Recycling process for recovery of gallium from GaN an e-waste of LED industry through ball milling, annealing and leaching

DOE Office of Scientific and Technical Information (OSTI.GOV)

Swain, Basudev, E-mail: swain@iae.re.kr; Mishra, Chinmayee; Kang, Leeseung

Waste dust generated during manufacturing of LED contains significant amounts of gallium and indium, needs suitable treatment and can be an important resource for recovery. The LED industry waste dust contains primarily gallium as GaN. Leaching followed by purification technology is the green and clean technology. To develop treatment and recycling technology of these GaN bearing e-waste, leaching is the primary stage. In our current investigation possible process for treatment and quantitative leaching of gallium and indium from the GaN bearing e-waste or waste of LED industry dust has been developed. To recycle the waste and quantitative leaching of gallium,more » two different process flow sheets have been proposed. In one, process first the GaN of the waste the LED industry dust was leached at the optimum condition. Subsequently, the leach residue was mixed with Na{sub 2}CO{sub 3}, ball milled followed by annealing, again leached to recover gallium. In the second process, the waste LED industry dust was mixed with Na{sub 2}CO{sub 3}, after ball milling and annealing, followed acidic leaching. Without pretreatment, the gallium leaching was only 4.91 w/w % using 4 M HCl, 100 °C and pulp density of 20 g/L. After mechano-chemical processing, both these processes achieved 73.68 w/w % of gallium leaching at their optimum condition. The developed process can treat and recycle any e-waste containing GaN through ball milling, annealing and leaching. - Highlights: • Simplest process for treatment of GaN an LED industry waste developed. • The process developed recovers gallium from waste LED waste dust. • Thermal analysis and phase properties of GaN to Ga{sub 2}O{sub 3} and GaN to NaGaO{sub 2} revealed. • Solid-state chemistry involved in this process reported. • Quantitative leaching of the GaN was achieved.« less

TECHNOLOGY EVALUATION REPORT: CHEMFIX TECHNOLOGIES, INC. - SOLIDIFICATION/STABILIZATION PROCESS - CLACKAMAS, OREGON - VOLUME I

EPA Science Inventory

The CHEMFIX solidification/stabilization process was evaluated in the U.S. Environment Protection Agency's SITE program. Waste from an uncontrolled hazardous waste site was treated by the CHEMFIX process and subjected to a variety of physical and chemical test methods. Physical t...

TECHNOLOGY EVALUATION REPORT: CHEMFIX TECHNOLOGIES, INC. - SOLIDIFICATION/STABILIZATION PROCESS - CLACKAMAS, OREGON - VOLUME II

EPA Science Inventory

The CHEMFIX solidification/stabilization process was evaluated in the U.S. Environmental Protection Agency's SITE program. Waste from an uncontrolled hazardous waste site was treated by the CHEMFIX process and subjected to a variety of physical and chemical test methods. Physical...

An industrial ecology approach to municipal solid waste ...

EPA Pesticide Factsheets

Municipal solid waste (MSW) can be viewed as a feedstock for industrial ecology inspired conversions of wastes to valuable products and energy. The industrial ecology principle of symbiotic processes using waste streams for creating value-added products is applied to MSW, with examples suggested for various residual streams. A methodology is presented to consider individual waste-to-energy or waste-to-product system synergies, evaluating the economic and environmental issues associated with each system. Steps included in the methodology include identifying waste streams, specific waste components of interest, and conversion technologies, plus steps for determining the economic and environmental effects of using wastes and changes due to transport, administrative handling, and processing. In addition to presenting the methodology, technologies for various MSW input streams are categorized as commercialized or demonstrated to provide organizations that are considering processes for MSW with summarized information. The organization can also follow the methodology to analyze interesting processes. Presents information useful for analyzing the sustainability of alternatives for the management of municipal solid waste.

Radioactive Waste Conditioning, Immobilisation, And Encapsulation Processes And Technologies: Overview And Advances (Chapter 7)

DOE Office of Scientific and Technical Information (OSTI.GOV)

Jantzen, Carol M.; Lee, William E.; Ojovan, Michael I.

The main immobilization technologies that are available commercially and have been demonstrated to be viable are cementation, bituminization, and vitrification. Vitrification is currently the most widely used technology for the treatment of high level radioactive wastes (HLW) throughout the world. Most of the nations that have generated HLW are immobilizing in either alkali borosilicate glass or alkali aluminophosphate glass. The exact compositions of nuclear waste glasses are tailored for easy preparation and melting, avoidance of glass-in-glass phase separation, avoidance of uncontrolled crystallization, and acceptable chemical durability, e.g., leach resistance. Glass has also been used to stabilize a variety of lowmore » level wastes (LLW) and mixed (radioactive and hazardous) low level wastes (MLLW) from other sources such as fuel rod cladding/decladding processes, chemical separations, radioactive sources, radioactive mill tailings, contaminated soils, medical research applications, and other commercial processes. The sources of radioactive waste generation are captured in other chapters in this book regarding the individual practices in various countries (legacy wastes, currently generated wastes, and future waste generation). Future waste generation is primarily driven by interest in sources of clean energy and this has led to an increased interest in advanced nuclear power production. The development of advanced wasteforms is a necessary component of the new nuclear power plant (NPP) flowsheets. Therefore, advanced nuclear wasteforms are being designed for robust disposal strategies. A brief summary is given of existing and advanced wasteforms: glass, glass-ceramics, glass composite materials (GCM’s), and crystalline ceramic (mineral) wasteforms that chemically incorporate radionuclides and hazardous species atomically in their structure. Cementitious, geopolymer, bitumen, and other encapsulant wasteforms and composites that atomically bond and encapsulate wastes are also discussed. The various processing technologies are cross-referenced to the various types of wasteforms since often a particular type of wasteform can be made by a variety of different processing technologies.« less

Recycling process for recovery of gallium from GaN an e-waste of LED industry through ball milling, annealing and leaching.

PubMed

Swain, Basudev; Mishra, Chinmayee; Kang, Leeseung; Park, Kyung-Soo; Lee, Chan Gi; Hong, Hyun Seon

2015-04-01

Waste dust generated during manufacturing of LED contains significant amounts of gallium and indium, needs suitable treatment and can be an important resource for recovery. The LED industry waste dust contains primarily gallium as GaN. Leaching followed by purification technology is the green and clean technology. To develop treatment and recycling technology of these GaN bearing e-waste, leaching is the primary stage. In our current investigation possible process for treatment and quantitative leaching of gallium and indium from the GaN bearing e-waste or waste of LED industry dust has been developed. To recycle the waste and quantitative leaching of gallium, two different process flow sheets have been proposed. In one, process first the GaN of the waste the LED industry dust was leached at the optimum condition. Subsequently, the leach residue was mixed with Na2CO3, ball milled followed by annealing, again leached to recover gallium. In the second process, the waste LED industry dust was mixed with Na2CO3, after ball milling and annealing, followed acidic leaching. Without pretreatment, the gallium leaching was only 4.91 w/w % using 4M HCl, 100°C and pulp density of 20g/L. After mechano-chemical processing, both these processes achieved 73.68 w/w % of gallium leaching at their optimum condition. The developed process can treat and recycle any e-waste containing GaN through ball milling, annealing and leaching. Copyright © 2015 Elsevier Inc. All rights reserved.

1987 Oak Ridge model conference: Proceedings: Volume I, Part 3, Waste Management

DOE Office of Scientific and Technical Information (OSTI.GOV)

Not Available

1987-01-01

A conference sponsored by the United States Department of Energy (DOE), was held on waste management. Topics of discussion were transuranic waste management, chemical and physical treatment technologies, waste minimization, land disposal technology and characterization and analysis. Individual projects are processed separately for the data bases. (CBS)

OVERVIEW OF THE HISTORY, PRESENT STATUS, AND FUTURE DIRECTION OF SOLIDIFICATION/STABILIZATION TECHNOLOGIES FOR HAZARDOUS WASTE TREATMENT

EPA Science Inventory

Solidification/stabilization (S/S) technology processes are currently being utilized in the United States to treat inorganic and organic hazardous waste and radioactive waste. These wastes are generated from operating industry or have resulted from the uncontrolled management of ...

RFID technology for hazardous waste management and tracking.

PubMed

Namen, Anderson Amendoeira; Brasil, Felipe da Costa; Abrunhosa, Jorge José Gouveia; Abrunhosa, Glaucia Gomes Silva; Tarré, Ricardo Martinez; Marques, Flávio José Garcia

2014-09-01

The illegal dumping of hazardous waste is one of the most concerning occurrences related to illegal waste activities. The waste management process is quite vulnerable, especially when it comes to assuring the right destination for the delivery of the hazardous waste. The purpose of this paper is to present a new system design and prototype for applying the RFID technology so as to guarantee the correct destination for the hazardous waste delivery. The aim of this innovative approach, compared with other studies that employ the same technology to the waste disposal process, is to focus on the certification that the hazardous waste will be delivered to the right destination site and that no inappropriate disposal will occur in the transportation stage. These studies were carried out based on data collected during visits to two hazardous waste producer companies in Brazil, where the material transportation and delivery to a company in charge of the waste disposal were closely monitored. © The Author(s) 2014.

Application of analytic hierarchy process in a waste treatment technology assessment in Mexico.

PubMed

Taboada-González, Paul; Aguilar-Virgen, Quetzalli; Ojeda-Benítez, Sara; Cruz-Sotelo, Samantha

2014-09-01

The high per capita generation of solid waste and the environmental problems in major rural communities of Ensenada, Baja California, have prompted authorities to seek alternatives for waste treatment. In the absence of a selection methodology, three technologies of waste treatment with energy recovery (an anaerobic digester, a downdraft gasifier, and a plasma gasifier) were evaluated, taking the broader social, political, economic, and environmental issues into considerations. Using the scientific literature as a baseline, interviews with experts, decision makers and the community, and waste stream studies were used to construct a hierarchy that was evaluated by the analytic hierarchy process. In terms of the criteria, judgments, and assumptions made in the model, the anaerobic digester was found to have the highest rating and should consequently be selected as the waste treatment technology for this area. The study results showed low sensitivity, so alternative scenarios were not considered. The methodology developed in this study may be useful for other governments who wish to assess technologies to select waste treatment.

Bubblers Speed Nuclear Waste Processing at SRS

ScienceCinema

None

2018-05-23

At the Department of Energy's Savannah River Site, American Recovery and Reinvestment Act funding has supported installation of bubbler technology and related enhancements in the Defense Waste Processing Facility (DWPF). The improvements will accelerate the processing of radioactive waste into a safe, stable form for storage and permit expedited closure of underground waste tanks holding 37 million gallons of liquid nuclear waste.

Leather waste--potential threat to human health, and a new technology of its treatment.

PubMed

Kolomaznik, K; Adamek, M; Andel, I; Uhlirova, M

2008-12-30

In this paper, the authors deal with the problem of processing various types of waste generated by leather industry, with special emphasis to chrome-tanned waste. The agent that makes this waste potentially hazardous is hexavalent chromium. Its compounds can have negative effects on human health and some CrVI salts are considered carcinogens. The authors present the risks of spontaneous oxidization of CrIII to CrVI in the open-air dumps as well as the possible risks of wearing bad quality shoes, in which the chromium content is not controlled. There are several ways of handling primary leather waste, but no satisfactory technology has been developed for the secondary waste (manipulation waste, e.g. leather scraps and used leather products). In this contribution, a new three-step hybrid technology of processing manipulation waste is presented and tested under laboratory, pilot-scale and industrial conditions. The filtrate can be used as a good quality NPK fertilizer. The solid product, titanium-chromium sludge, can serve as an inorganic pigment in glass and ceramic industry. Further, the authors propose selective collection of used leather products (e.g. old shoes), the hydrolysable parts of which can be also processed by the new hybrid technology.

40 CFR 412.12 - Effluent limitations attainable by the application of the best practicable control technology...

Code of Federal Regulations, 2010 CFR

2010-07-01

... effluent limitations representing the application of BPT: There shall be no discharge of process waste water pollutants to navigable waters. (b) Process waste pollutants in the overflow may be discharged to... waste water from a facility designed, constructed and operated to contain all process generated waste...

[PRIORITY TECHNOLOGIES OF THE MEDICAL WASTE DISPOSAL SYSTEM].

PubMed

Samutin, N M; Butorina, N N; Starodubova, N Yu; Korneychuk, S S; Ustinov, A K

2015-01-01

The annual production of waste in health care institutions (HCI) tends to increase because of the growth of health care provision for population. Among the many criteria for selecting the optimal treatment technologies HCI is important to provide epidemiological and chemical safety of the final products. Environmentally friendly method of thermal disinfection of medical waste may be sterilizators of medical wastes intended for hospitals, medical centers, laboratories and other health care facilities that have small and medium volume of processing of all types of waste Class B and C. The most optimal method of centralized disposal of medical waste is a thermal processing method of the collected material.

Albuquerque Operations Office, Albuquerque, New Mexico: Technology summary

DOE Office of Scientific and Technical Information (OSTI.GOV)

Not Available

1994-08-01

This document has been prepared by the Department of Energy`s (DOE) Environmental Management (EM) Office of Technology Development (OTD) in order to highlight research, development, demonstration, testing, and evaluation (RDDT&E) activities funded through the Albuquerque Operations Office. Technologies and processes described have the potential to enhance DOE`s cleanup and waste management efforts, as well as improve US industry`s competitiveness in global environmental markets. The information has been assembled from recently produced OTD documents that highlight technology development activities within each of the OTD program elements. These integrated program summaries include: Volatile Organic Compounds in Non-Arid Soils, Volatile Organic Compounds inmore » Arid Soils, Mixed Waste Landfill Integrated Demonstration, Uranium in Soils Integrated Demonstration, Characterization, Monitoring, and Sensor Technology, In Situ Remediation, Buried Waste Integrated Demonstration, Underground Storage Tank, Efficient Separations and Processing, Mixed Waste Integrated Program, Rocky Flats Compliance Program, Pollution Prevention Program, Innovation Investment Area, and Robotics Technology.« less

Radioactive Demonstration Of Mineralized Waste Forms Made From Hanford Low Activity Waste (Tank SX-105 And AN-103) By Fluidized Bed Steam Reformation

DOE Office of Scientific and Technical Information (OSTI.GOV)

Jantzen, Carol; Herman, Connie; Crawford, Charles

One of the immobilization technologies under consideration as a Supplemental Treatment for Hanford’s Low Activity Waste (LAW) is Fluidized Bed Steam Reforming (FBSR). The FBSR technology forms a mineral waste form at moderate processing temperatures thus retaining and atomically bonding the halides, sulfates, and technetium in the mineral phases (nepheline, sodalite, nosean, carnegieite). Additions of kaolin clay are used instead of glass formers and the minerals formed by the FBSR technology offers (1) atomic bonding of the radionuclides and constituents of concern (COC) comparable to glass, (2) short and long term durability comparable to glass, (3) disposal volumes comparable tomore » glass, and (4) higher Na2O and SO{sub 4} waste loadings than glass. The higher FBSR Na{sub 2}O and SO{sub 4} waste loadings contribute to the low disposal volumes but also provide for more rapid processing of the LAW. Recent FBSR processing and testing of Hanford radioactive LAW (Tank SX-105 and AN-103) waste is reported and compared to previous radioactive and non-radioactive LAW processing and testing.« less

Technology Readiness Assessment of a Large DOE Waste Processing Facility

DTIC Science & Technology

2007-09-12

Waste Generation at Hanford – Waste Treatment and Immobilization Plant ( WTP ) Project • Motivation to Conduct TRA • TRA Approach • Actions to ensure...Hanford’s WTP will be the world’s largest radioactive waste treatment plant to treat Hanford’s underground tank waste Waste Treatment Plant ( WTP ) Major...Mass Maximize Activity WTP Flow Sheet – Key Process Flows Hanford Tank Waste 10 How is the Vitrified Waste Dispositioned? High Level Waste Canisters

Selection of human consumables for future space missions

NASA Technical Reports Server (NTRS)

Bourland, C. T.; Smith, M. C.

1991-01-01

Consumables for human spaceflight include oxygen, water, food and food packaging, personal hygiene items, and clothing. This paper deals with the requirements for food and water, and their impact on waste product generation. Just as urbanization of society has been made possible by improved food processing and packaging, manned spaceflight has benefitted from this technology. The downside of this technology is increased food package waste product. Since consumables make up a major portion of the vehicle onboard stowage and generate most of the waste products, selection of consumables is a very critical process. Food and package waste comprise the majority of the trash generated on the current shuttle orbiter missions. Plans for future missions must include accurate assessment of the waste products to be generated, and the methods for processing and disposing of these wastes.

Industrial Waste Heat Recovery - Potential Applications, Available Technologies and Crosscutting R&D Opportunities

DOE Office of Scientific and Technical Information (OSTI.GOV)

Thekdi, Arvind; Nimbalkar, Sachin U.

2015-01-01

The purpose of this report was to explore key areas and characteristics of industrial waste heat and its generation, barriers to waste heat recovery and use, and potential research and development (R&D) opportunities. The report also provides an overview of technologies and systems currently available for waste heat recovery and discusses the issues or barriers for each. Also included is information on emerging technologies under development or at various stages of demonstrations, and R&D opportunities cross-walked by various temperature ranges, technology areas, and energy-intensive process industries.

Application of mixed based membrane technology from component materials bintaro, zeolite and bentonite to reduction of songket waste liquid cloth

NASA Astrophysics Data System (ADS)

Dahlan, Muhammad Hatta; Saleh, Abdullah; Asip, Faisol; Makmun, Akbar; Defi

2017-11-01

Application of membrane technology based on clay mixture, Activated Carbon from Bintaro, Zeolite and Bentonit to process the waste water of Songket cloth is Palembang traditionally cloth. The applied research is into the superior field of industrial and household waste processing with membrane ceramic technology. The objective of this research is to design the liquid waste separation tool of jumputan cloth using better and simpler ceramic membrane so that it can help the artisans of Palembang songket or songket in processing the waste in accordance with the standard of environmental quality standard (BML) and Pergub Sumsel no. 16 in 2005. The specific target to be achieved can decrease the waste of cloth jumputan in accordance with applicable environmental quality standards the method used in achieving the objectives of this study using 2 processes namely the adsorption process using activated carbon and the separation process using a ceramic membrane based on the composition of the mixture. The activated carbon from bintaro seeds is expected to decrease the concentration of liquid waste of Songket cloth. Bintaro seeds are non-edible fruits where the composition contains organic ingredients that can absorb because contains dyes and filler metals. The process of membranization in the processing is expected to decrease the concentration of waste better and clear water that can be used as recycled water for household use. With the composition of a mixture of clay-based materials: zeolite, bentonit, activated carbon from bintaro seeds are expected Find the solution and get the novelty value in the form of patent in this research

EMERGING TECHNOLOGY BULLETIN: RECLAMATION OF LEAD FROM SUPERFUND WASTE MATERIAL USING SECONDARY LEAD SMELTERS

EPA Science Inventory

This process involves incorporating lead-contaminated Superfund waste with the regular feed to a secondary lead smelter. Since secondary lead smelters already recover lead from recycled automobile batteries, it seems likely that this technology could be used to treat waste from ...

Hydrothermal Processing of Base Camp Solid Wastes To Allow Onsite Recycling

DTIC Science & Technology

2008-09-01

ER D C/ CE R L TR -0 8 -1 3 Hydrothermal Processing of Base Camp Solid Wastes To Allow Onsite Recycling Gary L. Gerdes, Deborah...release; distribution is unlimited. ERDC/CERL TR-08-13 September 2008 Hydrothermal Processing of Base Camp Solid Wastes To Allow Onsite Recycling...a technology to process domestic solid waste using a unique hydrothermal system. The process was successfully demonstrated at Forts Benning and

Delphi`s DETOXSM process: Preparing to treat high organic content hazardous and mixed wastes

DOE Office of Scientific and Technical Information (OSTI.GOV)

Robertson, D.T.; Rogers, T.W.; Goldblatt, S.D.

1998-12-31

The US Department of Energy (DOE) Federal Energy Technology Center is sponsoring a full-scale technology demonstration of Delphi Research, Inc.`s patented DETOX{sup SM} catalytic wet chemical oxidation waste treatment process at the Savannah River Site (SRS) in South Carolina. The process is being developed primarily to treat hazardous and mixed wastes within the DOE complex as an alternative to incineration, but it has significant potential to treat wastes in the commercial sector. The results of the demonstration will be intensively studied and used to validate the technology. A critical objective in preparing for the demonstration was the successful completion ofmore » a programmatic Operational Readiness Review. Readiness Reviews are required by DOE for all new process startups. The Readiness Review provided the vehicle to ensure that Delphi was ready to start up and operate the DETOX{sup SM} process in the safest manner possible by implementing industry accepted management practices for safe operation. This paper provides an overview of the DETOX{sup SM} demonstration at SRS, and describes the crucial areas of the Readiness Review that marked the first steps in Delphi`s transition from a technology developer to an operating waste treatment services provider.« less

Potential application of biodrying to treat solid waste

NASA Astrophysics Data System (ADS)

Zaman, Badrus; Oktiawan, Wiharyanto; Hadiwidodo, Mochtar; Sutrisno, Endro; Purwono; Wardana, Irawan Wisnu

2018-02-01

The generation of solid waste around the world creates problems if not properly managed. The method of processing solid waste by burning or landfill is currently not optimal. The availability of land where the final processing (TPA) is critical, looking for a new TPA alternative will be difficult and expensive, especially in big cities. The processing of solid waste using bio drying technology has the potential to produce renewable energy and prevention of climate change. Solid waste processing products can serve as Refuse Derived Fuel (RDF), reduce water content of solid waste, meningkatkan kualitas lindi and increase the amount of recycled solid waste that is not completely separated from home. Biodrying technology is capable of enhancing the partial disintegration and hydrolysis of macromolecule organic compounds (such as C-Organic, cellulose, hemicellulose, lignin, total nitrogen). The application of biodrying has the potential to reduce greenhouse gas emissions such as carbon dioxide (CO2), methane (CH4), and dinitrooksida (N2O). These gases cause global warming.

Recycling of the Electronic Waste Applying the Plasma Reactor Technology

NASA Astrophysics Data System (ADS)

Lázár, Marián; Jasminská, Natália; Čarnogurská, Mária; Dobáková, Romana

2016-12-01

The following paper discusses a high-temperature gasification process and melting of electronic components and computer equipment using plasma reactor technology. It analyses the marginal conditions of batch processing, as well as the formation of solid products which result from the procedure of waste processing. Attention is also paid to the impact of the emerging products on the environment.

Waste Processing Research and Technology Development at NASA Ames Research Center

NASA Technical Reports Server (NTRS)

Fisher, John; Kliss, Mark

2004-01-01

The current "store and return" approach for handling waste products generated during low Earth orbit missions will not meet the requirements for future human missions identified in NASA s new Exploration vision. The objective is to develop appropriate reliable waste management systems that minimize maintenance and crew time, while maintaining crew health and safety, as well as providing protection of planetary surfaces. Solid waste management requirements for these missions include waste volume reduction, stabilization and storage, water recovery, and ultimately recovery of carbon dioxide, nutrients and other resources from a fully regenerative food production life support system. This paper identifies the key drivers for waste management technology development within NASA, and provides a roadmap for the developmental sequence and progression of technologies. Recent results of research and technology development activities at NASA Ames Research Center on candidate waste management technologies with emphasis on compaction, lyophilization, and incineration are discussed.

Mixed-waste treatment -- What about the residuals?. A compartive analysis of MSO and incineration

DOE Office of Scientific and Technical Information (OSTI.GOV)

Carlson, T.; Carpenter, C.; Cummins, L.

1993-11-01

Incineration currently is the best demonstrated available technology for the large inventory of U.S. Department of Energy (DOE) mixed waste. However, molten salt oxidation (MSO) is an alternative thermal treatment technology with the potential to treat a number of these wastes. Of concern for both technologies is the final waste forms, or residuals, that are generated by the treatment process. An evaluation of the two technologies focuses on 10 existing DOE waste streams and current hazardous-waste regulations, specifically for the delisting of ``derived-from`` residuals. Major findings include that final disposal options are more significantly impacted by the type of wastemore » treated and existing regulations than by the type of treatment technology; typical DOE waste streams are not good candidates for delisting; and mass balance calculations indicate that MSO and incineration generate similar quantities (dry) and types of residuals.« less

Economic evaluation of an electrochemical process for the recovery of metals from electronic waste.

PubMed

Diaz, Luis A; Lister, Tedd E

2018-04-01

As the market of electronic devices continues to evolve, the waste stream generated from antiquated technology is increasingly view as an alternative to substitute primary sources of critical a value metals. Nevertheless, the sustainable recovery of materials can only be achieved by environmentally friendly processes that are economically competitive with the extraction from mineral ores. Hence, This paper presents the techno-economic assessment for a comprehensive process for the recovery of metals and critical materials from e-waste, which is based in an electrochemical recovery (ER) technology. Economic comparison is performed with the treatment of e-waste via smelting, which is currently the primary route for recycling metals from electronics. Results indicate that the electrochemical recovery process is a competitive alternative for the recovery of value from electronic waste when compared with the traditional black Cu smelting process. A significantly lower capital investment, 2.9 kg e-waste per dollar of capital investment, can be achieved with the ER process vs. 1.3 kg per dollar in the black Cu smelting process. Copyright © 2017 Elsevier Ltd. All rights reserved.

Radioactive Demonstrations Of Fluidized Bed Steam Reforming (FBSR) With Hanford Low Activity Wastes

DOE Office of Scientific and Technical Information (OSTI.GOV)

Jantzen, C. M.; Crawford, C. L.; Burket, P. R.

Several supplemental technologies for treating and immobilizing Hanford low activity waste (LAW) are being evaluated. One immobilization technology being considered is Fluidized Bed Steam Reforming (FBSR) which offers a low temperature (700-750?C) continuous method by which wastes high in organics, nitrates, sulfates/sulfides, or other aqueous components may be processed into a crystalline ceramic (mineral) waste form. The granular waste form produced by co-processing the waste with kaolin clay has been shown to be as durable as LAW glass. The FBSR granular product will be monolithed into a final waste form. The granular component is composed of insoluble sodium aluminosilicate (NAS)more » feldspathoid minerals such as sodalite. Production of the FBSR mineral product has been demonstrated both at the industrial, engineering, pilot, and laboratory scales on simulants. Radioactive testing at SRNL commenced in late 2010 to demonstrate the technology on radioactive LAW streams which is the focus of this study.« less

Activities of the Institute of Chemical Processing of Coal at Zabrze

DOE Office of Scientific and Technical Information (OSTI.GOV)

Dreszer, K.

1995-12-31

The Institute of Chemical Processing of Coal at Zabrze was established in 1955. The works on carbochemical technologies have been, therefore, carried out at the Institute for 40 years. The targets of the Institute`s activities are research, scientific and developing works regarding a sensible utilization of fuels via their processing into more refined forms, safe environment, highly efficient use of energy carriers and technological products of special quality. The Institute of Chemical Processing of Coal has been dealing with the following: optimized use of home hard coals; improvement of classic coal coking technologies, processing and utilization of volatile coking products;more » production technologies of low emission rate fuels for communal management; analyses of coal processing technologies; new technologies aimed at increasing the efficiency of coal utilization for energy-generating purposes, especially in industry and studies on the ecological aspects of these processes; production technologies of sorbents and carbon activating agents and technologies of the utilization; rationalization of water and wastes management in the metallurgical and chemical industries in connection with removal of pollution especially dangerous to the environment from wastes; utilization technologies of refined materials (electrode cokes, binders, impregnating agents) for making electrodes, refractories and new generation construction carbon materials; production technologies of high quality bituminous and bituminous and resin coating, anti-corrosive and insulation materials; environmentally friendly utilization technologies for power station, mine and other wastes, and dedusting processes in industrial gas streams.« less

Identification and assessment of site treatment plan implementation opportunities for emerging technologies

DOE Office of Scientific and Technical Information (OSTI.GOV)

Bernard, E.A.

1995-12-31

The Department of Energy (DOE), in response to the 1992 Federal Facility Compliance Act, has prepared Site Treatment Plans (STP) for the approximately 2,000 waste streams identified within its mixed waste inventory Concurrently, emerging mixed waste treatment technologies are in final development. This paper defines a three-phase process to identify and assess implementation opportunities for these emerging technologies within the STP. It highlights the first phase, functional matching of expected treatment capabilities with proposed treatment requirements. Matches are based on treatment type, regulated contaminant and waste matrix type, for both capabilities and requirements. Results identify specific waste streams and volumesmore » that could be treated by each emerging technology. A study for Plasma Hearth Process, Delphi DETOX{sup sm}, Supercritical Water Oxidation and Vitrification shows that about 200,000 ml of DOE`s mixed waste inventory can potentially be treated by one or more of these emerging technologies. Actual implementations are small fractions of the treatable inventory. Differences between potential and actual implementations must be minimized to accrue optimum benefit from implementation of emerging or alternative treatment technologies. Functional matching is the first phase in identifying and quantifying benefits, addressing technology system and treatment issues, and providing, in part, the basis for STP implementation decisions. DOE, through EM`s Office of Technology Development, has funded this work.« less

Recycle technology for recovering resources and products from waste printed circuit boards.

PubMed

Li, Jia; Lu, Hongzhou; Guo, Jie; Xu, Zhenming; Zhou, Yaohe

2007-03-15

The printed circuit board (PCB) contains nearly 28% metals that are abundant non-ferrous metals such as Cu, Al, Sn, etc. The purity of precious metals in PCBs is more than 10 times higher than that of rich-content minerals. Therefore, recycling of PCBs is an important subject not only from the treatment of waste but also from the recovery of valuable materials. Chemical and mechanical methods are two traditional recycling processes for waste PCBs. However, the prospect of chemical methods will be limited since the emission of toxic liquid or gas brings secondary pollution to the environment during the process. Mechanical processes, such as shape separation, jigging, density-based separation, and electrostatic separation have been widely utilized in the recycling industry. But, recycling of waste PCBs is only beginning. In this study, a total of 400 kg of waste PCBs was processed by a recycle technology without negative impact to the environment. The technology contained mechanical two-step crushing, corona electrostatic separating, and recovery. The results indicated that (i) two-step crushing was an effect process to strip metals from base plates completely; (ii) the size of particles between 0.6 and 1.2 mm was suitable for corona electrostatic separating during industrial application; and (iii) the nonmetal of waste PCBs attained 80% weight of a kind of nonmetallic plate that expanded the applying prospect of waste nonmetallic materials.

Melt processed crystalline ceramic waste forms for advanced nuclear fuel cycles: CRP T21027 1813: Processing technologies for high level waste, formulation of matrices and characterization of waste forms, task 17208: Final report

DOE Office of Scientific and Technical Information (OSTI.GOV)

Amoroso, J. W.; Marra, J. C.

2015-08-26

A multi-phase ceramic waste form is being developed at the Savannah River National Laboratory (SRNL) for treatment of secondary waste streams generated by reprocessing commercial spent nuclear. The envisioned waste stream contains a mixture of transition, alkali, alkaline earth, and lanthanide metals. Ceramic waste forms are tailored (engineered) to incorporate waste components as part of their crystal structure based on knowledge from naturally found minerals containing radioactive and non-radioactive species similar to the radionuclides of concern in wastes from fuel reprocessing. The ability to tailor ceramics to mimic naturally occurring crystals substantiates the long term stability of such crystals (ceramics)more » over geologic timescales of interest for nuclear waste immobilization [1]. A durable multi-phase ceramic waste form tailored to incorporate all the waste components has the potential to broaden the available disposal options and thus minimize the storage and disposal costs associated with aqueous reprocessing. This report summarizes results from three years of work on the IAEA Coordinated Research Project on “Processing technologies for high level waste, formulation of matrices and characterization of waste forms” (T21027), and specific task “Melt Processed Crystalline Ceramic Waste Forms for Advanced Nuclear Fuel Cycles” (17208).« less

Melt processed crystalline ceramic waste forms for advanced nuclear fuel cycles: CRP T21027 1813: Processing technologies for high level waste, formulation of matrices and characterization of waste forms, Task 17208: Final report

DOE Office of Scientific and Technical Information (OSTI.GOV)

Amoroso, J. W.; Marra, J. C.

2015-08-26

A multi-phase ceramic waste form is being developed at the Savannah River National Laboratory (SRNL) for treatment of secondary waste streams generated by reprocessing commercial spent nuclear. The envisioned waste stream contains a mixture of transition, alkali, alkaline earth, and lanthanide metals. Ceramic waste forms are tailored (engineered) to incorporate waste components as part of their crystal structure based on knowledge from naturally found minerals containing radioactive and non-radioactive species similar to the radionuclides of concern in wastes from fuel reprocessing. The ability to tailor ceramics to mimic naturally occurring crystals substantiates the long term stability of such crystals (ceramics)more » over geologic timescales of interest for nuclear waste immobilization [1]. A durable multi-phase ceramic waste form tailored to incorporate all the waste components has the potential to broaden the available disposal options and thus minimize the storage and disposal costs associated with aqueous reprocessing. This report summarizes results from three years of work on the IAEA Coordinated Research Project on “Processing technologies for high level waste, formulation of matrices and characterization of waste forms” (T21027), and specific task “Melt Processed Crystalline Ceramic Waste Forms for Advanced Nuclear Fuel Cycles” (17208).« less

Electrochemical/Pyrometallurgical Waste Stream Processing and Waste Form Fabrication

DOE Office of Scientific and Technical Information (OSTI.GOV)

Steven Frank; Hwan Seo Park; Yung Zun Cho

This report summarizes treatment and waste form options being evaluated for waste streams resulting from the electrochemical/pyrometallurgical (pyro ) processing of used oxide nuclear fuel. The technologies that are described are South Korean (Republic of Korea – ROK) and United States of America (US) ‘centric’ in the approach to treating pyroprocessing wastes and are based on the decade long collaborations between US and ROK researchers. Some of the general and advanced technologies described in this report will be demonstrated during the Integrated Recycle Test (IRT) to be conducted as a part of the Joint Fuel Cycle Study (JFCS) collaboration betweenmore » US Department of Energy (DOE) and ROK national laboratories. The JFCS means to specifically address and evaluated the technological, economic, and safe guard issues associated with the treatment of used nuclear fuel by pyroprocessing. The IRT will involve the processing of commercial, used oxide fuel to recover uranium and transuranics. The recovered transuranics will then be fabricated into metallic fuel and irradiated to transmutate, or burn the transuranic elements to shorter lived radionuclides. In addition, the various process streams will be evaluated and tested for fission product removal, electrolytic salt recycle, minimization of actinide loss to waste streams and waste form fabrication and characterization. This report specifically addresses the production and testing of those waste forms to demonstrate their compatibility with treatment options and suitability for disposal.« less

Waste management technology development and demonstration programs at Brookhaven National Laboratory

NASA Technical Reports Server (NTRS)

Kalb, Paul D.; Colombo, Peter

1991-01-01

Two thermoplastic processes for improved treatment of radioactive, hazardous, and mixed wastes were developed from bench scale through technology demonstration: polyethylene encapsulation and modified sulfur cement encapsulation. The steps required to bring technologies from the research and development stage through full scale implementation are described. Both systems result in durable waste forms that meet current Nuclear Regulatory Commission and Environmental Protection Agency regulatory criteria and provide significant improvements over conventional solidification systems such as hydraulic cement. For example, the polyethylene process can encapsulate up to 70 wt pct. nitrate salt, compared with a maximum of about 20 wt pct. for the best hydraulic cement formulation. Modified sulfur cement waste forms containing as much as 43 wt pct. incinerator fly ash were formulated, whereas the maximum quantity of this waste in hydraulic cement is 16 wt pct.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Not Available

The purpose of this analysis is to provide information necessary for the Department of Energy (DOE) to evaluate the practical utility of the Nitrate to Ammonia and Ceramic or Glass (NAC/NAG/NAX) process, which is under development in the Oak Ridge National Laboratory. The NAC/NACx/NAX process can convert aqueous radioactive nitrate-laden waste to a glass, ceramic, or grout solid waste form. The tasks include, but are not limited to, the following: Identify current commercial technologies to meet hazardous and radiological waste disposal requirements. The technologies may be thermal or non-thermal but must be all inclusive (i.e., must convert a radionuclide-containing nitratemore » waste with a pH around 12 to a stable form that can be disposed at permitted facilities); evaluate and compare DOE-sponsored vitrification, grouting, and minimum additive waste stabilization projects for life-cycle costs; compare the technologies above with respect to material costs, capital equipment costs, operating costs, and operating efficiencies. For the NAC/NAG/NAX process, assume aluminum reactant is government furnished and ammonia gas may be marketed; compare the identified technologies with respect to frequency of use within DOE for environmental management applications with appropriate rationale for use; Assess the potential size of the DOE market for the NAC/NAG/NAX process; assess and off-gas issues; and compare with international technologies, including life-cycle estimates.« less

Review of Potential Candidate Stabilization Technologies for Liquid and Solid Secondary Waste Streams

DOE Office of Scientific and Technical Information (OSTI.GOV)

Pierce, Eric M.; Mattigod, Shas V.; Westsik, Joseph H.

2010-01-30

Pacific Northwest National Laboratory has initiated a waste form testing program to support the long-term durability evaluation of a waste form for secondary wastes generated from the treatment and immobilization of Hanford radioactive tank wastes. The purpose of the work discussed in this report is to identify candidate stabilization technologies and getters that have the potential to successfully treat the secondary waste stream liquid effluent, mainly from off-gas scrubbers and spent solids, produced by the Hanford Tank Waste Treatment and Immobilization Plant (WTP). Down-selection to the most promising stabilization processes/waste forms is needed to support the design of a solidificationmore » treatment unit (STU) to be added to the Effluent Treatment Facility (ETF). To support key decision processes, an initial screening of the secondary liquid waste forms must be completed by February 2010.« less

Modeling of Solid Waste Processing Options in BIO-Plex

NASA Technical Reports Server (NTRS)

Rodriguez, Luis F.; Finn, Cory; Kang, Sukwon; Hogan, John; Luna, Bernadette (Technical Monitor)

2000-01-01

BIO-Plex is a ground-based test bed currently under development by NASA for testing technologies and practices that may be utilized in future long-term life support missions. All aspects of such an Advanced Life Support (ALS) System must be considered to confidently construct a reliable system, which will not only allow the crew to survive in harsh environments, but allow the crew time to perform meaningful research. Effective handling of solid wastes is a critical aspect of the system, especially when recovery of resources contained in the waste is required. This is particularly important for ALS Systems configurations that include a Biomass Production Chamber. In these cases, significant amounts of inedible biomass waste may be produced, which can ultimately serve as a repository of necessary resources for sustaining life, notably carbon, water, and plant nutrients. Numerous biological and physicochemical solid waste processing options have been considered. Biological options include composting, aerobic digestion, and anaerobic digestion. Physicochemical options include pyrolysis, SCWO (supercritical water oxidation), various incineration configurations, microwave incineration, magnetically assisted gasification, and low temperature plasma reaction. Modeling of these options is a necessary step to assist in the design process. A previously developed top-level model of BIO-Plex implemented in MATLAB Simulink (r) for the use of systems analysis and design has been adopted for this analysis. Presently, this model only considered incineration for solid waste processing. Present work, reported here, includes the expansion of this model to include a wider array of solid waste processing options selected from the above options, bearing in mind potential, near term solid waste treatment systems. Furthermore, a trade study has also been performed among these solid waste processing technologies in an effort to determine the ideal technology for long-term life support missions.

Mixed Waste Focus Area alternative oxidation technologies development and demonstration program

DOE Office of Scientific and Technical Information (OSTI.GOV)

Borduin, L.C.; Fewell, T.; Gombert, D.

1998-07-01

The Mixed Waste Focus Area (MWFA) is currently supporting the development and demonstration of several alternative oxidation technology (AOT) processes for treatment of combustible mixed low-level wastes. The impetus for this support derives from regulatory and political hurdles frequently encountered by traditional thermal techniques, primarily incinerators. AOTs have been defined as technologies that destroy organic material without using open-flame reactions. Whether thermal or nonthermal, the processes have the potential advantages of relatively low-volume gaseous emissions, generation of few or no dioxin/furan compounds, and operation at low enough temperatures that metals (except mercury) and most radionuclides are not volatilized. Technology developmentmore » and demonstration are needed to confirm and realize the potential of AOTs and to compare them on an equal basis with their fully demonstrated thermal counterparts. AOTs include both thermal and nonthermal processes that oxidize organic wastes but operate under significantly different physical and chemical conditions than incinerators. Nonthermal processes currently being studied include Delphi DETOX and acid digestion at the Savannah River Site, and direct chemical oxidation at Lawrence Livermore National Laboratory. All three technologies are at advanced stages of development or are entering the demonstration phase. Nonflame thermal processes include catalytic chemical oxidation, which is being developed and deployed at Lawrence Berkeley National Laboratory, and team reforming, a commercial process being supported by Department of Energy. Related technologies include two low-flow, secondary oxidation processes (Phoenix and Thermatrix units) that have been tested at MSE, Inc., in Butte, Montana. Although testing is complete on some AOT technologies, most require additional support to complete some or all of the identified development objectives. Brief descriptions, status, and planned paths forward for each of the technologies are presented.« less

Bioelectrochemical Integration of Waste Heat Recovery, Waste-to- Energy Conversion, and Waste-to-Chemical Conversion with Industrial Gas and Chemical Manufacturing Processes

DOE Office of Scientific and Technical Information (OSTI.GOV)

Mac Dougall, James

2016-02-05

Many U.S. manufacturing facilities generate unrecovered, low-grade waste heat, and also generate or are located near organic-content waste effluents. Bioelectrochemical systems, such as microbial fuel cells and microbial electrolysis cells, provide a means to convert organic-content effluents into electric power and useful chemical products. A novel biochemical electrical system for industrial manufacturing processes uniquely integrates both waste heat recovery and waste effluent conversion, thereby significantly reducing manufacturing energy requirements. This project will enable the further development of this technology so that it can be applied across a wide variety of US manufacturing segments, including the chemical, food, pharmaceutical, refinery, andmore » pulp and paper industries. It is conservatively estimated that adoption of this technology could provide nearly 40 TBtu/yr of energy, or more than 1% of the U.S. total industrial electricity use, while reducing CO 2 emissions by more than 6 million tons per year. Commercialization of this technology will make a significant contribution to DOE’s Industrial Technology Program goals for doubling energy efficiency and providing a more robust and competitive domestic manufacturing base.« less

Need for improvements in physical pretreatment of source-separated household food waste.

PubMed

Bernstad, A; Malmquist, L; Truedsson, C; la Cour Jansen, J

2013-03-01

The aim of the present study was to investigate the efficiency in physical pretreatment processes of source-separated solid organic household waste. The investigation of seventeen Swedish full-scale pretreatment facilities, currently receiving separately collected food waste from household for subsequent anaerobic digestion, shows that problems with the quality of produced biomass and high maintenance costs are common. Four full-scale physical pretreatment plants, three using screwpress technology and one using dispergation technology, were compared in relation to resource efficiency, losses of nitrogen and potential methane production from biodegradable matter as well as the ratio of unwanted materials in produced biomass intended for wet anaerobic digestion. Refuse generated in the processes represent 13-39% of TS in incoming wet waste. The methane yield from these fractions corresponds to 14-36Nm(3)/ton separately collected solid organic household waste. Also, 13-32% of N-tot in incoming food waste is found in refuse. Losses of both biodegradable material and nutrients were larger in the three facilities using screwpress technology compared to the facility using dispersion technology.(1) Thus, there are large potentials for increase of both the methane yield and nutrient recovery from separately collected solid organic household waste through increased efficiency in facilities for physical pretreatment. Improved pretreatment processes could thereby increase the overall environmental benefits from anaerobic digestion as a treatment alternative for solid organic household waste. Copyright © 2012 Elsevier Ltd. All rights reserved.

Physical-Chemical Solid Waste Processing for Space Missions at Ames Research Center

NASA Technical Reports Server (NTRS)

Fisher, John W.; Pisharody, Suresh; Moran, Mark; Wignarajah, K.; Tleimat, Maher; Pace, Greg

2001-01-01

As space missions become longer in duration and reach out to more distant locations such as Mars, solids waste processing progresses from storage technologies to reclamation technologies. Current low Earth orbit technologies consist of store-and dispose to space or return to Earth. Fully regenerative technologies recycle wastes. The materials reclaimed from waste can be used to provide the basic materials to support plant growth for food including carbon dioxide, water, and nutrients. Other products can also be reclaimed from waste such as hydrocarbons and activated carbon. This poster describes development at Ames Research Center of a process to make activated carbon from space mission wastes and to make an incineration system that produces clean flue gas. Inedible biomass and feces contain hydrocarbons in a form that can be pyrolyzed and converted to activated carbon. The activated carbon can then be used to clean up contaminants from various other life support systems; in particular, the activated carbon can be used regeneratively to remove NOx from incinerator flue gas. Incinerator flue gas can also be cleaned up by the use of reductive and oxidative catalysts. A catalytic incinerator flue gas cleanup system has been developed at ARC that produces flue gas clean enough (with the exception of carbon dioxide) to meet the Space Minimum Allowable Concentration limits for human exposure.

Demonstration of Plasma Arc Environmental Technology Applications for the Demilitrization of DOD Stockpiles

NASA Technical Reports Server (NTRS)

Smith, Ed; Dee, P. E.; Zaghloul, Hany; Filius, Krag; Rivers, Tim

2000-01-01

Since 1989 the US Army Construction Engineering Research Laboratories (USACERL) have been active participants in the research and development towards establishing Plasma Arc Technology (PAT) as an efficient, economical, and safe hazardous waste immobilization tool. A plasma torch capable of generating high temperatures makes this technology a viable and powerful tool for the thermal destruction of various military industrial waste streams into an innocuous ceramic material no longer requiring hazardous waste landfill disposal. The emerging plasma environmental thermal treatment process has been used to safely and efficiently meet the waste disposal needs for various demilitarized components disposal needs, such as: (1) pyrotechnic smoke assemblies, (2) thermal batteries, (3) proximity fuses, (4) cartridge actuated devices (CADs), and (5) propellant actuated devices (PADs). MSE Technology Applications, Inc., (MSE) has proposed and fabricated a Mobile Plasma Treatment System to be a technology demonstrator for pilotscale mobile plasma waste processing. The system is capable of providing small-scale waste remediation services, and conducting waste stream applicability demonstrations. The Mobile Plasma Treatment System's innovative concept provides the flexibility to treat waste streams at numerous sites and sites with only a limited quantity of waste, yet too hazardous to transport to a regional fixed facility. The system was designed to be operated as skid mounted modules; consisting of a furnace module, controls module, offgas module, and ancillary systems module. All system components have been integrated to be operated from a single control station with both semi-continuous feeding and batch slag-pouring capability.

Demonstration of Plasma Arc Environmental Technology Applications for the Demilitarization of DOD Stockpiles

NASA Technical Reports Server (NTRS)

Smith, Ed; Zaghloul, Hany; Filius, Krag; Rivers, Tim

2000-01-01

Since 1989 the U.S. Army Construction Engineering Research Laboratories (USACERL) have been active participants in the research and development toward establishing Plasma Arc Technology (PAT) as an efficient, economical, and safe hazardous waste immobilization tool. A plasma torch capable of generating high temperatures makes this technology a viable and powerful tool for the thermal destruction of various military industrial waste streams into an innocuous ceramic material no longer requiring hazardous waste landfill (Class 1) disposal. The emerging pl asma environmental thermal treatment process, has been used to safely and efficiently meet the waste disposal needs for various demilitarized components disposal needs, such as: pyrotechnic smoke assemblies, thermal batteries, proximity fuses, cartridge actuated devices (CAD's), and propellant actuated devices (PAD's). MSE Technology Applications, Inc., (MSE) has proposed and fabricated a Mobile Plasma Treatment System to be a technology demonstrator for pilot-scale mobile plasma waste processing. The system is capable of providing small-scale waste remediation services, and conducting waste stream applicability demonstrations. The Mobile Plasma Treatment System's innovative concept provides the flexibility to treat waste streams at numerous sites and sites with only a limited quantity of waste, yet too hazardous to transport to a regional fixed facility. The system was designed to be operated as skid mounted modules; consisting of a furnace module, controls module, offgas module, and ancillary systems module. All system components have been integrated to be operated from a single control station with both semi-continuous feeding and batch slag-pouring capability.

PARALLEL MULTIOBJECTIVE EVOLUTIONARY ALGORITHMS FOR WASTE SOLVENT RECYCLING

EPA Science Inventory

Waste solvents are of great concern to the chemical process industries and to the public, and many technologies have been suggested and implemented in the chemical process industries to reduce waste and associated environmental impacts. In this article we have developed a novel p...

Test plan for formulation and evaluation of grouted waste forms with shine process wastes

DOE Office of Scientific and Technical Information (OSTI.GOV)

Ebert, W. L.; Jerden, J. L.

2015-09-01

The objective of this experimental project is to demonstrate that waste streams generated during the production of Mo99 by the SHINE Medical Technologies (SHINE) process can be immobilized in cement-based grouted waste forms having physical, chemical, and radiological stabilities that meet regulatory requirements for handling, storage, transport, and disposal.

Effective pine bark composting with the Dome Aeration Technology

DOE Office of Scientific and Technical Information (OSTI.GOV)

Trois, Cristina; Polster, Andreas

2007-07-01

In South Africa garden refuse is primarily disposed of in domestic landfills. Due to the large quantities generated, any form of treatment would be beneficial for volume reduction, waste stabilization and resource recovery. Dome Aeration Technology (DAT) is an advanced process for aerobic biological degradation of garden refuse and general waste [Paar, S., Brummack, J., Gemende, B., 1999a. Advantages of dome aeration in mechanical-biological waste treatment. In: Proceedings of the 7th International Waste Management and Landfill Symposium, Cagliari, 4-8 October 1999; Paar, S., Brummack, J., Gemende, B., 1999b. Mechanical-biological waste stabilization by the dome aeration method. Environment Protection Engineering 25more » (3/99). Mollekopf, N., Brummack, J., Paar, S., Vorster, K., 2002. Use of the Dome Aeration Technology for biochemical stabilization of waste prior to landfilling. In: Proceedings of the Wastecon 2002, Waste Congress and Exhibition, Durban, South Africa.]. It is a non-reactor open windrow composting process, with the main advantage being that the input material needs no periodic turning. A rotting time of only 3-4 months indicates the high efficiency. Additionally, the low capital/operational costs, low energy inputs and limited plant requirements provide potential for use in aerobic refuse stabilization. The innovation in the DAT process is the passive aeration achieved by thermally driven advection through open windrows caused by temperature differences between the degrading material and the outside environment. This paper investigates the application of Dome Aeration Technology to pine bark composting as part of an integrated waste management strategy. A full-scale field experiment was performed at the Bisasar Road Landfill Site in Durban to assess the influence of climate, waste composition and operational conditions on the process. A test windrow was constructed and measurements of temperature and airflow through the material were taken. The process monitoring revealed that prevailing climatic conditions in a subtropical location do not affect the high efficiency of this technology. However, the composition of the input material can be detrimental for production of high quality compost because of a lack of nitrate.« less

DOE Office of Scientific and Technical Information (OSTI.GOV)

Elia, Valerio; Gnoni, Maria Grazia, E-mail: mariagrazia.gnoni@unisalento.it; Tornese, Fabiana

Highlights: • Pay-As-You-Throw (PAYT) schemes are becoming widespread in several countries. • Economic, organizational and technological issues have to be integrated in an efficient PAYT model design. • Efficiency refers to a PAYT system which support high citizen participation rates as well as economic sustainability. • Different steps and constraints have to be evaluated from collection services to type technologies. • An holistic approach is discussed to support PAYT systems diffusion. - Abstract: Pay-As-You-Throw (PAYT) strategies are becoming widely applied in solid waste management systems; the main purpose is to support a more sustainable – from economic, environmental and socialmore » points of view – management of waste flows. Adopting PAYT charging models increases the complexity level of the waste management service as new organizational issues have to be evaluated compared to flat charging models. In addition, innovative technological solutions could also be adopted to increase the overall efficiency of the service. Unit pricing, user identification and waste measurement represent the three most important processes to be defined in a PAYT system. The paper proposes a holistic framework to support an effective design and management process. The framework defines most critical processes and effective organizational and technological solutions for supporting waste managers as well as researchers.« less

Glass science tutorial: Lecture No. 7, Waste glass technology for Hanford

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kruger, A.A.

1995-07-01

This paper presents the details of the waste glass tutorial session that was held to promote knowledge of waste glass technology and how this can be used at the Hanford Reservation. Topics discussed include: glass properties; statistical approach to glass development; processing properties of nuclear waste glass; glass composition and the effects of composition on durability; model comparisons of free energy of hydration; LLW glass structure; glass crystallization; amorphous phase separation; corrosion of refractories and electrodes in waste glass melters; and glass formulation for maximum waste loading.

An LCA model for waste incineration enhanced with new technologies for metal recovery and application to the case of Switzerland.

PubMed

Boesch, Michael E; Vadenbo, Carl; Saner, Dominik; Huter, Christoph; Hellweg, Stefanie

2014-02-01

A process model of municipal solid waste incinerators (MSWIs) and new technologies for metal recovery from combustion residues was developed. The environmental impact is modeled as a function of waste composition as well as waste treatment and material recovery technologies. The model includes combustion with a grate incinerator, several flue gas treatment technologies, electricity and steam production from waste heat recovery, metal recovery from slag and fly ash, and landfilling of residues and can be tailored to specific plants and sites (software tools can be downloaded free of charge). Application of the model to Switzerland shows that the treatment of one tonne of municipal solid waste results on average in 425 kg CO2-eq. generated in the incineration process, and 54 kg CO2-eq. accrue in upstream processes such as waste transport and the production of operating materials. Downstream processes, i.e. residue disposal, generates 5 kg CO2-eq. Savings from energy recovery are in the range of 67 to 752 kg CO2-eq. depending on the assumptions regarding the substituted energy production, while the recovery of metals from slag and fly ash currently results in a net saving of approximately 35 kg CO2-eq. A similar impact pattern is observed when assessing the MSWI model for aggregated environmental impacts (ReCiPe) and for non-renewable resource consumption (cumulative exergy demand), except that direct emissions have less and no relevance, respectively, on the total score. The study illustrates that MSWI plants can be an important element of industrial ecology as they provide waste disposal services and can help to close material and energetic cycles. Copyright © 2013 Elsevier Ltd. All rights reserved.

Human life support during interplanetary travel and domicile. V - Mars expedition technology trade study for solid waste management

NASA Technical Reports Server (NTRS)

Ferrall, Joe; Rohatgi, Naresh K.; Seshan, P. K.

1992-01-01

A model has been developed for NASA to quantitatively compare and select life support systems and technology options. The model consists of a modular, top-down hierarchical breakdown of the life support system into subsystems, and further breakdown of subsystems into functional elements representing individual processing technologies. This paper includes the technology trades for a Mars mission, using solid waste treatment technologies to recover water from selected liquid and solid waste streams. Technologies include freeze drying, thermal drying, wet oxidation, combustion, and supercritical-water oxidation. The use of these technologies does not have any significant advantages with respect to weight; however, significant power penalties are incurred. A benefit is the ability to convert hazardous waste into a useful resource, namely water.

Modules for estimating solid waste from fossil-fuel technologies

DOE Office of Scientific and Technical Information (OSTI.GOV)

Crowther, M.A.; Thode, H.C. Jr.; Morris, S.C.

1980-10-01

Solid waste has become a subject of increasing concern to energy industries for several reasons. Increasingly stringent air and water pollution regulations result in a larger fraction of residuals in the form of solid wastes. Control technologies, particularly flue gas desulfurization, can multiply the amount of waste. With the renewed emphasis on coal utilization and the likelihood of oil shale development, increased amounts of solid waste will be produced. In the past, solid waste residuals used for environmental assessment have tended only to include total quantities generated. To look at environmental impacts, however, data on the composition of the solidmore » wastes are required. Computer modules for calculating the quantities and composition of solid waste from major fossil fuel technologies were therefore developed and are described in this report. Six modules have been produced covering physical coal cleaning, conventional coal combustion with flue gas desulfurization, atmospheric fluidized-bed combustion, coal gasification using the Lurgi process, coal liquefaction using the SRC-II process, and oil shale retorting. Total quantities of each solid waste stream are computed together with the major components and a number of trace elements and radionuclides.« less

WESTERN RESEARCH INSTITUTE CONTAINED RECOVERY OF OILY WASTES (CROW) PROCESS - ITER

EPA Science Inventory

This report summarizes the findings of an evaluation of the Contained Recovery of Oily Wastes (CROW) technology developed by the Western Research Institute. The process involves the injection of heated water into the subsurface to mobilize oily wastes, which are removed from the ...

Hydrothermal Gasification for Waste to Energy

NASA Astrophysics Data System (ADS)

Epps, Brenden; Laser, Mark; Choo, Yeunun

2014-11-01

Hydrothermal gasification is a promising technology for harvesting energy from waste streams. Applications range from straightforward waste-to-energy conversion (e.g. municipal waste processing, industrial waste processing), to water purification (e.g. oil spill cleanup, wastewater treatment), to biofuel energy systems (e.g. using algae as feedstock). Products of the gasification process are electricity, bottled syngas (H2 + CO), sequestered CO2, clean water, and inorganic solids; further chemical reactions can be used to create biofuels such as ethanol and biodiesel. We present a comparison of gasification system architectures, focusing on efficiency and economic performance metrics. Various system architectures are modeled computationally, using a model developed by the coauthors. The physical model tracks the mass of each chemical species, as well as energy conversions and transfers throughout the gasification process. The generic system model includes the feedstock, gasification reactor, heat recovery system, pressure reducing mechanical expanders, and electricity generation system. Sensitivity analysis of system performance to various process parameters is presented. A discussion of the key technological barriers and necessary innovations is also presented.

Energy from gasification of solid wastes.

PubMed

Belgiorno, V; De Feo, G; Della Rocca, C; Napoli, R M A

2003-01-01

Gasification technology is by no means new: in the 1850s, most of the city of London was illuminated by "town gas" produced from the gasification of coal. Nowadays, gasification is the main technology for biomass conversion to energy and an attractive alternative for the thermal treatment of solid waste. The number of different uses of gas shows the flexibility of gasification and therefore allows it to be integrated with several industrial processes, as well as power generation systems. The use of a waste-biomass energy production system in a rural community is very interesting too. This paper describes the current state of gasification technology, energy recovery systems, pre-treatments and prospective in syngas use with particular attention to the different process cycles and environmental impacts of solid wastes gasification.

Waste water processing technology for Space Station Freedom - Comparative test data analysis

NASA Technical Reports Server (NTRS)

Miernik, Janie H.; Shah, Burt H.; Mcgriff, Cindy F.

1991-01-01

Comparative tests were conducted to choose the optimum technology for waste water processing on SSF. A thermoelectric integrated membrane evaporation (TIMES) subsystem and a vapor compression distillation subsystem (VCD) were built and tested to compare urine processing capability. Water quality, performance, and specific energy were compared for conceptual designs intended to function as part of the water recovery and management system of SSF. The VCD is considered the most mature and efficient technology and was selected to replace the TIMES as the baseline urine processor for SSF.

Microwave technology for waste management applications: Treatment of discarded electronic circuitry

DOE Office of Scientific and Technical Information (OSTI.GOV)

Wicks, G.G.; Clark, D.E.; Schulz, R.L.

1997-01-01

Significant quantities of hazardous wastes are generated from a multitude of processes and products in today`s society. This waste inventory is not only very large and diverse, but is also growing at an alarming rate. In order to minimize the dangers presented by constituents in these wastes, microwave technologies are being investigated to render harmless the hazardous components and ultimately, to minimize their impact to individuals and the surrounding environment.

Recovery technologies for building materials

NASA Astrophysics Data System (ADS)

Karu, Veiko; Nurme, Martin; Valgma, Ingo

2015-04-01

Mining industry provides building materials for construction. Civil engineers have settled the quality parameters for construction materials. When we produce high quality building materials from carbonate rock (limestone, dolostone), then the estimated waste share is 25% to 30%, depending on crushing principles and rock quality. The challenge is to find suitable technology for waste recovery. During international mining waste related cooperation project MIN-NOVATION (www.min-novation.eu), partners mapped possibilities for waste recovery in mining industry and pointed out good examples and case studies. One example from Estonia showed that when we produce limestone aggregate, then we produce up to 30% waste material (fines with size 0-4mm). This waste material we can see as secondary raw material for building materials. Recovery technology for this fine grained material has been achieved with CDE separation plant. During the process the plant washes out minus 63 micron material from the limestone fines. This technology allows us to use 92% of all limestone reserves. By-product from 63 microns to 4 mm we can use as filler in concrete or as fine limestone aggregate for building or building materials. MIN-NOVATION project partners also established four pilot stations to study other mineral waste recovery technologies and solutions. Main aims on this research are to find the technology for recovery of mineral wastes and usage for new by-products from mineral mining waste. Before industrial production, testing period or case studies are needed. This research is part of the study of Sustainable and environmentally acceptable Oil shale mining No. 3.2.0501.11-0025 http://mi.ttu.ee/etp and the project B36 Extraction and processing of rock with selective methods - http://mi.ttu.ee/separation; http://mi.ttu.ee/miningwaste/

An LCA model for waste incineration enhanced with new technologies for metal recovery and application to the case of Switzerland

DOE Office of Scientific and Technical Information (OSTI.GOV)

Boesch, Michael E.; Vadenbo, Carl, E-mail: vadenbo@ifu.baug.ethz.ch; Saner, Dominik

2014-02-15

Highlights: • An enhanced process-based LCA model for MSWI is featured and applied in case study. • LCA modeling of recent technological developments for metal recovery from fly ash. • Net release from Swiss MSWI 133 kg CO{sub 2}-eq/tonne waste from attributional LCA perspective. • Net savings from a consequential LCA perspective reach up to 303 kg CO{sub 2}-eq/tonne waste. • Impacts according to ReCiPe and CExD show similar pattern to climate change. - Abstract: A process model of municipal solid waste incinerators (MSWIs) and new technologies for metal recovery from combustion residues was developed. The environmental impact is modeledmore » as a function of waste composition as well as waste treatment and material recovery technologies. The model includes combustion with a grate incinerator, several flue gas treatment technologies, electricity and steam production from waste heat recovery, metal recovery from slag and fly ash, and landfilling of residues and can be tailored to specific plants and sites (software tools can be downloaded free of charge). Application of the model to Switzerland shows that the treatment of one tonne of municipal solid waste results on average in 425 kg CO{sub 2}-eq. generated in the incineration process, and 54 kg CO{sub 2}-eq. accrue in upstream processes such as waste transport and the production of operating materials. Downstream processes, i.e. residue disposal, generates 5 kg CO{sub 2}-eq. Savings from energy recovery are in the range of 67 to 752 kg CO{sub 2}-eq. depending on the assumptions regarding the substituted energy production, while the recovery of metals from slag and fly ash currently results in a net saving of approximately 35 kg CO{sub 2}-eq. A similar impact pattern is observed when assessing the MSWI model for aggregated environmental impacts (ReCiPe) and for non-renewable resource consumption (cumulative exergy demand), except that direct emissions have less and no relevance, respectively, on the total score. The study illustrates that MSWI plants can be an important element of industrial ecology as they provide waste disposal services and can help to close material and energetic cycles.« less

An assessment of waste processing/resource recovery technologies for lunar/Mars life applications

NASA Technical Reports Server (NTRS)

Verostko, Charles E.; Packham, Nigel J. C.; Henninger, Donald H.

1992-01-01

NASA's future manned missions to explore the solar system are by nature of long duration, mandating extensive regeneration of life support consumables from wastes generated in space-based habitats. Long-duration exploration missions would otherwise be prohibitive due to the number and frequency of energy-intensive resupply missions from Earth. Resource recovery is therefore a critical component of the controlled ecological life support system (CELSS). In order to assess resource recovery technologies for CELSS applications, the Crew and Thermal Systems Division at NASA-Johnson Space Center convened a three-day workshop to assess potential resource recovery technologies for application in a space-based CELSS. This paper describes the methodology of assessing and ranking of these technologies. Recommendations and issues are identified. Evaluations focused on the processes for handling and treatment of inedible plant biomass, human waste, and human generated trash. Technologies were assessed on the basis of safety, reliability, technology readiness, and performance characteristics.

