Mechanical properties of concrete containing a high volume of tire-rubber particles.

PubMed

Khaloo, Ali R; Dehestani, M; Rahmatabadi, P

2008-12-01

Due to the increasingly serious environmental problems presented by waste tires, the feasibility of using elastic and flexible tire-rubber particles as aggregate in concrete is investigated in this study. Tire-rubber particles composed of tire chips, crumb rubber, and a combination of tire chips and crumb rubber, were used to replace mineral aggregates in concrete. These particles were used to replace 12.5%, 25%, 37.5%, and 50% of the total mineral aggregate's volume in concrete. Cylindrical shape concrete specimens 15 cm in diameter and 30 cm in height were fabricated and cured. The fresh rubberized concrete exhibited lower unit weight and acceptable workability compared to plain concrete. The results of a uniaxial compressive strain control test conducted on hardened concrete specimens indicate large reductions in the strength and tangential modulus of elasticity. A significant decrease in the brittle behavior of concrete with increasing rubber content is also demonstrated using nonlinearity indices. The maximum toughness index, indicating the post failure strength of concrete, occurs in concretes with 25% rubber content. Unlike plain concrete, the failure state in rubberized concrete occurs gently and uniformly, and does not cause any separation in the specimen. Crack width and its propagation velocity in rubberized concrete are lower than those of plain concrete. Ultrasonic analysis reveals large reductions in the ultrasonic modulus and high sound absorption for tire-rubber concrete.

Tire wear emissions for asphalt rubber and Portland cement concrete pavement surfaces.

DOT National Transportation Integrated Search

2006-04-01

Since 1990, it has been the policy of the State of Arizona that the recycling and reuse of : waste tires are the highest priority. The Arizona Department of Transportation (ADOT) : has long supported the use of recycled waste tire rubber in asphalt r...

Radiation crosslinking of styrene-butadiene rubber containing waste tire rubber and polyfunctional monomers

NASA Astrophysics Data System (ADS)

Yasin, Tariq; Khan, Sara; Shafiq, Muhammad; Gill, Rohama

2015-01-01

The objective of this study was to investigate the influence of polyfunctional monomers (PFMs) and absorbed dose on the final characteristics of styrene-butadiene rubber (SBR) mixed with waste tire rubber (WTR). A series of SBR/WTR blends were prepared by varying the ratios of WTR in the presence of PFMs, namely trimethylolpropane trimethacrylate (TMPTMA) and trimethylolpropane triacrylate (TMPTA) and crosslinked using gamma rays. The physicochemical characteristics of the prepared blends were investigated. It was observed that tensile strength, hardness and gel content of the blends increased with absorbed dose while the blends containing TMPTA showed higher tensile strength, gel content and thermal stability as compared to the blends containing TMPTMA. Higher thermal stability was observed in the blends which were crosslinked by radiation as compared to the blends crosslinked by sulfur. These blends exhibited higher rate of swelling in organic solvents, whereas negligible swelling was observed in acidic and basic environment.

Rubber friction and tire dynamics.

PubMed

Persson, B N J

2011-01-12

We propose a simple rubber friction law, which can be used, for example, in models of tire (and vehicle) dynamics. The friction law is tested by comparing numerical results to the full rubber friction theory (Persson 2006 J. Phys.: Condens. Matter 18 7789). Good agreement is found between the two theories. We describe a two-dimensional (2D) tire model which combines the rubber friction model with a simple mass-spring description of the tire body. The tire model is very flexible and can be used to accurately calculate μ-slip curves (and the self-aligning torque) for braking and cornering or combined motion (e.g. braking during cornering). We present numerical results which illustrate the theory. Simulations of anti-blocking system (ABS) braking are performed using two simple control algorithms.

Characterizing Tire Crumb Rubber for Exposure Assessment

EPA Science Inventory

Tire crumb rubber derived from recycled tires is widely used as infill material in synthetic turf fields in the United States. An estimated 95% of the over 12,000 installed fields in the U.S. use tire crumb rubber infill alone or mixed with sand or alternative materials. Concerns...

A new class of magnetorheological elastomers based on waste tire rubber and the characterization of their properties

NASA Astrophysics Data System (ADS)

Ubaidillah; Imaduddin, Fitrian; Li, Yancheng; Amri Mazlan, Saiful; Sutrisno, Joko; Koga, Tsuyoshi; Yahya, Iwan; Choi, Seung-Bok

2016-11-01

This paper proposes a new type of magnetorheological elastomer (MRE) using rubber from waste tires and describes its performance characteristics. In this work, scrap tires were utilized as a primary matrix for the MRE without incorporation of virgin elastomers. The synthesis of the scrap tire based MRE adopted a high-temperature high-pressure sintering technique to achieve the reclaiming of vulcanized rubber. The material properties of the MRE samples were investigated through physical and viscoelastic examinations. The physical tests confirmed several material characteristics—microstructure, magnetic, and thermal properties-while the viscoelastic examination was conducted with a laboratory-made dynamic compression apparatus. It was observed from the viscoelastic examination that the proposed MRE has magnetic-field-dependent properties of the storage modulus, loss modulus, and loss tangent at different excitation frequencies and strain amplitudes. Specifically, the synthesized MRE showed a high zero field modulus, a reasonable MR effect under maximum applied current, and remarkable damping properties.

Flexible and conductive waste tire-derived carbon/polymer composite paper as pseudocapacitive electrode

DOE Office of Scientific and Technical Information (OSTI.GOV)

Naskar, Amit K.; Paranthaman, Mariappan Parans; Boota, Muhammad

A method of making a supercapacitor from waste tires, includes the steps of providing rubber pieces and contacting the rubber pieces with a sulfonation bath to produce sulfonated rubber; pyrolyzing the sulfonated rubber to produce a tire-derived carbon composite comprising carbon black embedded in rubber-derived carbon matrix comprising graphitized interface portions; activating the tire-derived carbon composite by contacting the tire-derived carbon composite with a specific surface area-increasing composition to increase the specific surface area of the carbon composite to provide an activated tire-derived carbon composite; and, mixing the activated tire-derived carbon composite with a monomer and polymerizing the monomer tomore » produce a redox-active polymer coated, activated tire-derived carbon composite. The redox-active polymer coated, activated tire-derived carbon composite can be formed into a film. An electrode and a supercapacitor are also disclosed.« less

Rubber industry

NASA Astrophysics Data System (ADS)

Staszak, Maciej

2018-03-01

Following chapter presents short introductory description of rubber and rubber industry. The main problem of rubber industry is the way of the usage of spent tires. Furthermore very important group of problems arise considering the metal and nonmetal additives which are significant component of the vulcanized rubber. The key attention is dedicated to typical ways of rubber usage in utilization and recovery of metals from spent rubber materials concentrating specifically on used tires processing. The method of recovery of rare metals from rubber tires was described. The rubber debris finds widest use in the field of waste metal solutions processing. The environmental pollution caused by metals poses serious threat to humans. Several applications of the use of waste rubber debris to remove metals from environmental waters were described. Moreover, the agriculture usage of waste tire rubber debris is described, presenting systems where the rubber material can be useful as a soil replacement.

Ground tire rubber as a stabilizer for subgrade soils.

DOT National Transportation Integrated Search

2014-05-01

Over 250 million scrap tires are generated annually in the U.S. Historically, a significant portion of these tires : have been processed into finely ground tire rubber (GTR), or crumb rubber, for use as an additive in hot mix asphalt : (HMA) pavement...

Tailored Recovery of Carbons from Waste Tires for Enhanced Performance as Anodes in Lithium-ion Batteries

DOE Office of Scientific and Technical Information (OSTI.GOV)

Naskar, Amit K; Bi,; Saha, Dipendu

2014-01-01

Morphologically tailored pyrolysis-recovered carbon black is utilized in lithium-ion batteries as a potential solution for adding value to waste tire-rubber-derived materials. Micronized tire rubber was digested in a hot oleum bath to yield a sulfonated rubber slurry that was then filtered, washed, and compressed into a solid cake. Carbon was recovered from the modified rubber cake by pyrolysis in a nitrogen atmosphere. The chemical pretreatment of rubber produced a carbon monolith with higher yield than that from the control (a fluffy tire-rubber-derived carbon black). The carbon monolith showed a very small volume fraction of pores of widths 3 4 nm,more » reduced specific surface area, and an ordered assembly of graphitic domains. Electrochemical studies on the recovered-carbon-based anode revealed an improved Li-ion battery performance with higher reversible capacity than that of commercial carbon materials. Anodes made with a sulfonated tire-rubber-derived carbon and a control tire-rubber-derived carbon, respectively, exhibited an initial coulombic efficiency of 80% and 45%, respectively. The reversible capacity of the cell with the sulfonated carbon as anode was 400 mAh/g after 100 cycles, with nearly 100% coulombic efficiency. Our success in producing higher performance carbon material from waste tire rubber for potential use in energy storage applications adds a new avenue to tire rubber recycling.« less

EB-promoted recycling of waste tire rubber with polyolefins

NASA Astrophysics Data System (ADS)

Mészáros, László; Bárány, Tamás; Czvikovszky, Tibor

2012-09-01

Despite the fact that more and more methods and solutions are used in the recycling of polymers, there are still some problems, especially in the recycling of cross-linked materials such as rubber. Usually the biggest problem is the lack of compatibility between the cross-linked rubber and the thermoplastic matrix. In this study we applied ground tire rubber (GTR) as recycled material. The GTR was embedded into polyethylene (PE) and polyethylene/ethylene-vinyl acetate copolymer (PE/EVA) matrices. In order to increase the compatibility of the components electron beam (EB) irradiation was applied. The results showed that the irradiation has a beneficial effect on the polymer-GTR interfacial connection. The EB treatment increased not only the tensile strength but also the elongation at break. The irradiation had also positive effect on the impact strength properties.

Microwave Absorption Characteristics of Tire

NASA Astrophysics Data System (ADS)

Zhang, Yuzhe; Hwang, Jiann-Yang; Peng, Zhiwei; Andriese, Matthew; Li, Bowen; Huang, Xiaodi; Wang, Xinli

The recycling of waste tires has been a big environmental problem. About 280 million waste tires are produced annually in the United States and more than 2 billion tires are stockpiled, which cause fire hazards and health issues. Tire rubbers are insoluble elastic high polymer materials. They are not biodegradable and may take hundreds of years to decompose in the natural environment. Microwave irradiation can be a thermal processing method for the decomposition of tire rubbers. In this study, the microwave absorption properties of waste tire at various temperatures are characterized to determine the conditions favorable for the microwave heating of waste tires.

Ground tire rubber as a stabilizer for subgrade soils : [summary].

DOT National Transportation Integrated Search

2014-05-01

Over 250 million scrap tires are generated : annually in the U.S. Historically, a significant : portion of these tires have been processed into : finely ground tire rubber (GTR), or crumb rubber, : for use as an additive in hot mix asphalt (HMA) : pa...

Thermolysis of scrap tire and rubber in sub/super-critical water.

PubMed

Li, Qinghai; Li, Fuxin; Meng, Aihong; Tan, Zhongchao; Zhang, Yanguo

2018-01-01

The rapid growth of waste tires has become a serious environmental issue. Energy and material recovery is regarded as a promising use for waste tires. Thermolysis of scrap tire (ST), natural rubber (NR), and styrene-butadiene rubber (SBR) was carried out in subcritical and supercritical water using a temperature-pressure independent adjustable batch tubular reactor. As a result, oil yields increased as temperature and pressure increased, and they reached maximum values as the state of water was near the critical point. However, further increases in water temperature and pressure reduced the oil yields. The maximum oil yield of 21.21% was obtained at 420 °C and 18 MPa with a reaction time of 40 min. The relative molecular weights of the chemicals in the oil products were in the range of 70-140 g/mole. The oil produced from ST, NR, and SBR contained similar chemical compounds, but the oil yield of SR was between those of NR and SBR. The oil yield from thermolysis of subcritical or supercritical water should be further improved. The main gaseous products, including CH 4 , C 2 H 2 , C 2 H 4 , C 2 H 6 , and C 3 H 8 , increased with reaction time, temperature, and pressure, whereas the solid residues, including carbon black and impurities, decreased. These results provide useful information to develop a sub/super-critical water thermolysis process for energy and material regeneration from waste tires. Copyright © 2017 Elsevier Ltd. All rights reserved.

Laboratory Investigation on the Effects of Natural Fine Aggregates and Recycled Waste Tire Rubber in Pervious Concrete to Develop More Sustainable Pavement Materials

NASA Astrophysics Data System (ADS)

Bonicelli, Alessandra; Fuentes, Luis G.; Khalil Dawd Bermejo, Ibrahim

2017-10-01

Pervious concrete pavement is a recognized sustainable solution for urban roads. To enhance mechanical properties of pervious concrete material, in order to allow wider use of this technology, a lot of studies are going on all over the world. The use of a little percentage of fine aggregates is proven to increase the material resistance without an excessive reduction of permeability. This study aimed to evaluate the effect of replacing the fine virgin aggregates with r cycled tire rubber. 14 different mixes were analysed in terms of indirect tensile strength resistance, void content and density. Two different dimensions of crumb rubber were studied, as well as two different dosages, which were applied to different no-fine control mixes. All results were compared with the same control mixes containing natural fine aggregate. The mixes had a fixed granulometric curve but varied in water/cement ratio; this in order to evaluate the effect of recycled rubber depending to w/c ratio of the mix. An image analysis was also conducted to verify the rubber distribution in the mixture and the cracking surfaces. The experimental analysis showed that a correct proportioning of fine sand significantly increased the strength of the material. Moreover, the use of recycled waste tire rubber, gave interesting improvements respect to the no-fine control mixes, even though the developed resistance was lower respect to mixes containing mineral sand. This result was expected because of the cementing property of mineral sand. Although, the important result was that it was possible to use waste tire rubber in pervious concrete, with an appropriate dosage and granular dimension, for increasing the performance of traditional mix design, in order to achieve pavement materials more and more sustainable.

Strength and microstructure characteristics of the recycled rubber tire-sand mixtures as lightweight backfill.

PubMed

Zhang, Tao; Cai, Guojun; Duan, Weihong

2018-02-01

The disposal of scrap rubber tires has induced critical environmental issue worldwide due to the rapid increase in the number of vehicles. Recycled scrap tires as a construction material in civil engineering have significant environmental benefits from a waste management perspective. A systematic study that deals with strength and microstructure characteristics of the rubber-sand mixtures is initiated, and mechanical response of the mixtures is discussed in this investigation. Experiments were conducted to evaluate the effects of rubber fraction on the basic properties including mass density (ρ), stress-strain characteristics, shear strength, and unconfined compression strength (q u ) of the rubber-sand mixtures. Additionally, scanning electron microscopy (SEM) was carried out to reveal the microstructure characteristics of the mixtures with various rubber fractions. A discussion on the micromechanics of the mixtures also was conducted. This study demonstrates that the ρ, friction angle, and q u decrease linearly with an increase in rubber fraction, whereas shear strain at peak increases. The stress-strain characteristics of the rubber-sand mixtures shift from brittle to ductile as the rubber fraction increase. These changes are attributed to remarkably lower stiffness and higher compressibility of the rubber particle compared with those of the conventional mineral aggregates. With an increase in the rubber fraction, the mechanical response of rubber-sand mixtures exhibits two types: sand-like material and rubber-like material. Rubber particle possesses the capacity to prevent the contacted sand particles from sliding at lower rubber fraction, whereas it transmits the applied loadings as the rubber fraction increased. This outcome reinforces the practicability of using recycled rubber tire-sand mixtures as a lightweight backfill in subbase/base applications.

Evaluation of the use of rubber-tire rollers on asphalt concrete.

DOT National Transportation Integrated Search

1989-01-01

The addition of a rubber-tire roller was required on two projects on maintenance schedules and on two construction projects in 1988. The rubber-tire roller was used as an addition to the conventional rollers on one-half of each project. The rubber-ti...

Properties and potential environmental applications of carbon adsorbents from waste tire rubber

USGS Publications Warehouse

Lehmann, C.M.B.; Rameriz, D.; Rood, M.J.; Rostam-Abadi, M.

2000-01-01

The properties of tire-derived carbon adsorbents (TDCA) produced from select tire chars were compared with those derived from an Illinois coal and pistachio nut shells. Chemical analyses of the TDCA indicated that these materials contain metallic elements not present in coal-and nut shell-derived carbons. These metals, introduced during the production of tire rubber, potentially catalyze steam gasification reactions of tire char. TDCA carbons contained larger meso-and macopore volumes than their counterparts derived from coal and nut shell (on the moisture-and ash-free-basis). Adsorptive properties of the tire-derived adsorbent carbons for air separation, gas storage, and gas clean up were also evaluated and compared with those of the coal-and nut shell derived carbons as well as a commercial activated carbon. The results revealed that TDCA carbons are suitable adsorbents for removing vapor-phase mercury from combustion flue gases and hazardous organic compounds from industrial gas streams.

Microbial detoxification of waste rubber material by wood-rotting fungi.

PubMed

Bredberg, Katarina; Andersson, B Erik; Landfors, Eva; Holst, Olle

2002-07-01

The extensive use of rubber products, mainly tires, and the difficulties to recycle those products, has resulted in world wide environmental problems. Microbial devulcanisation is a promising way to increase the recycling of rubber materials. One obstacle is that several microorganisms tested for devulcanisation are sensitive to rubber additives. A way to overcome this might be to detoxify the rubber material with fungi prior to the devulcanisation. In this study, 15 species of white-rot and brown-rot fungi have been screened with regard to their capacity to degrade an aromatic model compound in the presence of ground waste tire rubber. The most effective fungus, Resinicium bicolor, was used for detoxification of rubber material. Increase in growth of the desulfurising bacterium Thiobacillus ferrooxidans in presence of the rubber treated with Resinicium bicolor compared to untreated rubber demonstrated that detoxification with fungi is possible.

Forensic analysis of tire rubbers based on their sulfur chemical states.

PubMed

Funatsuki, Atsushi; Shiota, Kenji; Takaoka, Masaki; Tamenori, Yusuke

2015-05-01

The chemical states of sulfur in 11 tires were analyzed using X-ray absorption near-edge structure (XANES) in order to discriminate between various tire rubbers. All tires had peaks around 2471.5 and 2480.5eV, and the shapes and heights of these peaks differed among tires, suggesting that the sulfur chemical state could be used for discrimination between tire rubbers. Based on t-tests on the results of XANES, 43 of 55 combinations were different at a significance level of 5%. Copyright © 2015 Elsevier Ireland Ltd. All rights reserved.

Improved crystallinity and dynamic mechanical properties of reclaimed waste tire rubber/EVA blends under the influence of electron beam irradiation

NASA Astrophysics Data System (ADS)

Ramarad, Suganti; Ratnam, Chantara T.; Khalid, Mohammad; Chuah, Abdullah Luqman; Hanson, Svenja

2017-01-01

Dependence on automobiles has led to a huge amount of waste tires produced annually around the globe. In this study, the feasibility of recycling these waste tires by blending reclaimed waste tire rubber (RTR) with poly(ethylene-co-vinyl acetate) (EVA) and electron beam irradiation was studied. The RTR/EVA blends containing 100-0 wt% of RTR were prepared in the internal mixer followed by electron beam (EB) irradiation with doses ranging from 50 to 200 kGy. The processing torques, calorimetric and dynamic mechanical properties of the blends were studied. Blends were found to have lower processing torque indicating easier processability of RTR/EVA blends compared to EVA. RTR domains were found to be dispersed in EVA matrix, whereas, irradiation improved the dispersion of RTR into smaller domains in EVA matrix. Results showed the addition of EVA improves the efficiency of irradiation induced crosslink formation and dynamic mechanical properties of the blends at the expense of the calorimetric properties. Storage and loss modulus of 50 wt% RTR blend was higher than RTR and EVA, suggesting partial miscibility of the blend. Whereas, electron beam irradiation improved the calorimetric properties and dynamic mechanical properties of the blends through redistribution of RTR in smaller domain sizes within EVA.

78 FR 54369 - The Goodyear Tire & Rubber Company, Mootness of Petition for Decision of Inconsequential...

Federal Register 2010, 2011, 2012, 2013, 2014

2013-09-03

... subject tires meet or exceed all applicable FMVSS performance standards for a tire labeled as either load...-0107; Notice 2] The Goodyear Tire & Rubber Company, Mootness of Petition for Decision of... Petition Mootness. SUMMARY: The Goodyear Tire & Rubber Company (Goodyear),\\1\\ has determined that certain...

Friction characteristics of 20 x 4.4, type 7, aircraft tires constructed with different tread rubber compounds

NASA Technical Reports Server (NTRS)

Dreher, R. C.; Yager, T. J.

1976-01-01

A test program was conducted at the Langley aircraft landing loads and traction facility to evaluate the friction characteristics of 20 x 4.4, type, aircraft tires constructed with experimental cut-resistant, tread rubber compounds. These compounds consisted of different blends of natural rubber (NR) and an alfin catalyzed styrene-butadiene copolymer rubber (SBR). One tire having a blend of 30 SBR and 70 NR and another having a blend of 60 SBR and 40 NR in the tread were tested together with a standard production tire with no SBR content in the tread rubber. The results of this investigation indicated that the test tires constructed with the special cut-resistant tread rubber compositions did not suffer any significant degradation in tire friction capability when compared with the standard tire. In general, tire friction capability decreased with increasing speed and surface wetness condition. As yaw angle increased, tire braking capability decreased while tire cornering capability increased. Tread-wear data based on number of brake cycles, however, suggested that the tires with alfin SBR blends experienced significantly greater wear than the standard production tire.

Upgrading pyrolytic residue from waste tires to commercial carbon black.

PubMed

Zhang, Xue; Li, Hengxiang; Cao, Qing; Jin, Li'e; Wang, Fumeng

2018-05-01

The managing and recycling of waste tires has become a worldwide environmental challenge. Among the different disposal methods for waste tires, pyrolysis is regarded as a promising route. How to effectively enhance the added value of pyrolytic residue (PR) from waste tires is a matter of great concern. In this study, the PRs were treated with hydrochloric and hydrofluoric acids in turn under ultrasonic waves. The removal efficiency for the ash and sulfur was investigated. The pyrolytic carbon black (PCB) obtained after treating PR with acids was analyzed by X-ray fluorescence spectrophotometry, Fourier transform infrared spectrometry, X-ray diffractometry, laser Raman spectrometry, scanning electron microscopy, thermogravimetric (TG) analysis, and physisorption apparatus. The properties of PCB were compared with those of commercial carbon black (CCB) N326 and N339. Results showed PRs from waste tires were mainly composed of carbon, sulfur, and ash. The carbon in PCB was mainly from the CCB added during tire manufacture rather than from the pyrolysis of pure rubbers. The removal percentages for the ash and sulfur of PR are 98.33% (from 13.98 wt % down to 0.24 wt %) and 70.16% (from 1.81 wt % down to 0.54 wt %), respectively, in the entire process. The ash was mainly composed of metal oxides, sulfides, and silica. The surface properties, porosity, and morphology of the PCB were all close to those of N326. Therefore, PCB will be a potential alternative of N326 and reused in tire manufacture. This route successfully upgrades PR from waste tires to the high value-added CCB and greatly increases the overall efficiency of the waste tire pyrolysis industry.

Analysis of Cement-Based Pastes Mixed with Waste Tire Rubber

NASA Astrophysics Data System (ADS)

Sola, O. C.; Ozyazgan, C.; Sayin, B.

2017-03-01

Using the methods of thermal gravimetry, differential thermal analysis, Furier transform infrared analysis, and capillary absorption, the properties of a cement composite produced by introducing waste tyre rubber into a cement mixture were investigated. It was found that the composite filled with the rubber had a much lower water absorption ability than the unfilled one.

Fabrication and viscoelastic characteristics of waste tire rubber based magnetorheological elastomer

NASA Astrophysics Data System (ADS)

Ubaidillah; Choi, H. J.; Mazlan, S. A.; Imaduddin, F.; Harjana

2016-11-01

In this study, waste tire rubber (WTR) was successfully converted into magnetorheological (MR) elastomer via high-pressure and high-temperature reclamation. The physical and rheological properties of WTR based MR elastomers were assessed for performance. The revulcanization process was at the absence of magnetic fields. Thus, the magnetizable particles were allowed to distribute randomly. To confirm the particle dispersion in the MR elastomer matrix, an observation by scanning electron microscopy was used. The magnetization saturation and other magnetic properties were obtained through vibrating sample magnetometer. Rheological properties including MR effect were examined under oscillatory loadings in the absence and presence of magnetic fields using rotational rheometer. The WTR based MR elastomer exhibited tunable intrinsic properties under presentation of magnetic fields. The storage and loss modulus, along with the loss factor, changed with increases in frequency and during magnetization. Interestingly, a Payne effect phenomenon was seen in all samples during dynamic swept strain testing. The Payne effect was significantly increased with incremental increases in the magnetic field. This phenomenon was interpreted as the process of formation-destruction-reformation undergone by the internal network chains in the MR elastomers.

Characterization of Irradiated and Non-Irradiated Rubber from Automotive Scrap Tires

NASA Astrophysics Data System (ADS)

Souza, Clécia Moura; Silva, Leonardo G.

The aim of this work was to characterize the samples of irradiated and non-irradiated rubber from automotive scrap tires. Rubber samples from scrap tires were irradiated at irradiation doses of 200, 400 and 600kGy in an electron beam accelerator. Subsequently, both the irradiated and non-irradiated samples were characterized by thermogravimetry (TG), differential scanning calorimetry (DSC), tensile strength mechanical test, and Fourier transform infrared (FTIR) spectrophotometry.

Direct molding of pavement tiles made of ground tire rubber

NASA Astrophysics Data System (ADS)

Quadrini, Fabrizio; Gagliardi, Donatella; Tedde, Giovanni Matteo; Santo, Loredana; Musacchi, Ettore

2016-10-01

Large rubber products can be molded by using only ground tire rubber (GTR) without any additive or binder due to a new technology called "direct molding". Rubber granules and powders from tire recycling are compression molded at elevated temperatures and pressures. The feasibility of this process was clearly shown in laboratory but the step to the industrial scale was missing. Thanks to an European Project (SMART "Sustainable Molding of Articles from Recycled Tires") this step has been made and some results are reported in this study. The press used for compression molding is described. Some tests were made to measure the energy consumption so as to evaluate costs for production in comparison with conventional technologies for GTR molding (by using binders). Results show that 1 m2 tiles can be easily molded with several thicknesses in a reasonable low time. Energy consumption is higher than conventional technologies but it is lower than the cost for binders.

75 FR 81712 - The Goodyear Tire & Rubber Company, Receipt of Petition for Decision of Inconsequential...

Federal Register 2010, 2011, 2012, 2013, 2014

2010-12-28

..., all of the tires included in this petition meet or exceed the performance requirements of FMVSS No...-0174; Notice 1] The Goodyear Tire & Rubber Company, Receipt of Petition for Decision of Inconsequential Noncompliance The Goodyear Tire & Rubber Company (Goodyear) \\1\\ has determined that certain Goodyear commercial...

Rubber tire leachates in the aquatic environment.

PubMed

Evans, J J

1997-01-01

Tires have a deleterious effect on the environment. This review discusses the background of scrap tires discarded in the environment, including tire composition, adverse environmental effects, threats to public health and safety, and solid waste management. Despite the widespread use of scrap tires in environmental applications, both land-based and aquatic, data on the indicators of environmental degradation are extremely scarce. Indicators of environmental degradation include analysis of chemicals within the water and sediment, analysis of contaminants within organisms, and analysis of the biological effects of these compounds on plants, animals, microbes, and organelles. Although these indicators are most useful when used in parallel, a review of the available information on chemical characterization of tire leachate from tire storage facilities, manufacturing, usage in recycling applications, and toxicity exposure studies, of vegetation surveys from waste tire areas and reviews of mammalian tire product toxicity, and of toxicity, mutagenicity, and carcinogenicity of tire exposure in experimental aquatic animals, microbes, and organelles is presented. The major characteristics of these studies are discussed in specific sections. The "Discussion and Conclusions" section discusses and summarizes the biological effects and chemical characterization of tire leachates. A global environmental perspective is included to improve our understanding of the deficiency of the current knowledge of tire leachate toxicity from various sources and to encourage interdisciplinary studies to establish the pattern of pollution associated with waste tire management.

77 FR 2775 - Goodyear Tire and Rubber Company, Grant of Petition for Decision of Inconsequential Noncompliance

Federal Register 2010, 2011, 2012, 2013, 2014

2012-01-19

... tread wear, temperature, and traction ratings, to assess performance capabilities of various tires. In...-0033; Notice 2] Goodyear Tire and Rubber Company, Grant of Petition for Decision of Inconsequential.... SUMMARY: Goodyear Tire and Rubber Company,(Goodyear),\\1\\ has determined that approximately 26,224 Goodyear...

Characterization of Semi-Volatile Organic Chemicals from Tire Crumb Rubber

EPA Science Inventory

Recycled tire crumb rubber (TCR) is often used as infill material in synthetic turf playing fields as well as some playgrounds. Concerns have been raised about the safety of this material and a multi-agency Federal Research Action Plan on Recycled Tire Crumb Used on Playing Field...

Rubber-based carbon electrode materials derived from dumped tires for efficient sodium-ion storage.

PubMed

Wu, Zhen-Yue; Ma, Chao; Bai, Yu-Lin; Liu, Yu-Si; Wang, Shi-Feng; Wei, Xiao; Wang, Kai-Xue; Chen, Jie-Sheng

2018-04-03

The development of sustainable and low cost electrode materials for sodium-ion batteries has attracted considerable attention. In this work, a carbon composite material decorated with in situ generated ZnS nanoparticles has been prepared via a simple pyrolysis of the rubber powder from dumped tires. Upon being used as an anode material for sodium-ion batteries, the carbon composite shows a high reversible capacity and rate capability. A capacity as high as 267 mA h g-1 is still retained after 100 cycles at a current density of 50 mA g-1. The well dispersed ZnS nanoparticles in carbon significantly enhance the electrochemical performance. The carbon composites derived from the rubber powder are proposed as promising electrode materials for low-cost, large-scale energy storage devices. This work provides a new and effective method for the reuse of dumped tires, contributing to the recycling of valuable waste resources.

Use of scrap tire rubber : state of the technology and best practices.

DOT National Transportation Integrated Search

2005-02-01

The California Department of Transportation (Caltrans) has been using scrap tire rubber (called crumb : rubber modifier (CRM)) in asphalt pavements since the 1970s in chip seals and the 1980s in rubberized : asphalt concrete (RAC). The performance of...

Theoretical and experimental analysis of the contact between a solid-rubber tire and a chassis dynamometer

NASA Astrophysics Data System (ADS)

Belkin, A. E.; Semenov, V. K.

2016-05-01

We consider the problem of modeling the test where a solid-rubber tire runs on a chassis dynamometer for determining the tire rolling resistance characteristics.We state the problem of free steady-state rolling of the tire along the test drum with the energy scattering in the rubber in the course of cyclic deformation taken into account. The viscoelastic behavior of the rubber is described by the Bergströ m-Boyce model whose numerical parameters are experimentally determined from the results of compression tests with specimens. The finite element method is used to obtain the solution of the three-dimensional viscoelasticity problem. To estimate the adequacy of the constructed model, we compare the numerical results with the results obtained in the solid-rubber tire tests on the Hasbach stand from the values of the rolling resistance forces for various loads on the tire.

Chemical and Physical Analysis Methods for Characterizing Tire Crumb Rubber Used in Synthetic Turf Fields

EPA Science Inventory

Tire crumb rubber from recycled tires is widely used as infill material in synthetic turf fields in the United States. Recycled crumb rubber is a complex and potentially variable matrix with many metal, VOC, and SVOC constituents, presenting challenges for characterization and ex...

40 CFR 721.10579 - Carbon black derived from the pyrolysis of rubber tire shreds (generic).

Code of Federal Regulations, 2013 CFR

2013-07-01

... pyrolysis of rubber tire shreds (generic). 721.10579 Section 721.10579 Protection of Environment... pyrolysis of rubber tire shreds (generic). (a) Chemical substance and significant new uses subject to reporting. (1) The chemical substance identified generically as carbon black derived from the pyrolysis of...

Fatigue of cord-rubber composites for tires

NASA Astrophysics Data System (ADS)

Song, Jaehoon

Fatigue behaviors of cord-rubber composite materials forming the belt region of radial pneumatic tires have been characterized to assess their dependence on stress, strain and temperature history as well as materials composition and construction . Using actual tires, it was found that interply shear strain is one of the crucial parameters for damage assessment from the result that higher levels of interply shear strain of actual tires reduce the fatigue lifetime. Estimated at various levels of load amplitude were the fatigue life, the extent and rate of resultant strain increase ("dynamic creep"), cyclic strains at failure, and specimen temperature. The interply shear strain of 2-ply 'tire belt' composite laminate under circumferential tension was affected by twisting of specimen due to tension-bending coupling. However, a critical level of interply shear strain, which governs the gross failure of composite laminate due to the delamination, appeared to be independent of different lay-up of 2-ply vs. symmetric 4-ply configuration. Reflecting their matrix-dominated failure modes such as cord-matrix debonding and delamination, composite laminates with different cord reinforcements showed the same S-N relationship as long as they were constructed with the same rubber matrix, the same cord angle, similar cord volume, and the same ply lay-up. Because of much lower values of single cycle strength (in terms of gross fracture load per unit width), the composite laminates with larger cord angle and the 2-ply laminates exhibited exponentially shorter fatigue lifetime, at a given stress amplitude, than the composite laminates with smaller cord angle and 4-ply symmetric laminates, respectively. The increase of interply rubber thickness lengthens their fatigue lifetime at an intermediate level of stress amplitude. However, the increase in the fatigue lifetime of the composite laminate becomes less noticeable at very low stress amplitude. Even with small compressive cyclic

78 FR 47050 - Cooper Tire & Rubber Company, Grant of Petition for Decision of Inconsequential Noncompliance

Federal Register 2010, 2011, 2012, 2013, 2014

2013-08-02

...: Cooper Tire & Rubber Company (Cooper) \\1\\ has determined that certain Cooper brand replacement tires... approximately 1,080 size P225/ 70R14 El Dorado Legend GT brand standard load replacement tires manufactured in...

Hazardous organic chemicals in rubber recycled tire playgrounds and pavers.

PubMed

Llompart, Maria; Sanchez-Prado, Lucia; Pablo Lamas, J; Garcia-Jares, Carmen; Roca, Enrique; Dagnac, Thierry

2013-01-01

In this study, the presence of hazardous organic chemicals in surfaces containing recycled rubber tires is investigated. Direct material analyses using solvent extraction, as well as SPME analysis of the vapour phase above the sample, were carried out. Twenty-one rubber mulch samples were collected from nine different playgrounds. In addition, seven commercial samples of recycled rubber pavers were acquired in a local store of a multinational company. All samples were extracted by ultrasound energy, followed by analysis of the extract by GC-MS. The analysis confirmed the presence of a large number of hazardous substances including PAHs, phthalates, antioxidants (e.g. BHT, phenols), benzothiazole and derivatives, among other chemicals. The study evidences the high content of toxic chemicals in these recycled materials. The concentration of PAHs in the commercial pavers was extremely high, reaching values up to 1%. In addition, SPME studies of the vapour phase above the samples confirm the volatilisation of many of those organic compounds. Uses of recycled rubber tires, especially those targeting play areas and other facilities for children, should be a matter of regulatory concern. Copyright © 2012 Elsevier Ltd. All rights reserved.

Upscaling of a Batch De-Vulcanization Process for Ground Car Tire Rubber to a Continuous Process in a Twin Screw Extruder.

PubMed

Saiwari, Sitisaiyidah; van Hoek, Johannes W; Dierkes, Wilma K; Reuvekamp, Louis E A M; Heideman, Geert; Blume, Anke; Noordermeer, Jacques W M

2016-08-24

As a means to decrease the amount of waste tires and to re-use tire rubber for new tires, devulcanization of ground passenger car tires is a promising process. Being an established process for NR and EPDM, earlier work has shown that for ground passenger car tire rubber with a relatively high amount of SBR, a devulcanization process can be formulated, as well. This was proven for a laboratory-scale batch process in an internal mixer, using diphenyl disulfide as the devulcanization aid and powder-sized material. In this paper, the devulcanization process for passenger car tire rubber is upscaled from 15 g per batch and transformed into a continuous process in a co-rotating twin screw extruder with a capacity of 2 kg/h. As SBR is rather sensitive to devulcanization process conditions, such as thermal and mechanical energy input, the screw design was based on a low shear concept. A granulate with particle sizes from 1-3.5 mm was chosen for purity, as well as economic reasons. The devulcanization process conditions were fine-tuned in terms of: devulcanization conditions (time/temperature profile, concentration of devulcanization aid), extruder parameters (screw configuration, screw speed, fill factor) and ancillary equipment (pre-treatment, extrudate handling). The influence of these parameters on the devulcanization efficiency and the quality of the final product will be discussed. The ratio of random to crosslink scission as determined by a Horikx plot was taken for the evaluation of the process and material. A best practice for continuous devulcanization will be given.

Upscaling of a Batch De-Vulcanization Process for Ground Car Tire Rubber to a Continuous Process in a Twin Screw Extruder

PubMed Central

Saiwari, Sitisaiyidah; van Hoek, Johannes W.; Dierkes, Wilma K.; Reuvekamp, Louis E.A.M.; Heideman, Geert; Blume, Anke; Noordermeer, Jacques W.M.

2016-01-01

As a means to decrease the amount of waste tires and to re-use tire rubber for new tires, devulcanization of ground passenger car tires is a promising process. Being an established process for NR and EPDM, earlier work has shown that for ground passenger car tire rubber with a relatively high amount of SBR, a devulcanization process can be formulated, as well. This was proven for a laboratory-scale batch process in an internal mixer, using diphenyl disulfide as the devulcanization aid and powder-sized material. In this paper, the devulcanization process for passenger car tire rubber is upscaled from 15 g per batch and transformed into a continuous process in a co-rotating twin screw extruder with a capacity of 2 kg/h. As SBR is rather sensitive to devulcanization process conditions, such as thermal and mechanical energy input, the screw design was based on a low shear concept. A granulate with particle sizes from 1–3.5 mm was chosen for purity, as well as economic reasons. The devulcanization process conditions were fine-tuned in terms of: devulcanization conditions (time/temperature profile, concentration of devulcanization aid), extruder parameters (screw configuration, screw speed, fill factor) and ancillary equipment (pre-treatment, extrudate handling). The influence of these parameters on the devulcanization efficiency and the quality of the final product will be discussed. The ratio of random to crosslink scission as determined by a Horikx plot was taken for the evaluation of the process and material. A best practice for continuous devulcanization will be given. PMID:28773843

A practical approach for solving disposal of rubber waste: Leachability of heavy metals from foamed concrete containing rubber powder waste (RPW)

NASA Astrophysics Data System (ADS)

Kadir, Aeslina Abdul; Hassan, Mohd Ikhmal Haqeem; Sarani, Noor Amira; Yatim, Fatin Syahirah Mohamed; Jaini, Zainorizuan Mohd

2017-09-01

Enormous disposal of rubber wastes has become an issue with the facts that all tires have its own life span. Inefficient disposal method of RPW from used tire can cause environmental impact as the heavy metals content in tire can easily leach out thus causing contamination to the soil and waterways. The goals of this study is to identify the heavy metals content of rubber powder waste (RPW) and to determine the potential of leachability of heavy metals from foamed concrete containing different percentages of RPW. Therefore, this study is focused on the leachability of RPW incorporated in foamed concrete. Different percentages of RPW were incorporated in foamed concrete (0%, 6%, 12% and 18%) for the investigation. Leachability tests were done by using toxicity characteristic leaching procedure (TCLP) on crushed samples of foamed concrete incorporated with RPW and were analyzed by using inductive coupled plasma mass spectrometry (ICP-MS). The results from XRF indicated that RPW is high in metals such as Zn, Cu, Ba and Co. The highest concentration of heavy metals in raw RPW is Zn with 51403 ppm which is exceeded USEPA (2010) maximum contaminant level (MCL) of Zn with only 5 ppm. After RPW had been incorporated into a foamed concrete, the results demonstrated that the Zn, Cu, Ba and Co heavy metals were less leached and complied with USEPA standard. The incorporation of RPW into foamed concrete in this study demonstrated that it could be a potential alternative raw material for concrete thus enhancing the possibility of its reuse in safe and sustainable way.

Respiratory tract disease from thermosetting resins. Study of an outbreak in rubber tire workers.

PubMed

doPico, G A; Rankin, J; Chosy, L W; Reddan, W G; Barbee, R A; Gee, B; Dickie, H A

1975-08-01

An outbreak of upper and lower respiratory tract inflammatory disease and conjunctivitis among synthetic rubber tire workers occurred. The outbreak began after the introduction of a new thermosetting resin, containing resorcinol and a trimere of methylene aminoacetronitrile, into the rubber tire carcass stock formulation. Two hundred ten workers were affected. Characteristically, symptoms improved during periods of sick leave or vacation, recurring upon the workers' return to the plant. Chest radiograms disclosed pneumonic infiltrates in about one fourth of the cases. Pulmonary function studies detected abnormal airways dynamics as well as abnormal diffusing capacity in more than one third of the workers tested. Lung biopsy showed evidence of focal interstitial fibrosis and peribronchiolar and perivascular chronic inflammatory reaction. The illness was ascribed to volatile products released during the manufacture of synthetic rubber tires. The exact chemical nature of these products is unknown.

Friction characteristics of three 30 by 11.5-14.5, type 8, aircraft tires with various tread groove patterns and rubber compounds

NASA Technical Reports Server (NTRS)

Yager, T. J.; Mccarty, J. L.

1977-01-01

A test program was conducted to evaluate friction performance and wear characteristics on wet runways of three 30 x 11.5-14.5, type, aircraft tires having two different tread patterns and natural rubber contents. All test tires had the standard three circumferential groove tread, but two had molded transverse grooves which extended from shoulder to shoulder. The tread rubber content of the two tires with transverse grooves differed in that one had a 100 percent natural rubber tread and the other had a rubber tread composition that was 30 percent synthetic and 70 percent natural. The third test tire had the conventional 100 percent natural rubber tread. Results indicate that the differences in tire tread design and rubber composition do not significantly affect braking and cornering friction capability on wet or dry surfaces. Braking performance of the tires decreases with increased speed, with increased yaw angle and, at higher speeds, with increased wetness of the surface.

Kinetics of zinc release from ground tire rubber and rubber ash in a calcareous soil as alternatives to Zn fertilizers

USDA-ARS?s Scientific Manuscript database

Ground rubber contains 15-20 g Zn/kg but very low levels of Cd and could serve as an inexpensive byproduct Zn fertilizer. The aim of this investigation was to test the kinetics of Zn release in a soil treated with ground tire rubber and rubber ash compared with commercial Zn fertilizer and a labora...

Characterization of Formaldehyde Emissions from Tire Crumb Rubber in Small Environmental Chambers - 2

EPA Science Inventory

Concerns have been raised about the safety of recycled rubber tire crumbs used in synthetic turf fields and playgrounds in the United States. To support federal efforts to better characterize recycled tire-derived surface materials, dynamic small chamber tests were conducted at...

78 FR 9775 - Cooper Tire & Rubber Company, Receipt of Petition for Decision of Inconsequential Noncompliance

Federal Register 2010, 2011, 2012, 2013, 2014

2013-02-11

...: Cooper Tire & Rubber Company (Cooper),\\1\\ has determined that certain Cooper brand tires manufactured... brand standard load tires manufactured in Mexico by Cooper's affiliate, Corporaci[oacute]n de Occidente... Docket Management System (FDMS) Web site at http://www.regulations.gov/ . Follow the online instructions...

77 FR 71678 - The Goodyear Tire & Rubber Company, Receipt of Petition for Decision of Inconsequential...

Federal Register 2010, 2011, 2012, 2013, 2014

2012-12-03

...: The Goodyear Tire & Rubber Company (GOODYEAR),\\1\\ has determined that certain Goodyear brand tires... LT 275/65R18 brand tires manufactured between April 8, 2012, and May 12, 2012 at its plant in Gadsden.... Electronically: By logging onto the Federal Docket Management System (FDMS) Web site at http://www.regulations...

Detecting Waste Tire Sites Using Satellite Imagery

NASA Astrophysics Data System (ADS)

Quinlan, B.; Huybrechts, C.; Schmidt, C.; Skiles, J. W.

2005-12-01

Waste tire piles pose environmental threats in the form of toxic fires and potential insect habitat. Previous techniques used to locate tire piles have included California Highway Patrol aerial surveillance and location tips from stakeholders. The TIRe (Tire Identification from Reflectance) model was developed as part of a pilot-project funded by the California Integrated Waste Management Board (CIWMB), a division of the California Environmental Protection Agency, and executed at NASA Ames Research Center's DEVELOP Program during the summer of 2005. The goal of the pilot-project was to determine if high-resolution satellite imagery could be used to locate waste tire disposal sites. The TIRe model, built in Leica Geosystems' ERDAS Imagine Model Builder, was created to automate the process of isolating tires in satellite imagery in two land cover types found in California. The sole geospatial data input to the TIRe model was Space Imaging IKONOS imagery. Once the imagery was processed through the TIRe model, less than 1% of the original image remained, consisting only of dark pixels containing tires or spectrally similar features. The output, a binary image was overlain on top of the original image for visual interpretation. The TIRe model was successfully able to identify waste tire piles as small as 400 tires and will prove to be a valuable tool for the detection, monitoring and remediation of waste tire sites.

Liquefaction of ground tire rubber at low temperature.

