Sustainable Materials Management (SMM) WasteWise Data
EPA??s WasteWise encourages organizations and businesses to achieve sustainability in their practices and reduce select industrial wastes. WasteWise is part of EPA??s sustainable materials management efforts, which promote the use and reuse of materials more productively over their entire lifecycles. All U.S. businesses, governments and nonprofit organizations can join WasteWise as a partner, endorser or both. Current participants range from small local governments and nonprofit organizations to large multinational corporations. Partners demonstrate how they reduce waste, practice environmental stewardship and incorporate sustainable materials management into their waste-handling processes. Endorsers promote enrollment in WasteWise as part of a comprehensive approach to help their stakeholders realize the economic benefits to reducing waste. WasteWise helps organizations reduce their impact on global climate change through waste reduction. Every stage of a product's life cycle??extraction, manufacturing, distribution, use and disposal??indirectly or directly contributes to the concentration of greenhouse gases (GHGs) in the atmosphere and affects the global climate. WasteWise is part of EPA's larger SMM program (https://www.epa.gov/smm). Sustainable Materials Management (SMM) is a systemic approach to using and reusing materials more productively over their entire lifecycles. It represents a change in how our society thinks about the use of natural resources
Nasrullah, Muhammad; Vainikka, Pasi; Hannula, Janne; Hurme, Markku; Kärki, Janne
2015-02-01
This is the third and final part of the three-part article written to describe the mass, energy and material balances of the solid recovered fuel production process produced from various types of waste streams through mechanical treatment. This article focused the production of solid recovered fuel from municipal solid waste. The stream of municipal solid waste used here as an input waste material to produce solid recovered fuel is energy waste collected from households of municipality. This article presents the mass, energy and material balances of the solid recovered fuel production process. These balances are based on the proximate as well as the ultimate analysis and the composition determination of various streams of material produced in a solid recovered fuel production plant. All the process streams are sampled and treated according to CEN standard methods for solid recovered fuel. The results of the mass balance of the solid recovered fuel production process showed that 72% of the input waste material was recovered in the form of solid recovered fuel; 2.6% as ferrous metal, 0.4% as non-ferrous metal, 11% was sorted as rejects material, 12% as fine faction and 2% as heavy fraction. The energy balance of the solid recovered fuel production process showed that 86% of the total input energy content of input waste material was recovered in the form of solid recovered fuel. The remaining percentage (14%) of the input energy was split into the streams of reject material, fine fraction and heavy fraction. The material balances of this process showed that mass fraction of paper and cardboard, plastic (soft) and wood recovered in the solid recovered fuel stream was 88%, 85% and 90%, respectively, of their input mass. A high mass fraction of rubber material, plastic (PVC-plastic) and inert (stone/rock and glass particles) was found in the reject material stream. © The Author(s) 2014.
DOE Office of Scientific and Technical Information (OSTI.GOV)
NONE
This report contains information on hazardous materials at the Hanford Site. Information consists of shipment date, physical state, chemical nature, waste description, waste number, weight, and waste designation.
19 CFR 10.91 - Prototypes used exclusively for product development and testing.
Code of Federal Regulations, 2014 CFR
2014-04-01
... prototypes or any part(s) of the prototypes may be sold as scrap, waste, or for recycling, as prescribed in..., or for recycling. This includes a prototype or any part thereof that is incorporated into another product, as scrap, waste, or recycled material. If sold as scrap, waste, or for recycling, applicable duty...
19 CFR 10.91 - Prototypes used exclusively for product development and testing.
Code of Federal Regulations, 2011 CFR
2011-04-01
... prototypes or any part(s) of the prototypes may be sold as scrap, waste, or for recycling, as prescribed in..., or for recycling. This includes a prototype or any part thereof that is incorporated into another product, as scrap, waste, or recycled material. If sold as scrap, waste, or for recycling, applicable duty...
19 CFR 10.91 - Prototypes used exclusively for product development and testing.
Code of Federal Regulations, 2010 CFR
2010-04-01
... prototypes or any part(s) of the prototypes may be sold as scrap, waste, or for recycling, as prescribed in..., or for recycling. This includes a prototype or any part thereof that is incorporated into another product, as scrap, waste, or recycled material. If sold as scrap, waste, or for recycling, applicable duty...
19 CFR 10.91 - Prototypes used exclusively for product development and testing.
Code of Federal Regulations, 2012 CFR
2012-04-01
... prototypes or any part(s) of the prototypes may be sold as scrap, waste, or for recycling, as prescribed in..., or for recycling. This includes a prototype or any part thereof that is incorporated into another product, as scrap, waste, or recycled material. If sold as scrap, waste, or for recycling, applicable duty...
19 CFR 10.91 - Prototypes used exclusively for product development and testing.
Code of Federal Regulations, 2013 CFR
2013-04-01
... prototypes or any part(s) of the prototypes may be sold as scrap, waste, or for recycling, as prescribed in..., or for recycling. This includes a prototype or any part thereof that is incorporated into another product, as scrap, waste, or recycled material. If sold as scrap, waste, or for recycling, applicable duty...
Hazardous Waste Minimization Initiation Decision Report. Volume 1
1988-06-01
different treatment and disposal practices for spent caustic materials. In some cases, the material is placed in drums and sent to DRMO for disposal or to a...often available. As at some Navy facilities, waste caustic may be neutralized with spent acid at the process line with the effluent sent to the IWTP...3-111 PART II - Spent Battery Electrolyte .... 3-112 PART III- Battery Acid Sludges ........ 3-113 3.13.3 Disposal of Wastes from Battery Repair and
Scenario of solid waste reuse in Khulna city of Bangladesh
DOE Office of Scientific and Technical Information (OSTI.GOV)
Bari, Quazi H., E-mail: qhbari@yahoo.com; Mahbub Hassan, K.; Haque, R.
2012-12-15
The reuse and recycling of waste materials are now sincerely considered to be an integral part of solid waste management in many parts of the world. In this context, a vast number of options ranging from small scale decentralized to larger scale centralized plants have been adopted. This study aimed at investigating the waste reuse schemes in Khulna city located in the southern part of Bangladesh and ranked third largest city in the country. The shops for reusable material (SRM) were mostly situated around railway, waterway, and truck station markets which provided easy transportation to further locations. For the reusesmore » of waste materials and products, a chain system was found to collect reusable wastes under a total number of 310 identified SRM with 859 persons directly or indirectly involved in the scheme. This was a decentralized waste management system with self sufficient (autonomous) management. According to mass balance, about 38.52 tons d{sup -1} solid wastes were reused in Khulna city area, accounting for 7.65% of the total generated wastes. This study revealed that apparently a silent, systematic, smooth, and clean reuse chain has been established in Khulna city area under private initiatives, whose sustainability was confirmed over the years in the country without any official or formal funds. However, proper adjustment between the higher and lower chain in the materials flow path, as well as personal hygiene training for the workers, would further improve the achievements of the established reuse scheme.« less
Scenario of solid waste reuse in Khulna city of Bangladesh.
Bari, Quazi H; Mahbub Hassan, K; Haque, R
2012-12-01
The reuse and recycling of waste materials are now sincerely considered to be an integral part of solid waste management in many parts of the world. In this context, a vast number of options ranging from small scale decentralized to larger scale centralized plants have been adopted. This study aimed at investigating the waste reuse schemes in Khulna city located in the southern part of Bangladesh and ranked third largest city in the country. The shops for reusable material (SRM) were mostly situated around railway, waterway, and truck station markets which provided easy transportation to further locations. For the reuses of waste materials and products, a chain system was found to collect reusable wastes under a total number of 310 identified SRM with 859 persons directly or indirectly involved in the scheme. This was a decentralized waste management system with self sufficient (autonomous) management. According to mass balance, about 38.52 tons d(-1) solid wastes were reused in Khulna city area, accounting for 7.65% of the total generated wastes. This study revealed that apparently a silent, systematic, smooth, and clean reuse chain has been established in Khulna city area under private initiatives, whose sustainability was confirmed over the years in the country without any official or formal funds. However, proper adjustment between the higher and lower chain in the materials flow path, as well as personal hygiene training for the workers, would further improve the achievements of the established reuse scheme. Copyright © 2012 Elsevier Ltd. All rights reserved.
40 CFR Appendix IV to Part 261 - Reserved
Code of Federal Regulations, 2010 CFR
2010-07-01
... AND LISTING OF HAZARDOUS WASTE Financial Requirements for Management of Excluded Hazardous Secondary Materials Wording of the instruments. Appendix IV to Part 261 [Reserved for Radioactive Waste Test Methods] ...
Concrete and cement composites used for radioactive waste deposition.
Koťátková, Jaroslava; Zatloukal, Jan; Reiterman, Pavel; Kolář, Karel
2017-11-01
This review article presents the current state-of-knowledge of the use of cementitious materials for radioactive waste disposal. An overview of radwaste management processes with respect to the classification of the waste type is given. The application of cementitious materials for waste disposal is divided into two main lines: i) as a matrix for direct immobilization of treated waste form; and ii) as an engineered barrier of secondary protection in the form of concrete or grout. In the first part the immobilization mechanisms of the waste by cement hydration products is briefly described and an up-to date knowledge about the performance of different cementitious materials is given, including both traditional cements and alternative binder systems. The advantages, disadvantages as well as gaps in the base of information in relation to individual materials are stated. The following part of the article is aimed at description of multi-barrier systems for intermediate level waste repositories. It provides examples of proposed concepts by countries with advanced waste management programmes. In the paper summary, the good knowledge of the material durability due to its vast experience from civil engineering is highlighted however with the urge for specific approach during design and construction of a repository in terms of stringent safety requirements. Copyright © 2017 Elsevier Ltd. All rights reserved.
Lifecycle Management of Hazardous Materials/ Hazardous Waste. Revision 1.
1997-02-01
1 WHAT YOU NEED TO KNOW ABOUT HAZARDOUS MATERIALS (HM) ....................... 1 PURCHASING HAZARDOUS MATERIALS...20 Figures 1 . Acquisition Flowchart .................................. 12 2. NRaD Hazardous Material Pre-Purchase Checklist ........ 13 3. NRaD...Hazardous Waste Profile Sheet (Part 111) .................. 18 Tables 1 . Class 1 Ozone Depleting Substances .................... 11 i INTRODUCTION This
40 CFR 63.4493 - What work practice standards must I meet?
Code of Federal Regulations, 2010 CFR
2010-07-01
... National Emission Standards for Hazardous Air Pollutants for Surface Coating of Plastic Parts and Products... materials used in, and waste materials generated by the controlled coating operation(s) for which you use..., thinners and/or other additives, cleaning materials, and waste materials must be stored in closed...
Testing of candidate waste-package backfill and canister materials for basalt
NASA Astrophysics Data System (ADS)
Wood, M. I.; Anderson, W. J.; Aden, G. D.
1982-09-01
The Basalt Waste Isolation Project (BWIP) is developing a multiple-barrier waste package to contain high-level nuclear waste as part of an overall system (e.g., waste package, repository sealing system, and host rock) designed to isolate the waste in a repository located in basalt beneath the Hanford Site, Richland, Washington. The three basic components of the waste package are the waste form, the canister, and the backfill. An extensive testing program is under way to determine the chemical, physical, and mechanical properties of potential canister and backfill materials. The data derived from this testing program will be used to recommend those materials that most adequately perform the functions assigned to the canister and backfill.
40 CFR Appendix V to Part 261 - Reserved
Code of Federal Regulations, 2011 CFR
2011-07-01
... 40 Protection of Environment 26 2011-07-01 2011-07-01 false Reserved V Appendix V to Part 261 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES (CONTINUED) IDENTIFICATION... Materials Wording of the instruments. Appendix V to Part 261 [Reserved for Infectious Waste Treatment...
40 CFR Appendix V to Part 261 - Reserved
Code of Federal Regulations, 2010 CFR
2010-07-01
... 40 Protection of Environment 25 2010-07-01 2010-07-01 false Reserved V Appendix V to Part 261 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES (CONTINUED) IDENTIFICATION... Materials Wording of the instruments. Appendix V to Part 261 [Reserved for Infectious Waste Treatment...
40 CFR Appendix V to Part 261 - Reserved
Code of Federal Regulations, 2012 CFR
2012-07-01
... 40 Protection of Environment 27 2012-07-01 2012-07-01 false Reserved V Appendix V to Part 261 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES (CONTINUED) IDENTIFICATION... Materials Wording of the instruments. Appendix V to Part 261 [Reserved for Infectious Waste Treatment...
40 CFR Appendix V to Part 261 - Reserved
Code of Federal Regulations, 2013 CFR
2013-07-01
... 40 Protection of Environment 27 2013-07-01 2013-07-01 false Reserved V Appendix V to Part 261 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES (CONTINUED) IDENTIFICATION... Materials Wording of the instruments. Appendix V to Part 261 [Reserved for Infectious Waste Treatment...
40 CFR Appendix V to Part 261 - Reserved
Code of Federal Regulations, 2014 CFR
2014-07-01
... 40 Protection of Environment 26 2014-07-01 2014-07-01 false Reserved V Appendix V to Part 261 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES (CONTINUED) IDENTIFICATION... Materials Wording of the instruments. Appendix V to Part 261 [Reserved for Infectious Waste Treatment...
Federal Register 2010, 2011, 2012, 2013, 2014
2011-08-30
... stakeholder input regarding the efficacy and scope of the MSW Characterization Report called ``Municipal Solid Waste in the United States'' as part of a broader discussion about sustainable materials management... efficacy and scope of the MSW Characterization Report called ``Municipal Solid Waste in the United States...
Radioactive waste material melter apparatus
Newman, D.F.; Ross, W.A.
1990-04-24
An apparatus for preparing metallic radioactive waste material for storage is disclosed. The radioactive waste material is placed in a radiation shielded enclosure. The waste material is then melted with a plasma torch and cast into a plurality of successive horizontal layers in a mold to form a radioactive ingot in the shape of a spent nuclear fuel rod storage canister. The apparatus comprises a radiation shielded enclosure having an opening adapted for receiving a conventional transfer cask within which radioactive waste material is transferred to the apparatus. A plasma torch is mounted within the enclosure. A mold is also received within the enclosure for receiving the melted waste material and cooling it to form an ingot. The enclosure is preferably constructed in at least two parts to enable easy transport of the apparatus from one nuclear site to another. 8 figs.
Radioactive waste material melter apparatus
Newman, Darrell F.; Ross, Wayne A.
1990-01-01
An apparatus for preparing metallic radioactive waste material for storage is disclosed. The radioactive waste material is placed in a radiation shielded enclosure. The waste material is then melted with a plasma torch and cast into a plurality of successive horizontal layers in a mold to form a radioactive ingot in the shape of a spent nuclear fuel rod storage canister. The apparatus comprises a radiation shielded enclosure having an opening adapted for receiving a conventional transfer cask within which radioactive waste material is transferred to the apparatus. A plasma torch is mounted within the enclosure. A mold is also received within the enclosure for receiving the melted waste material and cooling it to form an ingot. The enclosure is preferably constructed in at least two parts to enable easy transport of the apparatus from one nuclear site to another.
CHARACTERIZATION AND PH/EH-BASED LEACHING TESTS OF MINING WASTES CONTAINING MERCURY
This study was undertaken as a part of developing treatment alternatives for waste materials, primarily waste rock and roaster tailings, from sites contaminated with mercury (Hg) mining wastes. Leaching profiles of waste rock over a range of different pH and oxidation-reduction (...
CHARACTERIZATION AND PH/EH-BASED LEACHING TESTS OF MINING WASTES CONTAINING MERCURY
This study was undertaken as a part of developing treatment alternatives for waste materials, primarily waste rock and roaster tailings, from sites contaminated with Mercury (Hg) mining wastes. Leaching profiles of waste rock over a range of different pH and oxidation-reduction ...
IMPACT OF LEAD ACID BATTERIES AND CADMIUM STABILIZERS ON INCINERATOR EMISSIONS
The Waste Analysis Sampling, Testing and Evaluation (WASTE) Program is a multi-year, multi-disciplinary program designed to elicit the source and fate of environmentally significant trace materials as a solid waste progresses through management processes. s part of the WASTE Prog...
Coupling plant growth and waste recycling systems in a controlled life support system (CELSS)
NASA Technical Reports Server (NTRS)
Garland, Jay L.
1992-01-01
The development of bioregenerative systems as part of the Controlled Ecological Life Support System (CELSS) program depends, in large part, on the ability to recycle inorganic nutrients, contained in waste material, into plant growth systems. One significant waste (resource) stream is inedible plant material. This research compared wheat growth in hydroponic solutions based on inorganic salts (modified Hoagland's) with solutions based on the soluble fraction of inedible wheat biomass (leachate). Recycled nutrients in leachate solutions provided the majority of mineral nutrients for plant growth, although additions of inorganic nutrients to leachate solutions were necessary. Results indicate that plant growth and waste recyling systems can be effectively coupled within CELSS based on equivalent wheat yield in leachate and Hoagland solutions, and the rapid mineralization of waste organic material in the hydroponic systems. Selective enrichment for microbial communities able to mineralize organic material within the leachate was necessary to prevent accumulation of dissolved organic matter in leachate-based solutions. Extensive analysis of microbial abundance, growth, and activity in the hydroponic systems indicated that addition of soluble organic material from plants does not cause excessive microbial growth or 'biofouling', and helped define the microbially-mediated flux of carbon in hydroponic solutions.
Characterization of radioactive wastes with respect to harmful materials
DOE Office of Scientific and Technical Information (OSTI.GOV)
Kugel, Karin; Steyer, Stefan; Brennecke, Peter
In addendum 4 to the license of the German KONRAD repository, which considers mainly radiological aspects, a water law permit was issued in order to prevent the pollution of the near-surface groundwater. The water law permit stipulates limitations for 10 radionuclides and 2 groups of radionuclides as well as mass limitations for 94 substances and materials relevant for water protection issues. Two collateral clauses, i.e. additional requirements imposed by the licensing authority, include demands on the monitoring, registering and balancing of non-radioactive harmful substances and materials /1/. In order to fulfill the requirements of the water law permit the Germanmore » Federal Office for Radiation Protection (BfS) being the operator of the KONRAD repository has developed a concept, which ensures the compliance with all requirements of the water law permit and which provides standardized easy manageable guidance for the waste producers to describe their wastes. On 15 March 2011 the competent water authority, the 'Niedersaechsischer Landesbetrieb fuer Wasserwirtschaft, Kuesten- und Naturschutz' (NLWKN) issued the approval for this concept. Being the most essential part of this concept the procedural method and the developed description of nonradioactive waste package constituents by use of standardized lists of materials and containers is addressed and presented in this paper. The waste producer has to describe his waste package in a standardized way on the base of the lists of materials and containers. For each material in the list a comprehensive description is given comprising the composition, scope of application, quality control measures, thresholds and other data. Each entry in the list has to be approved by NLWKN. The scope of the lists is defined by the waste producers' needs. Using some particular materials as examples, the approval procedure for including materials in the list is described. The procedure of describing the material composition has to be considered in the KONRAD waste acceptance requirements. The respective part of these requirements will be introduced. In order to clarify the procedure of describing waste packages by use of the standardized lists of materials and containers some examples of typical waste package descriptions will be presented. (authors)« less
Sustainable Materials Management Challenge Data
Sustainable Materials Management (SMM) is a systemic approach to using and reusing materials more productively over their entire lifecycles. It represents a change in how our society thinks about the use of natural resources and environmental protection. By looking at a product's entire lifecycle we can find new opportunities to reduce environmental impacts, conserve resources, and reduce costs. There are multiple challenge programs available as part of the SMM program, including the Food Recovery Challenge, the Electronics Challenge, the Federal Green Challenge, and the WasteWise program. As part of EPA's Food Recovery Challenge, organizations pledge to improve their sustainable food management practices and report their results. The SMM Electronics Challenge encourages electronics manufacturers, brand owners and retailers to strive to send 100 percent of the used electronics they collect from the public, businesses and within their own organizations to third-party certified electronics refurbishers and recyclers. The Federal Green Challenge, a national effort under the EPA??s Sustainable Materials Management Program, challenges EPA and other federal agencies throughout the country to lead by example in reducing the federal government's environmental impact. EPA??s WasteWise encourages organizations and businesses to achieve sustainability in their practices and reduce select industrial wastes. WasteWise is part of EPA??s sustaina
Code of Federal Regulations, 2011 CFR
2011-07-01
... control devices, friable asbestos waste material, and bags or other similar packaging contaminated with... in the Act and in subpart A of this part. Active waste disposal site means any disposal site other... release of particulates. If visible emissions are observed coming from asbestos-containing material, then...
40 CFR 761.61 - PCB remediation waste.
Code of Federal Regulations, 2011 CFR
2011-07-01
.... Subpart N of this part provides a method for collecting new site characterization data or for assessing... left after cleanup is completed. (i) Bulk PCB remediation waste. Bulk PCB remediation waste includes... similar material of minimum thickness spread over the area where remediation waste was removed or left in...
This study was undertaken as a part of developing treatment alternatives for waste materials, primarily waste rock and roaster tailings, from sites contaminated with mercury (Hg) mining wastes. Leaching profiles of waste rock over a range of different pH and oxidation-reduction (...
40 CFR Appendix I to Part 261 - Representative Sampling Methods
Code of Federal Regulations, 2010 CFR
2010-07-01
... 40 Protection of Environment 25 2010-07-01 2010-07-01 false Representative Sampling Methods I...—Representative Sampling Methods The methods and equipment used for sampling waste materials will vary with the form and consistency of the waste materials to be sampled. Samples collected using the sampling...
40 CFR Appendix I to Part 261 - Representative Sampling Methods
Code of Federal Regulations, 2011 CFR
2011-07-01
... 40 Protection of Environment 26 2011-07-01 2011-07-01 false Representative Sampling Methods I...—Representative Sampling Methods The methods and equipment used for sampling waste materials will vary with the form and consistency of the waste materials to be sampled. Samples collected using the sampling...
40 CFR Appendix I to Part 261 - Representative Sampling Methods
Code of Federal Regulations, 2013 CFR
2013-07-01
... 40 Protection of Environment 27 2013-07-01 2013-07-01 false Representative Sampling Methods I Appendix I to Part 261 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES...—Representative Sampling Methods The methods and equipment used for sampling waste materials will vary with the...
Sustainable Materials Management (SMM) Food Recovery Challenge (FRC) Data
As part of EPA's Food Recovery Challenge (FRC), organizations pledge to improve their sustainable food management practices and report their results. The FRC is part of EPA's Sustainable Materials Management Program (SMM). SMM seeks to reduce the environmental impact of materials through their entire life cycle. This includes how they are extracted, manufactured, distributed, used, reused, recycled, and disposed. Organizations are encouraged to follow the Food Recovery Hierarchy (https://www.epa.gov/sustainable-management-food/food-recovery-hierarchy) to prioritize their actions to prevent and divert wasted food. Each tier of the Food Recovery Hierarchy focuses on different management strategies for your wasted food. The program started in 2011 and the first data were made available in 2012. The FRC is part of EPA's larger SMM program (https://www.epa.gov/smm). Sustainable Materials Management (SMM) is a systemic approach to using and reusing materials more productively over their entire lifecycles. It represents a change in how our society thinks about the use of natural resources and environmental protection. By looking at a product's entire lifecycle we can find new opportunities to reduce environmental impacts, conserve resources, and reduce costs. There are multiple challenge programs available as part of the SMM program, including the Food Recovery Challenge, the Electronics Challenge, the Federal Green Challenge, and the WasteWise program.
The report gives results of a materials flow analysis performed for composting municipal solid waste (MSW) and specific biodegradable organic components of MSW. (NOTE: This work is part of an overall U.S. EPA project providing cost, energy, and materials flow information on diffe...
Federal Register 2010, 2011, 2012, 2013, 2014
2011-08-02
... the efficacy and scope of the MSW Characterization Report called ``Municipal Solid Waste in the United States'' as part of a broader discussion about sustainable materials management. This information will be... assessments; however questions are being raised about its scope, the data sources used, the assumptions made...
NASA Technical Reports Server (NTRS)
Wingard, C. D.
2018-01-01
The Universal Waste Management System (UWMS) is an improved Waste Collection System for astronauts living and working in low Earth orbit spacecraft. Polymeric materials used in water recovery on International Space Station are regularly exposed to phosphoric acid-treated 'pretreated' urine. Polymeric materials used in UWMS are not only exposed to pretreated urine, but also to concentrated phosphoric acid with oxidizer before dilution known as 'pure pretreat.' Samples of five different polymeric materials immersed in pure pretreat for 1 year were tested for liquid compatibility by measuring changes in storage modulus with a dynamic mechanical analyzer.
40 CFR 60.1105 - How do I submit my final materials separation plan?
Code of Federal Regulations, 2012 CFR
2012-07-01
... for Small Municipal Waste Combustion Units for Which Construction is Commenced After August 30, 1999... part of the notice of construction for the municipal waste combustion unit. Preconstruction...
Monitoring and Testing the Parts Cleaning Stations, Abrasive Blasting Cabinets, and Paint Booths
NASA Technical Reports Server (NTRS)
Jordan, Tracee M.
2004-01-01
I have the opportunity to work in the Environmental Management Office (EMO) this summer. One of the EMO's tasks is to make sure the Environmental Management System is implemented to the entire Glenn Research Center (GRC). The Environmental Management System (EMS) is a policy or plan that is oriented toward minimizing an organization's impact to the environment. Our EMS includes the reduction of solid waste regeneration and the reduction of hazardous material use, waste, and pollution. With the Waste Management Team's (WMT) help, the EMS can be implemented throughout the NASA Glenn Research Center. The WMT is responsible for the disposal and managing of waste throughout the GRC. They are also responsible for the management of all chemical waste in the facility. My responsibility is to support the waste management team by performing an inventory on parts cleaning stations, abrasive cabinets, and paint booths through out the entire facility. These booths/stations are used throughout the center and they need to be monitored and tested for hazardous waste and material. My job is to visit each of these booths/stations, take samples of the waste, and analyze the samples.
Recovery technologies for building materials
NASA Astrophysics Data System (ADS)
Karu, Veiko; Nurme, Martin; Valgma, Ingo
2015-04-01
Mining industry provides building materials for construction. Civil engineers have settled the quality parameters for construction materials. When we produce high quality building materials from carbonate rock (limestone, dolostone), then the estimated waste share is 25% to 30%, depending on crushing principles and rock quality. The challenge is to find suitable technology for waste recovery. During international mining waste related cooperation project MIN-NOVATION (www.min-novation.eu), partners mapped possibilities for waste recovery in mining industry and pointed out good examples and case studies. One example from Estonia showed that when we produce limestone aggregate, then we produce up to 30% waste material (fines with size 0-4mm). This waste material we can see as secondary raw material for building materials. Recovery technology for this fine grained material has been achieved with CDE separation plant. During the process the plant washes out minus 63 micron material from the limestone fines. This technology allows us to use 92% of all limestone reserves. By-product from 63 microns to 4 mm we can use as filler in concrete or as fine limestone aggregate for building or building materials. MIN-NOVATION project partners also established four pilot stations to study other mineral waste recovery technologies and solutions. Main aims on this research are to find the technology for recovery of mineral wastes and usage for new by-products from mineral mining waste. Before industrial production, testing period or case studies are needed. This research is part of the study of Sustainable and environmentally acceptable Oil shale mining No. 3.2.0501.11-0025 http://mi.ttu.ee/etp and the project B36 Extraction and processing of rock with selective methods - http://mi.ttu.ee/separation; http://mi.ttu.ee/miningwaste/
Wolbarst, A B; Forinash, E K; Byrum, C O; Peake, R T; Marcinowski, F; Kruger, M U
2001-02-01
In March of 1999, the Waste Isolation Pilot Plant (WIPP) in southeast New Mexico, the world's first deep geological repository for radioactive materials, began receiving defense-related transuranic waste. The WIPP was designed and constructed by the U.S. Department of Energy, but critical to its opening was certification by the U.S. Environmental Protection Agency that the repository complies with the radioactive waste disposal regulations set forth as environmental radiation protection standards (40 CFR Part 191) and compliance criteria (40 CFR Part 194). This paper provides a summary of the regulatory process, including the Environmental Protection Agency's waste containment, groundwater protection, and individual dose regulations for the WIPP; the Department of Energy's performance assessment and the other parts of its compliance certification application; and the Environmental Protection Agency's review and analysis of the compliance certification application and related documentation.
Code of Federal Regulations, 2010 CFR
2010-10-01
... hazardous substances, hazardous wastes, marine pollutants, elevated temperature materials, materials... defining criteria for hazard classes and divisions in part 173 of subchapter C of this chapter. Hazardous...
ERIC Educational Resources Information Center
Ohio State Univ., Columbus. National Center for Research in Vocational Education.
This military-developed text contains the third section of a four-part course to train environmental support specialists. Covered in the individual sections are field sanitation, classes and sources of waste, composition and characteristics of sewage, principles of sewage treatment, primary waste treatment, secondary waste treatment, tertiary…
The Role of Packaging in Solid Waste Management 1966 to 1976.
ERIC Educational Resources Information Center
Darnay, Arsen; Franklin, William E.
The goals of waste processors and packagers obviously differ: the packaging industry seeks durable container material that will be unimpaired by external factors. Until recently, no systematic analysis of the relationship between packaging and solid waste disposal had been undertaken. This three-part document defines these interactions, and the…
Modelling for environmental assessment of municipal solid waste landfills (part II: biodegradation).
Garcia de Cortázar, Amaya Lobo; Lantarón, Javier Herrero; Fernández, Oscar Montero; Monzón, Iñaki Tejero; Lamia, Maria Fantelli
2002-12-01
The biodegradation module of a simulation program for municipal solid waste landfills (MODUELO) was developed. The biodegradation module carries out the balance of organic material starting with the results of the hydrologic simulation and the waste composition. It simulates the biologic reactions of hydrolysis of solids and the gasification of the dissolved biodegradable material. The results of this module are: organic matter (COD, BOD and elemental components such as carbon, hydrogen, nitrogen, oxygen, sulfur and ash), ammonium nitrogen generated with the gas and transported by the leachates and the potential rates of methane and carbon dioxide generation. The model was calibrated by using the general tendency curves of the pollutants recorded in municipal solid waste landfills, fitting the first part of them to available landfill data. Although the results show some agreement, further work is being done to make MODUELO a useful tool for real landfill simulation.
Policies to Enable Bioenergy Deployment: Key Considerations and Good Practices
DOE Office of Scientific and Technical Information (OSTI.GOV)
Smolinksi, Sharon; Cox, Sadie
2016-05-01
Bioenergy is renewable energy generated from biological source materials, and includes electricity, transportation fuels and heating. Source materials are varied types of biomass, including food crops such as corn and sugarcane, non-edible lignocellulosic materials such as agricultural and forestry waste and dedicated crops, and municipal and livestock wastes. Key aspects of policies for bioenergy deployment are presented in this brief as part of the Clean Energy Solutions Center's Clean Energy Policy Brief Series.
Uranium-233 waste definition: Disposal options, safeguards, criticality control, and arms control
DOE Office of Scientific and Technical Information (OSTI.GOV)
Forsberg, C.W.; Storch, S.N.; Lewis, L.C.
1998-07-07
The US investigated the use of {sup 233}U for weapons, reactors, and other purposes from the 1950s into the 1970s. Based on the results of these investigations, it was decided not to use {sup 233}U on a large scale. Most of the {sup 233}U-containing materials were placed in long-term storage. At the end of the cold war, the US initiated, as part of its arms control policies, a disposition program for excess fissile materials. Other programs were accelerated for disposal of radioactive wastes placed in storage during the cold war. Last, potential safety issues were identified related to the storagemore » of some {sup 233}U-containing materials. Because of these changes, significant activities associated with {sup 233}U-containing materials are expected. This report is one of a series of reports to provide the technical bases for future decisions on how to manage this material. A basis for defining when {sup 233}U-containing materials can be managed as waste and when they must be managed as concentrated fissile materials has been developed. The requirements for storage, transport, and disposal of radioactive wastes are significantly different than those for fissile materials. Because of these differences, it is important to classify material in its appropriate category. The establishment of a definition of what is waste and what is fissile material will provide the guidance for appropriate management of these materials. Wastes are defined in this report as materials containing sufficiently small masses or low concentrations of fissile materials such that they can be managed as typical radioactive waste. Concentrated fissile materials are defined herein as materials containing sufficient fissile content such as to warrant special handling to address nuclear criticality, safeguards, and arms control concerns.« less
40 CFR Appendix Vi to Part 261 - Reserved
Code of Federal Regulations, 2010 CFR
2010-07-01
... AND LISTING OF HAZARDOUS WASTE Financial Requirements for Management of Excluded Hazardous Secondary Materials Wording of the instruments. Appendix VI to Part 261 [Reserved for Etiologic Agents] ...
Theorizing waste in abortion and fetal ovarian tissue use.
Arris, Rachel
2003-01-01
This article explores the theoretical implications of the concept of waste as it specifically relates to arguments in favour of fetal ovarian tissue use as a source of donor eggs. The author begins by discussing medico-scientific constructions of women's reproductive bodies as wasteful. The article explores the works of Drucilla Cornell on bodily borders, Julia Kristeva on abjection, and Mary Douglas on pollution to develop a nuanced understanding of the relations between waste, women's reproductivity, and abortion in North American mainstream and medico-scientific cultures. This layered reading of waste and abortion deconstructs a significant assumption of arguments in favour of fetal ovarian tissue use as ethical--that such tissue is just "waste." The author suggests that theorizing waste this way may contribute to ethical analyses of uses of other reproductive materials (that is, embryos) that are supported, in part, by an assumption that those materials would otherwise be "wasted."
Part height control of laser metal additive manufacturing process
NASA Astrophysics Data System (ADS)
Pan, Yu-Herng
Laser Metal Deposition (LMD) has been used to not only make but also repair damaged parts in a layer-by-layer fashion. Parts made in this manner may produce less waste than those made through conventional machining processes. However, a common issue of LMD involves controlling the deposition's layer thickness. Accuracy is important, and as it increases, both the time required to produce the part and the material wasted during the material removal process (e.g., milling, lathe) decrease. The deposition rate is affected by multiple parameters, such as the powder feed rate, laser input power, axis feed rate, material type, and part design, the values of each of which may change during the LMD process. Using a mathematical model to build a generic equation that predicts the deposition's layer thickness is difficult due to these complex parameters. In this thesis, we propose a simple method that utilizes a single device. This device uses a pyrometer to monitor the current build height, thereby allowing the layer thickness to be controlled during the LMD process. This method also helps the LMD system to build parts even with complex parameters and to increase material efficiency.
Enhanced Landfill Mining case study: Innovative separation techniques
NASA Astrophysics Data System (ADS)
Cuyvers, Lars; Moerenhout, Tim; Helsen, Stefan; Van de Wiele, Katrien; Behets, Tom; Umans, Luk; Wille, Eddy
2014-05-01
In 2011, a corporate vision on Enhanced Landfill Mining (ELFM)1 was approved by the OVAM Board of directors, which resulted in an operational programme over the period 2011-2015. OVAM (Public Waste Agency of Flanders) is the competent authority in charge of waste, Sustainable Materials Management (SMM) and contaminated soil management in Flanders. The introduction of the ELFM concept needs to be related with the concept of SMM and the broader shift to a circular economy. Within the concept of ELFM, landfills are no longer considered to be a final and static situation, but a dynamic part of the materials cycle. The main goal of this research programme is to develop a comprehensive policy on resource management to deal with the issue of former landfills. In order to investigate the opportunities of ELFM, the OVAM is applying a three step approach including mapping, surveying and mining of these former landfills. As a result of the mapping part over 2,000 landfill sites, that will need to be dealt with, were revealed. The valorisation potential of ELFM could be assigned to different goals, according to the R³P-concept : Recycling of Materials, Recovery of Energy, Reclamation of Land and Protection of drinking water supply. . On behalf of the OVAM, ECOREM was assigned to follow-up a pilot case executed on a former landfill, located in Zuienkerke, Flanders. Within this case study some technical tests were carried out on the excavated waste material to investigate the possibilities for a waste to resource conversion. The performance of both on site and off site techniques were evaluated. These testings also contribute to the mapping part of OVAM's research programme on ELFM and reveal more information on the composition of former landfills dating from different era's. In order to recover as many materials as possible, five contractors were assigned to perform separation tests on the bulk material from the Zuienkerke landfill. All used techniques were described, resulting in a separate flowsheet for every contractor. The resulting fractions and materials were described in detail to obtain an inventory of the bulk material. Based on the characteristics from the obtained fractions, all possible valorisation pathways are listed, suggesting a Waste to Material (WtM) or a Waste to Energy (WtE) valorisation pathway. Fractions that needed further treatment were also discussed. The results of the separation tests proved to be very promising and delivered well sorted waste streams. The composition of the waste material, on the other hand, proved to be less beneficial to be economically feasible. Due to the high amount of sand and clay (up to 90wt%) in the Zuienkerke landfill the share of instant recoverable materials proved to be very limited. Due to the limited number of tests concerning the separation and valorisation of landfilled waste, the feasibility of ELFM in the short term is not fully described yet. Based on the first experiences, the main drivers to introduce the ELFM concept on these type of landfills are the necessity of urgent remediation actions and the reclamation of land. The added value of land reuse for the future might close the financial gap in a significant way, making the implementation of ELFM feasible on former landfills. 1 Jones et al.,2010: "the safe conditioning, excavation and integrated valorisation of landfilled waste streams as both materials and energy, using innovative transformation technologies and respecting the most stringent social and ecological criteria".
ERIC Educational Resources Information Center
National Archives and Records Administration, 2008
2008-01-01
The Environmental Protection Agency (EPA or the Agency) is finalizing an alternative set of generator requirements applicable to laboratories owned by eligible academic entities, as defined in this final rule. The rule provides a flexible and protective set of regulations that address the specific nature of hazardous waste generation and…
WastePD, an innovative center on materials degradation
DOE Office of Scientific and Technical Information (OSTI.GOV)
Frankel, Gerald S.; Vienna, John; Lian, Jie
The US Department of Energy recently awarded funds to create the Center for Performance and Design of Nuclear Waste Forms and Containers (WastePD) as part of the Energy Frontier Research Center (EFRC) program. EFRCs are multi-investigator collaborations of universities, national labs and companies that “conduct fundamental research focusing on one or more “grand challenges” and use-inspired “basic research needs” identified in major strategic planning efforts by the scientific community.” The major performance parameter of nuclear waste forms is their ability to isolate the radionuclides by withstanding degradation in a repository environment over very long periods of time. So WastePD ismore » at heart a center focused on materials degradation.« less
Abundance of (14)C in biomass fractions of wastes and solid recovered fuels.
Fellner, Johann; Rechberger, Helmut
2009-05-01
In recent years thermal utilization of mixed wastes and solid recovered fuels has become of increasing importance in European waste management. Since wastes or solid recovered fuels are generally composed of fossil and biogenic materials, only part of the CO(2) emissions is accounted for in greenhouse gas inventories or emission trading schemes. A promising approach for determining this fraction is the so-called radiocarbon method. It is based on different ratios of the carbon isotopes (14)C and (12)C in fossil and biogenic fuels. Fossil fuels have zero radiocarbon, whereas biogenic materials are enriched in (14)C and reflect the (14)CO(2) abundance of the ambient atmosphere. Due to nuclear weapons tests in the past century, the radiocarbon content in the atmosphere has not been constant, which has resulted in a varying (14)C content of biogenic matter, depending on the period of growth. In the present paper (14)C contents of different biogenic waste fractions (e.g., kitchen waste, paper, wood), as well as mixtures of different wastes (household, bulky waste, and commercial waste), and solid recovered fuels are determined. The calculated (14)C content of the materials investigated ranges between 98 and 135pMC.
Code of Federal Regulations, 2010 CFR
2010-01-01
... transferred to a Federal repository no later than 10 years following separation of fission products from the.... Disposal of high-level radioactive fission product waste material will not be permitted on any land other... of the policy stated above with respect to high-level radioactive fission product wastes generated...
Code of Federal Regulations, 2011 CFR
2011-01-01
... transferred to a Federal repository no later than 10 years following separation of fission products from the.... Disposal of high-level radioactive fission product waste material will not be permitted on any land other... of the policy stated above with respect to high-level radioactive fission product wastes generated...
Fiber reinforced concrete: An advanced technology for LL/ML radwaste conditioning and disposal
DOE Office of Scientific and Technical Information (OSTI.GOV)
Tchemitcheff, E.; Verdier, A.
Radioactive waste immobilization is an integral part of operations in nuclear facilities. The goal of immobilization is to contain radioactive materials in a waste form which can maintain its integrity over very long periods of time, thus effectively isolating the materials from the environment and hence from the public. This is true regardless of the activity of the waste, including low-, and medium-level waste (LLW, MLW). A multiple-year research effort by Cogema culminated in the development of a new process to immobilize nuclear waste in concrete containers reinforced with metal fibers. The fiber concrete containers satisfy all French safety requirementsmore » relating to waste immobilization and disposal, and have been certified by ANDRA, the national radioactive waste management agency. The fiber concrete containers have been fabricated on a production scale since July 1990 by Sogefibre, a jointly-owned subsidiary of SGN and Compagnie Generale des Eaux.« less
Nasrullah, Muhammad; Vainikka, Pasi; Hannula, Janne; Hurme, Markku; Kärki, Janne
2014-11-01
In this work, the fraction of construction and demolition waste (C&D waste) complicated and economically not feasible to sort out for recycling purposes is used to produce solid recovered fuel (SRF) through mechanical treatment (MT). The paper presents the mass, energy and material balances of this SRF production process. All the process streams (input and output) produced in MT waste sorting plant to produce SRF from C&D waste are sampled and treated according to CEN standard methods for SRF. Proximate and ultimate analysis of these streams is performed and their composition is determined. Based on this analysis and composition of process streams their mass, energy and material balances are established for SRF production process. By mass balance means the overall mass flow of input waste material stream in the various output streams and material balances mean the mass flow of components of input waste material stream (such as paper and cardboard, wood, plastic (soft), plastic (hard), textile and rubber) in the various output streams of SRF production process. The results from mass balance of SRF production process showed that of the total input C&D waste material to MT waste sorting plant, 44% was recovered in the form of SRF, 5% as ferrous metal, 1% as non-ferrous metal, and 28% was sorted out as fine fraction, 18% as reject material and 4% as heavy fraction. The energy balance of this SRF production process showed that of the total input energy content of C&D waste material to MT waste sorting plant, 74% was recovered in the form of SRF, 16% belonged to the reject material and rest 10% belonged to the streams of fine fraction and heavy fraction. From the material balances of this process, mass fractions of plastic (soft), paper and cardboard, wood and plastic (hard) recovered in the SRF stream were 84%, 82%, 72% and 68% respectively of their input masses to MT plant. A high mass fraction of plastic (PVC) and rubber material was found in the reject material stream. Streams of heavy fraction and fine fraction mainly contained non-combustible material (such as stone/rock, sand particles and gypsum material). Copyright © 2014 Elsevier Ltd. All rights reserved.
USDA-ARS?s Scientific Manuscript database
Thermogravimetric analysis (TGA) was used to investigate thermal and catalytic pyrolysis of waste plastics such as prescription bottles (polypropylene/PP), high density polyethylene, landfill liners (polyethylene/PE), packing materials (polystyrene/PS), and foams (polyurethane/PU) into crude plastic...
NASA Astrophysics Data System (ADS)
Tuzkaya, Umut R.; Eser, Arzum; Argon, Goner
2004-02-01
Today, growing amounts of waste due to fast consumption rate of products started an irreversible environmental pollution and damage. A considerable part of this waste is caused by packaging material. With the realization of this fact, various waste policies have taken important steps. Here we considered a firm, where waste Aluminum constitutes majority of raw materials for this fir0m. In order to achieve a profitable recycling process, plant layout should be well designed. In this study, we propose a two-step approach involving Analytic Hierarchy Process (AHP) and Data Envelopment Analysis (DEA) to solve facility layout design problems. A case example is considered to demonstrate the results achieved.
Sliwinski-Korell, A; Lutz, F
1998-05-01
In the last years the standards for professional handling of hazardous material as well as health and safety in the veterinary practice became considerably more stringent. This is expressed in various safety regulations, particularly the decree of hazardous material and the legislative directives concerning health and safety at work. In part 1, a definition based on the law for hazardous material was given and the potential risks were mentioned. The correct documentation regarding the protection of personal and the purchase, storage, working conditions and removal of hazardous material was explained. General rules for the handling of hazardous material were described. In part 2, partial emphasis is put on the handling of flammable liquids, disinfectants, cytostatica, pressurised gases, liquid nitrogen, narcotics, mailing of potentially infectious material and safe disposal of hazardous waste. Advice about possible unrecognized hazards and references are also given.
One project`s waste is another project`s resource
DOE Office of Scientific and Technical Information (OSTI.GOV)
Short, J.
1997-02-01
The author describes the efforts being made toward pollution prevention within the DOE complex, as a way to reduce overall project costs, in addition to decreasing the amount of waste to be handled. Pollution prevention is a concept which is trying to be ingrained into project planning. Part of the program involves the concept that ultimately the responsibility for waste comes back to the generator. Parts of the program involve efforts to reuse materials and equipment on new projects, to recycle wastes to generate offsetting revenue, and to increase awareness, accountability and incentives so as to stimulate action on thismore » plan. Summaries of examples are presented in tables.« less
NASA Astrophysics Data System (ADS)
Chen, Irvin Allen
Portland cement concrete, the most widely used manufactured material in the world, is made primarily from water, mineral aggregates, and portland cement. The production of portland cement is energy intensive, accounting for 2% of primary energy consumption and 5% of industrial energy consumption globally. Moreover, portland cement manufacturing contributes significantly to greenhouse gases and accounts for 5% of the global CO2 emissions resulting from human activity. The primary objective of this research was to explore methods of reducing the environmental impact of cement production while maintaining or improving current performance standards. Two approaches were taken, (1) incorporation of waste materials in portland cement synthesis, and (2) optimization of an alternative environmental friendly binder, calcium sulfoaluminate-belite cement. These approaches can lead to less energy consumption, less emission of CO2, and more reuse of industrial waste materials for cement manufacturing. In the portland cement part of the research, portland cement clinkers conforming to the compositional specifications in ASTM C 150 for Type I cement were successfully synthesized from reagent-grade chemicals with 0% to 40% fly ash and 0% to 60% slag incorporation (with 10% intervals), 72.5% limestone with 27.5% fly ash, and 65% limestone with 35% slag. The synthesized portland cements had similar early-age hydration behavior to commercial portland cement. However, waste materials significantly affected cement phase formation. The C3S--C2S ratio decreased with increasing amounts of waste materials incorporated. These differences could have implications on proportioning of raw materials for cement production when using waste materials. In the calcium sulfoaluminate-belite cement part of the research, three calcium sulfoaluminate-belite cement clinkers with a range of phase compositions were successfully synthesized from reagent-grade chemicals. The synthesized calcium sulfoaluminate-belite cement that contained medium C4A3 S¯ and C2S contents showed good dimensional stability, sulfate resistance, and compressive strength development and was considered the optimum phase composition for calcium sulfoaluminate-belite cement in terms of comparable performance characteristics to portland cement. Furthermore, two calcium sulfoaluminate-belite cement clinkers were successfully synthesized from natural and waste materials such as limestone, bauxite, flue gas desulfurization sludge, Class C fly ash, and fluidized bed ash proportioned to the optimum calcium sulfoaluminate-belite cement synthesized from reagent-grade chemicals. Waste materials composed 30% and 41% of the raw ingredients. The two calcium sulfoaluminate-belite cements synthesized from natural and waste materials showed good dimensional stability, sulfate resistance, and compressive strength development, comparable to commercial portland cement.
DOE Office of Scientific and Technical Information (OSTI.GOV)
Schecker, Jay A
After a prolonged absence, the word 'nuclear' has returned to the lexicon of sustainable domestic energy resources. Due in no small part to its demonstrated reliability, nuclear power is poised to playa greater role in the nation's energy future, producing clean, carbon-neutral electricity and contributing even more to our energy security. To nuclear scientists, the resurgence presents an opportunity to inject new technologies into the industry to maximize the benefits that nuclear energy can provide. 'By developing new options for waste management and exploiting new materials to make key technological advances, we can significantly impact the use of nuclear energymore » in our future energy mix,' says Chris Stanek, a materials scientist at Los Alamos National Laboratory. Stanek approaches the big technology challenges by thinking way small, all the way down to the atoms. He and his colleagues are using cutting edge atomic-scale simulations to address a difficult aspect of nuclear waste -- predicting its behavior far into the future. Their research is part of a broader, coordinated effort on the part of the Laboratory to use its considerable experimental, theoretical, and computational capabilities to explore advanced materials central to not only waste issues, but to nuclear fuels as well.« less
Process waste assessment: Petroleum jelly removal from semiconductor die using trichloroethylene
DOE Office of Scientific and Technical Information (OSTI.GOV)
Curtin, D.P.
The process analyzed involves non-production, laboratory environment use of trichloroethylene for the cleaning of semiconductor devices. The option selection centered on the replacement of the trichloroethylene with a non-hazardous material. This process waste assessment was performed as part of a pilot project.
Municipal Solid Waste Landfills and Wood Pallets - What's Happening in the United States
Philip A. Araman; Robert J. Bush; Vijay S. Reddy
1997-01-01
This article on pallet disposal and Municipal Solid Waste sites includes material presented by Dr. Bush at the recent NWPCA Recycling Meeting. This is the first in a two-part series; the second discusses pallet disposal in construction and demolition sites.
ERIC Educational Resources Information Center
Grinstead, Robert R.
1972-01-01
Solid wastes that go at low cost into municipal landfills contain valuable raw materials which technology is not equipped to handle on a large scale. Identifying the key stumbling blocks may help divert the flow of wastes to useful purposes rather than into permanent burial sites. First of a two-part article. (BL)
DOE Office of Scientific and Technical Information (OSTI.GOV)
Morcos, T.N.; Tadrous, N.A.; Borai, E.H.
2007-07-01
Increased industrialization over the last years in Egypt has resulted in an increased and uncontrolled generation of industrial hazardous waste. The current lack of management of the solid waste in Egypt has created a situation where large parts of the land (especially industrial areas) are covered by un-planned dumps of industrial wastes. Consequently, in the present work, industrial magnesite waste produced in large quantities after production process of magnesium sulfate in Zinc Misr factory, Egypt, was tried to be recycled. Firstly, this material has been characterized applying different analytical techniques such as infrared spectroscopy (IR), surface analyzer (BET), particle sizemore » distribution (PSD), elemental analysis by X-ray fluorescence (XRF) and X-ray diffraction (XRD). The magnesite material has been used as a source of producing aluminum, chromium, and magnesium oxides that has better chemical stability than conventional metal oxides. Secondly, utilization of magnesite material for removal of certain radionuclides was applied. Different factors affecting the removal capability such as pH, contacting time, metal concentration, particle size were systematically investigated. The overall objective was aimed at determining feasible and economic solution to the environmental problems related to re-use of the industrial solid waste for radioactive waste management. (authors)« less
Basic features of waste material storage in underground space in relation to geomechanics
DOE Office of Scientific and Technical Information (OSTI.GOV)
Konecny, P.
1994-12-31
It is logical to consider utilizing underground cavities for waste material disposal because, during mining, great volumes of rock materials are extracted, and underground hollow areas and communicating workings are created that can, in general, be utilized for waste disposal. Additionally, in many cases, underground waste disposal favorably supports mining process technology (for instance, application of power plant fly ash and preparation plant tailings as hardened backfill). However, it is necessary to give particular attention to the preparation, operation, and isolation of underground tip areas; errors and, in extreme cases, emergencies in underground tips are generally more difficult to dealmore » with than those in surface tips. A tip place constructed underground becomes part of the rock massif; therefore, all natural laws that rule the rock massif must be respected. Of course, such an approach requires knowledge of processes and natural regularities that will occur in rock strata where tip places have been constructed. Such knowledge is gained through familiarity with contemporary geomechanical science. The paper discusses basic geomechanical principles of underground waste disposal; geomechanical aspects of rock massif evaluation in view of waste material storage in mine workings; and plans for an experimental project for waste disposal in the Dul Ostrava underground mine.« less
DOE Office of Scientific and Technical Information (OSTI.GOV)
NSTec Environmental Programs
2010-06-17
The Area 5 Hazardous Waste Storage Unit (HWSU) was established to support testing, research, and remediation activities at the Nevada Test Site (NTS), a large-quantity generator of hazardous waste. The HWSU, located adjacent to the Area 5 Radioactive Waste Management Site (RWMS), is a prefabricated, rigid steel-framed, roofed shelter used to store hazardous nonradioactive waste generated on the NTS. No offsite generated wastes are managed at the HWSU. Waste managed at the HWSU includes the following categories: Flammables/Combustibles; Acid Corrosives; Alkali Corrosives; Oxidizers/Reactives; Toxics/Poisons; and Other Regulated Materials (ORMs). A list of the regulated waste codes accepted for storage atmore » the HWSU is provided in Section B.2. Hazardous wastes stored at the HWSU are stored in U.S. Department of Transportation (DOT) compliant containers, compatible with the stored waste. Waste transfer (between containers) is not allowed at the HWSU and containers remain closed at all times. Containers are stored on secondary containment pallets and the unit is inspected monthly. Table 1 provides the metric conversion factors used in this application. Table 2 provides a list of existing permits. Table 3 lists operational Resource Conservation and Recovery Act (RCRA) units at the NTS and their respective regulatory status.« less
Morello, Luca; Raga, Roberto; Sgarbossa, Paolo; Rosson, Egle; Cossu, Raffaello
2018-05-01
The storage capacity and the potentially residual emissions of a stabilized waste coming from a landfill simulation experiment were evaluated. The evolution in time of the potential emissions and the mobility of some selected elements or compounds were determined, comparing the results of the stabilized waste samples with the values detected in the related fresh waste samples. Analyses were conducted for the total bulk waste and also for each identified category (under-sieve, kitchen residues, green and wooden materials, plastics, cellulosic material and textiles) to highlight the contribution of the different waste fractions in the total emission potential. The waste characterization was performed through analyses on solids and on leaching test eluates; the chemical speciation of carbon, nitrogen, chlorine and sulfur together with the partitioning of heavy metals through a SCE procedure were carried out. Results showed that the under-sieve is the most environmentally relevant fraction, hosting a consistent part of mobile compounds in fresh waste (40.7% of carbon, 44.0% of nitrogen, 47.6% of chloride and 40.0% of sulfur) and the greater part of potentially residual emissions in stabilized waste (88.4% of carbon, 90.9% of nitrogen, 98.4% of chloride and 91.1% of sulfur). Landfilled Municipal Solid Waste (MSW) proved to be an effective sink, finally storing more than 55% of carbon, 53% of nitrogen, 33% of sulfur and 90% of heavy metals (HM) which were initially present in fresh waste samples. A general decrease in leachable fractions from fresh to stabilized waste was observed for each category. Tests showed that solid waste is not a good sink for chlorine, whose residual non-mobile fraction amounts to 12.3% only. Copyright © 2018 Elsevier Ltd. All rights reserved.
DOE Office of Scientific and Technical Information (OSTI.GOV)
Not Available
1991-12-31
This report (Vol. 6) for the WIPP facility contains appendices on the following information: Site characterization; general geology; ecological monitoring; and chemical compatibility of waste forms and container materials.
Code of Federal Regulations, 2013 CFR
2013-07-01
... milestone events) leading to compliance with the Act and regulations. SDWA means the Safe Drinking Water Act... hazardous waste so as to neutralize such wastes, or so as to recover energy or material resources from the... Underground Injection Control Program under part C of the Safe Drinking Water Act, including an approved...
Code of Federal Regulations, 2012 CFR
2012-07-01
... milestone events) leading to compliance with the Act and regulations. SDWA means the Safe Drinking Water Act... hazardous waste so as to neutralize such wastes, or so as to recover energy or material resources from the... Underground Injection Control Program under part C of the Safe Drinking Water Act, including an approved...
Code of Federal Regulations, 2014 CFR
2014-07-01
... milestone events) leading to compliance with the Act and regulations. SDWA means the Safe Drinking Water Act... hazardous waste so as to neutralize such wastes, or so as to recover energy or material resources from the... Underground Injection Control Program under part C of the Safe Drinking Water Act, including an approved...
