Sample records for waste package thermal

  1. Calculation of the Naval Long and Short Waste Package Three-Dimensional Thermal Interface Temperatures

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    H. Marr

    2006-10-25

    The purpose of this calculation is to evaluate the thermal performance of the Naval Long and Naval Short spent nuclear fuel (SNF) waste packages (WP) in the repository emplacement drift. The scope of this calculation is limited to the determination of the temperature profiles upon the surfaces of the Naval Long and Short SNF waste package for up to 10,000 years of emplacement. The temperatures on the top of the outside surface of the naval canister are the thermal interfaces for the Naval Nuclear Propulsion Program (NNPP). The results of this calculation are intended to support Licensing Application design activities.

  2. Development of an air flow calorimeter prototype for the measurement of thermal power released by large radioactive waste packages.

    PubMed

    Razouk, R; Beaumont, O; Failleau, G; Hay, B; Plumeri, S

    2018-03-01

    The estimation and control of the thermal power released by the radioactive waste packages are a key parameter in the management of radioactive waste geological repository sites. In the framework of the European project "Metrology for decommissioning nuclear facilities," the French National Agency of Radioactive Waste Management (ANDRA) collaborates with Laboratoire National de Métrologie et D'essais in order to measure the thermal power up to 500 W of typical real size radioactive waste packages (of at least 0.175 m 3 ) with an uncertainty better than 5% by using a measurement method traceable to the international system of units. One of the selected metrological approaches is based on the principles of air flow calorimetry. This paper describes in detail the development of the air flow calorimeter prototype as well as the design of a radioactive waste package simulator used for its calibration. Results obtained from the calibration of the calorimeter and from the determination of thermal powers are presented here with an investigation of the measurement uncertainties.

  3. Development of an air flow calorimeter prototype for the measurement of thermal power released by large radioactive waste packages

    NASA Astrophysics Data System (ADS)

    Razouk, R.; Beaumont, O.; Failleau, G.; Hay, B.; Plumeri, S.

    2018-03-01

    The estimation and control of the thermal power released by the radioactive waste packages are a key parameter in the management of radioactive waste geological repository sites. In the framework of the European project "Metrology for decommissioning nuclear facilities," the French National Agency of Radioactive Waste Management (ANDRA) collaborates with Laboratoire National de Métrologie et D'essais in order to measure the thermal power up to 500 W of typical real size radioactive waste packages (of at least 0.175 m3) with an uncertainty better than 5% by using a measurement method traceable to the international system of units. One of the selected metrological approaches is based on the principles of air flow calorimetry. This paper describes in detail the development of the air flow calorimeter prototype as well as the design of a radioactive waste package simulator used for its calibration. Results obtained from the calibration of the calorimeter and from the determination of thermal powers are presented here with an investigation of the measurement uncertainties.

  4. Naval Waste Package Design Sensitivity

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    T. Schmitt

    2006-12-13

    The purpose of this calculation is to determine the sensitivity of the structural response of the Naval waste packages to varying inner cavity dimensions when subjected to a comer drop and tip-over from elevated surface. This calculation will also determine the sensitivity of the structural response of the Naval waste packages to the upper bound of the naval canister masses. The scope of this document is limited to reporting the calculation results in terms of through-wall stress intensities in the outer corrosion barrier. This calculation is intended for use in support of the preliminary design activities for the license applicationmore » design of the Naval waste package. It examines the effects of small changes between the naval canister and the inner vessel, and in these dimensions, the Naval Long waste package and Naval Short waste package are similar. Therefore, only the Naval Long waste package is used in this calculation and is based on the proposed potential designs presented by the drawings and sketches in References 2.1.10 to 2.1.17 and 2.1.20. All conclusions are valid for both the Naval Long and Naval Short waste packages.« less

  5. Waste Package Component Design Methodology Report

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    D.C. Mecham

    2004-07-12

    This Executive Summary provides an overview of the methodology being used by the Yucca Mountain Project (YMP) to design waste packages and ancillary components. This summary information is intended for readers with general interest, but also provides technical readers a general framework surrounding a variety of technical details provided in the main body of the report. The purpose of this report is to document and ensure appropriate design methods are used in the design of waste packages and ancillary components (the drip shields and emplacement pallets). The methodology includes identification of necessary design inputs, justification of design assumptions, and usemore » of appropriate analysis methods, and computational tools. This design work is subject to ''Quality Assurance Requirements and Description''. The document is primarily intended for internal use and technical guidance for a variety of design activities. It is recognized that a wide audience including project management, the U.S. Department of Energy (DOE), the U.S. Nuclear Regulatory Commission, and others are interested to various levels of detail in the design methods and therefore covers a wide range of topics at varying levels of detail. Due to the preliminary nature of the design, readers can expect to encounter varied levels of detail in the body of the report. It is expected that technical information used as input to design documents will be verified and taken from the latest versions of reference sources given herein. This revision of the methodology report has evolved with changes in the waste package, drip shield, and emplacement pallet designs over many years and may be further revised as the design is finalized. Different components and analyses are at different stages of development. Some parts of the report are detailed, while other less detailed parts are likely to undergo further refinement. The design methodology is intended to provide designs that satisfy the safety and

  6. Waste disposal package

    DOEpatents

    Smith, M.J.

    1985-06-19

    This is a claim for a waste disposal package including an inner or primary canister for containing hazardous and/or radioactive wastes. The primary canister is encapsulated by an outer or secondary barrier formed of a porous ceramic material to control ingress of water to the canister and the release rate of wastes upon breach on the canister. 4 figs.

  7. Prevention policies addressing packaging and packaging waste: Some emerging trends.

    PubMed

    Tencati, Antonio; Pogutz, Stefano; Moda, Beatrice; Brambilla, Matteo; Cacia, Claudia

    2016-10-01

    Packaging waste is a major issue in several countries. Representing in industrialized countries around 30-35% of municipal solid waste yearly generated, this waste stream has steadily grown over the years even if, especially in Europe, specific recycling and recovery targets have been fixed. Therefore, an increasing attention starts to be devoted to prevention measures and interventions. Filling a gap in the current literature, this explorative paper is a first attempt to map the increasingly important phenomenon of prevention policies in the packaging sector. Through a theoretical sampling, 11 countries/states (7 in and 4 outside Europe) have been selected and analyzed by gathering and studying primary and secondary data. Results show evidence of three specific trends in packaging waste prevention policies: fostering the adoption of measures directed at improving packaging design and production through an extensive use of the life cycle assessment; raising the awareness of final consumers by increasing the accountability of firms; promoting collaborative efforts along the packaging supply chains. Copyright © 2016 Elsevier Ltd. All rights reserved.

  8. Nuclear fuel cycle waste stream immobilization with cermets for improved thermal properties and waste consolidation

    NASA Astrophysics Data System (ADS)

    Ortega, Luis H.; Kaminski, Michael D.; Zeng, Zuotao; Cunnane, James

    2013-07-01

    In the pursuit of methods to improve nuclear waste form thermal properties and combine potential nuclear fuel cycle wastes, a bronze alloy was combined with an alkali, alkaline earth metal bearing ceramic to form a cermet. The alloy was prepared from copper and tin (10 mass%) powders. Pre-sintered ceramic consisting of cesium, strontium, barium and rubidium alumino-silicates was mixed with unalloyed bronze precursor powders and cold pressed to 300 × 103 kPa, then sintered at 600 °C and 800 °C under hydrogen. Cermets were also prepared that incorporated molybdenum, which has a limited solubility in glass, under similar conditions. The cermet thermal conductivities were seven times that of the ceramic alone. These improved thermal properties can reduce thermal gradients within the waste forms thus lowering internal temperature gradients and thermal stresses, allowing for larger waste forms and higher waste loadings. These benefits can reduce the total number of waste packages necessary to immobilize a given amount of high level waste and immobilize troublesome elements.

  9. Hydrothermal carbonization of food waste and associated packaging materials for energy source generation.

    PubMed

    Li, Liang; Diederick, Ryan; Flora, Joseph R V; Berge, Nicole D

    2013-11-01

    Hydrothermal carbonization (HTC) is a thermal conversion technique that converts food wastes and associated packaging materials to a valuable, energy-rich resource. Food waste collected from local restaurants was carbonized over time at different temperatures (225, 250 and 275°C) and solids concentrations to determine how process conditions influence carbonization product properties and composition. Experiments were also conducted to determine the influence of packaging material on food waste carbonization. Results indicate the majority of initial carbon remains integrated within the solid-phase at the solids concentrations and reaction temperatures evaluated. Initial solids concentration influences carbon distribution because of increased compound solubilization, while changes in reaction temperature imparted little change on carbon distribution. The presence of packaging materials significantly influences the energy content of the recovered solids. As the proportion of packaging materials increase, the energy content of recovered solids decreases because of the low energetic retention associated with the packaging materials. HTC results in net positive energy balances at all conditions, except at a 5% (dry wt.) solids concentration. Carbonization of food waste and associated packaging materials also results in net positive balances, but energy needs for solids post-processing are significant. Advantages associated with carbonization are not fully realized when only evaluating process energetics. A more detailed life cycle assessment is needed for a more complete comparison of processes. Copyright © 2013 Elsevier Ltd. All rights reserved.

  10. WASTE PACKAGE REMEDIATION SYSTEM DESCRIPTION DOCUMENT

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    N.D. Sudan

    2000-06-22

    The Waste Package Remediation System remediates waste packages (WPs) and disposal containers (DCs) in one of two ways: preparation of rejected DC closure welds for repair or opening of the DC/WP. DCs are brought to the Waste Package Remediation System for preparation of rejected closure welds if testing of the closure weld by the Disposal Container Handling System indicates an unacceptable, but repairable, welding flaw. DC preparation of rejected closure welds will require removal of the weld in such a way that the Disposal Container Handling System may resume and complete the closure welding process. DCs/WPs are brought to themore » Waste Package Remediation System for opening if the Disposal Container Handling System testing of the DC closure weld indicates an unrepairable welding flaw, or if a WP is recovered from the subsurface repository because suspected damage to the WP or failure of the WP has occurred. DC/WP opening will require cutting of the DC/WP such that a temporary seal may be installed and the waste inside the DC/WP removed by another system. The system operates in a Waste Package Remediation System hot cell located in the Waste Handling Building that has direct access to the Disposal Container Handling System. One DC/WP at a time can be handled in the hot cell. The DC/WP arrives on a transfer cart, is positioned within the cell for system operations, and exits the cell without being removed from the cart. The system includes a wide variety of remotely operated components including a manipulator with hoist and/or jib crane, viewing systems, machine tools for opening WPs, and equipment used to perform pressure and gas composition sampling. Remotely operated equipment is designed to facilitate DC/WP decontamination and hot cell equipment maintenance, and interchangeable components are provided where appropriate. The Waste Package Remediation System interfaces with the Disposal Container Handling System for the receipt and transport of WPs and DCs

  11. Safety evaluation for packaging (onsite) concrete-lined waste packaging

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Romano, T.

    1997-09-25

    The Pacific Northwest National Laboratory developed a package to ship Type A, non-transuranic, fissile excepted quantities of liquid or solid radioactive material and radioactive mixed waste to the Central Waste Complex for storage on the Hanford Site.

  12. Thermal Management and Packaging Reliability (Text Version) |

    Science.gov Websites

    Transportation Research | NREL Thermal Management and Packaging Reliability (Text Version ) Thermal Management and Packaging Reliability (Text Version) Learn how NREL's thermal management and ;Boosting Thermal Management & Reliability of Vehicle Power Electronics." Better power electronics

  13. Conceptual waste packaging options for deep borehole disposal

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Su, Jiann -Cherng; Hardin, Ernest L.

    This report presents four concepts for packaging of radioactive waste for disposal in deep boreholes. Two of these are reference-size packages (11 inch outer diameter) and two are smaller (5 inch) for disposal of Cs/Sr capsules. All four have an assumed length of approximately 18.5 feet, which allows the internal length of the waste volume to be 16.4 feet. However, package length and volume can be scaled by changing the length of the middle, tubular section. The materials proposed for use are low-alloy steels, commonly used in the oil-and-gas industry. Threaded connections between packages, and internal threads used to sealmore » the waste cavity, are common oilfield types. Two types of fill ports are proposed: flask-type and internal-flush. All four package design concepts would withstand hydrostatic pressure of 9,600 psi, with factor safety 2.0. The combined loading condition includes axial tension and compression from the weight of a string or stack of packages in the disposal borehole, either during lower and emplacement of a string, or after stacking of multiple packages emplaced singly. Combined loading also includes bending that may occur during emplacement, particularly for a string of packages threaded together. Flask-type packages would be fabricated and heat-treated, if necessary, before loading waste. The fill port would be narrower than the waste cavity inner diameter, so the flask type is suitable for directly loading bulk granular waste, or loading slim waste canisters (e.g., containing Cs/Sr capsules) that fit through the port. The fill port would be sealed with a tapered, threaded plug, with a welded cover plate (welded after loading). Threaded connections between packages and between packages and a drill string, would be standard drill pipe threads. The internal flush packaging concepts would use semi-flush oilfield tubing, which is internally flush but has a slight external upset at the joints. This type of tubing can be obtained with premium

  14. Radioactive waste disposal package

    DOEpatents

    Lampe, Robert F.

    1986-11-04

    A radioactive waste disposal package comprising a canister for containing vitrified radioactive waste material and a sealed outer shell encapsulating the canister. A solid block of filler material is supported in said shell and convertible into a liquid state for flow into the space between the canister and outer shell and subsequently hardened to form a solid, impervious layer occupying such space.

  15. Radioactive waste disposal package

    DOEpatents

    Lampe, Robert F.

    1986-01-01

    A radioactive waste disposal package comprising a canister for containing vitrified radioactive waste material and a sealed outer shell encapsulating the canister. A solid block of filler material is supported in said shell and convertible into a liquid state for flow into the space between the canister and outer shell and subsequently hardened to form a solid, impervious layer occupying such space.

  16. 10 CFR 60.135 - Criteria for the waste package and its components.

    Code of Federal Regulations, 2010 CFR

    2010-01-01

    ... Section 60.135 Energy NUCLEAR REGULATORY COMMISSION (CONTINUED) DISPOSAL OF HIGH-LEVEL RADIOACTIVE WASTES... for the waste package and its components. (a) High-level-waste package design in general. (1) Packages... package's permanent written records. (c) Waste form criteria for HLW. High-level radioactive waste that is...

  17. Thermal management of LEDs: package to system

    NASA Astrophysics Data System (ADS)

    Arik, Mehmet; Becker, Charles A.; Weaver, Stanton E.; Petroski, James

    2004-01-01

    Light emitting diodes, LEDs, historically have been used for indicators and produced low amounts of heat. The introduction of high brightness LEDs with white light and monochromatic colors have led to a movement towards general illumination. The increased electrical currents used to drive the LEDs have focused more attention on the thermal paths in the developments of LED power packaging. The luminous efficiency of LEDs is soon expected to reach over 80 lumens/W, this is approximately 6 times the efficiency of a conventional incandescent tungsten bulb. Thermal management for the solid-state lighting applications is a key design parameter for both package and system level. Package and system level thermal management is discussed in separate sections. Effect of chip packages on junction to board thermal resistance was compared for both SiC and Sapphire chips. The higher thermal conductivity of the SiC chip provided about 2 times better thermal performance than the latter, while the under-filled Sapphire chip package can only catch the SiC chip performance. Later, system level thermal management was studied based on established numerical models for a conceptual solid-state lighting system. A conceptual LED illumination system was chosen and CFD models were created to determine the availability and limitations of passive air-cooling.

  18. Depleted uranium as a backfill for nuclear fuel waste package

    DOEpatents

    Forsberg, Charles W.

    1998-01-01

    A method for packaging spent nuclear fuel for long-term disposal in a geological repository. At least one spent nuclear fuel assembly is first placed in an unsealed waste package and a depleted uranium fill material is added to the waste package. The depleted uranium fill material comprises flowable particles having a size sufficient to substantially fill any voids in and around the assembly and contains isotopically-depleted uranium in the +4 valence state in an amount sufficient to inhibit dissolution of the spent nuclear fuel from the assembly into a surrounding medium and to lessen the potential for nuclear criticality inside the repository in the event of failure of the waste package. Last, the waste package is sealed, thereby substantially reducing the release of radionuclides into the surrounding medium, while simultaneously providing radiation shielding and increased structural integrity of the waste package.

  19. Waste forms, packages, and seals working group summary

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Sridhar, N.

    1995-09-01

    This article is a summary of the proceedings of a group discussion which took place at the Workshop on the Role of Natural Analogs in Geologic Disposal of High-Level Nuclear Waste in San Antonio, Texas on July 22-25, 1991. The working group concentrated on the subject of radioactive waste forms and packaging. Also included is a description of the use of natural analogs in waste packaging, container materials and waste forms.

  20. DESIGN ANALYSIS FOR THE NAVAL SNF WASTE PACKAGE

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    T.L. Mitchell

    2000-05-31

    The purpose of this analysis is to demonstrate the design of the naval spent nuclear fuel (SNF) waste package (WP) using the Waste Package Department's (WPD) design methodologies and processes described in the ''Waste Package Design Methodology Report'' (CRWMS M&O [Civilian Radioactive Waste Management System Management and Operating Contractor] 2000b). The calculations that support the design of the naval SNF WP will be discussed; however, only a sub-set of such analyses will be presented and shall be limited to those identified in the ''Waste Package Design Sensitivity Report'' (CRWMS M&O 2000c). The objective of this analysis is to describe themore » naval SNF WP design method and to show that the design of the naval SNF WP complies with the ''Naval Spent Nuclear Fuel Disposal Container System Description Document'' (CRWMS M&O 1999a) and Interface Control Document (ICD) criteria for Site Recommendation. Additional criteria for the design of the naval SNF WP have been outlined in Section 6.2 of the ''Waste Package Design Sensitivity Report'' (CRWMS M&O 2000c). The scope of this analysis is restricted to the design of the naval long WP containing one naval long SNF canister. This WP is representative of the WPs that will contain both naval short SNF and naval long SNF canisters. The following items are included in the scope of this analysis: (1) Providing a general description of the applicable design criteria; (2) Describing the design methodology to be used; (3) Presenting the design of the naval SNF waste package; and (4) Showing compliance with all applicable design criteria. The intended use of this analysis is to support Site Recommendation reports and assist in the development of WPD drawings. Activities described in this analysis were conducted in accordance with the technical product development plan (TPDP) ''Design Analysis for the Naval SNF Waste Package (CRWMS M&O 2000a).« less

  1. Depleted uranium as a backfill for nuclear fuel waste package

    DOEpatents

    Forsberg, C.W.

    1998-11-03

    A method is described for packaging spent nuclear fuel for long-term disposal in a geological repository. At least one spent nuclear fuel assembly is first placed in an unsealed waste package and a depleted uranium fill material is added to the waste package. The depleted uranium fill material comprises flowable particles having a size sufficient to substantially fill any voids in and around the assembly and contains isotopically-depleted uranium in the +4 valence state in an amount sufficient to inhibit dissolution of the spent nuclear fuel from the assembly into a surrounding medium and to lessen the potential for nuclear criticality inside the repository in the event of failure of the waste package. Last, the waste package is sealed, thereby substantially reducing the release of radionuclides into the surrounding medium, while simultaneously providing radiation shielding and increased structural integrity of the waste package. 6 figs.

  2. 10 CFR 60.135 - Criteria for the waste package and its components.

    Code of Federal Regulations, 2011 CFR

    2011-01-01

    ... IN GEOLOGIC REPOSITORIES Technical Criteria Design Criteria for the Waste Package § 60.135 Criteria for the waste package and its components. (a) High-level-waste package design in general. (1) Packages for HLW shall be designed so that the in situ chemical, physical, and nuclear properties of the waste...

  3. 10 CFR 60.135 - Criteria for the waste package and its components.

    Code of Federal Regulations, 2013 CFR

    2013-01-01

    ... IN GEOLOGIC REPOSITORIES Technical Criteria Design Criteria for the Waste Package § 60.135 Criteria for the waste package and its components. (a) High-level-waste package design in general. (1) Packages for HLW shall be designed so that the in situ chemical, physical, and nuclear properties of the waste...

  4. 10 CFR 60.135 - Criteria for the waste package and its components.

    Code of Federal Regulations, 2014 CFR

    2014-01-01

    ... IN GEOLOGIC REPOSITORIES Technical Criteria Design Criteria for the Waste Package § 60.135 Criteria for the waste package and its components. (a) High-level-waste package design in general. (1) Packages for HLW shall be designed so that the in situ chemical, physical, and nuclear properties of the waste...

  5. 10 CFR 60.135 - Criteria for the waste package and its components.

    Code of Federal Regulations, 2012 CFR

    2012-01-01

    ... IN GEOLOGIC REPOSITORIES Technical Criteria Design Criteria for the Waste Package § 60.135 Criteria for the waste package and its components. (a) High-level-waste package design in general. (1) Packages for HLW shall be designed so that the in situ chemical, physical, and nuclear properties of the waste...

  6. Oxidation and waste-to-energy output of aluminium waste packaging during incineration: A laboratory study.

    PubMed

    López, Félix A; Román, Carlos Pérez; García-Díaz, Irene; Alguacil, Francisco J

    2015-09-01

    This work reports the oxidation behaviour and waste-to-energy output of different semi-rigid and flexible aluminium packagings when incinerated at 850°C in an air atmosphere enriched with 6% oxygen, in the laboratory setting. The physical properties of the different packagings were determined, including their metallic aluminium contents. The ash contents of their combustion products were determined according to standard BS ISO 1171:2010. The net calorific value, the required energy, and the calorific gain associated with each packaging type were determined following standard BS EN 13431:2004. Packagings with an aluminium lamina thickness of >50μm did not fully oxidise. During incineration, the weight-for-weight waste-to-energy output of the packagings with thick aluminium lamina was lower than that of packagings with thin lamina. The calorific gain depended on the degree of oxidation of the metallic aluminium, but was greater than zero for all the packagings studied. Waste aluminium may therefore be said to act as an energy source in municipal solid waste incineration systems. Copyright © 2015 Elsevier Ltd. All rights reserved.

  7. StreamThermal: A software package for calculating thermal metrics from stream temperature data

    USGS Publications Warehouse

    Tsang, Yin-Phan; Infante, Dana M.; Stewart, Jana S.; Wang, Lizhu; Tingly, Ralph; Thornbrugh, Darren; Cooper, Arthur; Wesley, Daniel

    2016-01-01

    Improving quality and better availability of continuous stream temperature data allows natural resource managers, particularly in fisheries, to understand associations between different characteristics of stream thermal regimes and stream fishes. However, there is no convenient tool to efficiently characterize multiple metrics reflecting stream thermal regimes with the increasing amount of data. This article describes a software program packaged as a library in R to facilitate this process. With this freely-available package, users will be able to quickly summarize metrics that describe five categories of stream thermal regimes: magnitude, variability, frequency, timing, and rate of change. The installation and usage instruction of this package, the definition of calculated thermal metrics, as well as the output format from the package are described, along with an application showing the utility for multiple metrics. We believe this package can be widely utilized by interested stakeholders and greatly assist more studies in fisheries.

  8. Development of bio based plastic materials for packaging from soybeans waste

    NASA Astrophysics Data System (ADS)

    Muhammad, A.; Rashidi, A. R.; Roslan, A.; Idris, S. A.

    2017-09-01

    Demands of plastic material which increase with the increasing of human population encourage researchers to find alternative solution to replace petro based plastic. Thus, in the present study, a novel "green bioplastic" packaging was developed using soybean waste which is a major waste in soy sauce food industry. The evaluation of the effect of ratio of starch, soy waste and plasticizer in this bioplastic production was studied and their characteristics were compared with available bioplastics. Characteristics study was done in terms of burning test, water absorption capacity, thermal and tensile strength measurement and the result obtained were analyzed. The glass transition temperature (Tg) for soy waste bioplastic is 117˚C. The water absorption test shows that an increase in mass up to 114.17% which show large amount of water uptake capacity of this bioplastics. And about 38% of percentage loss was observed when compared with other novel bioplastics. The results clearly show that the amount of glycerol as a plasticizer had an inversely proportional relationship with the Glass Transition Temperature (Tg). The average maximum force value for tensile strength test is 6.71 N. The burning test show that the soy wastes bioplastic release a very faint smell of soy and glue-like substance. The flame ignited a Yellowish-Orange colour and released some sparks. Based on the overall results, soy-based have been proven to become an excellent bio-based packaging materials.

  9. Testing of candidate waste-package backfill and canister materials for basalt

    NASA Astrophysics Data System (ADS)

    Wood, M. I.; Anderson, W. J.; Aden, G. D.

    1982-09-01

    The Basalt Waste Isolation Project (BWIP) is developing a multiple-barrier waste package to contain high-level nuclear waste as part of an overall system (e.g., waste package, repository sealing system, and host rock) designed to isolate the waste in a repository located in basalt beneath the Hanford Site, Richland, Washington. The three basic components of the waste package are the waste form, the canister, and the backfill. An extensive testing program is under way to determine the chemical, physical, and mechanical properties of potential canister and backfill materials. The data derived from this testing program will be used to recommend those materials that most adequately perform the functions assigned to the canister and backfill.

  10. Thermal control of high energy nuclear waste, space option. [mathematical models

    NASA Technical Reports Server (NTRS)

    Peoples, J. A.

    1979-01-01

    Problems related to the temperature and packaging of nuclear waste material for disposal in space are explored. An approach is suggested for solving both problems with emphasis on high energy density waste material. A passive cooling concept is presented which utilized conduction rods that penetrate the inner core. Data are presented to illustrate the effectiveness of the rods and the limit of their capability. A computerized thermal model is discussed and developed for the cooling concept.

  11. Production patterns of packaging waste categories generated at typical Mediterranean residential building worksites

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    González Pericot, N., E-mail: natalia.gpericot@upm.es; Villoria Sáez, P., E-mail: paola.villoria@upm.es; Del Río Merino, M., E-mail: mercedes.delrio@upm.es

    2014-11-15

    Highlights: • On-site segregation level: 1.80%; training and motivation strategies were not effective. • 70% Cardboard waste: from switches and sockets during the building services stage. • 40% Plastic waste: generated during structures and partition works due to palletizing. • >50% Wood packaging waste, basically pallets, generated during the envelope works. - Abstract: The construction sector is responsible for around 28% of the total waste volume generated in Europe, which exceeds the amount of household waste. This has led to an increase of different research studies focusing on construction waste quantification. However, within the research studies made, packaging waste hasmore » been analyzed to a limited extent. This article focuses on the packaging waste stream generated in the construction sector. To this purpose current on-site waste packaging management has been assessed by monitoring ten Mediterranean residential building works. The findings of the experimental data collection revealed that the incentive measures implemented by the construction company to improve on-site waste sorting failed to achieve the intended purpose, showing low segregation ratios. Subsequently, through an analytical study the generation patterns for packaging waste are established, leading to the identification of the prevailing kinds of packaging and the products responsible for their generation. Results indicate that plastic waste generation maintains a constant trend throughout the whole construction process, while cardboard becomes predominant towards the end of the construction works with switches and sockets from the electricity stage. Understanding the production patterns of packaging waste will be beneficial for adapting waste management strategies to the identified patterns for the specific nature of packaging waste within the context of construction worksites.« less

  12. Recycling potential of post-consumer plastic packaging waste in Finland.

    PubMed

    Dahlbo, Helena; Poliakova, Valeria; Mylläri, Ville; Sahimaa, Olli; Anderson, Reetta

    2018-01-01

    Recycling of plastics is urged by the need for closing material loops to maintain our natural resources when striving towards circular economy, but also by the concern raced by observations of plastic scrap in oceans and lakes. Packaging industry is the sector using the largest share of plastics, hence packaging dominates in the plastic waste flow. The aim of this paper was to sum up the recycling potential of post-consumer plastic packaging waste in Finland. This potential was evaluated based on the quantity, composition and mechanical quality of the plastic packaging waste generated by consumers and collected as a source-separated fraction, within the mixed municipal solid waste (MSW) or within energy waste. Based on the assessment 86,000-117,000 tons (18 kg/person/a) of post-consumer plastic packaging waste was generated in Finland in 2014. The majority, 84% of the waste was in the mixed MSW flow in 2014. Due to the launching of new sorting facilities and separate collections for post-consumer plastic packaging in 2016, almost 40% of the post-consumer plastic packaging could become available for recycling. However, a 50% recycling rate for post-consumer plastic packaging (other than PET bottles) would be needed to increase the overall MSW recycling rate from the current 41% by around two percentage points. The share of monotype plastics in the overall MSW plastics fraction was 80%, hence by volume the recycling potential of MSW plastics is high. Polypropylene (PP) and low density polyethylene (LDPE) were the most common plastic types present in mixed MSW, followed by polyethylene terephthalate (PET), polystyrene (PS) and high density polyethylene (HDPE). If all the Finnish plastic packaging waste collected through the three collection types would be available for recycling, then 19,000-25,000 tons of recycled PP and 6000-8000 tons of recycled HDPE would be available on the local market. However, this assessment includes uncertainties due to performing the

  13. Production patterns of packaging waste categories generated at typical Mediterranean residential building worksites.

    PubMed

    González Pericot, N; Villoria Sáez, P; Del Río Merino, M; Liébana Carrasco, O

    2014-11-01

    The construction sector is responsible for around 28% of the total waste volume generated in Europe, which exceeds the amount of household waste. This has led to an increase of different research studies focusing on construction waste quantification. However, within the research studies made, packaging waste has been analyzed to a limited extent. This article focuses on the packaging waste stream generated in the construction sector. To this purpose current on-site waste packaging management has been assessed by monitoring ten Mediterranean residential building works. The findings of the experimental data collection revealed that the incentive measures implemented by the construction company to improve on-site waste sorting failed to achieve the intended purpose, showing low segregation ratios. Subsequently, through an analytical study the generation patterns for packaging waste are established, leading to the identification of the prevailing kinds of packaging and the products responsible for their generation. Results indicate that plastic waste generation maintains a constant trend throughout the whole construction process, while cardboard becomes predominant towards the end of the construction works with switches and sockets from the electricity stage. Understanding the production patterns of packaging waste will be beneficial for adapting waste management strategies to the identified patterns for the specific nature of packaging waste within the context of construction worksites. Copyright © 2014 Elsevier Ltd. All rights reserved.

  14. The Role of Packaging in Solid Waste Management 1966 to 1976.

    ERIC Educational Resources Information Center

    Darnay, Arsen; Franklin, William E.

    The goals of waste processors and packagers obviously differ: the packaging industry seeks durable container material that will be unimpaired by external factors. Until recently, no systematic analysis of the relationship between packaging and solid waste disposal had been undertaken. This three-part document defines these interactions, and the…

  15. Experimental thermal characterization of concrete to be used in CP5.2 packaging system

    NASA Astrophysics Data System (ADS)

    Lo Frano, R.; Maggini, A.; Aquaro, D.

    2017-01-01

    This work deals with the experimental evaluation of the thermal conductivity of a concrete matrix to be used for embedding LILW bituminised Wastes into the packaging system. Such a type of packaging, identified with the acronym CP5.2, has been also qualified by executing at the Lab. Scalbatraio of Dep. of Civil and Industrial Engineering of the University of Pisa, an experimental test campaign accordingly to the IAEA regulations. In particular, the knowledge of the thermal conductivity is important because of the fire or furnace test to carry out in oven at 800 °C for 30 minutes. These data allowed to simulate pre-test conditions and to set up safety and operational fire test procedures. The concrete thermal conductivity was obtained by performing hot wire tests on cylindrical concrete samples for temperatures ranging from 100° to about 800°C. Thermal conductivity is determined at steady state condition. Results indicate a monotonically reduction of the thermal conductivity as the temperature increases. The comparison with concrete thermal conductivity data available in literature indicates a quite good agreement. Finally, visual and X-ray inspection of sample did not highlight the presence of micro/macro damages that would have affected the thermal performance of the concrete under study.

  16. Life cycle assessment of a packaging waste recycling system in Portugal

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Ferreira, S.; Cabral, M.; Cruz, N.F. da, E-mail: nunocruz@tecnico.ulisboa.pt

    Highlights: • We modeled a real packaging waste recycling system. • The analysis was performed using the life cycle assessment methodology. • The 2010 situation was compared with scenarios where the materials were not recycled. • The “Baseline” scenario seems to be more beneficial to the environment. - Abstract: Life Cycle Assessment (LCA) has been used to assess the environmental impacts associated with an activity or product life cycle. It has also been applied to assess the environmental performance related to waste management activities. This study analyses the packaging waste management system of a local public authority in Portugal. Themore » operations of selective and refuse collection, sorting, recycling, landfilling and incineration of packaging waste were considered. The packaging waste management system in operation in 2010, which we called “Baseline” scenario, was compared with two hypothetical scenarios where all the packaging waste that was selectively collected in 2010 would undergo the refuse collection system and would be sent directly to incineration (called “Incineration” scenario) or to landfill (“Landfill” scenario). Overall, the results show that the “Baseline” scenario is more environmentally sound than the hypothetical scenarios.« less

  17. Advances in LED packaging and thermal management materials

    NASA Astrophysics Data System (ADS)

    Zweben, Carl

    2008-02-01

    Heat dissipation, thermal stresses and cost are key light-emitting diode (LED) packaging issues. Heat dissipation limits power levels. Thermal stresses affect performance and reliability. Copper, aluminum and conventional polymeric printed circuit boards (PCBs) have high coefficients of thermal expansion, which can cause high thermal stresses. Most traditional low-coefficient-of-thermal-expansion (CTE) materials like tungsten/copper, which date from the mid 20th century, have thermal conductivities that are no better than those of aluminum alloys, about 200 W/m-K. An OIDA LED workshop cited a need for better thermal materials. There are an increasing number of low-CTE materials with thermal conductivities ranging between that of copper (400 W/m-K) and 1700 W/m-K, and many other low-CTE materials with lower thermal conductivities. Some of these materials are low cost. Others have the potential to be low cost in high-volume production. High-thermal-conductivity materials enable higher power levels, potentially reducing the number of required LEDs. Advanced thermal materials can constrain PCB CTE and greatly increase thermal conductivity. This paper reviews traditional packaging materials and advanced thermal management materials. The latter provide the packaging engineer with a greater range of options than in the past. Topics include properties, status, applications, cost, using advanced materials to fix manufacturing problems, and future directions, including composites reinforced with carbon nanotubes and other thermally conductive materials.

  18. Tritium waste package

    DOEpatents

    Rossmassler, Rich; Ciebiera, Lloyd; Tulipano, Francis J.; Vinson, Sylvester; Walters, R. Thomas

    1995-01-01

    A containment and waste package system for processing and shipping tritium xide waste received from a process gas includes an outer drum and an inner drum containing a disposable molecular sieve bed (DMSB) seated within outer drum. The DMSB includes an inlet diffuser assembly, an outlet diffuser assembly, and a hydrogen catalytic recombiner. The DMSB absorbs tritium oxide from the process gas and converts it to a solid form so that the tritium is contained during shipment to a disposal site. The DMSB is filled with type 4A molecular sieve pellets capable of adsorbing up to 1000 curies of tritium. The recombiner contains a sufficient amount of catalyst to cause any hydrogen add oxygen present in the process gas to recombine to form water vapor, which is then adsorbed onto the DMSB.

  19. A Fruit of Yucca Mountain: The Remote Waste Package Closure System

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Kevin Skinner; Greg Housley; Colleen Shelton-Davis

    2011-11-01

    Was the death of the Yucca Mountain repository the fate of a technical lemon or a political lemon? Without caution, this debate could lure us away from capitalizing on the fruits of the project. In March 2009, Idaho National Laboratory (INL) successfully demonstrated the Waste Package Closure System, a full-scale prototype system for closing waste packages that were to be entombed in the now abandoned Yucca Mountain repository. This article describes the system, which INL designed and built, to weld the closure lids on the waste packages, nondestructively examine the welds using four different techniques, repair the welds if necessary,more » mitigate crack initiating stresses in the surfaces of the welds, evacuate and backfill the packages with an inert gas, and perform all of these tasks remotely. As a nation, we now have a proven method for securely sealing nuclear waste packages for long term storage—regardless of whether or not the future destination for these packages will be an underground repository. Additionally, many of the system’s features and concepts may benefit other remote nuclear applications.« less

  20. 10 CFR 60.143 - Monitoring and testing waste packages.

    Code of Federal Regulations, 2010 CFR

    2010-01-01

    ... package monitoring program shall include laboratory experiments which focus on the internal condition of... the laboratory experiments. (d) The waste package monitoring program shall continue as long as...

  1. 10 CFR 60.143 - Monitoring and testing waste packages.

    Code of Federal Regulations, 2011 CFR

    2011-01-01

    ... package monitoring program shall include laboratory experiments which focus on the internal condition of... the laboratory experiments. (d) The waste package monitoring program shall continue as long as...

  2. 10 CFR 60.143 - Monitoring and testing waste packages.

    Code of Federal Regulations, 2012 CFR

    2012-01-01

    ... package monitoring program shall include laboratory experiments which focus on the internal condition of... the laboratory experiments. (d) The waste package monitoring program shall continue as long as...

  3. 10 CFR 60.143 - Monitoring and testing waste packages.

    Code of Federal Regulations, 2013 CFR

    2013-01-01

    ... package monitoring program shall include laboratory experiments which focus on the internal condition of... the laboratory experiments. (d) The waste package monitoring program shall continue as long as...

  4. 10 CFR 60.143 - Monitoring and testing waste packages.

    Code of Federal Regulations, 2014 CFR

    2014-01-01

    ... package monitoring program shall include laboratory experiments which focus on the internal condition of... the laboratory experiments. (d) The waste package monitoring program shall continue as long as...

  5. Tritium waste package

    DOEpatents

    Rossmassler, R.; Ciebiera, L.; Tulipano, F.J.; Vinson, S.; Walters, R.T.

    1995-11-07

    A containment and waste package system for processing and shipping tritium oxide waste received from a process gas includes an outer drum and an inner drum containing a disposable molecular sieve bed (DMSB) seated within the outer drum. The DMSB includes an inlet diffuser assembly, an outlet diffuser assembly, and a hydrogen catalytic recombiner. The DMSB absorbs tritium oxide from the process gas and converts it to a solid form so that the tritium is contained during shipment to a disposal site. The DMSB is filled with type 4A molecular sieve pellets capable of adsorbing up to 1000 curies of tritium. The recombiner contains a sufficient amount of catalyst to cause any hydrogen and oxygen present in the process gas to recombine to form water vapor, which is then adsorbed onto the DMSB. 1 fig.

  6. Management of packaging waste in Poland--development agenda and accession to the EU.

    PubMed

    Grodzińska-Jurczak, Małgorzata; Zakowska, Hanna; Read, Adam

    2004-06-01

    In recent years the issue of the municipal waste in Poland has become increasingly topical, with a considerable rise in the waste generation, much of which can be attributed to a boom in product packaging (mainly plastic). The annual production of plastics packaging has been constantly increasing over the last 20 to 30 years, and now exceeds 3.7 million tons. Due to a lack of processing technologies and poorly developed selective segregation system, packaging waste is still treated as a part of the municipal solid waste (MSW) stream, most of which is landfilled. As a result of Poland's access to the European Union, previous legal regulations governing municipal waste management have been harmonized with those binding on the member countries. One of the main changes, the most revolutionary one, is to make entrepreneurs liable for environmental risks resulting from the introduction of packaging to the market, and for its recycling. In practice, all entrepreneurs are to ensure recovery, and recycling, of used packaging from products introduced to the market at the required level. In recent year, the required recycling levels were fulfilled for all types of materials but mainly by large institutions using grouped and transport packaging waste for that matter. Household packaging gathered in the selective segregation system at the municipalities was practically left alone. This paper is an attempt to describe the system and assess the first year of functioning of the new, revamped system of packaging waste management in Poland. Recommendations are made relating to those features that need to be included in packaging waste management systems in order to maximize their sustainability and harmonization with the EU legal system.

  7. Advances in photonics thermal management and packaging materials

    NASA Astrophysics Data System (ADS)

    Zweben, Carl

    2008-02-01

    Heat dissipation, thermal stresses, and cost are key packaging design issues for virtually all semiconductors, including photonic applications such as diode lasers, light-emitting diodes (LEDs), solid state lighting, photovoltaics, displays, projectors, detectors, sensors and laser weapons. Heat dissipation and thermal stresses affect performance and reliability. Copper, aluminum and conventional polymeric printed circuit boards (PCBs) have high coefficients of thermal expansion, which can cause high thermal stresses. Most traditional low-coefficient-of-thermal-expansion (CTE) materials like tungsten/copper, which date from the mid 20 th century, have thermal conductivities that are no better than those of aluminum alloys, about 200 W/m-K. There are an increasing number of low-CTE materials with thermal conductivities ranging between that of copper (400 W/m-K) and 1700 W/m-K, and many other new low-CTE materials with lower thermal conductivities. An important benefit of low-CTE materials is that they allow use of hard solders. Some advanced materials are low cost. Others have the potential to be low cost in high-volume production. High-thermal-conductivity materials enable higher power levels, potentially reducing the number of required devices. Advanced thermal materials can constrain PCB CTE and greatly increase thermal conductivity. This paper reviews traditional packaging materials and advanced thermal management materials. The latter provide the packaging engineer with a greater range of options than in the past. Topics include properties, status, applications, cost, using advanced materials to fix manufacturing problems, and future directions, including composites reinforced with carbon nanotubes and other thermally conductive materials.

  8. Packaging waste recycling in Europe: is the industry paying for it?

    PubMed

    da Cruz, Nuno Ferreira; Ferreira, Sandra; Cabral, Marta; Simões, Pedro; Marques, Rui Cunha

    2014-02-01

    This paper describes and examines the schemes established in five EU countries for the recycling of packaging waste. The changes in packaging waste management were mainly implemented since the Directive 94/62/EC on packaging and packaging waste entered into force. The analysis of the five systems allowed the authors to identify very different approaches to cope with the same problem: meet the recovery and recycling targets imposed by EU law. Packaging waste is a responsibility of the industry. However, local governments are generally in charge of waste management, particularly in countries with Green Dot schemes or similar extended producer responsibility systems. This leads to the need of establishing a system of financial transfers between the industry and the local governments (particularly regarding the extra costs involved with selective collection and sorting). Using the same methodological approach, the authors also compare the costs and benefits of recycling from the perspective of local public authorities for France, Portugal and Romania. Since the purpose of the current paper is to take note of who is paying for the incremental costs of recycling and whether the industry (i.e. the consumer) is paying for the net financial costs of packaging waste management, environmental impacts are not included in the analysis. The work carried out in this paper highlights some aspects that are prone to be improved and raises several questions that will require further research. In the three countries analyzed more closely in this paper the industry is not paying the net financial cost of packaging waste management. In fact, if the savings attained by diverting packaging waste from other treatment (e.g. landfilling) and the public subsidies to the investment on the "recycling system" are not considered, it seems that the industry should increase the financial support to local authorities (by 125% in France, 50% in Portugal and 170% in Romania). However, in France and

  9. Packaging waste prevention activities: A life cycle assessment of the effects on a regional waste management system.

    PubMed

    Nessi, Simone; Rigamonti, Lucia; Grosso, Mario

    2015-09-01

    A life cycle assessment was carried out to evaluate the effects of two packaging waste prevention activities on the overall environmental performance of the integrated municipal waste management system of Lombardia region, Italy. The activities are the use of refined tap water instead of bottled water for household consumption and the substitution of liquid detergents packaged in single-use containers by those distributed 'loose' through self-dispensing systems and refillable containers. A 2020 baseline scenario without waste prevention is compared with different waste prevention scenarios, where the two activities are either separately or contemporaneously implemented, by assuming a complete substitution of the traditional product(s). The results show that, when the prevention activities are carried out effectively, a reduction in total waste generation ranging from 0.14% to 0.66% is achieved, corresponding to a 1-4% reduction of the affected packaging waste fractions (plastics and glass). However, the improvements in the overall environmental performance of the waste management system can be far higher, especially when bottled water is substituted. In this case, a nearly 0.5% reduction of the total waste involves improvements ranging mostly between 5 and 23%. Conversely, for the substitution of single-use packaged liquid detergents (0.14% reduction of the total waste), the achieved improvements do not exceed 3% for nearly all impact categories. © The Author(s) 2015.

  10. Secondary Waste Form Down Selection Data Package – Ceramicrete

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Cantrell, Kirk J.; Westsik, Joseph H.

    2011-08-31

    As part of high-level waste pretreatment and immobilized low activity waste processing, liquid secondary wastes will be generated that will be transferred to the Effluent Treatment Facility on the Hanford Site for further treatment. These liquid secondary wastes will be converted to stable solid waste forms that will be disposed in the Integrated Disposal Facility. Currently, four waste forms are being considered for stabilization and solidification of the liquid secondary wastes. These waste forms are Cast Stone, Ceramicrete, DuraLith, and Fluidized Bed Steam Reformer. The preferred alternative will be down selected from these four waste forms. Pacific Northwest National Laboratorymore » is developing data packages to support the down selection process. The objective of the data packages is to identify, evaluate, and summarize the existing information on the four waste forms being considered for stabilization and solidification of the liquid secondary wastes. The information included will be based on information available in the open literature and from data obtained from testing currently underway. This data package is for the Ceramicrete waste form. Ceramicrete is a relatively new engineering material developed at Argonne National Laboratory to treat radioactive and hazardous waste streams (e.g., Wagh 2004; Wagh et al. 1999a, 2003; Singh et al. 2000). This cement-like waste form can be used to treat solids, liquids, and sludges by chemical immobilization, microencapsulation, and/or macroencapsulation. The Ceramicrete technology is based on chemical reaction between phosphate anions and metal cations to form a strong, dense, durable, low porosity matrix that immobilizes hazardous and radioactive contaminants as insoluble phosphates and microencapsulates insoluble radioactive components and other constituents that do not form phosphates. Ceramicrete is a type of phosphate-bonded ceramic, which are also known as chemically bonded phosphate ceramics. The

  11. Packaging waste recycling in Europe: Is the industry paying for it?

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Ferreira da Cruz, Nuno, E-mail: nunocruz@ist.utl.pt; Ferreira, Sandra; Cabral, Marta

    Highlights: • We study the recycling schemes of France, Germany, Portugal, Romania and the UK. • The costs and benefits of recycling are compared for France, Portugal and Romania. • The balance of costs and benefits depend on the perspective (strictly financial/economic). • Financial supports to local authorities ought to promote cost-efficiency. - Abstract: This paper describes and examines the schemes established in five EU countries for the recycling of packaging waste. The changes in packaging waste management were mainly implemented since the Directive 94/62/EC on packaging and packaging waste entered into force. The analysis of the five systems allowedmore » the authors to identify very different approaches to cope with the same problem: meet the recovery and recycling targets imposed by EU law. Packaging waste is a responsibility of the industry. However, local governments are generally in charge of waste management, particularly in countries with Green Dot schemes or similar extended producer responsibility systems. This leads to the need of establishing a system of financial transfers between the industry and the local governments (particularly regarding the extra costs involved with selective collection and sorting). Using the same methodological approach, the authors also compare the costs and benefits of recycling from the perspective of local public authorities for France, Portugal and Romania. Since the purpose of the current paper is to take note of who is paying for the incremental costs of recycling and whether the industry (i.e. the consumer) is paying for the net financial costs of packaging waste management, environmental impacts are not included in the analysis. The work carried out in this paper highlights some aspects that are prone to be improved and raises several questions that will require further research. In the three countries analyzed more closely in this paper the industry is not paying the net financial cost of packaging

  12. Thermal Pretreatment For TRU Waste Sorting

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Sasaki, T.; Aoyama, Y.; Miyamoto, Y.

    2008-07-01

    Japan Atomic Energy Agency conducted a study on thermal treatment of TRU waste to develop a removal technology for materials that are forbidden for disposal. The thermal pretreatment in which hot nitrogen and/or air is introduced to the waste is a process of removing combustibles, liquids, and low melting point metals from PVC wrapped TRU waste. In this study, thermal pretreatment of simulated waste was conducted using a desktop thermal treatment vessel and a laboratory scale thermal pretreatment system. Combustibles and low melting point metals are effectively separated from wastes by choosing appropriate temperature of flowing gases. Combustibles such asmore » papers, PVC, oil, etc. were removed and low melting point metals such as zinc, lead, and aluminum were separated from the simulated waste by the thermal pretreatment. (authors)« less

  13. Waste Generator Instructions: Key to Successful Implementation of the US DOE's 435.1 for Transuranic Waste Packaging Instructions (LA-UR-12-24155) - 13218

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    French, David M.; Hayes, Timothy A.; Pope, Howard L.

    In times of continuing fiscal constraints, a management and operation tool that is straightforward to implement, works as advertised, and virtually ensures compliant waste packaging should be carefully considered and employed wherever practicable. In the near future, the Department of Energy (DOE) will issue the first major update to DOE Order 435.1, Radioactive Waste Management. This update will contain a requirement for sites that do not have a Waste Isolation Pilot Plant (WIPP) waste certification program to use two newly developed technical standards: Contact-Handled Defense Transuranic Waste Packaging Instructions and Remote-Handled Defense Transuranic Waste Packaging Instructions. The technical standards aremore » being developed from the DOE O 435.1 Notice, Contact-Handled and Remote-Handled Transuranic Waste Packaging, approved August 2011. The packaging instructions will provide detailed information and instruction for packaging almost every conceivable type of transuranic (TRU) waste for disposal at WIPP. While providing specificity, the packaging instructions leave to each site's own discretion the actual mechanics of how those Instructions will be functionally implemented at the floor level. While the Technical Standards are designed to provide precise information for compliant packaging, the density of the information in the packaging instructions necessitates a type of Rosetta Stone that translates the requirements into concise, clear, easy to use and operationally practical recipes that are waste stream and facility specific for use by both first line management and hands-on operations personnel. The Waste Generator Instructions provide the operator with step-by-step instructions that will integrate the sites' various operational requirements (e.g., health and safety limits, radiological limits or dose limits) and result in a WIPP certifiable waste and package that can be transported to and emplaced at WIPP. These little known but widely productive

  14. Chip-scale thermal management of high-brightness LED packages

    NASA Astrophysics Data System (ADS)

    Arik, Mehmet; Weaver, Stanton

    2004-10-01

    The efficiency and reliability of the solid-state lighting devices strongly depend on successful thermal management. Light emitting diodes, LEDs, are a strong candidate for the next generation, general illumination applications. LEDs are making great strides in terms of lumen performance and reliability, however the barrier to widespread use in general illumination still remains the cost or $/Lumen. LED packaging designers are pushing the LED performance to its limits. This is resulting in increased drive currents, and thus the need for lower thermal resistance packaging designs. As the power density continues to rise, the integrity of the package electrical and thermal interconnect becomes extremely important. Experimental results with high brightness LED packages show that chip attachment defects can cause significant thermal gradients across the LED chips leading to premature failures. A numerical study was also carried out with parametric models to understand the chip active layer temperature profile variation due to the bump defects. Finite element techniques were utilized to evaluate the effects of localized hot spots at the chip active layer. The importance of "zero defects" in one of the more popular interconnect schemes; the "epi down" soldered flip chip configuration is investigated and demonstrated.

  15. Reliability of CCGA 1152 and CCGA 1272 Interconnect Packages for Extreme Thermal Environments

    NASA Technical Reports Server (NTRS)

    Ramesham, Rajeshuni

    2013-01-01

    Ceramic column grid array (CCGA) packages have been increasing in use based on their advantages of high interconnect density, very good thermal and electrical performance, and compatibility with standard surface-mount packaging assembly processes. CCGA packages are used in space applications such as in logics and microprocessor functions, telecommunications, flight avionics, and payload electronics. As these packages tend to have less solder joint strain relief than leaded packages, the reliability of CCGA packages is very important for short- and long-term space missions. Certain planetary satellites require operations of thermally uncontrolled hardware under extremely cold and hot temperatures with large diurnal temperature change from day to night. The planetary protection requires the hardware to be baked at +125 C for 72 hours to kill microbugs to avoid any biological contamination, especially for sample return missions. Therefore, the present CCGA package reliability research study has encompassed the temperature range of 185 to +125 C to cover various NASA deep space missions. Advanced 1152 and 1272 CCGA packaging interconnects technology test hardware objects have been subjected to ex treme temperature thermal cycles from 185 to +125 C. X-ray inspections of CCGA packages have been made before thermal cycling. No anomalous behavior and process problems were observed in the x-ray images. The change in resistance of the daisy-chained CCGA interconnects was measured as a function of increasing number of thermal cycles. Electrical continuity measurements of daisy chains have shown no anomalies, even until 596 thermal cycles. Optical inspections of hardware have shown a significant fatigue for CCGA 1152 packages over CCGA 1272 packages. No catastrophic failures have been observed yet in the results. Process qualification and assembly are required to optimize the CCGA assembly processes. Optical inspections of CCGA boards have been made after 258 and 596 thermal

  16. Thermal valorization of post-consumer film waste in a bubbling bed gasifier

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Martínez-Lera, S., E-mail: susanamartinezlera@gmail.com; Torrico, J.; Pallarés, J.

    2013-07-15

    Highlights: • Film waste from packaging is a common waste, a fraction of which is not recyclable. • Gasification can make use of the high energy value of the non-recyclable fraction. • This waste and two reference polymers were gasified in a bubbling bed reactor. • This experimental research proves technical feasibility of the process. • It also analyzes impact of composition and ER on the performance of the plant. - Abstract: The use of plastic bags and film packaging is very frequent in manifold sectors and film waste is usually present in different sources of municipal and industrial wastes.more » A significant part of it is not suitable for mechanical recycling but could be safely transformed into a valuable gas by means of thermal valorization. In this research, the gasification of film wastes has been experimentally investigated through experiments in a fluidized bed reactor of two reference polymers, polyethylene and polypropylene, and actual post-consumer film waste. After a complete experimental characterization of the three materials, several gasification experiments have been performed to analyze the influence of the fuel and of equivalence ratio on gas production and composition, on tar generation and on efficiency. The experiments prove that film waste and analogue polymer derived wastes can be successfully gasified in a fluidized bed reactor, yielding a gas with a higher heating value in a range from 3.6 to 5.6 MJ/m{sup 3} and cold gas efficiencies up to 60%.« less

  17. Thermal shock testing for assuring reliability of glass-sealed microelectronic packages

    NASA Technical Reports Server (NTRS)

    Thomas, Walter B., III; Lewis, Michael D.

    1991-01-01

    Tests were performed to determine if thermal shocking is destructive to glass-to-metal seal microelectronic packages and if thermal shock step stressing can compare package reliabilities. Thermal shocking was shown to be not destructive to highly reliable glass seals. Pin-pull tests used to compare the interfacial pin glass strengths showed no differences between thermal shocked and not-thermal shocked headers. A 'critical stress resistance temperature' was not exhibited by the 14 pin Dual In-line Package (DIP) headers evaluated. Headers manufactured in cryogenic nitrogen based and exothermically generated atmospheres showed differences in as-received leak rates, residual oxide depths and pin glass interfacial strengths; these were caused by the different manufacturing methods, in particular, by the chemically etched pins used by one manufacturer. Both header types passed thermal shock tests to temperature differentials of 646 C. The sensitivity of helium leak rate measurements was improved up to 70 percent by baking headers for two hours at 200 C after thermal shocking.

  18. Options for reducing food waste by quality-controlled logistics using intelligent packaging along the supply chain.

    PubMed

    Heising, Jenneke K; Claassen, G D H; Dekker, Matthijs

    2017-10-01

    Optimising supply chain management can help to reduce food waste. This paper describes how intelligent packaging can be used to reduce food waste when used in supply chain management based on quality-controlled logistics (QCL). Intelligent packaging senses compounds in the package that correlate with the critical quality attribute of a food product. The information on the quality of each individual packaged food item that is provided by the intelligent packaging can be used for QCL. In a conceptual approach it is explained that monitoring food quality by intelligent packaging sensors makes it possible to obtain information about the variation in the quality of foods and to use a dynamic expiration date (IP-DED) on a food package. The conceptual approach is supported by quantitative data from simulations on the effect of using the information of intelligent packaging in supply chain management with the goal to reduce food waste. This simulation shows that by using the information on the quality of products that is provided by intelligent packaging, QCL can substantially reduce food waste. When QCL is combined with dynamic pricing based on the predicted expiry dates, a further waste reduction is envisaged.

  19. Rethink Disposable: Packaging Waste Source Reduction Pilot Project

    EPA Pesticide Factsheets

    Information about the SFBWQP Rethink Disposable: Packaging Waste Source Reduction Pilot Project, part of an EPA competitive grant program to improve SF Bay water quality focused on restoring impaired waters and enhancing aquatic resources.

  20. BWR ASSEMBLY SOURCE TERMS FOR WASTE PACKAGE DESIGN

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    T.L. Lotz

    1997-02-15

    This analysis is prepared by the Mined Geologic Disposal System (MGDS) Waste Package Development Department (WPDD) to provide boiling water reactor (BWR) assembly radiation source term data for use during Waste Package (WP) design. The BWR assembly radiation source terms are to be used for evaluation of radiolysis effects at the WP surface, and for personnel shielding requirements during assembly or WP handling operations. The objectives of this evaluation are to generate BWR assembly radiation source terms that bound selected groupings of BWR assemblies, with regard to assembly average burnup and cooling time, which comprise the anticipated MGDS BWR commercialmore » spent nuclear fuel (SNF) waste stream. The source term data is to be provided in a form which can easily be utilized in subsequent shielding/radiation dose calculations. Since these calculations may also be used for Total System Performance Assessment (TSPA), with appropriate justification provided by TSPA, or radionuclide release rate analysis, the grams of each element and additional cooling times out to 25 years will also be calculated and the data included in the output files.« less

  1. Safety evaluation for packaging transportation of equipment for tank 241-C-106 waste sluicing system

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Calmus, D.B.

    1994-08-25

    A Waste Sluicing System (WSS) is scheduled for installation in nd waste storage tank 241-C-106 (106-C). The WSS will transfer high rating sludge from single shell tank 106-C to double shell waste tank 241-AY-102 (102-AY). Prior to installation of the WSS, a heel pump and a transfer pump will be removed from tank 106-C and an agitator pump will be removed from tank 102-AY. Special flexible receivers will be used to contain the pumps during removal from the tanks. After equipment removal, the flexible receivers will be placed in separate containers (packagings). The packaging and contents (packages) will be transferredmore » from the Tank Farms to the Central Waste Complex (CWC) for interim storage and then to T Plant for evaluation and processing for final disposition. Two sizes of packagings will be provided for transferring the equipment from the Tank Farms to the interim storage facility. The packagings will be designated as the WSSP-1 and WSSP-2 packagings throughout the remainder of this Safety Evaluation for Packaging (SEP). The WSSP-1 packagings will transport the heel and transfer pumps from 106-C and the WSSP-2 packaging will transport the agitator pump from 102-AY. The WSSP-1 and WSSP-2 packagings are similar except for the length.« less

  2. Generic Degraded Congiguration Probability Analysis for DOE Codisposal Waste Package

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    S.F.A. Deng; M. Saglam; L.J. Gratton

    2001-05-23

    In accordance with the technical work plan, ''Technical Work Plan For: Department of Energy Spent Nuclear Fuel Work Packages'' (CRWMS M&O 2000c), this Analysis/Model Report (AMR) is developed for the purpose of screening out degraded configurations for U.S. Department of Energy (DOE) spent nuclear fuel (SNF) types. It performs the degraded configuration parameter and probability evaluations of the overall methodology specified in the ''Disposal Criticality Analysis Methodology Topical Report'' (YMP 2000, Section 3) to qualifying configurations. Degradation analyses are performed to assess realizable parameter ranges and physical regimes for configurations. Probability calculations are then performed for configurations characterized by k{submore » eff} in excess of the Critical Limit (CL). The scope of this document is to develop a generic set of screening criteria or models to screen out degraded configurations having potential for exceeding a criticality limit. The developed screening criteria include arguments based on physical/chemical processes and probability calculations and apply to DOE SNF types when codisposed with the high-level waste (HLW) glass inside a waste package. The degradation takes place inside the waste package and is long after repository licensing has expired. The emphasis of this AMR is on degraded configuration screening and the probability analysis is one of the approaches used for screening. The intended use of the model is to apply the developed screening criteria to each DOE SNF type following the completion of the degraded mode criticality analysis internal to the waste package.« less

  3. Probablistic Analyses of Waste Package Quantities Impacted by Potential Igneous Disruption at Yucca Mountain

    NASA Astrophysics Data System (ADS)

    Wallace, M. G.; Iuzzolina, H.

    2005-12-01

    A probabilistic analysis was conducted to estimate ranges for the numbers of waste packages that could be damaged in a potential future igneous event through a repository at Yucca Mountain. The analysis includes disruption from an intrusive igneous event and from an extrusive volcanic event. This analysis supports the evaluation of the potential consequences of future igneous activity as part of the total system performance assessment for the license application for the Yucca Mountain Project (YMP). The first scenario, igneous intrusion, investigated the case where one or more igneous dikes intersect the repository. A swarm of dikes was characterized by distributions of length, width, azimuth, and number of dikes and the spacings between them. Through the use in part of a latin hypercube simulator and a modified video game engine, mathematical relationships were built between those parameters and the number of waste packages hit. Corresponding cumulative distribution function curves (CDFs) for the number of waste packages hit under several different scenarios were calculated. Variations in dike thickness ranges, as well as in repository magma bulkhead positions were examined through sensitivity studies. It was assumed that all waste packages in an emplacement drift would be impacted if that drift was intersected by a dike. Over 10,000 individual simulations were performed. Based on these calculations, out of a total of over 11,000 planned waste packages distributed over an area of approximately 5.5 km2 , the median number of waste packages impacted was roughly 1/10 of the total. Individual cases ranged from 0 waste packages to the entire inventory being impacted. The igneous intrusion analysis involved an explicit characterization of dike-drift intersections, built upon various distributions that reflect the uncertainties associated with the inputs. The second igneous scenario, volcanic eruption (eruptive conduits), considered the effects of conduits formed in

  4. The disposal of nuclear waste in space

    NASA Technical Reports Server (NTRS)

    Burns, R. E.

    1978-01-01

    The important problem of disposal of nuclear waste in space is addressed. A prior study proposed carrying only actinide wastes to space, but the present study assumes that all actinides and all fission products are to be carried to space. It is shown that nuclear waste in the calcine (oxide) form can be packaged in a container designed to provide thermal control, radiation shielding, mechanical containment, and an abort reentry thermal protection system. This package can be transported to orbit via the Space Shuttle. A second Space Shuttle delivers an oxygen-hydrogen orbit transfer vehicle to a rendezvous compatible orbit and the mated OTV and waste package are sent to the preferred destination. Preferred locations are either a lunar crater or a solar orbit. Shuttle traffic densities (which vary in time) are given and the safety of space disposal of wastes discussed.

  5. Investigation of transient thermal dissipation in thinned LSI for advanced packaging

    NASA Astrophysics Data System (ADS)

    Araga, Yuuki; Shimamoto, Haruo; Melamed, Samson; Kikuchi, Katsuya; Aoyagi, Masahiro

    2018-04-01

    Thinning of LSI is necessary for superior form factor and performance in dense cutting-edge packaging technologies. At the same time, degradation of thermal characteristics caused by the steep thermal gradient on LSIs with thinned base silicon is a concern. To manage a thermal environment in advanced packages, thermal characteristics of the thinned LSIs must be clarified. In this study, static and dynamic thermal dissipations were analyzed before and after thinning silicon to determine variations of thermal characteristics in thinned LSI. Measurement results revealed that silicon thinning affects dynamic thermal characteristics as well as static one. The transient variations of thermal characteristics of thinned LSI are precisely verified by analysis using an equivalent model based on the thermal network method. The results of analysis suggest that transient thermal characteristics can be easily estimated by employing the equivalent model.

  6. Estimation of packaged water consumption and associated plastic waste production from household budget surveys

    NASA Astrophysics Data System (ADS)

    Wardrop, Nicola A.; Dzodzomenyo, Mawuli; Aryeetey, Genevieve; Hill, Allan G.; Bain, Robert E. S.; Wright, Jim

    2017-08-01

    Packaged water consumption is growing in low- and middle-income countries, but the magnitude of this phenomenon and its environmental consequences remain unclear. This study aims to quantify both the volumes of packaged water consumed relative to household water requirements and associated plastic waste generated for three West African case study countries. Data from household expenditure surveys for Ghana, Nigeria and Liberia were used to estimate the volumes of packaged water consumed and thereby quantify plastic waste generated in households with and without solid waste disposal facilities. In Ghana, Nigeria and Liberia respectively, 11.3 (95% confidence interval: 10.3-12.4), 10.1 (7.5-12.5), and 0.38 (0.31-0.45) Ml day-1 of sachet water were consumed. This generated over 28 000 tonnes yr-1 of plastic waste, of which 20%, 63% and 57% was among households lacking formal waste disposal facilities in Ghana, Nigeria and Liberia respectively. Reported packaged water consumption provided sufficient water to meet daily household drinking-water requirements for 8.4%, less than 1% and 1.6% of households in Ghana, Nigeria and Liberia respectively. These findings quantify packaged water’s contribution to household water needs in our study countries, particularly Ghana, but indicate significant subsequent environmental repercussions.

  7. Cleanup Verification Package for the 300-18 Waste Site

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    J. M. Capron

    This cleanup verification package documents completion of remedial action for the 300-18 waste site. This site was identified as containing radiologically contaminated soil, metal shavings, nuts, bolts, and concrete.

  8. Thermal valorization of post-consumer film waste in a bubbling bed gasifier.

    PubMed

    Martínez-Lera, S; Torrico, J; Pallarés, J; Gil, A

    2013-07-01

    The use of plastic bags and film packaging is very frequent in manifold sectors and film waste is usually present in different sources of municipal and industrial wastes. A significant part of it is not suitable for mechanical recycling but could be safely transformed into a valuable gas by means of thermal valorization. In this research, the gasification of film wastes has been experimentally investigated through experiments in a fluidized bed reactor of two reference polymers, polyethylene and polypropylene, and actual post-consumer film waste. After a complete experimental characterization of the three materials, several gasification experiments have been performed to analyze the influence of the fuel and of equivalence ratio on gas production and composition, on tar generation and on efficiency. The experiments prove that film waste and analogue polymer derived wastes can be successfully gasified in a fluidized bed reactor, yielding a gas with a higher heating value in a range from 3.6 to 5.6 MJ/m3 and cold gas efficiencies up to 60%. Copyright © 2013 Elsevier Ltd. All rights reserved.

  9. Influence of different materials on the thermal behavior of a CDIP-8 ceramic package

    NASA Astrophysics Data System (ADS)

    Weide, Kirsten; Keck, Christian

    1999-08-01

    The temperature distribution inside a package is determined by the heat transfer from the package to the ambient, depending on the heat conductivities of the different used materials. With the help of finite element simulations the thermal behavior of the package can be characterized. In precise simulations convection and radiation effects have to be taken into account. In this paper the influence of different materials like the ceramic, the pin and die attach material and adhesive material between the chip and the die attach on the thermal resistance of the ceramic package will be investigated. A finite element model of the ceramic package including a voltage regulator on the chip was created. The simulations were carried out with the finite element program ANSYS. An easy way to take the radiation effect into account, which normally is difficult to handle in the simulation, will be shown. The results of the simulations are verified by infrared measurements. A comparison of the thermal resistance between the best case and worst case for different package materials was done. The thermal conductivity of the ceramic material shows the strongest influence on the thermal resistance.

  10. Natural additives and agricultural wastes in biopolymer formulations for food packaging.

    PubMed

    Valdés, Arantzazu; Mellinas, Ana Cristina; Ramos, Marina; Garrigós, María Carmen; Jiménez, Alfonso

    2014-01-01

    The main directions in food packaging research are targeted toward improvements in food quality and food safety. For this purpose, food packaging providing longer product shelf-life, as well as the monitoring of safety and quality based upon international standards, is desirable. New active packaging strategies represent a key area of development in new multifunctional materials where the use of natural additives and/or agricultural wastes is getting increasing interest. The development of new materials, and particularly innovative biopolymer formulations, can help to address these requirements and also with other packaging functions such as: food protection and preservation, marketing and smart communication to consumers. The use of biocomposites for active food packaging is one of the most studied approaches in the last years on materials in contact with food. Applications of these innovative biocomposites could help to provide new food packaging materials with improved mechanical, barrier, antioxidant, and antimicrobial properties. From the food industry standpoint, concerns such as the safety and risk associated with these new additives, migration properties and possible human ingestion and regulations need to be considered. The latest innovations in the use of these innovative formulations to obtain biocomposites are reported in this review. Legislative issues related to the use of natural additives and agricultural wastes in food packaging systems are also discussed.

  11. Natural additives and agricultural wastes in biopolymer formulations for food packaging

    NASA Astrophysics Data System (ADS)

    Valdés, Arantzazu; Mellinas, Ana Cristina; Ramos, Marina; Garrigós, María Carmen; Jiménez, Alfonso

    2014-02-01

    The main directions in food packaging research are targeted towards improvements in food quality and food safety. For this purpose, food packaging providing longer product shelf-life, as well as the monitoring of safety and quality based upon international standards, is desirable. New active packaging strategies represent a key area of development in new multifunctional materials where the use of natural additives and/or agricultural wastes is getting increasing interest. The development of new materials, and particularly innovative biopolymer formulations, can help to address these requirements and also with other packaging functions such as: food protection and preservation, marketing and smart communication to consumers. The use of biocomposites for active food packaging is one of the most studied approaches in the last years on materials in contact with food. Applications of these innovative biocomposites could help to provide new food packaging materials with improved mechanical, barrier, antioxidant and antimicrobial properties. From the food industry standpoint, concerns such as the safety and risk associated with these new additives, migration properties and possible human ingestion and regulations need to be considered. The latest innovations in the use of these innovative formulations to obtain biocomposites are reported in this review. Legislative issues related to the use of natural additives and agricultural wastes in food packaging systems are also discussed.

