Sample records for waste characterization requirements

  1. Waste Generation Overview, Course 23263

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Simpson, Lewis Edward

    This course, Waste Generation Overview Live (COURSE 23263), provides an overview of federal and state waste management regulations, as well as Los Alamos National Laboratory (LANL) policies and procedures for waste management operations. The course covers the activities involved in the cradle-to-grave waste management process and focuses on waste characterization, waste compatibility determinations and classification, and the storage requirements for temporary waste accumulation areas at LANL. When you have completed this course, you will be able to recognize federal, state, and LANL environmental requirements and their impact on waste operations; recognize the importance of the cradle-to-grave waste management process; identifymore » the roles and responsibilities of key LANL waste management personnel (e.g., Waste Generator, Waste Management Coordinator, Waste Stream Profile approver, and Waste Certification Official); characterize a waste stream to determine whether it meets the definition of a hazardous waste, as well as characterize the use and minimum requirements for use of acceptable knowledge (AK) for waste characterization and waste compatibility documentation requirements; and identify the requirements for setting up and managing temporary waste accumulation areas.« less

  2. Adequacy of a Small Quantity Site RH-TRU Waste Program in Meeting Proposed WIPP Characterization Objectives

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Biedscheid, J.; Stahl, S.; Devarakonda, M.

    2002-02-26

    The first remote-handled transuranic (RH-TRU) waste is expected to be permanently disposed of at the Waste Isolation Pilot Plant (WIPP) during Fiscal Year (FY) 2003. The first RH-TRU waste shipments are scheduled from the Battelle Columbus Laboratories (BCL) to WIPP in order to facilitate compliance with BCL Decommissioning Project (BCLDP) milestones. Milestones requiring RH-TRU waste containerization and removal from the site by 2004 in order to meet a 2006 site closure goal, established by Congress in the Defense Facilities Closure Projects account, necessitated the establishment and implementation of a site-specific program to direct the packaging of BCLDP RH-TRU waste priormore » to the finalization of WIPP RH-TRU waste characterization requirements. The program was designed to collect waste data, including audio and videotape records of waste packaging, such that upon completion of waste packaging, comprehensive data records exist from which compliance with final WIPP RH-TRU waste characterization requirements can be demonstrated. With the BCLDP data records generated to date and the development by the U.S. Department of Energy (DOE)-Carlsbad Field Office (CBFO) of preliminary documents proposing the WIPP RH-TRU waste characterization program, it is possible to evaluate the adequacy of the BCLDP program with respect to meeting proposed characterization objectives. The BCLDP characterization program uses primarily acceptable knowledge (AK) and visual examination (VE) during waste packaging to characterize RH-TRU waste. These methods are used to estimate physical waste parameters, including weight percentages of metals, cellulosics, plastics, and rubber in the waste, and to determine the absence of prohibited items, including free liquids. AK combined with computer modeling is used to estimate radiological waste parameters, including total activity on a waste container basis, for the majority of BCLDP RH-TRU waste. AK combined with direct analysis is used to characterize radiological parameters for the small populations of the RH-TRU waste generated by the BCLDP. All characterization based on AK is verified. Per its design for comprehensive waste data collection, the BCLDP characterization program using AK and waste packaging procedures, including VE during packaging, meets the proposed WIPP RH-TRU waste characterization objectives. The conservative program design implemented generates certification data that will be adequate to meet any additional program requirements that may be imposed by the CBFO.« less

  3. Waste Characterization Methods

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Vigil-Holterman, Luciana R.; Naranjo, Felicia Danielle

    2016-02-02

    This report discusses ways to classify waste as outlined by LANL. Waste Generators must make a waste determination and characterize regulated waste by appropriate analytical testing or use of acceptable knowledge (AK). Use of AK for characterization requires several source documents. Waste characterization documentation must be accurate, sufficient, and current (i.e., updated); relevant and traceable to the waste stream’s generation, characterization, and management; and not merely a list of information sources.

  4. RH-TRU Waste Inventory Characterization by AK and Proposed WIPP RH-TRU Waste Characterization Objectives

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Most, W. A.; Kehrman, R.; Gist, C.

    2002-02-26

    The U.S. Department of Energy (DOE)-Carlsbad Field Office (CBFO) has developed draft documentation to present the proposed Waste Isolation Pilot Plant (WIPP) remote-handled (RH-) transuranic (TRU) waste characterization program to its regulators, the U.S. Environmental Protection Agency and the New Mexico Environment Department. Compliance with Title 40, Code of Federal Regulations, Parts 191 and 194; the WIPP Land Withdrawal Act (PL 102-579); and the WIPP Hazardous Waste Facility Permit, as well as the Certificates of Compliance for the 72-B and 10-160B Casks, requires that specific waste parameter limits be imposed on DOE sites disposing of TRU waste at WIPP. Themore » DOE-CBFO must control the sites' compliance with the limits by specifying allowable characterization methods. As with the established WIPP contact handled TRU waste characterization program, the DOE-CBFO has proposed a Remote-Handled TRU Waste Acceptance Criteria (RH-WAC) document consolidating the requirements from various regulatory drivers and proposed allowable characterization methods. These criteria are consistent with the recommendation of a recent National Academy Sciences/National Research Council to develop an RH-TRU waste characterization approach that removes current self imposed requirements that lack a legal or safety basis. As proposed in the draft RH-WAC and other preliminary documents, the DOE-CBFO RH-TRU waste characterization program proposes the use of acceptable knowledge (AK) as the primary method for obtaining required characterization information. The use of AK involves applying knowledge of the waste in light of the materials or processes used to generate the waste. Documentation, records, or processes providing information about various attributes of a waste stream, such as chemical, physical, and radiological properties, may be used as AK and may be applied to individual waste containers either independently or in conjunction with radiography, visual examination, assay, and other sampling and analytical data. RH-TRU waste cannot be shipped to WIPP on the basis of AK alone if documentation demonstrating that all of the prescribed limits in the RH-WAC are met is not available, discrepancies exist among AK source documents describing the same waste stream and the most conservative assumptions regarding those documents indicates that a limit will not be met, or all required data are not available for a given waste stream.« less

  5. Dose potential of sludge contaminated and/or TRU contaminated waste in B-25s for tornado and straight wind events

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Aponte, C.I.

    F and H Tank Farms generate supernate and sludge contaminated Low-Level Waste. The waste is collected, characterized, and packaged for disposal. Before the waste can be disposed of, however, it must be properly characterized. Since the radionuclide distribution in typical supernate is well known, its characterization is relatively straight forward and requires minimal effort. Non-routine waste, including potentially sludge contaminated, requires much more effort to effectively characterize. The radionuclide distribution must be determined. In some cases the waste can be contaminated by various sludge transfers with unique radionuclide distributions. In these cases, the characterization can require an extensive effort. Evenmore » after an extensive characterization effort, the container must still be prepared for shipping. Therefore a significant amount of time may elapse from the time the waste is generated until the time of disposal. During the time it is possible for a tornado or high wind scenario to occur. The purpose of this report is to determine the effect of a tornado on potential sludge contaminated waste, or Transuranic (TRU) waste in B-25s [large storage containers], to evaluate the potential impact on F and H Tank Farms, and to help establish a B-25 control program for tornado events.« less

  6. Waste certification program plan for Oak Ridge National Laboratory. Revision 1

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Orrin, R.C.

    1997-05-01

    This document defines the waste certification program developed for implementation at Oak Ridge National Laboratory (ORNL). The document describes the program structure, logic, and methodology for certification of ORNL wastes. The purpose of the waste certification program is to provide assurance that wastes are properly characterized and that the Waste Acceptance Criteria (WAC) for receiving facilities are met. The program meets the waste certification requirements outlined in US Department of Energy (DOE) Order 5820.2A, Radioactive Waste Management, and ensures that 40 CFR documentation requirements for waste characterization are met for mixed (both radioactive and hazardous) and hazardous (including polychlorinated biphenyls)more » waste. Program activities will be conducted according to ORNL Level 1 document requirements.« less

  7. Project Management Plan for the Idaho National Engineering Laboratory Waste Isolation Pilot Plant Experimental Test Program

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Connolly, M.J.; Sayer, D.L.

    1993-11-01

    EG&G Idaho, Inc. and Argonne National Laboratory-West (ANL-W) are participating in the Idaho National Engineering Laboratory`s (INEL`s) Waste Isolation Pilot Plant (WIPP) Experimental Test Program (WETP). The purpose of the INEL WET is to provide chemical, physical, and radiochemical data on transuranic (TRU) waste to be stored at WIPP. The waste characterization data collected will be used to support the WIPP Performance Assessment (PA), development of the disposal No-Migration Variance Petition (NMVP), and to support the WIPP disposal decision. The PA is an analysis required by the Code of Federal Regulations (CFR), Title 40, Part 191 (40 CFR 191), whichmore » identifies the processes and events that may affect the disposal system (WIPP) and examines the effects of those processes and events on the performance of WIPP. A NMVP is required for the WIPP by 40 CFR 268 in order to dispose of land disposal restriction (LDR) mixed TRU waste in WIPP. It is anticipated that the detailed Resource Conservation and Recovery Act (RCRA) waste characterization data of all INEL retrievably-stored TRU waste to be stored in WIPP will be required for the NMVP. Waste characterization requirements for PA and RCRA may not necessarily be identical. Waste characterization requirements for the PA will be defined by Sandia National Laboratories. The requirements for RCRA are defined in 40 CFR 268, WIPP RCRA Part B Application Waste Analysis Plan (WAP), and WIPP Waste Characterization Program Plan (WWCP). This Project Management Plan (PMP) addresses only the characterization of the contact handled (CH) TRU waste at the INEL. This document will address all work in which EG&G Idaho is responsible concerning the INEL WETP. Even though EG&G Idaho has no responsibility for the work that ANL-W is performing, EG&G Idaho will keep a current status and provide a project coordination effort with ANL-W to ensure that the INEL, as a whole, is effectively and efficiently completing the requirements for WETP.« less

  8. EVALUATION OF RISKS AND WASTE CHARACTERIZATION REQUIREMENTS FOR THE TRANSURANIC WASTE EMPLACED IN WIPP DURING 1999

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Channell, J.K.; Walker, B.A.

    2000-05-01

    Specifically this report: 1. Compares requirements of the WAP that are pertinent from a technical viewpoint with the WIPP pre-Permit waste characterization program, 2. Presents the results of a risk analysis of the currently emplaced wastes. Expected and bounding risks from routine operations and possible accidents are evaluated; and 3. Provides conclusions and recommendations.

  9. 1998 report on Hanford Site land disposal restrictions for mixed waste

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Black, D.G.

    1998-04-10

    This report was submitted to meet the requirements of Hanford Federal Facility Agreement and Consent Order (Tri-Party Agreement) Milestone M-26-01H. This milestone requires the preparation of an annual report that covers characterization, treatment, storage, minimization, and other aspects of managing land-disposal-restricted mixed waste at the Hanford Facility. The US Department of Energy, its predecessors, and contractors on the Hanford Facility were involved in the production and purification of nuclear defense materials from the early 1940s to the late 1980s. These production activities have generated large quantities of liquid and solid mixed waste. This waste is regulated under authority of bothmore » the Resource Conservation and Recovery Act of l976 and the Atomic Energy Act of 1954. This report covers only mixed waste. The Washington State Department of Ecology, US Environmental Protection Agency, and US Department of Energy have entered into the Tri-Party Agreement to bring the Hanford Facility operations into compliance with dangerous waste regulations. The Tri-Party Agreement required development of the original land disposal restrictions (LDR) plan and its annual updates to comply with LDR requirements for mixed waste. This report is the eighth update of the plan first issued in 1990. The Tri-Party Agreement requires and the baseline plan and annual update reports provide the following information: (1) Waste Characterization Information -- Provides information about characterizing each LDR mixed waste stream. The sampling and analysis methods and protocols, past characterization results, and, where available, a schedule for providing the characterization information are discussed. (2) Storage Data -- Identifies and describes the mixed waste on the Hanford Facility. Storage data include the Resource Conservation and Recovery Act of 1976 dangerous waste codes, generator process knowledge needed to identify the waste and to make LDR determinations, quantities stored, generation rates, location and method of storage, an assessment of storage-unit compliance status, storage capacity, and the bases and assumptions used in making the estimates.« less

  10. DOE's Remote-Handled TRU Waste Characterization Program: Implementation Plan

    EPA Pesticide Factsheets

    Remote-handled (RH) transuranic (TRU) waste characterization, which involves obtaining chemical, radiological, and physical data, is a primary component of ensuring compliance of the Waste Isolation Pilot Plant (WIPP) with regulatory requirements.

  11. Data Quality Objectives for Regulatory Requirements for Dangerous Waste Sampling and Analysis

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    MULKEY, C.H.

    1999-07-02

    This document describes sampling and analytical requirements needed to meet state and federal regulations for dangerous waste (DW). The River Protection Project (RPP) is assigned to the task of storage and interim treatment of hazardous waste. Any final treatment or disposal operations, as well as requirements under the land disposal restrictions (LDRs), fall in the jurisdiction of another Hanford organization and are not part of this scope. The requirements for this Data Quality Objective (DQO) Process were developed using the RPP Data Quality Objective Procedure (Banning 1996), which is based on the U.S. Environmental Protection Agency's (EPA) Guidance for themore » Data Quality Objectives Process (EPA 1994). Hereafter, this document is referred to as the DW DQO. Federal and state laws and regulations pertaining to waste contain requirements that are dependent upon the composition of the waste stream. These regulatory drivers require that pertinent information be obtained. For many requirements, documented process knowledge of a waste composition can be used instead of analytical data to characterize or designate a waste. When process knowledge alone is used to characterize a waste, it is a best management practice to validate the information with analytical measurements.« less

  12. Enclosure (from letter from EPA to DOE sent 3/26/04) - Technical and Regulatory Support Document: EPA's Remote Handled Waste Characterization Determination

    EPA Pesticide Factsheets

    Based on the requirements presented in 40 CFR 194.24(c )(2) to (4) and 194.22(a)(1) and using experience gained as part of the CH waste characterization program, EPA examined the DOE's RH Waste Characterization Proposal as presented in the WCPIP.

  13. The role of acceptable knowledge in transuranic waste disposal operations - 11117

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Chancellor, Christopher John; Nelson, Roger

    2010-11-08

    The Acceptable Knowledge (AK) process plays a key role in the delineation of waste streams destined for the Waste Isolation Pilot Plant (WIPP). General Electric's Vallecitos Nuclear Center (GEVNC) provides for an ideal case study of the application of AK in a multiple steward environment. In this review we will elucidate the pivotal role Acceptable Knowledge played in segregating Department of Energy (DOE) responsibilities from a commercial facility. The Acceptable Knowledge process is a necessary component of waste characterization that determines whether or not a waste stream may be considered for disposal at the WIPP site. This process may bemore » thought of as an effort to gain a thorough understanding of the waste origin, chemical content, and physical form gleaned by the collection of documentation that concerns generator/storage site history, mission, and operations; in addition to waste stream specific information which includes the waste generation process, the waste matrix, the quantity of waste concerned, and the radiological and chemical make up of the waste. The collection and dissemination of relevant documentation is the fundamental requirement for the AK process to work. Acceptable Knowledge is the predominant process of characterization and, therefore, a crucial part of WIPP's transuranic waste characterization program. This characterization process, when conducted to the standards set forth in WIPP's operating permit, requires confirmation/verification by physical techniques such as Non-Destructive Examination (NDE), Visual Examination (VE), and Non-Destructive Assay (NDA). These physical characterization techniques may vary in their appropriateness for a given waste stream; however, nothing will allow the substitution or exclusion of AK. Beyond the normal scope of operations, AK may be considered, when appropriate, a surrogate for the physical characterization techniques in a procedure that appeals to concepts such As Low As Reasonably Achievable (ALARA) and budgetary savings. This substitution is referred to as an Acceptable Knowledge Sufficiency Determination. With a Sufficiency Determination Request, AK may supplant the need for one or all of the physical analysis methods. This powerful procedure may be used on a scale as small as a single container to that of a vast waste stream. Only under the most stringent requirements will an AK Sufficiency Determination be approved by the regulators and, to date, only six such Sufficiency Determinations have been approved. Although Acceptable Knowledge is legislated into the operational procedures of the WIPP facility there is more to it than compliance. AK is not merely one of a long list of requirements in the characterization and verification of transuranic (TRU) waste destined for the WIPP. Acceptable Knowledge goes beyond the regulatory threshold by offering a way to reduce risk, cost, time, and uncertainty on its own laurels. Therefore, AK alone can be argued superior to any other waste characterization technique.« less

  14. WIPP waste characterization program sampling and analysis guidance manual

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Not Available

    1991-01-01

    The Waste Isolation Pilot Plant (WIPP) Waste Characterization Program Sampling and Analysis Guidance Manual (Guidance Manual) provides a unified source of information on the sampling and analytical techniques that enable Department of Energy (DOE) facilities to comply with the requirements established in the current revision of the Quality Assurance Program Plan (QAPP) for the WIPP Experimental-Waste Characterization Program (the Program). This Guidance Manual includes all of the sampling and testing methodologies accepted by the WIPP Project Office (DOE/WPO) for use in implementing the Program requirements specified in the QAPP. This includes methods for characterizing representative samples of transuranic (TRU) wastesmore » at DOE generator sites with respect to the gas generation controlling variables defined in the WIPP bin-scale and alcove test plans, as well as waste container headspace gas sampling and analytical procedures to support waste characterization requirements under the WIPP test program and the Resource Conservation and Recovery Act (RCRA). The procedures in this Guidance Manual are comprehensive and detailed and are designed to provide the necessary guidance for the preparation of site specific procedures. The use of these procedures is intended to provide the necessary sensitivity, specificity, precision, and comparability of analyses and test results. The solutions to achieving specific program objectives will depend upon facility constraints, compliance with DOE Orders and DOE facilities' operating contractor requirements, and the knowledge and experience of the TRU waste handlers and analysts. With some analytical methods, such as gas chromatography/mass spectrometry, the Guidance Manual procedures may be used directly. With other methods, such as nondestructive/destructive characterization, the Guidance Manual provides guidance rather than a step-by-step procedure.« less

  15. EPA's Review of DOE's Inventory Tracking for TRU Wastes at Waste Control Specialists

    EPA Pesticide Factsheets

    On April 9, 2014, EPA's Waste Isolation Pilot Plant (WIPP) waste characterization team visited Waste Control Specialists (WCS) to determine whether DOE was meeting EPA's waste inventory tracking requirements at 40 CFR 194.24(c)(4).

  16. Characterization of the Old Hydrofracture Facility (OHF) waste tanks located at ORNL

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Keller, J.M.; Giaquinto, J.M.; Meeks, A.M.

    1997-04-01

    The Old Hydrofracture Facility (OHF) is located in Melton Valley within Waste Area Grouping (WAG) 5 and includes five underground storage tanks (T1, T2, T3, T4, and T9) ranging from 13,000 to 25,000 gal. capacity. During the period of 1996--97 there was a major effort to re-sample and characterize the contents of these inactive waste tanks. The characterization data summarized in this report was needed to address waste processing options, examine concerns dealing with the performance assessment (PA) data for the Waste Isolation Pilot Plant (WIPP), evaluate the waste characteristics with respect to the waste acceptance criteria (WAC) for WIPPmore » and Nevada Test Site (NTS), address criticality concerns, and to provide the data needed to meet DOT requirements for transporting the waste. This report discusses the analytical characterization data collected on both the supernatant and sludge samples taken from three different locations in each of the OHF tanks. The isotopic data presented in this report supports the position that fissile isotopes of uranium ({sup 233}U and {sup 235}U) do not satisfy the denature ratios required by the administrative controls stated in the ORNL LLLW waste acceptance criteria (WAC). The fissile isotope of plutonium ({sup 239}Pu and {sup 241}Pu) are diluted with thorium far above the WAC requirements. In general, the OHF sludge was found to be hazardous (RCRA) based on total metal content and the transuranic alpha activity was well above the 100 nCi/g limit for TRU waste. The characteristics of the OHF sludge relative to the WIPP WAC limits for fissile gram equivalent, plutonium equivalent activity, and thermal power from decay heat were estimated from the data in this report and found to be far below the upper boundary for any of the remote-handled transuranic waste (RH-TRU) requirements for disposal of the waste in WIPP.« less

  17. Characterization of the MVST waste tanks located at ORNL

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Keller, J.M.; Giaquinto, J.M.; Meeks, A.M.

    During the fall of 1996 there was a major effort to sample and analyze the Active Liquid Low-Level Waste (LLLW) tanks at ORNL which include the Melton Valley Storage Tanks (MVST) and the Bethel Valley Evaporator Service Tanks (BVEST). The characterization data summarized in this report was needed to address waste processing options, address concerns of the performance assessment (PA) data for the Waste Isolation Pilot Plant (WIPP), evaluate the characteristics with respect to the waste acceptance criteria (WAC) for WIPP and Nevada Test Site (NTS), address criticality concerns, and meet DOT requirements for transporting the waste. This report onlymore » discusses the analytical characterization data for the MVST waste tanks. The isotopic data presented in this report support the position that fissile isotopes of uranium and plutonium were ``denatured`` as required by administrative controls. In general, MVST sludge was found to be both hazardous by RCRA characteristics and the transuranic alpha activity was well about the limit for TRU waste. The characteristics of the MVST sludge relative to the WIPP WAC limits for fissile gram equivalent, plutonium equivalent activity, and thermal power from decay heat, were estimated from the data in this report and found to be far below the upper boundary for any of the remote-handled transuranic waste requirements for disposal of the waste in WIPP.« less

  18. Assessment of remote sensing technologies to discover and characterize waste sites

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    NONE

    1992-03-11

    This report presents details about waste management practices that are being developed using remote sensing techniques to characterize DOE waste sites. Once the sites and problems have been located and characterized and an achievable restoration and remediation program have been established, efforts to reclaim the environment will begin. Special problems to be considered are: concentrated waste forms in tanks and pits; soil and ground water contamination; ground safety hazards for workers; and requirement for long-term monitoring.

  19. RH-TRU Waste Characterization by Acceptable Knowledge at the Idaho National Engineering and Environmental Laboratory

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Schulz, C.; Givens, C.; Bhatt, R.

    2003-02-24

    Idaho National Engineering and Environmental Laboratory (INEEL) is conducting an effort to characterize approximately 620 drums of remote-handled (RH-) transuranic (TRU) waste currently in its inventory that were generated at the Argonne National Laboratory-East (ANL-E) Alpha Gamma Hot Cell Facility (AGHCF) between 1971 and 1995. The waste was generated at the AGHCF during the destructive examination of irradiated and unirradiated fuel pins, targets, and other materials from reactor programs at ANL-West (ANL-W) and other Department of Energy (DOE) reactors. In support of this effort, Shaw Environmental and Infrastructure (formerly IT Corporation) developed an acceptable knowledge (AK) collection and management programmore » based on existing contact-handled (CH)-TRU waste program requirements and proposed RH-TRU waste program requirements in effect in July 2001. Consistent with Attachments B-B6 of the Waste Isolation Pilot Plant (WIPP) Hazardous Waste Facility Permit (HWFP) and th e proposed Class 3 permit modification (Attachment R [RH-WAP] of this permit), the draft AK Summary Report prepared under the AK procedure describes the waste generating process and includes determinations in the following areas based on AK: physical form (currently identified at the Waste Matrix Code level); waste stream delineation; applicability of hazardous waste numbers for hazardous waste constituents; and prohibited items. In addition, the procedure requires and the draft summary report contains information supporting determinations in the areas of defense relationship and radiological characterization.« less

  20. Alternative Radiological Characterization of Sealed Source TRU Waste for WIPP Disposal (LAUR-05-8776)

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Whitworth, J.; Pearson, M.; Feldman, A.

    2006-07-01

    The Offsite Source Recovery (OSR) Project at Los Alamos National Laboratory is now shipping transuranic (TRU) waste containers to the Waste Isolation Pilot Plant (WIPP) in New Mexico for disposal. Sealed source waste disposal has become possible in part because OSR personnel were able to obtain Environmental Protection Agency (EPA) and DOE-CBFO approval for an alternative radiological characterization procedure relying on acceptable knowledge (AK) and modeling, rather than on non-destructive assay (NDA) of each container. This is the first successful qualification of an 'alternate methodology' under the radiological characterization requirements of the WIPP Waste Acceptance Criteria (WAC) by any TRUmore » waste generator site. This paper describes the approach OSR uses to radiologically characterize its sealed source waste and the process by which it obtained certification of this approach. (authors)« less

  1. The Advancement of Public Awareness, Concerning TRU Waste Characterization, Using a Virtual Document

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    West, T. B.; Burns, T. P.; Estill, W. G.

    2002-02-28

    Building public trust and confidence through openness is a goal of the DOE Carlsbad Field Office for the Waste Isolation Pilot Plant (WIPP). The objective of the virtual document described in this paper is to give the public an overview of the waste characterization steps, an understanding of how waste characterization instrumentation works, and the type and amount of data generated from a batch of drums. The document is intended to be published on a web page and/or distributed at public meetings on CDs. Users may gain as much information as they desire regarding the transuranic (TRU) waste characterization program,more » starting at the highest level requirements (drivers) and progressing to more and more detail regarding how the requirements are met. Included are links to: drivers (which include laws, permits and DOE Orders); various characterization steps required for transportation and disposal under WIPP's Hazardous Waste Facility Permit; physical/chemical basis for each characterization method; types of data produced; and quality assurance process that accompanies each measurement. Examples of each type of characterization method in use across the DOE complex are included. The original skeleton of the document was constructed in a PowerPoint presentation and included descriptions of each section of the waste characterization program. This original document had a brief overview of Acceptable Knowledge, Non-Destructive Examination, Non-Destructive Assay, Small Quantity sites, and the National Certification Team. A student intern was assigned the project of converting the document to a virtual format and to discuss each subject in depth. The resulting product is a fully functional virtual document that works in a web browser and functions like a web page. All documents that were referenced, linked to, or associated, are included on the virtual document's CD. WIPP has been engaged in a variety of Hazardous Waste Facility Permit modification activities. During the public meetings, discussion centered on proposed changes to the characterization program. The philosophy behind the virtual document is to show the characterization process as a whole, rather than as isolated parts. In addition to public meetings, other uses for the information might be as a training tool for new employees at the WIPP facility to show them where their activities fit into the overall scheme, as well as an employee review to help prepare for waste certification audits.« less

  2. NEVADA TEST SITE WASTE ACCEPTANCE CRITERIA, JUNE 2006

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    U.S. DEPARTMENT OF ENERGY, NATIONAL NUCLEAR SECURITY ADMINISTRATION NEVADA SITE OFFICE

    This document establishes the U.S. Department of Energy (DOE), National Nuclear Security Administration Nevada Site Office (NNSA/NSO) waste acceptance criteria (WAC). The WAC provides the requirements, terms, and conditions under which the Nevada Test Site (NTS) will accept low-level radioactive (LLW) and mixed waste (MW) for disposal. It includes requirements for the generator waste certification program, characterization, traceability, waste form, packaging, and transfer. The criteria apply to radioactive waste received at the NTS Area 3 and Area 5 Radioactive Waste Management Complex (RWMC) for storage or disposal.

  3. Nevada Test Site Waste Acceptance Criteria

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    U. S. Department of Energy, National Nuclear Security Administration Nevada Site Office

    This document establishes the U.S. Department of Energy (DOE), National Nuclear Security Administration Nevada Site Office (NNSA/NSO) waste acceptance criteria (WAC). The WAC provides the requirements, terms, and conditions under which the Nevada Test Site (NTS) will accept low-level radioactive (LLW) and mixed waste (MW) for disposal. It includes requirements for the generator waste certification program, characterization, traceability, waste form, packaging, and transfer. The criteria apply to radioactive waste received at the NTS Area 3 and Area 5 Radioactive Waste Management Complex (RWMC) for storage or disposal.

  4. Waste certification program plan for Oak Ridge National Laboratory. Revision 2

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Not Available

    1997-09-01

    This document defines the waste certification program (WCP) developed for implementation at Oak Ridge National Laboratory (ORNL). The document describes the program structure, logic, and methodology for certification of ORNL wastes. The purpose of the WCP is to provide assurance that wastes are properly characterized and that the Waste Acceptance Criteria (WAC) for receiving facilities are met. The program meets the waste certification requirements for mixed (both radioactive and hazardous) and hazardous [including polychlorinated biphenyls (PCB)] waste. Program activities will be conducted according to ORNL Level 1 document requirements.

  5. NEVADA TEST SITE WASTE ACCEPTANCE CRITERIA

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    U.S. DEPARTMENT OF ENERGY, NATIONAL NUCLEAR SECURITY ADMINISTRATION, NEVADA SITE OFFICE

    This document establishes the U. S. Department of Energy, National Nuclear Security Administration Nevada Site Office (NNSA/NSO) waste acceptance criteria (WAC). The WAC provides the requirements, terms, and conditions under which the Nevada Test Site will accept low-level radioactive and mixed waste for disposal. Mixed waste generated within the State of Nevada by NNSA/NSO activities is accepted for disposal. It includes requirements for the generator waste certification program, characterization, traceability, waste form, packaging, and transfer. The criteria apply to radioactive waste received at the Nevada Test Site Area 3 and Area 5 Radioactive Waste Management Site for storage or disposal.

  6. Waste Generation Overview Refresher, Course 21464

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Simpson, Lewis Edward

    This course, Waste Generation Overview Refresher (COURSE 21464), provides an overview of federal and state waste management regulations, as well as Los Alamos National Laboratory (LANL) policies and procedures for waste management operations. The course covers the activities involved in the cradle-to- grave waste management process and focuses on waste characterization, waste compatibility determinations and classification, and the storage requirements for temporary waste accumulation areas at LANL.

  7. 10 CFR 60.16 - Site characterization plan required.

    Code of Federal Regulations, 2010 CFR

    2010-01-01

    ... 10 Energy 2 2010-01-01 2010-01-01 false Site characterization plan required. 60.16 Section 60.16 Energy NUCLEAR REGULATORY COMMISSION (CONTINUED) DISPOSAL OF HIGH-LEVEL RADIOACTIVE WASTES IN GEOLOGIC REPOSITORIES Licenses Preapplication Review § 60.16 Site characterization plan required. Before proceeding to...

  8. 10 CFR 60.17 - Contents of site characterization plan.

    Code of Federal Regulations, 2012 CFR

    2012-01-01

    ... assurance to data collection, recording, and retention. (3) Plans for the decontamination and... rule or order, requires. (b) A description of the possible waste form or waste package for the high... practicable) of the relationship between such waste form or waste package and the host rock at such area, and...

  9. 10 CFR 60.17 - Contents of site characterization plan.

    Code of Federal Regulations, 2013 CFR

    2013-01-01

    ... assurance to data collection, recording, and retention. (3) Plans for the decontamination and... rule or order, requires. (b) A description of the possible waste form or waste package for the high... practicable) of the relationship between such waste form or waste package and the host rock at such area, and...

  10. 10 CFR 60.17 - Contents of site characterization plan.

    Code of Federal Regulations, 2014 CFR

    2014-01-01

    ... assurance to data collection, recording, and retention. (3) Plans for the decontamination and... rule or order, requires. (b) A description of the possible waste form or waste package for the high... practicable) of the relationship between such waste form or waste package and the host rock at such area, and...

  11. 10 CFR 60.17 - Contents of site characterization plan.

    Code of Federal Regulations, 2011 CFR

    2011-01-01

    ... assurance to data collection, recording, and retention. (3) Plans for the decontamination and... rule or order, requires. (b) A description of the possible waste form or waste package for the high... practicable) of the relationship between such waste form or waste package and the host rock at such area, and...

  12. Waste Sampling & Characterization Facility (WSCF) Complex Safety Analysis

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    MELOY, R.T.

    2002-04-01

    This document was prepared to analyze the Waste Sampling and Characterization Facility for safety consequences by: Determining radionuclide and highly hazardous chemical inventories; Comparing these inventories to the appropriate regulatory limits; Documenting the compliance status with respect to these limits; and Identifying the administrative controls necessary to maintain this status. The primary purpose of the Waste Sampling and Characterization Facility (WSCF) is to perform low-level radiological and chemical analyses on various types of samples taken from the Hanford Site. These analyses will support the fulfillment of federal, Washington State, and Department of Energy requirements.

  13. 10 CFR 60.7 - License not required for certain preliminary activities.

    Code of Federal Regulations, 2010 CFR

    2010-01-01

    ... WASTES IN GEOLOGIC REPOSITORIES General Provisions § 60.7 License not required for certain preliminary... repository: (a) For purposes of site characterization; or (b) For use, during site characterization or...

  14. Wastes as Aggregates, Binders or Additions in Mortars: Selecting Their Role Based on Characterization.

    PubMed

    Farinha, Catarina Brazão; de Brito, Jorge; Veiga, Rosário; Fernández, J M; Jiménez, J R; Esquinas, A R

    2018-03-20

    The production of waste has increased over the years and, lacking a recycle or recovery solution, it is forwarded to landfill. The incorporation of wastes in cement-based materials is a solution to reduce waste deposition. In this regard, some researchers have been studying the incorporation of wastes with different functions: aggregate, binder and addition. The incorporation of wastes should take advantage of their characteristics. It requires a judicious analysis of their particles. This research involves the analysis of seven industrial wastes: biomass ashes, glass fibre, reinforced polymer dust, sanitary ware, fluid catalytic cracking, acrylic fibre, textile fibre and glass fibre. The main characteristics and advantages of each waste are enunciated and the best type of introduction in mortars is discussed. The characterization of the wastes as particles is necessary to identify the most suitable incorporation in mortars. In this research, some wastes are studied with a view to their re-use or recycling in mortars. Thus, this research focuses on the chemical, physical and mechanical characterization of industrial wastes and identification of the potentially most advantageous type of incorporation.

  15. Wastes as Aggregates, Binders or Additions in Mortars: Selecting Their Role Based on Characterization

    PubMed Central

    de Brito, Jorge; Veiga, Rosário

    2018-01-01

    The production of waste has increased over the years and, lacking a recycle or recovery solution, it is forwarded to landfill. The incorporation of wastes in cement-based materials is a solution to reduce waste deposition. In this regard, some researchers have been studying the incorporation of wastes with different functions: aggregate, binder and addition. The incorporation of wastes should take advantage of their characteristics. It requires a judicious analysis of their particles. This research involves the analysis of seven industrial wastes: biomass ashes, glass fibre, reinforced polymer dust, sanitary ware, fluid catalytic cracking, acrylic fibre, textile fibre and glass fibre. The main characteristics and advantages of each waste are enunciated and the best type of introduction in mortars is discussed. The characterization of the wastes as particles is necessary to identify the most suitable incorporation in mortars. In this research, some wastes are studied with a view to their re-use or recycling in mortars. Thus, this research focuses on the chemical, physical and mechanical characterization of industrial wastes and identification of the potentially most advantageous type of incorporation. PMID:29558418

  16. Requirements Development Issues for Advanced Life Support Systems: Solid Waste Management

    NASA Technical Reports Server (NTRS)

    Levri, Julie A.; Fisher, John W.; Alazraki, Michael P.; Hogan, John A.

    2002-01-01

    Long duration missions pose substantial new challenges for solid waste management in Advanced Life Support (ALS) systems. These possibly include storing large volumes of waste material in a safe manner, rendering wastes stable or sterilized for extended periods of time, and/or processing wastes for recovery of vital resources. This is further complicated because future missions remain ill-defined with respect to waste stream quantity, composition and generation schedule. Without definitive knowledge of this information, development of requirements is hampered. Additionally, even if waste streams were well characterized, other operational and processing needs require clarification (e.g. resource recovery requirements, planetary protection constraints). Therefore, the development of solid waste management (SWM) subsystem requirements for long duration space missions is an inherently uncertain, complex and iterative process. The intent of this paper is to address some of the difficulties in writing requirements for missions that are not completely defined. This paper discusses an approach and motivation for ALS SWM requirements development, the characteristics of effective requirements, and the presence of those characteristics in requirements that are developed for uncertain missions. Associated drivers for life support system technological capability are also presented. A general means of requirements forecasting is discussed, including successive modification of requirements and the need to consider requirements integration among subsystems.

  17. Environmental characterization report for the Gulf Interior Region, Texas study area. [Oakwood, Palestine and Keechi salt domes

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Not Available

    1982-10-01

    This report is published as a product of the National Waste Terminal Storage (NWTS) Program. The objective of this program is the development of terminal waste storage facilities in deep, stable geologic formations for high-level nuclear waste, including spent fuel elements from commercial power reactors and transuranic nuclear waste for which the federal government is responsible. The report is part of the area study phase and contains environmental information for the Texas Study Area of the Gulf Interior Region acquired from federal, state, and regional agencies. The data in this report meet the requirements of predetermined survey plans and willmore » be used in determining locations of approximately 80 square kilometers (30 square miles) that will be further characterized. Information on surface water, atmosphere, background radiation, natural ecosystems, agricultural systems, demography, socioeconomics, land use, and transportation is presented. The environmental characterization will ensure that data on environmental values required by the National Environmental Policy Act (NEPA) of 1969 are available.« less

  18. Final Inventory Work-Off Plan for ORNL transuranic wastes (1986 version)

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Dickerson, L.S.

    1988-05-01

    The Final Inventory Work-Off Plan (IWOP) for ORNL Transuranic Wastes addresses ORNL's strategy for retrieval, certification, and shipment of its stored and newly generated contact-handled (CH) and remote-handled (RH) transuranic (TRU) wastes to the Waste Isolation Pilot Plant (WIPP), the proposed geologic repository near Carlsbad, New Mexico. This document considers certification compliance with the WIPP waste acceptance criteria (WAC) and is consistent with the US Department of Energy's Long-Range Master Plan for Defense Transuranic Waste Management. This document characterizes Oak Ridge National Laboratory's (ORNL's) TRU waste by type and estimates the number of shipments required to dispose of it; describesmore » the methods, facilities, and systems required for its certification and shipment; presents work-off strategies and schedules for retrieval, certification, and transportation; discusses the resource needs and additions that will be required for the effort and forecasts costs for the long-term TRU waste management program; and lists public documentation required to support certification facilities and strategies. 22 refs., 6 figs., 10 tabs.« less

  19. Cf-252 Characterization Documents

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Feldman, Alexander

    2014-03-14

    Six documents were written by Vance and Associates under contract to the Off-Site Source Recovery Project of Los Alamos National Laboratory. These Six documents provided the basis for characterization of Californium-252 sealed sources and for the packaging and manifesting of this material for disposal at the Waste Isolation Pilot Project. The Six documents are: 1. VA-OSR-10, Development of radionuclide distributions for Cf-252 sealed sources. 2. VA-OSR-11, Uncertainty analysis for Cf-252 sealed sources. 3. VA-OSR-12, To determine the radionuclides in the waste drums containing Cf-252 sealed source waste that are required to be reported under the requirements of the WIPP WACmore » and the TRAMPAC. 4. VA-OSR-13, Development of the spreadsheet for the radiological calculations for the characterization of Cf-252 sources. 5. VA-OSR-14, Relative importance of neutron-induced fission in Cf-252 sources. 6. VA-OSR-15, Determine upper bound of decay product inventories from a drum of Cf-252 sources. These six documents provide the technical basis for the characterization of Cf-252 sources and will be part of the AK documentation required for submittal to the Central Characterization Project (CCP) of WIPP.« less

  20. Compatibility Grab Sampling and Analysis Plan for FY 2000

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    SASAKI, L.M.

    1999-12-29

    This sampling and analysis plan (SAP) identifies characterization objectives pertaining to sample collection, laboratory analytical evaluation, and reporting requirements for grab samples obtained to address waste compatibility. It is written in accordance with requirements identified in Data Quality Objectives for Tank Farms Waste Compatibility Program (Mulkey et al. 1999) and Tank Farm Waste Transfer Compatibility Program (Fowler 1999). In addition to analyses to support Compatibility, the Waste Feed Delivery program has requested that tank samples obtained for Compatibility also be analyzed to confirm the high-level waste and/or low-activity waste envelope(s) for the tank waste (Baldwin 1999). The analytical requirements tomore » confirm waste envelopes are identified in Data Quality Objectives for TWRS Privatization Phase I: Confirm Tank T is an Appropriate Feed Source for Low-Activity Waste Feed Batch X (Nguyen 1999a) and Data Quality Objectives for RPP Privatization Phase I: Confirm Tank T is an Appropriate Feed Source for High-Level Waste Feed Batch X (Nguyen 1999b).« less

  1. Final Report. LAW Glass Formulation to Support AP-101 Actual Waste Testing, VSL-03R3470-2, Rev. 0

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Muller, I. S.; Pegg, I. L.; Rielley, Elizabeth

    2015-06-22

    The main objective of the work was to develop and select a glass formulation for vitrification testing of the actual waste sample of LAW AP-101 at Battelle - Pacific Northwest Division (PNWD). Other objectives of the work included preparation and characterization of glasses to demonstrate compliance with contract and processing requirements, evaluation of the ability to achieve waste loading requirements, testing to demonstrate compatibility of the glass melts with melter materials of construction, comparison of the properties of simulant and actual waste glasses, and identification of glass formulation issues with respect to contract specifications and processing requirements.

  2. Reanalysis of Plutonium and Americium-241 in the Tank 19F Closure Grab and Core Samples

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Swingle, R.F.

    2003-02-11

    Tank 19F is scheduled to be closed by March 2004. To close this tank, a characterization of the waste remaining in the tank was required to confirm the inventory of various species for input into groundwater transport models. This characterization has been developed by a combination of process knowledge, visual observation and sample analysis. The characterization samples were obtained by High Level Waste Division (HLWD) personnel and characterized by SRTC personnel.

  3. 1999 Report on Hanford Site land disposal restriction for mixed waste

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    BLACK, D.G.

    This report was submitted to meet the requirements of Hanford Federal Facility Agreement and Consent Order (Tri-Party Agreement) Milestone M-26-011. This milestone requires the preparation of an annual report that covers characterization, treatment, storage, minimization, and other aspects of managing land-disposal-restricted mixed waste at the Hanford Facility.

  4. Challenges to diagnosis of HIV-associated wasting.

    PubMed

    Kotler, Donald

    2004-12-01

    There is a wide variability in the clinical presentation of the protein energy malnutrition often characterized as wasting in patients infected with HIV. Moreover, the clinical presentation has evolved over time. Initially, protein energy malnutrition was characterized by profound weight loss and depletion of body cell mass (BCM). Recently, unrelated concurrent metabolic abnormalities, such as lipodystrophy, may complicate the diagnosis of HIV wasting. Although measures of BCM are relatively accurate for the diagnosis of HIV wasting, the optimal tools for assessing BCM are not necessarily available to the clinician. From the practical standpoint, HIV wasting may be a self-evident diagnosis in advanced stages, but effective interpretation of the early signs of HIV wasting requires familiarity with other complications included in the differential diagnosis.

  5. Tank characterization report for double-shell tank 241-AW-105

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Sasaki, L.M.

    1997-06-05

    One of the major functions of the Tank Waste Remediation System (TWRS) is to characterize wastes in support of waste management and disposal activities at the Hanford Site. Analytical data from sampling and analysis, along with other available information about a tank, are compiled and maintained in a tank characterization report (TCR). This report and its appendices serve as the TCR for double-shell tank 241-AW-105. The objectives of this report are to use characterization data in response to technical issues associated with tank 241-AW-105 waste; and to provide a standard characterization of this waste in terms of a best-basis inventorymore » estimate. The response to technical issues is summarized in Section 2.0, and the best-basis inventory estimate is presented in Section 3.0. Recommendations regarding safety status and additional sampling needs are provided in Section 4.0. Supporting data and information are contained in the appendices. This report supports the requirements of the Hanford Federal Facility Agreement and Consent Order milestone Characterization. information presented in this report originated from sample analyses and known historical sources. While only the results of a recent sampling event will be used to fulfill the requirements of the data quality objectives (DQOs), other information can be used to support or question conclusions derived from these results. Historical information for tank 241-AW-105 is provided in Appendix A, including surveillance information, records pertaining to waste transfers and tank operations, and expected tank contents derived from a process knowledge model. The recent sampling event listed, as well as pertinent sample data obtained before 1996, are summarized in Appendix B along with the sampling results. The results of the 1996 grab sampling event satisfied the data requirements specified in the sampling and analysis plan (SAP) for this tank. In addition, the tank headspace flammability was measured, which addresses one of the requirements specified in the safety screening DQO. The statistical analysis and numerical manipulation of data used in issue resolution are reported in Appendix C. Appendix D contains the evaluation to establish the best basis for the inventory estimate and the statistical analysis performed for this evaluation. A bibliography that resulted from an in-depth literature search of all known information sources applicable to tank 241-AW-105 and its respective waste types is contained in Appendix E. A majority of the documents listed in Appendix E may be found in the Tank Characterization and Safety Resource Center.« less

  6. WIPP Remote-Handled TRU Waste Program Update

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Most, W.; Kehrman, B.

    2006-07-01

    There are two major regulatory approval milestones necessary in order to commence disposal operations for remote-handled transuranic (RH TRU) waste at the Waste Isolation Pilot Plant (WIPP)-the RH TRU hazardous waste permit modification request [1] and the radiological characterization plan [2]. One of those milestones has been achieved. The US Environmental Protection Agency (EPA) issued its final decision to approve the Department of Energy's (DOE) RH TRU radiological characterization plan along with the RH TRU Waste Characterization Program Implementation Plan [3], on March 26, 2004. The RH TRU hazardous waste permit modification request still awaits agency approval. In EPA's decisionmore » to approve the DOE's RH TRU radiological characterization plan, the EPA also set forth the process for approving site-specific RH TRU waste characterization programs. Included in the March 29, 2005, RH TRU second Notice of Deficiency [4] (NOD) on the Class 3 Permit Modification Request for RH TRU Waste, the New Mexico Environment Department (NMED) requested that the Permittees combine their responses for the RH TRU Waste NOD with the Section 311 permit modification request NOD. The Combined Response Document was submitted April 28, 2005 [5]. Another NOD [6] was issued by the NMED on September 1, 2005, to clarify the Permittees' proposal and submit these clarifications to the administrative record. Combining both the chap. 311 [7] and RH TRU waste permit modification requests allows for both the regulator and Permittees to expedite action on the modification requests. The Combined Response Document preserves human resources and costs by having only one administrative process for both modification requests. Facility readiness requirements of the RH TRU waste final permit [8] must be implemented to declare that the WIPP is ready to receive RH TRU waste for storage and disposal. To demonstrate readiness, the WIPP is preparing for an Operational Readiness Review (ORR) of the RH TRU waste management equipment, system, and procedures. Required by DOE Order, the ORR demonstrates the capability of managing RH TRU waste. The Management and Operating Contractor (MOC) for the WIPP must first perform a Line Management Assessment. Upon successful completion of the Line Management Assessment, the MOC performs the Contractor ORR and presents the results to the local DOE office. At that time, the local DOE office performs its own ORR to declare readiness to DOE Headquarters. (authors)« less

  7. Greater-than-Class C low-level radioactive waste characterization: Estimated volumes, radionuclide activities, and other characteristics

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Hulse, R.A.

    1991-08-01

    Planning for storage or disposal of greater-than-Class C low-level radioactive waste (GTCC LLW) requires characterization of that waste to estimate volumes, radionuclide activities, and waste forms. Data from existing literature, disposal records, and original research were used to estimate the characteristics and project volumes and radionuclide activities to the year 2035. GTCC LLW is categorized as: nuclear utilities waste, sealed sources waste, DOE-held potential GTCC LLW; and, other generator waste. It has been determined that the largest volume of those wastes, approximately 57%, is generated by nuclear power plants. The Other Generator waste category contributes approximately 10% of the totalmore » GTCC LLW volume projected to the year 2035. Waste held by the Department of Energy, which is potential GTCC LLW, accounts for nearly 33% of all waste projected to the year 2035; however, no disposal determination has been made for that waste. Sealed sources are less than 0.2% of the total projected volume of GTCC LLW.« less

  8. Tank characterization report for single-shell tank 241-S-111

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Conner, J.M.

    1997-04-28

    One of the major functions of the Tank Waste Remediation System (TWRS) is to characterize wastes in support of waste management and disposal activities at the Hanford Site. Analytical data from sampling and analysis, along with other available information about a tank, are compiled and maintained in a tank characterization report (TCR). This report and its appendices serve as the TCR for single-shell tank 241-S-111. The objectives of this report are: (1) to use characterization data to address technical issues associated with tank 241-S-111 waste; and (2) to provide a standard characterization of this waste in terms of a best-basismore » inventory estimate. The response to technical issues is summarized in Section 2.0, and the best-basis inventory estimate is presented in Section 3.0. Recommendations regarding safety status and additional sampling needs are provided in Section 4.0. Supporting data and information are contained in the appendices. This report also supports the requirements of Hanford Federal Facility Agreement and Consent Order (Ecology et al. 1996) milestone M-44-10.« less

  9. Acceptable knowledge document for INEEL stored transuranic waste -- Rocky Flats Plant waste. Revision 2

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    NONE

    1998-01-23

    This document and supporting documentation provide a consistent, defensible, and auditable record of acceptable knowledge for waste generated at the Rocky Flats Plant which is currently in the accessible storage inventory at the Idaho National Engineering and Environmental Laboratory. The inventory consists of transuranic (TRU) waste generated from 1972 through 1989. Regulations authorize waste generators and treatment, storage, and disposal facilities to use acceptable knowledge in appropriate circumstances to make hazardous waste determinations. Acceptable knowledge includes information relating to plant history, process operations, and waste management, in addition to waste-specific data generated prior to the effective date of the RCRAmore » regulations. This document is organized to provide the reader a comprehensive presentation of the TRU waste inventory ranging from descriptions of the historical plant operations that generated and managed the waste to specific information about the composition of each waste group. Section 2 lists the requirements that dictate and direct TRU waste characterization and authorize the use of the acceptable knowledge approach. In addition to defining the TRU waste inventory, Section 3 summarizes the historical operations, waste management, characterization, and certification activities associated with the inventory. Sections 5.0 through 26.0 describe the waste groups in the inventory including waste generation, waste packaging, and waste characterization. This document includes an expanded discussion for each waste group of potential radionuclide contaminants, in addition to other physical properties and interferences that could potentially impact radioassay systems.« less

  10. DOE Office of Scientific and Technical Information (OSTI.GOV)

    Singledecker, Steven John

    The purpose of this document is to describe the waste stream from Z-Pinch Residual Waste Project that due to worker safety concerns and operational efficiency is a candidate for blending Transuranic and low level waste together and can be safely packaged as low-level waste consistent with DOE Order 435.1 requirements and NRC guidance 10 CFR 61.42. This waste stream consists of the Pu-ICE post-shot containment systems, including plutonium targets, generated from the Z Machine experiments requested by LANL and conducted by SNL/NM. In the past, this TRU waste was shipped back to LANL after Sandia sends the TRU data packagemore » to LANL to certify the characterization (by CCP), transport and disposition at WIPP (CBFO) per LANL MOU-0066. The Low Level Waste is managed, characterized, shipped and disposed of at NNSS by SNL/NM per Sandia MOU # 11-S-560.« less

  11. Active and passive computed tomography mixed waste focus area final report

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Roberson, G P

    1998-08-19

    The Mixed Waste Focus Area (MWFA) Characterization Development Strategy delineates an approach to resolve technology deficiencies associated with the characterization of mixed wastes. The intent of this strategy is to ensure the availability of technologies to support the Department of Energy's (DOE) mixed waste low-level or transuranic (TRU) contaminated waste characterization management needs. To this end the MWFA has defined and coordinated characterization development programs to ensure that data and test results necessary to evaluate the utility of non-destructive assay technologies are available to meet site contact handled waste management schedules. Requirements used as technology development project benchmarks are basedmore » in the National TRU Program Quality Assurance Program Plan. These requirements include the ability to determine total bias and total measurement uncertainty. These parameters must be completely evaluated for waste types to be processed through a given nondestructive waste assay system constituting the foundation of activities undertaken in technology development projects. Once development and testing activities have been completed, Innovative Technology Summary Reports are generated to provide results and conclusions to support EM-30, -40, or -60 end user/customer technology selection. The Active and Passive Computed Tomography non-destructive assay system is one of the technologies selected for development by the MWFA. Lawrence Livermore National Laboratory's (LLNL) is developing the Active and Passive Computed Tomography (A&PCT) nondestructive assay (NDA) technology to identify and accurately quantify all detectable radioisotopes in closed containers of waste. This technology will be applicable to all types of waste regardless of .their classification; low level, transuranic or provide results and conclusions to support EM-30, -40, or -60 end user/customer technology selection. The Active and Passive Computed Tomography non-destructive assay system is one of the technologies selected for development by the MWFA. Lawrence Livermore National Laboratory's (LLNL) is developing the Active and Passive Computed Tomography (A&PCT) nondestructive assay (NDA) technology to identify and accurately quantify all detectable radioisotopes in closed containers of waste. This technology will be applicable to all types of waste regardless of .their classification; low level, transuranic or mixed, which contains radioactivity and hazardous organic species. The scope of our technology is to develop a non-invasive waste-drum scanner that employs the principles of computed tomography and gamma-ray spectral analysis to identify and quantify all of the detectable radioisotopes. Once this and other applicable technologies are developed, waste drums can be non- destructively and accurately characterized to satisfy repository and regulatory guidelines prior to disposal.« less

  12. Buried transuranic wastes at ORNL: Review of past estimates and reconciliation with current data

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Trabalka, J.R.

    1997-09-01

    Inventories of buried (generally meaning disposed of) transuranic (TRU) wastes at Oak Ridge National Laboratory (ORNL) have been estimated for site remediation and waste management planning over a period of about two decades. Estimates were required because of inadequate waste characterization and incomplete disposal records. For a variety of reasons, including changing definitions of TRU wastes, differing objectives for the estimates, and poor historical data, the published results have sometimes been in conflict. The purpose of this review was (1) to attempt to explain both the rationale for and differences among the various estimates, and (2) to update the estimatesmore » based on more recent information obtained from waste characterization and from evaluations of ORNL waste data bases and historical records. The latter included information obtained from an expert panel`s review and reconciliation of inconsistencies in data identified during preparation of the ORNL input for the third revision of the Baseline Inventory Report for the Waste Isolation Pilot Plant. The results summarize current understanding of the relationship between past estimates of buried TRU wastes and provide the most up-to-date information on recorded burials thereafter. The limitations of available information on the latter and thus the need for improved waste characterization are highlighted.« less

  13. Waste Characterization Process

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Lambert, Patrick E.

    2014-11-01

    The purpose is to provide guidance to the Radiological Characterization Reviewer to complete the radiological characterization of waste items. This information is used for Department of Transportation (DOT) shipping and disposal, typically at the Nevada National Security Site (NNSS). Complete characterization ensures compliance with DOT shipping laws and NNSS Waste Acceptance Criteria (WAC). The fines for noncompliance can be extreme. This does not include possible bad press, and endangerment to the public, employees and the environment. A Radiological Characterization Reviewer has an important role in the organization. The scope is to outline the characterization process, but does not to includemore » every possible situation. The Radiological Characterization Reviewer position requires a strong background in Health Physics; therefore, these concepts are minimally addressed. The characterization process includes many Excel spreadsheets that were developed by Michael Enghauser known as the WCT software suite. New Excel spreadsheets developed as part of this project include the Ra- 226 Decider and the Density Calculator by Jesse Bland, MicroShield Density Calculator and Molecular Weight Calculator by Pat Lambert.« less

  14. DOE Office of Scientific and Technical Information (OSTI.GOV)

    Carlsbad Field Office

    The Performance Demonstration Program (PDP) for headspace gases distributes blind audit samples in a gas matrix for analysis of volatile organic compounds (VOCs). Participating measurement facilities (i.e., fixed laboratories, mobile analysis systems, and on-line analytical systems) are located across the United States. Each sample distribution is termed a PDP cycle. These evaluation cycles provide an objective measure of the reliability of measurements performed for transuranic (TRU) waste characterization. The primary documents governing the conduct of the PDP are the Quality Assurance Program Document (QAPD) (DOE/CBFO-94-1012) and the Waste Isolation Pilot Plant (WIPP) Waste Analysis Plan (WAP) contained in the Hazardousmore » Waste Facility Permit (NM4890139088-TSDF) issued by the New Mexico Environment Department (NMED). The WAP requires participation in the PDP; the PDP must comply with the QAPD and the WAP. This plan implements the general requirements of the QAPD and the applicable requirements of the WAP for the Headspace Gas (HSG) PDP. Participating measurement facilities analyze blind audit samples of simulated TRU waste package headspace gases according to the criteria set by this PDP Plan. Blind audit samples (hereafter referred to as PDP samples) are used as an independent means to assess each measurement facility’s compliance with the WAP quality assurance objectives (QAOs). To the extent possible, the concentrations of VOC analytes in the PDP samples encompass the range of concentrations anticipated in actual TRU waste package headspace gas samples. Analyses of headspace gases are required by the WIPP to demonstrate compliance with regulatory requirements. These analyses must be performed by measurement facilities that have demonstrated acceptable performance in this PDP. These analyses are referred to as WIPP analyses and the TRU waste package headspace gas samples on which they are performed are referred to as WIPP samples in this document. Participating measurement facilities must analyze PDP samples using the same procedures used for routine waste characterization analyses of WIPP samples.« less

  15. DOE Office of Scientific and Technical Information (OSTI.GOV)

    Carlsbad Field Office

    The Performance Demonstration Program (PDP) for headspace gases distributes sample gases of volatile organic compounds (VOCs) for analysis. Participating measurement facilities (i.e., fixed laboratories, mobile analysis systems, and on-line analytical systems) are located across the United States. Each sample distribution is termed a PDP cycle. These evaluation cycles provide an objective measure of the reliability of measurements performed for transuranic (TRU) waste characterization. The primary documents governing the conduct of the PDP are the Quality Assurance Program Document (QAPD) (DOE/CBFO-94-1012) and the Waste Isolation Pilot Plant (WIPP) Waste Analysis Plan (WAP) contained in the Hazardous Waste Facility Permit (NM4890139088-TSDF) issuedmore » by the New Mexico Environment Department (NMED). The WAP requires participation in the PDP; the PDP must comply with the QAPD and the WAP. This plan implements the general requirements of the QAPD and the applicable requirements of the WAP for the Headspace Gas (HSG) PDP. Participating measurement facilities analyze blind audit samples of simulated TRU waste package headspace gases according to the criteria set by this PDP Plan. Blind audit samples (hereafter referred to as PDP samples) are used as an independent means to assess each measurement facility’s compliance with the WAP quality assurance objectives (QAOs). To the extent possible, the concentrations of VOC analytes in the PDP samples encompass the range of concentrations anticipated in actual TRU waste package headspace gas samples. Analyses of headspace gases are required by the WIPP to demonstrate compliance with regulatory requirements. These analyses must be performed by measurement facilities that have demonstrated acceptable performance in this PDP. These analyses are referred to as WIPP analyses and the TRU waste package headspace gas samples on which they are performed are referred to as WIPP samples in this document. Participating measurement facilities must analyze PDP samples using the same procedures used for routine waste characterization analyses of WIPP samples.« less

  16. Characterization methodology for re-using marble slurry in industrial applications

    NASA Astrophysics Data System (ADS)

    Marras, Graziella; Careddu, Nicola; Peretti, Roberto; Bortolussi, Augusto

    2017-04-01

    In the effort towards waste minimization and circular economy, natural stone waste is one of the foremost parameter to turn scientific community attention. At this time, calcium carbonate has a great importance in industrial fields and currently there is the necessity of appreciate the potential value of marble waste and convert it into marketable products. A large amount of residues is produced in ornamental stone sector with different dimension and particle size. The research focused on marble slurry, recovered at the end of the treatment plant in the filter-press section. The aim of this paper is to propose a defined way to characterize marble slurry, primarily composed of micronized particles, in order to obtain useful data to make a comparison with market specifications. In particular the proposed characterization methodology follows the indicated steps: Leaching test (TCLP) - Grain size distribution and bulk density - Mineralogical analyses - X-Ray diffraction - Chemical analysis - Loss on ignition - SEM determination - Colorimetric and bright analysis. Marble slurry samples, collected by different dimension stone treatment plants in Orosei marble district (Sardinia - Italy), were analyzed by physical, mineralogical and chemical determinations and the obtained data were evaluated for compatibility with the CaCO3 specifications required by a definite industrial sector, seeing as how CaCO3 product specifications vary depending on the utilization. The importance of this investigation is to characterize completely the "waste" that must apply for further uses and to identify the feasibility to substitute marketable micronized CaCO3 with marble slurry. Further goal is to enhance the environmental advantages of re-using stone waste by reducing marble waste landfills and by applying raw material substitution, in accordance with regulatory requirements, thus pursuing the objective to convert natural stone waste into by-product with a renewed environmental and economic value. Consequently what until now was considered as a waste, can be an important economic resource capable of promoting the sustainability.