Technology transfer into the solid propulsion industry

NASA Technical Reports Server (NTRS)

Campbell, Ralph L.; Thomson, Lawrence J.

1995-01-01

This paper is a survey of the waste minimization efforts of industries outside of aerospace for possible applications in the manufacture of solid rocket motors (SRM) for NASA. The Redesigned Solid Rocket Motor (RSRM) manufacturing plan was used as the model for processes involved in the production of an SRM. A literature search was conducted to determine the recycling, waste minimization, and waste treatment methods used in the commercial sector that might find application in SRM production. Manufacturers, trade organizations, and professional associations were also contacted. Waste minimization efforts for current processes and replacement technologies, which might reduce the amount or severity of the wastes generated in SRM production, were investigated. An overview of the results of this effort are presented in this paper.

Solid Waste Treatment Technology

ERIC Educational Resources Information Center

Hershaft, Alex

1972-01-01

Advances in research and commercial solid waste handling are offering many more processing choices. This survey discusses techniques of storage and removal, fragmentation and sorting, bulk reduction, conversion, reclamation, mining and mineral processing, and disposal. (BL)

Evaluation of alternative nonflame technologies for destruction of hazardous organic waste

DOE Office of Scientific and Technical Information (OSTI.GOV)

Schwinkendorf, W.E.; Musgrave, B.C.; Drake, R.N.

1997-04-01

The US Department of Energy`s Mixed Waste Focus Area (MWFA) commissioned an evaluation of mixed waste treatment technologies that are alternatives to incineration for destruction of hazardous organic wastes. The purpose of this effort is to evaluate technologies that are alternatives to open-flame, free-oxygen combustion (as exemplified by incinerators), and recommend to the Waste Type Managers and the MWFA which technologies should be considered for further development. Alternative technologies were defined as those that have the potential to: destroy organic material without use of open-flame reactions with free gas-phase oxygen as the reaction mechanism; reduce the offgas volume and associatedmore » contaminants (metals, radionuclides, and particulates) emitted under normal operating conditions; eliminate or reduce the production of dioxins and furans; and reduce the potential for excursions in the process that can lead to accidental release of harmful levels of chemical or radioactive materials. Twenty-three technologies were identified that have the potential for meeting these requirements. These technologies were rated against the categories of performance, readiness for deployment, and environment safety, and health. The top ten technologies that resulted from this evaluation are Steam Reforming, Electron Beam, UV Photo-Oxidation, Ultrasonics, Eco Logic reduction process, Supercritical Water oxidation, Cerium Mediated Electrochemical Oxidation, DETOX{sup SM}, Direct Chemical Oxidation (peroxydisulfate), and Neutralization/Hydrolysis.« less

SELENIUM TREATMENT/REMOVAL ALTERNATIVES DEMONSTRATION PROJECT - MINE WASTE TECHNOLOGY PROGRAM ACTIVITY III, PROJECT 20

EPA Science Inventory

This document is the final report for EPA's Mine WAste Technology Program (MWTP) Activity III, Project 20--Selenium Treatment/Removal Alternatives Demonstration project. Selenium contamination originates from many sources including mining operations, mineral processing, abandoned...

Technology development in support of the TWRS process flowsheet. Revision 1

DOE Office of Scientific and Technical Information (OSTI.GOV)

Washenfelder, D.J.

1995-10-11

The Tank Waste Remediation System is to treat and dispose of Hanford`s Single-Shell and Double-Shell Tank Waste. The TWRS Process Flowsheet, (WHC-SD-WM-TI-613 Rev. 1) described a flowsheet based on a large number of assumptions and engineering judgements that require verification or further definition through process and technology development activities. This document takes off from the TWRS Process Flowsheet to identify and prioritize tasks that should be completed to strengthen the technical foundation for the flowsheet.

Plasma for environment

NASA Astrophysics Data System (ADS)

Van Oost, G.

2017-11-01

Human activity is associated with the permanent emergence of a very wide range of waste streams. The most widely used treatment of waste is thermal processing such as incineration. An alternative environmentally friendly process is based on thermal plasma technology which is a very flexible tool because it allows to operate in a wide temperature range with almost any chemical composition of waste and chemicals needed for processing this waste, and to convert organic waste into energy or chemical substances as well as to destroy toxic organic compounds, and to vitrify radioactive waste in a scenario that for each specific type of waste can be considered optimal, both in terms of energy efficiency and environmental safety.

Liquid secondary waste: Waste form formulation and qualification

DOE Office of Scientific and Technical Information (OSTI.GOV)

Cozzi, A. D.; Dixon, K. L.; Hill, K. A.

The Hanford Site Effluent Treatment Facility (ETF) currently treats aqueous waste streams generated during site cleanup activities. When the Hanford Tank Waste Treatment and Immobilization Plant (WTP) begins operations, including Direct Feed Low Activity Waste (DFLAW) vitrification, a liquid secondary waste (LSW) stream from the WTP will need to be treated. The volume of effluent for treatment at the ETF will increase significantly. The powdered salt waste form produced by the ETF will be replaced by a stabilized solidified waste form for disposal in Hanford’s Integrated Disposal Facility (IDF). Washington River Protection Solutions is implementing a Secondary Liquid Waste Immobilizationmore » Technology Development Plan to address the technology needs for a waste form and solidification process to treat the increased volume of waste planned for disposal at the IDF. Waste form testing to support this plan is composed of work in the near term to provide data as input to a performance assessment (PA) for Hanford’s IDF. In 2015, three Hanford Liquid Secondary Waste simulants were developed based on existing and projected waste streams. Using these waste simulants, fourteen mixes of Hanford Liquid Secondary Waste were prepared and tested varying the waste simulant, the water-to-dry materials ratio, and the dry materials blend composition.1 In FY16, testing was performed using a simulant of the EMF process condensate blended with the caustic scrubber—from the Low Activity Waste (LAW) melter—, processed through the ETF. The initial EMF-16 simulant will be based on modeling efforts performed to determine the mass balance of the ETF for the DFLAW.2 The compressive strength of all of the mixes exceeded the target of 3.4 MPa (500 psi) to meet the requirements identified as potential IDF Waste Acceptance Criteria in Table 1 of the Secondary Liquid Waste Immobilization Technology Development Plan.3 The hydraulic properties of the waste forms tested (hydraulic conductivity and water characteristic curves) were comparable to the properties measured on the Savannah River Site (SRS) Saltstone waste form. Future testing should include efforts to first; 1) determine the rate and amount of ammonia released during each unit operation of the treatment process to determine if additional ammonia management is required, then; 2) reduce the ammonia content of the ETF concentrated brine prior to solidification, making the waste more amenable to grouting, or 3) manage the release of ammonia during production and ongoing release during storage of the waste form, or 4) develop a lower pH process/waste form thereby precluding ammonia release.« less

Carbon black dispersion pre-plating technology for printed wire board manufacturing. Final technology evaluation report

DOE Office of Scientific and Technical Information (OSTI.GOV)

Folsom, D.W.; Gavaskar, A.R.; Jones, J.A.

1993-10-01

The project compared chemical use, waste generation, cost, and product quality between electroless copper and carbon-black-based preplating technologies at the printed wire board (PWB) manufacturing facility of McCurdy Circuits in Orange, CA. The carbon-black based preplating technology evaluated is used as an alternative process for electroless copper (EC) plating of through-holes before electrolytic copper plating. The specific process used at McCurdy is the BlackHole (BH) technology process, which uses a dispersion of carbon black in an aqueous solution to provide a conductive surface for subsequent electrolytic copper plating. The carbon-black dispersion technology provided effective waste reduction and long-term cost savings.more » The economic analysis determined that the new process was cost efficient because chemical use was reduced and the process proved more efficient; the payback period was less than 4 yrs.« less

FLASH Technology: Full-Scale Hospital Waste Water Treatments Adopted in Aceh

NASA Astrophysics Data System (ADS)

Rame; Tridecima, Adeodata; Pranoto, Hadi; Moesliem; Miftahuddin

2018-02-01

A Hospital waste water contains a complex mixture of hazardous chemicals and harmful microbes, which can pose a threat to the environment and public health. Some efforts have been carried out in Nangroe Aceh Darussalam (Aceh), Indonesia with the objective of treating hospital waste water effluents on-site before its discharge. Flash technology uses physical and biological pre-treatment, followed by advanced oxidation process based on catalytic ozonation and followed by GAC and PAC filtration. Flash Full-Scale Hospital waste water Treatments in Aceh from different district have been adopted and investigated. Referring to the removal efficiency of macro-pollutants, the collected data demonstrate good removal efficiency of macro-pollutants using Flash technologies. In general, Flash technologies could be considered a solution to the problem of managing hospital waste water.

Optimised management of orphan wastes in the UK

DOE Office of Scientific and Technical Information (OSTI.GOV)

Doudou, Slimane; McTeer, Jennifer; Wickham, Stephen

2013-07-01

Orphan wastes have properties preventing them from being managed according to existing or currently planned management routes, or lack characterisation so that their management is uncertain. The identification of new management opportunities for orphan wastes could realise significant benefits by reducing the number of processing facilities required, reducing waste volumes, reducing hazard or leading to the development of centres of excellence for the processing of certain types of orphan wastes. Information on the characteristics of orphan waste existing at nuclear licensed sites across the UK has been collated and a database developed to act as a repository for the informationmore » gathered. The database provides a capability to analyse the data and to explore possible treatment technologies for each orphan waste type. Thirty five distinct orphan waste types have been defined and possible treatment options considered. Treatment technologies (including chemical, high temperature, immobilisation and physical technologies) that could be applied to one or more of the generic orphan waste streams have been identified. Wiring diagrams have been used to highlight the waste treatment / lifecycle management options that are available for each of the generic orphan groups as well as identifying areas for further research and development. This work has identified the potential for optimising the management of orphan wastes in a number of areas, and many potential opportunities were identified. Such opportunities could be investigated by waste managers at waste producing nuclear sites, to facilitate the development of new management routes for orphan wastes. (authors)« less

40 CFR 270.65 - Research, development, and demonstration permits.

Code of Federal Regulations, 2010 CFR

2010-07-01

... (CONTINUED) SOLID WASTES (CONTINUED) EPA ADMINISTERED PERMIT PROGRAMS: THE HAZARDOUS WASTE PERMIT PROGRAM... may issue a research, development, and demonstration permit for any hazardous waste treatment facility which proposes to utilize an innovative and experimental hazardous waste treatment technology or process...

40 CFR 270.65 - Research, development, and demonstration permits.

Code of Federal Regulations, 2011 CFR

2011-07-01

... (CONTINUED) SOLID WASTES (CONTINUED) EPA ADMINISTERED PERMIT PROGRAMS: THE HAZARDOUS WASTE PERMIT PROGRAM... may issue a research, development, and demonstration permit for any hazardous waste treatment facility which proposes to utilize an innovative and experimental hazardous waste treatment technology or process...

EVALUATION OF WASTE STABILIZED BY THE SOLIDITECH SITE TECHNOLOGY

EPA Science Inventory

The Soliditech technology demonstration was conducted at the Imperial Oil Company/Champion Chemicals Superfund Site in Monmouth County, New Jersey. ontamination at this site includes PCBs, lead (with various other metals) and oil and grease. his process mixes the waste material w...

Microbial utilisation of natural organic wastes

NASA Astrophysics Data System (ADS)

Ilyin, V. K.; Smirnov, I. A.; Soldatov, P. E.; Korniushenkova, I. N.; Grinin, A. S.; Lykov, I. N.; Safronova, S. A.

2004-03-01

The waste management strategy for the future should meet the benefits of humanity safety, respect principals of planet ecology, and compatibility with other habitability systems. For these purpose the waste management technologies, relevant to application of the biodegradation properties of bacteria are of great value. The biological treatment method is based upon the biodegradation of organic substances by various microorganisms. The advantage of the biodegradation waste management in general: it allows to diminish the volume of organic wastes, the biological hazard of the wastes is controlled and this system may be compatible with the other systems. The objectives of our study were: to evaluate effectiveness of microbial biodegradation of non-pretreated substrate, to construct phneumoautomatic digester for organic wastes biodegradation and to study microbial characteristics of active sludge samples used as inoculi in biodegradation experiment. The technology of vegetable wastes treatment was elaborated in IBMP and BMSTU. For this purpose the special unit was created where the degradation process is activated by enforced reinvention of portions of elaborated biogas into digester. This technology allows to save energy normally used for electromechanical agitation and to create optimal environment for anaerobic bacteria growth. The investigations were performed on waste simulator, which imitates physical and chemical content of food wastes calculated basing on the data on food wastes of moderate Russian city. The volume of created experimental sample of digester is 40 l. The basic system elements of device are digesters, gas receiver, remover of drops and valve monitoring and thermal control system. In our testing we used natural food wastes to measure basic parameters and time of biodegradation process. The diminution rate of organic gained 76% from initial mass taking part within 9 days of fermentation. The biogas production achieved 46 l per 1 kg of substrate. The microbial studies of biodegradation process revealed following peculiarities: gradual quantitative increasing of Lactobacillus sp. (from 10 3 to 10 5 colony forming units (CFU) per ml), activation of Clostridia sp. (from 10 2 to 10 4 CFU/ml) and elimination of aerobic conventional pathogens ( Enterobacteriaceae sp., Protea sp., staphylococci). The obtained results allow to evaluate effectiveness of proposed technology and to determine the leading role of lactobacilli and clostridia in process of natural wastes biodegradation. Our further investigations shall further be concentrated on creation of artificial inoculi for launching of food wastes biodegradation. These inoculi will include active and adapted strains of clostridia and lactobacilli.

Waste gasification vs. conventional Waste-to-Energy: a comparative evaluation of two commercial technologies.

PubMed

Consonni, Stefano; Viganò, Federico

2012-04-01

A number of waste gasification technologies are currently proposed as an alternative to conventional Waste-to-Energy (WtE) plants. Assessing their potential is made difficult by the scarce operating experience and the fragmentary data available. After defining a conceptual framework to classify and assess waste gasification technologies, this paper compares two of the proposed technologies with conventional WtE plants. Performances are evaluated by proprietary software developed at Politecnico di Milano and compared on the basis of a coherent set of assumptions. Since the two gasification technologies are configured as "two-step oxidation" processes, their energy performances are very similar to those of conventional plants. The potential benefits that may justify their adoption relate to material recovery and operation/emission control: recovery of metals in non-oxidized form; collection of ashes in inert, vitrified form; combustion control; lower generation of some pollutants. Copyright © 2012 Elsevier Ltd. All rights reserved.

Chemical Technology Division annual technical report, 1990

DOE Office of Scientific and Technical Information (OSTI.GOV)

Not Available

1991-05-01

Highlights of the Chemical Technology (CMT) Division's activities during 1990 are presented. In this period, CMT conducted research and development in the following areas: (1) electrochemical technology, including advanced batteries and fuel cells; (2) technology for coal- fired magnetohydrodynamics and fluidized-bed combustion; (3) methods for recovery of energy from municipal waste and techniques for treatment of hazardous organic waste; (4) the reaction of nuclear waste glass and spent fuel under conditions expected for a high-level waste repository; (5) processes for separating and recovering transuranic elements from nuclear waste streams, concentrating plutonium solids in pyrochemical residues by aqueous biphase extraction, andmore » treating natural and process waters contaminated by volatile organic compounds; (6) recovery processes for discharged fuel and the uranium blanket in the Integral Fast Reactor (IFR); (7) processes for removal of actinides in spent fuel from commercial water-cooled nuclear reactors and burnup in IFRs; and (8) physical chemistry of selected materials in environments simulating those of fission and fusion energy systems. The Division also has a program in basic chemistry research in the areas of fluid catalysis for converting small molecules to desired products; materials chemistry for superconducting oxides and associated and ordered solutions at high temperatures; interfacial processes of importance to corrosion science, high-temperature superconductivity, and catalysis; and the geochemical processes responsible for trace-element migration within the earth's crust. The Analytical Chemistry Laboratory in CMT provides a broad range of analytical chemistry support services to the scientific and engineering programs at Argonne National Laboratory (ANL). 66 refs., 69 figs., 6 tabs.« less

Assessment of the Cast Stone Low-Temperature Waste Form Technology Coupled with Technetium Removal - 14379

DOE Office of Scientific and Technical Information (OSTI.GOV)

Brown, Christopher F.; Rapko, Brian M.; Serne, R. Jeffrey

2014-03-03

The U.S. Department of Energy Office of Environmental Management (EM) is engaging the national laboratories to provide the scientific and technological rigor to support EM program and project planning, technology development and deployment, project execution, and assessment of program outcomes. As an early demonstration of this new responsibility, Pacific Northwest National Laboratory (PNNL) and Savannah River National Laboratory (SRNL) were chartered to implement a science and technology program addressing low-temperature waste forms for immobilization of DOE aqueous waste streams, including technetium removal as an implementing technology. As a first step, the laboratories examined the technical risks and uncertainties associated withmore » the Cast Stone waste immobilization and technetium removal projects at Hanford. Science and technology gaps were identified for work associated with 1) conducting performance assessments and risk assessments of waste form and disposal system performance, and 2) technetium chemistry in tank wastes and separation of technetium from waste processing streams. Technical approaches to address the science and technology gaps were identified and an initial sequencing priority was suggested. A subset of research was initiated in 2013 to begin addressing the most significant science and technology gaps. The purpose of this paper is to report progress made towards closing these gaps and provide notable highlights of results achieved to date.« less

Metallurgical recovery of metals from electronic waste: a review.

PubMed

Cui, Jirang; Zhang, Lifeng

2008-10-30

Waste electric and electronic equipment, or electronic waste, has been taken into consideration not only by the government but also by the public due to their hazardous material contents. In the detailed literature survey, value distributions for different electronic waste samples were calculated. It is showed that the major economic driver for recycling of electronic waste is from the recovery of precious metals. The state of the art in recovery of precious metals from electronic waste by pyrometallurgical processing, hydrometallurgical processing, and biometallurgical processing are highlighted in the paper. Pyrometallurgical processing has been a traditional technology for recovery of precious metals from waste electronic equipment. However, state-of-the-art smelters are highly depended on investments. Recent research on recovery of energy from PC waste gives an example for using plastics in this waste stream. It indicates that thermal processing provides a feasible approach for recovery of energy from electronic waste if a comprehensive emission control system is installed. In the last decade, attentions have been removed from pyrometallurgical process to hydrometallurgical process for recovery of metals from electronic waste. In the paper, hydrometallurgical processing techniques including cyanide leaching, halide leaching, thiourea leaching, and thiosulfate leaching of precious metals are detailed. In order to develop an environmentally friendly technique for recovery of precious metals from electronic scrap, a critical comparison of main leaching methods is analyzed for both economic feasibility and environmental impact. It is believed that biotechnology has been one of the most promising technologies in metallurgical processing. Bioleaching has been used for recovery of precious metals and copper from ores for many years. However, limited research was carried out on the bioleaching of metals from electronic waste. In the review, initial researches on the topic are presented. In addition, mechanisms and models of biosorption of precious metal ions from solutions are discussed.

Chemical Technology Division annual technical report, 1992

DOE Office of Scientific and Technical Information (OSTI.GOV)

Battles, J.E.; Myles, K.M.; Laidler, J.J.

1993-06-01

In this period, CMT conducted research and development in the following areas: (1) electrochemical technology, including advanced batteries and fuel cells; (2) technology for fluidized-bed combustion and coal-fired magnetohydrodynamics; (3) methods for treatment of hazardous waste, mixed hazardous/radioactive waste, and municipal solid waste; (4) the reaction of nuclear waste glass and spent fuel under conditions expected for an unsaturated repository; (5) processes for separating and recovering transuranic elements from nuclear waste streams, treating water contaminated with volatile organics, and concentrating radioactive waste streams; (6) recovery processes for discharged fuel and the uranium blanket in the Integral Fast Reactor (EFR); (7)more » processes for removal of actinides in spent fuel from commercial water-cooled nuclear reactors and burnup in IFRs; and (8) physical chemistry of selected materials (corium; Fe-U-Zr, tritium in LiAlO{sub 2} in environments simulating those of fission and fusion energy systems. The Division also conducts basic research in catalytic chemistry associated with molecular energy resources and novel` ceramic precursors; materials chemistry of superconducting oxides, electrified metal/solution interfaces, and molecular sieve structures; and the geochemical processes involved in water-rock interactions occurring in active hydrothermal systems. In addition, the Analytical Chemistry Laboratory in CMT provides a broad range of analytical chemistry support services to the technical programs at Argonne National Laboratory (ANL).« less

Department of Energy Technology Readiness Assessments - Process Guide and Training Plan

DTIC Science & Technology

2008-09-12

Hanford Waste Treatment and Immobilization Plant ( WTP ) Analytical Laboratory, Low Activity Waste (LAW) Facility and Balance of Facilities (3 TRAs... WTP High-Level Waste (HLW) Facility – WTP Pre-Treatment (PT) Facility – Hanford River Protection Project Low Activity Waste Treatment Alternatives

A review of mechanochemistry applications in waste management.

PubMed

Guo, Xiuying; Xiang, Dong; Duan, Guanghong; Mou, Peng

2010-01-01

Mechanochemistry is defined to describe the chemical and physicochemical transformation of substances during the aggregation caused by the mechanical energy. Mechanochemical technology has several advantages, such as simple process, ecological safety and the possibility of obtaining a product in the metastable state. It potentially has a prospective application in pollution remediation and waste management. Therefore, this paper aims to give an overall review of the mechanochemistry applications in waste management and the related mechanisms. Based on our study, the modification of fly ash and asbestos-containing wastes (ACWs) can be achieved by mechanochemical technology. Waste metal oxides can be transformed into easily recyclable sulfide by mechanochemical sulfidization. Besides, the waste plastics and rubbers, which are usually very difficult to be recycled, can also be recycled by mechanochemical technology.

Control of Effluent Gases from Solid Waste Processing using Impregnated Carbon Nanotubes

NASA Technical Reports Server (NTRS)

Li, Jing; Fisher, John; Wignarajah, Kanapathipillai

2005-01-01

One of the major problems associated with solid waste processing technologies is effluent contaminants that are released in gaseous forms from the processes. This is a concern in both biological as well as physicochemical solid waste processing. Carbon dioxide (CO2), the major gas released, does not present a serious problem and there are currently in place a number of flight-qualified technologies for CO2 removal. However, a number of other gases, in particular NOx, SO2, NH3, and various hydrocarbons (e.g. CH4) do present health hazards to the crew members in space habitats. In the present configuration of solid waste processing in the International Space Station (ISS), some of these gases are removed by the Trace Contaminant Control System (TCCS), demands a major resupply. Reduction of the resupply can be effective by using catalyst impregnated carbon nanotubes. For example, NO decomposition to N2 and O2 is thermodynamically favored. Data showing decomposition of NO on metal impregnated carbon nanotubes is presented. Comparisons are made of the existing TCCS systems with the carbon nanotube based technology for removing NOx based on mass/energy penalties.

Plasma for environment

NASA Astrophysics Data System (ADS)

Van Oost, G.

2017-12-01

Human activity is associated with the permanent emergence of a very wide range of waste streams. The most widely used treatment of waste is thermal processing such as incineration. An alternative environmentally friendly process is based on thermal plasma technology which is a very flexible tool because it allows to operate in a wide temperature range with almost any chemical composition of waste and chemicals needed for processing this waste. It allows the conversion of organic waste into energy or chemical substances as well as the destruction of toxic organic compounds in a scenario that for each specific type of waste can be considered optimal, both in terms of energy efficiency and environmental safety.

Feedstock recycling program gets go ahead

DOE Office of Scientific and Technical Information (OSTI.GOV)

Layman, P.

1994-03-28

Feedstock recycling--recycling mixed plastics wastes back into chemical feedstocks such as olefins and naphtha--has received a commercial go ahead in Germany. DKR--Deutsche Kunstsoff recycling, a subsidiary of a commercial company, Duales System Deutschland, responsible for recycling packaging wastes in Germany--has issued three contracts to companies with feedstock recycling technology to convert to liquid feedstocks a total of some 500,000 metric tons per year of mixed plastics packaging wastes by 1996. DKR has also pledged to discontinue exports of used plastics packaging to foreign countries by that date. The three contracts go to a consortium between BASF and OTTO Kunststoff service,more » of Dossenheim; the oil and chemical producer Veba; and the electric power utilities company RWE. DKR's current processing costs are about $1,765 per ton of wastes. That total includes all costs for collecting, sorting, cleaning, and transporting the wastes. In its bid, the BASF-OTTO consortium envisioned a fee of about $190 per ton. That fee, says Niess, was determined by looking at BASF's and OTTO's costs, offset by the savings in raw materials BASF would be making as its technology converts mixed plastics wastes to a mixture of naphtha, aromatics, and oils, all of which can be used in BASF's processes in Ludwigshafen. And because BASF's technology requires no presorting or cleaning before it gets the wastes, the process will trim DKR's costs significantly.« less

Analysis on carbon dioxide emission reduction during the anaerobic synergetic digestion technology of sludge and kitchen waste: Taking kitchen waste synergetic digestion project in Zhenjiang as an example.

PubMed

Guo, Qia; Dai, Xiaohu

2017-11-01

With the popularization of municipal sewage treatment facilities, the improvement of sewage treatment efficiency and the deepening degree of sewage treatment, the sludge production of sewage plant has been sharply increased. Carbon emission during the process of municipal sewage treatment and disposal has become one of the important sources of greenhouse gases that cause greenhouse effect. How to reduce carbon dioxide emissions during sewage treatment and disposal process is of great significance for reducing air pollution. Kitchen waste and excess sludge, as two important organic wastes, once uses anaerobic synergetic digestion technology in the treatment process can on the one hand, avoid instability of sludge individual anaerobic digestion, improve sludge degradation rate and marsh gas production rate, and on the other hand, help increase the reduction of carbon dioxide emissions to a great extent. The paper uses material balance method, analyzes and calculates the carbon dioxide emissions from kitchen waste and sludge disposed by the anaerobic synergetic digestion technology, compares the anaerobic synergetic digestion technology with traditional sludge sanitary landfill technology and works out the carbon dioxide emission reductions after synergetic digestion. It takes the kitchen waste and sludge synergetic digestion engineering project of Zhenjiang city in Jiangsu province as an example, makes material balance analysis using concrete data and works out the carbon dioxide daily emission reductions. The paper analyzes the actual situation of emission reduction by comparing the data, and found that the synergetic digestion of kitchen waste and sludge can effectively reduce the carbon dioxide emission, and the reduction is obvious especially compared with that of sludge sanitary landfill, which has a certain effect on whether to promote the use of the technology. Copyright © 2017 Elsevier Ltd. All rights reserved.

Resources in Technology 7.

ERIC Educational Resources Information Center

International Technology Education Association, Reston, VA.

This volume of Resources in Technology contains the following eight instructional modules: (1) "Processing Technology"; (2) "Water--A Magic Resource"; (3) "Hazardous Waste Disposal--The NIMBY (Not in My Backyard) Syndrome"; (4) "Processing Fibers and Fabrics"; (5) "Robotics--An Emerging…

Biofuels from food processing wastes.

PubMed

Zhang, Zhanying; O'Hara, Ian M; Mundree, Sagadevan; Gao, Baoyu; Ball, Andrew S; Zhu, Nanwen; Bai, Zhihui; Jin, Bo

2016-04-01

Food processing industry generates substantial high organic wastes along with high energy uses. The recovery of food processing wastes as renewable energy sources represents a sustainable option for the substitution of fossil energy, contributing to the transition of food sector towards a low-carbon economy. This article reviews the latest research progress on biofuel production using food processing wastes. While extensive work on laboratory and pilot-scale biosystems for energy production has been reported, this work presents a review of advances in metabolic pathways, key technical issues and bioengineering outcomes in biofuel production from food processing wastes. Research challenges and further prospects associated with the knowledge advances and technology development of biofuel production are discussed. Copyright © 2016. Published by Elsevier Ltd.

Anaerobic digestion of municipal solid waste: Technical developments

DOE Office of Scientific and Technical Information (OSTI.GOV)

Rivard, C.J.

1996-01-01

The anaerobic biogasification of organic wastes generates two useful products: a medium-Btu fuel gas and a compost-quality organic residue. Although commercial-scale digestion systems are used to treat municipal sewage wastes, the disposal of solid organic wastes, including municipal solid wastes (MSW), requires a more cost-efficient process. Modern biogasification systems employ high-rate, high-solids fermentation methods to improve process efficiency and reduce capital costs. The design criteria and development stages are discussed. These systems are also compared with conventional low-solids fermentation technology.

Waste: A Hot Item These Days!

ERIC Educational Resources Information Center

Josephson, Julian

1978-01-01

Describes technologies used to conserve energy by using process wastes in the following situations: (1) incineration at a photographic company, (2) wet oxidation at a paper mill, and (3) sewage skimmings fuel at a municipal waste water plant. (MA)

On eco-efficient technologies to minimize industrial water consumption

NASA Astrophysics Data System (ADS)

Amiri, Mohammad C.; Mohammadifard, Hossein; Ghaffari, Ghasem

2016-07-01

Purpose - Water scarcity will further stress on available water systems and decrease the security of water in many areas. Therefore, innovative methods to minimize industrial water usage and waste production are of paramount importance in the process of extending fresh water resources and happen to be the main life support systems in many arid regions of the world. This paper demonstrates that there are good opportunities for many industries to save water and decrease waste water in softening process by substituting traditional with echo-friendly methods. The patented puffing method is an eco-efficient and viable technology for water saving and waste reduction in lime softening process. Design/methodology/approach - Lime softening process (LSP) is a very sensitive process to chemical reactions. In addition, optimal monitoring not only results in minimizing sludge that must be disposed of but also it reduces the operating costs of water conditioning. Weakness of the current (regular) control of LSP based on chemical analysis has been demonstrated experimentally and compared with the eco-efficient puffing method. Findings - This paper demonstrates that there is a good opportunity for many industries to save water and decrease waste water in softening process by substituting traditional method with puffing method, a patented eco-efficient technology. Originality/value - Details of the required innovative works to minimize industrial water usage and waste production are outlined in this paper. Employing the novel puffing method for monitoring of lime softening process results in saving a considerable amount of water while reducing chemical sludge.

Analysis of the energy potential of municipal solid waste for the thermal treatment technology development in Poland

NASA Astrophysics Data System (ADS)

Midor, Katarzyna; Jąderko, Karolina

2017-11-01

The problem of overproduction of waste has been a local issue for many years. Since the new environment law came into effect, the current approach to waste management has changed significantly. The accessible technological possibilities of thermal waste treatment with the energy recovery set a new area of research over the process of choosing effective and rational way of calorific waste management. The objective of this article is to provide assessment results of the analysed energy potential in waste management system in the form of calorific waste stream. In includes all the activities and actions required to manage municipal solid waste from its inception to its final disposal i.e. collection, transport, treatment and disposal. The graphical representation of waste flow indicates the lost opportunities of waste energy recovery. Visual research method was supported and founded on value stream mapping. On the basis of the results were presented the directions of further improvement of calorific waste stream mapping for the purposes of implementation the thermal treatment technology in the selected waste management region.

Anaerobic digestion of food waste - Challenges and opportunities.

PubMed

Xu, Fuqing; Li, Yangyang; Ge, Xumeng; Yang, Liangcheng; Li, Yebo

2018-01-01

The disposal of large amounts of food waste has caused significant environmental pollution and financial costs globally. Compared with traditional disposal methods (i.e., landfilling, incineration, and composting), anaerobic digestion (AD) is a promising technology for food waste management, but has not yet been fully applied due to a few technical and social challenges. This paper summarizes the quantity, composition, and methane potential of various types of food waste. Recent research on different strategies to enhance AD of food waste, including co-digestion, addition of micronutrients, control of foaming, and process design, is discussed. It is envisaged that AD of food waste could be combined with an existing AD facility or be integrated with the production of value-added products to reduce costs and increase revenue. Further understanding of the fundamental biological and physicochemical processes in AD is required to improve the technology. Copyright © 2017 Elsevier Ltd. All rights reserved.

A multi-criteria ranking of different technologies for the anaerobic digestion for energy recovery of the organic fraction of municipal solid wastes.

PubMed

Karagiannidis, A; Perkoulidis, G

2009-04-01

This paper describes a conceptual framework and methodological tool developed for the evaluation of different anaerobic digestion technologies suitable for treating the organic fraction of municipal solid waste, by introducing the multi-criteria decision support method Electre III and demonstrating its related applicability via a test application. Several anaerobic digestion technologies have been proposed over the last years; when compared to biogas recovery from landfills, their advantage is the stability in biogas production and the stabilization of waste prior to final disposal. Anaerobic digestion technologies also show great adaptability to a broad spectrum of different input material beside the organic fraction of municipal solid waste (e.g. agricultural and animal wastes, sewage sludge) and can also be used in remote and isolated communities, either stand-alone or in conjunction to other renewable energy sources. Main driver for this work was the preliminary screening of such methods for potential application in Hellenic islands in the municipal solid waste management sector. Anaerobic digestion technologies follow different approaches to the anaerobic digestion process and also can include production of compost. In the presented multi-criteria analysis exercise, Electre III is implemented for comparing and ranking 5 selected alternative anaerobic digestion technologies. The results of a performed sensitivity analysis are then discussed. In conclusion, the performed multi-criteria approach was found to be a practical and feasible method for the integrated assessment and ranking of anaerobic digestion technologies by also considering different viewpoints and other uncertainties of the decision-making process.

MODIFICATIONS TO REDUCE DRAG OUT AT A PRINTED CIRCUIT BOARD MANUFACTURER

EPA Science Inventory

This MnTAP/EPA Waste Reduction Innovative Technology Evaluation project at Micom, Inc., demonstrated the waste reducing capability of two simple rinsing modifications on an etchant and an electroless copper process. he simple, tow (or no) cost, low technology changes that were ma...

Converting lignocellulosic solid waste into ethanol for the State of Washington: an investigation of treatment technologies and environmental impacts.

PubMed

Schmitt, Elliott; Bura, Renata; Gustafson, Rick; Cooper, Joyce; Vajzovic, Azra

2012-01-01

There is little research literature on the conversion of lignocellulosic rich waste streams to ethanol, and even fewer have investigated both the technical aspects and environmental impacts together. This study assessed technical and environmental challenges of converting three lignocellulosic waste streams to ethanol: municipal solid waste (MSW), low grade mixed waste paper (MWP), and organic yard waste (YW). Experimental results showed high conversion yields for all three streams using suitable conversion methods. Environmental impacts are highly dependent on conversion technology, and process conditions used. Life cycle assessment results showed that both chemicals production and waste collection are important factors to be included within a waste-to-ethanol study. Copyright © 2011 Elsevier Ltd. All rights reserved.

Catalytic methods using molecular oxygen for treatment of PMMS and ECLSS waste streams, volume 2

NASA Technical Reports Server (NTRS)

Akse, James R.

1992-01-01

Catalytic oxidation has proven to be an effective addition to the baseline sorption, ion exchange water reclamation technology which will be used on Space Station Freedom (SSF). Low molecular weight, polar organics such as alcohols, aldehydes, ketones, amides, and thiocarbamides which are poorly removed by the baseline multifiltration (MF) technology can be oxidized to carbon dioxide at low temperature (121 C). The catalytic oxidation process by itself can reduce the Total Organic Carbon (TOC) to below 500 ppb for solutions designed to model these waste waters. Individual challenges by selected contaminants have shown only moderate selectivity towards particular organic species. The combined technology is applicable to the more complex waste water generated in the Process Materials Management System (PMMS) and Environmental Control and Life Support System (ECLSS) aboard SSF. During the phase 3 Core Module Integrated Facility (CMIF) water recovery tests at NASA MSFC, real hygiene waste water and humidity condensate were processed to meet potable specifications by the combined technology. A kinetic study of catalytic oxidation demonstrates that the Langmuir-Hinshelwood rate equation for heterogeneous catalysts accurately represent the kinetic behavior. From this relationship, activation energy and rate constants for acetone were determined.

CONTINUOUS MICRO-SORTING OF COMPLEX WASTE PLASTICS PARTICLEMIXTURES VIA LIQUID-FLUIDIZED BED CLASSIFICATION (LFBC) FOR WASTE MINIMIZATIONAND RECYCLING

EPA Science Inventory

A fundamental investigation is proposed to provide a technical basis for the development of a novel, liquid-fluidized bed classification (LFBC) technology for the continuous separation of complex waste plastic mixtures for in-process recycling and waste minimization. Although ...

Hydrothermal reactions of agricultural and food processing wastes in sub- and supercritical water: a review of fundamentals, mechanisms, and state of research.

PubMed

Pavlovič, Irena; Knez, Željko; Škerget, Mojca

2013-08-28

Hydrothermal (HT) reactions of agricultural and food-processing waste have been proposed as an alternative to conventional waste treatment technologies due to allowing several improvements in terms of process performance and energy and economical advantages, especially due to their great ability to process high moisture content biomass waste without prior dewatering. Complex structures of wastes and unique properties of water at higher temperatures and pressures enable a variety of physical-chemical reactions and a wide spectra of products. This paper's aim is to give extensive information about the fundamentals and mechanisms of HT reactions and provide state of the research of agri-food waste HT conversion.

Hidden flows and waste processing--an analysis of illustrative futures.

PubMed

Schiller, F; Raffield, T; Angus, A; Herben, M; Young, P J; Longhurst, P J; Pollard, S J T

2010-12-14

An existing materials flow model is adapted (using Excel and AMBER model platforms) to account for waste and hidden material flows within a domestic environment. Supported by national waste data, the implications of legislative change, domestic resource depletion and waste technology advances are explored. The revised methodology offers additional functionality for economic parameters that influence waste generation and disposal. We explore this accounting system under hypothetical future waste and resource management scenarios, illustrating the utility of the model. A sensitivity analysis confirms that imports, domestic extraction and their associated hidden flows impact mostly on waste generation. The model offers enhanced utility for policy and decision makers with regard to economic mass balance and strategic waste flows, and may promote further discussion about waste technology choice in the context of reducing carbon budgets.

Application countermeasures of non-incineration technologies for medical waste treatment in China.

PubMed

Chen, Yang; Ding, Qiong; Yang, Xiaoling; Peng, Zhengyou; Xu, Diandou; Feng, Qinzhong

2013-12-01

By the end of 2012, there were 272 modern, high-standard, centralized medical waste disposal facilities operating in various cities in China. Among these facilities nearly 50% are non-incineration treatment facilities, including the technologies of high temperature steam, chemical disinfection and microwave. Each of the non-incineration technologies has its advantages and disadvantages, and any single technology cannot offer a panacea because of the complexity of medical waste disposal. Although non-incineration treatment of medical waste can avoid the release of polychlorinated dibenzo-p-dioxins/dibenzofurans, it is still necessary to decide how to best meet the local waste management needs while minimizing the impact on the environment and public health. There is still a long way to go to establish the sustainable application and management mode of non-incineration technologies. Based on the analysis of typical non-incineration process, pollutant release, and the current tendency for technology application and development at home and abroad, this article recommends the application countermeasures of non-incineration technologies as the best available techniques and best environmental practices in China.

Technology Catalogue. First edition

DOE Office of Scientific and Technical Information (OSTI.GOV)

Not Available

1994-02-01

The Department of Energy`s Office of Environmental Restoration and Waste Management (EM) is responsible for remediating its contaminated sites and managing its waste inventory in a safe and efficient manner. EM`s Office of Technology Development (OTD) supports applied research and demonstration efforts to develop and transfer innovative, cost-effective technologies to its site clean-up and waste management programs within EM`s Office of Environmental Restoration and Office of Waste Management. The purpose of the Technology Catalogue is to provide performance data on OTD-developed technologies to scientists and engineers assessing and recommending technical solutions within the Department`s clean-up and waste management programs, asmore » well as to industry, other federal and state agencies, and the academic community. OTD`s applied research and demonstration activities are conducted in programs referred to as Integrated Demonstrations (IDs) and Integrated Programs (IPs). The IDs test and evaluate.systems, consisting of coupled technologies, at specific sites to address generic problems, such as the sensing, treatment, and disposal of buried waste containers. The IPs support applied research activities in specific applications areas, such as in situ remediation, efficient separations processes, and site characterization. The Technology Catalogue is a means for communicating the status. of the development of these innovative technologies. The FY93 Technology Catalogue features technologies successfully demonstrated in the field through IDs and sufficiently mature to be used in the near-term. Technologies from the following IDs are featured in the FY93 Technology Catalogue: Buried Waste ID (Idaho National Engineering Laboratory, Idaho); Mixed Waste Landfill ID (Sandia National Laboratories, New Mexico); Underground Storage Tank ID (Hanford, Washington); Volatile organic compound (VOC) Arid ID (Richland, Washington); and VOC Non-Arid ID (Savannah River Site, South Carolina).« less

Efficient use of shrimp waste: present and future trends.

PubMed

Kandra, Prameela; Challa, Murali Mohan; Jyothi, Hemalatha Kalangi Padma

2012-01-01

The production of shrimp waste from shrimp processing industries has undergone a dramatic increase in recent years. Continued production of this biomaterial without corresponding development of utilizing technology has resulted in waste collection, disposal, and pollution problems. Currently used chemical process releases toxic chemicals such as HCl, acetic acid, and NaOH into aquatic ecosystem as byproducts which will spoil the aquatic flora and fauna. Environmental protection regulations have become stricter. Now, there is a need to treat and utilize the waste in most efficient manner. The shrimp waste contains several bioactive compounds such as chitin, pigments, amino acids, and fatty acids. These bioactive compounds have a wide range of applications including medical, therapies, cosmetics, paper, pulp and textile industries, biotechnology, and food applications. This current review article present the utilization of shrimp waste as well as an alternative technology to replace hazardous chemical method that address the future trends in total utilization of shrimp waste for recovery of bioactive compounds.

SURVEY OF SOLIDIFICATION/STABILIZATION TECHNOLOGY FOR HAZARDOUS INDUSTRIAL WASTES

EPA Science Inventory

Stabilization/solidification or fixation is a process for treating industrial solid wastes (primarily sludges) that contain hazardous constituents to prevent dissolution and loss of toxic materials into the environment. Most of these treatment processes are designed to produce a ...

DOE Office of Scientific and Technical Information (OSTI.GOV)

Braase, Lori

Develop advanced nuclear fuel cycle separation and waste management technologies that improve current fuel cycle performance and enable a sustainable fuel cycle, with minimal processing, waste generation, and potential for material diversion.

Laser ablation/ionization characterization of solids: Second interim progress report of the strategic environmental research development program

DOE Office of Scientific and Technical Information (OSTI.GOV)

Hess, W.P.; Bushaw, B.A.; McCarthy, M.I.

1996-10-01

The Department of Energy is undertaking the enormous task of remediating defense wastes and environmental insults which have occurred over 50 years of nuclear weapons production. It is abundantly clear that significant technology advances are needed to characterize, process, and store highly radioactive waste and to remediate contaminated zones. In addition to the processing and waste form issues, analytical technologies needed for the characterization of solids, and for monitoring storage tanks and contaminated sites do not exist or are currently expensive labor-intensive tasks. This report describes progress in developing sensitive, rapid, and widely applicable laser-based mass spectrometry techniques for analysismore » of mixed chemical wastes and contaminated soils.« less

Processing industrial wastes with the liquid-phase reduction romelt process

NASA Astrophysics Data System (ADS)

Romenets, V.; Valavin, V.; Pokhvisnev, Yu.; Vandariev, S.

1999-08-01

The Romelt technology for liquid-phase reduction has been developed for processing metallurgical wastes containing nonferrousmetal components. Thermodynamic calculations were made to investigate the behavior of silver, copper, zinc, manganese, vanadium, chrome, and silicon when reduced from the slag melt into the metallic solution containing iron. The process can be applied to all types of iron-bearing wastes, including electric arc furnace dust. The distribution of elements between the phases can be controlled by adjusting the slag bath temperature. Experiments at a pilot Romelt plant proved the possibility of recovering the metallurgical wastes and obtaining iron.

Stabilization and disposal of Argonne-West low-level mixed wastes in ceramicrete waste forms.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Barber, D. B.; Singh, D.; Strain, R. V.

1998-02-17

The technology of room-temperature-setting phosphate ceramics or Ceramicrete{trademark} technology, developed at Argonne National Laboratory (ANL)-East is being used to treat and dispose of low-level mixed wastes through the Department of Energy complex. During the past year, Ceramicrete{trademark} technology was implemented for field application at ANL-West. Debris wastes were treated and stabilized: (a) Hg-contaminated low-level radioactive crushed light bulbs and (b) low-level radioactive Pb-lined gloves (part of the MWIR {number_sign} AW-W002 waste stream). In addition to hazardous metals, these wastes are contaminated with low-level fission products. Initially, bench-scale waste forms with simulated and actual waste streams were fabricated by acid-base reactionsmore » between mixtures of magnesium oxide powders and an acid phosphate solution, and the wastes. Size reduction of Pb-lined plastic glove waste was accomplished by cryofractionation. The Ceramicrete{trademark} process produces dense, hard ceramic waste forms. Toxicity Characteristic Leaching Procedure (TCLP) results showed excellent stabilization of both Hg and Pb in the waste forms. The principal advantage of this technology is that immobilization of contaminants is the result of both chemical stabilization and subsequent microencapsulation of the reaction products. Based on bench-scale studies, Ceramicrete{trademark} technology has been implemented in the fabrication of 5-gal waste forms at ANL-West. Approximately 35 kg of real waste has been treated. The TCLP is being conducted on the samples from the 5-gal waste forms. It is expected that because the waste forms pass the limits set by the EPAs Universal Treatment Standard, they will be sent to a radioactive-waste disposal facility.« less

Integration of National Laboratory and Low-Activity Waste Pre-Treatment System Technology Service Providers - 16435

DOE Office of Scientific and Technical Information (OSTI.GOV)

Subramanian, Karthik H.; Thien, Michael G.; Wellman, Dawn M.

The National Laboratories are a critical partner and provide expertise in numerous aspects of the successful execution of the Direct-Feed Low Activity Waste Program. The National Laboratories are maturing the technologies of the Low-Activity Waste Pre-Treatment System (LAWPS) consistent with DOE Order 413.3B “Program and Project Management for the Acquisition of Capital Assets” expectations. The National Laboratories continue to mature waste forms, i.e. glass and secondary waste grout, for formulations and predictions of long-term performance as inputs to performance assessments. The working processes with the National Laboratories have been developed in procurements, communications, and reporting to support the necessary delivery-basedmore » technology support. The relationship continues to evolve from planning and technology development to support of ongoing operations and integration of multiple highly coordinated facilities.« less

Microwave as an emerging technology for the treatment of biohazardous waste: A mini-review.

PubMed

Zimmermann, Klaus

2017-05-01

Microwave is an emerging technology to treat biohazardous waste, including material from healthcare facilities. A screen of the peer-reviewed literature shows that only limited information may be found in this area of work and, furthermore, analysis of the references reveals that sometimes not all necessary aspects for the appropriate use of the technology are considered. Very often conventional microwave technology is applied for the inactivation of pathogens, which might make sense for certain applications but, on the other hand, may lead to the misbelief that microwave systems cannot be used for the inactivation of a solid "dry" waste. However, conventional microwave units have no means to control the inactivation process, and especially moisture content. But there are a few sophisticated microwave technologies with appropriate measurements allowing a validated inactivation of biohazardous materials. These technologies are an effective tool for inactivation and some of them are commercially available. It must also be considered that the waste should be preferably inactivated either directly at the place where it is generated or biohazardous waste should be transported only in closed systems. Moreover, microwave technology presents a possibility to save energy costs in comparison to the more widely used autoclaves. This mini-review will discuss important aspects for the use of microwave technology for the treatment of biohazardous waste.

[Purification of complicated industrial organic waste gas by complex absorption].

PubMed

Chen, Ding-Sheng; Cen, Chao-Ping; Tang, Zhi-Xiong; Fang, Ping; Chen, Zhi-Hang

2011-12-01

Complicated industrial organic waste gas with the characteristics of low concentration,high wind volume containing inorganic dust and oil was employed the research object by complex absorption. Complex absorption mechanism, process flow, purification equipment and engineering application were studied. Three different surfactants were prepared for the composite absorbent to purify exhaust gas loaded with toluene and butyl acetate, respectively. Results show that the low surface tension of the composite absorbent can improve the removal efficiency of toluene and butyl acetate. With the advantages of the water film, swirl plate and fill absorption device, efficient absorption equipment was developed for the treatment of complicated industrial organic waste gas. It is with superiorities of simple structure, small size, anti-jam and high mass transfer. Based on absorption technology, waste gas treatment process integrated with heating stripping, burning and anaerobic and other processes, so that emissions of waste gas and absorption solution could meet the discharge standards. The technology has been put into practice, such as manufacturing and spraying enterprises.

Active and passive computed tomography mixed waste focus area final report

DOE Office of Scientific and Technical Information (OSTI.GOV)

Roberson, G P

1998-08-19

The Mixed Waste Focus Area (MWFA) Characterization Development Strategy delineates an approach to resolve technology deficiencies associated with the characterization of mixed wastes. The intent of this strategy is to ensure the availability of technologies to support the Department of Energy's (DOE) mixed waste low-level or transuranic (TRU) contaminated waste characterization management needs. To this end the MWFA has defined and coordinated characterization development programs to ensure that data and test results necessary to evaluate the utility of non-destructive assay technologies are available to meet site contact handled waste management schedules. Requirements used as technology development project benchmarks are basedmore » in the National TRU Program Quality Assurance Program Plan. These requirements include the ability to determine total bias and total measurement uncertainty. These parameters must be completely evaluated for waste types to be processed through a given nondestructive waste assay system constituting the foundation of activities undertaken in technology development projects. Once development and testing activities have been completed, Innovative Technology Summary Reports are generated to provide results and conclusions to support EM-30, -40, or -60 end user/customer technology selection. The Active and Passive Computed Tomography non-destructive assay system is one of the technologies selected for development by the MWFA. Lawrence Livermore National Laboratory's (LLNL) is developing the Active and Passive Computed Tomography (A&PCT) nondestructive assay (NDA) technology to identify and accurately quantify all detectable radioisotopes in closed containers of waste. This technology will be applicable to all types of waste regardless of .their classification; low level, transuranic or provide results and conclusions to support EM-30, -40, or -60 end user/customer technology selection. The Active and Passive Computed Tomography non-destructive assay system is one of the technologies selected for development by the MWFA. Lawrence Livermore National Laboratory's (LLNL) is developing the Active and Passive Computed Tomography (A&PCT) nondestructive assay (NDA) technology to identify and accurately quantify all detectable radioisotopes in closed containers of waste. This technology will be applicable to all types of waste regardless of .their classification; low level, transuranic or mixed, which contains radioactivity and hazardous organic species. The scope of our technology is to develop a non-invasive waste-drum scanner that employs the principles of computed tomography and gamma-ray spectral analysis to identify and quantify all of the detectable radioisotopes. Once this and other applicable technologies are developed, waste drums can be non- destructively and accurately characterized to satisfy repository and regulatory guidelines prior to disposal.« less

Liquid secondary waste. Waste form formulation and qualification

DOE Office of Scientific and Technical Information (OSTI.GOV)

Cozzi, A. D.; Dixon, K. L.; Hill, K. A.

The Hanford Site Effluent Treatment Facility (ETF) currently treats aqueous waste streams generated during Site cleanup activities. When the Hanford Tank Waste Treatment and Immobilization Plant (WTP) begins operations, a liquid secondary waste (LSW) stream from the WTP will need to be treated. The volume of effluent for treatment at the ETF will increase significantly. Washington River Protection Solutions is implementing a Secondary Liquid Waste Immobilization Technology Development Plan to address the technology needs for a waste form and solidification process to treat the increased volume of waste planned for disposal at the Integrated Disposal Facility IDF). Waste form testingmore » to support this plan is composed of work in the near term to demonstrate the waste form will provide data as input to a performance assessment (PA) for Hanford’s IDF.« less

Chemical Technology Division, Annual technical report, 1991

DOE Office of Scientific and Technical Information (OSTI.GOV)

Not Available

1992-03-01

Highlights of the Chemical Technology (CMT) Division's activities during 1991 are presented. In this period, CMT conducted research and development in the following areas: (1) electrochemical technology, including advanced batteries and fuel cells; (2) technology for fluidized-bed combustion and coal-fired magnetohydrodynamics; (3) methods for treatment of hazardous and mixed hazardous/radioactive waste; (4) the reaction of nuclear waste glass and spent fuel under conditions expected for an unsaturated repository; (5) processes for separating and recovering transuranic elements from nuclear waste streams; (6) recovery processes for discharged fuel and the uranium blanket in the Integral Fast Reactor (IFR); (7) processes for removalmore » of actinides in spent fuel from commercial water-cooled nuclear reactors and burnup in IFRs; and (8) physical chemistry of selected materials in environments simulating those of fission and fusion energy systems. The Division also conducts basic research in catalytic chemistry associated with molecular energy resources; chemistry of superconducting oxides and other materials of interest with technological application; interfacial processes of importance to corrosion science, catalysis, and high-temperature superconductivity; and the geochemical processes involved in water-rock interactions occurring in active hydrothermal systems. In addition, the Analytical Chemistry Laboratory in CMT provides a broad range of analytical chemistry support services to the technical programs at Argonne National Laboratory (ANL).« less

Chemical Technology Division, Annual technical report, 1991

DOE Office of Scientific and Technical Information (OSTI.GOV)

Not Available

1992-03-01

Highlights of the Chemical Technology (CMT) Division`s activities during 1991 are presented. In this period, CMT conducted research and development in the following areas: (1) electrochemical technology, including advanced batteries and fuel cells; (2) technology for fluidized-bed combustion and coal-fired magnetohydrodynamics; (3) methods for treatment of hazardous and mixed hazardous/radioactive waste; (4) the reaction of nuclear waste glass and spent fuel under conditions expected for an unsaturated repository; (5) processes for separating and recovering transuranic elements from nuclear waste streams; (6) recovery processes for discharged fuel and the uranium blanket in the Integral Fast Reactor (IFR); (7) processes for removalmore » of actinides in spent fuel from commercial water-cooled nuclear reactors and burnup in IFRs; and (8) physical chemistry of selected materials in environments simulating those of fission and fusion energy systems. The Division also conducts basic research in catalytic chemistry associated with molecular energy resources; chemistry of superconducting oxides and other materials of interest with technological application; interfacial processes of importance to corrosion science, catalysis, and high-temperature superconductivity; and the geochemical processes involved in water-rock interactions occurring in active hydrothermal systems. In addition, the Analytical Chemistry Laboratory in CMT provides a broad range of analytical chemistry support services to the technical programs at Argonne National Laboratory (ANL).« less

PROCESS DEVELOPMENT FOR THE RECOVERY OF CRITICAL MATERIALS FROM ELECTRONIC WASTE

DOE Office of Scientific and Technical Information (OSTI.GOV)

Lister, T. E.; Diaz, L. A.; Clark, G. G.

As electronic technology continues to evolve there is a growing need to develop processes which recover valuable material from antiquated technology. This need follows from the environmental challenges associated with the availability of raw materials and fast growing generation of electronic waste. Although just present in small quantities in electronic devices, the availability of raw materials, such as rare earths and precious metals, becomes critical for the production of high tech electronic devices and the development of green technologies (i.e. wind turbines, electric motors, and solar panels). Therefore, the proper recycling and processing of increasing volumes of electronic waste presentmore » an opportunity to stabilize the market of critical materials, reducing the demand of mined products, and providing a proper disposal and treatment of a hazardous waste stream. This paper will describe development and techno-economic assessment of a comprehensive process for the recovery of value and critical materials from electronic waste. This hydrometallurgical scheme aims to selectively recover different value segments in the materials streams (base metals, precious metals, and rare earths). The economic feasibility for the recovery of rare earths from electronic waste is mostly driven by the efficient recovery of precious metals, such as Au and Pd (ca. 80 % of the total recoverable value). Rare earth elements contained in magnets (speakers, vibrators and hard disk storage) can be recovered as a mixture of rare earths oxides which can later be reduced to the production of new magnets.« less

Data summary of municipal solid waste management alternatives. Volume 3, Appendix A: Mass burn technologies

DOE Office of Scientific and Technical Information (OSTI.GOV)

None

This appendix on Mass Burn Technologies is the first in a series designed to identify, describe and assess the suitability of several currently or potentially available generic technologies for the management of municipal solid waste (MSW). These appendices, which cover eight core thermoconversion, bioconversion and recycling technologies, reflect public domain information gathered from many sources. Representative sources include: professional journal articles, conference proceedings, selected municipality solid waste management plans and subscription technology data bases. The information presented is intended to serve as background information that will facilitate the preparation of the technoeconomic and life cycle mass, energy and environmental analysesmore » that are being developed for each of the technologies. Mass burn has been and continues to be the predominant technology in Europe for the management of MSW. In the United States, the majority of the existing waste-to-energy projects utilize this technology and nearly 90 percent of all currently planned facilities have selected mass burn systems. Mass burning generally refers to the direct feeding and combustion of municipal solid waste in a furnace without any significant waste preprocessing. The only materials typically removed from the waste stream prior to combustion are large bulky objects and potentially hazardous or undesirable wastes. The technology has evolved over the last 100 or so years from simple incineration to the most highly developed and commercially proven process available for both reducing the volume of MSW and for recovering energy in the forms of steam and electricity. In general, mass burn plants are considered to operate reliably with high availability.« less

Microbial utilisation of natural organic wastes.

PubMed

Ilyin, V K; Smirnov, I A; Soldatov, P E; Korniushenkova, I N; Grinin, A S; Lykov, I N; Safronova, S A

2004-03-01

The waste management strategy for the future should meet the benefits of humanity safety, respect principals of planet ecology, and compatibility with other habitability systems. For these purpose the waste management technologies, relevant to application of the biodegradation properties of bacteria are of great value. The biological treatment method is based upon the biodegradation of organic substances by various microorganisms. The advantage of the biodegradation waste management in general: it allows to diminish the volume of organic wastes, the biological hazard of the wastes is controlled, and this system may be compatible with the other systems. The objectives of our study were: to evaluate effectiveness of microbial biodegradation of non-pretreated substrate, to construct phneumoautomatic digester for organic wastes biodegradation, and to study microbial characteristics of active sludge samples used as inoculi in biodegradation experiment. The technology of vegetable wastes treatment was elaborated in IBMP and BMSTU. For this purpose the special unit was created where the degradation process is activated by enforced reinvention of portions of elaborated biogas into digester. This technology allows to save energy normally used for electromechanical agitation and to create optimal environment for anaerobic bacteria growth. The investigations were performed on waste simulator, which imitates physical and chemical content of food wastes calculated basing on the data on food wastes of moderate Russian city. The volume of created experimental sample of digester is 40 l. The basic system elements of device are digesters, gas receiver, remover of drops and valve monitoring and thermal control system. In our testing we used natural food wastes to measure basic parameters and time of biodegradation process. The diminution rate of organic gained 76% from initial mass taking part within 9 days of fermentation. The biogas production achieved 46 l per 1 kg of substrate. The microbial studies of biodegradation process revealed following peculiarities: (i) gradual quantitative increasing of Lactobacillus sp. (from 10(3) to 10(5) colony forming units (CFU) per ml), (ii) activation of Clostridia sp. (from 10(2) to 10(4)CFU/ml), (iii) elimination of aerobic conventional pathogens (Enterobacteriaceae sp., Protea sp., staphylococci). The obtained results allow to evaluate effectiveness of proposed technology and to determine the leading role of lactobacilli and clostridia in process of natural wastes biodegradation. Our further investigations shall further be concentrated on creation of artificial inoculi for launching of food wastes biodegradation. These inoculi will include active and adapted strains of clostridia and lactobacilli. c2003 Elsevier Ltd. All rights reserved.

Strategic Minimization of High Level Waste from Pyroprocessing of Spent Nuclear Fuel

DOE Office of Scientific and Technical Information (OSTI.GOV)

Simpson, Michael F.; Benedict, Robert W.

The pyroprocessing of spent nuclear fuel results in two high-level waste streams--ceramic and metal waste. Ceramic waste contains active metal fission product-loaded salt from the electrorefining, while the metal waste contains cladding hulls and undissolved noble metals. While pyroprocessing was successfully demonstrated for treatment of spent fuel from Experimental Breeder Reactor-II in 1999, it was done so without a specific objective to minimize high-level waste generation. The ceramic waste process uses “throw-away” technology that is not optimized with respect to volume of waste generated. In looking past treatment of EBR-II fuel, it is critical to minimize waste generation for technologymore » developed under the Global Nuclear Energy Partnership (GNEP). While the metal waste cannot be readily reduced, there are viable routes towards minimizing the ceramic waste. Fission products that generate high amounts of heat, such as Cs and Sr, can be separated from other active metal fission products and placed into short-term, shallow disposal. The remaining active metal fission products can be concentrated into the ceramic waste form using an ion exchange process. It has been estimated that ion exchange can reduce ceramic high-level waste quantities by as much as a factor of 3 relative to throw-away technology.« less

Current Development in Treatment and Hydrogen Energy Conversion of Organic Solid Waste

NASA Astrophysics Data System (ADS)

Shin, Hang-Sik

2008-02-01

This manuscript summarized current developments on continuous hydrogen production technologies researched in Korea advanced institute of science and technology (KAIST). Long-term continuous pilot-scale operation of hydrogen producing processes fed with non-sterile food waste exhibited successful results. Experimental findings obtained by the optimization processes of growth environments for hydrogen producing bacteria, the development of high-rate hydrogen producing strategies, and the feasibility tests for real field application could contribute to the progress of fermentative hydrogen production technologies. Three major technologies such as controlling dilution rate depending on the progress of acidogenesis, maintaining solid retention time independently from hydraulic retention time, and decreasing hydrogen partial pressure by carbon dioxide sparging could enhance hydrogen production using anaerobic leaching beds reactors and anaerobic sequencing batch reactors. These findings could contribute to stable, reliable and effective performances of pilot-scale reactors treating organic wastes.

Composting technology in waste stabilization: On the methods, challenges and future prospects.

PubMed

Onwosi, Chukwudi O; Igbokwe, Victor C; Odimba, Joyce N; Eke, Ifeanyichukwu E; Nwankwoala, Mary O; Iroh, Ikemdinachi N; Ezeogu, Lewis I

2017-04-01

Composting technology has become invaluable in stabilization of municipal waste due to its environmental compatibility. In this review, different types of composting methods reportedly applied in waste management were explored. Further to that, the major factors such as temperature, pH, C/N ratio, moisture, particle size that have been considered relevant in the monitoring of the composting process were elucidated. Relevant strategies to improve and optimize process effectiveness were also addressed. However, during composting, some challenges such as leachate generation, gas emission and lack of uniformity in assessing maturity indices are imminent. Here in, these challenges were properly addressed and some strategies towards ameliorating them were proffered. Finally, we highlighted some recent technologies that could improve composting. Copyright © 2016 Elsevier Ltd. All rights reserved.

Technologies for ECLSS Evolution

NASA Technical Reports Server (NTRS)

Diamant, Bryce L.

1990-01-01

Viewgraphs and discussion on technologies for Environmental Control and Life Support System (ECLSS) evolution are presented. Topics covered include: atmosphere revitalization including CO2 removal, CO2 reduction, O2 generation, and trace contaminant control; water recovery and management including urine processing, hygiene water processing, and potable water processing; and waste management. ECLSS technology schematics, process diagrams, and fluid interfaces are included.

Solid Waste: Resource Recovery and Reuse

ERIC Educational Resources Information Center

Bernardo, James V.

1973-01-01

Discusses some of the processes involved in resource recovery (recycling) from municipal solid wastes. Provides specific examples of recovery of valuable resources, and suggests that the environmental consequences and technology related to solid waste treatment should be included in high school science courses. (JR)

Decontamination and disposal of PCB wastes.

PubMed Central

Johnston, L E

1985-01-01

Decontamination and disposal processes for PCB wastes are reviewed. Processes are classed as incineration, chemical reaction or decontamination. Incineration technologies are not limited to the rigorous high temperature but include those where innovations in use of oxident, heat transfer and residue recycle are made. Chemical processes include the sodium processes, radiant energy processes and low temperature oxidations. Typical processing rates and associated costs are provided where possible. PMID:3928363

Critical Materials Needs

DTIC Science & Technology

1975-05-01

Waste-to-energy systems Recycling of materials from refuse Desulfurization of flue gases from electric power plants Sattelle Specialists...High-Temperature Gas -Turbine Engines for Automotive Applications Initiation of Task II and Task III (Task II: Description of Technologies and...3 - • Mining and Minerals Processing • Ocean Engineering • Transportation • Waste Treatment and Environmental Control The technologies

Critical analysis of pyrolysis process with cellulosic based municipal waste as renewable source in energy and technical perspective.

