets requires a significant amount of expert time prior to beginning field operations and must be considered in the overall project schedule. This approach has continued to be used for characterizing several hundred more empty drums in 2012 and is planned to continue in 2013. (authors)« less

  10. Characterization of bio-oil from hydrothermal liquefaction of organic waste by NMR spectroscopy and FTICR mass spectrometry.

    PubMed

    Leonardis, Irene; Chiaberge, Stefano; Fiorani, Tiziana; Spera, Silvia; Battistel, Ezio; Bosetti, Aldo; Cesti, Pietro; Reale, Samantha; De Angelis, Francesco

    2013-01-01

    Solid wastes of organic origins are potential feedstocks for the production of liquid biofuels, which could be suitable alternatives to fossil fuels for the transport and heating sectors, as well as for industrial use. By hydrothermal liquefaction, the wet biomass is partially transformed into a water-immiscible, oil-like organic matter called bio-oil. In this study, an integrated NMR spectroscopy/mass spectrometry approach has been developed for the characterization of the hydrothermal liquefaction of bio-oil at the molecular level. (1)H and (13)C NMR spectroscopy were used for the identification of functional groups and gauging the aromatic carbon content in the mixture. GC-MS analysis revealed that the volatile fraction was rich in fatty acids, as well as in amides and esters. High-resolution Fourier-transform ion cyclotron resonance mass spectrometry (FTICR-MS) has been applied in a systematic way to fully categorize the bio-oil in terms of different classes of components, according to their molecular formulas. Most importantly, for the first time, by using this technique, and for the liquefaction bio-oil characterization in particular, FT-MS data have been used to develop a methodology for the determination of the aromatic versus aliphatic carbon and nitrogen content. It is well known that, because they resist hydrogenation and represent sources of polluting species, both aromatic molecules and nitrogen-containing species raise concerns for subsequent upgrading of bio-oil into a diesel-like fuel. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  11. LCA of local strategies for energy recovery from waste in England, applied to a large municipal flow

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Tunesi, Simonetta, E-mail: s.tunesi@ucl.ac.uk

    An intense waste management (WM) planning activity is currently undergoing in England to build the infrastructure necessary to treat residual wastes, increase recycling levels and the recovery of energy from waste. From the analyses of local WM strategic and planning documents we have identified the emerging of three different energy recovery strategies: established combustion of residual waste; pre-treatment of residual waste and energy recovery from Solid Recovered Fuel in a dedicated plant, usually assumed to be a gasifier; pre-treatment of residual waste and reliance on the market to accept the 'fuel from waste' so produced. Each energy recovery strategy willmore » result in a different solution in terms of the technology selected; moreover, on the basis of the favoured solution, the total number, scale and location of thermal treatment plants built in England will dramatically change. To support the evaluation and comparison of these three WM strategy in terms of global environmental impacts, energy recovery possibilities and performance with respect to changing 'fuel from waste' market conditions, the LCA comparison of eight alternative WM scenarios for a real case study dealing with a large flow of municipal wastes was performed with the modelling tool WRATE. The large flow of waste modelled allowed to formulate and assess realistic alternative WM scenarios and to design infrastructural systems which are likely to correspond to those submitted for approval to the local authorities. The results show that all alternative scenarios contribute to saving abiotic resources and reducing global warming potential. Particularly relevant to the current English debate, the performance of a scenario was shown to depend not from the thermal treatment technology but from a combination of parameters, among which most relevant are the efficiency of energy recovery processes (both electricity and heat) and the calorific value of residual waste and pre-treated material. The contribution and relative importance of recycling and treatment/recovery processes change with the impact category. The lack of reprocessing plants in the area of the case study has shown the relevance of transport distances for recyclate material in reducing the efficiency of a WM system. Highly relevant to the current English WM infrastructural debate, these results for the first time highlight the risk of a significant reduction in the energy that could be recovered by local WM strategies relying only on the market to dispose of the 'fuel from waste' in a non dedicated plant in the case that the SRF had to be sent to landfill for lack of treatment capacity.« less

  12. LCA of local strategies for energy recovery from waste in England, applied to a large municipal flow.

    PubMed

    Tunesi, Simonetta

    2011-03-01

    An intense waste management (WM) planning activity is currently undergoing in England to build the infrastructure necessary to treat residual wastes, increase recycling levels and the recovery of energy from waste. From the analyses of local WM strategic and planning documents we have identified the emerging of three different energy recovery strategies: established combustion of residual waste; pre-treatment of residual waste and energy recovery from Solid Recovered Fuel in a dedicated plant, usually assumed to be a gasifier; pre-treatment of residual waste and reliance on the market to accept the 'fuel from waste' so produced. Each energy recovery strategy will result in a different solution in terms of the technology selected; moreover, on the basis of the favoured solution, the total number, scale and location of thermal treatment plants built in England will dramatically change. To support the evaluation and comparison of these three WM strategy in terms of global environmental impacts, energy recovery possibilities and performance with respect to changing 'fuel from waste' market conditions, the LCA comparison of eight alternative WM scenarios for a real case study dealing with a large flow of municipal wastes was performed with the modelling tool WRATE. The large flow of waste modelled allowed to formulate and assess realistic alternative WM scenarios and to design infrastructural systems which are likely to correspond to those submitted for approval to the local authorities. The results show that all alternative scenarios contribute to saving abiotic resources and reducing global warming potential. Particularly relevant to the current English debate, the performance of a scenario was shown to depend not from the thermal treatment technology but from a combination of parameters, among which most relevant are the efficiency of energy recovery processes (both electricity and heat) and the calorific value of residual waste and pre-treated material. The contribution and relative importance of recycling and treatment/recovery processes change with the impact category. The lack of reprocessing plants in the area of the case study has shown the relevance of transport distances for recyclate material in reducing the efficiency of a WM system. Highly relevant to the current English WM infrastructural debate, these results for the first time highlight the risk of a significant reduction in the energy that could be recovered by local WM strategies relying only on the market to dispose of the 'fuel from waste' in a non dedicated plant in the case that the SRF had to be sent to landfill for lack of treatment capacity. Copyright © 2010 Elsevier Ltd. All rights reserved.

