Women, e-waste, and technological solutions to climate change.

PubMed

McAllister, Lucy; Magee, Amanda; Hale, Benjamin

2014-06-14

In this paper, we argue that a crossover class of climate change solutions (which we term "technological solutions") may disproportionately and adversely impact some populations over others. We begin by situating our discussion in the wider climate discourse, particularly with regard to the Millennium Development Goals (MDGs) and the Basel Convention. We then suggest that many of the most attractive technological solutions to climate change, such as solar energy and electric car batteries, will likely add to the rapidly growing stream of electronic waste ("e-waste"). This e-waste may have negative downstream effects on otherwise disenfranchised populations. We argue that e-waste burdens women unfairly and disproportionately, affecting their mortality/morbidity and fertility, as well as the development of their children. Building on this, we claim that these injustices are more accurately captured as problems of recognition rather than distribution, since women are often institutionally under-acknowledged both in the workplace and in the home. Without institutional support and representation, women and children are deprived of adequate safety equipment, health precautions, and health insurance. Finally, we return to the question of climate justice in the context of the human right to health and argue for greater inclusion and recognition of women waste workers and other disenfranchised groups in forging future climate agreements. Copyright © 2014 McAllister, Magee. This is an open access article distributed under the terms of the Creative Commons Attribution Non-Commercial License (http://creativecommons.org/licenses/by-nc/3.0/), which permits unrestricted non-commercial use, distribution, and reproduction in any medium, provided the original author and source are credited.

Solid Waste Management Solutions for a Rapidly Urbanizing Area in Thailand: Recommendations Based on Stakeholder Input.

PubMed

Yukalang, Nachalida; Clarke, Beverley; Ross, Kirstin

2018-06-21

Municipal solid waste is a significant problem, particularly in developing countries that lack sufficient infrastructure and useable land mass to process it in an appropriate manner. Some developing nations are experiencing a combination of issues that prevent proper management of solid waste. This paper reviews the management of municipal solid waste in northeast Thailand, using the Tha Khon Yang Sub-district Municipality (TKYSM) in Maha Sarakham Province as a case study. The combination of rapid population and economic growth and its associated affluence has led to an increase in the use of consumer items and a concomitant increase in the production of municipal solid waste. In the TKYSM there is pressure on local government to establish a suitable waste management program to resolve the escalating waste crisis. The aim of this study is to provide viable solutions to waste management challenges in the TKYSM, and potentially to offer guidance to other similar localities also facing the same challenges. It is well established that successful changes to waste management require an understanding of local context and consideration of specific issues within a region. Therefore, extensive community consultation and engagement with local experts was undertaken to develop an understanding of the particular waste management challenges of the TKYSM. Research methods included observations, one-on-one interviews and focus groups with a range of different stakeholders. The outcomes of this research highlight a number of opportunities to improve local infrastructure and operational capacity around solid waste management. Waste management in rural and urban areas needs to be approached differently. Solutions include: development of appropriate policy and implementation plans (based around the recommendations of this paper); reduction of the volume of waste going to landfill by establishing a waste separation system; initiation of a collection service that supports waste

Planet Patrol. An Educational Unit on Solid Waste Solutions for Grades 4-6.

ERIC Educational Resources Information Center

Shively, Patti J.; And Others

This educational unit on solid waste solutions is intended to convey to students an understanding of the four methods of solid waste handling, in priority order, as recommended by the Environmental Protection Agency: (1) reduction in the volume of waste produced; (2) recycling and composting; (3) waste combustion, i.e., incineration of waste; and…

Radioactive Waste...The Problem and Some Possible Solutions

ERIC Educational Resources Information Center

Olivier, Jean-Pierre

1977-01-01

Nuclear safety is a highly technical and controversial subject that has caused much heated debate and political concern. This article examines the problems involved in managing radioactive wastes and the techniques now used. Potential solutions are suggested and the need for international cooperation is stressed. (Author/MA)

An eco friendly solution to the food waste disposal

NASA Astrophysics Data System (ADS)

Babu, G. Reddy; Kumar, G. Madhav

2017-07-01

In recent years, waste disposal at workmen camp is one of the major problems being faced by many nations across the world. In the workmen colony at Chittapur, a series of kitchens were built for cooking purpose and a number of small canteens are also functioning. Considerable quantity of food waste is collected daily from these eateries and disposed at a faraway place. Food waste is highly degradable in nature, if not disposed properly it causes problems related to environmental pollution. Hence, it is very important to identify an environment friendly process rather than opt for land filling or any disposal method. We worked together to find a suitable eco-friendly solution for the food waste disposal at Chittapur site and suggested that biogas production through anaerobic digestion is a solution for the disposal and utilization of food waste for better purpose. This resulted in setting up a 500 kg per day food waste treatment biogas plant at Chittapur. This establishment is the first time in the construction industry at workmen camp in India. Anaerobic Digestion has been recognized as one of the best options that is available for treating food waste, as it generates two valuable end products, biogas and compost. Biogas is a mixture of CH4 and CO2 about (55:45). Biogas generated can be used for thermal applications such as cooking or for generating electricity. The digested slurry is a well stabilized organic manure and can be used as soil fertilizer. Plant design is to handle 500 kg of food waste /day. 27 kg LPG is obtained from 500kg of kitchen waste. The Value of 27 kg of LPG is Rs.2700/day. Daily 1000 litres of digested effluent was obtained. It is good organic manure with plant micro nutrients and macro nutrients. This can be used for growing plants and in agriculture. The value of manure per day is Rs.250/-. The annual revenue is Rs.10.62 lakhs and the annual expenditure is 1.8 lakhs. The net benefit is 8.82 lakhs. Payback period is 2.1 years. This process

37. PLAN OF ACCESS CORRIDOR PIPING INCLUDES WASTE HOLD TANK ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

37. PLAN OF ACCESS CORRIDOR PIPING INCLUDES WASTE HOLD TANK CELL, OFFGAS CELL, ADSORBER CELL, AND OFFGAS FILTER CELL. INEEL DRAWING NUMBER 200-0633-00-287-106453. FLUOR NUMBER 5775-CPP-P-58. - Idaho National Engineering Laboratory, Old Waste Calcining Facility, Scoville, Butte County, ID

Calixarene crown ether solvent composition and use thereof for extraction of cesium from alkaline waste solutions

DOEpatents

Moyer, Bruce A.; Sachleben, Richard A.; Bonnesen, Peter V.; Presley, Derek J.

2001-01-01

A solvent composition and corresponding method for extracting cesium (Cs) from aqueous neutral and alkaline solutions containing Cs and perhaps other competing metal ions is described. The method entails contacting an aqueous Cs-containing solution with a solvent consisting of a specific class of lipophilic calix[4]arene-crown ether extractants dissolved in a hydrocarbon-based diluent containing a specific class of alkyl-aromatic ether alcohols as modifiers. The cesium values are subsequently recovered from the extractant, and the solvent subsequently recycled, by contacting the Cs-containing organic solution with an aqueous stripping solution. This combined extraction and stripping method is especially useful as a process for removal of the radionuclide cesium-137 from highly alkaline waste solutions which are also very concentrated in sodium and potassium. No pre-treatment of the waste solution is necessary, and the cesium can be recovered using a safe and inexpensive stripping process using water, dilute (millimolar) acid solutions, or dilute (millimolar) salt solutions. An important application for this invention would be treatment of alkaline nuclear tank wastes. Alternatively, the invention could be applied to decontamination of acidic reprocessing wastes containing cesium-137.

40 CFR 62.14590 - What should I include in my waste management plan?

Code of Federal Regulations, 2011 CFR

2011-07-01

... POLLUTANTS Federal Plan Requirements for Commercial and Industrial Solid Waste Incineration Units That Commenced Construction On or Before November 30, 1999 Waste Management Plan § 62.14590 What should I include... 40 Protection of Environment 8 2011-07-01 2011-07-01 false What should I include in my waste...

Closed circuit recovery of copper, lead and iron from electronic waste with citrate solutions.

PubMed

Torres, Robinson; Lapidus, Gretchen T

2017-02-01

An integral closed circuit hydrometallurgical process is presented for base metal recovery from electronic waste. The leaching medium consists of a sodium citrate solution, from which base metals are retrieved by direct electrowinning, and the barren solution is recycled back to the leaching stage. This leaching-electrowinning cycle was repeated four times. The redox properties of the fresh citrate solution, as well as the leach liquors, were characterized by cyclic voltammetry to determine adequate conditions for metal reduction, as well as to limit citrate degradation. The leaching efficiency of electronic waste, employing the same solution after four complete cycles was 71, 83 and 94% for copper, iron and lead, respectively, compared to the original leach with fresh citrate solution. Copyright © 2016 Elsevier Ltd. All rights reserved.

Nuclear waste solutions

DOEpatents

Walker, Darrel D.; Ebra, Martha A.

1987-01-01

High efficiency removal of technetium values from a nuclear waste stream is achieved by addition to the waste stream of a precipitant contributing tetraphenylphosphonium cation, such that a substantial portion of the technetium values are precipitated as an insoluble pertechnetate salt.

40 CFR 62.14590 - What should I include in my waste management plan?

Code of Federal Regulations, 2010 CFR

2010-07-01

... in my waste management plan? A waste management plan must include consideration of the reduction or separation of waste-stream elements such as paper, cardboard, plastics, glass, batteries, or metals; or the... waste management measures already in place, the costs of additional measures, the emissions reductions...

Technetium recovery from high alkaline solution

DOE Office of Scientific and Technical Information (OSTI.GOV)

Nash, Charles A.

2016-07-12

Disclosed are methods for recovering technetium from a highly alkaline solution. The highly alkaline solution can be a liquid waste solution from a nuclear waste processing system. Methods can include combining the solution with a reductant capable of reducing technetium at the high pH of the solution and adding to or forming in the solution an adsorbent capable of adsorbing the precipitated technetium at the high pH of the solution.

The Disposal of Hazardous Wastes.

ERIC Educational Resources Information Center

Barnhart, Benjamin J.

1978-01-01

The highlights of a symposium held in October, 1977 spotlight some problems and solutions. Topics include wastes from coal technologies, radioactive wastes, and industrial and agricultural wastes. (BB)

Removal of chromium(III) from aqueous waste solution by liquid-liquid extraction in a circular microchannel.

PubMed

Luo, Jian Hong; Li, Jun; Guo, Lei; Zhu, Xin Hua; Dai, Shuang; Li, Xing

2017-11-01

A new circular microchannel device has been proposed for the removal of chromium(III) from aqueous waste solution by using kerosene as a diluent and (2-ethylhexyl) 2-ethylhexyl phosphonate as an extractant. The proposed device has several advantages such as a flexible and easily adaptable design, easy maintenance, and cheap setup without the requirement of microfabrication. To study the extraction efficiency and advantages of the circular microchannel device in the removal of chromium(III), the effects of various operating conditions such as the inner diameter of the channel, the total flow velocity, the phase ratio, the initial pH of aqueous waste solution, the reaction temperature and the initial concentration of extractant on the extraction efficiency are investigated and the optimal process conditions are obtained. The results show that chromium(III) in aqueous waste solution can be effectively removed with (2-ethylhexyl) 2-ethylhexyl phosphonate in the circular microchannel. Under optimized conditions, an extraction efficiency of chromium(III) of more than 99% can be attained and the aqueous waste solution can be discharged directly, which can meet the Chinese national emission standards.

Geopolymerisation of fly ashes with waste aluminium anodising etching solutions.

PubMed

Ogundiran, M B; Nugteren, H W; Witkamp, G J

2016-10-01

Combined management of coal combustion fly ash and waste aluminium anodising etching solutions using geopolymerisation presents economic and environmental benefits. The possibility of using waste aluminium anodising etching solution (AES) as activator to produce fly ash geopolymers in place of the commonly used silicate solutions was explored in this study. Geopolymerisation capacities of five European fly ashes with AES and the leaching of elements from their corresponding geopolymers were studied. Conventional commercial potassium silicate activator-based geopolymers were used as a reference. The geopolymers produced were subjected to physical, mechanical and leaching tests. The leaching of elements was tested on 28 days cured and crushed geopolymers using NEN 12457-4, NEN 7375, SPLP and TCLP leaching tests. After 28 days ambient curing, the geopolymers based on the etching solution activator showed compressive strength values between 51 and 84 MPa, whereas the commercial potassium silicate based geopolymers gave compressive strength values between 89 and 115 MPa. Based on the regulatory limits currently associated with the used leaching tests, all except one of the produced geopolymers (with above threshold leaching of As and Se) passed the recommended limits. The AES-geopolymer geopolymers demonstrated excellent compressive strength, although less than geopolymers made from commercial activator. Additionally, they demonstrated low element leaching potentials and therefore can be suitable for use in construction works. Copyright © 2016. Published by Elsevier Ltd.

Electrolyte solutions including a phosphoranimine compound, and energy storage devices including same

DOE Office of Scientific and Technical Information (OSTI.GOV)

Klaehn, John R.; Dufek, Eric J.; Rollins, Harry W.

An electrolyte solution comprising at least one phosphoranimine compound and a metal salt. The at least one phosphoranimine compound comprises a compound of the chemical structure ##STR00001## where X is an organosilyl group or a tert-butyl group and each of R.sup.1, R.sup.2, and R.sup.3 is independently selected from the group consisting of an alkyl group, an aryl group, an alkoxy group, or an aryloxy group. An energy storage device including the electrolyte solution is also disclosed.

Recovery of cyanide in gold leach waste solution by volatilization and absorption.

PubMed

Gönen, N; Kabasakal, O S; Ozdil, G

2004-09-10

In this study, the effects of pH, time and temperature in regeneration of cyanide in the leaching waste solution of gold production from disseminated gold ore by cyanidation process were investigated and the optimum conditions, consumptions and cyanide recovery values were determined. The sample of waste solution containing 156 mg/l free CN- and 358 mg/l total CN-, that was obtained from Gümüşhane-Mastra/Turkey disseminated gold ores by cyanidation and carbon-in-pulp (CIP) process under laboratory conditions was used in the experiments. Acidification with H2SO4, volatilization of hydrogen cyanide (HCN) with air stripping and absorption of HCN in a basic solution stages were applied and under optimum conditions, 100% of free cyanide and 48% of complex cyanide and consequently 70% of the total cyanide in the liquid phase of gold leach effluent are recovered.

[Bioregeneration of the solutions obtained during the leaching of nonferrous metals from waste slag by acidophilic microorganisms].

PubMed

Fomchenko, N V; Murav'ev, M I; Kondrat'eva, T F

2014-01-01

The bioregeneration of the solutions obtained after the leaching of copper and zinc from waste slag by sulfuric solutions of ferric sulfate is examined. For bioregeneration, associations of mesophilic and moderately thermqophilic acidophilic chemolithotrophic microorganisms were made. It has been shown that the complete oxidation of iron ions in solutions obtained after the leaching of nonferrous metals from waste slag is possible at a dilution of the pregnant solution with a nutrient medium. It has been found that the maximal rate of oxidation of iron ions is observed at the use of a mesophilic association of microorganisms at a threefold dilution of the pregnant solution with a nutrient medium. The application ofbioregeneration during the production of nonferrous metals from both waste and converter slags would make it possible to approach the technology of their processing using the closed cycle of workflows.

Conditioning sulfidic mine waste for growth of Agrostis capillaris--impact on solution chemistry.

PubMed

Sjöberg, Viktor; Karlsson, Stefan; Grandin, Anna; Allard, Bert

2014-01-01

Contamination of the environment due to mining and mineral processing is an urgent problem worldwide. It is often desirable to establish a grass cover on old mine waste since it significantly decreases the production of leachates. To obtain sustainable growth, it is often necessary to improve several properties of the waste such as water-holding capacity, nutrient status, and toxicity. This can be done by addition of organic materials such as wood residues, e.g., compost. In this study, we focus on the solution chemistry of the leachates when a substrate containing historic sulfidic mine waste mixed with 30 % (volume) bark compost is overgrown by Agrostis capillaris. The pot experiments also included other growth-promoting additives (alkaline material, mycorrhiza, and metabolizable carbon) to examine whether a more sustainable growth could be obtained. Significant changes in the plant growth and in the leachates composition were observed during 8 weeks of growth. It was concluded that in this time span, the growth of A. capillaris did not affect the composition of the leachates from the pots. Instead, the composition of the leachates was determined by interactions between the bark compost and the mine waste. Best growth of A. capillaris was obtained when alkaline material and mycorrhiza or metabolizable carbon was added to the substrate.

40 CFR 60.3012 - What should I include in my waste management plan?

Code of Federal Regulations, 2010 CFR

2010-07-01

... management plan? 60.3012 Section 60.3012 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED... Compliance Times for Other Solid Waste Incineration Units That Commenced Construction On or Before December 9, 2004 Model Rule-Waste Management Plan § 60.3012 What should I include in my waste management plan? A...

Arsenic: a roadblock to potential animal waste management solutions.

PubMed

Nachman, Keeve E; Graham, Jay P; Price, Lance B; Silbergeld, Ellen K

2005-09-01

The localization and intensification of the poultry industry over the past 50 years have incidentally created a largely ignored environmental management crisis. As a result of these changes in poultry production, concentrated animal feeding operations (CAFOs) produce far more waste than can be managed by land disposal within the regions where it is produced. As a result, alternative waste management practices are currently being implemented, including incineration and pelletization of waste. However, organic arsenicals used in poultry feed are converted to inorganic arsenicals in poultry waste, limiting the feasibility of waste management alternatives. The presence of inorganic arsenic in incinerator ash and pelletized waste sold as fertilizer creates opportunities for population exposures that did not previously exist. The removal of arsenic from animal feed is a critical step toward safe poultry waste management.

Complex electronic waste treatment - An effective process to selectively recover copper with solutions containing different ammonium salts.

PubMed

Sun, Z H I; Xiao, Y; Sietsma, J; Agterhuis, H; Yang, Y

2016-11-01

Recovery of valuable metals from electronic waste has been highlighted by the EU directives. The difficulties for recycling are induced by the high complexity of such waste. In this research, copper could be selectively recovered using an ammonia-based process, from industrially processed information and communication technology (ICT) waste with high complexity. A detailed understanding on the role of ammonium salt was focused during both stages of leaching copper into a solution and the subsequent step for copper recovery from the solution. By comparing the reactivity of the leaching solution with different ammonium salts, their physiochemical behaviour as well as the leaching efficiency could be identified. The copper recovery rate could reach 95% with ammonium carbonate as the leaching salt. In the stage of copper recovery from the solution, electrodeposition was introduced without an additional solvent extraction step and the electrochemical behaviour of the solution was figured out. With a careful control of the electrodeposition conditions, the current efficiency could be improved to be 80-90% depending on the ammonia salts and high purity copper (99.9wt.%). This research provides basis for improving the recyclability and efficiency of copper recovery from such electronic waste and the whole process design for copper recycling. Copyright © 2016 Elsevier Ltd. All rights reserved.

Treatment of halogen-containing waste and other waste materials

DOEpatents

Forsberg, Charles W.; Beahm, Edward C.; Parker, George W.

1997-01-01

A process for treating a halogen-containing waste material. The process provides a bath of molten glass containing a sacrificial metal oxide capable of reacting with a halogen in the waste material. The sacrificial metal oxide is present in the molten glass in at least a stoichiometric amount with respect to the halogen in the waste material. The waste material is introduced into the bath of molten glass to cause a reaction between the halogen in the waste material and the sacrificial metal oxide to yield a metal halide. The metal halide is a gas at the temperature of the molten glass. The gaseous metal halide is separated from the molten glass and contacted with an aqueous scrubber solution of an alkali metal hydroxide to yield a metal hydroxide or metal oxide-containing precipitate and a soluble alkali metal halide. The precipitate is then separated from the aqueous scrubber solution. The molten glass containing the treated waste material is removed from the bath as a waste glass. The process of the invention can be used to treat all types of waste material including radioactive wastes. The process is particularly suited for separating halogens from halogen-containing wastes.

Agricultural waste material as potential adsorbent for sequestering heavy metal ions from aqueous solutions - a review.

PubMed

Sud, Dhiraj; Mahajan, Garima; Kaur, M P

2008-09-01

Heavy metal remediation of aqueous streams is of special concern due to recalcitrant and persistency of heavy metals in environment. Conventional treatment technologies for the removal of these toxic heavy metals are not economical and further generate huge quantity of toxic chemical sludge. Biosorption is emerging as a potential alternative to the existing conventional technologies for the removal and/or recovery of metal ions from aqueous solutions. The major advantages of biosorption over conventional treatment methods include: low cost, high efficiency, minimization of chemical or biological sludge, regeneration of biosorbents and possibility of metal recovery. Cellulosic agricultural waste materials are an abundant source for significant metal biosorption. The functional groups present in agricultural waste biomass viz. acetamido, alcoholic, carbonyl, phenolic, amido, amino, sulphydryl groups etc. have affinity for heavy metal ions to form metal complexes or chelates. The mechanism of biosorption process includes chemisorption, complexation, adsorption on surface, diffusion through pores and ion exchange etc. The purpose of this review article is to provide the scattered available information on various aspects of utilization of the agricultural waste materials for heavy metal removal. Agricultural waste material being highly efficient, low cost and renewable source of biomass can be exploited for heavy metal remediation. Further these biosorbents can be modified for better efficiency and multiple reuses to enhance their applicability at industrial scale.

Copper-Sulfate Pentahydrate as a Product of the Waste Sulfuric Acid Solution Treatment

NASA Astrophysics Data System (ADS)

Marković, Radmila; Stevanović, Jasmina; Avramović, Ljiljana; Nedeljković, Dragutin; Jugović, Branimir; Stajić-Trošić, Jasna; Gvozdenović, Milica

2012-12-01

The aim of this study is synthesis of copper-sulfate pentahydrate from the waste sulfuric acid solution-mother liquor generated during the regeneration process of copper bleed solution. Copper is removed from the mother liquor solution in the process of the electrolytic treatment using the insoluble lead anodes alloyed with 6 mass pct of antimony on the industrial-scale equipment. As the result of the decopperization process, copper is removed in the form of the cathode sludge and is precipitated at the bottom of the electrolytic cell. By this procedure, the content of copper could be reduced to the 20 mass pct of the initial value. Chemical characterization of the sludge has shown that it contains about 90 mass pct of copper. During the decopperization process, the very strong poison, arsine, can be formed, and the process is in that case terminated. The copper leaching degree of 82 mass pct is obtained using H2SO4 aqueous solution with the oxygen addition during the cathode sludge chemical treatment at 80 °C ± 5 °C. Obtained copper salt satisfies the requirements of the Serbian Standard for Pesticide, SRPS H.P1. 058. Therefore, the treatment of waste sulfuric acid solutions is of great economic and environmental interest.

Treatment of halogen-containing waste and other waste materials

DOEpatents

Forsberg, C.W.; Beahm, E.C.; Parker, G.W.

1997-03-18

A process is described for treating a halogen-containing waste material. The process provides a bath of molten glass containing a sacrificial metal oxide capable of reacting with a halogen in the waste material. The sacrificial metal oxide is present in the molten glass in at least a stoichiometric amount with respect to the halogen in the waste material. The waste material is introduced into the bath of molten glass to cause a reaction between the halogen in the waste material and the sacrificial metal oxide to yield a metal halide. The metal halide is a gas at the temperature of the molten glass. The gaseous metal halide is separated from the molten glass and contacted with an aqueous scrubber solution of an alkali metal hydroxide to yield a metal hydroxide or metal oxide-containing precipitate and a soluble alkali metal halide. The precipitate is then separated from the aqueous scrubber solution. The molten glass containing the treated waste material is removed from the bath as a waste glass. The process of the invention can be used to treat all types of waste material including radioactive wastes. The process is particularly suited for separating halogens from halogen-containing wastes. 3 figs.

40 CFR 60.2630 - What should I include in my waste management plan?

Code of Federal Regulations, 2010 CFR

2010-07-01

... management plan? 60.2630 Section 60.2630 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED... Compliance Times for Commercial and Industrial Solid Waste Incineration Units that Commenced Construction On or Before November 30, 1999 Model Rule-Waste Management Plan § 60.2630 What should I include in my...

40 CFR 273.81 - Factors for petitions to include other wastes under 40 CFR part 273.

Code of Federal Regulations, 2012 CFR

2012-07-01

... generic name to identify the waste category (e.g., batteries), the definition of universal waste in § 260... waste category (e.g., hazardous waste batteries).) Thus, only the portion of the waste stream that does... group of industries, is commonly generated by a wide variety of types of establishments (including, for...

40 CFR 60.2630 - What should I include in my waste management plan?

Code of Federal Regulations, 2012 CFR

2012-07-01

... 40 Protection of Environment 7 2012-07-01 2012-07-01 false What should I include in my waste management plan? 60.2630 Section 60.2630 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED... consideration of the reduction or separation of waste-stream elements such as paper, cardboard, plastics, glass...

40 CFR 62.14590 - What should I include in my waste management plan?

Code of Federal Regulations, 2014 CFR

2014-07-01

... 40 Protection of Environment 9 2014-07-01 2014-07-01 false What should I include in my waste management plan? 62.14590 Section 62.14590 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY... separation of waste-stream elements such as paper, cardboard, plastics, glass, batteries, or metals; or the...

40 CFR 62.14590 - What should I include in my waste management plan?

Code of Federal Regulations, 2013 CFR

2013-07-01

... 40 Protection of Environment 9 2013-07-01 2013-07-01 false What should I include in my waste management plan? 62.14590 Section 62.14590 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY... separation of waste-stream elements such as paper, cardboard, plastics, glass, batteries, or metals; or the...

40 CFR 60.2065 - What should I include in my waste management plan?

Code of Federal Regulations, 2013 CFR

2013-07-01

... 40 Protection of Environment 7 2013-07-01 2013-07-01 false What should I include in my waste management plan? 60.2065 Section 60.2065 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED... reduction or separation of waste-stream elements such as paper, cardboard, plastics, glass, batteries, or...

40 CFR 60.2901 - What should I include in my waste management plan?

Code of Federal Regulations, 2014 CFR

2014-07-01

... 40 Protection of Environment 7 2014-07-01 2014-07-01 false What should I include in my waste management plan? 60.2901 Section 60.2901 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED... consideration of the reduction or separation of waste-stream elements such as paper, cardboard, plastics, glass...

40 CFR 60.2065 - What should I include in my waste management plan?

Code of Federal Regulations, 2014 CFR

2014-07-01

... 40 Protection of Environment 7 2014-07-01 2014-07-01 false What should I include in my waste management plan? 60.2065 Section 60.2065 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED... reduction or separation of waste-stream elements such as paper, cardboard, plastics, glass, batteries, or...

40 CFR 62.14590 - What should I include in my waste management plan?

Code of Federal Regulations, 2012 CFR

2012-07-01

... 40 Protection of Environment 9 2012-07-01 2012-07-01 false What should I include in my waste management plan? 62.14590 Section 62.14590 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY... separation of waste-stream elements such as paper, cardboard, plastics, glass, batteries, or metals; or the...

40 CFR 60.2901 - What should I include in my waste management plan?

Code of Federal Regulations, 2013 CFR

2013-07-01

... 40 Protection of Environment 7 2013-07-01 2013-07-01 false What should I include in my waste management plan? 60.2901 Section 60.2901 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED... consideration of the reduction or separation of waste-stream elements such as paper, cardboard, plastics, glass...

40 CFR 60.2630 - What should I include in my waste management plan?

Code of Federal Regulations, 2011 CFR

2011-07-01

... 40 Protection of Environment 6 2011-07-01 2011-07-01 false What should I include in my waste management plan? 60.2630 Section 60.2630 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED... of waste-stream elements such as paper, cardboard, plastics, glass, batteries, or metals; or the use...

Textile Dye Removal from Aqueous Solution using Modified Graphite Waste/Lanthanum/Chitosan Composite

NASA Astrophysics Data System (ADS)

Kusrini, E.; Wicaksono, B.; Yulizar, Y.; Prasetyanto, EA; Gunawan, C.

2018-03-01

We investigated various pre-treatment processes of graphite waste using thermal, mechanical and chemical methods. The aim of this work is to study the performance of modified graphite waste/lanthanum/chitosan composite (MG) as adsorbent for textile dye removal from aqueous solution. Effect of graphite waste resources, adsorbent size and lanthanum concentration on the dye removal were studied in batch experiments. Selectivity of MG was also investigated. Pre-heated graphite waste (NMG) was conducted at 80°C for 1 h, followed by mechanical crushing of the resultant graphite to 75 μm particle size, giving adsorption performance of ˜58%, ˜67%, ˜93% and ˜98% of the model dye rhodamine B (concentration determined by UV-vis spectroscopy at 554 nm), methyl orange (464 nm), methylene blue (664 nm) and methyl violet (580 nm), respectively from aqueous solution. For this process, the system required less than ˜5 min for adsorbent material to be completely saturated with the adsorbate. Further chemical modification of the pre-treated graphite waste (MG) with lanthanum (0.01 – V 0.03 M) and chitosan (0.5% w/w) did not improve the performance of dye adsorption. Under comparable experimental conditions, as those of the ‘thermal-mechanical-pre-treated-only’ (NMG), modification of graphite waste (MG) with 0.03 M lanthanum and 0.5% w/w chitosan resulted in ˜14%, ˜47%, ˜72% and ˜85% adsorption of rhodamine B, methyl orange, methylene blue and methyl violet, respectively. Selective adsorption of methylene blue at most to ˜79%, followed by methyl orange, methyl violet and rhodamine B with adsorption efficiency ˜67, ˜38, and ˜9% sequentially using MG with 0.03 M lanthanum and 0.5% w/w chitosan.

Editor's Page: Management of Hazardous Wastes.

ERIC Educational Resources Information Center

Chemical and Engineering News, 1980

1980-01-01

Discussed is the problem of management of hazardous waste disposal. Included are various federal laws and congressional kills pertinent to the problem of hazardous waste disposal. Suggested is cooperation between government and the chemical industry to work for a comprehensive solution to waste disposal. (DS)

Radioactive Wastes.

PubMed

Choudri, B S; Charabi, Yassine; Baawain, Mahad; Ahmed, Mushtaque

2017-10-01

Papers reviewed herein present a general overview of radioactive waste related activities around the world in 2016. The current reveiw include studies related to safety assessments, decommission and decontamination of nuclear facilities, fusion facilities, transportation. Further, the review highlights on management solutions for the final disposal of low and high level radioactive wastes (LLW and HLW), interim storage and final disposal options for spent fuel (SF), and tritiated wastes, with a focus on environmental impacts due to the mobility of radionuclides in ecosystem, water and soil alongwith other progress made in the management of radioactive wastes.

Effect of temperature on copper, iron and lead leaching from e-waste using citrate solutions.

PubMed

Torres, Robinson; Segura-Bailón, Brenda; Lapidus, Gretchen T

2018-01-01

E-waste is a potential source of large quantities of metals. The ability of citrate solutions to recover base metals from these materials has been demonstrated. In the present study, the effect of the temperature on base metal leaching capacity by the citrate solutions is determined. The material employed consisted of a mechanically prepared, gravity concentrated e-waste, with a metallic content greater than 90%. The leaching conditions were selected based on previous research performed by the authors (0.5 M sodium citrate, pH 4.5 and 20 g per liter e-waste concentrate). Leaching tests were performed at temperatures between 0° and 70 °C. The initial leaching rates for the three metals increased with temperature. However, these tapered off with time for temperatures above 30 °C, which can be associated to citrate destruction. Copyright © 2017 Elsevier Ltd. All rights reserved.

Radioactive waste processing apparatus

DOEpatents

Nelson, Robert E.; Ziegler, Anton A.; Serino, David F.; Basnar, Paul J.

1987-01-01

Apparatus for use in processing radioactive waste materials for shipment and storage in solid form in a container is disclosed. The container includes a top, and an opening in the top which is smaller than the outer circumference of the container. The apparatus includes an enclosure into which the container is placed, solution feed apparatus for adding a solution containing radioactive waste materials into the container through the container opening, and at least one rotatable blade for blending the solution with a fixing agent such as cement or the like as the solution is added into the container. The blade is constructed so that it can pass through the opening in the top of the container. The rotational axis of the blade is displaced from the center of the blade so that after the blade passes through the opening, the blade and container can be adjusted so that one edge of the blade is adjacent the cylindrical wall of the container, to insure thorough mixing. When the blade is inside the container, a substantially sealed chamber is formed to contain vapors created by the chemical action of the waste solution and fixant, and vapors emanating through the opening in the container.

Characteristics of mineral nutrition of plants in the bio-technical life support system with human wastes included in mass exchange

NASA Astrophysics Data System (ADS)

Tikhomirova, Natalia; Ushakova, Sofya; Kalacheva, Galina; Tikhomirov, Alexander

2016-09-01

The study addresses the effectiveness of using ion exchange substrates (IES) to optimize mineral nutrition of plants grown in the nutrient solutions containing oxidized human wastes for application in bio-technical life support systems. The study shows that the addition of IES to the root-inhabited substrate is favorable for the growth of wheat vegetative organs but causes a decrease in the grain yield. By contrast, the addition of IES to the nutrient solution does not influence the growth of vegetative organs but favors normal development of wheat reproductive organs. Thus, to choose the proper method of adjusting the solution with IES, one should take into account specific parameters of plant growth and development and the possibility of multiple recycling of IES based on the liquid products of mineralization of human wastes.

Numerical modeling of subsurface radioactive solute transport from waste seepage ponds at the Idaho National Engineering Laboratory

USGS Publications Warehouse

Robertson, John B.

1976-01-01

Aqueous chemical and low-level radioactive effluents have been disposed to seepage ponds since 1952 at the Idaho National Engineering Laboratory. The solutions percolate toward the Snake River Plain aquifer (135 m below) through interlayered basalts and unconsolidated sediments and an extensive zone of ground water perched on a sedimentary layer about 40 m beneath the ponds. A three-segment numerical model was developed to simulate the system, including effects of convection, hydrodynamic dispersion, radioactive decay, and adsorption. Simulated hydraulics and solute migration patterns for all segments agree adequately with the available field data. The model can be used to project subsurface distributions of waste solutes under a variety of assumed conditions for the future. Although chloride and tritium reached the aquifer several years ago, the model analysis suggests that the more easily sorbed solutes, such as cesium-137 and strontium-90, would not reach the aquifer in detectable concentrations within 150 years for the conditions assumed. (Woodard-USGS)

Recovery of fission product palladium from acidic high level waste solutions

DOE Office of Scientific and Technical Information (OSTI.GOV)

Rizvi, G.H.; Mathur, J.N.; Murali, M.S.

1996-07-01

The recovery of palladium from a synthetic pressurized heavy water reactor high level waste (PHWR-HLW) solution has been carried out, and the best reagents to use for the actual HLW solutions are discussed. The extraction of palladium from nitric acid solutions has been carried out using Cyanex-471X (triisobutylphosphine sulfide, TIPS) as the extractant. The metal ion could be quantitatively extracted from solutions with nitric acid concentrations between 2.0 and 6.0 M. The species extracted into the organic phase was found to be Pd(NO{sub 3}){sub 2}{center_dot}TIPS. Nitric acid in the range of 2.0 to 5.0 M had no effect on TIPSmore » for at least 71 hours. A systematic study of gamma irradiation on loading and stripping of palladium from loaded organic phases using several potential extractants, TIPS, alpha benzoin oxime, dioctylsulfide, and dioctylsulfoxide has been made. A flow sheet for the recovery of palladium from actual HLW solutions using TIPS is proposed.« less

Controlling mechanisms of metals release form cement-based waste form in acetic acid solution

DOE Office of Scientific and Technical Information (OSTI.GOV)

Cheng, Kuang Ye.

1991-01-01

The purpose of this dissertation is to identify the individual leaching mechanisms of metals by knowing the pH profile within the leached specimen and the physical and chemical properties of the leached material. Leaching of cement-based waste form in acetic acid solutions with different acidic strengths has been investigated in this work. The pH profile along the acid penetration route in the cement-based waste form was identified by various pH color indicators. The pH in the surface altered layer varies from 5.0 to 6.0, which is very close to the pH in the bulk leachate. A reacting zone, where themore » pH abruptly changes from 6 to 12, sharply divides the altered surface layer from the remaining unleached waste form or kernel. Leaching of metals is controlled by the acidity available in the leachant. Dissolution of alkaline materials leaves a silica-rich layer on the surface of the cement-based waste form. This surface layer exhibits different properties than those of the unleached material. The surface layer has a higher water content, is lighter weight, and is soft and friable. Furthermore, the abundant silicate content on the solid surface detains portion of the leached metals, while they are moving through the leached layer into bulk solution. The leaching of metals is a consequence of acid penetration. The distance from the solid/solution interface to the front of the leaching boundary can be regarded as the depth of leaching zone, where the metals dissolve and diffuse out of the waste form. The metal ions diffuse through the leached layer may be retarded on the solid surface by the pH-dependent adsorption reactions. It is found that the leaching process through the leached layer is diffusion-controlled for calcium and cadmium, whereas diffusion and adsorption occur simultaneously in the leached layer for lead and arsenic.« less

Radioactive waste processing apparatus

DOEpatents

Nelson, R.E.; Ziegler, A.A.; Serino, D.F.; Basnar, P.J.

1985-08-30

Apparatus for use in processing radioactive waste materials for shipment and storage in solid form in a container is disclosed. The container includes a top, and an opening in the top which is smaller than the outer circumference of the container. The apparatus includes an enclosure into which the container is placed, solution feed apparatus for adding a solution containing radioactive waste materials into the container through the container opening, and at least one rotatable blade for blending the solution with a fixing agent such as cement or the like as the solution is added into the container. The blade is constructed so that it can pass through the opening in the top of the container. The rotational axis of the blade is displaced from the center of the blade so that after the blade passes through the opening, the blade and container can be adjusted so that one edge of the blade is adjacent the cylindrical wall of the container, to insure thorough mixing. When the blade is inside the container, a substantially sealed chamber is formed to contain vapors created by the chemical action of the waste solution and fixant, and vapors emanating through the opening in the container. The chamber may be formed by placing a removable extension over the top of the container. The extension communicates with the apparatus so that such vapors are contained within the container, extension and solution feed apparatus. A portion of the chamber includes coolant which condenses the vapors. The resulting condensate is returned to the container by the force of gravity.

40 CFR 62.14431 - What must my waste management plan include?

Code of Federal Regulations, 2012 CFR

2012-07-01

... include? 62.14431 Section 62.14431 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED... POLLUTANTS Federal Plan Requirements for Hospital/Medical/Infectious Waste Incinerators Constructed on or... Health Care Facilities.” This publication (AHA Catalog No. 057007) is available for purchase from the...

Research and demonstration results for a new "Double-Solution" technology for municipal solid waste treatment.

PubMed

Erping, Li; Haoyun, Chen; Yanyang, Shang; Jun, Pan; Qing, Hu

2017-11-01

In this paper, the pyrolysis characteristics of six typical components in municipal solid waste (MSW) were investigated through a TG-FTIR combined technique and it was concluded that the main pyrolysis process of the biomass components (including food residues, sawdust and paper) occurred at 150-600°C. The main volatiles were multi-component gas including H 2 O, CO 2 , and CO. The main pyrolysis temperatures of three artificial products (PP, PVC and leather) was ranged from 200to 500°C. The wavelength of small molecule gases (CH 4 , CO 2 and CO) and the the chemical bonds (CO and CC) were observed in the infrared spectrum Based on the pyrolysis temperature interval and volatile constituent, a new "double-solution" process of pyrolysis and oxygen-enrichment decomposition MSW was designed. To achieve this process, a double-solution project was built for the direct treatment of MSW (10t/d). The complete setup of equipment and analysis of the byproducts has been reported in this paper to indicate the performance of this process. Energy balance and economic benefits were analysed for the process supporting. It was successfully demonstrated that the double-solution process was the environmentally friendly alternative method for MSW treatment in Chinese rural areas. Copyright © 2017 Elsevier Ltd. All rights reserved.

Early containment of high-alkaline solution simulating low-level radioactive waste stream in clay-bearing blended cement

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kruger, A.A.; Olson, R.A.; Tennis, P.D.

1995-04-01

Portland cement blended with fly ash and attapulgite clay was mixed with high-alkaline solution simulating low-level radioactive waste stream at a one-to-one weight ratio. Mixtures were adiabatically and isothermally cured at various temperatures and analyzed for phase composition, total alkalinity, pore solution chemistry, and transport properties as measured by impedance spectroscopy. Total alkalinity is characterized by two main drops. The early one corresponds to a rapid removal of phosphorous, aluminum, sodium, and to a lesser extent potassium solution. The second drop from about 10 h to 3 days is mainly associated with the removal of aluminum, silicon, and sodium. Thereafter,more » the total alkalinity continues descending, but at a lower rate. All pastes display a rapid flow loss that is attributed to an early precipitation of hydrated products. Hemicarbonate appears as early as one hour after mixing and is probably followed by apatite precipitation. However, the former is unstable and decomposes at a rate that is inversely related to the curing temperature. At high temperatures, zeolite appears at about 10 h after mixing. At 30 days, the stabilized crystalline composition Includes zeolite, apatite and other minor amounts of CaCO{sub 3}, quartz, and monosulfate Impedance spectra conform with the chemical and mineralogical data. The normalized conductivity of the pastes shows an early drop, which is followed by a main decrease from about 12 h to three days. At three days, the permeability of the cement-based waste as calculated by Katz-Thompson equation is over three orders of magnitude lower than that of ordinary portland cement paste. However, a further decrease in the calculated permeability is questionable. Chemical stabilization is favorable through incorporation of waste species into apatite and zeolite.« less

Inhibition of nuclear waste solutions containing multiple aggressive anions

DOE Office of Scientific and Technical Information (OSTI.GOV)

Congdon, J.W.

1988-01-01

The inhibition of localized corrosion of carbon steel in caustic, high-level radioactive waste solutions was studied using cyclic potentiodynamic polarization scans, supplemented by partially immersed coupon tests. The electrochemical tests provided a rapid and accurate means of determining the relationship between the minimum inhibitor requirements and the concentration of the aggressive anions in this system. Nitrate, sulfate, chloride, and fluoride were identified as aggressive anions, however, no synergistic effects were observed between these anions. This observation may have important theoretical implications because it tends to contradict the behavior of aggressive anions as predicted by existing theories for localized corrosion.

Inhibition of nuclear waste solutions containing multiple aggressive anions

DOE Office of Scientific and Technical Information (OSTI.GOV)

Congdon, J.W.

1988-05-01

The inhibition of localized corrosion of carbon steel in caustic, high-level radioactive waste solutions was studied using cyclic potentiodynamic polarization scans supplemented by partially immersed coupon tests. The electrochemical tests provided a rapid and accurate means of determining the relationship between the minimum inhibitor requirements and the concentration of the aggressive anions in this system. Nitrate, sulfate, chloride, and fluoride were identified as aggressive anions; however, no synergistic effects were observed between these anions. This observation may have important theoretical implications because it tends to contradict the behavior of aggressive anions as predicted by existing theories for localized corrosion.

Ammonia nitrogen removal from aqueous solution by local agricultural wastes

NASA Astrophysics Data System (ADS)

Azreen, I.; Lija, Y.; Zahrim, A. Y.

2017-06-01

Excess ammonia nitrogen in the waterways causes serious distortion to environment such as eutrophication and toxicity to aquatic organisms. Ammonia nitrogen removal from synthetic solution was investigated by using 40 local agricultural wastes as potential low cost adsorbent. Some of the adsorbent were able to remove ammonia nitrogen with adsorption capacity ranging from 0.58 mg/g to 3.58 mg/g. The highest adsorption capacity was recorded by Langsat peels with 3.58 mg/g followed by Jackfruit seeds and Moringa peels with 3.37 mg/g and 2.64 mg/g respectively. This experimental results show that the agricultural wastes can be utilized as biosorbent for ammonia nitrogen removal. The effect of initial ammonia nitrogen concentration, pH and stirring rate on the adsorption process were studied in batch experiment. The adsorption capacity reached maximum value at pH 7 with initial concentration of 500 mg/L and the removal rate decreased as stirring rate was applied.

RECOVERY OF CESIUM FROM WASTE SOLUTIONS

DOEpatents

Burgus, W.H.

1959-06-30

This patent covers the precipitation of fission products including cesium on nickel or ferric ferrocyanide and subsequent selective dissolution from the carrier with a solution of ammonia or mercurlc nitrate.

Immobilization of Rose Waste Biomass for Uptake of Pb(II) from Aqueous Solutions

PubMed Central

Ansari, Tariq Mahmood; Hanif, Muhammad Asif; Mahmood, Abida; Ijaz, Uzma; Khan, Muhammad Aslam; Nadeem, Raziya; Ali, Muhammad

2011-01-01

Rosa centifolia and Rosa gruss an teplitz distillation waste biomass was immobilized using sodium alginate for Pb(II) uptake from aqueous solutions under varied experimental conditions. The maximum Pb(II) adsorption occurred at pH 5. Immobilized rose waste biomasses were modified physically and chemically to enhance Pb(II) removal. The Langmuir sorption isotherm and pseudo-second-order kinetic models fitted well to the adsorption data of Pb(II) by immobilized Rosa centifolia and Rosa gruss an teplitz. The adsorbed metal is recovered by treating immobilized biomass with different chemical reagents (H2SO4, HCl and H3PO4) and maximum Pb(II) recovered when treated with sulphuric acid (95.67%). The presence of cometals Na, Ca(II), Al(III), Cr(III), Cr(VI), and Cu(II), reduced Pb(II) adsorption on Rosa centifolia and Rosa gruss an teplitz waste biomass. It can be concluded from the results of the present study that rose waste can be effectively used for the uptake of Pb(II) from aqueous streams. PMID:21350666

Method for treating liquid wastes

DOEpatents

Katti, K.V.; Volkert, W.A.; Singh, P.; Ketring, A.R.

1995-12-26

The method of treating liquid waste in a media is accomplished by exposing the media to phosphinimines and sequestering {sup 99}Tc from the media by the phosphinimine (PN) functionalities. The system for treating the liquid waste in the media includes extraction of {sup 99}TcO{sub 4}{sup {minus}} from aqueous solutions into organic solvents or mixed organic/polar media, extraction of {sup 99}Tc from solutions on a solid matrix by using a container containing PN functionalities on solid matrices including an inlet and outlet for allowing flow of media through an immobilized phosphinimine ligand system contained within the container. Also, insoluble suspensions of phosphinimine functionalities on solid matrices in liquid solutions or present on supported liquid membranes (SLM) can be used to sequester {sup 99}Tc from those liquids. 6 figs.

Method for treating liquid wastes

DOEpatents

Katti, Kattesh V.; Volkert, Wynn A.; Singh, Prahlad; Ketring, Alan R.

1995-01-01

The method of treating liquid waste in a media is accomplished by exposing the media to phosphinimines and sequestering .sup.99 Tc from the media by the phosphinimine (PN) functionalities. The system for treating the liquid waste in the media includes extraction of .sup.99 TcO.sub.4.sup.- from aqueous solutions into organic solvents or mixed organic/polar media, extraction of .sup.99 Tc from solutions on a solid matrix by using a container containing PN functionalities on solid matrices including an inlet and outlet for allowing flow of media through an immobilized phosphinimine ligand system contained within the container. Also, insoluble suspensions of phosphinimine functionalities on solid matrices in liquid solutions or present on supported liquid membranes (SLM) can be used to sequester .sup.99 Tc from those liquids.

40 CFR 62.14431 - What must my waste management plan include?

Code of Federal Regulations, 2010 CFR

2010-07-01

... waste management plan must identify both the feasibility of, and the approach for, separating certain components of solid waste from the health care waste stream in order to reduce the amount of toxic emissions from incinerated waste. The waste management plan you develop may address, but is not limited to, paper...

40 CFR 62.14431 - What must my waste management plan include?

Code of Federal Regulations, 2011 CFR

2011-07-01

... waste management plan must identify both the feasibility of, and the approach for, separating certain components of solid waste from the health care waste stream in order to reduce the amount of toxic emissions from incinerated waste. The waste management plan you develop may address, but is not limited to, paper...

40 CFR 60.1565 - What subcategories of small municipal waste combustion units must I include in my State plan?

Code of Federal Regulations, 2014 CFR

2014-07-01

... waste combustion units must I include in my State plan? 60.1565 Section 60.1565 Protection of... NEW STATIONARY SOURCES Emission Guidelines and Compliance Times for Small Municipal Waste Combustion... of small municipal waste combustion units must I include in my State plan? This subpart specifies...