PubMed

Agarwal, Manu; Tardio, James; Venkata Mohan, S

2013-11-01

To understand the potential of cellulosic based municipal waste as a renewable feed-stock, application of pyrolysis by biorefinery approach was comprehensively studied for its practicable application towards technical and environmental viability in Indian context. In India, where the energy requirements are high, the pyrolysis of the cellulosic waste shows numerous advantages for its applicability as a potential waste-to-energy technology. The multiple energy outputs of the process viz., bio-gas, bio-oil and bio-char can serve the two major energy sectors, viz., electricity and transportation. The process suits best for high bio-gas and electrical energy production when energy input is satisfied from bio-char in form of steam (scheme-1). The bio-gas generated through the process shows its direct utility as a transportation fuel while the bio-oil produced can serve as fuel or raw material to chemical synthesis. On a commercial scale the process is a potent technology towards sustainable development. The process is self-sustained when operated on a continuous mode. Copyright © 2013 Elsevier Ltd. All rights reserved.

Solid Waste Processing: An Essential Technology for the Early Phases of Mars Exploration and Colonization

NASA Technical Reports Server (NTRS)

Wignarajah, Kanapathipillai; Pisharody, Suresh; Fisher, John; Flynn, Michael; Kliss, Mark (Technical Monitor)

1997-01-01

Terraforming of Mars is the long-term goal of colonization of Mars. However, this process is likely to be a very slow process and conservative estimates involving a synergic, technocentric approach estimate that it may take around 10,000 years before the planet can be parallel to that of Earth and where humans can live in open systems. Hence, any early missions will require the presence of a closed life support system where all wastes, both solids and liquids, will need to be recycled or where all consumables will need to be supplied. The economics of both are often a matter of speculation and conjecture, but some attempt is made here to evaluate the choice. If a choice is made to completely resupply and eject the waste mass, a number of unknown issues are at hand. On the other hand, processing of the wastes, will enable predictability and reliability of the ecosystem. Solid wastes though smaller in volume and mass than the liquid wastes contains more than 90% of the essential elements required by humans and plants. Further, if left unprocessed they present a serious risk to human health. This paper presents the use of well established technology in processing solid wastes, ensuring that the biogeochemical cycles of ecosystems are maintained, reliability of the closed life support system maintained and the establishment of the early processes necessary for the permanent presence of humans on Mars.

Bioremediation of Industrial Waste Through Enzyme Producing Marine Microorganisms.

PubMed

Sivaperumal, P; Kamala, K; Rajaram, R

Bioremediation process using microorganisms is a kind of nature-friendly and cost-effective clean green technology. Recently, biodegradation of industrial wastes using enzymes from marine microorganisms has been reported worldwide. The prospectus research activity in remediation area would contribute toward the development of advanced bioprocess technology. To minimize industrial wastes, marine enzymes could constitute a novel alternative in terms of waste treatment. Nowadays, the evidence on the mechanisms of bioremediation-related enzymes from marine microorganisms has been extensively studied. This review also will provide information about enzymes from various marine microorganisms and their complexity in the biodegradation of comprehensive range of industrial wastes. © 2017 Elsevier Inc. All rights reserved.

Ground Water Issue: Phytoremediation of Contaminated Soil and Ground Water at Hazardous Waste Sites

DTIC Science & Technology

2001-02-01

Development Ground Water Issue Phytoremediation of Contaminated Soil and Ground Water at Hazardous Waste Sites National Risk Management Research... Phytoremediation , the use of plants in remediation, is one such technology. This issue paper focuses on the processes and applications of phytoremediation ...of phytoremediation as a cleanup or containment technique for remediation of hazardous waste sites. Introductory material on plant processes is

Assessment of the greenhouse effect impact of technologies used for energy recovery from municipal waste: a case for England.

PubMed

Papageorgiou, A; Barton, J R; Karagiannidis, A

2009-07-01

Waste management activities contribute to global greenhouse gas emissions approximately by 4%. In particular the disposal of waste in landfills generates methane that has high global warming potential. Effective mitigation of greenhouse gas emissions is important and could provide environmental benefits and sustainable development, as well as reduce adverse impacts on public health. The European and UK waste policy force sustainable waste management and especially diversion from landfill, through reduction, reuse, recycling and composting, and recovery of value from waste. Energy from waste is a waste management option that could provide diversion from landfill and at the same time save a significant amount of greenhouse gas emissions, since it recovers energy from waste which usually replaces an equivalent amount of energy generated from fossil fuels. Energy from waste is a wide definition and includes technologies such as incineration of waste with energy recovery, or combustion of waste-derived fuels for energy production or advanced thermal treatment of waste with technologies such as gasification and pyrolysis, with energy recovery. The present study assessed the greenhouse gas emission impacts of three technologies that could be used for the treatment of Municipal Solid Waste in order to recover energy from it. These technologies are Mass Burn Incineration with energy recovery, Mechanical Biological Treatment via bio-drying and Mechanical Heat Treatment, which is a relatively new and uninvestigated method, compared to the other two. Mechanical Biological Treatment and Mechanical Heat Treatment can turn Municipal Solid Waste into Solid Recovered Fuel that could be combusted for energy production or replace other fuels in various industrial processes. The analysis showed that performance of these two technologies depends strongly on the final use of the produced fuel and they could produce GHG emissions savings only when there is end market for the fuel. On the other hand Mass Burn Incineration generates greenhouse gas emission savings when it recovers electricity and heat. Moreover the study found that the expected increase on the amount of Municipal Solid Waste treated for energy recovery in England by 2020 could save greenhouse gas emission, if certain Energy from Waste technologies would be applied, under certain conditions.

Modern technologies of processing municipal solid waste: investing in the future

NASA Astrophysics Data System (ADS)

Rumyantseva, A.; Berezyuk, M.; Savchenko, N.; Rumyantseva, E.

2017-06-01

The problem of effective municipal solid waste (MSW) management is known to all the municipal entities of the Russian Federation. The problem is multifaceted and complex. The article analyzes the dynamics of municipal solid waste formation and its utilization within the territory of the EU and Russia. The authors of the paper suggest a project of a plant for processing municipal solid waste into a combustible gas with the help of high temperature pyrolysis. The main indicators of economic efficiency are calculated.

Impact of diet on the design of waste processors in CELSS

NASA Technical Reports Server (NTRS)

Waleh, Ahmad; Kanevsky, Valery; Nguyen, Thoi K.; Upadhye, Ravi; Wydeven, Theodore

1991-01-01

The preliminary results of a design analysis for a waste processor which employs existing technologies and takes into account the constraints of human diet are presented. The impact of diet is determined by using a model and an algorithm developed for the control and management of diet in a Controlled Ecological Life Support System (CELSS). A material and energy balance model for thermal oxidation of waste is developed which is consistent with both physical/chemical methods of incineration and supercritical water oxidation. The two models yield quantitative analysis of the diet and waste streams and the specific design parameters for waste processors, respectively. The results demonstrate that existing technologies can meet the demands of waste processing, but the choice and design of the processors or processing methods will be sensitive to the constraints of diet. The numerical examples are chosen to display the nature and extent of the gap in the available experiment information about CELSS requirements.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Marra, James; Kim, Dong -Sang; Maio, Vincent

A number of waste components in US defense high level radioactive wastes (HLW) have proven challenging for current Joule heated ceramic melter (JHCM) operations and have limited the ability to increase waste loadings beyond already realized levels. Many of these “troublesome" waste species cause crystallization in the glass melt that can negatively impact product quality or have a deleterious effect on melter processing. Recent efforts at US Department of Energy laboratories have focused on understanding crystallization behavior within HLW glass melts and investigating approaches to mitigate the impacts of crystallization so that increases in waste loading can be realized. Advancedmore » glass formulations have been developed to highlight the unique benefits of next-generation melter technologies such as the Cold Crucible Induction Melter (CCIM). Crystal-tolerant HLW glasses have been investigated to allow sparingly soluble components such as chromium to crystallize in the melter but pass out of the melter before accumulating.The Hanford site AZ-101 tank waste composition represents a waste group that is waste loading limited primarily due to high concentrations of Fe 2O 3 (also with high Al 2O 3 concentrations). Systematic glass formulation development utilizing slightly higher process temperatures and higher tolerance to spinel crystals demonstrated that an increase in waste loading of more than 20% could be achieved for this waste composition, and by extension higher loadings for wastes in the same group. An extended duration CCIM melter test was conducted on an AZ-101 waste simulant using the CCIM platform at the Idaho National Laboratory (INL). The melter was continually operated for approximately 80 hours demonstrating that the AZ-101 high waste loading glass composition could be readily processed using the CCIM technology. The resulting glass was close to the targeted composition and exhibited excellent durability in both the as poured state and after being slowly cooled according to the canister centerline cooling (CCC) profile. Glass formulation development was also completed on other Hanford tank wastes that were identified to further challenge waste loading due to the presence of appreciable quantities (>750 g) of plutonium in the waste tanks. In addition to containing appreciable Pu quantities, the C-102 waste tank and the 244-TX waste tank contain high concentrations of aluminum and iron, respectively that will further challenge vitrification processing. Glass formulation testing also demonstrated that high waste loadings could be achieved with these tank compositions using the attributes afforded by the CCIM technology.« less

Triboelectrostatic separation for granular plastic waste recycling: a review.

PubMed

Wu, Guiqing; Li, Jia; Xu, Zhenming

2013-03-01

The world's plastic consumption has increased incredibly in recent decades, generating more and more plastic waste, which makes it a great public concern. Recycling is the best treatment for plastic waste since it cannot only reduce the waste but also reduce the consumption of oil for producing new virgin plastic. Mechanical recycling is recommended for plastic waste to avoid the loss of its virgin value. As a mechanical separation technology, triboelectrostatic separation utilizes the difference between surface properties of different materials to get them oppositely charged, deflected in the electric field and separately collected. It has advantages such as high efficiency, low cost, no concern of water disposal or secondary pollution and a relatively wide processing range of particle size especially suitable for the granular plastic waste. The process of triboelectrostatic separation for plastic waste is reviewed in this paper. Different devices have been developed and proven to be effective for separation of plastic waste. The influence factors are also discussed. It can be concluded that the triboelectrostatic separation of plastic waste is a promising technology. However, more research is required before it can be widely applied in industry. Copyright © 2012 Elsevier Ltd. All rights reserved.

Commercial Submersible Mixing Pump For SRS Tank Waste Removal - 15223

DOE Office of Scientific and Technical Information (OSTI.GOV)

Hubbard, Mike; Herbert, James E.; Scheele, Patrick W.

The Savannah River Site Tank Farms have 45 active underground waste tanks used to store and process nuclear waste materials. There are 4 different tank types, ranging in capacity from 2839 m 3 to 4921 m 3 (750,000 to 1,300,000 gallons). Eighteen of the tanks are older style and do not meet all current federal standards for secondary containment. The older style tanks are the initial focus of waste removal efforts for tank closure and are referred to as closure tanks. Of the original 51 underground waste tanks, six of the original 24 older style tanks have completed waste removalmore » and are filled with grout. The insoluble waste fraction that resides within most waste tanks at SRS requires vigorous agitation to suspend the solids within the waste liquid in order to transfer this material for eventual processing into glass filled canisters at the Defense Waste Processing Facility (DWPF). SRS suspends the solid waste by use of recirculating mixing pumps. Older style tanks generally have limited riser openings which will not support larger mixing pumps, since the riser access is typically 58.4 cm (23 inches) in diameter. Agitation for these tanks has been provided by four long shafted standard slurry pumps (SLP) powered by an above tank 112KW (150 HP) electric motor. The pump shaft is lubricated and cooled in a pressurized water column that is sealed from the surrounding waste in the tank. Closure of four waste tanks has been accomplished utilizing long shafted pump technology combined with heel removal using multiple technologies. Newer style waste tanks at SRS have larger riser openings, allowing the processing of waste solids to be accomplished with four large diameter SLPs equipped with 224KW (300 HP) motors. These tanks are used to process the waste from closure tanks for DWPF. In addition to the SLPs, a 224KW (300 HP) submersible mixer pump (SMP) has also been developed and deployed within older style tanks. The SMPs are product cooled and product lubricated canned motor pumps designed to fit within available risers and have significant agitation capabilities to suspend waste solids. Waste removal and closure of two tanks has been accomplished with agitation provided by 3 SMPs installed within the tanks. In 2012, a team was assembled to investigate alternative solids removal technologies to support waste removal for closing tanks. The goal of the team was to find a more cost effective approach that could be used to replace the current mixing pump technology. This team was unable to identify an alternative technology outside of mixing pumps to support waste agitation and removal from SRS waste tanks. However, the team did identify a potentially lower cost mixing pump compared to the baseline SLPs and SMPs. Rather than using the traditional procurement using an engineering specification, the team proposed to seek commercially available submersible mixer pumps (CSMP) as alternatives to SLPs and SMPs. SLPs and SMPs have a high procurement cost and the actual cost of moving pumps between tanks has shown to be significantly higher than the original estimates that justified the reuse of SMPs and SLPs. The team recommended procurement of “off-the-shelf” industry pumps which may be available for significant savings, but at an increased risk of failure and reduced operating life in the waste tank. The goal of the CSMP program is to obtain mixing pumps that could mix from bulk waste removal through tank closure and then be abandoned in place as part of tank closure. This paper will present the development, progress and relative advantages of the CSMP.« less

Methods of silver recovery from radiographs - comparative study

NASA Astrophysics Data System (ADS)

Canda, L. R.; Ardelean, E.; Hepuţ, T.

2018-01-01

Management and recovery of waste are activities with multiple impacts: technologically (by using waste on current production flows, thus replacing poor raw materials), economically (can substantially reduce manufacturing costs by recycling waste), social (by creating new jobs where it is necessary to process the waste in a form more suited to technological flows) and ecologically (by removing waste that is currently produced or already stored - but poses a threat to the health of the population and / or to the environment). This is also the case for medical waste, for example radiographs, which are currently produced in large quantities, for which replacement solutions are sought, but are currently stored by archiving in hospital units. The paper presents two methods used for this kind of waste management, the result being the recovery of silver, material with applications and with increasing price, but also the proper disposal of the polymeric support. This analysis aims at developing a more efficient recycling technology for medical radiographs.

The life cycle assessment of cellulose pulp from waste cotton via the SaXcell™ process.

NASA Astrophysics Data System (ADS)

Oelerich, Jens; Bijleveld, Marijn; Bouwhuis, Gerrit H.; Brinks, Ger J.

2017-10-01

Recycling of cotton waste into high value products is a longstanding goal in textile research. The SaXcellTM process provides a chemical recycling route towards virgin fibres. In this study a Life cycle assessment (LCA) is conducted to measure the impact of the chemical recycling of cotton waste on the environment. Pure cotton waste and cotton containing 10 % of polyester are elaborated. The results show that chemical recycling via the SaXcellTM process can have a lower impact on climate change and other impact category than comparable pulping technologies.

Environmental Management vitrification activities

DOE Office of Scientific and Technical Information (OSTI.GOV)

Krumrine, P.H.

1996-05-01

Both the Mixed Waste and Landfill Stabilization Focus Areas as part of the Office of Technology Development efforts within the Department of Energy`s (DOE) Environmental Management (EM) Division have been developing various vitrification technologies as a treatment approach for the large quantities of transuranic (TRU), TRU mixed and Mixed Low Level Wastes that are stored in either landfills or above ground storage facilities. The technologies being developed include joule heated, plasma torch, plasma arc, induction, microwave, combustion, molten metal, and in situ methods. There are related efforts going into development glass, ceramic, and slag waste form windows of opportunity formore » the diverse quantities of heterogeneous wastes needing treatment. These studies look at both processing parameters, and long term performance parameters as a function of composition to assure that developed technologies have the right chemistry for success.« less

Feasibility tests for treating shampoo and hair colorant wastewaters using anaerobic processes.

PubMed

Ahammad, Shaikh Z; Yakubu, A; Dolfing, J; Mota, C; Graham, D W

2012-01-01

Wastes from the personal care product (PCP) industry are often high in biodegradable carbon, which makes them amenable to aerobic biological treatment, although process costs are usually high due to aeration inefficiencies, high electricity demand and production of large amounts of sludge. As such, anaerobic treatment technologies are being considered to lower net energy costs by reducing air use and increasing methane production. To assess the amenability of PCP wastes to anaerobic treatment, methane yields and rates were quantified in different anaerobic reactors treating typical PCP wastes, including wastes from shampoo and hair colorant products. Overall, shampoo wastes were more amenable to methanogenesis with almost double the methane yields compared with colour wastes. To assess relevant microbial guilds, qPCR was performed on reactor biomass samples. Methanosaetaceae abundances were always significantly higher than Methanosarcinaceae and Methanomicrobiales abundances (P < 0.05), and did not differ significantly between waste types. Although colour wastes were less amenable to anaerobic treatment than shampoo wastes, differences cannot be explained by relative microbial abundances and probably result from the presence of inhibiting compounds in hair colorants (e.g., oxidants) at higher levels. Results showed that anaerobic technologies have great potential for treating PCP wastes, but additional work is needed to establish the basis of elevated methane yields and inhibition, especially when colorant wastes are present.

Food waste-to-energy conversion technologies: current status and future directions.

PubMed

Pham, Thi Phuong Thuy; Kaushik, Rajni; Parshetti, Ganesh K; Mahmood, Russell; Balasubramanian, Rajasekhar

2015-04-01

Food waste represents a significantly fraction of municipal solid waste. Proper management and recycling of huge volumes of food waste are required to reduce its environmental burdens and to minimize risks to human health. Food waste is indeed an untapped resource with great potential for energy production. Utilization of food waste for energy conversion currently represents a challenge due to various reasons. These include its inherent heterogeneously variable compositions, high moisture contents and low calorific value, which constitute an impediment for the development of robust, large scale, and efficient industrial processes. Although a considerable amount of research has been carried out on the conversion of food waste to renewable energy, there is a lack of comprehensive and systematic reviews of the published literature. The present review synthesizes the current knowledge available in the use of technologies for food-waste-to-energy conversion involving biological (e.g. anaerobic digestion and fermentation), thermal and thermochemical technologies (e.g. incineration, pyrolysis, gasification and hydrothermal oxidation). The competitive advantages of these technologies as well as the challenges associated with them are discussed. In addition, the future directions for more effective utilization of food waste for renewable energy generation are suggested from an interdisciplinary perspective. Copyright © 2014 Elsevier Ltd. All rights reserved.

Proposed best demonstrated available technology (BDAT) background document for K031, K084, K101, K102, characteristic arsenic wastes (D004), characteristic selenium wastes (D010), and P and U wastes containing arsenic and selenium listing constitutents. Volume 1

DOE Office of Scientific and Technical Information (OSTI.GOV)

Rosengrant, L.; Craig, R.

1989-11-01

The background document presents the technical support and rationale for developing regulatory standards for K031, K084, K101, K102, D004, D010 and P and U wastes. Section 1 presents available data regarding the industries affected by the land disposal restriction, brief descriptions of the waste-generating processes, and waste characterization data. Section 2 discusses the technologies used to treat the wastes; Section 3 presents available treatment performance data; Section explains EPA's determination of BDAT; Section 5 discusses the selection of constituents to be regulated; and Section 6 determines the proposed treatment standards.

Energy Supply- Production of Fuel from Agricultural and Animal Waste

DOE Office of Scientific and Technical Information (OSTI.GOV)

Gabriel Miller

2009-03-25

The Society for Energy and Environmental Research (SEER) was funded in March 2004 by the Department of Energy, under grant DE-FG-36-04GO14268, to produce a study, and oversee construction and implementation, for the thermo-chemical production of fuel from agricultural and animal waste. The grant focuses on the Changing World Technologies (CWT) of West Hempstead, NY, thermal conversion process (TCP), which converts animal residues and industrial food processing biproducts into fuels, and as an additional product, fertilizers. A commercial plant was designed and built by CWT, partially using grant funds, in Carthage, Missouri, to process animal residues from a nearby turkey processingmore » plant. The DOE sponsored program consisted of four tasks. These were: Task 1 Optimization of the CWT Plant in Carthage - This task focused on advancing and optimizing the process plant operated by CWT that converts organic waste to fuel and energy. Task 2 Characterize and Validate Fuels Produced by CWT - This task focused on testing of bio-derived hydrocarbon fuels from the Carthage plant in power generating equipment to determine the regulatory compliance of emissions and overall performance of the fuel. Task 3 Characterize Mixed Waste Streams - This task focused on studies performed at Princeton University to better characterize mixed waste incoming streams from animal and vegetable residues. Task 4 Fundamental Research in Waste Processing Technologies - This task focused on studies performed at the Massachusetts Institute of Technology (MIT) on the chemical reformation reaction of agricultural biomass compounds in a hydrothermal medium. Many of the challenges to optimize, improve and perfect the technology, equipment and processes in order to provide an economically viable means of creating sustainable energy were identified in the DOE Stage Gate Review, whose summary report was issued on July 30, 2004. This summary report appears herein as Appendix 1, and the findings of the report formed the basis for much of the subsequent work under the grant. An explanation of the process is presented as well as the completed work on the four tasks.« less

INNOVATIVE FOSSIL FUEL FIRED VITRIFICATION TECHNOLOGY FOR SOIL REMEDIATION

DOE Office of Scientific and Technical Information (OSTI.GOV)

J. Hnat; L.M. Bartone; M. Pineda

2001-07-13

This Summary Report summarizes the progress of Phases 3, 3A and 4 of a waste technology Demonstration Project sponsored under a DOE Environmental Management Research and Development Program and administered by the U.S. Department of Energy National Energy Technology Laboratory-Morgantown (DOE-NETL) for an ''Innovative Fossil Fuel Fired Vitrification Technology for Soil Remediation''. The Summary Reports for Phases 1 and 2 of the Program were previously submitted to DOE. The total scope of Phase 3 was to have included the design, construction and demonstration of Vortec's integrated waste pretreatment and vitrification process for the treatment of low level waste (LLW), TSCA/LLWmore » and mixed low-level waste (MLLW). Due to funding limitations and delays in the project resulting from a law suit filed by an environmental activist and the extended time for DOE to complete an Environmental Assessment for the project, the scope of the project was reduced to completing the design, construction and testing of the front end of the process which consists of the Material Handling and Waste Conditioning (MH/C) Subsystem of the vitrification plant. Activities completed under Phases 3A and 4 addressed completion of the engineering, design and documentation of the Material Handling and Conditioning System such that final procurement of the remaining process assemblies can be completed and construction of a Limited Demonstration Project be initiated in the event DOE elects to proceed with the construction and demonstration testing of the MH/C Subsystem.« less

Biodecontamination of concrete

DOE Office of Scientific and Technical Information (OSTI.GOV)

Rogers, R.D.

1995-12-31

This paper describes the development and results of a demonstration for a continuous bioprocess for mixed waste treatment. A key element of the process is a unique microbial strain, which tolerates high levels of aromatic solvents and surfactants. This microorganism is the biocatalysis of the continuous flow system designed for processing stored liquid scintillation wastes. During the past year, a process demonstration has been conducted on commercial formulation of liquid scintillation cocktails (LSQ). Based on data obtained from this demonstration, the Ohio Environmental Protection Agency granted the Mound Applied Technologies Laboratory a treatability permit allowing the limited processing of actualmore » mixed waste. Since August 1994, the system has been successfully processing stored {open_quotes}hot{close_quotes} LSC waste. This paper discusses the bioprocess, rates of processing, effluent, and implications of bioprocessing for mixed waste management.« less

Biopurification of industrial waste gas from rubber regeneration.

PubMed

Sun, Peishi; Yang, Xianwan; Huang, Ruohua; Bin, Huang; Zheng, Sunsheng; Wei, Zaishan; Xu, Xiaoyi; Lu, Jilai; Sun, Xing; Chen, Liuxin

2004-12-01

By using the biopurifying technology, the organic waste gas in low concentrations emitted from the rubber-regeneration process was purified in this research. The result of the 100-day continuous running test of the industrial test device indicated that the purification efficiency of toluene in the rubber-regeneration waste gas could be maintained at about 90% for a long period of time and the treated waste gas could meet the China National Emission Standard. The cost of waste gas biotreatment was about 0.12-0.14% of rubber-regeneration production value of the factory. The biopurifying technology of waste gas displayed its excellent technical advancement and economic rationale. The following industrialized device was run continuously and passed the examination and acceptance by the local EPA.

Dangerous Waste Characteristics of Contact-Handled Transuranic Mixed Wastes from Hanford Tanks

DOE Office of Scientific and Technical Information (OSTI.GOV)

Tingey, Joel M.; Bryan, Garry H.; Deschane, Jaquetta R.

2004-10-05

This report summarizes existing analytical data gleaned from samples taken from the Hanford tanks designated as potentially containing transuranic mixed process wastes. Process knowledge of the wastes transferred to these tanks has been reviewed to determine whether the dangerous waste characteristics now assigned to all Hanford underground storage tanks are applicable to these particular wastes. Supplemental technologies are being examined to accelerate the Hanford tank waste cleanup mission and accomplish waste treatment safely and efficiently. To date, 11 Hanford waste tanks have been designated as potentially containing contact-handled (CH) transuranic mixed (TRUM) wastes. The CH-TRUM wastes are found in single-shellmore » tanks B-201 through B-204, T-201 through T-204, T-104, T-110, and T-111. Methods and equipment to solidify and package the CH-TRUM wastes are part of the supplemental technologies being evaluated. The resulting packages and wastes must be acceptable for disposal at the Waste Isolation Pilot Plant (WIPP). The dangerous waste characteristics being considered include ignitability, corrosivity, reactivity, and toxicity arising from the presence of 2,4,5-trichlorophenol at levels above the dangerous waste threshold. The analytical data reviewed include concentrations of sulfur, sulfate, cyanide, 2,4,5-trichlorophenol, total organic carbon, and oxalate; the composition of the tank headspace, pH, and mercury. Differential scanning calorimetry results were used to determine the energetics of the wastes as a function of temperature. This report supercedes and replaces PNNL-14832.« less

Dangerous Waste Characteristics of Contact-Handled Transuranic Mixed Wastes from the Hanford Tanks

DOE Office of Scientific and Technical Information (OSTI.GOV)

Tingey, Joel M.; Bryan, Garry H.; Deschane, Jaquetta R.

2004-08-31

This report summarizes existing analytical data from samples taken from the Hanford tanks designated as potentially containing transuranic mixed process wastes. Process knowledge of the wastes transferred to these tanks has been reviewed to determine whether the dangerous waste characteristics now assigned to all Hanford underground storage tanks are applicable to these particular wastes. Supplemental technologies are being examined to accelerate the Hanford tank waste cleanup mission and accomplish waste treatment safely and efficiently. To date, 11 Hanford waste tanks have been designated as potentially containing contact-handled (CH) transuranic mixed (TRUM) wastes. The CH-TRUM wastes are found in single-shell tanksmore » B-201 through B-204, T-201 through T-204, T-104, T-110, and T-111. Methods and equipment to solidify and package the CH-TRUM wastes are part of the supplemental technologies being evaluated. The resulting packages and wastes must be acceptable for disposal at the Waste Isolation Pilot Plant (WIPP). The dangerous waste characteristics being considered include ignitability, corrosivity, reactivity, and toxicity arising from the presence of 2,4,5-trichlorophenol at levels above the dangerous waste threshold. The analytical data reviewed include concentrations of sulfur, sulfate, cyanide, 2,4,5-trichlorophenol, total organic carbon, and oxalate; the composition of the tank headspace, pH, and mercury. Differential scanning calorimetry results were used to determine the energetics of the wastes as a function of temperature.« less

Numerical Simulation of Hydrothermal Salt Separation Process and Analysis and Cost Estimating of Shipboard Liquid Waste Disposal

DTIC Science & Technology

2007-06-01

possible means to improve a variety of processes: supercritical water in steam Rankine cycles (fossil-fuel powered plants), supercritical carbon ... dioxide and supercritical water in advanced nuclear power plants, and oxidation in supercritical water for use in destroying toxic military wastes and...destruction technologies are installed in a class of ship. Additionally, the properties of one waste water destruction medium, supercritical

From electronic consumer products to e-wastes: Global outlook, waste quantities, recycling challenges.

PubMed

Tansel, Berrin

2017-01-01

Advancements in technology, materials development, and manufacturing processes have changed the consumer products and composition of municipal solid waste (MSW) since 1960s. Increasing quantities of discarded consumer products remain a major challenge for recycling efforts, especially for discarded electronic products (also referred as e-waste). The growing demand for high tech products has increased the e-waste quantities and its cross boundary transport globally. This paper reviews the challenges associated with increasing e-waste quantities. The increasing need for raw materials (especially for rare earth and minor elements) and unregulated e-waste recycling operations in developing and underdeveloped counties contribute to the growing concerns for e-waste management. Although the markets for recycled materials are increasing; there are major challenges for development of the necessary infrastructure for e-waste management and accountability as well as development of effective materials recovery technologies and product design. Copyright © 2016 Elsevier Ltd. All rights reserved.

Environmental Management Waste Management Facility Waste Lot Profile 155.5 for K-1015-A Laundry Pit, East Tennessee Technology Park Oak Ridge, Tennessee

DOE Office of Scientific and Technical Information (OSTI.GOV)

Bechtel Jacobs, Raymer J.E.

2008-06-12

In 1989, the Oak Ridge Reservation (ORR), which includes the East Tennessee Technology Park (ETTP), was placed on the Comprehensive Environmental Response, Compensation, and Liability Act of 1980 (CERCLA) National Priorities List. The Federal Facility Agreement (FFA) (DOE 1992), effective January 1, 1992, now governs environmental restoration activities conducted under CERCLA at the ORR. Following signing of the FFA, U.S. Department of Energy (DOE), U.S. Environmental Protection Agency (EPA), and the state of Tennessee signed the Oak Ridge Accelerated Cleanup Plan Agreement on June 18, 2003. The purpose of this agreement is to define a streamlined decision-making process to facilitatemore » the accelerated implementation of cleanup, to resolve ORR milestone issues, and to establish future actions necessary to complete the accelerated cleanup plan by the end of fiscal year 2008. While the FFA continues to serve as the overall regulatory framework for remediation, the Accelerated Cleanup Plan Agreement supplements existing requirements to streamline the decision-making process. The disposal of the K-1015 Laundry Pit waste will be executed in accordance with the 'Record of Decision for Soil, Buried Waste, and Subsurface Structure Actions in Zone, 2, East Tennessee Technology Park, Oak Ridge, Tennessee' (DOB/ORAH-2161&D2) and the 'Waste Handling Plan for the Consolidated Soil and Waste Sites with Zone 2, East Tennessee Technology Park, Oak Ridge, Tennessee' (DOE/OR/01-2328&D1). This waste lot consists of a total of approximately 50 cubic yards of waste that will be disposed at the Environmental Management Waste Management Facility (EMWMF) as non-containerized waste. This material will be sent to the EMWMF in dump trucks. This profile is for the K-1015-A Laundry Pit and includes debris (e.g., concrete, metal rebar, pipe), incidental soil, plastic and wood, and secondary waste (such as plastic sheeting, hay bales and other erosion control materials, wooden pallets, contaminated equipment, decontamination materials, etc.).« less

Gasification of Wood and Non-wood Waste of Timber Production as Perspectives for Development of Bioenergy

NASA Astrophysics Data System (ADS)

Kislukhina, Irina A.; Rybakova, Olga G.

2018-03-01

The article deals with biomass gasification technology using the gasification plant running on wood chips and pellets, produced from essential oils waste (waste of coniferous boughs). During the study, the authors solved the process task of improving the quality of the product gas derived from non-wood waste of timber production (coniferous boughs) due to the extraction of essential oils and the subsequent thermal processing of spent coniferous boughs at a temperature of 250-300°C degrees without oxygen immediately before pelleting. The paper provides the improved biomass gasification process scheme including the grinding of coniferous boughs, essential oil distillation and thermal treatment of coniferous boughs waste and pelletizing.

Plasma gasification of municipal solid waste

DOE Office of Scientific and Technical Information (OSTI.GOV)

Carter, G.W.; Tsangaris, A.V.

1995-12-31

Resorption Canada Limited (RCL) has conducted extensive operational testing with plasma technology in their plasma facility near Ottawa, Ontario, Canada to develop an environmentally friendly waste disposal process. Plasma technology, when utilized in a reactor vessel with the exclusion of oxygen, provides for the complete gasification of all combustibles in source materials with non-combustibles being converted to a non-hazardous slag. The energy and environmental characteristics of the plasma gasification of carbonaceous waste materials were studied over a period of eight years during which RCL completed extensive experimentation with MSW. A plasma processing system capable of processing 200--400 lbs/hr of MSWmore » was designed and built. The experimentation on MSW concentrated on establishing the optimum operating parameters and determining the energy and environmental characteristics at these operating parameters.« less

SUPERFUND INNOVATIVE TECHNOLOGY EVALUATION PROGRAM Evaluation of Soil Amendment Technologies at the Crooksville/RosevillePottery Area of Concern Rocky Mountain Remediation ServicesEnvirobond™ Process

EPA Science Inventory

RMRS developed the Envirobond™ process to treat heavy metals in soil.This phosphate-based technology consists of a proprietary powder and solution that binds with metals in contaminated waste. RMRS claims that the Envirobond™ process converts metal contaminants from their leach...

A review of the technological solutions for the treatment of oily sludges from petroleum refineries.

PubMed

da Silva, Leonardo Jordão; Alves, Flávia Chaves; de França, Francisca Pessôa

2012-10-01

The activities of the oil industry have several impacts on the environment due to the large amounts of oily wastes that are generated. The oily sludges are a semi-solid material composed by a mixture of clay, silica and iron oxides contaminated with oil, produced water and the chemicals used in the production of oil. Nowadays both the treatment and management of these waste materials is essential to promote sustainable management of exploration and exploitation of natural resources. Biological, physical and chemical processes can be used to reduce environmental contamination by petroleum hydrocarbons to acceptable levels. The choice of treatment method depends on the physical and chemical properties of the waste as well as the availability of facilities to process these wastes. Literature provides some operations for treatment of oily sludges, such as landfilling, incineration, co-processing in clinkerization furnaces, microwave liquefaction, centrifugation, destructive distillation, thermal plasma, low-temperature conversion, incorporation in ceramic materials, development of impermeable materials, encapsulation and biodegradation in land farming, biopiles and bioreactors. The management of the technology to be applied for the treatment of oily wastes is essential to promote proper environmental management, and provide alternative methods to reduce, reuse and recycle the wastes.

Yttrium recovery from primary and secondary sources: A review of main hydrometallurgical processes

DOE Office of Scientific and Technical Information (OSTI.GOV)

Innocenzi, Valentina, E-mail: valentina.innocenzi1@univaq.it; De Michelis, Ida; Kopacek, Bernd

2014-07-15

Highlights: • Review of the main hydrometallurgical processes to recover yttrium. • Recovery of yttrium from primary sources. • Recovery of yttrium from e-waste and other types of waste. - Abstract: Yttrium is important rare earths (REs) used in numerous fields, mainly in the phosphor powders for low-energy lighting. The uses of these elements, especially for high-tech products are increased in recent years and combined with the scarcity of the resources and the environmental impact of the technologies to extract them from ores make the recycling waste, that contain Y and other RE, a priority. The present review summarized themore » main hydrometallurgical technologies to extract Y from ores, contaminated solutions, WEEE and generic wastes. Before to discuss the works about the treatment of wastes, the processes to retrieval Y from ores are discussed, since the processes are similar and derived from those already developed for the extraction from primary sources. Particular attention was given to the recovery of Y from WEEE because the recycle of them is important not only for economical point of view, considering its value, but also for environmental impact that this could be generated if not properly disposal.« less

Trash to Gas (TtG) Simulant Analysis

NASA Technical Reports Server (NTRS)

Miles, John D., II; Hintze, Paul E.

2014-01-01

Space exploration in outer earths orbit is a long-term commitment, where the reuse of discarded materials is a critical component for its success. The Logistics Reduction and Repurposing (LRR) project under the NASA Advanced Exploration System Program is a project focused on technologies that reduce the amount of consumables that are needed to be sent into space, repurpose items sent to space, or convert wastes to commodities. In particular, Trash to Gas (TtG), part of the LRR project, is a novel space technology capable of converting raw elements from combustible waste including food waste and packaging, paper, wipes and towels, nitrile gloves, fecal matter, urine brine, maximum absorbency garments, and other organic wastes from human space exploration into useful gases. Trash to gas will ultimately reduce mission cost by producing a portion of important consumables in situ. This paper will discuss results of waste processing by steam reforming. Steam reforming is a thermochemical process developed as part of TtG, where waste is heated in the presence of oxygen and steam to produce carbon dioxide, carbon monoxide, hydrogen, methane and water. The aim of this experiment is to investigate the processing of different waste simulants and their gaseous products. This will lay a foundation for understating and optimizing the production of useful gases for propulsion and recovery of water for life support.

Planetary Protection Considerations for Life Support and Habitation Systems

NASA Technical Reports Server (NTRS)

Barta, Daniel J.; Hogan, John A.

2010-01-01

Life support systems for future human missions beyond low Earth orbit may include a combination of existing hardware components and advanced technologies. Discipline areas for technology development include atmosphere revitalization, water recovery, solid waste management, crew accommodations, food production, thermal systems, environmental monitoring, fire protection and radiation protection. Life support systems will be influenced by in situ resource utilization (ISRU), crew mobility and the degree of extravehicular activity. Planetary protection represents an additional set of requirements that technology developers have generally not considered. Planetary protection guidelines will affect the kind of operations, processes, and functions that can take place during future exploration missions, including venting and discharge of liquids and solids, ejection of wastes, use of ISRU, requirements for cabin atmospheric trace contaminant concentrations, cabin leakage and restrictions on what materials, organisms, and technologies that may be brought on missions. Compliance with planetary protection requirements may drive development of new capabilities or processes (e.g. in situ sterilization, waste containment, contaminant measurement) and limit or prohibit certain kinds of operations or processes (e.g. unfiltered venting). Ultimately, there will be an effect on mission costs, including the mission trade space. Planetary protection requirements need to be considered early in technology development programs. It is expected that planetary protection will have a major impact on technology selection for future missions.

An innovative approach to predict technology evolution for the desoldering of printed circuit boards: A perspective from China and America.

PubMed

Wang, Chen; Zhao, Wu; Wang, Jie; Chen, Ling; Luo, Chun-Jing

2016-06-01

The printed circuit boards basis of electronic equipment have seen a rapid growth in recent years and played a significant role in modern life. Nowadays, the fact that electronic devices upgrade quickly necessitates a proper management of waste printed circuit boards. Non-destructive desoldering of waste printed circuit boards becomes the first and the most crucial step towards recycling electronic components. Owing to the diversity of materials and components, the separation process is difficult, which results in complex and expensive recovery of precious materials and electronic components from waste printed circuit boards. To cope with this problem, we proposed an innovative approach integrating Theory of Inventive Problem Solving (TRIZ) evolution theory and technology maturity mapping system to forecast the evolution trends of desoldering technology of waste printed circuit boards. This approach can be applied to analyse the technology evolution, as well as desoldering technology evolution, then research and development strategy and evolution laws can be recommended. As an example, the maturity of desoldering technology is analysed with a technology maturity mapping system model. What is more, desoldering methods in different stages are analysed and compared. According to the analysis, the technological evolution trends are predicted to be 'the law of energy conductivity' and 'increasing the degree of idealisation'. And the potential technology and evolutionary state of waste printed circuit boards are predicted, offering reference for future waste printed circuit boards recycling. © The Author(s) 2016.

APPLICATIONS ANALYSIS REPORT: CHEMFIX TECHNOLOGIES, INC. - SOLIDIFICATION/STABILIZATION PROCESS

EPA Science Inventory

In support of the U.S. Environmental Protection Agency's (EPA) Superfund Innovative Technology Evaluation (SITE) Program, this report evaluates the Chemfix Technologies, Inc. (Chemfix), solidification/stabilization technology for on-site treatment of hazardous waste. The Chemfix ...

DIRECT CONVERSION OF MUNICIPAL AND AGRICULTURAL WASTES TO BIODIESEL AND ETHANOL UTILIZING A UNIQUE EXTREMOPHILIC FUNGUS - PHASE I

EPA Science Inventory

Sustainable Bioproducts LLC’s proposed research will further develop an efficient, economical and scalable process for conversion of municipal solid wastes and agricultural wastes to biodiesel and ethanol. The technology is based on use of a novel extremophilic fun...

The role of frit in nuclear waste vitrification

DOE Office of Scientific and Technical Information (OSTI.GOV)

Vienna, J.D.; Smith, P.A.; Dorn, D.A.

1994-04-01

Vitrification of nuclear waste requires additives which are often vitrified independently to form a frit. Frit composition is formulated to meet the needs of glass composition and processing. The effects of frit on melter feed and melt processing, glass acceptance, and waste loading is of practical interest in understanding the trade-offs associated with the competing demands placed on frit composition. Melter feed yield stress, viscosity and durability of frits and corresponding waste glasses as well as the kinetics of elementary melting processes have been measured. The results illustrate the competing requirements on frit. Four frits (FY91, FY93, HW39-4, and SR202)more » and simulated neutralized current acid waste (NCAW) were used in this study. The experimental evidence shows that optimization of frit for one processing related property often results in poorer performance for the remaining properties. The difficulties associated with maximum waste loading and durability are elucidated for glasses which could be processed using technology available for the previously proposed Hanford Waste Vitrification Plant.« less

DOE Office of Scientific and Technical Information (OSTI.GOV)

Wheeler, P.A.; Patel, N.M.; Painter, A.

Energy recovery from municipal solid waste (MSW) is an important component of an integrated waste management strategy. Waste management programs which remove or recover materials for recycling are particularly suited for considering the option of energy recovery via fluidized bed combustion (FBC). The last few years have seen growing interest in the application of FBC technology to the MSW treatment/disposal problem. This paper reviews and reports on the world-wide experience in fluidized bed combustion of MSW focusing particularly on the types and scales of the systems in operation in Japan and Scandinavia. In addition the paper also reports on themore » development of an energy from waste project employing circulating fluidized bed technology that is proposed for a local municipality in the UK. Japan currently has over 100 bubbling bed units in operation firing on 100% MSW; the technology is firmly established at scales of operation up to 160,000t/y (the largest single unit operates at 6.25t/h). The bubbling bed units accept MSW which has undergone only minimal pre-processing -- the waste is shredded to a nominal 300mm size fraction before being introduced to the furnace. There are distinct (combustion control) advantages to further processing of the waste stream prior to combustion. The Scandinavian countries in particular have been the prime movers in pioneering this technology to work in combination with circulating fluidized bed systems. Currently 2 units are in operation cofiring pre-processed MSW with a range of other biofuels. A number of FBC units firing 100% MSW are currently in the planning or construction stage around the world; they seem set to secure an increased market share particularly at the smaller scale of operation (up to about 200,000t/y).« less

Goodbye, Waste! What We Make. Science and Technology Education in Philippine Society.

ERIC Educational Resources Information Center

Philippines Univ., Quezon City. Science Education Center.

This module: (1) discusses the need for disposing of waste safely; (2) provides information and activities on wet and dry wastes; and (3) shows how to prepare, maintain, and study a fertilizer basket (in which fertilizer is made from wet waste). Information on the biology of the basket (including role of bacteria and fungi in the decay process) is…

The analysis of waste treatment methods and managerial skills towards the effectiveness of CO2 emmissions (an ex post facto study at TPA Bantar Gebang Bekasi)

NASA Astrophysics Data System (ADS)

Ria Rajagukguk, Jenni; Siagian, Lestina

2017-09-01

In the last three years, Java Island produces 29.413.336 m3/year of waste, coming from settlement (house hold) and non-settlement waste. Recently, this waste is managed with conventional technology, composting and recycling. Based on law No. 18 of 2008 on Waste Management, Chapter III Article 5, it is firmly stated that the government and regional governments are responsible for ensuring proper and environmentally sound waste management in accordance with the objectives. The observation of managerial skills is highly needed to investigate the operation of waste management at TPA Bantar Gebang towards the effectiveness of CO2 emissions.The problems are (1)Whether there is any influence between the method of waste management through Biogas Technology to the effectiveness of CO2 emissions. (2) Whether there is any influence between managerial skills to effectiveness of CO2 emission. (3) Whether there is any simultaneous influence between waste management method and managerial skill to CO2 emission effectiveness and (4) how is the method of waste management. Quantitative and egineering method were used to process the data.Biogas Technology variables and Managerial Skill are simultaneously and significantly influenced to CO2 Emission Effectiveness, this is based on Fh > Ft value of 168,453 > 3.072467) and its significance is 0.000 < 0,05. Then Ho was rejected and Ha was accepted which means that variable of Managerial Skill have influence or very big influence to Effeciveness of CO2 Emission, Correlation coefficient value 94,1% which means there is very strong relation between variable of Biogas Technology, Managerial Skill to Effectiveness of CO2 emission. Then Technology management through Biogas Technology is anaerobic biology.

TECHNICAL ASSESSMENT OF BULK VITRIFICATION PROCESS & PRODUCT FOR TANK WASTE TREATMENT AT THE DEPARTMENT OF ENERGY HANFORD SITE

DOE Office of Scientific and Technical Information (OSTI.GOV)

SCHAUS, P.S.

At the U.S. Department of Energy (DOE) Hanford Site, the Waste Treatment Plant (WTP) is being constructed to immobilize both high-level waste (IUW) for disposal in a national repository and low-activity waste (LAW) for onsite, near-surface disposal. The schedule-controlling step for the WTP Project is vitrification of the large volume of LAW, current capacity of the WTP (as planned) would require 50 years to treat the Hanford tank waste, if the entire LAW volume were to be processed through the WTP. To reduce the time and cost for treatment of Hanford Tank Waste, and as required by the Tank Wastemore » Remediation System Environmental Impact Statement Record of Decision and the Hanford Federal Facility Consent Agreement (Tn-Party Agreement), DOE plans to supplement the LAW treatment capacity of the WTP. Since 2002, DOE, in cooperation with the Environmental Protection Agency and State of Washington Department of Ecology has been evaluating technologies that could provide safe and effective supplemental treatment of LAW. Current efforts at Hanford are intended to provide additional information to aid a joint agency decision on which technology will be used to supplement the WTP. A Research, Development and Demonstration permit has been issued by the State of Washington to build and (for a limited time) operate a Demonstration Bulk Vitrification System (DBVS) facility to provide information for the decision on a supplemental treatment technology for up to 50% of the LAW. In the Bulk Vitrification (BV) process, LAW, soil, and glass-forming chemicals are mixed, dried, and placed in a refractory-lined box, Electric current, supplied through two graphite electrodes in the box, melts the waste feed, producing a durable glass waste-form. Although recent modifications to the process have resulted in significant improvements, there are continuing technical concerns.« less

Feasibility basis for use of new solid household waste processing equipment

NASA Astrophysics Data System (ADS)

Vertakova, Y. V.; Zvyagintsev, G. L.; Babich, T. N.; Polozhentseva, Y. S.

2017-10-01

Economic efficiency assessment of innovative organizational project of solid household waste processing enterprise (SHW) is given. A distinctive feature of this project is new mining and chemical technology use of waste depolymerization. The proved feature is fuel-resource production in portion modules of tubular type. They are patented and approved under laboratory conditions. The main ways of SHW processing in the world including Russia are described. Advantages and disadvantages are revealed. Comparative analysis is carried out. Technology prioritization is a result of this analysis. During organization of such enterprise, it was proved that not only SHW processing is a result of its functioning. The other result is environmentally friendly production using secondary raw materials. These products can be sold and can have bring income. Main investment and current expenses necessary for the offered project implementation are defined. This allows making economic assessment of innovative enterprise efficiency.

Enhancement of the recycling of waste Ni-Cd and Ni-MH batteries by mechanical treatment.

PubMed

Huang, Kui; Li, Jia; Xu, Zhenming

2011-06-01

A serious environmental problem was presented by waste batteries resulting from lack of relevant regulations and effective recycling technologies in China. The present work considered the enhancement of waste Ni-Cd and Ni-MH batteries recycling by mechanical treatment. In the process of characterization, two types of waste batteries (Ni-Cd and Ni-MH batteries) were selected and their components were characterized in relation to their elemental chemical compositions. In the process of mechanical separation and recycling, waste Ni-Cd and Ni-MH batteries were processed by a recycling technology without a negative impact on the environment. The technology contained mechanical crushing, size classification, gravity separation, and magnetic separation. The results obtained demonstrated that: (1) Mechanical crushing was an effective process to strip the metallic parts from separators and pastes. High liberation efficiency of the metallic parts from separators and pastes was attained in the crushing process until the fractions reached particle sizes smaller than 2mm. (2) The classified materials mainly consisted of the fractions with the size of particles between 0.5 and 2mm after size classification. (3) The metallic concentrates of the samples were improved from around 75% to 90% by gravity separation. More than 90% of the metallic materials were separated into heavy fractions when the particle sizes were larger than 0.5mm. (4) The size of particles between 0.5 and 2mm and the rotational speed of the separator between 30 and 60 rpm were suitable for magnetic separation during industrial application, with the recycling efficiency exceeding 95%. Copyright © 2011 Elsevier Ltd. All rights reserved.

Environmental and health impacts of using food waste as animal feed: a comparative analysis of food waste management options.

PubMed

Salemdeeb, Ramy; Zu Ermgassen, Erasmus K H J; Kim, Mi Hyung; Balmford, Andrew; Al-Tabbaa, Abir

2017-01-01

The disposal of food waste is a large environmental problem. In the United Kingdom (UK), approximately 15 million tonnes of food are wasted each year, mostly disposed of in landfill, via composting, or anaerobic digestion (AD). European Union (EU) guidelines state that food waste should preferentially be used as animal feed though for most food waste this practice is currently illegal, because of disease control concerns. Interest in the potential diversion of food waste for animal feed is however growing, with a number of East Asian states offering working examples of safe food waste recycling - based on tight regulation and rendering food waste safe through heat treatment. This study investigates the potential benefits of diverting food waste for pig feed in the UK. A hybrid, consequential life cycle assessment (LCA) was conducted to compare the environmental and health impacts of four technologies for food waste processing: two technologies of South Korean style-animal feed production (as a wet pig feed and a dry pig feed) were compared with two widespread UK disposal technologies: AD and composting. Results of 14 mid-point impact categories show that the processing of food waste as a wet pig feed and a dry pig feed have the best and second-best scores, respectively, for 13/14 and 12/14 environmental and health impacts. The low impact of food waste feed stems in large part from its substitution of conventional feed, the production of which has substantial environmental and health impacts. While the re-legalisation of the use of food waste as pig feed could offer environmental and public health benefits, this will require support from policy makers, the public, and the pig industry, as well as investment in separated food waste collection which currently occurs in only a minority of regions.

Environmentally Sound Processing Technology: JANNAF Safety and Environmental Protection Subcommittee and Propellant Development and Characterization Subcommittee Joint Workshop

NASA Technical Reports Server (NTRS)

Pickett, Lorri A. (Editor)

1995-01-01

Topics covered include: Risk assessment of hazardous materials, Automated systems for pollution prevention and hazardous materials elimination, Study design for the toxicity evaluation of ammonium perchlorate, Plasma sprayed bondable stainless surface coatings, Development of CFC-free cleaning processes, New fluorinated solvent alternatives to ozone depleting solvents, Cleaning with highly fluorinated liquids, Biotreatment of propyleneglycol nitrate by anoxic denitrification, Treatment of hazardous waste with white rot fungus, Hydrothermal oxidation as an environmentally benign treatment technology, Treatment of solid propellant manufacturing wastes by base hydrolysis, Design considerations for cleaning using supercritical fluid technology, and Centrifugal shear carbon dioxide cleaning.

Closed Fuel Cycle Waste Treatment Strategy

DOE Office of Scientific and Technical Information (OSTI.GOV)

Vienna, J. D.; Collins, E. D.; Crum, J. V.

This study is aimed at evaluating the existing waste management approaches for nuclear fuel cycle facilities in comparison to the objectives of implementing an advanced fuel cycle in the U.S. under current legal, regulatory, and logistical constructs. The study begins with the Global Nuclear Energy Partnership (GNEP) Integrated Waste Management Strategy (IWMS) (Gombert et al. 2008) as a general strategy and associated Waste Treatment Baseline Study (WTBS) (Gombert et al. 2007). The tenets of the IWMS are equally valid to the current waste management study. However, the flowsheet details have changed significantly from those considered under GNEP. In addition, significantmore » additional waste management technology development has occurred since the GNEP waste management studies were performed. This study updates the information found in the WTBS, summarizes the results of more recent technology development efforts, and describes waste management approaches as they apply to a representative full recycle reprocessing flowsheet. Many of the waste management technologies discussed also apply to other potential flowsheets that involve reprocessing. These applications are occasionally discussed where the data are more readily available. The report summarizes the waste arising from aqueous reprocessing of a typical light-water reactor (LWR) fuel to separate actinides for use in fabricating metal sodium fast reactor (SFR) fuel and from electrochemical reprocessing of the metal SFR fuel to separate actinides for recycle back into the SFR in the form of metal fuel. The primary streams considered and the recommended waste forms include; Tritium in low-water cement in high integrity containers (HICs); Iodine-129: As a reference case, a glass composite material (GCM) formed by the encapsulation of the silver Mordenite (AgZ) getter material in a low-temperature glass is assumed. A number of alternatives with distinct advantages are also considered including a fused silica waste form with encapsulated nano-sized AgI crystals; Carbon-14 immobilized as a CaCO3 in a cement waste form; Krypton-85 stored as a compressed gas; An aqueous reprocessing high-level waste (HLW) raffinate waste immobilized by the vitrification process; An undissolved solids (UDS) fraction from aqueous reprocessing of LWR fuel either included in the borosilicate HLW glass or immobilized in the form of a metal alloy or titanate ceramics; Zirconium-based LWR fuel cladding hulls and stainless steel (SS) fuel assembly hardware super-compacted for disposal or purified for reuse (or disposal as low-level waste, LLW) of Zr by reactive gas separations; Electrochemical process salt HLW incorporated into a glass bonded Sodalite waste form; and Electrochemical process UDS and SS cladding hulls melted into an iron based alloy waste form. Mass and volume estimates for each of the recommended waste forms based on the source terms from a representative flowsheet are reported. In addition to the above listed primary waste streams, a range of secondary process wastes are generated by aqueous reprocessing of LWR fuel, metal SFR fuel fabrication, and electrochemical reprocessing of SFR fuel. These secondary wastes have been summarized and volumes estimated by type and classification. The important waste management data gaps and research needs have been summarized for each primary waste stream and selected waste process.« less

Photochemical oxidation: A solution for the mixed waste dilemma

DOE Office of Scientific and Technical Information (OSTI.GOV)

Prellberg, J.W.; Thornton, L.M.; Cheuvront, D.A.

1995-12-31

Numerous technologies are available to remove organic contamination from water or wastewater. A variety of techniques also exist that are used to neutralize radioactive waste. However, few technologies can satisfactorily address the treatment of mixed organic/radioactive waste without creating unacceptable secondary waste products or resulting in extremely high treatment costs. An innovative solution to the mixed waste problem is on-site photochemical oxidation. Liquid-phase photochemical oxidation has a long- standing history of successful application to the destruction of organic compounds. By using photochemical oxidation, the organic contaminants are destroyed on-site leaving the water, with radionuclides, that can be reused or disposedmore » of as appropriate. This technology offers advantages that include zero air emissions, no solid or liquid waste formation, and relatively low treatment cost. Discussion of the photochemical process will be described, and several case histories from recent design testing, including cost analyses for the resulting full-scale installations, will be presented as examples.« less

Low-Activity Waste Pretreatment System Additional Engineering-Scale Integrated Test Report

DOE Office of Scientific and Technical Information (OSTI.GOV)

Landon, Matt R.; Wilson, Robert A.

Washington River Protections Solutions, LLC’s (WRPS) Low Activity Waste Pretreatment System (LAWPS) Project provides for the early production of immobilized low-activity waste (ILAW) by feeding LAW directly from Tank Farms to the Waste Treatment and Immobilization Plant (WTP) LAW Facility, bypassing the WTP Pretreatment Facility. Prior to the transfer of feed to the WTP LAW Vitrification Facility, tank supernatant waste will be pretreated in the LAWPS to meet the WTP LAW waste acceptance criteria (WAC). Full-scale and engineering-scale testing of critical technology elements, as part of the technology maturation process, are components of the overall LAWPS Project. WRPS awarded themore » engineering-scale integrated testing scope to AECOM via WRPS Subcontract 58349. This report is deliverable MSR-008 of the subcontract.« less

DOE Office of Scientific and Technical Information (OSTI.GOV)

Spoerri, Andy, E-mail: andy.spoerri@env.ethz.c; Lang, Daniel J.; Staeubli, Beat

Understanding technological change provides a crucial basis for governing sustainability transitions. In this paper we present an analysis of technological change using the example of Swiss thermal waste processing. In recent years, increased concerns about the low quality of residues from grate-firing systems led to the examination of alternative technologies. Yet despite clear indications of a potential better performance with respect to residue quality, none of these alternatives has been adopted. Based on a two-stage knowledge integration among 15 leading experts, in a retrospective analysis we identified factors that have significantly affected technological change in Swiss thermal waste processing. Thesemore » factors were then related to three technological options representing different types of technological change, i.e., from incremental improvements of the existing to the implementation of a new technology. The results indicate that technological change is currently in a technological lock-in and provide detailed insights on the causes. The lock-in results in the step-wise further development of the status quo grate-firing system despite its limitations for improving the residue qualities. Almost all factors (legal, economic, societal, technological) of the existing 'thermal waste management' system have been well adapted to the cost- and energy-efficient grate-firing technology, blocking innovative technologies from entering the Swiss market. In addition, pressures from the context, e.g., societal pressure related to landfill risks, have not been strong enough to promote non-incremental change.« less

SOLVENT WASTE REDUCTION ALTERNATIVES

EPA Science Inventory

This publication contains edited versions of presentations on this subject made at five Technology Transfer seminars in 1988. Chapters are included on land disposal regulations and requirements; waste solvent disposal alternatives from various industries such as process equipment...

Implementation of the U.S. Environmental Protection Agency's Waste Reduction (WAR) Algorithm in Cape-Open Based Process Simulators

EPA Science Inventory

The Sustainable Technology Division has recently completed an implementation of the U.S. EPA's Waste Reduction (WAR) Algorithm that can be directly accessed from a Cape-Open compliant process modeling environment. The WAR Algorithm add-in can be used in AmsterChem's COFE (Cape-Op...

40 CFR 436.132 - Effluent limitations guidelines representing the degree of effluent reduction attainable by the...

Code of Federal Regulations, 2011 CFR

2011-07-01

... practicable control technology currently available (BPT): there shall be no discharge of process waste water pollutants into navigable waters. (b) Only that volume of water resulting from precipitation that exceeds the maximum safe surge capacity of a process waste water impoundment may be discharged from that impoundment...

40 CFR 436.152 - Effluent limitations guidelines representing the degree of effluent reduction attainable by the...

Code of Federal Regulations, 2011 CFR

2011-07-01

... practicable control technology currently available (BPT): there shall be no discharge of process waste water pollutants into navigable waters. (b) Only that volume of water resulting from precipitation that exceeds the maximum safe surge capacity of a process waste water impoundment may be discharged from that impoundment...

40 CFR 436.142 - Effluent limitations guidelines representing the degree of effluent reduction attainable by the...

Code of Federal Regulations, 2011 CFR

2011-07-01

... practicable control technology currently available (BPT): there shall be no discharge of process waste water pollutants into navigable waters. (b) Only that volume of water resulting from precipitation that exceeds the maximum safe surge capacity of a process waste water impoundment may be discharged from that impoundment...

Molten salt oxidation: a versatile and promising technology for the destruction of organic-containing wastes.

PubMed

Yao, Zhitong; Li, Jinhui; Zhao, Xiangyang

2011-08-01

Molten salt oxidation (MSO), a robust thermal but non-flame process, has the inherent capability of destroying organic constituents in wastes, while retaining inorganic and radioactive materials in situ. It has been considered as an alternative to incineration and may be a solution to many waste disposal problems. The present review first describes the history and development of MSO, as well as design and engineering details, and then focuses on reaction mechanisms and its potential applications in various wastes, including hazardous wastes, medical wastes, mixed wastes, and energetic materials. Finally, the current status of and prospects for the MSO process and directions for future research are considered. Copyright © 2011 Elsevier Ltd. All rights reserved.

Integrated gasification and plasma cleaning for waste treatment: A life cycle perspective

DOE Office of Scientific and Technical Information (OSTI.GOV)

Evangelisti, Sara; Tagliaferri, Carla; Advanced Plasma Power

2015-09-15

Highlights: • A life cycle assessment of an advanced two-stage process is undertaken. • A comparison of the impacts of the process when fed with 7 feedstock is presented. • Sensitivity analysis on the system is performed. • The treatment of RDF shows the lowest impact in terms of both GWP and AP. • The plasma shows a small contribution to the overall impact of the plant. - Abstract: In the past, almost all residual municipal waste in the UK was landfilled without treatment. Recent European waste management directives have promoted the uptake of more sustainable treatment technologies, especially formore » biodegradable waste. Local authorities have started considering other options for dealing with residual waste. In this study, a life cycle assessment of a future 20 MWe plant using an advanced two-stage gasification and plasma technology is undertaken. This plant can thermally treat waste feedstocks with different composition and heating value to produce electricity, steam and a vitrified product. The objective of the study is to analyse the environmental impacts of the process when fed with seven different feedstocks (including municipal solid waste, solid refuse fuel, reuse-derived fuel, wood biomass and commercial & industrial waste) and identify the process steps which contribute more to the environmental burden. A scenario analysis on key processes, such as oxygen production technology, metal recovery and the appropriate choice for the secondary market aggregate material, is performed. The influence of accounting for the biogenic carbon content in the waste from the calculations of the global warming potential is also shown. Results show that the treatment of the refuse-derived fuel has the lowest impact in terms of both global warming potential and acidification potential because of its high heating value. For all the other impact categories analysed, the two-stage gasification and plasma process shows a negative impact for all the waste streams considered, mainly due to the avoided burdens associated with the production of electricity from the plant. The plasma convertor, key characteristic of the thermal process investigated, although utilising electricity shows a relatively small contribution to the overall environmental impact of the plant. The results do not significantly vary in the scenario analysis. Accounting for biogenic carbon enhanced the performance of biomass and refuse-derived fuel in terms of global warming potential. The main analysis of this study has been performed from a waste management perspective, using 1 ton of waste as functional unit. A comparison of the results when 1 kWhe of electricity produced is used as functional unit shows similar trends for the environmental impact categories considered.« less

Recovery of metals and nonmetals from electronic waste by physical and chemical recycling processes.

PubMed

Kaya, Muammer

2016-11-01

This paper reviews the existing and state of art knowledge for electronic waste (e-waste) recycling. Electrical and/or electronic devices which are unwanted, broken or discarded by their original users are known as e-waste. The main purpose of this article is to provide a comprehensive review of e-waste problem, strategies of e-waste management and various physical, chemical and metallurgical e-waste recycling processes, their advantages and disadvantages towards achieving a cleaner process of waste utilization, with special attention towards extraction of both metallic values and nonmetallic substances. The hazards arise from the presence of heavy metals Hg, Cd, Pb, etc., brominated flame retardants (BFRs) and other potentially harmful substances in e-waste. Due to the presence of these substances, e-waste is generally considered as hazardous waste and, if improperly managed, may pose significant human and environmental health risks. This review describes the potential hazards and economic opportunities of e-waste. Firstly, an overview of e-waste/printed circuit board (PCB) components is given. Current status and future perspectives of e-waste/PCB recycling are described. E-waste characterization, dismantling methods, liberation and classification processes are also covered. Manual selective dismantling after desoldering and metal-nonmetal liberation at -150μm with two step crushing are seen to be the best techniques. After size reduction, mainly physical separation processes employing gravity, electrostatic, magnetic separators, froth floatation, etc. have been critically reviewed here for separation of metals and nonmetals, along with useful utilizations of the nonmetallic materials. The recovery of metals from e-waste material after physical separation through pyrometallurgical, hydrometallurgical or biohydrometallurgical routes is also discussed along with purification and refining. Suitable PCB recycling flowsheets for industrial applications are also given. It seems that hydrometallurgical route will be a key player in the base and precious metals recoveries from e-waste. E-waste recycling will be a very important sector in the near future from economic and environmental perspectives. Recycling technology aims to take today's waste and turn it into conflict-free, sustainable polymetallic secondary resources (i.e. Urban Mining) for tomorrow. Recycling technology must ensure that e-waste is processed in an environmentally friendly manner, with high efficiency and lowered carbon footprint, at a fraction of the costs involved with setting multibillion dollar smelting facilities. Taking into consideration our depleting natural resources, this Urban Mining approach offers quite a few benefits. This results in increased energy efficiency and lowers demand for mining of new raw materials. Copyright © 2016 Elsevier Ltd. All rights reserved.