  13. Identification and Characterization of Oleaginous Yeast Isolated from Kefir and Its Ability to Accumulate Intracellular Fats in Deproteinated Potato Wastewater with Different Carbon Sources

    PubMed Central

    Kieliszek, Marek; Jermacz, Karolina; Błażejak, Stanisław

    2017-01-01

    The search for efficient oleaginous microorganisms, which can be an alternative to fossil fuels and biofuels obtained from oilseed crops, has been going on for many years. The suitability of microorganisms in this regard is determined by their ability to biosynthesize lipids with preferred fatty acid profile along with the concurrent utilization of energy-rich industrial waste. In this study, we isolated, characterized, and identified kefir yeast strains using molecular biology techniques. The yeast isolates identified were Candida inconspicua, Debaryomyces hansenii, Kluyveromyces marxianus, Kazachstania unispora, and Zygotorulaspora florentina. We showed that deproteinated potato wastewater, a starch processing industry waste, supplemented with various carbon sources, including lactose and glycerol, is a suitable medium for the growth of yeast, which allows an accumulation of over 20% of lipid substances in its cells. Fatty acid composition primarily depended on the yeast strain and the carbon source used, and, based on our results, most of the strains met the criteria required for the production of biodiesel. In particular, this concerns a significant share of saturated fatty acids, such as C16:0 and C18:0, and unsaturated fatty acids, such as C18:1 and C18:2. The highest efficiency in lipid biosynthesis exceeded 6.3 g L−1. Kazachstania unispora was able to accumulate the high amount of palmitoleic acid. PMID:29098157

  14. Identification and Characterization of Oleaginous Yeast Isolated from Kefir and Its Ability to Accumulate Intracellular Fats in Deproteinated Potato Wastewater with Different Carbon Sources.

    PubMed

    Gientka, Iwona; Kieliszek, Marek; Jermacz, Karolina; Błażejak, Stanisław

    2017-01-01

    The search for efficient oleaginous microorganisms, which can be an alternative to fossil fuels and biofuels obtained from oilseed crops, has been going on for many years. The suitability of microorganisms in this regard is determined by their ability to biosynthesize lipids with preferred fatty acid profile along with the concurrent utilization of energy-rich industrial waste. In this study, we isolated, characterized, and identified kefir yeast strains using molecular biology techniques. The yeast isolates identified were Candida inconspicua , Debaryomyces hansenii , Kluyveromyces marxianus , Kazachstania unispora , and Zygotorulaspora florentina . We showed that deproteinated potato wastewater, a starch processing industry waste, supplemented with various carbon sources, including lactose and glycerol, is a suitable medium for the growth of yeast, which allows an accumulation of over 20% of lipid substances in its cells. Fatty acid composition primarily depended on the yeast strain and the carbon source used, and, based on our results, most of the strains met the criteria required for the production of biodiesel. In particular, this concerns a significant share of saturated fatty acids, such as C16:0 and C18:0, and unsaturated fatty acids, such as C18:1 and C18:2. The highest efficiency in lipid biosynthesis exceeded 6.3 g L -1 . Kazachstania unispora was able to accumulate the high amount of palmitoleic acid.

  15. Possibility of heat recovery from gray water in residential building

    NASA Astrophysics Data System (ADS)

    Mazur, Aleksandra; Słyś, Daniel

    2017-12-01

    Recovery of waste heat from gray water can be an interesting alternative to other energy saving systems in a building, including alternative energy sources. Mainly, due to a number of advantages including independence from weather conditions, small investment outlay, lack of user support, or a slight interference with the installation system. The purpose of this article is to present the financial effectiveness of installations which provide hot, usable water to a detached house, using a Drain Water Heat Recovery (DWHR) system depending on the number of system users and the various combinations of bathing time in the shower, which has an influence on the daily warm water demand in each of the considered options. The economic analysis of the adopted installation variants is based on the Life Cycle Cost (LCC) method, which is characterized by the fact that it also includes the operating costs in addition to the capital expenditure during the entire analysis period. For each case, the necessary devices were selected and the cost of their installation was estimated.

  16. Fabrication and characterization of rice husk and coconut shell charcoal based bio-briquettes as alternative energy source

    NASA Astrophysics Data System (ADS)

    Yuliah, Y.; Kartawidjaja, M.; Suryaningsih, S.; Ulfi, K.

    2017-05-01

    Rice husk and coconut shell have been disposed or burned as waste. As biomass, both of materials are the potential sources of carbon which can be utilized as alternative energy sources. The energy content can be exploited more intensively when packaged in a brief and convenient. In this work, the mixtures of rice husks and coconut shells charcoal were prepared as briquettes. After going through the carbonization process, several measurements have been taken to find out the factors that determine the value of heat energy contains by each component of the charcoals. The basic ingredients briquettes prepared from rice husk and coconut shell charcoal with varying composition and addition of tapioca starch gradually as adhesive material to obtain briquettes in solid with the maximum heat energy content. After going through pressing and drying process, the briquettes with 50:50 percent of composition and the 6% addition of adhesive was found has the highest heat energy content, equal to 4966 cal/g.

  17. Nuclear Waste Disposal: Alternatives to Yucca Mountain

    DTIC Science & Technology

    2009-02-06

    metric tons of spent fuel at the nine decommissioned sites could be shipped to a federal central storage facility by 2018 , but that DOE had no...Disposal of High- Level Radioactive Waste into the Seabed, Overview of Research and Conclusions, Volume 1, Paris , 1988, p. 60. 63 1996 Protocol to...Convention on Prevention of Marine Pollution by Dumping of Wastes, Treaty Doc. 110-5, September 4, 2007

  18. Collection of Human Wastes on Long Missions

    NASA Technical Reports Server (NTRS)

    Jennings, D. C.; Lewis, T. A.; Brose, H. F.

    1986-01-01

    Report evaluates and compares three alternative approaches to hygienic containment of human wastes. Three practical means of waste collection: filter-bag collection with compaction by fan suction, canister collection with compaction by force applied to compaction cups or disks, and sleeve collection with compaction by rollers and winding on reel. Potentially useful in airplanes, buses, boats, trains, and campers and temporary toilets for construction sites and outdoor gatherings.

  19. Land Application of Wastes: An Educational Program. Design Procedures for Land Application of Wastes - Module 6, Objectives, Script and Figures.

    ERIC Educational Resources Information Center

    Clarkson, W. W.; And Others

    The purpose of this module is to develop a general procedure to decide the feasibility of land application as a waste management alternative, given a specific problem situation. This information provides a framework within which to apply the information presented in all other modules in the program. An outline of the general procedure followed in…

  20. 40 CFR 761.345 - Form of the waste to be sampled.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... Characterization for PCB Disposal in Accordance With § 761.62, and Sampling PCB Remediation Waste Destined for Off... waste and PCB remediation waste destined for off-site disposal must be in the form of either flattened...