The management of municipal solid waste (MSW) in many countries throughout the world has changed significantly over the past fifty years, with a shift from uncontrolled dumping or burning to complex systems that integrate multiple processes to recover materials or energy and prov...
DOE Office of Scientific and Technical Information (OSTI.GOV)
Neupauer, R.M.; Thurmond, S.M.
This report contains health and safety information relating to the chemicals that have been identified in the mixed waste streams at the Waste Treatment Facility at the Idaho National Engineering Laboratory. Information is summarized in two summary sections--one for health considerations and one for safety considerations. Detailed health and safety information is presented in material safety data sheets (MSDSs) for each chemical.
Briquette fuel production from wastewater sludge of beer industry and biodiesel production wastes
NASA Astrophysics Data System (ADS)
Nusong, P.; Puajindanetr, S.
2018-04-01
The production of industrial wastes is increasing each year. Current methods of waste disposal are severely impacting the environment. Utilization of industrial wastes as an alternative material for fuel is gaining interest due to its environmental friendliness. Thus, the objective of this research was to study the optimum condition for fuel briquettes produced from wastewater sludge of the beer industry and biodiesel production wastes. This research is divided into two parts. Part I will study the effects of carbonization of brewery wastewater sludge for high fixed carbon. Part II will study the ratio between brewery wastewater sludge and bleaching earth for its high heating value. The results show that the maximum fixed carbon of 10.01% by weight was obtained at a temperature of 350 °C for 30 minutes. The appropriate ratio of brewery wastewater sludge and bleaching earth by weight was 95:5. This condition provided the highest heating value of approximately 3548.10 kcal/kg.
Composite analysis E-area vaults and saltstone disposal facilities
DOE Office of Scientific and Technical Information (OSTI.GOV)
Cook, J.R.
1997-09-01
This report documents the Composite Analysis (CA) performed on the two active Savannah River Site (SRS) low-level radioactive waste (LLW) disposal facilities. The facilities are the Z-Area Saltstone Disposal Facility and the E-Area Vaults (EAV) Disposal Facility. The analysis calculated potential releases to the environment from all sources of residual radioactive material expected to remain in the General Separations Area (GSA). The GSA is the central part of SRS and contains all of the waste disposal facilities, chemical separations facilities and associated high-level waste storage facilities as well as numerous other sources of radioactive material. The analysis considered 114 potentialmore » sources of radioactive material containing 115 radionuclides. The results of the CA clearly indicate that continued disposal of low-level waste in the saltstone and EAV facilities, consistent with their respective radiological performance assessments, will have no adverse impact on future members of the public.« less
DOE Office of Scientific and Technical Information (OSTI.GOV)
Parker, B.
On March 31, the California Supreme Court decided the much awaited Rancho Mirage'' case (Waste Management of the Desert, Inc., and the City of Rancho Mirage v. Palm Springs Recycling Center, Inc.), and held that the California Integrated Waste Management Act of 1989 does not allow an exclusive franchise for the collection of recyclables not discarded by their owner.'' This ends a three-year slugfest between secondary materials processors in the state and municipalities and their franchised garbage haulers who also collect and process recyclables as part of their exclusive arrangement. Central to this nationally-watched litigation is a most fundamental questionmore » in waste management: at what point in time do articles in the solid waste stream become actual or potentially valuable secondary materials« less
Evaluation of final waste forms and recommendations for baseline alternatives to group and glass
DOE Office of Scientific and Technical Information (OSTI.GOV)
Bleier, A.
1997-09-01
An assessment of final waste forms was made as part of the Federal Facilities Compliance Agreement/Development, Demonstration, Testing, and Evaluation (FFCA/DDT&E) Program because supplemental waste-form technologies are needed for the hazardous, radioactive, and mixed wastes of concern to the Department of Energy and the problematic wastes on the Oak Ridge Reservation. The principal objective was to identify a primary waste-form candidate as an alternative to grout (cement) and glass. The effort principally comprised a literature search, the goal of which was to establish a knowledge base regarding four areas: (1) the waste-form technologies based on grout and glass, (2) candidatemore » alternatives, (3) the wastes that need to be immobilized, and (4) the technical and regulatory constraints on the waste-from technologies. This report serves, in part, to meet this goal. Six families of materials emerged as relevant; inorganic, organic, vitrified, devitrified, ceramic, and metallic matrices. Multiple members of each family were assessed, emphasizing the materials-oriented factors and accounting for the fact that the two most prevalent types of wastes for the FFCA/DDT&E Program are aqueous liquids and inorganic sludges and solids. Presently, no individual matrix is sufficiently developed to permit its immediate implementation as a baseline alternative. Three thermoplastic materials, sulfur-polymer cement (inorganic), bitumen (organic), and polyethylene (organic), are the most technologically developed candidates. Each warrants further study, emphasizing the engineering and economic factors, but each also has limitations that regulate it to a status of short-term alternative. The crystallinity and flexible processing of sulfur provide sulfur-polymer cement with the highest potential for short-term success via encapsulation. Long-term immobilization demands chemical stabilization, which the thermoplastic matrices do not offer. Among the properties of the remaining candidates, those of glass-ceramics (devitrified matrices) represent the best compromise for meeting the probable stricter disposal requirements in the future.« less
Consonni, S; Giugliano, M; Grosso, M
2005-01-01
This two-part paper assesses four strategies for energy recovery from Municipal Solid Waste (MSW) by dedicated Waste-To-Energy (WTE) plants. In strategy 1, the residue of Material Recovery (MR) is fed directly to a grate combustor, while in strategy 2 the grate combustor comes downstream of light mechanical treatment. In strategies 3 and 4, the MR residue is converted into Refuse Derived Fuel (RDF), in a fluidized cumbuster bed. The results of Part A, devoted to mass and energy balances, clearly show that pre-treating the MR residue in order to increase the heating value of the feedstock fed to the WTE plant has marginal effects on the energy efficiency of the WTE plant. When considering the efficiency of the whole strategy of waste management, the energy balances show that the more thorough the pre-treatment, the smaller the amount of energy recovered per unit of MR residue. Starting from the heat/mass balances illustrated in Part A, Part B examines the environmental impacts and economics of the various strategies by means of a Life Cycle Assessment (LCA). Results show that treating the MR residues ahead of the WTE plant does not provide environmental or economic benefits. RDF production worsens almost all impact indicators because it reduces net electricity production and thus the displacement of power plant emissions; it also increases costs, because the benefits of improving the quality of the material fed to the WTE plant do not compensate the cost of such improvement.
Industrial waste exchange: a mechanism for saving energy and money
DOE Office of Scientific and Technical Information (OSTI.GOV)
Gaines, L.L.
1983-01-01
Although considerable savings of both energy and money are possible through waste exchange, several major impediments limit the number of actual exchanges that take place. These impediments include the lack of economical separation technology, the small quantities of material available at each site, restrictive or uncertain regulation, and lack of knowledge on the part of potential waste users. None of these barriers is insurmountable if appropriate action is taken.
Bark, Marjorie; Bland, Michael; Grimes, Sue
2009-09-01
The use of waste materials for ecological benefit, agricultural improvement or as part of construction works are often exempt from waste management control in order to maximize the reuse of material that would otherwise be disposed of to landfill. It is important, however, to determine whether there is potential for such waste to cause environmental harm in the context of the basis for granting exemptions under the relevant framework objective to ensure that waste is recovered or disposed of without risk to water, air, soil, plants or animals. The potential for environmental harm was investigated by leaching studies on two wastes commonly found at exempt sites: bituminous road planings and waste soils. For bituminous road planings, the organic components of the waste were identified by their solubility in organic solvents but these components would have low environmental impact in terms of bioavailability. Leaching studies of the heavy metals copper, lead and zinc, into the environment, under specific conditions and particularly those modelling acid rain and landfill leachate conditions showed that, except for copper, the amounts leached fell within Waste Acceptance Criteria compliance limits for defining waste as inert waste. The fact that the amount of copper leached was greater than the Waste Acceptance Criteria level suggests that either additional testing of wastes regarded as exempt should be carried out to ensure that they are in analytical compliance or that legislation should allow for the potential benefits of reuse to supersede deviations from analytical compliance.
Industrial bioconversion of renewable resources as an alternative to conventional chemistry.
Willke, Th; Vorlop, K-D
2004-12-01
There are numerous possibilities for replacing chemical techniques with biotechnological methods based on renewable resources. The potential of biotechnology (products, technologies, metabolic pathways) is for the most part well known. Often the costs are still the problem. Biotechnological advances have the best chances for replacing some fine chemicals. While the raw material costs are less of a consideration here, the environmental benefit is huge, as chemical-technical processes often produce a wide range of undesirable/harmful by-products or waste. In the case of bulk chemicals (<1 US dollar/kg) the product price is affected mainly by raw material costs. As long as fossil raw materials are still relatively inexpensive, alternatives based on renewable resources cannot establish themselves. Residues and waste, which are available even at no cost in some cases, are an exception. The introduction of new technologies for the efficient use of such raw materials is currently being promoted. The utilisation of residual wood, plant parts, waste fat, and crude glycerol, for example, provides great potential. For industrial chemicals (2-4 US dollars/kg), process and recovery costs play a greater role. Here, innovative production technologies and product recovery techniques (e.g. on-line product separation) can increase competitiveness.
Analysing the production and treatment of solid waste using a national accounting framework.
Delahaye, Roel; Hoekstra, Rutger; Nootenboom, Leslie
2011-07-01
Our knowledge of the relationship between the economy and the environment has increased significantly over recent decades. One of the areas in which this is most apparent is the area of environmental accounting, where environmental data is presented according to national accounting principles. These accounts provide consistent, complete and detailed information for understanding environmental-economic interdependencies. One of the modules of these accounts is the waste accounts which record the origin and destination of waste materials. The first part of this paper discusses the Dutch waste accounts and their relation with economic indicators. In the second part a number of applications, which are based on the input-output model, are applied to these accounts. This section includes a novel structural decomposition analysis which quantifies the underlying driving forces of changes in total waste and landfilled waste between 1995 and 2004. The results show that the total amount of waste is mainly driven by economic growth (positive effect) and the direct export of waste (negative effect). The models also show that the construction sector has played a very important part in the reduction of waste. Furthermore, the decrease in the amount of landfilled waste, which is caused by Dutch regulations, has led to a large shift towards recycling and to a lesser degree incineration. Finally, the calculations for the 'environmental trade balance' for waste show that the waste-contents of exports exceed that of imports. This paper shows that the waste accounts have many analytical and policy-relevant applications.
Fellner, Johann; Cencic, Oliver; Zellinger, Günter; Rechberger, Helmut
2011-10-01
Thermal utilization of municipal solid waste and commercial wastes has become of increasing importance in European waste management. As waste materials are generally composed of fossil and biogenic materials, a part of the energy generated can be considered as renewable and is thus subsidized in some European countries. Analogously, CO(2) emissions of waste incinerators are only partly accounted for in greenhouse gas inventories. A novel approach for determining these fractions is the so-called balance method. In the present study, the implementation of the balance method on a waste-to-energy plant using oxygen-enriched combustion air was investigated. The findings of the 4-year application indicate on the one hand the general applicability and robustness of the method, and on the other hand the importance of reliable monitoring data. In particular, measured volume flows of the flue gas and the oxygen-enriched combustion air as well as corresponding O(2) and CO(2) contents should regularly be validated. The fraction of renewable (biogenic) energy generated throughout the investigated period amounted to between 27 and 66% for weekly averages, thereby denoting the variation in waste composition over time. The average emission factor of the plant was approximately 45 g CO(2) MJ(-1) energy input or 450 g CO(2) kg(-1) waste incinerated. The maximum error of the final result was about 16% (relative error), which was well above the error (<8%) of the balance method for plants with conventional oxygen supply.
40 CFR Appendix V to Part 264 - Examples of Potentially Incompatible Waste
Code of Federal Regulations, 2010 CFR
2010-07-01
... harmful consequences which result from mixing materials in one group with materials in another group. The...., a strong acid mixed with a strong base), or that controls substances produced (e.g., by generating... -incinerator). In the lists below, the mixing of a Group A material with a Group B material may have the...
Hot Runner Mold Design of Fan Diverter Parts
NASA Astrophysics Data System (ADS)
Juan, D. J.; Cheng, Y. L.
2017-09-01
In this study, we discuss the case of plastic parts for the production of fan steering gear shaft parts injection molding, and use POM plastic steel to produce plastic parts from traditional cold runners. Because of the parts have a hole, which need side slide. The runner produce more waste after plastic parts injection make the runner waste account for the cost is relatively high, the cost of stock preparation is relatively increased when the product quantity demanded is great. After the crushing treatment of the waste, the backfill will affect the quality, and in the crushing process, the volume generated will make the operator to withstand up to 130 dB of noise. The actual test results show that the production cycle reduce 6.25%, while the production yield increase by about 5% and material costs reduced by 2% . It can be recovered within a year, not to mention the increase of the quality and reduction the noise on the staff of the benefit is impossible to estimate.
Applications of fiber reinforced concrete containers in France and in Slovakia
DOE Office of Scientific and Technical Information (OSTI.GOV)
Verdier, A.; Delgrande, J.; Remias, V.
Radioactive waste immobilization is an integral part of operations in nuclear facilities. The goal of immobilization is to contain radioactive materials in a waste form which can maintain its integrity over very long periods of time, thus effectively isolating the materials from the environment and hence from the public. This is true regardless of the activity of the waste, including low-, and medium-level waste (LLW, MLW). A multiple-year research effort by COGEMA culminated in the development of a new process to immobilize nuclear waste in concrete containers reinforced with metal fibers. The fiber reinforced concrete containers satisfy all French safetymore » requirements relating to waste immobilization and disposal, and have been certified by ANDRA, the national radioactive waste management agency. The fiber reinforced concrete containers have been fabricated on a production scale since July 1990 by Sogefibre, a jointly-owned subsidiary of SGN and Campaign Generale des Eaux. This technology is being transferred to Slovenske Elektrarne (Slovak Power Plant) to intern the waste produced by Bohunice and Mochovce power plants in cubical fiber reinforced concrete containers.« less
324 Building spent fuel segments pieces and fragments removal summary report
DOE Office of Scientific and Technical Information (OSTI.GOV)
SMITH, C L
2003-01-09
As part of the 324 Building Deactivation Project, all Spent Nuclear Fuel (SNF) and Special Nuclear Material were removed. The removal entailed packaging the material into a GNS-12 cask and shipping it to the Central Waste Complex (CWC).
Federal Register 2010, 2011, 2012, 2013, 2014
2012-07-16
..., New York. A modernized facility is needed to streamline radioactive material handling and storage... waste shipments would be a small part of the shipments of radioactive materials made annually in the... preferred action to address the need for streamlining radioactive material handling and storage operations...
Preliminary Design of Industrial Symbiosis of Smes Using Material Flow Cost Accounting (MFCA) Method
NASA Astrophysics Data System (ADS)
Astuti, Rahayu Siwi Dwi; Astuti, Arieyanti Dwi; Hadiyanto
2018-02-01
Industrial symbiosis is a collaboration of several industries to share their necessities such material, energy, technology as well as waste management. As a part of industrial ecology, in principle, this system attempts to emulate ecosystem where waste of an organism is being used by another organism, therefore there is no waste in the nature. This system becomes an effort to optimize resources (material and energy) as well as minimize waste. Considerable, in a symbiosis incure material and energy flows among industries. Material and energy in an industry are known as cost carriers, thus flow analysis in this system can be conducted in perspective of material, energy and cost, or called as material flow cost accounting (MFCA) that is an economic and ecological appraisal approach. Previous researches shown that MFCA implementation could be used to evaluate an industry's environmental-related efficiency as well as in planning, business control and decision making. Moreover, the MFCA has been extended to assess environmental performance of SMEs Cluster or industrial symbiosis in SMEs Cluster, even to make preliminary design of an industrial symbiosis base on a major industry. This paper describes the use of MFCA to asses performance of SMEs industrial symbiosis and to improve the performance.
Methods of Predicting Solid Waste Characteristics.
ERIC Educational Resources Information Center
Boyd, Gail B.; Hawkins, Myron B.
The project summarized by this report involved a preliminary design of a model for estimating and predicting the quantity and composition of solid waste and a determination of its feasibility. The novelty of the prediction model is that it estimates and predicts on the basis of knowledge of materials and quantities before they become a part of the…
40 CFR Appendix D to Subpart E of... - Transport and Disposal of Asbestos Waste
Code of Federal Regulations, 2013 CFR
2013-07-01
... 40 Protection of Environment 32 2013-07-01 2013-07-01 false Transport and Disposal of Asbestos... (CONTINUED) TOXIC SUBSTANCES CONTROL ACT ASBESTOS Asbestos-Containing Materials in Schools Pt. 763, Subpt. E, App. D Appendix D to Subpart E of Part 763—Transport and Disposal of Asbestos Waste For the purposes...
40 CFR Appendix D to Subpart E of... - Transport and Disposal of Asbestos Waste
Code of Federal Regulations, 2010 CFR
2010-07-01
... 40 Protection of Environment 30 2010-07-01 2010-07-01 false Transport and Disposal of Asbestos... (CONTINUED) TOXIC SUBSTANCES CONTROL ACT ASBESTOS Asbestos-Containing Materials in Schools Pt. 763, Subpt. E, App. D Appendix D to Subpart E of Part 763—Transport and Disposal of Asbestos Waste For the purposes...
40 CFR Appendix D to Subpart E of... - Transport and Disposal of Asbestos Waste
Code of Federal Regulations, 2014 CFR
2014-07-01
... 40 Protection of Environment 31 2014-07-01 2014-07-01 false Transport and Disposal of Asbestos... (CONTINUED) TOXIC SUBSTANCES CONTROL ACT ASBESTOS Asbestos-Containing Materials in Schools Pt. 763, Subpt. E, App. D Appendix D to Subpart E of Part 763—Transport and Disposal of Asbestos Waste For the purposes...
40 CFR Appendix D to Subpart E of... - Transport and Disposal of Asbestos Waste
Code of Federal Regulations, 2012 CFR
2012-07-01
... 40 Protection of Environment 32 2012-07-01 2012-07-01 false Transport and Disposal of Asbestos... (CONTINUED) TOXIC SUBSTANCES CONTROL ACT ASBESTOS Asbestos-Containing Materials in Schools Pt. 763, Subpt. E, App. D Appendix D to Subpart E of Part 763—Transport and Disposal of Asbestos Waste For the purposes...
ERIC Educational Resources Information Center
Westinghouse Electric Corp., Carlsbad, NM.
This module is part of a set of management and supervisor training (MAST) materials developed by the Department of Energy for the Waste Isolation Division. Its stated purpose is to enable trainees to organize work activities efficiently and effectively. The first section of the module is an introduction that includes a terminal objective and…
78 FR 75672 - New Jersey Regulations on Transportation of Regulated Medical Waste
Federal Register 2010, 2011, 2012, 2013, 2014
2013-12-12
...(R), 69 FR at 34717. See also 49 CFR 173.134(a)(5). However, New Jersey's regulations appear to treat.... PHMSA-2011-0294 (PD-35(R)] New Jersey Regulations on Transportation of Regulated Medical Waste AGENCY... U.S.C. 5101 et seq., and the Hazardous Materials Regulations (HMR), 49 CFR parts 171-180. Modes...
40 CFR 63.4482 - What parts of my plant does this subpart cover?
Code of Federal Regulations, 2010 CFR
2010-07-01
... CATEGORIES National Emission Standards for Hazardous Air Pollutants for Surface Coating of Plastic Parts and... paragraphs (b)(1) through (4) of this section that are used for surface coating of plastic parts and products... automated equipment and containers used for conveying waste materials generated by a coating operation. (c...
NASA Astrophysics Data System (ADS)
Turuallo, Gidion; Mallisa, Harun
2018-03-01
The use of waste materials in concrete gave many advantages to prove the properties of concrete such as its workability, strength and durability; as well to support sustaianable development programs. Fly ash was a waste material produced from coal combustion. This research was conducted to find out the effect of fly ash as a part replacement of cement to produce high strength concrete. The fly ash, which was used in this research, was taken from PLTU Mpanau Palu, Central Sulawesi. The water-binder ratio used in this research was 0.3 selected from trial mixes done before. The results of this research showed that the strength of fly ash concretes were higher than concrete with PCC only. The replacement of cement with fly ash concrete could be up to 20% to produce high strength concrete.
NASA Astrophysics Data System (ADS)
Yilmaz, Deniz; Peyneau, Pierre-Emmanuel; Beaudet, Laure; Cannavo, Patrice; Sere, Geoffroy
2017-04-01
For the characterization of hydraulics soils functions, in situ infiltration experiments are commonly used. The BEST method based on the infiltration through a single ring is well suited for soils containing coarse material. Technosols built from Civil engineering waste material such as brick waste, concrete waste, track ballast and demolition rubble wastes contain large part of coarse material. In this work, different materials made of civil engineering wastes mixed with organic wastes are tested for greening applications in an urban environment using in situ lysimeters. Beerkan infiltrations experiments were performed on these technosols. Experimental data are used to estimate hydraulics properties through the BEST method. The results shows from a hydraulic point of view that studied technosols can achieve the role of urban soil for greening application. Five combinations of artefacts were tested either as "growing material" (one combination) or "structural material" (4 combinations) - as support for traffic. Structural materials consisted in 27 wt.% earth material, 60 wt.% mineral coarse material and 3 wt.% organic material. These constructed technosols were studied in situ using lysimeters under two contrasted climatic conditions in two sites in France (Angers, in northwestern France and Homécourt, in northeastern France). Constructed technosols exhibited high porosities (31-48 vol% for structural materials, 70 vol% for the growing material). The dry bulk density of the growing material is estimated to 0.66 kg/m3 and 1.59 kg/m3 for structural material. The particle size distribution analysis, involving manual sieving (> 2 mm) and complemented by a grain size analysis (< 2 mm) were used as described in the BEST method (2006) for the estimation of the shape parameter n of hydraulics functions (Van-Genuchten -Mualem, 1980). This n parameter was estimated to 2.23 for growing materials and 2.29 for structural materials. Beerkan infiltrations experiments data were inversed using the BEST method, the results exhibited high saturated hydraulic conductivities 10.7 cm/h for structural materials and 14,8 cm/h for the growing material. Beerkan infiltration experiements are well suited for assesment of hydraulic properties of technosol constructed with civil engineering wastes. According to the estimated hydraulics functions, the studied technosols can be classified between a sand and a loam soil. It shows that these materials can achieve the role of alternative to the consumption of natural arable earth for urban greening applications such as gardens, parks and trees lines.
DOE Office of Scientific and Technical Information (OSTI.GOV)
Boyle, C.A.; Baetz, B.W.
1998-12-31
Although there are a number of expert systems available which are designed to assist in resolving environmental problems, there is still a need for a system which would assist managers in determining waste management options for all types of wastes from one or more industrial plants, giving priority to sustainable use of resources, reuse and recycling. A prototype model was developed to determine the potentials for reuse and recycling of waste materials, to select the treatments needed to recycle waste materials or for treatment before disposal, and to determine potentials for co-treatment of wastes. A knowledge-based decision support system wasmore » then designed using this model. This paper describes the prototype model, the developed knowledge-based decision support system, the input and storage of data within the system and the inference engine developed for the system to determine the treatment options for the wastes. Options for sorting and selecting treatment trains are described, along with a discussion of the limitations of the approach and future developments needed for the system.« less
Evaluating the progress of the UK's Material Recycling Facilities: a mini review.
Ali, Muhammad; Courtenay, Peter
2014-12-01
Over the last 15 years, the UK has made great strides in reducing the amount of waste being sent to landfill while also increasing the amount of waste being recycled. The key drivers for this change are the European Union Landfill Directive (1999/31/EC) and the UK Landfill Tax. However, also playing their part are the growing numbers of Material Recycling Facilities (MRFs), which process recyclables. This mini review evaluates the current state of MRFs in the UK, through extensive secondary research, and detailed primary data analysis focussing on MRFs located in South-East England, UK. This study also explores technologies that aim to generate energy from waste, including Waste-to-Energy (WtE) and Refuse-derived Fuel (RDF) facilities. These facilities can have a huge appetite for waste, which can be detrimental to recycling efforts as some of the waste being sent there should be recycled. It was found that the waste sent to a typical UK MRF would recycle around 92% of materials while 6% was sent to energy recovery and the remaining 2% ended up in landfill. Therefore, the total estimated rejected or non-compliance materials from MRFs are around 8%. A key recommendation from this study is to adopt a strategy to combine MRFs with a form of energy generation, such as WtE or RDF. This integrated approach would ensure any residual waste arising from the recycling process can be used as a sustainable fuel, while also increasing the recycling rates. © The Author(s) 2014.
Mastellone, Maria Laura; Cremiato, Raffaele; Zaccariello, Lucio; Lotito, Roberta
2017-06-01
Most of the integrated systems for municipal solid waste management aim to increase the recycling of secondary materials by means of physical processes including sorting, shredding and reprocessing. Several restrictions prevent from reaching a very high material recycling efficiency: the variability of the composition of new-marketed materials used for packaging production and its shape and complexity are critical issues. The packaging goods are in fact made of different materials (aluminium, polymers, paper, etc.), possibly assembled, having different shape (flat, cylindrical, one-dimensional, etc.), density, colours, optical properties and so on. These aspects limit the effectiveness and efficiency of the sorting and reprocessing plants. The scope of this study was to evaluate the performance of a large scale Material Recovery Facility (MRF) by utilizing data collected during a long period of monitoring. The database resulted from the measured data has been organized in four sections: (1) data related to the amount and type of inlet waste; (2) amount and composition of output products and waste; (3) operating data (such as worked hours for shift, planned and unscheduled maintenance time, setting parameters of the equipment, and energy consumption for shift); (4) economic data (value of each product, disposal price for the produced waste, penalty for non-compliance of products and waste, etc.). A part of this database has been utilized to build an executive dashboard composed by a set of performance indicators suitable to measure the effectiveness and the efficiency of the MRF operations. The dashboard revealed itself as a powerful tool to support managers and engineers in their decisions in respect to the market demand or compliance regulation variation as well as in the designing of the lay-out improvements. The results indicated that the 40% of the input waste was recovered as valuable products and that a large part of these (88%) complied with the standards of the recycling companies. The evaluation of the indicators led to the decision to modify the layout to improve the interception of some polymers for which the performance indicators were poor. In particular, two additional optical sorters have to be inserted to increase the yield indicator and to the overall performance of the facility. Definitely, the results of the work allowed to: increase the yield and purity of products' flows; ensure the compliance of waste flows; increase the workability. Copyright © 2017 Elsevier Ltd. All rights reserved.
DOT National Transportation Integrated Search
2014-01-01
Reducing waste and reusing materials is now : a part of the everyday fabric of life. Recycling : glass, paper, and plastic is an activity in many : households and businesses. Similarly, the : transportation sector generates huge quantities : of concr...
ERIC Educational Resources Information Center
Westinghouse Electric Corp., Carlsbad, NM.
This module is part of a set of management and supervisor training (MAST) materials developed by the Department of Energy for the Waste Isolation Division. Its stated purpose is to enable trainees to communicate effectively in the workplace. The first section of the module is an introduction that includes a terminal objective and opening remarks…
ERIC Educational Resources Information Center
Westinghouse Electric Corp., Carlsbad, NM.
This module is part of a set of management and supervisor training (MAST) materials developed by the Department of Energy for the Waste Isolation Division. Its stated purpose is to provide participants with knowledge and skills necessary to take full advantage of the MAST learning experience. The module contains program guidelines, sample…
Code of Federal Regulations, 2011 CFR
2011-07-01
... are exempt mercury-bearing materials with less than 500 ppm of 40 CFR Part 261, appendix VIII organic... tank sludge 13. Mercury cell process solids 14. Recoverable levels of mercury contained in soil [59 FR...
Code of Federal Regulations, 2012 CFR
2012-07-01
... are exempt mercury-bearing materials with less than 500 ppm of 40 CFR Part 261, appendix VIII organic... tank sludge 13. Mercury cell process solids 14. Recoverable levels of mercury contained in soil [59 FR...
Code of Federal Regulations, 2014 CFR
2014-07-01
... are exempt mercury-bearing materials with less than 500 ppm of 40 CFR Part 261, appendix VIII organic... tank sludge 13. Mercury cell process solids 14. Recoverable levels of mercury contained in soil [59 FR...
Code of Federal Regulations, 2010 CFR
2010-07-01
... are exempt mercury-bearing materials with less than 500 ppm of 40 CFR Part 261, appendix VIII organic... tank sludge 13. Mercury cell process solids 14. Recoverable levels of mercury contained in soil [59 FR...
Code of Federal Regulations, 2013 CFR
2013-07-01
... are exempt mercury-bearing materials with less than 500 ppm of 40 CFR Part 261, appendix VIII organic... tank sludge 13. Mercury cell process solids 14. Recoverable levels of mercury contained in soil [59 FR...
An approach to the usage of polyethylene terephthalate (PET) waste as roadway pavement material.
Gürü, Metin; Çubuk, M Kürşat; Arslan, Deniz; Farzanian, S Ali; Bilici, İbrahim
2014-08-30
This study investigates an application area for Polyethylene Terephthalate (PET) bottle waste which has become an environmental problem in recent decades as being a considerable part of the total plastic waste bulk. Two novel additive materials, namely Thin Liquid Polyol PET (TLPP) and Viscous Polyol PET (VPP), were chemically derived from waste PET bottles and used to modify the base asphalt separately for this aim. The effects of TLPP and VPP on the asphalt and hot mix asphalt (HMA) mixture properties were detected through conventional tests (Penetration, Softening Point, Ductility, Marshall Stability, Nicholson Stripping) and Superpave methods (Rotational Viscosity, Dynamic Shear Rheometer (DSR), Bending Beam Rheometer (BBR)). Also, chemical structures were described by Scanning Electron Microscope (SEM) equipped with Energy Dispersive Spectrometer (EDS) and Fourier Transform Infrared (FTIR) techniques. Since TLPP and VPP were determined to improve the low temperature performance and fatigue resistance of the asphalt as well as the Marshall Stability and stripping resistance of the HMA mixtures based on the results of the applied tests, the usage of PET waste as an asphalt roadway pavement material offers an alternative and a beneficial way of disposal of this ecologically hazardous material. Copyright © 2014 Elsevier B.V. All rights reserved.
DOE Office of Scientific and Technical Information (OSTI.GOV)
Mueth, Joachim
The Paul Scherrer Institut (PSI) is the largest national research centre in Switzerland. Its multidisciplinary research is dedicated to a wide field in natural science and technology as well as particle physics. In this context, PSI is operating, amongst others, a large proton accelerator facility since more than 30 years. In two cyclotrons, protons are accelerated to high speeds and then guided along roughly 100 m of beam line to three different target stations to produce secondary particles like mesons and neutrons for experiments and a separately beam line for UCN. The protons induce spallation processes in the target materials,more » and also at other beam loss points along the way, with emission of protons, neutrons, hydrogen, tritium, helium, heavier fragments and fission processes. In particular the produced neutrons, due to their large penetration depth, will then interact also with the surrounding materials. These interactions of radiation with matter lead to activation and partly to contamination of machine components and the surrounding infrastructures. Maintenance, operation and decommissioning of installations generate inevitably substantial amounts of radioactive operational and dismantling waste like targets, magnets, collimators, shielding (concrete, steel) and of course secondary waste. To achieve an optimal waste management strategy for interim storage or final disposal, radioactive waste has to be characterized, sorted and treated. This strategy is based on radiation protection demands, raw waste properties (size, material, etc.), and requirements to reduce the volume of waste, mainly for legal and economical reasons. In addition, the radiological limitations for transportation of the waste packages to a future disposal site have to be taken into account, as well as special regulatory demands. The characterization is a task of the waste producer. The conditioning processes and quality checks for radioactive waste packages are part of an accredited waste management process of PSI, especially of the Section Dismantling and Waste Management. Strictly proven and accepted methods needed to be developed and enhanced for safe treatment, transport, conditioning and storage. But in the field of waste from research activities, individual and new solutions have to be found in an increasingly growing administrative environment. Furthermore, a wide variety of components, with a really large inventory of radioactive nuclides, has to be handled. And there are always surprising challenges concerning the unusual materials or the nuclide inventory. In case of the operational and dismantling radioactive accelerator waste, the existing conditioning methods are in the process of a continuous enhancement - technically and administratively. The existing authorized specifications of conditioning processes have to be extended to optimize and fully describe the treatment of the inevitably occurring radioactive waste from the accelerator facility. Additional challenges are the changes with time concerning the legal and regulatory requirements - or do we have to consider it as business as usual? This paper gives an overview of the current practices in radioactive waste management and decommissioning of the existing operational accelerator waste. (authors)« less
Treatment of copper industry waste and production of sintered glass-ceramic.
Coruh, Semra; Ergun, Osman Nuri; Cheng, Ta-Wui
2006-06-01
Copper waste is iron-rich hazardous waste containing heavy metals such as Cu, Zn, Co, Pb. The results of leaching tests show that the concentration of these elements exceeds the Turkish and EPA regulatory limits. Consequently, this waste cannot be disposed of in its present form and therefore requires treatment to stabilize it or make it inert prior to disposal. Vitrification was selected as the technology for the treatment of the toxic waste under investigation. During the vitrification process significant amounts of the toxic organic and inorganic chemical compounds could be destroyed, and at the same time, the metal species are immobilized as they become an integral part of the glass matrix. The copper flotation waste samples used in this research were obtained from the Black Sea Copper Works of Samsun, Turkey. The samples were vitrified after being mixed with other inorganic waste and materials. The copper flotation waste and their glass-ceramic products were characterized by X-ray analysis (XRD), scanning electron microscopy and by the toxicity characteristic leaching procedure test. The products showed very good chemical durability. The glass-ceramics fabricated at 850 degrees C/2 h have a large application potential especially as construction and building materials.
Towards Zero-Waste Furniture Design.
Koo, Bongjin; Hergel, Jean; Lefebvre, Sylvain; Mitra, Niloy J
2017-12-01
In traditional design, shapes are first conceived, and then fabricated. While this decoupling simplifies the design process, it can result in unwanted material wastage, especially where off-cut pieces are hard to reuse. In absence of explicit feedback on material usage, the designer remains helpless to effectively adapt the design - even when design variabilities exist. We investigate waste minimizing furniture design wherein based on the current design, the user is presented with design variations that result in less wastage of materials. Technically, we dynamically analyze material space layout to determine which parts to change and how , while maintaining original design intent specified in the form of design constraints. We evaluate the approach on various design scenarios, and demonstrate effective material usage that is difficult, if not impossible, to achieve without computational support.
29 CFR 1915.81 - Housekeeping.
Code of Federal Regulations, 2012 CFR
2012-07-01
... (ii) Provide slip-resistant footwear in accordance with 29 CFR part 1915, subpart I. (3) The employer shall store materials in a manner that does not create a hazard for employees. (4) The employer shall... solid and liquid wastes, that may create a hazard for employees; (iii) Is clear of tools, materials...
29 CFR 1915.81 - Housekeeping.
Code of Federal Regulations, 2014 CFR
2014-07-01
... (ii) Provide slip-resistant footwear in accordance with 29 CFR part 1915, subpart I. (3) The employer shall store materials in a manner that does not create a hazard for employees. (4) The employer shall... solid and liquid wastes, that may create a hazard for employees; (iii) Is clear of tools, materials...
40 CFR 270.17 - Specific part B information requirements for surface impoundments.
Code of Federal Regulations, 2011 CFR
2011-07-01
... volume, physical, and chemical characteristics of the wastes, including their potential to migrate through soil or to volatilize or escape into the atmosphere; (2) The attenuative properties of underlying and surrounding soils or other materials; (3) The mobilizing properties of other materials co-disposed...
Making Self-Lubricating Parts By Powder Metallurgy
NASA Technical Reports Server (NTRS)
Sliney, Harold E.; Dellacorte, Christopher
1990-01-01
Compositions and parameters of powder-metallurgical fabrication processes determined for new class of low-friction, low-wear, self-lubricating materials. Used in oxidizing or reducing atmospheres in bearings and seals, at temperatures from below 25 degrees C to as high as 900 degrees C. Thick parts made with minimal waste.
DOE Office of Scientific and Technical Information (OSTI.GOV)
Larsson, Arne; Lidar, Per; Bergh, Niklas
2013-07-01
Decommissioning of nuclear power plants generates large volumes of radioactive or potentially radioactive waste. The proper management of the dismantling waste plays an important role for the time needed for the dismantling phase and thus is critical to the decommissioning cost. An efficient and thorough process for inventorying, characterization and categorization of the waste provides a sound basis for the planning process. As part of comprehensive decommissioning studies for Nordic NPPs, Westinghouse has developed the decommissioning inventories that have been used for estimations of the duration of specific work packages and the corresponding costs. As part of creating the designmore » basis for a national repository for decommissioning waste, the total production of different categories of waste packages has also been predicted. Studsvik has developed a risk based concept for categorization and handling of the generated waste using six different categories with a span from extremely small risk for radiological contamination to high level waste. The two companies have recently joined their skills in the area of decommissioning on selected market in a consortium named 'ndcon' to further strengthen the proposed process. Depending on the risk for radiological contamination or the radiological properties and other properties of importance for waste management, treatment routes are proposed with well-defined and proven methods for on-site or off-site treatment, activity determination and conditioning. The system is based on a graded approach philosophy aiming for high confidence and sustainability, aiming for re-use and recycling where found applicable. The objective is to establish a process where all dismantled material has a pre-determined treatment route. These routes should through measurements, categorization, treatment, conditioning, intermediate storage and final disposal be designed to provide a steady, un-disturbed flow of material to avoid interruptions. Bottle-necks in the process causes increased space requirements and will have negative impact on the project schedule, which increases not only the cost but also the dose exposure to personnel. For these reasons it is critical to create a process that transfers material into conditioned waste ready for disposal as quickly as possible. To a certain extent the decommissioning program should be led by the waste management process. With the objective to reduce time for handling of dismantled material at site and to efficiently and environmental-friendly use waste management methods (clearance for re-use followed by clearance for recycling), the costs for the plant decommissioning could be reduced as well as time needed for performing the decommissioning project. Also, risks for delays would be reduced with a well-defined handling scheme which limits surprises. Delays are a major cost driver for decommissioning projects. (authors)« less
DOE Office of Scientific and Technical Information (OSTI.GOV)
Not Available
1993-03-01
This volume contains appendices D4 through D17 which cover the following: Waste Isolation Pilot Plant site environmental report; ecological monitoring program at the Waste Isolation Pilot Plant; site characterization; regional and site geology and hydrology; general geology; dissolution features; ground water hydrology; typical carbon sorption bed efficiency; VOC monitoring plan for bin-room tests; chemical compatibility analysis of waste forms and container materials; probable maximum precipitation; WHIP supplementary roof support system room 1, panel 1; and corrosion risk assessment of the Waste Isolation Pilot Plant ``humid`` test bins.
ERIC Educational Resources Information Center
Westinghouse Electric Corp., Carlsbad, NM.
This module is part of a set of management and supervisor training (MAST) materials developed by the Department of Energy for the Waste Isolation Division. Its stated purpose is to enable trainees to solve problems and make decisions in an efficient and effective manner. The first section of the module is an introduction that includes a terminal…
Use of recycled plastics in concrete: A critical review.
Gu, Lei; Ozbakkaloglu, Togay
2016-05-01
Plastics have become an essential part of our modern lifestyle, and the global plastic production has increased immensely during the past 50years. This has contributed greatly to the production of plastic-related waste. Reuse of waste and recycled plastic materials in concrete mix as an environmental friendly construction material has drawn attention of researchers in recent times, and a large number of studies reporting the behavior of concrete containing waste and recycled plastic materials have been published. This paper summarizes the current published literature until 2015, discussing the material properties and recycling methods of plastic and the influence of plastic materials on the properties of concrete. To provide a comprehensive review, a total of 84 studies were considered, and they were classified into sub categories based on whether they dealt with concrete containing plastic aggregates or plastic fibers. Furthermore, the morphology of concrete containing plastic materials is described in this paper to explain the influence of plastic aggregates and plastic fibers on the properties of concrete. The properties of concretes containing virgin plastic materials were also reviewed to establish their similarities and differences with concrete containing recycled plastics. Copyright © 2016 Elsevier Ltd. All rights reserved.
NASA Astrophysics Data System (ADS)
Antonella Dino, Giovanna; Willy Danielsen, Svein; Chiappino, Claudia; Primavori, Piero; Engelsen, Christian John
2016-04-01
Resource preservation is one of the main challenges in Europe, together with waste management and recycling; recently several researchers are interested in the recovering of critical raw materials and secondary raw materials from landfill. Aggregate supply, even if it is not "critical" sensus stricto (s.s.), is one of the European priorities (low value but high volume needs). On the other side, the management of quarry waste , mainly from dimension stones, but also as fines from aggregate crushing, is still a matter of concern. Such materials are managed in different ways both locally and nationwide, and often they are landfilled, because of an unclear legislation and a general lack of data. Most of time the local authorities adopt the maximum precaution principle or the enterprises find it little profitable to recover them, so that the sustainable recycling of such material is not valued. Several studies have shown, depending on the material specific characteristics, the viability of recycling quarry waste into new raw materials used in glass and ceramic industries, precast concrete production, infrastructures etc. (Loudes et al. 2012, Dino&Marian 2015, Bozzola et al 2012, Dino et al. 2012, etc.). Thus, aggregate production may be one of the profitable ways to use quarry waste and is falling under the priority of EU (aggregate supply). Positive economic and environmental effects are likely to be achieved by systematic recycling of quarry waste planned by industries (industrial planning) and public authorities (national and local planning of aggregate exploitation). Today, the recycling level varies to a great extent and systematic recovery is not common among European Countries. In Italy and Norway no significant incentives on recycling or systematic approaches for local aggregate exploitation exist. The environmental consequences can be overexploitation of the natural resources, land take for the landfills, environmental contamination and landscape alteration by the quarry waste heaps. The environmentally sustainable management of quarry waste, which aims to recover and recycle both clean and contaminated materials, would therefore help to reduce the pressure on natural resources, reduce the land take and the environmental contamination. The present paper shows the main challenges connected to quarry waste management, focusing on several possibilities for quarry waste recovering, in order to produce recycled aggregates.
Coelho, André; de Brito, Jorge
2013-05-01
This work is a part of a wider study involving the economic and environmental implications of managing construction and demolition waste (CDW), focused on the operation of a large scale CDW recycling plant. This plant, to be operated in the Lisbon Metropolitan Area (including the Setúbal peninsula), is analysed for a 60 year period, using primary energy consumption and CO2eq emission impact factors as environmental impact performance indicators. Simplified estimation methods are used to calculate industrial equipment incorporated, and the operation and transport related impacts. Material recycling--sorted materials sent to other industries, to act as input--is taken into account by discounting the impacts related to industrial processes no longer needed. This first part focuses on calculating the selected impact factors for a base case scenario (with a 350 tonnes/h installed capacity), while a sensitivity analysis is provided in part two. Overall, a 60 year global primary energy consumption of 71.4 thousand toe (tonne of oil equivalent) and a total CO2eq emission of 135.4 thousand tonnes are expected. Under this operating regime, around 563 thousand toe and 1465 thousand tonnes CO2eq could be prevented by replacing raw materials in several construction materials industries (e.g.: ferrous and non-ferrous metals, plastics, paper and cardboard). Copyright © 2013 Elsevier Ltd. All rights reserved.
Recycling of polymeric fraction of cable waste by rotational moulding.
Díaz, Sara; Ortega, Zaida; McCourt, Mark; Kearns, Mark P; Benítez, Antonio N
2018-06-01
This study focuses on the mechanical recycling of polymeric waste that is produced in considerable amount from the cable industry. Every year large amounts of cables become waste; wires recycling has traditionally focused on metal recovery, while the polymer cover has just been considered as a residue, being landfilled or incinerated. Nowadays, increasingly restrictive regulations and concern about environment make necessary to reduce landfilling as much as possible. Main novelty of the study is that the material used in the research is a post-consumer material and the entire residual material is used, without a previous purification, in contrast with similar studies. Characterization of this residue was performed by thermal analysis, showing that the material is mainly made up of a heavy fraction (84% of the residue), which is not able to melt, fact what makes recycling more difficult. Once characterized, the material was ground, blended with virgin polyethylene and reprocessed by rotational moulding. The influence of the amount of residue and parts structure (1, 2 and 3 layers) was assessed, studying the mechanical behaviour of obtained parts (tensile, flexural and impact properties). It has been found that although mechanical properties get reduced with the increased amount of residue, up to a 35% of residue can be used without an important decrease in mechanical properties. On the other hand, the use of multiple layers in the mouldings allowed obtaining a better external appearance without compromising the mechanical properties. Copyright © 2018 Elsevier Ltd. All rights reserved.
DOE Office of Scientific and Technical Information (OSTI.GOV)
Indacochea, J. E.; Gattu, V. K.; Chen, X.
The results of electrochemical corrosion tests and modeling activities performed collaboratively by researchers at the University of Illinois at Chicago and Argonne National Laboratory as part of workpackage NU-13-IL-UIC-0203-02 are summarized herein. The overall objective of the project was to develop and demonstrate testing and modeling approaches that could be used to evaluate the use of composite alloy/ceramic materials as high-level durable waste forms. Several prototypical composite waste form materials were made from stainless steels representing fuel cladding, reagent metals representing metallic fuel waste streams, and reagent oxides representing oxide fuel waste streams to study the microstructures and corrosion behaviorsmore » of the oxide and alloy phases. Microelectrodes fabricated from small specimens of the composite materials were used in a series of electrochemical tests to assess the corrosion behaviors of the constituent phases and phase boundaries in an aggressive acid brine solution at various imposed surface potentials. The microstructures were characterized in detail before and after the electrochemical tests to relate the electrochemical responses to changes in both the electrode surface and the solution composition. The results of microscopic, electrochemical, and solution analyses were used to develop equivalent circuit and physical models representing the measured corrosion behaviors of the different materials pertinent to long-term corrosion behavior. This report provides details regarding (1) the production of the composite materials, (2) the protocol for the electrochemical measurements and interpretations of the responses of multi-phase alloy and oxide composites, (3) relating corrosion behaviors to microstructures of multi-phase alloys based on 316L stainless steel and HT9 (410 stainless steel was used as a substitute) with added Mo, Ni, and/or Mn, and (4) modeling the corrosion behaviors and rates of several alloy/oxide composite materials made with added lanthanide and uranium oxides. These analyses show the corrosion behaviors of the alloy/ceramic composite materials are very similar to the corrosion behaviors of multi-phase alloy waste forms, and that the presence of oxide inclusions does not impact the corrosion behaviors of the alloy phases. Mixing with metallic waste streams is beneficial to lanthanide and uranium oxides in that they react with Zr in the fuel waste to form highly durable zirconates. The measured corrosion behaviors suggest properly formulated composite materials would be suitable waste forms for combined metallic and oxide waste streams generated during electrometallurgical reprocessing of spent nuclear fuel. Electrochemical methods are suitable for evaluating the durability and modeling long-term behavior of composite waste forms: the degradation model developed for metallic waste forms can be applied to the alloy phases formed in the composite and an affinity-based mineral dissolution model can be applied to the ceramic phases.« less
Waste management strategy for cost effective and environmentally friendly NPP decommissioning
DOE Office of Scientific and Technical Information (OSTI.GOV)
Per Lidar; Arne Larsson; Niklas Bergh
2013-07-01
Decommissioning of nuclear power plants generates large volumes of radioactive or potentially radioactive waste. The proper management of the dismantling waste plays an important role for the time needed for the dismantling phase and thus is critical to the decommissioning cost. An efficient and thorough process for inventorying, characterization and categorization of the waste provides a sound basis for the planning process. As part of comprehensive decommissioning studies for Nordic NPPs, Westinghouse has developed the decommissioning inventories that have been used for estimations of the duration of specific work packages and the corresponding costs. As part of creating the designmore » basis for a national repository for decommissioning waste, the total production of different categories of waste packages has also been predicted. Studsvik has developed a risk based concept for categorization and handling of the generated waste using six different categories with a span from extremely small risk for radiological contamination to high level waste. The two companies have recently joined their skills in the area of decommissioning on selected market in a consortium named ndcon to further strengthen the proposed process. Depending on the risk for radiological contamination or the radiological properties and other properties of importance for waste management, treatment routes are proposed with well-defined and proven methods for on-site or off-site treatment, activity determination and conditioning. The system is based on a graded approach philosophy aiming for high confidence and sustainability, aiming for re-use and recycling where found applicable. The objective is to establish a process where all dismantled material has a pre-determined treatment route. These routes should through measurements, categorization, treatment, conditioning, intermediate storage and final disposal be designed to provide a steady, un-disturbed flow of material to avoid interruptions. Bottle-necks in the process causes increased space requirements and will have negative impact on the project schedule, which increases not only the cost but also the dose exposure to personnel. For these reasons it is critical to create a process that transfers material into conditioned waste ready for disposal as quickly as possible. To a certain extent the decommissioning program should be led by the waste management process. With the objective to reduce time for handling of dismantled material at site and to efficiently and environmental-friendly use waste management methods (clearance for re-use followed by clearance for recycling), the costs for the plant decommissioning could be reduced as well as time needed for performing the decommissioning project. Also, risks for delays would be reduced with a well-defined handling scheme which limits surprises. Delays are a major cost driver for decommissioning projects. (authors)« less
NASA Technical Reports Server (NTRS)
Hyland, R. E.; Wohl, M. L.; Thompson, R. L.; Finnegan, P. M.
1972-01-01
The results are reported of a preliminary feasibility screening study for providing long-term solutions to the problems of handling and managing radioactive wastes by extraterrestrial transportation of the wastes. Matrix materials and containers are discussed along with payloads, costs, and destinations for candidate space vehicles. The conclusions reached are: (1) Matrix material such as spray melt can be used without exceeding temperature limits of the matrix. (2) The cost in mills per kw hr electric, of space disposal of fission products is 4, 5, and 28 mills per kw hr for earth escape, solar orbit, and solar escape, respectively. (3) A major factor effecting cost is the earth storage time. Based on a normal operating condition design for solar escape, a storage time of more than sixty years is required to make the space disposal charge less than 10% of the bus-bar electric cost. (4) Based on a 10 year earth storage without further processing, the number of shuttle launches required would exceed one per day.
The organic agricultural waste as a basic source of biohydrogen production
NASA Astrophysics Data System (ADS)
Sriwuryandari, Lies; Priantoro, E. Agung; Sintawardani, Neni; Astuti, J. Tri; Nilawati, Dewi; Putri, A. Mauliva Hada; Mamat, Sentana, Suharwadji; Sembiring, T.
2016-02-01
Biohydrogen production research was carried out using raw materials of agricultural organic waste that was obtained from markets around the Bandung city. The organic part, which consisted of agricultural waste material, mainly fruit and vegetable waste, was crushed and milled using blender. The sludge that produced from milling process was then used as a substrate for mixed culture microorganism as a raw material to produce biohydrogen. As much as 1.2 kg.day-1 of sludge (4% of total solid) was fed into bioreactor that had a capacity of 30L. Experiment was done under anaerobic fermentation using bacteria mixture culture that maintained at pH in the range of 5.6-6.5 and temperature of 25-30oC on semi-continuous mode. Parameters of analysis include pH, temperature, total solid (TS), organic total solid (OTS), total gas production, and hydrogen gas production. The results showed that from 4% of substrate resulted 897.86 L of total gas, which contained 660.74 L (73.59%) of hydrogen gas. The rate of hydrogen production in this study was 11,063 mol.L-1.h-1.
43 CFR 3715.6 - What things does BLM prohibit under this subpart?
Code of Federal Regulations, 2013 CFR
2013-10-01
..., processing, or disposal of non-mineral, hazardous or toxic materials or waste that are generated elsewhere... electronic parts, appliances, photographic film, and chemicals; searching for buried treasure, treasure trove...
43 CFR 3715.6 - What things does BLM prohibit under this subpart?
Code of Federal Regulations, 2011 CFR
2011-10-01
..., processing, or disposal of non-mineral, hazardous or toxic materials or waste that are generated elsewhere... electronic parts, appliances, photographic film, and chemicals; searching for buried treasure, treasure trove...
43 CFR 3715.6 - What things does BLM prohibit under this subpart?
Code of Federal Regulations, 2012 CFR
2012-10-01
..., processing, or disposal of non-mineral, hazardous or toxic materials or waste that are generated elsewhere... electronic parts, appliances, photographic film, and chemicals; searching for buried treasure, treasure trove...
30 CFR 7.504 - Refuge alternatives and components; general requirements.
Code of Federal Regulations, 2013 CFR
2013-07-01
... Emergency Response Plan. (2) Lighting sufficient for persons to perform tasks. (3) A means to contain human waste effectively and minimize objectionable odors. (4) First aid supplies. (5) Materials, parts, and...
30 CFR 7.504 - Refuge alternatives and components; general requirements.
Code of Federal Regulations, 2014 CFR
2014-07-01
... Emergency Response Plan. (2) Lighting sufficient for persons to perform tasks. (3) A means to contain human waste effectively and minimize objectionable odors. (4) First aid supplies. (5) Materials, parts, and...
30 CFR 7.504 - Refuge alternatives and components; general requirements.
Code of Federal Regulations, 2012 CFR
2012-07-01
... Emergency Response Plan. (2) Lighting sufficient for persons to perform tasks. (3) A means to contain human waste effectively and minimize objectionable odors. (4) First aid supplies. (5) Materials, parts, and...
40 CFR 355.61 - How are key words in this part defined?
Code of Federal Regulations, 2012 CFR
2012-07-01
... waste when mixed or commingled with bedding, compost, feed, soil and other typical materials found with... aqueous or organic solutions, slurries, viscous solutions, suspensions, emulsions, or pastes. State means...
40 CFR 355.61 - How are key words in this part defined?
Code of Federal Regulations, 2013 CFR
2013-07-01
... waste when mixed or commingled with bedding, compost, feed, soil and other typical materials found with... aqueous or organic solutions, slurries, viscous solutions, suspensions, emulsions, or pastes. State means...
Bailey-Shaw, Y A; Golden, K D; Pearson, A G M; Porter, R B R
2012-09-01
This paper describes the determination of fatty acid composition of coffee, citrus and rum distillery wastes using reversed-phase high-performance liquid chromatography (RP-HPLC). Lipid extracts of the waste samples are derivatized with phenacyl bromide and their phenacyl esters are separated on a C8 reversed-phase column by using continuous gradient elution with water and acetonitrile. The presence of saturated and unsaturated fatty acids in quantifiable amounts in the examined wastes, as well as the high percentage recoveries, are clear indications that these wastes have potential value as inexpensive sources of lipids. The HPLC procedures described here could be adopted for further analysis of materials of this nature.
Kang, Hai-Yong; Schoenung, Julie M
2006-03-01
The objectives of this study are to identify the various techniques used for treating electronic waste (e-waste) at material recovery facilities (MRFs) in the state of California and to investigate the costs and revenue drivers for these techniques. The economics of a representative e-waste MRF are evaluated by using technical cost modeling (TCM). MRFs are a critical element in the infrastructure being developed within the e-waste recycling industry. At an MRF, collected e-waste can become marketable output products including resalable systems/components and recyclable materials such as plastics, metals, and glass. TCM has two main constituents, inputs and outputs. Inputs are process-related and economic variables, which are directly specified in each model. Inputs can be divided into two parts: inputs for cost estimation and for revenue estimation. Outputs are the results of modeling and consist of costs and revenues, distributed by unit operation, cost element, and revenue source. The results of the present analysis indicate that the largest cost driver for the operation of the defined California e-waste MRF is the materials cost (37% of total cost), which includes the cost to outsource the recycling of the cathode ray tubes (CRTs) (dollar 0.33/kg); the second largest cost driver is labor cost (28% of total cost without accounting for overhead). The other cost drivers are transportation, building, and equipment costs. The most costly unit operation is cathode ray tube glass recycling, and the next are sorting, collecting, and dismantling. The largest revenue source is the fee charged to the customer; metal recovery is the second largest revenue source.
Impacts of policy and market incentives for solid waste recycling in Dhaka, Bangladesh.