40 CFR 60.1565 - What subcategories of small municipal waste combustion units must I include in my State plan?

Code of Federal Regulations, 2011 CFR

2011-07-01

... waste combustion units must I include in my State plan? 60.1565 Section 60.1565 Protection of... NEW STATIONARY SOURCES Emission Guidelines and Compliance Times for Small Municipal Waste Combustion... of small municipal waste combustion units must I include in my State plan? This subpart specifies...

40 CFR 60.1565 - What subcategories of small municipal waste combustion units must I include in my State plan?

Code of Federal Regulations, 2012 CFR

2012-07-01

... waste combustion units must I include in my State plan? 60.1565 Section 60.1565 Protection of... NEW STATIONARY SOURCES Emission Guidelines and Compliance Times for Small Municipal Waste Combustion... of small municipal waste combustion units must I include in my State plan? This subpart specifies...

40 CFR 60.1565 - What subcategories of small municipal waste combustion units must I include in my State plan?

Code of Federal Regulations, 2013 CFR

2013-07-01

... waste combustion units must I include in my State plan? 60.1565 Section 60.1565 Protection of... NEW STATIONARY SOURCES Emission Guidelines and Compliance Times for Small Municipal Waste Combustion... of small municipal waste combustion units must I include in my State plan? This subpart specifies...

40 CFR 60.1565 - What subcategories of small municipal waste combustion units must I include in my State plan?

Code of Federal Regulations, 2010 CFR

2010-07-01

... waste combustion units must I include in my State plan? 60.1565 Section 60.1565 Protection of... NEW STATIONARY SOURCES Emission Guidelines and Compliance Times for Small Municipal Waste Combustion... of small municipal waste combustion units must I include in my State plan? This subpart specifies...

Dissolution of Simulated and Radioactive Savannah River Site High-Level Waste Sludges with Oxalic Acid & Citric Acid Solutions

DOE Office of Scientific and Technical Information (OSTI.GOV)

STALLINGS, MARY

This report presents findings from tests investigating the dissolution of simulated and radioactive Savannah River Site sludges with 4 per cent oxalic acid and mixtures of oxalic and citric acid previously recommended by a Russian team from the Khlopin Radium Institute and the Mining and Chemical Combine (MCC). Testing also included characterization of the simulated and radioactive waste sludges. Testing results showed the following: Dissolution of simulated HM and PUREX sludges with oxalic and citric acid mixtures at SRTC confirmed general trends reported previously by Russian testing. Unlike the previous Russian testing six sequential contacts of a mixture of oxalicmore » acid citric acids at a 2:1 ratio (v/w) of acid to sludge did not produce complete dissolution of simulated HM and PUREX sludges. We observed that increased sludge dissolution occurred at a higher acid to sludge ratio, 50:1 (v/w), compared to the recommended ratio of 2:1 (v/w). We observed much lower dissolution of aluminum in a simulated HM sludge by sodium hydroxide leaching. We attribute the low aluminum dissolution in caustic to the high fraction of boehmite present in the simulated sludge. Dissolution of HLW sludges with 4 per cent oxalic acid and oxalic/citric acid followed general trends observed with simulated sludges. The limited testing suggests that a mixture of oxalic and citric acids is more efficient for dissolving HM and PUREX sludges and provides a more homogeneous dissolution of HM sludge than oxalic acid alone. Dissolution of HLW sludges in oxalic and oxalic/citric acid mixtures produced residual sludge solids that measured at higher neutron poison to equivalent 235U weight ratios than that in the untreated sludge solids. This finding suggests that residual solids do not present an increased nuclear criticality safety risk. Generally the neutron poison to equivalent 235U weight ratios of the acid solutions containing dissolved sludge components are lower than those in the

Comparison of DSMC and CFD Solutions of Fire II Including Radiative Heating

NASA Technical Reports Server (NTRS)

Liechty, Derek S.; Johnston, Christopher O.; Lewis, Mark J.

2011-01-01

The ability to compute rarefied, ionized hypersonic flows is becoming more important as missions such as Earth reentry, landing high mass payloads on Mars, and the exploration of the outer planets and their satellites are being considered. These flows may also contain significant radiative heating. To prepare for these missions, NASA is developing the capability to simulate rarefied, ionized flows and to then calculate the resulting radiative heating to the vehicle's surface. In this study, the DSMC codes DAC and DS2V are used to obtain charge-neutral ionization solutions. NASA s direct simulation Monte Carlo code DAC is currently being updated to include the ability to simulate charge-neutral ionized flows, take advantage of the recently introduced Quantum-Kinetic chemistry model, and to include electronic energy levels as an additional internal energy mode. The Fire II flight test is used in this study to assess these new capabilities. The 1634 second data point was chosen for comparisons to be made in order to include comparisons to computational fluid dynamics solutions. The Knudsen number at this point in time is such that the DSMC simulations are still tractable and the CFD computations are at the edge of what is considered valid. It is shown that there can be quite a bit of variability in the vibrational temperature inferred from DSMC solutions and that, from how radiative heating is computed, the electronic temperature is much better suited for radiative calculations. To include the radiative portion of heating, the flow-field solutions are post-processed by the non-equilibrium radiation code HARA. Acceptable agreement between CFD and DSMC flow field solutions is demonstrated and the progress of the updates to DAC, along with an appropriate radiative heating solution, are discussed. In addition, future plans to generate more high fidelity radiative heat transfer solutions are discussed.

Effect of saline waste solution infiltration rates on uranium retention and spatial distribution in Hanford sediments.

PubMed

Wan, Jiamin; Tokunaga, Tetsu K; Kim, Yongman; Wang, Zheming; Lanzirotti, Antonio; Saiz, Eduardo; Serne, R Jeffrey

2008-03-15

The accidental overfilling of waste liquid from tank BX-102 at the Hanford Site in 1951 put about 10 t of U(VI) into the vadose zone. In order to understand the dominant geochemical reactions and transport processes that occurred during the initial infiltration and to help understand current spatial distribution, we simulated the waste liquid spilling event in laboratory sediment columns using synthesized metal waste solution. We found that, as the plume propagated through sediments, pH decreased greatly (as much as 4 units) at the moving plume front. Infiltration flow rates strongly affect U behavior. Slower flow rates resulted in higher sediment-associated U concentrations, and higher flow rates (> or =5 cm/day) permitted practically unretarded U transport. Therefore, given the very high Ksat of most of Hanford formation, the low permeability zones within the sediment could have been most important in retaining high concentrations of U during initial release into the vadose zone. Massive amount of colloids, including U-colloids, formed at the plume fronts. Total U concentrations (aqueous and colloid) within plume fronts exceeded the source concentration by up to 5-fold. Uranium colloid formation and accumulation at the neutralized plume front could be one mechanism responsible for highly heterogeneous U distribution observed in the contaminated Hanford vadose zone.

Supported liquid inorganic membranes for nuclear waste separation

DOEpatents

Bhave, Ramesh R; DeBusk, Melanie M; DelCul, Guillermo D; Delmau, Laetitia H; Narula, Chaitanya K

2015-04-07

A system and method for the extraction of americium from radioactive waste solutions. The method includes the transfer of highly oxidized americium from an acidic aqueous feed solution through an immobilized liquid membrane to an organic receiving solvent, for example tributyl phosphate. The immobilized liquid membrane includes porous support and separating layers loaded with tributyl phosphate. The extracted solution is subsequently stripped of americium and recycled at the immobilized liquid membrane as neat tributyl phosphate for the continuous extraction of americium. The sequestered americium can be used as a nuclear fuel, a nuclear fuel component or a radiation source, and the remaining constituent elements in the aqueous feed solution can be stored in glassified waste forms substantially free of americium.

Inhibition of nuclear waste solutions containing multiple aggressive anions

DOE Office of Scientific and Technical Information (OSTI.GOV)

Congdon, J.W.

1987-01-01

The inhibition of localized corrosion of carbon steel in caustic, high-level radioactive waste solutions was studied using cyclic potentiodynamic polarization scans, supplemented by partially immersed coupon tests. The electrochemical tests provided a rapid and accurate means of determining the relationship between the minimum inhibitor requirements and the concentration of the aggressive anions in this system. Nitrate, sulfate, chloride, and fluoride were identified as aggressive anions, however, no synergistic effects were observed between these anions. This observation may have important theoretical implications because it tends to contradict the behavior of aggressive anions as predicted by existing theories for localized corrosion. 10more » refs., 5 figs., 2 tabs.« less

Ionic liquids, electrolyte solutions including the ionic liquids, and energy storage devices including the ionic liquids

DOE Office of Scientific and Technical Information (OSTI.GOV)

Gering, Kevin L.; Harrup, Mason K.; Rollins, Harry W.

2015-12-08

An ionic liquid including a phosphazene compound that has a plurality of phosphorus-nitrogen units and at least one pendant group bonded to each phosphorus atom of the plurality of phosphorus-nitrogen units. One pendant group of the at least one pendant group comprises a positively charged pendant group. Additional embodiments of ionic liquids are disclosed, as are electrolyte solutions and energy storage devices including the embodiments of the ionic liquid.

Efficiency Evaluation of Food Waste Materials for the Removal of Metals and Metalloids from Complex Multi-Element Solutions

PubMed Central

Giuliano, Antonella; Astolfi, Maria Luisa; Congedo, Rossana; Masotti, Andrea; Canepari, Silvia

2018-01-01

Recent studies have shown the potential of food waste materials as low cost adsorbents for the removal of heavy metals and toxic elements from wastewater. However, the adsorption experiments have been performed in heterogeneous conditions, consequently it is difficult to compare the efficiency of the individual adsorbents. In this study, the adsorption capacities of 12 food waste materials were evaluated by comparing the adsorbents’ efficiency for the removal of 23 elements from complex multi-element solutions, maintaining homogeneous experimental conditions. The examined materials resulted to be extremely efficient for the adsorption of many elements from synthetic multi-element solutions as well as from a heavy metal wastewater. The 12 adsorbent surfaces were analyzed by Fourier transform infrared spectroscopy and showed different types and amounts of functional groups, which demonstrated to act as adsorption active sites for various elements. By multivariate statistical computations of the obtained data, the 12 food waste materials were grouped in five clusters characterized by different elements’ removal efficiency which resulted to be in correlation with the specific adsorbents’ chemical structures. Banana peel, watermelon peel and grape waste resulted the least selective and the most efficient food waste materials for the removal of most of the elements. PMID:29495363

Efficiency Evaluation of Food Waste Materials for the Removal of Metals and Metalloids from Complex Multi-Element Solutions.

PubMed

Massimi, Lorenzo; Giuliano, Antonella; Astolfi, Maria Luisa; Congedo, Rossana; Masotti, Andrea; Canepari, Silvia

2018-02-26

Recent studies have shown the potential of food waste materials as low cost adsorbents for the removal of heavy metals and toxic elements from wastewater. However, the adsorption experiments have been performed in heterogeneous conditions, consequently it is difficult to compare the efficiency of the individual adsorbents. In this study, the adsorption capacities of 12 food waste materials were evaluated by comparing the adsorbents' efficiency for the removal of 23 elements from complex multi-element solutions, maintaining homogeneous experimental conditions. The examined materials resulted to be extremely efficient for the adsorption of many elements from synthetic multi-element solutions as well as from a heavy metal wastewater. The 12 adsorbent surfaces were analyzed by Fourier transform infrared spectroscopy and showed different types and amounts of functional groups, which demonstrated to act as adsorption active sites for various elements. By multivariate statistical computations of the obtained data, the 12 food waste materials were grouped in five clusters characterized by different elements' removal efficiency which resulted to be in correlation with the specific adsorbents' chemical structures. Banana peel, watermelon peel and grape waste resulted the least selective and the most efficient food waste materials for the removal of most of the elements.

An overview of the sustainability of solid waste management at military installations

DOE Office of Scientific and Technical Information (OSTI.GOV)

Borglin, S.; Shore, J.; Worden, H.

2009-08-15

Sustainable municipal solid waste management at military solutions necessitates a combined approach that includes waste reduction, alternative disposal techniques, and increased recycling. Military installations are unique because they often represent large employers in the region in which they are located, thereby making any practices they employ impact overall waste management strategies of the region. Solutions for waste sustainability will be dependent on operational directives and base location, availability of resources such as water and energy, and size of population. Presented in this paper are descriptions of available waste strategies that can be used to support sustainable waste management. Results presentedmore » indicate source reduction and recycling to be the most sustainable solutions. However, new waste-to-energy plants and composting have potential to improve on these well proven techniques and allow military installations to achieve sustainable waste management.« less

Estimation of cesium ion exchange distribution coefficients for concentrated electrolytic solutions when using crystalline silicotitanates

DOE Office of Scientific and Technical Information (OSTI.GOV)

Zheng, Z.; Gu, D.; Anthony, R.G.

1995-06-01

Polzer et al.`s method combined with Bromley`s method for estimating activity coefficients and a Langmuir isotherm for cesium in a simple simulated waste solution containing 5.1 M NaNO{sub 3} and 0.6 M NaOH was used to estimate distribution coefficients for cesium in a complex simulated waste solution characteristic of the radioactive tank wastes at Hanford and other US Department of energy sites. The ion exchange material was a hydrous sodium crystalline silicotitanate, labeled TAM-5, which is being developed by Texas A and M University, Sandia National Laboratories, and UOP Associates. Cesium distribution coefficients collected by Bray et al. on amore » NCAW simulated waste solution were predicted with deviations of less than 25% for solutions containing 1 M, 3 M, and 5 M Na{sup +} and Na:Cs ratios of 10{sup 3}--10{sup 8}. The deviations were less than 5% for the solutions with 1 M Na{sup +}. Cesium distribution coefficients were also predicted and compared with values measured by Egan et al. for TAM-5 and for a storage tank supernate and a newly generated waste solution. Excellent results were obtained for the newly generated waste simulated solution, which did not contain potassium or rubidium.The predictions for the other simulated waste solution were significantly greater than the measured values, because of the presence of large concentrations of potassium or rubidium. The effect of competitive ion exchange between Cs, Rb, and K was not included in the theory. However, the effect of competitive ion exchange between Cs, Rb, and K was not included in the theory. However, the effect of competitive exchange of Cs, Rb, and K appears to be greater for the Oak Ridge simulated waste solution than for the NCAW waste.« less

Ultrasonic recovery of copper and iron through the simultaneous utilization of Printed Circuit Boards (PCB) spent acid etching solution and PCB waste sludge.

PubMed

Huang, Zhiyuan; Xie, Fengchun; Ma, Yang

2011-01-15

A method was developed to recover the copper and iron from Printed Circuit Boards (PCB) manufacturing generated spent acid etching solution and waste sludge with ultrasonic energy at laboratory scale. It demonstrated that copper-containing PCB spent etching solution could be utilized as a leaching solution to leach copper from copper contained PCB waste sludge. It also indicated that lime could be used as an alkaline precipitating agent in this method to precipitate iron from the mixture of acidic PCB spent etching solution and waste sludge. This method provided an effective technique for the recovery of copper and iron through simultaneous use of PCB spent acid solution and waste sludge. The leaching rates of copper and iron enhanced with ultrasound energy were reached at 93.76% and 2.07% respectively and effectively separated copper from iron. Followed by applying lime to precipitate copper from the mixture of leachate and rinsing water produced by the copper and iron separation, about 99.99% and 1.29% of soluble copper and calcium were settled as the solids respectively. Furthermore the settled copper could be made as commercial rate copper. The process performance parameters studied were pH, ultrasonic power, and temperature. This method provided a simple and reliable technique to recover copper and iron from waste streams generated by PCB manufacturing, and would significantly reduce the cost of chemicals used in the recovery. Copyright © 2010 Elsevier B.V. All rights reserved.

Process for recovery of palladium from nuclear fuel reprocessing wastes

DOEpatents

Campbell, D.O.; Buxton, S.R.

1980-06-16

Palladium is selectively removed from spent nuclear fuel reprocessing waste by adding sugar to a strong nitric acid solution of the waste to partially denitrate the solution and cause formation of an insoluble palladium compound. The process includes the steps of: (a) adjusting the nitric acid content of the starting solution to about 10 M; (b) adding 50% sucrose solution in an amount sufficient to effect the precipitation of the palladium compound; (c) heating the solution at reflux temperature until precipitation is complete; and (d) centrifuging the solution to separate the precipitated palladium compound from the supernatant liquid.

Process for recovery of palladium from nuclear fuel reprocessing wastes

DOEpatents

Campbell, David O.; Buxton, Samuel R.

1981-01-01

Palladium is selectively removed from spent nuclear fuel reprocessing waste by adding sugar to a strong nitric acid solution of the waste to partially denitrate the solution and cause formation of an insoluble palladium compound. The process includes the steps of: (a) adjusting the nitric acid content of the starting solution to about 10 M, (b) adding 50% sucrose solution in an amount sufficient to effect the precipitation of the palladium compound, (c) heating the solution at reflux temperature until precipitation is complete, and (d) centrifuging the solution to separate the precipitated palladium compound from the supernatant liquid.

Uranium fate in Hanford sediment altered by simulated acid waste solutions

DOE PAGES

Gartman, Brandy N.; Qafoku, Nikolla P.; Szecsody, James E.; ...

2015-07-31

Many aspects of U(VI) behavior in sediments that are previously exposed to acidic waste fluids for sufficiently long times to induce significant changes in pH and other physical, mineralogical and chemical properties, are not well documented in the literature. For this reason, we conducted a series of macroscopic batch experiments combined with a variety of bulk characterization studies (Mössbauer and laser spectroscopy), micro-scale inspections (µ-XRF), and molecular scale interrogations (XANES) with the objectives to: i) determine the extent of U(VI) partitioning to Hanford sediments previously exposed to acidic waste simulants (pH = 2 and pH = 5) and under neutralmore » conditions (pH = 8) at varying background solution concentrations (i.e., NaNO 3); ii) determine micron-scale solid phase associated U valence state and phase identity; and iii) provide information for a plausible conceptual model of U(VI) attenuation under waste plume acidic conditions. The results of the batch experiments showed that the acid pre-treated sediment had high affinity for aqueous U(VI), which was removed from solution via two pH dependent and apparently different mechanisms (adsorption at pH = 2 and precipitation at pH = 5). The micro-scale inspections and XANES analyses confirmed that high concentration areas were rich mainly in U(VI), demonstrating that most of the added U(VI) was not reduced to U(IV). The laser spectroscopy data showed that uranyl phosphates {e.g. metaautunite [Ca(UO 2) 2(PO 4) 2•10-12H 2O] and phosphuranylite [KCa(H 3O) 3(UO 2) 7(PO 4) 4O 4•8(H 2O)]} were present in the sediments. They also showed clear differences between the U bearing phases in the experiments conducted in the presence or absence of air. As a result, the data generated from these experiments will help in a better understanding of the reactions and processes that have a significant effect and/or control U mobility.« less

78 FR 8586 - PEPSICO, Inc., Business & Information Solutions (BIS) Division Including On-Site Leased Workers...

Federal Register 2010, 2011, 2012, 2013, 2014

2013-02-06

...., Business & Information Solutions (BIS) Division, including on-site leased workers of Cognizant Technology..., Inc., Business & Information Solutions (BIS) Division Including On-Site Leased Workers From Procurestaff, Cognizant, Infosys, Wipro, and TCS; Plano, TX; PEPSICO, Inc., Business & Information Solutions...

Process for removing sulfate anions from waste water

DOEpatents

Nilsen, David N.; Galvan, Gloria J.; Hundley, Gary L.; Wright, John B.

1997-01-01

A liquid emulsion membrane process for removing sulfate anions from waste water is disclosed. The liquid emulsion membrane process includes the steps of: (a) providing a liquid emulsion formed from an aqueous strip solution and an organic phase that contains an extractant capable of removing sulfate anions from waste water; (b) dispersing the liquid emulsion in globule form into a quantity of waste water containing sulfate anions to allow the organic phase in each globule of the emulsion to extract and absorb sulfate anions from the waste water and (c) separating the emulsion including its organic phase and absorbed sulfate anions from the waste water to provide waste water containing substantially no sulfate anions.

Fluorescent Lamp Glass Waste Incorporation into Clay Ceramic: A Perfect Solution

NASA Astrophysics Data System (ADS)

Morais, Alline Sardinha Cordeiro; Vieira, Carlos Maurício Fontes; Rodriguez, Rubén Jesus Sanchez; Monteiro, Sergio Neves; Candido, Veronica Scarpini; Ferreira, Carlos Luiz

2016-09-01

The mandatory use of fluorescent lamps as part of a Brazilian energy-saving program generates a huge number of spent fluorescent lamps (SFLs). After operational life, SFLs cannot be disposed as common garbage owing to mercury and lead contamination. Recycling methods separate contaminated glass tubes and promote cleaning for reuse. In this work, glass from decontaminated SFLs was incorporated into clay ceramics, not only as an environmental solution for such glass wastes and clay mining reduction but also due to technical and economical advantages. Up to 30 wt.% of incorporation, a significant improvement in fired ceramic flexural strength and a decrease in water absorption was observed. A prospective analysis showed clay ceramic incorporation as an environmentally correct and technical alternative for recycling the enormous amount of SFLs disposed of in Brazil. This could also be a solution for other world clay ceramic producers, such as US, China and some European countries.

Investigations regarding the wet decontamination of fluorescent lamp waste using iodine in potassium iodide solutions

DOE Office of Scientific and Technical Information (OSTI.GOV)

Tunsu, Cristian, E-mail: tunsu@chalmers.se; Ekberg, Christian; Foreman, Mark

Highlights: • A wet-based decontamination process for fluorescent lamp waste is proposed. • Mercury can be leached using iodine in potassium iodide solution. • The efficiency of the process increases with an increase in leachant concentration. • Selective leaching of mercury from rare earth elements is achieved. • Mercury is furthered recovered using ion exchange, reduction or solvent extraction. - Abstract: With the rising popularity of fluorescent lighting, simple and efficient methods for the decontamination of discarded lamps are needed. Due to their mercury content end-of-life fluorescent lamps are classified as hazardous waste, requiring special treatment for disposal. A simplemore » wet-based decontamination process is required, especially for streams where thermal desorption, a commonly used but energy demanding method, cannot be applied. In this study the potential of a wet-based process using iodine in potassium iodide solution was studied for the recovery of mercury from fluorescent lamp waste. The influence of the leaching agent’s concentration and solid/liquid ratio on the decontamination efficiency was investigated. The leaching behaviour of mercury was studied over time, as well as its recovery from the obtained leachates by means of anion exchange, reduction, and solvent extraction. Dissolution of more than 90% of the contained mercury was achieved using 0.025/0.05 M I{sub 2}/KI solution at 21 °C for two hours. The efficiency of the process increased with an increase in leachant concentration. 97.3 ± 0.6% of the mercury contained was dissolved at 21 °C, in two hours, using a 0.25/0.5 M I{sub 2}/KI solution and a solid to liquid ratio of 10% w/v. Iodine and mercury can be efficiently removed from the leachates using Dowex 1X8 anion exchange resin or reducing agents such as sodium hydrosulphite, allowing the disposal of the obtained solution as non-hazardous industrial wastewater. The extractant CyMe{sub 4}BTBP showed good removal of

New Engineering Solutions in Creation of Mini-BOF for Metallic Waste Recycling

NASA Astrophysics Data System (ADS)

Eronko, S. P.; Gorbatyuk, S. M.; Oshovskaya, E. V.; Starodubtsev, B. I.

2017-12-01

New engineering solutions used in design of the mini melting unit capable of recycling industrial and domestic metallic waste with high content of harmful impurities are provided. High efficiency of the process technology implemented with its use is achieved due to the possibility of the heat and mass transfer intensification in the molten metal bath, controlled charge into it of large amounts of reagents in lumps and in fines, and cut-off of remaining process slag during metal tapping into the teeming ladle.

Neural network hardware and software solutions for sorting of waste plastics for recycling

DOE Office of Scientific and Technical Information (OSTI.GOV)

Stanton, S.L.; Alam, M.K.; Hebner, G.A.

1992-12-31

While plastic recycling efforts have expanded during the past several years, the cost of recovering plastics is still a major impediment for recyclers. Several factors contribute to the prohibitive cost of recycled resins, including the present low marketability of products made with mixed recycled materials, and costs of collecting, sorting and reprocessing plastic materials. A method for automatic sorting of post-consumer plastics into pure polymer streams is needed to overcome the inaccuracies and low product throughput of the currently used method of hand sorting of waste plastics for recycling. The Society of Plastics has designated seven categories as recyclable: Polyethylenemore » terephthalate (PET); High Density Polyethylene (HDPE); Polyvinyl Chloride (PVC); Low Density Polyethylene (LDPE); Polypropylene (PP); Polystyrene (PS); and Other (mixtures, layered items, etc.). With these categories in mind, a system for sorting of waste plastics using near-infrared reflectance spectra and a backpropagation neural network classifier has been developed. A solution has been demonstrated in the laboratory using a high resolution, and relatively slow instrument. A faster instrument is being developed at this time. Neural network hardware options have been evaluated for use in a real-time industrial system. In the lab, a Fourier transform Near Infrared (FT-NIR) scanning spectrometer was used to gather reflectance data from various locations on samples of actual waste plastics. Neural networks were trained off-line with this data using the NeuralWorks Professional II Plus software package on a SparcStation 2. One of the successfully trained networks was used to compare the neural accelerator hardware options available. The results of running this ``worst case`` network on the neural network hardware will be presented. The AT&T ANNA chip and the Intel 80170NX chip development system were used to determine the ease of implementation and accuracies for this network.« less

Neural network hardware and software solutions for sorting of waste plastics for recycling

DOE Office of Scientific and Technical Information (OSTI.GOV)

Stanton, S.L.; Alam, M.K.; Hebner, G.A.

1992-01-01

While plastic recycling efforts have expanded during the past several years, the cost of recovering plastics is still a major impediment for recyclers. Several factors contribute to the prohibitive cost of recycled resins, including the present low marketability of products made with mixed recycled materials, and costs of collecting, sorting and reprocessing plastic materials. A method for automatic sorting of post-consumer plastics into pure polymer streams is needed to overcome the inaccuracies and low product throughput of the currently used method of hand sorting of waste plastics for recycling. The Society of Plastics has designated seven categories as recyclable: Polyethylenemore » terephthalate (PET); High Density Polyethylene (HDPE); Polyvinyl Chloride (PVC); Low Density Polyethylene (LDPE); Polypropylene (PP); Polystyrene (PS); and Other (mixtures, layered items, etc.). With these categories in mind, a system for sorting of waste plastics using near-infrared reflectance spectra and a backpropagation neural network classifier has been developed. A solution has been demonstrated in the laboratory using a high resolution, and relatively slow instrument. A faster instrument is being developed at this time. Neural network hardware options have been evaluated for use in a real-time industrial system. In the lab, a Fourier transform Near Infrared (FT-NIR) scanning spectrometer was used to gather reflectance data from various locations on samples of actual waste plastics. Neural networks were trained off-line with this data using the NeuralWorks Professional II Plus software package on a SparcStation 2. One of the successfully trained networks was used to compare the neural accelerator hardware options available. The results of running this worst case'' network on the neural network hardware will be presented. The AT T ANNA chip and the Intel 80170NX chip development system were used to determine the ease of implementation and accuracies for this network.« less

40 CFR 60.2065 - What should I include in my waste management plan?

Code of Federal Regulations, 2010 CFR

2010-07-01

... include consideration of the reduction or separation of waste-stream elements such as paper, cardboard, plastics, glass, batteries, or metals; or the use of recyclable materials. The plan must identify any..., the emissions reductions expected to be achieved, and any other environmental or energy impacts they...

40 CFR 60.2901 - What should I include in my waste management plan?

Code of Federal Regulations, 2010 CFR

2010-07-01

... management plan must include consideration of the reduction or separation of waste-stream elements such as paper, cardboard, plastics, glass, batteries, or metals; or the use of recyclable materials. The plan... place, the costs of additional measures, the emissions reductions expected to be achieved, and any other...

Removal of Pb(II) ions from aqueous solution by a waste mud from copper mine industry: equilibrium, kinetic and thermodynamic study.

PubMed

Ozdes, Duygu; Gundogdu, Ali; Kemer, Baris; Duran, Celal; Senturk, Hasan Basri; Soylak, Mustafa

2009-07-30

The objective of this study was to assess the adsorption potential of a waste mud (WM) for the removal of lead (Pb(II)) ions from aqueous solutions. The WM was activated with NaOH in order to increase its adsorption capacity. Adsorption studies were conducted in a batch system as a function of solution pH, contact time, initial Pb(II) concentration, activated-waste mud (a-WM) concentration, temperature, etc. Optimum pH was specified as 4.0. The adsorption kinetic studies indicated that the overall adsorption process was best described by pseudo-second-order kinetics. The equilibrium adsorption capacity of a-WM was obtained by using Langmuir and Freundlich isotherm models and both models fitted well. Adsorption capacity for Pb(II) was found to be 24.4 mg g(-1) for 10 g L(-1) of a-WM concentration. Thermodynamic parameters including the Gibbs free energy (Delta G degrees), enthalpy (Delta H degrees), and entropy (DeltaS degrees) indicated that the adsorption of Pb(II) ions on the a-WM was feasible, spontaneous and endothermic, at temperature range of 0-40 degrees C. Desorption studies were carried out successfully with diluted HCl solutions. The results indicate that a-WM can be used as an effective and no-cost adsorbent for the treatment of industrial wastewaters contaminated with Pb(II) ions.

76 FR 81986 - Honeywell International, Inc., Automation and Control Solutions Division, Including On-Site...

Federal Register 2010, 2011, 2012, 2013, 2014

2011-12-29

..., Inc., Automation and Control Solutions Division, Including On-Site Leased Workers From Manpower... International, Inc., Automation and Control Solutions Division, Rock Island, Illinois. The notice was published...., Automation and Control Solutions Division. The Department has determined that these workers were sufficiently...

40 CFR 60.3012 - What should I include in my waste management plan?

Code of Federal Regulations, 2012 CFR

2012-07-01

... 40 Protection of Environment 7 2012-07-01 2012-07-01 false What should I include in my waste management plan? 60.3012 Section 60.3012 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED... such as paper, cardboard, plastics, glass, batteries, or metals; or the use of recyclable materials...

40 CFR 60.3012 - What should I include in my waste management plan?

Code of Federal Regulations, 2014 CFR

2014-07-01

... 40 Protection of Environment 7 2014-07-01 2014-07-01 false What should I include in my waste management plan? 60.3012 Section 60.3012 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED... such as paper, cardboard, plastics, glass, batteries, or metals; or the use of recyclable materials...

40 CFR 60.2065 - What should I include in my waste management plan?

Code of Federal Regulations, 2011 CFR

2011-07-01

... 40 Protection of Environment 6 2011-07-01 2011-07-01 false What should I include in my waste management plan? 60.2065 Section 60.2065 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED..., plastics, glass, batteries, or metals; or the use of recyclable materials. The plan must identify any...

40 CFR 60.3012 - What should I include in my waste management plan?

Code of Federal Regulations, 2013 CFR

2013-07-01

... 40 Protection of Environment 7 2013-07-01 2013-07-01 false What should I include in my waste management plan? 60.3012 Section 60.3012 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED... such as paper, cardboard, plastics, glass, batteries, or metals; or the use of recyclable materials...

40 CFR 60.2065 - What should I include in my waste management plan?

Code of Federal Regulations, 2012 CFR

2012-07-01

... 40 Protection of Environment 7 2012-07-01 2012-07-01 false What should I include in my waste management plan? 60.2065 Section 60.2065 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED..., plastics, glass, batteries, or metals; or the use of recyclable materials. The plan must identify any...

40 CFR 60.3012 - What should I include in my waste management plan?

Code of Federal Regulations, 2011 CFR

2011-07-01

... 40 Protection of Environment 6 2011-07-01 2011-07-01 false What should I include in my waste management plan? 60.3012 Section 60.3012 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED... such as paper, cardboard, plastics, glass, batteries, or metals; or the use of recyclable materials...

40 CFR 60.2901 - What should I include in my waste management plan?

Code of Federal Regulations, 2011 CFR

2011-07-01

... 40 Protection of Environment 6 2011-07-01 2011-07-01 false What should I include in my waste management plan? 60.2901 Section 60.2901 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED... paper, cardboard, plastics, glass, batteries, or metals; or the use of recyclable materials. The plan...

40 CFR 60.2901 - What should I include in my waste management plan?

Code of Federal Regulations, 2012 CFR

2012-07-01

... 40 Protection of Environment 7 2012-07-01 2012-07-01 false What should I include in my waste management plan? 60.2901 Section 60.2901 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED... paper, cardboard, plastics, glass, batteries, or metals; or the use of recyclable materials. The plan...

78 FR 19530 - Eastman Kodak Company (GCG), Electrographic Print Solutions, Including On-Site Leased Workers...

Federal Register 2010, 2011, 2012, 2013, 2014

2013-04-01

... Kodak Company (GCG), Electrographic Print Solutions, Including On-Site Leased Workers From Adecco and Datrose, Spencerport, New York; Eastman Kodak Company, IPS, Including On-Site Leased Workers From Adecco..., 2011, applicable to workers of Eastman Kodak Company (GCG), Electrographic Print Solutions, including...

CO2 and O2 Gas Exchange in an Experimental Model of the Btlss with Plant Wastes and Human Wastes Included in the Mass Exchange

NASA Astrophysics Data System (ADS)

Ushakova, Sofya; Tikhomirov, Alexander A.; Velichko, Vladimir; Tikhomirova, Natalia; Trifonov, Sergey V.

2016-07-01

Mass exchange processes in the new experimental model of the biotechnical life support system (BTLSS) constructed at the Institute of Biophysics SB RAS have a higher degree of closure than in the previous BTLSS, and, thus, the technologies employed in the new system are more complex. Therefore, before closing the loops of mass exchange processes for several months, the new model of the BTLSS was run to match the technologies employed to cultivate plants and the methods used to involve inedible plant parts and human wastes into the mass exchange with the CO2 absorption rate and the amount of the resulting O2. The plant compartment included vegetables grown on the soil-like substrate (SLS) (chufa, beet, carrot, radish, and lettuce), plants hydroponically grown on expanded clay aggregate (wheat, soybean, watercress), and plants grown in aquaculture (common glasswort and watercress). Nutrient solutions for hydroponically grown plants were prepared by using products of physicochemical mineralization of human wastes. Growing the plants in aquaculture enabled maintaining NaCl concentration in the irrigation solution for hydroponically grown plants at a level safe for the plants. Inedible plant biomass was added to the SLS. Three cycles of closing the system were run, which lasted 7, 7, and 10 days. The comparison of the amount of CO2 fed into the system over 24 h (simulating human respiration) and the amount of CO2 daily exhaled by a 70-kg middle-aged human showed that between 1% and 4% of the daily emissions of CO2 were assimilated in the system, and about 3% of the average human daily O2 requirement accumulated in the system. Plant productivity was between 4 and 4.7% of the human daily vegetable requirement, or between 3 and 3.5% of the total human daily food requirement. Thus, testing of the BTLSS showed a match between the technologies employed to arrange mass exchange processes. This study was supported by the grant of the Russian Science Foundation (Project No. 14-14-00599).

WASTE TIRES ON THE ISLAND OF DOMINICA: SURVEY AND SOLUTIONS

EPA Science Inventory

Phase I of LFL-Dominica was highly successful, resulting in a completed national tire inventory and Material Flow Analysis, a waste tire feasibility study, expansion of the project to include organic gardens, identification and screening of three sites for potential LFL implem...

Recovery of copper and cyanide from waste cyanide solutions using emulsion liquid membrane with LIX 7950 as the carrier.

PubMed

Xie, Feng; Wang, Wei

2017-08-01

The feasibility of using emulsion liquid membranes (ELMs) with the guanidine extractant LIX 7950 as the mobile carrier for detoxifying copper-containing waste cyanide solutions has been determined. Relatively stable ELMs can be maintained under suitable stirring speed during mixing ELMs and the external solution. Effective extraction of copper cyanides by ELMs only occurs at pH below 11. High copper concentration in the external phase and high volume ratio of the external phase to ELMs result in high transport rates of copper and cyanide. High molar ratio of cyanide to copper tends to suppress copper extraction. The presence of thiocyanate ion significantly depresses the transport of copper and cyanide through the membrane while the thiosulfate ion produces less impact on copper removal by ELMs. Zinc and nickel cyanides can also be effectively extracted by ELMs. More than 90% copper and cyanide can be effectively removed from alkaline cyanide solutions by ELMs under suitable experimental conditions, indicating the effectiveness of using the designed ELM for recovering copper and cyanide from waste cyanide solutions.

Time-marching transonic flutter solutions including angle-of-attack effects

NASA Technical Reports Server (NTRS)

Edwards, J. W.; Bennett, R. M.; Whitlow, W., Jr.; Seidel, D. A.

1982-01-01

Transonic aeroelastic solutions based upon the transonic small perturbation potential equation were studied. Time-marching transient solutions of plunging and pitching airfoils were analyzed using a complex exponential modal identification technique, and seven alternative integration techniques for the structural equations were evaluated. The HYTRAN2 code was used to determine transonic flutter boundaries versus Mach number and angle-of-attack for NACA 64A010 and MBB A-3 airfoils. In the code, a monotone differencing method, which eliminates leading edge expansion shocks, is used to solve the potential equation. When the effect of static pitching moment upon the angle-of-attack is included, the MBB A-3 airfoil can have multiple flutter speeds at a given Mach number.

Hydrogen Production in Radioactive Solutions in the Defense Waste Processing Facility

DOE Office of Scientific and Technical Information (OSTI.GOV)

CRAWFORD, CHARLES L.

2004-05-26

In the radioactive slurries and solutions to be processed in the Defense Waste Processing Facility (DWPF), hydrogen will be produced continuously by radiolysis. This production results from alpha, beta, and gamma rays from decay of radionuclides in the slurries and solutions interacting with the water. More than 1000 research reports have published data concerning this radiolytic production. The results of these studies have been reviewed in a comprehensive monograph. Information about radiolytic hydrogen production from the different process tanks is necessary to determine air purge rates necessary to prevent flammable mixtures from accumulating in the vapor spaces above these tanks.more » Radiolytic hydrogen production rates are usually presented in terms of G values or molecules of hydrogen produced per 100ev of radioactive decay energy absorbed by the slurry or solution. With the G value for hydrogen production, G(H2), for a particular slurry and the concentrations of radioactive species in that slurry, the rate of H2 production for that slurry can be calculated. An earlier investigation estimated that the maximum rate that hydrogen could be produced from the sludge slurry stream to the DWPF is with a G value of 0.45 molecules per 100ev of radioactive decay energy sorbed by the slurry.« less

Activated bauxite waste as an adsorbent for removal of Acid Blue 92 from aqueous solutions.

PubMed

Norouzi, Sh; Badii, Kh; Doulati Ardejani, F

2010-01-01

Bauxite waste, known as red mud, is produced in some industrial processes, such as aluminum production process. In this process, the waste material is produced from leached bauxite as a by product. In this research, the removal of Acid Blue 92 (AB92) dye was investigated from aqueous solution onto the activated bauxite waste (red mud) in a batch equilibration system. Besides, the influences of pH, adsorbent dosage, contact time, initial concentration of dye and temperature have been considered. It was found that the OH group is an effective functional group for the adsorption process. The intensity of the peaks correspond to OH group has been significantly climbed after the activation process. The adsorption kinetics of AB92 can be well described by the pseudo-second-order reaction model. Based on the isotherm data obtained from the fittings of the adsorption kinetics, the Langmuir model appears to fit the adsorption process better than the Freundlich and Brunauer-Emmett-Teller (BET) models.

Adsorption of Ag (I) from aqueous solution by waste yeast: kinetic, equilibrium and mechanism studies.

PubMed

Zhao, Yufeng; Wang, Dongfang; Xie, Hezhen; Won, Sung Wook; Cui, Longzhe; Wu, Guiping

2015-01-01

One type of biosorbents, brewer fermentation industry waste yeast, was developed to adsorb the Ag (I) in aqueous solution. The result of FTIR analysis of waste yeast indicated that the ion exchange, chelating and reduction were the main binding mechanisms between the silver ions and the binding sites on the surface of the biomass. Furthermore, TEM, XRD and XPS results suggested that Ag(0) nanoparticles were deposited on the surface of yeast. The kinetic experiments revealed that sorption equilibrium could reach within 60 min, and the removal efficiency of Ag (I) could be still over 93 % when the initial concentration of Ag (I) was below 100 mg/L. Thermodynamic parameters of the adsorption process (ΔG, ΔH and ΔS) identified that the adsorption was a spontaneous and exothermic process. The waste yeast, playing a significant role in the adsorption of the silver ions, is useful to fast adsorb Ag (I) from low concentration.

Kinetic modelling of anaerobic hydrolysis of solid wastes, including disintegration processes

DOE Office of Scientific and Technical Information (OSTI.GOV)

García-Gen, Santiago; Sousbie, Philippe; Rangaraj, Ganesh

2015-01-15

Highlights: • Fractionation of solid wastes into readily and slowly biodegradable fractions. • Kinetic coefficients estimation from mono-digestion batch assays. • Validation of kinetic coefficients with a co-digestion continuous experiment. • Simulation of batch and continuous experiments with an ADM1-based model. - Abstract: A methodology to estimate disintegration and hydrolysis kinetic parameters of solid wastes and validate an ADM1-based anaerobic co-digestion model is presented. Kinetic parameters of the model were calibrated from batch reactor experiments treating individually fruit and vegetable wastes (among other residues) following a new protocol for batch tests. In addition, decoupled disintegration kinetics for readily and slowlymore » biodegradable fractions of solid wastes was considered. Calibrated parameters from batch assays of individual substrates were used to validate the model for a semi-continuous co-digestion operation treating simultaneously 5 fruit and vegetable wastes. The semi-continuous experiment was carried out in a lab-scale CSTR reactor for 15 weeks at organic loading rate ranging between 2.0 and 4.7 g VS/L d. The model (built in Matlab/Simulink) fit to a large extent the experimental results in both batch and semi-continuous mode and served as a powerful tool to simulate the digestion or co-digestion of solid wastes.« less

Method for aqueous radioactive waste treatment

DOEpatents

Bray, Lane A.; Burger, Leland L.

1994-01-01

Plutonium, strontium, and cesium found in aqueous waste solutions resulting from nuclear fuel processing are removed by contacting the waste solutions with synthetic zeolite incorporating up to about 5 wt % titanium as sodium titanate in an ion exchange system. More than 99.9% of the plutonium, strontium, and cesium are removed from the waste solutions.

Interpretation of leaching data for cementitious waste forms using analytical solutions based on mass transport theory and empiricism

DOE Office of Scientific and Technical Information (OSTI.GOV)

Spence, R.D.; Godbee, H.W.; Tallent, O.K.

1989-01-01

The analysis of leaching data using analytical solutions based on mass transport theory and empiricism is presented. The waste forms leached to generate the data used in this analysis were prepared with a simulated radioactive waste slurry with traces of potassium ion, manganese ions, carbonate ions, phosphate ions, and sulfate ions solidified with several blends of cementitious materials. Diffusion coefficients were estimated from the results of ANS - 16.1 tests. Data of fraction leached versus time is presented and discussed.

Thermoelastic analysis of spent fuel and high level radioactive waste repositories in salt. A semi-analytical solution. [JUDITH

DOE Office of Scientific and Technical Information (OSTI.GOV)

St. John, C.M.

1977-04-01

An underground repository containing heat generating, High Level Waste or Spent Unreprocessed Fuel may be approximated as a finite number of heat sources distributed across the plane of the repository. The resulting temperature, displacement and stress changes may be calculated using analytical solutions, providing linear thermoelasticity is assumed. This report documents a computer program based on this approach and gives results that form the basis for a comparison between the effects of disposing of High Level Waste and Spent Unreprocessed Fuel.

78 FR 25304 - Siemens Medical Solutions, USA, Inc., Oncology Care Systems (Radiation Oncology), Including On...

Federal Register 2010, 2011, 2012, 2013, 2014

2013-04-30

..., USA, Inc., Oncology Care Systems (Radiation Oncology), Including On-Site Leased Workers From Source... Medical Solutions, USA, Inc., Oncology Care Systems (Radiation Oncology), including on- site leased... of February 2013, Siemens Medical Solutions, USA, Inc., Oncology Care Systems (Radiation Oncology...

Method for aqueous radioactive waste treatment

DOEpatents

Bray, L.A.; Burger, L.L.

1994-03-29

Plutonium, strontium, and cesium found in aqueous waste solutions resulting from nuclear fuel processing are removed by contacting the waste solutions with synthetic zeolite incorporating up to about 5 wt % titanium as sodium titanate in an ion exchange system. More than 99.9% of the plutonium, strontium, and cesium are removed from the waste solutions. 3 figures.

Evaluation and Analysis of Solid Waste at ISF Academy

NASA Astrophysics Data System (ADS)

Ma, D. W. J.

2017-12-01

Waste management is one of the biggest environmental problems in Hong Kong. According to a report from the HK government, in less than 3 years, which is 2020, all the local landfills will be filled with trash. Therefore, ISF Academy, a school in HK with 1800 students, is planning to reduce their solid waste on campus by evaluating and analysing all solid wastes, which can assist professionals to reform and innovate solutions for refuse disposal. Meanwhile, this project is designed for both raising students' awareness of the magnitude of waste and figuring out measures for waste reduction. For one thing, the project includes the promotion of Waste Audit to reach the former purpose by teaching students how to sort waste. In addition, the weight of each type of waste will be recorded as reference data for students to learn about varied degrees of quantities among different kinds of garbage and relate data to impacts brought by waste with diverse characteristics on the environment. For another, the researcher involved in this project will carry out solutions corresponding to various sorts of waste by applying scientific knowledge, carrying out surveys, organizing campaigns etc.

75 FR 34169 - Hewlett-Packard Company, Inkjet Consumer Solutions, HP Consumer Hardware Inkjet Lab, Including...

Federal Register 2010, 2011, 2012, 2013, 2014

2010-06-16

..., Inkjet Consumer Solutions, HP Consumer Hardware Inkjet Lab, Including Leased Workers From Hightower..., applicable to all workers of Hewlett-Packard Company, Inkjet Consumer Solutions, HP Consumer Hardware Inkjet... the Department's certification is to include all workers employed at Hewlett Packard Company, Inkjet...

75 FR 22846 - Norgren Automation Solutions, Including Workers Whose Unemployment Insurance (UI) Wages Are Paid...

Federal Register 2010, 2011, 2012, 2013, 2014

2010-04-30

... Solutions, Including Workers Whose Unemployment Insurance (UI) Wages Are Paid Through Syron Engineering Erie... from employment at the subject firm had their wages reported under a separated unemployment insurance... of Norgren Automation Solutions, including workers whose unemployment insurance (UI) wages are paid...

Kinetic modelling of anaerobic hydrolysis of solid wastes, including disintegration processes.

PubMed

García-Gen, Santiago; Sousbie, Philippe; Rangaraj, Ganesh; Lema, Juan M; Rodríguez, Jorge; Steyer, Jean-Philippe; Torrijos, Michel

2015-01-01

A methodology to estimate disintegration and hydrolysis kinetic parameters of solid wastes and validate an ADM1-based anaerobic co-digestion model is presented. Kinetic parameters of the model were calibrated from batch reactor experiments treating individually fruit and vegetable wastes (among other residues) following a new protocol for batch tests. In addition, decoupled disintegration kinetics for readily and slowly biodegradable fractions of solid wastes was considered. Calibrated parameters from batch assays of individual substrates were used to validate the model for a semi-continuous co-digestion operation treating simultaneously 5 fruit and vegetable wastes. The semi-continuous experiment was carried out in a lab-scale CSTR reactor for 15 weeks at organic loading rate ranging between 2.0 and 4.7 gVS/Ld. The model (built in Matlab/Simulink) fit to a large extent the experimental results in both batch and semi-continuous mode and served as a powerful tool to simulate the digestion or co-digestion of solid wastes. Copyright © 2014 Elsevier Ltd. All rights reserved.

Removal of Remazol turquoise Blue G-133 from aqueous solution using modified waste newspaper fiber.

PubMed

Zhang, Xiaoyu; Tan, Jia; Wei, Xinhao; Wang, Lijuan

2013-02-15

Waste newspaper fiber (WNF) was separated and modified via grafting quaternary ammonium salt to obtain an adsorbent, which removes Remazol turquoise Blue G-133 (RTB G-133) from aqueous solutions. SEM and IR were used to analyze the morphology and chemical groups of the modified waste newspaper fiber (MWNF). Batch adsorption studies were conducted with varying adsorbent dosages, solution pH, and contact time. Adsorption isotherms and models were fitted. The SEM photographs show the surface of MWNF is smoother in comparison with that of WNF. The IR analysis indicates that the quaternary ammonium salt was successfully grafted onto the cellulose skeleton in WNF and the chemical interaction played an important role in adsorption. Results show that the equilibrium adsorption capacity can be reached within 360 min, and that the maximum adsorption capacity was 260 mg g(-1). The adsorption of RTB G-133 on MWNF was a spontaneous endothermic process and well fitted pseudo-second-order kinetic model and Langmuir adsorption isotherm model. The results show that MWNF is promising for dye wastewater treatment. Crown Copyright © 2012. Published by Elsevier Ltd. All rights reserved.