  1. Waste-water characterization and hazardous-waste technical assistance survey, Mather AFB California. Final report, 28 November-9 December 1988

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Scott, S.P.; Hedgecock, N.S.

    1989-10-01

    Personnel from the AFOEHL conducted a waste-water characterization and hazardous-waste technical assistance survey at MAFB from 28 Nov to 9 Dec 1988. The scope of this survey was to characterize the waste-water, address hazardous-waste-management practices, and explore opportunities for hazardous waste minimization. The waste water survey team analyzed the base's industrial effluent, effluent from oil/water separators, and storm water. The team performed a shop-by-shop evaluation of chemical-waste-management practices. Survey results showed that MAFB needs to improve its hazardous-waste-management program. Recommendations for improvement include: (1) Collecting two additional grab samples on separate days from the hospital discharge. Analyze for EPA Methodmore » 601 to determine if the grab sample from the survey gives a true indication of what is being discharged. (2) Locate the source and prevent mercury from the hospital from discharging into the sanitary sewer. (3) Dilute the soaps used for cleaning at the Fuels Lab, Building 7060. (4) Investigate the source of chromium from the Photo Lab. (5) Clean out the sewer system manhole directly downgradient from the Photo Lab. (6) Locate the source of contamination in the West Ditch Outfall. (7) Reconnect the two oil/water separators that discharge into the storm sewerage system. (8) Investigate the source of methylene chloride coming on the base. (9) Investigate the source of mercury at Fuel Cell Repair, building 7005.« less

  2. Waste Characterization Process

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Lambert, Patrick E.

    2014-11-01

    The purpose is to provide guidance to the Radiological Characterization Reviewer to complete the radiological characterization of waste items. This information is used for Department of Transportation (DOT) shipping and disposal, typically at the Nevada National Security Site (NNSS). Complete characterization ensures compliance with DOT shipping laws and NNSS Waste Acceptance Criteria (WAC). The fines for noncompliance can be extreme. This does not include possible bad press, and endangerment to the public, employees and the environment. A Radiological Characterization Reviewer has an important role in the organization. The scope is to outline the characterization process, but does not to includemore » every possible situation. The Radiological Characterization Reviewer position requires a strong background in Health Physics; therefore, these concepts are minimally addressed. The characterization process includes many Excel spreadsheets that were developed by Michael Enghauser known as the WCT software suite. New Excel spreadsheets developed as part of this project include the Ra- 226 Decider and the Density Calculator by Jesse Bland, MicroShield Density Calculator and Molecular Weight Calculator by Pat Lambert.« less

  3. Hazardous Waste Clean-Up Information (CLU-IN) On-line Characterization and Remediation Databases Fact Sheet

    EPA Pesticide Factsheets

    This fact sheet provides an overview of the 10 on-line characterization and remediation databases available on the Hazardous Waste Clean-Up Information (CLU-IN) website sponsored by the U.S. Environmental Protection Agency.

  4. Health Risks of Nuclear Power.

    ERIC Educational Resources Information Center

    Cohen, Bernard L.

    1978-01-01

    Deals with the wastes generated in nuclear power plants and the health risks involved as compared to those of wastes generated by coal-fired plants. Concludes that the risks of nuclear power plants are many times smaller than the risks from alternative energy resources. (GA)

  5. Development of a Plastic Melt Waste Compactor for Space Missions Experiments and Prototype Design

    NASA Technical Reports Server (NTRS)

    Pace, Gregory; Wignarajah, Kanapathipillai; Pisharody, Suresh; Fisher, John

    2004-01-01

    This paper describes development at NASA Ames Research Center of a heat melt compactor that can be used on both near term and far term missions. Experiments have been performed to characterize the behavior of composite wastes that are representative of the types of wastes produced on current and previous space missions such as International Space Station, Space Shuttle, MIR and Skylab. Experiments were conducted to characterize the volume reduction, bonding, encapsulation and biological stability of the waste composite and also to investigate other key design issues such as plastic extrusion, noxious off-gassing and removal of the of the plastic waste product from the processor. The experiments provided the data needed to design a prototype plastic melt waste processor, a description of which is included in the paper.

  6. Gamma-ray spectrometry method used for radioactive waste drums characterization for final disposal at National Repository for Low and Intermediate Radioactive Waste--Baita, Romania.

    PubMed

    Done, L; Tugulan, L C; Dragolici, F; Alexandru, C

    2014-05-01

    The Radioactive Waste Management Department from IFIN-HH, Bucharest, performs the conditioning of the institutional radioactive waste in concrete matrix, in 200 l drums with concrete shield, for final disposal at DNDR - Baita, Bihor county, in an old exhausted uranium mine. This paper presents a gamma-ray spectrometry method for the characterization of the radioactive waste drums' radionuclides content, for final disposal. In order to study the accuracy of the method, a similar concrete matrix with Portland cement in a 200 l drum was used. © 2013 The Authors. Published by Elsevier Ltd All rights reserved.

  7. Report: new guidelines for characterization of municipal solid waste: the Portuguese case.

    PubMed

    da Graça Madeira Martinho, Maria; Silveira, Ana Isabel; Fernandes Duarte Branco, Elsa Maria

    2008-10-01

    This report proposes a new set of guidelines for the characterization of municipal solid waste. It is based on an analysis of reference methodologies, used internationally, and a case study of Valorsul (a company that handles recovery and treatment of solid waste in the North Lisbon Metropolitan Area). In particular, the suggested guidelines present a new definition of the waste to be analysed, change the sampling unit and establish statistical standards for the results obtained. In these new guidelines, the sampling level is the waste collection vehicle and contamination and moisture are taken into consideration. Finally, focus is on the quality of the resulting data, which is essential for comparability of data between countries. These new guidelines may also be applicable outside Portugal because the methodology includes, besides municipal mixed waste, separately collected fractions of municipal waste. They are a response to the need for information concerning Portugal (e.g. Eurostat or OECD inquiries) and follow European Union municipal solid waste management policies (e.g. packaging waste recovery and recycling targets and the reduction of biodegradable waste going to landfill).