  17. Regulatory controls on the hydrogeological characterization of a mixed waste disposal site, Radioactive Waste Management Complex, Idaho National Engineering Laboratory

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Ruebelmann, K.L.

    1990-01-01

    Following the detection of chlorinated volatile organic compounds in the groundwater beneath the SDA in the summer of 1987, hydrogeological characterization of the Radioactive Waste Management Complex (RWMC), Idaho National Engineering Laboratory (INEL) was required by the Resource Conservation and Recovery Act (RCRA). The waste site, the Subsurface Disposal Area (SDA), is the subject of a RCRA Corrective Action Program. Regulatory requirements for the Corrective Action Program dictate a phased approach to evaluation of the SDA. In the first phase of the program, the SDA is the subject of a RCRA Facility Investigation (RIF), which will obtain information to fullymore » characterize the physical properties of the site, determine the nature and extent of contamination, and identify pathways for migration of contaminants. If the need for corrective measures is identified during the RIF, a Corrective Measures Study (CMS) will be performed as second phase. Information generated during the RIF will be used to aid in the selection and implementation of appropriate corrective measures to correct the release. Following the CMS, the final phase is the implementation of the selected corrective measures. 4 refs., 1 fig.« less

  18. 40 CFR 194.24 - Waste characterization.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... other information and methods. (b) The Department shall submit in the compliance certification... proposed for disposal in the disposal system, WIPP complies with the numeric requirements of § 194.34 and... release. (2) Identify and describe the method(s) used to quantify the limits of waste components...

  19. APNEA/WIT system nondestructive assay capability evaluation plan for select accessibly stored INEL RWMC waste forms

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Becker, G.K.

    1997-01-01

    Bio-Imaging Research Inc. (BIR) and Lockheed Martin Speciality Components (LMSC) are engaged in a Program Research and Development Agreement and a Rapid Commercialization Initiative with the Department of Energy, EM-50. The agreement required BIR and LMSC to develop a data interpretation method that merges nondestructive assay and nondestructive examination (NDA/NDE) data and information sufficient to establish compliance with applicable National TRU Program (Program) waste characterization requirements and associated quality assurance performance criteria. This effort required an objective demonstration of the BIR and LMSC waste characterization systems in their standalone and integrated configurations. The goal of the test plan is tomore » provide a mechanism from which evidence can be derived to substantiate nondestructive assay capability and utility statement for the BIT and LMSC systems. The plan must provide for the acquisition, compilation, and reporting of performance data thereby allowing external independent agencies a basis for an objective evaluation of the standalone BIR and LMSC measurement systems, WIT and APNEA respectively, as well as an expected performance resulting from appropriate integration of the two systems. The evaluation is to be structured such that a statement regarding select INEL RWMC waste forms can be made in terms of compliance with applicable Program requirements and criteria.« less

  20. OSSA Space Station waste inventory

    NASA Technical Reports Server (NTRS)

    Rasmussen, Daryl N.; Johnson, Catherine C.; Bosley, John J.; Curran, George L.; Mains, Richard

    1987-01-01

    NASA's Office of Space Science and Applications has compiled an inventory of the types and quantities of the wastes that will be generated by the Space Station's initial operational phase in 35 possible mission scenarios. The objective of this study was the definition of waste management requirements for both the Space Station and the Space Shuttles servicing it. All missions, when combined, will produce about 5350 kg of gaseous, liquid and solid wastes every 90 days. A characterization has been made of the wastes in terms of toxicity, corrosiveness, and biological activity.

  1. DOE Office of Scientific and Technical Information (OSTI.GOV)

    Goldston, W.

    On April 21, 2009, the Energy Facilities Contractors Group (EFCOG) Waste Management Working Group (WMWG) provided a recommendation to the Department of Energy's Environmental Management program (DOE-EM) concerning supplemental guidance on blending methodologies to use to classify waste forms to determine if the waste form meets the definition of Transuranic (TRU) Waste or can be classified as Low-Level Waste (LLW). The guidance provides specific examples and methods to allow DOE and its Contractors to properly classify waste forms while reducing the generation of TRU wastes. TRU wastes are much more expensive to characterize at the generator's facilities, ship, and thenmore » dispose at the Waste Isolation Pilot Plant (WIPP) than Low-Level Radioactive Waste's disposal. Also the reduction of handling and packaging of LLW is inherently less hazardous to the nuclear workforce. Therefore, it is important to perform the characterization properly, but in a manner that minimizes the generation of TRU wastes if at all possible. In fact, the generation of additional volumes of radioactive wastes under the ARRA programs, this recommendation should improve the cost effective implementation of DOE requirements while properly protecting human health and the environment. This paper will describe how the message of appropriate, less expensive, less hazardous blending of radioactive waste is the 'right' thing to do in many cases, but can be confused with inappropriate 'dilution' that is frowned upon by regulators and stakeholders in the public. A proposal will be made in this paper on how to communicate this very complex and confusing technical issue to regulatory bodies and interested stakeholders to gain understanding and approval of the concept. The results of application of the proposed communication method and attempt to change the regulatory requirements in this area will be discussed including efforts by DOE and the NRC on this very complex subject.« less

  2. Activation and characterization of waste coffee grounds as bio-sorbent

    NASA Astrophysics Data System (ADS)

    Mariana; Marwan; Mulana, F.; Yunardi; Ismail, T. A.; Hafdiansyah, M. F.

    2018-03-01

    As the city well known for its culture of coffee drinkers, modern and traditional coffee shops are found everywhere in Banda Aceh, Indonesia. High number of coffee shops in the city generates large quantities of spent coffee grounds as waste without any effort to convert them as other valuable products. In an attempt to reduce environmental problems caused by used coffee grounds, this research was conducted to utilize waste coffee grounds as an activated carbon bio-sorbent. The specific purpose of this research is to improve the performance of coffee grounds bio-sorbent through chemical and physical activation, and to characterize the produced bio-sorbent. Following physical activation by carbonization, a chemical activation was achieved by soaking the carbonized waste coffee grounds in HCl solvent and carbonization process. The activated bio-sorbent was characterized for its morphological properties using Scanning Electron Microscopy (SEM), its functional groups by Fourier Transform Infra-Red Spectrophotometer (FTIR), and its material characteristics using X-Ray Diffraction (XRD). Characterization of the activated carbon prepared from waste coffee grounds shows that it meets standard quality requirement in accordance with Indonesian National Standard, SNI 06-3730-1995. Activation process has modified the functional groups of the waste coffee grounds. Comparing to natural waste coffee grounds, the resulted bio-sorbent demonstrated a more porous surface morphology following activation process. Consequently, such bio-sorbent is a potential source to be used as an adsorbent for various applications.

  3. CHARACTERIZATION OF HAZARDOUS WASTE SITES, A METHODS MANUAL. VOLUME 2. AVAILABLE SAMPLING METHODS (SECOND EDITION)

    EPA Science Inventory

    Investigations at hazardous waste sites and sites of chemical spills often require on-site measurements and sampling activities to assess the type and extent of contamination. This document is a compilation of sampling methods and materials suitable to address most needs that ari...

  4. (Low-level radioactive waste management techniques)

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Van Hoesen, S.D.; Kennerly, J.M.; Williams, L.C.

    1988-08-08

    The US team consisting of representatives of Oak Ridge National Laboratory (ORNL), Savannah River plant (SRP), Idaho National Engineering Laboratory (INEL), and the Department of Energy, Oak Ridge Operations participated in a training program on French low-level radioactive waste (LLW) management techniques. Training in the rigorous waste characterization, acceptance and certification procedures required in France was provided at Agence Nationale pour les Gestion des Dechets Radioactif (ANDRA) offices in Paris.

  5. Characterization, monitoring, and sensor technology crosscutting program: Technology summary

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    NONE

    1995-06-01

    The purpose of the Characterization, Monitoring, and Sensor Technology Crosscutting Program (CMST-CP) is to deliver appropriate characterization, monitoring, and sensor technology (CMST) to the Office of Waste Management (EM-30), the Office of Environmental Restoration (EM-40), and the Office of Facility Transition and Management (EM-60). The technology development must also be cost effective and appropriate to EM-30/40/60 needs. Furthermore, the required technologies must be delivered and implemented when needed. Accordingly, and to ensure that available DOE and other national resources are focused an the most pressing needs, management of the technology development is concentrated on the following Focus Areas: Contaminant Plumemore » Containment and Remediation (PFA); Landfill Stabilization (LSFA); High-Level Waste Tank Remediation (TFA); Mixed Waste Characterization, Treatment, and Disposal (MWFA); and Facility Deactivation, Decommissioning, and Material Disposition (FDDMDFA). Brief descriptions of CMST-CP projects funded in FY95 are presented.« less

  6. Deep Borehole Field Test Requirements and Controlled Assumptions.

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Hardin, Ernest

    2015-07-01

    This document presents design requirements and controlled assumptions intended for use in the engineering development and testing of: 1) prototype packages for radioactive waste disposal in deep boreholes; 2) a waste package surface handling system; and 3) a subsurface system for emplacing and retrieving packages in deep boreholes. Engineering development and testing is being performed as part of the Deep Borehole Field Test (DBFT; SNL 2014a). This document presents parallel sets of requirements for a waste disposal system and for the DBFT, showing the close relationship. In addition to design, it will also inform planning for drilling, construction, and scientificmore » characterization activities for the DBFT. The information presented here follows typical preparations for engineering design. It includes functional and operating requirements for handling and emplacement/retrieval equipment, waste package design and emplacement requirements, borehole construction requirements, sealing requirements, and performance criteria. Assumptions are included where they could impact engineering design. Design solutions are avoided in the requirements discussion. Deep Borehole Field Test Requirements and Controlled Assumptions July 21, 2015 iv ACKNOWLEDGEMENTS This set of requirements and assumptions has benefited greatly from reviews by Gordon Appel, Geoff Freeze, Kris Kuhlman, Bob MacKinnon, Steve Pye, David Sassani, Dave Sevougian, and Jiann Su.« less

  7. Greater-than-Class C low-level radioactive waste characterization: Estimated volumes, radionuclide activities, and other characteristics. Revision 1

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Not Available

    1994-09-01

    The Department of Energy`s (DOE`s) planning for the disposal of greater-than-Class C low-level radioactive waste (GTCC LLW) requires characterization of the waste. This report estimates volumes, radionuclide activities, and waste forms of GTCC LLW to the year 2035. It groups the waste into four categories, representative of the type of generator or holder of the waste: Nuclear Utilities, Sealed Sources, DOE-Held, and Other Generator. GTCC LLW includes activated metals (activation hardware from reactor operation and decommissioning), process wastes (i.e., resins, filters, etc.), sealed sources, and other wastes routinely generated by users of radioactive material. Estimates reflect the possible effect thatmore » packaging and concentration averaging may have on the total volume of GTCC LLW. Possible GTCC mixed LLW is also addressed. Nuclear utilities will probably generate the largest future volume of GTCC LLW with 65--83% of the total volume. The other generators will generate 17--23% of the waste volume, while GTCC sealed sources are expected to contribute 1--12%. A legal review of DOE`s obligations indicates that the current DOE-Held wastes described in this report will not require management as GTCC LLW because of the contractual circumstances under which they were accepted for storage. This report concludes that the volume of GTCC LLW should not pose a significant management problem from a scientific or technical standpoint. The projected volume is small enough to indicate that a dedicated GTCC LLW disposal facility may not be justified. Instead, co-disposal with other waste types is being considered as an option.« less

  8. Glass Waste Forms for Oak Ridge Tank Wastes: Fiscal Year 1998 Report for Task Plan SR-16WT-31, Task B

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Andrews, M.K.

    1999-05-10

    Using ORNL information on the characterization of the tank waste sludges, SRTC performed extensive bench-scale vitrification studies using simulants. Several glass systems were tested to ensure the optimum glass composition (based on the glass liquidus temperature, viscosity and durability) is determined. This optimum composition will balance waste loading, melt temperature, waste form performance and disposal requirements. By optimizing the glass composition, a cost savings can be realized during vitrification of the waste. The preferred glass formulation was selected from the bench-scale studies and recommended to ORNL for further testing with samples of actual OR waste tank sludges.

  9. CHARACTERIZING SOILS FOR HAZAROUDS WASTE SITE ASSESSMENTS

    EPA Science Inventory

    The purpose of this paper is to provide guidance to Remedial Project Managers (RPM) and On-Scene Coordinators (OSC) concerning soil characterization data types required for decision-making in the CERCLA RI/FS process related to risk assessment and remedial alternative evaluation ...

  10. 10 CFR 960.3-1-4-3 - Site recommendation for characterization.

    Code of Federal Regulations, 2011 CFR

    2011-01-01

    ... 10 Energy 4 2011-01-01 2011-01-01 false Site recommendation for characterization. 960.3-1-4-3... POTENTIAL SITES FOR A NUCLEAR WASTE REPOSITORY Implementation Guidelines § 960.3-1-4-3 Site recommendation for characterization. The evidence required to support the recommendation of a site as a candidate...

  11. Phenotypic and genotypic characterization of clinically relevant bacteria isolated from dental waste and waste workers' hands, mucosas and coats.

    PubMed

    Tagliaferri, T L; Vieira, C D; de Carvalho, M A R; Ladeira, L C D; Magalhães, P P; de Macêdo Farias, L; Dos Santos, S G

    2017-10-01

    Infectious wastes are potential sources of pathogenic micro-organisms, which may represent a risk to the professionals who manage them. In this study, we aimed to characterize the infectious bacteria present in dental waste and waste workers. The dental waste produced over 24 h was collected and waste workers were sampled by swabbing. Isolate resistance profiles were characterized by Vitek ® and PCR and biofilm formation by Congo Red agar, string test and microtitre assay. To assess similarity between the waste and the workers' samples, a random amplified polymorphic DNA test was used. Twenty-eight bacteria were identified as clinically relevant. The most frequent gene was bla TEM present in five Gram-negative micro-organisms, and one bla SHV in Klebsiella pneumoniae. All Pseudomonas aeruginosa were positive to extracellular polymeric substances formation, except one isolated from a worker. Klebsiella pneumoniae had negative results for the string test. Pseudomonas aeruginosa showed better adherence at 25°C after 48 h of incubation and K. pneumonia had the best biofilm formation at the same temperature, after 24 h. The similarity between P. aeruginosa recovered from dental waste and from workers was low, however, it is important to note that a pathogen was found on a worker's hands and that improvements in biosafety are required. Infectious dental waste can contain clinically relevant bacteria with important resistance and biofilm profiles. These micro-organisms could be transmitted to waste workers, other professionals and patients if the principles of biosafety measures are neglected. To our knowledge, no study has ever evaluated the microbial characterization and the potential contamination risk of dental infectious waste and waste handlers. The presence of clinically relevant bacteria in the hands and nasal mucosa of waste workers highlights the need for studies in this field to clarify the risk of these pathogens in dental healthcare services, and to stress the need for an efficient waste management. © 2017 The Society for Applied Microbiology.

  12. Food waste and the food-energy-water nexus: A review of food waste management alternatives.

    PubMed

    Kibler, Kelly M; Reinhart, Debra; Hawkins, Christopher; Motlagh, Amir Mohaghegh; Wright, James

    2018-04-01

    Throughout the world, much food produced is wasted. The resource impact of producing wasted food is substantial; however, little is known about the energy and water consumed in managing food waste after it has been disposed. Herein, we characterize food waste within the Food-Energy-Water (FEW) nexus and parse the differential FEW effects of producing uneaten food and managing food loss and waste. We find that various food waste management options, such as waste prevention, landfilling, composting, anaerobic digestion, and incineration, present variable pathways for FEW impacts and opportunities. Furthermore, comprehensive sustainable management of food waste will involve varied mechanisms and actors at multiple levels of governance and at the level of individual consumers. To address the complex food waste problem, we therefore propose a "food-waste-systems" approach to optimize resources within the FEW nexus. Such a framework may be applied to devise strategies that, for instance, minimize the amount of edible food that is wasted, foster efficient use of energy and water in the food production process, and simultaneously reduce pollution externalities and create opportunities from recycled energy and nutrients. Characterization of FEW nexus impacts of wasted food, including descriptions of dynamic feedback behaviors, presents a significant research gap and a priority for future work. Large-scale decision making requires more complete understanding of food waste and its management within the FEW nexus, particularly regarding post-disposal impacts related to water. Copyright © 2018 Elsevier Ltd. All rights reserved.

  13. DOE Office of Scientific and Technical Information (OSTI.GOV)

    Sailer, S.J.

    This Quality Assurance Project Plan (QAPJP) specifies the quality of data necessary and the characterization techniques employed at the Idaho National Engineering Laboratory (INEL) to meet the objectives of the Department of Energy (DOE) Waste Isolation Pilot Plant (WIPP) Transuranic Waste Characterization Quality Assurance Program Plan (QAPP) requirements. This QAPJP is written to conform with the requirements and guidelines specified in the QAPP and the associated documents referenced in the QAPP. This QAPJP is one of a set of five interrelated QAPjPs that describe the INEL Transuranic Waste Characterization Program (TWCP). Each of the five facilities participating in the TWCPmore » has a QAPJP that describes the activities applicable to that particular facility. This QAPJP describes the roles and responsibilities of the Idaho Chemical Processing Plant (ICPP) Analytical Chemistry Laboratory (ACL) in the TWCP. Data quality objectives and quality assurance objectives are explained. Sample analysis procedures and associated quality assurance measures are also addressed; these include: sample chain of custody; data validation; usability and reporting; documentation and records; audits and 0385 assessments; laboratory QC samples; and instrument testing, inspection, maintenance and calibration. Finally, administrative quality control measures, such as document control, control of nonconformances, variances and QA status reporting are described.« less

  14. Tank 241-AY-101 Privatization Push Mode Core Sampling and Analysis Plan

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    TEMPLETON, A.M.

    2000-01-12

    This sampling and analysis plan (SAP) identifies characterization objectives pertaining to sample collection, laboratory analytical evaluation, and reporting requirements for samples obtained from tank 241-AY-101. The purpose of this sampling event is to obtain information about the characteristics of the contents of 241-AY-101 required to satisfy Data Quality Objectives For RPP Privatization Phase I: Confirm Tank T Is An Appropriate Feed Source For High-Level Waste Feed Batch X(HLW DQO) (Nguyen 1999a), Data Quality Objectives For TWRS Privatization Phase I : Confirm Tank T Is An Appropriate Feed Source For Low-Activity Waste Feed Batch X (LAW DQO) (Nguyen 1999b), Low Activitymore » Waste and High-Level Waste Feed Data Quality Objectives (L and H DQO) (Patello et al. 1999), and Characterization Data Needs for Development, Design, and Operation of Retrieval Equipment Developed through the Data Quality Objective Process (Equipment DQO) (Bloom 1996). Special instructions regarding support to the LAW and HLW DQOs are provided by Baldwin (1999). Push mode core samples will be obtained from risers 15G and 150 to provide sufficient material for the chemical analyses and tests required to satisfy these data quality objectives. The 222-S Laboratory will extrude core samples; composite the liquids and solids; perform chemical analyses on composite and segment samples; archive half-segment samples; and provide subsamples to the Process Chemistry Laboratory. The Process Chemistry Laboratory will prepare test plans and perform process tests to evaluate the behavior of the 241-AY-101 waste undergoing the retrieval and treatment scenarios defined in the applicable DQOs. Requirements for analyses of samples originating in the process tests will be documented in the corresponding test plans and are not within the scope of this SAP.« less

  15. Characterizing the environmental impact of metals in construction and demolition waste.

    PubMed

    Yu, Danfeng; Duan, Huabo; Song, Qingbin; Li, Xiaoyue; Zhang, Hao; Zhang, Hui; Liu, Yicheng; Shen, Weijun; Wang, Jinben

    2018-05-01

    Large quantities of construction and demolition (C&D) waste are generated in China every year, but their potential environmental impacts on the surrounding areas are rarely assessed. This study focuses on metals contained in C&D waste, characterizing the metal concentrations and their related environmental risks. C&D waste samples were collected in Shenzhen City, China, from building demolition sites, renovation areas undergoing refurbishment, landfill sites, and recycling companies (all located in Shenzhen city) that produce recycled aggregate, in order to identify pollution levels of the metals As, Cd, Cr, Cu, Pb, Ni, and Zn. The results showed that (1) the metal concentrations in most demolition and renovation waste samples were below the soil environmental quality standard for agricultural purposes (SQ-Agr.) in China; (2) Cd, Cu, and Zn led to relatively higher environmental risks than other metals, especially for Zn (DM5 tile sample, 360 mg/kg; R4 tile sample, 281 mg/kg); (3) non-inert C&D waste such as wall insulation and foamed plastic had high concentrations of As and Cd, so that these materials required special attention for sound waste management; and (4) C&D waste collected from landfill sites had higher concentrations of Cd and Cu than did waste collected from demolition and refurbishment sites.

  16. Greater-than-Class C low-level waste characterization

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Piscitella, R.R.

    1991-12-31

    In 1985, Public Law 99-240 (Low-Level Radioactive Waste Policy Amendments Act of 1985) made the Department of Energy (DOE) responsible for the disposal of greater-than-Class C low-level radioactive waste (GTCC LLW). DOE strategies for storage and disposal of GTCC LLW required characterization of volumes, radionuclide activities, and waste forms. Data from existing literature, disposal records, and original research were used to estimate characteristics, project volumes, and determine radionuclide activities to the years 2035 and 2055. Twenty-year life extensions for 70% of the operating nuclear reactors were assumed to calculate the GTCC LLW available in 2055. The following categories of GTCCmore » LLW were addressed: Nuclear Utilities Waste; Potential Sealed Sources GTCC LLW; DOE-Held Potential GTCC LLW; and Other Generator Waste. It was determined that the largest volume of these wastes, approximately 57%, is generated by nuclear utilities. The Other Generator Waste category contributes approximately 10% of the total GTCC LLW volume projected to the year 2035. DOE-Held Potential GTCC LLW accounts for nearly 33% of all waste projected to the year 2035. Potential Sealed Sources GTCC LLW is less than 0.2% of the total projected volume. The base case total projected volume of GTCC LLW for all categories was 3,250 cubic meters. This was substantially less than previous estimates.« less

  17. Guidelines for generators to meet HWHF acceptance requirements for hazardous, radioactive, and mixed wastes at Berkeley Lab. Revision 3

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Albert, R.

    1996-06-01

    This document provides performance standards that one, as a generator of hazardous chemical, radioactive, or mixed wastes at the Berkeley Lab, must meet to manage their waste to protect Berkeley Lab staff and the environment, comply with waste regulations and ensure the continued safe operation of the workplace, have the waste transferred to the correct Waste Handling Facility, and enable the Environment, Health and Safety (EH and S) Division to properly pick up, manage, and ultimately send the waste off site for recycling, treatment, or disposal. If one uses and generates any of these wastes, one must establish a Satellitemore » Accumulation Area and follow the guidelines in the appropriate section of this document. Topics include minimization of wastes, characterization of the wastes, containers, segregation, labeling, empty containers, and spill cleanup and reporting.« less

  18. Tank 241-AZ-102 Privatization Push Mode Core Sampling and Analysis Plan

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    RASMUSSEN, J.H.

    1999-08-02

    This sampling and analysis plan (SAP) identifies characterization objectives pertaining to sample collection, laboratory analytical evaluation, and reporting requirements for samples obtained from tank 241-AZ-102. The purpose of this sampling event is to obtain information about the characteristics of the contents of 241-AZ-102 required to satisfy the Data Quality Objectives For TWRS Privatization Phase I: Confirm Tank TIS An Appropriate Feed Source For High-Level Waste Feed Batch X(HLW DQO) (Nguyen 1999a), Data Quality Objectives For TWRS Privatization Phase 1: Confirm Tank TIS An Appropriate Feed Source For Low-Activity Waste Feed Batch X (LAW DQO) (Nguyen 1999b), Low Activity Waste andmore » High Level Waste Feed Data Quality Objectives (L&H DQO) (Patello et al. 1999) and Characterization Data Needs for Development, Design, and Operation of Retrieval Equipment Developed through the Data Quality Objective Process (Equipment DQO) (Bloom 1996). The Tank Characterization Technical Sampling Basis document (Brown et al. 1998) indicates that these issues, except the Equipment DQO apply to tank 241-AZ-102 for this sampling event. The Equipment DQO is applied for shear strength measurements of the solids segments only. Poppiti (1999) requires additional americium-241 analyses of the sludge segments. Brown et al. (1998) also identify safety screening, regulatory issues and provision of samples to the Privatization Contractor(s) as applicable issues for this tank. However, these issues will not be addressed via this sampling event. Reynolds et al. (1999) concluded that information from previous sampling events was sufficient to satisfy the safety screening requirements for tank 241 -AZ-102. Push mode core samples will be obtained from risers 15C and 24A to provide sufficient material for the chemical analyses and tests required to satisfy these data quality objectives. The 222-S Laboratory will extrude core samples, composite the liquids and solids, perform chemical analyses, and provide subsamples to the Process Chemistry Laboratory. The Process Chemistry Laboratory will prepare test plans and perform process tests to evaluate the behavior of the 241-AZ-102 waste undergoing the retrieval and treatment scenarios defined in the applicable DQOs. Requirements for analyses of samples originating in the process tests will be documented in the corresponding test plan.« less

  19. Waste Isolation Pilot Plant Annual Site Environmental Report for 2014. Emended

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    none,

    2015-09-01

    The purpose of the Waste Isolation Pilot Plant (WIPP) Annual Site Environmental Report for 2014 (ASER) is to provide information required by U.S. Department of Energy (DOE) Order 231.1B, Environment, Safety, and Health Reporting. Specifically, the ASER presents summary environmental data to: Characterize site environmental management performance; Summarize environmental occurrences and responses reported during the calendar year (CY); Confirm compliance with environmental standards and requirements; Highlight significant environmental accomplishments, including progress toward the DOE environmental sustainability goals made through implementation of the WIPP Environmental Management System (EMS).

  20. 75 FR 54631 - Proposed Approval of the Central Characterization Project's Transuranic Waste Characterization...

    Federal Register 2010, 2011, 2012, 2013, 2014

    2010-09-08

    ... Central Characterization Project's Transuranic Waste Characterization Program at the Hanford Site AGENCY...) waste characterization program implemented by the Central Characterization Project (CCP) at the Hanford... characterization of TRU debris waste from Hanford-CCP during an inspection conducted on April 27-29, 2010. Using...

  1. Valorization of titanium metal wastes as tanning agent used in leather industry

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Crudu, Marian, E-mail: mariancrudu@yahoo.com; Deselnicu, Viorica, E-mail: viorica.deselnicu@icpi.ro; Deselnicu, Dana Corina, E-mail: d_deselnicu@yahoo.com

    2014-10-15

    Highlights: • Valorization of titanium wastes which cannot be recycled in metallurgical industry. • Transferring Ti waste into raw materials for obtaining Ti based tanning agent. • Characterization of new Ti based tanning agents and leather tanned with them. • Characterization of sewage waste water and sludge resulted from leather manufacture. • Analysis of the impact of main metal component of Ti waste. - Abstract: The development of new tanning agents and new technologies in the leather sector is required to cope with the increasingly higher environmental pressure on the current tanning materials and processes such as tanning with chromiummore » salts. In this paper, the use of titanium wastes (cuttings) resulting from the process of obtaining highly pure titanium (ingots), for the synthesis of new tanning agent and tanning bovine hides with new tanning agent, as alternative to tanning with chromium salts are investigated. For this purpose, Ti waste and Ti-based tanning agent were characterized for metal content by inductively coupled plasma mass spectrometry (ICP-MS) and chemical analysis; the tanned leather (wet white leather) was characterized by Scanning Electron Microscope/Energy Dispersive Using X-ray (Analysis). SEM/EDX analysis for metal content; Differential scanning calorimetric (DSC), Micro-Hot-Table and standard shrinkage temperature showing a hydrothermal stability (ranged from 75.3 to 77 °C) and chemical analysis showing the leather is tanned and can be processed through the subsequent mechanical operations (splitting, shaving). On the other hand, an analysis of major minor trace substances from Ti-end waste (especially vanadium content) in new tanning agent and wet white leather (not detected) and residue stream was performed and showed that leachability of vanadium is acceptable. The results obtained show that new tanning agent obtained from Ti end waste can be used for tanning bovine hides, as eco-friendly alternative for chrome tanning.« less

  2. Waste characterization study for the Kemp's Ridley sea turtle. Technical memo

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Malone, R.F.; Guarisco, M.

    1988-02-01

    The Kemp's Ridley sea turtle, Lepidochelys kempi, is an endangered species. The National Marine Fisheries Service's Head Start program is part of an international operation to save the turtles from extinction. Under the Head Start program, eggs from the Ridley's only known wild nesting beach at Rancho Nuevo in Mexico are transported to Padre Island on the Texas coast to be hatched. The head start enables the turtles to develop a survival advantage. The principal objective was to develop baseline waste-characterization data required to design a waste-water treatment scheme for the Galveston Head Start facility. As a secondary objective, preliminarymore » testing of some filtration components was undertaken to determine which units were most appropriate for inclusion in a wastewater treatment scheme.« less

  3. 1995 Report on Hanford site land disposal restrictions for mixed waste

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Black, D.G.

    This report was submitted to meet the requirements of Hanford Federal Facility Agreement and Consent Order Milestone M-26-01E. This milestone requires the preparation of an annual report that covers characterization, treatment, storage, minimization, and other aspects of land disposal restricted mixed waste at the Hanford Site. The U.S. Department of Energy, its predecessors, and contractors at the Hanford Site were involved in the production and purification of nuclear defense materials from the early 1940s to the late 1980s. These production activities have generated large quantities of liquid and solid radioactive mixed waste. This waste is subject to regulation under authoritymore » of both the Resource Conservation and Recovery Act of 1976 and Atomic Energy Act of 1954. This report covers mixed waste only. The Washington State Department of Ecology, U.S. Environmental Protection Agency, and U.S. Department of Energy have entered into an agreement, the Hanford Federal Facility Agreement and Consent Order (commonly referred to as the Tri-Party Agreement) to bring the Hanford Site operations into compliance with dangerous waste regulations. The Tri-Party Agreement required development of the original land disposal restrictions (LDRs) plan and its annual updates to comply with LDR requirements for radioactive mixed waste. This report is the fifth update of the plan first issued in 1990. Tri-Party Agreement negotiations completed in 1993 and approved in January 1994 changed and added many new milestones. Most of the changes were related to the Tank Waste Remediation System and these changes are incorporated into this report.« less

  4. Data sharing report characterization of the surveillance and maintenance project miscellaneous process inventory waste items Oak Ridge National Laboratory, Oak Ridge, TN

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Weaver, Phyllis C.

    2013-12-12

    The U.S. Department of Energy (DOE) Oak Ridge Office of Environmental Management (EM-OR) requested Oak Ridge Associated Universities (ORAU), working under the Oak Ridge Institute for Science and Education (ORISE) contract, to provide technical and independent waste management planning support under the American Recovery and Reinvestment Act (ARRA). Specifically, DOE EM-OR requested ORAU to plan and implement a sampling and analysis campaign to target certain items associated with URS|CH2M Oak Ridge, LLC (UCOR) surveillance and maintenance (S&M) process inventory waste. Eight populations of historical and reoccurring S&M waste at the Oak Ridge National Laboratory (ORNL) have been identified in themore » Waste Handling Plan for Surveillance and Maintenance Activities at the Oak Ridge National Laboratory, DOE/OR/01-2565&D2 (WHP) (DOE 2012) for evaluation and processing for final disposal. This waste was generated during processing, surveillance, and maintenance activities associated with the facilities identified in the process knowledge (PK) provided in Appendix A. A list of items for sampling and analysis were generated from a subset of materials identified in the WHP populations (POPs) 4, 5, 6, 7, and 8, plus a small number of items not explicitly addressed by the WHP. Specifically, UCOR S&M project personnel identified 62 miscellaneous waste items that would require some level of evaluation to identify the appropriate pathway for disposal. These items are highly diverse, relative to origin; composition; physical description; contamination level; data requirements; and the presumed treatment, storage, and disposal facility (TSDF). Because of this diversity, ORAU developed a structured approach to address item-specific data requirements necessary for acceptance in a presumed TSDF that includes the Environmental Management Waste Management Facility (EMWMF)—using the approved Waste Lot (WL) 108.1 profile—the Y-12 Sanitary Landfill (SLF) if appropriate; EnergySolutions Clive; and the Nevada National Security Site (NNSS) (ORAU 2013b). Finally, the evaluation of these wastes was more suited to a judgmental sampling approach rather than a statistical design, meaning data were collected for each individual item, thereby providing information for item-byitem disposition decisions. ORAU prepared a sampling and analysis plan (SAP) that outlined data collection strategies, methodologies, and analytical guidelines and requirements necessary for characterizing targeted items (ORAU 2013b). The SAP described an approach to collect samples that allowed evaluation as to whether or not the waste would be eligible for disposal at the EMWMF. If the waste was determined not to be eligible for EMWMF disposal, then there would be adequate information collected that would allow the waste to be profiled for one of the alternate TSDFs listed above.« less

  5. 77 FR 11112 - Proposed Approval of the Central Characterization Project's Remote-Handled Transuranic Waste...

    Federal Register 2010, 2011, 2012, 2013, 2014

    2012-02-24

    ... Central Characterization Project's Remote-Handled Transuranic Waste Characterization Program at the...-handled (RH), transuranic (TRU) waste characterization program implemented by the Central Characterization... Criteria, EPA evaluated the characterization of RH TRU debris waste from SRS-CCP during an inspection on...

  6. Performance characterization of water recovery and water quality from chemical/organic waste products

    NASA Technical Reports Server (NTRS)

    Moses, W. M.; Rogers, T. D.; Chowdhury, H.; Cullingford, H. S.

    1989-01-01

    The water reclamation subsystems currently being evaluated for the Space Shuttle Freedom are briefly reviewed with emphasis on a waste water management system capable of processing wastes containing high concentrations of organic/inorganic materials. The process combines low temperature/pressure to vaporize water with high temperature catalytic oxidation to decompose volatile organics. The reclaimed water is of potable quality and has high potential for maintenance under sterile conditions. Results from preliminary experiments and modifications in process and equipment required to control reliability and repeatability of system operation are presented.

  7. Characterization of Technetium Speciation in Cast Stone

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Um, Wooyong; Jung, Hun Bok; Wang, Guohui

    2013-11-11

    This report describes the results from laboratory tests performed at Pacific Northwest National Laboratory (PNNL) for the U.S. Department of Energy (DOE) EM-31 Support Program (EMSP) subtask, “Production and Long-Term Performance of Low Temperature Waste Forms” to provide additional information on technetium (Tc) speciation characterization in the Cast Stone waste form. To support the use of Cast Stone as an alternative to vitrification for solidifying low-activity waste (LAW) and as the current baseline waste form for secondary waste streams at the Hanford Site, additional understanding of Tc speciation in Cast Stone is needed to predict the long-term Tc leachability frommore » Cast Stone and to meet the regulatory disposal-facility performance requirements for the Integrated Disposal Facility (IDF). Characterizations of the Tc speciation within the Cast Stone after leaching under various conditions provide insights into how the Tc is retained and released. The data generated by the laboratory tests described in this report provide both empirical and more scientific information to increase our understanding of Tc speciation in Cast Stone and its release mechanism under relevant leaching processes for the purpose of filling data gaps and to support the long-term risk and performance assessments of Cast Stone in the IDF at the Hanford Site.« less

  8. Marshall Space Flight Center solid waste characterization and recycling improvement study

    NASA Technical Reports Server (NTRS)

    Eley, Michael H.; Crews, Lavonne; Johnston, Ben; Lee, David; Colebaugh, James

    1995-01-01

    The MSFC Facilities Office, which is responsible for disposing of all waste generated by MSFC, issued a delivery order to the University of Alabama in Huntsville (UAH) to characterize current MSFC waste streams and to evaluate their existing recycling program. The purpose of the study was to define the nature, quantity, and types of waste produced and to generate ideas for improving the present recycling program. Specifically, the following tasks were to be performed: Identify various surplus and waste materials--as identified by the Contracting Officer's Technical Representative (COTR)--by source, location, and type; Analyze MSFC's current methods for handling, storage, transport, and disposition of waste and surplussed materials; Determine the composition of various surplus and waste materials as to type and quantities from various sources and locations; Analyze different methods for the disposition of various surplus and waste materials, including quality, quantity, preparation, transport cost, and value; Study possible alternatives to current methods of handling, storage, transport, and disposition of surplus and waste materials to improve the quality and quantities recycled or sold and to reduce and minimize the quantities of surplus and waste material currently being disposed of or stored; Provide recommendations for source and centralized segregation and aggregation of materials for recycling and/or disposition; and The analysis could include identification and laboratory level evaluation of methods and/or equipment, including capital costs, operating costs, maintenance requirements, life cycle and return on investment for systems to support the waste reduction program mission.

  9. Food Waste in the Food-Energy-Water Nexus: Energy and Water Footprints of Wasted Food

    NASA Astrophysics Data System (ADS)

    Kibler, K. M.; Sarker, T.; Reinhart, D.

    2016-12-01

    The impact of wasted food to the food-energy-water (FEW) nexus is not well conceptualized or quantified, and is thus poorly understood. While improved understanding of water and energy requirements for food production may be applied to estimate costs associated with production of wasted food, the post-disposal costs of food waste to energy and water sectors are unknown. We apply both theoretical methods and direct observation of landfill leachate composition to quantify the net energy and water impact of food waste that is disposed in landfills. We characterize necessary energy inputs and biogas production to compute net impact to the energy sector. With respect to water, we quantify the volumes of water needed to attain permitted discharge concentrations of treated leachate, as well as the gray water footprint necessary for waste assimilation to the ambient regulatory standard. We find that approximately three times the energy produced as biogas (4.6E+8 kWh) is consumed in managing food waste and treating contamination from wasted food (1.3E+9 kWh). This energy requirement represents around 3% of the energy consumed in food production. The water requirement for leachate treatment and assimilation may exceed the amount of water needed to produce food. While not a consumptive use, the existence and replenishment of sufficient quantities of water in the environment for waste assimilation is an ecosystem service of the hydrosphere. This type of analysis may be applied to create water quality-based standards for necessary instream flows to perform the ecosystem service of waste assimilation. Clearer perception of wasted food as a source/sink for energy and water within the FEW nexus could be a powerful approach towards reducing the quantities of wasted food and more efficiently managing food that is wasted. For instance, comparative analysis of FEW impact across waste management strategies (e.g. landfilling, composting, anaerobic digestion) may assist local governments in developing integrated waste and water management strategies.

  10. 76 FR 62062 - Proposed Approval of the Central Characterization Project's Remote-Handled Transuranic Waste...

    Federal Register 2010, 2011, 2012, 2013, 2014

    2011-10-06

    ... Central Characterization Project's Remote-Handled Transuranic Waste Characterization Program at Sandia..., remote-handled (RH), transuranic (TRU) waste characterization program implemented by the Central Characterization Project (CCP) at Sandia National Laboratory (SNL) in Albuquerque, New Mexico. This waste is...

  11. 76 FR 33277 - Proposed Approval of the Central Characterization Project's Remote-Handled Transuranic Waste...

    Federal Register 2010, 2011, 2012, 2013, 2014

    2011-06-08

    ... Central Characterization Project's Remote-Handled Transuranic Waste Characterization Program at Bettis... radioactive remote-handled (RH) transuranic (TRU) waste characterization program implemented by the Central Characterization Project (CCP) at Bettis Atomic Power Laboratory (BAPL) in West Mifflin, Pennsylvania. This waste...

  12. Characterization of brominated flame retardants in construction and demolition waste components: HBCD and PBDEs.

    PubMed

    Duan, Huabo; Yu, Danfeng; Zuo, Jian; Yang, Bo; Zhang, Yukui; Niu, Yongning

    2016-12-01

    The vast majority of construction material is inert and can be managed as nonhazardous. However, structures may have either been built with some environmentally unfriendly substances such as brominated flame retardants (BFRs), or have absorbed harmful elements such as heavy metals. This study focuses on end-of-life construction materials, i.e. construction and demolition (C&D) waste components. The aim was to characterize the concentration of extremely harmful substances, primarily BFRs, including hexabromocyclododecane (HBCD) and polybrominateddiphenyl ethers (PBDEs). Results revealed extremely high contents of HBCD and PBDEs in typical C&D waste components, particularly polyurethane foam materials. Policies should therefore be developed for the proper management of C&D waste, with priority for POP-containing debris. The first priority is to develop a classification system and procedures to separate out the harmful materials for more extensive processing. Additionally, identification and quantification of the environmental implications associated with dumping-dominated disposal of these wastes are required. Finally, more sustainable materials should be selected for use in the construction industry. Copyright © 2016 Elsevier B.V. All rights reserved.

  13. Laboratory Methods for the Measurement of Pollutants in Water and Waste Effluents

    NASA Technical Reports Server (NTRS)

    Ballinger, Dwight G.

    1971-01-01

    The requirement for accurate, precise, and rapid analytical procedures for the examination of water and waste samples requires the use of a variety of instruments. The instrumentation in water laboratories includes atomic absorption, UV-visible. and infrared spectrophotometers, automatic colorimetric analyzers, gas chromatographs and mass spectrometers. Because of the emphasis on regulatory action, attention is being directed toward quality control of analytical results. Among the challenging problems are the differentiation of metallic species in water at nanogram concentrations, rapid measurement of free cyanide and free ammonia, more sensitive methods for arsenic and selenium and improved characterization of organic contaminants.

  14. Baseline LAW Glass Formulation Testing

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Kruger, Albert A.; Mooers, Cavin; Bazemore, Gina

    2013-06-13

    The major objective of the baseline glass formulation work was to develop and select glass formulations that are compliant with contractual and processing requirements for each of the LAW waste streams. Other objectives of the work included preparation and characterization of glasses with respect to the properties of interest, optimization of sulfate loading in the glasses, evaluation of ability to achieve waste loading limits, testing to demonstrate compatibility of glass melts with melter materials of construction, development of glass formulations to support ILAW qualification activities, and identification of glass formulation issues with respect to contract specifications and processing requirements.

  15. Environmental Quality Standards Research on Wastewaters of Army Ammunition Plants

    DTIC Science & Technology

    1978-06-01

    characterization of nitrocellulose wastewaters. We are grateful to LTC Leroy H. Reuter and LTC Robert P. Carnahan of the US Army Medical Research and...analytical methodology was required to characterize the wastes. The techniques used for fingerprinting (showing that the same compound exists although its...examination of the NC wastewaters has somewhat clarified the problem of characterizing the NC and has caused us to change or modify previous

  16. FIELD ANALYTICAL METHODS: ADVANCED FIELD MONITORING METHODS DEVELOPMENT AND EVALUATION OF NEW AND INNOVATIVE TECHNOLOGIES THAT SUPPORT THE SITE CHARACTERIZATION AND MONITORING REQUIREMENTS OF THE SUPERFUND PROGRAM.

    EPA Science Inventory

    The overall goal of this task is to help reduce the uncertainties in the assessment of environmental health and human exposure by better characterizing hazardous wastes through cost-effective analytical methods. Research projects are directed towards the applied development and ...

  17. Feasibility study of 235U and 239Pu characterization in radioactive waste drums using neutron-induced fission delayed gamma rays

    NASA Astrophysics Data System (ADS)

    Nicol, T.; Pérot, B.; Carasco, C.; Brackx, E.; Mariani, A.; Passard, C.; Mauerhofer, E.; Collot, J.

    2016-10-01

    This paper reports a feasibility study of 235U and 239Pu characterization in 225 L bituminized waste drums or 200 L concrete waste drums, by detecting delayed fission gamma rays between the pulses of a deuterium-tritium neutron generator. The delayed gamma yields were first measured with bare samples of 235U and 239Pu in REGAIN, a facility dedicated to the assay of 118 L waste drums by Prompt Gamma Neutron Activation Analysis (PGNAA) at CEA Cadarache, France. Detectability in the waste drums is then assessed using the MCNPX model of MEDINA (Multi Element Detection based on Instrumental Neutron Activation), another PGNAA cell dedicated to 200 L drums at FZJ, Germany. For the bituminized waste drum, performances are severely hampered by the high gamma background due to 137Cs, which requires the use of collimator and shield to avoid electronics saturation, these elements being very penalizing for the detection of the weak delayed gamma signal. However, for lower activity concrete drums, detection limits range from 10 to 290 g of 235U or 239Pu, depending on the delayed gamma rays of interest. These detection limits have been determined by using MCNPX to calculate the delayed gamma useful signal, and by measuring the experimental gamma background in MEDINA with a 200 L concrete drum mock-up. The performances could be significantly improved by using a higher interrogating neutron emission and an optimized experimental setup, which would allow characterizing nuclear materials in a wide range of low and medium activity waste packages.

  18. Radioactive Waste Characterization Strategies; Comparisons Between AK/PK, Dose to Curie Modeling, Gamma Spectroscopy, and Laboratory Analysis Methods- 12194

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Singledecker, Steven J.; Jones, Scotty W.; Dorries, Alison M.

    2012-07-01

    In the coming fiscal years of potentially declining budgets, Department of Energy facilities such as the Los Alamos National Laboratory (LANL) will be looking to reduce the cost of radioactive waste characterization, management, and disposal processes. At the core of this cost reduction process will be choosing the most cost effective, efficient, and accurate methods of radioactive waste characterization. Central to every radioactive waste management program is an effective and accurate waste characterization program. Choosing between methods can determine what is classified as low level radioactive waste (LLRW), transuranic waste (TRU), waste that can be disposed of under an Authorizedmore » Release Limit (ARL), industrial waste, and waste that can be disposed of in municipal landfills. The cost benefits of an accurate radioactive waste characterization program cannot be overstated. In addition, inaccurate radioactive waste characterization of radioactive waste can result in the incorrect classification of radioactive waste leading to higher disposal costs, Department of Transportation (DOT) violations, Notice of Violations (NOVs) from Federal and State regulatory agencies, waste rejection from disposal facilities, loss of operational capabilities, and loss of disposal options. Any one of these events could result in the program that mischaracterized the waste losing its ability to perform it primary operational mission. Generators that produce radioactive waste have four characterization strategies at their disposal: - Acceptable Knowledge/Process Knowledge (AK/PK); - Indirect characterization using a software application or other dose to curie methodologies; - Non-Destructive Analysis (NDA) tools such as gamma spectroscopy; - Direct sampling (e.g. grab samples or Surface Contaminated Object smears) and laboratory analytical; Each method has specific advantages and disadvantages. This paper will evaluate each method detailing those advantages and disadvantages including; - Cost benefit analysis (basic materials costs, overall program operations costs, man-hours per sample analyzed, etc.); - Radiation Exposure As Low As Reasonably Achievable (ALARA) program considerations; - Industrial Health and Safety risks; - Overall Analytical Confidence Level. The concepts in this paper apply to any organization with significant radioactive waste characterization and management activities working to within budget constraints and seeking to optimize their waste characterization strategies while reducing analytical costs. (authors)« less

  19. Pretest characterization of WIPP experimental waste

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Johnson, J.; Davis, H.; Drez, P.E.

    The Waste Isolation Pilot Plant (WIPP) near Carlsbad, New Mexico, is an underground repository designed for the storage and disposal of transuranic (TRU) wastes from US Department of Energy (DOE) facilities across the country. The Performance Assessment (PA) studies for WIPP address compliance of the repository with applicable regulations, and include full-scale experiments to be performed at the WIPP site. These experiments are the bin-scale and alcove tests to be conducted by Sandia National Laboratories (SNL). Prior to conducting these experiments, the waste to be used in these tests needs to be characterized to provide data on the initial conditionsmore » for these experiments. This characterization is referred to as the Pretest Characterization of WIPP Experimental Waste, and is also expected to provide input to other programmatic efforts related to waste characterization. The purpose of this paper is to describe the pretest waste characterization activities currently in progress for the WIPP bin-scale waste, and to discuss the program plan and specific analytical protocols being developed for this characterization. The relationship between different programs and documents related to waste characterization efforts is also highlighted in this paper.« less

  20. Milestones for Selection, Characterization, and Analysis of the Performance of a Repository for Spent Nuclear Fuel and High-Level Radioactive Waste at Yucca Mountain.

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Rechard, Robert P.

    This report presents a concise history in tabular form of events leading up to site identification in 1978, site selection in 1987, subsequent characterization, and ongoing analysis through 2008 of the performance of a repository for spent nuclear fuel and high-level radioactive waste at Yucca Mountain in southern Nevada. The tabulated events generally occurred in five periods: (1) commitment to mined geologic disposal and identification of sites; (2) site selection and analysis, based on regional geologic characterization through literature and analogous data; (3) feasibility analysis demonstrating calculation procedures and importance of system components, based on rough measures of performance usingmore » surface exploration, waste process knowledge, and general laboratory experiments; (4) suitability analysis demonstrating viability of disposal system, based on environment-specific laboratory experiments, in-situ experiments, and underground disposal system characterization; and (5) compliance analysis, based on completed site-specific characterization. Because the relationship is important to understanding the evolution of the Yucca Mountain Project, the tabulation also shows the interaction between four broad categories of political bodies and government agencies/institutions: (a) technical milestones of the implementing institutions, (b) development of the regulatory requirements and related federal policy in laws and court decisions, (c) Presidential and agency directives and decisions, and (d) critiques of the Yucca Mountain Project and pertinent national and world events related to nuclear energy and radioactive waste.« less

  1. Tank 241-AY-101 Privatization Push Mode Core Sampling and Analysis Plan

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    TEMPLETON, A.M.

    2000-05-19

    This sampling and analysis plan (SAP) identifies characterization objectives pertaining to sample collection, laboratory analytical evaluation, and reporting requirements for samples obtained from tank 241-AY-101. The purpose of this sampling event is to obtain information about the characteristics of the contents of 241-AY-101 required to satisfy ''Data Quality Objectives For RPP Privatization Phase I: Confirm Tank T Is An Appropriate Feed Source For High-Level Waste Feed Batch X(HLW DQO)' (Nguyen 1999a), ''Data Quality Objectives For TWRS Privatization Phase I: Confirm Tank T Is An Appropriate Feed Source For Low-Activity Waste Feed Butch X (LAW DQO) (Nguyen 1999b)'', ''Low Activity Wastemore » and High-Level Waste Feed Data Quality Objectives (L&H DQO)'' (Patello et al. 1999), and ''Characterization Data Needs for Development, Design, and Operation of Retrieval Equipment Developed through the Data Quality Objective Process (Equipment DQO)'' (Bloom 1996). Special instructions regarding support to the LAW and HLW DQOs are provided by Baldwin (1999). Push mode core samples will be obtained from risers 15G and 150 to provide sufficient material for the chemical analyses and tests required to satisfy these data quality objectives. The 222-S Laboratory will extrude core samples; composite the liquids and solids; perform chemical analyses on composite and segment samples; archive half-segment samples; and provide sub-samples to the Process Chemistry Laboratory. The Process Chemistry Laboratory will prepare test plans and perform process tests to evaluate the behavior of the 241-AY-101 waste undergoing the retrieval and treatment scenarios defined in the applicable DQOs. Requirements for analyses of samples originating in the process tests will be documented in the corresponding test plans and are not within the scope of this SAP.« less

  2. Role of geophysics in identifying and characterizing sites for high-level nuclear waste repositories.

    USGS Publications Warehouse

    Wynn, J.C.; Roseboom, E.H.

    1987-01-01

    Evaluation of potential high-level nuclear waste repository sites is an area where geophysical capabilities and limitations may significantly impact a major governmental program. Since there is concern that extensive exploratory drilling might degrade most potential disposal sites, geophysical methods become crucial as the only nondestructive means to examine large volumes of rock in three dimensions. Characterization of potential sites requires geophysicists to alter their usual mode of thinking: no longer are anomalies being sought, as in mineral exploration, but rather their absence. Thus the size of features that might go undetected by a particular method take on new significance. Legal and regulatory considerations that stem from this different outlook, most notably the requirements of quality assurance (necessary for any data used in support of a repository license application), are forcing changes in the manner in which geophysicists collect and document their data. -Authors

  3. Yucca Mountain Biological Resources Monitoring Program; Annual report, FY91

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    NONE

    1992-01-01

    The US Department of Energy (DOE) is required by the Nuclear Waste Policy Act of 1982 (as amended in 1987) to study and characterize Yucca Mountain as a possible site for a geologic repository for high-level nuclear waste. During site characterization, the DOE will conduct a variety of geotechnical, geochemical, geological, and hydrological studies to determine the suitability of Yucca Mountain as a repository. To ensure that site characterization activities (SCA) do not adversely affect the Yucca Mountain area, an environmental program has been implemented to monitor and mitigate potential impacts and to ensure that activities comply with applicable environmentalmore » regulations. This report describes the activities and accomplishments during fiscal year 1991 (FY91) for six program areas within the Terrestrial Ecosystem component of the YMP environmental program. The six program areas are Site Characterization Activities Effects, Desert Tortoises, Habitat Reclamation, Monitoring and Mitigation, Radiological Monitoring, and Biological Support.« less

  4. Remediation of a Former USAF Radioactive Material Disposal Site

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Hoffman, D. E.; Cushman, M; Tupyi, B.

    2003-02-25

    This paper describes the remediation of a low-level radiological waste burial site located at the former James Connally Air Force Base in Waco, Texas. Burial activities at the site occurred during the 1950's when the property was under the ownership of the United States Air Force. Included is a discussion of methods and strategies that were used to successfully exhume and characterize the wastes for proper disposal at offsite disposal facilities. Worker and environmental protection measures are also described. Information gained from this project may be used at other similar project sites. A total of nine burial tubes had beenmore » identified for excavation, characterization, and removal from the site. The disposal tubes were constructed of 4-ft lengths of concrete pipe buried upright with the upper ends flush with ground surface. Initial ground level observations of the burial tubes indicated that some weathering had occurred; however, the condition of the subsurface portions of the tubes was unknown. Soil excavation occurred in 1-foot lifts in order that the tubes could be inspected and to allow for characterization of the soils at each stage of the excavation. Due to the weight of the concrete pipe and the condition of the piping joints it was determined that special measures would be required to maintain the tubes intact during their removal. Special tube anchoring and handling methods were required to relocate the tubes from their initial positions to a staging area where they could be further characterized. Characterization of the disposal tubes was accomplished using a combination of gamma spectroscopy and activity mapping methods. Important aspects of the project included the use of specialized excavation and disposal tube reinforcement measures to maintain the disposal tubes intact during excavation, removal and subsequent characterization. The non-intrusive gamma spectroscopy and data logging methods allowed for effective characterization of the wastes while minimizing disposal costs. In addition, worker exposures were maintained ALARA as a result of the removal and characterization methods employed.« less

  5. Integrated software system for low level waste management

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Worku, G.

    1995-12-31

    In the continually changing and uncertain world of low level waste management, many generators in the US are faced with the prospect of having to store their waste on site for the indefinite future. This consequently increases the set of tasks performed by the generators in the areas of packaging, characterizing, classifying, screening (if a set of acceptance criteria applies), and managing the inventory for the duration of onsite storage. When disposal sites become available, it is expected that the work will require re-evaluating the waste packages, including possible re-processing, re-packaging, or re-classifying in preparation for shipment for disposal undermore » the regulatory requirements of the time. In this day and age, when there is wide use of computers and computer literacy is at high levels, an important waste management tool would be an integrated software system that aids waste management personnel in conducting these tasks quickly and accurately. It has become evident that such an integrated radwaste management software system offers great benefits to radwaste generators both in the US and other countries. This paper discusses one such approach to integrated radwaste management utilizing some globally accepted radiological assessment software applications.« less

  6. Radiation safety requirements for radioactive waste management in the framework of a quality management system

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Salgado, M.M.; Benitez, J.C.; Pernas, R.

    2007-07-01

    The Center for Radiation Protection and Hygiene (CPHR) is the institution responsible for the management of radioactive wastes generated from nuclear applications in medicine, industry and research in Cuba. Radioactive Waste Management Service is provided at a national level and it includes the collection and transportation of radioactive wastes to the Centralized Waste Management Facilities, where they are characterized, segregated, treated, conditioned and stored. A Quality Management System, according to the ISO 9001 Standard has been implemented for the RWM Service at CPHR. The Management System includes the radiation safety requirements established for RWM in national regulations and in themore » Licence's conditions. The role of the Regulatory Body and the Radiation Protection Officer in the Quality Management System, the authorization of practices, training and personal qualification, record keeping, inspections of the Regulatory Body and internal inspection of the Radiation Protection Officer, among other aspects, are described in this paper. The Quality Management System has shown to be an efficient tool to demonstrate that adequate measures are in place to ensure the safety in radioactive waste management activities and their continual improvement. (authors)« less

  7. Status of Environmental Management Initiatives to Accelerate the Reduction of Environmental Risks and Challenges Posed by the Legacy of the Cold War

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    None

    2009-01-01

    Fifty years of nuclear weapons production and energy research in the United States during the Cold War generated large amounts of radioactive wastes, spent nuclear fuel (SNF), excess plutonium and uranium, thousands of contaminated facilities, and contaminated soil and groundwater. During most of that half century, the Nation did not have the environmental regulatory structure or nuclear waste cleanup technologies that exist today. The result was a legacy of nuclear waste that was stored and disposed of in ways now considered unacceptable. Cleaning up and ultimately disposing of these wastes is the responsibility of the U.S. Department of Energy (DOE).more » In 1989, DOE established the Office of Environmental Management (EM) to solve the large scale and technically challenging risks posed by the world's largest nuclear cleanup. This required EM to build a new nuclear cleanup infrastructure, assemble and train a technically specialized workforce, and develop the technologies and tools required to safely decontaminate, disassemble, stabilize, disposition, and remediate unique radiation hazards. The sites where nuclear activities produced legacy waste and contamination include the original Manhattan Project sites--Los Alamos, New Mexico; Hanford, Washington; and Oak Ridge, Tennessee--as well as major Cold War sites, such as Savannah River Site, South Carolina; the Idaho National Laboratory, Idaho; Rocky Flats Plant, Colorado; and Fernald, Ohio. Today EM has responsibility for nuclear cleanup activities at 21 sites covering more than two million acres in 13 states, and employs more than 30,000 Federal and contractor employees, including scientists, engineers and hazardous waste technicians. This cleanup poses unique, technically complex problems, which must be solved under the most hazardous of conditions, and which will require billions of dollars a year for several more decades. The EM program focus during its first 10 years was on managing the most urgent risks and maintaining safety at each site while negotiating state and Federal environmental compliance agreements. The program also concentrated on characterizing waste and nuclear materials and assessing the magnitude and extent of environmental contamination. By the late 1990s, EM had made significant progress in identifying and characterizing the extent of contamination and cleanup required and began transitioning from primarily a characterization and stabilization program to an active cleanup and closure program. During that time, EM formulated multi-year cleanup and closure plans, which contributed to cleanup progress; however, reducing the overall environmental risk associated with the cleanup program remained a challenge. In response, the Secretary of Energy directed a review of the EM program be undertaken. The resulting 'Top-to Bottom Review' re-directed the program focus from managing risks to accelerating the reduction of these risks.« less

  8. Characterization of radioactive wastes with respect to harmful materials

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Kugel, Karin; Steyer, Stefan; Brennecke, Peter

    In addendum 4 to the license of the German KONRAD repository, which considers mainly radiological aspects, a water law permit was issued in order to prevent the pollution of the near-surface groundwater. The water law permit stipulates limitations for 10 radionuclides and 2 groups of radionuclides as well as mass limitations for 94 substances and materials relevant for water protection issues. Two collateral clauses, i.e. additional requirements imposed by the licensing authority, include demands on the monitoring, registering and balancing of non-radioactive harmful substances and materials /1/. In order to fulfill the requirements of the water law permit the Germanmore » Federal Office for Radiation Protection (BfS) being the operator of the KONRAD repository has developed a concept, which ensures the compliance with all requirements of the water law permit and which provides standardized easy manageable guidance for the waste producers to describe their wastes. On 15 March 2011 the competent water authority, the 'Niedersaechsischer Landesbetrieb fuer Wasserwirtschaft, Kuesten- und Naturschutz' (NLWKN) issued the approval for this concept. Being the most essential part of this concept the procedural method and the developed description of nonradioactive waste package constituents by use of standardized lists of materials and containers is addressed and presented in this paper. The waste producer has to describe his waste package in a standardized way on the base of the lists of materials and containers. For each material in the list a comprehensive description is given comprising the composition, scope of application, quality control measures, thresholds and other data. Each entry in the list has to be approved by NLWKN. The scope of the lists is defined by the waste producers' needs. Using some particular materials as examples, the approval procedure for including materials in the list is described. The procedure of describing the material composition has to be considered in the KONRAD waste acceptance requirements. The respective part of these requirements will be introduced. In order to clarify the procedure of describing waste packages by use of the standardized lists of materials and containers some examples of typical waste package descriptions will be presented. (authors)« less

  9. The Self-Reducing Pellet Production from Organic Household Waste

    NASA Astrophysics Data System (ADS)

    Nogueira, Alberto; Takano, Cyro; Mourão, Marcelo; Pillihuaman, Adolfo

    The organic household waste has a growing disposal problem, requiring costly disposal systems. It is necessary to find new applications for these materials; one could be the steelmaking raw material production. In this paper is studied the development of self-reducing pellets from the organic waste pyrolysis, where is generated carbon and condensable and non-condensable volatiles. Non-condensable volatiles were burned and condensable volatiles were recovered. The resulting tar was mixed with iron ore, coal powder and flux (CaO), to then be pelletized together. Compression, falls and tumbler tests were conducted to characterize the pellets before and after heat treatment and reduction processes. The reduction curve and their physical and morphological characterization were measured. The results were as was expected, the fluidized coal create sufficient adhesion that pellets earned resistance with an equivalent resistance of common pellets, showing a good feasibility of this process.