Matter, Anne; Ahsan, Mehedi; Marbach, Michelle; Zurbrügg, Christian
2015-05-01
Solid waste mismanagement in Dhaka, Bangladesh, illustrates a well-known market failure which can be summarized as: waste is a resource in the wrong place. Inorganic materials such as plastic or paper can be used to feed the demand for recycled materials in the industrial sector. Organic materials can be converted and used in the nutrient-starved agricultural sector which is currently heavily depending on chemical fertilizers. They are also a feedstock to generate renewable energy in the form of biogas for this energy-starved country relying on diminishing natural gas reserves and increasing import of coal. Reality however does not capitalize on this potential; instead the waste is a burden for municipal authorities who spend large portions of their budgets attempting to transport it out of the city for discharge into landfills. The major part of these materials still remains uncollected in the residential areas and is discarded indiscriminately in open spaces, polluting the residents' living environment including water, soil and air resources, in the city and beyond. Bangladeshi authorities have, to some extent, recognized this market failure and have developed policies to encourage the development of waste recycling activities. It is also important to note that this market failure is only partial: a large, mostly informal recycling sector has developed in Bangladesh, focusing on inorganic recyclables of market value. The fact that this sector remains largely informal means that these actors perceive significant barriers to formalization. Comparatively, the organic waste recycling sector is less driven by market mechanisms. Competition from chemical fertilizers and fossil fuels is fierce and hinders the development of market opportunities for compost and renewable energy. Nevertheless commercial production of compost and biogas from organic municipal waste is formalized and benefiting from policy incentives. Copyright © 2015 Elsevier Ltd. All rights reserved.
Code of Federal Regulations, 2010 CFR
2010-01-01
... license with respect to a geologic repository. 51.109 Section 51.109 Energy NUCLEAR REGULATORY COMMISSION... Public hearings in proceedings for issuance of materials license with respect to a geologic repository... waste repository at a geologic repository operations area under parts 60 and 63 of this chapter, and in...
Vascular plants of waste storage sites in the 200 areas of the Hanford reservation
DOE Office of Scientific and Technical Information (OSTI.GOV)
Price, K.R.; Rickard, W.H.
1973-12-01
A brief accounting of terrestrial, riparian and semi-aquatic plants known to be associated with radioactive waste storage sites in the 200 Areas of the Hanford Reservation is given. In most cases the species are characteristic of those which generally inhabit the reservation, but some plants are restricted to specialized habitats provided by particular waste storage sites. It is impractical to list all species growing at each waste storage site because of seasonal variation and changes brought about by environmental management practices. An alpbabetical listing has been prepared with an example of where each species is known to occur. The listmore » will be updated as needed and expanded to include other waste storage areas. Plant specimens were collected during spring and fall when flowering material was available. Herbarium mounts were prepared of many specimens and have been retained as part of the Hanford Reservation herbarium collection. Identification to species level was made whenever possible. Color photographs of the specimen mounts are used as training aids and demonstration material by ARHCO Radiation Monitoring personnel. (auth)« less
40 CFR 60.1090 - What must I do with my revised materials separation plan?
Code of Federal Regulations, 2014 CFR
2014-07-01
... Performance for Small Municipal Waste Combustion Units for Which Construction is Commenced After August 30... Administrator by the date you submit the application for a construction permit under 40 CFR part 51, subpart I, or part 52. (If you are not required to submit an application for a construction permit under 40 CFR...
40 CFR 60.1090 - What must I do with my revised materials separation plan?
Code of Federal Regulations, 2012 CFR
2012-07-01
... Performance for Small Municipal Waste Combustion Units for Which Construction is Commenced After August 30... Administrator by the date you submit the application for a construction permit under 40 CFR part 51, subpart I, or part 52. (If you are not required to submit an application for a construction permit under 40 CFR...
DOE Office of Scientific and Technical Information (OSTI.GOV)
Koenig, Werner; Baumann, Roland
2007-07-01
In September 2006, decommissioning and dismantling of the Siemens MOX Fuel Fabrication Plant in Hanau were completed. The process equipment and the fabrication buildings were completely decommissioned and dismantled. The other buildings were emptied in whole or in part, although they were not demolished. Overall, the decommissioning process produced approximately 8500 Mg of radioactive waste (including inactive matrix material); clearance measurements were also performed for approximately 5400 Mg of material covering a wide range of types. All the equipment in which nuclear fuels had been handled was disposed of as radioactive waste. The radioactive waste was conditioned on the basismore » of the requirements specified for the projected German final disposal site 'Schachtanlage Konrad'. During the pre-conditioning, familiar processes such as incineration, compacting and melting were used. It has been shown that on account of consistently applied activity containment (barrier concept) during operation and dismantling, there has been no significant unexpected contamination of the plant. Therefore almost all the materials that were not a priori destined for radioactive waste were released without restriction on the basis of the applicable legal regulations (chap. 29 of the Radiation Protection Ordinance), along with the buildings and the plant site. (authors)« less
Biodegradable and compostable alternatives to conventional plastics.
Song, J H; Murphy, R J; Narayan, R; Davies, G B H
2009-07-27
Packaging waste forms a significant part of municipal solid waste and has caused increasing environmental concerns, resulting in a strengthening of various regulations aimed at reducing the amounts generated. Among other materials, a wide range of oil-based polymers is currently used in packaging applications. These are virtually all non-biodegradable, and some are difficult to recycle or reuse due to being complex composites having varying levels of contamination. Recently, significant progress has been made in the development of biodegradable plastics, largely from renewable natural resources, to produce biodegradable materials with similar functionality to that of oil-based polymers. The expansion in these bio-based materials has several potential benefits for greenhouse gas balances and other environmental impacts over whole life cycles and in the use of renewable, rather than finite resources. It is intended that use of biodegradable materials will contribute to sustainability and reduction in the environmental impact associated with disposal of oil-based polymers. The diversity of biodegradable materials and their varying properties makes it difficult to make simple, generic assessments such as biodegradable products are all 'good' or petrochemical-based products are all 'bad'. This paper discusses the potential impacts of biodegradable packaging materials and their waste management, particularly via composting. It presents the key issues that inform judgements of the benefits these materials have in relation to conventional, petrochemical-based counterparts. Specific examples are given from new research on biodegradability in simulated 'home' composting systems. It is the view of the authors that biodegradable packaging materials are most suitable for single-use disposable applications where the post-consumer waste can be locally composted.
Densified waste form and method for forming
Garino, Terry J.; Nenoff, Tina M.; Sava Gallis, Dorina Florentina
2015-08-25
Materials and methods of making densified waste forms for temperature sensitive waste material, such as nuclear waste, formed with low temperature processing using metallic powder that forms the matrix that encapsulates the temperature sensitive waste material. The densified waste form includes a temperature sensitive waste material in a physically densified matrix, the matrix is a compacted metallic powder. The method for forming the densified waste form includes mixing a metallic powder and a temperature sensitive waste material to form a waste form precursor. The waste form precursor is compacted with sufficient pressure to densify the waste precursor and encapsulate the temperature sensitive waste material in a physically densified matrix.
DOE Office of Scientific and Technical Information (OSTI.GOV)
Curtin, D.P.
The process analyzed involves non-production, laboratory environment use of trichloroethylene for the cleaning of semiconductor devices. The option selection centered on the replacement of the trichloroethylene with a non-hazardous material. This process waste assessment was performed as part of a pilot project.
2003-08-29
KENNEDY SPACE CENTER, FLA. - A KSC employee dressed in a "bunny suit," standard clean room apparel, disposes of some waste material into a container designated for the purpose. The apparel is designed to cover the hair, clothing and shoes of employees entering a clean room to prevent particulate matter from contaminating the space flight hardware being stored or processed in the room. The suit and container are both part of KSC's Foreign Object Debris (FOD) control program, an important safety initiative.
Impacts of policy and market incentives for solid waste recycling in Dhaka, Bangladesh
DOE Office of Scientific and Technical Information (OSTI.GOV)
Matter, Anne; Swisscontact: Swiss Foundation for Technical Cooperation, South Asian Regional Office, House No. 19, Road No. 11, Baridhara, Dhaka 1212; Ahsan, Mehedi
Highlights: • Bangladesh’s industry and population are growing rapidly, producing more urban waste. • Recycling reduces the solid waste management burden of Municipalities. • A wide array of informal and formal actors is involved in collection and recycling. • Demand for recycled materials and renewable energy creates market incentives. • Policy incentives exist, but they only reach the formal industry. - Abstract: Solid waste mismanagement in Dhaka, Bangladesh, illustrates a well-known market failure which can be summarized as: waste is a resource in the wrong place. Inorganic materials such as plastic or paper can be used to feed the demandmore » for recycled materials in the industrial sector. Organic materials can be converted and used in the nutrient-starved agricultural sector which is currently heavily depending on chemical fertilizers. They are also a feedstock to generate renewable energy in the form of biogas for this energy-starved country relying on diminishing natural gas reserves and increasing import of coal. Reality however does not capitalize on this potential; instead the waste is a burden for municipal authorities who spend large portions of their budgets attempting to transport it out of the city for discharge into landfills. The major part of these materials still remains uncollected in the residential areas and is discarded indiscriminately in open spaces, polluting the residents’ living environment including water, soil and air resources, in the city and beyond. Bangladeshi authorities have, to some extent, recognized this market failure and have developed policies to encourage the development of waste recycling activities. It is also important to note that this market failure is only partial: a large, mostly informal recycling sector has developed in Bangladesh, focusing on inorganic recyclables of market value. The fact that this sector remains largely informal means that these actors perceive significant barriers to formalization. Comparatively, the organic waste recycling sector is less driven by market mechanisms. Competition from chemical fertilizers and fossil fuels is fierce and hinders the development of market opportunities for compost and renewable energy. Nevertheless commercial production of compost and biogas from organic municipal waste is formalized and benefiting from policy incentives.« less
Economical and environmentally-friendly approaches for usage of onion (Allium cepa L.) waste.
Sharma, Kavita; Mahato, Neelima; Nile, Shivraj Hariram; Lee, Eul Tal; Lee, Yong Rok
2016-08-10
Onion (Allium cepa L.) is one of the most commonly cultivated crops across the globe, and its production is increasing every year due to increasing consumer demand. Simultaneously, huge amounts of waste are produced from different parts of the onion, which ultimately affect the environment in various ways. Hence, proper usage as well as disposal of this waste is important from the environmental aspect. This review summarizes various usage methods of onion waste material, and processes involved to achieve maximum benefits. Processing industries produce the largest amount of onion waste. Other sources are storage systems, domestic usage and cultivation fields. Particular emphasis has been given to the methods used for better extraction and usage of onion waste under specific topics: viz. organic synthesis, production of biogas, absorbent for pollutants and value added products.
NASA Astrophysics Data System (ADS)
Yanagisawa, Mitsunori; Nakamura, Kanami; Nakasaki, Kiyohiko
In the present study, biomass waste raw materials including paper mill sludge, bamboo, sea lettuce, and shochu residue (from a distiller) and crude enzymes derived from inedible and discarded scallop parts were used to produce L-lactic acid for the raw material of biodegradable plastic poly-lactic acid. The activities of cellulase and amylase in the crude enzymes were 22 and 170units/L, respectively, and L-lactic acid was produced from every of the above mentioned biomass wastes, by the method of liquid-state simultaneous saccharification and fermentation (SSF) . The L-lactic acid concentrations produced from sea lettuce and shochu residue, which contain high concentration of starch were 3.6 and 9.3g/L, respectively, and corresponded to greater than 25% of the conversion of glucans contained in these biomass wastes. Furthermore, using the solid state SSF method, concentrations as high as 13g/L of L-lactic acid were obtained from sea lettuce and 26g/L were obtained from shochu residue.
Yasui, Shojiro
2014-01-01
The accident at the Fukushima Daiichi Atomic Power Plant that accompanied the Great East Japan Earthquake on March 11, 2011, released a large amount of radioactive material. To rehabilitate the contaminated areas, the government of Japan decided to carry out decontamination work and manage the waste resulting from decontamination. In the summer of 2013, the Ministry of the Environment planned to begin a full-scale process for waste disposal of contaminated soil and wastes removed as part of the decontamination work. The existing regulations were not developed to address such a large amount of contaminated wastes. The Ministry of Health, Labour and Welfare (MHLW), therefore, had to amend the existing regulations for waste disposal workers. The amendment of the general regulation targeted the areas where the existing exposure situation overlaps the planned exposure situation. The MHLW established the demarcation lines between the two regulations to be applied in each situation. The amendment was also intended to establish provisions for the operation of waste disposal facilities that handle large amounts of contaminated materials. Deliberation concerning the regulation was conducted when the facilities were under design; hence, necessary adjustments should be made as needed during the operation of the facilities.
Densified waste form and method for forming
DOE Office of Scientific and Technical Information (OSTI.GOV)
Garino, Terry J.; Nenoff, Tina M.; Sava Gallis, Dorina Florentina
Materials and methods of making densified waste forms for temperature sensitive waste material, such as nuclear waste, formed with low temperature processing using metallic powder that forms the matrix that encapsulates the temperature sensitive waste material. The densified waste form includes a temperature sensitive waste material in a physically densified matrix, the matrix is a compacted metallic powder. The method for forming the densified waste form includes mixing a metallic powder and a temperature sensitive waste material to form a waste form precursor. The waste form precursor is compacted with sufficient pressure to densify the waste precursor and encapsulate themore » temperature sensitive waste material in a physically densified matrix.« less
Trash to Gas (TtG) Simulant Analysis
NASA Technical Reports Server (NTRS)
Miles, John D., II; Hintze, Paul E.
2014-01-01
Space exploration in outer earths orbit is a long-term commitment, where the reuse of discarded materials is a critical component for its success. The Logistics Reduction and Repurposing (LRR) project under the NASA Advanced Exploration System Program is a project focused on technologies that reduce the amount of consumables that are needed to be sent into space, repurpose items sent to space, or convert wastes to commodities. In particular, Trash to Gas (TtG), part of the LRR project, is a novel space technology capable of converting raw elements from combustible waste including food waste and packaging, paper, wipes and towels, nitrile gloves, fecal matter, urine brine, maximum absorbency garments, and other organic wastes from human space exploration into useful gases. Trash to gas will ultimately reduce mission cost by producing a portion of important consumables in situ. This paper will discuss results of waste processing by steam reforming. Steam reforming is a thermochemical process developed as part of TtG, where waste is heated in the presence of oxygen and steam to produce carbon dioxide, carbon monoxide, hydrogen, methane and water. The aim of this experiment is to investigate the processing of different waste simulants and their gaseous products. This will lay a foundation for understating and optimizing the production of useful gases for propulsion and recovery of water for life support.
Hartwig, Eike; Clemens, Thomas; Heckroth, Mathias
2007-05-01
This paper continues the investigations of Clemens and Hartwig from 1992 on the proportion of garbage used as nesting material in the Kittiwake colony at Bulbjerg in the Jammerbugt in Northwest Denmark. Whereas in the year 1992 plastic garbage items were included in 39.3% of 466 Kittiwake nests in the Bulbjerg colony, in 2005 57.2% of 311 nests contained plastic debris. Although it has been forbidden to dispose of plastic garbage into the marine environment since the implementation of the MARPOL 73/78-Agreement/Annex V (Regulation for the Prevention of Pollution by Ship Waste) of 1989 and especially since the declaration of the North Sea as a MARPOL-Special Area for garbage in 1991, the pollution of the oceans and the North Sea is still an ubiquitous problem, particularly with regard to plastic waste. Plastic waste is presumably not used preferentially for nest-building, but in the context of available nesting material in the waters surrounding the breeding colony. Therefore the share of garbage parts in nests of certain species of birds is an indicator of the amount of waste in the natural environment in the vicinity of their breeding site.
RCRA Sustainable Materials Management Information
This asset includes a broad variety of documents, descriptive data, technical analyses and guidance materials relative to voluntary improvements in resource conservation, the beneficial use of sustainable materials and the management of non-hazardous wastes and materials. Included in this asset are participant information and outreach materials of various voluntary programs relating to better materials and waste management programs. An example is the WasteWise program and Sustainable Materials Management (SMM) Challenges, which help organizations and businesses apply sustainable materials management practices to reduce municipal and select industrial wastes. Also included in this asset are guidance materials to assist municipalities in recycling and reuse of municipal solid waste, including diverting materials to composting, and the use of conversion methods such as anaerobic digestion. Another component are the data necessary to compile reports on the characterization of municipal solid waste (including such waste streams as food waste, yard and wood waste, discarded electronics, and household non-hazardous waste), the recycled content of manufactured goods, and other analyses performed using such tools as the Waste Assessment Reduction Model (WARM).For industrial non-hazardous waste, this asset includes guidance and outreach materials on industrial materials recycling and waste minimization. Finally, this asset includes research analyses on sustainable materia
Nasrullah, Muhammad; Vainikka, Pasi; Hannula, Janne; Hurme, Markku; Kärki, Janne
2014-08-01
This paper presents the mass, energy and material balances of a solid recovered fuel (SRF) production process. The SRF is produced from commercial and industrial waste (C&IW) through mechanical treatment (MT). In this work various streams of material produced in SRF production process are analyzed for their proximate and ultimate analysis. Based on this analysis and composition of process streams their mass, energy and material balances are established for SRF production process. Here mass balance describes the overall mass flow of input waste material in the various output streams, whereas material balance describes the mass flow of components of input waste stream (such as paper and cardboard, wood, plastic (soft), plastic (hard), textile and rubber) in the various output streams of SRF production process. A commercial scale experimental campaign was conducted on an MT waste sorting plant to produce SRF from C&IW. All the process streams (input and output) produced in this MT plant were sampled and treated according to the CEN standard methods for SRF: EN 15442 and EN 15443. The results from the mass balance of SRF production process showed that of the total input C&IW material to MT waste sorting plant, 62% was recovered in the form of SRF, 4% as ferrous metal, 1% as non-ferrous metal and 21% was sorted out as reject material, 11.6% as fine fraction, and 0.4% as heavy fraction. The energy flow balance in various process streams of this SRF production process showed that of the total input energy content of C&IW to MT plant, 75% energy was recovered in the form of SRF, 20% belonged to the reject material stream and rest 5% belonged with the streams of fine fraction and heavy fraction. In the material balances, mass fractions of plastic (soft), plastic (hard), paper and cardboard and wood recovered in the SRF stream were 88%, 70%, 72% and 60% respectively of their input masses to MT plant. A high mass fraction of plastic (PVC), rubber material and non-combustibles (such as stone/rock and glass particles), was found in the reject material stream. Copyright © 2014 Elsevier Ltd. All rights reserved.
Javierre, C; Clavería, I; Ponz, L; Aísa, J; Fernández, A
2007-01-01
The amount of polymer material wasted during thermoplastic injection moulding is very high. It comes from both the feed system of the part, and parts necessary to set up the mould, as well as the scrap generated along the process due to quality problems. The residues are managed through polymer recycling that allows reuse of the materials in the manufacturing injection process. Recycling mills convert the parts into small pieces that are used as feed material for injection, by mixing the recycled feedstock in different percentages with raw material. This mixture of both raw and recycled material modifies material properties according to the percentage of recycled material introduced. Some of the properties affected by this modification are those related to rheologic behaviour, which strongly conditions the future injection moulding process. This paper analyzes the rheologic behaviour of material with different percentages of recycled material by means of a capillary rheometer, and evaluates the influence of the corresponding viscosity curves obtained on the injection moulding process, where small variations of parameters related to rheological behaviour, such as pressure or clamping force, can be critical to the viability and cost of the parts manufactured by injection moulding.
NASA Astrophysics Data System (ADS)
Galińska, Anna; Czarnecki, Sławomir
2017-10-01
In recent years, concrete has been the most popular construction material. The main component of the concrete is cement. However, its production and transport causes significant emissions of CO2. Reports in the literature show that many laboratories are attempting to modify the composition of the concrete using various additives. These attempts are primarily designed to eliminate parts of cement. The greater part of the cement will be replaced with the selected additive, the more significant is the economic and ecological effect. Most attempts are related to the replacement of the selected additive in an amount of from 10 to 30% by weight of cement. Mineral powders, which are waste material producing crushed aggregate, are increasingly used for this purpose. Management of the waste carries significant cost related to their storage and disposal. With this in mind, the aim of this study was to evaluate the effect of mineral powders derived from industrial wastes on selected mechanical properties of concrete. In particular, the aim was to determine the effect of quartz and quartz-feldspar powders. For this purpose, 40, 50, 60% by weight of the cement was replaced by the selected powders. The results obtained were analysed and compared with previous attempts to replace the selected additive in an amount of from 10 to 30% by weight of cement.
Biodegradable packing materials from hydrolysates of collagen waste proteins.
Langmaier, F; Mokrejs, P; Kolomaznik, K; Mladek, M
2008-01-01
Enzymatic hydrolysates of waste collagen proteins (H), from current industrial manufacture (leather, edible meat product casings, etc.) of mean molecular mass 20-30 kDa by a reaction with dialdehyde starch (DAS), produces hydrogels applicable as biodegradable (or even edible) packaging materials for food, cosmetic and pharmaceutical products. Thermo-reversibility of prepared hydrogels is given by concentrations of H and DAS in a reaction mixture. At concentrations of H 25-30% (w/w) and that of DAS 15-20% (related to weight of hydrolysate), thermo-reversible hydrogels arise, which can be processed into packaging materials by a technique similar to that of soft gelatin capsules (SGC). Exceeding the limit of 20% DAS leads to hydrogels that are thermo-reversible only in part, a further increase in DAS concentration then leads to thermo-irreversible gels whose processing into biodegradable packaging materials necessitates employment of other procedures.
Biodegradable and compostable alternatives to conventional plastics
Song, J. H.; Murphy, R. J.; Narayan, R.; Davies, G. B. H.
2009-01-01
Packaging waste forms a significant part of municipal solid waste and has caused increasing environmental concerns, resulting in a strengthening of various regulations aimed at reducing the amounts generated. Among other materials, a wide range of oil-based polymers is currently used in packaging applications. These are virtually all non-biodegradable, and some are difficult to recycle or reuse due to being complex composites having varying levels of contamination. Recently, significant progress has been made in the development of biodegradable plastics, largely from renewable natural resources, to produce biodegradable materials with similar functionality to that of oil-based polymers. The expansion in these bio-based materials has several potential benefits for greenhouse gas balances and other environmental impacts over whole life cycles and in the use of renewable, rather than finite resources. It is intended that use of biodegradable materials will contribute to sustainability and reduction in the environmental impact associated with disposal of oil-based polymers. The diversity of biodegradable materials and their varying properties makes it difficult to make simple, generic assessments such as biodegradable products are all ‘good’ or petrochemical-based products are all ‘bad’. This paper discusses the potential impacts of biodegradable packaging materials and their waste management, particularly via composting. It presents the key issues that inform judgements of the benefits these materials have in relation to conventional, petrochemical-based counterparts. Specific examples are given from new research on biodegradability in simulated ‘home’ composting systems. It is the view of the authors that biodegradable packaging materials are most suitable for single-use disposable applications where the post-consumer waste can be locally composted. PMID:19528060
Starvin, A M; Rao, T Prasada
2004-09-10
As a part of removal of toxic heavy metals from hazardous wastes, solid phase extraction (SPE) of mercury(II) at trace and ultra trace levels was studied using 1-(2-thiazolylazo)-2-naphthol (TAN) functionalized activated carbon (AC). The SPE material removes traces of mercury(II) quantitatively in the pH range 6.0 +/- 0.2. Other parameters that influence quantitative recovery of mercury(II), viz. percent concentration of TAN in AC, amount of TAN-AC, preconcentration time and volume of aqueous phase were varied and optimized. The possible means of removal of Hg(II) from other metal ions that are likely to be present in the wastes of the chloroalkali industry is discussed. The potential of TAN-functionalized AC SPE material for decontaminating mercury from the brine sludge and cell house effluent of a chloralkali plant has been evaluated.
DOE Office of Scientific and Technical Information (OSTI.GOV)
Not Available
1990-05-21
The package, referred to as 'Strawman II', is a working document that represents EPA's latest staff position on an effective program to regulate wastes and other materials uniquely associated with noncoal mining. Strawman II does not represent a proposed rule. The package consists of two parts: (1) the Foreward, which describes the pre-rulemaking Strawman process, a background and overview of the mining waste program as envisioned in the package, and discussions of major issues concerning the program and its scope; and (2) the Regulatory Approach, presented as '40 CFR XXX, XXY, and XXZ' to reflect how the program might appearmore » in regulatory language. Discussions and amplifications of specific points are also interspersed throughout the Regulatory Approach. EPA encourages all interested parties to convey their views on any and all aspects of the program concept.« less
Enhancement of the recycling of waste Ni-Cd and Ni-MH batteries by mechanical treatment.
Huang, Kui; Li, Jia; Xu, Zhenming
2011-06-01
A serious environmental problem was presented by waste batteries resulting from lack of relevant regulations and effective recycling technologies in China. The present work considered the enhancement of waste Ni-Cd and Ni-MH batteries recycling by mechanical treatment. In the process of characterization, two types of waste batteries (Ni-Cd and Ni-MH batteries) were selected and their components were characterized in relation to their elemental chemical compositions. In the process of mechanical separation and recycling, waste Ni-Cd and Ni-MH batteries were processed by a recycling technology without a negative impact on the environment. The technology contained mechanical crushing, size classification, gravity separation, and magnetic separation. The results obtained demonstrated that: (1) Mechanical crushing was an effective process to strip the metallic parts from separators and pastes. High liberation efficiency of the metallic parts from separators and pastes was attained in the crushing process until the fractions reached particle sizes smaller than 2mm. (2) The classified materials mainly consisted of the fractions with the size of particles between 0.5 and 2mm after size classification. (3) The metallic concentrates of the samples were improved from around 75% to 90% by gravity separation. More than 90% of the metallic materials were separated into heavy fractions when the particle sizes were larger than 0.5mm. (4) The size of particles between 0.5 and 2mm and the rotational speed of the separator between 30 and 60 rpm were suitable for magnetic separation during industrial application, with the recycling efficiency exceeding 95%. Copyright © 2011 Elsevier Ltd. All rights reserved.
Thermal Stability and Material Balance of Nanomaterials in Waste Incineration
NASA Astrophysics Data System (ADS)
Paur, H.-R.; Baumann, W.; Hauser, M.; Lang, I.; Teuscher, N.; Seifert, H.; Stapf, D.
2017-06-01
Nanostructured materials are widely used to improve the properties of consumer products such as tires, cosmetics, light weight equipment etc. Due to their complex composition these products are hardly recycled and thermal treatment is preferred. In this study we investigated the thermal stability and material balance of nanostructured metal oxides in flames and in an industrial waste incinerator. We studied the size distribution of nanostructured metal oxides (CeO2, TiO2, SiO2) in a flame reactor and in a heated reaction tube. In the premixed ethylene/air flame, nano-structured CeO2 partly evaporates forming a new particle mode. This is probably due to chemical reactions in the flame. In addition sintering of agglomerates takes place in the flame. In the electrically heated reaction tube however only sintering of the agglomerated nanomaterials is observed. Ceria has a low background in waste incinerators and is therefore a suitable tracer for investigating the fate of nanostructured materials. Low concentrations of Ceria were introduced by a two-phase nozzle into the post-combustion zone of a waste incinerator. By the incineration of coal dust in a burning chamber the Ceria nanoparticles are mainly found in the size range of the fly ash (1 - 10 µm) because of agglomeration. With gas as a fuel less agglomeration was observed and the Ceria nanoparticles were in the particle size range below 1 µm.
NASA Astrophysics Data System (ADS)
Jeong, Sueng-Won; Lee, Choonoh; Cho, Yong-Chan; Wu, Ying-Hsin
2015-04-01
In Korea, approximately 5,000 metal mines are spread, but 50% of them are still abandoned without any proper remediation and cleanup. Summer heavy rainfall can result in the physicochemical modification of waste rock materials in the mountainous. From the geotechnical monitoring and field investigation, there are visible traces of mass movements every year. Soil erosion is one of severe phenomena in the study area. In particular, study area is located in the upper part of the Busan Metropolitan City and near the city's water supply. With respect to the supply of drinking water and maintenance of ecological balance, proper disposal of waste rock materials is required. For this reason, we examine the rheological properties of waste rock materials as a function of solid content using a ball- and vane-penetrated rheometer. In the flow curves, which are the relationship between the shear stress and shear rate of waste rock materials, we found that the soil samples exhibited a shear thinning beahivor regardless of solid content. The Bingham, Herschel-Bulkley, Power-law, and Papanastasiou models are used to determine the rheological properties. Assuming that the soil samples behaved as the viscoplastic behavior, the yield stress and viscosity are determined for different water contents. As a result, there are clear relationships between the solid content and rheological values (i.e., Bingham yield stress and plastic viscosity). From these relationships, the maximum and minimum of Bingham yield stresses are ranged from 100 to 2000 Pa. The debris flow mobilization is analysed using a 1D BING and 2D Debris flow models. In addition, the effect of wall slip and test apparatus are discussed.
LITERATURE REVIEWS TO SUPPORT ION EXCHANGE TECHNOLOGY SELECTION FOR MODULAR SALT PROCESSING
DOE Office of Scientific and Technical Information (OSTI.GOV)
King, W
2007-11-30
This report summarizes the results of literature reviews conducted to support the selection of a cesium removal technology for application in a small column ion exchange (SCIX) unit supported within a high level waste tank. SCIX is being considered as a technology for the treatment of radioactive salt solutions in order to accelerate closure of waste tanks at the Savannah River Site (SRS) as part of the Modular Salt Processing (MSP) technology development program. Two ion exchange materials, spherical Resorcinol-Formaldehyde (RF) and engineered Crystalline Silicotitanate (CST), are being considered for use within the SCIX unit. Both ion exchange materials havemore » been studied extensively and are known to have high affinities for cesium ions in caustic tank waste supernates. RF is an elutable organic resin and CST is a non-elutable inorganic material. Waste treatment processes developed for the two technologies will differ with regard to solutions processed, secondary waste streams generated, optimum column size, and waste throughput. Pertinent references, anticipated processing sequences for utilization in waste treatment, gaps in the available data, and technical comparisons will be provided for the two ion exchange materials to assist in technology selection for SCIX. The engineered, granular form of CST (UOP IE-911) was the baseline ion exchange material used for the initial development and design of the SRS SCIX process (McCabe, 2005). To date, in-tank SCIX has not been implemented for treatment of radioactive waste solutions at SRS. Since initial development and consideration of SCIX for SRS waste treatment an alternative technology has been developed as part of the River Protection Project Waste Treatment Plant (RPP-WTP) Research and Technology program (Thorson, 2006). Spherical RF resin is the baseline media for cesium removal in the RPP-WTP, which was designed for the treatment of radioactive waste supernates and is currently under construction in Hanford, WA. Application of RF for cesium removal in the Hanford WTP does not involve in-riser columns but does utilize the resin in large scale column configurations in a waste treatment facility. The basic conceptual design for SCIX involves the dissolution of saltcake in SRS Tanks 1-3 to give approximately 6 M sodium solutions and the treatment of these solutions for cesium removal using one or two columns supported within a high level waste tank. Prior to ion exchange treatment, the solutions will be filtered for removal of entrained solids. In addition to Tanks 1-3, solutions in two other tanks (37 and 41) will require treatment for cesium removal in the SCIX unit. The previous SCIX design (McCabe, 2005) utilized CST for cesium removal with downflow supernate processing and included a CST grinder following cesium loading. Grinding of CST was necessary to make the cesium-loaded material suitable for vitrification in the SRS Defense Waste Processing Facility (DWPF). Because RF resin is elutable (and reusable) and processing requires conversion between sodium and hydrogen forms using caustic and acidic solutions more liquid processing steps are involved. The WTP baseline process involves a series of caustic and acidic solutions (downflow processing) with water washes between pH transitions across neutral. In addition, due to resin swelling during conversion from hydrogen to sodium form an upflow caustic regeneration step is required. Presumably, one of these basic processes (or some variation) will be utilized for MSP for the appropriate ion exchange technology selected. CST processing involves two primary waste products: loaded CST and decontaminated salt solution (DSS). RF processing involves three primary waste products: spent RF resin, DSS, and acidic cesium eluate, although the resin is reusable and typically does not require replacement until completion of multiple treatment cycles. CST processing requires grinding of the ion exchange media, handling of solids with high cesium loading, and handling of liquid wash and conditioning solutions. RF processing requires handling and evaporation of cesium eluates, disposal of spent organic resin, and handling of the various liquid wash and regenerate solutions used. In both cases, the DSS will be immobilized in a low activity waste form. It appears that both technologies are mature, well studied, and generally suitable for this application. Technology selection will likely be based on downstream impacts or preferences between the various processing options for the two materials rather than on some unacceptable performance property identified for one material. As a result, the following detailed technical review and summary of the two technologies should be useful to assist in technology selection for SCIX.« less
NASA Astrophysics Data System (ADS)
Neznakomova, Margarita; Boteva, Silvena; Tzankov, Luben; Elhag, Mohamed
2018-04-01
The aim of this work was to investigate the possibility of using non-woven materials (NWM) from waste fibers for oil spill cleanup and their subsequent recovery. Manufacture of textile and readymade products generates a significant amount of solid waste. A major part of it is deposited in landfills or disposed of uncontrollably. This slowly degradable waste causes environmental problems. In the present study are used two types of NWM obtained by methods where waste fibers are utilized. Thus, real textile products are produced (blankets) with which spills are covered and removed by adsorption. These products are produced by two methods: the strengthening of the covering from recovered fibers is made by entanglement when needles of special design pass through layers (needle-punching) or by stitching with thread (technology Maliwatt). Regardless of the random nature of the fiber mixture, the investigated products are good adsorbents of petroleum products. The nature of their structure (a significant void volume and developed surface) leads to a rapid recovery of the spilled petroleum products without sinking of the fiber layer for the sampled times. The used NWM can be burned under special conditions.
Sydney tar ponds: some problems in quantifying toxic waste.
Furimsky, Edward
2002-12-01
Information on the type and amount of hazardous and toxic waste is required to develop a meaningful strategy and estimate a realistic cost for clean up of the Sydney Tar Pond site which is located on Cape Breton, in the province of Nova Scotia, Canada. The site covers the area of the decommissioned Sysco (Sydney Steel Corporation) plant. The materials of concern include BTEX (benzene, toluene, ethylbenzene, and xylenes), PAH (polycyclic aromatic hydrocarbons), PCB (polychlorinated biphenyl), and particulates laden with toxic metals, such as arsenic, lead, and others. The originally nontoxic materials such as soil, blast furnace slag, and vegetation, as well as surface and ground waters, which were subsequently contaminated, must also be included if they fail tests prescribed by environmental regulations. An extensive sampling program must be undertaken to obtain data for an accurate estimate of the waste to be cleaned and disposed of. Apparently, 700,000 tons of toxic waste, which is believed to be present on the site, may represent only a fraction of the actual amount. The clean-up of the site is only part of the solution. Toxic waste has to be disposed of in accordance with environmental regulations.
Sliwinski-Korell, A; Lutz, F
1998-04-01
In the last years the standards for professional handling of hazardous material as well as health and safety in the veterinary practice became considerably more stringent. This is expressed in various safety regulations, particularly the decree of hazardous material and the legislative directives concerning health and safety at work. In part 1, a definition based on the law for hazardous material is given and the potential risks are mentioned. The correct documentation regarding the protection of the purchase, storage, working conditions and removal of hazardous material and of the personal is explained. General rules for the handling of hazardous material are described. In part 2, particular emphasis is put on the handling of flammable liquids, disinfectants, cytostatica, pressurised gas, liquid nitrogen, narcotics, mailing of potentially infectious material and safe disposal of hazardous waste. Advice about possible unrecognized hazards and references is also given.
Aqueous Alkaline Cleaners: An Alternative to Organic Solvents
1993-09-01
F021, F022, F023, F026, F027, F1028) Spent solvents (FOOl, F002, F003, F004, F005) July 8, 1987 California list wastes (Liquid hazardous wastes...installations and has been successful in developing a recycling program to reclaim spent Stoddard solvent and produce a material that meets Army specifications...metal parts it has cleaned. As the contamination level rises, it depletes the solvent’s effective cleaning power until the solvent becomes " spent
DOE Office of Scientific and Technical Information (OSTI.GOV)
Not Available
This is the RCRA required permit application for Radioactive and Hazardous Waste Management at the Oak Ridge Y-12 Plant for the following units: Building 9206 Container Storage Unit; Building 9212 Container Storage Unit; Building 9720-12 Container Storage Unit; Cyanide Treatment Unit. All four of these units are associated with the recovery of enriched uranium and other metals from wastes generated during the processing of nuclear materials.
Commercial Nuclear Steam-Electric Power Plants, Part II
ERIC Educational Resources Information Center
Shore, Ferdinand J.
1974-01-01
Presents the pros and cons of nuclear power systems. Includes a discussion of the institutional status of the AEC, AEC regulatory record, routine low-level radiation hazards, transport of radioactive materials, storage of wastes, and uranium resources and economics of supply. (GS)
Consonni, S; Giugliano, M; Grosso, M
2005-01-01
This two-part paper assesses four strategies for energy recovery from municipal solid waste (MSW) by dedicated waste-to-energy (WTE) plants generating electricity through a steam cycle. The feedstock is the residue after materials recovery (MR), assumed to be 35% by weight of the collected MSW. In strategy 1, the MR residue is fed directly to a grate combustor. In strategy 2, the MR residue is first subjected to light mechanical treatment. In strategies 3 and 4, the MR residue is converted into RDF, which is combusted in a fluidized bed combustor. To examine the relevance of scale, we considered a small waste management system (WMS) serving 200,000 people and a large WMS serving 1,200,000 people. A variation of strategy 1 shows the potential of cogeneration with district heating. The assessment is carried out by a Life Cycle Analysis where the electricity generated by the WTE plant displaces electricity generated by fossil fuel-fired steam plants. Part A focuses on mass and energy balances, while Part B focuses on emissions and costs. Results show that treating the MR residue ahead of the WTE plant reduces energy recovery. The largest energy savings are achieved by combusting the MR residue "as is" in large scale plants; with cogeneration, primary energy savings can reach 2.5% of total societal energy use.
Code of Federal Regulations, 2010 CFR
2010-01-01
... NUCLEAR REGULATORY COMMISSION STANDARDS FOR PROTECTION AGAINST RADIATION Pt. 20, App. G Appendix G to Part... Services, U.S. Nuclear Regulatory Commission, Washington, DC 20555-0001, telephone (301) 415-7232, or by... chapter. Special nuclear material has the same meaning as that given in § 70.4 of this chapter. Uniform...
Code of Federal Regulations, 2014 CFR
2014-01-01
... NUCLEAR REGULATORY COMMISSION STANDARDS FOR PROTECTION AGAINST RADIATION Pt. 20, App. G Appendix G to Part... Services, U.S. Nuclear Regulatory Commission, Washington, DC 20555-0001, telephone (301) 415-7232, or by... chapter. Special nuclear material has the same meaning as that given in § 70.4 of this chapter. Uniform...
Code of Federal Regulations, 2012 CFR
2012-01-01
... NUCLEAR REGULATORY COMMISSION STANDARDS FOR PROTECTION AGAINST RADIATION Pt. 20, App. G Appendix G to Part... Services, U.S. Nuclear Regulatory Commission, Washington, DC 20555-0001, telephone (301) 415-7232, or by... chapter. Special nuclear material has the same meaning as that given in § 70.4 of this chapter. Uniform...
Code of Federal Regulations, 2013 CFR
2013-01-01
... NUCLEAR REGULATORY COMMISSION STANDARDS FOR PROTECTION AGAINST RADIATION Pt. 20, App. G Appendix G to Part... Services, U.S. Nuclear Regulatory Commission, Washington, DC 20555-0001, telephone (301) 415-7232, or by... chapter. Special nuclear material has the same meaning as that given in § 70.4 of this chapter. Uniform...
Code of Federal Regulations, 2011 CFR
2011-01-01
... NUCLEAR REGULATORY COMMISSION STANDARDS FOR PROTECTION AGAINST RADIATION Pt. 20, App. G Appendix G to Part... Services, U.S. Nuclear Regulatory Commission, Washington, DC 20555-0001, telephone (301) 415-7232, or by... chapter. Special nuclear material has the same meaning as that given in § 70.4 of this chapter. Uniform...
Effective pine bark composting with the Dome Aeration Technology
DOE Office of Scientific and Technical Information (OSTI.GOV)
Trois, Cristina; Polster, Andreas
2007-07-01
In South Africa garden refuse is primarily disposed of in domestic landfills. Due to the large quantities generated, any form of treatment would be beneficial for volume reduction, waste stabilization and resource recovery. Dome Aeration Technology (DAT) is an advanced process for aerobic biological degradation of garden refuse and general waste [Paar, S., Brummack, J., Gemende, B., 1999a. Advantages of dome aeration in mechanical-biological waste treatment. In: Proceedings of the 7th International Waste Management and Landfill Symposium, Cagliari, 4-8 October 1999; Paar, S., Brummack, J., Gemende, B., 1999b. Mechanical-biological waste stabilization by the dome aeration method. Environment Protection Engineering 25more » (3/99). Mollekopf, N., Brummack, J., Paar, S., Vorster, K., 2002. Use of the Dome Aeration Technology for biochemical stabilization of waste prior to landfilling. In: Proceedings of the Wastecon 2002, Waste Congress and Exhibition, Durban, South Africa.]. It is a non-reactor open windrow composting process, with the main advantage being that the input material needs no periodic turning. A rotting time of only 3-4 months indicates the high efficiency. Additionally, the low capital/operational costs, low energy inputs and limited plant requirements provide potential for use in aerobic refuse stabilization. The innovation in the DAT process is the passive aeration achieved by thermally driven advection through open windrows caused by temperature differences between the degrading material and the outside environment. This paper investigates the application of Dome Aeration Technology to pine bark composting as part of an integrated waste management strategy. A full-scale field experiment was performed at the Bisasar Road Landfill Site in Durban to assess the influence of climate, waste composition and operational conditions on the process. A test windrow was constructed and measurements of temperature and airflow through the material were taken. The process monitoring revealed that prevailing climatic conditions in a subtropical location do not affect the high efficiency of this technology. However, the composition of the input material can be detrimental for production of high quality compost because of a lack of nitrate.« less
Determining the Level of Regulation for Hazardous Waste Recycling, Recycled Materials that are not Subject to RCRA Hazardous Waste Regulation, Materials Subject to Alternative Regulatory Controls, Materials Subject to Full Hazardous Waste Regulations.
Biochar as phosphorus transporter to support the closure of the phosphorus cycle
NASA Astrophysics Data System (ADS)
Soja, Gerhard; Jagerhofer, Reinhard; Fristak, Vladimir; Pfeifer, Christoph
2017-04-01
Waste materials rich in phosphorus could partly substitute rock phosphate-based mineral fertilizers. As rock phosphate is listed as critical raw material, measures for increasing the recovery rate of phosphorus and for closing the phosphorus cycle are required. However, direct use of the waste materials as fertilizers are frequently not possible because of legal constraints, adverse side effects because of co-occurring contaminants or hygienic concerns. So this study had the objective to test the appropriateness of carbonizing P-rich residues that can be used as secondary P resources for producing P fertilizers. The resulting biochar or hydrochar products should be tested for the bioavailability of P for plant uptake. Feedstock materials tested as secondary P resources were chicken manure, animal bone flour, sewage sludge, and digestates. These materials were either pyrolyzed at different temperatures, partly with different chemical modifications, or hydrothermally carbonized. The biochar and hydrochar products were analyzed for their total and available P concentrations, and the plant bioavailability was determined with a standardized plant growth test with rye (Neubauer-test). The results showed that biochar produced from a mixture of chicken manure and saw dust was equivalent to a standard phosphate fertilizer (superphosphate) with respect to P available for plant uptake. For most materials, a pyrolysis temperature of 400 °C was slightly more beneficial for P availability than 500 °C. Pyrolytic carbonization mostly was more supportive for plant growth than hydrothermal carbonization of the tested feedstocks. For some feedstocks the addition of sodium carbonate improved the P uptake of the plants without affecting the biomass production. The results show that P-rich waste materials used as secondary resources for carbonization can effectively contribute to increased P recovery, savings in the use of mineral phosphate fertilizers and reduced P loads to non-target ecosystems. Additionally, other benefits of biochar application to agricultural soils like carbon sequestration or improvements of physical soil characteristics may supplement the fertilizer effect of P-enriched biochars or hydrochars.
A novel bioconversion for value-added products from food waste using Musca domestica.
Niu, Yi; Zheng, Dong; Yao, Binghua; Cai, Zizhe; Zhao, Zhimin; Wu, Shengqing; Cong, Peiqing; Yang, Depo
2017-03-01
Food waste, as a major part of the municipal solid waste has been generated increasingly worldwide. Efficient and feasible utilization of this waste material for productivity process is significant for both economical and environmental reasons. In the present study, Musca domestica larva was used as the carrier to conduct a bioconversion with food waste to get the value-added maggot protein, oil and organic fertilizers. Methods of adult flies rearing, culture medium adjuvant selection, maggot culture conditions, stocking density and the valorization of the waste have been explored. From the experimental results, every 1000g culture mediums (700g food waste and 300g adjuvant) could be disposed by 1.5g M. domestica eggs under proper culture conditions after emergence in just 4days, 42.95±0.25% of which had been consumed and the culture medium residues could be used as good organic fertilizers, accompanying with the food waste consumption, ∼53.08g dried maggots that contained 57.06±2.19% protein and 15.07±2.03% oil had been produced. The maggot protein for its outstanding pharmacological activities is regarded as a good raw material in the field of medicine and animal feeding. Meanwhile, the maggot oil represents a potential alternative feedstock for biodiesel production. In our study, the maggot biodiesel was obtained after the procedure of transesterification reaction with methanol and the productivity was 87.71%. Copyright © 2016 Elsevier Ltd. All rights reserved.
Greenhouse gas accounting and waste management.
Gentil, Emmanuel; Christensen, Thomas H; Aoustin, Emmanuelle
2009-11-01
Accounting of emissions of greenhouse gas (GHG) is a major focus within waste management. This paper analyses and compares the four main types of GHG accounting in waste management including their special features and approaches: the national accounting, with reference to the Intergovernmental Panel on Climate Change (IPCC), the corporate level, as part of the annual reporting on environmental issues and social responsibility, life-cycle assessment (LCA), as an environmental basis for assessing waste management systems and technologies, and finally, the carbon trading methodology, and more specifically, the clean development mechanism (CDM) methodology, introduced to support cost-effective reduction in GHG emissions. These types of GHG accounting, in principle, have a common starting point in technical data on GHG emissions from specific waste technologies and plants, but the limited availability of data and, moreover, the different scopes of the accounting lead to many ways of quantifying emissions and producing the accounts. The importance of transparency in GHG accounting is emphasised regarding waste type, waste composition, time period considered, GHGs included, global warming potential (GWP) assigned to the GHGs, counting of biogenic carbon dioxide, choice of system boundaries, interactions with the energy system, and generic emissions factors. In order to enhance transparency and consistency, a format called the upstream-operating-downstream framework (UOD) is proposed for reporting basic technology-related data regarding GHG issues including a clear distinction between direct emissions from waste management technologies, indirect upstream (use of energy and materials) and indirect downstream (production of energy, delivery of secondary materials) activities.
Propelling plastics into the circular economy - weeding out the toxics first.
Leslie, H A; Leonards, P E G; Brandsma, S H; de Boer, J; Jonkers, N
2016-09-01
The Stockholm Convention bans toxic chemicals on its persistent organic pollutants (POPs) list in order to promote cleaner production and prevent POPs accumulation in the global environment. The original 'dirty dozen' set of POPs has been expanded to include some of the brominated diphenyl ether flame retardants (POP-BDEs). In addition to cleaner production, there is an urgent need for increased resource efficiency to address the finite amount of raw materials on Earth. Recycling plastic enhances resource efficiency and is part of the circular economy approach, but how clean are the materials we are recycling? With the help of a new screening method and detailed analyses, we set out to investigate where these largely obsolete BDEs were showing up in Dutch automotive and electronics waste streams, calculate mass flows and determine to what extent they are entering the new product chains. Our study revealed that banned BDEs and other toxic flame retardants are found at high concentrations in certain plastic materials destined for recycling markets. They were also found in a variety of new consumer products, including children's toys. A mass flow analysis showed that 22% of all the POP-BDE in waste electrical and electronic equipment (WEEE) is expected to end up in recycled plastics because these toxic, bioaccumulative and persistent substances are currently not effectively separated out of plastic waste streams. In the automotive sector, this is 14%, while an additional 19% is expected to end up in second-hand parts (reuse). These results raise the issue of delicate trade-offs between consumer safety/cleaner production and resource efficiency. As petroleum intensive materials, plastic products ought to be repaired, reused, remanufactured and recycled, making good use of the 'inner circles' of the circular economy. Keeping hazardous substances - whether they are well known POPs or emerging contaminants - out of products and plastic waste streams could make these cycles work better for businesses, people and nature. Copyright © 2016 Elsevier Ltd. All rights reserved.
Report: landfill alternative daily cover: conserving air space and reducing landfill operating cost.
Haughey, R D
2001-02-01
Title 40, Part 258 of the Code of Federal Regulations, Solid Waste Disposal Facility Criteria, commonly referred to as Subtitle D, became effective on October 9, 1993. It establishes minimum criteria for solid waste disposal facility siting, design, operations, groundwater monitoring and corrective action, and closure and postclosure maintenance, while providing EPA-approved state solid waste regulatory programs flexibility in implementing the criteria. Section 258.21(a) [40 CFR 258.21(a)] requires owners or operators of municipal solid waste landfill (MSWLF) units to cover disposed solid waste with 30cm of earthen material at the end of the operating day, or at more frequent intervals, if necessary, to control disease vectors, fires, odours, blowing litter, and scavenging. This requirement is consistent with already existing solid waste facility regulations in many states. For many MSWLFs, applying daily cover requires the importation of soil which increases landfill operating costs. Daily cover also uses valuable landfill air space, reducing potential operating revenue and the landfill's operating life. 40 CFR 258.21 (b) allows the director of an approved state to approve alternative materials of an alternative thickness if the owner or operator demonstrates that the alternative material and thickness will control disease vectors, fires, odours, blowing litter, and scavenging without presenting a threat to human health and the environment. Many different types of alternative daily cover (ADC) are currently being used, including geosynthetic tarps, foams, garden waste, and auto shredder fluff. These materials use less air space than soil and can reduce operating costs. This paper discusses the variety of ADCs currently being used around the country and their applicability to different climates and operating conditions, highlighting the more unusual types of ADC, the types of demonstrations necessary to obtain approval of ADC, and the impact on landfill air space and operating costs of ADC use.
Scientific Background for Processing of Aluminum Waste
NASA Astrophysics Data System (ADS)
Kononchuk, Olga; Alekseev, Alexey; Zubkova, Olga; Udovitsky, Vladimir
2017-11-01
Changing the source of raw materials for producing aluminum and the emergence of a huge number of secondary alumina waste (foundry slag, sludge, spent catalysts, mineral parts of coal and others that are formed in various industrial enterprises) require the creation of scientific and theoretical foundations for their processing. In this paper, the aluminum alloys (GOST 4784-97) are used as an aluminum raw material component, containing the aluminum component produced as chips in the machine-building enterprises. The aluminum waste is a whole range of metallic aluminum alloys including elements: magnesium, copper, silica, zinc and iron. Analysis of the aluminum waste A1- Zn-Cu-Si-Fe shows that depending on the content of the metal the dissolution process of an aluminum alloy should be treated as the result of the chemical interaction of the metal with an alkaline solution. It is necessary to consider the behavior of the main components of alloys in an alkaline solution as applied to the system Na2O - Al2O3 - SiO2 - CO2 - H2O.
Multimedia environmental management
DOE Office of Scientific and Technical Information (OSTI.GOV)
Soesilo, J.A.; Wiley, W.D.
1999-09-01
This book explores and supports the argument that effective environmental management must be based on a multimedia approach, which focuses simultaneously on air, water, and waste and enables managers to assess the resulting financial, operation, and management benefits. The multimedia approach, which can be used to design an effective compliance program, includes proper waste and material handling management, systematic monitoring, and record keeping requirements. This approach integrates a wide array of environmental requirements and decision processes, which the authors examine in sixteen chapters, organized into four parts: the role of environmental management; environmental aspects of business operation, environmental processes; andmore » environmental management trends. Within these parts, the authors highlight the development of modern environmental management and provide an overview of federal laws pertinent to multimedia environmental management. They examine such issues as chemical storage and transportation, tank system operations and requirements, waste determination, spill response procedures, and employee training. Environmental processes addressed in the book include the management of solid and hazardous waste, wastewater treatment systems, stormwater management, air emission control, and site remediation. The authors also briefly discuss significant initiatives in US environmental management and look toward corporate sustainable development.« less
10 CFR 60.3 - License required.
Code of Federal Regulations, 2010 CFR
2010-01-01
... REGULATORY COMMISSION (CONTINUED) DISPOSAL OF HIGH-LEVEL RADIOACTIVE WASTES IN GEOLOGIC REPOSITORIES General... byproduct material at a geologic repository operations area except as authorized by a license issued by the Commission pursuant to this part. (b) DOE shall not commence construction of a geologic repository operations...
77 FR 28406 - Spent Fuel Transportation Risk Assessment
Federal Register 2010, 2011, 2012, 2013, 2014
2012-05-14
... Regulations (10 CFR) part 71, ``Packaging and Transportation of Radioactive Waste,'' dated January 26, 2004) for the packaging and transport of spent nuclear fuel (and other large quantities of radioactive... NUREG- 0170, ``Final Environmental Statement on the Transportation of Radioactive Material by Air and...
MICROWAVE-ASSISTED EXTRACTION OF ORGANIC COMPOUNDS FROM STANDARD REFERENCE SOILS AND SEDIMENTS
As part of an ongoing evaluation of new sample preparation techniques by the U.S. Environmental Protection Agency (EPA), especially those that minimize waste solvents, microwave-assisted extraction (MAE) of organic compounds from solid materials (or "matrices") was evaluated. Six...
Kohfahl, Claus; Graupner, Torsten; Fetzer, Christian; Pekdeger, Asaf
2010-11-01
This article reports fibre-optic oxygen measurements on a reactive mine waste heap located in the polymetallic sulphide mine district of Freiberg in south-eastern Germany. The heaped material consists of sulphide-bearing tailings from a processing plant of a lead-zinc mine. Mine waste material was deposited in the water phase after separation of mining ores in a flotation process. The tailing impoundment is partly covered with coarse sand and topsoil. Oxygen profiles were monitored during one year at eleven locations showing different physical and mineralogical compositions. At each location a borehole was drilled where the optic sensors were installed at 2-5 different depths. After installation the oxygen profiles were monitored seven times during one year from 2006-2007 and three to five oxygen profiles at each location were obtained. Oxygen measurements were accompanied by physical, chemical and mineralogical data of the tailing material. Additionally, a detailed mineralogical profile was analysed at a location representative for the central part of the heap, where the cemented layers show lateral continuity. Results showed that cemented layers have a significant influence on natural attenuation of the toxic As and Pb species owing to their capacity of water retention. The measured oxygen profiles are controlled by the zone of active pyrite weathering as well as by the higher water content in the cemented layers which reduces gaseous atmospheric oxygen supply. In contrast, gypsum bearing hardpans detected at three other locations have no detectable influence on oxygen profiles. Furthermore, the grain size distribution was proved to have a major effect on oxygen diffusivity due to its control on the water saturation. Temporal changes of the oxygen profiles were only observed at locations with coarse sediment material indicating also an important advective part of gas flux. Copyright © 2010 Elsevier B.V. All rights reserved.
Incident Waste Decision Support Tool - Waste Materials ...
Report This is the technical documentation to the waste materials estimator module of I-WASTE. This document outlines the methodology and data used to develop the Waste Materials Estimator (WME) contained in the Incident Waste Decision Support Tool (I-WASTE DST). Specifically, this document reflects version 6.4 of the I-WASTE DST. The WME is one of four primary features of the I-WASTE DST. The WME is both a standalone calculator that generates waste estimates in terms of broad waste categories, and is also integrated into the Incident Planning and Response section of the tool where default inventories of specific waste items are provided in addition to the estimates for the broader waste categories. The WME can generate waste estimates for both common materials found in open spaces (soil, vegetation, concrete, and asphalt) and for a vast array of items and materials found in common structures.