Structure and dynamics of water in mixed solutions including laponite and PEO

NASA Astrophysics Data System (ADS)

Morikubo, Satoshi; Sekine, Yurina; Ikeda-Fukazawa, Tomoko

2011-01-01

To investigate the structure and dynamics of water in mixed solutions including laponite clay particles and poly(ethylene oxide) (PEO), we measured the Raman spectra of the mixed solutions in the temperature range 283-313 K. The results show that the vibrational energies of the O-H stretching modes in the mixed solutions depend on the water content and temperature. The energy shifts of the O-H stretching modes are attributed to changes in the water structure. By applying a structural model of bulk water to the spectra in the O-H stretching region, the local structures of water in the solutions were analyzed. The result shows that the formation probability of hydrogen bonds in the solutions decreases as the water content decreases. Laponite and PEO have effects to disrupt the network structure of hydrogen bonds between water molecules. Further, it was found that laponite and PEO cause increase in the strength of hydrogen bonds of surrounding water,although the strength of the hydrogen bonds increases with the order water-laponite < water-water < water-PEO. It is concluded that water in laponite-PEO mixed solutions has a less-networked structure with strong hydrogen bonds compared with bulk water.

Liquid secondary waste: Waste form formulation and qualification

DOE Office of Scientific and Technical Information (OSTI.GOV)

Cozzi, A. D.; Dixon, K. L.; Hill, K. A.

The Hanford Site Effluent Treatment Facility (ETF) currently treats aqueous waste streams generated during site cleanup activities. When the Hanford Tank Waste Treatment and Immobilization Plant (WTP) begins operations, including Direct Feed Low Activity Waste (DFLAW) vitrification, a liquid secondary waste (LSW) stream from the WTP will need to be treated. The volume of effluent for treatment at the ETF will increase significantly. The powdered salt waste form produced by the ETF will be replaced by a stabilized solidified waste form for disposal in Hanford’s Integrated Disposal Facility (IDF). Washington River Protection Solutions is implementing a Secondary Liquid Waste Immobilizationmore » Technology Development Plan to address the technology needs for a waste form and solidification process to treat the increased volume of waste planned for disposal at the IDF. Waste form testing to support this plan is composed of work in the near term to provide data as input to a performance assessment (PA) for Hanford’s IDF. In 2015, three Hanford Liquid Secondary Waste simulants were developed based on existing and projected waste streams. Using these waste simulants, fourteen mixes of Hanford Liquid Secondary Waste were prepared and tested varying the waste simulant, the water-to-dry materials ratio, and the dry materials blend composition.1 In FY16, testing was performed using a simulant of the EMF process condensate blended with the caustic scrubber—from the Low Activity Waste (LAW) melter—, processed through the ETF. The initial EMF-16 simulant will be based on modeling efforts performed to determine the mass balance of the ETF for the DFLAW.2 The compressive strength of all of the mixes exceeded the target of 3.4 MPa (500 psi) to meet the requirements identified as potential IDF Waste Acceptance Criteria in Table 1 of the Secondary Liquid Waste Immobilization Technology Development Plan.3 The hydraulic properties of the waste forms tested (hydraulic

Mechanical and Physical Performance of Concrete Including Waste Electrical Cable Rubber

NASA Astrophysics Data System (ADS)

Taner Yildirim, Salih; Pelin Duygun, Nur

2017-10-01

Solid wastes are important environmental problem all over the World. Consumption of the plastic solid waste covers big portion within the total solid waste. Although a numerous plastic material is subjected to the recycling process, it is not easy to be destroyed by nature. One of the recommended way to prevent is to utilize as an aggregate in cement-based material. There are many researches on use of recycling rubber in concrete. However, studies on recycling of waste electrical cable rubber (WECR) in concrete is insufficient although there are many research on waste tyre rubbers in concrete. In this study, fine aggregate was replaced with WECR which were 5%, 10%, and 15 % of the total aggregate volume in the concrete and researched workability, unit weight, water absorption, compressive strength, flexural strength, ultrasonic pulse velocity, modulus of elasticity, and abrasion resistance of concrete. As a result of experimental studies, increase of WECR amount in concrete increases workability due to lack of adherence between cement paste and WECR, and hydrophobic structure of WECR while it influences negatively mechanical properties of concrete. It is possible to use WECR in concrete taking into account the reduction in mechanical properties.

Use of cellulose-based wastes for adsorption of dyes from aqueous solutions.

PubMed

Annadurai, Gurusamy; Juang, Ruey-Shin; Lee, Duu-Jong

2002-06-10

Low-cost banana and orange peels were prepared as adsorbents for the adsorption of dyes from aqueous solutions. Dye concentration and pH were varied. The adsorption capacities for both peels decreased in the order methyl orange (MO) > methylene blue (MB) > Rhodamine B (RB) > Congo red (CR) > methyl violet (MV) > amido black 10B (AB). The isotherm data could be well described by the Freundlich and Langmuir equations in the concentration range of 10-120 mg/l. An alkaline pH was favorable for the adsorption of dyes. Based on the adsorption capacity, it was shown that banana peel was more effective than orange peel. Kinetic parameters of adsorption such as the Langergren rate constant and the intraparticle diffusion rate constant were determined. For the present adsorption process intraparticle diffusion of dyes within the particle was identified to be rate limiting. Both peel wastes were shown to be promising materials for adsorption removal of dyes from aqueous solutions.

Codigestion of solid wastes: a review of its uses and perspectives including modeling.

PubMed

Mata-Alvarez, Joan; Dosta, Joan; Macé, Sandra; Astals, Sergi

2011-06-01

The last two years have witnessed a dramatic increase in the number of papers published on the subject of codigestion, highlighting the relevance of this topic within anaerobic digestion research. Consequently, it seems appropriate to undertake a review of codigestion practices starting from the late 1970s, when the first papers related to this concept were published, and continuing to the present day, demonstrating the exponential growth in the interest shown in this approach in recent years. Following a general analysis of the situation, state-of-the-art codigestion is described, focusing on the two most important areas as regards publication: codigestion involving sewage sludge and the organic fraction of municipal solid waste (including a review of the secondary advantages for wastewater treatment plant related to biological nutrient removal), and codigestion in the agricultural sector, that is, including agricultural - farm wastes, and energy crops. Within these areas, a large number of oversized digesters appear which can be used to codigest other substrates, resulting in economic and environmental advantages. Although the situation may be changing, there is still a need for good examples on an industrial scale, particularly with regard to wastewater treatment plants, in order to extend this beneficial practice. In the last section, a detailed analysis of papers addressing the important aspect of modelisation is included. This analysis includes the first codigestion models to be developed as well as recent applications of the standardised anaerobic digestion model ADM1 to codigestion. (This review includes studies ranging from laboratory to industrial scale.).

75 FR 77664 - Honeywell International, Inc., Automation and Control Solutions Division, Including On-Site...

Federal Register 2010, 2011, 2012, 2013, 2014

2010-12-13

..., Inc., Automation and Control Solutions Division, Including On-Site Leased Workers From Manpower...., Automation and Control Solutions Division, Rock Island, Illinois. The notice was published in the Federal...-site at the Rock Island, Illinois location of Honeywell International, Inc., Automation and Control...

Persimmon leaf bio-waste for adsorptive removal of heavy metals from aqueous solution.

PubMed

Lee, Seo-Yun; Choi, Hee-Jeong

2018-03-01

The aim of this study was to investigate heavy metal removal using waste biomass adsorbent, persimmon leaves, in an aqueous solution. Persimmon leaves, which are biomaterials, have a large number of hydroxyl groups and are highly suitable for removal of heavy metals. Therefore, in this study, we investigated the possibility of removal of Cu, Pb, and Cd in aqueous solution by using raw persimmon leaves (RPL) and dried persimmon leaves (DPL). Removal of heavy metals by RPL and DPL showed that DPL had a 10%-15% higher removal than RPL, and the order of removal efficiency was found to be Pb > Cu > Cd. The pseudo-second order model was a better fit to the heavy metal adsorption experiments using RPL and DPL than the pseudo-first order model. The adsorption of Cu, Pb, and Cd by DPL was more suitable with the Freundlich isothermal adsorption and showed an ion exchange reaction which occurred in the uneven adsorption surface layer. The maximum adsorption capacity of Cu, Pb, and Cd was determined to be 19.42 mg/g, 22.59 mg/g, and 18.26 mg/g, respectively. The result of the adsorption experiments showed that the n value was higher than 2 regardless of the dose, indicating that the heavy metal adsorption on DPL was easy. In the thermodynamic experiment, ΔG° was a negative value, and ΔH° and ΔS° were positive values. It can be seen that the heavy metal adsorption process using DPL was spontaneous in nature and was an endothermic process. Moreover, as the temperature increased, the adsorption increased, and the affinity of heavy metal adsorption to DPL was very good. This experiment, in which heavy metals are removed using the waste biomass of persimmon leaves is an eco-friendly new bioadsorbent method because it can remove heavy metals without using chemicals while utilizing waste recycling. Copyright © 2018 Elsevier Ltd. All rights reserved.

Radioactive waste disposal in the marine environment

NASA Astrophysics Data System (ADS)

Anderson, D. R.

In order to find the optimal solution to waste disposal problems, it is necessary to make comparisons between disposal media. It has become obvious to many within the scientific community that the single medium approach leads to over protection of one medium at the expense of the others. Cross media comparisons are being conducted in the Department of Energy ocean disposal programs for several radioactive wastes. Investigations in three areas address model development, comparisons of laboratory tests with field results and predictions, and research needs in marine disposal of radioactive waste. Tabulated data are included on composition of liquid high level waste and concentration of some natural radionuclides in the sea.

Production of furfural from waste aqueous hemicellulose solution of hardwood over ZSM-5 zeolite.

PubMed

Gao, Hongling; Liu, Haitang; Pang, Bo; Yu, Guang; Du, Jian; Zhang, Yuedong; Wang, Haisong; Mu, Xindong

2014-11-01

This study aimed to produce furfural from waste aqueous hemicellulose solution of a hardwood kraft-based dissolving pulp production processing in a green method. The maximum furfural yield of 82.4% and the xylose conversion of 96.8% were achieved at 463K, 1.0g ZSM-5, 1.05g NaCl and organic solvent-to-aqueous phase ratio of 30:15 (V/V) for 3h. The furfural yield was just 51.5% when the same concentration of pure xylose solution was used. Under the optimized condition, furfural yield was still up to 67.1% even after the fifth reused of catalyst. Catalyst recycling study showed that ZSM-5 has a certain stability and can be efficiently reused. Copyright © 2014 Elsevier Ltd. All rights reserved.

Process Waste Assessment Machine and Fabrication Shop

DOE Office of Scientific and Technical Information (OSTI.GOV)

Phillips, N.M.

1993-03-01

This Process Waste Assessment was conducted to evaluate hazardous wastes generated in the Machine and Fabrication Shop at Sandia National Laboratories, Bonding 913, Room 119. Spent machine coolant is the major hazardous chemical waste generated in this facility. The volume of spent coolant generated is approximately 150 gallons/month. It is sent off-site to a recycler, but a reclaiming system for on-site use is being investigated. The Shop`s line management considers hazardous waste minimization very important. A number of steps have already been taken to minimize wastes, including replacement of a hazardous solvent with biodegradable, non-caustic solution and filtration unit; wastemore » segregation; restriction of beryllium-copper alloy machining; and reduction of lead usage.« less

"Control-alt-delete": rebooting solutions for the E-waste problem.

PubMed

Li, Jinhui; Zeng, Xianlai; Chen, Mengjun; Ogunseitan, Oladele A; Stevels, Ab

2015-06-16

A number of efforts have been launched to solve the global electronic waste (e-waste) problem. The efficiency of e-waste recycling is subject to variable national legislation, technical capacity, consumer participation, and even detoxification. E-waste management activities result in procedural irregularities and risk disparities across national boundaries. We review these variables to reveal opportunities for research and policy to reduce the risks from accumulating e-waste and ineffective recycling. Full regulation and consumer participation should be controlled and reinforced to improve local e-waste system. Aiming at standardizing best practice, we alter and identify modular recycling process and infrastructure in eco-industrial parks that will be expectantly effective in countries and regions to handle the similar e-waste stream. Toxicity can be deleted through material substitution and detoxification during the life cycle of electronics. Based on the idea of "Control-Alt-Delete", four patterns of the way forward for global e-waste recycling are proposed to meet a variety of local situations.

78 FR 15049 - The Evercare Company Including On-Site Leased Workers From Global Personnel Solutions and...

Federal Register 2010, 2011, 2012, 2013, 2014

2013-03-08

... DEPARTMENT OF LABOR Employment and Training Administration [TA-W-81,932] The Evercare Company Including On-Site Leased Workers From Global Personnel Solutions and Manpower Waynesboro, Georgia; Amended... group included on-site leased workers from Global Personnel Solutions. In response to an inquiry by the...

Optimization of municipal solid waste management in Port Said - Egypt

DOE Office of Scientific and Technical Information (OSTI.GOV)

Badran, M.F.; El-Haggar, S.M.

2006-07-01

Optimization of solid waste management systems using operational research methodologies has not yet been applied in any Egyptian governorate. In this paper, a proposed model for a municipal solid waste management system in Port Said, Egypt is presented. It includes the use of the concept of collection stations, which have not yet been used in Egypt. Mixed integer programming is used to model the proposed system and its solution is performed using MPL software V4.2. The results show that the best model would include 27 collection stations of 15-ton daily capacity and 2 collection stations of 10 ton daily capacity.more » Any transfer of waste between the collection station and the landfill should not occur. Moreover, the flow of the district waste should not be confined to the district collection stations. The cost of the objective function for this solution is 10,122 LE/day (equivalent to US$1716). After further calculations, the profit generated by the proposed model is 49,655.8 LE/day (equivalent to US$8418.23)« less

Finding urban waste management solutions and policies: Waste-to-energy development and livelihood support system in Payatas, Metro Manila, Philippines.

PubMed

Serrona, Kevin Roy; Yu, Jeong-Soo

2009-01-01

One of the potential solutions in social and environmental sustainability in municipal solid waste management (MSW) in Metro Manila is to combine community-based recycling and sound landfill management strategies. The marriage of the two puts importance on recycling as a source of livelihood while proper landfill management aims to improve the aesthetic and environmental quality of disposal facilities in urban areas. To do this, a social mapping of wastepickers, junkshops and local recycling practices needs to be undertaken and at the same time assess strategies of the national and local governments vis-à-vis existing laws on municipal solid waste. The case of Payatas controlled disposal facility was taken as a pilot study because it represents the general condition of disposal sites in Metro Manila and the social landscape that it currently has. In addition, a waste-to-energy (WTE) project has been established in Payatas to produce electricity from methane gas. Preliminary interviews with wastepickers show that development interventions in disposal sites such as WTE pose no opposition from host communities for as long as alternative livelihood opportunities are provided. Regulating the flow of wastepickers into the landfill has advantages like improved income and security. Felt needs were also articulated like provision of financial support or capital for junkshop operation and skills training. Overall, a smooth relationship between the local government and community associations pays well in a transitioning landfill management scheme such as Payatas.

Zirconia ceramics for excess weapons plutonium waste

NASA Astrophysics Data System (ADS)

Gong, W. L.; Lutze, W.; Ewing, R. C.

2000-01-01

We synthesized a zirconia (ZrO 2)-based single-phase ceramic containing simulated excess weapons plutonium waste. ZrO 2 has large solubility for other metallic oxides. More than 20 binary systems A xO y-ZrO 2 have been reported in the literature, including PuO 2, rare-earth oxides, and oxides of metals contained in weapons plutonium wastes. We show that significant amounts of gadolinium (neutron absorber) and yttrium (additional stabilizer of the cubic modification) can be dissolved in ZrO 2, together with plutonium (simulated by Ce 4+, U 4+ or Th 4+) and impurities (e.g., Ca, Mg, Fe, Si). Sol-gel and powder methods were applied to make homogeneous, single-phase zirconia solid solutions. Pu waste impurities were completely dissolved in the solid solutions. In contrast to other phases, e.g., zirconolite and pyrochlore, zirconia is extremely radiation resistant and does not undergo amorphization. Baddeleyite (ZrO 2) is suggested as the natural analogue to study long-term radiation resistance and chemical durability of zirconia-based waste forms.

Fluidized bed steam reformed mineral waste form performance testing to support Hanford Supplemental Low Activity Waste Immobilization Technology Selection

DOE Office of Scientific and Technical Information (OSTI.GOV)

Jantzen, C. M.; Pierce, E. M.; Bannochie, C. J.

This report describes the benchscale testing with simulant and radioactive Hanford Tank Blends, mineral product characterization and testing, and monolith testing and characterization. These projects were funded by DOE EM-31 Technology Development & Deployment (TDD) Program Technical Task Plan WP-5.2.1-2010-001 and are entitled “Fluidized Bed Steam Reformer Low-Level Waste Form Qualification”, Inter-Entity Work Order (IEWO) M0SRV00054 with Washington River Protection Solutions (WRPS) entitled “Fluidized Bed Steam Reforming Treatability Studies Using Savannah River Site (SRS) Low Activity Waste and Hanford Low Activity Waste Tank Samples”, and IEWO M0SRV00080, “Fluidized Bed Steam Reforming Waste Form Qualification Testing Using SRS Low Activity Wastemore » and Hanford Low Activity Waste Tank Samples”. This was a multi-organizational program that included Savannah River National Laboratory (SRNL), THOR® Treatment Technologies (TTT), Pacific Northwest National Laboratory (PNNL), Oak Ridge National Laboratory (ORNL), Office of River Protection (ORP), and Washington River Protection Solutions (WRPS). The SRNL testing of the non-radioactive pilot-scale Fluidized Bed Steam Reformer (FBSR) products made by TTT, subsequent SRNL monolith formulation and testing and studies of these products, and SRNL Waste Treatment Plant Secondary Waste (WTP-SW) radioactive campaign were funded by DOE Advanced Remediation Technologies (ART) Phase 2 Project in connection with a Work-For-Others (WFO) between SRNL and TTT.« less

An Inorganic Microsphere Composite for the Selective Removal of Cesium 137 from Acidic Nuclear Waste Solutions - Parts 1 and 2

DOE Office of Scientific and Technical Information (OSTI.GOV)

T. J. Tranter; T. A. Vereschchagina; V. Utgikar

2009-03-01

A new inorganic ion exchange composite for removing radioactive cesium from acidic waste streams has been developed. The new material consists of ammonium molybdophosphate, (NH4)3P(Mo3O10)4•3H2O (AMP), synthesized within hollow aluminosilicate microspheres (AMP-C), which are produced as a by-product from coal combustion. The selective cesium exchange capacity of this inorganic composite was evaluated in bench-scale column tests using simulated sodium bearing waste solution as a surrogate for the acidic tank waste currently stored at the Idaho National Laboratory (INL). Total cesium loading on the columns at saturation agreed very well with equilibrium values predicted from isotherm experiments performed previously. A numericalmore » algorithm for solving the governing partial differential equations (PDE) for cesium uptake was developed using the intraparticle mass transfer coefficient obtained from previous batch kinetic experiments. Solutions to the governing equations were generated to obtain the cesium concentration at the column effluent as a function of throughput volume using the same conditions as those used for the actual column experiments. The numerical solutions of the PDE fit the column break through data quite well for all the experimental conditions in the study. The model should therefore provide a reliable prediction of column performance at larger scales. A new inorganic ion exchange composite consisting of ammonium molybdophosphate, (NH4)3P(Mo3O10)4•3H2O (AMP), synthesized within hollow aluminosilicate microspheres (AMP-C) has been developed. Two different batches of the sorbent were produced resulting in 20% and 25% AMP loading for two and three loading cycles, respectively. The selective cesium exchange capacity of this inorganic composite was evaluated using simulated sodium bearing waste solution as a surrogate for the acidic tank waste currently stored at the Idaho National Laboratory (INL). Equilibrium isotherms obtained from these

Hanford Waste Physical and Rheological Properties: Data and Gaps

DOE Office of Scientific and Technical Information (OSTI.GOV)

Wells, Beric E.; Kurath, Dean E.; Mahoney, Lenna A.

2011-08-01

The Hanford Site in Washington State manages 177 underground storage tanks containing approximately 250,000 m3 of waste generated during past defense reprocessing and waste management operations. These tanks contain a mixture of sludge, saltcake and supernatant liquids. The insoluble sludge fraction of the waste consists of metal oxides and hydroxides and contains the bulk of many radionuclides such as the transuranic components and 90Sr. The saltcake, generated by extensive evaporation of aqueous solutions, consists primarily of dried sodium salts. The supernates consist of concentrated (5-15 M) aqueous solutions of sodium and potassium salts. The 177 storage tanks include 149 single-shellmore » tanks (SSTs) and 28 double -hell tanks (DSTs). Ultimately the wastes need to be retrieved from the tanks for treatment and disposal. The SSTs contain minimal amounts of liquid wastes, and the Tank Operations Contractor is continuing a program of moving solid wastes from SSTs to interim storage in the DSTs. The Hanford DST system provides the staging location for waste feed delivery to the Department of Energy (DOE) Office of River Protection’s (ORP) Hanford Tank Waste Treatment and Immobilization Plant (WTP). The WTP is being designed and constructed to pretreat and then vitrify a large portion of the wastes in Hanford’s 177 underground waste storage tanks.« less

Removal of 226Ra and 228Ra from TENORM sludge waste using surfactants solutions.

PubMed

Attallah, M F; Hamed, Mostafa M; El Afifi, E M; Aly, H F

2015-01-01

The feasibility of using surfactants as extracting agent for the removal of radium species from TENORM sludge produced from petroleum industry is evaluated. In this investigation cationic and nonionic surfactants were used as extracting agents for the removal of radium radionuclides from the sludge waste. Two surfactants namely cetyltrimethylammonium bromide (CTAB) and Triton X-100 (TX100) were investigated as the extracting agents. Different parameters affecting the removal of both (226)Ra and (228)Ra by the two surfactants as well as their admixture were studied by the batch technique. These parameters include effect of shaking time, surfactants concentration and temperature as well as the effect of surfactants admixture. It was found that, higher solution temperature improves the removal efficiency of radium species. Combined extraction of nonionic and cationic surfactants produces synergistic effect in removal both (226)Ra and (228)Ra, where the removals reached 84% and 80% for (226)Ra and (228)Ra, respectively, were obtained using surfactants admixture. Copyright © 2014 Elsevier Ltd. All rights reserved.

Community Solutions for Solid Waste Pollution, Level 6. Teacher Guide. Operation Waste Watch.

ERIC Educational Resources Information Center

Virginia State Dept. of Waste Management, Richmond. Div. of Litter & Recycling.

Operation Waste Watch is a series of seven sequential learning units which addresses the subject of litter control and solid waste management. Each unit may be used in a variety of ways, depending on the needs and schedules of individual schools, and may be incorporated into various social studies, science, language arts, health, mathematics, and…

76 FR 13666 - Pitney Bowes, Inc., Mailing Solutions Management, Global Engineering Group, Including On-Site...

Federal Register 2010, 2011, 2012, 2013, 2014

2011-03-14

...., Mailing Solutions Management, Global Engineering Group, Including On-Site Leased Workers From Guidant... workers and former workers of Pitney Bowes, Inc., Mailing Solutions Management Division, Engineering... reviewed the certification to clarify the subject worker group's identity. Additional information revealed...

Updated Liquid Secondary Waste Grout Formulation and Preliminary Waste Form Qualification

DOE Office of Scientific and Technical Information (OSTI.GOV)

Saslow, Sarah A.; Um, Wooyong; Russell, Renee L.

This report describes the results from liquid secondary waste grout (LSWG) formulation and cementitious waste form qualification tests performed by Pacific Northwest National Laboratory (PNNL) for Washington River Protection Solutions, LLC (WRPS). New formulations for preparing a cementitious waste form from a high-sulfate liquid secondary waste stream simulant, developed for Effluent Management Facility (EMF) process condensates merged with low activity waste (LAW) caustic scrubber, and the release of key constituents (e.g. 99Tc and 129I) from these monoliths were evaluated. This work supports a technology development program to address the technology needs for Hanford Site Effluent Treatment Facility (ETF) liquid secondarymore » waste (LSW) solidification and supports future Direct Feed Low-Activity Waste (DFLAW) operations. High-priority activities included simulant development, LSWG formulation, and waste form qualification. The work contained within this report relates to waste form development and testing and does not directly support the 2017 integrated disposal facility (IDF) performance assessment (PA). However, this work contains valuable information for use in PA maintenance past FY17, and for future waste form development efforts. The provided data should be used by (i) cementitious waste form scientists to further understanding of cementitious dissolution behavior, (ii) IDF PA modelers who use quantified constituent leachability, effective diffusivity, and partitioning coefficients to advance PA modeling efforts, and (iii) the U.S. Department of Energy (DOE) contractors and decision makers as they assess the IDF PA program. The results obtained help fill existing data gaps, support final selection of a LSWG waste form, and improve the technical defensibility of long-term waste form performance estimates.« less

Discussion on the methodology for determining food waste in household waste composition studies.

PubMed

Lebersorger, S; Schneider, F

2011-01-01

Food waste has become an increasingly discussed topic in recent years. However, there is little authoritative data on food waste quantities and composition and systematic and comparable data are missing. Household waste composition analyses, which are often carried out routinely at regular or irregular intervals, provide an opportunity for obtaining data about food waste at both local and regional levels. The results of prior waste composition studies are not really comparable due to the different classifications, definitions and methods used; in addition, these are mostly insufficiently described and not reproducible by a third party. The aim of this paper is to discuss a methodology for determining the proportion of food waste in household waste composition studies, by analysing specific problems and possible solutions. For that purpose, findings from the literature are analysed and the approach and results of a composition analysis of residual waste of a stratified sample (urban, rural area) are presented. The study suggests that in order to avoid a significant loss of information, waste should not be sieved before sorting and packed food waste should be classified into the relevant food waste category together with its packaging. The case study showed that the overall influence of the proportion of food packaging included in the food waste category, which amounted to only 8%, did not significantly influence the results and can therefore be disregarded. Copyright © 2011 Elsevier Ltd. All rights reserved.

Detection of stress corrosion cracking and general corrosion of mild steel in simulated defense nuclear waste solutions using electrochemical noise analysis

NASA Astrophysics Data System (ADS)

Edgemon, G. L.; Danielson, M. J.; Bell, G. E. C.

1997-06-01

Underground waste tanks fabricated from mild steel store more than 253 million liters of high level radioactive waste from 50 years of weapons production at the Hanford Site. The probable modes of corrosion failures are reported as nitrate stress corrosion cracking and pitting. In an effort to develop a waste tank corrosion monitoring system, laboratory tests were conducted to characterize electrochemical noise data for both uniform and localized corrosion of mild steel and other materials in simulated waste environments. The simulated waste solutions were primarily composed of ammonium nitrate or sodium nitrate and were held at approximately 97°C. The electrochemical noise of freely corroding specimens was monitored, recorded and analyzed for periods ranging between 10 and 500 h. At the end of each test period, the specimens were examined to correlate electrochemical noise data with corrosion damage. Data characteristic of uniform corrosion and stress corrosion cracking are presented.

Estimates of water and solute release from a coal waste rock dump in the Elk Valley, British Columbia, Canada.

PubMed

Villeneuve, S A; Barbour, S L; Hendry, M J; Carey, S K

2017-12-01

Long term (1999 to 2014) flow and water quality data from a rock drain located at the base of a coal waste rock dump constructed in the Elk Valley, British Columbia was used to characterize the release of three solutes (NO 3 - , Cl - and SO 4 2- ) from the dump and obtain whole dump estimates of net percolation (NP). The concentrations of dump derived solutes in the rock drain water were diluted by snowmelt waters from the adjacent natural watershed during the spring freshet and reached a maximum concentration during the winter baseflow period. Historical peak baseflow concentrations of conservative ions (NO 3 - and Cl - ) increased until 2006/07 after which they decreased. This decrease was attributed to completion of the flushing of the first pore volume of water stored within the dump. The baseflow SO 4 2- concentrations increased proportionally with NO 3 - and Cl - to 2007, but then continued to slowly increase as NO 3 - and Cl - concentrations decreased. This was attributed to ongoing production of SO 4 2- due to oxidation of sulfide minerals within the dump. Based on partitioning of the annual volume of water discharged from the rock drain to waste rock effluent (NP) and water entering the rock drain laterally from the natural watershed, the mean NP values were estimated to be 446±50mm/a (area normalized net percolation/year) for the dump and 172±71mm/a for the natural watershed. The difference was attributed to greater rates of recharge in the dump from summer precipitation compared to the natural watershed where rainfall interception and enhanced evapotranspiration will increase water losses. These estimates included water moving through subsurface pathways. However, given the limitations in quantifying these flows the estimated NP rates for both the natural watershed and the waste rock dump are considered to be low, and could be much higher (e.g. ~450mm/a and ~800mm/a). Copyright © 2017 Elsevier B.V. All rights reserved.

Method and system including a double rotary kiln pyrolysis or gasification of waste material

DOEpatents

McIntosh, M.J.; Arzoumanidis, G.G.

1997-09-02

A method is described for destructively distilling an organic material in particulate form wherein the particulates are introduced through an inlet into one end of an inner rotating kiln ganged to and coaxial with an outer rotating kiln. The inner and outer kilns define a cylindrical annular space with the inlet being positioned in registry with the axis of rotation of the ganged kilns. During operation, the temperature of the wall of the inner rotary kiln at the inlet is not less than about 500 C to heat the particulate material to a temperature in the range of from about 200 C to about 900 C in a pyrolyzing atmosphere to reduce the particulate material as it moves from the one end toward the other end. The reduced particulates including char are transferred to the annular space between the inner and the outer rotating kilns near the other end of the inner rotating kiln and moved longitudinally in the annular space from near the other end toward the one end in the presence of oxygen to combust the char at an elevated temperature to produce a waste material including ash. Also, heat is provided which is transferred to the inner kiln. The waste material including ash leaves the outer rotating kiln near the one end and the pyrolysis vapor leaves through the particulate material inlet. 5 figs.

Method and system including a double rotary kiln pyrolysis or gasification of waste material

DOEpatents

McIntosh, Michael J.; Arzoumanidis, Gregory G.

1997-01-01

A method of destructively distilling an organic material in particulate form wherein the particulates are introduced through an inlet into one end of an inner rotating kiln ganged to and coaxial with an outer rotating kiln. The inner and outer kilns define a cylindrical annular space with the inlet being positioned in registry with the axis of rotation of the ganged kilns. During operation, the temperature of the wall of the inner rotary kiln at the inlet is not less than about 500.degree. C. to heat the particulate material to a temperature in the range of from about 200.degree. C. to about 900.degree. C. in a pyrolyzing atmosphere to reduce the particulate material as it moves from the one end toward the other end. The reduced particulates including char are transferred to the annular space between the inner and the outer rotating kilns near the other end of the inner rotating kiln and moved longitudinally in the annular space from near the other end toward the one end in the presence of oxygen to combust the char at an elevated temperature to produce a waste material including ash. Also, heat is provided which is transferred to the inner kiln. The waste material including ash leaves the outer rotating kiln near the one end and the pyrolysis vapor leaves through the particulate material inlet.

Understanding the role of waste prevention in local waste management: A literature review.

PubMed

Zacho, Kristina O; Mosgaard, Mette A

2016-10-01

Local waste management has so far been characterised by end-of-pipe solutions, landfilling, incineration, and recycling. End-of-pipe solutions build on a different mind-set than life cycle-based approaches, and for this reason, local waste managers are reluctant to consider strategies for waste prevention. To accelerate the transition of waste and resource management towards a more integrated management, waste prevention needs to play a larger role in the local waste management. In this review article, we collect knowledge from the scientific community on waste prevention of relevance to local waste management. We analyse the trends in the waste prevention literature by organising the literature into four categories. The results indicate an increasing interest in waste prevention, but not much literature specifically concerns the integration of prevention into the local waste management. However, evidence from the literature can inform local waste management on the prevention potential; the environmental and social effects of prevention; how individuals in households can be motivated to reduce waste; and how the effects of prevention measures can be monitored. Nevertheless, knowledge is still lacking on local waste prevention, especially regarding the methods for monitoring and how local waste management systems can be designed to encourage waste reduction in the households. We end the article with recommendations for future research. The literature review can be useful for both practitioners in the waste sector and for academics seeking an overview of previous research on waste prevention. © The Author(s) 2016.

Iron-phosphate ceramics for solidification of mixed low-level waste

DOEpatents

Aloy, Albert S.; Kovarskaya, Elena N.; Koltsova, Tatiana I.; Macheret, Yevgeny; Medvedev, Pavel G.; Todd, Terry

2000-01-01

A method of immobilizing mixed low-level waste is provided which uses low cost materials and has a relatively long hardening period. The method includes: forming a mixture of iron oxide powders having ratios, in mass %, of FeO:Fe.sub.2 O.sub.3 :Fe.sub.3 O.sub.4 equal to 25-40:40-10:35-50, or weighing a definite amount of magnetite powder. Metallurgical cinder can also be used as the source of iron oxides. A solution of the orthophosphoric acid, or a solution of the orthophosphoric acid and ferric oxide, is formed and a powder phase of low-level waste and the mixture of iron oxide powders or cinder (or magnetite powder) is also formed. The acid solution is mixed with the powder phase to form a slurry with the ratio of components (mass %) of waste:iron oxide powders or magnetite:acid solution=30-60:15-10:55-30. The slurry is blended to form a homogeneous mixture which is cured at room temperature to form the final product.

Liquid secondary waste. Waste form formulation and qualification

DOE Office of Scientific and Technical Information (OSTI.GOV)

Cozzi, A. D.; Dixon, K. L.; Hill, K. A.

The Hanford Site Effluent Treatment Facility (ETF) currently treats aqueous waste streams generated during Site cleanup activities. When the Hanford Tank Waste Treatment and Immobilization Plant (WTP) begins operations, a liquid secondary waste (LSW) stream from the WTP will need to be treated. The volume of effluent for treatment at the ETF will increase significantly. Washington River Protection Solutions is implementing a Secondary Liquid Waste Immobilization Technology Development Plan to address the technology needs for a waste form and solidification process to treat the increased volume of waste planned for disposal at the Integrated Disposal Facility IDF). Waste form testingmore » to support this plan is composed of work in the near term to demonstrate the waste form will provide data as input to a performance assessment (PA) for Hanford’s IDF.« less

Engineering solutions of environmental problems in organic waste handling

NASA Astrophysics Data System (ADS)

Briukhanov, A. Y.; Vasilev, E. V.; Shalavina, E. V.; Kucheruk, O. N.

2017-10-01

This study shows the urgent need to consider modernization of agricultural production in terms of sustainable development, which takes into account environmental implications of intensive technologies in livestock farming. Some science-based approaches are offered to address related environmental challenges. High-end technologies of organic livestock waste processing were substantiated by the feasibility study and nutrient balance calculation. The technologies were assessed on the basis of best available techniques criteria, including measures such as specific capital and operational costs associated with nutrient conservation and their delivery to the plants.

Has the question of e-waste opened a Pandora's box? An overview of unpredictable issues and challenges.

PubMed

Bakhiyi, Bouchra; Gravel, Sabrina; Ceballos, Diana; Flynn, Michael A; Zayed, Joseph

2018-01-01

Despite regulatory efforts and position papers, electrical and electronic waste (e-waste) remains ill-managed as evidenced by the extremely low rates of proper e-waste recycling (e-recycling) worldwide, ongoing illegal shipments to developing countries and constantly reported human health issues and environmental pollution. The objectives of this review are, first, to expose the complexity of e-waste problems, and then to suggest possible upstream and downstream solutions. Exploring e-waste issues is akin to opening a Pandora's box. Thus, a review of prevailing e-waste management practices reveals complex and often intertwined gaps, issues and challenges. These include the absence of any consistent definition of e-waste to date, a prevalent toxic potential still involving already banned or restricted hazardous components such as heavy metals and persistent and bioaccumulative organic compounds, a relentless growth in e-waste volume fueled by planned obsolescence and unsustainable consumption, problematic e-recycling processes, a fragile formal e-recycling sector, sustained and more harmful informal e-recycling practices, and more convoluted and unpredictable patterns of illegal e-waste trade. A close examination of the e-waste legacy contamination reveals critical human health concerns, including significant occupational exposure during both formal and informal e-recycling, and persistent environmental contamination, particularly in some developing countries. However, newly detected e-waste contaminants as well as unexpected sources and environmental fates of contaminants are among the emerging issues that raise concerns. Moreover, scientific knowledge gaps remain regarding the complexity and magnitude of the e-waste legacy contamination, specifically, a comprehensive characterization of e-waste contaminants, information on the scale of legacy contamination in developing countries and on the potential environmental damage in developed countries, and a stronger body

40 CFR 260.23 - Petitions to amend 40 CFR part 273 to include additional hazardous wastes.

Code of Federal Regulations, 2014 CFR

2014-07-01

... PROTECTION AGENCY (CONTINUED) SOLID WASTES (CONTINUED) HAZARDOUS WASTE MANAGEMENT SYSTEM: GENERAL Rulemaking... appropriate for the waste or category of waste; will improve management practices for the waste or category of... waste or category of waste, will improve management practices for the waste or category of waste, and...

40 CFR 260.23 - Petitions to amend 40 CFR part 273 to include additional hazardous wastes.

Code of Federal Regulations, 2012 CFR

2012-07-01

... PROTECTION AGENCY (CONTINUED) SOLID WASTES (CONTINUED) HAZARDOUS WASTE MANAGEMENT SYSTEM: GENERAL Rulemaking... appropriate for the waste or category of waste; will improve management practices for the waste or category of... waste or category of waste, will improve management practices for the waste or category of waste, and...

40 CFR 260.23 - Petitions to amend 40 CFR part 273 to include additional hazardous wastes.

Code of Federal Regulations, 2013 CFR

2013-07-01

... PROTECTION AGENCY (CONTINUED) SOLID WASTES (CONTINUED) HAZARDOUS WASTE MANAGEMENT SYSTEM: GENERAL Rulemaking... appropriate for the waste or category of waste; will improve management practices for the waste or category of... waste or category of waste, will improve management practices for the waste or category of waste, and...

40 CFR 260.23 - Petitions to amend 40 CFR part 273 to include additional hazardous wastes.

Code of Federal Regulations, 2010 CFR

2010-07-01

... PROTECTION AGENCY (CONTINUED) SOLID WASTES (CONTINUED) HAZARDOUS WASTE MANAGEMENT SYSTEM: GENERAL Rulemaking... appropriate for the waste or category of waste; will improve management practices for the waste or category of... waste or category of waste, will improve management practices for the waste or category of waste, and...

Local existence of solutions to the Euler-Poisson system, including densities without compact support

NASA Astrophysics Data System (ADS)

Brauer, Uwe; Karp, Lavi

2018-01-01

Local existence and well posedness for a class of solutions for the Euler Poisson system is shown. These solutions have a density ρ which either falls off at infinity or has compact support. The solutions have finite mass, finite energy functional and include the static spherical solutions for γ = 6/5. The result is achieved by using weighted Sobolev spaces of fractional order and a new non-linear estimate which allows to estimate the physical density by the regularised non-linear matter variable. Gamblin also has studied this setting but using very different functional spaces. However we believe that the functional setting we use is more appropriate to describe a physical isolated body and more suitable to study the Newtonian limit.

Biosorption of clofibric acid and carbamazepine in aqueous solution by agricultural waste rice straw.

PubMed

Liu, Zhanguang; Zhou, Xuefei; Chen, Xiaohua; Dai, Chaomeng; Zhang, Juan; Zhang, Yalei

2013-12-01

Due to their widespread use, clofibric acid (CA) and carbamazepine (CBZ) have been frequently detected simultaneously at relatively high concentrations in aquatic environments. In this study, agricultural waste rice straw was employed as a potentially low-cost, effective and easy-to-operate biosorbent (RSB) to remove CA and CBZ. The adsorption of both pharmaceuticals followed pseudo second-order kinetics, and intraparticle diffusion was an important rate-limiting step. The adsorption isotherms of both drugs were fit well with Freundlich model. The adsorption of CA onto RSB was exothermic and was more likely to be dominated by physical processes, while the adsorption of CBZ was endothermic. Solution pH was determined to be the most important factor for CA adsorption, such that the adsorption capacity of CA onto RSB increased with the decline of solution pH. In the lower range of solution pH below 3.1, the CA removal efficiency was enhanced with the increase of biosorbent dosage. The CBZ removal efficiency was enhanced with the increase of RSB dosage without pH control. The maximum adsorption capacities were 126.3 mg/g for CA and 40.0 mg/g for CBZ.

Effluent Management Facility Evaporator Bottom-Waste Streams Formulation and Waste Form Qualification Testing

DOE Office of Scientific and Technical Information (OSTI.GOV)

Saslow, Sarah A.; Um, Wooyong; Russell, Renee L.

This report describes the results from grout formulation and cementitious waste form qualification testing performed by Pacific Northwest National Laboratory (PNNL) for Washington River Protection Solutions, LLC (WRPS). These results are part of a screening test that investigates three grout formulations proposed for wide-range treatment of different waste stream compositions expected for the Hanford Effluent Management Facility (EMF) evaporator bottom waste. This work supports the technical development need for alternative disposition paths for the EMF evaporator bottom wastes and future direct feed low-activity waste (DFLAW) operations at the Hanford Site. High-priority activities included simulant production, grout formulation, and cementitious wastemore » form qualification testing. The work contained within this report relates to waste form development and testing, and does not directly support the 2017 Integrated Disposal Facility (IDF) performance assessment (PA). However, this work contains valuable information for use in PA maintenance past FY 2017 and future waste form development efforts. The provided results and data should be used by (1) cementitious waste form scientists to further the understanding of cementitious leach behavior of contaminants of concern (COCs), (2) decision makers interested in off-site waste form disposal, and (3) the U.S. Department of Energy, their Hanford Site contractors and stakeholders as they assess the IDF PA program at the Hanford Site. The results reported help fill existing data gaps, support final selection of a cementitious waste form for the EMF evaporator bottom waste, and improve the technical defensibility of long-term waste form risk estimates.« less

Development of an Integrated Leachate Treatment Solution for the Port Granby Waste Management Facility - 12429

DOE Office of Scientific and Technical Information (OSTI.GOV)

Conroy, Kevin W.; Vandergaast, Gerald

2012-07-01

The Port Granby Project (the Project) is located near the north shore of Lake Ontario in the Municipality of Clarington, Ontario, Canada. The Project consists of relocating approximately 450,000 m{sup 3} of historic Low-Level Radioactive Waste (LLRW) and contaminated soil from the existing Port Granby Waste Management Facility (WMF) to a proposed Long-Term Waste Management Facility (LTWMF) located adjacent to the WMF. The LTWMF will include an engineered waste containment facility, a Wastewater Treatment Plant (WTP), and other ancillary facilities. A series of bench- and pilot-scale test programs have been conducted to identify preferred treatment processes to be incorporated intomore » the WTP to treat wastewater generated during the construction, closure and post-closure periods at the WMF/LTWMF. (authors)« less

Parametric and kinetic study of adsorptive removal of dyes from aqueous solutions using an agriculture waste

NASA Astrophysics Data System (ADS)

Bencheikh, imane; el hajjaji, souad; abourouh, imane; Kitane, Said; Dahchour, Abdelmalek; El M'Rabet, Mohammadine

2017-04-01

Wastewater treatment is the subject of several studies through decades. Interest is continuously oriented to provide cheaper and efficient methods of treatment. Several methods of treatment exit including coagulation flocculation, filtration, precipitation, ozonation, ion exchange, reverse osmosis, advanced oxidation process. The use of these methods proved limited because of their high investment and operational cost. Adsorption can be an efficient low-cost process to remove pollutants from wastewater. This method of treatment calls for an solid adsorbent which constitutes the purification tool. Agricultural wastes have been widely exploited in this case .As we know the agricultural wastes are an important source of water pollution once discharged into the aquatic environment (river, sea ...). The valorization of such wastes and their use allows the prevention of this problem with an economic and environment benefits. In this context our study aimed testing the wastewater treatment capacity by adsorption onto holocellulose resulting from the valorization of an agriculture waste. In this study, methylene blue (MB) and methyl orange (MO) are selected as models pollutants for evaluating the holocellulose adsorbent capacity. The kinetics of adsorption is performed using UV-visible spectroscopy. In order to study the effect of the main parameters for the adsorption process and their mutual interaction, a full factorial design (type nk) has been used.23 full factorial design analysis was performed to screen the parameters affecting dye removal efficiency. Using the experimental results, a linear mathematical model representing the influence of the different parameters and their interactions was obtained. The parametric study showed that efficiency of the adsorption system (Dyes/ Holocellulose) is mainly linked to pH variation. The best yields were observed for MB at pH=10 and for MO at pH=2.The kinetic data was analyzed using different models , namely , the pseudo

Removal of acid blue 062 on aqueous solution using calcinated colemanite ore waste.

PubMed

Atar, Necip; Olgun, Asim

2007-07-19

Colemanite ore waste (CW) has been employed as adsorbent for the removal of acid blue 062 anionic dye (AB 062) from aqueous solution. The adsorption of AB 062 onto CW was examined with respect to contact time, calcination temperature, particle size, pH, adsorbent dosage and temperature. The physical and chemical properties of the CW, such as particle sizes and calcinations temperature, play important roles in dye adsorption. The dye adsorption largely depends on the initial pH of the solution with maximum uptake occurring at pH 1. Three simplified kinetics models, namely, pseudo-first order, pseudo-second order, and intraparticle diffusion models were tested to investigate the adsorption mechanisms. The kinetic adsorption of AB 062 on CW follows a pseudo-second order equation. The adsorption data have been analyzed using Langmuir and Freundlich isotherms. The results indicate that the Langmuir model provides the best correlation of the experimental data. Isotherms have also been used to obtain the thermodynamic parameters such as free energy, enthalpy and entropy of the adsorption of dye onto CW.

Effective removal of tetracycline from aqueous solution using activated carbon prepared from tomato (Lycopersicon esculentum Mill.) industrial processing waste.

PubMed

Sayğılı, Hasan; Güzel, Fuat

2016-09-01

Activated carbon (TAC) prepared under optimized conditions with ZnCl2 activation from a new precursor; tomato industrial processing waste (TW), was applied as an adsorbent to remove tetracycline (TC) from aqueous solution. The factors (TAC dosage, initial TC concentration, contact time, ionic strength and solution temperature) affecting the adsorption process were examined at natural pH (5.7) of TAC-TC system in aqueous solution. Kinetic data was found to be best complied by the pseudo-second order model. The isotherm analysis indicated that the equilibrium data could be represented by the Langmuir model. The maximum adsorption capacity was identified as 500.0mgg(-1) at 308K. Copyright © 2016 Elsevier Inc. All rights reserved.

Extraction of cesium and strontium from nuclear waste

DOEpatents

Davis, Jr., Milton W.; Bowers, Jr., Charles B.

1988-01-01

Cesium is extracted from acidified nuclear waste by contacting the waste with a bis 4,4'(5) [1-hydroxy-2-ethylhexyl]benzo 18-crown-6 compound and a cation exchanger in a matrix solution. Strontium is extracted from acidified nuclear waste by contacting the waste with a bis 4,4'(5') [1-hydroxyheptyl]cyclohexo 18-crown-6 compound, and a cation exchanger in a matrix solution.

40 CFR 60.2630 - What should I include in my waste management plan?

Code of Federal Regulations, 2014 CFR

2014-07-01

...) AIR PROGRAMS (CONTINUED) STANDARDS OF PERFORMANCE FOR NEW STATIONARY SOURCES Emissions Guidelines and Compliance Times for Commercial and Industrial Solid Waste Incineration Units Model Rule-Waste Management.... Model Rule—Operator Training and Qualification ...

40 CFR 60.2630 - What should I include in my waste management plan?

Code of Federal Regulations, 2013 CFR

2013-07-01

...) AIR PROGRAMS (CONTINUED) STANDARDS OF PERFORMANCE FOR NEW STATIONARY SOURCES Emissions Guidelines and Compliance Times for Commercial and Industrial Solid Waste Incineration Units Model Rule-Waste Management.... Model Rule—Operator Training and Qualification ...