  10. Final Report. Baseline LAW Glass Formulation Testing, VSL-03R3460-1, Rev. 0

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Muller, Isabelle S.; Pegg, Ian L.; Gan, Hao

    2015-06-18

    The major objective of the baseline glass formulation work was to develop and select glass formulations that are compliant with contractual and processing requirements for each of the LAW waste streams. Other objectives of the work included preparation and characterization of glasses with respect to the properties of interest, optimization of sulfate loading in the glasses, evaluation of ability to achieve waste loading limits, testing to demonstrate compatibility of glass melts with melter materials of construction, development of glass formulations to support ILAW qualification activities, and identification of glass formulation issues with respect to contract specifications and processing requirements.

  11. Yucca Mountain Biological Resources Monitoring Program. Progress report, January 1994--December 1994

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    NONE

    1995-07-01

    The US Department of Energy (DOE) is required by the Nuclear Waste Policy Act of 1982 (as amended in 1987) to study and characterize the suitability of Yucca Mountain as a potential geological repository for high-level nuclear waste. During site characterization, the DOE will conduct a variety of geotechnical, geochemical, geological, and hydrological studies to determine the suitability of Yucca Mountain as a potential repository. To ensure that site characterization activities do not adversely affect the environment at Yucca Mountain, a program has been implemented to monitor and mitigate potential impacts and ensure activities comply with applicable environmental regulations. Thismore » report describes the activities and accomplishments of EG and G Energy Measurements, Inc. (EG and G/EM) from January 1994 through December 1994 for six program areas within the Terrestrial Ecosystem component of the environmental program for the Yucca Mountain Site Characterization Project (YMP): Site Characterization Effects, Desert Tortoises (Gopherus agassizii), Habitat Reclamation, Monitoring and Mitigation, Radiological Monitoring, and Biological Support.« less

  12. Characterization of urban solid waste in Chihuahua, Mexico.

    PubMed

    Gomez, Guadalupe; Meneses, Montserrat; Ballinas, Lourdes; Castells, Francesc

    2008-12-01

    The characterization of urban solid waste generation is fundamental for adequate decision making in the management strategy of urban solid waste in a city. The objective of this study is to characterize the waste generated in the households of Chihuahua city, and to compare the results obtained in areas of the city with three different socioeconomic levels. In order to identify the different socioeconomic trends in waste generation and characterization, 560 samples of solid waste were collected during 1 week from 80 households in Chihuahua and were hand sorted and classified into 15 weighted fractions. The average waste generation in Chihuahua calculated in this study was 0.676 kg per capita per day in April 2006. The main fractions were: organic (48%), paper (16%) and plastic (12%). Results show an increased waste generation associated with the socioeconomic level. The characterization in amount and composition of urban waste is the first step needed for the successful implementation of an integral waste management system.

  13. Regulatory requirements and tools for environmental assessment of hazardous wastes: Understanding tribal and stakeholder concerns using Department of Energy sites

    PubMed Central

    Burger, Joanna; Powers, Charles; Gochfeld, Michael

    2014-01-01

    Many US governmental and Tribal Nation agencies, as well as state and local entities, deal with hazardous wastes within regulatory frameworks that require specific environmental assessments. In this paper we use Department of Energy (DOE) sites as examples to examine the relationship between regulatory requirements and environmental assessments for hazardous waste sites and give special attention to how assessment tools differ. We consider federal laws associated with environmental protection include the National Environmental Policy Act (NEPA), the Resource Conservation and Recovery Act (RCRA), the Comprehensive Environmental Response Compensation and Liability Act (CERCLA), as well as regulations promulgated by the Nuclear Regulatory Commission, Tribal Nations and state agencies. These regulatory regimes require different types of environmental assessments and remedial investigations, dose assessments and contaminant pathways. The DOE case studies illustrate the following points: 1) there is often understandable confusion about what regulatory requirements apply to the site resources, and what environmental assessments are required by each, 2) the messages sent on site safety issued by different regulatory agencies are sometimes contradictory or confusing (e.g. Oak Ridge Reservation), 3) the regulatory frameworks being used to examine the same question can be different, leading to different conclusions (e.g. Brookhaven National Laboratory), 4) computer models used in support of groundwater models or risk assessments are not necessarily successful in convincing Native Americans and others that there is no possibility of risk from contaminants (e.g. Amchitka Island), 5) when given the opportunity to choose between relying on a screening risk assessments or waiting for a full site-specific analysis of contaminants in biota, the screening risk assessment option is rarely selected (e.g. Amchitka, Hanford Site), and finally, 6) there needs to be agreement on whether there has been adequate characterization to support the risk assessment (e.g. Hanford). The assessments need to be transparent and to accommodate different opinions about the relationship between characterizations and risk assessments. This paper illustrates how many of the problems at DOE sites, and potentially at other sites in the U.S. and elsewhere, derive from a lack of either understanding of, or consensus about, the regulatory process, including the timing and types of required characterizations and data in support of site characterizations and risk assessments. PMID:20719428

  14. Screening and Spectral Summing of LANL Empty Waste Drums - 13226

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Gruetzmacher, Kathleen M.; Bustos, Roland M.; Ferran, Scott G.

    2013-07-01

    Empty 55-gallon drums that formerly held transuranic (TRU) waste (often over-packed in 85- gallon drums) are generated at LANL and require radiological characterization for disposition. These drums are typically measured and analyzed individually using high purity germanium (HPGe) gamma detectors. This approach can be resource and time intensive. For a project requiring several hundred drums to be characterized in a short time frame, an alternative approach was developed. The approach utilizes a combination of field screening and spectral summing that was required to be technically defensible and meet the Nevada Nuclear Security Site (NNSS) Waste Acceptance Criteria (WAC). In themore » screening phase of the operation, the drums were counted for 300 seconds (compared to 600 seconds for the typical approach) and checked against Low Level (LL)/TRU thresholds established for each drum configuration and detector. Multiple TRU nuclides and multiple gamma rays for each nuclide were evaluated using an automated spreadsheet utility that can process data from up to 42 drums at a time. Screening results were reviewed by an expert analyst to confirm the field LL/TRU determination. The spectral summing analysis technique combines spectral data (channel-by-channel) associated with a group of individual waste containers producing a composite spectrum. The grouped drums must meet specific similarity criteria. Another automated spreadsheet utility was used to spectral sum data from an unlimited number of similar drums grouped together. The composite spectrum represents a virtual combined drum for the group of drums and was analyzed using the SNAP{sup TM}/Radioassay Data Sheet (RDS)/Batch Data Report (BDR) method. The activity results for a composite virtual drum were divided equally amongst the individual drums to generate characterization results for each individual drum in the group. An initial batch of approximately 500 drums were measured and analyzed in less than 2 months in 2011. A second batch of approximately 500 more drums were measured and analyzed during the following 2 1/2 months. Four different HPGe detectors were employed for the operation. The screening and spectral summing approach can reduce the overall measurement and analysis time required. However, developing the technical details and automation spreadsheets requires a significant amount of expert time prior to beginning field operations and must be considered in the overall project schedule. This approach has continued to be used for characterizing several hundred more empty drums in 2012 and is planned to continue in 2013. (authors)« less

  15. Site Safety and Health Plan (Phase 3) for the treatability study for in situ vitrification at Seepage Pit 1 in Waste Area Grouping 7, Oak Ridge National Laboratory, Oak Ridge, TN

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Spalding, B.P.; Naney, M.T.

    1995-06-01

    This plan is to be implemented for Phase III ISV operations and post operations sampling. Two previous project phases involving site characterization have been completed and required their own site specific health and safety plans. Project activities will take place at Seepage Pit 1 in Waste Area Grouping 7 at ORNL, Oak Ridge, Tennessee. Purpose of this document is to establish standard health and safety procedures for ORNL project personnel and contractor employees in performance of this work. Site activities shall be performed in accordance with Energy Systems safety and health policies and procedures, DOE orders, Occupational Safety and Healthmore » Administration Standards 29 CFR Part 1910 and 1926; applicable United States Environmental Protection Agency requirements; and consensus standards. Where the word ``shall`` is used, the provisions of this plan are mandatory. Specific requirements of regulations and orders have been incorporated into this plan in accordance with applicability. Included from 29 CFR are 1910.120 Hazardous Waste Operations and Emergency Response; 1910.146, Permit Required - Confined Space; 1910.1200, Hazard Communication; DOE Orders requirements of 5480.4, Environmental Protection, Safety and Health Protection Standards; 5480.11, Radiation Protection; and N5480.6, Radiological Control Manual. In addition, guidance and policy will be followed as described in the Environmental Restoration Program Health and Safety Plan. The levels of personal protection and the procedures specified in this plan are based on the best information available from reference documents and site characterization data. Therefore, these recommendations represent the minimum health and safety requirements to be observed by all personnel engaged in this project.« less

  16. Development of characterization protocol for mixed liquid radioactive waste classification

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Zakaria, Norasalwa, E-mail: norasalwa@nuclearmalaysia.gov.my; Wafa, Syed Asraf; Wo, Yii Mei

    2015-04-29

    Mixed liquid organic waste generated from health-care and research activities containing tritium, carbon-14, and other radionuclides posed specific challenges in its management. Often, these wastes become legacy waste in many nuclear facilities and being considered as ‘problematic’ waste. One of the most important recommendations made by IAEA is to perform multistage processes aiming at declassification of the waste. At this moment, approximately 3000 bottles of mixed liquid waste, with estimated volume of 6000 litres are currently stored at the National Radioactive Waste Management Centre, Malaysia and some have been stored for more than 25 years. The aim of this studymore » is to develop a characterization protocol towards reclassification of these wastes. The characterization protocol entails waste identification, waste screening and segregation, and analytical radionuclides profiling using various analytical procedures including gross alpha/ gross beta, gamma spectrometry, and LSC method. The results obtained from the characterization protocol are used to establish criteria for speedy classification of the waste.« less

  17. Characterization Results For The 2013 HTF 3H Evaporator Overhead Samples

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Washington, A. L. II

    2013-12-04

    This report tabulates the radiochemical analysis of the 3H evaporator overhead sample for {sup 137}Cs, {sup 90}Sr, and {sup 129}I to meet the requirements in the Effluent Treatment Project (ETP) Waste Acceptance Criteria (WAC) (rev. 6). This report identifies the sample receipt date, preparation method, and analysis performed in the accumulation of the listed values. All data was found to be within the ETP WAC (rev. 6) specification for the Waste Water Collection Tanks (WWCT).

  18. Characterization Results for the 2014 HTF 3H & 2H Evaporator Overhead Samples

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Washington, A.

    2015-05-11

    This report tabulates the radiochemical analysis of the 3H and 2H evaporator overhead samples for 137Cs, 90Sr, and 129I to meet the requirements in the Effluent Treatment Project (ETP) Waste Acceptance Criteria (WAC) (rev. 6). This report identifies the sample receipt date, preparation method, and analysis performed in the accumulation of the listed values. All data was found to be within the ETP WAC (rev. 6) specification for the Waste Water Collection Tanks (WWCT).

  19. HOUSEHOLD HAZARDOUS WASTE CHARACTERIZATION STUDY FOR PALM BEACH COUNTY, FLORIDA - A MITE PROGRAM EVALUATION

    EPA Science Inventory

    The objectives of the Household Hazardous Waste Characterization Study (the HHW Study) were to: 1) Quantity the annual household hazardous waste (HHW) tonnages disposed in Palm Beach County Florida’s (the County) residential solid waste (characterized in this study as municipal s...

  20. Characterization of Crew Refuse Returned from Shuttle Missions with Permanent Gas, Volatile Organic Compound, and Microbial Analyses

    NASA Astrophysics Data System (ADS)

    Peterson, B.; Hummerick, M.; Roberts, M.; Krummins, V.; Kish, A.; Garland, J.; Maxwell, S.; Mills, A.

    In addition to the mass and energy costs associated with bioregenerative systems for advanced life support, the storage and processing of waste on spacecraft requires both atmospheric and biological management. Risks to crew health may arise from the presence of potential human pathogens in waste or from decay processes during waste storage and/or processing. This study reports on the permanent gas, trace volatile organic and microbiological analyses of crew refuse returned from shuttle missions STS-105, 109 and 110. The research objective is to characterize the biological stability of the waste stream, to assess the risks associated with its storage, and to provide baseline measures for the evaluation of waste processing technologies. Microbiological samples were collected from packaging material, food waste, bathroom waste, and bulk liquid collected from the volume F waste container. The number of culturable bacteria and total bacteria were determined by plating on R2A media and by Acridine Orange direct count, respectively. Samples of the trash were analyzed for the presence of fecal and total coliforms and other human-associated bacteria. Dry and ash weights were determined to estimate both water and organic content of the materials. The aerobic and anaerobic bio-stability of stored waste was determined by on-line monitoring of CO2 and by laboratory analysis of off-gas samples for hydrogen sulfide and methane. Volatile organic compounds and permanent gases were analyzed using EPA method TO15 with gas chromatography/mass spectrometry and by gas chromatography with selective detectors . This study establishes a baseline measure of waste composition, labile organics, and microbial load for this material.

  1. Mineralogical, Microstructural and Thermal Characterization of Coal Fly Ash Produced from Kazakhstani Power Plants

    NASA Astrophysics Data System (ADS)

    Tauanov, Z.; Abylgazina, L.; Spitas, C.; Itskos, G.; Inglezakis, V.

    2017-09-01

    Coal fly ash (CFA) is a waste by-product of coal combustion. Kazakhstan has vast coal deposits and is major consumer of coal and hence produces huge amounts of CFA annually. The government aims to recycle and effectively utilize this waste by-product. Thus, a detailed study of the physical and chemical properties of material is required as the data available in literature is either outdated or not applicable for recently produced CFA samples. The full mineralogical, microstructural and thermal characterization of three types of coal fly ash (CFA) produced in two large Kazakhstani power plants is reported in this work. The properties of CFAs were compared between samples as well as with published values.

  2. MUNICIPAL WASTE COMBUSTION ASSESSMENT ...

    EPA Pesticide Factsheets

    The report defines and characterizes types of medical waste, discusses the impacts of burning medical waste on combustor emissions, and outlines important handling and operating considerations. Facility-specific design, handling, and operating practiced are also discussed for municipal waste combustors (MWCs) that reportedly accept medical waste in the U.S., Europe, and Canada. nly very limited data are available on the emission impacts associated with the combustion of medical waste in MWGs. Especially lacking is information needed to fully evaluate the impacts on acid gas, dioxin, and metals emissions, as well as the design and operating requirements for complete destruction of solvents, cytotoxic chemicals, and pathogens. The EPA's Office of Air Quatity Planning and Standards is developing emission standards and guidelines for new and existing MWCs under Sections 111(b) and 111(d) of the Clean Air Act. In support of these regulatory development efforts, the Air and Energy Engineering Research Laboratory in EPA's Office of Research and Development has conducted an assessment to examine the incineration of medical waste in MWGs from an emission standpoint. Potential worker safety and health problems associated with handling of medical wastes and residues were also identified. information

  3. Ecotoxicological assessment of the potential impact on soil porewater, surface and groundwater from the use of organic wastes as soil amendments.

    PubMed

    Alvarenga, Paula; Mourinha, Clarisse; Farto, Márcia; Palma, Patrícia; Sengo, Joana; Morais, Marie-Christine; Cunha-Queda, Cristina

    2016-04-01

    This study aimed to assess the potential impact on soil porewater, surface and groundwater from the beneficial application of organic wastes to soil, using their eluates and acute bioassays with aquatic organisms and plants: luminescence inhibition of Vibrio fischeri (15 and 30 min), Daphnia magna immobilization (48 h), Thamnocephalus platyurus survival (24 h), and seed germination of Lolium perenne (7 d) and Lactuca sativa (5 d). Some organic wastes' eluates promoted high toxic responses, but that toxicity could not be predicted by their chemical characterization, which is compulsory by regulatory documents. In fact, when organisms were exposed to the water-extractable chemical compounds of the organic wastes, the toxic responses were more connected to the degree of stabilization of the organic wastes, or to the treatment used to achieve that stabilization, than to their contaminant load. That is why the environmental risk assessment of the use of organic wastes as soil amendments should integrate bioassays with eluates, in order to correctly evaluate the effects of the most bioavailable fraction of all the chemical compounds, which can be difficult to predict from the characterization required in regulatory documents. According to our results, some rapid and standardized acute bioassays can be suggested to integrate a Tier 1 ecotoxicological evaluation of organic wastes with potential to be land applied, namely luminescence inhibition of V. fischeri, D. magna immobilization, and the germination of L. perenne and L. sativa. Copyright © 2015 Elsevier Inc. All rights reserved.

  4. Yucca Mountain biological resources monitoring program; Annual report FY92

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    NONE

    1993-02-01

    The US Department of Energy (DOE) is required by the Nuclear Waste Policy Act of 1982 (as amended in 1987) to study and characterize Yucca Mountain as a potential site for a geologic repository for high-level nuclear waste. During site characterization, the DOE will conduct a variety of geotechnical, geochemical, geological, and hydrological studies to determine the suitability of Yucca Mountain as a potential repository. To ensure that site characterization activities (SCA) do not adversely affect the environment at Yucca Mountain, an environmental program has been implemented to monitor and mitigate potential impacts and ensure activities comply with applicable environmentalmore » regulations. This report describes the activities and accomplishments of EG&G Energy Measurements, Inc. (EG&G/EM) during fiscal year 1992 (FY92) for six program areas within the Terrestrial Ecosystem component of the YMP environmental program. The six program areas are Site Characterization Effects, Desert Tortoises, Habitat Reclamation, Monitoring and Mitigation, Radiological Monitoring, and Biological Support.« less

  5. GY SAMPLING THEORY IN ENVIRONMENTAL STUDIES 2: SUBSAMPLING ERROR MEASUREMENTS

    EPA Science Inventory

    Sampling can be a significant source of error in the measurement process. The characterization and cleanup of hazardous waste sites require data that meet site-specific levels of acceptable quality if scientifically supportable decisions are to be made. In support of this effort,...

  6. 40 CFR 191.21 - Applicability.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... of any site required to be characterized under section 113(a) of Public Law 97-425, 96 Stat. 2201. ... ENVIRONMENTAL RADIATION PROTECTION STANDARDS FOR MANAGEMENT AND DISPOSAL OF SPENT NUCLEAR FUEL, HIGH-LEVEL AND TRANSURANIC RADIOACTIVE WASTES Environmental Standards for Ground-Water Protection § 191.21 Applicability. (a...

  7. ORNL Remedial Action Program strategy (FY 1987-FY 1992)

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Trabalka, J.R.; Myrick, T.E.

    1987-12-01

    Over 40 years of Oak Ridge National Laboratory (ORNL) operations have produced a diverse legacy of contaminated inactive facilities, research areas, and waste disposal areas that are potential candidates for remedial action. The ORNL Remedial Action Program (RAP) represents a comprehensive effort to meet new regulatory requirements and ensure adequate protection of on-site workers, the public, and the environment by providing appropriate corrective measures at over 130 sites contaminated historically with radioactive, hazardous chemical, or mixed wastes. A structured path of program planning, site characterization, alternatives assessment, technology development, engineering design, continued site maintenance and surveillance, interim corrective action, andmore » eventual site closure or decommissioning is required to meet these objectives. This report documents the development of the Remedial Action Program, through its preliminary characterization, regulatory interface, and strategy development activities. It provides recommendations for a comprehensive, long-term strategy consistent with existing technical, institutional, and regulatory information, along with a six-year plan for achieving its initial objectives. 53 refs., 8 figs., 12 tabs.« less

  8. Peoria Disposal Co.`s PDC Laboratories: Analyzing and cleaning up -- Literally

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    McAdams, C.L.

    1995-10-01

    In the early 1980s, says Royal Coulter, president and CEO of Peoria Disposal Co. (PDC, Peoria, IL), many PDC customers were unfamiliar with the methods required for the proper characterization of then newly regulated hazardous wastes. So in early 1981, to expedite permitting and, ultimately, acceptance of waste by PDC, a lab was set up so the company could step in and provide the needed services. By focusing on the delivery of quality services in the analysis of groundwater, wastewater, and solid waste for PDC, Coulter says, the laboratory soon developed into a successful and independent commercial operation. In Julymore » of 1981, PDC Laboratories was incorporated as an independent environmental analytical laboratory. PDC Labs is a subsidiary of PDC Technical Services, Inc., which provides environmental consulting and site remediation services, and is itself a wholly-owned subsidiary of Coulter Companies, Inc. Peoria Disposal offers solid waste disposal, industrial waste water treatment, waste stabilization, transportation services, and brokerage services.« less

  9. Prediction of municipal solid waste generation using nonlinear autoregressive network.

    PubMed

    Younes, Mohammad K; Nopiah, Z M; Basri, N E Ahmad; Basri, H; Abushammala, Mohammed F M; Maulud, K N A

    2015-12-01

    Most of the developing countries have solid waste management problems. Solid waste strategic planning requires accurate prediction of the quality and quantity of the generated waste. In developing countries, such as Malaysia, the solid waste generation rate is increasing rapidly, due to population growth and new consumption trends that characterize society. This paper proposes an artificial neural network (ANN) approach using feedforward nonlinear autoregressive network with exogenous inputs (NARX) to predict annual solid waste generation in relation to demographic and economic variables like population number, gross domestic product, electricity demand per capita and employment and unemployment numbers. In addition, variable selection procedures are also developed to select a significant explanatory variable. The model evaluation was performed using coefficient of determination (R(2)) and mean square error (MSE). The optimum model that produced the lowest testing MSE (2.46) and the highest R(2) (0.97) had three inputs (gross domestic product, population and employment), eight neurons and one lag in the hidden layer, and used Fletcher-Powell's conjugate gradient as the training algorithm.

  10. Melter Throughput Enhancements for High-Iron HLW

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Kruger, A. A.; Gan, Hoa; Joseph, Innocent

    2012-12-26

    This report describes work performed to develop and test new glass and feed formulations in order to increase glass melting rates in high waste loading glass formulations for HLW with high concentrations of iron. Testing was designed to identify glass and melter feed formulations that optimize waste loading and waste processing rate while meeting all processing and product quality requirements. The work included preparation and characterization of crucible melts to assess melt rate using a vertical gradient furnace system and to develop new formulations with enhanced melt rate. Testing evaluated the effects of waste loading on glass properties and themore » maximum waste loading that can be achieved. The results from crucible-scale testing supported subsequent DuraMelter 100 (DM100) tests designed to examine the effects of enhanced glass and feed formulations on waste processing rate and product quality. The DM100 was selected as the platform for these tests due to its extensive previous use in processing rate determination for various HLW streams and glass compositions.« less

  11. 40 CFR 194.24 - Waste characterization.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... system. (e) Waste may be emplaced in the disposal system only if the emplaced components of such waste... 40 Protection of Environment 26 2012-07-01 2011-07-01 true Waste characterization. 194.24 Section... PROGRAMS CRITERIA FOR THE CERTIFICATION AND RE-CERTIFICATION OF THE WASTE ISOLATION PILOT PLANT'S...

  12. 40 CFR 194.24 - Waste characterization.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... system. (e) Waste may be emplaced in the disposal system only if the emplaced components of such waste... 40 Protection of Environment 26 2013-07-01 2013-07-01 false Waste characterization. 194.24 Section... PROGRAMS CRITERIA FOR THE CERTIFICATION AND RE-CERTIFICATION OF THE WASTE ISOLATION PILOT PLANT'S...

  13. 40 CFR 194.24 - Waste characterization.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... system. (e) Waste may be emplaced in the disposal system only if the emplaced components of such waste... 40 Protection of Environment 25 2011-07-01 2011-07-01 false Waste characterization. 194.24 Section... PROGRAMS CRITERIA FOR THE CERTIFICATION AND RE-CERTIFICATION OF THE WASTE ISOLATION PILOT PLANT'S...

  14. 40 CFR 194.24 - Waste characterization.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... system. (e) Waste may be emplaced in the disposal system only if the emplaced components of such waste... 40 Protection of Environment 25 2014-07-01 2014-07-01 false Waste characterization. 194.24 Section... PROGRAMS CRITERIA FOR THE CERTIFICATION AND RE-CERTIFICATION OF THE WASTE ISOLATION PILOT PLANT'S...

  15. Advanced technologies for maintenance of electrical systems and equipment at the Savannah River Site Defense Waste Processing Facility

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Husler, R.O.; Weir, T.J.

    1991-01-01

    An enhanced maintenance program is being established to characterize and monitor cables, components, and process response at the Savannah River Site, Defense Waste Processing Facility. This facility was designed and constructed to immobilize the radioactive waste currently stored in underground storage tanks and is expected to begin operation in 1993. The plant is initiating the program to baseline and monitor instrument and control (I C) and electrical equipment, remote process equipment, embedded instrument and control cables, and in-cell jumper cables used in the facility. This program is based on the electronic characterization and diagnostic (ECAD) system which was modified tomore » include process response analysis and to meet rigid Department of Energy equipment requirements. The system consists of computer-automated, state-of-the-art electronics. The data that are gathered are stored in a computerized database for analysis, trending, and troubleshooting. It is anticipated that the data which are gathered and trended will aid in life extension for the facility.« less

  16. Advanced technologies for maintenance of electrical systems and equipment at the Savannah River Site Defense Waste Processing Facility

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Husler, R.O.; Weir, T.J.

    1991-12-31

    An enhanced maintenance program is being established to characterize and monitor cables, components, and process response at the Savannah River Site, Defense Waste Processing Facility. This facility was designed and constructed to immobilize the radioactive waste currently stored in underground storage tanks and is expected to begin operation in 1993. The plant is initiating the program to baseline and monitor instrument and control (I&C) and electrical equipment, remote process equipment, embedded instrument and control cables, and in-cell jumper cables used in the facility. This program is based on the electronic characterization and diagnostic (ECAD) system which was modified to includemore » process response analysis and to meet rigid Department of Energy equipment requirements. The system consists of computer-automated, state-of-the-art electronics. The data that are gathered are stored in a computerized database for analysis, trending, and troubleshooting. It is anticipated that the data which are gathered and trended will aid in life extension for the facility.« less

  17. Tilapia-waste flour as a natural nutritional replacer for bread: A consumer perspective.

    PubMed

    Monteiro, Maria Lúcia G; Mársico, Eliane T; Soares Junior, Manoel S; Deliza, Rosires; de Oliveira, Denize C R; Conte-Junior, Carlos A

    2018-01-01

    Six bread formulations with different levels of tilapia-waste flour (BTF0%, BTF2.5%, BTF5%, BTF10%, BTF15%, and BTF20%) were analyzed for nutritional composition and sensory characterization. Tilapia-waste flour (TF) increased (P < 0.05) the lipid, protein and ash contents, and decreased (P < 0.05) the levels of carbohydrates and total dietary fiber. BTF0%, BTF2.5% and BTF5% received the highest (P < 0.05) scores for acceptance and preference. Despite this apparent consumer preference for low or no levels, TF can be added to bread at levels below 12.17% (P < 0.05) without triggering consumer rejection. TF changed (P < 0.05) the sensory characterization of bread because of a disagreeable flavor, aroma, and texture; however, airy appearance, sticky in the teeth and cream color did not influence the overall liking. TF at 5% enhanced the nutritional value while maintaining acceptable sensory scores for bread, constituting a potential strategy to satisfy consumer and industry requirements.

  18. Tilapia-waste flour as a natural nutritional replacer for bread: A consumer perspective

    PubMed Central

    Mársico, Eliane T.; Soares Junior, Manoel S.; Deliza, Rosires; de Oliveira, Denize C. R.; Conte-Junior, Carlos A.

    2018-01-01

    Six bread formulations with different levels of tilapia-waste flour (BTF0%, BTF2.5%, BTF5%, BTF10%, BTF15%, and BTF20%) were analyzed for nutritional composition and sensory characterization. Tilapia-waste flour (TF) increased (P < 0.05) the lipid, protein and ash contents, and decreased (P < 0.05) the levels of carbohydrates and total dietary fiber. BTF0%, BTF2.5% and BTF5% received the highest (P < 0.05) scores for acceptance and preference. Despite this apparent consumer preference for low or no levels, TF can be added to bread at levels below 12.17% (P < 0.05) without triggering consumer rejection. TF changed (P < 0.05) the sensory characterization of bread because of a disagreeable flavor, aroma, and texture; however, airy appearance, sticky in the teeth and cream color did not influence the overall liking. TF at 5% enhanced the nutritional value while maintaining acceptable sensory scores for bread, constituting a potential strategy to satisfy consumer and industry requirements. PMID:29723283

  19. P losses in soil columns amended with compost and digestate from municipal solid wastes

    NASA Astrophysics Data System (ADS)

    García-Albacete, Marta; Cartagena, M. Carmen

    2013-04-01

    Sludge's, manures and compost applied to agricultural soils in high quantities and long-term application to increase crop productivity, result in accumulation of soil phosphorous (P). Soluble P is directly available to algae (Sonzogni et al., 1982) and thus particularly relevant to water quality degradation. Transport of P from agricultural soils to surface waters has been linked to eutrophication in fresh water and estuaries (Sharpley and Lemunyon, 1998). Almost 50% of stored water in Spain is degraded by eutrophication processes that cause the proliferation of algae and other organisms and a decrease in oxygen content (Environmental Profile of Spain 2005). Fertilizers and biodegradable wastes application rates in agriculture are based on nitrogen requirements. This results in a P supply that is in excess of crops needs since the ratio of P to N in waste use to be greater than required by plants (Smith, 1995). While surface runoff is an important pathway of phosphorus losses from agricultural lands, significant losses can also occur via leaching thought soils. Leaching tests are important for assessing the risk of release of potential pollutants from biodegradable wastes into groundwater or surface water. Percolation tests also get information about the interaction of organic waste with soils. The study was conducted according to the percolation leaching test CEN/TS 14405 "Characterization of waste-Leaching behavior test- Up-flow percolation test" with three different soils mixed with organic wastes from msw (compost and digestato) and an inorganic fertilizer (NaH2PO4). Each soil was amended with the P sources at rates of 100 kg P ha-1. Leachates were collected and analyzed for each column for dissolved reactive P by inductively coupled plasma atomic emission spectroscopy (ICP) following USEPA Method 3050A digestion (USEPA, 1995). The fact that P sorption capacity (Xmax, PSI) of the soils was determined using Langmuiŕs isotherms and the P forms from organic wastes were extensively characterized allows leaching data could be interpreted on the basis of P-sources chemical properties.

  20. Radiological Characterization Methodology of INEEL Stored RH-TRU Waste from ANL-E

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Rajiv N. Bhatt

    2003-02-01

    An Acceptable Knowledge (AK)-based radiological characterization methodology is being developed for RH TRU waste generated from ANL-E hot cell operations performed on fuel elements irradiated in the EBR-II reactor. The methodology relies on AK for composition of the fresh fuel elements, their irradiation history, and the waste generation and collection processes. Radiological characterization of the waste involves the estimates of the quantities of significant fission products and transuranic isotopes in the waste. Methods based on reactor and physics principles are used to achieve these estimates. Because of the availability of AK and the robustness of the calculation methods, the AK-basedmore » characterization methodology offers a superior alternative to traditional waste assay techniques. Using this methodology, it is shown that the radiological parameters of a test batch of ANL-E waste is well within the proposed WIPP Waste Acceptance Criteria limits.« less

  1. Radiological Characterization Methodology for INEEL-Stored Remote-Handled Transuranic (RH TRU) Waste from Argonne National Laboratory-East

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Kuan, P.; Bhatt, R.N.

    2003-01-14

    An Acceptable Knowledge (AK)-based radiological characterization methodology is being developed for RH TRU waste generated from ANL-E hot cell operations performed on fuel elements irradiated in the EBR-II reactor. The methodology relies on AK for composition of the fresh fuel elements, their irradiation history, and the waste generation and collection processes. Radiological characterization of the waste involves the estimates of the quantities of significant fission products and transuranic isotopes in the waste. Methods based on reactor and physics principles are used to achieve these estimates. Because of the availability of AK and the robustness of the calculation methods, the AK-basedmore » characterization methodology offers a superior alternative to traditional waste assay techniques. Using the methodology, it is shown that the radiological parameters of a test batch of ANL-E waste is well within the proposed WIPP Waste Acceptance Criteria limits.« less

  2. ENDOCRINE DISRUPTING CHEMICAL EMISSIONS FROM COMBUSTION SOURCES: DIESEL PARTICULATE EMISSIONS AND DOMESTIC WASTE OPEN BURN EMISSIONS

    EPA Science Inventory

    Emissions of endocrine disrupting chemicals (EDCs) from combustion sources are poorly characterized due to the large number of compounds present in the emissions, the complexity of the analytical separations required, and the uncertainty regarding identification of chemicals with...

  3. 40 CFR 191.11 - Applicability.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... required to be characterized under section 113(a) of Public Law 97-425, 96 Stat. 2201. [50 FR 38084, Sept... ENVIRONMENTAL RADIATION PROTECTION STANDARDS FOR MANAGEMENT AND DISPOSAL OF SPENT NUCLEAR FUEL, HIGH-LEVEL AND TRANSURANIC RADIOACTIVE WASTES Environmental Standards for Disposal § 191.11 Applicability. (a) This subpart...

  4. Fractionation study in bioleached metallurgy wastes using six-step sequential extraction.

    PubMed

    Krasnodebska-Ostrega, Beata; Pałdyna, Joanna; Kowalska, Joanna; Jedynak, Łukasz; Golimowski, Jerzy

    2009-08-15

    The stored metallurgy wastes contain residues from ore processing operations that are characterized by relatively high concentrations of heavy metals. The bioleaching process makes use of bacteria to recover elements from industrial wastes and to decrease potential risk of environmental contamination. Wastes were treated by solutions containing bacteria. In this work, the optimized six-stage sequential extraction procedure was applied for the fractionation of Ni, Cr, Fe, Mn, Cu and Zn in iron-nickel metallurgy wastes deposited in Southern Poland (Szklary). Fractionation and total concentrations of elements in wastes before and after various bioleaching treatments were studied. Analyses of the extracts were performed by ICP-MS and FAAS. To achieve the most effective bioleaching of Zn, Cr, Ni, Cu, Mn, Fe the usage of both autotrophic and heterotrophic bacteria in sequence, combined with flushing of the residue after bioleaching is required. 80-100% of total metal concentrations were mobilized after the proposed treatment. Wastes treated according to this procedure could be deposited without any risk of environmental contamination and additionally the metals could be recovered for industrial purposes.

  5. Listed waste determination report. Environmental characterization

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Not Available

    1993-06-01

    On September 23, 1988, the US Environmental Protection Agency (EPA) published a notice clarifying interim status requirements for the management of radioactive mixed waste thereby subjecting the Idaho National Engineering Laboratory (INEL) and other applicable Department of Energy (DOE) sites to regulation under the Resource Conservation and Recovery Act (RCRA). Therefore, the DOE was required to submit a Part A Permit application for each treatment, storage, and disposal (TSD) unit within the INEL, defining the waste codes and processes to be regulated under RCRA. The September 1990 revised Part A Permit application, that was approved by the State of Idahomore » identified 101 potential acute and toxic hazardous waste codes (F-, P-, and U- listed wastes according to 40 CFR 261.31 and 40 CFR 261.33) for some TSD units at the Idaho Chemical Processing Plant. Most of these waste were assumed to have been introduced into the High-level Liquid Waste TSD units via laboratory drains connected to the Process Equipment Waste (PEW) evaporator (PEW system). At that time, a detailed and systematic evaluation of hazardous chemical use and disposal practices had not been conducted to determine if F-, P-, or Unlisted waste had been disposed to the PEW system. The purpose of this investigation was to perform a systematic and detailed evaluation of the use and disposal of the 101 F-, P-, and Unlisted chemicals found in the approved September 1990 Part A Permit application. This investigation was aimed at determining which listed wastes, as defined in 40 CFR 261.31 (F-listed) and 261.33 (P & Unlisted) were discharged to the PEW system. Results of this investigation will be used to support revisions to the RCRA Part A Permit application.« less

  6. Packaging, Transportation and Recycling of NPP Condenser Modules - 12262

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Polley, G.M.

    2012-07-01

    Perma-Fix was awarded contract from Energy Northwest for the packaging, transportation and disposition of the condenser modules, water boxes and miscellaneous metal, combustibles and water generated during the 2011 condenser replacement outage at the Columbia Generating Station. The work scope was to package the water boxes and condenser modules as they were removed from the facility and transfer them to the Perma-Fix Northwest facility for processing, recycle of metals and disposition. The condenser components were oversized and overweight (the condenser modules weighed ∼102,058 kg [225,000 lb]) which required special equipment for loading and transport. Additional debris waste was packaged inmore » inter-modals and IP-1 boxes for transport. A waste management plan was developed to minimize the generation of virtually any waste requiring landfill disposal. The Perma-Fix Northwest facility was modified to accommodate the ∼15 m [50-ft] long condenser modules and equipment was designed and manufactured to complete the disassembly, decontamination and release survey. The condenser modules are currently undergoing processing for free release to a local metal recycler. Over three millions pounds of metal will be recycled and over 95% of the waste generated during this outage will not require land disposal. There were several elements of this project that needed to be addressed during the preparation for this outage and the subsequent packaging, transportation and processing. - Staffing the project to support 24/7 generation of large components and other wastes. - The design and manufacture of the soft-sided shipping containers for the condenser modules that measured ∼15 m X 4 m X 3 m [50 ft X 13 ft X 10 ft] and weighed ∼102,058 kg [225,000 lbs] - Developing a methodology for loading the modules into the shipping containers. - Obtaining a transport vehicle for the modules. - Designing and modifying the processing facility. - Movement of the modules at the processing facility. If any of these issues were not adequately resolved prior to the start of the outage, costly delays would result and the re-start of the power plant could be impacted. The main focus of this project was to find successful methods for keeping this material out of the landfills and preserving the natural resources. In addition, this operation provided a significant cost savings to the public utility by minimizing landfill disposal. The onsite portion of the project has been completed without impact to the overall outage schedule. By the date of presentation, the majority of the waste from the condenser replacement project will have been processed and recycled. The goals for this project included helping Energy Northwest maintain the outage schedule, package and characterize waste compliantly, perform transportation activities in compliance with 49CFR (Ref-1), and minimize the waste disposal volume. During this condenser replacement project, over three millions pounds of waste was generated, packaged, characterized and transported without injury or incident. It is anticipated that 95% of the waste generated during this project will not require landfill disposal. All of the waste is scheduled to be processed, decontaminated and recycled by June of 2012. (authors)« less

  7. Uncertainty quantification applied to the radiological characterization of radioactive waste.

    PubMed

    Zaffora, B; Magistris, M; Saporta, G; Chevalier, J-P

    2017-09-01

    This paper describes the process adopted at the European Organization for Nuclear Research (CERN) to quantify uncertainties affecting the characterization of very-low-level radioactive waste. Radioactive waste is a by-product of the operation of high-energy particle accelerators. Radioactive waste must be characterized to ensure its safe disposal in final repositories. Characterizing radioactive waste means establishing the list of radionuclides together with their activities. The estimated activity levels are compared to the limits given by the national authority of the waste disposal. The quantification of the uncertainty affecting the concentration of the radionuclides is therefore essential to estimate the acceptability of the waste in the final repository but also to control the sorting, volume reduction and packaging phases of the characterization process. The characterization method consists of estimating the activity of produced radionuclides either by experimental methods or statistical approaches. The uncertainties are estimated using classical statistical methods and uncertainty propagation. A mixed multivariate random vector is built to generate random input parameters for the activity calculations. The random vector is a robust tool to account for the unknown radiological history of legacy waste. This analytical technique is also particularly useful to generate random chemical compositions of materials when the trace element concentrations are not available or cannot be measured. The methodology was validated using a waste population of legacy copper activated at CERN. The methodology introduced here represents a first approach for the uncertainty quantification (UQ) of the characterization process of waste produced at particle accelerators. Copyright © 2017 Elsevier Ltd. All rights reserved.

  8. Solid waste generation and characterization in the University of Lagos for a sustainable waste management.

    PubMed

    Adeniran, A E; Nubi, A T; Adelopo, A O

    2017-09-01

    Waste characterization is the first step to any successful waste management policy. In this paper, the characterization and the trend of solid waste generated in University of Lagos, Nigeria was carried out using ASTM D5231-92 and Resource Conservation Reservation Authority RCRA Waste Sampling Draft Technical Guidance methods. The recyclable potential of the waste is very high constituting about 75% of the total waste generated. The estimated average daily solid waste generation in Unilag Akoka campus was estimated to be 32.2tons. The solid waste characterization was found to be: polythene bags 24% (7.73tons/day), paper 15% (4.83tons/day), organic matters 15%, (4.83tons/day), plastic 9% (2.90tons/day), inert materials 8% (2.58tons/day), sanitary 7% (2.25tons/day), textile 7% (2.25tons/day), others 6% (1.93tons/day), leather 4% (1.29tons/day) metals 3% (0.97tons/day), glass 2% (0.64tons/day) and e-waste 0% (0.0tons/day). The volume and distribution of polythene bags generated on campus had a positive significant statistical correlation with the distribution of commercial and academic structures on campus. Waste management options to optimize reuse, recycling and reduce waste generation were discussed. Copyright © 2017 Elsevier Ltd. All rights reserved.

  9. I-NERI-2007-004-K, DEVELOPMENT AND CHARACTERIZATION OF NEW HIGH-LEVEL WASTE FORMS FOR ACHIEVING WASTE MINIMIZATION FROM PYROPROCESSING

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    S.M. Frank

    Work describe in this report represents the final year activities for the 3-year International Nuclear Energy Research Initiative (I-NERI) project: Development and Characterization of New High-Level Waste Forms for Achieving Waste Minimization from Pyroprocessing. Used electrorefiner salt that contained actinide chlorides and was highly loaded with surrogate fission products was processed into three candidate waste forms. The first waste form, a high-loaded ceramic waste form is a variant to the CWF produced during the treatment of Experimental Breeder Reactor-II used fuel at the Idaho National Laboratory (INL). The two other waste forms were developed by researchers at the Korean Atomicmore » Energy Research Institute (KAERI). These materials are based on a silica-alumina-phosphate matrix and a zinc/titanium oxide matrix. The proposed waste forms, and the processes to fabricate them, were designed to immobilize spent electrorefiner chloride salts containing alkali, alkaline earth, lanthanide, and halide fission products that accumulate in the salt during the processing of used nuclear fuel. This aspect of the I-NERI project was to demonstrate 'hot cell' fabrication and characterization of the proposed waste forms. The outline of the report includes the processing of the spent electrorefiner salt and the fabrication of each of the three waste forms. Also described is the characterization of the waste forms, and chemical durability testing of the material. While waste form fabrication and sample preparation for characterization must be accomplished in a radiological hot cell facility due to hazardous radioactivity levels, smaller quantities of each waste form were removed from the hot cell to perform various analyses. Characterization included density measurement, elemental analysis, x-ray diffraction, scanning electron microscopy and the Product Consistency Test, which is a leaching method to measure chemical durability. Favorable results from this demonstration project will provide additional options for fission product immobilization and waste management associated the electrochemical/pyrometallurgical processing of used nuclear fuel.« less

  10. Quality control by HyperSpectral Imaging (HSI) in solid waste recycling: logics, algorithms and procedures

    NASA Astrophysics Data System (ADS)

    Bonifazi, Giuseppe; Serranti, Silvia

    2014-03-01

    In secondary raw materials and recycling sectors, the products quality represents, more and more, the key issue to pursuit in order to be competitive in a more and more demanding market, where quality standards and products certification play a preheminent role. These goals assume particular importance when recycling actions are applied. Recovered products, resulting from waste materials, and/or dismissed products processing, are, in fact, always seen with a certain suspect. An adequate response of the industry to the market can only be given through the utilization of equipment and procedures ensuring pure, high-quality production, and efficient work and cost. All these goals can be reached adopting not only more efficient equipment and layouts, but also introducing new processing logics able to realize a full control of the handled material flow streams fulfilling, at the same time, i) an easy management of the procedures, ii) an efficient use of the energy, iii) the definition and set up of reliable and robust procedures, iv) the possibility to implement network connectivity capabilities finalized to a remote monitoring and control of the processes and v) a full data storage, analysis and retrieving. Furthermore the ongoing legislation and regulation require the implementation of recycling infrastructure characterised by high resources efficiency and low environmental impacts, both aspects being strongly linked to the waste materials and/or dismissed products original characteristics. For these reasons an optimal recycling infrastructure design primarily requires a full knowledge of the characteristics of the input waste. What previously outlined requires the introduction of a new important concept to apply in solid waste recycling, the recycling-oriented characterization, that is the set of actions addressed to strategically determine selected attributes, in order to get goaloriented data on waste for the development, implementation or improvement of recycling strategies. The problems arising when suitable HyperSpectral Imaging (HSI) based procedures have to be developed and implemented to solid waste products characterization, in order to define time efficient compression and interpretation techniques, are thus analyzed and discussed in the following. Particular attention was also addressed to define an integrated hardware and software (HW and SW) platform able to perform a non-intrusive, non-contact and real-time analysis and embedding a core of analytical logics and procedures to utilize both at laboratory and industrial scale. Several case studies, referred to waste plastics products, are presented and discussed.

  11. Closure Plan for the Area 5 Radioactive Waste Management Site at the Nevada Test Site

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    NSTec Environmental Management

    The Area 5 Radioactive Waste Management Site (RMWS) at the Nevada Test Site (NTS) is managed and operated by National Security Technologies, LLC (NSTec), for the U.S. Department of Energy (DOE), National Nuclear Security Administration Nevada Site Office (NNSA/NSO). This document is the first update of the preliminary closure plan for the Area 5 RWMS at the NTS that was presented in the Integrated Closure and Monitoring Plan (DOE, 2005a). The major updates to the plan include a new closure schedule, updated closure inventory, updated site and facility characterization data, the Title II engineering cover design, and the closure processmore » for the 92-Acre Area of the RWMS. The format and content of this site-specific plan follows the Format and Content Guide for U.S. Department of Energy Low-Level Waste Disposal Facility Closure Plans (DOE, 1999a). This interim closure plan meets closure and post-closure monitoring requirements of the order DOE O 435.1, manual DOE M 435.1-1, Title 40 Code of Federal Regulations (CFR) Part 191, 40 CFR 265, Nevada Administrative Code (NAC) 444.743, and Resource Conservation and Recovery Act (RCRA) requirements as incorporated into NAC 444.8632. The Area 5 RWMS accepts primarily packaged low-level waste (LLW), low-level mixed waste (LLMW), and asbestiform low-level waste (ALLW) for disposal in excavated disposal cells.« less

  12. Sewage sludge, compost and other representative organic wastes as agricultural soil amendments: Benefits versus limiting factors.

    PubMed

    Alvarenga, Paula; Mourinha, Clarisse; Farto, Márcia; Santos, Teresa; Palma, Patrícia; Sengo, Joana; Morais, Marie-Christine; Cunha-Queda, Cristina

    2015-06-01

    Nine different samples of sewage sludges, composts and other representative organic wastes, with potential interest to be used as agricultural soil amendments, were characterized: municipal sewage sludge (SS1 and SS2), agro industrial sludge (AIS), municipal slaughterhouse sludge (MSS), mixed municipal solid waste compost (MMSWC), agricultural wastes compost (AWC), compost produced from agricultural wastes and sewage sludge (AWSSC), pig slurry digestate (PSD) and paper mill wastes (PMW). The characterization was made considering their: (i) physicochemical parameters, (ii) total and bioavailable heavy metals (Cd, Cr, Cu, Ni, Pb, Zn and Hg), (iii) organic contaminants, (iv) pathogenic microorganisms and (v) stability and phytotoxicity indicators. All the sludges, municipal or other, comply with the requirements of the legislation regarding the possibility of their application to agricultural soil (with the exception of SS2, due to its pathogenic microorganisms content), with a content of organic matter and nutrients that make them interesting to be applied to soil. The composts presented, in general, some constraints regarding their application to soil, and their impairment was due to the existence of heavy metal concentrations exceeding the proposed limit of the draft European legislation. As a consequence, with the exception of AWSSC, most compost samples were not able to meet these quality criteria, which are more conservative for compost than for sewage sludge. From the results, the composting of sewage sludge is recommended as a way to turn a less stabilized waste into a material that is no longer classified as a waste and, judging by the results of this work, with lower heavy metal content than the other composted materials, and without sanitation problems. Copyright © 2015 Elsevier Ltd. All rights reserved.

  13. Opportunities for Cost Effective Disposal of Radioactively Contaminated Solid Waste on the Oak Ridge Reservation, Oak Ridge, TN - 13045

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    DeMonia, Brian; Dunning, Don; Hampshire John

    2013-07-01

    Department of Energy (DOE) requirements for the release of non-real property, including solid waste, containing low levels of residual radioactive materials are specified in DOE Order 458.1 and associated guidance. Authorized limits have been approved under the requirements of DOE Order 5400.5, predecessor to DOE Order 458.1, to permit disposal of solid waste containing low levels of residual radioactive materials at solid waste landfills located within the DOE Oak Ridge Reservation (ORR). Specifically, volumetric concentration limits for disposal of solid waste at Industrial Landfill V and at Construction/Demolition Landfill VII were established in 2003 and 2007, respectively, based on themore » requirements in effect at that time, which included: an evaluation to ensure that radiation doses to the public would not exceed 25 mrem/year and would be as low as reasonably achievable (ALARA), with a goal of a few mrem/year or less (in fact, these authorized limits actually were derived to meet a dose constraint of 1 mrem/year); an evaluation of compliance with groundwater protection requirements; and reasonable assurance that the proposed disposal is not likely to result in a future requirement for remediation of the landfill. Prior to approval as DOE authorized limits, these volumetric concentration limits were coordinated with the Tennessee Department of Environment and Conservation (TDEC) and documented in a Memorandum of Understanding (MOU) between the TDEC Division of Radiological Health and the TDEC Division of Solid Waste Management. These limits apply to the disposal of soil and debris waste generated from construction, maintenance, environmental restoration, and decontamination and decommissioning (D and D) activities on the DOE Oak Ridge Reservation. The approved site-specific authorized limits were incorporated in the URS/CH2M Oak Ridge LLC (UCOR) waste profile system that authorizes disposal of special wastes at either of the RCRA Subtitle D landfills. However, a recent DOE assessment found that implementation of the site-specific authorized limits for volumetrically contaminated waste was potentially limited due in part to confusion regarding the applicability of volumetric concentration limits and/or surface activity limits to specific wastes. This paper describes recent efforts to update the authorized limits for Industrial Landfill V and Construction/Demolition Landfill VII and to improve the procedures for implementation of these criteria. The approved authorized limits have been evaluated and confirmed to meet the current requirements of DOE Order 458.1, which superseded DOE Order 5400.5 in February 2011. In addition, volumetric concentration limits have been developed for additional radionuclides, and site-specific authorized limits for wastes with surface contamination have been developed. Implementing procedures have been revised to clarify the applicability of volumetric concentration limits and surface activity limits, and to allow the use of non-destructive waste characterization methods. These changes have been designed to promote improved utilization of available disposal capacity of the onsite disposal facilities within the DOE Oak Ridge Reservation. In addition, these changes serve to bring the waste acceptance requirements at these DOE onsite landfills into greater consistency with the requirements for commercial/ public landfills under the TDEC Bulk Survey for Release (BSFR) program, including two public RCRA Subtitle D landfills in close proximity to the DOE Oak Ridge Reservation. (authors)« less

  14. Handling Radioactive Waste from the Proton Accelerator Facility at the Paul Scherrer Institut (PSI) - Always Surprising? - 13320

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Mueth, Joachim

    The Paul Scherrer Institut (PSI) is the largest national research centre in Switzerland. Its multidisciplinary research is dedicated to a wide field in natural science and technology as well as particle physics. In this context, PSI is operating, amongst others, a large proton accelerator facility since more than 30 years. In two cyclotrons, protons are accelerated to high speeds and then guided along roughly 100 m of beam line to three different target stations to produce secondary particles like mesons and neutrons for experiments and a separately beam line for UCN. The protons induce spallation processes in the target materials,more » and also at other beam loss points along the way, with emission of protons, neutrons, hydrogen, tritium, helium, heavier fragments and fission processes. In particular the produced neutrons, due to their large penetration depth, will then interact also with the surrounding materials. These interactions of radiation with matter lead to activation and partly to contamination of machine components and the surrounding infrastructures. Maintenance, operation and decommissioning of installations generate inevitably substantial amounts of radioactive operational and dismantling waste like targets, magnets, collimators, shielding (concrete, steel) and of course secondary waste. To achieve an optimal waste management strategy for interim storage or final disposal, radioactive waste has to be characterized, sorted and treated. This strategy is based on radiation protection demands, raw waste properties (size, material, etc.), and requirements to reduce the volume of waste, mainly for legal and economical reasons. In addition, the radiological limitations for transportation of the waste packages to a future disposal site have to be taken into account, as well as special regulatory demands. The characterization is a task of the waste producer. The conditioning processes and quality checks for radioactive waste packages are part of an accredited waste management process of PSI, especially of the Section Dismantling and Waste Management. Strictly proven and accepted methods needed to be developed and enhanced for safe treatment, transport, conditioning and storage. But in the field of waste from research activities, individual and new solutions have to be found in an increasingly growing administrative environment. Furthermore, a wide variety of components, with a really large inventory of radioactive nuclides, has to be handled. And there are always surprising challenges concerning the unusual materials or the nuclide inventory. In case of the operational and dismantling radioactive accelerator waste, the existing conditioning methods are in the process of a continuous enhancement - technically and administratively. The existing authorized specifications of conditioning processes have to be extended to optimize and fully describe the treatment of the inevitably occurring radioactive waste from the accelerator facility. Additional challenges are the changes with time concerning the legal and regulatory requirements - or do we have to consider it as business as usual? This paper gives an overview of the current practices in radioactive waste management and decommissioning of the existing operational accelerator waste. (authors)« less

  15. Characterization of spacecraft humidity condensate

    NASA Technical Reports Server (NTRS)

    Muckle, Susan; Schultz, John R.; Sauer, Richard L.

    1994-01-01

    When construction of Space Station Freedom reaches the Permanent Manned Capability (PMC) stage, the Water Recovery and Management Subsystem will be fully operational such that (distilled) urine, spent hygiene water, and humidity condensate will be reclaimed to provide water of potable quality. The reclamation technologies currently baselined to process these waste waters include adsorption, ion exchange, catalytic oxidation, and disinfection. To ensure that the baseline technologies will be able to effectively remove those compounds presenting a health risk to the crew, the National Research Council has recommended that additional information be gathered on specific contaminants in waste waters representative of those to be encountered on the Space Station. With the application of new analytical methods and the analysis of waste water samples more representative of the Space Station environment, advances in the identification of the specific contaminants continue to be made. Efforts by the Water and Food Analytical Laboratory at JSC were successful in enlarging the database of contaminants in humidity condensate. These efforts have not only included the chemical characterization of condensate generated during ground-based studies, but most significantly the characterization of cabin and Spacelab condensate generated during Shuttle missions. The analytical results presented in this paper will be used to show how the composition of condensate varies amongst enclosed environments and thus the importance of collecting condensate from an environment close to that of the proposed Space Station. Although advances were made in the characterization of space condensate, complete characterization, particularly of the organics, requires further development of analytical methods.

  16. Treatment of copper industry waste and production of sintered glass-ceramic.

    PubMed

    Coruh, Semra; Ergun, Osman Nuri; Cheng, Ta-Wui

    2006-06-01

    Copper waste is iron-rich hazardous waste containing heavy metals such as Cu, Zn, Co, Pb. The results of leaching tests show that the concentration of these elements exceeds the Turkish and EPA regulatory limits. Consequently, this waste cannot be disposed of in its present form and therefore requires treatment to stabilize it or make it inert prior to disposal. Vitrification was selected as the technology for the treatment of the toxic waste under investigation. During the vitrification process significant amounts of the toxic organic and inorganic chemical compounds could be destroyed, and at the same time, the metal species are immobilized as they become an integral part of the glass matrix. The copper flotation waste samples used in this research were obtained from the Black Sea Copper Works of Samsun, Turkey. The samples were vitrified after being mixed with other inorganic waste and materials. The copper flotation waste and their glass-ceramic products were characterized by X-ray analysis (XRD), scanning electron microscopy and by the toxicity characteristic leaching procedure test. The products showed very good chemical durability. The glass-ceramics fabricated at 850 degrees C/2 h have a large application potential especially as construction and building materials.

  17. Savannah River Site Operating Experience with Transuranic (TRU) Waste Retrieval

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Stone, K.A.; Milner, T.N.

    2006-07-01

    Drums of TRU Waste have been stored at the Savannah River Site (SRS) on concrete pads from the 1970's through the 1980's. These drums were subsequently covered with tarpaulins and then mounded over with dirt. Between 1996 and 2000 SRS ran a successful retrieval campaign and removed some 8,800 drums, which were then available for venting and characterization for WIPP disposal. Additionally, a number of TRU Waste drums, which were higher in activity, were stored in concrete culverts, as required by the Safety Analysis for the Facility. Retrieval of drums from these culverts has been ongoing since 2002. This papermore » will describe the operating experience and lessons learned from the SRS retrieval activities. (authors)« less

  18. Managing previously disposed waste to today's standards

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Not Available

    1990-01-01

    A Radioactive Waste Management Complex (RWMC) was established at the Idaho National Engineering Laboratory (INEL) in 1952 for controlled disposal of radioactive waste generated at the INEL. Between 1954 and 1970 waste characterized by long lived, alpha emitting radionuclides from the Rocky Flats Plant was also buried at this site. Migration of radionuclides and other hazardous substances from the buried Migration of radionuclides and other hazardous substances from the buried waste has recently been detected. A Buried Waste Program (BWP) was established to manage cleanup of the buried waste. This program has four objectives: (1) determine contaminant sources, (2) determinemore » extent of contamination, (3) mitigate migration, and (4) recommend an alternative for long term management of the waste. Activities designed to meet these objectives have been under way since the inception of the program. The regulatory environment governing these activities is evolving. Pursuant to permitting activities under the Resource Conservation and Recovery Act (RCRA), the Department of Energy (DOE) and the Environmental Protection Agency (EPA) entered into a Consent Order Compliance Agreement (COCA) for cleanup of past practice disposal units at the INEL. Subsequent to identification of the RWMC as a release site, cleanup activities proceeded under dual regulatory coverage of RCRA and the Atomic Energy Act. DOE, EPA, and the State of Idaho are negotiating a RCRA/Comprehensive Environmental Response, Compensation, and Liability Act (CERCLA) Interagency Agreement (IAG) for management of waste disposal sites at the INEL as a result of the November 1989 listing of the INEL on the National Priority List (NPL). Decision making for selection of cleanup technology will be conducted under the CERCLA process supplemented as required to meet the requirements of the National Environmental Policy Act (NEPA). 7 figs.« less

  19. The Direct Path To WIPP - 12471

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Spoerner, M.T.; Burger, M.J.; Garcia, J.