Lyophilization -Solid Waste Treatment

NASA Technical Reports Server (NTRS)

Litwiller, Eric; Flynn, Michael; Fisher, John; Reinhard, Martin

2004-01-01

This paper discusses the development of a solid waste treatment system that has been designed for a Mars transit exploration mission. The technology described is an energy-efficient lyophilization technique that is designed to recover water from spacecraft solid wastes. Candidate wastes include feces, concentrated brines from water processors, and other solid wastes that contain free water. The system is designed to operate as a stand-alone process or to be integrated into the International Space Station Waste Collection System. In the lyophilization process, water in an aqueous waste is frozen and then sublimed, separating the waste into a dried solid material and liquid water. The sublimed water is then condensed in a solid ice phase and then melted to generate a liquid product. In the subject system the waste solids are contained within a 0.2 micron bio-guard bag and after drying are removed from the system and stored in a secondary container. This technology is ideally suited to applications such as the Mars Reference Mission, where water recovery rates approaching 100% are desirable but production of CO2 is not. The system is designed to minimize power consumption through the use of thermoelectric heat pumps. The results of preliminary testing of a prototype system and testing of the final configuration are provided. A mathematical model of the system is also described.

[The influence of the oil and gas industry on environmental safety and population health in the Khanty-Mansiĭskiĭ Region - Iugra].

PubMed

Samutin, N M; Vorob'ev, V O; Butorin, N N

2013-01-01

Production activities of oil and gas industry plants are related to technogenic impact on the environment, which has a high environmental risk. This is associated with low levels of environmental orientation of sheer technological processes of exploration and exploitation of hydrocarbons and also used in this technical means, materials and chemical reagents. The main pollutants that deteriorate the toxic characteristics of drilling waste, are the most likely drilling fluids, mud flush agents and chemicals, which enter into their composition. Existing methods of disposal of drilling wastes are not effective, the technology of their use is often violated. Dumping drilling waste into water bodies and burying toxic waste in water protection areas under the guise of processed waste has been observed. In the region there are significantly exceeded the national average values rate of morbidity of allergic, cardiovascular, pulmonary and cancer diseases, mediated by environmental factors and new monofactorial and multifactorial diseases appear.

Technology Demonstration Summary Site Program Demonstration Test Soliditech Inc Solidification-stabilization Process

EPA Science Inventory

The major objective of the Soliditech, Inc., SITE demonstration was to develop reliable performance and cost information about the Soliditech solidification, stabilization technology. The Soliditech process mixes hazardous waste materials with Portland cement or pozzolanic m...

EPA SITE DEMONSTRATION OF THE INTERNATIONAL WASTE TECHNOLOGIES/GEO-CON IN SITU STABILIZATION/ SOLIDIFICATION PROCESS

EPA Science Inventory

This paper presents an EPA evaluation of the first field demonstration of an in situ stabilization/solidification process for contaminated soil under the EPA Superfund Innovative Technology Evaluation (SITE) program. Demonstration of this process was a joint effort of two vendors...

TREATMENT OF METAL-LADEN HAZARDOUS WASTES WITH ADVANCED CLEAN COAL TECHNOLOGY BY-PRODUCTS

DOE Office of Scientific and Technical Information (OSTI.GOV)

James T. Cobb, Jr.

2003-09-12

Metal-laden wastes can be stabilized and solidified using advanced clean coal technology by-products (CCTBs)--fluid bed combustor ash and spray drier solids. These utility-generated treatment chemicals are available for purchase through brokers, and commercial applications of this process are being practiced by treaters of metal-laden hazardous waste. A complex of regulations governs this industry, and sensitivities to this complex has discouraged public documentation of treatment of metal-laden hazardous wastes with CCTBs. This report provides a comprehensive public documentation of laboratory studies that show the efficacy of the stabilization and solidification of metal-laden hazardous wastes--such as lead-contaminated soils and sandblast residues--through treatmentmore » with CCTBs. It then describes the extensive efforts that were made to obtain the permits allowing a commercial hazardous waste treater to utilize CCTBs as treatment chemicals and to install the equipment required to do so. It concludes with the effect of this lengthy process on the ability of the treatment company to realize the practical, physical outcome of this effort, leading to premature termination of the project.« less

Bioprocessing of a stored mixed liquid waste

DOE Office of Scientific and Technical Information (OSTI.GOV)

Wolfram, J.H.; Rogers, R.D.; Finney, R.

1995-12-31

This paper describes the development and results of a demonstration for a continuous bioprocess for mixed waste treatment. A key element of the process is an unique microbial strain which tolerates high levels of aromatic solvents and surfactants. This microorganism is the biocatalysis of the continuous flow system designed for the processing of stored liquid scintillation wastes. During the past year a process demonstration has been conducted on commercial formulation of liquid scintillation cocktails (LSC). Based on data obtained from this demonstration, the Ohio EPA granted the Mound Applied Technologies Lab a treatability permit allowing the limited processing of actualmore » mixed waste. Since August 1994, the system has been successfully processing stored, {open_quotes}hot{close_quotes} LSC waste. The initial LSC waste fed into the system contained 11% pseudocumene and detectable quantities of plutonium. Another treated waste stream contained pseudocumene and tritium. Data from this initial work shows that the hazardous organic solvent, and pseudocumene have been removed due to processing, leaving the aqueous low level radioactive waste. Results to date have shown that living cells are not affected by the dissolved plutonium and that 95% of the plutonium was sorbed to the biomass. This paper discusses the bioprocess, rates of processing, effluent, and the implications of bioprocessing for mixed waste management.« less

Metals Recovery from Artificial Ore in Case of Printed Circuit Boards, Using Plasmatron Plasma Reactor

PubMed Central

Szałatkiewicz, Jakub

2016-01-01

This paper presents the investigation of metals production form artificial ore, which consists of printed circuit board (PCB) waste, processed in plasmatron plasma reactor. A test setup was designed and built that enabled research of plasma processing of PCB waste of more than 700 kg/day scale. The designed plasma process is presented and discussed. The process in tests consumed 2 kWh/kg of processed waste. Investigation of the process products is presented with their elemental analyses of metals and slag. The average recovery of metals in presented experiments is 76%. Metals recovered include: Ag, Au, Pd, Cu, Sn, Pb, and others. The chosen process parameters are presented: energy consumption, throughput, process temperatures, and air consumption. Presented technology allows processing of variable and hard-to-process printed circuit board waste that can reach up to 100% of the input mass. PMID:28773804

Metals Recovery from Artificial Ore in Case of Printed Circuit Boards, Using Plasmatron Plasma Reactor.

PubMed

Szałatkiewicz, Jakub

2016-08-10

This paper presents the investigation of metals production form artificial ore, which consists of printed circuit board (PCB) waste, processed in plasmatron plasma reactor. A test setup was designed and built that enabled research of plasma processing of PCB waste of more than 700 kg/day scale. The designed plasma process is presented and discussed. The process in tests consumed 2 kWh/kg of processed waste. Investigation of the process products is presented with their elemental analyses of metals and slag. The average recovery of metals in presented experiments is 76%. Metals recovered include: Ag, Au, Pd, Cu, Sn, Pb, and others. The chosen process parameters are presented: energy consumption, throughput, process temperatures, and air consumption. Presented technology allows processing of variable and hard-to-process printed circuit board waste that can reach up to 100% of the input mass.

Thirteenth annual U.S. DOE low-level radioactive waste management conference: Proceedings

DOE Office of Scientific and Technical Information (OSTI.GOV)

NONE

1991-12-31

The 40 papers in this document comprise the proceedings of the Department of Energy`s Thirteenth Annual Low-Level Radioactive Waste Management Conference that was held in Atlanta, Georgia, on November 19--21, 1991. General subjects addressed during the conference included: disposal facility design; greater-than-class C low-level waste; public acceptance considerations; waste certification; site characterization; performance assessment; licensing and documentation; emerging low-level waste technologies; waste minimization; mixed waste; tracking and transportation; storage; and regulatory changes. Papers have been processed separately for inclusion on the data base.

Technology and equipment based on induction melters with ``cold'' crucible for reprocessing active metal waste

NASA Astrophysics Data System (ADS)

Pastushkov, V. G.; Molchanov, A. V.; Serebryakov, V. P.; Smelova, T. V.; Shestoperov, I. N.

2000-07-01

The paper discusses specific features of technology, equipment and control of a single stage RAMW decontamination and melting process in an induction furnace equipped with a "cold" crucible. The calculated and experimental data are given on melting high activity level stainless steel and Zr simulating high activity level metal waste. The work is under way in SSC RF VNIINM.

Bioregenerative technologies for waste processing and resource recovery in advanced space life support system

NASA Technical Reports Server (NTRS)

Chamberland, Dennis

1991-01-01

The Controlled Ecological Life Support System (CELSS) for producing oxygen, water, and food in space will require an interactive facility to process and return wastes as resources to the system. This paper examines the bioregenerative techologies for waste processing and resource recovery considered for a CELSS Resource Recovery system. The components of this system consist of a series of biological reactors to treat the liquid and solid material fractions, in which the aerobic and anaerobic reactors are combined in a block called the Combined Reactor Equipment (CORE) block. The CORE block accepts the human wastes, kitchen wastes, inedible refractory plant materials, grey waters from the CELLS system, and aquaculture solids and processes these materials in either aerobic or anaerobic reactors depending on the desired product and the rates required by the integrated system.

Green technology innovation in a developing country

NASA Astrophysics Data System (ADS)

Treesubsuntorn, Chairat; Dolphen, Rujira; Dhurakit, Prapai; Siswanto, Dian; Thiravetyan, Paitip

2017-11-01

Developing countries rapidly grow when green technology, which is referred to as eco-friendly processes or methods, is developed in parallel. Here, some examples of green technology research and development in Thailand will be overviewed. A huge amount of agricultural waste is generated during agricultural processes. Applying these agricultural wastes in order to maximize the benefits for environmental cleanups of water, soil and air has been studied and commercialized. For example: 1) Application of agricultural waste and/or biochar developed from agricultural waste as biological adsorbents for wastewater treatment in some industries, such as textile/dye industries, and printing industries. In addition, this agricultural waste can also be applied in decolorization of sugar syrup from sugar industries; 2) The research on modified biomaterials as adsorbents and packing materials in biofilters would also be presented, and now, pilot scale biofilters have been developed and applied to solve air pollution problems in the field for future commercialization; 3) Some agricultural waste and/or biochar developed from agricultural waste in our laboratory can promote rice growth and improve rice quality via the reduction of Cd uptake and translocation in rice. Phytoremediation technology, in which plants are used to improve the environmental quality in water and air, has also been studied and would be presented. 1) Some species of native Thai plants can effectively remove heavy metals and dye from wastewater. For this research, a constructed wetland for wastewater treatment was developed and applied in a real contaminated site. 2) In air phytoremediation, some plant species harbor highly volatile organic compound (VOC) removal efficiency. In addition, plants do not only absorb organic pollutants, but also they have the innate ability to degrade organic compounds and use them as carbon sources for their growth. In addition, plant growth-promoting (PGP) bacteria inoculation into plants can enhance airborne pollutant removal. From this research, an indoor air phytoremediation system was developed in order to reduce CO2 emissions with high VOC removal efficiency. The high cost of technology transfer is a major problem, especially in developing countries, and green technology research and innovation can overcome this problem along with efficient allocation of resources and technologies.

DEMONSTRATION OF AN INTEGRATED, PASSIVE BIOLOGICAL TREATMENT PROCESS FOR AMD

EPA Science Inventory

An innovative, cost-effective, biological treatment process has been designed by MSE Technology Applications, Inc. to treat acid mine drainage (AMD). A pilot-scale demonstration is being conducted under the Mine Waste Technology Program using water flowing from an abandoned mine ...

FY16 Annual Accomplishments - Waste Form Development and Performance: Evaluation Of Ceramic Waste Forms - Comparison Of Hot Isostatic Pressed And Melt Processed Fabrication Methods

DOE Office of Scientific and Technical Information (OSTI.GOV)

Amoroso, J.; Dandeneau, C.

FY16 efforts were focused on direct comparison of multi-phase ceramic waste forms produced via melt processing and HIP methods. Based on promising waste form compositions previously devised at SRNL, simulant material was prepared at SRNL and a portion was sent to the Australian Nuclear Science and Technology Organization (ANSTO) for HIP treatments, while the remainder of the material was melt processed at SRNL. The microstructure, phase formation, elemental speciation, and leach behavior, and radiation stability of the fabricated ceramics was performed. In addition, melt-processed ceramics designed with different fractions of hollandite, zirconolite, perovskite, and pyrochlore phases were investigated. for performancemore » and properties.« less

Evaluating the Air Quality, Climate and Economic Impacts of ...

EPA Pesticide Factsheets

Anaerobic digestion is a natural biological process in which microorganisms break down organic materials in the absence of oxygen. When anaerobic microbes metabolize organic waste – i.e., the carbon-based remains of plants, animals and their waste products, e.g. animal manure, sewage sludge and food waste – they produce biogas. Biogas consists mainly of methane and carbon dioxide and can be used as a renewable energy fuel in a variety of applications. The impacts of biogas generation and utilization processes differ, depending on the source material (e.g., sewage, manure, food processing waste, municipal solid waste) and end uses (e.g., on-site electricity generation, conversion to a vehicle fuel, injection into the natural gas pipeline, etc.). Organic waste managers and regulators alike lack sufficient information about the overall environmental and economic performance of available biogas management technologies. A more complete understanding of the environmental and economic performance of biogas-to-energy technologies will assist state and local governments, regulators, and potential project developers in identifying geographically appropriate and cost-effective biogas management options.The backdrop for this research was California. The state has unique air quality challenges due to the combination of meteorology and topography, population growth and the pollution burden associated with mobile sources. However, with the strengthening of National Ambient

Enhanced methane yield by co-digestion of sewage sludge with micro-algae and catering waste leachate.

PubMed

2018-04-04

The co-digestion of different wastes is a promising concept to improve methane generation during anaerobic process. However, the anaerobic co-digestion of catering waste leachate with algal biomass and sewage sludge has not been studied to date. This work investigated the methane generation by the anaerobic co-digestion of different mixtures of catering waste leachate, micro-algal biomass, and sewage sludge. Co-digestion of waste mixture containing equal ratios of three substrates had 39.31% higher methane yield than anaerobic digestion of raw sludge. This was possibly due to a proliferation of methanogens during the co-digestion period induced by multi-phase digestion of different wastes with different degrees of digestibility. Therefore, co-digestion of catering waste leachate, micro-algal biomass, and sewage sludge appears to be an efficient technology for energy conversion from waste resources. The scientific application of this co-digestion technology with these three substrates may play a role in solving important environmental issues of waste management.

Valorization of date palm (Phoenix dactylifera) fruit processing by-products and wastes using bioprocess technology - Review.

PubMed

Chandrasekaran, M; Bahkali, Ali H

2013-04-01

The date palm Phoenix dactylifera has played an important role in the day-to-day life of the people for the last 7000 years. Today worldwide production, utilization and industrialization of dates are continuously increasing since date fruits have earned great importance in human nutrition owing to their rich content of essential nutrients. Tons of date palm fruit wastes are discarded daily by the date processing industries leading to environmental problems. Wastes such as date pits represent an average of 10% of the date fruits. Thus, there is an urgent need to find suitable applications for this waste. In spite of several studies on date palm cultivation, their utilization and scope for utilizing date fruit in therapeutic applications, very few reviews are available and they are limited to the chemistry and pharmacology of the date fruits and phytochemical composition, nutritional significance and potential health benefits of date fruit consumption. In this context, in the present review the prospects of valorization of these date fruit processing by-products and wastes' employing fermentation and enzyme processing technologies towards total utilization of this valuable commodity for the production of biofuels, biopolymers, biosurfactants, organic acids, antibiotics, industrial enzymes and other possible industrial chemicals are discussed.

Innovative vitrification for soil remediation

DOE Office of Scientific and Technical Information (OSTI.GOV)

Jetta, N.W.; Patten, J.S.; Hart, J.G.

1995-12-01

The objective of this DOE demonstration program is to validate the performance and operation of the Vortec Cyclone Melting System (CMS{trademark}) for the processing of LLW contaminated soils found at DOE sites. This DOE vitrification demonstration project has successfully progressed through the first two phases. Phase 1 consisted of pilot scale testing with surrogate wastes and the conceptual design of a process plant operating at a generic DOE site. The objective of Phase 2, which is scheduled to be completed the end of FY 95, is to develop a definitive process plant design for the treatment of wastes at amore » specific DOE facility. During Phase 2, a site specific design was developed for the processing of LLW soils and muds containing TSCA organics and RCRA metal contaminants. Phase 3 will consist of a full scale demonstration at the DOE gaseous diffusion plant located in Paducah, KY. Several DOE sites were evaluated for potential application of the technology. Paducah was selected for the demonstration program because of their urgent waste remediation needs as well as their strong management and cost sharing financial support for the project. During Phase 2, the basic nitrification process design was modified to meet the specific needs of the new waste streams available at Paducah. The system design developed for Paducah has significantly enhanced the processing capabilities of the Vortec vitrification process. The overall system design now includes the capability to shred entire drums and drum packs containing mud, concrete, plastics and PCB`s as well as bulk waste materials. This enhanced processing capability will substantially expand the total DOE waste remediation applications of the technology.« less

A review on waste heat recovery from exhaust in the ceramics industry

NASA Astrophysics Data System (ADS)

Delpech, Bertrand; Axcell, Brian; Jouhara, Hussam

2017-11-01

Following the energy crisis in 1980, many saving technologies have been investigated with attempts to implement them into various industries, one of them is the field of ceramic production. In order to comply with energy saving trends and environmental issues, the European ceramic industry sector has developed energy efficient systems which reduced significantly production time and costs and reduced total energy consumption. The last achievement is of great importance as the energy consumption of the ceramic process accounts for a significant percentage of the total production costs. More precisely, the firing stage consumes the highest amount of energy during the whole ceramic production process. The use of roller kilns, fired by natural gas, involves a loss of 50% of the input energy via the flue gas and the cooling gas exhausts. This review paper briefly describes the production process of the different ceramic products, with a focus on the ceramic sector in Europe. Due to the limited on waste heat recovery in the ceramic industry, other high temperature waste heat recovery applications are considered in the paper, such as in concrete and steel production, which could have a potential use in the ceramic industry. The state of the art technologies used in the ceramics industry are reviewed with a special interest in waste heat recovery from the ceramic process exhaust stacks and energy saving technologies.

Radio Frequency Identification (RFID) and communication technologies for solid waste bin and truck monitoring system.

PubMed

Hannan, M A; Arebey, Maher; Begum, R A; Basri, Hassan

2011-12-01

This paper deals with a system of integration of Radio Frequency Identification (RFID) and communication technologies for solid waste bin and truck monitoring system. RFID, GPS, GPRS and GIS along with camera technologies have been integrated and developed the bin and truck intelligent monitoring system. A new kind of integrated theoretical framework, hardware architecture and interface algorithm has been introduced between the technologies for the successful implementation of the proposed system. In this system, bin and truck database have been developed such a way that the information of bin and truck ID, date and time of waste collection, bin status, amount of waste and bin and truck GPS coordinates etc. are complied and stored for monitoring and management activities. The results showed that the real-time image processing, histogram analysis, waste estimation and other bin information have been displayed in the GUI of the monitoring system. The real-time test and experimental results showed that the performance of the developed system was stable and satisfied the monitoring system with high practicability and validity. Copyright © 2011 Elsevier Ltd. All rights reserved.

Advanced Energy and Water Recovery Technology from Low Grade Waste Heat

DOE Office of Scientific and Technical Information (OSTI.GOV)

Dexin Wang

2011-12-19

The project has developed a nanoporous membrane based water vapor separation technology that can be used for recovering energy and water from low-temperature industrial waste gas streams with high moisture contents. This kind of exhaust stream is widely present in many industrial processes including the forest products and paper industry, food industry, chemical industry, cement industry, metal industry, and petroleum industry. The technology can recover not only the sensible heat but also high-purity water along with its considerable latent heat. Waste heats from such streams are considered very difficult to recover by conventional technology because of poor heat transfer performancemore » of heat-exchanger type equipment at low temperature and moisture-related corrosion issues. During the one-year Concept Definition stage of the project, the goal was to prove the concept and technology in the laboratory and identify any issues that need to be addressed in future development of this technology. In this project, computational modeling and simulation have been conducted to investigate the performance of a nanoporous material based technology, transport membrane condenser (TMC), for waste heat and water recovery from low grade industrial flue gases. A series of theoretical and computational analyses have provided insight and support in advanced TMC design and experiments. Experimental study revealed condensation and convection through the porous membrane bundle was greatly improved over an impermeable tube bundle, because of the membrane capillary condensation mechanism and the continuous evacuation of the condensate film or droplets through the membrane pores. Convection Nusselt number in flue gas side for the porous membrane tube bundle is 50% to 80% higher than those for the impermeable stainless steel tube bundle. The condensation rates for the porous membrane tube bundle also increase 60% to 80%. Parametric study for the porous membrane tube bundle heat transfer performance was also done, which shows this heat transfer enhancement approach works well in a wide parameters range for typical flue gas conditions. Better understanding of condensing heat transfer mechanism for porous membrane heat transfer surfaces, shows higher condensation and heat transfer rates than non-permeable tubes, due to existence of the porous membrane walls. Laboratory testing has documented increased TMC performance with increased exhaust gas moisture content levels, which has exponentially increased potential markets for the product. The TMC technology can uniquely enhance waste heat recovery in tandem with water vapor recovery for many other industrial processes such as drying, wet and dry scrubber exhaust gases, dewatering, and water chilling. A new metallic substrate membrane tube development and molded TMC part fabrication method, provides an economical way to expand this technology for scaled up applications with less than 3 year payback expectation. A detailed market study shows a broad application area for this advanced waste heat and water recovery technology. A commercialization partner has been lined up to expand this technology to this big market. This research work led to new findings on the TMC working mechanism to improve its performance, better scale up design approaches, and economical part fabrication methods. Field evaluation work needs to be done to verify the TMC real world performance, and get acceptance from the industry, and pave the way for our commercial partner to put it into a much larger waste heat and waste water recovery market. This project is addressing the priority areas specified for DOE Industrial Technologies Program's (ITP's): Energy Intensive Processes (EIP) Portfolio - Waste Heat Minimization and Recovery platform.« less

Technologies and decision support systems to aid solid-waste management: a systematic review.

PubMed

Vitorino de Souza Melaré, Angelina; Montenegro González, Sahudy; Faceli, Katti; Casadei, Vitor

2017-01-01

Population growth associated with population migration to urban areas and industrial development have led to a consumption relation that results in environmental, social, and economic problems. With respect to the environment, a critical concern is the lack of control and the inadequate management of the solid waste generated in urban centers. Among the challenges are proper waste-collection management, treatment, and disposal, with an emphasis on sustainable management. This paper presents a systematic review on scientific publications concerning decision support systems applied to Solid Waste Management (SWM) using ICTs and OR in the period of 2010-2013. A statistical analysis of the eighty-seven most relevant publications is presented, encompassing the ICTs and OR methods adopted in SWM, the processes of solid-waste management where they were adopted, and which countries are investigating solutions for the management of solid waste. A detailed discussion on how the ICTs and OR methods have been combined in the solutions was also presented. The analysis and discussion provided aims to help researchers and managers to gather insights on technologies/methods suitable the SWM challenges they have at hand, and on gaps that can be explored regarding technologies/methods that could be useful as well as the processes in SWM that currently do not benefit from using ICTs and OR methods. Copyright © 2016 Elsevier Ltd. All rights reserved.

EVALUATION OF COLLIER COUNTY, FLORIDA LANDFILL MINING DEMONSTRATION

EPA Science Inventory

This report describes the landfill mining process as demonstrated under the U.S. EPA, Risk Reduction Engineering Laboratory's Municipal Waste Innovative Technology Evaluation (MITE) Program by the Collier County (Florida) Solid Waste Management Department. Landfill mining is the ...

EVALUATION OF THE COLLIER COUNTY, FLORIDA LANDFILL MINING DEMONSTRATION

EPA Science Inventory

This report describes the landfill mining process as demonstrated under the U.S. EPA, Risk Reduction Engineering Laboratory's Municipal Waste Innovative Technology Evaluation (MITE) Program by the Collier County (Florida) Solid Waste Management Department. Landfill mining is the ...

An overview of metals recovery from thermal power plant solid wastes.

PubMed

Meawad, Amr S; Bojinova, Darinka Y; Pelovski, Yoncho G

2010-12-01

Thermal power plants (TPPs) that burn fossil fuels emit several pollutants linked to the environmental problems of acid rain, urban ozone, and the possibility of global climate change. As coal is burned in a power plant, its noncombustible mineral content is partitioned into bottom ash, which remains in the furnace, and fly ash, which rises with flue gases. Two other by-products of coal combustion air-pollution control technologies are flue gas desulfurization (FGD) wastes and fluidized-bed combustion (FBC) wastes. This paper analyzed and summarized the generation, characteristics and application of TPP solid wastes and discussed the potential effects of such solid wastes on the environment. On this basis, a review of a number of methods for recovery of metals from TPP solid wastes was made. They usually contain a quantity of valuable metals and they are actually a secondary resource of metals. By applying mineral processing technologies and hydrometallurgical and biohydrometallurgical processes, it is possible to recover metals such as Al, Ga, Ge, Ca, Cd, Fe, Hg, Mg, Na, Ni, Pb, Ra, Th, V, Zn, etc., from TPP solid wastes. Recovery of metals from such wastes and its utilization are important not only for saving metal resources, but also for protecting the environment. Copyright © 2010 Elsevier Ltd. All rights reserved.

Lyophilization for Water Recovery From Solid Waste

NASA Technical Reports Server (NTRS)

Flynn, Michael; Litwiller, Eric; Reinhard, Martin

2003-01-01

This abstract describes the development of a solid waste treatment system designed for a near term human exploration mission. The technology being developed is an energy- efficient lyophilization technique that recovers water from spacecraft solid waste. In the lyophilization process water in an aqueous waste is frozen and then sublimed, resulting in the separation of the waste into a dried solid material and liquid water. This technology is ideally suited to applications where water recovery rates approaching 100% are desirable but production of CO, is not. Water contained within solid wastes accounts for approximately 3% of the total water balance. If 100% closure of the water loop is desired the water contained within this waste would need to be recovered. To facilitate operation in microgravity thermoelectric heat pumps have be used in place of traditional fluid cycle heat pumps. A mathematical model of a thermoelectric lyophilizer has been developed and used to generate energy use and processing rate parameters. The results of laboratory investigations and discussions with ALS program management have been used to iteratively arrive at a prototype design. This design address operational limitations which were identified in the laboratory studies and handling and health concerns raised by ALS program management. The current prototype design is capable of integration into the ISS Waste Collection System.

Application of computational methods to analyse and investigate physical and chemical processes of high-temperature mineralizing of condensed substances in gas stream

NASA Astrophysics Data System (ADS)

Markelov, A. Y.; Shiryaevskii, V. L.; Kudrinskiy, A. A.; Anpilov, S. V.; Bobrakov, A. N.

2017-11-01

A computational method of analysis of physical and chemical processes of high-temperature mineralizing of low-level radioactive waste in gas stream in the process of plasma treatment of radioactive waste in shaft furnaces was introduced. It was shown that the thermodynamic simulation method allows fairly adequately describing the changes in the composition of the pyrogas withdrawn from the shaft furnace at different waste treatment regimes. This offers a possibility of developing environmentally and economically viable technologies and small-sized low-cost facilities for plasma treatment of radioactive waste to be applied at currently operating nuclear power plants.

Spring 2004 Industry Study Final Report: Strategic Materials

DTIC Science & Technology

2004-01-01

decreasing processing costs. Processing costs can be reduced by using powder metallurgy technology to reduce waste and by seeking new markets to... market share is likely to remain fierce until the arrival of the next miniaturization technology , nanoelectromechanical system (NEMS). Smart...the transportation, medical, energy, information technology , and environmental industries will create the strongest economic pull for the

Technology Readiness Assessment of Department of Energy Waste Processing Facilities

DTIC Science & Technology

2007-09-11

Must Be Reliable, Robust, Flexible, and Durable 6 EM Is Piloting the TRA/AD2 Process Hanford Waste Treatment Plant ( WTP ) – The Initial Pilot Project...Evaluation WTP can only treat ~ ½ of the LAW in the time it will take to treat all the HLW. • There is a need for tank space that will get more urgent with...Facility before the WTP Pretreatment and High-Level Waste (HLW) Vitrification Facilities are available (Requires tank farm pretreatment capability) TRAs

CAV-OX CAVITATION OXIDIATION PROCESS - MAGNUM WATER TECHNOLOGY, INC. - APPLICATIONS ANALYSIS REPORT

EPA Science Inventory

This report evaluates the ability of the CAV-OX cavitation oxidation process to remove volatile organic compounds (VOC) present in aqueous wastes. This report also presents economic data based on the Superfund Innovative Technology Evaluation (SITE) Program demonstration and nine...

SILICATE TECHNOLOGY CORPORATION'S SOLIDIFICATION/ STABILIZATION TECHNOLOGY FOR ORGANIC AND INORGANIC CONTAMINANTS IN SOILS - APPLICATIONS ANALYSIS REPORT

EPA Science Inventory

This Applications Analysis Report evaluates the solidification/stabilization treatment process of Silicate Technology Corporation (STC) for the on-site treatment of hazardous waste. The STC immobilization technology utilizes a proprietary product (FMS Silicate) to chemically stab...

EM-21 Retrieval Knowledge Center: Waste Retrieval Challenges

DOE Office of Scientific and Technical Information (OSTI.GOV)

Fellinger, Andrew P.; Rinker, Michael W.; Berglin, Eric J.

EM-21 is the Waste Processing Division of the Office of Engineering and Technology, within the U.S. Department of Energy’s (DOE) Office of Environmental Management (EM). In August of 2008, EM-21 began an initiative to develop a Retrieval Knowledge Center (RKC) to provide the DOE, high level waste retrieval operators, and technology developers with centralized and focused location to share knowledge and expertise that will be used to address retrieval challenges across the DOE complex. The RKC is also designed to facilitate information sharing across the DOE Waste Site Complex through workshops, and a searchable database of waste retrieval technology information.more » The database may be used to research effective technology approaches for specific retrieval tasks and to take advantage of the lessons learned from previous operations. It is also expected to be effective for remaining current with state-of-the-art of retrieval technologies and ongoing development within the DOE Complex. To encourage collaboration of DOE sites with waste retrieval issues, the RKC team is co-led by the Savannah River National Laboratory (SRNL) and the Pacific Northwest National Laboratory (PNNL). Two RKC workshops were held in the Fall of 2008. The purpose of these workshops was to define top level waste retrieval functional areas, exchange lessons learned, and develop a path forward to support a strategic business plan focused on technology needs for retrieval. The primary participants involved in these workshops included retrieval personnel and laboratory staff that are associated with Hanford and Savannah River Sites since the majority of remaining DOE waste tanks are located at these sites. This report summarizes and documents the results of the initial RKC workshops. Technology challenges identified from these workshops and presented here are expected to be a key component to defining future RKC-directed tasks designed to facilitate tank waste retrieval solutions.« less

Sustainable conversion of coffee and other crop wastes to biofuels and bioproducts using coupled biochemical and thermochemical processes in a multi-stage biorefinery concept.

PubMed

Hughes, Stephen R; López-Núñez, Juan Carlos; Jones, Marjorie A; Moser, Bryan R; Cox, Elby J; Lindquist, Mitch; Galindo-Leva, Luz Angela; Riaño-Herrera, Néstor M; Rodriguez-Valencia, Nelson; Gast, Fernando; Cedeño, David L; Tasaki, Ken; Brown, Robert C; Darzins, Al; Brunner, Lane

2014-10-01

The environmental impact of agricultural waste from the processing of food and feed crops is an increasing concern worldwide. Concerted efforts are underway to develop sustainable practices for the disposal of residues from the processing of such crops as coffee, sugarcane, or corn. Coffee is crucial to the economies of many countries because its cultivation, processing, trading, and marketing provide employment for millions of people. In coffee-producing countries, improved technology for treatment of the significant amounts of coffee waste is critical to prevent ecological damage. This mini-review discusses a multi-stage biorefinery concept with the potential to convert waste produced at crop processing operations, such as coffee pulping stations, to valuable biofuels and bioproducts using biochemical and thermochemical conversion technologies. The initial bioconversion stage uses a mutant Kluyveromyces marxianus yeast strain to produce bioethanol from sugars. The resulting sugar-depleted solids (mostly protein) can be used in a second stage by the oleaginous yeast Yarrowia lipolytica to produce bio-based ammonia for fertilizer and are further degraded by Y. lipolytica proteases to peptides and free amino acids for animal feed. The lignocellulosic fraction can be ground and treated to release sugars for fermentation in a third stage by a recombinant cellulosic Saccharomyces cerevisiae, which can also be engineered to express valuable peptide products. The residual protein and lignin solids can be jet cooked and passed to a fourth-stage fermenter where Rhodotorula glutinis converts methane into isoprenoid intermediates. The residues can be combined and transferred into pyrocracking and hydroformylation reactions to convert ammonia, protein, isoprenes, lignins, and oils into renewable gas. Any remaining waste can be thermoconverted to biochar as a humus soil enhancer. The integration of multiple technologies for treatment of coffee waste has the potential to contribute to economic and environmental sustainability.

The Development of Environmentally Friendly Technologies of Using Coals and Products of Their Enrichment in the Form of Coal Water Slurries

NASA Astrophysics Data System (ADS)

Murko, Vasily; Hamalainen, Veniamin

2017-11-01

The article presents the current state of the technology for production and combustion of fuel coal water slurries in Russia and foreign countries. Experimental and industrial facilities show the technological and economic efficiency of using this technology for disposal of wastes resulting after coal processing and enrichment. The feasibility studies of use of the technology at large Kuzbass thermal power stations are presented. The possibility of solving a serious environmental problem of reducing storage of the most toxic waste of coal enrichment in the location areas of coal washing plants and coal mining enterprises is demonstrated.

The nitrate to ammonia and ceramic (NAC) process for the denitration and immobilization of low-level radioactive liquid waste (LLW)

NASA Astrophysics Data System (ADS)

Muguercia, Ivan

Hazardous radioactive liquid waste is the legacy of more than 50 years of plutonium production associated with the United States' nuclear weapons program. It is estimated that more than 245,000 tons of nitrate wastes are stored at facilities such as the single-shell tanks (SST) at the Hanford Site in the state of Washington, and the Melton Valley storage tanks at Oak Ridge National Laboratory (ORNL) in Tennessee. In order to develop an innovative, new technology for the destruction and immobilization of nitrate-based radioactive liquid waste, the United State Department of Energy (DOE) initiated the research project which resulted in the technology known as the Nitrate to Ammonia and Ceramic (NAC) process. However, inasmuch as the nitrate anion is highly mobile and difficult to immobilize, especially in relatively porous cement-based grout which has been used to date as a method for the immobilization of liquid waste, it presents a major obstacle to environmental clean-up initiatives. Thus, in an effort to contribute to the existing body of knowledge and enhance the efficacy of the NAC process, this research involved the experimental measurement of the rheological and heat transfer behaviors of the NAC product slurry and the determination of the optimal operating parameters for the continuous NAC chemical reaction process. Test results indicate that the NAC product slurry exhibits a typical non-Newtonian flow behavior. Correlation equations for the slurry's rheological properties and heat transfer rate in a pipe flow have been developed; these should prove valuable in the design of a full-scale NAC processing plant. The 20-percent slurry exhibited a typical dilatant (shear thickening) behavior and was in the turbulent flow regime due to its lower viscosity. The 40-percent slurry exhibited a typical pseudoplastic (shear thinning) behavior and remained in the laminar flow regime throughout its experimental range. The reactions were found to be more efficient in the lower temperature range investigated. With respect to leachability, the experimental final NAC ceramic waste form is comparable to the final product of vitrification, the technology chosen by DOE to treat these wastes. As the NAC process has the potential of reducing the volume of nitrate-based radioactive liquid waste by as much as 70 percent, it not only promises to enhance environmental remediation efforts but also effect substantial cost savings.

Hanford's Simulated Low Activity Waste Cast Stone Processing

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kim, Young

2013-08-20

Cast Stone is undergoing evaluation as the supplemental treatment technology for Hanford’s (Washington) high activity waste (HAW) and low activity waste (LAW). This report will only cover the LAW Cast Stone. The programs used for this simulated Cast Stone were gradient density change, compressive strength, and salt waste form phase identification. Gradient density changes show a favorable outcome by showing uniformity even though it was hypothesized differently. Compressive strength exceeded the minimum strength required by Hanford and greater compressive strength increase seen between the uses of different salt solution The salt waste form phase is still an ongoing process asmore » this time and could not be concluded.« less

Stabilization and Solidification of Nitric Acid Effluent Waste at Y-12

DOE Office of Scientific and Technical Information (OSTI.GOV)

Singh, Dileep; Lorenzo-Martin, Cinta

Consolidated Nuclear Security, LLC (CNS) at the Y-12 plant is investigating approaches for the treatment (stabilization and solidification) of a nitric acid waste effluent that contains uranium. Because the pH of the waste stream is 1-2, it is a difficult waste stream to treat and stabilize by a standard cement-based process. Alternative waste forms are being considered. In this regard, Ceramicrete technology, developed at Argonne National Laboratory, is being explored as an option to solidify and stabilize the nitric acid effluent wastes.

40 CFR 240.205-2 - Recommended procedures: Design.

Code of Federal Regulations, 2010 CFR

2010-07-01

....205-2 Section 240.205-2 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES GUIDELINES FOR THE THERMAL PROCESSING OF SOLID WASTES Requirements and Recommended Procedures... air pollution control technology. (b) All emissions, including dust from vents, should be controlled. ...

40 CFR 240.205-2 - Recommended procedures: Design.

Code of Federal Regulations, 2011 CFR

2011-07-01

....205-2 Section 240.205-2 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES GUIDELINES FOR THE THERMAL PROCESSING OF SOLID WASTES Requirements and Recommended Procedures... air pollution control technology. (b) All emissions, including dust from vents, should be controlled. ...

A study of the impact of moist-heat and dry-heat treatment processes on hazardous trace elements migration in food waste.

PubMed

Chen, Ting; Jin, Yiying; Qiu, Xiaopeng; Chen, Xin

2015-03-01

Using laboratory experiments, the authors investigated the impact of dry-heat and moist-heat treatment processes on hazardous trace elements (As, Hg, Cd, Cr, and Pb) in food waste and explored their distribution patterns for three waste components: oil, aqueous, and solid components. The results indicated that an insignificant reduction of hazardous trace elements in heat-treated waste-0.61-14.29% after moist-heat treatment and 4.53-12.25% after dry-heat treatment-and a significant reduction in hazardous trace elements (except for Hg without external addition) after centrifugal dehydration (P < 0.5). Moreover, after heat treatment, over 90% of the hazardous trace elements in the waste were detected in the aqueous and solid components, whereas only a trace amount of hazardous trace elements was detected in the oil component (<0.01%). In addition, results indicated that heat treatment process did not significantly reduce the concentration of hazardous trace elements in food waste, but the separation process for solid and aqueous components, such as centrifugal dehydration, could reduce the risk considerably. Finally, combined with the separation technology for solid and liquid components, dry-heat treatment is superior to moist-heat treatment on the removal of external water-soluble ionic hazardous trace elements. An insignificant reduction of hazardous trace elements in heat-treated waste showed that heat treatment does not reduce trace elements contamination in food waste considerably, whereas the separation process for solid and aqueous components, such as centrifugal dehydration, could reduce the risk significantly. Moreover, combined with the separation technology for solid and liquid components, dry-heat treatment is superior to moist-heat treatment for the removal of external water-soluble ionic hazardous trace elements, by exploring distribution patterns of trace elements in three waste components: oil, aqueous, and solid components.

Effective dialogue: Enhanced public engagement as a legitimising tool for municipal waste management decision-making

DOE Office of Scientific and Technical Information (OSTI.GOV)

Garnett, Kenisha, E-mail: k.garnett@cranfield.ac.uk; Cooper, Tim, E-mail: t.h.cooper@ntu.ac.uk

2014-12-15

Highlights: • A review of public engagement in waste management decision-making is undertaken. • Enhanced public engagement is explored as a means to legitimise waste decisions. • Analytical–deliberative processes are explored as a tool for effective dialogue. • Considerations for integrating public values with technical analysis are outlined. • Insights into the design of appropriate public engagement processes are provided. - Abstract: The complexity of municipal waste management decision-making has increased in recent years, accompanied by growing scrutiny from stakeholders, including local communities. This complexity reflects a socio-technical framing of the risks and social impacts associated with selecting technologies andmore » sites for waste treatment and disposal facilities. Consequently there is growing pressure on local authorities for stakeholders (including communities) to be given an early opportunity to shape local waste policy in order to encourage swift planning, development and acceptance of the technologies needed to meet statutory targets to divert waste from landfill. This paper presents findings from a research project that explored the use of analytical–deliberative processes as a legitimising tool for waste management decision-making. Adopting a mixed methods approach, the study revealed that communicating the practical benefits of more inclusive forms of engagement is proving difficult even though planning and policy delays are hindering development and implementation of waste management infrastructure. Adopting analytical–deliberative processes at a more strategic level will require local authorities and practitioners to demonstrate how expert-citizen deliberations may foster progress in resolving controversial issues, through change in individuals, communities and institutions. The findings suggest that a significant shift in culture will be necessary for local authorities to realise the potential of more inclusive decision processes. This calls for political actors and civic society to collaborate in institutionalising public involvement in both strategic and local planning structures.« less

Diagnostics for a waste processing plasma arc furnace (invited) (abstract)a)

NASA Astrophysics Data System (ADS)

Woskov, P. P.

1995-01-01

Maintaining the quality of our environment has become an important goal of society. As part of this goal new technologies are being sought to clean up hazardous waste sites and to treat ongoing waste streams. A 1 MW pilot scale dc graphite electrode plasma arc furnace (Mark II) has been constructed at MIT under a joint program among Pacific Northwest Laboratory (PNL), MIT, and Electro-Pyrolysis, Inc. (EPI)c) for the remediation of buried wastes in the DOE complex. A key part of this program is the development of new and improved diagnostics to study, monitor, and control the entire waste remediation process for the optimization of this technology and to safeguard the environment. Continuous, real time diagnostics are needed for a variety of the waste process parameters. These parameters include internal furnace temperatures, slag fill levels, trace metals content in the off-gas stream, off-gas molecular content, feed and slag characterization, and off-gas particulate size, density, and velocity distributions. Diagnostics are currently being tested at MIT for the first three parameters. An active millimeter-wave radiometer with a novel, rotatable graphite waveguide/mirror antenna system has been implemented on Mark II for the measurement of surface emission and emissivity which can be used to determine internal furnace temperatures and fill levels. A microwave torch plasma is being evaluated for use as a excitation source in the furnace off-gas stream for continuous atomic emission spectroscopy of trace metals. These diagnostics should find applicability not only to waste remediation, but also to other high temperature processes such as incinerators, power plants, and steel plants.

Preliminary survey of separations technology applicable to the pretreatment of Hanford tank waste (1992--1993)

DOE Office of Scientific and Technical Information (OSTI.GOV)

Lawrence, W.E.; Kurath, D.E.

1994-04-01

The US Department of Energy has established the Tank Waste Remediation System (TWRS) to manage and dispose of radioactive wastes stored at the Hanford Site. Within this program are evaluations of pretreatment system alternatives through literature reviews. The information in this report was collected as part of this project at Pacific Northwest Laboratory. A preliminary survey of literature on separations recently entered into the Hanford electronic databases (1992--1993) that have the potential for pretreatment of Hanford tank waste was conducted. Separation processes that can assist in the removal of actinides (uranium, plutonium, americium), lanthanides, barium, {sup 137}Cs, {sup 90}Sr,{sup 129more » }I, {sup 63}Ni, and {sup 99}Tc were evaluated. Separation processes of interest were identified through literature searches, journal reviews, and participation in separation technology conferences. This report contains brief descriptions of the potential separation processes, the extent and/or selectivity of the separation, the experimental conditions, and observations. Information was collected on both national and international separation studies to provide a global perspective on recent research efforts.« less

FY 1994 program summary: Office of Technology Development, Office of Research and Development, Office of Demonstration, Testing, and Evaluation

DOE Office of Scientific and Technical Information (OSTI.GOV)

Not Available

1994-10-01

The US Department of Energy (DOE) Office of Environmental Management, formerly the Office of Environmental Restoration and Waste Management (EM), was established in November 1989 as the first step toward correcting contamination problems resulting from nearly 50 years of nuclear weapons production and fuel processing activities. EM consolidates several DOE organizations previously responsible for the handling, treatment, and disposition of radioactive and hazardous waste. Within EM, the Office of Technology Development (OTD/EM-50) is responsible for developing technologies to meet DOE`s goal for environmental restoration. OTD manages an aggressive national program of applied research, development, demonstration, testing, and evaluation (RDDT andmore » E) for environmental cleanup, waste management, and related technologies. The program is designed to resolve major technical issues, to rapidly advanced beyond current technologies for environmental restoration and waste management operations, and to expedite compliance with applicable environmental laws and regulations. This report summarizes Fiscal Year 1994 (FY94) programmatic information, accomplishments, and planned activities relevant to the individual activities within OTD`s RDDT and E.« less

TREATABILITY STUDY REPORT OF GREEN MOUNTAIN LABORATORIES, INC.'S BIOREMEDIATION PROCESS, TREATMENT OF PCB CONTAMINATED SOILS, AT BEEDE WASTE OIL/CASH ENERGY SUPERFUND SITE, PLAISTOW, NEW HAMPSHIRE

EPA Science Inventory

In 1998, Green Mountain Laboratories, Inc. (GML) and the USEPA agreed to carry out a Superfund Innovative Technology Evaluation (SITE) project to evaluate the effectiveness of GML's Bioremediation Process for the treatment of PCB contaminated soils at the Beede Waste Oil/Cash Ene...

Short mechanical biological treatment of municipal solid waste allows landfill impact reduction saving waste energy content.

PubMed

Scaglia, Barbara; Salati, Silvia; Di Gregorio, Alessandra; Carrera, Alberto; Tambone, Fulvia; Adani, Fabrizio

2013-09-01

The aim of this work was to evaluate the effects of full scale MBT process (28 d) in removing inhibition condition for successive biogas (ABP) production in landfill and in reducing total waste impact. For this purpose the organic fraction of MSW was treated in a full-scale MBT plant and successively incubated vs. untreated waste, in simulated landfills for one year. Results showed that untreated landfilled-waste gave a total ABP reduction that was null. On the contrary MBT process reduced ABP of 44%, but successive incubation for one year in landfill gave a total ABP reduction of 86%. This ABP reduction corresponded to a MBT process of 22 weeks length, according to the predictive regression developed for ABP reduction vs. MBT-time. Therefore short MBT allowed reducing landfill impact, preserving energy content (ABP) to be produced successively by bioreactor technology since pre-treatment avoided process inhibition because of partial waste biostabilization. Copyright © 2013 Elsevier Ltd. All rights reserved.

Fossil Energy Program

NASA Astrophysics Data System (ADS)

McNeese, L. E.

1981-01-01

Increased utilization of coal and other fossil fuel alternatives as sources of clean energy is reported. The following topics are discussed: coal conversion development, chemical research and development, materials technology, component development and process evaluation studies, technical support to major liquefaction projects, process analysis and engineering evaluations, fossil energy environmental analysis, flue gas desulfurization, solid waste disposal, coal preparation waste utilization, plant control development, atmospheric fluidized bed coal combustor for cogeneration, TVA FBC demonstration plant program technical support, PFBC systems analysis, fossil fuel applications assessments, performance assurance system support for fossil energy projects, international energy technology assessment, and general equilibrium models of liquid and gaseous fuel supplies.

US Department of Energy's Efforts in Intelligent Processing Equipment

NASA Technical Reports Server (NTRS)

Peavy, Richard D.; Mcfarland, Janet C.

1992-01-01

The Department of Energy (DOE) uses intelligent processing equipment (IPE) technologies to conduct research and development and manufacturing for energy and nuclear weapons programs. This paper highlights several significant IPE efforts underway in DOE. IPE technologies are essential to the accomplishment of DOE's missions, because of the need for small lot production, precision, and accuracy in manufacturing, hazardous waste management, and protection of the environment and the safety and health of the workforce and public. Applications of IPE technologies include environmental remediation and waste handling, advanced manufacturing, and automation of tasks carried out in hazardous areas. DOE laboratories have several key programs that integrate robotics, sensor, and control technologies. These programs embody a considerable technical capability that also may be used to enhance U.S. industrial competitiveness. DOE encourages closer cooperation with U.S. industrial partners based on mutual benefits. This paper briefly describes technology transfer mechanisms available for industrial involvement.

Waste Printed Circuit Board (PCB) Recycling Techniques.

PubMed

Ning, Chao; Lin, Carol Sze Ki; Hui, David Chi Wai; McKay, Gordon

2017-04-01

With the development of technologies and the change of consumer attitudes, the amount of waste electrical and electronic equipment (WEEE) is increasing annually. As the core part of WEEE, the waste printed circuit board (WPCB) is a dangerous waste but at the same time a rich resource for various kinds of materials. In this work, various WPCB treatment methods as well as WPCB recycling techniques divided into direct treatment (landfill and incineration), primitive recycling technology (pyrometallurgy, hydrometallurgy, biometallurgy and primitive full recovery of NMF-non metallic fraction), and advanced recycling technology (mechanical separation, direct use and modification of NMF) are reviewed and analyzed based on their advantages and disadvantages. Also, the evaluation criteria are discussed including economic, environmental, and gate-to-market ability. This review indicates the future research direction of WPCB recycling should focus on a combination of several techniques or in series recycling to maximize the benefits of process.

Engineering solutions of environmental problems in organic waste handling

NASA Astrophysics Data System (ADS)

Briukhanov, A. Y.; Vasilev, E. V.; Shalavina, E. V.; Kucheruk, O. N.

2017-10-01

This study shows the urgent need to consider modernization of agricultural production in terms of sustainable development, which takes into account environmental implications of intensive technologies in livestock farming. Some science-based approaches are offered to address related environmental challenges. High-end technologies of organic livestock waste processing were substantiated by the feasibility study and nutrient balance calculation. The technologies were assessed on the basis of best available techniques criteria, including measures such as specific capital and operational costs associated with nutrient conservation and their delivery to the plants.

A case-study of landfill minimization and material recovery via waste co-gasification in a new waste management scheme.

PubMed

Tanigaki, Nobuhiro; Ishida, Yoshihiro; Osada, Morihiro

2015-03-01

This study evaluates municipal solid waste co-gasification technology and a new solid waste management scheme, which can minimize final landfill amounts and maximize material recycled from waste. This new scheme is considered for a region where bottom ash and incombustibles are landfilled or not allowed to be recycled due to their toxic heavy metal concentration. Waste is processed with incombustible residues and an incineration bottom ash discharged from existent conventional incinerators, using a gasification and melting technology (the Direct Melting System). The inert materials, contained in municipal solid waste, incombustibles and bottom ash, are recycled as slag and metal in this process as well as energy recovery. Based on this new waste management scheme with a co-gasification system, a case study of municipal solid waste co-gasification was evaluated and compared with other technical solutions, such as conventional incineration, incineration with an ash melting facility under certain boundary conditions. From a technical point of view, co-gasification produced high quality slag with few harmful heavy metals, which was recycled completely without requiring any further post-treatment such as aging. As a consequence, the co-gasification system had an economical advantage over other systems because of its material recovery and minimization of the final landfill amount. Sensitivity analyses of landfill cost, power price and inert materials in waste were also conducted. The higher the landfill costs, the greater the advantage of the co-gasification system has. The co-gasification was beneficial for landfill cost in the range of 80 Euro per ton or more. Higher power prices led to lower operation cost in each case. The inert contents in processed waste had a significant influence on the operating cost. These results indicate that co-gasification of bottom ash and incombustibles with municipal solid waste contributes to minimizing the final landfill amount and has great possibilities maximizing material recovery and energy recovery from waste. Copyright © 2014 Elsevier Ltd. All rights reserved.

Balanced program plan. Analysis for biomedical and environmental research

DOE Office of Scientific and Technical Information (OSTI.GOV)

Not Available

1976-06-01

Major issues associated with the use of nuclear power are health hazards of exposure to radioactive materials; sources of radiation exposure; reactor accidents; sabotage of nuclear facilities; diversion of fissile material and its use for extortion; and the presence of plutonium in the environment. Fission fuel cycle technology is discussed with regard to milling, UF/sub 6/ production, uranium enrichment, plutonium fuel fabrication, power production, fuel processing, waste management, and fuel and waste transportation. The following problem areas of fuel cycle technology are briefly discussed: characterization, measurement, and monitoring; transport processes; health effects; ecological processes and effects; and integrated assessment. Estimatedmore » program unit costs are summarized by King-Muir Category. (HLW)« less

Corrosion probe. Innovative technology summary report

DOE Office of Scientific and Technical Information (OSTI.GOV)

NONE

Over 253 million liters of high-level waste (HLW) generated from plutonium production is stored in mild steel tanks at the Department of Energy (DOE) Hanford Site. Corrosion monitoring of double-shell storage tanks (DSTs) is currently performed at Hanford using a combination of process knowledge and tank waste sampling and analysis. Available technologies for corrosion monitoring have progressed to a point where it is feasible to monitor and control corrosion by on-line monitoring of the corrosion process and direct addition of corrosion inhibitors. The electrochemical noise (EN) technique deploys EN-based corrosion monitoring probes into storage tanks. This system is specifically designedmore » to measure corrosion rates and detect changes in waste chemistry that trigger the onset of pitting and cracking. These on-line probes can determine whether additional corrosion inhibitor is required and, if so, provide information on an effective end point to the corrosion inhibitor addition procedure. This report describes the technology, its performance, its application, costs, regulatory and policy issues, and lessons learned.« less

Nitrogen cycling in Bioregenerative Life Support Systems: Challenges for waste refinery and food production processes

NASA Astrophysics Data System (ADS)

Clauwaert, Peter; Muys, Maarten; Alloul, Abbas; De Paepe, Jolien; Luther, Amanda; Sun, Xiaoyan; Ilgrande, Chiara; Christiaens, Marlies E. R.; Hu, Xiaona; Zhang, Dongdong; Lindeboom, Ralph E. F.; Sas, Benedikt; Rabaey, Korneel; Boon, Nico; Ronsse, Frederik; Geelen, Danny; Vlaeminck, Siegfried E.

2017-05-01

In order to sustain human life in an isolated environment, an efficient conversion of wasted nutrients to food might become mandatory. This is particularly the case for space missions where resupply from earth or in-situ resource utilization is not possible or desirable. A combination of different technologies is needed to allow full recycling of e.g. nitrogenous compounds in space. In this review, an overview is given of the different essential processes and technologies that enable closure of the nitrogen cycle in Bioregenerative Life Support Systems (BLSS). Firstly, a set of biological and physicochemical refinery stages ensures efficient conversion of waste products into the building blocks, followed by the production of food with a range of biological methods. For each technology, bottlenecks are identified. Furthermore, challenges and outlooks are presented at the integrated system level. Space adaptation and integration deserve key attention to enable the recovery of nitrogen for the production of nutritional food in space, but also in closed loop systems on earth.

Chelation technology: a promising green approach for resource management and waste minimization.

PubMed

Chauhan, Garima; Pant, K K; Nigam, K D P

2015-01-01

Green chemical engineering recognises the concept of developing innovative environmentally benign technologies to protect human health and ecosystems. In order to explore this concept for minimizing industrial waste and for reducing the environmental impact of hazardous chemicals, new greener approaches need to be adopted for the extraction of heavy metals from industrial waste. In this review, a range of conventional processes and new green approaches employed for metal extraction are discussed in brief. Chelation technology, a modern research trend, has shown its potential to develop sustainable technology for metal extraction from various metal-contaminated sites. However, the interaction mechanism of ligands with metals and the ecotoxicological risk associated with the increased bioavailability of heavy metals due to the formation of metal-chelant complexes is still not sufficiently explicated in the literature. Therefore, a need was felt to provide a comprehensive state-of-the-art review of all aspects associated with chelation technology to promote this process as a green chemical engineering approach. This article elucidates the mechanism and thermodynamics associated with metal-ligand complexation in order to have a better understanding of the metal extraction process. The effects of various process parameters on the formation and stability of complexes have been elaborately discussed with respect to optimizing the chelation efficiency. The non-biodegradable attribute of ligands is another important aspect which is currently of concern. Therefore, biotechnological approaches and computational tools have been assessed in this review to illustrate the possibility of ligand degradation, which will help the readers to look for new environmentally safe mobilizing agents. In addition, emerging trends and opportunities in the field of chelation technology have been summarized and the diverse applicability of chelation technology in metal extraction from contaminated sites has also been reviewed.

Characterization, monitoring, and sensor technology catalogue

DOE Office of Scientific and Technical Information (OSTI.GOV)

Matalucci, R.V.; Esparza-Baca, C.; Jimenez, R.D.

1995-12-01

This document represents a summary of 58 technologies that are being developed by the Department of Energy`s (DOE`s) Office of Science and Technology (OST) to provide site, waste, and process characterization and monitoring solutions to the DOE weapons complex. The information was compiled to provide performance data on OST-developed technologies to scientists and engineers responsible for preparing Remedial Investigation/Feasibility Studies (RI/FSs) and preparing plans and compliance documents for DOE cleanup and waste management programs. The information may also be used to identify opportunities for partnering and commercialization with industry, DOE laboratories, other federal and state agencies, and the academic community.more » Each technology is featured in a format that provides: (1) a description, (2) technical performance data, (3) applicability, (4) development status, (5) regulatory considerations, (6) potential commercial applications, (7) intellectual property, and (8) points-of-contact. Technologies are categorized into the following areas: (1) Bioremediation Monitoring, (2) Decontamination and Decommissioning, (3) Field Analytical Laboratories, (4) Geophysical and Hydrologic Characterization, (5) Hazardous Inorganic Contaminant Analysis, (6) Hazardous Organic Contaminant Analysis, (7) Mixed Waste, (8) Radioactive Contaminant Analysis, (9) Remote Sensing,(10)Sampling and Drilling, (11) Statistically Guided Sampling, and (12) Tank Waste.« less

Production of Caproic Acid from Mixed Organic Waste: An Environmental Life Cycle Perspective

PubMed Central

2017-01-01

Caproic acid is an emerging platform chemical with diverse applications. Recently, a novel biorefinery process, that is, chain elongation, was developed to convert mixed organic waste and ethanol into renewable caproic acids. In the coming years, this process may become commercialized, and continuing to improve on the basis of numerous ongoing technological and microbiological studies. This study aims to analyze the environmental performance of caproic acid production from mixed organic waste via chain elongation at this current, early stage of technological development. To this end, a life cycle assessment (LCA) was performed to evaluate the environmental impact of producing 1 kg caproic acid from organic waste via chain elongation, in both a lab-scale and a pilot-scale system. Two mixed organic waste were used as substrates: the organic fraction of municipal solid waste (OFMSW) and supermarket food waste (SFW). Ethanol use was found to be the dominant cause of environmental impact over the life cycle. Extraction solvent recovery was found to be a crucial uncertainty that may have a substantial influence on the life-cycle impacts. We recommend that future research and industrial producers focus on the reduction of ethanol use in chain elongation and improve the recovery efficiency of the extraction solvent. PMID:28513150

[Organic waste treatment by earthworm vermicomposting and larvae bioconversion: review and perspective].

PubMed

Zhang, Zhi-jian; Liu, Meng; Zhu, Jun

2013-05-01

There is a growing attention on the environmental pollution and loss of potential regeneration of resources due to the poor handling of organic wastes, while earthworm vermicomposting and larvae bioconversion are well-known as two promising biotechnologies for sustainable wastes treatments, where earthworms or housefly larvae are employed to convert the organic wastes into humus like material, together with value-added worm product. Taken earthworm ( Eisenia foetida) and housefly larvae ( Musca domestica) as model species, this work illustrates fundamental definition and principle, operational process, technical mechanism, main factors, and bio-chemical features of organisms of these two technologies. Integrated with the physical and biochemical mechanisms, processes of biomass conversion, intestinal digestion, enzyme degradation and microflora decomposition are comprehensively reviewed on waste treatments with purposes of waste reduction, value-addition, and stabilization.

DOE Office of Scientific and Technical Information (OSTI.GOV)

SAMS TL; GUILLOT S

Scoping laboratory scale tests were performed at the Chemical Engineering Department of the Georgia Institute of Technology (Georgia Tech), and the Hanford 222-S Laboratory, involving double-shell tank (DST) and single-shell tank (SST) Hanford waste simulants. These tests established the viability of the Lithium Hydrotalcite precipitation process as a solution to remove aluminum and recycle sodium hydroxide from the Hanford tank waste, and set the basis of a validation test campaign to demonstrate a Technology Readiness Level of 3.

Effective dialogue: enhanced public engagement as a legitimising tool for municipal waste management decision-making.

PubMed

Garnett, Kenisha; Cooper, Tim

2014-12-01

The complexity of municipal waste management decision-making has increased in recent years, accompanied by growing scrutiny from stakeholders, including local communities. This complexity reflects a socio-technical framing of the risks and social impacts associated with selecting technologies and sites for waste treatment and disposal facilities. Consequently there is growing pressure on local authorities for stakeholders (including communities) to be given an early opportunity to shape local waste policy in order to encourage swift planning, development and acceptance of the technologies needed to meet statutory targets to divert waste from landfill. This paper presents findings from a research project that explored the use of analytical-deliberative processes as a legitimising tool for waste management decision-making. Adopting a mixed methods approach, the study revealed that communicating the practical benefits of more inclusive forms of engagement is proving difficult even though planning and policy delays are hindering development and implementation of waste management infrastructure. Adopting analytical-deliberative processes at a more strategic level will require local authorities and practitioners to demonstrate how expert-citizen deliberations may foster progress in resolving controversial issues, through change in individuals, communities and institutions. The findings suggest that a significant shift in culture will be necessary for local authorities to realise the potential of more inclusive decision processes. This calls for political actors and civic society to collaborate in institutionalising public involvement in both strategic and local planning structures. Copyright © 2014 Elsevier Ltd. All rights reserved.

Characterisation of metals in the electronic waste of complex mixtures of end-of-life ICT products for development of cleaner recovery technology

DOE Office of Scientific and Technical Information (OSTI.GOV)

Sun, Z.H.I.; Xiao, Y.; Sietsma, J.

2015-01-15

Highlights: • New characterisation methodology has been established to understand an industrially processed ICT waste. • Particle size distribution, composition, thermal–chemical behaviour and occurrence of metals were considered. • The characterisation provides direct guidelines for values recovery from the waste. - Abstract: Recycling of valuable metals from electronic waste, especially complex mixtures of end-of-life information and communication technology (ICT) products, is of great difficulty due to their complexity and heterogeneity. One of the important reasons is the lack of comprehensive characterisation on such materials, i.e. accurate compositions, physical/chemical properties. In the present research, we focus on developing methodologies for themore » characterisation of metals in an industrially processed ICT waste. The morphology, particle size distribution, compositional distribution, occurrence, liberation as well as the thermo-chemical properties of the ICT waste were investigated with various characterisation techniques, including X-ray Fluorescence Spectrometry (XRF), differential scanning calorimetry (DSC) and scanning electron microscopy (SEM) with energy dispersed spectroscopy (EDS). Due to the high heterogeneity of the material, special sample preparation procedures were introduced to minimise the discrepancies during compositional analyses. As a result, a clearer overview of the ICT waste has been reached. This research provides better understanding of the extractability of each metal and improves the awareness of potential obstacles for extraction. It will lead to smarter decisions during further development of a clean and effective recovery process.« less

[Recent advance in solidification/stabilization technology for the remediation of heavy metals-contaminated soil].