PubMed

Cheng, Xiangyun; Song, Pan; Zhao, Xinyu; Peng, Zonglin; Wang, Shifeng

2018-01-01

Low-temperature liquefaction has been investigated as a novel method for recycling ground tire rubber (GTR) into liquid using an environmentally benign process. The liquefaction was carried out at different temperatures (140, 160 and 180 °C) over variable time ranges (2-24 h) by blending the GTR with aromatic oil in a range from 0 to 100 parts per hundred rubber (phr). The liquefied GTR was separated into sol (the soluble fraction of rubber which can be extracted with toluene) and gel fractions (the solid fraction obtained after extraction) to evaluate the reclaiming efficiency. It was discovered that the percentage of the sol fraction increased with time, swelling ratio and temperature. Liquefied rubber was obtained with a high sol fraction (68.34 wt%) at 140 °C. Simultaneously, separation of nano-sized carbon black from the rubber networks occurred. The separation of carbon black from the network is the result of significant damage to the cross-linked-network that occurs throughout the liquefaction process. During liquefaction, a competitive reaction between main chain scission and cross-link bond breakage takes place. Copyright © 2017 Elsevier Ltd. All rights reserved.

Recycled tire crumb rubber anodes for sustainable power production in microbial fuel cells

NASA Astrophysics Data System (ADS)

Wang, Heming; Davidson, Matthew; Zuo, Yi; Ren, Zhiyong

One of the greatest challenges facing microbial fuel cells (MFCs) in large scale applications is the high cost of electrode material. We demonstrate here that recycled tire crumb rubber coated with graphite paint can be used instead of fine carbon materials as the MFC anode. The tire particles showed satisfactory conductivity after 2-4 layers of coating. The specific surface area of the coated rubber was over an order of magnitude greater than similar sized graphite granules. Power production in single chamber tire-anode air-cathode MFCs reached a maximum power density of 421 mW m -2, with a coulombic efficiency (CE) of 25.1%. The control graphite granule MFC achieved higher power density (528 mW m -2) but lower CE (15.6%). The light weight of tire particle could reduce clogging and maintenance cost but posts challenges in conductive connection. The use of recycled material as the MFC anodes brings a new perspective to MFC design and application and carries significant economic and environmental benefit potentials.

Physical and chemical characterization of representative samples of recycled rubber from end-of-life tires.

PubMed

Re Depaolini, Andrea; Bianchi, Giancarlo; Fornai, Daniele; Cardelli, Angela; Badalassi, Marco; Cardelli, Camillo; Davoli, Enrico

2017-10-01

A large number of end-of-life tires (ELTs) were sampled and classified by type, age and origin to obtain recycled rubber samples representative of the materials placed on the Italian market. The selected recycled tire rubber samples were physically and chemically characterized and a chemometric approach was used to determine correlations. The polycyclic aromatic hydrocarbons (PAHs) content was correlated to the aromaticity index and a model was built to establish the H-Bay aromaticity index (H-Bay) from the PAH concentrations. ELT of different origin and age produced in non-European countries generally had higher PAH content and a higher H-Bay index. H-Bay values of all the samples were lower than the REACH limits and old tires had higher aromatic content than recent ones, possibly due to the replacement of aromatic oils in tire production. Copyright © 2017 The Authors. Published by Elsevier Ltd.. All rights reserved.

Investigation and Evaluation of Ground Tire Rubber in Hot Mix Asphalt

DOT National Transportation Integrated Search

1989-08-01

The purpose of this study, which is published in five volumes, was to identify and verify using all available state-of-the-art sources, how ground tire rubber can be utilized in asphalt concrete mixtures for pavement construction meeting standard qua...

Productivity of rubber-tired skidders in southern pine forests

Treesearch

R. Kluender; D. Lortz; W. McCoy; B. Stokes; J. Klepac

1997-01-01

Sixteen stands were harvested at intensities (proportion of basal area removed) ranging from 0.27 to 1.00. Logging contractors used one or two rubber-tired cable and/or grapple skidders. Harvested sites were similar in slope, tree size, and stand composition. Thirteen of the stands had even-aged structures while the other three were uneven-aged. Skidding time per cycle...

A multi-site recycled tire crumb rubber characterization study: recruitment strategy and field sampling approach

EPA Science Inventory

Recently, concerns have been raised by the public about the safety of tire crumb rubber infill used in synthetic turf fields. In response, the 2016 Federal Research Action Plan on Recycled Tire Crumb Used on Playing Fields and Playgrounds (FRAP) was developed to examine key envir...

Rubber Tire Dozer Operator. Open Pit Mining Job Training Series.

ERIC Educational Resources Information Center

British Columbia Dept. of Education, Victoria.

This training outline for rubber tire dozer operators, one in a series of eight outlines, is designed primarily for company training foremen or supervisors and for trainers to use as an industry-wide guideline for heavy equipment operator training in open pit mining in British Columbia. Intended as a guide for preparation of lesson plans both for…

Characterization of Exposure Potential during Activities on Synthetic Turf Fields with Recycled Tire Crumb Rubber Infill

EPA Science Inventory

The Federal Research Action Plan on Recycled Tire Crumb Used on Playing Fields and Playgrounds (FRAP), released in February 2016, is a multi-agency research plan in response to concerns over the use of tire crumb rubber as infill on synthetic turf fields. The FRAP outlines specif...

Fundamental understanding of the thermal degradation mechanisms of waste tires and their air pollutant generation in a N2 atmosphere.

PubMed

Kwon, Eilhann; Castaldi, Marco J

2009-08-01

The thermal decomposition of waste tires has been characterized via thermo-gravimetric analysis (TGA) tests, and significant mass loss has been observed between 300 and 500 degrees C. A series of gas chromatography-mass spectrometer (GC-MS) measurements, in which the instrument was coupled to a TGA unit, have been carried out to investigate the thermal degradation mechanisms as well as the air pollutant generation including volatile organic carbons (VOCs) and polycyclic aromatic hydrocarbons (PAHs) in a nitrogen atmosphere. In order to understand fundamental information on the thermal degradation mechanisms of waste tires, the main constituents of tires, poly-isoprene rubber (IR) and styrene butadiene rubber (SBR), have been studied under the same conditions. All of the experimental work indicated that the bond scission on each monomer of the main constituents of tires was followed by hydrogenation and gas phase reactions. This helped to clarify the independent pathways and species attributable to IR and SBR during the pyrolysis process. To extend that understanding to a more practical level, a flow-through reactor was used to test waste tire, SBR and IR samples in the temperature range of 500-800 degrees C at a heating rate of approximately 200 degrees C. Lastly, the formation of VOCs (approximately 1-50 PPMV/10 mg of sample) and PAHs (approximately 0.2-7 PPMV/10 mg of sample) was observed at relatively low temperatures compared to conventional fuels, and its quantified concentration was significantly high due to the chemical structure of SBR and IR. The measurement of chemicals released during pyrolysis suggests not only a methodology for reducing the air pollutants but also the feasibility of petrochemical recovery during thermal treatment.

Effects of preparation process on performance of rubber modified asphalt

NASA Astrophysics Data System (ADS)

Liu, Hanbing; Luo, Guobao; Wang, Xianqiang; Jiao, Yubo

2015-06-01

The rational utilization of waste rubber tire is essential for the environmental protection. Utilizing rubber particles to modify asphalt can not only improve asphalt performance, but also help the recycling of waste materials. Considering the effect of different preparation process parameters on the performance of rubber modified asphalt, this paper analyzes the effects of the shear temperature, shear time and shear rate on the performance of rubber modified asphalt, and provided a reference for its preparation.

Possibility of using waste tire composites reinforced with rice straw as construction materials.

PubMed

Yang, Han-Seung; Kim, Dae-Jun; Lee, Young-Kyu; Kim, Hyun-Joong; Jeon, Jin-Yong; Kang, Chun-Won

2004-10-01

Agricultural lignocellulosic fiber (rice straw)-waste tire particle composite boards were manufactured for use as insulation boards in construction, using the same method as that used in the wood-based panel industry. The manufacturing parameters were: a specific gravity of 0.8 and a rice straw content (10/90, 20/80 and 30/70 by wt.% of rice straw/waste tire particle). A commercial polyurethane adhesive for rubber was used as the composite binder. The water proof, water absorption and thickness swelling properties of the composite boards were better than those of wood particleboard. Furthermore, the flexibility and flexural properties of the composite boards were superior to those of other wood-based panel products. The composite boards also demonstrated good acoustical insulation, electrical insulation, anti-caustic and anti-rot properties. These boards can be used to prevent impact damage, are easily modifiable and are inexpensive. They are able to be used as a substitute for insulation boards and other flexural materials in construction.

Characteristics of styrene-butadiene rubber/silica/Nanoprene compounds for application in tire tread.

PubMed

Seo, Byeongho; Kang, Jonghyub; Jang, Sukhee; Kang, Yonggu; Kim, Wonho

2013-03-01

Nanoprene is made from chemically cross-linked rubber particles, and has many hydroxyl groups on the surface of the particles. It is speculated that the Nanoprene could reduce the silica-silica network formation by introducing hydrogen bonding between the silanol group of silica and the hydroxyl group of Nanoprene. In this study, the styrene-butadiene rubber (SBR)/silica compounds with two types of the Nanoprene (BM75OH, BM15OH) were evaluated and it could be well explained by the concept of the volume fraction of filler or the volume fraction of rubber. If the Nanoprene applied to the compound is considered as a kind of filler, the minimum torque values and bound rubber contents of the un-vulcanized compounds, the swelling ratio and the stress-strain relationship of the vulcanized compounds could be well explained by the volume fraction of filler (phi(F)). If Nanoprene is considered as a kind of rubber such as SBR, the properties such as peak tan delta, Payne effect, tan delta at 0 degrees C and 60 degrees C, and abrasion resistance could be well explained by the volume fraction of rubber (phi'(R)). However, the improvement of silica dispersion by addition of the Nanoprene particles in the compounds was not significant. The application of BM75OH as a polymer to the tread compound will be suitable for winter tires. In addition, the compound with BM15OH as an additive will be suitable as a tread compound for summer tires.

Pyrolysis kinetics behavior of solid tire wastes available in Bangladesh.

PubMed

Islam, M Rofiqul; Haniu, H; Fardoushi, J

2009-02-01

Pyrolysis kinetics of available bicycle/rickshaw, motorcycle and truck tire wastes in Bangladesh have been investigated thermogravimetrically in a nitrogen atmosphere at heating rates of 10 and 60 degrees C/min over a temperature range of 30-800 degrees C. The three tire wastes exhibited similar behaviors in that, when heating rate was increased, the initial reaction temperature decreased but the reaction range and reaction rate increased. The percentage of total weight loss was higher for truck tire waste and lower for bicycle/rickshaw tire waste. The pyrolysis of truck tire waste was found to be easier than that of bicycle/rickshaw and motorcycle tire wastes while it was comparatively more difficult for motorcycle tire waste. The overall rate equation for the three tire wastes has been modeled satisfactorily by one simplified equation from which the kinetic parameters of unreacted materials based on the Arrhenius form can be determined. The predicted rate equation compares fairly well with the measured TG and DTG data. DTA curves for all of the samples show that the degradation reactions are three main exotherms and one endotherm.

Promoting the use of crumb rubber concrete in developing countries.

PubMed

Batayneh, Malek K; Marie, Iqbal; Asi, Ibrahim

2008-11-01

The use of accumulated waste materials in third world countries is still in its early phases. It will take courage for contractors and others in the construction industry to recycle selected types of waste materials in the concrete mixes. This paper addresses the recycling of rubber tires accumulated every year in Jordan to be used in concrete mixes. The main objectives of this research were to provide more scientific evidence to support the use of legislation or incentive-based schemes to promote the reuse of accumulated waste tires. This research focused on using crumb tires as a replacement for a percentage of the local fine aggregates used in the concrete mixes in Jordan. Different concrete specimens were prepared and tested in terms of uniaxial compression and splitting tension. The main variable in the mixture was the volumetric percentage of crumb tires used in the mix. The test results showed that even though the compressive strength is reduced when using the crumb tires, it can meet the strength requirements of light weight concrete. In addition, test results and observations indicated that the addition of crumb rubber to the mix has a limited effect toward reducing the workability of the mixtures. The mechanical test results demonstrated that the tested specimens of the crumb rubber concrete remained relatively intact after failure compared to the conventional concrete specimens. It is also concluded that modified concrete would contribute to the disposal of the non-decaying scrap tires, since the amount being accumulated in third world countries is creating a challenge for proper disposal. Thus, obliging authorities to invest in facilitating the use of waste tires in concrete, a fundamental material to the booming construction industry in theses countries, serves two purposes.

Fate and effect of tire rubber ash nano-particles (RANPs) in cucumber.

PubMed

Moghaddasi, Sahar; Hossein Khoshgoftarmanesh, Amir; Karimzadeh, Fatholah; Chaney, Rufus

2015-05-01

There are growing interests on effects of nano-materials on living organisms including higher plants. No report is available on positive and negative effects of rubber ash nano-particles (RANPs) on edible plants. Recently, we reported the possibility of using waste tire rubber and rubber ash as zinc (Zn) fertilizer for plants. In this nutrient solution culture study, for the first time, root uptake and the effects of RANPs on growth and Zn, cadmium (Cd), and lead (Pb) concentration in cucumber was investigated. Various Zn levels (0, 1, 5, 25, 125mgL(-1)) were applied in the form of RANPs or ZnSO4. The root RANPs uptake was visualized by light (LA), scanning electron (SEM), and transmission electron microcopies (TEM). At all Zn levels, cucumber plants supplied with RANPs produced higher shoot and root biomass compared with those supplied with ZnSO4. In addition, the RANPs resulted in higher accumulation of Zn in cucumber tissues in comparison with ZnSO4; although phytotoxicity of Zn from ZnSO4 was greater than that from RANPs. Clear evidence of the RANPs penetration into the root cells was obtained by using SEM and TEM. Filaments of RANPs were also observed at the end of roots by LM and TEM. Further research is needed to clarify the fate of the RANPs in plant cells and their possible risks for food chain. Copyright © 2015 Elsevier Inc. All rights reserved.

Securing the future of natural rubber – an American tire and bio-energy platform from guayule

USDA-ARS?s Scientific Manuscript database

There is a high level of interest in alternative sources of natural rubber for the tire industry due to both the price and supply volatility of Hevea brasiliensis. The guayule plant (Parthenium argentatum) has served as a major source of domestic natural rubber in the early 20th century and is being...

The analysis of tire rubber traces collected after braking incidents using Pyrolysis-GasChromatography/Mass Spectrometry.

PubMed

Sarkissian, Garry

2007-09-01

Automobile tire marks can routinely be found at the scenes of crime, particularly hit-and-run accidents and are left on road surfaces because of sudden braking or the wheels spinning. The tire marks are left due to the friction between the tire rubber and the solid road surface, and do not always demonstrate the tire tread pattern. However, the tire mark will contain traces of the tire. In this study, Pyrolysis Gas Chromatography/Mass Spectrometry was used to analyze 12 tires from different manufacturer's and their traces collected after braking incidents. Tire marks were left on a conglomerate road surface with sudden braking. The samples were pyrolysed without removal of contaminant in a micro-furnace type pyrolyser. Quantitative and qualitative analysis were performed on all the samples. All 12 samples were distinguished from each other. Each of the tire traces were identified as coming from there original source.

Experimental Investigation of the Mechanical and Durability Properties of Crumb Rubber Concrete.

PubMed

Liu, Hanbing; Wang, Xianqiang; Jiao, Yubo; Sha, Tao

2016-03-07

Recycling waste tire rubber by incorporating it into concrete has become the preferred solution to dispose of waste tires. In this study, the effect of the volume content of crumb rubber and pretreatment methods on the performances of concrete was evaluated. Firstly, the fine aggregate and mixture were partly replaced by crumb rubber to produce crumb rubber concrete. Secondly, the mechanical and durability properties of crumb rubber concrete with different replacement forms and volume contents had been investigated. Finally, the crumb rubber after pretreatment by six modifiers was introduced into the concrete mixture. Corresponding tests were conducted to verify the effectiveness of pretreatment methods as compared to the concrete containing untreated crumb rubber. It was observed that the mechanical strength of crumb rubber concrete was reduced, while durability was improved with the increasing of crumb rubber content. 20% replacement of fine aggregate and 5% replacement of the total mixture exhibited acceptable properties for practical applications. In addition, the results indicated that the modifiers had a positive impact on the mechanical and durability properties of crumb rubber concrete. It avoided the disadvantage of crumb rubber concrete having lower strength and provides a reference for the production of modified crumb rubber concrete.

Experimental Investigation of the Mechanical and Durability Properties of Crumb Rubber Concrete

PubMed Central

Liu, Hanbing; Wang, Xianqiang; Jiao, Yubo; Sha, Tao

2016-01-01

Recycling waste tire rubber by incorporating it into concrete has become the preferred solution to dispose of waste tires. In this study, the effect of the volume content of crumb rubber and pretreatment methods on the performances of concrete was evaluated. Firstly, the fine aggregate and mixture were partly replaced by crumb rubber to produce crumb rubber concrete. Secondly, the mechanical and durability properties of crumb rubber concrete with different replacement forms and volume contents had been investigated. Finally, the crumb rubber after pretreatment by six modifiers was introduced into the concrete mixture. Corresponding tests were conducted to verify the effectiveness of pretreatment methods as compared to the concrete containing untreated crumb rubber. It was observed that the mechanical strength of crumb rubber concrete was reduced, while durability was improved with the increasing of crumb rubber content. 20% replacement of fine aggregate and 5% replacement of the total mixture exhibited acceptable properties for practical applications. In addition, the results indicated that the modifiers had a positive impact on the mechanical and durability properties of crumb rubber concrete. It avoided the disadvantage of crumb rubber concrete having lower strength and provides a reference for the production of modified crumb rubber concrete. PMID:28773298

Directions for material recovery of used tires and their use in the production of new products intended for the industry of civil construction and pavements

NASA Astrophysics Data System (ADS)

Bulei, C.; Todor, M. P.; Heput, T.; Kiss, I.

2018-01-01

The management of waste from used tires is one of the major principles of recycling and reuse, which involves encouraging a high level of material recovery components, preferably by recycling. Given the current pressure on natural resources on a global scale we must fully take into account the waste in a broader framework defined by the flow of raw materials and their sustainable use. Thus, the opportunity to use various waste from used tires as raw material in order to support economic activities becomes a priority. The recycling of raw materials from waste products and their use in new production processes for their material capitalization is becoming a sustainable approach. Used tire recycling, is the process of recycling waste tires that are no longer suitable for use on vehicles due to wear or irreparable damage. These tires are a problematic source of waste, due to the large volume produced, the durability of the tires, and the components in the tire that are ecologically problematic. Although tires are usually burnt, not recycled, efforts are continuing to find value. Tires can be recycled into, among other things, typically as crumb rubber modifier in recycled pavement. The paper presents aspects of the product resulting from crushing of used tires (powder), which can be used properly valued in the street furniture field or building materials containing rubber.

Mortality from cancer and other causes in an Italian cohort of male rubber tire workers.

PubMed

Pira, Enrico; Pelucchi, Claudio; Romano, Canzio; Manzari, Marco; Negri, Eva; La Vecchia, Carlo

2012-03-01

To investigate mortality among workers of an Italian rubber tire factory employed between 1954 and 2008. This cohort study included 6246 men, totaling 190,512 man-years of observation. Employment data were obtained from personnel records, whereas vital status and causes of death were ascertained from local authorities. We computed standardized mortality ratios (SMRs) using national and regional death certification rates. Mortality was significantly lower than expected for all cancers (SMR = 79) and all causes (SMR = 85). The SMRs were 99 for cancer of stomach, 78 for lung, 121 for urinary bladder, 116 for lymphoma, and 89 for leukemia, none being significant. Decreased mortality emerged for cancers of the oral cavity and pharynx (SMR = 45), esophagus (SMR = 29), colorectum (SMR = 71), liver (SMR = 57), and kidney (SMR = 33). This study shows no excess cancer risk among male rubber tire workers employed after 1954.

Experimental use of rubber-tire rollers as a means of improving density in asphalt overlays.

DOT National Transportation Integrated Search

1991-01-01

This study reports the results of comparative tests on sections of asphalt pavement rolled with conventional steel-wheel rollers and those rolled with a rubber tire roller added between the steel-wheel breakdown and steel wheel finish rollers. Nuclea...

26 CFR 48.4073-3 - Exemption of tread rubber used for recapping nonhighway tires.

Code of Federal Regulations, 2010 CFR

2010-04-01

... TREASURY (CONTINUED) MISCELLANEOUS EXCISE TAXES MANUFACTURERS AND RETAILERS EXCISE TAXES Motor Vehicles... person otherwise than in the recapping or retreading of tires of the type used on highway vehicles. In determining whether tread rubber is sold for a taxable or nontaxable use, the type of vehicle on which the...

Developing Specifications for Waste Glass, Municipal Waste Combustor Ash and Waste Tires as Highway Fill Materials (Continuation). Final Report. Volume 3. Waste Tires.

DOT National Transportation Integrated Search

1995-04-01

A two year study was conducted as a continuation project for the Florida Department of Transportation (FDOT) to evaluate Municipal Waste Combustor (MWC) ash, Waste Glass, and Waste Tires for use as general highway fill. Initial studies conducted at F...

Potential of scrap tire rubber as lightweight aggregate in flowable fill.

PubMed

Pierce, C E; Blackwell, M C

2003-01-01

Flowable fill is a self-leveling and self-compacting material that is rapidly gaining acceptance and application in construction, particularly in transportation and utility earthworks. When mixed with concrete sand, standard flowable fill produces a mass density ranging from 1.8 to 2.3 g/cm(3) (115-145 pcf). Scrap tires can be granulated to produce crumb rubber, which has a granular texture and ranges in size from very fine powder to coarse sand-sized particles. Due to its low specific gravity, crumb rubber can be considered a lightweight aggregate. This paper describes an experimental study on replacing sand with crumb rubber in flowable fill to produce a lightweight material. To assess the technical feasibility of using crumb rubber, the fluid- and hardened-state properties of nine flowable fill mixtures were measured. Mixture proportions were varied to investigate the effects of water-to-cement ratio and crumb rubber content on fill properties. Experimental results indicate that crumb rubber can be successfully used to produce a lightweight flowable fill (1.2-1.6 g/cm(3) [73-98 pcf]) with excavatable 28-day compressive strengths ranging from 269 to 1194 kPa (39-173 psi). Using a lightweight fill reduces the applied stress on underlying soils, thereby reducing the potential for bearing capacity failure and minimizing soil settlement. Based on these results, a crumb rubber-based flowable fill can be used in a substantial number of construction applications, such as bridge abutment fills, trench fills, and foundation support fills.

Ground tire rubber (GTR) as a component material in concrete mixtures for paving concrete, phase 2 : [summary].

DOT National Transportation Integrated Search

2015-02-01

Using ground tire rubber (GTR) in : concrete mixtures is a possible solution : to mitigating flexibility and thermal : expansion issues with high-strength : concrete pavements. Florida State : University researchers designed concrete : mixtures using...

Processing Satellite Imagery To Detect Waste Tire Piles

NASA Technical Reports Server (NTRS)

Skiles, Joseph; Schmidt, Cynthia; Wuinlan, Becky; Huybrechts, Catherine

2007-01-01

A methodology for processing commercially available satellite spectral imagery has been developed to enable identification and mapping of waste tire piles in California. The California Integrated Waste Management Board initiated the project and provided funding for the method s development. The methodology includes the use of a combination of previously commercially available image-processing and georeferencing software used to develop a model that specifically distinguishes between tire piles and other objects. The methodology reduces the time that must be spent to initially survey a region for tire sites, thereby increasing inspectors and managers time available for remediation of the sites. Remediation is needed because millions of used tires are discarded every year, waste tire piles pose fire hazards, and mosquitoes often breed in water trapped in tires. It should be possible to adapt the methodology to regions outside California by modifying some of the algorithms implemented in the software to account for geographic differences in spectral characteristics associated with terrain and climate. The task of identifying tire piles in satellite imagery is uniquely challenging because of their low reflectance levels: Tires tend to be spectrally confused with shadows and deep water, both of which reflect little light to satellite-borne imaging systems. In this methodology, the challenge is met, in part, by use of software that implements the Tire Identification from Reflectance (TIRe) model. The development of the TIRe model included incorporation of lessons learned in previous research on the detection and mapping of tire piles by use of manual/ visual and/or computational analysis of aerial and satellite imagery. The TIRe model is a computational model for identifying tire piles and discriminating between tire piles and other objects. The input to the TIRe model is the georeferenced but otherwise raw satellite spectral images of a geographic region to be surveyed

Rubber Reclamation

ERIC Educational Resources Information Center

Williams, Kathryn R.

2007-01-01

The safety and health hazards related to recycling of used rubber, due to the scarcity and high price of virgin rubber are reported. Various threats like stagnant water pools trapped in tires leading to diseases and ignited tires, which become very difficult to extinguish and generating smoke that is extremely detrimental to the environment, have…

Interactive effect of trivalent iron on activated sludge digestion and biofilm structure in attached growth reactor of waste tire rubber.

PubMed

Sharafat, Iqra; Saeed, Dania Khalid; Yasmin, Sumera; Imran, Asma; Zafar, Zargona; Hameed, Abdul; Ali, Naeem

2018-01-01

Waste tire rubber (WTR) has been introduced as an alternative, novel media for biofilm development in several experimental systems including attached growth bioreactors. In this context, four laboratory-scale static batch bioreactors containing WTR as a support material for biofilm development were run under anoxic condition for 90 days using waste activated sludge as an inoculum under the influence of different concentrations (2.5, 6.5, 8.5 mg/l) of trivalent ferric iron (Fe 3+ ). The data revealed that activated sludge with a Fe 3+ concentration of 8.5 mg/l supported the maximum bacterial biomass [4.73E + 10 CFU/ml cm 2 ]; besides, it removed 38% more Chemical oxygen demand compared to Fe 3+ free condition from the reactor. Biochemical testing and 16S rDNA phylogenetic analysis of WTR-derived biofilm communities further suggested the role of varying concentrations of Fe 3+ on the density and diversity of members of Enterobacteria(ceae), ammonium (AOB) and nitrite oxidizing bacteria. Furthermore, Fluorescent in situ hybridization with phylogenetic oligonucleotide probes and confocal laser scanning microscopy of WTR biofilms indicated a significant increase in density of eubacteria (3.00E + 01 to.05E + 02 cells/cm 2 ) and beta proteobacteria (8.10E + 01 to 1.42E + 02 cells/cm 2 ), respectively, with an increase in Fe 3+ concentration in the reactors, whereas, the cell density of gamma proteobacteria in biofilms decreased.

Influence of triallyl cyanurate as co-agent on gamma irradiation cured high density polyethylene/reclaimed tire rubber blend

NASA Astrophysics Data System (ADS)

Mali, Manoj N.; Arakh, Amar A.; Dubey, K. A.; Mhaske, S. T.

2017-02-01

Utilization of waste from tire industry as reclaimed tire rubber (RTR) by formation of blends with high density polyethylene (HDPE) is great area to be focused. Enhancement of properties by the addition of triallyl cyanurate (TAC) as a co-agent with 1%, 3% and 5% to blend of HDPE 50 wt% and RTR 50 wt% in presence of gamma irradiation curing were investigated. Specifically, mechanical and thermal properties were studied as a function of amount of TAC and gamma irradiation dose in range of 50-200 kGy. The resultant blends were evaluated for the values of impact strength, gel content, thermal stability, tensile properties, rheological properties and morphological properties with increasing irradiation dosage and TAC loading. The mechanical properties tensile strength, hardness, impact strength of blend containing 3% of TAC were substantially increased with increasing irradiation dosage up to 150 KGy. Rheological analysis has shown increase in viscosity with increase in TAC loading up to 3% and 150 KGy irradiation dosages. 3% loading of TAC lead to better set of properties with150 KGy gamma irradiation dosage.

40 CFR 721.10579 - Carbon black derived from the pyrolysis of rubber tire shreds (generic).

Code of Federal Regulations, 2014 CFR

2014-07-01

... 40 Protection of Environment 31 2014-07-01 2014-07-01 false Carbon black derived from the pyrolysis of rubber tire shreds (generic). 721.10579 Section 721.10579 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) TOXIC SUBSTANCES CONTROL ACT SIGNIFICANT NEW USES OF CHEMICAL SUBSTANCES Significant New Uses for Specific Chemical...

Experimental Investigation on Damping Property of Coarse Aggregate Replaced Rubber Concrete

NASA Astrophysics Data System (ADS)

Sugapriya, P.; Ramkrishnan, R.; Keerthana, G.; Saravanamurugan, S.

2018-02-01

Rubber has good damping and vibrational characteristics and can reduce cracking significantly due to its elastic nature. This property of rubber can be incorporated in concrete to control vibrations and create better pavements. Crumb Rubber on being dumped in landfills has serious repercussions and causes soil and land pollution. An innovative use of waste tires is shredding them into small pieces and using them as a replacement for coarse aggregate. Crumb rubber is obtained by chopping scrap tires, and in this study it was added in two different sets named SET 1 - Treated Crumb Rubber and concrete, and SET 2 - Treated Crumb rubber with Ultra Fine GGBS as admixture in concrete. Coarse aggregate replaces Rubber in each of the 2 SET’s in proportions of 5, 10, 15 and 20%. Properties like Compressive Strength, Young’s Modulus, Direct and Semi direct Ultrasonic Pulse Velocity, Sorptivity, Damping ratio and Frequency were found out. Deformation and mode shape were studied with modal analysis and static analysis by applying a uniform pressure corresponding to the highest compressive strength of the slab, using ANSYS.

Wireless Monitoring of Automobile Tires for Intelligent Tires

PubMed Central

Matsuzaki, Ryosuke; Todoroki, Akira

2008-01-01

This review discusses key technologies of intelligent tires focusing on sensors and wireless data transmission. Intelligent automobile tires, which monitor their pressure, deformation, wheel loading, friction, or tread wear, are expected to improve the reliability of tires and tire control systems. However, in installing sensors in a tire, many problems have to be considered, such as compatibility of the sensors with tire rubber, wireless transmission, and battery installments. As regards sensing, this review discusses indirect methods using existing sensors, such as that for wheel speed, and direct methods, such as surface acoustic wave sensors and piezoelectric sensors. For wireless transmission, passive wireless methods and energy harvesting are also discussed. PMID:27873979

Thermal and catalytic coprocessing of coal and waste materials

DOE Office of Scientific and Technical Information (OSTI.GOV)

Orr, E.C.; Tuntawiroon, W.; Ding, W.B.

1995-12-31

Coprocessing of coal with waste materials to produce liquid fuels with emphasis on finding reasonable reaction pathways and catalysts for such processing is presently the subject of intensive investigation. Polymer wastes such as polyethylene, polystyrene, polypropylene and used rubber tires are not naturally degraded over time. More than 22 million tons of plastic waste are annually discarded in landfills and over 75 percent of used rubber tires are similarly treated. In order to obtain distillate liquids or petroleum compatible refined products from coal, addition of hydrogen is necessary. A possible method for hydrogen addition is coprocessing of coal with polymericmore » waste materials since these latter materials contain hydrogen at levels much higher than are found in coal. The breakdown of waste rubber tires is interesting because the liquids derived may prove to be important as a coal dissolution and/or hydrogen donor solvent. Recently, Badger and coworkers reported that hydrogenated tire oils (hydrogenated in the presence of CoMo catalyst) were effective for the dissolution of coal. Studies on the coprocessing of coal and waste materials have only recently been done intensively. Limited data are available on reaction conditions and catalytic effects for processing coal mixed with post-consumer wastes. The purpose of the present study was to determine the effects of reaction temperature, pressure, catalysts, and mixture ratio on the coprocessing of coal and waste materials.« less

Water Treatment Residuals and Scrap Tire Rubber as Green Sorbents for Removal of Stormwater Metals.

PubMed

Deng, Yang; Morris, Ciapha; Rakshit, Sudipta; Landa, Edward; Punamiya, Pravin; Sarkar, Dibyendu

2016-06-01

Bench scale tests were performed to evaluate two recycled wastes, water treatment residuals (WTR) and scrap tire rubber (STR), for adsorption of selected metals from urban stormwater, and assess their release from used sorbents. Aluminum-WTR alone could rapidly and effectively remove Cu, Pb, and Zn, while STR alone continuously released Zn accompanied with Cu and Pb adsorption. Zn leaching from STR was significantly reduced in the presence of WTR. Very little metals released from used combined adsorbents in NaNO3 solution, and only part of them were extracted with EDTA (a strong chelating agent), suggesting that metal release is not a concern in a typical stormwater condition. A combination of WTR and STR is a new, effective method for mitigation of urban stormwater metals-WTR can inhibit the STR leaching, and STR improves the hydraulic permeability of WTR powders, a limiting factor for stormwater flow when WTR is used alone.

Experimental Investigations on the Pull-Out Behavior of Tire Strips Reinforced Sands

PubMed Central

Li, Li-Hua; Chen, Yan-Jun; Ferreira, Pedro Miguel Vaz; Liu, Yong; Xiao, Heng-Lin

2017-01-01

Waste tires have excellent mechanical performance and have been used as reinforcing material in geotechnical engineering; however, their interface properties are poorly understood. To further our knowledge, this paper examines the pull-out characteristics of waste tire strips in a compacted sand, together with uniaxial and biaxial geogrids also tested under the same conditions. The analysis of the results shows that the interlocking effect and pull-out resistance between the tire strip and the sand is very strong and significantly higher than that of the geogrids. In the early stages of the pull-out test, the resistance is mainly provided by the front portion of the embedded tire strips, as the pull-out test continues, more and more of the areas towards the end of the tire strips are mobilized, showing a progressive failure mechanism. The deformations are proportional to the frictional resistance between the tire-sand interface, and increase as the normal stresses increase. Tire strips of different wear intensities were tested and presented different pull-out resistances; however, the pull-out resistance mobilization patterns were generally similar. The pull-out resistance values obtained show that rubber reinforcement can provide much higher pull-out forces than the geogrid reinforcements tested here, showing that waste tires are an excellent alternative as a reinforcing system, regardless of the environmental advantages. PMID:28773069

Experimental Investigations on the Pull-Out Behavior of Tire Strips Reinforced Sands.

PubMed

Li, Li-Hua; Chen, Yan-Jun; Ferreira, Pedro Miguel Vaz; Liu, Yong; Xiao, Heng-Lin

2017-06-27

Waste tires have excellent mechanical performance and have been used as reinforcing material in geotechnical engineering; however, their interface properties are poorly understood. To further our knowledge, this paper examines the pull-out characteristics of waste tire strips in a compacted sand, together with uniaxial and biaxial geogrids also tested under the same conditions. The analysis of the results shows that the interlocking effect and pull-out resistance between the tire strip and the sand is very strong and significantly higher than that of the geogrids. In the early stages of the pull-out test, the resistance is mainly provided by the front portion of the embedded tire strips, as the pull-out test continues, more and more of the areas towards the end of the tire strips are mobilized, showing a progressive failure mechanism. The deformations are proportional to the frictional resistance between the tire-sand interface, and increase as the normal stresses increase. Tire strips of different wear intensities were tested and presented different pull-out resistances; however, the pull-out resistance mobilization patterns were generally similar. The pull-out resistance values obtained show that rubber reinforcement can provide much higher pull-out forces than the geogrid reinforcements tested here, showing that waste tires are an excellent alternative as a reinforcing system, regardless of the environmental advantages.

Properties of concrete with tire derived aggregate and crumb rubber as a lighthweight substitute for mineral aggregates in the concrete mix

NASA Astrophysics Data System (ADS)

Siringi, Gideon Momanyi

Scrap tires continue to be a nuisance to the environment and this research proposes one way of recycling them as a lightweight aggregate which can substitute for mineral aggregates in concrete. Aggregates derived from scrap tires are often referred to as Tire Derived Aggregate (TDA). First, the focus is how much mineral aggregate can be replaced by these waste tires and how the properties of concrete are affected with the introduction of rubber. This is being mindful of the fact that for a new material to be acceptable as an engineering material, its properties and behavior has to be well understood, the materials must perform properly and be acceptable to the regulating agencies. The role played by the quantity of TDA and Crumb Rubber replacing coarse aggregate and fine aggregate respectively as well as different treatment and additives in concrete on its properties are examined. Conventional concrete (without TDA) and concrete containing TDA are compared by examining their compressive strength based on ASTM C39, workability based on ASTM C143, Splitting Tensile Strength based on ASTM C496, Modulus of Rupture (flexural strength) based on ASTM C78 and Bond strength of concrete developed with reinforcing steel based on ASTM C234.Through stress-strain plots, the rubberized concrete is compared in terms of change in ductility, toughness and Elastic Modulus. Results indicate that while replacement of mineral aggregates with TDA results in reduction in compressive strength, this may be mitigated by addition of silica fume or using a smaller size of TDA to obtain the desired strength. The greatest benefit of using TDA is in the development of a higher ductile product with lower density while utilizing recycled TDA. From the results, it is observed that 7-10% of weight of mineral aggregates can be replaced by an equal volume of TDA to produce concrete with compressive strength of up to 4000 psi (27.5 MPa). Rubberized concrete would have higher ductility and toughness with

Processing methods, characteristics and adsorption behavior of tire derived carbons: a review.

PubMed

Saleh, Tawfik A; Gupta, Vinod Kumar

2014-09-01

The remarkable increase in the number of vehicles worldwide; and the lack of both technical and economical mechanisms of disposal make waste tires to be a serious source of pollution. One potential recycling process is pyrolysis followed by chemical activation process to produce porous activated carbons. Many researchers have recently proved the capability of such carbons as adsorbents to remove various types of pollutants including organic and inorganic species. This review attempts to compile relevant knowledge about the production methods of carbon from waste rubber tires. The effects of various process parameters including temperature and heating rate, on the pyrolysis stage; activation temperature and time, activation agent and activating gas are reviewed. This review highlights the use of waste-tires derived carbon to remove various types of pollutants like heavy metals, dye, pesticides and others from aqueous media. Copyright © 2014 Elsevier B.V. All rights reserved.

Performance of sand and shredded rubber tire mixture as a natural base isolator for earthquake protection

NASA Astrophysics Data System (ADS)

Bandyopadhyay, Srijit; Sengupta, Aniruddha; Reddy, G. R.

2015-12-01

The performance of a well-designed layer of sand, and composites like layer of sand mixed with shredded rubber tire (RSM) as low cost base isolators, is studied in shake table tests in the laboratory. The building foundation is modeled by a 200 mm by 200 mm and 40 mm thick rigid plexi-glass block. The block is placed in the middle of a 1m by 1m tank filled with sand. The selected base isolator is placed between the block and the sand foundation. Accelerometers are placed on top of the footing and foundation sand layer. The displacement of the footing is also measured by LVDT. The whole setup is mounted on a shake table and subjected to sinusoidal motions with varying amplitude and frequency. Sand is found to be effective only at very high amplitude (> 0.65 g) of motions. The performance of a composite consisting of sand and 50% shredded rubber tire placed under the footing is found to be most promising as a low-cost effective base isolator.

26 CFR 48.4071-4 - Original equipment tires on imported articles.

Code of Federal Regulations, 2010 CFR

2010-04-01

... 26 Internal Revenue 16 2010-04-01 2010-04-01 true Original equipment tires on imported articles..., Tread Rubber, and Taxable Fuel Tires, Tubes, and Tread Rubber § 48.4071-4 Original equipment tires on... than bicycle tires and inner tubes) that are original equipment for an imported article upon which no...

The optimum content of rubber ash in concrete: flexural strength

NASA Astrophysics Data System (ADS)

Senin, M. S.; Shahidan, S.; Shamsuddin, S. M.; Ariffin, S. F. A.; Othman, N. H.; Rahman, R.; Khalid, F. S.; Nazri, F. M.

2017-11-01

Discarded scrap tyres have become one of the major environmental problems nowadays. Several studies have been carried out to reuse waste tires as an additive or sand replacement in concrete with appropriate percentages of tire rubber, called as rubberized concrete to solve this problem. The main objectives of this study are to investigate the flexural strength performance of concrete when adding the rubber ash and also to analyse the optimum content of rubber ash in concrete prisms. The performance total of 30 number of concrete prisms in size of 100mm x 100mm x 500 mm were investigated, by partially replacement of rubber ash with percentage of 0%, 3%, 5%, 7% and 9% from the volume of the sand. The flexural strength is increased when percentage of rubber ash is added 3% from control concrete prism, RA 0 for both concrete prism age, 7 days and 28 days with value 1.21% and 0.976% respectively. However, for RA 5, RA 7 and RA 9, the flexural strength was decreased compared to the control for both age, 7 days and 28 days. In conclusion, 3% is the optimum content of rubber ash in concrete prism for both concrete age

Spring Tire

NASA Technical Reports Server (NTRS)

Asnani, Vivake M.; Benzing, Jim; Kish, Jim C.

2011-01-01

The spring tire is made from helical springs, requires no air or rubber, and consumes nearly zero energy. The tire design provides greater traction in sandy and/or rocky soil, can operate in microgravity and under harsh conditions (vastly varying temperatures), and is non-pneumatic. Like any tire, the spring tire is approximately a toroidal-shaped object intended to be mounted on a transportation wheel. Its basic function is also similar to a traditional tire, in that the spring tire contours to the surface on which it is driven to facilitate traction, and to reduce the transmission of vibration to the vehicle. The essential difference between other tires and the spring tire is the use of helical springs to support and/or distribute load. They are coiled wires that deform elastically under load with little energy loss.

Carbon materials derived from waste tires as high-performance anodes in microbial fuel cells.

PubMed

Chen, Wei; Feng, Huajun; Shen, Dongsheng; Jia, Yufeng; Li, Na; Ying, Xianbin; Chen, Ting; Zhou, Yuyang; Guo, Jiayun; Zhou, Mengjiao

2018-03-15

In this study, carbonized waste tires were directly used as a high-performance anode material in microbial fuel cells (MFCs). The effect of the pyrolysis temperature used for waste tire carbonization on the current output performance was investigated to determine the optimal pyrolysis temperature. Thermal gravimetric analysis/differential scanning calorimetry showed that tire carbonization started at 200°C and ended at about 500°C; the weight loss was about 64%. When used in an MFC, the electrode obtained from waste tires carbonized at 800°C gave a current density of 23.1±1.4Am -2 , which is much higher than that achieved with traditional graphite felt anodes (5.5±0.1Am -2 ). The results of this study will be useful in optimizing the design of carbonized waste tire anodes for enhancing MFC performances and will alleviate the environmental problems caused by waste tires. Copyright © 2017 Elsevier B.V. All rights reserved.

Exposure to aged crumb rubber reduces survival time during a stress test in earthworms (Eisenia fetida).

PubMed

Pochron, Sharon; Nikakis, Jacqueline; Illuzzi, Kyra; Baatz, Andrea; Demirciyan, Loriana; Dhillon, Amritjot; Gaylor, Thomas; Manganaro, Alexa; Maritato, Nicholas; Moawad, Michael; Singh, Rajwinder; Tucker, Clara; Vaughan, Daniel

2018-04-01

Solid waste management struggles with the sustainable disposal of used tires. One solution involves shredding used tires into crumb rubber and using the material as infill for artificial turf. However, crumb rubber contains hydrocarbons, organic compounds, and heavy metals, and it travels into the environment. Earthworms living in soil contaminated with virgin crumb rubber gained 14% less body weight than did earthworms living in uncontaminated soil, but the impact of aged crumb rubber on the earthworms is unknown. Since many athletic fields contain aged crumb rubber, we compared the body weight, survivorship, and longevity in heat and light stress for earthworms living in clean topsoil to those living in topsoil contaminated with aged crumb rubber. We also characterized levels of metals, nutrients, and micronutrients of both soil treatments and compared those to published values for soil contaminated with virgin crumb rubber. Consistent with earlier research, we found that contaminated soil did not inhibit microbial respiration rates. Aged crumb rubber, like new crumb rubber, had high levels of zinc. However, while exposure to aged crumb rubber did not reduce earthworm body weight as did exposure to new crumb rubber, exposure to aged crumb rubber reduced earthworm survival time during a stress test by a statistically significant 38 min (16.2%) relative to the survival time for worms that had lived in clean soil. Aged crumb rubber and new crumb rubber appear to pose similar toxic risks to earthworms. This study suggests an environmental cost associated with the current tire-recycling solution.

Biotechnological possibilities for waste tyre-rubber treatment.

PubMed

Holst, O; Stenberg, B; Christiansson, M

1998-01-01

Every year large amounts of spent rubber material, mainly from rubber tyres, are discarded. Of the annual total global production of rubber material, which amounts to 16-17 million tonnes, approximately 65% is used for the production of tyres. About 250 millions spent car tyres are generated yearly in USA only. This huge amount of waste rubber material is an environmental problem of great concern. Various ways to remediate the problem have been proposed. Among these are road fillings and combustion in kilns. Spent tyres, however, comprise valuable material that could be recycled if a proper technique can be developed. One way of recycling old tyres is to blend ground spent rubber with virgin material followed by vulcanization. The main obstacle to this recycling is bad adhesion between the crumb and matrix of virgin rubber material due to little formation of interfacial sulphur crosslinks. Micro-organisms able to break sulphur-sulphur and sulphur-carbon bonds can be used to devulcanize waste rubber in order to make polymer chains on the surface more flexible and facilitate increased binding upon vulcanization. Several species belonging to both Bacteria and Archaea have this ability. Mainly sulphur oxidizing species, such as different species of the genus Thiobacillus and thermoacidophiles of the order of Sulfolobales, have been studied in this context. The present paper will give a background to the problem and an overview of the biotechnological possibilities for solutions of waste rubber as an environmental problem, focusing on microbial desulphurization.