  12. Natural additives and agricultural wastes in biopolymer formulations for food packaging

    PubMed Central

    Valdés, Arantzazu; Mellinas, Ana Cristina; Ramos, Marina; Garrigós, María Carmen; Jiménez, Alfonso

    2014-01-01

    The main directions in food packaging research are targeted toward improvements in food quality and food safety. For this purpose, food packaging providing longer product shelf-life, as well as the monitoring of safety and quality based upon international standards, is desirable. New active packaging strategies represent a key area of development in new multifunctional materials where the use of natural additives and/or agricultural wastes is getting increasing interest. The development of new materials, and particularly innovative biopolymer formulations, can help to address these requirements and also with other packaging functions such as: food protection and preservation, marketing and smart communication to consumers. The use of biocomposites for active food packaging is one of the most studied approaches in the last years on materials in contact with food. Applications of these innovative biocomposites could help to provide new food packaging materials with improved mechanical, barrier, antioxidant, and antimicrobial properties. From the food industry standpoint, concerns such as the safety and risk associated with these new additives, migration properties and possible human ingestion and regulations need to be considered. The latest innovations in the use of these innovative formulations to obtain biocomposites are reported in this review. Legislative issues related to the use of natural additives and agricultural wastes in food packaging systems are also discussed. PMID:24790975

  13. Shielding Calculations on Waste Packages - The Limits and Possibilities of different Calculation Methods by the example of homogeneous and inhomogeneous Waste Packages

    NASA Astrophysics Data System (ADS)

    Adams, Mike; Smalian, Silva

    2017-09-01

    For nuclear waste packages the expected dose rates and nuclide inventory are beforehand calculated. Depending on the package of the nuclear waste deterministic programs like MicroShield® provide a range of results for each type of packaging. Stochastic programs like "Monte-Carlo N-Particle Transport Code System" (MCNP®) on the other hand provide reliable results for complex geometries. However this type of program requires a fully trained operator and calculations are time consuming. The problem here is to choose an appropriate program for a specific geometry. Therefore we compared the results of deterministic programs like MicroShield® and stochastic programs like MCNP®. These comparisons enable us to make a statement about the applicability of the various programs for chosen types of containers. As a conclusion we found that for thin-walled geometries deterministic programs like MicroShield® are well suited to calculate the dose rate. For cylindrical containers with inner shielding however, deterministic programs hit their limits. Furthermore we investigate the effect of an inhomogeneous material and activity distribution on the results. The calculations are still ongoing. Results will be presented in the final abstract.

  14. Thermal Analysis of the Mound One Kilowatt Package

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Or, Chuen T.

    The Mound One Kilowatt (1 KW) package was designed for the shipment of plutonium (Pu-238) with not more than 1 kW total heat dissipation. To comply with regulations, the Mound 1 kW package has to pass all the requirements under Normal Conditions of Transport (NCT; 38 degrees C ambient temperature) and Hypothetical Accident Conditions (HAC; package engulfed in fire for 30 minutes). Analytical and test results were presented in the Safety Analysis Report for Packaging (SARP) for the Mound 1 kW package, revision 1, April 1991. Some issues remained unresolved in that revision. In March 1992, Fairchild Space and Defensemore » Corporation was commissioned by the Department of Energy to perform the thermal analyses. 3-D thermal models were created to perform the NCT and HAC analyses. Four shipping configurations in the SARP revision 3 were analyzed. They were: (1) The GPHS graphite impact shell (GIS) in the threaded product can (1000 W total heat generation); (2) The fueled clads in the welded product can (1000 W total heat generation); (3) The General Purpose Heat Source (GPHS) module (750 W total heat generation); and (4) The Multi-Hundred Watt (MHW) spheres (810 W total heat generation). Results from the four cases show that the GIS or fuel clad in the product can is the worse case. The temperatures predicted under NCT and HAC in all four cases are within the design limits. The use of helium instead of argon as cover gas provides a bigger safety margin. There is a duplicate copy.« less

  15. Investigation of Expandable Polymeric Microspheres for Packaging Applications

    DTIC Science & Technology

    2012-06-06

    FILMS COST REDUCTION OLEFIN POLYMERS COSTS PACKAGING MICROSPHERES WASTE DISPOSAL WEIGHT...MANAGEMENT THERMAL INSULATION DENSITY SOLID WASTES ENVIRONMENTAL IMPACT THERMOPLASTIC POLYMERS POLYMERS ...research. The purpose was to provide information on the incorporation of hollow, expandable  polymeric microspheres  into  thermoplastic   polymers   to

  16. Secondary Waste Cementitious Waste Form Data Package for the Integrated Disposal Facility Performance Assessment

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Cantrell, Kirk J.; Westsik, Joseph H.; Serne, R Jeffrey

    A review of the most up-to-date and relevant data currently available was conducted to develop a set of recommended values for use in the Integrated Disposal Facility (IDF) performance assessment (PA) to model contaminant release from a cementitious waste form for aqueous wastes treated at the Hanford Effluent Treatment Facility (ETF). This data package relies primarily upon recent data collected on Cast Stone formulations fabricated with simulants of low-activity waste (LAW) and liquid secondary wastes expected to be produced at Hanford. These data were supplemented, when necessary, with data developed for saltstone (a similar grout waste form used at themore » Savannah River Site). Work is currently underway to collect data on cementitious waste forms that are similar to Cast Stone and saltstone but are tailored to the characteristics of ETF-treated liquid secondary wastes. Recommended values for key parameters to conduct PA modeling of contaminant release from ETF-treated liquid waste are provided.« less

  17. Nanotechnology for the Solid Waste Reduction of Military Food Packaging

    DTIC Science & Technology

    2016-06-01

    WP-200816) Nanotechnology for the Solid Waste Reduction of Military Food Packaging June 2016 This document has been cleared for public release...NAME OF RESPONSIBLE PERSON 19b. TELEPHONE NUMBER (Include area code) 01/06/2016 Cost and Performance Report 04/01/2008 - 01/01/2015 Nanotechnology for... nanotechnology packaging. The PIs have been dedicated to these efforts, and it is anticipated that this technology will be used someday by the Warfighter

  18. Thermal Analysis of a Nuclear Waste Repository in Argillite Host Rock

    NASA Astrophysics Data System (ADS)

    Hadgu, T.; Gomez, S. P.; Matteo, E. N.

    2017-12-01

    Disposal of high-level nuclear waste in a geological repository requires analysis of heat distribution as a result of decay heat. Such an analysis supports design of repository layout to define repository footprint as well as provide information of importance to overall design. The analysis is also used in the study of potential migration of radionuclides to the accessible environment. In this study, thermal analysis for high-level waste and spent nuclear fuel in a generic repository in argillite host rock is presented. The thermal analysis utilized both semi-analytical and numerical modeling in the near field of a repository. The semi-analytical method looks at heat transport by conduction in the repository and surroundings. The results of the simulation method are temperature histories at selected radial distances from the waste package. A 3-D thermal-hydrologic numerical model was also conducted to study fluid and heat distribution in the near field. The thermal analysis assumed a generic geological repository at 500 m depth. For the semi-analytical method, a backfilled closed repository was assumed with basic design and material properties. For the thermal-hydrologic numerical method, a repository layout with disposal in horizontal boreholes was assumed. The 3-D modeling domain covers a limited portion of the repository footprint to enable a detailed thermal analysis. A highly refined unstructured mesh was used with increased discretization near heat sources and at intersections of different materials. All simulations considered different parameter values for properties of components of the engineered barrier system (i.e. buffer, disturbed rock zone and the host rock), and different surface storage times. Results of the different modeling cases are presented and include temperature and fluid flow profiles in the near field at different simulation times. Sandia National Laboratories is a multimission laboratory managed and operated by National Technology and

  19. Reliability of High I/O High Density CCGA Interconnect Electronic Packages under Extreme Thermal Environment

    NASA Technical Reports Server (NTRS)

    Ramesham, Rajeshuni

    2012-01-01

    This paper provides the experimental test results of advanced CCGA packages tested in extreme temperature thermal environments. Standard optical inspection and x-ray non-destructive inspection tools were used to assess the reliability of high density CCGA packages for deep space extreme temperature missions. Ceramic column grid array (CCGA) packages have been increasing in use based on their advantages such as high interconnect density, very good thermal and electrical performances, compatibility with standard surface-mount packaging assembly processes, and so on. CCGA packages are used in space applications such as in logic and microprocessor functions, telecommunications, payload electronics, and flight avionics. As these packages tend to have less solder joint strain relief than leaded packages or more strain relief over lead-less chip carrier packages, the reliability of CCGA packages is very important for short-term and long-term deep space missions. We have employed high density CCGA 1152 and 1272 daisy chained electronic packages in this preliminary reliability study. Each package is divided into several daisy-chained sections. The physical dimensions of CCGA1152 package is 35 mm x 35 mm with a 34 x 34 array of columns with a 1 mm pitch. The dimension of the CCGA1272 package is 37.5 mm x 37.5 mm with a 36 x 36 array with a 1 mm pitch. The columns are made up of 80% Pb/20%Sn material. CCGA interconnect electronic package printed wiring polyimide boards have been assembled and inspected using non-destructive x-ray imaging techniques. The assembled CCGA boards were subjected to extreme temperature thermal atmospheric cycling to assess their reliability for future deep space missions. The resistance of daisy-chained interconnect sections were monitored continuously during thermal cycling. This paper provides the experimental test results of advanced CCGA packages tested in extreme temperature thermal environments. Standard optical inspection and x-ray non

  20. Cleanup Verification Package for the 300 VTS Waste Site

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    S. W. Clark and T. H. Mitchell

    2006-03-13

    This cleanup verification package documents completion of remedial action for the 300 Area Vitrification Test Site, also known as the 300 VTS site. The site was used by Pacific Northwest National Laboratory as a field demonstration site for in situ vitrification of soils containing simulated waste.

  1. Reliability of high I/O high density CCGA interconnect electronic packages under extreme thermal environments

    NASA Astrophysics Data System (ADS)

    Ramesham, Rajeshuni

    2012-03-01

    Ceramic column grid array (CCGA) packages have been increasing in use based on their advantages such as high interconnect density, very good thermal and electrical performances, compatibility with standard surfacemount packaging assembly processes, and so on. CCGA packages are used in space applications such as in logic and microprocessor functions, telecommunications, payload electronics, and flight avionics. As these packages tend to have less solder joint strain relief than leaded packages or more strain relief over lead-less chip carrier packages, the reliability of CCGA packages is very important for short-term and long-term deep space missions. We have employed high density CCGA 1152 and 1272 daisy chained electronic packages in this preliminary reliability study. Each package is divided into several daisy-chained sections. The physical dimensions of CCGA1152 package is 35 mm x 35 mm with a 34 x 34 array of columns with a 1 mm pitch. The dimension of the CCGA1272 package is 37.5 mm x 37.5 mm with a 36 x 36 array with a 1 mm pitch. The columns are made up of 80% Pb/20%Sn material. CCGA interconnect electronic package printed wiring polyimide boards have been assembled and inspected using non-destructive x-ray imaging techniques. The assembled CCGA boards were subjected to extreme temperature thermal atmospheric cycling to assess their reliability for future deep space missions. The resistance of daisy-chained interconnect sections were monitored continuously during thermal cycling. This paper provides the experimental test results of advanced CCGA packages tested in extreme temperature thermal environments. Standard optical inspection and x-ray non-destructive inspection tools were used to assess the reliability of high density CCGA packages for deep space extreme temperature missions.

  2. IN-PACKAGE CHEMISTRY ABSTRACTION

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    E. Thomas

    2005-07-14

    This report was developed in accordance with the requirements in ''Technical Work Plan for Postclosure Waste Form Modeling'' (BSC 2005 [DIRS 173246]). The purpose of the in-package chemistry model is to predict the bulk chemistry inside of a breached waste package and to provide simplified expressions of that chemistry as a function of time after breach to Total Systems Performance Assessment for the License Application (TSPA-LA). The scope of this report is to describe the development and validation of the in-package chemistry model. The in-package model is a combination of two models, a batch reactor model, which uses the EQ3/6more » geochemistry-modeling tool, and a surface complexation model, which is applied to the results of the batch reactor model. The batch reactor model considers chemical interactions of water with the waste package materials, and the waste form for commercial spent nuclear fuel (CSNF) waste packages and codisposed (CDSP) waste packages containing high-level waste glass (HLWG) and DOE spent fuel. The surface complexation model includes the impact of fluid-surface interactions (i.e., surface complexation) on the resulting fluid composition. The model examines two types of water influx: (1) the condensation of water vapor diffusing into the waste package, and (2) seepage water entering the waste package as a liquid from the drift. (1) Vapor-Influx Case: The condensation of vapor onto the waste package internals is simulated as pure H{sub 2}O and enters at a rate determined by the water vapor pressure for representative temperature and relative humidity conditions. (2) Liquid-Influx Case: The water entering a waste package from the drift is simulated as typical groundwater and enters at a rate determined by the amount of seepage available to flow through openings in a breached waste package.« less

  3. Seal welded cast iron nuclear waste container

    DOEpatents

    Filippi, Arthur M.; Sprecace, Richard P.

    1987-01-01

    This invention identifies methods and articles designed to circumvent metallurgical problems associated with hermetically closing an all cast iron nuclear waste package by welding. It involves welding nickel-carbon alloy inserts which are bonded to the mating plug and main body components of the package. The welding inserts might be bonded in place during casting of the package components. When the waste package closure weld is made, the most severe thermal effects of the process are restricted to the nickel-carbon insert material which is far better able to accommodate them than is cast iron. Use of nickel-carbon weld inserts should eliminate any need for pre-weld and post-weld heat treatments which are a problem to apply to nuclear waste packages. Although the waste package closure weld approach described results in a dissimilar metal combination, the relative surface area of nickel-to-iron, their electrochemical relationship, and the presence of graphite in both materials will act to prevent any galvanic corrosion problem.

  4. Disposal of LLW and ILW in Germany - Characterisation and Documentation of Waste Packages with Respect to the Change of Requirements

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Bandt, G.; Spicher, G.; Steyer, St.

    2008-07-01

    Since the 1998 termination of LLW and ILW emplacement in the Morsleben repository (ERAM), Germany, the treatment, conditioning and documentation of radioactive waste products and packages have been continued on the basis of the waste acceptance requirements as of 1995, prepared for the Konrad repository near Salzgitter in Lower Saxony, Germany. The resulting waste products and packages are stored in interim storage facilities. Due to the Konrad license issued in 2002 the waste acceptance requirements have to be completed by additional requirements imposed by the licensing authority, e. g. for the declaration of chemical waste package constituents. Therefore, documentation ofmore » waste products and packages which are checked by independent experts and are in parts approved by the responsible authority (Office for Radiation Protection, BfS) up to now will have to be checked again for fulfilling the final waste acceptance requirements prior to disposal. In order to simplify these additional checks, databases are used to ensure an easy access to all known facts about the waste packages. A short balance of the existing waste products and packages which are already checked and partly approved by BfS as well as an overview on the established databases ensuring a fast access to the known facts about the conditioning processes is presented. (authors)« less

  5. Prompt gamma neutron activation analysis of toxic elements in radioactive waste packages.

    PubMed

    Ma, J-L; Carasco, C; Perot, B; Mauerhofer, E; Kettler, J; Havenith, A

    2012-07-01

    The French Alternative Energies and Atomic Energy Commission (CEA) and National Radioactive Waste Management Agency (ANDRA) are conducting an R&D program to improve the characterization of long-lived and medium activity (LL-MA) radioactive waste packages. In particular, the amount of toxic elements present in radioactive waste packages must be assessed before they can be accepted in repository facilities in order to avoid pollution of underground water reserves. To this aim, the Nuclear Measurement Laboratory of CEA-Cadarache has started to study the performances of Prompt Gamma Neutron Activation Analysis (PGNAA) for elements showing large capture cross sections such as mercury, cadmium, boron, and chromium. This paper reports a comparison between Monte Carlo calculations performed with the MCNPX computer code using the ENDF/B-VII.0 library and experimental gamma rays measured in the REGAIN PGNAA cell with small samples of nickel, lead, cadmium, arsenic, antimony, chromium, magnesium, zinc, boron, and lithium to verify the validity of a numerical model and gamma-ray production data. The measurement of a ∼20kg test sample of concrete containing toxic elements has also been performed, in collaboration with Forschungszentrum Jülich, to validate the model in view of future performance studies for dense and large LL-MA waste packages. Copyright © 2012 Elsevier Ltd. All rights reserved.

  6. Thermal investigation of nuclear waste disposal in space

    NASA Technical Reports Server (NTRS)

    Wilkinson, C. L.

    1981-01-01

    A thermal analysis has been conducted to determine the allowable size and response of bare and shielded nuclear waste forms in both low earth orbit and at 0.85 astronomical units. Contingency conditions of re-entry with a 45 deg and 60 deg aeroshell are examined as well as re-entry of a spherical shielded waste form. A variety of shielded schemes were examined and the waste form thermal response for each determined. Two optimum configurations were selected. The thermal response of these two shielded waste configurations to indefinite exposure to ground conditions following controlled and uncontrolled re-entry is determined. In all cases the prime criterion is that waste containment must be maintained.

  7. 21 CFR 500.23 - Thermally processed low-acid foods packaged in hermetically sealed containers.

    Code of Federal Regulations, 2010 CFR

    2010-04-01

    ... 21 Food and Drugs 6 2010-04-01 2010-04-01 false Thermally processed low-acid foods packaged in hermetically sealed containers. 500.23 Section 500.23 Food and Drugs FOOD AND DRUG ADMINISTRATION, DEPARTMENT... Administrative Rulings and Decisions § 500.23 Thermally processed low-acid foods packaged in hermetically sealed...

  8. 21 CFR 500.23 - Thermally processed low-acid foods packaged in hermetically sealed containers.

    Code of Federal Regulations, 2011 CFR

    2011-04-01

    ... 21 Food and Drugs 6 2011-04-01 2011-04-01 false Thermally processed low-acid foods packaged in hermetically sealed containers. 500.23 Section 500.23 Food and Drugs FOOD AND DRUG ADMINISTRATION, DEPARTMENT... Administrative Rulings and Decisions § 500.23 Thermally processed low-acid foods packaged in hermetically sealed...

  9. 21 CFR 500.23 - Thermally processed low-acid foods packaged in hermetically sealed containers.

    Code of Federal Regulations, 2012 CFR

    2012-04-01

    ... 21 Food and Drugs 6 2012-04-01 2012-04-01 false Thermally processed low-acid foods packaged in hermetically sealed containers. 500.23 Section 500.23 Food and Drugs FOOD AND DRUG ADMINISTRATION, DEPARTMENT... Administrative Rulings and Decisions § 500.23 Thermally processed low-acid foods packaged in hermetically sealed...

  10. 21 CFR 500.23 - Thermally processed low-acid foods packaged in hermetically sealed containers.

    Code of Federal Regulations, 2013 CFR

    2013-04-01

    ... 21 Food and Drugs 6 2013-04-01 2013-04-01 false Thermally processed low-acid foods packaged in hermetically sealed containers. 500.23 Section 500.23 Food and Drugs FOOD AND DRUG ADMINISTRATION, DEPARTMENT... Administrative Rulings and Decisions § 500.23 Thermally processed low-acid foods packaged in hermetically sealed...

  11. 21 CFR 500.23 - Thermally processed low-acid foods packaged in hermetically sealed containers.

    Code of Federal Regulations, 2014 CFR

    2014-04-01

    ... 21 Food and Drugs 6 2014-04-01 2014-04-01 false Thermally processed low-acid foods packaged in hermetically sealed containers. 500.23 Section 500.23 Food and Drugs FOOD AND DRUG ADMINISTRATION, DEPARTMENT... Administrative Rulings and Decisions § 500.23 Thermally processed low-acid foods packaged in hermetically sealed...

  12. Chemical compatibility screening results of plastic packaging to mixed waste simulants

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Nigrey, P.J.; Dickens, T.G.

    1995-12-01

    We have developed a chemical compatibility program for evaluating transportation packaging components for transporting mixed waste forms. We have performed the first phase of this experimental program to determine the effects of simulant mixed wastes on packaging materials. This effort involved the screening of 10 plastic materials in four liquid mixed waste simulants. The testing protocol involved exposing the respective materials to {approximately}3 kGy of gamma radiation followed by 14 day exposures to the waste simulants of 60 C. The seal materials or rubbers were tested using VTR (vapor transport rate) measurements while the liner materials were tested using specificmore » gravity as a metric. For these tests, a screening criteria of {approximately}1 g/m{sup 2}/hr for VTR and a specific gravity change of 10% was used. It was concluded that while all seal materials passed exposure to the aqueous simulant mixed waste, EPDM and SBR had the lowest VTRs. In the chlorinated hydrocarbon simulant mixed waste, only VITON passed the screening tests. In both the simulant scintillation fluid mixed waste and the ketone mixture simulant mixed waste, none of the seal materials met the screening criteria. It is anticipated that those materials with the lowest VTRs will be evaluated in the comprehensive phase of the program. For specific gravity testing of liner materials the data showed that while all materials with the exception of polypropylene passed the screening criteria, Kel-F, HDPE, and XLPE were found to offer the greatest resistance to the combination of radiation and chemicals.« less

  13. Life testing of reflowed and reworked advanced CCGA surface mount packages in harsh thermal environments

    NASA Astrophysics Data System (ADS)

    Ramesham, Rajeshuni

    2013-03-01

    Life testing/qualification of reflowed (1st reflow) and reworked (1st reflow, 1st removal, and then 1st rework) advanced ceramic column grid array (CCGA) surface mount interconnect electronic packaging technologies for future flight projects has been studied to enhance the mission assurance of JPL-NASA projects. The reliability of reworked/reflowed surface mount technology (SMT) packages is very important for short-duration and long-duration deep space harsh extreme thermal environmental missions. The life testing of CCGA electronic packages under extreme thermal environments (for example: -185°C to +125°C) has been performed with reference to various JPL/NASA project requirements which encompass the temperature range studied. The test boards of reflowed and reworked CCGA packages (717 Xilinx package, 624, 1152, and 1272 column Actel Packages) were selected for the study to survive three times the total number of expected temperature cycles resulting from all environmental and operational exposures occurring over the life of the flight hardware including all relevant manufacturing, ground operations, and mission phases or cycles to failure to assess the life of the hardware. Qualification/life testing was performed by subjecting test boards to the environmental harsh temperature extremes and assessing any structural failures, mechanical failures or degradation in electrical performance solder-joint failures due to either overstress or thermal cycle fatigue. The large, high density, high input/output (I/O) electronic interconnect SMT packages such as CCGA have increased usage in avionics hardware of NASA projects during the last two decades. The test boards built with CCGA packages are expensive and often require a rework to replace a reflowed, reprogrammed, failed, redesigned, etc., CCGA packages. Theoretically speaking, a good rework process should have similar temperature-time profile as that used for the original manufacturing process of solder reflow. A

  14. Data Packages for the Hanford Immobilized Low Activity Tank Waste Performance Assessment 2001 Version [SEC 1 THRU 5

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    MANN, F.M.

    Data package supporting the 2001 Immobilized Low-Activity Waste Performance Analysis. Geology, hydrology, geochemistry, facility, waste form, and dosimetry data based on recent investigation are provided. Verification and benchmarking packages for selected software codes are provided.

  15. Cleanup Verification Package for the 118-C-1, 105-C Solid Waste Burial Ground

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    M. J. Appel and J. M. Capron

    2007-07-25

    This cleanup verification package documents completion of remedial action for the 118-C-1, 105-C Solid Waste Burial Ground. This waste site was the primary burial ground for general wastes from the operation of the 105-C Reactor and received process tubes, aluminum fuel spacers, control rods, reactor hardware, spent nuclear fuel and soft wastes.

  16. Nuclear Waste Package Mockups: A Study of In-situ Redox State

    NASA Astrophysics Data System (ADS)

    Helean, K.; Anderson, B.; Brady, P. V.

    2006-05-01

    The Yucca Mountain Repository (YMR), located in southern Nevada, is to be the first facility in the U.S. for the permanent disposal of high-level radioactive waste and spent nuclear fuels. Total system performance assessment(TSPA) has indicated that among the major radionuclides contributing to dose are Np, Tc, and I. These three radionuclides are mobile in most geochemical settings, and therefore sequestering them within the repository horizon is a priority for the Yucca Mountain Project (YMP). Corroding steel may offset radionuclide transport processes within the proposed waste packages at YMR by retaining radionuclides, creating locally reducing conditions, and reducing porosity. Ferrous iron has been shown to reduce UO22+ to UO2s, and some ferrous iron-bearing ion-exchange materials have been shown to adsorb radionuclides and heavy metals. Locally reducing conditions may lead to the reduction and subsequent immobilization of problematic dissolved species such as TcO4-, NpO2+, and UO22+ and can also inhibit corrosion of spent nuclear fuel. Water occluded during corrosion produces bulky corrosion products, and consequently less porosity is available for water and radionuclide transport. The focus of this study is on the nature of Yucca Mountain waste package corrosion products and their effects on local redox conditions, radionuclide transport, and porosity. In order to measure in-situ redox, six small-scale (1:40) waste package mockups were constructed using A516 and 316 stainless steel, the same materials as the proposed Yucca Mountain waste packages. The mockups are periodically injected with a simulated groundwater and the accumulated effluent and corrosion products are evaluated for their Fe(II)/Fe(III) content and mineralogy. Oxygen fugacities are then calculated and, thus, in-situ redox conditions are determined. Early results indicate that corrosion products are largely amorphous Fe-oxyhydroxides, goethite and magnetite. That information together with the

  17. In-Package Chemistry Abstraction

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    E. Thomas

    2004-11-09

    This report was developed in accordance with the requirements in ''Technical Work Plan for: Regulatory Integration Modeling and Analysis of the Waste Form and Waste Package'' (BSC 2004 [DIRS 171583]). The purpose of the in-package chemistry model is to predict the bulk chemistry inside of a breached waste package and to provide simplified expressions of that chemistry as function of time after breach to Total Systems Performance Assessment for the License Application (TSPA-LA). The scope of this report is to describe the development and validation of the in-package chemistry model. The in-package model is a combination of two models, amore » batch reactor model that uses the EQ3/6 geochemistry-modeling tool, and a surface complexation model that is applied to the results of the batch reactor model. The batch reactor model considers chemical interactions of water with the waste package materials and the waste form for commercial spent nuclear fuel (CSNF) waste packages and codisposed waste packages that contain both high-level waste glass (HLWG) and DOE spent fuel. The surface complexation model includes the impact of fluid-surface interactions (i.e., surface complexation) on the resulting fluid composition. The model examines two types of water influx: (1) the condensation of water vapor that diffuses into the waste package, and (2) seepage water that enters the waste package from the drift as a liquid. (1) Vapor Influx Case: The condensation of vapor onto the waste package internals is simulated as pure H2O and enters at a rate determined by the water vapor pressure for representative temperature and relative humidity conditions. (2) Water Influx Case: The water entering a waste package from the drift is simulated as typical groundwater and enters at a rate determined by the amount of seepage available to flow through openings in a breached waste package. TSPA-LA uses the vapor influx case for the nominal scenario for simulations where the waste package has been

  18. Packaging strategies for printed circuit board components. Volume I, materials & thermal stresses.

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Neilsen, Michael K.; Austin, Kevin N.; Adolf, Douglas Brian

    2011-09-01

    Decisions on material selections for electronics packaging can be quite complicated by the need to balance the criteria to withstand severe impacts yet survive deep thermal cycles intact. Many times, material choices are based on historical precedence perhaps ignorant of whether those initial choices were carefully investigated or whether the requirements on the new component match those of previous units. The goal of this program focuses on developing both increased intuition for generic packaging guidelines and computational methodologies for optimizing packaging in specific components. Initial efforts centered on characterization of classes of materials common to packaging strategies and computational analysesmore » of stresses generated during thermal cycling to identify strengths and weaknesses of various material choices. Future studies will analyze the same example problems incorporating the effects of curing stresses as needed and analyzing dynamic loadings to compare trends with the quasi-static conclusions.« less

  19. Review of waste package verification tests. Semiannual report, October 1982-March 1983

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Soo, P.

    1983-08-01

    The current study is part of an ongoing task to specify tests that may be used to verify that engineered waste package/repository systems comply with NRC radionuclide containment and controlled release performance objectives. Work covered in this report analyzes verification tests for borosilicate glass waste forms and bentonite- and zeolite-based packing mateials (discrete backfills). 76 references.

  20. Cleanup Verification Package for the 600-47 Waste Site

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    M. J. Cutlip

    This cleanup verification package documents completion of interim remedial action for the 600-47 waste site. This site consisted of several areas of surface debris and contamination near the banks of the Columbia River across from Johnson Island. Contaminated material identified in field surveys included four areas of soil, wood, nuts, bolts, and other metal debris.

  1. Characterization of the solid low level mixed waste inventory for the solid waste thermal treatment activity - III

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Place, B.G., Westinghouse Hanford

    1996-09-24

    The existing thermally treatable, radioactive mixed waste inventory is characterized to support implementation of the commercial, 1214 thermal treatment contract. The existing thermally treatable waste inventory has been identified using a decision matrix developed by Josephson et al. (1996). Similar to earlier waste characterization reports (Place 1993 and 1994), hazardous materials, radionuclides, physical properties, and waste container data are statistically analyzed. In addition, the waste inventory data is analyzed to correlate waste constituent data that are important to the implementation of the commercial thermal treatment contract for obtaining permits and for process design. The specific waste parameters, which were analyzed,more » include the following: ``dose equivalent`` curie content, polychlorinated biphenyl (PCB) content, identification of containers with PA-related mobile radionuclides (14C, 12 79Se, 99Tc, and U isotopes), tritium content, debris and non-debris content, container free liquid content, fissile isotope content, identification of dangerous waste codes, asbestos containers, high mercury containers, beryllium dust containers, lead containers, overall waste quantities, analysis of container types, and an estimate of the waste compositional split based on the thermal treatment contractor`s proposed process. A qualitative description of the thermally treatable mixed waste inventory is also provided.« less

  2. Thermal properties of simulated Hanford waste glasses

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Rodriguez, Carmen P.; Chun, Jaehun; Crum, Jarrod V.

    The Hanford Tank Waste Treatment and Immobilization Plant (WTP) will vitrify the mixed hazardous wastes generated from 45 years of plutonium production. The molten glasses will be poured into stainless steel containers or canisters and subsequently quenched for storage and disposal. Such highly energy-consuming processes require precise thermal properties of materials for appropriate facility design and operations. Key thermal properties (heat capacity, thermal diffusivity, and thermal conductivity) of representative high-level and low-activity waste glasses were studied as functions of temperature in the range of 200 to 800°C (relevant to the cooling process), implementing simultaneous differential scanning calorimetry-thermal gravimetry (DSC-TGA), Xe-flashmore » diffusivity, pycnometry, and dilatometry. The study showed that simultaneous DSC-TGA would be a reliable method to obtain heat capacity of various glasses at the temperature of interest. Accurate thermal properties from this study were shown to provide a more realistic guideline for capacity and time constraint of heat removal process, in comparison to the design basis conservative engineering estimates. The estimates, though useful for design in the absence measured physical properties, can now be supplanted and the measured thermal properties can be used in design verification activities.« less

  3. Validation of thermal effects of LED package by using Elmer finite element simulation method

    NASA Astrophysics Data System (ADS)

    Leng, Lai Siang; Retnasamy, Vithyacharan; Mohamad Shahimin, Mukhzeer; Sauli, Zaliman; Taniselass, Steven; Bin Ab Aziz, Muhamad Hafiz; Vairavan, Rajendaran; Kirtsaeng, Supap

    2017-02-01

    The overall performance of the Light-emitting diode, LED package is critically affected by the heat attribution. In this study, open source software - Elmer FEM has been utilized to study the thermal analysis of the LED package. In order to perform a complete simulation study, both Salome software and ParaView software were introduced as Pre and Postprocessor. The thermal effect of the LED package was evaluated by this software. The result has been validated with commercially licensed software based on previous work. The percentage difference from both simulation results is less than 5% which is tolerable and comparable.

  4. Preliminary Study of Radioactive Waste Package Made of High-Strength and Ultra Low-Permeability Concrete for Geological Disposal of TRU Wastes

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Matsuo, T.; Kawasaki, T.; Sakamoto, H.

    2003-02-27

    We have been developing a radioactive waste package made of high-strength and ultra low-permeability concrete (HSULPC) for geological disposal of TRU wastes, which is expected to be much more impervious to water than conventional concrete. In this study, basic data for the HSULPC regarding its the impervious character and the thermodynamics during cement hydration were obtained through water permeability measurements using cold isostatic pressing (CIP) and adiabatic concrete hydration experiments, respectively. Then, a prediction tool to find concrete package construction conditions to avoid thermal cracking was developed, which could deal with coupled calculations of cement hydration, heat transfer, stress, andmore » cracking. The developed tool was applied to HSULPC hydration on a small-scale cylindrical model to examine whether there was any effect on cracking which depended on the ratio of concrete cylinder thickness to its inner diameter. The results were compared to experiments. For concrete with a compressive strength of 200MPa, the water permeability coefficient was 4 x 10{sup 19} m/s. Dependences of activation energy and frequency factor on degree of cement hydration had a sharp peaking due to the nucleation rate-determining step, and a gradual increase region due to the diffusion rate-determining step. From analyses of the small-scale cylindrical model, dependences of the maximum principal stress on the radius were obtained. When the ratio of the concrete thickness to the heater diameter was around 1, the risk of cracking was predicted to be minimized. These numerical predictions from the developed tool were verified by experiments.« less

  5. Changes in electrical and thermal parameters of led packages under different current and heating stresses

    NASA Astrophysics Data System (ADS)

    Jayawardena, Adikaramge Asiri

    The goal of this dissertation is to identify electrical and thermal parameters of an LED package that can be used to predict catastrophic failure real-time in an application. Through an experimental study the series electrical resistance and thermal resistance were identified as good indicators of contact failure of LED packages. This study investigated the long-term changes in series electrical resistance and thermal resistance of LED packages at three different current and junction temperature stress conditions. Experiment results showed that the series electrical resistance went through four phases of change; including periods of latency, rapid increase, saturation, and finally a sharp decline just before failure. Formation of voids in the contact metallization was identified as the underlying mechanism for series resistance increase. The rate of series resistance change was linked to void growth using the theory of electromigration. The rate of increase of series resistance is dependent on temperature and current density. The results indicate that void growth occurred in the cap (Au) layer, was constrained by the contact metal (Ni) layer, preventing open circuit failure of contact metal layer. Short circuit failure occurred due to electromigration induced metal diffusion along dislocations in GaN. The increase in ideality factor, and reverse leakage current with time provided further evidence to presence of metal in the semiconductor. An empirical model was derived for estimation of LED package failure time due to metal diffusion. The model is based on the experimental results and theories of electromigration and diffusion. Furthermore, the experimental results showed that the thermal resistance of LED packages increased with aging time. A relationship between thermal resistance change rate, with case temperature and temperature gradient within the LED package was developed. The results showed that dislocation creep is responsible for creep induced plastic

  6. Use of advanced modeling techniques to optimize thermal packaging designs.

    PubMed

    Formato, Richard M; Potami, Raffaele; Ahmed, Iftekhar

    2010-01-01

    Through a detailed case study the authors demonstrate, for the first time, the capability of using advanced modeling techniques to correctly simulate the transient temperature response of a convective flow-based thermal shipper design. The objective of this case study was to demonstrate that simulation could be utilized to design a 2-inch-wall polyurethane (PUR) shipper to hold its product box temperature between 2 and 8 °C over the prescribed 96-h summer profile (product box is the portion of the shipper that is occupied by the payload). Results obtained from numerical simulation are in excellent agreement with empirical chamber data (within ±1 °C at all times), and geometrical locations of simulation maximum and minimum temperature match well with the corresponding chamber temperature measurements. Furthermore, a control simulation test case was run (results taken from identical product box locations) to compare the coupled conduction-convection model with a conduction-only model, which to date has been the state-of-the-art method. For the conduction-only simulation, all fluid elements were replaced with "solid" elements of identical size and assigned thermal properties of air. While results from the coupled thermal/fluid model closely correlated with the empirical data (±1 °C), the conduction-only model was unable to correctly capture the payload temperature trends, showing a sizeable error compared to empirical values (ΔT > 6 °C). A modeling technique capable of correctly capturing the thermal behavior of passively refrigerated shippers can be used to quickly evaluate and optimize new packaging designs. Such a capability provides a means to reduce the cost and required design time of shippers while simultaneously improving their performance. Another advantage comes from using thermal modeling (assuming a validated model is available) to predict the temperature distribution in a shipper that is exposed to ambient temperatures which were not bracketed

  7. Thermal plasma technology for the treatment of wastes: a critical review.

    PubMed

    Gomez, E; Rani, D Amutha; Cheeseman, C R; Deegan, D; Wise, M; Boccaccini, A R

    2009-01-30

    This review describes the current status of waste treatment using thermal plasma technology. A comprehensive analysis of the available scientific and technical literature on waste plasma treatment is presented, including the treatment of a variety of hazardous wastes, such as residues from municipal solid waste incineration, slag and dust from steel production, asbestos-containing wastes, health care wastes and organic liquid wastes. The principles of thermal plasma generation and the technologies available are outlined, together with potential applications for plasma vitrified products. There have been continued advances in the application of plasma technology for waste treatment, and this is now a viable alternative to other potential treatment/disposal options. Regulatory, economic and socio-political drivers are promoting adoption of advanced thermal conversion techniques such as thermal plasma technology and these are expected to become increasingly commercially viable in the future.

  8. Establishing a store baseline during interim storage of waste packages and a review of potential technologies for base-lining

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    McTeer, Jennifer; Morris, Jenny; Wickham, Stephen

    Interim storage is an essential component of the waste management lifecycle, providing a safe, secure environment for waste packages awaiting final disposal. In order to be able to monitor and detect change or degradation of the waste packages, storage building or equipment, it is necessary to know the original condition of these components (the 'waste storage system'). This paper presents an approach to establishing the baseline for a waste-storage system, and provides guidance on the selection and implementation of potential base-lining technologies. The approach is made up of two sections; assessment of base-lining needs and definition of base-lining approach. Duringmore » the assessment of base-lining needs a review of available monitoring data and store/package records should be undertaken (if the store is operational). Evolutionary processes (affecting safety functions), and their corresponding indicators, that can be measured to provide a baseline for the waste-storage system should then be identified in order for the most suitable indicators to be selected for base-lining. In defining the approach, identification of opportunities to collect data and constraints is undertaken before selecting the techniques for base-lining and developing a base-lining plan. Base-lining data may be used to establish that the state of the packages is consistent with the waste acceptance criteria for the storage facility and to support the interpretation of monitoring and inspection data collected during store operations. Opportunities and constraints are identified for different store and package types. Technologies that could potentially be used to measure baseline indicators are also reviewed. (authors)« less

  9. Greater-than-Class C low-level radioactive waste shipping package/container identification and requirements study. National Low-Level Waste Management Program

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Tyacke, M.

    1993-08-01

    This report identifies a variety of shipping packages (also referred to as casks) and waste containers currently available or being developed that could be used for greater-than-Class C (GTCC) low-level waste (LLW). Since GTCC LLW varies greatly in size, shape, and activity levels, the casks and waste containers that could be used range in size from small, to accommodate a single sealed radiation source, to very large-capacity casks/canisters used to transport or dry-store highly radioactive spent fuel. In some cases, the waste containers may serve directly as shipping packages, while in other cases, the containers would need to be placedmore » in a transport cask. For the purpose of this report, it is assumed that the generator is responsible for transporting the waste to a Department of Energy (DOE) storage, treatment, or disposal facility. Unless DOE establishes specific acceptance criteria, the receiving facility would need the capability to accept any of the casks and waste containers identified in this report. In identifying potential casks and waste containers, no consideration was given to their adequacy relative to handling, storage, treatment, and disposal. Those considerations must be addressed separately as the capabilities of the receiving facility and the handling requirements and operations are better understood.« less

  10. Operating Experience and Lessons Learned in the Use of Soft-Sided Packaging for Transportation and Disposal of Low Activity Radioactive Waste

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Kapoor, A.; Gordon, S.; Goldston, W.

    2013-07-08

    This paper describes the operating experience and lessons learned at U.S. Department of Energy (DOE) sites as a result of an evaluation of potential trailer contamination and soft-sided packaging integrity issues related to the disposal of low-level and mixed low-level (LLW/MLLW) radioactive waste shipments. Nearly 4.3 million cubic meters of LLW/MLLW will have been generated and disposed of during fiscal year (FY) 2010 to FY 2015—either at commercial disposal sites or disposal sites owned by DOE. The LLW/MLLW is packaged in several different types of regulatory compliant packaging and transported via highway or rail to disposal sites safely and efficientlymore » in accordance with federal, state, and local regulations and DOE orders. In 1999, DOE supported the development of LLW containers that are more volumetrically efficient, more cost effective, and easier to use as compared to metal or wooden containers that existed at that time. The DOE Idaho National Engineering and Environmental Laboratory (INEEL), working in conjunction with the plastic industry, tested several types of soft-sided waste packaging systems that meet U.S. Department of Transportation requirements for transport of low specific activity and surface contaminated objects. Since then, soft-sided packaging of various capacities have been used successfully by the decontamination and decommissioning (D&D) projects to package, transport, and dispose D&D wastes throughout the DOE complex. The joint team of experts assembled by the Energy Facility Contractors Group from DOE waste generating sites, DOE and commercial waste disposal facilities, and soft-sided packaging suppliers conducted the review of soft-sided packaging operations and transportation of these packages to the disposal sites. As a result of this evaluation, the team developed several recommendations and best practices to prevent or minimize the recurrences of equipment contamination issues and proper use of soft-sided packaging for

  11. Onset of thermally induced gas convection in mine wastes

    USGS Publications Warehouse

    Lu, N.; Zhang, Y.

    1997-01-01

    A mine waste dump in which active oxidation of pyritic materials occurs can generate a large amount of heat to form convection cells. We analyze the onset of thermal convection in a two-dimensional, infinite horizontal layer of waste rock filled with moist gas, with the top surface of the waste dump open to the atmosphere and the bedrock beneath the waste dump forming a horizontal and impermeable boundary. Our analysis shows that the thermal regime of a waste rock system depends heavily on the atmospheric temperature, the strength of the heat source and the vapor pressure. ?? 1997 Elsevier Science Ltd. All rights reserved.

  12. Practical Thermal Evaluation Methods For HAC Fire Analysis In Type B Radiaoactive Material (RAM) Packages

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Abramczyk, Glenn; Hensel, Stephen J; Gupta, Narendra K.

    Title 10 of the United States Code of Federal Regulations Part 71 for the Nuclear Regulatory Commission (10 CFR Part 71.73) requires that Type B radioactive material (RAM) packages satisfy certain Hypothetical Accident Conditions (HAC) thermal design requirements to ensure package safety during accidental fire conditions. Compliance with thermal design requirements can be met by prototype tests, analyses only or a combination of tests and analyses. Normally, it is impractical to meet all the HAC using tests only and the analytical methods are too complex due to the multi-physics non-linear nature of the fire event. Therefore, a combination of testsmore » and thermal analyses methods using commercial heat transfer software are used to meet the necessary design requirements. The authors, along with his other colleagues at Savannah River National Laboratory in Aiken, SC, USA, have successfully used this 'tests and analyses' approach in the design and certification of several United States' DOE/NNSA certified packages, e.g. 9975, 9977, 9978, 9979, H1700, and Bulk Tritium Shipping Package (BTSP). This paper will describe these methods and it is hoped that the RAM Type B package designers and analysts can use them for their applications.« less

  13. Packaging material and flexible medical tubing containing thermally exfoliated graphite oxide

    NASA Technical Reports Server (NTRS)

    Prud'homme, Robert K. (Inventor); Aksay, Ilhan A. (Inventor)

    2011-01-01

    A packaging material or flexible medical tubing containing a modified graphite oxide material, which is a thermally exfoliated graphite oxide with a surface area of from about 300 m.sup.2/g to 2600 m.sup.2/g.

  14. 77 FR 23751 - Certain Food Waste Disposers and Components and Packaging Thereof; Institution of Investigation...

    Federal Register 2010, 2011, 2012, 2013, 2014

    2012-04-20

    ... INTERNATIONAL TRADE COMMISSION [Inv. No. 337-TA-838] Certain Food Waste Disposers and Components... States after importation of certain food waste disposers and components and packaging thereof by reason... an industry in the United States exists as required by subsections (a)(1)(A) and (a)(2) of section...

  15. An econometric analysis of regional differences in household waste collection: the case of plastic packaging waste in Sweden.

    PubMed

    Hage, Olle; Söderholm, Patrik

    2008-01-01

    The Swedish producer responsibility ordinance mandates producers to collect and recycle packaging materials. This paper investigates the main determinants of collection rates of household plastic packaging waste in Swedish municipalities. This is done by the use of a regression analysis based on cross-sectional data for 252 Swedish municipalities. The results suggest that local policies, geographic/demographic variables, socio-economic factors and environmental preferences all help explain inter-municipality collection rates. For instance, the collection rate appears to be positively affected by increases in the unemployment rate, the share of private houses, and the presence of immigrants (unless newly arrived) in the municipality. The impacts of distance to recycling industry, urbanization rate and population density on collection outcomes turn out, though, to be both statistically and economically insignificant. A reasonable explanation for this is that the monetary compensation from the material companies to the collection entrepreneurs vary depending on region and is typically higher in high-cost regions. This implies that the plastic packaging collection in Sweden may be cost ineffective. Finally, the analysis also shows that municipalities that employ weight-based waste management fees generally experience higher collection rates than those municipalities in which flat and/or volume-based fees are used.

  16. An econometric analysis of regional differences in household waste collection: The case of plastic packaging waste in Sweden

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Hage, Olle; Soederholm, Patrik

    2008-07-01

    The Swedish producer responsibility ordinance mandates producers to collect and recycle packaging materials. This paper investigates the main determinants of collection rates of household plastic packaging waste in Swedish municipalities. This is done by the use of a regression analysis based on cross-sectional data for 252 Swedish municipalities. The results suggest that local policies, geographic/demographic variables, socio-economic factors and environmental preferences all help explain inter-municipality collection rates. For instance, the collection rate appears to be positively affected by increases in the unemployment rate, the share of private houses, and the presence of immigrants (unless newly arrived) in the municipality. Themore » impacts of distance to recycling industry, urbanization rate and population density on collection outcomes turn out, though, to be both statistically and economically insignificant. A reasonable explanation for this is that the monetary compensation from the material companies to the collection entrepreneurs vary depending on region and is typically higher in high-cost regions. This implies that the plastic packaging collection in Sweden may be cost ineffective. Finally, the analysis also shows that municipalities that employ weight-based waste management fees generally experience higher collection rates than those municipalities in which flat and/or volume-based fees are used.« less

  17. Thermal Neutron Die-Way-Time Studies for P and DGNAA of Radioactive Waste Drums at the MEDINA Facility

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Mildenberger, Frank; Mauerhofer, Eric

    2015-07-01

    In Germany, radioactive waste with negligible heat production has to pass through a process of quality checking in order to check its conformance with national regulations prior to its transport, intermediate storage and final disposal. Additionally to its radioactive components, the waste may contain non-radioactive chemically toxic substances that can adversely affect human health and pollute the environment, especially the ground water. After an adequate decay time, the waste radioactivity will become harmless but the non-radioactive substances will persist over time. In principle, these hazardous substances may be quantified from traceability and quality controls performed during the production of themore » waste packages. As a consequence, a research and development program was initiated in 2007 with the aim to develop a nondestructive analytical technique for radioactive waste packages based on prompt and delayed gamma neutron activation analysis (P and DGNAA) employing a DT-neutron generator in pulsed mode. In a preliminary study it was experimentally demonstrated that P and DGNAA is suitable to determine the chemical composition of large samples. In 2010 a facility called MEDINA (Multi Element Detection based on Instrumental Neutron Activation) was developed for the qualitative and quantitative determination of nonradioactive, toxic elements and substances in 200-l steel drums. The determination of hazardous substances and elements is generally achieved measuring the prompt gamma-rays induced by thermal neutrons. Additional information about the composition of the waste matrix could be derived measuring the delayed gamma-rays from short life activation products. However a sensitive detection of these delayed gamma-rays requires that thermal neutrons have almost vanished. Therefore, the thermal neutron die-away-time has to be known in order to achieve an optimal discrimination between prompt and delayed gamma-ray spectra acquisition. Measurements Thermal

  18. A case study of packaging waste collection systems in Portugal - Part II: Environmental and economic analysis.

    PubMed

    Pires, Ana; Sargedas, João; Miguel, Mécia; Pina, Joaquim; Martinho, Graça

    2017-03-01

    An understanding of the environmental impacts and costs related to waste collection is needed to ensure that existing waste collection schemes are the most appropriate with regard to both environment and cost. This paper is Part II of a three-part study of a mixed packaging waste collection system (curbside plus bring collection). Here, the mixed collection system is compared to an exclusive curbside system and an exclusive bring system. The scenarios were assessed using life cycle assessment and an assessment of costs to the waste management company. The analysis focuses on the collection itself so as to be relevant to waste managers and decision-makers who are involved only in this step of the packaging life cycle. The results show that the bring system has lower environmental impacts and lower economic costs, and is capable of reducing the environmental impacts of the mixed system. However, a sensitivity analysis shows that these results could differ if the curbside collection were to be optimized. From economic and environmental perspectives, the mixed system has few advantages. Copyright © 2016 Elsevier Ltd. All rights reserved.

  19. Investigating the Thermal Limit of Clay Minerals for Applications in Nuclear Waste Repository Design

    NASA Astrophysics Data System (ADS)

    Matteo, E. N.; Miller, A. W.; Kruichak, J.; Mills, M.; Tellez, H.; Wang, Y.

    2013-12-01

    Clay minerals are likely candidates to aid in nuclear waste isolation due to their low permeability, favorable swelling properties, and high cation sorption capacities. Establishing the thermal limit for clay minerals in a nuclear waste repository is a potentially important component of repository design, as flexibility of the heat load within the repository can have a major impact on the selection of repository design. For example, the thermal limit plays a critical role in the time that waste packages would need to cool before being transferred to the repository. Understanding the chemical and physical changes that occur in clay minerals at various temperatures above the current thermal limit (of 100 °C) can enable decision-makers with information critical to evaluating the potential trade-offs of increasing the thermal limit within the repository. Most critical is gaining understanding of how varying thermal conditions in the repository will impact radionuclide sorption and transport in clay materials either as engineered barriers or as disposal media. A variety of clays (illite, mixed layer illite/smectite, montmorillonite, and palygorskite) were heated for a range of temperatures between 100-500 °C. These samples were characterized by a variety of methods, including nitrogen adsorption, x-ray diffraction, thermogravimetric analysis, barium chloride exchange for cation exchange capacity (CEC), and iodide sorption. The nitrogen porosimetry shows that for all the clays, thermally-induced changes in BET surface area are dominated by collapse/creation of the microporosity, i.e. pore diameters < 17 angstroms. Changes in micro porosity (relative to no heat treatment) are most significant for heat treatments 300 °C and above. Alterations are also seen in the chemical properties (CEC, XRD, iodide sorption) of clays, and like pore size distribution changes, are most significant above 300 °C. Overall, the results imply that changes seen in pores size distribution

  20. Generic repository design concepts and thermal analysis (FY11).

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Howard, Robert; Dupont, Mark; Blink, James A.

    2011-08-01

    Reference concepts for geologic disposal of used nuclear fuel and high-level radioactive waste in the U.S. are developed, including geologic settings and engineered barriers. Repository thermal analysis is demonstrated for a range of waste types from projected future, advanced nuclear fuel cycles. The results show significant differences among geologic media considered (clay/shale, crystalline rock, salt), and also that waste package size and waste loading must be limited to meet targeted maximum temperature values. In this study, the UFD R&D Campaign has developed a set of reference geologic disposal concepts for a range of waste types that could potentially be generatedmore » in advanced nuclear FCs. A disposal concept consists of three components: waste inventory, geologic setting, and concept of operations. Mature repository concepts have been developed in other countries for disposal of spent LWR fuel and HLW from reprocessing UNF, and these serve as starting points for developing this set. Additional design details and EBS concepts will be considered as the reference disposal concepts evolve. The waste inventory considered in this study includes: (1) direct disposal of SNF from the LWR fleet, including Gen III+ advanced LWRs being developed through the Nuclear Power 2010 Program, operating in a once-through cycle; (2) waste generated from reprocessing of LWR UOX UNF to recover U and Pu, and subsequent direct disposal of used Pu-MOX fuel (also used in LWRs) in a modified-open cycle; and (3) waste generated by continuous recycling of metal fuel from fast reactors operating in a TRU burner configuration, with additional TRU material input supplied from reprocessing of LWR UOX fuel. The geologic setting provides the natural barriers, and establishes the boundary conditions for performance of engineered barriers. The composition and physical properties of the host medium dictate design and construction approaches, and determine hydrologic and thermal responses

  1. 40 CFR 262.30 - Packaging.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 40 Protection of Environment 25 2010-07-01 2010-07-01 false Packaging. 262.30 Section 262.30... APPLICABLE TO GENERATORS OF HAZARDOUS WASTE Pre-Transport Requirements § 262.30 Packaging. Before... the waste in accordance with the applicable Department of Transportation regulations on packaging...

  2. Thermal Testing and Quality Assurance of BGA LCC & QFN Electronic Packages

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Kuper, Cameron Mathias

    The purpose of this project is to experimentally validate the thermal fatigue life of solder interconnects for a variety of surface mount electronic packages. Over the years, there has been a significant amount of research and analysis in the fracture of solder joints on printed circuit boards. Solder is important in the mechanical and electronic functionality of the component. It is important throughout the life of the product that the solder remains crack and fracture free. The specific type of solder used in this experiment is a 63Sn37Pb eutectic alloy. Each package was surrounded conformal coating or underfill material.

  3. Hydrogen recovery from the thermal plasma gasification of solid waste.

    PubMed

    Byun, Youngchul; Cho, Moohyun; Chung, Jae Woo; Namkung, Won; Lee, Hyeon Don; Jang, Sung Duk; Kim, Young-Suk; Lee, Jin-Ho; Lee, Carg-Ro; Hwang, Soon-Mo

    2011-06-15

    Thermal plasma gasification has been demonstrated as one of the most effective and environmentally friendly methods for solid waste treatment and energy utilization in many of studies. Therefore, the thermal plasma process of solid waste gasification (paper mill waste, 1.2 ton/day) was applied for the recovery of high purity H(2) (>99.99%). Gases emitted from a gasification furnace equipped with a nontransferred thermal plasma torch were purified using a bag-filter and wet scrubber. Thereafter, the gases, which contained syngas (CO+H(2)), were introduced into a H(2) recovery system, consisting largely of a water gas shift (WGS) unit for the conversion of CO to H(2) and a pressure swing adsorption (PSA) unit for the separation and purification of H(2). It was successfully demonstrated that the thermal plasma process of solid waste gasification, combined with the WGS and PSA, produced high purity H(2) (20 N m(3)/h (400 H(2)-Nm(3)/PMW-ton), up to 99.99%) using a plasma torch with 1.6 MWh/PMW-ton of electricity. The results presented here suggest that the thermal plasma process of solid waste gasification for the production of high purity H(2) may provide a new approach as a future energy infrastructure based on H(2). Copyright © 2011 Elsevier B.V. All rights reserved.

  4. Temperature-package power correlations for open-mode geologic disposal concepts.

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Hardin, Ernest.

    2013-02-01

    Logistical simulation of spent nuclear fuel (SNF) management in the U.S. combines storage, transportation and disposal elements to evaluate schedule, cost and other resources needed for all major operations leading to final geologic disposal. Geologic repository reference options are associated with limits on waste package thermal power output at emplacement, in order to meet limits on peak temperature for certain key engineered and natural barriers. These package power limits are used in logistical simulation software such as CALVIN, as threshold requirements that must be met by means of decay storage or SNF blending in waste packages, before emplacement in amore » repository. Geologic repository reference options include enclosed modes developed for crystalline rock, clay or shale, and salt. In addition, a further need has been addressed for open modes in which SNF can be emplaced in a repository, then ventilated for decades or longer to remove heat, prior to permanent repository closure. For each open mode disposal concept there are specified durations for surface decay storage (prior to emplacement), repository ventilation, and repository closure operations. This study simulates those steps for several timing cases, and for SNF with three fuel-burnup characteristics, to develop package power limits at which waste packages can be emplaced without exceeding specified temperature limits many years later after permanent closure. The results are presented in the form of correlations that span a range of package power and peak postclosure temperature, for each open-mode disposal concept, and for each timing case. Given a particular temperature limit value, the corresponding package power limit for each case can be selected for use in CALVIN and similar tools.« less

  5. FABRICATION AND DEPLOYMENT OF THE 9979 TYPE AF RADIOACTIVE WASTE PACKAGING FOR THE DEPARTMENT OF ENERGY

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Blanton, P.; Eberl, K.

    2013-10-10

    This paper summarizes the development, testing, and certification of the 9979 Type A Fissile Packaging that replaces the UN1A2 Specification Shipping Package eliminated from Department of Transportation (DOT) 49 CFR 173. The DOT Specification Package was used for many decades by the U.S. nuclear industry as a fissile waste container until its removal as an authorized container by DOT. This paper will discuss stream lining procurement of high volume radioactive material packaging manufacturing, such as the 9979, to minimize packaging production costs without sacrificing Quality Assurance. The authorized content envelope (combustible and non-combustible) as well as planned content envelope expansionmore » will be discussed.« less

  6. 77 FR 17093 - Certain Food Waste Disposers and Components and Packaging Thereof: Notice of Receipt of Complaint...

    Federal Register 2010, 2011, 2012, 2013, 2014

    2012-03-23

    ... INTERNATIONAL TRADE COMMISSION [DN 2886] Certain Food Waste Disposers and Components and Packaging...: U.S. International Trade Commission. ACTION: Notice. SUMMARY: Notice is hereby given that the U.S. International Trade Commission has received a complaint entitled Certain Food Waste Disposers and Components and...

  7. An investigation of the usability of sound recognition for source separation of packaging wastes in reverse vending machines.

    PubMed

    Korucu, M Kemal; Kaplan, Özgür; Büyük, Osman; Güllü, M Kemal

    2016-10-01

    In this study, we investigate the usability of sound recognition for source separation of packaging wastes in reverse vending machines (RVMs). For this purpose, an experimental setup equipped with a sound recording mechanism was prepared. Packaging waste sounds generated by three physical impacts such as free falling, pneumatic hitting and hydraulic crushing were separately recorded using two different microphones. To classify the waste types and sizes based on sound features of the wastes, a support vector machine (SVM) and a hidden Markov model (HMM) based sound classification systems were developed. In the basic experimental setup in which only free falling impact type was considered, SVM and HMM systems provided 100% classification accuracy for both microphones. In the expanded experimental setup which includes all three impact types, material type classification accuracies were 96.5% for dynamic microphone and 97.7% for condenser microphone. When both the material type and the size of the wastes were classified, the accuracy was 88.6% for the microphones. The modeling studies indicated that hydraulic crushing impact type recordings were very noisy for an effective sound recognition application. In the detailed analysis of the recognition errors, it was observed that most of the errors occurred in the hitting impact type. According to the experimental results, it can be said that the proposed novel approach for the separation of packaging wastes could provide a high classification performance for RVMs. Copyright © 2016 Elsevier Ltd. All rights reserved.

  8. Circular economy of plastic packaging: Current practice and perspectives in Austria.

    PubMed

    Van Eygen, Emile; Laner, David; Fellner, Johann

    2018-02-01

    Plastics, especially from packaging, have gained increasing attention in waste management, driving many policy initiatives to improve the circularity of these materials in the economy to increase resource efficiency. In this context, the EU has proposed increasing targets to encourage the recycling of (plastic) packaging. To accurately calculate the recycling rates, detailed information on the flows of plastic packaging is needed. Therefore, the aim of this paper is to quantitatively and qualitatively investigate the waste management system for plastic packaging in Austria in 2013 using material flow analysis, taking into account the used product types and the polymer composition. The results show that 300,000 ± 3% t/a (35 kg/cap·a) of waste plastic packaging were produced, mainly composed of large and small films and small hollow bodies, including PET bottles. Correspondingly, the polymer composition of the waste stream was dominated by LDPE (46% ± 6%), PET (19% ± 4%) and PP (14% ± 6%). 58% ± 3% was collected separately, and regarding the final treatment, 26% ± 7% of the total waste stream was recovered as re-granulates, whereas the rest was thermally recovered in waste-to-energy plants (40% ± 3%) and the cement industry (33% ± 6%). The targets set by the EU and Austria were reached comfortably, although to reach the proposed future target major technological steps regarding collection and sorting will be needed. However, the current calculation point of the targets, i.e. on the input side of the recycling plant, is not deemed to be fully in line with the overall objective of the circular economy, namely to keep materials in the economy and prevent losses. It is therefore recommended that the targets be calculated with respect to the actual output of the recycling process, provided that the quality of the output products is maintained, to accurately assess the performance of the waste management system. Copyright © 2017

  9. Post-consumer plastic packaging waste in England: Assessing the yield of multiple collection-recycling schemes.

    PubMed

    Hahladakis, John N; Purnell, Phil; Iacovidou, Eleni; Velis, Costas A; Atseyinku, Maryann

    2018-05-01

    The European Commission (EC) recently introduced a 'Circular Economy Package', setting ambitious recycling targets and identifying waste plastics as a priority sector where major improvements are necessary. Here, the authors explain how different collection modalities affect the quantity and quality of recycling, using recent empirical data on household (HH) post-consumer plastic packaging waste (PCPP) collected for recycling in the devolved administration of England over the quarterly period July-September 2014. Three main collection schemes, as currently implemented in England, were taken into account: (i) kerbside collection (KS), (ii) household waste recycling centres (HWRCs) (also known as 'civic amenity sites'), and (iii) bring sites/banks (BSs). The results indicated that: (a) the contribution of KS collection scheme in recovering packaging plastics is higher than HWRCs and BBs, with respective percentages by weight (wt%) 90%, 9% and 1%; (b) alternate weekly collection (AWC) of plastic recyclables in wheeled bins, when collected commingled, demonstrated higher yield in KS collection; (c) only a small percentage (16%) of the total amount of post-consumer plastics collected in the examined period (141 kt) was finally sent to reprocessors (22 kt); (c) nearly a third of Local Authorities (LAs) reported insufficient or poor data; and (d) the most abundant fractions of plastics that finally reached the reprocessors were mixed plastic bottles and mixed plastics. Crown Copyright © 2018. Published by Elsevier Ltd. All rights reserved.

  10. Non-Thermal Treatment of Hanford Site Low-Level Mixed Waste

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    NONE

    1998-09-01

    DOE proposes to transport contact-handled LLMW from the Hanford Site to the Allied Technology Group (ATG) Mixed Waste Facility (MWF) in Richland, Washington, for non-thermal treatment and to return the treated waste to the Hanford Site for eventual land disposal. Over a 3-year period the waste would be staged to the ATG MWF, and treated waste would be returned to the Hanford Site. The ATG MWF would be located on an 18 hectare (ha) (45 acre [at]) ATG Site adjacent to ATG's licensed low-level waste processing facility at 2025 Battelle Boulevard. The ATG MWF is located approximately 0.8 kilometers (km)more » (0.5 miles [mi]) south of Horn Rapids Road and 1.6 km (1 mi) west of Stevens Drive. The property is located within the Horn Rapids triangle in northern Richland (Figure 2.1). The ATG MWF is to be located on the existing ATG Site, near the DOE Hanford Site, in an industrial area in the City of Richland. The effects of siting, construction, and overall operation of the MWF have been evaluated in a separate State Environmental Policy Act (SEPA) EIS (City of Richland 1998). The proposed action includes transporting the LLMW from the Hanford Site to the ATG Facility, non-thermal treatment of the LLMW at the ATG MWF, and transporting the waste from ATG back to the Hanford Site. Impacts fi-om waste treatment operations would be bounded by the ATG SEPA EIS, which included an evaluation of the impacts associated with operating the non-thermal portion of the MWF at maximum design capacity (8,500 metric tons per year) (City of Richland 1998). Up to 50 employees would be required for non-thermal treatment portion of the MWF. This includes 40 employees that would perform waste treatment operations and 10 support staff. Similar numbers were projected for the thermal treatment portion of the MWF (City of Richland 1998).« less

  11. Utilizing Radioisotope Power System Waste Heat for Spacecraft Thermal Management

    NASA Technical Reports Server (NTRS)

    Pantano, David R.; Dottore, Frank; Tobery, E. Wayne; Geng, Steven M.; Schreiber, Jeffrey G.; Palko, Joseph L.

    2005-01-01

    An advantage of using a Radioisotope Power System (RPS) for deep space or planetary surface missions is the readily available waste heat, which can be used for a number of beneficial purposes including: maintaining electronic components within a controlled temperature range, warming propulsion tanks and mobility actuators, and maintaining liquid propellants above their freezing temperature. Previous missions using Radioisotope Thermoelectric Generators (RTGs) dissipated large quantities of waste heat due to the low efficiency of the thermoelectric conversion technology. The next generation RPSs, such as the 110-Watt Stirling Radioisotope Generator (SRG110) will have higher conversion efficiencies, thereby rejecting less waste heat at a lower temperature and may require alternate approaches to transferring waste heat to the spacecraft. RTGs, with efficiencies of 6 to 7 percent, reject their waste heat at the relatively high heat rejection temperature of 200 C. This is an advantage when rejecting heat to space; however, transferring heat to the internal spacecraft components requires a large and heavy radiator heat exchanger. At the same time, sensitive spacecraft instruments must be shielded from the thermal radiation of the RTG. The SRG110, with an efficiency around 22 percent and 50 C nominal housing surface temperature, can readily transfer the available waste heat directly via heat pipes, thermal straps, or fluid loops. The lower temperatures associated with the SRG110 avoid the chances of overheating other scientific components, eliminating the need for thermal shields. This provides the spacecraft designers more flexibility when locating the generator for a specific mission. A common misconception with high-efficiency systems is that there is not enough waste heat for spacecraft thermal management. This paper will dispel this misconception and investigate the use of a high-efficiency SRG110 for spacecraft thermal management and outline potential methods of

  12. Edible packaging materials.

    PubMed

    Janjarasskul, Theeranun; Krochta, John M

    2010-01-01

    Research groups and the food and pharmaceutical industries recognize edible packaging as a useful alternative or addition to conventional packaging to reduce waste and to create novel applications for improving product stability, quality, safety, variety, and convenience for consumers. Recent studies have explored the ability of biopolymer-based food packaging materials to carry and control-release active compounds. As diverse edible packaging materials derived from various by-products or waste from food industry are being developed, the dry thermoplastic process is advancing rapidly as a feasible commercial edible packaging manufacturing process. The employment of nanocomposite concepts to edible packaging materials promises to improve barrier and mechanical properties and facilitate effective incorporation of bioactive ingredients and other designed functions. In addition to the need for a more fundamental understanding to enable design to desired specifications, edible packaging has to overcome challenges such as regulatory requirements, consumer acceptance, and scaling-up research concepts to commercial applications.

  13. THERMUS—A thermal model package for ROOT

    NASA Astrophysics Data System (ADS)

    Wheaton, S.; Cleymans, J.; Hauer, M.

    2009-01-01

    THERMUS is a package of C++ classes and functions allowing statistical-thermal model analyses of particle production in relativistic heavy-ion collisions to be performed within the ROOT framework of analysis. Calculations are possible within three statistical ensembles; a grand-canonical treatment of the conserved charges B, S and Q, a fully canonical treatment of the conserved charges, and a mixed-canonical ensemble combining a canonical treatment of strangeness with a grand-canonical treatment of baryon number and electric charge. THERMUS allows for the assignment of decay chains and detector efficiencies specific to each particle yield, which enables sensible fitting of model parameters to experimental data. Program summaryProgram title: THERMUS, version 2.1 Catalogue identifier: AEBW_v1_0 Program summary URL:http://cpc.cs.qub.ac.uk/summaries/AEBW_v1_0.html Program obtainable from: CPC Program Library, Queen's University, Belfast, N. Ireland Licensing provisions: Standard CPC licence, http://cpc.cs.qub.ac.uk/licence/licence.html No. of lines in distributed program, including test data, etc.: 17 152 No. of bytes in distributed program, including test data, etc.: 93 581 Distribution format: tar.gz Programming language: C++ Computer: PC, Pentium 4, 1 GB RAM (not hardware dependent) Operating system: Linux: FEDORA, RedHat, etc. Classification: 17.7 External routines: Numerical Recipes in C [1], ROOT [2] Nature of problem: Statistical-thermal model analyses of heavy-ion collision data require the calculation of both primordial particle densities and contributions from resonance decay. A set of thermal parameters (the number depending on the particular model imposed) and a set of thermalized particles, with their decays specified, is required as input to these models. The output is then a complete set of primordial thermal quantities for each particle, together with the contributions to the final particle yields from resonance decay. In many applications of

  14. Report to Congress on the potential use of lead in the waste packages for a geologic repository at Yucca Mountain, Nevada

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    NONE

    1989-12-01

    In the Report of the Senate Committee on Appropriations accompanying the Energy and Water Appropriation Act for 1989, the Committee directed the Department of Energy (DOE) to evaluate the use of lead in the waste packages to be used in geologic repositories for spent nuclear fuel and high-level waste. The evaluation that was performed in response to this directive is presented in this report. This evaluation was based largely on a review of the technical literature on the behavior of lead, reports of work conducted in other countries, and work performed for the waste-management program being conducted by the DOE.more » The initial evaluation was limited to the potential use of lead in the packages to be used in the repository. Also, the focus of this report is post closure performance and not on retrievability and handling aspects of the waste package. 100 refs., 8 figs., 15 tabs.« less

  15. Optimizing and developing a continuous separation system for the wet process separation of aluminum and polyethylene in aseptic composite packaging waste.