Saryg-Ool, B Yu; Myagkaya, I N; Kirichenko, I S; Gustaytis, M A; Shuvaeva, O V; Zhmodik, S M; Lazareva, E V
2017-03-01
Migration and redistribution of elements during prolonged interaction of cyanide wastes with the underlying natural organic-bearing material have been studied in two ~40cm deep cores that sample primary ores and their weathering profile (wastes I and II, respectively) in the dispersion train of gold-bearing sulfide tailings in Siberia. Analytical results of SR-XRF, whole-rock XRF, AAS, CHNS, and SEM measurements of core samples show high K, Sr, Ti, and Fe enrichments and correlation of P 2 O 5 and Mn with LOI and C org . Organic material interlayered or mixed with the wastes accumulates Cu, Zn, Se, Cd, Ag, Au, and Hg. The peat that contacts wastes II bears up to 3wt.% Zn, 1000g/t Se, 100g/t Cd, and 8000g/t Hg. New phases of Zn and Hg sulfides and Hg selenides occur as abundant sheaths over bacterial cells suggesting microbial mediation in sorption of elements. Organic-bearing material in the cores contains 10-30g/t Au in 2-5cm thick intervals, both within and outside the intervals rich in sulfides and selenides. Most of gold is invisible but reaches 345g/t and forms 50nm to 1.5μm Au 0 particles in a thin 2-3cm interval of organic remnants mixed with wastes I. Vertical and lateral infiltration of AMD waters in peat and oxidative dissolution of wastes within the dispersion train of the Ursk tailings lead to redistribution of elements and their accumulation by combined physical (material's permeability, direction AMD), chemical (complexing, sorption by organic matter and Fe(III) hydroxides) and biochemical (metabolism of sulfate-reducing bacteria) processes. The accumulated elements form secondary sulfates, and Hg and Zn selenides. The results provide insights into accumulation of elements in the early history of coal and black shale deposits and have implications for remediation of polluted areas and for secondary enrichment technologies. Copyright © 2017 Elsevier B.V. All rights reserved.
Sustainable Materials Management: Non-Hazardous Materials and Waste Management Hierarchy
EPA developed the non-hazardous materials and waste management hierarchy in recognition that no single waste management approach is suitable for managing all materials and waste streams in all circumstances.
Treatment of halogen-containing waste and other waste materials
Forsberg, Charles W.; Beahm, Edward C.; Parker, George W.
1997-01-01
A process for treating a halogen-containing waste material. The process provides a bath of molten glass containing a sacrificial metal oxide capable of reacting with a halogen in the waste material. The sacrificial metal oxide is present in the molten glass in at least a stoichiometric amount with respect to the halogen in the waste material. The waste material is introduced into the bath of molten glass to cause a reaction between the halogen in the waste material and the sacrificial metal oxide to yield a metal halide. The metal halide is a gas at the temperature of the molten glass. The gaseous metal halide is separated from the molten glass and contacted with an aqueous scrubber solution of an alkali metal hydroxide to yield a metal hydroxide or metal oxide-containing precipitate and a soluble alkali metal halide. The precipitate is then separated from the aqueous scrubber solution. The molten glass containing the treated waste material is removed from the bath as a waste glass. The process of the invention can be used to treat all types of waste material including radioactive wastes. The process is particularly suited for separating halogens from halogen-containing wastes.
Treatment of halogen-containing waste and other waste materials
Forsberg, C.W.; Beahm, E.C.; Parker, G.W.
1997-03-18
A process is described for treating a halogen-containing waste material. The process provides a bath of molten glass containing a sacrificial metal oxide capable of reacting with a halogen in the waste material. The sacrificial metal oxide is present in the molten glass in at least a stoichiometric amount with respect to the halogen in the waste material. The waste material is introduced into the bath of molten glass to cause a reaction between the halogen in the waste material and the sacrificial metal oxide to yield a metal halide. The metal halide is a gas at the temperature of the molten glass. The gaseous metal halide is separated from the molten glass and contacted with an aqueous scrubber solution of an alkali metal hydroxide to yield a metal hydroxide or metal oxide-containing precipitate and a soluble alkali metal halide. The precipitate is then separated from the aqueous scrubber solution. The molten glass containing the treated waste material is removed from the bath as a waste glass. The process of the invention can be used to treat all types of waste material including radioactive wastes. The process is particularly suited for separating halogens from halogen-containing wastes. 3 figs.
Mathematics and Statistics Research Department progress report, period ending June 30, 1982
DOE Office of Scientific and Technical Information (OSTI.GOV)
Denson, M.V.; Funderlic, R.E.; Gosslee, D.G.
1982-08-01
This report is the twenty-fifth in the series of progress reports of the Mathematics and Statistics Research Department of the Computer Sciences Division, Union Carbide Corporation Nuclear Division (UCC-ND). Part A records research progress in analysis of large data sets, biometrics research, computational statistics, materials science applications, moving boundary problems, numerical linear algebra, and risk analysis. Collaboration and consulting with others throughout the UCC-ND complex are recorded in Part B. Included are sections on biology, chemistry, energy, engineering, environmental sciences, health and safety, materials science, safeguards, surveys, and the waste storage program. Part C summarizes the various educational activities inmore » which the staff was engaged. Part D lists the presentations of research results, and Part E records the staff's other professional activities during the report period.« less
Recovery of fissile materials from nuclear wastes
Forsberg, Charles W.
1999-01-01
A process for recovering fissile materials such as uranium, and plutonium, and rare earth elements, from complex waste feed material, and converting the remaining wastes into a waste glass suitable for storage or disposal. The waste feed is mixed with a dissolution glass formed of lead oxide and boron oxide resulting in oxidation, dehalogenation, and dissolution of metal oxides. Carbon is added to remove lead oxide, and a boron oxide fusion melt is produced. The fusion melt is essentially devoid of organic materials and halogens, and is easily and rapidly dissolved in nitric acid. After dissolution, uranium, plutonium and rare earth elements are separated from the acid and recovered by processes such as PUREX or ion exchange. The remaining acid waste stream is vitrified to produce a waste glass suitable for storage or disposal. Potential waste feed materials include plutonium scrap and residue, miscellaneous spent nuclear fuel, and uranium fissile wastes. The initial feed materials may contain mixtures of metals, ceramics, amorphous solids, halides, organic material and other carbon-containing material.
Review: Utilization of Waste From Coffee Production
NASA Astrophysics Data System (ADS)
Blinová, Lenka; Sirotiak, Maroš; Bartošová, Alica; Soldán, Maroš
2017-06-01
Coffee is one of the most valuable primary products in the world trade, and also a central and popular part of our culture. However, coffees production generate a lot of coffee wastes and by-products, which, on the one hand, could be used for more applications (sorbent for the removal of heavy metals and dyes from aqueous solutions, production of fuel pellets or briquettes, substrate for biogas, bioethanol or biodiesel production, composting material, production of reusable cups, substrat for mushroom production, source of natural phenolic antioxidants etc.), but, on the other hand, it could be a source of severe contamination posing a serious environmental problem. In this paper, we present an overview of utilising the waste from coffee production.
Dissolution and characterization of HEV NiMH batteries.
Larsson, Kristian; Ekberg, Christian; Ødegaard-Jensen, Arvid
2013-03-01
Metal recovery is an essential part of the recycling of hybrid electric vehicle battery waste and the first step in a hydrometallurgical treatment is dissolution of the solid material. The properties of separated battery electrode materials were investigated. Focus was put on both the solid waste and then the dissolution behaviour. The cathode contains metallic nickel that remains undissolved when utilizing non-oxidizing conditions such as hydrochloric or sulphuric acid in combination with a low oxygen atmosphere. In these conditions the cathode active electrode material is fully dissolved. Not dissolving the nickel metal saves up to 37% of the acid consumption for the cathode electrode material. In the commonly used case of oxidizing conditions the nickel metal dissolves and a cobalt-rich phase remains undissolved from the cathode active material. For the anode material a complete and rapid dissolution can be achieved at mild conditions with hydrochloric, nitric or sulphuric acid. Optimal parameters for all cases of dissolution was pH 1 with a reaction time of approximately ≥ 20,000 s. Copyright © 2012 Elsevier Ltd. All rights reserved.
The Role of Ceramics in a Resurgent Nuclear Industry
DOE Office of Scientific and Technical Information (OSTI.GOV)
Marra, J
2006-02-28
With fuel oil and natural gas prices near record highs and worldwide energy demands increasing at an alarming rate, there is growing interest in revitalization of the nuclear power industry within the United States and across the globe. Ceramic materials have long played a very important part in the commercial nuclear industry with applications throughout the entire fuel cycle; from fuel fabrication to waste stabilization. As the international community begins to look at advanced fuel cycles that minimize waste and increase proliferation resistance, ceramic materials will play an even larger role. Many of the advanced reactor concepts being evaluated operatemore » at high-temperature requiring the use of durable, heat-resistant materials. Ceramic fuels are being investigated for a variety of Generation IV reactor concepts. These include the traditional TRISO-coated particles as well as advanced inert-matrix fuels. In order to minimize wastes and legacy materials, ceramic processes are also being applied to fuel reprocessing operations. Ceramic materials continue to provide a vital contribution in ''closing the fuel cycle'' by stabilization of associated low-level and high-level wastes in highly durable grout, ceramics, and glass. In the next five years, programs that are currently in the conceptual phase will begin laboratory- and engineering-scale demonstrations. This will require production-scale demonstrations of several ceramic technologies from fuel form development to advanced stabilization methods. Within the next five to ten years, these demonstrations will move to even larger scales and will also include radioactive demonstrations of these advanced technologies. These radioactive demonstrations are critical to program success and will require advances in ceramic materials associated with nuclear energy applications.« less
Sustainable Approaches for Materials Management in Remote ...
Remote, economically challenged areas in the Commonwealth of the Northern Marianas Islands (CNMI) and American Samoa in the US Pacific island territories face unique challenges with respect to solid waste management. These islands are remote and isolated, with some islands supporting only small populations, thus limiting options for pooling resources among communities in the form of regional waste management facilities, as is common on the US mainland. This isolation also results in greater costs for waste management compared to those encountered in the mainland US, a consequence of, among other factors, more expensive construction and maintenance costs because of the necessary transport of facility components (e.g., landfill liner materials) and the decreased attractiveness of waste recovery for recycling because of lower commodity prices after off-island transportation. Adding to these economic limitations, the gross domestic product and per capita income of the Pacific territories is less than half what it is in parts of the US. The first section of this report outlines a snapshot of the current state of solid waste management overall in the US Pacific island territories, primarily based on site visits.. Steps involved in this work included a review of selected existing published information related to the subject; site visits to Guam, Saipan, Tinian, Rota, Tutuila, and Apia; an assessment of the technical and economic feasibility of different solid waste
DOE Office of Scientific and Technical Information (OSTI.GOV)
Smith, F.; Flach, G.
This report describes work performed by the Savannah River National Laboratory (SRNL) in fiscal year 2014 to develop a new Cementitious Barriers Project (CBP) software module designated as FLOExcel. FLOExcel incorporates a uniform database to capture material characterization data and a GoldSim model to define flow properties for both intact and fractured cementitious materials and estimate Darcy velocity based on specified hydraulic head gradient and matric tension. The software module includes hydraulic parameters for intact cementitious and granular materials in the database and a standalone GoldSim framework to manipulate the data. The database will be updated with new data asmore » it comes available. The software module will later be integrated into the next release of the CBP Toolbox, Version 3.0. This report documents the development efforts for this software module. The FY14 activities described in this report focused on the following two items that form the FLOExcel package; 1) Development of a uniform database to capture CBP data for cementitious materials. In particular, the inclusion and use of hydraulic properties of the materials are emphasized; and 2) Development of algorithms and a GoldSim User Interface to calculate hydraulic flow properties of degraded and fractured cementitious materials. Hydraulic properties are required in a simulation of flow through cementitious materials such as Saltstone, waste tank fill grout, and concrete barriers. At SRNL these simulations have been performed using the PORFLOW code as part of Performance Assessments for salt waste disposal and waste tank closure.« less
Ajayi, Saheed O; Oyedele, Lukumon O
2018-05-01
Albeit the understanding that construction waste is caused by activities ranging from all stages of project delivery process, research efforts have been concentrated on design and construction stages, while the possibility of reducing waste through materials procurement process is widely neglected. This study aims at exploring and confirming strategies for achieving waste-efficient materials procurement in construction activities. The study employs sequential exploratory mixed method approach as its methodological framework, using focus group discussion, statistical analysis and structural equation modelling. The study suggests that for materials procurement to enhance waste minimisation in construction projects, the procurement process would be characterised by four features. These include suppliers' commitment to low waste measures, low waste purchase management, effective materials delivery management and waste-efficient Bill of Quantity, all of which have significant impacts on waste minimisation. This implies that commitment of materials suppliers to such measures as take back scheme and flexibility in supplying small materials quantity, among others, are expected of materials procurement. While low waste purchase management stipulates the need for such measures as reduced packaging and consideration of pre-assembled/pre-cut materials, efficient delivery management entails effective delivery and storage system as well as adequate protection of materials during the delivery process, among others. Waste-efficient specification and bill of quantity, on the other hand, requires accurate materials take-off and ordering of materials based on accurately prepared design documents and bill of quantity. Findings of this study could assist in understanding a set of measures that should be taken during materials procurement process, thereby corroborating waste management practices at other stages of project delivery process. Copyright © 2018. Published by Elsevier Ltd.
40 CFR 227.13 - Dredged materials.
Code of Federal Regulations, 2011 CFR
2011-07-01
... by the U.S. Army Corps of Engineers using the criteria of applicable sections of parts 227 and 228... municipal or industrial wastes or by runoff from terrestrial sources such as agricultural lands. (b) Dredged... phase are those deemed critical by the District Engineer, after evaluating and considering any comments...
Code of Federal Regulations, 2012 CFR
2012-07-01
... analyses Acid filters Baghouse bags Clothing (e.g., coveralls, aprons, shoes, hats, gloves) Sweepings Air filter bags and cartridges Respiratory cartridge filters Shop abrasives Stacking boards Waste shipping... pallets Water treatment sludges, filter cakes, residues, and solids Emission control dusts, sludges...
Code of Federal Regulations, 2013 CFR
2013-07-01
... analyses Acid filters Baghouse bags Clothing (e.g., coveralls, aprons, shoes, hats, gloves) Sweepings Air filter bags and cartridges Respiratory cartridge filters Shop abrasives Stacking boards Waste shipping... pallets Water treatment sludges, filter cakes, residues, and solids Emission control dusts, sludges...
Code of Federal Regulations, 2014 CFR
2014-07-01
... analyses Acid filters Baghouse bags Clothing (e.g., coveralls, aprons, shoes, hats, gloves) Sweepings Air filter bags and cartridges Respiratory cartridge filters Shop abrasives Stacking boards Waste shipping... pallets Water treatment sludges, filter cakes, residues, and solids Emission control dusts, sludges...
Code of Federal Regulations, 2011 CFR
2011-07-01
... analyses Acid filters Baghouse bags Clothing (e.g., coveralls, aprons, shoes, hats, gloves) Sweepings Air filter bags and cartridges Respiratory cartridge filters Shop abrasives Stacking boards Waste shipping... pallets Water treatment sludges, filter cakes, residues, and solids Emission control dusts, sludges...
Code of Federal Regulations, 2010 CFR
2010-07-01
... analyses Acid filters Baghouse bags Clothing (e.g., coveralls, aprons, shoes, hats, gloves) Sweepings Air filter bags and cartridges Respiratory cartridge filters Shop abrasives Stacking boards Waste shipping... pallets Water treatment sludges, filter cakes, residues, and solids Emission control dusts, sludges...
This bench-scale study was conducted to evaluate the stabilization of mercury (Hg) and mercuric chloride-containing surrogate test materials by the chemically bonded phosphate ceramics technology. This study was performed as part of a U.S. EPA program to evaluate treatment and d...
78 FR 69531 - America Recycles Day, 2013
Federal Register 2010, 2011, 2012, 2013, 2014
2013-11-19
.... Recycling not only reduces pollution, but also saves energy, preserves valuable raw materials, and reduces... recycling a part of our daily lives. We should reuse or donate when possible, and recycle or compost as much as we are able. Students can get involved by championing waste-free lunches, recycling programs, and...
Modernization at the Y-12 National Security Complex: A Case for Additional Experimental Benchmarks
DOE Office of Scientific and Technical Information (OSTI.GOV)
Thornbury, Matthew
Electrorefining (ER) is a major part of efforts at the Y-12 National Security Complex to revolutionize the reprocessing and purification of enriched uranium (EU). Successful implementation of ER could drastically reduce the operational costs and footprint, hazardous materials use, and waste generation.
Improved method and composition for immobilization of waste in cement-based material
Tallent, O.K.; Dodson, K.E.; McDaniel, E.W.
1987-10-01
A composition and method for fixation or immobilization of aqueous hazardous waste material in cement-based materials (grout) is disclosed. The amount of drainable water in the cured grout is reduced by the addition of an ionic aluminum compound to either the waste material or the mixture of waste material and dry-solid cement- based material. This reduction in drainable water in the cured grout obviates the need for large, expensive amounts of gelling clays in grout materials and also results in improved consistency and properties of these cement-based waste disposal materials.
Underground waste barrier structure
Saha, Anuj J.; Grant, David C.
1988-01-01
Disclosed is an underground waste barrier structure that consists of waste material, a first container formed of activated carbonaceous material enclosing the waste material, a second container formed of zeolite enclosing the first container, and clay covering the second container. The underground waste barrier structure is constructed by forming a recessed area within the earth, lining the recessed area with a layer of clay, lining the clay with a layer of zeolite, lining the zeolite with a layer of activated carbonaceous material, placing the waste material within the lined recessed area, forming a ceiling over the waste material of a layer of activated carbonaceous material, a layer of zeolite, and a layer of clay, the layers in the ceiling cojoining with the respective layers forming the walls of the structure, and finally, covering the ceiling with earth.
Synthesis and Characterization of Thermoelectric Oxides at Macro- and Nano-scales
NASA Astrophysics Data System (ADS)
Ma, Feiyue
Thermoelectric materials can directly convert a temperature difference into electrical voltage and vice versa. Due to this unique property, thermoelectric materials are widely used in industry and scientific laboratories for temperature sensing and thermal management applications. Waste heat harvesting, another potential application of thermoelectric materials, has long been limited by the low conversion efficiency of the materials. Potential high temperature applications, such as power plant waste heat harvesting and combustion engine exhaust heat recovery, make thermoelectric oxides a very promising class of thermoelectric materials. In this thesis, the synthesis and characterization of thermoelectric oxide materials are explored. In the first part of this thesis, the measurement methodologies and instrumentation processes employed to investigate different thermoelectric properties, such as the Seebeck coefficient and carrier concentration at the bulk scale and the thermal conductivity at the nanoscale, are detailed. Existing scientific and engineering challenges associated with these measurements are also reviewed. To overcome such problems, original parts and methodologies have been designed. Three fully functional systems were ultimately developed for the characterization of macroscale thermoelectric properties as well as localized thermal conductivity. In the second part of the thesis, the synthesis of NaxCo 2O4, a thermoelectric oxide material, is discussed. Modification of both composition and structure were carried out so as to optimize the thermoelectric performance of NaxCo2O4. Nanostructuring methods, such as ball milling, electrospinning, auto-combustion synthesis, and core-shell structure fabrication, have been developed to refine the grain size of NaxCo2O4 in order to reduce its thermal conductivity. However, the structure of the nanostructured materials is very unstable at high temperature and limited improvement on thermoelectric performance is observed. Therefore, another technique was adopted to address this issue. A texturing process was also explored to optimize the NaxCo 2O4 structure. It was found that a highly textured structure can be obtained using a combined process of combustion synthesis, chemical demixing, and a flux method.
DOE Office of Scientific and Technical Information (OSTI.GOV)
NONE
1996-09-01
US DOE mixed low-level and mixed transuranic waste inventory was estimated at 181,000 cubic meters (about 2,000 waste streams). Treatability studies may be used as part of DOE`s mixed waste management program. Commercial treatability study suppliers have been identified that either have current capability in their own facilities or have access to licensed facilities. Numerous federal and state regulations, as well as DOE Order 5820.2A, impact the performance of treatability studies. Generators, transporters, and treatability study facilities are subject to regulation. From a mixed- waste standpoint, a key requirement is that the treatability study facility must have an NRC ormore » state license that allows it to possess radioactive materials. From a RCRA perspective, the facility must support treatability study activities with the applicable plans, reports, and documentation. If PCBs are present in the waste, TSCA will also be an issue. CERCLA requirements may apply, and both DOE and NRC regulations will impact the transportation of DOE mixed waste to an off-site treatment facility. DOE waste managers will need to be cognizant of all applicable regulations as mixed-waste treatability study programs are initiated.« less
Thermal valorization of post-consumer film waste in a bubbling bed gasifier.
Martínez-Lera, S; Torrico, J; Pallarés, J; Gil, A
2013-07-01
The use of plastic bags and film packaging is very frequent in manifold sectors and film waste is usually present in different sources of municipal and industrial wastes. A significant part of it is not suitable for mechanical recycling but could be safely transformed into a valuable gas by means of thermal valorization. In this research, the gasification of film wastes has been experimentally investigated through experiments in a fluidized bed reactor of two reference polymers, polyethylene and polypropylene, and actual post-consumer film waste. After a complete experimental characterization of the three materials, several gasification experiments have been performed to analyze the influence of the fuel and of equivalence ratio on gas production and composition, on tar generation and on efficiency. The experiments prove that film waste and analogue polymer derived wastes can be successfully gasified in a fluidized bed reactor, yielding a gas with a higher heating value in a range from 3.6 to 5.6 MJ/m3 and cold gas efficiencies up to 60%. Copyright © 2013 Elsevier Ltd. All rights reserved.
Status of electronic waste recycling techniques: a review.
Abdelbasir, Sabah M; Hassan, Saad S M; Kamel, Ayman H; El-Nasr, Rania Seif
2018-05-08
The increasing use of electrical and electronic equipment leads to a huge generation of electronic waste (e-waste). It is the fastest growing waste stream in the world. Almost all electrical and electronic equipment contain printed circuit boards as an essential part. Improper handling of these electronic wastes could bring serious risk to human health and the environment. On the other hand, proper handling of this waste requires a sound management strategy for awareness, collection, recycling, and reuse. Nowadays, the effective recycling of this type of waste has been considered as a main challenge for any society. Printed circuit boards (PCBs), which are the base of many electronic industries, are rich in valuable heavy metals and toxic halogenated organic substances. In this review, the composition of different PCBs and their harmful effects are discussed. Various techniques in common use for recycling the most important metals from the metallic fractions of e-waste are illustrated. The recovery of metals from e-waste material after physical separation through pyrometallurgical, hydrometallurgical, or biohydrometallurgical routes is also discussed, along with alternative uses of non-metallic fraction. The data are explained and compared with the current e-waste management efforts done in Egypt. Future perspectives and challenges facing Egypt for proper e-waste recycling are also discussed.
NASA Astrophysics Data System (ADS)
Buyantuev, S. L.; Urkhanova, L. A.; Kondratenko, A. S.; Shishulkin, S. Yu; Lkhasaranov, S. A.; Khmelev, A. B.
2017-01-01
The resultsare presented of plasma processing slag and ash waste from coal combustion in heating plants. Melting mechanism of ashand slagraw material is considered by an electromagnetic technological reactor. The analysis was conducted of temperature and phase transformations of raw material when it is heated up to the melting point, and also determination of specific energy consumption by using a generalized model of the thermodynamic analysis of TERRA. The study of materials melting temperature conditions and plum of melt was carried with high-temperature thermal imaging method, followed by mapping and 3D-modeling of the temperature fields. The investigations to establish the principal possibilities of using slag waste of local coal as raw material for the production of mineral (ash and slag) fibers found that by chemical composition there are oxides in the following ranges: 45-65% SiO2; 10-25% Al2O3; 10-45% CaO; 5-10% MgO; other minerals (less than 5%). Thus, these technological wastes are principally suitable for melts to produce mineral wool by the plasma method. An analysis of the results shows the melting point of ash and slag waste - 1800-2000 °C. In this case the specific energy consumption of these processes keeps within the limits of 1.1-1.3 kW*h/kg. For comparison it should be noted that the unit cost of electricity in the known high-melting industrial installations 5-6 kW*h/kg. Upon melting ash and slag waste, which contains up to 2-5% of unburned carbon, carbon nanomaterials were discovered.in the form of ultrafine soot accumulating as a plaque on the water-cooled surfaces in the gas cleaning chamber. The process of formation of soot consists in sublimation-desublimation of part of carbon which is in ash and slag, and graphite electrode. Thus, upon melting of ash and slag in the electromagnetic reactor it is possible to obtain melt, and in the subsequent mineral high quality fiber, which satisfies the requirements of normative documents, and simultaneously to receive a condensed product in the form of carbon sublimated nanoparticles, which can be found further use in construction materials, in particular in high-strength concrete and other materials.
Becquart, Frederic; Bernard, Fabrice; Abriak, Nor Edine; Zentar, Rachid
2009-04-01
Municipal solid waste incineration (MSWI) bottom ash is an atypical granular material because it may include industrial by-products that result from the incineration of domestic waste. The prospects for the beneficial use of this particular material mainly lie in the field of road construction, as a substitute for the traditional natural aggregates. However, its mechanical properties are still little known, particularly in term of stiffness and deformability, characteristics that are essential to the construction of a durable roadway. The purpose of this paper is to describe better the mechanical behaviour of this recycled material. In order to reach this objective, a large experimental campaign is presented. The first part of this paper presents and comments in detail on the results obtained from static monotonic tests. Oedometric and triaxial shear tests were performed on MSWI bottom ash both before and after treatment with a specific hydraulic binder. These tests allow specification of the mechanical characteristics of the MSWI bottom ash, such as the initial Young's modulus, Poisson's ratio, the compressibility index, the friction angle, and the contracting or dilating behaviour of the material. The results reveal a mechanical behaviour similar to that of initially dense standard materials (sands, unbound granular materials) and a dependence on the applied average pressure, characteristic of the mechanical behaviour of granular media. More laboratory data on other samples of MSWI bottom ash are required to ensure that this comparison is statistically valid.
Cumulative metal leaching from utilisation of secondary building materials in river engineering.
Leuven, R S E W; Willems, F H G
2004-01-01
The present paper estimates the utilisation of bulky wastes (minestone, steel slag, phosphorus slag and demolition waste) in hydraulic engineering structures in Dutch parts of the rivers Rhine, Meuse and Scheldt over the period 1980-2025. Although they offer several economic, technical and environmental benefits, these secondary building materials contain various metals that may leach into river water. A leaching model was used to predict annual emissions of arsenic, cadmium, copper, chromium, lead, mercury, nickel and zinc. Under the current utilisation and model assumptions, the contribution of secondary building materials to metal pollution in Dutch surface waters is expected to be relatively low compared to other sources (less than 0.1% and 0.2% in the years 2000 and 2025, respectively). However, continued and widespread large-scale applications of secondary building materials will increase pollutant leaching and may require further cuts to be made in emissions from other sources to meet emission reduction targets and water quality standards. It is recommended to validate available leaching models under various field conditions. Complete registration of secondary building materials will be required to improve input data for leaching models.
DOE Office of Scientific and Technical Information (OSTI.GOV)
Neeway, James J.; Pierce, Eric M.; Freedman, Vicky L.
2014-08-04
The federal facilities located on the Hanford Site in southeastern Washington State have been used extensively by the U.S. government to produce nuclear materials for the U.S. strategic defense arsenal. Currently, the Hanford Site is under the stewardship of the U.S. Department of Energy (DOE) Office of Environmental Management (EM). A large inventory of radioactive and mixed waste resulting from the production of nuclear materials has accumulated, mainly in 177 underground single- and double-shell tanks located in the central plateau of the Hanford Site (Mann et al., 2001). The DOE-EM Office of River Protection (ORP) is proceeding with plans tomore » immobilize and permanently dispose of the low-activity waste (LAW) fraction onsite in a shallow subsurface disposal facility (the Integrated Disposal Facility [IDF]). Pacific Northwest National Laboratory (PNNL) was contracted to provide the technical basis for estimating radionuclide release from the engineered portion of the IDF (the source term) as part of an immobilized low-activity waste (ILAW) glass testing program to support future IDF performance assessments (PAs).« less
Coulthard, E. James
1994-01-01
An infectious waste feed system for comminuting infectious waste and feeding the comminuted waste to a combustor automatically without the need for human intervention. The system includes a receptacle for accepting waste materials. Preferably, the receptacle includes a first and second compartment and a means for sealing the first and second compartments from the atmosphere. A shredder is disposed to comminute waste materials accepted in the receptacle to a predetermined size. A trough is disposed to receive the comminuted waste materials from the shredder. A feeding means is disposed within the trough and is movable in a first and second direction for feeding the comminuted waste materials to a combustor.
Bio-Refineries Bioprocess Technologies for Waste-Water Treatment, Energy and Product Valorization
NASA Astrophysics Data System (ADS)
Keith Cowan, A.
2010-04-01
Increasing pressure is being exerted on communities and nations to source energy from forms other than fossil fuels. Also, potable water is becoming a scarce resource in many parts of the world, and there remains a large divide in the demand and utilization of plant products derived from genetically modified organisms (GMOs) and non-GMOs. The most extensive user and manager of terrestrial ecosystems is agriculture which is also the de facto steward of natural resources. As stated by Miller (2008) no other industry or institution comes close to the comparative advantage held for this vital responsibility while simultaneously providing food, fiber, and other biology-based products, including energy. Since modern commercial agriculture is transitioning from the production of bulk commodities to the provision of standardized products and specific-attribute raw materials for differentiated markets, we can argue that processes such as mass cultivation of microalgae and the concept of bio-refineries be seen as part of a `new' agronomy. EBRU is currently exploring the integration of bioprocess technologies using microalgae as biocatalysts to achieve waste-water treatment, water polishing and endocrine disruptor (EDC) removal, sustainable energy production, and exploitation of the resultant biomass in agriculture as foliar fertilizer and seed coatings, and for commercial extraction of bulk commodities such as bio-oils and lecithin. This presentation will address efforts to establish a fully operational solar-driven microalgae bio-refinery for use not only in waste remediation but to transform waste and biomass to energy, fuels, and other useful materials (valorisation), with particular focus on environmental quality and sustainability goals.
Unirradiated testing of the demonstration-scale ceramic waste form at ANL-West
DOE Office of Scientific and Technical Information (OSTI.GOV)
Goff, K.M.; Simpson, M.F.; Bateman, K.J.
1997-12-01
The ceramic waste form is being developed by Argonne National Laboratory (ANL) as part of the demonstration of the electrometallurgical treatment of spent nuclear fuel for disposal. The alkali, alkaline earth, halide, and rare earth fission products are stabilized in zeolite, which is combined with glass and processed in a hot isostatic press (HIP) to form a ceramic composite. The transuranics, including plutonium, are also stabilized in this high-level waste. Most of the laboratory-scale development work is performed in the Chemical Technology Division of ANL in Illinois. At ANL-West in Idaho, this technology is being demonstrated on an engineering scalemore » before implementation with irradiated materials in a remote environment.« less
A review on automated sorting of source-separated municipal solid waste for recycling.
Gundupalli, Sathish Paulraj; Hait, Subrata; Thakur, Atul
2017-02-01
A crucial prerequisite for recycling forming an integral part of municipal solid waste (MSW) management is sorting of useful materials from source-separated MSW. Researchers have been exploring automated sorting techniques to improve the overall efficiency of recycling process. This paper reviews recent advances in physical processes, sensors, and actuators used as well as control and autonomy related issues in the area of automated sorting and recycling of source-separated MSW. We believe that this paper will provide a comprehensive overview of the state of the art and will help future system designers in the area. In this paper, we also present research challenges in the field of automated waste sorting and recycling. Copyright © 2016 Elsevier Ltd. All rights reserved.
From waste to sustainable materials management: Three case studies of the transition journey.
Silva, Angie; Rosano, Michele; Stocker, Laura; Gorissen, Leen
2017-03-01
Waste policy is increasingly moving on from the 'prevention of waste' to a 'sustainable materials policy' focused agenda recognising individual wastes as a resource. In order to comparatively analyse policy developments in enhanced waste management, three case studies were selected; San Francisco's Zero Waste Program, Flanders's Sustainable Materials Management Initiative and Japan's Sound Material-Cycle Society Plan. These case studies were chosen as an opportunity to investigate the variety of leading approaches, governance structures, and enhanced waste policy outcomes, emerging globally. This paper concludes that the current transitional state of waste management across the world, is only in the first leg of the journey towards Circular Economy closed loop production models of waste as a resource material. It is suggested that further development in government policy, planning and behaviour change is required. A focus on material policy and incorporating multiple front runners across industry and knowledge institutions are offered as potential directions in the movement away from end-pipe land-fill solutions. Copyright © 2016 Elsevier Ltd. All rights reserved.
Infrared analysis of clay bricks incorporated with spent shea waste from the shea butter industry.
Adazabra, A N; Viruthagiri, G; Shanmugam, N
2017-04-15
The peculiar challenge of effective disposing abundant spent shea waste and the excellent compositional variation tolerance of clay material offered an impetus to examine the incorporation of spent shea waste into clay material as an eco-friendly disposal route in making clay bricks. For this purpose, the chemical constituent, mineralogical compositions and thermal behavior of both clay material and spent shea waste were initially characterized from which modelled brick specimens incorporating 5-20 wt% of the waste into the clay material were prepared. The clay material showed high proportions of SiO 2 (52.97 wt%) and Al 2 O 3 (27.10 wt%) indicating their rich kaolinitic content: whereas, the inert nature of spent shea waste was exhibited by their low oxide content. The striking similarities in infrared absorption bands of pristine clay material and clay materials incorporated with 15 wt% of spent shea waste showed that the waste incorporation had no impact on bond formation of the clay bricks. Potential performance benefits of developing bricks from clay material incorporated with spent shea waste included improved fluxing agents, economic sintering and making of sustainable bricks. Consequently, the analytical results authenticate the incorporation of spent shea waste into clay materials for various desired benefits aside being an environmental correct route of its disposal. Copyright © 2017 Elsevier Ltd. All rights reserved.
Nuclear Waste Disposal and Strategies for Predicting Long-Term Performance of Material
DOE Office of Scientific and Technical Information (OSTI.GOV)
Wicks, G G
2001-03-28
Ceramics have been an important part of the nuclear community for many years. On December 2, 1942, an historic event occurred under the West Stands of Stagg Field, at the University of Chicago. Man initiated his first self-sustaining nuclear chain reaction and controlled it. The impact of this event on civilization is considered by many as monumental and compared by some to other significant events in history, such as the invention of the steam engine and the manufacturing of the first automobile. Making this event possible and the successful operation of this first man-made nuclear reactor, was the use ofmore » forty tons of UO2. The use of natural or enriched UO2 is still used today as a nuclear fuel in many nuclear power plants operating world-wide. Other ceramic materials, such as 238Pu, are used for other important purposes, such as ceramic fuels for space exploration to provide electrical power to operate instruments on board spacecrafts. Radioisotopic Thermoelectric Generators (RTGs) are used to supply electrical power and consist of a nuclear heat source and converter to transform heat energy from radioactive decay into electrical power, thus providing reliable and relatively uniform power over the very long lifetime of a mission. These sources have been used in the Galileo spacecraft orbiting Jupiter and for scientific investigations of Saturn with the Cassini spacecraft. Still another very important series of applications using the unique properties of ceramics in the nuclear field, are as immobilization matrices for management of some of the most hazardous wastes known to man. For example, in long-term management of radioactive and hazardous wastes, glass matrices are currently in production immobilizing high-level radioactive materials, and cementious forms have also been produced to incorporate low level wastes. Also, as part of nuclear disarmament activities, assemblages of crystalline phases are being developed for immobilizing weapons grade plutonium, to not only produce environmentally friendly products, but also forms that are proliferation resistant. All of these waste forms as well as others, are designed to take advantage of the unique properties of the ceramic systems.« less
Marchaim, U; Gelman, A; Braverman, Y
2003-01-01
There is currently no market in Israel for the large amounts of waste from fish- and poultry-processing plants. Therefore, this waste is incinerated, as part of the measures to prevent the spread of pathogens. Anaerobic methanogenic thermophilic fermentation (AMTF) of wastes from the cattle-slaughtering industry was examined previously, as an effective system to treat pathogenic bacteria, and in this article, we discuss a combined method of digestion by thermophilic anaerobic bacteria and by flesh flies, as a means of waste treatment. The AMTF process was applied to the wastes on a laboratory scale, and digestion by rearing of flesh fly (Phaenicia sericata) and housefly (Musca domestica) larvae on the untreated raw material was done on a small scale and showed remarkable weight conversion to larvae. The yield from degradation of poultry waste by flesh fly was 22.47% (SD = 3.89) and that from fish waste degradation was 35.34% (SD = 12.42), which is significantly higher than that from rearing houseflies on a regular rearing medium. Bacterial contents before and after thermophilic anaerobic digestion, as well as the changes in the chemical composition of the components during the rearing of larvae, were also examined.
29 CFR 1926.252 - Disposal of waste materials.
Code of Federal Regulations, 2014 CFR
2014-07-01
... fire regulations. (e) All solvent waste, oily rags, and flammable liquids shall be kept in fire... 29 Labor 8 2014-07-01 2014-07-01 false Disposal of waste materials. 1926.252 Section 1926.252..., Use, and Disposal § 1926.252 Disposal of waste materials. (a) Whenever materials are dropped more than...
NASA Astrophysics Data System (ADS)
Teipel, Elisa
Rural communities in developing countries are most vulnerable to the plight of requiring repeated infusions of charitable aid over time. Micro-business opportunities that effectively break the cycle of poverty in resource-rich countries in the developing world are limited. However, a strong model for global commerce can break the cycle of donor-based economic supplements and limited local economic growth. Sustainable economic development can materialize when a robust framework combines engineering with the generous investment of profits back into the community. This research presents a novel, systems-based approach to sustainable community development in which a waste-to-resource methodology catalyzes the disruption of rural poverty. The framework developed in this thesis was applied to the rural communities of Cagmanaba and Badian, Philippines. An initial assessment of these communities showed that community members are extremely poor, but they possess an abundant natural resource: coconuts. The various parts of the coconut offer excellent potential value in global commerce. Today the sale of coconut water is on the rise, and coconut oil is an established $3 billion market annually that is also growing rapidly. Since these current industries harvest only two parts of the coconut (meat and water), the 50 billion coconuts that grow annually leave behind approximately 100 billion pounds of coconut shell and husk as agricultural waste. Coconuts thus provide an opportunity to create and test a waste-to-resource model. Intensive materials analysis, research, development, and optimization proved that coconut shell, currently burned as a fuel or discarded as agricultural waste, can be manufactured into high-grade coconut shell powder (CSP), which can be a viable filler in polymeric composites. This framework was modeled and tested as a case study in a manufacturing facility known as a Community Transformation Plant (CTP) in Cagmanaba, Philippines. The CTP enables local creation of globally viable products from agricultural waste. This researcher seeks to encourage the propagation of CTPs throughout developing communities worldwide, each profiting from its own waste-to-resource value.
Federal Register 2010, 2011, 2012, 2013, 2014
2011-04-29
... materials with a lignocellulosic component such as cellulose, including wood, sawdust, paper mill waste and..., and Affirmative Critical Circumstances, In Part: Certain Lined Paper Products From the People's.... \\29\\ See id. \\30\\ See, e.g., Final Results of Antidumping Duty Administrative Review: Petroleum Wax...
ERIC Educational Resources Information Center
Ohio State Univ., Columbus. National Center for Research in Vocational Education.
This military-developed text contains the final section of a four-part course to train environmental support specialists. Covered in the individual course blocks are maintenance of water and waste processing system components (external corrosion control, cathodic protection, drive equipment, pipelines and valves, meters and recorders, chemical…
40 CFR 440.104 - New source performance standards (NSPS).
Code of Federal Regulations, 2014 CFR
2014-07-01
..., in-situ leach or vat-leach processes to extract copper from ores or ore waste materials. The Agency... provided in subpart L of this part any new source subject to this subsection must achieve the following... demonstrated technology (BADT): (a) The concentration of pollutants discharged in mine drainage from mines that...
40 CFR 440.104 - New source performance standards (NSPS).
Code of Federal Regulations, 2012 CFR
2012-07-01
..., in-situ leach or vat-leach processes to extract copper from ores or ore waste materials. The Agency... provided in subpart L of this part any new source subject to this subsection must achieve the following... demonstrated technology (BADT): (a) The concentration of pollutants discharged in mine drainage from mines that...
ERIC Educational Resources Information Center
Cole, Charles A.
The rehabilitation of existing on-site wastewater treatment facilities is often the best approach to meeting waste disposal needs. Upon completing the learning session described in this instructor's guide, participants should understand the technology and treatment methods for low-volume wastewater flows. These materials are part of the Working…
Industrial waste materials and by-products as thermal energy storage (TES) materials: A review
NASA Astrophysics Data System (ADS)
Gutierrez, Andrea; Miró, Laia; Gil, Antoni; Rodríguez-Aseguinolaza, Javier; Barreneche, Camila; Calvet, Nicolas; Py, Xavier; Fernández, A. Inés; Grágeda, Mario; Ushak, Svetlana; Cabeza, Luisa F.
2016-05-01
A wide variety of potential materials for thermal energy storage (TES) have been identify depending on the implemented TES method, Sensible, latent or thermochemical. In order to improve the efficiency of TES systems more alternatives are continuously being sought. In this regard, this paper presents the review of low cost heat storage materials focused mainly in two objectives: on the one hand, the implementation of improved heat storage devices based on new appropriate materials and, on the other hand, the valorisation of waste industrial materials will have strong environmental, economic and societal benefits such as reducing the landfilled waste amounts, reducing the greenhouse emissions and others. Different industrial and municipal waste materials and by products have been considered as potential TES materials and have been characterized as such. Asbestos containing wastes, fly ashes, by-products from the salt industry and from the metal industry, wastes from recycling steel process and from copper refining process and dross from the aluminium industry, and municipal wastes (glass and nylon) have been considered. This work shows a great revalorization of wastes and by-product opportunity as TES materials, although more studies are needed to achieve industrial deployment of the idea.
Yang, Deming; Xu, Zhenming
2011-09-15
Crushing and separating technology is widely used in waste printed circuit boards (PCBs) recycling process. A set of automatic line without negative impact to environment for recycling waste PCBs was applied in industry scale. Crushed waste PCBs particles grinding and classification cyclic system is the most important part of the automatic production line, and it decides the efficiency of the whole production line. In this paper, a model for computing the process of the system was established, and matrix analysis method was adopted. The result showed that good agreement can be achieved between the simulation model and the actual production line, and the system is anti-jamming. This model possibly provides a basis for the automatic process control of waste PCBs production line. With this model, many engineering problems can be reduced, such as metals and nonmetals insufficient dissociation, particles over-pulverizing, incomplete comminuting, material plugging and equipment fever. Copyright © 2011 Elsevier B.V. All rights reserved.
Life cycle assessment of a national policy proposal - the case of a Swedish waste incineration tax.
Björklund, Anna E; Finnveden, Göran
2007-01-01
At the core of EU and Swedish waste policy is the so-called waste hierarchy, according to which waste should first be prevented, but should otherwise be treated in the following order of prioritisation: reuse, recycling when environmentally motivated, energy recovery, and last landfilling. Some recent policy decisions in Sweden aim to influence waste management in the direction of the waste hierarchy. In 2001 a governmental commission assessed the economic and environmental impacts of introducing a weight-based tax on waste incineration, the purpose of which would be to encourage waste reduction and increase materials recycling and biological treatment. This paper presents the results of a life cycle assessment (LCA) of the waste incineration tax proposal. It was done in the context of a larger research project concerning the development and testing of a framework for Strategic Environmental Assessment (SEA). The aim of this paper is to assess the life cycle environmental impacts of the waste incineration tax proposal, and to investigate whether there are any possibilities of more optimal design of such a tax. The proposed design of the waste incineration tax results in increased recycling, but only in small environmental improvements. A more elaborate tax design is suggested, in which the tax level would partly be related to the fossil carbon content of the waste.
NASA Astrophysics Data System (ADS)
Hamzah, Mohamad Hazmi; Deraman, Rafikullah; Saman, Nor Sarwani Mat
2017-12-01
In Malaysia, 45% of the average household electricity was consumed by air conditioners to create an acceptable indoor environment. This high energy consumption was mostly related to poor thermal performance of the building envelope. Therefore, selecting a low thermal conductivity of brick wall was of considerable importance in creating energy efficient buildings. Previously, numerous researchers reported the potential used of agricultural waste as an additive in building materials to enhance their thermal properties. The aim of this study is to examine how agricultural wastes from empty fruit bunch (EFB), coconut fibre (CF) and sugarcane bagasse (SB) can act as additive agents in a fired clay brick manufacturing process to produce a low thermal conductivity clay brick. In this study, these agricultural wastes were individually mixed with clay soil in different proportions ranging from 0%, 2.5%, 5%, 7.5% and 10% by weight. Physical and mechanical properties including soil physical properties, as well as thermal conductivity were performed in accordance with BS 1377: Part 2: 1990, BS 3921: 1985 and ASTM C518. The results reveal that incorporating 5% of EFB as an additive component into the brick making process significantly enhances the production of a low thermal conductivity clay brick as compared to other waste alternatives tested. This finding suggests that EFB waste was a potential additive material to be used for the thermal property enhancement of the building envelope.
Pollution level and reusability of the waste soil generated from demolition of a rural railway.
Han, Il; Wee, Gui Nam; No, Jee Hyun; Lee, Tae Kwon
2018-09-01
Railways are typically considered polluted from years of train operation. However, the pollution level of railway in a rural area, which is less exposed to hazardous material from trains and freights, is rarely assessed. This study evaluated common railway pollutants such as heavy metals, total petroleum hydrocarbons (TPHs) and polycyclic aromatic hydrocarbons (PAHs) and their chemical properties in the waste soil generated from the renovation of an old railway in rural area of Wonju, South Korea. Furthermore, lab-scale cultivation tests of peas (Pisum sativum) were performed to assess reusability of the waste soil as a soil amendment. Carbonaceous materials were found in the upper layer of the railway (0 to -40 cm) and the concentration of common railway pollutants was comparable to those of the agricultural land nearby. Specifically, total aromatic and aliphatic TPHs were below detection limit; and total PAHs < 1.0 mg kg -1 was 1000-times less than railway functional parts. Applying the carbonaceous waste soil improved the water holding capacity of soil by approximately 10% and sprouts formed on the soil with 10% waste soil composition had greater fresh weight, stem length, and root length than the control. Although this investigation was confined to a small length of the railway route, the results confirm environmental safety and the potential value of the waste generated from rural railways for the first time. Copyright © 2018 Elsevier Ltd. All rights reserved.
Screening tests for hazard classification of complex waste materials - Selection of methods
DOE Office of Scientific and Technical Information (OSTI.GOV)
Weltens, R., E-mail: reinhilde.weltens@vito.be; Vanermen, G.; Tirez, K.
In this study we describe the development of an alternative methodology for hazard characterization of waste materials. Such an alternative methodology for hazard assessment of complex waste materials is urgently needed, because the lack of a validated instrument leads to arbitrary hazard classification of such complex waste materials. False classification can lead to human and environmental health risks and also has important financial consequences for the waste owner. The Hazardous Waste Directive (HWD) describes the methodology for hazard classification of waste materials. For mirror entries the HWD classification is based upon the hazardous properties (H1-15) of the waste which canmore » be assessed from the hazardous properties of individual identified waste compounds or - if not all compounds are identified - from test results of hazard assessment tests performed on the waste material itself. For the latter the HWD recommends toxicity tests that were initially designed for risk assessment of chemicals in consumer products (pharmaceuticals, cosmetics, biocides, food, etc.). These tests (often using mammals) are not designed nor suitable for the hazard characterization of waste materials. With the present study we want to contribute to the development of an alternative and transparent test strategy for hazard assessment of complex wastes that is in line with the HWD principles for waste classification. It is necessary to cope with this important shortcoming in hazardous waste classification and to demonstrate that alternative methods are available that can be used for hazard assessment of waste materials. Next, by describing the pros and cons of the available methods, and by identifying the needs for additional or further development of test methods, we hope to stimulate research efforts and development in this direction. In this paper we describe promising techniques and argument on the test selection for the pilot study that we have performed on different types of waste materials. Test results are presented in a second paper. As the application of many of the proposed test methods is new in the field of waste management, the principles of the tests are described. The selected tests tackle important hazardous properties but refinement of the test battery is needed to fulfil the a priori conditions.« less
Waste Printed Circuit Board (PCB) Recycling Techniques.
Ning, Chao; Lin, Carol Sze Ki; Hui, David Chi Wai; McKay, Gordon
2017-04-01
With the development of technologies and the change of consumer attitudes, the amount of waste electrical and electronic equipment (WEEE) is increasing annually. As the core part of WEEE, the waste printed circuit board (WPCB) is a dangerous waste but at the same time a rich resource for various kinds of materials. In this work, various WPCB treatment methods as well as WPCB recycling techniques divided into direct treatment (landfill and incineration), primitive recycling technology (pyrometallurgy, hydrometallurgy, biometallurgy and primitive full recovery of NMF-non metallic fraction), and advanced recycling technology (mechanical separation, direct use and modification of NMF) are reviewed and analyzed based on their advantages and disadvantages. Also, the evaluation criteria are discussed including economic, environmental, and gate-to-market ability. This review indicates the future research direction of WPCB recycling should focus on a combination of several techniques or in series recycling to maximize the benefits of process.
The upcycling of post-industrial PP/PET waste streams through in-situ microfibrillar preparation
NASA Astrophysics Data System (ADS)
Delva, Laurens; Ragaert, Kim; Cardon, Ludwig
2015-12-01
Post-industrial plastic waste streams can be re-used as secondary material streams for polymer processing by extrusion or injection moulding. One of the major commercially available waste stream contains polypropylene (PP) contaminated with polyesters (mostly polyethylene tereftalate - PET). An important practical hurdle for the direct implementation of this waste stream is the immiscibility of PP and PET in the melt, which leads to segregation within the polymer structure and adversely affects the reproducibility and mechanical properties of the manufactured parts. It has been indicated in literature that the creation of PET microfibrils in the PP matrix could undo these drawbacks and upcycle the PP/PET combination. Within the current research, a commercially available virgin PP/PET was evaluated for the microfibrillar preparation. The mechanical (tensile and impact) properties, thermal properties and morphology of the composites were characterized at different stages of the microfibrillar preparation.
Consonni, Stefano; Viganò, Federico
2011-01-01
This article is part of a set of six coordinated papers reporting the main findings of a research project carried out by five Italian universities on "Material and energy recovery in Integrated Waste Management Systems (IWMS)". An overview of the project and a summary of the most relevant results can be found in the introductory article of the series. This paper describes the work related to the evaluation of mass and energy balances, which has consisted of three major efforts (i) development of a model for quantifying the energy content and the elemental compositions of the waste streams appearing in a IWMS; (ii) upgrade of an earlier model to predict the performances of Waste-to-Energy (WtE) plants; (iii) evaluation of mass and energy balances of all the scenarios and the recovery paths considered in the project. Results show that not only the amount of material available for energy recovery is significantly higher than the Unsorted Residual Waste (URW) left after Separate Collection (SC), because selection and recycling generate significant amounts of residues, but its heating value is higher than that of the original, gross waste. Therefore, the energy potential of what is left after recycling is always higher than the complement to 100% of the Source Separation Level (SSL). Also, increasing SSL has marginal effects on the potential for energy recovery: nearly doubling SSL (from 35% to 65%) reduces the energy potential only by one fourth. Consequently, even at high SSL energy recovery is a fundamental step of a sustainable waste management system. Variations of SSL do bring about variations of the composition, heating value and moisture content of the material fed to WtE plants, but these variations (i) are smaller than one can expect; (ii) have marginal effects on the performances of the WtE plant. These considerations suggest that the mere value of SSL is not a good indicator of the quality of the waste management system, nor of its energy and environmental outcome. Given the well-known dependence of the efficiency of steam power plants with their power output, the efficiency of energy recovery crucially depends on the size of the IWMS served by the WtE plant. A fivefold increase of the amount of gross waste handled in the IWMS (from 150,000 to 750,000 tons per year of gross waste) allows increasing the electric efficiencies of the WtE plant by about 6-7 percentage points (from 21-23% to 28.5% circa). Copyright © 2011 Elsevier Ltd. All rights reserved.
NASA Astrophysics Data System (ADS)
Fidlerová, Helena; Mĺkva, Miroslava
2016-06-01
Reverse logistics, the movement of materials back up the supply chain, is recognised by many organisations as an opportunity for adding value. The paper considers the theoretical framework and the conception of reverse logistics in literature and practice. The objective of the article is to propose tangible solutions which eliminate the imbalances in reverse logistics and improve the waste management in the company. The case study focuses on the improvement in the process of waste packaging in the context of sustainable development as a part of reverse logistics in the surveyed industrial company in Slovakia.
Götze, R; Pivnenko, K; Boldrin, A; Scheutz, C; Astrup, T Fruergaard
2016-08-01
Physico-chemical waste composition data are paramount for the assessment and planning of waste management systems. However, the applicability of data is limited by the regional, temporal and technical scope of waste characterisation studies. As Danish and European legislation aims for higher recycling rates evaluation of source-segregation and recycling chains gain importance. This paper provides a consistent up-to-date dataset for 74 physico-chemical parameters in 49 material fractions from residual and 24 material fractions from source-segregated Danish household waste. Significant differences in the physico-chemical properties of residual and source-segregated waste fractions were found for many parameters related to organic matter, but also for elements of environmental concern. Considerable differences in potentially toxic metal concentrations between the individual recyclable fractions within one material type were observed. This indicates that careful planning and performance evaluation of recycling schemes are important to ensure a high quality of collected recyclables. Rare earth elements (REE) were quantified in all waste fractions analysed, with the highest concentrations of REE found in fractions with high content of mineral raw materials, soil materials and dust. The observed REE concentrations represent the background concentration level in non-hazardous waste materials that may serve as a reference point for future investigations related to hazardous waste management. The detailed dataset provided here can be used for assessments of waste management solutions in Denmark and for the evaluation of the quality of recyclable materials in waste. Copyright © 2016 Elsevier Ltd. All rights reserved.
Evaluating the feasibility of biological waste processing for long term space missions.
Garland, J L; Alazraki, M P; Atkinson, C F; Finger, B W
1998-01-01
Recycling waste products during orbital (e.g., International Space Station) and planetary missions (e.g., lunar base, Mars transit mission, Martian base) will reduce storage and resupply costs. Wastes streams on the space station will include human hygiene water, urine, faeces, and trash. Longer term missions will contain human waste and inedible plant material from plant growth systems used for atmospheric regeneration, food production, and water recycling. The feasibility of biological and physical-chemical waste recycling is being investigated as part of National Aeronautics and Space Administration's (NASA) Advanced Life Support (ALS) Program. In-vessel composting has lower manpower requirements, lower water and volume requirements, and greater potential for sanitization of human waste compared to alternative bioreactor designs such as continuously stirred tank reactors (CSTR). Residual solids from the process (i.e. compost) could be used a biological air filter, a plant nutrient source, and a carbon sink. Potential in-vessel composting designs for both near- and long-term space missions are presented and discussed with respect to the unique aspects of space-based systems.
Evaluating the feasibility of biological waste processing for long term space missions
NASA Technical Reports Server (NTRS)
Garland, J. L.; Alazraki, M. P.; Atkinson, C. F.; Finger, B. W.; Sager, J. C. (Principal Investigator)
1998-01-01
Recycling waste products during orbital (e.g., International Space Station) and planetary missions (e.g., lunar base, Mars transit mission, Martian base) will reduce storage and resupply costs. Wastes streams on the space station will include human hygiene water, urine, faeces, and trash. Longer term missions will contain human waste and inedible plant material from plant growth systems used for atmospheric regeneration, food production, and water recycling. The feasibility of biological and physical-chemical waste recycling is being investigated as part of National Aeronautics and Space Administration's (NASA) Advanced Life Support (ALS) Program. In-vessel composting has lower manpower requirements, lower water and volume requirements, and greater potential for sanitization of human waste compared to alternative bioreactor designs such as continuously stirred tank reactors (CSTR). Residual solids from the process (i.e. compost) could be used a biological air filter, a plant nutrient source, and a carbon sink. Potential in-vessel composting designs for both near- and long-term space missions are presented and discussed with respect to the unique aspects of space-based systems.