Biopurification of industrial waste gas from rubber regeneration.

PubMed

Sun, Peishi; Yang, Xianwan; Huang, Ruohua; Bin, Huang; Zheng, Sunsheng; Wei, Zaishan; Xu, Xiaoyi; Lu, Jilai; Sun, Xing; Chen, Liuxin

2004-12-01

By using the biopurifying technology, the organic waste gas in low concentrations emitted from the rubber-regeneration process was purified in this research. The result of the 100-day continuous running test of the industrial test device indicated that the purification efficiency of toluene in the rubber-regeneration waste gas could be maintained at about 90% for a long period of time and the treated waste gas could meet the China National Emission Standard. The cost of waste gas biotreatment was about 0.12-0.14% of rubber-regeneration production value of the factory. The biopurifying technology of waste gas displayed its excellent technical advancement and economic rationale. The following industrialized device was run continuously and passed the examination and acceptance by the local EPA.

Federal Research Action Plan on Recycled Tire Crumb Used ...

EPA Pesticide Factsheets

Over the past several years, parents, athletes, schools, and communities have raised concerns about the safety of recycled tire crumb rubber used as infill for playing fields and playgrounds in the United States. The public has expressed concerns that the use of these fields could potentially be related to certain health effects. Studies to date have not shown an elevated health risk from playing on fields with tire crumb rubber, but these studies have limitations and do not comprehensively evaluate the concerns about health risks from exposure to tire crumb rubber. This status report provides a summary of activities to date, including: (1) stakeholder outreach, (2) the tire crumb rubber manufacturing industry, (3) the final peer-reviewed Literature Review/Gaps Analysis (LRGA), (4) progress on the research activities, and (5) next steps and a timeline for completion of the final report. The status report does not include research findings.

26 CFR 48.4073-1 - Exemption of tires of certain sizes.

Code of Federal Regulations, 2012 CFR

2012-04-01

...) MISCELLANEOUS EXCISE TAXES MANUFACTURERS AND RETAILERS EXCISE TAXES Motor Vehicles, Tires, Tubes, Tread Rubber... tax does not apply to sales of tires of all-rubber construction (whether hollow center or solid) if...

26 CFR 48.4073-1 - Exemption of tires of certain sizes.

Code of Federal Regulations, 2013 CFR

2013-04-01

...) MISCELLANEOUS EXCISE TAXES MANUFACTURERS AND RETAILERS EXCISE TAXES Motor Vehicles, Tires, Tubes, Tread Rubber... tax does not apply to sales of tires of all-rubber construction (whether hollow center or solid) if...

26 CFR 48.4073-1 - Exemption of tires of certain sizes.

Code of Federal Regulations, 2010 CFR

2010-04-01

...) MISCELLANEOUS EXCISE TAXES MANUFACTURERS AND RETAILERS EXCISE TAXES Motor Vehicles, Tires, Tubes, Tread Rubber... tax does not apply to sales of tires of all-rubber construction (whether hollow center or solid) if...

26 CFR 48.4073-1 - Exemption of tires of certain sizes.

Code of Federal Regulations, 2011 CFR

2011-04-01

...) MISCELLANEOUS EXCISE TAXES MANUFACTURERS AND RETAILERS EXCISE TAXES Motor Vehicles, Tires, Tubes, Tread Rubber... tax does not apply to sales of tires of all-rubber construction (whether hollow center or solid) if...

Acute toxicity of leachates of tire wear material to Daphnia magna--variability and toxic components.

PubMed

Wik, Anna; Dave, Göran

2006-09-01

Large amounts of tire rubber are deposited along the roads due to tread wear. Several compounds may leach from the rubber and cause toxicity to aquatic organisms. To investigate the toxic effects of tire wear material from different tires, rubber was abraded from the treads of twenty-five tires. Leachates were prepared by allowing the rubber to equilibrate with dilution water at 44 degrees C for 72 h. Then the rubber was filtered from the leachates, and test organisms (Daphnia magna) were added. Forty-eight hour EC50s ranged from 0.5 to >10.0 g l(-1). The toxicity identification evaluation (TIE) indicated that non-polar organic compounds caused most of the toxicity. UV exposure of the filtered tire leachates caused no significant increase in toxicity. However, when tested as unfiltered leachates (the rubber was not filtered from the leachates before addition of D. magna) photo-enhanced toxicity was considerable for some tires, which means that test procedures are important when testing tire leachates for aquatic (photo) toxicity. The acute toxicity of tire wear for Daphnia magna was found to be <40 times a predicted environmental concentration based on reports on the concentration of a tire component found in environmental samples, which emphasizes the need for a more extensive risk assessment of tire wear for the environment.

Exposure to rubber fume and rubber process dust in the general rubber goods, tyre manufacturing and retread industries.

PubMed

Dost, A A; Redman, D; Cox, G

2000-08-01

This study assesses the current patterns and levels of exposure to rubber fume and rubber process dust in the British rubber industry and compares and contrasts the data obtained from the general rubber goods (GRG), retread tire (RT) and new tire (NT) sectors. A total of 179 rubber companies were visited and data were obtained from 52 general rubber goods, 29 retread tire and 7 new tire manufacturers. The survey was conducted using a questionnaire and included a walk-through inspection of the workplace to assess the extent of use of control measures and the nature of work practices being employed. The most recent (predominantly 1995-97) exposure monitoring data for rubber fume and rubber process dust were obtained from these companies; no additional sampling was conducted for the purpose of this study. In addition to the assessment of exposure data, evaluation of occupational hygiene reports for the quality of information and advice was also carried out.A comparison of the median exposures for processes showed that the order of exposure to rubber fume (E, in mg m(-3)) is: E(moulding) (0.40) approximately E(extrusion) (0.33)>E(milling) (0.18) for GRG; E(press) (0. 32)>E(extrusion) (0.19)>E(autoclave) (0.10) for RT; and E(press) (0. 22) approximately E(all other) (0.22) for NT. The order of exposure to rubber fume between sectors was E(GRG) (0.40)>E(RT) (0.32)>E(NT) (0.22). Median exposures to rubber process dust in the GRG was E(weighing) (4.2)>E(mixing) (1.2) approximately E(milling) (0.8) approximately E(extrusion) (0.8) and no significant difference (P=0. 31) between GRG and NT sectors. The findings compare well with the study carried out in the Netherlands [Kromhout et al. (1994), Annals of Occupational Hygiene 38(1), 3-22], and it is suggested that the factors governing the significant differences noted between the three sectors relate principally to the production and task functions and also to the extent of controls employed. Evaluation of occupational

Amino acid modifiers in guayule rubber compounds

USDA-ARS?s Scientific Manuscript database

Tire producers are increasingly interested in biobased materials, including rubber but also as compounding chemicals. An alternative natural rubber for tire use is produced by guayule, a woody desert shrub native to North America. Alternative compounding chemicals include naturally-occurring amino a...

WASTE TIRES ON THE ISLAND OF DOMINICA: SURVEY AND SOLUTIONS

EPA Science Inventory

Phase I of LFL-Dominica was highly successful, resulting in a completed national tire inventory and Material Flow Analysis, a waste tire feasibility study, expansion of the project to include organic gardens, identification and screening of three sites for potential LFL implem...

Improving rubber concrete by waste organic sulfur compounds.

PubMed

Chou, Liang-Hisng; Lin, Chun-Nan; Lu, Chun-Ku; Lee, Cheng-Haw; Lee, Maw-Tien

2010-01-01

In this study, the use of crumb tyres as additives to concrete was investigated. For some time, researchers have been studying the physical properties of concrete to determine why the inclusion of rubber particles causes the concrete to degrade. Several methods have been developed to improve the bonding between rubber particles and cement hydration products (C-S-H) with the hope of creating a product with an improvement in mechanical strength. In this study, the crumb tyres were treated with waste organic sulfur compounds from a petroleum refining factory in order to modify their surface properties. Organic sulfur compounds with amphiphilic properties can enhance the hydrophilic properties of the rubber and increase the intermolecular interaction forces between rubber and C-S-H. In the present study, a colloid probe of C-S-H was prepared to measure these intermolecular interaction forces by utilizing an atomic force microscope. Experimental results showed that rubber particles treated with waste organic sulfur compounds became more hydrophilic. In addition, the intermolecular interaction forces increased with the adsorption of waste organic sulfur compounds on the surface of the rubber particles. The compressive, tensile and flexural strengths of concrete samples that included rubber particles treated with organic sulfur compound also increased significantly.

Novel Acid Catalysts from Waste-Tire-Derived Carbon: Application in Waste-to-Biofuel Conversion

DOE PAGES

Hood, Zachary D.; Adhikari, Shiba P.; Li, Yunchao; ...

2017-06-21

Many inexpensive biofuel feedstocks, including those containing free fatty acids (FFAs) in high concentrations, are typically disposed of as waste due to our inability to efficiently convert them into usable biofuels. Here we demonstrate that carbon derived from waste tires could be functionalized with sulfonic acid (-SO 3H) to effectively catalyze the esterification of oleic acid or a mixture of fatty acids to usable biofuels. Waste tires were converted to hard carbon, then functionalized with catalytically active -SO 3H groups on the surface through an environmentally benign process that involved the sequential treatment with L-cysteine, dithiothreitol, and H 2O 2.more » In conclusion, when benchmarked against the same waste-tire derived carbon material treated with concentrated sulfuric acid at 150 °C, similar catalytic activity was observed. Both catalysts could also effectively convert oleic acid or a mixture of fatty acids and soybean oil to usable biofuels at 65 °C and 1 atm without leaching of the catalytic sites.« less

Using shredded waste tires as a lightweight fill material for road subgrades : summary report

DOT National Transportation Integrated Search

1994-04-01

Waste tires have been a disposal problem in the past and are continuing to accumulate throughout the U.S. today. Using shredded waste tires as a lightweight fill material for road construction has proven to be a beneficial use of this waste product. ...

Using shredded waste tires as a lightweight fill material for road subgrades. Summary report

DOT National Transportation Integrated Search

1994-04-01

Waste tires have been a disposal problem in the past and are continuing to accumulate throughout the U.S. today. Using shredded waste tires as a lightweight fill material for road construction has proven to be a beneficial use of this waste product. ...

Effect of polyfunctional monomers on properties of radiation crosslinked EPDM/waste tire dust blend

NASA Astrophysics Data System (ADS)

Yasin, Tariq; Khan, Sajid; Nho, Young-Chang; Ahmad, Rashid

2012-04-01

In this study, waste tire dust is recycled as filler and blended with ethylene-propylene diene monomer (EPDM) rubber. Three different polyfuntional monomers (PFMs) are incorporated into the standard formulation and irradiated under electron beam at different doses up to maximum of 100 kGy. The combined effects of PFMs and absorbed dose on the physical properties of EPDM/WTD blend are measured and compared with sulfur crosslinked formulation. Thermogravimetric analysis showed that radiation developed better crosslinked network with higher thermal stability than sulfur crosslinked structure. The physical properties of radiation crosslinked blend are similar to the sulfur crosslinked blend. The absence of toxic chemicals/additives in radiation crosslinked blends made them an ideal candidate for many applications such as roof sealing sheets, water retention pond, playground mat, sealing profile for windows etc.

Mechanistic study of the rubber-brass adhesion interphase

NASA Astrophysics Data System (ADS)

Ashirgade, Akshay

Brass-plated steel tire cords form an essential strengthening component of a radial automobile tire. Adhesion between rubber compound and brass-plated steel tire cord is crucial in governing the overall performance of tires. The rubber-brass interfacial adhesion is influenced by the chemical composition and thickness of the interfacial layer. It has been shown that the interfacial layer consists mainly of sulfides and oxides of copper and zinc. This thesis discusses the effect of changes in the chemical composition and the structure of the interfacial layers due to addition of adhesion promoter resins. Grazing incidence X-Ray Diffraction (GIXRD) experiments were run on sulfidized polished brass coupons previously bonded to six experimental rubber compounds. It was confirmed that heat and humidity conditions lead to physical and chemical changes of the rubber-steel tire cord interfacial layer, closely related to the degree of rubber-brass adhesion. Morphological transformation of the interfacial layer led to loss of adhesion after aging. The adhesion promoter resins inhibit unfavorable morphological changes in the interfacial layer thus stabilizing it during aging and prolonging failure. Tire cord adhesion tests illustrated that the one-component resins improved adhesion after aging using a rubber compound with lower cobalt loading. Based on the acquired diffraction profiles, these resins were also found to impede crystallization of the sulfide layer after aging leading to improved adhesion. Secondary Ion Mass Spectrometry (SIMS) depth profiles, SEM micrographs and AFM images strongly corroborated the findings from GIXRD. FTIR was utilized in a novel way to understand the degradation mechanism due to aging. A model for rubber and interfacial layer degradation is proposed to illustrate the effect of aging and the one-component resins. This interfacial analysis adds valuable new information to our understanding of the complex nature of the rubber-brass bonding

A review on the suitability of rubberized concrete for concrete bridge decks

NASA Astrophysics Data System (ADS)

Syamir Senin, Mohamad; Shahidan, Shahiron; Radziah Abdullah, Siti; Anting Guntor, Nickholas; Syazani Leman, Alif

2017-11-01

Road authorities manage a large population of ageing bridges, a substantial number of which fail to meet the current requirements either due to deterioration and other structural deficiencies or as a result of the escalating demands imposed by increased traffic. This problem is related to the dynamic load from vehicles. This problem can be solved by producing a type of concrete that can reduce the amplitude of oscillation or vibration such as rubberized concrete. Green construction has been a very important aspect in concrete production field in the last decade. One of the most problematic waste materials is scrap tires. The use of scrap tires in civil engineering is increasing by producing rubberized concrete. Rubberized concrete is a type of concrete that is mixed with rubber. The purpose of this review is to justify the suitability of rubberized concrete for concrete bridge decks. Several parameters named physical, chemical and mechanical properties were measured to ensure the suitability of rubberized concrete for concrete bridge decks. Rubberized concrete has similar workability to normal concrete. The rubber reduced the density and compressive strength of the concrete while increased the flexural strength, water absorption and damping ratio. The used of rubber in concrete beyond 20% is not recommended due to decreasing in compressive strength. Rubberized concrete recommended to be used in circumstances where vibration damping was required such as in bridge construction as shock-wave absorber.

A comparative study of ground tire rubber devulcanization using twin screw extruder and internal mixer

NASA Astrophysics Data System (ADS)

Ujianto, O.; Putri, D. B.; Jayatin; AWinarto, D.

2017-07-01

Devulcanization of ground tire rubber (GTR) was done using twin screw extruder (TSE) and internal mixer (IM). Processing parameters were varied to analyze its effect on gel content. Fourier Transform Infrared Spectroscopy (FTIR) analysis was performed as qualitative technique to confirm structural change. The devulcanized rubbers with the least gel content percentage produced in both TSE and IM were then used as filler in natural rubber (NR)/coconut coir (CC) composite preparation. Effects of gel content percentage on NR/CC composite tensile strength and elongation at break were analyzed. The results show that the gel content decreased by 41% for sample processed in TSE and 50% in IM compared to control sample. Overall, the devulcanization is influenced by high energy generated by thermal or thermo-mechanical process. FTIR spectra show chemically structural changes of GTR as C=C, CH2, CH3 with higher intensity for IM sample than its counterpart indicated devulcanization. The replacement of GTR to DGTR on NR/CC/GTR composites provided less network structures and resulted better tensile strength and elongation at break.

A Tire Gasification Senior Design Project That Integrates Laboratory Experiments and Computer Simulation

ERIC Educational Resources Information Center

Weiss, Brian; Castaldi, Marco J.

2006-01-01

A reactor to convert waste rubber tires to useful products such as CO and H2, was investigated in a university undergraduate design project. The student worked individually with mentorship from a faculty professor who aided the student with professional critique. The student was able to research the background of the field and conceive of a novel…

Crumb waste tire rubber surface modification by plasma polymerization of ethanol and its application on oil-well cement

NASA Astrophysics Data System (ADS)

Xiaowei, Cheng; Sheng, Huang; Xiaoyang, Guo; Wenhui, Duan

2017-07-01

Crumb waste tire rubber (WTR) was pretreated by oxygen low temperature plasma (LTP) and modified by LTP polymerization process of ethanol monomer to improve the adhesion property with oil-well cement matrix and the mechanical properties of cement. The surface properties of modified crumb WTR and the mechanical properties and structures of modified oil-well cement were investigated by means of contact angle measurement, dispersion test, attenuated total reflection Fourier transform infrared (ATR-FTIR) spectroscopy, X-ray photoelectron spectroscopy (XPS), mechanics performance tests, permeability test and scanning electron microscopy (SEM). It was demonstrated that LTP treatment changed both the surface composition and roughness. The contact angle of pretreated crumb WTR dramatically fell from 122° to 34°, and sample with ethanol LPT polymer film decreased even further to 11°. The ATR-FTIR and XPS analysis results demonstrated that hydrophilic groups, such as -COOH, C-OH, and -CHO, were introduced on the WTR surface. The oxygen atomic percent increased from 8.11% to 14.50% and 24.83%. The mechanical properties, porosity and permeability of raw cement were compared to samples modified by untreated crumb WTR, pretreated crumb WTR and ethanol LTP polymerization treated crumb WTR. It was found that after 28 days, the compressive strength of the samples with the untreated crumb WTR decreased to 80% with respect to raw cement. The tensile strength and flexural strength also had a slight reduction compared with the raw cement. On the contrary, after 28 days, the tensile strength of cement modified by LTP polymerization treated WTR increased 11.03% and 13.36%, and the flexural strength increased 9.65% and 7.31%, respectively. A decrease in the compressive strength also occurred but was inconspicuous. A tight interface bonding for ethanol LTP polymerization treated WTR with cement matrix was observed via an SEM image.

Studless Winter Tires

NASA Technical Reports Server (NTRS)

1976-01-01

Goodyear Tire and Rubber Company developed a material for Johnson Space Center used as parachute shrouds to soft land the Vikings through the tenuous Martian atmosphere and has been adapted to new radial tire five times stronger than steel. Fiber has a chain-like molecular structure that gives it incredible strength in proportion to its weight. Material is expected to increase tread life by 10,000 miles.

Dynamic mechanical analysis of waste tyre rubber filled brake friction composite materials

NASA Astrophysics Data System (ADS)

Rathi, Mukesh Kumar; Singh, Tej; Chauhan, Ranchan

2018-05-01

In this research work, the dynamic mechanical properties of waste tyre rubber filled friction composites were studied. Four friction composites with varying amount of waste rubber (0, 4, 8, 12 wt.%) and barium sulphate (38, 42, 46, 50 wt.%) were designed and fabricated as per industrial norms. Dynamic mechanical analysis has been carried out to characterize the storage modulus, loss modulus and damping factor of the fabricated friction composite. Experimental results indicated that storage modulus decreases with increasing waste rubber content up to particular loading (4 wt.%), and after that it increases with further loading. The loss modulus of the composites increases steadily with increasing waste rubber content whereas, damping factor remain maximum for 12 wt.% waste rubber filled friction composites.

Interaggregate Interaction in Filled Rubber

DTIC Science & Technology

1989-01-01

from a black masterbatch (Carbomix 1848 from the Copolymer Rubber and Chemical Corporation). The masterbatch was unmilled (SBR-83-0), passed 5 times...Vanderbilt Company) 3 97% 1,2-polybutadiene (Firestone Tire and Rubber Company) 4 Carbomix 1848 Masterbatch (Copolymer Rubber and Chemical Corporation) 14

Tire Recycling

NASA Technical Reports Server (NTRS)

1997-01-01

Cryopolymers, Inc. tapped NASA expertise to improve a process for recycling vehicle tires by converting shredded rubber into products that can be used in asphalt road beds, new tires, hoses, and other products. In conjunction with the Southern Technology Applications Center and Stennis Space Center, NASA expertise in cryogenic fuel-handling needed for launch vehicle and spacecraft operations was called upon to improve the recycling concept. Stennis advised Cryopolymers on the type of equipment required, as well as steps to reduce the amount of liquid nitrogen used in the process. They also guided the company to use more efficient ways to control system hardware. It is estimated that more than 300 million tires nationwide are produced per year. Cryopolymers expects to reach a production rate of 5,000 tires recycled per day.

Investigation on dynamic performance of concrete column crumb rubber steel and fiber concrete

NASA Astrophysics Data System (ADS)

Siti Nurul Nureda, M. Z.; Mariyana, A. K.; Khiyon, M. Iqbal; Rahman, M. S. Abdul; Nurizaty, Z.

2017-11-01

In general the Normal Concrete (NC) are by quasi-brittle failure, where, the nearly complete loss of loading capacity, once failure is initiated especially under dynamic loadings. The significance of this study is to improve the damping properties of concrete structure by utilization of the recycled materials from waste tires to be used in concrete as structural materials that improve seismic performance. In this study, the concrete containing 10% of fine crumb rubber and 1 % volume fraction of steel fiber from waste tires is use to investigate the dynamic performance (natural frequency and damping ratio).A small scale column were fabricated from Treated Crumb Rubber and Steel Fiber Concrete (TCRSFC) and NC were cast and cured for 28 days to investigate the dynamic performance. Based on analysis, dynamic modulus, damping ratio and natural frequency of TCRSFC has improved considerably by 5.18%, 109% and 10.94% when compared with NC. The TCRSFC producing concrete with the desired properties as well as to introduce the huge potential as dynamic resistance structure from severe damage especially prevention on catastrophic failure.

Effects of simulant mixed waste on EPDM and butyl rubber

DOE Office of Scientific and Technical Information (OSTI.GOV)

Nigrey, P.J.; Dickens, T.G.

1997-11-01

The authors have developed a Chemical Compatibility Testing Program for the evaluation of plastic packaging components which may be used in transporting mixed waste forms. In this program, they have screened 10 plastic materials in four liquid mixed waste simulants. These plastics were butadiene-acrylonitrile copolymer (Nitrile) rubber, cross-linked polyethylene, epichlorohydrin rubber, ethylene-propylene (EPDM) rubber, fluorocarbons (Viton and Kel-F{trademark}), polytetrafluoro-ethylene (Teflon), high-density polyethylene, isobutylene-isoprene copolymer (Butyl) rubber, polypropylene, and styrene-butadiene (SBR) rubber. The selected simulant mixed wastes were (1) an aqueous alkaline mixture of sodium nitrate and sodium nitrite; (2) a chlorinated hydrocarbon mixture; (3) a simulant liquid scintillation fluid; andmore » (4) a mixture of ketones. The screening testing protocol involved exposing the respective materials to approximately 3 kGy of gamma radiation followed by 14-day exposures to the waste simulants at 60 C. The rubber materials or elastomers were tested using Vapor Transport Rate measurements while the liner materials were tested using specific gravity as a metric. The authors have developed a chemical compatibility program for the evaluation of plastic packaging components which may be incorporated in packaging for transporting mixed waste forms. From the data analyses performed to date, they have identified the thermoplastic, polychlorotrifluoroethylene, as having the greatest chemical compatibility after having been exposed to gamma radiation followed by exposure to the Hanford Tank simulant mixed waste. The most striking observation from this study was the poor performance of polytetrafluoroethylene under these conditions. In the evaluation of the two elastomeric materials they have concluded that while both materials exhibit remarkable resistance to these environmental conditions, EPDM has a greater resistance to this corrosive simulant mixed waste.« less

Applications for activated carbons from waste tires: Natural gas storage and air pollution control

USGS Publications Warehouse

Brady, T.A.; Rostam-Abadi, M.; Rood, M.J.

1996-01-01

Natural gas storage for natural gas vehicles and the separation and removal of gaseous contaminants from gas streams represent two emerging applications for carbon adsorbents. A possible precursor for such adsorbents is waste tires. In this study, activated carbon has been developed from waste tires and tested for its methane storage capacity and SO2 removal from a simulated flue-gas. Tire-derived carbons exhibit methane adsorption capacities (g/g) within 10% of a relatively expensive commercial activated carbon; however, their methane storage capacities (Vm/Vs) are almost 60% lower. The unactivated tire char exhibits SO2 adsorption kinetics similar to a commercial carbon used for flue-gas clean-up. Copyright ?? 1996 Elsevier Science Ltd.

Preliminary measurements on heat balance in pneumatic tires

NASA Technical Reports Server (NTRS)

Nybakken, G. H.; Collart, D. Y.; Staples, R. J.; Lackey, J. I.; Clark, S. K.; Dodge, R. N.

1973-01-01

A variety of tests was undertaken to determine the nature of heat generation associated with a pneumatic tire operating under various conditions. Tests were conducted to determine the magnitude and distribution of internally generated heat caused by hysteresis in the rubber and ply fabric in an automobile tire operating under conditions of load, pressure, and velocity representative of normal operating conditions. These included tests at various yaw angles and tests with braking applied. In other tests, temperature sensors were mounted on a road to measure the effect of a tire rolling over and an attempt was made to deduce the magnitude and nature of interfacial friction from the resulting information. In addition, tests were performed using the scratch plate technique to determine the nature of the motion between the tire and road. Finally, a model tire was tested on a roadwheel, the surface covering which could be changed, and an optical pyrometer was used to measure rubber surface temperatures.

Tech Transfer Office discusses the finer points of tire recycling

NASA Technical Reports Server (NTRS)

1995-01-01

NASA's Technology Transfer Office at Stennis worked with a tire recycling company in St. Francisville, La., to help the company make better use of the cryogenics, or supercold fluids, in its recycling process. The process separates the rubber from the steel belts and other particles. The rubber is broken down into a material called crumb. Other parts of the tire particle removed is called fluff.

Environmental labeling of car tires--toxicity to Daphnia magna can be used as a screening method.

PubMed

Wik, Anna; Dave, Göran

2005-02-01

Car tires contain several water-soluble compounds that can leach into water and have toxic effects on aquatic organisms. Due to tire wear, 10,000 tonnes of rubber particles end up along the Swedish roads every year. This leads to a diffuse input of emissions of several compounds. Emissions of polyaromatic hydrocarbons (PAHs) are of particular concern. PAHs are ingredients of the high aromatic oil (HA oil) that is used in the rubber as a softener and as a filler. The exclusion of HA oils from car tires has started, and an environmental labeling of tires could make HA oils obsolete. The toxicity to Daphnia magna from 12 randomly selected car tires was tested in this study. Rubber from the tread of the tires was grated into small pieces, to simulate material from tire wear, and the rubber was equilibrated with dilution water for 72 h before addition of test organisms. The 24-h EC50s of the rubber pieces ranged from 0.29 to 32 gl-1, and the 48-h EC50s ranged from 0.0625 to 2.41 gl-1. Summer tires were more toxic than winter tires. After the 48-h exposure, the daphnids were exposed to UV-light for 2 h, to determine if the tires contained compounds that were phototoxic. After UV-activation the EC50s ranged from 0.0625 to 0.38 gl-1. Four of the 12 tires had a very distinct photoactivation, with a toxicity increase of >10 times. This study has shown that the used method for toxicity testing with Daphnia magna according to ISO 6341 could be used as a basis for environmental labeling of car tires.

Tire containing thermally exfoliated graphite oxide

NASA Technical Reports Server (NTRS)

Prud'homme, Robert K. (Inventor); Aksay, Ilhan A. (Inventor)

2011-01-01

A tire, tire lining or inner tube, containing a polymer composite, made of at least one rubber and/or at least one elastomer and a modified graphite oxide material, which is a thermally exfoliated graphite oxide with a surface area of from about 300 sq m/g to 2600 sq m/g.

Tables for estimating skidder tire wear

Treesearch

Cleveland J. Biller; Cleveland J. Biller

1970-01-01

This book of tables was prepared to help the logging operator estimate how much a particular logging job will wear the tires on his rubber-wheeled skidders. This is an important element in the cost of a logging operation. The logging operator can translate these estimates of tire wear into a production cost.

[Epidemiology of contact hypersensitivity to rubber components in manufacturers of automobile tires at the Stomil plant].

PubMed

Rubisz-Brzezińska, J; Bogdanowski, T; Brzezińska-Wcisło, L; Mozdzanowska, K; Bajcar, S

1990-01-01

Dermatological examination and patch tests with 34 rubber components were carried out in 114 tire manufacturers, 78 women and 36 men aged 29 years on average, with a mean duration of work in the plant 7 years. For correct interpretation of the obtained results patch tests with the same components were done in two control groups that is in 120 healthy subjects and 120 patients with contact dermatitis. Patch tests with proper concentrations of the studied components were evaluated after 48, 72 and 96 hours. Positive patch tests were found most frequently with antioxidants--16.6% (including IPPD--8.6%), followed by vulcanization accelerators--10.6%, and other rubber components--11.4% in all. During about 3 years of follow-up in 4 manufacturers contact allergic eczema was noted and polyvalent hypersensitivity to antioxidants and vulcanization accelerators without clinical manifestations of this hypersensitivity was diagnosed in 3 other subjects.

Tests of two new polyurethane foam wheelchair tires.

PubMed

Gordon, J; Kauzlarich, J J; Thacker, J G

1989-01-01

The performance characteristics of four 24-inch wheelchair tires are considered; one pneumatic and three airless. Specifically, two new airless polyurethane foam tires (circular and tapered cross-section) were compared to both a molded polyisoprene tire and a rubber pneumatic tire. Rolling resistance, coefficient of static friction, spring rate, tire roll-off, impact absorption, wear resistance, and resistance to compression set were the characteristics considered for the basis of comparison. Although the pneumatic tire is preferred by many wheelchair users, the two new polyurethane foam tires were found to offer a performance similar to the high-pressure pneumatic tire. In addition, the foam tires are less expensive and lighter in weight than the other tires tested.

Developing Specifications for Waste Glass, Municipal Waste Combustor Ash and Waste Tires as Highway Fill Materials (Continuation): Final Report. Volume 2. Waste Glass.

DOT National Transportation Integrated Search

1995-04-01

A two year study was conducted as a continuation project for the Florida Department of Transportation (FDOT) to evaluate Municipal Waste Combustor (MWD) ash, Waste Glass, and Waste Tires for use as general highway fill. Initial studies conducted at F...

Tire with Self-Repairing Mechanism

NASA Astrophysics Data System (ADS)

Nagaya, Kosuke; Ikai, Sigeo; Chiba, Manabu; Chao, Xujing

A new type of tire is presented, in which there is no air leakage when nails puncture the tire. The broken part is repaired automatically by a self-repairing mechanism. The self-repairing unit consists of two rubber sheets with internal lattices. Polymer particles, which expand their volume on adding water, are inserted into the lattices. The unit is adhered to the inside wall of the tire. Coolant fluid diluted with water is introduced to the polymers uniformly. In this system, the polymer particles expand with water-diluted coolant fluid, and become gel. Hence, they stop air leakages in the tire. Fundamental experiments are performed, and optimum conditions are found. This technique is also applied to real tires, and it is ascertained that there is no air leakage when the tire is punctured by nails.

Numerical analysis of some problems related to the mechanics of pneumatic tires: Finite deformation/rolling contact of a viscoelastic cylinder and finite deformation of cord-reinforced rubber composites

NASA Technical Reports Server (NTRS)

Oden, J. T.; Becker, E. B.; Lin, T. L.; Hsieh, K. T.

1984-01-01

The formulation and numerical analysis of several problems related to the behavior of pneumatic tires are considered. These problems include the general rolling contact problem of a rubber-like viscoelastic cylinder undergoing finite deformations and the finite deformation of cord-reinforced rubber composites. New finite element models are developed for these problems. Numerical results obtained for several representative cases are presented.

Comprehensive evaluation of the long-term performance of rubberized pavement, phase I : laboratory study of rubberized asphalt mix performance.

DOT National Transportation Integrated Search

2012-12-01

Crumb rubber, made from scrap tires, has been introduced into the production of different types of hot : mix asphalt (HMA) in either a wet or dry process. In the wet process, the crumb rubber and binder are : completely mixed to form asphalt rubber (...

Innovative technologies of waste recycling with production of high performance products

NASA Astrophysics Data System (ADS)

Gilmanshin, R.; Ferenets, A. V.; Azimov, Yu I.; Galeeva, A. I.; Gilmanshina, S. I.

2015-06-01

The innovative ways of recycling wastes as a tool for sustainable development are presented in the article. The technology of the production of a composite material based on the rubber fiber composite waste tire industry is presented. The results of experimental use of the products in the real conditions. The comparative characteristics of the composite material rubber fiber composite are given. The production technology of construction and repairing materials on the basis of foamed glass is presented.

TIRES, OPEN BURNING

EPA Science Inventory

The chapter describes available information on the health effects from open burning of rubber tires. It concentrates on the three known sources of detailed measurements: (1) a small-scale emissions characterization study performed by the U.S. EPA in a facility designed to simulat...

Chlorinated rubbers with advanced properties for tire industry

NASA Astrophysics Data System (ADS)

Mikhaylov, I. A.; Sukhareva, K. V.; Andriasyan, Yu. O.; Popov, A. A.

2017-12-01

The paper investigates the production and processing of halide-modified chlorinated rubbers, such as isobutylene isoprene rubber and ethylene-propylene-diene-monomer rubber (IIR and EPDM), which are perspective in terms of application in rubber industry. Prospects for their production and application are determined by the specific properties of these rubbers (low gas permeability of IIR, high heat and ozone resistance of EPDM). These properties are governed by the structure of both initial IIR and EPDM and chlorinated rubbers (ChIIR and ChEPDM). A new alternative technology of obtaining chlorinated elastomers based on solid-phase mechanochemical halide modification is proposed. Novel chlorinated polyolefin rubbers obtained by the developed technology show good technological properties under industrial production conditions due to enhanced covulcanization.

Measurement of Vehicle Tire-to-Road Coefficient of Friction with a Portable Microcomputerized Transducer.

DTIC Science & Technology

1982-08-01

Sliding Rubber and the Load Dependance of Road Tyre Friction," The Physics of Tire Tractio,’. Theory, and Experiment (Hays, D. F., and Brown, A. L...Saturation of Sliding Rubber and the Load Dependance of Road Tyre Friction," The Physics of Tire Traction, Theory, and Expe-iment (Hays, D. F., and...surfaces could be identified and evaluated before accidents happen or runway surfaces could be evaluated to determine if rubber or other contaminant

Rubber friction directional asymmetry

NASA Astrophysics Data System (ADS)

Tiwari, A.; Dorogin, L.; Steenwyk, B.; Warhadpande, A.; Motamedi, M.; Fortunato, G.; Ciaravola, V.; Persson, B. N. J.

2016-12-01

In rubber friction studies it is usually assumed that the friction force does not depend on the sliding direction, unless the substrate has anisotropic properties, like a steel surface grinded in one direction. Here we will present experimental results for rubber friction, where we observe a strong asymmetry between forward and backward sliding, where forward and backward refer to the run-in direction of the rubber block. The observed effect could be very important in tire applications, where directional properties of the rubber friction could be induced during braking.

Developing Specifications for Waste Glass, Municipal Waste Combustor Ash and Waste Tires as Highway Fill Materials (Continuation): Final Report. Volume 1. Municipal Waste Combustor Ash.

DOT National Transportation Integrated Search

1995-04-01

A two year study was conducted as a continuation project for the Florida Department of Transportation (FDOT) to evlauate Municipal Waste Combustor (MWC) ash, Waste Glass, and Waste Tires for use as general highway fill. Initial studies conducted at F...

Enhanced performance of crumb rubber filtration for ballast water treatment.

PubMed

Tang, Zhijian; Butkus, Michael A; Xie, Yuefeng F

2009-03-01

Waste-tire-derived crumb rubber was utilized as filter media to develop an efficient filter for ballast water treatment. In this study, the effects of coagulation, pressure filtration and dual-media (gravity) filtration on the performance of the crumb rubber filtration were investigated. The removal efficiencies of turbidity, phytoplankton and zooplankton, and head loss development were monitored during the filtration process. The addition of a coagulant enhanced the removal efficiencies of all targeted matter, but resulted in substantial increase of head loss. Pressure filtration increased filtration rates to 220 m(3)h(-1)m(-2) for 8-h operation and improved the zooplankton removal. Dual-media (crumb rubber/sand) gravity filtration also improved the removal efficiencies of phytoplankton and zooplankton over mono-media gravity crumb rubber filtration. However, these filtration techniques alone did not meet the criteria for removing indigenous organisms from ballast water. A combination of filtration and disinfection is suggested for future studies.

Evaluation of moisture damage in asphalt concrete with CRM motorcycle tire waste passing #50 sieve size

NASA Astrophysics Data System (ADS)

Siswanto, Henri; Supriyanto, Bambang; Pranoto, Pranoto; Chandra, Pria Rizky; Hakim, Arief Rahman

2017-09-01

The objective of this experimental research is to evaluate moisture damage in Asphalt Concrete (AC) with Crumb Rubber Modified (CRM) motorcycle tire waste passing #50 and retaining #100 sieve size. Two gradations were used in this research, the first gradation is usual for asphalt concrete base (ACB) and the second gradation is for asphalt concrete wearing course (ACWC). Marshall testing apparatus was used for testing the Marshall specimens. Seven levels of CRM content were used, namely 0%, 0.5%, 1%, 1.5%, 3%, 4.5% and 6% by weight of mixtures. Retained stability represent the level of moisture damage of AC pavement. The result indicates that addition CRM to the AC mixture increases their the stability to a maximum value and subsequent addition decrease the stability. The addition CRM to AC decreases their moisture damage susceptibility. AC with 1% CRM is the best asphalt-CRM mix.

Application of woven tires waste as soft clay subgrade reinforcement for preventing highway structural failure

NASA Astrophysics Data System (ADS)

Apriyono, Arwan; Sumiyanto, Gusmawan, Dadan Deri

2017-03-01

This study presents the application of woven waste tires as soft clay subgrade reinforcement for preventing highway structural failure, reducing construction cost and minimizing environmental hazards associated with the increasingly large amount of waste tires in Indonesia. To his end, we performed experiments using five stripe distance variations of woven tires - i.e. 2, 2.5, 3, 3.5 and 4 cm. Five soft clay samples were made and each was reinforced using each of these woven tires. The California Bearing Ratio (CBR) test was conducted on each softclay sample and the CBR value was determined from the stress on the displacement of 0.10 and 0.20 inch. The correlation between CBR value and strip distance was used to infer the optimum woven tires strip distance, indicated by the largest CBR value. The result suggests that the strip distance of 3 cm is optimum with corresponding CBR value of ˜20%, which is 115% increase compared to softclay without reinforcement.

Using acid-washed waste tire rubber in soilless media for tomato production

USDA-ARS?s Scientific Manuscript database

'Cerasiforne’ tomato (Lycopersicon esculentum Mill.) was grown in soilless potting media contained different substrate formulas including 25:25:50 volume ratio of acid-washed (AWR) or non-washed shredded rubber (NAWR): vermiculite or zeolite: perlite. Additionally, plants were grown in a peat: perli...

Investigation of the Influence of Acoustic Oscillation Parameters on the Mechanism of Waste Rubber Products Combustion

NASA Astrophysics Data System (ADS)

Shakurov, R. F.; Sitnikov, O. R.; Galimova, A. I.; Sabitova, A. F.

2018-03-01

The article presents an analysis of the used methods of recycling of waste rubber products. The worn out tires are exposed to natural decomposition only after 50 - 100 years, and toxic organic compounds used in the manufacture constitute a danger to the environment. It contemplates a method of recycling waste rubber products in devices where pulsating combustion is realized. The dependence of the influence of acoustic pulsation parameters on the combustion mechanism of waste rubber products and on the composition of combustion products was experimentally investigated and established. For this purpose, the setup scheme based on the Rijke effect is optimized. The resonance pipe is coaxially embedded in the shaft. The known mathematical model of finding the combustion zones in the Rijke pipe, corresponding to the gas flow oscillations with the maximum amplitude, is applied to the chosen scheme. Investigations were carried out for three positions of the grate relative to the lower section of the experimental pipe, in which 1st, 2nd, 3rd modes of oscillation are formed. There are favorable conditions arise for the secondary combustion of mechanical particles entrained in the gas flow in the tube. The favorable conditions for afterburning also include the fact that through the upper section of the resonant pipe, the ambient air, caused by the features of the standing wave, is mixed into the gas stream. A comparative analysis of the change of gas concentration composition along the length of the resonance tube is carried out. It is established that the basic mode of oscillations contributes to the reduction of nitrogen oxides, in comparison with the oscillations occurring simultaneously at several harmonics, considering the main one. The results of research for the three positions of the grate in relation to the lower section of the installation are presented in tabular form, in which 1, 2, 3 modes of oscillation are formed. The analysis of experimental results confirms

Federal Research on Recycled Tire Crumb Used on Playing Fields

EPA Pesticide Factsheets

Ground rubber is recovered from scrap tires or from the tire retreading process. It is used in road construction and in athletic and recreational applications,like ground cover under playground equipment, running track material, and as a soil additive.

Update on the Federal Research Action Plan on Recycled Tire Crumb Used on Playing Fields and Playgrounds

EPA Science Inventory

Concerns have been raised by the public about the safety of recycled tire crumb rubber used in synthetic turf fields and playgrounds in the United States. Several studies have been identified that examine exposure to tire crumb rubber infill in these settings. While, in general, ...

77 FR 10615 - Cooper Tire & Rubber Tire Company, Grant of Petition for Decision of Inconsequential Noncompliance

Federal Register 2010, 2011, 2012, 2013, 2014

2012-02-22

... measurable effect on the safety of the tire retread, repair, and recycling industries. The use of steel cord... no effect of the noncompliances on the operational safety of the vehicles on which these tires are mounted. The safety of people working in the tire retread, repair, and recycling industries must also be...

Method for co-processing waste rubber and carbonaceous material

DOEpatents

Farcasiu, Malvina; Smith, Charlene M.

1991-01-01

In a process for the co-processing of waste rubber and carbonaceous material to form a useful liquid product, the rubber and the carbonaceous material are combined and heated to the depolymerization temperature of the rubber in the presence of a source of hydrogen. The depolymerized rubber acts as a liquefying solvent for the carbonaceous material while a beneficial catalytic effect is obtained from the carbon black released on depolymerization the reinforced rubber. The reaction is carried out at liquefaction conditions of 380.degree.-600.degree. C. and 70-280 atmospheres hydrogen pressure. The resulting liquid is separated from residual solids and further processed such as by distillation or solvent extraction to provide a carbonaceous liquid useful for fuels and other purposes.

Comparative study of engineering properties of two-lime waste tire particle soil and soil with lime/loess ratio of 3:7

NASA Astrophysics Data System (ADS)

Tiecheng, Yan; Xingyuan, Zhang; Hongping, Yang

2018-03-01

This study describes an analytical comparison of the engineering characteristics of two-lime waste tire particle soil and soil with lime/loess ratio of 3:7 using density measurements, results of indoor consolidation tests, and direct shear tests to examine the strength and deformation characteristics. It investigates the engineering performance of collapsible loess treated with waste tire particles and lime. The results indicate that (1) the shear strength of the two-lime waste tire particle soils increases continuously with soil age; and (2) the two-lime waste tire particle soils are light-weight, strong, and low-deformation soils, and can be applied primarily to improve the foundation soil conditions in areas with collapsible loess soils. This could address the problem of used tire disposal, while providing a new method to consider and manage collapsible loess soils.

Environmental impact of highway construction and repair materials on surface and ground waters. Case study: crumb rubber asphalt concrete.

PubMed

Azizian, Mohammad F; Nelson, Peter O; Thayumanavan, Pugazhendhi; Williamson, Kenneth J

2003-01-01

The practice of incorporating certain waste products into highway construction and repair materials (CRMs) has become more popular. These practices have prompted the National Academy of Science, National Cooperative Highway Research Program (NCHRP) to research the possible impacts of these CRMs on the quality of surface and ground waters. State department of transportations (DOTs) are currently experimenting with use of ground tire rubber ( crumb rubber) in bituminous construction and as a crack sealer. Crumb rubber asphalt concrete (CR-AC) leachates contain a mixture of organic and metallic contaminants. Benzothiazole and 2(3H)-benzothiazolone (organic compounds used in tire rubber manufacturing) and the metals mercury and aluminum were leached in potentially harmful concentrations (exceeding toxic concentrations for aquatic toxicity tests). CR-AC leachate exhibited moderate to high toxicity for algae ( Selenastrum capriconutum) and moderate toxicity for water fleas ( Daphnia magna). Benzothiazole was readily removed from CR-AC leachate by the environmental processes of soil sorption, volatilization, and biodegradation. Metals, which do not volatilize or photochemically or biologically degrade, were removed from the leachate by soil sorption. Contaminants from CR-AC leachates are thus degraded or retarded in their transport through nearby soils and ground waters.

The use of mixed pyrrhotite/pyrite catalysts for co-liquefaction of coal and waste rubber tires

DOE Office of Scientific and Technical Information (OSTI.GOV)

Dadyburjor, D.B.; Zondlo, J.W.; Sharma, R.K.

1995-12-31

The overall objective of this research program is to determine the optimum processing conditions for tire/coal co-liquefaction. The catalysts used will be a ferric-sulfide-based materials, as well as promising catalysts from other consortium laboratories. The intent here is to achieve the maximum coal+tire conversion at the mildest conditions of temperature and pressure. Specific objectives include an investigation of the effects of time, temperature, pressure, catalyst and co-solvent on the conversion and product slate of the co-liquefaction. Accomplishments and conclusions are discussed.

Feasibility of High-Resolution Pulse-Echo Techniques for Automobile Tire Inspection

DOT National Transportation Integrated Search

1973-06-01

The report presents ultrasonic A-scan reflection oscillograms and B-scan one-dimensional scanning displays for small sections of automobile tires, and for tire-like rubber and cord composite structures, using impulse excitation of 1-MHz and 5-MHz tra...