    PubMed

    Yan, Dahai; Peng, Zheng; Liu, Yuqiang; Li, Li; Huang, Qifei; Xie, Minghui; Wang, Qi

    2015-01-01

    The consumption of milk in China is increasing as living standards rapidly improve, and huge amounts of aseptic composite milk packaging waste are being generated. Aseptic composite packaging is composed of paper, polyethylene, and aluminum. It is difficult to separate the polyethylene and aluminum, so most of the waste is currently sent to landfill or incinerated with other municipal solid waste, meaning that enormous amounts of resources are wasted. A wet process technique for separating the aluminum and polyethylene from the composite materials after the paper had been removed from the original packaging waste was studied. The separation efficiency achieved using different separation reagents was compared, different separation mechanisms were explored, and the impacts of a range of parameters, such as the reagent concentration, temperature, and liquid-solid ratio, on the separation time and aluminum loss ratio were studied. Methanoic acid was found to be the optimal separation reagent, and the suitable conditions were a reagent concentration of 2-4 mol/L, a temperature of 60-80°C, and a liquid-solid ratio of 30 L/kg. These conditions allowed aluminum and polyethylene to be separated in less than 30 min, with an aluminum loss ratio of less than 3%. A mass balance was produced for the aluminum-polyethylene separation system, and control technique was developed to keep the ion concentrations in the reaction system stable. This allowed a continuous industrial-scale process for separating aluminum and polyethylene to be developed, and a demonstration facility with a capacity of 50t/d was built. The demonstration facility gave polyethylene and aluminum recovery rates of more than 98% and more than 72%, respectively. Separating 1t of aluminum-polyethylene composite packaging material gave a profit of 1769 Yuan, meaning that an effective method for recycling aseptic composite packaging waste was achieved. Copyright © 2014 Elsevier Ltd. All rights reserved.

  16. Corrosion of Metal Inclusions In Bulk Vitrification Waste Packages. Erratum

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Smith, Gary L.

    This report refers to or contains K g values for glasses LAWA44, LAWB45 and LAWC22 affected by calculations errors as identified by Papathanassiu et al. (2011). The corrected K g values are reported in an erratum included in the revised version of the original report. The revised report can be referenced as follows: Pierce E. M. et al. (2004) Waste Form Release Data Package for the 2005 Integrated Disposal Facility Performance Assessment. PNNL-14805 Rev. 0 Erratum. Pacific Northwest National Laboratory, Richland, WA, USA.

  17. Thermal energy storage for industrial waste heat recovery

    NASA Technical Reports Server (NTRS)

    Hoffman, H. W.; Kedl, R. J.; Duscha, R. A.

    1978-01-01

    Thermal energy storage systems designed for energy conservation through the recovery, storage, and reuse of industrial process waste heat are reviewed. Consideration is given to systems developed for primary aluminum, cement, the food processing industry, paper and pulp, and primary iron and steel. Projected waste-heat recovery and energy savings are listed for each category.

  18. 40 CFR 265.383 - Interim status thermal treatment devices burning particular hazardous waste.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... devices burning particular hazardous waste. 265.383 Section 265.383 Protection of Environment... status thermal treatment devices burning particular hazardous waste. (a) Owners or operators of thermal treatment devices subject to this subpart may burn EPA Hazardous Wastes FO20, FO21, FO22, FO23, FO26, or...

  19. 40 CFR 265.383 - Interim status thermal treatment devices burning particular hazardous waste.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... devices burning particular hazardous waste. 265.383 Section 265.383 Protection of Environment... status thermal treatment devices burning particular hazardous waste. (a) Owners or operators of thermal treatment devices subject to this subpart may burn EPA Hazardous Wastes FO20, FO21, FO22, FO23, FO26, or...

  20. 40 CFR 265.383 - Interim status thermal treatment devices burning particular hazardous waste.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... devices burning particular hazardous waste. 265.383 Section 265.383 Protection of Environment... status thermal treatment devices burning particular hazardous waste. (a) Owners or operators of thermal treatment devices subject to this subpart may burn EPA Hazardous Wastes FO20, FO21, FO22, FO23, FO26, or...

  1. 40 CFR 265.383 - Interim status thermal treatment devices burning particular hazardous waste.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... devices burning particular hazardous waste. 265.383 Section 265.383 Protection of Environment... status thermal treatment devices burning particular hazardous waste. (a) Owners or operators of thermal treatment devices subject to this subpart may burn EPA Hazardous Wastes FO20, FO21, FO22, FO23, FO26, or...

  2. 40 CFR 265.383 - Interim status thermal treatment devices burning particular hazardous waste.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... devices burning particular hazardous waste. 265.383 Section 265.383 Protection of Environment... status thermal treatment devices burning particular hazardous waste. (a) Owners or operators of thermal treatment devices subject to this subpart may burn EPA Hazardous Wastes FO20, FO21, FO22, FO23, FO26, or...

  3. Thermal Hysteresis of MEMS Packaged Capacitive Pressure Sensor (CPS) Based 3C-SiC

    NASA Astrophysics Data System (ADS)

    Marsi, N.; Majlis, B. Y.; Mohd-Yasin, F.; Hamzah, A. A.; Mohd Rus, A. Z.

    2016-11-01

    Presented herein are the effects of thermal hysteresis analyses of the MEMS packaged capacitive pressure sensor (CPS). The MEMS CPS was employed on Si-on-3C-SiC wafer that was performed using the hot wall low-pressure chemical vapour deposition (LPCVD) reactors at the Queensland Micro and Nanotechnology Center (QMNC), Griffith University and fabricated using the bulk-micromachining process. The MEMS CPS was operated at an extreme temperature up to 500°C and high external pressure at 5.0 MPa. The thermal hysteresis phenomenon that causes the deflection, strain and stress on the 3C-SiC diaphragm spontaneously influence the MEMS CPS performances. The differences of temperature, hysteresis, and repeatability test were presented to demonstrate the functionality of the MEMS packaged CPS. As expected, the output hysteresis has a low hysteresis (less than 0.05%) which has the hardness greater than the traditional silicon. By utilizing this low hysteresis, it was revealed that the MEMS packaged CPS has high repeatability and stability of the sensor.

  4. Packaging waste prevention in the distribution of fruit and vegetables: An assessment based on the life cycle perspective.

    PubMed

    Tua, Camilla; Nessi, Simone; Rigamonti, Lucia; Dolci, Giovanni; Grosso, Mario

    2017-04-01

    In recent years, alternative food supply chains based on short distance production and delivery have been promoted as being more environmentally friendly than those applied by the traditional retailing system. An example is the supply of seasonal and possibly locally grown fruit and vegetables directly to customers inside a returnable crate (the so-called 'box scheme'). In addition to other claimed environmental and economic advantages, the box scheme is often listed among the packaging waste prevention measures. To check whether such a claim is soundly based, a life cycle assessment was carried out to verify the real environmental effectiveness of the box scheme in comparison to the Italian traditional distribution. The study focused on two reference products, carrots and apples, which are available in the crate all year round. An experience of a box scheme carried out in Italy was compared with some traditional scenarios where the product is distributed loose or packaged at the large-scale retail trade. The packaging waste generation, 13 impact indicators on environment and human health and energy consumptions were calculated. Results show that the analysed experience of the box scheme, as currently managed, cannot be considered a packaging waste prevention measure when compared with the traditional distribution of fruit and vegetables. The weaknesses of the alternative system were identified and some recommendations were given to improve its environmental performance.

  5. Teaching Old Packaging New Tricks - 12593

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    England, Jeffery L.; Shuler, James M.

    2012-07-01

    Waste disposition campaigns have been an industry and government focus area since the mid- 1970's. With increased focus on this issue, and a lot of hard work, most waste packaging and transportation issues have been addressed. The material has been successfully shipped and dis-positioned. DOE has successfully de-inventoried materials from multiple sites to meet material consolidation, footprint reduction, nonproliferation, and regulatory obligations with cost savings from reduced maintenance and regulatory compliance. There has been a wide range of certified shipping packagings for the transportation of hazardous materials to meet most of the waste needs. The remaining materials are problematic, generallymore » low volume, and do not meet the certified content of the existing inventory of packaging. Designing, testing and certifying new packaging designs can be a long and expensive process and for small volumes of material it is cost prohibitive. One very cost effective option is to lease and use a certified packaging to overpack waste containers. There are many robust certified packagings available with the capability to envelope the waste content. The capability to use inner containers, inside the current fleet of certified casks or packaging, to address specific content problems of additional shielding (e.g., U-233) or containment (e.g., sodium bonded nuclear material) has successfully expanded the capability for timely cost effective shipment of unique contents. This option has been used successfully in the NAC-LWT, T-3 and other packagings. (authors)« less

  6. Thermal properties of light-weight concrete with waste polypropylene aggregate

    NASA Astrophysics Data System (ADS)

    Záleská, Martina; Pokorný, Jaroslav; Pavlíková, Milena; Pavlík, Zbyšek

    2017-07-01

    Thermal properties of a sustainable light-weight concrete incorporating high volume of waste polypropylene as partial substitution of natural aggregate were studied in the paper. Glass fiber reinforced polypropylene (GFPP), a by-product of PP tubes production, partially substituted fine natural silica aggregate in 10, 20, 30, 40, and 50 mass%. In order to quantify the effect of GFPP use on concrete properties, a reference concrete mix without plastic waste was studied as well. For the applied GFPP, bulk density, matrix density, and particle size distribution were measured. Specific attention was paid to thermal transport and storage properties of GFPP that were examined in dependence on compaction time. For the developed light-weight concrete, thermal properties were accessed using transient impulse technique, whereas the measurement was done in dependence on moisture content, from the dry state to fully water saturated state. Additionally, the investigated thermal properties were plotted as function of porosity. The tested light-weight concrete was found to be prospective construction material possessing improved thermal insulation function. Moreover, the reuse of waste plastics in concrete composition was beneficial both from the environmental and financial point of view considering plastics low biodegradability and safe disposal.

  7. Study of Selected Composites Copper Concentrate-Plastic Waste Using Thermal Analysis

    NASA Astrophysics Data System (ADS)

    Szyszka, Danuta

    2017-12-01

    The paper presents thermal analysis of selected composites (copper concentrate, plastic waste) in two stages. The first stage consisted in thermogravimetric analysis and differential thermal analysis on the applied plastic waste and copper concentrate, and subsequently, a comparative study has been carried out on products obtained, constituting composites of those materials. As a result of analyses, it was found that up to ca. 400 °C composites show high thermal stability, whereas above that temperature, a thermal decomposition of the composite occurs, resulting in emissions of organic compounds, i.e. hydrocarbon compounds and organic oxygenate derivatives.

  8. Current status of circularity for aluminum from household waste in Austria.

    PubMed

    Warrings, R; Fellner, J

    2018-02-20

    Aluminum (Al) represents the metal with the highest consumption growth in the last few decades. Beside its increasing usage in the transport (lightweight construction of vehicles) and building sector, Al is used ever more frequently for household goods like packaging material, which represents a readily available source for secondary aluminum due to its short lifetime. The present paper investigates the extent to which this potential source for recycling of Al is already utilized in Austria and highlights areas for future improvements. Thereto a detailed material flow analysis for Al used in packaging & household non-packaging in 2013 was conducted. In practice, all Al flows starting from market entrance through waste collection and processing until its final recycling or disposal have been investigated. The results indicate that about 25,100 t/a (2.96 kg/cap/a) of Al packaging & household non-packaging arose as waste. At present about 9800 t/a, or 39%, are recycled as secondary Al, of which 26% is regained from separate collection and sorting, 8% from bottom ash and 5% from mechanical treatment. The type of Al packaging & household non-packaging affects the recycling rate: 82% of the total recycled quantities come from rigid packaging & household non-packaging, while only 3% of the total recycled Al derives from flexible materials. A significant amount of Al was lost during thermal waste treatment due to oxidation (10%) and insufficient recovery of Al from both waste incineration bottom ash and municipal solid waste treated in mechanical biological treatment plants (49%). Overall it can be concluded that once Al ends up in commingled waste the recovery of Al becomes less likely and its material quality is reduced. Although Austria can refer to a highly developed recycling system, the Austrian packaging industry, collection and recovery systems and waste management need to increase their efforts to comply with future recycling targets. Copyright © 2018

  9. Development of integrated radioactive waste packaging and conditioning solutions in the UK

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Sibley, Peter; Butter, Kevin; Zimmerman, Ian

    2013-07-01

    In order to offer a more cost effective, safer and efficient Intermediate Level Waste (ILW) management service, EnergySolutions EU Ltd. and Gesellschaft fur Nuklear-Service mbH (GNS) have been engaged in the development of integrated radioactive waste retrieval, packaging and conditioning solutions in the UK. Recognising the challenges surrounding regulatory endorsement and on-site implementation in particular, this has resulted in an alternative approach to meeting customer, safety regulator and disposability requirements. By working closely with waste producers and the organisation(s) responsible for endorsing radioactive waste management operations in the UK, our proposed solutions are now being implemented. By combining GNS' off-the-shelf,more » proven Ductile Cast Iron Containers (DCICs) and water removal technologies, with EnergySolutions EU Ltd.'s experience and expertise in waste retrieval, safety case development and disposability submissions, a fully integrated service offering has been developed. This has involved significant effort to overcome technical challenges such as onsite equipment deployment, active commissioning, conditioning success criteria and disposability acceptance. Our experience in developing such integrated solutions has highlighted the importance of working in collaboration with all parties to achieve a successful and viable outcome. Ultimately, the goal is to ensure reliable, safe and effective delivery of waste management solutions. (authors)« less

  10. A Feasibility Study on Reactor Based Fission Neutron Radiography of 200-l Waste Packages

    NASA Astrophysics Data System (ADS)

    Bücherl, T.; Kalthoff, O.; von Gostomski, Ch. Lierse

    This feasibility study investigates the applicability of fission neutrons for the non-destructive characterization of radioactive waste packages by means of neutron radiography. Based on a number of mock-up drums of different non-radioactive matrices, but being typical for radioactive waste generated in Europe, radiography measurements at the NECTAR and the ITS facility using fission neutrons and 60Co-gamma-rays, respectively, are performed. The resulting radiographs are compared and qualitatively assessed. In addition, a first approach for the stitching of the fission neutron radiographs to visualize the complete area of 200-l waste drums is performed. While the feasibility of fission neutrons is demonstrated successfully, fields for further improvements are identified.

  11. Review of DOE Waste Package Program. Semiannual report, October 1984-March 1985. Volume 8

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Davis, M.S.

    1985-12-01

    A large number of technical reports on waste package component performance were reviewed over the last year in support of the NRC`s review of the Department of Energy`s (DOE`s) Environmental Assessment reports. The intent was to assess in some detail the quantity and quality of the DOE data and their relevance to the high-level waste repository site selection process. A representative selection of the reviews is presented for the salt, basalt, and tuff repository projects. Areas for future research have been outlined. 141 refs.

  12. Pyrolysis of plastic packaging waste: A comparison of plastic residuals from material recovery facilities with simulated plastic waste.

    PubMed

    Adrados, A; de Marco, I; Caballero, B M; López, A; Laresgoiti, M F; Torres, A

    2012-05-01

    Pyrolysis may be an alternative for the reclamation of rejected streams of waste from sorting plants where packing and packaging plastic waste is separated and classified. These rejected streams consist of many different materials (e.g., polyethylene (PE), polypropylene (PP), polystyrene (PS), polyvinyl chloride (PVC), polyethylene terephthalate (PET), acrylonitrile butadiene styrene (ABS), aluminum, tetra-brik, and film) for which an attempt at complete separation is not technically possible or economically viable, and they are typically sent to landfills or incinerators. For this study, a simulated plastic mixture and a real waste sample from a sorting plant were pyrolyzed using a non-stirred semi-batch reactor. Red mud, a byproduct of the aluminum industry, was used as a catalyst. Despite the fact that the samples had a similar volume of material, there were noteworthy differences in the pyrolysis yields. The real waste sample resulted, after pyrolysis, in higher gas and solid yields and consequently produced less liquid. There were also significant differences noted in the compositions of the compared pyrolysis products. Copyright © 2011 Elsevier Ltd. All rights reserved.

  13. ATTIRE (analytical tools for thermal infrared engineering): A sensor simulation and modeling package

    NASA Astrophysics Data System (ADS)

    Jaggi, S.

    1993-02-01

    The Advanced Sensor Development Laboratory (ASDL) at the Stennis Space Center develops, maintains and calibrates remote sensing instruments for the National Aeronautics & Space Administration (NASA). To perform system design trade-offs, analysis, and establish system parameters, ASDL has developed a software package for analytical simulation of sensor systems. This package called 'Analytical Tools for Thermal InfraRed Engineering' - ATTIRE, simulates the various components of a sensor system. The software allows each subsystem of the sensor to be analyzed independently for its performance. These performance parameters are then integrated to obtain system level information such as Signal-to-Noise Ratio (SNR), Noise Equivalent Radiance (NER), Noise Equivalent Temperature Difference (NETD) etc. This paper describes the uses of the package and the physics that were used to derive the performance parameters.

  14. 78 FR 1881 - Certain Food Waste Disposers and Components and Packaging Thereof; Notice of the Commission's...

    Federal Register 2010, 2011, 2012, 2013, 2014

    2013-01-09

    ... INTERNATIONAL TRADE COMMISSION [Investigation No. 337-TA-838] Certain Food Waste Disposers and Components and Packaging Thereof; Notice of the Commission's Determination Not To Review Initial Determinations Granting Complainant's Motions To Partially Terminate the Investigation and To Withdraw the...

  15. Upgrading of recycled plastics obtained from flexible packaging waste by adding nanosilicates

    NASA Astrophysics Data System (ADS)

    Garofalo, E.; Claro, M.; Scarfato, P.; Di Maio, L.; Incarnato, L.

    2015-12-01

    Currently, the growing consumption of polymer products creates large quantities of waste materials resulting in public concern in the environment and people life. The efficient treatment of polymer wastes is still a difficult challenge and the recycling process represents the best way to manage them. Recently, many researchers have tried to develop nanotechnology for polymer recycling. The products prepared through the addition of nanoparticles to post-used plastics could offer the combination of improved properties, low weight, easy of processing and low cost which is not easily and concurrently found by other methods of plastic recycling. In this study materials, obtained by the separation and mechanical recycling of post-consumer packaging films of small size (thermal, rheological and mechanical properties of the prepared nanocomposites were extensively discussed.

  16. Thermal interface material characterization for cryogenic electronic packaging solutions

    NASA Astrophysics Data System (ADS)

    Dillon, A.; McCusker, K.; Van Dyke, J.; Isler, B.; Christiansen, M.

    2017-12-01

    As applications of superconducting logic technologies continue to grow, the need for efficient and reliable cryogenic packaging becomes crucial to development and testing. A trade study of materials was done to develop a practical understanding of the properties of interface materials around 4 K. While literature exists for varying interface tests, discrepancies are found in the reported performance of different materials and in the ranges of applied force in which they are optimal. In considering applications extending from top cooling a silicon chip to clamping a heat sink, a range of forces from approximately 44 N to approximately 445 N was chosen for testing different interface materials. For each range of forces a single material was identified to optimize the thermal conductance of the joint. Of the tested interfaces, indium foil clamped at approximately 445 N showed the highest thermal conductance. Results are presented from these characterizations and useful methodologies for efficient testing are defined.

  17. Gravity packaging final waste recovery based on gravity separation and chemical imaging control.

    PubMed

    Bonifazi, Giuseppe; Serranti, Silvia; Potenza, Fabio; Luciani, Valentina; Di Maio, Francesco

    2017-02-01

    Plastic polymers are characterized by a high calorific value. Post-consumer plastic waste can be thus considered, in many cases, as a typical secondary solid fuels according to the European Commission directive on End of Waste (EoW). In Europe the practice of incineration is considered one of the solutions for waste disposal waste, for energy recovery and, as a consequence, for the reduction of waste sent to landfill. A full characterization of these products represents the first step to profitably and correctly utilize them. Several techniques have been investigated in this paper in order to separate and characterize post-consumer plastic packaging waste fulfilling the previous goals, that is: gravity separation (i.e. Reflux Classifier), FT-IR spectroscopy, NIR HyperSpectralImaging (HSI) based techniques and calorimetric test. The study demonstrated as the proposed separation technique and the HyperSpectral NIR Imaging approach allow to separate and recognize the different polymers (i.e. PolyVinyl Chloride (PVC), PolyStyrene (PS), PolyEthylene (PE), PoliEtilene Tereftalato (PET), PolyPropylene (PP)) in order to maximize the removal of the PVC fraction from plastic waste and to perform the full quality control of the resulting products, can be profitably utilized to set up analytical/control strategies finalized to obtain a low content of PVC in the final Solid Recovered Fuel (SRF), thus enhancing SRF quality, increasing its value and reducing the "final waste". Copyright © 2016 Elsevier Ltd. All rights reserved.

  18. Utilizing Radioisotope Power System Waste Heat for Spacecraft Thermal Management

    NASA Technical Reports Server (NTRS)

    Pantano, David R.; Dottore, Frank; Geng, Steven M.; Schrieber, Jeffrey G.; Tobery, E. Wayne; Palko, Joseph L.

    2005-01-01

    One of the advantages of using a Radioisotope Power System (RPS) for deep space or planetary surface missions is the readily available waste heat, which can be used to maintain electronic components within a controlled temperature range, to warm propulsion tanks and mobility actuators, and to gasify liquid propellants. Previous missions using Radioisotope Thermoelectric Generators (RTGs) dissipated a very large quantity of waste heat due to the relatively low efficiency of the thermoelectric conversion technology. The next generation RPSs, such as the 110-watt Stirling Radioisotope Generator (SRG110) will have much higher conversion efficiencies than their predecessors and therefore may require alternate approaches to transferring waste heat to the spacecraft. RTGs, with efficiencies of approx. 6 to 7% and 200 C housing surface temperatures, would need to use large and heavy radiator heat exchangers to transfer the waste heat to the internal spacecraft components. At the same time, sensitive spacecraft instruments must be shielded from the thermal radiation by using the heat exchangers or additional shields. The SRG110, with an efficiency around 22% and 50 C nominal housing surface temperature, can use the available waste heat more efficiently by more direct heat transfer methods such as heat pipes, thermal straps, or fluid loops. The lower temperatures allow the SRG110 much more flexibility to the spacecraft designers in configuring the generator without concern of overheating nearby scientific instruments, thereby eliminating the need for thermal shields. This paper will investigate using a high efficiency SRG110 for spacecraft thermal management and outline potential methods in several conceptual missions (Lunar Rover, Mars Rover, and Titan Lander) to illustrate the advantages with regard to ease of assembly, less complex interfaces, and overall mass savings.

  19. Evaluation Framework and Analyses for Thermal Energy Storage Integrated with Packaged Air Conditioning

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Kung, F.; Deru, M.; Bonnema, E.

    2013-10-01

    Few third-party guidance documents or tools are available for evaluating thermal energy storage (TES) integrated with packaged air conditioning (AC), as this type of TES is relatively new compared to TES integrated with chillers or hot water systems. To address this gap, researchers at the National Renewable Energy Laboratory conducted a project to improve the ability of potential technology adopters to evaluate TES technologies. Major project outcomes included: development of an evaluation framework to describe key metrics, methodologies, and issues to consider when assessing the performance of TES systems integrated with packaged AC; application of multiple concepts from the evaluationmore » framework to analyze performance data from four demonstration sites; and production of a new simulation capability that enables modeling of TES integrated with packaged AC in EnergyPlus. This report includes the evaluation framework and analysis results from the project.« less

  20. Identification of the bioactive compounds and antioxidant, antimutagenic and antimicrobial activities of thermally processed agro-industrial waste.

    PubMed

    Vodnar, Dan Cristian; Călinoiu, Lavinia Florina; Dulf, Francisc Vasile; Ştefănescu, Bianca Eugenia; Crişan, Gianina; Socaciu, Carmen

    2017-09-15

    The purpose of the research was to identify the bioactive compounds and to evaluate the antioxidant, antimutagenic and antimicrobial activities of the major Romanian agro-industrial wastes (apple peels, carrot pulp, white- and red-grape peels and red-beet peels and pulp) for the purpose of increasing the wastes' value. Each type of waste material was analyzed without (fresh) and with thermal processing (10min, 80°C). Based on the obtained results, the thermal process enhanced the total phenolic content. The highest antioxidant activity was exhibited by thermally processed red-grape waste followed by thermally processed red-beet waste. Linoleic acid was the major fatty acid in all analyzed samples, but its content decreased significantly during thermal processing. The carrot extracts have no antimicrobial effects, while the thermally processed red-grape waste has the highest antimicrobial effect against the studied strains. The thermally processed red-grape sample has the highest antimutagenic activity toward S. typhimurium TA98 and TA100. Copyright © 2017 Elsevier Ltd. All rights reserved.

  1. Case study: Is the 'catch-all-plastics bin' useful in unlocking the hidden resource potential in the residual waste collection system?

    PubMed

    Kranzinger, Lukas; Schopf, Kerstin; Pomberger, Roland; Punesch, Elisabeth

    2017-02-01

    Austria's performance in the collection of separated waste is adequate. However, the residual waste still contains substantial amounts of recyclable materials - for example, plastics, paper and board, glass and composite packaging. Plastics (lightweight packaging and similar non-packaging materials) are detected at an average mass content of 13% in residual waste. Despite this huge potential, only 3% of the total amount of residual waste (1,687,000 t y -1 ) is recycled. This implies that most of the recyclable materials contained in the residual waste are destined for thermal recovery and are lost for recycling. This pilot project, commissioned by the Land of Lower Austria, applied a holistic approach, unique in Europe, to the Lower Austrian waste management system. It aims to transfer excess quantities of plastic packaging and non-packaging recyclables from the residual waste system to the separately collected waste system by introducing a so-called 'catch-all-plastics bin'. A quantity flow model was constructed and the results showed a realistic increase in the amount of plastics collected of 33.9 wt%. This equals a calculated excess quantity of 19,638 t y -1 . The increased plastics collection resulted in a positive impact on the climate footprint (CO 2 equivalent) in line with the targets of EU Directive 94/62/EG (Circular Economy Package) and its Amendments. The new collection system involves only moderate additional costs.

  2. Investigation of thermodynamic parameters in the thermal decomposition of plastic waste-waste lube oil compounds.

    PubMed

    Kim, Yong Sang; Kim, Young Seok; Kim, Sung Hyun

    2010-07-01

    Thermal decomposition properties of plastic waste-waste lube oil compounds were investigated under nonisothermal conditions. Polyethylene (PE), polypropylene (PP), polystyrene (PS), and polyethylene terephthalate (PET) were selected as representative household plastic wastes. A plastic waste mixture (PWM) and waste lube oil (WLO) were mixed with mixing ratios of 33, 50, and 67 (w/w) % on a PWM weight basis, and thermogravimetric (TG) experiments were performed from 25 to 600 degrees C. The Flynn-Wall method and the Ozawa-Flynn-Wall method were used for analyses of thermodynamic parameters. In this study, activation energies of PWM/WLO compounds ranged from 73.4 to 229.6 kJ/mol between 0.2 and 0.8 of normalized mass conversions, and the 50% PWM/WLO compound had lower activation energies and enthalpies among the PWM/WLO samples at each mass conversion. At the point of maximum differential mass conversion, the analyzed activation energies, enthalpies, entropies, and Gibbs free energies indicated that mixing PWM and WLO has advantages in reducing energy to decrease the degree of disorder. However, no difference in overall energy that would require overcoming both thermal decomposition reactions and degree of disorder was observed among PWM/WLO compounds under these experimental conditions.

  3. Applications of thermal energy storage to waste heat recovery in the food processing industry

    NASA Astrophysics Data System (ADS)

    Wojnar, F.; Lunberg, W. L.

    1980-03-01

    A study to assess the potential for waste heat recovery in the food industry and to evaluate prospective waste heat recovery system concepts employing thermal energy storage was conducted. The study found that the recovery of waste heat in canning facilities can be performed in significant quantities using systems involving thermal energy storage that are both practical and economical. A demonstration project is proposed to determine actual waste heat recovery costs and benefits and to encourage system implementation by the food industry.

  4. Applications of thermal energy storage to waste heat recovery in the food processing industry

    NASA Technical Reports Server (NTRS)

    Wojnar, F.; Lunberg, W. L.

    1980-01-01

    A study to assess the potential for waste heat recovery in the food industry and to evaluate prospective waste heat recovery system concepts employing thermal energy storage was conducted. The study found that the recovery of waste heat in canning facilities can be performed in significant quantities using systems involving thermal energy storage that are both practical and economical. A demonstration project is proposed to determine actual waste heat recovery costs and benefits and to encourage system implementation by the food industry.

  5. Thermal treatment of toxic metals of industrial hazardous wastes with fly ash and clay.

    PubMed

    Singh, I B; Chaturvedi, K; Morchhale, R K; Yegneswaran, A H

    2007-03-06

    Waste generated from galvanizing and metal finishing processes is considered to be a hazardous due to the presence of toxic metals like Pb, Cu, Cr, Zn, etc. Thermal treatment of such types of wastes in the presence of clay and fly ash can immobilizes their toxic metals to a maximum level. After treatment solidified mass can be utilized in construction or disposed off through land fillings without susceptibility of re-mobilization of toxic metals. In the present investigation locally available clay and fly ash of particular thermal power plant were used as additives for thermal treatment of both of the wastes in their different proportions at 850, 900 and 950 degrees C. Observed results indicated that heating temperature to be a key factor in the immobilization of toxic metals of the waste. It was noticed that the leachability of metals of the waste reduces to a negligible level after heating at 950 degrees C. Thermally treated solidified specimen of 10% waste and remaining clay have shown comparatively a higher compressive strength than clay fired bricks used in building construction. Though, thermally heated specimens made of galvanizing waste have shown much better strength than specimen made of metal finishing waste. The lechability of toxic metals like Cr, Cu, Pb and Zn became far below from their regulatory threshold after heating at 950 degrees C. Addition of fly ash did not show any improvement either in engineering property or in leachability of metals from the solidified mass. X-ray diffraction (XRD) analysis of the solidified product confirmed the presence of mixed phases of oxides of metals.

  6. Energy implications of the thermal recovery of biodegradable municipal waste materials in the United Kingdom

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Burnley, Stephen, E-mail: s.j.burnley@open.ac.uk; Phillips, Rhiannon, E-mail: rhiannon.jones@environment-agency.gov.uk; Coleman, Terry, E-mail: terry.coleman@erm.com

    2011-09-15

    Highlights: > Energy balances were calculated for the thermal treatment of biodegradable wastes. > For wood and RDF, combustion in dedicated facilities was the best option. > For paper, garden and food wastes and mixed waste incineration was the best option. > For low moisture paper, gasification provided the optimum solution. - Abstract: Waste management policies and legislation in many developed countries call for a reduction in the quantity of biodegradable waste landfilled. Anaerobic digestion, combustion and gasification are options for managing biodegradable waste while generating renewable energy. However, very little research has been carried to establish the overall energymore » balance of the collection, preparation and energy recovery processes for different types of wastes. Without this information, it is impossible to determine the optimum method for managing a particular waste to recover renewable energy. In this study, energy balances were carried out for the thermal processing of food waste, garden waste, wood, waste paper and the non-recyclable fraction of municipal waste. For all of these wastes, combustion in dedicated facilities or incineration with the municipal waste stream was the most energy-advantageous option. However, we identified a lack of reliable information on the energy consumed in collecting individual wastes and preparing the wastes for thermal processing. There was also little reliable information on the performance and efficiency of anaerobic digestion and gasification facilities for waste.« less

  7. Assessment of collection schemes for packaging and other recyclable waste in European Union-28 Member States and capital cities.

    PubMed

    Seyring, Nicole; Dollhofer, Marie; Weißenbacher, Jakob; Bakas, Ioannis; McKinnon, David

    2016-09-01

    The Waste Framework Directive obliged European Union Member States to set up separate collection systems to promote high quality recycling for at least paper, metal, plastic and glass by 2015. As implementation of the requirement varies across European Union Member States, the European Commission contracted BiPRO GmbH/Copenhagen Resource Institute to assess the separate collection schemes in the 28 European Union Member States, focusing on capital cities and on metal, plastic, glass (with packaging as the main source), paper/cardboard and bio-waste. The study includes an assessment of the legal framework for, and the practical implementation of, collection systems in the European Union-28 Member States and an in depth-analysis of systems applied in all capital cities. It covers collection systems that collect one or more of the five waste streams separately from residual waste/mixed municipal waste at source (including strict separation, co-mingled systems, door-to-door, bring-point collection and civic amenity sites). A scoreboard including 13 indicators is elaborated in order to measure the performance of the systems with the capture rates as key indicators to identify best performers. Best performance are by the cities of Ljubljana, Helsinki and Tallinn, leading to the key conclusion that door-to-door collection, at least for paper and bio-waste, and the implementation of pay-as-you-throw schemes results in high capture and thus high recycling rates of packaging and other municipal waste. © The Author(s) 2016.

  8. Performance Assessment of a Generic Repository in Bedded Salt for DOE-Managed Nuclear Waste

    NASA Astrophysics Data System (ADS)

    Stein, E. R.; Sevougian, S. D.; Hammond, G. E.; Frederick, J. M.; Mariner, P. E.

    2016-12-01

    A mined repository in salt is one of the concepts under consideration for disposal of DOE-managed defense-related spent nuclear fuel (SNF) and high level waste (HLW). Bedded salt is a favorable medium for disposal of nuclear waste due to its low permeability, high thermal conductivity, and ability to self-heal. Sandia's Generic Disposal System Analysis framework is used to assess the ability of a generic repository in bedded salt to isolate radionuclides from the biosphere. The performance assessment considers multiple waste types of varying thermal load and radionuclide inventory, the engineered barrier system comprising the waste packages, backfill, and emplacement drifts, and the natural barrier system formed by a bedded salt deposit and the overlying sedimentary sequence (including an aquifer). The model simulates disposal of nearly the entire inventory of DOE-managed, defense-related SNF (excluding Naval SNF) and HLW in a half-symmetry domain containing approximately 6 million grid cells. Grid refinement captures the detail of 25,200 individual waste packages in 180 disposal panels, associated access halls, and 4 shafts connecting the land surface to the repository. Equations describing coupled heat and fluid flow and reactive transport are solved numerically with PFLOTRAN, a massively parallel flow and transport code. Simulated processes include heat conduction and convection, waste package failure, waste form dissolution, radioactive decay and ingrowth, sorption, solubility limits, advection, dispersion, and diffusion. Simulations are run to 1 million years, and radionuclide concentrations are observed within an aquifer at a point approximately 4 kilometers downgradient of the repository. The software package DAKOTA is used to sample likely ranges of input parameters including waste form dissolution rates and properties of engineered and natural materials in order to quantify uncertainty in predicted concentrations and sensitivity to input parameters. Sandia

  9. Intact and Degraded Criticality Calculations for the Codisposal of Shippingport LWBR Spent Nuclear Fuel in a Waste Package

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    L.M. Montierth

    2000-09-15

    The objective of this calculation is to characterize the nuclear criticality safety concerns associated with the codisposal of the U.S. Department of Energy's (DOE) Shippingport Light Water Breeder Reactor (SP LWBR) Spent Nuclear Fuel (SNF) in a 5-Defense High-Level Waste (5-DHLW) Waste Package (WP), which is to be placed in a Monitored Geologic Repository (MGR). The scope of this calculation is limited to the determination of the effective neutron multiplication factor (K{sub eff}) for intact- and degraded-mode internal configurations of the codisposal WP containing Shippingport LWBR seed-type assemblies. The results of this calculation will be used to evaluate criticality issuesmore » and support the analysis that is planed to be performed to demonstrate the viability of the codisposal concept for the MGR. This calculation is associated with the waste package design and was performed in accordance with the DOE SNF Analysis Plan for FY 2000 (See Ref. 22). The document has been prepared in accordance with the Administrative Procedure AP-3.12Q, Calculations (Ref. 23).« less

  10. Model for the separate collection of packaging waste in Portuguese low-performing recycling regions.

    PubMed

    Oliveira, V; Sousa, V; Vaz, J M; Dias-Ferreira, C

    2018-06-15

    Separate collection of packaging waste (glass; plastic/metals; paper/cardboard), is currently a widespread practice throughout Europe. It enables the recovery of good quality recyclable materials. However, separate collection performance are quite heterogeneous, with some countries reaching higher levels than others. In the present work, separate collection of packaging waste has been evaluated in a low-performance recycling region in Portugal in order to investigate which factors are most affecting the performance in bring-bank collection system. The variability of separate collection yields (kg per inhabitant per year) among 42 municipalities was scrutinized for the year 2015 against possible explanatory factors. A total of 14 possible explanatory factors were analysed, falling into two groups: socio-economic/demographic and waste collection service related. Regression models were built in an attempt to evaluate the individual effect of each factor on separate collection yields and predict changes on the collection yields by acting on those factors. The best model obtained is capable to explain 73% of the variation found in the separate collection yields. The model includes the following statistically significant indicators affecting the success of separate collection yields: i) inhabitants per bring-bank; ii) relative accessibility to bring-banks; iii) degree of urbanization; iv) number of school years attended; and v) area. The model presented in this work was developed specifically for the bring-bank system, has an explanatory power and quantifies the impact of each factor on separate collection yields. It can therefore be used as a support tool by local and regional waste management authorities in the definition of future strategies to increase collection of recyclables of good quality and to achieve national and regional targets. Copyright © 2017 Elsevier Ltd. All rights reserved.

  11. Experimental research of solid waste drying in the process of thermal processing

    NASA Astrophysics Data System (ADS)

    Bukhmirov, V. V.; Kolibaba, O. B.; Gabitov, R. N.

    2015-10-01

    The convective drying process of municipal solid waste layer as a polydispersed multicomponent porous structure is studied. On the base of the experimental data criterial equations for calculating heat transfer and mass transfer processes in the layer, depending on the humidity of the material, the speed of the drying agent and the layer height are obtained. These solutions are used in the thermal design of reactors for the thermal processing of multicomponent organic waste.

  12. Thermal co-treatment of combustible hazardous waste and waste incineration fly ash in a rotary kiln.

    PubMed

    Huber, Florian; Blasenbauer, Dominik; Mallow, Ole; Lederer, Jakob; Winter, Franz; Fellner, Johann

    2016-12-01

    As current disposal practices for municipal solid waste incineration (MSWI) fly ash are either associated with significant costs or negative environmental impacts, an alternative treatment was investigated in a field scale experiment. Thereto, two rotary kilns were fed with hazardous waste, and moistened MSWI fly ash (water content of 23%) was added to the fuel of one kiln with a ratio of 169kg/Mg hazardous waste for 54h and 300kg/Mg hazardous waste for 48h while the other kiln was used as a reference. It was shown that the vast majority (>90%) of the inserted MSWI fly ash was transferred to the bottom ash of the rotary kiln. This bottom ash complied with the legal limits for non-hazardous waste landfills, thereby demonstrating the potential of the investigated method to transfer hazardous waste (MSWI fly ash) into non-hazardous waste (bottom ash). The results of a simple mixing test (MSWI fly ash and rotary kiln bottom ash have been mixed accordingly without thermal treatment) revealed that the observed transformation of hazardous MSWI fly ash into non-hazardous bottom ash during thermal co-treatment cannot be referred to dilution, as the mixture did not comply with legal limits for non-hazardous waste landfills. For the newly generated fly ash of the kiln, an increase in the concentration of Cd, K and Pb by 54%, 57% and 22%, respectively, was observed. In general, the operation of the rotary kiln was not impaired by the MSWI fly ash addition. Copyright © 2016 Elsevier Ltd. All rights reserved.

  13. Review on factors influencing thermal conductivity of concrete incorporating various type of waste materials

    NASA Astrophysics Data System (ADS)

    Misri, Z.; Ibrahim, M. H. W.; Awal, A. S. M. A.; Desa, M. S. M.; Ghadzali, N. S.

    2018-04-01

    Concrete is well-known as a construction material which is widely used in building and infrastructure around the world. However, its widespread use has affected the reduction of natural resources. Hence, many approached have been made by researchers to study the incorporation of waste materials in concrete as a substitution for natural resources besides reducing waste disposal problems. Concrete is basically verified by determining its properties; strengths, permeability, shrinkage, durability, thermal properties etc. In various thermal properties of concrete, thermal conductivity (TC) has received a large amount of attention because it is depend upon the composition of concrete. Thermal conductivity is important in building insulation to measure the ability of a material to transfer heat. The aim of this paper is to discuss the methods and influence factors of TC of concrete containing various type of waste materials.

  14. Thermal-Hydrology Simulations of Disposal of High-Level Radioactive Waste in a Single Deep Borehole

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Hadgu, Teklu; Stein, Emily; Hardin, Ernest

    2015-11-01

    Simulations of thermal-hydrology were carried out for the emplacement of spent nuclear fuel canisters and cesium and strontium capsules using the PFLOTRAN simulator. For the cesium and strontium capsules the analysis looked at disposal options such as different disposal configurations and surface aging of waste to reduce thermal effects. The simulations studied temperature and fluid flux in the vicinity of the borehole. Simulation results include temperature and vertical flux profiles around the borehole at selected depths. Of particular importance are peak temperature increases, and fluxes at the top of the disposal zone. Simulations of cesium and strontium capsule disposal predictmore » that surface aging and/or emplacement of the waste at the top of the disposal zone reduces thermal effects and vertical fluid fluxes. Smaller waste canisters emplaced over a longer disposal zone create the smallest thermal effect and vertical fluid fluxes no matter the age of the waste or depth of emplacement.« less

  15. Thermal and enzymatic recovering of proteins from untanned leather waste.

    PubMed

    Bajza, Z; Vrucek, V

    2001-01-01

    The laboratory trials of a process to treat untanned leather waste to isolate valuable protein products are presented. In this comparative study, both thermal and enzymatic treatments of leather waste were performed. The enzymatic method utilizes commercially available alkaline protease at moderate temperatures and for short periods of time. The concentration of the enzyme was 500 units per gram of leather waste which makes the method cost-effective. Amino acid composition in the hydrolysate obtained by the enzyme hydrolysis of untanned leather waste is determined. Chemical and physical properties of protein powder products from untanned leather waste were evaluated by spectrophotometric and chromatographic methods and by use of electron microscope. The results of microbiological assays confirm that these products agree to food safety standards. This relatively simple treatment of untanned leather waste may provide a practical and economical solution to the disposal of potentially dangerous waste.

  16. Energy implications of the thermal recovery of biodegradable municipal waste materials in the United Kingdom.

    PubMed

    Burnley, Stephen; Phillips, Rhiannon; Coleman, Terry; Rampling, Terence

    2011-01-01

    Waste management policies and legislation in many developed countries call for a reduction in the quantity of biodegradable waste landfilled. Anaerobic digestion, combustion and gasification are options for managing biodegradable waste while generating renewable energy. However, very little research has been carried to establish the overall energy balance of the collection, preparation and energy recovery processes for different types of wastes. Without this information, it is impossible to determine the optimum method for managing a particular waste to recover renewable energy. In this study, energy balances were carried out for the thermal processing of food waste, garden waste, wood, waste paper and the non-recyclable fraction of municipal waste. For all of these wastes, combustion in dedicated facilities or incineration with the municipal waste stream was the most energy-advantageous option. However, we identified a lack of reliable information on the energy consumed in collecting individual wastes and preparing the wastes for thermal processing. There was also little reliable information on the performance and efficiency of anaerobic digestion and gasification facilities for waste. Copyright © 2011 Elsevier Ltd. All rights reserved.

  17. 21 CFR 108.35 - Thermal processing of low-acid foods packaged in hermetically sealed containers.

    Code of Federal Regulations, 2010 CFR

    2010-04-01

    ... authorized employee of the Food and Drug Administration to inspect the commercial processor's manufacturing... 21 Food and Drugs 2 2010-04-01 2010-04-01 false Thermal processing of low-acid foods packaged in hermetically sealed containers. 108.35 Section 108.35 Food and Drugs FOOD AND DRUG ADMINISTRATION, DEPARTMENT...

  18. Recent advances in photonics packaging materials

    NASA Astrophysics Data System (ADS)

    Zweben, Carl

    2006-02-01

    There are now over a dozen low-CTE materials with thermal conductivities between that of copper (400 w/m-K) and over 4X copper (1700 W/m-K). Most have low densities. For comparison, traditional low-CTE packaging materials like copper/tungsten have thermal conductivities that are little or no better than that of aluminum (200 W/m-K) and high densities. There are also low-density thermal insulators with low CTEs. Some advanced materials are low cost. Most do not outgas. They have a wide range of electrical properties that can be used to minimize electromagnetic emissions or provide EMI shielding. Several are now in commercial and aerospace applications, including laser diode packages; light-emitting diode (LED) packages; thermoelectric cooler bases, plasma displays; power modules; servers; laptops; heat sinks; thermally conductive, low-CTE printed circuit boards; and printed circuit board cold plates. Advanced material payoffs include: improved thermal performance, reliability, alignment and manufacturing yield; reduced thermal stresses and heating power requirements; simplified thermal design; enablement of hard solder direct attach; weight savings up to 85%; size reductions up to 65%; and lower cost. This paper discusses the large and increasing number of advanced packaging materials, including properties, development status, applications, increasing manufacturing yield, cost, lessons learned and future directions, including nanocomposites.

  19. Application of Glass Fiber Waste Polypropylene Aggregate in Lightweight Concrete – thermal properties

    NASA Astrophysics Data System (ADS)

    Citek, D.; Rehacek, S.; Pavlik, Z.; Kolisko, J.; Dobias, D.; Pavlikova, M.

    2018-03-01

    Actual paper focus on thermal properties of a sustainable lightweight concrete incorporating high volume of waste polypropylene aggregate as partial substitution of natural aggregate. In presented experiments a glass fiber reinforced polypropylene (GFPP) which is a by-product of PP tubes production, partially substituted fine natural silica aggregate in 10, 20, 30, 40 and 50 mass %. Results were compared with a reference concrete mix without plastic waste in order to quantify the effect of GFPP use on concrete properties. Main material physical parameters were studied (bulk density, matrix density without air content, and particle size distribution). Especially a thermal transport and storage properties of GFPP were examined in dependence on compaction time. For the developed lightweight concrete, thermal properties were accessed using transient impulse technique, where the measurement was done in dependence on moisture content (from the fully water saturated state to dry state). It was found that the tested lightweight concrete should be prospective construction material possessing improved thermal insulation function and the reuse of waste plastics in concrete composition was beneficial both from the environmental and financial point of view.

  20. Innovative Soft-Sided Waste Packaging System Implementation at a Small Department of Energy Environmental Restoration/Waste Management (ER/WM) Site

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Wolf, J.

    2002-02-28

    Weiss Associates (WA) performs a broad range of environmental restoration/waste management (ER/WM) activities for the U.S. Department of Energy (DOE) at the former Laboratory for Energy-Related Health Research (LEHR), University of California, Davis (UC Davis). Over the last three years, the LEHR ER/WM program transitioned from a baseline packaging system of steel, 2.7 cubic meter (3.5-cubic yard) B-25 boxes to a 7.0 cubic meter (9.1-cubic yard) soft-sided container (Lift Liner) system. The transition increased efficiencies in processing, packaging, and storage, and when combined with decreased procurement costs, achieved a $402,000 cost savings (Table I). Additional disposal costs between $128,600 andmore » $182,600 were avoided by minimizing void space. Future cost savings by the end of fiscal year 2003 are projected between $250,640 and $1,003,360.« less

  1. Waste IPSC : Thermal-Hydrologic-Chemical-Mechanical (THCM) modeling and simulation.

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Freeze, Geoffrey A.; Wang, Yifeng; Arguello, Jose Guadalupe, Jr.

    2010-10-01

    Waste IPSC Objective is to develop an integrated suite of high performance computing capabilities to simulate radionuclide movement through the engineered components and geosphere of a radioactive waste storage or disposal system: (1) with robust thermal-hydrologic-chemical-mechanical (THCM) coupling; (2) for a range of disposal system alternatives (concepts, waste form types, engineered designs, geologic settings); (3) for long time scales and associated large uncertainties; (4) at multiple model fidelities (sub-continuum, high-fidelity continuum, PA); and (5) in accordance with V&V and software quality requirements. THCM Modeling collaborates with: (1) Other Waste IPSC activities: Sub-Continuum Processes (and FMM), Frameworks and Infrastructure (and VU,more » ECT, and CT); (2) Waste Form Campaign; (3) Used Fuel Disposition (UFD) Campaign; and (4) ASCEM.« less

  2. Applications of thermal energy storage to waste heat recovery in the food processing industry

    NASA Astrophysics Data System (ADS)

    Trebilcox, G. J.; Lundberg, W. L.

    1981-03-01

    The canning segment of the food processing industry is a major energy user within that industry. Most of its energy demand is met by hot water and steam and those fluids, in addition to product cooling water, eventually flow from the processes as warm waste water. To minimize the possibility of product contamination, a large percentage of that waste water is sent directly to factory drains and sewer systems without being recycled and in many cases the thermal energy contained by the waste streams also goes unreclaimed and is lost from further use. Waste heat recovery in canning facilities can be performed economically using systems that employ thermal energy storage (TES). A project was proposed in which a demonstration waste heat recovery system, including a TES feature, would be designed, installed and operated.

  3. Packaged Waste Treatment

    NASA Technical Reports Server (NTRS)

    1977-01-01

    This Jacksonville, Florida, apartment complex has a wastewater treatment system which clears the water, removes harmful microorganisms and reduces solid residue to ash. It is a spinoff from spacecraft waste management and environmental control technology.

  4. An Innovative Very Low Thermal Power Waste Heat Recovery System for Thermal Control of Deep Space Missions: A Thermal Flask in Space

    NASA Technical Reports Server (NTRS)

    Bhandari, Pradeep

    2015-01-01

    Future missions to deep space, such as those to the outer planets (Jupiter, Saturn, etc.), which would rely on solar photovoltaic power, would need extremely large solar arrays to produce sufficient power for their operations because solar intensity is so low at those locations. Hence any additional power that would be needed for thermal control is extremely limited. Previous deep space missions like Juno (to Jupiter) required almost 200 W of electrical power for thermal control. This is prohibitively large for many future mission concepts, and leads to them needing very large solar arrays. For Saturn, where the solar flux is 1/4th the flux at Jupiter, this would entail an extremely large increase in the solar array size to accommodate the need for thermal survival power, which would be prohibitively large in size and mass, and very expensive. Hence there is a need to come up with a thermal architecture and design options that would not need such prohibitively large thermal power levels. One solution relies on harvesting the pre-existing waste heat from all the heat dissipation that would be present from operation of electronics, instruments, etc. for their own functionality. For example, for a generic Saturn mission, the various electronics would already dissipate about 200 Watts of heat that is simply "thrown away" to space from the spacecraft surfaces. The amount of thermal power that would be required for the safe thermal control of components within the spacecraft in deep space would be roughly of this magnitude for this class of spacecraft. So it makes good sense to try to harvest the waste heat and employ it to maintain the temperatures of all the components within their allowable limits. In particular, propulsion systems typically need to be kept above their freezing limits, around room temperature (15 C). Electronics needs to be kept typically above -40 C and batteries above -20 C. The next question becomes how to harvest this waste heat and direct it to

  5. Environmental Assessment of Packaging: The Consumer Point of View

    PubMed

    Van Dam YK

    1996-09-01

    When marketing environmentally responsible packaged products, the producer is confronted with consumer beliefs concerning the environmental friendliness of packaging materials. When making environmentally conscious packaging decisions, these consumer beliefs should be taken into account alongside the technical guidelines. Dutch consumer perceptions of the environmental friendliness of packaged products are reported and compared with the results of a life-cycle analysis assessment. It is shown that consumers judge environmental friendliness mainly from material and returnability. Furthermore, the consumer perception of the environmental friendliness of packaging material is based on the postconsumption waste, whereas the environmental effects of production are ignored. From the consumer beliefs concerning environmental friendliness implications are deduced for packaging policy and for environmental policy.KEY WORDS: Consumer behavior; Environment; Food; Packaging; Perception; Waste

  6. Evaluation of performance indicators applied to a material recovery facility fed by mixed packaging waste.

    PubMed

    Mastellone, Maria Laura; Cremiato, Raffaele; Zaccariello, Lucio; Lotito, Roberta

    2017-06-01

    Most of the integrated systems for municipal solid waste management aim to increase the recycling of secondary materials by means of physical processes including sorting, shredding and reprocessing. Several restrictions prevent from reaching a very high material recycling efficiency: the variability of the composition of new-marketed materials used for packaging production and its shape and complexity are critical issues. The packaging goods are in fact made of different materials (aluminium, polymers, paper, etc.), possibly assembled, having different shape (flat, cylindrical, one-dimensional, etc.), density, colours, optical properties and so on. These aspects limit the effectiveness and efficiency of the sorting and reprocessing plants. The scope of this study was to evaluate the performance of a large scale Material Recovery Facility (MRF) by utilizing data collected during a long period of monitoring. The database resulted from the measured data has been organized in four sections: (1) data related to the amount and type of inlet waste; (2) amount and composition of output products and waste; (3) operating data (such as worked hours for shift, planned and unscheduled maintenance time, setting parameters of the equipment, and energy consumption for shift); (4) economic data (value of each product, disposal price for the produced waste, penalty for non-compliance of products and waste, etc.). A part of this database has been utilized to build an executive dashboard composed by a set of performance indicators suitable to measure the effectiveness and the efficiency of the MRF operations. The dashboard revealed itself as a powerful tool to support managers and engineers in their decisions in respect to the market demand or compliance regulation variation as well as in the designing of the lay-out improvements. The results indicated that the 40% of the input waste was recovered as valuable products and that a large part of these (88%) complied with the standards of

  7. Gas permeability and thermal behavior of polypropylene films used for packaging minimally processed fresh-cut potatoes: a case study.

    PubMed

    Siracusa, Valentina; Blanco, Ignazio; Romani, Santina; Tylewicz, Urszula; Dalla Rosa, Marco

    2012-10-01

    This work reports an experimental study on the permeability and thermal behavior of commercial polypropylene (PP) film used for fresh-cut potatoes packaging. The permeability was tested using oxygen, carbon dioxide, nitrogen, mix of these 3 gases, normally used for modified atmosphere packaging (MAP) and Air, to understand if it would be possible to extend the shelf life of this food product designed for the catering field in respect to the packaging behavior. The temperature influence on permeability data, from 5 to 40 °C, was analyzed, before and after 4, 8, 12, 15, and 20 d of food contact, pointing out the dependence between temperature and gas transmission rate (GTR), solubility (S), diffusion coefficient (D), and time lag (t(L)) parameters. The activation energies (E) of the permeation process were determined with the different gases used in the experiments. The thermal behavior of PP film was studied by differential scanning calorimetry (DSC) and thermogravimetric analysis (TG) to well understand its thermal stability. Fourier transformed-infrared with attenuated total reflectance (FT-IR/ATR) spectroscopy was also performed in order to study the influence of the food contact on the chemical characteristics of the polymer film. The results obtained were discussed and compared each other. Studied samples showed, for all investigated gases, an increase of gas permeability and S values at higher temperature. Heat resistance classification among the sample as it is and stored in modified atmospheres was made. Finally all performed experiments have showed good polymer stability for the shelf-life storage potatoes under study. Study of packaging material was performed in a range of temperature, which can simulate the service condition to assess the suitability of a commercial polymer film for modified atmosphere packaging of fresh-cut potatoes minimally processed designed for catering purpose. © 2012 Institute of Food Technologists®

  8. Modular electronics packaging system

    NASA Technical Reports Server (NTRS)

    Hunter, Don J. (Inventor)

    2001-01-01

    A modular electronics packaging system includes multiple packaging slices that are mounted horizontally to a base structure. The slices interlock to provide added structural support. Each packaging slice includes a rigid and thermally conductive housing having four side walls that together form a cavity to house an electronic circuit. The chamber is enclosed on one end by an end wall, or web, that isolates the electronic circuit from a circuit in an adjacent packaging slice. The web also provides a thermal path between the electronic circuit and the base structure. Each slice also includes a mounting bracket that connects the packaging slice to the base structure. Four guide pins protrude from the slice into four corresponding receptacles in an adjacent slice. A locking element, such as a set screw, protrudes into each receptacle and interlocks with the corresponding guide pin. A conduit is formed in the slice to allow electrical connection to the electronic circuit.

  9. Containers and Packaging: Product-Specific Data

    EPA Pesticide Factsheets

    This web page provide numbers on the different containers and packaging products in our municipal solid waste. These include containers of all types, such as glass, steel, plastic, aluminum, wood, and other types of packaging

  10. Hazardous waste characterization among various thermal processes in South Korea: a comparative analysis.

    PubMed

    Shin, Sun Kyoung; Kim, Woo-Il; Jeon, Tae-Wan; Kang, Young-Yeul; Jeong, Seong-Kyeong; Yeon, Jin-Mo; Somasundaram, Swarnalatha

    2013-09-15

    Ministry of Environment, Republic of Korea (South Korea) is in progress of converting its current hazardous waste classification system to harmonize it with the international standard and to set-up the regulatory standards for toxic substances present in the hazardous waste. In the present work, the concentrations along with the trend of 13 heavy metals, F(-), CN(-) and 19 PAH present in the hazardous waste generated among various thermal processes (11 processes) in South Korea were analyzed along with their leaching characteristics. In all thermal processes, the median concentrations of Cu (3.58-209,000 mg/kg), Ni (BDL-1560 mg/kg), Pb (7.22-5132.25mg/kg) and Zn (83.02-31419 mg/kg) were comparatively higher than the other heavy metals. Iron & Steel thermal process showed the highest median value of the heavy metals Cd (14.76 mg/kg), Cr (166.15 mg/kg) and Hg (2.38 mg/kg). Low molecular weight PAH (BDL-37.59 mg/kg) was predominant in sludge & filter cake samples present in most of the thermal processes. Comparatively flue gas dust present in most of the thermal processing units resulted in the higher leaching of the heavy metals. Copyright © 2013 Elsevier B.V. All rights reserved.

  11. Tritium Packages and 17th RH Canister Categories of Transuranic Waste Stored Below Ground within Area G

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Hargis, Kenneth Marshall

    A large wildfire called the Las Conchas Fire burned large areas near Los Alamos National Laboratory (LANL) in 2011 and heightened public concern and news media attention over transuranic (TRU) waste stored at LANL’s Technical Area 54 (TA-54) Area G waste management facility. The removal of TRU waste from Area G had been placed at a lower priority in budget decisions for environmental cleanup at LANL because TRU waste removal is not included in the March 2005 Compliance Order on Consent (Reference 1) that is the primary regulatory driver for environmental cleanup at LANL. The Consent Order is a settlementmore » agreement between LANL and the New Mexico Environment Department (NMED) that contains specific requirements and schedules for cleaning up historical contamination at the LANL site. After the Las Conchas Fire, discussions were held by the U.S. Department of Energy (DOE) with the NMED on accelerating TRU waste removal from LANL and disposing it at the Waste Isolation Pilot Plant (WIPP). This report summarizes available information on the origin, configuration, and composition of the waste containers within the Tritium Packages and 17th RH Canister categories; their physical and radiological characteristics; the results of the radioassays; and potential issues in retrieval and processing of the waste containers.« less

  12. Packaging of solid state devices

    DOEpatents

    Glidden, Steven C.; Sanders, Howard D.

    2006-01-03

    A package for one or more solid state devices in a single module that allows for operation at high voltage, high current, or both high voltage and high current. Low thermal resistance between the solid state devices and an exterior of the package and matched coefficient of thermal expansion between the solid state devices and the materials used in packaging enables high power operation. The solid state devices are soldered between two layers of ceramic with metal traces that interconnect the devices and external contacts. This approach provides a simple method for assembling and encapsulating high power solid state devices.

  13. Numerical Modeling of Thermal-Hydrology in the Near Field of a Generic High-Level Waste Repository

    NASA Astrophysics Data System (ADS)

    Matteo, E. N.; Hadgu, T.; Park, H.

    2016-12-01

    Disposal in a deep geologic repository is one of the preferred option for long term isolation of high-level nuclear waste. Coupled thermal-hydrologic processes induced by decay heat from the radioactive waste may impact fluid flow and the associated migration of radionuclides. This study looked at the effects of those processes in simulations of thermal-hydrology for the emplacement of U. S. Department of Energy managed high-level waste and spent nuclear fuel. Most of the high-level waste sources have lower thermal output which would reduce the impact of thermal propagation. In order to quantify the thermal limits this study concentrated on the higher thermal output sources and on spent nuclear fuel. The study assumed a generic nuclear waste repository at 500 m depth. For the modeling a representative domain was selected representing a portion of the repository layout in order to conduct a detailed thermal analysis. A highly refined unstructured mesh was utilized with refinements near heat sources and at intersections of different materials. Simulations looked at different values for properties of components of the engineered barrier system (i.e. buffer, disturbed rock zone and the host rock). The simulations also looked at the effects of different durations of surface aging of the waste to reduce thermal perturbations. The PFLOTRAN code (Hammond et al., 2014) was used for the simulations. Modeling results for the different options are reported and include temperature and fluid flow profiles in the near field at different simulation times. References:G. E. Hammond, P.C. Lichtner and R.T. Mills, "Evaluating the Performance of Parallel Subsurface Simulators: An Illustrative Example with PFLOTRAN", Water Resources Research, 50, doi:10.1002/2012WR013483 (2014). Sandia National Laboratories is a multiprogram laboratory operated by Sandia Corporation, a Lockheed Martin Company, for the United States Department of Energy's National Nuclear Security Administration under

  14. Waste Form Release Data Package for the 2005 Integrated Disposal Facility Performance Assessment. Erratum

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Smith, Gary L.

    2016-09-06

    This report refers to or contains K g values for glasses LAWA44, LAWB45 and LAWC22 affected by calculations errors as identified by Papathanassiu et al. (2011). The corrected K g values are reported in an erratum included in the revised version of the original report. The revised report can be referenced as follows: Pierce E. M. et al. (2004) Waste Form Release Data Package for the 2005 Integrated Disposal Facility Performance Assessment. PNNL-14805 Rev. 0 Erratum. Pacific Northwest National Laboratory, Richland, WA, USA.

  15. Deposition and thermal characterization of nano-structured aluminum nitride thin film on Cu-W substrate for high power light emitting diode package.

    PubMed

    Cho, Hyun Min; Kim, Min-Sun

    2014-08-01

    In this study, we developed AlN thick film on metal substrate for hybrid type LED package such as chip on board (COB) using metal printed circuit board (PCB). Conventional metal PCB uses ceramic-polymer composite as electrical insulating layer. Thermal conductivities of such type dielectric film are typically in the range of 1~4 W/m · K depending on the ceramic filler. Also, Al or Cu alloy are mainly used for metal base for high thermal conduction to dissipate heat from thermal source mounted on metal PCB. Here we used Cu-W alloy with low thermal expansion coefficient as metal substrate to reduce thermal stress between insulating layer and base metal. AlN with polyimide (PI) powder were used as starting materials for deposition. We could obtain very high thermal conductivity of 28.3 W/m · K from deposited AlN-PI thin film by AlN-3 wt% PI powder. We made hybrid type high power LED package using AlN-PI thin film. We tested thermal performance of this film by thermal transient measurement and compared with conventional metal PCB substrate.

  16. Thermal behaviour of ESP ash from municipal solid waste incinerators.

    PubMed

    Yang, Y; Xiao, Y; Wilson, N; Voncken, J H L

    2009-07-15

    Stricter environmental regulations demand safer treatment and disposal of incinerator fly ashes. So far no sound technology or a process is available for a sustainable and ecological treatment of the waste incineration ashes, and only partial treatment is practised for temporary and short-term solutions. New processes and technology need to be developed for comprehensive utilization and detoxification of the municipal solid waste (MSW) incinerator residues. To explore the efficiency of thermal stabilisation and controlled vitrification, the thermal behaviour of electrostatic precipitator (ESP) ash was investigated under controlled conditions. The reaction stages are identified with the initial moisture removal, volatilization, melting and slag formation. At the temperature higher than 1100 degrees C, the ESP ashes have a quicker weight loss, and the total weight loss reaches up to 52%, higher than the boiler ash. At 1400 degrees C a salt layer and a homogeneous glassy slag were formed. The effect of thermal treatment on the leaching characteristics of various elements in the ESP ash was evaluated with the availability-leaching test. The leaching values of the vitrified slag are significantly lowered than that of the original ash.

  17. Transient Thermal Response of Lightweight Cementitious Composites Made with Polyurethane Foam Waste

    NASA Astrophysics Data System (ADS)

    Kismi, M.; Poullain, P.; Mounanga, P.

    2012-07-01

    The development of low-cost lightweight aggregate (LWA) mortars and concretes presents many advantages, especially in terms of lightness and thermal insulation performances of structures. Low-cost LWA mainly comes from the recovery of vegetal or plastic wastes. This article focuses on the characterization of the thermal conductivity of innovative lightweight cementitious composites made with fine particles of rigid polyurethane (PU) foam waste. Five mortars were prepared with various mass substitution rates of cement with PU-foam particles. Their thermal conductivity was measured with two transient methods: the heating-film method and the hot-disk method. The incorporation of PU-foam particles causes a reduction of up to 18 % of the mortar density, accompanied by a significant improvement of the thermal insulating performance. The effect of segregation on the thermal properties of LWA mortars due to the differences of density among the cementitious matrix, sand, and LWA has also been quantified. The application of the hot-disk method reveals a gradient of thermal conductivity along the thickness of the specimens, which could be explained by a non-uniform repartition of fine PU-foam particles and mineral aggregates within the mortars. The results show a spatial variation of the thermal conductivity of the LWA mortars, ranging from 9 % to 19 %. However, this variation remains close to or even lower than that observed on a normal weight aggregate mortar. Finally, a self-consistent approach is proposed to estimate the thermal conductivity of PU-foam cement-based composites.

  18. Packaging for Posterity.

    ERIC Educational Resources Information Center

    Sias, Jim

    1990-01-01

    A project in which students designed environmentally responsible food packaging is described. The problem definition; research on topics such as waste paper, plastic, metal, glass, incineration, recycling, and consumer preferences; and the presentation design are provided. (KR)

  19. Carbon nanotubes for thermal interface materials in microelectronic packaging

    NASA Astrophysics Data System (ADS)

    Lin, Wei

    density was beneficial in increasing the collective thermal conductivity of the VACNT film; however, the increased tube-tube interaction in dense VACNT films decreased the thermal conductivity of the individual CNTs. The tip-to-tip contact resistance was shown to be ˜1x10-7 m2 K W -1. The study will shed light on the potential application of VACNTs as thermal interface materials in microelectronic packaging. 5. A combined process of in situ functionalization and microwave curing has been developed to effective enhance the interface between carbon nanotubes and the epoxy matrix. Effective medium theory has been used to analyze the interfacial thermal resistance between carbon nanotubes and polymer matrix, and that between graphite nanoplatlets and polymer matrix.

  20. A review of technologies and performances of thermal treatment systems for energy recovery from waste

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Lombardi, Lidia, E-mail: lidia.lombardi@unicusano.it; Carnevale, Ennio; Corti, Andrea

    2015-03-15

    Highlights: • The topic of energy recovery from waste by thermal treatment is reviewed. • Combustion, gasification and pyrolysis were considered. • Data about energy recovery performances were collected and compared. • Main limitations to high values of energy performances were illustrated. • Diffusion of energy recovery from waste in EU, USA and other countries was discussed. - Abstract: The aim of this work is to identify the current level of energy recovery through waste thermal treatment. The state of the art in energy recovery from waste was investigated, highlighting the differences for different types of thermal treatment, considering combustion/incineration,more » gasification and pyrolysis. Also different types of wastes – Municipal Solid Waste (MSW), Refuse Derived Fuel (RDF) or Solid Refuse Fuels (SRF) and some typologies of Industrial Waste (IW) (sludge, plastic scraps, etc.) – were included in the analysis. The investigation was carried out mainly reviewing papers, published in scientific journals and conferences, but also considering technical reports, to gather more information. In particular the goal of this review work was to synthesize studies in order to compare the values of energy conversion efficiencies measured or calculated for different types of thermal processes and different types of waste. It emerged that the dominant type of thermal treatment is incineration associated to energy recovery in a steam cycle. When waste gasification is applied, the produced syngas is generally combusted in a boiler to generate steam for energy recovery in a steam cycle. For both the possibilities – incineration or gasification – cogeneration is the mean to improve energy recovery, especially for small scale plants. In the case of only electricity production, the achievable values are strongly dependent on the plant size: for large plant size, where advanced technical solutions can be applied and sustained from an economic point of

  1. Assessment of two thermally treated drill mud wastes for landfill containment applications.

    PubMed

    Carignan, Marie-Pierre; Lake, Craig B; Menzies, Todd

    2007-10-01

    Offshore oil and gas drilling operations generate significant amounts of drill mud waste, some of which is transported onshore for subsequent thermal treatment (i.e. via thermal remediation). This treatment process results in a mineral waste by-product (referred to as thermally treated drill mud waste; TTDMW). Bentonites are originally present in many of the drill mud products and it is hypothesized that TTDMW can be utilized in landfill containment applications (i.e. cover or base liner). The objective of this paper is to examine the feasibility of this application by performing various physical and chemical tests on two TTDMW samples. It is shown that the two TTDMW samples contained relatively small amounts of clay-sized minerals although hydraulic conductivity values are found to be less than 10(-8) m/s. Organic carbon contents of the samples were approximately 2%. Mineralogy characterization of the samples confirmed varying amounts of smectite, however, peak friction angles for a TTDMW sample was greater than 36 degrees. Chemical characterization of the TTDMW samples show potential leaching of barium and small amounts of other heavy metals. Discussion is provided in the paper on suggestions to assist in overcoming regulatory issues associated with utilization of TTDMW in landfill containment applications.