    2012-07-01

    Sandia National Laboratories/New Mexico (SNL/NM), designated as a small quantity site (SQS) by the National TRU Program (NTP), generated contact-handled (CH) and remote-handled (RH) transuranic (TRU) waste primarily from the decontamination and clean-out of glove boxes at the Hot Cell Facility (HCF) at Technical Area (TA) V. All of the waste required repackaging, with the CH TRU waste being repackaged from late 2007 through 2011. Three shipments of CH were completed in October 2011, which de-inventoried SNL/NM's legacy TRU waste. In FY11, RH TRU waste was repackaged at the Auxiliary Hot Cell Facility (AHCF) located in TAV with the supportmore » of the Central Characterization Project (CCP). The waste was originally packaged in SNL/NM fabricated casks, cement or lead-lined 55-gallon drums, or 30-gallon drums. The AHCF is a small hot cell, with access only through a roof port which presented challenges for inserting and removing waste from the hot cell. The CCP provided visual examination operators (VEOs) to observe and document each waste item repackaged, removal of prohibited items, and radiological sampling. Dose-to-Curie measurements were calculated by CCP after a radiological report was prepared using scaling factors determined by the analysis of swipe samples. Finally, headspace gas samples were taken and sent to the Advanced Mixed Waste Treatment Project (AMWTP) for analysis. Despite the challenges, the RH waste is on track to be shipped to WIPP in early FY12. The processes used and procedures developed to conduct the repackaging operations, the issues identified and mitigated were challenging but the cooperation between SNL/NM and the Central Characterization Program (CCP) enabled SNL/NM to complete the repackaging and support the characterization and shipment. An inventory list, identification of the campaigns, discussion of the challenges and mitigations, and the final loading of the RH 72-B casks at TA-V for direct shipment to the Waste Isolation Pilot Plant (WIPP) will be discussed. Lessons learned from the RH campaigns are: - Some containers that were originally identified as HC-3 have been re-evaluated and became < HC-3 due to the conservative estimates made by the original generators - Operators at the AHCF were not accustomed to the detail required by the VE operators. However, they worked well together and the repackaging was completed ahead of schedule. - The AK was not always accurate as was demonstrated by the solid waste found in the drum during the first visit by EPA. That waste has since been determined to be low-level. - Two drums originally thought to be RH turned out to be CH and arrangement for RTR had to be made quickly. - Six of the original RH repacked drums became low level. - Lessons learned from the CH campaigns were helpful in avoiding many issues. The RH repackaging effort has been a success due to the expertise of the AHCF operators, supervisor, and manager, the conscientious attention to detail of the CCP VE operators, the experience of the CCP DTC and headspace gas sampling staff, and the guidance and support from CCP and CBFO. Sometimes schedules had to be adjusted, processes updated, and issues discussed, but the communication between CCP and SNL/NM was good. SNL/NM hopes to have the legacy RH TRU waste shipped off-site by early 2012. (authors)« less

  20. The contribution of multidimensional spatial analysis to a waste management policy: implementation of the ELECTRE method for characterizing transfer centers in the region of Oran

    NASA Astrophysics Data System (ADS)

    Saidi, A.; Trache, M. A.; Khelfi, M. F.

    2016-08-01

    The social and economic activity steadily growing in our cities creates a significant waste production in constantly evolving. The management of this waste is problematic because it is the center of many issues and interests. Indeed, any action or decision to the collection, transportation, treatment and disposal of waste should be considered in the economic, social, political and especially environmental aspect. A global Geomatic solution requires implementing a GIS with powerful multidimensional spatial analysis tools that support really waste management problem. Algeria has adopted a solution of waste landfill for all urban cities. In the Oran region, it exists three Centers Controlled landfill (CET) which the most important is that of Hassi-Bounif. This center currently meeting the needs of the region is unsustainable solution at the long-term because of its rapid saturation and its geographic location, which is still far from city centers (20-30 km) implying a negative impact on the vehicle park collecting such frequent breakdowns, the rapid degradation, slow delivery time and especially the high cost of the maintenance operation. This phenomenon is aggravated by the absence of real and actual initiatives targeting the recycling and recovery of waste, which makes the CET an endpoint for all types of waste. We present in this study, the use of the ELECTRE method (Multicriteria Analysis) integrated into a GIS to characterize the impact of the implementation of transfers centers at Oran region. The results of this study will accentuate the advantages of the activation of waste warehouse closer to the city, and relieving considerably the volume of transfer towards CET. The objective of our presentation is to show the leading role of the new Geomatics tools and the multidimensional spatial analysis in the apprehension of an environmental problem such the waste management and more generally in the urban management.

  1. DOE Office of Scientific and Technical Information (OSTI.GOV)

    Elicio, Andy U.

    My ERM 593 applied project will provide guidance for the Los Alamos National Laboratory Waste Stream Profile reviewer (i.e. RCRA reviewer) in regards to Reviewing and Approving a Waste Stream Profile in the Waste Compliance and Tracking System. The Waste Compliance and Tracking system is called WCATS. WCATS is a web-based application that “supports the generation, characterization, processing and shipment of LANL radioactive, hazardous, and industrial waste.” The LANL generator must characterize their waste via electronically by filling out a waste stream profile (WSP) in WCATS. Once this process is completed, the designated waste management coordinator (WMC) will perform amore » review of the waste stream profile to ensure the generator has completed their waste stream characterization in accordance with applicable state, federal and LANL directives particularly P930-1, “LANL Waste Acceptance Criteria,” and the “Waste Compliance and Tracking System User's Manual, MAN-5004, R2,” as applicable. My guidance/applied project will describe the purpose, scope, acronyms, definitions, responsibilities, assumptions and guidance for the WSP reviewer as it pertains to each panel and subpanel of a waste stream profile.« less

  2. Agricultural waste as a source for the production of silica nanoparticles.

    PubMed

    Vaibhav, Vineet; Vijayalakshmi, U; Roopan, S Mohana

    2015-03-15

    The major interest of the paper deals with the extraction of silica from four natural sources such as rice husk, bamboo leaves, sugarcane bagasse and groundnut shell. These waste materials in large quantities can create a serious environmental problem. Hence, there is a need to adopt proper strategy to reduce the waste. In the present investigation, all the waste materials are subjected to moisture removal in a hot plate and sintered at 900°C for 7 h. The sintered powder was treated with 1 M NaOH to form sodium silicate and then with 6M H2SO4 to precipitate silica. The prepared silica powders were characterized by FT-IR, XRD and SEM-EDAX analysis. The silica recovered from different sources was found to vary between 52% and 78%. Magnesium substituted silica was formed from the groundnut waste and further treatment is required to precipitate silica. Copyright © 2014 Elsevier B.V. All rights reserved.

  3. HEPA Filter Disposal Write-Up 10/19/16

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Loll, C.

    Process knowledge (PK) collection on HEPA filters is handled via the same process as other waste streams at LLNL. The Field technician or Characterization point of contact creates an information gathering document (IGD) in the IGD database, with input provided from the generator, and submits it for electronic approval. This document is essentially a waste generation profile, detailing the physical, chemical as well as radiological characteristics, and hazards, of a waste stream. It will typically contain a general, but sometimes detailed, description of the work processes which generated the waste. It will contain PK as well as radiological and industrialmore » hygiene analytical swipe results, and any other analytical or other supporting knowledge related to characterization. The IGD goes through an electronic approval process to formalize the characterization and to ensure the waste has an appropriate disposal path. The waste generator is responsible for providing initial process knowledge information, and approves the IGD before it routed to chemical and radiological waste characterization professionals. This is the standard characterization process for LLNL-generated HEPA Filters.« less

  4. Space augmentation of military high-level waste disposal

    NASA Technical Reports Server (NTRS)

    English, T.; Lees, L.; Divita, E.

    1979-01-01

    Space disposal of selected components of military high-level waste (HLW) is considered. This disposal option offers the promise of eliminating the long-lived radionuclides in military HLW from the earth. A space mission which meets the dual requirements of long-term orbital stability and a maximum of one space shuttle launch per week over a period of 20-40 years, is a heliocentric orbit about halfway between the orbits of earth and Venus. Space disposal of high-level radioactive waste is characterized by long-term predictability and short-term uncertainties which must be reduced to acceptably low levels. For example, failure of either the Orbit Transfer Vehicle after leaving low earth orbit, or the storable propellant stage failure at perihelion would leave the nuclear waste package in an unplanned and potentially unstable orbit. Since potential earth reencounter and subsequent burn-up in the earth's atmosphere is unacceptable, a deep space rendezvous, docking, and retrieval capability must be developed.

  5. Physical, Hydraulic, and Transport Properties of Sediments and Engineered Materials Associated with Hanford Immobilized Low-Activity Waste

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Rockhold, Mark L.; Zhang, Z. F.; Meyer, Philip D.

    2015-02-28

    Current plans for treatment and disposal of immobilized low-activity waste (ILAW) from Hanford’s underground waste storage tanks include vitrification and storage of the glass waste form in a nearsurface disposal facility. This Integrated Disposal Facility (IDF) is located in the 200 East Area of the Hanford Central Plateau. Performance assessment (PA) of the IDF requires numerical modeling of subsurface flow and reactive transport processes over very long periods (thousands of years). The models used to predict facility performance require parameters describing various physical, hydraulic, and transport properties. This report provides updated estimates of physical, hydraulic, and transport properties and parametersmore » for both near- and far-field materials, intended for use in future IDF PA modeling efforts. Previous work on physical and hydraulic property characterization for earlier IDF PA analyses is reviewed and summarized. For near-field materials, portions of this document and parameter estimates are taken from an earlier data package. For far-field materials, a critical review is provided of methodologies used in previous data packages. Alternative methods are described and associated parameters are provided.« less

  6. Evaluation of Low-Level Waste Disposal Receipt Data for Los Alamos National Laboratory Technical Area 54, Area G Disposal Facility - Fiscal Year 2011

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    French, Sean B.; Shuman, Robert

    2012-04-17

    The Los Alamos National Laboratory (LANL or the Laboratory) generates radioactive waste as a result of various activities. Operational or institutional waste is generated from a wide variety of research and development activities including nuclear weapons development, energy production, and medical research. Environmental restoration (ER), and decontamination and decommissioning (D and D) waste is generated as contaminated sites and facilities at LANL undergo cleanup or remediation. The majority of this waste is low-level radioactive waste (LLW) and is disposed of at the Technical Area 54 (TA-54), Area G disposal facility. U.S. Department of Energy (DOE) Order 435.1 (DOE, 2001) requiresmore » that radioactive waste be managed in a manner that protects public health and safety, and the environment. To comply with this order, DOE field sites must prepare and maintain site-specific radiological performance assessments for LLW disposal facilities that accept waste after September 26, 1988. Furthermore, sites are required to conduct composite analyses that account for the cumulative impacts of all waste that has been (or will be) disposed of at the facilities and other sources of radioactive material that may interact with the facilities. Revision 4 of the Area G performance assessment and composite analysis was issued in 2008 (LANL, 2008). These analyses estimate rates of radionuclide release from the waste disposed of at the facility, simulate the movement of radionuclides through the environment, and project potential radiation doses to humans for several on-site and off-site exposure scenarios. The assessments are based on existing site and disposal facility data and on assumptions about future rates and methods of waste disposal. The accuracy of the performance assessment and composite analysis depends upon the validity of the data used and assumptions made in conducting the analyses. If changes in these data and assumptions are significant, they may invalidate or call into question certain aspects of the analyses. For example, if the volumes and activities of waste disposed of during the remainder of the disposal facility's lifetime differ significantly from those projected, the doses projected by the analyses may no longer apply. DOE field sites are required to implement a performance assessment and composite analysis maintenance program. The purpose of this program is to ensure the continued applicability of the analyses through incremental improvement of the level of understanding of the disposal site and facility. Site personnel are required to conduct field and experimental work to reduce the uncertainty in the data and models used in the assessments. Furthermore, they are required to conduct periodic reviews of waste receipts, comparing them to projected waste disposal rates. The radiological inventory for Area G was updated in conjunction with Revision 4 of the performance assessment and composite analysis (Shuman, 2008). That effort used disposal records and other sources of information to estimate the quantities of radioactive waste that have been disposed of at Area G from 1959, the year the facility started receiving waste on a routine basis, through 2007. It also estimated the quantities of LLW that will require disposal from 2008 through 2044, the year in which it is assumed that disposal operations at Area G will cease. This report documents the fourth review of Area G disposal receipts since the inventory was updated and examines information for waste placed in the ground during fiscal years (FY) 2008 through 2011. The primary objective of the disposal receipt review is to ensure that the future waste inventory projections developed for the performance assessment and composite analysis are consistent with the actual types and quantities of waste being disposed of at Area G. Toward this end, the disposal data that are the subject of this review are used to update the future waste inventory projections for the disposal facility. These projections are compared to the future inventory projections that were developed for Revision 4 of the performance assessment and composite analysis. The approach used to characterize the FY 2008 through 2011 waste is generally the same as that used to characterize the inventory for the Revision 4 analyses (Shuman, 2008). This methodology is described in Section 2. The results of the disposal receipt review are presented in Section 3 and discussed in terms of their significance to the Area G analyses.« less

  7. Radionuclide Migration through Sediment and Concrete: 16 Years of Investigations

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Golovich, Elizabeth C.; Mattigod, Shas V.; Snyder, Michelle MV

    The Waste Management Project provides safe, compliant, and cost-effective waste management services for the Hanford Site and the U.S. Department of Energy (DOE) complex. Part of these services includes safe disposal of low-level waste and mixed low-level waste at the Hanford Low-Level Waste Burial Grounds in accordance with the requirements of DOE Order 435.1, Radioactive Waste Management. To partially satisfy these requirements, performance assessment analyses were completed and approved. DOE Order 435.1 also requires continuing data collection to increase confidence in the critical assumptions used in these analyses to characterize the operational features of the disposal facility that are reliedmore » on to satisfy the performance objectives identified in the order. Cement-based solidification and stabilization is considered for hazardous waste disposal because it is easily done and cost-efficient. One critical assumption is that concrete will be used as a waste form or container material at the Hanford Site to control and minimize the release of radionuclide constituents in waste into the surrounding environment. Concrete encasement would contain and isolate the waste packages from the hydrologic environment and act as an intrusion barrier. Any failure of concrete encasement may result in water intrusion and consequent mobilization of radionuclides from the waste packages. The radionuclides iodine-129, selenium-75, technetium-99, and uranium-238 have been identified as long-term dose contributors (Mann et al. 2001; Wood et al. 1995). Because of their anionic nature in aqueous solutions, these constituents of potential concern may be released from the encased concrete by mass flow and/or diffusion and migrate into the surrounding subsurface environment (Serne et al. 1989; 1992; 1993a, b; 1995). Therefore, it is necessary to assess the performance of the concrete encasement structure and the ability of the surrounding soil to retard radionuclide migration. Each of the test methods performed throughout the lifetime of the project has focused on different aspects of the concrete waste form weathering process. Diffusion of different analytes [technetium-99 (Tc-99), iodine-125 (I-125), stable iodine (I), uranium (U), and rhenium (Re)] has been quantified from experiments under both saturated and unsaturated conditions. The water-saturated conditions provide a conservative estimate of the concrete’s performance in situ, and the unsaturated conditions provide a more accurate estimate of the diffusion of contaminants from the concrete.« less

  8. Characterization and Leaching Tests of the Fluidized Bed Steam Reforming (FBSR) Waste Form for LAW Immobilization

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Neeway, James J.; Qafoku, Nikolla; Brown, Christopher F.

    2013-10-01

    Several supplemental technologies for treating and immobilizing Hanford low activity waste (LAW) have been evaluated. One such immobilization technology is the Fluidized Bed Steam Reforming (FBSR) granular product. The FBSR granular product is composed of insoluble sodium aluminosilicate (NAS) feldspathoid minerals. Production of the FBSR mineral product has been demonstrated both at the industrial and laboratory scale. Pacific Northwest National Laboratory (PNNL) was involved in an extensive characterization campaign. This goal of this campaign was study the durability of the FBSR mineral product and the mineral product encapsulated in a monolith to meet compressive strength requirements. This paper gives anmore » overview of results obtained using the ASTM C 1285 Product Consistency Test (PCT), the EPA Test Method 1311 Toxicity Characteristic Leaching Procedure (TCLP), and the ASTMC 1662 Single-Pass Flow-Through (SPFT) test. Along with these durability tests an overview of the characteristics of the waste form has been collected using Scanning Electron Microscopy (SEM), X-ray Diffraction (XRD), microwave digestions for chemical composition, and surface area from Brunauer, Emmett, and Teller (BET) theory.« less

  9. An overview on characterization, utilization and leachate analysis of biomedical waste incinerator ash.

    PubMed

    Rajor, Anita; Xaxa, Monika; Mehta, Ratika; Kunal

    2012-10-15

    Solid waste management is one of the major global environmental issues, as there is continuous increase in industrial globalization and generation of waste. Solid wastes encompass the heterogeneous mass of throwaways from the urban community as well as the homogeneous accumulations of agricultural, industrial and mineral wastes. Biomedical waste pose a significant impact on health and environment. A proper waste management system should be required to dispose hazardous biomedical waste and incineration should be the best available technology to reduce the volume of this hazardous waste. The incineration process destroys pathogens and reduces the waste volume and weight but leaves a solid material called biomedical waste ash as residue which increases the levels of heavy metals, inorganic salts and organic compounds in the environment. Disposal of biomedical waste ash in landfill may cause contamination of groundwater as metals are not destroyed during incineration. The limited space and the high cost for land disposal led to the development of recycling technologies and the reuse of ash in different systems. In order to minimize leaching of its hazardous components into the environment several studies confirmed the successful utilization of biomedical waste ash in agriculture and construction sector. This paper presents the overview on the beneficial use of ash in agriculture and construction materials and its leachate characteristics. This review also stressed on the need to further evaluate the leachate studies of the ashes and slag for their proper disposal and utilization. Copyright © 2012 Elsevier Ltd. All rights reserved.

  10. An algorithm for the optimal collection of wet waste.

    PubMed

    Laureri, Federica; Minciardi, Riccardo; Robba, Michela

    2016-02-01

    This work refers to the development of an approach for planning wet waste (food waste and other) collection at a metropolitan scale. Some specific modeling features distinguish this specific waste collection problem from the other ones. For instance, there may be significant differences as regards the values of the parameters (such as weight and volume) characterizing the various collection points. As it happens for classical waste collection planning, even in the case of wet waste, one has to deal with difficult combinatorial problems, where the determination of an optimal solution may require a very large computational effort, in the case of problem instances having a noticeable dimensionality. For this reason, in this work, a heuristic procedure for the optimal planning of wet waste is developed and applied to problem instances drawn from a real case study. The performances that can be obtained by applying such a procedure are evaluated by a comparison with those obtainable via a general-purpose mathematical programming software package, as well as those obtained by applying very simple decision rules commonly used in practice. The considered case study consists in an area corresponding to the historical center of the Municipality of Genoa. Copyright © 2015 Elsevier Ltd. All rights reserved.

  11. WCATS: Waste Documentation, Course No. 8504

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Simpson, Sandy

    2016-04-14

    This course was developed for individuals at Los Alamos National Laboratory (LANL) who characterize and document waste streams in the Waste Compliance and Tracking System (WCATS) according to Environmental Protection Agency (EPA) Department of Transportation (DOT) regulations, Department of Energy Orders, and other applicable criteria. When you have completed this course, you will be able to recognize how waste documentation enables LANL to characterize and classify hazardous waste for compliant treatment, storage, and disposal, identify the purpose of the waste stream profile (WSP), identify the agencies that provide guidance for waste management, and more.

  12. Contaminated groundwater characterization at the Chalk River Laboratories, Ontario, Canada

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Schilk, A.J.; Robertson, D.E.; Thomas, C.W.

    1993-03-01

    The licensing requirements for the disposal of low-level radioactive waste (10 CFR 61) specify the performance objectives and technical requisites for federal and commercial land disposal facilities, the ultimate goal of which is to contain the buried wastes so that the general population is adequately protected from harmful exposure to any released radioactive materials. A major concern in the operation of existing and projected waste disposal sites is subterranean radionuclide transport by saturated or unsaturated flow, which could lead to the contamination of groundwater systems as well as uptake by the surrounding biosphere, thereby directly exposing the general public tomore » such materials. Radionuclide transport in groundwater has been observed at numerous commercial and federal waste disposal sites [including several locations within the waste management area of Chalk River Laboratories (CRL)], yet the physico-chemical processes that lead to such migration are still not completely understood. In an attempt to assist in the characterization of these processes, an intensive study was initiated at CRL to identify and quantify the mobile radionuclide species originating from three separate disposal sites: (a) the Chemical Pit, which has received aqueous wastes containing various radioisotopes, acids, alkalis, complexing agents and salts since 1956, (b) the Reactor Pit, which has received low-level aqueous wastes from a reactor rod storage bay since 1956, and (c) the Waste Management Area C, a thirty-year-old series of trenches that contains contaminated solid wastes from CRL and various regional medical facilities. Water samples were drawn downgradient from each of the above sites and passed through a series of filters and ion-exchange resins to retain any particulate and dissolved or colloidal radionuclide species, which were subsequently identified and quantified via radiochemical separations and gamma spectroscopy. These groundwaters were also analyzed for anions, trace metals, Eh, pH, alkalinity and dissolved oxygen.« less

  13. Characterization of the non-metal fraction of the processed waste printed circuit boards.

    PubMed

    Kumar, Amit; Holuszko, Maria E; Janke, Travis

    2018-05-01

    Electronic waste is one the fastest growing waste streams in the world and waste printed circuit boards (PCB) are the most valuable part of this stream due to the presence of gold, silver, copper, and palladium. The metal present in PCBs is mostly recovered for the market value whereas the nonmetal fractions are often ignored. This research explored the characteristics of the non-metal fraction (NMF) obtained after the processing of milled waste PCBs with a focus on responsible end-of-life solutions, in the form of non-hazardous landfilling or incineration. The NMF was characterized using sizing, assaying, loss on ignition, calorific value measurement, and thermogravimetric analysis (TGA). The result showed that the metal content in the NMF increased with decrease in the particle size for most of the metals except antimony and the result from loss on ignition (LOI) also showed that over 50% of the coarser fraction represented organic matter compared to less than 30% for the finest fraction. The study also showed that after the recovery of metals from the waste PCBs, landfill leaching for most of the metal is reduced below the environmental limits, with lead being the only exception. The lead leachate concentration of 18 mg/L was observed, which requires further treatment prior to landfilling. With an energy value of 16 GJ/t, the NMF could provide high energy recovery if incinerated but 194 mg/kg of hazardous flame retardants present in the NMF might be released if the combustion process is not closely monitored. Copyright © 2018 Elsevier Ltd. All rights reserved.

  14. Generation, characterization and reuse of solid wastes from a biodiesel production plant.

    PubMed

    Oliveira, Fernando Jorge Santos; Santana, Daniele Dos Santos; Costa, Simone Soraya Brito; Oliveira, Lenise Diniz; Liduino, Vitor Silva; Servulo, Eliana Flávia Camporese

    2017-03-01

    The aim of this study was to identify and characterize industrial solid wastes generated by a biodiesel production plant in Brazil, as well as to present strategies for the management of these materials. This plant produces every year around 100,000tons of biodiesel from vegetable oils and animal fats. The methodology of the study included technical visits, interviews with the operational and environmental management staff as well as analysis of documents, reports and computerized data systems. An approach to reduce the generation of hazardous waste was investigated. It was take into account the amount of raw material that was processed, reduction of landfill disposal, and the maximization of the their recycling and reuse. The study also identified the sources of waste generation and accordingly prepared an evaluation matrix to determine the types of waste with the higher potential for minimization. The most important residue of the process was the filter material impregnated with oil and biodiesel, requiring, therefore, measures for its minimization. The use of these residues in the production of ceramic artefacts (light bricks) was considered to be very promising, since no significant effect on the physico-chemical and mechanical properties of the artefacts produced was observed. Phytotoxicity test using seeds of Lactuva sativa (lettuce), Brassica juncea (mustard), Abelmoschus esculentus (okra), Chrysanthemum leucanthemum (daisy), Dendranthema grandiflorum (chrysanthemum) and Allium porrum (leek) were carried out. The results clearly show incorporation of the waste material into bricks did not influence relative germination and relative root elongation in comparison to control tests. Copyright © 2016 Elsevier Ltd. All rights reserved.

  15. Tanks Focus Area annual report FY2000

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    None

    2000-12-01

    The U.S. Department of Energy (DOE) continues to face a major radioactive waste tank remediation effort with tanks containing hazardous and radioactive waste resulting from the production of nuclear materials. With some 90 million gallons of waste in the form of solid, sludge, liquid, and gas stored in 287 tanks across the DOE complex, containing approximately 650 million curies, radioactive waste storage tank remediation is the nation's highest cleanup priority. Differing waste types and unique technical issues require specialized science and technology to achieve tank cleanup in an environmentally acceptable manner. Some of the waste has been stored for overmore » 50 years in tanks that have exceeded their design lives. The challenge is to characterize and maintain these contents in a safe condition and continue to remediate and close each tank to minimize the risks of waste migration and exposure to workers, the public, and the environment. In 1994, the DOE's Office of Environmental Management (EM) created a group of integrated, multiorganizational teams focusing on specific areas of the EM cleanup mission. These teams have evolved into five focus areas managed within EM's Office of Science and Technology (OST): Tanks Focus Area (TFA); Deactivation and Decommissioning Focus Area; Nuclear Materials Focus Area; Subsurface Contaminants Focus Area; and Transuranic and Mixed Waste Focus Area.« less

  16. 40 CFR 271.10 - Requirements for generators of hazardous wastes.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... hazardous wastes. 271.10 Section 271.10 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES (CONTINUED) REQUIREMENTS FOR AUTHORIZATION OF STATE HAZARDOUS WASTE PROGRAMS Requirements for Final Authorization § 271.10 Requirements for generators of hazardous wastes. (a) The State...

  17. 40 CFR 271.11 - Requirements for transporters of hazardous wastes.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... hazardous wastes. 271.11 Section 271.11 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES (CONTINUED) REQUIREMENTS FOR AUTHORIZATION OF STATE HAZARDOUS WASTE PROGRAMS Requirements for Final Authorization § 271.11 Requirements for transporters of hazardous wastes. (a) The State...

  18. 40 CFR 271.11 - Requirements for transporters of hazardous wastes.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... hazardous wastes. 271.11 Section 271.11 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES (CONTINUED) REQUIREMENTS FOR AUTHORIZATION OF STATE HAZARDOUS WASTE PROGRAMS Requirements for Final Authorization § 271.11 Requirements for transporters of hazardous wastes. (a) The State...

  19. 40 CFR 271.10 - Requirements for generators of hazardous wastes.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... hazardous wastes. 271.10 Section 271.10 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES (CONTINUED) REQUIREMENTS FOR AUTHORIZATION OF STATE HAZARDOUS WASTE PROGRAMS Requirements for Final Authorization § 271.10 Requirements for generators of hazardous wastes. (a) The State...

  20. 40 CFR 271.10 - Requirements for generators of hazardous wastes.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... hazardous wastes. 271.10 Section 271.10 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES (CONTINUED) REQUIREMENTS FOR AUTHORIZATION OF STATE HAZARDOUS WASTE PROGRAMS Requirements for Final Authorization § 271.10 Requirements for generators of hazardous wastes. (a) The State...

  1. The mixed low-level waste problem in BE/NWN capsule

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Hensley, D.C.

    1999-07-01

    The Boh Environmental, LLC (BE) and Northwest Nuclear, LLC (NWN) program addresses the problem of diminishing capacity in the United States to store mixed waste. A lack of an alternative program has caused the US Department of Energy (DOE) to indefinitely store all of its mixed waste in Resource Conservation and Recovery Act (RCRA) compliant storage facilities. Unfortunately, this capacity is fast approaching the administrative control limit. The combination of unique BE encapsulation and NWN waste characterization technologies provides an effective solution to DOE's mixed-waste dilemma. The BE ARROW-PAK technique encapsulates mixed low-level waste (MLLW) in extra-high molecular weight, high-densitymore » polyethylene, pipe-grade resin cylinders. ARROW-PAK applications include waste treatment, disposal, transportation (per 49 CFR 173), vault encasement, and interim/long-term storage for 100 to 300 yr. One of the first demonstrations of this treatment/storage technique successfully treated 880 mixed-waste debris drums at the DOE Hanford Site in 1997. NWN, deploying the APNea neutron assay technology, provides the screening and characterization capability necessary to ensure that radioactive waste is correctly categorized as either transuranic (TRU) or LLW. MLLW resulting from D and D activities conducted at the Oak Ridge East Tennessee Technology Park will be placed into ARROW-PAK containers following comprehensive characterization of the waste by NWN. The characterized and encapsulated waste will then be shipped to a commercial disposal facility, where the shipments meet all waste acceptance criteria of the disposal facility including treatment criteria.« less

  2. 10 CFR 60.18 - Review of site characterization activities. 2

    Code of Federal Regulations, 2011 CFR

    2011-01-01

    ... developed, and on the progress of waste form and waste package research and development. The semiannual... of site characterization will be established. Other topics related to site characterization shall...

  3. 10 CFR 60.18 - Review of site characterization activities. 2

    Code of Federal Regulations, 2012 CFR

    2012-01-01

    ... developed, and on the progress of waste form and waste package research and development. The semiannual... of site characterization will be established. Other topics related to site characterization shall...

  4. 10 CFR 60.18 - Review of site characterization activities. 2

    Code of Federal Regulations, 2013 CFR

    2013-01-01

    ... developed, and on the progress of waste form and waste package research and development. The semiannual... of site characterization will be established. Other topics related to site characterization shall...

  5. 10 CFR 60.18 - Review of site characterization activities. 2

    Code of Federal Regulations, 2014 CFR

    2014-01-01

    ... developed, and on the progress of waste form and waste package research and development. The semiannual... of site characterization will be established. Other topics related to site characterization shall...

  6. Use of acceptable knowledge to demonstrate TRAMPAC compliance

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Whitworth, J.; Becker, B.; Guerin, D.

    2004-01-01

    Recently, Los Alamos National Laboratory-Carlsbad Operations (LANL-CO) has supported the Central Characterization Project (CCP) managed by the U.S. Department of Energy (DOE) in the shipment of transuranic (TRU) waste from various small-quantity TRU waste generators to hub sites or other DOE sites in TRUPACT-II shipping containers. This support has involved using acceptable knowledge (AK) to demonstrate compliance with various requirements of Revision 19 of the TRUPACT-II Authorized Methods of Payload Compliance (TRAMPAC). LANL-CO has worked to facilitate TRUPACT-II shipments from the University of Missouri Research Reactor (MURR) and Lovelace Respiratory Research Institute (LRRI) to Argonne National Laboratory-East (ANL-E) and Losmore » Alamos National Laboratory (LANL), respectively. The latter two sites have TRU waste certification programs approved to ship waste to the Waste Isolation Pilot Plant (WIPP) for disposal. In each case, AK was used to satisfy the necessary information to ship the waste to other DOE facilities. For the purposes of intersite shipment, AK provided data to WIPP Waste Information System (WWIS) transportation modules to ensure that required information was obtained prior to TRUPACT-II shipments. The WWIS modules were used for the intersite shipments, not to enter certification data into WWIS, but rather to take advantage of a validated system to ensure that the containers to be shipped were compliant with TRAMPAC requirements, particularly in the evaluation of quantitative criteria. LANL-CO also assisted with a TRAMPAC compliance demonstration for homogeneous waste containers shipped in TRUPACT-II containers from ANL-E to Idaho National Engineering and Environmental Laboratory (INEEL) for the purpose of core sampling. The basis for the TRAMPAC compliance determinations was AK regarding radiological composition, chemical composition, TRU waste container packaging, and absence of prohibited items. Also, even in the case where AK is not used to fully demonstrate TRAMPAC compliance, it may be used to identify problem areas for shippability of different waste streams. An example is the case of Pu-238-contaminated waste from the Savannah River Site that had a low probability of meeting decay heat limits and aspiration times due to several factors including large numbers of confinement layers. This paper will outline 17 TRAMPAC compliance criteria assessed and the types of information used to show compliance with all criteria other than dose rate and container weight, which are normally easily measured at load preparation.« less

  7. U.S. Geological Survey research in radioactive waste disposal - Fiscal years 1986-1990

    USGS Publications Warehouse

    Trask, N.J.; Stevens, P.R.

    1991-01-01

    The report summarizes progress on geologic and hydrologic research related to the disposal of radioactive wastes. The research efforts are categorized according to whether they are related most directly to: (1) high-level wastes, (2) transuranic wastes, (3) low-level and mixed low-level and hazardous wastes, or (4) uranium mill tailings. Included is research applicable to the identification and geohydrologic characterization of waste-disposal sites, to investigations of specific sites where wastes have been stored, to development of techniques and methods for characterizing disposal sites, and to studies of geologic and hydrologic processes related to the transport and/or retention of waste radionuclides.

  8. De-Inventory Plan for Transuranic Waste Stored at Area G

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Hargis, Kenneth Marshall; Christensen, Davis V.; Shepard, Mark D.

    This report describes the strategy and detailed work plan developed by Los Alamos National Laboratory (LANL) to disposition transuranic (TRU) waste stored at its Area G radioactive waste storage site. The focus at this time is on disposition of 3,706 m 3 of TRU waste stored above grade by June 30, 2014, which is one of the commitments within the Framework Agreement: Realignment of Environmental Priorities between the Department of Energy (DOE) National Nuclear Security Administration (NNSA) and the State of New Mexico Environment Department (NMED), Reference 1. A detailed project management schedule has been developed to manage this workmore » and better ensure that all required activities are aligned and integrated. The schedule was developed in conjunction with personnel from the NNSA Los Alamos Site Office (LASO), the DOE Carlsbad Field Office (CBFO), the Central Characterization Project (CCP), and Los Alamos National Security, LLC (LANS). A detailed project management schedule for the remainder of the above grade inventory and the below grade inventory will be developed and incorporated into the De-Inventory Plan by December 31, 2012. This schedule will also include all newly-generated TRU waste received at Area G in FYs 2012 and 2013, which must be removed by no later than December 31, 2014, under the Framework Agreement. The TRU waste stored above grade at Area G is considered to be one of the highest nuclear safety risks at LANL, and the Defense Nuclear Facility Safety Board has expressed concern for the radioactive material at risk (MAR) contained within the above grade TRU waste inventory and has formally requested that DOE reduce the MAR. A large wildfire called the Las Conchas Fire burned extensive areas west of LANL in late June and July 2011. Although there was minimal to no impact by the fire to LANL, the fire heightened public concern and news media attention on TRU waste storage at Area G. After the fire, New Mexico Governor Susana Martinez also requested that LANL accelerate disposition of TRU waste stored above grade at Area G. The 3,706 m 3 volume of TRU waste stored above grade consists of 4,495 containers that include all above grade non-cemented waste as well as above grade cemented waste that was ready for characterization on October 1, 2011. This volume includes all newly-generated TRU waste currently stored at Area G as of October 1, 2011. This volume does not include the Bolas Grandes spheres, mixed low level waste (MLLW) containers, empty containers, cemented waste that requires remediation, projected newly generated TRU waste from FY 2012 and later, or TRU waste stored below grade. The 3,706 m 3 volume represents about 86 per cent of the total volume of TRU waste stored above grade on October 1, 2011. The De-Inventory Plan supports the DOE Office of Environmental Management (EM) goal to disposition 90% of the Legacy TRU waste within the DOE complex by the end of 2015 as stated in its Roadmap for EM’s Journey to Excellence (Reference 2). The plan also addresses precursor actions for disposition of TRU waste that are necessary for compliance with the Compliance Order on Consent issued by the NMED in 2005 (Reference 3).« less

  9. 40 CFR 271.11 - Requirements for transporters of hazardous wastes.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... that such wastes do not present a hazard to human health or the environment. These requirements shall... hazardous wastes. 271.11 Section 271.11 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES (CONTINUED) REQUIREMENTS FOR AUTHORIZATION OF STATE HAZARDOUS WASTE PROGRAMS Requirements...

  10. 40 CFR 271.11 - Requirements for transporters of hazardous wastes.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... that such wastes do not present a hazard to human health or the environment. These requirements shall... hazardous wastes. 271.11 Section 271.11 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES (CONTINUED) REQUIREMENTS FOR AUTHORIZATION OF STATE HAZARDOUS WASTE PROGRAMS Requirements...

  11. 40 CFR 271.11 - Requirements for transporters of hazardous wastes.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... that such wastes do not present a hazard to human health or the environment. These requirements shall... hazardous wastes. 271.11 Section 271.11 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES (CONTINUED) REQUIREMENTS FOR AUTHORIZATION OF STATE HAZARDOUS WASTE PROGRAMS Requirements...

  12. WIPP Hazardous Waste Facility Permit Update

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Kehrman, B.; Most, W.

    2006-07-01

    The Waste Isolation Pilot Plant (WIPP) Hazardous Waste Facility Permit (HWFP) was issued on October 27, 1999 [1]. Since that time, the WIPP has sought modifications to clarify the permit language, provide alternative methods for meeting permit requirements and to update permit conditions. Significant advancements have been made in transuranic (TRU) waste management as the result of modifications to the HWFP. Among these advancements is a modification to obtain a drum age criteria (DAC) value to perform headspace gas sampling on drums to be super-compacted and placed in a 100-gallon overpack drum. In addition, the Section 311 permit modification requestmore » that would allow for more efficient waste characterization, and the modification to authorize the shipment and disposal of Remote-Handled (RH) TRU waste were merged together and submitted to the regulator as the Consolidated Permit Modification Request (PMR). The submittal of the Consolidated PMR came at the request of the regulator as part of responses to Notices of Deficiency (NODs) for the separate PMRs which had been submitted in previous years. Section 311 of the fiscal year 2004 Energy and Water Developments Appropriations Act (Public Law 108-137) [2] directs the Department of Energy to submit a permit modification that limits waste confirmation to radiography or visual examination of a statistical subpopulation of containers. Section 311 also specifically directs that disposal room performance standards be to be met by monitoring for volatile organic compounds in the underground disposal rooms. This statute translates into the elimination of other waste confirmation methods such as headspace gas sampling and analysis and solids sampling and analysis. These methods, as appropriate, will continue to be used by the generator sites during hazardous waste determinations or characterization activities. This modification is expected to reduce the overall cost of waste analysis by hundreds of millions of dollars [3]. Combining both the chap. 311 and RH TRU waste permit modification requests allows for both the regulator and DOE to expedite action on the modification requests. The Combined PMR reduces costs by having only one administrative process for both modification requests. (authors)« less

  13. Valorization of titanium metal wastes as tanning agent used in leather industry.

    PubMed

    Crudu, Marian; Deselnicu, Viorica; Deselnicu, Dana Corina; Albu, Luminita

    2014-10-01

    The development of new tanning agents and new technologies in the leather sector is required to cope with the increasingly higher environmental pressure on the current tanning materials and processes such as tanning with chromium salts. In this paper, the use of titanium wastes (cuttings) resulting from the process of obtaining highly pure titanium (ingots), for the synthesis of new tanning agent and tanning bovine hides with new tanning agent, as alternative to tanning with chromium salts are investigated. For this purpose, Ti waste and Ti-based tanning agent were characterized for metal content by inductively coupled plasma mass spectrometry (ICP-MS) and chemical analysis; the tanned leather (wet white leather) was characterized by Scanning Electron Microscope/Energy Dispersive Using X-ray (Analysis). SEM/EDX analysis for metal content; Differential scanning calorimetric (DSC), Micro-Hot-Table and standard shrinkage temperature showing a hydrothermal stability (ranged from 75.3 to 77°C) and chemical analysis showing the leather is tanned and can be processed through the subsequent mechanical operations (splitting, shaving). On the other hand, an analysis of major minor trace substances from Ti-end waste (especially vanadium content) in new tanning agent and wet white leather (not detected) and residue stream was performed and showed that leachability of vanadium is acceptable. The results obtained show that new tanning agent obtained from Ti end waste can be used for tanning bovine hides, as eco-friendly alternative for chrome tanning. Copyright © 2014 Elsevier Ltd. All rights reserved.

  14. Study of Material Used in Nanotechnology for the Recycling of Industrial Waste Water

    NASA Astrophysics Data System (ADS)

    Larbi, L.; Fertikh, N.; Toubal, A.

    The objective of our study is to recycle the industrial waste water of a industrial Complex after treatment by the bioprocess MBR (membrane bioreactor). In order to apply this bioprocess, the water quality in question was first of all studied. To characterize this industrial waste water, a series of physicochemical analysis was carried out according to standardized directives and methods. Following-up the water quality to meet the regulatory requirements with rejection of this industrial waste water, a study was done thanks to the permanently monitoring of the following relevant parameters(P): the flow, the potential of hydrogen (pH), the total suspended solids(TSS), the turbidity (Turb), the chemical oxygen demand (COD),the biochemical oxygen demand (BOD), the Kjeldahl total nitrogen (KTN) and ammonia (NH4+), the total phosphorus (Ptot), the fluorine (F), the oils (O), the fats (F) and the phenols (Ph). According to collected information, it was established the sampling rates to which the quality control was done, the selected analytical methods were validated by the control charts and the analysis test number was determined by the Cochran test. The results of the quality control show that some rejected water contents are not in the Algerian standards, but, in our case, the objective is the preoccupation for a standard setting of these industrial water parameters so as to recycle it. The process adopted by MBR for waste water treatment is being studied, first in the development of the experimental characterizing of the reactor and the selected membrane.

  15. Characterization of Class A low-level radioactive waste 1986--1990. Volume 6: Appendices G--J

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Dehmel, J.C.; Loomis, D.; Mauro, J.

    1994-01-01

    Under contract to the US Nuclear Regulatory Commission, Office of Nuclear Regulatory Research, the firms of S. Cohen & Associates, Inc. (SC&A) and Eastern Research Group (ERG) have compiled a report that describes the physical, chemical, and radiological properties of Class-A low-level radioactive waste. The report also presents information characterizing various methods and facilities used to treat and dispose non-radioactive waste. A database management program was developed for use in accessing, sorting, analyzing, and displaying the electronic data provided by EG&G. The program was used to present and aggregate data characterizing the radiological, physical, and chemical properties of the wastemore » from descriptions contained in shipping manifests. The data thus retrieved are summarized in tables, histograms, and cumulative distribution curves presenting radionuclide concentration distributions in Class-A waste as a function of waste streams, by category of waste generators, and regions of the United States. The report also provides information characterizing methods and facilities used to treat and dispose non-radioactive waste, including industrial, municipal, and hazardous waste regulated under Subparts C and D of the Resource Conservation and Recovery Act (RCRA). The information includes a list of disposal options, the geographical locations of the processing and disposal facilities, and a description of the characteristics of such processing and disposal facilities. Volume 1 contains the Executive Summary, Volume 2 presents the Class-A waste database, Volume 3 presents the information characterizing non-radioactive waste management practices and facilities, and Volumes 4 through 7 contain Appendices A through P with supporting information.« less

  16. Idaho National Engineering Laboratory code assessment of the Rocky Flats transuranic waste

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    NONE

    1995-07-01

    This report is an assessment of the content codes associated with transuranic waste shipped from the Rocky Flats Plant in Golden, Colorado, to INEL. The primary objective of this document is to characterize and describe the transuranic wastes shipped to INEL from Rocky Flats by item description code (IDC). This information will aid INEL in determining if the waste meets the waste acceptance criteria (WAC) of the Waste Isolation Pilot Plant (WIPP). The waste covered by this content code assessment was shipped from Rocky Flats between 1985 and 1989. These years coincide with the dates for information available in themore » Rocky Flats Solid Waste Information Management System (SWIMS). The majority of waste shipped during this time was certified to the existing WIPP WAC. This waste is referred to as precertified waste. Reassessment of these precertified waste containers is necessary because of changes in the WIPP WAC. To accomplish this assessment, the analytical and process knowledge available on the various IDCs used at Rocky Flats were evaluated. Rocky Flats sources for this information include employee interviews, SWIMS, Transuranic Waste Certification Program, Transuranic Waste Inspection Procedure, Backlog Waste Baseline Books, WIPP Experimental Waste Characterization Program (headspace analysis), and other related documents, procedures, and programs. Summaries are provided of: (a) certification information, (b) waste description, (c) generation source, (d) recovery method, (e) waste packaging and handling information, (f) container preparation information, (g) assay information, (h) inspection information, (i) analytical data, and (j) RCRA characterization.« less

  17. Plants for water recycling, oxygen regeneration and food production

    NASA Technical Reports Server (NTRS)

    Bubenheim, D. L.

    1991-01-01

    During long-duration space missions that require recycling and regeneration of life support materials the major human wastes to be converted to usable forms are CO2, hygiene water, urine and feces. A Controlled Ecological Life Support System (CELSS) relies on the air revitalization, water purification and food production capabilities of higher plants to rejuvenate human wastes and replenish the life support materials. The key processes in such a system are photosynthesis, whereby green plants utilize light energy to produce food and oxygen while removing CO2 from the atmosphere, and transpiration, the evaporation of water from the plant. CELSS research has emphasized the food production capacity and efforts to minimize the area/volume of higher plants required to satisfy all human life support needs. Plants are a dynamic system capable of being manipulated to favour the supply of individual products as desired. The size and energy required for a CELSS that provides virtually all human needs are determined by the food production capacity. Growing conditions maximizing food production do not maximize transpiration of water; conditions favoring transpiration and scaling to recycle only water significantly reduces the area, volume, and energy inputs per person. Likewise, system size can be adjusted to satisfy the air regeneration needs. Requirements of a waste management system supplying inputs to maintain maximum plant productivity are clear. The ability of plants to play an active role in waste processing and the consequence in terms of degraded plant performance are not well characterized. Plant-based life support systems represent the only potential for self sufficiency and food production in an extra-terrestrial habitat.

  18. From waste to high-value product: Jackfruit peel derived pectin/apatite bionanocomposites for bone healing applications.

    PubMed

    Govindaraj, Dharman; Rajan, Mariappan; Hatamleh, Ashraf A; Munusamy, Murugan A

    2018-01-01

    Public requirements encouraged by the current asset framework drive industry to expand its general effectiveness by enhancing existing procedures or finding new uses for waste. Thus, the aim of this study was the isolation, fabrication, and characterization of pectin derived from jackfruit (Artocarpus heterophyllus) peels and the generation of hybrid of pectin (P)/apatite (HA) (P/HA) bionanocomposites. In this process, the natural pectin polymer derived from the peel of jackfruits was used in different concentrations for the fabrication of HA bionanocomposites. Characterization of the isolated pectin and bionanocomposites samples was performed with 1 H NMR and 13 C NMR, FTIR, XRD, SEM-EDX, and HR-TEM. Cytocompatibility, ALP, fibroblast stem cells, anti-inflammatory and cell adhesion testing of the fabricated bionanocomposites was showed good biocompatibility. Our results signify that the fabricated bionanocomposites might be applicable as bone graft materials. Copyright © 2017 Elsevier B.V. All rights reserved.

  19. Characterization of the solid low level mixed waste inventory for the solid waste thermal treatment activity - III

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Place, B.G., Westinghouse Hanford

    1996-09-24

    The existing thermally treatable, radioactive mixed waste inventory is characterized to support implementation of the commercial, 1214 thermal treatment contract. The existing thermally treatable waste inventory has been identified using a decision matrix developed by Josephson et al. (1996). Similar to earlier waste characterization reports (Place 1993 and 1994), hazardous materials, radionuclides, physical properties, and waste container data are statistically analyzed. In addition, the waste inventory data is analyzed to correlate waste constituent data that are important to the implementation of the commercial thermal treatment contract for obtaining permits and for process design. The specific waste parameters, which were analyzed,more » include the following: ``dose equivalent`` curie content, polychlorinated biphenyl (PCB) content, identification of containers with PA-related mobile radionuclides (14C, 12 79Se, 99Tc, and U isotopes), tritium content, debris and non-debris content, container free liquid content, fissile isotope content, identification of dangerous waste codes, asbestos containers, high mercury containers, beryllium dust containers, lead containers, overall waste quantities, analysis of container types, and an estimate of the waste compositional split based on the thermal treatment contractor`s proposed process. A qualitative description of the thermally treatable mixed waste inventory is also provided.« less

  20. Electrical and electronic waste: a global environmental problem.

    PubMed

    Ramesh Babu, Balakrishnan; Parande, Anand Kuber; Ahmed Basha, Chiya

    2007-08-01

    The production of electrical and electronic equipment (EEE) is one of the fastest growing global manufacturing activities. This development has resulted in an increase of waste electric and electronic equipment (WEEE). Rapid economic growth, coupled with urbanization and growing demand for consumer goods, has increased both the consumption of EEE and the production of WEEE, which can be a source of hazardous wastes that pose a risk to the environment and to sustainable economic growth. To address potential environmental problems that could stem from improper management of WEEE, many countries and organizations have drafted national legislation to improve the reuse, recycling and other forms of material recovery from WEEE to reduce the amount and types of materials disposed in landfills. Recycling of waste electric and electronic equipment is important not only to reduce the amount of waste requiring treatment, but also to promote the recovery of valuable materials. EEE is diverse and complex with respect to the materials and components used and waste streams from the manufacturing processes. Characterization of these wastes is of paramount importance for developing a cost-effective and environmentally sound recycling system. This paper offers an overview of electrical and e-waste recycling, including a description of how it is generated and classified, strategies and technologies for recovering materials, and new scientific developments related to these activities. Finally, the e-waste recycling industry in India is also discussed.

  1. Solid waste characterization in Ketao, a rural town in Togo, West Africa.

    PubMed

    Edjabou, Maklawe Essonanawe; Møller, Jacob; Christensen, Thomas H

    2012-07-01

    In Africa the majority of solid waste data is for big cities. Small and rural towns are generally neglected and waste data from these areas are often unavailable, which makes planning a proper solid waste management difficult. This paper presents the results from two waste characterization projects conducted in Kétao, a rural town in Togo during the rainy season and the dry season in 2010. The seasonal variation has a significant impact on the waste stream. The household waste generation rate was estimated at 0.22 kg person(-1) day(-1) in the dry season and 0.42 in the rainy season. Likewise, the waste moisture content was 4% in the dry season while it was 33-63% in the rainy season. The waste consisted mainly of soil and dirt characterized as 'other' (41%), vegetables and putrescibles (38%) and plastic (11%). In addition to these fractions, considerable amounts of material are either recycled or reused locally and do not enter the waste stream. The study suggests that additional recycling is not feasible, but further examination of the degradability of the organic fraction is needed in order to assess whether the residual waste should be composed or landfilled.

  2. Characterization of the March 2017 Tank 15 Waste Removal Slurry Sample (Combination of Slurry Samples HTF-15-17-28 and HTF-15-17-29)

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Reboul, S. H.; King, W. D.; Coleman, C. J.

    2017-05-09

    Two March 2017 Tank 15 slurry samples (HTF-15-17-28 and HTF-15-17-29) were collected during the second bulk waste removal campaign and submitted to SRNL for characterization. At SRNL, the two samples were combined and then characterized by a series of physical, elemental, radiological, and ionic analysis methods. Sludge settling as a function of time was also quantified. The characterization results reported in this document are consistent with expectations based upon waste type, process knowledge, comparisons between alternate analysis techniques, and comparisons with the characterization results obtained for the November 2016 Tank 15 slurry sample (the sample collected during the first bulkmore » waste removal campaign).« less

  3. Spacecraft active thermal control subsystem design and operation considerations

    NASA Technical Reports Server (NTRS)

    Sadunas, J. A.; Lehtinen, A. M.; Nguyen, H. T.; Parish, R.

    1986-01-01

    Future spacecraft missions will be characterized by high electrical power requiring active thermal control subsystems for acquisition, transport, and rejection of waste heat. These systems will be designed to operate with minimum maintenance for up to 10 years, with widely varying externally-imposed environments, as well as the spacecraft waste heat rejection loads. This paper presents the design considerations and idealized performance analysis of a typical thermal control subsystem with emphasis on the temperature control aspects during off-design operation. The selected thermal management subsystem is a cooling loop for a 75-kWe fuel cell subsystem, consisting of a fuel cell heat exchanger, thermal storage, pumps, and radiator. Both pumped-liquid transport and two-phase (liquid/vapor) transport options are presented with examination of similarities and differences of the control requirements for these representative thermal control options.

  4. Tank characterization report for single-shell tank 241-C-109

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Simpson, B.C.

    1997-05-23

    One of the major functions of the Tank Waste Remediation System (TWRS) is to characterize wastes in support of waste management and disposal activities at the Hanford Site. Analytical data from sampling and analysis, along with other available information about a tank, are compiled and maintained in a tank characterization report (TCR). This report and its appendices serve as the TCR for single-shell tank 241-C-109. The objectives of this report are: (1) to use characterization data in response to technical issues associated with tank 241 C-109 waste; and (2) to provide a standard characterization of this waste in terms ofmore » a best-basis inventory estimate. The response to technical issues is summarized in Section 2.0, and the best-basis inventory estimate is presented in Section 3.0. Recommendations regarding safety status and additional sampling needs are provided in Section 4.0. Supporting data and information are contained in the appendices.« less

  5. Brain drains: new insights into brain clearance pathways from lymphatic biology.

    PubMed

    Bower, Neil I; Hogan, Benjamin M

    2018-05-01

    The lymphatic vasculature act as the drainage system for most of our tissues and organs, clearing interstitial fluid and waste and returning them to the blood circulation. This is not the case for the central nervous system (CNS), which is devoid of parenchymal lymphatic vessels. Nevertheless, the brain is responsible for 25% of the body's metabolism and only compromises 2% of the body's mass. This high metabolic load requires an efficient system to remove waste products and maintain homeostasis. Well-described mechanisms of waste clearance include phagocytic immune cell functions as well as perivascular fluid flow; however, the need for active drainage of waste from the brain is becoming increasingly appreciated. Recent developments in lymphatic vascular biology challenge the proposition that the brain lacks lymphatic drainage or an equivalent. In this review, we describe the roles of the glymphatic system (a key drainage mechanism in the absence of lymphatics), the recently characterized meningeal lymphatic vessels, and explore an enigmatic cell population found in zebrafish called mural lymphatic endothelial cells. These systems may play important individual and collective roles in draining and clearing wastes from the brain.

  6. Progress and future direction for the interim safe storage and disposal of Hanford high-level waste

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Kinzer, J.E.; Wodrich, D.D.; Bacon, R.F.

    This paper describes the progress made at the largest environmental cleanup program in the United States. Substantial advances in methods to start interim safe storage of Hanford Site high-level wastes, waste characterization to support both safety- and disposal-related information needs, and proceeding with cost-effective disposal by the U.S. Department of Energy (DOE) and its Hanford Site contractors, have been realized. Challenges facing the Tank Waste Remediation System (TWRS) Program, which is charged with the dual and parallel missions of interim safe storage and disposal of the high-level tank waste stored at the Hanford Site, are described. In these times ofmore » budget austerity, implementing an ongoing program that combines technical excellence and cost effectiveness is the near-term challenge. The technical initiatives and progress described in this paper are made more cost effective by DOE`s focus on work force productivity improvement, reduction of overhead costs, and reduction, integration and simplification of DOE regulations and operations requirements to more closely model those used in the private sector.« less

  7. Characterization of microbial and chemical composition of shuttle wet waste with permanent gas and volatile organic compound analyses

    NASA Astrophysics Data System (ADS)

    Peterson, B. V.; Hummerick, M.; Roberts, M. S.; Krumins, V.; Kish, A. L.; Garland, J. L.; Maxwell, S.; Mills, A.

    2004-01-01

    Solid-waste treatment in space for Advanced Life Support, ALS, applications requires that the material can be safely processed and stored in a confined environment. Many solid-wastes are not stable because they are wet (40-90% moisture) and contain levels of soluble organic compounds that can contribute to the growth of undesirable microorganisms with concomitant production of noxious odors. In the absence of integrated Advanced Life Support systems on orbit, permanent gas, trace volatile organic and microbiological analyses were performed on crew refuse returned from the volume F "wet" trash of three consecutive Shuttle missions (STS-105, 109, and 110). These analyses were designed to characterize the short-term biological stability of the material and assess potential crew risks resulting from microbial decay processes during storage. Waste samples were collected post-orbiter landing and sorted into packaging material, food waste, toilet waste, and bulk liquid fractions deposited during flight in the volume F container. Aerobic and anaerobic microbial loads were determined in each fraction by cultivation on R2A and by acridine orange direct count (AODC). Dry and ash weights were performed to determine both water and organic content of the materials. Experiments to determine the aerobic and anaerobic biostability of refuse stored for varying periods of time were performed by on-line monitoring of CO 2 and laboratory analysis for production of hydrogen sulfide and methane. Volatile organic compounds and permanent gases were analyzed using EPA Method TO15 by USEPA et al. [EPA Method TO15, The Determination of Volatile Organic Compounds (VOCs) in Ambient Air using SUMMA, Passivated Canister Sampling and Gas Chromatographic Analysis, 1999] with gas chromatography/mass spectrometry and by gas chromatography with selective detectors. These baseline measures of waste stream content, labile organics, and microbial load in the volume F Shuttle trash provide data for waste subsystem analysis and atmospheric management within the ALS Project.

  8. Characterization of microbial and chemical composition of shuttle wet waste with permanent gas and volatile organic compound analyses

    NASA Technical Reports Server (NTRS)

    Peterson, B. V.; Hummerick, M.; Roberts, M. S.; Krumins, V.; Kish, A. L.; Garland, J. L.; Maxwell, S.; Mills, A.

    2004-01-01

    Solid-waste treatment in space for Advanced Life Support, ALS, applications requires that the material can be safely processed and stored in a confined environment. Many solid-wastes are not stable because they are wet (40-90% moisture) and contain levels of soluble organic compounds that can contribute to the growth of undesirable microorganisms with concomitant production of noxious odors. In the absence of integrated Advanced Life Support systems on orbit, permanent gas, trace volatile organic and microbiological analyses were performed on crew refuse returned from the volume F "wet" trash of three consecutive Shuttle missions (STS-105, 109, and 110). These analyses were designed to characterize the short-term biological stability of the material and assess potential crew risks resulting from microbial decay processes during storage. Waste samples were collected post-orbiter landing and sorted into packaging material, food waste, toilet waste, and bulk liquid fractions deposited during flight in the volume F container. Aerobic and anaerobic microbial loads were determined in each fraction by cultivation on R2A and by acridine orange direct count (AODC). Dry and ash weights were performed to determine both water and organic content of the materials. Experiments to determine the aerobic and anaerobic biostability of refuse stored for varying periods of time were performed by on-line monitoring of CO2 and laboratory analysis for production of hydrogen sulfide and methane. Volatile organic compounds and permanent gases were analyzed using EPA Method TO15 by USEPA et al. [EPA Method TO15, The Determination of Volatile Organic Compounds (VOCs) in Ambient Air using SUMMA, Passivated Canister Sampling and Gas Chromatographic Analysis,1999] with gas chromatography/mass spectrometry and by gas chromatography with selective detectors. These baseline measures of waste stream content, labile organics, and microbial load in the volume F Shuttle trash provide data for waste subsystem analysis and atmospheric management within the ALS Project. Published by Elsevier Ltd on behalf of COSPAR.

  9. Characterization of microbial and chemical composition of shuttle wet waste with permanent gas and volatile organic compound analyses.

    PubMed

    Peterson, B V; Hummerick, M; Roberts, M S; Krumins, V; Kish, A L; Garland, J L; Maxwell, S; Mills, A

    2004-01-01

    Solid-waste treatment in space for Advanced Life Support, ALS, applications requires that the material can be safely processed and stored in a confined environment. Many solid-wastes are not stable because they are wet (40-90% moisture) and contain levels of soluble organic compounds that can contribute to the growth of undesirable microorganisms with concomitant production of noxious odors. In the absence of integrated Advanced Life Support systems on orbit, permanent gas, trace volatile organic and microbiological analyses were performed on crew refuse returned from the volume F "wet" trash of three consecutive Shuttle missions (STS-105, 109, and 110). These analyses were designed to characterize the short-term biological stability of the material and assess potential crew risks resulting from microbial decay processes during storage. Waste samples were collected post-orbiter landing and sorted into packaging material, food waste, toilet waste, and bulk liquid fractions deposited during flight in the volume F container. Aerobic and anaerobic microbial loads were determined in each fraction by cultivation on R2A and by acridine orange direct count (AODC). Dry and ash weights were performed to determine both water and organic content of the materials. Experiments to determine the aerobic and anaerobic biostability of refuse stored for varying periods of time were performed by on-line monitoring of CO2 and laboratory analysis for production of hydrogen sulfide and methane. Volatile organic compounds and permanent gases were analyzed using EPA Method TO15 by USEPA et al. [EPA Method TO15, The Determination of Volatile Organic Compounds (VOCs) in Ambient Air using SUMMA, Passivated Canister Sampling and Gas Chromatographic Analysis,1999] with gas chromatography/mass spectrometry and by gas chromatography with selective detectors. These baseline measures of waste stream content, labile organics, and microbial load in the volume F Shuttle trash provide data for waste subsystem analysis and atmospheric management within the ALS Project. Published by Elsevier Ltd on behalf of COSPAR.