Colloid formation in Hanford sediments reacted with simulated tank waste.

PubMed

Mashal, Kholoud; Harsh, James B; Flury, Markus; Felmy, Andrew R; Zhao, Hongting

2004-11-01

Solutions of high pH, ionic strength, and aluminum concentration have leaked into the subsurface from underground waste storage tanks atthe Hanford Reservation in Washington State. Here, we test the hypothesis that these waste solutions alter and dissolve the native minerals present in the sediments and that colloidal (diameter < 2 microm) feldspathoids form. We reacted Hanford sediments with simulated solutions representative of Hanford waste tanks. The solutions consisted of 1.4 or 2.8 mol/kg NaOH, 0.125 or 0.25 mol/kg NaAlO4, and 3.7 mol/kg NaNO3 and were contacted with the sediments for a period of 25 or 40 days at 50 degrees C. The colloidal size fraction was separated from the sediments and characterized in terms of mineralogy, morphology, chemical composition, and electrophoretic mobility. Upon reaction with tank waste solutions, native minerals released Si and other elements into the solution phase. This Si precipitated with the Al present in the waste solutions to form secondary minerals, identified as the feldspathoids cancrinite and sodalite. The solution phase was modeled with the chemical equilibrium model GMIN for solution speciation and saturation indices with respect to sodalite and cancrinite. The amount of colloidal material in the sediments increased upon reaction with waste solutions. At the natural pH found in Hanford sediments (pH 8) the newly formed minerals are negatively charged, similar to the unreacted colloidal material present in the sediments. The formation of colloidal material in Hanford sediments upon reaction with tank waste solutions is an important aspect to consider in the characterization of Hanford tank leaks and may affect the fate of hazardous radionuclides present in the tank waste.

Extraction of cesium and strontium from nuclear waste

DOEpatents

Davis, M.W. Jr.; Bowers, C.B. Jr.

1988-06-07

Cesium is extracted from acidified nuclear waste by contacting the waste with a bis 4,4[prime](5) [1-hydroxy-2-ethylhexyl]benzo 18-crown-6 compound and a cation exchanger in a matrix solution. Strontium is extracted from acidified nuclear waste by contacting the waste with a bis 4,4[prime](5[prime]) [1-hydroxyheptyl]cyclohexo 18-crown-6 compound, and a cation exchanger in a matrix solution. 3 figs.

Subseabed storage of radioactive waste

NASA Astrophysics Data System (ADS)

Bell, Peter M.

The subject of the storage of nuclear wastes products incites emotional responses from the public, and thus the U.S. Subseabed Disposal Program will have to make a good case for waste storage beneath the ocean floor. The facts attendant, however, describe circumstances necessitating cool-headed analysis to achieve a solution to the growing nuclear waste problem. Emotion aside, a good case indeed is being made for safe disposal beneath the ocean floor.The problems of nuclear waste storage are acute. A year ago, U.S. military weapons production had accumulated over seventy-five million gallons of high-level radioactive liquid waste; solid wastes, such as spent nuclear fuel rods from reactors, amounted to more than 12,000 tons. These wastes are corrosive and will release heat for 1000 years or more. The wastes will remain dangerously radioactive for a period of 10,000 years. There are advantages in storing the wastes on land, in special underground repositories, or on the surface. These include the accessibility to monitor the waste and the possibility of taking action should a container rupture occur, and thus the major efforts to determine suitable disposal at this time are focused on land-based storage. New efforts, not to be confused with ocean dumping practices of the past, are demonstrating that waste containers isolated in the clays and sediments of the ocean floor may be superior (Environ. Sci. Tech., 16, 28A-37A 1982).

Recycling of CdTe photovoltaic waste

DOEpatents

Goozner, Robert E.; Long, Mark O.; Drinkard, Jr., William F.

1999-01-01

A method for extracting and reclaiming metals from scrap CdTe photovoltaic cells and manufacturing waste by leaching the waste with a leaching solution comprising nitric acid and water, skimming any plastic material from the top of the leaching solution, separating the glass substrate from the liquid leachate and electrolyzing the leachate to separate Cd from Te, wherein the Te is deposits onto a cathode while the Cd remains in solution.

Closed-form solutions for linear regulator-design of mechanical systems including optimal weighting matrix selection

NASA Technical Reports Server (NTRS)

Hanks, Brantley R.; Skelton, Robert E.

1991-01-01

This paper addresses the restriction of Linear Quadratic Regulator (LQR) solutions to the algebraic Riccati Equation to design spaces which can be implemented as passive structural members and/or dampers. A general closed-form solution to the optimal free-decay control problem is presented which is tailored for structural-mechanical systems. The solution includes, as subsets, special cases such as the Rayleigh Dissipation Function and total energy. Weighting matrix selection is a constrained choice among several parameters to obtain desired physical relationships. The closed-form solution is also applicable to active control design for systems where perfect, collocated actuator-sensor pairs exist. Some examples of simple spring mass systems are shown to illustrate key points.

76 FR 2710 - Pitney Bowes, Inc., Mailing Solutions Management Division Including On-Site Leased Workers of...

Federal Register 2010, 2011, 2012, 2013, 2014

2011-01-14

...., Mailing Solutions Management Division Including On-Site Leased Workers of Guidant Group, and Teleworkers... Bowes, Inc., Mailing Solutions Management Division, Engineering Quality Assurance, Shelton, Connecticut... identity of the subject worker group. The worker group consists of workers of Pitney Bowes, Inc., the...

Incineration of European non-nuclear radioactive waste in the USA

DOE Office of Scientific and Technical Information (OSTI.GOV)

Moloney, B. P.; Ferguson, D.; Stephenson, B.

2013-07-01

Incineration of dry low level radioactive waste from nuclear stations is a well established process achieving high volume reduction factors to minimise disposal costs and to stabilise residues for disposal. Incineration has also been applied successfully in many European Union member countries to wastes arising from use of radionuclides in medicine, nonnuclear research and industry. However, some nations have preferred to accumulate wastes over many years in decay stores to reduce the radioactive burden at point of processing. After decay and sorting the waste, they then require a safe, industrial scale and affordable processing solution for the large volumes accumulated.more » This paper reports the regulatory, logistical and technical issues encountered in a programme delivered for Eckert and Ziegler Nuclitec to incinerate safely 100 te of waste collected originally from German research, hospital and industrial centres, applying for the first time a 'burn and return' process model for European waste in the US. The EnergySolutions incinerators at Bear Creek, Oak Ridge, Tennessee, USA routinely incinerate waste arising from the non-nuclear user community. To address the requirement from Germany, EnergySolutions had to run a dedicated campaign to reduce cross-contamination with non-German radionuclides to the practical minimum. The waste itself had to be sampled in a carefully controlled programme to ensure the exacting standards of Bear Creek's license and US emissions laws were maintained. Innovation was required in packaging of the waste to minimise transportation costs, including sea freight. The incineration was inspected on behalf of the German regulator (the BfS) to ensure suitability for return to Germany and disposal. This first 'burn and return' programme has safely completed the incineration phase in February and the arising ash will be returned to Germany presently. The paper reports the main findings and lessons learned on this first of its kind

Environmental Hazards of Nuclear Wastes

ERIC Educational Resources Information Center

Micklin, Philip P.

1974-01-01

Present methods for storage of radioactive wastes produced at nuclear power facilities are described. Problems arising from present waste management are discussed and potential solutions explored. (JP)

Scientific Background for Processing of Aluminum Waste

NASA Astrophysics Data System (ADS)

Kononchuk, Olga; Alekseev, Alexey; Zubkova, Olga; Udovitsky, Vladimir

2017-11-01

Changing the source of raw materials for producing aluminum and the emergence of a huge number of secondary alumina waste (foundry slag, sludge, spent catalysts, mineral parts of coal and others that are formed in various industrial enterprises) require the creation of scientific and theoretical foundations for their processing. In this paper, the aluminum alloys (GOST 4784-97) are used as an aluminum raw material component, containing the aluminum component produced as chips in the machine-building enterprises. The aluminum waste is a whole range of metallic aluminum alloys including elements: magnesium, copper, silica, zinc and iron. Analysis of the aluminum waste A1- Zn-Cu-Si-Fe shows that depending on the content of the metal the dissolution process of an aluminum alloy should be treated as the result of the chemical interaction of the metal with an alkaline solution. It is necessary to consider the behavior of the main components of alloys in an alkaline solution as applied to the system Na2O - Al2O3 - SiO2 - CO2 - H2O.

The Paravascular Pathway for Brain Waste Clearance: Current Understanding, Significance and Controversy

PubMed Central

Bacyinski, Andrew; Xu, Maosheng; Wang, Wei; Hu, Jiani

2017-01-01

The paravascular pathway, also known as the “glymphatic” pathway, is a recently described system for waste clearance in the brain. According to this model, cerebrospinal fluid (CSF) enters the paravascular spaces surrounding penetrating arteries of the brain, mixes with interstitial fluid (ISF) and solutes in the parenchyma, and exits along paravascular spaces of draining veins. Studies have shown that metabolic waste products and solutes, including proteins involved in the pathogenesis of neurodegenerative diseases such as amyloid-beta, may be cleared by this pathway. Consequently, a growing body of research has begun to explore the association between glymphatic dysfunction and various disease states. However, significant controversy exists in the literature regarding both the direction of waste clearance as well as the anatomical space in which the waste-fluid mixture is contained. Some studies have found no evidence of interstitial solute clearance along the paravascular space of veins. Rather, they demonstrate a perivascular pathway in which waste is cleared from the brain along an anatomically distinct perivascular space in a direction opposite to that of paravascular flow. Although possible explanations have been offered, none have been able to fully reconcile the discrepancies in the literature, and many questions remain. Given the therapeutic potential that a comprehensive understanding of brain waste clearance pathways might offer, further research and clarification is highly warranted. PMID:29163074

The Paravascular Pathway for Brain Waste Clearance: Current Understanding, Significance and Controversy.

PubMed

Bacyinski, Andrew; Xu, Maosheng; Wang, Wei; Hu, Jiani

2017-01-01

The paravascular pathway, also known as the "glymphatic" pathway, is a recently described system for waste clearance in the brain. According to this model, cerebrospinal fluid (CSF) enters the paravascular spaces surrounding penetrating arteries of the brain, mixes with interstitial fluid (ISF) and solutes in the parenchyma, and exits along paravascular spaces of draining veins. Studies have shown that metabolic waste products and solutes, including proteins involved in the pathogenesis of neurodegenerative diseases such as amyloid-beta, may be cleared by this pathway. Consequently, a growing body of research has begun to explore the association between glymphatic dysfunction and various disease states. However, significant controversy exists in the literature regarding both the direction of waste clearance as well as the anatomical space in which the waste-fluid mixture is contained. Some studies have found no evidence of interstitial solute clearance along the paravascular space of veins. Rather, they demonstrate a perivascular pathway in which waste is cleared from the brain along an anatomically distinct perivascular space in a direction opposite to that of paravascular flow. Although possible explanations have been offered, none have been able to fully reconcile the discrepancies in the literature, and many questions remain. Given the therapeutic potential that a comprehensive understanding of brain waste clearance pathways might offer, further research and clarification is highly warranted.

Utilization of municipal solid and liquid wastes for bioenergy and bioproducts production.

PubMed

Chen, Paul; Xie, Qinglong; Addy, Min; Zhou, Wenguang; Liu, Yuhuan; Wang, Yunpu; Cheng, Yanling; Li, Kun; Ruan, Roger

2016-09-01

Municipal wastes, be it solid or liquid, are rising due to the global population growth and rapid urbanization and industrialization. Conventional management practice involving recycling, combustion, and treatment/disposal is deemed unsustainable. Solutions must be sought to not only increase the capacity but also improve the sustainability of waste management. Research has demonstrated that the non-recyclable waste materials and bio-solids can be converted into useable heat, electricity, or fuel and chemical through a variety of processes, including gasification, pyrolysis, anaerobic digestion, and landfill gas in addition to combustion, and wastewater streams have the potential to support algae growth and provide other energy recovery options. The present review is intended to assess and analyze the current state of knowledge in the municipal solid wastes and wastewater treatment and utilization technologies and recommend practical solution options and future research and development needs. Copyright © 2016 Elsevier Ltd. All rights reserved.

78 FR 28642 - Eastman Kodak Company, Electrographic Print Solutions, Including On-Site Leased Workers From...

Federal Register 2010, 2011, 2012, 2013, 2014

2013-05-15

... Kodak Company, Electrographic Print Solutions, Including On-Site Leased Workers From Adecco and Datrose, Spencerport, New York; Eastman Kodak Company, IPS, Including On-Site Leased Workers From Adecco, Dayton, Ohio... Trade Adjustment Assistance (TAA) filed on behalf of Eastman Kodak Company, Electrographic Print...

Toward zero waste to landfill: an effective method for recycling zeolite waste from refinery industry

NASA Astrophysics Data System (ADS)

Homchuen, K.; Anuwattana, R.; Limphitakphong, N.; Chavalparit, O.

2017-07-01

One-third of landfill waste of refinery plant in Thailand was spent chloride zeolite, which wastes a huge of land, cost and time for handling. Toward zero waste to landfill, this study was aimed at determining an effective method for recycling zeolite waste by comparing the chemical process with the electrochemical process. To investigate the optimum conditions of both processes, concentration of chemical solution and reaction time were carried out for the former, while the latter varied in term of current density, initial pH of water, and reaction time. The results stated that regenerating zeolite waste from refinery industry in Thailand should be done through the chemical process with alkaline solution because it provided the best chloride adsorption efficiency with cost the least. A successful recycling will be beneficial not only in reducing the amount of landfill waste but also in reducing material and disposal costs and consumption of natural resources as well.

40 CFR 273.81 - Factors for petitions to include other wastes under 40 CFR part 273.

Code of Federal Regulations, 2011 CFR

2011-07-01

... generic name to identify the waste category (e.g., batteries), the definition of universal waste in § 260... waste category (e.g., hazardous waste batteries).) Thus, only the portion of the waste stream that does...) to recycling, treatment, or disposal in compliance with Subtitle C of RCRA. (g) Regulation of the...

40 CFR 273.81 - Factors for petitions to include other wastes under 40 CFR part 273.

Code of Federal Regulations, 2010 CFR

2010-07-01

... generic name to identify the waste category (e.g., batteries), the definition of universal waste in § 260... waste category (e.g., hazardous waste batteries).) Thus, only the portion of the waste stream that does...) to recycling, treatment, or disposal in compliance with Subtitle C of RCRA. (g) Regulation of the...

40 CFR 273.81 - Factors for petitions to include other wastes under 40 CFR part 273.

Code of Federal Regulations, 2014 CFR

2014-07-01

... generic name to identify the waste category (e.g., batteries), the definition of universal waste in § 260... waste category (e.g., hazardous waste batteries).) Thus, only the portion of the waste stream that does...) to recycling, treatment, or disposal in compliance with Subtitle C of RCRA. (g) Regulation of the...

40 CFR 273.81 - Factors for petitions to include other wastes under 40 CFR part 273.

Code of Federal Regulations, 2013 CFR

2013-07-01

... generic name to identify the waste category (e.g., batteries), the definition of universal waste in § 260... waste category (e.g., hazardous waste batteries).) Thus, only the portion of the waste stream that does...) to recycling, treatment, or disposal in compliance with Subtitle C of RCRA. (g) Regulation of the...

EnergySolution's Clive Disposal Facility Operational Research Model - 13475

DOE Office of Scientific and Technical Information (OSTI.GOV)

Nissley, Paul; Berry, Joanne

2013-07-01

EnergySolutions owns and operates a licensed, commercial low-level radioactive waste disposal facility located in Clive, Utah. The Clive site receives low-level radioactive waste from various locations within the United States via bulk truck, containerised truck, enclosed truck, bulk rail-cars, rail boxcars, and rail inter-modals. Waste packages are unloaded, characterized, processed, and disposed of at the Clive site. Examples of low-level radioactive waste arriving at Clive include, but are not limited to, contaminated soil/debris, spent nuclear power plant components, and medical waste. Generators of low-level radioactive waste typically include nuclear power plants, hospitals, national laboratories, and various United States government operatedmore » waste sites. Over the past few years, poor economic conditions have significantly reduced the number of shipments to Clive. With less revenue coming in from processing shipments, Clive needed to keep its expenses down if it was going to maintain past levels of profitability. The Operational Research group of EnergySolutions were asked to develop a simulation model to help identify any improvement opportunities that would increase overall operating efficiency and reduce costs at the Clive Facility. The Clive operations research model simulates the receipt, movement, and processing requirements of shipments arriving at the facility. The model includes shipment schedules, processing times of various waste types, labor requirements, shift schedules, and site equipment availability. The Clive operations research model has been developed using the WITNESS{sup TM} process simulation software, which is developed by the Lanner Group. The major goals of this project were to: - identify processing bottlenecks that could reduce the turnaround time from shipment arrival to disposal; - evaluate the use (or idle time) of labor and equipment; - project future operational requirements under different forecasted scenarios. By

Evidence-based integrated environmental solutions for secondary lead smelters: pollution prevention and waste minimization technologies and practices.

PubMed

Genaidy, A M; Sequeira, R; Tolaymat, T; Kohler, J; Rinder, M

2009-05-01

An evidence-based methodology was adopted in this research to establish strategies to increase lead recovery and recycling via a systematic review and critical appraisal of the published literature. In particular, the research examines pollution prevention and waste minimization practices and technologies that meet the following criteria: (a) reduce/recover/recycle the largest quantities of lead currently being disposed of as waste, (b) technically and economically viable, that is, ready to be diffused and easily transferable, and (c) strong industry interest (i.e., industry would consider implementing projects with higher payback periods). The following specific aims are designed to achieve the study objectives: Aim 1 - To describe the recycling process of recovering refined lead from scrap; Aim 2 - To document pollution prevention and waste management technologies and practices adopted by US stakeholders along the trajectory of LAB and lead product life cycle; Aim 3 - To explore improved practices and technologies which are employed by other organizations with an emphasis on the aforementioned criteria; Aim 4 - To demonstrate the economic and environmental costs and benefits of applying improved technologies and practices to existing US smelting operations; and Aim 5 - To evaluate improved environmental technologies and practices using an algorithm that integrates quantitative and qualitative criteria. The process of identifying relevant articles and reports was documented. The description of evidence was presented for current practices and technologies used by US smelters as well as improved practices and technologies. Options for integrated environmental solutions for secondary smelters were introduced and rank ordered on the basis of costs (i.e., capital investment) and benefits (i.e., production increases, energy and flux savings, and reduction of SO(2) and slag). An example was provided to demonstrate the utility of the algorithm by detailing the costs and

Valorization of aquaculture waste in removal of cadmium from aqueous solution: optimization by kinetics and ANN analysis

NASA Astrophysics Data System (ADS)

Aditya, Gautam; Hossain, Asif

2018-05-01

Cadmium is one of the most hazardous heavy metal concerning human health and aquatic pollution. The removal of cadmium through biosorption is a feasible option for restoration of the ecosystem health of the contaminated freshwater ecosystems. In compliance with this proposition and considering the efficiency of calcium carbonate as biosorbent, the shell dust of the economically important snail Bellamya bengalensis was tested for the removal of cadmium from aqueous medium. Following use of the flesh as a cheap source of protein, the shells of B. bengalensis made up of CaCO3 are discarded as aquaculture waste. The biosorption was assessed through batch sorption studies along with studies to characterize the morphology and surface structures of waste shell dust. The data on the biosorption were subjected to the artificial neural network (ANN) model for optimization of the process. The biosorption process changed as functions of pH of the solution, concentration of heavy metal, biomass of the adsorbent and time of exposure. The kinetic process was well represented by pseudo second order ( R 2 = 0.998), and Langmuir equilibrium ( R 2 = 0.995) had better fits in the equilibrium process with 30.33 mg g-1 of maximum sorption capacity. The regression equation ( R 2 = 0.948) in the ANN model supports predicted values of Cd removal satisfactorily. The normalized importance analysis in ANN predicts Cd2+ concentration, and pH has the most influence in removal than biomass dose and time. The SEM and EDX studies show clear peaks for Cd confirming the biosorption process while the FTIR study depicts the main functional groups (-OH, C-H, C=O, C=C) responsible for the biosorption process. The study indicated that the waste shell dust can be used as an efficient, low cost, environment friendly, sustainable adsorbent for the removal of cadmium from aqueous solution.

Influence of acidic and alkaline waste solution properties on uranium migration in subsurface sediments.

PubMed

Szecsody, Jim E; Truex, Mike J; Qafoku, Nikolla P; Wellman, Dawn M; Resch, Tom; Zhong, Lirong

2013-08-01

This study shows that acidic and alkaline wastes co-disposed with uranium into subsurface sediments have significant impact on changes in uranium retardation, concentration, and mass during downward migration. For uranium co-disposal with acidic wastes, significant rapid (i.e., hours) carbonate and slow (i.e., 100 s of hours) clay dissolution resulted, releasing significant sediment-associated uranium, but the extent of uranium release and mobility change was controlled by the acid mass added relative to the sediment proton adsorption capacity. Mineral dissolution in acidic solutions (pH2) resulted in a rapid (<10 h) increase in aqueous carbonate (with Ca(2+), Mg(2+)) and phosphate and a slow (100 s of hours) increase in silica, Al(3+), and K(+), likely from 2:1 clay dissolution. Infiltration of uranium with a strong acid resulted in significant shallow uranium mineral dissolution and deeper uranium precipitation (likely as phosphates and carbonates) with downward uranium migration of three times greater mass at a faster velocity relative to uranium infiltration in pH neutral groundwater. In contrast, mineral dissolution in an alkaline environment (pH13) resulted in a rapid (<10h) increase in carbonate, followed by a slow (10 s to 100 s of hours) increase in silica concentration, likely from montmorillonite, muscovite, and kaolinite dissolution. Infiltration of uranium with a strong base resulted in not only uranium-silicate precipitation (presumed Na-boltwoodite) but also desorption of natural uranium on the sediment due to the high ionic strength solution, or 60% greater mass with greater retardation compared with groundwater. Overall, these results show that acidic or alkaline co-contaminant disposal with uranium can result in complex depth- and time-dependent changes in uranium dissolution/precipitation reactions and uranium sorption, which alter the uranium migration mass, concentration, and velocity. Copyright © 2013 Elsevier B.V. All rights reserved.

Process for disposal of aqueous solutions containing radioactive isotopes

DOEpatents

Colombo, Peter; Neilson, Jr., Robert M.; Becker, Walter W.

1979-01-01

A process for disposing of radioactive aqueous waste solutions whereby the waste solution is utilized as the water of hydration to hydrate densified powdered portland cement in a leakproof container; said waste solution being dispersed without mechanical inter-mixing in situ in said bulk cement, thereafter the hydrated cement body is impregnated with a mixture of a monomer and polymerization catalyst to form polymer throughout the cement body. The entire process being carried out while maintaining the temperature of the components during the process at a temperature below 99.degree. C. The container containing the solid polymer-impregnated body is thereafter stored at a radioactive waste storage dump such as an underground storage dump.

Processing industrial wastes with the liquid-phase reduction romelt process

NASA Astrophysics Data System (ADS)

Romenets, V.; Valavin, V.; Pokhvisnev, Yu.; Vandariev, S.

1999-08-01

The Romelt technology for liquid-phase reduction has been developed for processing metallurgical wastes containing nonferrousmetal components. Thermodynamic calculations were made to investigate the behavior of silver, copper, zinc, manganese, vanadium, chrome, and silicon when reduced from the slag melt into the metallic solution containing iron. The process can be applied to all types of iron-bearing wastes, including electric arc furnace dust. The distribution of elements between the phases can be controlled by adjusting the slag bath temperature. Experiments at a pilot Romelt plant proved the possibility of recovering the metallurgical wastes and obtaining iron.

Utilization of Aluminum Waste with Hydrogen and Heat Generation

NASA Astrophysics Data System (ADS)

Buryakovskaya, O. A.; Meshkov, E. A.; Vlaskin, M. S.; Shkolnokov, E. I.; Zhuk, A. Z.

2017-10-01

A concept of energy generation via hydrogen and heat production from aluminum containing wastes is proposed. The hydrogen obtained by oxidation reaction between aluminum waste and aqueous solutions can be supplied to fuel cells and/or infrared heaters for electricity or heat generation in the region of waste recycling. The heat released during the reaction also can be effectively used. The proposed method of aluminum waste recycling may represent a promising and cost-effective solution in cases when waste transportation to recycling plants involves significant financial losses (e.g. remote areas). Experiments with mechanically dispersed aluminum cans demonstrated that the reaction rate in alkaline solution is high enough for practical use of the oxidation process. In theexperiments aluminum oxidation proceeds without any additional aluminum activation.

[Decolorization of dyestuff and dying waste water by laccase solution with self-flocculent mycelial pellets of Coriolus versicolor].

PubMed

Wu, Mianbin; Xia, Liming

2002-06-01

Both laccase production by the white-rot fungus Coriolus versicolor and decolorization of dyestuff and dying waste water with crude solution of laccase were studied in this work. Laccase production meets the definition of secondary metabolism. For laccase production the optimum initial pH is 4.5. Addition of veratryl alcohol or elevated trace metals could both enhance the laccase activity, while Tween80 showed some inhibition. The immobilized mycelia of C. versicolor in polyurethane foam had less laccase production ability than mycelial pellets. A repeated batch cultivation process was found to be a very economical way for laccase harvest. The same pellets could be used for at least 14 times and average laccase activity of each batch could maintain 6.72 IU/mL. This method reduces the enzyme production course, medium consumption and the possibility of contamination, showing high efficient and great economic benefit. Good results were also obtained in decolorization experiments with the crude solution of laccase. With 3.3 IU/mL initial laccase activity, color removal of Acid Orange reached 98.5% after 24 h reaction. Also with 2.6 IU/mL initial laccase activity, color removal of dying waste water reached 93% after 24 h reaction.

A-Way with Waste. A Waste Management Curriculum for Schools. Second Edition.

ERIC Educational Resources Information Center

Peterson, Todd; And Others

Designed to address the problems and solutions related to waste management, this curriculum guide contains interdisciplinary activities for K-12 students in Washington State schools. Listings of the activities are provided by concept categories (under the themes of revise, reuse, recycle, and recover); by waste management subject area (addressing…

Consolidation and Centralization of Waste Operations Business Systems - 12319

DOE Office of Scientific and Technical Information (OSTI.GOV)

Newton, D. Dean

This abstract provides a comprehensive plan supporting the continued development and integration of all waste operations and waste management business systems. These include existing systems such as ATMS (Automated Transportation Management System), RadCalc, RFITS (Radio Frequency Identification Transportation System) Programs as well as incorporating key components of existing government developed waste management systems and COTS (Computer Off The Shelf) applications in order to deliver a truly integrated waste tracking and management business system. Some of these existing systems to be integrated include IWTS at Idaho National Lab, WIMS at Sandia National Lab and others. The aggregation of data and consolidationmore » into a single comprehensive business system delivers best practices in lifecycle waste management processes to be delivered across the Department of Energy facilities. This concept exists to reduce operational costs to the federal government by combining key business systems into a centralized enterprise application following the methodology that as contractors change, the tools they use to manage DOE's assets do not. IWITS is one efficient representation of a sound architecture currently supporting multiple DOE sites from a waste management solution. The integration of ATMS, RadCalc and RFITS and the concept like IWITS into a single solution for DOE contractors will result in significant savings and increased efficiencies for DOE. Building continuity and solving collective problems can only be achieved through mass collaboration, resulting in an online community that DOE contractors and subcontractors access common applications, allowing for the collection of business intelligence at an unprecedented level. This is a fundamental shift from a solely 'for profit' business model to a 'for purpose' business model. To the conventional-minded, putting values before profit is an unfamiliar and unnatural way for a contractor to operate - unless however

Precipitation-adsorption process for the decontamination of nuclear waste supernates

DOEpatents

Lee, Lien-Mow; Kilpatrick, Lester L.

1984-01-01

High-level nuclear waste supernate is decontaminated of cesium by precipitation of the cesium and potassium with sodium tetraphenyl boron. Simultaneously, strontium-90 is removed from the waste supernate sorption of insoluble sodium titanate. The waste solution is then filtered to separate the solution decontaminated of cesium and strontium.

Precipitation-adsorption process for the decontamination of nuclear waste supernates

DOEpatents

Lee, L.M.; Kilpatrick, L.L.

1982-05-19

High-level nuclear waste supernate is decontaminated of cesium by precipitation of the cesium and potassium with sodium tetraphenyl boron. Simultaneously, strontium-90 is removed from the waste supernate sorption of insoluble sodium titanate. The waste solution is then filtered to separate the solution decontaminated of cesium and strontium.

40 CFR 62.14431 - What must my waste management plan include?

Code of Federal Regulations, 2013 CFR

2013-07-01

.... In developing your waste management plan, you must consider the American Hospital Association (AHA... publication (AHA Catalog Number 057007) is available for purchase from AHA Services, Inc., Post Office Box...

40 CFR 62.14431 - What must my waste management plan include?

Code of Federal Regulations, 2014 CFR

2014-07-01

.... In developing your waste management plan, you must consider the American Hospital Association (AHA... publication (AHA Catalog Number 057007) is available for purchase from AHA Services, Inc., Post Office Box...

Household Hazardous Waste: Everyone's Problem--Everyone's Solution.

ERIC Educational Resources Information Center

Evenson, Linda

1985-01-01

Examines the household hazardous waste problem, addressing several areas related to regulation, disposal, and control. Also gives a list of safer alternatives for household cleaners/disinfectants, paint products, and pesticides. Indicates that individuals can collectively make a difference in public exposure by changing purchases and practices.…

78 FR 14773 - U.S. Environmental Solutions Toolkit-Medical Waste

Federal Register 2010, 2011, 2012, 2013, 2014

2013-03-07

...--Medical Waste AGENCY: International Trade Administration, DOC. ACTION: Notice and Request for Comment... or services relevant to management of medical waste. The Department of Commerce continues to develop... foreign end-users of environmental technologies that will outline U.S. approaches to a series of...

Reuse of waste beer yeast sludge for biosorptive decolorization of reactive blue 49 from aqueous solution.

PubMed

Wang, Baoe; Guo, Xiu

2011-06-01

Reactive blue 49 was removed from aqueous solution by biosorption using powder waste sludge composed of Saccharomyces cerevisiae from the beer-brewing industry. The effect of initial pH, temperature and the biosorption thermodynamics, equilibrium, kinetics was investigated in this study. It was found that the biosorption capacity was at maximum at initial pH 3, that the effect of temperature on biosorption of reactive blue 49 was only slight in relation to the large biosorption capacity (25°C, 361 mg g(-1)) according as the biosorption capacity decreased only 43 mg g(-1) at the temperature increased from 25 to 50°C. The biosorption was spontaneous, exothermic in nature and the dye molecules movements decreased slightly in random at the solid/liquid interface during the biosorption of dye on biosorbents. The biosorption equilibrium data could be described by Freundich isotherm model. The biosorption rates were found to be consistent with a pseudo-second-order kinetics model. The functional group interaction analysis between waste beer yeast sludge and reactive blue 49 by the aid of Fourier transform infrared (abbr. FTIR) spectroscopy indicated that amino components involved in protein participated in the biosorption process, which may be achieved by the mutual electrostatic adsorption process between the positively charged amino groups in waste beer yeast sludge with negatively charged sulfonic groups in reactive blue 49.

BLENDING ANALYSIS FOR RADIOACTIVE SALT WASTE PROCESSING FACILITY

DOE Office of Scientific and Technical Information (OSTI.GOV)

Lee, S.

2012-05-10

Savannah River National Laboratory (SRNL) evaluated methods to mix and blend the contents of the blend tanks to ensure the contents are properly blended before they are transferred from the blend tank such as Tank 21 and Tank 24 to the Salt Waste Processing Facility (SWPF) feed tank. The tank contents consist of three forms: dissolved salt solution, other waste salt solutions, and sludge containing settled solids. This paper focuses on developing the computational model and estimating the operation time of submersible slurry pump when the tank contents are adequately blended prior to their transfer to the SWPF facility. Amore » three-dimensional computational fluid dynamics approach was taken by using the full scale configuration of SRS Type-IV tank, Tank 21H. Major solid obstructions such as the tank wall boundary, the transfer pump column, and three slurry pump housings including one active and two inactive pumps were included in the mixing performance model. Basic flow pattern results predicted by the computational model were benchmarked against the SRNL test results and literature data. Tank 21 is a waste tank that is used to prepare batches of salt feed for SWPF. The salt feed must be a homogeneous solution satisfying the acceptance criterion of the solids entrainment during transfer operation. The work scope described here consists of two modeling areas. They are the steady state flow pattern calculations before the addition of acid solution for tank blending operation and the transient mixing analysis during miscible liquid blending operation. The transient blending calculations were performed by using the 95% homogeneity criterion for the entire liquid domain of the tank. The initial conditions for the entire modeling domain were based on the steady-state flow pattern results with zero second phase concentration. The performance model was also benchmarked against the SRNL test results and literature data.« less

Preparation of porous carbon sphere from waste sugar solution for electric double-layer capacitor

NASA Astrophysics Data System (ADS)

Hao, Zhi-Qiang; Cao, Jing-Pei; Wu, Yan; Zhao, Xiao-Yan; Zhuang, Qi-Qi; Wang, Xing-Yong; Wei, Xian-Yong

2017-09-01

Waste sugar solution (WSS), which contains abundant 2-keto-L-gulonic acid, is harmful to the environment if discharged directly. For value-added utilization of the waste resource, a novel process is developed for preparation of porous carbon spheres by hydrothermal carbonization (HTC) of WSS followed by KOH activation. Additionally, the possible preparation mechanism of carbon spheres is proposed. The effects of hydrothermal and activation parameters on the properties of the carbon sphere are also investigated. The carbon sphere is applied to electric double-layer capacitor and its electrochemical performance is studied. These results show that the carbon sphere obtained by HTC at 180 °C for 12 h with the WSS/deionized water volume ratio of 2/3 possess the highest specific capacitance under identical activation conditions. The specific capacitance of the carbon spheres can reach 296.1 F g-1 at a current density of 40 mA g-1. Besides, excellent cycle life and good capacitance retention (89.6%) are observed at 1.5 A g-1 after 5000 cycles. This study not only provides a facile and potential method for the WSS treatment, but also achieves the high value-added recycling of WSS for the preparation of porous carbon spheres with superior electrochemical properties.

Impact assessment of waste management options in Singapore.

PubMed

Tan, Reginald B H; Khoo, Hsien H

2006-03-01

This paper describes the application of life cycle assessment for evaluating various waste management options in Singapore, a small-island city state. The impact assessment method by SimaPro is carried out for comparing the potential environmental impacts of waste treatment options including landfilling, incineration, recycling, and composting. The inventory data include gases and leachate from landfills, air emissions and energy recovery from incinerators, energy (and emission) savings from recycling, composting gases, and transport pollution. The impact assessment results for climate change, acidification, and ecotoxicity show that the incineration of materials imposes considerable harm to both human health and the environment, especially for the burning of plastics, paper/cardboard, and ferrous metals. The results also show that, although some amount of energy can be derived from the incineration of wastes, these benefits are outweighed by the air pollution (heavy metals and dioxins/furans) that incinerators produce. For Singapore, landfill gases and leachate generate minimal environmental damage because of the nation's policy to landfill only 10% of the total disposed wastes. Land transportation and separation of waste materials also pose minimal environmental damage. However, sea transportation to the landfill could contribute significantly to acidification because of the emissions of sulfur oxides and nitrogen oxides from barges. The composting of horticultural wastes hardly imposes any environmental damage. Out of all the waste strategies, the recycling of wastes offers the best solution for environmental protection and improved human health for the nation. Significant emission savings can be realized through recycling.

78 FR 48467 - Delphi Automotive Systems, LLC, Products and Service Solutions Division, Including On-Site Leased...

Federal Register 2010, 2011, 2012, 2013, 2014

2013-08-08

... amending this certification to include all workers of Delphi Automotive Systems, LLC, Product and Service..., LLC, Products and Service Solutions Division, Including On-Site Leased Workers From Bartech Workforce Management, Kokomo, Indiana; Amended Certification Regarding Eligibility To Apply for Worker Adjustment...

Yucca Mountain, Nevada - A proposed geologic repository for high-level radioactive waste

USGS Publications Warehouse

Levich, R.A.; Stuckless, J.S.

2006-01-01

Yucca Mountain in Nevada represents the proposed solution to what has been a lengthy national effort to dispose of high-level radioactive waste, waste which must be isolated from the biosphere for tens of thousands of years. This chapter reviews the background of that national effort and includes some discussion of international work in order to provide a more complete framework for the problem of waste disposal. Other chapters provide the regional geologic setting, the geology of the Yucca Mountain site, the tectonics, and climate (past, present, and future). These last two chapters are integral to prediction of long-term waste isolation. ?? 2007 Geological Society of America. All rights reserved.

Thermal and chemical remediation of mixed wastes

DOEpatents

Nelson, Paul A.; Swift, William M.

1997-01-01

A process for treating organic waste materials without venting gaseous emissions to the atmosphere which includes oxidizing the organic waste materials at an elevated temperature not less than about 500.degree. C. with a gas having an oxygen content in the range of from about 20% to about 70% to produce an oxidation product containing CO.sub.2 gas. The gas is then filtered to remove particulates, and then contacted with an aqueous absorbent solution of alkali metal carbonates or alkanolamines to absorb a portion of the CO.sub.2 gas from the particulate-free oxidation product. The CO.sub.2 absorbent is thereafter separated for further processing. A process and system are also disclosed in which the waste materials are contacted with a reactive medium such as lime and product treatment as described.

WASTE ISOLATION PILOT PLANT (WIPP): THE NATIONS' SOLUTION TO NUCLEAR WASTE STORAGE AND DISPOSAL ISSUES

DOE Office of Scientific and Technical Information (OSTI.GOV)

Lopez, Tammy Ann

2014-07-17

In the southeastern portion of my home state of New Mexico lies the Chihuahauan desert, where a transuranic (TRU), underground disposal site known as the Waste Isolation Pilot Plant (WIPP) occupies 16 square miles. Full operation status began in March 1999, the year I graduated from Los Alamos High School, in Los Alamos, NM, the birthplace of the atomic bomb and one of the nation’s main TRU waste generator sites. During the time of its development and until recently, I did not have a full grasp on the role Los Alamos was playing in regards to WIPP. WIPP is usedmore » to store and dispose of TRU waste that has been generated since the 1940s because of nuclear weapons research and testing operations that have occurred in Los Alamos, NM and at other sites throughout the United States (U.S.). TRU waste consists of items that are contaminated with artificial, man-made radioactive elements that have atomic numbers greater than uranium, or are trans-uranic, on the periodic table of elements and it has longevity characteristics that may be hazardous to human health and the environment. Therefore, WIPP has underground rooms that have been carved out of 2,000 square foot thick salt formations approximately 2,150 feet underground so that the TRU waste can be isolated and disposed of. WIPP has operated safely and successfully until this year, when two unrelated events occurred in February 2014. With these events, the safety precautions and measures that have been operating at WIPP for the last 15 years are being revised and improved to ensure that other such events do not occur again.« less

Food waste generation and industrial uses: A review.

PubMed

Girotto, Francesca; Alibardi, Luca; Cossu, Raffaello

2015-11-01

Food waste is made up of materials intended for human consumption that are subsequently discharged, lost, degraded or contaminated. The problem of food waste is currently on an increase, involving all sectors of waste management from collection to disposal; the identifying of sustainable solutions extends to all contributors to the food supply chains, agricultural and industrial sectors, as well as retailers and final consumers. A series of solutions may be implemented in the appropriate management of food waste, and prioritised in a similar way to waste management hierarchy. The most sought-after solutions are represented by avoidance and donation of edible fractions to social services. Food waste is also employed in industrial processes for the production of biofuels or biopolymers. Further steps foresee the recovery of nutrients and fixation of carbon by composting. Final and less desirable options are incineration and landfilling. A considerable amount of research has been carried out on food waste with a view to the recovery of energy or related products. The present review aims to provide an overview of current debate on food waste definitions, generation and reduction strategies, and conversion technologies emerging from the biorefinery concept. Copyright © 2015 Elsevier Ltd. All rights reserved.

Progresses in Polystyrene Biodegradation and Prospects for Solutions to Plastic Waste Pollution

NASA Astrophysics Data System (ADS)

Yang, S. S.; Brandon, A. M.; Xing, D. F.; Yang, J.; Pang, J. W.; Criddle, C. S.; Ren, N. Q.; Wu, W. M.

2018-05-01

Petroleum-based plastic pollution has been a global environmental concern for decades. The obvious contrast between the remarkable durability of the plastics and their short service time leads to the increasing accumulation of plastic wastes in the environment. A cost-effective, sustainable strategy to solve the problem should focus on source control and clean up. Polystyrene (PS) wastes, a recalcitrant plastic polymer, are among the wide spread man-made plastic pollutants. Destruction of PS wastes can be achieved using various abiotic methods such as incineration but such methods release potential air pollution and generation of hazardous by-products. Biodegradation and bioremediation has been proposed for years. Since the 1970’s, the microbial biodegradation of plastics, including PS, has been evaluated with mixed and isolated cultures from different sources such as activated sludge, trash, soil, and manure. To date, PS biodegradation by these microbial cultures is still quite slow. Recently, the larvae of yellow mealworms (Tenebrio molitor Linnaeus) have demonstrated promising PS biodegradation performance. Mealworms have demonstrated the ability to chew and ingest PS foam as food and are capable of degrading and mineralizing PS into CO2 via microbe-dependent activities within the gut in less than the 12-15 hrs gut retention time. These research results have revealed a potential for microbial biodegradation and bioremediation of plastic pollutants.

Thermodynamic model for uranium release from hanford site tank residual waste.

PubMed

Cantrell, Kirk J; Deutsch, William J; Lindberg, Mike J

2011-02-15

A thermodynamic model of U solid-phase solubility and paragenesis was developed for Hanford Site tank residual waste that will remain in place after tank closure. The model was developed using a combination of waste composition data, waste leach test data, and thermodynamic modeling of the leach test data. The testing and analyses were conducted using actual Hanford Site tank residual waste. Positive identification of U phases by X-ray diffraction was generally not possible either because solids in the waste were amorphous or their concentrations were not detectable by XRD for both as-received and leached residual waste. Three leachant solutions were used in the studies: deionized water, CaCO3 saturated solution, and Ca(OH)2 saturated solution. Analysis of calculated saturation indices indicate that NaUO2PO4·xH2O and Na2U2O7(am) are present in the residual wastes initially. Leaching of the residual wastes with deionized water or CaCO3 saturated solution results in preferential dissolution Na2U2O7(am) and formation of schoepite. Leaching of the residual wastes with Ca(OH)2 saturated solution appears to result in transformation of both NaUO2PO4·xH2O and Na2U2O7(am) to CaUO4. Upon the basis of these results, the paragenetic sequence of secondary phases expected to occur as leaching of residual waste progresses for two tank closure scenarios was identified.

Implementation of spatial smart waste management system in malaysia

NASA Astrophysics Data System (ADS)

Omar, M. F.; Termizi, A. A. A.; Zainal, D.; Wahap, N. A.; Ismail, N. M.; Ahmad, N.

2016-06-01

One of the challenges to innovate and create an IoT -enabled solution is in monitoring and management of the environment. Waste collection utilizing the Internet of Things (IoT) with the technology of smart wireless sensors will able to gather fill-level data from waste containers hence providing a waste monitoring solution that brings up savings in waste collection costs. One of the challenges to the local authority is how to monitor the works of contractor effective and efficiently in waste management. This paper will propose to the local authority the implementation of smart waste management in Malaysia to improve the city management and to provide better services to the public towards smart city applications.

Removal of mercury from aqueous solutions using activated carbon prepared from agricultural by-product/waste.

PubMed

Rao, M Madhava; Reddy, D H K Kumar; Venkateswarlu, Padala; Seshaiah, K

2009-01-01

Removal of mercury from aqueous solutions using activated carbon prepared from Ceiba pentandra hulls, Phaseolus aureus hulls and Cicer arietinum waste was investigated. The influence of various parameters such as effect of pH, contact time, initial metal ion concentration and adsorbent dose for the removal of mercury was studied using a batch process. The experiments demonstrated that the adsorption process corresponds to the pseudo-second-order-kinetic models and the equilibrium adsorption data fit the Freundlich isotherm model well. The prepared adsorbents ACCPH, ACPAH and ACCAW had removal capacities of 25.88 mg/g, 23.66 mg/g and 22.88 mg/g, respectively, at an initial Hg(II) concentration of 40 mg/L. The order of Hg(II) removal capacities of these three adsorbents was ACCPH>ACPAH>ACCAW. The adsorption behavior of the activated carbon is explained on the basis of its chemical nature. The feasibility of regeneration of spent activated carbon adsorbents for recovery of Hg(II) and reuse of the adsorbent was determined using HCl solution.

Revolutionary advances in medical waste management. The Sanitec system.

PubMed

Edlich, Richard F; Borel, Lise; Jensen, H Gordon; Winters, Kathryne L; Long, William B; Gubler, K Dean; Buschbacher, Ralph M; Becker, Daniel G; Chang, Dillon E; Korngold, Jonathan; Chitwood, W Randolph; Lin, Kant Y; Nichter, Larry S; Berenson, Susan; Britt, L D; Tafel, John A

2006-01-01

It is the purpose of this collective review to provide a detailed outline of a revolutionary medical waste disposal system that should be used in all medical centers in the world to prevent pollution of our planet from medical waste. The Sanitec medical waste disposal system consists of the following seven components: (1) an all-weather steel enclosure of the waste management system, allowing it to be used inside or outside of the hospital center; (2) an automatic mechanical lift-and-load system that protects the workers from devastating back injuries; (3) a sophisticated shredding system designed for medical waste; (4) a series of air filters including the High Efficiency Particulate Air (HEPA) filter; (5) microwave disinfection of the medical waste material; (6) a waste compactor or dumpster; and (7) an onboard microprocessor. It must be emphasized that this waste management system can be used either inside or outside the hospital. From start to finish, the Sanitec Microwave Disinfection system is designed to provide process and engineering controls that assure complete disinfection and destruction, while minimizing the operator's exposure to risk. There are numerous technologic benefits to the Sanitec systems, including environmental, operational, physical, and disinfection efficiency as well as waste residue disinfection. Wastes treated through the Sanitec system are thoroughly disinfected, unrecognizable, and reduced in volume by approximately 80% (saving valuable landfill space and reducing hauling requirements and costs). They are acceptable in any municipal solid waste program. Sanitec's Zero Pollution Advantage is augmented by a complete range of services, including installation, startup, testing, training, maintenance, and repair, over the life of this system. The Sanitec waste management system has essentially been designed to provide the best overall solution to the customer, when that customer actually looks at the total cost of dealing with the

Nitric acid recovery from waste solutions

DOEpatents

Wilson, A. S.

1959-04-14

The recovery of nitric acid from aqueous nitrate solutions containing fission products as impurities is described. It is desirable to subject such solutions to concentration by evaporation since nitric acid is regenerated thereby. A difficulty, however, is that the highly radioactive fission product ruthenium is volatilized together with the nitric acid. It has been found that by adding nitrous acid, ruthenium volatilization is suppressed and reduced to a negligible degree so that the distillate obtained is practically free of ruthenium.

Hazardous waste management system design under population and environmental impact considerations.

PubMed

Yilmaz, Ozge; Kara, Bahar Y; Yetis, Ulku

2017-12-01

This paper presents a multi objective mixed integer location/routing model that aims to minimize transportation cost and risks for large-scale hazardous waste management systems (HWMSs). Risks induced by hazardous wastes (HWs) on both public and the environment are addressed. For this purpose, a new environmental impact definition is proposed that considers the environmentally vulnerable elements including water bodies, agricultural areas, coastal regions and forestlands located within a certain bandwidth around transportation routes. The solution procedure yields to Pareto optimal curve for two conflicting objectives. The conceptual model developed prior to mathematical formulation addresses waste-to-technology compatibility and HW processing residues to assure applicability of the model to real-life HWMSs. The suggested model was used in a case study targeting HWMS in Turkey. Based on the proposed solution, it was possible to identify not only the transportation routes but also a set of information on HW handling facilities including the types, locations, capacities, and investment/operational cost. The HWMS of this study can be utilized both by public authorities and private sector investors for planning purposes. Copyright © 2016 Elsevier Ltd. All rights reserved.

Management of hazardous medical waste in Croatia.