An innovative national health care waste management system in Kyrgyzstan.
Toktobaev, Nurjan; Emmanuel, Jorge; Djumalieva, Gulmira; Kravtsov, Alexei; Schüth, Tobias
2015-02-01
A novel low-cost health care waste management system was implemented in all rural hospitals in Kyrgyzstan. The components of the Kyrgyz model include mechanical needle removers, segregation using autoclavable containers, safe transport and storage, autoclave treatment, documentation, recycling of sterilized plastic and metal parts, cement pits for anatomical waste, composting of garden wastes, training, equipment maintenance, and management by safety and quality committees. The gravity-displacement autoclaves were fitted with filters to remove pathogens from the air exhaust. Operating parameters for the autoclaves were determined by thermal and biological tests. A hospital survey showed an average 33% annual cost savings compared to previous costs for waste management. All general hospitals with >25 beds except in the capital Bishkek use the new system, corresponding to 67.3% of all hospital beds. The investment amounted to US$0.61 per capita covered. Acceptance of the new system by the staff, cost savings, revenues from recycled materials, documented improvements in occupational safety, capacity building, and institutionalization enhance the sustainability of the Kyrgyz health care waste management system. © The Author(s) 2015.
New materials for thermal energy storage in concentrated solar power plants
NASA Astrophysics Data System (ADS)
Guerreiro, Luis; Collares-Pereira, Manuel
2016-05-01
Solar Thermal Electricity (STE) is an important alternative to PV electricity production, not only because it is getting more cost competitive with the continuous growth in installed capacity, engineering and associated innovations, but also, because of its unique dispatch ability advantage as a result of the already well established 2-tank energy storage using molten salts (MS). In recent years, research has been performed, on direct MS systems, to which features like modularity and combinations with other (solid) thermal storage materials are considered with the goal of achieving lower investment cost. Several alternative materials and systems have been studied. In this research, storage materials were identified with thermo-physical data being presented for different rocks (e.g. quartzite), super concrete, and other appropriate solid materials. Among the new materials being proposed like rocks from old quarries, an interesting option is the incorporation of solid waste material from old mines belonging to the Iberian Pyritic Belt. These are currently handled as byproducts of past mine activity, and can potentially constitute an environmental hazard due to their chemical (metal) content. This paper presents these materials, as part of a broad study to improve the current concept of solar energy storage for STE plants, and additionally presents a potentially valuable solution for environmental protection related to re-use of mining waste.
NASA Astrophysics Data System (ADS)
Remerowski, Mary Lynn; Dozhier, C.; Krenek, K.; VanPelt, C. E.; Reimus, M. A.; Spengler, D.; Matonic, J.; Garcia, L.; Rios, E.; Sandoval, F.; Herman, D.; Hart, R.; Ewing, B.; Lovato, M.; Romero, J. P.
2005-02-01
Pu-238 heat sources are used to fuel radioisotope thermoelectric generators (RTG) used in space missions. The demand for this fuel is increasing, yet there are currently no domestic sources of this material. Much of the fuel is material reprocessed from other sources. One rich source of Pu-238 residual material is that from contaminated combustible materials, such as cheesecloth, ion exchange resins and plastics. From both waste minimization and production efficiency standpoints, the best solution is to recover this material. One way to accomplish separation of the organic component from these residues is a flameless oxidation process using molten salt as the matrix for the breakdown of the organic to carbon dioxide and water. The plutonium is retained in the salt, and can be recovered by dissolution of the carbonate salt in an aqueous solution, leaving the insoluble oxide behind. Further aqueous scrap recovery processing is used to purify the plutonium oxide. Recovery of the plutonium from contaminated combustibles achieves two important goals. First, it increases the inventory of Pu-238 available for heat source fabrication. Second, it is a significant waste minimization process. Because of its thermal activity (0.567 W per gram), combustibles must be packaged for disposition with much lower amounts of Pu-238 per drum than other waste types. Specifically, cheesecloth residues in the form of pyrolyzed ash (for stabilization) are being stored for eventual recovery of the plutonium.
DOE Office of Scientific and Technical Information (OSTI.GOV)
Remerowski, Mary Lynn; Dozhier, C.; Krenek, K.
2005-02-06
Pu-238 heat sources are used to fuel radioisotope thermoelectric generators (RTG) used in space missions. The demand for this fuel is increasing, yet there are currently no domestic sources of this material. Much of the fuel is material reprocessed from other sources. One rich source of Pu-238 residual material is that from contaminated combustible materials, such as cheesecloth, ion exchange resins and plastics. From both waste minimization and production efficiency standpoints, the best solution is to recover this material. One way to accomplish separation of the organic component from these residues is a flameless oxidation process using molten salt asmore » the matrix for the breakdown of the organic to carbon dioxide and water. The plutonium is retained in the salt, and can be recovered by dissolution of the carbonate salt in an aqueous solution, leaving the insoluble oxide behind. Further aqueous scrap recovery processing is used to purify the plutonium oxide. Recovery of the plutonium from contaminated combustibles achieves two important goals. First, it increases the inventory of Pu-238 available for heat source fabrication. Second, it is a significant waste minimization process. Because of its thermal activity (0.567 W per gram), combustibles must be packaged for disposition with much lower amounts of Pu-238 per drum than other waste types. Specifically, cheesecloth residues in the form of pyrolyzed ash (for stabilization) are being stored for eventual recovery of the plutonium.« less
40 CFR 260.42 - Notification requirement for hazardous secondary materials.
Code of Federal Regulations, 2014 CFR
2014-07-01
... (CONTINUED) SOLID WASTES (CONTINUED) HAZARDOUS WASTE MANAGEMENT SYSTEM: GENERAL Rulemaking Petitions § 260.42... according to the exclusion (reported as the EPA hazardous waste numbers that would apply if the hazardous secondary materials were managed as hazardous wastes); (8) For each hazardous secondary material, whether...
40 CFR 260.42 - Notification requirement for hazardous secondary materials.
Code of Federal Regulations, 2012 CFR
2012-07-01
... (CONTINUED) SOLID WASTES (CONTINUED) HAZARDOUS WASTE MANAGEMENT SYSTEM: GENERAL Rulemaking Petitions § 260.42... according to the exclusion (reported as the EPA hazardous waste numbers that would apply if the hazardous secondary materials were managed as hazardous wastes); (8) For each hazardous secondary material, whether...
40 CFR 260.42 - Notification requirement for hazardous secondary materials.
Code of Federal Regulations, 2013 CFR
2013-07-01
... (CONTINUED) SOLID WASTES (CONTINUED) HAZARDOUS WASTE MANAGEMENT SYSTEM: GENERAL Rulemaking Petitions § 260.42... according to the exclusion (reported as the EPA hazardous waste numbers that would apply if the hazardous secondary materials were managed as hazardous wastes); (8) For each hazardous secondary material, whether...
40 CFR 260.42 - Notification requirement for hazardous secondary materials.
Code of Federal Regulations, 2010 CFR
2010-07-01
... (CONTINUED) SOLID WASTES (CONTINUED) HAZARDOUS WASTE MANAGEMENT SYSTEM: GENERAL Rulemaking Petitions § 260.42... according to the exclusion (reported as the EPA hazardous waste numbers that would apply if the hazardous secondary materials were managed as hazardous wastes); (8) For each hazardous secondary material, whether...
Laboratory Testing of Waste Isolation Pilot Plant Surrogate Waste Materials
NASA Astrophysics Data System (ADS)
Broome, S.; Bronowski, D.; Pfeifle, T.; Herrick, C. G.
2011-12-01
The Waste Isolation Pilot Plant (WIPP) is a U.S. Department of Energy geological repository for the permanent disposal of defense-related transuranic (TRU) waste. The waste is emplaced in rooms excavated in the bedded Salado salt formation at a depth of 655 m below the ground surface. After emplacement of the waste, the repository will be sealed and decommissioned. WIPP Performance Assessment modeling of the underground material response requires a full and accurate understanding of coupled mechanical, hydrological, and geochemical processes and how they evolve with time. This study was part of a broader test program focused on room closure, specifically the compaction behavior of waste and the constitutive relations to model this behavior. The goal of this study was to develop an improved waste constitutive model. The model parameters are developed based on a well designed set of test data. The constitutive model will then be used to realistically model evolution of the underground and to better understand the impacts on repository performance. The present study results are focused on laboratory testing of surrogate waste materials. The surrogate wastes correspond to a conservative estimate of the degraded containers and TRU waste materials after the 10,000 year regulatory period. Testing consists of hydrostatic, uniaxial, and triaxial tests performed on surrogate waste recipes that were previously developed by Hansen et al. (1997). These recipes can be divided into materials that simulate 50% and 100% degraded waste by weight. The percent degradation indicates the anticipated amount of iron corrosion, as well as the decomposition of cellulosics, plastics, and rubbers. Axial, lateral, and volumetric strain and axial and lateral stress measurements were made. Two unique testing techniques were developed during the course of the experimental program. The first involves the use of dilatometry to measure sample volumetric strain under a hydrostatic condition. Bulk moduli of the samples measured using this technique were consistent with those measured using more conventional methods. The second technique involved performing triaxial tests under lateral strain control. By limiting the lateral strain to zero by controlling the applied confining pressure while loading the specimen axially in compression, one can maintain a right-circular cylindrical geometry even under large deformations. This technique is preferred over standard triaxial testing methods which result in inhomogeneous deformation or "barreling". Manifestations of the inhomogeneous deformation included non-uniform stress states, as well as unrealistic Poisson's ratios (> 0.5) or those that vary significantly along the length of the specimen. Zero lateral strain controlled tests yield a more uniform stress state, and admissible and uniform values of Poisson's ratio. Hansen, F.D., Knowles, M.K., et al. 1997. Description and Evaluation of a Mechanistically Based Conceptual Model for Spall. SAND97-1369. Sandia National Laboratories, Albuquerque. Sandia National Laboratories is a multi-program laboratory managed and operated by Sandia Corporation, a wholly owned subsidiary of Lockheed Martin Corporation, for the U.S. Department of Energy's National Nuclear Security Administration under contract DE-AC04-94AL85000.
In-situ vitrification of waste materials
Powell, J.R.; Reich, M.; Barletta, R.
1997-10-14
A method for the in-situ vitrification of waste materials in a disposable can that includes an inner container and an outer container is disclosed. The method includes the steps of adding frit and waste materials to the inner container, removing any excess water, heating the inner container such that the frit and waste materials melt and vitrify after cooling, while maintaining the outer container at a significantly lower temperature than the inner container. The disposable can is then cooled to ambient temperatures and stored. A device for the in-situ vitrification of waste material in a disposable can is also disclosed. 7 figs.
In-situ vitrification of waste materials
Powell, James R.; Reich, Morris; Barletta, Robert
1997-11-14
A method for the in-situ vitrification of waste materials in a disposable can that includes an inner container and an outer container is disclosed. The method includes the steps of adding frit and waste materials to the inner container, removing any excess water, heating the inner container such that the frit and waste materials melt and vitrify after cooling, while maintaining the outer container at a significantly lower temperature than the inner container. The disposable can is then cooled to ambient temperatures and stored. A device for the in-situ vitrification of waste material in a disposable can is also disclosed.
Martinho, Graça; Gomes, Ana; Santos, Pedro; Ramos, Mário; Cardoso, João; Silveira, Ana; Pires, Ana
2017-03-01
The need to increase packaging recycling rates has led to the study and analysis of recycling schemes from various perspectives, including technical, economic, social, and environmental. This paper is part one of a three-part study devoted to comparing two recyclable packaging waste collection systems operating in western Portugal: a mixed collection system, where curbside and drop-off collections are operated simultaneously (but where the curbside system was introduced after the drop-off system), and an exclusive drop-off system. This part of the study focuses on analyzing the operation and performance of the two waste collection systems. The mixed collection system is shown to yield higher material separation rates, higher recycling rates, and lower contamination rates compared with the exclusive drop-off system, a result of the curbside component in the former system. However, the operational efficiency of the curbside collection in the mixed system is lower than the drop-off collection in the mixed system and the exclusive drop-off system, mainly because of inefficiency of collection. A key recommendation is to ensure that the systems should be optimized in an attempt to improve performance. Optimization should be applied not only to logistical aspects but also to citizens' participation, which could be improved by conducting curbside collection awareness campaigns in the neighborhoods that have a mixed system. Copyright © 2017 Elsevier Ltd. All rights reserved.
Cuevas, Jaime; Ruiz, Ana Isabel; Fernández, Raúl
2018-02-21
Clay and cement are known nano-colloids originating from natural processes or traditional materials technology. Currently, they are used together as part of the engineered barrier system (EBS) to isolate high-level nuclear waste (HLW) metallic containers in deep geological repositories (DGR). The EBS should prevent radionuclide (RN) migration into the biosphere until the canisters fail, which is not expected for approximately 10 3 years. The interactions of cementitious materials with bentonite swelling clay have been the scope of our research team at the Autonomous University of Madrid (UAM) with participation in several European Union (EU) projects from 1998 up to now. Here, we describe the mineral and chemical nature and microstructure of the alteration rim generated by the contact between concrete and bentonite. Its ability to buffer the surrounding chemical environment may have potential for further protection against RN migration. © 2018 The Chemical Society of Japan & Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.
NASA Astrophysics Data System (ADS)
Holliday, Kiel Steven
There is a significant buildup in plutonium stockpiles throughout the world, because of spent nuclear fuel and the dismantling of weapons. The radiotoxicity of this material and proliferation risk has led to a desire for destroying excess plutonium. To do this effectively, it must be fissioned in a reactor as part of a uranium free fuel to eliminate the generation of more plutonium. This requires an inert matrix to volumetrically dilute the fissile plutonium. Zirconia-magnesia dual phase ceramic has been demonstrated to be a favorable material for this task. It is neutron transparent, zirconia is chemically robust, magnesia has good thermal conductivity and the ceramic has been calculated to conform to current economic and safety standards. This dissertation contributes to the knowledge of zirconia-magnesia as an inert matrix fuel to establish behavior of the material containing a fissile component. First, the zirconia-magnesia inert matrix is synthesized in a dual phase ceramic containing a fissile component and a burnable poison. The chemical constitution of the ceramic is then determined. Next, the material performance is assessed under conditions relevant to an advanced fuel cycle. Reactor conditions were assessed with high temperature, high pressure water. Various acid solutions were used in an effort to dissolve the material for reprocessing. The ceramic was also tested as a waste form under environmental conditions, should it go directly to a repository as a spent fuel. The applicability of zirconia-magnesia as an inert matrix fuel and waste form was tested and found to be a promising material for such applications.
DOE Office of Scientific and Technical Information (OSTI.GOV)
Kosaka, Hitoshi; Iwahashi, Takashi; Yoshida, Nobuhiro
1998-07-01
A new concept of a gasifier for coal and wastes is proposed where entrained bed and fixed pebble bed are combined. Main features of this pebble bed gasifier are high efficiency molten slag capture, high efficiency gasification and compactness. Coal and RFD combustion experiments using the pebble bed gasifier demonstrated high efficiency capture and continuous extraction of molten slag as well as complete char combustion with extra ordinarily short residence time of pulverized coal and crushed RDF at the temperature level of about 1,500 C within the pebble bed. Durability tests using high temperature electric furnace has shown that highmore » density alumna is a good candidate for pebble material.« less
Code of Federal Regulations, 2013 CFR
2013-01-01
... waste repository at a geologic repository operations area under parts 60 and 63 of this chapter, and in... whether it is practicable to adopt, without further supplementation, the environmental impact statement... supplementation of the environmental impact statement by NRC is required, it shall file its final supplemental...
Code of Federal Regulations, 2012 CFR
2012-01-01
... waste repository at a geologic repository operations area under parts 60 and 63 of this chapter, and in... whether it is practicable to adopt, without further supplementation, the environmental impact statement... supplementation of the environmental impact statement by NRC is required, it shall file its final supplemental...
STONES SAWING SLUDGE AS BY-PRODUCT: characterization for a future recovery
NASA Astrophysics Data System (ADS)
Zichella, Lorena; Bellopede, Rossana; Marini, Paola
2017-04-01
The European Commission, as part of its Thematic Strategy on the prevention and recycling of waste, committed itself to tackle one of the issues around the waste definition, namely the distinction between waste and by-products. This definition has been outlined through the Communication on waste and by-product of the European Court of Justice (Brussels, 21.2.2007 COM(2007) 59 final COMMUNICATION FROM THE COMMISSION TO THE COUNCIL AND THE EUROPEAN PARLIAMENT). By-product is a substance or object, resulting from a production process, the primary aim of which is not the production of that item. By-products can come from a wide range of business sectors, and can have very different environmental impacts. If there is a possibility that the material is in fact not useable, because it does not meet the technical specifications that would be required for its use, then it should continue to be considered as a waste. The status of waste protects the environment from the potential consequences of this uncertainty. If it subsequently happens that a use is found for the waste in question then it will lose its status of waste and it will be considered a by-product. An incorrect classification could be the cause of environmental damage or unnecessary costs for business. For this purpose a characterization of sludge coming from different plants of stone processing was carried out for a better classification of the materials in view of a future recovery. The different stones cutting processes considered for this study are: gangsaw, diamond blade and diamond wire. The cut materials are granites, gneisses, and other stones mainly of silicatic nature. The tests performed on the sawing sludge are the following: particle size analysis, chemical analysis, wet magnetic separation, diffraction and SEM analysis. The study performed is useful for evaluating the possible reuses of the products coming from the magnetic separation: the metal fraction, and the mineral one. In order to avoid a subsequent environmental degradation and to promote a technology innovation (sustainability and circular economy) a proactive waste management strategy trying to optimize on the one hand the processing to obtain reduced waste and the other to improve the process to obtain two reusable by-products was considered.
DOE Office of Scientific and Technical Information (OSTI.GOV)
Greg Shott, Vefa Yucel, Lloyd Desotell
2008-05-01
This Special Analysis (SA) was prepared to assess the potential impact of inadvertent disposal of a limited quantity of transuranic (TRU) waste in classified Trench 4 (T04C) within the Area 5 Radioactive Waste Management Site (RWMS) at the Nevada Test Site (NTS). The Area 5 RWMS is a low-level radioactive waste disposal site in northern Frenchman Flat on the Nevada Test Site (NTS). The Area 5 RWMS is regulated by the U.S. Department of Energy (DOE) under DOE Order 435.1 and DOE Manual (DOE M) 435.1-1. The primary objective of the SA is to evaluate if inadvertent disposal of limitedmore » quantities of TRU waste in a shallow land burial trench at the Area 5 RWMS is in compliance with the existing, approved Disposal Authorization Statement (DAS) issued under DOE M 435.1-1. In addition, supplemental analyses are performed to determine if there is reasonable assurance that the requirements of Title 40, Code of Federal Regulations (CFR), Part 191, Environmental Radiation Protection Standards for Management and Disposal of Spent Nuclear Fuel, High-Level, and Transuranic Radioactive Wastes, can be met. The 40 CFR 191 analyses provide supplemental information regarding the risk to human health and the environment of leaving the TRU waste in T04C. In 1989, waste management personnel reviewing classified materials records discovered that classified materials buried in trench T04C at the Area 5 RWMS contained TRU waste. Subsequent investigations determined that a total of 102 55-gallon drums of TRU waste from Rocky Flats were buried in trench T04C in 1986. The disposal was inadvertent because unclassified records accompanying the shipment indicated that the waste was low-level. The exact location of the TRU waste in T04C was not recorded and is currently unknown. Under DOE M 435.1-1, Chapter IV, Section P.5, low-level waste disposal facilities must obtain a DAS. The DAS specifies conditions that must be met to operate within the radioactive waste management basis, consisting of a performance assessment (PA), composite analysis (CA), closure plan, monitoring plan, waste acceptance criteria, and a PA/CA maintenance plan. The DOE issued a DAS for the Area 5 RWMS in 2000. The Area 5 RWMS DAS was, in part, based on review of a CA as required under DOE M 435.1-1, Chapter IV, Section P.(3). A CA is a radiological assessment required for DOE waste disposed before 26 September 1988 and includes the radiological dose from all sources of radioactive material interacting with all radioactive waste disposed at the Area 5 RWMS. The approved Area 5 RWMS CA, which includes the inventory of TRU waste in T04C, indicates that the Area 5 RWMS waste inventory and all interacting sources of radioactive material can meet the 0.3 mSv dose constraint. The composite analysis maximum annual dose for a future resident at the Area 5 RWMS was estimated to be 0.01 mSv at 1,000 years. Therefore, the inadvertent disposal of TRU in T04C is protective of the public and the environment, and compliant with all the applicable requirements in DOE M 435.1-1 and the DAS. The U.S. Environmental Protection Agency promulgated 40 CFR 191 to establish standards for the planned disposal of spent nuclear fuel, high level, and transuranic wastes in geologic repositories. Although not required, the National Nuclear Security Administration Nevada Site Office requested a supplemental analysis to evaluate the likelihood that the inadvertent disposal of TRU waste in T04C meets the requirements of 40 CFR 191. The SA evaluates the likelihood of meeting the 40 CFR 191 containment requirements (CRs), assurance requirements, individual protection requirements (IPRs), and groundwater protection standards. The results of the SA indicate that there is a reasonable expectation of meeting all the requirements of 40 CFR 191. The conclusion of the SA is that the Area 5 RWMS with the TRU waste buried in T04C is in compliance with all requirements in DOE M 435.1-1 and the DAS. Compliance with the DAS is demonstrated by the results of the Area 5 RWMS CA. Supplemental analyses in the SA indicate there is a reasonable expectation that the TRU in T04C can meet all the requirements of 40 CFR 191. Therefore, inadvertent disposal of a limited quantity of TRU in a shallow land burial trench at the Area 5 RWMS does not pose a significant risk to the public and the environment.« less
Marshall Space Flight Center solid waste characterization and recycling improvement study
NASA Technical Reports Server (NTRS)
Eley, Michael H.; Crews, Lavonne; Johnston, Ben; Lee, David; Colebaugh, James
1995-01-01
The MSFC Facilities Office, which is responsible for disposing of all waste generated by MSFC, issued a delivery order to the University of Alabama in Huntsville (UAH) to characterize current MSFC waste streams and to evaluate their existing recycling program. The purpose of the study was to define the nature, quantity, and types of waste produced and to generate ideas for improving the present recycling program. Specifically, the following tasks were to be performed: Identify various surplus and waste materials--as identified by the Contracting Officer's Technical Representative (COTR)--by source, location, and type; Analyze MSFC's current methods for handling, storage, transport, and disposition of waste and surplussed materials; Determine the composition of various surplus and waste materials as to type and quantities from various sources and locations; Analyze different methods for the disposition of various surplus and waste materials, including quality, quantity, preparation, transport cost, and value; Study possible alternatives to current methods of handling, storage, transport, and disposition of surplus and waste materials to improve the quality and quantities recycled or sold and to reduce and minimize the quantities of surplus and waste material currently being disposed of or stored; Provide recommendations for source and centralized segregation and aggregation of materials for recycling and/or disposition; and The analysis could include identification and laboratory level evaluation of methods and/or equipment, including capital costs, operating costs, maintenance requirements, life cycle and return on investment for systems to support the waste reduction program mission.
DOE Office of Scientific and Technical Information (OSTI.GOV)
NONE
The Weldon Spring Quarry is one of two noncontiguous areas that constitute the US Department of Energy`s (DOE) Weldon Spring site. The main area of the site is the chemical plant. Both areas are located in St. Charles County, Missouri, about 48 km (30 mi) west of St. Louis. The US Environmental Protection Agency (EPA) listed the quarry on the National Priorities List (NPL) in 1987, and the chemical plant area was added to the list in 1989. The quarry is about 6.4 km (4 mi) south-southwest of the chemical plant area; it is accessible from State Route 94 andmore » is currently fenced and closed to the public. The quarry is approximately 300 m (1,000 ft) long by 140 m (450 ft) wide and covers an area of approximately 3.6 ha (9 acres). The quarry was used by the Army for disposal of chemically contaminated (explosive) materials in the 1940s and was later used for the disposal of radioactively contaminated material by the Atomic Energy Commission (AEC) in the 1960s. Approximately 110,000 m{sup 3} (144,000 yd{sup 3}) of soil and waste material was removed from the quarry and transported to the chemical plant area as part of completing the remedial action stipulated in the Record of Decision (ROD) for the Quarry Bulk Waste Operable Unit (DOE 1990). Bulk waste removal was completed in October 1995. These wastes have been placed in the disposal cell at the chemical plant. Prior to bulk waste removal, contaminated water contained in the quarry pond was also removed; approximately 170 million liters (44 million gal) have been treated as of March 1998.« less
Code of Federal Regulations, 2013 CFR
2013-01-01
...) Food waste and yard waste; and (4) Algae. Eligible material owner, for purposes of the matching payment... and trees; or (D) Algae; (ii) Waste material, including: (A) Crop residue; (B) Other vegetative waste...
Tansel, Berrin
2017-01-01
Advancements in technology, materials development, and manufacturing processes have changed the consumer products and composition of municipal solid waste (MSW) since 1960s. Increasing quantities of discarded consumer products remain a major challenge for recycling efforts, especially for discarded electronic products (also referred as e-waste). The growing demand for high tech products has increased the e-waste quantities and its cross boundary transport globally. This paper reviews the challenges associated with increasing e-waste quantities. The increasing need for raw materials (especially for rare earth and minor elements) and unregulated e-waste recycling operations in developing and underdeveloped counties contribute to the growing concerns for e-waste management. Although the markets for recycled materials are increasing; there are major challenges for development of the necessary infrastructure for e-waste management and accountability as well as development of effective materials recovery technologies and product design. Copyright © 2016 Elsevier Ltd. All rights reserved.
NASA Astrophysics Data System (ADS)
Subekti, S.; Bayuaji, R.; Darmawan, M. S.; Husin, N. A.; Wibowo, B.; Anugraha, B.; Irawan, S.; Dibiantara, D.
2017-11-01
This research provided an overview of the potential fly ash based geopolymer paste for application in building construction. Geopolymer paste with various variations of fly ash substitution with local waste material and high-temperature influence exploited with the fresh and hardened condition. The local waste material which utilized for this study were sandblasting waste, carbide waste, shell powder, bagasse ash, rice husk and bottom ash. The findings of this study indicated that fly-based geopolymer paste with local waste material substitution which had high-temperature influence ash showed a similar nature of OPC binders potentially used in civil engineering applications.
40 CFR 262.215 - Unwanted material that is not solid or hazardous waste.
Code of Federal Regulations, 2011 CFR
2011-07-01
... 40 Protection of Environment 26 2011-07-01 2011-07-01 false Unwanted material that is not solid or... (CONTINUED) SOLID WASTES (CONTINUED) STANDARDS APPLICABLE TO GENERATORS OF HAZARDOUS WASTE Alternative... Eligible Academic Entities § 262.215 Unwanted material that is not solid or hazardous waste. (a) If an...
40 CFR 262.215 - Unwanted material that is not solid or hazardous waste.
Code of Federal Regulations, 2010 CFR
2010-07-01
... 40 Protection of Environment 25 2010-07-01 2010-07-01 false Unwanted material that is not solid or... (CONTINUED) SOLID WASTES (CONTINUED) STANDARDS APPLICABLE TO GENERATORS OF HAZARDOUS WASTE Alternative... Eligible Academic Entities § 262.215 Unwanted material that is not solid or hazardous waste. (a) If an...
Sustainable disposal of municipal solid waste: post bioreactor landfill polishing.
Batarseh, Eyad S; Reinhart, Debra R; Berge, Nicole D
2010-11-01
Sustainable disposal of municipal solid waste (MSW) requires assurance that contaminant release will be minimized or prevented within a reasonable time frame before the landfill is abandoned so that the risk of contamination release is not passed to future generations. This could be accomplished through waste acceptance criteria such as those established by the European Union (EU) that prohibit land disposal of untreated organic matter. In the EU, mechanical, biological and/or thermal pretreatment of MSW is therefore necessary prior to landfilling which is complicated and costly. In other parts of the world, treatment within highly engineered landfills is under development, known as bioreactor landfills. However, the completed bioreactor landfill still contains material, largely nonbiodegradable carbon and ammonia that may be released to the environment over the long-term. This paper provides a conceptual analysis of an approach to ensure landfill sustainability by the rapid removal of these remaining materials, leachate treatment and recirculation combined with aeration. The analysis in this paper includes a preliminary experimental evaluation using real mature leachate and waste samples, a modeling effort using a simplified mass balance approach and input parameters from real typical bioreactor cases, and a cost estimate for the suggested treatment method. Copyright © 2010 Elsevier Ltd. All rights reserved.
Butera, Stefania; Christensen, Thomas H; Astrup, Thomas F
2014-07-15
Thirty-three samples of construction and demolition waste collected at 11 recycling facilities in Denmark were characterised in terms of total content and leaching of inorganic elements and presence of the persistent organic pollutants PCBs and PAHs. Samples included (i) "clean" (i.e. unmixed) concrete waste, (ii) mixed masonry and concrete, (iii) asphalt and (iv) freshly cast concrete cores; both old and newly generated construction and demolition waste was included. PCBs and PAHs were detected in all samples, generally in non-critical concentrations. Overall, PAHs were comparable to background levels in urban environments. "Old" and "new" concrete samples indicated different PCB congener profiles and the presence of PCB even in new concrete suggested that background levels in raw materials may be an issue. Significant variability in total content of trace elements, even more pronounced for leaching, was observed indicating that the number of analysed samples may be critical in relation to decisions regarding management and utilisation of the materials. Higher leaching of chromium, sulphate and chloride were observed for masonry-containing and partly carbonated samples, indicating that source segregation and management practices may be important. Generally, leaching was in compliance with available leaching limits, except for selenium, and in some cases chromium, sulphate and antimony. Copyright © 2014 Elsevier B.V. All rights reserved.
Quantifying capital goods for biological treatment of organic waste.
Brogaard, Line K; Petersen, Per H; Nielsen, Peter D; Christensen, Thomas H
2015-02-01
Materials and energy used for construction of anaerobic digestion (AD) and windrow composting plants were quantified in detail. The two technologies were quantified in collaboration with consultants and producers of the parts used to construct the plants. The composting plants were quantified based on the different sizes for the three different types of waste (garden and park waste, food waste and sludge from wastewater treatment) in amounts of 10,000 or 50,000 tonnes per year. The AD plant was quantified for a capacity of 80,000 tonnes per year. Concrete and steel for the tanks were the main materials for the AD plant. For the composting plants, gravel and concrete slabs for the pavement were used in large amounts. To frame the quantification, environmental impact assessments (EIAs) showed that the steel used for tanks at the AD plant and the concrete slabs at the composting plants made the highest contribution to Global Warming. The total impact on Global Warming from the capital goods compared to the operation reported in the literature on the AD plant showed an insignificant contribution of 1-2%. For the composting plants, the capital goods accounted for 10-22% of the total impact on Global Warming from composting. © The Author(s) 2015.
Chemical compatibility screening results of plastic packaging to mixed waste simulants
DOE Office of Scientific and Technical Information (OSTI.GOV)
Nigrey, P.J.; Dickens, T.G.
1995-12-01
We have developed a chemical compatibility program for evaluating transportation packaging components for transporting mixed waste forms. We have performed the first phase of this experimental program to determine the effects of simulant mixed wastes on packaging materials. This effort involved the screening of 10 plastic materials in four liquid mixed waste simulants. The testing protocol involved exposing the respective materials to {approximately}3 kGy of gamma radiation followed by 14 day exposures to the waste simulants of 60 C. The seal materials or rubbers were tested using VTR (vapor transport rate) measurements while the liner materials were tested using specificmore » gravity as a metric. For these tests, a screening criteria of {approximately}1 g/m{sup 2}/hr for VTR and a specific gravity change of 10% was used. It was concluded that while all seal materials passed exposure to the aqueous simulant mixed waste, EPDM and SBR had the lowest VTRs. In the chlorinated hydrocarbon simulant mixed waste, only VITON passed the screening tests. In both the simulant scintillation fluid mixed waste and the ketone mixture simulant mixed waste, none of the seal materials met the screening criteria. It is anticipated that those materials with the lowest VTRs will be evaluated in the comprehensive phase of the program. For specific gravity testing of liner materials the data showed that while all materials with the exception of polypropylene passed the screening criteria, Kel-F, HDPE, and XLPE were found to offer the greatest resistance to the combination of radiation and chemicals.« less
The application of waste fly ash and construction-waste in cement filling material in goaf
NASA Astrophysics Data System (ADS)
Chen, W. X.; Xiao, F. K.; Guan, X. H.; Cheng, Y.; Shi, X. P.; Liu, S. M.; Wang, W. W.
2018-01-01
As the process of urbanization accelerated, resulting in a large number of abandoned fly ash and construction waste, which have occupied the farmland and polluted the environment. In this paper, a large number of construction waste and abandoned fly ash are mixed into the filling material in goaf, the best formula of the filling material which containing a large amount of abandoned fly ash and construction waste is obtained, and the performance of the filling material is analyzed. The experimental results show that the cost of filling material is very low while the performance is very good, which have a good prospect in goaf.
NASA Technical Reports Server (NTRS)
Ray, C. S.; Sen, S.; Reis, S. T.; Kim, C. W.
2005-01-01
In-situ resource processing and utilization on planetary bodies is an important and integral part of NASA's space exploration program. Within this scope and context, our general effort is primarily aimed at developing glass and glass-ceramic type materials using lunar and martian soils, and exploring various applications of these materials for planetary surface operations. Our preliminary work to date have demonstrated that glasses can be successfully prepared from melts of the simulated composition of both lunar and martian soils, and the melts have a viscosity-temperature window appropriate for drawing continuous glass fibers. The glasses are shown to have the potential for immobilizing certain types of nuclear wastes without deteriorating their chemical durability and thermal stability. This has a direct impact on successfully and economically disposing nuclear waste generated from a nuclear power plant on a planetary surface. In addition, these materials display characteristics that can be manipulated using appropriate processing protocols to develop glassy or glass-ceramic magnets. Also discussed in this presentation are other potential applications along with a few selected thermal, chemical, and structural properties as evaluated up to this time for these materials.
Method for treating materials for solidification
Jantzen, Carol M.; Pickett, John B.; Martin, Hollis L.
1995-01-01
A method for treating materials such as wastes for solidification to form a solid, substantially nonleachable product. Addition of reactive silica rather than ordinary silica to the material when bringing the initial molar ratio of its silica constituent to a desired ratio within a preselected range increases the solubility and retention of the materials in the solidified matrix. Materials include hazardous, radioactive, mixed, and heavy metal species. Amounts of other constituents of the material, in addition to its silica content are also added so that the molar ratio of each of these constituents is within the preselected ranges for the final solidified product. The mixture is then solidified by cement solidification or vitrification. The method can be used to treat a variety of wastes, including but not limited to spent filter aids from waste water treatment, waste sludges, combinations of spent filter aids and waste sludges, combinations of supernate and waste sludges, incinerator ash, incinerator offgas blowdown, combinations of incinerator ash and offgas blowdown, cementitious wastes and contaminated soils.
Method and apparatus for incinerating hazardous waste
Korenberg, Jacob
1990-01-01
An incineration apparatus and method for disposal of infectious hazardous waste including a fluidized bed reactor containing a bed of granular material. The reactor includes a first chamber, a second chamber, and a vertical partition separating the first and second chambers. A pressurized stream of air is supplied to the reactor at a sufficient velocity to fluidize the granular material in both the first and second chambers. Waste materials to be incinerated are fed into the first chamber of the fluidized bed, the fine waste materials being initially incinerated in the first chamber and subsequently circulated over the partition to the second chamber wherein further incineration occurs. Coarse waste materials are removed from the first chamber, comminuted, and recirculated to the second chamber for further incineration. Any partially incinerated waste materials and ash from the bottom of the second chamber are removed and recirculated to the second chamber for further incineration. This process is repeated until all infectious hazardous waste has been completely incinerated.
Lithner, Delilah; Halling, Maja; Dave, Göran
2012-05-01
Electronic waste has become one of the fastest growing waste problems in the world. It contains both toxic metals and toxic organics. The aim of this study was to (1) investigate to what extent toxicants can leach from different electronic products, components, and materials into water and (2) identify which group of toxicants (metals or hydrophobic organics) that is causing toxicity. Components from five discarded electronic products (cell phone, computer, phone modem, keyboard, and computer mouse) were leached in deionised water for 3 days at 23°C in concentrations of 25 g/l for metal components, 50 g/l for mixed-material components, and 100 g/l for plastic components. The water phase was tested for acute toxicity to Daphnia magna. Eighteen of 68 leachates showed toxicity (with immobility of D. magna ≥ 50% after 48 h) and came from metal or mixed-material components. The 8 most toxic leachates, with 48 h EC(50)s ranging from 0.4 to 20 g/l, came from 2 circuit sheets (key board), integrated drive electronics (IDE) cable clips (computer), metal studs (computer), a circuit board (computer mouse), a cord (phone modem), mixed parts (cell phone), and a circuit board (key board). All 5 electronic products were represented among them. Toxicity identification evaluations (with C18 and CM resins filtrations and ethylenediaminetetraacetic acid addition) indicated that metals caused the toxicity in the majority of the most toxic leachates. Overall, this study has shown that electronic waste can leach toxic compounds also during short-term leaching with pure water.
Gu, Fu; Guo, Jianfeng; Zhang, Wujie; Summers, Peter A; Hall, Philip
2017-12-01
Mechanical recycling of waste plastics is an environmental solution to the problem of waste plastic disposal, and has already become a common practice in industry. However, limited information can be found on either the industralised plastic recycling or the recycled materials, despite the use of recycled plastics has already extended to automobile production. This study investigates the life cycle environmental impacts of mechanical plastic recycling practice of a plastic recycling company in China. Waste plastics from various sources, such as agricultural wastes, plastic product manufacturers, collected solid plastic wastes and parts dismantled from waste electric and electronic equipments, are processed in three routes with products end up in different markets. The results of life cycle assessments show that the extrusion process has the largest environmental impacts, followed by the use of fillers and additives. Compared to production of virgin plastics and composites, the mechanical recycling is proved to be a superior alternative in most environmental aspects. Substituting virgin plastic composites with recycled plastic composites has achieved the highest environmental benefits, as virgin composite production has an impact almost 4 times higher that of the recycled composite production in each ReCiPe endpoint damage factor. Sensitivity analysis shows that the coverage of collecting network contribute affect little to overall environmental impact, and centralisation plays an important role in reducing overall environmental impacts. Among the fillers and additives, impact modifiers account for the most significant contributions to the environmental impacts of recycled composites. This study provides necessary information about the existing industrialised plastic recycling practice, and recommendations are given. Research implications are presented with the purpose to achieve higher substitution rate and lower environmental impact. Copyright © 2017 Elsevier B.V. All rights reserved.
Method and apparatus for reducing mixed waste
Elliott, Michael L.; Perez, Jr., Joseph M.; Chapman, Chris C.; Peters, Richard D.
1995-01-01
The present invention is a method and apparatus for in-can waste reduction. The method is mixing waste with combustible material prior to placing the waste into a waste reduction vessel. The combustible portion is ignited, thereby reducing combustible material to ash and non-combustible material to a slag. Further combustion or heating may be used to sinter or melt the ash. The apparatus is a waste reduction vessel having receiving canister connection means on a first end, and a waste/combustible mixture inlet on a second end. An oxygen supply is provided to support combustion of the combustible mixture.
40 CFR Appendix Viii to Part 268 - LDR Effective Dates of Injected Prohibited Hazardous Wastes
Code of Federal Regulations, 2014 CFR
2014-07-01
... Prohibited Hazardous Wastes VIII Appendix VIII to Part 268 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES (CONTINUED) LAND DISPOSAL RESTRICTIONS Pt. 268, App. VIII Appendix VIII to Part 268—LDR Effective Dates of Injected Prohibited Hazardous Wastes National Capacity LDR...
40 CFR Appendix Viii to Part 268 - LDR Effective Dates of Injected Prohibited Hazardous Wastes
Code of Federal Regulations, 2012 CFR
2012-07-01
... Prohibited Hazardous Wastes VIII Appendix VIII to Part 268 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES (CONTINUED) LAND DISPOSAL RESTRICTIONS Pt. 268, App. VIII Appendix VIII to Part 268—LDR Effective Dates of Injected Prohibited Hazardous Wastes National Capacity LDR...
40 CFR Appendix Viii to Part 268 - LDR Effective Dates of Injected Prohibited Hazardous Wastes
Code of Federal Regulations, 2011 CFR
2011-07-01
... Prohibited Hazardous Wastes VIII Appendix VIII to Part 268 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES (CONTINUED) LAND DISPOSAL RESTRICTIONS Pt. 268, App. VIII Appendix VIII to Part 268—LDR Effective Dates of Injected Prohibited Hazardous Wastes National Capacity LDR...
40 CFR Appendix Viii to Part 268 - LDR Effective Dates of Injected Prohibited Hazardous Wastes
Code of Federal Regulations, 2013 CFR
2013-07-01
... Prohibited Hazardous Wastes VIII Appendix VIII to Part 268 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES (CONTINUED) LAND DISPOSAL RESTRICTIONS Pt. 268, App. VIII Appendix VIII to Part 268—LDR Effective Dates of Injected Prohibited Hazardous Wastes National Capacity LDR...
Lemieux, P; Wood, J; Drake, J; Minamyer, S; Silvestri, E; Yund, C; Nichols, T; Ierardi, M; Amidan, B
2016-01-01
The Bio-response Operational Testing and Evaluation (BOTE) Project was a cross-government effort designed to operationally test and evaluate a response to a biological incident (release of Bacillus anthracis [Ba] spores, the causative agent for anthrax) from initial public health and law enforcement response through environmental remediation. The BOTE Project was designed to address site remediation after the release of a Ba simulant, Bacillus atrophaeus spp. globigii (Bg), within a facility, drawing upon recent advances in the biological sampling and decontamination areas. A key component of response to a biological contamination incident is the proper management of wastes and residues, which is woven throughout all response activities. Waste is generated throughout the response and includes items like sampling media packaging materials, discarded personal protective equipment, items removed from the facility either prior to or following decontamination, aqueous waste streams, and materials generated through the application of decontamination technologies. The amount of residual contaminating agent will impact the available disposal pathways and waste management costs. Waste management is an integral part of the decontamination process and should be included through "Pre-Incident" response planning. Overall, the pH-adjusted bleach decontamination process generated the most waste from the decontamination efforts, and fumigation with chlorine dioxide generated the least waste. A majority of the solid waste generated during pH-adjusted bleach decontamination was the nonporous surfaces that were removed, bagged, decontaminated ex situ, and treated as waste. The waste during the two fumigation rounds of the BOTE Project was associated mainly with sampling activities. Waste management activities may represent a significant contribution to the overall cost of the response/recovery operation. This paper addresses the waste management activities for the BOTE field test. Management of waste is a critical element of activities dealing with remediation of buildings and outdoor areas following a biological contamination incident. Waste management must be integrated into the overall remediation process, along with sampling, decontamination, resource management, and other important response elements, rather than being a stand-alone activity. The results presented in this paper will provide decision makers and emergency planners at the federal/state/tribal/local level information that can be used to integrate waste management into an overall systems approach to planning and response activities.
Canyon transfer neutron absorber to fissile material ratio analysis. Revision 1
DOE Office of Scientific and Technical Information (OSTI.GOV)
Clemmons, J.S.
1994-03-04
Waste tank fissile material and non-fissile material estimates are used to evaluate criticality safety for the existing sludge inventory and batches of sludge sent to Extended Sludge Processing (ESP). This report documents the weight ratios of several non-fissile waste constituents to fissile waste constituents from canyon reprocessing waste streams. Weight ratios of Fe, Mn, Al, Mi, and U-238 to fissile material are calculated from monthly loss estimates from the F and H Canyon Low Heat Waste (LHW) and High Heat Waste (HHW) streams. The monthly weight ratios for Fe, Mn and U-238 are then compared to calculated minimum safe weightmore » ratios. Documented minimum safe weight ratios for Al and Ni to fissile material are currently not available. Total mass data for the subject sludge constituents is provided along with scatter plots of the monthly weight ratios for each waste stream.« less
DOE Office of Scientific and Technical Information (OSTI.GOV)
Nigrey, P.J.; Dickens, T.G.; Dickman, P.T.
1997-08-01
Based on regulatory requirements for Type A and B radioactive material packaging, a Testing Program was developed to evaluate the effects of mixed wastes on plastic materials which could be used as liners and seals in transportation containers. The plastics evaluated in this program were butadiene-acrylonitrile copolymer (Nitrile rubber), cross-linked polyethylene, epichlorohydrin, ethylene-propylene rubber (EPDM), fluorocarbons, high-density polyethylene (HDPE), butyl rubber, polypropylene, polytetrafluoroethylene, and styrene-butadiene rubber (SBR). These plastics were first screened in four simulant mixed wastes. The liner materials were screened using specific gravity measurements and seal materials by vapor transport rate (VTR) measurements. For the screening of linermore » materials, Kel-F, HDPE, and XLPE were found to offer the greatest resistance to the combination of radiation and chemicals. The tests also indicated that while all seal materials passed exposure to the aqueous simulant mixed waste, EPDM and SBR had the lowest VTRs. In the chlorinated hydrocarbon simulant mixed waste, only Viton passed the screening tests. In both the simulant scintillation fluid mixed waste and the ketone mixture waste, none of the seal materials met the screening criteria. Those materials which passed the screening tests were subjected to further comprehensive testing in each of the simulant wastes. The materials were exposed to four different radiation doses followed by exposure to a simulant mixed waste at three temperatures and four different exposure times (7, 14, 28, 180 days). Materials were tested by measuring specific gravity, dimensional, hardness, stress cracking, VTR, compression set, and tensile properties. The second phase of this Testing Program involving the comprehensive testing of plastic liner has been completed and for seal materials is currently in progress.« less
The study on deformation characterization in micro rolling for ultra-thin strip
NASA Astrophysics Data System (ADS)
Xie, H. B.; Manabe, K.; Furushima, T.; Jiang, Z. Y.
2013-12-01
The demand for miniaturized parts and miniaturized semi-finished products is increasing. Metal forming processes cannot be simply scaled down to produce miniaturized micro parts and microforming processes have the capability of improving mass production and minimizing material waste. In this study, experimental and theoretical investigations on the micro rolling process have proven that the micro rolling deformation of thin strip is influenced by size effects from specimen sizeon flow stress and friction coefficient. The analytical and finite element (FE) models for describing the size effect related phenomena for SUS 304 stainless steel, such as the change of flow stress, friction and deformation behaviour, are proposed. The material surface constraint and the material deformation mode are critical in determination of material flow stress curve. The identified deformation and mechanics behaviours provide a basis for further exploration of the material deformation behaviour in plastic deformation of micro scale and the development of micro scale products via micro rolling.
Computational modelling of a thermoforming process for thermoplastic starch
NASA Astrophysics Data System (ADS)
Szegda, D.; Song, J.; Warby, M. K.; Whiteman, J. R.
2007-05-01
Plastic packaging waste currently forms a significant part of municipal solid waste and as such is causing increasing environmental concerns. Such packaging is largely non-biodegradable and is particularly difficult to recycle or to reuse due to its complex composition. Apart from limited recycling of some easily identifiable packaging wastes, such as bottles, most packaging waste ends up in landfill sites. In recent years, in an attempt to address this problem in the case of plastic packaging, the development of packaging materials from renewable plant resources has received increasing attention and a wide range of bioplastic materials based on starch are now available. Environmentally these bioplastic materials also reduce reliance on oil resources and have the advantage that they are biodegradable and can be composted upon disposal to reduce the environmental impact. Many food packaging containers are produced by thermoforming processes in which thin sheets are inflated under pressure into moulds to produce the required thin wall structures. Hitherto these thin sheets have almost exclusively been made of oil-based polymers and it is for these that computational models of thermoforming processes have been developed. Recently, in the context of bioplastics, commercial thermoplastic starch sheet materials have been developed. The behaviour of such materials is influenced both by temperature and, because of the inherent hydrophilic characteristics of the materials, by moisture content. Both of these aspects affect the behaviour of bioplastic sheets during the thermoforming process. This paper describes experimental work and work on the computational modelling of thermoforming processes for thermoplastic starch sheets in an attempt to address the combined effects of temperature and moisture content. After a discussion of the background of packaging and biomaterials, a mathematical model for the deformation of a membrane into a mould is presented, together with its finite element discretisation. This model depends on material parameters of the thermoplastic and details of tests undertaken to determine these and the results produced are given. Finally the computational model is applied for a thin sheet of commercially available thermoplastic starch material which is thermoformed into a specific mould. Numerical results of thickness and shape for this problem are given.
DOE Office of Scientific and Technical Information (OSTI.GOV)
Barariu, G.
2008-07-01
The paper presents the progress of the Decontamination Plan and Radioactive Waste Management Plan which accompanies the Decommissioning Plan for research reactor VVR-S located in Magurele, Ilfov, near Bucharest, Romania. The new variant of the Decommissioning Plan was elaborated taking into account the IAEA recommendation concerning radioactive waste management. A new feasibility study for VVR-S decommissioning was also elaborated. The preferred safe management strategy for radioactive wastes produced by reactor decommissioning is outlined. The strategy must account for reactor decommissioning, as well as rehabilitation of the existing Radioactive Waste Treatment Plant and the upgrade of the Radioactive Waste Disposal Facilitymore » at Baita-Bihor. Furthermore, the final rehabilitation of the laboratories and reusing of cleaned reactor building is envisaged. An inventory of each type of radioactive waste is presented. The proposed waste management strategy is selected in accordance with the IAEA assistance. Environmental concerns are a part of the radioactive waste management strategy. In conclusion: The current version 8 of the Draft Decommissioning Plan which include the Integrated concept of Decontamination and Decommissioning and Radwaste Management, reflects the substantial work that has been incorporated by IFIN-HH in collaboration with SITON, which has resulted in substantial improvement in document The decommissioning strategy must take into account costs for VVR-S Reactor decommissioning, as well as costs for much needed refurbishments to the radioactive waste treatment plant and the Baita-Bihor waste disposal repository. Several improvements to the Baita-Bihor repository and IFIN-HH waste treatment facility were proposed. The quantities and composition of the radioactive waste generated by VVR-S Reactor dismantling were again estimated by streams and the best demonstrated practicable processing solution was proposed. The estimated quantities of materials to be managed in the near future raise some issues that need to be solved swiftly, such as treatment of aluminum and lead and graphite management. It is envisaged that these materials to be treated to Subsidiary for Nuclear Research (SCN) Pitesti. (authors)« less
Getters for Tc and I Removal from Liquid Waste
NASA Astrophysics Data System (ADS)
Qafoku, N. P.; Asmussen, M.; Lawter, A.; Neeway, J.; Smith, G.
2015-12-01
A cementitious waste form, Cast Stone, is being evaluated as a possible supplemental waste form for the low activity waste (LAW) at the Hanford Site, which contains significant amounts of radioactive 99Tc and 129I, as part of the tank waste cleanup mission. To improve the retention of Tc and/or I in Cast Stone, materials with a high affinity for Tc and/or I, termed "getters," can be added to decrease the rate of contaminant release and diffusivity, and improve Cast Stone performance. A series of kinetic batch sorption experiments was performed to determine the effectiveness of the getter materials. Several Tc getters [blast furnace slag, Sn (II) apatite, SnCl2, nanoporous Sn phosphate, KMS-2 (a potassium-metal-sulfide), and Sn(II) hydroxyapatite] and I getters [layered Bi hydroxide, natural argentite mineral, synthetic argentite, Ag-impregnated carbon, and Ag-exchanged zeolite] were tested in different solution media, 18.2 MΩ DI H2O and a caustic LAW waste simulant containing 6.5 M Na or 7.8 M Na. The experiments were conducted at room temperature in the presence or absence of air. Results indicated that most Tc getters (with the exception of KMS-2) performed better in the DI H2O solution than in the 6.5 and 7.8 M Na LAW simulant. In addition, Tc sequestration may be affected by the presence of other redox sensitive elements that were present in the LAW simulant, such as Cr. The Tc getter materials have been examined through various solid-state characterization techniques such as XRD, SEM/EDS, XANES and EXAFS which provided evidence for plausible mechanisms of aqueous Tc removal. The results indicated that the Tc precipitates differ depending on the getter material and that Tc(VII) is reduced to Tc(IV) in most of the getters but to a differing extents. For the I getters, Ag-exchanged zeolite and synthetic argentite were the most effective ones. The other I getters showed limited effectiveness for sorbing I under the high ionic strength and caustic conditions of the LAW simulant.
The Use of Basalt, Basalt Fibers and Modified Graphite for Nuclear Waste Repository - 12150
DOE Office of Scientific and Technical Information (OSTI.GOV)
Gulik, V.I.; Biland, A.B.
2012-07-01
New materials enhancing the isolation of radioactive waste and spent nuclear fuel are continuously being developed.. Our research suggests that basalt-based materials, including basalt roving chopped basalt fiber strands, basalt composite rebar and materials based on modified graphite, could be used for enhancing radioactive waste isolation during the storage and disposal phases and maintaining it during a significant portion of the post-closure phase. The basalt vitrification process of nuclear waste is a viable alternative to glass vitrification. Basalt roving, chopped basalt fiber strands and basalt composite rebars can significantly increase the strength and safety characteristics of nuclear waste and spentmore » nuclear fuel storages. Materials based on MG are optimal waterproofing materials for nuclear waste containers. (authors)« less
Waste Materials in Hot Mix Asphalt - An Overview
DOT National Transportation Integrated Search
1992-12-01
Numerous waste materials result from manufacturing operations, service industries, sewage treatment plants, households and mining. Legislation has been enacted by several states in recent years to either mandate the use of some waste materials or to ...
Code of Federal Regulations, 2011 CFR
2011-07-01
... identification of non-hazardous secondary materials that are solid wastes when used as fuels or ingredients in...) SOLID WASTES SOLID WASTES USED AS FUELS OR INGREDIENTS IN COMBUSTION UNITS Identification of Non-Hazardous Secondary Materials That Are Solid Wastes When Used as Fuels or Ingredients in Combustion Units...
Code of Federal Regulations, 2010 CFR
2010-07-01
... OF SPECIFIC HAZARDOUS WASTES AND SPECIFIC TYPES OF HAZARDOUS WASTE MANAGEMENT FACILITIES Recyclable... material, which is contaminated with dioxin or any other hazardous waste (other than a waste identified... materials that are used in a manner that constitutes disposal. 266.23 Section 266.23 Protection of...
Code of Federal Regulations, 2012 CFR
2012-07-01
... asbestos-containing waste material into nonasbestos (asbestos-free) material. 61.155 Section 61.155... EMISSION STANDARDS FOR HAZARDOUS AIR POLLUTANTS National Emission Standard for Asbestos § 61.155 Standard for operations that convert asbestos-containing waste material into nonasbestos (asbestos-free...
Code of Federal Regulations, 2011 CFR
2011-07-01
... asbestos-containing waste material into nonasbestos (asbestos-free) material. 61.155 Section 61.155... EMISSION STANDARDS FOR HAZARDOUS AIR POLLUTANTS National Emission Standard for Asbestos § 61.155 Standard for operations that convert asbestos-containing waste material into nonasbestos (asbestos-free...
Code of Federal Regulations, 2010 CFR
2010-07-01
... asbestos-containing waste material into nonasbestos (asbestos-free) material. 61.155 Section 61.155... EMISSION STANDARDS FOR HAZARDOUS AIR POLLUTANTS National Emission Standard for Asbestos § 61.155 Standard for operations that convert asbestos-containing waste material into nonasbestos (asbestos-free...
Code of Federal Regulations, 2013 CFR
2013-07-01
... asbestos-containing waste material into nonasbestos (asbestos-free) material. 61.155 Section 61.155... EMISSION STANDARDS FOR HAZARDOUS AIR POLLUTANTS National Emission Standard for Asbestos § 61.155 Standard for operations that convert asbestos-containing waste material into nonasbestos (asbestos-free...