Surface treated carbon catalysts produced from waste tires for fatty acids to biofuel conversion

DOE Office of Scientific and Technical Information (OSTI.GOV)

Hood, Zachary D.; Adhikari, Shiba P.; Wright, Marcus W.

A method of making solid acid catalysts includes the step of sulfonating waste tire pieces in a first sulfonation step. The sulfonated waste tire pieces are pyrolyzed to produce carbon composite pieces having a pore size less than 10 nm. The carbon composite pieces are then ground to produce carbon composite powders having a size less than 50 .mu.m. The carbon composite particles are sulfonated in a second sulfonation step to produce sulfonated solid acid catalysts. A method of making biofuels and solid acid catalysts are also disclosed.

Tire Production and Pollution Control. Environmental Education Curriculum. Revised.

ERIC Educational Resources Information Center

Topeka Public Schools, KS.

This unit was developed to introduce secondary students to the many facets of a typical, large manufacturing plant - the Topeka Goodyear Tire and Rubber Company - in an effort to increase awareness of sound environmental practices in industry. Its five major foci include the production of tires and quality control procedures; applications of…

40 CFR 428.50 - Applicability; description of the small-sized general molded, extruded, and fabricated rubber...

Code of Federal Regulations, 2010 CFR

2010-07-01

... RUBBER MANUFACTURING POINT SOURCE CATEGORY Small-Sized General Molded, Extruded, and Fabricated Rubber..., foam rubber backing, rubber cement-dipped goods, and retreaded tires by small-sized plants...

40 CFR 428.70 - Applicability; description of the large-sized general molded, extruded, and fabricated rubber...

Code of Federal Regulations, 2010 CFR

2010-07-01

... RUBBER MANUFACTURING POINT SOURCE CATEGORY Large-Sized General Molded, Extruded, and Fabricated Rubber..., foam rubber backing, rubber cement-dipped goods, and retreaded tires by large-sized plants...

ANSYS tools in modeling tires

NASA Technical Reports Server (NTRS)

Ali, Ashraf; Lovell, Michael

1995-01-01

This presentation summarizes the capabilities in the ANSYS program that relate to the computational modeling of tires. The power and the difficulties associated with modeling nearly incompressible rubber-like materials using hyperelastic constitutive relationships are highlighted from a developer's point of view. The topics covered include a hyperelastic material constitutive model for rubber-like materials, a general overview of contact-friction capabilities, and the acoustic fluid-structure interaction problem for noise prediction. Brief theoretical development and example problems are presented for each topic.

Analytical studies of the Space Shuttle orbiter nose-gear tire

NASA Technical Reports Server (NTRS)

Noor, Ahmed K.; Tanner, John A.; Peters, Jeanne M.; Robinson, Martha P.

1991-01-01

A computational procedure is presented for evaluating the analytic sensitivity derivatives of the tire response with respect to material and geometrical properties of the tire. The tire is modeled by using a two-dimensional laminated anisotropic shell theory with the effects of variation in material and geometric parameters included. The computational procedure is applied to the case of the Space Shuttle orbiter nose-gear tire subjected to uniform inflation pressure. Numerical results are presented which show the sensitivity of the different tire response quantities to variations in the material characteristics of both the cord and rubber.

40 CFR 63.5984 - What emission limits must I meet for tire production affected sources?

Code of Federal Regulations, 2010 CFR

2010-07-01

... tire production affected sources? 63.5984 Section 63.5984 Protection of Environment ENVIRONMENTAL... POLLUTANTS FOR SOURCE CATEGORIES National Emissions Standards for Hazardous Air Pollutants: Rubber Tire Manufacturing Emission Limits for Tire Production Affected Sources § 63.5984 What emission limits must I meet...

Mechanical and Physical Performance of Concrete Including Waste Electrical Cable Rubber

NASA Astrophysics Data System (ADS)

Taner Yildirim, Salih; Pelin Duygun, Nur

2017-10-01

Solid wastes are important environmental problem all over the World. Consumption of the plastic solid waste covers big portion within the total solid waste. Although a numerous plastic material is subjected to the recycling process, it is not easy to be destroyed by nature. One of the recommended way to prevent is to utilize as an aggregate in cement-based material. There are many researches on use of recycling rubber in concrete. However, studies on recycling of waste electrical cable rubber (WECR) in concrete is insufficient although there are many research on waste tyre rubbers in concrete. In this study, fine aggregate was replaced with WECR which were 5%, 10%, and 15 % of the total aggregate volume in the concrete and researched workability, unit weight, water absorption, compressive strength, flexural strength, ultrasonic pulse velocity, modulus of elasticity, and abrasion resistance of concrete. As a result of experimental studies, increase of WECR amount in concrete increases workability due to lack of adherence between cement paste and WECR, and hydrophobic structure of WECR while it influences negatively mechanical properties of concrete. It is possible to use WECR in concrete taking into account the reduction in mechanical properties.

40 CFR 63.6006 - How do I demonstrate continuous compliance with the emission limits for tire cord production...

Code of Federal Regulations, 2010 CFR

2010-07-01

... compliance with the emission limits for tire cord production affected sources? 63.6006 Section 63.6006... Hazardous Air Pollutants: Rubber Tire Manufacturing Continuous Compliance Requirements for Tire Cord... tire cord production affected sources? (a) You must demonstrate continuous compliance with each...

Demonstration of the waste tire pyrolysis process on pilot scale in a continuous auger reactor.

PubMed

Martínez, Juan Daniel; Murillo, Ramón; García, Tomás; Veses, Alberto

2013-10-15

This work shows the technical feasibility for valorizing waste tires by pyrolysis using a pilot scale facility with a nominal capacity of 150 kWth. A continuous auger reactor was operated to perform thirteen independent experiments that conducted to the processing of more than 500 kg of shredded waste tires in 100 h of operation. The reaction temperature was 550°C and the pressure was 1 bar in all the runs. Under these conditions, yields to solid, liquid and gas were 40.5 ± 0.3, 42.6 ± 0.1 and 16.9 ± 0.3 wt.% respectively. Ultimate and proximate analyses as well as heating value analysis were conducted for both the solid and liquid fraction. pH, water content, total acid number (TAN), viscosity and density were also assessed for the liquid and compared to the specifications of marine fuels (standard ISO 8217). Gas chromatography was used to calculate the composition of the gaseous fraction. It was observed that all these properties remained practically invariable along the experiments without any significant technical problem. In addition, the reaction enthalpy necessary to perform the waste tire pyrolysis process (907.1 ± 40.0 kJ/kg) was determined from the combustion and formation enthalpies of waste tire and conversion products. Finally, a mass balance closure was performed showing an excellent reliability of the data obtained from the experimental campaign. Copyright © 2013 Elsevier B.V. All rights reserved.

The Federal Research Action Plan on Recycled Tire Crumb Used on Playing Fields and Playgrounds - Background and Exposure Research Goals.

EPA Science Inventory

Concerns have been raised by the public about the safety of recycled tire crumb rubber used in synthetic turf fields and playgrounds in the United States (U.S.). Several studies have been identified that examine potential exposure to tire crumb rubber infill in these settings. Th...

Pyrolysis reaction models of waste tires: Application of Master-Plots method for energy conversion via devolatilization.

PubMed

Irmak Aslan, Dilan; Parthasarathy, Prakash; Goldfarb, Jillian L; Ceylan, Selim

2017-10-01

Land applied disposal of waste tires has far-reaching environmental, economic, and human health consequences. Pyrolysis represents a potential waste management solution, whereby the solid carbonaceous residue is heated in the absence of oxygen to produce liquid and gaseous fuels, and a solid char. The design of an efficient conversion unit requires information on the reaction kinetics of pyrolysis. This work is the first to probe the appropriate reaction model of waste tire pyrolysis. The average activation energy of pyrolysis was determined via iso-conversional methods over a mass fraction conversion range between 0.20 and 0.80 to be 162.8±23.2kJmol -1 . Using the Master Plots method, a reaction order of three was found to be the most suitable model to describe the pyrolytic decomposition. This suggests that the chemical reactions themselves (cracking, depolymerization, etc.), not diffusion or boundary layer interactions common with carbonaceous biomasses, are the rate-limiting steps in the pyrolytic decomposition of waste tires. Copyright © 2017 Elsevier Ltd. All rights reserved.

76 FR 28502 - Cooper Tire & Rubber Tire Company, Receipt of Petition for Decision of Inconsequential Noncompliance

Federal Register 2010, 2011, 2012, 2013, 2014

2011-05-17

... one-fourth of the distance from the bead to the shoulder of the tire. If the maximum section width... from the bead to the shoulder of the tire, on at least one sidewall. The markings must be in letters...

40 CFR 63.5996 - How do I demonstrate initial compliance with the emission limits for tire production affected...

Code of Federal Regulations, 2010 CFR

2010-07-01

... with the emission limits for tire production affected sources? 63.5996 Section 63.5996 Protection of... Pollutants: Rubber Tire Manufacturing Testing and Initial Compliance Requirements for Tire Production Affected Sources § 63.5996 How do I demonstrate initial compliance with the emission limits for tire...

QENS investigation of filled rubbers

NASA Astrophysics Data System (ADS)

Triolo, A.; Lo Celso, F.; Negroni, F.; Arrighi, V.; Qian, H.; Lechner, R. E.; Desmedt, A.; Pieper, J.; Frick, B.; Triolo, R.

The polymer segmental dynamics is investigated in a series of silica-filled rubbers. The presence of inert fillers in polymers greatly affects the mechanical and physical performance of the final materials. For example, silica has been proposed as a reinforcing agent of elastomers in tire production. Results from quasielastic neutron scattering and Dynamic Mechanical Thermal Analysis (DMTA) measurements are presented on styrene-ran-butadiene rubber filled with silica. A clear indication is obtained of the existence of a bimodal dynamics, which can be rationalized in terms of the relaxation of bulk rubber and the much slower relaxation of the rubber adsorbed on the filler surface.

Work environments and exposure to hazardous substances in korean tire manufacturing.

PubMed

Lee, Naroo; Lee, Byung-Kyu; Jeong, Sijeong; Yi, Gwang Yong; Shin, Jungah

2012-06-01

The purpose of this study is to evaluate the tire manufacturing work environments extensively and to identify workers' exposure to hazardous substances in various work processes. Personal air sampling was conducted to measure polycyclic aromatic hydrocarbons, carbon disulfide, 1,3-butadiene, styrene, methyl isobutyl ketone, methylcyclohexane, formaldehyde, sulfur dioxide, and rubber fume in tire manufacturing plants using the National Institute for Occupational Safety Health Manual of Analytical Methods. Noise, carbon monoxide, and heat stress exposure were evaluated using direct reading instruments. Past concentrations of rubber fume were assessed using regression analysis of total particulate data from 2003 to 2007, after identifying the correlation between the concentration of total particulate and rubber fume. Workers were exposed to rubber fume that exceeded 0.6 mg/m(3), the maximum exposure limit of the UK, in curing and production management processes. Forty-seven percent of workers were exposed to noise levels exceeding 85 dBA. Workers in the production management process were exposed to 28.1℃ (wet bulb globe temperature value, WBGT value) even when the outdoor atmosphere was 2.7℃ (WBGT value). Exposures to other substances were below the limit of detection or under a tenth of the threshold limit values given by the American Conference of Governmental Industrial Hygienists. To better classify exposure groups and to improve work environments, examining closely at rubber fume components and temperature as risk indicators in tire manufacturing is recommended.

40 CFR 63.5999 - How do I demonstrate initial compliance with the emission limits for tire cord production...

Code of Federal Regulations, 2010 CFR

2010-07-01

... with the emission limits for tire cord production affected sources? 63.5999 Section 63.5999 Protection... Pollutants: Rubber Tire Manufacturing Testing and Initial Compliance Requirements for Tire Cord Production Affected Sources § 63.5999 How do I demonstrate initial compliance with the emission limits for tire cord...

40 CFR 63.5986 - What emission limits must I meet for tire cord production affected sources?

Code of Federal Regulations, 2010 CFR

2010-07-01

... tire cord production affected sources? 63.5986 Section 63.5986 Protection of Environment ENVIRONMENTAL... POLLUTANTS FOR SOURCE CATEGORIES National Emissions Standards for Hazardous Air Pollutants: Rubber Tire Manufacturing Emission Limits for Tire Cord Production Affected Sources § 63.5986 What emission limits must I...

Study on cord/rubber interface at elevated temperatures by H-pull test method

NASA Astrophysics Data System (ADS)

Jamshidi, M.; Afshar, F.; Mohammadi, N.; Pourmahdian, S.

2005-08-01

Cords are used as reinforcing materials in rubber compounds. To increase cord/rubber interfacial adhesion, they are coated by an adhesive (usually based on resorcinol-formaldehyde-latex). These composites are used in many sectors such as tire and belt industries. Cord/rubber adhesion strength is an important aspect to determine the durability of system. Due to temperature increase during running tires, the adhesion energy becomes different from initial one. To study cord/rubber interface at elevated temperatures, H-adhesion test method was used. H-pull test is a simple method for adhesion evaluation at ambient temperature, so it is usually used for material quality control. In this research, cord/rubber systems were vulcanized at different temperatures and H-adhesion of samples were evaluated at elevated temperatures. Also cord/rubber interface was studied by ATR analyze to determine interfacial interactions kind.

Chemistry of rubber processing and disposal.

PubMed Central

Bebb, R L

1976-01-01

The major chemical changes during the processing of rubber occur with the breakdown in mastication and during vulcanization of the molded tire. There is little chemical change during the compounding, calendering, extrusion, and molding steps. Reclaiming is the process of converting scrap rubber into an unsaturated, processible product that can be vulcanized with sulfur. Pyrolysis of scrap rubber yields a complex mixture of liquids, gas, and residue in varying ratios dependent on the nature of the scrap and the conditions of pyrolysis. PMID:799964

The use of Crumb Rubber as Substitute of Fine Aggregate for Hot Asphalt Mixture using Polymer Modified Bitumen

NASA Astrophysics Data System (ADS)

Setyawan, A.; Nugroho, S. K.; Irsyad, A. M.; Mutaqo, H. F.; Ramadhan, P.; Sumarsono, A.; Pramesti, F. P.

2018-03-01

The development of road pavement to fulfilled the need of modern life is not only focused on heavy duty road, but also a light duty road for the convenience of road users according to its function. For example the use of pavement on the jogging track, rail crossing, playground and so on. Due to the need of an alternative and the innovation of a comfortable pavement layer, but sufficiently strong in holding the load on the layer. The alternative innovation that can be used for the respective requirement is the utilization of waste old tires as substitute material in pavement construction. In this case the use of crumb rubber made from old tire rubber as an 100% fine aggregate substitute on the asphalt mixtures is investigated. To improve the strength and durability of the mixtures, the addition of polymer modified bitumen was incorporated. The two types of asphalt mixture selected in this study by using a continuous gradation of asphalt concrete and a gap gradation of hot roll asphalt. Testing to be implemented in this research is volumetric characteristics, Marshall characteristics, resistance to abrasion and impact and permeability. Replacement of fine aggregate with crumb rubber on asphalt concrete mixture with 60/70 penetration grade bitumen and polymer modified asphalt SBS E-55 in this research are expected to be an alternative in improving the quality of pavement and overcoming the environmental problems by reuse the waste materials.

49 CFR 571.139 - Standard No. 139; New pneumatic radial tires for light vehicles.

Code of Federal Regulations, 2014 CFR

2014-10-01

... part of the tire that is made of steel wires, wrapped or reinforced by ply cords and that is shaped to... mechanical device made of rubber, chemicals, fabric and steel or other materials, that, when mounted on an....Test sample. For the tests specified in S6, use: (a) One tire for high speed; (b) Another tire for...

49 CFR 571.139 - Standard No. 139; New pneumatic radial tires for light vehicles.

Code of Federal Regulations, 2013 CFR

2013-10-01

... part of the tire that is made of steel wires, wrapped or reinforced by ply cords and that is shaped to... mechanical device made of rubber, chemicals, fabric and steel or other materials, that, when mounted on an....Test sample. For the tests specified in S6, use: (a) One tire for high speed; (b) Another tire for...

49 CFR 571.139 - Standard No. 139; New pneumatic radial tires for light vehicles.

Code of Federal Regulations, 2012 CFR

2012-10-01

... part of the tire that is made of steel wires, wrapped or reinforced by ply cords and that is shaped to... mechanical device made of rubber, chemicals, fabric and steel or other materials, that, when mounted on an....Test sample. For the tests specified in S6, use: (a) One tire for high speed; (b) Another tire for...

40 CFR 63.5987 - What are my alternatives for meeting the emission limits for tire cord production affected sources?

Code of Federal Regulations, 2010 CFR

2010-07-01

... the emission limits for tire cord production affected sources? 63.5987 Section 63.5987 Protection of... Pollutants: Rubber Tire Manufacturing Emission Limits for Tire Cord Production Affected Sources § 63.5987 What are my alternatives for meeting the emission limits for tire cord production affected sources? You...

Mechanistic understanding of tetracycline sorption on waste tire powder and its chars as affected by Cu(2+) and pH.

PubMed

Lian, Fei; Song, Zhengguo; Liu, Zhongqi; Zhu, Lingyan; Xing, Baoshan

2013-07-01

The sorption characteristics of tetracycline (TC) by waste tire powder and its chars were investigated to explore the potential of using waste tires as effective sorbents for removal of TC from aqueous solution. Naphthalene (NAPH), a typical hydrophobic organic compound, was selected as asorbate for comparison. TC displayed much lower sorption affinity to tire powder than NAPH. However, it exhibited similar adsorption affinity as NAPH on the pyrolyzed tire chars, which was mainly attributed to π-π electron-donor-acceptor interactions of TC with the graphite surface of chars. TC and Cu(2+) could mutually facilitate the sorption of each other on both tire powder and pyrolyzed chars in a wide pH range. This could be explained by the metallic complexation and/or surface-bridging mechanisms (i.e., Cu- or TC-bridging). However, Cu(2+) and NAPH depressed the sorption of each other on tire powder and displayed negligible impact to each other on the highly pyrolyzed chars. Copyright © 2013 Elsevier Ltd. All rights reserved.

Use of rubber crumbs in cement concrete

NASA Astrophysics Data System (ADS)

Longvinenko, A. A.

2018-03-01

Rubber crumb obtained from worn out tires has been increasingly used over the last 15-20 years, especially in manufacture of asphalt and cement concrete mixtures. This review pays principal attention to application of the rubber crumb to cement concrete mixtures. Use of the rubber crumb in cement concrete is not as successful as in asphalt concrete mixtures, due to incompatibility problems linked to chemical composition and a significant difference in rigidity between the rubber crumb and concrete mixture aggregates. Different methods are proposed and studied to mitigate the adverse influence and increase the beneficial effects of the rubber crumb when added to cement concrete.

A new recycling technique for the waste tires reuse.

PubMed

Derakhshan, Zahra; Ghaneian, Mohammad Taghi; Mahvi, Amir Hossein; Oliveri Conti, Gea; Faramarzian, Mohammad; Dehghani, Mansooreh; Ferrante, Margherita

2017-10-01

In this series of laboratory experiments, the feasibility of using fixed bed biofilm carriers (FBBC) manufactured from existing reclaimed waste tires (RWTs) for wastewater treatment was evaluated. To assess polyamide yarn waste tires as a media, the fixed bed sequence batch reactor (FBSBR) was evaluated under different organic loading rate (OLRs). An experimental model was used to study the kinetics of substrate consumption in biofilm. Removal efficiency of soluble chemical oxygen demand (SCOD) ranged by 76-98% for the FBSBR compared to 71-96% in a sequencing batch reactor (SBR). Removal efficiency of FBBC was significantly increased by inoculating these RWTs carriers. The results revealed that the sludge production yield (Y obs ) was significantly less in the FBSBR compared to the SBR (p < 0.01). It also produced less sludge and recorded a lower stabilization ratio (VSS/TSS). The findings show that the Stover-Kincannon model was the best fit (R 2 > 99%) in a FBSBR. Results from this study suggest that RWTs to support biological activity for a variety of wastewater treatment applications as a biofilm carrier have high potential that better performance as COD and TSS removal and sludge settling properties and effluent quality supported these findings. Copyright © 2017. Published by Elsevier Inc.

Sensitivity of tire response to variations in material and geometric parameters

NASA Technical Reports Server (NTRS)

Noor, Ahmed K.; Tanner, John A.; Peters, Jeanne M.

1992-01-01

A computational procedure is presented for evaluating the analytic sensitivity derivatives of the tire response with respect to material and geometric parameters of the tire. The tire is modeled by using a two-dimensional laminated anisotropic shell theory with the effects of variation in material and geometric parameters included. The computational procedure is applied to the case of uniform inflation pressure on the Space Shuttle nose-gear tire when subjected to uniform inflation pressure. Numerical results are presented showing the sensitivity of the different response quantities to variations in the material characteristics of both the cord and the rubber.

Fine granular of shredded waste tyre for road kerb application as improvised road furniture

NASA Astrophysics Data System (ADS)

Munikanan, Vikneswaran; Yahya, Muhamad Azani; Yusof, Mohammed Alias; Radzi, Muhammad Haris Fauzan

2018-02-01

Solid waste management in Malaysia was still in a backward stage. Population growth, urbanization and rapid industrialization led to an increase in the solid waste generated by society. Solid waste management is one of the main problems faced by the community, especially in the city. Solid waste management costs of the collection, collecting, transporting waste to the landfill, is very high. The quantity of solid waste should be reduced in order to reduce government spending. Moreover, improper solid waste management caused a negative impact on people and the environment. Method of recycling is one of the best alternatives to reduce the number of solid waste. Therefore, this study was to identify methods of recycling used tires to be used in civil engineering. This study was conducted to determine the effectiveness and properties of rubber from used tires to be add in the road kerb design.

Recycling of waste tyre rubber into oil absorbent.

PubMed

Wu, B; Zhou, M H

2009-01-01

The abundant and indiscriminant disposal of waste tyres has caused both health and environmental problems. In this work, we provide a new way to dispose off waste tyres by reusing the waste tyre rubber (WTR) for oil absorptive material production. To investigate this feasibility, a series of absorbents were prepared by graft copolymerization-blending method, using waste tyre rubber and 4-tert-butylstyrene (tBS) as monomers. Divinylbenzene (DVB) and benzoyl peroxide (BPO) were employed as crosslinker and initiator, respectively. The existence of graft-blends (WTR-g-tBS) was determined by FTIR spectrometry and verified using thin-layer chromatography (TLC). In addition, the thermal properties of WTR-g-tBS were confirmed by a thermogravimetric analyzer (TGA). Oil absorbency of the grafted-blends increased with increases in either feed ratio of WTR to tBS or DVB concentration. This absorbency reached a maximum of 24.0gg(-1) as the feed ratio and DVB concentration were 60/40 and 1wt%, respectively, after which it decreased. At other ratios and concentrations the absorbency decreased. The gel fraction of grafted-blends increased with increasing concentration of DVB. Oil-absorption processes in pure toluene and crude oil diluted with toluene were found to adhere to first-order absorption kinetics. Furthermore, the oil-absorption rate in diluted crude oil was observed to be lower than pure toluene.

Tests to Determine the Adhesive Power of Passenger-Car Tires

NASA Technical Reports Server (NTRS)

Foerster, B.

1956-01-01

The concept of the adhesive power of a tire with respect to the road involves several properties which result from the purpose of the tire; namely, connecting link between vehicle and road: (1) The tire must transfer the tractive and braking forces acting in the direction of travel (tractive and braking adhesion); (2) The tire is to prevent lateral deviations of the vehicle from the desired direction of travel (track adhesion). Moreover, the rubber tire provides part of the springing of the vehicle. Above all, it has to level out the minor road irregularities; thus it smoothes, as it were, the road and simultaneously reduces the noise of driving. The springing properties of the tire affect the adhesive power. The tests described below comprise a determination of the braking and track adhesion of individual tires. The adhesion of driven wheels has not been investigated so far.

CHEMICAL RECLAMATION OF SCRAP RUBBER

EPA Science Inventory

A conceptual, commercial-scale plant design was formulated for processing 22,500 t/yr of scrap rubber tires to hydrocarbon fuel gases, oils, petrochemicals (principally ethylene and aromatic liquids), and carbon black. The process is based upon molten salt (zinc chloride) pyrolys...

75 FR 74003 - Certain New Pneumatic Off-the-Road Tires From the People's Republic of China: Partial Rescission...

Federal Register 2010, 2011, 2012, 2013, 2014

2010-11-30

...-the-Road Tires From the People's Republic of China: Partial Rescission of Countervailing Duty... the countervailing duty order on certain new pneumatic off-the-road tires (OTR Tires) from the People... Guizhou Tyre Co., Ltd., Guizhou Advanced Rubber Co., Ltd., and Guizhou Tyre Import and Export Corporation...

Promising Technologies of Mining and Processing of Solid Minerals

NASA Astrophysics Data System (ADS)

Shabaev, Sergey; Ivanov, Seregey; Vakhianov, Evgeniy

2017-11-01

The continuing growth in mineral extraction entails an increase in industrial waste, which in turn has a negative impact on the environment. Rubber-tired vehicles, in which the tires wear colossally, is mainly used as a transport for loading, unloading, transportation and other types of work in the extraction of solid minerals. The used tires are not disposed in any way, but are stored in special areas where harmful toxic substances are emitted under the influence of ultraviolet rays. Therefore, a decision was made to find a method for utilization and rational use of industrial waste in the road construction sector. The operating temperature of composite rubber-bituminous binders based on rubber crumb from the used automobile tires is estimated in this paper, which is necessary for assigning technological parameters of production and laying of asphalt-concrete mixtures produced on their basis. It is established that composite rubber-bituminous binders based on rubber chips from the used automobile tires, produced according to the two-stage technology, have the same viscosity as the original petroleum bitumen, at a temperature increased by 20°C.

Catalytic pyrolysis of car tire waste using expanded perlite.

PubMed

Kar, Y

2011-08-01

In this study, the non-catalytic and catalytic pyrolysis experiments were conducted on the sample of tire waste using expanded perlite as an additive material to determine especially the effect of temperature and catalyst-to-tire ratio on the products yields and the compositions and qualities of pyrolytic oils (NCPO and CPO). Non-catalytic studies, which were carried out under the certain conditions (a nitrogen flow of 100mL/min and a heating rate of 10°C/min), showed that the highest yield of pyrolytic oil (NCPO) was 60.02wt.% at 425°C. Then, the catalytic pyrolysis studies were carried out at catalyst-to-tire ratio range of 0.05-0.25 and the highest catalytic pyrolytic oil (CPO) yield was 65.11wt.% at the ratio of 0.10 with the yield increase of 8.48wt.% compared with the non-catalytic pyrolysis. Lastly, the pyrolytic oils were characterized with applying a various techniques such as elemental analyses and various chromatographic and spectroscopic techniques (GC-MS, (1)H NMR, FT-IR, etc.). The characterization results revealed that the pyrolytic oils which were complex mixtures of C(5)-C(15) organic compounds (predominantly aromatic compounds) and also the CPO compared to the NCPO was more similar to conventional fuels in view of the certain fuel properties. Copyright © 2011 Elsevier Ltd. All rights reserved.

Vacuum pyrolysis of waste tires with basic additives.

PubMed

Zhang, Xinghua; Wang, Tiejun; Ma, Longlong; Chang, Jie

2008-11-01

Granules of waste tires were pyrolyzed under vacuum (3.5-10 kPa) conditions, and the effects of temperature and basic additives (Na2CO3, NaOH) on the properties of pyrolysis were thoroughly investigated. It was obvious that with or without basic additives, pyrolysis oil yield increased gradually to a maximum and subsequently decreased with a temperature increase from 450 degrees C to 600 degrees C, irrespective of the addition of basic additives to the reactor. The addition of NaOH facilitated pyrolysis dramatically, as a maximal pyrolysis oil yield of about 48 wt% was achieved at 550 degrees C without the addition of basic additives, while a maximal pyrolysis oil yield of about 50 wt% was achieved at 480 degrees C by adding 3 wt% (w/w, powder/waste tire granules) of NaOH powder. The composition analysis of pyrolytic naphtha (i.b.p. (initial boiling point) approximately 205 degrees C) distilled from pyrolysis oil showed that more dl-limonene was obtained with basic additives and the maximal content of dl-limonene in pyrolysis oil was 12.39 wt%, which is a valuable and widely-used fine chemical. However, no improvement in pyrolysis was observed with Na2CO3 addition. Pyrolysis gas was mainly composed of H2, CO, CH4, CO2, C2H4 and C2H6. Pyrolytic char had a surface area comparable to commercial carbon black, but its proportion of ash (above 11.5 wt%) was much higher.

Bulk Viscoelastic Contribution to the Wet Sliding Friction of Rubber Compounds

NASA Astrophysics Data System (ADS)

Pan, Xiao-Dong

2002-03-01

An efficient stopping of an automobile on a wet highway in a rainy day is of obvious importance to the safety of the driving public. Here tire tread made of filled rubber compounds plays an essential role in detremining the wet traction performance. Even though significant progress has been made in improving this tire performance character and much knowledge has been accumulated, there still lacks a coherent fundamental understanding on this dynamic process. Consequently there currently exist no accurate guidelines for designing rubber compounds for better wet traction, and for predicting the wet traction performance of a rubber compound. In this experimental study, a portable British Pendulum Skid Tester has been employed to examine in the laboratory how the rubber compound material properties affect its wet sliding friction on a concrete surface. A dramatic dispaly of the impacts from the compound bulk viscoelastic properties has been observed for the first time. This observation will be discussed in relation to previous results discussed in the literature.

2013-2014 Production of guayule natural rubber in Arizona, U.S.A.

USDA-ARS?s Scientific Manuscript database

Natural rubber is a unique biopolymer whose physical properties cannot be replicated in synthetic alternatives; therefore, it is required for production of tires (passenger, truck, and aircraft) and thousands of consumer and medical products. While demand for natural rubber is expected to increase ...

Fabrication and Assessment of Crumb-Rubber-Modified Coatings with Anticorrosive Properties.

PubMed

Al-Aqeeli, Nasser

2015-01-06

Scrap tires continue to be a major source of waste due to the lack of valuable and effective disposal routes. A viable solution to this problem is to recycle crumb rubber (CR)-a granulated material derived from scrap tires-and use it to develop other valuable products. Herein we report the fabrication and characterization of CR-modified coatings with anticorrosive properties on metal substrates. By varying the particle size and concentration of CR, we have determined the coating composition that offers the highest level of erosion protection. Images from a scanning electron microscope (SEM) reveal that CR is homogenously dispersed in the coating, especially when fine particles are used. As the concentration of CR increases, the hardness of the coating decreases as a result of the elastic properties of CR. More importantly, the erosion rate of the coating decreases due to increased ductility. Following Potentiodynamic tests, the utilization of these coatings proved to be beneficial as they showed good protection against aqueous corrosion when tested in 0.5 M NaCl solution. Our newly developed coatings offer an incentive to recycling CR and open up a safe and sustainable route to the disposal of scrap tires.

An evaluation: The potential of discarded tires as a source of fuel

NASA Technical Reports Server (NTRS)

Collins, L. W.; Downs, W. R.; Gibson, E. K.; Moore, G. W.

1974-01-01

The destructive distillation of rubber tire samples was studied by thermogravimetry, differential scanning calorimetry, combustion calorimetry, and mass spectroscopy. The decomposition reaction was found to be exothermic and produced a mass loss of 65 percent. The gas evolution curves that were obtained indicate that a variety of organic materials are evolved simultaneously during the decomposition of the rubber polymer.

Waste tyre rubberized concrete: properties at fresh and hardened state.

PubMed

Aiello, M A; Leuzzi, F

2010-01-01

The main objective of this paper is to investigate the properties of various concrete mixtures at fresh and hardened state, obtained by a partial substitution of coarse and fine aggregate with different volume percentages of waste tyres rubber particles, having the same dimensions of the replaced aggregate. Workability, unit weight, compressive and flexural strength and post-cracking behaviour were evaluated and a comparison of the results for the different rubcrete mixtures were proposed in order to define the better mix proportions in terms of mechanical properties of the rubberized concrete. Results showed in this paper were also compared to data reported in literature. Moreover, a preliminary geometrical, physical and mechanical characterization on scrap tyre rubber shreds was made. The rubberized concrete mixtures showed lower unit weight compared to plain concrete and good workability. The results of compressive and flexural tests indicated a larger reduction of mechanical properties of rubcrete when replacing coarse aggregate rather than fine aggregate. On the other hand, the post-cracking behaviour of rubberized concrete was positively affected by the substitution of coarse aggregate with rubber shreds, showing a good energy absorption and ductility indexes in the range observed for fibrous concrete, as suggested by standard (ASTM C1018-97, 1997). 2010 Elsevier Ltd. All rights reserved.

Evaluation of Reclaimed Rubber in Bituminous Pavements

DOT National Transportation Integrated Search

1995-06-01

Section 1038 of the 1991 Intermodal Surface Transportation Efficiency Act (ISTEA) mandated use of crumb rubber from scrap tires in asphalt pavement starting in FY 94. To gain some experience, the Illinois Department of Transportation (IDOT) construct...

A Strain-Based Method to Detect Tires' Loss of Grip and Estimate Lateral Friction Coefficient from Experimental Data by Fuzzy Logic for Intelligent Tire Development.

PubMed

Yunta, Jorge; Garcia-Pozuelo, Daniel; Diaz, Vicente; Olatunbosun, Oluremi

2018-02-06

Tires are a key sub-system of vehicles that have a big responsibility for comfort, fuel consumption and traffic safety. However, current tires are just passive rubber elements which do not contribute actively to improve the driving experience or vehicle safety. The lack of information from the tire during driving gives cause for developing an intelligent tire. Therefore, the aim of the intelligent tire is to monitor tire working conditions in real-time, providing useful information to other systems and becoming an active system. In this paper, tire tread deformation is measured to provide a strong experimental base with different experiments and test results by means of a tire fitted with sensors. Tests under different working conditions such as vertical load or slip angle have been carried out with an indoor tire test rig. The experimental data analysis shows the strong relation that exists between lateral force and the maximum tensile and compressive strain peaks when the tire is not working at the limit of grip. In the last section, an estimation system from experimental data has been developed and implemented in Simulink to show the potential of strain sensors for developing intelligent tire systems, obtaining as major results a signal to detect tire's loss of grip and estimations of the lateral friction coefficient.

The role of oxide structure on copper wire to the rubber adhesion

NASA Astrophysics Data System (ADS)

Su, Yea-Yang; Shemenski, Robert M.

2000-07-01

Most metals have an oxide layer on the surface. However, the structure of the oxide varies with the matrix composition, and depends upon the environmental conditions. A bronze coating, nominal composition of 98.5% Cu and balance of Sn, is applied to steel wire for reinforcing pneumatic tire beads and to provide adhesion to rubber. This work studied the influence of copper oxides on the bronze coating on adhesion during vulcanization. To emphasize the oxide structures, electrolytic tough pitch (ETP) copper wire was used instead of the traditional bronze-coated tire bead wire. Experimental results confirmed the hypothesis that cuprous oxide (Cu 2O) could significantly improve bonding between copper wire and rubber, and demonstrated that the interaction between rubber and oxide layer on wire is an electrochemical reaction.

Heat Exchange with Air and Temperature Profile of a Moving Oversize Tire

NASA Astrophysics Data System (ADS)

Grinchuk, P. S.; Fisenko, S. P.

2016-11-01

A one-dimensional mathematical model of heat transfer in a tire with account for the deformation energy dissipation and heat exchange of a moving tire with air has been developed. The mean temperature profiles are calculated and transition to a stationary thermal regime is considered. The influence of the rate of energy dissipation and of effective thermal conductivity of rubber on the temperature field is investigated quantitatively.

Experimental project : use of shredded tires for lightweight fill.

DOT National Transportation Integrated Search

1991-02-01

Shredded rubber tires have been used as lightweight fill in repair of a landslide that occurred under a highway embankment in mountainous terrain on Highway US 42 (Oregon State route #35). The force driving the slide was decreased by removing the soi...

Evaluation of asphalt rubber stress-absorbing membrane.

DOT National Transportation Integrated Search

1997-01-01

This report describes the construction and evaluation of a stress-absorbing membrane (SAM) using a liquid asphalt binder containing ground tire rubber. Approximately 10 lane-km of SAM and 4 lane-km of control surface treatment for comparison were con...

Evaluation of the Waste Tire Resources Recovery Program and Environmental Health Policy in Taiwan

PubMed Central

Chen, Chia-Ching; Yamada, Tetsuji; Chiu, I-Ming; Liu, Yi-Kuen

2009-01-01

This paper examines the effectiveness of Taiwanese environmental health policies, whose aim is to improve environmental quality by reducing tire waste via the Tire Resource Recovery Program. The results confirm that implemented environmental health policies improve the overall health of the population (i.e. a decrease in death caused by bronchitis and other respiratory diseases). Current policy expenditures are far below the optimal level, as it is estimated that a ten percent increase in the subsidy would decrease the number of deaths caused by bronchitis and other respiratory diseases by 0.58% per county/city per year on average. PMID:19440434

Epoxy composites based on inexpensive tire waste filler

NASA Astrophysics Data System (ADS)

Ahmetli, Gulnare; Gungor, Ahmet; Kocaman, Suheyla

2014-05-01

Tire waste (TW) was recycled as raw material for the preparation of DGEBA-type epoxy composite materials. The effects of filler amount and epoxy type on the mechanical properties of the composites were investigated. Tensile strength and Young's modulus of the composites with NPEL were generally higher than composites with NPEF. The appropriate mass level for TW in both type composites was found to be 20 wt%. The equilibrium water sorption of NPEL/TW and NPEF/TW composites for 14-day immersion was determined as 0.10 % and 0.21 %, respectively. Scanning electron microscopy (SEM) and X-ray diffraction (XRD) were used for characterization of the composites.

Comprehensive testing to measure the response of butyl rubber to Hanford tank waste simulant

DOE Office of Scientific and Technical Information (OSTI.GOV)

NIGREY,PAUL J.

This report presents the findings of the Chemical Compatibility Program developed to evaluate plastic packaging components that may be incorporated in packaging mixed-waste forms for transportation. Consistent with the methodology outlined in this report, the authors performed the second phase of this experimental program to determine the effects of simulant Hanford tank mixed wastes on packaging seal materials. That effort involved the comprehensive testing of five plastic liner materials in an aqueous mixed-waste simulant. The testing protocol involved exposing the materials to {approximately}143, 286, 571, and 3,670 krad of gamma radiation and was followed by 7-, 14-, 28-, 180-day exposuresmore » to the waste simulant at 18, 50, and 60 C. Butyl rubber samples subjected to the same protocol were then evaluated by measuring seven material properties: specific gravity, dimensional changes, mass changes, hardness, compression set, vapor transport rates, and tensile properties. From the analyses, they determined that butyl rubber has relatively good resistance to radiation, this simulant, and a combination of these factors. These results suggest that butyl rubber is a relatively good seal material to withstand aqueous mixed wastes having similar composition to the one used in this study.« less

Materials Approach to Fuel Efficient Tires

DOE Office of Scientific and Technical Information (OSTI.GOV)

Votruba-Drzal, Peter; Kornish, Brian

2015-06-30

The objective of this project was to design, develop, and demonstrate fuel efficient and safety regulation compliant tire filler and barrier coating technologies that will improve overall fuel efficiency by at least 2%. The program developed and validated two complementary approaches to improving fuel efficiency through tire improvements. The first technology was a modified silica-based product that is 15% lower in cost and/or enables a 10% improvement in tread wear while maintaining the already demonstrated minimum of 2% improvement in average fuel efficiency. The second technology was a barrier coating with reduced oxygen transmission rate compared to the state-of-the-art halobutylmore » rubber inner liners that will provide extended placarded tire pressure retention at significantly reduced material usage. A lower-permeance, thinner inner liner coating which retains tire pressure was expected to deliver the additional 2% reduction in fleet fuel consumption. From the 2006 Transportation Research Board Report1, a 10 percent reduction in rolling resistance can reduce consumer fuel expenditures by 1 to 2 percent for typical vehicles. This savings is equivalent to 6 to 12 gallons per year. A 1 psi drop in inflation pressure increases the tire's rolling resistance by about 1.4 percent.« less

Feasibility of Steel Fiber-Reinforced Rubberized Concrete in Cold Regions for High Volume Intersections

NASA Astrophysics Data System (ADS)

Abou Eid, Mahear A.

There are many challenges faced with the use of Portland Cement Concrete (PCC) in cold regions, but with the inclusion of new technologies such as steel fibers and recycled tire crumb rubber efficient construction may be possible. Research was conducted on a modified concrete material that included both steel fibers and crumb rubber. The composite material was called Steel Fiber-Reinforced Rubberized Concrete (SFRRC). The objective of this investigation was to provide evidence showing that SFRRC can reduce tire rutting compared to asphaltic pavement. In addition, the research showed that the SFRRC could withstand freeze-thaw cycles and increase service life of roadways. Several tests were performed to determine the characteristics of the material. Freeze-thaw testing was performed to determine compressive strength loss and visual deterioration of the material. Wheel tracker rut testing was performed both with the standard steel wheel and with a modified studded rubber tire to determine plastic deformation and rut resistance. An experimental test slab was cast in place on a public approach to observe the construction procedures, the effects of studded tire wear and the frost actions in cold region conditions. Based on freeze-thaw and wheel tracker test results and observations of the experimental test slab, the SFRRC material shows viability in cold regions for resisting freeze-thaw actions. The freeze-thaw testing resulted in increased compressive strength after 300 freeze-thaw cycles and very low deterioration of material compared to standard PCC. The wheel tracker testing resulted in very low plastic deformation and minor material rutting with use of the studded rubber tire. The test slab showed very minor surface wear, no freeze-thaw cracking and no rutting after one winter of use. It is recommended that further testing of the material be conducted by means of a large-scale trial section. This would provide information with respect to cost analysis and

Amphiphilic semi-interpenetrating polymer networks using pulverized rubber

NASA Astrophysics Data System (ADS)

Shahidi, Nima

Scrap rubber materials provide a significant challenge to either reuse or safe disposal. Every year, millions of tires are discarded to landfills in the United States, consuming a staggering amount of land space, creating a high risk for large fires, breeding mosquitoes that spread diseases, and wasting the planet's natural resources. This situation cannot be sustained. The challenge of reusing scrap rubber materials is mainly due to the crosslinked structure of vulcanized rubber that prevent them from melting and further processing for reuse. The most feasible recycling approach is believed to be a process in which the vulcanized rubber is first pulverized into a fine powder and then incorporated into new products. The production of fine rubber particles is generally accomplished through the use of a cryogenic process that is costly. Therefore, development of a cost effective technology that utilizes a large quantity of the scrap rubber materials to produce high value added materials is an essential element in maintaining a sustainable solution to rubber recycling. In this research, a cost effective pulverization process, solid state shear extrusion (SSSE), was modified and used for continuous pulverization of the rubber into fine particles. In the modified SSSE process, pulverization takes place at high compressive shear forces and a controlled temperature. Furthermore, an innovative particle modification process was developed to enhance the chemical structure and surface properties of the rubber particles for manufacturing of high value added products. Modification of rubber particles was accomplished through the polymerization of a hydrophilic monomer mixture within the intermolecular structure of the hydrophobic rubber particles. The resulting composite particles are considered as amphiphilic particulate phase semi-interpenetrating polymer networks (PPSIPNs). The modified rubber particles are water dispersible and suitable for use in a variety of aqueous media

A North American model to contain the spread of Aedes albopictus through tire legislation.

PubMed

Novak, R J

1995-12-01

The introduction, spread, and establishment of the Asian tiger mosquito, Aedes albopictus, in the United States has been facilitated by used or waste tires. This species has not only caused considerable concern among public health officials but also highlighted that the growing accumulations of used tires are a serious solid waste problem and a challenge to the recycling industry. This paper illustrates how the State of Illinois addressed the public health and solid waste problems associated with waste tires, mosquitoes and mosquito-borne pathogens. The goal of the State was to develop and implement through legislative process the Illinois Waste Tire Act. The purpose of the Waste Tire Act is: 1) to ensure that used and waste tires are collected for disposal and recycling, 2) to provide for the abatement of used and waste tire dumps and associated threats to public health, 3) to encourage the development of used and waste tire processing facilities and technologies, including energy recovery, and 4) to provide for research on vectors associated with used and waste tires, and the diseases they spread. The discussion will include key statutes from the Act and the model used to coordinate the effort of five different governmental agencies. An up-to-date presentation of vector-related research, mandated by the Act, ranging from applied investigations on mosquito control to more basic studies investigations on virus identification using molecular technology will be discussed. Finally a discussion of problems that have been encountered along with solutions dealing with legislative language, multidisciplined agency efforts and interactions with the general public are presented.

Pyrolytic conversion of plastic and rubber waste to hydrocarbons with basic salt catalysts

DOEpatents

Wingfield, Jr., Robert C.; Braslaw, Jacob; Gealer, Roy L.

1985-01-01

The invention relates to a process for improving the pyrolytic conversion of waste selected from rubber and plastic to low molecular weight olefinic materials by employing basis salt catalysts in the waste mixture. The salts comprise alkali or alkaline earth compounds, particularly sodium carbonate, in an amount of greater than about 1 weight percent based on the waste feed.

Reduction of carbon content in waste-tire combustion ashes by bio-thermal treatment.