PubMed

Hao, Han-zhou; Chen, Tong-bin; Jin, Meng-gui; Lei, Mei; Liu, Cheng-wu; Zu, Wen-pu; Huang, Li-mi

2011-03-01

Remediation of heavy metals-contaminated soil is still a difficulty and a hotspot of international research projects. At present, the technologies commonly adopted for the remediation of contaminated sites mainly include excavation, solidification/stabilization (S/S), soil washing, soil vapor extraction (SVE), thermal treatment, and bioremediation. Based on the S/S technical guidelines of Unite State Environmental Protection Agency (EPA) and United Kingdom Environment Agency (EA) and the domestic and foreign patents, this paper introduced the concepts of S/S and its development status at home and abroad, and discussed its future development directions. Solidification refers to a process that binds contaminated media with a reagent, changing the media's physical properties via increasing its compressive strength, decreasing its permeability, and encapsulating the contaminants to form a solid material. Stabilization refers to the process that involves a chemical reaction which reduces the leachability of a waste, chemically immobilizes the waste and reduces its solubility, making the waste become less harmful or less mobile. S/S technology includes cement solidification, lime pozzolanic solidification, plastic materials stabilization, vitrification, and regent-based stabilization. Stabilization (or immobilization) treatment processes convert contaminants to less mobile forms through chemical or thermal interactions. In stabilization technology, the aim of adding agents is to change the soil physical and chemical properties through pH control technology, redox potential technology, precipitation techniques, adsorption technology, and ion-exchange technology that change the existing forms of heavy metals in soil, and thus, reduce the heavy metals bioavailability and mobility. This review also discussed the S/S evaluation methods, highlighted the need to enhance S/S technology in the molecular bonding, soil polymers, and formulation of China's S/S technical guidelines.

CAPSULE REPORT: SOURCES AND AIR EMISSION CONTROL TECHNOLOGIES AT WASTE MANAGEMENT FACILITIES

EPA Science Inventory

The chemicals processed during waste management operations can volatilize into the atmosphere and cause carcinogenic or other toxic effects or contribute to ozone formation. Regulations have been developed to control air emissions from these operations. The EPA has promulgated st...

CONTROLLING EMISSIONS FROM FUEL AND WASTE COMBUSTION

EPA Science Inventory

Control of emissions from combustion of fuels and wastes has been a traditional focus of air pollution regulations. Significant technology developments of the '50s and '60s have been refined into reliable chemical and physical process unit operations. In the U.S., acid rain legis...

Metal Recovery from Industrial Solid Waste — Contribution to Resource Sustainability

NASA Astrophysics Data System (ADS)

Yang, Yongxiang

Increased demand of metals has driven the accelerated mining and metallurgical production in recent years, causing fast depletion of primary metals resources. On the contrary, the mining and metallurgical industry generates large amount of solid residues and waste such as tailings, slags, flue dust and leach residues, with relative low valuable metal contents. On the other hand, end-of-life (EoL) consumer products form another significant resources. The current technology and processes for primary metals production are not readily applicable for direct metals extraction from these waste materials, and special adaptation and tailor-made processes are required. In the present paper, various solid waste resources are reviewed, and current technologies and R&D trends are discussed. The recent research at author's group is illustrated for providing potential solutions to future resource problems, including metal recovery from MSW incinerator bottom ashes, zinc recovery from industrial ashes and residues, and rare earth metals recovery from EoL permanent magnets.

Environmental impacts and benefits of state-of-the-art technologies for E-waste management.

PubMed

Ikhlayel, Mahdi

2017-10-01

This study aims to evaluate the environmental impacts and benefits of state-of-the-art technologies for proper e-waste handling using Jordan as a case study. Life Cycle Assessment (LCA) was employed to evaluate five advanced management systems represent state-of-the-art treatment technologies, including sanitary landfilling; proper recycling of metals, materials, and precious metals (PMs); and incineration of plastic and the hazardous portion of printed circuit boards (PCBs). Six e-waste products that contribute the most to the e-waste in Jordan were included in the assessment of each scenario, which resulted in 30 total cases of e-waste management. The findings indicated that landfills for the entire components of the e-waste stream are the worst option and should be avoided. The most promising e-waste management scenario features integrated e-waste processes based on the concept of Integrated Waste Management (IWM), including recycling materials such as non-PMs and PMs, incinerating plastic and the hazardous content of PCBs using the energy recovered from incineration, and using sanitary landfills of residues. For this scenario, the best environmental performance was obtained for the treatment of mobile phones. Incineration of the portion of hazardous waste using energy recovery is an option that deserves attention. Because scenario implementation depends on more than just the environmental benefits (e.g., economic cost and technical aspects), the study proposes a systematic approach founded on the IWM concept for e-waste management scenario selection. Copyright © 2017 Elsevier Ltd. All rights reserved.

Methods of Responsibly Managing End-of-Life Foams and Plastics Containing Flame Retardants: Part II.

PubMed

Lucas, Donald; Petty, Sara M; Keen, Olya; Luedeka, Bob; Schlummer, Martin; Weber, Roland; Yazdani, Ramin; Riise, Brian; Rhodes, James; Nightingale, Dave; Diamond, Miriam L; Vijgen, John; Lindeman, Avery; Blum, Arlene; Koshland, Catherine P

2018-06-01

This is Part II of a review covering the wide range of issues associated with all aspects of the use and responsible disposal of foam and plastic wastes containing toxic or potentially toxic flame retardants. We identify basic and applied research needs in the areas of responsible collection, pretreatment, processing, and management of these wastes. In Part II, we explore alternative technologies for the management of halogenated flame retardant (HFR) containing wastes, including chemical, mechanical, and thermal processes for recycling, treatment, and disposal.

On-site low level radwaste storage facility

DOE Office of Scientific and Technical Information (OSTI.GOV)

Knauss, C.H.; Gardner, D.A.

1993-12-31

This paper will explore several storage and processing technologies that are available for the safe storage of low-level waste, their advantages and their limitations such that potential users may be able to determine which technology may be most appropriate for their particular application. Also, a brief discussion will be included on available types of shipping and disposal containers and waste forms for use in those containers when ready for ultimate disposal. For the purposes of this paper, the waste streams considered will be restricted to nuclear power plant wastes. Wastes that will be discussed are powdered and bead resins formore » cooling and reactor water clean-up, filter cartridges, solidified waste oils, and Dry Active Wastes (DAW), which consist of contaminated clothing, tools, respirator filters, etc. On-site storage methods that will be analyzed include a storage facility constructed of individual temporary shielded waste containers on a hard surface; an on-site, self contained low level radwaste facility for resins and filters; and an on-site storage and volume reduction facility for resins and filters; and an on-site DAW. Simple, warehouse-type buildings and pre-engineered metal buildings will be discussed only to a limited degree since dose rate projections can be high due to their lack of adequate shielding for radiation protection. Waste processing alternatives that will be analyzed for resins include dewatering, solidifying in Portland cement, solidifying in bituminous material, and solidifying in a vinyl ester styrene matrix. The storage methods describes will be analyzed for their ability to shield the populace from the effects of direct transmission and skyshine radiation when storing the above mentioned materials, which have been properly processed for storage and have been placed in suitable storage containers.« less

Gaseous emissions from waste combustion.

PubMed

Werther, Joachim

2007-06-18

An overview is given on methods and technologies for limiting the gaseous emissions from waste combustion. With the guideline 2000/76/EC recent European legislation has set stringent limits not only for the mono-combustion of waste in specialized incineration plants but also for co-combustion in coal-fired power plants. With increased awareness of environmental issues and stepwise decrease of emission limits and inclusion of more and more substances into the network of regulations a multitude of emission abatement methods and technologies have been developed over the last decades. The result is the state-of-the-art waste incinerator with a number of specialized process steps for the individual components in the flue gas. The present work highlights some new developments which can be summarized under the common goal of reducing the costs of flue gas treatment by applying systems which combine the treatment of several noxious substances in one reactor or by taking new, simpler routes instead of the previously used complicated ones or - in the case of flue gas desulphurisation - by reducing the amount of limestone consumption. Cost reduction is also the driving force for new processes of conditioning of nonhomogenous waste before combustion. Pyrolysis or gasification is used for chemical conditioning whereas physical conditioning means comminution, classification and sorting processes. Conditioning yields a fuel which can be used in power plants either as a co-fuel or a mono-fuel and which will burn there under much better controlled conditions and therefore with less emissions than the nonhomogeneous waste in a conventional waste incinerator. Also for cost reasons, co-combustion of wastes in coal-fired power stations is strongly pressing into the market. Recent investigations reveal that the co-firing of waste can also have beneficial effects on the operating behavior of the boiler and on the gaseous emissions.

Laboratory Reactor for Processing Carbon-Containing Sludge

NASA Astrophysics Data System (ADS)

Korovin, I. O.; Medvedev, A. V.

2016-10-01

The paper describes a reactor for high-temperature pyrolysis of carbon-containing sludge with the possibility of further development of environmentally safe technology of hydrocarbon waste disposal to produce secondary products. A solution of the urgent problem has been found: prevention of environmental pollution resulting from oil pollution of soils using the pyrolysis process as a method of disposal of hydrocarbon waste to produce secondary products.

Acid and alkaline solubilization (pH shift) process: a better approach for the utilization of fish processing waste and by-products.

PubMed

Surasani, Vijay Kumar Reddy

2018-05-22

Several technologies and methods have been developed over the years to address the environmental pollution and nutritional losses associated with the dumping of fish processing waste and low-cost fish and by-products. Despite the continuous efforts put in this field, none of the developed technologies was successful in addressing the issues due to various technical problems. To solve the problems associated with the fish processing waste and low-value fish and by-products, a process called pH shift/acid and alkaline solubilization process was developed. In this process, proteins are first solubilized using acid and alkali followed by precipitating them at their isoelectric pH to recover functional and stable protein isolates from underutilized fish species and by-products. Many studies were conducted using pH shift process to recover proteins from fish and fish by-products and found to be most successful in recovering proteins with increased yields than conventional surimi (three cycle washing) process and with good functional properties. In this paper, problems associated with conventional processing, advantages and principle of pH shift processing, effect of pH shift process on the quality and storage stability of recovered isolates, applications protein isolates, etc. are discussed in detail for better understanding.

Direct valorisation of waste cocoa butter triglycerides via catalytic epoxidation, ring-opening and polymerisation.

PubMed

Plaza, Dorota D; Strobel, Vinzent; Heer, Parminder Kaur Ks; Sellars, Andrew B; Hoong, Seng-Soi; Clark, Andrew J; Lapkin, Alexei A

2017-09-01

Development of circular economy requires significant advances in the technologies for valorisation of waste, as waste becomes new feedstock. Food waste is a particularly important feedstock, containing large variation of complex chemical functionality. Although most food waste sources are complex mixtures, waste from food processing, no longer suitable for the human food chain, may also represent relatively clean materials. One such material requiring valorisation is cocoa butter. Epoxidation of a triglyceride from a food waste source, processing waste cocoa butter, into the corresponding triglyceride epoxide was carried out using a modified Ishii-Venturello catalyst in batch and continuous flow reactors. The batch reactor achieved higher yields due to the significant decomposition of hydrogen peroxide in the laminar flow tubular reactor. Integral and differential models describing the reaction and the phase transfer kinetics were developed for the epoxidation of cocoa butter and the model parameters were estimated. Ring-opening of the epoxidised cocoa butter was undertaken to provide polyols of varying molecular weight (M w = 2000-84 000 Da), hydroxyl value (27-60 mg KOH g -1 ) and acid value (1-173 mg KOH g -1 ), using either aqueous ortho-phosphoric acid (H 3 PO 4 ) or boron trifluoride diethyl etherate (BF 3 · OEt 2 )-mediated oligomerisation in bulk, using hexane or tetrahydrofuran (THF) as solvents. The thermal and tensile properties of the polyurethanes obtained from the reaction of these polyols with 4,4'-methylene diphenyl diisocyanate (MDI) are described. The paper presents a complete valorisation scheme for a food manufacturing industry waste stream, starting from the initial chemical transformation, developing a process model for the design of a scaled-up process, and leading to synthesis of the final product, in this case a polymer. This work describes aspects of optimisation of the conversion route, focusing on clean synthesis and also demonstrates the interdisciplinary nature of the development projects, requiring input from different areas of chemistry, process modelling and process design. © 2017 The Authors. Journal of Chemical Technology & Biotechnology published by John Wiley & Sons Ltd on behalf of Society of Chemical Industry.

Environmental Management Waste Management Facility Proxy Waste Lot Profile 6.999 for Building K-25 West Wing, East Tennessee Technology Park, Oak Ridge, Tennessee

DOE Office of Scientific and Technical Information (OSTI.GOV)

Rigsby V.P.

2009-02-12

In 1989, the Oak Ridge Reservation (ORR), which includes the East Tennessee Technology Park (ETTP), was placed on the Comprehensive Environmental Response, Compensation, and Liability Act of 1980 (CERCLA) National Priorities List. The Federal Facility Agreement (FFA) (DOE 1992), effective January 1, 1992, now governs environmental restoration activities conducted under CERCLA at the ORR. Following signing of the FFA, U.S. Department of Energy (DOE), U.S. Environmental Protection Agency (EPA), and the state of Tennessee signed the Oak Ridge Accelerated Cleanup Plan Agreement on June 18, 2002. The purpose of this agreement is to define a streamlined decision-making process to facilitatemore » the accelerated implementation of cleanup, resolve ORR milestone issues, and establish future actions necessary to complete the accelerated cleanup plan by the end of fiscal year 2008. While the FFA continues to serve as the overall regulatory framework for remediation, the Accelerated Cleanup Plan Agreement supplements existing requirements to streamline the decision-making process. Decontamination and decommissioning (D&D) activities of Bldg. K-25, the original gaseous diffusion facility, is being conducted by Bechtel Jacobs Company LLC (BJC) on behalf of the DOE. The planned CERCLA action covering disposal of building structure and remaining components from the K-25 building is scheduled as a non-time-critical CERCLA action as part of DOE's continuous risk reduction strategy for ETTP. The K-25 building is proposed for D&D because of its poor physical condition and the expense of surveillance and maintenance activities. The K-25/K-27 D&D Project proposes to dispose of the commingled waste listed below from the K-25 west side building structure and remaining components and process gas equipment and piping at the Environmental Management Waste Management Facility (EMWMF) under waste disposal proxy lot (WPXL) 6.999: (1) Building structure (e.g. concrete floors [excluding basement slab], roofing, structural steel supports, interior walls, and exterior walls) and support system components including the recirculation cooling water (RCW); electrical; communication; fire protection; ventilation; process coolant; process lube oil; utilities such as steam, water and drain lines; (2) Process Piping; (3) Seal Exhaust Headers; (4) Seal Exhaust Traps; (5) Process Valves; (6) Differential Blind Multipliers (DBM)/Partial Blind Multipliers (PBM); and (7) Aftercoolers (also known as Intercell coolers). Converters and compressors while components of the process gas system, are not included in this commingled waste lot. On January 6, 2009, a meeting was held with EPA, TDEC, DOE and the team for the sole purpose of finalizing the objectives, format, and content of WPXL 6.999. The objective of WPXL 6.999 was to provide a crosswalk to the building structure and the PGE components profiles. This was accomplished by providing tables with references to the specific section of the individual profiles for each of the WLs. There are two building profiles and eight PGE profiles. All of the waste identified in the individual profiles will be commingled, shipped, and disposed exclusively under WPXL 6.999. The individual profiles were provided to the EPA and Tennessee Department of Environment and Conservation (TDEC) for information purposes only. This summary WPXL 6.999 will be submitted to EPA, TDEC, and DOE for review and approval. The format agreed upon by the regulators and DOE form the basis for WPXL 6.999. The agreed format is found on pages v and vi of the CONTENTS section of this profile. The disposal of this waste will be executed in accordance with the Action Memorandum for the Decontamination and Decommissioning of the K-25 and K-27 Buildings, East Tennessee Technology Park, Oak Ridge, Tennessee (DOE 2002), Removal Action Work Plan for the K-25 and K-27 Buildings, Process Equipment Removal and Demolition, K-25/K-27 Project, East Tennessee Technology Park, Oak Ridge, Tennessee (DOE 2008a); Waste Handling Plan for Demolition of the K-25 and K-27 Building Structures and Remaining Components Located at the East Tennessee Technology Park, Oak Ridge, Tennessee (DOE 2005); and Waste Handling Plan for Building K-25 West Wing Process Equipment and Piping at the East Tennessee Technology Park, Oak Ridge, Tennessee (DOE 2008b).« less

Cryo-comminution of plastic waste.

PubMed

Gente, Vincenzo; La Marca, Floriana; Lucci, Federica; Massacci, Paolo; Pani, Eleonora

2004-01-01

Recycling of plastics is a big issue in terms of environmental sustainability and of waste management. The development of proper technologies for plastic recycling is recognised as a priority. To achieve this aim, the technologies applied in mineral processing can be adapted to recycling systems. In particular, the improvement of comminution technologies is one of the main actions to improve the quality of recycled plastics. The aim of this work is to point out suitable comminution processes for different types of plastic waste. Laboratory comminution tests have been carried out under different conditions of temperature and sample pre-conditioning adopting as refrigerant agents CO2 and liquid nitrogen. The temperature has been monitored by thermocouples placed in the milling chamber. Also different internal mill screens have been adopted. A proper procedure has been set up in order to obtain a selective comminution and a size reduction suitable for further separation treatment. Tests have been performed on plastics coming from medical plastic waste and from a plant for spent lead batteries recycling. Results coming from different mill devices have been compared taking into consideration different indexes for representative size distributions. The results of the performed tests show as cryo-comminution improves the effectiveness of size reduction of plastics, promotes liberation of constituents and increases specific surface size of comminuted particles in comparison to a comminution process carried out at room temperature. Copyright 2004 Elsevier Ltd.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Vienna, John D.; Todd, Terry A.; Gray, Kimberly D.

The U.S. Department of Energy, Office of Nuclear Energy has chartered an effort to develop technologies to enable safe and cost effective recycle of commercial used nuclear fuel (UNF) in the U.S. Part of this effort includes the evaluation of exiting waste management technologies for effective treatment of wastes in the context of current U.S. regulations and development of waste forms and processes with significant cost and/or performance benefits over those existing. This study summarizes the results of these ongoing efforts with a focus on the highly radioactive primary waste streams. The primary streams considered and the recommended waste formsmore » include: •Tritium separated from either a low volume gas stream or a high volume water stream. The recommended waste form is low-water cement in high integrity containers. •Iodine-129 separated from off-gas streams in aqueous processing. There are a range of potentially suitable waste forms. As a reference case, a glass composite material (GCM) formed by the encapsulation of the silver Mordenite (AgZ) getter material in a low-temperature glass is assumed. A number of alternatives with distinct advantages are also considered including a fused silica waste form with encapsulated nano-sized AgI crystals. •Carbon-14 separated from LWR fuel treatment off-gases and immobilized as a CaCO3 in a cement waste form. •Krypton-85 separated from LWR and SFR fuel treatment off-gases and stored as a compressed gas. •An aqueous reprocessing high-level waste (HLW) raffinate waste which is immobilized by the vitrification process in one of three forms: a single phase borosilicate glass, a borosilicate based glass ceramic, or a multi-phased titanate ceramic [e.g., synthetic rock (Synroc)]. •An undissolved solids (UDS) fraction from aqueous reprocessing of LWR fuel that is either included in the borosilicate HLW glass or is immobilized in the form of a metal alloy in the case of glass ceramics or titanate ceramics. •Zirconium-based LWR fuel cladding hulls and stainless steel (SS) fuel assembly hardware that are washed and super-compacted for disposal or as an alternative Zr purification and reuse (or disposal as low-level waste, LLW) by reactive gas separations. •Electrochemical process salt HLW which is immobilized in a glass bonded Sodalite waste form known as the ceramic waste form (CWF). •Electrochemical process UDS and SS cladding hulls which are melted into an iron based alloy waste form. Mass and volume estimates for each of the recommended waste forms based on the source terms from a representative flowsheet are reported.« less

Newly invented biobased materials from low-carbon, diverted waste fibers: research methods, testing, and full-scale application in a case study structure

Treesearch

Julee A Herdt; John Hunt; Kellen Schauermann

2016-01-01

This project demonstrates newly invented, biobased construction materials developed by applying lowcarbon, biomass waste sources through the Authors’ engineered fiber processes and technology. If manufactured and applied large-scale the project inventions can divert large volumes of cellulose waste into high-performance, low embodied energy, environmental construction...

Analysis of energy recovery potential using innovative technologies of waste gasification.

PubMed

Lombardi, Lidia; Carnevale, Ennio; Corti, Andrea

2012-04-01

In this paper, two alternative thermo-chemical processes for waste treatment were analysed: high temperature gasification and gasification associated to plasma process. The two processes were analysed from the thermodynamic point of view, trying to reconstruct two simplified models, using appropriate simulation tools and some support data from existing/planned plants, able to predict the energy recovery performances by process application. In order to carry out a comparative analysis, the same waste stream input was considered as input to the two models and the generated results were compared. The performances were compared with those that can be obtained from conventional combustion with energy recovery process by means of steam turbine cycle. Results are reported in terms of energy recovery performance indicators as overall energy efficiency, specific energy production per unit of mass of entering waste, primary energy source savings, specific carbon dioxide production. Copyright © 2011 Elsevier Ltd. All rights reserved.

Electromagnetic mixed waste processing system for asbestos decontamination

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kasevich, R.S.; Vaux, W.; Ulerich, N.

The overall objective of this three-phase program is to develop an integrated process for treating asbestos-containing material that is contaminated with radioactive and hazardous constituents. The integrated process will attempt to minimize processing and disposal costs. The objectives of Phase 1 were to establish the technical feasibility of asbestos decomposition, inorganic radionuclide nd heavy metal removal, and organic volatilization. Phase 1 resulted in the successful bench-scale demonstration of the elements required to develop a mixed waste treatment process for asbestos-containing material (ACM) contaminated with radioactive metals, heavy metals, and organics. Using the Phase 1 data, a conceptual process was developed.more » The Phase 2 program, currently in progress, is developing an integrated system design for ACM waste processing. The Phase 3 program will target demonstration of the mixed waste processing system at a DOE facility. The electromagnetic mixed waste processing system employs patented technologies to convert DOE asbestos to a non-hazardous, radionuclide-free, stable waste. The dry, contaminated asbestos is initially heated with radiofrequency energy to remove organic volatiles. Second,the radionuclides are removed by solvent extraction coupled with ion exchange solution treatment. Third, the ABCOV method converts the asbestos to an amorphous silica suspension at low temperature (100{degrees}C). Finally the amorphous silica is solidified for disposal.« less

Dielectric Properties of Low-Level Liquid Waste

DOE Office of Scientific and Technical Information (OSTI.GOV)

L. E. Lagos; M. A. Ebadian

1998-10-20

The purpose of this study was to develop a data collection containing values for the dielectric properties of various low-level liquid waste (LLLW) simulants measured as a function of frequency, temperature, and composition. The investigation was motivated by current interest in the use of microwave processing for the treatment of radioactive waste. A large volume of transuranic liquid and sludge produced by the U.S. Department of Defense (DOD) during the production of nuclear fiel bars is stored at several U.S. Department of Energy (DOE) sites around the United States. Waste storage and disposal space is scarce, expensive, and must bemore » minimized. Thus, several DOE sites are pursuing the use of microwave heating as a means of achieving volume reduction and solidification of low-level liquid wastes. It is important to know which microwave frequencies should be employed tc achieve the most efficient processing at a range of different temperatures. The dielectric properties of the LLLW simulants can be utilized to determine the optimum frequencies for use with a particular LLLW or with other LLLWS of similar composition. Furthermore, nonlinear thermal processes, such as thermal runaway, which occur in the material being treated cannot be modeled without a knowledge of the temperature dependence of the dielectric properties. Often, this data does not exist; however, when it does, only very limited data near room temperature are available. The data collection generated in this study can be used to predict the behavior of a variety of microwave thermal treatment technologies, which have the potential of substantially reducing the volume of the LLLWS that are currently stored at many DOE sites. This information should help the users of the microwave reduction and solidification technology to optimize microwave processes used in the treatment of LLLW. The microwave reduction and solidification technology has clear advantages over other methods of reducing LLLWS. These include the incineration of combustibles, the evaporation of combustibles, the evaporation of liquids, and the compaction of noncombustibles. The handling of radioactive liquid waste is generally carried out within closed systems consisting of highly corrosion-resistant, welded, leak-tight pipes, tanks, and other apparatus. High power microwave processing is a promising technology for reducing risks to the environment and human health, thereby supporting the DOE's decontamination and decommissioning (D&D) objectives.« less

Recycling of inorganic waste in monolithic and cellular glass-based materials for structural and functional applications.

PubMed

Rincón, Acacio; Marangoni, Mauro; Cetin, Suna; Bernardo, Enrico

2016-07-01

The stabilization of inorganic waste of various nature and origin, in glasses, has been a key strategy for environmental protection for the last decades. When properly formulated, glasses may retain many inorganic contaminants permanently, but it must be acknowledged that some criticism remains, mainly concerning costs and energy use. As a consequence, the sustainability of vitrification largely relies on the conversion of waste glasses into new, usable and marketable glass-based materials, in the form of monolithic and cellular glass-ceramics. The effective conversion in turn depends on the simultaneous control of both starting materials and manufacturing processes. While silica-rich waste favours the obtainment of glass, iron-rich wastes affect the functionalities, influencing the porosity in cellular glass-based materials as well as catalytic, magnetic, optical and electrical properties. Engineered formulations may lead to important reductions of processing times and temperatures, in the transformation of waste-derived glasses into glass-ceramics, or even bring interesting shortcuts. Direct sintering of wastes, combined with recycled glasses, as an example, has been proven as a valid low-cost alternative for glass-ceramic manufacturing, for wastes with limited hazardousness. The present paper is aimed at providing an up-to-date overview of the correlation between formulations, manufacturing technologies and properties of most recent waste-derived, glass-based materials. © 2016 The Authors. Journal of Chemical Technology & Biotechnology published by John Wiley & Sons Ltd on behalf of Society of Chemical Industry.

CONTROL TECHNOLOGIES FOR REMEDIATION OF CONTAMINATED SOIL AND WASTE DEPOSITS AT SUPERFUND LEAD BATTERY SITES

EPA Science Inventory

This paper primarily addresses remediation of contaminated soils and waste deposits at defunct lead-acid battery recycling sites (LBRS) via immobilization and separation processes. efunct LBRS is a facility at which battery breaking, secondary lead smelting, or both operations we...

Evaluating the Air Quality, Climate & Economic Impacts of Biogas Management Technologies

EPA Science Inventory

Anaerobic digestion is a natural biological process in which microorganisms break down organic materials in the absence of oxygen. When anaerobic microbes metabolize organic waste – i.e., the carbon-based remains of plants, animals and their waste products, e.g. animal manu...

DOE Office of Scientific and Technical Information (OSTI.GOV)

Bishop, J.

Every environmentalist and environmental manager dreams of a day when it will be possible to load hazardous waste into one end of a magic machine and retrieve beneficial -- or at least benign -- products from the other end. Two unrelated companies -- Molten Metal Technology Inc., (Waltham, Mass.) and ELI Eco Logic Inc. (Rockwood, Ontario, Canada) -- have developed different technologies that show promise of realizing such dreams. Whether either company`s solution to the problem of effectively managing hazardous wastes proves to be the dream machine remains to be seen, but their stories offer insight into what the futuremore » may hold for hazardous waste management. The Eco Logic Process was demonstrated in 1991 at Hamilton Harbour, Ontario, and later at Bay City, Mich., in cleanups of polychlorinated biphenyls (PCBs) and other soil contaminants. The technology was accepted into the US Environmental Protection Agency`s Superfund Innovative Technology Evaluation (SITE) program in 1992.« less

A science and technology initiative within the office of civilian radioactive waste management

USGS Publications Warehouse

Budnitz, R.J.; Kiess, T.E.; Peters, M.; Duncan, D.

2003-01-01

In 2002, by following a national decision-making process that had been specified in the 1982 Nuclear Waste Policy Act, Yucca Mountain (YM) was designated as the site for the nation's geologic repository for commercial spent nuclear fuel (SNF). The U.S. Department of Energy's (DOE's) Office of Civilian Radioactive Waste Management (OCRWM) must now obtain regulatory approval to construct and operate a repository there, and to develop transportation and infrastructure needed to support operations. The OCRWM has also recently begun a separate Science and Technology (S&T) initiative, whose purposes, beginnings, current projects, and future plans are described here.

Eliminating Medical Waste Liabilities Through Mobile Maceration and Disinfection

DOE Office of Scientific and Technical Information (OSTI.GOV)

R. A. Rankin; N. R. Soelberg; K. M. Klingler

2006-02-01

Commercial medical waste treatment technologies include incineration, melting, autoclaving, and chemical disinfection. Incineration disinfects, destroys the original nature of medical waste, and reduces the waste volume by converting organic waste content to carbon dioxide and water, leaving only residual inorganic ash. However, medical waste incinerator numbers have plummeted from almost 2,400 in 1995 to 115 in 2003 and to about 62 in 2005, due to negative public perception and escalating compliance costs associated with increasingly strict regulations. High-temperature electric melters have been designed and marketed as incinerator alternatives, but they are also costly and generally must comply with the samemore » incinerator emissions regulations and permitting requirements. Autoclave processes disinfect medical waste at much lower operating temperatures than incinerators operate at, but are sometimes subject to limitations such as waste segregration requirements to be effective. Med-Shred, Inc. has developed a patented mobile shredding and chemical disinfecting process for on-site medical waste treatment. Medical waste is treated on-site at customer facilities by shredding and disinfecting the waste. The treated waste can then be transported in compliance with Health Insurance Portability and Accountability Act of 1996 (HIPAA) requirements to a landfill for disposal as solid municipal waste. A team of Idaho National Laboratory engineers evaluated the treatment process design. The process effectiveness has been demonstrated in mycobacterium tests performed by Analytical Services Incorporated. A process description and the technical and performance evaluation results are presented in the paper. A treatment demonstration and microbiological disinfecting tests show that the processor functions as it was intended.« less

Physical/chemical closed-loop water-recycling

NASA Technical Reports Server (NTRS)

Herrmann, Cal C.; Wydeven, Theodore

1991-01-01

Water needs, water sources, and means for recycling water are examined in terms appropriate to the water quality requirements of a small crew and spacecraft intended for long duration exploration missions. Inorganic, organic, and biological hazards are estimated for waste water sources. Sensitivities to these hazards for human uses are estimated. The water recycling processes considered are humidity condensation, carbon dioxide reduction, waste oxidation, distillation, reverse osmosis, pervaporation, electrodialysis, ion exchange, carbon sorption, and electrochemical oxidation. Limitations and applications of these processes are evaluated in terms of water quality objectives. Computerized simulation of some of these chemical processes is examined. Recommendations are made for development of new water recycling technology and improvement of existing technology for near term application to life support systems for humans in space. The technological developments are equally applicable to water needs on Earth, in regions where extensive water recycling is needed or where advanced water treatment is essential to meet EPA health standards.

THE DOE OFFICE OF ENVIRONMENTAL MANAGEMENT INTERNATIONAL COOPERATIVE PROGRAM: OVERVIEW OF TECHNICAL TASKS AND RESULTS

DOE Office of Scientific and Technical Information (OSTI.GOV)

Marra, J.; Fox, K.; Farfan, E.

2009-12-08

The DOE Office of Environmental Management (DOE-EM) Office of Engineering and Technology is responsible for implementing EM's International Cooperative Program. Over the past 15 years, collaborative work has been conducted through this program with researchers in Russia, Ukraine, France, United Kingdom and Republic of Korea. Currently, work is being conducted with researchers in Russia and Ukraine. Efforts aimed at evaluating and advancing technologies to support U.S. high-level waste (HLW) vitrification initiatives are being conducted in collaboration with Russian researchers. Work at Khlopin Radium Institute (KRI) is targeted at improving the throughput of current vitrification processes by increasing melting rate. Thesemore » efforts are specifically targeted at challenging waste types identified at the Savannah River Site (SRS) and Hanford Site. The objectives of current efforts at SIA Radon are to gain insight into vitrification process limits for the cold crucible induction melter (CCIM) technology. Previous demonstration testing has shown that the CCIM offers the potential for dramatic increases in waste loading and waste throughput. However, little information is known regarding operational limits that could affect long-term, efficient CCIM operations. Collaborative work with the Russian Electrotechnical University (ETU) 'LETI' is aimed at advancing CCIM process monitoring, process control and design. The goal is to further mature the CCIM technology and to establish it as a viable HLW vitrification technology. The greater than two year effort conducted with the International Radioecology Laboratory in the Ukraine recently completed. The objectives of this study were: to assess the long-term impacts to the environment from radiation exposure in the Chernobyl Exclusion Zone (ChEZ); and to provide information on remediation guidelines and ecological risk assessment within radioactively contaminated territories around the Chernobyl Nuclear Power Plant (ChNPP) based on the results of long-term field monitoring, analytical measurements, and numerical modeling of soils and groundwater radioactive contamination.« less

Staff exchange with Chemical Waste Management. Final project report

DOE Office of Scientific and Technical Information (OSTI.GOV)

Harrer, B.J.; Barak, D.W.

1993-12-01

Original objective was transfer of PNL technology and expertise in computational chemistry and waste flow/treatment modeling to CWM. Identification and characterization of a broader portfolio of PNL`s environmental remediation technologies with high potential for rapid application became the focus of the exchange, which included E-mail exchanges. Of the 14 technologies discussed, the following were identified as being of high interest to CWM: six phase soil heating (in-situ heating), high energy electrical corona, RAAS/ReOpt{trademark} (remedial, expert system), TEES{trademark} (catalytic production of methane from biological wastes), PST (process for treating petroleum sludge). CWM`s reorganization and downsizing reduced the potential benefits to industry,more » but a proposal for transfer and application of PST to Wheelabrator was made.« less

Secondary Waste Form Down-Selection Data Package—Fluidized Bed Steam Reforming Waste Form

DOE Office of Scientific and Technical Information (OSTI.GOV)

Qafoku, Nikolla; Westsik, Joseph H.; Strachan, Denis M.

2011-09-12

The Hanford Site in southeast Washington State has 56 million gallons of radioactive and chemically hazardous wastes stored in 177 underground tanks (ORP 2010). The U.S. Department of Energy (DOE), Office of River Protection (ORP), through its contractors, is constructing the Hanford Tank Waste Treatment and Immobilization Plant (WTP) to convert the radioactive and hazardous wastes into stable glass waste forms for disposal. Within the WTP, the pretreatment facility will receive the retrieved waste from the tank farms and separate it into two treated process streams. These waste streams will be vitrified, and the resulting waste canisters will be sentmore » to offsite (high-level waste [HLW]) and onsite (immobilized low-activity waste [ILAW]) repositories. As part of the pretreatment and ILAW processing, liquid secondary wastes will be generated that will be transferred to the Effluent Treatment Facility (ETF) on the Hanford Site for further treatment. These liquid secondary wastes will be converted to stable solid waste forms that will be disposed of in the Integrated Disposal Facility (IDF). To support the selection of a waste form for the liquid secondary wastes from WTP, Washington River Protection Solutions (WRPS) has initiated secondary waste form testing work at Pacific Northwest National Laboratory (PNNL). In anticipation of a down-selection process for a waste form for the Solidification Treatment Unit to be added to the ETF, PNNL is developing data packages to support that down-selection. The objective of the data packages is to identify, evaluate, and summarize the existing information on the four waste forms being considered for stabilizing and solidifying the liquid secondary wastes. At the Hanford Site, the FBSR process is being evaluated as a supplemental technology for treating and immobilizing Hanford LAW radioactive tank waste and for treating secondary wastes from the WTP pretreatment and LAW vitrification processes.« less

Direct oxidation of strong waste waters, simulating combined wastes in extended-mission space cabins

NASA Technical Reports Server (NTRS)

Ross, L. W.

1973-01-01

The applications of modern technology to the resolution of the problem of solid wastes in space cabin environments was studied with emphasis on the exploration of operating conditions that would permit lowering of process temperatures in wet oxidation of combined human wastes. It was found that the ultimate degree of degradation is not enhanced by use of a catalyst. However, the rate of oxidation is increased, and the temperature of oxidation is reduced to 400 F.

The use of fly larvae for organic waste treatment.

PubMed

Čičková, Helena; Newton, G Larry; Lacy, R Curt; Kozánek, Milan

2015-01-01

The idea of using fly larvae for processing of organic waste was proposed almost 100 years ago. Since then, numerous laboratory studies have shown that several fly species are well suited for biodegradation of organic waste, with the house fly (Musca domestica L.) and the black soldier fly (Hermetia illucens L.) being the most extensively studied insects for this purpose. House fly larvae develop well in manure of animals fed a mixed diet, while black soldier fly larvae accept a greater variety of decaying organic matter. Blow fly and flesh fly maggots are better suited for biodegradation of meat processing waste. The larvae of these insects have been successfully used to reduce mass of animal manure, fecal sludge, municipal waste, food scrapes, restaurant and market waste, as well as plant residues left after oil extraction. Higher yields of larvae are produced on nutrient-rich wastes (meat processing waste, food waste) than on manure or plant residues. Larvae may be used as animal feed or for production of secondary products (biodiesel, biologically active substances). Waste residue becomes valuable fertilizer. During biodegradation the temperature of the substrate rises, pH changes from neutral to alkaline, ammonia release increases, and moisture decreases. Microbial load of some pathogens can be substantially reduced. Both larvae and digested residue may require further treatment to eliminate pathogens. Facilities utilizing natural fly populations, as well as pilot and full-scale plants with laboratory-reared fly populations have been shown to be effective and economically feasible. The major obstacles associated with the production of fly larvae from organic waste on an industrial scale seem to be technological aspects of scaling-up the production capacity, insufficient knowledge of fly biology necessary to produce large amounts of eggs, and current legislation. Technological innovations could greatly improve performance of the biodegradation facilities and decrease production costs. Copyright © 2014 Elsevier Ltd. All rights reserved.

17 CFR 250.58 - Exemption of investments in certain nonutility companies.

Code of Federal Regulations, 2010 CFR

2010-04-01

... facilities relating to electric and compressed natural gas powered vehicles; (iv) The sale of electric and gas appliances; equipment to promote new technologies, or new applications for existing technologies... and commercialization of technologies or processes that utilize coal waste by-products as an integral...

Economic screening of renewable energy technologies: Incineration, anaerobic digestion, and biodiesel as applied to waste water scum.

PubMed

Anderson, Erik; Addy, Min; Ma, Huan; Chen, Paul; Ruan, Roger

2016-12-01

In the U.S., the total amount of municipal solid waste is continuously rising each year. Millions of tons of solid waste and scum are produced annually that require safe and environmentally sound disposal. The availability of a zero-cost energy source like municipal waste scum is ideal for several types of renewable energy technologies. However, the way the energy is produced, distributed and valued also contributes to the overall process sustainability. An economic screening method was developed to compare the potential energy and economic value of three waste-to-energy technologies; incineration, anaerobic digestion, and biodiesel. A St. Paul, MN wastewater treatment facility producing 3175 "wet" kilograms of scum per day was used as a basis of the comparison. After applying all theoretically available subsidies, scum to biodiesel was shown to have the greatest economic potential, valued between $491,949 and $610,624/year. The incineration of scum yielded the greatest reclaimed energy potential at 29billion kilojoules/year. Copyright © 2016 Elsevier Ltd. All rights reserved.

Waste-to-Energy Technology Brief

EPA Science Inventory

ETV's Greenhouse Gas Technology (GHG) Center, operated by Southern Research Institute under a cooperative agreement with US EPA, verified two biogas processing systems and four distributed generation (DG) energy systems in collaboration with the Colorado Governors Office or the N...

Advanced evaporator technology progress report FY 1992

DOE Office of Scientific and Technical Information (OSTI.GOV)

Chamberlain, D.; Hutter, J.C.; Leonard, R.A.

1995-01-01

This report summarizes the work that was completed in FY 1992 on the program {open_quotes}Technology Development for Concentrating Process Streams.{close_quotes} The purpose of this program is to evaluate and develop evaporator technology for concentrating radioactive waste and product streams such as those generated by the TRUEX process. Concentrating these streams and minimizing the volume of waste generated can significantly reduce disposal costs; however, equipment to concentrate the streams and recycle the decontaminated condensates must be installed. LICON, Inc., is developing an evaporator that shows a great deal of potential for this application. In this report, concepts that need to bemore » incorporated into the design of an evaporator operated in a radioactive environment are discussed. These concepts include criticality safety, remote operation and maintenance, and materials of construction. Both solubility and vapor-liquid equilibrium data are needed to design an effective process for concentrating process streams. Therefore, literature surveys were completed and are summarized in this report. A model that is being developed to predict vapor phase compositions is described. A laboratory-scale evaporator was purchased and installed to study the evaporation process and to collect additional data. This unit is described in detail. Two new LICON evaporators are being designed for installation at Argonne-East in FY 1993 to process low-level radioactive waste generated throughout the laboratory. They will also provide operating data from a full-sized evaporator processing radioactive solutions. Details on these evaporators are included in this report.« less

Technologies for utilizing natural resources create new job opportunities in the geosciences in developing countries

NASA Astrophysics Data System (ADS)

Aswathanarayana, U.

Water, soils, minerals, and biota constitute a community's most significant natural resources. Innovations in technology are generating new jobs in converting into a resource what was yesterday a non-resource; in developing process and control technologies to minimize wastes; and in waste recycling.“Resources are not, they become,” in the words of Zimmerman. In the case of the developing countries, the technologies of choice have not only to be ecologically sustainable and economically viable, but more importantly, employment generating. The new kinds of jobs—for example, in poverty alleviation projects via micro-enterprises based on value-added processing of natural resources—have a strong environmental relevance and tend to lie at the interface of several traditional scientific disciplines. Geoscience graduates in the developing countries are best placed to take advantage of these new job opportunities involving Earth materials, but only if they are exposed to broad-based geoscience instruction.

A North American model to contain the spread of Aedes albopictus through tire legislation.

PubMed

Novak, R J

1995-12-01

The introduction, spread, and establishment of the Asian tiger mosquito, Aedes albopictus, in the United States has been facilitated by used or waste tires. This species has not only caused considerable concern among public health officials but also highlighted that the growing accumulations of used tires are a serious solid waste problem and a challenge to the recycling industry. This paper illustrates how the State of Illinois addressed the public health and solid waste problems associated with waste tires, mosquitoes and mosquito-borne pathogens. The goal of the State was to develop and implement through legislative process the Illinois Waste Tire Act. The purpose of the Waste Tire Act is: 1) to ensure that used and waste tires are collected for disposal and recycling, 2) to provide for the abatement of used and waste tire dumps and associated threats to public health, 3) to encourage the development of used and waste tire processing facilities and technologies, including energy recovery, and 4) to provide for research on vectors associated with used and waste tires, and the diseases they spread. The discussion will include key statutes from the Act and the model used to coordinate the effort of five different governmental agencies. An up-to-date presentation of vector-related research, mandated by the Act, ranging from applied investigations on mosquito control to more basic studies investigations on virus identification using molecular technology will be discussed. Finally a discussion of problems that have been encountered along with solutions dealing with legislative language, multidisciplined agency efforts and interactions with the general public are presented.

Valorization of date palm (Phoenix dactylifera) fruit processing by-products and wastes using bioprocess technology – Review

PubMed Central

Chandrasekaran, M.; Bahkali, Ali H.

2013-01-01

The date palm Phoenix dactylifera has played an important role in the day-to-day life of the people for the last 7000 years. Today worldwide production, utilization and industrialization of dates are continuously increasing since date fruits have earned great importance in human nutrition owing to their rich content of essential nutrients. Tons of date palm fruit wastes are discarded daily by the date processing industries leading to environmental problems. Wastes such as date pits represent an average of 10% of the date fruits. Thus, there is an urgent need to find suitable applications for this waste. In spite of several studies on date palm cultivation, their utilization and scope for utilizing date fruit in therapeutic applications, very few reviews are available and they are limited to the chemistry and pharmacology of the date fruits and phytochemical composition, nutritional significance and potential health benefits of date fruit consumption. In this context, in the present review the prospects of valorization of these date fruit processing by-products and wastes’ employing fermentation and enzyme processing technologies towards total utilization of this valuable commodity for the production of biofuels, biopolymers, biosurfactants, organic acids, antibiotics, industrial enzymes and other possible industrial chemicals are discussed. PMID:23961227

Study of waste management towards sustainable green campus in Universitas Gadjah Mada

NASA Astrophysics Data System (ADS)

Setyowati, Mega; Kusumawanto, Arif; Prasetya, Agus

2018-05-01

Waste management is a part of the green campus achievement program. Universitas Gadjah Mada has a Standard Operating Procedure for managing produced waste. Waste produced by each building or work unit is temporarily accommodated in the waste depot before dumped into the landfill. This research aims to study the waste management system in UGM, in accordance with the concept of a green campus. The concept of green campus to improve the efficiency of waste management needs to be supported by various parties. The success of the green campus program relies on an integrated approach, a sustainable implementation that involves stakeholders of the university. In actualizing the concept of a green campus, the university has its own waste processing system. The organic produced waste is processed into compost, while plastic waste is converted into alternative fuel. Overall, the waste management system that UGM owns is ineffective and inefficient, it was proved by the fact that there is still much waste dumped into the landfill. UGM provides a laboratory that is specialized to process waste that is produced by UGM. It is planned to be able to reduce the amount of waste that is dumped into the landfill. According to the results, vermicomposting technology, the manufacture of liquid fertilizer from leachate, and the manufacture of the composite from a mixture of leaves and paper were offered as solutions.

A life cycle assessment of environmental performances of two combustion- and gasification-based waste-to-energy technologies.

PubMed

Arena, Umberto; Ardolino, Filomena; Di Gregorio, Fabrizio

2015-07-01

An attributional life cycle analysis (LCA) was developed to compare the environmental performances of two waste-to-energy (WtE) units, which utilize the predominant technologies among those available for combustion and gasification processes: a moving grate combustor and a vertical shaft gasifier coupled with direct melting. The two units were assumed to be fed with the same unsorted residual municipal waste, having a composition estimated as a European average. Data from several plants in operation were processed by means of mass and energy balances, and on the basis of the flows and stocks of materials and elements inside and throughout the two units, as provided by a specific substance flow analysis. The potential life cycle environmental impacts related to the operations of the two WtE units were estimated by means of the Impact 2002+ methodology. They indicate that both the technologies have sustainable environmental performances, but those of the moving grate combustion unit are better for most of the selected impact categories. The analysis of the contributions from all the stages of each specific technology suggests where improvements in technological solutions and management criteria should be focused to obtain further and remarkable environmental improvements. Copyright © 2015 Elsevier Ltd. All rights reserved.

Analysis of nuclear waste disposal in space, phase 3. Volume 2: Technical report

NASA Technical Reports Server (NTRS)

Rice, E. E.; Miller, N. E.; Yates, K. R.; Martin, W. E.; Friedlander, A. L.

1980-01-01

The options, reference definitions and/or requirements currently envisioned for the total nuclear waste disposal in space mission are summarized. The waste form evaluation and selection process is documented along with the physical characteristics of the iron nickel-base cermet matrix chosen for disposal of commercial and defense wastes. Safety aspects of radioisotope thermal generators, the general purpose heat source, and the Lewis Research Center concept for space disposal are assessed as well as the on-pad catastrophic accident environments for the uprated space shuttle and the heavy lift launch vehicle. The radionuclides that contribute most to long-term risk of terrestrial disposal were determined and the effects of resuspension of fallout particles from an accidental release of waste material were studied. Health effects are considered. Payload breakup and rescue technology are discussed as well as expected requirements for licensing, supporting research and technology, and safety testing.

Analysis of nuclear waste disposal in space, phase 3. Volume 2: Technical report

NASA Astrophysics Data System (ADS)

Rice, E. E.; Miller, N. E.; Yates, K. R.; Martin, W. E.; Friedlander, A. L.

1980-03-01

The options, reference definitions and/or requirements currently envisioned for the total nuclear waste disposal in space mission are summarized. The waste form evaluation and selection process is documented along with the physical characteristics of the iron nickel-base cermet matrix chosen for disposal of commercial and defense wastes. Safety aspects of radioisotope thermal generators, the general purpose heat source, and the Lewis Research Center concept for space disposal are assessed as well as the on-pad catastrophic accident environments for the uprated space shuttle and the heavy lift launch vehicle. The radionuclides that contribute most to long-term risk of terrestrial disposal were determined and the effects of resuspension of fallout particles from an accidental release of waste material were studied. Health effects are considered. Payload breakup and rescue technology are discussed as well as expected requirements for licensing, supporting research and technology, and safety testing.

Hanford High-Level Waste Vitrification Program at the Pacific Northwest National Laboratory: technology development - annotated bibliography

DOE Office of Scientific and Technical Information (OSTI.GOV)

Larson, D.E.

1996-09-01

This report provides a collection of annotated bibliographies for documents prepared under the Hanford High-Level Waste Vitrification (Plant) Program. The bibliographies are for documents from Fiscal Year 1983 through Fiscal Year 1995, and include work conducted at or under the direction of the Pacific Northwest National Laboratory. The bibliographies included focus on the technology developed over the specified time period for vitrifying Hanford pretreated high-level waste. The following subject areas are included: General Documentation; Program Documentation; High-Level Waste Characterization; Glass Formulation and Characterization; Feed Preparation; Radioactive Feed Preparation and Glass Properties Testing; Full-Scale Feed Preparation Testing; Equipment Materials Testing; Meltermore » Performance Assessment and Evaluations; Liquid-Fed Ceramic Melter; Cold Crucible Melter; Stirred Melter; High-Temperature Melter; Melter Off-Gas Treatment; Vitrification Waste Treatment; Process, Product Control and Modeling; Analytical; and Canister Closure, Decontamination, and Handling« less

Non-composted municipal solid waste byproduct influences soil and plant nutrients five years after soil reclamation

USDA-ARS?s Scientific Manuscript database

Concerns for the mounting supply of municipal solid waste being generated combined with decreasing landfill space have compelled military installations to evaluate alternative methods for disposal. One approach to reduce landfilling is the use of a new garbage-processing technology that sterilizes a...

CONTROL TECHNOLOGIES FOR REMEDIATION OF CONTAMINATED SOIL AND WASTE DEPOSITS AT SUPERFUND LEAD BATTERY RECYCLING SITES

EPA Science Inventory

This paper primarily addresses remediation of contaminated soils and waste deposits at defunct lead-acid battery recycling sites (LBRS) via immobilization and separation processes. A defunct LBRS is a facility at which battery breaking, secondary lead smelting, or both operations...

Evaluating the Air Quality, Climate and Economic Impacts of Biogas Management Technologies

EPA Science Inventory

Anaerobic digestion is a natural biological process in which microorganisms break down organic materials in the absence of oxygen. When anaerobic microbes metabolize organic waste – i.e., the carbon-based remains of plants, animals and their waste products, e.g. animal manure, se...

The Conversion and Sustainable Use of Alumina Refinery Residues: Global Solution Examples

NASA Astrophysics Data System (ADS)

Fergusson, Lee

This paper introduces current industry best practice for the conversion of alumina refinery residues (or "red mud") from hazardous waste to benign, inert material. The paper will examine four neutralization methods and Basecon Technology, a sustainable conversion process. The paper will consider ways through which this converted material can be combined and processed for sustainable applications in the treatment of hazardous waste streams (such as industrial wastewater and sludges, biosolids, and CCA wastes), contaminated brownfield sites, and mine site wastes. Recent discoveries and applications, such as the successful treatment of high levels of radium in drinking water in the USA, will also be discussed. Examples of global solutions and their technical merits will be assessed.

Microbial-processing of fruit and vegetable wastes for production of vital enzymes and organic acids: Biotechnology and scopes.

PubMed

Panda, Sandeep K; Mishra, Swati S; Kayitesi, Eugenie; Ray, Ramesh C

2016-04-01

Wastes generated from fruits and vegetables are organic in nature and contribute a major share in soil and water pollution. Also, green house gas emission caused by fruit and vegetable wastes (FVWs) is a matter of serious environmental concern. This review addresses the developments over the last one decade on microbial processing technologies for production of enzymes and organic acids from FVWs. The advances in genetic engineering for improvement of microbial strains in order to enhance the production of the value added bio-products as well as the concept of zero-waste economy have been briefly discussed. Copyright © 2015 Elsevier Inc. All rights reserved.

Hot-isostatically pressed wasteforms for Magnox sludge immobilisation

NASA Astrophysics Data System (ADS)

Heath, Paul G.; Stewart, Martin W. A.; Moricca, Sam; Hyatt, Neil C.

2018-02-01

Thermal treatment technologies offer many potential benefits for the treatment of radioactive wastes including the passivation of reactive species and significant waste volume reductions. This paper presents a study investigating the production of wasteforms using Hot-isostatic pressing technology for the immobilisation of Magnox sludges from the UK's Sellafield Site. Simulants considered physically representative of these sludges were used to determine possible processing parameters and to determine the phase assemblages and morphologies produced during processing. The study showed hot-isostatic pressing is capable of processing Magnox sludges at up to 60 wt% (oxide basis) into dense, mixed ceramic wasteforms. The wasteforms produced are a glass-bonded ceramic of mixed magnesium titanates, encapsulating localised grains of periclase. The ability to co-process Magnox sludges with SIXEP sand/clinoptilolite slurries has also been demonstrated. The importance of these results is presented through a comparison of volume reduction data, which shows HIPing may provide a 20-fold volume reduction over the current cementitious baseline and double the volume reduction attainable for vitrification technologies.

Incinerator technology overview

NASA Astrophysics Data System (ADS)

Santoleri, Joseph J.

1991-04-01

In the 1960's, much effort was expended on cleaning up the air and water. Air Quality and Water Quality Acts were written and inpleinented in many states and coninunities. New products such as unleaded gasoline and water base paints were developed to aid in minimizing pollution. Conversion from oil fired combustion systems to natural gas fired for comfort and industrial heating was the normal practice. In 1970, the Clean Air Act was passed. There was concern on how to safely dispose of hazardous wastes. Indiscriminate dumping of chemical process wastes had been the practice since the birth of the chemical industry in the USA. Land dumping, inadequate landfills, and river-ocean dumping were the most economical ways to dispose of chemical wastes. Processes that would have reduced or eliminated wastes were disregarded as being too costly. Many of the major chemical companies who regarded a safe environment as their responsibility installed waste treatment and disposal facilities on their plant sites. Many of these plants elected to use incinerators as the treatment process. This was not always the most economical method, but in many cases it was the only method of disposal that provided a safe and sure method of maximum destruction. Environmental concern over contamination from uncontrolled land disposal sites, and the emergence of tougher regulations for land disposal provide incentives for industry to employ a wide variety of traditional and advanced technologies for managing hazardous wastes. Incineration systems utilizing proper design, operation, and maintenance provides the safest and in the long run, the most economical avenue to the maximum level of destruction of organic hazardous wastes.

Pacific Basin conference on hazardous waste: Proceedings

DOE Office of Scientific and Technical Information (OSTI.GOV)

NONE

This conference was held November 4--8, 1996 in Kuala Lumpur, Malaysia. The purpose of this conference was to provide a multidisciplinary forum for exchange of state-of-the-art information on the problems of hazardous waste. Topics of discussion deal with pollution prevention, waste treatment technology, health and ecosystem effects research, analysis and assessment, and regulatory management techniques. Individual papers have been processed separately for inclusion in the appropriate data bases.

Aerospace Fuels From Nonpetroleum Raw Materials

NASA Technical Reports Server (NTRS)

Palaszewski, Bryan A.; Hepp, Aloysius F.; Kulis, Michael J.; Jaworske, Donald A.

2013-01-01

Recycling human metabolic and plastic wastes minimizes cost and increases efficiency by reducing the need to transport consumables and return trash, respectively, from orbit to support a space station crew. If the much larger costs of transporting consumables to the Moon and beyond are taken into account, developing waste recycling technologies becomes imperative and possibly mission enabling. Reduction of terrestrial waste streams while producing energy and/or valuable raw materials is an opportunity being realized by a new generation of visionary entrepreneurs; several relevant technologies are briefly compared, contrasted and assessed for space applications. A two-step approach to nonpetroleum raw materials utilization is presented; the first step involves production of supply or producer gas. This is akin to synthesis gas containing carbon oxides, hydrogen, and simple hydrocarbons. The second step involves production of fuel via the Sabatier process, a methanation reaction, or another gas-to-liquid technology, typically Fischer-Tropsch processing. Optimization to enhance the fraction of product stream relevant to transportation fuels via catalytic (process) development at NASA Glenn Research Center is described. Energy utilization is a concern for production of fuels whether for operation on the lunar or Martian surface, or beyond. The term green relates to not only mitigating excess carbon release but also to the efficiency of energy usage. For space, energy usage can be an essential concern. Another issue of great concern is minimizing impurities in the product stream(s), especially those that are potential health risks and/or could degrade operations through catalyst poisoning or equipment damage; technologies being developed to remove heteroatom impurities are discussed. Alternative technologies to utilize waste fluids, such as a propulsion option called the resistojet, are discussed. The resistojet is an electric propulsion technology with a powered thruster to vaporize and heat a propellant to high temperature, hot gases are subsequently passed through a converging-diverging nozzle expanding gases to supersonic velocities. A resistojet can accommodate many different fluids, including various reaction chamber (by-)products.

Aerospace Fuels from Nonpetroleum Raw Materials

NASA Technical Reports Server (NTRS)

Palaszewski, B. A.; Hepp, A. F.; Kulis, M. J.; Jaworske, D. A.

2013-01-01

Recycling human metabolic and plastic wastes minimizes cost and increases efficiency by reducing the need to transport consumables and return trash, respectively, from orbit to support a space station crew. If the much larger costs of transporting consumables to the Moon and beyond are taken into account, developing waste recycling technologies becomes imperative and possibly mission enabling. Reduction of terrestrial waste streams while producing energy and/or valuable raw materials is an opportunity being realized by a new generation of visionary entrepreneurs; several relevant technologies are briefly compared, contrasted and assessed for space applications. A two-step approach to nonpetroleum raw materials utilization is presented; the first step involves production of supply or producer gas. This is akin to synthesis gas containing carbon oxides, hydrogen, and simple hydrocarbons. The second step involves production of fuel via the Sabatier process, a methanation reaction, or another gas-to-liquid technology, typically Fischer- Tropsch processing. Optimization to enhance the fraction of product stream relevant to transportation fuels via catalytic (process) development at NASA GRC is described. Energy utilization is a concern for production of fuels whether for operation on the lunar or Martian surface, or beyond. The term "green" relates to not only mitigating excess carbon release but also to the efficiency of energy usage. For space, energy usage can be an essential concern. Other issues of great concern include minimizing impurities in the product stream(s), especially those that are potential health risks and/or could de-grade operations through catalyst poisoning or equipment damage; technologies being developed to remove heteroatom impurities are discussed. Alternative technologies to utilize waste fluids, such as a propulsion option called the resistojet, are discussed. The resistojet is an electric propulsion technology with a powered thruster to vaporize and heat a propellant to high temperature, hot gases are subsequently passed through a converging-diverging nozzle expanding gases to supersonic velocities. A resistojet can accommodate many different fluids, including various reaction chamber (by-)products.

Prospects for development of hydrocarbon raw materials resources reproduction

NASA Astrophysics Data System (ADS)

Vertakova, Y. V.; Babich, T. N.; Polozhentseva, Y. S.; Zvyagintsev, G. L.

2017-10-01

The article presents data on the influence of factors in the field of innovative technology of thermocatalytic depolymerization of solid household wastes (SHW) on the efficiency and prospects for the development of technogenic hydrocarbon raw materials resource reproduction. Process thermodynamics, reactions kinetics, the mechanism of thermolysis of secondary polymers in organic solvents have been studied by means of laboratory experiments. It is shown that different morphological groups of wastes dissolve practically at the same rate at temperatures of 250-310°C. A homogeneous product is formed in the liquid phase; the spread of values for the elements lies in the interval of 1.5-4.5 %; technological requirements of the stages of formation of boiler fuels are satisfied. Using the principles of patent analysis, new techniques of processing household waste components are proposed. The basics of energy-efficient and energy-saving processes of technogenic hydrocarbon raw materials resource reproduction have been laid. The possibility of increasing the production payback and intensification is shown. Ecological and demographic safety for population and technical and economic benefits from SHW processing are achieved.

Energy recovery from solid waste. [production engineering model

NASA Technical Reports Server (NTRS)

Dalton, C.; Huang, C. J.

1974-01-01

A recent group study on the problem of solid waste disposal provided a decision making model for a community to use in determining the future for its solid waste. The model is a combination of the following factors: technology, legal, social, political, economic and environmental. An assessment of local or community needs determines what form of energy recovery is desirable. A market for low pressure steam or hot water would direct a community to recover energy from solid waste by incineration to generate steam. A fuel gas could be produced by a process known as pyrolysis if there is a local market for a low heating value gaseous fuel. Solid waste can also be used directly as a fuel supplemental to coal in a steam generator. An evaluation of these various processes is made.

Performance evaluation of integrated solid-liquid wastes treatment technology in palm oil industry

NASA Astrophysics Data System (ADS)

Amelia, J. R.; Suprihatin, S.; Indrasti, N. S.; Hasanudin, U.; Fujie, K.

2017-05-01

The oil palm industry significantly contributes to environmental degradation if without waste management properly. The newest alternative waste management that might be developed is by utilizing the effluent of POME anaerobic digestion with EFB through integrated anaerobic decomposition process. The aim of this research was to examine and evaluate the integrated solid-liquid waste treatment technology in the view point of greenhouse gasses emission, compost, and biogas production. POME was treated in anaerobic digester with loading rate about 1.65 gCOD/L/day. Treated POME with dosis of 15 and 20 L/day was sprayed to the anaerobic digester that was filled of 25 kg of EFB. The results of research showed that after 60 days, the C/N ratio of EFB decreased to 12.67 and 10.96 for dosis of treated POME 15 and 20 L/day, respectively. In case of 60 day decomposition, the integrated waste treatment technology could produce 51.01 and 34.34 m3/Ton FFB which was equivalent with 636,44 and 466,58 kgCO2e/ton FFB for dosis of treated POME 15 and 20 L/day, respectively. The results of research also showed that integrated solid-liquid wastes treatment technology could reduce GHG emission about 421.20 and 251.34 kgCO2e/ton FFB for dosis of treated POME 15 and 20 L/day, respectively.

Evaluation of a Novel Approach for Reducing Emissions of Pharmaceuticals to the Environment

NASA Astrophysics Data System (ADS)

Bean, Thomas G.; Bergstrom, Ed; Thomas-Oates, Jane; Wolff, Amy; Bartl, Peter; Eaton, Bob; Boxall, Alistair B. A.

2016-10-01

Increased interest over the levels of pharmaceuticals detected in the environment has led to the need for new approaches to manage their emissions. Inappropriate disposal of unused and waste medicines and release from manufacturing plants are believed to be important pathways for pharmaceuticals entering the environment. In situ treatment technologies, which can be used on-site in pharmacies, hospitals, clinics, and at manufacturing plants, might provide a solution. In this study we explored the use of Pyropure, a microscale combined pyrolysis and gasification in situ treatment system for destroying pharmaceutical wastes. This involved selecting 17 pharmaceuticals, including 14 of the most thermally stable compounds currently in use and three of high environmental concern to determine the technology's success in waste destruction. Treatment simulation studies were done on three different waste types and liquid, solid, and gaseous emissions from the process were analyzed for parent pharmaceutical and known active transformation products. Gaseous emissions were also analyzed for NOx, particulates, dioxins, furans, and metals. Results suggest that Pyropure is an effective treatment process for pharmaceutical wastes: over 99 % of each study pharmaceutical was destroyed by the system without known active transformation products being formed during the treatment process. Emissions of the other gaseous air pollutants were within acceptable levels. Future uptake of the system, or similar in situ treatment approaches, by clinics, pharmacists, and manufacturers could help to reduce the levels of pharmaceuticals in the environment and reduce the economic and environmental costs of current waste management practices.