  10. DOE Office of Scientific and Technical Information (OSTI.GOV)

    Osmanlioglu, Ahmet Erdal

    Available in abstract form only. Full text of publication follows: Naturally occurring radioactive material (NORM) in concentrated forms arises both in industry and in nature where natural radioisotopes accumulate at particular sites. Technically enhanced naturally occurring radioactive materials (TE-NORM) often occurs in an acidic environment where precipitates containing radionuclides plate out onto pipe walls, filters, tank linings, etc. Because of the radionuclides are selectively deposited at these sites, radioactivity concentration is extremely higher than the natural concentration. This paper presents characterization and related considerations of TE-NORM wastes in Turkey. Generally, accumulation conditions tend to favour the build-up of radium. Asmore » radium is highly radio-toxic, handling, treatment, storage and disposal of such material requires careful management. Turkey has the only low level waste processing and storage facility (WPSF) in Istanbul. This facility has interim storage buildings and storage area for storage of packaged radioactive waste which are containing artificial radioisotopes, but there is an increasing demand for the storage to accept bulk concentrated TE-NORM wastes from iron-steel and related industries. Most of these wastes generated from scrap metal piles which are imported from other countries. These wastes generally contain radium. (authors)« less

  11. A new approach to characterize very-low-level radioactive waste produced at hadron accelerators.

    PubMed

    Zaffora, Biagio; Magistris, Matteo; Chevalier, Jean-Pierre; Luccioni, Catherine; Saporta, Gilbert; Ulrici, Luisa

    2017-04-01

    Radioactive waste is produced as a consequence of preventive and corrective maintenance during the operation of high-energy particle accelerators or associated dismantling campaigns. Their radiological characterization must be performed to ensure an appropriate disposal in the disposal facilities. The radiological characterization of waste includes the establishment of the list of produced radionuclides, called "radionuclide inventory", and the estimation of their activity. The present paper describes the process adopted at CERN to characterize very-low-level radioactive waste with a focus on activated metals. The characterization method consists of measuring and estimating the activity of produced radionuclides either by experimental methods or statistical and numerical approaches. We adapted the so-called Scaling Factor (SF) and Correlation Factor (CF) techniques to the needs of hadron accelerators, and applied them to very-low-level metallic waste produced at CERN. For each type of metal we calculated the radionuclide inventory and identified the radionuclides that most contribute to hazard factors. The methodology proposed is of general validity, can be extended to other activated materials and can be used for the characterization of waste produced in particle accelerators and research centres, where the activation mechanisms are comparable to the ones occurring at CERN. Copyright © 2017 Elsevier Ltd. All rights reserved.

  12. Summary Report of Laboratory Testing to Establish the Effectiveness of Proposed Treatment Methods for Unremediated and Remediated Nitrate Salt Waste Streams

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Anast, Kurt Roy; Funk, David John

    The inadvertent creation of transuranic waste carrying hazardous waste codes D001 and D002 requires the treatment of the material to eliminate the hazardous characteristics and allow its eventual shipment and disposal at the Waste Isolation Pilot Plant (WIPP). This report documents the effectiveness of two treatment methods proposed to stabilize both the unremediated and remediated nitrate salt waste streams (UNS and RNS, respectively). The two technologies include the addition of zeolite (with and without the addition of water as a processing aid) and cementation. Surrogates were developed to evaluate both the solid and liquid fractions expected from parent waste containers,more » and both the solid and liquid fractions were tested. Both technologies are shown to be effective at eliminating the characteristic of ignitability (D001), and the addition of zeolite was determined to be effective at eliminating corrosivity (D002), with the preferred option1 of zeolite addition currently planned for implementation at the Waste Characterization, Reduction, and Repackaging Facility. During the course of this work, we established the need to evaluate and demonstrate the effectiveness of the proposed remedy for debris material, if required. The evaluation determined that Wypalls absorbed with saturated nitrate salt solutions exhibit the ignitability characteristic (all other expected debris is not classified as ignitable). Follow-on studies will be developed to demonstrate the effectiveness of stabilization for ignitable Wypall debris. Finally, liquid surrogates containing saturated nitrate salts did not exhibit the characteristic of ignitability in their pure form (those neutralized with Kolorsafe and mixed with sWheat did exhibit D001). As a result, additional nitrate salt solutions (those exhibiting the oxidizer characteristic) will be tested to demonstrate the effectiveness of the remedy.« less

  13. Waste Generated from LMR-AMTEC Reactor Concept

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Hasan, Ahmed; Mohamed, Yasser, T.; Mohammaden, Tarek, F.

    2003-02-25

    The candidate Liquid Metal Reactor-Alkali Metal Thermal -to- Electric Converter (LMR-AMTEC) is considered to be the first reactor that would use pure liquid potassium as a secondary coolant, in which potassium vapor aids in the conversion of thermal energy to electric energy. As with all energy production, the thermal generation of electricity produces wastes. These wastes must be managed in ways which safeguard human health and minimize their impact on the environment. Nuclear power is the only energy industry, which takes full responsibility for all its wastes. Based on the candidate design of the LMR-AMTEC components and the coolant types,more » different wastes will be generated from LMR. These wastes must be classified and characterized according to the U.S. Code of Federal Regulation, CFR. This paper defines the waste generation and waste characterization from LMR-AMTEC and reviews the applicable U.S. regulations that govern waste transportation, treatment, storage and final disposition. The wastes generated from LMR-AMTEC are characterized as: (1) mixed waste which is generated from liquid sodium contaminated by fission products and activated corrosion products; (2) hazardous waste which is generated from liquid potassium contaminated by corrosion products; (3) spent nuclear fuel; and (4) low-level radioactive waste which is generated from the packing materials (e.g. activated carbon in cold trap and purification units). The regulations and management of these wastes are summarized in this paper.« less

  14. Characterization of Volume F Trash from Four Recent STS Missions: Weights, Categorization, Water Content

    NASA Technical Reports Server (NTRS)

    Strayer, Richard F.; Hummerick, Mary E.; Richards, Jeffrey T.; McCoy, LaShelle E.; Roberts, Michael S.; Wheeler, Raymond M.

    2011-01-01

    The fate of space-generated solid wastes, including trash, for future missions is under consideration by NASA. Several potential treatment options are under consideration and active technology development. Potential fates for space-generated solid wastes are: Storage without treatment; storage after treatment(s) including volume reduction, water recovery, sterilization, and recovery plus recycling of waste materials. Recycling might be important for partial or full closure scenarios because of the prohibitive costs associated with resupply of consumable materials. For this study, we determined the composition of trash returned from four recent STS missions. The trash material was 'Volume F' trash and other trash, in large zip-lock bags, that accompanied the Volume F trash. This is the first of two submitted papers on these wastes. This one will cover trash content, weight and water content. The other will report on the microbial Characterization of this trash. STS trash was usually made available within 2 days of landing at KSC. The Volume F bag was weighed, opened and the contents were catalogued and placed into one of the following categories: food waste (and containers), drink containers, personal hygiene items - including EVA maximum absorbent garments (MAGs)and Elbow packs (daily toilet wipes, etc), paper, and packaging materials - plastic firm and duct tape. Trash generation rates for the four STS missions: Total wet trash was 0.602 plus or minus 0.089 kg(sub wet) crew(sup -1) d(sup -1) containing about 25% water at 0.154 plus or minus 0.030 kg(sub water) crew(sup -1) d(sup -1) (avg plus or minus stdev). Cataloguing by category: personal hygiene wastes accounted for 50% of the total trash and 69% of the total water for the four missions; drink items were 16% of total weight and 16% water; food wastes were 22% of total weight and 15% of the water; office waste and plastic film were 2% and 11% of the total waste and did not contain any water. The results can be used by NASA to determine requirements and criteria for Waste Management Systems on future missions.

  15. EnergySolution's Clive Disposal Facility Operational Research Model - 13475

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Nissley, Paul; Berry, Joanne

    2013-07-01

    EnergySolutions owns and operates a licensed, commercial low-level radioactive waste disposal facility located in Clive, Utah. The Clive site receives low-level radioactive waste from various locations within the United States via bulk truck, containerised truck, enclosed truck, bulk rail-cars, rail boxcars, and rail inter-modals. Waste packages are unloaded, characterized, processed, and disposed of at the Clive site. Examples of low-level radioactive waste arriving at Clive include, but are not limited to, contaminated soil/debris, spent nuclear power plant components, and medical waste. Generators of low-level radioactive waste typically include nuclear power plants, hospitals, national laboratories, and various United States government operatedmore » waste sites. Over the past few years, poor economic conditions have significantly reduced the number of shipments to Clive. With less revenue coming in from processing shipments, Clive needed to keep its expenses down if it was going to maintain past levels of profitability. The Operational Research group of EnergySolutions were asked to develop a simulation model to help identify any improvement opportunities that would increase overall operating efficiency and reduce costs at the Clive Facility. The Clive operations research model simulates the receipt, movement, and processing requirements of shipments arriving at the facility. The model includes shipment schedules, processing times of various waste types, labor requirements, shift schedules, and site equipment availability. The Clive operations research model has been developed using the WITNESS{sup TM} process simulation software, which is developed by the Lanner Group. The major goals of this project were to: - identify processing bottlenecks that could reduce the turnaround time from shipment arrival to disposal; - evaluate the use (or idle time) of labor and equipment; - project future operational requirements under different forecasted scenarios. By identifying processing bottlenecks and unused equipment and/or labor, improvements to operating efficiency could be determined and appropriate cost saving measures implemented. Model runs forecasting various scenarios helped illustrate potential impacts of certain conditions (e.g. 20% decrease in shipments arrived), variables (e.g. 20% decrease in labor), or other possible situations. (authors)« less

  16. Development of Alternative Technetium Waste Forms

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Czerwinski, Kenneth

    2013-09-13

    The UREX+1 process is under consideration for the separation of transuranic elements from spent nuclear fuel. The first steps of this process extract the fission product technicium-99 ({sup 99}Tc) into an organic phase containing tributylphosphate together with uranium. Treatment of this stream requires the separation of Tc from U and placement into a suitable waste storage form. A potential candidate waste form involves immobilizing the Tc as an alloy with either excess metallic zirconium or stainless steel. Although Tc-Zr alloys seem to be promising waste forms, alternative materials must be investigated. Innovative studies related to the synthesis and behavior ofmore » a different class of Tc materials will increase the scientific knowledge related to development of Tc waste forms. These studies will also provide a better understanding of the behavior of {sup 99}Tc in repository conditions. A literature survey has selected promising alternative waste forms for further study: technetium metallic alloys, nitrides, oxides, sulfides, and pertechnetate salts. The goals of this project are to 1) synthesize and structurally characterize relevant technetium materials that may be considered as waste forms, 2) investigate material behavior in solution under different conditions of temperature, electrochemical potential, and radiation, and 3) predict the long-term behavior of these materials.« less

  17. Results For The Fourth Quarter 2014 Tank 50 WAC Slurry Sample: Chemical And Radionuclide Contaminants

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Crawford, C.

    2015-09-30

    This report details the chemical and radionuclide contaminant results for the characterization of the Calendar Year (CY) 2014 Fourth Quarter sampling of Tank 50 for the Saltstone Waste Acceptance Criteria (WAC) in effect at that time. Information from this characterization will be used by DWPF & Saltstone Facility Engineering (DSFE) to support the transfer of low-level aqueous waste from Tank 50 to the Salt Feed Tank in the Saltstone Facility in Z-Area, where the waste will be immobilized. This information is also used to update the Tank 50 Waste Characterization System.

  18. CHARACTERIZATION OF ORGANIC EMISSIONS FROM HAZARDOUS WASTE INCINERATION PROCESSES UNDER THE NEW EPA DRAFT RISK BURN GUIDANCE: MEASUREMENT ISSUES

    EPA Science Inventory

    The paper discusses measurement issues relating to the characterization of organic emissions from hazardous waste incineration processes under EPA's new risk burn guidance. The recently published draft quidance recommends that hazardous waste combustion facilities complete a mass...

  19. EVALUATION OF EMISSIONS FROM THE OPEN BURNING OF HOUSEHOLD WASTE IN BARRELS - VOLUME 1. TECHNICAL REPORT

    EPA Science Inventory

    The report gives results of a detailed emissions characterization study undertaken to examine, characterize, and quantify emissions from the simulated burning of household waste in barrels. The study evaluated two waste streams: that of an avid recycler, who removed most of the r...

  20. EVALUATION OF EMISSIONS FROM THE OPEN BURNING OF HOUSEHOLD WASTES IN BARRELS - VOLUME 2. APPENDICES

    EPA Science Inventory

    The report gives results of a detailed emissions characterization study undertaken to examine, characterize, and quantify emissions from the simulated burning of household waste in barrels. The study evaluated two waste streams: that of an avid recycler, who removed most of the r...

  1. Remedial investigation work plan for Bear Creek Valley Operable Unit 2 (Rust Spoil Area, SY-200 Yard, Spoil Area 1) at the Oak Ridge Y-12 Plant, Oak Ridge, Tennessee. Environmental Restoration Program

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Not Available

    1993-05-01

    The enactment of the Resource Conservation and Recovery Act (RCRA) in 1976 and the Hazardous and Solid Waste Amendments (HSWA) to RCRA in 1984 created management requirements for hazardous waste facilities. The facilities within the Oak Ridge Reservation (ORR) were in the process of meeting the RCRA requirements when ORR was placed on the Comprehensive Environmental Response, Compensation, and Liability Act (CERCLA) National Priorities List (NPL) on November 21, 1989. Under RCRA, the actions typically follow the RCRA Facility Assessment (RFA)/RCRA Facility Investigation (RFI)/Corrective Measures Study (CMS)/Corrective Measures implementation process. Under CERCLA the actions follow the PA/SI/Remedial Investigation (RI)/Feasibility Studymore » (FS)/Remedial Design/Remedial Action process. The development of this document will incorporate requirements under both RCRA and CERCLA into an RI work plan for the characterization of Bear Creek Valley (BCV) Operable Unit (OU) 2.« less

  2. Summary Report of Comprehensive Laboratory Testing to Establish the Effectiveness of Proposed Treatment Methods for Unremediated and Remediated Nitrate Salt Waste Streams

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Anast, Kurt Roy; Funk, David John; Hargis, Kenneth Marshall

    The inadvertent creation of transuranic waste carrying hazardous waste codes D001 and D002 requires the treatment of the material to eliminate the hazardous characteristics and allow its eventual shipment and disposal at the Waste Isolation Pilot Plant (WIPP). This report documents the effectiveness of two treatment methods proposed to stabilize both the unremediated and remediated nitrate salt waste streams (UNS and RNS, respectively) at Los Alamos National Laboratory (LANL). The two technologies include the addition of zeolite (with and without the addition of water as a processing aid) and cementation. Surrogates were developed to evaluate both the solid and liquidmore » fractions expected from parent waste containers, and both the solid and liquid fractions were tested. Both technologies are shown to be effective at eliminating the characteristic of ignitability (D001), and the addition of zeolite was determined to be effective at eliminating corrosivity (D002), with the preferred option1 of adding zeolite currently planned for implementation at LANL’s Waste Characterization, Reduction, and Repackaging Facility (WCRRF). The course of this work verified the need to evaluate and demonstrate the effectiveness of the proposed remedy for debris material, if required. The evaluation determined that WypAlls, cheesecloth, and Celotex absorbed with saturated nitrate salt solutions exhibit the ignitability characteristic (all other expected debris is not classified as ignitable). Finally, liquid surrogates containing saturated nitrate salts did not exhibit the characteristic of ignitability in their pure form (those neutralized with Kolorsafe and mixed with sWheat did exhibit D001). Sensitivity testing and an analysis were conducted to evaluate the waste form for reactivity. Tests included subjecting surrogate material to mechanical impact, friction, electrostatic discharge and thermal insults. The testing confirmed that the waste does not exhibit the characteristic of reactivity (D003). Follow-on testing was conducted to demonstrate the effectiveness of zeolite stabilization for ignitable WypAll and cheesecloth debris and additional nitrate salt solutions (those exhibiting the oxidizer characteristic) to demonstrate the effectiveness of the remedy. Follow-on testing also included testing of surrogate materials containing Waste Lock 770, which is present in four of the RNS containers, and potential items of debris such as plywood and Celotex material. Testing to evaluate the effectiveness of the remedy was performed using the specific remediation processes that are planned for use at the WCRRF. Finally, testing was also performed to evaluate the holding capacity of zeolite using a highly acidic surrogate solution and to characterize the composition of gases generated during mixing of zeolite with surrogate solutions. All these tests demonstrated the effectiveness of adding zeolite as the planned remedy.« less

  3. Economic and environmental characterization of an evolving Li-ion battery waste stream.

    PubMed

    Wang, Xue; Gaustad, Gabrielle; Babbitt, Callie W; Bailey, Chelsea; Ganter, Matthew J; Landi, Brian J

    2014-03-15

    While disposal bans of lithium-ion batteries are gaining in popularity, the infrastructure required to recycle these batteries has not yet fully emerged and the economic motivation for this type of recycling system has not yet been quantified comprehensively. This study combines economic modeling and fundamental material characterization methods to quantify economic trade-offs for lithium ion batteries at their end-of-life. Results show that as chemistries transition from lithium-cobalt based cathodes to less costly chemistries, battery recovery value decreases along with the initial value of the raw materials used. For example, manganese-spinel and iron phosphate cathode batteries have potential material values 73% and 79% less than cobalt cathode batteries, respectively. A majority of the potentially recoverable value resides in the base metals contained in the cathode; this increases disassembly cost and time as this is the last portion of the battery taken apart. A great deal of compositional variability exists, even within the same cathode chemistry, due to differences between manufacturers with coefficient of variation up to 37% for some base metals. Cathode changes over time will result in a heavily co-mingled waste stream, further complicating waste management and recycling processes. These results aim to inform disposal, collection, and take-back policies being proposed currently that affect waste management infrastructure as well as guide future deployment of novel recycling techniques. Copyright © 2014 Elsevier Ltd. All rights reserved.

  4. Characterization of Fine Metal Particles Derived from Shredded WEEE Using a Hyperspectral Image System: Preliminary Results

    PubMed Central

    Candiani, Gabriele; Picone, Nicoletta; Pompilio, Loredana; Pepe, Monica; Colledani, Marcello

    2017-01-01

    Waste of electric and electronic equipment (WEEE) is the fastest-growing waste stream in Europe. The large amount of electric and electronic products introduced every year in the market makes WEEE disposal a relevant problem. On the other hand, the high abundance of key metals included in WEEE has increased the industrial interest in WEEE recycling. However, the high variability of materials used to produce electric and electronic equipment makes key metals’ recovery a complex task: the separation process requires flexible systems, which are not currently implemented in recycling plants. In this context, hyperspectral sensors and imaging systems represent a suitable technology to improve WEEE recycling rates and the quality of the output products. This work introduces the preliminary tests using a hyperspectral system, integrated in an automatic WEEE recycling pilot plant, for the characterization of mixtures of fine particles derived from WEEE shredding. Several combinations of classification algorithms and techniques for signal enhancement of reflectance spectra were implemented and compared. The methodology introduced in this study has shown characterization accuracies greater than 95%. PMID:28505070

  5. 40 CFR 265.256 - Special requirements for ignitable or reactive waste.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... TREATMENT, STORAGE, AND DISPOSAL FACILITIES Waste Piles § 265.256 Special requirements for ignitable or reactive waste. (a) Ignitable or reactive waste must not be placed in a pile unless the waste and pile satisfy all applicable requirements of 40 CFR part 268, and: (1) Addition of the waste to an existing pile...

  6. 40 CFR 261.9 - Requirements for Universal Waste.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 40 Protection of Environment 25 2010-07-01 2010-07-01 false Requirements for Universal Waste. 261.9 Section 261.9 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES (CONTINUED) IDENTIFICATION AND LISTING OF HAZARDOUS WASTE General § 261.9 Requirements for Universal Waste...

  7. Environmental and Geotechnical Assessment of the Steel Slags as a Material for Road Structure.

    PubMed

    Sas, Wojciech; Głuchowski, Andrzej; Radziemska, Maja; Dzięcioł, Justyna; Szymański, Alojzy

    2015-07-30

    Slags are the final solid wastes from the steel industry. Their production from waste and associated materials is a proper implementation of the basic objectives and principles of the waste management. This study aims to investigate the chemical and selected significant geotechnical parameters of steel slag as the alternative materials used in road construction. These investigations are strongly desired for successful application in engineering. Young's modules E , and resilient modules M r showed that their values corresponding with requirements for subbase (principal or auxiliary) and riding surface as well. Tested mechanical properties were conducted in soaked and un-soaked (optimal moisture content) conditions. The designated high content of chromium and zinc are strongly associated with the internal crystal structure of steel slag. The results do not lead to threats when they are applied in roads' structures. Mechanical characterization was obtained by performing California bearing ratio (CBR) tests for steel slag in fixed compaction and moisture content conditions. Moreover, cyclic loading of steel slag was conducted with the application of cyclic California bearing ratio (cCBR) apparatus to characterization of this material as a controlled low-strength material. Finally, field studies that consist of static load plate VSS tests were presented.

  8. U.S. Geological Survey research in radioactive waste disposal - Fiscal years 1983, 1984, and 1985

    USGS Publications Warehouse

    Dinwiddie, G.A.; Trask, N.J.

    1986-01-01

    The report summarizes progress on geologic and hydrologic research related to the disposal of radioactive wastes. The research is described according to whether it is related most directly to: (1) high-level and transuranic wastes, (2) low-level wastes, or (3) uranium mill tailings. Included is research applicable to the identification and geohydrologic characterization of waste-disposal sites, to investigations of specific sites where wastes have been stored, and to studies of regions or environments where waste-disposal sites might be located. A significant part of the activity is concerned with techniques and methods for characterizing disposal sites and studies of geologic and hydrologic processes related to the transport and (or) retention of waste radionuclides.

  9. DOE Office of Scientific and Technical Information (OSTI.GOV)

    Osmanlioglu, Ahmet Erdal

    Pre-treatment of radioactive waste is the first step in waste management program that occurs after waste generation from various applications in Turkey. Pre-treatment and characterization practices are carried out in Radioactive Waste Management Unit (RWMU) at Cekmece Nuclear Research and Training Center (CNRTC) in Istanbul. This facility has been assigned to take all low-level radioactive wastes generated by nuclear applications in Turkey. The wastes are generated from research and nuclear applications mainly in medicine, biology, agriculture, quality control in metal processing and construction industries. These wastes are classified as low- level radioactive wastes. Pre-treatment practices cover several steps. In thismore » paper, main steps of pre-treatment and characterization are presented. Basically these are; collection, segregation, chemical adjustment, size reduction and decontamination operations. (author)« less

  10. Assessment of multiple geophysical techniques for the characterization of municipal waste deposit sites

    NASA Astrophysics Data System (ADS)

    Gaël, Dumont; Tanguy, Robert; Nicolas, Marck; Frédéric, Nguyen

    2017-10-01

    In this study, we tested the ability of geophysical methods to characterize a large technical landfill installed in a former sand quarry. The geophysical surveys specifically aimed at delimitating the deposit site horizontal extension, at estimating its thickness and at characterizing the waste material composition (the moisture content in the present case). The site delimitation was conducted with electromagnetic (in-phase and out-of-phase) and magnetic (vertical gradient and total field) methods that clearly showed the transition between the waste deposit and the host formation. Regarding waste deposit thickness evaluation, electrical resistivity tomography appeared inefficient on this particularly thick deposit site. Thus, we propose a combination of horizontal to vertical noise spectral ratio (HVNSR) and multichannel analysis of the surface waves (MASW), which successfully determined the approximate waste deposit thickness in our test landfill. However, ERT appeared to be an appropriate tool to characterize the moisture content of the waste, which is of prior information for the organic waste biodegradation process. The global multi-scale and multi-method geophysical survey offers precious information for site rehabilitation studies, water content mitigation processes for enhanced biodegradation or landfill mining operation planning.

  11. Impact of Water Recovery from Wastes on the Lunar Surface Mission Water Balance

    NASA Technical Reports Server (NTRS)

    Fisher, John W.; Hogan, John Andrew; Wignarajah, Kanapathipi; Pace, Gregory S.

    2010-01-01

    Future extended lunar surface missions will require extensive recovery of resources to reduce mission costs and enable self-sufficiency. Water is of particular importance due to its potential use for human consumption and hygiene, general cleaning, clothes washing, radiation shielding, cooling for extravehicular activity suits, and oxygen and hydrogen production. Various water sources are inherently present or are generated in lunar surface missions, and subject to recovery. They include: initial water stores, water contained in food, human and other solid wastes, wastewaters and associated brines, ISRU water, and scavenging from residual propellant in landers. This paper presents the results of an analysis of the contribution of water recovery from life support wastes on the overall water balance for lunar surface missions. Water in human wastes, metabolic activity and survival needs are well characterized and dependable figures are available. A detailed life support waste model was developed that summarizes the composition of life support wastes and their water content. Waste processing technologies were reviewed for their potential to recover that water. The recoverable water in waste is a significant contribution to the overall water balance. The value of this contribution is discussed in the context of the other major sources and loses of water. Combined with other analyses these results provide guidance for research and technology development and down-selection.

  12. Planning for the recreational end use of a future LLR waste mound in Canada - Leaving an honourable legacy

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Kleb, H.R.; Zelmer, R.L.

    2007-07-01

    The Low-Level Radioactive Waste Management Office was established in 1982 to carry out the federal government's responsibilities for low-level radioactive (LLR) waste management in Canada. In this capacity, the Office operates programs to characterize, delineate, decontaminate and consolidate historic LLR waste for interim and long-term storage. The Office is currently the proponent of the Port Hope Area Initiative; a program directed at the development and implementation of a safe, local long-term management solution for historic LLR waste in the Port Hope area. A legal agreement between the Government of Canada and the host community provides the framework for the implementationmore » of the Port Hope Project. Specifically, the agreement requires that the surface of the long-term LLR waste management facility be 'conducive to passive and active recreational uses such as soccer fields and baseball diamonds'. However, there are currently no examples of licensed LLR waste management facilities in Canada that permit recreational use. Such an end use presents challenges with respect to engineering and design, health and safety and landscape planning. This paper presents the cover system design, the environmental effects assessment and the landscape planning processes that were undertaken in support of the recreational end use of the Port Hope long-term LLR waste management facility. (authors)« less

  13. 40 CFR 63.1092 - What are the major differences between the requirements of 40 CFR part 61, subpart FF, and the...

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... the requirements of 40 CFR part 61, subpart FF, and the waste requirements for ethylene production... Waste Operations Background for Waste Requirements § 63.1092 What are the major differences between the requirements of 40 CFR part 61, subpart FF, and the waste requirements for ethylene production sources? The...

  14. Ecotoxicological characterization of hazardous wastes.

    PubMed

    Wilke, B-M; Riepert, F; Koch, Christine; Kühne, T

    2008-06-01

    In Europe hazardous wastes are classified by 14 criteria including ecotoxicity (H 14). Standardized methods originally developed for chemical and soil testing were adapted for the ecotoxicological characterization of wastes including leachate and solid phase tests. A consensus on which tests should be recommended as mandatory is still missing. Up to now, only a guidance on how to proceed with the preparation of waste materials has been standardized by CEN as EN 14735. In this study, tests including higher plants, earthworms, collembolans, microorganisms, duckweed and luminescent bacteria were selected to characterize the ecotoxicological potential of a boiler slag, a dried sewage sludge, a thin sludge and a waste petrol. In general, the instructions given in EN 14735 were suitable for all wastes used. The evaluation of the different test systems by determining the LC/EC(50) or NOEC-values revealed that the collembolan reproduction and the duckweed frond numbers were the most sensitive endpoints. For a final classification and ranking of wastes the Toxicity Classification System (TCS) using EC/LC(50) values seems to be appropriate.

  15. 76 FR 53897 - EPA Seeking Input Materials Measurement; Municipal Solid Waste (MSW), Recycling, and Source...

    Federal Register 2010, 2011, 2012, 2013, 2014

    2011-08-30

    ... stakeholder input regarding the efficacy and scope of the MSW Characterization Report called ``Municipal Solid Waste in the United States'' as part of a broader discussion about sustainable materials management... efficacy and scope of the MSW Characterization Report called ``Municipal Solid Waste in the United States...

  16. 10 CFR 61.58 - Alternative requirements for waste classification and characteristics.

    Code of Federal Regulations, 2014 CFR

    2014-01-01

    ... LAND DISPOSAL OF RADIOACTIVE WASTE Technical Requirements for Land Disposal Facilities § 61.58 Alternative requirements for waste classification and characteristics. The Commission may, upon request or on... 10 Energy 2 2014-01-01 2014-01-01 false Alternative requirements for waste classification and...

  17. 10 CFR 61.58 - Alternative requirements for waste classification and characteristics.

    Code of Federal Regulations, 2012 CFR

    2012-01-01

    ... LAND DISPOSAL OF RADIOACTIVE WASTE Technical Requirements for Land Disposal Facilities § 61.58 Alternative requirements for waste classification and characteristics. The Commission may, upon request or on... 10 Energy 2 2012-01-01 2012-01-01 false Alternative requirements for waste classification and...

  18. 10 CFR 61.58 - Alternative requirements for waste classification and characteristics.

    Code of Federal Regulations, 2010 CFR

    2010-01-01

    ... LAND DISPOSAL OF RADIOACTIVE WASTE Technical Requirements for Land Disposal Facilities § 61.58 Alternative requirements for waste classification and characteristics. The Commission may, upon request or on... 10 Energy 2 2010-01-01 2010-01-01 false Alternative requirements for waste classification and...

  19. 10 CFR 61.58 - Alternative requirements for waste classification and characteristics.

    Code of Federal Regulations, 2013 CFR

    2013-01-01

    ... LAND DISPOSAL OF RADIOACTIVE WASTE Technical Requirements for Land Disposal Facilities § 61.58 Alternative requirements for waste classification and characteristics. The Commission may, upon request or on... 10 Energy 2 2013-01-01 2013-01-01 false Alternative requirements for waste classification and...

  20. 10 CFR 61.58 - Alternative requirements for waste classification and characteristics.

    Code of Federal Regulations, 2011 CFR

    2011-01-01

    ... LAND DISPOSAL OF RADIOACTIVE WASTE Technical Requirements for Land Disposal Facilities § 61.58 Alternative requirements for waste classification and characteristics. The Commission may, upon request or on... 10 Energy 2 2011-01-01 2011-01-01 false Alternative requirements for waste classification and...

  1. Work plan for the radiological survey for the David Witherspoon, Incorporated, Landfill-1630 site, Knoxville, Tennessee

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    NONE

    1996-07-01

    This work plan establishes the methods and requirements for performing a radiological survey at the David Witherspoon, Incorporated, Landfill-1630 Site, Knoxville, Tennessee (DWI 1630 Site) in accordance with requirements under the Comprehensive Environmental Response, Compensation, and Liability Act of 1980 (CERCLA). The radiological survey will identify the radiological contamination level of the equipment and debris stored at the DWI 1630 Site. The data generated from the survey activities will support the decisions for characterization of the equipment/debris and aid in subsequent disposition and waste handling. The survey activities to be performed under this work plan include an equipment radiological survey,more » a walkover survey, and an immunoassay testing for polychlorinated biphenyls (PCBs). This work plan includes a quality assurance (QA)/quality control (QC) project plan, a health and safety (H&S) plan, and a waste management plan.« less

  2. Leaching of lead from computer printed wire boards and cathode ray tubes by municipal solid waste landfill leachates.

    PubMed

    Jang, Yong-Chul; Townsend, Timothy G

    2003-10-15

    The proper management of discarded electronic devices (E-waste) is an important issue for solid waste professionals because of the magnitude of the waste stream and because these devices often contain a variety of toxic metals (e.g., lead). While recycling of E-waste is developing, much of this waste stream is disposed in landfills. Leaching tests are frequently used to characterize the potential of a solid waste to leach when disposed in a landfill. In the United States, the Toxicity Characteristic Leaching Procedure (TCLP) is used to determine whether a solid waste is a hazardous waste by the toxicity characteristic. The TCLP is designed to simulate worse-case leaching in a landfill environment where the waste is co-disposed with municipal solid waste (MSW). While the TCLP is a required analysis from a regulatory perspective, the leachate concentrations measured may not accurately reflect the concentrations observed under typical landfill conditions. Another method that can be performed to assess the degree a pollutant might leach from a waste in a landfill is to use actual landfill leachate as the leaching solution. In this study, two lead-containing components found in electronic devices (printed wire boards from computers and cathode ray tubes from computers and televisions) were leached using the TCLP and leachates from 11 Florida landfills. California's Waste Extraction Test (WET) and the Synthetic Precipitation Leaching Procedure were also performed. The results indicated that the extractions using MSW landfill leachates resulted in lower lead concentrations than those by the TCLP. The pH of the leaching solution and the ability of the organic acids in the TCLP and WET to complex with the lead are factors that regulate the amount of lead leached.

  3. Closure Report for Corrective Action Unit 151: Septic Systems and Discharge Area, Nevada Test Site, Nevada

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    NSTec Environmental Restoration

    2008-04-01

    Corrective Action Unit (CAU) 151 is identified in the Federal Facility Agreement and Consent Order (FFACO) as Septic Systems and Discharge Area. CAU 151 consists of the following eight Corrective Action Sites (CASs), located in Areas 2, 12, and 18 of the Nevada Test Site, approximately 65 miles northwest of Las Vegas, Nevada: (1) CAS 02-05-01, UE-2ce Pond; (2) CAS 12-03-01, Sewage Lagoons (6); (3) CAS 12-04-01, Septic Tanks; (4) CAS 12-04-02, Septic Tanks; (5) CAS 12-04-03, Septic Tank; (6) CAS 12-47-01, Wastewater Pond; (7) CAS 18-03-01, Sewage Lagoon; and (8) CAS 18-99-09, Sewer Line (Exposed). CAU 151 closure activitiesmore » were conducted according to the FFACO (FFACO, 1996; as amended February 2008) and the Corrective Action Plan for CAU 151 (U.S. Department of Energy, National Nuclear Security Administration Nevada Site Office, 2007) from October 2007 to January 2008. The corrective action alternatives included no further action, clean closure, and closure in place with administrative controls. CAU 151 closure activities are summarized in Table 1. Closure activities generated liquid remediation waste, sanitary waste, hydrocarbon waste, and mixed waste. Waste generated was appropriately managed and disposed. Waste that is currently staged onsite is being appropriately managed and will be disposed under approved waste profiles in permitted landfills. Waste minimization activities included waste characterization sampling and segregation of waste streams. Some waste exceeded land disposal restriction limits and required offsite treatment prior to disposal. Other waste meeting land disposal restrictions was disposed of in appropriate onsite or offsite landfills. Waste disposition documentation is included as Appendix C.« less

  4. 40 CFR 264.256 - Special requirements for ignitable or reactive waste.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ..., AND DISPOSAL FACILITIES Waste Piles § 264.256 Special requirements for ignitable or reactive waste. Ignitable or reactive waste must not be placed in a waste pile unless the waste and waste pile satisfy all... immediately after placement in the pile so that: (1) The resulting waste, mixture, or dissolution of material...

  5. Preliminary study to characterize plastic polymers using elemental analyser/isotope ratio mass spectrometry (EA/IRMS).

    PubMed

    Berto, Daniela; Rampazzo, Federico; Gion, Claudia; Noventa, Seta; Ronchi, Francesca; Traldi, Umberto; Giorgi, Giordano; Cicero, Anna Maria; Giovanardi, Otello

    2017-06-01

    Plastic waste is a growing global environmental problem, particularly in the marine ecosystems, in consideration of its persistence. The monitoring of the plastic waste has become a global issue, as reported by several surveillance guidelines proposed by Regional Sea Conventions (OSPAR, UNEP) and appointed by the EU Marine Strategy Framework Directive. Policy responses to plastic waste vary at many levels, ranging from beach clean-up to bans on the commercialization of plastic bags and to Regional Plans for waste management and recycling. Moreover, in recent years, the production of plant-derived biodegradable plastic polymers has assumed increasing importance. This study reports the first preliminary characterization of carbon stable isotopes (δ 13 C) of different plastic polymers (petroleum- and plant-derived) in order to increase the dataset of isotopic values as a tool for further investigation in different fields of polymers research as well as in the marine environment surveillance. The δ 13 C values determined in different packaging for food uses reflect the plant origin of "BIO" materials, whereas the recycled plastic materials displayed a δ 13 C signatures between plant- and petroleum-derived polymers source. In a preliminary estimation, the different colours of plastic did not affect the variability of δ 13 C values, whereas the abiotic and biotic degradation processes that occurred in the plastic materials collected on beaches and in seawater, showed less negative δ 13 C values. A preliminary experimental field test confirmed these results. The advantages offered by isotope ratio mass spectrometry with respect to other analytical methods used to characterize the composition of plastic polymers are: high sensitivity, small amount of material required, rapidity of analysis, low cost and no limitation in black/dark samples compared with spectroscopic analysis. Copyright © 2017 Elsevier Ltd. All rights reserved.

  6. Issues that Drive Waste Management Technology Development for Space Missions

    NASA Technical Reports Server (NTRS)

    Fisher, John W.; Levri, Julie A.; Hogan, John A.; Wignarajah, Kanapathipillai

    2005-01-01

    Waste management technologies for space life support systems are currently at low development levels. Manual compaction of waste in plastic bags and overboard disposal to earth return vehicles are the primary current waste management methods. Particularly on future missions, continuance of current waste management methods would tend to expose the crew to waste hazards, forfeit recoverable resources such as water, consume valuable crew time, contaminate planetary surfaces, and risk return to Earth of extraterrestrial life. Improvement of waste management capabilities is needed for adequate management of wastes. Improvements include recovery of water and other resources, conversion of waste to states harmless to humans, long-term containment of wastes, and disposal of waste. Current NASA requirements documents on waste management are generally not highly detailed. More detailed requirements are needed to guide the development of waste management technologies that will adequately manage waste. In addition to satisfying requirements, waste management technologies must also recover resources. Recovery of resources such as water and habitat volume can reduce mission cost. This paper explores the drivers for waste management technology development including requirements and resource recovery.

  7. Characterization of urban waste management practices in developing Asian countries: A new analytical framework based on waste characteristics and urban dimension.

    PubMed

    Aleluia, João; Ferrão, Paulo

    2016-12-01

    This paper characterizes municipal solid waste (MSW) management practices in developing Asia, with a focus on low and middle-income countries. The analysis that is conducted supports a proposed framework that maps out the trends observed in the region in relation to two parameters, waste compositions and urban dimension, which was prepared based on a set of national and urban case studies. The management of MSW in developing Asian countries is driven, first and foremost, by a public health imperative: the collection and disposal of waste in order to avoid the spread of disease vectors from uncollected waste. This comes, however, at a high cost, with local government authorities in these countries spending up to 50% of their budgets in the provision of these services. Little or no value is derived from waste, which is typically seen as a liability and not as a resource that can be harnessed. On the other hand, in many cities in developing Asia there is an informal sector that ekes out a living from the recovery of recyclable materials found in waste. Members of this "informal waste sector" are especially active in areas that are not served by formal waste collection systems, such as slums or squatter areas. A distinctive element shared among many cities in developing Asian countries concerns the composition of the municipal solid waste. MSW in those countries tends to be richer in biodegradable organic matter, which usually accounts for more than 50% of the total waste composition, suggesting that biological methods are more appropriate for treating this organic fraction. Conversely, thermal combustion technologies, which are extensively applied in high-income countries, are technically and economically challenging to deploy in light of the lower calorific value of waste streams which are rich in organics and moisture. Specific approaches and methods are therefore required for designing adequate waste management systems in developing Asian countries. In addition, despite some common characteristics shared among cities in developing Asia, their specific circumstances can significantly vary, even within the same country, calling for the need for context-specific waste management approaches. Set against this background, this paper proposes a guiding framework in the form of a matrix that maps out approaches observed in the management of municipal solid waste in cities of developing Asian countries as a function of the city dimension, share of organics on waste streams, and wealth generated by the city. The cities of Surabaya (Indonesia), Bangalore (India), Quy Nhon (Viet Nam), and Matale (Sri Lanka) are showcased as good practices in the region in the management of solid waste, with their experiences used to illustrate the framework laid out in the matrix. Copyright © 2016 Elsevier Ltd. All rights reserved.

  8. Geohydrologic aspects for siting and design of low-level radioactive-waste disposal

    USGS Publications Warehouse

    Bedinger, M.S.

    1989-01-01

    The objective for siting and design of low-level radioactive-waste repository sites is to isolate the waste from the biosphere until the waste no longer poses an unacceptable hazard as a result of radioactive decay. Low-level radioactive waste commonly is isolated at shallow depths with various engineered features to stabilize the waste and to reduce its dissolution and transport by ground water. The unsaturated zone generally is preferred for isolating the waste. Low-level radioactive waste may need to be isolated for 300 to 500 years. Maintenance and monitoring of the repository site are required by Federal regulations for only the first 100 years. Therefore, geohydrology of the repository site needs to provide natural isolation of the waste for the hazardous period following maintenance of the site. Engineering design of the repository needs to be compatible with the natural geohydrologic conditions at the site. Studies at existing commercial and Federal waste-disposal sites provide information on the problems encountered and the basis for establishing siting guidelines for improved isolation of radioactive waste, engineering design of repository structures, and surveillance needs to assess the effectiveness of the repositories and to provide early warning of problems that may require remedial action.Climate directly affects the hydrology of a site and probably is the most important single factor that affects the suitability of a site for shallow-land burial of low-level radioactive waste. Humid and subhumid regions are not well suited for shallow isolation of low-level radioactive waste in the unsaturated zone; arid regions with zero to small infiltration from precipitation, great depths to the water table, and long flow paths to natural discharge areas are naturally well suited to isolation of the waste. The unsaturated zone is preferred for isolation of low-level radioactive waste. The guiding rationale is to minimize contact of water with the waste and to minimize transport of waste from the repository. The hydrology of a flow system containing a repository is greatly affected by the engineering of the repository site. Prediction of the performance of the repository is a complex problem, hampered by problems of characterizing the natural and manmade features of the flow system and by the limitations of models to predict flow and geochemical processes in the saturated and unsaturated zones. Disposal in low-permeability unfractured clays in the saturated zone may be feasible where the radionuclide transport is controlled by diffusion rather than advection.

  9. 30 CFR 816.81 - Coal mine waste: General requirements.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... 30 Mineral Resources 3 2012-07-01 2012-07-01 false Coal mine waste: General requirements. 816.81... ACTIVITIES § 816.81 Coal mine waste: General requirements. (a) General. All coal mine waste disposed of in an... within a permit area, which are approved by the regulatory authority for this purpose. Coal mine waste...

  10. 30 CFR 817.81 - Coal mine waste: General requirements.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... 30 Mineral Resources 3 2012-07-01 2012-07-01 false Coal mine waste: General requirements. 817.81... ACTIVITIES § 817.81 Coal mine waste: General requirements. (a) General. All coal mine waste disposed of in an... within a permit area, which are approved by the regulatory authority for this purpose. Coal mine waste...

  11. 30 CFR 817.81 - Coal mine waste: General requirements.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 30 Mineral Resources 3 2011-07-01 2011-07-01 false Coal mine waste: General requirements. 817.81... ACTIVITIES § 817.81 Coal mine waste: General requirements. (a) General. All coal mine waste disposed of in an... within a permit area, which are approved by the regulatory authority for this purpose. Coal mine waste...

  12. 30 CFR 816.81 - Coal mine waste: General requirements.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 30 Mineral Resources 3 2013-07-01 2013-07-01 false Coal mine waste: General requirements. 816.81... ACTIVITIES § 816.81 Coal mine waste: General requirements. (a) General. All coal mine waste disposed of in an... within a permit area, which are approved by the regulatory authority for this purpose. Coal mine waste...

  13. 30 CFR 817.81 - Coal mine waste: General requirements.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 30 Mineral Resources 3 2013-07-01 2013-07-01 false Coal mine waste: General requirements. 817.81... ACTIVITIES § 817.81 Coal mine waste: General requirements. (a) General. All coal mine waste disposed of in an... within a permit area, which are approved by the regulatory authority for this purpose. Coal mine waste...

  14. 30 CFR 816.81 - Coal mine waste: General requirements.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 30 Mineral Resources 3 2010-07-01 2010-07-01 false Coal mine waste: General requirements. 816.81... ACTIVITIES § 816.81 Coal mine waste: General requirements. (a) General. All coal mine waste disposed of in an... within a permit area, which are approved by the regulatory authority for this purpose. Coal mine waste...

  15. 30 CFR 816.81 - Coal mine waste: General requirements.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 30 Mineral Resources 3 2011-07-01 2011-07-01 false Coal mine waste: General requirements. 816.81... ACTIVITIES § 816.81 Coal mine waste: General requirements. (a) General. All coal mine waste disposed of in an... within a permit area, which are approved by the regulatory authority for this purpose. Coal mine waste...

  16. 30 CFR 816.81 - Coal mine waste: General requirements.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 30 Mineral Resources 3 2014-07-01 2014-07-01 false Coal mine waste: General requirements. 816.81... ACTIVITIES § 816.81 Coal mine waste: General requirements. (a) General. All coal mine waste disposed of in an... within a permit area, which are approved by the regulatory authority for this purpose. Coal mine waste...

  17. 30 CFR 817.81 - Coal mine waste: General requirements.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 30 Mineral Resources 3 2014-07-01 2014-07-01 false Coal mine waste: General requirements. 817.81... ACTIVITIES § 817.81 Coal mine waste: General requirements. (a) General. All coal mine waste disposed of in an... within a permit area, which are approved by the regulatory authority for this purpose. Coal mine waste...

  18. 30 CFR 817.81 - Coal mine waste: General requirements.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 30 Mineral Resources 3 2010-07-01 2010-07-01 false Coal mine waste: General requirements. 817.81... ACTIVITIES § 817.81 Coal mine waste: General requirements. (a) General. All coal mine waste disposed of in an... within a permit area, which are approved by the regulatory authority for this purpose. Coal mine waste...

  19. DOE Office of Scientific and Technical Information (OSTI.GOV)

    Dehmel, J.C.; Loomis, D.; Mauro, J.

    Under contract to the US Nuclear Regulatory Commission, Office of Nuclear Regulatory Research, the firms of S. Cohen & Associates, Inc. (SC&A) and Eastern Research Group (ERG) have compiled a report that describes the physical, chemical, and radiological properties of Class-A low-level radioactive waste. The report also presents information characterizing various methods and facilities used to treat and dispose non-radioactive waste. A database management program was developed for use in accessing, sorting, analyzing, and displaying the electronic data provided by EG&G. The program was used to present and aggregate data characterizing the radiological, physical, and chemical properties of the wastemore » from descriptions contained in shipping manifests. The data thus retrieved are summarized in tables, histograms, and cumulative distribution curves presenting radionuclide concentration distributions in Class-A waste as a function of waste streams, by category of waste generators, and regions of the United States. The report also provides information characterizing methods and facilities used to treat and dispose non-radioactive waste, including industrial, municipal, and hazardous waste regulated under Subparts C and D of the Resource Conservation and Recovery Act (RCRA). The information includes a list of disposal options, the geographical locations of the processing and disposal facilities, and a description of the characteristics of such processing and disposal facilities. Volume 1 contains the Executive Summary, Volume 2 presents the Class-A waste database, Volume 3 presents the information characterizing non-radioactive waste management practices and facilities, and Volumes 4 through 7 contain Appendices A through P with supporting information.« less

  20. 40 CFR 268.36 - Waste specific prohibitions-inorganic chemical wastes

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ...) SOLID WASTES (CONTINUED) LAND DISPOSAL RESTRICTIONS Prohibitions on Land Disposal § 268.36 Waste... radioactive wastes mixed with these wastes are prohibited from land disposal. (b) The requirements of... applicable subpart D levels, the waste is prohibited from land disposal, and all requirements of this part...

  1. 40 CFR 268.36 - Waste specific prohibitions-inorganic chemical wastes

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ...) SOLID WASTES (CONTINUED) LAND DISPOSAL RESTRICTIONS Prohibitions on Land Disposal § 268.36 Waste... radioactive wastes mixed with these wastes are prohibited from land disposal. (b) The requirements of... applicable subpart D levels, the waste is prohibited from land disposal, and all requirements of this part...

  2. 40 CFR 268.36 - Waste specific prohibitions-inorganic chemical wastes

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ...) SOLID WASTES (CONTINUED) LAND DISPOSAL RESTRICTIONS Prohibitions on Land Disposal § 268.36 Waste... radioactive wastes mixed with these wastes are prohibited from land disposal. (b) The requirements of... applicable subpart D levels, the waste is prohibited from land disposal, and all requirements of this part...

  3. 40 CFR 268.36 - Waste specific prohibitions-inorganic chemical wastes.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ...) SOLID WASTES (CONTINUED) LAND DISPOSAL RESTRICTIONS Prohibitions on Land Disposal § 268.36 Waste... radioactive wastes mixed with these wastes are prohibited from land disposal. (b) The requirements of... applicable subpart D levels, the waste is prohibited from land disposal, and all requirements of this part...

  4. 40 CFR 268.33 - Waste specific prohibitions-chlorinated aliphatic wastes.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... (CONTINUED) SOLID WASTES (CONTINUED) LAND DISPOSAL RESTRICTIONS Prohibitions on Land Disposal § 268.33 Waste... wastes mixed with these wastes are prohibited from land disposal. (b) The requirements of paragraph (a... levels of subpart D of this part, the waste is prohibited from land disposal, and all requirements of...

  5. 40 CFR 268.33 - Waste specific prohibitions-chlorinated aliphatic wastes.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... (CONTINUED) SOLID WASTES (CONTINUED) LAND DISPOSAL RESTRICTIONS Prohibitions on Land Disposal § 268.33 Waste... wastes mixed with these wastes are prohibited from land disposal. (b) The requirements of paragraph (a... levels of subpart D of this part, the waste is prohibited from land disposal, and all requirements of...

  6. 40 CFR 268.33 - Waste specific prohibitions-chlorinated aliphatic wastes.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... (CONTINUED) SOLID WASTES (CONTINUED) LAND DISPOSAL RESTRICTIONS Prohibitions on Land Disposal § 268.33 Waste... wastes mixed with these wastes are prohibited from land disposal. (b) The requirements of paragraph (a... levels of subpart D of this part, the waste is prohibited from land disposal, and all requirements of...

  7. 40 CFR 268.36 - Waste specific prohibitions-inorganic chemical wastes.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ...) SOLID WASTES (CONTINUED) LAND DISPOSAL RESTRICTIONS Prohibitions on Land Disposal § 268.36 Waste... radioactive wastes mixed with these wastes are prohibited from land disposal. (b) The requirements of... applicable subpart D levels, the waste is prohibited from land disposal, and all requirements of this part...

  8. 40 CFR 268.33 - Waste specific prohibitions-chlorinated aliphatic wastes.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... (CONTINUED) SOLID WASTES (CONTINUED) LAND DISPOSAL RESTRICTIONS Prohibitions on Land Disposal § 268.33 Waste... wastes mixed with these wastes are prohibited from land disposal. (b) The requirements of paragraph (a... levels of subpart D of this part, the waste is prohibited from land disposal, and all requirements of...

  9. 40 CFR 268.33 - Waste specific prohibitions-chlorinated aliphatic wastes.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... (CONTINUED) SOLID WASTES (CONTINUED) LAND DISPOSAL RESTRICTIONS Prohibitions on Land Disposal § 268.33 Waste... wastes mixed with these wastes are prohibited from land disposal. (b) The requirements of paragraph (a... levels of subpart D of this part, the waste is prohibited from land disposal, and all requirements of...

  10. Potential application of microsensor technology in radioactive waste management with emphasis on headspace gas detection.

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Davis, Chad Edward; Thomas, Michael Loren; Wright, Jerome L.

    2004-09-01

    Waste characterization is probably the most costly part of radioactive waste management. An important part of this characterization is the measurements of headspace gas in waste containers in order to demonstrate the compliance with Resource Conservation and Recovery Act (RCRA) or transportation requirements. The traditional chemical analysis methods, which include all steps of gas sampling, sample shipment and laboratory analysis, are expensive and time-consuming as well as increasing worker's exposure to hazardous environments. Therefore, an alternative technique that can provide quick, in-situ, and real-time detections of headspace gas compositions is highly desirable. This report summarizes the results obtained from amore » Laboratory Directed Research & Development (LDRD) project entitled 'Potential Application of Microsensor Technology in Radioactive Waste Management with Emphasis on Headspace Gas Detection'. The objective of this project is to bridge the technical gap between the current status of microsensor development and the intended applications of these sensors in nuclear waste management. The major results are summarized below: {sm_bullet} A literature review was conducted on the regulatory requirements for headspace gas sampling/analysis in waste characterization and monitoring. The most relevant gaseous species and the related physiochemical environments were identified. It was found that preconcentrators might be needed in order for chemiresistor sensors to meet desired detection {sm_bullet} A long-term stability test was conducted for a polymer-based chemresistor sensor array. Significant drifts were observed over the time duration of one month. Such drifts should be taken into account for long-term in-situ monitoring. {sm_bullet} Several techniques were explored to improve the performance of sensor polymers. It has been demonstrated that freeze deposition of black carbon (CB)-polymer composite can effectively eliminate the so-called 'coffee ring' effect and lead to a desirable uniform distribution of CB particles in sensing polymer films. The optimal ratio of CB/polymer has been determined. UV irradiation has been shown to improve sensor sensitivity. {sm_bullet} From a large set of commercially available polymers, five polymers were selected to form a sensor array that was able to provide optimal responses to six target-volatile organic compounds (VOCs). A series of tests on the response of sensor array to various VOC concentrations have been performed. Linear sensor responses have been observed over the tested concentration ranges, although the responses over a whole concentration range are generally nonlinear. {sm_bullet} Inverse models have been developed for identifying individual VOCs based on sensor array responses. A linear solvation energy model is particularly promising for identifying an unknown VOC in a single-component system. It has been demonstrated that a sensor array as such we developed is able to discriminate waste containers for their total VOC concentrations and therefore can be used as screening tool for reducing the existing headspace gas sampling rate. {sm_bullet} Various VOC preconcentrators have been fabricated using Carboxen 1000 as an absorbent. Extensive tests have been conducted in order to obtain optimal configurations and parameter ranges for preconcentrator performance. It has been shown that use of preconcentrators can reduce the detection limits of chemiresistors by two orders of magnitude. The life span of preconcentrators under various physiochemical conditions has also been evaluated. {sm_bullet} The performance of Pd film-based H2 sensors in the presence of VOCs has been evaluated. The interference of sensor readings by VOC has been observed, which can be attributed to the interference of VOC with the H2-O2 reaction on the Pd alloy surface. This interference can be eliminated by coating a layer of silicon dioxide on sensing film surface. Our work has demonstrated a wide range of applications of gas microsensors in radioactive waste management. Such applications can potentially lead to a significant cost saving and risk reduction for waste characterization.« less

  11. 40 CFR 262.52 - General requirements.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 262.52 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES (CONTINUED) STANDARDS APPLICABLE TO GENERATORS OF HAZARDOUS WASTE Exports of Hazardous Waste § 262.52 General requirements. Exports of hazardous waste are prohibited except in compliance with the applicable requirements...

  12. Properties of Clay for Ceramics with Rock Waste for Production Structural Block by Pressing and Firing

    NASA Astrophysics Data System (ADS)

    Cerqueira, N. A.; Choe, D.; Alexandre, J.; Azevedo, A. R. G.; Xavier, C. G.; Souza, V. B.

    Building work requires optimization of materials and labor, so that the execution of its subsystems contribute to the quality, reduce costs, decrease waste in buildings, productivity, practicality and especially agility. Thus, the fitting blocks can contribute in this direction. This work therefore consists of physical characterization (determination of fitness levels, grain size and bulk density), chemical (EDX) and thermal (DTA and TGA) sample clay Campos dos Goytacazes-RJ and waste rock ornamental Cachoeiro de Itapemirim-ES, to verify potential for producing red ceramic blocks, pressed and burned, male and female type. The output of block will be with different pe rcentages of incorporation of residues of ornamental rocks (0%, 5% and 10%). With the results obtained, it was found that the raw materials under consideration has the potential for application in the production of ceramic articles.

  13. DOE Office of Scientific and Technical Information (OSTI.GOV)

    Riley, Brian J.; Kroll, Jared O.; Peterson, Jacob A.

    This paper provides an overview of research evaluating the use of tellurite glass as a waste form for salt wastes from electrochemical processing. The capacities to immobilize different salts were evaluated including: a LiCl-Li2O oxide reduction salt (for oxide fuel) containing fission products, a LiCl-KCl eutectic salt (for metallic fuel) containing fission products, and SrCl2. Physical and chemical properties of the glasses were characterized by using X-ray diffraction, bulk density measurements, chemical durability tests, scanning electron microscopy, and energy dispersive X-ray emission spectroscopy. These glasses were found to accommodate high concentrations of halide salts and have high densities. However, improvementsmore » are needed to meet chemical durability requirements.« less

  14. Assessment of sanitary landfill leachate characterizations and its impacts on groundwater at Alexandria.

    PubMed

    Hassan, Ahmed Hossam; Ramadan, Mohamed Hassan

    2005-01-01

    The total amount of solid waste generated in Alexandria is 2820 tons/d which increases to 3425 tons/day during summer. In the past, 77% of the collected solid wastes was open dumped. The open dumping sites did not have the minimum requirements for pollution control. Following the exacerbation of the problem, the Alexandria Governorate contracted a company to carry out the solid waste management. The contracted company transferred 75% of the daily generated solid wastes to a new constructed sanitary lanfill. The site receives a daily average of 1910 tons. The landfilling is performed by trench method in the form of cells. The produced leachate is discharged into two lined aerated lagoons. The biogas formed from biodegradation of landfilled solid wastes is burned and the produced heat is used for drying the lagoons leachate. The remaining residues are relandfilled. The study aims at assessment of the solid waste sanitary landfill leachate characterization and its impacts on the groundwater. The analysis of the collected data confirms that leachates from the landfill are severely contaminated with organics, salts, and heavy metals. The fluctuations in concentration levels of the different parameters were attributed to aging and thickness of waste layers, stage of decomposition, and re-landfilling of the concentrated residues from the drying lagoons. The concentrations of NH4-N (600 mg/l) indicated that the process of stabilization was still in the initial stages and attributed to the compaction process. The high BOD5 results (28,833 mg/l) indicated that the process of stabilization was in the initial stages which were very slow. The high COD results (45,240 mg/l) can be attributed to the compaction of the wastes which also retards the degradation of the solid wastes. The BOD and COD values indicated clearly severe contamination. The BOD5/COD ratio measured in the current study (0.64) indicated that the leachate of the present study was biodegradable and unstabilized, and required time and favourable conditions for anaerobic biodegradation. Heavy metals were lower compared with what have been observed in other countries. Re-landfilling of the residue after drying the leachate in lagoons and the short time of biodegradation in the landfill site were factors which effected the high strength of most of the parameters concentrations of the leachate. Assessment of groundwater contamination through piezometer wells around the active cells indicated that there was no contamination from the leachate to the groundwater surrounding the site. The study recommended emphasizing the importance of adjusting the biodegradation factors, the monitoring program, the prohibition of disposing heavy metals, determination of the leachate generation rate, and treatment of leachate.

  15. Pathways for Disposal of Commercially-Generated Tritiated Waste

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Halverson, Nancy V.