PubMed

Marinković, Natalija; Vitale, Ksenija; Janev Holcer, Natasa; Dzakula, Aleksandar; Pavić, Tomo

2008-01-01

This article provides a review of hazardous medical waste production and its management in Croatia. Even though Croatian regulations define all steps in the waste management chain, implementation of those steps is one of the country's greatest issues. Improper practice is evident from the point of waste production to final disposal. The biggest producers of hazardous medical waste are hospitals that do not implement existing legislation, due to the lack of education and funds. Information on quantities, type and flow of medical waste are inadequate, as is sanitary control. We propose an integrated approach to medical waste management based on a hierarchical structure from the point of generation to its disposal. Priority is given to the reduction of the amounts and potential for harm. Where this is not possible, management includes reduction by sorting and separating, pretreatment on site, safe transportation, final treatment and sanitary disposal. Preferred methods should be the least harmful for human health and the environment. Integrated medical waste management could greatly reduce quantities and consequently financial strains. Landfilling is the predominant route of disposal in Croatia, although the authors believe that incineration is the most appropriate method. In a country such as Croatia, a number of small incinerators would be the most economical solution.

Economic and environmental optimization of waste treatment

DOE Office of Scientific and Technical Information (OSTI.GOV)

Münster, M.; Ravn, H.; Hedegaard, K.

2015-04-15

Highlights: • Optimizing waste treatment by incorporating LCA methodology. • Applying different objectives (minimizing costs or GHG emissions). • Prioritizing multiple objectives given different weights. • Optimum depends on objective and assumed displaced electricity production. - Abstract: This article presents the new systems engineering optimization model, OptiWaste, which incorporates a life cycle assessment (LCA) methodology and captures important characteristics of waste management systems. As part of the optimization, the model identifies the most attractive waste management options. The model renders it possible to apply different optimization objectives such as minimizing costs or greenhouse gas emissions or to prioritize several objectivesmore » given different weights. A simple illustrative case is analysed, covering alternative treatments of one tonne of residual household waste: incineration of the full amount or sorting out organic waste for biogas production for either combined heat and power generation or as fuel in vehicles. The case study illustrates that the optimal solution depends on the objective and assumptions regarding the background system – illustrated with different assumptions regarding displaced electricity production. The article shows that it is feasible to combine LCA methodology with optimization. Furthermore, it highlights the need for including the integrated waste and energy system into the model.« less

78 FR 48468 - M/A-Com Technology Solutions, Including On-Site Leased Workers of Kelly Temps and Aerotek CE...

Federal Register 2010, 2011, 2012, 2013, 2014

2013-08-08

...-W-82,242 is hereby issued as follows: All workers of M/A-Com Technology Solutions, including on-site... DEPARTMENT OF LABOR Employment and Training Administration [TA-W-80,242; TA-W-80,242A] M/A-Com.../A-Com Technology Solutions, Including On-Site Leased Workers of Kelly Temps and Aerotek CE, Long...

Molten salt oxidation: a versatile and promising technology for the destruction of organic-containing wastes.

PubMed

Yao, Zhitong; Li, Jinhui; Zhao, Xiangyang

2011-08-01

Molten salt oxidation (MSO), a robust thermal but non-flame process, has the inherent capability of destroying organic constituents in wastes, while retaining inorganic and radioactive materials in situ. It has been considered as an alternative to incineration and may be a solution to many waste disposal problems. The present review first describes the history and development of MSO, as well as design and engineering details, and then focuses on reaction mechanisms and its potential applications in various wastes, including hazardous wastes, medical wastes, mixed wastes, and energetic materials. Finally, the current status of and prospects for the MSO process and directions for future research are considered. Copyright © 2011 Elsevier Ltd. All rights reserved.

Closed-form solutions for linear regulator design of mechanical systems including optimal weighting matrix selection

NASA Technical Reports Server (NTRS)

Hanks, Brantley R.; Skelton, Robert E.

1991-01-01

Vibration in modern structural and mechanical systems can be reduced in amplitude by increasing stiffness, redistributing stiffness and mass, and/or adding damping if design techniques are available to do so. Linear Quadratic Regulator (LQR) theory in modern multivariable control design, attacks the general dissipative elastic system design problem in a global formulation. The optimal design, however, allows electronic connections and phase relations which are not physically practical or possible in passive structural-mechanical devices. The restriction of LQR solutions (to the Algebraic Riccati Equation) to design spaces which can be implemented as passive structural members and/or dampers is addressed. A general closed-form solution to the optimal free-decay control problem is presented which is tailored for structural-mechanical system. The solution includes, as subsets, special cases such as the Rayleigh Dissipation Function and total energy. Weighting matrix selection is a constrained choice among several parameters to obtain desired physical relationships. The closed-form solution is also applicable to active control design for systems where perfect, collocated actuator-sensor pairs exist.

Thermal and chemical remediation of mixed wastes

DOEpatents

Nelson, P.A.; Swift, W.M.

1997-12-16

A process is described for treating organic waste materials without venting gaseous emissions to the atmosphere which includes oxidizing the organic waste materials at an elevated temperature not less than about 500 C with a gas having an oxygen content in the range of from about 20% to about 70% to produce an oxidation product containing CO{sub 2} gas. The gas is then filtered to remove particulates, and then contacted with an aqueous absorbent solution of alkali metal carbonates or alkanolamines to absorb a portion of the CO{sub 2} gas from the particulate-free oxidation product. The CO{sub 2} absorbent is thereafter separated for further processing. A process and system are also disclosed in which the waste materials are contacted with a reactive medium such as lime and product treatment as described. 8 figs.

Industrial Program of Waste Management - Cigeo Project - 13033

DOE Office of Scientific and Technical Information (OSTI.GOV)

Butez, Marc; Bartagnon, Olivier; Gagner, Laurent

2013-07-01

The French Planning Act of 28 June 2006 prescribed that a reversible repository in a deep geological formation be chosen as the reference solution for the long-term management of high-level and intermediate-level long-lived radioactive waste. It also entrusted the responsibility of further studies and design of the repository (named Cigeo) upon the French Radioactive Waste Management Agency (Andra), in order for the review of the creation-license application to start in 2015 and, subject to its approval, the commissioning of the repository to take place in 2025. Andra is responsible for siting, designing, implementing, operating the future geological repository, including operationalmore » and long term safety and waste acceptance. Nuclear operators (Electricite de France (EDF), AREVA NC, and the French Commission in charge of Atomic Energy and Alternative Energies (CEA) are technically and financially responsible for the waste they generate, with no limit in time. They provide Andra, on one hand, with waste packages related input data, and on the other hand with their long term industrial experiences of high and intermediate-level long-lived radwaste management and nuclear operation. Andra, EDF, AREVA and CEA established a cooperation agreement for strengthening their collaborations in these fields. Within this agreement Andra and the nuclear operators have defined an industrial program for waste management. This program includes the waste inventory to be taken into account for the design of the Cigeo project and the structural hypothesis underlying its phased development. It schedules the delivery of the different categories of waste and defines associated flows. (authors)« less

Electrical efficiency in modern waste to energy plants -- The advanced solutions adopted in a new Italian plant (Milan)

DOE Office of Scientific and Technical Information (OSTI.GOV)

Lucchini, F.M.; Pezzella, B.

1998-07-01

The paper has the goal to give a general overview of the current approach for the design of modern Waste to Energy (WtE) plants. The thermal treatment of solid waste is an environmentally sound method to get rid of the garbage produced by everyone and to recover energy simultaneously. A typical waste to energy plant is divided in four segments: incineration/boiler, air pollution control, residues treatment and power generation. Still in the 80's a WtE plant was simply consisting of a these four segments without any particular effort in putting them together into a coordinated plant; therefore the results weremore » very poor in term of overall plant performances even if the single segments were properly designed. This paper shows how this approach is changing and how the synergism between the segments allows to reach interesting performances in term of electric efficiency, always keeping in mind that power must be considered a by-product of the incinerator. Therefore all these efforts have to be done without affecting the burning capacity of the station. The new Milan WtE plant is taken as example throughout the paper. The first section of the paper tries to consider the Municipal Solid Waste as standard fuel; then focal point becomes the electrical efficiency of the plant. In the fourth section the flue gas cleaning system is approached, pointing out the gas quality at stack. Then in the fifth and sixth paragraphs all most important and innovative technical solutions of the Milan plant are shown with some details on water/steam cycle, giving also some availability results. Chapter seven shows some interesting key-figures, related to the combustion of 1,000 kg of MSW at 11 MJ/kg, with also some economical evaluations in term of investment cost per ton of waste per day.« less

Geochemical features of the utilization of buried wastes of the Tyrnyauz Tungsten-Molybdenum Plant using acid leaching

NASA Astrophysics Data System (ADS)

Vinokurov, S. F.; Gurbanov, A. G.; Bogatikov, O. A.; Sychkova, V. A.; Shevchenko, A. V.; Lexin, A. B.; Dudarov, Z. I.

2016-10-01

The decontamination of buried wastes of the Tyrnyauz Tungsten-Molybdenum Plant is complicated by the geochemical features of the waste composition: low sulfide and high carbonate content, polyelemental composition, and considerable amounts of technogenic admixtures (kerosene, oils, soda, and soluble glasses). These circumstances result in sufficient complication of the suggested technology of waste treatment, including the sulfuric-acid leaching and separate sorption recovery of hazardous and useful elements from the working solution.

Waste to biodiesel: A preliminary assessment for Saudi Arabia.

PubMed

Rehan, M; Gardy, J; Demirbas, A; Rashid, U; Budzianowski, W M; Pant, Deepak; Nizami, A S

2018-02-01

This study presents a preliminary assessment of biodiesel production from waste sources available in the Kingdom of Saudi Arabia (KSA) for energy generation and solution for waste disposal issues. A case study was developed under three different scenarios: (S1) KSA population only in 2017, (S2) KSA population and pilgrims in 2017, and (S3) KSA population and pilgrims by 2030 using the fat fraction of the municipal solid waste. It was estimated that S1, S2, and S3 scenarios could produce around 1.08, 1.10 and 1.41 million tons of biodiesel with the energy potential of 43423, 43949 and 56493 TJ respectively. Furthermore, annual savings of US $55.89, 56.56 and 72.71 million can be generated from landfill diversion of food waste and added to the country's economy. However, there are challenges in commercialization of waste to biodiesel facilities in KSA, including waste collection and separation, impurities, reactor design and biodiesel quality. Copyright © 2017 Elsevier Ltd. All rights reserved.

The mixed low-level waste problem in BE/NWN capsule

DOE Office of Scientific and Technical Information (OSTI.GOV)

Hensley, D.C.

1999-07-01

The Boh Environmental, LLC (BE) and Northwest Nuclear, LLC (NWN) program addresses the problem of diminishing capacity in the United States to store mixed waste. A lack of an alternative program has caused the US Department of Energy (DOE) to indefinitely store all of its mixed waste in Resource Conservation and Recovery Act (RCRA) compliant storage facilities. Unfortunately, this capacity is fast approaching the administrative control limit. The combination of unique BE encapsulation and NWN waste characterization technologies provides an effective solution to DOE's mixed-waste dilemma. The BE ARROW-PAK technique encapsulates mixed low-level waste (MLLW) in extra-high molecular weight, high-densitymore » polyethylene, pipe-grade resin cylinders. ARROW-PAK applications include waste treatment, disposal, transportation (per 49 CFR 173), vault encasement, and interim/long-term storage for 100 to 300 yr. One of the first demonstrations of this treatment/storage technique successfully treated 880 mixed-waste debris drums at the DOE Hanford Site in 1997. NWN, deploying the APNea neutron assay technology, provides the screening and characterization capability necessary to ensure that radioactive waste is correctly categorized as either transuranic (TRU) or LLW. MLLW resulting from D and D activities conducted at the Oak Ridge East Tennessee Technology Park will be placed into ARROW-PAK containers following comprehensive characterization of the waste by NWN. The characterized and encapsulated waste will then be shipped to a commercial disposal facility, where the shipments meet all waste acceptance criteria of the disposal facility including treatment criteria.« less

Adsorptive removal of Cu(II) from aqueous solution and industrial effluent using natural/agricultural wastes.

PubMed

Singha, Biswajit; Das, Sudip Kumar

2013-07-01

The potentiality of low cost natural/agricultural waste biomasses for the removal of Cu(II) ion from aqueous solution has been investigated in batch experiments. The effect of various physico-chemical parameters such as initial pH, initial Cu(II) concentration, adsorbent dosage, contact time and temperature has been studied. The optimum pH for adsorption was found to be 6 for all adsorbents used. Kinetics data were best described by the pseudo-2nd-order model. The experimental data were fitted well with Freundlich and Halsey isotherm models. The diffusion coefficient and sorption energy indicated that the adsorption process was chemical in nature. Thermodynamic parameters such as ΔG°, ΔH° and ΔS° were calculated, and it was observed that the adsorption process was spontaneous and endothermic. The mean sorption energy was calculated using Dubinin-Radushkevich isotherm model and it confirmed that the sorption process was chemical in nature. Different active functional groups were identified by FTIR studies which were responsible for Cu(II) ion adsorption process. Application study using electroplating industrial waste water and regeneration experiment of the adsorbent were also investigated. Design procedure for the batch process was also reported. Copyright © 2013 Elsevier B.V. All rights reserved.

Construction materials as a waste management solution for cellulose sludge

DOE Office of Scientific and Technical Information (OSTI.GOV)

Modolo, R., E-mail: regina.modolo@ua.pt; Ferreira, V.M.; Machado, L.M.

2011-02-15

Sustainable waste management system for effluents treatment sludge has been a pressing issue for pulp and paper sector. Recycling is always recommended in terms of environmental sustainability. Following an approach of waste valorisation, this work aims to demonstrate the technical viability of producing fiber-cement roof sheets incorporating cellulose primary sludge generated on paper and pulp mills. From the results obtained with preliminary studies it was possible to verify the possibility of producing fiber-cement sheets by replacing 25% of the conventional used virgin long fiber by primary effluent treatment cellulose sludge. This amount of incorporation was tested on an industrial scale.more » Environmental parameters related to water and waste, as well as tests for checking the quality of the final product was performed. These control parameters involved total solids in suspension, dissolved salts, chlorides, sulphates, COD, metals content. In the product, parameters like moisture, density and strength were controlled. The results showed that it is possible to replace the virgin long fibers pulp by primary sludge without impacts in final product characteristics and on the environment. This work ensures the elimination of significant waste amounts, which are nowadays sent to landfill, as well as reduces costs associated with the standard raw materials use in the fiber-cement industrial sector.« less

76 FR 72978 - Whirlpool Corporation Including On-Site Leased Workers From Career Solutions TEC Staffing...

Federal Register 2010, 2011, 2012, 2013, 2014

2011-11-28

..., TEK Systems, Penske Logistics, Eurest, and Canteen, Fort Smith, AR; Amended Certification Regarding... Corporation, including on-site leased workers from Career Solutions TEC Staffing, Fort Smith, Arkansas. The... Corporation, TEK Systems, Penske Logistics, Eurest, and Canteen were employed on-site at the Fort Smith...

Reclamation of zinc-contaminated soil using a dissolved organic carbon solution prepared using liquid fertilizer from food-waste composting.

PubMed

Chiang, Po-Neng; Tong, Ou-Yang; Chiou, Chyow-San; Lin, Yu-An; Wang, Ming-Kuang; Liu, Cheng-Chung

2016-01-15

A liquid fertilizer obtained through food-waste composting can be used for the preparation of a dissolved organic carbon (DOC) solution. In this study, we used the DOC solutions for the remediation of a Zn-contaminated soil (with Zn concentrations up to 992 and 757 mg kg(-1) in topsoil and subsoil, respectively). We then determined the factors that affect Zn removal, such as pH, initial concentration of DOC solution, and washing frequency. Measurements using a Fourier Transform infrared spectrometer (FT-IR) revealed that carboxyl and amide were the major functional groups in the DOC solution obtained from the liquid fertilizer. Two soil washes using 1,500 mg L(-1) DOC solution with a of pH 2.0 at 25°C removed about 43% and 21% of the initial Zn from the topsoil and subsoil, respectively. Following this treatment, the pH of the soil declined from 5.4 to 4.1; organic matter content slightly increased from 6.2 to 6.5%; available ammonium (NH4(+)-N) content increased to 2.4 times the original level; and in the topsoil, the available phosphorus content and the exchangeable potassium content increased by 1.65 and 2.53 times their initial levels, respectively. Copyright © 2015 Elsevier B.V. All rights reserved.

Recycling of CdTe photovoltaic waste

DOEpatents

Goozner, Robert E.; Long, Mark O.; Drinkard, Jr., William F.

1999-04-27

A method for extracting and reclaiming metals from scrap CdTe photovoltaic cells and manufacturing waste by leaching the metals in dilute nitric acid, leaching the waste with a leaching solution comprising nitric acid and water, skimming any plastic material from the top of the leaching solution, separating the glass substrate from the liquid leachate, adding a calcium containing base to the leachate to precipitate Cd and Te, separating the precipitated Cd and Te from the leachate, and recovering the calcium-containing base.

Removal of lead (II) ions from aqueous solutions onto activated carbon derived from waste biomass.

PubMed

Erdem, Murat; Ucar, Suat; Karagöz, Selhan; Tay, Turgay

2013-01-01

The removal of lead (II) ions from aqueous solutions was carried out using an activated carbon prepared from a waste biomass. The effects of various parameters such as pH, contact time, initial concentration of lead (II) ions, and temperature on the adsorption process were investigated. Energy Dispersive X-Ray Spectroscopy (EDS) analysis after adsorption reveals the accumulation of lead (II) ions onto activated carbon. The Langmuir and Freundlich isotherm models were applied to analyze equilibrium data. The maximum monolayer adsorption capacity of activated carbon was found to be 476.2 mg g⁻¹. The kinetic data were evaluated and the pseudo-second-order equation provided the best correlation. Thermodynamic parameters suggest that the adsorption process is endothermic and spontaneous.

Inclusion of products of physicochemical oxidation of organic wastes in matter recycling of biological-technical life support systems.

NASA Astrophysics Data System (ADS)

Tikhomirov, Alexander A.; Kudenko, Yurii; Trifonov, Sergei; Ushakova, Sofya

Inclusion of products of human and plant wastes' `wet' incineration in 22 medium using alter-nating current into matter recycling of biological-technical life support system (BTLSS) has been considered. Fluid and gaseous components have been shown to be the products of such processing. In particular, the final product contained all necessary for plant cultivation nitrogen forms: NO2, NO3, NH4+. As the base solution included urine than NH4+ form dominated. At human solid wastes' mineralization NO2 NH4+ were registered in approximately equal amount. Comparative analysis of mineral composition of oxidized human wastes' and standard Knop solutions has been carried out. On the grounds of that analysis the dilution methods of solutions prepared with addition of oxidized human wastes for their further use for plant irrigation have been suggested. Reasonable levels of wheat productivity cultivated at use of given solutions have been obtained. CO2, N2 and O2 have been determined to be the main gas components of the gas admixture emitted within the given process. These gases easily integrate in matter recycling process of closed ecosystem. The data of plants' cultivation feasibility in the atmosphere obtained after closing of gas loop including physicochemical facility and vegetation chamber with plants-representatives of LSS phototrophic unit has been received. Conclusion of advance research on creation of matter recycling process in the integrated physical-chemical-biological model system has been drawn.

Hanford Double Shell Waste Tank Corrosion Studies - Final Report FY2015

DOE Office of Scientific and Technical Information (OSTI.GOV)

Fuentes, R. E.; Wyrwas, R. B.

2016-05-01

During FY15, SRNL performed corrosion testing that supported Washington River Protection Solutions (WRPS) with their double shell tank (DST) integrity program. The testing investigated six concerns including, 1) the possibility of corrosion of the exterior of the secondary tank wall; 2) the effect of ammonia on vapor space corrosion (VSC) above waste simulants; 3) the determination of the minimum required nitrite and hydroxide concentrations that prevent pitting in concentrated nitrate solutions (i.e., waste buffering); 4) the susceptibility to liquid air interface (LAI) corrosion at proposed stress corrosion cracking (SCC) inhibitor concentrations; 5) the susceptibility of carbon steel to pitting inmore » dilute solutions that contain significant quantities of chloride and sulfate; and 6) the effect of different heats of A537 carbon steel on the corrosion response. For task 1, 2, and 4, the effect of heat treating and/ or welding of the materials was also investigated.« less

GUIDE TO TREATMENT TECHNOLOGIES FOR HAZARDOUS WASTES AT SUPERFUND SITES

EPA Science Inventory

Over the past fewyears, it has become increasinsly evident that land disposal of hazardous wastes is at least only a temporary solution for much of the wastes present at Superfund sites. The need for more Iong-term, permanent "treatment solutions as alternatives to land disposal ...

Approach to the vadose zone monitoring in hazardous and solid waste disposal facilities

NASA Astrophysics Data System (ADS)

Twardowska, Irena

2004-03-01

In the solid waste (SW)disposal sites, in particular at the unlined facilities, at the remediated or newly-constructed units equipped with novel protective/reactive permeable barriers or at lined facilities with leachate collection systems that are prone to failure, the vadose zone monitoring should comprise besides the natural soil layer beneath the landfill, also the anthropogenic vadose zone, i.e. the waste layer and pore solutions in the landfill. The vadose zone screening along the vertical profile of SW facilities with use of direct invasive soil-core and soil-pore liquid techniques shows vertical downward redistribution of inorganic (macroconstituents and heavy metals) and organic (PAHs) contaminant loads in water infiltrating through the waste layer. These loads can make ground water down-gradient of the dump unfit for any use. To avoid damage of protective/reactive permeable barriers and liners, an installation of stationary monitoring systems along the waste layer profile during the construction of a landfill, which are amenable to generate accurate data and information in a near-real time should be considered including:(i) permanent samplers of pore solution, with a periodic pump-induced transport of collected solution to the surface, preferably with instant field measurements;(ii)chemical sensors with continuous registration of critical parameters. These techniques would definitely provide an early alert in case when the chemical composition of pore solution percolating downward the waste profile shows unfavorable transformations, which indicate an excessive contaminant load approaching ground water. The problems concerning invasive and stationary monitoring of the vadose zone in SW disposal facilities will be discussed at the background of results of monitoring data and properties of permeable protective/reactive barriers considered for use.

Nickel recovery from electronic waste II electrodeposition of Ni and Ni-Fe alloys from diluted sulfate solutions.

PubMed

Robotin, B; Ispas, A; Coman, V; Bund, A; Ilea, P

2013-11-01

This study focuses on the electrodeposition of Ni and Ni-Fe alloys from synthetic solutions similar to those obtained by the dissolution of electron gun (an electrical component of cathode ray tubes) waste. The influence of various parameters (pH, electrolyte composition, Ni(2+)/Fe(2+) ratio, current density) on the electrodeposition process was investigated. Scanning electron microscopy (SEM) and X-ray fluorescence analysis (XRFA) were used to provide information about the obtained deposits' thickness, morphology, and elemental composition. By controlling the experimental parameters, the composition of the Ni-Fe alloys can be tailored towards specific applications. Complementarily, the differences in the nucleation mechanisms for Ni, Fe and Ni-Fe deposition from sulfate solutions have been evaluated and discussed using cyclic voltammetry and potential step chronoamperometry. The obtained results suggest a progressive nucleation mechanism for Ni, while for Fe and Ni-Fe, the obtained data points are best fitted to an instantaneous nucleation model. Copyright © 2013 Elsevier Ltd. All rights reserved.

RADIOACTIVE WASTE PROCESSING AND DISPOSAL: A BIBLIOGRAPHY OF SELECTED REPORT LITERATURE

DOE Office of Scientific and Technical Information (OSTI.GOV)

Voress, H.E.; Davis, T.F.; Hubbard, T.N. Jr.

1958-06-01

An annotated bibliography is presented containing 698 references to unclassifled reports on currert and proposed ranioactive waste processing and disposal practices for solutions from radiochemical processing plants and laboratories, decontamination of surfaces, air cleaning, and other related subjects. Author, corporate author, subject, and report nuunber indexes are included. (auth)

A numerical solution of Duffing's equations including the prediction of jump phenomena

NASA Technical Reports Server (NTRS)

Moyer, E. T., Jr.; Ghasghai-Abdi, E.

1987-01-01

Numerical methodology for the solution of Duffing's differential equation is presented. Algorithms for the prediction of multiple equilibrium solutions and jump phenomena are developed. In addition, a filtering algorithm for producing steady state solutions is presented. The problem of a rigidly clamped circular plate subjected to cosinusoidal pressure loading is solved using the developed algorithms (the plate is assumed to be in the geometrically nonlinear range). The results accurately predict regions of solution multiplicity and jump phenomena.

IONSIV(R) IE-911 Performance in Savannah River Site Radioactive Waste

DOE Office of Scientific and Technical Information (OSTI.GOV)

Walker, D.D.

2001-06-04

This report describes cesium sorption from high-level radioactive waste solutions onto IONSIV(R) IE-911 at ambient temperature. Researchers characterized six radioactive waste samples from five high-level waste tanks in the Savannah River Site tank farm, diluted the wastes to 5.6 M Na+, and made equilibrium and kinetic measurements of cesium sorption. The equilibrium measurements were compared to ZAM (Zheng, Anthony, and Martin) model predictions. The kinetic measurements were compared to simulant solutions whose column performance has been measured.

Method of solution preparation of polyolefin class polymers for electrospinning processing included

NASA Technical Reports Server (NTRS)

Rabolt, John F. (Inventor); Givens, Steven R. (Inventor); Lee, Keun-Hyung (Inventor)

2011-01-01

A process to make a polyolefin fiber which has the following steps: mixing at least one polyolefin into a solution at room temperature or a slightly elevated temperature to form a polymer solution and electrospinning at room temperature said polymer solution to form a fiber.

Commercial Coffee Wastes as Materials for Adsorption of Heavy Metals from Aqueous Solutions

PubMed Central

Kyzas, George Z.

2012-01-01

This work aims to study the removal of Cu(II) and Cr(VI) from aqueous solutions with commercial coffee wastes. Materials with no further treatment such as coffee residues from café may act as adsorbents for the removal of Cu(II) and Cr(VI). Equilibrium data were successfully fitted to the Langmuir, Freundlich and Langmuir-Freundlich model (L-F). The maximum adsorption capacity of the coffee residues can reach 70 mg/g for the removal of Cu(II) and 45 mg/g for Cr(VI). The kinetic data were fitted to pseudo-first, -second and -third order equations. The equilibrium was achieved in 120 min. Also, the effect of pH on adsorption and desorption was studied, as well as the influence of agitation rate. Ten cycles of adsorption-desorption were carried out revealing the strong reuse potential of these low-cost adsorbents; the latter was confirmed from a brief economic approach.

Experiment on the treatment of waste extraction solvent from the molybdenum-99 process

DOE Office of Scientific and Technical Information (OSTI.GOV)

Hsien-Ming Hsiao; Chang-Liang Hu; Kuang-Li Chien

2013-07-01

In the Mo-99 (Molybdenum-99) isotope extraction test process for radiopharmaceutical applications, organic solvent is used to extract Mo-99 from an irradiated UO{sub 2} dissolution. The extraction solvent was stored when the test work was stopped. A total of about 120 liters of waste solvent was stored at INER (Institute of Nuclear Energy Research, Taiwan). The extraction solvent consisted of 5% di-(2-ethylhexyl)-phosphoric acid (D2EHPA) and kerosene. The radionuclides found in the waste solvent include Cs-137, Am-241, Tc-99, and Sr-90, which give off gross alpha and beta radioactivity of 1898 and 471 Bq/ml, respectively. This study aims to remove radionuclides from themore » waste solvent using sodium carbonate and sodium hydroxide solutions in different concentrations. After mixing the waste solvent with the alkaline solution followed by settling, a third phase other than organic and aqueous phase appeared which is expected due to the saponification reaction. The experimental results showed that increasing the number of washing and the alkaline solution concentration could enhance the radionuclides removal rate. An optimal removal method was proposed using 2 M Na{sub 2}CO{sub 3} solution twice followed by 1 M NaOH solution one time for the third phase generated early in the mixing stages. The remaining gross alpha and beta radioactivity of the treated organic solvent was 2 and 3 Bq/ml, respectively. The treated solvent could be stabilized by ashing at 500 deg. C and then immobilized. The alkaline solution would be neutralized by hydrochloric or nitric acid and then treated using a variety of adsorbents or bone char via adsorption to remove nuclides to meet the wastewater discharge limitation. (authors)« less

Method for removal of explosives from aqueous solution using suspended plant cells

DOEpatents

Jackson, Paul J.; Torres, deceased, Agapito P.; Delhaize, Emmanuel

1994-01-01

The use of plant suspension cultures to remove ionic metallic species and TNT-based explosives and their oxidation products from aqueous solution is described. Several plant strains were investigated including D. innoxia, Citrus citrus, and Black Mexican Sweet Corn. All showed significant ability to remove metal ions. Ions removed to sub-ppm levels include barium, iron, and plutonium. D. innoxia cells growing in media containing weapons effluent contaminated with Ba.sup.2+ also remove TNT, other explosives and oxidation products thereof from solution. The use of dead, dehydrated cells was also found to be of use in treating waste directly.

Recycling of CdTe photovoltaic waste

DOEpatents

Goozner, R.E.; Long, M.O.; Drinkard, W.F. Jr.

1999-04-27

A method for extracting and reclaiming metals from scrap CdTe photovoltaic cells and manufacturing waste by leaching the metals in dilute nitric acid, leaching the waste with a leaching solution comprising nitric acid and water, skimming any plastic material from the top of the leaching solution, separating the glass substrate from the liquid leachate, adding a calcium containing base to the leachate to precipitate Cd and Te, separating the precipitated Cd and Te from the leachate, and recovering the calcium-containing base. 3 figs.

ECLSS Universal Waste Management System (UWMS) Metal Materials Compatibility Study- Electrochemical and Crevice Corrosion Evaluation

NASA Technical Reports Server (NTRS)

Lee, R. E.

2017-01-01

Electrochemical and crevice corrosion laboratory test results are presented for three noble metal candidates with possible application on the Universal Waste Management System (UWMS) in support of the Environmental Control and Life Support System (ECLSS) aboard the International Space Station (ISS). The three metal candidates, which included Inconel 625, Hastelloy C276 and Titanium 6Al-4V, were evaluated in two solutions representative of the acidic pretreatment formulations utilized during processing of waste liquids within the ECLSS. Final test results and data analysis indicated that the passive layer on all three metals provides excellent corrosion protection in both solutions under standard test conditions.

Increase of a BLSS closure using mineralized human waste in plant cultivation on a neutral substrate

NASA Astrophysics Data System (ADS)

Gros, Jean-Bernard; Ushakova, Sofya; Tikhomirov, Alexander A.; Kudenko, Yurii; Lasseur, Christophe; Shikhov, V.; Anischenko, O.

The purpose of this work was to study the full-scale potential use of human mineralized waste (feces and urine) as a source of mineral elements for plants cultivation in a Biological Life Support System. The plants which are potential candidates for a photosynthesizing link were grown on a neutral solution containing human mineralized waste. Spring wheat Triticum aestivum L., peas Pisum sativum L. Ambrosia cultivar and leaf lettuce Lactuca sativa L., Vitamin variety, were taken as the investigation objects. The plants were grown by hydroponics method on expanded clay aggregates in a vegetation chamber in constant environmental conditions. During the plants growth a definite amount of human mineralized waste was added daily in the nutrient solution. The nutrient solution was not changed during the entire vegetation period. Estimation of the plant needs in macro elements was based on a total biological productivity equal to 0.04 kg.day--1 .m-2 . As the plant requirements in potassium exceeded the potassium content in human waste, water extract of wheat straw containing the required potassium amount was added to the nutrient solution. Knop's solution was used in the control experiments. The experiment and control plants did not show significant differences in their photosynthetic apparatus state and productivity. A small decrease in total productivity of the experimental plants was observed which can result in some reduction of ˆ2 production in a BLSS. Most I probably it is due to the reduced nitrogen use. Therefore in a real BLSS after the mineralization of human feces and urine, it will be efficient to implement a more complete oxidation of nitrogencontaining compounds system, including nitrification. In this case the plants, prospective representatives of the BLSS photosynthesizing unit, could be cultivated on the solutions mainly based on human mineralized waste.

Waste and Recycling

ScienceCinema

McCarthy, Kathy

2018-01-01

Nuclear engineer Dr. Kathy McCarthy talks about nuclear energy, the challenge of nuclear waste and the research aimed at solutions. For more information about nuclear energy research, visit http://www.facebook.com/idahonationallaboratory.

Sydney tar ponds: some problems in quantifying toxic waste.

PubMed

Furimsky, Edward

2002-12-01

Information on the type and amount of hazardous and toxic waste is required to develop a meaningful strategy and estimate a realistic cost for clean up of the Sydney Tar Pond site which is located on Cape Breton, in the province of Nova Scotia, Canada. The site covers the area of the decommissioned Sysco (Sydney Steel Corporation) plant. The materials of concern include BTEX (benzene, toluene, ethylbenzene, and xylenes), PAH (polycyclic aromatic hydrocarbons), PCB (polychlorinated biphenyl), and particulates laden with toxic metals, such as arsenic, lead, and others. The originally nontoxic materials such as soil, blast furnace slag, and vegetation, as well as surface and ground waters, which were subsequently contaminated, must also be included if they fail tests prescribed by environmental regulations. An extensive sampling program must be undertaken to obtain data for an accurate estimate of the waste to be cleaned and disposed of. Apparently, 700,000 tons of toxic waste, which is believed to be present on the site, may represent only a fraction of the actual amount. The clean-up of the site is only part of the solution. Toxic waste has to be disposed of in accordance with environmental regulations.

ELECTROLYTIC REDUCTION OF NITRIC ACID SOLUTIONS

DOEpatents

Alter, H.W.; Barney, D.L.

1958-09-30

A process is presented for the treatment of radioactivc waste nitric acid solutions. The nitric acid solution is neutralized with an alkali metal hydroxide in an amount sufficient to precipitate insoluble hydroxides, and after separation of the precipitate the solution is electrolyzed to convert the alkali nitrate formed, to alkali hydroxide, gaseous ammonla and oxygen. The solution is then reusable after reducing the volume by evaporating the water and dissolved ammonia.

Separate collection of plastic waste, better than technical sorting from municipal solid waste?

PubMed

Feil, Alexander; Pretz, Thomas; Jansen, Michael; Thoden van Velzen, Eggo U

2017-02-01

The politically preferred solution to fulfil legal recycling demands is often implementing separate collection systems. However, experience shows their limitations, particularly in urban centres with a high population density. In response to the European Union landfill directive, mechanical biological waste treatment plants have been installed all over Europe. This technology makes it possible to retrieve plastic waste from municipal solid waste. Operators of mechanical biological waste treatment plants, both in Germany and the Netherlands, have started to change their mechanical separation processes to additionally produce plastic pre-concentrates. Results from mechanical biological waste treatment and separate collection of post-consumer packaging waste will be presented and compared. They prove that both the yield and the quality of plastic waste provided as feedstock for the production of secondary plastic raw material are largely comparable. An economic assessment shows which conditions for a technical sorting plant are economically attractive in comparison to separate collection systems. It is, however, unlikely that plastic recycling will ever reach cost neutrality.

Optimization of municipal solid waste collection and transportation routes.

PubMed

Das, Swapan; Bhattacharyya, Bidyut Kr

2015-09-01

Optimization of municipal solid waste (MSW) collection and transportation through source separation becomes one of the major concerns in the MSW management system design, due to the fact that the existing MSW management systems suffer by the high collection and transportation cost. Generally, in a city different waste sources scatter throughout the city in heterogeneous way that increase waste collection and transportation cost in the waste management system. Therefore, a shortest waste collection and transportation strategy can effectively reduce waste collection and transportation cost. In this paper, we propose an optimal MSW collection and transportation scheme that focus on the problem of minimizing the length of each waste collection and transportation route. We first formulize the MSW collection and transportation problem into a mixed integer program. Moreover, we propose a heuristic solution for the waste collection and transportation problem that can provide an optimal way for waste collection and transportation. Extensive simulations and real testbed results show that the proposed solution can significantly improve the MSW performance. Results show that the proposed scheme is able to reduce more than 30% of the total waste collection path length. Copyright © 2015 Elsevier Ltd. All rights reserved.

The potential of household solid waste reduction in Sukomanunggal District, Surabaya

NASA Astrophysics Data System (ADS)

Warmadewanthi, I. D. A. A.; Kurniawati, S.

2018-01-01

The rapid population growth affects the amount of waste generated. Sukomanunggal Subdistrict is the densest area in West Surabaya which has a population of 100,602 inhabitants with a total area of 11.2 km2. The population growth significantly affects the problem of limited land for landfill facilities (final processing sites). According to the prevailing regulations, solid waste management solutions include the solid waste reduction and management. This study aims to determine the potential reduction of household solid waste at the sources. Household solid waste samplings were performed for eight consecutive days. The samples were then analyzed to obtain the generation rate, density, and composition so that the household solid waste reduction potential for the next 20 years could be devised. Results of the analysis showed that the value of waste is 0.27 kg/person/day, while the total household solid waste generation amounted to 27,162.58 kg/day or 187.70 m3/day. Concerning the technical aspects, the current solid waste reduction in Sukomanunggal Subdistrict has reached 2.1% through the application of waste bank, composting, and scavenging activities at the dumping sites by the garbage collectors. In the year of 2036, the potential reduction of household solid waste in Sukomanunggal Subdistrict has been estimated to reach 28.0%.

Fabrication of the novel hydrogel based on waste corn stalk for removal of methylene blue dye from aqueous solution

NASA Astrophysics Data System (ADS)

Ma, Dongzhuo; Zhu, Baodong; Cao, Bo; Wang, Jian; Zhang, Jianwei

2017-11-01

The novel hydrogel based on waste corn stalk was synthetized by aqueous solution polymerization technique with functional monomers in the presence of organic montmorillonite (OMMT) under ultrasonic. In this study, batch adsorption experiments were carried out to research the effect of initial dye concentration, the dosage of hydrogel, stirring speed, contact time and temperature on the adsorption of methylene blue (MB) dye. The adsorption process was best described by the pseudo-second-order kinetic model, which confirmed that it should be a chemical process. Furthermore, we ascertained the rate controlling step by establishing the intraparticle diffusion model and the liquid film diffusion model. The adsorption and synthesis mechanisms were vividly depicted in our work as well. Structural and morphological characterizations by virtue of FTIR, FESEM, and Biomicroscope supported the relationship between the adsorption performance and material's microstructure. This research is a valuable contribution for the environmental protection, which not only converts waste corn stalks into functional materials, but improves the removal of organic dye from sewage water.

Performance Assessments of Generic Nuclear Waste Repositories in Shale

NASA Astrophysics Data System (ADS)

Stein, E. R.; Sevougian, S. D.; Mariner, P. E.; Hammond, G. E.; Frederick, J.

2017-12-01

Simulations of deep geologic disposal of nuclear waste in a generic shale formation showcase Geologic Disposal Safety Assessment (GDSA) Framework, a toolkit for repository performance assessment (PA) whose capabilities include domain discretization (Cubit), multiphysics simulations (PFLOTRAN), uncertainty and sensitivity analysis (Dakota), and visualization (Paraview). GDSA Framework is used to conduct PAs of two generic repositories in shale. The first considers the disposal of 22,000 metric tons heavy metal of commercial spent nuclear fuel. The second considers disposal of defense-related spent nuclear fuel and high level waste. Each PA accounts for the thermal load and radionuclide inventory of applicable waste types, components of the engineered barrier system, and components of the natural barrier system including the host rock shale and underlying and overlying stratigraphic units. Model domains are half-symmetry, gridded with Cubit, and contain between 7 and 22 million grid cells. Grid refinement captures the detail of individual waste packages, emplacement drifts, access drifts, and shafts. Simulations are run in a high performance computing environment on as many as 2048 processes. Equations describing coupled heat and fluid flow and reactive transport are solved with PFLOTRAN, an open-source, massively parallel multiphase flow and reactive transport code. Additional simulated processes include waste package degradation, waste form dissolution, radioactive decay and ingrowth, sorption, solubility, advection, dispersion, and diffusion. Simulations are run to 106 y, and radionuclide concentrations are observed within aquifers at a point approximately 5 km downgradient of the repository. Dakota is used to sample likely ranges of input parameters including waste form and waste package degradation rates and properties of engineered and natural materials to quantify uncertainty in predicted concentrations and sensitivity to input parameters. Sandia National

An approximate JKR solution for a general contact, including rough contacts

NASA Astrophysics Data System (ADS)

Ciavarella, M.

2018-05-01

In the present note, we suggest a simple closed form approximate solution to the adhesive contact problem under the so-called JKR regime. The derivation is based on generalizing the original JKR energetic derivation assuming calculation of the strain energy in adhesiveless contact, and unloading at constant contact area. The underlying assumption is that the contact area distributions are the same as under adhesiveless conditions (for an appropriately increased normal load), so that in general the stress intensity factors will not be exactly equal at all contact edges. The solution is simply that the indentation is δ =δ1 -√{ 2 wA‧ /P″ } where w is surface energy, δ1 is the adhesiveless indentation, A‧ is the first derivative of contact area and P‧‧ the second derivative of the load with respect to δ1. The solution only requires macroscopic quantities, and not very elaborate local distributions, and is exact in many configurations like axisymmetric contacts, but also sinusoidal waves contact and correctly predicts some features of an ideal asperity model used as a test case and not as a real description of a rough contact problem. The solution permits therefore an estimate of the full solution for elastic rough solids with Gaussian multiple scales of roughness, which so far was lacking, using known adhesiveless simple results. The result turns out to depend only on rms amplitude and slopes of the surface, and as in the fractal limit, slopes would grow without limit, tends to the adhesiveless result - although in this limit the JKR model is inappropriate. The solution would also go to adhesiveless result for large rms amplitude of roughness hrms, irrespective of the small scale details, and in agreement with common sense, well known experiments and previous models by the author.

Mechanisms of iodine release from iodoapatite in aqueous solution

NASA Astrophysics Data System (ADS)

Zhang, Z.; Wang, J.

2017-12-01

Immobilization of iodine-129 with waste forms in geological setting is challenging due to its extremely long half-life and high volatility in the environment. To evaluate the long-term performance of waste form, it is imperative to determine the release mechanism of iodine hosted in the waste form materials. This study investigated the iodine released from apatite structured waste form Pb9.85 (VO4)6 I1.7 to understand how diffusion and dissolution control the durability of apatite waste form. A standard semi-dynamic leach test was adopted in this study. Samples were exposed in fresh leachant periodically and the leachant was replaced after each interval. Each experiment was carried out in cap-sealed Teflon vessels under constant temperature (e.g. 90 °C). ICP-MS analysis on the reacted leachates shows that Pb and V were released constantly and congruently with the stoichiometric ratio of Pb/V. However, iodine release is incongruent and time dependent. The iodine release rate starts significantly higher than the corresponding stoichiometric value and gradually decreases, approaching the stoichiometric value. Therefore, a dual-mode mechanism is proposed to account for the iodine release from apatite, which is dominated by short-term diffusion and long-term dissolution processes. Additional tests show that the element release rates depend on a number of test parameters, including sample surface to solution volume ratio (m-1), interval (day), temperature (°C), and solution pH. This study provides a quantitative characterization of iodine release mechanism. The activation energy of iodine leaching 21±1.6 kJ/mol was obtained by varying the test temperature. At the test conditions of to neutral pH and 90 °C, the long-term iodine release rate 3.3 mg/(m2 • day) is projected by normalizing sample surface area to solution volume ratio (S/V) to 1.0 m-1 and interval to 1 day. These findings demonstrate i) the feasibility of our approach to quantify the release mechanism

Removal of Pb(II) from aqueous solutions using waste textiles/poly(acrylic acid) composite synthesized by radical polymerization technique.

PubMed

Zhou, Tao; Xia, Fafa; Deng, Yue; Zhao, Youcai

2018-05-01

Waste textiles (WTs) are the inevitable outcome of human activity and should be separated and recycled in view of sustainable development. In this work, WT was modified through grafting with acrylic acid (AA) via radical polymerization process using ceric ammonium nitrate (CAN) as an initiator and microwave and/or UV irradiation as energy supply. The acrylic acid-grafted waste textiles (WT-g-AA) thus obtained was then used as an adsorbent to remove Pb(II) from Pb(II)-containing wastewater. The effects of pH, initial concentrations of Pb(II) and adsorbent dose were investigated, and around 95% Pb(II) can be removed from the aqueous solution containing 10mg/L at pH6.0-8.0. The experimental adsorption isotherm data was fitted to the Langmuir model with maximum adsorption capacity of 35.7mg Pb/g WT-g-AA. The Pb-absorbed WT-g-AA was stripped using dilute nitric acid solution and the adsorption capacity of Pb-free material decreased from 95.4% (cycle 1) to 91.1% (cycle 3). It was considered that the WT-g-AA adsorption for Pb(II) may be realized through the ion-exchange mechanism between COOH and Pb(II). The promising results manifested that WT-g-AA powder was an efficient, eco-friendly and reusable adsorbent for the removal of Pb(II) from wastewater. Copyright © 2017. Published by Elsevier B.V.

Electrochemical probing of high-level radioactive waste tanks containing washed sludge and precipitates

DOE Office of Scientific and Technical Information (OSTI.GOV)

Bickford, D.F.; Congdon, J.W.; Oblath, S.B.

1986-12-01

At the US Department of Energy's Savannah River Plant, corrosion of carbon steel storage tanks containing alkaline, high-level radioactive waste is controlled by specification of limits on waste composition and temperature. Processes for the preparation of waste for final disposal will result in waste with low corrosion inhibitor concentrations and, in some cases, high aromatic organic concentrations, neither of which are characteristic of previous operations. Laboratory tests, conducted to determine minimum corrosion inhibitor levels indicated pitting of carbon steel near the waterline for proposed storage conditions. In situ electrochemical measurements of full-scale radioactive process demonstrations have been conducted to assessmore » the validity of laboratory tests. Probes included pH, Eh (potential relative to a standard hydrogen electrode), tank potential, and alloy coupons. In situ results are compared to those of the laboratory tests, with particular regard given to simulated solution composition. Transition metal hydroxide sludge contains strong passivating species for carbon steel. Washed precipitate contains organic species that lower solution pH and tend to reduce passivating films, requiring higher inhibitor concentrations than the 0.01 molar nitrite required for reactor fuel reprocessing wastes. Periodic agitation, to keep the organic phase suspended, or cathodic protection are possible alternatives to higher nitrite inhibitor concentrations.« less

Pilot-scale laboratory waste treatment by supercritical water oxidation.

PubMed

Oshima, Yoshito; Hayashi, Rumiko; Yamamoto, Kazuo

2006-01-01

Supercritical water oxidation (SCWO) is a reaction in which organics in an aqueous solution can be oxidized by O2 to CO2 and H2O at a very high reaction rate. In 2003, The University of Tokyo constructed a facility for the SCWO process, the capacity of which is approximately 20 kl/year, for the purpose of treating organic laboratory waste. Through the operation of this facility, we have demonstrated that most of the organics in laboratory waste including halogenated organic compounds can be successfully treated without the formation of dioxines, suggesting that SCWO is useful as an alternative technology to the conventional incineration process.

Generating revenue from X-ray waste.

PubMed

Hundal, Simon

2013-09-01

According to Betts Envirometal, experts in precious metal recovery from waste streams, and a provider of 'total waste management' solutions, 'disposing of hospital wastes isn't usually a glamorous subject, unless, of course, you know how to make money from it'. As general manager, Simon Hundal, explains, the company is seeking to 'revolutionise' how the NHS treats certain waste streams, and, in doing so, to encourage NHS Trust directors and governance managers to check their compliance with patient data retention guidelines as far as medical X-ray film, in particular, is concerned.

Calcine Waste Storage at the Idaho Nuclear Technology and Engineering Center

DOE Office of Scientific and Technical Information (OSTI.GOV)

Staiger, Merle Daniel; M. C. Swenson

2005-01-01

This report documents an inventory of calcined waste produced at the Idaho Nuclear Technology and Engineering Center during the period from December 1963 to May 2000. The report was prepared based on calciner runs, operation of the calcined solids storage facilities, and miscellaneous operational information that establishes the range of chemical compositions of calcined waste stored at Idaho Nuclear Technology and Engineering Center. The report will be used to support obtaining permits for the calcined solids storage facilities, possible treatment of the calcined waste at the Idaho National Engineering and Environmental Laboratory, and to ship the waste to an off-sitemore » facility including a geologic repository. The information in this report was compiled from calciner operating data, waste solution analyses and volumes calcined, calciner operating schedules, calcine temperature monitoring records, and facility design of the calcined solids storage facilities. A compact disk copy of this report is provided to facilitate future data manipulations and analysis.« less

Planet Patrol. An Environmental Unit on Solid Waste Solutions for Grades 4-6.