  8. Integrating Hazardous Materials Characterization and Assessment Tools to Guide Pollution Prevention in Electronic Products and Manufacturing

    NASA Astrophysics Data System (ADS)

    Lam, Carl

    Due to technology proliferation, the environmental burden attributed to the production, use, and disposal of hazardous materials in electronics have become a worldwide concern. The major theme of this dissertation is to develop and apply hazardous materials assessment tools to systematically guide pollution prevention opportunities in the context of electronic product design, manufacturing and end-of-life waste management. To this extent, a comprehensive review is first provided on describing hazard traits and current assessment methods to evaluate hazardous materials. As a case study at the manufacturing level, life cycle impact assessment (LCIA)-based and risk-based screening methods are used to quantify chemical and geographic environmental impacts in the U.S. printed wiring board (PWB) industry. Results from this industrial assessment clarify priority waste streams and States to most effectively mitigate impact. With further knowledge of PWB manufacturing processes, select alternative chemical processes (e.g., spent copper etchant recovery) and material options (e.g., lead-free etch resist) are discussed. In addition, an investigation on technology transition effects for computers and televisions in the U.S. market is performed by linking dynamic materials flow and environmental assessment models. The analysis forecasts quantities of waste units generated and maps shifts in environmental impact potentials associated with metal composition changes due to product substitutions. This insight is important to understand the timing and waste quantities expected and the emerging toxic elements needed to be addressed as a consequence of technology transition. At the product level, electronic utility meter devices are evaluated to eliminate hazardous materials within product components. Development and application of a component Toxic Potential Indicator (TPI) assessment methodology highlights priority components requiring material alternatives. Alternative recommendations are provided and substitute materials such as aluminum alloys for stainless steel and high-density polyethylene for polyvinyl chloride and acrylonitrile-based polymers show promise to meet toxicity reduction, cost, and material functionality requirements. Furthermore, the TPI method, an European Union focused screening tool, is customized to reflect regulated U.S. toxicity parameters. Results show that, although it is possible to adopt U.S. parameters into the TPI method, harmonization of toxicity regulation and standards in various nations and regions is necessary to eliminate inconsistencies during hazard screening of substances used globally. As a whole, the present work helps to assimilate material hazard assessment methods into the larger framework of design for environment strategies so toxics use reduction could be achieved for the development and management of electronics and other consumer goods.

  9. DOE Office of Scientific and Technical Information (OSTI.GOV)

    Singledecker, Steven John

    The purpose of this document is to describe the waste stream from Z-Pinch Residual Waste Project that due to worker safety concerns and operational efficiency is a candidate for blending Transuranic and low level waste together and can be safely packaged as low-level waste consistent with DOE Order 435.1 requirements and NRC guidance 10 CFR 61.42. This waste stream consists of the Pu-ICE post-shot containment systems, including plutonium targets, generated from the Z Machine experiments requested by LANL and conducted by SNL/NM. In the past, this TRU waste was shipped back to LANL after Sandia sends the TRU data packagemore » to LANL to certify the characterization (by CCP), transport and disposition at WIPP (CBFO) per LANL MOU-0066. The Low Level Waste is managed, characterized, shipped and disposed of at NNSS by SNL/NM per Sandia MOU # 11-S-560.« less

  10. Genesis and continuity of quaternary sand and gravel in glacigenic sediment at a proposed low-level radioactive waste disposal site in east-central Illinois

    USGS Publications Warehouse

    Troost, K.G.; Curry, B. Brandon

    1991-01-01

    The Illinois Department of Nuclear Safety has characterized the Martinsville Alternative Site (MAS) for a proposed low-level radioactive waste disposal facility. The MAS is located in east-central Illinois approximately 1.6 km (1 mi) north of the city of Martinsville. Geologic investigation of the 5.5-km2 (1380-acre) site revealed a sequence of chiefly Illinoian glacigenic sediments from 6 to 60 m (20-200 ft) thick overlying two major bedrock valleys carved in Pennsylvanian strata. Relatively permeable buried units include basal, preglacial alluvium; a complex of intraglacial and subglacial sediment; englacial deposits; and supraglacial fluvial deposits. Postglacial alluvium underlies stream valleys on and adjacent to the site. In most areas, the buried sand units are confined by low-permeability till, lacustrine sediment, colluvium, and loess. The distribution and thickness of the most extensive and continuous buried sand units have been modified considerably by subglacial erosion, and their distributions have been influenced by the buried bedrock valleys. The most continuous of the various sand units were deposited as preglacial and postglacial alluvium and are the uppermost and lowermost stratigraphic units at the alternative site. Sand units that were deposited in englacial or ice-marginal environments are less continuous. Aquifer pumping tests, potentiometric head data, and groundwater geochemistry analyses indicate minimal interaction of groundwater across localized interconnections of the permeable units. ?? 1991 Springer-Verlag New York Inc.

  11. Site characterization report for the basalt waste isolation project. Volume II

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    None

    1982-11-01

    The reference location for a repository in basalt for the terminal storage of nuclear wastes on the Hanford Site and the candidate horizons within this reference repository location have been identified and the preliminary characterization work in support of the site screening process has been completed. Fifteen technical questions regarding the qualification of the site were identified to be addressed during the detailed site characterization phase of the US Department of Energy-National Waste Terminal Storage Program site selection process. Resolution of these questions will be provided in the final site characterization progress report, currently planned to be issued in 1987,more » and in the safety analysis report to be submitted with the License Application. The additional information needed to resolve these questions and the plans for obtaining the information have been identified. This Site Characterization Report documents the results of the site screening process, the preliminary site characterization data, the technical issues that need to be addressed, and the plans for resolving these issues. Volume 2 contains chapters 6 through 12: geochemistry; surface hydrology; climatology, meteorology, and air quality; environmental, land-use, and socioeconomic characteristics; repository design; waste package; and performance assessment.« less

  12. A multi-criteria analysis of options for energy recovery from municipal solid waste in India and the UK.

    PubMed

    Yap, H Y; Nixon, J D

    2015-12-01

    Energy recovery from municipal solid waste plays a key role in sustainable waste management and energy security. However, there are numerous technologies that vary in suitability for different economic and social climates. This study sets out to develop and apply a multi-criteria decision making methodology that can be used to evaluate the trade-offs between the benefits, opportunities, costs and risks of alternative energy from waste technologies in both developed and developing countries. The technologies considered are mass burn incineration, refuse derived fuel incineration, gasification, anaerobic digestion and landfill gas recovery. By incorporating qualitative and quantitative assessments, a preference ranking of the alternative technologies is produced. The effect of variations in decision criteria weightings are analysed in a sensitivity analysis. The methodology is applied principally to compare and assess energy recovery from waste options in the UK and India. These two countries have been selected as they could both benefit from further development of their waste-to-energy strategies, but have different technical and socio-economic challenges to consider. It is concluded that gasification is the preferred technology for the UK, whereas anaerobic digestion is the preferred technology for India. We believe that the presented methodology will be of particular value for waste-to-energy decision-makers in both developed and developing countries. Copyright © 2015 Elsevier Ltd. All rights reserved.