    From a waste disposal standpoint, tritium is a major challenge. Because it behaves like hydrogen, tritium exchanges readily with hydrogen in the ground water and moves easily through the ground. Land disposal sites must control the tritium activity and mobility of incoming wastes to protect human health and the environment. Consequently, disposal of tritiated low-level wastes is highly regulated and disposal options are limited. The United States has had eight operating commercial facilities licensed for low-level radioactive waste disposal, only four of which are currently receiving waste. Each of these is licensed and regulated by its state. Only two ofmore » these sites accept waste from states outside of their specified regional compact. For waste streams that cannot be disposed directly at one of the four active commercial low-level waste disposal facilities, processing facilities offer various forms of tritiated low-level waste processing and treatment, and then transport and dispose of the residuals at a disposal facility. These processing facilities may remove and recycle tritium, reduce waste volume, solidify liquid waste, remove hazardous constituents, or perform a number of additional treatments. Waste brokers also offer many low-level and mixed waste management and transportation services. These services can be especially helpful for small-quantity tritiated-waste generators, such as universities, research institutions, medical facilities, and some industries. The information contained in this report covers general capabilities and requirements for the various disposal/processing facilities and brokerage companies, but is not considered exhaustive. Typically, each facility has extensive waste acceptance criteria and will require a generator to thoroughly characterize their wastes. Then a contractual agreement between the waste generator and the disposal/processing/broker entity must be in place before waste is accepted. Costs for tritiated waste transportation, processing and disposal vary based a number of factors. In many cases, wastes with very low radioactivity are priced primarily based on weight or volume. For higher activities, costs are based on both volume and activity, with the activity-based charges usually being much larger than volume-based charges. Other factors affecting cost include location, waste classification and form, other hazards in the waste, etc. Costs may be based on general guidelines used by an individual disposal or processing site, but final costs are established by specific contract with each generator. For this report, seven hypothetical waste streams intended to represent commercially-generated tritiated waste were defined in order to calculate comparative costs. Ballpark costs for disposition of these hypothetical waste streams were calculated. These costs ranged from thousands to millions of dollars. Due to the complexity of the cost-determining factors mentioned above, the costs calculated in this report should be understood to represent very rough cost estimates for the various hypothetical wastes. Actual costs could be higher or could be lower due to quantity discounts or other factors.« less

  16. A procedure to estimate proximate analysis of mixed organic wastes.

    PubMed

    Zaher, U; Buffiere, P; Steyer, J P; Chen, S

    2009-04-01

    In waste materials, proximate analysis measuring the total concentration of carbohydrate, protein, and lipid contents from solid wastes is challenging, as a result of the heterogeneous and solid nature of wastes. This paper presents a new procedure that was developed to estimate such complex chemical composition of the waste using conventional practical measurements, such as chemical oxygen demand (COD) and total organic carbon. The procedure is based on mass balance of macronutrient elements (carbon, hydrogen, nitrogen, oxygen, and phosphorus [CHNOP]) (i.e., elemental continuity), in addition to the balance of COD and charge intensity that are applied in mathematical modeling of biological processes. Knowing the composition of such a complex substrate is crucial to study solid waste anaerobic degradation. The procedure was formulated to generate the detailed input required for the International Water Association (London, United Kingdom) Anaerobic Digestion Model number 1 (IWA-ADM1). The complex particulate composition estimated by the procedure was validated with several types of food wastes and animal manures. To make proximate analysis feasible for validation, the wastes were classified into 19 types to allow accurate extraction and proximate analysis. The estimated carbohydrates, proteins, lipids, and inerts concentrations were highly correlated to the proximate analysis; correlation coefficients were 0.94, 0.88, 0.99, and 0.96, respectively. For most of the wastes, carbohydrate was the highest fraction and was estimated accurately by the procedure over an extended range with high linearity. For wastes that are rich in protein and fiber, the procedure was even more consistent compared with the proximate analysis. The new procedure can be used for waste characterization in solid waste treatment design and optimization.

  17. Generation of 3-D surface maps in waste storage silos using a structured light source

    NASA Technical Reports Server (NTRS)

    Burks, B. L.; Rowe, J. C.; Dinkins, M. A.; Christensen, B.; Selleck, C.; Jacoboski, D.; Markus, R.

    1992-01-01

    Surface contours inside the large waste storage tanks typical of the Department of Energy (DOE) complex are, in general, highly irregular. In addition to pipes and other pieces of equipment in the tanks, the surfaces may have features such as mounds, fissures, crystalline structures, and mixed solid and liquid forms. Prior to remediation activities, it will be necessary to characterize the waste to determine the most effective remediation approaches. Surface contour data will be required both prior to and during remediation. The use is described of a structured light source to generate 3-D surface contour maps of the interior of waste storage silos at the Feed Materials Production Center at Fernald, OH. The landscape inside these large waste storage tanks bears a strong resemblance to some of the landscapes that might be encountered during lunar or planetary exploration. Hence, these terrestrial 3-D mapping techniques may be directly applicable to extraterrestrial exploration. In further development, it will be demonstrated that these 3-D data can be used for robotic task planning just as 3-D surface contour data of a satellite could be used to plan maintenance tasks for a space-based servicing robot.

  18. Co-ensiling as a new technique for long-term storage of agro-industrial waste with low sugar content prior to anaerobic digestion.

    PubMed

    Hillion, Marie-Lou; Moscoviz, Roman; Trably, Eric; Leblanc, Yoann; Bernet, Nicolas; Torrijos, Michel; Escudié, Renaud

    2018-01-01

    Biodegradable wastes produced seasonally need an upstream storage, because of the requirement for a constant feeding of anaerobic digesters. In the present article, the potential of co-ensiling biodegradable agro-industrial waste (sugar beet leaves) and lignocellulosic agricultural residue (wheat straw) to obtain a mixture with low soluble sugar content was evaluated for long-term storage prior to anaerobic digestion. The aim is to store agro-industrial waste while pretreating lignocellulosic biomass. The dynamics of co-ensiling was evaluated in vacuum-packed bags at lab-scale during 180 days. Characterization of the reaction by-products and microbial communities showed a succession of metabolic pathways. Even though the low initial sugars content was not sufficient to lower the pH under 4.5 and avoid undesirable fermentations, the methane potential was not substantially impacted all along the experiment. No lignocellulosic damages were observed during the silage process. Overall, it was shown that co-ensiling was effective to store highly fermentable fresh waste evenly with low sugar content and offers new promising possibilities for constant long-term supply of industrial anaerobic digesters. Copyright © 2017 Elsevier Ltd. All rights reserved.

  19. DOE Office of Scientific and Technical Information (OSTI.GOV)

    Hamilton, T.; Jones, H.; Wong, K.

    The Marshall Islands Environmental Characterization and Dose Assessment Program has recently implemented waste minimization measures to reduce low level radioactive (LLW) and low level mixed (LLWMIXED) waste streams at the Lawrence Livermore National Laboratory (LLNL). Several thousand environmental samples are collected annually from former US nuclear test sites in the Marshall Islands, and returned to LLNL for processing and radiometric analysis. In the past, we analyzed coconut milk directly by gamma-spectrometry after adding formaldehyde (as preservative) and sealing the fluid in metal cans. This procedure was not only tedious and time consuming but generated storage and waste disposal problems. Wemore » have now reduced the number of coconut milk samples required for analysis from 1500 per year to approximately 250, and developed a new analytical procedure which essentially eliminates the associated mixed radioactive waste stream. Coconut milk samples are mixed with a few grams of ammonium-molydophosphate (AMP) which quantitatively scavenges the target radionuclide cesium 137 in an ion-exchange process. The AMP is then separated from the mixture and sealed in a plastic container. The bulk sample material can be disposed of as a non- radioactive non-hazardous waste, and the relatively small amount of AMP conveniently counted by gamma-spectrometry, packaged and stored for future use.« less

  20. Waste-water characterization and hazardous-waste technical assistance survey, Bergstrom AFB tTxas. Final report, 6-15 March 1989

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Hedgecock, N.S.

    1990-01-01

    At the request of 67 Combat Support Group/DEEV the Air Force Occupational and Environmental Health Laboratory conducted a waste-water characterization and hazardous-waste technical assistance survey at Bergstrom AFB (BAFB) from 6-15 Mar 89. The scope of the waste-water survey was to characterize the effluent exiting the base and the effluent from 23 industrial facilities and 10 food-serving facilities. The scope of the hazardous-waste survey was to address hazardous-waste-management practices and explore opportunities for hazardous waste minimization. Specific recommendations from the survey include: (1) Accompany City of Austin personnel during waste-water sampling procedures; (2) Sample at the manhole exiting the mainmore » lift station rather than at the lift station wet well; (3) Split waste-water samples with the City of Austin for comparison of results; (4) Ensure that oil/water separators and grease traps are functioning properly and are cleaned out regularly; (5) Limit the quantity of soaps and solvents discharged down the drain to the sanitary sewer; (6) Establish a waste disposal contract for the removal of wastes in the Petroleum Oils and Lubricants underground storage tanks. (7) Remove, analyze, and properly dispose of oil contaminated soil from accumulation sites. (8) Move indoors or secure, cover, and berm the aluminum sign reconditioning tank at 67 Civil Engineering Squadron Protective Coating. (9) Connect 67 Combat Repair Squadron Test Cell floor drains to the sanitary sewer.« less

  1. Results for the First, Second, and Third Quarter Calendar Year 2015 Tank 50H WAC slurry samples chemical and radionuclide contaminants

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Crawford, C.

    2016-02-18

    This report details the chemical and radionuclide contaminant results for the characterization of the Calendar Year (CY) 2015 First, Second, and Third Quarter sampling of Tank 50H for the Saltstone Waste Acceptance Criteria (WAC) in effect at that time. Information from this characterization will be used by Defense Waste Processing Facility (DWPF) & Saltstone Facility Engineering (D&S-FE) to support the transfer of low-level aqueous waste from Tank 50H to the Salt Feed Tank in the Saltstone Facility in Z-Area, where the waste will be immobilized. This information is also used to update the Tank 50H Waste Characterization System. Previous memorandamore » documenting the WAC analyses results have been issued for these three samples.« less

  2. Speciation and Characterization of E-Waste, Using Analytical Techniques

    NASA Astrophysics Data System (ADS)

    López, C. Cortés; Cruz, V. E. Reyes; Rodríguez, M. A. Veloz; Ávila, J. Hernández; Badillo, J. Flores; Murcia, J. A. Cobos

    Electronic waste (e-waste), have a high potential as a source of precious metals, since they can contain metals like silver, gold, platinum, copper, zinc, nickel, tin and others. In this paper some e-waste were characterized using several analytical techniques as Scanning Electron Microscopy (SEM), X-ray diffraction (XRD) and inductively coupled plasma (ICP) in addition to the thermodynamic study by Pourbaix diagrams of silver (Ag), gold (Au), platinum (Pt), copper (Cu), nickel (Ni), tin (Sn) and zinc (Zn); considering an average low concentration of HNO3 (10% v/v). With results of the characterization was determined that the e-waste is an ideal source for the recovery of valuable metals. Similarly, the thermodynamic studies showed that it is possible to obtain all metallic species except Pt, in a potential window of 1.45V to 2.0V vs SCE.

  3. 40 CFR 761.260 - Applicability.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... Site Characterization Sampling for PCB Remediation Waste in Accordance with § 761.61(a)(2) § 761.260 Applicability. This subpart provides a method for collecting new data for characterizing a PCB remediation waste...

  4. Analysis of chemical weapons decontamination waste from old ton containers from Johnston Atoll using multiple analytical methods

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Creasy, W.R.; Brickhouse, M.D.; Morrisse, K.M.

    1999-07-01

    Decontamination waste from chemical weapons (CW) agents has been stored in ton containers on Johnston Atoll since 1971. The waste was recently sampled and analyzed to determine its chemical composition in preparation for future cleanups. Due to the range of products and analytical requirements, multiple chromatographic and spectroscopic methods were necessary, including gas chromatography/mass spectrometry (GC/MS), gas chromatography/atomic emission detection (GC/AED), liquid chromatography/mass spectrometry (LC/MS), capillary electrophoresis (CE), and nuclear magnetic resonance spectroscopy (NMR). The samples were screened for residual agents. No residual sarin (GB) or VX was found to detection limits of 20 ng/mL, but 3% of the samplesmore » contained residual sulfur mustard (HD) at < 140 ng/mL. Decontamination products of agents were identified. The majority (74%) of the ton containers were documented correctly, in that the observed decontamination products were in agreement with the labeled agent type, but for a number of the containers, the contents were not in agreement with the labels. In addition, arsenic compounds that are decontamination products of the agent lewisite (L) were observed in a few ton containers, suggesting that lewisite was originally present but not documented. This study was a prototype to demonstrate the level of effort required to characterize old bulk CW-related waste.« less

  5. Mission analysis for cross-site transfer

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Riesenweber, S.D.; Fritz, R.L.; Shipley, L.E.

    1995-11-01

    The Mission Analysis Report describes the requirements and constraints associated with the Transfer Waste Function as necessary to support the Manage Tank Waste, Retrieve Waste, and Process Tank Waste Functions described in WHC-SD-WM-FRD-020, Tank Waste Remediation System (TWRS) Functions and Requirements Document and DOE/RL-92-60, Revision 1, TWRS Functions and Requirements Document, March 1994. It further assesses the ability of the ``initial state`` (or current cross-site transfer system) to meet the requirements and constraints.

  6. MUNICIPAL WASTE COMBUSTION ASSESSMENT: MEDICAL WASTE COMBUSTION PRACTICES AT MUNICIPAL WASTE COMBUSTION FACILITIES

    EPA Science Inventory

    The report defines and characterizes types of medical waste, discusses the impacts of burning medical waste on combustor emissions, and outlines important handling and operating considerations. Facility-specific design, handling, and operating practiced are also discussed for mun...

  7. 10 CFR 61.56 - Waste characteristics.

    Code of Federal Regulations, 2012 CFR

    2012-01-01

    ... 10 Energy 2 2012-01-01 2012-01-01 false Waste characteristics. 61.56 Section 61.56 Energy NUCLEAR REGULATORY COMMISSION (CONTINUED) LICENSING REQUIREMENTS FOR LAND DISPOSAL OF RADIOACTIVE WASTE Technical Requirements for Land Disposal Facilities § 61.56 Waste characteristics. (a) The following requirements are...

  8. 10 CFR 61.56 - Waste characteristics.

    Code of Federal Regulations, 2013 CFR

    2013-01-01

    ... 10 Energy 2 2013-01-01 2013-01-01 false Waste characteristics. 61.56 Section 61.56 Energy NUCLEAR REGULATORY COMMISSION (CONTINUED) LICENSING REQUIREMENTS FOR LAND DISPOSAL OF RADIOACTIVE WASTE Technical Requirements for Land Disposal Facilities § 61.56 Waste characteristics. (a) The following requirements are...

  9. 10 CFR 61.56 - Waste characteristics.

    Code of Federal Regulations, 2010 CFR

    2010-01-01

    ... 10 Energy 2 2010-01-01 2010-01-01 false Waste characteristics. 61.56 Section 61.56 Energy NUCLEAR REGULATORY COMMISSION (CONTINUED) LICENSING REQUIREMENTS FOR LAND DISPOSAL OF RADIOACTIVE WASTE Technical Requirements for Land Disposal Facilities § 61.56 Waste characteristics. (a) The following requirements are...

  10. 10 CFR 61.56 - Waste characteristics.

    Code of Federal Regulations, 2011 CFR

    2011-01-01

    ... 10 Energy 2 2011-01-01 2011-01-01 false Waste characteristics. 61.56 Section 61.56 Energy NUCLEAR REGULATORY COMMISSION (CONTINUED) LICENSING REQUIREMENTS FOR LAND DISPOSAL OF RADIOACTIVE WASTE Technical Requirements for Land Disposal Facilities § 61.56 Waste characteristics. (a) The following requirements are...

  11. 10 CFR 61.56 - Waste characteristics.

    Code of Federal Regulations, 2014 CFR

    2014-01-01

    ... 10 Energy 2 2014-01-01 2014-01-01 false Waste characteristics. 61.56 Section 61.56 Energy NUCLEAR REGULATORY COMMISSION (CONTINUED) LICENSING REQUIREMENTS FOR LAND DISPOSAL OF RADIOACTIVE WASTE Technical Requirements for Land Disposal Facilities § 61.56 Waste characteristics. (a) The following requirements are...

  12. Characterization of a polyhydroxyalkanoate obtained from pineapple peel waste using Ralsthonia eutropha.

    PubMed

    Vega-Castro, Oscar; Contreras-Calderon, Jose; León, Emilson; Segura, Almir; Arias, Mario; Pérez, León; Sobral, Paulo J A

    2016-08-10

    Agro-industrial waste can be the production source of biopolymers such as polyhydroxyalkanoates. The aim of this study was to produce and characterize Polyhydroxyalkanoates produced from pineapple peel waste fermentation processes. The methodology includes different pineapple peel waste fermentation conditions. The produced biopolymer was characterized using FTIR, GC-MS and NMR. The best fermentation condition for biopolymer production was obtained using pH 9, Carbon/Nitrogen 11, carbon/phosphorus 6 and fermentation time of 60h. FTIR analyzes showed PHB group characteristics, such as OH, CH and CO. In addition, GC-MS showed two monomers with 4 and 8 carbons, referred to PHB and PHBHV. H(1) NMR analysis showed 0.88-0.97 and 5.27ppm signals, corresponding to CH3 and CH, respectively. In conclusion, polyhydroxyalkanoate production from pineapple peels waste is an alternative for the treatment of waste generated in Colombia's fruit industry. Copyright © 2016 Elsevier B.V. All rights reserved.

  13. Characterization Data Package for Containerized Sludge Samples Collected from Engineered Container SCS-CON-210

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Fountain, Matthew S.; Fiskum, Sandra K.; Baldwin, David L.

    This data package contains the K Basin sludge characterization results obtained by Pacific Northwest National Laboratory during processing and analysis of four sludge core samples collected from Engineered Container SCS-CON-210 in 2010 as requested by CH2M Hill Plateau Remediation Company. Sample processing requirements, analytes of interest, detection limits, and quality control sample requirements are defined in the KBC-33786, Rev. 2. The core processing scope included reconstitution of a sludge core sample distributed among four to six 4-L polypropylene bottles into a single container. The reconstituted core sample was then mixed and subsampled to support a variety of characterization activities. Additionalmore » core sludge subsamples were combined to prepare a container composite. The container composite was fractionated by wet sieving through a 2,000 micron mesh and a 500-micron mesh sieve. Each sieve fraction was sampled to support a suite of analyses. The core composite analysis scope included density determination, radioisotope analysis, and metals analysis, including the Waste Isolation Pilot Plant Hazardous Waste Facility Permit metals (with the exception of mercury). The container composite analysis included most of the core composite analysis scope plus particle size distribution, particle density, rheology, and crystalline phase identification. A summary of the received samples, core sample reconstitution and subsampling activities, container composite preparation and subsampling activities, physical properties, and analytical results are presented. Supporting data and documentation are provided in the appendices. There were no cases of sample or data loss and all of the available samples and data are reported as required by the Quality Assurance Project Plan/Sampling and Analysis Plan.« less

  14. DOE Office of Scientific and Technical Information (OSTI.GOV)

    Not Available

    This volume contains appendices for the following: Rocky Flats Plant and Idaho National Engineering Laboratory waste process information; TRUPACT-II content codes (TRUCON); TRUPACT-II chemical list; chemical compatibility analysis for Rocky Flats Plant waste forms; chemical compatibility analysis for waste forms across all sites; TRU mixed waste characterization database; hazardous constituents of Rocky Flats Transuranic waste; summary of waste components in TRU waste sampling program at INEL; TRU waste sampling program; and waste analysis data.

  15. The Cementitious Barriers Partnership Experimental Programs and Software Advancing DOE’s Waste Disposal/Tank Closure Efforts – 15436

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Burns, Heather; Flach, Greg; Smith, Frank

    2015-01-27

    The U.S. Department of Energy Environmental Management (DOE-EM) Office of Tank Waste Management-sponsored Cementitious Barriers Partnership (CBP) is chartered with providing the technical basis for implementing cement-based waste forms and radioactive waste containment structures for long-term disposal. DOE needs in this area include the following to support progress in final treatment and disposal of legacy waste and closure of High-Level Waste (HLW) tanks in the DOE complex: long-term performance predictions, flow sheet development and flow sheet enhancements, and conceptual designs for new disposal facilities. The DOE-EM Cementitious Barriers Partnership is producing software and experimental programs resulting in new methods andmore » data needed for end-users involved with environmental cleanup and waste disposal. Both the modeling tools and the experimental data have already benefited the DOE sites in the areas of performance assessments by increasing confidence backed up with modeling support, leaching methods, and transport properties developed for actual DOE materials. In 2014, the CBP Partnership released the CBP Software Toolbox –“Version 2.0” which provides concrete degradation models for 1) sulfate attack, 2) carbonation, and 3) chloride initiated rebar corrosion, and includes constituent leaching. These models are applicable and can be used by both DOE and the Nuclear Regulatory Commission (NRC) for service life and long-term performance evaluations and predictions of nuclear and radioactive waste containment structures across the DOE complex, including future SRS Saltstone and HLW tank performance assessments and special analyses, Hanford site HLW tank closure projects and other projects in which cementitious barriers are required, the Advanced Simulation Capability for Environmental Management (ASCEM) project which requires source terms from cementitious containment structures as input to their flow simulations, regulatory reviews of DOE performance assessments, and Nuclear Regulatory Commission reviews of commercial nuclear power plant (NPP) structures which are part of the overall US Energy Security program to extend the service life of NPPs. In addition, the CBP experimental programs have had a significant impact on the DOE complex by providing specific data unique to DOE sodium salt wastes at Hanford and SRS which are not readily available in the literature. Two recent experimental programs on cementitious phase characterization and on technetium (Tc) mobility have provided significant conclusions as follows: recent mineralogy characterization discussed in this paper illustrates that sodium salt waste form matrices are somewhat similar to but not the same as those found in blended cement matrices which to date have been used in long-term thermodynamic modeling and contaminant sequestration as a first approximation. Utilizing the CBP generated data in long-term performance predictions provides for a more defensible technical basis in performance evaluations. In addition, recent experimental studies related to technetium mobility indicate that conventional leaching protocols may not be conservative for direct disposal of Tc-containing waste forms in vadose zone environments. These results have the potential to influence the current Hanford supplemental waste treatment flow sheet and disposal conceptual design.« less

  16. Ecological Characterization Data for the 2004 Composite Analysis

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Downs, Janelle L.; Simmons, Mary A.; Stegen, Jennifer A.

    2004-11-01

    A composite analysis is required by U.S. Department of Energy (DOE) Order 435.1 to ensure public safety through the management of active and planned low-level radioactive waste disposal facilities associated with the Hanford Site. The original Hanford Site Composite Analysis of 1998 must be revised and submitted to DOE Headquarters (DOE-HQ) in 2004 because of revisions to waste site information in the 100, 200, and 300 Areas, updated performance assessments and environmental impact statements (EIS), changes in inventory estimates for key sites and constituents, and a change in the definition of offsite receptors. Beginning in fiscal year (FY) 2003, themore » DOE Richland Operations Office (DOE-RL) initiated activities, including the development of data packages, to support the 2004 Composite Analysis. This report describes the data compiled in FY 2003 to support ecological site assessment modeling for the 2004 Composite Analysis. This work was conducted as part of the Characterization of Systems Task of the Groundwater Remediation Project (formerly the Groundwater Protection Program) managed by Fluor Hanford, Inc., Richland, Washington. The purpose of this report is to provide summaries of the characterization information and available spatial data on the biological resources and ecological receptors found in the upland, riparian, aquatic, and island habitats on the Hanford Site. These data constitute the reference information used to establish parameters for the ecological risk assessment module of the System Assessment Capability and other assessment activities requiring information on the presence and distribution of biota on the Hanford Site.« less

  17. Low-level radioactive waste management: transitioning to off-site disposal at Los Alamos National Laboratory

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Dorries, Alison M

    2010-11-09

    Facing the closure of nearly all on-site management and disposal capability for low-level radioactive waste (LLW), Los Alamos National Laboratory (LANL) is making ready to ship the majority of LLW off-site. In order to ship off-site, waste must meet the Treatment, Storage, and Disposal Facility's (TSDF) Waste Acceptance Criteria (WAC). In preparation, LANL's waste management organization must ensure LANL waste generators characterize and package waste compliantly and waste characterization documentation is complete and accurate. Key challenges that must be addressed to successfully make the shift to off-site disposal of LLW include improving the detail, accuracy, and quality of process knowledgemore » (PK) and acceptable knowledge (AK) documentation, training waste generators and waste management staff on the higher standard of data quality and expectations, improved WAC compliance for off-site facilities, and enhanced quality assurance throughout the process. Certification of LANL generators will allow direct off-site shipping of LLW from their facilities.« less

  18. MICRO AUTO GASIFICATION SYSTEM: EMISSIONS ...

    EPA Pesticide Factsheets

    A compact, CONEX-housed waste to energy unit, Micro Auto Gasification System (MAGS), was characterized for air emissions from burning of military waste types. The MAGS unit is a dual chamber gasifier with a secondary diesel-fired combustor. Eight tests were conducted with multiple waste types in a 7-day period at the Kilauea Military Camp in Hawai’i. The emissions characterized were chosen based on regulatory emissions limits as well as their ability to cause adverse health effects on humans: particulate matter (PM), mercury, heavy metals, volatile organic compounds (VOCs), polyaromatic hydrocarbons (PAHs), and polychlorinated dibenzo-p-dioxins (PCDDs) and polychlorinated dibenzofurans (PCDFs). Three military waste feedstock compositions reflecting the variety of wastes to be encountered in theatre were investigated: standard waste (SW), standard waste with increased plastic content (HP), standard waste without SW food components but added first strike ration (FSR) food and packaging material (termed FSR). A fourth waste was collected from the Kilauea dumpster that served the dining facility and room lodging (KMC). Limited scrubber water and solid ash residue samples were collected to obtain a preliminary characterization of these effluents/residues.Gasifying SW, HP, and KMC resulted in similar PCDD/PCDF stack concentrations, 0.26-0.27 ng TEQ/m3 at 7% O2, while FSR waste generated a notably higher stack concentration of 0.68 ng TEQ/m3 at 7% O2. The PM emission

  19. Ceramics in nuclear waste management

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Chikalla, T D; Mendel, J E

    1979-05-01

    Seventy-three papers are included, arranged under the following section headings: national programs for the disposal of radioactive wastes, waste from stability and characterization, glass processing, ceramic processing, ceramic and glass processing, leaching of waste materials, properties of nuclear waste forms, and immobilization of special radioactive wastes. Separate abstracts were prepared for all the papers. (DLC)

  20. 40 CFR 63.1095 - What specific requirements must I comply with?

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... according to any of the options in 40 CFR 61.342(c)(1) through (e) or transfer waste off-site. If you elect... Systems and Waste Operations Waste Requirements § 63.1095 What specific requirements must I comply with? For waste that is not transferred off-site, you must comply with the requirements in paragraph (a) of...

  1. 40 CFR 63.1095 - What specific requirements must I comply with?

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... according to any of the options in 40 CFR 61.342(c)(1) through (e) or transfer waste off-site. If you elect... Systems and Waste Operations Waste Requirements § 63.1095 What specific requirements must I comply with? For waste that is not transferred off-site, you must comply with the requirements in paragraph (a) of...

  2. 40 CFR 264.230 - Special requirements for incompatible wastes.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... wastes. 264.230 Section 264.230 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES (CONTINUED) STANDARDS FOR OWNERS AND OPERATORS OF HAZARDOUS WASTE TREATMENT, STORAGE, AND DISPOSAL FACILITIES Surface Impoundments § 264.230 Special requirements for incompatible wastes...

  3. STONES SAWING SLUDGE AS BY-PRODUCT: characterization for a future recovery

    NASA Astrophysics Data System (ADS)

    Zichella, Lorena; Bellopede, Rossana; Marini, Paola

    2017-04-01

    The European Commission, as part of its Thematic Strategy on the prevention and recycling of waste, committed itself to tackle one of the issues around the waste definition, namely the distinction between waste and by-products. This definition has been outlined through the Communication on waste and by-product of the European Court of Justice (Brussels, 21.2.2007 COM(2007) 59 final COMMUNICATION FROM THE COMMISSION TO THE COUNCIL AND THE EUROPEAN PARLIAMENT). By-product is a substance or object, resulting from a production process, the primary aim of which is not the production of that item. By-products can come from a wide range of business sectors, and can have very different environmental impacts. If there is a possibility that the material is in fact not useable, because it does not meet the technical specifications that would be required for its use, then it should continue to be considered as a waste. The status of waste protects the environment from the potential consequences of this uncertainty. If it subsequently happens that a use is found for the waste in question then it will lose its status of waste and it will be considered a by-product. An incorrect classification could be the cause of environmental damage or unnecessary costs for business. For this purpose a characterization of sludge coming from different plants of stone processing was carried out for a better classification of the materials in view of a future recovery. The different stones cutting processes considered for this study are: gangsaw, diamond blade and diamond wire. The cut materials are granites, gneisses, and other stones mainly of silicatic nature. The tests performed on the sawing sludge are the following: particle size analysis, chemical analysis, wet magnetic separation, diffraction and SEM analysis. The study performed is useful for evaluating the possible reuses of the products coming from the magnetic separation: the metal fraction, and the mineral one. In order to avoid a subsequent environmental degradation and to promote a technology innovation (sustainability and circular economy) a proactive waste management strategy trying to optimize on the one hand the processing to obtain reduced waste and the other to improve the process to obtain two reusable by-products was considered.

  4. Generic waste management requirements for a controlled ecological life support system /CELSS/

    NASA Technical Reports Server (NTRS)

    Hoshizaki, T.; Hansen, B. D., III

    1981-01-01

    Regenerative life support systems for future space missions will require closure of the waste-food loop. Each mission application will generate specific requirements for the waste management system. However, there are generic input and output requirements that can be identified when a probable scenario is chosen. This paper discusses the generic requirements when higher plants are chosen as the primary food source. Attention is focused on the quality and quantity of nutrients necessary for culturing higher plants. The types of wastes to be processed are also discussed. In addition, requirements generated by growing plants on three different substrates are presented. This work suggests that the mineral composition of waste materials may require minimal adjustment to satisfy the plant requirements.

  5. Small-Scale Waste-to-Energy Technology for Contingency Bases

    DTIC Science & Technology

    2012-05-24

    Expedient, No Waste Sorting Technology Readiness Level High Fuel Demand Water Required Steam Infrastructure Required Air Emissions Gasification ...Full gasification system • Costs $26K • GM Industrial Engine (GM 4 Cylinder, 3.00 L) • MeccAlte Generator Head • Imbert type downdraft reactor...Solid waste volume reduction − Response to waste streams  biomass , refuse-derived fuel, shredded waste − Operation and maintenance requirements

  6. Technical Basis for the Removal of Unremediated Nitrate Salt Sampling (UNS) to Support LANL Treatment Studies

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Funk, David John

    2016-05-05

    The sampling of unremediated nitrate salts (UNS) was originally proposed by the U.S. Department of Energy (DOE) and Los Alamos National Security, LLC (LANS) (collectively, the Permittees) as a means to ensure adequate understanding and characterization of the problematic waste stream created when the Permittees remediated these nitrate salts-bearing waste with an organic absorbent. The proposal to sample the UNS was driven by a lack of understanding with respect to the radioactive contamination release that occurred within the underground repository at the Waste Isolation Pilot Plant (WIPP) in February 14, 2014, as well as recommendations made by a Peer Reviewmore » Team. As discussed, the Permittees believe that current knowledge and understanding of the waste has sufficiently matured such that this additional sampling is not required. Perhaps more importantly, the risk of both chemical and radiological exposure to the workers sampling the UNS drum material is unwarranted. This memo provides the technical justification and rationale for excluding the UNS sampling from the treatment studies.« less

  7. An innovative way of thinking nuclear waste management - Neutron physics of a reactor directly operating on SNF.

    PubMed

    Merk, Bruno; Litskevich, Dzianis; Bankhead, Mark; Taylor, Richard J

    2017-01-01

    A solution for the nuclear waste problem is the key challenge for an extensive use of nuclear reactors as a major carbon free, sustainable, and applied highly reliable energy source. Partitioning and Transmutation (P&T) promises a solution for improved waste management. Current strategies rely on systems designed in the 60's for the massive production of plutonium. We propose an innovative strategic development plan based on invention and innovation described with the concept of developments in s-curves identifying the current boundary conditions, and the evolvable objectives. This leads to the ultimate, universal vision for energy production characterized by minimal use of resources and production of waste, while being economically affordable and safe, secure and reliable in operation. This vision is transformed into a mission for a disruptive development of the future nuclear energy system operated by burning of existing spent nuclear fuel (SNF) without prior reprocessing. This highly innovative approach fulfils the sustainability goals and creates new options for P&T. A proof on the feasibility from neutronic point of view is given demonstrating sufficient breeding of fissile material from the inserted SNF. The system does neither require new resources nor produce additional waste, thus it provides a highly sustainable option for a future nuclear system fulfilling the requests of P&T as side effect. In addition, this nuclear system provides enhanced resistance against misuse of Pu and a significantly reduced fuel cycle. However, the new system requires a demand driven rethinking of the separation process to be efficient.

  8. An innovative way of thinking nuclear waste management – Neutron physics of a reactor directly operating on SNF

    PubMed Central

    Litskevich, Dzianis; Bankhead, Mark; Taylor, Richard J.

    2017-01-01

    A solution for the nuclear waste problem is the key challenge for an extensive use of nuclear reactors as a major carbon free, sustainable, and applied highly reliable energy source. Partitioning and Transmutation (P&T) promises a solution for improved waste management. Current strategies rely on systems designed in the 60’s for the massive production of plutonium. We propose an innovative strategic development plan based on invention and innovation described with the concept of developments in s-curves identifying the current boundary conditions, and the evolvable objectives. This leads to the ultimate, universal vision for energy production characterized by minimal use of resources and production of waste, while being economically affordable and safe, secure and reliable in operation. This vision is transformed into a mission for a disruptive development of the future nuclear energy system operated by burning of existing spent nuclear fuel (SNF) without prior reprocessing. This highly innovative approach fulfils the sustainability goals and creates new options for P&T. A proof on the feasibility from neutronic point of view is given demonstrating sufficient breeding of fissile material from the inserted SNF. The system does neither require new resources nor produce additional waste, thus it provides a highly sustainable option for a future nuclear system fulfilling the requests of P&T as side effect. In addition, this nuclear system provides enhanced resistance against misuse of Pu and a significantly reduced fuel cycle. However, the new system requires a demand driven rethinking of the separation process to be efficient. PMID:28749952

  9. Force Provider Solid Waste Characterization Study

    DTIC Science & Technology

    2004-08-01

    energy converter (WEC) and/or composter . For a five-day period in June 2000, the solid waste generated by soldiers at the Force Provider Training Module...MATERIALS REDUCTION WASTE DISPOSAL MILITARY FACILITIES SANITARY ENGINEERING DISPOSAL FORCE PROVIDER FIELD FEEDING COMPOSTS WASTES GARBAGE WASTE RECYCLING...waste reduction through onsite waste-to-energy conversion and/or composting . The work was performed by Hughes Associates, Inc., 3610 Commerce

  10. 40 CFR 265.273 - Waste analysis.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 40 Protection of Environment 26 2011-07-01 2011-07-01 false Waste analysis. 265.273 Section 265... FACILITIES Land Treatment § 265.273 Waste analysis. In addition to the waste analyses required by § 265.13... listed as a hazardous waste. As required by § 265.13, the waste analysis plan must include analyses...

  11. Management of solid waste

    NASA Astrophysics Data System (ADS)

    Thompson, W. T.; Stinton, L. H.

    1980-04-01

    Compliance with the latest regulatory requirements addressing disposal of radioactive, hazardous, and sanitary solid waste criteria in the selection, design, and operation of solid waste management facilities. Due to the state of flux of these regulatory requirements from EPA and NRC, several waste management options were of solid waste. The current regulatory constraints and the design and operational requirements for construction of both storage and disposal facilities for use in management of DOE-ORO solid waste are highlighted. Capital operational costs are included for both disposal and storage options.

  12. CHARACTERIZATION AND PH/EH-BASED LEACHING TESTS OF MINING WASTES CONTAINING MERCURY

    EPA Science Inventory

    This study was undertaken as a part of developing treatment alternatives for waste materials, primarily waste rock and roaster tailings, from sites contaminated with mercury (Hg) mining wastes. Leaching profiles of waste rock over a range of different pH and oxidation-reduction (...

  13. CHARACTERIZATION AND PH/EH-BASED LEACHING TESTS OF MINING WASTES CONTAINING MERCURY

    EPA Science Inventory

    This study was undertaken as a part of developing treatment alternatives for waste materials, primarily waste rock and roaster tailings, from sites contaminated with Mercury (Hg) mining wastes. Leaching profiles of waste rock over a range of different pH and oxidation-reduction ...

  14. 40 CFR 264.282 - Special requirements for incompatible wastes.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... wastes. 264.282 Section 264.282 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES (CONTINUED) STANDARDS FOR OWNERS AND OPERATORS OF HAZARDOUS WASTE TREATMENT, STORAGE, AND DISPOSAL FACILITIES Land Treatment § 264.282 Special requirements for incompatible wastes. The owner or...

  15. 40 CFR 264.282 - Special requirements for incompatible wastes.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... wastes. 264.282 Section 264.282 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES (CONTINUED) STANDARDS FOR OWNERS AND OPERATORS OF HAZARDOUS WASTE TREATMENT, STORAGE, AND DISPOSAL FACILITIES Land Treatment § 264.282 Special requirements for incompatible wastes. The owner or...

  16. 40 CFR 264.282 - Special requirements for incompatible wastes.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... wastes. 264.282 Section 264.282 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES (CONTINUED) STANDARDS FOR OWNERS AND OPERATORS OF HAZARDOUS WASTE TREATMENT, STORAGE, AND DISPOSAL FACILITIES Land Treatment § 264.282 Special requirements for incompatible wastes. The owner or...

  17. 40 CFR 264.282 - Special requirements for incompatible wastes.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... wastes. 264.282 Section 264.282 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES (CONTINUED) STANDARDS FOR OWNERS AND OPERATORS OF HAZARDOUS WASTE TREATMENT, STORAGE, AND DISPOSAL FACILITIES Land Treatment § 264.282 Special requirements for incompatible wastes. The owner or...

  18. Decommissioning Handbook

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Not Available

    1994-03-01

    The Decommissioning Handbook is a technical guide for the decommissioning of nuclear facilities. The decommissioning of a nuclear facility involves the removal of the radioactive and, for practical reasons, hazardous materials to enable the facility to be released and not represent a further risk to human health and the environment. This handbook identifies and technologies and techniques that will accomplish these objectives. The emphasis in this handbook is on characterization; waste treatment; decontamination; dismantling, segmenting, demolition; and remote technologies. Other aspects that are discussed in some detail include the regulations governing decommissioning, worker and environmental protection, and packaging and transportationmore » of the waste materials. The handbook describes in general terms the overall decommissioning project, including planning, cost estimating, and operating practices that would ease preparation of the Decommissioning Plan and the decommissioning itself. The reader is referred to other documents for more detailed information. This Decommissioning Handbook has been prepared by Enserch Environmental Corporation for the US Department of Energy and is a complete restructuring of the original handbook developed in 1980 by Nuclear Energy Services. The significant changes between the two documents are the addition of current and the deletion of obsolete technologies and the addition of chapters on project planning and the Decommissioning Plan, regulatory requirements, characterization, remote technology, and packaging and transportation of the waste materials.« less

  19. Environmental and Geotechnical Assessment of the Steel Slags as a Material for Road Structure

    PubMed Central

    Sas, Wojciech; Głuchowski, Andrzej; Radziemska, Maja; Dzięcioł, Justyna; Szymański, Alojzy

    2015-01-01

    Slags are the final solid wastes from the steel industry. Their production from waste and associated materials is a proper implementation of the basic objectives and principles of the waste management. This study aims to investigate the chemical and selected significant geotechnical parameters of steel slag as the alternative materials used in road construction. These investigations are strongly desired for successful application in engineering. Young’s modules E, and resilient modules Mr showed that their values corresponding with requirements for subbase (principal or auxiliary) and riding surface as well. Tested mechanical properties were conducted in soaked and un-soaked (optimal moisture content) conditions. The designated high content of chromium and zinc are strongly associated with the internal crystal structure of steel slag. The results do not lead to threats when they are applied in roads’ structures. Mechanical characterization was obtained by performing California bearing ratio (CBR) tests for steel slag in fixed compaction and moisture content conditions. Moreover, cyclic loading of steel slag was conducted with the application of cyclic California bearing ratio (cCBR) apparatus to characterization of this material as a controlled low-strength material. Finally, field studies that consist of static load plate VSS tests were presented. PMID:28793477

  20. Mixed waste focus area alternative technologies workshop

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Borduin, L.C.; Palmer, B.A.; Pendergrass, J.A.

    1995-05-24

    This report documents the Mixed Waste Focus Area (MWFA)-sponsored Alternative Technology Workshop held in Salt Lake City, Utah, from January 24--27, 1995. The primary workshop goal was identifying potential applications for emerging technologies within the Options Analysis Team (OAT) ``wise`` configuration. Consistent with the scope of the OAT analysis, the review was limited to the Mixed Low-Level Waste (MLLW) fraction of DOE`s mixed waste inventory. The Los Alamos team prepared workshop materials (databases and compilations) to be used as bases for participant review and recommendations. These materials derived from the Mixed Waste Inventory Report (MWIR) data base (May 1994), themore » Draft Site Treatment Plan (DSTP) data base, and the OAT treatment facility configuration of December 7, 1994. In reviewing workshop results, the reader should note several caveats regarding data limitations. Link-up of the MWIR and DSTP data bases, while representing the most comprehensive array of mixed waste information available at the time of the workshop, requires additional data to completely characterize all waste streams. A number of changes in waste identification (new and redefined streams) occurred during the interval from compilation of the data base to compilation of the DSTP data base with the end result that precise identification of radiological and contaminant characteristics was not possible for these streams. To a degree, these shortcomings compromise the workshop results; however, the preponderance of waste data was linked adequately, and therefore, these analyses should provide useful insight into potential applications of alternative technologies to DOE MLLW treatment facilities.« less

  1. Partitioning of Inorganic Elements Consumed by Humans Between the Various Fractions of Human Wastes: A Review and Analysis of Existing Literature

    NASA Technical Reports Server (NTRS)

    Wignarajah, K.; Fisher, John W.; Pisharody, Suresh A.

    2003-01-01

    The nutritional requirements of humans and astronauts are well defined and show consistency, but the same cannot be said of human wastes. Nutrients taken up by humans can be considered to fall into two major categories - organic and inorganic fractions. Carbon, hydrogen, oxygen, nitrogen and sulfur are elements that are associated with the organic fraction. These elements are taken up in large amounts by humans and when metabolized released in wastes often in gaseous forms or as water. On the other hand, a large number of the elements are simply exchanged and can be accounted for in the liquid and solid wastes of humans. These elements fall into three major categories - cationic macroelements (e.g. Ca, K, Na, Mg and Si), anionic macroelements (e.g P, S and Cl), 17 essential microelements, (e.g. Fe, Mn, Cr, Co, Cu, Zn, Se and Sr). When provided in the recommended concentrations to an adult human, these elements should not normally accumulate in humans, but will be excreted in the different human wastes. Knowledge of the partitioning of these elements between the different human waste fractions is fundamental to understanding (a) how these elements can be recovered for reuse in space habitats, and (b) to developing the processors for waste management. The current literature is exhaustive but sometimes also conflicting. We have used the existing knowledge of nutrition and waste from medical literature and NASA documentation to develop a consensus to typify and chemically characterize the various human wastes. The partitioning of these elements has been developed into a functional model.

  2. ELIMINATION OF THE CHARACTERIZATION OF DWPF POUR STREAM SAMPLE AND THE GLASS FABRICATION AND TESTING OF THE DWPF SLUDGE BATCH QUALIFICATION SAMPLE

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Amoroso, J.; Peeler, D.; Edwards, T.

    2012-05-11

    A recommendation to eliminate all characterization of pour stream glass samples and the glass fabrication and Product Consistency Test (PCT) of the sludge batch qualification sample was made by a Six-Sigma team chartered to eliminate non-value-added activities for the Defense Waste Processing Facility (DWPF) sludge batch qualification program and is documented in the report SS-PIP-2006-00030. That recommendation was supported through a technical data review by the Savannah River National Laboratory (SRNL) and is documented in the memorandums SRNL-PSE-2007-00079 and SRNL-PSE-2007-00080. At the time of writing those memorandums, the DWPF was processing sludge-only waste but, has since transitioned to a coupledmore » operation (sludge and salt). The SRNL was recently tasked to perform a similar data review relevant to coupled operations and re-evaluate the previous recommendations. This report evaluates the validity of eliminating the characterization of pour stream glass samples and the glass fabrication and Product Consistency Test (PCT) of the sludge batch qualification samples based on sludge-only and coupled operations. The pour stream sample has confirmed the DWPF's ability to produce an acceptable waste form from Slurry Mix Evaporator (SME) blending and product composition/durability predictions for the previous sixteen years but, ultimately the pour stream analysis has added minimal value to the DWPF's waste qualification strategy. Similarly, the information gained from the glass fabrication and PCT of the sludge batch qualification sample was determined to add minimal value to the waste qualification strategy since that sample is routinely not representative of the waste composition ultimately processed at the DWPF due to blending and salt processing considerations. Moreover, the qualification process has repeatedly confirmed minimal differences in glass behavior from actual radioactive waste to glasses fabricated from simulants or batch chemicals. In contrast, the variability study has significantly added value to the DWPF's qualification strategy. The variability study has evolved to become the primary aspect of the DWPF's compliance strategy as it has been shown to be versatile and capable of adapting to the DWPF's various and diverse waste streams and blending strategies. The variability study, which aims to ensure durability requirements and the PCT and chemical composition correlations are valid for the compositional region to be processed at the DWPF, must continue to be performed. Due to the importance of the variability study and its place in the DWPF's qualification strategy, it will also be discussed in this report. An analysis of historical data and Production Records indicated that the recommendation of the Six Sigma team to eliminate all characterization of pour stream glass samples and the glass fabrication and PCT performed with the qualification glass does not compromise the DWPF's current compliance plan. Furthermore, the DWPF should continue to produce an acceptable waste form following the remaining elements of the Glass Product Control Program; regardless of a sludge-only or coupled operations strategy. If the DWPF does decide to eliminate the characterization of pour stream samples, pour stream samples should continue to be collected for archival reasons, which would allow testing to be performed should any issues arise or new repository test methods be developed.« less

  3. Laser ablation/ionization characterization of solids: Second interim progress report of the strategic environmental research development program

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Hess, W.P.; Bushaw, B.A.; McCarthy, M.I.

    1996-10-01

    The Department of Energy is undertaking the enormous task of remediating defense wastes and environmental insults which have occurred over 50 years of nuclear weapons production. It is abundantly clear that significant technology advances are needed to characterize, process, and store highly radioactive waste and to remediate contaminated zones. In addition to the processing and waste form issues, analytical technologies needed for the characterization of solids, and for monitoring storage tanks and contaminated sites do not exist or are currently expensive labor-intensive tasks. This report describes progress in developing sensitive, rapid, and widely applicable laser-based mass spectrometry techniques for analysismore » of mixed chemical wastes and contaminated soils.« less

  4. Pollution characterization of liquid waste of the factory complex Fertial (Arzew, Algeria).

    PubMed

    Redouane, Fares; Mourad, Lounis

    2016-03-01

    The industrial development in Algeria has made a worrying situation for all socioeconomic stakeholders. Indeed, this economic growth is marked in recent years by the establishment of factories and industrial plants that discharge liquid waste in marine shorelines. These releases could destabilize the environmental balance in the coming years, hence the need to support the processing of all sources of pollution. Remediation of such discharges requires several steps of identifying the various pollutants to their treatments. Therefore, the authors conducted this first work of characterization of industrial effluents generated by the mineral fertilizer factory complex Fertial (Arzew), and discussed the pollution load generated by this type of industry. This monitoring would establish a tool for reflection and decision support developed by a management system capable of ensuring effective and sustainable management of effluents from industrial activities of Fertial. The authors conducted this first work of characterization of industrial effluents generated by the mineral fertilizer factory complex Fertial (Arzew), and discussed the pollution load generated by this type of industry. This monitoring would establish a tool for reflection and decision support developed by a management system capable of ensuring effective and sustainable management of effluents from industrial activities of Fertial.

  5. 40 CFR 264.198 - Special requirements for ignitable or reactive wastes.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... waste, mixture, or dissolved material no longer meets the definition of ignitable or reactive waste... comply with the requirements for the maintenance of protective distances between the waste management... reactive wastes. 264.198 Section 264.198 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY...

  6. 10 CFR 61.55 - Waste classification.

    Code of Federal Regulations, 2014 CFR

    2014-01-01

    ... 10 Energy 2 2014-01-01 2014-01-01 false Waste classification. 61.55 Section 61.55 Energy NUCLEAR REGULATORY COMMISSION (CONTINUED) LICENSING REQUIREMENTS FOR LAND DISPOSAL OF RADIOACTIVE WASTE Technical Requirements for Land Disposal Facilities § 61.55 Waste classification. (a) Classification of waste for near...

  7. 10 CFR 61.55 - Waste classification.

    Code of Federal Regulations, 2012 CFR

    2012-01-01

    ... 10 Energy 2 2012-01-01 2012-01-01 false Waste classification. 61.55 Section 61.55 Energy NUCLEAR REGULATORY COMMISSION (CONTINUED) LICENSING REQUIREMENTS FOR LAND DISPOSAL OF RADIOACTIVE WASTE Technical Requirements for Land Disposal Facilities § 61.55 Waste classification. (a) Classification of waste for near...

  8. 10 CFR 61.55 - Waste classification.

    Code of Federal Regulations, 2013 CFR

    2013-01-01

    ... 10 Energy 2 2013-01-01 2013-01-01 false Waste classification. 61.55 Section 61.55 Energy NUCLEAR REGULATORY COMMISSION (CONTINUED) LICENSING REQUIREMENTS FOR LAND DISPOSAL OF RADIOACTIVE WASTE Technical Requirements for Land Disposal Facilities § 61.55 Waste classification. (a) Classification of waste for near...

  9. 40 CFR 264.281 - Special requirements for ignitable or reactive waste.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... reactive waste. 264.281 Section 264.281 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES (CONTINUED) STANDARDS FOR OWNERS AND OPERATORS OF HAZARDOUS WASTE TREATMENT, STORAGE, AND DISPOSAL FACILITIES Land Treatment § 264.281 Special requirements for ignitable or reactive waste...

  10. 40 CFR 264.281 - Special requirements for ignitable or reactive waste.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... reactive waste. 264.281 Section 264.281 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES (CONTINUED) STANDARDS FOR OWNERS AND OPERATORS OF HAZARDOUS WASTE TREATMENT, STORAGE, AND DISPOSAL FACILITIES Land Treatment § 264.281 Special requirements for ignitable or reactive waste...

  11. 40 CFR 264.281 - Special requirements for ignitable or reactive waste.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... reactive waste. 264.281 Section 264.281 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES (CONTINUED) STANDARDS FOR OWNERS AND OPERATORS OF HAZARDOUS WASTE TREATMENT, STORAGE, AND DISPOSAL FACILITIES Land Treatment § 264.281 Special requirements for ignitable or reactive waste...

  12. 40 CFR 264.281 - Special requirements for ignitable or reactive waste.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... reactive waste. 264.281 Section 264.281 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES (CONTINUED) STANDARDS FOR OWNERS AND OPERATORS OF HAZARDOUS WASTE TREATMENT, STORAGE, AND DISPOSAL FACILITIES Land Treatment § 264.281 Special requirements for ignitable or reactive waste...

  13. Nuclear waste management. Semiannual progress report, October 1982-March 1983

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Chikalla, T.D.; Powell, J.A.

    1983-06-01

    This document is one of a series of technical progress reports designed to report radioactive waste management programs at the Pacific Northwest Laboratory. Accomplishments in the following programs are reported: waste stabilization; Materials Characterization Center; waste isolation; low-level waste management; remedial action; and supporting studies.

  14. 40 CFR 271.16 - Requirements for enforcement authority.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... WASTES (CONTINUED) REQUIREMENTS FOR AUTHORIZATION OF STATE HAZARDOUS WASTE PROGRAMS Requirements for... environment. Note: This paragraph requires that States have a mechanism (e.g., an administrative cease and... obtainable against any person who knowingly transports any hazardous waste to an unpermitted facility; who...

  15. 40 CFR 271.16 - Requirements for enforcement authority.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... WASTES (CONTINUED) REQUIREMENTS FOR AUTHORIZATION OF STATE HAZARDOUS WASTE PROGRAMS Requirements for... environment. Note: This paragraph requires that States have a mechanism (e.g., an administrative cease and... obtainable against any person who knowingly transports any hazardous waste to an unpermitted facility; who...

  16. 40 CFR 271.16 - Requirements for enforcement authority.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... WASTES (CONTINUED) REQUIREMENTS FOR AUTHORIZATION OF STATE HAZARDOUS WASTE PROGRAMS Requirements for... environment. Note: This paragraph requires that States have a mechanism (e.g., an administrative cease and... obtainable against any person who knowingly transports any hazardous waste to an unpermitted facility; who...

  17. 40 CFR 271.16 - Requirements for enforcement authority.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... WASTES (CONTINUED) REQUIREMENTS FOR AUTHORIZATION OF STATE HAZARDOUS WASTE PROGRAMS Requirements for... environment. Note: This paragraph requires that States have a mechanism (e.g., an administrative cease and... obtainable against any person who knowingly transports any hazardous waste to an unpermitted facility; who...

  18. 40 CFR 271.16 - Requirements for enforcement authority.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... WASTES (CONTINUED) REQUIREMENTS FOR AUTHORIZATION OF STATE HAZARDOUS WASTE PROGRAMS Requirements for... environment. Note: This paragraph requires that States have a mechanism (e.g., an administrative cease and... obtainable against any person who knowingly transports any hazardous waste to an unpermitted facility; who...

  19. Chemical composition and methane potential of commercial food wastes.

    PubMed

    Lopez, Victoria M; De la Cruz, Florentino B; Barlaz, Morton A

    2016-10-01

    There is increasing interest in anaerobic digestion in the U.S. However, there is little information on the characterization of commercial food waste sources as well as the effect of waste particle size on methane yield. The objective of this research was to characterize four commercial food waste sources: (1) university dining hall waste, (2) waste resulting from prepared foods and leftover produce at a grocery store, (3) food waste from a hotel and convention center, and (4) food preparation waste from a restaurant. Each sample was tested in triplicate 8L batch anaerobic digesters after shredding and after shredding plus grinding. Average methane yields for the university dining, grocery store, hotel, and restaurant wastes were 363, 427, 492, and 403mL/dry g, respectively. Starch exhibited the most complete consumption and particle size did not significantly affect methane yields for any of the tested substrates. Lipids represented 59-70% of the methane potential of the fresh substrates. Copyright © 2016 Elsevier Ltd. All rights reserved.

  20. 10 CFR 61.57 - Labeling.

    Code of Federal Regulations, 2012 CFR

    2012-01-01

    ... COMMISSION (CONTINUED) LICENSING REQUIREMENTS FOR LAND DISPOSAL OF RADIOACTIVE WASTE Technical Requirements for Land Disposal Facilities § 61.57 Labeling. Each package of waste must be clearly labeled to identify whether it is Class A waste, Class B waste, or Class C waste, in accordance with § 61.55. ...

  1. 10 CFR 61.57 - Labeling.

    Code of Federal Regulations, 2010 CFR

    2010-01-01

    ... COMMISSION (CONTINUED) LICENSING REQUIREMENTS FOR LAND DISPOSAL OF RADIOACTIVE WASTE Technical Requirements for Land Disposal Facilities § 61.57 Labeling. Each package of waste must be clearly labeled to identify whether it is Class A waste, Class B waste, or Class C waste, in accordance with § 61.55. ...

  2. 10 CFR 61.57 - Labeling.

    Code of Federal Regulations, 2011 CFR

    2011-01-01

    ... COMMISSION (CONTINUED) LICENSING REQUIREMENTS FOR LAND DISPOSAL OF RADIOACTIVE WASTE Technical Requirements for Land Disposal Facilities § 61.57 Labeling. Each package of waste must be clearly labeled to identify whether it is Class A waste, Class B waste, or Class C waste, in accordance with § 61.55. ...

  3. 10 CFR 61.57 - Labeling.

    Code of Federal Regulations, 2014 CFR

    2014-01-01

    ... COMMISSION (CONTINUED) LICENSING REQUIREMENTS FOR LAND DISPOSAL OF RADIOACTIVE WASTE Technical Requirements for Land Disposal Facilities § 61.57 Labeling. Each package of waste must be clearly labeled to identify whether it is Class A waste, Class B waste, or Class C waste, in accordance with § 61.55. ...

  4. 10 CFR 61.57 - Labeling.

    Code of Federal Regulations, 2013 CFR

    2013-01-01

    ... COMMISSION (CONTINUED) LICENSING REQUIREMENTS FOR LAND DISPOSAL OF RADIOACTIVE WASTE Technical Requirements for Land Disposal Facilities § 61.57 Labeling. Each package of waste must be clearly labeled to identify whether it is Class A waste, Class B waste, or Class C waste, in accordance with § 61.55. ...

  5. Environment Monitor

    NASA Technical Reports Server (NTRS)

    1988-01-01

    Viking landers touched down on Mars equipped with a variety of systems to conduct automated research, each carrying a compact but highly sophisticated instrument for analyzing Martian soil and atmosphere. Instrument called a Gas Chromatography/Mass Spectrometer (GC/MS) had to be small, lightweight, shock resistant, highly automated and extremely sensitive, yet require minimal electrical power. Viking Instruments Corporation commercialized this technology and targeted their primary market as environmental monitoring, especially toxic and hazardous waste site monitoring. Waste sites often contain chemicals in complex mixtures, and the conventional method of site characterization, taking samples on-site and sending them to a laboratory for analysis is time consuming and expensive. Other terrestrial applications are explosive detection in airports, drug detection, industrial air monitoring, medical metabolic monitoring and for military, chemical warfare agents.

  6. The road to Yucca Mountain—Evolution of nuclear waste disposal in the United States

    USGS Publications Warehouse

    Stuckless, John S.; Levich, Robert A.

    2016-01-01

    The generation of electricity by nuclear power and the manufacturing of atomic weapons have created a large amount of spent nuclear fuel and high-level radioactive waste. There is a world-wide consensus that the best way to protect mankind and the environment is to dispose of this waste in a deep geologic repository. Initial efforts focused on salt as the best medium for disposal, but the heat generated by the radioactive waste led many earth scientists to examine other rock types. In 1976, the director of the U.S. Geological Survey (USGS) wrote to the U.S. Energy Research and Development Administration (ERDA), predecessor agency of the U.S. Department of Energy (DOE), suggesting that there were several favorable environments at the Nevada Test Site (NTS), and that the USGS already had extensive background information on the NTS. Later, in a series of communications and one publication, the USGS espoused the favorability of the thick unsaturated zone. After the passage of the Nuclear Waste Policy Act (1982), the DOE compiled a list of nine favorable sites and settled on three to be characterized. In 1987, as the costs of characterizing three sites ballooned, Congress amended the Nuclear Waste Policy Act directing the DOE to focus only on Yucca Mountain in Nevada, with the proviso that if anything unfavorable was discovered, work would stop immediately. The U.S. DOE, the U.S. DOE national laboratories, and the USGS developed more than 100 detailed plans to study various earth-science aspects of Yucca Mountain and the surrounding area, as well as materials studies and engineering projects needed for a mined geologic repository. The work, which cost more than 10 billion dollars and required hundreds of man-years of work, culminated in a license application submitted to the U.S. Nuclear Regulatory Commission (NRC) in 2008.

  7. 40 CFR 761.345 - Form of the waste to be sampled.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... Characterization for PCB Disposal in Accordance With § 761.62, and Sampling PCB Remediation Waste Destined for Off... waste and PCB remediation waste destined for off-site disposal must be in the form of either flattened...

  8. 40 CFR 264.199 - Special requirements for incompatible wastes.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ...) SOLID WASTES (CONTINUED) STANDARDS FOR OWNERS AND OPERATORS OF HAZARDOUS WASTE TREATMENT, STORAGE, AND DISPOSAL FACILITIES Tank Systems § 264.199 Special requirements for incompatible wastes. (a) Incompatible...(b) is complied with. (b) Hazardous waste must not be placed in a tank system that has not been...

  9. Waste-water characterization and hazardous-waste technical assistance survey, Mather AFB California. Final report, 28 November-9 December 1988

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Scott, S.P.; Hedgecock, N.S.