ERIC Educational Resources Information Center

Procter and Gamble Educational Services, Cincinnati, OH.

This classroom unit was developed for use in grades 4-6 to help teach the concept of solid waste management. The teacher's guide provides an overview of the issue of solid waste disposal, a description of government, industry, and consumer roles in resolving the solid waste issue, and four lessons involving sanitary landfills, the reduction of…

Method for removal of metal atoms from aqueous solution using suspended plant cells

DOEpatents

Jackson, Paul J.; Torres, deceased, Agapito P.; Delhaize, Emmanuel

1992-01-01

The use of plant suspension cultures to remove ionic metallic species and TNT-based explosives and their oxidation products from aqueous solution is described. Several plant strains were investigated including D. innoxia, Citrus citrus, and Black Mexican Sweet Corn. All showed significant ability to remove metal ions. Ions removed to sub-ppm levels include barium, iron, and plutonium. D. innoxia cells growing in media containing weapons effluent contaminated with Ba.sup.2+ also remove TNT, other explosives and oxidation products thereof from solution. The use of dead, dehydrated cells were also found to be of use in treating waste directly.

CHARACTERIZATION OF ACTINIDES IN SIMULATED ALKALINE TANK WASTE SLUDGES AND LEACHATES

DOE Office of Scientific and Technical Information (OSTI.GOV)

Nash, Kenneth L.

In this project, both the fundamental chemistry of actinides in alkaline solutions (relevant to those present in Hanford-style waste storage tanks), and their dissolution from sludge simulants (and interactions with supernatants) have been investigated under representative sludge leaching procedures. The leaching protocols were designed to go beyond conventional alkaline sludge leaching limits, including the application of acidic leachants, oxidants and complexing agents. The simulant leaching studies confirm in most cases the basic premise that actinides will remain in the sludge during leaching with 2-3 M NaOH caustic leach solutions. However, they also confirm significant chances for increased mobility of actinidesmore » under oxidative leaching conditions. Thermodynamic data generated improves the general level of experiemental information available to predict actinide speciation in leach solutions. Additional information indicates that improved Al removal can be achieved with even dilute acid leaching and that acidic Al(NO3)3 solutions can be decontaminated of co-mobilized actinides using conventional separations methods. Both complexing agents and acidic leaching solutions have significant potential to improve the effectiveness of conventional alkaline leaching protocols. The prime objective of this program was to provide adequate insight into actinide behavior under these conditions to enable prudent decision making as tank waste treatment protocols develop.« less

Precipitation process for the removal of technetium values from nuclear waste solutions

DOEpatents

Walker, D.D.; Ebra, M.A.

1985-11-21

High efficiency removal of techetium values from a nuclear waste stream is achieved by addition to the waste stream of a precipitant contributing tetraphenylphosphonium cation, such that a substantial portion of the technetium values are precipitated as an insoluble pertechnetate salt.

Liquid Secondary Waste Grout Formulation and Waste Form Qualification

DOE Office of Scientific and Technical Information (OSTI.GOV)

Um, Wooyong; Williams, B. D.; Snyder, Michelle M. V.

This report describes the results from liquid secondary waste (LSW) grout formulation and waste form qualification tests performed at Pacific Northwest National Laboratory (PNNL) for Washington River Protection Solutions (WRPS) to evaluate new formulations for preparing a grout waste form with high-sulfate secondary waste simulants and the release of key constituents from these grout monoliths. Specific objectives of the LSW grout formulation and waste form qualification tests described in this report focused on five activities: 1.preparing new formulations for the LSW grout waste form with high-sulfate LSW simulants and solid characterization of the cured LSW grout waste form; 2.conducting themore » U.S. Environmental Protection Agency (EPA) Method 1313 leach test (EPA 2012) on the grout prepared with the new formulations, which solidify sulfate-rich Hanford Tank Waste Treatment and Immobilization Plant (WTP) off-gas condensate secondary waste simulant, using deionized water (DIW); 3.conducting the EPA Method 1315 leach tests (EPA 2013) on the grout monoliths made with the new dry blend formulations and three LSW simulants (242-A evaporator condensate, Environmental Restoration Disposal Facility (ERDF) leachate, and WTP off-gas condensate) using two leachants, DIW and simulated Hanford Integrated Disposal Facility (IDF) Site vadose zone pore water (VZPW); 4.estimating the 99Tc desorption K d (distribution coefficient) values for 99Tc transport in oxidizing conditions to support the IDF performance assessment (PA); 5.estimating the solubility of 99Tc(IV)-bearing solid phases for 99Tc transport in reducing conditions to support the IDF PA.« less

Automotive absorption air conditioner utilizing solar and motor waste heat

NASA Technical Reports Server (NTRS)

Popinski, Z. (Inventor)

1981-01-01

In combination with the ground vehicles powered by a waste heat generating electric motor, a cooling system including a generator for driving off refrigerant vapor from a strong refrigerant absorbant solution is described. A solar collector, an air-cooled condenser connected with the generator for converting the refrigerant vapor to its liquid state, an air cooled evaporator connected with the condenser for returning the liquid refrigerant to its vapor state, and an absorber is connected to the generator and to the evaporator for dissolving the refrigerant vapor in the weak refrigerant absorbant solution, for providing a strong refrigerant solution. A pump is used to establish a pressurized flow of strong refrigerant absorbant solution from the absorber through the electric motor, and to the collector.

Optimization of municipal solid waste collection and transportation routes

DOE Office of Scientific and Technical Information (OSTI.GOV)

Das, Swapan, E-mail: swapan2009sajal@gmail.com; Bhattacharyya, Bidyut Kr., E-mail: bidyut53@yahoo.co.in

2015-09-15

Graphical abstract: Display Omitted - Highlights: • Profitable integrated solid waste management system. • Optimal municipal waste collection scheme between the sources and waste collection centres. • Optimal path calculation between waste collection centres and transfer stations. • Optimal waste routing between the transfer stations and processing plants. - Abstract: Optimization of municipal solid waste (MSW) collection and transportation through source separation becomes one of the major concerns in the MSW management system design, due to the fact that the existing MSW management systems suffer by the high collection and transportation cost. Generally, in a city different waste sources scattermore » throughout the city in heterogeneous way that increase waste collection and transportation cost in the waste management system. Therefore, a shortest waste collection and transportation strategy can effectively reduce waste collection and transportation cost. In this paper, we propose an optimal MSW collection and transportation scheme that focus on the problem of minimizing the length of each waste collection and transportation route. We first formulize the MSW collection and transportation problem into a mixed integer program. Moreover, we propose a heuristic solution for the waste collection and transportation problem that can provide an optimal way for waste collection and transportation. Extensive simulations and real testbed results show that the proposed solution can significantly improve the MSW performance. Results show that the proposed scheme is able to reduce more than 30% of the total waste collection path length.« less

Recycling paper-pulp waste liquors

NASA Technical Reports Server (NTRS)

Sarbolouki, M. N.

1981-01-01

Papermills in U.S. annually produce 3 million tons of sulfite waste liquor solids; other fractions of waste liquor are monomeric sugars and lignosulfonates in solution. Recovery of lignosulfonates involves precipitation and cross-linking of sulfonates to form useful solid ion-exchange resin. Contamination of sugars recovered from liquor is avoided by first converting them to ethanol, then removing ethanol by distillation.

Enhanced biogas yield by thermo-alkali solubilization followed by co-digestion of intestine waste from slaughterhouse with food waste.

PubMed

Porselvam, S; Soundara Vishal, N; Srinivasan, S V

2017-10-01

Intestine waste generated from slaughterhouse (IWS) is difficult to degrade in anaerobic process due to the presence of high protein and lipid contents. However, anaerobic co-digestion helps to increase the degradation of IWS by the addition of carbon-rich food waste (FW). To increase the biogas yield, thermo-alkali pretreatment may be more viable method for the anaerobic digestion of protein and lipid rich wastes. In the present study, Thermo-alkali pretreatment of intestine waste from slaughterhouse and food waste alone and mixing of IWS and FW with different ratios (1:1-1:3) on VS basis have been studied. To study the effect of Thermo-alkali pretreatment on solubilization of substrate, the substrate was mixed with alkali solutions (NaOH and KOH) at different concentrations of 1, 2, 3, 4 and 5% solutions. The results revealed that the maximum solubilization was observed to be 94.7% and 90.1% at KOH (1:3 and 5%) and NaOH (1:3 and 5%), respectively. Based on the study, enhancement in biogas yield by 16% (IWS), 11.5% (FW), 12.2% (1:1), 18.11% (1:2) and 22.5% (1:3) in KOH pretreated waste when compared with NaOH pretreated waste.

Hazardous waste status of discarded electronic cigarettes

DOE Office of Scientific and Technical Information (OSTI.GOV)

Krause, Max J.; Townsend, Timothy G., E-mail: ttown@ufl.edu

Highlights: • Electronic cigarettes were tested using TCLP and WET. • Several electronic cigarette products leached lead at hazardous waste levels. • Lead was the only element that exceeded hazardous waste concentration thresholds. • Nicotine solution may cause hazardous waste classification when discarded unused. - Abstract: The potential for disposable electronic cigarettes (e-cigarettes) to be classified as hazardous waste was investigated. The Toxicity Characteristic Leaching Procedure (TCLP) was performed on 23 disposable e-cigarettes in a preliminary survey of metal leaching. Based on these results, four e-cigarette products were selected for replicate analysis by TCLP and the California Waste Extraction Testmore » (WET). Lead was measured in leachate as high as 50 mg/L by WET and 40 mg/L by TCLP. Regulatory thresholds were exceeded by two of 15 products tested in total. Therefore, some e-cigarettes would be toxicity characteristic (TC) hazardous waste but a majority would not. When disposed in the unused form, e-cigarettes containing nicotine juice would be commercial chemical products (CCP) and would, in the United States (US), be considered a listed hazardous waste (P075). While household waste is exempt from hazardous waste regulation, there are many instances in which such waste would be subject to regulation. Manufactures and retailers with unused or expired e-cigarettes or nicotine juice solution would be required to manage these as hazardous waste upon disposal. Current regulations and policies regarding the availability of nicotine-containing e-cigarettes worldwide were reviewed. Despite their small size, disposable e-cigarettes are consumed and discarded much more quickly than typical electronics, which may become a growing concern for waste managers.« less

Inhibiting localized corrosion during storage of dilute SRP wastes

DOE Office of Scientific and Technical Information (OSTI.GOV)

Oblath, S.B.; Congdon, J.W.

1986-01-01

High-level radioactive waste will be incorporated in borosilicate glass in the Defense Waste Processing Facility (DWPF) at the Savannah River Plant (SRP). As part of this process, large volumes of inorganic salt wastes will be decontaminated for disposal as low-level waste. The principal contaminants, /sup 137/Cs and /sup 90/Sr, are removed by treatment with sodium tetraphenylborate and sodium titanate. The resulting solids will be slurried with a dilute salt solution and stored in existing carbon steel tanks for several years prior to processing and disposal. Initial tests indicated a tendency for localized corrosion of the tanks. An investigation, using nonradioactivemore » simulants for the expected solution compositions, identified inhibitors which would protect the steel. Changes in solution compositions over time, due to radiolytic effects, were also accounted for by the simulants. Six inhibitors were identified which would protect the steel tanks. The effects these inhibitors would have on later processing steps in the DWPF were then evaluated. After this process, only sodium nitrite remained as an inhibitor that was both effective and compatible with the DWPF. The use of this inhibitor has been demonstrated on a real waste slurry.« less

Evaluation of healthcare waste treatment/disposal alternatives by using multi-criteria decision-making techniques.

PubMed

Özkan, Aysun

2013-02-01

Healthcare waste should be managed carefully because of infected, pathological, etc. content especially in developing countries. Applied management systems must be the most appropriate solution from a technical, environmental, economic and social point of view. The main objective of this study was to analyse the current status of healthcare waste management in Turkey, and to investigate the most appropriate treatment/disposal option by using different decision-making techniques. For this purpose, five different healthcare waste treatment/disposal alternatives including incineration, microwaving, on-site sterilization, off-site sterilization and landfill were evaluated according to two multi-criteria decision-making techniques: analytic network process (ANP) and ELECTRE. In this context, benefits, costs and risks for the alternatives were taken into consideration. Furthermore, the prioritization and ranking of the alternatives were determined and compared for both methods. According to the comparisons, the off-site sterilization technique was found to be the most appropriate solution in both cases.

Method for stabilizing low-level mixed wastes at room temperature

DOEpatents

Wagh, A.S.; Singh, D.

1997-07-08

A method to stabilize solid and liquid waste at room temperature is provided comprising combining solid waste with a starter oxide to obtain a powder, contacting the powder with an acid solution to create a slurry, said acid solution containing the liquid waste, shaping the now-mixed slurry into a predetermined form, and allowing the now-formed slurry to set. The invention also provides for a method to encapsulate and stabilize waste containing cesium comprising combining the waste with Zr(OH){sub 4} to create a solid-phase mixture, mixing phosphoric acid with the solid-phase mixture to create a slurry, subjecting the slurry to pressure; and allowing the now pressurized slurry to set. Lastly, the invention provides for a method to stabilize liquid waste, comprising supplying a powder containing magnesium, sodium and phosphate in predetermined proportions, mixing said powder with the liquid waste, such as tritium, and allowing the resulting slurry to set. 4 figs.

Method for stabilizing low-level mixed wastes at room temperature

DOEpatents

Wagh, Arun S.; Singh, Dileep

1997-01-01

A method to stabilize solid and liquid waste at room temperature is provided comprising combining solid waste with a starter oxide to obtain a powder, contacting the powder with an acid solution to create a slurry, said acid solution containing the liquid waste, shaping the now-mixed slurry into a predetermined form, and allowing the now-formed slurry to set. The invention also provides for a method to encapsulate and stabilize waste containing cesium comprising combining the waste with Zr(OH).sub.4 to create a solid-phase mixture, mixing phosphoric acid with the solid-phase mixture to create a slurry, subjecting the slurry to pressure; and allowing the now pressurized slurry to set. Lastly, the invention provides for a method to stabilize liquid waste, comprising supplying a powder containing magnesium, sodium and phosphate in predetermined proportions, mixing said powder with the liquid waste, such as tritium, and allowing the resulting slurry to set.

Modeling transient heat transfer in nuclear waste repositories.

PubMed

Yang, Shaw-Yang; Yeh, Hund-Der

2009-09-30

The heat of high-level nuclear waste may be generated and released from a canister at final disposal sites. The waste heat may affect the engineering properties of waste canisters, buffers, and backfill material in the emplacement tunnel and the host rock. This study addresses the problem of the heat generated from the waste canister and analyzes the heat distribution between the buffer and the host rock, which is considered as a radial two-layer heat flux problem. A conceptual model is first constructed for the heat conduction in a nuclear waste repository and then mathematical equations are formulated for modeling heat flow distribution at repository sites. The Laplace transforms are employed to develop a solution for the temperature distributions in the buffer and the host rock in the Laplace domain, which is numerically inverted to the time-domain solution using the modified Crump method. The transient temperature distributions for both the single- and multi-borehole cases are simulated in the hypothetical geological repositories of nuclear waste. The results show that the temperature distributions in the thermal field are significantly affected by the decay heat of the waste canister, the thermal properties of the buffer and the host rock, the disposal spacing, and the thickness of the host rock at a nuclear waste repository.

Dispersive—diffusive transport of non-sorbed solute in multicomponent solutions

NASA Astrophysics Data System (ADS)

Hu, Qinhong; Brusseau, Mark L.

1995-10-01

The composition of fuels, mixed-solvent wastes and other contaminants that find their way into the subsurface are frequently chemically complex. The dispersion and diffusion characteristics of multicomponent solutions in soil have rarely been compared to equivalent single-solute systems. The purpose of this work was to examine the diffusive and dispersive transport of single- and multi-component solutions in homogeneous porous media. The miscible displacement technique was used to investigate the transport behavior of 14C-labelled 2,4-dichlorophenoxyacetic acid ( 2,4-D) in two materials for which sorption of 2,4-D was minimal. Comparison of breakthrough curves collected for 2,4-D in single- and multi-component solutions shows that there is little, if any, difference in transport behavior over a wide range of pore-water velocities (70, 7, 0.66 and 0.06 cm h -1). Thus, dispersivities measured with a non-sorbing single-solute solution should be applicable to multicomponent systems.

Combustion of liquid paint wastes in fluidized bed boiler as element of waste management system in the paint factory

DOE Office of Scientific and Technical Information (OSTI.GOV)

Soko, W.A.; Biaecka, B.

1998-12-31

In this paper the solution to waste problems in the paint industry is presented by describing their combustion in a fluidized bed boiler as a part of the waste management system in the paint factory. Based on the Cleaner Production idea and concept of integration of design process with a future exploitation of equipment, some modifications of the waste management scheme in the factory are discussed to reduce the quantity of toxic wastes. To verify this concept combustion tests of paint production wastes and cocombustion of paint wastes with coal in an adopted industrial boiler were done. Results of thesemore » tests are presented in the paper.« less

75 FR 77665 - Whirlpool Corporation, Including On-Site Leased Workers From Career Solutions TEC Staffing and...

Federal Register 2010, 2011, 2012, 2013, 2014

2010-12-13

..., Including On-Site Leased Workers From Career Solutions TEC Staffing and Andrews International, Fort Smith... Staffing, Fort Smith, Arkansas. The notice was published in the Federal Register on October 25, 2010 (75 FR... reports that workers leased from Andrews International were employed on-site at the Fort Smith, Arkansas...

The removal of As(III) and As(V) from aqueous solutions by waste materials.

PubMed

Rahaman, M S; Basu, A; Islam, M R

2008-05-01

The use of different waste materials such as Atlantic Cod fish scale, chicken fat, coconut fibre and charcoal in removing arsenic [As(III) and As(V)] from aqueous solutions was investigated. Initial experimental runs, conducted for both As(III) and As(V) with the aforementioned materials, demonstrated the potential of using Atlantic Cod fish scale in removing both species of arsenic from aqueous streams. Therefore, the biosorbent fish scale was selected for further investigations and various parameters such as residence time, adsorbent dose, initial concentration of adsorbate, grain size of the adsorbent and pH of the bulk phase were studied to establish optimum conditions. The maximum adsorption capacity was observed at pH value 4.0. The equilibrium adsorption data were interpreted by using both Freundlich and Langmuir models. Rapid small-scale column tests (RSSCT) were also performed to determine the breakthrough characteristics of the arsenic species with respect to packed biosorbent columns.

Cracking of Clay Due to Contact with Waste Chlorinated Solvents

NASA Astrophysics Data System (ADS)

Otero, M.; Ayral, D.; Shipan, J.; Goltz, M. N.; Huang, J.; Demond, A. H.

2012-12-01

Clays are known to crack upon desiccation. Desiccation cracks of up to 3 cm wide have been reported in natural soils. This raises the question if a similar behavior is seen when a dense non-aqueous phase liquids (DNAPL) waste is in contact with clay. The contact with organic liquids causes the clay structure to shrink, leading to the formation of cracks. Moreover, DNAPL waste not only contains the organic liquid solvent but also includes surface-active solutes or surfactants. Such solutes can enhance the interaction of the organic solvents with the clay. This research will assess whether or not contact with chlorinated organic waste causes cracking. In order to evaluate the possibility of cracking in the clay, microcosms have been constructed that mimic aquifer systems, consisting of a saturated layer of sand, a saturated layer of bentonite clay and a 2.5 cm layer of either pure chlorinated solvents or DNAPL waste. The onset of cracking for the microcosm with tetrachloroethylene (PCE) waste as the DNAPL layer occurred after ten days of contact. Similarly, at eight days, cracks were observed in a microcosm containing trichloroethylene (TCE) waste . Forty-four days later, the length and number of cracks have grown considerably; with a total crack length of 50 cm on a surface of 80 cm2 in the microcosm containing PCE waste. On the other hand it took approximately 161 days for the clay layer in the microcosm containing pure PCE to crack. To quantity the degree of cracking, crack maps were developed using the image software, Image J. Characteristics like crack length, crack aperture, and the percentage of total length for a range of apertures were calculated using this software. For example, for the PCE waste microcosm, it was calculated that 3.7% of the crack length had an aperture of 100-300 microns, 15.1% of the crack length had an aperture of 300-500 microns, 29.7% of the crack length had an aperture of 500-700 microns, 40.1% of the crack length had an aperture of

Searching for Solutions. A Citizen's Guide to Hazardous Waste Management in Ohio.

ERIC Educational Resources Information Center

Clapham, Pete, Comp.

This guide was developed to promote responsible hazardous waste management by Ohio citizens, citizens who are interested in upgrading operations of existing waste facilities, oppose the development of any new landfills, and those who promote the establishment of modern, efficient facilities. Information is presented in six chapters. The hazardous…

Relationship between food waste, diet quality, and environmental sustainability

PubMed Central

Niles, Meredith T.; Neher, Deborah A.; Roy, Eric D.; Tichenor, Nicole E.; Jahns, Lisa

2018-01-01

Improving diet quality while simultaneously reducing environmental impact is a critical focus globally. Metrics linking diet quality and sustainability have typically focused on a limited suite of indicators, and have not included food waste. To address this important research gap, we examine the relationship between food waste, diet quality, nutrient waste, and multiple measures of sustainability: use of cropland, irrigation water, pesticides, and fertilizers. Data on food intake, food waste, and application rates of agricultural amendments were collected from diverse US government sources. Diet quality was assessed using the Healthy Eating Index-2015. A biophysical simulation model was used to estimate the amount of cropland associated with wasted food. This analysis finds that US consumers wasted 422g of food per person daily, with 30 million acres of cropland used to produce this food every year. This accounts for 30% of daily calories available for consumption, one-quarter of daily food (by weight) available for consumption, and 7% of annual cropland acreage. Higher quality diets were associated with greater amounts of food waste and greater amounts of wasted irrigation water and pesticides, but less cropland waste. This is largely due to fruits and vegetables, which are health-promoting and require small amounts of cropland, but require substantial amounts of agricultural inputs. These results suggest that simultaneous efforts to improve diet quality and reduce food waste are necessary. Increasing consumers’ knowledge about how to prepare and store fruits and vegetables will be one of the practical solutions to reducing food waste. PMID:29668732

Medical waste to energy: experimental study.

PubMed

Arcuri, C; Luciani, F; Piva, P; Bartuli, F N; Ottria, L; Mecheri, B; Licoccia, S

2013-04-01

Although waste is traditionally assessed as a pollutant which needs to be reduced or lessened, its management is certainly necessary. Nowadays, biological fuel cells, through the direct conversion of organic matter to electricity using biocatalysts, represent a technology able to produce sustainable energy by means of waste treatment. This study aims to propose a mean to generate energy from blood and saliva, that are common risk-infectious medical waste. Material employed (purchased by Sigma-Aldrich) were: Glucose oxidase (GOx), Nafion perfluorinated resin solution at 5% in a mixture of lower aliphatic alcohols and water, Polyethylene oxide. Stock solutions of D (+) glucose were prepared in a 0.1 M phosphate buffer solution and stored at 4 °C for at least 24 h before use. Carbon cloth electrode ELAT HT 140 E-W with a platinum loading of 5 gm-2 was purchased by E-Tek. Electrospun Nafion fibers were obtained as follows. Scanning electron microscopy was used to characterize the electrode morphologies. In order to develop an effective immobilization strategy of GOx on the electrode surface, Nafion fibers (a fully fluorinated ion conducting polymer used as a membrane material in enzymatic fuel cells - EFC) were selected as immobilizing polymer matrix. In this work, exploiting the nafion fibers capability of being able to cathalize Gox activity, we have tried to produce an enzymatic fuel cell which could produce energy from the blood and the saliva within medical-dental waste. Medical waste refers to all those materials produced by the interaction among doctor and patient, such as blood and saliva. During our research we will try to complete an EFC prototype able to produce energy from blood and saliva inside the risk-infectious medical waste in order to contribute to the energy requirements of a consulting room.

Method of waste stabilization via chemically bonded phosphate ceramics

DOEpatents

Wagh, Arun S.; Singh, Dileep; Jeong, Seung-Young

1998-01-01

A method for regulating the reaction temperature of a ceramic formulation process is provided comprising supplying a solution containing a monovalent alkali metal; mixing said solution with an oxide powder to create a binder; contacting said binder with bulk material to form a slurry; and allowing the slurry to cure. A highly crystalline waste form is also provided consisting of a binder containing potassium and waste substrate encapsulated by the binder.

Environmental assessment of garden waste management in the Municipality of Aarhus, Denmark

DOE Office of Scientific and Technical Information (OSTI.GOV)

Boldrin, Alessio, E-mail: aleb@env.dtu.dk; Andersen, Jacob K.; Christensen, Thomas H.

2011-07-15

An environmental assessment of six scenarios for handling of garden waste in the Municipality of Aarhus (Denmark) was performed from a life cycle perspective by means of the LCA-model EASEWASTE. In the first (baseline) scenario, the current garden waste management system based on windrow composting was assessed, while in the other five scenarios alternative solutions including incineration and home composting of fractions of the garden waste were evaluated. The environmental profile (normalised to Person Equivalent, PE) of the current garden waste management in Aarhus is in the order of -6 to 8 mPE Mg{sup -1} ww for the non-toxic categoriesmore » and up to 100 mPE Mg{sup -1} ww for the toxic categories. The potential impacts on non-toxic categories are much smaller than what is found for other fractions of municipal solid waste. Incineration (up to 35% of the garden waste) and home composting (up to 18% of the garden waste) seem from an environmental point of view suitable for diverting waste away from the composting facility in order to increase its capacity. In particular the incineration of woody parts of the garden waste improved the environmental profile of the garden waste management significantly.« less

Environmental assessment of garden waste management in the Municipality of Aarhus, Denmark.

PubMed

Boldrin, Alessio; Andersen, Jacob K; Christensen, Thomas H

2011-07-01

An environmental assessment of six scenarios for handling of garden waste in the Municipality of Aarhus (Denmark) was performed from a life cycle perspective by means of the LCA-model EASEWASTE. In the first (baseline) scenario, the current garden waste management system based on windrow composting was assessed, while in the other five scenarios alternative solutions including incineration and home composting of fractions of the garden waste were evaluated. The environmental profile (normalised to Person Equivalent, PE) of the current garden waste management in Aarhus is in the order of -6 to 8 mPE Mg(-1) ww for the non-toxic categories and up to 100 mPE Mg(-1) ww for the toxic categories. The potential impacts on non-toxic categories are much smaller than what is found for other fractions of municipal solid waste. Incineration (up to 35% of the garden waste) and home composting (up to 18% of the garden waste) seem from an environmental point of view suitable for diverting waste away from the composting facility in order to increase its capacity. In particular the incineration of woody parts of the garden waste improved the environmental profile of the garden waste management significantly. Copyright © 2011 Elsevier Ltd. All rights reserved.

LEACHING BOUNDARY IN CEMENT-BASED WASTE FORMS

EPA Science Inventory

Cement-based fixation systems are among the most commonly employed stabilization/solidification techniques. These cement haste mixtures, however, are vulnerable to ardic leaching solutions. Leaching of cement-based waste forms in acetic acid solutions with different acidic streng...

Public health response to striking solid waste management.

PubMed

Murti, Michelle; Ayre, Reg; Shapiro, Howard; de Burger, Ron

2011-10-01

In 2009, the City of Toronto, Ontario, Canada, experienced a six-week labor disruption involving 24,000 city workers that included solid waste and public health employees. In an attempt to control illegal dumping and to manage garbage storage across the city during this period, 24 temporary garbage storage sites were established by the city (mostly in local parks) for residents to dispose of their household waste. No other municipality in North America has attempted to operate this many temporary sites for this long a period. Management and nonunion staff from Healthy Environments in Toronto Public Health performed daily inspections, responded to community questions, issued public health orders, and worked closely with Solid Waste Management and the Ministry of the Environment to actively manage the public health concerns associated with these sites. This intensive oversight mitigated public health risks to the community and facilitated an effective, safe solution to the temporary garbage storage problem.

Mechanical-biological treatment: performance and potentials. An LCA of 8 MBT plants including waste characterization.

PubMed

Montejo, Cristina; Tonini, Davide; Márquez, María del Carmen; Astrup, Thomas Fruergaard

2013-10-15

In the endeavour of avoiding presence of biodegradable waste in landfills and increasing recycling, mechanical-biological treatment (MBT) plants have seen a significant increase in number and capacity in the last two decades. The aim of these plants is separating and stabilizing the quickly biodegradable fraction of the waste as well as recovering recyclables from mixed waste streams. In this study the environmental performance of eight MBT-based waste management scenarios in Spain was assessed by means of life cycle assessment. The focus was on the technical and environmental performance of the MBT plants. These widely differed in type of biological treatment and recovery efficiencies. The results indicated that the performance is strongly connected with energy and materials recovery efficiency. The recommendation for upgrading and/or commissioning of future plants is to optimize materials recovery through increased automation of the selection and to prioritize biogas-electricity production from the organic fraction over direct composting. The optimal strategy for refuse derived fuel (RDF) management depends upon the environmental compartment to be prioritized and the type of marginal electricity source in the system. It was estimated that, overall, up to ca. 180-190 kt CO2-eq. y(-1) may be saved by optimizing the MBT plants under assessment. Copyright © 2013 Elsevier Ltd. All rights reserved.

Selective separation of copper over solder alloy from waste printed circuit boards leach solution.

PubMed

Kavousi, Maryam; Sattari, Anahita; Alamdari, Eskandar Keshavarz; Firozi, Sadegh

2017-02-01

The printed circuit boards (PCBs) from electronic waste are important resource, since the PCBs contain precious metals such as gold, copper, tin, silver, platinum and so forth. In addition to the economic point of view, the presence of lead turns this scrap into dangerous to environment. This study was conducted as part of the development of a novel process for selective recovery of copper over tin and lead from printed circuit boards by HBF 4 leaching. In previous study, Copper with solder alloy was associated, simultaneously were leached in HBF 4 solution using hydrogen peroxide as an oxidant at room temperature. The objective of this study is the separation of copper from tin and lead from Fluoroborate media using CP-150 as an extractant. The influence of organic solvent's concentration, pH, temperature and A/O phase ratio was investigated. The possible extraction mechanism and the composition of the extracted species have been determined. The separation factors for these metals using this agent are reported, while efficient methods for separation of Cu (II) from other metal ions are proposed. The treatment of leach liquor for solvent extraction of copper with CP-150 revealed that 20% CP-150 in kerosene, a 30min period of contact time, and a pH of 3 were sufficient for the extraction of Cu(II) and 99.99% copper was recovered from the leached solution. Copyright © 2016. Published by Elsevier Ltd.

40 CFR 262.102 - What special definitions are included in this subpart?

Code of Federal Regulations, 2013 CFR

2013-07-01

... Laboratory Waste means a laboratory waste, defined in the Environmental Management Plan as posing significant potential hazards to human health or the environment and which must include RCRA “P” wastes, and may include... (CONTINUED) SOLID WASTES (CONTINUED) STANDARDS APPLICABLE TO GENERATORS OF HAZARDOUS WASTE University...

Framework for city planning including nature-based solutions (NBS)

NASA Astrophysics Data System (ADS)

Alkan Olsson, Johanna; Sörensen, Johanna; Persson, Anna

2017-04-01

A common strategy to lower the demand for intense land use and energy consumption is the densification of urban areas. While this might be a fruitful strategy for its main objectives, one concern is that space for green areas and surface water will be decreased. Therefore, densification increases the need of strategies to develop and increase the quality of nature-based solutions (NBS) in urban areas. Smarter city planning strategies are needed, both for maintenance of existing NBS and for implementation of NBS in new developments. City planning must be based on well-evaluated solutions, which in turn must be based on a decent data material for each city. Today there is however several type of difficulties related to adequate provision of data to ensure a better implementation of NBS. The challenges arise from issues such as lack of information about for example costs of maintenance of existing NBS, citizens' perceptions and preferred use of NBS to difficulties of a more technical character such as the format of available GIS information. This study focuses on this information gap regarding NBS that persists in most cities today. The project aims to develop a framework that can help city planners to overcome the gaps and facilitate the inclusion of high quality nature-based solutions where developed or maintained. The framework, which is detailed by identifying information gaps through a literature review and selected interviews with urban planners and experts in the area of NBS, is based on the idea that well-structured and user-friendly data supporting city-planning strategies are essential to facilitate the implementation of NBS. What can be understood as well structured and user-friendly data depends on the goals and needs expressed in the strategic plans, which mean that there is a need for a close interaction between the development data and the strategic political goals expressed in the plans.

Integrated management of hazardous waste generated from community sources in Thailand

DOE Office of Scientific and Technical Information (OSTI.GOV)

Yodnane, P.; Spaeder, D.J.

A system for the collection, transport, disposal and recycling of hazardous waste was developed as part of an overall master plan for the management of hazardous waste generated from community sources in Thailand. Results of a waste generation survey conducted as part of the study indicated that over 300 million kilograms per year of hazardous waste is generated from non-industrial, community sources such as automotive repair shops, gas stations, hospitals, farms, and households in Thailand. Hazardous waste from community sources consists primarily of used oils, lead-acid and dry cell batteries, cleaning chemicals, pesticides, medical wastes, solvents and fuels. Most ofmore » this waste was found to be mismanaged by codisposing with municipal waste in burning, unlined dumps, dumping directly to land or water courses, dumping into sewers, or recycling improperly, all of which pose serious threats to human health and the environment. The survey data on waste generation quantities and data from a reconnaissance survey of the conditions and operations of 86 existing waste disposal facilities was incorporated into a nationwide Geographic Information System (GIS) database. Based on this data, problems associated with hazardous waste were identified and needs for waste management systems were tabulated. A system was developed for ranking geographic regions according to hazardous waste management problems and needs, in order to prioritize implementation of waste management programs. The data were also used in developing solutions for hazardous waste management, which addressed methods for storing, collecting, transporting, disposing, and recycling the waste. It was recommended that centralized waste management facilities be utilized which included hazardous waste and medical waste incinerators, waste stabilization units, and secure landfills.« less

Secondary Waste Form Down-Selection Data Package—Fluidized Bed Steam Reforming Waste Form

DOE Office of Scientific and Technical Information (OSTI.GOV)

Qafoku, Nikolla; Westsik, Joseph H.; Strachan, Denis M.

2011-09-12

The Hanford Site in southeast Washington State has 56 million gallons of radioactive and chemically hazardous wastes stored in 177 underground tanks (ORP 2010). The U.S. Department of Energy (DOE), Office of River Protection (ORP), through its contractors, is constructing the Hanford Tank Waste Treatment and Immobilization Plant (WTP) to convert the radioactive and hazardous wastes into stable glass waste forms for disposal. Within the WTP, the pretreatment facility will receive the retrieved waste from the tank farms and separate it into two treated process streams. These waste streams will be vitrified, and the resulting waste canisters will be sentmore » to offsite (high-level waste [HLW]) and onsite (immobilized low-activity waste [ILAW]) repositories. As part of the pretreatment and ILAW processing, liquid secondary wastes will be generated that will be transferred to the Effluent Treatment Facility (ETF) on the Hanford Site for further treatment. These liquid secondary wastes will be converted to stable solid waste forms that will be disposed of in the Integrated Disposal Facility (IDF). To support the selection of a waste form for the liquid secondary wastes from WTP, Washington River Protection Solutions (WRPS) has initiated secondary waste form testing work at Pacific Northwest National Laboratory (PNNL). In anticipation of a down-selection process for a waste form for the Solidification Treatment Unit to be added to the ETF, PNNL is developing data packages to support that down-selection. The objective of the data packages is to identify, evaluate, and summarize the existing information on the four waste forms being considered for stabilizing and solidifying the liquid secondary wastes. At the Hanford Site, the FBSR process is being evaluated as a supplemental technology for treating and immobilizing Hanford LAW radioactive tank waste and for treating secondary wastes from the WTP pretreatment and LAW vitrification processes.« less

Emergy analysis of the recycling options for construction and demolition waste.

PubMed

Yuan, Fang; Shen, Li-yin; Li, Qi-ming

2011-12-01

Construction and demolition (C&D) waste is becoming a major contributor to environmental pollution. In Shanghai, China, the quantity of C&D waste is 2.11E+07 t/yr, which accounts for 45% of the total quantity of solid waste. There has been a growing promotion of recycling C&D waste as an effective way to solve this waste problem. However, the evaluation of the efficiency of recycling C&D waste as a potential source of resources is largely based on traditional economic analysis. The economic analysis emphasizes money instead of the harmony between economic benefit and environmental effects. There is a need for a new strategic approach to investigate the efficiency of recycling C&D waste to achieve the integration between economic, social and environmental effects. Emergy theory can be employed to analyze different recycling options for C&D waste. With reference to the Chinese construction industry, this paper demonstrates that the close-loop recycling option is better than the open-loop recycling option for C&D waste in terms of the integration of social, environmental and sustainable aspects. To evaluate different technology solutions for C&D waste recycling, the emergy theory and method is not limited to a cost-benefit balance but can include economic, social, environmental and sustainable effects. Copyright © 2011 Elsevier Ltd. All rights reserved.

Radioactive Waste.

ERIC Educational Resources Information Center

Blaylock, B. G.

1978-01-01

Presents a literature review of radioactive waste disposal, covering publications of 1976-77. Some of the studies included are: (1) high-level and long-lived wastes, and (2) release and burial of low-level wastes. A list of 42 references is also presented. (HM)

TiO2/bone composite materials for the separation of heavy metal impurities from waste water solutions

NASA Astrophysics Data System (ADS)

Dakroury, G.; Labib, Sh.; Abou El-Nour, F. H.

2012-09-01

Pure bone material obtained from cow meat, as apatite-rich material, and TiO2-bone composite materials are prepared and studied to be used for heavy metal ions separation from waste water solutions. Meat wastes are chemically and thermally treated to control their microstructure in order to prepare the composite materials that fulfill all the requirements to be used as selective membranes with high performance, stability and mechanical strength. The prepared materials are analyzed using Hg-porosimetry for surface characterization, energy dispersive X-ray spectroscopy (EDAX) for elemental analysis and Fourier transform infrared spectroscopy (FTIR) for chemical composition investigation. Structural studies are performed using X-ray diffraction (XRD). Microstructural properties are studied using scanning electron microscopy (SEM) and specific surface area studies are performed using Brunauer-Emmet-Teller (BET) method. XRD studies show that multiphase structures are obtained as a result of 1h sintering at 700-1200 °C for both pure bone and TiO2-bone composite materials. The factors affecting the transport of different heavy metal ions through the selected membranes are determined from permeation flux measurements. It is found that membrane pore size, membrane surface roughness and membrane surface charge are the key parameters that control the transport or rejection of heavy metal ions through the selected membranes.

The cost benefit and efficiency of waste water treatment using domestic ponds—the ultimate solution in Southern Africa

NASA Astrophysics Data System (ADS)

Ntengwe, F. W.

Wastewater treatment has become a challenge to most countries in Southern Africa because of the fluctuating economies that have been hit by high levels of debts. The treatment of domestic wastewater using ponds, if carefully utilized, as has been observed in most countries in the world, is the most cost effective means of handling wastewaters. When compared to the conventional use of treatment plants, the ponds have been observed to be the ultimate solution for the countries in Southern Africa especially those that are classified as Highly Indebted Poor Countries (HIPC) because of little or no operating costs associated with the treatment. The study conducted on Kitwe Waste Water Treatment Ponds to evaluate the cost benefit and efficiencies has revealed low levels of operating cost and high removal efficiencies of oxygen demanding wastes (BOD removal of 86% and TSS removal of 75%), pH values ranged from 7 to 8 indicating an increasing alkalinity from facultative to maturation ponds while other parameters such as nitrates, phosphates and temperature were found to be within acceptable levels thereby releasing effluent that makes the environment sustainable. The overall social benefit was found to be much higher than the operating costs.

One System Integrated Project Team: Retrieval and Delivery of Hanford Tank Wastes for Vitrification in the Waste Treatment Plant - 13234

DOE Office of Scientific and Technical Information (OSTI.GOV)

Harp, Benton J.; Kacich, Richard M.; Skwarek, Raymond J.

The One System Integrated Project Team (IPT) was formed in late 2011 as a way for improving the efficiency of delivery and treatment of highly radioactive waste stored in underground tanks at the U.S. Department of Energy's (DOE's) 586-square-mile Hanford Site in southeastern Washington State. The purpose of the One System IPT is to improve coordination and integration between the Hanford's Waste Treatment Plant (WTP) contractor and the Tank Operations Contractor (TOC). The vision statement is: One System is a WTP and TOC safety-conscious team that, through integrated management and implementation of risk-informed decision and mission-based solutions, will enable themore » earliest start of safe and efficient treatment of Hanford's tank waste, to protect the Columbia River, environment and public. The IPT is a formal collaboration between Bechtel National, Inc. (BNI), which manages design and construction of the WTP for the U.S. Department of Energy's Office of River Protection (DOEORP), and Washington River Protection Solutions (WRPS), which manages the TOC for ORP. More than fifty-six (56) million gallons of highly radioactive liquid waste are stored in one hundred seventy-seven (177) aging, underground tanks. Most of Hanford's waste tanks - one hundred forty-nine (149) of them - are of an old single-shell tank (SST) design built between 1944 and 1964. More than sixty (60) of these tanks have leaked in the past, releasing an estimated one million gallons of waste into the soil and threatening the nearby Columbia River. There are another twenty-eight (28) new double-shelled tanks (DSTs), built from 1968 to 1986, that provide greater protection to the environment. In 1989, DOE, the U.S. Environmental Protection Agency (EPA), and the Washington State Department of Ecology (Ecology) signed a landmark agreement that required Hanford to comply with federal and state environmental standards. It also paved the way for agreements that set deadlines for retrieving the

One System Integrated Project Team: Retrieval And Delivery Of The Hanford Tank Wastes For Vitrification In The Waste Treatment Plant

DOE Office of Scientific and Technical Information (OSTI.GOV)

Harp, Benton J.; Kacich, Richard M.; Skwarek, Raymond J.

The One System Integrated Project Team (IPT) was formed in late 2011 as a way for improving the efficiency of delivery and treatment of highly radioactive waste stored in underground tanks at the U.S. Department of Energy's (DOE's) 586-square-mile Hanford Site in southeastern Washington State. The purpose of the One System IPT is to improve coordination and integration between the Hanford's Waste Treatment Plant (WTP) contractor and the Tank Operations Contractor (TOC). The vision statement is: One System is a WTP and TOC safety conscious team that, through integrated management and implementation of risk-informed decision and mission-based solutions, will enablemore » the earliest start of safe and efficient treatment of Hanford's tank waste, to protect the Columbia River, environment and public. The IPT is a formal collaboration between Bechtel National, Inc. (BNI), which manages design and construction of the WTP for the U.S. Department of Energy's Office of River Protection (DOEORP), and Washington River Protection Solutions (WRPS), which manages the TOC for ORP. More than fifty-six (56) million gallons of highly radioactive liquid waste are stored in one hundred seventy-seven (177) aging, underground tanks. Most of Hanford's waste tanks - one hundred forty-nine (149) of them - are of an old single-shell tank (SST) design built between 1944 and 1964. More than sixty (60) of these tanks have leaked in the past, releasing an estimated one million gallons of waste into the soil and threatening the nearby Columbia River. There are another twenty-eight (28) new double-shelled tanks (DSTs), built from 1968 to 1986, that provide greater protection to the environment. In 1989, DOE, the U.S. Environmental Protection Agency (EPA), and the Washington State Department of Ecology (Ecology) signed a landmark agreement that required Hanford to comply with federal and state environmental standards. It also paved the way for agreements that set deadlines for retrieving the

An implicit finite-difference solution to the viscous shock layer, including the effects of radiation and strong blowing

NASA Technical Reports Server (NTRS)

Garrett, L. B.; Smith, G. L.; Perkins, J. N.

1972-01-01

An implicit finite-difference scheme is developed for the fully coupled solution of the viscous, radiating stagnation-streamline equations, including strong blowing. Solutions are presented for both air injection and injection of carbon-phenolic ablation products into air at conditions near the peak radiative heating point in an earth entry trajectory from interplanetary return missions. A detailed radiative-transport code that accounts for the important radiative exchange processes for gaseous mixtures in local thermodynamic and chemical equilibrium is utilized in the study. With minimum number of assumptions for the initially unknown parameters and profile distributions, convergent solutions to the full stagnation-line equations are rapidly obtained by a method of successive approximations. Damping of selected profiles is required to aid convergence of the solutions for massive blowing. It is shown that certain finite-difference approximations to the governing differential equations stabilize and improve the solutions. Detailed comparisons are made with the numerical results of previous investigations. Results of the present study indicate lower radiative heat fluxes at the wall for carbonphenolic ablation than previously predicted.

Method of waste stabilization via chemically bonded phosphate ceramics

DOEpatents

Wagh, A.S.; Singh, D.; Jeong, S.Y.

1998-11-03

A method for regulating the reaction temperature of a ceramic formulation process is provided comprising supplying a solution containing a monovalent alkali metal; mixing said solution with an oxide powder to create a binder; contacting said binder with bulk material to form a slurry; and allowing the slurry to cure. A highly crystalline waste form is also provided consisting of a binder containing potassium and waste substrate encapsulated by the binder. 3 figs.

Automotive Thermoelectric Waste Heat Recovery

NASA Astrophysics Data System (ADS)

Meisner, Gregory P.

2015-03-01

Considerable fuel energy, as much as 70%, is not converted to useful work by internal combustion engines but is instead rejected as waste heat, and more than half of the waste heat, nearly 40% of fuel energy, is contained in vehicle exhaust gas. This provides an opportunity to recover some of the wasted fuel energy and convert it from heat into useful work, subject to the laws of thermodynamics, and thereby improve vehicle energy efficiency. Thermoelectric (TE) materials have been extensively researched and TE devices are now being developed for operation at high temperatures corresponding to automotive exhaust gases for direct solid-state conversion of heat into electricity. This has stimulated substantial progress in the development of practical TE generator (TEG) systems for large-scale commercialization. A significant enabler of this progress has been the US Department of Energy's Vehicle Technologies Program through funding for low cost solutions for automotive TE waste heat recovery to improve fuel economy. Our current project at General Motors has culminated in the identification of the potential supply chain for all components and assembly of an automotive TEG. A significant focus has been to develop integrated and iterative modeling tools for a fully optimized TEG design that includes all components and subsystems (TE modules, heat exchangers, thermal interfaces, electrical interconnects, power conditioning, and vehicle integration for maximal use of TEG power). We have built and tested a new, low-cost Initial TEG prototype based on state-of-the-art production-scale skutterudite TE modules, novel heat exchanger designs, and practical solutions to the many technical challenges for optimum TEG performance. We will use the results for our Initial TEG prototype to refine our modeling and design tools for a Final automotive TEG system prototype. Our recent results will be presented. Thanks to: J.R. Salvador, E.R. Gundlach, D. Thompson, N.K. Bucknor, M

78 FR 14774 - U.S. Environmental Solutions Toolkit-Universal Waste

Federal Register 2010, 2011, 2012, 2013, 2014

2013-03-07

... following list: (a) Mercury Recycling Technology (b) E-Waste Recycling Technology (c) CRT Recycling Technology (d) Lamp Crushing Systems For purposes of participation in the Toolkit, ``United States exporter...

Infectious waste feed system

DOEpatents

Coulthard, E. James

1994-01-01

An infectious waste feed system for comminuting infectious waste and feeding the comminuted waste to a combustor automatically without the need for human intervention. The system includes a receptacle for accepting waste materials. Preferably, the receptacle includes a first and second compartment and a means for sealing the first and second compartments from the atmosphere. A shredder is disposed to comminute waste materials accepted in the receptacle to a predetermined size. A trough is disposed to receive the comminuted waste materials from the shredder. A feeding means is disposed within the trough and is movable in a first and second direction for feeding the comminuted waste materials to a combustor.

PROCESSING OF RADIOACTIVE WASTE

DOEpatents

Johnson, B.M. Jr.; Barton, G.B.