  13. Thermal plasma technology for the treatment of wastes: a critical review.

    PubMed

    Gomez, E; Rani, D Amutha; Cheeseman, C R; Deegan, D; Wise, M; Boccaccini, A R

    2009-01-30

    This review describes the current status of waste treatment using thermal plasma technology. A comprehensive analysis of the available scientific and technical literature on waste plasma treatment is presented, including the treatment of a variety of hazardous wastes, such as residues from municipal solid waste incineration, slag and dust from steel production, asbestos-containing wastes, health care wastes and organic liquid wastes. The principles of thermal plasma generation and the technologies available are outlined, together with potential applications for plasma vitrified products. There have been continued advances in the application of plasma technology for waste treatment, and this is now a viable alternative to other potential treatment/disposal options. Regulatory, economic and socio-political drivers are promoting adoption of advanced thermal conversion techniques such as thermal plasma technology and these are expected to become increasingly commercially viable in the future.

  14. Geomechanical Considerations for the Deep Borehole Field Test

    NASA Astrophysics Data System (ADS)

    Park, B. Y.

    2015-12-01

    Deep borehole disposal of high-level radioactive waste is under consideration as a potential alternative to shallower mined repositories. The disposal concept consists of drilling a borehole into crystalline basement rocks to a depth of 5 km, emplacement of canisters containing solid waste in the lower 2 km, and plugging and sealing the upper 3 km of the borehole. Crystalline rocks such as granites are particularly attractive for borehole emplacement because of their low permeability and porosity at depth, and high mechanical strength to resist borehole deformation. In addition, high overburden pressures contribute to sealing of some of the fractures that provide transport pathways. We present geomechanical considerations during construction (e.g., borehole breakouts, disturbed rock zone development, and creep closure), relevant to both the smaller-diameter characterization borehole (8.5") and the larger-diameter field test borehole (17"). Sandia National Laboratories is a multi-program laboratory managed and operated by Sandia Corporation, a wholly owned subsidiary of Lockheed Martin Corporation, for the U.S. Department of Energy's National Nuclear Security Administration under contract DE-AC04-94AL85000.

  15. Water treatment capacity of forward osmosis systems utilizing power plant waste heat

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Zhou, Xingshi; Gingerich, Daniel B.; Mauter, Meagan S.

    Forward osmosis (FO) has the potential to improve the energy efficiency of membrane-based water treatment by leveraging waste heat from steam electric power generation as the primary driving force for separation. In this study, we develop a comprehensive FO process model, consisting of membrane separation, heat recovery, and draw solute regeneration (DSR) models. We quantitatively characterize three alternative processes for DSR: distillation, steam stripping, and air stripping. We then construct a mathematical model of the distillation process for DSR that incorporates hydrodynamics, mass and heat transport resistances, and reaction kinetics, and we integrate this into a model for the fullmore » FO process. Finally, we utilize this FO process model to derive a first-order approximation of the water production capacity given the rejected heat quantity and quality available at U.S. electric power facilities. We find that the upper bound of FO water treatment capacity using low-grade heat sources at electric power facilities exceeds process water treatment demand for boiler water make-up and flue gas desulfurization wastewater systems.« less

  16. Applying fermentation liquid of food waste as carbon source to a pilot-scale anoxic/oxic-membrane bioreactor for enhancing nitrogen removal: Microbial communities and membrane fouling behaviour.

    PubMed

    Tang, Jialing; Wang, Xiaochang C; Hu, Yisong; Ngo, Huu Hao; Li, Yuyou; Zhang, Yongmei

    2017-07-01

    Fermentation liquid of food waste (FLFW) was applied as an external carbon source in a pilot-scale anoxic/oxic-membrane bioreactor (A/O-MBR) system to enhance nitrogen removal for treating low COD/TN ratio domestic wastewater. Results showed that, with the FLFW addition, total nitrogen removal increased from lower than 20% to 44-67% during the 150days of operation. The bacterial metabolic activities were obviously enhanced, and the significant change in microbial community structure promoted pollutants removal and favored membrane fouling mitigation. By monitoring transmembrane pressure and characterizing typical membrane foulants, such as extracellular polymeric substances (EPS), dissolved organic matter (DOM), and inorganics and biopolymers in the cake layer, it was confirmed that FLFW addition did not bring about any additional accumulation of membrane foulants, acceleration of fouling rate, or obvious irreversible membrane fouling in the whole operation period. Therefore, FLFW is a promising alternative carbon source to enhance nitrogen removal for the A/O-MBR system. Copyright © 2017 Elsevier Ltd. All rights reserved.

  17. Water treatment capacity of forward osmosis systems utilizing power plant waste heat

    DOE PAGES

    Zhou, Xingshi; Gingerich, Daniel B.; Mauter, Meagan S.

    2015-06-11

    Forward osmosis (FO) has the potential to improve the energy efficiency of membrane-based water treatment by leveraging waste heat from steam electric power generation as the primary driving force for separation. In this study, we develop a comprehensive FO process model, consisting of membrane separation, heat recovery, and draw solute regeneration (DSR) models. We quantitatively characterize three alternative processes for DSR: distillation, steam stripping, and air stripping. We then construct a mathematical model of the distillation process for DSR that incorporates hydrodynamics, mass and heat transport resistances, and reaction kinetics, and we integrate this into a model for the fullmore » FO process. Finally, we utilize this FO process model to derive a first-order approximation of the water production capacity given the rejected heat quantity and quality available at U.S. electric power facilities. We find that the upper bound of FO water treatment capacity using low-grade heat sources at electric power facilities exceeds process water treatment demand for boiler water make-up and flue gas desulfurization wastewater systems.« less

  18. Molten salt oxidation: a versatile and promising technology for the destruction of organic-containing wastes.

    PubMed

    Yao, Zhitong; Li, Jinhui; Zhao, Xiangyang

    2011-08-01

    Molten salt oxidation (MSO), a robust thermal but non-flame process, has the inherent capability of destroying organic constituents in wastes, while retaining inorganic and radioactive materials in situ. It has been considered as an alternative to incineration and may be a solution to many waste disposal problems. The present review first describes the history and development of MSO, as well as design and engineering details, and then focuses on reaction mechanisms and its potential applications in various wastes, including hazardous wastes, medical wastes, mixed wastes, and energetic materials. Finally, the current status of and prospects for the MSO process and directions for future research are considered. Copyright © 2011 Elsevier Ltd. All rights reserved.