  2. Formation of PCDD and PCDF in the thermal treatment of footwear leather wastes.

    PubMed

    Godinho, Marcelo; Marcilio, Nilson Romeu; Masotti, Leonardo; Martins, Celso Brisolara; Ritter, Diego Elias; Wenzel, Bruno München

    2009-08-15

    The leather waste generated by the footwear industry is considered dangerous due to the presence of trivalent chromium, derived from the salt utilized to tan hides. In Brazil, the majority of this waste is disposed on landfills and only about 3% are recycled. The thermal treatment is an alternative method for purification of such residues. By using this technique it is possible to generate energy and recover the chromium present in the ash for the production of basic chromium sulfate (tanning industry), high carbon ferrochromium or carbon-free ferrochromium (steel industry). In the last 10 years, the gasification and combustion of footwear leather waste have been intensively studied at the Federal University of Rio Grande do Sul. The research experiment for characterization of the emissions of polychlorinated dibenzo-p-dioxins and dibenzofurans (PCDD/F) were carried out in a semi-pilot unit (350 kW(th)). From new investments the thermal capacity of the unit will increase to 600 kW(th). The unit will produce power from the heat generated in the combustion. The experimental results indicated that during the thermal treatment of footwear leather wastes, the formation mechanism of PCDD/F is the de novo synthesis. Most of PCDD/F were found in the particulate phase (>95%). A kinetic model was used for discussion of the achieved experimental results. The model is based in the carbon gasification, PCDD/F formation, desorption and degradation. From the conclusions obtained in this work will be possible minimize the PCDD/F formation in process of combustion of footwear leather wastes.

  3. Analysis of the energy potential of municipal solid waste for the thermal treatment technology development in Poland

    NASA Astrophysics Data System (ADS)

    Midor, Katarzyna; Jąderko, Karolina

    2017-11-01

    The problem of overproduction of waste has been a local issue for many years. Since the new environment law came into effect, the current approach to waste management has changed significantly. The accessible technological possibilities of thermal waste treatment with the energy recovery set a new area of research over the process of choosing effective and rational way of calorific waste management. The objective of this article is to provide assessment results of the analysed energy potential in waste management system in the form of calorific waste stream. In includes all the activities and actions required to manage municipal solid waste from its inception to its final disposal i.e. collection, transport, treatment and disposal. The graphical representation of waste flow indicates the lost opportunities of waste energy recovery. Visual research method was supported and founded on value stream mapping. On the basis of the results were presented the directions of further improvement of calorific waste stream mapping for the purposes of implementation the thermal treatment technology in the selected waste management region.

  4. PBDEs emission from waste printed wiring boards during thermal process.

    PubMed

    Guo, Jie; Zhang, Ran; Xu, Zhenming

    2015-03-03

    Polybrominated diphenyl ethers (PBDEs) contained in waste printed wiring board (PWB) matrix and surface dust can be emitted into the air during thermal process, which is widely used to detach the electronic components from the base boards of waste PWB. In this study, PBDEs concentrations in air and dust samples were detected in a PWB-heating workshop, and then heating experiments of PBDEs-containing materials in a quartz tube furnace were performed to investigate the PBDEs emission mechanism. The results showed that the mean concentrations of Σ8PBDEs in PM10 and TSP were 479 and 1670 ng/m(3), respectively. Compared with surface dust collected from waste PWB (15600 ng/g), PBDEs concentrations in dust from the workshop floor (31,100 ng/g), heating machine inside (84,700 ng/g), and the cyclone extractor (317,000 ng/g), were condensed after thermal process. Heating experiments showed that the emission rates of PBDEs from PBDEs-containing dust were obviously higher than those from PWB fragments in the first 1-h time. The cumulative amounts of PBDEs emitted from dust increased rapidly at first, and then leveled off to become asymptotic to the maximum amounts. At the temperature of 300 °C, the PBDEs emission from dust mainly occurred within the first 5 min, and the average emission rates for BDE-28, -47, and -99 among the first 5 min were 1230, 4480, and 1950 ng/(g·min), respectively. During the initial 1-h period, the trends of PBDEs emission from PWB fragments had a linear increase, and the emission rates of penta-BDE (BDE-47, -99, -100) at different temperatures were at a range of 9.75-11.5 ng/(g·min). All the results showed that PBDEs emission from PWB waste happened during thermal process, and management strategies were provided to reduce the occupational exposure level of PBDEs for workers.

  5. Thermal hydrolysis (TDH) as a pretreatment method for the digestion of organic waste.

    PubMed

    Schieder, D; Schneider, R; Bischof, F

    2000-01-01

    The recycling concept under consideration is based on the process of Thermal Hydrolysis (TDH) followed by an anaerobic digestion. By increasing pressure and temperature the organic part of the waste is split up in a first step into short-chain fragments that are biologically well suited for microorganisms. The following fermentation runs much faster and more complete than in conventional digestion processes and the biogas yield is increased. Left is just a small amount of a solid residue that can be easily dewatered and utilized as surrogate fuel for incineration or as compost additive. The thermal hydrolysis process allows a complete energy recovery from organic waste. During the total procedure more energy sources are produced than are needed for running the plant. The procedure is especially suited for wet organic waste and biosolids that are difficult to compost, such as food scraps, biological waste from compact residential areas and sewage sludge. As a complete disinfection is granted due to the process temperatures the procedure is also suited for carcasses.

  6. Investigation of potential waste material insulating properties at different temperature for thermal storage application

    NASA Astrophysics Data System (ADS)

    Ali, T. Z. S.; Rosli, A. B.; Gan, L. M.; Billy, A. S.; Farid, Z.

    2013-12-01

    Thermal energy storage system (TES) is developed to extend the operation of power generation. TES system is a key component in a solar energy power generation plant, but the main issue in designing the TES system is its thermal capacity of storage materials, e.g. insulator. This study is focusing on the potential waste material acts as an insulator for thermal energy storage applications. As the insulator is used to absorb heat, it is needed to find suitable material for energy conversion and at the same time reduce the waste generation. Thus, a small-scale experimental testing of natural cooling process of an insulated tank within a confined room is conducted. The experiment is repeated by changing the insulator from the potential waste material and also by changing the heat transfer fluid (HTF). The analysis presented the relationship between heat loss and the reserved period by the insulator. The results show the percentage of period of the insulated tank withstands compared to tank insulated by foam, e.g. newspaper reserved the period of 84.6% as much as foam insulated tank to withstand the heat transfer of cooking oil to the surrounding. The paper finally justifies the most potential waste material as an insulator for different temperature range of heat transfer fluid.

  7. Processed milk waste recycling via thermal pretreatment and lactic acid bacteria fermentation.

    PubMed

    Kasmi, Mariam; Hamdi, Moktar; Trabelsi, Ismail

    2017-05-01

    Processed milk waste (MW) presents a serious problem within the dairy industries due to its high polluting load. Its chemical oxygen demand (COD) can reach values as high as 80,000 mg O 2  L -1 . This study proposes to reduce the organic load of those wastes using thermal coagulation and recover residual valuable components via fermentation. Thermal process results showed that the COD removal rates exceeded 40% when samples were treated at temperature above 60 °C to reach 72% at 100 °C. Clarified supernatants resulting from thermal treatment of the samples at the temperatures of 60 (MW 60 ), 80 (MW 80 ), and 100 °C (MW 100 ) were fermented using lactic acid bacteria strains without pH control. Lactic strains recorded important final cell yields (5-7 g L -1 ). Growth mediums prepared using the thermally treated MW produced 73% of the bacterial biomass recorded with a conventional culture medium. At the end of fermentation, mediums were found exhausted from several valuable components. Industrial scale implementation of the proposed process for the recycling of industrial MWs is described and discussed.

  8. A case study of packaging waste collection systems in Portugal - Part I: Performance and operation analysis.

    PubMed

    Martinho, Graça; Gomes, Ana; Santos, Pedro; Ramos, Mário; Cardoso, João; Silveira, Ana; Pires, Ana

    2017-03-01

    The need to increase packaging recycling rates has led to the study and analysis of recycling schemes from various perspectives, including technical, economic, social, and environmental. This paper is part one of a three-part study devoted to comparing two recyclable packaging waste collection systems operating in western Portugal: a mixed collection system, where curbside and drop-off collections are operated simultaneously (but where the curbside system was introduced after the drop-off system), and an exclusive drop-off system. This part of the study focuses on analyzing the operation and performance of the two waste collection systems. The mixed collection system is shown to yield higher material separation rates, higher recycling rates, and lower contamination rates compared with the exclusive drop-off system, a result of the curbside component in the former system. However, the operational efficiency of the curbside collection in the mixed system is lower than the drop-off collection in the mixed system and the exclusive drop-off system, mainly because of inefficiency of collection. A key recommendation is to ensure that the systems should be optimized in an attempt to improve performance. Optimization should be applied not only to logistical aspects but also to citizens' participation, which could be improved by conducting curbside collection awareness campaigns in the neighborhoods that have a mixed system. Copyright © 2017 Elsevier Ltd. All rights reserved.

  9. Utilization of chemically treated municipal solid waste (spent coffee bean powder) as reinforcement in cellulose matrix for packaging applications.

    PubMed

    Thiagamani, Senthil Muthu Kumar; Nagarajan, Rajini; Jawaid, Mohammad; Anumakonda, Varadarajulu; Siengchin, Suchart

    2017-11-01

    As the annual production of the solid waste generable in the form of spent coffee bean powder (SCBP) is over 6 million tons, its utilization in the generation of green energy, waste water treatment and as a filler in biocomposites is desirable. The objective of this article is to analyze the possibilities to valorize coffee bean powder as a filler in cellulose matrix. Cellulose matrix was dissolved in the relatively safer aqueous solution mixture (8% LiOH and 15% Urea) precooled to -12.5°C. To the cellulose solution (SCBP) was added in 5-25wt% and the composite films were prepared by regeneration method using ethyl alcohol as a coagulant. Some SCBP was treated with aq. 5% NaOH and the composite films were also prepared using alkali treated SCBP as a filler. The films of composites were uniform with brown in color. The cellulose/SCBP films without and with alkali treated SCBP were characterized by FTIR, XRD, optical and polarized optical microscopy, thermogravimetric analysis (TGA) and tensile tests. The maximum tensile strength of the composite films with alkali treated SCBP varied between (106-149MPa) and increased with SCBP content when compared to the composites with untreated SCBP. The thermal stability of the composite was higher at elevated temperatures when alkali treated SCBP was used. Based on the improved tensile properties and photo resistivity, the cellulose/SCBP composite films with alkali treated SCBP may be considered for packaging and wrapping of flowers and vegetables. Copyright © 2017 Elsevier Ltd. All rights reserved.

  10. An Overview of Opportunities for Waste Heat Recovery and Thermal Integration in the Primary Aluminum Industry

    NASA Astrophysics Data System (ADS)

    Nowicki, Cassandre; Gosselin, Louis

    2012-08-01

    Efficient smelters currently consume roughly 13 MWh of electricity per ton of aluminum, while roughly half of that energy is lost as thermal waste. Although waste heat is abundant, current thermal integration in primary aluminum facilities remains limited. This is due to both the low quality of waste heat available and the shortage of potential uses within reasonable distance of identified waste heat sources. In this article, we present a mapping of both heat dissipation processes and heat demands around a sample facility (Alcoa Deschambault Quebec smelter). Our primary aim is to report opportunities for heat recovery and integration in the primary aluminum industry. We consider potential heat-to-sink pairings individually and assess their thermodynamic potential for producing energy savings.

  11. Performance Assessments of Generic Nuclear Waste Repositories in Shale

    NASA Astrophysics Data System (ADS)

    Stein, E. R.; Sevougian, S. D.; Mariner, P. E.; Hammond, G. E.; Frederick, J.

    2017-12-01

    Simulations of deep geologic disposal of nuclear waste in a generic shale formation showcase Geologic Disposal Safety Assessment (GDSA) Framework, a toolkit for repository performance assessment (PA) whose capabilities include domain discretization (Cubit), multiphysics simulations (PFLOTRAN), uncertainty and sensitivity analysis (Dakota), and visualization (Paraview). GDSA Framework is used to conduct PAs of two generic repositories in shale. The first considers the disposal of 22,000 metric tons heavy metal of commercial spent nuclear fuel. The second considers disposal of defense-related spent nuclear fuel and high level waste. Each PA accounts for the thermal load and radionuclide inventory of applicable waste types, components of the engineered barrier system, and components of the natural barrier system including the host rock shale and underlying and overlying stratigraphic units. Model domains are half-symmetry, gridded with Cubit, and contain between 7 and 22 million grid cells. Grid refinement captures the detail of individual waste packages, emplacement drifts, access drifts, and shafts. Simulations are run in a high performance computing environment on as many as 2048 processes. Equations describing coupled heat and fluid flow and reactive transport are solved with PFLOTRAN, an open-source, massively parallel multiphase flow and reactive transport code. Additional simulated processes include waste package degradation, waste form dissolution, radioactive decay and ingrowth, sorption, solubility, advection, dispersion, and diffusion. Simulations are run to 106 y, and radionuclide concentrations are observed within aquifers at a point approximately 5 km downgradient of the repository. Dakota is used to sample likely ranges of input parameters including waste form and waste package degradation rates and properties of engineered and natural materials to quantify uncertainty in predicted concentrations and sensitivity to input parameters. Sandia National

  12. High-temperature thermal destruction of poultry derived wastes for energy recovery in Australia.

    PubMed

    Florin, N H; Maddocks, A R; Wood, S; Harris, A T

    2009-04-01

    The high-temperature thermal destruction of poultry derived wastes (e.g., manure and bedding) for energy recovery is viable in Australia when considering resource availability and equivalent commercial-scale experience in the UK. In this work, we identified and examined the opportunities and risks associated with common thermal destruction techniques, including: volume of waste, costs, technological risks and environmental impacts. Typical poultry waste streams were characterised based on compositional analysis, thermodynamic equilibrium modelling and non-isothermal thermogravimetric analysis coupled with mass spectrometry (TG-MS). Poultry waste is highly variable but otherwise comparable with other biomass fuels. The major technical and operating challenges are associated with this variability in terms of: moisture content, presence of inorganic species and type of litter. This variability is subject to a range of parameters including: type and age of bird, and geographical and seasonal inconsistencies. There are environmental and health considerations associated with combustion and gasification due to the formation of: NO(X), SO(X), H(2)S and HCl gas. Mitigation of these emissions is achievable through correct plant design and operation, however, with significant economic penalty. Based on our analysis and literature data, we present cost estimates for generic poultry-waste-fired power plants with throughputs of 2 and 8 tonnes/h.

  13. Evaluating laser-driven Bremsstrahlung radiation sources for imaging and analysis of nuclear waste packages.

    PubMed

    Jones, Christopher P; Brenner, Ceri M; Stitt, Camilla A; Armstrong, Chris; Rusby, Dean R; Mirfayzi, Seyed R; Wilson, Lucy A; Alejo, Aarón; Ahmed, Hamad; Allott, Ric; Butler, Nicholas M H; Clarke, Robert J; Haddock, David; Hernandez-Gomez, Cristina; Higginson, Adam; Murphy, Christopher; Notley, Margaret; Paraskevoulakos, Charilaos; Jowsey, John; McKenna, Paul; Neely, David; Kar, Satya; Scott, Thomas B

    2016-11-15

    A small scale sample nuclear waste package, consisting of a 28mm diameter uranium penny encased in grout, was imaged by absorption contrast radiography using a single pulse exposure from an X-ray source driven by a high-power laser. The Vulcan laser was used to deliver a focused pulse of photons to a tantalum foil, in order to generate a bright burst of highly penetrating X-rays (with energy >500keV), with a source size of <0.5mm. BAS-TR and BAS-SR image plates were used for image capture, alongside a newly developed Thalium doped Caesium Iodide scintillator-based detector coupled to CCD chips. The uranium penny was clearly resolved to sub-mm accuracy over a 30cm(2) scan area from a single shot acquisition. In addition, neutron generation was demonstrated in situ with the X-ray beam, with a single shot, thus demonstrating the potential for multi-modal criticality testing of waste materials. This feasibility study successfully demonstrated non-destructive radiography of encapsulated, high density, nuclear material. With recent developments of high-power laser systems, to 10Hz operation, a laser-driven multi-modal beamline for waste monitoring applications is envisioned. Copyright © 2016. Published by Elsevier B.V.

  14. A review of technologies and performances of thermal treatment systems for energy recovery from waste.

    PubMed

    Lombardi, Lidia; Carnevale, Ennio; Corti, Andrea

    2015-03-01

    The aim of this work is to identify the current level of energy recovery through waste thermal treatment. The state of the art in energy recovery from waste was investigated, highlighting the differences for different types of thermal treatment, considering combustion/incineration, gasification and pyrolysis. Also different types of wastes - Municipal Solid Waste (MSW), Refuse Derived Fuel (RDF) or Solid Refuse Fuels (SRF) and some typologies of Industrial Waste (IW) (sludge, plastic scraps, etc.) - were included in the analysis. The investigation was carried out mainly reviewing papers, published in scientific journals and conferences, but also considering technical reports, to gather more information. In particular the goal of this review work was to synthesize studies in order to compare the values of energy conversion efficiencies measured or calculated for different types of thermal processes and different types of waste. It emerged that the dominant type of thermal treatment is incineration associated to energy recovery in a steam cycle. When waste gasification is applied, the produced syngas is generally combusted in a boiler to generate steam for energy recovery in a steam cycle. For both the possibilities--incineration or gasification--co-generation is the mean to improve energy recovery, especially for small scale plants. In the case of only electricity production, the achievable values are strongly dependent on the plant size: for large plant size, where advanced technical solutions can be applied and sustained from an economic point of view, net electric efficiency may reach values up to 30-31%. In small-medium plants, net electric efficiency is constrained by scale effect and remains at values around 20-24%. Other types of technical solutions--gasification with syngas use in internally fired devices, pyrolysis and plasma gasification--are less common or studied at pilot or demonstrative scale and, in any case, offer at present similar or lower levels

  15. Robust, Rework-able Thermal Electronic Packaging: Applications in High Power TR Modules for Space

    NASA Technical Reports Server (NTRS)

    Hoffman, James Patrick; Del Castillo, Linda; Hunter, Don; Miller, Jennifer

    2012-01-01

    The higher output power densities required of modern radar architectures, such as the proposed DESDynI [Deformation, Ecosystem Structure, and Dynamics of Ice] SAR [Synthetic Aperture Radar] Instrument (or DSI) require increasingly dense high power electronics. To enable these higher power densities, while maintaining or even improving hardware reliability, requires improvements in integrating advanced thermal packaging technologies into radar transmit/receive (TR) modules. New materials and techniques have been studied and are now being implemented side-by-side with more standard technology typically used in flight hardware.

  16. Reduction of carbon content in waste-tire combustion ashes by bio-thermal treatment.

    PubMed

    Chen, Chun-Chi; Lee, Wen-Jhy; Shih, Shun-I; Mou, Jin-Luh

    2009-11-01

    Application of bio-catalyst (NOE-7F) in thermal treatment can adequately dispose dark-black fly ashes from co-combustion of both waste tires and coal. After thermal treatment of fly ashes by adding 10% NOE-7F, the carbon contents reduced by 37.6% and the weight losses increased by 405%, compared with the fly ashes without mixing with NOE-7F. The combustion behaviors of wasted tires combustion fly ashes with NOE-7F were also investigated by both thermogravimetric analysis (TGA) and differential thermal analysis (DTA). The results verify that NOE-7F has positive effects on the combustion of residual carbon and toxic polycyclic aromatic hydrocarbons (PAHs) enhance the energy release and reduce the toxicity during the process of thermal treatment. Furthermore, using NOE-7F to dispose high-carbon content fly ashes did improve the compressive strength of fly ashes and concrete mixtures. Therefore, NOE-7F is a promising additive which could decrease treatment cost of high-carbon content fly ashes and reduce the amount of survival toxic PAHs.

  17. Reduction of carbon content in waste-tire combustion ashes by bio-thermal treatment

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Chen, C.C.; Lee, W.J.; Shih, S.I.

    2009-07-01

    Application of bio-catalyst (NOE-7F) in thermal treatment can adequately dispose dark-black fly ashes from co-combustion of both waste tires and coal. After thermal treatment of fly ashes by adding 10% NOE-7F, the carbon contents reduced by 37.6% and the weight losses increased by 405%, compared with the fly ashes without mixing with NOE-7F. The combustion behaviors of wasted tires combustion fly ashes with NOE-7F were also investigated by both thermogravimetric analysis (TGA) and differential thermal analysis (DTA). The results verify that NOE-7F has positive effects on the combustion of residual carbon and toxic polycyclic aromatic hydrocarbons (PAHs) enhance the energymore » release and reduce the toxicity during the process of thermal treatment. Furthermore, using NOE-7F to dispose high-carbon content fly ashes did improve the compressive strength of fly ashes and concrete mixtures. Therefore, NOE-7F is a promising additive which could decrease treatment cost of high-carbon content fly ashes and reduce the amount of survival toxic PAHs.« less

  18. Enhanced thermaly managed packaging for III-nitride light emitters

    NASA Astrophysics Data System (ADS)

    Kudsieh, Nicolas

    In this Dissertation our work on `enhanced thermally managed packaging of high power semiconductor light sources for solid state lighting (SSL)' is presented. The motivation of this research and development is to design thermally high stable cost-efficient packaging of single and multi-chip arrays of III-nitrides wide bandgap semiconductor light sources through mathematical modeling and simulations. Major issues linked with this technology are device overheating which causes serious degradation in their illumination intensity and decrease in the lifetime. In the introduction the basics of III-nitrides WBG semiconductor light emitters are presented along with necessary thermal management of high power cingulated and multi-chip LEDs and laser diodes. This work starts at chip level followed by its extension to fully packaged lighting modules and devices. Different III-nitride structures of multi-quantum well InGaN/GaN and AlGaN/GaN based LEDs and LDs were analyzed using advanced modeling and simulation for different packaging designs and high thermal conductivity materials. Study started with basic surface mounted devices using conventional packaging strategies and was concluded with the latest thermal management of chip-on-plate (COP) method. Newly discovered high thermal conductivity materials have also been incorporated for this work. Our study also presents the new approach of 2D heat spreaders using such materials for SSL and micro LED array packaging. Most of the work has been presented in international conferences proceedings and peer review journals. Some of the latest work has also been submitted to well reputed international journals which are currently been reviewed for publication. .

  19. Excess Weapons Plutonium Disposition: Plutonium Packaging, Storage and Transportation and Waste Treatment, Storage and Disposal Activities

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Jardine, L J; Borisov, G B

    2004-07-21

    A fifth annual Excess Weapons Plutonium Disposition meeting organized by Lawrence Livermore National Laboratory (LLNL) was held February 16-18, 2004, at the State Education Center (SEC), 4 Aerodromnya Drive, St. Petersburg, Russia. The meeting discussed Excess Weapons Plutonium Disposition topics for which LLNL has the US Technical Lead Organization responsibilities. The technical areas discussed included Radioactive Waste Treatment, Storage, and Disposal, Plutonium Oxide and Plutonium Metal Packaging, Storage and Transportation and Spent Fuel Packaging, Storage and Transportation. The meeting was conducted with a conference format using technical presentations of papers with simultaneous translation into English and Russian. There were 46more » Russian attendees from 14 different Russian organizations and six non-Russian attendees, four from the US and two from France. Forty technical presentations were made. The meeting agenda is given in Appendix B and the attendance list is in Appendix C.« less

  20. Solid Waste Reduction--A Hands-on Study.

    ERIC Educational Resources Information Center

    Wiessinger, Diane

    1991-01-01

    This lesson plan uses grocery shopping to demonstrate the importance of source reduction in the handling of solid waste problems. Students consider different priorities in shopping (convenience, packaging, and waste reduction) and draw conclusions about the relationship between packaging techniques and solid waste problems. (MCO)

  1. SITE GENERATED RADIOLOGICAL WASTE HANDLING SYSTEM DESCRIPTION DOCUMENT

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    S. C. Khamankar

    2000-06-20

    The Site Generated Radiological Waste Handling System handles radioactive waste products that are generated at the geologic repository operations area. The waste is collected, treated if required, packaged for shipment, and shipped to a disposal site. Waste streams include low-level waste (LLW) in solid and liquid forms, as-well-as mixed waste that contains hazardous and radioactive constituents. Liquid LLW is segregated into two streams, non-recyclable and recyclable. The non-recyclable stream may contain detergents or other non-hazardous cleaning agents and is packaged for shipment. The recyclable stream is treated to recycle a large portion of the water while the remaining concentrated wastemore » is packaged for shipment; this greatly reduces the volume of waste requiring disposal. There will be no liquid LLW discharge. Solid LLW consists of wet solids such as ion exchange resins and filter cartridges, as-well-as dry active waste such as tools, protective clothing, and poly bags. Solids will be sorted, volume reduced, and packaged for shipment. The generation of mixed waste at the Monitored Geologic Repository (MGR) is not planned; however, if it does come into existence, it will be collected and packaged for disposal at its point of occurrence, temporarily staged, then shipped to government-approved off-site facilities for disposal. The Site Generated Radiological Waste Handling System has equipment located in both the Waste Treatment Building (WTB) and in the Waste Handling Building (WHB). All types of liquid and solid LLW are processed in the WTB, while wet solid waste from the Pool Water Treatment and Cooling System is packaged where received in the WHB. There is no installed hardware for mixed waste. The Site Generated Radiological Waste Handling System receives waste from locations where water is used for decontamination functions. In most cases the water is piped back to the WTB for processing. The WTB and WHB provide staging areas for storing and

  2. Optimal segmentation and packaging process

    DOEpatents

    Kostelnik, Kevin M.; Meservey, Richard H.; Landon, Mark D.

    1999-01-01

    A process for improving packaging efficiency uses three dimensional, computer simulated models with various optimization algorithms to determine the optimal segmentation process and packaging configurations based on constraints including container limitations. The present invention is applied to a process for decontaminating, decommissioning (D&D), and remediating a nuclear facility involving the segmentation and packaging of contaminated items in waste containers in order to minimize the number of cuts, maximize packaging density, and reduce worker radiation exposure. A three-dimensional, computer simulated, facility model of the contaminated items are created. The contaminated items are differentiated. The optimal location, orientation and sequence of the segmentation and packaging of the contaminated items is determined using the simulated model, the algorithms, and various constraints including container limitations. The cut locations and orientations are transposed to the simulated model. The contaminated items are actually segmented and packaged. The segmentation and packaging may be simulated beforehand. In addition, the contaminated items may be cataloged and recorded.

  3. Optimal segmentation and packaging process

    DOEpatents

    Kostelnik, K.M.; Meservey, R.H.; Landon, M.D.

    1999-08-10

    A process for improving packaging efficiency uses three dimensional, computer simulated models with various optimization algorithms to determine the optimal segmentation process and packaging configurations based on constraints including container limitations. The present invention is applied to a process for decontaminating, decommissioning (D and D), and remediating a nuclear facility involving the segmentation and packaging of contaminated items in waste containers in order to minimize the number of cuts, maximize packaging density, and reduce worker radiation exposure. A three-dimensional, computer simulated, facility model of the contaminated items are created. The contaminated items are differentiated. The optimal location, orientation and sequence of the segmentation and packaging of the contaminated items is determined using the simulated model, the algorithms, and various constraints including container limitations. The cut locations and orientations are transposed to the simulated model. The contaminated items are actually segmented and packaged. The segmentation and packaging may be simulated beforehand. In addition, the contaminated items may be cataloged and recorded. 3 figs.

  4. Thermal treatment of medical waste in a rotary kiln.

    PubMed

    Bujak, J

    2015-10-01

    This paper presents the results of a study of an experimental system with thermal treatment (incineration) of medical waste conducted at a large complex of hospital facilities. The studies were conducted for a period of one month. The processing system was analysed in terms of the energy, environmental and economic aspects. A rotary combustion chamber was designed and built with the strictly assumed length to inner diameter ratio of 4:1. In terms of energy, the temperature distribution was tested in the rotary kiln, secondary combustion (afterburner) chamber and heat recovery system. Calorific value of medical waste was 25.0 MJ/kg and the thermal efficiency of the entire system equalled 66.8%. Next, measurements of the pollutant emissions into the atmosphere were performed. Due to the nature of the disposed waste, particular attention was paid to the one-minute average values of carbon oxide and volatile organic compounds as well as hydrochloride, hydrogen fluoride, sulphur dioxide and total dust. Maximum content of non-oxidized organic compounds in slag and bottom ash were also verified during the analyses. The best rotary speed for the combustion chamber was selected to obtain proper afterburning of the bottom slag. Total organic carbon content was 2.9%. The test results were used to determine the basic economic indicators of the test system for evaluating the profitability of its construction. Simple payback time (SPB) for capital expenditures on the implementation of the project was 4 years. Copyright © 2015 Elsevier Ltd. All rights reserved.

  5. Thermal stress control using waste steel fibers in massive concretes

    NASA Astrophysics Data System (ADS)

    Sarabi, Sahar; Bakhshi, Hossein; Sarkardeh, Hamed; Nikoo, Hamed Safaye

    2017-11-01

    One of the important subjects in massive concrete structures is the control of the generated heat of hydration and consequently the potential of cracking due to the thermal stress expansion. In the present study, using the waste turnery steel fibers in the massive concretes, the amount of used cement was reduced without changing the compressive strength. By substituting a part of the cement with waste steel fibers, the costs and the generated hydration heat were reduced and the tensile strength was increased. The results showed that by using 0.5% turnery waste steel fibers and consequently, reducing to 32% the cement content, the hydration heat reduced to 23.4% without changing the compressive strength. Moreover, the maximum heat gradient reduced from 18.5% in the plain concrete sample to 12% in the fiber-reinforced concrete sample.

  6. Mercury recovery from mercury-containing wastes using a vacuum thermal desorption system.

    PubMed

    Lee, Woo Rim; Eom, Yujin; Lee, Tai Gyu

    2017-02-01

    Mercury (Hg)-containing waste from various industrial facilities is commonly treated by incineration or stabilization/solidification and retained in a landfill at a managed site. However, when highly concentrated Hg waste is treated using these methods, Hg is released into the atmosphere and soil environment. To eliminate these risks, Hg recovery technology using thermal treatment has been developed and commercialized to recover Hg from Hg-containing waste for safe disposal. Therefore, we developed Hg recovery equipment to treat Hg-containing waste under a vacuum of 6.67kPa (abs) at 400°C and recover the Hg. In addition, the dust generated from the waste was separated by controlling the temperature of the dust filtration unit to 230°C. Additionally, water and Hg vapors were condensed in a condensation unit. The Hg removal rate after waste treatment was 96.75%, and the Hg recovery rate as elemental Hg was 75.23%. Copyright © 2016 Elsevier Ltd. All rights reserved.

  7. DESIGN ANALYSIS FOR THE DEFENSE HIGH-LEVEL WASTE DISPOSAL CONTAINER

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    G. Radulesscu; J.S. Tang

    The purpose of ''Design Analysis for the Defense High-Level Waste Disposal Container'' analysis is to technically define the defense high-level waste (DHLW) disposal container/waste package using the Waste Package Department's (WPD) design methods, as documented in ''Waste Package Design Methodology Report'' (CRWMS M&O [Civilian Radioactive Waste Management System Management and Operating Contractor] 2000a). The DHLW disposal container is intended for disposal of commercial high-level waste (HLW) and DHLW (including immobilized plutonium waste forms), placed within disposable canisters. The U.S. Department of Energy (DOE)-managed spent nuclear fuel (SNF) in disposable canisters may also be placed in a DHLW disposal container alongmore » with HLW forms. The objective of this analysis is to demonstrate that the DHLW disposal container/waste package satisfies the project requirements, as embodied in Defense High Level Waste Disposal Container System Description Document (SDD) (CRWMS M&O 1999a), and additional criteria, as identified in Waste Package Design Sensitivity Report (CRWMS M&Q 2000b, Table 4). The analysis briefly describes the analytical methods appropriate for the design of the DHLW disposal contained waste package, and summarizes the results of the calculations that illustrate the analytical methods. However, the analysis is limited to the calculations selected for the DHLW disposal container in support of the Site Recommendation (SR) (CRWMS M&O 2000b, Section 7). The scope of this analysis is restricted to the design of the codisposal waste package of the Savannah River Site (SRS) DHLW glass canisters and the Training, Research, Isotopes General Atomics (TRIGA) SNF loaded in a short 18-in.-outer diameter (OD) DOE standardized SNF canister. This waste package is representative of the waste packages that consist of the DHLW disposal container, the DHLW/HLW glass canisters, and the DOE-managed SNF in disposable canisters. The intended use of this analysis

  8. Waste Handling and Emplacement Options for Disposal of Radioactive Waste in Deep Boreholes.

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Cochran, John R.; Hardin, Ernest

    2015-11-01

    Traditional methods cannot be used to handle and emplace radioactive wastes in boreholes up to 16,400 feet (5 km) deep for disposal. This paper describes three systems that can be used for handling and emplacing waste packages in deep borehole: (1) a 2011 reference design that is based on a previous study by Woodward–Clyde in 1983 in which waste packages are assembled into “strings” and lowered using drill pipe; (2) an updated version of the 2011 reference design; and (3) a new concept in which individual waste packages would be lowered to depth using a wireline. Emplacement on coiled tubingmore » was also considered, but not developed in detail. The systems described here are currently designed for U.S. Department of Energy-owned high-level waste (HLW) including the Cesium- 137/Strontium-90 capsules from the Hanford Facility and bulk granular HLW from fuel processing in Idaho.« less

  9. A testing program to evaluate the effects of simulant mixed wastes on plastic transportation packaging components

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Nigrey, P.J.; Dickens, T.G.; Dickman, P.T.

    1997-08-01

    Based on regulatory requirements for Type A and B radioactive material packaging, a Testing Program was developed to evaluate the effects of mixed wastes on plastic materials which could be used as liners and seals in transportation containers. The plastics evaluated in this program were butadiene-acrylonitrile copolymer (Nitrile rubber), cross-linked polyethylene, epichlorohydrin, ethylene-propylene rubber (EPDM), fluorocarbons, high-density polyethylene (HDPE), butyl rubber, polypropylene, polytetrafluoroethylene, and styrene-butadiene rubber (SBR). These plastics were first screened in four simulant mixed wastes. The liner materials were screened using specific gravity measurements and seal materials by vapor transport rate (VTR) measurements. For the screening of linermore » materials, Kel-F, HDPE, and XLPE were found to offer the greatest resistance to the combination of radiation and chemicals. The tests also indicated that while all seal materials passed exposure to the aqueous simulant mixed waste, EPDM and SBR had the lowest VTRs. In the chlorinated hydrocarbon simulant mixed waste, only Viton passed the screening tests. In both the simulant scintillation fluid mixed waste and the ketone mixture waste, none of the seal materials met the screening criteria. Those materials which passed the screening tests were subjected to further comprehensive testing in each of the simulant wastes. The materials were exposed to four different radiation doses followed by exposure to a simulant mixed waste at three temperatures and four different exposure times (7, 14, 28, 180 days). Materials were tested by measuring specific gravity, dimensional, hardness, stress cracking, VTR, compression set, and tensile properties. The second phase of this Testing Program involving the comprehensive testing of plastic liner has been completed and for seal materials is currently in progress.« less

  10. Economic aspects of thermal treatment of solid waste in a sustainable WM system

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Massarutto, Antonio

    2015-03-15

    Highlights: • Provides a comprehensive review of the applied economic literature dedicated to WtE. • Offers a detailed discussion of the main assumptions that characterize alternative positions. • Highlights the most robust achievements obtained by the applied economic research in this field. • Compares economic and non-economic valuation techniques. - Abstract: This paper offers a systematic review of the literature of the last 15 years, which applies economic analysis and theories to the issue of combustion of solid waste. Waste incineration has attracted the interest of economists in the first place concerning the comparative assessment of waste management options, withmore » particular reference to external costs and benefits. A second important field of applied economic research concerns the market failures associated with the provision of thermal treatment of waste, that justify some deviation from the standard competitive market model. Our analysis discusses the most robust achievements and the more controversial areas. All in all, the economic perspective seems to confirm the desirability of assigning a prominent role to thermal treatments in an integrated waste management strategy. Probably the most interesting original contribution it has to offer concerns the refusal of categorical assumptions and too rigid priority ladders, emphasizing instead the need to consider site-specific circumstances that may favor one or another solution.« less

  11. HALT to qualify electronic packages: a proof of concept

    NASA Astrophysics Data System (ADS)

    Ramesham, Rajeshuni

    2014-03-01

    the test boards to various g levels ranging from 5g to 50g, test durations of 10 minutes to 60 minutes, hot temperatures of up to +125°C and cold temperatures down to -150°C. During the HALT test, electrical continuity measurements of the PBGA package showed an open-circuit, whereas the BGA, MLF, and QFPs showed signs of small variations of electrical continuity measurements. The electrical continuity anomaly of the PBGA occurred in the test board within 12 hours of commencing the accelerated test. Similar test boards were assembled, thermal cycled independently from -150°C to +125°C and monitored for electrical continuity through each package design. The PBGA package on the test board showed an anomalous electrical continuity behavior after 959 thermal cycles. Each thermal cycle took around 2.33 hours, so that a total test time to failure of the PBGA was 2,237 hours (or ~3.1 months) due to thermal cycling alone. The accelerated technique (thermal cycling + shock) required only 12 hours to cause a failure in the PBGA electronic package. Compared to the thermal cycle only test, this was an acceleration of ~186 times (more than 2 orders of magnitude). This acceleration process can save significant time and resources for predicting the life of a package component in a given environment, assuming the failure mechanisms are similar in both the tests. Further studies are in progress to make systematic evaluations of the HALT technique on various other advanced electronic packaging components on the test board. With this information one will be able to estimate the number of mission thermal cycles to failure with a much shorter test program. Further studies are in progress to make systematic study of various components, constant temperature range for both the tests. Therefore, one can estimate the number of hours to fail in a given thermal and shock levels for a given test board physical properties.

  12. Acoustic barriers obtained from industrial wastes.

    PubMed

    Garcia-Valles, M; Avila, G; Martinez, S; Terradas, R; Nogués, J M

    2008-07-01

    Acoustic pollution is an environmental problem that is becoming increasingly more important in our society. Likewise, the accumulation of generated waste and the need for waste management are also becoming more and more pressing. In this study we describe a new material--called PROUSO--obtained from industrial wastes. PROUSO has a variety of commercial and engineering, as well as building, applications. The main raw materials used for this environmentally friendly material come from slag from the aluminium recycling process, dust from the marble industry, foundry sands, and recycled expanded polystyrene from recycled packaging. Some natural materials, such as plastic clays, are also used. To obtain PROUSO we used a conventional ceramic process, forming new mineral phases and incorporating polluted elements into the structure. Its physical properties make PROUSO an excellent acoustic and thermal insulation material. It absorbs 95% of the sound in the frequency band of the 500 Hz. Its compressive strength makes it ideal for use in ceramic wall building.

  13. An overview of metals recovery from thermal power plant solid wastes.

    PubMed

    Meawad, Amr S; Bojinova, Darinka Y; Pelovski, Yoncho G

    2010-12-01

    Thermal power plants (TPPs) that burn fossil fuels emit several pollutants linked to the environmental problems of acid rain, urban ozone, and the possibility of global climate change. As coal is burned in a power plant, its noncombustible mineral content is partitioned into bottom ash, which remains in the furnace, and fly ash, which rises with flue gases. Two other by-products of coal combustion air-pollution control technologies are flue gas desulfurization (FGD) wastes and fluidized-bed combustion (FBC) wastes. This paper analyzed and summarized the generation, characteristics and application of TPP solid wastes and discussed the potential effects of such solid wastes on the environment. On this basis, a review of a number of methods for recovery of metals from TPP solid wastes was made. They usually contain a quantity of valuable metals and they are actually a secondary resource of metals. By applying mineral processing technologies and hydrometallurgical and biohydrometallurgical processes, it is possible to recover metals such as Al, Ga, Ge, Ca, Cd, Fe, Hg, Mg, Na, Ni, Pb, Ra, Th, V, Zn, etc., from TPP solid wastes. Recovery of metals from such wastes and its utilization are important not only for saving metal resources, but also for protecting the environment. Copyright © 2010 Elsevier Ltd. All rights reserved.

  14. Novel Techniques for Millimeter-Wave Packages

    NASA Technical Reports Server (NTRS)

    Herman, Martin I.; Lee, Karen A.; Kolawa, Elzbieta A.; Lowry, Lynn E.; Tulintseff, Ann N.

    1995-01-01

    A new millimeter-wave package architecture with supporting electrical, mechanical and material science experiment and analysis is presented. This package is well suited for discrete devices, monolithic microwave integrated circuits (MMIC's) and multichip module (MCM) applications. It has low-loss wide-band RF transitions which are necessary to overcome manufacturing tolerances leading to lower per unit cost Potential applications of this new packaging architecture which go beyond the standard requirements of device protection include integration of antennas, compatibility to photonic networks and direct transitions to waveguide systems. Techniques for electromagnetic analysis, thermal control and hermetic sealing were explored. Three dimensional electromagnetic analysis was performed using a finite difference time-domain (FDTD) algorithm and experimentally verified for millimeter-wave package input and output transitions. New multi-material system concepts (AlN, Cu, and diamond thin films) which allow excellent surface finishes to be achieved with enhanced thermal management have been investigated. A new approach utilizing block copolymer coatings was employed to hermetically seal packages which met MIL STD-883.

  15. Waste Management Information System (WMIS) User Guide

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    R. E. Broz

    2008-12-22

    This document provides the user of the Waste Management Information System (WMIS) instructions on how to use the WMIS software. WMIS allows users to initiate, track, and close waste packages. The modular design supports integration and utilization of data throuh the various stages of waste management. The phases of the waste management work process include generation, designation, packaging, container management, procurement, storage, treatment, transportation, and disposal.

  16. Thermal Stability and Material Balance of Nanomaterials in Waste Incineration

    NASA Astrophysics Data System (ADS)

    Paur, H.-R.; Baumann, W.; Hauser, M.; Lang, I.; Teuscher, N.; Seifert, H.; Stapf, D.

    2017-06-01

    Nanostructured materials are widely used to improve the properties of consumer products such as tires, cosmetics, light weight equipment etc. Due to their complex composition these products are hardly recycled and thermal treatment is preferred. In this study we investigated the thermal stability and material balance of nanostructured metal oxides in flames and in an industrial waste incinerator. We studied the size distribution of nanostructured metal oxides (CeO2, TiO2, SiO2) in a flame reactor and in a heated reaction tube. In the premixed ethylene/air flame, nano-structured CeO2 partly evaporates forming a new particle mode. This is probably due to chemical reactions in the flame. In addition sintering of agglomerates takes place in the flame. In the electrically heated reaction tube however only sintering of the agglomerated nanomaterials is observed. Ceria has a low background in waste incinerators and is therefore a suitable tracer for investigating the fate of nanostructured materials. Low concentrations of Ceria were introduced by a two-phase nozzle into the post-combustion zone of a waste incinerator. By the incineration of coal dust in a burning chamber the Ceria nanoparticles are mainly found in the size range of the fly ash (1 - 10 µm) because of agglomeration. With gas as a fuel less agglomeration was observed and the Ceria nanoparticles were in the particle size range below 1 µm.

  17. A Description and Analysis of the German Packaging Take-Back System

    ERIC Educational Resources Information Center

    Nakajima, Nina; Vanderburg, Willem H.

    2006-01-01

    The German packaging ordinance is an example of legislated extended producer responsibility (also known as product take-back). Consumers can leave packaging with retailers, and packagers are required to pay for their recycling and disposal. It can be considered to be successful in reducing waste, spurring the redesign of packaging to be more…

  18. Cleanup Verification Package for the 618-2 Burial Ground

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    W. S. Thompson

    2006-12-28

    This cleanup verification package documents completion of remedial action for the 618-2 Burial Ground, also referred to as Solid Waste Burial Ground No. 2; Burial Ground No. 2; 318-2; and Dry Waste Burial Site No. 2. This waste site was used primarily for the disposal of contaminated equipment, materials and laboratory waste from the 300 Area Facilities.

  19. High-Performance Power-Semiconductor Packages

    NASA Technical Reports Server (NTRS)

    Renz, David; Hansen, Irving; Berman, Albert

    1989-01-01

    A 600-V, 50-A transistor and 1,200-V, 50-A diode in rugged, compact, lightweight packages intended for use in inverter-type power supplies having switching frequencies up to 20 kHz. Packages provide low-inductance connections, low loss, electrical isolation, and long-life hermetic seal. Low inductance achieved by making all electrical connections to each package on same plane. Also reduces high-frequency losses by reducing coupling into inherent shorted turns in packaging material around conductor axes. Stranded internal power conductors aid conduction at high frequencies, where skin effect predominates. Design of packages solves historical problem of separation of electrical interface from thermal interface of high-power semiconductor device.

  20. RH Packaging Program Guidance

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Washington TRU Solutions LLC

    The purpose of this program guidance document is to provide the technical requirements for use, operation, inspection, and maintenance of the RH-TRU 72-B Waste Shipping Package (also known as the "RH-TRU 72-B cask") and directly related components. This document complies with the requirements as specified in the RH-TRU 72-B Safety Analysis Report for Packaging (SARP), and Nuclear Regulatory Commission (NRC) Certificate of Compliance (C of C) 9212. If there is a conflict between this document and the SARP and/or C of C, the C of C shall govern. The C of C states: "...each package must be prepared for shipmentmore » and operated in accordance with the procedures described in Chapter 7.0, Operating Procedures, of the application." It further states: "...each package must be tested and maintained in accordance with the procedures described in Chapter 8.0, Acceptance Tests and Maintenance Program of the Application." Chapter 9.0 of the SARP tasks the Waste Isolation Pilot Plant (WIPP) Management and Operating (M&O) Contractor with assuring the packaging is used in accordance with the requirements of the C of C. Because the packaging is NRC-approved, users need to be familiar with Title 10 Code of Federal Regulations (CFR) §71.8, "Deliberate Misconduct." Any time a user suspects or has indications that the conditions of approval in the C of C were not met, the U.S. Department of Energy (DOE) Carlsbad Field Office (CBFO) shall be notified immediately. The CBFO will evaluate the issue and notify the NRC if required.In accordance with 10 CFR Part 71, "Packaging and Transportation of Radioactive Material," certificate holders, packaging users, and contractors or subcontractors who use, design, fabricate, test, maintain, or modify the packaging shall post copies of (1) 10 CFR Part 21, "Reporting of Defects and Noncompliance," regulations, (2) Section 206 of the Energy Reorganization Act of 1974, and (3) NRC Form 3, Notice to Employees. These documents must be posted in a

  1. RH Packaging Program Guidance

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Washington TRU Solutions LLC

    The purpose of this program guidance document is to provide the technical requirements for use, operation, inspection, and maintenance of the RH-TRU 72-B Waste Shipping Package and directly related components. This document complies with the requirements as specified in the RH-TRU 72-B Safety Analysis Report for Packaging (SARP), and Nuclear Regulatory Commission (NRC) Certificate of Compliance (C of C) 9212. If there is a conflict between this document and the SARP and/or C of C, the C of C shall govern. The C of C states: "...each package must be prepared for shipment and operated in accordance with the proceduresmore » described in Chapter 7.0, Operating Procedures, of the application." It further states: "...each package must be tested and maintained in accordance with the procedures described in Chapter 8.0, Acceptance Tests and Maintenance Program of the Application." Chapter 9.0 of the SARP tasks the Waste Isolation Pilot Plant (WIPP) Management and Operating (M&O) Contractor with assuring the packaging is used in accordance with the requirements of the C of C. Because the packaging is NRC-approved, users need to be familiar with 10 Code of Federal Regulations (CFR) §71.8, "Deliberate Misconduct." Any time a user suspects or has indications that the conditions of approval in the C of C were not met, the U.S. Department of Energy (DOE) Carlsbad Field Office (CBFO) shall be notified immediately. CBFO will evaluate the issue and notify the NRC if required. In accordance with 10 CFR Part 71, "Packaging and Transportation of Radioactive Material," certificate holders, packaging users, and contractors or subcontractors who use, design, fabricate, test, maintain, or modify the packaging shall post copies of (1) 10 CFR Part 21, "Reporting of Defects and Noncompliance," regulations, (2) Section 206 of the Energy Reorganization Act of 1974, and (3) NRC Form 3, Notice to Employees. These documents must be posted in a conspicuous location where the activities subject

  2. Measurement of radionuclides in waste packages

    DOEpatents

    Brodzinski, R.L.; Perkins, R.W.; Rieck, H.G.; Wogman, N.A.

    1984-09-12

    A method is described for non-destructively assaying the radionuclide content of solid waste in a sealed container by analysis of the waste's gamma-ray spectrum and neutron emissions. Some radionuclides are measured by characteristic photopeaks in the gamma-ray spectrum; transuranic nuclides are measured by neutron emission rate; other radionuclides are measured by correlation with those already measured.

  3. Measurement of radionuclides in waste packages

    DOEpatents

    Brodzinski, Ronald L.; Perkins, Richard W.; Rieck, Henry G.; Wogman, Ned A.

    1986-01-01

    A method is described for non-destructively assaying the radionuclide content of solid waste in a sealed container by analysis of the waste's gamma-ray spectrum and neutron emissions. Some radionuclides are measured by characteristic photopeaks in the gamma-ray spectrum; transuranic nuclides are measured by neutron emission rate; other radionuclides are measured by correlation with those already measured.

  4. Climate impact analysis of waste treatment scenarios--thermal treatment of commercial and pretreated waste versus landfilling in Austria.

    PubMed

    Ragossnig, A M; Wartha, C; Pomberger, R

    2009-11-01

    A major challenge for modern waste management lies in a smart integration of waste-to-energy installations in local energy systems in such a way that the energy efficiency of the waste-to-energy plant is optimized and that the energy contained in the waste is, therefore, optimally utilized. The extent of integration of thermal waste treatment processes into regular energy supply systems plays a major role with regard to climate control. In this research, the specific waste management situation looked at scenarios aiming at maximizing the energy recovery from waste (i.e. actual scenario and waste-to-energy process with 75% energy efficiency [22.5% electricity, 52.5% heat]) yield greenhouse gas emission savings due to the fact that more greenhouse gas emissions are avoided in the energy sector than caused by the various waste treatment processes. Comparing dedicated waste-to-energy-systems based on the combined heat and power (CHP) process with concepts based on sole electricity production, the energy efficiency proves to be crucial with regard to climate control. This underlines the importance of choosing appropriate sites for waste-to-energy-plants. This research was looking at the effect with regard to the climate impact of various waste management scenarios that could be applied alternatively by a private waste management company in Austria. The research is, therefore, based on a specific set of data for the waste streams looked at (waste characteristics, logistics needed, etc.). Furthermore, the investigated scenarios have been defined based on the actual available alternatives with regard to the usage of treatment plants for this specific company. The standard scenarios for identifying climate impact implications due to energy recovery from waste are based on the respective marginal energy data for the power and heat generation facilities/industrial processes in Austria.

  5. Management of MSW in Spain and recovery of packaging steel scrap.

    PubMed

    Tayibi, Hanan; Peña, Carmen; López, Félix A; López-Delgado, Aurora

    2007-01-01

    Packaging steel is more advantageously recovered and recycled than other packaging material due to its magnetic properties. The steel used for packaging is of high quality, and post-consumer waste therefore produces high-grade ferrous scrap. Recycling is thus an important issue for reducing raw material consumption, including iron ore, coal and energy. Household refuse management consists of collection/disposal, transport, and processing and treatment - incineration and composting being the most widely used methods in Spain. Total Spanish MSW production exceeds 21 million tons per year, of which 28.1% and 6.2% are treated in compost and incineration plants, respectively. This paper presents a comprehensive study of incineration and compost plants in Spain, including a review of the different processes and technologies employed and the characteristics and quality of the recovered ferrous scrap. Of the total amount of packaging steel scrap recovered from MSW, 38% comes from compost plants and 14% from incineration plants. Ferrous scrap from incineration plants presents a high degree of chemical alteration as a consequence of the thermal process to which the MSW is subjected, particularly the conditions in which the slag is cooled, and accordingly its quality diminishes. Fragmentation and magnetic separation processes produce an enhancement of the scrap quality. Ferrous scrap from compost plants has a high tin content, which negatively affects its recycling. Cleaning and detinning processes are required prior to recycling.

  6. Recycling of blast furnace sludge by briquetting with starch binder: Waste gas from thermal treatment utilizable as a fuel.

    PubMed

    Drobíková, Klára; Plachá, Daniela; Motyka, Oldřich; Gabor, Roman; Kutláková, Kateřina Mamulová; Vallová, Silvie; Seidlerová, Jana

    2016-02-01

    Steel plants generate significant amounts of wastes such as sludge, slag, and dust. Blast furnace sludge is a fine-grained waste characterized as hazardous and affecting the environment negatively. Briquetting is one of the possible ways of recycling of this waste while the formed briquettes serve as a feed material to the blast furnace. Several binders, both organic and inorganic, had been assessed, however, only the solid product had been analysed. The aim of this study was to assess the possibilities of briquetting using commonly available laundry starch as a binder while evaluating the possible utilization of the waste gas originating from the thermal treatment of the briquettes. Briquettes (100g) were formed with the admixture of starch (UNIPRET) and their mechanical properties were analysed. Consequently, they were subjected to thermal treatment of 900, 1000 and 1100°C with retention period of 40min during which was the waste gas collected and its content analysed using gas chromatography. Dependency of the concentration of the compounds forming the waste gas on the temperature used was determined using Principal component analysis (PCA) and correlation matrix. Starch was found to be a very good binder and reduction agent, it was confirmed that metallic iron was formed during the thermal treatment. Approximately 20l of waste gas was obtained from the treatment of one briquette; main compounds were methane and hydrogen rendering the waste gas utilizable as a fuel while the greatest yield was during the lowest temperatures. Preparation of blast furnace sludge briquettes using starch as a binder and their thermal treatment represents a suitable method for recycling of this type of metallurgical waste. Moreover, the composition of the resulting gas is favourable for its use as a fuel. Copyright © 2015 Elsevier Ltd. All rights reserved.

  7. Packaging, Transportation and Recycling of NPP Condenser Modules - 12262

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Polley, G.M.

    2012-07-01

    Perma-Fix was awarded contract from Energy Northwest for the packaging, transportation and disposition of the condenser modules, water boxes and miscellaneous metal, combustibles and water generated during the 2011 condenser replacement outage at the Columbia Generating Station. The work scope was to package the water boxes and condenser modules as they were removed from the facility and transfer them to the Perma-Fix Northwest facility for processing, recycle of metals and disposition. The condenser components were oversized and overweight (the condenser modules weighed ∼102,058 kg [225,000 lb]) which required special equipment for loading and transport. Additional debris waste was packaged inmore » inter-modals and IP-1 boxes for transport. A waste management plan was developed to minimize the generation of virtually any waste requiring landfill disposal. The Perma-Fix Northwest facility was modified to accommodate the ∼15 m [50-ft] long condenser modules and equipment was designed and manufactured to complete the disassembly, decontamination and release survey. The condenser modules are currently undergoing processing for free release to a local metal recycler. Over three millions pounds of metal will be recycled and over 95% of the waste generated during this outage will not require land disposal. There were several elements of this project that needed to be addressed during the preparation for this outage and the subsequent packaging, transportation and processing. - Staffing the project to support 24/7 generation of large components and other wastes. - The design and manufacture of the soft-sided shipping containers for the condenser modules that measured ∼15 m X 4 m X 3 m [50 ft X 13 ft X 10 ft] and weighed ∼102,058 kg [225,000 lbs] - Developing a methodology for loading the modules into the shipping containers. - Obtaining a transport vehicle for the modules. - Designing and modifying the processing facility. - Movement of the modules at the

  8. Reliability of Ceramic Column Grid Array Interconnect Packages Under Extreme Temperatures

    NASA Technical Reports Server (NTRS)

    Ramesham, Rajeshuni

    2011-01-01

    A paper describes advanced ceramic column grid array (CCGA) packaging interconnects technology test objects that were subjected to extreme temperature thermal cycles. CCGA interconnect electronic package printed wiring boards (PWBs) of polyimide were assembled, inspected nondestructively, and, subsequently, subjected to ex - treme-temperature thermal cycling to assess reliability for future deep-space, short- and long-term, extreme-temperature missions. The test hardware consisted of two CCGA717 packages with each package divided into four daisy-chained sections, for a total of eight daisy chains to be monitored. The package is 33 33 mm with a 27 27 array of 80%/20% Pb/Sn columns on a 1.27-mm pitch. The change in resistance of the daisy-chained CCGA interconnects was measured as a function of the increasing number of thermal cycles. Several catastrophic failures were observed after 137 extreme-temperature thermal cycles, as per electrical resistance measurements, and then the tests were continued through 1,058 thermal cycles to corroborate and understand the test results. X-ray and optical inspection have been made after thermal cycling. Optical inspections were also conducted on the CCGA vs. thermal cycles. The optical inspections were conclusive; the x-ray images were not. Process qualification and assembly is required to optimize the CCGA assembly, which is very clear from the x-rays. Six daisy chains were open out of seven daisy chains, as per experimental test data reported. The daisy chains are open during the cold cycle, and then recover during the hot cycle, though some of them also opened during the hot thermal cycle..

  9. Packaged silica microsphere-taper coupling system for robust thermal sensing application.

    PubMed

    Yan, Ying-Zhan; Zou, Chang-Ling; Yan, Shu-Bin; Sun, Fang-Wen; Ji, Zhe; Liu, Jun; Zhang, Yu-Guang; Wang, Li; Xue, Chen-Yang; Zhang, Wen-Dong; Han, Zheng-Fu; Xiong, Ji-Jun

    2011-03-28

    We propose and realize a novel packaged microsphere-taper coupling structure (PMTCS) with a high quality factor (Q) up to 5×10(6) by using the low refractive index (RI) ultraviolet (UV) glue as the coating material. The optical loss of the PMTCS is analyzed experimentally and theoretically, which indicate that the Q is limited by the glue absorption and the radiation loss. Moreover, to verify the practicability of the PMTCS, thermal sensing experiments are carried out, showing the excellent convenience and anti-jamming ability of the PMTCS with a high temperature resolution of 1.1×10(-3) ◦C. The experiments also demonstrate that the PMTCS holds predominant advantages, such as the robustness, mobility, isolation, and the PMTCS can maintain the high Q for a long time. The above advantages make the PMTCS strikingly attractive and potential in the fiber-integrated sensors and laser.

  10. The quality study of recycled glass phosphor waste for LED

    NASA Astrophysics Data System (ADS)

    Tsai, Chun-Chin; Chen, Guan-Hao; Yue, Cheng-Feng; Chen, Cin-Fu; Cheng, Wood-Hi

    2017-02-01

    To study the feasibility and quality of recycled glass phosphor waste for LED packaging, the experiments were conducted to compare optical characteristics between fresh color conversion layer and that made of recycled waste. The fresh color conversion layer was fabricated through sintering pristine mixture of Y.A.G. powder [yellow phosphor (Y3AlO12 : Ce3+). Those recycled waste glass phosphor re-melted to form Secondary Molten Glass Phosphor (S.M.G.P.). The experiments on such low melting temperature glass results showed that transmission rates of S.M.G.P. are 9% higher than those of first-sintered glass phosphor, corresponding to 1.25% greater average bubble size and 36% more bubble coverage area in S.M.G.P. In the recent years, high power LED modules and laser projectors have been requiring higher thermal stability by using glass phosphor materials for light mixing. Nevertheless, phosphor and related materials are too expensive to expand their markets. It seems a right trend and research goal that recycling such waste of high thermal stability and quality materials could be preferably one of feasible cost-down solutions. This technical approach could bring out brighter future for solid lighting and light source module industries.

  11. Thermal energy storage for industrial waste heat recovery

    NASA Technical Reports Server (NTRS)

    Hoffman, H. W.; Kedl, R. J.; Duscha, R. A.

    1978-01-01

    The potential is examined for waste heat recovery and reuse through thermal energy storage in five specific industrial categories: (1) primary aluminum, (2) cement, (3) food processing, (4) paper and pulp, and (5) iron and steel. Preliminary results from Phase 1 feasibility studies suggest energy savings through fossil fuel displacement approaching 0.1 quad/yr in the 1985 period. Early implementation of recovery technologies with minimal development appears likely in the food processing and paper and pulp industries; development of the other three categories, though equally desirable, will probably require a greater investment in time and dollars.

  12. Space station power semiconductor package

    NASA Technical Reports Server (NTRS)

    Balodis, Vilnis; Berman, Albert; Devance, Darrell; Ludlow, Gerry; Wagner, Lee

    1987-01-01

    A package of high-power switching semiconductors for the space station have been designed and fabricated. The package includes a high-voltage (600 volts) high current (50 amps) NPN Fast Switching Power Transistor and a high-voltage (1200 volts), high-current (50 amps) Fast Recovery Diode. The package features an isolated collector for the transistors and an isolated anode for the diode. Beryllia is used as the isolation material resulting in a thermal resistance for both devices of .2 degrees per watt. Additional features include a hermetical seal for long life -- greater than 10 years in a space environment. Also, the package design resulted in a low electrical energy loss with the reduction of eddy currents, stray inductances, circuit inductance, and capacitance. The required package design and device parameters have been achieved. Test results for the transistor and diode utilizing the space station package is given.

  13. Examination of SR101 shipping packages

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Daugherty, W. L.

    Four SR101 shipping packages were removed from service and provided for disassembly and examination of the internal fiberboard assemblies. These packages were 20 years old, and had experienced varying levels of degradation. Two of the packages were successfully disassembled and fiberboard samples were removed from these packages and tested. Mechanical and thermal property values are generally comparable to or higher than baseline values measured on fiberboard from 9975 packages, which differs primarily in the specified density range. While baseline data for the SR101 material is not available, this comparison with 9975 material suggests that the material properties of the SR101more » fiberboard have not significantly degraded.« less

  14. Energy recovery from waste glycerol by utilizing thermal water vapor plasma.

    PubMed

    Tamošiūnas, Andrius; Valatkevičius, Pranas; Gimžauskaitė, Dovilė; Jeguirim, Mejdi; Mėčius, Vladas; Aikas, Mindaugas

    2017-04-01

    Glycerol, considered as a waste feedstock resulting from biodiesel production, has received much attention in recent years due to its properties, which offer to recover energy. The aim of this study was to investigate the use of a thermal water vapor plasma for waste (crude) glycerol conversion to synthesis gas, or syngas (H 2  + CO). In parallel of crude glycerol, a pure glycerol (99.5%) was used as a reference material in order to compare the concentrations of the formed product gas. A direct current (DC) arc plasma torch stabilized by a mixture of argon/water vapor was utilized for the effective glycerol conversion to hydrogen-rich synthesis gas. It was found that after waste glycerol treatment, the main reaction products were gases with corresponding concentrations of H 2 50.7%, CO 23.53%, CO 2 11.45%, and CH 4 3.82%, and traces of C 2 H 2 and C 2 H 6 , which concentrations were below 0.5%. The comparable concentrations of the formed gas products were obtained after pure glycerol conversion-H 2 46.4%, CO 26.25%, CO 2 11.3%, and CH 4 4.7%. The use of thermal water vapor plasma producing synthesis gas is an effective method to recover energy from both crude and pure glycerol. The performance of the glycerol conversion system was defined in terms of the produced gas yield, the carbon conversion efficiency, the cold gas efficiency, and the specific energy requirements.

  15. Fabrication and Performance of MEMS-Based Pressure Sensor Packages Using Patterned Ultra-Thick Photoresists

    PubMed Central

    Chen, Lung-Tai; Chang, Jin-Sheng; Hsu, Chung-Yi; Cheng, Wood-Hi

    2009-01-01

    A novel plastic packaging of a piezoresistive pressure sensor using a patterned ultra-thick photoresist is experimentally and theoretically investigated. Two pressure sensor packages of the sacrifice-replacement and dam-ring type were used in this study. The characteristics of the packaged pressure sensors were investigated by using a finite-element (FE) model and experimental measurements. The results show that the thermal signal drift of the packaged pressure sensor with a small sensing-channel opening or with a thin silicon membrane for the dam-ring approach had a high packaging induced thermal stress, leading to a high temperature coefficient of span (TCO) response of −0.19% span/°C. The results also show that the thermal signal drift of the packaged pressure sensors with a large sensing-channel opening for sacrifice-replacement approach significantly reduced packaging induced thermal stress, and hence a low TCO response of −0.065% span/°C. However, the packaged pressure sensors of both the sacrifice-replacement and dam-ring type still met the specification −0.2% span/°C of the unpackaged pressure sensor. In addition, the size of proposed packages was 4 × 4 × 1.5 mm3 which was about seven times less than the commercialized packages. With the same packaging requirement, the proposed packaging approaches may provide an adequate solution for use in other open-cavity sensors, such as gas sensors, image sensors, and humidity sensors. PMID:22454580

  16. Thermal anomalies of the transmitter experiment package on the communications technology satellite

    NASA Technical Reports Server (NTRS)

    Alexovich, R. E.; Curren, A. N.

    1979-01-01

    The causes of four temporary thermal-control-system malfunctions that gave rise to unexpected temperature excursions in the 12-gigahertz, 200-watt transmitter experiment package (TEP) on the Communications Technology Satellite were investigated. The TEP consists of a nominal 200-watt output stage tube (OST), a supporting power-processing system (PPS), and a variable-conductance heat-pipe system (VCHPS). The VCHPS, which uses three heat pipes to conduct heat from the body of the OST to a radiator fin, was designed to maintain the TEP at safe operating temperatures at all operating conditions. On four occasions during 1977, all near the spring and fall equinoxes, the OST body temperature and related temperatures displayed sudden, rapid, and unexpected rises above normal levels while the TEP was operating at essentially constant, normal conditions. The temperature excursions were terminated without TEP damage by reducing the radio frequency (RF) output power of the OST. Between the anomalies and since the fourth, the thermal control system has apparently functioned as designed. The results indicate the most probable cause of the temperature anomalies is depriming of the arteries in the variable-conductance heat pipes. A mode was identified in which the TEP, as presently configured, may operate with stable temperatures and with minimum change in performance level.

  17. Thermally Stabilized Transmit/Receive Modules

    NASA Technical Reports Server (NTRS)

    Hoffman, James; DelCastillo, Linda; Miller, Jennifer; Birur, Gaj

    2011-01-01

    RF-hybrid technologies enable smaller packaging and mass reduction in radar instruments, especially for subsystems with dense electronics, such as electronically steered arrays. We are designing thermally stabilized RF-hybrid T/R modules using new materials for improved thermal performance of electronics. We are combining advanced substrate and housing materials with a thermal reservoir material, and develop new packaging techniques to significantly improve thermal-cycling reliability and performance stability over temperature.

  18. Characterization and thermal behaviour of textile waste from the industrial city of Aleppo in Syria.

    PubMed

    Majanny, Abdulkader; Nassour, Abdallah; Gose, Sven; Scholz, Reinhard; Nelles, Michael

    2011-03-01

    This paper describes the present waste management practices in the industrial city Alsheikh Najjar of Aleppo, mainly with regard to textile waste materials, and provides some insights into future prospects. As a first exploration for energy recovery from textile waste materials, the thermal behaviour of seven different types of textile waste were studied by thermogravimetry. There were assorted differential thermogravimetry peaks found over a particular range of temperatures. Pyrolysis experiments were carried out to identify the pyrolysis products such as gas, liquid, and solid residues known as char. In a subsequent analysis, the combustion behaviour of textile waste was determined and analysed. Typical parameters - reaction front velocity, ignition rate - were considered for the evaluation of the combustion behaviour and the results were compared with values observed for waste wood.

  19. Thermal immobilization of Cr, Cu and Zn of galvanizing wastes in the presence of clay and fly ash.

    PubMed

    Singh, I B; Chaturvedi, K; Yegneswaran, A H

    2007-07-01

    In the present investigation thermal treatment of galvanizing waste with clay and fly ash has been carried out to immobilize Cr, Zn, Cu and other metals of the waste at temperature range 850 degrees C to 950 degrees C. Leaching of the metals from the waste and solidified product was analyzed using toxic characteristic leaching procedure (TCLP). Results indicated that the composition of waste and clay treatment temperature are the key factors in determining the stability of solidified product. After heating at 950 degrees C, the solidified specimens of 10% waste with clay have shown comparatively a high compressive strength and less water absorption. However, a decrease in compressive strength and increase in water absorption were noticed after addition of 15% of waste with clay. The leachability of all the metals present in the waste was found to reduce considerably with the increase of treatment temperature. In the case of Cr and Zn, their leachabilty was found at unacceptable levels from the treated product obtained after heating at 850 degrees C However, their leachability was reduced significantly within an acceptable level after treatment at 950 degrees C. The thermal treatment has shown an increase of re-oxidation trend of Cr (III) to Cr (VI) up to 900 degrees C of heating and this trend became almost zero after heating at 950 degrees C. Addition of fly ash did not show any improvement in strength, durability and leachability of metals from the thermally treated product. X-ray diffraction (XRD) analysis of the product confirmed the presence of mixed phases of oxides of toxic metals.

  20. Micronutrient dynamics after thermal pretreatment of olive mill solid waste.

    PubMed

    Almansa, Ana R; Rodriguez-Galan, Monica; Borja, Rafael; Fermoso, Fernando G

    2015-09-01

    This study investigated metal dynamics, and their bioavailability, before and after thermal pretreatment of olive mill solid waste (OMSW), using a sequential metal extraction scheme. The 11.5% increase of cobalt in the most available fraction after the pretreatment coupled to the increase of methane production rate have been a good indicator that the OMSW anaerobic digestion might be metal limited due to the lack of cobalt. Copyright © 2015 Elsevier Ltd. All rights reserved.