Ethanol from municipal cellulosic wastes

NASA Astrophysics Data System (ADS)

Parker, A. J., Jr.; Timbario, T. J.; Mulloney, J. A., Jr.

This paper addresses the use of municipal cellulosic wastes as a feedstock for producing ethanol fuels, and describes the application of enzymatic hydrolysis technology for their production. The concept incorporates recent process technology developments within the framework of an existing industry familiar with large-scale ethanol fermentation (the brewing industry). Preliminary indications are that the cost of producing ethanol via enzymatic hydrolysis in an existing plant with minimal facility modifications (low capital investment) can be significantly less than that of ethanol from grain fermentation.

40 CFR 406.53 - Effluent limitations guidelines representing the degree of effluent reduction attainable by the...

Code of Federal Regulations, 2010 CFR

2010-07-01

... technology economically achievable: there shall be no discharge of process waste water pollutants to... representing the degree of effluent reduction attainable by the application of the best available technology... by the application of the best available technology economically achievable. The following...

40 CFR 426.33 - Effluent limitations guidelines representing the degree of effluent reduction attainable by the...

Code of Federal Regulations, 2010 CFR

2010-07-01

... technology economically achievable: There shall be no discharge of process waste water pollutants to... representing the degree of effluent reduction attainable by the application of the best available technology... attainable by the application of the best available technology economically achievable. The following...

40 CFR 427.23 - Effluent limitations guidelines representing the degree of effluent reduction attainable by the...

Code of Federal Regulations, 2010 CFR

2010-07-01

... technology economically achievable: There shall be no discharge of process waste water pollutants to... representing the degree of effluent reduction attainable by the application of the best available technology... attainable by the application of the best available technology economically achievable. The following...

40 CFR 426.27 - Effluent limitations guidelines representing the degree of effluent reduction attainable by the...

Code of Federal Regulations, 2010 CFR

2010-07-01

... conventional pollutant control technology: There shall be no discharge of process waste water pollutants to... control technology. 426.27 Section 426.27 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY... attainable by the application of the best conventional pollutant control technology. The following...

40 CFR 418.77 - Effluent limitations guidelines representing the degree of effluent reduction attainable by the...

Code of Federal Regulations, 2010 CFR

2010-07-01

... conventional pollutant control technology: There shall be no discharge of process waste water pollutants to... control technology. 418.77 Section 418.77 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY... effluent reduction attainable by the application of the best conventional pollutant control technology. The...

40 CFR 426.13 - Effluent limitations guidelines representing the degree of effluent reduction attainable by the...

Code of Federal Regulations, 2010 CFR

2010-07-01

... technology economically achievable: There shall be no discharge of process waste water pollutants to... representing the degree of effluent reduction attainable by the application of the best available technology... by the application of the best available technology economically achievable. The following...

40 CFR 427.13 - Effluent limitations guidelines representing the degree of effluent reduction attainable by the...

Code of Federal Regulations, 2010 CFR

2010-07-01

... technology economically achievable: There shall be no discharge of process waste water pollutants to... representing the degree of effluent reduction attainable by the application of the best available technology... attainable by the application of the best available technology economically achievable. The following...

40 CFR 424.53 - Effluent limitations guidelines representing the degree of effluent reduction attainable by the...

Code of Federal Regulations, 2010 CFR

2010-07-01

... technology economically achievable: There shall be no discharge of process waste water pollutants to... representing the degree of effluent reduction attainable by the application of the best available technology... reduction attainable by the application of the best available technology economically achievable. The...

40 CFR 424.57 - Effluent limitations guidelines representing the degree of effluent reduction attainable by the...

Code of Federal Regulations, 2010 CFR

2010-07-01

... conventional pollutant control technology: There shall be no discharge of process waste water pollutants to... control technology. 424.57 Section 424.57 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY... reduction attainable by the application of the best conventional pollutant control technology. The following...

40 CFR 424.52 - Effluent limitations guidelines representing the degree of effluent reduction attainable by the...

Code of Federal Regulations, 2010 CFR

2010-07-01

... practicable control technology currently available (BPT): There shall be no discharge of process waste water... technology currently available. 424.52 Section 424.52 Protection of Environment ENVIRONMENTAL PROTECTION... effluent reduction attainable by the application of the best practicable control technology currently...

40 CFR 426.23 - Effluent limitations guidelines representing the degree of effluent reduction attainable by the...

Code of Federal Regulations, 2010 CFR

2010-07-01

... technology economically achievable: There shall be no discharge of process waste water pollutants to... representing the degree of effluent reduction attainable by the application of the best available technology... attainable by the application of the best available technology economically achievable. The following...

40 CFR 418.67 - Effluent limitations guidelines representing the degree of effluent reduction attainable by the...

Code of Federal Regulations, 2010 CFR

2010-07-01

... conventional pollutant control technology: There shall be no discharge of process waste water pollutants to... control technology. 418.67 Section 418.67 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY... attainable by the application of the best conventional pollutant control technology. The following...

40 CFR 406.33 - Effluent limitations guidelines representing the degree of effluent reduction attainable by the...

Code of Federal Regulations, 2010 CFR

2010-07-01

... technology economically achievable: there shall be no discharge of process waste water pollutants to... representing the degree of effluent reduction attainable by the application of the best available technology... by the application of the best available technology economically achievable. The following...

40 CFR 426.37 - Effluent limitations guidelines representing the degree of effluent reduction attainable by the...

Code of Federal Regulations, 2010 CFR

2010-07-01

... conventional pollutant control technology: There shall be no discharge of process waste water pollutants to... control technology. 426.37 Section 426.37 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY... attainable by the application of the best conventional pollutant control technology. The following...

40 CFR 436.182 - Effluent limitations guidelines representing the degree of effluent reduction attainable by the...

Code of Federal Regulations, 2011 CFR

2011-07-01

... technology currently available. 436.182 Section 436.182 Protection of Environment ENVIRONMENTAL PROTECTION... reduction attainable by the application of the best practicable control technology currently available. (a... practicable control technology currently available (BPT): (1) Discharges of process generated waste water and...

40 CFR 436.182 - Effluent limitations guidelines representing the degree of effluent reduction attainable by the...

Code of Federal Regulations, 2010 CFR

2010-07-01

... technology currently available. 436.182 Section 436.182 Protection of Environment ENVIRONMENTAL PROTECTION... reduction attainable by the application of the best practicable control technology currently available. (a... practicable control technology currently available (BPT): (1) Discharges of process generated waste water and...

Recent developments in chemical decontamination technology

DOE Office of Scientific and Technical Information (OSTI.GOV)

Wood, C.J.

1995-03-01

Chemical decontamination of parts of reactor coolant systems is a mature technology, used routinely in many BWR plants, but less frequently in PWRs. This paper reviews recent developments in the technology - corrosion minimization, waste processing and full system decontamination, including the fuel. Earlier work was described in an extensive review published in 1990.

Knowledge and technology transfer to improve the municipal solid waste management system of Durango City, Mexico.

PubMed

Valencia-Vázquez, Roberto; Pérez-López, Maria E; Vicencio-de-la-Rosa, María G; Martínez-Prado, María A; Rubio-Hernández, Rubén

2014-09-01

As society evolves its welfare level increases, and as a consequence the amount of municipal solid waste increases, imposing great challenges to municipal authorities. In developed countries, municipalities have established integrated management schemes to handle, treat, and dispose of municipal solid waste in an economical and environmentally sound manner. Municipalities of developing and transition countries are not exempted from the challenges involving municipal solid waste handling, but their task is not easy to accomplish since they face budget deficits, lack of knowledge, and deficiencies in infrastructure and equipment. In the northern territory of Mexico, the municipality of Durango is facing the challenge of increased volumes of waste with a lack of adequate facilities and infrastructure. This article analyses the evolution of the municipal solid waste management of Durango city, which includes actions such as proper facilities construction, equipment acquisition, and the implementation of social programmes. The World Bank, offering courses to municipal managers on landfill operation and waste management, promoted the process of knowledge and technology transfer. Thereafter, municipal authorities attended regional and some international workshops on waste management. In addition they followed suggestions of international contractors and equipment dealers with the intention to improve the situation of the waste management of the city. After a 15-year period, transfer of knowledge and technology resulted in a modern municipal solid waste management system in Durango municipality. The actual system did not reach the standard levels of an integrated waste management system, nevertheless, a functional evaluation shows clear indications that municipality actions have put them on the right pathway. © The Author(s) 2014.

Management strategies on the industrialization road of state-of-the-art technologies for e-waste recycling: the case study of electrostatic separation--a review.

PubMed

Xue, Mianqiang; Li, Jia; Xu, Zhenming

2013-02-01

Electronic waste (e-waste) management is pressing as global production has increased significantly in the past few years and is rising continuously at a fast rate. Many countries are facing hazardous e-waste mountains, most of which are disposed of by backyard recyclers, creating serious threats to public health and ecosystems. Industrialization of state-of-the-art recycling technologies is imperative to enhance the comprehensive utilization of resources and to protect the environment. This article aims to provide an overview of management strategies solving the crucial problems during the process of industrialization. A typical case study of electrostatic separation for recycling waste printed circuit boards was discussed in terms of parameters optimization, materials flow control, noise assessment, risk assessment, economic evaluation and social benefits analysis. The comprehensive view provided by the review could be helpful to the progress of the e-waste recycling industry.

Life support systems analysis and technical trades for a lunar outpost

NASA Technical Reports Server (NTRS)

Ferrall, J. F.; Ganapathi, G. B.; Rohatgi, N. K.; Seshan, P. K.

1994-01-01

The NASA/JPL life support systems analysis (LISSA) software tool was used to perform life support system analysis and technology trades for a Lunar Outpost. The life support system was modeled using a chemical process simulation program on a steady-state, one-person, daily basis. Inputs to the LiSSA model include metabolic balance load data, hygiene load data, technology selection, process operational assumptions and mission parameter assumptions. A baseline set of technologies has been used against which comparisons have been made by running twenty-two cases with technology substitutions. System, subsystem, and technology weights and powers are compared for a crew of 4 and missions of 90 and 600 days. By assigning a weight value to power, equivalent system weights are compared. Several less-developed technologies show potential advantages over the baseline. Solid waste treatment technologies show weight and power disadvantages but one could have benefits associated with the reduction of hazardous wastes and very long missions. Technology development towards reducing the weight of resupplies and lighter materials of construction was recommended. It was also recommended that as technologies are funded for development, contractors should be required to generate and report data useful for quantitative technology comparisons.

Trends in food waste valorization for the production of chemicals, materials and fuels: Case study South and Southeast Asia.

PubMed

Ong, Khai Lun; Kaur, Guneet; Pensupa, Nattha; Uisan, Kristiadi; Lin, Carol Sze Ki

2018-01-01

Staggering amounts of food waste are being generated in Asia by means of agricultural processing, food transportation and storage, and human food consumption activities. This along with the recent sustainable development goals of food security, environmental protection, and energy efficiency are the key drivers for food waste valorization. The aim of this review is to provide an insight on the latest trends in food waste valorization in Asian countries such as India, Thailand, Singapore, Malaysia and Indonesia. Landfilling, incineration, and composting are the first-generation food waste processing technologies. The advancement of valorisation alternatives to tackle the food waste issue is the focus of this review. Furthermore, a series of examples of key food waste valorization schemes in this Asian region as case studies to demonstrate the advancement in bioconversions in these countries are described. Finally, important legislation aspects for food waste disposal in these Asian countries are also reported. Copyright © 2017 Elsevier Ltd. All rights reserved.

Periodic processes in vapor phase biofiltration

DOE Office of Scientific and Technical Information (OSTI.GOV)

Moe, W.M.; Irvine, R.L.

1998-07-01

Most industrial processes and environmental remediation activities generate large volumes of air contaminated with low concentrations of volatile organic compounds. Carbon adsorption is the most widely used conventional treatment technology, but it has many drawbacks including secondary waste streams and excessive regeneration costs. Biofiltration, a microbial-based treatment technology, removes and biodegrades contaminants from a wide variety of waste streams without the disadvantages of carbon adsorption. In biofiltration, contaminated air flows through a packed bed containing microorganisms which convert contaminants primarily into carbon dioxide, water, and biomass. This paper describes how periodically operated, controlled unsteady state conditions were imposed on biofiltersmore » which used a new polyurethane foam medium that couples high porosity, suitable pore size, and low density with an ability to sorb water. The potential benefits associated with the controlled, unsteady-state operation of biofilters containing this new polyurethane foam medium are described herein. An example system treating a toluene contaminated waste gas is presented.« less

Technoeconomic aspects of alternative municipal solid wastes treatment methods.

PubMed

Economopoulos, Alexander P

2010-04-01

This paper considers selected treatment technologies for comingled domestic and similar wastes and provides technoeconomic data and information, useful for the development of strategic management plans. For this purpose, treatment technologies of interest are reviewed and representative flow diagrams, along with material and energy balances, are presented for the typical composition of wastes in Greece; possible difficulties in the use of treatment products, along with their management implications, are discussed, and; cost functions are developed, allowing assessment of the initial capital investment and annual operating costs. Based on the latter, cost functions are developed for predicting the normalized treatment costs of alternative methods (in euro/t of MSW treated), as function of the quantity of MSW processed by plants built and operated (a) by municipality associations, and (b) by private enterprises. Finally, the alternative technologies considered are evaluated on the basis of their cost aspects, product utilization and compatibility with the EU waste framework Directive 2008/98. Copyright 2009 Elsevier Ltd. All rights reserved.

Radionuclide Retention Mechanisms in Secondary Waste-Form Testing: Phase II

DOE Office of Scientific and Technical Information (OSTI.GOV)

Um, Wooyong; Valenta, Michelle M.; Chung, Chul-Woo

2011-09-26

This report describes the results from laboratory tests performed at Pacific Northwest National Laboratory (PNNL) for Washington River Protection Solutions (WRPS) to evaluate candidate stabilization technologies that have the potential to successfully treat liquid secondary waste stream effluents produced by the Hanford Tank Waste Treatment and Immobilization Plant (WTP). WRPS is considering the design and construction of a Solidification Treatment Unit (STU) for the Effluent Treatment Facility (ETF) at Hanford. The ETF, a multi-waste, treatment-and-storage unit that has been permitted under the Resource Conservation and Recovery Act (RCRA), can accept dangerous, low-level, and mixed wastewaters for treatment. The STU needsmore » to be operational by 2018 to receive secondary liquid waste generated during operation of the WTP. The STU will provide the additional capacity needed for ETF to process the increased volume of secondary waste expected to be produced by WTP. This report on radionuclide retention mechanisms describes the testing and characterization results that improve understanding of radionuclide retention mechanisms, especially for pertechnetate, {sup 99}TcO{sub 4}{sup -} in four different waste forms: Cast Stone, DuraLith alkali aluminosilicate geopolymer, encapsulated fluidized bed steam reforming (FBSR) product, and Ceramicrete phosphate bonded ceramic. These data and results will be used to fill existing data gaps on the candidate technologies to support a decision-making process that will identify a subset of the candidate waste forms that are most promising and should undergo further performance testing.« less

APPLICATION OF THERMAL DESORPTION TECHNOLOGIES TO HAZARDOUS WASTE SITES

EPA Science Inventory

Thermal desorption is a separation process frequently used to remediate many Superfund sites. Thermal desorption technologies are recommended and used because of (1) the wide range of organic contaminants effectively treated, (2) availability and mobility of commercial systems, ...

SUMMARY REPORT: SMALL COMMUNITY WATER AND WASTE- WATER TREATMENT

EPA Science Inventory

This summary report presents information on the unique needs of small communities facing new water and wastewater treatment requirements. t contains three main sections: technology overviews (each presents a process description, O&M requirements, technology limitations, and finan...

UNDERSTANDING BIOREMEDIATION: A GUIDEBOOK FOR CITIZENS

EPA Science Inventory

Bioremediation—a process that uses microorganisms to transform harmful substances to nontoxic compounds—is one of the most promising new technologies for treating chemical spills and hazardous waste problems. In order to improve this technology and better understand its cap...

Drivers for innovation in waste-to-energy technology.

PubMed

Gohlke, Oliver; Martin, Johannes

2007-06-01

This paper summarizes developments made in the field of waste-to-energy technology between the 1980s and the present. In the USA, many waste-to-energy systems were developed in the 1980s and early 1990s. These plants generated power relatively efficiently (typically 23%) in 60 bar/ 443 degrees C boilers. Unfortunately, the development came to a stop when the US Supreme Court rejected the practice of waste flow control in 1994. Consequently, waste was directed to mega-landfills, associated with very negative environmental impacts. However, given landfill taxes and increased fuel prices, new waste-to-energy projects have recently been developed. Attractive premiums for renewable power production from municipal waste have been introduced in several European countries. This triggered important innovations in the field of improved energy recovery. Examples of modern waste-to-energy plants are Brescia and Amsterdam with net efficiencies of 24 and 30%, respectively. Incineration is traditionally preferred in Japan due to space constraints. New legislation promoted ash melting or gasification to obtain improved ash quality. However, these processes reduce the efficiency in terms of energy, cost and availability. A new oxygen-enriched waste-to-energy system is under development in order to better achieve the required inert ash quality.

Life-cycle-assessment of the historical development of air pollution control and energy recovery in waste incineration.

PubMed

Damgaard, Anders; Riber, Christian; Fruergaard, Thilde; Hulgaard, Tore; Christensen, Thomas H

2010-07-01

Incineration of municipal solid waste is a debated waste management technology. In some countries it is the main waste management option whereas in other countries it has been disregarded. The main discussion point on waste incineration is the release of air emissions from the combustion of the waste, but also the energy recovery efficiency has a large importance. The historical development of air pollution control in waste incineration was studied through life-cycle-assessment modelling of eight different air pollution control technologies. The results showed a drastic reduction in the release of air emissions and consequently a significant reduction in the potential environmental impacts of waste incineration. Improvements of a factor 0.85-174 were obtained in the different impact potentials as technology developed from no emission control at all, to the best available emission control technologies of today (2010). The importance of efficient energy recovery was studied through seven different combinations of heat and electricity recovery, which were modelled to substitute energy produced from either coal or natural gas. The best air pollution control technology was used at the incinerator. It was found that when substituting coal based energy production total net savings were obtained in both the standard and toxic impact categories. However, if the substituted energy production was based on natural gas, only the most efficient recovery options yielded net savings with respect to the standard impacts. With regards to the toxic impact categories, emissions from the waste incineration process were always larger than those from the avoided energy production based on natural gas. The results shows that the potential environmental impacts from air emissions have decreased drastically during the last 35 years and that these impacts can be partly or fully offset by recovering energy which otherwise should have been produced from fossil fuels like coal or natural gas. Copyright (c) 2010 Elsevier Ltd. All rights reserved.

The Use of Microwave Incineration to Process Biological Wastes

NASA Technical Reports Server (NTRS)

Sun, Sidney C.; Srinivasan, Venkatesh; Covington, Alan (Technical Monitor)

1994-01-01

The handling and disposal of solid waste matter that has biological or biohazardous components is a difficult issue for hospitals, research laboratories, and industry. NASA faces the same challenge as it is developing regenerative systems that will process waste materials into materials that can be used to sustain humans living in space for extended durations. Plants provide critical functions in such a regenerative life support scheme in that they photosynthesize carbon dioxide and water into glucose and oxygen. The edible portions of the plant provide a food source for the crew. Inedible portions can be processed into materials that are more recyclable. The Advanced Life Support Division at NASA Ames Research Center has been evaluating a microwave incinerator that will oxidize inedible plant matter into carbon dioxide and water. The commercially available microwave incinerator is produced by Matsushita Electronic Instruments Corporation of Japan. Microwave incineration is a technology that is simple, safe, and compact enough for home use. It also has potential applications for institutions that produce biological or biohazardous waste. The incinerator produces a sterile ash that has only 13% of the mass of the original waste. The authors have run several sets of tests with the incinerator to establish its viability in processing biological material. One goal of the tests is to show that the incinerator does not generate toxic compounds as a byproduct of the combustion process. This paper will describe the results of the tests, including analyses of the resulting ash and exhaust gases. The significance of the results and their implications on commercial applications of the technology will also be discussed.

Waste streams in a crewed space habitat

NASA Technical Reports Server (NTRS)

Wydeven, T.; Golub, M. A.

1991-01-01

A judicious compilation of generation rates and chemical compositions of potential waste feed streams in a typical crewed space habitat was made in connection with the waste-management aspect of NASA's Physical/Chemical Closed-Loop Life Support Program. Waste composition definitions are needed for the design of waste-processing technologies involved in closing major life support functions in future long-duration human space missions. Tables of data for the constituents and chemical formulas of the following waste streams are presented and discussed: human urine, feces, hygiene (laundry and shower) water, cleansing agents, trash, humidity condensate, dried sweat, and trace contaminants. Tables of data on dust generation and pH values of the different waste streams are also presented and discussed.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Hadi, Pejman; Ning, Chao; Ouyang, Weiyi

Highlights: • Environmental impacts of electronic waste and specifically waste printed circuit boards. • Review of the recycling techniques of waste printed circuit boards. • Advantages of physico-mechanical recycling techniques over chemical methods. • Utilization of nonmetallic fraction of waste printed circuit boards as modifier/filler. • Recent advances in the use of nonmetallic fraction of waste printed circuit boards as precursor. - Abstract: Electronic waste, including printed circuit boards, is growing at an alarming rate due to the accelerated technological progress and the shorter lifespan of the electronic equipment. In the past decades, due to the lack of proper economicmore » and environmentally-benign recycling technologies, a major fraction of e-waste generated was either destined to landfills or incinerated with the sole intention of its disposal disregarding the toxic nature of this waste. Recently, with the increasing public awareness over their environment and health issues and with the enaction of more stringent regulations, environmentally-benign recycling has been driven to be an alternative option partially replacing the traditional eco-unfriendly disposal methods. One of the most favorable green technologies has been the mechanical separation of the metallic and nonmetallic fraction of the waste printed circuit boards. Although metallic fraction, as the most profitable component, is used to generate the revenue of the separation process, the nonmetallic fraction (NMF) has been left isolated. Herein, the recent developments in the application of NMF have been comprehensively reviewed and an eco-friendly emerging usage of NMF as a value-added material for sustainable remediation has been introduced.« less

Knowledge-based and model-based hybrid methodology for comprehensive waste minimization in electroplating plants

NASA Astrophysics Data System (ADS)

Luo, Keqin

1999-11-01

The electroplating industry of over 10,000 planting plants nationwide is one of the major waste generators in the industry. Large quantities of wastewater, spent solvents, spent process solutions, and sludge are the major wastes generated daily in plants, which costs the industry tremendously for waste treatment and disposal and hinders the further development of the industry. It becomes, therefore, an urgent need for the industry to identify technically most effective and economically most attractive methodologies and technologies to minimize the waste, while the production competitiveness can be still maintained. This dissertation aims at developing a novel WM methodology using artificial intelligence, fuzzy logic, and fundamental knowledge in chemical engineering, and an intelligent decision support tool. The WM methodology consists of two parts: the heuristic knowledge-based qualitative WM decision analysis and support methodology and fundamental knowledge-based quantitative process analysis methodology for waste reduction. In the former, a large number of WM strategies are represented as fuzzy rules. This becomes the main part of the knowledge base in the decision support tool, WMEP-Advisor. In the latter, various first-principles-based process dynamic models are developed. These models can characterize all three major types of operations in an electroplating plant, i.e., cleaning, rinsing, and plating. This development allows us to perform a thorough process analysis on bath efficiency, chemical consumption, wastewater generation, sludge generation, etc. Additional models are developed for quantifying drag-out and evaporation that are critical for waste reduction. The models are validated through numerous industrial experiments in a typical plating line of an industrial partner. The unique contribution of this research is that it is the first time for the electroplating industry to (i) use systematically available WM strategies, (ii) know quantitatively and accurately what is going on in each tank, and (iii) identify all WM opportunities through process improvement. This work has formed a solid foundation for the further development of powerful WM technologies for comprehensive WM in the following decade.

An Industrial Ecology Approach to Municipal Solid Waste ...

EPA Pesticide Factsheets

The organic fraction of municipal solid waste provides abundant opportunities for industrial ecology-based symbiotic use. Energy production, economics, and environmental aspects are analyzed for four alternatives based on different technologies: incineration with energy recovery, gasification, anaerobic digestion, and fermentation. In these cases electricity and ethanol are the products considered, but other products and attempts at symbiosis can be made. The four technologies are in various states of commercial development. To highlight their relative complexities some adjustable parameters which are important for the operability of each process are discussed. While these technologies need to be considered for specific locations and circumstances, generalized economic and environmental information suggests relative comparisons for newly conceptualized processes. The results of industrial ecology-based analysis suggest that anaerobic digestion may improve seven emission categories, while fermentation, gasification, and incineration successively improve fewer emissions. A conceptual level analysis indicates that gasification, anaerobic digestion, and fermentation alternatives lead to positive economic results. In each case the alternatives and their assumptions need further analysis for any particular community. Presents information useful for analyzing the sustainability of alternatives for the management of municipal solid waste.

Robotics for mixed waste operations, demonstration description

DOE Office of Scientific and Technical Information (OSTI.GOV)

Ward, C.R.

The Department of Energy (DOE) Office of Technology Development (OTD) is developing technology to aid in the cleanup of DOE sites. Included in the OTD program are the Robotics Technology Development Program and the Mixed Waste Integrated Program. These two programs are working together to provide technology for the cleanup of mixed waste, which is waste that has both radioactive and hazardous constituents. There are over 240,000 cubic meters of mixed low level waste accumulated at DOE sites and the cleanup is expected to generate about 900,000 cubic meters of mixed low level waste over the next five years. Thismore » waste must be monitored during storage and then treated and disposed of in a cost effective manner acceptable to regulators and the states involved. The Robotics Technology Development Program is developing robotics technology to make these tasks safer, better, faster and cheaper through the Mixed Waste Operations team. This technology will also apply to treatment of transuranic waste. The demonstration at the Savannah River Site on November 2-4, 1993, showed the progress of this technology by DOE, universities and industry over the previous year. Robotics technology for the handling, characterization and treatment of mixed waste as well robotics technology for monitoring of stored waste was demonstrated. It was shown that robotics technology can make future waste storage and waste treatment facilities better, faster, safer and cheaper.« less

Waste disposal technology transfer matching requirement clusters for waste disposal facilities in China.

PubMed

Dorn, Thomas; Nelles, Michael; Flamme, Sabine; Jinming, Cai

2012-11-01

Even though technology transfer has been part of development aid programmes for many decades, it has more often than not failed to come to fruition. One reason is the absence of simple guidelines or decision making tools that help operators or plant owners to decide on the most suitable technology to adopt. Practical suggestions for choosing the most suitable technology to combat a specific problem are hard to get and technology drawbacks are not sufficiently highlighted. Western counterparts in technology transfer or development projects often underestimate or don't sufficiently account for the high investment costs for the imported incineration plant; the differing nature of Chinese MSW; the need for trained manpower; and the need to treat flue gas, bunker leakage water, and ash, all of which contain highly toxic elements. This article sets out requirements for municipal solid waste disposal plant owner/operators in China as well as giving an attribute assessment for the prevalent waste disposal plant types in order to assist individual decision makers in their evaluation process for what plant type might be most suitable in a given situation. There is no 'best' plant for all needs and purposes, and requirement constellations rely on generalisations meaning they cannot be blindly applied, but an alignment of a type of plant to a type of owner or operator can realistically be achieved. To this end, a four-step approach is suggested and a technology matrix is set out to ease the choice of technology to transfer and avoid past errors. The four steps are (1) Identification of plant owner/operator requirement clusters; (2) Determination of different municipal solid waste (MSW) treatment plant attributes; (3) Development of a matrix matching requirement clusters to plant attributes; (4) Application of Quality Function Deployment Method to aid in technology localisation. The technology transfer matrices thus derived show significant performance differences between the various technologies available. It is hoped that the resulting research can build a bridge between technology transfer research and waste disposal research in order to enhance the exchange of more sustainable solutions in future. Copyright © 2012 Elsevier Ltd. All rights reserved.

Control technology assessment of hazardous waste disposal operations in chemicals manufacturing: walk-through survey report of Olin Chemicals Group, Charleston, Tennessee

DOE Office of Scientific and Technical Information (OSTI.GOV)

Crandall, M.S.

1983-08-01

A walk through survey was conducted to assess control technology for hazardous wastes disposal operations at Olin Chemicals Group (SIC-2800, SIC-2812, SIC-2819), Charleston, Tennessee in May 1982. Hazardous wastes generated at the facility included brine sludge, thick mercury (7439954) (Hg) butter, and calcium-hypochlorite (7778543). An estimated 8500 tons of waste were disposed of annually. The Hg waste underwent a retorting process that recycled the Hg. The final detoxified waste was land filled. Brine sludge and calcium-hypochlorite were also land filled. No controls beyond those normally used at such sites were found at the landfills. Periodic monitoring of Hg vapor concentrationsmore » was conducted by the company. Medical monitoring of urine for Hg exposure was conducted. Specific limits were set for urinary Hg concentrations. When these limits were exceeded the workers were removed from exposure. Personal protective equipment consisted of hard hats, safety glasses, and spirators specially designed for Hg exposure. The author concludes that the hazardous waste disposal and treatment operations at the facility are well controlled.« less

Waste Separations and Pretreatment Workshop report

DOE Office of Scientific and Technical Information (OSTI.GOV)

Cruse, J.M.; Harrington, R.A.; Quadrel, M.J.

1994-01-01

This document provides the minutes from the Waste Separations and Pretreatment Workshop sponsored by the Underground Storage Tank-Integrated Demonstration in Salt Lake City, Utah, February 3--5, 1993. The Efficient Separations and Processing-Integrated Program and the Hanford Site Tank Waste Remediation System were joint participants. This document provides the detailed minutes, including responses to questions asked, an attendance list, reproductions of the workshop presentations, and a revised chart showing technology development activities.

Present status of recycling waste mobile phones in China: a review.

PubMed

Li, Jingying; Ge, Zhongying; Liang, Changjin; An, Ni

2017-07-01

A large number of waste mobile phones have already been generated and are being generated. Various countries around the world have all been positively exploring the way of recycling and reuse when facing such a large amount of waste mobile phones. In some countries, processing waste mobile phones has been forming a complete industrial chain, which can not only recycle waste mobile phones to reduce their negative influence on the environment but also turn waste into treasure to acquire economic benefits dramatically. However, the situation of recycling waste mobile phones in China is not going well. Waste mobile phones are not formally covered by existing regulations and policies for the waste electric and electronic equipment in China. In order to explore an appropriate system to recover waste mobile phones, the mobile phone production and the amount of waste mobile phones are introduced in this paper, and status of waste mobile phones recycling is described; then, the disposal technology of electronic waste that would be most likely to be used for processing of electronic waste in industrial applications in the near future is reviewed. Finally, rationalization proposals are put forward based on the current recovery status of waste mobile phones for the purpose of promoting the development of recycling waste mobile phones in developing countries with a special emphasis on China.

Sustainable recycling technologies for Solar PV off-grid system

NASA Astrophysics Data System (ADS)

Uppal, Bhavesh; Tamboli, Adish; Wubhayavedantapuram, Nandan

2017-11-01

Policy makers throughout the world have accepted climate change as a repercussion of fossil fuel exploitation. This has led the governments to integrate renewable energy streams in their national energy mix. PV off-grid Systems have been at the forefront of this transition because of their permanently increasing efficiency and cost effectiveness. These systems are expected to produce large amount of different waste streams at the end of their lifetime. It is important that these waste streams should be recycled because of the lack of available resources. Our study found that separate researches have been carried out to increase the efficiencies of recycling of individual PV system components but there is a lack of a comprehensive methodical research which details efficient and sustainable recycling processes for the entire PV off-grid system. This paper reviews the current and future recycling technologies for PV off-grid systems and presents a scheme of the most sustainable recycling technologies which have the potential for adoption. Full Recovery End-of-Life Photovoltaic (FRELP) recycling technology can offer opportunities to sustainably recycle crystalline silicon PV modules. Electro-hydrometallurgical process & Vacuum technologies can be used for recovering lead from lead acid batteries with a high recovery rate. The metals in the WEEE can be recycled by using a combination of biometallurgical technology, vacuum metallurgical technology and other advanced metallurgical technologies (utrasonical, mechano-chemical technology) while the plastic components can be effectively recycled without separation by using compatibilizers. All these advanced technologies when used in combination with each other provide sustainable recycling options for growing PV off-grid systems waste. These promising technologies still need further improvement and require proper integration techniques before implementation.

40 CFR 426.112 - Effluent limitations guidelines representing the degree of effluent reduction attainable by the...

Code of Federal Regulations, 2014 CFR

2014-07-01

... technology currently available (BPT). (The fluoride and lead limitations are applicable to the abrasive polishing and acid polishing waste water streams while the TSS, oil, and pH limitations are applicable to the entire process waste water stream): Effluent characteristic Effluent limitations Maximum for any 1...

40 CFR 426.112 - Effluent limitations guidelines representing the degree of effluent reduction attainable by the...

Code of Federal Regulations, 2012 CFR

2012-07-01

... technology currently available (BPT). (The fluoride and lead limitations are applicable to the abrasive polishing and acid polishing waste water streams while the TSS, oil, and pH limitations are applicable to the entire process waste water stream): Effluent characteristic Effluent limitations Maximum for any 1...

40 CFR 426.112 - Effluent limitations guidelines representing the degree of effluent reduction attainable by the...

Code of Federal Regulations, 2013 CFR

2013-07-01

... technology currently available (BPT). (The fluoride and lead limitations are applicable to the abrasive polishing and acid polishing waste water streams while the TSS, oil, and pH limitations are applicable to the entire process waste water stream): Effluent characteristic Effluent limitations Maximum for any 1...

Combustion Power Unit--400: CPU-400.

ERIC Educational Resources Information Center

Combustion Power Co., Palo Alto, CA.

Aerospace technology may have led to a unique basic unit for processing solid wastes and controlling pollution. The Combustion Power Unit--400 (CPU-400) is designed as a turboelectric generator plant that will use municipal solid wastes as fuel. The baseline configuration is a modular unit that is designed to utilize 400 tons of refuse per day…

COAL CONVERSION CONTROL TECHNOLOGY. VOLUME II. GASEOUS EMISSIONS; SOLID WASTES

EPA Science Inventory

This volume is the product of an information-gathering effort relating to coal conversion process streams. Available and developing control technology has been evaluated in view of the requirements of present and proposed federal, state, regional, and international environmental ...

Waste-to-Energy Decision Support Method for Forward Deployed Forces

DTIC Science & Technology

2014-03-27

15 Gasification ...stable electrical source to generate the plasma. Thermal WTE technology includes three subtypes called incineration, gasification , and pyrolysis...unfavorable public perception associated with the emissions produced by the technology. Gasification Gasification is a thermal process in which

Bioenergy Potential Based on Vinasse From Ethanol Industrial Waste to Green Energy Sustainability

NASA Astrophysics Data System (ADS)

Harihastuti, Nani; Marlena, Bekti

2018-02-01

The waste water from alcohol industry is called vinasse has a high organic content, with BOD5 = 109.038 mg / l, COD = 353.797 mg / l and TSS = 7200 mg / l, pH 4-5 with a temperature of around 40-50ºC. The current treatment of alcohol waste water, most still using facultative anaerobic technology with open ponds that are only covered with HDPE plastics. This technology produces less optimal biogas and has a weakness that is the hydraulic residence time (HRT) for long (40-50 days), wide land needs, low COD reduction efficiency as well as high risk of fire and leakage of biogas release high to trigger the occurrence of greenhouse gas and global warming effects. Development of technology with innovation reactor integration model Fixed Dome-Hybrid Anaerobic Filter aims to expand the contact area between the substrate and microbial with modification of the substrate flow system and the area of the filter and integrate with the gas accumulator. The design of this Fixed Dome-Hybrid Anaerobic filter integration model technology, has the advantage of producing optimal bioenergy with CH4 more than 50% content with decrease of COD more than 85% and hydraulic residence time of about 10 (ten) days, bioenergy result is renewable energy made from raw material vinasse from alcohol industrial waste which can be utilized for fuel substitution on the distillation process or boiler process of the industry in a sustainable and cleaner environment.

Approach of technical decision-making by element flow analysis and Monte-Carlo simulation of municipal solid waste stream.

PubMed

Tian, Bao-Guo; Si, Ji-Tao; Zhao, Yan; Wang, Hong-Tao; Hao, Ji-Ming

2007-01-01

This paper deals with the procedure and methodology which can be used to select the optimal treatment and disposal technology of municipal solid waste (MSW), and to provide practical and effective technical support to policy-making, on the basis of study on solid waste management status and development trend in China and abroad. Focusing on various treatment and disposal technologies and processes of MSW, this study established a Monte-Carlo mathematical model of cost minimization for MSW handling subjected to environmental constraints. A new method of element stream (such as C, H, O, N, S) analysis in combination with economic stream analysis of MSW was developed. By following the streams of different treatment processes consisting of various techniques from generation, separation, transfer, transport, treatment, recycling and disposal of the wastes, the element constitution as well as its economic distribution in terms of possibility functions was identified. Every technique step was evaluated economically. The Mont-Carlo method was then conducted for model calibration. Sensitivity analysis was also carried out to identify the most sensitive factors. Model calibration indicated that landfill with power generation of landfill gas was economically the optimal technology at the present stage under the condition of more than 58% of C, H, O, N, S going to landfill. Whether or not to generate electricity was the most sensitive factor. If landfilling cost increases, MSW separation treatment was recommended by screening first followed with incinerating partially and composting partially with residue landfilling. The possibility of incineration model selection as the optimal technology was affected by the city scale. For big cities and metropolitans with large MSW generation, possibility for constructing large-scale incineration facilities increases, whereas, for middle and small cities, the effectiveness of incinerating waste decreases.

Effective solidification/stabilisation of mercury-contaminated wastes using zeolites and chemically bonded phosphate ceramics.

PubMed

Zhang, Shaoqing; Zhang, Xinyan; Xiong, Ya; Wang, Guoping; Zheng, Na

2015-02-01

In this study, two kinds of zeolites materials (natural zeolite and thiol-functionalised zeolite) were added to the chemically bonded phosphate ceramic processes to treat mercury-contaminated wastes. Strong promotion effects of zeolites (natural zeolite and thiol-functionalised zeolite) on the stability of mercury in the wastes were obtained and these technologies showed promising advantages toward the traditional Portland cement process, i.e. using Portland cement as a solidification agent and natural or thiol-functionalised zeolite as a stabilisation agent. Not only is a high stabilisation efficiency (lowered the Toxicity Characteristic Leaching Procedure Hg by above 10%) obtained, but also a lower dosage of solidification (for thiol-functionalised zeolite as stabilisation agent, 0.5 g g(-1) and 0.7 g g(-1) for chemically bonded phosphate ceramic and Portland cement, respectively) and stabilisation agents (for natural zeolite as stabilisation agent, 0.35 g g(-1) and 0.4 g g(-1) for chemically bonded phosphate ceramic and Portland cement, respectively) were used compared with the Portland cement process. Treated by thiol-functionalised zeolite and chemically bonded phosphate ceramic under optimum parameters, the waste containing 1500 mg Hg kg(-1) passed the Toxicity Characteristic Leaching Procedure test. Moreover, stabilisation/solidification technology using natural zeolite and chemically bonded phosphate ceramic also passed the Toxicity Characteristic Leaching Procedure test (the mercury waste containing 625 mg Hg kg(-1)). Moreover, the presence of chloride and phosphate did not have a negative effect on the chemically bonded phosphate ceramic/thiol-functionalised zeolite treatment process; thus, showing potential for future application in treatment of 'difficult-to-manage' mercury-contaminated wastes or landfill disposal with high phosphate and chloride content. © The Author(s) 2015.

Waste management of printed wiring boards: a life cycle assessment of the metals recycling chain from liberation through refining.

PubMed

Xue, Mianqiang; Kendall, Alissa; Xu, Zhenming; Schoenung, Julie M

2015-01-20

Due to economic and societal reasons, informal activities including open burning, backyard recycling, and landfill are still the prevailing methods used for electronic waste treatment in developing countries. Great efforts have been made, especially in China, to promote formal approaches for electronic waste management by enacting laws, developing green recycling technologies, initiating pilot programs, etc. The formal recycling process can, however, engender environmental impact and resource consumption, although information on the environmental loads and resource consumption is currently limited. To quantitatively assess the environmental impact of the processes in a formal printed wiring board (PWB) recycling chain, life cycle assessment (LCA) was applied to a formal recycling chain that includes the steps from waste liberation through materials refining. The metal leaching in the refining stage was identified as a critical process, posing most of the environmental impact in the recycling chain. Global warming potential was the most significant environmental impact category after normalization and weighting, followed by fossil abiotic depletion potential, and marine aquatic eco-toxicity potential. Scenario modeling results showed that variations in the power source and chemical reagents consumption had the greatest influence on the environmental performance. The environmental impact from transportation used for PWB collection was also evaluated. The results were further compared to conventional primary metals production processes, highlighting the environmental benefit of metal recycling from waste PWBs. Optimizing the collection mode, increasing the precious metals recovery efficiency in the beneficiation stage and decreasing the chemical reagents consumption in the refining stage by effective materials liberation and separation are proposed as potential improvement strategies to make the recycling chain more environmentally friendly. The LCA results provide environmental information for the improvement of future integrated technologies and electronic waste management.

Waste treatment: Beverage industry. January 1984-October 1989 (Citations from the Food Science and Technology Abstracts data base). Report for January 1984-October 1989

DOE Office of Scientific and Technical Information (OSTI.GOV)

Not Available

This bibliography contains citations concerning the treatment of effluents from beverage-industry processes. Particular emphasis is on brewery and winery effluent treatment. Characteristics of the waste products and pre-treatment and treatment methods are discussed. Regulations governing waste disposal are also considered along with the economics of waste disposal. Both alcoholic and soft drink beverages are considered. (This updated bibliography contains 223 citations, all of which are new entries to the previous edition.)

Waste treatment: Beverage industry. January 1972-December 1983 (Citations from the Food Science and Technology Abstracts data base). Report for January 1972-December 1983

DOE Office of Scientific and Technical Information (OSTI.GOV)

Not Available

This bibliography contains citations concerning the treatment of effluents from beverage-industry processes. Particular emphasis is on brewery and winery effluent treatment. Characteristics of the waste products and pre-treatment and treatment methods are discussed. Regulations governing waste disposal are also considered along with the economics of waste disposal. Both alcoholic and soft drink beverages are considered. (This updated bibliography contains 312 citations, none of which are new entries to the previous edition.)

Production of biogas from solid organic wastes through anaerobic digestion: a review.

PubMed

Muhammad Nasir, Ismail; Mohd Ghazi, Tinia I; Omar, Rozita

2012-07-01

Anaerobic digestion treatments have often been used for biological stabilization of solid wastes. These treatment processes generate biogas which can be used as a renewable energy sources. Recently, anaerobic digestion of solid wastes has attracted more interest because of current environmental problems, most especially those concerned with global warming. Thus, laboratory-scale research on this area has increased significantly. In this review paper, the summary of the most recent research activities covering production of biogas from solid wastes according to its origin via various anaerobic technologies was presented.

Recycling of waste lead storage battery by vacuum methods.

PubMed

Lin, Deqiang; Qiu, Keqiang

2011-07-01

Waste lead storage battery is the most important recyclable lead material not only in various European and other OECD countries but also in China. Pollution control of lead has become the focus of people's attention in the world. A vacuum process for recycling waste lead storage battery was developed in this work. The experimental results showed that all the valuable materials in waste lead storage battery could be satisfactorily recycled by vacuum technologies. The vacuum melting of lead grids and the vacuum reduction of lead pastes produce the lead bullion with the direct recovery ratio of 96.29% and 98.98%, respectively. The vacuum pyrolysis of plastics can produce pyrolysis oil with yield of more than 93 wt.%. These vacuum recycling technologies offer improvements in metallurgical and environmental performance. Copyright © 2011 Elsevier Ltd. All rights reserved.

Plastic flexible films waste management - A state of art review.

PubMed

Horodytska, O; Valdés, F J; Fullana, A

2018-04-21

Plastic flexible films are increasingly used in many applications due to their lightness and versatility. In 2014, the amount of plastic films represented 34% of total plastic packaging produced in UK. The flexible film waste generation rises according to the increase in number of applications. Currently, in developed countries, about 50% of plastics in domestic waste are films. Moreover, about 615,000 tonnes of agricultural flexible waste are generated in the EU every year. A review of plastic films recycling has been conducted in order to detect the shortcomings and establish guidelines for future research. This paper reviews plastic films waste management technologies from two different sources: post-industrial and post-consumer. Clean and homogeneous post-industrial waste is recycled through closed-loop or open-loop mechanical processes. The main differences between these methods are the quality and the application of the recycled materials. Further research should be focused on closing the loops to obtain the highest environmental benefits of recycling. This could be accomplished through minimizing the material degradation during mechanical processes. Regarding post-consumer waste, flexible films from agricultural and packaging sectors have been assessed. The agricultural films and commercial and industrial flexible packaging are recycled through open-loop mechanical recycling due to existing selective waste collection routes. Nevertheless, the contamination from the use phase adversely affects the quality of recycled plastics. Therefore, upgrading of current washing lines is required. On the other hand, household flexible packaging shows the lowest recycling rates mainly because of inefficient sorting technologies. Delamination and compatibilization methods should be further developed to ensure the recycling of multilayer films. Finally, Life Cycle Assessment (LCA) studies on waste management have been reviewed. A lack of thorough LCA on plastic films waste management systems was identified. Copyright © 2018 Elsevier Ltd. All rights reserved.

40 CFR 412.13 - Effluent limitations attainable by the application of the best available technology economically...

Code of Federal Regulations, 2014 CFR

2014-07-01

... application of the best available technology economically achievable (BAT). 412.13 Section 412.13 Protection... limitations attainable by the application of the best available technology economically achievable (BAT). (a... limitations representing the application of BAT: There shall be no discharge of process waste water pollutants...

40 CFR 412.13 - Effluent limitations attainable by the application of the best available technology economically...

Code of Federal Regulations, 2011 CFR

2011-07-01

... application of the best available technology economically achievable (BAT). 412.13 Section 412.13 Protection... limitations attainable by the application of the best available technology economically achievable (BAT). (a... limitations representing the application of BAT: There shall be no discharge of process waste water pollutants...

40 CFR 412.13 - Effluent limitations attainable by the application of the best available technology economically...

Code of Federal Regulations, 2012 CFR

2012-07-01

... application of the best available technology economically achievable (BAT). 412.13 Section 412.13 Protection... limitations attainable by the application of the best available technology economically achievable (BAT). (a... limitations representing the application of BAT: There shall be no discharge of process waste water pollutants...

40 CFR 412.13 - Effluent limitations attainable by the application of the best available technology economically...

Code of Federal Regulations, 2010 CFR

2010-07-01

... application of the best available technology economically achievable (BAT). 412.13 Section 412.13 Protection... limitations attainable by the application of the best available technology economically achievable (BAT). (a... limitations representing the application of BAT: There shall be no discharge of process waste water pollutants...

40 CFR 412.13 - Effluent limitations attainable by the application of the best available technology economically...

Code of Federal Regulations, 2013 CFR

2013-07-01

... application of the best available technology economically achievable (BAT). 412.13 Section 412.13 Protection... limitations attainable by the application of the best available technology economically achievable (BAT). (a... limitations representing the application of BAT: There shall be no discharge of process waste water pollutants...

Waste-to-Energy biofuel production potential for selected feedstocks in the conterminous United States

DOE Office of Scientific and Technical Information (OSTI.GOV)

Skaggs, Richard L.; Coleman, André M.; Seiple, Timothy E.

Waste-to-Energy (WtE) technologies offer the promise of diverting organic wastes, including wastewater sludge, livestock waste, and food waste, for beneficial energy use while reducing the quantities of waste that are disposed or released to the environment. To ensure economic and environmental viability of WtE feedstocks, it is critical to gain an understanding of the spatial and temporal variability of waste production. Detailed information about waste characteristics, capture/diversion, transport requirements, available conversion technologies, and overall energy conversion efficiency is also required. Building on the development of a comprehensive WtE feedstock database that includes municipal wastewater sludge; animal manure; food processing waste;more » and fats, oils, and grease for the conterminous United States, we conducted a detailed analysis of the wastes’ potential for biofuel production on a site-specific basis. Our analysis indicates that with conversion by hydrothermal liquefaction, these wastes have the potential to produce up to 22.3 GL/y (5.9 Bgal/y) of a biocrude oil intermediate that can be upgraded and refined into a variety of liquid fuels, in particular renewable diesel and aviation kerosene. Conversion to aviation kerosene can potentially meet 23.9% of current U.S. demand.« less

Waste-to-Energy biofuel production potential for selected feedstocks in the conterminous United States

DOE PAGES

Skaggs, Richard L.; Coleman, André M.; Seiple, Timothy E.; ...

2017-10-18

Waste-to-Energy (WtE) technologies offer the promise of diverting organic wastes, including wastewater sludge, livestock waste, and food waste, for beneficial energy use while reducing the quantities of waste that are disposed or released to the environment. To ensure economic and environmental viability of WtE feedstocks, it is critical to gain an understanding of the spatial and temporal variability of waste production. Detailed information about waste characteristics, capture/diversion, transport requirements, available conversion technologies, and overall energy conversion efficiency is also required. Building on the development of a comprehensive WtE feedstock database that includes municipal wastewater sludge; animal manure; food processing waste;more » and fats, oils, and grease for the conterminous United States, we conducted a detailed analysis of the wastes’ potential for biofuel production on a site-specific basis. Our analysis indicates that with conversion by hydrothermal liquefaction, these wastes have the potential to produce up to 22.3 GL/y (5.9 Bgal/y) of a biocrude oil intermediate that can be upgraded and refined into a variety of liquid fuels, in particular renewable diesel and aviation kerosene. Conversion to aviation kerosene can potentially meet 23.9% of current U.S. demand.« less

Proceedings of the 21st DOE/NRC Nuclear Air Cleaning Conference; Sessions 1--8

DOE Office of Scientific and Technical Information (OSTI.GOV)

First, M.W.

1991-02-01

Separate abstracts have been prepared for the papers presented at the meeting on nuclear facility air cleaning technology in the following specific areas of interest: air cleaning technologies for the management and disposal of radioactive wastes; Canadian waste management program; radiological health effects models for nuclear power plant accident consequence analysis; filter testing; US standard codes on nuclear air and gas treatment; European community nuclear codes and standards; chemical processing off-gas cleaning; incineration and vitrification; adsorbents; nuclear codes and standards; mathematical modeling techniques; filter technology; safety; containment system venting; and nuclear air cleaning programs around the world. (MB)

Examples from the Greenland-Project - Gentle Remediation Optiones (GROs) on Pb/zn Contaminated Sites

NASA Astrophysics Data System (ADS)

Friesl-Hanl, Wolfgang; Kidd, Petra; Siebielec, Grzegorz

2017-04-01

The GREENLAND-project brought together "best practice" examples of several field applied gentle remediation techniques (EUFP7-project "Gentle remediation of trace element-contaminated land - GREENLAND; www.greenland-project.eu) with 17 partners from 11 countries. Gentle remediation options (GRO) comprise environmentally friendly technologies that have little or no negative impact on the soil. The main technologies are • phytoextraction • in situ immobilization and • assisted phytostabilization. Mining and processing activities affecting many sites worldwide negatively. The huge amounts of moved and treated materials have led to considerable flows of wastes and emissions. Alongside the many advantages of processed ores to our society, adverse effects in nature and risks for the environment and human health are observed. Three stages of impact of Pb/Zn-ore-treatment on the environment are discussed here: (1) On sites where the ores are mined impacts are the result of crushing, grinding, concentrating activities, and where additionally parts of the installations remain after abandoning the mine, as well as by the massive amounts of remaining deposits or wastes (mine tailings). (2) On sites where smelting and processing takes place, depending on the process (Welz, Doerschel) different waste materials are deposited. The Welz process waste generally contains less Cd and Pb than the Doerschel process waste which additionally shows higher water- extractable metals. (3) On sites close to the emitting source metal contamination can be found in areas for housing, gardening, and agricultural use. Emissions consist mainly from oxides and sulfides (Zn, Cd), sulfates (Zn, Pb, and Cd), chlorides (Pb) and carbonates (Cd). All these wastes and emissions pose potential risks of dispersion of pollutants into the food chain due to erosion (wind, water), leaching and the transfer into feeding stuff and food crops. In-situ treatments have the potential for improving the situation on site and will be shown by means of field experiments in Spain, Poland and Austria. Keywords: Mining and smelting, in-situ remediation, phytomanagement, gentle remediation options

An economic and ecological perspective of ethanol production from renewable agro waste: a review

PubMed Central

2012-01-01

Agro-industrial wastes are generated during the industrial processing of agricultural products. These wastes are generated in large amounts throughout the year, and are the most abundant renewable resources on earth. Due to the large availability and composition rich in compounds that could be used in other processes, there is a great interest on the reuse of these wastes, both from economical and environmental view points. The economic aspect is based on the fact that such wastes may be used as low-cost raw materials for the production of other value-added compounds, with the expectancy of reducing the production costs. The environmental concern is because most of the agro-industrial wastes contain phenolic compounds and/or other compounds of toxic potential; which may cause deterioration of the environment when the waste is discharged to the nature. Although the production of bioethanol offers many benefits, more research is needed in the aspects like feedstock preparation, fermentation technology modification, etc., to make bioethanol more economically viable. PMID:23217124

Global responses for recycling waste CRTs in e-waste.

PubMed

Singh, Narendra; Li, Jinhui; Zeng, Xianlai

2016-11-01

The management of used cathode ray tube (CRT) devices is a major problem worldwide due to rapid uptake of the technology and early obsolescence of CRT devices, which is considered an environment hazard if disposed improperly. Previously, their production has grown in step with computer and television demand but later on with rapid technological innovation; TVs and computer screens has been replaced by new products such as Liquid Crystal Displays (LCDs) and Plasma Display Panel (PDPs). This change creates a large volume of waste stream of obsolete CRTs waste in developed countries and developing countries will be becoming major CRTs waste producers in the upcoming years. We studied that there is also high level of trans-boundary movement of these devices as second-hand electronic equipment into developing countries in an attempt to bridge the 'digital divide'. Moreover, the current global production of e-waste is estimated to be '41million tonnes per year' where a major part of the e-waste stream consists of CRT devices. This review article provides a concise overview of world's current CRTs waste scenario, namely magnitude of the demand and processing, current disposal and recycling operations. Copyright © 2016 Elsevier Ltd. All rights reserved.

POLLUTION PREVENTION TECHNOLOGY DIFFUSION INITIATIVE (TDI)

EPA Science Inventory

Although pollution prevention (P2) technologies save money and help prevent the release of toxic and hazardous wastes into the environment, many companies are reluctant to install new equipment or change the current processes. Some of the reluctance is initiated by lack of time a...

CARBON BLACK DISPERSION PRE-PLATING TECHNOLOGY FOR PRINTED WIRE BOARD MANUFACTURING

EPA Science Inventory

This evaluation addresses the product quality, waste reduction, and economic issues involved in replacing electroless copper with a carbon black dispersion technology. McCurdy Circuits of Orange County, California, currently has both processes in operation. McCurdy has found that...

DEMONSTRATION BULLETIN: SLURRY BIODEGRADATION, International Technology Corporation

EPA Science Inventory

This technology uses a slurry-phase bioreactor in which the soil is mixed with water to form a slurry. Microorganisms and nutrients are added to the slurry to enhance the biodegradation process, which converts organic wastes into relatively harmless byproducts of microbial metabo...

Significant volume reduction of tank waste by selective crystallization: 1994 Annual report

DOE Office of Scientific and Technical Information (OSTI.GOV)

Herting, D.L.; Lunsford, T.R.

1994-09-27

The objective of this technology task plan is to develop and demonstrate a scaleable process of reclaim sodium nitrate (NaNO{sub 3}) from Hanford waste tanks as a clean nonradioactive salt. The purpose of the so-called Clean Salt Process is to reduce the volume of low level waste glass by as much as 70%. During the reporting period of October 1, 1993, through May 31, 1994, progress was made on four fronts -- laboratory studies, surrogate waste compositions, contracting for university research, and flowsheet development and modeling. In the laboratory, experiments with simulated waste were done to explore the effects ofmore » crystallization parameters on the size and crystal habit of product NaNO{sub 3} crystals. Data were obtained to allows prediction of decontamination factor as a function of solid/liquid separation parameters. Experiments with actual waste from tank 101-SY were done to determine the extent of contaminant occlusions in NaNO{sub 3} crystals. In preparation for defining surrogate waste compositions, single shell tanks were categorized according to the weight percent NaNO{sub 3} in each tank. A detailed process flowsheet and computer model were created using the ASPENPlus steady state process simulator. This is the same program being used by the Tank Waste Remediation System (TWRS) program for their waste pretreatment and disposal projections. Therefore, evaluations can be made of the effect of the Clean Salt Process on the low level waste volume and composition resulting from the TWRS baseline flowsheet. Calculations, using the same assumptions as used for the TWRS baseline where applicable indicate that the number of low level glass vaults would be reduced from 44 to 16 if the Clean Salt Process were incorporated into the baseline flowsheet.« less

Development of Technology and Installation for Biohydrogen Production

NASA Astrophysics Data System (ADS)

Pridvizhkin, S. V.; Vyguzova, M. A.; Bazhenov, O. V.

2017-11-01

The article discusses the method for hydrogen production and the device this method application. The relevance of the use of renewable fuels and the positive impact of renewable energy on the environment and the economy is also considered. The presented technology relates to a method for hydrogen production from organic materials subject to anaerobic fermentation, such as the components of solid municipal waste, sewage sludge and agricultural enterprises wastes, sewage waste. The aim of the research is to develop an effective eco-friendly technology for hydrogen producing within an industrial project To achieve the goal, the following issues have been addressed in the course of the study: - development of the process schemes for hydrogen producing from organic materials; - development of the technology for hydrogen producing; - optimization of a biogas plant with the aim of hydrogen producing at one of the fermentation stages; - approbation of the research results. The article is recommended for engineers and innovators working on the renewable energy development issues.

Toward environmentally-benign utilization of nonmetallic fraction of waste printed circuit boards as modifier and precursor.

PubMed

Hadi, Pejman; Ning, Chao; Ouyang, Weiyi; Xu, Meng; Lin, Carol S K; McKay, Gordon

2015-01-01

Electronic waste, including printed circuit boards, is growing at an alarming rate due to the accelerated technological progress and the shorter lifespan of the electronic equipment. In the past decades, due to the lack of proper economic and environmentally-benign recycling technologies, a major fraction of e-waste generated was either destined to landfills or incinerated with the sole intention of its disposal disregarding the toxic nature of this waste. Recently, with the increasing public awareness over their environment and health issues and with the enaction of more stringent regulations, environmentally-benign recycling has been driven to be an alternative option partially replacing the traditional eco-unfriendly disposal methods. One of the most favorable green technologies has been the mechanical separation of the metallic and nonmetallic fraction of the waste printed circuit boards. Although metallic fraction, as the most profitable component, is used to generate the revenue of the separation process, the nonmetallic fraction (NMF) has been left isolated. Herein, the recent developments in the application of NMF have been comprehensively reviewed and an eco-friendly emerging usage of NMF as a value-added material for sustainable remediation has been introduced. Copyright © 2014 Elsevier Ltd. All rights reserved.

Long-term bio-H2 and bio-CH4 production from food waste in a continuous two-stage system: Energy efficiency and conversion pathways.

PubMed

Algapani, Dalal E; Qiao, Wei; di Pumpo, Francesca; Bianchi, David; Wandera, Simon M; Adani, Fabrizio; Dong, Renjie

2018-01-01

Anaerobic digestion is a well-established technology for treating organic waste, but it is still under challenge for food waste due to process stability problems. In this work, continuous H 2 and CH 4 production from canteen food waste (FW) in a two-stage system were successfully established by optimizing process parameters. The optimal hydraulic retention time was 5d for H 2 and 15d for CH 4 . Overall, around 59% of the total COD in FW was converted into H 2 (4%) and into CH 4 (55%). The fluctuations of FW characteristics did not significantly affect process performance. From the energy point view, the H 2 reactor contributed much less than the methane reactor to total energy balance, but it played a key role in maintaining the stability of anaerobic treatment of food waste. Microbial characterization indicated that methane formation was through syntrophic acetate oxidation combined with hydrogenotrophic methanogenesis pathway. Copyright © 2017. Published by Elsevier Ltd.

A model for simulating the grinding and classification cyclic system of waste PCBs recycling production line.

PubMed

Yang, Deming; Xu, Zhenming

2011-09-15

Crushing and separating technology is widely used in waste printed circuit boards (PCBs) recycling process. A set of automatic line without negative impact to environment for recycling waste PCBs was applied in industry scale. Crushed waste PCBs particles grinding and classification cyclic system is the most important part of the automatic production line, and it decides the efficiency of the whole production line. In this paper, a model for computing the process of the system was established, and matrix analysis method was adopted. The result showed that good agreement can be achieved between the simulation model and the actual production line, and the system is anti-jamming. This model possibly provides a basis for the automatic process control of waste PCBs production line. With this model, many engineering problems can be reduced, such as metals and nonmetals insufficient dissociation, particles over-pulverizing, incomplete comminuting, material plugging and equipment fever. Copyright © 2011 Elsevier B.V. All rights reserved.

EM-31 RETRIEVAL KNOWLEDGE CENTER MEETING REPORT: MOBILIZE AND DISLODGE TANK WASTE HEELS

DOE Office of Scientific and Technical Information (OSTI.GOV)

Fellinger, A.

2010-02-16

The Retrieval Knowledge Center sponsored a meeting in June 2009 to review challenges and gaps to retrieval of tank waste heels. The facilitated meeting was held at the Savannah River Research Campus with personnel broadly representing tank waste retrieval knowledge at Hanford, Savannah River, Idaho, and Oak Ridge. This document captures the results of this meeting. In summary, it was agreed that the challenges to retrieval of tank waste heels fell into two broad categories: (1) mechanical heel waste retrieval methodologies and equipment and (2) understanding and manipulating the heel waste (physical, radiological, and chemical characteristics) to support retrieval optionsmore » and subsequent processing. Recent successes and lessons from deployments of the Sand and Salt Mantis vehicles as well as retrieval of C-Area tanks at Hanford were reviewed. Suggestions to address existing retrieval approaches that utilize a limited set of tools and techniques are included in this report. The meeting found that there had been very little effort to improve or integrate the multiple proven or new techniques and tools available into a menu of available methods for rapid insertion into baselines. It is recommended that focused developmental efforts continue in the two areas underway (low-level mixing evaluation and pumping slurries with large solid materials) and that projects to demonstrate new/improved tools be launched to outfit tank farm operators with the needed tools to complete tank heel retrievals effectively and efficiently. This document describes the results of a meeting held on June 3, 2009 at the Savannah River Site in South Carolina to identify technology gaps and potential technology solutions to retrieving high-level waste (HLW) heels from waste tanks within the complex of sites run by the U. S. Department of Energy (DOE). The meeting brought together personnel with extensive tank waste retrieval knowledge from DOE's four major waste sites - Hanford, Savannah River, Idaho, and Oak Ridge. The meeting was arranged by the Retrieval Knowledge Center (RKC), which is a technology development project sponsored by the Office of Technology Innovation & Development - formerly the Office of Engineering and Technology - within the DOE Office of Environmental Management (EM).« less

Evaluation of final waste forms and recommendations for baseline alternatives to group and glass

DOE Office of Scientific and Technical Information (OSTI.GOV)

Bleier, A.