  19. 40 CFR 761.260 - Applicability.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) TOXIC SUBSTANCES CONTROL ACT... Site Characterization Sampling for PCB Remediation Waste in Accordance with § 761.61(a)(2) § 761.260 Applicability. This subpart provides a method for collecting new data for characterizing a PCB remediation waste...

  20. 40 CFR 761.260 - Applicability.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) TOXIC SUBSTANCES CONTROL ACT... Site Characterization Sampling for PCB Remediation Waste in Accordance with § 761.61(a)(2) § 761.260 Applicability. This subpart provides a method for collecting new data for characterizing a PCB remediation waste...

  1. 40 CFR 761.260 - Applicability.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) TOXIC SUBSTANCES CONTROL ACT... Site Characterization Sampling for PCB Remediation Waste in Accordance with § 761.61(a)(2) § 761.260 Applicability. This subpart provides a method for collecting new data for characterizing a PCB remediation waste...

  2. 40 CFR 761.260 - Applicability.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) TOXIC SUBSTANCES CONTROL ACT... Site Characterization Sampling for PCB Remediation Waste in Accordance with § 761.61(a)(2) § 761.260 Applicability. This subpart provides a method for collecting new data for characterizing a PCB remediation waste...

  3. Analysis of waste hierarchy in the European waste directive 2008/98/EC.

    PubMed

    Gharfalkar, Mangesh; Court, Richard; Campbell, Callum; Ali, Zulfiqur; Hillier, Graham

    2015-05-01

    Loss of recoverable resources in linear resource flow systems is likely to contribute to the depletion of natural resources and environmental degradation. The 'waste hierarchy' in the European Commission's latest Waste Framework Directive 2008/98/EC (WFD2008) makes recommendations on how to address this issue. The WFD2008 is analysed in this work for its adequacy in ensuring return of 'recoverable waste' as a 'resource' into the productive system. Despite the release of guidance documents by the DG Environment, DEFRA and WRAP UK on the interpretation of key provisions of the WFD2008, lack of clarity still exists around the WFD2008 'waste hierarchy'. There is also an overlap between measures such as 'prevention' and 'reduction', 'preparing for reuse' and 'reuse' and lack of clarity on why the measure of 'reuse' is included in the WFD2008 definition of 'prevention'. Finally, absence of the measures of 'recovery' and 'reuse' from the WFD2008 'waste hierarchy' reduces its effectiveness as a resource efficiency tool. Without clarity on the WFD2008 'waste hierarchy', it is challenging for decision makers to take direct action to address inefficiencies existing within their operations or supply chains. This paper proposes the development of an alternative 'hierarchy of resource use' and alternative 'definitions' that attempt to fill identified gaps in the WFD2008 and bring clarity to the key measures of waste prevention, reduction and recovery. This would help the key stakeholders in driving resource effectiveness, which in turn would assist in conservation of natural resources and prevention of environmental degradation. Copyright © 2015 Elsevier Ltd. All rights reserved.

  4. 40 CFR 265.250 - Applicability.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... Piles § 265.250 Applicability. The regulations in this subpart apply to owners and operators of facilities that treat or store hazardous waste in piles, except as § 265.1 provides otherwise. Alternatively, a pile of hazardous waste may be managed as a landfill under subpart N. ...

  5. Conversion of lipid from food waste to biodiesel.

    PubMed

    Karmee, Sanjib Kumar; Linardi, Darwin; Lee, Jisoo; Lin, Carol Sze Ki

    2015-07-01

    Depletion of fossil fuels and environmental problems are encouraging research on alternative fuels of renewable sources. Biodiesel is a promising alternative fuel to be used as a substitute to the petroleum based diesel fuels. However, the cost of biodiesel production is high and is attributed mainly to the feedstock used which leads to the investigation of low cost feedstocks that are economically feasible. In this paper, we report on the utilization of lipid obtained from food waste as a low-cost feedstock for biodiesel production. Lipid from food waste was transesterified with methanol using base and lipase as catalysts. The maximum biodiesel yield was 100% for the base (KOH) catalyzed transesterification at 1:10M ratio of lipid to methanol in 2h at 60°C. Novozyme-435 yielded a 90% FAME conversion at 40°C and 1:5 lipid to methanol molar ratio in 24h. Lipid obtained from fungal hydrolysis of food waste is found to be a suitable feedstock for biodiesel production. Copyright © 2015 Elsevier Ltd. All rights reserved.

  6. Method for producing synthetic fuels from solid waste

    DOEpatents

    Antal, Jr., Michael J.

    1976-11-23

    Organic solid wastes represented by the general chemical formula C.sub.X H.sub.Y O.sub.Z are reacted with steam at elevated temperatures to produce H.sub.2 and CO.sub.2. The overall process is represented by the reaction C.sub.X H.sub.Y O.sub.Z + 2(X-Z/2)H.sub.2 O.fwdarw..sup..delta.XCO.sub.2 + [(Y/2) + 2(X-Z/2)] H.sub.2 . (1) reaction (1) is endothermic and requires heat. This heat is supplied by a tower top solar furnace; alternatively, some of the solid wastes can be burned to supply heat for the reaction. The hydrogen produced by reaction (1) can be used as a fuel or a chemical feedstock. Alternatively, methanol can be produced by the commercial process CO.sub.2 + 3H.sub.2 .fwdarw. CH.sub.3 OH + H.sub.2 O . (2) since reaction (1) is endothermic, the system represents a method for storing heat energy from an external source in a chemical fuel produced from solid wastes.