  1. Interfacial and mechanical property analysis of waste printed circuit boards subject to thermal shock.

    PubMed

    Li, Jinhui; Duan, Huabo; Yu, Keli; Wang, Siting

    2010-02-01

    Waste printed circuit boards (PCBs) are the focal points for handling electric and electronic waste. In this paper, a thermal shock method was used to pretreat waste PCBs for the improvement of crushing performance. The influence of the thermal shock process on interfacial modification and mechanical property attenuation of PCB waste was studied. The appearance and layer spacing of the basal plane began to change slightly when the temperature reached 200 degrees C. By 250 degrees C, apparent bulging, cracking, and delamination were observed. However, pyrolysis of PCBs occurred when the temperature reached 275 degrees C, where PCBs were carbonized. The thermogravimetric analysis of PCB particles under vacuum showed that 270 degrees C was the starting point of pyrolysis. The tensile and impact strength of PCBs were reduced as shock temperature rose gradually, with a reduction by 2.6 and 16.5%, respectively, at 250 degrees C from its unheated strength. The PCBs that were heated to 250 degrees C achieved 100% liberation, increasing linearly from 13.6% for unheated PCBs through a single-level shear-crusher (2-mm mesh) and resulting in an obvious reduction of 9.5% (dB) in dust and noise at 250 degrees C. These parameters could be helpful for establishing the operational setup for industrial-scale facilities with the aim of achieving a compact process and a highly efficient recovery for waste PCBs compared with those of the traditional combination mechanical technologies.

  2. Thermal Destruction of TETS: Experiments and Modeling ...

    EPA Pesticide Factsheets

    Symposium Paper In the event of a contamination event involving chemical warfare agents (CWAs) or toxic industrial chemicals (TICs), large quantities of potentially contaminated materials, both indoor and outdoor, may be treated with thermal incineration during the site remediation process. Even if the CWAs or TICs of interest are not particularly thermally stable and might be expected to decompose readily in a high temperature combustion environment, the refractory nature of many materials found inside and outside buildings may present heat transfer challenges in an incineration system depending on how the materials are packaged and fed into the incinerator. This paper reports on a study to examine the thermal decomposition of a banned rodenticide, tetramethylene disulfotetramine (TETS) in a laboratory reactor, analysis of the results using classical reactor design theory, and subsequent scale-up of the results to a computer-simulation of a full-scale commercial hazardous waste incinerator processing ceiling tile contaminated with residual TETS.

  3. Improving efficiency of transport fuels production by thermal hydrolysis of waste activated sludge

    NASA Astrophysics Data System (ADS)

    Gulshin, Igor

    2017-10-01

    The article deals with issues of transport biofuels. Transport biofuels are an important element of a system of energy security. Moreover, as part of a system it is inextricably linked to the urban, rural or industrial infrastructure. The paper discusses methods of increasing the yield of biogas from anaerobic digesters at wastewater treatment plants. The thermal hydrolysis method was considered. The main advantages and drawbacks of this method were analyzed. The experimental biomass (from SNDOD-bioreactor) and high-organic substrate have been previously studied by respirometry methods. A biomethane potential of the investigated organic substrate has high rates because of substrate composition (the readily biodegradable substrate in the total composition takes about 85%). Waste activated sludge from SNDOD-bioreactor can be used for biofuel producing with high efficiency especially with pre-treatment like a thermal hydrolysis. Further studies have to consider the possibility of withdrawing inhibitors from waste activated sludge.

  4. Evaluation of trade-offs in costs and environmental impacts for returnable packaging implementation

    NASA Astrophysics Data System (ADS)

    Jarupan, Lerpong; Kamarthi, Sagar V.; Gupta, Surendra M.

    2004-02-01

    The main thrust of returnable packaging these days is to provide logistical services through transportation and distribution of products and be environmentally friendly. Returnable packaging and reverse logistics concepts have converged to mitigate the adverse effect of packaging materials entering the solid waste stream. Returnable packaging must be designed by considering the trade-offs between costs and environmental impact to satisfy manufacturers and environmentalists alike. The cost of returnable packaging entails such items as materials, manufacturing, collection, storage and disposal. Environmental impacts are explicitly linked with solid waste, air pollution, and water pollution. This paper presents a multi-criteria evaluation technique to assist decision-makers for evaluating the trade-offs in costs and environmental impact during the returnable packaging design process. The proposed evaluation technique involves a combination of multiple objective integer linear programming and analytic hierarchy process. A numerical example is used to illustrate the methodology.

  5. DEMONSTRATION BULLETIN: X*TRAX MODEL 200 THERMAL DESORPTION SYSTEMS - CHEMICAL WASTE MANAGEMENT, INC.

    EPA Science Inventory

    The X*TRAX™ Mode! 200 Thermal Desorption System developed by Chemical Waste Management, Inc. (CWM), is a low-temperature process designed to separate organic contaminants from soils, sludges, and other solid media. The X*TRAX™ Model 200 is fully transportable and consists of thre...

  6. Long duration exposure facility solar illumination data package

    NASA Technical Reports Server (NTRS)

    Berrios, William M.; Sampair, Thomas

    1990-01-01

    A post flight solar illumination data package was created by the LDEF thermal analysis data group in support of the LDEF science office data group. The data presented was prepared with the Thermal Radiation Analysis System (TRASYS) program. Ground tracking data was used to calculate daily orbital beta angles for the calculation of resultant fluxes. This data package will be useful in calculation of solar illumination fluent for a variety of beta angle orbital conditions encountered during the LDEF mission.

  7. Reliability of CGA/LGA/HDI Package Board/Assembly (Final Report)

    NASA Technical Reports Server (NTRS)

    Ghaffaroam. Reza

    2014-01-01

    Package manufacturers are now offering commercial-off-the-shelf column grid array (COTS CGA) packaging technologies in high-reliability versions. Understanding the process and quality assurance (QA) indicators for reliability are important for low-risk insertion of these advanced electronics packages. The previous reports, released in January of 2012 and January of 2013, presented package test data, assembly information, and reliability evaluation by thermal cycling for CGA packages with 1752, 1517, 1509, and 1272 inputs/outputs (I/Os) and 1-mm pitch. It presented the thermal cycling (-55C either 100C or 125C) test results for up to 200 cycles. This report presents up to 500 thermal cycles with quality assurance and failure analysis evaluation represented by optical photomicrographs, 2D real time X-ray images, dye-and-pry photomicrographs, and optical/scanning electron Microscopy (SEM) cross-sectional images. The report also presents assembly challenge using reflowing by either vapor phase or rework station of CGA and land grid array (LGA) versions of three high I/O packages both ceramic and plastic configuration. A new test vehicle was designed having high density interconnect (HDI) printed circuit board (PCB) with microvia-in-pad to accommodate both LGA packages as well as a large number of fine pitch ball grid arrays (BGAs). The LGAs either were assembled onto HDI PCB as an LGA or were solder paste print and reflow first to form solder dome on pads before assembly. Both plastic BGAs with 1156 I/O and ceramic LGAs were assembled. It also presented the X-ray inspection results as well as failures due to 200 thermal cycles. Lessons learned on assembly of ceramic LGAs are also presented.

  8. Physical and thermal behavior of cement composites reinforced with recycled waste paper fibers

    NASA Astrophysics Data System (ADS)

    Hospodarova, Viola; Stevulova, Nadezda; Vaclavik, Vojtech; Dvorsky, Tomas

    2017-07-01

    In this study, three types of recycled waste paper fibers were used to manufacture cement composites reinforced with recycled cellulosic fibers. Waste cellulosic fibers in quantity of 0.2, 0.3, and 0.5 wt.% were added to cement mixtures. Physical properties such as density, water capillarity, water absorbability and thermal conductivity of fiber cement composites were studied after 28 days of hardening. However, durability of composites was tested after their water storage up to 90 days. Final results of tested properties of fiber cement composites were compared with cement reference sample without cellulosic fibers.

  9. Lessons Learned in the Design and Use of IP1 / IP2 Flexible Packaging - 13621

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Sanchez, Mike; Reeves, Wendall; Smart, Bill

    2013-07-01

    For many years in the USA, Low Level Radioactive Waste (LLW), contaminated soils and construction debris, have been transported, interim stored, and disposed of, using IP1 / IP2 metal containers. The performance of these containers has been more than adequate, with few safety occurrences. The containers are used under the regulatory oversight of the US Department of Transportation (DOT), 49 Code of Federal Regulations (CFR). In the late 90's the introduction of flexible packaging for the transport, storage, and disposal of low level contaminated soils and construction debris was introduced. The development of flexible packaging came out of a needmore » for a more cost effective package, for the large volumes of waste generated by the decommissioning of many of the US Department of Energy (DOE) legacy sites across the US. Flexible packaging had to be designed to handle a wide array of waste streams, including soil, gravel, construction debris, and fine particulate dust migration. The design also had to meet all of the IP1 requirements under 49CFR 173.410, and be robust enough to pass the IP2 testing 49 CFR 173.465 required for many LLW shipments. Tens of thousands of flexible packages have been safely deployed and used across the US nuclear industry as well as for hazardous non-radioactive applications, with no recorded release of radioactive materials. To ensure that flexible packages are designed properly, the manufacturer must use lessons learned over the years, and the tests performed to provide evidence that these packages are suitable for transporting low level radioactive wastes. The design and testing of flexible packaging for LLW, VLLW and other hazardous waste streams must be as strict and stringent as the design and testing of metal containers. The design should take into consideration the materials being loaded into the package, and should incorporate the right materials, and manufacturing methods, to provide a quality, safe product. Flexible packaging

  10. WASTE TREATMENT BUILDING SYSTEM DESCRIPTION DOCUMENT

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    F. Habashi

    2000-06-22

    The Waste Treatment Building System provides the space, layout, structures, and embedded subsystems that support the processing of low-level liquid and solid radioactive waste generated within the Monitored Geologic Repository (MGR). The activities conducted in the Waste Treatment Building include sorting, volume reduction, and packaging of dry waste, and collecting, processing, solidification, and packaging of liquid waste. The Waste Treatment Building System is located on the surface within the protected area of the MGR. The Waste Treatment Building System helps maintain a suitable environment for the waste processing and protects the systems within the Waste Treatment Building (WTB) from mostmore » of the natural and induced environments. The WTB also confines contaminants and provides radiological protection to personnel. In addition to the waste processing operations, the Waste Treatment Building System provides space and layout for staging of packaged waste for shipment, industrial and radiological safety systems, control and monitoring of operations, safeguards and security systems, and fire protection, ventilation and utilities systems. The Waste Treatment Building System also provides the required space and layout for maintenance activities, tool storage, and administrative facilities. The Waste Treatment Building System integrates waste processing systems within its protective structure to support the throughput rates established for the MGR. The Waste Treatment Building System also provides shielding, layout, and other design features to help limit personnel radiation exposures to levels which are as low as is reasonably achievable (ALARA). The Waste Treatment Building System interfaces with the Site Generated Radiological Waste Handling System, and with other MGR systems that support the waste processing operations. The Waste Treatment Building System interfaces with the General Site Transportation System, Site Communications System, Site Water System

  11. TRANSIENT SUPPRESSION PACKAGING FOR REDUCED EMISSIONS FROM ROTARY KILN INCINERATORS

    EPA Science Inventory

    Experiments were performed on a 73 kW rotary kiln incinerator simulator to determine whether innovative waste packaging designs might reduce transient emissions of products of incomplete combustion due to batch charging of containerized liquid surrogate waste compounds bound on g...

  12. Thermal hydrolysis integration in the anaerobic digestion process of different solid wastes: energy and economic feasibility study.

    PubMed

    Cano, R; Nielfa, A; Fdz-Polanco, M

    2014-09-01

    An economic assessment of thermal hydrolysis as a pretreatment to anaerobic digestion has been achieved to evaluate its implementation in full-scale plants. Six different solid wastes have been studied, among them municipal solid waste (MSW). Thermal hydrolysis has been tested with batch lab-scale tests, from which an energy and economic assessment of three scenarios is performed: with and without energy integration (recovering heat to produce steam in a cogeneration plant), finally including the digestate management costs. Thermal hydrolysis has lead to an increase of the methane productions (up to 50%) and kinetics parameters (even double). The study has determined that a proper energy integration design could lead to important economic savings (5 €/t) and thermal hydrolysis can enhance up to 40% the incomes of the digestion plant, even doubling them when digestate management costs are considered. In a full-scale MSW treatment plant (30,000 t/year), thermal hydrolysis would provide almost 0.5 M€/year net benefits. Copyright © 2014 Elsevier Ltd. All rights reserved.

  13. Use of thermal analysis techniques (TG-DSC) for the characterization of diverse organic municipal waste streams to predict biological stability prior to land application

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Fernandez, Jose M., E-mail: joseman@sas.upenn.edu; Plaza, Cesar; Polo, Alfredo

    2012-01-15

    Highlights: Black-Right-Pointing-Pointer Thermal analysis was used to assess stability and composition of organic matter in three diverse municipal waste streams. Black-Right-Pointing-Pointer Results were compared with C mineralization during 90-day incubation, FTIR and {sup 13}C NMR. Black-Right-Pointing-Pointer Thermal analysis reflected the differences between the organic wastes before and after the incubation. Black-Right-Pointing-Pointer The calculated energy density showed a strong correlation with cumulative respiration. Black-Right-Pointing-Pointer Conventional and thermal methods provide complimentary means of characterizing organic wastes. - Abstract: The use of organic municipal wastes as soil amendments is an increasing practice that can divert significant amounts of waste from landfill, and providesmore » a potential source of nutrients and organic matter to ameliorate degraded soils. Due to the high heterogeneity of organic municipal waste streams, it is difficult to rapidly and cost-effectively establish their suitability as soil amendments using a single method. Thermal analysis has been proposed as an evolving technique to assess the stability and composition of the organic matter present in these wastes. In this study, three different organic municipal waste streams (i.e., a municipal waste compost (MC), a composted sewage sludge (CS) and a thermally dried sewage sludge (TS)) were characterized using conventional and thermal methods. The conventional methods used to test organic matter stability included laboratory incubation with measurement of respired C, and spectroscopic methods to characterize chemical composition. Carbon mineralization was measured during a 90-day incubation, and samples before and after incubation were analyzed by chemical (elemental analysis) and spectroscopic (infrared and nuclear magnetic resonance) methods. Results were compared with those obtained by thermogravimetry (TG) and differential scanning calorimetry (DSC

  14. Thermal cycling fatigue of organic thermal interface materials using a thermal-displacement measurement technique

    NASA Astrophysics Data System (ADS)

    Steill, Jason Scott

    The long term reliability of polymer-based thermal interface materials (TIM) is essential for modern electronic packages which require robust thermal management. The challenge for today's materials scientists and engineers is to maximize the heat flow from integrated circuits through a TIM and out the heat sink. Thermal cycling of the electronic package and non-uniformity in the heat flux with respect to the plan area can lead to void formation and delamination which re-introduces inefficient heat transfer. Measurement and understanding at the nano-scale is essential for TIM development. Finding and documenting the evolution of the defects is dependent upon a full understanding of the thermal probes response to changing environmental conditions and the effects of probe usage. The response of the thermal-displacement measurement technique was dominated by changes to the environment. Accurate measurement of the thermal performance was hindered by the inability to create a model system and control the operating conditions. This research highlights the need for continued study into the probe's thermal and mechanical response using tightly controlled test conditions.

  15. Life and stability testing of packaged low-cost energy storage materials

    NASA Astrophysics Data System (ADS)

    Frysinger, G. R.

    1980-07-01

    A low-cost laminated plastic film which is used to contain a Glauber's salt-based phase change thermal energy storage material in sausage like containers called Chubs was developed. Results of tests performed on the Chub packages themselves and on the thermal energy storage capacity of the packaged phase change material are described. From the test results, a set of specifications was drawn up for a film material which will satisfactorily contain the phase change material under anticipated operating conditions. Calorimetric testing of the phase change material with thermal cycling indicates that a design capacity of 45 to 50 Btu/lb for a delta T of 30 F can be used for the packaged material.

  16. Food Packaging Materials

    NASA Technical Reports Server (NTRS)

    1978-01-01

    The photos show a few of the food products packaged in Alure, a metallized plastic material developed and manufactured by St. Regis Paper Company's Flexible Packaging Division, Dallas, Texas. The material incorporates a metallized film originally developed for space applications. Among the suppliers of the film to St. Regis is King-Seeley Thermos Company, Winchester, Ma'ssachusetts. Initially used by NASA as a signal-bouncing reflective coating for the Echo 1 communications satellite, the film was developed by a company later absorbed by King-Seeley. The metallized film was also used as insulating material for components of a number of other spacecraft. St. Regis developed Alure to meet a multiple packaging material need: good eye appeal, product protection for long periods and the ability to be used successfully on a wide variety of food packaging equipment. When the cost of aluminum foil skyrocketed, packagers sought substitute metallized materials but experiments with a number of them uncovered problems; some were too expensive, some did not adequately protect the product, some were difficult for the machinery to handle. Alure offers a solution. St. Regis created Alure by sandwiching the metallized film between layers of plastics. The resulting laminated metallized material has the superior eye appeal of foil but is less expensive and more easily machined. Alure effectively blocks out light, moisture and oxygen and therefore gives the packaged food long shelf life. A major packaging firm conducted its own tests of the material and confirmed the advantages of machinability and shelf life, adding that it runs faster on machines than materials used in the past and it decreases product waste; the net effect is increased productivity.

  17. Effect of device package on optical, spectral, and thermal properties of InGaN/GaN near-ultraviolet lateral light-emitting diodes

    NASA Astrophysics Data System (ADS)

    Lee, Soo Hyun; Guan, Xiang-Yu; Jeon, Soo-Kun; Yu, Jae Su

    2017-09-01

    We investigated the package effect on the temperature-dependent optical and spectral characteristics of InGaN/GaN near-ultraviolet (NUV) lateral light-emitting diodes (LLEDs) on the metal heatsink (MH) and package (PKG) in the injection current range of 0 - 500 mA at 298 and 358 K. For the NUV LLEDs on the MH, the device characteristics reflected directly its chip performance. For the NUV LLEDs on the PKG, the rapidly varied spectral shift as well as the reduced device efficiency was observed due to the increased number of layers with relatively low thermal conductivities. The junction temperature ( T j ) and thermal resistance of the NUV LLEDs on the PKG were also significantly increased compared to the NUV LLEDs on the MH. The three-dimensional heat transfer simulations for both the devices were carried out to obtain the temperature distributions by finite element method. The theoretically calculated T j values showed a good agreement with the experimentally measured T j values.

  18. Thermal conversion of municipal solid waste via hydrothermal carbonization: comparison of carbonization products to products from current waste management techniques.

    PubMed

    Lu, Xiaowei; Jordan, Beth; Berge, Nicole D

    2012-07-01

    Hydrothermal carbonization (HTC) is a novel thermal conversion process that may be a viable means for managing solid waste streams while minimizing greenhouse gas production and producing residual material with intrinsic value. HTC is a wet, relatively low temperature (180-350 °C) thermal conversion process that has been shown to convert biomass to a carbonaceous residue referred to as hydrochar. Results from batch experiments indicate HTC of representative waste materials is feasible, and results in the majority of carbon (45-75% of the initially present carbon) remaining within the hydrochar. Gas production during the batch experiments suggests that longer reaction periods may be desirable to maximize the production of energy-favorable products. If using the hydrochar for applications in which the carbon will remain stored, results suggest that the gaseous products from HTC result in fewer g CO(2)-equivalent emissions than the gases associated with landfilling, composting, and incineration. When considering the use of hydrochar as a solid fuel, more energy can be derived from the hydrochar than from the gases resulting from waste degradation during landfilling and anaerobic digestion, and from incineration of food waste. Carbon emissions resulting from the use of the hydrochar as a fuel source are smaller than those associated with incineration, suggesting HTC may serve as an environmentally beneficial alternative to incineration. The type and extent of environmental benefits derived from HTC will be dependent on hydrochar use/the purpose for HTC (e.g., energy generation or carbon storage). Copyright © 2012 Elsevier Ltd. All rights reserved.

  19. Thermal Interface Materials Selection and Application Guidelines: In Perspective of Xilinx Virtex-5QV Thermal Management

    NASA Technical Reports Server (NTRS)

    Suh, Jong-ook; Dillon, R. Peter; Tseng, Stephen

    2015-01-01

    The heat from high-power microdevices for space, such as Xilinx Virtex 4 and 5 (V4 and V5), has to be removed mainly through conduction in the space vacuum environment. The class-Y type packages are designed to remove the heat from the top of the package, and the most effective method to remove heat from the class-Y type packages is to attach a heat transfer device on the lid of the package and to transfer the heat to frame or chassis. When a heat transfer device is attached to the package lid, the surfaces roughness of the package lid and the heat transfer device reduces the effective contact area between the two. The reduced contact area results in increased thermal contact resistance, and a thermal interface material is required to reduce the thermal contact resistance by filling in the gap between the surfaces of the package lid and the heat transfer device. The current report describes JPL's FY14 NEPP task study on property requirements of TIM and impact of TIM properties on the packaging reliability. The current task also developed appratuses to investigate the performances of TIMs in the actual mission environment.

  20. On The Cusp of the New Spatial Challenges - The Thermal Waste Processing Plant as an Element of Urban Space

    NASA Astrophysics Data System (ADS)

    Wójtowicz-Wróbel, Agnieszka

    2017-10-01

    The goal of this paper is to answer the question about the current importance of structures associated with the thermal processing of waste within the space of Polish cities and what status can they have in the functional and spatial structure of Polish cities in the future. The construction of thermal waste processing plants in Poland is currently a new and important problem, with numerous structures of this type being built due to increasing care for the natural environment, with the introduction of legal regulations, as well as due to the possibility of obtaining large external funding for the purposes of undertaking pro-environmental spatial initiatives, etc. For this reason, the paper contains research on the increase in the number of thermal waste processing plants in Poland in recent years. The abovementioned data was compared with similar information from other European Union member states. In the group containing Polish thermal waste processing plants, research was performed regarding the stage of the construction of a plant (operating plant, plant under construction, design in a construction phase, etc.). The paper also contains a listing of the functions other than the basic form of use, which is the incineration of waste - similarly to numerous foreign examples - that the environmentally friendly waste incineration plants fulfil in Poland, dividing the additional forms of use into "hard" elements (at the design level, requiring the expansion of a building featuring new elements that are not directly associated with the basic purpose of waste processing) and soft (social, educational, promotional actions, as well as other endeavours that require human involvement, but that do not entail significant design work on the buildings itself, expanding its form of use, etc.) as well as mixed activity, which required design work, but on a relatively small scale. Research was also conducted regarding the placement of thermal waste processing plants within the

  1. Warpage of QFN Package in Post Mold Cure Process of integrated circuit packaging

    NASA Astrophysics Data System (ADS)

    Sriwithoon, Nattha; Ugsornrat, Kessararat; Srisuwitthanon, Warayoot; Thonglor, Panakamon

    2017-09-01

    This research studied about warpage of QFN package in post mold cure process of integrated circuit (IC) packages using pre-plated (PPF) leadframe. For IC package, epoxy molding compound (EMC) are molded by cross linking of compound stiffness but incomplete crosslinked network and leading the fully cured thermoset by post mold cure (PMC) process. The cure temperature of PMC can change microstructure of EMC in term of stress inside the package and effect to warpage of the package due to coefficient of thermal expansion (CTE) between EMC and leadframe. In experiment, cure temperatures were varied to check the effect of internal stress due to different cure temperature after completed post mold cure for TDFN 2×3 8L. The cure temperature were varied with 180 °C, 170 °C, 160 °C, and 150°C with cure time 4 and 6 hours, respectively. For analysis, the TDFN 2×3 8L packages were analyzed the warpage by thickness gauge and scanning acoustic microscope (SAM) after take the test samples out from the oven cure. The results confirmed that effect of different CTE between EMC and leadframe due to different cure temperature resulting to warpage of the TDFN 2×3 8L packages.

  2. Limitations to the use of two-dimensional thermal modeling of a nuclear waste repository

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Davis, B.W.

    1979-01-04

    Thermal modeling of a nuclear waste repository is basic to most waste management predictive models. It is important that the modeling techniques accurately determine the time-dependent temperature distribution of the waste emplacement media. Recent modeling studies show that the time-dependent temperature distribution can be accurately modeled in the far-field using a 2-dimensional (2-D) planar numerical model; however, the near-field cannot be modeled accurately enough by either 2-D axisymmetric or 2-D planar numerical models for repositories in salt. The accuracy limits of 2-D modeling were defined by comparing results from 3-dimensional (3-D) TRUMP modeling with results from both 2-D axisymmetric andmore » 2-D planar. Both TRUMP and ADINAT were employed as modeling tools. Two-dimensional results from the finite element code, ADINAT were compared with 2-D results from the finite difference code, TRUMP; they showed almost perfect correspondence in the far-field. This result adds substantially to confidence in future use of ADINAT and its companion stress code ADINA for thermal stress analysis. ADINAT was found to be somewhat sensitive to time step and mesh aspect ratio. 13 figures, 4 tables.« less

  3. Summary of Uranium Solubility Studies in Concrete Waste Forms and Vadose Zone Environments

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Golovich, Elizabeth C.; Wellman, Dawn M.; Serne, R. Jeffrey

    2011-09-30

    One of the methods being considered for safely disposing of Category 3 low-level radioactive wastes is to encase the waste in concrete. Concrete encasement would contain and isolate the waste packages from the hydrologic environment and act as an intrusion barrier. The current plan for waste isolation consists of stacking low-level waste packages on a trench floor, surrounding the stacks with reinforced steel, and encasing these packages in concrete. These concrete-encased waste stacks are expected to vary in size with maximum dimensions of 6.4 m long, 2.7 m wide, and 4 m high. The waste stacks are expected to havemore » a surrounding minimum thickness of 15 cm of concrete encasement. These concrete-encased waste packages are expected to withstand environmental exposure (solar radiation, temperature variations, and precipitation) until an interim soil cover or permanent closure cover is installed and to remain largely intact thereafter. Any failure of concrete encasement may result in water intrusion and consequent mobilization of radionuclides from the waste packages. This report presents the results of investigations elucidating the uranium mineral phases controlling the long-term fate of uranium within concrete waste forms and the solubility of these phases in concrete pore waters and alkaline, circum-neutral vadose zone environments.« less

  4. Low-cost CWDM transmitter package

    NASA Astrophysics Data System (ADS)

    Bhandarkar, Navin; Castillega, Jaime

    2005-03-01

    A low-cost coarse-wavelength-division multiplexer (CWDM) transmitter that combines four channels (wavelengths) in the infrared spectrum (~1310 nm) in a small form-factor un-cooled package is demonstrated. The package utilizes precision molded optics to multiplex beams from four grating-outcoupled surface-emitting (GSE) lasers into a single beam suitable for coupling into multimode fiber. This paper summarizes the optical and opto-mechanical design, fabrication and assembly of prototypes, and optical, thermal and electrical measurement results of the prototypes. This unique design enables multiplexing of wavelengths without the use of filters, waveguides, couplers and fiber splicing. Commercial fabrication and alignment technology is used to manufacture the package, resulting in a more robust, reliable and low-cost transmitter. The transmitter package is enabled by the unique characteristics of the long-wavelength GSE laser.

  5. Dangerous Waste Characteristics of Contact-Handled Transuranic Mixed Wastes from Hanford Tanks

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Tingey, Joel M.; Bryan, Garry H.; Deschane, Jaquetta R.

    2004-10-05

    This report summarizes existing analytical data gleaned from samples taken from the Hanford tanks designated as potentially containing transuranic mixed process wastes. Process knowledge of the wastes transferred to these tanks has been reviewed to determine whether the dangerous waste characteristics now assigned to all Hanford underground storage tanks are applicable to these particular wastes. Supplemental technologies are being examined to accelerate the Hanford tank waste cleanup mission and accomplish waste treatment safely and efficiently. To date, 11 Hanford waste tanks have been designated as potentially containing contact-handled (CH) transuranic mixed (TRUM) wastes. The CH-TRUM wastes are found in single-shellmore » tanks B-201 through B-204, T-201 through T-204, T-104, T-110, and T-111. Methods and equipment to solidify and package the CH-TRUM wastes are part of the supplemental technologies being evaluated. The resulting packages and wastes must be acceptable for disposal at the Waste Isolation Pilot Plant (WIPP). The dangerous waste characteristics being considered include ignitability, corrosivity, reactivity, and toxicity arising from the presence of 2,4,5-trichlorophenol at levels above the dangerous waste threshold. The analytical data reviewed include concentrations of sulfur, sulfate, cyanide, 2,4,5-trichlorophenol, total organic carbon, and oxalate; the composition of the tank headspace, pH, and mercury. Differential scanning calorimetry results were used to determine the energetics of the wastes as a function of temperature. This report supercedes and replaces PNNL-14832.« less

  6. Thermal oxidation of nuclear graphite: A large scale waste treatment option.

    PubMed

    Theodosiou, Alex; Jones, Abbie N; Marsden, Barry J

    2017-01-01

    This study has investigated the laboratory scale thermal oxidation of nuclear graphite, as a proof-of-concept for the treatment and decommissioning of reactor cores on a larger industrial scale. If showed to be effective, this technology could have promising international significance with a considerable impact on the nuclear waste management problem currently facing many countries worldwide. The use of thermal treatment of such graphite waste is seen as advantageous since it will decouple the need for an operational Geological Disposal Facility (GDF). Particulate samples of Magnox Reactor Pile Grade-A (PGA) graphite, were oxidised in both air and 60% O2, over the temperature range 400-1200°C. Oxidation rates were found to increase with temperature, with a particular rise between 700-800°C, suggesting a change in oxidation mechanism. A second increase in oxidation rate was observed between 1000-1200°C and was found to correspond to a large increase in the CO/CO2 ratio, as confirmed through gas analysis. Increasing the oxidant flow rate gave a linear increase in oxidation rate, up to a certain point, and maximum rates of 23.3 and 69.6 mg / min for air and 60% O2 respectively were achieved at a flow of 250 ml / min and temperature of 1000°C. These promising results show that large-scale thermal treatment could be a potential option for the decommissioning of graphite cores, although the design of the plant would need careful consideration in order to achieve optimum efficiency and throughput.

  7. Thermal oxidation of nuclear graphite: A large scale waste treatment option

    PubMed Central

    Jones, Abbie N.; Marsden, Barry J.

    2017-01-01

    This study has investigated the laboratory scale thermal oxidation of nuclear graphite, as a proof-of-concept for the treatment and decommissioning of reactor cores on a larger industrial scale. If showed to be effective, this technology could have promising international significance with a considerable impact on the nuclear waste management problem currently facing many countries worldwide. The use of thermal treatment of such graphite waste is seen as advantageous since it will decouple the need for an operational Geological Disposal Facility (GDF). Particulate samples of Magnox Reactor Pile Grade-A (PGA) graphite, were oxidised in both air and 60% O2, over the temperature range 400–1200°C. Oxidation rates were found to increase with temperature, with a particular rise between 700–800°C, suggesting a change in oxidation mechanism. A second increase in oxidation rate was observed between 1000–1200°C and was found to correspond to a large increase in the CO/CO2 ratio, as confirmed through gas analysis. Increasing the oxidant flow rate gave a linear increase in oxidation rate, up to a certain point, and maximum rates of 23.3 and 69.6 mg / min for air and 60% O2 respectively were achieved at a flow of 250 ml / min and temperature of 1000°C. These promising results show that large-scale thermal treatment could be a potential option for the decommissioning of graphite cores, although the design of the plant would need careful consideration in order to achieve optimum efficiency and throughput. PMID:28793326

  8. 49 CFR 173.197 - Regulated medical waste.

    Code of Federal Regulations, 2010 CFR

    2010-10-01

    ... (bio) medical waste must be rigid containers meeting the provisions of subpart B of this part. (b) Non... medical waste or clinical waste or (bio) medical waste must be UN standard packagings conforming to the... filled. (2) Liquids. Liquid regulated medical waste or clinical waste or (bio) medical waste transported...

  9. Geochemical data package for the Hanford immobilized low-activity tank waste performance assessment (ILAW PA)

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    DI Kaplan; RJ Serne

    Lockheed Martin Hanford Company (LMHC) is designing and assessing the performance of disposal facilities to receive radioactive wastes that are stored in single- and double-shell tanks at the Hanford Site. The preferred method of disposing of the portion that is classified as low-activity waste is to vitrify the liquid/slurry and place the solid product in near-surface, shallow-land burial facilities. The LMHC project to assess the performance of these disposal facilities is the Hanford Immobilized Low-Activity Tank Waste (ILAW) Performance Assessment (PA) activity. The goal of this project is to provide a reasonable expectation that the disposal of the waste ismore » protective of the general public, groundwater resources, air resources, surface-water resources, and inadvertent intruders. Achieving this goal will require prediction of contaminant migration from the facilities. This migration is expected to occur primarily via the movement of water through the facilities, and the consequent transport of dissolved contaminants in the porewater of the vadose zone. Pacific Northwest National Laboratory assists LMHC in their performance assessment activities. One of the PNNL tasks is to provide estimates of the geochemical properties of the materials comprising the disposal facility, the disturbed region around the facility, and the physically undisturbed sediments below the facility (including the vadose zone sediments and the aquifer sediments in the upper unconfined aquifer). The geochemical properties are expressed as parameters that quantify the adsorption of contaminants and the solubility constraints that might apply for those contaminants that may exceed solubility constraints. The common parameters used to quantify adsorption and solubility are the distribution coefficient (K{sub d}) and the thermodynamic solubility product (K{sub sp}), respectively. In this data package, the authors approximate the solubility of contaminants using a more simplified

  10. Thermal/structural modeling of a large scale in situ overtest experiment for defense high level waste at the Waste Isolation Pilot Plant Facility

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Morgan, H.S.; Stone, C.M.; Krieg, R.D.

    Several large scale in situ experiments in bedded salt formations are currently underway at the Waste Isolation Pilot Plant (WIPP) near Carlsbad, New Mexico, USA. In these experiments, the thermal and creep responses of salt around several different underground room configurations are being measured. Data from the tests are to be compared to thermal and structural responses predicted in pretest reference calculations. The purpose of these comparisons is to evaluate computational models developed from laboratory data prior to fielding of the in situ experiments. In this paper, the computational models used in the pretest reference calculation for one of themore » large scale tests, The Overtest for Defense High Level Waste, are described; and the pretest computed thermal and structural responses are compared to early data from the experiment. The comparisons indicate that computed and measured temperatures for the test agree to within ten percent but that measured deformation rates are between two and three times greater than corresponsing computed rates. 10 figs., 3 tabs.« less

  11. Solidification and Biotoxicity Assessment of Thermally Treated Municipal Solid Waste Incineration (MSWI) Fly Ash

    PubMed Central

    Gong, Bing; Deng, Yi; Yang, Yuanyi; Tan, Swee Ngin; Liu, Qianni; Yang, Weizhong

    2017-01-01

    In the present work, thermal treatment was used to stabilize municipal solid waste incineration (MSWI) fly ash, which was considered hazardous waste. Toxicity characteristic leaching procedure (TCLP) results indicated that, after the thermal process, the leaching concentrations of Pb, Cu, and Zn decreased from 8.08 to 0.16 mg/L, 0.12 to 0.017 mg/L and 0.39 to 0.1 mg/L, respectively, which well met the limits in GB5085.3-2007 and GB16689-2008. Thermal treatment showed a negative effect on the leachability of Cr with concentrations increasing from 0.1 to 1.28 mg/L; nevertheless, it was still under the limitations. XRD analysis suggested that, after thermal treatments, CaO was newly generated. CaO was a main contribution to higher Cr leaching concentrations owing to the formation of Cr (VI)—compounds such as CaCrO4. SEM/EDS tests revealed that particle adhesion, agglomeration, and grain growth happened during the thermal process and thus diminished the leachability of Pb, Cu, and Zn, but these processes had no significant influence on the leaching of Cr. A microbial assay demonstrated that all thermally treated samples yet possessed strong bactericidal activity according to optical density (OD) test results. Among all samples, the OD value of raw fly ash (RFA) was lowest followed by FA700-10, FA900-10, and FA1100-10 in an increasing order, which indicated that the sequence of the biotoxicity for these samples was RFA > FA700-10 > FA900-10 > FA1100-10. This preliminary study indicated that, apart from TCLP criteria, the biotoxicity assessment was indispensable for evaluating the effect of thermal treatment for MSWI fly ash. PMID:28604580

  12. Cleanup Verification Package for the 618-8 Burial Ground

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    M. J. Appel

    2006-08-10

    This cleanup verification package documents completion of remedial action for the 618-8 Burial Ground, also referred to as the Solid Waste Burial Ground No. 8, 318-8, and the Early Solid Waste Burial Ground. During its period of operation, the 618-8 site is speculated to have been used to bury uranium-contaminated waste derived from fuel manufacturing, and construction debris from the remodeling of the 313 Building.

  13. Impact of external influences on food packaging.

    PubMed

    Brody, A L

    1977-09-01

    Since the food supply is dependent upon an effective packaging system, threats to packaging represent implied threats to food processing and distribution. Enacted and potential legislation and regulation are retarding technological and commercial progress in food packaging and have already restricted some food packaging/processins systems. The results of these external influences is not simply the sum of the individual acts, but is a cascading self-imposed arresting of food packaging/processing advancement. The technological bases for the enacted and proposed legislation and regulation are presented in the enumeration of the external influences on food packaging. Economic and sociological arguments and facts surrounding the issues are also presented. Among the external influences on food packaging detailed are indirect additives, nutritional labeling, benefit:risk, solid waste and litter, environmental pollution, universal product code, and food industry productivity. The magnitude of the total impact of these external influences upon the food supply is so large that assertive action must be taken to channel these influences into more productive awareness. An objective and comprehensive public communications program supported by the technological community appears mandatory.

  14. Industrial waste materials and by-products as thermal energy storage (TES) materials: A review

    NASA Astrophysics Data System (ADS)

    Gutierrez, Andrea; Miró, Laia; Gil, Antoni; Rodríguez-Aseguinolaza, Javier; Barreneche, Camila; Calvet, Nicolas; Py, Xavier; Fernández, A. Inés; Grágeda, Mario; Ushak, Svetlana; Cabeza, Luisa F.

    2016-05-01

    A wide variety of potential materials for thermal energy storage (TES) have been identify depending on the implemented TES method, Sensible, latent or thermochemical. In order to improve the efficiency of TES systems more alternatives are continuously being sought. In this regard, this paper presents the review of low cost heat storage materials focused mainly in two objectives: on the one hand, the implementation of improved heat storage devices based on new appropriate materials and, on the other hand, the valorisation of waste industrial materials will have strong environmental, economic and societal benefits such as reducing the landfilled waste amounts, reducing the greenhouse emissions and others. Different industrial and municipal waste materials and by products have been considered as potential TES materials and have been characterized as such. Asbestos containing wastes, fly ashes, by-products from the salt industry and from the metal industry, wastes from recycling steel process and from copper refining process and dross from the aluminium industry, and municipal wastes (glass and nylon) have been considered. This work shows a great revalorization of wastes and by-product opportunity as TES materials, although more studies are needed to achieve industrial deployment of the idea.

  15. Development of low thermal conductivity brick using rice husk, corn cob and waste tea in clay brick manufacturing

    NASA Astrophysics Data System (ADS)

    Saman, Nor Sarwani Mat; Deraman, Rafikullah; Hamzah, Mohamad Hazmi

    2017-12-01

    The consumption of energy for cooling the indoor environment of buildings in Malaysia is high and mostly related to poor thermal performance of the building envelope. It is evident that reducing energy consumption of buildings has become vital, taking into considerations the limitation of conventional energy resources and the adverse effects associated with the use of such type of energy on the environment. Therefore, selecting the proper thermal properties of a building envelope play a major role in determining the energy consumption patterns and comfort conditions in enclosed spaces. The objective of this study is to investigate the potential application of rice husk (RH), corn cob (CC) and waste tea (WT) as an additive agent in a fired clay brick manufacturing to produce an improved thermal conductivity of final brick product. In the execution of this study, these agricultural wastes were mixed together with clay soil in different percentages, ranging from 0 %, 2.5 %, 5 %, 7.5 % and 10 % by weight. Physical and mechanical properties including soil physical properties, density, shrinkage, water absorption, compressive strength as well as thermal conductivity were measured, reported and discussed in accordance with BS 1377: Part 2: 1990, BS 3921: 1985, MS 76: 1972: Part 2 and ASTM C 518. The results show that RH at 7.5 % is the most effective combination to achieve low thermal conductivity of fired clay brick. This finding suggests that RH waste is a potentially good additive material to be used for thermal properties enhancement of the building envelope.

  16. Thermohydrological conditions and silica redistribution near high-level nuclear wastes emplaced in saturated geological formations

    NASA Astrophysics Data System (ADS)

    Verma, A.; Pruess, K.

    1988-02-01

    Evaluation of the thermohydrological conditions near high-level nuclear waste packages is needed for the design of the waste canister and for overall repository design and performance assessment. Most available studies in this area have assumed that the hydrologic properties of the host rock are not changed in response to the thermal, mechanical, or chemical effects caused by waste emplacement. However, the ramifications of this simplifying assumption have not been substantiated. We have studied dissolution and precipitation of silica in liquid-saturated hydrothermal flow systems, including changes in formation porosity and permeability. Using numerical simulation, we compare predictions of thermohydrological conditions with and without inclusion of silica redistribution effects. Two cases were studied, namely, a canister-scale problem, and a repository-wide thermal convection problem and different pore models were employed for the permeable medium (fractures with uniform or nonuniform cross sections). We find that silica redistribution in water-saturated conditions does not have a sizeable effect on host rock and canister temperatures, pore pressures, or flow velocities.

  17. Finite element code FENIA verification and application for 3D modelling of thermal state of radioactive waste deep geological repository

    NASA Astrophysics Data System (ADS)

    Butov, R. A.; Drobyshevsky, N. I.; Moiseenko, E. V.; Tokarev, U. N.

    2017-11-01

    The verification of the FENIA finite element code on some problems and an example of its application are presented in the paper. The code is being developing for 3D modelling of thermal, mechanical and hydrodynamical (THM) problems related to the functioning of deep geological repositories. Verification of the code for two analytical problems has been performed. The first one is point heat source with exponential heat decrease, the second one - linear heat source with similar behavior. Analytical solutions have been obtained by the authors. The problems have been chosen because they reflect the processes influencing the thermal state of deep geological repository of radioactive waste. Verification was performed for several meshes with different resolution. Good convergence between analytical and numerical solutions was achieved. The application of the FENIA code is illustrated by 3D modelling of thermal state of a prototypic deep geological repository of radioactive waste. The repository is designed for disposal of radioactive waste in a rock at depth of several hundred meters with no intention of later retrieval. Vitrified radioactive waste is placed in the containers, which are placed in vertical boreholes. The residual decay heat of radioactive waste leads to containers, engineered safety barriers and host rock heating. Maximum temperatures and corresponding times of their establishment have been determined.

  18. Using dairy ingredients to produce edible films and biodegradable packaging materials

    USDA-ARS?s Scientific Manuscript database

    Food packaging is comprised of multi-layers of films which are thin continuous sheets of synthetic polymers. Recently, major food retailers and consumers have become concerned about the waste that packaging generates and the scarce natural resources and energy used in its manufacture. They are deman...

  19. Thermal destruction of wastes containing polychlorinated naphthalenes in an industrial waste incinerator.

    PubMed

    Yamamoto, Takashi; Noma, Yukio; Sakai, Shin-Ichi

    2016-07-02

    A series of verification tests were carried out in order to confirm that polychlorinated naphthalenes (PCNs) contained in synthetic rubber products (Neoprene FB products) and aerosol adhesives, which were accidentally imported into Japan, could be thermally destroyed using an industrial waste incinerator. In the verification tests, Neoprene FB products containing PCNs at a concentration of 2800 mg/kg were added to industrial wastes at a ratio of 600 mg Neoprene FB product/kg-waste, and then incinerated at an average temperature of 985 °C. Total PCN concentrations were 14 ng/m 3 N in stack gas, 5.7 ng/g in bottom ash, 0.98 ng/g in boiler dust, and 1.2 ng/g in fly ash. Destruction efficiency (DE) and destruction removal efficiency (DRE) of congener No. 38/40, which is considered an input marker congener, were 99.9974 and 99.9995 %, respectively. The following dioxin concentrations were found: 0.11 ng-TEQ/m 3 N for the stack gas, 0.096 ng-TEQ/g for the bottom ash, 0.010 ng-TEQ/g for the boiler dust, and 0.072 ng-TEQ/g for the fly ash. Since the PCN levels in the PCN destruction test were even at slightly lower concentrations than in the baseline test without PCN addition, the detected PCNs are to a large degree unintentionally produced PCNs and does not mainly stem from input material. Also, the dioxin levels did not change. From these results, we confirmed that PCNs contained in Neoprene FB products and aerosol adhesives could be destroyed to a high degree by high-temperature incineration. Therefore, all recalled Neoprene FB products and aerosol adhesives containing PCNs were successfully treated under the same conditions as the verification tests.

  20. Dangerous Waste Characteristics of Contact-Handled Transuranic Mixed Wastes from the Hanford Tanks

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Tingey, Joel M.; Bryan, Garry H.; Deschane, Jaquetta R.

    2004-08-31

    This report summarizes existing analytical data from samples taken from the Hanford tanks designated as potentially containing transuranic mixed process wastes. Process knowledge of the wastes transferred to these tanks has been reviewed to determine whether the dangerous waste characteristics now assigned to all Hanford underground storage tanks are applicable to these particular wastes. Supplemental technologies are being examined to accelerate the Hanford tank waste cleanup mission and accomplish waste treatment safely and efficiently. To date, 11 Hanford waste tanks have been designated as potentially containing contact-handled (CH) transuranic mixed (TRUM) wastes. The CH-TRUM wastes are found in single-shell tanksmore » B-201 through B-204, T-201 through T-204, T-104, T-110, and T-111. Methods and equipment to solidify and package the CH-TRUM wastes are part of the supplemental technologies being evaluated. The resulting packages and wastes must be acceptable for disposal at the Waste Isolation Pilot Plant (WIPP). The dangerous waste characteristics being considered include ignitability, corrosivity, reactivity, and toxicity arising from the presence of 2,4,5-trichlorophenol at levels above the dangerous waste threshold. The analytical data reviewed include concentrations of sulfur, sulfate, cyanide, 2,4,5-trichlorophenol, total organic carbon, and oxalate; the composition of the tank headspace, pH, and mercury. Differential scanning calorimetry results were used to determine the energetics of the wastes as a function of temperature.« less

  1. Seafood Packaging

    NASA Technical Reports Server (NTRS)

    1996-01-01

    NASA's Technology Transfer Office at Stennis Space Center worked with a New Orleans seafood packaging company to develop a container to improve the shipping longevity of seafood, primarily frozen and fresh fish, while preserving the taste. A NASA engineer developed metalized heat resistant polybags with thermal foam liners using an enhanced version of the metalized mylar commonly known as 'space blanket material,' which was produced during the Apollo era.

  2. Waste heat generation: A comprehensive review.

    PubMed

    Yeşiller, Nazli; Hanson, James L; Yee, Emma H

    2015-08-01

    A comprehensive review of heat generation in various types of wastes and of the thermal regime of waste containment facilities is provided in this paper. Municipal solid waste (MSW), MSW incineration ash, and mining wastes were included in the analysis. Spatial and temporal variations of waste temperatures, thermal gradients, thermal properties of wastes, average temperature differentials, and heat generation values are provided. Heat generation was influenced by climatic conditions, mean annual earth temperatures, waste temperatures at the time of placement, cover conditions, and inherent heat generation potential of the specific wastes. Time to onset of heat generation varied between months and years, whereas timelines for overall duration of heat generation varied between years and decades. For MSW, measured waste temperatures were as high as 60-90°C and as low as -6°C. MSW incinerator ash temperatures varied between 5 and 87°C. Mining waste temperatures were in the range of -25 to 65°C. In the wastes analyzed, upward heat flow toward the surface was more prominent than downward heat flow toward the subsurface. Thermal gradients generally were higher for MSW and incinerator ash and lower for mining waste. Based on thermal properties, MSW had insulative qualities (low thermal conductivity), while mining wastes typically were relatively conductive (high thermal conductivity) with ash having intermediate qualities. Heat generation values ranged from -8.6 to 83.1MJ/m(3) and from 0.6 to 72.6MJ/m(3) for MSW and mining waste, respectively and was 72.6MJ/m(3) for ash waste. Conductive thermal losses were determined to range from 13 to 1111MJ/m(3)yr. The data and analysis provided in this review paper can be used in the investigation of heat generation and thermal regime of a wide range of wastes and waste containment facilities located in different climatic regions. Copyright © 2015 Elsevier Ltd. All rights reserved.

  3. Natural biopolymer-based nanocomposite films for packaging applications.

    PubMed

    Rhim, Jong-Whan; Ng, Perry K W

    2007-01-01

    Concerns on environmental waste problems caused by non-biodegradable petrochemical-based plastic packaging materials as well as the consumer's demand for high quality food products has caused an increasing interest in developing biodegradable packaging materials using annually renewable natural biopolymers such as polysaccharides and proteins. Inherent shortcomings of natural polymer-based packaging materials such as low mechanical properties and low water resistance can be recovered by applying a nanocomposite technology. Polymer nanocomposites, especially natural biopolymer-layered silicate nanocomposites, exhibit markedly improved packaging properties due to their nanometer size dispersion. These improvements include increased modulus and strength, decreased gas permeability, and increased water resistance. Additionally, biologically active ingredients can be added to impart the desired functional properties to the resulting packaging materials. Consequently, natural biopolymer-based nanocomposite packaging materials with bio-functional properties have a huge potential for application in the active food packaging industry. In this review, recent advances in the preparation of natural biopolymer-based films and their nanocomposites, and their potential use in packaging applications are addressed.

  4. Radiation and Thermal Effects on Used Nuclear Fuel and Nuclear Waste Forms

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Weber, William J.; Zhang, Yanwen

    This is the final report of the NEUP project “Radiation and Thermal Effects on Used Nuclear Fuel and Nuclear Waste Forms.” This project started on July 1, 2012 and was successfully completed on June 30, 2016. This report provides an overview of the main achievements, results and findings through the duration of the project. Additional details can be found in the main body of this report and in the individual Quarterly Reports and associated Deliverables of this project, which have been uploaded in PICS-NE. The objective of this research was to advance understanding and develop validated models on the effectsmore » of self-radiation from beta and alpha decay on the response of used nuclear fuel and nuclear waste forms during high-temperature interim storage and long-term permanent disposition. To achieve this objective, model used-fuel materials and model waste form materials were identified, fabricated, and studied.« less

  5. The study of the mobile compressor unit heat losses recovery system waste heat exchanger thermal insulation types influence on the operational efficiency

    NASA Astrophysics Data System (ADS)

    Yusha, V. L.; Chernov, G. I.; Kalashnikov, A. M.

    2017-08-01

    The paper examines the mobile compressor unit (MCU) heat losses recovery system waste heat exchanger prototype external thermal insulation types influence on the operational efficiency. The study is conducted by means of the numerical method through the modellingof the heat exchange processes carried out in the waste heat exchanger in ANSUS. Thermaflex, mineral wool, penofol, water and air were applied as the heat exchanger external insulation. The study results showed the waste heat exchanger external thermal insulationexistence or absence to have a significant impact on the heat exchanger operational efficiency.

  6. Catalytic thermal cracking of post-consumer waste plastics to fuels: Part 1 - Kinetics and optimization

    USDA-ARS?s Scientific Manuscript database

    Thermogravimetric analysis (TGA) was used to investigate thermal and catalytic pyrolysis of waste plastics such as prescription bottles (polypropylene/PP), high density polyethylene, landfill liners (polyethylene/PE), packing materials (polystyrene/PS), and foams (polyurethane/PU) into crude plastic...

  7. Natural biopolimers in organic food packaging

    NASA Astrophysics Data System (ADS)

    Wieczynska, Justyna; Cavoski, Ivana; Chami, Ziad Al; Mondelli, Donato; Di Donato, Paola; Di Terlizzi, Biagio

    2014-05-01

    Concerns on environmental and waste problems caused by use of non-biodegradable and non-renewable based plastic packaging have caused an increase interest in developing biodegradable packaging using renewable natural biopolymers. Recently, different types of biopolymers like starch, cellulose, chitosan, casein, whey protein, collagen, egg white, soybean protein, corn zein, gelatin and wheat gluten have attracted considerable attention as potential food packaging materials. Recyclable or biodegradable packaging material in organic processing standards is preferable where possible but specific principles of packaging are not precisely defined and standards have to be assessed. There is evidence that consumers of organic products have specific expectations not only with respect to quality characteristics of processed food but also in social and environmental aspects of food production. Growing consumer sophistication is leading to a proliferation in food eco-label like carbon footprint. Biopolymers based packaging for organic products can help to create a green industry. Moreover, biopolymers can be appropriate materials for the development of an active surfaces designed to deliver incorporated natural antimicrobials into environment surrounding packaged food. Active packaging is an innovative mode of packaging in which the product and the environment interact to prolong shelf life or enhance safety or sensory properties, while maintaining the quality of the product. The work will discuss the various techniques that have been used for development of an active antimicrobial biodegradable packaging materials focusing on a recent findings in research studies. With the current focus on exploring a new generation of biopolymer-based food packaging materials with possible applications in organic food packaging. Keywords: organic food, active packaging, biopolymers , green technology

  8. Romanian experience on packaging testing

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Vieru, G.

    2007-07-01

    With more than twenty years ago, the Institute for Nuclear Research Pitesti (INR), through its Reliability and Testing Laboratory, was licensed by the Romanian Nuclear Regulatory Body- CNCAN and to carry out qualification tests [1] for packages intended to be used for the transport and storage of radioactive materials. Radioactive materials, generated by Romanian nuclear facilities [2] are packaged in accordance with national [3] and the IAEA's Regulations [1,6] for a safe transport to the disposal center. Subjecting these packages to the normal and simulating test conditions accomplish the evaluation and certification in order to prove the package technical performances.more » The paper describes the qualification tests for type A and B packages used for transport and storage of radioactive materials, during a period of 20 years of experience. Testing is used to substantiate assumption in analytical models and to demonstrate package structural response. The Romanian test facilities [1,3,6] are used to simulate the required qualification tests and have been developed at INR Pitesti, the main supplier of type A packages used for transport and storage of low radioactive wastes in Romania. The testing programme will continue to be a strong option to support future package development, to perform a broad range of verification and certification tests on radioactive material packages or component sections, such as packages used for transport of radioactive sources to be used for industrial or medical purposes [2,8]. The paper describes and contain illustrations showing some of the various tests packages which have been performed during certain periods and how they relate to normal conditions and minor mishaps during transport. Quality assurance and quality controls measures taken in order to meet technical specification provided by the design there are also presented and commented. (authors)« less

  9. Active cooling of microvascular composites for battery packaging

    NASA Astrophysics Data System (ADS)

    Pety, Stephen J.; Chia, Patrick X. L.; Carrington, Stephen M.; White, Scott R.

    2017-10-01

    Batteries in electric vehicles (EVs) require a packaging system that provides both thermal regulation and crash protection. A novel packaging scheme is presented that uses active cooling of microvascular carbon fiber reinforced composites to accomplish this multifunctional objective. Microvascular carbon fiber/epoxy composite panels were fabricated and their cooling performance assessed over a range of thermal loads and experimental conditions. Tests were performed for different values of coolant flow rate, channel spacing, panel thermal conductivity, and applied heat flux. More efficient cooling occurs when the coolant flow rate is increased, channel spacing is reduced, and thermal conductivity of the host composite is increased. Computational fluid dynamics (CFD) simulations were also performed and correlate well with the experimental data. CFD simulations of a typical EV battery pack confirm that microvascular composite panels can adequately cool battery cells generating 500 W m-2 heat flux below 40 °C.

  10. Investigating the effectiveness of using agricultural wastes from empty fruit bunch (EFB), coconut fibre (CF) and sugarcane baggasse (SB) to produce low thermal conductivity clay bricks

    NASA Astrophysics Data System (ADS)

    Hamzah, Mohamad Hazmi; Deraman, Rafikullah; Saman, Nor Sarwani Mat

    2017-12-01

    In Malaysia, 45% of the average household electricity was consumed by air conditioners to create an acceptable indoor environment. This high energy consumption was mostly related to poor thermal performance of the building envelope. Therefore, selecting a low thermal conductivity of brick wall was of considerable importance in creating energy efficient buildings. Previously, numerous researchers reported the potential used of agricultural waste as an additive in building materials to enhance their thermal properties. The aim of this study is to examine how agricultural wastes from empty fruit bunch (EFB), coconut fibre (CF) and sugarcane bagasse (SB) can act as additive agents in a fired clay brick manufacturing process to produce a low thermal conductivity clay brick. In this study, these agricultural wastes were individually mixed with clay soil in different proportions ranging from 0%, 2.5%, 5%, 7.5% and 10% by weight. Physical and mechanical properties including soil physical properties, as well as thermal conductivity were performed in accordance with BS 1377: Part 2: 1990, BS 3921: 1985 and ASTM C518. The results reveal that incorporating 5% of EFB as an additive component into the brick making process significantly enhances the production of a low thermal conductivity clay brick as compared to other waste alternatives tested. This finding suggests that EFB waste was a potential additive material to be used for the thermal property enhancement of the building envelope.

  11. Qualification and Reliability for MEMS and IC Packages

    NASA Technical Reports Server (NTRS)

    Ghaffarian, Reza

    2004-01-01

    Advanced IC electronic packages are moving toward miniaturization from two key different approaches, front and back-end processes, each with their own challenges. Successful use of more of the back-end process front-end, e.g. microelectromechanical systems (MEMS) Wafer Level Package (WLP), enable reducing size and cost. Use of direct flip chip die is the most efficient approach if and when the issues of know good die and board/assembly are resolved. Wafer level package solve the issue of known good die by enabling package test, but it has its own limitation, e.g., the I/O limitation, additional cost, and reliability. From the back-end approach, system-in-a-package (SIAP/SIP) development is a response to an increasing demand for package and die integration of different functions into one unit to reduce size and cost and improve functionality. MEMS add another challenging dimension to electronic packaging since they include moving mechanical elements. Conventional qualification and reliability need to be modified and expanded in most cases in order to detect new unknown failures. This paper will review four standards that already released or being developed that specifically address the issues on qualification and reliability of assembled packages. Exposures to thermal cycles, monotonic bend test, mechanical shock and drop are covered in these specifications. Finally, mechanical and thermal cycle qualification data generated for MEMS accelerometer will be presented. The MEMS was an element of an inertial measurement unit (IMU) qualified for NASA Mars Exploration Rovers (MERs), Spirit and Opportunity that successfully is currently roaring the Martian surface

  12. Characteristics of Polybrominated Diphenyl Ethers Released from Thermal Treatment and Open Burning of E-Waste.

    PubMed

    Li, Ting-Yu; Zhou, Jun-Feng; Wu, Chen-Chou; Bao, Lian-Jun; Shi, Lei; Zeng, Eddy Y

    2018-04-17

    Primitive processing of e-waste potentially releases abundant organic contaminants to the environment, but the magnitudes and mechanisms remain to be adequately addressed. We conducted thermal treatment and open burning of typical e-wastes, that is, plastics and printed circuit boards. Emission factors of the sum of 39 polybrominated diphenyl ethers (∑ 39 PBDE) were 817-1.60 × 10 5 ng g -1 in thermal treatment and nondetected-9.14 × 10 4 ng g -1 , in open burning. Airborne particles (87%) were the main carriers of PBDEs, followed by residual ashes (13%) and gaseous constituents (0.3%), in thermal treatment, while they were 30%, 43% and 27% in open burning. The output-input mass ratios of ∑ 39 PBDE were 0.12-3.76 in thermal treatment and 0-0.16 in open burning. All PBDEs were largely affiliated with fine particles, with geometric mean diameters at 0.61-0.83 μm in thermal degradation and 0.57-1.16 μm in open burning from plastic casings, and 0.44-0.56 and nondetected- 0.55 μm, from printed circuit boards. Evaporation and reabsorption may be the main emission mechanisms for lightly brominated BDEs, but heavily brominated BDEs tend to affiliate with particles from heating or combustion. The different size distributions of particulate PBDEs in emission sources and adjacent air implicated a noteworthy redisposition process during atmospheric dispersal.

  13. A pyrolysis study for the thermal and kinetic characteristics of an agricultural waste with two different plastic wastes.

    PubMed

    Çepelioğullar, Özge; Pütün, Ayşe E

    2014-10-01

    In this study, thermochemical conversion of plastic wastes (PET and PVC) together with an agricultural waste (hazelnut shell) was investigated. In order to determine the thermal and kinetic behaviours, pyrolysis experiments were carried out from room temperature to 800 °C, with a heating rate of 10 °C min(-1) in the presence of a N2 atmosphere in a thermogravimetric analyzer. With the obtained thermogravimetric data, an appropriate temperature was specified for the pyrolysis of biomass-plastic wastes in a fixed-bed reactor. At the second step, pyrolysis experiments were carried out at the same conditions with the thermogravimetric analyzer, except the final temperature which was up to 500 °C in this case. After pyrolysis experiments, pyrolysis yields were calculated and characterization studies for bio-oil were investigated. Experimental results showed that co-pyrolysis has an important role in the determination of the pyrolysis mechanism and the process conditions while designing/implementing a thermochemical conversion method where biomass-plastic materials were preferred as raw materials. © The Author(s) 2014.

  14. Starch plastics packaging and agriculture applications

    USDA-ARS?s Scientific Manuscript database

    The environmental impact of petroleum-based plastics is a growing concern throughout the world. Containers and packaging comprise the largest sector of municipal solid waste and are a major component of pollution on both land and sea. Although the benefits of plastics in many consumer and industrial...

  15. Thermal disposal of waste containing nanomaterials: first investigations on a methodology for risk management

    NASA Astrophysics Data System (ADS)

    Ounoughene, G.; LeBihan, O.; Debray, B.; Chivas-Joly, C.; Longuet, C.; Joubert, A.; Lopez-Cuesta, J.-M.; Le Coq, L.

    2017-06-01

    Considering the wide use and production of NMs since last two decades, these trendy nanomaterials (NMs) are expected to end up in thermal disposal and waste incineration plants (WIP). It seems relevant to assess the risks related to the thermal disposal and incineration of waste containing NMs (WCNMs). The objective of this work is to present a first approach to develop a preliminary methodology for risk management in order (1) to give insights on nanosafety of exposed operators and on potential environmental risks related to the incineration and thermal disposal of WCNMs, and (2) to eventually support decision-makers and incineration plant managers. Therefore, the main challenge is to find (a) key parameter(s) which would govern the decision related to risk management of NMs thermal disposal. On the one hand, we focused on the relevant literature studies about experimental works on incineration of NMs. On the other hand, we conducted an introductory discussion with a group of experts. The review of this literature highlights that the nano-object’s nanostructure destruction appears as a relevant indicator of the risks related to the NMs incineration. As a consequence, we defined a “temperature of nanostructure destruction” (TND) which would be the temperature from which the nanostructure will be destroyed. This parameter has been assumed to be a consistent indicator to develop a preliminary methodology. If the combustion chamber temperature is higher than the TND of the NM (or if they are close to each other), then the nanostructure will be destroyed and no risks related to NMs remain. If the TND of the NMs is higher than the combustion chamber temperature, then the nanostructure will not be destroyed and risks related to NMs have to be considered. As a result, five groups of NMs have been identified. WCNMs including carbonic NMs appear to be in good position to be destroyed safely in WIP. On the other hand, based on this criterion, there would be no

  16. Pressure Build-Up During the Fire Test in Type B(U) Packages Containing Water - 13280

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Feldkamp, Martin; Nehrig, Marko; Bletzer, Claus

    The safety assessment of packages for the transport of radioactive materials with content containing liquids requires special consideration. The main focus is on water as supplementary liquid content in Type B(U) packages. A typical content of a Type B(U) package is ion exchange resin, waste of a nuclear power plant, which is not dried, normally only drained. Besides the saturated ion exchange resin, a small amount of free water can be included in these contents. Compared to the safety assessment of packages with dry content, attention must be paid to some more specific issues. An overview of these issues ismore » provided. The physical and chemical compatibility of the content itself and the content compatibility with the packages materials must be demonstrated for the assessment. Regarding the mechanical resistance the package has to withstand the forces resulting from the freezing liquid. The most interesting point, however, is the pressure build-up inside the package due to vaporization. This could for example be caused by radiolysis of the liquid and must be taken into account for the storage period. If the package is stressed by the total inner pressure, this pressure leads to mechanical loads to the package body, the lid and the lid bolts. Thus, the pressure is the driving force on the gasket system regarding the activity release and a possible loss of tightness. The total pressure in any calculation is the sum of partial pressures of different gases which can be caused by different effects. The pressure build-up inside the package caused by the regulatory thermal test (30 min at 800 deg. C), as part of the cumulative test scenario under accident conditions of transport is discussed primarily. To determine the pressure, the temperature distribution in the content must be calculated for the whole period from beginning of the thermal test until cooling-down. In this case, while calculating the temperature distribution, conduction and radiation as well as

  17. Residues from the thermal conversion of waste from the meat industry as a source of valuable macro- and micronutrients.

    PubMed

    Staroń, Paweł; Kowalski, Zygmunt; Staroń, Anita; Seidlerová, Jana; Banach, Marcin

    2016-03-01

    The increased consumption of meat (including poultry) observed over the last decade has led to the intensification of its production. With the production increase, the amount of generated waste also increases. Appropriate disposal of waste from the meat industry will significantly reduce the amount of such waste and its negative impact on the environment. The paper presents a method for the thermal neutralisation of feathers, poultry litter and meat and bone meal (MBM). Waste incineration was carried out in a stationary electric furnace, at a temperature varying in the range of 600-900°C. The resulting ashes were characterised by a high percentage of phosphorus (30-170 g/kg ash), calcium (20-360 g/kg ash) and other valuable macro- and micronutrients like copper, iron, manganese and zinc. The ashes produced during the thermal treatment are safe in terms of sanitary and can be used as additives enriching the fertilisers and soil improvers. Copyright © 2016 Elsevier Ltd. All rights reserved.

  18. Laser Welding in Electronic Packaging

    NASA Technical Reports Server (NTRS)

    2000-01-01

    The laser has proven its worth in numerous high reliability electronic packaging applications ranging from medical to missile electronics. In particular, the pulsed YAG laser is an extremely flexible and versatile too] capable of hermetically sealing microelectronics packages containing sensitive components without damaging them. This paper presents an overview of details that must be considered for successful use of laser welding when addressing electronic package sealing. These include; metallurgical considerations such as alloy and plating selection, weld joint configuration, design of optics, use of protective gases and control of thermal distortions. The primary limitations on use of laser welding electronic for packaging applications are economic ones. The laser itself is a relatively costly device when compared to competing welding equipment. Further, the cost of consumables and repairs can be significant. These facts have relegated laser welding to use only where it presents a distinct quality or reliability advantages over other techniques of electronic package sealing. Because of the unique noncontact and low heat inputs characteristics of laser welding, it is an ideal candidate for sealing electronic packages containing MEMS devices (microelectromechanical systems). This paper addresses how the unique advantages of the pulsed YAG laser can be used to simplify MEMS packaging and deliver a product of improved quality.

  19. Thermal and hydrometallurgical recovery methods of heavy metals from municipal solid waste fly ash.

    PubMed

    Kuboňová, L; Langová, Š; Nowak, B; Winter, F

    2013-11-01

    Heavy metals in fly ash from municipal solid waste incinerators are present in high concentrations. Therefore fly ash must be treated as a hazardous material. On the other hand, it may be a potential source of heavy metals. Zinc, lead, cadmium, and copper can be relatively easily removed during the thermal treatment of fly ash, e.g. in the form of chlorides. In return, wet extraction methods could provide promising results for these elements including chromium and nickel. The aim of this study was to investigate and compare thermal and hydrometallurgical treatment of municipal solid waste fly ash. Thermal treatment of fly ash was performed in a rotary reactor at temperatures between 950 and 1050°C and in a muffle oven at temperatures from 500 to 1200°C. The removal more than 90% was reached by easy volatile heavy metals such as cadmium and lead and also by copper, however at higher temperature in the muffle oven. The alkaline (sodium hydroxide) and acid (sulphuric acid) leaching of the fly ash was carried out while the influence of temperature, time, concentration, and liquid/solid ratio were investigated. The combination of alkaline-acidic leaching enhanced the removal of, namely, zinc, chromium and nickel. Copyright © 2013 Elsevier Ltd. All rights reserved.

  20. Thermal and hydrometallurgical recovery methods of heavy metals from municipal solid waste fly ash

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Kuboňová, L., E-mail: lenka.kubonova@vsb.cz; Langová, Š.; Nowak, B.

    2013-11-15

    Highlights: • MSW fly ash was thermally and hydrometallurgically treated to remove heavy metals. • More than 90% of easy volatile heavy metals (Cd and Pb) were removed thermally. • More than 90% of Cd, Cr, Cu an Zn were removed by alkaline – acid leaching. • The best results were obtained for the solution of 3 M NaOH and 2 M H{sub 2}SO{sub 4}. - Abstract: Heavy metals in fly ash from municipal solid waste incinerators are present in high concentrations. Therefore fly ash must be treated as a hazardous material. On the other hand, it may be amore » potential source of heavy metals. Zinc, lead, cadmium, and copper can be relatively easily removed during the thermal treatment of fly ash, e.g. in the form of chlorides. In return, wet extraction methods could provide promising results for these elements including chromium and nickel. The aim of this study was to investigate and compare thermal and hydrometallurgical treatment of municipal solid waste fly ash. Thermal treatment of fly ash was performed in a rotary reactor at temperatures between 950 and 1050 °C and in a muffle oven at temperatures from 500 to 1200 °C. The removal more than 90% was reached by easy volatile heavy metals such as cadmium and lead and also by copper, however at higher temperature in the muffle oven. The alkaline (sodium hydroxide) and acid (sulphuric acid) leaching of the fly ash was carried out while the influence of temperature, time, concentration, and liquid/solid ratio were investigated. The combination of alkaline-acidic leaching enhanced the removal of, namely, zinc, chromium and nickel.« less

  1. Discussion on the methodology for determining food waste in household waste composition studies.

    PubMed

    Lebersorger, S; Schneider, F

    2011-01-01

    Food waste has become an increasingly discussed topic in recent years. However, there is little authoritative data on food waste quantities and composition and systematic and comparable data are missing. Household waste composition analyses, which are often carried out routinely at regular or irregular intervals, provide an opportunity for obtaining data about food waste at both local and regional levels. The results of prior waste composition studies are not really comparable due to the different classifications, definitions and methods used; in addition, these are mostly insufficiently described and not reproducible by a third party. The aim of this paper is to discuss a methodology for determining the proportion of food waste in household waste composition studies, by analysing specific problems and possible solutions. For that purpose, findings from the literature are analysed and the approach and results of a composition analysis of residual waste of a stratified sample (urban, rural area) are presented. The study suggests that in order to avoid a significant loss of information, waste should not be sieved before sorting and packed food waste should be classified into the relevant food waste category together with its packaging. The case study showed that the overall influence of the proportion of food packaging included in the food waste category, which amounted to only 8%, did not significantly influence the results and can therefore be disregarded. Copyright © 2011 Elsevier Ltd. All rights reserved.