1961-11-14

A process for treating radioactive waste solutions prior to disposal is described. A water-soluble phosphate, borate, and/or silicate is added. The solution is sprayed with steam into a space heated from 325 to 400 deg C whereby a powder is formed. The powder is melted and calcined at from 800 to 1000 deg C. Water vapor and gaseous products are separated from the glass formed. (AEC)

Noise control of waste water pipes

NASA Astrophysics Data System (ADS)

Lilly, Jerry

2005-09-01

Noise radiated by waste water pipes is a major concern in multifamily housing projects. While the most common solution to this problem is to use cast-iron pipes in lieu of plastic pipes, this may not be sufficient in high-end applications. It should also be noted that many (if not most) multifamily housing projects in the U.S.A. are constructed with plastic waste piping. This paper discusses some of the measures that developers are currently using to control noise from both plastic and cast-iron waste pipes. In addition, results of limited noise measurements of transient water flow in plastic and cast-iron waste pipes will be presented.

Technoeconomic Optimization of Waste Heat Driven Forward Osmosis for Flue Gas Desulfurization Wastewater Treatment

DOE Office of Scientific and Technical Information (OSTI.GOV)

Gingerich, Daniel B; Bartholomew, Timothy V; Mauter, Meagan S

With the Environmental Protection Agency’s recent Effluent Limitation Guidelines for Steam Electric Generators, power plants are having to install and operate new wastewater technologies. Many plants are evaluating desalination technologies as possible compliance options. However, the desalination technologies under review that can reduce wastewater volume or treat to a zero-liquid discharges standard have a significant energy penalty to the plant. Waste heat, available from the exhaust gas or cooling water from coal-fired power plants, offers an opportunity to drive wastewater treatment using thermal desalination technologies. One such technology is forward osmosis (FO). Forward osmosis utilizes an osmotic pressure gradient tomore » passively pull water from a saline or wastewater stream across a semi-permeable membrane and into a more concentrated draw solution. This diluted draw solution is then fed into a distillation column, where the addition of low temperature waste heat can drive the separation to produce a reconcentrated draw solution and treated water for internal plant reuse. The use of low-temperature waste heat decouples water treatment from electricity production and eliminates the link between reducing water pollution and increasing air emissions from auxiliary electricity generation. In order to evaluate the feasibility of waste heat driven FO, we first build a model of an FO system for flue gas desulfurization (FGD) wastewater treatment at coal-fired power plants. This model includes the FO membrane module, the distillation column for draw solution recovery, and waste heat recovery from the exhaust gas. We then add a costing model to account for capital and operating costs of the forward osmosis system. We use this techno-economic model to optimize waste heat driven FO for the treatment of FGD wastewater. We apply this model to three case studies: the National Energy Technology Laboratory (NETL) 550 MW model coal fired power plant without

Coupling plant growth and waste recycling systems in a controlled life support system (CELSS)

NASA Technical Reports Server (NTRS)

Garland, Jay L.

1992-01-01

The development of bioregenerative systems as part of the Controlled Ecological Life Support System (CELSS) program depends, in large part, on the ability to recycle inorganic nutrients, contained in waste material, into plant growth systems. One significant waste (resource) stream is inedible plant material. This research compared wheat growth in hydroponic solutions based on inorganic salts (modified Hoagland's) with solutions based on the soluble fraction of inedible wheat biomass (leachate). Recycled nutrients in leachate solutions provided the majority of mineral nutrients for plant growth, although additions of inorganic nutrients to leachate solutions were necessary. Results indicate that plant growth and waste recyling systems can be effectively coupled within CELSS based on equivalent wheat yield in leachate and Hoagland solutions, and the rapid mineralization of waste organic material in the hydroponic systems. Selective enrichment for microbial communities able to mineralize organic material within the leachate was necessary to prevent accumulation of dissolved organic matter in leachate-based solutions. Extensive analysis of microbial abundance, growth, and activity in the hydroponic systems indicated that addition of soluble organic material from plants does not cause excessive microbial growth or 'biofouling', and helped define the microbially-mediated flux of carbon in hydroponic solutions.

Radiation-driven winds of hot stars. VI - Analytical solutions for wind models including the finite cone angle effect

NASA Technical Reports Server (NTRS)

Kudritzki, R. P.; Pauldrach, A.; Puls, J.; Abbott, D. C.

1989-01-01

Analytical solutions for radiation-driven winds of hot stars including the important finite cone angle effect (see Pauldrach et al., 1986; Friend and Abbott, 1986) are derived which approximate the detailed numerical solutions of the exact wind equation of motion very well. They allow a detailed discussion of the finite cone angle effect and provide for given line force parameters k, alpha, delta definite formulas for mass-loss rate M and terminal velocity v-alpha as function of stellar parameters.

Potential use of Plastic Waste as Construction Materials: Recent Progress and Future Prospect

NASA Astrophysics Data System (ADS)

Kamaruddin, M. A.; Abdullah, M. M. A.; Zawawi, M. H.; Zainol, M. R. R. A.

2017-11-01

Plastic associates products based have been considered as the world most consumer packaging solution. However, substantial quantities of plastic consumption have led to exponential increase of plastic derived waste. Recycling of plastic waste as valued added product such as concrete appears as one of promising solution for alternative use of plastic waste. This paper summarized recent progress on the development of concrete mixture which incorporates plastic wastes as partial aggregate replacement during concrete manufacturing. A collection of data from previous studies that have been researched which employed plastic waste in concrete mixtures were evaluated and conclusions are drawn based on the laboratory results of all the mentioned research papers studied.

Reclamation of landfills and dumps of municipal solid waste in a energy efficient waste management system: methodology and practice

NASA Astrophysics Data System (ADS)

Orlova, Tatyana; Melnichuk, Aleksandr; Klimenko, Kseniya; Vitvitskaya, Valentina; Popovych, Valentina; Dunaieva, Ielizaveta; Terleev, Vitaly; Nikonorov, Aleksandr; Togo, Issa; Volkova, Yulia; Mirschel, Wilfried; Garmanov, Vitaly

2017-10-01

The article considers the methodological and practical aspects of reclamation of landfills and dumps of municipal solid waste in a waste management system. The general tendencies of system development in the context of elements of the international concept of waste hierarchy are analyzed. Statistics of the formation and burial of domestic waste indicate a strategic non-alternative to the rejection of landfill technologies in favor of environmentally, energy efficient and economically expedient ways of utilization of municipal waste as a world trend. Practical approaches to the study of territories on which there are dumps and landfills are considered to justify the design solutions for reclamation.

Solitary solutions including spatially localized chaos and their interactions in two-dimensional Kolmogorov flow.

PubMed

Hiruta, Yoshiki; Toh, Sadayoshi

2015-12-01

Two-dimensional Kolmogorov flow in wide periodic boxes is numerically investigated. It is shown that the total flow rate in the direction perpendicular to the force controls the characteristics of the flow, especially the existence of spatially localized solitary solutions such as traveling waves, periodic solutions, and chaotic solutions, which can behave as elementary components of the flow. We propose a procedure to construct approximate solutions consisting of solitary solutions. It is confirmed by direct numerical simulations that these solutions are stable and represent interactions between elementary components such as collisions, coexistence, and collapse of chaos.

Gasification: An alternative solution for energy recovery and utilization of vegetable market waste.

PubMed

Narnaware, Sunil L; Srivastava, Nsl; Vahora, Samir

2017-03-01

Vegetables waste is generally utilized through a bioconversion process or disposed of at municipal landfills, dumping sites or dumped on open land, emitting a foul odor and causing health hazards. The presents study deals with an alternative way to utilize solid vegetable waste through a thermochemical route such as briquetting and gasification for its energy recovery and subsequent power generation. Briquettes of 50 mm diameter were produced from four different types of vegetable waste. The bulk density of briquettes produced was increased 10 to 15 times higher than the density of the dried vegetable waste in loose form. The lower heating value (LHV) of the briquettes ranged from 10.26 MJ kg -1 to 16.60 MJ kg -1 depending on the type of vegetable waste. The gasification of the briquettes was carried out in an open core downdraft gasifier, which resulted in syngas with a calorific value of 4.71 MJ Nm -3 at the gasification temperature between 889°C and 1011°C. A spark ignition, internal combustion engine was run on syngas and could generate a maximum load up to 10 kW e . The cold gas efficiency and the hot gas efficiency of the gasifier were measured at 74.11% and 79.87%, respectively. Energy recovery from the organic vegetable waste was possible through a thermochemical conversion route such as briquetting and subsequent gasification and recovery of the fuel for small-scale power generation.

High removal efficacy of Hg(II) and MeHg(II) ions from aqueous solution by organoalkoxysilane-grafted lignocellulosic waste biomass.

PubMed

Saman, Norasikin; Johari, Khairiraihanna; Song, Shiow-Tien; Kong, Helen; Cheu, Siew-Chin; Mat, Hanapi

2017-03-01

An effective organoalkoxysilanes-grafted lignocellulosic waste biomass (OS-LWB) adsorbent aiming for high removal towards inorganic and organic mercury (Hg(II) and MeHg(II)) ions was prepared. Organoalkoxysilanes (OS) namely mercaptoproyltriethoxylsilane (MPTES), aminopropyltriethoxylsilane (APTES), aminoethylaminopropyltriethoxylsilane (AEPTES), bis(triethoxysilylpropyl) tetrasulfide (BTESPT), methacrylopropyltrimethoxylsilane (MPS) and ureidopropyltriethoxylsilane (URS) were grafted onto the LWB using the same conditions. The MPTES grafted lignocellulosic waste biomass (MPTES-LWB) showed the highest adsorption capacity towards both mercury ions. The adsorption behavior of inorganic and organic mercury ions (Hg(II) and MeHg(II)) in batch adsorption studies shows that it was independent with pH of the solutions and dependent on initial concentration, temperature and contact time. The maximum adsorption capacity of Hg(II) was greater than MeHg(II) which respectively followed the Temkin and Langmuir models. The kinetic data analysis showed that the adsorptions of Hg(II) and MeHg(II) onto MPTES-LWB were respectively controlled by the physical process of film diffusion and the chemical process of physisorption interactions. The overall mechanism of Hg(II) and MeHg(II) adsorption was a combination of diffusion and chemical interaction mechanisms. Regeneration results were very encouraging especially for the Hg(II); this therefore further demonstrated the potential application of organosilane-grafted lignocellulosic waste biomass as low-cost adsorbents for mercury removal process. Copyright © 2016 Elsevier Ltd. All rights reserved.

Food Waste to Energy: An Overview of Sustainable Approaches for Food Waste Management and Nutrient Recycling

PubMed Central

Paritosh, Kunwar; Kushwaha, Sandeep K.; Yadav, Monika; Pareek, Nidhi; Chawade, Aakash

2017-01-01

Food wastage and its accumulation are becoming a critical problem around the globe due to continuous increase of the world population. The exponential growth in food waste is imposing serious threats to our society like environmental pollution, health risk, and scarcity of dumping land. There is an urgent need to take appropriate measures to reduce food waste burden by adopting standard management practices. Currently, various kinds of approaches are investigated in waste food processing and management for societal benefits and applications. Anaerobic digestion approach has appeared as one of the most ecofriendly and promising solutions for food wastes management, energy, and nutrient production, which can contribute to world's ever-increasing energy requirements. Here, we have briefly described and explored the different aspects of anaerobic biodegrading approaches for food waste, effects of cosubstrates, effect of environmental factors, contribution of microbial population, and available computational resources for food waste management researches. PMID:28293629

Food Waste to Energy: An Overview of Sustainable Approaches for Food Waste Management and Nutrient Recycling.

PubMed

Paritosh, Kunwar; Kushwaha, Sandeep K; Yadav, Monika; Pareek, Nidhi; Chawade, Aakash; Vivekanand, Vivekanand

2017-01-01

Food wastage and its accumulation are becoming a critical problem around the globe due to continuous increase of the world population. The exponential growth in food waste is imposing serious threats to our society like environmental pollution, health risk, and scarcity of dumping land. There is an urgent need to take appropriate measures to reduce food waste burden by adopting standard management practices. Currently, various kinds of approaches are investigated in waste food processing and management for societal benefits and applications. Anaerobic digestion approach has appeared as one of the most ecofriendly and promising solutions for food wastes management, energy, and nutrient production, which can contribute to world's ever-increasing energy requirements. Here, we have briefly described and explored the different aspects of anaerobic biodegrading approaches for food waste, effects of cosubstrates, effect of environmental factors, contribution of microbial population, and available computational resources for food waste management researches.

Acceptable knowledge document for INEEL stored transuranic waste -- Rocky Flats Plant waste. Revision 2

DOE Office of Scientific and Technical Information (OSTI.GOV)

NONE

1998-01-23

This document and supporting documentation provide a consistent, defensible, and auditable record of acceptable knowledge for waste generated at the Rocky Flats Plant which is currently in the accessible storage inventory at the Idaho National Engineering and Environmental Laboratory. The inventory consists of transuranic (TRU) waste generated from 1972 through 1989. Regulations authorize waste generators and treatment, storage, and disposal facilities to use acceptable knowledge in appropriate circumstances to make hazardous waste determinations. Acceptable knowledge includes information relating to plant history, process operations, and waste management, in addition to waste-specific data generated prior to the effective date of the RCRAmore » regulations. This document is organized to provide the reader a comprehensive presentation of the TRU waste inventory ranging from descriptions of the historical plant operations that generated and managed the waste to specific information about the composition of each waste group. Section 2 lists the requirements that dictate and direct TRU waste characterization and authorize the use of the acceptable knowledge approach. In addition to defining the TRU waste inventory, Section 3 summarizes the historical operations, waste management, characterization, and certification activities associated with the inventory. Sections 5.0 through 26.0 describe the waste groups in the inventory including waste generation, waste packaging, and waste characterization. This document includes an expanded discussion for each waste group of potential radionuclide contaminants, in addition to other physical properties and interferences that could potentially impact radioassay systems.« less

E-waste: a problem or an opportunity? Review of issues, challenges and solutions in Asian countries.

PubMed

Herat, Sunil; Agamuthu, P

2012-11-01

Safe management of electronic and electrical waste (e-waste/WEEE) is becoming a major problem for many countries around the world. In particular, developing countries face a number of issues with the generation, transboundary movement and management of e-waste. It is estimated that the world generates around 20-50 million tonnes of e-waste annually, most of it from Asian countries. Improper handling of e-waste can cause harm to the environment and human health because of its toxic components. Several countries around the world are now struggling to deal with this emerging threat. Although the current emphasis is on end-of-life management of e-waste activities, such as reuse, servicing, remanufacturing, recycling and disposal, upstream reduction of e-waste generation through green design and cleaner production is gaining much attention. Environmentally sound management (ESM) of e-waste in developing countries is absent or very limited. Transboundary movement of e-waste is a major issue throughout the region. Dealing with the informal recycling sector is a complex social and environmental issue. There are significant numbers of such challenges faced by these countries in achieving ESM of e-waste. This article aims to present a review of challenges and issues faced by Asian countries in managing their e-waste in a sustainable way.

Performance of a Steel/Oxide Composite Waste Form for Combined Waste Steams from Advanced Electrochemical Processes

DOE Office of Scientific and Technical Information (OSTI.GOV)

Indacochea, J. E.; Gattu, V. K.; Chen, X.

The results of electrochemical corrosion tests and modeling activities performed collaboratively by researchers at the University of Illinois at Chicago and Argonne National Laboratory as part of workpackage NU-13-IL-UIC-0203-02 are summarized herein. The overall objective of the project was to develop and demonstrate testing and modeling approaches that could be used to evaluate the use of composite alloy/ceramic materials as high-level durable waste forms. Several prototypical composite waste form materials were made from stainless steels representing fuel cladding, reagent metals representing metallic fuel waste streams, and reagent oxides representing oxide fuel waste streams to study the microstructures and corrosion behaviorsmore » of the oxide and alloy phases. Microelectrodes fabricated from small specimens of the composite materials were used in a series of electrochemical tests to assess the corrosion behaviors of the constituent phases and phase boundaries in an aggressive acid brine solution at various imposed surface potentials. The microstructures were characterized in detail before and after the electrochemical tests to relate the electrochemical responses to changes in both the electrode surface and the solution composition. The results of microscopic, electrochemical, and solution analyses were used to develop equivalent circuit and physical models representing the measured corrosion behaviors of the different materials pertinent to long-term corrosion behavior. This report provides details regarding (1) the production of the composite materials, (2) the protocol for the electrochemical measurements and interpretations of the responses of multi-phase alloy and oxide composites, (3) relating corrosion behaviors to microstructures of multi-phase alloys based on 316L stainless steel and HT9 (410 stainless steel was used as a substitute) with added Mo, Ni, and/or Mn, and (4) modeling the corrosion behaviors and rates of several alloy/oxide composite

Minimising food waste: a call for multidisciplinary research.

PubMed

Alamar, Maria Del Carmen; Falagán, Natalia; Aktas, Emel; Terry, Leon A

2018-01-01

Food losses and waste have always been a significant global problem for mankind, and one which has become increasingly recognised as such by policy makers, food producers, processors, retailers, and consumers. It is, however, an emotive subject whereby the extent, accuracy and resolution of available data on postharvest loss and waste are questionable, such that key performance indicators on waste can be misinformed. The nature and extent of food waste differ among developed economies, economies in transition and developing countries. While most emphasis has been put on increasing future crop production, far less resource has been and is still channelled towards enabling both established and innovative food preservation technologies to reduce food waste while maintaining safety and quality. Reducing food loss and waste is a more tractable problem than increasing production in the short to medium term, as its solution is not directly limited, for instance, by available land and water resources. Here we argue the need for a paradigm shift of current funding strategies and research programmes that will encourage the development, implementation and translation of collective biological, engineering and management solutions to better preserve and utilise food. Such multidisciplinary thinking across global supply chains is an essential element in the pursuit of achieving sustainable food and nutritional security. The implementation of allied technological and management solutions is reliant on there being sufficient skilled human capital and resources. There is currently a lack of robust postharvest research networks outside of the developed world, and insufficient global funding mechanisms that can support such interdisciplinary collaborations. There is, thus, a collective need for schemes that encourage inter-supply chain research, knowledge exchange and capacity building to reduce food losses and waste. © 2017 Society of Chemical Industry. © 2017 Society of Chemical

Estimation of marginal costs at existing waste treatment facilities.

PubMed

Martinez-Sanchez, Veronica; Hulgaard, Tore; Hindsgaul, Claus; Riber, Christian; Kamuk, Bettina; Astrup, Thomas F

2016-04-01

address and include costs in existing waste facilities in decision-making may unintendedly lead to higher overall costs at societal level. To avoid misleading conclusions, economic assessment of alternative SWM solutions should not only consider potential costs associated with alternative treatment but also include marginal costs associated with existing facilities. Copyright © 2016 Elsevier Ltd. All rights reserved.

LEACHING BOUNDARY MOVEMENT IN SOLIDIFIED/STABILIZED WASTE FORMS

EPA Science Inventory

Investigation of the leaching of cement-based waste forms in acetic acid solutions found that acids attacked the waste form from the surface toward the center. A sharp leaching boundary was identified in every leached sample, using pH color indica- tors. The movement of the leach...

SELECTIVE REMOVAL OF STRONTIUM AND CESIUM FROM SIMULATED WASTE SOLUTION WITH TITANATE ION-EXCHANGERS IN A FILTER CARTRIDGE CONFIGURATIONS-12092

DOE Office of Scientific and Technical Information (OSTI.GOV)

Oji, L.; Martin, K.; Hobbs, D.

2012-01-03

Experimental results for the selective removal of strontium and cesium from simulated waste solutions with monosodium titanate and crystalline silicotitanate laden filter cartridges are presented. In these proof-of-principle tests, effective uptake of both strontium-85 and cesium-137 were observed using ion-exchangers in this filter cartridge configuration. At low salt simulant conditions, the instantaneous decontamination factor for strontium-85 with monosodium titanate impregnated filter membrane cartridges measured 26, representing 96% strontium-85 removal efficiency. On the other hand, the strontium-85 instantaneous decontamination factor with co-sintered active monosodium titanate cartridges measured 40 or 98% Sr-85 removal efficiency. Strontium-85 removal with the monosodium titanate impregnated membranemore » cartridges and crystalline silicotitanate impregnated membrane cartridges, placed in series arrangement, produced an instantaneous decontamination factor of 41 compared to an instantaneous decontamination factor of 368 for strontium-85 with co-sintered active monosodium titanate cartridges and co-sintered active crystalline silicotitanate cartridges placed in series. Overall, polyethylene co-sintered active titanates cartridges performed as well as titanate impregnated filter membrane cartridges in the uptake of strontium. At low ionic strength conditions, there was a significant uptake of cesium-137 with co-sintered crystalline silicotitanate cartridges. Tests results with crystalline silicotitanate impregnated membrane cartridges for cesium-137 decontamination are currently being re-evaluated. Based on these preliminary findings we conclude that incorporating monosodium titanate and crystalline silicotitanate sorbents into membranes represent a promising method for the semicontinuous removal of radioisotopes of strontium and cesium from nuclear waste solutions.« less

Pretreatment of Hanford medium-curie wastes by fractional crystallization.

PubMed

Nassif, Laurent; Dumont, George; Alysouri, Hatem; Rousseau, Ronald W

2008-07-01

Acceleration of the schedule for decontamination of the Hanford site using bulk vitrification requires implementation of a pretreatment operation. Medium-curie waste must be separated into two fractions: one is to go to a waste treatment and immobilization plant and a second, which is low-activity waste, is to be processed by bulk vitrification. The work described here reports research on using fractional crystallization for that pretreatment. Sodium salts are crystallized by evaporation of water from solutions simulating those removed from single-shell tanks, while leaving cesium in solution. The crystalline products are then recovered and qualified as low-activity waste, which is suitable upon redissolution for processing by bulk vitrification. The experimental program used semibatch operation in which a feed solution was continuously added to maintain a constant level in the crystallizer while evaporating water. The slurry recovered at the end of a run was filtered to recover product crystals, which were then analyzed to determine their composition. The results demonstrated that targets on cesium separation from the solids, fractional recovery of sodium salts, and sulfate content of the recovered salts can be achieved by the process tested.

Summary Report of Comprehensive Laboratory Testing to Establish the Effectiveness of Proposed Treatment Methods for Unremediated and Remediated Nitrate Salt Waste Streams

DOE Office of Scientific and Technical Information (OSTI.GOV)

Anast, Kurt Roy; Funk, David John; Hargis, Kenneth Marshall

The inadvertent creation of transuranic waste carrying hazardous waste codes D001 and D002 requires the treatment of the material to eliminate the hazardous characteristics and allow its eventual shipment and disposal at the Waste Isolation Pilot Plant (WIPP). This report documents the effectiveness of two treatment methods proposed to stabilize both the unremediated and remediated nitrate salt waste streams (UNS and RNS, respectively) at Los Alamos National Laboratory (LANL). The two technologies include the addition of zeolite (with and without the addition of water as a processing aid) and cementation. Surrogates were developed to evaluate both the solid and liquidmore » fractions expected from parent waste containers, and both the solid and liquid fractions were tested. Both technologies are shown to be effective at eliminating the characteristic of ignitability (D001), and the addition of zeolite was determined to be effective at eliminating corrosivity (D002), with the preferred option1 of adding zeolite currently planned for implementation at LANL’s Waste Characterization, Reduction, and Repackaging Facility (WCRRF). The course of this work verified the need to evaluate and demonstrate the effectiveness of the proposed remedy for debris material, if required. The evaluation determined that WypAlls, cheesecloth, and Celotex absorbed with saturated nitrate salt solutions exhibit the ignitability characteristic (all other expected debris is not classified as ignitable). Finally, liquid surrogates containing saturated nitrate salts did not exhibit the characteristic of ignitability in their pure form (those neutralized with Kolorsafe and mixed with sWheat did exhibit D001). Sensitivity testing and an analysis were conducted to evaluate the waste form for reactivity. Tests included subjecting surrogate material to mechanical impact, friction, electrostatic discharge and thermal insults. The testing confirmed that the waste does not exhibit the characteristic

WIPP waste characterization program sampling and analysis guidance manual

DOE Office of Scientific and Technical Information (OSTI.GOV)

Not Available

1991-01-01

The Waste Isolation Pilot Plant (WIPP) Waste Characterization Program Sampling and Analysis Guidance Manual (Guidance Manual) provides a unified source of information on the sampling and analytical techniques that enable Department of Energy (DOE) facilities to comply with the requirements established in the current revision of the Quality Assurance Program Plan (QAPP) for the WIPP Experimental-Waste Characterization Program (the Program). This Guidance Manual includes all of the sampling and testing methodologies accepted by the WIPP Project Office (DOE/WPO) for use in implementing the Program requirements specified in the QAPP. This includes methods for characterizing representative samples of transuranic (TRU) wastesmore » at DOE generator sites with respect to the gas generation controlling variables defined in the WIPP bin-scale and alcove test plans, as well as waste container headspace gas sampling and analytical procedures to support waste characterization requirements under the WIPP test program and the Resource Conservation and Recovery Act (RCRA). The procedures in this Guidance Manual are comprehensive and detailed and are designed to provide the necessary guidance for the preparation of site specific procedures. The use of these procedures is intended to provide the necessary sensitivity, specificity, precision, and comparability of analyses and test results. The solutions to achieving specific program objectives will depend upon facility constraints, compliance with DOE Orders and DOE facilities' operating contractor requirements, and the knowledge and experience of the TRU waste handlers and analysts. With some analytical methods, such as gas chromatography/mass spectrometry, the Guidance Manual procedures may be used directly. With other methods, such as nondestructive/destructive characterization, the Guidance Manual provides guidance rather than a step-by-step procedure.« less

Heavy metal removal from aqueous solutions using engineered magnetic biochars derived from waste marine macro-algal biomass.

PubMed

Son, Eun-Bi; Poo, Kyung-Min; Chang, Jae-Soo; Chae, Kyu-Jung

2018-02-15

Despite the excellent sorption ability of biochar for heavy metals, it is difficult to separate and reuse after adsorption when applied to wastewater treatment process. To overcome these drawbacks, we developed an engineered magnetic biochar by pyrolyzing waste marine macro-algae as a feedstock, and we doped iron oxide particles (e.g., magnetite, maghemite) to impart magnetism. The physicochemical characteristics and adsorption properties of the biochar were evaluated. When compared to conventional pinewood sawdust biochar, the waste marine algae-based magnetic biochar exhibited a greater potential to remove heavy metals despite having a lower surface area (0.97m 2 /g for kelp magnetic biochar and 63.33m 2 /g for hijikia magnetic biochar). Although magnetic biochar could be effectively separated from the solution, however, the magnetization of the biochar partially reduced its heavy metal adsorption efficiency due to the biochar's surface pores becoming plugged with iron oxide particles. Therefore, it is vital to determine the optimum amount of iron doping that maximizes the biochar's separation without sacrificing its heavy metal adsorption efficiency. The optimum concentration of the iron loading solution for the magnetic biochar was determined to be 0.025-0.05mol/L. The magnetic biochar's heavy metal adsorption capability is considerably higher than that of other types of biochar reported previously. Further, it demonstrated a high selectivity for copper, showing two-fold greater removal (69.37mg/g for kelp magnetic biochar and 63.52mg/g for hijikia magnetic biochar) than zinc and cadmium. This high heavy metal removal performance can likely be attributed to the abundant presence of various oxygen-containing functional groups (COOH and OH) on the magnetic biochar, which serve as potential adsorption sites for heavy metals. The unique features of its high heavy metal removal performance and easy separation suggest that the magnetic algae biochar can potentially

Exact solutions of the population balance equation including particle transport, using group analysis

NASA Astrophysics Data System (ADS)

Lin, Fubiao; Meleshko, Sergey V.; Flood, Adrian E.

2018-06-01

The population balance equation (PBE) has received an unprecedented amount of attention in recent years from both academics and industrial practitioners because of its long history, widespread use in engineering, and applicability to a wide variety of particulate and discrete-phase processes. However it is typically impossible to obtain analytical solutions, although in almost every case a numerical solution of the PBEs can be obtained. In this article, the symmetries of PBEs with homogeneous coagulation kernels involving aggregation, breakage and growth processes and particle transport in one dimension are found by direct solving the determining equations. Using the optimal system of one and two-dimensional subalgebras, all invariant solutions and reduced equations are obtained. In particular, an explicit analytical physical solution is also presented.

Stabilization and disposal of Argonne-West low-level mixed wastes in ceramicrete waste forms.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Barber, D. B.; Singh, D.; Strain, R. V.

1998-02-17

The technology of room-temperature-setting phosphate ceramics or Ceramicrete{trademark} technology, developed at Argonne National Laboratory (ANL)-East is being used to treat and dispose of low-level mixed wastes through the Department of Energy complex. During the past year, Ceramicrete{trademark} technology was implemented for field application at ANL-West. Debris wastes were treated and stabilized: (a) Hg-contaminated low-level radioactive crushed light bulbs and (b) low-level radioactive Pb-lined gloves (part of the MWIR {number_sign} AW-W002 waste stream). In addition to hazardous metals, these wastes are contaminated with low-level fission products. Initially, bench-scale waste forms with simulated and actual waste streams were fabricated by acid-base reactionsmore » between mixtures of magnesium oxide powders and an acid phosphate solution, and the wastes. Size reduction of Pb-lined plastic glove waste was accomplished by cryofractionation. The Ceramicrete{trademark} process produces dense, hard ceramic waste forms. Toxicity Characteristic Leaching Procedure (TCLP) results showed excellent stabilization of both Hg and Pb in the waste forms. The principal advantage of this technology is that immobilization of contaminants is the result of both chemical stabilization and subsequent microencapsulation of the reaction products. Based on bench-scale studies, Ceramicrete{trademark} technology has been implemented in the fabrication of 5-gal waste forms at ANL-West. Approximately 35 kg of real waste has been treated. The TCLP is being conducted on the samples from the 5-gal waste forms. It is expected that because the waste forms pass the limits set by the EPAs Universal Treatment Standard, they will be sent to a radioactive-waste disposal facility.« less

Radioactive waste storage issues

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kunz, Daniel E.

1994-08-15

In the United States we generate greater than 500 million tons of toxic waste per year which pose a threat to human health and the environment. Some of the most toxic of these wastes are those that are radioactively contaminated. This thesis explores the need for permanent disposal facilities to isolate radioactive waste materials that are being stored temporarily, and therefore potentially unsafely, at generating facilities. Because of current controversies involving the interstate transfer of toxic waste, more states are restricting the flow of wastes into - their borders with the resultant outcome of requiring the management (storage and disposal)more » of wastes generated solely within a state`s boundary to remain there. The purpose of this project is to study nuclear waste storage issues and public perceptions of this important matter. Temporary storage at generating facilities is a cause for safety concerns and underscores, the need for the opening of permanent disposal sites. Political controversies and public concern are forcing states to look within their own borders to find solutions to this difficult problem. Permanent disposal or retrievable storage for radioactive waste may become a necessity in the near future in Colorado. Suitable areas that could support - a nuclear storage/disposal site need to be explored to make certain the health, safety and environment of our citizens now, and that of future generations, will be protected.« less

WASTE RESEARCH STRATEGY

EPA Science Inventory

The Waste Research Strategy covers research necessary to support both the proper management of solid and hazardous wastes and the effective remediation of contaminated waste sites. This research includes improving the assessment of existing environmental risks, as well as develop...

TREATMENT OF AMMONIUM NITRATE SOLUTIONS

DOEpatents

Boyer, T.W.; MacHutchin, J.G.; Yaffe, L.

1958-06-10

The treatment of waste solutions obtained in the processing of neutron- irradiated uranium containing fission products and ammonium nitrate is described. The object of this process is to provide a method whereby the ammonium nitrate is destroyed and removed from the solution so as to permit subsequent concentration of the solution.. In accordance with the process the residual nitrate solutions are treated with an excess of alkyl acid anhydride, such as acetic anhydride. Preferably, the residual nitrate solution is added to an excess of the acetic anhydride at such a rate that external heat is not required. The result of this operation is that the ammonium nitrate and acetic anhydride react to form N/sub 2/ O and acetic acid.

Electrochemical probing of high-level radioactive waste tanks containing washed sludge and precipitates

DOE Office of Scientific and Technical Information (OSTI.GOV)

Bickford, D.F.; Congdon, J.W.; Oblath, S.B.

1987-01-01

At the U.S. Department of Energy's Savannah River Plant, corrosion of carbon steel storage tanks containing alkaline, high-level radioactive waste is controlled by specification of limits on waste composition and temperature. Processes for the preparation of waste for final disposal will result in waste with low corrosion inhibitor concentrations and, in some cases, high aromatic organic concentrations, neither of which are characteristic of previous operations. Laboratory tests, conducted to determine minimum corrosion inhibitor levels indicated pitting of carbon steel near the waterline for proposed storage conditions. In situ electrochemical measurements of full-scale radioactive process demonstrations have been conducted to assessmore » the validity of laboratory tests. Probes included pH, Eh (potential relative to a standard hydrogen electrode), tank potential, and alloy coupons. In situ results are compared to those of the laboratory tests, with particular regard given to simulated solution composition.« less

Nuclear waste solidification

DOEpatents

Bjorklund, William J.

1977-01-01

High level liquid waste solidification is achieved on a continuous basis by atomizing the liquid waste and introducing the atomized liquid waste into a reaction chamber including a fluidized, heated inert bed to effect calcination of the atomized waste and removal of the calcined waste by overflow removal and by attrition and elutriation from the reaction chamber, and feeding additional inert bed particles to the fluidized bed to maintain the inert bed composition.

Bio-extraction of precious metals from urban solid waste

NASA Astrophysics Data System (ADS)

Das, Subhabrata; Natarajan, Gayathri; Ting, Yen-Peng

2017-01-01

Reduced product lifecycle and increasing demand for electronic devices have resulted in the generation of huge volumes of electronic waste (e-waste). E-wastes contain high concentrations of toxic heavy metals, which have detrimental effects on health and the environment. However, e-wastes also contain significant concentrations of precious metals such as gold, silver and palladium, which can be a major driving force for recycling of urban waste. Cyanogenic bacteria such as Chromobacterium violaceum generate cyanide as a secondary metabolite which mobilizes gold into solution via a soluble gold-cyanide complex. However, compared to conventional technology for metal recovery, this approach is not effective, owing largely to the low concentration of lixiviants produced by the bacteria. To overcome the challenges of bioleaching of gold from e-waste, several strategies were adopted to enhance gold recovery rates. These included (i) pretreatment of e-waste to remove competing metal ions, (ii) mutation to adapt the bacteria to high pH environment, (iii) metabolic engineering to produce higher cyanide lixiviant, and (iv) spent medium leaching with adjusted initial pH. Compared to 7.1 % recovery by the wild type bacteria, these strategies achieved gold recoveries of 11.3%, 22.5%, 30% and 30% respectively at 0.5% w/v pulp density respectively. Bioleached gold was finally mineralized and precipitated as gold nanoparticles using the bacterium Delftia acidovorans. This study demonstrates the potential for enhancement of biocyanide production and gold recovery from electronic waste through different strategies, and extraction of solid gold from bioleached leachate.

Metallurgical recovery of metals from electronic waste: a review.

PubMed

Cui, Jirang; Zhang, Lifeng

2008-10-30

Waste electric and electronic equipment, or electronic waste, has been taken into consideration not only by the government but also by the public due to their hazardous material contents. In the detailed literature survey, value distributions for different electronic waste samples were calculated. It is showed that the major economic driver for recycling of electronic waste is from the recovery of precious metals. The state of the art in recovery of precious metals from electronic waste by pyrometallurgical processing, hydrometallurgical processing, and biometallurgical processing are highlighted in the paper. Pyrometallurgical processing has been a traditional technology for recovery of precious metals from waste electronic equipment. However, state-of-the-art smelters are highly depended on investments. Recent research on recovery of energy from PC waste gives an example for using plastics in this waste stream. It indicates that thermal processing provides a feasible approach for recovery of energy from electronic waste if a comprehensive emission control system is installed. In the last decade, attentions have been removed from pyrometallurgical process to hydrometallurgical process for recovery of metals from electronic waste. In the paper, hydrometallurgical processing techniques including cyanide leaching, halide leaching, thiourea leaching, and thiosulfate leaching of precious metals are detailed. In order to develop an environmentally friendly technique for recovery of precious metals from electronic scrap, a critical comparison of main leaching methods is analyzed for both economic feasibility and environmental impact. It is believed that biotechnology has been one of the most promising technologies in metallurgical processing. Bioleaching has been used for recovery of precious metals and copper from ores for many years. However, limited research was carried out on the bioleaching of metals from electronic waste. In the review, initial researches on the

APPROXIMATE AND ANALYTICAL SOLUTIONS FOR SOLUTE TRANSPORT FROM AN INJECTION WELL INTO A SINGLE FRACTURE

EPA Science Inventory

In dealing with problems related to land-based nuclear waste management, a number of analytical and approximate solutions were developed to quantify radionuclide transport through fractures contained in the porous formation. t has been reported that by treating the radioactive de...

Waste canister for storage of nuclear wastes

DOEpatents

Duffy, James B.

1977-01-01

A waste canister for storage of nuclear wastes in the form of a solidified glass includes fins supported from the center with the tips of the fins spaced away from the wall to conduct heat away from the center without producing unacceptable hot spots in the canister wall.

Dangerous Waste Characteristics of Contact-Handled Transuranic Mixed Wastes from Hanford Tanks

DOE Office of Scientific and Technical Information (OSTI.GOV)

Tingey, Joel M.; Bryan, Garry H.; Deschane, Jaquetta R.

2004-10-05

This report summarizes existing analytical data gleaned from samples taken from the Hanford tanks designated as potentially containing transuranic mixed process wastes. Process knowledge of the wastes transferred to these tanks has been reviewed to determine whether the dangerous waste characteristics now assigned to all Hanford underground storage tanks are applicable to these particular wastes. Supplemental technologies are being examined to accelerate the Hanford tank waste cleanup mission and accomplish waste treatment safely and efficiently. To date, 11 Hanford waste tanks have been designated as potentially containing contact-handled (CH) transuranic mixed (TRUM) wastes. The CH-TRUM wastes are found in single-shellmore » tanks B-201 through B-204, T-201 through T-204, T-104, T-110, and T-111. Methods and equipment to solidify and package the CH-TRUM wastes are part of the supplemental technologies being evaluated. The resulting packages and wastes must be acceptable for disposal at the Waste Isolation Pilot Plant (WIPP). The dangerous waste characteristics being considered include ignitability, corrosivity, reactivity, and toxicity arising from the presence of 2,4,5-trichlorophenol at levels above the dangerous waste threshold. The analytical data reviewed include concentrations of sulfur, sulfate, cyanide, 2,4,5-trichlorophenol, total organic carbon, and oxalate; the composition of the tank headspace, pH, and mercury. Differential scanning calorimetry results were used to determine the energetics of the wastes as a function of temperature. This report supercedes and replaces PNNL-14832.« less

VS2DRTI: Simulating Heat and Reactive Solute Transport in Variably Saturated Porous Media.

PubMed

Healy, Richard W; Haile, Sosina S; Parkhurst, David L; Charlton, Scott R

2018-01-29

Variably saturated groundwater flow, heat transport, and solute transport are important processes in environmental phenomena, such as the natural evolution of water chemistry of aquifers and streams, the storage of radioactive waste in a geologic repository, the contamination of water resources from acid-rock drainage, and the geologic sequestration of carbon dioxide. Up to now, our ability to simulate these processes simultaneously with fully coupled reactive transport models has been limited to complex and often difficult-to-use models. To address the need for a simple and easy-to-use model, the VS2DRTI software package has been developed for simulating water flow, heat transport, and reactive solute transport through variably saturated porous media. The underlying numerical model, VS2DRT, was created by coupling the flow and transport capabilities of the VS2DT and VS2DH models with the equilibrium and kinetic reaction capabilities of PhreeqcRM. Flow capabilities include two-dimensional, constant-density, variably saturated flow; transport capabilities include both heat and multicomponent solute transport; and the reaction capabilities are a complete implementation of geochemical reactions of PHREEQC. The graphical user interface includes a preprocessor for building simulations and a postprocessor for visual display of simulation results. To demonstrate the simulation of multiple processes, the model is applied to a hypothetical example of injection of heated waste water to an aquifer with temperature-dependent cation exchange. VS2DRTI is freely available public domain software. © 2018, National Ground Water Association.

Process for the extraction of strontium from acidic solutions

DOEpatents

Horwitz, E. Philip; Dietz, Mark L.

1994-01-01

The invention is a process for selectively extracting strontium values from aqueous nitric acid waste solutions containing these and other fission product values. The extractant solution is a macrocyclic polyether in an aliphatic hydrocarbon diluent containing a phase modifier. The process will selectively extract strontium values from nitric acid solutions which are up to 6 molar in nitric acid.

Process for the extraction of strontium from acidic solutions

DOEpatents

Horwitz, E.P.; Dietz, M.L.

1993-01-01

The invention is a process for selectively extracting strontium values from aqueous nitric acid waste solutions containing these and other fission product values. The extractant solution is a macrocyclic polyether in an aliphatic hydrocarbon diluent containing a phase modifier. The process will selectively extract strontium values from nitric acid solutions which are up to 6 molar in nitric acid.

Steam jet mill-a prospective solution to industrial exhaust steam and solid waste.

PubMed

Zhang, Mingxing; Chen, Haiyan

2018-04-20

Bulk industrial solid wastes occupy a lot of our resources and release large amounts of toxic and hazardous substances to the surrounding environment, demanding innovative strategies for grinding, classification, collection, and recycling for economically ultrafine powder. A new technology for grinding, classification, collection, and recycling solid waste is proposed, using the superheated steam produced from the industrial exhaust steam to disperse, grind, classify, and collect the industrial solid waste. A large-scale steam jet mill was designed to operate at an inlet steam temperature 230-300 °C and an inlet pressure of 0.2-0.6 MPa. A kind of industrial solid waste fluidized-bed combustion ashes was used to grinding tests at different steam temperatures and inlet pressures. The total process for grinding, classification, and collection is drying. Two kinds of particle sizes are obtained. One particle size is d 50  = 4.785 μm, and another particle size is d 50  = 8.999 μm. For particle size d 50  = 8.999 μm, the inlet temperature is 296 °C and an inlet pressure is 0.54 MPa for the grinding chamber. The steam flow is 21.7 t/h. The yield of superfine powder is 73 t/h. The power consumption is 3.76 kW h/t. The obtained superfine powder meets the national standard S95 slag. On the basis of these results, a reproducible and sustainable industrial ecological protocol using steam produced by industrial exhaust heat coupled to solid waste recycling is proposed, providing an efficient, large-scale, low-cost, promising, and green method for both solid waste recovery and industrial exhaust heat reutilization.

Hanford facility dangerous waste permit application, 616 Nonradioactive dangerous waste storage facility

DOE Office of Scientific and Technical Information (OSTI.GOV)

Price, S.M.

1997-04-30

This chapter provides information on the physical, chemical, and biological characteristics of the waste stored at the 616 NRDWSF. A waste analysis plan is included that describes the methodology used for determining waste types.

Optimisation of the Management of Higher Activity Waste in the UK - 13537

DOE Office of Scientific and Technical Information (OSTI.GOV)

Walsh, Ciara; Buckley, Matthew

2013-07-01

The Upstream Optioneering project was created in the Nuclear Decommissioning Authority (UK) to support the development and implementation of significant opportunities to optimise activities across all the phases of the Higher Activity Waste management life cycle (i.e. retrieval, characterisation, conditioning, packaging, storage, transport and disposal). The objective of the Upstream Optioneering project is to work in conjunction with other functions within NDA and the waste producers to identify and deliver solutions to optimise the management of higher activity waste. Historically, optimisation may have occurred on aspects of the waste life cycle (considered here to include retrieval, conditioning, treatment, packaging, interimmore » storage, transport to final end state, which may be geological disposal). By considering the waste life cycle as a whole, critical analysis of assumed constraints may lead to cost savings for the UK Tax Payer. For example, it may be possible to challenge the requirements for packaging wastes for disposal to deliver an optimised waste life cycle. It is likely that the challenges faced in the UK are shared in other countries. It is therefore likely that the opportunities identified may also apply elsewhere, with the potential for sharing information to enable value to be shared. (authors)« less

Development of a novel wet oxidation process for hazardous and mixed wastes

DOE Office of Scientific and Technical Information (OSTI.GOV)

Dhooge, P.M.

1994-12-31

Many DOE waste streams and remediates contain complex and variable mixtures of organic compounds, toxic metals, and radionuclides. These materials are often dispersed in organic or inorganic matrices, such as personal protective equipment, various sludges, soils, and water. The over all objective of the effort described here is to develop a novel catalytic wet oxidation process for the treatment of these multi-component wastes, with the aim of providing a versatile, non-thermal method which will destroy hazardous organic compounds while simultaneously containing and concentrating toxic and radioactive metals for recovery or disposal in a readily stabilized matrix. The DETOX process usesmore » a unique combination of metal catalysts to increase the rate of oxidation of organic materials. The metal catalysts are in the form of salts dissolved in a dilute acid solution. A typical catalyst composition is 60% ferric chloride, 3--4% hydrochloric acid, 0.13% platinum ions, and 0.13% ruthenium ions in a water solution. The catalyst solution is maintained at 423--473 K. Wastes are introduced into contact with the solution, where their organic portion is oxidized to carbon dioxide and water. If the organic portion is chlorinated, hydrogen chloride will be produced as a product. The process is a viable alternative to incineration for the treatment of organic mixed wastes. Estimated costs for waste treatment using the process are from $2.50/kg to $25.00/kg, depending on the size of the unit and the amount of waste processed. Process units can be mobile for on-site treatment of wastes. Results from phase 1 and 2, design and engineering studies, are described.« less

Waste/By-Product Hydrogen

DTIC Science & Technology

2011-01-13

Waste /By product Hydrogen Waste H2 sources include: � Waste bio‐mass: biogas to high temp fuel cells to produce H2 – there are over two dozen sites...By‐product Hydrogen Fuel Flexibility Biogas : generated from organic waste �Wastewater treatment plants can provide multiple MW of renewable...13 Waste /By product Hydrogen ‐ Biogas

Analysis of the waste selective collection at drop-off systems: Case study including the income level and the seasonal variation.

PubMed

Gallardo, A; Carlos, M; Colomer, F J; Edo-Alcón, N

2018-01-01

There are several factors which have an influence in the selective collection of the municipal waste. To define a selective collection system, the waste generation pattern should be firstly determined and these factors should be analyzed in depth. This paper tries to analyze the economic income level and the seasonal variation on the collection and the purity of light-packaging waste to determine actions to improve the waste management plan of a town. In the first stage of the work, waste samples of the light-packaging containers were collected in two zones of the town with different economic characteristics in different seasons during one year. In the second stage, the samples were characterized to analyze the composition and purity of the waste. They were firstly separated into four fractions: metals; plastic; beverage cartons; and misplaced materials. The misplaced fraction was in its turn separated into cardboard, rubber and leather, inert waste, organic matter, paper, hazardous waste, clothes and shoes, glass and others. The plastic fraction was separated into five types of plastics and the metal fraction into three. In the third stage, the data have been analyzed and conclusions have been extracted. The main result is that the quality of the light-packaging fraction collected in these zones during both seasons were similar. This methodology can be extrapolated to towns with similar characteristics. It will be useful when implementing a system to collect the waste selectively and to develop actions to achieve a good participation in the selective collection of the waste.

Status of waste tyres and management practice in Botswana.