1997-09-01

An assessment of final waste forms was made as part of the Federal Facilities Compliance Agreement/Development, Demonstration, Testing, and Evaluation (FFCA/DDT&E) Program because supplemental waste-form technologies are needed for the hazardous, radioactive, and mixed wastes of concern to the Department of Energy and the problematic wastes on the Oak Ridge Reservation. The principal objective was to identify a primary waste-form candidate as an alternative to grout (cement) and glass. The effort principally comprised a literature search, the goal of which was to establish a knowledge base regarding four areas: (1) the waste-form technologies based on grout and glass, (2) candidatemore » alternatives, (3) the wastes that need to be immobilized, and (4) the technical and regulatory constraints on the waste-from technologies. This report serves, in part, to meet this goal. Six families of materials emerged as relevant; inorganic, organic, vitrified, devitrified, ceramic, and metallic matrices. Multiple members of each family were assessed, emphasizing the materials-oriented factors and accounting for the fact that the two most prevalent types of wastes for the FFCA/DDT&E Program are aqueous liquids and inorganic sludges and solids. Presently, no individual matrix is sufficiently developed to permit its immediate implementation as a baseline alternative. Three thermoplastic materials, sulfur-polymer cement (inorganic), bitumen (organic), and polyethylene (organic), are the most technologically developed candidates. Each warrants further study, emphasizing the engineering and economic factors, but each also has limitations that regulate it to a status of short-term alternative. The crystallinity and flexible processing of sulfur provide sulfur-polymer cement with the highest potential for short-term success via encapsulation. Long-term immobilization demands chemical stabilization, which the thermoplastic matrices do not offer. Among the properties of the remaining candidates, those of glass-ceramics (devitrified matrices) represent the best compromise for meeting the probable stricter disposal requirements in the future.« less

Generation rates and chemical compositions of waste streams in a typical crewed space habitat

NASA Technical Reports Server (NTRS)

Wydeven, Theodore; Golub, Morton A.

1990-01-01

A judicious compilation of generation rates and chemical compositions of potential waste feed streams in a typical crewed space habitat was made in connection with the waste-management aspect of NASA's Physical/Chemical Closed-Loop Life Support Program. Waste composition definitions are needed for the design of waste-processing technologies involved in closing major life support functions in future long-duration human space missions. Tables of data for the constituents and chemical formulas of the following waste streams are presented and discussed: human urine, feces, hygiene (laundry and shower) water, cleansing agents, trash, humidity condensate, dried sweat, and trace contaminants. Tables of data on dust generation and pH values of the different waste streams are also presented and discussed.

Recycling of inorganic waste in monolithic and cellular glass‐based materials for structural and functional applications

PubMed Central

Rincón, Acacio; Marangoni, Mauro; Cetin, Suna

2016-01-01

Abstract The stabilization of inorganic waste of various nature and origin, in glasses, has been a key strategy for environmental protection for the last decades. When properly formulated, glasses may retain many inorganic contaminants permanently, but it must be acknowledged that some criticism remains, mainly concerning costs and energy use. As a consequence, the sustainability of vitrification largely relies on the conversion of waste glasses into new, usable and marketable glass‐based materials, in the form of monolithic and cellular glass‐ceramics. The effective conversion in turn depends on the simultaneous control of both starting materials and manufacturing processes. While silica‐rich waste favours the obtainment of glass, iron‐rich wastes affect the functionalities, influencing the porosity in cellular glass‐based materials as well as catalytic, magnetic, optical and electrical properties. Engineered formulations may lead to important reductions of processing times and temperatures, in the transformation of waste‐derived glasses into glass‐ceramics, or even bring interesting shortcuts. Direct sintering of wastes, combined with recycled glasses, as an example, has been proven as a valid low‐cost alternative for glass‐ceramic manufacturing, for wastes with limited hazardousness. The present paper is aimed at providing an up‐to‐date overview of the correlation between formulations, manufacturing technologies and properties of most recent waste‐derived, glass‐based materials. © 2016 The Authors. Journal of Chemical Technology & Biotechnology published by John Wiley & Sons Ltd on behalf of Society of Chemical Industry. PMID:27818564

Review of technologies for the pretreatment of retrieved single-shell tank waste at Hanford

DOE Office of Scientific and Technical Information (OSTI.GOV)

Gerber, M.A.

1992-08-01

The purpose of the study reported here was to identify and evaluate innovative processes that could be used to pretreat mixed waste retrieved from the 149 single-shell tanks (SSTs) on the US Department of Energy's (DOE) Hanford site. The information was collected as part of the Single Shell Tank Waste Treatment project at Pacific Northwest Laboratory (PNL). The project is being conducted for Westinghouse Hanford Company under their SST Disposal Program.

Review of technologies for the pretreatment of retrieved single-shell tank waste at Hanford

DOE Office of Scientific and Technical Information (OSTI.GOV)

Gerber, M.A.

1992-08-01

The purpose of the study reported here was to identify and evaluate innovative processes that could be used to pretreat mixed waste retrieved from the 149 single-shell tanks (SSTs) on the US Department of Energy`s (DOE) Hanford site. The information was collected as part of the Single Shell Tank Waste Treatment project at Pacific Northwest Laboratory (PNL). The project is being conducted for Westinghouse Hanford Company under their SST Disposal Program.

Preliminary Technology Maturation Plan for Immobilization of High-Level Waste in Glass Ceramics

DOE Office of Scientific and Technical Information (OSTI.GOV)

Vienna, John D.; Crum, Jarrod V.; Sevigny, Gary J.

2012-09-30

A technology maturation plan (TMP) was developed for immobilization of high-level waste (HLW) raffinate in a glass ceramics waste form using a cold-crucible induction melter (CCIM). The TMP was prepared by the following process: 1) define the reference process and boundaries of the technology being matured, 2) evaluate the technology elements and identify the critical technology elements (CTE), 3) identify the technology readiness level (TRL) of each of the CTE’s using the DOE G 413.3-4, 4) describe the development and demonstration activities required to advance the TRLs to 4 and 6 in order, and 5) prepare a preliminary plan tomore » conduct the development and demonstration. Results of the technology readiness assessment identified five CTE’s and found relatively low TRL’s for each of them: • Mixing, sampling, and analysis of waste slurry and melter feed: TRL-1 • Feeding, melting, and pouring: TRL-1 • Glass ceramic formulation: TRL-1 • Canister cooling and crystallization: TRL-1 • Canister decontamination: TRL-4 Although the TRL’s are low for most of these CTE’s (TRL-1), the effort required to advance them to higher values. The activities required to advance the TRL’s are listed below: • Complete this TMP • Perform a preliminary engineering study • Characterize, estimate, and simulate waste to be treated • Laboratory scale glass ceramic testing • Melter and off-gas testing with simulants • Test the mixing, sampling, and analyses • Canister testing • Decontamination system testing • Issue a requirements document • Issue a risk management document • Complete preliminary design • Integrated pilot testing • Issue a waste compliance plan A preliminary schedule and budget were developed to complete these activities as summarized in the following table (assuming 2012 dollars). TRL Budget Year MSA FMP GCF CCC CD Overall $M 2012 1 1 1 1 4 1 0.3 2013 2 2 1 1 4 1 1.3 2014 2 3 1 1 4 1 1.8 2015 2 3 2 2 4 2 2.6 2016 2 3 2 2 4 2 4.9 2017 2 3 3 2 4 2 9.8 2018 3 3 3 3 4 3 7.9 2019 3 3 3 3 4 3 5.1 2020 3 3 3 3 4 3 14.6 2021 3 3 3 3 4 3 7.3 2022 3 3 3 3 4 3 8.8 2023 4 4 4 4 4 4 9.1 2024 5 5 5 5 5 5 6.9 2025 6 6 6 6 6 6 6.9 CCC = canister cooling and crystallization; FMP = feeding, melting, and pouring; GCF = glass ceramic formulation; MSA = mixing, sampling, and analyses. This TMP is intended to guide the development of the glass ceramics waste form and process to the point where it is ready for industrialization.« less

Recent development of recycling lead from scrap CRTs: A technological review.

PubMed

Yu-Gong; Tian, Xiang-Miao; Wu, Yu-Feng; Zhe-Tan; Lei-Lv

2016-11-01

Cathode ray tubes (CRTs) contain numerous harmful substances with different functions. Lead is found in the funnel glass of CRTs. Improperly treated toxic lead may pose significant risks to human health and the environment. This paper reviews and summarizes existing technological processes on the recycling of lead from waste CRTs, including pyrometallurgy, hydrometallurgy, and product-regeneration. The present situation, advantages, and disadvantages of these techniques are described in detail. Generally, pyrometallurgy shows better practicability in recovery lead from waste CRT than hydrometallurgy and hydrometallurgy, in view of environmental impact, energy-consumption, product formats and safety and maturity of technology. Moreover, the gaps in the existing technologies were identified and recommendations for future research were provided. Copyright © 2015 Elsevier Ltd. All rights reserved.

Separations in the STATS report

DOE Office of Scientific and Technical Information (OSTI.GOV)

Choppin, G.R.

1996-12-31

The Separations Technology and Transmutation Systems (STATS) Committee formed a Subcommittee on Separations. This subcommittee was charged with evaluating the separations proposed for the several reactor and accelerator transmutation systems. It was also asked to review the processing options for the safe management of high-level waste generated by the defense programs, in particular, the special problems involved in dealing with the waste at the U.S. Department of Energy (DOE) facility in Hanford, Washington. Based on the evaluations from the Subcommittee on Separations, the STATS Committee concluded that for the reactor transmutation programs, aqueous separations involving a combination of PUREX andmore » TRUEX solvent extraction processes could be used. However, additional research and development (R&D) would be required before full plant-scale use of the TRUEX technology could be employed. Alternate separations technology for the reactor transmutation program involves pyroprocessing. This process would require a significant amount of R&D before its full-scale application can be evaluated.« less

Evaluation of gasification and novel thermal processes for the treatment of municipal solid waste

DOE Office of Scientific and Technical Information (OSTI.GOV)

Niessen, W.R.; Marks, C.H.; Sommerlad, R.E.

1996-08-01

This report identifies seven developers whose gasification technologies can be used to treat the organic constituents of municipal solid waste: Energy Products of Idaho; TPS Termiska Processor AB; Proler International Corporation; Thermoselect Inc.; Battelle; Pedco Incorporated; and ThermoChem, Incorporated. Their processes recover heat directly, produce a fuel product, or produce a feedstock for chemical processes. The technologies are on the brink of commercial availability. This report evaluates, for each technology, several kinds of issues. Technical considerations were material balance, energy balance, plant thermal efficiency, and effect of feedstock contaminants. Environmental considerations were the regulatory context, and such things as composition,more » mass rate, and treatability of pollutants. Business issues were related to likelihood of commercialization. Finally, cost and economic issues such as capital and operating costs, and the refuse-derived fuel preparation and energy c onversion costs, were considered. The final section of the report reviews and summarizes the information gathered during the study.« less

Technological process and optimum design of organic materials vacuum pyrolysis and indium chlorinated separation from waste liquid crystal display panels.

PubMed

Ma, En; Xu, Zhenming

2013-12-15

In this study, a technology process including vacuum pyrolysis and vacuum chlorinated separation was proposed to convert waste liquid crystal display (LCD) panels into useful resources using self-design apparatuses. The suitable pyrolysis temperature and pressure are determined as 300°C and 50 Pa at first. The organic parts of the panels were converted to oil (79.10 wt%) and gas (2.93 wt%). Then the technology of separating indium was optimized by central composite design (CCD) under response surface methodology (RSM). The results indicated the indium recovery ratio was 99.97% when the particle size is less than 0.16 mm, the weight percentage of NH4Cl to glass powder is 50 wt% and temperature is 450°C. The research results show that the organic materials, indium and glass of LCD panel can be recovered during the recovery process efficiently and eco-friendly. Copyright © 2013 Elsevier B.V. All rights reserved.

Physical/chemical closed-loop water-recycling for long-duration missions

NASA Technical Reports Server (NTRS)

Herrmann, Cal C.; Wydeven, Ted

1990-01-01

Water needs, water sources, and means for recycling water are examined in terms appropriate to the water quality requirements of a small crew and spacecraft intended for long duration exploration missions. Inorganic, organic, and biological hazards are estimated for waste water sources. Sensitivities to these hazards for human uses are estimated. The water recycling processes considered are humidity condensation, carbon dioxide reduction, waste oxidation, distillation, reverse osmosis, pervaporation, electrodialysis, ion exchange, carbon sorption, and electrochemical oxidation. Limitations and applications of these processes are evaluated in terms of water quality objectives. Computerized simulation of some of these chemical processes is examined. Recommendations are made for development of new water recycling technology and improvement of existing technology for near term application to life support systems for humans in space. The technological developments are equally applicable to water needs on earth, in regions where extensive water ecycling is needed or where advanced water treatment is essential to meet EPA health standards.

Waste lipids to energy: how to optimize methane production from long‐chain fatty acids (LCFA)

PubMed Central

Alves, M. Madalena; Pereira, M. Alcina; Sousa, Diana Z.; Cavaleiro, Ana J.; Picavet, Merijn; Smidt, Hauke; Stams, Alfons J. M.

2009-01-01

Summary The position of high‐rate anaerobic technology (HR‐AnWT) in the wastewater treatment and bioenergy market can be enhanced if the range of suitable substrates is expanded. Analyzing existing technologies, applications and problems, it is clear that, until now, wastewaters with high lipids content are not effectively treated by HR‐AnWT. Nevertheless, waste lipids are ideal potential substrates for biogas production, since theoretically more methane can be produced, when compared with proteins or carbohydrates. In this minireview, the classical problems of lipids methanization in anaerobic processes are discussed and new concepts to enhance lipids degradation are presented. Reactors operation, feeding strategies and prospects of technological developments for wastewater treatment are discussed. Long‐chain fatty acids (LCFA) degradation is accomplished by syntrophic communities of anaerobic bacteria and methanogenic archaea. For optimal performance these syntrophic communities need to be clustered in compact aggregates, which is often difficult to achieve with wastewaters that contain fats and lipids. Driving the methane production from lipids/LCFA at industrial scale without risk of overloading and inhibition is still a challenge that has the potential for filling a gap in the existing processes and technologies for biological methane production associated to waste and wastewater treatment. PMID:21255287

COSMOS-rice technology abrogates the biotoxic effects of municipal solid waste incinerator residues.

PubMed

Guarienti, Michela; Cardozo, Sdenka Moscoso; Borgese, Laura; Lira, Gloria Rodrigo; Depero, Laura E; Bontempi, Elza; Presta, Marco

2016-07-01

Fly ashes generated by municipal solid waste incinerator (MSWI) are classified as hazardous waste and usually landfilled. For the sustainable reuse of these materials is necessary to reduce the resulting impact on human health and environment. The COSMOS-rice technology has been recently proposed for the treatment of fly ashes mixed with rice husk ash, to obtain a low-cost composite material with significant performances. Here, aquatic biotoxicity assays, including daphnidae and zebrafish embryo-based tests, were used to assess the biosafety efficacy of this technology. Exposure to lixiviated MSWI fly ash caused dose-dependent biotoxic effects on daphnidae and zebrafish embryos with alterations of embryonic development, teratogenous defects and apoptotic events. On the contrary, no biotoxic effects were observed in daphnidae and zebrafish embryos exposed to lixiviated COSMOS-rice material. Accordingly, whole-mount in situ hybridization analysis of the expression of various tissue-specific genes in zebrafish embryos provided genetic evidence about the ability of COSMOS-rice stabilization process to minimize the biotoxic effects of MSWI fly ash. These results demonstrate at the biological level that the newly developed COSMOS-rice technology is an efficient and cost-effective method to process MSWI fly ash, producing a biologically safe and reusable material. Copyright © 2016 Elsevier Ltd. All rights reserved.

New concepts in anaerobic digestion processes: recent advances and biological aspects.

PubMed

Castellano-Hinojosa, Antonio; Armato, Caterina; Pozo, Clementina; González-Martínez, Alejandro; González-López, Jesús

2018-06-01

Waste treatment and the simultaneous production of energy have gained great interest in the world. In the last decades, scientific efforts have focused largely on improving and developing sustainable bioprocess solutions for energy recovery from challenging waste. Anaerobic digestion (AD) has been developed as a low-cost organic waste treatment technology with a simple setup and relatively limited investment and operating costs. Different technologies such as one-stage and two-stage AD have been developed. The viability and performance of these technologies have been extensively reported, showing the supremacy of two-stage AD in terms of overall energy recovery from biomass under different substrates, temperatures, and pH conditions. However, a comprehensive review of the advantages and disadvantages of these technologies is still lacking. Since microbial ecology is critical to developing successful AD, many studies have shown the structure and dynamics of archaeal and bacterial communities in this type of system. However, the role of Eukarya groups remains largely unknown to date. In this review, we provide a comprehensive review of the role, abundance, dynamics, and structure of archaeal, bacterial, and eukaryal communities during the AD process. The information provided could help researchers to select the adequate operational parameters to obtain the best performance and biogas production results.

Precious metal recovery from waste printed circuit boards using cyanide and non-cyanide lixiviants--A review.

PubMed

Akcil, Ata; Erust, Ceren; Gahan, Chandra Sekhar; Ozgun, Mehmet; Sahin, Merve; Tuncuk, Aysenur

2015-11-01

Waste generated by the electrical and electronic devices is huge concern worldwide. With decreasing life cycle of most electronic devices and unavailability of the suitable recycling technologies it is expected to have huge electronic and electrical wastes to be generated in the coming years. The environmental threats caused by the disposal and incineration of electronic waste starting from the atmosphere to the aquatic and terrestrial living system have raised high alerts and concerns on the gases produced (dioxins, furans, polybrominated organic pollutants, and polycyclic aromatic hydrocarbons) by thermal treatments and can cause serious health problems if the flue gas cleaning systems are not developed and implemented. Apart from that there can be also dissolution of heavy metals released to the ground water from the landfill sites. As all these electronic and electrical waste do posses richness in the metal values it would be worth recovering the metal content and protect the environmental from the pollution. Cyanide leaching has been a successful technology worldwide for the recovery of precious metals (especially Au and Ag) from ores/concentrates/waste materials. Nevertheless, cyanide is always preferred over others because of its potential to deliver high recovery with a cheaper cost. Cyanidation process also increases the additional work of effluent treatment prior to disposal. Several non-cyanide leaching processes have been developed considering toxic nature and handling problems of cyanide with non-toxic lixiviants such as thiourea, thiosulphate, aqua regia and iodine. Therefore, several recycling technologies have been developed using cyanide or non-cyanide leaching methods to recover precious and valuable metals. Copyright © 2015 Elsevier Ltd. All rights reserved.

Waste Determination Equivalency - 12172

DOE Office of Scientific and Technical Information (OSTI.GOV)

Freeman, Rebecca D.

2012-07-01

The Savannah River Site (SRS) is a Department of Energy (DOE) facility encompassing approximately 800 square kilometers near Aiken, South Carolina which began operations in the 1950's with the mission to produce nuclear materials. The SRS contains fifty-one tanks (2 stabilized, 49 yet to be closed) distributed between two liquid radioactive waste storage facilities at SRS containing carbon steel underground tanks with storage capacities ranging from 2,800,000 to 4,900,000 liters. Treatment of the liquid waste from these tanks is essential both to closing older tanks and to maintaining space needed to treat the waste that is eventually vitrified or disposedmore » of onsite. Section 3116 of the Ronald W. Reagan National Defense Authorization Act of Fiscal Year 2005 (NDAA) provides the Secretary of Energy, in consultation with the Nuclear Regulatory Commission (NRC), a methodology to determine that certain waste resulting from prior reprocessing of spent nuclear fuel are not high-level radioactive waste if it can be demonstrated that the waste meets the criteria set forth in Section 3116(a) of the NDAA. The Secretary of Energy, in consultation with the NRC, signed a determination in January 2006, pursuant to Section 3116(a) of the NDAA, for salt waste disposal at the SRS Saltstone Disposal Facility. This determination is based, in part, on the Basis for Section 3116 Determination for Salt Waste Disposal at the Savannah River Site and supporting references, a document that describes the planned methods of liquid waste treatment and the resulting waste streams. The document provides descriptions of the proposed methods for processing salt waste, dividing them into 'Interim Salt Processing' and later processing through the Salt Waste Processing Facility (SWPF). Interim Salt Processing is separated into Deliquification, Dissolution, and Adjustment (DDA) and Actinide Removal Process/Caustic Side Solvent Extraction Unit (ARP/MCU). The Waste Determination was signed by the Secretary of Energy in January of 2006 based on proposed processing techniques with the expectation that it could be revised as new processing capabilities became viable. Once signed, however, it became evident that any changes would require lengthy review and another determination signed by the Secretary of Energy. With the maturation of additional salt removal technologies and the extension of the SWPF start-up date, it becomes necessary to define 'equivalency' to the processes laid out in the original determination. For the purposes of SRS, any waste not processed through Interim Salt Processing must be processed through SWPF or an equivalent process, and therefore a clear statement of the requirements for a process to be equivalent to SWPF becomes necessary. (authors)« less

Control technology appendices for pollution control technical manuals. Final report, June 1982-February 1983

DOE Office of Scientific and Technical Information (OSTI.GOV)

Not Available

1983-04-01

The document is one of six technical handbooks prepared by EPA to help government officials granting permits to build synfuels facilities, synfuels process developers, and other interested parties. They provide technical data on waste streams from synfuels facilities and technologies capable of controlling them. Process technologies covered in the manuals include coal gasification, coal liquefaction by direct and idirect processing, and the extraction of oil from shale. The manuals offer no regulatory guidance, allowing the industry flexibility in deciding how best to comply with environmental regulations.

DEMONSTRATION BULLETIN - SOLIDIFICATION/ STABILIZATION PROCESS, SOLIDTECH, INC.

EPA Science Inventory

The Soliditech solidification/stabilization technology mixes hazardous waste materials in soils or sludges with pozzolanic material (cement, fly ash, or kiln dust), a proprietary additive called Urrichem, other proprietary additives, and water. The process is designed to aid ...

Pilot-scale laboratory waste treatment by supercritical water oxidation.

PubMed

Oshima, Yoshito; Hayashi, Rumiko; Yamamoto, Kazuo

2006-01-01

Supercritical water oxidation (SCWO) is a reaction in which organics in an aqueous solution can be oxidized by O2 to CO2 and H2O at a very high reaction rate. In 2003, The University of Tokyo constructed a facility for the SCWO process, the capacity of which is approximately 20 kl/year, for the purpose of treating organic laboratory waste. Through the operation of this facility, we have demonstrated that most of the organics in laboratory waste including halogenated organic compounds can be successfully treated without the formation of dioxines, suggesting that SCWO is useful as an alternative technology to the conventional incineration process.

Test plan: the Czechowice Oil Refinery bioremediation demonstration of a process waste lagoon

DOE Office of Scientific and Technical Information (OSTI.GOV)

Altman, D.J.; Lombard, K.H.; Hazen, T.C.

1997-03-31

The remediation strategies that will be applied at the Czechowice Oil Refinery waste lagoon in Czechowice, Poland are designed, managed, and implemented under the direction of the Westinghouse Savannah River Company (WSRC) for the United States Department of Energy (DOE). WSRC will be assisted in the demonstration by The Institute for Ecology of Industrial Areas (IETU). This collaboration between IETU and DOE will provide the basis for international technology transfer of new and innovative remediation technologies that can be applied in Poland and the Eastern European Region as well.

System decontamination as a tool to control radiation fields

DOE Office of Scientific and Technical Information (OSTI.GOV)

Riess, R.; Bertholdt, H.O.

1995-03-01

Since chemical decontamination of the Reactor Coolant Systems (RCS) and subsystems has the highest potential to reduce radiation fields in a short term this technology has gained an increasing importance. The available decontamination process at Siemens, i.e., the CORD processes, will be described. It is characterized by using permanganic acid for preoxidation and diluted organic acid for the decontamination step. It is a regenerative process resulting in very low waste volumes. This technology has been used frequently in Europe and Japan in both RCS and subsystems. An overview will be given i.e. on the 1993 applications. This overview will includemore » plant, scope, date of performance, system volume specal features of the process removed activities, decon factor time, waste volumes, and personnel dose during decontamination. This overview will be followed by an outlook on future developments in this area.« less

Utilization of waste heat from aluminium electrolytic cell

NASA Astrophysics Data System (ADS)

Nosek, Radovan; Gavlas, Stanislav; Lenhard, Richard; Malcho, Milan; Sedlak, Veroslav; Teie, Sebastian

2017-12-01

During the aluminium production, 50% of the supplied energy is consumed by the chemical process, and 50% of the supplied energy is lost in form of heat. Heat losses are necessary to maintain a frozen side ledge to protect the side walls, so extra heat has to be wasted. In order to increase the energy efficiency of the process, it is necessary to significantly lower the heat losses dissipated by the furnace's external surface. Goodtech Recovery Technology (GRT) has developed a technology based on the use of heat pipes for utilization energy from the waste heat produced in the electrolytic process. Construction of condenser plays important role for efficient operation of energy systems. The condensation part of the heat pipe is situated on top of the heating zone. The thermal oil is used as cooling medium in the condenser. This paper analyses the effect of different operation condition of thermal oil to thermal performance. From the collected results it is obvious that the larger mass flow and higher temperature cause better thermal performance and lower pressure drop.

Liquid fuels from food waste: An alternative process to co-digestion

NASA Astrophysics Data System (ADS)

Sim, Yoke-Leng; Ch'ng, Boon-Juok; Mok, Yau-Cheng; Goh, Sok-Yee; Hilaire, Dickens Saint; Pinnock, Travis; Adams, Shemlyn; Cassis, Islande; Ibrahim, Zainab; Johnson, Camille; Johnson, Chantel; Khatim, Fatima; McCormack, Andrece; Okotiuero, Mary; Owens, Charity; Place, Meoak; Remy, Cristine; Strothers, Joel; Waithe, Shannon; Blaszczak-Boxe, Christopher; Pratt, Lawrence M.

2017-04-01

Waste from uneaten, spoiled, or otherwise unusable food is an untapped source of material for biofuels. A process is described to recover the oil from mixed food waste, together with a solid residue. This process includes grinding the food waste to an aqueous slurry, skimming off the oil, a combined steam treatment of the remaining solids concurrent with extrusion through a porous cylinder to release the remaining oil, a second oil skimming step, and centrifuging the solids to obtain a moist solid cake for fermentation. The water, together with any resulting oil from the centrifuging step, is recycled back to the grinding step, and the cycle is repeated. The efficiency of oil extraction increases with the oil content of the waste, and greater than 90% of the oil was collected from waste containing at least 3% oil based on the wet mass. Fermentation was performed on the solid cake to obtain ethanol, and the dried solid fermentation residue was a nearly odorless material with potential uses of biochar, gasification, or compost production. This technology has the potential to enable large producers of food waste to comply with new laws which require this material to be diverted from landfills.

Bread enriched in lycopene and other bioactive compounds by addition of dry tomato waste.

PubMed

Nour, Violeta; Ionica, Mira Elena; Trandafir, Ion

2015-12-01

The tomato processing industry generates high amounts of waste, mainly tomato skins and seeds, which create environmental problems. These residues are attractive sources of valuable bioactive components and pigments. A relatively simple recovery technology could consist of production of powders to be directly incorporated into foods. Tomato waste coming from a Romanian tomato processing unit were analyzed for the content of several bioactive compounds like ascorbic acid, β-carotene, lycopene, total phenolics, mineral and trace elements. In addition, its antioxidant capacity was assayed. Results revealed that tomato waste (skins and seeds) could be successfully utilized as functional ingredient for the formulation of antioxidant rich functional foods. Dry tomato processing waste were used to supplement wheat flour at 6 and 10 % levels (w/w flour basis) and the effects on the bread's physicochemical, baking and sensorial characteristics were studied. The following changes were observed: increase in moisture content, titratable acidity and bread crumb elasticity, reduction in specific volume and bread crumb porosity. The addition of dry tomato waste at 6 % resulted in bread with good sensory characteristics and overall acceptability but as the amount of dry tomato waste increased to 10 %, bread was less acceptable.

Characterisation of metals in the electronic waste of complex mixtures of end-of-life ICT products for development of cleaner recovery technology.

PubMed

Sun, Z H I; Xiao, Y; Sietsma, J; Agterhuis, H; Visser, G; Yang, Y

2015-01-01

Recycling of valuable metals from electronic waste, especially complex mixtures of end-of-life information and communication technology (ICT) products, is of great difficulty due to their complexity and heterogeneity. One of the important reasons is the lack of comprehensive characterisation on such materials, i.e. accurate compositions, physical/chemical properties. In the present research, we focus on developing methodologies for the characterisation of metals in an industrially processed ICT waste. The morphology, particle size distribution, compositional distribution, occurrence, liberation as well as the thermo-chemical properties of the ICT waste were investigated with various characterisation techniques, including X-ray Fluorescence Spectrometry (XRF), differential scanning calorimetry (DSC) and scanning electron microscopy (SEM) with energy dispersed spectroscopy (EDS). Due to the high heterogeneity of the material, special sample preparation procedures were introduced to minimise the discrepancies during compositional analyses. As a result, a clearer overview of the ICT waste has been reached. This research provides better understanding of the extractability of each metal and improves the awareness of potential obstacles for extraction. It will lead to smarter decisions during further development of a clean and effective recovery process. Copyright © 2014 Elsevier Ltd. All rights reserved.

Recent developments in photocatalytic water treatment technology: a review.

PubMed

Chong, Meng Nan; Jin, Bo; Chow, Christopher W K; Saint, Chris

2010-05-01

In recent years, semiconductor photocatalytic process has shown a great potential as a low-cost, environmental friendly and sustainable treatment technology to align with the "zero" waste scheme in the water/wastewater industry. The ability of this advanced oxidation technology has been widely demonstrated to remove persistent organic compounds and microorganisms in water. At present, the main technical barriers that impede its commercialisation remained on the post-recovery of the catalyst particles after water treatment. This paper reviews the recent R&D progresses of engineered-photocatalysts, photoreactor systems, and the process optimizations and modellings of the photooxidation processes for water treatment. A number of potential and commercial photocatalytic reactor configurations are discussed, in particular the photocatalytic membrane reactors. The effects of key photoreactor operation parameters and water quality on the photo-process performances in terms of the mineralization and disinfection are assessed. For the first time, we describe how to utilize a multi-variables optimization approach to determine the optimum operation parameters so as to enhance process performance and photooxidation efficiency. Both photomineralization and photo-disinfection kinetics and their modellings associated with the photocatalytic water treatment process are detailed. A brief discussion on the life cycle assessment for retrofitting the photocatalytic technology as an alternative waste treatment process is presented. This paper will deliver a scientific and technical overview and useful information to scientists and engineers who work in this field.

Relationship between e-waste recycling and human health risk in India: a critical review.

PubMed

Awasthi, Abhishek Kumar; Zeng, Xianlai; Li, Jinhui

2016-06-01

Informal recycling of waste (including e-waste) is an emerging source of environmental pollution in India. Polychlorinated biphenyls (PCBs), polychlorinated diphenyl ethers (PBDEs), and heavy metals, among other substances, are a major health concern for workers engaged in waste disposal and processing, and for residents living near these facilities, and are also a detriment to the natural environment. The main objective of this review article was to evaluate the status of these impacts. The review found that, huge quantity of e-waste/waste generated, only a small amount is treated formally; the remainder is processed through the informal sector. We also evaluated the exposure pathways, both direct and indirect, and the human body load markers (e.g., serum, blood, breast milk, urine, and hair), and assessed the evidence for the association between these markers and e-waste exposure. Our results indicated that the open dumping and informal e-waste recycling systems should be replaced by the best available technology and environmental practices, with proper monitoring and regular awareness programs for workers and residents. Further and more detailed investigation in this area is also recommended.

Green plants as solar energy converters

DOE Office of Scientific and Technical Information (OSTI.GOV)

Not Available

1976-06-01

A survey covers the potential of energy production from biomass and solid wastes; various processes for the combustion of wastes, such as the co-combustion of solid waste and sewage sludge at the St. Paul/Seneca Treatment Plant Sludge Incinerator; various biological processes for the conversion of solid wastes to fuel such as the Institute of Gas Technology 400 l. digestor for the biogasification of municipal solid waste and sewage solids to a methane-rich product gas; the use of industrial wastes for fuel, such as slash and mill residues used as fuel in lumber mills; the biogasification of animal wastes by usingmore » small-scale on-site digesters to produce methane gas for cooking and lighting; energy farming methods, such as growing giant California kelp, sargassum, and plankton as suitable feedstock for the production of methane, fertilizers, and food; problems, such as the possible alteration of the reflectivity of large areas of the earth's surface by rapidly growing plants raised for biomass; and benefits such as the reduction in air, water, and land pollution associated with the use of wastes and biomass grown especially for energy.« less

Understanding waste for lean health information systems: a preliminary review.

PubMed

Kalong, Nadia Awang; Yusof, Maryati Mohd

2013-01-01

Despite the rapid application of the Lean method in healthcare, its study in IT environments, particularly in Health Information Systems (HIS), is still limited primarily by a lack of waste identification. This paper aims to review the literature to provide an insight into the nature of waste in HIS from the perspective of Lean management. Eight waste frameworks within the context of healthcare and information technology were reviewed. Based on the review, it was found that all the seven waste categories from the manufacturing sector also exist in both the healthcare and IT domains. However, the nature of the waste varied depending on the processes of the domains. A number of additional waste categories were also identified. The findings reveal that the traditional waste model can be adapted to identify waste in both the healthcare and IT sectors.

Trash-to-Gas: Using Waste Products to Minimize Logistical Mass During Long Duration Space Missions

NASA Technical Reports Server (NTRS)

Hintze, Paul E.; Caraccio, A. J.; Anthony, S. M.; Tsoras, A. N.; Devor, Robert; Captain, James G.; Nur, Mononita

2013-01-01

Just as waste-to-energy processes utilizing municipal landftll and biomass wastes are finding increased terrestrial uses, the Trash-to-Gas (TtG) project seeks to convert waste generated during spaceflight into high value commodities. These include methane for propulsion and water for life support in addition to a variety of other gasses. TtG is part of the Logistic Reduction and Repurposing (LRR) project under the NASA Advanced Exploration Systems Program. The LRR project will enable a largely mission-independent approach to minimize logistics contributions to total mission architecture mass. LRR includes technologies that reduce the amount of consumables that need to be sent to space, repurpose items sent to space, or convert wastes to commodities. Currently, waste generated on the International Space Station is stored inside a logistic module which is de-orbited into Earth's atmosphere for destruction. The waste consists of food packaging, food, clothing and other items. This paper will discuss current results on incineration as a waste processing method. Incineration is part of a two step process to produce methane from waste: first the waste is converted to carbon oxides; second, the carbon oxides are fed to a Sabatier reactor where they are converted to methane. The quantities of carbon dioxide, carbon monoxide, methane and water were measured under the different thermal degradation conditions. The overall carbon conversion efficiency and water recovery are discussed

Small hazardous waste generators in developing countries: use of stabilization/solidification process as an economic tool for metal wastewater treatment and appropriate sludge disposal.

PubMed

Silva, Marcos A R; Mater, Luciana; Souza-Sierra, Maria M; Corrêa, Albertina X R; Sperb, Rafael; Radetski, Claudemir M

2007-08-25

The aim of this study was to propose a profitable destination for an industrial sludge that can cover the wastewater treatment costs of small waste generators. Optimized stabilization/solidification technology was used to treat hazardous waste from an electroplating industry that is currently released untreated to the environment. The stabilized/solidified (S/S) waste product was used as a raw material to build concrete blocks, to be sold as pavement blocks or used in roadbeds and/or parking lots. The quality of the blocks containing a mixture of cement, lime, clay and waste was evaluated by means of leaching and solubility tests according to the current Brazilian waste regulations. Results showed very low metal leachability and solubility of the block constituents, indicating a low environmental impact. Concerning economic benefits from the S/S process and reuse of the resultant product, the cost of untreated heavy metal-containing sludge disposal to landfill is usually on the order of US$ 150-200 per tonne of waste, while 1tonne of concrete roadbed blocks (with 25% of S/S waste constitution) has a value of around US$ 100. The results of this work showed that the cement, clay and lime-based process of stabilization/solidification of hazardous waste sludge is sufficiently effective and economically viable to stimulate the treatment of wastewater from small industrial waste generators.

Trash-to-Gas: Using Waste Products to Minimize Logistical Mass During Long Duration Space Missions

NASA Technical Reports Server (NTRS)

Hintze, Paul. E.; Caraccio, Anne J.; Anthony, Stephen M.; Tsoras, Alexandra N.; Nur, Monoita; Devor, Robert; Captain, James G.

2013-01-01

Just as waste-to-energy processes utilizing municipal landftll and biomass wastes are finding increased terrestrial uses, the Trash-to-Gas (TtG) project seeks to convert waste generated during spaceflight into high value commodities. These include methane for propulsion and water for life support in addition to a variety of other gasses. TtG is part of the Logistic Reduction and Repurposing (LRR) project under the NASA Advanced Exploration Systems Program. The LRR project will enable a largely mission-independent approach to minimize logistics contributions to total mission architecture mass. LRR includes technologies that reduce the amount of consumables that need to be sent to space, repurpose items sent to space, or convert wastes to commodities. Currently, waste generated on the International Space Station is stored inside a logistic module which is de-orbited into Earth's atmosphere for destruction. The waste consists of food packaging, food, clothing and other items. This paper will discuss current results on incineration as a waste processing method. Incineration is part of a two step process to produce methane from waste: first the waste is converted to carbon oxides; second, the carbon oxides are fed to a Sabatier reactor where they are converted to methane. The quantities of carbon dioxide, carbon monoxide, methane and water were measured under the different thermal degradation conditions. The overall carbon conversion efficiency and water recovery are discussed.

Unirradiated testing of the demonstration-scale ceramic waste form at ANL-West

DOE Office of Scientific and Technical Information (OSTI.GOV)

Goff, K.M.; Simpson, M.F.; Bateman, K.J.

1997-12-01

The ceramic waste form is being developed by Argonne National Laboratory (ANL) as part of the demonstration of the electrometallurgical treatment of spent nuclear fuel for disposal. The alkali, alkaline earth, halide, and rare earth fission products are stabilized in zeolite, which is combined with glass and processed in a hot isostatic press (HIP) to form a ceramic composite. The transuranics, including plutonium, are also stabilized in this high-level waste. Most of the laboratory-scale development work is performed in the Chemical Technology Division of ANL in Illinois. At ANL-West in Idaho, this technology is being demonstrated on an engineering scalemore » before implementation with irradiated materials in a remote environment.« less

Treatment of metal-laden hazardous wastes with advanced clean coal technology by-products. Quarterly report, December 30, 1996--March 30, 1997

DOE Office of Scientific and Technical Information (OSTI.GOV)

NONE

1997-12-31

The objective of this project is to utilize coal ashes to process hazardous materials such as industrial waste water treatment residues, contaminated soils, and air pollution control dusts from the metal industry and municipal waste incineration. This report describes the activities of the project team during the reporting period. The principal work has focused upon continuing evaluation of aged samples from Phase 1, planning supportive laboratory studies for Phase 2, completing scholarly work, reestablishing MAX Environmental Technologies, Inc., as the subcontractor for the field work of Phase 2, proposing two presentations for later in 1997, and making and responding tomore » several outside contacts.« less

Combined Chemical Activation and Fenton Degradation to Convert Waste Polyethylene into High-Value Fine Chemicals.

PubMed

Chow, Cheuk-Fai; Wong, Wing-Leung; Ho, Keith Yat-Fung; Chan, Chung-Sum; Gong, Cheng-Bin

2016-07-04

Plastic waste is a valuable organic resource. However, proper technologies to recover usable materials from plastic are still very rare. Although the conversion/cracking/degradation of certain plastics into chemicals has drawn much attention, effective and selective cracking of the major waste plastic polyethylene is extremely difficult, with degradation of C-C/C-H bonds identified as the bottleneck. Pyrolysis, for example, is a nonselective degradation method used to crack plastics, but it requires a very high energy input. To solve the current plastic pollution crisis, more effective technologies are needed for converting plastic waste into useful substances that can be fed into the energy cycle or used to produce fine chemicals for industry. In this study, we demonstrate a new and effective chemical approach by using the Fenton reaction to convert polyethylene plastic waste into carboxylic acids under ambient conditions. Understanding the fundamentals of this new chemical process provides a possible protocol to solve global plastic-waste problems. © 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Lifecycle Assessment of Biofuel Production from Wood Pyrolysis Technology

ERIC Educational Resources Information Center

Manyele, S. V.

2007-01-01

Due to a stronger dependency on biomass for energy, there is a need for improved technologies in biomass-to-energy conversion in Tanzania. This paper presents a life cycle assessment (LCA) of pyrolysis technology used for conversion of wood and wood waste to liquid biofuel. In particular, a survey of environmental impacts of the process is…

Biogas: Production and utilization

NASA Astrophysics Data System (ADS)

Price, E. C.; Cheremisinoff, P. N.

Among the aspects of biogas production and utilization covered are: (1) the microbiology and biochemistry of the acid and methane production stages in the anaerobic process; (2) factors affecting the process, such as temperature, acidity and alkalinity, nutrients, and cations; (3) denitrification processes and systems; and (4) the process kinetics of suspended growth systems, packed columns, and fluidized beds. Also considered are such issues in the application of this technology as the digestion of municipal treatment plant sludges, animal wastes, food processing wastes and energy crops. Attention is in addition given to anaerobic digester design, offgas measurement of anaerobic digesters, and sludge treatment through soil conditioning and composting.

Issues that Drive Waste Management Technology Development for Space Missions

NASA Technical Reports Server (NTRS)

Fisher, John W.; Levri, Julie A.; Hogan, John A.; Wignarajah, Kanapathipillai

2005-01-01

Waste management technologies for space life support systems are currently at low development levels. Manual compaction of waste in plastic bags and overboard disposal to earth return vehicles are the primary current waste management methods. Particularly on future missions, continuance of current waste management methods would tend to expose the crew to waste hazards, forfeit recoverable resources such as water, consume valuable crew time, contaminate planetary surfaces, and risk return to Earth of extraterrestrial life. Improvement of waste management capabilities is needed for adequate management of wastes. Improvements include recovery of water and other resources, conversion of waste to states harmless to humans, long-term containment of wastes, and disposal of waste. Current NASA requirements documents on waste management are generally not highly detailed. More detailed requirements are needed to guide the development of waste management technologies that will adequately manage waste. In addition to satisfying requirements, waste management technologies must also recover resources. Recovery of resources such as water and habitat volume can reduce mission cost. This paper explores the drivers for waste management technology development including requirements and resource recovery.

An overview on characterization, utilization and leachate analysis of biomedical waste incinerator ash.

PubMed

Rajor, Anita; Xaxa, Monika; Mehta, Ratika; Kunal

2012-10-15

Solid waste management is one of the major global environmental issues, as there is continuous increase in industrial globalization and generation of waste. Solid wastes encompass the heterogeneous mass of throwaways from the urban community as well as the homogeneous accumulations of agricultural, industrial and mineral wastes. Biomedical waste pose a significant impact on health and environment. A proper waste management system should be required to dispose hazardous biomedical waste and incineration should be the best available technology to reduce the volume of this hazardous waste. The incineration process destroys pathogens and reduces the waste volume and weight but leaves a solid material called biomedical waste ash as residue which increases the levels of heavy metals, inorganic salts and organic compounds in the environment. Disposal of biomedical waste ash in landfill may cause contamination of groundwater as metals are not destroyed during incineration. The limited space and the high cost for land disposal led to the development of recycling technologies and the reuse of ash in different systems. In order to minimize leaching of its hazardous components into the environment several studies confirmed the successful utilization of biomedical waste ash in agriculture and construction sector. This paper presents the overview on the beneficial use of ash in agriculture and construction materials and its leachate characteristics. This review also stressed on the need to further evaluate the leachate studies of the ashes and slag for their proper disposal and utilization. Copyright © 2012 Elsevier Ltd. All rights reserved.

Applied technology for mine waste water decontamination in the uranium ores extraction from Romania

DOE Office of Scientific and Technical Information (OSTI.GOV)

Bejenaru, C.; Filip, G.; Vacariu, V.T.

1996-12-31

The exploitation of uranium ores in Romania is carried out in underground mines. In all exploited uranium deposits, mine waste waters results and will still result after the closure of uranium ore extraction activity. The mine waters are radioactively contaminated with uranium and its decay products being a hazard both for underground waters as for the environment. This paper present the results of research work carried out by authors for uranium elimination from waste waters as the problems involved during the exploitation process of the existent equipment as its maintenance in good experimental conditions. The main waste water characteristics aremore » discussed: solids as suspension, uranium, radium, mineral salts, pH, etc. The moist suitable way to eliminate uranium from mine waste waters is the ion exchange process based on ion exchangers in fluidized bed. A flowsheet is given with main advantages resulted.« less

Solid anaerobic digestion: State-of-art, scientific and technological hurdles.

PubMed

André, Laura; Pauss, André; Ribeiro, Thierry

2018-01-01

In this paper, a state-of-art about solid anaerobic digestion (AD), focused on recent progress and trends of research is proposed. Solid anaerobic digestion should be the most appropriate process for degradation of by-products with high total solid (TS) content, especially lignocellulosic materials like agricultural waste (straw, manure), household waste and food waste. Solid AD is already widely used in waste water treatment plant for treating plant for sewage sludge but could be more developed for lignocellulosic materials with high TS content. Many research works were carried out in Europe on solid AD, focused on current hurdles (BMP, codigestion, inhibition, microbial population, rheology, water transfers, inoculum, etc.) in order to optimize the solid AD process. In conclusion, hurdles of solid AD process should and must be solved in order to propose better productivity and profitability of such system operating with high TS content (>15%), favouring reliable industrial processes. Copyright © 2017 Elsevier Ltd. All rights reserved.

Radiation Stability of Benzyl Tributyl Ammonium Chloride towards Technetium-99 Extraction - 13016

DOE Office of Scientific and Technical Information (OSTI.GOV)

Paviet-Hartmann, Patricia; Horkley, Jared; Campbell, Keri

2013-07-01

A closed nuclear fuel cycle combining new separation technologies along with generation III and generation IV reactors is a promising way to achieve a sustainable energy supply. But it is important to keep in mind that future recycling processes of used nuclear fuel (UNF) must minimize wastes, improve partitioning processes, and integrate waste considerations into processes. New separation processes are being developed worldwide to complement the actual industrialized PUREX process which selectively separates U(VI) and Pu(IV) from the raffinate. As an example, the UREX process has been developed in the United States to co-extract hexavalent uranium (U) and hepta-valent technetiummore » (Tc) by tri-n-butyl phosphate (TBP). Tc-99 is recognized to be one of the most abundant, long-lived radio-toxic isotopes in UNF (half-life, t{sub 1/2} = 2.13 x 10{sup 5} years), and as such, is targeted in UNF separation strategies for isolation and encapsulation in solid waste-forms for final disposal in a nuclear waste repository. Immobilization of Tc-99 by a durable solid waste-form is a challenge, and its fate in new advanced technology processes is of importance. It is essential to be able to quantify and locate 1) its occurrence in any new developed flowsheets, 2) its chemical form in the individual phases of a process, 3) its potential quantitative transfer in any waste streams, and consequently, 4) its quantitative separation for either potential transmutation to Ru-100 or isolation and encapsulation in solid waste-forms for ultimate disposal. In addition, as a result of an U(VI)-Tc(VII) co-extraction in a UREX-based process, Tc(VII) could be found in low level waste (LLW) streams. There is a need for the development of new extraction systems that would selectively extract Tc-99 from LLW streams and concentrate it for feed into high level waste (HLW) for either Tc-99 immobilization in metallic waste-forms (Tc-Zr alloys), and/or borosilicate-based waste glass. Studies have been launched to investigate the suitability of new macro-compounds such as crown-ethers, aza-crown ethers, quaternary ammonium salts, and resorcin-arenes for the selective extraction of Tc-99 from nitric acid solutions. The selectivity of the ligand is important in evaluating potential separation processes and also the radiation stability of the molecule is essential for minimization of waste and radiolysis products. In this paper, we are reporting the extraction of TcO{sub 4}{sup -} by benzyl tributyl ammonium chloride (BTBA). Experimental efforts were focused on determining the best extraction conditions by varying the ligand's matrix conditions and concentration, as well as varying the organic phase composition (i.e. diluent variation). Furthermore, the ligand has been investigated for radiation stability. The ?-irradiation was performed on the neat organic phases containing the ligand at different absorbed doses to a maximum of 200 kGy using an external Co-60 source. Post-irradiation solvent extraction measurements will be discussed. (authors)« less

Study of water recovery and solid waste processing for aerospace and domestic applications. Volume 2: Final report

NASA Technical Reports Server (NTRS)

Guarneri, C. A.; Reed, A.; Renman, R. E.

1972-01-01

The manner in which current and advanced technology can be applied to develop practical solutions to existing and emerging water supply and waste disposal problems is evaluated. An overview of water resource factors as they affect new community planning, and requirements imposed on residential waste treatment systems are presented. The results of equipment surveys contain information describing: commercially available devices and appliances designed to conserve water; devices and techniques for monitoring water quality and controlling back contamination; and advanced water and waste processing equipment. System concepts are developed and compared on the basis of current and projected costs. Economic evaluations are based on community populations of from 2,000 to 250,000. The most promising system concept is defined in sufficient depth to initiate detailed design.

Enzymatic conversion of waste cooking oils into alternative fuel--biodiesel.

PubMed

Chen, Guanyi; Ying, Ming; Li, Weizhun

2006-01-01

Production of biodiesel from pure oils through chemical conversion may not be applicable to waste oils/fats. Therefore, enzymatic conversion using immobilized lipase based on Rhizopus orzyae is considered in this article. This article studies this technological process, focusing on optimization of several process parameters, including the molar ratio of methanol to waste oils, biocatalyst load, and adding method, reaction temperature, and water content. The results indicate that methanol/oils ratio of 4, immobilized lipase/oils of 30 wt% and 40 degrees C are suitable for waste oils under 1 atm. The irreversible inactivation of the lipase is presumed and a stepwise addition of methanol to reduce inactivation of immobilized lipases is proposed. Under the optimum conditions the yield of methyl esters is around 88-90%.

New Engineering Solutions in Creation of Mini-BOF for Metallic Waste Recycling

NASA Astrophysics Data System (ADS)

Eronko, S. P.; Gorbatyuk, S. M.; Oshovskaya, E. V.; Starodubtsev, B. I.

2017-12-01

New engineering solutions used in design of the mini melting unit capable of recycling industrial and domestic metallic waste with high content of harmful impurities are provided. High efficiency of the process technology implemented with its use is achieved due to the possibility of the heat and mass transfer intensification in the molten metal bath, controlled charge into it of large amounts of reagents in lumps and in fines, and cut-off of remaining process slag during metal tapping into the teeming ladle.

Requirements Development Issues for Advanced Life Support Systems: Solid Waste Management

NASA Technical Reports Server (NTRS)

Levri, Julie A.; Fisher, John W.; Alazraki, Michael P.; Hogan, John A.

2002-01-01

Long duration missions pose substantial new challenges for solid waste management in Advanced Life Support (ALS) systems. These possibly include storing large volumes of waste material in a safe manner, rendering wastes stable or sterilized for extended periods of time, and/or processing wastes for recovery of vital resources. This is further complicated because future missions remain ill-defined with respect to waste stream quantity, composition and generation schedule. Without definitive knowledge of this information, development of requirements is hampered. Additionally, even if waste streams were well characterized, other operational and processing needs require clarification (e.g. resource recovery requirements, planetary protection constraints). Therefore, the development of solid waste management (SWM) subsystem requirements for long duration space missions is an inherently uncertain, complex and iterative process. The intent of this paper is to address some of the difficulties in writing requirements for missions that are not completely defined. This paper discusses an approach and motivation for ALS SWM requirements development, the characteristics of effective requirements, and the presence of those characteristics in requirements that are developed for uncertain missions. Associated drivers for life support system technological capability are also presented. A general means of requirements forecasting is discussed, including successive modification of requirements and the need to consider requirements integration among subsystems.

APPLICATION, PERFORMANCE, AND COSTS OF ...

EPA Pesticide Factsheets

A critical review of biological treatment processes for remediation of contaminated soils is presented. The focus of the review is on documented cost and performance of biological treatment technologies demonstrated at full- or field-scale. Some of the data were generated by the U.S. Environmental Protection Agency's (EPA's) Bioremediation in the Field Program, jointly supported by EPA's Office of Research and Development, EPA's Office of Solid Waste and Emergency Waste, and the EPA Regions through the Superfund Innovative Technology Evaluation Program (SITE) Program. Military sites proved to be another fertile data source. Technologies reviewed in this report include both ex-situ processes, (land treatment, biopile/biocell treatment, composting, and bioslurry reactor treatment) and in-situ alternatives (conventional bioventing, enhanced or cometabolic bioventing, anaerobic bioventing, bioslurping, phytoremediation, and natural attenuation). Targeted soil contaminants at the documented sites were primarily organic chemicals, including BTEX, petroleum hydrocarbons, polycyclic aromatic hydrocarbons (PAHs), chlorinated aliphatic hydrocarbons (CAHs), organic solvents, polychlorinated biphenyls (PCBs), pesticides, dioxin, and energetics. The advantages, limitations, and major cost drivers for each technology are discussed. Box and whisker plots are used to summarize before and after concentrations of important contaminant groups for those technologies consider

Iron Phosphate Glass-Containing Hanford Waste Simulant

DOE Office of Scientific and Technical Information (OSTI.GOV)

Sevigny, Gary J.; Kimura, Marcia L.; Fischer, Christopher M.

2012-01-18

Resolution of the nation's high-level tank waste legacy requires the design, construction, and operation of large and technically complex one-of-a-kind processing waste treatment and vitrification facilities. While the ultimate limits for waste loading and melter efficiency have yet to be defined or realized, significant reductions in glass volumes for disposal and mission life may be possible with advancements in melter technologies and/or glass formulations. This test report describes the experimental results from a small-scale test using the research-scale melter (RSM) at Pacific Northwest National Laboratory (PNNL) to demonstrate the viability of iron-phosphate-based glass with a selected waste composition that ismore » high in sulfate (4.37 wt% SO3). The primary objective of the test was to develop data to support a cost-benefit analysis related to the implementation of phosphate-based glasses for Hanford low-activity waste (LAW) and/or other high-level waste streams within the U.S. Department of Energy complex. The testing was performed by PNNL and supported by Idaho National Laboratory, Savannah River National Laboratory, Missouri University of Science and Technology, and Mo-Sci Corporation.« less

Suitable technological conditions for enzymatic hydrolysis of waste paper by Novozymes® enzymes NS50013 and NS50010.

PubMed

Brummer, Vladimir; Skryja, Pavel; Jurena, Tomas; Hlavacek, Viliam; Stehlik, Petr

2014-10-01

Waste paper belongs to a group of quantitatively the most produced waste types. Enzymatic hydrolysis is becoming a suitable way to treat this type of waste and at the same time, to produce a valuable liquid biofuel, because reducing sugars solutions that are formed during the process of saccharification can be a precursor for following or simultaneous fermentation. If it will be possible to make the enzymatic hydrolysis of the waste paper economically viable, it could serve as one of the new ways to lower the dependence of the transport sector on oil in the future. Only several studies comparing the enzymatic hydrolysis of different waste papers were performed in the past; they are summarized in this manuscript. In our experimental trials, suitable technological conditions for waste paper enzymatic hydrolysis using enzymes from Novozymes® biomass kit: enzymes NS50013 and NS50010 were investigated. The following enzymatic hydrolysis parameters in laboratory scale trials were verified on high cellulose content substrates-filter paper and cellulose pulp: type of buffer, pH, temperature, concentration of the substrate, loading of the enzyme and rate of stirring.

Demonstration of Combined Food and Landscape Waste Composting at Fort Leonard Wood, MO: Fort Leonard Wood Installation Strategic Sustainable Plan

DTIC Science & Technology

2016-01-01

Availability of on-site food waste-processing technologies suitable for small- to medium- sized generators is often desirable; several manufactur - ers...waste digestors varies according to manufacturer , but typically range from 0.5 to 2 cu yd/day. Food pulpers operate somewhat similarly to food ...and food courts. Based on an analysis of the volumes, potential for cross- contamination , and ease of collection, it was agreed that the primary

Industrial bioconversion of renewable resources as an alternative to conventional chemistry.

PubMed

Willke, Th; Vorlop, K-D

2004-12-01

There are numerous possibilities for replacing chemical techniques with biotechnological methods based on renewable resources. The potential of biotechnology (products, technologies, metabolic pathways) is for the most part well known. Often the costs are still the problem. Biotechnological advances have the best chances for replacing some fine chemicals. While the raw material costs are less of a consideration here, the environmental benefit is huge, as chemical-technical processes often produce a wide range of undesirable/harmful by-products or waste. In the case of bulk chemicals (<1 US dollar/kg) the product price is affected mainly by raw material costs. As long as fossil raw materials are still relatively inexpensive, alternatives based on renewable resources cannot establish themselves. Residues and waste, which are available even at no cost in some cases, are an exception. The introduction of new technologies for the efficient use of such raw materials is currently being promoted. The utilisation of residual wood, plant parts, waste fat, and crude glycerol, for example, provides great potential. For industrial chemicals (2-4 US dollars/kg), process and recovery costs play a greater role. Here, innovative production technologies and product recovery techniques (e.g. on-line product separation) can increase competitiveness.

Performance Qualification Test of the ISS Water Processor Assembly (WPA) Expendables

NASA Technical Reports Server (NTRS)

Carter, Layne; Tabb, David; Tatara, James D.; Mason, Richard K.

2005-01-01

The Water Processor Assembly (WPA) for use on the International Space Station (ISS) includes various technologies for the treatment of waste water. These technologies include filtration, ion exchange, adsorption, catalytic oxidation, and iodination. The WPA hardware implementing portions of these technologies, including the Particulate Filter, Multifiltration Bed, Ion Exchange Bed, and Microbial Check Valve, was recently qualified for chemical performance at the Marshall Space Flight Center. Waste water representing the quality of that produced on the ISS was generated by test subjects and processed by the WPA. Water quality analysis and instrumentation data was acquired throughout the test to monitor hardware performance. This paper documents operation of the test and the assessment of the hardware performance.

The Global Rise of Zero Liquid Discharge for Wastewater Management: Drivers, Technologies, and Future Directions.

PubMed

Tong, Tiezheng; Elimelech, Menachem

2016-07-05

Zero liquid discharge (ZLD)-a wastewater management strategy that eliminates liquid waste and maximizes water usage efficiency - has attracted renewed interest worldwide in recent years. Although implementation of ZLD reduces water pollution and augments water supply, the technology is constrained by high cost and intensive energy consumption. In this critical review, we discuss the drivers, incentives, technologies, and environmental impacts of ZLD. Within this framework, the global applications of ZLD in the United States and emerging economies such as China and India are examined. We highlight the evolution of ZLD from thermal- to membrane-based processes, and analyze the advantages and limitations of existing and emerging ZLD technologies. The potential environmental impacts of ZLD, notably greenhouse gas emission and generation of solid waste, are discussed and the prospects of ZLD technologies and research needs are highlighted.

Assessment of application of selected waste for production of biogas

NASA Astrophysics Data System (ADS)

Pawlita-Posmyk, Monika; Wzorek, Małgorzata

2017-10-01

Recently, the idea of biogas production has become a popular topic in Poland. Biogas is a valuable source of renewable energy with a potential application in electricity and heat production. Numerous types of technological solutions of biogas production are closely linked to the availability of substrates in the area, as well as their quantity and their properties. The paper presents the assessment of application in biogas production selected wastes such as communal and household sewage sludge and waste from a paper production in Opole region (Poland). The annual productions of methane, biogas and electricity were estimated. Chosen physico-chemical properties important in fermentation process were taken into consideration in the assessment. The highest value of potential energy was obtained using waste from the paper industry but the most appropriate parameters for this process has sewage sludge from the municipal sewage treatment plant. The use of sewage sludge from domestic and municipal sewage and waste from the paper industry creates the opportunity to reduce the amount of waste materials.

Updated Liquid Secondary Waste Grout Formulation and Preliminary Waste Form Qualification

DOE Office of Scientific and Technical Information (OSTI.GOV)

Saslow, Sarah A.; Um, Wooyong; Russell, Renee L.

This report describes the results from liquid secondary waste grout (LSWG) formulation and cementitious waste form qualification tests performed by Pacific Northwest National Laboratory (PNNL) for Washington River Protection Solutions, LLC (WRPS). New formulations for preparing a cementitious waste form from a high-sulfate liquid secondary waste stream simulant, developed for Effluent Management Facility (EMF) process condensates merged with low activity waste (LAW) caustic scrubber, and the release of key constituents (e.g. 99Tc and 129I) from these monoliths were evaluated. This work supports a technology development program to address the technology needs for Hanford Site Effluent Treatment Facility (ETF) liquid secondarymore » waste (LSW) solidification and supports future Direct Feed Low-Activity Waste (DFLAW) operations. High-priority activities included simulant development, LSWG formulation, and waste form qualification. The work contained within this report relates to waste form development and testing and does not directly support the 2017 integrated disposal facility (IDF) performance assessment (PA). However, this work contains valuable information for use in PA maintenance past FY17, and for future waste form development efforts. The provided data should be used by (i) cementitious waste form scientists to further understanding of cementitious dissolution behavior, (ii) IDF PA modelers who use quantified constituent leachability, effective diffusivity, and partitioning coefficients to advance PA modeling efforts, and (iii) the U.S. Department of Energy (DOE) contractors and decision makers as they assess the IDF PA program. The results obtained help fill existing data gaps, support final selection of a LSWG waste form, and improve the technical defensibility of long-term waste form performance estimates.« less

Investigation of bioaerosols released from swine farms using conventional and alternative waste treatment and management technologies

USGS Publications Warehouse

Ko, G.; Simmons, O. D.; Likirdopulos, C.A.; Worley-Davis, L.; Williams, M.; Sobsey, M.D.

2008-01-01

Microbial air pollution from concentrated animal feeding operations (CAFOs) has raised concerns about potential public health and environmental impacts. We investigated the levels of bioaerosols released from two swine farms using conventional lagoon-sprayfield technology and ten farms using alternative waste treatment and management technologies in the United States. In total, 424 microbial air samples taken at the 12 CAFOs were analyzed for several indicator and pathogenic microorganisms, including culturable bacteria and fungi, fecal coliform, Escherichia coli, Clostridium perfringens, bacteriophage, and Salmonella. At all of the investigated farms, bacterial concentrations at the downwind boundary were higher than those at the upwind boundary, suggesting that the farms are sources of microbial air contamination. In addition, fecal indicator microorganisms were found more frequently near barns and treatment technology sites than upwind or downwind of the farms. Approximately 4.5% (19/424), 1.2% (5/424), 22.2% (94/424), and 12.3% (53/424) of samples were positive for fecal coliform, E. coli, Clostridium, and total coliphage, respectively. Based on statistical comparison of airborne fecal indicator concentrations at alternative treatment technology farms compared to control farms with conventional technology, three alternative waste treatment technologies appear to perform better at reducing the airborne release of fecal indicator microorganisms during on-farm treatment and management processes. These results demonstrate that airborne microbial contaminants are released from swine farms and pose possible exposure risks to farm workers and nearby neighbors. However, the release of airborne microorganisms appears to decrease significantly through the use of certain alternative waste management and treatment technologies. ?? 2008 American Chemical Society.

Thermal Pretreatment For TRU Waste Sorting

DOE Office of Scientific and Technical Information (OSTI.GOV)

Sasaki, T.; Aoyama, Y.; Miyamoto, Y.