Code of Federal Regulations, 2014 CFR
2014-07-01
... asbestos-containing waste material into nonasbestos (asbestos-free) material. 61.155 Section 61.155... EMISSION STANDARDS FOR HAZARDOUS AIR POLLUTANTS National Emission Standard for Asbestos § 61.155 Standard for operations that convert asbestos-containing waste material into nonasbestos (asbestos-free...
Fuels from pyrolysis of waste plastic
USDA-ARS?s Scientific Manuscript database
A large quantity of carbon containing materials, such as waste plastic, used tires, food waste, and biomass end up in landfills. These materials represent a rich energy source that is currently untapped or underutilized. Municipal solid waste is comprised of 12% waste plastic, but only a small fract...
40 CFR 272.701 - State-administered program: Final authorization.
Code of Federal Regulations, 2011 CFR
2011-07-01
...) SOLID WASTES (CONTINUED) APPROVED STATE HAZARDOUS WASTE MANAGEMENT PROGRAMS Illinois § 272.701 State... Register in accordance with 5 U.S.C. 552(a) and 1 CFR part 51 as part of the hazardous waste management... Administrator on January 26, 1990, is part of the authorized hazardous waste management program under Subtitle C...
40 CFR 272.701 - State-administered program: Final authorization.
Code of Federal Regulations, 2012 CFR
2012-07-01
...) SOLID WASTES (CONTINUED) APPROVED STATE HAZARDOUS WASTE MANAGEMENT PROGRAMS Illinois § 272.701 State... Register in accordance with 5 U.S.C. 552(a) and 1 CFR part 51 as part of the hazardous waste management... Administrator on January 26, 1990, is part of the authorized hazardous waste management program under Subtitle C...
40 CFR 272.701 - State-administered program: Final authorization.
Code of Federal Regulations, 2013 CFR
2013-07-01
...) SOLID WASTES (CONTINUED) APPROVED STATE HAZARDOUS WASTE MANAGEMENT PROGRAMS Illinois § 272.701 State... Register in accordance with 5 U.S.C. 552(a) and 1 CFR part 51 as part of the hazardous waste management... Administrator on January 26, 1990, is part of the authorized hazardous waste management program under Subtitle C...
40 CFR 272.701 - State-administered program: Final authorization.
Code of Federal Regulations, 2014 CFR
2014-07-01
...) SOLID WASTES (CONTINUED) APPROVED STATE HAZARDOUS WASTE MANAGEMENT PROGRAMS Illinois § 272.701 State... Register in accordance with 5 U.S.C. 552(a) and 1 CFR part 51 as part of the hazardous waste management... Administrator on January 26, 1990, is part of the authorized hazardous waste management program under Subtitle C...
40 CFR 272.701 - State-administered program: Final authorization.
Code of Federal Regulations, 2010 CFR
2010-07-01
...) SOLID WASTES (CONTINUED) APPROVED STATE HAZARDOUS WASTE MANAGEMENT PROGRAMS Illinois § 272.701 State... Register in accordance with 5 U.S.C. 552(a) and 1 CFR part 51 as part of the hazardous waste management... Administrator on January 26, 1990, is part of the authorized hazardous waste management program under Subtitle C...
Environmental Assessment: Apalachicola National Forest Helicopter Landing Zones Florida
2003-12-01
25 3.12 Hazardous Waste/ Materials ...37 4.11 Hazardous Waste/ Materials .................................................................. 38 4.11.1 Proposed Action Alterative...26 Apalachicola Helicopter Landing Zones 3.12 Hazardous Waste/ Materials No hazardous substances or petroleum substances are generated, stored
Waste in Education: The Potential of Materiality and Practice
ERIC Educational Resources Information Center
Jørgensen, Nanna Jordt; Madsen, Katrine Dahl; Laessøe, Jeppe
2018-01-01
This article explores how waste materials and waste practices figure in education, pointing to educational potentials of waste which have hitherto received little consideration in environmental and sustainability education practice and research. Building on empirical research on waste education in Danish schools and preschools, we discuss how an…
NASA Astrophysics Data System (ADS)
Stolboushkin, A. Yu; Akst, D. V.; Fomina, O. A.; Ivanov, A. I.; Syromyasov, V. A.
2017-09-01
The analysis of waste coal from mining enterprises of Kemerovo region as raw materials for production of building ceramics is given. The results of studies of material, chemical and mineralogical compositions of waste coal from Abashevskaya processing plant (Novokuznetsk) are presented. It was established that the chemical composition of waste coal refers to aluminosilicate raw materials with a high content of alumina and coloring oxides, the residual carbon content in the wastes is 12-25 %. According to the granulometric composition the waste coal is basically a sandy-dusty fraction with a small amount of clay particles (1-3 %). Additional grinding of coal waste and the introduction of a clay additive in an amount of up to 30 % are recommended. The results of the study of the mineral composition of waste coal are presented. Clay minerals are represented in the descending order by hydromuscovite, montmorillonite and kaolinite, minerals-impurities consist of quartz, feldspar fine-dispersed carbonates. The results of the investigation of ceramic-technological properties of waste coal, which belong to the group of moderately plastic low-melting raw materials, are given. As a result of a comprehensive study it was been established that with chemical, granulometric and mineralogical compositions waste coal with the reduced residual carbon can be used in the production of ceramic bricks.
USBI Booster Production Company's Hazardous Waste Management Program at the Kennedy Space Center, FL
NASA Technical Reports Server (NTRS)
Venuto, Charles
1987-01-01
In response to the hazardous-waste generating processes associated with the launch of the Space Shuttle, a hazardous waste management plan has been developed. It includes waste recycling, product substitution, waste treatment, and waste minimization at the source. Waste material resulting from the preparation of the nonmotor segments of the solid rocket boosters include waste paints (primer, topcoats), waste solvents (methylene chloride, freon, acetone, toluene), waste inorganic compounds (aluminum anodizing compound, fixer), and others. Ways in which these materials are contended with at the Kennedy Space Center are discussed.
Life-Cycle Assessment of Biodiesel Produced from Grease Trap Waste.
Hums, Megan E; Cairncross, Richard A; Spatari, Sabrina
2016-03-01
Grease trap waste (GTW) is a low-quality waste material with variable lipid content that is an untapped resource for producing biodiesel. Compared to conventional biodiesel feedstocks, GTW requires different and additional processing steps for biodiesel production due to its heterogeneous composition, high acidity, and high sulfur content. Life-cycle assessment (LCA) is used to quantify greenhouse gas emissions, fossil energy demand, and criteria air pollutant emissions for the GTW-biodiesel process, in which the sensitivity to lipid concentration in GTW is analyzed using Monte Carlo simulation. The life-cycle environmental performance of GTW-biodiesel is compared to that of current GTW disposal, the soybean-biodiesel process, and low-sulfur diesel (LSD). The disposal of the water and solid wastes produced from separating lipids from GTW has a high contribution to the environmental impacts; however, the impacts of these processed wastes are part of the current disposal practice for GTW and could be excluded with consequential LCA system boundaries. At lipid concentrations greater than 10%, most of the environmental metrics studied are lower than those of LSD and comparable to soybean biodiesel.
SHC Project 3.63, Task 2, Beneficial Use of Waste Materials ...
SHC Project 3.63, Task 2, “Beneficial Use of Waste Materials”, is designed to conduct research and analyses to characterize and quantify the risks and benefits of using or reusing waste materials. There are 6 primary research areas in Task 2 that cover a broad spectrum of topics germane to the beneficial use of waste materials and address Agency, Office, Region and other client needs. The 6 research areas include: 1) Materials Recovery Technology, 2) Beneficial Use of Materials Optimization, 3) Novel Products from Waste Materials, 4) Land Application of Biosolids, 5) Soil Remediation Amendments and 6) Improved Leaching Methods for More Accurate Prediction of Environmental Release of Metals. The objectives of each research area, their intended products and progress to date will be presented. The products of this Task will enable communities and the Agency to better protect and enhance human health, well-being and the environment for current and future generations, through the reduction in material consumption, reuse, and recycling of materials. This presentation is designed to convey the rational, purpose and planned research in EPAs Safe and Healthy Communities (SHC) National Research Program Project 3.63 (Sustainable Materials Management) Task 2, “Beneficial Use of Waste Materials”, which is designed to conduct research and analyses to characterize and quantify the risks and benefits of using or reusing waste materials. . This presentation has bee
Applications of Nano palm oil fuel ash and Nano fly ash in concrete
NASA Astrophysics Data System (ADS)
Hamada, Hussein M.; Jokhio, Gul Ahmed; Mat Yahaya, Fadzil; Humada, Ali M.
2018-04-01
This paper discusses the applications of Nano waste materials including palm oil fuel ash and fly ash in the concrete production. The implementation of nanotechnology has been instrumental in the development of significant interest among the stakeholders to improve the mechanical and chemical properties of materials involved in the production of concrete. Although many researchers have shown the potential of nanomaterials to increase strength and durability of concrete and improve its physical and chemical properties, there is still a knowledge gap regarding the preparation of Nano waste materials from agricultural waste to use as cement replacement instead of non-renewable materials. Therefore, it should be focused on to study Nano- waste materials to benefit from these characteristics during preparation of concrete mixtures. Therefore, this paper highlights the potential of waste materials in the Nano size to partially replace cement in concrete and achieve the same or better result than the traditional concrete. This paper recommends to conduct further experimental works to improve the concrete material properties by investigating the properties of waste materials in Nano size.
Using Powder Cored Tubular Wire Technology to Enhance Electron Beam Freeform Fabricated Structures
NASA Technical Reports Server (NTRS)
Gonzales, Devon; Liu, Stephen; Domack, Marcia; Hafley, Robert
2016-01-01
Electron Beam Freeform Fabrication (EBF3) is an additive manufacturing technique, developed at NASA Langley Research Center, capable of fabricating large scale aerospace parts. Advantages of using EBF3 as opposed to conventional manufacturing methods include, decreased design-to-product time, decreased wasted material, and the ability to adapt controls to produce geometrically complex parts with properties comparable to wrought products. However, to fully exploit the potential of the EBF3 process development of materials tailored for the process is required. Powder cored tubular wire (PCTW) technology was used to modify Ti-6Al-4V and Al 6061 feedstock to enhance alloy content, refine grain size, and create a metal matrix composite in the as-solidified structures, respectively.
ANIMAL WASTE COMPOSTING WITH CARBONACEOUS MATERIAL
High rate thermophilic composting of animal wastes with added carbonaceous waste materials followed by land application has considerable potential as a means of treatment and useful final disposal of these wastes. The process described in this report utilizes a mechanically mixed...
Environmental application of gamma technology: Update on the Canadian sludge irradiator
NASA Astrophysics Data System (ADS)
Swinwood, Jean F.; Fraser, Frank M.
1993-10-01
Waste treatment and disposal technologies have recently been subjected to increasing public and regulatory scrutiny. Concern for the environment and a heightened awareness of potential health hazards that could result from insufficient or inappropriate waste handling methods have combined to push waste generators in their search for new treatment alternatives. Gamma technology can offer a new option for the treatment of potentially infectious wastes, including municipal sewage sludge. Sewage sludge contains beneficial plant nutrients and a high organic component that make it ideal as a soil conditioning agent or fertilizer bulking material. It also carries potentially infectious microorganisms which limit opportunities for beneficial recycling of sludges. Gamma irradiation-disinfection of these sludges offers a reliable, fast and efficient method for safe sludge recycling. Nordion International's Market Development Division was created in 1987 as part of a broad corporate reorganization. It was given an exclusive mandate to develop new applications of gamma irradiation technology and markets for these new applications. Nordion has since explored and developed opportunities in food irradiation, pharmaceutical/cosmetic products irradiation, biomedical waste sterilization, airline waste disinfection, and sludge disinfection for recycling. This paper focuses on the last of these -a proposed sludge recycling facility that incorporates a cobalt 60 sludge irradiator.
Vapor compression distillation module
NASA Technical Reports Server (NTRS)
Nuccio, P. P.
1975-01-01
A Vapor Compression Distillation (VCD) module was developed and evaluated as part of a Space Station Prototype (SSP) environmental control and life support system. The VCD module includes the waste tankage, pumps, post-treatment cells, automatic controls and fault detection instrumentation. Development problems were encountered with two components: the liquid pumps, and the waste tank and quantity gauge. Peristaltic pumps were selected instead of gear pumps, and a sub-program of materials and design optimization was undertaken leading to a projected life greater than 10,000 hours of continuous operation. A bladder tank was designed and built to contain the waste liquids and deliver it to the processor. A detrimental pressure pattern imposed upon the bladder by a force-operated quantity gauge was corrected by rearranging the force application, and design goals were achieved. System testing has demonstrated that all performance goals have been fulfilled.
DOE Office of Scientific and Technical Information (OSTI.GOV)
Hang, T.
2003-07-16
The U.S. Department of Energy (DOE) and the Nuclear Energy Commission of Argentina (CNEA) have a collaborative project to separate cesium/strontium from waste resulting from the production of Mo-99. The Pacific Northwest National Laboratory (PNNL) is assisting DOE on this joint project by providing technical guidance to CNEA scientists. As part of the collaboration, PNNL staff works with staff at the Savannah River Technology Center (SRTC) to run the VERSE-LC model for removal of cesium from the Mo-99 waste using the crystalline silicotitanate (CST) material (IONSIV(R) IE-911, UOP LLC, DesPlaines, IL) based on technical data provided by CNEA. This reportmore » discusses the VERSE-LC ion-exchange-column model and the predicted results of CNEA test cases.« less
DOE Office of Scientific and Technical Information (OSTI.GOV)
Not Available
1985-11-21
The 50-acre Lake Sandy Jo Landfill is located in the Black Oak community (predominantly residential) of southwestern Gary in Lake County, Indiana. From about 1971 until about 1980, the lake was filled in with construction and demolition debris, municipal garbage, industrial wastes, hazardous materials, and possibly drummed wastes. These wastes are partly to completely exposed on the landfill surface. Surface soil, subsurface soil, surface water, sediment, and ground water show a variety of metal and organic chemical carcinogens. Toxic noncarcinogen priority pollutants found were chloromethane, copper, cyanide, lead, mercury, and silver. Inorganic soil levels found on the site for leadmore » and cadmium exceed levels of concern that would permit unrestricted use of the site. Remedial measures would be necessary before the site could be granted unrestricted use.« less
Zaccariello, Lucio; Cremiato, Raffaele; Mastellone, Maria Laura
2015-10-01
The main role of a waste management plan is to define which is the combination of waste management strategies and method needed to collect and manage the waste in such a way to ensure a given set of targets is reached. Objectives have to be sustainable and realistic, consistent with the environmental policies and regulations and monitored to verify the progressive achievement of the given targets. To get the aim, the setting up and quantification of indicators can allow the measurement of efficiency of a waste management system. The quantification of efficiency indicators requires the developing of a material flow analysis over the system boundary, from waste collection to secondary materials selling, processing and disposal. The material flow analysis has been carried out with reference to a case study for which a reliable, time- and site-specific database was available. The material flow analysis allowed the evaluation of the amount of materials sent to recycling, to landfilling and to waste-to-energy, by highlighting that the sorting of residual waste can further increase the secondary materials amount. The utilisation of energy recovery to treat the low-grade waste allows the maximisation of waste diversion from landfill with a low production of hazardous ash. A preliminary economic balance has been carried out to define the gate fee of the waste management system that was in the range of 84-145 € t(-1) without including the separate collection cost. The cost of door-by-door separate collection, designed to ensure the collection of five separate streams, resulted in 250 € t(-1) ±30%. © The Author(s) 2015.
DOE Office of Scientific and Technical Information (OSTI.GOV)
Fischer, D.K.; Gitt, M.; Williams, G.A.
1991-07-01
The objective of this document is to provide a resource for all states and compact regions interested in promoting the minimization of low-level radioactive waste (LLW). This project was initiated by the Commonwealth of Massachusetts, and Massachusetts waste streams have been used as examples; however, the methods of analysis presented here are applicable to similar waste streams generated elsewhere. This document is a guide for states/compact regions to use in developing a system to evaluate and prioritize various waste minimization techniques in order to encourage individual radioactive materials users (LLW generators) to consider these techniques in their own independent evaluations.more » This review discusses the application of specific waste minimization techniques to waste streams characteristic of three categories of radioactive materials users: (1) industrial operations using radioactive materials in the manufacture of commercial products, (2) health care institutions, including hospitals and clinics, and (3) educational and research institutions. Massachusetts waste stream characterization data from key radioactive materials users in each category are used to illustrate the applicability of various minimization techniques. The utility group is not included because extensive information specific to this category of LLW generators is available in the literature.« less
Waste minimization for commercial radioactive materials users generating low-level radioactive waste
DOE Office of Scientific and Technical Information (OSTI.GOV)
Fischer, D.K.; Gitt, M.; Williams, G.A.
1991-07-01
The objective of this document is to provide a resource for all states and compact regions interested in promoting the minimization of low-level radioactive waste (LLW). This project was initiated by the Commonwealth of Massachusetts, and Massachusetts waste streams have been used as examples; however, the methods of analysis presented here are applicable to similar waste streams generated elsewhere. This document is a guide for states/compact regions to use in developing a system to evaluate and prioritize various waste minimization techniques in order to encourage individual radioactive materials users (LLW generators) to consider these techniques in their own independent evaluations.more » This review discusses the application of specific waste minimization techniques to waste streams characteristic of three categories of radioactive materials users: (1) industrial operations using radioactive materials in the manufacture of commercial products, (2) health care institutions, including hospitals and clinics, and (3) educational and research institutions. Massachusetts waste stream characterization data from key radioactive materials users in each category are used to illustrate the applicability of various minimization techniques. The utility group is not included because extensive information specific to this category of LLW generators is available in the literature.« less
Identification of Sources of Endotoxin Exposure as Input for Effective Exposure Control Strategies.
van Duuren-Stuurman, Birgit; Gröllers-Mulderij, Mariska; van de Runstraat, Annemieke; Duisterwinkel, Anton; Terwoert, Jeroen; Spaan, Suzanne
2018-02-13
Aim of the present study is to investigate the levels of endotoxins on product samples from potatoes, onions, and seeds, representing a relevant part of the agro-food industry in the Netherlands, to gather valuable insights in possibilities for exposure control measures early in the process of industrial processing of these products. Endotoxin levels on 330 products samples from companies representing the potato, onion, and seed (processing) industry (four potato-packaging companies, five potato-processing companies, five onion-packaging companies, and four seed-processing companies) were assessed using the Limulus Amboecyte Lysate (LAL) assay. As variation in growth conditions (type of soil, growth type) and product characteristics (surface roughness, dustiness, size, species) are assumed to influence the level of endotoxin on products, different types, and growth conditions were considered when collecting the samples. Additionally, waste material, rotten products, felt material (used for drying), and process water were collected. A large variation in the endotoxin levels was found on samples of potatoes, onions, and seeds (overall geometric standard deviation 17), in the range between 0.7 EU g-1 to 16400000 EU g-1. The highest geometric mean endotoxin levels were found in plant material (319600 EU g-1), followed by soil material (49100 EU g-1) and the outer side of products (9300 EU g-1), indicating that removal of plant and soil material early in the process would be an effective exposure control strategy. The high levels of endotoxins found in the limited number of samples from rotten onions indicate that these rotten onions should also be removed early in the process. Mean endotoxin levels found in waste material (only available for seed processing) is similar to the level found in soil material, although the range is much larger. On uncleaned seeds, higher endotoxin levels were found than on cleaned seeds, indicating that cleaning processes are important control measures and also that the waste material should be handled with care. Although endotoxin levels in batches of to-be-processed potatoes, onions, and seeds vary quite dramatically, it could be concluded that rotten products, plant material, and waste material contain particularly high endotoxin levels. This information was used to propose control measures to reduce exposure to endotoxins of workers during the production process. © The Author(s) 2017. Published by Oxford University Press on behalf of the British Occupational Hygiene Society.
Removal of radioactive and other hazardous material from fluid waste
Tranter, Troy J [Idaho Falls, ID; Knecht, Dieter A [Idaho Falls, ID; Todd, Terry A [Aberdeen, ID; Burchfield, Larry A [W. Richland, WA; Anshits, Alexander G [Krasnoyarsk, RU; Vereshchagina, Tatiana [Krasnoyarsk, RU; Tretyakov, Alexander A [Zheleznogorsk, RU; Aloy, Albert S [St. Petersburg, RU; Sapozhnikova, Natalia V [St. Petersburg, RU
2006-10-03
Hollow glass microspheres obtained from fly ash (cenospheres) are impregnated with extractants/ion-exchangers and used to remove hazardous material from fluid waste. In a preferred embodiment the microsphere material is loaded with ammonium molybdophosphonate (AMP) and used to remove radioactive ions, such as cesium-137, from acidic liquid wastes. In another preferred embodiment, the microsphere material is loaded with octyl(phenyl)-N-N-diisobutyl-carbamoylmethylphosphine oxide (CMPO) and used to remove americium and plutonium from acidic liquid wastes.
Francisković-Bilinski, S; Bilinski, H; Grbac, R; Zunić, J; Necemer, M; Hanzel, D
2007-02-01
The present work was designed as an extension of a previous study of a barium anomaly observed in stream sediments of the Kupa River. In its upper part the Kupa River drains a region underlain by a trans-boundary aquifer. The river is a significant water resource in a region of tourism, sport, and fishing in both Croatia and Slovenia. The contamination source is situated in Homer (Lokve), Croatia, where barite was mined until 10 years ago. The barium processing waste material (<3-mm fraction) was carelessly deposited in gardens, forests, and into a sinkhole, which has an underground link with the Kupica River, a tributary of the Kupa River. Barium waste and stream sediments were analyzed using comparative techniques: X-ray diffraction (XRD), X-ray fluorescence (XRF), Mössbauer spectroscopy, and grain size analysis. XRD of the waste material identified the major minerals quartz, barite, and dolomite and the Fe-containing minor minerals muscovite and goethite. Barite was identified as a minor or trace mineral in the Kupica River sediments. XRF analysis of the waste material has shown Ba and Fe to be the predominant elements, Ca and K to be minor elements, and Mn, Zn, Sr, Pb, Co, Cu, As, Zr, Rb, Y, and Mo to be trace elements. Mössbauer spectroscopy performed at room temperature (RT) was used to study iron minerals, particularly to obtain information on the valence status of Fe ions. Grain size analysis of the waste material (<63-microm fraction) has shown that it contains 23.5% clay-size material in comparison with 7-8% clay-size material in stream sediments. It is our aim to combine geochemical and medical methods to investigate the possible impact of waste disposal on human health in Lokve. At this stage of the work, concentrations of Ba and other toxic elements in the water compartment of the Kupica River (a source of drinking water) have not been monitored by Croatian Waters (name of the Croatian water authorities). The necessity of such measurements in future studies has been highlighted. A preliminary study of diseases diagnosed in Lokve shows that about 18% of the total inhabitants have serious medical problems. Diseases of the circulatory system, endocrine, nutritional, and metabolic diseases, neoplasms, and respiratory diseases predominate. This paper calls for further multidisciplinary research on the health effects of barium and trace elements, as well as for bioremediation of contaminated gardens and for watershed management of vulnerable karstic aquifers.
DOE Office of Scientific and Technical Information (OSTI.GOV)
Laguna, O.; Collar, E.P.; Taranco, J.
Observations are made about microstructural aspects from HDPE and LDPE homopolymers and their blends as virgin materials and also from urban plastic wastes. Micrographs were taken by SEM. Micrographs corresponding to the fracture surface from specimens tested in an impact test clearly show different microstructural features due to polymer which is more than 50%. Parts were injection molded. A discussion is given about crystallization behavior of those materials obtained by DSC. For all blends the same results have been found, i.e., two peaks owing to each of the two polymers which are present in the blends.
Secondary Waste Form Down Selection Data Package – Ceramicrete
DOE Office of Scientific and Technical Information (OSTI.GOV)
Cantrell, Kirk J.; Westsik, Joseph H.
2011-08-31
As part of high-level waste pretreatment and immobilized low activity waste processing, liquid secondary wastes will be generated that will be transferred to the Effluent Treatment Facility on the Hanford Site for further treatment. These liquid secondary wastes will be converted to stable solid waste forms that will be disposed in the Integrated Disposal Facility. Currently, four waste forms are being considered for stabilization and solidification of the liquid secondary wastes. These waste forms are Cast Stone, Ceramicrete, DuraLith, and Fluidized Bed Steam Reformer. The preferred alternative will be down selected from these four waste forms. Pacific Northwest National Laboratorymore » is developing data packages to support the down selection process. The objective of the data packages is to identify, evaluate, and summarize the existing information on the four waste forms being considered for stabilization and solidification of the liquid secondary wastes. The information included will be based on information available in the open literature and from data obtained from testing currently underway. This data package is for the Ceramicrete waste form. Ceramicrete is a relatively new engineering material developed at Argonne National Laboratory to treat radioactive and hazardous waste streams (e.g., Wagh 2004; Wagh et al. 1999a, 2003; Singh et al. 2000). This cement-like waste form can be used to treat solids, liquids, and sludges by chemical immobilization, microencapsulation, and/or macroencapsulation. The Ceramicrete technology is based on chemical reaction between phosphate anions and metal cations to form a strong, dense, durable, low porosity matrix that immobilizes hazardous and radioactive contaminants as insoluble phosphates and microencapsulates insoluble radioactive components and other constituents that do not form phosphates. Ceramicrete is a type of phosphate-bonded ceramic, which are also known as chemically bonded phosphate ceramics. The Ceramicrete binder is formed through an acid-base reaction between calcined magnesium oxide (MgO; a base) and potassium hydrogen phosphate (KH{sub 2}PO{sub 4}; an acid) in aqueous solution. The reaction product sets at room temperature to form a highly crystalline material. During the reaction, the hazardous and radioactive contaminants also react with KH{sub 2}PO{sub 4} to form highly insoluble phosphates. In this data package, physical property and waste acceptance data for Ceramicrete waste forms fabricated with wastes having compositions that were similar to those expected for secondary waste effluents, as well as secondary waste effluent simulants from the Hanford Tank Waste Treatment and Immobilization Plant were reviewed. With the exception of one secondary waste form formulation (25FA+25 W+1B.A. fabricated with the mixed simulant did not meet the compressive strength requirement), all the Ceramicrete waste forms that were reviewed met or exceeded Integrated Disposal Facility waste acceptance criteria.« less
Eriksson, Ola; Bisaillon, Mattias; Haraldsson, Mårten; Sundberg, Johan
2016-06-15
Management of municipal solid waste is an efficient method to increase resource efficiency, as well as to replace fossil fuels with renewable energy sources due to that (1) waste to a large extent is renewable as it consists of food waste, paper, wood etc. and (2) when energy and materials are recovered from waste treatment, fossil fuels can be substituted. In this paper results from a comprehensive system study of future biological treatment of readily degradable waste in two Swedish regions are presented. Different collection and separation systems for food waste in households have been applied as well as technical improvements of the biogas process as to reduce environmental impact. The results show that central sorting of a mixed fraction into recyclables, combustibles, biowaste and inert is a competitive option compared to source separation. Use of pellets is beneficial compared to direct spreading as fertiliser. Fuel pellets seem to be the most favourable option, which to a large extent depends on the circumstances in the energy system. Separation and utilisation of nitrogen in the wet part of the digestion residue is made possible with a number of technologies which decreases environmental impact drastically, however to a substantial cost in some cases. Copyright © 2016 Elsevier Ltd. All rights reserved.
Metallic elements fractionation in municipal solid waste incineration residues
NASA Astrophysics Data System (ADS)
Kowalski, Piotr R.; Kasina, Monika; Michalik, Marek
2016-04-01
Municipal solid waste incineration (MSWI) residues are represented by three main materials: bottom ash, fly ash and air pollution control (APC) residues. Among them ˜80 wt% is bottom ash. All of that materials are products of high temperature (>1000° C) treatment of waste. Incineration process allows to obtain significant reduction of waste mass (up to 70%) and volume (up to 90%) what is commonly used in waste management to reduce the amount need to be landfilled or managed in other way. Incineration promote accumulation non-combustible fraction of waste, which part are metallic elements. That type of concentration is object of concerns about the incineration residues impact on the environment and also gives the possibility of attempts to recover them. Metallic elements are not equally distributed among the materials. Several factors influence the process: melting points, volatility and place and forms of metallic occurrence in the incinerated waste. To investigate metallic elements distribution in MSWI residues samples from one of the biggest MSW incineration plant in Poland were collected in 2015. Chemical analysis with emphasis on the metallic elements content were performed using inductively coupled plasma optical emission (ICP-OES) and mass spectrometry (ICP-MS). The bottom ash was a SiO2-CaO-Al2O3-Fe2O3-Na2O rich material, whereas fly ash and APC residues were mostly composed of CaO and SiO2. All of the materials were rich in amorphous phase occurring together with various, mostly silicate crystalline phases. In a mass of bottom ash 11 wt% were metallic elements but also in ashes 8.5 wt% (fly ash) and ˜4.5 wt% (APC residues) of them were present. Among the metallic elements equal distribution between bottom and fly ash was observed for Al (˜3.85 wt%), Mn (770 ppm) and Ni (˜65 ppm). In bottom ash Fe (5.5 wt%), Cr (590 ppm) and Cu (1250 ppm) were concentrated. These values in comparison to fly ash were 5-fold higher for Fe, 3-fold for Cu and 1.5-fold for Cr. In comparison to bottom ash, in fly ash 10-fold more Zn was present (8070 ppm), 4-fold more Sn (540 ppm) and also 2-fold more Ti (1.1 wt%), Pb (460 ppm) and Sn (540 ppm). Although APC residue is the material produced in the smallest quantities, in its composition some high concentrations of metallic elements were also present. Contents of Zn (>1 wt%), Pb (2560 ppm) and Sn (875 ppm) were much higher than in bottom and fly ash. Obtained results confirmed that fractionation of elements occurs during the municipal waste incineration and further detailed study of the residues may allow better understanding of the process. Acknowledgment: Research was funded by Polish National Science Centre (NCN). Scientific grant No. UMO-2014/15/B/ST10/04171.
40 CFR 258.21 - Cover material requirements.
Code of Federal Regulations, 2010 CFR
2010-07-01
... Section 258.21 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES CRITERIA FOR MUNICIPAL SOLID WASTE LANDFILLS Operating Criteria § 258.21 Cover material requirements. (a... cover disposed solid waste with six inches of earthen material at the end of each operating day, or at...
40 CFR 258.21 - Cover material requirements.
Code of Federal Regulations, 2011 CFR
2011-07-01
... Section 258.21 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES CRITERIA FOR MUNICIPAL SOLID WASTE LANDFILLS Operating Criteria § 258.21 Cover material requirements. (a... cover disposed solid waste with six inches of earthen material at the end of each operating day, or at...
NASA Astrophysics Data System (ADS)
Indrawati, V.; Manaf, A.; Purwadi, G.
2009-09-01
This paper reports recent investigations on the use of biomass like rice husk, palm kernel shell, saw dust and municipal waste to reduce the use of fossil fuels energy in the cement production. Such waste materials have heat values in the range approximately from 2,000 to 4,000 kcal/kg. These are comparable to the average value of 5800 kcal/kg from fossil materials like coals which are widely applied in many industrial processing. Hence, such waste materials could be used as alternative fuels replacing the fossil one. It is shown that replacement of coals with such waste materials has a significant impact on cost effectiveness as well as sustainable development. Variation in moisture content of the waste materials, however should be taken into account because this is one of the parameter that could not be controlled. During fuel combustion, some amount of the total energy is used to evaporate the water content and thus the net effective heat value is less.
NASA Astrophysics Data System (ADS)
Tewolde, Mahder
Thermoelectric generators (TEGs) are solid-state devices that convert heat directly into electricity. They are well suited for waste-heat energy harvesting applications as opposed to primary energy generation. Commercially available thermoelectric modules are flat, inflexible and have limited sizes available. State-of-art manufacturing of TEG devices relies on assembling prefabricated parts with soldering, epoxy bonding, and mechanical clamping. Furthermore, efforts to incorporate them onto curved surfaces such as exhaust pipes, pump housings, steam lines, mixing containers, reaction chambers, etc. require custom-built heat exchangers. This is costly and labor-intensive, in addition to presenting challenges in terms of space, thermal coupling, added weight and long-term reliability. Additive manufacturing technologies are beginning to address many of these issues by reducing part count in complex designs and the elimination of sub-assembly requirements. This work investigates the feasibility of utilizing such novel manufacturing routes for improving the manufacturing process of thermoelectric devices. Much of the research in thermoelectricity is primarily focused on improving thermoelectric material properties by developing of novel materials or finding ways to improve existing ones. Secondary to material development is improving the manufacturing process of TEGs to provide significant cost benefits. To improve the device fabrication process, this work explores additive manufacturing technologies to provide an integrated and scalable approach for TE device manufacturing directly onto engineering component surfaces. Additive manufacturing techniques like thermal spray and ink-dispenser printing are developed with the aim of improving the manufacturing process of TEGs. Subtractive manufacturing techniques like laser micromachining are also studied in detail. This includes the laser processing parameters for cutting the thermal spray materials efficiently by optimizing cutting speed and power while maintaining surface quality and interface properties. Key parameters are obtained from these experiments and used to develop a process that can be used to fabricate a working TEG directly onto the waste-heat component surface. A TEG module has been fabricated for the first time entirely by using thermal spray technology and laser micromachining. The target applications include automotive exhaust systems and other high-volume industrial waste heat sources. The application of TEGs for thermoelectrically powered sensors for Small Modular Reactors (SMRs) is presented. In conclusion, more ways to improve the fabrication process of TEGs are suggested.
Thermal valorization of post-consumer film waste in a bubbling bed gasifier
DOE Office of Scientific and Technical Information (OSTI.GOV)
Martínez-Lera, S., E-mail: susanamartinezlera@gmail.com; Torrico, J.; Pallarés, J.
2013-07-15
Highlights: • Film waste from packaging is a common waste, a fraction of which is not recyclable. • Gasification can make use of the high energy value of the non-recyclable fraction. • This waste and two reference polymers were gasified in a bubbling bed reactor. • This experimental research proves technical feasibility of the process. • It also analyzes impact of composition and ER on the performance of the plant. - Abstract: The use of plastic bags and film packaging is very frequent in manifold sectors and film waste is usually present in different sources of municipal and industrial wastes.more » A significant part of it is not suitable for mechanical recycling but could be safely transformed into a valuable gas by means of thermal valorization. In this research, the gasification of film wastes has been experimentally investigated through experiments in a fluidized bed reactor of two reference polymers, polyethylene and polypropylene, and actual post-consumer film waste. After a complete experimental characterization of the three materials, several gasification experiments have been performed to analyze the influence of the fuel and of equivalence ratio on gas production and composition, on tar generation and on efficiency. The experiments prove that film waste and analogue polymer derived wastes can be successfully gasified in a fluidized bed reactor, yielding a gas with a higher heating value in a range from 3.6 to 5.6 MJ/m{sup 3} and cold gas efficiencies up to 60%.« less
Code of Federal Regulations, 2014 CFR
2014-07-01
... the requirements of 40 CFR part 61, subpart FF, and the waste requirements for ethylene production... Waste Operations Background for Waste Requirements § 63.1092 What are the major differences between the requirements of 40 CFR part 61, subpart FF, and the waste requirements for ethylene production sources? The...
Code of Federal Regulations, 2013 CFR
2013-01-01
... 10 Energy 2 2013-01-01 2013-01-01 false Environmental report-land disposal of radioactive waste....62 Environmental report—land disposal of radioactive waste licensed under 10 CFR part 61. (a) Each applicant for issuance of a license for land disposal of radioactive waste pursuant to part 61 of this...
Code of Federal Regulations, 2011 CFR
2011-01-01
... 10 Energy 2 2011-01-01 2011-01-01 false Environmental report-land disposal of radioactive waste....62 Environmental report—land disposal of radioactive waste licensed under 10 CFR part 61. (a) Each applicant for issuance of a license for land disposal of radioactive waste pursuant to part 61 of this...
Code of Federal Regulations, 2014 CFR
2014-01-01
... 10 Energy 2 2014-01-01 2014-01-01 false Environmental report-land disposal of radioactive waste....62 Environmental report—land disposal of radioactive waste licensed under 10 CFR part 61. (a) Each applicant for issuance of a license for land disposal of radioactive waste pursuant to part 61 of this...
Code of Federal Regulations, 2012 CFR
2012-01-01
... 10 Energy 2 2012-01-01 2012-01-01 false Environmental report-land disposal of radioactive waste....62 Environmental report—land disposal of radioactive waste licensed under 10 CFR part 61. (a) Each applicant for issuance of a license for land disposal of radioactive waste pursuant to part 61 of this...
Code of Federal Regulations, 2010 CFR
2010-01-01
... 10 Energy 2 2010-01-01 2010-01-01 false Environmental report-land disposal of radioactive waste....62 Environmental report—land disposal of radioactive waste licensed under 10 CFR part 61. (a) Each applicant for issuance of a license for land disposal of radioactive waste pursuant to part 61 of this...
High Tensile Strength Amalgams for In-Space Fabrication and Repair
NASA Technical Reports Server (NTRS)
Grugel, Richard N.
2006-01-01
Amalgams are well known for their use in dental practice as a tooth filling material. They have a number of useful attributes that include room temperature fabrication, corrosion resistance, dimensional stability, and very good compressive strength. These properties well serve dental needs but, unfortunately, amalgams have extremely poor tensile strength, a feature that severely limits other potential applications. Improved material properties (strength and temperature) of amalgams may have application to the freeform fabrication of repairs or parts that might be necessary during an extended space mission. Advantages would include, but are not limited to: the ability to produce complex parts, a minimum number of processing steps, minimum crew interaction, high yield - minimum wasted material, reduced gravity compatibility, minimum final finishing, safety, and minimum power consumption. The work presented here shows how the properties of amalgams can be improved by changing particle geometries in conjunction with novel engineering metals.
Thermal and catalytic coprocessing of coal and waste materials
DOE Office of Scientific and Technical Information (OSTI.GOV)
Orr, E.C.; Tuntawiroon, W.; Ding, W.B.
1995-12-31
Coprocessing of coal with waste materials to produce liquid fuels with emphasis on finding reasonable reaction pathways and catalysts for such processing is presently the subject of intensive investigation. Polymer wastes such as polyethylene, polystyrene, polypropylene and used rubber tires are not naturally degraded over time. More than 22 million tons of plastic waste are annually discarded in landfills and over 75 percent of used rubber tires are similarly treated. In order to obtain distillate liquids or petroleum compatible refined products from coal, addition of hydrogen is necessary. A possible method for hydrogen addition is coprocessing of coal with polymericmore » waste materials since these latter materials contain hydrogen at levels much higher than are found in coal. The breakdown of waste rubber tires is interesting because the liquids derived may prove to be important as a coal dissolution and/or hydrogen donor solvent. Recently, Badger and coworkers reported that hydrogenated tire oils (hydrogenated in the presence of CoMo catalyst) were effective for the dissolution of coal. Studies on the coprocessing of coal and waste materials have only recently been done intensively. Limited data are available on reaction conditions and catalytic effects for processing coal mixed with post-consumer wastes. The purpose of the present study was to determine the effects of reaction temperature, pressure, catalysts, and mixture ratio on the coprocessing of coal and waste materials.« less
Apparatus for the processing of solid mixed waste containing radioactive and hazardous materials
Gotovchikov, Vitaly T.; Ivanov, Alexander V.; Filippov, Eugene A.
1999-03-16
Apparatus for the continuous heating and melting of a solid mixed waste bearing radioactive and hazardous materials to form separate metallic, slag and gaseous phases for producing compact forms of the waste material to facilitate disposal includes a copper split water-cooled (cold) crucible as a reaction vessel for receiving the waste material. The waste material is heated by means of the combination oaf plasma torch directed into the open upper portion of the cold crucible and an electromagnetic flux produced by induction coils disposed about the crucible which is transparent to electromagnetic fields. A metallic phase of the waste material is formed in a lower portion of the crucible and is removed in the form of a compact ingot suitable for recycling and further processing. A glass-like, non-metallic slag phase containing radioactive elements is also formed in the crucible and flows out of the open upper portion of the crucible into a slag ingot mold for disposal. The decomposition products of the organic and toxic materials are incinerated and converted to environmentally safe gases in the melter.
Processing of solid mixed waste containing radioactive and hazardous materials
Gotovchikov, Vitaly T.; Ivanov, Alexander V.; Filippov, Eugene A.
1998-05-12
Apparatus for the continuous heating and melting of a solid mixed waste bearing radioactive and hazardous materials to form separate metallic, slag and gaseous phases for producing compact forms of the waste material to facilitate disposal includes a copper split water-cooled (cold) crucible as a reaction vessel for receiving the waste material. The waste material is heated by means of the combination of a plasma torch directed into the open upper portion of the cold crucible and an electromagnetic flux produced by induction coils disposed about the crucible which is transparent to electromagnetic fields. A metallic phase of the waste material is formed in a lower portion of the crucible and is removed in the form of a compact ingot suitable for recycling and further processing. A glass-like, non-metallic slag phase containing radioactive elements is also formed in the crucible and flows out of the open upper portion of the crucible into a slag ingot mold for disposal. The decomposition products of the organic and toxic materials are incinerated and converted to environmentally safe gases in the melter.
Apparatus for the processing of solid mixed waste containing radioactive and hazardous materials
Gotovchikov, V.T.; Ivanov, A.V.; Filippov, E.A.
1999-03-16
Apparatus for the continuous heating and melting of a solid mixed waste bearing radioactive and hazardous materials to form separate metallic, slag and gaseous phases for producing compact forms of the waste material to facilitate disposal includes a copper split water-cooled (cold) crucible as a reaction vessel for receiving the waste material. The waste material is heated by means of the combination of a plasma torch directed into the open upper portion of the cold crucible and an electromagnetic flux produced by induction coils disposed about the crucible which is transparent to electromagnetic fields. A metallic phase of the waste material is formed in a lower portion of the crucible and is removed in the form of a compact ingot suitable for recycling and further processing. A glass-like, non-metallic slag phase containing radioactive elements is also formed in the crucible and flows out of the open upper portion of the crucible into a slag ingot mold for disposal. The decomposition products of the organic and toxic materials are incinerated and converted to environmentally safe gases in the melter. 6 figs.
Processing of solid mixed waste containing radioactive and hazardous materials
Gotovchikov, V.T.; Ivanov, A.V.; Filippov, E.A.
1998-05-12
Apparatus for the continuous heating and melting of a solid mixed waste bearing radioactive and hazardous materials to form separate metallic, slag and gaseous phases for producing compact forms of the waste material to facilitate disposal includes a copper split water-cooled (cold) crucible as a reaction vessel for receiving the waste material. The waste material is heated by means of the combination of a plasma torch directed into the open upper portion of the cold crucible and an electromagnetic flux produced by induction coils disposed about the crucible which is transparent to electromagnetic fields. A metallic phase of the waste material is formed in a lower portion of the crucible and is removed in the form of a compact ingot suitable for recycling and further processing. A glass-like, non-metallic slag phase containing radioactive elements is also formed in the crucible and flows out of the open upper portion of the crucible into a slag ingot mold for disposal. The decomposition products of the organic and toxic materials are incinerated and converted to environmentally safe gases in the melter. 6 figs.
40 CFR 273.8 - Applicability-household and conditionally exempt small quantity generator waste.
Code of Federal Regulations, 2011 CFR
2011-07-01
... managing the wastes listed below may, at their option, manage them under the requirements of this part: (1... section together with universal waste regulated under this part must manage the commingled waste under the...
40 CFR 273.8 - Applicability-household and conditionally exempt small quantity generator waste.
Code of Federal Regulations, 2012 CFR
2012-07-01
... managing the wastes listed below may, at their option, manage them under the requirements of this part: (1... section together with universal waste regulated under this part must manage the commingled waste under the...
40 CFR 273.8 - Applicability-household and conditionally exempt small quantity generator waste.
Code of Federal Regulations, 2010 CFR
2010-07-01
... managing the wastes listed below may, at their option, manage them under the requirements of this part: (1... section together with universal waste regulated under this part must manage the commingled waste under the...
40 CFR 273.8 - Applicability-household and conditionally exempt small quantity generator waste.
Code of Federal Regulations, 2013 CFR
2013-07-01
... managing the wastes listed below may, at their option, manage them under the requirements of this part: (1... section together with universal waste regulated under this part must manage the commingled waste under the...
40 CFR 273.8 - Applicability-household and conditionally exempt small quantity generator waste.
Code of Federal Regulations, 2014 CFR
2014-07-01
... managing the wastes listed below may, at their option, manage them under the requirements of this part: (1... section together with universal waste regulated under this part must manage the commingled waste under the...
Code of Federal Regulations, 2013 CFR
2013-07-01
...)(3) for acute hazardous waste, or § 261.5(g)(3) for hazardous waste. (e) An unwanted material that is... 40 Protection of Environment 27 2013-07-01 2013-07-01 false Making the hazardous waste....210 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES (CONTINUED...
Code of Federal Regulations, 2014 CFR
2014-07-01
...)(3) for acute hazardous waste, or § 261.5(g)(3) for hazardous waste. (e) An unwanted material that is... 40 Protection of Environment 26 2014-07-01 2014-07-01 false Making the hazardous waste....210 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES (CONTINUED...
Code of Federal Regulations, 2012 CFR
2012-07-01
...)(3) for acute hazardous waste, or § 261.5(g)(3) for hazardous waste. (e) An unwanted material that is... 40 Protection of Environment 27 2012-07-01 2012-07-01 false Making the hazardous waste....210 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES (CONTINUED...
Code of Federal Regulations, 2010 CFR
2010-07-01
...)(3) for acute hazardous waste, or § 261.5(g)(3) for hazardous waste. (e) An unwanted material that is... 40 Protection of Environment 25 2010-07-01 2010-07-01 false Making the hazardous waste....210 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES (CONTINUED...
Code of Federal Regulations, 2011 CFR
2011-07-01
...)(3) for acute hazardous waste, or § 261.5(g)(3) for hazardous waste. (e) An unwanted material that is... 40 Protection of Environment 26 2011-07-01 2011-07-01 false Making the hazardous waste....210 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES (CONTINUED...
AN EVALUATION OF FACTORS AFFECTING THE SOLIDIFICATION/STABILIZATION OF HEAVY METAL SLUDGE
Solidification/stabilization (SIS) of hazardous waste involves mixing the waste with a binder material to enhance the physical properties of the waste and to immobilize contaminants that may be detrimental to the environment. Many hazardous wastes contain materials that are know...
Haralur, Satheesh B.; Al-Qahtani, Ali S.; Al-Qarni, Marie M.; Al-Homrany, Rami M.; Aboalkhair, Ayyob E.; Madalakote, Sujatha S.
2015-01-01
Aim: To study the awareness, attitude, practice and facilities among the different categories of dental laboratories in Abha city. Materials and Methods: A total of 80 dental technicians were surveyed in the study. The dental laboratories included in the study were teaching institute (Group I), Government Hospital (Group II), Private Dental Clinic (Group III) and Independent laboratory (Group IV). The pre-tested anonymous questionnaire was used to understand knowledge, attitude, facilities, practice and orientation regarding biomedical waste management. Results: The knowledge of biomedical waste categories, colour coding and segregation was better among Group I (55-65%) and Group II (65-75%). The lowest standard of waste disposal was practiced at Group IV (15-20%) and Group III (25-35%). The availability of disposal facilities was poor at Group IV. The continuous education on biomedical waste management lacked in all the Groups. Conclusion: The significant improvement in disposal facilities was required at Group III and Group IV laboratories. All dental technicians were in need of regular training of biomedical waste management. Clinical Significance: The dental laboratories are an integral part of dental practice. The dental laboratories are actively involved in the generation, handling and disposal of biomedical waste. Hence, it is important to assess the biomedical waste management knowledge, attitude, facilities and practice among different categories of dental laboratories. PMID:26962373
NASA Technical Reports Server (NTRS)
Hyland, R. E.; Wohl, M. L.; Finnegan, P. M.
1973-01-01
A preliminary study was conducted of the feasibility of space disposal of the actinide class of radioactive waste material. This waste was assumed to contain 1 and 0.1 percent residual fission products, since it may not be feasible to completely separate the actinides. The actinides are a small fraction of the total waste but they remain radioactive much longer than the other wastes and must be isolated from human encounter for tens of thousands of years. Results indicate that space disposal is promising but more study is required, particularly in the area of safety. The minimum cost of space transportation would increase the consumer electric utility bill by the order of 1 percent for earth escape and 3 percent for solar escape. The waste package in this phase of the study was designed for normal operating conditions only; the design of next phase of the study will include provisions for accident safety. The number of shuttle launches per year required to dispose of all U.S. generated actinide waste with 0.1 percent residual fission products varies between 3 and 15 in 1985 and between 25 and 110 by 2000. The lower values assume earth escape (solar orbit) and the higher values are for escape from the solar system.
Environmental Impact Statement Addressing Campus Development at Fort George Meade, Maryland
2010-09-01
II, and III) Hazardous Materials and Wastes No impacts on hazardous materials and wastes would be expected. Short- and long-term, negligible...adverse impacts would be expected from generation of hazardous materials and petroleum products and wastes during construction and operational...activities. No impacts on asbestos-containing materials , radon, lead-based paint, pesticides, or polychlorinated biphenyls would be expected. Short
DOE Office of Scientific and Technical Information (OSTI.GOV)
U.S. Department of Energy, National Nuclear Security Administration Nevada Operations Office
This Corrective Action Investigation Plan contains the U.S. Department of Energy (DOE), National Nuclear Security Administration Nevada Operations Office's approach to collect the data necessary to evaluate corrective action alternatives appropriate for the closure of Corrective Action Unit (CAU) 527, Horn Silver Mine, Nevada Test Site, Nevada, under the Federal Facility Agreement and Consent Order. Corrective Action Unit 527 consists of one Corrective Action Site (CAS): 26-20-01, Contaminated Waste Dump No.1. The site is located in an abandoned mine site in Area 26 (which is the most arid part of the NTS) approximately 65 miles northwest of Las Vegas. Historicalmore » documents may refer to this site as CAU 168, CWD-1, the Wingfield mine (or shaft), and the Wahmonie mine (or shaft). Historical documentation indicates that between 1959 and the 1970s, nonliquid classified material and unclassified waste was placed in the Horn Silver Mine's shaft. Some of the waste is known to be radioactive. Documentation indicates that the waste is present from 150 feet to the bottom of the mine (500 ft below ground surface). This CAU is being investigated because hazardous constituents migrating from materials and/or wastes disposed of in the Horn Silver Mine may pose a threat to human health and the environment as well as to assess the potential impacts associated with any potential releases from the waste. The results of this field investigation will support a defensible evaluation of corrective action alternatives in the corrective action decision document.« less
Timing of Getter Material Addition in Cementitious Wasteforms
NASA Astrophysics Data System (ADS)
Lawter, A.; Qafoku, N. P.; Asmussen, M.; Neeway, J.; Smith, G. L.
2015-12-01
A cementitious waste form, Cast Stone, is being evaluated as a possible supplemental immobilization technology for the Hanford sites's low activity waste (LAW), which contains radioactive 99Tc and 129I, as part of the tank waste cleanup mission. Cast Stone is made of a dry blend 47% blast furnace slag, 45% fly ash, and 8% ordinary Portland cement, mixed with a low-activity waste (LAW). To improve the retention of Tc and/or I in Cast Stone, materials with a high affinity for Tc and/or I, termed "getters," can be added to provide a stable domain for the radionuclides of concern. Previous testing conducted with a variety of getters has identified Tin(II)-Apatite and Silver Exchanged Zeolite as promising candidates for Tc and I, respectively. Investigation into the sequence in which getters are added to Cast Stone was performed following two methods: 1) adding getters to the Cast Stone dry blend, and then mixing with liquid waste, and 2) adding getters to the liquid waste first, followed by addition of the Cast Stone dry blend. Cast Stone monolith samples were prepared with each method and leach tests, following EPA method 1315, were conducted in either distilled water or simulated vadose zone porewater for a period of up to 63 days. The leachate was analyzed for Tc, I, Na, NO3-, NO2- and Cr with ICP-MS, ICP-OES and ion chromatography and the results indicated that the Cast Stone with getter addition in the dry blend mix (method 1) has lower rates of Tc and I leaching. The mechanisms of radionuclide release from the Cast Stone were also investigated with a variety of solid phase characterization techniques of the monoliths before and after leaching, such as XRD, SEM/EDS, TEM/SAED and other spectroscopic techniques.
Energy-saving drying and its application
NASA Astrophysics Data System (ADS)
Kovbasyuk, V. I.
2015-09-01
Superheated steam is efficiently applied as a coolant for the intensification of drying, which is an important component of many up-to-date technologies. However, traditional drying is extremely energy consuming, and many drying apparatus are environmentally unfriendly. Thus, it is important to implement the proposed drying technique using superheated steam under pressure significantly higher than the atmospheric one with subsequent steam transfer for use in a turbine for electric power generation as a compensation of energy costs for drying. This paper includes a brief thermodynamic analysis of such a technique, its environmental advantages, and possible benefits of the use of wet wastes and obtaining high-quality fuels from wet raw materials. A scheme is developed for the turbine protection from impurities that can occur in the steam at drying. Potential advantage of the technique are also the absence of heating surfaces that are in contact with wet media, the absence of the emissions to the atmosphere, and the use of low potential heat for desalination and the purification of water. The new drying technique can play an extremely important part in the implementation in the field of thermal destruction of anthropogenic wastes. In spite of the promotion of waste sorting to obtain valuable secondary raw materials, the main problem of big cities is nonutilizable waste, which makes not less than 85% of the starting quantity of waste. This can only be totally solved by combustion, which even more relates to the sewage sludge utilization. The wastes can be safely and efficiently combusted only provided that they are free of moisture. Combustion temperature optimization makes possible full destruction of dioxins and their toxic analogues.
Li, Hua; Nitivattananon, Vilas; Li, Peng
2015-05-01
This study is to quantify and objectively evaluate the extent of environmental health risks from three waste treatment options suggested by the national municipal solid waste management enhancing strategy (No [2011] 9 of the State Council, promulgated on 19 April 2011), which includes sanitary landfill, waste-to-energy incineration and compost, together with the material recovery facility through a case study in Zhangqiu City of China. It addresses potential chronic health risks from air emissions to residential receptors in the impacted area. It combines field survey, analogue survey, design documents and life cycle inventory methods in defining the source strength of chemicals of potential concern. The modelling of life cycle inventory and air dispersion is via integrated waste management(IWM)-2 and Screening Air Dispersion Model (Version 3.0) (SCREEN3). The health risk assessment is in accordance with United States Environmental Protection Agency guidance Risk Assessment Guidance for Superfund (RAGS), Volume I: Human Health Evaluation Manual (Part F, Supplemental Guidance for Inhalation Risk Assessment). The exposure concentration is based on long-term exposure to the maximum ground level contaminant in air under the 'reasonable worst situation' emissions and then directly compared with reference for concentration and unit risk factor/cancer slope factor derived from the national air quality standard (for a conventional pollutant) and toxicological studies (for a specific pollutant). Results from this study suggest that the option of compost with material recovery facility treatment may pose less negative health impacts than other options; the sensitivity analysis shows that the landfill integrated waste management collection rate has a great influence on the impact results. Further investigation is needed to validate or challenge the findings of this study. © The Author(s) 2015.
Analysis and Modeling of Boundary Layer Separation Method (BLSM).
Pethő, Dóra; Horváth, Géza; Liszi, János; Tóth, Imre; Paor, Dávid
2010-09-01
Nowadays rules of environmental protection strictly regulate pollution material emission into environment. To keep the environmental protection laws recycling is one of the useful methods of waste material treatment. We have developed a new method for the treatment of industrial waste water and named it boundary layer separation method (BLSM). We apply the phenomena that ions can be enriched in the boundary layer of the electrically charged electrode surface compared to the bulk liquid phase. The main point of the method is that the boundary layer at correctly chosen movement velocity can be taken out of the waste water without being damaged, and the ion-enriched boundary layer can be recycled. Electrosorption is a surface phenomenon. It can be used with high efficiency in case of large electrochemically active surface of electrodes. During our research work two high surface area nickel electrodes have been prepared. The value of electrochemically active surface area of electrodes has been estimated. The existence of diffusion part of the double layer has been experimentally approved. The electrical double layer capacity has been determined. Ion transport by boundary layer separation has been introduced. Finally we have tried to estimate the relative significance of physical adsorption and electrosorption.