PubMed

Chen, Chun-Chi; Lee, Wen-Jhy; Shih, Shun-I; Mou, Jin-Luh

2009-11-01

Application of bio-catalyst (NOE-7F) in thermal treatment can adequately dispose dark-black fly ashes from co-combustion of both waste tires and coal. After thermal treatment of fly ashes by adding 10% NOE-7F, the carbon contents reduced by 37.6% and the weight losses increased by 405%, compared with the fly ashes without mixing with NOE-7F. The combustion behaviors of wasted tires combustion fly ashes with NOE-7F were also investigated by both thermogravimetric analysis (TGA) and differential thermal analysis (DTA). The results verify that NOE-7F has positive effects on the combustion of residual carbon and toxic polycyclic aromatic hydrocarbons (PAHs) enhance the energy release and reduce the toxicity during the process of thermal treatment. Furthermore, using NOE-7F to dispose high-carbon content fly ashes did improve the compressive strength of fly ashes and concrete mixtures. Therefore, NOE-7F is a promising additive which could decrease treatment cost of high-carbon content fly ashes and reduce the amount of survival toxic PAHs.

Reduction of carbon content in waste-tire combustion ashes by bio-thermal treatment

DOE Office of Scientific and Technical Information (OSTI.GOV)

Chen, C.C.; Lee, W.J.; Shih, S.I.

2009-07-01

Application of bio-catalyst (NOE-7F) in thermal treatment can adequately dispose dark-black fly ashes from co-combustion of both waste tires and coal. After thermal treatment of fly ashes by adding 10% NOE-7F, the carbon contents reduced by 37.6% and the weight losses increased by 405%, compared with the fly ashes without mixing with NOE-7F. The combustion behaviors of wasted tires combustion fly ashes with NOE-7F were also investigated by both thermogravimetric analysis (TGA) and differential thermal analysis (DTA). The results verify that NOE-7F has positive effects on the combustion of residual carbon and toxic polycyclic aromatic hydrocarbons (PAHs) enhance the energymore » release and reduce the toxicity during the process of thermal treatment. Furthermore, using NOE-7F to dispose high-carbon content fly ashes did improve the compressive strength of fly ashes and concrete mixtures. Therefore, NOE-7F is a promising additive which could decrease treatment cost of high-carbon content fly ashes and reduce the amount of survival toxic PAHs.« less

Adding crumb rubber into exterior wall materials.

PubMed

Zhu, Han; Thong-On, Norasit; Zhang, Xiong

2002-10-01

In Arizona US, most houses are built with walls covered by stuccos/coatings/mortars. This paper presents an explorative investigation of adding crumb rubber into stuccos/coatings/mortars. A series of experiments are conducted to examine the thermal and mechanical performance of the crumb rubber mixes. The results show that, the mixes with crumb rubber do exhibit more desirable performances like being high in crack-resistance and thermal insulation, and low in thermal expansion/contraction. The drawback for the crumb rubber mixes is the reduction in compressive strength, but which can be compensated by other means. As a site experiment, an area of 100 square-feet of crumb rubber coatings for two mix designs is sprayed on a tire-adobe wall. After being sprayed more than 14 months, the coatings apparently are in good condition. Significance of this study is that this practice, if accepted, will yield improved products that consume large quantities of crumb rubber.

Epoxy composites based on inexpensive tire waste filler

DOE Office of Scientific and Technical Information (OSTI.GOV)

Ahmetli, Gulnare, E-mail: ahmetli@selcuk.edu.tr; Gungor, Ahmet, E-mail: ahmetli@selcuk.edu.tr; Kocaman, Suheyla, E-mail: ahmetli@selcuk.edu.tr

2014-05-15

Tire waste (TW) was recycled as raw material for the preparation of DGEBA-type epoxy composite materials. The effects of filler amount and epoxy type on the mechanical properties of the composites were investigated. Tensile strength and Young’s modulus of the composites with NPEL were generally higher than composites with NPEF. The appropriate mass level for TW in both type composites was found to be 20 wt%. The equilibrium water sorption of NPEL/TW and NPEF/TW composites for 14-day immersion was determined as 0.10 % and 0.21 %, respectively. Scanning electron microscopy (SEM) and X-ray diffraction (XRD) were used for characterization ofmore » the composites.« less

Cancer mortality and occupational exposure to aromatic amines and inhalable aerosols in rubber tire manufacturing in Poland.

PubMed

de Vocht, Frank; Sobala, Wojciech; Wilczynska, Urszula; Kromhout, Hans; Szeszenia-Dabrowska, Neonila; Peplonska, Beata

2009-08-01

Most data on carcinogenic risk in the rubber industry are based on data from Western countries. This study assessed cancer risks in a retrospective cohort in a Polish tire manufacturing plant, relying on quantified exposure to inhalable aerosols and aromatic amines instead of job titles or external comparisons. Cumulative exposure for all exposures was assigned to cohort members based on estimates from a company-specific JEM. Cancer risks associated with cumulative exposure adjusted for co-exposures, gender and year of birth were calculated. Exposure levels were higher for women than for men. Aromatic amine exposure was significantly associated with increased urinary bladder cancer risk (RR=7.32-8.27), depending on exposure level, and prostate cancer at low levels only (RR=5.86). In women, increased risks were found for all cancers (RR=2.50) and of the digestive organs and peritoneum (RR=4.54) at low level only, while an exposure-response association with breast cancer risk was found. Inhalable aerosol exposure was associated with cancers of the liver and intrahepatic bile ducts in a dose-dependent manner, while dose-dependent reduced risks were found for respiratory cancers (most notably the larynx) and cancer of the colon. Increased risks for specific cancer sites in this rubber plant were similar to Western Europe and the US. However, several cancer risks were gender-specific which could relate to higher exposure levels in women or to differences in exposures to chemicals not assessed in this study.

40 CFR Table 11 to Subpart Xxxx of... - Minimum Data for Continuous Compliance With the Emission Limits for Tire Cord Production Affected...

Code of Federal Regulations, 2010 CFR

2010-07-01

... With the Emission Limits for Tire Cord Production Affected Sources 11 Table 11 to Subpart XXXX of Part... for Hazardous Air Pollutants: Rubber Tire Manufacturing Pt. 63, Subpt. XXXX, Table 11 Table 11 to Subpart XXXX of Part 63—Minimum Data for Continuous Compliance With the Emission Limits for Tire Cord...

Tire Development for Effective Transportation and Utilization of Used Tires, CRADA 01-N044, Final Report

DOE Office of Scientific and Technical Information (OSTI.GOV)

Susan M. Maley

Scrap tires represent a significant disposal and recycling challenge for the United States. Over 280 million tires are generated on an annual basis, and several states have large stockpiles or abandoned tire piles that are slated for remediation. While most states have programs to address the accumulation and generation of scrap tires, most of these states struggle with creating and sustaining recycling or beneficial end use markets. One of the major issues with market development has been the costs associated with transporting and processing the tires into material for recycling or disposal. According to a report by the Rubber Manufacturesmore » Association tire-derived fuel (TDF) represents the largest market for scrap tires, and approximately 115 million tires were consumed in 2001 as TDF (U.S. Scrap Tire Markets, 2001, December 2002, www.rma.org/scraptires). This market is supported primarily by cement kilns, followed by various industries including companies that operate utility and industrial boilers. However the use of TDF has not increased and the amount of TDF used by boiler operators has declined. The work completed through this cooperative research and development agreement (CRADA) has shown the potential of a mobile tire shredding unit to economically produce TDF and to provide an alterative low cost fuel to suitable coal-fired power systems. This novel system addresses the economic barriers by processing the tires at the retailer, thereby eliminating the costs associated with hauling whole tires. The equipment incorporated into the design allow for small 1-inch chunks of TDF to be produced in a timely fashion. The TDF can then be co-fired with coal in suitable combustion systems, such as a fluidized bed. Proper use of TDF has been shown to boost efficiency and reduce emissions from power generation systems, which is beneficial to coal utilization in existing power plants. Since the original scope of work outlined in the CRADA could not be completed

Criteria for asphalt-rubber concrete in civil airport pavements: Mixture design

NASA Astrophysics Data System (ADS)

Roberts, F. L.; Lytton, R. L.; Hoyt, D.

1986-07-01

A mixture design procedure is developed to allow the use of asphalt-rubber binders in concrete for flexible airport pavement. The asphalt-rubber is produced by reacting asphalt with ground, scrap tire rubber to produce the binder for the asphalt-rubber concrete. Procedures for laboratory preparation of alsphalt-rubber binders using an equipment setup that was found by researchers to produce laboratory binders with similar properties to field processes are included. The rubber-asphalt concrete mixture design procedure includes adjustments to the aggregate gradation to permit space for the rubber particles in the asphalt-rubber binder as well as suggested mixing and compaction temperatures, and compaction efforts. While the procedure was used in the laboratory to successfully produce asphalt-rubber concrete mixtures, it should be evaluated in the field to ensure that consistent results can be achieved in a production environment.

Feasibility study of a soil-based rubberized CLSM.

PubMed

Wu, Jason Y; Tsai, Mufan

2009-02-01

The development of beneficial uses of recycled scrap tires is always in great demand around the world. The disposal of on-site surplus excavated soil and the production of standard engineering aggregates have also been facing increasing environmental and ecological challenges in congested islands, such as Taiwan. This paper presents an experimental study using recycled crumb rubber and native silty sand to produce a lightweight, soil-based, rubberized controlled low strength material (CLSM) for a bridge approach repair. To assess the technical feasibility of this material, the effects of weight ratios of cement-to-water (C/W) and water-to-solid (W/S), and of rubber content on the engineering properties for different mixtures were investigated. The presented test results include flowability, unit weight, strength, settlement potential, and bearing capacity. Based on the findings, we conclude that a soil-based rubberized CLSM with 40% sand by weight and an optimal design ratio of 0.7 for C/W and 0.35 for W/S can be used for the proposed bridge approach repair. Such a mixture has demonstrated acceptable flowability, strength, and bearing capacity. Its lower unit weight, negligible compressibility, and hydrocollapse potential also help ensure that detrimental settlement is unlikely to occur. The results illustrate a novel scheme of CLSM production, and suggest a beneficial alternative for the reduction of scrap tires as well as conservation of resources and environment.

Nonlinear Viscoelastic Mechanics of Cross-linked Rubbers

NASA Technical Reports Server (NTRS)

Freed, Alan D.; Leonov, Arkady I.; Gray, Hugh R. (Technical Monitor)

2002-01-01

The paper develops a general theory for finite rubber viscoelasticity, and specifies it in the form, convenient for solving problems important for rubber, tire and space industries. Based on the quasi-linear approach of non-equilibrium thermodynamics, a general nonlinear theory has been developed for arbitrary nonisothermal deformations of viscoelastic solids. In this theory, the constitutive equations are presented as the sum of known equilibrium (rubber elastic) and non-equilibrium (liquid polymer viscoelastic) terms. These equations are then simplified using several modeling arguments. Stability constraints for the proposed constitutive equations are also discussed. It is shown that only strong ellipticity criteria are applicable for assessing stability of the equations governing viscoelastic solids.

Durability of Fly Ash Based Geopolymer Concrete Infilled with Rubber Crumb in Seawater Exposure

NASA Astrophysics Data System (ADS)

Yahya, Z.; Abdullah, M. M. A. B.; Ramli, S. N. H.; Minciuna, M. G.; Razak, R. Abd

2018-06-01

Geopolymer is an alternative binder to replace Ordinary Portland Cement (OPC)in construction industry. Source materials that rich in silica (Si) and alumina (Al) were activated by using alkaline solution. Production of tires keep increasing every year and due to its non-biodegradable properties it causes problems for disposal process. In current scenario, waste materials should be used or recycled so that the existing natural resources can be saved and at the same times it can protected environment. In this paper, the effect of rubber crumb on fly ash based geopolymer concrete have been investigated by immersing the samples in seawater for 28 and 60 days. The rubber crumb was used to replace coarse aggregates from range 5% until 20%. The ratio of fly ash/alkaline activator and sodium silicate/sodium hydroxide(NaOH) ratio were fixed at 2.0 and 2.5. It has been shown that the compressive strength decreased when the content of rubber crumb increased. The highest compressive strength (39.6 MPa) was obtained at 5% replacement of rubber crumb when exposure to seawater for 28 days. The density of geopolymer samples also increased when immersed in seawater for all samples. The lack of bonding between rubber crumb and geoplymer paste cause increasing in porosity hence reduced the strength, increment in density and changes in weight of geopolymer samples.

The leaching of inorganic species from activated carbons produced from waste tyre rubber.

PubMed

San Miguel, G; Fowler, G D; Sollars, C J

2002-04-01

Waste tyre rubber can be used as a precursor for the production of high quality activated carbons. However, there is concern that inorganic impurities present in the rubber feed may restrict their use in liquid phase applications with high purity requirements. This paper presents an investigation of the presence and the leaching of inorganic species from activated carbons derived from waste tyre rubber. For the purpose of this work, a number of carbons were produced, characterised for their BET surface area and analysed for their inorganic composition. Subsequently, a number of tests were performed to evaluate the leaching of different inorganic species into solution at various pH values and carbon doses. Results showed that rubber-derived carbons contained elevated concentrations of sulphur and zinc, as well as traces of other metals such as lead, cadmium, chromium and molybdenum. Inorganic levels were significantly affected by production conditions, particularly degree of carbon activation and the nature of the gasification agent. However, leaching tests showed that the availability of these species in neutral pH conditions was very limited. Results demonstrated that, when using carbons doses comparable to those employed in water treatment works, only sulphur levels exceeded, in some occasions, health based quality standards proposed for drinking water.

Field study of a shredded-tire embankment.

DOT National Transportation Integrated Search

1994-01-01

This report presents interim data from the ongoing field study of an experimental shredded-tire embankment constructed near Williamsburg, Virginia. Approximately 1.7 million tires were used. This constitutes the largest reported use to date of waste ...

Whole-body vibration in heavy equipment operators of a front-end loader: role of task exposure and tire configuration with and without traction chains.

PubMed

Blood, Ryan P; Rynell, Patrik W; Johnson, Peter W

2012-12-01

This study measured whole-body vibration (WBV) exposures in front-end loader operators, and evaluated the effects of traction chains and work tasks on their WBV exposures. WBV exposures were measured and compared across three different front-end loader tire configurations: (a) stock rubber tires, (b) rubber tires with ladder chains, and (c) rubber tires with basket chains. The operators completed three distinct standardized tasks: driving on a city street, simulated plowing, and a simulated scooping and dumping task. A portable data acquisition system collected tri-axial time weighted and raw WBV data per ISO 2631-1 and 2631-5 standards. In addition, Global Positioning System (GPS) data were collected in order to compare loader speeds across tire conditions and the standardized tasks. Relative to the stock rubber tires, both types of tire chains significantly increased WBV exposures with the ladder chains having substantially higher WBV exposures compared to basket chains. Additionally, there were task dependent differences in WBV exposures. During the driving task, the z-axis (up and down) was the predominant exposure; the plowing task had a more even distribution of exposure across all three axes; while during scooping and dumping task, the x-axis (fore and aft) had the highest WBV exposures. The GPS data indicated that there were significant speed differences across tasks but not between the basket and ladder chain conditions. Tires with ladder chains increased the front-end loader operators' exposure to WBV above the ISO 2631-1 recommended eight hour action limit increasing risk for adverse health effects. Although more expensive, basket chains are recommended over ladder chains since they substantially lowered the front-end loader operator's exposures and may ultimately reduce vibration related wear and tear on the vehicle. In order to reduce a heavy equipment vehicle (HEV) operator's chances for developing low back pain, this study provides information that

Leaching of DOC, DN, and inorganic constituents from scrap tires.

PubMed

Selbes, Meric; Yilmaz, Ozge; Khan, Abdul A; Karanfil, Tanju

2015-11-01

One concern for recycle and reuse of scrap tires is the leaching of tire constituents (organic and inorganic) with time, and their subsequent potential harmful impacts in environment. The main objective of this study was to examine the leaching of dissolved organic carbon (DOC), dissolved nitrogen (DN), and selected inorganic constituents from scrap tires. Different sizes of tire chips and crumb rubber were exposed to leaching solutions with pH's ranging from 3.0 to 10.0 for 28days. The leaching of DOC and DN were found to be higher for smaller size tire chips; however, the leaching of inorganic constituents was independent of the size. In general, basic pH conditions increased the leaching of DOC and DN, whereas acidic pH conditions led to elevated concentrations of metals. Leaching was minimal around the neutral pH values for all the monitored parameters. Analysis of the leaching rates showed that components associated with the rubbery portion of the tires (DOC, DN, zinc, calcium, magnesium, etc.) exhibited an initial rapid followed by a slow release. On the other hand, a constant rate of leaching was observed for iron and manganese, which are attributed to the metal wires present inside the tires. Although the total amounts that leached varied, the observed leaching rates were similar for all tire chip sizes and leaching solutions. Operation under neutral pH conditions, use of larger size tire chips, prewashing of tires, and removal of metal wires prior to application will reduce the impact of tire recycle and reuse. Copyright © 2015 Elsevier Ltd. All rights reserved.

75 FR 17827 - Goodyear Tire & Rubber Company, Grant of Petition for Decision of Inconsequential Noncompliance

Federal Register 2010, 2011, 2012, 2013, 2014

2010-04-07

... measurable effect on the safety of the tire retread, repair, and recycling industries. The use of steel cord... effect of the noncompliance on the operational safety of vehicles on which these tires are mounted. The safety of people working in the tire retread, repair, and recycling industries must also be considered...

RoxB Is a Novel Type of Rubber Oxygenase That Combines Properties of Rubber Oxygenase RoxA and Latex Clearing Protein (Lcp).

PubMed

Birke, Jakob; Röther, Wolf; Jendrossek, Dieter

2017-07-15

Only two types of rubber oxygenases, rubber oxygenase (RoxA) and latex clearing protein (Lcp), have been described so far. RoxA proteins (RoxAs) are c -type cytochromes of ≈70 kDa produced by Gram-negative rubber-degrading bacteria, and they cleave polyisoprene into 12-oxo-4,8-dimethyltrideca-4,8-diene-1-al (ODTD), a C 15 oligo-isoprenoid, as the major end product. Lcps are common among Gram-positive rubber degraders and do not share amino acid sequence similarities with RoxAs. Furthermore, Lcps have much smaller molecular masses (≈40 kDa), are b -type cytochromes, and cleave polyisoprene to a mixture of C 20 , C 25 , C 30 , and higher oligo-isoprenoids as end products. In this article, we purified a new type of rubber oxygenase, RoxB Xsp (RoxB of Xanthomonas sp. strain 35Y). RoxB Xsp is distantly related to RoxAs and resembles RoxAs with respect to molecular mass (70.3 kDa for mature protein) and cofactor content (2 c -type hemes). However, RoxB Xsp differs from all currently known RoxAs in having a distinctive product spectrum of C 20 , C 25 , C 30 , and higher oligo-isoprenoids that has been observed only for Lcps so far. Purified RoxB Xsp revealed the highest specific activity of 4.5 U/mg (at 23°C) of all currently known rubber oxygenases and exerts a synergistic effect on the efficiency of polyisoprene cleavage by RoxA Xsp RoxB homologs were identified in several other Gram-negative rubber-degrading species, pointing to a prominent function of RoxB for the biodegradation of rubber in Gram-negative bacteria. IMPORTANCE The enzymatic cleavage of rubber (polyisoprene) is of high environmental importance given that enormous amounts of rubber waste materials are permanently released (e.g., by abrasion of tires). Research from the last decade has discovered rubber oxygenase A, RoxA, and latex clearing protein (Lcp) as being responsible for the primary enzymatic attack on the hydrophobic and water-insoluble biopolymer poly( cis -1,4-isoprene) in Gram

Effects of leachate from crumb rubber and zinc in green roofs on the survival, growth, and resistance characteristics of Salmonella enterica subsp. enterica serovar Typhimurium.

PubMed

Crampton, Mollee; Ryan, Allayna; Eckert, Cori; Baker, Katherine H; Herson, Diane S

2014-05-01

The use of green roofs is a growing practice worldwide, particularly in densely populated areas. In an attempt to find new methods for recycling crumb rubber, incorporation of crumb rubber into artificial medium for plant growth in green roofs and similar engineered environments has become an attractive option for the recycling of waste tires. Though this approach decreases waste in landfills, there are concerns about the leaching of zinc and other heavy metals, as well as nutrient and organic compounds, into the environment. The present study analyzed the impact of leachate from crumb rubber and zinc on the growth and viability of Salmonella enterica subsp. enterica serovar Typhimurium. Zinc was chosen for further studies since it has been previously implicated with other biological functions, including biofilm formation, motility, and possible cross-resistance to antimicrobial agents. The study showed that Salmonella can colonize crumb rubber and that crumb rubber extract may provide nutrients that are usable by this bacterium. Salmonella strains with reduced susceptibility (SRS) to zinc were obtained after subculturing in increasing concentrations of zinc. The SRS exhibited differences in gene expression of flux pump genes zntA and znuA compared to that of the parent when exposed to 20 mM added zinc. In biofilm formation studies, the SRS formed less biofilm but was more motile than the parental strain.

Effects of Leachate from Crumb Rubber and Zinc in Green Roofs on the Survival, Growth, and Resistance Characteristics of Salmonella enterica subsp. enterica Serovar Typhimurium

PubMed Central

Crampton, Mollee; Ryan, Allayna; Eckert, Cori; Baker, Katherine H.

2014-01-01

The use of green roofs is a growing practice worldwide, particularly in densely populated areas. In an attempt to find new methods for recycling crumb rubber, incorporation of crumb rubber into artificial medium for plant growth in green roofs and similar engineered environments has become an attractive option for the recycling of waste tires. Though this approach decreases waste in landfills, there are concerns about the leaching of zinc and other heavy metals, as well as nutrient and organic compounds, into the environment. The present study analyzed the impact of leachate from crumb rubber and zinc on the growth and viability of Salmonella enterica subsp. enterica serovar Typhimurium. Zinc was chosen for further studies since it has been previously implicated with other biological functions, including biofilm formation, motility, and possible cross-resistance to antimicrobial agents. The study showed that Salmonella can colonize crumb rubber and that crumb rubber extract may provide nutrients that are usable by this bacterium. Salmonella strains with reduced susceptibility (SRS) to zinc were obtained after subculturing in increasing concentrations of zinc. The SRS exhibited differences in gene expression of flux pump genes zntA and znuA compared to that of the parent when exposed to 20 mM added zinc. In biofilm formation studies, the SRS formed less biofilm but was more motile than the parental strain. PMID:24584242

Characterization of asphalt cements modified with crumbed rubber from discarded tires : final report.

DOT National Transportation Integrated Search

1994-11-01

The potential legislative requirement for incorporation of scrap rubber into asphalt blends mandated a thorough evaluation of the influence of scrap rubber additives on the physical properties and aging characteristics of rubber/asphalt blends. Blend...

Spin-up studies of the Space Shuttle Orbiter main gear tire

NASA Technical Reports Server (NTRS)

Daugherty, Robert H.; Stubbs, Sandy M.

1988-01-01

One of the factors needed to describe the wear behavior of the Space Shuttle Orbiter main gear tires is their behavior during the spin-up process. An experimental investigation of tire spin-up processes was conducted at the NASA Langley Research Center's Aircraft Landing Dynamics Facility. During the investigation, the influence of various parameters such as forward speed and sink speed on tire spin-up forces were evaluated. A mathematical model was developed to estimate drag forces and spin-up times and is presented. The effect of prerotation was explored and is discussed. Also included is a means of determining the sink speed of the orbiter at touchdown based upon the appearance of the rubber deposits left on the runway during spinup.

[Contemporary state of work conditions and occupational morbidity of workers engaged into rubber, mechanical rubber and tire industries].

PubMed

Stepanov, E G; Galiullina, É F; Samsonov, V M; Kudriavtsev, V P; Davletgareeva, G R; Shakirova, É D; Khasanov, B G; Buliakov, R T; Kamilov, R F; Shakirov, D F

2014-01-01

Based on analysis of materials provided by occupational safety department PC "UZEMiK" and JSC "Kauchuk", the authors evaluate contemporary work conditions and occupational morbidity in workers engaged into rubber, mechanical rubber and tyre industries.

Industrial waste treatment and application in rubber production

NASA Astrophysics Data System (ADS)

Pugacheva, I. N.; Popova, L. V.; Repin, P. S.; Molokanova, L. V.

2018-03-01

The paper provides for the relevance of various industrial waste treatment and application, as well as their secondary commercialization. It considers treatment of secondary polymer materials turning to additives applied in rubber production, in particular, in production of conveyor and V-type belts used in mechanical engineering. It is found that oligomers obtained from petroleum by-products can be used as an impregnating compound for fiber materials. Such adhesive treatment prior to introduction of impregnating compounds into elastomeric materials improves adhesion and complements performance of obtained composites.

Response of ethylene propylene diene monomer rubber (EPDM) to simulant Hanford tank waste

DOE Office of Scientific and Technical Information (OSTI.GOV)

NIGREY,PAUL J.

2000-02-01

This report presents the findings of the Chemical Compatibility Program developed to evaluate plastic packaging components that may be incorporated in packaging mixed-waste forms for transportation. Consistent with the methodology outlined in this report, the author performed the second phase of this experimental program to determine the effects of simulant Hanford tank mixed wastes on packaging seal materials. That effort involved the comprehensive testing of five plastic liner materials in an aqueous mixed-waste simulant. The testing protocol involved exposing the materials to {approximately}143, 286, 571, and 3,670 krad of gamma radiation and was followed by 7-, 14-, 28-, 180-day exposuresmore » to the waste simulant at 18, 50, and 60 C. Ethylene propylene diene monomer (EPDM) rubber samples subjected to the same protocol were then evaluated by measuring seven material properties: specific gravity, dimensional changes, mass changes, hardness, compression set, vapor transport rates, and tensile properties. The author has determined that EPDM rubber has excellent resistance to radiation, this simulant, and a combination of these factors. These results suggest that EPDM is an excellent seal material to withstand aqueous mixed wastes having similar composition to the one used in this study.« less

Plant Assimilation Kinetics and Metabolism of 2-Mercaptobenzothiazole Tire Rubber Vulcanizers by Arabidopsis.

PubMed

LeFevre, Gregory H; Portmann, Andrea C; Müller, Claudia E; Sattely, Elizabeth S; Luthy, Richard G

2016-07-05

2-Mercaptobenzothiazole (MBT) is a tire rubber vulcanizer found in potential sources of reclaimed water where it may come in contact with vegetation. In this work, we quantified the plant assimilation kinetics of MBT using Arabidopsis under hydroponic conditions. MBT depletion kinetics in the hydroponic medium with plants were second order (t1/2 = 0.52 to 2.4 h) and significantly greater than any abiotic losses (>18 times faster; p = 0.0056). MBT depletion rate was related to the initial exposure concentration with higher rates at greater concentrations from 1.6 μg/L to 147 μg/L until a potentially inhibitory level (1973 μg/L) lowered the assimilation rate. 9.8% of the initial MBT mass spike was present in the plants after 3 h and decreased through time. In-source LC-MS/MS fragmentation revealed that MBT was converted by Arabidopsis seedlings to multiple conjugated-MBT metabolites of differential polarity that accumulate in both the plant tissue and hydroponic medium; metabolite representation evolved temporally. Multiple novel MBT-derived plant metabolites were detected via LC-QTOF-MS analysis; proposed transformation products include glucose and amino acid conjugated MBT metabolites. Elucidating plant transformation products of trace organic contaminants has broad implications for water reuse because plant assimilation could be employed advantageously in engineered natural treatment systems, and plant metabolites in food crops could present an unintended exposure route to consumers.

40 CFR Table 12 to Subpart Xxxx of... - Continuous Compliance With the Emission Limits for Tire Cord Production Affected Sources

Code of Federal Regulations, 2010 CFR

2010-07-01

... 40 Protection of Environment 12 2010-07-01 2010-07-01 true Continuous Compliance With the Emission Limits for Tire Cord Production Affected Sources 12 Table 12 to Subpart XXXX of Part 63 Protection of... Pollutants: Rubber Tire Manufacturing Pt. 63, Subpt. XXXX, Table 12 Table 12 to Subpart XXXX of Part 63...

Waste tire derived carbon-polymer composite paper as pseudocapacitive electrode with long cycle life

DOE PAGES

Boota, M.; Paranthaman, Mariappan Parans; Naskar, Amit K.; ...

2015-09-25

Recycling hazardous wastes to produce value-added products is becoming essential for the sustainable progress of our society. Herein, highly porous carbon (1625 m 2/g –1) is synthesized using waste tires as the precursor and used as supercapacitor electrode. The narrow pore size distribution (PSD) and high surface area led to a good charge storage capacity, especially when used as a three-dimensional nanoscaffold to polymerize polyaniline (PANI/TC). The composite film was highly flexible, conductive and exhibited a capacitance of 480 F/g –1 at 1 mV/s –1 with excellent capacitance retention up to 98% after 10,000 charge/discharge cycles. The high capacitance andmore » long cycle life were ascribed to the short diffusional paths, uniform PANI coating and tight confinement of the PANI in the inner pores of the tire-derived carbon via - interactions, which minimized the degradation of the PANI upon cycling. Here, we anticipate that the same strategy can be applied to deposit other pseudocapacitive materials with low-cost TC to achieve even higher electrochemical performance and longer cycle life, a key challenge for redox active polymers.« less

Waste Tire Derived Carbon-Polymer Composite Paper as Pseudocapacitive Electrode with Long Cycle Life

DOE Office of Scientific and Technical Information (OSTI.GOV)

Boota, M.; Paranthaman, M. Parans; Naskar, Amit K.

2015-09-25

Recycling hazardous wastes to produce value-added products is becoming essential for the sustainable progress of our society. Herein, highly porous carbon (1625 m2 g-1) is synthesized using waste tires as the precursor and used as a supercapacitor electrode material. The narrow pore-size distribution and high surface area led to good charge storage capacity, especially when used as a three-dimensional nanoscaffold to polymerize polyaniline (PANI). The composite paper was highly flexible, conductive, and exhibited a capacitance of 480 F g-1 at 1 mV s-1 with excellent capacitance retention of up to 98 % after 10 000 charge/discharge cycles. The high capacitancemore » and long cycle life were ascribed to the short diffusional paths, uniform PANI coating, and tight confinement of the PANI in the inner pores of the tire-derived carbon through π–π interactions, which minimized the degradation of the PANI upon cycling. We anticipate that the same strategy can be applied to deposit other pseudocapacitive materials to achieve even higher electrochemical performance and longer cycle life—a key challenge for redox active polymers.« less

Waste Tire Derived Carbon-Polymer Composite Paper as Pseudocapacitive Electrode with Long Cycle Life.

PubMed

Boota, M; Paranthaman, M Parans; Naskar, Amit K; Li, Yunchao; Akato, Kokouvi; Gogotsi, Y

2015-11-01

Recycling hazardous wastes to produce value-added products is becoming essential for the sustainable progress of our society. Herein, highly porous carbon (1625 m(2)  g(-1)) is synthesized using waste tires as the precursor and used as a supercapacitor electrode material. The narrow pore-size distribution and high surface area led to good charge storage capacity, especially when used as a three-dimensional nanoscaffold to polymerize polyaniline (PANI). The composite paper was highly flexible, conductive, and exhibited a capacitance of 480 F g(-1) at 1 mV s(-1) with excellent capacitance retention of up to 98% after 10,000 charge/discharge cycles. The high capacitance and long cycle life were ascribed to the short diffusional paths, uniform PANI coating, and tight confinement of the PANI in the inner pores of the tire-derived carbon through π-π interactions, which minimized the degradation of the PANI upon cycling. We anticipate that the same strategy can be applied to deposit other pseudocapacitive materials to achieve even higher electrochemical performance and longer cycle life-a key challenge for redox active polymers. © 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

78 FR 22513 - Certain New Pneumatic Off-the-Road Tires From the People's Republic of China: Final Results of...

Federal Register 2010, 2011, 2012, 2013, 2014

2013-04-16

...''); see also Issues and Decision Memorandum at Comment 6. Carbon Black: We have used the Thai import data for ``Rubber Grade Carbon Black'' to value all carbon black inputs.\\7\\ \\7\\ See Surrogate Value... Certain Material Inputs A. Carbon Black B. Bead Wire C. Nylon Tire Cord D. Natural Rubber E. Gap-filling...

49 CFR 571.139 - Standard No. 139; New pneumatic radial tires for light vehicles.

Code of Federal Regulations, 2011 CFR

2011-10-01

... means the part of the tire that is made of steel wires, wrapped or reinforced by ply cords and that is... mechanical device made of rubber, chemicals, fabric and steel or other materials, that, when mounted on an...

Fabrication and Assessment of Crumb-Rubber-Modified Coatings with Anticorrosive Properties

PubMed Central

Al-Aqeeli, Nasser

2015-01-01

Scrap tires continue to be a major source of waste due to the lack of valuable and effective disposal routes. A viable solution to this problem is to recycle crumb rubber (CR)—a granulated material derived from scrap tires—and use it to develop other valuable products. Herein we report the fabrication and characterization of CR-modified coatings with anticorrosive properties on metal substrates. By varying the particle size and concentration of CR, we have determined the coating composition that offers the highest level of erosion protection. Images from a scanning electron microscope (SEM) reveal that CR is homogenously dispersed in the coating, especially when fine particles are used. As the concentration of CR increases, the hardness of the coating decreases as a result of the elastic properties of CR. More importantly, the erosion rate of the coating decreases due to increased ductility. Following Potentiodynamic tests, the utilization of these coatings proved to be beneficial as they showed good protection against aqueous corrosion when tested in 0.5 M NaCl solution. Our newly developed coatings offer an incentive to recycling CR and open up a safe and sustainable route to the disposal of scrap tires. PMID:28787931

40 CFR Table 7 to Subpart Xxxx of... - Initial Compliance With the Emission Limits for Tire Cord Production Affected Sources

Code of Federal Regulations, 2010 CFR

2010-07-01

... 40 Protection of Environment 12 2010-07-01 2010-07-01 true Initial Compliance With the Emission Limits for Tire Cord Production Affected Sources 7 Table 7 to Subpart XXXX of Part 63 Protection of... Pollutants: Rubber Tire Manufacturing Pt. 63, Subpt. XXXX, Table 7 Table 7 to Subpart XXXX of Part 63—Initial...

Monte carlo simulation of innovative neutron and photon shielding material composing of high density concrete, waste rubber, lead and boron carbide

NASA Astrophysics Data System (ADS)

Aim-O, P.; Wongsawaeng, D.; Phruksarojanakun, P.; Tancharakorn, S.

2017-06-01

High-density concrete exhibits high strength and can perform an important role of gamma ray attenuation. In order to upgrade this material’s radiation-shielding performance, hydrogen-rich material can be incorporated. Waste rubber from vehicles has high hydrogen content which is the prominent characteristic to attenuate neutron. The objective of this work was to evaluate the radiation-shielding properties of this composite material against neutron and photon radiations. Monte Carlo transport simulation was conducted to simulate radiation through the composite material. Am-241/Be was utilized for neutron source and Co-60 for photon source. Parameters of the study included volume percentages of waste rubber, lead and boron carbide and thickness of the shielding material. These designs were also fabricated and the radiation shielding properties were experimentally evaluated. The best neutron and gamma ray shielding material was determined to be high-density concrete mixed with 5 vol% crumb rubber and 5 vol% lead powder. This shielding material increased the neutron attenuation by 64% and photon attenuation by 68% compared to ordinary concrete. Also, increasing the waste rubber content to greater than 5% resulted in a decrease in the radiation attenuation. This innovative composite radiation shielding material not only benefits nuclear science and engineering applications, but also helps solve the environmental issue of waste rubber.

Method for the addition of vulcanized waste rubber to virgin rubber products

DOEpatents

Romine, Robert A.; Snowden-Swan, Lesley J.

1997-01-01

The invention is a method of using enzymes from thiophyllic microbes for selectively breaking the sulfur rubber cross-link bonds in vulcanized rubber. The process is halted at the sulfoxide or sulfone step so that a devulcanized layer is reactive with virgin rubber.

Sustainable stabilization of sulfate-bearing soils with expansive soil-rubber technology.

DOT National Transportation Integrated Search

2013-03-01

The beneficial use of scrap tire rubber mixed with expansive soils is of interest to civil engineering : applications since the swell percent and the swell pressure can be potentially reduced with no deleterious : effect to the shear strength of the ...

Predicting the compressibility behaviour of tire shred samples for landfill applications.

PubMed

Warith, M A; Rao, Sudhakar M

2006-01-01

Tire shreds have been used as an alternative to crushed stones (gravel) as drainage media in landfill leachate collection systems. The highly compressible nature of tire shreds (25-47% axial strain on vertical stress applications of 20-700 kPa) may reduce the thickness of the tire shred drainage layer to less than 300 mm (minimum design requirement) during the life of the municipal solid waste landfill. There hence exists a need to predict axial strains of tire shred samples in response to vertical stress applications so that the initial thickness of the tire shred drainage layer can be corrected for compression. The present study performs one-dimensional compressibility tests on four tire shred samples and compares the results with stress/strain curves from other studies. The stress/strain curves are developed into charts for choosing the correct initial thickness of tire shred layers that maintain the minimum thickness of 300 mm throughout the life of the landfill. The charts are developed for a range of vertical stresses based on the design height of municipal waste cell and bulk unit weight of municipal waste. Experimental results also showed that despite experiencing large axial strains, the average permeability of the tire shred sample consistently remained two to three orders of magnitude higher than the design performance criterion of 0.01cm/s for landfill drainage layers. Laboratory experiments, however, need to verify whether long-term chemical and bio-chemical reactions between landfill leachate and the tire shred layer will deteriorate their mechanical functions (hydraulic conductivity, compressibility, strength) beyond permissible limits for geotechnical applications.

Method for the addition of vulcanized waste rubber to virgin rubber products

DOEpatents

Romine, R.A.; Snowden-Swan, L.J.

1997-01-28

The invention is a method of using enzymes from thiophyllic microbes for selectively breaking the sulfur rubber cross-link bonds in vulcanized rubber. The process is halted at the sulfoxide or sulfone step so that a devulcanized layer is reactive with virgin rubber. 8 figs.

Rubber modified concrete (METRO RUMAC) Evaluation : N. Marine Drive in Portland, Oregon , S.E. Stark Street in Gresham, Oregon : construction report.

DOT National Transportation Integrated Search

1992-11-01

This report covers the construction in 1991 of two test pavements using asphalt modified crumb rubber form scrap tires. The pavements are on arterial roadways in the Portland, Oregon metropolitan area. : Both test pavements use a dense-graded rubber ...

Rubber friction on road surfaces: Experiment and theory for low sliding speeds

DOE Office of Scientific and Technical Information (OSTI.GOV)

Lorenz, B.; Persson, B. N. J.; Oh, Y. R.

We study rubber friction for tire tread compounds on asphalt road surfaces. The road surface topographies are measured using a stylus instrument and atomic force microscopy, and the surface roughness power spectra are calculated. The rubber viscoelastic modulus mastercurves are obtained from dynamic mechanical analysis measurements and the large-strain effective modulus is obtained from strain sweep data. The rubber friction is measured at different temperatures and sliding velocities, and is compared to the calculated data obtained using the Persson contact mechanics theory. We conclude that in addition to the viscoelastic deformations of the rubber surface by the road asperities, theremore » is an important contribution to the rubber friction from shear processes in the area of contact. The analysis shows that the latter contribution may arise from rubber molecules (or patches of rubber) undergoing bonding-stretching-debonding cycles as discussed in a classic paper by Schallamach.« less

Federal Research Action Plan (FRAP) on Recycled Tire Crumb Used on Playing Fields and Playgrounds

EPA Science Inventory

This is part of the stakeholder engagement effort for the Federal Research Action Plan on Recycled Tire Crumb Used on Playing Fields and Playgrounds. The 2017 California Tire Conference gathers those interested and involved in waste tire management, tire-derived products and tire...

Cold recycle pavement using urea urethane dispersion agent and rubber : final report.

DOT National Transportation Integrated Search

1994-12-01

This research study was a joint venture of the Oregon Department of Transportation (ODOT), Evans, Loosely, Inc., and Roseburg Paving Company, to evaluate the use of Urea Urethane Dispersion (UUD) agent, with finely ground tire rubber, high float emul...

DOE Office of Scientific and Technical Information (OSTI.GOV)

Magdalena Zaharia; Veena Sahajwalla; Byong-Chul Kim

The present study investigates the effect of addition of waste rubber tires on the combustion behavior of its blends with coke for carbon injection in electric arc furnace steelmaking. Waste rubber tires were mixed in different proportions with metallurgical coke (MC) (10:90, 20:80, 30:70) for combustion and pyrolysis at 1473 K in a drop tube furnace (DTF) and thermogravimetric analyzer (TGA), respectively. Under experimental conditions most of the rubber blends indicated higher combustion efficiencies compared to those of the constituent coke. In the early stage of combustion the weight loss rate of the blends is much faster compared to thatmore » of the raw coke due to the higher volatile yield of rubber. The presence of rubber in the blends may have had an impact upon the structure during the release and combustion of their high volatile matter (VM) and hence increased char burnout. Measurements of micropore surface area and bulk density of the chars collected after combustion support the higher combustion efficiency of the blends in comparison to coke alone. The surface morphology of the 30% rubber blend revealed pores in the residual char that might be attributed to volatile evolution during high temperature reaction in oxygen atmosphere. Physical properties and VM appear to have a major effect upon the measured combustion efficiency of rubber blends. The study demonstrates that waste rubber tires can be successfully co-injected with metallurgical coke in electric arc furnace steelmaking process to provide additional energy from combustion. 44 refs., 11 figs., 2 tabs.« less

Developments in new aircraft tire tread materials. [fatigue life of elastomeric materials

NASA Technical Reports Server (NTRS)

Yager, T. J.; Mccarty, J. L.; Riccitiello, S. R.; Golub, M. A.

1976-01-01

Comparative laboratory and field tests were conducted on experimental and state-of-the-art aircraft tire tread materials in a program aimed at seeking new elastomeric materials which would provide improved aircraft tire tread wear, traction, and blowout resistance in the interests of operational safety and economy. The experimental stock was formulated of natural rubber and amorphous vinyl polybutadiene to provide high thermal-oxidative resistance, a characteristic pursued on the premise that thermal oxidation is involved both in the normal abrasion or wear of tire treads and probably in the chain of events leading to blowout failures. Results from the tests demonstrate that the experimental stock provided better heat buildup (hysteresis) and fatigue properties, at least equal wet and dry traction, and greater wear resistance than the state-of-the-art stock.

Industrywide studies report of an in-depth survey at Copolymer Rubber and Chemical Corporation, Baton Rouge, Louisiana

DOE Office of Scientific and Technical Information (OSTI.GOV)

Krishnan, E.R.; Fajen, J.M.

1987-05-08

An in depth industrial hygiene survey was conducted at the Copolymer Rubber and Chemical Corporation located in Baton Rouge, Louisiana. The facility produced styrene-butadiene rubber and nitrile-butadiene rubber by continuous emulsion polymerization. The ultimate use of this product was for the manufacture of tire and rubber products. The authors recommend that leaking pumps which can present a potential for 1,3-butadiene exposure in the tank farm and recovery areas should be controlled through the use of dual mechanical seals. Employees assigned to maintenance tasks should use respirators with organic vapor cartridges.

Tire-derived carbon composite anodes for sodium-ion batteries

NASA Astrophysics Data System (ADS)

Li, Yunchao; Paranthaman, M. Parans; Akato, Kokouvi; Naskar, Amit K.; Levine, Alan M.; Lee, Richard J.; Kim, Sang-Ok; Zhang, Jinshui; Dai, Sheng; Manthiram, Arumugam

2016-06-01

Hard-carbon materials are considered as one of the most promising anodes for the emerging sodium-ion batteries. Here, we report a low-cost, scalable waste tire-derived carbon as an anode for sodium-ion batteries (SIBs). Tire-derived carbons obtained by pyrolyzing acid-treated tire at 1100 °C, 1400 °C and 1600 °C show capacities of 179, 185 and 203 mAh g-1, respectively, after 100 cycles at a current density of 20 mA g-1 in sodium-ion batteries with good electrochemical stability. The portion of the low-voltage plateau region in the charge-discharge curves increases as the heat-treatment temperature increases. The low-voltage plateau is beneficial to enhance the energy density of the full cell. This study provides a new pathway for inexpensive, environmentally benign and value-added waste tire-derived products towards large-scale energy storage applications.

Ionic Modification Turns Commercial Rubber into a Self-Healing Material.

PubMed

Das, Amit; Sallat, Aladdin; Böhme, Frank; Suckow, Marcus; Basu, Debdipta; Wiessner, Sven; Stöckelhuber, Klaus Werner; Voit, Brigitte; Heinrich, Gert

2015-09-23

Invented by Charles Goodyear, chemical cross-linking of rubbers by sulfur vulcanization is the only method by which modern automobile tires are manufactured. The formation of these cross-linked network structures leads to highly elastic properties, which substantially reduces the viscous properties of these materials. Here, we describe a simple approach to converting commercially available and widely used bromobutyl rubber (BIIR) into a highly elastic material with extraordinary self-healing properties without using conventional cross-linking or vulcanising agents. Transformation of the bromine functionalities of BIIR into ionic imidazolium bromide groups results in the formation of reversible ionic associates that exhibit physical cross-linking ability. The reversibility of the ionic association facilitates the healing processes by temperature- or stress-induced rearrangements, thereby enabling a fully cut sample to retain its original properties after application of the self-healing process. Other mechanical properties, such as the elastic modulus, tensile strength, ductility, and hysteresis loss, were found to be superior to those of conventionally sulfur-cured BIIR. This simple and easy approach to preparing a commercial rubber with self-healing properties offers unique development opportunities in the field of highly engineered materials, such as tires, for which safety, performance, and longer fatigue life are crucial factors.