  2. Thermal alterations of organic matter in coal wastes from Upper Silesia, Poland

    NASA Astrophysics Data System (ADS)

    Misz-Kennan, Magdalena

    2010-01-01

    organic matter is lacking suggests that they originated elsewhere and subsequently migrated through the dump piles. During their migration, the compounds fractionated, were adsorbed on minerals and/or interacted. The absence of alkenes, and of other unsaturated organic compounds, may reflect primary diagenetic processes that occurred in coals and coal shales during burial and/or organic matter type. Their absence may also be a consequence of heating that lasted many years, hydropyrolysis, and/or the participation of minerals in the reactions occurring within the dumps. The wastes contain compounds typical of organic matter of unaltered kerogen III type and the products of pyrolytic processes, and mixtures of both. In some wastes, organic compounds are completely absent having been destroyed by severe heating. The distributions of n-alkanes in many samples are typical of pyrolysates. In some wastes, narrow n-alkane distributions reflect their generation over small temperature ranges. In others, wider distributions point to greater temperature ranges. Other wastes contain n-alkane distributions typical of unaltered coal and high pristane content or mixtures of pyrolysates and unaltered waste material. The wastes also contain significant amounts of final αβ hopanes. Polycyclic aromatic hydrocarbons are represented only by two- to five-ring compounds as is typical of the thermal alteration of hard coal. Correlations between the degree of organic matter alteration and the relative contents of individual PAHs and hopanes and geochemical indicators of thermal alteration are generally poor. The properties of the organic matter (its composition and rank), temperature fluctuations within the dumps, migration of organic compounds and mineral involvement are probably responsible for this. The processes taking place in coal waste dumps undergoing self-heating and self-combustion are complicated; they are very difficult to estimate

  3. Ferulic acid-coupled chitosan: thermal stability and utilization as an antioxidant for biodegradable active packaging film.

    PubMed

    Woranuch, Sarekha; Yoksan, Rangrong; Akashi, Mitsuru

    2015-01-22

    The aim of the present research was to study the thermal stability of ferulic acid after coupling onto chitosan, and the possibility of using ferulic acid-coupled chitosan (FA-CTS) as an antioxidant for biodegradable active packaging film. FA-CTS was incorporated into biodegradable film via a two-step process, i.e. compounding extrusion at temperatures up to 150°C followed by blown film extrusion at temperatures up to 175°C. Although incorporation of FA-CTS with a content of 0.02-0.16% (w/w) caused decreased water vapor barrier property and reduced extensibility, the biodegradable films possessed improved oxygen barrier property and antioxidant activity. Radical scavenging activity and reducing power of film containing FA-CTS were higher than those of film containing naked ferulic acid, by about 254% and 94%, respectively. Tensile strength and rigidity of the films were not significantly affected by the addition of FA-CTS with a content of 0.02-0.08% (w/w). The above results suggested that FA-CTS could potentially be used as an antioxidant for active packaging film. Copyright © 2014 Elsevier Ltd. All rights reserved.

  4. Steady-state low thermal resistance characterization apparatus: The bulk thermal tester

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Burg, Brian R.; Kolly, Manuel; Blasakis, Nicolas

    The reliability of microelectronic devices is largely dependent on electronic packaging, which includes heat removal. The appropriate packaging design therefore necessitates precise knowledge of the relevant material properties, including thermal resistance and thermal conductivity. Thin materials and high conductivity layers make their thermal characterization challenging. A steady state measurement technique is presented and evaluated with the purpose to characterize samples with a thermal resistance below 100 mm{sup 2} K/W. It is based on the heat flow meter bar approach made up by two copper blocks and relies exclusively on temperature measurements from thermocouples. The importance of thermocouple calibration is emphasizedmore » in order to obtain accurate temperature readings. An in depth error analysis, based on Gaussian error propagation, is carried out. An error sensitivity analysis highlights the importance of the precise knowledge of the thermal interface materials required for the measurements. Reference measurements on Mo samples reveal a measurement uncertainty in the range of 5% and most accurate measurements are obtained at high heat fluxes. Measurement techniques for homogeneous bulk samples, layered materials, and protruding cavity samples are discussed. Ultimately, a comprehensive overview of a steady state thermal characterization technique is provided, evaluating the accuracy of sample measurements with thermal resistances well below state of the art setups. Accurate characterization of materials used in heat removal applications, such as electronic packaging, will enable more efficient designs and ultimately contribute to energy savings.« less

  5. Recharge Data Package for the Immobilized Low-Activity Waste 2001 Performance Assessment

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    MJ Fayer; EM Murphy; JL Downs

    2000-01-18

    Lockheed Martin Hanford Company (LMHC) is designing and assessing the performance of disposal facilities to receive radioactive wastes that are currently stored in single- and double-shell tanks at the Hanford Site. The preferred method of disposing of the portion that is classified as immobilized low-activity waste (ILAW) is to vitrify the waste and place the product in near-surface, shallow-land burial facilities. The LMHC project to assess the performance of these disposal facilities is known as the Hanford ILAW Performance Assessment (PA) Activity, hereafter called the ILAW PA project. The goal of this project is to provide a reasonable expectation thatmore » the disposal of the waste is protective of the general public, groundwater resources, air resources, surface-water resources, and inadvertent intruders. Achieving this goal will require predictions of contaminant migration from the facility. To make such predictions will require estimates of the fluxes of water moving through the sediments within the vadose zone around and beneath the disposal facility. These fluxes, loosely called recharge rates, are the primary mechanism for transporting contaminants to the groundwater. Pacific Northwest National Laboratory (PNNL) assists LMHC in their performance assessment activities. One of the PNNL tasks is to provide estimates of recharge rates for current conditions and long-term scenarios involving the shallow-land disposal of ILAW. Specifically, recharge estimates are needed for a filly functional surface cover; the cover sideslope, and the immediately surrounding terrain. In addition, recharge estimates are needed for degraded cover conditions. The temporal scope of the analysis is 10,000 years, but could be longer if some contaminant peaks occur after 10,000 years. The elements of this report compose the Recharge Data Package, which provides estimates of recharge rates for the scenarios being considered in the 2001 PA. Table S.1 identifies the surface

  6. Diamond-based heat spreaders for power electronic packaging applications

    NASA Astrophysics Data System (ADS)

    Guillemet, Thomas

    As any semiconductor-based devices, power electronic packages are driven by the constant increase of operating speed (higher frequency), integration level (higher power), and decrease in feature size (higher packing density). Although research and innovation efforts have kept these trends continuous for now more than fifty years, the electronic packaging technology is currently facing a challenge that must be addressed in order to move toward any further improvements in terms of performances or miniaturization: thermal management. Thermal issues in high-power packages strongly affect their reliability and lifetime and have now become one of the major limiting factors of power modules development. Thus, there is a strong need for materials that can sustain higher heat flux levels while safely integrating into the electronic package architecture. In such context, diamond is an attractive candidate because of its outstanding thermal conductivity, low thermal expansion, and high electrical resistivity. Its low heat capacity relative to metals such as aluminum or copper makes it however preferable for heat spreading applications (as a heat-spreader) rather than for dissipating the heat flux itself (as a heat sink). In this study, a dual diamond-based heat-spreading solution is proposed. Polycrystalline diamond films were grown through laser-assisted combustion synthesis on electronic substrates (in the U.S) while, in parallel, diamond-reinforced copper-matrix composite films were fabricated through tape casting and hot pressing (in France). These two types of diamond-based heat-spreading films were characterized and their microstructure and chemical composition were related to their thermal performances. Particular emphasize was put on the influence of interfaces on the thermal properties of the materials, either inside a single material (grain boundaries) or between dissimilar materials (film/substrate interface, matrix/reinforcement interface). Finally, the packaging

  7. Solid Waste Activity Packet for Teachers.

    ERIC Educational Resources Information Center

    Illinois Univ., Urbana. Cooperative Extension Service.

    This solid waste activity packet introduces students to the solid waste problem in Illinois. Topics explore consumer practices in the market place, packaging, individual and community garbage generation, and disposal practices. The activities provide an integrated approach to incorporating solid waste management issues into subject areas. The…

  8. Calculation Package for the Analysis of Performance of Cells 1-6, with Underdrain, of the Environmental Management Waste Management Facility Oak Ridge, Tennessee

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Gonzales D.

    2010-03-30

    This calculation package presents the results of an assessment of the performance of the 6 cell design of the Environmental Management Waste Management Facility (EMWMF). The calculations show that the new cell 6 design at the EMWMF meets the current WAC requirement. QA/QC steps were taken to verify the input/output data for the risk model and data transfer from modeling output files to tables and calculation.

  9. Behaviour of antimony during thermal treatment of Sb-rich halogenated waste.

    PubMed

    Klein, J; Dorge, S; Trouvé, G; Venditti, D; Durécu, S

    2009-07-30

    Antimony compounds have a wide range of industrial applications, particularly as additives in flame retardants. To ensure environmentally friendly waste incineration of Sb-rich wastes, it is essential to strengthen the knowledge about the fate of antimony and the potential formation of harmful species. Investigations should be conducted particularly in relation with the main operational parameters controlling the process, chiefly temperature, residence time and air supply in the oven and in the post-combustion zone, prior final adapted cleaning of the flue-gas stream. Experimental studies focusing on antimony behaviour were undertaken through laboratory-scale thermal treatment at 850 degrees C and 1100 degrees C of a Sb-rich halogenated waste, originating from the sector of flame retardants formulation. The configuration of our laboratory experimental device allowed to achieve only low oxidative conditions in the waste bed, but high oxidative strength coupled with high temperature and sufficient gas residence time in the post-combustion zone, as prescribed during the incineration of hazardous wastes. Atomic absorption spectroscopy was used to assess the partition of antimony in the different compartments of the process. The oxidation degree of antimony in the gas-phase was determined by the use of electrochemical techniques, namely polarography coupled with anodic stripping voltamperometry. The partition of antimony between the residual ash and the gas-phase under moderate oxidative conditions in the waste bed was constant, whatever the temperature: the volatilization rate for antimony was approximately 64%, while a approximately 36% fraction remained in the residual bottom ashes. But interestingly, while at 850 degrees C, antimony was mainly present in the gas-phase at a +III oxidation degree, an increase in temperature of 250 degrees C favoured the presence of antimony to its highest oxidation degree +V in the flue-gas stream, a valence known to be involved in

  10. Potential migration of buoyant LNAPL from intermediate level waste (ILW) emplaced in a geological disposal facility (GDF) for U.K. radioactive waste.

    PubMed

    Benbow, Steven J; Rivett, Michael O; Chittenden, Neil; Herbert, Alan W; Watson, Sarah; Williams, Steve J; Norris, Simon

    2014-10-15

    A safety case for the disposal of Intermediate Level (radioactive) Waste (ILW) in a deep geological disposal facility (GDF) requires consideration of the potential for waste-derived light non-aqueous phase liquid (LNAPL) to migrate under positive buoyancy from disposed waste packages. Were entrainment of waste-derived radionuclides in LNAPL to occur, such migration could result in a shorter overall travel time to environmental or human receptors than radionuclide migration solely associated with the movement of groundwater. This paper provides a contribution to the assessment of this issue through multiphase-flow numerical modelling underpinned by a review of the UK's ILW inventory and literature to define the nature of the associated ILW LNAPL source term. Examination has been at the waste package-local GDF environment scale to determine whether proposed disposal of ILW would lead to significant likelihood of LNAPL migration, both from waste packages and from a GDF vault into the local host rock. Our review and numerical modelling support the proposition that the release of a discrete free phase LNAPL from ILW would not present a significant challenge to the safety case even with conservative approximations. 'As-disposed' LNAPL emplaced with the waste is not expected to pose a significant issue. 'Secondary LNAPL' generated in situ within the disposed ILW, arising from the decomposition of plastics, in particular PVC (polyvinyl chloride), could form the predominant LNAPL source term. Released high molecular weight phthalate plasticizers are judged to be the primary LNAPL potentially generated. These are expected to have low buoyancy-based mobility due to their very low density contrast with water and high viscosity. Due to the inherent uncertainties, significant conservatisms were adopted within the numerical modelling approach, including: the simulation of a deliberately high organic material--PVC content wastestream (2D03) within an annular grouted waste package

  11. Technical and Regulatory Considerations in Using Freight Containers as Industrial Packages

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Hawk, Mark B; Opperman, Erich; Natali, Ronald

    2008-01-01

    The US Department of Energy (DOE), Office of Environmental Management (EM), is actively pursuing activities to reduce the radiological risk and clean up the environmental legacy of the nation's nuclear weapons programmes. The EM has made significant progress in recent years in the clean-up and closure of sites and is also focusing on longer term activities necessary for the completion of the clean-up programme. The packaging and transportation of contaminated demolition debris and low level waste materials in a safe and cost effective manner are essential in completing this mission. Toward this end, the US Department of Transportation's Final Rulemore » on Hazardous Materials Regulation issued on 26 January 2004, included a new provision authorising the use of freight containers (e.g. 20 and 40 ft ISO containers) as industrial packages type 2 or 3. This paper will discuss the technical and regulatory considerations in using these newly authorised and large packages for the packaging and transportation of low level waste materials.« less

  12. Secondary Waste Form Down-Selection Data Package—Fluidized Bed Steam Reforming Waste Form

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Qafoku, Nikolla; Westsik, Joseph H.; Strachan, Denis M.

    2011-09-12

    The Hanford Site in southeast Washington State has 56 million gallons of radioactive and chemically hazardous wastes stored in 177 underground tanks (ORP 2010). The U.S. Department of Energy (DOE), Office of River Protection (ORP), through its contractors, is constructing the Hanford Tank Waste Treatment and Immobilization Plant (WTP) to convert the radioactive and hazardous wastes into stable glass waste forms for disposal. Within the WTP, the pretreatment facility will receive the retrieved waste from the tank farms and separate it into two treated process streams. These waste streams will be vitrified, and the resulting waste canisters will be sentmore » to offsite (high-level waste [HLW]) and onsite (immobilized low-activity waste [ILAW]) repositories. As part of the pretreatment and ILAW processing, liquid secondary wastes will be generated that will be transferred to the Effluent Treatment Facility (ETF) on the Hanford Site for further treatment. These liquid secondary wastes will be converted to stable solid waste forms that will be disposed of in the Integrated Disposal Facility (IDF). To support the selection of a waste form for the liquid secondary wastes from WTP, Washington River Protection Solutions (WRPS) has initiated secondary waste form testing work at Pacific Northwest National Laboratory (PNNL). In anticipation of a down-selection process for a waste form for the Solidification Treatment Unit to be added to the ETF, PNNL is developing data packages to support that down-selection. The objective of the data packages is to identify, evaluate, and summarize the existing information on the four waste forms being considered for stabilizing and solidifying the liquid secondary wastes. At the Hanford Site, the FBSR process is being evaluated as a supplemental technology for treating and immobilizing Hanford LAW radioactive tank waste and for treating secondary wastes from the WTP pretreatment and LAW vitrification processes.« less

  13. A simplified heat transfer model for predicting temperature change inside food package kept in cold room.

    PubMed

    Raval, A H; Solanki, S C; Yadav, Rajvir

    2013-04-01

    A simple analytical heat flow model for a closed rectangular food package containing fruits or vegetables is proposed for predicting time temperature distribution during transient cooling in a controlled environment cold room. It is based on the assumption of only conductive heat transfer inside a closed food package with effective thermal properties, and convective and radiative heat transfer at the outside of the package. The effective thermal conductivity of the food package is determined by evaluating its effective thermal resistance to heat conduction in the packages. Food packages both as an infinite slab and a finite slab have been investigated. The finite slab solution has been obtained as the product of three infinite slab solutions describe in ASHRAE guide and data book. Time temperature variation has been determined and is presented graphically. The cooling rate and the half cooling time were also obtained. These predicted values, are compared with the experimentally measured values for both the finite and infinite closed packages containing oranges. An excellent agreement between them validated the simple proposed model.

  14. Auxiliary propulsion system flight package

    NASA Technical Reports Server (NTRS)

    Collett, C. R.

    1987-01-01

    Hughes Aircraft Company developed qualified and integrated flight, a flight test Ion Auxiliary Propulsion System (IAPS), on an Air Force technology satellite. The IAPS Flight Package consists of two identical Thruster Subsystems and a Diagnostic Subsystem. Each thruster subsystem (TSS) is comprised of an 8-cm ion Thruster-Gimbal-Beam Shield Unit (TGBSU); Power Electronics Unit; Digital Controller and Interface Unit (DCIU); and Propellant Tank, Valve and Feed Unit (PTVFU) plus the requisite cables. The Diagnostic Subsystem (DSS) includes four types of sensors for measuring the effect of the ion thrusters on the spacecraft and the surrounding plasma. Flight qualifications of IAPS, prior to installation on the spacecraft, consisted of performance, vibration and thermal-vacuum testing at the unit level, and thermal-vacuum testing at the subsystem level. Mutual compatibility between IAPS and the host spacecraft was demonstrated during a series of performance and environmental tests after the IAPS Flight Package was installed on the spacecraft. After a spacecraft acoustic test, performance of the ion thrusters was reverified by removing the TGBSUs for a thorough performance test at Hughes Research Laboratories (HRL). The TGBSUs were then reinstalled on the spacecraft. The IAPS Flight Package is ready for flight testing when Shuttle flights are resumed.

  15. Anaerobic co-digestion of high-strength organic wastes pretreated by thermal hydrolysis.

    PubMed

    Choi, Gyucheol; Kim, Jaai; Lee, Seungyong; Lee, Changsoo

    2018-06-01

    Thermal hydrolysis (TH) pretreatment was investigated for the anaerobic digestion (AD) of a mixture of high-strength organic wastes (i.e., dewatered human feces, dewatered sewage sludge, and food wastewater) at laboratory scale to simulate a full-scale plant and evaluate its feasibility. The reactors maintained efficient and stable performance at a hydraulic retention time of 20 days, which may be not sufficient for the mesophilic AD of high-suspended-solid wastes, despite the temporal variations in organic load. The addition of FeCl 3 was effective in controlling H 2 S and resulted in significant changes in the microbial community structure, particularly the methanogens. The temporary interruption in feeding or temperature control led to immediate performance deterioration, but it recovered rapidly when normal operations were resumed. The overall results suggest that the AD process coupled with TH pretreatment can provide an efficient, robust, and resilient system to manage high-suspended-solid wastes, supporting the feasibility of its full-scale implementation. Copyright © 2018 Elsevier Ltd. All rights reserved.

  16. Physical performance of biodegradable films intended for antimicrobial food packaging.

    PubMed

    Marcos, Begonya; Aymerich, Teresa; Monfort, Josep M; Garriga, Margarita

    2010-10-01

    Antimicrobial films were prepared by including enterocins to alginate, polyvinyl alcohol (PVOH), and zein films. The physical performance of the films was assessed by measuring color, microstructure (SEM), water vapor permeability (WVP), and tensile properties. All studied biopolymers showed poor WVP and limited tensile properties. PVOH showed the best performance exhibiting the lowest WVP values, higher tensile properties, and flexibility among studied biopolymers. SEM of antimicrobial films showed increased presence of voids and pores as a consequence of enterocin addition. However, changes in microstructure did not disturb WVP of films. Moreover, enterocin-containing films showed slight improvement compared to control films. Addition of enterocins to PVOH films had a plasticizing effect, by reducing its tensile strength and increasing the strain at break. The presence of enterocins had an important effect on tensile properties of zein films by significantly reducing its brittleness. Addition of enterocins, thus, proved not to disturb the physical performance of studied biopolymers. Development of new antimicrobial biodegradable packaging materials may contribute to improving food safety while reducing environmental impact derived from packaging waste. Practical Application: Development of new antimicrobial biodegradable packaging materials may contribute to improving food safety while reducing environmental impact derived from packaging waste.

  17. Cleanup Verification Package for the 118-F-1 Burial Ground

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    E. J. Farris and H. M. Sulloway

    2008-01-10

    This cleanup verification package documents completion of remedial action for the 118-F-1 Burial Ground on the Hanford Site. This burial ground is a combination of two locations formerly called Minor Construction Burial Ground No. 2 and Solid Waste Burial Ground No. 2. This waste site received radioactive equipment and other miscellaneous waste from 105-F Reactor operations, including dummy elements and irradiated process tubing; gun barrel tips, steel sleeves, and metal chips removed from the reactor; filter boxes containing reactor graphite chips; and miscellaneous construction solid waste.

  18. Packaging Reliability Effect of ENIG and ENEPIG Surface Finishes in Board Level Thermal Test under Long-Term Aging and Cycling

    PubMed Central

    Shen, Chaobo; Hai, Zhou; Zhao, Cong; Zhang, Jiawei; Evans, John L.; Bozack, Michael J.; Suhling, Jeffrey C.

    2017-01-01

    This study illustrates test results and comparative literature data on the influence of isothermal aging and thermal cycling associated with Sn-1.0Ag-0.5Cu (SAC105) and Sn-3.0Ag-0.5Cu (SAC305) ball grid array (BGA) solder joints finished with ENIG and ENEPIG on the board side and ENIG on the package side compared with ImAg plating on both sides. The resulting degradation data suggests that the main concern for 0.4 mm pitch 10 mm package size BGA is package side surface finish, not board side. That is, ENIG performs better than immersion Ag for applications involving long-term isothermal aging. SAC305, with a higher relative fraction of Ag3Sn IMC within the solder, performs better than SAC105. SEM and polarized light microscope analysis show cracks propagated from the corners to the center or even to solder bulk, which eventually causes fatigue failure. Three factors are discussed: IMC, grain structure, and Ag3Sn particle. The continuous growth of Cu-Sn intermetallic compounds (IMC) and grains increase the risk of failure, while Ag3Sn particles seem helpful in blocking the crack propagation. PMID:28772811

  19. Review: nanocomposites in food packaging.

    PubMed

    Arora, Amit; Padua, G W

    2010-01-01

    The development of nanocomposites is a new strategy to improve physical properties of polymers, including mechanical strength, thermal stability, and gas barrier properties. The most promising nanoscale size fillers are montmorillonite and kaolinite clays. Graphite nanoplates are currently under study. In food packaging, a major emphasis is on the development of high barrier properties against the migration of oxygen, carbon dioxide, flavor compounds, and water vapor. Decreasing water vapor permeability is a critical issue in the development of biopolymers as sustainable packaging materials. The nanoscale plate morphology of clays and other fillers promotes the development of gas barrier properties. Several examples are cited. Challenges remain in increasing the compatibility between clays and polymers and reaching complete dispersion of nanoplates. Nanocomposites may advance the utilization of biopolymers in food packaging.

  20. Convection and thermal radiation analytical models applicable to a nuclear waste repository room

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Davis, B.W.

    1979-01-17

    Time-dependent temperature distributions in a deep geologic nuclear waste repository have a direct impact on the physical integrity of the emplaced canisters and on the design of retrievability options. This report (1) identifies the thermodynamic properties and physical parameters of three convection regimes - forced, natural, and mixed; (2) defines the convection correlations applicable to calculating heat flow in a ventilated (forced-air) and in a nonventilated nuclear waste repository room; and (3) delineates a computer code that (a) computes and compares the floor-to-ceiling heat flow by convection and radiation, and (b) determines the nonlinear equivalent conductivity table for a repositorymore » room. (The tables permit the use of the ADINAT code to model surface-to-surface radiation and the TRUMP code to employ two different emissivity properties when modeling radiation exchange between the surface of two different materials.) The analysis shows that thermal radiation dominates heat flow modes in a nuclear waste repository room.« less

  1. Treatment of electronic waste to recover metal values using thermal plasma coupled with acid leaching--a response surface modeling approach.

    PubMed

    Rath, Swagat S; Nayak, Pradeep; Mukherjee, P S; Roy Chaudhury, G; Mishra, B K

    2012-03-01

    The global crisis of the hazardous electronic waste (E-waste) is on the rise due to increasing usage and disposal of electronic devices. A process was developed to treat E-waste in an environmentally benign process. The process consisted of thermal plasma treatment followed by recovery of metal values through mineral acid leaching. In the thermal process, the E-waste was melted to recover the metal values as a metallic mixture. The metallic mixture was subjected to acid leaching in presence of depolarizer. The leached liquor mainly contained copper as the other elements like Al and Fe were mostly in alloy form as per the XRD and phase diagram studies. Response surface model was used to optimize the conditions for leaching. More than 90% leaching efficiency at room temperature was observed for Cu, Ni and Co with HCl as the solvent, whereas Fe and Al showed less than 40% efficiency. Copyright © 2011 Elsevier Ltd. All rights reserved.

  2. Substitution potentials of recycled HDPE and wood particles from post-consumer packaging waste in Wood-Plastic Composites.

    PubMed

    Sommerhuber, Philipp F; Welling, Johannes; Krause, Andreas

    2015-12-01

    The market share of Wood-Plastic Composites (WPC) is small but expected to grow sharply in Europe. This raises some concerns about suitable wood particles needed in the wood-based panels industry in Europe. Concerns are stimulated by the competition between the promotion of wooden products through the European Bioeconomy Strategy and wood as an energy carrier through the Renewable Energy Directive. Cascade use of resources and valorisation of waste are potential strategies to overcome resource scarcity. Under experimental design conditions, WPC made from post-consumer recycled wood and plastic (HDPE) were compared to WPC made from virgin resources. Wood content in the polymer matrix was raised in two steps from 0% to 30% and 60%. Mechanical and physical properties and colour differences were characterized. The feasibility of using cascaded resources for WPC is discussed. Results indicate the technical and economic feasibility of using recycled HDPE from packaging waste for WPC. Based on technical properties, 30% recycled wood content for WPC is feasible, but economic and political barriers of efficient cascading of biomass need to be overcome. Copyright © 2015 Elsevier Ltd. All rights reserved.

  3. Consumer preferences for reduced packaging under economic instruments and recycling policy.

    PubMed

    Yamaguchi, Keiko; Takeuchi, Kenji

    2016-02-01

    This study was conducted using a web-based survey and bidding game in contingent valuation method to evaluate consumer preferences for packaging with less material. Results revealed that people who live in a municipality implementing unit-based pricing of waste have a higher willingness-to-pay (WTP) for a product. Economic instruments can affect the purchase of products with reduced packaging because a higher disposal cost increases the attractiveness of source reduction. However, unit-based pricing combined with plastic separation for recycling reduces WTP. This result suggests that recycling policy weakens the effect of economic instruments on source reduction of waste. Copyright © 2015 Elsevier Ltd. All rights reserved.

  4. Packaging and Transportation Support at LANL CTMA 2012

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Salazar, Nick

    2012-06-08

    Operations Support Packaging and Transportation (OS-PT) supports LANL in various functions. Some highlights of the past year have been with the work relating to environmental remediation, type B packaging, non-DOT compliant transfers, and special permit training. The TA-21 remediation project was part of the ARRA funding that LANL received. The $212 million in funding was used to demolish 24 buildings at TA-21, excavate the lab's oldest waste disposal site, and install 16 groundwater monitoring wells. The project was completed ahead of schedule and under budget. More than 300 tons of metal was recycled and all the soil excavated from MDA-Bmore » was replaced with clean fill. OS-PT supported this projected by transporting more than 7 million pounds of waste to TA-54 Area G with an addendum to their TSD. Because of the public access on the transfer route, Los Alamos County restricted the transfer to happen from 2:00 AM to 4:00 AM. OS-PT conducted 8 transfers in support of this project. Some concerns included the contaminated trailers at receipt facilities when transferring filled Super Sacks. Future Super Sacks were over packed into new IP-2 Super Sacks before shipping. OS-PT is also supporting the remediation of TA-54 Area G. LANL has an agreement with the State of New Mexico to remove all TRU waste currently stored above ground from at Area G. OS-PT supports this initiative with transfers of TRU waste under LANL's TSD and support of TRU shipments to WIPP. Another project supported by our organization is gas cylinder/dewar recycling and remediation. We are focusing on reducing risk associated with unneeded gasses at LANL. To minimized excessive ordering, to save money and time, and to minimize hazards OS-PT is supporting a gas recycling program. This program will allow programmatic organization across LANL to share unused/unneeded gasses. Instead of old dewars being disposed of, OS-PT has began identifying these dewars and sending them for refurbishment. To date

  5. RH Packaging Program Guidance

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Washington TRU Solutions, LLC

    The purpose of this program guidance document is to provide technical requirements for use, operation, inspection, and maintenance of the RH-TRU 72-B Waste Shipping Package and directly related components. This document complies with the requirements as specified in the RH-TRU 72-B Safety Analysis Report for Packaging (SARP), and Nuclear Regulatory Commission (NRC) Certificate of Compliance (C of C) 9212. If there is a conflict between this document and the SARP and/or C of C, the SARP and/or C of C shall govern. The C of C states: ''...each package must be prepared for shipment and operated in accordance with themore » procedures described in Chapter 7.0, ''Operating Procedures,'' of the application.'' It further states: ''...each package must be tested and maintained in accordance with the procedures described in Chapter 8.0, ''Acceptance Tests and Maintenance Program of the Application.'' Chapter 9.0 of the SARP tasks the Waste Isolation Pilot Plant (WIPP) Management and Operating (M&O) contractor with assuring the packaging is used in accordance with the requirements of the C of C. Because the packaging is NRC approved, users need to be familiar with 10 CFR {section} 71.11, ''Deliberate Misconduct.'' Any time a user suspects or has indications that the conditions of approval in the C of C were not met, the Carlsbad Field Office (CBFO) shall be notified immediately. CBFO will evaluate the issue and notify the NRC if required. This document details the instructions to be followed to operate, maintain, and test the RH-TRU 72-B packaging. This Program Guidance standardizes instructions for all users. Users shall follow these instructions. Following these instructions assures that operations are safe and meet the requirements of the SARP. This document is available on the Internet at: ttp://www.ws/library/t2omi/t2omi.htm. Users are responsible for ensuring they are using the current revision and change notices. Sites may prepare their own document using the word

  6. Use of thermal analysis techniques (TG-DSC) for the characterization of diverse organic municipal waste streams to predict biological stability prior to land application.

    PubMed

    Fernández, José M; Plaza, César; Polo, Alfredo; Plante, Alain F

    2012-01-01

    The use of organic municipal wastes as soil amendments is an increasing practice that can divert significant amounts of waste from landfill, and provides a potential source of nutrients and organic matter to ameliorate degraded soils. Due to the high heterogeneity of organic municipal waste streams, it is difficult to rapidly and cost-effectively establish their suitability as soil amendments using a single method. Thermal analysis has been proposed as an evolving technique to assess the stability and composition of the organic matter present in these wastes. In this study, three different organic municipal waste streams (i.e., a municipal waste compost (MC), a composted sewage sludge (CS) and a thermally dried sewage sludge (TS)) were characterized using conventional and thermal methods. The conventional methods used to test organic matter stability included laboratory incubation with measurement of respired C, and spectroscopic methods to characterize chemical composition. Carbon mineralization was measured during a 90-day incubation, and samples before and after incubation were analyzed by chemical (elemental analysis) and spectroscopic (infrared and nuclear magnetic resonance) methods. Results were compared with those obtained by thermogravimetry (TG) and differential scanning calorimetry (DSC) techniques. Total amounts of CO(2) respired indicated that the organic matter in the TS was the least stable, while that in the CS was the most stable. This was confirmed by changes detected with the spectroscopic methods in the composition of the organic wastes due to C mineralization. Differences were especially pronounced for TS, which showed a remarkable loss of aliphatic and proteinaceous compounds during the incubation process. TG, and especially DSC analysis, clearly reflected these differences between the three organic wastes before and after the incubation. Furthermore, the calculated energy density, which represents the energy available per unit of organic

  7. The combined hybrid system: A symbiotic thermal reactor/fast reactor system for power generation and radioactive waste toxicity reduction

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Hollaway, W.R.

    1991-08-01

    If there is to be a next generation of nuclear power in the United States, then the four fundamental obstacles confronting nuclear power technology must be overcome: safety, cost, waste management, and proliferation resistance. The Combined Hybrid System (CHS) is proposed as a possible solution to the problems preventing a vigorous resurgence of nuclear power. The CHS combines Thermal Reactors (for operability, safety, and cost) and Integral Fast Reactors (for waste treatment and actinide burning) in a symbiotic large scale system. The CHS addresses the safety and cost issues through the use of advanced reactor designs, the waste management issuemore » through the use of actinide burning, and the proliferation resistance issue through the use of an integral fuel cycle with co-located components. There are nine major components in the Combined Hybrid System linked by nineteen nuclear material mass flow streams. A computer code, CHASM, is used to analyze the mass flow rates CHS, and the reactor support ratio (the ratio of thermal/fast reactors), IFR of the system. The primary advantages of the CHS are its essentially actinide-free high-level radioactive waste, plus improved reactor safety, uranium utilization, and widening of the option base. The primary disadvantages of the CHS are the large capacity of IFRs required (approximately one MW{sub e} IFR capacity for every three MW{sub e} Thermal Reactor) and the novel radioactive waste streams produced by the CHS. The capability of the IFR to burn pure transuranic fuel, a primary assumption of this study, has yet to be proven. The Combined Hybrid System represents an attractive option for future nuclear power development; that disposal of the essentially actinide-free radioactive waste produced by the CHS provides an excellent alternative to the disposal of intact actinide-bearing Light Water Reactor spent fuel (reducing the toxicity based lifetime of the waste from roughly 360,000 years to about 510 years).« less

  8. EQ6 Calculation for Chemical Degradation of Shippingport LWBR (TH/U Oxide) Spent Nuclear Fuel Waste Packages

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    S. Arthur

    The Monitored Geologic Repository (MGR) Waste Package Department of the Civilian Radioactive Waste Management System Management & Operating contractor (CRWMS M&O) performed calculations to provide input for disposal of spent nuclear fuel (SNF) from the Shippingport Light Water Breeder Reactor (LWBR) (Ref. 1). The Shippingport LWBR SNF has been considered for disposal at the potential Yucca Mountain site. Because of the high content of fissile material in the SNF, the waste package (WP) design requires special consideration of the amount and placement of neutron absorbers and the possible loss of absorbers and SNF materials over geologic time. For some WPs,more » the outer shell corrosion-resistant material (CRM) and the corrosion-allowance inner shell may breach (Refs. 2 and 3), allowing the influx of water. Water in the WP will moderate neutrons, increasing the likelihood of a criticality event within the WP; and the water may, in time, gradually leach the fissile components and neutron absorbers from the WP, further affecting the neutronics of the system. This study presents calculations of the long-term geochemical behavior of WPs containing a Shippingport LWBR SNF seed assembly, and high-level waste (HLW) glass canisters arranged according to the codisposal concept (Ref. 4). The specific study objectives were to determine: (1) The extent to which criticality control material, suggested for this WP design, will remain in the WP after corrosion/dissolution of the initial WP configuration (such that it can be effective in preventing criticality); (2) The extent to which fissile uranium and fertile thorium will be carried out of the degraded WP by infiltrating water (such that internal criticality is no longer possible, but the possibility of external criticality may be enhanced); and (3) The nominal chemical composition for the criticality evaluations of the WP design, and to suggest the range of parametric variations for additional evaluations. The scope of

  9. ANTS — a simulation package for secondary scintillation Anger-camera type detector in thermal neutron imaging

    NASA Astrophysics Data System (ADS)

    Morozov, A.; Defendi, I.; Engels, R.; Fraga, F. A. F.; Fraga, M. M. F. R.; Guerard, B.; Jurkovic, M.; Kemmerling, G.; Manzin, G.; Margato, L. M. S.; Niko, H.; Pereira, L.; Petrillo, C.; Peyaud, A.; Piscitelli, F.; Raspino, D.; Rhodes, N. J.; Sacchetti, F.; Schooneveld, E. M.; Van Esch, P.; Zeitelhack, K.

    2012-08-01

    A custom and fully interactive simulation package ANTS (Anger-camera type Neutron detector: Toolkit for Simulations) has been developed to optimize the design and operation conditions of secondary scintillation Anger-camera type gaseous detectors for thermal neutron imaging. The simulation code accounts for all physical processes related to the neutron capture, energy deposition pattern, drift of electrons of the primary ionization and secondary scintillation. The photons are traced considering the wavelength-resolved refraction and transmission of the output window. Photo-detection accounts for the wavelength-resolved quantum efficiency, angular response, area sensitivity, gain and single-photoelectron spectra of the photomultipliers (PMTs). The package allows for several geometrical shapes of the PMT photocathode (round, hexagonal and square) and offers a flexible PMT array configuration: up to 100 PMTs in a custom arrangement with the square or hexagonal packing. Several read-out patterns of the PMT array are implemented. Reconstruction of the neutron capture position (projection on the plane of the light emission) is performed using the center of gravity, maximum likelihood or weighted least squares algorithm. Simulation results reproduce well the preliminary results obtained with a small-scale detector prototype. ANTS executables can be downloaded from http://coimbra.lip.pt/~andrei/.

  10. Post-anaerobic digestion thermal hydrolysis of sewage sludge and food waste: Effect on methane yields, dewaterability and solids reduction.

    PubMed

    Svensson, Kine; Kjørlaug, Oda; Higgins, Matthew J; Linjordet, Roar; Horn, Svein J

    2018-04-01

    Post-anaerobic digestion (PAD) treatment technologies have been suggested for anaerobic digestion (AD) to improve process efficiency and assure hygenization of organic waste. Because AD reduces the amount of organic waste, PAD can be applied to a much smaller volume of waste compared to pre-digestion treatment, thereby improving efficiency. In this study, dewatered digestate cakes from two different AD plants were thermally hydrolyzed and dewatered, and the liquid fraction was recirculated to a semi-continuous AD reactor. The thermal hydrolysis was more efficient in relation to methane yields and extent of dewaterability for the cake from a plant treating waste activated sludge, than the cake from a plant treating source separated food waste (SSFW). Temperatures above 165 °C yielded the best results. Post-treatment improved volumetric methane yields by 7% and the COD-reduction increased from 68% to 74% in a mesophilic (37 °C) semi-continuous system despite lowering the solid retention time (from 17 to 14 days) compared to a conventional system with pre-treatment of feed substrates at 70 °C. Results from thermogravimetric analysis showed an expected increase in maximum TS content of dewatered digestate cake from 34% up to 46% for the SSFW digestate cake, and from 17% up to 43% in the sludge digestate cake, after the PAD thermal hydrolysis process (PAD-THP). The increased dewatering alone accounts for a reduction in wet mass of cake leaving the plant of 60% in the case of sludge digestate cake. Additionaly, the increased VS-reduction will contribute to further reduce the mass of wet cake. Copyright © 2018 Elsevier Ltd. All rights reserved.

  11. Chip packaging technique

    NASA Technical Reports Server (NTRS)

    Jayaraj, Kumaraswamy (Inventor); Noll, Thomas E. (Inventor); Lockwood, Harry F. (Inventor)

    2001-01-01

    A hermetically sealed package for at least one semiconductor chip is provided which is formed of a substrate having electrical interconnects thereon to which the semiconductor chips are selectively bonded, and a lid which preferably functions as a heat sink, with a hermetic seal being formed around the chips between the substrate and the heat sink. The substrate is either formed of or includes a layer of a thermoplastic material having low moisture permeability which material is preferably a liquid crystal polymer (LCP) and is a multiaxially oriented LCP material for preferred embodiments. Where the lid is a heat sink, the heat sink is formed of a material having high thermal conductivity and preferably a coefficient of thermal expansion which substantially matches that of the chip. A hermetic bond is formed between the side of each chip opposite that connected to the substrate and the heat sink. The thermal bond between the substrate and the lid/heat sink may be a pinched seal or may be provided, for example by an LCP frame which is hermetically bonded or sealed on one side to the substrate and on the other side to the lid/heat sink. The chips may operate in the RF or microwave bands with suitable interconnects on the substrate and the chips may also include optical components with optical fibers being sealed into the substrate and aligned with corresponding optical components to transmit light in at least one direction. A plurality of packages may be physically and electrically connected together in a stack to form a 3D array.

  12. Data Package for Secondary Waste Form Down-Selection—Cast Stone

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Serne, R. Jeffrey; Westsik, Joseph H.

    2011-09-05

    Available literature on Cast Stone and Saltstone was reviewed with an emphasis on determining how Cast Stone and related grout waste forms performed in relationship to various criteria that will be used to decide whether a specific type of waste form meets acceptance criteria for disposal in the Integrated Disposal Facility (IDF) at Hanford. After the critical review of the Cast Stone/Saltstone literature, we conclude that Cast Stone is a good candidate waste form for further consideration. Cast stone meets the target IDF acceptance criteria for compressive strength, no free liquids, TCLP leachate are below the UTS permissible concentrations andmore » leach rates for Na and Tc-99 are suiteably low. The cost of starting ingredients and equipment necessary to generate Cast Stone waste forms with secondary waste streams are low and the Cast Stone dry blend formulation can be tailored to accommodate variations in liquid waste stream compositions. The database for Cast Stone short-term performance is quite extensive compared to the other three candidate waste solidification processes. The solidification of liquid wastes in Cast Stone is a mature process in comparison to the other three candidates. Successful production of Cast Stone or Saltstone has been demonstrated from lab-scale monoliths with volumes of cm3 through m3 sized blocks to 210-liter sized drums all the way to the large pours into vaults at Savannah River. To date over 9 million gallons of low activity liquid waste has been solidified and disposed in concrete vaults at Savannah River.« less

  13. Solid Waste Management Practices in EBRP Schools.

    ERIC Educational Resources Information Center

    Mann, Nadine L.

    1994-01-01

    A Louisiana school district has made tremendous progress toward developing and implementing an environmentally friendly solid waste management program. Packaging changes in school food service, newspaper and aluminum can recycling, and composting of leaf and yard waste have contributed to reduced waste sent to the local landfill. (MLF)

  14. The empowerment of sustainable design in food packaging as designer responsibilities

    NASA Astrophysics Data System (ADS)

    Setiadi, V.

    2018-01-01

    The purpose of this paper is emphasized on the empowerment of sustainable design in providing the dual function of a food packaging. Which can extend the life of paper, cardboard, plastic, aluminum foil so as to reduce the contribution of waste on earth. The methodology used in this research is using qualitative research. With the main approach taken on the layout of the packaging design, the approach that relies heavily on the data in the form of packaging design. For the process of observation, the authors should compare with the forms of food packaging designs that are contained in the diversity of food packaging types from products outside Indonesia. The purpose of this study is also intended as a recommendation through observation of data interviews and survey related products. Conclusion through material exploration, packaging structure exploration, efficient exploration of ink usage and packaging usage patterns.

  15. Characterization of Heat-treated Clay Minerals in the Context of Nuclear Waste Disposal

    NASA Astrophysics Data System (ADS)

    Matteo, E. N.; Wang, Y.; Kruichak, J. N.; Mills, M. M.

    2015-12-01

    Clay minerals are likely candidates to aid in nuclear waste isolation due to their low permeability, favorable swelling properties, and high cation sorption capacities. Establishing the thermal limit for clay minerals in a nuclear waste repository is a potentially important component of repository design, as flexibility of the heat load within the repository can have a major impact on the selection of repository design. For example, the thermal limit plays a critical role in the time that waste packages would need to cool before being transferred to the repository. Understanding the chemical and physical changes, if any, that occur in clay minerals at various temperatures above the current thermal limit (of 100 °C) can enable decision-makers with information critical to evaluating the potential trade-offs of increasing the thermal limit within the repository. Most critical is gaining understanding of how varying thermal conditions in the repository will impact radionuclide sorption and transport in clay materials either as engineered barriers or as disposal media. A variety of repository-relevant clay minerals (illite, mixed layer illite/smectite, and montmorillonite), were heated for a range of temperatures between 100-1000 °C. These samples were characterized to determine surface area, mineralogical alteration, and cation exchange capacity (CEC). Our results show that for conditions up to 500 °C, no significant change occurs, so long as the clay mineral remains mineralogically intact. At temperatures above 500 °C, transformation of the layered silicates into silica phases leads to alteration that impacts important clay characteristics. Sandia National Laboratories is a multi-program laboratory managed and operated by Sandia Corporation, a wholly owned subsidiary of Lockheed Martin Corporation, for the U.S. Department of Energy's Nation Nuclear Security Administration under contract DE-AC04-94AL85000. SAND Number: SAND2015-6524 A

  16. Nonwoven production from agricultural okra wastes and investigation of their thermal conductivities

    NASA Astrophysics Data System (ADS)

    Duman, M. N.; Kocak, E. D.; Merdan, N.; Mistik, I.

    2017-10-01

    Nowadays bio-based composite materials have been used in rising amounts and demanded widely in industrial uses, as they provide cost reduction and weight loss in the end use products. Agricultural cellulose based wastes can be a good alternative to synthetic fibers and can be used in natural fiber reinforced composite production, as there is a huge (more than 40 million tons) potential for natural cellulose production from agricultural wastes. Okra is one of the most grown vegetables around the world with stems left on the fields after harvest. When the similarity of mechanical properties of okra fibers with traditional bast fibers (flax, kenaf, hemp) are considered, from an economical and an environmental point of view this research emphasizes the potential of agricultural biomass for natural fiber production. In this study, okra stem wastes used for natural cellulosic fiber production and treated with 10% NaOH at 60°C for 10, 20, 30 and 40 minutes. By alkali treatment, decrease in fiber diameter and weight, and increase in tensile strength and elongation % have been observed. Nonwoven production has been done from both the fibers with and without surface treatments. Thermal conductivity properties of both nonwovens have been investigated.

  17. Assessing the perception and reality of arguments against thermal waste treatment plants in terms of property prices.

    PubMed

    Phillips, K J O; Longhurst, P J; Wagland, S T

    2014-01-01

    The thermal processing of waste materials, although considered to be an essential part of waste management, is often sharply contested in the UK. Arguments such as health, depletion of resources, cost, noise, odours, traffic movement and house prices are often cited as reasons against the development of such facilities. This study aims to review the arguments and identify any effect on property prices due to the public perception of the plant. A selection of existing energy from waste (EfW) facilities in the UK, operational for at least 7 years, was selected and property sales data, within 5 km of the sites, was acquired and analysed in detail. The locations of the properties were calculated in relation to the plant using GIS software (ArcGIS) and the distances split into 5 zones ranging from 0 to 5 km from the site. The local property sale prices, normalised against the local house price index, were compared in two time periods, before and after the facility became operational, across each of the 5 zones. In all cases analysed no significant negative effect was observed on property prices at any distance within 5 km from a modern operational incinerator. This indicated that the perceived negative effect of the thermal processing of waste on local property values is negligible. Copyright © 2013 Elsevier Ltd. All rights reserved.

  18. Thermal degradation of paper industry wastes from a recovered paper mill using TGA. Characterization and gasification test.

    PubMed

    Arenales Rivera, Jorge; Pérez López, Virginia; Ramos Casado, Raquel; Sánchez Hervás, José-María

    2016-01-01

    In this survey, a refuse derived fuel (RDF) was produced from paper industry wastes through a mechanical treatment (MT). The two main wastes generated from a recovered paper mill were rejects and de-inking sludge, which were produced principally in the pulping and de-inking processes, respectively. This work presents raw wastes characterization, fuel preparation and gasification tests performed in a circulating fluidized bed (CFB) gasifier pilot plant. The characterization was carried out by proximate and ultimate analysis. Several blends of pre-conditioned rejects and de-inking sludge were densified by means of pelletizing, studying the energy consumption and its quality properties. Besides, thermal degradation of blends was studied under thermogravimetric analysis (TGA). The experimental runs were made from 30 to 900°C in nitrogen atmosphere at three heating ranges, β=5, 10 and 20°C/min. Two thermal stages were identified during the thermal degradation, which are linked to cellulose and plastic degradation. In addition, kinetics parameters were estimated by the application of non-isothermal methods: Kissinger-Akahira-Sunose (KAS), Flynn-Ozawa-Wall (FOW) and Coats and Redfern. The activation energy values were about 140-160 kJ/mol and 60-80 kJ/mol for plastic and cellulosic materials, respectively. Regarding waste valorisation, a blend composed of 95% of rejects and 5% of de-inking sludge was selected for gasification tests. The energy consumption during the preparation was recorded and a gasification tests were done to prove the usability of these pellets in a CFB gasifier. The main results were a net calorific value (NCV) of 5 MJ/Nm(3) and a total tar content of 11.44 g/Nm(3) at an equivalence ratio (ER) of 0.3. Copyright © 2015 Elsevier Ltd. All rights reserved.

  19. 33 Shafts Category of Transuranic Waste Stored Below Ground within Area G

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Hargis, Kenneth Marshall; Monk, Thomas H

    This report compiles information to support the evaluation of alternatives and analysis of regulatory paths forward for the 33 shafts. The historical information includes a form completed by waste generators for each waste package (Reference 6) that included a waste description, estimates of Pu-239 and uranium-235 (U-235) based on an accounting technique, and calculations of mixed fission products (MFP) based on radiation measurements. A 1979 letter and questionnaire (Reference 7) provides information on waste packaging of hot cell waste and the configuration of disposal shafts as storage in the 33 Shafts was initiated. Tables of data by waste package weremore » developed during a review of historical documents that was performed in 2005 (Reference 8). Radiological data was coupled with material-type data to estimate the initial isotopic content of each waste package and an Oak Ridge National Laboratory computer code was used to calculate 2009 decay levels. Other sources of information include a waste disposal logbook for the 33 shafts (Reference 9), reports that summarize remote-handled waste generated at the CMR facility (Reference 10) and placement of waste in the 33 shafts (Reference 11), a report on decommissioning of the LAMPRE reactor (Reference 12), interviews with an employee and manager involved in placing waste in the 33 shafts (References 13 and 14), an interview with a long-time LANL employee involved in waste operations (Reference 15), a 2002 plan for disposition of remote-handled TRU waste (Reference 16), and photographs obtained during field surveys of several shafts in 2007. The WIPP Central Characterization Project (CCP) completed an Acceptable Knowledge (AK) summary report for 16 canisters of remote-handled waste from the CMR Facility that contains information relevant to the 33 Shafts on hot-cell operations and timeline (Reference 17).« less

  20. Functions of Nano-Materials in Food Packaging

    NASA Astrophysics Data System (ADS)

    Yap, Ray Chin Chong; Kwablah, Amegadze Paul Seyram; He, Jiating; Li, Xu

    Food packaging has been changing from bulky and rigid form in the past to different variation of lights and plastic packagings. Regardless of the changes, the packaging must be able to uphold its original function which is to serve as food containment as well as to protect the food from the external environment. Coupled with the increasing consumer’s awareness on food waste, higher standard of living, technological developments are underway to enhance the shelf-life of packed food as well as methods to provide indications of food packaging environment. There are many different indicators for food spoilage, but two commonly found gases in food packaging are oxygen and carbon dioxide. Oxygen is the main mechanism for food spoilage, while carbon dioxide is often used in modified-atmosphere-packaging. There are also different methods of gas scavenging and/or sensing techniques based on different concepts in the literature. In this review, the focus will be on nano-materials, namely titanium dioxide, silica, zeolites and metal organic frameworks. This review is structured in a manner to highlight how each material can be used in both gas scavenging and/or indicators applications. The last part of the review focuses on the approach and some key considerations when integrating nano-materials into the plastic film.

  1. Determining the amount of waste plastics in the feed of Austrian waste-to-energy facilities

    PubMed Central

    Schwarzböck, Therese; Van Eygen, Emile; Rechberger, Helmut; Fellner, Johann

    2016-01-01

    Although thermal recovery of waste plastics is widely practiced in many European countries, reliable information on the amount of waste plastics in the feed of waste-to-energy plants is rare. In most cases the amount of plastics present in commingled waste, such as municipal solid waste, commercial, or industrial waste, is estimated based on a few waste sorting campaigns, which are of limited significance with regard to the characterisation of plastic flows. In the present study, an alternative approach, the so-called Balance Method, is used to determine the total amount of plastics thermally recovered in Austria’s waste incineration facilities in 2014. The results indicate that the plastics content in the waste feed may vary considerably among different plants but also over time. Monthly averages determined range between 8 and 26 wt% of waste plastics. The study reveals an average waste plastics content in the feed of Austria’s waste-to-energy plants of 16.5 wt%, which is considerably above findings from sorting campaigns conducted in Austria. In total, about 385 kt of waste plastics were thermally recovered in all Austrian waste-to-energy plants in 2014, which equals to 45 kg plastics cap-1. In addition, the amount of plastics co-combusted in industrial plants yields a total thermal utilisation rate of 70 kg cap-1 a-1 for Austria. This is significantly above published rates, for example, in Germany reported rates for 2013 are in the range of only 40 kg of waste plastics combusted per capita. PMID:27474393

  2. Determining the amount of waste plastics in the feed of Austrian waste-to-energy facilities.

    PubMed

    Schwarzböck, Therese; Van Eygen, Emile; Rechberger, Helmut; Fellner, Johann

    2017-02-01

    Although thermal recovery of waste plastics is widely practiced in many European countries, reliable information on the amount of waste plastics in the feed of waste-to-energy plants is rare. In most cases the amount of plastics present in commingled waste, such as municipal solid waste, commercial, or industrial waste, is estimated based on a few waste sorting campaigns, which are of limited significance with regard to the characterisation of plastic flows. In the present study, an alternative approach, the so-called Balance Method, is used to determine the total amount of plastics thermally recovered in Austria's waste incineration facilities in 2014. The results indicate that the plastics content in the waste feed may vary considerably among different plants but also over time. Monthly averages determined range between 8 and 26 wt% of waste plastics. The study reveals an average waste plastics content in the feed of Austria's waste-to-energy plants of 16.5 wt%, which is considerably above findings from sorting campaigns conducted in Austria. In total, about 385 kt of waste plastics were thermally recovered in all Austrian waste-to-energy plants in 2014, which equals to 45 kg plastics cap -1 . In addition, the amount of plastics co-combusted in industrial plants yields a total thermal utilisation rate of 70 kg cap -1  a -1 for Austria. This is significantly above published rates, for example, in Germany reported rates for 2013 are in the range of only 40 kg of waste plastics combusted per capita.

  3. Cleanup Verification Package for the 118-F-6 Burial Ground

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    H. M. Sulloway

    2008-10-02

    This cleanup verification package documents completion of remedial action for the 118-F-6 Burial Ground located in the 100-FR-2 Operable Unit of the 100-F Area on the Hanford Site. The trenches received waste from the 100-F Experimental Animal Farm, including animal manure, animal carcasses, laboratory waste, plastic, cardboard, metal, and concrete debris as well as a railroad tank car.

  4. Wearable and flexible thermoelectric generator with enhanced package

    NASA Astrophysics Data System (ADS)

    Francioso, L.; De Pascali, C.; Taurino, A.; Siciliano, P.; De Risi, A.

    2013-05-01

    Present work shows recent progresses in thin film-based flexible and wearable thermoelectric generator (TEG), finalized to support energy scavenging and local storage for low consumption electronics in Ambient Assisted Living (AAL) applications and buildings integration. The proposed TEG is able to recover energy from heat dispersed into the environment converting a thermal gradient to an effective electrical energy available to power ultra-low consumption devices. A low cost fabrication process based on planar thin-film technology was optimized to scale down the TEG dimensions to micrometer range. The prototype integrates 2778 thermocouples of sputtered Sb2Te3 and Bi2Te3 thin films (1 μm thick) on an area of 25 cm2. The electrical properties of thermoelectric materials were investigated by Van der Pauw measurements. Transfer Length Method (TLM) analysis was performed on three different multi-layer contact schemes in order to select the best solution to use for the definition of the contact pads realized on each section of the thermoelectric array configuration to allow electrical testing of single production areas. Kapton polyimide film was used as flexible substrate in order to add comfortable lightweight and better wearability to the device. The realized TEG is able to autonomously recover the thermal gradient useful to thermoelectric generation thanks to an appropriate package designed and optimized by a thermal analysis based on finite element method (FEM). The proposed package solution consists in coupling the module realized onto Kapton foil to a PDMS layer opportunely molded to thermally insulate TEG cold junctions and enhance the thermal gradient useful for the energy scavenging. Simulations results were compared to experimental tests performed by a thermal infrared camera, in order to evaluate the real performance of the designed package. First tests conducted on the realized TEG indicate that the prototype is able to recover about 5°C between hot and

  5. Electrical power production from low-grade waste heat using a thermally regenerative ethylenediamine battery

    NASA Astrophysics Data System (ADS)

    Rahimi, Mohammad; D'Angelo, Adriana; Gorski, Christopher A.; Scialdone, Onofrio; Logan, Bruce E.

    2017-05-01

    Thermally regenerative ammonia-based batteries (TRABs) have been developed to harvest low-grade waste heat as electricity. To improve the power production and anodic coulombic efficiency, the use of ethylenediamine as an alternative ligand to ammonia was explored here. The power density of the ethylenediamine-based battery (TRENB) was 85 ± 3 W m-2-electrode area with 2 M ethylenediamine, and 119 ± 4 W m-2 with 3 M ethylenediamine. This power density was 68% higher than that of TRAB. The energy density was 478 Wh m-3-anolyte, which was ∼50% higher than that produced by TRAB. The anodic coulombic efficiency of the TRENB was 77 ± 2%, which was more than twice that obtained using ammonia in a TRAB (35%). The higher anodic efficiency reduced the difference between the anode dissolution and cathode deposition rates, resulting in a process more suitable for closed loop operation. The thermal-electric efficiency based on ethylenediamine separation using waste heat was estimated to be 0.52%, which was lower than that of TRAB (0.86%), mainly due to the more complex separation process. However, this energy recovery could likely be improved through optimization of the ethylenediamine separation process.

  6. Cleanup Verification Package for the 100-F-20, Pacific Northwest Laboratory Parallel Pits

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    M. J. Appel

    2007-01-22

    This cleanup verification package documents completion of remedial action for the 100-F-20, Pacific Northwest Laboratory Parallel Pits waste site. This waste site consisted of two earthen trenches thought to have received both radioactive and nonradioactive material related to the 100-F Experimental Animal Farm.

  7. Pyrolysis behavior of different type of materials contained in the rejects of packaging waste sorting plants.

    PubMed

    Adrados, A; De Marco, I; Lopez-Urionabarrenechea, A; Caballero, B M; Laresgoiti, M F

    2013-01-01

    In this paper rejected streams coming from a waste packaging material recovery facility have been characterized and separated into families of products of similar nature in order to determine the influence of different types of ingredients in the products obtained in the pyrolysis process. The pyrolysis experiments have been carried out in a non-stirred batch 3.5 dm(3) reactor, swept with 1 L min(-1) N(2), at 500°C for 30 min. Pyrolysis liquids are composed of an organic phase and an aqueous phase. The aqueous phase is greater as higher is the cellulosic material content in the sample. The organic phase contains valuable chemicals as styrene, ethylbenzene and toluene, and has high heating value (HHV) (33-40 MJ kg(-1)). Therefore they could be used as alternative fuels for heat and power generation and as a source of valuable chemicals. Pyrolysis gases are mainly composed of hydrocarbons but contain high amounts of CO and CO(2); their HHV is in the range of 18-46 MJ kg(-1). The amount of COCO(2) increases, and consequently HHV decreases as higher is the cellulosic content of the waste. Pyrolysis solids are mainly composed of inorganics and char formed in the process. The cellulosic materials lower the quality of the pyrolysis liquids and gases, and increase the production of char. Copyright © 2012 Elsevier Ltd. All rights reserved.

  8. Prevalence of pesticides in postconsumer agrochemical polymeric packaging.

    PubMed

    Eras, J; Costa, J; Vilaró, F; Pelacho, A M; Canela-Garayoa, R; Martin-Closas, L

    2017-02-15

    Pesticide remains contained in agrochemical packaging waste are a source of uncontrolled risk for human health; they are also a quality feedstock for the plastic recycling industry. Many governments have recently started to establish laws and regulations to develop systems for recovering and recycling the polymeric packages used for pesticides. There is also a demand in having a procedure to control the suitability of the pesticide packages to be reused. We have developed a two-step operation process to assess the pesticide residues in agricultural containers made of a variety of polymeric matrices. The procedure is based on an extraction with a solvent mixture followed by UPLC-MS/MS determination. Solvents for neutral pesticides were selected considering the Hildebrand solubility (δ) of solvents and polymers together with those estimated for the pesticides. The proposed technique is effective in recovering imbibed pesticides in polymeric matrices. Also, a simplified extraction procedure has been tested to become a routine method for these wastes. We have found that in many cases a significant amount of pesticides remain into the polymeric matrix, even after a standardized cleaning; the impact of releasing these hazardous compounds into the environment is to be of further consideration. Copyright © 2016 Elsevier B.V. All rights reserved.

  9. Long duration exposure facility post-flight thermal analysis: Orbital/thermal environment data package

    NASA Technical Reports Server (NTRS)

    Berrios, William M.

    1990-01-01

    A post flight mission thermal environment for the Long Duration Exposure Facility was created as part of the thermal analysis data reduction effort. The data included herein is the thermal parameter data used in the calculation of boundary temperatures. This boundary temperature data is to be released in the near future for use by the LDEF principal investigators in the final analysis of their particular experiment temperatures. Also included is the flight temperature data as recorded by the LDEF Thermal Measurements System (THERM) for the first 90 days of flight.

  10. Adequacy of a Small Quantity Site RH-TRU Waste Program in Meeting Proposed WIPP Characterization Objectives

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Biedscheid, J.; Stahl, S.; Devarakonda, M.

    2002-02-26

    The first remote-handled transuranic (RH-TRU) waste is expected to be permanently disposed of at the Waste Isolation Pilot Plant (WIPP) during Fiscal Year (FY) 2003. The first RH-TRU waste shipments are scheduled from the Battelle Columbus Laboratories (BCL) to WIPP in order to facilitate compliance with BCL Decommissioning Project (BCLDP) milestones. Milestones requiring RH-TRU waste containerization and removal from the site by 2004 in order to meet a 2006 site closure goal, established by Congress in the Defense Facilities Closure Projects account, necessitated the establishment and implementation of a site-specific program to direct the packaging of BCLDP RH-TRU waste priormore » to the finalization of WIPP RH-TRU waste characterization requirements. The program was designed to collect waste data, including audio and videotape records of waste packaging, such that upon completion of waste packaging, comprehensive data records exist from which compliance with final WIPP RH-TRU waste characterization requirements can be demonstrated. With the BCLDP data records generated to date and the development by the U.S. Department of Energy (DOE)-Carlsbad Field Office (CBFO) of preliminary documents proposing the WIPP RH-TRU waste characterization program, it is possible to evaluate the adequacy of the BCLDP program with respect to meeting proposed characterization objectives. The BCLDP characterization program uses primarily acceptable knowledge (AK) and visual examination (VE) during waste packaging to characterize RH-TRU waste. These methods are used to estimate physical waste parameters, including weight percentages of metals, cellulosics, plastics, and rubber in the waste, and to determine the absence of prohibited items, including free liquids. AK combined with computer modeling is used to estimate radiological waste parameters, including total activity on a waste container basis, for the majority of BCLDP RH-TRU waste. AK combined with direct analysis is used to

  11. Plastic flexible films waste management - A state of art review.

    PubMed

    Horodytska, O; Valdés, F J; Fullana, A

    2018-04-21

    Plastic flexible films are increasingly used in many applications due to their lightness and versatility. In 2014, the amount of plastic films represented 34% of total plastic packaging produced in UK. The flexible film waste generation rises according to the increase in number of applications. Currently, in developed countries, about 50% of plastics in domestic waste are films. Moreover, about 615,000 tonnes of agricultural flexible waste are generated in the EU every year. A review of plastic films recycling has been conducted in order to detect the shortcomings and establish guidelines for future research. This paper reviews plastic films waste management technologies from two different sources: post-industrial and post-consumer. Clean and homogeneous post-industrial waste is recycled through closed-loop or open-loop mechanical processes. The main differences between these methods are the quality and the application of the recycled materials. Further research should be focused on closing the loops to obtain the highest environmental benefits of recycling. This could be accomplished through minimizing the material degradation during mechanical processes. Regarding post-consumer waste, flexible films from agricultural and packaging sectors have been assessed. The agricultural films and commercial and industrial flexible packaging are recycled through open-loop mechanical recycling due to existing selective waste collection routes. Nevertheless, the contamination from the use phase adversely affects the quality of recycled plastics. Therefore, upgrading of current washing lines is required. On the other hand, household flexible packaging shows the lowest recycling rates mainly because of inefficient sorting technologies. Delamination and compatibilization methods should be further developed to ensure the recycling of multilayer films. Finally, Life Cycle Assessment (LCA) studies on waste management have been reviewed. A lack of thorough LCA on plastic films waste

  12. Ultra Low Temperature Ultra Low Power Instrument Packages for Planetary Surfaces

    NASA Technical Reports Server (NTRS)

    Clark, P. E.; Millar, P. S.; Beaman, B.; Yeh, P. S.; Cooper, L.; Feng, S.; Young, E.

    2010-01-01

    Achievement of solar system exploration roadmap goals will involve robotic or human deployment and longterm operation of surface science packages remote from human presence, thus requiring autonomous, self-powered operation. The major challenge such packages face will be operating during long periods of darkness in extreme cold potentially without the Pu238 based power and thermal systems available to Apollo era packages (ALSEP). Development of such science payloads will thus require considerable optimization of instrument and subsystem design, packaging and integration for a variety of planetary surface environments in order to support solar system exploration fully. Our work supports this process through the incorporation of low temperature operational components and design strategies which radically minimize power, mass, and cost while maximizing the performance under extreme surface conditions that are in many cases more demanding than those routinely experienced by spacecraft in deep space. Chief instruments/instrument package candidates include those which could provide long-term monitoring of the surface and subsurface environments for fundamental science and human crew safety. The initial attempt to design a 10 instrument environmental monitoring package with a solar/battery based power system led to a package with a unacceptably large mass (500 kg) of which over half was battery mass. In phase 1, a factor of 5 reduction in mass was achieved, first through the introduction of high performance electronics capable of operating at far lower temperature and then through the use of innovative thermal balance strategies involving the use of multi-layer thin materials and gravity-assisted heat pipes. In phase 2, reported here, involves strategies such as universal incorporation of ULT/ULP digital and analog electronics, and distributed or non-conventionally packaged power systems. These strategies will be required to meet the far more challenging thermal

  13. Nevada Test Site Waste Acceptance Criteria

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    U. S. Department of Energy, National Nuclear Security Administration Nevada Site Office

    This document establishes the U.S. Department of Energy (DOE), National Nuclear Security Administration Nevada Site Office (NNSA/NSO) waste acceptance criteria (WAC). The WAC provides the requirements, terms, and conditions under which the Nevada Test Site (NTS) will accept low-level radioactive (LLW) and mixed waste (MW) for disposal. It includes requirements for the generator waste certification program, characterization, traceability, waste form, packaging, and transfer. The criteria apply to radioactive waste received at the NTS Area 3 and Area 5 Radioactive Waste Management Complex (RWMC) for storage or disposal.

  14. Reliability of CGA/LGA/HDI Package Board/Assembly (Revision A)

    NASA Technical Reports Server (NTRS)

    Ghaffarian, Reza

    2013-01-01

    This follow-up report presents reliability test results conducted by thermal cycling of five CGA assemblies evaluated under two extreme cycle profiles, representative of use for high-reliability applications. The thermal cycles ranged from a low temperature of 55 C to maximum temperatures of either 100 C or 125 C with slow ramp-up rate (3 C/min) and dwell times of about 15 minutes at the two extremes. Optical photomicrographs that illustrate key inspection findings of up to 200 thermal cycles are presented. Other information presented include an evaluation of the integrity of capacitors on CGA substrate after thermal cycling as well as process evaluation for direct assembly of an LGA onto PCB. The qualification guidelines, which are based on the test results for CGA/LGA/HDI packages and board assemblies, will facilitate NASA projects' use of very dense and newly available FPGA area array packages with known reliably and mitigation risks, allowing greater processing power in a smaller board footprint and lower system weight.

  15. Concept for Underground Disposal of Nuclear Waste

    NASA Technical Reports Server (NTRS)

    Bowyer, J. M.

    1987-01-01

    Packaged waste placed in empty oil-shale mines. Concept for disposal of nuclear waste economically synergistic with earlier proposal concerning backfilling of oil-shale mines. New disposal concept superior to earlier schemes for disposal in hard-rock and salt mines because less uncertainty about ability of oil-shale mine to contain waste safely for millenium.

  16. Processing Plan for Potentially Reactive/Ignitable Remote Handled Transuranic Waste at the Idaho Cleanup Project - 12090

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Troescher, Patrick D.; Hobbes, Tammy L.; Anderson, Scott A.