  7. Sustainability assessment and prioritisation of e-waste management options in Brazil.

    PubMed

    de Souza, Ricardo Gabbay; Clímaco, João C Namorado; Sant'Anna, Annibal Parracho; Rocha, Tiago Barreto; do Valle, Rogério de Aragão Bastos; Quelhas, Osvaldo Luiz Gonçalves

    2016-11-01

    Brazil has an increasing rate of e-waste generation, but there are currently few adequate management systems in operation, with the largest share of Waste Electrical and Electronic Equipment (WEEE) going to landfill sites or entering informal chains. The National Solid Waste Policy (2010) enforces the implementation of reverse logistics systems under the shared responsibility of consumers, companies and governments. The objective of this paper is to assess sustainability and prioritise system alternatives for potential implementation in the metropolitan region of Rio de Janeiro. Sustainability criteria and decision alternatives were defined by elicitation of stakeholders. The adopted multicriteria approach combines Life Cycle Assessment with qualitative evaluations by a small sample of regional experts with knowledge of the problem. The recommended system consists of a hybrid WEEE collection scheme with delivery points at shops, metro stations and neighbourhood centres; a pre-treatment phase with the involvement of private companies, cooperatives and social enterprises; and full recycling of all components in the country. Copyright © 2016 Elsevier Ltd. All rights reserved.

  8. An integrated approach for the management of demolition waste in Cyprus.

    PubMed

    Kourmpanis, Basilis; Papadopoulos, Achilleas; Moustakas, Konstantinos; Kourmoussis, Fotis; Stylianou, Marinos; Loizidou, Maria

    2008-12-01

    This study investigated the generation and management of demolition waste (DW) in Cyprus. A methodology has been developed and applied for the estimation of the quantities of the waste stream under examination, since quantitative primary data were not available. The existing situation relating to the practices applied for the management of DW was investigated and assessed. Furthermore, a multi-criteria analysis method (PROMETHEE II) was developed and applied in order to examine alternative systems that could be implemented for the management of the DW in the country. In particular, nine management systems (scenarios) were examined, evaluated and ranked according to their efficiency using seventeen individual criteria, divided into four groups (social-legislative, environmental, economic and technical). The ranking of the alternative waste management scenarios indicated that the optimum management system for possible implementation in the island included complete selective demolition procedures and transfer of mixed recyclable materials to the recycling centre and non-recyclable material to landfill.

  9. A Remote Absorption Process for Disposal of Evaporate and Reverse Osmosis Concentrates

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Brunsell, D.A.

    2008-07-01

    Many commercial nuclear plants and DOE facilities generate secondary waste streams consisting of evaporator bottoms and reverse osmosis (RO) concentrate. Since liquids are not permitted in disposal facilities, these waste streams must be converted to dry solids, either by evaporation to dried solids or by solidification to liquid-free solids. Evaporation of the liquid wastes reduces their volume, but requires costly energy and capital equipment. In some cases, concentration of the contaminants during drying can cause the waste to exceed Class A waste for nuclear utilities or exceed DOE transuranic limits. This means that disposal costs will be increased, or that,more » when the Barnwell, SC disposal site closes to waste outside of the Atlantic Compact in July 2008, the waste will be precluded from disposal for the foreseeable future). Solidification with cement agents requires less energy and equipment than drying, but results in a volume increase of 50-100%. The doubling or tripling of waste weight, along with the increased volume, sharply increases shipping and disposal costs. Confronted with these unattractive alternatives, Diversified Technologies Services (DTS), in conjunction with selected nuclear utilities and D and D operations at Rocky Flats, undertook an exploratory effort to convert this liquid wastewater to a solid without using cement. This would avoid the bulking effect of cement, and permit the waste to be disposed of the Energy Solutions facility in Utah as well as some DOE facilities. To address the need for an attractive alternative to drying and cement solidification, a test program was developed using a polymer absorbent media to convert the concentrate streams to a liquid-free waste form that meets the waste acceptance criteria of the pertinent burial sites. Two approaches for mixing the polymer with the liquid were tested: mechanical mixing and in-situ incorporation. As part of this test program, a process control program (PCP) was developed that is 100% scalable from a concentrate test sample as small as 50 grams to full-scale processing of 100 cubic foot containers or larger. In summary: The absorption process offers utilities a viable and less costly alternative to on-site drying or solidification of concentrates. The absorption process can be completed by site personnel or by a vendor as a turnkey service. The process is suitable for multiple types of waste, including RO and evaporator concentrates, sludges, and other difficult to process waters and wet solids. (author)« less

  10. Mixed waste landfill corrective measures study final report Sandia National Laboratories, Albuquerque, New Mexico.

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Peace, Gerald; Goering, Timothy James

    2004-03-01

    The Mixed Waste Landfill occupies 2.6 acres in the north-central portion of Technical Area 3 at Sandia National Laboratories, Albuquerque, New Mexico. The landfill accepted low-level radioactive and mixed waste from March 1959 to December 1988. This report represents the Corrective Measures Study that has been conducted for the Mixed Waste Landfill. The purpose of the study was to identify, develop, and evaluate corrective measures alternatives and recommend the corrective measure(s) to be taken at the site. Based upon detailed evaluation and risk assessment using guidance provided by the U.S. Environmental Protection Agency and the New Mexico Environment Department, themore » U.S. Department of Energy and Sandia National Laboratories recommend that a vegetative soil cover be deployed as the preferred corrective measure for the Mixed Waste Landfill. The cover would be of sufficient thickness to store precipitation, minimize infiltration and deep percolation, support a healthy vegetative community, and perform with minimal maintenance by emulating the natural analogue ecosystem. There would be no intrusive remedial activities at the site and therefore no potential for exposure to the waste. This alternative poses minimal risk to site workers implementing institutional controls associated with long-term environmental monitoring as well as routine maintenance and surveillance of the site.« less

  11. Construction and operation of an industrial solid waste landfill at Portsmouth Gaseous Diffusion Plant, Piketon, Ohio

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    NONE

    1995-10-01

    The US Department of Energy (DOE), Office of Waste Management, proposes to construct and operate a solid waste landfill within the boundary of the Portsmouth Gaseous Diffusion Plant (PORTS), Piketon, Ohio. The purpose of the proposed action is to provide PORTS with additional landfill capacity for non-hazardous and asbestos wastes. The proposed action is needed to support continued operation of PORTS, which generates non-hazardous wastes on a daily basis and asbestos wastes intermittently. Three alternatives are evaluated in this environmental assessment (EA): the proposed action (construction and operation of the X-737 landfill), no-action, and offsite shipment of industrial solid wastesmore » for disposal.« less

  12. Potential use of Plastic Waste as Construction Materials: Recent Progress and Future Prospect

    NASA Astrophysics Data System (ADS)

    Kamaruddin, M. A.; Abdullah, M. M. A.; Zawawi, M. H.; Zainol, M. R. R. A.