Acetylene from the co-pyrolysis of biomass and waste tires or coal in the H{sub 2}/Ar plasma

DOE Office of Scientific and Technical Information (OSTI.GOV)

Bao, W.; Cao, Q.; Lv, Y.

Acetylene from carbon-containing materials via plasma pyrolysis is not only simple but also environmentally friendly. In this article, the acetylene produced from co-pyrolyzing biomass with waste tire or coal under the conditions of H{sub 2}/Ar DC arc plasma jet was investigated. The experimental results showed that the co-pyrolysis of mixture with biomass and waste tire or coal can improve largely the acetylene relative volume fraction (RVF) in gaseous products and the corresponding yield of acetylene. The change trends for the acetylene yield of plasma pyrolysis from mixture with raw sample properties were the same as relevant RVF. But the yieldmore » change trend with feeding rate is different from its RVF. The effects of the feeding rate of raw materials and the electric current of plasmatron on acetylene formation are also discussed.« less

Treatment of screened dairy manure by upflow anaerobic fixed bed reactors packed with waste tyre rubber and a combination of waste tyre rubber and zeolite: effect of the hydraulic retention time.

PubMed

Umaña, Oscar; Nikolaeva, Svetlana; Sánchez, Enrique; Borja, Rafael; Raposo, Francisco

2008-10-01

Two laboratory-scale anaerobic fixed bed reactors were evaluated while treating dairy manure at upflow mode and semicontinuous feeding. One reactor was packed with a combination of waste tyre rubber and zeolite (R1) while the other had only waste tyre rubber as a microorganism immobilization support (R2). Effluent quality improved when the hydraulic retention time (HRT) increased from 1.0 to 5.5 days. Higher COD, BOD5, total and volatile solids removal efficiencies were always achieved in the reactor R1. No clogging was observed during the operation period. Methane yield was also a function of the HRT and of the type of support used, and was 12.5% and 40% higher in reactor R1 than in R2 for HRTs of 5.5 and 1.0 days, respectively. The results obtained demonstrated that this type of reactor is capable of operating with dairy manure at a HRT 5 times lower than that used in a conventional reactor.

Fly ash reinforced thermoplastic vulcanizates obtained from waste tire powder.

PubMed

Sridhar, V; Xiu, Zhang Zhen; Xu, Deng; Lee, Sung Hyo; Kim, Jin Kuk; Kang, Dong Jin; Bang, Dae-Suk

2009-03-01

Novel thermoplastic composites made from two major industrial and consumer wastes, fly ash and waste tire powder, have been developed. The effect of increasing fly ash loadings on performance characteristics such as tensile strength, thermal, dynamic mechanical and magnetic properties has been investigated. The morphology of the blends shows that fly ash particles have more affinity and adhesion towards the rubbery phase when compared to the plastic phase. The fracture surface of the composites shows extensive debonding of fly ash particles. Thermal analysis of the composites shows a progressive increase in activation energy with increase in fly ash loadings. Additionally, morphological studies of the ash residue after 90% thermal degradation shows extensive changes occurring in both the polymer and filler phases. The processing ability of the thermoplastics has been carried out in a Monsanto processability testing machine as a function of shear rate and temperature. Shear thinning behavior, typical of particulate polymer systems, has been observed irrespective of the testing temperatures. Magnetic properties and percolation behavior of the composites have also been evaluated.

Preparation and application of nanocrystalline cellulose derived from sugarcane waste as filler modified alkanolamide on crosslink of natural rubber latex film

NASA Astrophysics Data System (ADS)

Harahap, Hamidah; Hayat, Nuim; Lubis, Marfuah

2017-07-01

Sugarcane waste is abundant sources of cellulose and it has potential to reutilize. Cellulose from sugarcane waste can be derived into nanocystalline cellulose (NCC) from crystalline region. The NCC as a filler has capability to reinforce natural rubber latex product. The crosslink in vulcanized natural rubber latex film influences several properties of product. In this work, we extracted NCC from sugarcane waste then added into natural rubber latex as filler modified alkanolamide (ALK) and also studied the crosslink of natural rubber latex films. NCC were produced from sugarcane waste by hydrolysis process with sulfuric acid 45%. The obtained NCC was characterized by using x-ray diffraction (XRD), transmission electron microscopy (TEM), and fourier transform infra red (FTIR). NCC was modified by alkanolamide and dispersed in water with filler concentration of 10%. Then the dispersion were added into latex system followed by pre-vulcanization at 70 °C. The films were prepared by coagulant dipping method and dried at 100 °C and 120 °C for 20 minutes. Characterization of NCC from sugarcane waste by using FTIR was done, it clearly showed the functional groups of cellulose. TEM showed the obtained NCC were rod-shaped with about 40-160 nm in diameter and several hundred nm in length, and XRD showed that the degree of crystalinity of NCC from sugarcane waste is 92.33%. The crosslink of natural rubber films were studied by measure the crosslink density for different filler loading by using swelling measurement with toluene solution. The result show that the crosslink density increased in line with amount of filler which added into the system, and also the crosslink density that obtained from vulcanization at 120 °C were higher than 100 °C.

Reinforcement of SBR/waste rubber powder vulcanizate with in situ generated zinc dimethacrylate

NASA Astrophysics Data System (ADS)

Wang, X. P.; Cheng, B. K.; Zhang, X.; Jia, D. M.

2016-07-01

Methyl acrylic acid/zinc oxide (MAA/ZnO) was introduced to modify styrene- butadiene rubber/waste rubber powder (SBR/WRP) composites by blending. The enhanced mechanical properties and processing ability were presumably originated from improved compatibility and interfacial interaction between WRP and the SBR matrix by the in situ polymerization of zinc dimethacrylate (ZDMA). A refined interface of the modified SBR/WRP composite was observed by scanning electron microscopy. The formation of ZDMA significantly increased the ionic bond content in the vulcanizate, resulting in exceptional mechanical performance. The comprehensive mechanical properties including tensile strength, tear strength and dynamic heat-building performance reached optimum values with 16 phr MAA.

Study of montmorillonite nanoparticles and electron beam irradiation interaction of ethylene vinyl acetate (EVA)/de-vulcanized waste rubber thermoplastic composites

NASA Astrophysics Data System (ADS)

Bee, Soo-Tueen; Sin, Lee Tin; Hoe, Tie Teck; Ratnam, C. T.; Bee, Soo Ling; Rahmat, A. R.

2018-05-01

The purpose of this work was to investigate the effects of montmorillonite (MMT) loading level and electron beam irradiation on the physical-mechanical properties and thermal stability of ethylene vinyl acetate (EVA)- devulcanised waste rubber blends. The addition of MMT particles has significantly increased the d-spacing and interchain separation of deflection peak (0 0 2) of MMT particles. This indicates that MMT particles have effectively intercalated in polymer matrix of EVA-devulcanised waste rubber blends. Besides, the application of electron beam irradiation dosages <150 kGy could also significantly induce the effective intercalation effect of MMT particles in polymer matrix by introducing crosslinking networks. The increasing of electron beam irradiation dosages up to 250 kGy has gradually increased the gel content of all EVA-devulcanized rubber blends by inducing the formation of crosslinking networks in polymer matrix. Also, the tensile strength of all EVA-devulcanized waste rubber blends was gradually increased when irradiated up to 150 kGy. This is due to the occurrence of crosslinking networks by irradiation could significantly provide reinforcement effect to polymer matrix by effectively transferring the stress applied on polymer matrix throughout the whole polymer matrix.

Adsorptive removal of hydrophobic organic compounds by carbonaceous adsorbents: a comparative study of waste-polymer-based, coal-based activated carbon, and carbon nanotubes.

PubMed

Lian, Fei; Chang, Chun; Du, Yang; Zhu, Lingyan; Xing, Baoshan; Liu, Chang

2012-01-01

Adsorption of the hydrophobic organic compounds (HOCs) trichloroethylene (TCE), 1,3-dichlorobenzene (DCB), 1,3-dinitrobenzene (DNB) and gamma-hexachlorocyclohexane (HCH) on five different carbonaceous materials was compared. The adsorbents included three polymer-based activated carbons, one coal-based activated carbon (F400) and multiwalled carbon nanotubes (MWNT). The polymer-based activated carbons were prepared using KOH activation from waste polymers: polyvinyl chloride (PVC), polyethyleneterephthalate (PET) and tire rubber (TR). Compared with F400 and MWNT, activated carbons derived from PVC and PET exhibited fast adsorption kinetics and high adsorption capacity toward the HOCs, attributed to their extremely large hydrophobic surface area (2700 m2/g) and highly mesoporous structures. Adsorption of small-sized TCE was stronger on the tire-rubber-based carbon and F400 resulting from the pore-filling effect. In contrast, due to the molecular sieving effect, their adsorption on HCH was lower. MWNT exhibited the lowest adsorption capacity toward HOCs because of its low surface area and characteristic of aggregating in aqueous solution.

The reclaiming of butyl rubber and in-situ compatibilization of thermoplastic elastomer by power ultrasound

NASA Astrophysics Data System (ADS)

Feng, Wenlai

This is a study of the continuous ultrasound aided extrusion process for the in-situ compatibilization of isotactic polypropylene (iPP)/ethylene-propylene diene rubber (EPDM) thermoplastic elastomer (TPE) using a newly developed ultrasonic treatment reactor. The rheological, mechanical properties and morphology of the TPE with and without ultrasonic treatment were studied. In-situ compatibilization in the ultrasonically treated blends was observed as evident by their more stable morphology after annealing, improved mechanical properties and IR spectra. The obtained results indicated that ultrasonic treatment induced the thermo-mechanical degradations and led to the possibility of enhanced molecular transport and chemical reactions at the interfaces. Processing conditions were established for enhanced in situ compatibilization of the PP/EPDM TPE. The ultrasonic treatments of butyl rubber gum and ultrasonic devulcanization of butyl rubber, tire-curing bladder during extrusion using a grooved barrel ultrasonic reactor were carried out. The ultrasonic treatment of gum caused degradation of the polymer main chain leading to lower molecular weight, broader molecular weight distribution, less unsaturation and changes in physical properties. The devulcanization of butyl rubber was successfully accomplished only at severe conditions of ultrasonic treatment. The mechanical properties of vulcanizates prepared from devulcanized butyl rubber are comparable to that of the virgin vulcanizate. The molecular characterization of sol fraction of devulcanized butyl rubber showed the devulcanization and degradation of butyl rubber occurred simultaneously. 1H NMR transverse relaxation was also used to study butyl rubber gum before and after ultrasonic treatment, and ultrasonically devulcanized unfilled butyl rubber. The T2 relaxation decays were successfully described using a two-component model. The recyclability of tire-curing bladder was also investigated. Gel fraction, crosslink

40 CFR 63.5994 - How do I conduct tests and procedures for tire production affected sources?

Code of Federal Regulations, 2011 CFR

2011-07-01

... PROTECTION AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED) NATIONAL EMISSION STANDARDS FOR HAZARDOUS AIR POLLUTANTS FOR SOURCE CATEGORIES National Emissions Standards for Hazardous Air Pollutants: Rubber Tire... mass percent of HAP in cements and solvents. To determine the HAP content in the cements and solvents...

High performance graphene oxide based rubber composites.

PubMed

Mao, Yingyan; Wen, Shipeng; Chen, Yulong; Zhang, Fazhong; Panine, Pierre; Chan, Tung W; Zhang, Liqun; Liang, Yongri; Liu, Li

2013-01-01

In this paper, graphene oxide/styrene-butadiene rubber (GO/SBR) composites with complete exfoliation of GO sheets were prepared by aqueous-phase mixing of GO colloid with SBR latex and a small loading of butadiene-styrene-vinyl-pyridine rubber (VPR) latex, followed by their co-coagulation. During co-coagulation, VPR not only plays a key role in the prevention of aggregation of GO sheets but also acts as an interface-bridge between GO and SBR. The results demonstrated that the mechanical properties of the GO/SBR composite with 2.0 vol.% GO is comparable with those of the SBR composite reinforced with 13.1 vol.% of carbon black (CB), with a low mass density and a good gas barrier ability to boot. The present work also showed that GO-silica/SBR composite exhibited outstanding wear resistance and low-rolling resistance which make GO-silica/SBR very competitive for the green tire application, opening up enormous opportunities to prepare high performance rubber composites for future engineering applications.

Microstructure characterization of multi-phase composites and utilization of phase change materials and recycled rubbers in cementitious materials

NASA Astrophysics Data System (ADS)

Meshgin, Pania

2011-12-01

This research focuses on two important subjects: (1) Characterization of heterogeneous microstructure of multi-phase composites and the effect of microstructural features on effective properties of the material. (2) Utilizations of phase change materials and recycled rubber particles from waste tires to improve thermal properties of insulation materials used in building envelopes. Spatial pattern of multi-phase and multidimensional internal structures of most composite materials are highly random. Quantitative description of the spatial distribution should be developed based on proper statistical models, which characterize the morphological features. For a composite material with multi-phases, the volume fraction of the phases as well as the morphological parameters of the phases have very strong influences on the effective property of the composite. These morphological parameters depend on the microstructure of each phase. This study intends to include the effect of higher order morphological details of the microstructure in the composite models. The higher order statistics, called two-point correlation functions characterize various behaviors of the composite at any two points in a stochastic field. Specifically, correlation functions of mosaic patterns are used in the study for characterizing transport properties of composite materials. One of the most effective methods to improve energy efficiency of buildings is to enhance thermal properties of insulation materials. The idea of using phase change materials and recycled rubber particles such as scrap tires in insulation materials for building envelopes has been studied.

Study of the use of truck tire beads as drainage pipe and analysis of the economics of tire disposal in Oklahoma. Part 1. Culverts. Final report

DOE Office of Scientific and Technical Information (OSTI.GOV)

Everett, J.W.; Gattis, J.L.

1994-07-01

In an attempt to find alternate ways of dealing with waste truck tires, a private tire recycling company developed a pipe from the tire bead and sidewall. The tire-pipe has seen limited use as a roadway drainage culvert. To encourage wider use of this product, an evaluation of pipe performance was performed. The evaluation consisted of (1) inspections of existing installations; (2) structural tests; and (3) leakage tests. The study found that the majority of installations were performing well. Compared with corrugated steel and fiberglass pipes, the tire-pipe exhibited favorable structural performance. An individual tire-pipe section was found to bemore » watertight. However, when tested in the open-air (not in the ground), the tire-pipe joints were found to leak. Development of an improved end connection would improve the utility of the tire-pipe.« less

Federal Research Action Plan on Recycled Tire Crumb Used on Playing Fields and Playgrounds: Status Report

EPA Science Inventory

Over the past several years, parents, athletes, schools, and communities have raised concerns about the safety of recycled tire crumb rubber used as infill for playing fields and playgrounds in the United States. The public has expressed concerns that the use of these fields coul...

Tire traces - discrimination and classification of pyrolysis-GC/MS profiles.

PubMed

Gueissaz, Line; Massonnet, Geneviève

2013-07-10

Tire traces can be observed on several crime scenes as vehicles are often used by criminals. The tread abrasion on the road, while braking or skidding, leads to the production of small rubber particles which can be collected for comparison purposes. This research focused on the statistical comparison of Py-GC/MS profiles of tire traces and tire treads. The optimisation of the analytical method was carried out using experimental designs. The aim was to determine the best pyrolysis parameters regarding the repeatability of the results. Thus, the pyrolysis factor effect could also be calculated. The pyrolysis temperature was found to be five time more important than time. Finally, a pyrolysis at 650°C during 15s was selected. Ten tires of different manufacturers and models were used for this study. Several samples were collected on each tire, and several replicates were carried out to study the variability within each tire (intravariability). More than eighty compounds were integrated for each analysis and the variability study showed that more than 75% presented a relative standard deviation (RSD) below 5% for the ten tires, thus supporting a low intravariability. The variability between the ten tires (intervariability) presented higher values and the ten most variant compounds had a RSD value above 13%, supporting their high potential of discrimination between the tires tested. Principal Component Analysis (PCA) was able to fully discriminate the ten tires with the help of the first three principal components. The ten tires were finally used to perform braking tests on a racetrack with a vehicle equipped with an anti-lock braking system. The resulting tire traces were adequately collected using sheets of white gelatine. As for tires, the intravariability for the traces was found to be lower than the intervariability. Clustering methods were carried out and the Ward's method based on the squared Euclidean distance was able to correctly group all of the tire traces

A Study of a Super-Cooling Technique for Removal of Rubber from Solid-Rubber Tires.

DTIC Science & Technology

environmental pollution . In answering these questions, an experiment is conducted to validate the concept and to determine liquid...is performed to compare the costs of the super-cooling technique with those of the brake drum lathe method of rubber removal. Safety and environmental pollution factors are also investigated and

Tire-derived carbon composite anodes for sodium-ion batteries

DOE PAGES

Li, Yunchao; Paranthaman, M. Parans; Akato, Kokouvi; ...

2016-04-04

We report that hard-carbon materials are considered as one of the most promising anodes for the emerging sodium-ion batteries. Here, we report a low-cost, scalable waste tire-derived carbon as an anode for sodium-ion batteries (SIBs). The tire-derived carbons obtained by pyrolyzing the acid-treated tire at 1100 °C, 1400 °C and 1600 °C show capacities of 179, 185 and 203 mAh g -1, respectively, after 100 cycles at a current density of 20 mA g -1 in sodium-ion batteries with good electrochemical stability. The portion of the low-voltage plateau region in the charge-discharge curves increases as the heat-treatment temperature increases. Themore » low-voltage plateau is beneficial to enhance the energy density of the full cell. However, this plateau suffers rapid capacity fade at higher current densities. This study provides a new pathway for inexpensive, environmentally benign and value-added waste tire-derived products towards large-scale energy storage applications.« less

Quality improvement of pyrolysis oil from waste rubber by adding sawdust.

PubMed

Wang, Wen-liang; Chang, Jian-min; Cai, Li-ping; Shi, Sheldon Q

2014-12-01

This work was aimed at improving the pyrolysis oil quality of waste rubber by adding larch sawdust. Using a 1 kg/h stainless pyrolysis reactor, the contents of sawdust in rubber were gradually increased from 0%, 50%, 100% and 200% (wt%) during the pyrolysis process. Using a thermo-gravimetric (TG) analyzer coupled with Fourier transform infrared (FTIR) analysis of evolving products (TG-FTIR), the weight loss characteristics of the heat under different mixtures of sawdust/rubber were observed. Using the pyrolysis-gas chromatography (GC)-mass spectrometry (Py-GC/MS), the vapors from the pyrolysis processes were collected and the compositions of the vapors were examined. During the pyrolysis process, the recovery of the pyrolysis gas and its composition were measured in-situ at a reaction temperature of 450 °C and a retaining time of 1.2s. The results indicated that the efficiency of pyrolysis was increased and the residual carbon was reduced as the percentage of sawdust increased. The adding of sawdust significantly improved the pyrolysis oil quality by reducing the polycyclic aromatic hydrocarbons (PAHs) and nitrogen and sulfur compounds contents, resulting in an improvement in the combustion efficiency of the pyrolysis oil. Copyright © 2014 Elsevier Ltd. All rights reserved.

Quality improvement of pyrolysis oil from waste rubber by adding sawdust

DOE Office of Scientific and Technical Information (OSTI.GOV)

Wang, Wen-liang; Chang, Jian-min, E-mail: cjianmin@bjfu.edu.cn; Cai, Li-ping

Highlights: • Rubber-pyrolysis oil is difficult to be fuel due to high proportion of PAHs. • The efficiency of pyrolysis was increased as the percentage of sawdust increased. • The adding of sawdust improved pyrolysis oil quality by reducing the PAHs content. • Adding sawdust reduced nitrogen/sulfur in oil and was easier to convert to diesel. - Abstract: This work was aimed at improving the pyrolysis oil quality of waste rubber by adding larch sawdust. Using a 1 kg/h stainless pyrolysis reactor, the contents of sawdust in rubber were gradually increased from 0%, 50%, 100% and 200% (wt%) during themore » pyrolysis process. Using a thermo-gravimetric (TG) analyzer coupled with Fourier transform infrared (FTIR) analysis of evolving products (TG–FTIR), the weight loss characteristics of the heat under different mixtures of sawdust/rubber were observed. Using the pyrolysis–gas chromatography (GC)–mass spectrometry (Py–GC/MS), the vapors from the pyrolysis processes were collected and the compositions of the vapors were examined. During the pyrolysis process, the recovery of the pyrolysis gas and its composition were measured in-situ at a reaction temperature of 450 °C and a retaining time of 1.2 s. The results indicated that the efficiency of pyrolysis was increased and the residual carbon was reduced as the percentage of sawdust increased. The adding of sawdust significantly improved the pyrolysis oil quality by reducing the polycyclic aromatic hydrocarbons (PAHs) and nitrogen and sulfur compounds contents, resulting in an improvement in the combustion efficiency of the pyrolysis oil.« less

Characterization of carbon silica hybrid fillers obtained by pyrolysis of waste green tires by the STEM–EDX method

DOE Office of Scientific and Technical Information (OSTI.GOV)

Al-Hartomy, Omar A.; Department of Physics, Faculty of Science, University of Tabuk, Tabuk 71491; Al-Ghamdi, Ahmed A.

2015-03-15

Dual phase carbon–silica hybrid fillers obtained by pyrolysis-cum-water vapor of waste green tires have been characterized by energy dispersive X-ray spectroscopy in a scanning transmission electron microscope, silicate analysis, weight analysis, atomic absorption spectroscopy and by inductively coupled plasma–optical emission spectroscopy. The results achieved have shown that the location and distribution of the phases in the carbon silica hybrid fillers as well as their most essential characteristics are influenced by the pyrolysis conditions. The carbon phase of the filler thus obtained is located predominantly in the space among silica aggregates which have already been existing while it has been formedmore » by elastomer destruction in the course of pyrolysis. The presence of ZnS also has been found in the hybrid fillers investigated. - Highlights: • Dual phase fillers obtained by pyrolysis of waste green tires have been characterized. • The STEM–EDX method was used for characterization. • The phase distributions in the fillers are influenced by the pyrolysis conditions.« less

Study of Rubber Composites with Positron Doppler Broadening Spectroscopy: Consideration of Counting Rate

NASA Astrophysics Data System (ADS)

Yang, Chun; Quarles, C. A.

2007-10-01

We have used positron Doppler Broadening Spectroscopy (DBS) to investigate the uniformity of rubber-carbon black composite samples. The amount of carbon black added to a rubber sample is characterized by phr, the number of grams of carbon black per hundred grams of rubber. Typical concentrations in rubber tires are 50 phr. It has been shown that the S parameter measured by DBS depends on the phr of the sample, so the variation in carbon black concentration can be easily measured to 0.5 phr. In doing the experiments we observed a dependence of the S parameter on small variation in the counting rate or deadtime. By carefully calibrating this deadtime correction we can significantly reduce the experimental run time and thus make faster determination of the uniformity of extended samples.

Soft matter: rubber and networks

NASA Astrophysics Data System (ADS)

McKenna, Gregory B.

2018-06-01

Rubber networks are important and form the basis for materials with properties ranging from rubber tires to super absorbents and contact lenses. The development of the entropy ideas of rubber deformation thermodynamics provides a powerful framework from which to understand and to use these materials. In addition, swelling of the rubber in the presence of small molecule liquids or solvents leads to materials that are very soft and ‘gel’ like in nature. The review covers the thermodynamics of polymer networks and gels from the perspective of the thermodynamics and mechanics of the strain energy density function. Important relationships are presented and experimental results show that the continuum ideas contained in the phenomenological thermodynamics are valid, but that the molecular bases for some of them remain to be fully elucidated. This is particularly so in the case of the entropic gels or swollen networks. The review is concluded with some perspectives on other networks, ranging from entropic polymer networks such as thermoplastic elastomers to physical gels in which cross-link points are formed by glassy or crystalline domains. A discussion is provided for other physical gels in which the network forms a spinodal-like decomposition, both in thermoplastic polymers that form a glassy network upon phase separation and for colloidal gels that seem to have a similar behavior.

77 FR 3031 - The Goodyear Tire & Rubber Company, Grant of Petition for Decision of Inconsequential Noncompliance

Federal Register 2010, 2011, 2012, 2013, 2014

2012-01-20

... inconsequentiality to motor vehicle safety in this case is that there is no effect of the noncompliances on the... retread, repair and recycling industries must also be considered. Although tire construction affects the... labeling of the tire construction information will have an inconsequential effect on motor vehicle safety...

Investigation of improved compaction by rubber-tire rollers : final report.

DOT National Transportation Integrated Search

1987-01-01

The study consisted of a review of the literature and field testing on five projects. The field testing on each project consisted of rolling a conventional section using the contractor's steel-wheel rollers and rolling a test section using a rubber-t...

Application of tire chips to reduce the temperature of secondary geomembranes in municipal solid waste landfills.

PubMed

Hoor, Azadeh; Rowe, R Kerry

2012-05-01

Heat generated by the biodegradation of waste and other chemical processes in a landfill can potentially affect the long-term performance of landfill liner system, in particular that of a high-density polyethylene geomembrane. In a double liner system, the difference in leachate exposure and temperature might improve the long-term performance of the secondary geomembrane compared to that of the primary geomembrane. However, in some cases, the temperature is likely to be high enough to substantially reduce the service-life of the secondary geomembrane. This study explores the possible effectiveness of using tire chips as thermal insulation between primary and secondary liners to reduce the temperature of secondary geomembranes as compared to traditional soil materials. Heat and contaminant migration analyses are performed for cases with no insulation and for cases in which a layer of soil or tire chips has been used as thermal insulation between the primary and secondary liners. The effect of insulation on prolonging the service-life of a secondary geomembrane and, consequently, on contaminant transport through a liner system is examined for the case of a volatile organic compound (dichloromethane) found in landfill leachate. The study suggests that the use of tire chips warrants consideration, however there are other practical issues that require consideration in the detailed design and construction of landfill liners. Issues such as finite service-life, low working temperature, excessive settlement, ability to generate internal heat, leaching of tire chips and limitations in performing electrical resistivity leak detection tests are identified. Copyright © 2012 Elsevier Ltd. All rights reserved.

76 FR 73007 - Goodyear Tire and Rubber Company, Grant of Petition for Decision of Inconsequential Noncompliance

Federal Register 2010, 2011, 2012, 2013, 2014

2011-11-28

... measurable effect on the safety of the tire retread, repair, and recycling industries. The use of steel cord... true measure of inconsequentiality to motor vehicle safety in this case is that there is no effect of... safety of people working in the tire retread, repair, and recycling industries must also be considered...

78 FR 64913 - Certain New Pneumatic Off-the-Road Tires From the People's Republic of China: Initiation of...

Federal Register 2010, 2011, 2012, 2013, 2014

2013-10-30

.... (``Leo Rubber''), a separate-rate respondent in the original investigation. DATES: Effective: October 30... Uruguay Round Agreements Act (``URAA''), regarding the antidumping duty investigation on OTR Tires from... determination, the Department typically examines several factors including, but not limited to, changes in: (1...

Adsorption of mercury by carbonaceous adsorbents prepared from rubber of tyre wastes.

PubMed

Manchón-Vizuete, E; Macías-García, A; Nadal Gisbert, A; Fernández-González, C; Gómez-Serrano, V

2005-03-17

Rubber from tyre wastes has been used to prepare carbonaceous adsorbents and the products obtained have been tested as adsorbents for mercury in aqueous solution. The adsorbents have been prepared by applying thermal, chemical and combined (thermal and chemical or vice versa) treatments. Tyre rubber has been: heated at 400 or 900 degrees C for 2 h in N2, chemically-treated with H2SO4, HNO3 or H2SO4/HNO3 solution for 24 h, and in two successive steps first heated at 400 degrees C for 2h in N2 and then treated with a H2SO4/HNO3 solution for 24 h, or vice versa. Resultant products have been characterised in terms of elementary composition and textural properties. The adsorption of mercury has been studied from kinetic and equilibrium standpoints. The treatments effected to tyre rubber decrease the carbon content and the hydrogen content. The oxygen content and the nitrogen content increase for the chemically-treated products. The heat treatment of tyre rubber results in a larger development of surface area, microporosity, and mesoporosity than the chemical treatments. These treatments, however, produce a great creation of macropores. In comparison to the starting rubber, the adsorption process of mercury is faster when the material is heated or treated with the H2SO4, HNO3 or 1:3 H2SO4/HNO3 solution. These adsorbents are either a non-porous solid or possess a high mesopore volume or a wide pore size distribution in the macropore range. The adsorption capacity is larger for products prepared by heat, chemical and combined treatments of the rubber. A common textural characteristic of these adsorbents is their better developed microporosity. The ability to adsorb mercury is higher for the heated products than for the chemically-treated ones. The maximum adsorption of mercury is 211 mg g(-1). The constant Kf of the Freundlich equation is as high as 108.9 mg g(-1).

Some functional properties of composite material based on scrap tires

NASA Astrophysics Data System (ADS)

Plesuma, Renate; Malers, Laimonis

2013-09-01

The utilization of scrap tires still obtains a remarkable importance from the aspect of unloading the environment from non-degradable waste [1]. One of the most prospective ways for scrap tires reuse is a production of composite materials [2] This research must be considered as a continuation of previous investigations [3, 4]. It is devoted to the clarification of some functional properties, which are considered important for the view of practical applications, of the composite material. Some functional properties of the material were investigated, for instance, the compressive stress at different extent of deformation of sample (till 67% of initial thickness) (LVS EN 826) [5] and the resistance to UV radiation (modified method based on LVS EN 14836) [6]. Experiments were realized on the purposefully selected samples. The results were evaluated in the correlation with potential changes of Shore C hardness (Shore scale, ISO 7619-1, ISO 868) [7, 8]. The results showed noticeable resistance of the composite material against the mechanical influence and ultraviolet (UV) radiation. The correlation with the composition of the material, activity of binder, definite technological parameters, and the conditions supported during the production, were determined. It was estimated that selected properties and characteristics of the material are strongly dependent from the composition and technological parameters used in production of the composite material, and from the size of rubber crumb. Obtained results show possibility to attain desirable changes in the composite material properties by changing both the composition and technological parameters of examined material.

75 FR 36472 - Goodyear Tire and Rubber Company, Receipt of Petition for Decision of Inconsequential Noncompliance

Federal Register 2010, 2011, 2012, 2013, 2014

2010-06-25

... below the tire surface not less than 0.015 inches * * * (f) The actual number of plies in the sidewall, and the actual number of plies in the tread area, if different * * * Goodyear explains that the... incorrectly describes the actual number of plies in the tread area of the tires as required by paragraph S5.5...

A kinematically driven anisotropic viscoelastic constitutive model applied to tires

NASA Technical Reports Server (NTRS)

Johnson, Arthur R.; Tanner, John A.; Mason, Angela J.

1995-01-01

Aircraft tires are composite structures manufactured with viscoelastic materials such as carbon black filled rubber and nylon cords. When loaded they experience large deflections and moderately large strains. Detailed structural models of tires require the use of either nonlinear shell or nonlinear three dimensional solid finite elements. Computational predictions of the dynamic response of tires must consider the composite viscoelastic material behavior in a realistic fashion. We describe a modification to a nonlinear anisotropic shell finite element so it can be used to model viscoelastic stresses during general deformations. The model is developed by introducing internal variables of the type used to model elastic strain energy. The internal variables are strains, curvatures, and transverse shear angles which are in a one-to-one correspondence with the generalized coordinates used to model the elastic strain energy for nonlinear response. A difference-relaxation equation is used to relate changes in the observable strain field to changes in the internal strain field. The internal stress state is introduced into the equilibrium equations by converting it to nodal loads associated with the element's displacement degrees of freedom. In this form the tangent matrix in the Newton-Raphson solution algorithm is not modified from its form for the nonlinear statics problem. Only the gradient vector is modified and the modification is not computationally costly. The existing finite element model for the Space Shuttle nose gear tire is used to provide examples of the algorithm. In the first example, the tire's rim is displaced at a constant rate up to a fixed value. In the second example, the tire's rim is enforced to follow a saw tooth load and unload curve to generate hysteresis loops.

A kinematically driven anisotropic viscoelastic constitutive model applied to tires

NASA Astrophysics Data System (ADS)

Johnson, Arthur R.; Tanner, John A.; Mason, Angela J.

1995-08-01

Aircraft tires are composite structures manufactured with viscoelastic materials such as carbon black filled rubber and nylon cords. When loaded they experience large deflections and moderately large strains. Detailed structural models of tires require the use of either nonlinear shell or nonlinear three dimensional solid finite elements. Computational predictions of the dynamic response of tires must consider the composite viscoelastic material behavior in a realistic fashion. We describe a modification to a nonlinear anisotropic shell finite element so it can be used to model viscoelastic stresses during general deformations. The model is developed by introducing internal variables of the type used to model elastic strain energy. The internal variables are strains, curvatures, and transverse shear angles which are in a one-to-one correspondence with the generalized coordinates used to model the elastic strain energy for nonlinear response. A difference-relaxation equation is used to relate changes in the observable strain field to changes in the internal strain field. The internal stress state is introduced into the equilibrium equations by converting it to nodal loads associated with the element's displacement degrees of freedom. In this form the tangent matrix in the Newton-Raphson solution algorithm is not modified from its form for the nonlinear statics problem. Only the gradient vector is modified and the modification is not computationally costly. The existing finite element model for the Space Shuttle nose gear tire is used to provide examples of the algorithm. In the first example, the tire's rim is displaced at a constant rate up to a fixed value. In the second example, the tire's rim is enforced to follow a saw tooth load and unload curve to generate hysteresis loops.

High Performance Graphene Oxide Based Rubber Composites

PubMed Central

Mao, Yingyan; Wen, Shipeng; Chen, Yulong; Zhang, Fazhong; Panine, Pierre; Chan, Tung W.; Zhang, Liqun; Liang, Yongri; Liu, Li

2013-01-01

In this paper, graphene oxide/styrene-butadiene rubber (GO/SBR) composites with complete exfoliation of GO sheets were prepared by aqueous-phase mixing of GO colloid with SBR latex and a small loading of butadiene-styrene-vinyl-pyridine rubber (VPR) latex, followed by their co-coagulation. During co-coagulation, VPR not only plays a key role in the prevention of aggregation of GO sheets but also acts as an interface-bridge between GO and SBR. The results demonstrated that the mechanical properties of the GO/SBR composite with 2.0 vol.% GO is comparable with those of the SBR composite reinforced with 13.1 vol.% of carbon black (CB), with a low mass density and a good gas barrier ability to boot. The present work also showed that GO-silica/SBR composite exhibited outstanding wear resistance and low-rolling resistance which make GO-silica/SBR very competitive for the green tire application, opening up enormous opportunities to prepare high performance rubber composites for future engineering applications. PMID:23974435

Requirements for energy based constitutive modeling in tire mechanics

NASA Technical Reports Server (NTRS)

Luchini, John R.; Peters, Jim M.; Mars, Will V.

1995-01-01

The history, requirements, and theoretical basis of a new energy based constitutive model for (rubber) material elasticity, hysteresis, and failure are presented. Energy based elasticity is handled by many constitutive models, both in one dimension and in three dimensions. Conversion of mechanical energy to heat can be modeled with viscoelasticity or as structural hysteresis. We are seeking unification of elasticity, hysteresis, and failure mechanisms such as fatigue and wear. An energy state characterization for failure criteria of (rubber) materials may provide this unification and also help explain the interaction of temperature effects with failure mechanisms which are described as creation of growth of internal crack surface. Improved structural modeling of tires with FEM should result from such a unified constitutive theory. The theory will also guide experimental work and should enable better interpretation of the results of computational stress analyses.

Evaluating the Rheological Properties of Waste Natural Rubber Latex Modified Binder

NASA Astrophysics Data System (ADS)

Khatijah Abu Bakar, Siti; Ezree Abdulah, Mohd; Mustafa Kamal, Mazlina; Rahman, Raha Abd; Arifin Hadithon, Kamarul; Buhari, Rosnawati; Tajudin, Saiful Azhar Ahmad

2018-03-01

Road surface is designed to be the durable surface material to sustain the traffic loading. However, due to physical and mechanical stress, pavement deterioration is accelerated. Thus, modifying conventional bitumen by improving its properties is seen as the best method to prolong pavement in-service life. The purpose of this paper is to study the effect of waste natural rubber (NR) latex on rheological properties of bitumen. Conventional bitumen PEN 80/100 was modified with different content of waste NR latex using a high shear mixer at temperature of 150°C. The modified binder properties were characterized by conducting physical test (i.e. softening point, penetration and penetration index) and rheological test (i.e. dynamic shear rheometer, DSR). Results showed that, the addition of waste NR latex improved the rheology properties, which indicates by improving of rutting factor (G*/sin δ). This properties improvement has also shows a potential to resist deformation on road surface despite of high traffic loading.

MUTAGENICITY OF EMISSIONS FROM THE SIMULATED OPEN BURNING OF SCRAP RUBBER TIRES

EPA Science Inventory

The report describes a follow-up to a small-scale combustion study to collect, identify, and quantify products emitted during the simulated open combustion of scrap tires. The initial study found that total estimated emissions of semi-volatile organics ranged from 10 to 50 g/kg o...

75 FR 32158 - New Pneumatic Off-the-Road Tires from the People's Republic of China: Extension of Preliminary...

Federal Register 2010, 2011, 2012, 2013, 2014

2010-06-07

..., 2010, Tianjin United Tire & Rubber International Co., Ltd. (``TUTRIC''), a mandatory respondent... deadlines by seven calendar days due to closure of federal government offices in February 2010 from a...: Tolling of Administrative Deadlines As A Result of the Government Closure During the Recent Snowstorm...

A review on using crumb rubber in reinforcement of asphalt pavement.

PubMed

Mashaan, Nuha Salim; Ali, Asim Hassan; Karim, Mohamed Rehan; Abdelaziz, Mahrez

2014-01-01

An immense problem affecting environmental pollution is the increase of waste tyre vehicles. In an attempt to decrease the magnitude of this issue, crumb rubber modifier (CRM) obtained from waste tyre rubber has gained interest in asphalt reinforcement. The use of crumb rubber in the reinforcement of asphalt is considered as a smart solution for sustainable development by reusing waste materials, and it is believed that crumb rubber modifier (CRM) could be an alternative polymer material in improving hot mix asphalt performance properties. In this paper, a critical review on the use of crumb rubber in reinforcement of asphalt pavement will be presented and discussed. It will also include a review on the effects of CRM on the stiffness, rutting, and fatigue resistance of road pavement construction.

LSRA STS Tire Test - on rim

NASA Technical Reports Server (NTRS)

1995-01-01

From 1993 to 1995, in conjunction with other NASA centers, NASA Dryden Flight Research Center, Edwards, California, used a Convair CV-990 airplane as a Landing Systems Research Aircraft (LSRA) to perform Space Shuttle tire tests. The results provided the Space Shuttle Program with data to support its flight rules and enabled it to resurface a grooved runway at Kennedy Space Center that had added unnecessary wear to the Space Shuttle tires. Tests were done using a unique fixture mounted in the center of the CV-990 fuselage, between the main landing gear. Landing gear systems from other aircraft could be attached to the test fixture, which lowered them to the runway surface during actual landings. The LSRA had the ability to reproduce the loads and speeds of the other aircraft, as well as simulate crosswind landing conditions in a safe, controlled environment. The video clip shows a landing on the concrete runway at Edwards, California on August 11, 1995, which concluded the Space Shuttle gear research program. As the Space Shuttle tire was lowered onto the surface, it was destroyed almost instantly. The rim scraped on the concrete, and stopped rolling as it became flat. It heated up and left a flaming trail of hot rubber and aluminum alloy particles. Notice how the fire quickly went out as the test gear was raised, indicating a safer condition than prevailed in a lakebed landing.

Rubber Impact on 3D Textile Composites

NASA Astrophysics Data System (ADS)

Heimbs, Sebastian; Van Den Broucke, Björn; Duplessis Kergomard, Yann; Dau, Frederic; Malherbe, Benoit

2012-06-01

A low velocity impact study of aircraft tire rubber on 3D textile-reinforced composite plates was performed experimentally and numerically. In contrast to regular unidirectional composite laminates, no delaminations occur in such a 3D textile composite. Yarn decohesions, matrix cracks and yarn ruptures have been identified as the major damage mechanisms under impact load. An increase in the number of 3D warp yarns is proposed to improve the impact damage resistance. The characteristic of a rubber impact is the high amount of elastic energy stored in the impactor during impact, which was more than 90% of the initial kinetic energy. This large geometrical deformation of the rubber during impact leads to a less localised loading of the target structure and poses great challenges for the numerical modelling. A hyperelastic Mooney-Rivlin constitutive law was used in Abaqus/Explicit based on a step-by-step validation with static rubber compression tests and low velocity impact tests on aluminium plates. Simulation models of the textile weave were developed on the meso- and macro-scale. The final correlation between impact simulation results on 3D textile-reinforced composite plates and impact test data was promising, highlighting the potential of such numerical simulation tools.

Chrome-tanned leather shavings as a filler of butadiene-acrylonitrile rubber.

PubMed

Przepiórkowska, A; Chrońska, K; Zaborski, M

2007-03-06

The noxious wastes from the tanning industry such as chrome-tanned leather shavings were used as the only filler of rubber mixes containing carboxylated butadiene-acrylonitrile rubber (XNBR) or butadiene-acrylonitrile rubber (NBR), and a dispersing agent Limanol PEV (Schill & Seilacher). The best form addition of leather powder to the rubber mixes is mixed the waste protein with zinc oxide. The leather powder added to the rubber mixes improves the mechanical properties: tensile strength (T(s)), elongation at break (epsilon(b)) and increase the cross-linking density of carboxylated XNBR and NBR rubber mixes. Satisfactory results of these studies are presented in this work.

Polybutadiene and Styrene-Butadiene rubbers for high-dose dosimetry

DOE Office of Scientific and Technical Information (OSTI.GOV)

Oliveira, Lucas N.; Instituto de Pesquisas Energeticas e Nucleares -IPEN, Sao Paulo-SP; Vieira, Silvio L.

2015-07-01

Polybutadiene and Styrene-Butadiene are synthetical rubbers used widely for pneumatic tires manufacturing. In this research, the dosimeter characteristics of those rubbers were studied for application in high-dose dosimetry. The rubber samples were irradiated with doses of 10 Gy up to 10 kGy, using a {sup 60}Co Gamma Cell-220 system (dose rate of 1.089 kGy/h) and their readings were taken on a Fourier Transform Infrared Spectroscopy-FTIR system (model Frontier/Perkin Elmer). The ratios of two absorbance peaks were taken for each kind of rubber spectrum, Polybutadiene (1306/1130 cm{sup -1}) and Styrene-Butadiene (1449/1306 cm{sup -1}). The ratio calculated was used as the responsemore » to the irradiation, and is not uniform across the sample. From the results, it can be concluded for both rubbers: a) the dose-response curves may be useful for high-dose dosimetry (greater than 250 Gy); b) their response for reproducibility presented standard deviations lower than 2.5%; c) the relative sensitivity was higher for Styrene-Butadiene (1.86 kGy{sup -1}) than for Polybutadiene (1.81 kGy{sup -1}), d) for doses of 10 kGy to 200 kGy, there was no variation in the dosimetric response. Both types of rubber samples showed usefulness as high-dose dosimeters. (authors)« less

Effect of gamma irradiation on ethylene propylene diene terpolymer rubber composites

NASA Astrophysics Data System (ADS)

Abou Zeid, M. M.; Rabie, S. T.; Nada, A. A.; Khalil, A. M.; Hilal, R. H.

2008-01-01

Composites of ethylene propylene dine terpolymer rubber (EPDM), high density polyethylene (HDPE) and ground tire rubber powder (GTR) at different ratios were subjected to gamma irradiation at various doses up to 250 kGy. The physical, mechanical and thermal properties were investigated as a function of irradiation dose and blend composition. Gamma irradiation led to a significant improvement in the properties for all blend compositions. The results indicate that the improvement in properties is inversely proportional to the substituted ratio of GTR, attributed to the development of an interfacial adhesion between GTR and blend components. The results were confirmed by examining the fracture surfaces by scanning electron microscopy.

Hybrid waste filler filled bio-polymer foam composites for sound absorbent materials

NASA Astrophysics Data System (ADS)

Rus, Anika Zafiah M.; Azahari, M. Shafiq M.; Kormin, Shaharuddin; Soon, Leong Bong; Zaliran, M. Taufiq; Ahraz Sadrina M. F., L.

2017-09-01

Sound absorption materials are one of the major requirements in many industries with regards to the sound insulation developed should be efficient to reduce sound. This is also important to contribute in economically ways of producing sound absorbing materials which is cheaper and user friendly. Thus, in this research, the sound absorbent properties of bio-polymer foam filled with hybrid fillers of wood dust and waste tire rubber has been investigated. Waste cooking oil from crisp industries was converted into bio-monomer, filled with different proportion ratio of fillers and fabricated into bio-polymer foam composite. Two fabrication methods is applied which is the Close Mold Method (CMM) and Open Mold Method (OMM). A total of four bio-polymer foam composite samples were produce for each method used. The percentage of hybrid fillers; mixture of wood dust and waste tire rubber of 2.5 %, 5.0%, 7.5% and 10% weight to weight ration with bio-monomer. The sound absorption of the bio-polymer foam composites samples were tested by using the impedance tube test according to the ASTM E-1050 and Scanning Electron Microscope to determine the morphology and porosity of the samples. The sound absorption coefficient (α) at different frequency range revealed that the polymer foam of 10.0 % hybrid fillers shows highest α of 0.963. The highest hybrid filler loading contributing to smallest pore sizes but highest interconnected pores. This also revealed that when highly porous material is exposed to incident sound waves, the air molecules at the surface of the material and within the pores of the material are forced to vibrate and loses some of their original energy. This is concluded that the suitability of bio-polymer foam filled with hybrid fillers to be used in acoustic application of automotive components such as dashboards, door panels, cushion and etc.