    Remote Handle Transuranic (RH-TRU) Waste generated at Argonne National Laboratory - East, from the examination of irradiated and un-irradiated fuel pins and other reactor materials requires a detailed processing plan to ensure reactive/ignitable material is absent to meet WIPP Waste Acceptance Criteria prior to shipping and disposal. The Idaho Cleanup Project (ICP) approach to repackaging Lot 2 waste and how we ensure prohibited materials are not present in waste intended for disposal at Waste Isolation Pilot Plant 'WIPP' uses an Argon Repackaging Station (ARS), which provides an inert gas blanket. Opening of the Lot 2 containers under an argon gasmore » blanket is proposed to be completed in the ARS. The ARS is an interim transition repackaging station that provides a mitigation technique to reduce the chances of a reoccurrence of a thermal event prior to rendering the waste 'Safe'. The consequences, should another thermal event be encountered, (which is likely) is to package the waste, apply the reactive and or ignitable codes to the container, and store until the future treatment permit and process are available. This is the same disposition that the two earlier containers in the 'Thermal Events' were assigned. By performing the initial handling under an inert gas blanket, the waste can sorted and segregate the fines and add the Met-L-X to minimize risk before it is exposed to air. The 1-gal cans that are inside the ANL-E canister will be removed and each can is moved to the ARS for repackaging. In the ARS, the 1-gal can is opened in the inerted environment. The contained waste is sorted, weighed, and visually examined for non compliant items such as unvented aerosol cans and liquids. The contents of the paint cans are transferred into a sieve and manipulated to allow the fines, if any, to be separated into the tray below. The fines are weighed and then blended with a minimum 5:1 mix of Met-L-X. Other debris materials found are segregated from the cans into

  17. A Thermally-Regenerative Ammonia-Based Flow Battery for Electrical Energy Recovery from Waste Heat.

    PubMed

    Zhu, Xiuping; Rahimi, Mohammad; Gorski, Christopher A; Logan, Bruce

    2016-04-21

    Large amounts of low-grade waste heat (temperatures <130 °C) are released during many industrial, geothermal, and solar-based processes. Using thermally-regenerative ammonia solutions, low-grade thermal energy can be converted to electricity in battery systems. To improve reactor efficiency, a compact, ammonia-based flow battery (AFB) was developed and tested at different solution concentrations, flow rates, cell pairs, and circuit connections. The AFB achieved a maximum power density of 45 W m(-2) (15 kW m(-3) ) and an energy density of 1260 Wh manolyte (-3) , with a thermal energy efficiency of 0.7 % (5 % relative to the Carnot efficiency). The power and energy densities of the AFB were greater than those previously reported for thermoelectrochemical and salinity-gradient technologies, and the voltage or current could be increased using stacked cells. These results demonstrated that an ammonia-based flow battery is a promising technology to convert low-grade thermal energy to electricity. © 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  18. Multi-material classification of dry recyclables from municipal solid waste based on thermal imaging.

    PubMed

    Gundupalli, Sathish Paulraj; Hait, Subrata; Thakur, Atul

    2017-12-01

    There has been a significant rise in municipal solid waste (MSW) generation in the last few decades due to rapid urbanization and industrialization. Due to the lack of source segregation practice, a need for automated segregation of recyclables from MSW exists in the developing countries. This paper reports a thermal imaging based system for classifying useful recyclables from simulated MSW sample. Experimental results have demonstrated the possibility to use thermal imaging technique for classification and a robotic system for sorting of recyclables in a single process step. The reported classification system yields an accuracy in the range of 85-96% and is comparable with the existing single-material recyclable classification techniques. We believe that the reported thermal imaging based system can emerge as a viable and inexpensive large-scale classification-cum-sorting technology in recycling plants for processing MSW in developing countries. Copyright © 2017 Elsevier Ltd. All rights reserved.

  19. Integrated software system for low level waste management

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Worku, G.

    1995-12-31

    In the continually changing and uncertain world of low level waste management, many generators in the US are faced with the prospect of having to store their waste on site for the indefinite future. This consequently increases the set of tasks performed by the generators in the areas of packaging, characterizing, classifying, screening (if a set of acceptance criteria applies), and managing the inventory for the duration of onsite storage. When disposal sites become available, it is expected that the work will require re-evaluating the waste packages, including possible re-processing, re-packaging, or re-classifying in preparation for shipment for disposal undermore » the regulatory requirements of the time. In this day and age, when there is wide use of computers and computer literacy is at high levels, an important waste management tool would be an integrated software system that aids waste management personnel in conducting these tasks quickly and accurately. It has become evident that such an integrated radwaste management software system offers great benefits to radwaste generators both in the US and other countries. This paper discusses one such approach to integrated radwaste management utilizing some globally accepted radiological assessment software applications.« less

  20. NEVADA TEST SITE WASTE ACCEPTANCE CRITERIA

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    U.S. DEPARTMENT OF ENERGY, NATIONAL NUCLEAR SECURITY ADMINISTRATION, NEVADA SITE OFFICE

    This document establishes the U. S. Department of Energy, National Nuclear Security Administration Nevada Site Office (NNSA/NSO) waste acceptance criteria (WAC). The WAC provides the requirements, terms, and conditions under which the Nevada Test Site will accept low-level radioactive and mixed waste for disposal. Mixed waste generated within the State of Nevada by NNSA/NSO activities is accepted for disposal. It includes requirements for the generator waste certification program, characterization, traceability, waste form, packaging, and transfer. The criteria apply to radioactive waste received at the Nevada Test Site Area 3 and Area 5 Radioactive Waste Management Site for storage or disposal.

  1. Consideration of Thermoelectric Power Generation by Using Hot Spring Thermal Energy or Industrial Waste Heat

    NASA Astrophysics Data System (ADS)

    Sasaki, Keiichi; Horikawa, Daisuke; Goto, Koichi

    2015-01-01

    Today, we face some significant environmental and energy problems such as global warming, urban heat island, and the precarious balance of world oil supply and demand. However, we have not yet found a satisfactory solution to these problems. Waste heat recovery is considered to be one of the best solutions because it can improve energy efficiency by converting heat exhausted from plants and machinery to electric power. This technology would also prevent atmospheric temperature increases caused by waste heat, and decrease fossil fuel consumption by recovering heat energy, thus also reducing CO2 emissions. The system proposed in this research generates electric power by providing waste heat or unharnessed thermal energy to built-in thermoelectric modules that can convert heat into electric power. Waste heat can be recovered from many places, including machinery in industrial plants, piping in electric power plants, waste incineration plants, and so on. Some natural heat sources such as hot springs and solar heat can also be used for this thermoelectric generation system. The generated power is expected to be supplied to auxiliary machinery around the heat source, stored as an emergency power supply, and so on. The attributes of this system are (1) direct power generation using hot springs or waste heat; (2) 24-h stable power generation; (3) stand-alone power system with no noise and no vibration; and (4) easy maintenance attributed to its simple structure with no moving parts. In order to maximize energy use efficiency, the temperature difference between both sides of the thermoelectric (TE) modules built into the system need to be kept as large as possible. This means it is important to reduce thermal resistance between TE modules and heat source. Moreover, the system's efficiency greatly depends on the base temperature of the heat sources and the material of the system's TE modules. Therefore, in order to make this system practical and efficient, it is necessary to

  2. Compaction of Space Mission Wastes

    NASA Technical Reports Server (NTRS)

    Fisher, John; Pisharody, Suresh; Wignarajah, K.

    2004-01-01

    The current solid waste management system employed on the International Space Station (ISS) consists of compaction, storage, and disposal. Wastes such plastic food packaging and trash are compacted manually and wrapped in duct tape footballs by the astronauts. Much of the waste is simply loaded either into the empty Russian Progress vehicle for destruction on reentry or into Shuttle for return to Earth. This manual method is wasteful of crew time and does not transition well to far term missions. Different wastes onboard spacecraft vary considerably in their characteristics and in the appropriate method of management. In advanced life support systems for far term missions, recovery of resources such as water from the wastes becomes important. However waste such as plastic food packaging, which constitutes a large fraction of solid waste (roughly 21% on ISS, more on long duration missions), contains minimal recoverable resource. The appropriate management of plastic waste is waste stabilization and volume minimization rather than resource recovery. This paper describes work that has begun at Ames Research Center on development of a heat melt compactor that can be used on near term and future missions, that can minimize crew interaction, and that can handle wastes with a significant plastic composition. The heat melt compactor takes advantage of the low melting point of plastics to compact plastic materials using a combination of heat and pressure. The US Navy has demonstrated successful development of a similar unit for shipboard application. Ames is building upon the basic approach demonstrated by the Navy to develop an advanced heat melt type compactor for space mission type wastes.

  3. Type B drum packages

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    McCoy, J.C.

    1994-08-01

    The Type B drum packages (TBD) are conceptualized as a family of containers in which a single 208 L or 114 L (55 gal or 30 gal) drum containing Type B quantities of radioactive material (RAM) can be packaged for shipment. The TBD containers are being developed to fill a void in the packaging and transportation capabilities of the U.S. Department of Energy as no container packaging single drums of Type B RAM exists offering double containment. Several multiple-drum containers currently exist, as well as a number of shielded casks, but the size and weight of these containers present manymore » operational challenges for single-drum shipments. As an alternative, the TBD containers will offer up to three shielded versions (light, medium, and heavy) and one unshielded version, each offering single or optional double containment for a single drum. To reduce operational complexity, all versions will share similar design and operational features where possible. The primary users of the TBD containers are envisioned to be any organization desiring to ship single drums of Type B RAM, such as laboratories, waste retrieval activities, emergency response teams, etc. Currently, the TBD conceptual design is being developed with the final design and analysis to be completed in 1995 to 1996. Testing and certification of the unshielded version are planned to be completed in 1996 to 1997 with production to begin in 1997 to 1998.« less

  4. MUPUS --- a Suite of Small Instruments for the ROSETTA Surface Science Package to Measure the Thermal and Mechanical Properties of a Comet Nucleus

    NASA Astrophysics Data System (ADS)

    Spohn, T.; MUPUS Team

    1996-09-01

    The Surface Science Package, which will be deployed in course of the ROSETTA mission on the surface of the target comet, offers the unprecedented opportunity to study the physical properties and dominating processes of a comet nucleus in situ. While most SSP experiments focuse on composition and chemistry, the MUPUS instrument package is aimed to study the energy balance of the nucleus/coma interface and the evolution of key thermal and mechanical parameters. Unlike planetary evolution, cometary evolution is influenced by the energy input at the surface. The near surface layers are accessible with some effort and may thus be directly studied. A penetrator equipped with temperature sensors and heaters (MUPUS--PEN) aims to measure the vertical temperature distribution (PEN--TP) and the thermal conductivity (PEN--THC) in the first tens of centimeters of the nucleus as they evolve with time. A combined evaluation of the PEN--TP and PEN--THC data will allow to understand vertical surface heat flow into or from the comet nucleus and the energy balance of the comet. The surface temperature will be measured with an infrared thermal mapper (MUPUS TM). Both thermal sensors will provide a ground truth for IR data from the orbiter. The PEN--M sensor will measure mechanical properties like hardness and grain size during penetration. A compton backscatter densitometer (CBD) will be used to measure the density. Additional temperature sensors and penetrometers in the SSP's anchor(s) will supplement the data and expand the volume probed. The results will help to understand the onset of activity, gas and dust emission, which will be measured by the orbiter. Understanding the dominating processes and their time scales allows to determine the present state of the surface material ("Is the matter found close to the surface pristine?") as well as extrapolation both into the past and the future.

  5. Ethanolic extract of propolis for biodegradable films packaging enhanced with chitosan

    NASA Astrophysics Data System (ADS)

    Ismail, M. I.; Roslan, A.; Saari, N. S.; Hashim, K. H.; Kalamullah, M. R.

    2017-09-01

    The use of industrial organic waste which are chitosan and propolis as materials for the development of biodegradable and active packaging is economical and environmentally appealing. Processing of propolis-chitosan film can minimize waste, and produce low-cost added value biopolymer packaging films for targeted applications. This aims of this research is to develop and characterize a biodegradable films by incorporating chitosan with propolis extract to enhance the functional properties for potential use as active food packaging. The film's moisture content, solubility and antimicrobial activity increase due to increasing volume of propolis extract which are 0 ml, 1.2 ml and 2.4 ml of propolis extract. Propolis-chitosan film with 2.4 ml of propolis extract is more soluble in water compared to propolis-chitosan film with 0 ml of propolis extract and 1.2 ml of propolis extract. The higher the volume of the propolis extract used, the higher the solubility of film in the water. The moisture content also will increase when higher volume of propolis extract used. Characterization of moisture content, solubility and antimicrobial activities revealed the benefits of adding propolis extract into chitosan films and the potential of using the developed film as active food packaging.

  6. Waste-to-energy: Dehalogenation of plastic-containing wastes.

    PubMed

    Shen, Yafei; Zhao, Rong; Wang, Junfeng; Chen, Xingming; Ge, Xinlei; Chen, Mindong

    2016-03-01

    The dehalogenation measurements could be carried out with the decomposition of plastic wastes simultaneously or successively. This paper reviewed the progresses in dehalogenation followed by thermochemical conversion of plastic-containing wastes for clean energy production. The pre-treatment method of MCT or HTT can eliminate the halogen in plastic wastes. The additives such as alkali-based metal oxides (e.g., CaO, NaOH), iron powders and minerals (e.g., quartz) can work as reaction mediums and accelerators with the objective of enhancing the mechanochemical reaction. The dehalogenation of waste plastics could be achieved by co-grinding with sustainable additives such as bio-wastes (e.g., rice husk), recyclable minerals (e.g., red mud) via MCT for solid fuels production. Interestingly, the solid fuel properties (e.g., particle size) could be significantly improved by HTT in addition with lignocellulosic biomass. Furthermore, the halogenated compounds in downstream thermal process could be eliminated by using catalysts and adsorbents. Most dehalogenation of plastic wastes primarily focuses on the transformation of organic halogen into inorganic halogen in terms of halogen hydrides or salts. The integrated process of MCT or HTT with the catalytic thermal decomposition is a promising way for clean energy production. The low-cost additives (e.g., red mud) used in the pre-treatment by MCT or HTT lead to a considerable synergistic effects including catalytic effect contributing to the follow-up thermal decomposition. Copyright © 2015 Elsevier Ltd. All rights reserved.

  7. Applications in the Nuclear Industry for Thermal Spray Amorphous Metal and Ceramic Coatings

    NASA Astrophysics Data System (ADS)

    Blink, J.; Farmer, J.; Choi, J.; Saw, C.

    2009-06-01

    Amorphous metal and ceramic thermal spray coatings have been developed with excellent corrosion resistance and neutron absorption. These coatings, with further development, could be cost-effective options to enhance the corrosion resistance of drip shields and waste packages, and limit nuclear criticality in canisters for the transportation, aging, and disposal of spent nuclear fuel. Iron-based amorphous metal formulations with chromium, molybdenum, and tungsten have shown the corrosion resistance believed to be necessary for such applications. Rare earth additions enable very low critical cooling rates to be achieved. The boron content of these materials and their stability at high neutron doses enable them to serve as high efficiency neutron absorbers for criticality control. Ceramic coatings may provide even greater corrosion resistance for waste package and drip shield applications, although the boron-containing amorphous metals are still favored for criticality control applications. These amorphous metal and ceramic materials have been produced as gas-atomized powders and applied as near full density, nonporous coatings with the high-velocity oxy-fuel process. This article summarizes the performance of these coatings as corrosion-resistant barriers and as neutron absorbers. This article also presents a simple cost model to quantify the economic benefits possible with these new materials.

  8. Modeling Pumped Thermal Energy Storage with Waste Heat Harvesting

    NASA Astrophysics Data System (ADS)

    Abarr, Miles L. Lindsey

    This work introduces a new concept for a utility scale combined energy storage and generation system. The proposed design utilizes a pumped thermal energy storage (PTES) system, which also utilizes waste heat leaving a natural gas peaker plant. This system creates a low cost utility-scale energy storage system by leveraging this dual-functionality. This dissertation first presents a review of previous work in PTES as well as the details of the proposed integrated bottoming and energy storage system. A time-domain system model was developed in Mathworks R2016a Simscape and Simulink software to analyze this system. Validation of both the fluid state model and the thermal energy storage model are provided. The experimental results showed the average error in cumulative fluid energy between simulation and measurement was +/- 0.3% per hour. Comparison to a Finite Element Analysis (FEA) model showed <1% error for bottoming mode heat transfer. The system model was used to conduct sensitivity analysis, baseline performance, and levelized cost of energy of a recently proposed Pumped Thermal Energy Storage and Bottoming System (Bot-PTES) that uses ammonia as the working fluid. This analysis focused on the effects of hot thermal storage utilization, system pressure, and evaporator/condenser size on the system performance. This work presents the estimated performance for a proposed baseline Bot-PTES. Results of this analysis showed that all selected parameters had significant effects on efficiency, with the evaporator/condenser size having the largest effect over the selected ranges. Results for the baseline case showed stand-alone energy storage efficiencies between 51 and 66% for varying power levels and charge states, and a stand-alone bottoming efficiency of 24%. The resulting efficiencies for this case were low compared to competing technologies; however, the dual-functionality of the Bot-PTES enables it to have higher capacity factor, leading to 91-197/MWh levelized cost

  9. Consumption and production waste: another externality of tobacco use.

    PubMed

    Novotny, T E; Zhao, F

    1999-01-01

    To describe the waste produced by and environmental implications of individual cigarette consumption (filter tips, packages, and cartons) and tobacco manufacturing. All available articles and reports published since 1970 related to cigarette consumption and production waste were reviewed. Global cigarette consumption data were used to estimate cigarette butt and packaging waste quantities. Data from the Center for Marine Conservation's International Coastal Cleanup Project were used to describe some environmental impacts of tobacco-related trash. Data from the United States Environmental Protection Agency's (EPA's) Toxics Release Inventory and reported global cigarette consumption totals were used to estimate waste production from cigarette manufacturing. In 1995, an estimated 5.535 trillion cigarettes (27,675 million cartons and 276,753 million packages) were sold by the tobacco industry globally. Some of the wastes from these products were properly deposited, but a large amount of tobacco consumption waste ends up in the environment. Some is recovered during environmental clean-up days. For the past eight years (1990-1997), cigarette butts have been the leading item found during the International Coastal Cleanup Project; they accounted for 19.1% of all items collected in 1997. The tobacco manufacturing process produces liquid, solid, and airborne waste. Among those wastes, some materials, including nicotine, are designated by the EPA as Toxics Release Inventory (TRI) chemicals. These are possible environmental health hazards. In 1995, the global tobacco industry produced an estimated 2262 million kilograms of manufacturing waste and 209 million kilograms of chemical waste. In addition, total nicotine waste produced in the manufacture of reduced nicotine cigarettes was estimated at 300 million kilograms. Laws against littering relative to cigarette butts could be better enforced. Additional taxes might be levied on cigarette products that would then be directed to

  10. Food losses, shelf life extension and environmental impact of a packaged cheesecake: A life cycle assessment.

    PubMed

    Gutierrez, Michele Mario; Meleddu, Marta; Piga, Antonio

    2017-01-01

    Packaging is associated with a high environmental impact. This is also the case in the food industry despite packaging being necessary for maintaining food quality, safety assurance and preventing food waste. The aim of the present study was to identify improvements in food packaging solutions able to minimize environmental externalities while maximizing the economic sustainability. To this end, the life cycle assessment (LCA) methodology was applied to evaluate the environmental performance of new packaging solutions. The environmental impact of packaging and food losses and the balance between the two were examined in relation to a cheesecake that is normally packaged in low density polyethylene film and has a limited shelf life due to microbial growth. A shelf life extension was sought via application of the well-established modified atmosphere packaging (MAP) technique. Samples for MAP (N 2 /CO 2 : 70/30) were placed inside multilayer gas barrier trays, which were then wrapped with a multilayer gas and water barrier film (i.e. AerPack packaging); control batches were packaged in gas barrier recycled polyethylene terephthalate (XrPet) trays and wrapped with a XrPet film. Samples were then stored at 20°C and inspected at regular intervals for chemical-physical, microbiological and sensory parameters. Results show that the new packaging solution could considerably extend the shelf life of cheesecakes, thereby reducing food waste and decreasing the overall environmental impact. Moreover, the new packaging allows one to minimize transport costs and to generate economies of scale in manufacturing. Copyright © 2016 Elsevier Ltd. All rights reserved.

  11. Trash-to-Gas: Using Waste Products to Minimize Logistical Mass During Long Duration Space Missions

    NASA Technical Reports Server (NTRS)

    Hintze, Paul E.; Caraccio, A. J.; Anthony, S. M.; Tsoras, A. N.; Devor, Robert; Captain, James G.; Nur, Mononita

    2013-01-01

    Just as waste-to-energy processes utilizing municipal landftll and biomass wastes are finding increased terrestrial uses, the Trash-to-Gas (TtG) project seeks to convert waste generated during spaceflight into high value commodities. These include methane for propulsion and water for life support in addition to a variety of other gasses. TtG is part of the Logistic Reduction and Repurposing (LRR) project under the NASA Advanced Exploration Systems Program. The LRR project will enable a largely mission-independent approach to minimize logistics contributions to total mission architecture mass. LRR includes technologies that reduce the amount of consumables that need to be sent to space, repurpose items sent to space, or convert wastes to commodities. Currently, waste generated on the International Space Station is stored inside a logistic module which is de-orbited into Earth's atmosphere for destruction. The waste consists of food packaging, food, clothing and other items. This paper will discuss current results on incineration as a waste processing method. Incineration is part of a two step process to produce methane from waste: first the waste is converted to carbon oxides; second, the carbon oxides are fed to a Sabatier reactor where they are converted to methane. The quantities of carbon dioxide, carbon monoxide, methane and water were measured under the different thermal degradation conditions. The overall carbon conversion efficiency and water recovery are discussed

  12. Trash-to-Gas: Using Waste Products to Minimize Logistical Mass During Long Duration Space Missions

    NASA Technical Reports Server (NTRS)

    Hintze, Paul. E.; Caraccio, Anne J.; Anthony, Stephen M.; Tsoras, Alexandra N.; Nur, Monoita; Devor, Robert; Captain, James G.

    2013-01-01

    Just as waste-to-energy processes utilizing municipal landftll and biomass wastes are finding increased terrestrial uses, the Trash-to-Gas (TtG) project seeks to convert waste generated during spaceflight into high value commodities. These include methane for propulsion and water for life support in addition to a variety of other gasses. TtG is part of the Logistic Reduction and Repurposing (LRR) project under the NASA Advanced Exploration Systems Program. The LRR project will enable a largely mission-independent approach to minimize logistics contributions to total mission architecture mass. LRR includes technologies that reduce the amount of consumables that need to be sent to space, repurpose items sent to space, or convert wastes to commodities. Currently, waste generated on the International Space Station is stored inside a logistic module which is de-orbited into Earth's atmosphere for destruction. The waste consists of food packaging, food, clothing and other items. This paper will discuss current results on incineration as a waste processing method. Incineration is part of a two step process to produce methane from waste: first the waste is converted to carbon oxides; second, the carbon oxides are fed to a Sabatier reactor where they are converted to methane. The quantities of carbon dioxide, carbon monoxide, methane and water were measured under the different thermal degradation conditions. The overall carbon conversion efficiency and water recovery are discussed.

  13. An investigation on the modelling of kinetics of thermal decomposition of hazardous mercury wastes.

    PubMed

    Busto, Yailen; M G Tack, Filip; Peralta, Luis M; Cabrera, Xiomara; Arteaga-Pérez, Luis E

    2013-09-15

    The kinetics of mercury removal from solid wastes generated by chlor-alkali plants were studied. The reaction order and model-free method with an isoconversional approach were used to estimate the kinetic parameters and reaction mechanism that apply to the thermal decomposition of hazardous mercury wastes. As a first approach to the understanding of thermal decomposition for this type of systems (poly-disperse and multi-component), a novel scheme of six reactions was proposed to represent the behaviour of mercury compounds in the solid matrix during the treatment. An integration-optimization algorithm was used in the screening of nine mechanistic models to develop kinetic expressions that best describe the process. The kinetic parameters were calculated by fitting each of these models to the experimental data. It was demonstrated that the D₁-diffusion mechanism appeared to govern the process at 250°C and high residence times, whereas at 450°C a combination of the diffusion mechanism (D₁) and the third order reaction mechanism (F3) fitted the kinetics of the conversions. The developed models can be applied in engineering calculations to dimension the installations and determine the optimal conditions to treat a mercury containing sludge. Copyright © 2013 Elsevier B.V. All rights reserved.

  14. The role of waste thermal water in the soil degradation

    NASA Astrophysics Data System (ADS)

    Balog, Kitti; Farsang, Andrea

    2010-05-01

    Thermal water exploitation is widespread, because it is considered to a "green" renewable energy source, the transporter of the Earth crust's heat. It is suitable for very diverse purposes: balneology, heating, mineral water, municipal hot water supply, technological water, etc. After usage, large amount of thermal water becomes sewage water with high concentrations of salts, heavy metals, ammonia, nitrate, and high temperature. Besides that, most of these waters have an unfavourable ion composition. Na+ (and in some cases Mg+) is predominant among cations. A common way of treatment is to let off the waste thermal water in unlined ground channels to leak into the soil. This can cause physical and chemical soil degradation. Continouos Na+ supply occurs, that occupies the place of Ca2+ on the ion exchange surfaces. Thus, adverse effects of Na+ can appear, like formation of extreme moisture regime, peptization, liquefaction. Beside Na+, Mg2+ also helps the formation of physical degradation in the soil. High water retain and unfavourable structure evolves. Not only the physical features of the soil are touched, fertility of production sites as well. Namely sorrounding the unlined ground channels, agricultural areas are seated, so it is important to protect productivity of the soil to maintain yield. Because of the seepage of high salt concentration waters, salt accumulation can be observed near to the channel lines. The investigated sample sites are located in the Great Hungarian Plane. We determined the main pollutants of the thermal waters, and the effects to the sorrounding soils. On two selected investigation areas (Cserkeszőlő, Tiszakécske) salt profiles and Na+ adsorption isotherms are presented to characterize soil degradation. Genetic soil types are differ on the investigated areas, so the aspect of impact is different, as well.

  15. High barrier multilayer packaging by the coextrusion method: The effect of nanocomposites and biodegradable polymers on flexible film properties

    NASA Astrophysics Data System (ADS)

    Thellen, Christopher T.

    The objective of this research was to investigate the use of nanocomposite and multilayer co-extrusion technologies for the development of high gas barrier packaging that is more environmentally friendly than many current packaging system. Co-extruded bio-based and biodegradable polymers that could be composted in a municipal landfill were one direction that this research was aimed. Down-gauging of high performance barrier films using nanocomposite technology and co-extrusion was also investigated in order to reduce the amount of solid waste being generated by the packaging. Although the research is focused on military ration packaging, the technologies could easily be introduced into the commercial flexible packaging market. Multilayer packaging consisting of poly(m-xylylene adipamide) nanocomposite layers along with adhesive and tie layers was co-extruded using both laboratory and pilot-scale film extrusion equipment. Co-extrusion of biodegradable polyhydroxyalkanoates (PHA) along with polyvinyl alcohol (PVOH) and tie layers was also accomplished using similar co-extrusion technology. All multilayer films were characterized for gas barrier, mechanical, and thermal properties. The biodegradability of the PVOH and PHA materials in a marine environment was also investigated. The research has shown that co-extrusion of these materials is possible at a research and pilot level. The use of nanocomposite poly(m-xylylene adipamide) was effective in down-gauging the un-filled barrier film to thinner structures. Bio-based PHA/PVOH films required the use of a malefic anhydride grafted PHA tie layer to improve layer to layer adhesion in the structure to avoid delamination. The PHA polymer demonstrated a high rate of biodegradability/mineralization in the marine environment while the rate of biodegradation of the PVOH polymer was slower.

  16. Waste reduction through consumer education. Final report

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Harrison, E.Z.

    The Waste Reduction through Consumer Education research project was conducted to determine how environmental educational strategies influence purchasing behavior in the supermarket. The objectives were to develop, demonstrate, and evaluate consumer education strategies for waste reduction. The amount of waste generated by packaging size and form, with an adjustment for local recyclability of waste, was determined for 14 product categories identified as having more waste generating and less waste generating product choices (a total of 484 products). Using supermarket scan data and shopper identification numbers, the research tracked the purchases of shoppers in groups receiving different education treatments for 9more » months. Statistical tests applied to the purchase data assessed patterns of change between the groups by treatment period. Analysis of the data revealed few meaningful statistical differences between study groups or changes in behavior over time. Findings suggest that broad brush consumer education about waste reduction is not effective in changing purchasing behaviors in the short term. However, it may help create a general awareness of the issues surrounding excess packaging and consumer responsibility. The study concludes that the answer to waste reduction in the future may be a combination of voluntary initiatives by manufacturers and retailers, governmental intervention, and better-informed consumers.« less

  17. Early thermal testing of type B radioactive material packages in USA to environments beyond regulatory package thermal test standards

    DOE PAGES

    Yoshimura, H. R.; Pope, R. B.; Kubo, M.

    2007-06-01

    Three separate fire test programmes exposing casks beyond the regulatory thermal test requirements were performed by Sandia National Laboratories during the late 1970s and mid 1980s. The results of these test programmes can be used to assist in addressing the adequacy of the regulatory thermal test of fully engulfing exposure at 800°C for 30 min and how that test might relate to real accident thermal environments. The test programmes were undertaken on obsolete and new casks on behalf of the US Department of Energy (DOE), the US Department of Transportation (DOT) and the Japanese Power Reactor and Nuclear Fuel Developmentmore » Corporation (PNC), currently known as the Japan Atomic Energy Agency. Two of the tests involved exposure of casks in damaged transport vehicles to fully engulfing fires for 72–125 min, and the other test involved four exposures of a cask to torch environments for 30 min. Much of the original documentation regarding these tests and their results is no longer readily available. The documents relating to these tests have been surveyed; this paper presents summaries from this survey of the tests and their results. Specifically, for the pool fire exposures, the temperatures measured in the flames of both exceeded the flame temperature required by the Transport Regulations; yet an obsolete 67 t cask endured 90 min of exposure before evidence of failure was detected, and a new cask endured the 72 min exposure while retaining its containment integrity. For the exposure of a modified obsolete cask to four different torch environments, the integrity of the cask was retained and the relative temperature increases within the cask were well within acceptable limits and well below the values that could be expected if the cask was exposed to the regulatory thermal test. In this paper, a review of these three thermal test programmes, establishes that the two older cask designs and one new cask design have the ability to survive environments that were

  18. A User-Friendly Software Package for HIFU Simulation

    NASA Astrophysics Data System (ADS)

    Soneson, Joshua E.

    2009-04-01

    A freely-distributed, MATLAB (The Mathworks, Inc., Natick, MA)-based software package for simulating axisymmetric high-intensity focused ultrasound (HIFU) beams and their heating effects is discussed. The package (HIFU_Simulator) consists of a propagation module which solves the Khokhlov-Zabolotskaya-Kuznetsov (KZK) equation and a heating module which solves Pennes' bioheat transfer (BHT) equation. The pressure, intensity, heating rate, temperature, and thermal dose fields are computed, plotted, the output is released to the MATLAB workspace for further user analysis or postprocessing.

  19. Monolithic microwave integrated circuits: Interconnections and packaging considerations

    NASA Technical Reports Server (NTRS)

    Bhasin, K. B.; Downey, A. N.; Ponchak, G. E.; Romanofsky, R. R.; Anzic, G.; Connolly, D. J.

    1984-01-01

    Monolithic microwave integrated circuits (MMIC's) above 18 GHz were developed because of important potential system benefits in cost reliability, reproducibility, and control of circuit parameters. The importance of interconnection and packaging techniques that do not compromise these MMIC virtues is emphasized. Currently available microwave transmission media are evaluated to determine their suitability for MMIC interconnections. An antipodal finline type of microstrip waveguide transition's performance is presented. Packaging requirements for MMIC's are discussed for thermal, mechanical, and electrical parameters for optimum desired performance.

  20. Monolithic microwave integrated circuits: Interconnections and packaging considerations

    NASA Astrophysics Data System (ADS)

    Bhasin, K. B.; Downey, A. N.; Ponchak, G. E.; Romanofsky, R. R.; Anzic, G.; Connolly, D. J.

    Monolithic microwave integrated circuits (MMIC's) above 18 GHz were developed because of important potential system benefits in cost reliability, reproducibility, and control of circuit parameters. The importance of interconnection and packaging techniques that do not compromise these MMIC virtues is emphasized. Currently available microwave transmission media are evaluated to determine their suitability for MMIC interconnections. An antipodal finline type of microstrip waveguide transition's performance is presented. Packaging requirements for MMIC's are discussed for thermal, mechanical, and electrical parameters for optimum desired performance.

  1. Physical and thermal processing of Waste Printed Circuit Boards aiming for the recovery of gold and copper.

    PubMed

    Ventura, E; Futuro, A; Pinho, S C; Almeida, M F; Dias, J M

    2018-06-20

    The recovery of electronic waste to obtain secondary raw materials is a subject of high relevance in the context of circular economy. Accordingly, the present work relies on the evaluation of mining separation/concentration techniques (comminution, size screening, magnetic separation and gravity concentration) alone as well as combined with thermal pre-treatment to recover gold and copper from Waste Printed Circuit Boards. For that purpose, Waste Printed Circuit Boards were subjected to physical processing (comminution, size screening in 6 classes from <0.425 mm to > 6.70 mm, magnetic separation and gravity concentration) alone and combined with thermal treatment (200-500 °C), aiming the recovery of gold and copper. Mixed motherboards and graphic cards (Lot 1 and 3) and highly rich components (connectors separated from memory cards, Lot 2) were analyzed. Gold and copper concentrations were determined before and after treatment. Before treatment, concentrations from 0.01 to 0.6 % wt. and from 9 to 20 % wt. were found for gold and copper respectively. The highest concentrations were observed in the size fractions between 0.425 and 1.70 mm. The highest copper concentration was around 35 % wt. (class 0.425-0.85 mm) and when analyzing memory card connectors alone, gold concentrations reached almost 2% in the same class, reflecting the interest of separating such components. The physical treatment alone was more effective for Lot 1/3, compared to Lot 2, allowing recoveries of 67 % wt. and 87 % wt. for gold and copper respectively, mostly due to differences in particles size and shape. The thermal treatment showed unperceptive influence on gold concentration but significant effect for copper concentration, mostly attributed to the size of the copper particles. Concentrations increased in a factor of around 10 when the thermal treatment was performed at 300 °C for the larger particles (1.70-6.70 mm); the best results were obtained at 400 °C for the

  2. Potential of thermal treatment for decontamination of mercury containing wastes from chlor-alkali industry.

    PubMed

    Busto, Y; Cabrera, X; Tack, F M G; Verloo, M G

    2011-02-15

    Old dumps of mercury waste sludges from chlor-alkaline industry are an environmental threat if not properly secured. Thermal retortion can be used to remove mercury from such wastes. This treatment reduces the total mercury content, and also may reduce the leachability of the residual mercury. The effects of treatment temperature and treatment time on both residual mercury levels and mercury leachability according to the US EPA TCLP leaching procedure, were investigated. Treatment for 1h at 800°C allowed to quantitatively remove the mercury. Treatment at 400°C and above allowed to decrease the leachable Hg contents to below the US EPA regulations. The ultimate choice of treatment conditions will depend on requirements of further handling options and cost considerations. Copyright © 2010 Elsevier B.V. All rights reserved.

  3. Characterizing emissions from open burning of military food waste and ration packaging compositions

    EPA Science Inventory

    Emissions from open burning of Meals, Ready-To-Eat (MRE) and MRE packaging were characterized in response to inhalation concerns at military forward operating bases. Emissions from four compositions of MREs and four types of packaging were compared to assess contributions of ind...

  4. Antimicrobial agent-free hybrid cationic starch/sodium alginate polyelectrolyte films for food packaging materials.

    PubMed

    Şen, Ferhat; Uzunsoy, İrem; Baştürk, Emre; Kahraman, Memet Vezir

    2017-08-15

    This study aimed to develop polyelectrolyte structured antimicrobial food packaging materials that do not contain any antimicrobial agents. Cationic starch was synthesized and characterized by FT-IR spectroscopy and 1 H NMR spectroscopy. Its nitrogen content was determined by Kjeldahl method. Polyelectrolyte structured antimicrobial food packaging materials were prepared using starch, cationic starch and sodium alginate. Antimicrobial activity of materials was defined by inhibition zone method (disc diffusion method). Thermal stability of samples was evaluated by TGA and DSC. Hydrophobicity of samples was determined by contact angle measurements. Surface morphology of samples was investigated by SEM. Moreover, gel contents of samples were determined. The obtained results prove that produced food packaging materials have good thermal, antimicrobial and surface properties, and they can be used as food packaging material in many industries. Copyright © 2017 Elsevier Ltd. All rights reserved.

  5. Reliability assessment of ceramic column grid array (CCGA717) interconnect packages under extreme temperatures for space applications (-185°C to +125°C)

    NASA Astrophysics Data System (ADS)

    Ramesham, Rajeshuni

    2010-02-01

    Ceramic Column Grid Array packages have been increasing in use based on their advantages such as high interconnect density, very good thermal and electrical performance, compatibility with standard surface-mount packaging assembly processes, etc. CCGA packages are used in space applications such as in logics and microprocessor functions, telecommunications, flight avionics, payload electronics, etc. As these packages tend to have less solder joint strain relief than leaded packages, the reliability of CCGA packages is very important for short and long-term space missions. CCGA interconnect electronic package printed wiring boards (PWBs) of polyimide have been assembled, inspected non-destructively and subsequently subjected to extreme temperature thermal cycling to assess the reliability for future deep space, short and long-term, extreme temperature missions. In this investigation, the employed temperature range covers from -185°C to +125°C extreme thermal environments. The test hardware consists of two CCGA717 packages with each package divided into four daisy-chained sections, for a total of eight daisy chains to be monitored. The CCGA717 package is 33 mm × 33 mm with a 27×27 array of 80%/20% Pb/Sn columns on a 1.27 mm pitch. The resistance of daisy-chained, CCGA interconnects were continuously monitored as a function of thermal cycling. Electrical resistance measurements as a function of thermal cycling are reported and the tests to date have shown significant change in daisy chain resistance as a function of thermal cycling. The change in interconnect resistance becomes more noticeable with increasing number of thermal cycles. This paper will describe the experimental test results of CCGA testing under wide extreme temperatures. Standard Weibull analysis tools were used to extract the Weibull parameters to understand the CCGA failures. Optical inspection results clearly indicate that the solder joints of columns with the board and the ceramic package have

  6. System analyses on advanced nuclear fuel cycle and waste management

    NASA Astrophysics Data System (ADS)

    Cheon, Myeongguk

    To evaluate the impacts of accelerator-driven transmutation of waste (ATW) fuel cycle on a geological repository, two mathematical models are developed: a reactor system analysis model and a high-level waste (HLW) conditioning model. With the former, fission products and residual trans-uranium (TRU) contained in HLW generated from a reference ATW plant operations are quantified and the reduction of TRU inventory included in commercial spent-nuclear fuel (CSNF) is evaluated. With the latter, an optimized waste loading and composition in solidification of HLW are determined and the volume reduction of waste packages associated with CSNF is evaluated. WACOM, a reactor system analysis code developed in this study for burnup calculation, is validated by ORIGEN2.1 and MCNP. WACOM is used to perform multicycle analysis for the reference lead-bismuth eutectic (LBE) cooled transmuter. By applying the results of this analysis to the reference ATW deployment scenario considered in the ATW roadmap, the HLW generated from the ATW fuel cycle is quantified and the reduction of TRU inventory contained in CSNF is evaluated. A linear programming (LP) model has been developed for determination of an optimized waste loading and composition in solidification of HLW. The model has been applied to a US-defense HLW. The optimum waste loading evaluated by the LP model was compared with that estimated by the Defense Waste Processing Facility (DWPF) in the US and a good agreement was observed. The LP model was then applied to the volume reduction of waste packages associated with CSNF. Based on the obtained reduction factors, the expansion of Yucca Mountain Repository (YMR) capacity is evaluated. It is found that with the reference ATW system, the TRU contained in CSNF could be reduced by a factor of ˜170 in terms of inventory and by a factor of ˜40 in terms of toxicity under the assumed scenario. The number of waste packages related to CSNF could be reduced by a factor of ˜8 in terms of

  7. G-189A analytical simulation of the integrated waste management-water system using radioisotopes for thermal energy

    NASA Technical Reports Server (NTRS)

    Coggi, J. V.; Loscutoff, A. V.; Barker, R. S.

    1973-01-01

    An analytical simulation of the RITE-Integrated Waste Management and Water Recovery System using radioisotopes for thermal energy was prepared for the NASA-Manned Space Flight Center (MSFC). The RITE system is the most advanced concept water-waste management system currently under development and has undergone extended duration testing. It has the capability of disposing of nearly all spacecraft wastes including feces and trash and of recovering water from usual waste water sources: urine, condensate, wash water, etc. All of the process heat normally used in the system is produced from low penalty radioisotope heat sources. The analytical simulation was developed with the G189A computer program. The objective of the simulation was to obtain an analytical simulation which can be used to (1) evaluate the current RITE system steady state and transient performance during normal operating conditions, and also during off normal operating conditions including failure modes; and (2) evaluate the effects of variations in component design parameters and vehicle interface parameters on system performance.

  8. Consumption and production waste: another externality of tobacco use

    PubMed Central

    Novotny, T.; Zhao, F.

    1999-01-01

    OBJECTIVE—To describe the waste produced by and environmental implications of individual cigarette consumption (filter tips, packages, and cartons) and tobacco manufacturing.
STUDY SELECTION—All available articles and reports published since 1970 related to cigarette consumption and production waste were reviewed.
DATA SOURCES—Global cigarette consumption data were used to estimate cigarette butt and packaging waste quantities. Data from the Center for Marine Conservation's International Coastal Cleanup Project were used to describe some environmental impacts of tobacco-related trash. Data from the United States Environmental Protection Agency's (EPA's) Toxics Release Inventory and reported global cigarette consumption totals were used to estimate waste production from cigarette manufacturing.
DATA EXTRACTION AND SYNTHESIS—In 1995, an estimated 5.535 trillion cigarettes (27 675 million cartons and 276 753 million packages) were sold by the tobacco industry globally. Some of the wastes from these products were properly deposited, but a large amount of tobacco consumption waste ends up in the environment. Some is recovered during environmental clean-up days. For the past eight years (1990-1997), cigarette butts have been the leading item found during the International Coastal Cleanup Project; they accounted for 19.1% of all items collected in 1997. The tobacco manufacturing process produces liquid, solid, and airborne waste. Among those wastes, some materials, including nicotine, are designated by the EPA as Toxics Release Inventory (TRI) chemicals. These are possible environmental health hazards. In 1995, the global tobacco industry produced an estimated 2262 million kilograms of manufacturing waste and 209 million kilograms of chemical waste. In addition, total nicotine waste produced in the manufacture of reduced nicotine cigarettes was estimated at 300 million kilograms.
CONCLUSIONS—Laws against littering relative to cigarette butts

  9. Life cycle assessment of thermal waste-to-energy technologies: review and recommendations.

    PubMed

    Astrup, Thomas Fruergaard; Tonini, Davide; Turconi, Roberto; Boldrin, Alessio

    2015-03-01

    Life cycle assessment (LCA) has been used extensively within the recent decade to evaluate the environmental performance of thermal Waste-to-Energy (WtE) technologies: incineration, co-combustion, pyrolysis and gasification. A critical review was carried out involving 250 individual case-studies published in 136 peer-reviewed journal articles within 1995 and 2013. The studies were evaluated with respect to critical aspects such as: (i) goal and scope definitions (e.g. functional units, system boundaries, temporal and geographic scopes), (ii) detailed technology parameters (e.g. related to waste composition, technology, gas cleaning, energy recovery, residue management, and inventory data), and (iii) modeling principles (e.g. energy/mass calculation principles, energy substitution, inclusion of capital goods and uncertainty evaluation). Very few of the published studies provided full and transparent descriptions of all these aspects, in many cases preventing an evaluation of the validity of results, and limiting applicability of data and results in other contexts. The review clearly suggests that the quality of LCA studies of WtE technologies and systems including energy recovery can be significantly improved. Based on the review, a detailed overview of assumptions and modeling choices in existing literature is provided in conjunction with practical recommendations for state-of-the-art LCA of Waste-to-Energy. Copyright © 2014 Elsevier Ltd. All rights reserved.

  10. A review on thermal and catalytic pyrolysis of plastic solid waste (PSW).

    PubMed

    Al-Salem, S M; Antelava, A; Constantinou, A; Manos, G; Dutta, A

    2017-07-15

    Plastic plays an important role in our daily lives due to its versatility, light weight and low production cost. Plastics became essential in many sectors such as construction, medical, engineering applications, automotive, aerospace, etc. In addition, economic growth and development also increased our demand and dependency on plastics which leads to its accumulation in landfills imposing risk on human health, animals and cause environmental pollution problems such as ground water contamination, sanitary related issues, etc. Hence, a sustainable and an efficient plastic waste treatment is essential to avoid such issues. Pyrolysis is a thermo-chemical plastic waste treatment technique which can solve such pollution problems, as well as, recover valuable energy and products such as oil and gas. Pyrolysis of plastic solid waste (PSW) has gained importance due to having better advantages towards environmental pollution and reduction of carbon footprint of plastic products by minimizing the emissions of carbon monoxide and carbon dioxide compared to combustion and gasification. This paper presents the existing techniques of pyrolysis, the parameters which affect the products yield and selectivity and identify major research gaps in this technology. The influence of different catalysts on the process as well as review and comparative assessment of pyrolysis with other thermal and catalytic plastic treatment methods, is also presented. Copyright © 2017 Elsevier Ltd. All rights reserved.

  11. Bionanocomposites materials for food packaging applications: Concepts and future outlook.

    PubMed

    Youssef, Ahmed M; El-Sayed, Samah M

    2018-08-01

    Bionanocomposites materials open a chance for the usage of novel, high performance, lightweight, and ecofriendly composite materials making them take place the traditional non-biodegradable plastic packaging materials. Biopolymers like polysaccharides such as chitosan (CS), carboxymethyl cellulose (CMC), starch and cellophane could be used to resolve environmental hazards owing to their biodegradability and non-toxicity. In addition these advantages, polysaccharides have some disadvantages for example poor mechanical properties and low resistance to water. Therefore, nanomaterials are used to improve the thermal, mechanical and gas barrier properties without hindering their biodegradable and non-toxic characters. Furthermore, the most favorable nanomaterials are layered silicate nanoclays for example montmorillonite (MMT) and kaolinite, zinc oxide (ZnO-NPs), titanium dioxide (TiO 2 -NPs), and silver nanoparticles (Ag-NPs). In packaging application, the improvement of barrier properties of prepared films against oxygen, carbon dioxide, flavor compounds diffusion through the packaging films. Wide varieties of nanomaterials are suitable to offer smart and/or intelligent properties for food packaging materials, as demonstrated by oxygen scavenging capability, antimicrobial activity, and sign of the level of exposure to various harmful features for instance oxygen levels or insufficient temperatures. The compatibility between nanomaterials and polymers matrix consider the most challenge for the preparation of bionanocomposites as well as getting whole distribution of nanoparticles into the polymer matrix. We keen in this review the development of packaging materials performance and their mechanical, degradability and thermal stability as well as antibacterial activity for utilization of bionanocomposites in different packaging application is considered. Copyright © 2018 Elsevier Ltd. All rights reserved.

  12. Treatment of electronic waste to recover metal values using thermal plasma coupled with acid leaching - A response surface modeling approach

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Rath, Swagat S., E-mail: swagat.rath@gmail.com; Nayak, Pradeep; Mukherjee, P.S.

    2012-03-15

    Highlights: Black-Right-Pointing-Pointer Sentences/phrases were modified. Black-Right-Pointing-Pointer Necessary discussions for different figures were included. Black-Right-Pointing-Pointer More discussion have been included on the flue gas analysis. Black-Right-Pointing-Pointer Queries to both the reviewers have been given. - Abstract: The global crisis of the hazardous electronic waste (E-waste) is on the rise due to increasing usage and disposal of electronic devices. A process was developed to treat E-waste in an environmentally benign process. The process consisted of thermal plasma treatment followed by recovery of metal values through mineral acid leaching. In the thermal process, the E-waste was melted to recover the metal values asmore » a metallic mixture. The metallic mixture was subjected to acid leaching in presence of depolarizer. The leached liquor mainly contained copper as the other elements like Al and Fe were mostly in alloy form as per the XRD and phase diagram studies. Response surface model was used to optimize the conditions for leaching. More than 90% leaching efficiency at room temperature was observed for Cu, Ni and Co with HCl as the solvent, whereas Fe and Al showed less than 40% efficiency.« less

  13. Space disposal of nuclear wastes

    NASA Technical Reports Server (NTRS)

    Priest, C. C.; Nixon, R. F.; Rice, E. E.

    1980-01-01

    The DOE has been studying several options for nuclear waste disposal, among them space disposal, which NASA has been assessing. Attention is given to space disposal destinations noting that a circular heliocentric orbit about halfway between Earth and Venus is the reference option in space disposal studies. Discussion also covers the waste form, showing that parameters to be considered include high waste loading, high thermal conductivity, thermochemical stability, resistance to leaching, fabrication, resistance to oxidation and to thermal shock. Finally, the Space Shuttle nuclear waste disposal mission profile is presented.

  14. Optimisation of the Management of Higher Activity Waste in the UK - 13537

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Walsh, Ciara; Buckley, Matthew

    2013-07-01

    The Upstream Optioneering project was created in the Nuclear Decommissioning Authority (UK) to support the development and implementation of significant opportunities to optimise activities across all the phases of the Higher Activity Waste management life cycle (i.e. retrieval, characterisation, conditioning, packaging, storage, transport and disposal). The objective of the Upstream Optioneering project is to work in conjunction with other functions within NDA and the waste producers to identify and deliver solutions to optimise the management of higher activity waste. Historically, optimisation may have occurred on aspects of the waste life cycle (considered here to include retrieval, conditioning, treatment, packaging, interimmore » storage, transport to final end state, which may be geological disposal). By considering the waste life cycle as a whole, critical analysis of assumed constraints may lead to cost savings for the UK Tax Payer. For example, it may be possible to challenge the requirements for packaging wastes for disposal to deliver an optimised waste life cycle. It is likely that the challenges faced in the UK are shared in other countries. It is therefore likely that the opportunities identified may also apply elsewhere, with the potential for sharing information to enable value to be shared. (authors)« less

  15. Investigation of package sealing using organic adhesives

    NASA Technical Reports Server (NTRS)

    Perkins, K. L.; Licari, J. J.

    1977-01-01

    A systematic study was performed to evaluate the suitability of adhesives for sealing hybrid packages. Selected adhesives were screened on the basis of their ability to seal gold-plated Kovar butterfly-type packages that retain their seal integrity after individual exposures to increasingly severe temperature-humidity environments. Tests were also run using thermal shock, temperature cycling, mechanical shock and temperature aging. The four best adhesives were determined and further tested in a 60 C/98% RH environment and continuously monitored in regard to moisture content. Results are given, however, none of the tested adhesives passed all the tests.

  16. Ohmic Heating of an Electrically Conductive Food Package.

    PubMed

    Kanogchaipramot, Kanyawee; Tongkhao, Kullanart; Sajjaanantakul, Tanaboon; Kamonpatana, Pitiya

    2016-12-01

    Ohmic heating through an electrically conductive food package is a new approach to heat the food and its package as a whole after packing to avoid post-process contamination and to serve consumer needs for convenience. This process has been successfully completed using polymer film integrated with an electrically conductive film to form a conductive package. Orange juice packed in the conductive package surrounded with a conductive medium was pasteurized in an ohmic heater. A mathematical model was developed to simulate the temperature distribution within the package and its surroundings. A 3-D thermal-electric model showed heating uniformity inside the food package while the hot zone appeared in the orange juice adjacent to the conductive film. The accuracy of the model was determined by comparing the experimental results with the simulated temperature and current drawn; the model showed good agreement between the actual and simulated results. An inoculated pack study using Escherichia coli O157:H7 indicated negative growth of viable microorganisms at the target and over target lethal process temperatures, whereas the microorganism was present in the under target temperature treatment. Consequently, our developed ohmic heating system with conductive packaging offers potential for producing safe food. © 2016 Institute of Food Technologists®.

  17. Sustainable (food) packaging--an overview.

    PubMed

    Russell, David A M

    2014-01-01

    Packaging has an increasingly essential role to play in preserving the value invested in products by ensuring that they can deliver their designed service with minimum wastage. Food contact materials that deliver more units of service with increasingly fewer inputs of energy and materials, and increasingly fewer negative social, economic and environmental impacts, e.g., from emission of wastes, will be more sustainable both in the food processing machines of the industrial system and as packaging for food. Buzz words, whether bio-, nano-, degradable, or whatever comes next, must be critically examined per unit of service delivered to determine if, over the whole life cycle of the products to which they are applied, energy and resource use are minimised, pollution is reduced (not relocated), ecological benefits are created, and social and economic well-being are increased. Only when this caution is applied can a new solution be described as more sustainable.

  18. Enhanced Shielding Performance of HLW Storage Packages via Multi- Component Coatings

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Winfrey, Leigh

    The steel coatings developed here prevent water, dirt, and chemical contaminants from the atmosphere or soil from making contact with waste packages that would damage and weaken them during long-term storage. In addition, through this project we demonstrated that a range of coatings have this capability, will survive in the environment they will be used in, and can be deposited readily on large surfaces which is critical for their use in waste storage.

  19. Reliability evaluation of hermetic dual in-line flat microcircuit packages

    NASA Technical Reports Server (NTRS)

    Johnson, G. M.; Conaway, L. K.

    1977-01-01

    The relative strengths and weaknesses of 35 commonly used hermetic flat and dual in-line packages were determined and used to rank each of the packages according to a numerical weighting scheme for package attributes. The list of attributes included desirable features in five major areas: lead and lead seal, body construction, body materials, lid and lid seal, and marking. The metal flat pack and multilayer integral ceramic flat pack and DIP received the highest rankings, and the soft glass Cerdip and Cerpak types received the lowest rankings. Loss of package hermeticity due to lead and lid seal problems was found to be the predominant failure mode from the literature/data search. However, environmental test results showed that lead and lid seal failures due to thermal stressing was only a problem with the hard glass (Ceramic) body DIP utilizing a metal lid and/or bottom. Insufficient failure data were generated for the other package types tested to correlate test results with the package ranking.

  20. Characterization of radioactive wastes with respect to harmful materials

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Kugel, Karin; Steyer, Stefan; Brennecke, Peter

    In addendum 4 to the license of the German KONRAD repository, which considers mainly radiological aspects, a water law permit was issued in order to prevent the pollution of the near-surface groundwater. The water law permit stipulates limitations for 10 radionuclides and 2 groups of radionuclides as well as mass limitations for 94 substances and materials relevant for water protection issues. Two collateral clauses, i.e. additional requirements imposed by the licensing authority, include demands on the monitoring, registering and balancing of non-radioactive harmful substances and materials /1/. In order to fulfill the requirements of the water law permit the Germanmore » Federal Office for Radiation Protection (BfS) being the operator of the KONRAD repository has developed a concept, which ensures the compliance with all requirements of the water law permit and which provides standardized easy manageable guidance for the waste producers to describe their wastes. On 15 March 2011 the competent water authority, the 'Niedersaechsischer Landesbetrieb fuer Wasserwirtschaft, Kuesten- und Naturschutz' (NLWKN) issued the approval for this concept. Being the most essential part of this concept the procedural method and the developed description of nonradioactive waste package constituents by use of standardized lists of materials and containers is addressed and presented in this paper. The waste producer has to describe his waste package in a standardized way on the base of the lists of materials and containers. For each material in the list a comprehensive description is given comprising the composition, scope of application, quality control measures, thresholds and other data. Each entry in the list has to be approved by NLWKN. The scope of the lists is defined by the waste producers' needs. Using some particular materials as examples, the approval procedure for including materials in the list is described. The procedure of describing the material composition has to

  1. Radiometric packaging of uncooled bolometric infrared focal plane arrays

    NASA Astrophysics Data System (ADS)

    García-Blanco, Sonia; Pope, Timothy; Côté, Patrice; Leclerc, Mélanie; Ngo Phong, Linh; Châteauneuf, François

    2017-11-01

    INO has a wide experience in the design and fabrication of different kinds of microbolometer focal plane arrays (FPAs). In particular, a 512x3 pixel microbolometer FPA has been selected as the sensor for the New Infrared Sensor Technology (NIRST) instrument, one of the payloads of the SACD/Aquarius mission. In order to make the absolute temperature measurements necessary for many infrared Earth observation applications, the microbolometer FPA must be integrated into a package offering a very stable thermal environment. The radiometric packaging technology developed at INO presents an innovative approach since it was conceived to be modular and adaptable for the packaging of different microbolometer FPAs and for different sets of assembly requirements without need for requalification of the assembly process. The development of the radiometric packaging technology has broadened the position of INO as a supplier of radiometric detector modules integrating FPAs of microbolometers inside a radiometric package capable of achieving the requirements of different space missions. This paper gives an overview of the design of INO's radiometric package. Key performance parameters are also discussed and the test campaign conducted with the radiometric package is presented.

  2. Development of a self-packaged 2D MEMS thermal wind sensor for low power applications

    NASA Astrophysics Data System (ADS)

    Zhu, Yan-qing; Chen, Bei; Qin, Ming; Huang, Jian-qiu; Huang, Qing-an

    2015-08-01

    This article describes the design, fabrication, and testing of a self-packaged 2D thermal wind sensor. The sensor consists of four heaters and nine thermistors. A central thermistor senses the average heater temperature, whereas the other eight, which are distributed symmetrically around the heaters, measure the temperature differences between the upstream and downstream surface of the sensor. The sensor was realized on one side of a silicon-in-glass (SIG) substrate. Vertical silicon vias in the substrate ensure good thermal contact between the sensor and the airflow and the glass effectively isolates the heaters from the thermistors. The substrate was fabricated by using a glass reflow process, after which the sensor was realized by a lift-off process. The sensor’s geometry was investigated with the help of simulations. These show that narrow heaters, moderate heater spacing, and thin substrates all improve the sensor’s sensitivity. Finally, the sensor was tested and calibrated in a wind tunnel by using a linear interpolation algorithm. At a constant heating power of 24.5 mW, measurement results show that the sensor can detect airflow speeds of up to 25 m s-1, with an accuracy of 0.1 m s-1 at low speeds and 0.5 m s-1 at high speeds. Airflow direction can be determined in a range of 360° with an accuracy of ±6°.

  3. Modified ADM1 disintegration/hydrolysis structures for modeling batch thermophilic anaerobic digestion of thermally pretreated waste activated sludge.

    PubMed

    Ramirez, Ivan; Mottet, Alexis; Carrère, Hélène; Déléris, Stéphane; Vedrenne, Fabien; Steyer, Jean-Philippe

    2009-08-01

    Anaerobic digestion disintegration and hydrolysis have been traditionally modeled according to first-order kinetics assuming that their rates do not depend on disintegration/hydrolytic biomass concentrations. However, the typical sigmoid-shape increase in time of the disintegration/hydrolysis rates cannot be described with first-order models. For complex substrates, first-order kinetics should thus be modified to account for slowly degradable material. In this study, a slightly modified IWA ADM1 model is presented to simulate thermophilic anaerobic digestion of thermally pretreated waste activated sludge. Contois model is first included for disintegration and hydrolysis steps instead of first-order kinetics and Hill function is then used to model ammonia inhibition of aceticlastic methanogens instead of a non-competitive function. One batch experimental data set of anaerobic degradation of a raw waste activated sludge is used to calibrate the proposed model and three additional data sets from similar sludge thermally pretreated at three different temperatures are used to validate the parameters values.

  4. Resources and Wastes. In-Service Package for Volunteer Workshop Leaders.

    ERIC Educational Resources Information Center

    Miiller, Marnie

    Designed to be used as a supplementary teaching aid for subjects such as science, social studies, and environmental education, this packet of modules contains materials related to waste and waste management for secondary level students. Each of the eight modules consists of a teacher's page, background information, references, questions, projects,…

  5. Industrial waste pollution

    NASA Technical Reports Server (NTRS)

    Jensen, L. D.

    1972-01-01

    The characteristics and effects of industrial waste pollution in the Chesapeake Bay are discussed. The sources of inorganic and organic pollution entering the bay are described. The four types of pollutants are defined as: (1) inorganic chemical wastes, (2) naturally occurring organic wastes, (3) synthetic organic wastes (exotics) and (4) thermal effluents. The ecological behavior of industrial wastes in the surface waters is analyzed with respect to surface film phenomena, interfacial phenomena, and benthis phenomena

  6. Novel Micro ElectroMechanical Systems (MEMS) Packaging for the Skin of the Satellite

    NASA Technical Reports Server (NTRS)

    Darrin, M. Ann; Osiander, Robert; Lehtonen, John; Farrar, Dawnielle; Douglas, Donya; Swanson, Ted

    2004-01-01

    This paper includes a discussion of the novel packaging techniques that are needed to place MEMS based thermal control devices on the skin of various satellites, eliminating the concern associated with potential particulates &om integration and test or the launch environment. Protection of this MEMS based thermal device is achieved using a novel polymer that is both IR transmissive and electrically conductive. This polymer was originally developed and qualified for space flight application by NASA at the Langley Research Center. The polymer material, commercially known as CPI, is coated with a thin layer of ITO and sandwiched between two window-like frames. The packaging of the MEMS based radiator assembly offers the benefits of micro-scale devices in a chip on board fashion, with the level of protection generally found in packaged parts.

  7. Small terminase couples viral DNA-binding to genome-packaging ATPase activity

    PubMed Central

    Roy, Ankoor; Bhardwaj, Anshul; Datta, Pinaki; Lander, Gabriel C.; Cingolani, Gino

    2012-01-01

    SUMMARY Packaging of viral genomes into empty procapsids is powered by a large DNA-packaging motor. In most viruses, this machine is composed of a large (L) and a small (S) terminase subunit complexed with a dodecamer of portal protein. Here, we describe the 1.75 Å crystal structure of the bacteriophage P22 S-terminase in a nonameric conformation. The structure presents a central channel ~23 Å in diameter, sufficiently large to accommodate hydrated B-DNA. The last 23 residues of S-terminase are essential for binding to DNA and assembly to L-terminase. Upon binding to its own DNA, S-terminase functions as a specific activator of L-terminase ATPase activity. The DNA-dependent stimulation of ATPase activity thus rationalizes the exclusive specificity of genome-packaging motors for viral DNA in the crowd of host DNA, ensuring fidelity of packaging and avoiding wasteful ATP hydrolysis. This posits a model for DNA-dependent activation of genome-packaging motors of general interest in virology. PMID:22771211

  8. The University of Georgia Chemical Waste Disposal Program.

    ERIC Educational Resources Information Center

    Dreesen, David W.; Pohlman, Thomas J.

    1980-01-01

    Describes a university-wide program directed at reducing the improper storage and disposal of toxic chemical wastes from laboratories. Specific information is included on the implementation of a waste pick-up service, safety equipment, materials and methods for packaging, and costs of the program. (CS)

  9. Fundamental understanding of the thermal degradation mechanisms of waste tires and their air pollutant generation in a N2 atmosphere.

    PubMed

    Kwon, Eilhann; Castaldi, Marco J

    2009-08-01

    The thermal decomposition of waste tires has been characterized via thermo-gravimetric analysis (TGA) tests, and significant mass loss has been observed between 300 and 500 degrees C. A series of gas chromatography-mass spectrometer (GC-MS) measurements, in which the instrument was coupled to a TGA unit, have been carried out to investigate the thermal degradation mechanisms as well as the air pollutant generation including volatile organic carbons (VOCs) and polycyclic aromatic hydrocarbons (PAHs) in a nitrogen atmosphere. In order to understand fundamental information on the thermal degradation mechanisms of waste tires, the main constituents of tires, poly-isoprene rubber (IR) and styrene butadiene rubber (SBR), have been studied under the same conditions. All of the experimental work indicated that the bond scission on each monomer of the main constituents of tires was followed by hydrogenation and gas phase reactions. This helped to clarify the independent pathways and species attributable to IR and SBR during the pyrolysis process. To extend that understanding to a more practical level, a flow-through reactor was used to test waste tire, SBR and IR samples in the temperature range of 500-800 degrees C at a heating rate of approximately 200 degrees C. Lastly, the formation of VOCs (approximately 1-50 PPMV/10 mg of sample) and PAHs (approximately 0.2-7 PPMV/10 mg of sample) was observed at relatively low temperatures compared to conventional fuels, and its quantified concentration was significantly high due to the chemical structure of SBR and IR. The measurement of chemicals released during pyrolysis suggests not only a methodology for reducing the air pollutants but also the feasibility of petrochemical recovery during thermal treatment.

  10. NEVADA TEST SITE WASTE ACCEPTANCE CRITERIA, JUNE 2006

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    U.S. DEPARTMENT OF ENERGY, NATIONAL NUCLEAR SECURITY ADMINISTRATION NEVADA SITE OFFICE

    This document establishes the U.S. Department of Energy (DOE), National Nuclear Security Administration Nevada Site Office (NNSA/NSO) waste acceptance criteria (WAC). The WAC provides the requirements, terms, and conditions under which the Nevada Test Site (NTS) will accept low-level radioactive (LLW) and mixed waste (MW) for disposal. It includes requirements for the generator waste certification program, characterization, traceability, waste form, packaging, and transfer. The criteria apply to radioactive waste received at the NTS Area 3 and Area 5 Radioactive Waste Management Complex (RWMC) for storage or disposal.

  11. METHOD FOR MANUFACTURING LAMINATED SHEETS FOR PROTECTION AGAINST RADIOACTIVE WASTES, AND PROTECTING AND PACKAGING MEANS MANUFACTURED WITH THESE SHEETS; Papierfabrik Wilhemstal Wilhelm Ernst

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    None

    1959-07-15

    A description is given of laminated sheet, consisting of a first layer of absorbing and preferably fibrous material (e.g., filter or blotting paper, or felt), a second layer of adhesive, impermeable, and hydrophobic material (e.g., wax, bitumen, a polyvinyl or polyacrylic compound, or a polyhydrocarbon), and a third (and fourth) layer of rigid material more or less impermeable to liquids (e.g., metal (aluminum), polyvinyl chloride, polyethylene, or cardboard). These sheets can be used for covering laboratory tables and walls, for radiation protection (manufacture of clothes, etc.), or for packaging radioactive waste (manufacture of boxes, bags, etc.). (NPO)

  12. Assessing the perception and reality of arguments against thermal waste treatment plants in terms of property prices

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Phillips, K.J.O.; Longhurst, P.J.; Wagland, S.T., E-mail: s.t.wagland@cranfield.ac.uk

    Highlights: • Previous research studies have shown that EfW facilities negatively impact the local house prices. • In this study property prices surrounding 3 operational EfW plants were analysed. • No significant negative effect on property prices due to an incinerator was found. - Abstract: The thermal processing of waste materials, although considered to be an essential part of waste management, is often sharply contested in the UK. Arguments such as health, depletion of resources, cost, noise, odours, traffic movement and house prices are often cited as reasons against the development of such facilities. This study aims to review themore » arguments and identify any effect on property prices due to the public perception of the plant. A selection of existing energy from waste (EfW) facilities in the UK, operational for at least 7 years, was selected and property sales data, within 5 km of the sites, was acquired and analysed in detail. The locations of the properties were calculated in relation to the plant using GIS software (ArcGIS) and the distances split into 5 zones ranging from 0 to 5 km from the site. The local property sale prices, normalised against the local house price index, were compared in two time periods, before and after the facility became operational, across each of the 5 zones. In all cases analysed no significant negative effect was observed on property prices at any distance within 5 km from a modern operational incinerator. This indicated that the perceived negative effect of the thermal processing of waste on local property values is negligible.« less

  13. Localized heating/bonding techniques in MEMS packaging

    NASA Astrophysics Data System (ADS)

    Mabesa, J. R., Jr.; Scott, A. J.; Wu, X.; Auner, G. W.

    2005-05-01

    Packaging is used to protect and enable intelligent sensor systems utilized in manned/unmanned ground vehicle systems/subsystems. Because Micro electro mechanical systems (MEMS) are used often in these sensor or actuation products, it must interact with the surrounding environment, which may be in direct conflict with the desire to isolate the electronics for improved reliability/durability performance. For some very simple devices, performance requirements may allow a high degree of isolation from the environment (e.g., stints and accelerometers). Other more complex devices (i.e. chemical and biological analysis systems, particularly in vivo systems) present extremely complex packaging requirements. Power and communications to MEMS device arrays are also extremely problematic. The following describes the research being performed at the U.S. Army Research, Development, and Engineering Command (RDECOM) Tank and Automotive Research, Development, and Engineering Center (TARDEC), in collaboration with Wayne State University, in Detroit, MI. The focus of the packaging research is limited to six main categories: a) provision for feed-through for electrical, optical, thermal, and fluidic interfaces; b) environmental management including atmosphere, hermiticity, and temperature; c) control of stress and mechanical durability; d) management of thermal properties to minimize absorption and/or emission; e) durability and structural integrity; and f) management of RF/magnetic/electrical and optical interference and/or radiation properties and exposure.

  14. Process for remediation of plastic waste

    DOEpatents

    Pol, Vilas G [Westmont, IL; Thiyagarajan, Pappannan [Germantown, MD

    2012-04-10

    A single step process for degrading plastic waste by converting the plastic waste into carbonaceous products via thermal decomposition of the plastic waste by placing the plastic waste into a reactor, heating the plastic waste under an inert or air atmosphere until the temperature of 700.degree. C. is achieved, allowing the reactor to cool down, and recovering the resulting decomposition products therefrom. The decomposition products that this process yields are carbonaceous materials, and more specifically egg-shaped and spherical-shaped solid carbons. Additionally, in the presence of a transition metal compound, this thermal decomposition process produces multi-walled carbon nanotubes.