    2017-11-01

    Plastic associates products based have been considered as the world most consumer packaging solution. However, substantial quantities of plastic consumption have led to exponential increase of plastic derived waste. Recycling of plastic waste as valued added product such as concrete appears as one of promising solution for alternative use of plastic waste. This paper summarized recent progress on the development of concrete mixture which incorporates plastic wastes as partial aggregate replacement during concrete manufacturing. A collection of data from previous studies that have been researched which employed plastic waste in concrete mixtures were evaluated and conclusions are drawn based on the laboratory results of all the mentioned research papers studied.

  13. Estimation of marginal costs at existing waste treatment facilities.

    PubMed

    Martinez-Sanchez, Veronica; Hulgaard, Tore; Hindsgaul, Claus; Riber, Christian; Kamuk, Bettina; Astrup, Thomas F

    2016-04-01

    This investigation aims at providing an improved basis for assessing economic consequences of alternative Solid Waste Management (SWM) strategies for existing waste facilities. A bottom-up methodology was developed to determine marginal costs in existing facilities due to changes in the SWM system, based on the determination of average costs in such waste facilities as function of key facility and waste compositional parameters. The applicability of the method was demonstrated through a case study including two existing Waste-to-Energy (WtE) facilities, one with co-generation of heat and power (CHP) and another with only power generation (Power), affected by diversion strategies of five waste fractions (fibres, plastic, metals, organics and glass), named "target fractions". The study assumed three possible responses to waste diversion in the WtE facilities: (i) biomass was added to maintain a constant thermal load, (ii) Refused-Derived-Fuel (RDF) was included to maintain a constant thermal load, or (iii) no reaction occurred resulting in a reduced waste throughput without full utilization of the facility capacity. Results demonstrated that marginal costs of diversion from WtE were up to eleven times larger than average costs and dependent on the response in the WtE plant. Marginal cost of diversion were between 39 and 287 € Mg(-1) target fraction when biomass was added in a CHP (from 34 to 303 € Mg(-1) target fraction in the only Power case), between -2 and 300 € Mg(-1) target fraction when RDF was added in a CHP (from -2 to 294 € Mg(-1) target fraction in the only Power case) and between 40 and 303 € Mg(-1) target fraction when no reaction happened in a CHP (from 35 to 296 € Mg(-1) target fraction in the only Power case). Although average costs at WtE facilities were highly influenced by energy selling prices, marginal costs were not (provided a response was initiated at the WtE to keep constant the utilized thermal capacity). Failing to systematically address and include costs in existing waste facilities in decision-making may unintendedly lead to higher overall costs at societal level. To avoid misleading conclusions, economic assessment of alternative SWM solutions should not only consider potential costs associated with alternative treatment but also include marginal costs associated with existing facilities. Copyright © 2016 Elsevier Ltd. All rights reserved.

  14. Hazardous Waste and Wastewater Characterization Survey, Columbus AFB, Mississippi

    DTIC Science & Technology

    1988-06-01

    behind bldg 322 (Liquid Fuels Maintenance Branch). These wastes are then picked up by a waste oil contractor. All other drummed wastes are disposed of...is responsible for custody of the waste until a contractor (currently, Chemical Waste Management) comes to pick up the waste. Prior to disposal...chemicals are used up in the process. Any leftover chemicals are drained and stored in containers for use at a later time. All empty containers are

  15. 40 CFR 761.347 - First level sampling-waste from existing piles.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... Purposes of Characterization for PCB Disposal in Accordance With § 761.62, and Sampling PCB Remediation... a cone; that is, having a circular base with PCB bulk product waste or PCB remediation waste... one pile. If the PCB bulk product waste or PCB remediation waste consists of more than one pile or...

  16. 40 CFR 194.8 - Approval process for waste shipment from waste generator sites for disposal at the WIPP.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... waste generator site will be conveyed in a letter from the Administrator's authorized representative to... transmittal to the WIPP Waste Information System database of waste characterization data, in accordance with... will be conveyed in a letter from the Administrator's authorized representative to DOE. EPA will not...

  17. 40 CFR 194.8 - Approval process for waste shipment from waste generator sites for disposal at the WIPP.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... waste generator site will be conveyed in a letter from the Administrator's authorized representative to... transmittal to the WIPP Waste Information System database of waste characterization data, in accordance with... will be conveyed in a letter from the Administrator's authorized representative to DOE. EPA will not...

  18. 40 CFR 194.8 - Approval process for waste shipment from waste generator sites for disposal at the WIPP.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... waste generator site will be conveyed in a letter from the Administrator's authorized representative to... transmittal to the WIPP Waste Information System database of waste characterization data, in accordance with... will be conveyed in a letter from the Administrator's authorized representative to DOE. EPA will not...

  19. 40 CFR 194.8 - Approval process for waste shipment from waste generator sites for disposal at the WIPP.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... waste generator site will be conveyed in a letter from the Administrator's authorized representative to... transmittal to the WIPP Waste Information System database of waste characterization data, in accordance with... will be conveyed in a letter from the Administrator's authorized representative to DOE. EPA will not...

  20. Melt processed crystalline ceramic waste forms for advanced nuclear fuel cycles: CRP T21027 1813: Processing technologies for high level waste, formulation of matrices and characterization of waste forms, task 17208: Final report

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Amoroso, J. W.; Marra, J. C.

    2015-08-26

    A multi-phase ceramic waste form is being developed at the Savannah River National Laboratory (SRNL) for treatment of secondary waste streams generated by reprocessing commercial spent nuclear. The envisioned waste stream contains a mixture of transition, alkali, alkaline earth, and lanthanide metals. Ceramic waste forms are tailored (engineered) to incorporate waste components as part of their crystal structure based on knowledge from naturally found minerals containing radioactive and non-radioactive species similar to the radionuclides of concern in wastes from fuel reprocessing. The ability to tailor ceramics to mimic naturally occurring crystals substantiates the long term stability of such crystals (ceramics)more » over geologic timescales of interest for nuclear waste immobilization [1]. A durable multi-phase ceramic waste form tailored to incorporate all the waste components has the potential to broaden the available disposal options and thus minimize the storage and disposal costs associated with aqueous reprocessing. This report summarizes results from three years of work on the IAEA Coordinated Research Project on “Processing technologies for high level waste, formulation of matrices and characterization of waste forms” (T21027), and specific task “Melt Processed Crystalline Ceramic Waste Forms for Advanced Nuclear Fuel Cycles” (17208).« less

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