2008-07-01

Japan Atomic Energy Agency conducted a study on thermal treatment of TRU waste to develop a removal technology for materials that are forbidden for disposal. The thermal pretreatment in which hot nitrogen and/or air is introduced to the waste is a process of removing combustibles, liquids, and low melting point metals from PVC wrapped TRU waste. In this study, thermal pretreatment of simulated waste was conducted using a desktop thermal treatment vessel and a laboratory scale thermal pretreatment system. Combustibles and low melting point metals are effectively separated from wastes by choosing appropriate temperature of flowing gases. Combustibles such asmore » papers, PVC, oil, etc. were removed and low melting point metals such as zinc, lead, and aluminum were separated from the simulated waste by the thermal pretreatment. (authors)« less

Acid Tar Lagoons: Management and Recovery

NASA Astrophysics Data System (ADS)

Bohers, Anna; Hroncová, Emília; Ladomerský, Juraj

2017-04-01

This contribution presents the issue with possibility of definitive removal of dangerous environmental burden in Slovakia - serious historical problem of two acid tar lagoons. In relation to their removal, no technology has been found so far - technologically and economically suitable, what caused problems with its management. Locality Predajná is well known in Slovakia by its character of contrasts: it is situated in the picturesque landscape of National Park buffer zone of Nízke Tatry, on the other site it is contaminated by 229 211m3 of acid tar with its characteristics of toxicity, carcinogenicity, teratogenicity, mutagenicity and toxicity especially for animals and plants. Acid tar in two landfills with depth of 1m in case of the first lagoon and 9,5m in case of the second lagoon is a waste product derived from operation of Petrochema Dubová - refinery and petrochemical plant whose activity was to process the crude oil through processes of sulfonation and adsorption technology for producing lubricating and special oils, synthetic detergents and special white oils for cosmetic and medical purposes. A part of acid tar was incinerated in two incineration plats. Concentration of SO2 in combustion gases was too high and it was not possible to decrease it under the value of 2000 mg.mn-3 [LADOMERSKÝ, J. - SAMEŠOVÁ, D.: Reduction in sulfur dioxide emissions waste gases of incineration plant. Acta facultatis ecologiae. 1999, p. 217-223]. That is why it was necessary to put them out of operation. Later, because of public opposition it was not possible to build a new incineration plat corresponding to the state of the art. Even though actual Slovak and European legislative for protection of environment against such impacts, neither of tried methods - bio or non-biologic treatment methods - was proved as suitable for processing or for recovery in the reason of different factors admission: i.e. strong aggressivity, difficulty with handling because of its sludgy and liquid state et sim. Because of lack of geological research caused by fragile limestone bedrock under the lagoon in combination with aggressive substance in the lagoon, waste management of this contaminated site became even more complicated. The main aim of this work is to present by analysis a new possibility of acid tarry-waste management thanks to the technique of thermal desorption as a method for acid tar processing, through which it is possible to gain only organic part; and a technology of Blowing Decomposition as a method for its consequent recovery. Thermal desorption process is an effective separation process through which is possible to split acid tarry material into matrix (soil, sediments) and organic contaminants (PCB and POPs compounds). The process is carried out through a mobile unit which is relocatable. The work also presents a relation between volume of de-contaminated matrix and organic compounds. In order to boost the efficiency in processing of acid tar waste through thermal desorption, the work will present possibility of application of innovative technology - method of Blowing Decomposition for recovering of organic matter into technological lubricating oil.

Plasma methods for metals recovery from metal-containing waste.

PubMed

Changming, Du; Chao, Shang; Gong, Xiangjie; Ting, Wang; Xiange, Wei

2018-04-27

Metal-containing waste, a kind of new wastes, has a great potential for recycling and is also difficult to deal with. Many countries pay more and more attention to develop the metal recovery process and equipment of this kind of waste as raw material, so as to solve the environmental pollution and comprehensively utilize the discarded metal resources. Plasma processing is an efficient and environmentally friendly way for metal-containing waste. This review mainly discuss various metal-containing waste types, such as printed circuit boards (PCBs), red mud, galvanic sludge, Zircon, aluminium dross and incinerated ash, and the corresponding plasma methods, which include DC extended transferred arc plasma reactor, DC non-transferred arc plasma torch, RF thermal plasma reactor and argon and argon-hydrogen plasma jets. In addition, the plasma arc melting technology has a better purification effect on the extraction of useful metals from metal-containing wastes, a great capacity of volume reduction of waste materials, and a low leaching toxicity of solid slag, which can also be used to deal with all kinds of metal waste materials, having a wide range of applications. Copyright © 2018 Elsevier Ltd. All rights reserved.

Occupational health hazards related to informal recycling of E-waste in India: An overview.

PubMed

Annamalai, Jayapradha

2015-01-01

The innovation in science and technology coupled with the change in lifestyle of an individual has made an incredible change in the electronic industry show casing an assorted range of new products every day to the world. India too has been impacted by this digital revolution where consumption of electronics goods grows at a rapid rate producing a large amount of waste electrical and electronic equipment. This substantial generation of electronic waste referred to as e-waste accompanied with the lack of stringent environmental laws and regulations for handling the hazardous e-waste has resulted in the cropping of number of informal sectors. Over 95% of the e-waste is treated and processed in the majority of urban slums of the country, where untrained workers carry out the dangerous procedures without personal protective equipment, which are detrimental not only to their health but also to the environment. This paper focuses on the occupational health hazards due to the informal recycling of e-waste and then proceeds to show the safe disposal methods for handling the large quantities of e-waste generated in this electronic era and thus finds a sustainable solution for the formal processing of e-waste.

Occupational health hazards related to informal recycling of E-waste in India: An overview

PubMed Central

Annamalai, Jayapradha

2015-01-01

The innovation in science and technology coupled with the change in lifestyle of an individual has made an incredible change in the electronic industry show casing an assorted range of new products every day to the world. India too has been impacted by this digital revolution where consumption of electronics goods grows at a rapid rate producing a large amount of waste electrical and electronic equipment. This substantial generation of electronic waste referred to as e-waste accompanied with the lack of stringent environmental laws and regulations for handling the hazardous e-waste has resulted in the cropping of number of informal sectors. Over 95% of the e-waste is treated and processed in the majority of urban slums of the country, where untrained workers carry out the dangerous procedures without personal protective equipment, which are detrimental not only to their health but also to the environment. This paper focuses on the occupational health hazards due to the informal recycling of e-waste and then proceeds to show the safe disposal methods for handling the large quantities of e-waste generated in this electronic era and thus finds a sustainable solution for the formal processing of e-waste. PMID:26023273

Towards zero waste: a case study in the City of Tshwane.

PubMed

Snyman, Jacques; Vorster, Kobus

2011-05-01

Tshwane is presently landfilling all of its municipal solid waste (MSW) with no pre-processing or minimization efforts. This is a result of the available capacity of its existing landfills, thought to be able to satisfy the city's needs for, at most, the next 10 years. It is possible that the authorities will not wake up to the problem before it is too late. This study addresses these challenges. This study first identified and evaluated technologies available in developed countries for processing the various components of the MSW stream, appropriate to local conditions, as an alternative to landfilling, to ensure that these components will be either reused, recycled or rendered harmless to the environment before disposal. Then most appropriate technologies for Tshwane were selected and assembled into an optimal configuration to achieve a zero waste situation in Tshwane within a decade or two. This represents a significant change in MSW management in Tshwane, from total landfill to zero waste to landfill. Although the study focused on Tshwane, it can be argued that the findings can be implemented in any other South African municipality, and even implemented in other emerging countries.

Development studies for a novel wet oxidation process. Phase 2

DOE Office of Scientific and Technical Information (OSTI.GOV)

NONE

1994-07-01

DETOX{sup SM} is a catalyzed wet oxidation process which destroys organic materials in an acidic water solution of iron at 373 to 473 K. The solution can be used repeatedly to destroy great amounts of organic materials. Since the process is conducted in a contained vessel, air emissions from the process can be well controlled. The solution is also capable of dissolving and concentrating many heavy and radioactive metals for eventual stabilization and disposal. The Phase 2 effort for this project is site selection and engineering design for a DETOX demonstration unit. Site selection was made using a set ofmore » site selection criteria and evaluation factors. A survey of mixed wastes at DOE sites was conducted using the Interim Mixed Waste Inventory Report. Sites with likely suitable waste types were identified. Potential demonstration sites were ranked based on waste types, interest, regulatory needs, scheduling, ability to provide support, and available facilities. Engineering design for the demonstration unit is in progress and is being performed by Jacobs Applied Technology. The engineering design proceeded through preliminary process flow diagrams (PFDs), calculation of mass and energy balances for representative waste types, process and instrumentation diagrams (P and IDs), preparation of component specifications, and a firm cost estimate for fabrication of the demonstration unit.« less

[Methodological approaches to the development of environmentally benign technology for the use of solid waste in iron metallurgy].

PubMed

Pugin, K G; Vaĭsman, Ia I

2013-01-01

On the basis of the life cycle of materials, containing wastes of iron and steel industry, new methodological approaches to the assessment of technologies of the secondary use of wastes are developed A complex criteria for selection of the technology for the use of resource potential of solid waste of iron and steel industry are developed with taking into account environmental, technological and economic indices. The technology of the use of wastes of ferrovanadium industry as bulk solid materials at the solid waste landfill is shown.

Thermal plasma technology for the treatment of wastes: a critical review.

PubMed

Gomez, E; Rani, D Amutha; Cheeseman, C R; Deegan, D; Wise, M; Boccaccini, A R

2009-01-30

This review describes the current status of waste treatment using thermal plasma technology. A comprehensive analysis of the available scientific and technical literature on waste plasma treatment is presented, including the treatment of a variety of hazardous wastes, such as residues from municipal solid waste incineration, slag and dust from steel production, asbestos-containing wastes, health care wastes and organic liquid wastes. The principles of thermal plasma generation and the technologies available are outlined, together with potential applications for plasma vitrified products. There have been continued advances in the application of plasma technology for waste treatment, and this is now a viable alternative to other potential treatment/disposal options. Regulatory, economic and socio-political drivers are promoting adoption of advanced thermal conversion techniques such as thermal plasma technology and these are expected to become increasingly commercially viable in the future.

Institutionalizing Emerging Technology Assessment Process into National Incident Response

DTIC Science & Technology

2013-10-01

mechanical methods, devices, and products, including oil sensors, booms, skimmers, decontamination , and waste minimization technologies...handling). • Alternative Oil Spill Response Technologies (in situ burning , dispersants, etc.). • Oil Spill Damage Assessment and Restoration. The TETs...deaths of eleven crewmembers and a subsequent uncontrolled oil spill that tested the government’s ability to respond to a spill of this magnitude as

Additional Equipment for Soil Biodegradation

NASA Astrophysics Data System (ADS)

Vondráčková, Terezie; Kraus, Michal; Šál, Jiří

2017-12-01

Intensification of industrial production, increasing citizens’ living standards, expanding the consumer assortment mean in the production - consumption cycle a constantly increasing occurrence of waste material, which by its very nature must be considered as a source of useful raw materials in all branches of human activity. In addition to strict legislative requirements, a number of circumstances characterize waste management. It is mainly extensive transport associated with the handling and storage of large volumes of substances with a large assortment of materials (substances of all possible physical and chemical properties) and high demands on reliability and time coordination of follow-up processes. Considerable differences in transport distances, a large number of sources, processors and customers, and not least seasonal fluctuations in waste and strong price pressures cannot be overlooked. This highlights the importance of logistics in waste management. Soils that are contaminated with oil and petroleum products are hazardous industrial waste. Methods of industrial waste disposal are landfilling, biological processes, thermal processes and physical and chemical methods. The paper focuses on the possibilities of degradation of oil pollution, in particular biodegradation by bacteria, which is relatively low-cost among technologies. It is necessary to win the fight with time so that no ground water is contaminated. We have developed two additional devices to help reduce oil accident of smaller ranges. In the case of such an oil accident, it is necessary to carry out the permeability test of contaminated soil in time and, on this basis, to choose the technology appropriate to the accident - either in-sit biodegradation - at the site of the accident, or on-sit - to remove the soil and biodegrade it on the designated deposits. A special injection drill was developed for in-sit biodegradation, tossing and aeration equipment of the extracted soil was developed for on-sit biodegradation.

Human Support Technology Research to Enable Exploration

NASA Technical Reports Server (NTRS)

Joshi, Jitendra

2003-01-01

Contents include the following: Advanced life support. System integration, modeling, and analysis. Progressive capabilities. Water processing. Air revitalization systems. Why advanced CO2 removal technology? Solid waste resource recovery systems: lyophilization. ISRU technologies for Mars life support. Atmospheric resources of Mars. N2 consumable/make-up for Mars life. Integrated test beds. Monitoring and controlling the environment. Ground-based commercial technology. Optimizing size vs capability. Water recovery systems. Flight verification topics.

Hazardous and toxic waste management in Botswana: practices and challenges.

PubMed

Mmereki, Daniel; Li, Baizhan; Meng, Liu

2014-12-01

Hazardous and toxic waste is a complex waste category because of its inherent chemical and physical characteristics. It demands for environmentally sound technologies and know-how as well as clean technologies that simultaneously manage and dispose it in an environmentally friendly way. Nevertheless, Botswana lacks a system covering all the critical steps from importation to final disposal or processing of hazardous and toxic waste owing to limited follow-up of the sources and types of hazardous and toxic waste, lack of modern and specialised treatment/disposal facilities, technical know-how, technically skilled manpower, funds and capabilities of local institutions to take lead in waste management. Therefore, because of a lack of an integrated system, there are challenges such as lack of cooperation among all the stakeholders about the safe management of hazardous and toxic waste. Furthermore, Botswana does not have a systematic regulatory framework regarding monitoring and hazardous and toxic waste management. In addition to the absence of a systematic regulatory framework, inadequate public awareness and dissemination of information about hazardous and toxic waste management, slower progress to phase-out persistent and bio-accumulative waste, and lack of reliable and accurate information on hazardous and toxic waste generation, sources and composition have caused critical challenges to effective hazardous and toxic waste management. It is, therefore, important to examine the status of hazardous and toxic waste as a waste stream in Botswana. By default; this mini-review article presents an overview of the current status of hazardous and toxic waste management and introduces the main challenges in hazardous and toxic waste management. Moreover, the article proposes the best applicable strategies to achieve effective hazardous and toxic waste management in the future. © The Author(s) 2014.

Reducing environmental damage through the use of unmanned aerial vehicles as the best available technology

NASA Astrophysics Data System (ADS)

Fedulova, E. A.; Akulov, A. O.; Rada, A. O.; Alabina, T. A.; Savina, Ju Ju

2018-01-01

The article examines the possibilities of using unmanned aerial vehicles as the best available technologies in the field of agriculture and mining. The object of the study is the use of unmanned aerial vehicles as the best available technology. The main areas of application of this technology are identified: agro technical operations, aerial photography of mining operations. The technology of unmanned aerial vehicles is compared with the technologies of ground agricultural machinery. The research methodology includes an expert evaluation of the unmanned aerial vehicle technology belonging to the class of the best available technologies by the criteria: the level of environmental impact, resource saving, the use of low-waste, non-waste processes, the existence of at least two objects, economic efficiency. Expert evaluations were processed using the apparatus of fuzzy sets, which make it possible to construct membership functions. This allowed us to prove that the technology of unmanned aerial vehicles belongs to a fuzzy set of the best available technologies. The results of the research show that the use of unmanned aerial vehicles provides a saving of resources, especially non-renewable combustible minerals, reduces emissions and discharges of pollutants into the atmosphere, and also reduces soil erosion. Unmanned aerial vehicles should be included in the national directories of the best available technologies for the mining industry and agriculture.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Moghissi, A.A.; Blauvelt, R.K.; Benda, G.A.

This volume contains the peer-reviewed and edited versions of papers submitted for presentation a the Second International Mixed Waste Symposium. Following the tradition of the First International Mixed Waste Symposium, these proceedings were prepared in advance of the meeting for distribution to participants. The symposium was organized by the Mixed Waste Committee of the American Society of Mechanical Engineers. The topics discussed at the symposium include: stabilization technologies, alternative treatment technologies, regulatory issues, vitrification technologies, characterization of wastes, thermal technologies, laboratory and analytical issues, waste storage and disposal, organic treatment technologies, waste minimization, packaging and transportation, treatment of mercury contaminatedmore » wastes and bioprocessing, and environmental restoration. Individual abstracts are catalogued separately for the data base.« less

Synthesis and Performance Evaluation of a New Deoiling Agent for Treatment of Waste Oil-Based Drilling Fluids

PubMed Central

Liu, Pingting; Huang, Zhiyu; Deng, Hao; Wang, Rongsha; Xie, Shuixiang

2014-01-01

Oil-based drilling fluid is used more and more in the field of oil and gas exploration. However, because of unrecyclable treating agent and hard treatment conditions, the traditional treating technologies of waste oil-based drilling fluid have some defects, such as waste of resource, bulky equipment, complex treatment processes, and low oil recovery rate. In this work, switchable deoiling agent (SDA), as a novel surfactant for treatment of waste oil-based drilling fluid, was synthesized by amine, formic acid, and formaldehyde solution. With this agent, the waste oil-based drilling fluid can be treated without complex process and expensive equipment. Furthermore, the agent used in the treatment can be recycled, which reduces waste of resource and energy. The switch performance, deoiling performance, structural characterization, and mechanisms of action are studied. The experimental results show that the oil content of the recycled oil is higher than 96% and more than 93% oil in waste oil-based drilling fluid can be recycled. The oil content of the solid residues of deoiling is less than 3%. PMID:25045749

Synthesis and performance evaluation of a new deoiling agent for treatment of waste oil-based drilling fluids.

PubMed

Liu, Pingting; Huang, Zhiyu; Deng, Hao; Wang, Rongsha; Xie, Shuixiang

2014-01-01

Oil-based drilling fluid is used more and more in the field of oil and gas exploration. However, because of unrecyclable treating agent and hard treatment conditions, the traditional treating technologies of waste oil-based drilling fluid have some defects, such as waste of resource, bulky equipment, complex treatment processes, and low oil recovery rate. In this work, switchable deoiling agent (SDA), as a novel surfactant for treatment of waste oil-based drilling fluid, was synthesized by amine, formic acid, and formaldehyde solution. With this agent, the waste oil-based drilling fluid can be treated without complex process and expensive equipment. Furthermore, the agent used in the treatment can be recycled, which reduces waste of resource and energy. The switch performance, deoiling performance, structural characterization, and mechanisms of action are studied. The experimental results show that the oil content of the recycled oil is higher than 96% and more than 93% oil in waste oil-based drilling fluid can be recycled. The oil content of the solid residues of deoiling is less than 3%.

Technical area status report for waste destruction and stabilization

DOE Office of Scientific and Technical Information (OSTI.GOV)

Dalton, J.D.; Harris, T.L.; DeWitt, L.M.

1993-08-01

The Office of Environmental Restoration and Waste Management (EM) was established by the Department of Energy (DOE) to direct and coordinate waste management and site remediation programs/activities throughout the DOE complex. In order to successfully achieve the goal of properly managing waste and the cleanup of the DOE sites, the EM was divided into five organizations: the Office of Planning and Resource Management (EM-10); the Office of Environmental Quality Assurance and Resource Management (EM-20); the Office of Waste Operations (EM-30); the Office of Environmental Restoration (EM-40); and the Office of Technology and Development (EM-50). The mission of the Office ofmore » Technology Development (OTD) is to develop treatment technologies for DOE`s operational and environmental restoration wastes where current treatment technologies are inadequate or not available. The Mixed Waste Integrated Program (MWIP) was created by OTD to assist in the development of treatment technologies for the DOE mixed low-level wastes (MLLW). The MWIP has established five Technical Support Groups (TSGs) whose purpose is to identify, evaluate, and develop treatment technologies within five general technical areas representing waste treatment functions from initial waste handling through generation of final waste forms. These TSGs are: (1) Front-End Waste Handling, (2) Physical/Chemical Treatment, (3) Waste Destruction and Stabilization, (4) Second-Stage Destruction and Offgas Treatment, and (5) Final Waste Forms. This report describes the functions of the Waste Destruction and Stabilization (WDS) group. Specifically, the following items are discussed: DOE waste stream identification; summary of previous efforts; summary of WDS treatment technologies; currently funded WDS activities; and recommendations for future activities.« less

Implementation of an evaporative oxidation process for treatment of aqueous mixed wastes

DOE Office of Scientific and Technical Information (OSTI.GOV)

Bounini, L.; Stelmach, J.

1995-12-31

The US Department of Energy and Rust Geotech conducted treatability tests for mixed wastes with a pilot-scale evaporative oxidation unit known as the mini-PO*WW*ER unit. In the evaporative oxidation process, water and volatile organic compounds are vaporized and passed through a catalytic oxidizer to destroy the organic compounds. Nonvolatiles are concentrated into a brine that may be solidified. Ten experiment runs were made. The oxidation of the unit was calculated using total organic carbon analyses of feed and composite product condensate samples. These data indicate that the technology is capable of achieving oxidation efficiencies as high as 99.999 percent onmore » mixed wastes when the bed temperature is near 600 C, residence times are about 0.2 seconds, and adequate oxygen flow is maintained. Concentrations of the tested volatile organic compounds in the product-condensate composite samples were well below standards for wastewaters. Combined gross alpha and beta radioactivity levels in the samples were below detection limites of 12.5 pico-Cu/l, so the liquid would not qualify as a radioactive waste. Thus, the product condensate process by the process is not restricted as either hazardous or mixed waste and is suitable for direct disposal. The brines produced were not considered mixed waste and could be handled and disposed of as radioactive waste.« less

SUBGRADE MONOLITHIC ENCASEMENT STABILIZATION OF CATEGORY 3 LOW LEVEL WASTE (LLW)

DOE Office of Scientific and Technical Information (OSTI.GOV)

PHILLIPS, S.J.

2004-02-03

A highly efficient and effective technology has been developed and is being used for stabilization of Hazard Category 3 low-level waste at the U.S. Department of Energy's Hanford Site. Using large, structurally interconnected monoliths, which form one large monolith that fills a waste disposal trench, the patented technology can be used for final internment of almost any hazardous, radioactive, or toxic waste or combinations of these waste materials packaged in a variety of sizes, shapes, and volumes within governmental regulatory limits. The technology increases waste volumetric loading by 100 percent, area use efficiency by 200 percent, and volumetric configuration efficiencymore » by more than 500 percent over past practices. To date, in excess of 2,010 m{sup 3} of contact-handled and remote-handled low-level radioactive waste have been interned using this patented technology. Additionally, in excess of 120 m{sup 3} of low-level radioactive waste requiring stabilization in low-diffusion coefficient waste encasement matrix has been disposed using this technology. Greater than five orders of magnitude in radiation exposure reduction have been noted using this method of encasement of Hazard Category 3 waste. Additionally, exposure monitored at all monolith locations produced by the slip form technology is less than 1.29 x E-07 C {center_dot} kg{sup -1}. Monolithic encasement of Hazard Category 3 low-level waste and other waste category materials may be successfully accomplished using this technology at nominally any governmental or private sector waste disposal facility. Additionally, other waste materials consisting of hazardous, radioactive, toxic, or mixed waste materials can be disposed of using the monolithic slip form encasement technology.« less

POTENTIAL IMPACT OF BLENDING RESIDUAL SOLIDS FROM TANKS 18/19 MOUNDS WITH TANK 7 OPERATIONS

DOE Office of Scientific and Technical Information (OSTI.GOV)

Eibling, R; Erich Hansen, E; Bradley Pickenheim, B

2007-03-29

High level waste tanks 18F and 19F have residual mounds of waste which may require removal before the tanks can be closed. Conventional slurry pump technology, previously used for waste removal and tank cleaning, has been incapable of removing theses mounds from tanks 18F and 19F. A mechanical cleaning method has been identified that is potentially capable of removing and transferring the mound material to tank 7F for incorporation in a sludge batch for eventual disposal in high level waste glass by the Defense Waste Processing Facility. The Savannah River National Laboratory has been requested to evaluate whether the materialmore » transferred from tanks 18F/19F by the mechanical cleaning technology can later be suspended in Tank 7F by conventional slurry pumps after mixing with high level waste sludge. The proposed mechanical cleaning process for removing the waste mounds from tanks 18 and 19 may utilize a high pressure water jet-eductor that creates a vacuum to mobilize solids. The high pressure jet is also used to transport the suspended solids. The jet-eductor system will be mounted on a mechanical crawler for movement around the bottom of tanks 18 and 19. Based on physical chemical property testing of the jet-eductor system processed IE-95 zeolite and size-reduced IE-95 zeolite, the following conclusions were made: (1) The jet-eductor system processed zeolite has a mean and median particle size (volume basis) of 115.4 and 43.3 microns in water. Preferential settling of these large particles is likely. (2) The jet-eductor system processed zeolite rapidly generates settled solid yield stresses in excess of 11,000 Pascals in caustic supernates and will not be easily retrieved from Tank 7 with the existing slurry pump technology. (3) Settled size-reduced IE-95 zeolite (less than 38 microns) in caustic supernate does not generate yield stresses in excess of 600 Pascals in less than 30 days. (4) Preferential settling of size-reduced zeolite is a function of the amount of sludge and the level of dilution for the mixture. (5) Blending the size-reduced zeolite into larger quantities of sludge can reduce the amount of preferential settling. (6) Periodic dilution or resuspension due to sludge washing or other mixing requirements will increase the chances of preferential settling of the zeolite solids. (7) Mixtures of Purex sludge and size-reduced zeolite did not produce yield stresses greater than 200 Pascals for settling times less than thirty days. Most of the sludge-zeolite blends did not exceed 50 Pascals. These mixtures should be removable by current pump technology if sufficient velocities can be obtained. (8) The settling rate of the sludge-zeolite mixtures is a function of the ionic strength (or supernate density) and the zeolite- sludge mixing ratio. (9) Simulant tests indicate that leaching of Si may be an issue for the processed Tank 19 mound material. (10) Floating zeolite fines observed in water for the jet-eductor system and size-reduced zeolite were not observed when the size-reduced zeolite was blended with caustic solutions, indicating that the caustic solutions cause the fines to agglomerate. Based on the test programs described in this report, the potential for successfully removing Tank 18/19 mound material from Tank 7 with the current slurry pump technology requires the reduction of the particle size of the Tank 18/19 mound material.« less

Incinerator technology overview

NASA Astrophysics Data System (ADS)

Santoleri, Joseph J.

1993-03-01

Many of the major chemical companies in the U.S. who regarded a safe environment as their responsibility installed waste treatment and disposal facilities on their plant sites in the last two decades. Many of these plants elected to use incinerators as the treatment process. This was not always the most economical method, but in many cases it was the only method of disposal that provided a safe and sure method of maximum destruction. Environmental concern over contamination from uncontrolled land disposal sites, and the emergence of tougher regulations for land disposal provide incentives for industry to employ a wide variety of traditional and advanced technologies for managing hazardous wastes. Incineration systems utilizing proper design, operation, and maintenance provides the safest, and in the long run, the most economical avenue to the maximum level of destruction of organic hazardous wastes.

Human Factor Investigation of Waste Processing System During the HI-SEAS 4 Month Mars Analog Mission in Support of NASA's Logistic Reduction and Repurposing Project: Trash to Gas

NASA Technical Reports Server (NTRS)

Caraccio, Anne; Hintze, Paul; Miles, John D.

2014-01-01

NASAs Logistics Reduction and Repurposing (LRR) project is a collaborative effort in which NASA is tasked with reducing total logistical mass through reduction, reuse and recycling of various wastes and components of long duration space missions and habitats. Trash to Gas (TtG) is a sub task to LRR with efforts focused on development of a technology that converts wastes generated during long duration space missions into high-value products such as methane, water for life support, raw material production feedstocks, and other energy sources. The reuse of discarded materials is a critical component to reducing overall mission mass. The 120 day Hawaii Space Exploration and Analog Simulation provides a unique opportunity to answer questions regarding crew interface and system analysis for designing and developing future flight-like versions of a TtG system. This paper will discuss the human factors that would affect the design of a TtG or other waste processing systems. An overview of the habitat, utility usage, and waste storage and generation is given. Crew time spent preparing trash for TtG processing was recorded. Gas concentrations were measured near the waste storage locations and at other locations in the habitat. In parallel with the analog mission, experimental processing of waste materials in a TtG reactor was performed in order to evaluate performance with realistic waste materials.

Human Factor Investigation of Waste Processing System During the HI-SEAS 4-month Mars Analog Mission in Support of NASA's Logistic Reduction and Repurposing Project: Trash to Gas

NASA Technical Reports Server (NTRS)

Caraccio, Anne; Hintze, Paul E.; Miles, John D.

2014-01-01

NASA's Logistics Reduction and Repurposing (LRR) project is a collaborative effort in which NASA is tasked with reducing total logistical mass through reduction, reuse and recycling of various wastes and components of long duration space missions and habitats. Trash to Gas (TtG) is a sub task to LRR with efforts focused on development of a technology that converts wastes generated during long duration space missions into high-value products such as methane, water for life support, raw material production feedstocks, and other energy sources. The reuse of discarded materials is a critical component to reducing overall mission mass. The 120 day Hawaii Space Exploration and Analog Simulation provides a unique opportunity to answer questions regarding crew interface and system analysis for designing and developing future flight-like versions of a TtG system. This paper will discuss the human factors that would affect the design of a TtG or other waste processing systems. An overview of the habitat, utility usage, and waste storage and generation is given. Crew time spent preparing trash for TtG processing was recorded. Gas concentrations were measured near the waste storage locations and at other locations in the habitat. In parallel with the analog mission, experimental processing of waste materials in a TtG reactor was performed in order to evaluate performance with realistic waste materials.

Engineering development and demonstration of DETOX{sup SM} wet oxidation for mixed waste treatment

DOE Office of Scientific and Technical Information (OSTI.GOV)

Dhooge, P.M.; Goldblatt, S.D.; Moslander, J.E.

1997-12-01

DETOX{sup SM}, a catalyzed chemical oxidation process, is under development for treatment of hazardous and mixed wastes at Department of Energy sites. To support this effort, developmental engineering studies have been formed for aspects of the process to help ensure safe and effective operation. Subscale agitation studies have been preformed to identify a suitable mixing head and speed for the primary reaction vessel agitator. Mechanisms for feeding solid waste materials to the primary reaction vessel have been investigated. Filtration to remove solid field process residue, and the use of various filtration aids, has been studied. Extended compatibility studies on themore » materials of construction have been performed. Due to a change to Rocky Flats Environmental Technology Site (RFETS) for the mixed waste portion of the demonstration, types of wastes suitable and appropriate for treatment at RFETS had to be chosen. A Prototype unit has been fabricated and will be demonstrated on hazardous and mixed wastes at Savannah River Site (SRS) and RFETS during 1997 and 1998. The unit is in shakedown testing at present. Data validation and an engineering evaluation will be performed during the demonstration.« less

An alternative method for the treatment of waste produced at a dye and a metal-plating industry using natural and/or waste materials.

PubMed

Fatta, Despo; Papadopoulos, Achilleas; Stefanakis, Nikos; Loizidou, Maria; Savvides, Chrysanthos

2004-08-01

The aim of this study was to develop cost-effective, appropriate solidification technologies for treating hazardous industrial wastes that are currently disposed of in ways that may threaten the quality of local groundwater. One major objective was to use materials other than cement, and preferably materials that are themselves wastes, as the solidification additives, namely using wastes to treat wastes or locally available natural material. This research examines the cement-based and lime-based stabilization/solidification (S/S) techniques applied for waste generated at a metal-plating industry and a dye industry. For the lime-based S/S process the following binder mixtures were used: cement kiln dust/ lime, bentonite/lime and gypsum/lime. For the cement-based S/S process three binder mixtures were used: cement kiln dust/cement, bentonite/cement and gypsum/cement. The leachability of the wastes was evaluated using the toxicity characteristic leaching procedure. The applicability and optimum weight ratio of the binder mixtures were estimated using the unconfined compressive strength test. The optimum ratio mixtures were mixed with waste samples in different ratios and cured for 28 days in order to find the S/S products with the highest strength and lowest leachability at the same time. The results of this work showed that the cement-and lime-based S/S process, using cement kiln dust and bentonite as additives can be effectively used in order to treat industrial waste.

Hydrothermal carbonization of animal manures: Processes and energetics

USDA-ARS?s Scientific Manuscript database

Hydrothermal carbonization (HTC) is an emerging technology for thermochemically converting biomass and waste materials into value-added carbonaceous char called hydrochar. HTC is well suited to manage wet feedstocks streams because pre-drying prior to processing is not required as with gasification...

Field Evaluations Test Plan for Validation of Alternative Low-Emission Surface Preparation/Depainting Technologies for Structural Steel

NASA Technical Reports Server (NTRS)

Lewis, Pattie

2005-01-01

Headquarters National Aeronautics and Space Administration (NASA) chartered the Acquisition Pollution Prevention (AP2) Office to coordinate agency activities affecting pollution prevention issues identified during system and component acquisition and sustainment processes. The primary objectives of the AP2 Office are to: (1) Reduce or eliminate the use of hazardous materials (HazMats) or hazardous processes at manufacturing, remanufacturing, and sustainment locations. (2) Avoid duplication of effort in actions required to reduce or eliminate HazMats through joint center cooperation and technology sharing. To achieve a substrate condition suitable for the application of a coating system, both new and old (in-situ) substrates must undergo some type of surface preparation and/or depainting operation to ensure adhesion of the new coating system. The level of cleanliness or anchor profile desired is typically a function of the type of coating to be applied and the specification being adhered to. In high performance environments, cleanliness and surface profile requirements for carbon steel (the dominant substrate for facilities, structures and equipment) dictates the use of abrasive media. Many of the abrasive media currently used across NASA and Air Force Space Command (AFSPC) installations generate large quantities of fugitive particulate emissions and waste. The high quantities of airborne dust and waste generated from these operations pose significant environmental concern. Efforts to contain emissions and the reduce quantity of waste generated have significant implications on project cost; this is often a deterrent to engaging in maintenance activities. In response to recent technological developments and NASA's and AFSPC's need to undertake environmentally conscious corrosion prevention projects, a review of the industry needs to be undertaken to evaluate surface preparation technologies (materials and processes) for embrace. This project will identify, evaluate and approve alternative surface preparation technologies for use at NASA and AFSPC installations. Materials and processes will be evaluated with the goal of selecting those processes that will improve corrosion protection at critical systems, facilitate easier maintenance activity, extend maintenance cycles, eliminate flight hardware contamination and reduce the amount of hazardous waste generated. This Field Evaluations Test Plan defines the field evaluation and testing requirements for validating alternative surface preparation/depainting technologies and supplements the JTP. The field evaluations will be performed at Stennis Space Center, Mississippi, under the oversight of the Project Engineer. Additional field evaluations may be performed at other NASA centers or AFSPC facilities.

Reprint of: Pyrolysis technologies for municipal solid waste: a review.

PubMed

Chen, Dezhen; Yin, Lijie; Wang, Huan; He, Pinjing

2015-03-01

Pyrolysis has been examined as an attractive alternative to incineration for municipal solid waste (MSW) disposal that allows energy and resource recovery; however, it has seldom been applied independently with the output of pyrolysis products as end products. This review addresses the state-of-the-art of MSW pyrolysis in regards to its technologies and reactors, products and environmental impacts. In this review, first, the influence of important operating parameters such as final temperature, heating rate (HR) and residence time in the reaction zone on the pyrolysis behaviours and products is reviewed; then the pyrolysis technologies and reactors adopted in literatures and scale-up plants are evaluated. Third, the yields and main properties of the pyrolytic products from individual MSW components, refuse-derived fuel (RDF) made from MSW, and MSW are summarised. In the fourth section, in addition to emissions from pyrolysis processes, such as HCl, SO2 and NH3, contaminants in the products, including PCDD/F and heavy metals, are also reviewed, and available measures for improving the environmental impacts of pyrolysis are surveyed. It can be concluded that the single pyrolysis process is an effective waste-to-energy convertor but is not a guaranteed clean solution for MSW disposal. Based on this information, the prospects of applying pyrolysis technologies to dealing with MSW are evaluated and suggested. Copyright © 2015 Elsevier Ltd. All rights reserved.

Production of High-Value Nanoparticles via Biogenic Processes Using Aquacultural and Horticultural Food Waste

PubMed Central

Ghosh, Purabi R.; Fawcett, Derek; Sharma, Shashi B.; Poinern, Gerrard E. J.

2017-01-01

The quantities of organic waste produced globally by aquacultural and horticulture are extremely large and offer an attractive renewable source of biomolecules and bioactive compounds. The availability of such large and diverse sources of waste materials creates a unique opportunity to develop new recycling and food waste utilisation strategies. The aim of this review is to report the current status of research in the emerging field of producing high-value nanoparticles from food waste. Eco-friendly biogenic processes are quite rapid, and are usually carried out at normal room temperature and pressure. These alternative clean technologies do not rely on the use of the toxic chemicals and solvents commonly associated with traditional nanoparticle manufacturing processes. The relatively small number of research articles in the field have been surveyed and evaluated. Among the diversity of waste types, promising candidates and their ability to produce various high-value nanoparticles are discussed. Experimental parameters, nanoparticle characteristics and potential applications for nanoparticles in pharmaceuticals and biomedical applications are discussed. In spite of the advantages, there are a number of challenges, including nanoparticle reproducibility and understanding the formation mechanisms between different food waste products. Thus, there is considerable scope and opportunity for further research in this emerging field. PMID:28773212

Processing real-world waste plastics by pyrolysis-reforming for hydrogen and high-value carbon nanotubes.

PubMed

Wu, Chunfei; Nahil, Mohamad A; Miskolczi, Norbert; Huang, Jun; Williams, Paul T

2014-01-01

Producing both hydrogen and high-value carbon nanotubes (CNTs) derived from waste plastics is reported here using a pyrolysis-reforming technology comprising a two-stage reaction system, in the presence of steam and a Ni-Mn-Al catalyst. The waste plastics consisted of plastics from a motor oil container (MOC), commercial waste high density polyethylene (HDPE) and regranulated HDPE waste containing polyvinyl chloride (PVC). The results show that hydrogen can be produced from the pyrolysis-reforming process, but also carbon nanotubes are formed on the catalyst. However, the content of 0.3 wt.% polyvinyl chloride in the waste HDPE (HDPE/PVC) has been shown to poison the catalyst and significantly reduce the quantity and purity of CNTs. The presence of sulfur has shown less influence on the production of CNTs in terms of quantity and CNT morphologies. Around 94.4 mmol H2 g(-1) plastic was obtained for the pyrolysis-reforming of HDPE waste in the presence of the Ni-Mn-Al catalyst and steam at a reforming temperature of 800 °C. The addition of steam in the process results in an increase of hydrogen production and reduction of carbon yield; in addition, the defects of CNTs, for example, edge dislocations were found to be increased with the introduction of steam (from Raman analysis).

Development of space technology for ecological habitats

NASA Technical Reports Server (NTRS)

Martello, N. V.

1986-01-01

The development of closed ecological systems for space stations is discussed. Growth chambers, control systems, microgravity, ecosystem stability, lighting equipment, and waste processing systems are among the topics discussed.

Limited Bacterial Diversity within a Treatment Plant Receiving Antibiotic-Containing Waste from Bulk Drug Production.

PubMed

Marathe, Nachiket P; Shetty, Sudarshan A; Shouche, Yogesh S; Larsson, D G Joakim

2016-01-01

Biological treatment of waste water from bulk drug production, contaminated with high levels of fluoroquinolone antibiotics, can lead to massive enrichment of antibiotic resistant bacteria, resistance genes and associated mobile elements, as previously shown. Such strong selection may be boosted by the use of activated sludge (AS) technology, where microbes that are able to thrive on the chemicals within the wastewater are reintroduced at an earlier stage of the process to further enhance degradation of incoming chemicals. The microbial community structure within such a treatment plant is, however, largely unclear. In this study, Illumina-based 16S rRNA amplicon sequencing was applied to investigate the bacterial communities of different stages from an Indian treatment plant operated by Patancheru Environment Technology Limited (PETL) in Hyderabad, India. The plant receives waste water with high levels of fluoroquinolones and applies AS technology. A total of 1,019,400 sequences from samples of different stages of the treatment process were analyzed. In total 202, 303, 732, 652, 947 and 864 operational taxonomic units (OTUs) were obtained at 3% distance cutoff in the equilibrator, aeration tanks 1 and 2, settling tank, secondary sludge and old sludge samples from PETL, respectively. Proteobacteria was the most dominant phyla in all samples with Gammaproteobacteria and Betaproteobacteria being the dominant classes. Alcaligenaceae and Pseudomonadaceae, bacterial families from PETL previously reported to be highly multidrug resistant, were the dominant families in aeration tank samples. Despite regular addition of human sewage (approximately 20%) to uphold microbial activity, the bacterial diversity within aeration tanks from PETL was considerably lower than corresponding samples from seven, regular municipal waste water treatment plants. The strong selection pressure from antibiotics present may be one important factor in structuring the microbial community in PETL, which may affect not only resistance promotion but also general efficiency of the waste treatment process.

Limited Bacterial Diversity within a Treatment Plant Receiving Antibiotic-Containing Waste from Bulk Drug Production

PubMed Central

Shouche, Yogesh S.; Larsson, D. G. Joakim

2016-01-01

Biological treatment of waste water from bulk drug production, contaminated with high levels of fluoroquinolone antibiotics, can lead to massive enrichment of antibiotic resistant bacteria, resistance genes and associated mobile elements, as previously shown. Such strong selection may be boosted by the use of activated sludge (AS) technology, where microbes that are able to thrive on the chemicals within the wastewater are reintroduced at an earlier stage of the process to further enhance degradation of incoming chemicals. The microbial community structure within such a treatment plant is, however, largely unclear. In this study, Illumina-based 16S rRNA amplicon sequencing was applied to investigate the bacterial communities of different stages from an Indian treatment plant operated by Patancheru Environment Technology Limited (PETL) in Hyderabad, India. The plant receives waste water with high levels of fluoroquinolones and applies AS technology. A total of 1,019,400 sequences from samples of different stages of the treatment process were analyzed. In total 202, 303, 732, 652, 947 and 864 operational taxonomic units (OTUs) were obtained at 3% distance cutoff in the equilibrator, aeration tanks 1 and 2, settling tank, secondary sludge and old sludge samples from PETL, respectively. Proteobacteria was the most dominant phyla in all samples with Gammaproteobacteria and Betaproteobacteria being the dominant classes. Alcaligenaceae and Pseudomonadaceae, bacterial families from PETL previously reported to be highly multidrug resistant, were the dominant families in aeration tank samples. Despite regular addition of human sewage (approximately 20%) to uphold microbial activity, the bacterial diversity within aeration tanks from PETL was considerably lower than corresponding samples from seven, regular municipal waste water treatment plants. The strong selection pressure from antibiotics present may be one important factor in structuring the microbial community in PETL, which may affect not only resistance promotion but also general efficiency of the waste treatment process. PMID:27812209

Physico-chemical treatment of liquid waste on an industrial plant for electrocoagulation.

PubMed

Mlakar, Matej; Levstek, Marjetka; Stražar, Marjeta

2017-10-01

Wastewater from washing, oil separators, the metal processing and detergent industries, was tested and treated for treatment of different types of liquid waste at industrial level at Domžale-Kamnik Wastewater Treatment Plant (WWTP). The effect of implementing the electrocoagulation (EC) and flotation processes, respectively, is analysed and includes the duration of the EC implementation, voltage, number of electrodes, and chemical addition, as well as the pH effect and conductivity. The tests were performed not only on various types of liquid waste, but also on different mixtures of liquid waste. Laboratory analysis of the samples before and after EC have shown an effective reduction not only in organic loads in accordance with the COD (chemical oxygen demand) parameter, but also in mineral oil content, toxic metal concentration, and surfactants. The COD in liquid waste from the detergent industry was reduced by 73% and the content of surfactants by 64%. In liquid waste from the metal processing industry, the COD decreased by up to 95%, while the content of toxic metals decreased from 59 to 99%. Similar phenomena were shown in liquid waste from oil separators, where the COD was reduced to 33% and the concentration of mineral oils by 99%. Some of the liquid wastes were mixed together in the ratio 1:1, thus allowing testing of the operation of EC technology in heterogeneous liquid waste, where the final result proved to be effective cleaning as well. After treatment in the process of EC, the limit values of the treated water proved appropriate for discharge into the sewerage system.

Preparation of activated carbon from waste plastics polyethylene terephthalate as adsorbent in natural gas storage

NASA Astrophysics Data System (ADS)

Yuliusman; Nasruddin; Sanal, A.; Bernama, A.; Haris, F.; Ramadhan, I. T.

2017-02-01

The main problem is the process of natural gas storage and distribution, because in normal conditions of natural gas in the gas phase causes the storage capacity be small and efficient to use. The technology is commonly used Compressed Natural Gas (CNG) and Liquefied Natural Gas (LNG). The weakness of this technology safety level is low because the requirement for high-pressure CNG (250 bar) and LNG requires a low temperature (-161°C). It takes innovation in the storage of natural gas using the technology ANG (Adsorbed Natural Gas) with activated carbon as an adsorbent, causing natural gas can be stored in a low pressure of about 34.5. In this research, preparation of activated carbon using waste plastic polyethylene terephthalate (PET). PET plastic waste is a good raw material for making activated carbon because of its availability and the price is a lot cheaper. Besides plastic PET has the appropriate characteristics as activated carbon raw material required for the storage of natural gas because the material is hard and has a high carbon content of about 62.5% wt. The process of making activated carbon done is carbonized at a temperature of 400 ° C and physical activation using CO2 gas at a temperature of 975 ° C. The parameters varied in the activation process is the flow rate of carbon dioxide and activation time. The results obtained in the carbonization process yield of 21.47%, while the yield on the activation process by 62%. At the optimum process conditions, the CO2 flow rate of 200 ml/min and the activation time of 240 minutes, the value % burn off amounted to 86.69% and a surface area of 1591.72 m2/g.

Technical Review of Retrieval and Closure Plans for the INEEL INTEC Tank Farm Facility

DOE Office of Scientific and Technical Information (OSTI.GOV)

Bamberger, Judith A; Burks, Barry L; Quigley, Keith D

2001-09-28

The purpose of this report is to document the conclusions of a technical review of retrieval and closure plans for the Idaho National Energy and Environmental Laboratory (INEEL) Idaho Nuclear Technology and Engineering Center (INTEC) Tank Farm Facility. In addition to reviewing retrieval and closure plans for these tanks, the review process served as an information exchange mechanism so that staff in the INEEL High Level Waste (HLW) Program could become more familiar with retrieval and closure approaches that have been completed or are planned for underground storage tanks at the Oak Ridge National Laboratory (ORNL) and Hanford sites. Thismore » review focused not only on evaluation of the technical feasibility and appropriateness of the approach selected by INEEL but also on technology gaps that could be addressed through utilization of technologies or performance data available at other DOE sites and in the private sector. The reviewers, Judith Bamberger of Pacific Northwest National Laboratory (PNNL) and Dr. Barry Burks of The Providence Group Applied Technology, have extensive experience in the development and application of tank waste retrieval technologies for nuclear waste remediation.« less

Beyond land application: Emerging technologies for the treatment and reuse of anaerobically digested agricultural and food waste.

PubMed

Sheets, Johnathon P; Yang, Liangcheng; Ge, Xumeng; Wang, Zhiwu; Li, Yebo

2015-10-01

Effective treatment and reuse of the massive quantities of agricultural and food wastes generated daily has the potential to improve the sustainability of food production systems. Anaerobic digestion (AD) is used throughout the world as a waste treatment process to convert organic waste into two main products: biogas and nutrient-rich digestate, called AD effluent. Biogas can be used as a source of renewable energy or transportation fuels, while AD effluent is traditionally applied to land as a soil amendment. However, there are economic and environmental concerns that limit widespread land application, which may lead to underutilization of AD for the treatment of agricultural and food wastes. To combat these constraints, existing and novel methods have emerged to treat or reuse AD effluent. The objective of this review is to analyze several emerging methods used for efficient treatment and reuse of AD effluent. Overall, the application of emerging technologies is limited by AD effluent composition, especially the total solid content. Some technologies, such as composting, use the solid fraction of AD effluent, while most other technologies, such as algae culture and struvite crystallization, use the liquid fraction. Therefore, dewatering of AD effluent, reuse of the liquid and solid fractions, and land application could all be combined to sustainably manage the large quantities of AD effluent produced. Issues such as pathogen regrowth and prevalence of emerging organic micro-pollutants are also discussed. Copyright © 2015 Elsevier Ltd. All rights reserved.

Development of an Alternative Treatment Scheme for Sr/TRU Removal: Permanganate Treatment of AN-107 Waste

DOE Office of Scientific and Technical Information (OSTI.GOV)

RT Hallen; SA Bryan; FV Hoopes

A number of Hanford tanks received waste containing organic complexants, which increase the volubility of Sr-90 and transuranic (TRU) elements. Wastes from these tanks require additional pretreatment to remove Sr-90 and TRU for immobilization as low activity waste (Waste Envelope C). The baseline pretreatment process for Sr/TRU removal was isotopic exchange and precipitation with added strontium and iron. However, studies at both Battelle and Savannah River Technology Center (SRTC) have shown that the Sr/Fe precipitates were very difficult to filter. This was a result of the formation of poor filtering iron solids. An alternate treatment technology was needed for Sr/TRUmore » removal. Battelle had demonstrated that permanganate treatment was effective for decontaminating waste samples from Hanford Tank SY-101 and proposed that permanganate be examined as an alternative Sr/TRU removal scheme for complexant-containing tank wastes such as AW107. Battelle conducted preliminary small-scale experiments to determine the effectiveness of permanganate treatment with AN-107 waste samples that had been archived at Battelle from earlier studies. Three series of experiments were performed to evaluate conditions that provided adequate Sr/TRU decontamination using permanganate treatment. The final series included experiments with actual AN-107 diluted feed that had been obtained specifically for BNFL process testing. Conditions that provided adequate Sr/TRU decontamination were identified. A free hydroxide concentration of 0.5M provided adequate decontamination with added Sr of 0.05M and permanganate of 0.03M for archived AN-107. The best results were obtained when reagents were added in the sequence Sr followed by permanganate with the waste at ambient temperature. The reaction conditions for Sr/TRU removal will be further evaluated with a 1-L batch of archived AN-107, which will provide a large enough volume of waste to conduct crossflow filtration studies (Hallen et al. 2000a).« less

Applications analysis report: Silicate Technology Corporation's solidification/stabilization technology for organic and inorganic contaminants in soils

NASA Astrophysics Data System (ADS)

Bates, E.

1992-12-01

The STC demonstration was conducted under EPA's Superfund Innovative Technology Evaluation (SITE) Program in November, 1990, at the Selma Pressure Treating (SPT) wood preserving site in Selma, California. The SPT site was contaminated with both organics, predominantly pentachlorophenol (PCP), inorganics, mainly arsenic, chromium, and copper. Extensive sampling and analyses were performed on the waste both before and after treatment to compare physical, chemical, and leaching characteristics of raw and treated wastes. STC's contaminated soil treatment process was evaluated based on contaminant mobility measured by numerous leaching tests, structural integrity of the solidified material, measured by physical and engineering tests and morphological examinations; and economic analysis, using cost information supplied by STC and the results of the SITE demonstration, the vendor's design and test data, and other laboratory and field applications of the technology. It discusses the advantages, disadvantages, and limitations, as well as estimated costs of the technology.

Small Column Ion Exchange Design and Safety Strategy

DOE Office of Scientific and Technical Information (OSTI.GOV)

Huff, T.; Rios-Armstrong, M.; Edwards, R.

2011-02-07

Small Column Ion Exchange (SCIX) is a transformational technology originally developed by the Department of Energy (DOE) Environmental Management (EM-30) office and is now being deployed at the Savannah River Site (SRS) to significantly increase overall salt processing capacity and accelerate the Liquid Waste System life-cycle. The process combines strontium and actinide removal using Monosodium Titanate (MST), Rotary Microfiltration, and cesium removal using Crystalline Silicotitanate (CST, specifically UOP IONSIV{reg_sign}IE-911 ion exchanger) to create a low level waste stream to be disposed in grout and a high level waste stream to be vitrified. The process also includes preparation of the streamsmore » for disposal, e.g., grinding of the loaded CST material. These waste processing components are technically mature and flowsheet integration studies are being performed including glass formulations studies, application specific thermal modeling, and mixing studies. The deployment program includes design and fabrication of the Rotary Microfilter (RMF) assembly, ion-exchange columns (IXCs), and grinder module, utilizing an integrated system safety design approach. The design concept is to install the process inside an existing waste tank, Tank 41H. The process consists of a feed pump with a set of four RMFs, two IXCs, a media grinder, three Submersible Mixer Pumps (SMPs), and all supporting infrastructure including media receipt and preparation facilities. The design addresses MST mixing to achieve the required strontium and actinide removal and to prevent future retrieval problems. CST achieves very high cesium loadings (up to 1,100 curies per gallon (Ci/gal) bed volume). The design addresses the hazards associated with this material including heat management (in column and in-tank), as detailed in the thermal modeling. The CST must be size reduced for compatibility with downstream processes. The design addresses material transport into and out of the grinder and includes provisions for equipment maintenance including remote handling. The design includes a robust set of nuclear safety controls compliant with DOE Standard (STD)-1189, Integration of Safety into the Design Process. The controls cover explosions, spills, boiling, aerosolization, and criticality. Natural Phenomena Hazards (NPH) including seismic event, tornado/high wind, and wildland fire are considered. In addition, the SCIX process equipment was evaluated for impact to existing facility safety equipment including the waste tank itself. SCIX is an innovative program which leverages DOE's technology development capabilities to provide a basis for a successful field deployment.« less

Comparative lifecycle assessment of alternatives for waste management in Rio de Janeiro - Investigating the influence of an attributional or consequential approach.

PubMed

Bernstad Saraiva, A; Souza, R G; Valle, R A B

2017-10-01

The environmental impacts from three management alternatives for organic fraction of municipal solid waste were compared using lifecycle assessment methodology. The alternatives (sanitary landfill, selective collection of organic waste for anaerobic digestion and anaerobic digestion after post-separation of organic waste) were modelled applying an attributional as well as consequential approach, in parallel with the aim of identifying if and how these approaches can affect results and conclusions. The marginal processes identified in the consequential modelling were in general associated with higher environmental impacts than average processes modelled with an attributional approach. As all investigated waste management alternatives result in net-substitution of energy and in some cases also materials, the consequential modelling resulted in lower absolute environmental impacts in five of the seven environmental impact categories assessed in the study. In three of these, the chosen modelling approach can alter the hierarchy between compared waste management alternatives. This indicates a risk of underestimating potential benefits from efficient energy recovery from waste when applying attributional modelling in contexts in which electricity provision historically has been dominated by technologies presenting rather low environmental impacts, but where projections point at increasing impacts from electricity provision in coming years. Thus, in the present case study, the chosen approach affects both absolute and relative results from the comparison. However, results were largely related to the processes identified as affected by investigated changes, and not merely the chosen modelling approach. The processes actually affected by future choices between different waste management alternatives are intrinsically uncertain. The study demonstrates the benefits of applying different assumptions regarding the processes affected by investigated choices - both for provision of energy and materials substituted by waste management processes in consequential LCA modelling, in order to present outcomes that are relevant as decision support within the waste management sector. Copyright © 2017 Elsevier Ltd. All rights reserved.

Green Aerospace Fuels from Nonpetroleum Sources

NASA Technical Reports Server (NTRS)

Hepp, Aloysius F.; Kulis, Michael J.; DeLaRee, Ana B.; Zubrin, Robert; Berggren, Mark; Hensel, Joseph D.; Kimble, Michael C.

2011-01-01

Efforts to produce green aerospace propellants from nonpetroleum sources are outlined. The paper begins with an overview of feedstock processing and relevant small molecule or C1 chemistry. Gas-to-liquid technologies, notably Fischer-Tropsch (FT) processing of synthesis gas (CO and H2), are being optimized to enhance the fraction of product stream relevant to aviation (and other transportation) fuels at the NASA Glenn Research Center (GRC). Efforts to produce optimized catalysts are described. Given the high cost of space launch, the recycling of human metabolic and plastic wastes to reduce the need to transport consumables to orbit to support the crew of a space station has long been recognized as a high priority. If the much larger costs of transporting consumables to the Moon or beyond are taken into account, the importance of developing waste recycling systems becomes still more imperative. One promising way to transform organic waste products into useful gases is steam reformation; this well-known technology is currently being optimized by a Colorado company for exploration and planetary surface operations. Reduction of terrestrial waste streams while producing energy and/or valuable raw materials is an opportunity being realized by a new generation of visionary entrepreneurs. A technology that has successfully demonstrated production of fuels and related chemicals from waste plastics developed in Northeast Ohio is described. Technologies being developed by a Massachusetts company to remove sulfur impurities are highlighted. Common issues and concerns for nonpetroleum fuel production are emphasized. Energy utilization is a concern for production of fuels whether a terrestrial operation or on the lunar (or Martian) surface; the term green relates to not only mitigating excess carbon release but also to the efficiency of grid-energy usage. For space exploration, energy efficiency can be an essential concern. Other issues of great concern include minimizing impurities in the product stream(s), especially those that potential health risks and/or could degrade operations through catalyst poisoning or equipment damage. The potential impacts on future missions by such concerns are addressed in closing.

Small Scale Gasification Application and Perspectives in Circular Economy

NASA Astrophysics Data System (ADS)

Klavins, Maris; Bisters, Valdis; Burlakovs, Juris

2018-06-01

Gasification is the process converting solid fuels as coal and organic plant matter, or biomass into combustible gas, called syngas. Gasification is a thermal conversion process using carbonaceous fuel, and it differs substantially from other thermal processes such as incineration or pyrolysis. The process can be used with virtually any carbonaceous fuel. It is an endothermic thermal conversion process, with partial oxidation being the dominant feature. Gasification converts various feedstock including waste to a syngas. Instead of producing only heat and electricity, synthesis gas produced by gasification may be transformed into commercial products with higher value as transport fuels, fertilizers, chemicals and even to substitute natural gas. Thermo-chemical conversion of biomass and solid municipal waste is developing as a tool to promote the idea of energy system without fossil fuels to a reality. In municipal solid waste management, gasification does not compete with recycling, moreover it enhances recycling programs. Pre-processing and after-processing must increase the amount of recyclables in the circular economy. Additionally, end of life plastics can serve as an energy feedstock for gasification as otherwise it cannot be sorted out and recycled. There is great potential for application of gasification technology within the biomass waste and solid waste management sector. Industrial self-consumption in the mode of combined heat and power can contribute to sustainable economic development within a circular economy.

Current technologies and new insights for the recovery of high valuable compounds from fruits by-products.

PubMed

Ferrentino, Giovanna; Asaduzzaman, Md; Scampicchio, Matteo Mario

2018-02-11

The recovery of high valuable compounds from food waste is becoming a tighten issue in food processing. The large amount of non-edible residues produced by food industries causes pollution, difficulties in the management, and economic loss. The waste produced during the transformation of fruits includes a huge amount of materials such as peels, seeds, and bagasse, whose disposal usually represents a problem. Research over the past 20 years revealed that many food wastes could serve as a source of potentially valuable bioactive compounds, such as antioxidants and vitamins with increasing scientific interest thanks to their beneficial effects on human health. The challenge for the recovery of these compounds is to find the most appropriate and environment friendly extraction technique able to achieve the maximum extraction yield without compromising the stability of the extracted products. Based on this scenario, the aim of the current review is twofold. The first is to give a brief overview of the most important bioactive compounds occurring in fruit wastes. The second is to describe the pro and cons of the most up-to-dated innovative and environment friendly extraction technologies that can be an alternative to the classical solvent extraction procedures for the recovery of valuable compounds from fruit processing. Furthermore, a final section will take into account published findings on the combination of some of these technologies to increase the extracts yields of bioactives.

Energy and cost savings results for advanced technology systems from the Cogeneration Technology Alternatives Study /CTAS/

NASA Technical Reports Server (NTRS)

Sagerman, G. D.; Barna, G. J.; Burns, R. K.

1979-01-01

The Cogeneration Technology Alternatives Study (CTAS), a program undertaken to identify the most attractive advanced energy conversion systems for industrial cogeneration applications in the 1985-2000 time period, is described, and preliminary results are presented. Two cogeneration options are included in the analysis: a topping application, in which fuel is input to the energy conversion system which generates electricity and waste heat from the conversion system is used to provide heat to the process, and a bottoming application, in which fuel is burned to provide high temperature process heat and waste heat from the process is used as thermal input to the energy conversion system which generates energy. Steam turbines, open and closed cycle gas turbines, combined cycles, diesel engines, Stirling engines, phosphoric acid and molten carbonate fuel cells and thermionics are examined. Expected plant level energy savings, annual energy cost savings, and other results of the economic analysis are given, and the sensitivity of these results to the assumptions concerning fuel prices, price of purchased electricity and the potential effects of regional energy use characteristics is discussed.

Waste management facility accident analysis (WASTE ACC) system: software for analysis of waste management alternatives

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kohout, E.F.; Folga, S.; Mueller, C.

1996-03-01

This paper describes the Waste Management Facility Accident Analysis (WASTE{underscore}ACC) software, which was developed at Argonne National Laboratory (ANL) to support the US Department of Energy`s (DOE`s) Waste Management (WM) Programmatic Environmental Impact Statement (PEIS). WASTE{underscore}ACC is a decision support and database system that is compatible with Microsoft{reg_sign} Windows{trademark}. It assesses potential atmospheric releases from accidents at waste management facilities. The software provides the user with an easy-to-use tool to determine the risk-dominant accident sequences for the many possible combinations of process technologies, waste and facility types, and alternative cases described in the WM PEIS. In addition, its structure willmore » allow additional alternative cases and assumptions to be tested as part of the future DOE programmatic decision-making process. The WASTE{underscore}ACC system demonstrates one approach to performing a generic, systemwide evaluation of accident risks at waste management facilities. The advantages of WASTE{underscore}ACC are threefold. First, the software gets waste volume and radiological profile data that were used to perform other WM PEIS-related analyses directly from the WASTE{underscore}MGMT system. Second, the system allows for a consistent analysis across all sites and waste streams, which enables decision makers to understand more fully the trade-offs among various policy options and scenarios. Third, the system is easy to operate; even complex scenario runs are completed within minutes.« less

Mobilization of radionuclides from uranium mill tailings and related waste materials in anaerobic environments

USGS Publications Warehouse

Landa, E.R.

2003-01-01

Specific extraction studies in our laboratory have shown that iron and manganese oxide- and alkaline earth sulfate minerals are important hosts of radium in uranium mill tailings. Iron- and sulfate-reducing bacteria may enhance the release of radium (and its analog barium) from uranium mill tailings, oil field pipe scale [a major technologically enhanced naturally occurring radioactive material (TENORM) waste], and jarosite (a common mineral in sulfuric acid processed-tailings). These research findings are reviewed and discussed in the context of nuclear waste forms (such as barium sulfate matrices), radioactive waste management practices, and geochemical environments in the Earth's surficial and shallow subsurface regions.

Valorization of winery waste vs. the costs of not recycling

DOE Office of Scientific and Technical Information (OSTI.GOV)

Devesa-Rey, R., E-mail: rosa.devesa.rey@uvigo.es; Vecino, X.; Varela-Alende, J.L.

Graphical abstract: Highlights: > Lactic acid, biosurfactants, xylitol or ethanol may be obtained from wine residues. > By-products valorization turns wine wastes into products with industrial applications. > The costs of waste disposal enhances the search of economically viable solutions for valorizing residues. - Abstract: Wine production generates huge amounts of waste. Before the 1990s, the most economical option for waste removal was the payment of a disposal fee usually being of around 3000 Euros. However, in recent years the disposal fee and fines for unauthorized discharges have increased considerably, often reaching 30,000-40,000 Euros, and a prison sentence is sometimesmore » also imposed. Some environmental friendly technologies have been proposed for the valorization of winery waste products. Fermentation of grape marc, trimming vine shoot or vinification lees has been reported to produce lactic acid, biosurfactants, xylitol, ethanol and other compounds. Furthermore, grape marc and seeds are rich in phenolic compounds, which have antioxidants properties, and vinasse contains tartaric acid that can be extracted and commercialized. Companies must therefore invest in new technologies to decrease the impact of agro-industrial residues on the environment and to establish new processes that will provide additional sources of income.« less

Conversion of transuranic waste to low level waste by decontamination: a site specific update

DOE Office of Scientific and Technical Information (OSTI.GOV)

Allen, R.P.; Hazelton, R.F.

1985-09-01

As a followup to an FY-1984 cost/benefit study, a program was conducted in FY-1985 to transfer to the relevant DOE sites the information and technology for the direct conversion of transuranic (TRU) waste to low-level waste (LLW) by decontamination. As part of this work, the economic evaluation of the various TRUW volume reduction and conversion options was updated and expanded to include site-specific factors. The results show, for the assumptions used, that size reduction, size reduction followed by decontamination, or in situ decontamination are cost effective compared with the no-processing option. The technology transfer activities included site presentations and discussionsmore » with operations and waste management personnel to identify application opportunities and site-specific considerations and constraints that could affect the implementation of TRU waste conversion principles. These discussions disclosed definite potential for the beneficial application of these principles at most of the sites, but also confirmed the existence of site-specific factors ranging from space limitations to LLW disposal restrictions that could preclude particular applications or diminish expected benefits. 8 refs., 2 figs., 4 tabs.« less