    1989-10-01

    Personnel from the AFOEHL conducted a waste-water characterization and hazardous-waste technical assistance survey at MAFB from 28 Nov to 9 Dec 1988. The scope of this survey was to characterize the waste-water, address hazardous-waste-management practices, and explore opportunities for hazardous waste minimization. The waste water survey team analyzed the base's industrial effluent, effluent from oil/water separators, and storm water. The team performed a shop-by-shop evaluation of chemical-waste-management practices. Survey results showed that MAFB needs to improve its hazardous-waste-management program. Recommendations for improvement include: (1) Collecting two additional grab samples on separate days from the hospital discharge. Analyze for EPA Methodmore » 601 to determine if the grab sample from the survey gives a true indication of what is being discharged. (2) Locate the source and prevent mercury from the hospital from discharging into the sanitary sewer. (3) Dilute the soaps used for cleaning at the Fuels Lab, Building 7060. (4) Investigate the source of chromium from the Photo Lab. (5) Clean out the sewer system manhole directly downgradient from the Photo Lab. (6) Locate the source of contamination in the West Ditch Outfall. (7) Reconnect the two oil/water separators that discharge into the storm sewerage system. (8) Investigate the source of methylene chloride coming on the base. (9) Investigate the source of mercury at Fuel Cell Repair, building 7005.« less

  10. 40 CFR 60.3068 - What are the recordkeeping and reporting requirements for air curtain incinerators that burn only...

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... reporting requirements for air curtain incinerators that burn only wood waste, clean lumber, and yard waste... Model Rule-Air Curtain Incinerators That Burn Only Wood Waste, Clean Lumber, and Yard Waste § 60.3068 What are the recordkeeping and reporting requirements for air curtain incinerators that burn only wood...

  11. 40 CFR 60.3068 - What are the recordkeeping and reporting requirements for air curtain incinerators that burn only...

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... reporting requirements for air curtain incinerators that burn only wood waste, clean lumber, and yard waste... Model Rule-Air Curtain Incinerators That Burn Only Wood Waste, Clean Lumber, and Yard Waste § 60.3068 What are the recordkeeping and reporting requirements for air curtain incinerators that burn only wood...

  12. 40 CFR 60.3068 - What are the recordkeeping and reporting requirements for air curtain incinerators that burn only...

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... reporting requirements for air curtain incinerators that burn only wood waste, clean lumber, and yard waste... Model Rule-Air Curtain Incinerators That Burn Only Wood Waste, Clean Lumber, and Yard Waste § 60.3068 What are the recordkeeping and reporting requirements for air curtain incinerators that burn only wood...

  13. 40 CFR 60.2973 - What are the recordkeeping and reporting requirements for air curtain incinerators that burn only...

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... reporting requirements for air curtain incinerators that burn only wood waste, clean lumber, and yard waste... Qualification Air Curtain Incinerators That Burn Only Wood Waste, Clean Lumber, and Yard Waste § 60.2973 What are the recordkeeping and reporting requirements for air curtain incinerators that burn only wood...

  14. 40 CFR 60.3068 - What are the recordkeeping and reporting requirements for air curtain incinerators that burn only...

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... reporting requirements for air curtain incinerators that burn only wood waste, clean lumber, and yard waste... Model Rule-Air Curtain Incinerators That Burn Only Wood Waste, Clean Lumber, and Yard Waste § 60.3068 What are the recordkeeping and reporting requirements for air curtain incinerators that burn only wood...

  15. 40 CFR 60.3068 - What are the recordkeeping and reporting requirements for air curtain incinerators that burn only...

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... reporting requirements for air curtain incinerators that burn only wood waste, clean lumber, and yard waste... Model Rule-Air Curtain Incinerators That Burn Only Wood Waste, Clean Lumber, and Yard Waste § 60.3068 What are the recordkeeping and reporting requirements for air curtain incinerators that burn only wood...

  16. 40 CFR 60.2973 - What are the recordkeeping and reporting requirements for air curtain incinerators that burn only...

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... reporting requirements for air curtain incinerators that burn only wood waste, clean lumber, and yard waste... Qualification Air Curtain Incinerators That Burn Only Wood Waste, Clean Lumber, and Yard Waste § 60.2973 What are the recordkeeping and reporting requirements for air curtain incinerators that burn only wood...

  17. 40 CFR 60.2973 - What are the recordkeeping and reporting requirements for air curtain incinerators that burn only...

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... reporting requirements for air curtain incinerators that burn only wood waste, clean lumber, and yard waste... Qualification Air Curtain Incinerators That Burn Only Wood Waste, Clean Lumber, and Yard Waste § 60.2973 What are the recordkeeping and reporting requirements for air curtain incinerators that burn only wood...

  18. Hazardous Waste Clean-Up Information (CLU-IN) On-line Characterization and Remediation Databases Fact Sheet

    EPA Pesticide Factsheets

    This fact sheet provides an overview of the 10 on-line characterization and remediation databases available on the Hazardous Waste Clean-Up Information (CLU-IN) website sponsored by the U.S. Environmental Protection Agency.

  19. Development of a Plastic Melt Waste Compactor for Space Missions Experiments and Prototype Design

    NASA Technical Reports Server (NTRS)

    Pace, Gregory; Wignarajah, Kanapathipillai; Pisharody, Suresh; Fisher, John

    2004-01-01

    This paper describes development at NASA Ames Research Center of a heat melt compactor that can be used on both near term and far term missions. Experiments have been performed to characterize the behavior of composite wastes that are representative of the types of wastes produced on current and previous space missions such as International Space Station, Space Shuttle, MIR and Skylab. Experiments were conducted to characterize the volume reduction, bonding, encapsulation and biological stability of the waste composite and also to investigate other key design issues such as plastic extrusion, noxious off-gassing and removal of the of the plastic waste product from the processor. The experiments provided the data needed to design a prototype plastic melt waste processor, a description of which is included in the paper.

  20. Gamma-ray spectrometry method used for radioactive waste drums characterization for final disposal at National Repository for Low and Intermediate Radioactive Waste--Baita, Romania.

    PubMed

    Done, L; Tugulan, L C; Dragolici, F; Alexandru, C

    2014-05-01

    The Radioactive Waste Management Department from IFIN-HH, Bucharest, performs the conditioning of the institutional radioactive waste in concrete matrix, in 200 l drums with concrete shield, for final disposal at DNDR - Baita, Bihor county, in an old exhausted uranium mine. This paper presents a gamma-ray spectrometry method for the characterization of the radioactive waste drums' radionuclides content, for final disposal. In order to study the accuracy of the method, a similar concrete matrix with Portland cement in a 200 l drum was used. © 2013 The Authors. Published by Elsevier Ltd All rights reserved.

  1. Report: new guidelines for characterization of municipal solid waste: the Portuguese case.

    PubMed

    da Graça Madeira Martinho, Maria; Silveira, Ana Isabel; Fernandes Duarte Branco, Elsa Maria

    2008-10-01

    This report proposes a new set of guidelines for the characterization of municipal solid waste. It is based on an analysis of reference methodologies, used internationally, and a case study of Valorsul (a company that handles recovery and treatment of solid waste in the North Lisbon Metropolitan Area). In particular, the suggested guidelines present a new definition of the waste to be analysed, change the sampling unit and establish statistical standards for the results obtained. In these new guidelines, the sampling level is the waste collection vehicle and contamination and moisture are taken into consideration. Finally, focus is on the quality of the resulting data, which is essential for comparability of data between countries. These new guidelines may also be applicable outside Portugal because the methodology includes, besides municipal mixed waste, separately collected fractions of municipal waste. They are a response to the need for information concerning Portugal (e.g. Eurostat or OECD inquiries) and follow European Union municipal solid waste management policies (e.g. packaging waste recovery and recycling targets and the reduction of biodegradable waste going to landfill).

  2. Valorization of solid waste products from olive oil industry as potential adsorbents for water pollution control--a review.

    PubMed

    Bhatnagar, Amit; Kaczala, Fabio; Hogland, William; Marques, Marcia; Paraskeva, Christakis A; Papadakis, Vagelis G; Sillanpää, Mika

    2014-01-01

    The global olive oil production for 2010 is estimated to be 2,881,500 metric tons. The European Union countries produce 78.5% of the total olive oil, which stands for an average production of 2,136,000 tons. The worldwide consumption of olive oil increased of 78% between 1990 and 2010. The increase in olive oil production implies a proportional increase in olive mill wastes. As a consequence of such increasing trend, olive mills are facing severe environmental problems due to lack of feasible and/or cost-effective solutions to olive-mill waste management. Therefore, immediate attention is required to find a proper way of management to deal with olive mill waste materials in order to minimize environmental pollution and associated health risks. One of the interesting uses of solid wastes generated from olive mills is to convert them as inexpensive adsorbents for water pollution control. In this review paper, an extensive list of adsorbents (prepared by utilizing different types of olive mill solid waste materials) from vast literature has been compiled, and their adsorption capacities for various aquatic pollutants removal are presented. Different physicochemical methods that have been used to convert olive mill solid wastes into efficient adsorbents have also been discussed. Characterization of olive-based adsorbents and adsorption mechanisms of various aquatic pollutants on these developed olive-based adsorbents have also been discussed in detail. Conclusions have been drawn from the literature reviewed, and suggestions for future research are proposed.

  3. Milestones for Selection, Characterization, and Analysis of the Performance of a Repository for Spent Nuclear Fuel and High-Level Radioactive Waste at Yucca Mountain.

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Rechard, Robert P.

    This report presents a concise history in tabular form of events leading up to site identification in 1978, site selection in 1987, subsequent characterization, and ongoing analysis through 2009 of the performance of a repository for spent nuclear fuel and high - level radioactive waste at Yucca Mountain in southern Nevada. The tabulated events generally occurred in five periods: (1) commitment to mined geologic disposal and identification of sites; (2) site selection and analysis, based on regional geologic characterization through literature and analogous data; (3) feasibility analysis demonstrating calculation procedures and importance of system components, based on rough measures ofmore » performance using surface exploration, waste process knowledge, and general laboratory experiments; (4) suitability analysis demonstrating viability of disposal system, based on environment - specific laboratory experiments, in - situ experiments, and underground disposal system characterization; and (5) compliance analysis, based on completed site - specific characterization . The current sixth period beyond 2010 represents a new effort to set waste management policy in the United States. Because the relationship is important to understanding the evolution of the Yucca Mountain Project , the tabulation also shows the interaction between the policy realm and technical realm using four broad categories of events : (a) Regulatory requirements and related federal policy in laws and court decisions, (c) Presidential and agency directives, (c) technical milestones of implementing institutions, and (d) critiques of the Yucca Mountain Project and pertinent national and world events related to nuclear energy and radioactive waste. Preface The historical progression of technical milestones for the Yucca Mountain Project was originally developed for 10 journal articles in a special issue of Reliability Engineering System Safety on the performance assessment for the Yucca Mountain license application [1-10]. The listing of mile stones, a distinct feature of those articles, has been collected and tabulated here. A lthough a brief description is presented here (based on the summaries in the 10 journal articles), the emphasis remains on the tabulation because of its usefulness in providing a comprehensive but concise history of the Yucca Mountain Project. The tabulation presented here is more elaborate than originally presented in that many of the interactions that occurred between the technical realm and policy realm can be depicted in separate columns. The usefulness of the milestones table is due in part to L.A. Connolly, for editorial and reference support, and S.K. Best, Raytheon, and L. Mays, Sandia National Laboratories (SNL), for illustration support. Reviewers P.N. Swift, SNL, and K. Gupta, University of Oklahoma, helped improve the discussion. The historical perspective presented is that of the author and is not necessarily held by reviewers, Sandia National Laboratories , and the US Department of Energy. As a historic perspective, the author is reporting on the work of others; however, any interpretative error s of the documentation are those of the author alone. The characterization and modeling of the Yucca Mountain disposal system required numerous participants with expertise in many areas of science and technology, as evident from the extensive reference list. Their diligent efforts are generally acknowledged here and through the many references to their impressive work, but the 10 journal articles acknowledge by name many of the numerous participants that contributed to the Yucca Mountain Project .« less

  4. Site characterization report for the basalt waste isolation project. Volume II

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    None

    1982-11-01

    The reference location for a repository in basalt for the terminal storage of nuclear wastes on the Hanford Site and the candidate horizons within this reference repository location have been identified and the preliminary characterization work in support of the site screening process has been completed. Fifteen technical questions regarding the qualification of the site were identified to be addressed during the detailed site characterization phase of the US Department of Energy-National Waste Terminal Storage Program site selection process. Resolution of these questions will be provided in the final site characterization progress report, currently planned to be issued in 1987,more » and in the safety analysis report to be submitted with the License Application. The additional information needed to resolve these questions and the plans for obtaining the information have been identified. This Site Characterization Report documents the results of the site screening process, the preliminary site characterization data, the technical issues that need to be addressed, and the plans for resolving these issues. Volume 2 contains chapters 6 through 12: geochemistry; surface hydrology; climatology, meteorology, and air quality; environmental, land-use, and socioeconomic characteristics; repository design; waste package; and performance assessment.« less

  5. 40 CFR 761.260 - Applicability.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) TOXIC SUBSTANCES CONTROL ACT... Site Characterization Sampling for PCB Remediation Waste in Accordance with § 761.61(a)(2) § 761.260 Applicability. This subpart provides a method for collecting new data for characterizing a PCB remediation waste...

  6. 40 CFR 761.260 - Applicability.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) TOXIC SUBSTANCES CONTROL ACT... Site Characterization Sampling for PCB Remediation Waste in Accordance with § 761.61(a)(2) § 761.260 Applicability. This subpart provides a method for collecting new data for characterizing a PCB remediation waste...

  7. 40 CFR 761.260 - Applicability.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) TOXIC SUBSTANCES CONTROL ACT... Site Characterization Sampling for PCB Remediation Waste in Accordance with § 761.61(a)(2) § 761.260 Applicability. This subpart provides a method for collecting new data for characterizing a PCB remediation waste...

  8. 40 CFR 761.260 - Applicability.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) TOXIC SUBSTANCES CONTROL ACT... Site Characterization Sampling for PCB Remediation Waste in Accordance with § 761.61(a)(2) § 761.260 Applicability. This subpart provides a method for collecting new data for characterizing a PCB remediation waste...

  9. 40 CFR 265.257 - Special requirements for incompatible wastes.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ..., STORAGE, AND DISPOSAL FACILITIES Waste Piles § 265.257 Special requirements for incompatible wastes. (a... the same pile, unless § 265.17(b) is complied with. (b) A pile of hazardous waste that is incompatible with any waste or other material stored nearby in other containers, piles, open tanks, or surface...

  10. 40 CFR 264.257 - Special requirements for incompatible wastes.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... DISPOSAL FACILITIES Waste Piles § 264.257 Special requirements for incompatible wastes. (a) Incompatible... placed in the same pile, unless § 264.17(b) is complied with. (b) A pile of hazardous waste that is incompatible with any waste or other material stored nearby in containers, other piles, open tanks, or surface...

  11. High-Level Radioactive Waste.

    ERIC Educational Resources Information Center

    Hayden, Howard C.

    1995-01-01

    Presents a method to calculate the amount of high-level radioactive waste by taking into consideration the following factors: the fission process that yields the waste, identification of the waste, the energy required to run a 1-GWe plant for one year, and the uranium mass required to produce that energy. Briefly discusses waste disposal and…

  12. 40 CFR 240.200-1 - Requirement.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ...-1 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES GUIDELINES FOR THE THERMAL PROCESSING OF SOLID WASTES Requirements and Recommended Procedures § 240.200-1 Requirement. In consultation with the responsible agencies, the owner/operator shall determine what wastes shall...

  13. 40 CFR 240.200-1 - Requirement.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ...-1 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES GUIDELINES FOR THE THERMAL PROCESSING OF SOLID WASTES Requirements and Recommended Procedures § 240.200-1 Requirement. In consultation with the responsible agencies, the owner/operator shall determine what wastes shall...

  14. 40 CFR 60.2973 - What are the recordkeeping and reporting requirements for air curtain incinerators that burn only...

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... reporting requirements for air curtain incinerators that burn only wood waste, clean lumber, and yard waste... Modification or Reconstruction is Commenced on or After June 16, 2006 Air Curtain Incinerators That Burn Only... requirements for air curtain incinerators that burn only wood waste, clean lumber, and yard waste? (a) Prior to...

  15. 40 CFR 60.2973 - What are the recordkeeping and reporting requirements for air curtain incinerators that burn only...

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... reporting requirements for air curtain incinerators that burn only wood waste, clean lumber, and yard waste... Modification or Reconstruction is Commenced on or After June 16, 2006 Air Curtain Incinerators That Burn Only... requirements for air curtain incinerators that burn only wood waste, clean lumber, and yard waste? (a) Prior to...

  16. Environmental assessment and management of metal-rich wastes generated in acid mine drainage passive remediation systems.

    PubMed

    Macías, Francisco; Caraballo, Manuel A; Nieto, José Miguel

    2012-08-30

    As acid mine drainage (AMD) remediation is increasingly faced by governments and mining industries worldwide, the generation of metal-rich solid residues from the treatments plants is concomitantly raising. A proper environmental management of these metal-rich wastes requires a detailed characterization of the metal mobility as well as an assessment of this new residues stability. The European standard leaching test EN 12457-2, the US EPA TCLP test and the BCR sequential extraction procedure were selected to address the environmental assessment of dispersed alkaline substrate (DAS) residues generated in AMD passive treatment systems. Significant discrepancies were observed in the hazardousness classification of the residues according to the TCLP or EN 12457-2 test. Furthermore, the absence of some important metals (like Fe or Al) in the regulatory limits employed in both leaching tests severely restricts their applicability for metal-rich wastes. The results obtained in the BCR sequential extraction suggest an important influence of the landfill environmental conditions on the metals released from the wastes. To ensure a complete stability of the pollutants in the studied DAS-wastes the contact with water or any other leaching solutions must be avoided and a dry environment needs to be provided in the landfill disposal selected. Copyright © 2012 Elsevier B.V. All rights reserved.

  17. 223Ra-dichloride spectrometric characterization: Searching for the presence of long-lived isotopes with radiological protection implications.

    PubMed

    Sánchez-Jiménez, J; López-Montes, A; Núñez-Martínez, L; Villa-Abaunza, A; Fraile, L M; Sánchez-Tembleque, V; Udías, J M

    2017-03-01

    223 Ra-dichloride was approved with the commercial name of Xofigo in 2014 for treatment of metastatic castration-resistant prostate cancer. 223 Ra is obtained by neutron irradiation of 226 Ra yielding 227 Ac, which decays to 227 Th and 223 Fr, both decaying to 223 Ra. Since 223 Ra is predominantly (95.3%) an alpha emitter with a 11.42days long half-life, the radiopharmaceutical, its remnants, the patient, and waste material can be managed and disposed with low radiation protection requirements. 227 Ac is a long-lived (T 1/2 =21.77years) beta emitter that demands strong radiation protection measures. In particular waste disposal has to follow the International Atomic Energy Agency (IAEA) and European Commission (EC) regulations. Since 227 Ac is involved in the production of 223 Ra, an impurity analysis of each batch is required after production. Due to time restrictions, the manufacturer's detection limit (<0.001%) exceeds the one required to assure that 227 Ac concentrations are below direct disposal levels. To improve the detection limit, long-term accurate spectroscopy is required. Alpha and gamma spectroscopy measurements were carried out at the Complutense University Nuclear Physics Laboratory. After twelve months follow up of a sample, 227 Ac concentration was found to be smaller than 10 -9 . This allows for direct waste disposal and no additional radiation protection restrictions than those required for 223 Ra. The presence of contamination by other radioisotopes was also ruled out by this experiment. Specifically 226 Ra, involved in 223 Ra production as the original parent and with a very long-lived (T 1/2 =1577years) alpha emitter, was also below the experimental detection limit. Copyright © 2017 Associazione Italiana di Fisica Medica. Published by Elsevier Ltd. All rights reserved.

  18. 40 CFR 240.201-1 - Requirement.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ...-1 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES GUIDELINES FOR THE THERMAL PROCESSING OF SOLID WASTES Requirements and Recommended Procedures § 240.201-1 Requirement. Using information provided to them by the waste generator/owner, the responsible agency and the facility...

  19. Hazardous Waste and Wastewater Characterization Survey, Columbus AFB, Mississippi

    DTIC Science & Technology

    1988-06-01

    behind bldg 322 (Liquid Fuels Maintenance Branch). These wastes are then picked up by a waste oil contractor. All other drummed wastes are disposed of...is responsible for custody of the waste until a contractor (currently, Chemical Waste Management) comes to pick up the waste. Prior to disposal...chemicals are used up in the process. Any leftover chemicals are drained and stored in containers for use at a later time. All empty containers are

  20. DOE Office of Scientific and Technical Information (OSTI.GOV)

    Mayberry, J.; Stelle, S.; O`Brien, M.

    The Mixed Waste Integrated Program Logic Diagram was developed to provide technical alternative for mixed wastes projects for the Office of Technology Development`s Mixed Waste Integrated Program (MWIP). Technical solutions in the areas of characterization, treatment, and disposal were matched to a select number of US Department of Energy (DOE) treatability groups represented by waste streams found in the Mixed Waste Inventory Report (MWIR).

  1. 40 CFR 761.347 - First level sampling-waste from existing piles.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... Purposes of Characterization for PCB Disposal in Accordance With § 761.62, and Sampling PCB Remediation... a cone; that is, having a circular base with PCB bulk product waste or PCB remediation waste... one pile. If the PCB bulk product waste or PCB remediation waste consists of more than one pile or...

  2. 40 CFR 194.8 - Approval process for waste shipment from waste generator sites for disposal at the WIPP.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... waste generator site will be conveyed in a letter from the Administrator's authorized representative to... transmittal to the WIPP Waste Information System database of waste characterization data, in accordance with... will be conveyed in a letter from the Administrator's authorized representative to DOE. EPA will not...

  3. 40 CFR 194.8 - Approval process for waste shipment from waste generator sites for disposal at the WIPP.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... waste generator site will be conveyed in a letter from the Administrator's authorized representative to... transmittal to the WIPP Waste Information System database of waste characterization data, in accordance with... will be conveyed in a letter from the Administrator's authorized representative to DOE. EPA will not...

  4. 40 CFR 194.8 - Approval process for waste shipment from waste generator sites for disposal at the WIPP.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... waste generator site will be conveyed in a letter from the Administrator's authorized representative to... transmittal to the WIPP Waste Information System database of waste characterization data, in accordance with... will be conveyed in a letter from the Administrator's authorized representative to DOE. EPA will not...

  5. 40 CFR 194.8 - Approval process for waste shipment from waste generator sites for disposal at the WIPP.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... waste generator site will be conveyed in a letter from the Administrator's authorized representative to... transmittal to the WIPP Waste Information System database of waste characterization data, in accordance with... will be conveyed in a letter from the Administrator's authorized representative to DOE. EPA will not...

  6. Melt processed crystalline ceramic waste forms for advanced nuclear fuel cycles: CRP T21027 1813: Processing technologies for high level waste, formulation of matrices and characterization of waste forms, task 17208: Final report

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Amoroso, J. W.; Marra, J. C.

    2015-08-26

    A multi-phase ceramic waste form is being developed at the Savannah River National Laboratory (SRNL) for treatment of secondary waste streams generated by reprocessing commercial spent nuclear. The envisioned waste stream contains a mixture of transition, alkali, alkaline earth, and lanthanide metals. Ceramic waste forms are tailored (engineered) to incorporate waste components as part of their crystal structure based on knowledge from naturally found minerals containing radioactive and non-radioactive species similar to the radionuclides of concern in wastes from fuel reprocessing. The ability to tailor ceramics to mimic naturally occurring crystals substantiates the long term stability of such crystals (ceramics)more » over geologic timescales of interest for nuclear waste immobilization [1]. A durable multi-phase ceramic waste form tailored to incorporate all the waste components has the potential to broaden the available disposal options and thus minimize the storage and disposal costs associated with aqueous reprocessing. This report summarizes results from three years of work on the IAEA Coordinated Research Project on “Processing technologies for high level waste, formulation of matrices and characterization of waste forms” (T21027), and specific task “Melt Processed Crystalline Ceramic Waste Forms for Advanced Nuclear Fuel Cycles” (17208).« less

  7. Melt processed crystalline ceramic waste forms for advanced nuclear fuel cycles: CRP T21027 1813: Processing technologies for high level waste, formulation of matrices and characterization of waste forms, Task 17208: Final report

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Amoroso, J. W.; Marra, J. C.

    2015-08-26

    A multi-phase ceramic waste form is being developed at the Savannah River National Laboratory (SRNL) for treatment of secondary waste streams generated by reprocessing commercial spent nuclear. The envisioned waste stream contains a mixture of transition, alkali, alkaline earth, and lanthanide metals. Ceramic waste forms are tailored (engineered) to incorporate waste components as part of their crystal structure based on knowledge from naturally found minerals containing radioactive and non-radioactive species similar to the radionuclides of concern in wastes from fuel reprocessing. The ability to tailor ceramics to mimic naturally occurring crystals substantiates the long term stability of such crystals (ceramics)more » over geologic timescales of interest for nuclear waste immobilization [1]. A durable multi-phase ceramic waste form tailored to incorporate all the waste components has the potential to broaden the available disposal options and thus minimize the storage and disposal costs associated with aqueous reprocessing. This report summarizes results from three years of work on the IAEA Coordinated Research Project on “Processing technologies for high level waste, formulation of matrices and characterization of waste forms” (T21027), and specific task “Melt Processed Crystalline Ceramic Waste Forms for Advanced Nuclear Fuel Cycles” (17208).« less

  8. 40 CFR 62.15145 - What are the operating practice requirements for my municipal waste combustion unit?

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... requirements for my municipal waste combustion unit? 62.15145 Section 62.15145 Protection of Environment... Combustion Units Constructed on or Before August 30, 1999 Good Combustion Practices: Operating Requirements § 62.15145 What are the operating practice requirements for my municipal waste combustion unit? (a) You...

  9. 40 CFR 62.15145 - What are the operating practice requirements for my municipal waste combustion unit?

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... requirements for my municipal waste combustion unit? 62.15145 Section 62.15145 Protection of Environment... Combustion Units Constructed on or Before August 30, 1999 Good Combustion Practices: Operating Requirements § 62.15145 What are the operating practice requirements for my municipal waste combustion unit? (a) You...

  10. 40 CFR 62.15145 - What are the operating practice requirements for my municipal waste combustion unit?

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... requirements for my municipal waste combustion unit? 62.15145 Section 62.15145 Protection of Environment... Combustion Units Constructed on or Before August 30, 1999 Good Combustion Practices: Operating Requirements § 62.15145 What are the operating practice requirements for my municipal waste combustion unit? (a) You...

  11. 40 CFR 62.15145 - What are the operating practice requirements for my municipal waste combustion unit?

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... requirements for my municipal waste combustion unit? 62.15145 Section 62.15145 Protection of Environment... Combustion Units Constructed on or Before August 30, 1999 Good Combustion Practices: Operating Requirements § 62.15145 What are the operating practice requirements for my municipal waste combustion unit? (a) You...

  12. 40 CFR 62.15145 - What are the operating practice requirements for my municipal waste combustion unit?

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... requirements for my municipal waste combustion unit? 62.15145 Section 62.15145 Protection of Environment... Combustion Units Constructed on or Before August 30, 1999 Good Combustion Practices: Operating Requirements § 62.15145 What are the operating practice requirements for my municipal waste combustion unit? (a) You...

  13. Independent Review of Elemental Phosphorus Remediation at the Eastern Michaud Flats FMC Operable Unit near Pocatello, Idaho

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Martino, L. E.; Jerden, J. J.; Kimmell, T. A.

    2016-01-01

    If, despite risks to workers and these potential impacts, stakeholders decide that P4 wastes need to be excavated and treated, the Review Team determined that a number of the ETTs examined warrant further consideration for the treatment of P4 waste that has been characterized (for example, P4 waste present in the historical ponds). Nevertheless, concerns about the health and safety of site investigation workers using then-available investigation approaches prevented the collection of subsurface samples containing P4 from large areas of the site (e.g., the railroad swale, the vadose zone beneath the Furnace Building, and the abandoned railcars), As a result,more » the contaminant CSM in those particular areas was not refined enough to allow the Review Team to draw conclusions about using some of the ETTs to treat P4 waste in those areas. The readiness of an ETT for implementation varies depending on many factors, including stakeholder input, permitting, and remedial action construction requirements. Technologies that could be ready for use in the near term (within 1 year) include the following: mechanical excavation, containment technologies, off-site incineration, and drying and mechanical mixing under a tent structure. Technologies that could be ready for use in the mid-term (1 to 2 years) include cutter suction dredging, thermal-hydraulic dredging, and underground pipeline cleaning technologies. Technologies requiring a longer lead time (2 to 5 years) include on-site incineration, a land disposal restriction waste treatment system, an Albright & Wilson batch mud still, post-treatment on-site disposal, and post-treatment off-site disposal.« less

  14. Gravity packaging final waste recovery based on gravity separation and chemical imaging control.

    PubMed

    Bonifazi, Giuseppe; Serranti, Silvia; Potenza, Fabio; Luciani, Valentina; Di Maio, Francesco

    2017-02-01

    Plastic polymers are characterized by a high calorific value. Post-consumer plastic waste can be thus considered, in many cases, as a typical secondary solid fuels according to the European Commission directive on End of Waste (EoW). In Europe the practice of incineration is considered one of the solutions for waste disposal waste, for energy recovery and, as a consequence, for the reduction of waste sent to landfill. A full characterization of these products represents the first step to profitably and correctly utilize them. Several techniques have been investigated in this paper in order to separate and characterize post-consumer plastic packaging waste fulfilling the previous goals, that is: gravity separation (i.e. Reflux Classifier), FT-IR spectroscopy, NIR HyperSpectralImaging (HSI) based techniques and calorimetric test. The study demonstrated as the proposed separation technique and the HyperSpectral NIR Imaging approach allow to separate and recognize the different polymers (i.e. PolyVinyl Chloride (PVC), PolyStyrene (PS), PolyEthylene (PE), PoliEtilene Tereftalato (PET), PolyPropylene (PP)) in order to maximize the removal of the PVC fraction from plastic waste and to perform the full quality control of the resulting products, can be profitably utilized to set up analytical/control strategies finalized to obtain a low content of PVC in the final Solid Recovered Fuel (SRF), thus enhancing SRF quality, increasing its value and reducing the "final waste". Copyright © 2016 Elsevier Ltd. All rights reserved.

  15. High levels of antimony in dust from e-waste recycling in southeastern China.

    PubMed

    Bi, Xiangyang; Li, Zhonggen; Zhuang, Xiaochun; Han, Zhixuan; Yang, Wenlin

    2011-11-01

    Environmental contamination due to uncontrolled e-waste recycling is an emerging global issue. Antimony (Sb) is a toxic element used in semiconductor components and flame retardants for circuit board within electronic equipment. When e-waste is recycled, Sb is released and contaminates the surrounding environment; however, few studies have characterized the extent of this problem. In this study, we investigated Sb and arsenic (As) distributions in indoor dust from 13 e-waste recycling villages in Guiyu, Guangdong Province, southeastern China. Results revealed significantly elevated concentrations of Sb (6.1-232 mg/kg) in dust within all villages, which were 3.9-147 times higher than those from the non e-waste sites, indicating e-waste recycling was an important source of Sb pollution. On the contrary, As concentrations (5.4-17.7 mg/kg) in e-waste dusts were similar to reference values from the control sites. Therefore, dusts emitted from e-waste recycling may be characterized by high Sb/As ratios, which may help identify the contamination due to the e-waste recycling activities. Copyright © 2011 Elsevier B.V. All rights reserved.

  16. Identification of Non-Pertechnetate Species In Hanford Tank Waste, Their Synthesis, Characterization, And Fundamental Chemistry

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Kenneth R. Ashely; Norman Schroeder; Jose A. Olivares

    2004-12-10

    This proposal had three major goals: (1) develop capillary electrophoresis mass spectrometry as a characterization technique, (2) separate a non-pertechnetate fraction from a waste sample and identify the non-pertechnetate species in it by CEMS, and (3) synthesize and characterize bulk quantities of the identified non-pertechnetate species and study their ligand substitution and redox chemistry.

  17. 40 CFR 240.208-1 - Requirement.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ...-1 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES GUIDELINES FOR THE THERMAL PROCESSING OF SOLID WASTES Requirements and Recommended Procedures § 240.208-1 Requirement. Residue and other solid waste products resulting from a thermal process shall be disposed of in an...

  18. 40 CFR 262.20 - General requirements.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... either designate another facility or instruct the transporter to return the waste. (e) The requirements... 262.20 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES (CONTINUED) STANDARDS APPLICABLE TO GENERATORS OF HAZARDOUS WASTE The Manifest § 262.20 General requirements. (a)(1) A...

  19. Applied Geochemistry Special Issue on Environmental geochemistry of modern mining

    USGS Publications Warehouse

    Seal, Robert R.; Nordstrom, D. Kirk

    2015-01-01

    Environmental geochemistry is an integral part of the mine-life cycle, particularly for modern mining. The critical importance of environmental geochemistry begins with pre-mining baseline characterization and the assessment of environmental risks related to mining, continues through active mining especially in water and waste management practices, and culminates in mine closure. The enhanced significance of environmental geochemistry to modern mining has arisen from an increased knowledge of the impacts that historical and active mining can have on the environment, and from new regulations meant to guard against these impacts. New regulations are commonly motivated by advances in the scientific understanding of the environmental impacts of past mining. The impacts can be physical, chemical, and biological in nature. The physical challenges typically fall within the purview of engineers, whereas the chemical and biological challenges typically require a multidisciplinary array of expertise including geologists, geochemists, hydrologists, microbiologists, and biologists. The modern mine-permitting process throughout most of the world now requires that potential risks be assessed prior to the start of mining. The strategies for this risk assessment include a thorough characterization of pre-mining baseline conditions and the identification of risks specifically related to the manner in which the ore will be mined and processed, how water and waste products will be managed, and what the final configuration of the post-mining landscape will be.In the Fall 2010, the Society of Economic Geologists held a short course in conjunction with the annual meeting of the Geological Society of America in Denver, Colorado (USA) to examine the environmental geochemistry of modern mining. The intent was to focus on issues that are pertinent to current and future mines, as opposed to abandoned mines, which have been the focus of numerous previous short courses. The geochemical challenges of current and future mines share similarities with abandoned mines, but differences also exist. Mining and ore processing techniques have changed; the environmental footprint of waste materials has changed; environmental protection has become a more integral part of the mine planning process; and most historical mining was done with limited regard for the environment. The 17 papers in this special issue evolved from the Society of Economic Geologists’ short course.The relevant geochemical processes encompass the source, transport, and fate of contaminants related to the life cycle of a mine. Contaminants include metals and other inorganic species derived from geologic sources such as ore and solid mine waste, and substances brought to the site for ore processing, such as cyanide to leach gold. Factors, such as mine-waste mineralogy, hydrologic setting, mine-drainage chemistry, and microbial activity, that affect the hydrochemical risks from mining are reviewed by Nordstrom et al. In another paper, Nordstrom discusses baseline characterization at mine sites in a regulatory framework, and emphasizes the influence of mineral deposits in producing naturally elevated concentrations of many trace elements in surface water and groundwater. Surface water quality in mineralized watersheds is influenced by a number of processes that act on daily (diel) cycles and can produce dramatic variations in trace element concentrations as described by Gammons et al. Pre-mining baseline characterization studies should strive to capture the magnitude of these diel variations. Desbarats et al., using a case study of mine drainage from a gold mine, illustrate how elements that commonly occur as negatively charged species (anions) in solution, such as arsenic as arsenate, behave in an opposite fashion than most metals, which occur as positively charged species (cations). Significant improvement in the understanding of factors that influence the toxicity of metals to aquatic organisms in surface water has highlighted the importance of aqueous chemistry, particularly dissolved organic carbon, as described by Smith et al. Stream sediment contamination is another important pathway for affecting aquatic organisms, as reviewed by Besser et al. Understanding and predicting environmental consequences from mining begins with knowing the mineralogy and mineral reactivity of the ore, the wastes, and of secondary minerals formed later. Jamieson et al. review the importance of mineralogical studies in mine planning and remediation. A number of types of site-specific studies are needed to identify environmental risks related to individual mines. Lapakko reviews the general framework of mine waste characterization studies that are integral to the mine planning process. Hageman et al. present a comparative study of several static tests commonly used to characterize mine waste.The mining and ore processing practices employed at a specific mine site will vary on the basis of the commodities being targeted, the geology of the deposit, the geometry of the deposit, and the mining and ore processing methods used. Thus, these factors, in addition to the waste management practices used, can result in a variety of end-member mine waste features, each of which has its own set of challenges. Open pit mines and underground mines require waste rock to be removed to access ore. Waste rock presents unique problems because the rock is commonly mineralized at sub-economic grades and has not been processed to remove potentially problematic minerals, such as pyrite. Amos et al. examine the salient aspects of the geochemistry of waste rock. Mill tailings – the waste material after ore minerals have been removed – are a volumetrically important solid waste at many mine sites. Their fine grain size and the options for their management make their behavior in the environment distinct from that of waste rock. Lindsay et al. describe some of these differences through three case-study examples. Subaqueous disposal of tailings is another option described by Moncur et al. Cyanide leaching for gold extraction is a common method throughout the world. Johnson describes environmental aspects of cyanidation. Uranium mining presents unique environmental challenges, particularly since in-situ recovery has seen widespread use. Campbell et al. review the environmental geochemistry of uranium mining and current research on bioremediation. Ore concentrates from many types of metal mining undergo a pyrometallurgical technique known as smelting to extract the metal. Slag is the result of smelting, and it may be an environmental liability or a valuable byproduct, as described by Piatak et al. Finally, the open pits that result from surface mining commonly reach below the water table. At the end of mining, these pits may fill to form lakes that become part of the legacy of the mine. Castendyk et al., in two papers, review theoretical aspects of the environmental limnology of pit lakes. They also describe approaches that have been used to model pit lake water balance, wall-rock contributions to pit lake chemistry, pit lake water quality, and limnological processes, such as vertical mixing, through the use of three case studies.

  20. Hazardous-waste-characterization survey of unknown drums at the 21st Tactical Fighter Wing, Elmendorf and Shemya Air Force Bases, and Galena and King Salmon Airports, Alaska. Final report 2-13 Aug 91

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Bishop, M.S.

    1991-12-01

    At the request of the USAF Regional Hospital Elmendorf/SGPB (PACAF), the Armstrong Laboratory, Occupational and Environmental Health Directorate, conducted a hazardous waste characterization survey of unknown drums at Elmendorf AFB from 2 Aug - 13 Aug 91. The scope of the survey was to sample and characterize drums of unknown material stored at Elmendorf AFB, Shemya AFB, and Galena and King Salmon Airports. Several waste streams were sampled at Elmendorf AFB to revalidate sample results from a previous survey.

  1. DEVELOPMENT OF AN INSOLUBLE SALT SIMULANT TO SUPPORT ENHANCED CHEMICAL CLEANING TESTS

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Eibling, R

    The closure process for high level waste tanks at the Savannah River Site will require dissolution of the crystallized salts that are currently stored in many of the tanks. The insoluble residue from salt dissolution is planned to be removed by an Enhanced Chemical Cleaning (ECC) process. Development of a chemical cleaning process requires an insoluble salt simulant to support evaluation tests of different cleaning methods. The Process Science and Engineering section of SRNL has been asked to develop an insoluble salt simulant for use in testing potential ECC processes (HLE-TTR-2007-017). An insoluble salt simulant has been developed based uponmore » the residues from salt dissolution of saltcake core samples from Tank 28F. The simulant was developed for use in testing SRS waste tank chemical cleaning methods. Based on the results of the simulant development process, the following observations were developed: (1) A composition based on the presence of 10.35 grams oxalate and 4.68 grams carbonate per 100 grams solids produces a sufficiently insoluble solids simulant. (2) Aluminum observed in the solids remaining from actual waste salt dissolution tests is probably precipitated from sodium aluminate due to the low hydroxide content of the saltcake. (3) In-situ generation of aluminum hydroxide (by use of aluminate as the Al source) appears to trap additional salts in the simulant in a manner similar to that expected for actual waste samples. (4) Alternative compositions are possible with higher oxalate levels and lower carbonate levels. (5) The maximum oxalate level is limited by the required Na content of the insoluble solids. (6) Periodic mixing may help to limit crystal growth in this type of salt simulant. (7) Long term storage of an insoluble salt simulant is likely to produce a material that can not be easily removed from the storage container. Production of a relatively fresh simulant is best if pumping the simulant is necessary for testing purposes. The insoluble salt simulant described in this report represents the initial attempt to represent the material which may be encountered during final waste removal and tank cleaning. The final selected simulant was produced by heating and evaporation of a salt slurry sample to remove excess water and promote formation and precipitation of solids with solubility characteristics which are consistent with actual tank insoluble salt samples. The exact anion composition of the final product solids is not explicitly known since the chemical components in the final product are distributed between the solid and liquid phases. By combining the liquid phase analyses and total solids analysis with mass balance requirements a calculated composition of assumed simple compounds was obtained and is shown in Table 0-1. Additional improvements to and further characterization of the insoluble salt simulant are possible. During the development of these simulants it was recognized that: (1) Additional waste characterization on the residues from salt dissolution tests with actual waste samples to determine the amount of species such as carbonate, oxalate and aluminosilicate would allow fewer assumptions to be made in constructing an insoluble salt simulant. (2) The tank history will impact the amount and type of insoluble solids that exist in the salt dissolution solids. Varying the method of simulant production (elevated temperature processing time, degree of evaporation, amount of mixing (shear) during preparation, etc.) should be tested.« less

  2. Development of a simple and sensitive method for the characterization of odorous waste gas emissions by means of solid-phase microextraction (SPME) and GC-MS/olfactometry.

    PubMed

    Kleeberg, K K; Liu, Y; Jans, M; Schlegelmilch, M; Streese, J; Stegmann, R

    2005-01-01

    A solid-phase microextraction (SPME) method has been developed for the extraction of odorous compounds from waste gas. The enriched compounds were characterized by gas chromatography-mass spectrometry (GC-MS) and gas chromatography followed by simultaneous flame ionization detection and olfactometry (GC-FID/O). Five different SPME fiber coatings were tested, and the carboxen/polydimethylsiloxane (CAR/PDMS) fiber showed the highest ability to extract odorous compounds from the waste gas. Furthermore, parameters such as exposure time, desorption temperature, and desorption time have been optimized. The SPME method was successfully used to characterize an odorous waste gas from a fat refinery prior to and after waste gas treatment in order to describe the treatment efficiency of the used laboratory scale plant which consisted of a bioscrubber/biofilter combination and an activated carbon adsorber. The developed method is a valuable approach to provide detailed information of waste gas composition and complements existing methods for the determination of odors. However, caution should be exercised if CAR/PDMS fibers are used for the quantification of odorous compounds in multi-component matrices like waste gas emissions since the relative affinity of each analyte was shown to differ according to the total amount of analytes present in the sample.

  3. 40 CFR 264.229 - Special requirements for ignitable or reactive waste.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... reactive waste. 264.229 Section 264.229 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES (CONTINUED) STANDARDS FOR OWNERS AND OPERATORS OF HAZARDOUS WASTE TREATMENT, STORAGE, AND DISPOSAL FACILITIES Surface Impoundments § 264.229 Special requirements for ignitable or reactive...

  4. DOE Office of Scientific and Technical Information (OSTI.GOV)

    Not Available

    The Office of Civilian Radioactive Waste Management Systems Engineering Management Plan (OCRWM SEMP) specifies the technical management approach for the development of the waste management system, and specifies the approach for the development of each of the system elements -- the waste acceptance system, the transportation system, the Monitored Retrievable Storage (MRS) facility, and the mined geologic disposal system, which includes site characterization activity. The SEMP also delineates how systems engineering will be used by OCRWM to describe the system development process; it identifies responsibilities for its implementation, and specifies the minimum requirements for systems engineering. It also identifies themore » close interrelationship of system engineering and licensing processes. This SEMP, which is a combined OCRWM and M&O SEMP, is part of the top-level program documentation and is prepared in accordance with the direction provided in the Program Management System Manual (PMSM). The relationship of this document to other top level documents in the CRWMS document hierarchy is defined in the PMSM. A systems engineering management plan for each project, which specifies the actions to be taken in implementing systems engineering at the project level, shall be prepared by the respective project managers. [``Program`` refers to the CRWMS-wide activity and ``project`` refers to that level responsible for accomplishing the specific activities of that segment of the program.] The requirements for the project level SEMPs are addressed in Section 4.2.2.2. They represent the minimum set of requirements, and do not preclude the broadening of systems engineering activities to meet the specific needs of each project.« less

  5. 40 CFR 62.14620 - What site-specific documentation is required?

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... POLLUTANTS Federal Plan Requirements for Commercial and Industrial Solid Waste Incineration Units That...) Procedures for receiving, handling, and charging waste. (3) Incinerator startup, shutdown, and malfunction... limits. (7) Reporting and recordkeeping procedures. (8) The waste management plan required under §§ 62...

  6. Characterization of Airborne Particles in an Electronic Waste Recycling Facility and Their Toxicity Assessment

    EPA Science Inventory

    Improper disposal of electronic waste (e-waste) can lead to release of toxic chemicals into the environment and also may pose health risks. Thus, recycling e-waste, instead of landfilling, is considered to be an effective way to reduce pollutant release and exposure. However, lit...

  7. 1987 Oak Ridge model conference: Proceedings: Volume I, Part 3, Waste Management

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Not Available

    1987-01-01

    A conference sponsored by the United States Department of Energy (DOE), was held on waste management. Topics of discussion were transuranic waste management, chemical and physical treatment technologies, waste minimization, land disposal technology and characterization and analysis. Individual projects are processed separately for the data bases. (CBS)

  8. CHARACTERIZATION OF AIR EMISSIONS AND RESIDUAL ASH FROM OPEN BURNING OF ELECTRONIC WASTES DURING SIMULATED RUDIMENTALRY RECYCLING OPERATIONS

    EPA Science Inventory

    Air emissions and residual ash measurements were made from open, uncontrolled combustion of electronic waste (e-waste) during simulations of practices associated with rudimentary e-waste recycling operations. Circuit boards and insulated wires were separately burned to simulate p...

  9. 40 CFR 761.61 - PCB remediation waste.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    .... Subpart N of this part provides a method for collecting new site characterization data or for assessing... left after cleanup is completed. (i) Bulk PCB remediation waste. Bulk PCB remediation waste includes... similar material of minimum thickness spread over the area where remediation waste was removed or left in...

  10. ESP`s Tank 42 washwater transfer to the 241-F/H tank farms

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Aponte, C.I.; Lee, E.D.

    1997-12-01

    As a result of the separation of the High-Level Liquid Waste Department into three separate organizations (formerly there were two) (Concentration, Storage, and Transfer (CST), Waste Pre-Treatment (WPT) and Waste Disposition (WD)) process interface controls were required. One of these controls is implementing the Waste the waste between CST and WPT. At present, CST`s Waste Acceptance Criteria is undergoing revision and WPT has not prepared the required Waste Compliance Plan (WCP). The Waste Pre-Treatment organization is making preparations for transferring spent washwater in Tank 42 to Tank 43 and/or Tank 22. The washwater transfer is expected to complete the washingmore » steps for preparing ESP batch 1B sludge. This report is intended to perform the function of a Waste Compliance Plan for the proposed transfer. Previously, transfers between the Tank Farm and ITP/ESP were controlled by requirements outlined in the Tank Farm`s Technical Standards and ITP/ESP`s Process Requirements. Additionally, these controls are implemented primarily in operating procedure 241-FH-7TSQ and ITP Operations Manual SW16.1-SOP-WTS-1 which will be completed prior to performing the waste transfers.« less

  11. 40 CFR 761.345 - Form of the waste to be sampled.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... Characterization for PCB Disposal in Accordance With § 761.62, and Sampling PCB Remediation Waste Destined for Off-Site Disposal, in Accordance With § 761.61 § 761.345 Form of the waste to be sampled. PCB bulk product waste and PCB remediation waste destined for off-site disposal must be in the form of either flattened...

  12. Draft Site Treatment Plan (DSTP), Volumes I and II

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    D`Amelio, J.

    1994-08-30

    Site Treatment Plans (STP) are required for facilities at which the DOE generates or stores mixed waste. This Draft Site Treatment Plan (DSTP) the second step in a three-phase process, identifies the currently preferred options for treating mixed waste at the Savannah River Site (SRS) or for developing treatment technologies where technologies do not exist or need modification. The DSTP reflects site-specific preferred options, developed with the state`s input and based on existing available information. To the extent possible, the DSTP identifies specific treatment facilities for treating the mixed waste and proposes schedules. Where the selection of specific treatment facilitiesmore » is not possible, schedules for alternative activities such as waste characterization and technology assessment are provided. All schedule and cost information presented is preliminary and is subject to change. The DSTP is comprised of two volumes: this Compliance Plan Volume and the Background Volume. This Compliance Plan Volume proposes overall schedules with target dates for achieving compliance with the land disposal restrictions (LDR) of RCRA and procedures for converting the target dates into milestones to be enforced under the Order. The more detailed discussion of the options contained in the Background Volume is provided for informational purposes only.« less

  13. The use of expanded clay dust in paint manufacturing

    NASA Astrophysics Data System (ADS)

    Sverguzova, S. V.; Sapronova, Zh A.; Starostina, Yu L.; Belovodskiy, E. A.

    2018-01-01

    Production increase of useful products is accompanied by the formation and the accumulation of the vast amounts of industrial wastes, the bulk of which is not involved in the recycling processes. An example of such wastes is dust bag filters of ceramsite production. At the large enterprises, the volume of its formation can reach 7-8 tons of dust per day, which is 10-15% of feedstock mass. The studies on the use of ceramsite production dust as filler pigment in the composition of organic mixed primer of red-brown color are carried out in this work. For comparison, red iron oxide pigment (Pg FGM) was used. The results showed that, primer with the use of expanded clay dust is characterized by the short drying time and meets all regulatory requirements.

  14. Review on Material Synthesis and Characterization of Sodium (Na) Super-Ionic Conductor (NASICON)

    NASA Astrophysics Data System (ADS)

    Kimpa, M. I.; Mayzan, M. Z. H.; Yabagi, J. A.; Nmaya, M. M.; Isah, K. U.; Agam, M. A.

    2018-04-01

    Sodium (Na) Super Ionic Conductor (NASICON) has general formula Na1+ x Zr2P3- xSi x O12 (0 ≤x ≤ 3) derived from its parent compound, sodium zirconium phosphate NaZr2(PO4)3 (NZP) which belong to a rhombohedral crystal structure. This material consists of three-dimensional structure with interesting features such as low thermal expansion coefficient, thermal stability, gas sensor and nuclear waste immobilization that make it viable for industrial applications. Current study presents comprehensive studies on the synthesis and essential characteristics required to understand the theory behind the mechanism that justifies the study of NASICON structure and its application such as lithium ion rechargeable battery, gas sensor, and nuclear waste immobilization and so on.

  15. Characterization and Analysis of Liquid Waste from Marcellus Shale Gas Development.

    PubMed

    Shih, Jhih-Shyang; Saiers, James E; Anisfeld, Shimon C; Chu, Ziyan; Muehlenbachs, Lucija A; Olmstead, Sheila M

    2015-08-18

    Hydraulic fracturing of shale for gas production in Pennsylvania generates large quantities of wastewater, the composition of which has been inadequately characterized. We compiled a unique data set from state-required wastewater generator reports filed in 2009-2011. The resulting data set, comprising 160 samples of flowback, produced water, and drilling wastes, analyzed for 84 different chemicals, is the most comprehensive available to date for Marcellus Shale wastewater. We analyzed the data set using the Kaplan-Meier method to deal with the high prevalence of nondetects for some analytes, and compared wastewater characteristics with permitted effluent limits and ambient monitoring limits and capacity. Major-ion concentrations suggested that most wastewater samples originated from dilution of brines, although some of our samples were more concentrated than any Marcellus brines previously reported. One problematic aspect of this wastewater was the very high concentrations of soluble constituents such as chloride, which are poorly removed by wastewater treatment plants; the vast majority of samples exceeded relevant water quality thresholds, generally by 2-3 orders of magnitude. We also examine the capacity of regional regulatory monitoring to assess and control these risks.

  16. Argonne National Laboratory Expedited Site Characterization: First International Symposium on Integrated Technical Approaches to Site Characterization - Proceedings Volume

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    NONE

    1998-06-08

    Laboratory applications for the analysis of PCBS (polychlorinated biphenyls) in environmental matrices such as soil/sediment/sludge and oil/waste oil were evaluated for potential reduction in waste, source reduction, and alternative techniques for final determination. As a consequence, new procedures were studied for solvent substitution, miniaturization of extraction and cleanups, minimization of reagent consumption, reduction of cost per analysis, and reduction of time. These new procedures provide adequate data that meet all the performance requirements for the determination of PCBS. Use of the new procedures reduced costs for all sample preparation techniques. Time and cost were also reduced by combining the newmore » sample preparation procedures with the power of fast gas chromatography. Separation of Aroclor 1254 was achieved in less than 6 min by using DB-1 and SPB-608 columns. With the greatly shortened run times, reproducibility can be tested quickly and consequently with low cost. With performance-based methodology, the applications presented here can be applied now, without waiting for regulatory approval.« less

  17. Report on Analyses of WAC Samples of Evaporator Overheads - 2004

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    OJI, LAWRENCE

    2004-08-16

    All water received into ETF requires characterization versus the defined Waste Acceptance Criteria. Currently much of the water received by ETF comes from the F and H Evaporator Overheads. Concentration, Storage and Transfer Engineering issued a modified list of species to be determined. In March of 2004, the Tank Farm submitted annual samples from 2F, 2H and 3H Evaporator Overhead streams for characterization to verify compliance with the Effluent Treatment Facility (ETF) Waste Acceptance Criteria (WAC) and to look for organic species. With the exception of high silicon in the 2H and slightly high tritium in 2F evaporator overheads, allmore » the overheads samples were found to be in compliance with the Effluent Treatment Facility WAC. The silicon concentration in the 2H-evaporator overhead, at 44 mg/L, was above the ETF WAC limit of 5 mg/L and tritium at 2.11E+05 dpm/mL in 2F overhead sample was above the ETF WAC limit of 1.2E+05 dpm/mL.« less

  18. Advances in Glass Formulations for Hanford High-Aluminum, High-Iron and Enhanced Sulphate Management in HLW Streams - 13000

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Kruger, Albert A.

    2013-07-01

    The current estimates and glass formulation efforts have been conservative in terms of achievable waste loadings. These formulations have been specified to ensure that the glasses are homogenous, contain essentially no crystalline phases, are processable in joule-heated, ceramic-lined melters and meet Hanford Tank Waste Treatment and Immobilization Plant (WTP) Contract terms. The WTP's overall mission will require the immobilization of tank waste compositions that are dominated by mixtures of aluminum (Al), chromium (Cr), bismuth (Bi), iron (Fe), phosphorous (P), zirconium (Zr), and sulphur (S) compounds as waste-limiting components. Glass compositions for these waste mixtures have been developed based upon previousmore » experience and current glass property models. Recently, DOE has initiated a testing program to develop and characterize HLW glasses with higher waste loadings and higher throughput efficiencies. Results of this work have demonstrated the feasibility of increases in waste loading from about 25 wt% to 33-50 wt% (based on oxide loading) in the glass depending on the waste stream. In view of the importance of aluminum limited waste streams at Hanford (and also Savannah River), the ability to achieve high waste loadings without adversely impacting melt rates has the potential for enormous cost savings from reductions in canister count and the potential for schedule acceleration. Consequently, the potential return on the investment made in the development of these enhancements is extremely favorable. Glass composition development for one of the latest Hanford HLW projected compositions with sulphate concentrations high enough to limit waste loading have been successfully tested and show tolerance for previously unreported tolerance for sulphate. Though a significant increase in waste loading for high-iron wastes has been achieved, the magnitude of the increase is not as substantial as those achieved for high-aluminum, high-chromium, high-bismuth or sulphur. Waste processing rate increases for high-iron streams as a combined effect of higher waste loadings and higher melt rates resulting from new formulations have been achieved. (author)« less

  19. Advances in Glass Formulations for Hanford High-Alumimum, High-Iron and Enhanced Sulphate Management in HLW Streams - 13000

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Kruger, Albert A.

    2013-01-16

    The current estimates and glass formulation efforts have been conservative in terms of achievable waste loadings. These formulations have been specified to ensure that the glasses are homogenous, contain essentially no crystalline phases, are processable in joule-heated, ceramic-lined melters and meet Hanford Tank Waste Treatment and Immobilization Plant (WTP) Contract terms. The WTP?s overall mission will require the immobilization of tank waste compositions that are dominated by mixtures of aluminum (Al), chromium (Cr), bismuth (Bi), iron (Fe), phosphorous (P), zirconium (Zr), and sulphur (S) compounds as waste-limiting components. Glass compositions for these waste mixtures have been developed based upon previousmore » experience and current glass property models. Recently, DOE has initiated a testing program to develop and characterize HLW glasses with higher waste loadings and higher throughput efficiencies. Results of this work have demonstrated the feasibility of increases in waste loading from about 25 wt% to 33-50 wt% (based on oxide loading) in the glass depending on the waste stream. In view of the importance of aluminum limited waste streams at Hanford (and also Savannah River), the ability to achieve high waste loadings without adversely impacting melt rates has the potential for enormous cost savings from reductions in canister count and the potential for schedule acceleration. Consequently, the potential return on the investment made in the development of these enhancements is extremely favorable. Glass composition development for one of the latest Hanford HLW projected compositions with sulphate concentrations high enough to limit waste loading have been successfully tested and show tolerance for previously unreported tolerance for sulphate. Though a significant increase in waste loading for high-iron wastes has been achieved, the magnitude of the increase is not as substantial as those achieved for high-aluminum, high-chromium, high-bismuth or sulphur. Waste processing rate increases for high-iron streams as a combined effect of higher waste loadings and higher melt rates resulting from new formulations have been achieved.« less

  20. Disposal of LLW and ILW in Germany - Characterisation and Documentation of Waste Packages with Respect to the Change of Requirements

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Bandt, G.; Spicher, G.; Steyer, St.

    2008-07-01

    Since the 1998 termination of LLW and ILW emplacement in the Morsleben repository (ERAM), Germany, the treatment, conditioning and documentation of radioactive waste products and packages have been continued on the basis of the waste acceptance requirements as of 1995, prepared for the Konrad repository near Salzgitter in Lower Saxony, Germany. The resulting waste products and packages are stored in interim storage facilities. Due to the Konrad license issued in 2002 the waste acceptance requirements have to be completed by additional requirements imposed by the licensing authority, e. g. for the declaration of chemical waste package constituents. Therefore, documentation ofmore » waste products and packages which are checked by independent experts and are in parts approved by the responsible authority (Office for Radiation Protection, BfS) up to now will have to be checked again for fulfilling the final waste acceptance requirements prior to disposal. In order to simplify these additional checks, databases are used to ensure an easy access to all known facts about the waste packages. A short balance of the existing waste products and packages which are already checked and partly approved by BfS as well as an overview on the established databases ensuring a fast access to the known facts about the conditioning processes is presented. (authors)« less

  1. Waste-water characterization/hazardous-waste survey, Beale Air Force Base, California. Final report, 12-26 September 1988

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Attebery, C.W.; Zimmer, A.T.; Hedgecock, N.S.

    1989-01-01

    A waste-water characterization hazardous-waste survey was conducted at Beale AFB by USAFOEHL/ECQ personnel to provide the base with sufficient information to address a State of California Notice of Violation concerning excessive discharges of boron and cyanide from the base sewage-treatment plant (STP). The results of the survey showed that the 9th RTS Precision Photo Lab along with other film-processing organizations were major contributors to the boron and cyanide discharge problems being experienced by the base STP. Maintenance organizations that utilize soaps and detergents that contain boron and cyanide also contributed to the problem.

  2. 40 CFR 63.1091 - What do the waste requirements do?

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ...) National Emission Standards for Ethylene Manufacturing Process Units: Heat Exchange Systems and Waste... Operations. There are some differences between the ethylene production waste requirements and those of...

  3. Performance test results of noninvasive characterization of Resource Conservation and Recovery Act surrogate waste by prompt gamma neutron activation analysis

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Gehrke, R.J.; Streier, G.G.