System for chemically digesting low level radioactive, solid waste material
Cowan, Richard G.; Blasewitz, Albert G.
1982-01-01
An improved method and system for chemically digesting low level radioactive, solid waste material having a high through-put. The solid waste material is added to an annular vessel (10) substantially filled with concentrated sulfuric acid. Concentrated nitric acid or nitrogen dioxide is added to the sulfuric acid within the annular vessel while the sulfuric acid is reacting with the solid waste. The solid waste is mixed within the sulfuric acid so that the solid waste is substantilly fully immersed during the reaction. The off gas from the reaction and the products slurry residue is removed from the vessel during the reaction.
DOE Office of Scientific and Technical Information (OSTI.GOV)
David Burnett; Harold Vance
2007-08-31
The goal of our project is to develop innovative processes and novel cleaning agents for water treatment facilities designed to remove fouling materials and restore micro-filter and reverse osmosis (RO) membrane performance. This project is part of Texas A&M University's comprehensive study of the treatment and reuse of oilfield brine for beneficial purposes. Before waste water can be used for any beneficial purpose, it must be processed to remove contaminants, including oily wastes such as residual petroleum hydrocarbons. An effective way of removing petroleum from brines is the use of membrane filters to separate oily waste from the brine. Texasmore » A&M and its partners have developed highly efficient membrane treatment and RO desalination for waste water including oil field produced water. We have also developed novel and new cleaning agents for membrane filters utilizing environmentally friendly materials so that the water from the treatment process will meet U.S. EPA drinking water standards. Prototype micellar cleaning agents perform better and use less clean water than alternate systems. While not yet optimized, the new system restores essentially complete membrane flux and separation efficiency after cleaning. Significantly the amount of desalinated water that is required to clean the membranes is reduced by more than 75%.« less
Formation and corrosion of a 410 SS/ceramic composite
DOE Office of Scientific and Technical Information (OSTI.GOV)
Chen, X.; Ebert, W. L.; Indacochea, J. E.
This study evaluates the possible use of alloy/ceramic composite waste forms to immobilize metallic and oxide waste streams generated during the electrochemical reprocessing of spent reactor fuel in a single waste form. A representative composite material AOC410 was made to evaluate the microstructure and corrosion behavior at alloy/ceramic interfaces by reacting 410 stainless steel with Zr, Mo, and a mixture of lanthanide oxides. Essentially all of the Zr reacted with lanthanide oxides to form lanthanide zirconate, which combined with the remaining lanthanide oxides to form a porous ceramic network encapsulated by alloy as a composite puck. Excess alloy formed amore » metal bead on top of the composite. The alloys in the composite and bead were both mixture of martensite grains and ferrite grains with carbide precipitates. FeCrMo intermetallic phases also precipitated in the ferrite grains in the composite part. Ferrite surrounding carbides was sensitized and the least corrosion resistant in electrochemical corrosion tests conducted in an acidic brine electrolyte; ferrite neighboring martensite grains and intermetallics corroded galvanically. The lanthanide oxide domains dissolved chemically, but lanthanide zirconate domains did not dissolve. The presence of oxide phases did not affect corrosion of the neighboring alloy phases. These results suggest the longterm corrosion of a composite waste form can be evaluated by using separate material degradation models for the alloy and ceramic phases.« less
Code of Federal Regulations, 2014 CFR
2014-07-01
... comparative data to other methods and SRM materials are presented in Reference 23 of Section 16.0. 13... Plasma, Anal. Chem. 52:1965, 1980. 20. Deming, S.N. and S.L. Morgan. Experimental Design for Quality and... Statistical Designs, 9941 Rowlett, Suite 6, Houston, TX 77075, 1989. 21. Winefordner, J.D., Trace Analysis...
Code of Federal Regulations, 2013 CFR
2013-07-01
... comparative data to other methods and SRM materials are presented in Reference 23 of Section 16.0. 13... Plasma, Anal. Chem. 52:1965, 1980. 20. Deming, S.N. and S.L. Morgan. Experimental Design for Quality and... Statistical Designs, 9941 Rowlett, Suite 6, Houston, TX 77075, 1989. 21. Winefordner, J.D., Trace Analysis...
Code of Federal Regulations, 2012 CFR
2012-07-01
... comparative data to other methods and SRM materials are presented in Reference 23 of Section 16.0. 13... Plasma, Anal. Chem. 52:1965, 1980. 20. Deming, S.N. and S.L. Morgan. Experimental Design for Quality and... Statistical Designs, 9941 Rowlett, Suite 6, Houston, TX 77075, 1989. 21. Winefordner, J.D., Trace Analysis...
Youth Solid Waste Educational Materials List, November 1991.
ERIC Educational Resources Information Center
Cornell Univ., Ithaca, NY. Cooperative Extension Service.
This guide provides a brief description and ordering information for approximately 300 educational materials for grades K-12 on the subject of solid waste. The materials cover a variety of environmental issues and actions related to solid waste management. Entries are divided into five sections including audiovisual programs, books, magazines,…
Abd Elrahman, Mohamed; Sikora, Pawel; Rucinska, Teresa; Horszczaruk, Elzbieta
2017-01-01
Recently, the recycling of waste glass has become a worldwide issue in the reduction of waste and energy consumption. Waste glass can be utilized in construction materials, and understanding its effects on material properties is crucial in developing advanced materials. In this study, recycled crushed and expanded glasses are used as lightweight aggregates for concrete, and their relation to the material characteristics and properties is investigated using several approaches. Lightweight concrete specimens containing only crushed and expanded waste glass as fine aggregates are produced, and their pore and structural characteristics are examined using image-based methods, such as scanning electron microscopy (SEM), X-ray computed tomography (CT), and automated image analysis (RapidAir). The thermal properties of the materials are measured using both Hot Disk and ISOMET devices to enhance measurement accuracy. Mechanical properties are also evaluated, and the correlation between material characteristics and properties is evaluated. As a control group, a concrete specimen with natural fine sand is prepared, and its characteristics are compared with those of the specimens containing crushed and expanded waste glass aggregates. The obtained results support the usability of crushed and expanded waste glass aggregates as alternative lightweight aggregates. PMID:29186854
Chung, Sang-Yeop; Abd Elrahman, Mohamed; Sikora, Pawel; Rucinska, Teresa; Horszczaruk, Elzbieta; Stephan, Dietmar
2017-11-25
Recently, the recycling of waste glass has become a worldwide issue in the reduction of waste and energy consumption. Waste glass can be utilized in construction materials, and understanding its effects on material properties is crucial in developing advanced materials. In this study, recycled crushed and expanded glasses are used as lightweight aggregates for concrete, and their relation to the material characteristics and properties is investigated using several approaches. Lightweight concrete specimens containing only crushed and expanded waste glass as fine aggregates are produced, and their pore and structural characteristics are examined using image-based methods, such as scanning electron microscopy (SEM), X-ray computed tomography (CT), and automated image analysis (RapidAir). The thermal properties of the materials are measured using both Hot Disk and ISOMET devices to enhance measurement accuracy. Mechanical properties are also evaluated, and the correlation between material characteristics and properties is evaluated. As a control group, a concrete specimen with natural fine sand is prepared, and its characteristics are compared with those of the specimens containing crushed and expanded waste glass aggregates. The obtained results support the usability of crushed and expanded waste glass aggregates as alternative lightweight aggregates.
Method of draining water through a solid waste site without leaching
Treat, Russell L.; Gee, Glendon W.; Whyatt, Greg A.
1993-01-01
The present invention is a method of preventing water from leaching solid waste sites by preventing atmospheric precipitation from contacting waste as the water flows through a solid waste site. The method comprises placing at least one drain hole through the solid waste site. The drain hole is seated to prevent waste material from entering the drain hole, and the solid waste site cover material is layered and graded to direct water to flow toward the drain hole and to soil beneath the waste site.
Method of draining water through a solid waste site without leaching
Treat, R.L.; Gee, G.W.; Whyatt, G.A.
1993-02-02
The present invention is a method of preventing water from leaching solid waste sites by preventing atmospheric precipitation from contacting waste as the water flows through a solid waste site. The method comprises placing at least one drain hole through the solid waste site. The drain hole is seated to prevent waste material from entering the drain hole, and the solid waste site cover material is layered and graded to direct water to flow toward the drain hole and to soil beneath the waste site.
Carbon speciation in ash, residual waste and contaminated soil by thermal and chemical analyses.
Kumpiene, Jurate; Robinson, Ryan; Brännvall, Evelina; Nordmark, Désirée; Bjurström, Henrik; Andreas, Lale; Lagerkvist, Anders; Ecke, Holger
2011-01-01
Carbon in waste can occur as inorganic (IC), organic (OC) and elemental carbon (EC) each having distinct chemical properties and possible environmental effects. In this study, carbon speciation was performed using thermogravimetric analysis (TGA), chemical degradation tests and the standard total organic carbon (TOC) measurement procedures in three types of waste materials (bottom ash, residual waste and contaminated soil). Over 50% of the total carbon (TC) in all studied materials (72% in ash and residual waste, and 59% in soil) was biologically non-reactive or EC as determined by thermogravimetric analyses. The speciation of TOC by chemical degradation also showed a presence of a non-degradable C fraction in all materials (60% of TOC in ash, 30% in residual waste and 13% in soil), though in smaller amounts than those determined by TGA. In principle, chemical degradation method can give an indication of the presence of potentially inert C in various waste materials, while TGA is a more precise technique for C speciation, given that waste-specific method adjustments are made. The standard TOC measurement yields exaggerated estimates of organic carbon and may therefore overestimate the potential environmental impacts (e.g. landfill gas generation) of waste materials in a landfill environment. Copyright © 2010 Elsevier Ltd. All rights reserved.
Use of selected waste materials in concrete mixes.
Batayneh, Malek; Marie, Iqbal; Asi, Ibrahim
2007-01-01
A modern lifestyle, alongside the advancement of technology has led to an increase in the amount and type of waste being generated, leading to a waste disposal crisis. This study tackles the problem of the waste that is generated from construction fields, such as demolished concrete, glass, and plastic. In order to dispose of or at least reduce the accumulation of certain kinds of waste, it has been suggested to reuse some of these waste materials to substitute a percentage of the primary materials used in the ordinary portland cement concrete (OPC). The waste materials considered to be recycled in this study consist of glass, plastics, and demolished concrete. Such recycling not only helps conserve natural resources, but also helps solve a growing waste disposal crisis. Ground plastics and glass were used to replace up to 20% of fine aggregates in concrete mixes, while crushed concrete was used to replace up to 20% of coarse aggregates. To evaluate these replacements on the properties of the OPC mixes, a number of laboratory tests were carried out. These tests included workability, unit weight, compressive strength, flexural strength, and indirect tensile strength (splitting). The main findings of this investigation revealed that the three types of waste materials could be reused successfully as partial substitutes for sand or coarse aggregates in concrete mixtures.
DOE Office of Scientific and Technical Information (OSTI.GOV)
Carter, E.
A new class of grout material based on molten wax offers a dramatic improvement in permeation grouting performance. This new material makes a perfect in situ containment of buried radioactive waste both feasible and cost effective. This paper describes various ways the material can be used to isolate buried waste in situ. Potential applications described in the paper include buried radioactive waste in deep trenches, deep shafts, Infiltration trenches, and large buried objects. Use of molten wax for retrieval of waste is also discussed. Wax can also be used for retrieval of air sensitive materials or drummed waste. This papermore » provides an analysis of the methods of application and the expected performance and cost of several potential projects. (authors)« less
E-waste management and resources recovery in France.
Vadoudi, Kiyan; Kim, Junbeum; Laratte, Bertrand; Lee, Seung-Jin; Troussier, Nadège
2015-10-01
There are various issues of concern regarding electronic waste management, such as the toxicity of hazardous materials and the collection, recycling and recovery of useful resources. To understand the fate of electronic waste after collection and recycling, a products and materials flow analysis should be performed. This is a critical need, as material resources are becoming increasingly scarce and recycling may be able to provide secondary sources for new materials in the future. In this study, we investigate electronic waste systems, specifically the resource recovery or recycling aspects, as well as mapping electronic waste flows based on collection data in France. Approximately 1,588,453 t of new electrical and electronic equipment were sold in the French market in 2010. Of this amount, 430,000 t of electronic waste were collected, with the remaining 1,128,444 t remaining in stock. Furthermore, the total recycled amounts were 354,106 t and 11,396 t, respectively. The main electronic waste materials were ferrous metals (37%), plastic (22%), aluminium (12%), copper (11%) and glass (7%). This study will contribute to developing sustainable electronic waste and resource recycling systems in France. © The Author(s) 2015.
NASA Astrophysics Data System (ADS)
Perdana, Mastariyanto; Prastiawan; Hadi, Syafrul
2017-12-01
The garbage issue becomes a very serious problem at the moment. Much research has been done to make waste into useful materials. One of the utilization of waste is as the basic material of composite material that can be applied in the field of engineering. Some of the wastes generated are styrofoam, bagasse and eggshell. Styrofoam, bagasse and eggshell can be applied to a composite material. Styrofoam serves as a composite binder material while the bagasse and eggshells serve as a reinforcement. Volume fraction between styrofoam, bagasse and eggshell are 80%:10%:10%, 70%:15%:15%, 60%:20%:20%, and 50%:25%:25%. The aims of research are determine the mechanical properties of composite material based waste materials from styrofoam, bagasse and eggshell. Mechanical properties tested in this study are bending strength and toughness of composite materials. The results showed bending strength of composite for each volume fraction of 80%:10%:10%, 70%:15%:15%, 60%:20%:20%, and 50%:25%:25% are 5.07 MPa, 8.45 MPa, 8.68 MPa, and 11.01 MPa, respectively. Toughness of composite materials for each volume fraction of 80%:10%:10%, 70%:15%:15%, 60%:20%:20%, and 50%:25%:25% are 0.33 J/mm2, 0.42 J/mm2, 0.75 J/mm2, and 0.75 J/mm2, respectively. Composite materials based on waste materials from styrofoam, bagasse and eggshell can be used as an alternative material for drone frames.
DOE Office of Scientific and Technical Information (OSTI.GOV)
Vienna, John D.; Todd, Terry A.; Gray, Kimberly D.
The U.S. Department of Energy, Office of Nuclear Energy has chartered an effort to develop technologies to enable safe and cost effective recycle of commercial used nuclear fuel (UNF) in the U.S. Part of this effort includes the evaluation of exiting waste management technologies for effective treatment of wastes in the context of current U.S. regulations and development of waste forms and processes with significant cost and/or performance benefits over those existing. This study summarizes the results of these ongoing efforts with a focus on the highly radioactive primary waste streams. The primary streams considered and the recommended waste formsmore » include: •Tritium separated from either a low volume gas stream or a high volume water stream. The recommended waste form is low-water cement in high integrity containers. •Iodine-129 separated from off-gas streams in aqueous processing. There are a range of potentially suitable waste forms. As a reference case, a glass composite material (GCM) formed by the encapsulation of the silver Mordenite (AgZ) getter material in a low-temperature glass is assumed. A number of alternatives with distinct advantages are also considered including a fused silica waste form with encapsulated nano-sized AgI crystals. •Carbon-14 separated from LWR fuel treatment off-gases and immobilized as a CaCO3 in a cement waste form. •Krypton-85 separated from LWR and SFR fuel treatment off-gases and stored as a compressed gas. •An aqueous reprocessing high-level waste (HLW) raffinate waste which is immobilized by the vitrification process in one of three forms: a single phase borosilicate glass, a borosilicate based glass ceramic, or a multi-phased titanate ceramic [e.g., synthetic rock (Synroc)]. •An undissolved solids (UDS) fraction from aqueous reprocessing of LWR fuel that is either included in the borosilicate HLW glass or is immobilized in the form of a metal alloy in the case of glass ceramics or titanate ceramics. •Zirconium-based LWR fuel cladding hulls and stainless steel (SS) fuel assembly hardware that are washed and super-compacted for disposal or as an alternative Zr purification and reuse (or disposal as low-level waste, LLW) by reactive gas separations. •Electrochemical process salt HLW which is immobilized in a glass bonded Sodalite waste form known as the ceramic waste form (CWF). •Electrochemical process UDS and SS cladding hulls which are melted into an iron based alloy waste form. Mass and volume estimates for each of the recommended waste forms based on the source terms from a representative flowsheet are reported.« less
Using shredded waste tires as a lightweight fill material for road subgrades : summary report
DOT National Transportation Integrated Search
1994-04-01
Waste tires have been a disposal problem in the past and are continuing to accumulate throughout the U.S. today. Using shredded waste tires as a lightweight fill material for road construction has proven to be a beneficial use of this waste product. ...
Using shredded waste tires as a lightweight fill material for road subgrades. Summary report
DOT National Transportation Integrated Search
1994-04-01
Waste tires have been a disposal problem in the past and are continuing to accumulate throughout the U.S. today. Using shredded waste tires as a lightweight fill material for road construction has proven to be a beneficial use of this waste product. ...
Challenges in disposing of anthrax waste.
Lesperance, Ann M; Stein, Steve; Upton, Jaki F; Toomey, Chris
2011-09-01
Disasters often create large amounts of waste that must be managed as part of both immediate response and long-term recovery. While many federal, state, and local agencies have debris management plans, these plans often do not address chemical, biological, and radiological contamination. The Interagency Biological Restoration Demonstration's (IBRD) purpose was to holistically assess all aspects of an anthrax incident and assist in the development of a plan for long-term recovery. In the case of wide-area anthrax contamination and the follow-on response and recovery activities, a significant amount of material would require decontamination and disposal. Accordingly, IBRD facilitated the development of debris management plans to address contaminated waste through a series of interviews and workshops with local, state, and federal representatives. The outcome of these discussions was the identification of 3 primary topical areas that must be addressed: planning, unresolved research questions, and resolving regulatory issues.
Challenges in Disposing of Anthrax Waste
DOE Office of Scientific and Technical Information (OSTI.GOV)
Lesperance, Ann M.; Stein, Steven L.; Upton, Jaki F.
2011-09-01
Disasters often create large amounts of waste that must be managed as part of both immediate response and long-term recovery. While many federal, state, and local agencies have debris management plans, these plans often do not address chemical, biological, and radiological contamination. The Interagency Biological Restoration Demonstration’s (IBRD) purpose was to holistically assess all aspects of an anthrax incident and assist the development of a plan for long-term recovery. In the case of wide-area anthrax contamination and the follow-on response and recovery activities, a significant amount of material will require decontamination and disposal. Accordingly, IBRD facilitated the development of debrismore » management plans to address contaminated waste through a series of interviews and workshops with local, state, and federal representatives. The outcome of these discussion was the identification of three primary topical areas that must be addressed: 1) Planning; 2) Unresolved research questions, and resolving regulatory issues.« less
Tanigaki, Nobuhiro; Ishida, Yoshihiro; Osada, Morihiro
2015-03-01
This study evaluates municipal solid waste co-gasification technology and a new solid waste management scheme, which can minimize final landfill amounts and maximize material recycled from waste. This new scheme is considered for a region where bottom ash and incombustibles are landfilled or not allowed to be recycled due to their toxic heavy metal concentration. Waste is processed with incombustible residues and an incineration bottom ash discharged from existent conventional incinerators, using a gasification and melting technology (the Direct Melting System). The inert materials, contained in municipal solid waste, incombustibles and bottom ash, are recycled as slag and metal in this process as well as energy recovery. Based on this new waste management scheme with a co-gasification system, a case study of municipal solid waste co-gasification was evaluated and compared with other technical solutions, such as conventional incineration, incineration with an ash melting facility under certain boundary conditions. From a technical point of view, co-gasification produced high quality slag with few harmful heavy metals, which was recycled completely without requiring any further post-treatment such as aging. As a consequence, the co-gasification system had an economical advantage over other systems because of its material recovery and minimization of the final landfill amount. Sensitivity analyses of landfill cost, power price and inert materials in waste were also conducted. The higher the landfill costs, the greater the advantage of the co-gasification system has. The co-gasification was beneficial for landfill cost in the range of 80 Euro per ton or more. Higher power prices led to lower operation cost in each case. The inert contents in processed waste had a significant influence on the operating cost. These results indicate that co-gasification of bottom ash and incombustibles with municipal solid waste contributes to minimizing the final landfill amount and has great possibilities maximizing material recovery and energy recovery from waste. Copyright © 2014 Elsevier Ltd. All rights reserved.
NASA Astrophysics Data System (ADS)
Appels, Willemijn M.; Ireson, Andrew M.; Barbour, S. Lee
2018-02-01
Mine waste rock dumps have highly variable flowpaths caused by contrasting textures and geometry of materials laid down during the 'plug dumping' process. Numerical experiments were conducted to investigate how these characteristics control unsaturated zone flow and transport. Hypothetical profiles of inner-lift structure were generated with multiple point statistics and populated with hydraulic parameters of a finer and coarser material. Early arrival of water and solutes at the bottom of the lifts was observed after spring snowmelt. The leaching efficiency, a measure of the proportion of a resident solute that is flushed out of the rock via infiltrating snowmelt or rainfall, was consistently high, but modified by the structure and texture of the lift. Under high rates of net percolation during snowmelt, preferential flow was generated in coarse textured part of the rock, and solutes in the fine textured parts of the rock remained stagnant. Under lower rates of net percolation during the summer and fall, finer materialswere flushed too, and the spatial variability of solute concentration in the lift was reduced. Layering of lifts leads to lower flow rates at depth, minimizing preferential flow and increased leaching of resident solutes. These findings highlight the limited role of large scale connected geometries on focusing flow and transport under dynamic surface net percolation conditions. As such, our findings agree with recent numerical results from soil studies with Gaussian connected geometries as well as recent experimental findings, emphasizing the dominant role of matrix flow and high leaching efficiency in large waste rock dumps.
NASA Astrophysics Data System (ADS)
Kolasiński, Piotr; Kolasińska, Ewa
2016-02-01
The effective waste heat recovery is one of the present-day challenges in the industry and power engineering. The energy systems dedicated for waste heat conversion into electricity are usually characterized by low efficiency and are complicated in the design. The possibility of waste heat recovery via thermoelectric materials may be an interesting alternative to the currently used technologies. In particular, due to their material characteristics, conducting polymers may be competitive when compared with the power machinery and equipment. These materials can be used in a wide range of the geometries e.g. the bulk products, thin films, pristine form or composites and the others. In this article, the authors present selected issues related to the mathematical and thermodynamic description of the heat transfer processes in the thermoelectric materials dedicated for the waste heat recovery. The link of these models with electrical properties of the material and a material solution based on a conducting polymer have also been presented in this paper.
Naroznova, Irina; Møller, Jacob; Scheutz, Charlotte
2016-04-01
This study is dedicated to characterising the chemical composition and biochemical methane potential (BMP) of individual material fractions in untreated Danish source-separated organic household waste (SSOHW). First, data on SSOHW in different countries, available in the literature, were evaluated and then, secondly, laboratory analyses for eight organic material fractions comprising Danish SSOHW were conducted. No data were found in the literature that fully covered the objectives of the present study. Based on laboratory analyses, all fractions were assigned according to their specific properties in relation to BMP, protein content, lipids, lignocellulose biofibres and easily degradable carbohydrates (carbohydrates other than lignocellulose biofibres). The three components in lignocellulose biofibres, i.e. lignin, cellulose and hemicellulose, were differentiated, and theoretical BMP (TBMP) and material degradability (BMP from laboratory incubation tests divided by TBMP) were expressed. Moreover, the degradability of lignocellulose biofibres (the share of volatile lignocellulose biofibre solids degraded in laboratory incubation tests) was calculated. Finally, BMP for average SSOHW composition in Denmark (untreated) was calculated, and the BMP contribution of the individual material fractions was then evaluated. Material fractions of the two general waste types, defined as "food waste" and "fibre-rich waste," were found to be anaerobically degradable with considerable BMP. Material degradability of material fractions such as vegetation waste, moulded fibres, animal straw, dirty paper and dirty cardboard, however, was constrained by lignin content. BMP for overall SSOHW (untreated) was 404 mL CH4 per g VS, which might increase if the relative content of material fractions, such as animal and vegetable food waste, kitchen tissue and dirty paper in the waste, becomes larger. Copyright © 2016 Elsevier Ltd. All rights reserved.
Advance assessment for movement of Haz Cat 3 radioactive materials.
DOE Office of Scientific and Technical Information (OSTI.GOV)
Vosburg, Susan K.
2010-04-01
The current packaging of most HC-3 radioactive materials at SNL/NM do not meet DOT requirements for offsite shipment. SNL/NM is transporting HC-3 quantities of radioactive materials from their storage locations in the Manzano Nuclear Facilities bunkers to facilities in TA-5 to be repackaged for offsite shipment. All transportation of HC-3 rad material by SNL/NM is onsite (performed within the confines of KAFB). Transport is performed only by the Regulated Waste/Nuclear Material Disposition Department. Part of the HC3T process is to provide the CAT with the following information at least three days prior to the move: (1) RFt-Request for transfer; (2)more » HC3T movement report; (3) Radiological survey; and (4) Transportation Route Map.« less
Federal Register 2010, 2011, 2012, 2013, 2014
2013-01-29
... Accidental Releases of Radioactive Materials From Liquid Waste Tanks in Ground and Surface Waters for... Radioactive Materials from Liquid Waste Tanks in Ground and Surface Waters for Combined License Applications... Radioactive Materials from Liquid Waste Tanks in Ground and Surface Waters for Combined License Applications...
NASA Astrophysics Data System (ADS)
van Loon, A. J.
2000-06-01
Man does not only extract material from the Earth but increasingly uses the underground for storage and disposal purposes. One of the materials that might be disposed of this way is high-level nuclear waste. The development of safe disposal procedures, the choice of suitable host rocks, and the design of underground facilities have taken much time and money, but commissions in several countries have presented reports showing that — and how — safe geological disposal will be possible in such a way that definite isolation from the biosphere is achieved. Political views have changed in the past few years, however, and there is a strong tendency now to require that the high-level waste disposed of will be retrievable. Considering the underlying arguments for isolation from the biosphere, and also considering waste policy in general, this provides an irrational context. The development of new procedures and the design of new disposal facilities that allow retrieval will take much time again. A consequence may be that the high-active, heat-generating nuclear waste will be stored temporarily for a much longer time than objectively desirable. The delay in disposal and the counterproductive requirement of retrievability are partly due to the fact that earth-science organisations have failed to communicate in the way they should, possibly fearing public (and financial) reactions if taking a position that is (was?) considered as politically incorrect. Such an attitude should not be maintained in modern society, which has the right to be informed reliably by the scientific community.
Utilization of Palm Oil Clinker as Cement Replacement Material
Kanadasan, Jegathish; Abdul Razak, Hashim
2015-01-01
The utilization of waste materials from the palm oil industry provides immense benefit to various sectors of the construction industry. Palm oil clinker is a by-product from the processing stages of palm oil goods. Channelling this waste material into the building industry helps to promote sustainability besides overcoming waste disposal problems. Environmental pollution due to inappropriate waste management system can also be drastically reduced. In this study, cement was substituted with palm oil clinker powder as a binder material in self-compacting mortar. The fresh, hardened and microstructure properties were evaluated throughout this study. In addition, sustainability component analysis was also carried out to assess the environmental impact of introducing palm oil clinker powder as a replacement material for cement. It can be inferred that approximately 3.3% of cement production can be saved by substituting palm oil clinker powder with cement. Reducing the utilization of cement through a high substitution level of this waste material will also help to reduce carbon emissions by 52%. A cleaner environment free from pollutants can be created to ensure healthier living. Certain industries may benefit through the inclusion of this waste material as the cost and energy consumption of the product can be minimized. PMID:28793748
Utilization of Palm Oil Clinker as Cement Replacement Material.
Kanadasan, Jegathish; Abdul Razak, Hashim
2015-12-16
The utilization of waste materials from the palm oil industry provides immense benefit to various sectors of the construction industry. Palm oil clinker is a by-product from the processing stages of palm oil goods. Channelling this waste material into the building industry helps to promote sustainability besides overcoming waste disposal problems. Environmental pollution due to inappropriate waste management system can also be drastically reduced. In this study, cement was substituted with palm oil clinker powder as a binder material in self-compacting mortar. The fresh, hardened and microstructure properties were evaluated throughout this study. In addition, sustainability component analysis was also carried out to assess the environmental impact of introducing palm oil clinker powder as a replacement material for cement. It can be inferred that approximately 3.3% of cement production can be saved by substituting palm oil clinker powder with cement. Reducing the utilization of cement through a high substitution level of this waste material will also help to reduce carbon emissions by 52%. A cleaner environment free from pollutants can be created to ensure healthier living. Certain industries may benefit through the inclusion of this waste material as the cost and energy consumption of the product can be minimized.
Nikodinovic-Runic, Jasmina; Guzik, Maciej; Kenny, Shane T; Babu, Ramesh; Werker, Alan; O Connor, Kevin E
2013-01-01
Research into the production of biodegradable polymers has been driven by vision for the most part from changes in policy, in Europe and America. These policies have their origins in the Brundtland Report of 1987, which provides a platform for a more sustainable society. Biodegradable polymers are part of the emerging portfolio of renewable raw materials seeking to deliver environmental, social, and economic benefits. Polyhydroxyalkanoates (PHAs) are naturally-occurring biodegradable-polyesters accumulated by bacteria usually in response to inorganic nutrient limitation in the presence of excess carbon. Most of the early research into PHA accumulation and technology development for industrial-scale production was undertaken using virgin starting materials. For example, polyhydroxybutyrate and copolymers such as polyhydroxybutyrate-co-valerate are produced today at industrial scale from corn-derived glucose. However, in recent years, research has been undertaken to convert domestic and industrial wastes to PHA. These wastes in today's context are residuals seen by a growing body of stakeholders as platform resources for a biobased society. In the present review, we consider residuals from food, plastic, forest and lignocellulosic, and biodiesel manufacturing (glycerol). Thus, this review seeks to gain perspective of opportunities from literature reporting the production of PHA from carbon-rich residuals as feedstocks. A discussion on approaches and context for PHA production with reference to pure- and mixed-culture technologies is provided. Literature reports advocate results of the promise of waste conversion to PHA. However, the vast majority of studies on waste to PHA is at laboratory scale. The questions of surmounting the technical and political hurdles to industrialization are generally left unanswered. There are a limited number of studies that have progressed into fermentors and a dearth of pilot-scale demonstration. A number of fermentation studies show that biomass and PHA productivity can be increased, and sometimes dramatically, in a fermentor. The relevant application-specific properties of the polymers from the wastes studied and the effect of altered-waste composition on polymer properties are generally not well reported and would greatly benefit the progress of the research as high productivity is of limited value without the context of requisite case-specific polymer properties. The proposed use of a waste residual is advantageous from a life cycle viewpoint as it removes the direct or indirect effect of PHA production on land usage and food production. However, the question, of how economic drivers will promote or hinder advancements to demonstration scale, when wastes generally become understood as resources for a biobased society, hangs today in the balance due to a lack of shared vision and the legacy of mistakes made with first generation bioproducts. Copyright © 2013 Elsevier Inc. All rights reserved.
48 CFR 52.211-5 - Material Requirements.
Code of Federal Regulations, 2010 CFR
2010-10-01
... materials and by-products generated from, and reused within, an original manufacturing process; provided... readjustments and material replacement. Recovered material means waste materials and by-products recovered or diverted from solid waste, but the term does not include those materials and by-products generated from...
Incentivizing secondary raw material markets for sustainable waste management.
Schreck, Maximilian; Wagner, Jeffrey
2017-09-01
Notwithstanding several policy initiatives in many countries over a number of years, there remains a general sense that too much municipal solid waste is generated and that too much of the waste that is generated is landfilled. There is an emerging consensus that a sustainable approach to waste management requires further development of secondary raw material markets. The purpose of this paper is to propose a theoretical economic model that focuses upon this stage of a sustainable waste management program and explores policy options that could motivate efficiency in secondary raw material markets. In particular, we show how firm profit and social welfare optimizing objectives can be reconciled in a two-product market of waste management processes: landfilling and material reclamation. Our results provide theoretical support for building out recent Circular Economy initiatives as well as for the relatively recent emergence of landfill mining as a means for procuring secondary raw materials. Copyright © 2017 Elsevier Ltd. All rights reserved.
2015-04-27
from waste biomass using these two high temperature reactors. We have extensively used a Raman spectrometer to analyse as synthesized carbon materials...corporation). These tools were fully installed and operational. We have also synthesized carbon materials from waste biomass using these two high...materials from waste biomass using these two high temperature reactors. We have extensively used a Raman spectrometer to analyse as synthesized carbon
Merrild, Hanna; Larsen, Anna W; Christensen, Thomas H
2012-05-01
Recycling of materials from municipal solid waste is commonly considered to be superior to any other waste treatment alternative. For the material fractions with a significant energy content this might not be the case if the treatment alternative is a waste-to-energy plant with high energy recovery rates. The environmental impacts from recycling and from incineration of six material fractions in household waste have been compared through life cycle assessment assuming high-performance technologies for material recycling as well as for waste incineration. The results showed that there are environmental benefits when recycling paper, glass, steel and aluminium instead of incinerating it. For cardboard and plastic the results were more unclear, depending on the level of energy recovery at the incineration plant, the system boundaries chosen and which impact category was in focus. Further, the environmental impact potentials from collection, pre-treatment and transport was compared to the environmental benefit from recycling and this showed that with the right means of transport, recyclables can in most cases be transported long distances. However, the results also showed that recycling of some of the material fractions can only contribute marginally in improving the overall waste management system taking into consideration their limited content in average Danish household waste. Copyright © 2012 Elsevier Ltd. All rights reserved.
DOE Office of Scientific and Technical Information (OSTI.GOV)
Kawakami, S.; Yamanaka, Y.; Kato, K.
1999-07-01
The methods of fabrication, handling, and emplacement of engineered barriers used in a deep geological repository for high level radioactive waste should be planned as simply as possible from the engineering and economic viewpoints. Therefore, a new concept of a monolithic buffer material around a waste package have been proposed instead of the conventional concept with the use of small blocks, which would decrease the cost for buffer material. The monolithic buffer material is composed of two parts of highly compacted bentonite, a cup type body and a cover. As the forming method of the monolithic buffer material, compaction bymore » the cold isostatic pressing process (CIP) has been employed. In this study, monolithic bentonite bodies with the diameter of about 333 mm and the height of about 455 mm (corresponding to the approx. 1/5 scale for the Japanese reference concept) were made by the CIP of bentonite powder. The dry densities: {rho}d of the bodies as a whole were measured and the small samples were cut from several locations to investigate the density distribution. The swelling pressure and hydraulic conductivity as function of the monolithic body density for CIP-formed specimens were also measured. High density ({rho}d: 1.4--2.0 Mg/m{sup 3}) and homogeneous monolithic bodies were formed by the CIP. The measured results of the swelling pressure (3--15 MPa) and hydraulic conductivity (0.5--1.4 x 10{sup {minus}13} m/s) of the specimens were almost the same as those for the uniaxial compacted bentonite in the literature. It is shown that the vacuum hoist system is an applicable handling method for emplacement of the monolithic bentonite.« less
40 CFR Appendix to Part 240 - Recommended Bibliography
Code of Federal Regulations, 2011 CFR
2011-07-01
... Part 240 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES GUIDELINES FOR THE THERMAL PROCESSING OF SOLID WASTES Pt. 240, App. Appendix to Part 240—Recommended Bibliography 1. The Solid Waste Disposal Act as amended; Title II of Pub. L. 89-272, 89th Cong., S. 306, Oct. 20...
40 CFR 239.6 - Permitting requirements.
Code of Federal Regulations, 2012 CFR
2012-07-01
... CFR part 257, subpart B or 40 CFR part 258 federal revised criteria. (e) For municipal solid waste... solid waste landfill units shall have a permit incorporating the conditions identified in paragraph (e... solid waste landfill units which achieve compliance with 40 CFR part 258, subpart E; (vi) Closure and...
40 CFR 239.6 - Permitting requirements.
Code of Federal Regulations, 2014 CFR
2014-07-01
... CFR part 257, subpart B or 40 CFR part 258 federal revised criteria. (e) For municipal solid waste... solid waste landfill units shall have a permit incorporating the conditions identified in paragraph (e... solid waste landfill units which achieve compliance with 40 CFR part 258, subpart E; (vi) Closure and...
40 CFR 239.6 - Permitting requirements.
Code of Federal Regulations, 2010 CFR
2010-07-01
... CFR part 257, subpart B or 40 CFR part 258 federal revised criteria. (e) For municipal solid waste... solid waste landfill units shall have a permit incorporating the conditions identified in paragraph (e... solid waste landfill units which achieve compliance with 40 CFR part 258, subpart E; (vi) Closure and...
7 CFR 1951.232 - Water and waste disposal systems which have become part of an urban area.
Code of Federal Regulations, 2010 CFR
2010-01-01
... 7 Agriculture 14 2010-01-01 2009-01-01 true Water and waste disposal systems which have become... Water and waste disposal systems which have become part of an urban area. A water and/or waste disposal.... The following will be forwarded to the Administrator, Attention: Water and Waste Disposal Division...
40 CFR 268.6 - Petitions to allow land disposal of a waste prohibited under subpart C of part 268.
Code of Federal Regulations, 2010 CFR
2010-07-01
... ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES (CONTINUED) LAND DISPOSAL RESTRICTIONS General § 268.6 Petitions to allow land disposal of a waste prohibited under subpart C of part 268. (a) Any person seeking... operator of a land disposal unit receiving restricted waste(s) will comply with other applicable Federal...
40 CFR 268.6 - Petitions to allow land disposal of a waste prohibited under subpart C of part 268.
Code of Federal Regulations, 2011 CFR
2011-07-01
... ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES (CONTINUED) LAND DISPOSAL RESTRICTIONS General § 268.6 Petitions to allow land disposal of a waste prohibited under subpart C of part 268. (a) Any person seeking... operator of a land disposal unit receiving restricted waste(s) will comply with other applicable Federal...
40 CFR 268.6 - Petitions to allow land disposal of a waste prohibited under subpart C of part 268.
Code of Federal Regulations, 2014 CFR
2014-07-01
... ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES (CONTINUED) LAND DISPOSAL RESTRICTIONS General § 268.6 Petitions to allow land disposal of a waste prohibited under subpart C of part 268. (a) Any person seeking... operator of a land disposal unit receiving restricted waste(s) will comply with other applicable Federal...
40 CFR 268.6 - Petitions to allow land disposal of a waste prohibited under subpart C of part 268.
Code of Federal Regulations, 2013 CFR
2013-07-01
... ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES (CONTINUED) LAND DISPOSAL RESTRICTIONS General § 268.6 Petitions to allow land disposal of a waste prohibited under subpart C of part 268. (a) Any person seeking... operator of a land disposal unit receiving restricted waste(s) will comply with other applicable Federal...
40 CFR 268.6 - Petitions to allow land disposal of a waste prohibited under subpart C of part 268.
Code of Federal Regulations, 2012 CFR
2012-07-01
... ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES (CONTINUED) LAND DISPOSAL RESTRICTIONS General § 268.6 Petitions to allow land disposal of a waste prohibited under subpart C of part 268. (a) Any person seeking... operator of a land disposal unit receiving restricted waste(s) will comply with other applicable Federal...
NASA Astrophysics Data System (ADS)
Rapp, F.; Schneider, A.; Elsner, P.
2014-05-01
Biopolymers are becoming increasingly important to both industry and consumers. With regard to waste management, CO2 balance and the conservation of petrochemical resources, increasing efforts are being made to replace standard plastics with bio-based polymers. Nowadays biopolymers can be built for example of cellulose, lactic acid, starch, lignin or bio mass. The paper will present material properties of selected cellulose based polymers (cellulose propionate [CP], cellulose acetate butyrate [CAB]) and corresponding processing conditions for particle foams as well as characterization of produced parts. Special focus is given to the raw material properties by analyzing thermal behavior (differential scanning calorimetry), melt strength (Rheotens test) and molecular weight distribution (gel-permeation chromatography). These results will be correlated with the foaming behavior in a continuous extrusion process with physical blowing agents and underwater pelletizer. Process set-up regarding particle foam technology, including extrusion foaming and pre-foaming, will be shown. The characteristics of the resulting foam beads will be analyzed regarding part density, cell morphology and geometry. The molded parts will be tested on thermal conductivity as well as compression behavior (E-modulus, compression strength).
49 CFR 173.154 - Exceptions for Class 8 (corrosive materials).
Code of Federal Regulations, 2010 CFR
2010-10-01
... material meets the definition of a hazardous substance, hazardous waste, marine pollutant, or are offered... waste, or a marine pollutant, a material classed as a Class 8, Packing Group III, material solely...
77 FR 52073 - Request To Amend a License To Export Radioactive Waste
Federal Register 2010, 2011, 2012, 2013, 2014
2012-08-28
... NUCLEAR REGULATORY COMMISSION Request To Amend a License To Export Radioactive Waste Pursuant to..., 2012, July 31, 2012, XW012/ radioactive total of 5,500 materials and/or 02, 11005699. waste including tons or about radioactive various 1,000 tons waste that is materials (e.g., metal, 4,000 attributed to...
48 CFR 52.211-5 - Material Requirements.
Code of Federal Regulations, 2011 CFR
2011-10-01
... readjustments and material replacement. Recovered material means waste materials and by-products recovered or diverted from solid waste, but the term does not include those materials and by-products generated from... is, or with new technology will become, a source of raw materials. (b) Unless this contract otherwise...
An industry perspective on commercial radioactive waste disposal conditions and trends.
Romano, Stephen A
2006-11-01
The United States is presently served by Class-A, -B and -C low-level radioactive waste and naturally-occurring and accelerator-produced radioactive material disposal sites in Washington and South Carolina; a Class-A and mixed waste disposal site in Utah that also accepts naturally-occurring radioactive material; and hazardous and solid waste facilities and uranium mill tailings sites that accept certain radioactive materials on a site-specific basis. The Washington site only accepts low-level radioactive waste from 11 western states due to interstate Compact restrictions on waste importation. The South Carolina site will be subject to geographic service area restrictions beginning 1 July 2008, after which only three states will have continued access. The Utah site dominates the commercial Class-A and mixed waste disposal market due to generally lower state fees than apply in South Carolina. To expand existing commercial services, an existing hazardous waste site in western Texas is seeking a Class-A, -B and -C and mixed waste disposal license. With that exception, no new Compact facilities are proposed. This fluid, uncertain situation has inspired national level rulemaking initiatives and policy studies, as well as alternative disposal practices for certain low-activity materials.
Waste to energy--key element for sustainable waste management.
Brunner, Paul H; Rechberger, Helmut
2015-03-01
Human activities inevitably result in wastes. The higher the material turnover, and the more complex and divers the materials produced, the more challenging it is for waste management to reach the goals of "protection of men and environment" and "resource conservation". Waste incineration, introduced originally for volume reduction and hygienic reasons, went through a long and intense development. Together with prevention and recycling measures, waste to energy (WTE) facilities contribute significantly to reaching the goals of waste management. Sophisticated air pollution control (APC) devices ensure that emissions are environmentally safe. Incinerators are crucial and unique for the complete destruction of hazardous organic materials, to reduce risks due to pathogenic microorganisms and viruses, and for concentrating valuable as well as toxic metals in certain fractions. Bottom ash and APC residues have become new sources of secondary metals, hence incineration has become a materials recycling facility, too. WTE plants are supporting decisions about waste and environmental management: They can routinely and cost effectively supply information about chemical waste composition as well as about the ratio of biogenic to fossil carbon in MSW and off-gas. Copyright © 2014 Elsevier Ltd. All rights reserved.
The artificial water cycle: emergy analysis of waste water treatment.
Bastianoni, Simone; Fugaro, Laura; Principi, Ilaria; Rosini, Marco
2003-04-01
The artificial water cycle can be divided into the phases of water capture from the environment, potabilisation, distribution, waste water collection, waste water treatment and discharge back into the environment. The terminal phase of this cycle, from waste water collection to discharge into the environment, was assessed by emergy analysis. Emergy is the quantity of solar energy needed directly or indirectly to provide a product or energy flow in a given process. The emergy flow attributed to a process is therefore an index of the past and present environmental cost to support it. Six municipalities on the western side of the province of Bologna were analysed. Waste water collection is managed by the municipal councils and treatment is carried out in plants managed by a service company. Waste water collection was analysed by compiling a mass balance of the sewer system serving the six municipalities, including construction materials and sand for laying the pipelines. Emergy analysis of the water treatment plants was also carried out. The results show that the great quantity of emergy required to treat a gram of water is largely due to input of non renewable fossil fuels. As found in our previous analysis of the first part of the cycle, treatment is likewise characterised by high expenditure of non renewable resources, indicating a correlation with energy flows.
Impact of the Munitions Rule on management of military chemical warfare agents and associated waste
DOE Office of Scientific and Technical Information (OSTI.GOV)
Kimmell, T.A.; Green, D.R.; Rosenblatt, D.H.
1997-07-01
The Federal Facility Compliance Act (FFCA), an amendment to the Resource Conservation and Recovery Act (RCRA), was signed by President Bush on October 6, 1992. Section 107 of the FFCA amended RCRA by adding a new Section 3004(y) that required the US Environmental Protection Agency (EPA) to develop, after consultation with the US Department of Defense (DOD) and appropriate state officials, regulations that identify when conventional and chemical munitions become hazardous waste and that provide for the safe transportation and storage of these wastes. The Military Munitions Rule (MMR) was proposed by EPA on November 8, 1995. The impact ofmore » the MMR on the management of military chemical warfare agents and associated waste is an important topic. There has been significant controversy regarding the disposition, under RCRA, of military chemical stockpile materials, and the MMR, in addition to issues with respect to conventional munitions, was expected to clarify the applicability of RCRA in these situations. The purpose of this paper is to review the applicability of the RCRA regulations to military chemical munitions that become waste and to discuss the impacts of the final MMR on the management of these wastes. The focus is on selected chemical agents that are part of the US chemical stockpile.« less
40 CFR 272.1801 - State-administered program: Final authorization.
Code of Federal Regulations, 2010 CFR
2010-07-01
...) SOLID WASTES (CONTINUED) APPROVED STATE HAZARDOUS WASTE MANAGEMENT PROGRAMS Ohio § 272.1801 State... regulations are incorporated by reference and codified as part of the hazardous waste management program under..., 1989, is codified as part of the authorized hazardous waste management program under Subtitle C of RCRA...
Electrical and electronic waste: a global environmental problem.
Ramesh Babu, Balakrishnan; Parande, Anand Kuber; Ahmed Basha, Chiya
2007-08-01
The production of electrical and electronic equipment (EEE) is one of the fastest growing global manufacturing activities. This development has resulted in an increase of waste electric and electronic equipment (WEEE). Rapid economic growth, coupled with urbanization and growing demand for consumer goods, has increased both the consumption of EEE and the production of WEEE, which can be a source of hazardous wastes that pose a risk to the environment and to sustainable economic growth. To address potential environmental problems that could stem from improper management of WEEE, many countries and organizations have drafted national legislation to improve the reuse, recycling and other forms of material recovery from WEEE to reduce the amount and types of materials disposed in landfills. Recycling of waste electric and electronic equipment is important not only to reduce the amount of waste requiring treatment, but also to promote the recovery of valuable materials. EEE is diverse and complex with respect to the materials and components used and waste streams from the manufacturing processes. Characterization of these wastes is of paramount importance for developing a cost-effective and environmentally sound recycling system. This paper offers an overview of electrical and e-waste recycling, including a description of how it is generated and classified, strategies and technologies for recovering materials, and new scientific developments related to these activities. Finally, the e-waste recycling industry in India is also discussed.
Corrective action investigation plan: Cactus Spring Waste Trenches. Revision 2
DOE Office of Scientific and Technical Information (OSTI.GOV)
NONE
This Correction Action Investigation Plan (CAIP) contains environmental sample collection objectives and logic for the Corrective Action Unit No. 426, which includes the Cactus Spring Waste Trenches, located at the Tonopah Test Range. The purpose of this investigation is to generate sufficient data to establish the types of waste buried in the trenches, identify the presence and nature of contamination, determine the vertical extent of contaminant migration below the Cactus Spring Waste Trenches, and determine the appropriate course of action for the site. The potential courses of action for the site are clean closure, closure in place (with or withoutmore » remediation), or no further action. The scope of this investigation will include drilling and collecting subsurface samples from within and below the trenches. Sampling locations will be biased toward the areas most likely to be contaminated. The Cactus Spring Waste Trenches Site is identified as one of three potential locations for buried, radioactively contaminated materials from the Double Tracks Test. This test was the first of four storage-transportation tests conducted in 1963 as part of Operation Roller Coaster. The experiment involved the use of live animals to assess the inhalation intake of a plutonium aerosol.« less
Smith, Karen P; Arnish, John J; Williams, Gustavious P; Blunt, Deborah L
2003-05-15
Certain petroleum production activities cause naturally occurring radioactive materials (NORM) to accumulate in concentrations above natural background levels, making safe and cost-effective management of such technologically enhanced NORM (TENORM) a key issue for the petroleum industry. As a result, both industry and regulators are interested in identifying cost-effective disposal alternatives that provide adequate protection of human health and the environment One such alternative, currently allowed in Michigan with restrictions, is the disposal of TENORM wastes in nonhazardous waste landfills. The disposal of petroleum industry wastes containing radium-226 (Ra-226) in nonhazardous landfills was modeled to evaluate the potential radiological doses and health risks to workers and the public. Multiple scenarios were considered in evaluating the potential risks associated with landfill operations and the future use of the property. The scenarios were defined, in part, to evaluate the Michigan policy; sensitivity analyses were conducted to evaluate the impact of key parameters on potential risks. The results indicate that the disposal of petroleum industry TENORM wastes in nonhazardous landfills in accordance with the Michigan policy and existing landfill regulations presents a negligible risk to most of the potential receptors considered in this study.
Waste separation and pretreatment using crystalline silicotitanate ion exchangers
DOE Office of Scientific and Technical Information (OSTI.GOV)
Tadros, M.E.; Miller, J.E.; Anthony, R.G.
1997-10-01
A new class of inorganic ion exchangers called crystalline silicotitanates (CSTs) has been developed jointly by Sandia National Laboratories and Texas A&M University to selectively remove Cs and other radionuclides from a wide spectrum of radioactive defense wastes. The CST exhibits high selectivity and affinity for Cs and Sr under a wide range of conditions. Tests show it can remove part-per-million concentrations of Cs{sup +} from highly alkaline, high-sodium simulated radioactive waste solutions modeled after those at Hanford, Oak Ridge, and Savannah River. The materials exhibit ion exchange properties based on ionic size selectivity. Specifically, crystalline lattice spacing is controlledmore » to be highly selective for Cs ions even in waste streams containing very high (5 to 10 M) concentrations of sodium. The CST technology is being demonstrated with actual waste at several DOE facilities. The use of inorganic ion exchangers. The inorganics are more resistant to chemical, thermal, and radiation degradation. Their high selectivities result in more efficient operations offering the possibility of a simple single-pass operation. In contrast, regenerable organic ion exchangers require additional processing equipment to handle the regeneration liquids and the eluant with the dissolved Cs.« less
Codigestion of manure and organic wastes in centralized biogas plants: status and future trends.
Angelidaki, I; Ellegaard, L
2003-01-01
Centralized biogas plants in Denmark codigest mainly manure, together with other organic waste such as industrial organic waste, source sorted household waste, and sewage sludge. Today 22 large-scale centralized biogas plants are in operation in Denmark, and in 2001 they treated approx 1.2 million tons of manure as well as approx 300,000 of organic industrial waste. Besides the centralized biogas plants there are a large number of smaller farm-scale plants. The long-term energy plan objective is a 10-fold increase of the 1998 level of biogas production by the year 2020. This will help to achieve a target of 12-14% of the national energy consumption being provided by renewable energy by the year 2005 and 33% by the year 2030. A major part of this increase is expected to come from new centralized biogas plants. The annual potential for biogas production from biomass resources available in Denmark is estimated to be approx 30 Peta Joule (PJ). Manure comprises about 80% of this potential. Special emphasis has been paid to establishing good sanitation and pathogen reduction of the digested material, to avoid risk of spreading pathogens when applying the digested manure as fertilizer to agricultural soils.
The mass flow and proposed management of bisphenol A in selected Norwegian waste streams.
Arp, Hans Peter H; Morin, Nicolas A O; Hale, Sarah E; Okkenhaug, Gudny; Breivik, Knut; Sparrevik, Magnus
2017-02-01
Current initiatives for waste-handling in a circular economy favor prevention and recycling over incineration or landfilling. However, the impact of such a transition on environmental emissions of contaminants like bisphenol A (BPA) during waste-handling is not fully understood. To address this, a material flow analysis (MFA) was constructed for selected waste categories in Norway, for which the amount recycled is expected to increase in the future; glass, vehicle, electronic, plastic and combustible waste. Combined, 92tons/y of BPA are disposed of via these waste categories in Norway, with 98.5% associated with plastic and electronic waste. During the model year 2011, the MFA showed that BPA in these waste categories was destroyed through incineration (60%), exported for recycling into new products (35%), stored in landfills (4%) or released into the environment (1%). Landfilling led to the greatest environmental emissions (up to 13% of landfilled BPA), and incinerating the smallest (0.001% of incinerated BPA). From modelling different waste management scenarios, the most effective way to reduce BPA emissions are to incinerate BPA-containing waste and avoid landfilling it. A comparison of environmental and human BPA concentrations with CoZMoMAN exposure model estimations suggested that waste emissions are an insignificant regional source. Nevertheless, from monitoring studies, landfill emissions can be a substantial local source of BPA. Regarding the transition to a circular economy, it is clear that disposing of less BPA-containing waste and less landfilling would lead to lower environmental emissions, but several uncertainties remain regarding emissions of BPA during recycling, particularly for paper and plastics. Future research should focus on the fate of BPA, as well as BPA alternatives, in emerging reuse and recycling processes, as part of the transition to a circular economy. Copyright © 2017 Elsevier Ltd. All rights reserved.
Mechanisms and modelling of waste-cement and cement-host rock interactions
NASA Astrophysics Data System (ADS)
2017-06-01
Safe and sustainable disposal of hazardous and radioactive waste is a major concern in today's industrial societies. The hazardous waste forms originate from residues of thermal treatment of waste, fossil fuel combustion and ferrous/non-ferrous metal smelting being the most important ones in terms of waste production. Low- and intermediate-level radioactive waste is produced in the course of nuclear applications in research and energy production. For both waste forms encapsulation in alkaline, cement-based matrices is considered to ensure long-term safe disposal. Cementitious materials are in routine use as industrial materials and have mainly been studied with respect to their evolution over a typical service life of several decades. Use of these materials in waste management applications, however, requires assessments of their performance over much longer time periods on the order of thousands to several ten thousands of years.
Recycled industrial and construction waste for mutual beneficial use.
DOT National Transportation Integrated Search
2016-08-01
Instead of going to landfills, certain waste materials from industry and building construction can be recycled in transportation infrastructure projects, such as roadway paving. The beneficial use of waste materials in the construction of transportat...
Physical and chemical properties of slash pine tree parts
E. T. Howard
1973-01-01
In three 22-year-old slash pines from an unthinned plantation in central Louisiana, stemwood comprised 58.5 percent of total ovendry tree weight. Stumps and main roots made up 16.5 percent, bark 12.5, top of bole 5.0, needles 4.0, and branches 3.5. This material now is largely wasted when a tree is harvested; methods of utilizing it would extend fiber supplies by 70...
Analysis of the process applied to end-of-life vehicles in Authorised Treatment Facilities
NASA Astrophysics Data System (ADS)
Muñoz, C.; Garraín, D.; Franco, V.; Royo, M.; Justel, D.; Vidal, R.