Steam thermolysis of tire shreds: modernization in afterburning of accompanying gas with waste steam

NASA Astrophysics Data System (ADS)

Kalitko, V. A.

2010-03-01

On the basis of experience in the commercial operation of tire-shred steam thermolysis in EnresTec Inc. (Taiwan) producing high-grade commercial carbon, liquid pyrolysis fuel, and accompanying fuel gas by this method, we have proposed a number of engineering solutions and calculated-analytical substantiations for modernization and intensification of the process by afterburning the accompanying gas with waste steam condensable in the scrubber of water gas cleaning of afterburning products. The condensate is completely freed of the organic pyrolysis impurities and the necessity of separating it from the liquid fuel, as is the case with the active process, is excluded.

40 CFR Table 1 to Subpart Xxxx of... - Emission Limits for Tire Production Affected Sources

Code of Federal Regulations, 2014 CFR

2014-07-01

... to this subpart must not exceed 1,000 grams HAP per megagram (2 pounds per ton) of total cements and... subpart must not exceed 10,000 grams HAP per megagram (20 pounds per ton) of total cements and solvents... not exceed 0.024 grams per megagram (0.00005 pounds per ton) of rubber used at the tire production...

40 CFR Table 1 to Subpart Xxxx of... - Emission Limits for Tire Production Affected Sources

Code of Federal Regulations, 2011 CFR

2011-07-01

... to this subpart must not exceed 1,000 grams HAP per megagram (2 pounds per ton) of total cements and... subpart must not exceed 10,000 grams HAP per megagram (20 pounds per ton) of total cements and solvents... not exceed 0.024 grams per megagram (0.00005 pounds per ton) of rubber used at the tire production...

40 CFR Table 1 to Subpart Xxxx of... - Emission Limits for Tire Production Affected Sources

Code of Federal Regulations, 2010 CFR

2010-07-01

... to this subpart must not exceed 1,000 grams HAP per megagram (2 pounds per ton) of total cements and... subpart must not exceed 10,000 grams HAP per megagram (20 pounds per ton) of total cements and solvents... not exceed 0.024 grams per megagram (0.00005 pounds per ton) of rubber used at the tire production...

40 CFR Table 1 to Subpart Xxxx of... - Emission Limits for Tire Production Affected Sources

Code of Federal Regulations, 2013 CFR

2013-07-01

... to this subpart must not exceed 1,000 grams HAP per megagram (2 pounds per ton) of total cements and... subpart must not exceed 10,000 grams HAP per megagram (20 pounds per ton) of total cements and solvents... not exceed 0.024 grams per megagram (0.00005 pounds per ton) of rubber used at the tire production...

Recovery and disposal of discarded tires in the Taiwan area.

PubMed

Hwang, J S; Roam, G D

1994-12-01

Urbanization and industrialization has resulted in a vast amount of artificial water containers in Taiwan, especially discarded automobile tires. 3.5 million automobile tires and several million motorcycle tires are discarded annually. The discarded tires contaminate the environment and also become a substantial number of breeding sites for the dengue vector mosquitoes. In order to establish a sound system for the recovery and disposal of discarded tires and to control dengue fever through source reduction, it has been emphasized that users must pay for their waste. It is necessary to recover and properly dispose of these discarded tired. The commercial firms which sell or manufacture tires are therefore advised to cooperate with the Environmental Protection Administration of the Executive Yuan, R.O.C. and follow the "Regulations of Recovery and Disposal of Discarded Tires". They are requested to establish foundations for the recovery of discarded tires. Those who are willing to join should prepay a deposit or related charge by the size of tire, which is imported or locally manufactured. The foundation utilizes the deposits for the recovery and disposal of discarded tires. From 1991 to 1993 the commercial tire firms had already achieved the 80% recovery rates declared by the authorities concerned. Some of the tires, after having been recovered, were recycled in the original form and the rest were cut into small pieces for recycling after physical treatment. It should be mentioned that the Department of Environmental Protection of Kaohsiung City has collected 80 thousand discarded automobile tires to be used as ocean jetty.(ABSTRACT TRUNCATED AT 250 WORDS)

A Review on Using Crumb Rubber in Reinforcement of Asphalt Pavement

PubMed Central

Mashaan, Nuha Salim; Ali, Asim Hassan; Karim, Mohamed Rehan; Abdelaziz, Mahrez

2014-01-01

An immense problem affecting environmental pollution is the increase of waste tyre vehicles. In an attempt to decrease the magnitude of this issue, crumb rubber modifier (CRM) obtained from waste tyre rubber has gained interest in asphalt reinforcement. The use of crumb rubber in the reinforcement of asphalt is considered as a smart solution for sustainable development by reusing waste materials, and it is believed that crumb rubber modifier (CRM) could be an alternative polymer material in improving hot mix asphalt performance properties. In this paper, a critical review on the use of crumb rubber in reinforcement of asphalt pavement will be presented and discussed. It will also include a review on the effects of CRM on the stiffness, rutting, and fatigue resistance of road pavement construction. PMID:24688369

Buffing dust as a filler of carboxylated butadiene-acrylonitrile rubber and butadiene-acrylonitrile rubber.

PubMed

Chronska, K; Przepiorkowska, A

2008-03-01

Buffing dust from chrome tanned leather is one of the difficult tannery wastes to manage. It is also hazardous to both human health and the environment. The scientific literature rarely reports studies on dust management, especially on its utilization as a filler for elastomers. In this connection we have made an attempt to use this leather waste as a filler for rubbers such as XNBR and NBR. The addition of the buffing dust to rubber mixes brought improvement in mechanical properties, and increase in resistance to thermal ageing as well as in electric conductivity and crosslink density of vulcalizates.

Installation report : rubber modified asphalt mix.

DOT National Transportation Integrated Search

1983-01-01

This report describes the design of an asphalt mix containing up to 3.0% closed cell waste rubber and a field installation of the mix. The Marshall design procedure was used to determine the asphalt content for the mix containing 3.0% rubber as well ...

Influence of ground tire rubber on the transient loading response of a peat biofilter.

PubMed

Alvarez-Hornos, F J; Izquierdo, M; Martínez-Soria, V; Penya-Roja, J M; Sempere, F; Gabaldón, C

2011-08-01

The effect of using ground tire rubber (GTR) as an adsorptive material in the removal of a 2:1:1 weight mixture of n-butyl acetate, toluene and m-xylene by using a peat biofilter under different intermittent conditions was investigated. The performance of two identical size biofilters, one packed with fibrous peat alone and the other with a 3:1 (vol) fibrous peat and GTR mixture, was examined for a period of four months. Partition coefficients of both materials were measured. Values of 53, 118 and 402 L kg(-1) were determined for n-butyl acetate, toluene and m-xylene in peat, respectively; and values of 40, 609 and 3035 L kg(-1) were measured for the same compounds in GTR. Intermittent load feeding of 16 h per day, 5 days per week working at an EBRT of 60 s and an inlet VOC concentration of 0.3 g C m(-1), resulted in removal efficiencies higher than 90% for both biofilters, indicating that the addition of GTR did not adversely affect the behavior of the bioreactor. Full removal of n-butyl acetate was obtained for both biofilters. GTR improved the removal of the aromatics in the first part of the biofilter, facilitating lower penetration of the toluene and m-xylene into the bed. A 31-day starvation period was applied and intermittent operation subsequently restarted. In both biofilters, high removal efficiencies after a re-acclimation period of two days were achieved. A shock loading test related to 1-h peaks of three- and four-fold increases in its baseline concentration (0.30 g C m(-3)) was applied in both biofilters. For the biofilter packed with the peat and GTR mixture, attenuation greater than 60% was observed in the maximum outlet concentration when compared to the biofilter packed with peat alone. Copyright © 2011 Elsevier Ltd. All rights reserved.

Monitoring Temperatures of Tires Using Luminescent Materials

NASA Technical Reports Server (NTRS)

Bencic, Timothy J

2006-01-01

A method of noncontact, optical monitoring of the surface temperature of a tire has been devised to enable the use of local temperature rise as an indication of potential or impending failures. The method involves the use of temperature-sensitive paint (or filler): Temperature-sensitive luminescent dye molecules or other luminescent particles are incorporated into a thin, flexible material coating the tire surface of interest. (Alternatively, in principle, the luminescent material could be incorporated directly into the tire rubber, though this approach has not yet been tested.) The coated surface is illuminated with shorter-wavelength light to excite longer-wavelength luminescence, which is observed by use of a charge-coupled-device camera or a photodetector (see Figure 1). If temporally constant illumination is used, then the temperature can be deduced from the known temperature dependence of the intensity response of the luminescence. If pulsed illumination is used, then the temperature can be deduced from the known temperature dependence of the time or frequency response of the luminescence. If sinusoidally varying illumination is used, then the temperature can be deduced from the known temperature dependence of the phase response of the luminescence. Unlike a prior method of monitoring the temperature at a fixed spot on a tire by use of a thermocouple, this method is not restricted to one spot and can, therefore, yield information on the spatial distribution of temperature: in particular, it enables the discovery of newly forming hot spots where damage may be starting. Also unlike in the thermocouple method, the measurements in this method are not vulnerable to breakage of wires in repeated flexing of the tire. Moreover, unlike in another method in which infrared radiation is monitored as an indication of surface temperature, the luminescence measurements in this method are not significantly affected by changes in infrared emissivity. This method has been

Haul truck tire dynamics due to tire condition

NASA Astrophysics Data System (ADS)

Vaghar Anzabi, R.; Nobes, D. S.; Lipsett, M. G.

2012-05-01

Pneumatic tires are costly components on large off-road haul trucks used in surface mining operations. Tires are prone to damage during operation, and these events can lead to injuries to personnel, loss of equipment, and reduced productivity. Damage rates have significant variability, due to operating conditions and a range of tire fault modes. Currently, monitoring of tire condition is done by physical inspection; and the mean time between inspections is often longer than the mean time between incipient failure and functional failure of the tire. Options for new condition monitoring methods include off-board thermal imaging and camera-based optical methods for detecting abnormal deformation and surface features, as well as on-board sensors to detect tire faults during vehicle operation. Physics-based modeling of tire dynamics can provide a good understanding of the tire behavior, and give insight into observability requirements for improved monitoring systems. This paper describes a model to simulate the dynamics of haul truck tires when a fault is present to determine the effects of physical parameter changes that relate to faults. To simulate the dynamics, a lumped mass 'quarter-vehicle' model has been used to determine the response of the system to a road profile when a failure changes the original properties of the tire. The result is a model of tire vertical displacement that can be used to detect a fault, which will be tested under field conditions in time-varying conditions.

Investigation of the recycling of tires to elastomeric requirements by techniques of thermal compression

NASA Astrophysics Data System (ADS)

Nadal Gisbert, Antonio V.

In this work is investigated the recycling of tires to elastomeric requirements by thermal compression. The production of recycled products is carried out starting from the powder, of elastomeric nature, coming from the grinding of used tires denominated GTR (Ground Tire Rubber) of different grain size, although the fundamental objective is the recycling of powder of 0,2mm grain size. The process of forming used for obtaining the recycled product is thermal compression, due to its simplicity and low cost. The composition of the powder has been analyzed and also the influence, on the elastomeric characteristics of the recycled product, of different parameters: Grain size, compact pressure, temperature, time, thickness of the recycled product and combination of sizes. At last we give an hypothesis that justifies the mechanism that gives cohesion to the powder GTR and allows their recycling. We also have carried out an analysis of the investigation lines, at the present, on the recycling of tires in general and an economic study of the viability of the recycled product in front of present products in the market, agglomerated with polyurethane, that have their application in using it in different types of floors.

Source Hierarchy List. Volume 2. E through N

DTIC Science & Technology

1994-07-01

SEE CONTINENTAL AG HANNOVER (GERMANY F R) 421628 02 GENERAL TIRE AND RUBBER CO MARION IN 151750 02 GENERAL TIRE ANO RUBBER CO WABASH IN...151800 03 GENERAL TIRE AND RUBBER CO WABASH IN 151820 INDUSTRIAL PRODUCTS DIV...GENERAL TIRE AND RUBBER CO WABASH IN 151800 FOR HIGHEST ORGANIZATIONAL LEVEL SEE CONTINENTAL AG HANNOVER (GERMANY F R) G3 GENERAL TIRE AND RUBBER CO

Close-up of Shuttle tire after LSRA test

NASA Technical Reports Server (NTRS)

1995-01-01

One of the final tests of the CV-990 Landing Systems Research Aircraft (LSRA) in August, 1995 at NASA's Dryden Flight Research Center, Edwards, California, resulted in the destruction of the wheel, following a fire caused by a mixture of heat, aluminum particles, and rubber. Following successful tests of tire wear at Edwards and the Kennedy Space Center, Fl., this series of roll-on-rim tests determined the failure modes ofwheels for the space shuttle. The aluminum wheel locked in postion and was ground to within four inches of the axle before the test concluded. The series of 155 test missions for the space shuttle program provided extensive data about the life and endurance of the shuttle tire systems and helped raise the shuttle crosswind landing limits at Kennedy. Project engineer Christopher J. Nagy said, 'NASA pilots Gordon Fullerton and Terry Rager did a superb job of flying the aircraft in many difficult test situations, at speeds higher than the aircraft was intended to land, without once losing a single flight.'

Close-up of Shuttle tire after LSRA test

NASA Technical Reports Server (NTRS)

1995-01-01

One of the final tests of the CV-990 Landing Systems Research Aircraft (LSRA) in August, 1995 at NASA's Dryden Flight Research Center, Edwards, California, resulted in the destruction of the wheel, following a fire caused by a mixture of heat, aluminum particles, and rubber. Following successful tests of tire wear at Edwards and the Kennedy Space Center, Fla., this series of roll-on-rim tests determined the failure modes of wheels for the space shuttle. In one test, the aluminum wheel locked in position and was ground to within four inches of the axle before the test concluded. The series of 155 test missions for the space shuttle program provided extensive data about the life and endurance of the shuttle tire systems and helped raise the shuttle crosswind landing limits at Kennedy. Project engineer Christopher J. Nagy said, 'NASA pilots Gordon Fullerton and Terry Rager did a superb job of flying the aircraft in many difficult test situations, at speeds higher than the aircraft was intended to land, without once losing a single test flight.'

Evaluation of mix ingredients on the performance of rubber-modified asphalt mixtures

DOE Office of Scientific and Technical Information (OSTI.GOV)

Takallou, H.B.

1987-01-01

In rubber-modified asphalt pavements ground recycled tire particles are added to a gap-graded aggregate and then mixed with hot asphalt cement. In view of the significant reductions in wintertime stopping distances under icy or frosty road surface conditions, the use of coarse rubber in asphalt pavements should be seriously considered. This research project consisted of a laboratory study of mix properties as a function of variables such as rubber gradation and content, void content, aggregate graduation, mix process, temperature, and asphalt content. Twenty different mix combinations were evaluated for diametral modulus and fatigue at two different temperatures. Also, five differentmore » mix combinations were evaluated for static creep and permanent deformation. The findings of the laboratory study indicate that the rubber gradation and content, aggregate gradation, and use of surcharge during sample preparation have considerable effect on modulus and fatigue life of the mix. The results of static creep and permanent deformation tests indicate that the rubber asphalt mixes had low stability and high elasticity. Also, due to greater allowable tensile strain in rubber-modified mixtures, the thickness of the modified mixture can be reduced, using a layer equivalency of 1.4 to 1.0« less

Land Vehicle Tire Qualification: DSCC Annual Tire Conference

DTIC Science & Technology

2011-03-24

liner separations - Tire induced loss of air -Exposed or broken casing -Bulges in tread or sidewall SAE J2014 UNCLASSIFIED 11 SAE J2014 4.14 Tire ...Treadlife Durability -10000 miles duration -Evaluate tread wear performance of candidate tire -Measurements at prescribed intervals - Tread depth at centerline...shoulder -Diameter, section width, tread arc width -Conducted on courses required for mission profile Criteria: -Candidate tire exceeds 95% of

Evaluating Waste Charcoal as Potential Rubber Composite Filler

USDA-ARS?s Scientific Manuscript database

Carbon black, a byproduct of the petroleum industry, is the world's most predominant filler for rubber composites. In this study, charcoal in the form of pyrolyzed agricultural products was evaluated as potential carbon-based filler for rubber composites made with carboxylated styrene-butadiene lat...

Latex allergens in tire dust and airborne particles.

PubMed Central

Miguel, A G; Cass, G R; Weiss, J; Glovsky, M M

1996-01-01

The prevalence and severity of latex allergy has increased dramatically in the last 15 years due to exposure to natural rubber products. Although historically this health risk has been elevated in hospital personnel and patients, a recent survey has indicated a significant potential risk for the general population. To obtain a wide-spread source for latex exposure, we have considered tire debris. We have searched for the presence of latex allergens in passenger car and truck tire tread, in debris deposited from the atmosphere near a freeway, and in airborne particulate matter samples representative of the entire year 1993 at two sites in the Los Angeles basin (California). After extraction of the samples with phosphate buffered saline, a modified-ELISA inhibition assay was used to measure relative allergen potency and Western blot analyses were used to identify latex allergens. The inhibition studies with the human IgE latex assay revealed inhibition by the tire tread source samples and ambient freeway dust, as well as by control latex sap and latex glove extracts. Levels of extractable latex allergen per unit of protein extracted were about two orders of magnitude lower for tire tread as compared to latex gloves. Western blot analyses using binding of human IgE from latex-sensitive patients showed a band at 34-36 kDa in all tire and ambient samples. Long Beach and Los Angeles, California, air samples showed four additional bands between 50 and 135 kDa. Alternative Western blot analyses using rabbit IgG raised against latex proteins showed a broad band at 30-50 kDa in all samples, with additional bands in the urban air samples similar to the IgE results. A latex cross-reactive material was identified in mountain cedar. In conclusion, the latex allergens or latex cross-reactive material present in sedimented and airborne particulate material, derived from tire debris, and generated by heavy urban vehicle traffic could be important factors in producing latex allergy

40 CFR Table 11 to Subpart Xxxx of... - Minimum Data for Continuous Compliance With the Emission Limits for Tire Cord Production Affected...

Code of Federal Regulations, 2013 CFR

2013-07-01

...) NATIONAL EMISSION STANDARDS FOR HAZARDOUS AIR POLLUTANTS FOR SOURCE CATEGORIES (CONTINUED) National Emissions Standards for Hazardous Air Pollutants: Rubber Tire Manufacturing Pt. 63, Subpt. XXXX, Table 11... method, test results, indicating the mass percent of each HAP for coating used.b. The mass of each...

Tire Modeling

NASA Technical Reports Server (NTRS)

Tanner, J. A. (Compiler)

1983-01-01

The workshop was organized into six sessions dealing with finite element developments, applications to tire dynamic problems, solution techniques for tire contact problems, experimental data, tire thermal studies, and current design practices.

40 CFR Table 9 to Subpart Xxxx of... - Minimum Data for Continuous Compliance With the Emission Limits for Tire Production Affected Sources

Code of Federal Regulations, 2013 CFR

2013-07-01

... EMISSION STANDARDS FOR HAZARDOUS AIR POLLUTANTS FOR SOURCE CATEGORIES (CONTINUED) National Emissions Standards for Hazardous Air Pollutants: Rubber Tire Manufacturing Pt. 63, Subpt. XXXX, Table 9 Table 9 to... Method 311 (40 CFR part 60, appendix A), or approved alternative method, test results indicating the mass...

The Use of Deconstructed Tires as Elastic Elements in Railway Tracks.

PubMed

Sol-Sánchez, Miguel; Moreno-Navarro, Fernando; Rubio-Gámez, Mª Carmen

2014-08-18

Elastic elements such as rail pads, under sleeper pads and under ballast mats are railway components that allow for a reduction in track deterioration and vibrations. And they are furthermore commonly used to obtain an optimal vertical stiffness of the infrastructure. However, the use of elastomeric materials can increase construction costs and the consumption of raw materials. Thus, the utilization of used tire layers offers an alternative to reuse an abundant waste reducing the cost of elastic elements. In addition, an innovator technique allows deconstructing tire layers without grinding up the material, reducing production costs at the same time that tire properties are remained. This research is focused on the study of the viability of developing elastic components from used tire layers by evaluating the influence of thickness, the resistance capacity of the elements and their behavior in a ballast box. Results indicate the ability of tire pads to manufacture elastic elements (rail pads, under sleeper pads and under ballast mats) to be used in railway tracks.

Chronic diseases in the rubber industry

PubMed Central

Tyroler, H. A.; Andjelkovic, Dragana; Harris, Robert; Lednar, Wayne; McMichael, Anthony; Symons, Mike

1976-01-01

An overview is presented of epidemiologic studies of chronic diseases in the rubber industry. Analyses of the mortality experience during the period 1964-1972 of workers age 40–64 and retirees age 65–84 of two large rubber and tire manufacturing companies consistently disclosed excesses of deaths attributed to leukemia and lymphosarcoma, and for cancers of the stomach, large intestine, and prostate. The relation of site-specific malignancies to work histories and grouped occupational titles as surrogate measures of work-related exposures to possible carcinogens is described. There was no evidence of company-wide, sizable, consistent excess for the other major chronic diseases causes of death. Although a total cohort deficit in the mortality rate for lung cancer was found, there was a history of increased frequency of exposure to certain work areas among lung cancer decedents. Morbidity studies, including analysis of disability retirements, and ad hoc questionnaire and health testing surveys, disclosed excesses of chronic pulmonary diseases. There was evidence of an interactive effect in the association of work and smoking histories with pulmonary disability retirement. PMID:1026398

Multiscale physics of rubber-ice friction

NASA Astrophysics Data System (ADS)

Tuononen, Ari J.; Kriston, András; Persson, Bo

2016-09-01

Ice friction plays an important role in many engineering applications, e.g., tires on icy roads, ice breaker ship motion, or winter sports equipment. Although numerous experiments have already been performed to understand the effect of various conditions on ice friction, to reveal the fundamental frictional mechanisms is still a challenging task. This study uses in situ white light interferometry to analyze ice surface topography during linear friction testing with a rubber slider. The method helps to provide an understanding of the link between changes in the surface topography and the friction coefficient through direct visualization and quantitative measurement of the morphologies of the ice surface at different length scales. Besides surface polishing and scratching, it was found that ice melts locally even after one sweep showing the refrozen droplets. A multi-scale rubber friction theory was also applied to study the contribution of viscoelasticity to the total friction coefficient, which showed a significant level with respect to the smoothness of the ice; furthermore, the theory also confirmed the possibility of local ice melting.

Influence of different processing techniques on the mechanical properties of used tires in embankment construction.

PubMed

Edinçliler, Ayşe; Baykal, Gökhan; Saygili, Altug

2010-06-01

Use of the processed used tires in embankment construction is becoming an accepted way of beneficially recycling scrap tires due to shortages of natural mineral resources and increasing waste disposal costs. Using these used tires in construction requires an awareness of the properties and the limitations associated with their use. The main objective of this paper is to assess the different processing techniques on the mechanical properties of used tires-sand mixtures to improve the engineering properties of the available soil. In the first part, a literature study on the mechanical properties of the processed used tires such as tire shreds, tire chips, tire buffings and their mixtures with sand are summarized. In the second part, large-scale direct shear tests are performed to evaluate shear strength of tire crumb-sand mixtures where information is not readily available in the literature. The test results with tire crumb were compared with the other processed used tire-sand mixtures. Sand-used tire mixtures have higher shear strength than that of the sand alone and the shear strength parameters depend on the processing conditions of used tires. Three factors are found to significantly affect the mechanical properties: normal stress, processing techniques, and the used tire content. Copyright 2009. Published by Elsevier Ltd.

A Strain-Based Method to Detect Tires’ Loss of Grip and Estimate Lateral Friction Coefficient from Experimental Data by Fuzzy Logic for Intelligent Tire Development

PubMed Central

Garcia-Pozuelo, Daniel; Diaz, Vicente; Olatunbosun, Oluremi

2018-01-01

Tires are a key sub-system of vehicles that have a big responsibility for comfort, fuel consumption and traffic safety. However, current tires are just passive rubber elements which do not contribute actively to improve the driving experience or vehicle safety. The lack of information from the tire during driving gives cause for developing an intelligent tire. Therefore, the aim of the intelligent tire is to monitor tire working conditions in real-time, providing useful information to other systems and becoming an active system. In this paper, tire tread deformation is measured to provide a strong experimental base with different experiments and test results by means of a tire fitted with sensors. Tests under different working conditions such as vertical load or slip angle have been carried out with an indoor tire test rig. The experimental data analysis shows the strong relation that exists between lateral force and the maximum tensile and compressive strain peaks when the tire is not working at the limit of grip. In the last section, an estimation system from experimental data has been developed and implemented in Simulink to show the potential of strain sensors for developing intelligent tire systems, obtaining as major results a signal to detect tire’s loss of grip and estimations of the lateral friction coefficient. PMID:29415513

Standards for tire-bale erosion control and bank stabilization projects: validation of existing practice and implementation.

DOT National Transportation Integrated Search

2010-09-01

In an effort to promote the use of increasing stockpiles of waste tires and a growing demand for adequate : backfill material in highway construction, NMDOT has embarked on a move to use compressed tire-bales : as a means to reduce cost of constructi...

Tire footprint studies

NASA Technical Reports Server (NTRS)

Chawla, Mangal; Medzorian, John

1995-01-01

This presentation covers the results of tire footprint studies conducted in the Landing Gear Development Facility of the USAF Wright Laboratory at the Wright Patterson Air force Base, OH. Tire footprint studies are essential in understanding tire wear mechanisms and computing tire tread wear rates. The power input into the tread is the driving force for tread wear. Variables needed for power input calculations include the footprint pressure and slip velocity distributions. Studies were performed on the effects of power input distributions due to vertical load, camber, yaw, inflation pressure, and tire construction. For the present study, two tire constructions, one radial and the other bias, were selected. These tires were for the F-16 Block 30 fighter aircraft, both of which were previously worn. The present study was limited to steady straight roll with a 14,000 lb vertical load, a 310 psi inflation pressure, and zero yaw and camber. All tests were conducted on the Tire Force Machine (TFM) with a specialized sensor plate with embedded pressure sensors (X, Y, and Z) and slip sensors (X and Y). All tests were conducted for a table speed of 1 in/s. Tests on the TFM show that the power intensity distributions and total power for both tire constructions are quite similar for straight roll. Later on, tests were also conducted on a modified dynamometer which was overlaid with a grit wear surface. The tire speed was maintained at 40 miles per hour and yaw was set to four degrees. Dynamometer tests showed that radial tires have more tread wear than the bias tire; however, in the field, radial tires have longer life.

40 CFR 63.5981 - Am I subject to this subpart?

Code of Federal Regulations, 2010 CFR

2010-07-01

... subject to this subpart? (a) You are subject to this subpart if you own or operate a rubber tire..., such as wheels, inner tubes, tire bladders, and valve stems, are not components of rubber tires or tire... more per year. (b) You are not subject to this subpart if the affected source at your rubber tire...

Intelligent Tires Based on Measurement of Tire Deformation

NASA Astrophysics Data System (ADS)

Matsuzaki, Ryosuke; Todoroki, Akira

From a traffic safety point-of-view, there is an urgent need for intelligent tires as a warning system for road conditions, for optimized braking control on poor road surfaces and as a tire fault detection system. Intelligent tires, equipped with sensors for monitoring applied strain, are effective in improving reliability and control systems such as anti-lock braking systems (ABSs). In previous studies, we developed a direct tire deformation or strain measurement system with sufficiently low stiffness and high elongation for practical use, and a wireless communication system between tires and vehicle that operates without a battery. The present study investigates the application of strain data for an optimized braking control and road condition warning system. The relationships between strain sensor outputs and tire mechanical parameters, including braking torque, effective radius and contact patch length, are calculated using finite element analysis. Finally, we suggested the possibility of optimized braking control and road condition warning systems. Optimized braking control can be achieved by keeping the slip ratio constant. The road condition warning would be actuated if the recorded friction coefficient at a certain slip ratio is lower than a ‘safe’ reference value.

Evaluation of hydrogenated resin acids as molecular markers for tire-wear debris in urban environments.

PubMed

Kumata, Hidetoshi; Mori, Mika; Takahashi, Sho; Takamiya, Shohei; Tsuzuki, Mikio; Uchida, Tatsuya; Fujiwara, Kitao

2011-12-01

To propose new molecular markers for tire-wear emissions, four dihydroresin acids, that is, 8-isopimaren-18-oic acid (I), 8-pimaren-18-oic acid (II), 13β(H)-abieten-18-oic acid (III), and 13α(H)-abiet-8-en-18-oic acid (IV), were identified and investigated for source specificities, distributions, and environmental stabilities. The absence of I-IV in natural sources and the linear correlations between dihydroresin acids with different skeletons in tires and in environmental samples demonstrated that I-IV are specific markers for synthetic rubbers. The ratio of III + IV to the sum of III + IV plus abietic acid showed the resin acids distribution between different environmental compartments receiving contributions from traffic and natural sources. The physicochemical properties and results of photolysis experiments suggested that I-IV can set lower limits for tire-wear contributions to environmental loads of particulate matter (PM) and polycyclic aromatic hydrocarbons with molecular weight ≥202. By comparing III + IV concentrations or (III+IV)/pyrene or (III+IV)/benzo[a]pyrene ratios in tires and those in environmental matrices, the contributions of tire-wear emissions to PM, pyrene, and benzo[a]pyrene were estimated to be 0.68 ± 0.54%, 6.9 ± 4.8%, and 0.37 ± 0.18% in roadside PM and 0.83 ± 0.21%, 0.88 ± 0.52%, and 0.08 ± 0.06% in rooftop PM.

Application of mathematical planning in production of filled emulsion rubbers

NASA Astrophysics Data System (ADS)

Pugacheva, I. N.; Molokanova, L. V.; Popova, L. V.; Repin, P. S.

2018-05-01

The applicability of mathematical planning of experiment in the field of chemistry and chemical engineering, in particular in the industrial production of synthetic rubbers, is considered in the article. Possibility of using secondary material resources, which are waste products of light industry, in the production of elastomeric compositions is studied. The method of obtaining a powdered cellulose additive from wastes containing cellulose fiber is described. The best way of introducing the obtained additive into elastomeric compositions based on the emulsion rubber is established. Optimal conditions for obtaining filled emulsion rubber with the help of a powdered cellulose additive were established basing on the mathematical planning of experiment.

Effect of crumb-rubber particle size on mechanical response of polyurethane foam composites

NASA Astrophysics Data System (ADS)

Sanjay, Omer Sheik

The compression properties of foam are governed by by three factors: i) cell edge bending ii) compression of cell fluid iii) membrane stresses in the cell faces. The effect of reinforcement, granular form of scrap tire rubber on contribution of each of these effects along with the physical properties of polyurethane foam is investigated. It is seen that the addition of crumb-rubber hinders the formation of cell membranes during the foaming process. Four different sizes of particles were chosen to closely study the effect of particle size on the physical properties of the foam composite. There is a definite pattern seen in each of the physical property of the composite with change in the particle size. Addition of crumb-rubber decreases the compressive strength but in turn increases the elastic modulus of the composite. The rubber particles act as the sites for stress concentration and hence the inclusion of rubber particles induces the capability to transfer the axial load laterally along the surface of the foam. Also, the filler material induces porosity into the foam, which is seen in the SEM images, and hence the addition of rubber particles induces brittleness, which makes the foam composites extensively applicable for structural application in sandwich components. The lightweight composite therefore is a potential substitute to the heavier metal foams and honeycombs as a protective layer.

The Use of Deconstructed Tires as Elastic Elements in Railway Tracks

PubMed Central

Sol-Sánchez, Miguel; Moreno-Navarro, Fernando; Rubio-Gámez, Mª Carmen

2014-01-01

Elastic elements such as rail pads, under sleeper pads and under ballast mats are railway components that allow for a reduction in track deterioration and vibrations. And they are furthermore commonly used to obtain an optimal vertical stiffness of the infrastructure. However, the use of elastomeric materials can increase construction costs and the consumption of raw materials. Thus, the utilization of used tire layers offers an alternative to reuse an abundant waste reducing the cost of elastic elements. In addition, an innovator technique allows deconstructing tire layers without grinding up the material, reducing production costs at the same time that tire properties are remained. This research is focused on the study of the viability of developing elastic components from used tire layers by evaluating the influence of thickness, the resistance capacity of the elements and their behavior in a ballast box. Results indicate the ability of tire pads to manufacture elastic elements (rail pads, under sleeper pads and under ballast mats) to be used in railway tracks. PMID:28788168

Radiation degradation of spent butyl rubbers

NASA Astrophysics Data System (ADS)

Telnov, A. V.; Zavyalov, N. V.; Khokhlov, Yu. A.; Sitnikov, N. P.; Smetanin, M. L.; Tarantasov, V. P.; Shadrin, D. N.; Shorikov, I. V.; Liakumovich, A. L.; Miryasova, F. K.

2002-03-01

Radiation methods of materials modification applied in technological chains can have significant economical and ecological advantages as compared to the established chemical, thermal and mechanical methods. Each year the problems of nature resources economy through the use of production and consumption wastes acquire a more significant value, as it allows to solve also ecological issues along with economical ones. This is mostly acute in relation to polymeric systems based on saturated rubbers, for example butyl rubber (BR) used in the tyre industry, as due to their high resistance to the action of oxygen, ozone, solar radiation and bacteria, they contaminate the environment for rather a long period. At VNIIEF and KSPU experiments were carried out on application of electron beams with energy from 6 to 10 MeV for radiation destruction of spent rubber based on BR. The radiation-degraded material was tested for re-use in the formulation of initial diaphragm mixture, rubber mixture for producing rubberized fabric and roofing.

All-Metal Tires

NASA Technical Reports Server (NTRS)

Bickler, Donald B.; Sword, Lee F.; Lindemann, Randel A.

1994-01-01

Tires used where elastomeric and pneumatic tires would not function. Metal tires withstand extreme temperatures. Used on Earth for vehicles and robots that fight fires or clean up dangerous chemicals.

Use of rubber and bentonite added fly ash as a liner material.

PubMed

Cokca, Erdal; Yilmaz, Zeka

2004-01-01

In many countries regulations require all hazardous waste disposal facilities to be lined with suitable impermeable barriers to protect against contamination. In this study, a series of laboratory tests on rubber and bentonite added fly ash were conducted. The aim of the tests was to evaluate the feasibility of utilizing fly ash, rubber and bentonite as a low hydraulic conductivity liner material. Type C fly ash was obtained from Soma thermal power plant in Turkey; rubber in pulverized form was waste from the retreading industry. To investigate the properties of rubber and bentonite added fly ash, hydraulic conductivity, leachate analysis, unconfined compression, split tensile strength, one-dimensional consolidation, swell and freeze/thaw cycle tests were performed. The overall evaluation of results have revealed that rubber and bentonite added fly ash showed good promise and a candidate for construction of a liner.

Major tire fragment contributions to PM{sub 10} non-attainment in Anchorage

DOE Office of Scientific and Technical Information (OSTI.GOV)

Draftz, R.G.; Cowherd, C. Jr.; Grelinger, M.A.

1999-07-01

Anchorage exceeded the 24-hour National Ambient Air Quality Standard for PM{sub 10} a total of thirty-one times in the period from 1987 to 1997. About half of these exceedances were due to natural events. The remaining exceedances could not be linked to natural events. Moreover, these exceedances occurred predominantly at one PM{sub 10} site near one of the major thoroughfares in Anchorage. The apportionment of sources producing these unexplained violations was one of the major goals of a 1996--98 study sponsored and directed by the Air Quality Program of the Municipality of Anchorage. Two suites of PM{sub 10} samples weremore » utilized for source apportionment of exceedances. The first consisted of historical samples selected from sampling periods unaffected by natural events. These samples were carefully selected to avoid the high values during and following volcanic eruptions when there were likely to be considerable accumulations of volcanic ejecta on roads. Dust storms were excluded by simple inspection of data for days that showed that all sites in the Anchorage basin had high PM{sub 10} loadings. The second group of samples were selected from a special springtime road dust tagging experiment used to measure emission and depletion rates of the taggant and accumulated road dust particles, mainly road aggregate wear and anti-skid minerals. Quantitative microscopical analysis of the first suite of historical samples showed that rubber tire concentrations contributed from approximately 12 to 42{micro}g/m{sup 3} of the PM{sub 10} for samples near or exceeding the 24 hour limit. Road dust samples from the road tagging experiment showed that the PM{sub 10}-sized tire fragments were not present in the road dust and therefore, had to have become immediately airborne rather than re-entrained from road dust deposits. Rubber tire fragments are one of the three dominant components that collectively account for more than 95% of the PM{sub 10} non-attainment in Anchorage.« less

40 CFR 428.80 - Applicability; description of the wet digestion reclaimed rubber subcategory.

Code of Federal Regulations, 2014 CFR

2014-07-01

... digestion reclaimed rubber subcategory. 428.80 Section 428.80 Protection of Environment ENVIRONMENTAL... CATEGORY Wet Digestion Reclaimed Rubber Subcategory § 428.80 Applicability; description of the wet digestion reclaimed rubber subcategory. The provisions of this subpart are applicable to process waste water...

40 CFR 428.80 - Applicability; description of the wet digestion reclaimed rubber subcategory.

Code of Federal Regulations, 2012 CFR

2012-07-01

... digestion reclaimed rubber subcategory. 428.80 Section 428.80 Protection of Environment ENVIRONMENTAL... CATEGORY Wet Digestion Reclaimed Rubber Subcategory § 428.80 Applicability; description of the wet digestion reclaimed rubber subcategory. The provisions of this subpart are applicable to process waste water...

40 CFR 428.80 - Applicability; description of the wet digestion reclaimed rubber subcategory.

Code of Federal Regulations, 2013 CFR

2013-07-01

... digestion reclaimed rubber subcategory. 428.80 Section 428.80 Protection of Environment ENVIRONMENTAL... CATEGORY Wet Digestion Reclaimed Rubber Subcategory § 428.80 Applicability; description of the wet digestion reclaimed rubber subcategory. The provisions of this subpart are applicable to process waste water...

Environmental Assessment: Anti-Terrorism/Force Protection McConnell Air Force Base, Kansas

DTIC Science & Technology

2003-09-01

handled, stored, transported, disposed, or recycled in accordance with these regulations. The potential for hazardous waste generation from gate...Loader (rubber tire) Concrete Truck Concrete Finisher Crane Asphalt Spreader Roller Flat Bed Truck (18 wheel) Scraper Trenching Machine 1...plastics, and lumber. These materials would be placed in the appropriate construction materials landfill or recycled when possible. These wastes

Evaluation of Low Hazardous Air Pollutant Thermoset Adhesives for the Application of Rubber-to-Metal Bonding on Army Tank Pads and Road Wheels

DTIC Science & Technology

2011-09-01

Department of the Army. Track Shoe Rebuild; SOP 39; Red River Army Depot, Texarkana , Texas, July 2, 2002. 3. Operational Directorate, Department...of the Army. Rebuild of Wheel, Solid Rubber Tire; SOP 47; Red River Army Depot, Texarkana , Texas, July 15, 2002. 4. Chemcentral Corporation

40 CFR 60.540 - Applicability and designation of affected facilities.

Code of Federal Regulations, 2010 CFR

2010-07-01

... Performance for the Rubber Tire Manufacturing Industry § 60.540 Applicability and designation of affected... each of the following affected facilities in rubber tire manufacturing plants that commence... cementing operation in rubber tire manufacturing plants that commenced construction, modification, or...

Phenomena of Pneumatic Tire Hydroplaning

NASA Technical Reports Server (NTRS)

Dreher, R. C.; Horne, W. B.

1963-01-01

Recent research on pneumatic tire hydroplaning has been collected and summarized with the aim of describing what is presently known about the phenomena of tire hydroplaning. A physical description of tire hydroplaning is given along with formulae for estimating the ground speed at which it occurs. Eight manifestations of tire hydroplaning which have been experimentally observed are presented and discussed. These manifestations are: detachment of tire footprint, hydrodynamic ground pressure, spin-down of wheel, suppression of tire bow wave, scouring action of escaping fluid in tire-ground footprint region, peaking of fluid displacement drag, loss in braking traction, and loss of tire directional stability. The vehicle, pavement, tire, and fluid parameters of importance to tire hydroplaning are listed and described. Finally, the hazards of tire hydroplaning to ground and air-vehicle-ground performance are listed, and procedures are given to minimize these effects.

Tires: Traffic Safety Tips

DOT National Transportation Integrated Search

1996-01-01

This fact sheet, NHTSA Facts: Summer 1996, discuses motor vehicle tires. It includes how to buy the right tires (obtaining tires of the correct size, type and tread); how to grade the tires (treadwear, traction, and temperature resistance); and how t...

78 FR 73524 - Information Collection Request Submitted to OMB for Review and Approval; Comment Request; NSPS...

Federal Register 2010, 2011, 2012, 2013, 2014

2013-12-06

... Request Submitted to OMB for Review and Approval; Comment Request; NSPS for Rubber Tire Manufacturing... Protection Agency has submitted an information collection request (ICR), ``NSPS for Rubber Tire Manufacturing.../dockets . Abstract: Respondents are owners or operators of rubber tire manufacturing plants which include...

Tire

NASA Technical Reports Server (NTRS)

Benzing, II, James Alfred (Inventor); Kish, James Christopher (Inventor); Asnani, Vivake Manohar (Inventor)

2012-01-01

A tire includes a plurality of helical springs. Each helical spring includes a first end portion, a second end portion, and an arching middle portion. Each helical spring is interlaced with at least one other helical spring thereby forming a laced toroidal structure extending about an entire circumference of the tire.

Land Vehicle Tire Qualification

DTIC Science & Technology

2009-03-25

Bead damage / separation -Severe open splices and/or liner separations - Tire induced loss of air -Exposed or broken casing -Bulges in tread or...sidewall SAE J2014 11 SAE J2014 4.14 Tire Treadlife Durability -10000 miles duration -Evaluate tread wear performance of candidate tire -Measurements at... Tread Depth measurement of reference and candidate tires taken at specified intervals • Candidate tires must complete the test and tread wear projections

Tire/runway friction interface

NASA Technical Reports Server (NTRS)

Yager, Thomas J.

1990-01-01

An overview is given of NASA Langley's tire/runway pavement interface studies. The National Tire Modeling Program, evaluation of new tire and landing gear designs, tire wear and friction tests, and tire hydroplaning studies are examined. The Aircraft Landing Dynamics Facility is described along with some ground friction measuring vehicles. The major goals and scope of several joint FAA/NASA programs are identified together with current status and plans.

Rolling Resistance of Pneumatic Tires

DOT National Transportation Integrated Search

1975-01-01

Potential improvements in tire power transmission efficiency are worth seeking for gaining improved automotive fuel economy. Summaries herein of tire rolling resistance as influenced by tire construction and design, tire materials, and tire operating...

Rolling Resistance of Pneumatic Tires

DOT National Transportation Integrated Search

1979-05-01

Potential improvements in tire power transmission efficiency are worth seeking for gaining improved automotive fuel economy. Summaries herein of tire rolling resistance as influenced by tire construction and design, tire materials, and tire operating...

49 CFR 574.7 - Information requirements-new tire manufacturers, new tire brand name owners.

Code of Federal Regulations, 2010 CFR

2010-10-01

... 49 Transportation 7 2010-10-01 2010-10-01 false Information requirements-new tire manufacturers, new tire brand name owners. 574.7 Section 574.7 Transportation Other Regulations Relating to..., new tire brand name owners. (a)(1) Each new tire manufacturer and each new tire brand name owner...

Feasibility study for thermal treatment of solid tire wastes in Bangladesh by using pyrolysis technology

DOE Office of Scientific and Technical Information (OSTI.GOV)

Islam, M.R., E-mail: mrislam1985@yahoo.com; Joardder, M.U.H.; Hasan, S.M.

2011-09-15

In this study on the basis of lab data and available resources in Bangladesh, feasibility study has been carried out for pyrolysis process converting solid tire wastes into pyrolysis oils, solid char and gases. The process considered for detailed analysis was fixed-bed fire-tube heating pyrolysis reactor system. The comparative techno-economic assessment was carried out in US$ for three different sizes plants: medium commercial scale (144 tons/day), small commercial scale (36 tons/day), pilot scale (3.6 tons/day). The assessment showed that medium commercial scale plant was economically feasible, with the lowest unit production cost than small commercial and pilot scale plants formore » the production of crude pyrolysis oil that could be used as boiler fuel oil and for the production of upgraded liquid-products.« less

76 FR 15045 - Goodyear Tire and Rubber Company, Receipt of Petition for Decision of Inconsequential Noncompliance

Federal Register 2010, 2011, 2012, 2013, 2014

2011-03-18

... located in an area that is not more than one-fourth of the distance from the bead to the shoulder of the... and a point one-half the distance from the bead to the shoulder of the tire, on at least one sidewall...

Intelligent tires for improved tire safety using wireless strain measurement

NASA Astrophysics Data System (ADS)

Matsuzaki, Ryosuke; Todoroki, Akira

2008-03-01

From a traffic safety point-of-view, there is an urgent need for intelligent tires as a warning system for road conditions, for optimized braking control on poor road surfaces and as a tire fault detection system. Intelligent tires, equipped with sensors for monitoring applied strain, are effective in improving reliability and control systems such as anti-lock braking systems (ABSs). In previous studies, we developed a direct tire deformation or strain measurement system with sufficiently low stiffness and high elongation for practical use, and a wireless communication system between tires and vehicle that operates without a battery. The present study investigates the application of strain data for an optimized braking control and road condition warning system. The relationships between strain sensor outputs and tire mechanical parameters, including braking torque, effective radius and contact patch length, are calculated using finite element analysis. Finally, we suggested the possibility of optimized braking control and road condition warning systems. Optimized braking control can be achieved by keeping the slip ratio constant. The road condition warning would be actuated if the recorded friction coefficient at a certain slip ratio is lower than a 'safe' reference value.