PubMed

Mmereki, Daniel; Machola, Bontle; Mokokwe, Kentlafetse

2017-02-22

Waste tyres (WTs) are becoming a significant environmental, economical and technological challenge due to their high contents of combustible composition and potential for valuable materials and energy resources. Fewer studies in developing and even developed countries have been carried out to assess the challenges regarding waste tyres management, and suggested the best alternative solutions for managing this waste stream. While developed countries made progress in waste tyres management needs by implementing more efficient innovative recovery and recycling methods, and restrictive regulations regarding the management of used tyres, in many developing countries the management of waste tyres has not received adequate interest, and the processing, treatment and disposal of waste tyre is still nascent. In recent years, worldwide, several methods for managing used tyres, including other principal alternatives for managing end-of-life tyres defined in the 4Rs, reduction, re-use, recovery and recycling have been adopted and applied to minimize serious threats to both the natural environment environment and human. The paper attempted to establish stakeholders' action that has the responsibility in waste tyre management in Botswana. This study also analyzed important aspects on waste tyres management in Botswana. A synthesis of approaches was employed in the present investigation to determine the factors influencing effective performance of waste tyres management practice in Botswana. Data for the present study was obtained using relevant published literature, scientific journals, other third sector sources, academic sources, and research derived from governments and other agencies and field observations. Group discussions with the participants and semi-structured interviews with professionals were carried out. The outcomes of this investigation are a wide-range outline concerning the participants that are important in waste tyres management, and a set of aspects affecting

Biologically Pre-Treated Habitation Waste Water as a Sustainable Green Urine Pre-Treat Solution

NASA Technical Reports Server (NTRS)

Jackson, W. Andrew; Thompson, Bret; Sevanthi, Ritesh; Morse, Audra; Meyer, Caitlin; Callahan, Michael

2017-01-01

The ability to recover water from urine and flush water is a critical process to allow long term sustainable human habitation in space or bases on the moon or mars. Organic N present as urea or similar compounds can hydrolyze producing free ammonia. This reaction results in an increase in the pH converting ammonium to ammonia which is volatile and not removed by distillation. The increase in pH will also cause precipitation reactions to occur. In order to prevent this, urine on ISS is combined with a pretreat solution. While use of a pretreatment solution has been successful, there are numerous draw backs including: storage and use of highly hazardous solutions, limitations on water recovery (less than 85%), and production of brine with pore dewatering characteristics. We evaluated the use of biologically treated habitation wastewaters (ISS and early planetary base) to replace the current pretreat solution. We evaluated both amended and un-amended bioreactor effluent. For the amended effluent, we evaluated "green" pretreat chemicals including citric acid and citric acid amended with benzoic acid. We used a mock urine/air separator modeled after the urine collection assembly on ISS. The urine/air separator was challenged continually for >6 months. Depending on the test point, the separator was challenged daily with donated urine and flushed with amended or un-amended reactor effluent. We monitored the pH of the urine, flush solution and residual pH in the urine/air separator after each urine event. We also evaluated solids production and biological growth. Our results support the use of both un-amended and amended bioreactor effluent to maintain the operability of the urine /air separator. The ability to use bioreactor effluent could decrease consumable cost, reduce hazards associated with current pre-treat chemicals, allow other membrane based desalination processes to be utilized, and improve brine characteristics.

Thiosulfate leaching of gold from waste mobile phones.

PubMed

Ha, Vinh Hung; Lee, Jae-chun; Jeong, Jinki; Hai, Huynh Trung; Jha, Manis K

2010-06-15

The present communication deals with the leaching of gold from the printed circuit boards (PCBs) of waste mobile phones using an effective and less hazardous system, i.e., a copper-ammonia-thiosulfate solution, as an alternative to the conventional and toxic cyanide leaching of gold. The influence of thiosulfate, ammonia and copper sulfate concentrations on the leaching of gold from PCBs of waste mobile phones was investigated. Gold extraction was found to be enhanced with solutions containing 15-20 mM cupric, 0.1-0.14 M thiosulfate, and 0.2-0.3 M ammonia. Similar trends were obtained for the leaching of gold from two different types of scraps and PCBs of waste mobile phones. From the scrap samples, 98% of the gold was leached out using a solution containing 20 mM copper, 0.12 M thiosulfate and 0.2 M ammonia. Similarly, the leaching of gold from the PCBs samples was also found to be good, but it was lower than that of scrap samples in similar experimental conditions. In this case, only 90% of the gold was leached, even with a contact time of 10h. The obtained data will be useful for the development of processes for the recycling of gold from waste mobile phones. Copyright 2010 Elsevier B.V. All rights reserved.

Waste Acceptance Testing of Secondary Waste Forms: Cast Stone, Ceramicrete and DuraLith

DOE Office of Scientific and Technical Information (OSTI.GOV)

Mattigod, Shas V.; Westsik, Joseph H.; Chung, Chul-Woo

2011-08-12

To support the selection of a waste form for the liquid secondary wastes from WTP, Washington River Protection Solutions has initiated secondary-waste-form testing work at Pacific Northwest National Laboratory (PNNL). In anticipation of a down-selection process for a waste form for the Solidification Treatment Unit to be added to the ETF, PNNL is conducting tests on four candidate waste forms to evaluate their ability to meet potential waste acceptance criteria for immobilized secondary wastes that would be placed in the IDF. All three waste forms demonstrated compressive strengths above the minimum 3.45 MPa (500 psi) set as a target formore » cement-based waste forms. Further, none of the waste forms showed any significant degradation in compressive strength after undergoing thermal cycling (30 cycles in a 10 day period) between -40 C and 60 C or water immersion for 90 days. The three leach test methods are intended to measure the diffusion rates of contaminants from the waste forms. Results are reported in terms of diffusion coefficients and a leachability index (LI) calculated based on the diffusion coefficients. A smaller diffusion coefficient and a larger LI are desired. The NRC, in its Waste Form Technical Position (NRC 1991), provides recommendations and guidance regarding methods to demonstrate waste stability for land disposal of radioactive waste. Included is a recommendation to conduct leach tests using the ANS 16.1 method. The resulting leachability index (LI) should be greater than 6.0. For Hanford secondary wastes, the LI > 6.0 criterion applies to sodium leached from the waste form. For technetium and iodine, higher targets of LI > 9 for Tc and LI > 11 for iodine have been set based on early waste-disposal risk and performance assessment analyses. The results of these three leach tests conducted for a total time between 11days (ASTM C1308) to 90 days (ANS 16.1) showed: (1) Technetium diffusivity: ANSI/ANS 16.1, ASTM C1308, and EPA 1315 tests

DuraLith geopolymer waste form for Hanford secondary waste: correlating setting behavior to hydration heat evolution.

PubMed

Xu, Hui; Gong, Weiliang; Syltebo, Larry; Lutze, Werner; Pegg, Ian L

2014-08-15

The binary furnace slag-metakaolin DuraLith geopolymer waste form, which has been considered as one of the candidate waste forms for immobilization of certain Hanford secondary wastes (HSW) from the vitrification of nuclear wastes at the Hanford Site, Washington, was extended to a ternary fly ash-furnace slag-metakaolin system to improve workability, reduce hydration heat, and evaluate high HSW waste loading. A concentrated HSW simulant, consisting of more than 20 chemicals with a sodium concentration of 5 mol/L, was employed to prepare the alkaline activating solution. Fly ash was incorporated at up to 60 wt% into the binder materials, whereas metakaolin was kept constant at 26 wt%. The fresh waste form pastes were subjected to isothermal calorimetry and setting time measurement, and the cured samples were further characterized by compressive strength and TCLP leach tests. This study has firstly established quantitative linear relationships between both initial and final setting times and hydration heat, which were never discovered in scientific literature for any cementitious waste form or geopolymeric material. The successful establishment of the correlations between setting times and hydration heat may make it possible to efficiently design and optimize cementitious waste forms and industrial wastes based geopolymers using limited testing results. Copyright © 2014 Elsevier B.V. All rights reserved.

Wastes as Aggregates, Binders or Additions in Mortars: Selecting Their Role Based on Characterization.

PubMed

Farinha, Catarina Brazão; de Brito, Jorge; Veiga, Rosário; Fernández, J M; Jiménez, J R; Esquinas, A R

2018-03-20

The production of waste has increased over the years and, lacking a recycle or recovery solution, it is forwarded to landfill. The incorporation of wastes in cement-based materials is a solution to reduce waste deposition. In this regard, some researchers have been studying the incorporation of wastes with different functions: aggregate, binder and addition. The incorporation of wastes should take advantage of their characteristics. It requires a judicious analysis of their particles. This research involves the analysis of seven industrial wastes: biomass ashes, glass fibre, reinforced polymer dust, sanitary ware, fluid catalytic cracking, acrylic fibre, textile fibre and glass fibre. The main characteristics and advantages of each waste are enunciated and the best type of introduction in mortars is discussed. The characterization of the wastes as particles is necessary to identify the most suitable incorporation in mortars. In this research, some wastes are studied with a view to their re-use or recycling in mortars. Thus, this research focuses on the chemical, physical and mechanical characterization of industrial wastes and identification of the potentially most advantageous type of incorporation.

Wastes as Aggregates, Binders or Additions in Mortars: Selecting Their Role Based on Characterization

PubMed Central

de Brito, Jorge; Veiga, Rosário

2018-01-01

The production of waste has increased over the years and, lacking a recycle or recovery solution, it is forwarded to landfill. The incorporation of wastes in cement-based materials is a solution to reduce waste deposition. In this regard, some researchers have been studying the incorporation of wastes with different functions: aggregate, binder and addition. The incorporation of wastes should take advantage of their characteristics. It requires a judicious analysis of their particles. This research involves the analysis of seven industrial wastes: biomass ashes, glass fibre, reinforced polymer dust, sanitary ware, fluid catalytic cracking, acrylic fibre, textile fibre and glass fibre. The main characteristics and advantages of each waste are enunciated and the best type of introduction in mortars is discussed. The characterization of the wastes as particles is necessary to identify the most suitable incorporation in mortars. In this research, some wastes are studied with a view to their re-use or recycling in mortars. Thus, this research focuses on the chemical, physical and mechanical characterization of industrial wastes and identification of the potentially most advantageous type of incorporation. PMID:29558418

Use of human wastes oxidized to different degrees in cultivation of higher plants on the soil-like substrate intended for closed ecosystems

NASA Astrophysics Data System (ADS)

Tikhomirov, A. A.; Kudenko, Yu. A.; Ushakova, S. A.; Tirranen, L. S.; Gribovskaya, I. A.; Gros, J.-B.; Lasseur, Ch.

2010-09-01

To close mass exchange loops in bioregenerative life support systems more efficiently, researchers of the Institute of Biophysics SB RAS (Krasnoyarsk, Russia) have developed a procedure of wet combustion of human wastes and inedible parts of plants using H 2O 2 in alternating electromagnetic field. Human wastes pretreated in this way can be used as nutrient solutions to grow plants in the phototrophic unit of the LSS. The purpose of this study was to explore the possibilities of using human wastes oxidized to different degrees to grow plants cultivated on the soil-like substrate (SLS). The treated human wastes were analyzed to test their sterility. Then we investigated the effects produced by human wastes oxidized to different degrees on growth and development of wheat plants and on the composition of microflora in the SLS. The irrigation solution contained water, substances extracted from the substrate, and certain amounts of the mineralized human wastes. The experiments showed that the human wastes oxidized using reduced amounts of 30% H 2O 2: 1 ml/g of feces and 0.25 ml/ml of urine were still sterile. The experiments with wheat plants grown on the SLS and irrigated by the solution containing treated human wastes in the amount simulating 1/6 of the daily diet of a human showed that the degree of oxidation of human wastes did not significantly affect plant productivity. On the other hand, the composition of the microbiota of irrigation solutions was affected by the oxidation level of the added metabolites. In the solutions supplemented with partially oxidized metabolites yeast-like microscopic fungi were 20 times more abundant than in the solutions containing fully oxidized metabolites. Moreover, in the solutions containing incompletely oxidized human wastes the amounts of phytopathogenic bacteria and denitrifying microorganisms were larger. Thus, insufficiently oxidized sterile human wastes added to the irrigation solutions significantly affect the composition of

Chemical Disposition of Plutonium in Hanford Site Tank Wastes

DOE Office of Scientific and Technical Information (OSTI.GOV)

Delegard, Calvin H.; Jones, Susan A.

2015-05-07

This report examines the chemical disposition of plutonium (Pu) in Hanford Site tank wastes, by itself and in its observed and potential interactions with the neutron absorbers aluminum (Al), cadmium (Cd), chromium (Cr), iron (Fe), manganese (Mn), nickel (Ni), and sodium (Na). Consideration also is given to the interactions of plutonium with uranium (U). No consideration of the disposition of uranium itself as an element with fissile isotopes is considered except tangentially with respect to its interaction as an absorber for plutonium. The report begins with a brief review of Hanford Site plutonium processes, examining the various means used tomore » recover plutonium from irradiated fuel and from scrap, and also examines the intermediate processing of plutonium to prepare useful chemical forms. The paper provides an overview of Hanford tank defined-waste–type compositions and some calculations of the ratios of plutonium to absorber elements in these waste types and in individual waste analyses. These assessments are based on Hanford tank waste inventory data derived from separately published, expert assessments of tank disposal records, process flowsheets, and chemical/radiochemical analyses. This work also investigates the distribution and expected speciation of plutonium in tank waste solution and solid phases. For the solid phases, both pure plutonium compounds and plutonium interactions with absorber elements are considered. These assessments of plutonium chemistry are based largely on analyses of idealized or simulated tank waste or strongly alkaline systems. The very limited information available on plutonium behavior, disposition, and speciation in genuine tank waste also is discussed. The assessments show that plutonium coprecipitates strongly with chromium, iron, manganese and uranium absorbers. Plutonium’s chemical interactions with aluminum, nickel, and sodium are minimal to non-existent. Credit for neutronic interaction of plutonium with these

Municipal waste management in Sicily: practices and challenges.

PubMed

Messineo, Antonio; Panno, Domenico

2008-01-01

There are numerous problems yet to be solved in waste management and although efforts towards waste recovery and recycling have been made, landfills are still the most common method used in the EU and many other industrialised countries. Thermal disposal, particularly incineration, is a tested and viable alternative. In 2004, only 11% of the annual waste production of Italy was incinerated. Sicily, with over five million inhabitants, is the second largest region in Italy where waste management is now a critical problem. The use of landfills can no longer be considered a satisfactory environmental solution; therefore, new methods have to be chosen and waste-to-energy plants could provide an answer. This paper gives details of municipal solid waste management in Sicily following a new Waste Management Plan. Four waste-to-energy plants will generate electricity through a steam cycle; the feedstock will become the residue after material recovery, which is calculated as 20-40% weight of the collected municipal solid waste.

Wastes and by-products - alternatives for agricultural use

DOE Office of Scientific and Technical Information (OSTI.GOV)

Boles, J.L.; Craft, D.J.; Parker, B.R.

1994-10-01

Top address a growing national problem with generation of wastes and by-products, TVA has been involved for several years with developing and commercializing environmentally responsible practices for eliminating, minimizing, or utilizing various wastes/by-products. In many cases, reducing waste generation is impractical, but the wastes/by-products can be converted into other environmentally sound products. In some instances, conversion of safe, value-added agricultural products in the best or only practical alternative. TVA is currently involved with a diversity of projects converting wastes/by-products into safe, economical, and agriculturally beneficial products. Environmental improvement projects have involved poultry litter, cellulosic wastes, used battery acid, ammonium sulfatemore » fines, lead smelting effluents, deep-welled sulfuric acid/ammonium bisulfate solutions, wood ash, waste magnesium ammonium sulfate slurry from recording tape production, and ammunition plant waste sodium nitrate/ammonium nitrate streams.« less

Removal of arsenic from aqueous solutions using waste iron columns inoculated with iron bacteria.

PubMed

Azhdarpoor, Abooalfazl; Nikmanesh, Roya; Samaei, Mohammad Reza

2015-01-01

Arsenic contamination of water resources is one of the serious risks threatening natural ecosystems and human health. This study investigates arsenic removal using a waste iron column with and without iron bacteria in continuous and batch phases. In batch experiments, the effects of pH, contact time, initial concentration of arsenic and adsorbent dose were investigated. Results indicated that the highest arsenate removal efficiency occurred at pH 7 (96.76%). On increasing the amount of waste iron from 0.25 to 1 g, the removal rate changed from about 42.37%-96.70%. The results of continuous experiments on the column containing waste iron showed that as the empty bed contact time increased from 5 to 60 min, the secondary arsenate concentration changed from 23 to 6 µg/l. In experiments involving a waste iron column with iron bacteria, an increase in residence time from 5 to 60 min decreased the secondary arsenate concentration from 14.97 to 4.86 µg/l. The results of this study showed that waste iron containing iron bacteria is a good adsorbent for removal of arsenic from contaminated water.

A combined physicochemical-biological method of NaCl extraction from the irrigation solution in the BTLSS

NASA Astrophysics Data System (ADS)

Trifonov, Sergey V.; Tikhomirov, Alexander A.; Ushakova, Sofya; Tikhomirova, Natalia

2016-07-01

The use of processed human wastes as a source of minerals for plants in closed biotechnical life support systems (BTLSS) leads to high salt levels in the irrigation solution, as urine contains high concentrations of NaCl. It is important to develop a process that would effectively decrease NaCl concentration in the irrigation solution and return this salt to the crew's diet. The salt-tolerant plants (Salicornia europea) used to reduce NaCl concentration in the irrigation solution require higher salt concentrations than those of the solution, and this problem cannot be resolved by concentrating the solution. At the same time, NaCl extracted from mineralized wastes by physicochemical methods is not pure enough to be included in the crew's diet. This study describes an original physicochemical method of NaCl extraction from the solution, which is intended to be used in combination with the biological method of NaCl extraction by using saltwort plants. The physicochemical method produces solutions with high NaCl concentrations, and saltwort plants serve as a biological filter in the final phase, to produce table salt. The study reports the order in which physicochemical and biological methods of NaCl extraction from the irrigation solution should be used to enable rapid and effective inclusion of NaCl into the cycling of the BTLSS with humans. This study was carried out in the IBP SB RAS and supported by the grant of the Russian Science Foundation (Project No. 14-14-00599).

Secondary Waste Cast Stone Waste Form Qualification Testing Plan

DOE Office of Scientific and Technical Information (OSTI.GOV)

Westsik, Joseph H.; Serne, R. Jeffrey

2012-09-26

The Hanford Tank Waste Treatment and Immobilization Plant (WTP) is being constructed to treat the 56 million gallons of radioactive waste stored in 177 underground tanks at the Hanford Site. The WTP includes a pretreatment facility to separate the wastes into high-level waste (HLW) and low-activity waste (LAW) fractions for vitrification and disposal. The LAW will be converted to glass for final disposal at the Integrated Disposal Facility (IDF). Cast Stone – a cementitious waste form, has been selected for solidification of this secondary waste stream after treatment in the ETF. The secondary-waste Cast Stone waste form must be acceptablemore » for disposal in the IDF. This secondary waste Cast Stone waste form qualification testing plan outlines the testing of the waste form and immobilization process to demonstrate that the Cast Stone waste form can comply with the disposal requirements. Specifications for the secondary-waste Cast Stone waste form have not been established. For this testing plan, Cast Stone specifications are derived from specifications for the immobilized LAW glass in the WTP contract, the waste acceptance criteria for the IDF, and the waste acceptance criteria in the IDF Permit issued by the State of Washington. This testing plan outlines the testing needed to demonstrate that the waste form can comply with these waste form specifications and acceptance criteria. The testing program must also demonstrate that the immobilization process can be controlled to consistently provide an acceptable waste form product. This testing plan also outlines the testing needed to provide the technical basis for understanding the long-term performance of the waste form in the disposal environment. These waste form performance data are needed to support performance assessment analyses of the long-term environmental impact of the secondary-waste Cast Stone waste form in the IDF« less

Solutions of the Dirac Equation with the Shifted DENG-FAN Potential Including Yukawa-Like Tensor Interaction

NASA Astrophysics Data System (ADS)

Yahya, W. A.; Falaye, B. J.; Oluwadare, O. J.; Oyewumi, K. J.

2013-08-01

By using the Nikiforov-Uvarov method, we give the approximate analytical solutions of the Dirac equation with the shifted Deng-Fan potential including the Yukawa-like tensor interaction under the spin and pseudospin symmetry conditions. After using an improved approximation scheme, we solved the resulting schr\\"{o}dinger-like equation analytically. Numerical results of the energy eigenvalues are also obtained, as expected, the tensor interaction removes degeneracies between spin and pseudospin doublets.

Waste Encapsulation and Storage Facility (WESF) Dangerous Waste Training Plan (DWTP)

DOE Office of Scientific and Technical Information (OSTI.GOV)

SIMMONS, F.M.

2000-03-29

This Waste Encapsulation Storage Facility (WESF) Dangerous Waste Training Plan (DWTP) applies to personnel who perform work at, or in support of WESF. The plan, along with the names of personnel, may be given to a regulatory agency inspector upon request. General workers, subcontractors, or visiting personnel who have not been trained in the management of dangerous wastes must be accompanied by an individual who meets the requirements of this training plan. Dangerous waste management includes handling, treatment, storage, and/or disposal of dangerous and/or mixed waste. Dangerous waste management units covered by this plan include: less-than-90-day accumulation area(s); pool cellsmore » 1-8 and 12 storage units; and process cells A-G storage units. This training plan describes general requirements, worker categories, and provides course descriptions for operation of the WESF permitted miscellaneous storage units and the Less-than-90-Day Accumulation Areas.« less

Combined Municipal Solid Waste and biomass system optimization for district energy applications.

PubMed

Rentizelas, Athanasios A; Tolis, Athanasios I; Tatsiopoulos, Ilias P

2014-01-01

Municipal Solid Waste (MSW) disposal has been a controversial issue in many countries over the past years, due to disagreement among the various stakeholders on the waste management policies and technologies to be adopted. One of the ways of treating/disposing MSW is energy recovery, as waste is considered to contain a considerable amount of bio-waste and therefore can lead to renewable energy production. The overall efficiency can be very high in the cases of co-generation or tri-generation. In this paper a model is presented, aiming to support decision makers in issues relating to Municipal Solid Waste energy recovery. The idea of using more fuel sources, including MSW and agricultural residue biomass that may exist in a rural area, is explored. The model aims at optimizing the system specifications, such as the capacity of the base-load Waste-to-Energy facility, the capacity of the peak-load biomass boiler and the location of the facility. Furthermore, it defines the quantity of each potential fuel source that should be used annually, in order to maximize the financial yield of the investment. The results of an energy tri-generation case study application at a rural area of Greece, using mixed MSW and biomass, indicate positive financial yield of investment. In addition, a sensitivity analysis is performed on the effect of the most important parameters of the model on the optimum solution, pinpointing the parameters of interest rate, investment cost and heating oil price, as those requiring the attention of the decision makers. Finally, the sensitivity analysis is enhanced by a stochastic analysis to determine the effect of the volatility of parameters on the robustness of the model and the solution obtained. Copyright © 2013 Elsevier Ltd. All rights reserved.

Process for the extraction of strontium from acidic solutions

DOEpatents

Horwitz, E.P.; Dietz, M.L.

1994-09-06

The invention is a process for selectively extracting strontium values from aqueous nitric acid waste solutions containing these and other fission product values. The extractant solution is a macrocyclic polyether in an aliphatic hydrocarbon diluent containing a phase modifier. The process will selectively extract strontium values from nitric acid solutions which are up to 6 molar in nitric acid. 4 figs.

Biosorption of Pb2+ and Cu2+ in aqueous solutions using agricultural wastes

NASA Astrophysics Data System (ADS)

Nieva, Aileen D.; Doma, Bonifacio T.; Chao, Huan-Ping; Siang Leng, Lai

2017-11-01

This study aimed to determine and compare the adsorptive capacity of Pb2+ and Cu2+ in simulated wastewater onto three agricultural wastes The adsorption capacities of Pb2+ onto the agricultural wastes can be arranged as Litchi chinensis (4.30 mg of sorbate per g of sorbent (mg g-1), 85.68% adsorption) > Bambusa vulgaris (3.83 mg g-1, 76.19% adsorption) > Annona squamosa (2.70 mg g-1, 53.66% adsorption) while the adsorption capacities of Cu2+ onto the same agricultural wastes can be arranged in the order: Bambusa vulgaris (3.86 mg g-1, 77.17% adsorption) > Annona squamosal (3.58 mg g-1, 71.58% adsorption) > Litchi chinensis (3.42 mg g-1, 68.32% adsorption). The biosorbents had relatively higher adsorptive capacities with Cu2+ as compared to that of Pb2+ except for Litchi chinensis. Although the results show lower adsorptive capacity as compared to a number of treated agricultural wastes showing 80% up to almost 100% adsorption of Pb2+ and Cu2+, the results show that Annona squamosa, Bamubusa vulgaris, and Litchi chinensis are potential biosorbents and promote sustainable treatment process.

EM-21 Retrieval Knowledge Center: Waste Retrieval Challenges

DOE Office of Scientific and Technical Information (OSTI.GOV)

Fellinger, Andrew P.; Rinker, Michael W.; Berglin, Eric J.

EM-21 is the Waste Processing Division of the Office of Engineering and Technology, within the U.S. Department of Energy’s (DOE) Office of Environmental Management (EM). In August of 2008, EM-21 began an initiative to develop a Retrieval Knowledge Center (RKC) to provide the DOE, high level waste retrieval operators, and technology developers with centralized and focused location to share knowledge and expertise that will be used to address retrieval challenges across the DOE complex. The RKC is also designed to facilitate information sharing across the DOE Waste Site Complex through workshops, and a searchable database of waste retrieval technology information.more » The database may be used to research effective technology approaches for specific retrieval tasks and to take advantage of the lessons learned from previous operations. It is also expected to be effective for remaining current with state-of-the-art of retrieval technologies and ongoing development within the DOE Complex. To encourage collaboration of DOE sites with waste retrieval issues, the RKC team is co-led by the Savannah River National Laboratory (SRNL) and the Pacific Northwest National Laboratory (PNNL). Two RKC workshops were held in the Fall of 2008. The purpose of these workshops was to define top level waste retrieval functional areas, exchange lessons learned, and develop a path forward to support a strategic business plan focused on technology needs for retrieval. The primary participants involved in these workshops included retrieval personnel and laboratory staff that are associated with Hanford and Savannah River Sites since the majority of remaining DOE waste tanks are located at these sites. This report summarizes and documents the results of the initial RKC workshops. Technology challenges identified from these workshops and presented here are expected to be a key component to defining future RKC-directed tasks designed to facilitate tank waste retrieval solutions.« less

Leaching boundary movement in solidified/stabilized waste forms

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kuang Ye Cheng; Bishop, P.L.

1992-02-01

Investigation of the leaching of cement-based waste forms in acetic acid solutions found that acids attacked the waste form from the surface toward the center. A sharp leaching boundary was identified in every leached sample, using pH color indicators. The movement of the leaching boundary was found to be a single diffusion-controlled process.

Dangerous Waste Characteristics of Contact-Handled Transuranic Mixed Wastes from the Hanford Tanks

DOE Office of Scientific and Technical Information (OSTI.GOV)

Tingey, Joel M.; Bryan, Garry H.; Deschane, Jaquetta R.

2004-08-31

This report summarizes existing analytical data from samples taken from the Hanford tanks designated as potentially containing transuranic mixed process wastes. Process knowledge of the wastes transferred to these tanks has been reviewed to determine whether the dangerous waste characteristics now assigned to all Hanford underground storage tanks are applicable to these particular wastes. Supplemental technologies are being examined to accelerate the Hanford tank waste cleanup mission and accomplish waste treatment safely and efficiently. To date, 11 Hanford waste tanks have been designated as potentially containing contact-handled (CH) transuranic mixed (TRUM) wastes. The CH-TRUM wastes are found in single-shell tanksmore » B-201 through B-204, T-201 through T-204, T-104, T-110, and T-111. Methods and equipment to solidify and package the CH-TRUM wastes are part of the supplemental technologies being evaluated. The resulting packages and wastes must be acceptable for disposal at the Waste Isolation Pilot Plant (WIPP). The dangerous waste characteristics being considered include ignitability, corrosivity, reactivity, and toxicity arising from the presence of 2,4,5-trichlorophenol at levels above the dangerous waste threshold. The analytical data reviewed include concentrations of sulfur, sulfate, cyanide, 2,4,5-trichlorophenol, total organic carbon, and oxalate; the composition of the tank headspace, pH, and mercury. Differential scanning calorimetry results were used to determine the energetics of the wastes as a function of temperature.« less

Prediction of stress corrosion of carbon steel by nuclear process liquid wastes

DOE Office of Scientific and Technical Information (OSTI.GOV)

Ondrejcin, R.S.

1978-08-01

Radioactive liquid wastes are produced as a consequence of processing fuel from Savannah River Plant (SRP) production reactors. These wastes are stored in mild steel waste tanks, some of which have developed cracks from stress corrosion. A laboratory test was developed to determine the relative agressiveness of the wastes for stress corrosion cracking of mild steel. Tensile samples were strained to fracture in synthetic waste solutions in an electrochemical cell with the sample as the anode. Crack initiation is expected if total elongation of the steel in the test is less than its uniform elongation in air. Cracking would bemore » anticipated in a plant waste tank if solution conditions were equivalent to test conditions that cause a total elongation that is less than uniform elongation. The electrochemical tensile tests showed that the supernates in salt receiver tanks at SRP have the least aggressive compositions, and wastes newly generated during fuel repocessing have the most aggressive ones. Test data also verified that ASTM A 516-70 steel used in the fabrication of the later design waste tanks is less susceptible to cracking than the ASTM A 285-B steel used in earlier designs.« less

Densified waste form and method for forming

DOEpatents

Garino, Terry J.; Nenoff, Tina M.; Sava Gallis, Dorina Florentina

2015-08-25

Materials and methods of making densified waste forms for temperature sensitive waste material, such as nuclear waste, formed with low temperature processing using metallic powder that forms the matrix that encapsulates the temperature sensitive waste material. The densified waste form includes a temperature sensitive waste material in a physically densified matrix, the matrix is a compacted metallic powder. The method for forming the densified waste form includes mixing a metallic powder and a temperature sensitive waste material to form a waste form precursor. The waste form precursor is compacted with sufficient pressure to densify the waste precursor and encapsulate the temperature sensitive waste material in a physically densified matrix.

What gets measured gets managed: A new method of measuring household food waste.

PubMed

Elimelech, Efrat; Ayalon, Ofira; Ert, Eyal

2018-03-22

The quantification of household food waste is an essential part of setting policies and waste reduction goals, but it is very difficult to estimate. Current methods include either direct measurements (physical waste surveys) or measurements based on self-reports (diaries, interviews, and questionnaires). The main limitation of the first method is that it cannot always trace the waste source, i.e., an individual household, whereas the second method lacks objectivity. This article presents a new measurement method that offers a solution to these challenges by measuring daily produced food waste at the household level. This method is based on four main principles: (1) capturing waste as it enters the stream, (2) collecting waste samples at the doorstep, (3) using the individual household as the sampling unit, and (4) collecting and sorting waste daily. We tested the feasibility of the new method with an empirical study of 192 households, measuring the actual amounts of food waste from households as well as its composition. Household food waste accounted for 45% of total waste (573 g/day per capita), of which 54% was identified as avoidable. Approximately two thirds of avoidable waste consisted of vegetables and fruit. These results are similar to previous findings from waste surveys, yet the new method showed a higher level of accuracy. The feasibility test suggests that the proposed method provides a practical tool for policy makers for setting policy based on reliable empirical data and monitoring the effectiveness of different policies over time. Copyright © 2018 Elsevier Ltd. All rights reserved.

Assessment for the management of NORM wastes in conventional hazardous and nonhazardous waste landfills.

PubMed

Mora, Juan C; Baeza, Antonio; Robles, Beatriz; Sanz, Javier

2016-06-05

Naturally Occurring Radioactive Materials (NORM) wastes are generated in huge quantities in several industries and their management has been carried out under considerations of industrial non-radioactive wastes, before the concern on the radioactivity content was included in the legislation. Therefore these wastes were conditioned using conventional methods and the waste disposals were designed to isolate toxic elements from the environment for long periods of time. Spanish regulation for these conventional toxic waste disposals includes conditions that assure adequate isolation to minimize the impact of the wastes to the environment in present and future conditions. After 1996 the radiological impact of the management of NORM wastes is considered and all the aspects related with natural radiations and the radiological control regarding the management of residues from NORM industries were developed in the new regulation. One option to be assessed is the disposal of NORM wastes in hazardous and non-hazardous waste disposals, as was done before this new regulation. This work analyses the management of NORM wastes in these landfills to derive the masses that can be disposed without considerable radiological impact. Generic dose assessments were carried out under highly conservative hypothesis and a discussion on the uncertainty and variability sources was included to provide consistency to the calculations. Copyright © 2016 Elsevier B.V. All rights reserved.

Two-stage agglomeration of fine-grained herbal nettle waste

NASA Astrophysics Data System (ADS)

Obidziński, Sławomir; Joka, Magdalena; Fijoł, Olga

2017-10-01

This paper compares the densification work necessary for the pressure agglomeration of fine-grained dusty nettle waste, with the densification work involved in two-stage agglomeration of the same material. In the first stage, the material was pre-densified through coating with a binder material in the form of a 5% potato starch solution, and then subjected to pressure agglomeration. A number of tests were conducted to determine the effect of the moisture content in the nettle waste (15, 18 and 21%), as well as the process temperature (50, 70, 90°C) on the values of densification work and the density of the obtained pellets. For pre-densified pellets from a mixture of nettle waste and a starch solution, the conducted tests determined the effect of pellet particle size (1, 2, and 3 mm) and the process temperature (50, 70, 90°C) on the same values. On the basis of the tests, we concluded that the introduction of a binder material and the use of two-stage agglomeration in nettle waste densification resulted in increased densification work (as compared to the densification of nettle waste alone) and increased pellet density.

Evaluation and Testing of IONSIV IE-911 for the Removal of Cesium-137 from INEEL Tank Waste and Dissolved Calcines

DOE Office of Scientific and Technical Information (OSTI.GOV)

N. R. Mann; T. A. Todd; K. N. Brewer

1999-04-01

Development of waste treatment processes for the remediation of radioactive wastes is currently underway. A number of experiments were performed at the Idaho Nuclear Technology and Environmental Center (INTEC) located at the Idaho National Engineering and Environmental Laboratory (INEEL) with the commercially available sorbent material, IONSIV IE-911, crystalline silicotitanate (CST), manufactured by UOP LLC. The purpose of this work was to evaluate the removal efficiency, sorbent capacity and selectivity of CST for removing Cs-137 from actual and simulated acidic tank waste in addition to dissolved pilot-plant calcine solutions. The scope of this work included batch contact tests performed with non-radioactivemore » dissolved Al and Run-64 pilot plant calcines in addition to simulants representing the average composition of tank waste. Small-scale column tests were performed with actual INEEL tank WM-183 waste, tank waste simulant, dissolved Al and Run-64 pilot plant calcine solutions. Small-scale column experiments using actual WM-183 tank waste resulted in fifty-percent Cs-137 breakthrough at approximately 589 bed volumes. Small-scale column experiments using the tank waste simulant displayed fifty-percent Cs-137 breakthrough at approximately 700 bed volumes. Small-scale column experiments using dissolved Al calcine simulant displayed fifty-percent Cs-137 breakthrough at approximately 795 bed volumes. Column experiments with dissolved Run-64, pilot plant calcine did not reach fifty-percent breakthrough throughout the test.« less

Biogenic carbon in combustible waste: waste composition, variability and measurement uncertainty.

PubMed

Larsen, Anna W; Fuglsang, Karsten; Pedersen, Niels H; Fellner, Johann; Rechberger, Helmut; Astrup, Thomas

2013-10-01

Obtaining accurate data for the contents of biogenic and fossil carbon in thermally-treated waste is essential for determination of the environmental profile of waste technologies. Relations between the variability of waste chemistry and the biogenic and fossil carbon emissions are not well described in the literature. This study addressed the variability of biogenic and fossil carbon in combustible waste received at a municipal solid waste incinerator. Two approaches were compared: (1) radiocarbon dating ((14)C analysis) of carbon dioxide sampled from the flue gas, and (2) mass and energy balance calculations using the balance method. The ability of the two approaches to accurately describe short-term day-to-day variations in carbon emissions, and to which extent these short-term variations could be explained by controlled changes in waste input composition, was evaluated. Finally, the measurement uncertainties related to the two approaches were determined. Two flue gas sampling campaigns at a full-scale waste incinerator were included: one during normal operation and one with controlled waste input. Estimation of carbon contents in the main waste types received was included. Both the (14)C method and the balance method represented promising methods able to provide good quality data for the ratio between biogenic and fossil carbon in waste. The relative uncertainty in the individual experiments was 7-10% (95% confidence interval) for the (14)C method and slightly lower for the balance method.

Solution dewatering with concomitant ion removal

DOEpatents

Peterson, Eric S.; Marshall, Douglas W.; Stone, Mark L.

2003-08-05

One of the biggest needs in the separations and waste handling and reduction area is a method for dewatering ion-containing solutions. Unexpectedly, it has been found that phosphazene polymers can discriminate between water and metal ions, allowing water to pass through the membrane while retaining the ions. This unexpected result, along with the inherent chemical and thermal stability of the phosphazene polymers, yields a powerful tool for separating and dewatering metal-ion-containing solutions.

Status report on the disposal of radioactive wastes

DOE Office of Scientific and Technical Information (OSTI.GOV)

Culler, F.L. Jr.; McLain, S.

1957-06-25

A comprehensive survey of waste disposal techniques, requirements, costs, hazards, and long-range considerations is presented. The nature of high level wastes from reactors and chemical processes, in the form of fission product gases, waste solutions, solid wastes, and particulate solids in gas phase, is described. Growth predictions for nuclear reactor capacity and the associated fission product and transplutonic waste problem are made and discussed on the basis of present knowledge. Biological hazards from accumulated wastes and potential hazards from reactor accidents, ore and feed material processing, chemical reprocessing plants, and handling of fissionable and fertile material after irradiation and decontaminationmore » are surveyed. The waste transportation problem is considered from the standpoints of magnitude of the problem, present regulations, costs, and cooling periods. The possibilities for ultimate waste management and/or disposal are reviewed and discussed. The costs of disposal, evaporation, storage tanks, and drum-drying are considered.« less

Waste Minimization Study on Pyrochemical Reprocessing Processes

DOE Office of Scientific and Technical Information (OSTI.GOV)

Boussier, H.; Conocar, O.; Lacquement, J.

2006-07-01

Ideally a new pyro-process should not generate more waste, and should be at least as safe and cost effective as the hydrometallurgical processes currently implemented at industrial scale. This paper describes the thought process, the methodology and some results obtained by process integration studies to devise potential pyro-processes and to assess their capability of achieving this challenging objective. As example the assessment of a process based on salt/metal reductive extraction, designed for the reprocessing of Generation IV carbide spent fuels, is developed. Salt/metal reductive extraction uses the capability of some metals, aluminum in this case, to selectively reduce actinide fluoridesmore » previously dissolved in a fluoride salt bath. The reduced actinides enter the metal phase from which they are subsequently recovered; the fission products remain in the salt phase. In fact, the process is not so simple, as it requires upstream and downstream subsidiary steps. All these process steps generate secondary waste flows representing sources of actinide leakage and/or FP discharge. In aqueous processes the main solvent (nitric acid solution) has a low boiling point and evaporate easily or can be removed by distillation, thereby leaving limited flow containing the dissolved substance behind to be incorporated in a confinement matrix. From the point of view of waste generation, one main handicap of molten salt processes, is that the saline phase (fluoride in our case) used as solvent is of same nature than the solutes (radionuclides fluorides) and has a quite high boiling point. So it is not so easy, than it is with aqueous solutions, to separate solvent and solutes in order to confine only radioactive material and limit the final waste flows. Starting from the initial block diagram devised two years ago, the paper shows how process integration studies were able to propose process fittings which lead to a reduction of the waste variety and flows leading at an

Removal of basic dye (methylene blue) from wastewaters utilizing beer brewery waste.

PubMed

Tsai, Wen-Tien; Hsu, Hsin-Chieh; Su, Ting-Yi; Lin, Keng-Yu; Lin, Chien-Ming

2008-06-15

In the work, the beer brewery waste has been shown to be a low-cost adsorbent for the removal of basic dye from the aqueous solution as compared to its precursor (i.e., diatomite) based on its physical and chemical characterizations including surface area, pore volume, scanning electron microscopy (SEM), and non-mineral elemental analyses. The pore properties of this waste were significantly larger than those of its raw material, reflecting that the trapped organic matrices contained in the waste probably provided additional adsorption sites and/or adsorption area. The results of preliminary adsorption kinetics showed that the diatomite waste could be directly used as a potential adsorbent for removal of methylene blue on the basis of its adsorption-biosorption mechanisms. The adsorption parameters thus obtained from the pseudo-second-order model were in accordance with their pore properties. From the results of adsorption isotherm at 298 K and the applicability examinations in treating industrial wastewater containing basic dye, it was further found that the adsorption capacities of diatomite waste were superior to those of diatomite, which were also in good agreement with their corresponding physical properties. From the results mentioned above, it is feasible to utilize the food-processing waste for removing dye from the industrial dying wastewater.

Densified waste form and method for forming

DOE Office of Scientific and Technical Information (OSTI.GOV)

Garino, Terry J.; Nenoff, Tina M.; Sava Gallis, Dorina Florentina

Materials and methods of making densified waste forms for temperature sensitive waste material, such as nuclear waste, formed with low temperature processing using metallic powder that forms the matrix that encapsulates the temperature sensitive waste material. The densified waste form includes a temperature sensitive waste material in a physically densified matrix, the matrix is a compacted metallic powder. The method for forming the densified waste form includes mixing a metallic powder and a temperature sensitive waste material to form a waste form precursor. The waste form precursor is compacted with sufficient pressure to densify the waste precursor and encapsulate themore » temperature sensitive waste material in a physically densified matrix.« less

Method for contamination control and barrier apparatus with filter for containing waste materials that include dangerous particulate matter

DOEpatents

Pinson, Paul A.

1998-01-01

A container for hazardous waste materials that includes air or other gas carrying dangerous particulate matter has incorporated in barrier material, preferably in the form of a flexible sheet, one or more filters for the dangerous particulate matter sealably attached to such barrier material. The filter is preferably a HEPA type filter and is preferably chemically bonded to the barrier materials. The filter or filters are preferably flexibly bonded to the barrier material marginally and peripherally of the filter or marginally and peripherally of air or other gas outlet openings in the barrier material, which may be a plastic bag. The filter may be provided with a backing panel of barrier material having an opening or openings for the passage of air or other gas into the filter or filters. Such backing panel is bonded marginally and peripherally thereof to the barrier material or to both it and the filter or filters. A coupling or couplings for deflating and inflating the container may be incorporated. Confining a hazardous waste material in such a container, rapidly deflating the container and disposing of the container, constitutes one aspect of the method of the invention. The chemical bonding procedure for producing the container constitutes another aspect of the method of the invention.

Method for contamination control and barrier apparatus with filter for containing waste materials that include dangerous particulate matter

DOEpatents

Pinson, P.A.

1998-02-24

A container for hazardous waste materials that includes air or other gas carrying dangerous particulate matter has incorporated barrier material, preferably in the form of a flexible sheet, and one or more filters for the dangerous particulate matter sealably attached to such barrier material. The filter is preferably a HEPA type filter and is preferably chemically bonded to the barrier materials. The filter or filters are preferably flexibly bonded to the barrier material marginally and peripherally of the filter or marginally and peripherally of air or other gas outlet openings in the barrier material, which may be a plastic bag. The filter may be provided with a backing panel of barrier material having an opening or openings for the passage of air or other gas into the filter or filters. Such backing panel is bonded marginally and peripherally thereof to the barrier material or to both it and the filter or filters. A coupling or couplings for deflating and inflating the container may be incorporated. Confining a hazardous waste material in such a container, rapidly deflating the container and disposing of the container, constitutes one aspect of the method of the invention. The chemical bonding procedure for producing the container constitutes another aspect of the method of the invention. 3 figs.

Vegetation cover and long-term conservation of radioactive waste packages: the case study of the CSM waste disposal facility (Manche District, France).

PubMed

Petit-Berghem, Yves; Lemperiere, Guy

2012-03-01

The CSM is the first French waste disposal facility for radioactive waste. Waste material is buried several meters deep and protected by a multi-layer cover, and equipped with a drainage system. On the surface, the plant cover is a grassland vegetation type. A scientific assessment has been carried out by the Géophen laboratory, University of Caen, in order to better characterize the plant cover (ecological groups and associated soils) and to observe its medium and long term evolution. Field assessments made on 10 plots were complemented by laboratory analyses carried out over a period of 1 year. The results indicate scenarios and alternative solutions which could arise, in order to passively ensure the long-term safety of the waste disposal system. Several proposals for a blanket solution are currently being studied and discussed, under the auspices of international research institutions in order to determine the most appropriate materials for the storage conditions. One proposal is an increased thickness of these materials associated with a geotechnical barrier since it is well adapted to the forest plants which are likely to colonize the site. The current experiments that are carried out will allow to select the best option and could provide feedback for other waste disposal facility sites already being operated in France (CSFMA waste disposal facility, Aube district) or in other countries.

An empirical investigation of construction and demolition waste generation rates in Shenzhen city, South China.

PubMed

Lu, Weisheng; Yuan, Hongping; Li, Jingru; Hao, Jane J L; Mi, Xuming; Ding, Zhikun

2011-04-01

The construction and demolition waste generation rates (C&D WGRs) is an important factor in decision-making and management of material waste in any construction site. The present study investigated WGRs by conducting on-site waste sorting and weighing in four ongoing construction projects in Shenzhen city of South China. The results revealed that WGRs ranged from 3.275 to 8.791 kg/m(2) and miscellaneous waste, timber for formwork and falsework, and concrete were the three largest components amongst the generated waste. Based on the WGRs derived from the research, the paper also discussed the main causes of waste in the construction industry and attempted to connect waste generation with specific construction practices. It was recommended that measures mainly including performing waste sorting at source, employing skilful workers, uploading and storing materials properly, promoting waste management capacity, replacing current timber formwork with metal formwork and launching an incentive reward program to encourage waste reduction could be potential solutions to reducing current WGRs in Shenzhen. Although these results were derived from a relatively small sample and so cannot justifiably be generalized, they do however add to the body of knowledge that is currently available for understanding the status of the art of C&D waste management in China. Copyright © 2010 Elsevier Ltd. All rights reserved.

Recycling Of Cis Photovoltaic Waste

DOEpatents

Drinkard, Jr., William F.; Long, Mark O.; Goozner; Robert E.

1998-07-14

A method for extracting and reclaiming metals from scrap CIS photovoltaic cells and associated photovoltaic manufacturing waste by leaching the waste with dilute nitric acid, skimming any plastic material from the top of the leaching solution, separating glass substrate from the leachate, electrolyzing the leachate to plate a copper and selenium metal mixture onto a first cathode, replacing the cathode with a second cathode, re-electrolyzing the leachate to plate cadmium onto the second cathode, separating the copper from selenium, and evaporating the depleted leachate to yield a zinc and indium containing solid.

Metal Recovery from Industrial Solid Waste — Contribution to Resource Sustainability

NASA Astrophysics Data System (ADS)

Yang, Yongxiang

Increased demand of metals has driven the accelerated mining and metallurgical production in recent years, causing fast depletion of primary metals resources. On the contrary, the mining and metallurgical industry generates large amount of solid residues and waste such as tailings, slags, flue dust and leach residues, with relative low valuable metal contents. On the other hand, end-of-life (EoL) consumer products form another significant resources. The current technology and processes for primary metals production are not readily applicable for direct metals extraction from these waste materials, and special adaptation and tailor-made processes are required. In the present paper, various solid waste resources are reviewed, and current technologies and R&D trends are discussed. The recent research at author's group is illustrated for providing potential solutions to future resource problems, including metal recovery from MSW incinerator bottom ashes, zinc recovery from industrial ashes and residues, and rare earth metals recovery from EoL permanent magnets.

Multistage leaching of metals from spent lithium ion battery waste using electrochemically generated acidic lixiviant.

PubMed

Boxall, N J; Adamek, N; Cheng, K Y; Haque, N; Bruckard, W; Kaksonen, A H

2018-04-01

Lithium ion battery (LIB) waste contains significant valuable resources that could be recovered and reused to manufacture new products. This study aimed to develop an alternative process for extracting metals from LIB waste using acidic solutions generated by electrolysis for leaching. Results showed that solutions generated by electrolysis of 0.5 M NaCl at 8 V with graphite or mixed metal oxide (MMO) electrodes were weakly acidic and leach yields obtained under single stage (batch) leaching were poor (<10%). This was due to the highly acid-consuming nature of the battery waste. Multistage leaching with the graphite electrolyte solution improved leach yields overall, but the electrodes corroded over time. Though yields obtained with both electrolyte leach solutions were low when compared to the 4 M HCl control, there still remains potential to optimise the conditions for the generation of the acidic anolyte solution and the solubilisation of valuable metals from the LIB waste. A preliminary value proposition indicated that the process has the potential to be economically feasible if leach yields can be improved, especially based on the value of recoverable cobalt and lithium. Copyright © 2018 Elsevier Ltd. All rights reserved.

INTELLIGENT DECISION SUPPORT FOR WASTE MINIMIZATION IN ELECTROPLATING PLANTS. (R824732)

EPA Science Inventory

Abstract

Wastewater, spent solvent, spent process solutions, and sludge are the major waste streams generated in large volumes daily in electroplating plants. These waste streams can be significantly minimized through process modification and operational improvement. I...

A multiobjective modeling approach to locate multi-compartment containers for urban-sorted waste

DOE Office of Scientific and Technical Information (OSTI.GOV)

Tralhao, Lino, E-mail: lmlrt@inescc.p; Coutinho-Rodrigues, Joao, E-mail: coutinho@dec.uc.p; Alcada-Almeida, Luis, E-mail: alcada@inescc.p

2010-12-15