2009-11-01
Authorised treatment facilities (ATFs) play a key role in the process undergone by vehicles when they reach their end of life (EoL) within the context of Directive 2000/53/EC. Whenever an EoL vehicle is received at an ATF, a certificate of destruction is issued. The process continues with the depollution of hazardous waste materials from the vehicle and dismantling of parts that will be reused or recycled. Finally, the remaining parts of the vehicle are transported to a shredding plant. Directive 2000/53/EC sets a number of environmental goals regarding the reuse and recycling of vehicle parts and the recovery of waste materials at the EoL of vehicles. These goals will condition the evolution of ATFs as they gradually become more restrictive. As of today, the goals set by Directive 2000/53/EC for the year 2006 are being met (1). However, it would be necessary to assess the situation of those parts that comprise the fraction of the vehicle that is not recycled, reused or recovered in order to predict the degree of compliance with the goals set for the year 2015 (recycling, reusing or recovering 95% by weight of EoL vehicles). The use of lighter materials—light alloys and reinforced plastics—as a vehicle weight-reducing strategy should be coordinated with the process carried out at ATFs in order to ensure compliance with the aforementioned goals. The results of our study seem to indicate that the most usual EoL scenario today—that in which practically all of the ferrous and non-ferrous metals are recycled and the lightweight fraction of vehicles and remaining inert materials are sent to a landfill—should be revised in order to reach the environmental goals set for the year 2015. To that avail, new strategies will have to be developed to allow for an adequate treatment—recycling, reuse or recovery—of those vehicle components that are presently sent to a landfill.
Quality design of belite–melilite clinker
DOE Office of Scientific and Technical Information (OSTI.GOV)
Kurokawa, Daisuke, E-mail: daisuke_kurokawa@taiheiyo-cement.co.jp; Department of Materials Science and Engineering, Nagoya Institute of Technology, Nagoya 466-8555; Honma, Kenichi
2013-12-15
We have developed a new cement clinker, consisting mainly of belite and melilite, which is capable of increasing the amount of recycled waste as a part of its raw materials. We analyzed clinkers with a wide range of compositions, and clarified the quantitative relationship between the chemical and mineral compositions. Clinkers consisting mostly of belite and melilite were successfully obtained at the CaO/SiO{sub 2} mass ratio of 1.7 to 1.9. Test cements were prepared using these clinkers and mixed with OPC for the evaluation of fluidity and strength. The belite–melilite cement was found to have good fluidity, and the belite–melilitemore » cement mixed with OPC at up to 30% exhibited a satisfactory long term strength equivalent to the OPC, demonstrating the potential as an alternative to OPC. Electron probe microanalysis revealed the relatively high concentration of diphosphorus pentaoxide in belite, suggesting this component might contribute to the strength enhancement of the cement. -- Highlights: •A new cement clinker consisting mainly of belite and melilite was designed. •The clinker enables the use of various recycled wastes as part of its raw materials. •The relationship between the chemical and mineral compositions was clarified. •This cement mixed with OPC at up to 30% exhibited a good quality equivalent to OPC.« less
Marín, Maria; Artola, Adriana; Sánchez, Antoni
2018-04-01
Production of enzymes through solid-state fermentation (SSF) of agro-industrial wastes reports high productivity with low investment. The extraction of the final product from the solid waste and solid disposal represent the main cost of the process. In this work, the complete downstream processes of SSF of two industrial residues for the production of proteases, soy fibre (SF) and a mixture of hair and sludge (HS), were studied in terms of activity recovery, using different extraction parameters (extracting solvent, ratio solid: solvent and extraction mode). Activity after lyophilisation was tested. Solid waste valorisation after extraction was studied using respiration techniques and biogas production tests, as part of a zero waste strategy. Results showed a maximum extraction yield of 91% for SF and 121% for HS, both in agitated mode and distilled water as extraction agent. An average activity recovery of 95 ± 6 and 94 ± 6% for SF and HS, respectively, was obtained after lyophilisation and redissolution. To reduce the cost of extraction, a ratio 1:3 w : v solid-solvent in static mode is advised for SF, and 1:2 w : v extraction ratio in agitated mode for HS, both with distilled water as extracting agent. Both composting and anaerobic digestion are suitable techniques for valorisation of the waste material.
Method of making nanostructured glass-ceramic waste forms
Gao, Huizhen; Wang, Yifeng; Rodriguez, Mark A.; Bencoe, Denise N.
2014-07-08
A waste form for and a method of rendering hazardous materials less dangerous is disclosed that includes fixing the hazardous material in nanopores of a nanoporous material, reacting the trapped hazardous material to render it less volatile/soluble, and vitrifying the nanoporous material containing the less volatile/soluble hazardous material.
Chemical compatibility screening test results
DOE Office of Scientific and Technical Information (OSTI.GOV)
Nigrey, P.J.; Dickens, T.G.
1997-12-01
A program for evaluating packaging components that may be used in transporting mixed-waste forms has been developed and the first phase has been completed. This effort involved the screening of ten plastic materials in four simulant mixed-waste types. These plastics were butadiene-acrylonitrile copolymer rubber, cross-linked polyethylene (XLPE), epichlorohydrin rubber, ethylene-propylene rubber (EPDM), fluorocarbon (Viton or Kel-F), polytetrafluoroethylene, high-density polyethylene (HDPE), isobutylene-isoprene copolymer rubber (butyl), polypropylene, and styrene-butadiene rubber (SBR). The selected simulant mixed wastes were (1) an aqueous alkaline mixture of sodium nitrate and sodium nitrite; (2) a chlorinated hydrocarbon mixture; (3) a simulant liquid scintillation fluid; and (4) amore » mixture of ketones. The testing protocol involved exposing the respective materials to 286,000 rads of gamma radiation followed by 14-day exposures to the waste types at 60{degrees}C. The seal materials were tested using vapor transport rate (VTR) measurements while the liner materials were tested using specific gravity as a metric. For these tests, a screening criterion of 0.9 g/hr/m{sup 2} for VTR and a specific gravity change of 10% was used. Based on this work, it was concluded that while all seal materials passed exposure to the aqueous simulant mixed waste, EPDM and SBR had the lowest VTRs. In the chlorinated hydrocarbon simulant mixed waste, only Viton passed the screening tests. In both the simulant scintillation fluid mixed waste and the ketone mixture simulant mixed waste, none of the seal materials met the screening criteria. For specific gravity testing of liner materials, the data showed that while all materials with the exception of polypropylene passed the screening criteria, Kel-F, HDPE, and XLPE offered the greatest resistance to the combination of radiation and chemicals.« less
DOE Office of Scientific and Technical Information (OSTI.GOV)
Miyazaki, M.; Une, H.
In Japan, the waste management practice is carried out in accordance with the Waste Disposal Law of 1970. The first rule of infectious waste management was regulated in 1992, and infectious wastes are defined as the waste materials generated in medical institutions as a result of medical care or research which contain pathogens that have the potential to transmit infectious diseases. Revised criteria for infectious waste management were promulgated by the Ministry of Environment in 2004. Infectious waste materials are divided into three categories: the form of waste; the place of waste generation; the kind of infectious diseases. A reductionmore » of infectious waste is expected. We introduce a summary of the revised regulation of infectious waste management in this article.« less
EPA is responsible for certifying that DOE’s Waste Isolation Pilot Plant (WIPP) remains in compliance with environmental standards for the disposal of transuranic waste. 40 CFR Part 194 specifies criteria for certification or recertification of WIPP.
40 CFR Appendix I to Part 264 - Recordkeeping Instructions
Code of Federal Regulations, 2010 CFR
2010-07-01
...., liquid, sludge, solid, or contained gas. If the waste is not listed in part 261, subpart D, of this... from production of ----, EPA Hazardous Waste Number W051). Each hazardous waste listed in part 261... Methods Enter the handling code(s) listed below that most closely represents the technique(s) used at the...
Fires at storage sites of organic materials, waste fuels and recyclables.
Ibrahim, Muhammad Asim; Alriksson, Stina; Kaczala, Fabio; Hogland, William
2013-09-01
During the last decade, the European Union has enforced the diversion of organic wastes and recyclables to waste management companies operating incineration plants, composting plants and recycling units instead of landfills. The temporary storage sites have been established as a buffer against fluctuations in energy demand throughout the year. Materials also need to be stored at temporary storage sites before recovery and recycling. However, regulations governing waste fuel storage and handling have not yet been developed, and, as a result, companies have engaged in risky practices that have resulted in a high number of fire incidents. In this study, a questionnaire survey was distributed to 249 of the 400 members of Avfall Sverige (Swedish Waste Management Association), which represents the waste management of 95% of the Swedish population. Information regarding 122 storage facilities owned by 69 companies was obtained; these facilities were responsible for the storage of 47% of the total treated waste (incineration + digestion + composting) in 2010 in Sweden. To identify factors related to fire frequency, the questionnaire covered the amounts of material handled and burnt per year, financial losses due to fires, storage duration, storage method and types of waste. The results show that 217 fire incidents corresponded to 170 kilotonnes of material burnt and cumulative losses of 49 million SEK (€4.3 million). Fire frequency and amount of material burnt per fire was found to be dependent upon type of management group (waste operator). Moreover, a correlation was found between fire frequency and material recycled during past years. Further investigations of financial aspects and externalities of fire incidents are recommended.
Corrosion assessment of refractory materials for high temperature waste vitrification
DOE Office of Scientific and Technical Information (OSTI.GOV)
Marra, J.C.; Congdon, J.W.; Kielpinski, A.L.
1995-11-01
A variety of vitrification technologies are being evaluated to immobilize radioactive and hazardous wastes following years of nuclear materials production throughout the Department of Energy (DOE) complex. The compositions and physical forms of these wastes are diverse ranging from inorganic sludges to organic liquids to heterogeneous debris. Melt and off-gas products can be very corrosive at the high temperatures required to melt many of these waste streams. Ensuring material durability is required to develop viable treatment processes. Corrosion testing of materials in some of the anticipated severe environments is an important aspect of the materials identification and selection process. Corrosionmore » coupon tests on typical materials used in Joule heated melters were completed using glass compositions with high salt contents. The presence of chloride in the melts caused the most severe attack. In the metal alloys, oxidation was the predominant corrosion mechanism, while in the tested refractory material enhanced dissolution of the refractory into the glass was observed. Corrosion testing of numerous different refractory materials was performed in a plasma vitrification system using a surrogate heterogeneous debris waste. Extensive corrosion was observed in all tested materials.« less
Uranium mining wastes, garden exhibition and health risks
DOE Office of Scientific and Technical Information (OSTI.GOV)
Schmidt, Gerhard; Schmidt, Peter; Hinz, Wilko
2007-07-01
Available in abstract form only. Full text of publication follows: For more than 40 years the Soviet-German stockholding company SDAG WISMUT mined and milled Uranium in the East of Germany and became up to 1990 the world's third largest Uranium producer. After reunification of Germany, the new found state own company Wismut GmbH was faced with the task of decommissioning and rehabilitation of the mining and milling sites. One of the largest mining areas in the world, that had to be cleaned up, was located close to the municipality of Ronneburg near the City of Gera in Thuringia. After closingmore » the operations of the Ronneburg underground mine and at the 160 m deep open pit mine with a free volume of 84 Mio.m{sup 3}, the open pit and 7 large piles of mine waste, together 112 Mio.m{sup 3} of material, had to be cleaned up. As a result of an optimisation procedure it was chosen to relocate the waste rock piles back into the open pit. After taking this decision and approval of the plan the disposal operation was started. Even though the transport task was done by large trucks, this took 16 years. The work will be finished in 2007, a cover consisting of 40 cm of uncontaminated material will be placed on top of the material, and the re-vegetation of the former open pit area will be established. When in 2002 the City of Gera applied to host the largest garden exhibition in Germany, Bundesgartenschau (BUGA), in 2007, Wismut GmbH supported this plan by offering parts of the territory of the former mining site as an exhibition ground. Finally, it was decided by the BUGA organizers to arrange its 2007 exhibition on grounds in Gera and in the valley adjacent to the former open pit mine, with parts of the remediated area within the fence of the exhibition. (authors)« less
On-site characterisation, re-packaging and transport of luminised, former aircraft escape hatches
DOE Office of Scientific and Technical Information (OSTI.GOV)
Reeves, Nigel; John, Gordon; Beadle, Ian
2007-07-01
AMEC NNC, under contract to the UK Environment Agency, recovered a number of redundant aircraft hatches from an insecure location in North Wales. The Environment Agency instigated emergency action under the Radioactive Substances Act 1993 (RSA93), to recover the hatches. Section 30(1) of RSA93 gives the Environment Agency powers to dispose of radioactive waste where it is unlikely the waste will be lawfully disposed of. Funding for this project was provided by the UK Government, within the Surplus Source Disposal Programme. The Environment Agency worked closely with partner regulatory organisations including the Health and Safety Executive (HSE), the Department formore » Transport (DfT) and the Local Authority to ensure the safe packaging, removal and transport of the material to a part-shielded store pending final disposal. The project comprised a number of technical difficulties that needed to be overcome. These included poor existing characterisation of the waste, insecure premises requiring daily lock-down, construction of a temporary containment facility with associated filtered extract and the inclement weather. AMEC NNC's initial risk assessment identified the likelihood of high levels of loose, airborne radiological material. In order to provide adequate protection for personnel, and to prevent the spread of any radioactive contamination, the decision was made to implement radiological containment and to equip contractors with appropriate RPE (Respiratory Protective Equipment). Accurate characterisation of the radiological nature of the material was a crucial objective within the project. This was in order to correctly identify the Proper Shipping Name for consignment for transport, and to ensure that suitable transport containers were used. The packaged wastes were then transported to a secure location for temporary storage prior to final disposal. An innovative route was identified for processing of this material. Beneficial recycling and re-use within the nuclear industry was the outcome. (authors)« less
Martial recycling from renewable landfill and associated risks: A review.
Ziyang, Lou; Luochun, Wang; Nanwen, Zhu; Youcai, Zhao
2015-07-01
Landfill is the dominant disposal choice for the non-classified waste, which results in the stockpile of materials after a long term stabilization process. A novel landfill, namely renewable landfill (RL), is developed and applied as a strategy to recycle the residual materials and reuse the land occupation, aim to reduce the inherent problems of large land occupied, materials wasted and long-term pollutants released in the conventional landfill. The principle means of RL is to accelerate the waste biodegradation process in the initial period, recover the various material resources disposal and extend the landfill volume for waste re-landfilling after waste stabilized. The residual material available and risk assessment, the methodology of landfill excavation, the potential utilization routes for different materials, and the reclamation options for the unsanitary landfill are proposed, and the integrated beneficial impacts are identified finally from the economic, social and environmental perspectives. RL could be draw as the future reservoirs for resource extraction. Copyright © 2015 Elsevier Ltd. All rights reserved.
Annual waste reduction activities report. Issue 1
DOE Office of Scientific and Technical Information (OSTI.GOV)
NONE
1991-03-18
This report discusses the waste minimization activities for the Pinellas Plant. The Pinellas Plant deals with low-level radioactive wastes, solvents, scrap metals and various other hazardous materials. This program has realized cost savings through recycling and reuse of materials.
Code of Federal Regulations, 2013 CFR
2013-07-01
... agents, radioactive materials, chemicals, biological and laboratory waste, wreck or discarded equipment, rock, sand, excavation debris, industrial, municipal, agricultural, and other waste, but such term does... matter of any kind or description, including, but not limited to, dredged material, solid waste...
Reuse of Material Containing Natural Radionuclides - 12444
DOE Office of Scientific and Technical Information (OSTI.GOV)
Metlyaev, E.G.; Novikova, N.J.
2012-07-01
Disposal of and use of wastes containing natural radioactive material (NORM) or technologically enhanced natural radioactive material (TENORM) with excessive natural background as a building material is very important in the supervision body activity. At the present time, the residents of Octyabrsky village are under resettlement. This village is located just near the Priargunsky mining and chemical combine (Ltd. 'PPGHO'), one of the oldest uranium mines in our country. The vacated wooden houses in the village are demolished and partly used as a building material. To address the issue of potential radiation hazard of the wooden beams originating from demolitionmore » of houses in Octyabrsky village, the contents of the natural radionuclides (K-40, Th-232, Ra-226, U- 238) are being determined in samples of the wooden beams of houses. The NORM contents in the wooden house samples are higher, on average, than their content in the reference sample of the fresh wood shavings, but the range of values is rather large. According to the classification of waste containing the natural radionuclides, its evaluation is based on the effective specific activity. At the effective specific activity lower 1.5 kBq/kg and gamma dose rate lower 70 μR/h, the material is not considered as waste and can be used in building by 1 - 3 classes depending upon A{sub eff} value. At 1.5 kBq/kg < A{sub eff} ≤ 4 kBq/kg (4 class), the wooden beams might be used for the purpose of the industrial building, if sum of ratios between the radionuclide specific activity and its specific activity of minimum significance is lower than unit. The material classified as the waste containing the natural radionuclides has A{sub eff} higher 1.5 kBq /kg, and its usage for the purpose of house-building and road construction is forbidden. As for the ash classification and its future usage, such usage is unreasonable, because, according to the provided material, more than 50% of ash samples are considered as radioactive waste containing natural radionuclides. All materials originated from demolition of houses in Octyabrsky village are subjected to the obligatory radiation control. The decision to use the wooden beams shall enter into force after agreement with the State Sanitary and Epidemiological Supervision bodies. Conclusions: 1 - The wooden beam originated from the house demolition in Octyabrsky village might be used as the construction material only in case of compliance with the requirements of the regulatory documents, as well as under approval of the authorities responsible for the state sanitary and epidemiological supervision in this area. 2 - The industrial control is introduced to verify the compliance with the current regulations. 3 - The material originated from the house demolition might be used only if such usage does not cause increasing radiation exposure to the public. (authors)« less
DOE Office of Scientific and Technical Information (OSTI.GOV)
Moak, Don J.; Grondin, Richard L.; Triner, Glen C.
CH2M Hill Plateau Remediation Company (CHRPC) is a prime contractor to the U.S. Department of Energy (DOE) focused on the largest ongoing environmental remediation project in the world at the DOE Hanford Site Central Plateau, i.e. the DOE Hanford Plateau Remediation Contract. The East Tennessee Materials and Energy Corporation (M and EC); a wholly owned subsidiary of Perma-Fix Environmental Services, Inc. (PESI), is a small business team member to CHPRC. Our scope includes project management; operation and maintenance of on-site storage, repackaging, treatment, and disposal facilities; and on-site waste management including waste receipt from generators and delivery to on-site andmore » off-site treatment, storage, and disposal facilities. As part of this scope, M and EC staffs the centralized Waste Support Services organization responsible for all waste characterization and acceptance required to support CHPRC and waste generators across the Hanford Site. At the time of the CHPRC contract award (August 2008) slightly more than 9,000 cubic meters (m{sup 3}) of legacy waste was defined as 'no-path-forward waste'. A significant portion of this waste (7,650 m{sup 3}) comprised wastes with up to 50 grams of special nuclear materials (SNM) in oversized packages recovered during retrieval operations and large glove boxes removed from the Plutonium Finishing Plant (PFP). Through a collaborative effort between the DOE, CHPRC, and Perma-Fix Environmental Services, Inc. (PESI), pathways for these problematic wastes were developed that took advantage of commercial treatment capabilities at a nearby vendor facility, Perma-Fix Northwest (PFNW). In the spring of 2009, CHPRC initiated a pilot program under which they began shipping large package, low gram suspect TRU (<15 g SNM per container), and large package contact and remote handled MLLW to the off-site PFNW facility for treatment. PFNW is restricted by the SNM limits set for the total quantity of SNM allowed at the facility in accordance with the facility's radioactive materials license(s) (RML). While both CHPRC and PFNW maintain waste databases to track all waste movements, it became evident early in the process that a tool was needed that married the two systems to better track SNM inventories and sequence waste from the point of generation, through the PFNW facility, and back to the Hanford site for final disposition. This tool, known as the Treatment Integration and Planning Tool (TIPT), has become a robust planning tool that provides real-time data to support compliant and efficient waste generation, transportation, treatment, and disposition. TIPT is developing into the next generation tool that will change the way in which legacy wastes, retrieval wastes and decontamination and decommissioning operations are conducted on the Plateau Remediation Contract (PRC). The real value of the TIPT is its predictive capability. It allows the W and FMP to map out optimal windows for processing waste through the PFNW facility, or through any process that is in some way resource limited. It allows project managers to identify and focus on problem areas before shipments are affected. It has been modified for use in broader applications to predict turnaround times and identify windows of opportunity for processing higher gram wastes through PFNW and to allow waste generators, site-wide, to accurately predict scope, cost, and schedule for waste generation to optimize processing and eliminate storage, double handling, and related costs and unnecessary safety risks. The TIPT addresses the years old problem of how to effectively predict not only what needs to be done, but when. 'When' is the key planning parameter that has been ignored by the generator and processor for many years, but has proven to be the most important parameter for both parties. While further refinement is a natural part of any development process, the current improvements on the TIPT have shown that prediction is a powerful consideration. Even in lean times expected for the foreseeable future, the improved TIPT continues to play a central role in managing our way through those times to assure facilities remain viable and available. It is recommended that other major remediation projects and waste processing facilities incorporate a tool such as TIPT to improve customer-commercial supplier communications and better optimization of resources. (authors)« less
DOE Office of Scientific and Technical Information (OSTI.GOV)
Not Available
1977-06-01
The pilot plant is developed for ERDA low-level contact-handled transuranic waste, ERDA remote-handled intermediate-level transuranic waste, and for high-level waste experiments. All wastes placed in the WIPP arrive at the site processed and packaged; no waste processing is done at the WIPP. All wastes placed into the WIPP are retrievable. The proposed site for WIPP lies 26 miles east of Carlsbad, New Mexico. This document includes the executive summary and a detailed description of the facilities and systems. (DLC)
40 CFR 270.13 - Contents of part A of the permit application.
Code of Federal Regulations, 2011 CFR
2011-07-01
... WASTES (CONTINUED) EPA ADMINISTERED PERMIT PROGRAMS: THE HAZARDOUS WASTE PERMIT PROGRAM Permit..., and disposing of hazardous waste, and the design capacity of these items. (j) A specification of the hazardous wastes listed or designated under 40 CFR part 261 to be treated, stored, or disposed of at the...
40 CFR 270.13 - Contents of part A of the permit application.
Code of Federal Regulations, 2010 CFR
2010-07-01
... WASTES (CONTINUED) EPA ADMINISTERED PERMIT PROGRAMS: THE HAZARDOUS WASTE PERMIT PROGRAM Permit..., and disposing of hazardous waste, and the design capacity of these items. (j) A specification of the hazardous wastes listed or designated under 40 CFR part 261 to be treated, stored, or disposed of at the...
40 CFR Appendix I to Part 265 - Recordkeeping Instructions
Code of Federal Regulations, 2010 CFR
2010-07-01
... physical form, i.e., liquid, sludge, solid, or contained gas. If the waste is not listed in part 261..., solid filter cake from production of ___, EPA Hazardous Waste Number W051). Each hazardous waste listed... technique(s) used at the facility to treat, store or dispose of each quantity of hazardous waste received. 1...
Medical waste treatment and decontamination system
Wicks, George G.; Schulz, Rebecca L.; Clark, David E.
2001-01-01
The invention discloses a tandem microwave system consisting of a primary chamber in which hybrid microwave energy is used for the controlled combustion of materials. A second chamber is used to further treat the off-gases from the primary chamber by passage through a susceptor matrix subjected to additional hybrid microwave energy. The direct microwave radiation and elevated temperatures provide for significant reductions in the qualitative and quantitative emissions of the treated off gases. The tandem microwave system can be utilized for disinfecting wastes, sterilizing materials, and/or modifying the form of wastes to solidify organic or inorganic materials. The simple design allows on-site treatment of waste by small volume waste generators.
Tandem microwave waste remediation and decontamination system
Wicks, George G.; Clark, David E.; Schulz, Rebecca L.
1999-01-01
The invention discloses a tandem microwave system consisting of a primary chamber in which microwave energy is used for the controlled combustion of materials. A second chamber is used to further treat the off-gases from the primary chamber by passage through a susceptor matrix subjected to additional microwave energy. The direct microwave radiation and elevated temperatures provide for significant reductions in the qualitative and quantitative emissions of the treated off gases. The tandem microwave system can be utilized for disinfecting wastes, sterilizing materials, and/or modifying the form of wastes to solidify organic or inorganic materials. The simple design allows on-site treatment of waste by small volume waste generators.
Thermal and chemical remediation of mixed waste
Nelson, P.A.; Swift, W.M.
1994-08-09
A process and system for treating organic waste materials without venting gaseous emissions to the atmosphere. A fluidized bed including lime particles is operated at a temperature of at least 500 C by blowing gas having 20%/70% oxygen upwardly through the bed particles at a rate sufficient to fluidize same. A toxic organic waste material is fed into the fluidized bed where the organic waste material reacts with the lime forming CaCO[sub 3]. The off gases are filtered and cooled to condense water which is separated. A portion of the calcium carbonate formed during operation of the fluidized bed is replaced with lime particles. The off gases from the fluidized bed after drying are recirculated until the toxic organic waste material in the bed is destroyed. 3 figs.
Waste glass as eco-friendly replacement material in construction products
NASA Astrophysics Data System (ADS)
Sharma, Gayatri; Sharma, Anu
2018-05-01
Atpresent time the biggest issue is increasing urban population, industrialization and development all over the world. The quantity of the raw materials of construction products like cement, concrete etc is gradually depleting. This is important because if we don't find the alternative material to accomplish need of this industry, with every year it will put pressure on natural resources which are limited in quantity. This major issue can be solved by partial replacing with waste glass of different construction products. This paper gives an overview of the current growth and recycling situation of waste glass and point out the direction for the proper use of waste glass as replacement of construction material. These will not only help in the reuse of waste glass but also create eco-friendly environment.
Thermal and chemical remediation of mixed waste
Nelson, Paul A.; Swift, William M.
1994-01-01
A process and system for treating organic waste materials without venting gaseous emissions to the atmosphere. A fluidized bed including lime particles is operated at a temperature of at least 500.degree. C. by blowing gas having 20%/70% oxygen upwardly through the bed particles at a rate sufficient to fluidize same. A toxic organic waste material is fed into the fluidized bed where the organic waste material reacts with the lime forming CaCO.sub.3. The off gases are filtered and cooled to condense water which is separated. A portion of the calcium carbonate formed during operation of the fluidized bed is replaced with lime particles. The off gases from the fluidized bed after drying are recirculated until the toxic organic waste material in the bed is destroyed.
Hageman, Philip L.
2007-01-01
The U. S. Geological Survey (USGS) has developed a fast (5-minute), effective, simple, and cost-effective leach test that can be used to simulate the reactions that occur when materials are leached by water. The USGS Field Leach Test has been used to predict, assess, and characterize the geochemical interactions between water and a broad variety of geologic and environmental matrices. Examples of some of the samples leached include metal mine wastes, various types of dusts, biosolids (processed sewage sludge), flood and wetland sediments, volcanic ash, forest-fire burned soils, and many other diverse matrices. The Field Leach Test has been an integral part of these investigations and has demonstrated its value as a geochemical characterization tool. It has enabled investigators to identify which constituents are water reactive, soluble, mobilized, and made bioaccessible because of leaching by water, and to understand potential impacts of these interactions on the surrounding environment.
Ma, En; Xu, Zhenming
2013-12-15
In this study, a technology process including vacuum pyrolysis and vacuum chlorinated separation was proposed to convert waste liquid crystal display (LCD) panels into useful resources using self-design apparatuses. The suitable pyrolysis temperature and pressure are determined as 300°C and 50 Pa at first. The organic parts of the panels were converted to oil (79.10 wt%) and gas (2.93 wt%). Then the technology of separating indium was optimized by central composite design (CCD) under response surface methodology (RSM). The results indicated the indium recovery ratio was 99.97% when the particle size is less than 0.16 mm, the weight percentage of NH4Cl to glass powder is 50 wt% and temperature is 450°C. The research results show that the organic materials, indium and glass of LCD panel can be recovered during the recovery process efficiently and eco-friendly. Copyright © 2013 Elsevier B.V. All rights reserved.
NASA Astrophysics Data System (ADS)
Abou Chehade, Lara; Chami, Ziad Al; De Pascali, Sandra; Cavoski, Ivana; Fanizzi, Francesco Paolo
2015-04-01
In organic farming, where nutrient management is constrained and sustainability is claimed, bio-effectors pave their way. Considering selected bio-effectors, this study integrates metabolomics to agronomy in depicting induced relevant phenomena. Extracts of three agro-industrial wastes (Lemon processing residues, Fennel processing residues and Brewer's spent grain) are being investigated as sources of bio-effectors for the third trial consequently. Corresponding individual and mixture aqueous extracts are assessed for their synergistic and/or single agronomic and qualitative performances on soil-grown tomato, compared to both a control and humic acid treatments. A metabolomic profiling of tomato fruits via the Proton Nuclear Magnetic Resonance (NMR) spectroscopy, as holistic indicator of fruit quality and extract-induced responses, complements crop productivity and organoleptic/nutritional qualitative analyses. Results are expected to show mainly an enhancement of the fruit qualitative traits, and to confirm partly the previous results of better crop productivity and metabolism enhancement. Waste-derived bio-effectors could be, accordingly, demonstrated as potential candidates of plant-enhancing substances. Keywords: bio-effectors, organic farming, agro-industrial wastes, nuclear magnetic resonance (NMR), tomato.
Kandasamy, Saravanan; Ramu, Sasikala; Aradhya, Somaradhya Mallikarjuna
2016-03-15
Pseudostem and rhizome are the significant bio-waste generated (43.48%) from the banana plant post fruit harvest, which are usually left in the plantation or incinerated and wasted. Amounts used in production for consumption are negligible. However, the material has an important part to play in indigenous systems of medicine. Based on the huge volume of bio-waste generated and its traditional medicinal use, it is worth exploiting it as a source of natural bioactive compounds. In the current study, sequential extracts from banana pseudostem (BPS) and rhizome (BR), and isolated compounds including chlorogenic acid, 4-epicyclomusalenone and cycloeucalenol acetate, were tested for their antimicrobial activity, antiplatelet aggregation and cytotoxicity. Isolated compounds and crude extracts exhibited strong antimicrobial activity against a wide range of bacterial and fungal strains, platelet aggregation induced by collagen and cytotoxicity towards human liver cancer (HepG2) cells. Banana plant bio-waste, pseudostem and rhizome may serve as a potential source of multifunctional bioactive compounds and functional ingredient in food and other allied industries. © 2015 Society of Chemical Industry.
Effect of natural ageing on volume stability of MSW and wood waste incineration residues
DOE Office of Scientific and Technical Information (OSTI.GOV)
Gori, Manuela, E-mail: manuela.gori@dicea.unifi.it; Bergfeldt, Britta; Reichelt, Jürgen
2013-04-15
Highlights: ► Natural weathering on BA from MSW and wood waste incineration was evaluated. ► Type of mineral phases, pH and volume stability were considered. ► Weathering reactions effect in improved stability of the materials. - Abstract: This paper presents the results of a study on the effect of natural weathering on volume stability of bottom ash (BA) from municipal solid waste (MSW) and wood waste incineration. BA samples were taken at different steps of treatment (fresh, 4 weeks and 12 weeks aged) and then characterised for their chemical and mineralogical composition and for volume stability by means of themore » mineralogical test method (M HMVA-StB), which is part of the German quality control system for using aggregates in road construction (TL Gestein-StB 04). Changes of mineralogical composition with the proceeding of the weathering treatment were also monitored by leaching tests. At the end of the 12 weeks of treatment, almost all the considered samples resulted to be usable without restrictions in road construction with reference to the test parameter volume stability.« less
SUBGRADE MONOLITHIC ENCASEMENT STABILIZATION OF CATEGORY 3 LOW LEVEL WASTE (LLW)
DOE Office of Scientific and Technical Information (OSTI.GOV)
PHILLIPS, S.J.
2004-02-03
A highly efficient and effective technology has been developed and is being used for stabilization of Hazard Category 3 low-level waste at the U.S. Department of Energy's Hanford Site. Using large, structurally interconnected monoliths, which form one large monolith that fills a waste disposal trench, the patented technology can be used for final internment of almost any hazardous, radioactive, or toxic waste or combinations of these waste materials packaged in a variety of sizes, shapes, and volumes within governmental regulatory limits. The technology increases waste volumetric loading by 100 percent, area use efficiency by 200 percent, and volumetric configuration efficiencymore » by more than 500 percent over past practices. To date, in excess of 2,010 m{sup 3} of contact-handled and remote-handled low-level radioactive waste have been interned using this patented technology. Additionally, in excess of 120 m{sup 3} of low-level radioactive waste requiring stabilization in low-diffusion coefficient waste encasement matrix has been disposed using this technology. Greater than five orders of magnitude in radiation exposure reduction have been noted using this method of encasement of Hazard Category 3 waste. Additionally, exposure monitored at all monolith locations produced by the slip form technology is less than 1.29 x E-07 C {center_dot} kg{sup -1}. Monolithic encasement of Hazard Category 3 low-level waste and other waste category materials may be successfully accomplished using this technology at nominally any governmental or private sector waste disposal facility. Additionally, other waste materials consisting of hazardous, radioactive, toxic, or mixed waste materials can be disposed of using the monolithic slip form encasement technology.« less
A Review on Electroactive Polymers for Waste Heat Recovery.
Kolasińska, Ewa; Kolasiński, Piotr
2016-06-17
This paper reviews materials for thermoelectric waste heat recovery, and discusses selected industrial and distributed waste heat sources as well as recovery methods that are currently applied. Thermoelectric properties, especially electrical conductivity, thermopower, thermal conductivity and the thermoelectric figures of merit, are considered when evaluating thermoelectric materials for waste heat recovery. Alloys and oxides are briefly discussed as materials suitable for medium- and high-grade sources. Electroactive polymers are presented as a new group of materials for low-grade sources. Polyaniline is a particularly fitting polymer for these purposes. We also discuss types of modifiers and modification methods, and their influence on the thermoelectric performance of this class of polymers.
A novel process for preparing fireproofing materials from various industrial wastes.
Su, Yi; Wang, Lei; Zhang, Fu-Shen
2018-05-09
In the current study, the possibility of incorporating various industrial wastes into fireproofing materials was investigated. It was found that the newly developed materials showed excellent air sealing and fireproofing performance, with air permeability coefficients 3 to 4 orders of magnitude smaller than traditional fire prevention materials. The influence of different parameters on the air permeability was investigated, and the air sealing mechanisms were clarified through microstructure analysis. In addition, the workability and mechanical properties of the fireproofing materials for practical application in coal mine were studied. The new materials derived from industrial wastes had a compact and monolithic structure, and the excellent air tightness could be attributed to the pozzolanic activity of the industrial wastes and the film-forming property of organic polymers. Among the industrial wastes examined, a special coal fly ash with high pozzolanic activity and little free calcium oxide derived the best product with air permeability coefficient, tensile strength and breaking elongation of 4.17 × 10 -8 m 2 /s, 2.14 MPa and 48.90%, respectively. This study provides an economical, environmentally friendly and promising approach for industrial wastes recycling. Copyright © 2018 Elsevier Ltd. All rights reserved.
Field scale manure born animal waste management : GIS application
USDA-ARS?s Scientific Manuscript database
Intensive beef backgrounding often accumulate manure born soil nutrients, microbes, and pharmaceuticals at different site locations. Unless properly managed, such waste materials can pollute surrounding soil and water sources. Soil sampling from these sites helps determining waste material levels bu...
40 CFR 227.12 - Insoluble wastes.
Code of Federal Regulations, 2012 CFR
2012-07-01
... Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) OCEAN DUMPING CRITERIA FOR THE EVALUATION OF PERMIT APPLICATIONS FOR OCEAN DUMPING OF MATERIALS Environmental Impact § 227.12 Insoluble wastes. (a) Solid wastes consisting of inert natural minerals or materials compatible with the ocean...
[Co-composting high moisture vegetable waste and flower waste in a sequential fed operation].
Zhang, Xiangfeng; Wang, Hongtao; Nie, Yongfeng
2003-11-01
Co-composting of high moisture vegetable wastes (celery and cabbage) and flower wastes (carnation) were studied in a sequential fed bed. The preliminary materials of composting were celery and carnation wastes. The sequential fed materials of composting were cabbage wastes and were fed every 4 days. Moisture content of mixture materials was between 60% and 70%. Composting was done in an aerobic static bed of composting based temperature feedback and control via aeration rate regulation. Aeration was ended when temperature of the pile was about 40 degrees C. Changes of composting of temperature, aeration rate, water content, organic matter, ash, pH, volume, NH4(+)-N, and NO3(-)-N were studied. Results show that co-composting of high moisture vegetable wastes and flower wastes, in a sequential fed aerobic static bed based temperature feedback and control via aeration rate regulation, can stabilize organic matter and removal water rapidly. The sequential fed operation are effective to overcome the difficult which traditional composting cannot applied successfully where high moisture vegetable wastes in more excess of flower wastes, such as Dianchi coastal.
ICPP tank farm closure study. Volume 1
DOE Office of Scientific and Technical Information (OSTI.GOV)
Spaulding, B.C.; Gavalya, R.A.; Dahlmeir, M.M.
1998-02-01
The disposition of INEEL radioactive wastes is now under a Settlement Agreement between the DOE and the State of Idaho. The Settlement Agreement requires that existing liquid sodium bearing waste (SBW), and other liquid waste inventories be treated by December 31, 2012. This agreement also requires that all HLW, including calcined waste, be disposed or made road ready to ship from the INEEL by 2035. Sodium bearing waste (SBW) is produced from decontamination operations and HLW from reprocessing of SNF. SBW and HLW are radioactive and hazardous mixed waste; the radioactive constituents are regulated by DOE and the hazardous constituentsmore » are regulated by the Resource Conservation and Recovery Act (RCRA). Calcined waste, a dry granular material, is produced in the New Waste Calcining Facility (NWCF). Two primary waste tank storage locations exist at the ICPP: Tank Farm Facility (TFF) and the Calcined Solids Storage Facility (CSSF). The TFF has the following underground storage tanks: four 18,400-gallon tanks (WM 100-102, WL 101); four 30,000-gallon tanks (WM 103-106); and eleven 300,000+ gallon tanks. This includes nine 300,000-gallon tanks (WM 182-190) and two 318,000 gallon tanks (WM 180-181). This study analyzes the closure and subsequent use of the eleven 300,000+ gallon tanks. The 18,400 and 30,000-gallon tanks were not included in the work scope and will be closed as a separate activity. This study was conducted to support the HLW Environmental Impact Statement (EIS) waste separations options and addresses closure of the 300,000-gallon liquid waste storage tanks and subsequent tank void uses. A figure provides a diagram estimating how the TFF could be used as part of the separations options. Other possible TFF uses are also discussed in this study.« less
Waste Reduction Model (WARM) Material Descriptions and ...
2017-02-14
This page provides a summary of the materials included in EPA’s Waste Reduction Model (WARM). The page includes a list of materials, a description of the material as defined in the primary data source, and citations for primary data sources.
Each year EPA produces a report called Advancing Sustainable Materials Management: Facts and Figures. It includes information on municipal solid waste (MSW) generation, recycling, composting, combustion with energy recovery and landfilling. The 2014 report provides information on historical tipping fees for MSW, and information on the construction and demolition debris generation, which is outside of the scope of MSW. The Facts and Figures website includes recent reports (2012 to 2014 as well as historical information on materials in the U.S. Municipal Waste Stream, 1960 to 2014 (in tons). The reports for both current and historical waste prevention can be accessed at EPA's SMM website. The recent Annual Facts and Figures reports are accessible at the following link: https://www.epa.gov/smm/advancing-sustainable-materials-management-facts-and-figures-report. Historical data as well as studies and summary tables related to the Advancing Sustainable Materials Management Report are accessible here: https://www.epa.gov/smm/studies-summary-tables-and-data-related-advancing-sustainable-materials-management-report. An excel file containing the data from 1960 - 2014 is located here: https://edg.epa.gov/data/PUBLIC/OLEM/Materials_Municipal_Waste_Stream_1960_to_2014.xlsx. EPA also maintains a list of state and local waste characterization studies (reports are not available for all states). You can search for your state at https://www.epa.gov/smm/advancing-
Preparation of sustainable photocatalytic materials through the valorization of industrial wastes.
Sugrañez, Rafael; Cruz-Yusta, Manuel; Mármol, Isabel; Morales, Julián; Sánchez, Luis
2013-12-01
A new value-added material was developed from wastes to aim for appropriate waste management and sustainable development. This paper reports the valorization of industrial sandblasting operation wastes (SOWs) as new photocatalytic materials. This waste is composed of Fe2 O3 (60.7 %), SiO2 (29.1 %), and Al2 O3 (3.9 %) as the main components. The high presence of iron oxides was used to develop photocatalytic properties through their thermal transformation into α-Fe2 O3 . The new product, SOW-T, exhibited a good behavior towards the photochemical degradation of organic dyes. The preparation of advanced photocatalytic materials that exhibit self-cleaning and depolluting properties was possible by the inclusion of SOW-T and TiO2 in a cement-based mortar. The synergy observed between both materials enhanced their photocatalytic action. To the best of our knowledge, this is the first report that describes the use of transformed wastes based on iron oxide for the photochemical oxidation of NOx gases. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
NASA LaRC Hazardous Material Pharmacy
NASA Technical Reports Server (NTRS)
Esquenet, Remy
1995-01-01
In 1993-1994 the Office of Environmental Engineering contracted SAIC to develop NASA Langley's Pollution Prevention (P2) Program. One of the priority projects identified in this contract was the development of a hazardous waste minimization (HAZMIN)/hazardous materials reutilization (HAZMART) program in the form of a Hazardous Materials Pharmacy. A hazardous materials pharmacy is designed to reduce hazardous material procurement costs and hazardous waste disposal costs. This is accomplished through the collection and reissue of excess hazardous material. Currently, a rarely used hazardous material may be stored in a shop area, unused, until it passes its expiration date. The material is then usually disposed of as a hazardous waste, often at a greater expense than the original cost of the material. While this material was on the shelf expiring, other shop areas may have ordered new supplies of the same material. The hazardous material pharmacy would act as a clearinghouse for such materials. Material that is not going to be used would be turned in to the pharmacy. Other users could then be issued this material free of charge, thereby reducing procurement costs. The use of this material by another shop prevents it from expiring, thereby reducing hazardous waste disposal costs.
TENORM (Technologically Enhanced Naturally Occurring Radioactive Materials)
... and Titanium Mining Wastes Rare Earths Mining Wastes Uranium Mining Wastes Copper Mining and Production Wastes Bauxite and Alumina Production Wastes Energy production Oil and Gas Production Wastes Coal Combustion Residuals Water ...
Application of material flow analysis to municipal solid waste in Maputo City, Mozambique.
Dos Muchangos, Leticia Sarmento; Tokai, Akihiro; Hanashima, Atsuko
2017-03-01
Understanding waste flows within an urban area is important for identifying the main problems and improvement opportunities for efficient waste management. Assessment tools such as material flow analysis (MFA), an extensively applied method in waste management studies, provide a structured and objective evaluating process to characterize the waste management system best, to identify its shortcomings and to propose suitable strategies. This paper presents the application of MFA to municipal solid waste management (MSWM) in Maputo City, the capital of Mozambique. The results included the identification and quantification of the main input and output flows of the MSWM system in 2007 and 2014, from the generation, material recovery and collection, to final disposal and the unaccounted flow of municipal solid waste (MSW). We estimated that the waste generation increased from 397×10 3 tonnes in 2007 to 437×10 3 tonnes in 2014, whereas the total material recovery was insignificant in both years - 3×10 3 and 7×10 3 tonnes, respectively. As for collection and final disposal, the official collection of waste to the local dumpsite in the inner city increased about threefold, from 76×10 3 to 253×10 6 tonnes. For waste unaccounted for, the estimates indicated a reduction during the study period from 300×10 3 to 158×10 3 tonnes, due to the increase of collection services. The emphasized aspects include the need for practical waste reduction strategies, the opportunity to explore the potential for material recovery, careful consideration regarding the growing trend of illegal dumping and the urgency in phasing-out from the harmful practice of open dumping.
Vegas, I; Ibañez, J A; San José, J T; Urzelai, A
2008-01-01
The objective of the study is to analyze the technical suitability of using secondary materials from three waste flows (construction and demolition waste (CDW), Waelz slag and municipal solid waste incineration (MSWI) bottom ash), under the regulations and standards governing the use of materials for road construction. A detailed technical characterization of the materials was carried out according to Spanish General Technical Specifications for Road Construction (PG3). The results show that Waelz slag can be adequate for using in granular structural layers, while CDW fits better as granular material in roadbeds. Likewise, fresh MSWI bottom ash can be used as roadbed material as long as it does not contain a high concentration of soluble salts. This paper also discusses the adequacy of using certain traditional test methods for natural soils when characterizing secondary materials for use as aggregates in road construction.
Recycling and reuse of chosen kinds of waste materials in a building industry
NASA Astrophysics Data System (ADS)
Ferek, B.; Harasymiuk, J.; Tyburski, J.
2016-08-01
The article describes the current state of knowledge and practice in Poland concerning recycling as a method of reuse of chosen groups of waste materials in building industry. The recycling of building scraps is imposed by environmental, economic and technological premises. The issue of usage of sewage residues is becoming a problem of ever -growing gravity as the presence of the increasing number of pernicious contaminants makes their utilization for agricultural purposes more and more limited. The strategies of using waste materials on Polish building sites were analyzed. The analysis of predispositions to salvage for a group of traditional materials, such as: timber, steel, building debris, insulation materials, plastics, and on the example of new materials, such as: artificial light aggregates made by appropriate mixing of siliceous aggregates, glass refuses and sewage residues in order to obtain a commodity which is apt for economic usage also was made in the article. The issue of recycling of waste materials originating from building operations will be presented in the context of the binding home and EU legal regulations. It was proved that the level of recycling of building wastes in Poland is considerably different from one which is achieved in the solid market economies, both in quantity and in assortment. The method of neutralization of building refuses in connection with special waste materials, which are sewage sludge that is presented in the article may be one of the alternative solutions to the problem of recycling of these wastes not only on the Polish scale.
Rincón, Acacio; Marangoni, Mauro; Cetin, Suna; Bernardo, Enrico
2016-07-01
The stabilization of inorganic waste of various nature and origin, in glasses, has been a key strategy for environmental protection for the last decades. When properly formulated, glasses may retain many inorganic contaminants permanently, but it must be acknowledged that some criticism remains, mainly concerning costs and energy use. As a consequence, the sustainability of vitrification largely relies on the conversion of waste glasses into new, usable and marketable glass-based materials, in the form of monolithic and cellular glass-ceramics. The effective conversion in turn depends on the simultaneous control of both starting materials and manufacturing processes. While silica-rich waste favours the obtainment of glass, iron-rich wastes affect the functionalities, influencing the porosity in cellular glass-based materials as well as catalytic, magnetic, optical and electrical properties. Engineered formulations may lead to important reductions of processing times and temperatures, in the transformation of waste-derived glasses into glass-ceramics, or even bring interesting shortcuts. Direct sintering of wastes, combined with recycled glasses, as an example, has been proven as a valid low-cost alternative for glass-ceramic manufacturing, for wastes with limited hazardousness. The present paper is aimed at providing an up-to-date overview of the correlation between formulations, manufacturing technologies and properties of most recent waste-derived, glass-based materials. © 2016 The Authors. Journal of Chemical Technology & Biotechnology published by John Wiley & Sons Ltd on behalf of Society of Chemical Industry.
Energy or compost from green waste? - A CO{sub 2} - Based assessment
DOE Office of Scientific and Technical Information (OSTI.GOV)
Kranert, Martin, E-mail: martin.kranert@iswa.uni-stuttgart.d; Gottschall, Ralf; Bruns, Christian
2010-04-15
Green waste is increasingly extracted from the material recycling chain and, as a result of the financial subsidy arising from the German renewable energy law for the generation of energy from renewable raw materials; it is fed into the energy recovery process in biomass power stations. A reduction in climate relevant gases is also linked to the material recovery of green waste - in particular when using composts gained from the process as a new raw material in different types of potting compost and plant culture media as a replacement for peat. Unlike energy recovery, material valorisation is not currentlymore » subsidised. Through the analysis of material and energy valorisation methods for green waste, with particular emphasis on primary resource consumption and CO{sub 2}-balance, it could be determined that the use of green waste for energy generation and its recovery for material and peat replacement purposes can be considered to be on a par. Based on energy recovery or material oriented scenarios, it can be further deduced that no method on its own will achieve the desired outcome and that a combination of recycling processes is more likely to lead to a significant decrease of greenhouse gas emissions.« less
Material Flow Analysis as a Tool to improve Waste Management Systems: The Case of Austria.
Allesch, Astrid; Brunner, Paul H
2017-01-03
This paper demonstrates the power of material flow analysis (MFA) for designing waste management (WM) systems and for supporting decisions with regards to given environmental and resource goals. Based on a comprehensive case study of a nationwide WM-system, advantages and drawbacks of a mass balance approach are discussed. Using the software STAN, a material flow system comprising all relevant inputs, stocks and outputs of wastes, products, residues, and emissions is established and quantified. Material balances on the level of goods and selected substances (C, Cd, Cr, Cu, Fe, Hg, N, Ni, P, Pb, Zn) are developed to characterize this WM-system. The MFA results serve well as a base for further assessments. Based on given goals, stakeholders engaged in this study selected the following seven criteria for evaluating their WM-system: (i) waste input into the system, (ii) export of waste (iii) gaseous emissions from waste treatment plants, (iv) long-term gaseous and liquid emissions from landfills, (v) waste being recycled, (vi) waste for energy recovery, (vii) total waste landfilled. By scenario analysis, strengths and weaknesses of different measures were identified. The results reveal the benefits of a mass balance approach due to redundancy, data consistency, and transparency for optimization, design, and decision making in WM.
de Guardia, A; Petiot, C; Benoist, J C; Druilhe, C
2012-06-01
The paper focused on the modelling of the heat transfers during composting in a pilot-scale reactor under forced aeration. The model took into account the heat production and the transfers by evaporation, convection between material and gas crossing the material, conduction and surface convection between gas and material in bottom and upper parts of the reactor. The model was adjusted thanks to the measurements practised during fifteen composting experiments in which five organic wastes were, each, composted under three constant aeration rates. Heat production was considered proportional to oxygen consumption rate and the enthalpy per mole oxygen consumed was assumed constant. The convective heat transfer coefficients were determined on basis of the continuous measurements of the temperatures of both the lid and the bottom part of the reactor. The model allowed a satisfying prediction of the temperature of the composting material. In most cases, the mean absolute discard between the experimental and the simulated temperatures was inferior to 2.5°C and the peaks of temperature occurred with less than 8h delay. For the half of the experiments the temperature discard between the simulated peak and the experimental one was inferior to 5°C. On basis of the calculation of a stoichiometric production of water through oxidation of the biodegradable organic matter, the simulation of water going out from material as vapour also allowed a rather satisfying prediction of the mass of water in final mixture. The influence of the aeration rate on every type of heat loss was characterized. Finally, the model was used to evaluate the impacts on material temperature caused by the change of the insulation thickness, the ambient temperature, take the lid away, the increase or the decrease of the mass of waste to compost. Copyright © 2012 Elsevier Ltd. All rights reserved.
DOE Office of Scientific and Technical Information (OSTI.GOV)
Guardia, A. de, E-mail: amaury.de-guardia@irstea.fr; Universite Europeenne de Bretagne, F-35000 Rennes; Petiot, C.
2012-06-15
The paper focused on the modelling of the heat transfers during composting in a pilot-scale reactor under forced aeration. The model took into account the heat production and the transfers by evaporation, convection between material and gas crossing the material, conduction and surface convection between gas and material in bottom and upper parts of the reactor. The model was adjusted thanks to the measurements practised during fifteen composting experiments in which five organic wastes were, each, composted under three constant aeration rates. Heat production was considered proportional to oxygen consumption rate and the enthalpy per mole oxygen consumed was assumedmore » constant. The convective heat transfer coefficients were determined on basis of the continuous measurements of the temperatures of both the lid and the bottom part of the reactor. The model allowed a satisfying prediction of the temperature of the composting material. In most cases, the mean absolute discard between the experimental and the simulated temperatures was inferior to 2.5 Degree-Sign C and the peaks of temperature occurred with less than 8 h delay. For the half of the experiments the temperature discard between the simulated peak and the experimental one was inferior to 5 Degree-Sign C. On basis of the calculation of a stoichiometric production of water through oxidation of the biodegradable organic matter, the simulation of water going out from material as vapour also allowed a rather satisfying prediction of the mass of water in final mixture. The influence of the aeration rate on every type of heat loss was characterized. Finally, the model was used to evaluate the impacts on material temperature caused by the change of the insulation thickness, the ambient temperature, take the lid away, the increase or the decrease of the mass of waste to compost.« less
Copper removal by algal biomass: biosorbents characterization and equilibrium modelling.
Vilar, Vítor J P; Botelho, Cidália M S; Pinheiro, José P S; Domingos, Rute F; Boaventura, Rui A R
2009-04-30
The general principles of Cu(II) binding to algal waste from agar extraction, composite material and algae Gelidium, and different modelling approaches, are discussed. FTIR analyses provided a detailed description of the possible binding groups present in the biosorbents, as carboxylic groups (D-glucuronic and pyruvic acids), hydroxyl groups (cellulose, agar and floridean starch) and sulfonate groups (sulphated galactans). Potentiometric acid-base titrations showed a heterogeneous distribution of two major binding groups, carboxyl and hydroxyl, following the quasi-Gaussian affinity constant distribution suggested by Sips, which permitted to estimate the maximum amount of acid functional groups (0.36, 0.25 and 0.1 mmol g(-1)) and proton binding parameters (pK(H)=5.0, 5.3 and 4.4; m(H)=0.43, 0.37, 0.33), respectively for algae Gelidium, algal waste and composite material. A non-ideal, semi-empirical, thermodynamically consistent (NICCA) isotherm fitted better the experimental ion binding data for different pH values and copper concentrations, considering only the acid functional groups, than the discrete model. Values of pK(M) (3.2; 3.6 and 3.3), n(M) (0.98, 0.91, 1.0) and p (0.67, 0.53 and 0.43) were obtained, respectively for algae Gelidium, algal waste and composite material. NICCA model reflects the complex macromolecular systems that take part in biosorption considering the heterogeneity of the biosorbent, the competition between protons and metals ions to the binding sites and the stoichiometry for different ions.
Leaded electronic waste is a possible source material for lead-contaminated jewelry.
Weidenhamer, Jeffrey D; Clement, Michael L
2007-10-01
Highly leaded jewelry, often imported from China, remains widely available in the United States. Leaded electronic waste is exported from the United States to several Asian countries where solder is recovered and circuit boards are stripped of parts in small workshops. To assess whether electronic waste is being recycled into the jewelry, lead, tin and copper content of highly leaded jewelry samples were determined by atomic absorption spectrometry. Sixteen jewelry items previously determined to contain 20-80% lead by weight were analyzed. Samples were digested in nitric acid for analysis of lead and copper, and in aqua regia for analysis of tin. Six samples contained significant amounts of tin, from 20.8% to 29.9% by weight. In addition, copper was a significant minor component of five of these samples (up to 4% by weight). Copper (present at 10-40% by weight in circuit boards) was shown to rapidly move into heated lead-tin solder. The combined lead-tin-copper content of these six items ranges from 93.5% to 100%, suggestive of a solder-based source material. These results are consistent with the hypothesis that recycled circuit board solders are being used to produce some of the heavily leaded imported jewelry sold in the United States. Should this hypothesis be substantiated, it suggests that environmental policies to protect children's health must address both proper recycling of source materials as well as restrictions of the lead content in consumer goods.
Proposal for a zero-gravity toilet facility for the space station
NASA Technical Reports Server (NTRS)
Fleri, Edgar L., Jr.; Galliano, Paul A.; Harrison, Mark E.; Johnson, William B.; Meyer, Gregory J.
1989-01-01
This proposed toilet facility has a straightforward design. It has few moving parts and is easily maintained. Air and water flow provide sanitary movement of the waste. The toilet's chambers are coated with Teflon which, along with the water flow, makes it self-cleaning. An added disinfectant called Betadiene kills any bacteria that may form on the chamber walls. The chair is contoured to take into account the neutral body position and the necessary strain position for defecation. Restraints at the ankles, knees, and midsection hold the body in the chair. The waste is stored in discs of Gortex material which are inside a replaceable storage chamber. This chamber can be removed, capped and stored until eventual return to earth.