    1997-03-01

    During FY-96, a performance test was carried out with funding from the Mixed Waste Focus Area (MWFA) of the Department of Energy (DOE) to determine the noninvasive elemental assay capabilities of commercial companies for Resource Conservation and Recovery Act (RCRA) metals present in 8-gal drums containing surrogate waste. Commercial companies were required to be experienced in the use of prompt gamma neutron activation analysis (PGNAA) techniques and to have a prototype assay system with which to conduct the test assays. Potential participants were identified through responses to a call for proposals advertised in the Commerce Business Daily and through personalmore » contacts. Six companies were originally identified. Two of these six were willing and able to participate in the performance test, as described in the test plan, with some subsidizing from the DOE MWFA. The tests were conducted with surrogate sludge waste because (1) a large volume of this type of waste awaits final disposition and (2) sludge tends to be somewhat homogeneous. The surrogate concentrations of the above RCRA metals ranged from {approximately} 300 ppm to {approximately} 20,000 ppm. The lower limit was chosen as an estimate of the expected sensitivity of detection required by noninvasive, pretreatment elemental assay systems to be of value for operational and compliance purposes and to still be achievable with state-of-the-art methods of analysis. The upper limit of {approximately} 20,000 ppm was chosen because it is the opinion of the author that assay above this concentration level is within current state-of-the-art methods for most RCRA constituents. This report is organized into three parts: Part 1, Test Plan to Evaluate the Technical Status of Noninvasive Elemental Assay Techniques for Hazardous Waste; Part 2, Participants` Results; and Part 3, Evaluation of and Comments on Participants` Results.« less

  4. Use of thermal analysis techniques (TG-DSC) for the characterization of diverse organic municipal waste streams to predict biological stability prior to land application

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Fernandez, Jose M., E-mail: joseman@sas.upenn.edu; Plaza, Cesar; Polo, Alfredo

    2012-01-15

    Highlights: Black-Right-Pointing-Pointer Thermal analysis was used to assess stability and composition of organic matter in three diverse municipal waste streams. Black-Right-Pointing-Pointer Results were compared with C mineralization during 90-day incubation, FTIR and {sup 13}C NMR. Black-Right-Pointing-Pointer Thermal analysis reflected the differences between the organic wastes before and after the incubation. Black-Right-Pointing-Pointer The calculated energy density showed a strong correlation with cumulative respiration. Black-Right-Pointing-Pointer Conventional and thermal methods provide complimentary means of characterizing organic wastes. - Abstract: The use of organic municipal wastes as soil amendments is an increasing practice that can divert significant amounts of waste from landfill, and providesmore » a potential source of nutrients and organic matter to ameliorate degraded soils. Due to the high heterogeneity of organic municipal waste streams, it is difficult to rapidly and cost-effectively establish their suitability as soil amendments using a single method. Thermal analysis has been proposed as an evolving technique to assess the stability and composition of the organic matter present in these wastes. In this study, three different organic municipal waste streams (i.e., a municipal waste compost (MC), a composted sewage sludge (CS) and a thermally dried sewage sludge (TS)) were characterized using conventional and thermal methods. The conventional methods used to test organic matter stability included laboratory incubation with measurement of respired C, and spectroscopic methods to characterize chemical composition. Carbon mineralization was measured during a 90-day incubation, and samples before and after incubation were analyzed by chemical (elemental analysis) and spectroscopic (infrared and nuclear magnetic resonance) methods. Results were compared with those obtained by thermogravimetry (TG) and differential scanning calorimetry (DSC) techniques. Total amounts of CO{sub 2} respired indicated that the organic matter in the TS was the least stable, while that in the CS was the most stable. This was confirmed by changes detected with the spectroscopic methods in the composition of the organic wastes due to C mineralization. Differences were especially pronounced for TS, which showed a remarkable loss of aliphatic and proteinaceous compounds during the incubation process. TG, and especially DSC analysis, clearly reflected these differences between the three organic wastes before and after the incubation. Furthermore, the calculated energy density, which represents the energy available per unit of organic matter, showed a strong correlation with cumulative respiration. Results obtained support the hypothesis of a potential link between the thermal and biological stability of the studied organic materials, and consequently the ability of thermal analysis to characterize the maturity of municipal organic wastes and composts.« less

  5. Characterization of Volume F Trash from the Three FY11 STS Missions: Trash Weights and Categorization and Microbial Characterization

    NASA Technical Reports Server (NTRS)

    Strayer, Richard F.; Hummerick, Mary E.; Richards, Jeffrey T.; McCoy, LaShelle E.; Roberts, Michael S.; Wheller, Raymond M.

    2011-01-01

    The project reported here provides microbial characterization support to the Waste Management Systems (WMS) element of NASA's Life Support and Habitation Systems (LSHS) program. Conventional microbiological methods were used to detect and enumerate microorganisms in STS Volume F Compartment trash for three shuttle missions: STS 133, 134, and 135. This trash was usually made available within 2 days of landing at KSC. The Volume F bag was weighed, opened and the contents were cataloged and placed into categories: personal hygiene items - inclUding EVA maximum absorbent garments (MAGs) and Elbow packs (daily toilet wipes, etc), drink containers, food waste (and containers), office waste (paper), and packaging materials - plastic film and duct tape. The average wet trash generation rate for the three STS missions was 0.362 % 0.157 kgwet crew 1 d-1 . This was considerably lower and more variable than the average rate for 4 STS missions reported for FY10. Trash subtotals by category: personal hygiene wastes, 56%; drink items, 11 %; food wastes, 18%; office waste, 3%; and plastic film, 12%. These wastes have an abundance of easily biodegraded compounds that can support the growth of microorganisms. Microbial characterization of trash showed that large numbers of bacteria and fungi have taken advantage of this readily available nutrient source to proliferate. Exterior and interior surfaces of plastic film bags containing trash were sampled and counts of cultivatable microbes were generally low and mostly occurred on trash bundles within the exterior trash bags. Personal hygiene wastes, drink containers, and food wastes and packaging all contained high levels of, mostly, aerobic heterotrophic bacteria and lower levels of yeasts and molds. Isolates from plate count media were obtained and identified .and were mostly aerobic heterotrophs with some facultative anaerobes. These are usually considered common environmental isolates on Earth. However, several pathogens were also isolated: Staphylococcus aureus and Escherichia coli.

  6. 40 CFR 265.281 - Special requirements for ignitable or reactive waste.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 40 Protection of Environment 25 2010-07-01 2010-07-01 false Special requirements for ignitable or reactive waste. 265.281 Section 265.281 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY... waste is immediately incorporated into the soil so that: (1) The resulting waste, mixture, or...

  7. (Low-level waste disposal facility siting and site characterization)

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Mezga, L.J.; Ketelle, R.H.; Pin, F.G.

    A US team consisting of representatives of Oak Ridge National Laboratory (ORNL), Savannah River Plant (SRP), Savannah river Laboratory (SRL), and the Department of Energy Office of Defense Waste and Byproducts Management participated in the fourth meeting held under the US/French Radioactive Waste Management Agreement between the US Department of Energy and the Commissariat a l'Energie Atomique. This meeting, held at Agence Nationale pour les Gestion des Dechets Radioactifs' (ANDRA's) Headquarters in Paris, was a detailed, technical topical workshop focusing on Low-Level Waste Disposal Facility Siting and Site Characterization.'' The meeting also included a visit to the Centre de lamore » Manche waste management facility operated by ANDRA to discuss and observe the French approach to low-level waste management. The final day of the meeting was spent at the offices of Societe Generale pour les Techniques Nouvelles (SGN) discussing potential areas of future cooperation and exchange. 20 figs.« less

  8. RCRA, superfund and EPCRA hotline training module. Introduction to: Containers (40 cfr parts 264/265, subpart i; section 261.7) updated July 1996

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    NONE

    1996-07-01

    The module reviews two sets of regulatory requirements for containers: requirements that pertain to the management of hazardous waste containers and regulations governing residues of hazardous waste in empty containers. It defines `container` and `empty container` and provides examples and citations for each. It provides an overview of the requirements for the design and operation of hazardous waste containers. It explains the difference between the container standards set out in part 264 and part 265. It states the requirements for rendering a hazardous waste container `RCRA empty`. It explains when container rinsate must be managed as a hazardous waste.

  9. 40 CFR 60.1200 - What are the operating practice requirements for my municipal waste combustion unit?

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... requirements for my municipal waste combustion unit? 60.1200 Section 60.1200 Protection of Environment... SOURCES Standards of Performance for Small Municipal Waste Combustion Units for Which Construction is... Good Combustion Practices: Operating Requirements § 60.1200 What are the operating practice...

  10. 40 CFR 60.1200 - What are the operating practice requirements for my municipal waste combustion unit?

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... requirements for my municipal waste combustion unit? 60.1200 Section 60.1200 Protection of Environment... SOURCES Standards of Performance for Small Municipal Waste Combustion Units for Which Construction is... Good Combustion Practices: Operating Requirements § 60.1200 What are the operating practice...

  11. 40 CFR 60.1200 - What are the operating practice requirements for my municipal waste combustion unit?

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... requirements for my municipal waste combustion unit? 60.1200 Section 60.1200 Protection of Environment... SOURCES Standards of Performance for Small Municipal Waste Combustion Units for Which Construction is... Good Combustion Practices: Operating Requirements § 60.1200 What are the operating practice...

  12. 40 CFR 60.1200 - What are the operating practice requirements for my municipal waste combustion unit?

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... requirements for my municipal waste combustion unit? 60.1200 Section 60.1200 Protection of Environment... SOURCES Standards of Performance for Small Municipal Waste Combustion Units for Which Construction is... Good Combustion Practices: Operating Requirements § 60.1200 What are the operating practice...

  13. 40 CFR 60.1200 - What are the operating practice requirements for my municipal waste combustion unit?

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... requirements for my municipal waste combustion unit? 60.1200 Section 60.1200 Protection of Environment... SOURCES Standards of Performance for Small Municipal Waste Combustion Units for Which Construction is... Good Combustion Practices: Operating Requirements § 60.1200 What are the operating practice...

  14. 40 CFR 264.259 - Special requirements for hazardous wastes FO20, FO21, FO22, FO23, FO26, and FO27.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... wastes FO20, FO21, FO22, FO23, FO26, and FO27. 264.259 Section 264.259 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES (CONTINUED) STANDARDS FOR OWNERS AND OPERATORS OF HAZARDOUS WASTE TREATMENT, STORAGE, AND DISPOSAL FACILITIES Waste Piles § 264.259 Special requirements for...

  15. 40 CFR 264.259 - Special requirements for hazardous wastes FO20, FO21, FO22, FO23, FO26, and FO27.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... wastes FO20, FO21, FO22, FO23, FO26, and FO27. 264.259 Section 264.259 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES (CONTINUED) STANDARDS FOR OWNERS AND OPERATORS OF HAZARDOUS WASTE TREATMENT, STORAGE, AND DISPOSAL FACILITIES Waste Piles § 264.259 Special requirements for...

  16. 40 CFR 264.259 - Special requirements for hazardous wastes FO20, FO21, FO22, FO23, FO26, and FO27.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... wastes FO20, FO21, FO22, FO23, FO26, and FO27. 264.259 Section 264.259 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES (CONTINUED) STANDARDS FOR OWNERS AND OPERATORS OF HAZARDOUS WASTE TREATMENT, STORAGE, AND DISPOSAL FACILITIES Waste Piles § 264.259 Special requirements for...

  17. 40 CFR 761.345 - Form of the waste to be sampled.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ....345 Section 761.345 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) TOXIC... Characterization for PCB Disposal in Accordance With § 761.62, and Sampling PCB Remediation Waste Destined for Off... waste and PCB remediation waste destined for off-site disposal must be in the form of either flattened...

  18. 40 CFR 761.345 - Form of the waste to be sampled.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ....345 Section 761.345 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) TOXIC... Characterization for PCB Disposal in Accordance With § 761.62, and Sampling PCB Remediation Waste Destined for Off... waste and PCB remediation waste destined for off-site disposal must be in the form of either flattened...

  19. 40 CFR 761.345 - Form of the waste to be sampled.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ....345 Section 761.345 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) TOXIC... Characterization for PCB Disposal in Accordance With § 761.62, and Sampling PCB Remediation Waste Destined for Off... waste and PCB remediation waste destined for off-site disposal must be in the form of either flattened...

  20. 40 CFR 761.265 - Sampling bulk PCB remediation waste and porous surfaces.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 40 Protection of Environment 30 2010-07-01 2010-07-01 false Sampling bulk PCB remediation waste..., DISTRIBUTION IN COMMERCE, AND USE PROHIBITIONS Cleanup Site Characterization Sampling for PCB Remediation Waste in Accordance with § 761.61(a)(2) § 761.265 Sampling bulk PCB remediation waste and porous surfaces...

  1. 40 CFR 761.269 - Sampling liquid PCB remediation waste.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 40 Protection of Environment 30 2010-07-01 2010-07-01 false Sampling liquid PCB remediation waste..., AND USE PROHIBITIONS Cleanup Site Characterization Sampling for PCB Remediation Waste in Accordance with § 761.61(a)(2) § 761.269 Sampling liquid PCB remediation waste. (a) If the liquid is single phase...

  2. WOOD PRODUCTS IN THE WASTE STREAM: CHARACTERIZATION AND COMBUSTION EMISSIONS - VOLUME 2. APPENDICES

    EPA Science Inventory

    The report gives results of a study of technical, public policy, and regulatory issues that affect the processing and combustion of waste wood for fuel. (NOTE: Waste wood is wood that is separated from a solid-waste stream, processed into a uniform-sized product, and reused for o...

  3. WOOD PRODUCTS IN THE WASTE STREAM: CHARACTERIZATION AND COMBUSTION EMISSIONS - VOLUME 1. TECHNICAL REPORT

    EPA Science Inventory

    The report gives results of a study of technical, public policy, and regulatory issues that affect the processing and combustion of waste wood for fuel. (NOTE: Waste wood is wood that is separated from a solid-waste stream, processed into a uniform-sized product, and reused for o...

  4. [Cause-specific mortality in an area of Campania with numerous waste disposal sites].

    PubMed

    Altavista, Pierluigi; Belli, Stefano; Bianchi, Fabrizio; Binazzi, Alessandra; Comba, Pietro; Del Giudice, Raffaele; Fazzo, Lucia; Felli, Angelo; Mastrantonio, Marina; Menegozzo, Massimo; Musmeci, Loredana; Pizzuti, Renato; Savarese, Anna; Trinca, Stefania; Uccelli, Raffaella

    2004-01-01

    To investigate cause-specific mortality in an area of Campania region, in the surroundings of Naples, characterized by many toxic waste dumping grounds sites and by widespread burning of urban wastes. The study area was characterized by examining the spatial distribution of waste disposal sites and toxic waste dumping grounds, using a geographic information system (GIS). Mortality (1986-2000) was studied in the three municipalities of Giugliano in Campania, Qualiano and Villaricca, encompassing a population of about 150,000 inhabitants. Mortality rates of the population resident in the Campania region were used in order to generate expected figures. Causes of death of a priori interest where those previously associated to residence in the neighbourhood of (toxic) waste sites, including lung cancer, bladder cancer, leukemia and liver cancer. Overall 39 waste sites, 27 of which characterized by the likely presence of toxic wastes, were identified in the area of interest. A good agreement was found between two independent surveys of the Regional Environmental Protection Agency and of the environmentalist association Legambiente. Cancer mortality was significantly increased, with special reference to malignant neoplasm of lung, pleura, larynx, bladder, liver and brain. Circulatory diseases were also significantly in excess and diabetes showed some increases. Mortality statistics provide preliminary evidence of the disease load in the area. Mapping waste dumping grounds provides information for defining high risk areas. Improvements in exposure assessment together with the use of a range of health data (hospital discharge cards, malformation notifications, observations of general practitioners) will contribute to second generation studies aimed at inferring causal relationships.

  5. DOE Office of Scientific and Technical Information (OSTI.GOV)

    Not Available

    The Nuclear Waste Policy Act of 1982 (42 USC sections 10101-10226) requires the environmental assessment of a proposed site to include a statement of the basis for nominating a site as suitable for characterization. Volume 2 provides a detailed statement evaluating the site suitability of the Deaf Smith County Site under DOE siting guidelines, as well as a comparison of the Deaf Smith County Site to the other sites under consideration. The evaluation of the Deaf Smith County Site is based on the impacts associated with the reference repository design, but the evaluation will not change if based on themore » Mission Plan repository concept. The second part of this document compares the Deaf Smith County Site to Davis Canyon, Hanford, Richton Dome and Yucca Mountain. This comparison is required under DOE guidelines and is not intended to directly support subsequent recommendation of three sites for characterization as candidate sites. 259 refs., 29 figs., 66 refs. (MHB)« less

  6. Characterization and potential recycling of home building wood waste

    Treesearch

    Philip A. Araman; D.P. Hindman; M.F. Winn

    2010-01-01

    Construction waste represents a significant portion of landfill waste, estimated as 17% of the total waste stream. Wood construction waste of a 2000 square foot single family home we found to be 1500-3700 lbs of solid-sawn wood, and 1000-1800 lbs of engineered wood products (EWP). Much of the solid-sawn lumber and EWPs could be recycled into several products. Through a...

  7. Environmental waste site characterization utilizing aerial photographs and satellite imagery: Three sites in New Mexico, USA

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Van Eeckhout, E.; Pope, P.; Becker, N.

    1996-04-01

    The proper handling and characterization of past hazardous waste sites is becoming more and more important as world population extends into areas previously deemed undesirable. Historical photographs, past records, current aerial satellite imagery can play an important role in characterizing these sites. These data provide clear insight into defining problem areas which can be surface samples for further detail. Three such areas are discussed in this paper: (1) nuclear wastes buried in trenches at Los Alamos National Laboratory, (2) surface dumping at one site at Los Alamos National Laboratory, and (3) the historical development of a municipal landfill near Lasmore » Cruces, New Mexico.« less

  8. Waste Isolation Pilot Plant No-migration variance petition. Addendum: Volume 7, Revision 1

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Not Available

    1990-03-01

    This report describes various aspects of the Waste Isolation Pilot Plant (WIPP) including design data, waste characterization, dissolution features, ground water hydrology, natural resources, monitoring, general geology, and the gas generation/test program.

  9. Municipal solid waste characterizations and management strategies for the Lower Rio Grande Valley, Texas.

    PubMed

    Chang, Ni-Bin; Davila, Eric

    2008-01-01

    The Lower Rio Grande Valley (LRGV or Valley) in Texas, facing the big waste management challenge along the US-Mexico border today, is at the crossroads as a result of the rapid population growth, the scarcity of landfill space, the bi-nation's trade impacts, and the illusive goal of environmental sustainability. This paper offers a unique municipal solid waste investigation with regard to both physical and chemical characteristics leading to illuminate the necessary management policies with greater regional relevancy. With multiple sampling campaigns conducted during the spring of 2005, this study holistically summarizes the composition of solid waste, the statistical distribution patterns of key recyclable items, and the heating value in an uncertain environment. Research findings indicate that high fractions of plastics and paper in the waste stream imply a strong potential for energy recovery. Incineration options are thus bolstered by mildly high heating values across 10 cities in this region, which may lead to save land resources required for final disposal and increase electricity generation in the long run. Additional regression analyses further identify the correlation between recyclable items and heating value, which show that current recycling programs permit no obvious negative impacts on the incineration option. Final statistical hypothesis tests for both the Brownsville-Harlingen-San Benito and the McAllen-Edinburg-Mission metropolitan regions help foster consistent management strategies across the Valley regardless of the trivial differences of waste characteristics in between.

  10. 40 CFR 63.1094 - What waste streams are exempt from the requirements of this subpart?

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... CATEGORIES (CONTINUED) National Emission Standards for Ethylene Manufacturing Process Units: Heat Exchange... section are exempt from this subpart. (a) Waste in the form of gases or vapors that is emitted from process fluids. (b) Waste that is contained in a segregated storm water sewer system. Waste Requirements ...

  11. [Substantiation of a complex of radiation-hygienic approaches to the management of very low-level waste].

    PubMed

    Korenkov, I P; Lashchenova, T N; Shandala, N K

    2015-01-01

    In the article there are presented materials on radiation-hygienic approaches to the treatment of very low level radioactive waste (VLLW) and industrial waste containing radionuclides. There is done detailed information on radiation-hygienic principles and criteria for the assurance ofradiation safety in the collection, transportation, storage and processing of VLLW as a category of radioactive waste.. Particular attention is paid to the problem of designing VLLW landfill site choice, system of radiation monitoring in operation and decommissioning of the landfill. There are presented data about the criteria for the release of VLLW buried at the site, from regulatory control. Also there are considered in detail the radiation-hygienic requirements for radiation safety of industrial waste containing radionuclides for which there is assumed unlimited and limited use of solid materials in economic activity, based on the requirements ofthe revised Basic Sanitary Rules for Radiation Safety - 99/2010. There are considered basic requirements for the organization of industrial waste landfill. As an example, there-are presented the hygiene requirements for industrial waste management and results of waste categorization in Northern Federal Enterprise for Radioactive Waste Management.

  12. Isolation and characterization of potential lactic acid bacteria (LAB) from freshwater fish processing wastes for application in fermentative utilisation of fish processing waste

    PubMed Central

    R, Jini; HC, Swapna; Rai, Amit Kumar; R, Vrinda; PM, Halami; NM, Sachindra; N, Bhaskar

    2011-01-01

    Proteolytic and/or lipolytic lactic acid bacteria (LAB) were isolated from visceral wastes of different fresh water fishes. LAB count was found to be highest in case of visceral wastes of Mrigal (5.88 log cfu/g) and lowest in that of tilapia (4.22 log cfu/g). Morphological, biochemical and molecular characterization of the selected LAB isolates were carried out. Two isolates FJ1 (E. faecalis NCIM5367) and LP3 (P. acidilactici NCIM5368) showed both proteolytic and lipolytic properties. All the six native isolates selected for characterization showed antagonistic properties against several human pathogens. All the native isolates were sensitive to antibiotics cephalothin and clindamycin; and, resistant to cotrimoxazole and vancomycin. Considering individually, P. acidilactici FM37, P. acidilactici MW2 and E. faecalis FD3 were sensitive to erythromycin. The two strains FJ1 (E. faecalis NCIM 5367) and LP3 (P. acidilactici NCIM 5368) that had both proteolytic and lipolytic properties have the potential for application in fermentative recovery of lipids and proteins from fish processing wastes. PMID:24031786

  13. Methanol from wood waste : a technical and economic study

    Treesearch

    A. E. Hokanson; R. M. Rowell

    1977-01-01

    A methanol-from-wood waste facility having a capacity of 50 million gallons per year requires 1,500 ovendry tons (ODT) of wood waste per day. The yield of methanol from wood is about 38 percent, or about 100 gallons per ODT of wood. This yield is based on all process energy required coming from the wood waste. At a wood waste cost of $15/ODT, the selling price of...

  14. Use of thermal analysis techniques (TG-DSC) for the characterization of diverse organic municipal waste streams to predict biological stability prior to land application.

    PubMed

    Fernández, José M; Plaza, César; Polo, Alfredo; Plante, Alain F

    2012-01-01

    The use of organic municipal wastes as soil amendments is an increasing practice that can divert significant amounts of waste from landfill, and provides a potential source of nutrients and organic matter to ameliorate degraded soils. Due to the high heterogeneity of organic municipal waste streams, it is difficult to rapidly and cost-effectively establish their suitability as soil amendments using a single method. Thermal analysis has been proposed as an evolving technique to assess the stability and composition of the organic matter present in these wastes. In this study, three different organic municipal waste streams (i.e., a municipal waste compost (MC), a composted sewage sludge (CS) and a thermally dried sewage sludge (TS)) were characterized using conventional and thermal methods. The conventional methods used to test organic matter stability included laboratory incubation with measurement of respired C, and spectroscopic methods to characterize chemical composition. Carbon mineralization was measured during a 90-day incubation, and samples before and after incubation were analyzed by chemical (elemental analysis) and spectroscopic (infrared and nuclear magnetic resonance) methods. Results were compared with those obtained by thermogravimetry (TG) and differential scanning calorimetry (DSC) techniques. Total amounts of CO(2) respired indicated that the organic matter in the TS was the least stable, while that in the CS was the most stable. This was confirmed by changes detected with the spectroscopic methods in the composition of the organic wastes due to C mineralization. Differences were especially pronounced for TS, which showed a remarkable loss of aliphatic and proteinaceous compounds during the incubation process. TG, and especially DSC analysis, clearly reflected these differences between the three organic wastes before and after the incubation. Furthermore, the calculated energy density, which represents the energy available per unit of organic matter, showed a strong correlation with cumulative respiration. Results obtained support the hypothesis of a potential link between the thermal and biological stability of the studied organic materials, and consequently the ability of thermal analysis to characterize the maturity of municipal organic wastes and composts. Copyright © 2011 Elsevier Ltd. All rights reserved.

  15. 40 CFR 60.1690 - What are the operating practice requirements for my municipal waste combustion unit?

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... requirements for my municipal waste combustion unit? 60.1690 Section 60.1690 Protection of Environment... SOURCES Emission Guidelines and Compliance Times for Small Municipal Waste Combustion Units Constructed on or Before August 30, 1999 Model Rule-Good Combustion Practices: Operating Requirements § 60.1690 What...

  16. 40 CFR 60.1690 - What are the operating practice requirements for my municipal waste combustion unit?

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... requirements for my municipal waste combustion unit? 60.1690 Section 60.1690 Protection of Environment... SOURCES Emission Guidelines and Compliance Times for Small Municipal Waste Combustion Units Constructed on or Before August 30, 1999 Model Rule-Good Combustion Practices: Operating Requirements § 60.1690 What...

  17. 40 CFR 60.1690 - What are the operating practice requirements for my municipal waste combustion unit?

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... requirements for my municipal waste combustion unit? 60.1690 Section 60.1690 Protection of Environment... SOURCES Emission Guidelines and Compliance Times for Small Municipal Waste Combustion Units Constructed on or Before August 30, 1999 Model Rule-Good Combustion Practices: Operating Requirements § 60.1690 What...

  18. 40 CFR 60.1690 - What are the operating practice requirements for my municipal waste combustion unit?

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... requirements for my municipal waste combustion unit? 60.1690 Section 60.1690 Protection of Environment... SOURCES Emission Guidelines and Compliance Times for Small Municipal Waste Combustion Units Constructed on or Before August 30, 1999 Model Rule-Good Combustion Practices: Operating Requirements § 60.1690 What...

  19. 40 CFR 60.1690 - What are the operating practice requirements for my municipal waste combustion unit?

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... requirements for my municipal waste combustion unit? 60.1690 Section 60.1690 Protection of Environment... SOURCES Emission Guidelines and Compliance Times for Small Municipal Waste Combustion Units Constructed on or Before August 30, 1999 Model Rule-Good Combustion Practices: Operating Requirements § 60.1690 What...

  20. Glasses for immobilization of low- and intermediate-level radioactive waste

    NASA Astrophysics Data System (ADS)

    Laverov, N. P.; Omel'yanenko, B. I.; Yudintsev, S. V.; Stefanovsky, S. V.; Nikonov, B. S.

    2013-03-01

    Reprocessing of spent nuclear fuel (SNF) for recovery of fissionable elements is a precondition of long-term development of nuclear energetics. Solution of this problem is hindered by the production of a great amount of liquid waste; 99% of its volume is low- and intermediate-level radioactive waste (LILW). The volume of high-level radioactive waste (HLW), which is characterized by high heat release, does not exceed a fraction of a percent. Solubility of glasses at an elevated temperature makes them unfit for immobilization of HLW, the insulation of which is ensured only by mineral-like matrices. At the same time, glasses are a perfect matrix for LILW, which are distinguished by low heat release. The solubility of borosilicate glass at a low temperature is so low that even a glass with relatively low resistance enables them to retain safety of under-ground LILW depositories without additional engineering barriers. The optimal technology of liquid confinement is their concentration and immobilization in borosilicate glasses, which are disposed in shallow-seated geological repositories. The vitrification of 1 m3 liquid LILW with a salt concentration of ˜300 kg/m3 leaves behind only 0.2 m3 waste, that is, 4-6 times less than by bitumen impregnation and 10 times less than by cementation. Environmental and economic advantages of LILW vitrification result from (1) low solubility of the vitrified LILW in natural water; (2) significant reduction of LILW volume; (3) possibility to dispose the vitrified waste without additional engineering barriers under shallow conditions and in diverse geological media; (4) the strength of glass makes its transportation and storage possible; and finally (5) reliable longterm safety of repositories. When the composition of the glass matrix for LILW is being chosen, attention should be paid to the factors that ensure high technological and economic efficiency of vitrification. The study of vitrified LILW from the Kursk nuclear power plant with high-power channel reactors (HPCR; equivalent Russian acronym, RBMK) and the Kalinin nuclear power plant with pressurized water reactors (PWR; equivalent Russian acronym VVER) after their 14-yr storage in the shallow-seated repository at the MosNPO Radon testing ground has confirmed the safety of repositories ensured by confinement properties of borosilicate matrix. The most efficient vitrification technology is based on cold crucible induction melting. If the content of a chemical element in waste exceeds its solubility in glass, a crystalline phase is formed in the course of vitrification, so that the glass ceramics become a matrix for such waste. Vitrified waste with high Fe; Na and Al; Na, Fe, and Al; Na and B is characterized. The composition of frit and its proportion to waste depends on waste composition. This procedure requires careful laboratory testing.

  1. Utilization of Activated Carbon Prepared from Aceh Coffee Grounds as Bio-sorbent for Treatment of Fertilizer Industrial Waste Water

    NASA Astrophysics Data System (ADS)

    Mariana, M.; Mahidin, M.; Mulana, F.; Aman, F.

    2018-05-01

    The people of Aceh are well known as coffee drinkers. Therefore, a lot of coffee shops have been established in Aceh in the past decade. The growing of coffee shops resulting to large amounts of coffee waste produced in Aceh Province that will become solid waste if not wisely utilized. The high carbon content in coffee underlined as background of this research to be utilized those used coffee grounds as bio-sorbent. The preparation of activated carbon from coffee grounds by using carbonization method that was initially activated with HCl was expected to increase the absorption capacity. The prepared activated carbon with high reactivity was applied to adsorb nitrite, nitrate and ammonia in wastewater outlet of PT. PIM wastewater pond. Morphological structure of coffee waste was analyzed by using Scanning Electron Microscopy (SEM) and Fourier transform infrared spectroscopy (FTIR). The result showed that the adsorption capacity of iodine was equal to 856.578 mg/g. From the characterization results, it was concluded that the activated carbon from coffee waste complied to the permitted quality standards in accordance with the quality requirements of activated carbon SNI No. 06-3730-1995. Observed from the adsorption efficiency, the bio-sorbent showed a tendency of adsorbing more ammonia than nitrite and nitrate of PT. PIM wastewater with ammonia absorption efficiency of 56%.

  2. Life cycle comparison of waste-to-energy alternatives for municipal waste treatment in Chilean Patagonia.

    PubMed

    Bezama, Alberto; Douglas, Carla; Méndez, Jacqueline; Szarka, Nóra; Muñoz, Edmundo; Navia, Rodrigo; Schock, Steffen; Konrad, Odorico; Ulloa, Claudia

    2013-10-01

    The energy system in the Region of Aysén, Chile, is characterized by a strong dependence on fossil fuels, which account for up to 51% of the installed capacity. Although the implementation of waste-to-energy concepts in municipal waste management systems could support the establishment of a more fossil-independent energy system for the region, previous studies have concluded that energy recovery systems are not suitable from an economic perspective in Chile. Therefore, this work intends to evaluate these technical options from an environmental perspective, using life cycle assessment as a tool for a comparative analysis, considering Coyhaique city as a case study. Three technical alternatives were evaluated: (i) landfill gas recovery and flaring without energy recovery; (ii) landfill gas recovery and energy use; and (iii) the implementation of an anaerobic digestion system for the organic waste fraction coupled with energy recovery from the biogas produced. Mass and energy balances of the three analyzed alternatives have been modeled. The comparative LCA considered global warming potential, abiotic depletion and ozone layer depletion as impact categories, as well as required raw energy and produced energy as comparative regional-specific indicators. According to the results, the use of the recovered landfill gas as an energy source can be identified as the most environmentally appropriate solution for Coyhaique, especially when taking into consideration the global impact categories.

  3. Permanent Disposal of Nuclear Waste in Salt

    NASA Astrophysics Data System (ADS)

    Hansen, F. D.

    2016-12-01

    Salt formations hold promise for eternal removal of nuclear waste from our biosphere. Germany and the United States have ample salt formations for this purpose, ranging from flat-bedded formations to geologically mature dome structures. Both nations are revisiting nuclear waste disposal options, accompanied by extensive collaboration on applied salt repository research, design, and operation. Salt formations provide isolation while geotechnical barriers reestablish impermeability after waste is placed in the geology. Between excavation and closure, physical, mechanical, thermal, chemical, and hydrological processes ensue. Salt response over a range of stress and temperature has been characterized for decades. Research practices employ refined test techniques and controls, which improve parameter assessment for features of the constitutive models. Extraordinary computational capabilities require exacting understanding of laboratory measurements and objective interpretation of modeling results. A repository for heat-generative nuclear waste provides an engineering challenge beyond common experience. Long-term evolution of the underground setting is precluded from direct observation or measurement. Therefore, analogues and modeling predictions are necessary to establish enduring safety functions. A strong case for granular salt reconsolidation and a focused research agenda support salt repository concepts that include safety-by-design. Sandia National Laboratories is a multi-program laboratory managed and operated by Sandia Corporation, a wholly owned subsidiary of Lockheed Martin Corporation, for the U.S. Department of Energy's National Nuclear Security Administration under contract DE-AC04-94AL85000. Author: F. D. Hansen, Sandia National Laboratories

  4. 40 CFR 256.26 - Requirement for schedules leading to compliance with the prohibition of open dumping.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES GUIDELINES FOR DEVELOPMENT AND IMPLEMENTATION OF STATE SOLID WASTE MANAGEMENT PLANS Solid Waste Disposal Programs § 256.26 Requirement for schedules leading to...

  5. 40 CFR 256.26 - Requirement for schedules leading to compliance with the prohibition of open dumping.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES GUIDELINES FOR DEVELOPMENT AND IMPLEMENTATION OF STATE SOLID WASTE MANAGEMENT PLANS Solid Waste Disposal Programs § 256.26 Requirement for schedules leading to...

  6. DOE's Notification of Planned Change to the EPA 40 CFR Part 194 Certification of the Waste Isolation Pilot Plant: Remote-Handled Transuranic Waste Characterization Plan

    EPA Pesticide Factsheets

    The U.S. Department of Energy's Carlsbad Field Office (DOE/CBFO) provided the U.S. Environmental Protection Agency (EPA) this Notification of Planned Change to accept remote-handled (RH) transuranic (TRU) waste at the Waste Isolation Pilot Plant (WIPP).

  7. 40 CFR 267.202 - What special requirements must I meet for ignitable or reactive wastes?

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... material no longer meets the definition of ignitable or reactive waste under § 261.21 or § 261.23 of this... requirements for the maintenance of protective distances between the waste management area and any public ways... for ignitable or reactive wastes? 267.202 Section 267.202 Protection of Environment ENVIRONMENTAL...

  8. 40 CFR 261.5 - Special requirements for hazardous waste generated by conditionally exempt small quantity...

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... batteries managed under the requirements of 40 CFR part 266, subpart G; or (6) Is universal waste managed... waste prior to beneficial use or reuse, or legitimate recycling or reclamation; or (vii) For universal... waste prior to beneficial use or reuse, or legitimate recycling or reclamation; or (vii) For universal...

  9. 40 CFR 261.5 - Special requirements for hazardous waste generated by conditionally exempt small quantity...

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... batteries managed under the requirements of 40 CFR part 266, subpart G; or (6) Is universal waste managed... waste prior to beneficial use or reuse, or legitimate recycling or reclamation; or (vii) For universal... waste prior to beneficial use or reuse, or legitimate recycling or reclamation; or (vii) For universal...

  10. [Hygienic requirements for transportation of industrial waste and consumption residues].

    PubMed

    Metel'skiĭ, S V; Sin'kova, N V

    2009-01-01

    All wishing legal persons and individual entrepreneurs are presently engaged in garbage disposal Sanitary-and-epidemiological examination of activities in transportation of waste is complicated by that the existing sanitary regulations lack no requirements for storage, repair, washing, sanitization of waste-carrying transport, particularly epidemiologically dangerous (domestic, food, and biological waste, animal excreta, cut hair, etc.).

  11. Thirteenth annual U.S. DOE low-level radioactive waste management conference: Proceedings

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    NONE

    1991-12-31

    The 40 papers in this document comprise the proceedings of the Department of Energy`s Thirteenth Annual Low-Level Radioactive Waste Management Conference that was held in Atlanta, Georgia, on November 19--21, 1991. General subjects addressed during the conference included: disposal facility design; greater-than-class C low-level waste; public acceptance considerations; waste certification; site characterization; performance assessment; licensing and documentation; emerging low-level waste technologies; waste minimization; mixed waste; tracking and transportation; storage; and regulatory changes. Papers have been processed separately for inclusion on the data base.

  12. 1QCY17 Saltstone waste characterization analysis

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Johnson, F. C.

    2017-07-25

    In the first quarter of calendar year 2017, a salt solution sample was collected from Tank 50 on January 16, 2017 in order to meet South Carolina (SC) Regulation 61-107.19 Part I C, “Solid Waste Management: Solid Waste Landfills and Structural Fill – General Requirements” and the Saltstone Disposal Facility Class 3 Landfill Permit. The Savannah River National Laboratory (SRNL) was requested to prepare and ship saltstone samples to a United States Environmental Protection Agency (EPA) certified laboratory to perform the Toxicity Characteristic Leaching Procedure (TCLP) and subsequent characterization.

  13. Roles of Historical Photography in Waste Site Characterization, Closure, and Remediation

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Mackey, H.

    1998-07-01

    Over 40,000 frames of vertical historical photography from 1938 to 1996 and over 10,000 frames of oblique photography from 1981 to 1991 of the 777-square kilometer Savannah River Site in south central South Carolina were reviewed, cataloged, and referenced utilizing ARCView and associated ArcInfo tools. This allows environmental reviews of over 400 potential waste units on the SRS to be conducted in a rapid fashion to support preparation of work plans, characterization, risk assessments, and closure of the waste units in a more cost effective manner.

  14. Waste reduction plan for The Oak Ridge National Laboratory

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Schultz, R.M.

    1990-04-01

    The Oak Ridge National Laboratory (ORNL) is a multipurpose Research and Development (R D) facility. These R D activities generate numerous small waste streams. Waste minimization is defined as any action that minimizes the volume or toxicity of waste by avoiding its generation or recycling. This is accomplished by material substitution, changes to processes, or recycling wastes for reuse. Waste reduction is defined as waste minimization plus treatment which results in volume or toxicity reduction. The ORNL Waste Reduction Program will include both waste minimization and waste reduction efforts. Federal regulations, DOE policies and guidelines, increased costs and liabilities associatedmore » with the management of wastes, limited disposal options and facility capacities, and public consciousness have been motivating factors for implementing comprehensive waste reduction programs. DOE Order 5820.2A, Section 3.c.2.4 requires DOE facilities to establish an auditable waste reduction program for all LLW generators. In addition, it further states that any new facilities, or changes to existing facilities, incorporate waste minimization into design considerations. A more recent DOE Order, 3400.1, Section 4.b, requires the preparation of a waste reduction program plan which must be reviewed annually and updated every three years. Implementation of a waste minimization program for hazardous and radioactive mixed wastes is sited in DOE Order 5400.3, Section 7.d.5. This document has been prepared to address these requirements. 6 refs., 1 fig., 2 tabs.« less

  15. 76 FR 4823 - Hazardous Waste Management System; Identifying and Listing Hazardous Waste Exclusion

    Federal Register 2010, 2011, 2012, 2013, 2014

    2011-01-27

    ... Waste Management System; Identifying and Listing Hazardous Waste Exclusion AGENCY: Environmental... hazardous wastes. The Agency has decided to grant the petition based on an evaluation of waste-specific... excludes the petitioned waste from the requirements of hazardous waste regulations under the Resource...

  16. Using the Triad Approach to Improve the Cost-effectiveness of Hazardous Waste Site Cleanups

    EPA Pesticide Factsheets

    U.S. EPA's Office of Solid Waste and Emergency Response is promoting more effective strategies for characterizing, monitoring, and cleaning up hazardous waste sites. In particular, a paradigm based on using an integrated triad of systematic planning...

  17. 40 CFR 60.1930 - What are the recordkeeping and reporting requirements for air curtain incinerators that burn 100...

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... reporting requirements for air curtain incinerators that burn 100 percent yard waste? 60.1930 Section 60... Incinerators That Burn 100 Percent Yard Waste § 60.1930 What are the recordkeeping and reporting requirements for air curtain incinerators that burn 100 percent yard waste? (a) Provide a notice of construction...

  18. 40 CFR 62.15385 - What are the recordkeeping and reporting requirements for air curtain incinerators that burn 100...

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... reporting requirements for air curtain incinerators that burn 100 percent yard waste? 62.15385 Section 62... Incinerators That Burn 100 Percent Yard Waste § 62.15385 What are the recordkeeping and reporting requirements for air curtain incinerators that burn 100 percent yard waste? (a) Provide a notice of construction...

  19. 40 CFR 60.1930 - What are the recordkeeping and reporting requirements for air curtain incinerators that burn 100...

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... reporting requirements for air curtain incinerators that burn 100 percent yard waste? 60.1930 Section 60... Incinerators That Burn 100 Percent Yard Waste § 60.1930 What are the recordkeeping and reporting requirements for air curtain incinerators that burn 100 percent yard waste? (a) Provide a notice of construction...

  20. 40 CFR 62.15385 - What are the recordkeeping and reporting requirements for air curtain incinerators that burn 100...

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... reporting requirements for air curtain incinerators that burn 100 percent yard waste? 62.15385 Section 62... Incinerators That Burn 100 Percent Yard Waste § 62.15385 What are the recordkeeping and reporting requirements for air curtain incinerators that burn 100 percent yard waste? (a) Provide a notice of construction...

  1. 40 CFR 62.15385 - What are the recordkeeping and reporting requirements for air curtain incinerators that burn 100...

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... reporting requirements for air curtain incinerators that burn 100 percent yard waste? 62.15385 Section 62... Incinerators That Burn 100 Percent Yard Waste § 62.15385 What are the recordkeeping and reporting requirements for air curtain incinerators that burn 100 percent yard waste? (a) Provide a notice of construction...

  2. 40 CFR 62.15385 - What are the recordkeeping and reporting requirements for air curtain incinerators that burn 100...

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... reporting requirements for air curtain incinerators that burn 100 percent yard waste? 62.15385 Section 62... Incinerators That Burn 100 Percent Yard Waste § 62.15385 What are the recordkeeping and reporting requirements for air curtain incinerators that burn 100 percent yard waste? (a) Provide a notice of construction...

  3. 40 CFR 62.15385 - What are the recordkeeping and reporting requirements for air curtain incinerators that burn 100...

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... reporting requirements for air curtain incinerators that burn 100 percent yard waste? 62.15385 Section 62... Incinerators That Burn 100 Percent Yard Waste § 62.15385 What are the recordkeeping and reporting requirements for air curtain incinerators that burn 100 percent yard waste? (a) Provide a notice of construction...

  4. 40 CFR 60.1930 - What are the recordkeeping and reporting requirements for air curtain incinerators that burn 100...

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... reporting requirements for air curtain incinerators that burn 100 percent yard waste? 60.1930 Section 60... Incinerators That Burn 100 Percent Yard Waste § 60.1930 What are the recordkeeping and reporting requirements for air curtain incinerators that burn 100 percent yard waste? (a) Provide a notice of construction...

  5. 40 CFR 60.1930 - What are the recordkeeping and reporting requirements for air curtain incinerators that burn 100...

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... reporting requirements for air curtain incinerators that burn 100 percent yard waste? 60.1930 Section 60... Incinerators That Burn 100 Percent Yard Waste § 60.1930 What are the recordkeeping and reporting requirements for air curtain incinerators that burn 100 percent yard waste? (a) Provide a notice of construction...

  6. 40 CFR 60.1930 - What are the recordkeeping and reporting requirements for air curtain incinerators that burn 100...

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... reporting requirements for air curtain incinerators that burn 100 percent yard waste? 60.1930 Section 60... Incinerators That Burn 100 Percent Yard Waste § 60.1930 What are the recordkeeping and reporting requirements for air curtain incinerators that burn 100 percent yard waste? (a) Provide a notice of construction...

  7. 40 CFR 271.4 - Consistency.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES (CONTINUED) REQUIREMENTS FOR AUTHORIZATION OF STATE HAZARDOUS WASTE PROGRAMS Requirements for Final Authorization § 271.4... hazardous waste programs which have received final authorization under this part. (a) Any aspect of the...

  8. Ground Water Monitoring Requirements for Hazardous Waste Treatment, Storage and Disposal Facilities

    EPA Pesticide Factsheets

    The groundwater monitoring requirements for hazardous waste treatment, storage and disposal facilities (TSDFs) are just one aspect of the Resource Conservation and Recovery Act (RCRA) hazardous waste management strategy for protecting human health and the

  9. 40 CFR 271.4 - Consistency.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES (CONTINUED) REQUIREMENTS FOR AUTHORIZATION OF STATE HAZARDOUS WASTE PROGRAMS Requirements for Final Authorization § 271.4... hazardous waste programs which have received final authorization under this part. (a) Any aspect of the...

  10. 40 CFR 271.4 - Consistency.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES (CONTINUED) REQUIREMENTS FOR AUTHORIZATION OF STATE HAZARDOUS WASTE PROGRAMS Requirements for Final Authorization § 271.4... hazardous waste programs which have received final authorization under this part. (a) Any aspect of the...

  11. 77 FR 12046 - Agency Information Collection Activities; Proposed Collection; Comment Request; Hazardous...

    Federal Register 2010, 2011, 2012, 2013, 2014

    2012-02-28

    ... Activities; Proposed Collection; Comment Request; Hazardous Remediation Waste Management Requirements (HWIR... approved Information Collection Request (ICR) concerning the hazardous remediation waste management... business or other for-profit. Title: Hazardous Remediation Waste Management Requirements (HWIR Contaminated...

  12. Seismic site-response characterization of high-velocity sites using advanced geophysical techniques: application to the NAGRA-Net

    NASA Astrophysics Data System (ADS)

    Poggi, V.; Burjanek, J.; Michel, C.; Fäh, D.

    2017-08-01

    The Swiss Seismological Service (SED) has recently finalised the installation of ten new seismological broadband stations in northern Switzerland. The project was led in cooperation with the National Cooperative for the Disposal of Radioactive Waste (Nagra) and Swissnuclear to monitor micro seismicity at potential locations of nuclear-waste repositories. To further improve the quality and usability of the seismic recordings, an extensive characterization of the sites surrounding the installation area was performed following a standardised investigation protocol. State-of-the-art geophysical techniques have been used, including advanced active and passive seismic methods. The results of all analyses converged to the definition of a set of best-representative 1-D velocity profiles for each site, which are the input for the computation of engineering soil proxies (traveltime averaged velocity and quarter-wavelength parameters) and numerical amplification models. Computed site response is then validated through comparison with empirical site amplification, which is currently available for any station connected to the Swiss seismic networks. With the goal of a high-sensitivity network, most of the NAGRA stations have been installed on stiff-soil sites of rather high seismic velocity. Seismic characterization of such sites has always been considered challenging, due to lack of relevant velocity contrast and the large wavelengths required to investigate the frequency range of engineering interest. We describe how ambient vibration techniques can successfully be applied in these particular conditions, providing practical recommendations for best practice in seismic site characterization of high-velocity sites.

  13. Characterization of cartridge filters from the IEA-R1 Nuclear Reactor

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    NONE

    The management of radioactive waste ensures safety to human health and the environment nowadays and for the future, without overwhelming the upcoming generations. The primary characterization of radioactive waste is one of the main steps in the management of radioactive waste. This step permits to choose the best treatment for the radioactive waste before forwarding it to its final disposal. The aim of the present work is the primary characterization of cartridge filters from the IEA-R1 nuclear reactor utilizing gamma-ray spectrometry, and the method of Monte Carlo for calibration. The IEA-R1 is located in the Nuclear and Energy Research Institutemore » (IPEN - CNEN) in the city of Sao Paulo, Brazil. Cartridge filters are used for purification of the cooling water that is pumped through the core of the pool type nuclear research reactors. Once worn out, these filters are replaced and then become radioactive waste. Determination of the radioactive inventory is of paramount importance in the management of such radioactive waste, and one of the main methods for doing so is the gamma-ray spectrometry, which can identify and quantify high energy photon emitters. The technique chosen for the characterization of radioactive waste in the present work is the gamma-ray spectrometry with High purity Germanium (HPGe) detectors. From the energy identified in the experimental spectrum, three radioisotopes were identified in the cartridge filter: {sup 108m}Ag, {sup 110m}Ag, {sup 60}Co. For the estimated activity of the filter, the calibration in efficiency was made utilizing the MCNP4C code of the Monte Carlo method. Such method was chosen because there is no standard source available in the same geometry of the cartridge filter, therefore a simulation had to be developed in order to reach a calibration equation, necessary to estimate the activity of the radioactive waste. The results presented an activity value in the order of MBq for all radioisotopes. (authors)« less

  14. Oak Ridge National Laboratory Waste Management Plan, fiscal year 1994. Revision 3

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Turner, J.W.

    1993-12-01

    US Department of Energy (DOE) Order 5820.2A was promulgated in final form on September 26, 1988. The order requires heads of field organizations to prepare and to submit updates on the waste management plans for all operations under their purview according to the format in Chap. 6, {open_quotes}Waste Management Plan Outline.{close_quotes} These plans are to be submitted by the DOE Oak Ridge Operations Office (DOE-ORO) in December of each year and distributed to the DP-12, ES&H-1, and other appropriate DOE Headquarters (DOE-HQ) organizations for review and comment. This document was prepared in response to this requirement for fiscal year (FY)more » 1994. The Oak Ridge National Laboratory (ORNL) waste management mission is reduction, collection, storage, treatment, and disposal of DOE wastes, generated primarily in pursuit of ORNL missions, in order to protect human health and safety and the environment. In carrying out this mission, waste management staff in the Waste Management and Remedial Action Division (WMRAD) will (1) guide ORNL in optimizing waste reduction and waste management capabilities and (2) conduct waste management operations in a compliant, publicly acceptable, technically sound, and cost-efficient manner. Waste management requirements for DOE radioactive wastes are detailed in DOE Order 5820.2A, and the ORNL Waste Management Program encompasses all elements of this order. The requirements of this DOE order and other appropriate DOE orders, along with applicable Tennessee Department of Environment and Conservation and US Environmental Protection Agency (EPA) rules and regulations, provide the principal source of regulatory guidance for waste management operations at ORNL. The objective of this document is compilation and consolidation of information on how the ORNL Waste Management Program is conducted, which waste management facilities are being used to manage wastes, what activities are planned for FY 1994, and how all of the activities are documented.« less

  15. Underwater characterization of control rods for waste disposal using SMOPY

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Gallozzi-Ulmann, A.; Couturier, P.; Amgarou, K.

    Storage of spent fuel assemblies in cooling ponds requires careful control of the geometry and proximity of adjacent assemblies. Measurement of the fuel burnup makes it possible to optimise the storage arrangement of assemblies taking into account the effect of the burnup on the criticality safety margins ('burnup credit'). Canberra has developed a measurement system for underwater measurement of spent fuel assemblies. This system, known as 'SMOPY', performs burnup measurements based on gamma spectroscopy (collimated CZT detector) and neutron counting (fission chamber). The SMOPY system offers a robust and waterproof detection system as well as the needed capability of performingmore » radiometric measurements in the harsh high dose - rate environments of the cooling ponds. The gamma spectroscopy functionality allows powerful characterization measurements to be performed, in addition to burnup measurement. Canberra has recently performed waste characterisation measurements at a Nuclear Power Plant. Waste activity assessment is important to control costs and risks of shipment and storage, to ensure that the activity level remains in the range allowed by the facility, and to declare activity data to authorities. This paper describes the methodology used for the SMOPY measurements and some preliminary results of a radiological characterisation of AIC control rods. After describing the features and normal operation of the SMOPY system, we describe the approach used for establishing an optimum control rod geometric scanning approach (optimum count time and speed) and the method of the gamma spectrometry measurements as well as neutron check measurements used to verify the absence of neutron sources in the waste. We discuss the results obtained including {sup 60}Co, {sup 110m}Ag and {sup 108m}Ag activity profiles (along the length of the control rods) and neutron results including Total Measurement Uncertainty evaluations. Full self-consistency checks were performed and these demonstrate the validity of the techniques. The results are described and analysed in the context of the measurement performance of the equipment. Different casks were fully characterized using a 60 mm{sup 3} CZT detector, to determine the total activities and spatial profiles. A total activity range measurement of 1x10{sup 8} - 1x10{sup 13} Bq/cm was found to be achievable. Finally, comments are made, based on our measurements, on the ability of this equipment for performing in-situ characterisation of wastes in the harsh environments typical of fuel assembly and waste storage ponds and silos. (authors)« less

  16. Generation and collection of restaurant waste: Characterization and evaluation at a case study in Italy.

    PubMed

    Tatàno, Fabio; Caramiello, Cristina; Paolini, Tonino; Tripolone, Luca

    2017-03-01

    Because restaurants (as a division of the hospitality sector) contribute to the generation of commercial and institutional waste, thus representing both a challenge and an opportunity, the objective of the present study was to deepen the knowledge of restaurant waste in terms of the qualitative and quantitative characteristics of waste generation and the performance achievable by the implementation of a separate collection scheme. In this study, the generated waste was characterized and the implemented separate collection was evaluated at a relevant case study restaurant in a coastal tourist area of Central Italy (Marche Region, Adriatic Sea side). The qualitative (compositional) characterization of the generated total restaurant waste showed considerable incidences of, in decreasing order, food (28.2%), glass (22.6%), paper/cardboard (19.1%), and plastic (17.1%). The quantitative (parametric) characterization of the generated restaurant waste determined the unit generation values of total waste and individual fractions based on the traditional employee and area parameters and the peculiar meal parameter. In particular, the obtained representative values per meal were: 0.72kgmeal -1 for total waste, and ranging, for individual fractions, from 0.20 (for food) to 0.008kgmeal -1 (for textile). Based on the critical evaluation of some of the resulting unit waste generation values, possible influences of restaurant practices, conditions, or characteristics were pointed out. In particular, food waste generation per meal can likely be limited by: promoting and using local, fresh, and quality food; standardizing and limiting daily menu items; basing food recipes on consolidated cooking knowledge and experience; and limiting plate sizes. The evaluation of the monthly variation of the monitored separate collection, ranging from an higher level of 52.7% to a lower level of 41.4%, indicated the following: a reduction in the separate collection level can be expected at times of high working pressure or the closing of a seasonal business (typical for restaurants in tourist areas); and the monthly variation of the separate collection level is inversely correlated with that of the unit generation of total waste per meal. The interception rates of the different restaurant waste fractions collected separately presented a ranking order (i.e., 96.0% for glass, 67.7% for paper/cardboard, 34.4% for food, 20.6% for metal, and 17.9% for plastic) similar to the order of efficiencies achievable at both small and large urban levels. Finally, the original concept of the customer equivalent person (P ce ) was introduced and behaviorally evaluated at the case study restaurant, providing the values of 0.42 and 0.39kgP ce -1 day -1 for the food waste generation and the landfilling of biodegradable waste by the customer equivalent person, respectively. These values were compared, respectively, with the food waste generation per person at the household level and the landfilling of biodegradable waste per inhabitant at the territorial level. Copyright © 2017 Elsevier Ltd. All rights reserved.

  17. Radiological assessment of target materials for accelerator transmutation of waste (ATW) applications

    NASA Astrophysics Data System (ADS)

    Vickers, Linda Diane

    This dissertation issues the first published document of the radiation absorbed dose rate (rad-h-1) to tissue from radioactive spallation products in Ta, W, Pb, Bi, and LBE target materials used in Accelerator Transmutation of Waste (ATW) applications. No previous works have provided an estimate of the absorbed dose rate (rad-h-1) from activated targets for ATW applications. The results of this dissertation are useful for planning the radiological safety assessment to personnel, and for the design, construction, maintenance, and disposition of target materials of high-energy particle accelerators for ATW applications (Charlton, 1996). In addition, this dissertation provides the characterization of target materials of high-energy particle accelerators for the parameters of: (1) spallation neutron yield (neutrons/proton), (2) spallation products yield (nuclides/proton), (3) energy-dependent spallation neutron fluence distribution, (4) spallation neutron flux, (5) identification of radioactive spallation products for consideration in safety of personnel to high radiation dose rates, and (6) identification of the optimum geometrical dimensions for the target applicable to the maximum radial spallation neutron leakage from the target. Pb and Bi target materials yielded the lowest absorbed dose rates (rad-h -1) for a 10-year irradiation/50-year decay scheme, and would be the preferred target materials for consideration of the radiological safety of personnel during ATW operations. A beneficial characteristic of these target materials is that they do not produce radioactive transuranic isotopes, which have very long half-lives and require special handling and disposition requirements. Furthermore, the targets are not considered High-Level Waste (HLW) such as reactor spent fuel for disposal purposes. It is a basic ATW system requirement that the spallation target after it has been expended should be disposable as Class C low-level radioactive waste. Therefore, the disposal of Pb and Bi targets would be optimally beneficial to the economy and environment. Future studies should relate the target performance to other system parameters, specifically solid and liquid blanket systems that contain the radioactive waste to be transmuted. The methodology of this dissertation may be applied to any target material of a high-energy particle accelerator.

  18. HAZWOPER work plan and site safety and health plan for the Alpha characterization project at the solid waste storage area 4 bathtubbing trench at Oak Ridge National Laboratory

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Not Available

    1994-07-01

    This work plan/site safety and health plan is for the alpha sampling project at the Solid Waste Storage Area 4 bathtubbing trench. The work will be conducted by the Oak Ridge National Laboratory (ORNL) Environmental Sciences Division and associated ORNL environmental, safety, and health support groups. This activity will fall under the scope of 29 CFR 1910.120, Hazardous Waste Operations and Emergency Response (HAZWOPER). The purpose of this document is to establish health and safety guidelines to be followed by all personnel involved in conducting work for this project. Work will be conducted in accordance with requirements as stipulated inmore » the ORNL HAZWOPER Program Manual and applicable ORNL; Martin Marietta Energy Systems, Inc.; and U.S. Department of Energy policies and procedures. The levels of protection and the procedures specified in this plan are based on the best information available from historical data and preliminary evaluations of the area. Therefore, these recommendations represent the minimum health and safety requirements to be observed by all personnel engaged in this project. Unforeseeable site conditions or changes in scope of work may warrant a reassessment of the stated protection levels and controls. All adjustments to the plan must have prior approval by the safety and health disciplines signing the original plan.« less

  19. A model of muscle atrophy based on live microscopy of muscle remodelling in Drosophila metamorphosis.

    PubMed

    Kuleesha, Yadav; Puah, Wee Choo; Wasser, Martin

    2016-02-01

    Genes controlling muscle size and survival play important roles in muscle wasting diseases. In Drosophila melanogaster metamorphosis, larval abdominal muscles undergo two developmental fates. While a doomed population is eliminated by cell death, another persistent group is remodelled and survives into adulthood. To identify and characterize genes involved in the development of remodelled muscles, we devised a workflow consisting of in vivo imaging, targeted gene perturbation and quantitative image analysis. We show that inhibition of TOR signalling and activation of autophagy promote developmental muscle atrophy in early, while TOR and yorkie activation are required for muscle growth in late pupation. We discovered changes in the localization of myonuclei during remodelling that involve anti-polar migration leading to central clustering followed by polar migration resulting in localization along the midline. We demonstrate that the Cathepsin L orthologue Cp1 is required for myonuclear clustering in mid, while autophagy contributes to central positioning of nuclei in late metamorphosis. In conclusion, studying muscle remodelling in metamorphosis can provide new insights into the cell biology of muscle wasting.

  20. A model of muscle atrophy based on live microscopy of muscle remodelling in Drosophila metamorphosis

    PubMed Central

    Kuleesha, Yadav; Puah, Wee Choo; Wasser, Martin

    2016-01-01

    Genes controlling muscle size and survival play important roles in muscle wasting diseases. In Drosophila melanogaster metamorphosis, larval abdominal muscles undergo two developmental fates. While a doomed population is eliminated by cell death, another persistent group is remodelled and survives into adulthood. To identify and characterize genes involved in the development of remodelled muscles, we devised a workflow consisting of in vivo imaging, targeted gene perturbation and quantitative image analysis. We show that inhibition of TOR signalling and activation of autophagy promote developmental muscle atrophy in early, while TOR and yorkie activation are required for muscle growth in late pupation. We discovered changes in the localization of myonuclei during remodelling that involve anti-polar migration leading to central clustering followed by polar migration resulting in localization along the midline. We demonstrate that the Cathepsin L orthologue Cp1 is required for myonuclear clustering in mid, while autophagy contributes to central positioning of nuclei in late metamorphosis. In conclusion, studying muscle remodelling in metamorphosis can provide new insights into the cell biology of muscle wasting. PMID:26998322

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