Structural modeling of aircraft tires

NASA Technical Reports Server (NTRS)

Clark, S. K.; Dodge, R. N.; Lackey, J. I.; Nybakken, G. H.

1973-01-01

A theoretical and experimental investigation of the feasibility of determining the mechanical properties of aircraft tires from small-scale model tires was accomplished. The theoretical results indicate that the macroscopic static and dynamic mechanical properties of aircraft tires can be accurately determined from the scale model tires although the microscopic and thermal properties of aircraft tires can not. The experimental investigation was conducted on a scale model of a 40 x 12, 14 ply rated, type 7 aircraft tire with a scaling factor of 8.65. The experimental results indicate that the scale model tire exhibited the same static mechanical properties as the prototype tire when compared on a dimensionless basis. The structural modeling concept discussed in this report is believed to be exact for mechanical properties of aircraft tires under static, rolling, and transient conditions.

Outbreak of sudden cardiac deaths in a tire manufacturing facility: can it be caused by nanoparticles?

PubMed

Kim, Eun-A; Park, Jungsun; Kim, Kun-Hyung; Lee, Naroo; Kim, Dae-Seong; Kang, Seong-Kyu

2012-03-01

The purpose of this study was to review clinical characteristics and working environments of sudden cardiac death (SCD) cases associated with a tire manufacturer in Korea, and review possible occupational risk factors for cardiovascular disease including nanoparticles (ultrafine particles, UFPs). We reviewed (i) the clinical course of SCD cases and (ii) occupational and non-occupational risk factors including chemicals, the physical work environment, and job characteristics. Possible occupational factors were chemicals, UFPs of rubber fume, a hot environment, shift work, overworking, and noise exposure. The mean diameter of rubber fume (63-73 nm) was (larger than diesel exhaust [12 nm] and outdoor dust [50 nm]). The concentration of carbon disulfide, carbon monoxide and styrene were lower than the limit of detection. Five SCD cases were exposed to shift work and overworking. Most of the cases had several non-occupational factors such as hypertension, overweight and smoking. The diameter of rubber fume was larger than outdoor and the diesel exhaust, the most well known particulate having a causal relationship with cardiovascular disease. The possibility of a causal relation between UFPs of rubber fume and SCD was not supported in this study. However, it is necessary to continue studying the relationship between large sized UFPs and SCD.

Outbreak of Sudden Cardiac Deaths in a Tire Manufacturing Facility: Can It Be Caused by Nanoparticles?

PubMed Central

Kim, Eun-A; Kim, Kun-Hyung; Lee, Naroo; Kim, Dae-Seong; Kang, Seong-Kyu

2012-01-01

Objectives The purpose of this study was to review clinical characteristics and working environments of sudden cardiac death (SCD) cases associated with a tire manufacturer in Korea, and review possible occupational risk factors for cardiovascular disease including nanoparticles (ultrafine particles, UFPs). Methods We reviewed (i) the clinical course of SCD cases and (ii) occupational and non-occupational risk factors including chemicals, the physical work environment, and job characteristics. Results Possible occupational factors were chemicals, UFPs of rubber fume, a hot environment, shift work, overworking, and noise exposure. The mean diameter of rubber fume (63-73 nm) was (larger than diesel exhaust [12 nm] and outdoor dust [50 nm]). The concentration of carbon disulfide, carbon monoxide and styrene were lower than the limit of detection. Five SCD cases were exposed to shift work and overworking. Most of the cases had several non-occupational factors such as hypertension, overweight and smoking. Conclusion The diameter of rubber fume was larger than outdoor and the diesel exhaust, the most well known particulate having a causal relationship with cardiovascular disease. The possibility of a causal relation between UFPs of rubber fume and SCD was not supported in this study. However, it is necessary to continue studying the relationship between large sized UFPs and SCD. PMID:22953232

The effect of carbon black (CB) loading on curing characteristics and mechanical properties of virgin acrylonitrile butadiene rubber (Nbrv)/recycled acrylonitrile butadiene rubber (Nbrr) blends

NASA Astrophysics Data System (ADS)

Husnan, M. A.; Ismail, H.; Shuib, R. K.

2018-02-01

Recently, the interest of polymer industry researchers have grown rapidly on the use of specific techniques which can reduce cost and utilize rubber waste into the processing form. The increasing of cognizance in environmental matters and the desire to sustain the resources had fortified the practice of recycling waste materials. In this work, the effect of carbon black loading on curing characteristics and mechanical properties of virgin acrylonitrile butadiene rubber/recycled acrylonitrile butadiene rubber (NBRv/NBRr) blends were studied. Cure time (t90), scorch time (tS2) and swelling percentage decreased but minimum torque (ML) and maximum torque (MH) increased with increasing carbon black (CB) loading in the blends. Increasing CB loading also increased tensile strength, tensile modulus (M100), hardness and compression set but decreased elongation at break (Eb) of NBRv/NBRr blends.

A Tire-Sulfur Hybrid Adsorption Denitrification (T-SHAD) process for decentralized wastewater treatment.

PubMed

Krayzelova, Lucie; Lynn, Thomas J; Banihani, Qais; Bartacek, Jan; Jenicek, Pavel; Ergas, Sarina J

2014-09-15

Nitrogen discharges from decentralized wastewater treatment (DWT) systems contribute to surface and groundwater contamination. However, the high variability in loading rates, long idle periods and lack of regular maintenance presents a challenge for biological nitrogen removal in DWT. A Tire-Sulfur Hybrid Adsorption Denitrification (T-SHAD) process was developed that combines nitrate (NO3(-)) adsorption to scrap tire chips with sulfur-oxidizing denitrification. This allows the tire chips to adsorb NO3(-) when the influent loading exceeds the denitrification capacity of the biofilm and release it when NO3(-) loading rates are low (e.g. at night). Three waste products, scrap tire chips, elemental sulfur pellets and crushed oyster shells, were used as a medium in adsorption, leaching, microcosm and up-flow packed bed bioreactor studies of NO3(-) removal from synthetic nitrified DWT wastewater. Adsorption isotherms showed that scrap tire chips have an adsorption capacity of 0.66 g NO3(-)-N kg(-1) of scrap tires. Leaching and microcosm studies showed that scrap tires leach bioavailable organic carbon that can support mixotrophic metabolism, resulting in lower effluent SO4(2-) concentrations than sulfur oxidizing denitrification alone. In column studies, the T-SHAD process achieved high NO3(-)-N removal efficiencies under steady state (90%), variable flow (89%) and variable concentration (94%) conditions. Copyright © 2014 Elsevier Ltd. All rights reserved.

Use of zinc and copper (I) salts to reduce sulfur and nitrogen impurities during the pyrolysis of plastic and rubber waste to hydrocarbons

DOEpatents

Wingfield, Jr., Robert C.; Braslaw, Jacob; Gealer, Roy L.

1984-01-01

An improvement in a process for the pyrolytic conversion of rubber and plastic waste to hydrocarbon products which results in reduced levels of nitrogen and sulfur impurities in these products. The improvement comprises pyrolyzing the waste in the presence of at least about 1 weight percent of salts, based on the weight of the waste, preferably chloride or carbonate salts, of zinc or copper (I). This invention was made under contract with or subcontract thereunder of the Department of Energy Contract #DE-AC02-78-ER10049.

Nano-carbons from waste tyre rubber: An insight into structure and morphology.

PubMed

Maroufi, Samane; Mayyas, Mohannad; Sahajwalla, Veena

2017-11-01

This study reports on the novel and sustainable synthesis of high value carbon nanoparticles (CNPs) from waste tyre rubber (WTR), using an innovative high temperature approach. As waste tyres are composed, primarily, of carbon - accounting for some 81.2wt% - they represent a promising source of carbon for many potential applications. However, cost-effective options for their processing are limited and, consequently, billions of waste tyres have accumulated in landfills and stockpiles, posing a serious global environmental threat. The rapid, high temperature transformation of low value WTR to produce valuable CNPs, reported here, addresses this challenge. In this study, the transformation of WTRs was carried out at 1550°C over different reaction times (5s to 20min). The structure and morphology of the resulting CNPs were investigated using X-ray diffraction (XRD), Raman spectroscopy, X-ray photon spectroscopy (XPS), N 2 isothermal adsorption method and scanning electron microscopy (SEM). The formation of CNPs with diameters of 30 and 40nm was confirmed by Field Emission Electron Microscopy (FE-SEM). Longer heating times also resulted in CNPs with regular and uniform spherical shapes and a specific surface area of up to 117.7m 2 /g, after 20min. A mechanism that describes the formation of CNPs through mesophase nuclei intermediate is suggested. Copyright © 2017 Elsevier Ltd. All rights reserved.

Tire/wheel concept

NASA Technical Reports Server (NTRS)

Harper, P. M., Sr. (Inventor)

1981-01-01

A tire and wheel assembly is disclosed in which a low profile pneumatic tire (having sidewalls which deflect inwardly under load) and a wheel (having a rim featuring a narrow central channel and extended rim flanges) form the combination. The extended rim flanges support the tire sidewalls under static and dynamic loading conditions to produce a combination particularly suited to aircraft applications.

A Tire Air Maintenance Technology

ERIC Educational Resources Information Center

Pierce, Alan

2012-01-01

Improperly inflated car tires can reduce gas mileage and car performance, speed up tire wear, and even cause a tire to blow out. The AAA auto club recommends that someone check the air pressure of one's car's tires at least once a month. Wouldn't it be nice, though, if someone came up with a tire pressure-monitoring system that automatically kept…

Identification of benzothiazole derivatives and polycyclic aromatic hydrocarbons as aryl hydrocarbon receptor agonists present in tire extracts.

PubMed

He, Guochun; Zhao, Bin; Denison, Michael S

2011-08-01

Leachate from rubber tire material contains a complex mixture of chemicals previously shown to produce toxic and biological effects in aquatic organisms. The ability of these leachates to induce Ah receptor (AhR)-dependent cytochrome P4501A1 expression in fish indicated the presence of AhR active chemicals, but the responsible chemicals and their direct interaction with the AhR signaling pathway were not examined. Using a combination of AhR-based bioassays, we have demonstrated the ability of tire extract to stimulate both AhR DNA binding and AhR-dependent gene expression and confirmed that the responsible chemicals were metabolically labile. The application of CALUX (chemical-activated luciferase gene expression) cell bioassay-driven toxicant identification evaluation not only revealed that tire extract contained a variety of known AhR-active polycyclic aromatic hydrocarbons but also identified 2-methylthiobenzothiazole and 2-mercaptobenzothiazole as AhR agonists. Analysis of a structurally diverse series of benzothiazoles identified many that could directly stimulate AhR DNA binding and transiently activate the AhR signaling pathway and identified benzothiazoles as a new class of AhR agonists. In addition to these compounds, the relatively high AhR agonist activity of a large number of fractions strongly suggests that tire extract contains a large number of physiochemically diverse AhR agonists whose identities and toxicological/biological significances are unknown. Copyright © 2011 SETAC.

Mechanical Parameters of Rubber-Sand Mixtures for Numerical Analysis of a Road Embankment

NASA Astrophysics Data System (ADS)

Kowalska, Magdalena; Chmielewski, Maciej

2017-10-01

Waste production is one of the greatest problems of the modern world. It is inevitably related to the increase of industrialization. One of the most difficult, and growing in amounts, waste is scrap tyres. The most common method of utilization of end-of-life tyres by their incineration raises much concern in terms of air pollution. More sustainable seems to reuse the tyre derived products - rubber in particular - in civil engineering, where the interesting properties of this material may be effectively utilized. This paper presents results of direct shear strength tests on sand-rubber mixtures, which were next applied to a numerical FEM (finite element method) model of a road embankment built on soft ground. The laboratory tests, conducted for two types of scrap tyre rubber granulates (0.5 - 2 mm and 1 - 5 mm in size) mixed with medium fluvial sand in various proportions (5, 10, 30 and 50% by weight), proved that the unit weight of the mixtures is distinctly smaller that the unit weight of sand alone and at 50% rubber content it drops by half. The internal angle of friction stays almost unchanged for the mixtures with up to 10% of rubber (33 - 37°), but decreases by about 10° when the rubber content increases to 50%. In most of the cases analysed, the cohesion intercept is higher in case of sand-rubber mixtures when compared to sand alone. The numerical model simulated a 4.5 m high embankment with a 3 m thick layer made of sand-rubber mixtures, containing 0%, 10% or 30% of the waste product, founded on a weak subsoil (with a 3 m layer of organic soil). The results showed that stability factor of the structure built with the layer containing 30% of the coarser rubber granulate has increased from 1.60 - for sand only, to 2.15. The embankment was also able to carry load increased from 32 kPa to 45.5 kPa and its base showed much smaller settlement. The results prove that the use of tyre derived aggregates in embankment construction is not only an effective way of

Proceedings of the Floating Tire Breakwater Workshop Held in Niagara Falls, New York on 8-9 November 1984.

DTIC Science & Technology

1985-11-01

report are not to be construed as an official Department of the Army position unless so designated by other authorized documents. The contents of...New York AGENDA Wednesday, 7 November 7:30 p.m. Registration 8:00 Floating Tire Breakwater (FTB) Slides and Movies Thursday, 8 November 8:30 a.m...which urethanes to use with which rubber. Some of the variables are: the -k solvent used in the bonding agent, room temperature, air moisture content

A Study on the Rheological Properties of Recycled Rubber-Modified Asphalt Mixtures

PubMed Central

Karacasu, Murat; Er, Arzu

2015-01-01

Using waste rubber in asphalt mixes has become a common practice in road construction. This paper presents the results of a study on the rheological characteristics of rubber-modified asphalt (RMA) concrete under static and dynamic loading conditions. A number of static and dynamic creep tests were conducted on RMA mix specimens with different rubber sizes and contents, and a series of resonant column tests were conducted to evaluate the shear modulus and damping values. To simulate the stress-strain response of traffic-induced loading, the measurements were taken for different confining pressures and strain levels. The results of the study indicated that rubber modification increases stiffness and damping ratio, making it a very attractive material for use in road construction. However the grain size of the rubber is very important. Although RMA may cost up to 100% more than regular asphalt, the advantages it brings, such as an increased service life of the road and proper waste utilization contributing to a more sustainable infrastructure, may justify the added cost. PMID:25695096

Tire safety : everything rides on it

DOT National Transportation Integrated Search

2008-01-01

This booklet presents a comprehensive overview of tire safety, including information on the following topics: basic tire maintenance; Uniform Tire Quality Grading System; fundamental characteristics of tires; and tire safety tips.

Effect of wheelchair mass, tire type and tire pressure on physical strain and wheelchair propulsion technique.

PubMed

de Groot, Sonja; Vegter, Riemer J K; van der Woude, Lucas H V

2013-10-01

The purpose of this study was to evaluate the effect of wheelchair mass, solid vs. pneumatic tires and tire pressure on physical strain and wheelchair propulsion technique. 11 Able-bodied participants performed 14 submaximal exercise blocks on a treadmill with a fixed speed (1.11 m/s) within 3 weeks to determine the effect of tire pressure (100%, 75%, 50%, 25% of the recommended value), wheelchair mass (0 kg, 5 kg, or 10 kg extra) and tire type (pneumatic vs. solid). All test conditions (except pneumatic vs. solid) were performed with and without instrumented measurement wheels. Outcome measures were power output (PO), physical strain (heart rate (HR), oxygen uptake (VO2), gross mechanical efficiency (ME)) and propulsion technique (timing, force application). At 25% tire pressure PO and subsequently VO2 were higher compared to 100% tire pressure. Furthermore, a higher tire pressure led to a longer cycle time and contact angle and subsequently lower push frequency. Extra mass did not lead to an increase in PO, physical strain or propulsion technique. Solid tires led to a higher PO and physical strain. The solid tire effect was amplified by increased mass (tire × mass interaction). In contrast to extra mass, tire pressure and tire type have an effect on PO, physical strain or propulsion technique of steady-state wheelchair propulsion. As expected, it is important to optimize tire pressure and tire type. Copyright © 2013 IPEM. Published by Elsevier Ltd. All rights reserved.

75 FR 7586 - Baled Natural Rubber in Tires; TSCA Section 21 Petition; Agency Response

Federal Register 2010, 2011, 2012, 2013, 2014

2010-02-22

... affect the incidence of Hevea brasiliensis natural-rubber allergies and allergy induced autism.'' After... allergy induced autism'' (Refs. 1 and 2). This petition is similar to a previous petition that the same...?keywords=allergies+and+autism&x=13+y=9 ) dated November 13, 2009, which advertises, and includes an...

Research and application of online measurement system of tire tread profile in automobile tire production

NASA Astrophysics Data System (ADS)

Wang, Pengyao; Chen, Xiangguang; Yang, Kai; Liu, Xuejiao

2017-01-01

To improve the measuring efficiency of width and thickness of tire tread in the process of automobile tire production, the actual condition for the tire production process is analyzed, and a fast online measurement system based on moving tire tread of tire specifications is established in this paper. The coordinate data of tire tread profile is acquired by 3D laser sensor, and we use C# language for programming which is an object-oriented programming language to complete the development of client program. The system with laser sensor can provide real-time display of tire tread profile and the data to require in the process of tire production. Experimental results demonstrate that the measuring precision of the system is <= 1mm, it can meet the measurement requirements of the production process, and the system has the characteristics of convenient installation and testing, system stable operation.

Chevron cutting: Experiment with new runway mixtures

NASA Technical Reports Server (NTRS)

Tyran, K. (Compiler)

1978-01-01

Chevron cutting is shown to occur in different forms depending on the type of tire and the rubber on the running surface. Hardest wear is shown by the main tires of the B-747. Four defects occurred, in the form of two rip separation and two breakouts of the running surface. Tires capped by Thompson are more affected than any of the other rubber-capping fabrics. For Thompson tires, Chevron Cutting is greatly reduced with a fiberglass-rubber mixture. For Goodyear tires, it is eliminated with spiral wrap rubbercapping; resistance to damages through cuts seems to be more positive for Goodyear tires. For Mader tires, the extent of Chevron Cutting is generally smaller than for Thompson cappings.

Thermoset recycling via high-pressure high-temperature sintering: Revisiting the effect of interchange chemistry

NASA Astrophysics Data System (ADS)

Morin, Jeremy Edward

In 1844 Charles Goodyear obtained U.S. Patent #3,633 for his "Gum Elastic Composition". In a published circular, which describes his patent for the sulfur vulcanization of gum elastic composition, he stated: "No degree of heat, without blaze, can melt it (rubber)... It resists the most powerful chemical reagents. Aquafortis (nitric acid), sulphuric acid, essential and common oils, turpentine and other solvents... ..." Goodyear's sulfur vulcanization of rubber fueled much of the industrial revolution and made transportation possible, as it exists today. In doing so, Goodyear created one of the most difficult materials to recycle. Rubber will not melt, dissolve, or lend itself to the usual methods of chemical decomposition. Ironically, Goodyear recognized this problem and in 1853 he patented the process of adding ground rubber to virgin material, now currently known as regrind blending. Today, scrap tires represent one of the most serious sources of pollution in the world. Studies estimate that there are roughly 2 billion scrap tires in U.S. landfills and more are being added at a rate of over 273 million tires per year. Current methods of recycling waste tires are crude, ineffective, and use rubber powder as a low cost filler instead of a new rubber. The groundwork for a very simple and effective method of producing high-quality rubber goods using 100% scrap rubber was discovered in 1944 by A. V. Tobolsky et al. This application, however, was not recognized until recently in our laboratory. The process as studied to date represents a method of creating quality, high-value added rubber goods with nothing other than heat and pressure. High pressure is required to obtain a void-free compaction of the rubber particles by forcing all of the free surfaces into intimate contact. High temperature then activates the chemical rearrangement, scission, and reformation of the chemical bonds thus providing new bridges between the once fractured interfaces. This occurs both within

Lightweight tire concept for space shuttle

NASA Technical Reports Server (NTRS)

Shufflebotham, W. T.

1973-01-01

Various tests were conducted on a 49x17/26 PR aircraft tire that had been designed as a lightweight tire for use on the C-5A military transport. This tire is approximately 25 per cent lighter than a tire of the same size and ply rating that would be used in commercial airline service. The tires were tested at 40 per cent, 37 per cent, and 35 per cent deflections. These deflections were obtained by adjusting the inflation pressure while the load on the tire remained constant at 60,000 pounds. It was determined that the tire would operate successfully under the test conditions at 35% deflection. Prior to testing, the tires were subjected to conditions of high vacuum and low temperature. It was determined that the tires were not adversely affected by these conditions.

Incorporation of Rubber Powder as Filler in a New Dry-Hybrid Technology: Rheological and 3D DEM Mastic Performances Evaluation

PubMed Central

Vignali, Valeria; Mazzotta, Francesco; Sangiorgi, Cesare; Simone, Andrea; Lantieri, Claudio; Dondi, Giulio

2016-01-01

In recent years, the use of crumb rubber as modifier or additive within asphalt concretes has allowed obtaining mixtures able to bind high performances to recovery and reuse of discarded tires. To date, the common technologies that permit the reuse of rubber powder are the wet and dry ones. In this paper, a dry-hybrid technology for the production of Stone Mastic Asphalt mixtures is proposed. It allows the use of the rubber powder as filler, replacing part of the limestone one. Fillers are added and mixed with a high workability bitumen, modified with SBS (styrene-butadiene-styrene) polymer and paraffinic wax. The role of rubber powder and limestone filler within the bituminous mastic has been investigated through two different approaches. The first one is a rheological approach, which comprises a macro-scale laboratory analysis and a micro-scale DEM simulation. The second, instead, is a performance approach at high temperatures, which includes Multiple Stress Creep Recovery tests. The obtained results show that the rubber works as filler and it improves rheological characteristics of the polymer modified bitumen. In particular, it increases stiffness and elasticity at high temperatures and it reduces complex modulus at low temperatures. PMID:28773965

Wheels and Tires: Understanding the Numbers on the Sides of Tires Might Lead to Longer Life Tires and Improved Driving Safety

ERIC Educational Resources Information Center

Ritz, John M.

2005-01-01

Automotive wheels and tires require knowledge to understand their specifications and use. While the durability and useful life of tires have increased substantially over the last several decades, in all probability consumers will purchase a number of vehicle tires over their lifetime. Knowing how they are made and what the numbers mean will assist…

Investigating Low Temperature Properties of Rubber Seals - 13020

DOE Office of Scientific and Technical Information (OSTI.GOV)

Jaunich, M.; Wolff, D.; Stark, W.

To achieve the required tightness levels of containers for low and intermediate level radioactive wastes rubbers are widely applied as main sealing materials. The save encapsulation of the radioactive container contents has to be guaranteed according to legislation and appropriate guidelines for long storage periods as well as down to temperatures of -40 deg. C during transportation. Therefore the understanding of failure mechanisms that lead to leakage at low temperatures is of high importance. It is known that the material properties of rubbers are strongly influenced by temperature. At low temperatures this is caused by the rubber-glass transition (abbr. glassmore » transition). During continuous cooling the material changes from rubber-like entropy-elastic to stiff energy-elastic behaviour, that allows nearly no strain or retraction. Therefore, rubbers are normally used above their glass transition but the minimum working temperature limit is not defined precisely, what can cause problems during application. The temperature range where full functionality is possible is strongly dependent on the application conditions and the material. For this investigation mainly ethylene propylene diene (EPDM) and fluorocarbon rubbers (FKM) were selected as they are often used for radioactive waste containers. Differential Scanning Calorimetry (DSC) and Dynamic Mechanical Analysis (DMA) are typically used for the determination of the temperature range of the glass transition process. The standardized compression set measurement according to ISO 815 is common for investigation of rubber sealing materials as the test simulates the seal behaviour after release. To reduce the test time of the standard tests a faster technique giving the same information was developed. Additionally, the breakdown temperature of the sealing function of complete O-ring seals is measured in a component test setup to compare it with the results of the other tests. The experimental setup is capable

A study of the dynamic tire properties over a range of tire constructions

NASA Technical Reports Server (NTRS)

Nybakken, G. H.; Dodge, R. N.; Clark, S. K.

1973-01-01

The dynamic properties of four model aircraft tires of various construction were evaluated experimentally and compared with available theory. The experimental investigation consisted of measuring the cornering force and the self-aligning torque developed by the tires undergoing sinusoidal steering inputs while operating on a small scale, road-wheel tire testing apparatus. The force and moment data from the different tires are compared with both finite- and point-contact patch string theory predictions. In general, agreement between finite contact patch theory and experimental observation is good. A modified string theory is also presented in which coefficients for cornering force and self-aligning torque are determined separately. This theory improves the correspondence between the experimental and analytical data, particularly on tires with relatively high self-aligning torques.

Features and characterization needs of rubber composite structures

NASA Technical Reports Server (NTRS)

Tabaddor, Farhad

1989-01-01

Some of the major unique features of rubber composite structures are outlined. The features covered are those related to the material properties, but the analytical features are also briefly discussed. It is essential to recognize these features at the planning stage of any long-range analytical, experimental, or application program. The development of a general and comprehensive program which fully accounts for all the important characteristics of tires, under all the relevant modes of operation, may present a prohibitively expensive and impractical task at the near future. There is therefore a need to develop application methodologies which can utilize the less general models, beyond their theoretical limitations and yet with reasonable reliability, by proper mix of analytical, experimental, and testing activities.

Used tire recycling to produce granulates: evaluation of occupational exposure to chemical agents.

PubMed

Savary, Barbara; Vincent, Raymond

2011-10-01

Exposure was assessed in four facilities where used tires are turned into rubber granulates. Particulate exposure levels were measured using filter samples and gravimetric analysis. In parallel, volatile organic compounds (VOCs) screening was carried out using samples taken on activated carbon supports, followed by an analysis using a gas chromatograph coupled to a spectrometric detector. The exposure level medians are between 0.58 and 3.95 mg m(-3). Clogging of the textile fiber separation systems can lead to worker exposure; in this case, the measured concentrations can reach 41 mg m(-3). However, in contrast to the data in the literature, VOC levels >1 p.p.m. were not detected. The particulate mixtures deposited on the installation surfaces are complex; some of the chemical agents are toxic to humans. The results of this study indicate significant exposure to complex mixtures of rubber dust. Optimizing exhaust ventilation systems inside the shredders, with a cyclone for example, is essential for reducing the exposure of workers in this rapidly developing sector.

Identification of Benzothiazole Derivatives and Polycyclic Aromatic Hydrocarbons as Aryl Hydrocarbon Receptor Agonists Present in Tire Extracts

PubMed Central

He, Guochun; Zhao, Bin; Denison, Michael S.

2012-01-01

Leachate from rubber tire material contains a complex mixture of chemicals previously shown to produce toxic and biological effects in aquatic organisms. While the ability of these leachates to induce Ah receptor (AhR)-dependent cytochrome P4501A1 expression in fish indicated the presence of AhR active chemicals, the responsible chemical(s) and their direct interaction with the AhR signaling pathway were not examined. Using a combination of AhR-based bioassays, we have demonstrated the ability of tire extract to stimulate both AhR DNA binding and AhR-dependent gene expression and confirmed that the responsible chemical(s) was metabolically labile. The application of CALUX (Chemical-Activated LUciferase gene eXpression) cell bioassay-driven toxicant identification evaluation not only revealed that tire extract contained a variety of known AhR-active polycyclic aromatic hydrocarbons, but also identified 2-methylthiobenzothiazole and 2-mercaptobenzothiazole as AhR agonists. Analysis of a structurally diverse series of benzothiazoles identified many that could directly stimulate AhR DNA binding and transiently activate the AhR signaling pathway and identified benzothiazoles as a new class of AhR agonists. In addition to these compounds, the relatively high AhR agonist activity of a large number of fractions strongly suggests that tire extract contains a large number of physiochemically diverse AhR agonists whose identities and toxicological/biological significances are unknown. PMID:21590714

Computational Modeling of Tires

NASA Technical Reports Server (NTRS)

Noor, Ahmed K. (Compiler); Tanner, John A. (Compiler)

1995-01-01

This document contains presentations and discussions from the joint UVA/NASA Workshop on Computational Modeling of Tires. The workshop attendees represented NASA, the Army and Air force, tire companies, commercial software developers, and academia. The workshop objectives were to assess the state of technology in the computational modeling of tires and to provide guidelines for future research.

Energy dissipation in a rolling aircraft tire

NASA Technical Reports Server (NTRS)

Tielking, John T.

1988-01-01

The project is extending an existing finite element tire model to calculate the energy dissipation in a free-rolling aircraft tire and temperature buildup in the tire carcass. The model will provide a means of calculating the influence of tire design on the distribution of tire temperature. Current focus is on energy loss measurements of aircraft tire material. The feasibility of taking test specimens directly from the tire carcass for measurements of viscoelastic properties was demonstrated. The interaction of temperature and frequency effects on material loss properties was studied. The tire model was extended to calculate the cyclic energy change in a tire during rolling under load. Input data representing the 40 by 14 aircraft tire whose material loss properties were measured are being used.

Fixed-bed adsorption study of methylene blue onto pyrolytic tire char

NASA Astrophysics Data System (ADS)

Makrigianni, Vassiliki; Giannakas, Aris; Papadaki, Maria; Albanis, Triantafyllos; Konstantinou, Ioannis

2016-04-01

In this work, the adsorption efficiency of acid treated pyrolytic tire char to cationic methylene blue (MB) dye adsorption from aqueous solutions was investigated by fixed-bed adsorption column experiments. The effects of the initial dye concentration (10 - 40 mg L-1) and feed flow rate (50 - 150 mL min -1) with a fixed bed height (15 cm) were studied in order to determine the breakthrough characteristics of the adsorption system. The Adams-Bohart, Yoon-Nelson and Thomas model were applied to the adsorption of MB onto char at different operational conditions to predict the breakthrough curves and to determine the characteristic parameters of the column. The results showed that the maximum adsorbed quantities decreased with increasing flow rate and increased with increasing initial MB concentration. Breakthrough time and exhaustion time increased with decreasing inlet dye concentration and flow rate. In contrast with Adams-Bohart model, Yoon-Nelson model followed by Thomas model were found more suitable to describe the fixed-bed adsorption of methylene blue by char. The correlation coefficient values R2 for both models at different operating conditions are higher than 0.9 and the low average relative error values provided very good fittings of experimental data at different operating conditions. Higher adsorption capacity of 3.85 mg g -1 was obtained at 15 cm of adsorbent bed height, flow rate of 100 mL min -1and initial MB concentration of 40 mg L-1. Although that activated carbons exhibited higher adsorption capacities in the literature, acid-treated pyrolytic tire char was found to be considerably efficient adsorbent for the removal of MB dye column taking into account the advantages of the simpler production process compared to activated carbons, as well as, the availability of waste tire feedstock and concurrent waste tire management.

Tire-wear particles as a source of zinc to the environment

USGS Publications Warehouse

Councell, T.B.; Duckenfield, K.U.; Landa, E.R.; Callender, E.

2004-01-01

Tire-tread material has a zinc (Zn) content of about 1 wt %. The quantity of tread material lost to road surfaces by abrasion has not been well characterized. Two approaches were used to assess the magnitude of this nonpoint source of Zn in the U.S. for the period 1936-1999. In the first approach, tread-wear rates from the automotive engineering literature were used in conjunction with vehicle distance-driven data from the U.S. Department of Transportation to determine Zn releases. A second approach calculated this source term from the volume of tread lost during lifetime tire wear. These analyses showed that the quantity of Zn released by tire wear in the mid-1990s was of the same magnitude as that released from waste incineration. For 1999, the quantity of Zn released by tire wear in the U.S. is estimated to be 10 000-11 000 metric tons. A specific case study focused on Zn sources and sinks in an urban-suburban watershed (Lake Anne) in the Washington, DC, metropolitan area for a time period of the late 1990s. The atmospheric flux of total Zn (wet deposition) to the watershed was 2 ??g/cm2/yr. The flux of Zn to the watershed estimated from tire wear was 42 ??g/cm2/yr. The measured accumulation rate of total Zn in age-dated sediment cores from Lake Anne was 27 ??g/cm2/yr. These data suggest that tire-wear Zn inputs to urban-suburban watersheds can be significantly greater than atmospheric inputs, although the watershed appears to retain appreciable quantities of vehicular Zn inputs.

Tire-soil interaction model for turning (steered) tires

NASA Astrophysics Data System (ADS)

Karafiath, L. L.

1985-07-01

A review of the experimental information on the development of lateral forces on tires traveling at an angle to their center plane is presented and the usefulness of the consideration of the lateral forces for the development of an analytical model is evaluated. Major components of the lateral force have been identified as the forces required to balance the tractive force and the drawbar pull vectorially. These are the shear stresses developing in the contact area and the horizontal component of the normal stresses acting on the in-ground portion or the curved side walls of the tire. The tire-soil interaction model for steady state straight travel has been expanded to include the necessary algorithms for the calculation of these lateral forces. The pattern of tractive force-slip and longitudinal-lateral force relationships is in general agreement with experiments.

Land Vehicle Tire Qualification

DTIC Science & Technology

2010-03-25

separation -Bead damage / separation -Severe open splices and/or liner separations - Tire induced loss of air -Exposed or broken casing -Bulges in tread ...or sidewall *UNCLASSIFIED* SAE J2014 11 SAE J2014 4.14 Tire Treadlife Durability -10000 miles duration -Evaluate tread wear performance of candidate... tire -Measurements at prescribed intervals - Tread depth at centerline & shoulder -Diameter, section width, tread arc width -Conducted on courses

Tyre char preparation from waste tyre rubber for dye removal from effluents.

PubMed

Mui, Edward L K; Cheung, W H; McKay, Gordon

2010-03-15

A number of chars from waste tyre rubber were prepared by carbonisation at 673-1173 K. The effects of holding time, heating rate and particle size on the textural characteristics and elemental composition of the resultant chars were investigated. It was demonstrated that temperatures over 773 K did not have a significant improvement on the total surface area but resulted in lower char yields following increased aromatisation. Modelling of dye adsorption isotherms showed that the Redlich-Peterson expression yields the best-fit between experimental and predicted data. Furthermore, for a larger sized dye like Acid Yellow 117 (MW=848 g/mol), the amount adsorbed by the tyre char is not directly proportional to the total surface area when compared with a commercial carbon, revealing that factors other than total surface area are involved in the adsorption potential of the tyre chars. (c) 2009 Elsevier B.V. All rights reserved.

Tire Footprint Affects Hydroplaning On Wet Pavement

NASA Technical Reports Server (NTRS)

Yager, Thomas J.

1989-01-01

Recent investigations of tire hydroplaning at highway speeds reveal, in addition to inflation pressure, tire-footprint aspect ratio (FAR), defined as width divided by length of tire surface in contact with pavement, significantly influences speed at which dynamic hydroplaning begins. Tire speeds and forces developed during tests of up to 65 mi/h (105 km/h) were monitored on flooded test surface to identify development of hydroplaning. Study focused on automotive tires because FAR's of automotive tires vary more than those of aircraft tires.

Novel polymer composites from waste ethylene-propylene-diene-monomer rubber by supercritical CO2 foaming technology.

PubMed

Jeong, Keuk Min; Hong, Yeo Joo; Saha, Prosenjit; Park, Seong Ho; Kim, Jin Kuk

2014-11-01

In this study, a composite has been prepared by mixing waste rubber, such as ethylene-propylene-diene-monomer and low-density poly ethylene foaming, with supercritical carbon dioxide. In order to optimise the foaming process of the waste ethylene-propylene-diene-monomer-low-density poly ethylene composite, the variations of pressure and temperature on the foamed Microcell formation were studied. As indicated in scanning electron microscope photographs, the most uniform microcellular pattern was found at 200 bar and 100 °C using 30% by weight of waste ethylene-propylene-diene-monomer. Carbon dioxide could not be dissolved uniformly during foaming owing to extensive cross-linking of the waste ethylene-propylene-diene-monomer used for the composite. As a result the presence of un-uniform microcells after foaming were observed in the composite matrix to impart inferior mechanical properties of the composite. This problem was solved with uniform foaming by increasing the cross-link density of low-density poly ethylene using 1.5 parts per hundred dicumyl peroxide that enhances composite tensile and compressive strength up to 57% and 15%, respectively. The composite has the potential to be used as a foaming mat for artificial turf. © The Author(s) 2014.

A Strain-Based Method to Estimate Slip Angle and Tire Working Conditions for Intelligent Tires Using Fuzzy Logic.

PubMed

Garcia-Pozuelo, Daniel; Yunta, Jorge; Olatunbosun, Oluremi; Yang, Xiaoguang; Diaz, Vicente

2017-04-16

Tires equipped with sensors, the so-called "intelligent tires", can provide vital information for control systems, drivers and external users. In this research, tire dynamic strain characteristics in cornering conditions are collected and analysed in relation to the variation of tire working conditions, such as inflation pressure, rolling speed, vertical load and slip angle. An experimental tire strain-based prototype and an indoor tire test rig are used to demonstrate the suitability of strain sensors to establish relations between strain data and lateral force. The results of experiments show that strain values drop sharply when lateral force is decreasing, which can be used to predict tire slip conditions. As a first approach to estimate some tire working conditions, such as the slip angle and vertical load, a fuzzy logic method has been developed. The simulation and test results confirm the feasibility of strain sensors and the proposed computational model to solve the non-linearity characteristics of the tires' parameters and turn tires into a source of useful information.

Study of in-plane dynamics of tires

NASA Astrophysics Data System (ADS)

Gong, S.

1993-12-01

The in-plane dynamics of tires deals with the forces and motion in the plane of rotation of the wheel. Three aspects of tire in-plane dynamics can be identified: the rolling contact between the tire and the road surface; the transmission of forces and motion from the contact patch to the wheel axle; and the vibration of the tire treadband. The main objective of the investigation reported in this thesis is to develop a tire model which is suitable to study all three aspects of the in-plane dynamics of tires in both low and high frequency ranges. The tire model is finally validated by experimental modal analysis of a test tire. Laboratory tests are conducted to establish the modal shapes and natural frequencies of the test tire. The tests are carried out for two different configurations of the tire: one with the wheel rim fixed in space and one with the tire-wheel system suspended freely in the air. Good agreement is found between the experimental and theoretical results.

Remote tire pressure sensing technique

NASA Technical Reports Server (NTRS)

Robinson, Howard H. (Inventor); Mcginnis, Timothy A. (Inventor); Daugherty, Robert H. (Inventor)

1993-01-01

A remote tire pressure sensing technique is provided which uses vibration frequency to determine tire pressure. A vibration frequency measuring device is attached to the external surface of a tire which is then struck with an object, causing the tire to vibrate. The frequency measuring device measures the vibrations and converts the vibrations into corresponding electrical impulses. The electrical impulses are then fed into the frequency analyzing system which uses the electrical impulses to determine the relative peaks of the vibration frequencies as detected by the frequency measuring device. The measured vibration frequency peaks are then compared to predetermined data describing the location of vibration frequency peaks for a given pressure, thereby determining the air pressure of the tire.

30 CFR 56.14104 - Tire repairs.

Code of Federal Regulations, 2010 CFR

2010-07-01

... 30 Mineral Resources 1 2010-07-01 2010-07-01 false Tire repairs. 56.14104 Section 56.14104 Mineral... Devices and Maintenance Requirements § 56.14104 Tire repairs. (a) Before a tire is removed from a vehicle for tire repair, the valve core shall be partially removed to allow for gradual deflation and then...

30 CFR 57.14104 - Tire repairs.

Code of Federal Regulations, 2010 CFR

2010-07-01

... 30 Mineral Resources 1 2010-07-01 2010-07-01 false Tire repairs. 57.14104 Section 57.14104 Mineral... Devices and Maintenance Requirements § 57.14104 Tire repairs. (a) Before a tire is removed from a vehicle for tire repair, the valve core shall be partially removed to allow for gradual deflation and then...

Compression Molding of Composite of Recycled HDPE and Recycled Tire Particles

NASA Technical Reports Server (NTRS)

Liu, Ping; Waskom, Tommy L.; Chen, Zhengyu; Li, Yanze; Peng, Linda

1996-01-01

Plastic and rubber recycling is an effective means of reducing solid waste to the environment and preserving natural resources. A project aimed at developing a new composite material from recycled high density polyethylene (HDPE) and recycled rubber is currently being conducted at Eastern Illinois University. The recycled plastic pellets with recycled rubber particles are extruded into some HDPE/rubber composite strands. The strand can be further cut into pellets that can be used to fabricate other material forms or products. This experiment was inspired by the above-mentioned research activity. In order to measure Durometer hardness of the extruded composite, a specimen with relatively large dimensions was needed. Thus, compression molding was used to form a cylindrical specimen of 1 in. diameter and 1 in. thickness. The initial poor quality of the molded specimen prompted a need to optimize the processing parameters such as temperature, holding time, and pressure. Design of experiment (DOE) was used to obtain optimum combination of the parameters.

Arsenite and arsenate removal from wastewater using cationic polymer-modified waste tyre rubber.

PubMed

Imyim, Apichat; Sirithaweesit, Thitayati; Ruangpornvisuti, Vithaya

2016-01-15

Waste tyre rubber (WTR) granulate was modified with a cationic polymer, poly(3-acrylamidopropyl)trimethylammonium chloride (p(APTMACl)). The resulting WTR/p(APTMACl) was utilized for the adsorption of arsenite, As(III) and arsenate, As(V) from aqueous medium in both batch and column methods. The level of adsorption increased gradually with increasing monomer concentration and contact time. The adsorption behavior obeyed the Freundlich model, and the rate of adsorption could be predicted by employing the pseudo-second order model. In the column method, As(V) could be adsorbed onto the sorbent more effectively than As(III). Remarkable desorption of As(III) and As(V) (99 and 92%, respectively) from the adsorbent was achieved using 0.10 M HCl as eluent. An approach of evaluation of adsorption capacity uncertainty is proposed. Copyright © 2015 Elsevier Ltd. All rights reserved.

14 CFR 27.733 - Tires.

Code of Federal Regulations, 2011 CFR

2011-01-01

... STANDARDS: NORMAL CATEGORY ROTORCRAFT Design and Construction Landing Gear § 27.733 Tires. (a) Each landing... gravity. (c) Each tire installed on a retractable landing gear system must, at the maximum size of the tire type expected in service, have a clearance to surrounding structure and systems that is adequate...

40 CFR 63.5980 - What is the purpose of this subpart?

Code of Federal Regulations, 2010 CFR

2010-07-01

... Standards for Hazardous Air Pollutants: Rubber Tire Manufacturing What This Subpart Covers § 63.5980 What is... pollutants (NESHAP) for rubber tire manufacturing. This subpart also establishes requirements to demonstrate...

26 CFR 48.4073-4 - Other tax-free sales.

Code of Federal Regulations, 2010 CFR

2010-04-01

... EXCISE TAXES MANUFACTURERS AND RETAILERS EXCISE TAXES Motor Vehicles, Tires, Tubes, Tread Rubber, and Taxable Fuel Tires, Tubes, and Tread Rubber § 48.4073-4 Other tax-free sales. (a) Cross references. For... the Secretary of the Treasury under section 4293 for sales of certain tires and inner tubes sold to...

14 CFR 25.733 - Tires.

Code of Federal Regulations, 2011 CFR

2011-01-01

... reactions in paragraph (b) of this section, on the nose wheel tire, except as provided in paragraphs (b)(2) and (b)(3) of this section. (b) The applicable ground reactions for nose wheel tires are as follows: (1) The static ground reaction for the tire corresponding to the most critical combination of...

14 CFR 25.733 - Tires.

Code of Federal Regulations, 2010 CFR

2010-01-01

... reactions in paragraph (b) of this section, on the nose wheel tire, except as provided in paragraphs (b)(2) and (b)(3) of this section. (b) The applicable ground reactions for nose wheel tires are as follows: (1) The static ground reaction for the tire corresponding to the most critical combination of...

Influence of Rubber Size on Properties of Crumb Rubber Mortars

PubMed Central

Yu, Yong; Zhu, Han

2016-01-01

Studies on the properties and applications of rubber cement-based materials are well documented. The sizes of rubbers used in these materials varied. However, information about the effects of rubber size on the properties of rubber cement-based materials, especially pore structure, mechanical strengths, and drying shrinkage properties, remains limited. Three groups of rubber with major particle sizes of 2–4 mm, 1–3 mm, and 0–2 mm were selected in this study. This paper presents experimental studies on the effects of rubber size on the consistency, fresh density, pore structure, mechanical properties, and drying shrinkage properties of crumb rubber mortars (CRMs). Results demonstrated that the consistency and fresh density of CRMs decreased with the rubber size. As to the pore structure, the total pore volume increased with the decrease of the rubber size. By contrast, the influence of the rubber size on the mesopore (<50 nm) volume is not as significant as that of the rubber content. The mechanical properties of CRMs decreased with the rubber size. Low rubber stiffness and large pore volumes, especially those of small sized rubbers, contribute to the reduction of CRMs strength. The drying shrinkage of CRM increases as the rubber size decreases. The influences of rubber size on capillary tension are not significant. Thus, the shrinkage increases with the decrease of rubber size mainly because of its function in the deformation modulus reduction of CRMs. PMID:28773649

Adhesion and friction between glass and rubber in the dry state and in water: role of contact hydrophobicity.

PubMed

Kawasaki, S; Tada, T; Persson, B N J