  15. Determination of the Porosity Surfaces of the Disposal Room Containing Various Waste Inventories for WIPP PA

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Park, Byoung Yoon; Hansen, Francis D.

    2005-07-01

    This report develops a series of porosity surfaces for the Waste Isolation Pilot Plant. The concept of a porosity surface was developed for performance assessment and comprises calculation of room closure as salt creep processes are mitigated by gas generation and back stress created by the waste packages within the rooms. The physical and mechanical characteristics of the waste packaging that has already been disposed--such as the pipe overpack--and new waste packaging--such as the advanced mixed waste compaction--are appreciably different than the waste form upon which the original compliance was based and approved. This report provides structural analyses of roommore » closure with various waste inventories. All of the underlying assumptions pertaining to the original compliance certification including the same finite element code are implemented; only the material parameters describing the more robust waste packages are changed from the certified baseline. As modeled, the more rigid waste tends to hold open the rooms and create relatively more void space in the underground than identical calculations run on the standard waste packages, which underpin the compliance certification. The several porosity surfaces quantified within this report provide possible ranges of pressure and porosity for performance assessment analyses.3 Intentionally blank4 AcknowledgementsThis research is funded by WIPP programs administered by the U.S. Department of Energy. The authors would like to acknowledge the valuable contributions to this work provided by others. Dr. Joshua S. Stein helped explain the hand off between these finite element porosity surfaces and implementation in the performance calculations. Dr. Leo L. Van Sambeek of RESPEC Inc. helped us understand the concepts of room closure under the circumstances created by a rigid waste inventory. Dr. T. William Thompson and Tom W. Pfeifle provided technical review and Mario J. Chavez provided a Quality Assurance review. The

  16. Characterization of a thermal power plant air heater washing waste: a case study from Iran.

    PubMed

    Saeedi, M; Amini, H R

    2007-02-01

    In Iran most of the electricity is generated by thermal power plants. As a result of fuel oil burning in winter time, the air heaters of the boilers have to be washed and cleaned frequently. The wastewater originating from air heater washing is then treated in an effluent treatment plant by chemical precipitation followed by dewatering of the sludge produced. The resulting waste is classified as specific industrial waste that should be characterized in detail under the Waste Management Act of Iran. The quantity of this waste produced in the studied power plant is about 20 tonnes year(-1). In the present investigation, the first to be carried out in Iran, seven composite samples of dewatered sludge from air heater washing wastewater treatment were subjected to investigation of the physical properties, chemical composition and leaching properties. The most likely pollutants that were of concern in this study were heavy and other hazardous metals (Cd, Co, Cr, Mn, Ni, Pb, Zn and V). The results revealed that mean pH, wet and dry density and moisture content of the waste were 6.31, 1532 kg m(-30, 1879 kg m(-3) and 15.35%, respectively. Magnetite, SiO2, P2O5, CaO, Al2O3 and MgO were the main constituents of the waste with a weight percentage order of 68.88, 5.91, 3.39, 2.64, 2.59 and 1.76%, respectively. The toxicity characteristic leaching procedure test results for some heavy and other hazardous metals showed that mean elemental concentrations of Cd, Co, Cr, Mn, Ni, Pb, V and Zn in leachate were 0.06, 1.55, 5.49, 36.32, 209.10, 0.58, 314.06 and 24.84 mg L(-1), respectively. According to the Waste Management Act of Iran this waste should be classified as hazardous and should be disposed of in accordance with hazardous waste disposal regulations.

  17. Thermal Flow Sensors for Harsh Environments.

    PubMed

    Balakrishnan, Vivekananthan; Phan, Hoang-Phuong; Dinh, Toan; Dao, Dzung Viet; Nguyen, Nam-Trung

    2017-09-08

    Flow sensing in hostile environments is of increasing interest for applications in the automotive, aerospace, and chemical and resource industries. There are thermal and non-thermal approaches for high-temperature flow measurement. Compared to their non-thermal counterparts, thermal flow sensors have recently attracted a great deal of interest due to the ease of fabrication, lack of moving parts and higher sensitivity. In recent years, various thermal flow sensors have been developed to operate at temperatures above 500 °C. Microelectronic technologies such as silicon-on-insulator (SOI), and complementary metal-oxide semiconductor (CMOS) have been used to make thermal flow sensors. Thermal sensors with various heating and sensing materials such as metals, semiconductors, polymers and ceramics can be selected according to the targeted working temperature. The performance of these thermal flow sensors is evaluated based on parameters such as thermal response time, flow sensitivity. The data from thermal flow sensors reviewed in this paper indicate that the sensing principle is suitable for the operation under harsh environments. Finally, the paper discusses the packaging of the sensor, which is the most important aspect of any high-temperature sensing application. Other than the conventional wire-bonding, various novel packaging techniques have been developed for high-temperature application.

  18. Thermal Flow Sensors for Harsh Environments

    PubMed Central

    Dinh, Toan; Dao, Dzung Viet

    2017-01-01

    Flow sensing in hostile environments is of increasing interest for applications in the automotive, aerospace, and chemical and resource industries. There are thermal and non-thermal approaches for high-temperature flow measurement. Compared to their non-thermal counterparts, thermal flow sensors have recently attracted a great deal of interest due to the ease of fabrication, lack of moving parts and higher sensitivity. In recent years, various thermal flow sensors have been developed to operate at temperatures above 500 °C. Microelectronic technologies such as silicon-on-insulator (SOI), and complementary metal-oxide semiconductor (CMOS) have been used to make thermal flow sensors. Thermal sensors with various heating and sensing materials such as metals, semiconductors, polymers and ceramics can be selected according to the targeted working temperature. The performance of these thermal flow sensors is evaluated based on parameters such as thermal response time, flow sensitivity. The data from thermal flow sensors reviewed in this paper indicate that the sensing principle is suitable for the operation under harsh environments. Finally, the paper discusses the packaging of the sensor, which is the most important aspect of any high-temperature sensing application. Other than the conventional wire-bonding, various novel packaging techniques have been developed for high-temperature application. PMID:28885595

  19. Test report dot 7A type a liquid packaging

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Ketusky, E. T.; Brandjes, C.; Benoit, T. J.

    This test report documents the performance of Savannah River National Laboratory’s (SRNL’s) U.S. Department of Transportation (DOT) Specification 7A; General Packaging, Type A shielded liquid shipping packaging and compliance with the regulatory requirements of Title 49 of the Code of Federal Regulations (CFR). The primary use of this packaging design is for the transport of radioactive liquids of up to 1.3 liters in an unshielded configuration and up to 113 mL of radioactive liquids in a shielded configuration, with no more than an A2 quantity in either configuration, over public highways and/or commercial aircraft. The contents are liquid radioactive materialsmore » sufficiently shielded and within the activity limits specified in173.435 or 173.433 for A2 (normal form) materials, as well as within the analyzed thermal heat limits. Any contents must be compatibly packaged and must be compatible with the packaging. The basic packaging design is based on the U.S. Department of Energy’s (DOE’s) Model 9979 Type A fissile shipping packaging designed and tested by SRNL. The shielded liquid configuration consists of the outer and inner drums of the 9979 package with additional low density polyethylene (LDPE) dunnage nesting a tungsten shielded cask assembly (WSCA) within the 30-gallon inner drum. The packaging model for the DOT Specification 7A, Type A liquids packaging is HVYTAL.« less

  20. An approach for modeling thermal destruction of hazardous wastes in circulating fluidized bed incinerator.

    PubMed

    Patil, M P; Sonolikar, R L

    2008-10-01

    This paper presents a detailed computational fluid dynamics (CFD) based approach for modeling thermal destruction of hazardous wastes in a circulating fluidized bed (CFB) incinerator. The model is based on Eular - Lagrangian approach in which gas phase (continuous phase) is treated in a Eularian reference frame, whereas the waste particulate (dispersed phase) is treated in a Lagrangian reference frame. The reaction chemistry hasbeen modeled through a mixture fraction/ PDF approach. The conservation equations for mass, momentum, energy, mixture fraction and other closure equations have been solved using a general purpose CFD code FLUENT4.5. Afinite volume method on a structured grid has been used for solution of governing equations. The model provides detailed information on the hydrodynamics (gas velocity, particulate trajectories), gas composition (CO, CO2, O2) and temperature inside the riser. The model also allows different operating scenarios to be examined in an efficient manner.

  1. High temperature insulation materials for reradiative thermal protection systems

    NASA Technical Reports Server (NTRS)

    Hughes, T. A.

    1972-01-01

    Results are presented of a two year program to evaluate packaged thermal insulations for use under a metallic radiative TPS of a shuttle orbiter vehicle. Evaluations demonstrated their survival for up to 100 mission reuse cycles under shuttle acoustic and thermal loads with peak temperatures of 1000 F, 1800 F, 2000 F, 2200 F and 2500 F. The specimens were composed of low density refractory fiber felts, packaged in thin gage metal foils. In addition, studies were conducted on the venting requirements of the packages, salt spray resistance of the metal foils, and the thermal conductivity of many of the insulations as a function of temperature and ambient air pressure. Data is also presented on the radiant energy transport through insulations, and back-scattering coefficients were experimentally determined as a function of source temperature.

  2. Going green by reducing red. New alternative medical waste treatment technologies.

    PubMed

    Zanoni, P

    1998-01-01

    The field of medical waste disposal is changing rapidly. Over the past decade, there has been increasing public health concern over health care's red bag waste. The health care industry must routinely contend with a complex set of regulations covering occupational safety, transportation and packaging, medical waste disposal management, and now environmental regulations for medical waste incinerators.

  3. Thermal and chemical remediation of mixed waste

    DOEpatents

    Nelson, P.A.; Swift, W.M.

    1994-08-09

    A process and system for treating organic waste materials without venting gaseous emissions to the atmosphere. A fluidized bed including lime particles is operated at a temperature of at least 500 C by blowing gas having 20%/70% oxygen upwardly through the bed particles at a rate sufficient to fluidize same. A toxic organic waste material is fed into the fluidized bed where the organic waste material reacts with the lime forming CaCO[sub 3]. The off gases are filtered and cooled to condense water which is separated. A portion of the calcium carbonate formed during operation of the fluidized bed is replaced with lime particles. The off gases from the fluidized bed after drying are recirculated until the toxic organic waste material in the bed is destroyed. 3 figs.

  4. Thermal and chemical remediation of mixed waste

    DOEpatents

    Nelson, Paul A.; Swift, William M.

    1994-01-01

    A process and system for treating organic waste materials without venting gaseous emissions to the atmosphere. A fluidized bed including lime particles is operated at a temperature of at least 500.degree. C. by blowing gas having 20%/70% oxygen upwardly through the bed particles at a rate sufficient to fluidize same. A toxic organic waste material is fed into the fluidized bed where the organic waste material reacts with the lime forming CaCO.sub.3. The off gases are filtered and cooled to condense water which is separated. A portion of the calcium carbonate formed during operation of the fluidized bed is replaced with lime particles. The off gases from the fluidized bed after drying are recirculated until the toxic organic waste material in the bed is destroyed.

  5. Skylab S191 visible-infrared spectrometer. [in Earth Resources Experiment Package

    NASA Technical Reports Server (NTRS)

    Barnett, T. L.; Juday, R. D.

    1977-01-01

    The paper describes the S191 visible-infrared spectrometer of the Skylab Earth Resources Experiment Package - a manually pointed two-channel instrument operating in the reflective (0.4-2.5 micron) and thermal emissive (6-15 micron) regions. A sensor description is provided and attention is given to data quality in the short wavelength and thermal infrared regions.

  6. Small boiler uses waste coal

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Virr, M.J.

    Burning coal waste in small boilers at low emissions poses considerable problem. While larger boiler suppliers have successfully installed designs in the 40 to 80 MW range for some years, the author has been developing small automated fluid bed boiler plants for 25 years that can be applied in the range of 10,000 to 140,000 lbs/hr of steam. Development has centered on the use of an internally circulating fluid bed (CFB) boiler, which will burn waste fuels of most types. The boiler is based on the traditional D-shaped watertable boiler, with a new type of combustion chamber that enables amore » three-to-one turndown to be achieved. The boilers have all the advantages of low emissions of the large fluid boilers while offering a much lower height incorporated into the package boiler concept. Recent tests with a waste coal that had a high nitrogen content of 1.45% demonstrated a NOx emission below the federal limit of 0.6 lbs/mm Btu. Thus a NOx reduction on the order of 85% can be demonstrate by combustion modification alone. Further reductions can be made by using a selective non-catalytic reduction (SNCR) system and sulfur absorption of up to 90% retention is possible. The article describes the operation of a 30,000 lbs/hr boiler at the Fayette Thermal LLC plant. Spinheat has installed three ICFB boilers at a nursing home and a prison, which has been tested on poor-grade anthracite and bituminous coal. 2 figs.« less

  7. Response of CO2 laser written long period fiber gratings packaged by polymer materials

    NASA Astrophysics Data System (ADS)

    Wu, Zhaodi; Liu, Yunqi; Zou, Jian; Chen, Na; Pang, Fufei; Wang, Tingyun

    2011-12-01

    We demonstrate the packaging of CO2 laser written long-period fiber gratings (LPFGs) using different polymer materials. We use three different silicone rubber polymers to package the LPFGs by simply coating it outside the grating. After the polymer coating, the resonance wavelength of LPFG was found to shift towards shorter wavelength by about 6 nm, and the temperature sensitivity of the packaged gratings was studied experimentally. Experiments showed that the gratings packaged by different polymers have different temperature characteristics and all of them have good thermal stability.

  8. Volume reduction of hot cell plastic wastes

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Dykes, F W; Henscheid, J P; Lewis, L C

    1989-09-19

    The disposal of radioactively-contaminated solid wastes has become a national crisis. In such circumstances, it is imperative that this waste be reduced to minimum volume and be packaged to prevent pollution of the environment. The majority of the solid waste generated at the hot cell under consideration is plastic lab ware. Cutting this waste into small pieces with a hot wire technique reduced the volume 66%. Melting the waste, although more time consuming, reduced the volume 90%. The hot wire technique can also be used to cut up damaged master slave manipulator boots, greatly reducing their disposal volume.

  9. Soft plastic bread packaging: lead content and reuse by families.

    PubMed Central

    Weisel, C; Demak, M; Marcus, S; Goldstein, B D

    1991-01-01

    The presence of lead in labels painted on soft plastic bread packaging was evaluated. Lead was detected on the outside of 17 of 18 soft plastic bread bags that were analyzed, with an average of 26 +/- 6 mg per bag with lead. Of 106 families questioned, 16 percent of respondents reported turning the bags inside out before reusing for food storage, thus putting food in contact with the lead paint. We estimate that a weak acid, such as vinegar, could readily leach 100 micrograms of lead from a painted plastic bag within 10 minutes. Further, lead and other metals painted on food packaging of any type becomes part of the municipal waste stream subject to incineration and to land-filling. The use of lead in packaging presents an unnecessary risk to public health. PMID:2029047

  10. Soft plastic bread packaging: lead content and reuse by families.

    PubMed

    Weisel, C; Demak, M; Marcus, S; Goldstein, B D

    1991-06-01

    The presence of lead in labels painted on soft plastic bread packaging was evaluated. Lead was detected on the outside of 17 of 18 soft plastic bread bags that were analyzed, with an average of 26 +/- 6 mg per bag with lead. Of 106 families questioned, 16 percent of respondents reported turning the bags inside out before reusing for food storage, thus putting food in contact with the lead paint. We estimate that a weak acid, such as vinegar, could readily leach 100 micrograms of lead from a painted plastic bag within 10 minutes. Further, lead and other metals painted on food packaging of any type becomes part of the municipal waste stream subject to incineration and to land-filling. The use of lead in packaging presents an unnecessary risk to public health.

  11. Separate collection of plastic waste, better than technical sorting from municipal solid waste?

    PubMed

    Feil, Alexander; Pretz, Thomas; Jansen, Michael; Thoden van Velzen, Eggo U

    2017-02-01

    The politically preferred solution to fulfil legal recycling demands is often implementing separate collection systems. However, experience shows their limitations, particularly in urban centres with a high population density. In response to the European Union landfill directive, mechanical biological waste treatment plants have been installed all over Europe. This technology makes it possible to retrieve plastic waste from municipal solid waste. Operators of mechanical biological waste treatment plants, both in Germany and the Netherlands, have started to change their mechanical separation processes to additionally produce plastic pre-concentrates. Results from mechanical biological waste treatment and separate collection of post-consumer packaging waste will be presented and compared. They prove that both the yield and the quality of plastic waste provided as feedstock for the production of secondary plastic raw material are largely comparable. An economic assessment shows which conditions for a technical sorting plant are economically attractive in comparison to separate collection systems. It is, however, unlikely that plastic recycling will ever reach cost neutrality.

  12. Process for remediation of plastic waste

    DOEpatents

    Pol, Vilas G; Thiyagarajan, Pappannan

    2013-11-12

    A single step process for degrading plastic waste by converting the plastic waste into carbonaceous products via thermal decomposition of the plastic waste by placing the plastic waste into a reactor, heating the plastic waste under an inert or air atmosphere until the temperature of about 700.degree. C. is achieved, allowing the reactor to cool down, and recovering the resulting decomposition products therefrom. The decomposition products that this process yields are carbonaceous materials, and more specifically carbon nanotubes having a partially filled core (encapsulated) adjacent to one end of the nanotube. Additionally, in the presence of a transition metal compound, this thermal decomposition process produces multi-walled carbon nanotubes.

  13. Emerging low-cost LED thermal management materials

    NASA Astrophysics Data System (ADS)

    Zweben, Carl H.

    2004-10-01

    As chip size and power levels continue to increase, thermal management, thermal stresses and cost have become key LED packaging issues. Until recently, low-coefficient-of-thermal-expansion (CTE) materials, which are needed to minimize thermal stresses, had thermal conductivities that are no better than those of aluminum alloys, about 200 W/m-K. Copper, which has a higher thermal conductivity (400 W/m-K), also has a high CTE, which can cause severe thermal stresses. We now have over a dozen low-CTE materials with thermal conductivities ranging between 400 and 1700 W/m-K, and almost a score with thermal conductivities at least 50% greater than that of aluminum. Some of these materials are low cost. Others have the potential to be low cost in high volume production. Emphasizing low cost, this paper reviews traditional packaging materials and the six categories of advanced materials: polymer matrix-, metal matrix-, ceramic matrix-, and carbon matrix composites; monolithic carbonaceous materials; and metal-metal composites/alloys. Topics include properties, status, applications, cost and likely future directions of new advanced materials, including carbon nanotubes and inexpensive graphite nanoplatelets.

  14. Far-Field Accumulation of Fissile Material From Waste Packages Containing Plutonium Disposition Waste Form

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    J.P. Nicot

    The objective of this calculation is to estimate the quantity of fissile material that could accumulate in fractures in the rock beneath plutonium-ceramic (Pu-ceramic) and Mixed-Oxide (MOX) waste packages (WPs) as they degrade in the potential monitored geologic repository at Yucca Mountain. This calculation is to feed another calculation (Ref. 31) computing the probability of criticality in the systems described in Section 6 and then ultimately to a more general report on the impact of plutonium on the performance of the proposed repository (Ref. 32), both developed concurrently to this work. This calculation is done in accordance with the developmentmore » plan TDP-DDC-MD-000001 (Ref. 9), item 5. The original document described in item 5 has been split into two documents: this calculation and Ref. 4. The scope of the calculation is limited to only very low flow rates because they lead to the most conservative cases for Pu accumulation and more generally are consistent with the way the effluent from the WP (called source term in this calculation) was calculated (Ref. 4). Ref. 4 (''In-Drift Accumulation of Fissile Material from WPs Containing Plutonium Disposition Waste Forms'') details the evolution through time (breach time is initial time) of the chemical composition of the solution inside the WP as degradation of the fuel and other materials proceed. It is the chemical solution used as a source term in this calculation. Ref. 4 takes that same source term and reacts it with the invert; this calculation reacts it with the rock. In addition to reactions with the rock minerals (that release Si and Ca), the basic mechanisms for actinide precipitation are dilution and mixing with resident water as explained in Section 2.1.4. No other potential mechanism such as flow through a reducing zone is investigated in this calculation. No attempt was made to use the effluent water from the bottom of the invert instead of using directly the effluent water from the WP. This

  15. Design of an innovative, ecological portable waste compressor for in-house recycling of paper, plastic and metal packaging waste.

    PubMed

    Xevgenos, D; Athanasopoulos, N; Kostazos, P K; Manolakos, D E; Moustakas, K; Malamis, D; Loizidou, M

    2015-05-01

    Waste management in Greece relies heavily on unsustainable waste practices (mainly landfills and in certain cases uncontrolled dumping of untreated waste). Even though major improvements have been achieved in the recycling of municipal solid waste during recent years, there are some barriers that hinder the achievement of high recycling rates. Source separation of municipal solid waste has been recognised as a promising solution to produce high-quality recycled materials that can be easily directed to secondary materials markets. This article presents an innovative miniature waste separator/compressor that has been designed and developed for the source separation of municipal solid waste at a household level. The design of the system is in line with the Waste Framework Directive (2008/98/EC), since it allows for the separate collection (and compression) of municipal solid waste, namely: plastic (polyethylene terephthalate and high-density polyethylene), paper (cardboard and Tetrapak) and metal (aluminium and tin cans). It has been designed through the use of suitable software tools (LS-DYNA, INVENTROR and COMSOL). The results from the simulations, as well as the whole design process and philosophy, are discussed in this article. © The Author(s) 2015.

  16. Advanced Packaging Materials and Techniques for High Power TR Module: Standard Flight vs. Advanced Packaging

    NASA Technical Reports Server (NTRS)

    Hoffman, James Patrick; Del Castillo, Linda; Miller, Jennifer; Jenabi, Masud; Hunter, Donald; Birur, Gajanana

    2011-01-01

    The higher output power densities required of modern radar architectures, such as the proposed DESDynI [Deformation, Ecosystem Structure, and Dynamics of Ice] SAR [Synthetic Aperture Radar] Instrument (or DSI) require increasingly dense high power electronics. To enable these higher power densities, while maintaining or even improving hardware reliability, requires advances in integrating advanced thermal packaging technologies into radar transmit/receive (TR) modules. New materials and techniques have been studied and compared to standard technologies.

  17. Description of the three axis low-g accelerometer package

    NASA Technical Reports Server (NTRS)

    Amalavage, A. J.; Fikes, E. H.; Berry, E. H.

    1978-01-01

    The three axis low-g accelerometer package designed for use on the Space Processing Application Rocket (SPAR) Program is described. The package consists of the following major sections: (1) three Kearfott model 2412 accelerometers mounted in an orthogonal triad configuration on a temperature controlled, thermally isolated cube, (2) the accelerometer servoelectronics (printed circuit cards PC-6 through PC-12), and (3) the signal conditioner (printed circuit cards PC-15 and PC-16). The measurement range is 0 + or - 0.031 g with a quantization of 1.1 x 10 to the 7th power g. The package was flown successfully on six SPAR launches with the Black Brant booster. These flights provide approximately 300 s of free fall or zero-g environment.

  18. Towards co-packaging of photonics and microelectronics in existing manufacturing facilities

    NASA Astrophysics Data System (ADS)

    Janta-Polczynski, Alexander; Cyr, Elaine; Bougie, Jerome; Drouin, Alain; Langlois, Richard; Childers, Darrell; Takenobu, Shotaro; Taira, Yoichi; Lichoulas, Ted W.; Kamlapurkar, Swetha; Engelmann, Sebastian; Fortier, Paul; Boyer, Nicolas; Barwicz, Tymon

    2018-02-01

    The impact of integrated photonics on optical interconnects is currently muted by challenges in photonic packaging and in the dense integration of photonic modules with microelectronic components on printed circuit boards. Single mode optics requires tight alignment tolerance for optical coupling and maintaining this alignment in a cost-efficient package can be challenging during thermal excursions arising from downstream microelectronic assembly processes. In addition, the form factor of typical fiber connectors is incompatible with the dense module integration expected on printed circuit boards. We have implemented novel approaches to interfacing photonic chips to standard optical fibers. These leverage standard high throughput microelectronic assembly tooling and self-alignment techniques resulting in photonic packaging that is scalable in manufacturing volume and in the number of optical IOs per chip. In addition, using dense optical fiber connectors with space-efficient latching of fiber patch cables results in compact module size and efficient board integration, bringing the optics closer to the logic chip to alleviate bandwidth bottlenecks. This packaging direction is also well suited for embedding optics in multi-chip modules, including both photonic and microelectronic chips. We discuss the challenges and rewards in this type of configuration such as thermal management and signal integrity.

  19. Background studies in support of a feasibility assessment on the use of copper-base materials for nuclear waste packages in a repository in tuff

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Van Konynenburg, R.A.; Kundig, K.J.A.; Lyman, W.S.

    1990-06-01

    This report combines six work units performed in FY`85--86 by the Copper Development Association and the International Copper Research Association under contract with the University of California. The work includes literature surveys and state-of-the-art summaries on several considerations influencing the feasibility of the use of copper-base materials for fabricating high-level nuclear waste packages for the proposed repository in tuff rock at Yucca Mountain, Nevada. The general conclusion from this work was that copper-base materials are viable candidates for inclusion in the materials selection process for this application. 55 refs., 48 figs., 22 tabs.

  20. Hazardous Waste Cleanup: Clean Harbors BTD, LLC in Clarence, New York

    EPA Pesticide Factsheets

    The Clean Harbors BDT, LLC site was a commercial treatment, storage, and disposal facility that treated reactive hazardous wastes, pressurized waste, pharmaceutical and packaged laboratory chemicals. The facility was initially owned and operated by Wilson-

  1. Thermal destruction of organic waste hydrophobicity for agricultural soils application.

    PubMed

    Comino, Francisco; Aranda, Víctor; Domínguez-Vidal, Ana; Ayora-Cañada, María José

    2017-11-01

    Use of organic amendments is a good strategy for combating the growing problem of soil degradation due to deterioration of organic matter content, particularly severe in semi-arid European Mediterranean regions, while at the same time providing an opportunity for recycling organic wastes. Olive mill pomace (OMP), the main by-product of the olive oil industry, is being used increasingly in olive grove soils for this purpose. Although the positive effects of OMP amendments have been widely studied, they also have some negative effects on soil. One of the most critical is that they increase water repellency (WR) due to the presence of poorly evolved, strongly aliphatic compounds. This detrimental effect has received very little attention, although it may impair plant water availability and infiltration rates, increase erosion and lower long-term soil quality. This study proposed, for the first time, thermal treatment as an effective way of reducing WR in organic amendments (i.e. mixtures of OMP, olive tree pruning, chicken manure and spent coffee grounds) prior to their application to soil. Thermal treatment at 275 °C proved effective in removing WR, while lower temperatures (175 or 225 °C) can even increase it. Changes by thermal treatment in the characteristics of the organic amendments studied with FTIR and UV-Vis spectroscopy and thermogravimetric analysis showed that it strongly reduced the aliphatic compounds mainly responsible for their hydrophobicity, concentrated aromatic compounds and increased thermostability. Heating also reduced phytotoxicity, making all of the organic amendments usable in the field (germination index over 100%). Therefore, heating at 275 °C could be an acceptable option for removing WR from organic amendments, enhancing their quality with more stable evolved characteristics. Copyright © 2017 Elsevier Ltd. All rights reserved.

  2. Burner liner thermal-structural load modeling

    NASA Technical Reports Server (NTRS)

    Maffeo, R.

    1986-01-01

    The software package Transfer Analysis Code to Interface Thermal/Structural Problems (TRANCITS) was developed. The TRANCITS code is used to interface temperature data between thermal and structural analytical models. The use of this transfer module allows the heat transfer analyst to select the thermal mesh density and thermal analysis code best suited to solve the thermal problem and gives the same freedoms to the stress analyst, without the efficiency penalties associated with common meshes and the accuracy penalties associated with the manual transfer of thermal data.

  3. Wavelet analysis to decompose a vibration simulation signal to improve pre-distribution testing of packaging

    NASA Astrophysics Data System (ADS)

    Griffiths, K. R.; Hicks, B. J.; Keogh, P. S.; Shires, D.

    2016-08-01

    In general, vehicle vibration is non-stationary and has a non-Gaussian probability distribution; yet existing testing methods for packaging design employ Gaussian distributions to represent vibration induced by road profiles. This frequently results in over-testing and/or over-design of the packaging to meet a specification and correspondingly leads to wasteful packaging and product waste, which represent 15bn per year in the USA and €3bn per year in the EU. The purpose of the paper is to enable a measured non-stationary acceleration signal to be replaced by a constructed signal that includes as far as possible any non-stationary characteristics from the original signal. The constructed signal consists of a concatenation of decomposed shorter duration signals, each having its own kurtosis level. Wavelet analysis is used for the decomposition process into inner and outlier signal components. The constructed signal has a similar PSD to the original signal, without incurring excessive acceleration levels. This allows an improved and more representative simulated input signal to be generated that can be used on the current generation of shaker tables. The wavelet decomposition method is also demonstrated experimentally through two correlation studies. It is shown that significant improvements over current international standards for packaging testing are achievable; hence the potential for more efficient packaging system design is possible.

  4. Enhanced mesophilic anaerobic digestion of food waste by thermal pretreatment: Substrate versus digestate heating.

    PubMed

    Ariunbaatar, Javkhlan; Panico, Antonio; Yeh, Daniel H; Pirozzi, Francesco; Lens, Piet N L; Esposito, Giovanni

    2015-12-01

    Food waste (FW) represents a source of high potential renewable energy if properly treated with anaerobic digestion (AD). Pretreating the substrates could yield a higher biomethane production in a shorter time. In this study, the effects of thermal (heating the FW in a separate chamber) and thermophilic (heating the full reactor content containing both FW and inoculum) pretreatments at 50, 60, 70 and 80°C prior to mesophilic AD were studied through a series of batch experiments. Pretreatments at a lower temperature (50°C) and a shorter time (<12h) had a positive effect on the AD process. The highest enhancement of the biomethane production with an increase by 44-46% was achieved with a thermophilic pretreatment at 50°C for 6-12h or a thermal pretreatment at 80°C for 1.5h. Thermophilic pretreatments at higher temperatures (>55°C) and longer operating times (>12h) yielded higher soluble chemical oxygen demand (CODs), but had a negative effect on the methanogenic activity. The thermal pretreatments at the same conditions resulted in a lower solubilization of COD. Based on net energy calculations, the enhanced biomethane production is sufficient to heat up the FW for the thermal, but not for the thermophilic pretreatment. Copyright © 2015 Elsevier Ltd. All rights reserved.

  5. Phosphorus leaching from soils amended with thermally gasified piggery waste ash.

    PubMed

    Kuligowski, Ksawery; Poulsen, Tjalfe Gorm

    2009-09-01

    In regions with intensive livestock farming, thermal treatment for local energy extraction from the manure and export of the P rich ash as a fertilizer has gained interest. One of the main risks associated with P fertilizers is eutrophication of water bodies. In this study P and K mobility in ash from anaerobically digested, thermally gasified (GA) and incinerated (IA) piggery waste has been tested using water loads ranging from 0.1 to 200 ml g(-1). Leaching of P from soil columns amended with GA was investigated for one P application rate (205 kg P ha(-1) corresponding to 91 mg P kg(-1) soil dry matter) as a function of precipitation rate (9.5 and 2.5 mm h(-1)), soil type (Jyndevad agricultural soil and sand), amount of time elapsed between ash amendment and onset of precipitation (0 and 5 weeks) and compared to leaching from soils amended with a commercial fertilizer (Na(2)HPO(4)). Water soluble P in GA and IA constituted 0.04% and 0.8% of total ash P. Ash amended soil released much less P (0.35% of total P applied in sand) than Na(2)HPO(4) (97% and 12% of total P applied in Jyndevad and sand, respectively).

  6. Ceramic Borehole Seals for Nuclear Waste Disposal Applications

    NASA Astrophysics Data System (ADS)

    Lowry, B.; Coates, K.; Wohletz, K.; Dunn, S.; Patera, E.; Duguid, A.; Arnold, B.; Zyvoloski, G.; Groven, L.; Kuramyssova, K.

    2015-12-01

    Sealing plugs are critical features of the deep borehole system design. They serve as structural platforms to bear the weight of the backfill column, and as seals through their low fluid permeability and bond to the borehole or casing wall. High hydrostatic and lithostatic pressures, high mineral content water, and elevated temperature due to the waste packages and geothermal gradient challenge the long term performance of seal materials. Deep borehole nuclear waste disposal faces the added requirement of assuring performance for thousands of years in large boreholes, requiring very long term chemical and physical stability. A high performance plug system is being developed which capitalizes on the energy of solid phase reactions to form a ceramic plug in-situ. Thermites are a family of self-oxidized metal/oxide reactions with very high energy content and the ability to react under water. When combined with engineered additives the product exhibits attractive structural, sealing, and corrosion properties. In the initial phase of this research, exploratory and scaled tests demonstrated formulations that achieved controlled, fine grained, homogeneous, net shape plugs composed predominantly of ceramic material. Laboratory experiments produced plug cores with confined fluid permeability as low as 100 mDarcy, compressive strength as high as 70 MPa (three times the strength of conventional well cement), with the inherent corrosion resistance and service temperature of ceramic matrices. Numerical thermal and thermal/structural analyses predicted the in-situ thermal performance of the reacted plugs, showing that they cooled to ambient temperature (and design strength) within 24 to 48 hours. The current development effort is refining the reactant formulations to achieve desired performance characteristics, developing the system design and emplacement processes to be compatible with conventional well service practices, and understanding the thermal, fluid, and structural

  7. Thermal Cycle Reliability and Failure Mechanisms of CCGA and PBGA Assemblies with and without Corner Staking

    NASA Technical Reports Server (NTRS)

    Ghaffarian, Reza

    2008-01-01

    Area array packages (AAPs) with 1.27 mm pitch have been the packages of choice for commercial applications; they are now starting to be implemented for use in military and aerospace applications. Thermal cycling characteristics of plastic ball grid array (PBGA) and chip scale package assemblies, because of their wide usage for commercial applications, have been extensively reported on in literature. Thermal cycling represents the on-off environmental condition for most electronic products and therefore is a key factor that defines reliability.However, very limited data is available for thermal cycling behavior of ceramic packages commonly used for the aerospace applications. For high reliability applications, numerous AAPs are available with an identical design pattern both in ceramic and plastic packages. This paper compares assembly reliability of ceramic and plastic packages with the identical inputs/outputs(I/Os) and pattern. The ceramic package was in the form of ceramic column grid array (CCGA) with 560 I/Os peripheral array with the identical pad design as its plastic counterpart.

  8. Thermal Characterization for a Modular 3-D Multichip Module

    NASA Technical Reports Server (NTRS)

    Fan, Mark S.; Plante, Jeannette; Shaw, Harry

    2000-01-01

    NASA Goddard Space Flight Center has designed a high-density modular 3-D multichip module (MCM) for future spaceflight use. This MCM features a complete modular structure, i.e., each stack can be removed from the package without damaging the structure. The interconnection to the PCB is through the Column Grid Array (CGA) technology. Because of its high-density nature, large power dissipation from multiple layers of circuitry is anticipated and CVD diamond films are used in the assembly for heat conduction enhancement. Since each stacked layer dissipates certain amount of heat, designing effective heat conduction paths through each stack and balancing the heat dissipation within each stack for optimal thermal performance become a challenging task. To effectively remove the dissipated heat from the package, extensive thermal analysis has been performed with finite element methods. Through these analyses, we are able to improve the thermal design and increase the total wattage of the package for maximum electrical performance. This paper provides details on the design-oriented thermal analysis and performance enhancement. It also addresses issues relating to contact thermal resistance between the diamond film and the metallic heat conduction paths.

  9. Soft plastic bread packaging: lead content and reuse by families

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Weisel, C.; Demak, M.; Marcus, S.

    The presence of lead in labels painted on soft plastic bread packaging was evaluated. Lead was detected on the outside of 17 of 18 soft plastic bread bags that were analyzed, with an average of 26 +/- 6 mg per bag with lead. Of 106 families questioned, 16 percent of respondents reported turning the bags inside out before reusing for food storage, thus putting food in contact with the lead paint. We estimate that a weak acid, such as vinegar, could readily leach 100 micrograms of lead from a painted plastic bag within 10 minutes. Further, lead and other metalsmore » painted on food packaging of any type becomes part of the municipal waste stream subject to incineration and to land-filling. The use of lead in packaging presents an unnecessary risk to public health.« less

  10. Wafer-level vacuum/hermetic packaging technologies for MEMS

    NASA Astrophysics Data System (ADS)

    Lee, Sang-Hyun; Mitchell, Jay; Welch, Warren; Lee, Sangwoo; Najafi, Khalil

    2010-02-01

    An overview of wafer-level packaging technologies developed at the University of Michigan is presented. Two sets of packaging technologies are discussed: (i) a low temperature wafer-level packaging processes for vacuum/hermeticity sealing, and (ii) an environmentally resistant packaging (ERP) technology for thermal and mechanical control as well as vacuum packaging. The low temperature wafer-level encapsulation processes are implemented using solder bond rings which are first patterned on a cap wafer and then mated with a device wafer in order to encircle and encapsulate the device at temperatures ranging from 200 to 390 °C. Vacuum levels below 10 mTorr were achieved with yields in an optimized process of better than 90%. Pressures were monitored for more than 4 years yielding important information on reliability and process control. The ERP adopts an environment isolation platform in the packaging substrate. The isolation platform is designed to provide low power oven-control, vibration isolation and shock protection. It involves batch flip-chip assembly of a MEMS device onto the isolation platform wafer. The MEMS device and isolation structure are encapsulated at the wafer-level by another substrate with vertical feedthroughs for vacuum/hermetic sealing and electrical signal connections. This technology was developed for high performance gyroscopes, but can be applied to any type of MEMS device.

  11. Degradation Behavior and Accelerated Weathering of Composite Boards Produced from Waste Tetra Pak® Packaging Materials

    Treesearch

    Nural Yilgor; Coskun Kose; Evren Terzi; Aysel Kanturk Figen; Rebecca Ibach; S. Nami Kartal; Sabriye Piskin

    2014-01-01

    Manufacturing panels from Tetra Pak® (TP) packaging material might be an alternative to conventional wood-based panels. This study evaluated some chemical and physical properties as well as biological, weathering, and fire performance of panels with and without zinc borate (ZnB) by using shredded TP packaging cartons. Such packaging material, a worldwide well-known...

  12. Prospects for application of post-consumer used plastics in food packaging.

    PubMed

    Miltz, J; Ram, A; Nir, M M

    1997-01-01

    The two most widely used polymers in packaging in recent years are polyethylene terephthalate (PET) and polyethylene (PE). The biggest fractions of these polymers are not re-utilized, in spite of the fact that they possess excellent properties even after their first application. The ban on using recycled polymers in food packaging applications and the lack of good value outlets for these materials causes them to end up in landfills. The high cost nylon, used in packaging primarily as high gas barrier laminates with PE, also finds its way to landfills. In this case, the reason is the difficulty of recycling different polymers that are incompatible. Thus, the Municipal Solid Waste (MSW) stream transferred to landfills contains many plastic packages. These packages are being blamed as a major pollutant of the environment in spite of the fact that all plastics contribute only a small percentage to the weight of the garbage in landfills. If proper and cost effective applications for the recycled polymers could be developed, the waste related to their disposal could be limited. In addition, the contribution of plastic packages to the environmental problem could be diminished. In the present paper, the possibility of sandwiching a contaminated PET layer between two layers of the virgin material was studied. The aim of the study was to determine whether such an operation could lower the migration level of contaminants from a multilayer structure (containing a recycled layer of PET) to values below the limits required by regulatory agencies. The diffusion coefficients (required to determine migration) of four organic liquids in PET were determined. As a result of the sandwiching operation, the amount of pollutant (toluene) migrating into the food simulant was reduced by two orders of magnitude. The properties of PE/nylon blends were also studied. It was found that the high gas barrier properties of nylon are preserved in the blend when proper processing conditions are used

  13. Waste Generated from LMR-AMTEC Reactor Concept

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Hasan, Ahmed; Mohamed, Yasser, T.; Mohammaden, Tarek, F.

    2003-02-25

    The candidate Liquid Metal Reactor-Alkali Metal Thermal -to- Electric Converter (LMR-AMTEC) is considered to be the first reactor that would use pure liquid potassium as a secondary coolant, in which potassium vapor aids in the conversion of thermal energy to electric energy. As with all energy production, the thermal generation of electricity produces wastes. These wastes must be managed in ways which safeguard human health and minimize their impact on the environment. Nuclear power is the only energy industry, which takes full responsibility for all its wastes. Based on the candidate design of the LMR-AMTEC components and the coolant types,more » different wastes will be generated from LMR. These wastes must be classified and characterized according to the U.S. Code of Federal Regulation, CFR. This paper defines the waste generation and waste characterization from LMR-AMTEC and reviews the applicable U.S. regulations that govern waste transportation, treatment, storage and final disposition. The wastes generated from LMR-AMTEC are characterized as: (1) mixed waste which is generated from liquid sodium contaminated by fission products and activated corrosion products; (2) hazardous waste which is generated from liquid potassium contaminated by corrosion products; (3) spent nuclear fuel; and (4) low-level radioactive waste which is generated from the packing materials (e.g. activated carbon in cold trap and purification units). The regulations and management of these wastes are summarized in this paper.« less

  14. Non-thermal plasma destruction of allyl alcohol in waste gas: kinetics and modelling

    NASA Astrophysics Data System (ADS)

    DeVisscher, A.; Dewulf, J.; Van Durme, J.; Leys, C.; Morent, R.; Van Langenhove, H.

    2008-02-01

    Non-thermal plasma treatment is a promising technique for the destruction of volatile organic compounds in waste gas. A relatively unexplored technique is the atmospheric negative dc multi-pin-to-plate glow discharge. This paper reports experimental results of allyl alcohol degradation and ozone production in this type of plasma. A new model was developed to describe these processes quantitatively. The model contains a detailed chemical degradation scheme, and describes the physics of the plasma by assuming that the fraction of electrons that takes part in chemical reactions is an exponential function of the reduced field. The model captured the experimental kinetic data to less than 2 ppm standard deviation.

  15. Impact of Isothermal Aging on Long-Term Reliability of Fine-Pitch Ball Grid Array Packages with Sn-Ag-Cu Solder Interconnects: Surface Finish Effects

    NASA Astrophysics Data System (ADS)

    Lee, Tae-Kyu; Ma, Hongtao; Liu, Kuo-Chuan; Xue, Jie

    2010-12-01

    The interaction between isothermal aging and the long-term reliability of fine-pitch ball grid array (BGA) packages with Sn-3.0Ag-0.5Cu (wt.%) solder ball interconnects was investigated. In this study, 0.4-mm fine-pitch packages with 300- μm-diameter Sn-Ag-Cu solder balls were used. Two different package substrate surface finishes were selected to compare their effects on the final solder composition, especially the effect of Ni, during thermal cycling. To study the impact on thermal performance and long-term reliability, samples were isothermally aged and thermally cycled from 0°C to 100°C with 10 min dwell time. Based on Weibull plots for each aging condition, package lifetime was reduced by approximately 44% by aging at 150°C. Aging at 100°C showed a smaller impact but similar trend. The microstructure evolution was observed during thermal aging and thermal cycling with different phase microstructure transformations between electrolytic Ni/Au and organic solderability preservative (OSP) surface finishes, focusing on the microstructure evolution near the package-side interface. Different mechanisms after aging at various conditions were observed, and their impacts on the fatigue lifetime of solder joints are discussed.

  16. Tentative to use wastes from thermal power plants for construction building materials

    NASA Astrophysics Data System (ADS)

    Bui, Quoc-Bao; Phan, To-Anh-Vu; Tran, Minh-Tung; Le, Duc-Hien

    2018-04-01

    Thermal power plants (TPP) generates wastes (bottom and fly ashes) which become a serious environmental problem in Vietnam. Indeed, although in several countries fly ash can be used for cement industry, fly ash from actual TPP in Vietnam does not have enough good quality for cement production, because the fly ash treatment phase has not yet included in the generations of existing Vietnamese TPP. That is why bottom ash and fly ash purely become wastes and their evacuation is an urgent demand of the society. This paper presents an investigation using fly and bottom ashes in the manufacturing of construction materials. The main aims of this study is to reduce environmental impacts of fly and bottom ashes, and to test another non-conventional binder to replace cement in the manufacture of unburnt bricks. Several proportions of fly ash, bottom ash, cement, gravel, sand and water were tested to manufacture concretes. Then, geopolymer was prepared from the fly ash and an activator. Specimens were tested in uniaxial compressions. Results showed that the cement concrete tested had the compressive strengths which could be used for low rise constructions and the material using geopolymer could be used for non-load-bearing materials (unburnt bricks).

  17. CANE FIBERBOARD DEGRADATION WITHIN THE 9975 SHIPPING PACKAGE DURING LONG-TERM STORAGE APPLICATION

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Daugherty, W.; Dunn, K.; Hackney, B.

    The 9975 shipping package is used as part of the configuration for long-term storage of special nuclear materials in the K Area Complex at the Savannah River Site. The cane fiberboard overpack in the 9975 package provides thermal insulation, impact absorption and criticality control functions relevant to this application. The Savannah River National Laboratory has conducted physical, mechanical and thermal tests on aged fiberboard samples to identify degradation rates and support the development of aging models and service life predictions in a storage environment. This paper reviews the data generated to date, and preliminary models describing degradation rates of canemore » fiberboard in elevated temperature – elevated humidity environments.« less

  18. Effect of novel food processing methods on packaging: structure, composition, and migration properties.

    PubMed

    Guillard, V; Mauricio-Iglesias, M; Gontard, N

    2010-11-01

    Classical stabilization techniques (thermal treatments) usually involve food to be packed after being processed. On the contrary and increasingly, novel food processing methods, such as high pressure or microwaves, imply that both packaging and foodstuff undergo the stabilization treatment. Moreover, novel treatments (UV light, irradiation, ozone, cold plasma) are specifically used for disinfection and sterilization of the packaging material itself. Therefore, in the last several years a number of papers have focused on the effects of these new treatments on food-packaging interactions with a special emphasis on chemical migration and safety concerns. New packaging materials merged on the market with specific interest regarding the environment (i.e. bio-sourced materials) or mechanical and barrier properties (i.e. nanocomposites packaging materials). It is time to evaluate the knowledge about how these in-package food technologies affect food/packaging interactions, and especially for novel biodegradable and/or active materials. This article presents the effect of high pressure treatment, microwave heating, irradiation, UV-light, ozone and, cold plasma treatment on food/packaging interactions.

  19. Sensor Package Pan and Tilt Unit on Atlantis during STS-132

    NASA Image and Video Library

    2010-05-15

    S132-E-005110 (15 May 2010) --- While preparing for the routine inspection of Atlantis’ thermal protection system on Flight Day 2, the STS-132 crew discovered a cable was being pinched and preventing the sensor package pan and tilt unit from moving properly. There are alternate sensor packages that do not require the pan and tilt function; and personnel in the Johnson Space Center’s Mission Control Center are evaluating those procedures. Photo credit: NASA or National Aeronautics and Space Administration

  20. Response of ethylene propylene diene monomer rubber (EPDM) to simulant Hanford tank waste

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    NIGREY,PAUL J.

    2000-02-01

    This report presents the findings of the Chemical Compatibility Program developed to evaluate plastic packaging components that may be incorporated in packaging mixed-waste forms for transportation. Consistent with the methodology outlined in this report, the author performed the second phase of this experimental program to determine the effects of simulant Hanford tank mixed wastes on packaging seal materials. That effort involved the comprehensive testing of five plastic liner materials in an aqueous mixed-waste simulant. The testing protocol involved exposing the materials to {approximately}143, 286, 571, and 3,670 krad of gamma radiation and was followed by 7-, 14-, 28-, 180-day exposuresmore » to the waste simulant at 18, 50, and 60 C. Ethylene propylene diene monomer (EPDM) rubber samples subjected to the same protocol were then evaluated by measuring seven material properties: specific gravity, dimensional changes, mass changes, hardness, compression set, vapor transport rates, and tensile properties. The author has determined that EPDM rubber has excellent resistance to radiation, this simulant, and a combination of these factors. These results suggest that EPDM is an excellent seal material to withstand aqueous mixed wastes having similar composition to the one used in this study.« less

  1. 40 CFR 265.375 - Waste analysis.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... each waste analysis, or the documented information, in the operating record of the facility.] ... 40 Protection of Environment 27 2012-07-01 2012-07-01 false Waste analysis. 265.375 Section 265... FACILITIES Thermal Treatment § 265.375 Waste analysis. In addition to the waste analyses required by § 265.13...

  2. 40 CFR 265.375 - Waste analysis.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... each waste analysis, or the documented information, in the operating record of the facility.] ... 40 Protection of Environment 25 2010-07-01 2010-07-01 false Waste analysis. 265.375 Section 265... FACILITIES Thermal Treatment § 265.375 Waste analysis. In addition to the waste analyses required by § 265.13...

  3. Effects of simulant mixed waste on EPDM and butyl rubber

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Nigrey, P.J.; Dickens, T.G.

    1997-11-01

    The authors have developed a Chemical Compatibility Testing Program for the evaluation of plastic packaging components which may be used in transporting mixed waste forms. In this program, they have screened 10 plastic materials in four liquid mixed waste simulants. These plastics were butadiene-acrylonitrile copolymer (Nitrile) rubber, cross-linked polyethylene, epichlorohydrin rubber, ethylene-propylene (EPDM) rubber, fluorocarbons (Viton and Kel-F{trademark}), polytetrafluoro-ethylene (Teflon), high-density polyethylene, isobutylene-isoprene copolymer (Butyl) rubber, polypropylene, and styrene-butadiene (SBR) rubber. The selected simulant mixed wastes were (1) an aqueous alkaline mixture of sodium nitrate and sodium nitrite; (2) a chlorinated hydrocarbon mixture; (3) a simulant liquid scintillation fluid; andmore » (4) a mixture of ketones. The screening testing protocol involved exposing the respective materials to approximately 3 kGy of gamma radiation followed by 14-day exposures to the waste simulants at 60 C. The rubber materials or elastomers were tested using Vapor Transport Rate measurements while the liner materials were tested using specific gravity as a metric. The authors have developed a chemical compatibility program for the evaluation of plastic packaging components which may be incorporated in packaging for transporting mixed waste forms. From the data analyses performed to date, they have identified the thermoplastic, polychlorotrifluoroethylene, as having the greatest chemical compatibility after having been exposed to gamma radiation followed by exposure to the Hanford Tank simulant mixed waste. The most striking observation from this study was the poor performance of polytetrafluoroethylene under these conditions. In the evaluation of the two elastomeric materials they have concluded that while both materials exhibit remarkable resistance to these environmental conditions, EPDM has a greater resistance to this corrosive simulant mixed waste.« less

  4. Modular package for cooling a laser diode array

    DOEpatents

    Mundinger, David C.; Benett, William J.; Beach, Raymond J.

    1992-01-01

    A laser diode array is disclosed that includes a plurality of planar packages and active cooling. The laser diode array may be operated in a long duty cycle, or in continuous operation. A laser diode bar and a microchannel heat sink are thermally coupled in a compact, thin planar package having the laser diode bar located proximate to one edge. In an array, a number of such thin planar packages are secured together in a stacked configuration, in close proximity so that the laser diodes are spaced closely. The cooling means includes a microchannel heat sink that is attached proximate to the laser bar so that it absorbs heat generated by laser operation. To provide the coolant to the microchannels, each thin planar package comprises a thin inlet manifold and a thin outlet manifold connected to an inlet corridor and an outlet corridor. The inlet corridor comprises a hole extending through each of the packages in the array, and the outlet corridor comprises a hole extending through each of the packages in the array. The inlet and outlet corridors are connected to a conventional coolant circulation system. The laser diode array with active cooling has application as an optical pump for high power solid state lasers. Further, it can be incorporated in equipment such as communications devices and active sensors, and in military and space applications, and it can be useful in applications having space constraints and energy limitations.

  5. Nano-engineered Multiwall Carbon Nanotube-copper Composite Thermal Interface Material for Efficient Heat Conduction

    NASA Technical Reports Server (NTRS)

    Ngo, Quoc; Cruden, Brett A.; Cassell, Alan M.; Sims, Gerard; Li, Jun; Meyyappa, M.; Yang, Cary Y.

    2005-01-01

    Efforts in integrated circuit (IC) packaging technologies have recently been focused on management of increasing heat density associated with high frequency and high density circuit designs. While current flip-chip package designs can accommodate relatively high amounts of heat density, new materials need to be developed to manage thermal effects of next-generation integrated circuits. Multiwall carbon nanotubes (MWNT) have been shown to significantly enhance thermal conduction in the axial direction and thus can be considered to be a candidate for future thermal interface materials by facilitating efficient thermal transport. This work focuses on fabrication and characterization of a robust MWNT-copper composite material as an element in IC package designs. We show that using vertically aligned MWNT arrays reduces interfacial thermal resistance by increasing conduction surface area, and furthermore, the embedded copper acts as a lateral heat spreader to efficiently disperse heat, a necessary function for packaging materials. In addition, we demonstrate reusability of the material, and the absence of residue on the contacting material, both novel features of the MWNT-copper composite that are not found in most state-of-the-art thermal interface materials. Electrochemical methods such as metal deposition and etch are discussed for the creation of the MWNT-Cu composite, detailing issues and observations with using such methods. We show that precise engineering of the composite surface affects the ability of this material to act as an efficient thermal interface material. A thermal contact resistance measurement has been designed to obtain a value of thermal contact resistance for a variety of different thermal contact materials.

  6. Influence of interconnection on the long-term reliability of UV LED packages

    NASA Astrophysics Data System (ADS)

    Nieland, S.; Mitrenga, D.; Karolewski, D.; Brodersen, O.; Ortlepp, T.

    2017-02-01

    High power LEDs have conquered the mass market in recent years. Besides the main development focus to achieve higher productivity in the field of visible semiconductor LED processing, the wavelength range is further enhanced by active research and development in the direction of UVA / UVB / UVC. UVB and UVC LEDs are new and promising due to their numerous advantages. UV LEDs emit in a near range of one single emission peak with a width (FWHM) below 15 nm compared to conventional mercury discharge lamps and xenon sources, which show broad spectrums with many emission peaks over a wide range of wavelengths. Furthermore, the UV LED size is in the range of a few hundred microns and offers a high potential of significant system miniaturization. Of course, LED efficiency, lifetime and output power have to be increased [1]. Lifetime limiting issues of UVB/UVC-LED are the very high thermal stress in the chip resulting from the higher forward voltages (6-10 V @ 350 mA), the lower external quantum efficiency, below 10 % (most of the power disappears as heat), and the thermal resistance Rth of conventional LED packages being not able to dissipate these large amounts of heat for spreading. Beside the circuit boards and submounts which should have maximum thermal conductivity, the dimension of contacts as well as the interconnection of UV LED to the submount/package determinates the resolvable amount of heat [2]. In the paper different innovative interconnection techniques for UVC-LED systems will be discussed focused on the optimization of thermal conductivity in consideration of the assembly costs. Results on thermal simulation for the optimal contact dimensions and interconnections will be given. In addition, these theoretical results will be compared with results on electrical characterization as well as IR investigations on real UV LED packages in order to give recommendations for optimal UV LED assembly.

  7. Thermal and Physical Property Determinations for Ionsiv IE-911 Crystalline Silicotitanate and Savannah River Site Waste Simulant Solutions

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Bostick, D.T.; Steele, W.V.

    1999-08-01

    This document describes physical and thermophysical property determinations that were made in order to resolve questions associated with the decontamination of Savannah River Site (SRS) waste streams using ion exchange on crystalline silicotitanate (CST). The research will aid in the understanding of potential issues associated with cooling of feed streams within SRS waste treatment processes. Toward this end, the thermophysical properties of engineered CST, manufactured under the trade name, Ionsive{reg_sign} IE-911 by UOP, Mobile, AL, were determined. The heating profiles of CST samples from several manufacturers' production runs were observed using differential scanning calorimetric (DSC) measurements. DSC data were obtainedmore » over the region of 10 to 215 C to check for the possibility of a phase transition or any other enthalpic event in that temperature region. Finally, the heat capacity, thermal conductivity, density, viscosity, and salting-out point were determined for SRS waste simulants designated as Average, High NO{sub 3}{sup {minus}} and High OH{sup {minus}} simulants.« less

  8. Fabrication of spherical biochar by a two-step thermal process from waste potato peel.

    PubMed

    Yang, Xiao; Kwon, Eilhann E; Dou, Xiaomin; Zhang, Ming; Kim, Ki-Hyun; Tsang, Daniel C W; Ok, Yong Sik

    2018-06-01

    The aim of this study was to develop a new approach for the preparation of spherical biochar (SBC) by employing a two-step thermal technology to potato peel waste (PPW). Potato starch (PS), as a carbon-rich material with microscale spherical shape, was separated from PPW as a precursor to synthesizing SBC. The synthesis process comprised (1) pre-oxidization (preheating under air) of PS at 220 °C and (2) subsequent pyrolysis of the pretreated sample at 700 °C. Results showed that the produced SBC successfully retained the original PS morphology and that pre-oxidization was the key for its shape maintenance, as it reduced surface tension and enhanced structural stability. The SBC possessed excellent chemical inertness (high aromaticity) and uniform particle size (10-30 μm). Zero-cost waste material with a facile and easy-to-control process allows the method to be readily scalable for industrialization, while offering a new perspective on the full use of PPW. Copyright © 2018 Elsevier B.V. All rights reserved.

  9. Impact of iron redox chemistry on nuclear waste disposal

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Pearce, Carolyn I.; Rosso, Kevin M.; Pattrick, Richard

    For the safe disposal of nuclear waste, the ability to predict the changes in oxidation states of redox active actinide elements and fission products, such as U, Pu, Tc and Np is a key factor in determining their long term mobility. Both in the Geological Disposal Facility (GDF) near-field and in the far-field subsurface environment, the oxidation states of radionuclides are closely tied to changes in the redox condition of other elements in the subsurface such as iron. Iron pervades all aspects of the waste package environment, from the steel in the waste containers, through corrosion products, to the ironmore » minerals present in the host rock. Over the long period required for nuclear waste disposal, the chemical conditions of the subsurface waste package will vary along the entire continuum from oxidizing to reducing conditions. This variability leads to the expectation that redox-active components such as Fe oxides can undergo phase transformations or dissolution; to understand and quantify such a system with respect to potential impacts on waste package integrity and radionuclide fate is clearly a serious challenge. Traditional GDF performance assessment models currently rely upon surface adsorption or single phase solubility experiments and do not deal with the incorporation of radionuclides into specific crystallographic sites within the evolving Fe phases. In this chapter, we focus on the iron-bearing phases that are likely to be present in both the near and far-field of a GDF, examining their potential for redox activity and interaction with radionuclides. To support this, thermodynamic and molecular modelling is particularly important in predicting radionuclide behaviour in the presence of Fe-phases. Examination of radionuclide contamination of the natural environment provides further evidence of the importance of Fe-phases in far-field processes; these can be augmented by experimental and analogue studies.« less

  10. Novel Application of Glass Fibers Recovered From Waste Printed Circuit Boards as Sound and Thermal Insulation Material

    NASA Astrophysics Data System (ADS)

    Sun, Zhixing; Shen, Zhigang; Ma, Shulin; Zhang, Xiaojing

    2013-10-01

    The aim of this study is to investigate the feasibility of using glass fibers, a recycled material from waste printed circuit boards (WPCB), as sound absorption and thermal insulation material. Glass fibers were obtained through a fluidized-bed recycling process. Acoustic properties of the recovered glass fibers (RGF) were measured and compared with some commercial sound absorbing materials, such as expanded perlite (EP), expanded vermiculite (EV), and commercial glass fiber. Results show that RGF have good sound absorption ability over the whole tested frequency range (100-6400 Hz). The average sound absorption coefficient of RGF is 0.86, which is prior to those of EP (0.81) and EV (0.73). Noise reduction coefficient analysis indicates that the absorption ability of RGF can meet the requirement of II rating for sound absorbing material according to national standard. The thermal insulation results show that RGF has a fair low thermal conductivity (0.046 W/m K), which is comparable to those of some insulation materials (i.e., EV, EP, and rock wool). Besides, an empirical dependence of thermal conductivity on material temperature was determined for RGF. All the results showed that the reuse of RGF for sound and thermal insulation material provided a promising way for recycling WPCB and obtaining high beneficial products.

  11. Thermal and chemical remediation of mixed wastes

    DOEpatents

    Nelson, Paul A.; Swift, William M.

    1997-01-01

    A process for treating organic waste materials without venting gaseous emissions to the atmosphere which includes oxidizing the organic waste materials at an elevated temperature not less than about 500.degree. C. with a gas having an oxygen content in the range of from about 20% to about 70% to produce an oxidation product containing CO.sub.2 gas. The gas is then filtered to remove particulates, and then contacted with an aqueous absorbent solution of alkali metal carbonates or alkanolamines to absorb a portion of the CO.sub.2 gas from the particulate-free oxidation product. The CO.sub.2 absorbent is thereafter separated for further processing. A process and system are also disclosed in which the waste materials are contacted with a reactive medium such as lime and product treatment as described.

  12. Identification of junk buyers' contribution to recycling of household waste in Hanoi, Vietnam, through a physical composition analysis.

    PubMed

    Kawai, Kosuke; Osako, Masahiro; Matsui, Saburo; Dong, Nguyen The

    2012-07-01

    Even in developing countries, the amount of containers and packaging waste are increasing in line with population concentration and lifestyle changes in urban areas. This can cause serious problems for the disposal of municipal solid waste. Through a physical composition analysis of household waste in Hanoi, the capital of Vietnam, this study aimed to identify the contribution made by junk buyers to recycling. Interviews on the handling of recyclable waste by households were conducted. About 232 kg of recyclable waste was sampled from a total of 115 households, and about 230 kg of municipal solid waste was sampled from a total of 101 households and sorted into 69 categories for measurement by volume and weight. The interview survey revealed that a high proportion of households tended to routinely store recyclable waste for sale or donation to junk buyers. Junk buyers accounted for 8.8% of recycling by weight or 26.0% by volume according to the results of the physical composition analysis. In addition, the results suggested that containers and packaging waste accounted for the largest proportion of household waste by volume. Junk buyers recycled 25.5% by weight of containers and packaging waste. In the formulation of new plans for municipal solid waste management to improve the current situation and handle future challenges, the role of the informal sector should be monitored carefully and reliable data on recyclable waste should be collected continuously.

  13. Packaging-induced failure of semiconductor lasers and optical telecommunications components

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Sharps, J.A.

    1996-12-31

    Telecommunications equipment for field deployment generally have specified lifetimes of > 100,000 hr. To achieve this high reliability, it is common practice to package sensitive components in hermetic, inert gas environments. The intent is to protect components from particulate and organic contamination, oxidation, and moisture. However, for high power density 980 nm diode lasers used in optical amplifiers, the authors found that hermetic, inert gas packaging induced a failure mode not observed in similar, unpackaged lasers. They refer to this failure mode as packaging-induced failure, or PIF. PIF is caused by nanomole amounts of organic contamination which interact with highmore » intensity 980 nm light to form solid deposits over the emitting regions of the lasers. These deposits absorb 980 nm light, causing heating of the laser, narrowing of the band gap, and eventual thermal runaway. The authors have found PIF is averted by packaging with free O{sub 2} and/or a getter material that sequesters organics.« less

  14. Proposed Ancestors of Phage Nucleic Acid Packaging Motors (and Cells)

    PubMed Central

    Serwer, Philip

    2011-01-01

    I present a hypothesis that begins with the proposal that abiotic ancestors of phage RNA and DNA packaging systems (and cells) include mobile shells with an internal, molecule-transporting cavity. The foundations of this hypothesis include the conjecture that current nucleic acid packaging systems have imprints from abiotic ancestors. The abiotic shells (1) initially imbibe and later also bind and transport organic molecules, thereby providing a means for producing molecular interactions that are links in the chain of events that produces ancestors to the first molecules that are both information carrying and enzymatically active, and (2) are subsequently scaffolds on which proteins assemble to form ancestors common to both shells of viral capsids and cell membranes. Emergence of cells occurs via aggregation and merger of shells and internal contents. The hypothesis continues by using proposed imprints of abiotic and biotic ancestors to deduce an ancestral thermal ratchet-based DNA packaging motor that subsequently evolves to integrate a DNA packaging ATPase that provides a power stroke. PMID:21994778

  15. Uv-Light Stabilization Additive Package For Solar Cell Module And Laminated Glass Applications

    DOEpatents

    Hanoka, Jack I.; Klemchuk, Peter P.

    2002-03-05

    An ultraviolet light stabilization additive package is used in an encapsulant material that may be used in solar cell modules, laminated glass and a variety of other applications. The ultraviolet light stabilization additive package comprises a first hindered amine light stabilizer and a second hindered amine light stabilizer. The first hindered amine light stabilizer provides thermal oxidative stabilization, and the second hindered amine light stabilizer providing photo-oxidative stabilization.

  16. Reference commercial high-level waste glass and canister definition

    NASA Astrophysics Data System (ADS)

    Slate, S. C.; Ross, W. A.; Partain, W. L.

    1981-09-01

    Technical data and performance characteristics of a high level waste glass and canister intended for use in the design of a complete waste encapsulation package suitable for disposal in a geologic repository are presented. The borosilicate glass contained in the stainless steel canister represents the probable type of high level waste product that is produced in a commercial nuclear-fuel reprocessing plant. Development history is summarized for high level liquid waste compositions, waste glass composition and characteristics, and canister design. The decay histories of the fission products and actinides (plus daughters) calculated by the ORIGEN-II code are presented.

  17. Savannah River Site Eastern Transportation Hub: A Concept For a DOE Eastern Packaging, Staging and Maintenance Center - 13143

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    England, Jeffery L.; Adams, Karen; Maxted, Maxcine

    2013-07-01

    The Department of Energy (DOE) is working to de-inventory sites and consolidate hazardous materials for processing and disposal. The DOE administers a wide range of certified shipping packages for the transport of hazardous materials to include Special Nuclear Material (SNM), radioactive materials, sealed sources and radioactive wastes. A critical element to successful and safe transportation of these materials is the availability of certified shipping packages. There are over seven thousand certified packagings (i.e., Type B/Type AF) utilized within the DOE for current missions. The synergistic effects of consolidated maintenance, refurbishment, testing, certification, and costing of these services would allow formore » efficient management of the packagings inventory and to support anticipated future in-commerce shipping needs. The Savannah River Site (SRS) receives and ships radioactive materials (including SNM) and waste on a regular basis for critical missions such as consolidated storage, stabilization, purification, or disposition using H-Canyon and HB-Line. The Savannah River National Laboratory (SRNL) has the technical capability and equipment for all aspects of packaging management. SRS has the only active material processing facility in the DOE complex and is one of the sites of choice for nuclear material consolidation. SRS is a logical location to perform maintenance and periodic testing of the DOE fleet of certified packagings. This initiative envisions a DOE Eastern Packaging Staging and Maintenance Center (PSMC) at the SRS and a western hub at the Nevada National Security Site (NNSS), an active DOE Regional Disposal Site. The PSMC's would be the first place DOE would go to meet their radioactive packaging needs and the primary locations projects would go to disposition excess packaging for beneficial reuse. These two hubs would provide the centralized management of a packaging fleet rather than the current approach to design, procure, maintain and

  18. Nanotechnology for Food Packaging and Food Quality Assessment.

    PubMed

    Rossi, Marco; Passeri, Daniele; Sinibaldi, Alberto; Angjellari, Mariglen; Tamburri, Emanuela; Sorbo, Angela; Carata, Elisabetta; Dini, Luciana

    Nanotechnology has paved the way to innovative food packaging materials and analytical methods to provide the consumers with healthier food and to reduce the ecological footprint of the whole food chain. Combining antimicrobial and antifouling properties, thermal and mechanical protection, oxygen and moisture barrier, as well as to verify the actual quality of food, e.g., sensors to detect spoilage, bacterial growth, and to monitor incorrect storage conditions, or anticounterfeiting devices in food packages may extend the products shelf life and ensure higher quality of foods. Also the ecological footprint of food chain can be reduced by developing new completely recyclable and/or biodegradable packages from natural and eco-friendly resources. The contribution of nanotechnologies to these goals is reviewed in this chapter, together with a description of portable devices ("lab-on-chip," sensors, nanobalances, etc.) which can be used to assess the quality of food and an overview of regulations in force on food contact materials. © 2017 Elsevier Inc. All rights reserved.

  19. Thermal-powered reciprocating pump

    NASA Technical Reports Server (NTRS)

    Sabelman, E. E.

    1972-01-01

    Waste heat from radioisotope thermal generators in spacecraft is transported to keep instruments warm by two-cylinder reciprocating pump powered by energy from warm heat exchange fluid. Each cylinder has thermally nonconductive piston, heat exchange coil, and heat sink surface.

  20. Recovery of PET from packaging plastics mixtures by wet shaking table.

    PubMed

    Carvalho, M T; Agante, E; Durão, F

    2007-01-01

    Recycling requires the separation of materials appearing in a mass of wastes of heterogeneous composition and characteristics, into single, almost pure, component/material flows. The separation of materials (e.g., some types of plastics) with similar physical properties (e.g., specific gravity) is often accomplished by human sorting. This is the case of the separation of packaging plastics in municipal solid wastes (MSW). The low cost of virgin plastics and low value of recycled plastics necessitate the utilization of low cost techniques and processes in the recycling of packaging plastics. An experimental study was conducted to evaluate the feasibility of production of a PET product, cleaned from PVC and PS, using a wet shaking table. The wet shaking table is an environmentally friendly process, widely used to separate minerals, which has low capital and operational costs. Some operational variables of the equipment, as well as different feed characteristics, were considered. The results show that the separation of these plastics is feasible although, similarly to the mineral field, in somewhat complex flow sheets.